WorldWideScience
1

Physical and optical properties of rare earth cobalt magnets  

Energy Technology Data Exchange (ETDEWEB)

Rare Earth Cobalt (REC) permanent magnets have unique properties that permit solutions to some optical tasks that cannot be accomplished with conventional magnets. A review of design and of performance characteristics of these magnets includes an analytical description of the three dimensional fringe fields of REC quadrupoles.

1980-08-01

2

Paramagnetic properties of the RCo_2 compounds (R = rare earth)  

International Nuclear Information System (INIS)

The paramagnetic susceptibilities of all the RCo_2 compounds for which measurements are available are found to obey a Curie-Weiss law consistent with the modified indirect exchange model. The rare-earth ions are in a well defined tripositive valence state. Paramagnetic moments and paramagnetic Curie temperatures are obtained for these materials for the first time. The paramagnetic moments of these materials are changed from their free-ion values by the effects of itinerant electron polarisation, an effect which is particularly large for SmCo_2 whose paramagnetic moment is almost three times greater than the free-ion value. The modified indirect exchange model is found to be able to give a full description of the magnitude of the rare-earth, cobalt and diffuse moments in polarised neutron experiments. The band structures of the light RCo_2 compounds are found to be distinctly different to those of the heavy RCo_2 compounds. ...

1984-03-01

4

Investigation of new materials for SOFC applications; Untersuchungen zum Einsatz neuer Werkstoffe fuer SOFC-Anwendungen  

Energy Technology Data Exchange (ETDEWEB)

Fuel cells based on solid oxides ('SOFC') are excellent alternative devices for power generation, when they are operated at high temperature, e.g. above 600 C. Having only fixed parts for the power generating part of the device is only one advantage of the fuel cell. Due to their unique design, these devices offer a maximum of efficiency for energy conversion compared to conventional power generating systems, which are mainly based on turbines. One aim of this thesis is the examination of alternative electrolyte and cathode materials for the SOFC applications at reduced temperatures, which means in the temperature range between 600 C and 750 C. For the first main task, several materials from the oxygen ion conducting electrolytes were selected. Different strontium and magnesium doped lanthanum gallate (LSGM) materials with additional transition metal doping were selected and prepared via two different preparation methods. The optimum calcining conditions were ...

2007-05-04

5

Electrochemical and gas phase parameters of cathodes for intermediate temperature solid oxide fuel cells  

International Nuclear Information System (INIS)

A series of cyclic voltammetry, chronoamperometry and electrochemical impedance experiments have been carried out in order to investigate the effect of cathode composition and porosity on the electrochemical characteristics of strontium-doped lanthanum, praseodymium and gadolinium cobaltite cathodes. The impedance responses at different electrode potentials of the half cell and symmetric single cell setups are compared and analyzed by the equivalent circuit modeling method. The deconvolution of impedance spectra for single cell cathode and anode reactions contributions based on the results of simultaneous analysis of half cells and symmetric single cells has been made by differential impedance real part vs. ac frequency plot analysis method. Noticeable influence of cathode chemical composition, meso-porosity and macro-porosity on the electrochemical activity of the oxygen electroreduction has been demonstrated. Seeming activation energy values have been calculated ...

2010-11-01

6

Microemulsion-mediated synthesis of cobalt (pure fcc and hexagonal phases) and cobalt-nickel alloy nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

By choosing appropriate microemulsion systems, hexagonal cobalt (Co) and cobalt-nickel (1:1) alloy nanoparticles have been obtained with cetyltrimethylammonium bromide as a cationic surfactant at 500degreeC. This method thus stabilizes the hcp cobalt even at sizes (<10nm) at which normally fcc cobalt is predicted to be stable. On annealing the hcp cobalt nanoparticles in H2 at 700degreeC we could transform them to fcc cobalt nanoparticles. Microscopy studies show the formation of spherical nanoparticles of hexagonal and cubic forms of cobalt and Co-Ni (1:1) alloy nanoparticles with the average size of 4, 8 and 20nm, respectively. Electrochemical studies show that the catalytic property towards oxygen evolution is dependent on the applied voltage. At low voltage (less than 0.65V) the Co (he...

2009-01-01

7

Structure and magnetic properties of RE_4CoCd and RE_4RhCd (RE = Tb, Dy, Ho)  

International Nuclear Information System (INIS)

New rare earth metal rich cadmium compounds RE_4CoCd and RE_4RhCd (RE = Tb, Dy, Ho) were prepared by high-frequency melting of the elements in sealed tantalum tubes. The samples were studied by x-ray powder and single-crystal diffraction. All the compounds crystallize with Gd_4RhIn-type structure, with space group F4-bar3m. The structures are built up from rigid three-dimensional networks of condensed, cobalt (rhodium) centred trigonal RE_6 prisms. The voids left by these networks are filled by Cd_4 cluster units and the coordination number 14 polyhedra of the RE1 atoms. The terbium and dysprosium compounds in both series undergo antiferromagnetic ordering, whereas the holmium compounds exhibit ferromagnetic ordering. The magnetic ordering in these compounds is characterized by broad peaks around the transition temperatures. The results of detailed crystallographic investigations and preliminary magnetic and specific heat studies are presented ...

2007-02-21

8

Heat resistant nickel base alloy excellent in workability and high temperature strength properties  

Energy Technology Data Exchange (ETDEWEB)

A heat resistant nickel base alloy which is excellent in not only hot and cold workability but also high temperature strength properties and which also possesses satisfactory oxidation resistance. The nickel base alloy consists essentially of 0.001-0.15 percent carbon, 0.0005-0.05 percent calcium, 20.0-126.0 percent chromium, 4.7-9.4 percent cobalt, 5.0-16.0 percent molybdenum, 0.5-4.0 percent tungsten, with the total of molybdenum plus tungsten being from 9.0 to 16.5 percent, and the balance nickel and inevitable impurities. The alloy may further contain one selected from the group consisting of (1) 0.3-1.5 percent aluminum and 0.1-1.0 percent titanium, (2) 0.001-0.30 percent at least one of yttrium and rare earth elements, and (3) 0.001-1.0 percent at least one of niobium, vanadium and tantalum, whereby the aforementioned characteristics are further enhanced.

1984-10-02

9

TIMBER TOP - The Gateway to Astronaut Photography of Earth  

Science.gov (United States)

The Gateway to Astronaut Photography of Earth hosts the best and most complete online collection of astronaut photographs of the Earth.

10

TIMBER CREEK - The Gateway to Astronaut Photography of Earth  

Science.gov (United States)

The Gateway to Astronaut Photography of Earth hosts the best and most complete online collection of astronaut photographs of the Earth.

11

BIG TIMBER - The Gateway to Astronaut Photography of Earth - NASA  

Science.gov (United States)

The Gateway to Astronaut Photography of Earth hosts the best and most complete online collection of astronaut photographs of the Earth.

12

Use of the 2-Pyridinealdoxime/N,N?-Donor Ligand Combination in Cobalt(III) Chemistry: Synthesis and Characterization of Two Cationic Mononuclear Cobalt(III) Complexes  

UK PubMed Central (United Kingdom)

The use of 2-pyridinealdoxime (paoH)/N,N′-donor ligand (L-L) “blend” in cobalt chemistry has afforded two cationic mononuclear cobalt(III) complexes of the general type [Co(pao)2(L-L)]+,...Full Text Available

2010-01-01

14

Visible Earth: Typhoon Aere  

Science.gov (United States)

NASA's Visible Earth catalog of NASA images and animations of our home planet.

15

beta- and gamma-decay studies of neutron-rich chromium, manganese, cobalt and nickel isotopes including the new isotopes $^{60}$Cr and $^{60g}$Mn  

CERN Document Server

beta- and gamma-decay studies of neutron-rich chromium, manganese, cobalt and nickel isotopes including the new isotopes $^{60}$Cr and $^{60g}$Mn

1987-01-01

16

Dynamics of ligand substitution in labile cobalt complexes resolved by ultrafast T-jump  

UK PubMed Central (United Kingdom)

Ligand exchange of hydrated metal complexes is common in chemical and biological systems. Using the ultrafast T-jump, we examined this process, specifically the transformation of aqua cobalt (II) complexes...Full Text Available

2008-09-02

17

Cobalt-57-bleomycin scanning of hila and mediastinum in patients with bronchial carcinoma: a prospective study.  

UK PubMed Central (United Kingdom)

Because the results with cobalt-57-bleomycin (57Co-bleo) as a tumour-seeking agent in patients with pulmonary tumours were promising, a prospective study was carried out to test the sensitivity and...Full Text Available

1976-12-01

18

Microstructure of spray converted nanostructured tungsten carbide-cobalt composite  

Energy Technology Data Exchange (ETDEWEB)

This paper reports the presence of face centered cubic cobalt precipitates inside tungsten carbide in nanocomposite of WC-Co synthesized by spray conversion processing. EDS was used to identify the presence and micro-diffraction was employed to determine the nature of the precipitates. There is entrapment of cobalt in tungsten carbide during the spray conversion process used to form WC/Co powder. During consolidation, at high temperatures, the cobalt attains enough mobility to precipitate inside WC. A vanadium containing compound was seen at the interfaces in samples which incorporated VC as a grain growth inhibitor. (orig.)

1996-05-01

20

Simplified Infrastructure - NASA History Office  

Science.gov (United States)

Automated Transport. Not Studied in Detail. Earth's Neighborhood. Simplified Infrastructure. Mars. Earth-. Moon L. 1. Gateway. Moon. Earth-Sun L. 2. Science ...

22

Visible Earth: Food Additives  

Science.gov (United States)

Feb 25, 2008 ... NASA's Visible Earth catalog of NASA images and animations of our home planet.

23

Development of a stable cobalt-ruthenium Fisher-Tropsch catalyst. Final report  

Energy Technology Data Exchange (ETDEWEB)

The reverse micelle catalyst preparation method has been used to prepare catalysts on four supports: magnesium oxide, carbon, alumina- titania and steamed Y zeolite. These catalysts were not as active as a reference catalyst prepared during previous contracts to Union Carbide Corp. This catalyst was supported on steamed Y zerolite support and was impregnated by a pore-filling method using a nonaqueous solvent. Additional catalysts were prepared via pore- filling impregnation of steamed Y zeolites. These catalysts had levels of cobalt two to three and a half times as high as the original Union Carbide catalyst. On a catalyst volume basis they were much more active than the previous catalyst; on an atom by atom basis the cobalt was about of the same activity, i.e., the high cobalt catalysts` cobalt atoms were not extensively covered over and deactivated by other cobalt atoms. The new, ...

1995-02-01

24

Metal phthalocyanine catalysts  

Energy Technology Data Exchange (ETDEWEB)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

1994-01-01

25

Double perovskite catalysts for oxidative coupling  

Energy Technology Data Exchange (ETDEWEB)

Alkali metal doped double perovskites containing manganese and at least one of cobalt, iron and nickel are useful in the oxidative coupling of alkane to higher hydrocarbons.

1991-01-01

26

Cobalt release from PCA steel during possible fusion reactor accidents  

Energy Technology Data Exchange (ETDEWEB)

Possible accident scenarios for a fusion reactor include breaches in the vacuum or cooling system. Intruding air or steam could react with structural or plasma facing materials, possibly mobilizing radioactive isotopes. Safety assessments must consider the early dose at the site boundary from the release of these activated materials. Previous calculations have indicated that cobalt isotopes dominate dose calculations for designs using stainless steel. Values used in these calculations, however, had been largely determined by the measurement limits of the chemical analysis methodology instead of measured releases. The purpose of the current study was to refine the analytical method to reduce the limit for detecting cobalt, and then test PCA steel in air and steam between 973 and 1473 K. Goals were to obtain more accurate measurements of cobalt mobilization in terms of g/m{sup 2}{center_dot}h and insight into the mobilization ...

1995-01-01

27

Catalyst for the manufacture of acrylonitrile and methacrylonitrile  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a catalyst composition. It consists of the catalytic oxides of iron, bismuth, molybdenum and magnesium as essential components and optionally the oxides of cobalt, nickel, phosphorus and arsenic.

1989-09-05

28

Visible Earth: Haitian Deforestation - Visible Earth - NASA  

Science.gov (United States)

Jun 8, 2006 ... It also reflects the large amount of deforestation that has occurred on the Haitian side of the border. One can easily see from satellite imagery ...

29

Visible Earth: Deforestation in Sumatra - Visible Earth - NASA  

Science.gov (United States)

Feb 25, 2008 ... In the two Landsat scenes shown above, the pattern of deforestation can be clearly discerned. Deep green in these images shows lush ...

30

Tropical Deforestation : Feature Articles - NASA Earth Observatory  

Science.gov (United States)

Mar 30, 2007 ... Tropical forests are home to half the Earth's species, and their trees are an immense standing reservoir of carbon. Deforestation will have ...

31

Rare Earth Doped Yttrium Aluminum Garnet (YAG ... - GLTRS - NASA  

Science.gov (United States)

films and cylinders of rare earth doped yttrium aluminum garnets. ... We knew that yttrium aluminum garnet (YAG) could be doped with ...

32

ENGLISH R. PD.-SNOW-ICE - The Gateway to Astronaut Photography of ...  

Science.gov (United States)

Jul 26, 2011 ... The Gateway to Astronaut Photography of Earth hosts the best and most complete online collection of astronaut photographs of the Earth.

33

Addt'l. Earth Fill-McMurdo  

Science.gov (United States)

... of this material is, however, outside the currently approved earth fill materials collection area ... fill material suitable for its intended use. The currently approved site contains material that is ...

34

Silylated Co/SBA-15 catalysts for Fischer-Tropsch synthesis  

International Nuclear Information System (INIS)

A series of silylated Co/SBA-15 catalysts were prepared via the reaction of surface Si-OH of SBA-15 with hexamethyldisilazane (HMDS) under anhydrous, vapor-phase conditions, and then characterized by FT-IR, N2 physisorption, TG, XRD, and TPR-MS. The results showed that organic modification led to a silylated SBA-15 surface composed of stable hydrophobic Si-(CH3)3 species even after calcinations and H2 reduction at 673 K. Furthermore, the hydrophobic surface strongly influenced both metal dispersion and reducibility. Compared with non-silylated Co/SBA, Co/S-SBA (impregnation after silylation) showed a high activity, due to the better cobalt reducibility on the hydrophobic support. However, S-Co/SBA (silylation after impregnation) had the lowest FT activity among all the catalysts, due to the lower cobalt reducibility along with the steric hindrance of grafted -Si(CH3)3 for the re-adsorption of ?-olefins. -- Graphical abstract: The silylation of ...

2011-03-01

35

The influence of ground slope to the lightning screen failure of high voltage transmission lines  

Energy Technology Data Exchange (ETDEWEB)

The electrogeometric model cannot consider the influence of some parameters on the screening of the wire conductor of the H.V. lines. For analysing the influence of these parameters (the conductor potential, the influence of the distance from phase conductor to earth wire, the influence of the reducing factor of the striking earth distance, the earth slope, etc.), the Monte Carlo method is preferable. The influence of the earth slope on the screening effect of the wire conductor for different conditions is presented in this paper. (author)

1999-07-01

36

Population and Global Warming  

Science.gov (United States)

Description of how global warming could be disastrous for much of the earth's population....

38

Geoengineering the Earth's Climate  

ScienceCinema

...global warming situation is more than evaporation around ...background red ? which was the global warming the ...

40

Synthesis and characterization of Co-Ag core-shell nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

A micellar method has been used to prepare silver-coated cobalt (Co-Ag) nanoparticles. The synthesized particles have been deeply characterized by several methods, i.e., XRD, UV-Vis, TEM, XPS, and electrochemical techniques. There is every indication that the obtained particles show a truly core-shell structure. All the nanoparticles obtained under different conditions are in the size range 3-5 nm. High-resolution TEM (HRTEM), Fast Fourier Transformation (FFT), and Selected Area Electron Diffraction (SAED) indicated that the presence of hcp-Co and fcc-Ag, in which cobalt is located in the central area; meanwhile silver is at the edges of the nanoparticle. The absorption band of the Co-Ag colloid shifts to a longer wavelength and broadens relative to that of pure silver colloid. Voltammetric characterization allowed to determine the coverage of the cobalt core.

2010-08-15

41

Surface oxidation of Co2+ and its dependence on ligand coordination number in silica polyamine composites  

British Library Electronic Table of Contents (United Kingdom)

Coordination of CoCl2 solutions to the silica polyamine composite, WP-1, made with the branched polymer polyethylenimine (PEI) shows irreversible binding resulting from surface oxidation of the Co2+-Co3+. This is not the case for the silica polyamine composite BP-1 made with the linear polymer polyallylamine where reversible binding and no oxidation is observed. These observations suggested that oxidation of the cobalt was related to the greater coordination number available with the branched polyamine relative to the linear polyamine. A study of the kinetics of cobalt binding to WP-1 indicated initial loading of Co2+ at relatively low coordination number followed by desorption of Co2+ leading to oxidation and irreversible binding. Exclusion of oxygen from the composite-cobalt solution mix...

2010-01-01

42

Lead, cadmium, chromium, cobalt, and copper in chicken feathers from Tuskegee, Alabama  

Energy Technology Data Exchange (ETDEWEB)

The feather has been widely used as a indicator tissue of metal exposure in birds. The feathers were collected from Tuskegee University poultry farm (TUPF) and Harrison Poultry farm (HPF) chicken and analyzed by Inductively Coupled Plasma Atomic Emission Spectroscopy for lead, cadmium, cobalt, chromium, and copper contaminations. The mean levels of lead, cadmium, cobalt, chromium, and copper in TUPF chicken were 3.67, 0.13, 12.23, 0.22, and 7.71 ppm, respectively, and in HPF chicken were 5.32, 0.096, 11.03, 0.15, and 8.06 ppm, respectively. The mean levels of these metals did not show any significant difference between TUPF and HPF chicken.

1994-12-31

43

Influence of silicon, copper and cobalt on corrosion cracking and pitting corrosion in 03Kh18N30 steel  

International Nuclear Information System (INIS)

The effect of alloying low carbon 18Cr-30Ni steel with silicon (up to 5.1%), copper (up to 5.4%), cobalt (up to 15.3%) on the resistance to corrosion cracking and pitting corrosion, is studied. Tests on uniaxial tension are carried out in 42% MgCl_2 solution and gravimetric studies in 10% FeCl_3x6H_2O. It is established that alloying steel of the Kh18N30 type with silicon increases strength and resistance to corrosion cracking. Copper and cobalt decrease a resistance to pitting corrosion but somewhat increase a resistance to corrosion cracking.

44

Development of a stable cobalt-ruthenium Fischer-Tropsch catalyst. Technical progress report No. 17, 1 November 1993--31 December 1993  

Energy Technology Data Exchange (ETDEWEB)

Very high cobalt catalysts have been prepared on steamed and acid-washed y zeolite. These catalysts are very active. Some of them have proven to be very stable. Additionally, if provisions are made to control the temperature build up on the catalyst bed, low methane selectivities result. Additional work is indicated, for instance, perhaps even higher activity catalysts can result from higher levels of cobalt or changes in the catalyst preparation procedure. Since the issue of whether small amounts of ruthenium can promote the catalyst is not completely resolved, catalyst preparation procedure experiments should continue with ruthenium vs. ruthenium-free catalysts. For instance, different methods of impregnation and/or activation should be investigated.

1994-06-01

45

Determination of some minor and trace elements in iron ores by ion exchange chromatography, spectrophotometry and atomic absorption spectrometry  

International Nuclear Information System (INIS)

A method is described for determination of aluminium, cadmium, cobalt, chromium, copper, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, zinc, titanium and vanadium in iron ore. After dissolution, a 1 gram sample of iron ore is applied to a column of AGI-X8 anion exchange resin (chloride form), in 100 ml of 7M HCl. Aluminium, chromium, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, titanium and vanadium are eluted with 7M HCl; iron, copper and cobalt are eluted with 0.5M HCl; cadmium and zinc are eluted with 2M HNO_3. Iron is subsequently removed from copper and cobalt by a solvent extraction with methyl isobutyl ketone. The elements are determined in the eluates by atomic absorption spectrometry, except for titanium and vanadium, which are determined spectrophotometrically.

46

Catalytic desulfurization of organic sulfur compounds over zeolite catalysts  

Energy Technology Data Exchange (ETDEWEB)

In the dehydrodesulfurization of ethanethiol at 400/sup 0/C, the activities of sodium X, Y, and A zeolites decreased in the order given as did the activities of nickel, cobalt, zinc, cadmium, copper, silver, lead, manganese, barium, calcium, sodium, and iron Y zeolite catalysts. A volcano-shape order was observed between the catalytic activity and the electronegativity of the metal ions. The changes in the activity of hydrogen Y zeolite catalyst in ethanethiol dehydrodesulfurization and cumene dealkylation by calcination agreed with the decrease in the Broensted acidity but were independent of Lewis acidity. For hydrodesulfurization of thiophene, the activities of nickel, cobalt, copper, and silver Y zeolite catalysts decreased in the order given and were greater than for a commercial hydrodesulfurization catalyst; reduced and presulfided catalysts showed selective hydrodesulfurization activity. Addition of 5% of nickel or molybdenum oxides to ...

1980-01-01

47

Red mud as a catalyst for coal liquefaction  

Energy Technology Data Exchange (ETDEWEB)

In order to replace industrial cobalt and nickel and molybdenum catalysts, more economical catalysts, red muds, are used. Comparative data about the chemical, structural and thermal properties of different samples of red muds, which are important for catalytic hydrogenation, are cited. The different conditions for hydrogenation of coals in a reactor are examined.

1983-01-01

48

Labelling of bleomycin with cobalt-57, indium-111, technetium-99m, mercury-197, lead-203, and copper-67  

International Nuclear Information System (INIS)

The radiochemical purity of the cobalt-57 complex of bleomycin could be enhanced by adjusting the pH of the final product to a value between 5 and 6. This radiopharmaceutical appeared to have better tumor visualizing properties compared to the not neutralized preparation. The clinical use of the cobalt-57 bleomycin complex is however limited by the long physical half-life of the label, causing a risk of radioactive contamination. It appeared to be possible to label bleomycin with radioactive cations ("1"1"1In"3"+, sup(99m)Tc"4"+, "1"9"7Hg"2"+ and "6"7Cu"2"+) having suitable gamma ray energies and short half-lifes. These bleomycin complexes showed a high radiochemical purity judged by their behaviour on thin layer chromatography, paper chromatography, and electrophoresis, but their application as tumor visualizing radiopharmaceutical turned out to be disappointing compared with cobalt-57 bleomycin. (orig.).

49

Interrelationships in trace-element metabolism in metal toxicities in a cobalt-resistant strain of Neurospora crassa  

UK PubMed Central (United Kingdom)

A strain of Neurospora crassa was isolated by training the mould to grow on media containing high concentrations of Co2+. This strain, the CoR strain, exhibited...Full Text Available

1973-04-01

50

Development of surface decontamination technology for radioactive waste using plasma. Summary of decontamination performance in dry surface decontamination technology with low-pressure arc plasma  

International Nuclear Information System (INIS)

Various kinds of decontaminations are carried out in atomic power plant. Here current decontamination technologies such as chemical decontamination with chemical solution or blast decontamination have a problem of reduction of secondary radioactive waste generated in the decontamination process. On the other hand, a low pressure arc plasma can remove metal oxide film on the metal substrate without heavy damage on the metal substrate when the object to be treated was set as a cathode. Dry surface decontamination technology with using low-pressure arc plasma can decrease secondary radioactive waste because low-pressure arc plasma does not need any chemical solution. In addition, the time required for treatment can be shorter, so it is possible for the low-pressure arc plasma decontamination technology to interpolate the current decontamination technologies such as spot decontamination technology etc. Therefore we have been investigating the dependence of removal of metal oxide film on ...

2008-12-01

51

the earth observer - Earth Observing System - NASA  

Science.gov (United States)

of satellite, aircraft and ground-based observations. In ..... swarm traps by Utah Department of Food and Agriculture (DAF) personnel. Preliminary Results ..... the 150th anniversary of the book's publication and the 200th anniversary of Darwin's birth. ...... cold war submarine missions to find that Arctic Ocean ...

52

Reuse Working Group - Earth Science Data Systems Working Groups - NASA  

Science.gov (United States)

Al Fleig, PITA Analytic Sciences. 7th Earth Science Data Systems Working Group Meeting ..... The Reuse Industry in Brazil, CESAR, and the Reuse in Software ...

53

Mean distance of closest approach of alkaline-earth metals ions in aqueous solutions: Experimental and theoretical calculations  

British Library Electronic Table of Contents (United Kingdom)

The estimation of numerical values of the mean distance of closest approach of ions, a, of alkaline-earth metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.

2010-01-01

54

Host Your Own Tweetup! Sun-Earth Day 2011 - Sun-Earth Day - NASA  

Science.gov (United States)

(Like using solar cookers to make hot dogs! Yummm!) How many people do you want to attend? 5? 30? 200?!? (Ambitious aren't we?) ...

55

FAQ: Earthquakes, Faults, Plate Tectonics, Earth Structure  

Science.gov (United States)

This frequently-asked-questions feature provides answers about earthquakes, faults, plate tectonics, and earth structure. Maps and diagrams are provided with some answers, and links to additional information and to related topics are included.

56

Earth Resources NASA SP-7041 (18) - NASA Technical Reports Server  

Science.gov (United States)

The Grover S and X-band dual-wavelength radar system has been ...... A. H. Watkins (U.S. Geological Survey, Earth Resources. Observation Systems Data Center ...

57

Do energetic heavy nuclei penetrate deeply into Earth's atmosphere?  

UK PubMed Central (United Kingdom)

We calculate the expected fluxes of cosmic ray nuclei with charge 5 ≤ Z ≤ 28 at various depths in the earth's atmosphere, taking into account the initial charge distribution,...Full Text Available

1980-01-01

58

Recovery of rare earths from red mud  

International Nuclear Information System (INIS)

The prospect for the recovery of rare earths from red mud, the bauxite tailings from the production of alumina is examined. The Jamaican red mud by far has the higher trace concentrations of lanthanum, cerium, neodymium, and yttrium. Scandium is also present. The dissolution of the rare earth is a major extraction problem because of the large volume of other materials. The recovery processes that have been proposed include the production of co-products such as iron, alumina, and titanium concentrates, with the rare earths going with the titanium. In this paper a critical examination of the possible processes are presented with the recommended research projects to be carried out.

1992-03-01

59

Moment of inertia calculations for some even-even rare earth nuclei  

International Nuclear Information System (INIS)

... angular momentum cranking model even-even nuclei gadolinium 156 governor

60

Glory Mission Overview  

National Aeronautics and Space Administration (NASA)

NASA's Glory spacecraft is equipped to survey and map aerosols in Earth's atmosphere during a mission marking the return to flight of the Taurus XL rocket.

2011-02-22

61

A small particle selective emitter for thermophotovoltaic energy conversion  

Energy Technology Data Exchange (ETDEWEB)

This paper presents an analysis of the performance of a selective emitter using small particles of rare earth compounds stable at high temperatures in a low emittance inert gas stream. An expression for the spectral emissive power excluding radiation scattering was derived to include the radiation in the emission band, produced by electronic transitions of the rare earth ion, and the continuum radiation outside the emission band produced by the rare earth host. Preliminary results suggest that a selective emitter based on suspended rare earth oxide particles will have high efficiency and merits further experimental investigation. {copyright} {ital 1996 American Institute of Physics.}

1996-02-01

62

25th Space Simulation Conference. Environmental Testing: The Earth-Space Connection  

Science.gov (United States)

Topics covered include: Methods of Helium Injection and Removal for Heat Transfer Augmentation; The

2008-01-01

63

The rare earth antimonates: spectroscopic properties, crystal field and paramagnetic susceptibility simulations  

International Nuclear Information System (INIS)

The rare earth antimonates RE_3Sb_5O_1_2 constitute an isostructural series, where the rare earth site symmetry is S_4. The spectroscopic properties of pure or doped compounds of this family are studied in order to derive their energy level schemes and to simulate them through the crystal field theory, by using the approximated D_2_d potential. The paramagnetic susceptibilities are calculated with the derived wavefunctions and compared to experiment.

1990-09-01

64

Energy transfer processes in rare-earth compounds  

International Nuclear Information System (INIS)

In this thesis the results are described of an investigation into the radiationless transfer of electronic excitation energies in various Eu"3"+ and Tb"3"+ compounds, which show structural peculiarities in the rare-earth sublattice. These peculiarities are an one-dimensional sublattice as well as two different crystallographic locations for the rare-earth ion. 154 refs.; 43 figs.; 12 tabs.

1999-01-01

65

Earth Matter Effects in Detection of Supernova Neutrinos  

CERN Document Server

We calculated the matter effect, including both the Earth and supernova, on the detection of neutrinos from type II supernovae at the proposed Daya Bay reactor neutrino experiment. It is found that apart from the dependence on the flip probability P_H inside the supernova and the mass hierarchy of neutrinos, the amount of the Earth matter effect depends on the direction of the incoming supernova neutrinos, and reaches the biggest value when the incident angle of neutrinos is around 93^\\circ. In the reaction channel \\bar{\

2006-01-01

66

In vitro percutaneous absorption of metal compounds.  

Science.gov (United States)

It is well known that contact with metals can be responsible for allergic contact dermatitis; also, there is experimental evidence that nickel ions are readily available on the surface of used coins containing nickel and copper. The aim of this study was to prove that metal powders of nickel (Ni), cobalt (Co) and chromium (Cr) dispersed in synthetic sweat are oxidised into respective ions that can permeate the skin. Suspensions of 5 g of metal powder (Ni, Co and Cr) in 100 mL of synthetic sweat at pH 6.5 were prepared and shaken with a stirring plate at room temperature for 30 min. Human skin membranes were set up in Franz-diffusion cells and 2 mL of the freshly made suspension were applied to the outer surface of the skin for 24h. The appearance of metal ions in the aqueous receptor phase (NaCl 0.9%) was quantified by Electro Thermal Atomic Absorption Spectroscopy (ETAAS). Also, metals ions were analysed using Differential Pulse Polarography (DDP), Differential ...

2007-02-23

67

Treatment of a waste salt delivered from an electrorefining process by an oxidative precipitation of the rare earth elements  

British Library Electronic Table of Contents (United Kingdom)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two sha...

2009-01-01

68

The sorption recovery of rare earth elements, yttrium and aluminium from the red mud  

International Nuclear Information System (INIS)

The extraction of rare earth elements, yttrium and aluminium from red mud resulting from alumina production with the ion-exchange resin KU-2-8n was studied. Experimental results are presented. The technology of hydrometallurgical processing of pulps obtained by sorption extraction of scandium from red mud is developed. It is shown that in the process of precipitation from sulfate sulfuric acid desorbate it became possible to obtain a high degree of rare earths deposition. The use of sodium hydroxide makes it possible to obtain a maximum deposition of rare earths and aluminium - 99.9 %. Aluminium leaching from crude composite concentrate gives a possibility to get concentrates which 15 - 20 times richer in yttrium and rare earths

2002-08-01

69

Galactic Cosmic Rays - Clouds Effect and Bifurcation Model of the Earth Global Climate. Part 1. Theory  

CERN Document Server

The possible physical linkage between galactic cosmic rays intensity and the Earth's cloud cover is discussed using the analysis of the first indirect aerosol effect (Twomey effect) and its experimental representation as the dependence of average cloud droplet effective radius on aerosol index characterizing the aerosol concentration in the atmospheric air column of unit section. It is shown that the basic kinetic equation of the Earth's climate energy-balance model is described by the bifurcation equation (with respect to the temperature of the Earth's surface) in the form of fold catastrophe with two governing parameters defining the variations of insolation and Earth's magnetic field (or galactic cosmic rays intensity in the atmosphere), respectively. The principle of hierarchical climatic models construction, which consists in the structural invariance of balance equations of these models evolving ...

2008-01-01

70

Treatment of a waste salt delivered from an electrorefining process by an oxidative precipitation of the rare earth elements  

Energy Technology Data Exchange (ETDEWEB)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO{sub 2}, PrO{sub 2}), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of ...

2009-02-28

71

Treatment of a waste salt delivered from an electrorefining process by an oxidative precipitation of the rare earth elements  

International Nuclear Information System (INIS)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare ...

2009-02-28

72

Study on a recovery of rare earth oxides from a LiCl-KCl-RECl3 system  

British Library Electronic Table of Contents (United Kingdom)

Radioactive rare earth chlorides in waste LiCl-KCl molten salts have to be separated as a stable form to minimize waste volume and to achieve stable solidification. In this work, thermal behavior of rare earth chlorides (CeCl3, GdCl3, NdCl3, PrCl3) was investigated in an oxygen condition to recover rare earth oxides from a LiCl-KCl-RECl3 system. The rare earth chlorides in the LiCl-KCl molten salts were smoothly converted to an oxychloride form at a higher temperature than 650degreeC, except for CeCl3. CeCl3 was totally converted to an oxide from at a higher temperature than 450degreeC. The rare earth oxychlorides (GdOCl, NdOCl, PrOCl) were effectively converted to oxide forms at a higher temperature than 1100degreeC. It was confirmed that rare earth oxides can be recovered from a LiCl-KCl...

2011-01-01

73

Investigation of the evaporation of rare earth chlorides in a LiCl-KCl molten salt  

International Nuclear Information System (INIS)

Uranium dendrites which were deposited at a solid cathode of an electrorefiner contained a certain amount of salts. These salts should be removed for the recovery of pure metal using a cathode processor. In the uranium deposits from the electrorefining process, there are actinide chlorides and rare earth chlorides in addition to uranium chloride in the LiCl-KCl eutectic salt. The evaporation behaviors of the actinides and rare earth chlorides in the salts should be investigated for the removal of salts in the deposits. Experiments on the salt evaporation of rare earth chlorides in a LiCl-KCl eutectic salt were carried out. Though the vapor pressures of the rare earth chlorides were lower than those of the LiCl and KCl, the rare earth chlorides were co-evaporized with the LiCl-KCl eutectic salt. The Hertz-Langmuir relation was applied for this evaporation, and also the evaporation ...

2011-02-01

74

A ~5 M_earth Super-Earth Orbiting GJ 436?: The Power of Near-Grazing Transits  

CERN Document Server

Most of the presently identified exoplanets have masses similar to that of Jupiter and therefore are assumed to be gaseous objects. With the ever-increasing interest in discovering lower-mass planets, several of the so-called super-Earths (i.e., with masses in the interval 1 M_earth < M < 10 M_earth), which are predicted to be rocky, have already been found. Here we report the possible discovery of a planet around the M-type star GJ 436 with a minimum mass of 4.8+/-0.6 M_earth and a true mass of ~5 M_earth, which makes it the least massive planet around a main-sequence star found to date. In contrast with other discoveries, the planet is identified from its perturbations on an inner Neptune-mass transiting planet (GJ 436b), by pumping eccentricity and producing secular variations in the orbital inclination. Analysis of published radial velocity measurements indeed reveals a ...

2008-01-01

75

Synthesis and electrochemical performance of carbon nanofiber-cobalt oxide composites  

Energy Technology Data Exchange (ETDEWEB)

Carbon nanofiber (CNF) supported cobalt oxide composites as high-capacity anode materials were prepared through a facile, effective method for potential use in rechargeable lithium-ion batteries. The effects of the calcining temperature on the crystallinity, grain size, specific surface area of Co{sub 3}O{sub 4} and phase transformation from Co{sub 3}O{sub 4} to CoO were studied in detail. Both the specific surface area and CNF content in CNF-cobalt oxide composites strongly affect the electrochemical performance of these series composites. The CNF-Co{sub 3}O{sub 4} composite with 24.3% CNF pyrolyzed at 500 deg. C in Ar shows an excellent cycling performance, retaining a specific capacity of 881 mAh g{sup -1} beyond 100 cycles. Homogeneous deposition and distribution of nanosized Co{sub 3}O{sub 4} particles on the surface of CNF can stabilize the electronic and ionic conductivity as well as the morphology of Co{sub 3}O{sub 4} phase, which may ...

2008-10-15

76

Synthesis and electrochemical performance of carbon nanofiber-cobalt oxide composites  

Energy Technology Data Exchange (ETDEWEB)

Carbon nanofiber (CNF) supported cobalt oxide composites as high-capacity anode materials were prepared through a facile, effective method for potential use in rechargeable lithium-ion batteries. The effects of the calcining temperature on the crystallinity, grain size, specific surface area of Co{sub 3}O{sub 4} and phase transformation from Co{sub 3}O{sub 4} to CoO were studied in detail. Both the specific surface area and CNF content in CNF-cobalt oxide composites strongly affect the electrochemical performance of these series composites. The CNF-Co{sub 3}O{sub 4} composite with 24.3% CNF pyrolyzed at 500{sup o}C in Ar shows an excellent cycling performance, retaining a specific capacity of 881 mAh g{sup -1} beyond 100 cycles. Homogeneous deposition and distribution of nanosized Co{sub 3}O{sub 4} particles on the surface of CNF can stabilize the electronic and ionic conductivity as well as the morphology of Co{sub 3}O{sub 4} phase, which may ...

2008-10-15

77

Radiological safety aspects associated with the handling, storage and disposal of self power neutron detectors in TAPS - 3 and 4  

International Nuclear Information System (INIS)

At Tarapur Atomic Power Station 3 and 4, 540 MWe Pressurised Heavy Water Reactors, core being large in size requires a continuous in core monitoring for local flux disturbances. Nearly 200 Self Powered Neutron Detectors (SPNDs) of the Straight Individually Replaceable (SIR) type are distributed in the reactor core. For purpose of reactor regulation and protection, cobalt SPNDs that have a prompt response for changes in power is used for in-core flux mapping, vanadium SPNDs that provide accurate measure of neutron flux, even though having slow response is used In core SPNDs are placed in Vertical Flux Units (VFU) and Horizontal Flux Units (HFUs). These SPNDs were to be replaced at regular intervals to meet the design intent. Cobalt SPNDs have dose rates of the order of 1000 Gy/h and the Mineral Insulated (MI) cables of Vanadium SPNDs have dose rates of the order of 100 Gy/h. So far 3 Cobalt SPNDs were removed from HFUs and ...

2006-11-13

78

Cobalt, titanium or cerium oxide protective coatings for the nickel cathode of the molten carbonate fuel cells; Revetements protecteurs a base d'oxyde de cobalt, de titane ou de cerium pour la cathode de nickel des piles a combustible a carbonates fondus  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to combine the MCFC cathode Li{sub x}Ni{sub 1-x}O properties to those of the protective coatings of LiCoO{sub 2}, Li{sub 2}TiO{sub 3} or of CeO{sub 2}, less soluble in the molten carbonates. In the cases of LiCoO{sub 2}, have been carried out by controlled potential coulometry in aqueous solution, a deposition of Co{sub 3}O{sub 4} on dense Ni. The cobalt oxide reacts rapidly in the Li{sub 2}CO{sub 3}-Na{sub 2}CO{sub 3} medium at 650 C to give LiCoO{sub 2}, a spinel cubic phase revealed by Raman spectroscopy. (O.M.)

2003-10-15

79

Self-diffusion of silicon in thin films of cobalt, nickel, palladium and platinum silicides  

International Nuclear Information System (INIS)

Radioactive "3"1Si was used as a tracer to study silicon self-diffusion in thin film silicides of cobalt, nickel, palladium and platinum. The specimens were prepared by sequential electron beam evaporation of radioactive "3"1Si and of the metal onto cleaned silicon wafers. By vacuum annealing at the appropriate formation temperature a silicide about 250 nm thick containing a sharp radioactive band about 50 nm thick was generally formed. Subsequent heating above the formation temperature resulted in a spreading of the activity owing to silicon self-diffusion. Activity profiles in the silicides were measured by a combination of ion beam sputtering, radioactivity counting and Rutherford backscattering of charged nuclear particles. (orig.).

80

Oxidation/sulfidation of material candidates for distributed solar receiver thermochemical transport program in SO/sub 2//O/sub 2/  

Energy Technology Data Exchange (ETDEWEB)

Metals for potential use in the dissociator and the synthesizer reactors of a distributed solar receiver thermochemical transport loop utilizing SO/sub 3//SO/sub 2//O/sub 2/ molecular chemistry were tested in SO/sub 2//O/sub 2/ mixtures at 500/sup 0/C and 900/sup 0/C, respectively, for times of up to four weeks. They included titanium, aluminum and nickel, and iron-base, nickel-base and cobalt-base superalloys. Weight gain measurements determine the oxidation/sulfidation kinetics. Electron microprobe analysis identifies any possible penetration of oxygen and sulfur into the metal and the formation of internal oxides and sulfides. The most promising candidates as a result of these tests are the cobalt-base superalloys.

1985-06-01

81

Microstructural changes of stearic acid films by immersion in salt solution  

Energy Technology Data Exchange (ETDEWEB)

X-Ray reflectivity has been used to investigate the microstructural changes of solution-cast stearic acid films before and after immersion in CoCl{sub 2} solutions. Before immersion, the films possess a well-defined layered structure with an interlayer spacing of 4.01{+-}0.05 nm. After the films were immersed in the CoCl{sub 2} solutions, a new set of equidistant diffraction peaks emerge, the corresponding interlayer spacing of which is 5.13{+-}0.05 nm. The X-ray photoelectron spectra of the films indicate the existence of cobalt ions inside the films after immersion. It is concluded that the permeation of the cobalt ions into the hydrophilic interlayer causes the stearic acid molecules to reorient perpendicular to the films, resulting in the increase of interlayer spacing and the roughening of the interfaces.

2003-11-01

82

Elasto-plastic analysis of settlement of pile foundations. Part 2. ; Prediction of immediate settlement of building. Kui kiso no dansosei chinka kaiseki. 2. ; Kenchikubutsu no sokuji chinka yosoku hoho  

Energy Technology Data Exchange (ETDEWEB)

When the foundations of the building are designed and worked, the prediction calculation of immediate settlement of the building exercised practically is to calculate assuming the earth is a linear elastic body, but the actual stress-strain relationship of the earth is nonlinear and rigidity of the earth becomes lower as strain (or stress) increases. Hence in order to grasp the actual settling behavior of the earth, it is necessary to elucidate the nonlinear relationship between stress and strain. In this article, a prediction method of building settlement is introduced which uses an analytical technique of the multi-layered earth by the linear elasticity theory and takes into consideration strain dependency of rigidity of the earth. Part of the conclusion is as follows which has been obtained by studying the settling behaviors observed in examples of vertical ...

1992-12-25

83

The rare earth antimonates: spectroscopic properties, crystal field and paramagnetic susceptibility simulations  

Energy Technology Data Exchange (ETDEWEB)

The rare earth antimonates RE{sub 3}Sb{sub 5}O{sub 12} constitute an isostructural series, where the rare earth site symmetry is S{sub 4}. The spectroscopic properties of pure or doped compounds of this family are studied in order to derive their energy level schemes and to simulate them through the crystal field theory, by using the approximated D{sub 2d} potential. The paramagnetic susceptibilities are calculated with the derived wavefunctions and compared to experiment.

1991-01-01

84

NMR at earth's magnetic field using para-hydrogen induced polarization  

British Library Electronic Table of Contents (United Kingdom)

A method to achieve NMR of dilute samples in the earth's magnetic field by applying para-hydrogen induced polarization is presented. Maximum achievable polarization enhancements were calculated by numerically simulating the experiment and compared to the experimental results and to the thermal equilibrium in the earth's magnetic field. Simultaneous 19F and 1H NMR detection on a sub-milliliter sample of a fluorinated alkyne at millimolar concentration (1018 nuclear spins) was realized with just one single scan. A highly resolved spectrum with a signal/noise ratio higher than 50:1 was obtained without using an auxiliary magnet or any form of radio frequency shielding.

2011-01-01

85

Chiral crystallization and the origin of chiral life on earth  

British Library Electronic Table of Contents (United Kingdom)

Abstract The creation of chirality on Earth and the development of chiral life have been discussed in this highlight. Convincing evidence for the introduction of chirality on Earth is still fragmentary. We believe that by a combination of chiral crystallization and formation of helical polymers with preferred chiral conformational structure is the key to this question. This concept of macromolecular asymmetry has inspired ideas and resulted in possible rules for how chiral life as we know it, could have been introduced. These investigations needed the understanding of the requirements for chiral crystallization, for the stereochemistry of the initial formation of helical polymers, the measurements of optical activity of solids and their coordination with the fundamentals of chirality. Spac...

2011-01-01

86

Worldwide Report, Telecommunications Policy, Research and ...  

Science.gov (United States)

... 80 Briefs New Television Transmitter 81 Matadi Satellite Earth Station Inaugurated (Kinshasa AZAP, various dates) 82 Ramazani Marks Opening ...

1985-12-31

87

Viscosity of the Earth's inner core: Constraints from nutation observations  

British Library Electronic Table of Contents (United Kingdom)

The gravitational torque applied on the Earth by the other celestial bodies generates periodic variations in the orientation of the Earth's rotation axis in space which are called nutations. Observations of Earth's nutations allow for insights into the physical properties of the inner core because of the presence of a normal mode, the Free Inner Core Nutation (FICN), which is characterized by a tilt of the inner core figure and rotation axes with respect to the mantle and outer core. The frequency of the FICN is controlled by the strength of the mechanical coupling acting at the inner core boundary (ICB) and by the ability of the inner core to deform under the action of centrifugal and gravitational forces. Attenuation of the FICN reflects energy dissipated by electromagnetic (EM) and visc...

2011-01-01

88

View larger image for ISS022-E-26137 - Earth Sciences and Image ...  

Science.gov (United States)

The Asarco-Mission complex (image left) is an active producer of copper and molybdenum (important in making steel and other metal alloys), ...

89

VOLUME I11 IMISSION SYSTEM PERFORMANCE - NASA Technical Report ...  

Science.gov (United States)

Nov 8, 2010 ... Ihring Mission 11, the radiation dosimetry measurement system functioned normally and provided data on the Earth's trapped radiation belts ...

90

Typhoon Aere : Image of the Day - NASA Earth Observatory  

Science.gov (United States)

Aug 25, 2004 ... The Tropical Rainfall Measuring Mission or TRMM satellite provided this image of Typhoon Aere over the western Philippine Sea as it was ...

91

Treatment of LiCl-KCl eutectic waste salt delivered from pyroprocessing of spent oxide fuel  

Energy Technology Data Exchange (ETDEWEB)

An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements.

2008-08-15

92

Treatment of LiCl-KCl eutectic waste salt delivered from pyroprocessing of spent oxide fuel  

International Nuclear Information System (INIS)

An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements

2008-08-01

93

The Shifty Nature of Grains  

Science.gov (United States)

... Astronomy & Space Biology Chemistry & Materials Computing Earth & Environment Education ... Materials Research Center at the University of Chicago, one of nearly 30 NSF-supported Materials ...

94

TIGER in Antarctica - Q&A - Misc. Antarctic Topics - NASA  

Science.gov (United States)

Jan 5, 2004 ... Even if dinosaurs were cold-blooded, in the Mesozoic Era (when dinosaurs roamed the Earth), Antarctica was warm enough to have them. ...

95

Science Directed Spacecraft Autonomy for Mars Missions - detail  

Science.gov (United States)

The rapidly growing field of remote sensing is beginning to supply massive amounts of high resolution imagery of the earth and other planets. ...

96

STS067-703D-090 Kinshasa ... - Earth from Space - Image Information  

Science.gov (United States)

... rivers of the world, the Zaire is not an efficient transportation link because of many rapids and falls to negotiate between Kinshasa and the port city of Matadi. ...

97

Rio Negro Floodplain, Patagonia, Argentina - NASA Earth Observatory  

Science.gov (United States)

Feb 15, 2010 ... This astronaut photo from January 4, 2010, shows meander scars and oxbow lakes in the floodplain of the Rio Negro in South America.

98

Remarks of Obama on space exploration in 21st century  

Science.gov (United States)

Apr 22, 2010 ... I believe that space exploration is not a ... plan for space exploration, especially in .... space exploration beyond low Earth orbit. ...

99

Regulators to Vote on Ocean Trawling Plan : News - NASA Earth ...  

Science.gov (United States)

Federal regulators were set to vote on a plan to protect deep water corals and other sensitive fish habitats that will likely include a permanent ban on ...

100

Preliminary representation of world population by spherical harmonics.  

UK PubMed Central (United Kingdom)

The geographical arrangement of people on the surface of the earth is approximated by a mathematical equation of 361 terms. This is a convenient form for comparison with other distributions and for...Full Text Available

1992-07-15

101

Optimal haulage routing of off-road dump trucks in construction and mining sites using Google Earth and a modified least-cost path algorithm  

British Library Electronic Table of Contents (United Kingdom)

This study presents new software, called Google Earth-based Optimal HAulage RouTing System (GEOHARTS), to improve the functionality of Google Earth for optimal haulage routing of off-road dump trucks in construction and mining sites. A modified least-cost path algorithm, which is applicable to working areas with both paved and unpaved temporary roads and can consider the effects of terrain relief and curves along a route on the route planning, was proposed and utilized for the software development. GEOHARTS can determine optimal haulage routes between loaders and dumps that ensure the least travel time or fuel consumption of off-road dump trucks and can visualize the results using an embedded 3D render window of Google Earth. The application to the Pasir open-pit coal mine in Indonesia dem...

2011-01-01

103

News - NASA Earth Observatory  

Science.gov (United States)

Satellite Observations of the Southeast Pacific Intertropical Convergence Zone During 1993-1998, Halpern, D.; Hung, C.-W., Journal of Geophysical Research ? ...

104

New remote sensing techniques for the detection and quantification of earth surface CO2 degassing  

British Library Electronic Table of Contents (United Kingdom)

Earth degassing specifically of carbon dioxide CO2 is of increasing interest with respect to the global carbon budget, related climate effects, earthquake and volcano eruption mechanisms, as well as plant physiological reactions in gas-rich environments. Investigations in all of these disciplines require the detection of surface CO2 degassing structures and quantification of their emissions. We introduce minimal thermal change detection based on infrared imaging as a new remote sensing tool for the detection of earth surface thermal anomalies suiting among others to discover earth degassing locations of any origin. The method allows for seamless areal search and monitoring of degassing structures in any terrain. As proof of concept infrared imaging measurements were performed at the Bossol...

2008-01-01

105

NASA's Next Major Space Observatory - Flight Projects - NASA  

Science.gov (United States)

of Earth Science data and information management capabilities. Dale Schulz/400 . For your exceptional achievement in leading the joint LaRC/GSFC team in ...

106

Impact of Ionospheric Scintillations on Space-Based ...  

Science.gov (United States)

... Zinn, J., Hoerlin, H., and Petschek, AG, "The Motion of Bomb Debris Follow- ing the Starfish Test," Radiation Trapped in the Earth's Magnetic Field ...

1991-06-01

107

ISS020-E-9861 - The Gateway to Astronaut Photography of Earth  

Science.gov (United States)

The portion of the Waterpocket Fold illustrated in this image includes layered rocks formed during the Mesozoic Era (~ 250 65 million years ago) the oldest ...

108

General Disclaimer One or more of the Following Statements may ...  

Science.gov (United States)

Hie synthesis of diverse biologically important compounds, under condi- tions which existed on the earth in the initial period of its evolution, ha; ...

109

GLYDER - Earth Science Technology Office (ESTO) - NASA  

Science.gov (United States)

goals for multisensor co-registration and fusion. 6 - 12.5 Km ..... Beta-Test toolkit for cyclogenesis and early evolution of cyclones ...

110

Five Special Types of Orbits Around Mars  

CERN Document Server

The abstract is additional with repect to the paper published in JGCD. Ordinary Earth satellites are usually placed into five categories of special orbits: sun-synchronous orbits, orbits at the critical inclination, frozen orbits, repeating ground track orbits, and geostationary orbits. This paper investigates their counterparts around Mars and examines the basic nature of these orbits, which are of special interest for missions conducted around Mars, including Mars reconnaissance. Mars' gravity field is much more complicated, with relatively smaller J2, compared to Earth's, which makes the behaviors of these Martian orbits different from those of Earth. Analytical formulations and numerical simulations are used to analyze these Martian orbits and compare them with their Earth counterparts. First, mean element theory is employed to describe variations of orbital elements and give the constraint ...

2011-01-01

111

Far-out Pathways to Space: Great Guns? - ISTP  

Science.gov (United States)

The SHARP cannon. Hydrogen is compressed in the tube on top, the gun barrel is on bottom. When Jules Verne wrote in 1865 "From Earth to the Moon" he ...

112

Far-out Pathways to Space: Great Guns?  

Science.gov (United States)

Turbine Afterword The SHARP cannon. Hydrogen is compressed in the tube on top, the gun barrel is on bottom. When Jules Verne wrote in 1865 "From Earth to the Moon" he envisioned...

2011-09-03

113

Extraction of rare earths by carbonic acids melts  

Energy Technology Data Exchange (ETDEWEB)

Extraction of rare earths (La, Ce, Pr, Eu, Gd, Er, Yb) from nitrate solutions by melts of carboxylic acids of the C/sub 17/-C/sub 20/ fraction and stearic acid with paraffin, depending on the temperature (60-90 deg), phase contact time and their volume ratio (O:B from 1:5 up to 1:100), pH of the aqueous phase (2-6), rare earth concentration (10/sup -6/-10/sup -3/ m) is studied. It is shown that in the whole concentration range investigated rare earths are extracted quantitatively into the carboxylic acid melt of C/sub 17/-C/sub 20/ fraction at the equilibrium value of pH>=3.8, while into the melt of 0.1 M stearic acid in paraffin at pH>=4.5.

1980-10-01

114

Electric and magnetic dipole transitions in odd-proton rare-earth nuclei  

International Nuclear Information System (INIS)

... gamma cascades kev range 10-100 lifetime lutetium 171 lutetium 173 lutetium

1972-05-01

115

Earthquakes, Hurricanes and Stubborn ... - NASA Earth Observatory  

Science.gov (United States)

Aug 23, 2011 ... Earthquakes, Hurricanes and Stubborn Instruments ... And if earthquakes and stubborn instruments aren't enough, there's this giant hurricane ...

116

Deforestation in Mato Grosso, Brazil - NASA  

Science.gov (United States)

Deforestation in Mato Grosso, Brazil. atom_author. atom_name, Jesse Allen. atom_link. kml_href, http://earthobservatory.nasa.gov/Feeds/GoogleEarth/ ...

117

Deforestation Plays Critical Climate Change Role - NASA Earth ...  

Science.gov (United States)

May 11, 2007 ... "Deforestation in the tropics accounts for nearly 20 per cent of carbon emissions due to human activities," Dr. Canadell says. ...

118

Deep-sea mud in the Pacific Ocean as a potential resource for rare-earth elements  

British Library Electronic Table of Contents (United Kingdom)

World demand for rare-earth elements and the metal yttrium?which are crucial for novel electronic equipment and green-energy technologies?is increasing rapidly. Several types of seafloor sediment harbour high concentrations of these elements. However, seafloor sediments have not been regarded as a rare-earth element and yttrium resource, because data on the spatial distribution of these deposits are insufficient. Here, we report measurements of the elemental composition of over 2,000 seafloor sediments, sampled at depth intervals of around one metre, at 78 sites that cover a large part of the Pacific Ocean. We show that deep-sea mud contains high concentrations of rare-earth elements and yttrium at numerous sites throughout the eastern South and central North Pacific. We estimate that an a...

2011-01-01

119

DEFORESTATION - Earth from Space - Search Results  

Science.gov (United States)

Features: FOREST, DEFORESTATION, RIO JAMARI Geographic Region: BRAZIL .... Features: DEFORESTATION, TIERRAS BAJAS DEFORESTATION Geographic Region: BOLIVIA ...

120

Compact ... - Earth Science Technology Office (ESTO) - NASA  

Science.gov (United States)

switch when this cavity matching condition is determined. This results is a ... MHz offset is provided by an acousto-optic modulator. (AOM). The AOM will be shut ...

121

BARIUM RELEASES at ALTITUDES BET\\VEEN 200 and 1000 - NASA ...  

Science.gov (United States)

Zinn, John;. Hoerlin,. Herman; and Petschek,. Albert. G.: The Motion of Bomb. Debris. Following the Starfish. Test. Radiation. Trapped in the Earth's ...

122

Transfer of chemical elements to breast milk  

International Nuclear Information System (INIS)

The project is intended to yield information on the transfer factors describing the transfer of ingested radionuclides to breast milk for the following elements: antimony, cerium, chromium, cobalt, gallium, lanthanum, molybdenum, niobium, radium, ruthenium, silver, thorium, titanium, and uranium. Those yet unknown or poorly known transfer factors are required in order to be able to develop a reliable model for description and assessment of the transfer of the radionuclides and the possibly resulting hazardous doses to infants, and for subsequent formulation of recommendations for radiological protection of the population. (orig./CB)

1999-08-01

123

The separation and determination of trace elements in iron ore  

International Nuclear Information System (INIS)

The separation, concentration, and determination of trace elements in iron ores are described. After the sample has been dissolved, the iron is separated by liquid-liquid extraction with a liquid cation-exchanger, di-(2-ethylhexyl) phosphoric acid. The trace elements aluminium, cadmium, calcium, chromium, cobalt, copper, lead, magnesium, manganese, mercury, potassium, sodium, vanadium, and zinc are determined in the aqueous phase by atomic-absorption spectrophotometry.

2008-05-01

124

Power MOSFET transistors hardening: way to proceed and characterization  

International Nuclear Information System (INIS)

SGS-Thomson and CNES significantly hardened a power MOSFET transistor against heavy ions and cobalt 60 total dose. The influence of the major technological steps on the component radiation sensitivity has been analyzed. Then the optimization has been carried out, using booth computerized simulation and experimental data. (D.L.). 5 refs., 8 figs.

125

Magnetic properties of FeSi with cobalt impurities  

Energy Technology Data Exchange (ETDEWEB)

Results of experimental researches of impurity level crystals Fe1-xCoxSi are presented in this article. Magnetic properties in a temperature range up to T {<=} 1000 K are analyzed. It was established that with Co impurities increasing origin of magnetic ordering exists at low temperatures. At high temperatures a high temperature maximum of susceptibility of nominally pure iron monosilicide crystal is observed.

2010-01-01

126

Decree of the Ministry of Health about conditions of irradiation of food, permissible additional substances or other food components, which can be subjected to ionizing radiation action, their specification, maximum irradiation doses as well as about requirements for marking and introducing into turnover  

International Nuclear Information System (INIS)

The decree refers to conditions of irradiation of food and its components for radappertization and radurization using gamma radiation from cobalt 60 or cesium 137, X radiation or electron beam up to maximum total medium absorbed dose 10 kGy.

2003-03-04

127

Study of the {sup 60}Co speciation in the aqueous radioactive waste of the la Hague nuclear reprocessing plant; environmental behaviour after discharges in the waters of the channel; Etude de la speciation du {sup 60}Co dans les effluents de l'usine de retraitement de combustibles irradies de la Hague; devenir apres rejet dans les eaux de la Manche  

Energy Technology Data Exchange (ETDEWEB)

{sup 60}Co is produced as an activation product and is present in the low-level aqueous radioactive waste released from the La Hague plant. At present, the concentration in the sea (non filtered at 0.45 {mu}m) at the Goury site are close to or even below, the detection limit: 0.2 mBq.l{sup -1}. The {sup 60}Co speciation depends on the type of effluent considered: in the effluent A ('active'), the cobalt is in the form of a stable trivalent complex; in the effluent V (to be checked), the cobalt is in majority (50% of the activity release) in the form of particles (>0.45 {mu}m), and then in the form of two soluble species: ionic divalent (Co{sup 2+}) and some stable complexes. The evolution of the reprocessing techniques used does not affect the speciation. So, since the nuclear reprocessing plant started at the La Hague plant in 1966, the chemical species discharged in the sea shows time variation related to the ...

1999-07-01

128

Supernova Neutrinos Detection On Earth  

CERN Document Server

In this paper, we first discuss the detection of supernova neutrino on Earth. Then we propose a possible method to acquire information about $\\theta_{13}$ smaller than $1.5^\\circ$ by detecting the ratio of the event numbers of different flavor supernova neutrinos. Such an sensitivity cannot yet be achieved by the Daya Bay reactor neutrino experiment.

2009-01-01

129

Radioactive and stable isotope geology  

Energy Technology Data Exchange (ETDEWEB)

Aimed at post-graduate and post-doctoral researchers in geochemistry, this book reflects the rapid changes in the applications of radioactive and stable isotope analysis to a range of geological and geochemical problems. Isotropic chemistry and methods used in mass spectroscopy are discussed initially. The second section deals with radiometric dating methods. The role of isotopes in climate and environmental research is also explored. The book closes with a section on extra-terrestrial matter, geothermometry and the isotopic geochemistry of the Earth`s lithosphere. (UK).

1997-10-01

130

Molar extinction coefficients in aqueous solutions of some alkaline earth chlorides  

International Nuclear Information System (INIS)

Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)

1999-12-21

131

Mineralogy of clay and zeolite dusts (exclusive of 1:1 layer silicates)  

Energy Technology Data Exchange (ETDEWEB)

Clays and zeolites are among the most important of natural dusts by virtue of their occurrence through out the world on the earth`s surface and their important industrial uses. (The 1:1 layer silicates, including the serpentine and kaolin minerals, are not addressed in this chapter.) This chapter provides basic information on a variety of important aspects of each mineral, including crystal structure diagrams of each and references to more detailed discussions. 110 refs., 20 figs.

1993-12-31

132

Magnetic properties of heavy rare-earth tungstates  

International Nuclear Information System (INIS)

Measurement of the magnetic susceptibility of powder samples of heavy rare-earth (Tb, Dy, Ho, Er, Tm and Yb) tungstates have been reported in the temperature range 300 to 900 K. Curie-Weiss law behaviour has been observed for all samples. The Curie constant, paramagnetic Curie temperature and magneton number for the magnetic ions have also been evaluated for each material. (author).

1978-12-01

133

How common are Earths? How common are Jupiters?  

CERN Document Server

Among the billions of planetary systems that fill the Universe, we would like to know how ours fits in. Exoplanet data can already be used to address the question: How common are Jupiters? Here we discuss a simple analysis of recent exoplanet data indicating that Jupiter is a typical massive planet rather than an outlier. A more difficult question to address is: How common are Earths? However, much indirect evidence suggests that wet rocky planets are common.

2002-01-01

134

Earth Sciences Division annual report 1980  

Energy Technology Data Exchange (ETDEWEB)

Summaries of the highlights of programs in the Earth Sciences Division are presented under four headings; Geosciences, Geothermal Energy Development, Nuclear Waste Isolation, and Marine Sciences. Utilizing both basic and applied research in a wide spectrum of topics, these programs are providing results that will be of value in helping to secure the nation's energy future. Separate abstracts have been prepared for each project for inclusion in the Energy Data Base. (DMC)

1981-07-01

135

BUBL LINK: Space observation  

Wastenet

...Observatory Edinburgh SkyView Virtual Observatory Solar System Simulator Space Telescope Science Institute Space Weather : A Research Perspective Subaru Telescope Project Two Micron All ...Universities for Research in Astronomy Subjects: space observation DeweyClass: 522 Resource type: index Space Weather : A Research Perspective Documents discussing space weather , the ...elements of near-Earth space, Earth-space meteorology and practical consequences of space weather . Glossary included. Author: National Academy of ...

136

BUBL LINK: Oceanographic data  

Wastenet

...6 Resource type: reference data Global Change Master Directory An extensive source of information about satellite and in situ Earth science data, with broad coverage of the atmosphere, hydrosphere, oceans, solid earth, and biosphere. Author: NASA Subjects: climatology, global change, oceanographic data DeweyClass: 551.6 Resource type: documents, news International ...

137

A New DC Breaker Used as Metallic Return Transfer Breaker.  

Energy Technology Data Exchange (ETDEWEB)

When a bipolar HVDC transmission system is operating monopolar using the earth as a return path, it is often desired to divert the return current from the earth to the line from the unused pole. To do so requires either that the system be shut down temporarily or that a dc circuit breaker be used. This paper describes the development of such a new dc circuit breaker, and its application on the Pacific Intertie as a Metallic Return Transfer Breaker (MRTB).

1982-10-01

138

A nuclear powered pulsed inductive plasma accelerator as a viable propulsion concept for advanced OTV space applications  

International Nuclear Information System (INIS)

An electric propulsion concept suitable for delivering heavy payloads from low earth orbit (LEO) to high energy earth orbit is proposed. The system consists of a number of pulsed inductive plasma thrusters powered by a 100 kWe space nuclear power system. The pulsed plasma thruster is a relatively simple electrodeless device. It also exhibits adequate conversion to thrust power in the desired I sub sp regime of 1500 to 3000 seconds for optimal payload transfer from low earth to high earth orbit. Because of these features and the fact that the nuclear power unit will be capable of delivering sustained high power levels throughout the duration of any given mission, the system presented appears to be a very promising propulsion candidate for advanced orbital transfer vehicle (OTV) applications. An OTV, which makes use of this propulsion system and which has been designed to lift a 9000-lb payload into ...

139

55 Cancri: Stellar Astrophysical Parameters, a Planet in the Habitable Zone, and Implications for the Radius of a Transiting Super-Earth  

CERN Document Server

The bright star 55 Cancri is known to host five planets, including a transiting super-Earth. The interferometric study presented here yields directly determined values for 55 Cnc's stellar astrophyiscal parameters: $R=0.943 \\pm 0.010 R_{\\odot}$, $T_{\\rm EFF} = 5196 \\pm 24$ K. We use isochrone fitting to determine 55 Cnc's age to be 10.2 $\\pm$ 2.5 Gyr, implying a stellar mass of $0.905 \\pm 0.015 M_{\\odot}$. Our analysis of the location and extent of the system's habitable zone (0.67--1.32 AU) shows that planet f ($M \\sin i = 0.155 M_{Jupiter}$) spends the majority of the duration of its elliptical orbit in the circumstellar habitable zone, where, with moderate greenhouse heating, it could harbor liquid water. Finally, our direct value for 55 Cancri's stellar radius allows for a model-independent calculation of the physical diameter of the transiting super-Earth 55 Cnc e ($\\sim 2.05 \\pm 0.15 R_{\\earth}$), which, ...

2011-01-01

140

Transfer of chemical elements to breast milk; Transfer von Elementen in die Muttermilch  

Energy Technology Data Exchange (ETDEWEB)

The project is intended to yield information on the transfer factors describing the transfer of ingested radionuclides to breast milk for the following elements: antimony, cerium, chromium, cobalt, gallium, lanthanum, molybdenum, niobium, radium, ruthenium, silver, thorium, titanium, and uranium. Those yet unknown or poorly known transfer factors are required in order to be able to develop a reliable model for description and assessment of the transfer of the radionuclides and the possibly resulting hazardous doses to infants, and for subsequent formulation of recommendations for radiological protection of the population. (orig./CB) [German] Ziel des Projektes ist die Ermittlung von Transferfaktoren fuer den Uebergang von Radionukliden aus der Nahrung der Muetter in die Muttermilch fuer die Elemente Antimon, Cer, Chrom, Cobalt, Gallium, Lanthan, Molybdaen, Niob, Radium, Ruthenium, Silber, Thorium, Titan und Uran. Um die Exposition und damit die ...

1999-08-01

141

Synthesis, crystallographic data, solubility and electrokinetic properties of copper-, nickel- and cobalt-uranylphosphate  

Energy Technology Data Exchange (ETDEWEB)

A discussion is given concerning the transformation in acid medium of curite into copper-, nickel- and cobalt-uranylphosphate. From chemical, differential thermal and thermogravimetric analyses, the crystal-chemical formula are calculated as: Cu(UO/sub 2//PO/sub 4/)/sub 2/.8H/sub 2/O, Ni(UO/sub 2//PO/sub 4/)/sub 2/.7H/sub 2/O and Co(UO/sub 2//PO/sub 4/)/sub 2/.7H/sub 2/O. The two last compounds crystallize in the triclinic system with space group P1 or P1(overscore) and the first one crystallizes in the tetragonal system with space group P4/nmm. The cell parameters are calculated. From solubility data, the solubility products are computed as 10sup(-12.8), 10sup(-9.5) and 10sup(-9.9) for the copper-, nickel- and colbalt-compound respectively. The electrokinetic properties of the three species are closely similar to those of natural meta-torbernite: the zeta-potential is negative and the point of zero charge be reached cannot in the pH-range 2 to 9.

1981-01-01

142

Synthesis, crystallographic data, solubility and electrokinetic properties of copper-, nickel- and cobalt-uranylphosphate  

International Nuclear Information System (INIS)

A discussion is given concerning the transformation in acid medium of curite into copper-, nickel- and cobalt-uranylphosphate. From chemical, differentiel thermal and thermogravimetric analyses, the crystal-chemical formula are calculated as: Cu(UO_2/PO_4)_2.8H_2O, Ni(UO_2/PO_4)_2.7H_2O and Co(UO_2/PO_4)_2.7H_2O. The two last compounds crystallize in the triclinic system with space group P1 or P1(overscore) and the first one crystallizes in the tetragonal system with space group P4/nmm. The cell parameters are calculated. From solubility data, the solubility products are computed as 10sup(-12.8), 10sup(-9.5) and 10sup(-9.9) for the copper-, nickel- and colbalt-compound respectively. The electrokinetic properties of the three species are closely similar to those of natural meta-torbernite: the zeta-potential is negative and the point of zero charge be reached cannot in the pH-range 2 to 9.

143

Structure and properties of a novel cobaltate La0.30CoO2  

British Library Electronic Table of Contents (United Kingdom)

The layered cobaltate La0.30CoO2 was prepared from NaxCoO2 precursor by a solid-state ionic exchange and was characterized by means of X-ray and neutron diffraction, magnetic, thermal and electric transport measurements. The compound consists of hexagonal sheets of edge-sharing CoO6 octahedra interleaved by lanthanum monolayers. Compared to Na+ in the parent system, the La3+ ions occupy only one-third of available sites, forming a 2-dimensional superstructure. The deviation from the ideal stoichiometry La1/3CoO2 introduces extra hole carriers into the diamagnetic LS Co3+ matrix making the sample Pauli paramagnetic. The temperature dependence of the electrical conductivity in La0.30CoO2 follows Mott's T?1/3 law up to about 400K, which is in contrast w...

2011-01-01

144

Quinary metallic glass alloys  

Energy Technology Data Exchange (ETDEWEB)

At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic ...

1998-01-01

145

Interaction of cis-diamminediaquoplatinum(II) with adenosylcobalamin and alkylcobalamins  

Energy Technology Data Exchange (ETDEWEB)

The interaction of cis-diamminediaquoplatinum(II) nitrate with adenosylcobalamin and a series of alkylcobalamins was studied by carbon-13 nuclear magnetic resonance spectroscopy and by electronic spectroscopy. With these cobalamins cis-(Pt(NH/sub 3/)/sub 2/(OH/sub 2/)/sub 2/)/sup 2 +/ forms adducts in which N(3) of the 5,6-methylbenzimidazole moiety is co-ordinated to platinum(II) rather than to cobalt(III) of the corrin. The chemical shifts of the 5'-methylene carbon of adenosylcobalamin-platinum adduct and of the Co-methyl carbon of the methylcobalamin-platinum adduct are characteristic of these cobalamins in the base-off form. Furthermore, these cobalamin-platinum complexes have visible spectra identical to those of the cobalamins in acidic solution. The /sup 13/C NMR spectrum of the adenosylcobalamin-platinum complex suggests the presence of a second adduct in which platinum(II) complexes are co-ordinated to both the N(3) of the ...

1980-01-01

146

Chemistry and morphology of coal liquefaction. Quarterly report, January 1-March 30, 1981  

Science.gov (United States)

In the course of observing by means of Auger spectroscopy graphite gasification reactions catalyzed by metals, it has been found that in the presence of hydrogen, nickel appears to diffuse from the surface into the bulk of the graphite. When potassium is deposited on graphite, it is volatilized above 400/sup 0/C. Surprisingly the production of methane and carbon dioxide from the reaction of graphite and steam was catalyzed by potassium at as low a temperature as 250/sup 0/C. It has been shown that literature on the alkylation of benzene with synthesis gas is erroneous and that the products reported are due to Lewis acid catalyzed cracking of benzene. A novel cobalt mediated, reversible cleavage of a vinyl-hydrogen bond has been discovered. All products from the thermal decomposition of tetralin have been identified. The stereochemistry of cis-1, 2 dihydrotetralin was determined. In the utilization of the water gas shift reaction as a reducing agent for model coal ...

1981-03-01

147

Synthesis and characterization of nickel(II), chromium(III), cobalt(II), copper(II), zinc(II), and cadmium(II) complexes with isatin- isonicotinoylhydrazone  

International Nuclear Information System (INIS)

A few metal complexes of isatin-isonicotinoylhydrazone with Ni(II), Cr(III), Co(II), Cu(II), Zn(II) and Cd(II) have been prepared and characterized on the basis of elemental analyses, infrared and electronic spectra as well as "1H NMR spectra, conductivity and magnetic measurements. In view of the results obtained, it has been found that two molecules of isatin-isonicotinoylhydrazone are chelated to the central metal ion as bis-uninegative ONO tridentate ligand forming non-electrolytic octahedral metal complexes. (author)

1997-03-01

148

Studies on radioactive liquid waste treatment by reverse osmosis  

Energy Technology Data Exchange (ETDEWEB)

Reverse osmosis is a simple process and has relatively high decontamination factor compared to other processes used for the treatment of radioactive liquid waste. Furthermore the quantity of secondary waste of this process is small. In this study, test solution containing nine elements such as cesium, strontium, cobalt etc. in chloride forms are treated by reverse osmosis. Permeate rate decreases as the increase of osmotic pressure of feed solution and is expressed by linear equation. Decontamination factor of cations of univalency is more than ten, and about one tenth of that of bivalency. Decontamination factors of all the elements used in this experiment are approximately estimated using the solution-diffusion model.

1982-06-01

149

Studies on radioactive liquid waste treatment by reverse osmosis  

International Nuclear Information System (INIS)

Reverse osmosis is a simple process and has relatively high decontamination factor comparing to other processes used for the treatment of radioactive liquid waste. Furthermore the quantity of secondary waste of this process is small. In this study, test solution containing nine elements such as cesium, strontium, cobalt etc. in chloride forms are treated by reverse osmosis. Permeate rate decreases as the increase of osmotic pressure of feed solution and is expressed by linear equation. Decontamination factor of cations of univalency is more than ten, and about one tenth of that of bivalency. Decontamination factors of all the elements used in this experiment are approximately estimated using the solution-diffusion model. (author).

150

Probable role of trace elements of some medicinal plants in cardio-vascular diseases  

International Nuclear Information System (INIS)

A number of herbal drugs are used in the Unani (Greco-Arab) System of Medicine for cardiovascular diseases. The herbs were analyzed by flame AAS and ICP-AES to determine if their therapeutic actions can be associated with the elements present in them. Cadmium, cobalt, chromium, copper, iron, potassium, magnesium, manganese, sodium, nickel, phosphorus, lead and zinc were some of the elements which play various roles in cardiovascular affections. An effort was made to correlate the role of these elements in cardiac diseases. (Auth.). 2 tabs., 32 refs.

151

Primary explosives  

Energy Technology Data Exchange (ETDEWEB)

The present invention provides a compound of the formula (Cat).sup.+.sub.z[M.sup.++(5-nitro-1H-tetrazolato-N2).sup.-.sub.x(H.sub.2- O).sub.y] where x is 3 or 4, y is 2 or 3, x+y is 6, z is 1 or 2, and M.sup.++ is selected from the group consisting of iron, cobalt, nickel, copper, zinc, chromium, and manganese, and (Cat).sup.+ is selected from the group consisting of ammonium, sodium, potassium, rubidium and cesium. A method of preparing the compound of that formula is also disclosed.

2009-03-03

152

Primary explosives  

Energy Technology Data Exchange (ETDEWEB)

The present invention provides a compound of the formula (Cat).sup.+.sub.z[M.sup.++(5-nitro-1H-tetrazolato-N2).sup.-.sub.x(H.sub.2- O).sub.y] where x is 3 or 4, y is 2 or 3, x+y is 6, z is 1 or 2, and M.sup.++ is selected from the group consisting of iron, cobalt, nickel, copper, zinc, chromium, and manganese, and (Cat).sup.+ is selected from the group consisting of ammonium, sodium, potassium, rubidium and cesium. A method of preparing the compound of that formula is also disclosed.

2011-01-25

153

Phase diagrams  

International Nuclear Information System (INIS)

The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.

154

Non-nitro radiation sensitizers  

International Nuclear Information System (INIS)

This short communication aims to update the review of non-nitro radiation sensitizers (Shenoy and Singh 1985) and correct omissions. Work is mentioned and bibliography given for studied of cis-platinum, potassium permanganate, cobalt hexammine, sodium bromide, dimethylsulphoxide, zinc and copper ions, organic nitroxyl free radicals (TAN,TMPN and NPPN + PNAP), halogenated pyrimidines, organic and inorganic iodine containing compounds, diacetyl, acetone and acetophenone, rho-hydrobenzoic acid and its esters, pentobarbitone and secobarbitone, heparin and 9-anilinoacridines, dehydropiandosterone and paraquat. (U.K.).

155

Electrical conductivity of radiation-processed wood polymer composites  

International Nuclear Information System (INIS)

Two species of wood, viz. Haldu (Adina Cordifolia) and Jamun (Syzygium Cumini) were vacuum-impregnated with two styrene-based monomer systems and polymerized in situ with gamma radiation from a cobalt-60 source. The electrical conductivity of these specimens was determined at various polymer loadings under dry conditions, after wetting and after wet recovery as per ASTM standards. The water absorption characteristics are also presented. The results are discussed with special reference to the role of water. Potential applications are also discussed. 7 figures.

1978-01-01

156

Anodic oxide coatings on metals and anodic protection /2nd revised and enlarged edition/. Anodnye oksidnye pokrytiia na metallakh i anodnaia zashchita /2nd revised and enlarged edition/  

Energy Technology Data Exchange (ETDEWEB)

The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.

1985-01-01

157

Towards atomic scale engineering of rare-earth-doped SiAlON ceramics through aberration-corrected scanning transmission electron microscopy  

British Library Electronic Table of Contents (United Kingdom)

Direct visualization of rare earths in @a- and @b-SiAlON unit-cells is performed through Z-contrast imaging technique in an aberration-corrected scanning transmission electron microscope. The preferential occupation of Yb and Ce atoms in different interstitial locations of @b-SiAlON lattice is demonstrated, yielding higher solubility for Yb than Ce. The triangular-like host sites in @a-SiAlON unit cell accommodate more Ce atoms than hexagonal sites in @b-SiAlON. We think that our results will be applicable as guidelines for many kinds of rare-earth-doped materials.

2011-01-01

158

Three-dimensional modeling of heat transport in deep hydrothermal reservoirs  

British Library Electronic Table of Contents (United Kingdom)

The need for alternative energy increases steadily???especially due to the climate change and the limited availability of fossil fuels. Geothermal power uses the intrinsic heat which is stored in the accessible part of the Earth???s crust. Its importance among the renewable energy resources originates from the almost unlimited energy supply of the Earth and its independence from external influences such as seasonal or even daily climatic variability. Nevertheless, there are risks which have to be assessed. From a mathematical point of view there are four building blocks of the characterization of deep geothermal systems: seismic exploration, gravimetry, modeling transport processes, and modeling the stress field. In particular, local depletion poses a significant risk during the industrial...

2011-01-01

159

The 'glass earth' - geochemical frontiers in exploration through cover  

International Nuclear Information System (INIS)

'Glass Earth' represents a number of current and planned projects within CSIRO aimed at making 'transparent' the top 1000 m of the Earth's crust It builds upon current technologies developed within a number of CSIRO divisions as well as the Australian Mineral Exploration Technologies CRC (AMET CRC), the Australian Geodynamics CRC (AG CRC) and the CRC for Landscape Evolution and Mineral Exploration (CRC LEME). New geophysical and geochemical technologies will be developed to complement these, together with new capabilities in modelling, data integration and visualisation, including hydrogeochemistry, hydrogeology, surface geochemistry and isotope geochemistry, modelling of chemical, fluid and heat flows in rock and regolith, advanced visualisation and data fusion. This paper describes some recent work in the field of isotope geochemistry, with the principal aim of 'seeing through' cover to understand basement geology and detect hidden ore ...

1999-09-24

160

Production of rare-earth atomic negative ion beams in a cesium-sputter-type negative ion source  

International Nuclear Information System (INIS)

The desire to study negative ion structure and negative ion-photon interactions has spurred the development of ion sources for use in research and industry. The many different types of negative ion sources available today differ in their characteristics and abilities to produce anions of various species. Thus the importance of choosing the correct type of negative ion source for a particular research or industrial application is clear. In this study, the results of an investigation on the production of beams composed of negatively-charged rare-earth ions from a cylindrical-cathode-geometry, cesium-sputter-type negative ion source are presented. Beams of atomic anions have been observed for most of the first-row rare-earth elements, with typical currents ranging from hundreds of picoamps to several nanoamps.

2007-08-01

161

Interaction of rare earths with orthanyl K and its spectrophotometric determination in binary mixtures  

International Nuclear Information System (INIS)

A study has been made of the colour reaction involved in the interaction or rare-earth elements with the reagent orthanyl K, the optimum conditions for the reaction being: pH=4.0-4.5 and lambda=660-670 nm. The ratio of components in the complex is Me:R=1:2. Consideration of the relative optical density values of the complex solutions as a function of the serial number of the rare-earth elements made it possible to recommend orthanyl K as a selective reagent for determining La, Ce, Pr and Nb in a mixture of Tu, Yb, Lu and Y oxides. The molar extinction coefficients, the sensitivity of the reaction and the concentration limits where Beer's law applies were calculated. Lanthanum was determined in a binary mixture with thulium and yttrium. (author).

1975-01-01

162

Development of a through-the-earth monitor system. Open file report (final) Oct 77-Dec 80  

Energy Technology Data Exchange (ETDEWEB)

The object of this program was to design and build a self-contained system for remote monitoring of the atmosphere in mines. The system developed uses the mine pager phone line as the primary communication channel and also has the capability of using 208 Hz in the ELF band for wireless transmission through the earth. The depth for through-the-earth transmission is expected to be about 80 to 90 meters in high conductivity soil and is limited by the noise level in the ELF band-pass filters. The underground components of the TEM System are energized by mine power through a battery charger-storage battery power supply. In the event of mine power failure the battery capacity is more than sufficient for 1 week's operation with interrogations every 4 hours.

1980-12-01

163

Comparative planetology, climatology and biology of Venus, Earth and Mars  

British Library Electronic Table of Contents (United Kingdom)

Spacecraft studies of the three terrestrial planets with atmospheres have made it possible to make meaningful comparisons that shed light on their common origin and divergent evolutionary paths. Early in their histories, all three apparently had oceans and extensive volcanism; Mars and Earth, at least, had magnetic fields, and Earth, at least, had life. All three currently have climates determined by energy balance relationships involving carbon dioxide, water and aerosols, regulated by solar energy deposition, atmospheric and ocean circulation, composition, and cloud physics and chemistry. This paper addresses the extent to which current knowledge allows us to explain the observed state of each planet, its planetology, climatology and biology, within a common framework. Areas of ignorance...

2011-01-01

164

Assessment of periodic sub-diurnal Earth rotation variations at tidal frequencies through transformation of VLBI normal equation systems  

British Library Electronic Table of Contents (United Kingdom)

We present an empirical model for periodic variations of diurnal and sub-diurnal Earth rotation parameters (ERPs) that was derived based on the transformation of normal equation (NEQ) systems of Very Long Baseline Interferometry (VLBI) observing sessions. NEQ systems that contain highly resolved polar motion and UT1-TAI with a temporal resolution of 15?min were generated and then transformed to the coefficients of the tidal ERP model to be solved for. To investigate the quality of this model, comparisons with empirical models from the Global Positioning System (GPS), another VLBI model and the model adopted by the conventions of the International Earth Rotation and Reference Systems Service (IERS) were performed. The absolute coefficients of these models agree almost completely within 7.5?...

2011-01-01

165

Structure and property relationship in the mixed-conducting Sr-Fe-Co-O system.  

Energy Technology Data Exchange (ETDEWEB)

Mixed-conducting ceramic oxides have potential uses in high-temperature electrochemical applications such as solid oxide fuel cells, advanced batteries, sensors, and oxygen-permeable membranes. The Sr-Fe-Co-O system combines high electronic/ionic conductivity with appreciable oxygen permeability at elevated temperatures. Dense ceramic membranes made of this material can be used to separate high-purity oxygen from air without the need for external electrical circuitry, or to partially oxidize methane to produce syngas. Samples of Sr{sub 2}Fe{sub 3{minus}x}Co{sub x}O{sub y} (with x = 0, 0.6, 1.0, and 1.4) were prepared by solid-state reaction in atmospheres with various oxygen partial pressures (pO{sub 2}) and were characterized by X-ray diffraction, scanning electron microscopy, and electrical conductivity measurements. Phase components of the samples are dependent on cobalt concentration and synthesis pO{sub 2}. Total conductivity increases with increasing ...

1998-05-18

166

Structural and electrical characteristics of epitaxial CoSi{sub 2} grown on n-Si{sub 0.83}Ge{sub 0.17}/n-Si(001) by reactive chemical vapor deposition using a Si capping layer  

Energy Technology Data Exchange (ETDEWEB)

Epitaxial cobalt disilicide (CoSi{sub 2}) layers are grown on n-Si{sub 0.83}Ge{sub 0.17}/n-Si(001) using a sacrificial Si capping layer at the growth temperature T{sub s}=650 deg. C by reactive chemical vapor deposition using cyclopentadienyl dicarbonyl cobalt (Co({eta}{sup 5}-C{sub 5}H{sub 5})(CO){sub 2}). Structural and electrical properties of epi-CoSi{sub 2}/Si{sub 0.83}Ge{sub 0.17}/Si(001) were measured by transmission electron microscopy, X-ray diffraction, Auger electron spectroscopy and sheet resistance measurement as a function of annealing temperature. The combined results showed that the epitaxial CoSi{sub 2} phase by the reaction of Co with the Si capping layer was formed in the as-grown layers. Rapid thermal anneals for the investigation of thermal stability of the as-grown layers showed good thermal stability of the epitaxial CoSi{sub 2} layers with the low sheet resistance value as low as congruent with 4.4 {omega}/cm up to the ...

2004-06-30

167

Structural and electrical characteristics of epitaxial CoSi_2 grown on n-Si_0_._8_3Ge_0_._1_7/n-Si(001) by reactive chemical vapor deposition using a Si capping layer  

International Nuclear Information System (INIS)

Epitaxial cobalt disilicide (CoSi_2) layers are grown on n-Si_0_._8_3Ge_0_._1_7/n-Si(001) using a sacrificial Si capping layer at the growth temperature T_s=650 deg. C by reactive chemical vapor deposition using cyclopentadienyl dicarbonyl cobalt (Co(#eta#"5-C_5H_5)(CO)_2). Structural and electrical properties of epi-CoSi_2/Si_0_._8_3Ge_0_._1_7/Si(001) were measured by transmission electron microscopy, X-ray diffraction, Auger electron spectroscopy and sheet resistance measurement as a function of annealing temperature. The combined results showed that the epitaxial CoSi_2 phase by the reaction of Co with the Si capping layer was formed in the as-grown layers. Rapid thermal anneals for the investigation of thermal stability of the as-grown layers showed good thermal stability of the epitaxial CoSi_2 layers with the low sheet resistance value as low as congruent with 4.4 #OMEGA#/cm up to the annealing temperature as high as 850 deg. C without ...

2004-06-30

168

Performance of SPNDs used in control and safety systems  

International Nuclear Information System (INIS)

Large sized reactor such as 540 MWe Pressurised Heavy Water Reactor (PHWR) requires continuous in core monitoring of local flux in order to provide effective control and protection. About 198 self powered neutron detectors (SPNDs) of the straight individually replaceable type are distributed in the reactor core. For purposes of reactor regulation, 42 prompt responding cobalt SPNDs called zone control detectors (ZCDs) are housed in vertical flux units (VFUs) and these are uniformly distributed in 14 power zones. The in core detectors used for spatial control by ZCCs do not accurately represent average zone power as they sense the flux over a small volume. Flux mapping system (FMS) comprising of 102 vanadium SPNDs in 26 VFUs, provide accurate measure of neutron flux, even though they have slow response to change in neutron flux levels. For reactor protection system-1 (RPS-1), 36 cobalt SPNDs are placed in VFUs and become part of core overpower ...

2006-11-13

169

Implant detectibility of intervertebral disc spacers in post fusion MRI: evaluation of the MRI scan quality by using a scoring system - an in vitro study  

International Nuclear Information System (INIS)

Intervertebral spacers for anterior spine fusion are made of different materials, such as titanium and cobalt chromium alloys and carbon fiber-reinforced polymers. Implant-related susceptibility artifacts can decrease the quality of MRI scans. The aim of this cadaveric study was to demonstrate the extent that implant-related MRI artifacting affects the postfusion differentiation of determined regions of interest (ROIs). In six cadaveric porcine spines, we evaluated the postimplantation MRI scans of a titanium, cobalt-chromium and carbon spacer that differed in shape and surface qualities. A spacer made of human cortical bone was used as a control. A defined evaluation unit was divided into ROIs to characterize the spinal canal as well as the intervertebral disc space. Considering 15 different MRI sequences read independently by an interobserver-validated team of specialists the artifact-affected image quality of the median MRI slice was rated ...

2007-02-01

170

Development of an irradiation system for a small size continuous run multipurpose gamma irradiator  

International Nuclear Information System (INIS)

The Radiation Technology Center from IPEN-CNEN/SP, Brazil, developed a revolutionary design and national technology, a small-sized continuous run and multipurpose industrial gamma irradiator, to be used as a demonstration facility for manufacturers and contract service companies, which need economical and logistical in-house irradiation system alternatives. Also, to be useful for supporting the local scientific community on development of products and process using gamma radiation, assisting the traditional and potential users on process validation, training and qualification of operators and radioprotection officers. The developed technology for this facility consists of a continuous tote box transport system, comprising a single concrete vault, where the automated transport system of products inside and outside of the irradiator utilizes a rotating door, integrated with the shielding, avoiding the traditional maze configuration. Covering 76 m"2 of floor area, the irradiator design is ...

171

Analysis of ZPPR experiments supporting production of "6"0Co in FFTF  

International Nuclear Information System (INIS)

An effort to expand the irradiation mission of the Fast Flux Test Facility (FFTF) beyond testing fuels and materials for the liquid-metal reactor (LMR) program included a study of the feasibility of producing commercial quantities of "6"0Co. The "6"0Co would be produced by neutron capture in assemblies containing an array of natural cobalt pins and hydrogen-bearing moderator pins located at the periphery of the FFTF core. Adding hydrogenous material to the assemblies enhances "6"0Co production by slowing neutrons into energy ranges where the "5"9Co capture cross section is higher. Some of the moderated neutrons leak from the moderated region to adjacent fuel regions, increasing local fission rates. In order to validate calculated fission rates and establish calculational biases and uncertainties, experiments were conducted in the zero-power plutonium reactor (ZPPR) to measure fission rates in fuel regions adjacent to a mock-up of a cobalt ...

1987-06-07

172

An Insoluble Titanium-Lead Anode for Sulfate Electrolytes  

Energy Technology Data Exchange (ETDEWEB)

The project is devoted to the development of novel insoluble anodes for copper electrowinning and electrolytic manganese dioxide (EMD) production. The anodes are made of titanium-lead composite material produced by techniques of powder metallurgy, compaction of titanium powder, sintering and subsequent lead infiltration. The titanium-lead anode combines beneficial electrochemical behavior of a lead anode with high mechanical properties and corrosion resistance of a titanium anode. In the titanium-lead anode, the titanium stabilizes the lead, preventing it from spalling, and the lead sheathes the titanium, protecting it from passivation. Interconnections between manufacturing process, structure, composition and properties of the titanium-lead composite material were investigated. The material containing 20-30 vol.% of lead had optimal combination of mechanical and electrochemical properties. Optimal process parameters to manufacture the anodes were identified. Prototypes having ...

2005-05-11

173

ch3 - NASA History Office  

Science.gov (United States)

Incoming solar energy had to be assimilated to sustain it. .... Roll stability was achieved with an Earth sensor mounted on the directional antenna. .... Once more a rocket becomes the means of producing a vector change in velocity. ...

174

Wildlife Monitoring Program Plan - NASA Technical Report Server (NTRS)  

Science.gov (United States)

Wildlife Monitoring System Schematic .......................... 40 ...... sentinel species - healthy fish are placed in an environment of water (where they arc not .... The way ir! which data for the fnre mdor study groups will be gathered tor managciacilt ...... Earth Resources Aircraft Program (ERAP) Camera ...

175

Transcriptome Profiling of a Toxic Dinoflagellate Reveals a Gene-Rich Protist and a Potential Impact on Gene Expression Due to Bacterial Presence  

UK PubMed Central (United Kingdom)

BackgroundDinoflagellates are unicellular, often photosynthetic protists that play a major role in the dynamics of the Earth's oceans and climate. Sequencing of dinoflagellate nuclear...Full Text Available

176

Topographic Map Creation  

Science.gov (United States)

In this activity, students create two- and three-dimensional maps by using a data grid of an imaginary section of Earth's surface. They are challenged to create six different maps of various surface features and answer questions about them.

2005-01-01

177

Time Travel Through A Trail Of ... - Near-Earth Object Program - NASA  

Science.gov (United States)

Dolores Beasley Headquarters, Washington, DC July 19, 2000 (Phone: 202/358- 1753) Bill Steigerwald Goddard Space Flight Center, Greenbelt, MD (Phone: ...

178

The Goddard Library - Goddard Projects Directory - NASA  

Science.gov (United States)

Oct 2, 2007 ... The Payload combines some of the most sensitive particle sensors .... provide state-of-the-art measurements of incoming x-ray, ultraviolet, .... It will be launched into a low-Earth orbit on a Delta 7320 rocket in September 2004. ...

179

Spatial confidentiality and GIS: re-engineering mortality locations from published maps about Hurricane Katrina  

UK PubMed Central (United Kingdom)

BackgroundGeographic Information Systems (GIS) can provide valuable insight into patterns of human activity. Online spatial display applications, such as Google Earth, can democratise...Full Text Available

180

Sociology and Space Development  

Science.gov (United States)

As the presence of humans in space expands in scope and duration, the quality of life in space as well as on Earth becomes pertinent. .... Military uses of space, such as the introduction of space-based laser or particle beam weapons, may have a major impact on the way people think and relate to .... AIAA Student Journal. ...

181

Selection of trends for recultivation of land in the Dnieper coal basin  

Energy Technology Data Exchange (ETDEWEB)

Types of disorders in the earth's surface as a result of open pit mining operations are analyzed. Trends for recultivation of lands are defined. Formulas are presented for calculating the economic expediency of the selected direction of recultivation.

1980-01-01

183

Satellite imagery in the study and forecast of malaria  

UK PubMed Central (United Kingdom)

More than 30 years ago, human beings looked back from the Moon to see the magnificent spectacle of Earth-rise. The technology that put us into space has since been used to assess the damage...Full Text Available

2002-02-07

184

Safety limits for utilization of secondary mining operations at deposits  

Energy Technology Data Exchange (ETDEWEB)

A procedure was developed to monitor boundaries within which secondary mining operations can be applied. Principal techniques include instrument and operative-remote observations of earth shifts and aerial photography of displacements on the surface of the trough.

1982-01-01

185

SUBMIT TO: AM105 CONFERENCE TITLE: Earth Observing Systems VI - NASA  

Science.gov (United States)

BAE SYSTEMS Infrared Imaging Systems. MS 209. 2 Forbes Road. Lexington, MA 02421 -7306. (781) 863-3762. (781) 863-4809 (fax) ken.overoye @lmco.com ...

186

SIERRA GORDA - The Gateway to Astronaut Photography of Earth  

Science.gov (United States)

ISS022, E, 8269, CHILE, OPEN PIT MINING OPERATIONS E. OF SIERRA GORDA, ROADS, DRAINAGE, -22.9, -69.1, 20091209. ISS022, E, 8270, CHILE, OPEN PIT MINING ...

187

Rocks, minerals, and a dusty world  

Energy Technology Data Exchange (ETDEWEB)

The Earth`s troposphere and hydrosphere contain abundant naturally generated dust. The ultimate source materials from which the terrestrially produced dust is generated are the various rock types exposed at the Earth`s surface. Natural dust is a composite of (1) lithic, primary mineral grains; (2) mineral grains formed by secondary chemical reactions; (3) volcanic ash and dust; (4) salts from sea sprays; (5) extra-terrestrial dust; and (6) biologic materials. In this paper the various pathways to the natural generation of dust (via the hydrologic cycle) will be discussed, and two geologically well-known natural dust sources will be described, paying particular attention to quantitative measurements of the dusts from these areas. General dust studies that provide data on possibly global background levels will be presented as well.. A few general aspects of the mineralogical characterization of dust particles and a discussion of some of the ...

1993-12-31

188

Ranger 8 - NASA - NSSDC - Spacecraft - Details  

Science.gov (United States)

5 days ago... Sun sensors, 2 secondary Sun sensors, and an Earth sensor. ... This continued intermittently until the rocket burn, at which time ... with incoming asymptotic direction at an angle of -13.6 degrees from the lunar equator. ...

189

Radioanalytical methods of rare earth element determination  

International Nuclear Information System (INIS)

Instrumental neutron activation analysis (INAA) and radionuclide X-ray fluorescence analysis (RXFA) were used for the determination of rare earth elements. For INAA, solution obtained by sample decomposition was dripped onto filter paper, enclosed and sealed into a polyethylene foil. The sample was activated in reactor WWR-S over a period of 4 to 6 hours with a neutron fluence of 10"1"3cm"-"2. Gamma radiation measurement was carried out with a planar and a coaxial HP-Ge detector in three decay periods. La, Ce, Nd, Sm, Eu, Gd, Tb, Ho, Tm, Yb and Lu were determined. The advantage of the method is its accuracy and high sensitivity, the disadvantage is the time-consuming analysis. The RXFA method was used as a rapid and operative method for the analysis of loose ore samples, aqueous and organic solutions of rare earth elements. For exciting X-ray radiation, "2"4"1Am was used and the radiation of K-lines was detected with a planar Si(Li) detector. ...

1989-06-01

190

Optical properties of rare earth sodium double molybdates Na[sub 5]RE(MoO[sub 4])[sub 4], RE=Pr, Nd, Eu  

Energy Technology Data Exchange (ETDEWEB)

Absorption and emission measurements at liquid-helium temperature, liquid-nitrogen temperature and room temperature have been performed on tetragonal scheelite-type rare earth sodium double molybdates Na[sub 5]RE(MoO[sub 4])[sub 4] and on RE-doped Na[sub 5]Gd(MoO[sub 4])[sub 4] samples. The rare earth occupies one single crystallographic position with S[sub 4] as point symmetry. The spectra were analysed according to the crystal field theory. From the experimental data, nearly complete energy level schemes of the Pr[sup 3+] and Nd[sup 3+], on the 4f [sup 2] and 4f [sup 3] configurations were derived. Very good correlation was obtained between the experimental and simulated energy level schemes, first for the approximated D[sub 2d] and then for the true S[sub 4] symmetries. The crystal field parameters vary smoothly with the atomic number of the rare earth, when compared with those determined previously for Eu[sup 3+] in the ...

1994-06-01

191

Optical Feshbach Resonances in Alkaline Earth Atoms  

Science.gov (United States)

Recent proposals have shown that a quantum degenerate gas of alkaline earth atoms can be used for a number of novel quantum computing and quantum simulation experiments. Strontium is a good candidate for such experiments because it can be controlled with high precision, as demonstrated in recent atomic clock experiments. Unfortunately, the small scattering length of strontium is not amenable to evaporative cooling techniques that are used to reach quantum degeneracy. Furthermore, increasing the scattering length of alkaline earths with a magnetic Feshbach resonance is not possible due to their spinless electronic ground state configuration. However, recent theoretical and experimental work suggests the possibility of changing scattering lengths in alkaline earths with laser light. Using this optical Feshbach resonance near strontium's narrow ^1S0->^3P1 intercombination transition might allow its scattering length to be ...

2009-10-01

192

Oil Leak from Damaged Well in Gulf of ... - NASA Earth Observatory  

Science.gov (United States)

Apr 25, 2010... oil per day were leaking from an oil well in the Gulf of Mexico in late April, following an explosion at an offshore drilling rig on April 20, 2010. ...

193

October 2010 Notes - Earth Science Data Systems Working Groups - NASA  

Science.gov (United States)

Federated Search (openSearch) (C. Lynnes); Infusion Process (S. Olding) Metrics Planning & Reporting (R. Ramapriyan); Service & Event Casting (B. Wilson) ...

194

Molecular determinants archetypical to the phylum Nematoda  

UK PubMed Central (United Kingdom)

BackgroundNematoda diverged from other animals between 600–1,200 million years ago and has become one of the most diverse animal phyla on earth. Most nematodes are free-living...Full Text Available

195

Medical fund took off like a rocket, but will budget bring it down to earth?  

UK PubMed Central (United Kingdom)

In 18 months the Canadian Medical Discoveries Fund (CMDF) has attracted investments worth $180 million to spend on biotechnology and medical research. Although eight initial investments totalled only...Full Text Available

1996-08-15

196

Mastacembelid eels support Lake Tanganyika as an evolutionary hotspot of diversification  

UK PubMed Central (United Kingdom)

BackgroundLake Tanganyika (LT) is the oldest of the African Rift Lakes and is one of the richest freshwater ecosystems on Earth, with high levels of faunal diversity and endemism....Full Text Available

197

Magnetic excitations studied with time-of-flight spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

An introduction to time-of-flight neutron spectroscopy is presented in the context of the study of magnetic materials. Examples are taken from the class of rare earth and actinide magnetic materials known as `strongly correlated electron` systems. (author) 11 figs., 24 refs.

1996-11-01

198

ISS022-E-8261 - The Gateway to Astronaut Photography of Earth  

Science.gov (United States)

Features: CHUQUICAMATA, LARGE OPEN PIT MINING OPERATIONS, ROADS, HILLS Center Point Latitude: -22.3 Center Point Longitude: -68.9 (Negative numbers indicate ...

199

ISS022-E-8260 - The Gateway to Astronaut Photography of Earth  

Science.gov (United States)

Features: CHUQUICAMATA, LARGE OPEN PIT MINING OPERATIONS, ROADS, HILLS Center Point Latitude: -22.3 Center Point Longitude: -68.9 (Negative numbers indicate ...

200

Gross Thermodynamics of Heat Engines in Deep Interior of Earth  

UK PubMed Central (United Kingdom)

From the gross conservation laws of thermodynamics in a convecting material we derive a bound on the ratio of the rate of production of mechanical or magnetic energy to the rate of internal radioactive...Full Text Available

1975-04-01

201

Geophysical Remote Sensing - The Remote Sensing Tutorial - NASA  

Science.gov (United States)

It was thus actually the fourth stage of the rocket assembly. ... package, and several temperature sensors - was mounted in the cross-lattice frame. ... Earth's geomagnetic field and incoming charged particles from the Sun and extra-solar space. ...

202

GSFC Earth-Sun Exploration Division - Sciences and Exploration ...  

Science.gov (United States)

retrieve detailed aerosol and cloud particle size distribution and shape ...... but on rain types, and hydrometeor characteristics. ..... of ice streams, decreasing sea ice cover in the Arctic, poleward movement of forest cover, and ...

203

Frequently Asked ... - Precipitation Measurement Missions - NASA  

Science.gov (United States)

... say for sure if the signal is coming from hail, lots of graupel, or some other hydrometeor . ... Precipitation forms when cloud droplets or ice particles in clouds grow and .... A landslide is the movement of rock, debris, or earth down a slope. ...

204

Epilogue - GES DISC - NASA  

Science.gov (United States)

Sep 9, 2009... a French Ariane rocket successfully launched a new Earth-observing satellite ... The payload is a pair of identical sensors known as "high-resolution ... the resulting image) are activated simultaneously by incoming radiation; ...

205

EcoEarth.Info Environment Links: Water/Rivers  

Wastenet

... 03, 2001 | Rate It Lake Superior Streams http://www.lakesuperiorstreams.org/ (1 vote) interactively examine real-time water quality data from 5 ...north shore Lake Superior trout streams and learn about other streams in the region, how they \\

206

Earth and Environment: murray_dobbie_morris  

Wastenet

... In recent years workers in this field have focused on nucleation by nano-porous materials . This was in part motivated by a theoretical study by Page and Sear (2006) who proposed a two step model for nucleation in pores which suggest that there is ...

207

Earth and Environment: Person detail  

Wastenet

...October 2006 - present: University of Leeds, UK PhD Candidate in Geochemistry Thesis Title: Magnetite formation in reducing natural environments Supervisors: Dr Liane G. Benning ...Germany Bachelor of Science in Geosciences and Astrophysics Project Details Project Title: \\

208

ESW 2009: The Ocean's Green Machines  

National Aeronautics and Space Administration (NASA)

One tiny marine plant makes life on Earth possible: phytoplankton. These microscopic photosynthetic drifters form the basis of the marine food web, they regulate carbon in the atmosphere, and are responsible for half of the photosynthesis that takes place on this planet.

2010-03-10

209

Combining Google Earth and GIS mapping technologies in a dengue surveillance system for developing countries  

UK PubMed Central (United Kingdom)

BackgroundDengue fever is a mosquito-borne illness that places significant burden on tropical developing countries with unplanned urbanization. A surveillance system using Google...Full Text Available

210

Charge transfer transitions and location of the rare earth ion energy levels in Ca-#alpha#-SiAlON  

International Nuclear Information System (INIS)

The broad bands in the room-temperature excitation spectra of Sm"3"+-, Dy"3"+- and Tm"3"+-activated Ca-#alpha#-SiAlON phosphors are interpreted as the N"3"--to-rare earth charge transfer transition (CTT). From the energies of the charge transfer transitions and from the optical data presented for the Eu"2"+ ion, the location of the divalent rare earth ion energy levels relative to the valence and the conduction band of Ca-#alpha#-SiAlON is derived. The salient features of the energy-level diagram are shown to be practical in explaining the temperature-dependent variations of the Eu"2"+ and Yb"2"+ luminescence efficiency in Ca-#alpha#-SiAlON. A comparative study pertaining to the nature of the Yb"2"+ and Eu"2"+ ion luminescence in Ca-#alpha#-SiAlON and in SrSi_2O_2N_2 is presented. A tentative energy-level diagram of the trivalent rare earth ions in Ca-#alpha#-SiAlON is also constructed.

2009-06-01

211

Characterization of psychrotrophic microorganisms producing beta-galactosidase activities.  

UK PubMed Central (United Kingdom)

Investigations of psychrotrophic microorganisms have been limited even though the dominant environment of the Earth is cold and enzymes with high activities at low temperatures could have commercial...Full Text Available

1994-01-01

212

CY00 Annual Report - NASA's History Office  

Science.gov (United States)

is approximately 327000 km from the Earth's center (58000 km from the Moon's ...... source (figure 7-4). NEXT developed funding requirements for those ...... Code SF 2. 2101 NASA Rd. 1. Houston, TX 77058. Phone: (281) 483-7224 ...

213

CHUQUICAMATA - The Gateway to Astronaut Photography of Earth  

Science.gov (United States)

ISS022, E, 8260, CHILE, CHUQUICAMATA, LARGE OPEN PIT MINING OPERATIONS, ROADS, HILLS, -22.3, -68.9, 20091209. ISS022, E, 8261, CHILE, CHUQUICAMATA, ...

214

Astronaut Jeff Williams Answers Your Questions  

National Aeronautics and Space Administration (NASA)

Expedition 22 Commander Jeff Williams, aboard the International Space Station 220 miles above Earth, responds to questions posted on YouTube concerning the station's orientation, life in space and the recent butterfly experiment.

2010-03-10

215

Asia - Goddard Earth Science Data and Information Services Center ...  

Science.gov (United States)

Sep 9, 2009 ... You are here: GES DISC Home Geomorphology from Space By Location Landforms by Location: Asia. Info. Landforms by Location: Asia. KEY, ASIA ...

216

Aluminium. Health and Environmental Hazards.  

Science.gov (United States)

Aluminium is an abundant metal consisting about 8 per cent of the earth's crust. It has long been considered as essentially nontoxic and nonabsorbable from the gastrointestinal tract. More recent studies have, however, due to better analytical capabilitie...

1982-01-01

217

AVISO and PODAAC User Handbook IGDR and GDR Jason Products - NASA  

Science.gov (United States)

An ascending node occurs when the subsatellite point crosses the earth's equator going from .... 11dB sigma-naught. This error budget includes the altimeter noise, ...... it is also recommended to filter the data as follows to ...

218

APOD: 2011 January 25 - The Rippled Red Ribbons of SNR 0509  

Science.gov (United States)

blast should have passed the Earth? Like: Follow APOD on Facebook Tomorrow's picture: whirlpool dust < | Archive | Index | Search | Calendar | RSS | Education | About APOD |...

2011-10-07

219

29 CFR 1926.602 - Material handling equipment.  

Science.gov (United States)

...Pneumatic-tired earth-moving haulage equipment (trucks, scrapers, tractors...Pneumatic-Tired Earthmoving Haulage Equipment. An employer may, of course...pneumatic-tired earthmoving haulage equipment, is suspended pending...

2009-07-01

220

Temperature Dependences of Leakage Currents of ZnO Varistors Doped with Rare-Earth Oxides  

British Library Electronic Table of Contents (United Kingdom)

Rare-earth oxides are doped into ZnO varistors as grain growth inhibitors for increasing the varistors' voltage gradients. However, their leakage currents become large and their nonlinear coefficients decrease at the same time. The reasonable explanation for such a phenomenon has not yet been available. In this paper, the temperature dependences of varistor samples' leakage currents are investigated, which reveal that the increased leakage currents of ZnO varistors with Y2O3 doping are mainly due to the bypass paths through the intergranular materials at grain corners.

2010-01-01

221

Spectroscopic study of rare earth chromates: relation to the structure  

International Nuclear Information System (INIS)

The luminescence spectra of trivalent europium ion embedded in various rare earth chromates were analysed. The spectroscopic data in most of chromates are in agreement with the structural determination but for some others the discrepancy between two methods is underlined. Energy level schemes were deducted from the experimental emission spectra and the crystal field simulation has been performed. The maximum splitting of the "7F_1 manifold of the Eu"3"+ ion as a function of N_v, the so-called crystal field strength parameter, is given. This allows us to classify the compounds according to their crystal field extent. (author)

1996-03-24

222

Space activities in the Bolivarian Republic of Venezuela  

British Library Electronic Table of Contents (United Kingdom)

This paper summarizes the establishment and current development of space activities in the Bolivarian Republic of Venezuela. Space activities in Venezuela are focused on the areas of telecommunications, Earth observation and research on the physical properties of the Earth, and have as a primary goal the satisfaction of social needs. Current development of space activities started in 1999 when the new National Constitution recognized the value of outer space as the common heritage of mankind, and the key role of science and technology in promoting human welfare. The Bolivarian Agency for Space Activities (ABAE) was created in 2007. Its legal framework recognizes three key elements that drive its policy: the participation of society, capacity building and human training, and international c...

2011-01-01

223

Simulation of statistical {gamma}-spectra of highly excited rare earth nuclei  

Energy Technology Data Exchange (ETDEWEB)

The statistical {gamma}-spectra of highly excited even-even rare earth nuclei are simulated applying appropriate level density and strength function to a given nucleus. Hindrance effects due to K-conservation are taken into account. Simulations are compared to experimental data from the {sup 163}Dy({sup 3}He,{alpha}){sup 162}Dy and {sup 173}Yb({sup 3}He,{alpha}){sup 172}Yb reactions. The influence of the K quantum number at higher energies is discussed. 21 refs., 7 figs., 2 tabs.

1997-05-01

224

Remote sensing of the atmosphere by resonance Raman LIDAR  

Energy Technology Data Exchange (ETDEWEB)

When in resonance, Raman scattering exhibits strong enhancement ranging from four to six orders of magnitude. This physical phenomenon has been applied to remote sensing of the Earth`s atmosphere. With a 16 inch Cassegrain telescope and spectrometer/ CCD-detector system, 70-150 ppm-m of SO{sub 2} in the atmosphere has been detected at a distance of 0.5 kilometer. This system can be used to detect/monitor chemical effluence in the atmosphere by their unique Raman fingerprints. Experimental result together with detailed resonance Raman and atmospheric laser propagation effects will be discussed.

1994-12-01

225

Radon concentration measurements in the presence of water and its consequences for Earth sciences studies  

Energy Technology Data Exchange (ETDEWEB)

Radon is often used as a natural tracer for geochemical studies. In many cases radon interacts with water. The aim of this study is to assess the time required for radon to dissolve in water and reciprocally to degas from it, and to estimate the partition ratio between the two phases. A special setup has been devised and built for this purpose. Several experiments carried out with this equipment show that both dissolution and degassing are rapidly achieved phenomena. The qualitative consequence of these results in the field of Earth science are shortly discussed in the paper.

2005-06-01

226

Preparation of poly (aryl ether ketones) in the presence of an alkali, alkaline earth of lanthanide metal salt  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for preparing poly(aryl ether ketones) by nucleophilic displacement polymerization in the presence of at least one alkali metal base selected from potassium, rubidium or cesium, and fluoride ions, which comprises adding to the polymerization: (a) an effective amount of at least one metal salt selected from lithium, sodium, alkaline earth or lanthanide chloride, bromide, iodide, sulfate, alkyl or aryl carboxylate, cyanide, borate or phosphate to slow or stop advancement of molecular weight and (b) an end-capping agent.

1988-09-27

227

Occurrence of magnetism in superconductors  

Science.gov (United States)

We discuss how magnetic phenomena affect superconductivity in simple metals, transition metals and alloys thereof, and dilute Rare-Earth alloys. It is shown both qualitatively and quantitatively that superconductors are sensitive probes for studying itinerant spin excitations, local spin excitations associated with nearly magnetic impurities, the effect of the atomic environment on the stability of local magnetic moments, and the nature of the spin order in Rare-Earth alloys. Also, we discuss how magnetic impurities can be used to study the electronic configuration which is responsible for superconductivity in Laves-phase crystals like A-15 compounds and ..beta..-W crystals, for example.

1970-12-14

228

Planetary protection protecting earth and planets against alien microbes  

International Nuclear Information System (INIS)

Protecting Earth and planets against the invasion of 'alien life forms' is not military science fiction, but it is the peaceful daily job of engineers and scientists of space agencies. 'Planetary Protection' is preventing microbial contamination of both the target planet and the Earth when sending robots on interplanetary space mission. It is important to preserve the 'natural' conditions of other planets and to not bring with robots 'earthly microbes' (forward contamination) when looking for 'spores of extra terrestrial life'. The Earth and its biosphere must be protected from potential extraterrestrial biological contamination when returning samples of other planets to the Earth (backward contamination). The NASA-Caltech Laboratory for Planetary Protection of Dr. Kasthuri Venkateswaran at the Jet Propulsion Laboratory (JPL) (California, USA) routinely monitors and characterizes ...

2006-04-01

229

Microclimatic models. Estimation of components of the energy balance over land surfaces  

Energy Technology Data Exchange (ETDEWEB)

Climates at regional scale are strongly dependent on the interaction between atmosphere and its lower boundary, the oceans and the land surface mosaic. Land surfaces influence climate through their albedo, and the aerodynamic roughness, the processes of the biosphere and many soil hydrological properties; all these factors vary considerably geographically. Land surfaces receive a certain portion of the solar irradiance depending on the cloudiness, atmospheric transparency and surface albedo. Short-wave solar irradiance is the source of the heat energy exchange at the earth`s surface and also regulates many biological processes, e.g. photosynthesis. Methods for estimating solar irradiance, atmospheric transparency and surface albedo were reviewed during the course of this project. The solar energy at earth`s surface is consumed for heating the soil and the lower atmosphere. Where moisture is available, evaporation is one of the key components of ...

1996-12-31

230

The platinum chromium element stent platform: from alloy, to design, to clinical practice  

British Library Electronic Table of Contents (United Kingdom)

Despite advances in polymer and drug technology, the underlying stent platform remains a key determinant of clinical outcome. A clear understanding of stent design and the differences between various stent platforms are of increasing importance for the interventional cardiologist. Reduction in stent strut thickness has been associated with improved stent deliverability, improved procedural outcome, and lower rates of subsequent restenosis. Newer-generation 316L-SS stent designs have enabled reduced strut thickness while retaining radial strength and minimizing recoil, but with significant loss of radiopacity, leading to reduced visibility. Cobalt chromium alloys have enabled a reduction in stent strut thickness to around 80?90 mm while retaining modest radiopacity, but due to higher elasti...

2010-01-01

231

Shutdown Chemistry Process Development for PWR Primary System  

Energy Technology Data Exchange (ETDEWEB)

This study report presents the shutdown chemistry of PWR primary system to reduce and remove the radioactive corrosion products which were deposited on the nuclear fuel rods surface and the outside of core like steam generator channel head, RCS pipings etc. The major research results are the follows ; the deposition radioactive mechanism of corrosion products, the radiochemical composition, the condition of coolant chemistry to promote the dissolution of radioactive cobalt and nickel ferrite, the control method of dissolved hydrogen concentration in the coolant by the mechanical and chemical methods. The another part of study is to investigate the removal characteristics of corrosion product ions and particles by the demineralization system to suggest the method which the system could be operate effectively in shut-down purification period. (author). 19 refs., 25 figs., 48 tabs.

1997-12-31

232

Resonance Raman and photophysical studies of transition metal complexes in solution and entrapped in zeolites  

Science.gov (United States)

We have obtained convincing evidence for localization of the optical electron on a single-ring fragment of a chelated bipyridine-like'' ligand (ie., pyridylpyrazine or 4-Methyl-bipyridine). In addition we have completed studies of Ru(bipyrazine){sub 3}{sup 2+} in aqueous sulfuric acid (0--98% by weight) and find clear evidence for sequential addition of six-protons to the six peripheral nitrogen atoms. Studies of zeolite-entrapped complexes are continuing and a series of homo- and heteroleptic complexes have been prepared and characterized. Finally, the synthesis of zeolite-entrapped metallophthalocyanines has now been developed and the copper and cobalt analogues synthesized. The characterization of these materials is now in progress.

1992-03-31

233

Removal of 106Ru traces from NH4NO3 effluent generated during recycling of sintered depleted uranium fuel pellets  

British Library Electronic Table of Contents (United Kingdom)

Feasibility of using fixed bed column of conventional ion exchangers/sorbent and chemical precipitation based processes have been examined for the effective removal of the very low levels of 106Ru activity from NH4NO3 effluent generated during wet processing of rejected sintered depleted uranium fuel pellets. Based on the results, a simple process involving precipitation of cobalt sulphide along with ferric hydroxide was selected and further optimization of process variables was carried out. The optimized process has been found to be highly efficient in reducing 106Ru activity down to extremely low levels.

2011-01-01

234

Production of plastified wood with stronger static bending strength means of polymerization induced by gamma radiation; Producao da madeira plastificada de elevada resistencia a flexao estatica mediante polimerizacao induzida por raios gama  

Energy Technology Data Exchange (ETDEWEB)

The use of gamma radiation to obtain wood-polymer composites is one of the applications of radiation that presents the most commercial interest. The process, denominated radiopolymerization, comprises the impregnation of monomers into the completely dried wood followed by exposure to gamma radiation to induce polymerization of the impregnated monomers. I this context, the present work aimed the application of this process to seven kinds of wood existing in the brazilian forests. The considered monomer is styrene and the gamma source is Cobalt-60. The obtained wood-polystyrene composites were found to have stronger static bending strength. (author)

1999-07-01

235

Process for preparing inorganic particulate adsorbent and process for treating nuclear reactor core-circulating water  

Energy Technology Data Exchange (ETDEWEB)

An inorganic particulate adsorbent of a titania-alumina is described for treating a superheated water containing radioactive materials such as cobalt ions, which is free from release of corrosive impruities, and which has a high adsorption capacity of radioactive materials and a high mechanical strength is prepared by hydrolyzing a titanium alkoxide and an aluminum alkoxide, thereby forming a hydrous titanium oxide and a hydrous aluminum oxide, respectively; precalcining the hydrous titanium oxide and aluminum oxide, mixing and molding the resulting titania and alumina into a particulate mixture thereof having a titania mole fraction of 0.2 to 0.9, and calcining the particulate mixture at 500/sup 0/-700/sup 0/C. This absorbent is effectively used in treat boiling water-type nuclear reactor core-circulating water to remove radioactive substances therefrom.

1981-08-04

236

Preparation of cost-effective Pt-Co electrodes by pulse electrodeposition for PEMFC electrocatalysts  

International Nuclear Information System (INIS)

Graphical abstract: - Abstract: Low loading platinum-cobalt (Pt-Co) cathode catalyst on a Nafion(Na+)-bonded carbon layer is fabricated by using galvanostatic pulse technique to show the advantage of electrodeposition for high utilization of catalyst in proton exchange membrane fuel cell (PEMFC). We observed that Pt-Co catalysts evenly exist on the surface of carbon electrode and its thickness is about 5.8 ?m, which is four times thinner than conventional Pt/C. Improved single cell power performance of Pt-Co cathode catalysts with a ratio of 3.2:1 compared with Pt/C is clearly presented.

2011-03-01

237

Pilot project ''measurement of efficacy'' - biological monitoring of antimony pollution in the Munich test area using a standardized grass culture  

International Nuclear Information System (INIS)

This pilot project was carried out for the purpose of testing methods for active biological monitoring. It covered a period of three years (until September 1994), including two years of exposure. The measurements served to determine pollutant levels in plants used as animal fodder and dust-borne heavy metal concentrations in different sites and, on this basis, to obtain indirect information on human exposure. Among others, the pilot project investigated the suitability of Italian rye-grass as a biological indicator for aluminium, arsenic, cadmium, cobalt, chromium, copper, iron, mercury, magnesium, manganese, nickel, lead, platinum, antimony, titanium, and zinc. (orig./GL).

238

On synergism in inhibition of liquidphase oxidation of styrene and tetralin by organic phosphites and transition eleement acetylacetonates  

International Nuclear Information System (INIS)

Synergism has been observed during inhibiting initiated oxidation of styrene or tetralin by organic phosphites in the presence of complex compounds of some transition metals. The results are given of non-additive intensification of antioxidative activity of triphenylphosphite (TPP) and tri-(4-methyl-6-tert.-- butyl)-phenyl-phosphite (TMBP) in the process of initiated oxidation of styrene or tetralin with addition of acetylacetonates of cobalt and vanadyl. During styrene oxidation, inhibition of the reaction with chelate complex of vanadyl is weakened considerably when phosphite is added into the reaction system. During tetralin oxidation, postcatalytic (or branched) oxidation is observed only for large concentration of vanadyl complex. Addition of TPP to above complex sharply increases the induction period. When the induction period is completed, oxidation of tetralin follows the mechanism of usual, i.e. initiated, reaction.

239

Milling materials using CO{sub 2} clusters; Materialbearbeitung durch Clusterionenbeschuss  

Energy Technology Data Exchange (ETDEWEB)

The Sputter coefficient of accelerated CO{sub 2} cluster ions hitting surfaces of various materials is investigated. For copper it varies proportional to the 2nd power of the energy between 155 and 260 keV. The rate of erosion for different target materials varies by two orders of magnitude from tungsten to PMMA. Diamond is eroded fairly quickly, while aluminum is eroded less than corundum (Al{sub 2}O{sub 3}). No simple correlation of the sputter coefficient on the bulk material properties is found. For copper the angular distribution of sputtered material is measured and found to be following roughly a cosine distribution. By using masks different microstructures have been produced in cobalt-samarium magnets, diamond and glass. (orig.)

1993-10-01

240

Microstructure and properties of ultrafine WC-10Co composites with chemically doped VC  

British Library Electronic Table of Contents (United Kingdom)

Vanadium carbide is the most effective grain growth inhibitor for ultrafine WC-Co composites due to its high solubility and mobility in the cobalt phase at relatively low temperatures; however, there are still some debates over the best way to introduce it into the WC-Co formulation. In this paper, the differences between admixed and chemically doped grain growth inhibitors on the microstructural development and properties of an ultrafine WC-10Co composite are discussed. The densification rate of chemically doped samples is slower in the early stage of sintering and the WC grain sizes of the sintered alloys are finer than those of admixed samples, leading to the increase of hardness and transverse rupture strength of the sintered alloys. The effectiveness of the chemically doped inhibitor ...

2011-01-01

241

Magnetic properties of Fe-Co-Mo-Cu-B nanocrystalline ribbons with stressing surfaces  

British Library Electronic Table of Contents (United Kingdom)

Magnetic properties of Fe-Co-Mo-Cu-B alloy system with Co up to 26at.% were investigated. After proper thermal treatment, the nanocrystalline grain remains tiny, the density hardly increases, but the room-temperature saturation attains 1.5T mainly due to a high enough Curie temperature. The generally observed slant hysteresis loops point to ribbon surfaces, which stress the ribbon interior and induce a specific magnetoelastic contribution to hard-ribbon-axis magnetic anisotropy even after vacuum annealing. The effect does not come from cobalt but rather from the lack of silicon. Partial removal of the surfaces resulted in a decrease of the loop tilt.

2011-01-01

242

Magnetic and magnetostrictive properties of manganese substituted cobalt ferrite  

International Nuclear Information System (INIS)

The magnetic and magnetostrictive properties of polycrystalline Co1-xMnxFe2O4 (0 ? x ? 0.4) have been studied. Although the Curie temperature decreases continuously with increasing concentration of Mn, the magnetization remains high up to x = 0.3 and unexpectedly low coercivity is observed for this composition showing an unusual magnetostrictive behaviour. This composition shows a relatively larger magnetostriction at low fields. Moreover, the strain derivative which is the slope of the magnetostriction curve at low magnetic fields is almost doubled and the field at which maximum magnetostriction is observed is reduced to almost half for 30% of Mn substitution. The results show that x ? 0.3 in Co1-xMnxFe2O4 is an optimum composition with superior magnetostrictive properties for many applications.

2007-06-07

243

Low power flux logging system for TAPS 3 and 4  

International Nuclear Information System (INIS)

This system provides data logging facility for axial profile and dynamic profile experiments during low power physics experiments. The data from Cobalt Self Powered Neutron Detectors (SPNDs) are logged via hardware consisting of PC plug-in cards and data of vanadium SPNDs are logged from the Flux Mapping System (FMS) network (multicast data). The data along with programmable details of the experiment is transferred to an Access Database. The system provides online displays and extensive reports from the Access Database as per the requirement from Reactor Physicists. This paper briefly describes the evolvement of requirements (from the experience of operation of TAPS 4 to TAPS 3), software architecture and design. (author)

2010-02-01

244

In-vitro evaluation of corrosion resistance of nitrogen ion implanted titanium simulated body fluid  

International Nuclear Information System (INIS)

Titanium and its alloy Ti6Al4V enjoy widespread use in various biomedical applications because of favourable local tissue response, higher corrosion resistance and fatigue strength than the stainless steels and cobalt-chromium alloy previously used. The study reported in this paper aims to optimize the conditions of nitrogen ion implantation on commercially pure titanium and to correlate the implantation parameters to the corrosion resistance. X-ray photoelectron spectroscopy was used to analyse surface concentration and the implantation processes. An improvement in the electrochemical behaviour of the passive film was shown to occur with nitrogen ion implantation on titanium, in simulated body fluids. (UK).

245

Fracture Resistance of Metal Ceramic Restorations with Two Different Margin Designs After Exposure to Masticatory Simulation  

British Library Electronic Table of Contents (United Kingdom)

Statement of problem Although the esthetic outcome of a collarless metal ceramic restoration is superior to that of a restoration with a metal margin, its mechanical strength has not been evaluated. Purpose The purpose of this study was to evaluate and compare the fracture resistance of metal ceramic restorations with metal margins to that of metal ceramic restorations with circumferential porcelain margins, after exposure to masticatory simulation. Material and methods Twenty-four metal ceramic restorations were fabricated and paired with 24 cobalt-chrome tooth analogs. Twelve of the specimens had metal margins, while the remainder had circumferential porcelain margins. The restorations were cemented on the metal tooth analogs with a resin-modified glass ionomer luting agent (FujiCEM). Al...

2009-01-01

246

Electrochemical hydrogen storage behaviors of ultrafine Co-P particles prepared by direct ball-milling method  

Energy Technology Data Exchange (ETDEWEB)

Ultrafine particles of Co-P were synthesized by direct ball milling of Co and P powders and also investigated as a reversible hydrogen storage electrode material. The electrochemical results demonstrated that the reversible charge-discharge capacity of the Co-P electrode can reach more than 300mAh/g. In addition, the cycling ability and high rate capability of the Co-P electrode are excellent with only 5% capacity decay after 100 cycles at a high rate of 300mA/g. The temperature-programmed desorption measurements (TPD) of the Co-P electrode revealed that the charge and discharge reactions of the Co-P electrode proceeds predominantly through electrochemical hydrogen storage mechanism and the electrooxidation of cobalt contributes only a negligible part to the reversible electrochemical capacity. (author)

2006-05-25

247

Catalyzed oxidative degradation of methylene blue by in situ generated cobalt (II)-bicarbonate complexes with hydrogen peroxide  

British Library Electronic Table of Contents (United Kingdom)

Oxidative degradation of methylene blue (MB) by Co^2^+-HCO3^- system with H2O2 in aqueous solution was studied. Nearly complete decolorization of the dye was obtained in less than 50min in diluted NaHCO3 solution (25mM) in the presence of only 20mM Co^2^+ ions. Meanwhile, the conjugated structure and phenyl rings of the MB molecule were destroyed or even broken down into small organic acids and inorganic ions, as indicated by FT-IR spectra and ion-chromatography. Photoluminescence probing and radical scavenging technologies suggested that the reaction of MB degradation in this system mainly involved the generation and participation of hydroxyl radicals. Furthermore, by cyclovoltammetric measurements, the in situ formed different complexes between Co^2^+ and HCO3^- were observed at differen...

2011-01-01

248

Adhesive wear of iron chromium nickel silicon manganese molybdenum niobium alloys with duplex structure. Untersuchung von Eisen-Chrom-Nickel-Silizium-Mangan-Molybdaen-Niob-Legierungen mit Duplexgefuege auf adhaesiven Verschleiss  

Energy Technology Data Exchange (ETDEWEB)

Iron nickel chromium manganese silicon and iron chromium nickel manganese silicon molybdenum niobium alloys have a so-called duplex structure in a wide concentration range. This causes an excellent resistance to wear superior in the case of adhesive stress with optimized concentrations of manganese, silicon, molybdenum and niobium. The materials can be used for welded armouring structures wherever cobalt and boron-containing alloy systems are not permissible, e.g. in nuclear science. Within the framework of pre-investigations for manufacturing of filling wire electrodes, cast test pieces were set up with duplex structure, and their wear behavior was examined. (orig.).

1991-11-01

249

Elemental transfer from Chinese soil via the diet to the whole human body  

International Nuclear Information System (INIS)

Based on results from recent studies of elemental dietary intake and organ or tissue content for adult Chinese men, quoted nationwide elemental concentrations in Chinese soil and newly published national average consumption of dietary foods, values of both transfer coefficients and discrimination factor (DF) for transfer from soil via the diet to both critical organs and the whole body have been calculated for important elements in radiation protection, including alkaline earths, alkali metals, rare earths and other related elements. These calculations have used both the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) model and the DF method. In the UNSCEAR model, the basic parameters used to describe the transport of radionuclides are the transfer coefficients P_i_j, which describe the relationship of concentrations or other amounts between compartment i and the following compartment j, whereas the DF is the ...

2008-12-01

250

Correlated variations and periodicity of global CO{sub 2}, biological mass extinctions and extra-terrestrial bolide impacts over the past 250 million years and possible geodynamical implications  

Energy Technology Data Exchange (ETDEWEB)

Earth`s history has been witness to recurrently alternating phases of catastrophic evolution and dominant tectonic deformations, contractions and extension of rifting and spreading leading to quasi-cyclic changes in sedimentary environment and various earth processes. Recent studies have shown quasi-periodicities of 32{+-}2 Million years (Myr) in various endogenic (geomagnetic reversals, magmatic events, mantle convection, various tectonic activities, climate change and biological extinctions) and exogenic (impact catering) processes indicating a remarkable kinship. A time series analysis is presented of the available CO{sub 2} record over the past 250 Myr decoded from global CaCO{sub 3} accumulation rates in sedimentary environment. The time series analysis reveals an intriguing evidence of a dominant periodicity of 33{+-}2 Myr which matches closely with a `common catastrophic periodicity` of 32 Myr identified in various terrestrial and ...

1998-12-31

251

The Effect of Lunar-like Satellites on the Orbital Infrared Light Curves of Earth-analog Planets  

CERN Document Server

We investigate the influence of lunar-like satellites on the infrared orbital light curves of Earth-analog extra-solar planets. Such light curves will be obtained by NASA's Terrestrial Planet Finder (TPF) and ESA's Darwin missions as a consequence of repeat observations to confirm the companion status of a putative planet. We use an energy balance model to calculate disk-averaged infrared (bolometric) fluxes from planet-satellite systems over a full orbital period (one year). The satellites are assumed to lack an atmosphere, have a low thermal inertia like that of the Moon and span a range of plausible radii. The planets are assumed to have thermal and orbital properties that mimic those of the Earth while their obliquities and orbital longitudes of inferior conjunction remain free parameters. Even if the gross thermal properties of the planet can be independently constrained (e.g. via spectroscopy or visible-wavelength detection of specular ...

2008-01-01

252

Synthesis and characterization of #beta#-SiAlON with a rare earth concentrate as sintering aid  

International Nuclear Information System (INIS)

Silicon nitride-based ceramics behavior is strongly influenced by microstructural parameters, which, in turn are determined by chosen densification method. Highly covalent Si-N bond hind are the silicon nitride densification. Therefore, metal oxides are used in order to get high density. However, such oxides must be carefully selected, because they affect the general macroscopic properties of sintered bodies. In the present work, the viability of rare earth concentrate use to produce #beta#--Si_6_-_xAl_xO_xN_8_-_x and its effect on mechanical properties of the sintering ceramics are studied. Additive composition, heating rate, soaking time and sintering temperature were took as variables. Hardness, fracture toughness, Young's modulus and flexural strength were investigated. Lattice parameter compositional dependence and secondary phases crystallized after past-sintering heat treatment were also determined. The results show that rare earth ...

253

Stereoscopic observations of a solar hard x-ray flare with Ulysses, PVO, GRO and Yohkoh spacecraft  

Energy Technology Data Exchange (ETDEWEB)

Hard X-ray/gamma-ray spectrometers aboard two interplanetary spacecraft, Ulysses and Pioneer Venus Orbiter (PVO), and two near-Earth spacecraft, Yohkoh and Compton Gamma Ray Observatory (GRO/BATSE), are currently in operation. A unique set of circumstances have permitted the observation of the 15 November 1991 (2238 UT) flare by all the four instruments. This intense flare (GOES class X 1.5) was associated with the bright (3B) H-alpha flare located on the disk (S13, W19) in the active region 6919. At the time of the flare, the Ulysses and PVO spacecraft were located respectively 101[degree] and 52[degree] west of the Sun-Earth line. Thus the view angles for the PVO and Ulysses instruments were quite different from those of the near-Earth instruments on GRO and Yohkoh. The preliminary photon energy spectra observed by the four instruments at different times during the flare will be presented and their implications regarding ...

1992-01-01

254

Realistic Earth matter effects and a method to measure small \\theta_{13} in the detection of supernova neutrinos  

CERN Document Server

In this paper, we first calculate the realistic Earth matter effects on the detection of type II supernova neutrinos at the Daya Bay reactor neutrino experiment which is currently under construction. It is found that the Earth matter effects depend on the neutrino incident angle \\theta, the neutrino mass hierarchy \\Delta m_{31}^{2}, the crossing probability at the high resonance region inside the supernova, P_H, the neutrino temperature, T_{\\alpha}, and the pinching parameter in the neutrino spectrum, \\eta_{\\alpha}. We give the expression for the dependence of P_H on the neutrino mixing angle \\theta_{13}. With this we obtain the relations between \\theta_{13} and the event numbers for various reaction channels of supernova neutrinos. Using these relations, we propose a possible way to measure \\theta_{13} smaller than 1.5^\\circ. Such a sensitivity cannot be achieved by the Daya Bay neutrino experiment (the sensitivity of the Daya Bay ...

2008-01-01

255

Neutron activation analysis of Permian-Triassic (P-Tr) boundary layer at Selong site in China  

Energy Technology Data Exchange (ETDEWEB)

Since living things began their activities on the earth, the extermination of living things in large number on global scale occurred twice 230 million years ago (P-Tr boundary) and 65 million years ago (K-T boundary). As to the cause of exterminating living things in short period, there are volcano eruption theory, meteorite collision theory and so on, but still it is not decided. Therefore, as to the strata of P-Tr boundary in south-western part of China where it has been known the preservation of P-Tr strata is especially good, the existence of elements was measured by instrument neutron activation analysis and ICP-MS, and the state of change was examined. According to the results, the change occurred at the P-Tr boundary on the earth, and further, the possibility of meteorite collision by paying attention to Ir were examined. The samples, the neutron activation analysis, the ICP-MS and the results are reported. The distinction by strata and ...

1994-07-01

256

EXPLORENEOs. I. DESCRIPTION AND FIRST RESULTS FROM THE WARM SPITZER NEAR-EARTH OBJECT SURVEY  

International Nuclear Information System (INIS)

We have begun the ExploreNEOs project in which we observe some 700 Near-Earth Objects (NEOs) at 3.6 and 4.5 ?m with the Spitzer Space Telescope in its Warm Spitzer mode. From these measurements and catalog optical photometry we derive albedos and diameters of the observed targets. The overall goal of our ExploreNEOs program is to study the history of near-Earth space by deriving the physical properties of a large number of NEOs. In this paper, we describe both the scientific and technical construction of our ExploreNEOs program. We present our observational, photometric, and thermal modeling techniques. We present results from the first 101 targets observed in this program. We find that the distribution of albedos in this first sample is quite broad, probably indicating a wide range of compositions within the NEO population. Many objects smaller than 1 km have high albedos (?>0.35), but few objects larger than 1 km have high albedos. This ...

2010-09-01

257

Collisions with ice-volatile objects: Geological implications  

International Nuclear Information System (INIS)

The collision of the Earth with extra-terrestrial ice-volatile bodies is proposed as a mechanism to produce rapid changes in the geologic record. These bodies would be analogs of the ice satellites found for the Jovian planets and suspected for comets and certain low density bodies in the Asteroid belt. Five generic end-members are postulated: (1) water ice; (2) dry ice: carbon-carbon dioxide rich, (3) oceanic (chloride) ice; (4) sulfur-rich ice; (5) ammonia hydrate-rich ice; and (6) clathrate: methane-rich ice. Due to the volatile nature of these bodies, evidence for their impact with the Earth would be subtle and probably best reflected geochemically or in the fossil record. Actual boloids impacting the Earth may have a variable composition, generally some admixture with water ice. However for discussion purposes, only the effects of a dominant component will be treated. The general geological effects of such collisions, ...

1988-10-20

258

A preliminary stage configuration for a low pressure nuclear thermal rocket (LPNTR)  

Energy Technology Data Exchange (ETDEWEB)

A low pressure nuclear thermal rocket (LPNTR) is configured to meet the requirements of a nuclear stage for manned Mars exploration. Safety, reliability and performance are given equal consideration in selecting the stage configuration. Preliminary trade studies are conducted to size the engine thrust and determine the thrust chamber pressure. A weight breakdown and mechanical configuration for the selected LPNTR concept are defined. A seven engine stage configuration is selected which gives a two engine out capability and eliminates the need for engine gimbaling. The stage can be ground assembled and launched as a unit including tankage for trans Earth injection and Earth orbital capture. The tankage is configured to eliminate the need for an inert shield. The small engine will be cheaper to develop than a single engine providing full thrust, and will be compatible with stages for Earth orbital, Lunar and deep space ...

1990-01-01

259

Valence mixing in rare earth compounds  

International Nuclear Information System (INIS)

The concepts of ''fast'' and ''slow'' time scale valence measurements are emphasized by a comparison of L/sub III/ absorption and Mossbauer effect measurements on the temperature induced valence change in EuPd/sub 2/Si/sub 2/. Further the authors show how synchrotron radiation based L/sub III/ measurements of the Ce-valence state can be used to demonstrate electronic structure trends under wide changes in chemical environment. The purpose of this paper is to provide an introduction to researchers in the People's Republic of China to the field of mixed valent rate earth compounds. They hope to illustrate some of the basic concepts in this field, how the field is contributing to the overall insight into the chemical physics of solids and finally how synchrotron radiation measurements in particular are playing a key role in this field.

260

Using "EC-Assess" to Assess a Small Biofuels Project in Honduras  

Science.gov (United States)

Biofuels may contribute to both rural economic development and climate change mitigation and adaptation. The Gota Verde Project in Yoro, Honduras, attempts to demonstrate the technical and economic feasibility of small-scale biofuel production for local use by implementing a distinctive approach to feedstock production that encourages small farm sizes, mixed cropping of biofuel feedstock from Jatropha and food crops, particularly corn and beans, grown side by side on the same farmland and the total involvement of small rural farmers. But is the project sustainable? Using EC-Assess, the Earth Charter ethics-based assessment tool, to assess the sustainability of this project, the author found that in some assessment categories the actions surpassed the intended objectives, showing that the project was achieving certain Earth Charter goals without specifically stating its intention to address them. (Contains 3 images, 3 figures and 2 notes.)

2010-09-01

261

Superconductivity in cage doped fullerenes. Final report  

Energy Technology Data Exchange (ETDEWEB)

Motivated by the discovery of superconductivity in alkali and alkaline earth fullerides, this program was undertaken both to understand the nature of and expand the range of materials demonstrating superconductivity. The first approach involved attempts to modify the fullerene cage by incorporating heteroatoms in the structure and the preparation and photophysical properties of nitrogen and sulfur doped fullerenes were studied in detail. The second approach involved examining the stoichiometry and effect of preparative conditions on the behavior of alkali, alkaline earth, lanthanide and mixed ion fullerides. In particular, the authors have elaborated on a technique for making such salts using liquid ammonia or aliphatic amines as solvents. Thirdly, modeling studies were undertaken to predict the properties of heterohedral fullerines and metal - C60 complexes, and theoretical guidelines were developed for understanding the reactivity of the ...

1996-08-26

262

Structure and electric transport properties of LnSr_2FeTiO_7 (Ln = La, Nd and Gd)  

International Nuclear Information System (INIS)

Three new phases with compositions, LaSr_2FeTiO_7, NdSr_2FeTiO_7 and GdSr_2FeTiO_7, were prepared by the traditional ceramic method. Lazy-Pulverix analysis of the X-ray diffraction data suggests that the phases crystallize in the RP-type (n = 2) structure in the space group, I4/mmm. The cell dimensions along the c-axis decrease with decrease in size of the rare earth ions. Electrical resistivity, as a function of temperature, shows that the materials are insulators and the resistivity decreases with decrease in the size of the rare earth ion, which is attributed to increase in the three-dimensional character. (author)

2011-02-01

263

Spectroscopic study of rare earth chromates: relation to the structure  

Energy Technology Data Exchange (ETDEWEB)

The luminescence spectra of trivalent europium ion embedded in various rare earth chromates were analysed. The spectroscopic data in most of chromates are in agreement with the structural determination but for some others the discrepancy between two methods is underlined. Energy level schemes were deducted from the experimental emission spectra and the crystal field simulation has been performed. The maximum splitting of the {sup 7}F{sub 1} manifold of the Eu{sup 3+} ion as a function of N{sub v}, the so-called crystal field strength parameter, is given. This allows us to classify the compounds according to their crystal field extent. (author) 11 refs, 8 figs, 2 tabs

1996-12-31

264

Simulation study of the influence of the ionospheric layer height in the thin layer ionospheric model  

British Library Electronic Table of Contents (United Kingdom)

This work aims to contribute to the understanding of the influence of the ionospheric layer height (ILH) on the thin layer ionospheric model (TLIM) used to retrieve ionospheric information from the GNSS observations. Particular attention is paid to the errors caused on the estimation of the vertical total electron content (vTEC) and the GNSS satellites and receivers inter-frequency biases (IFB), by the use of an inappropriate ILH. The work relies upon numerical simulations performed with an empirical model of the Earth?s ionosphere: the model is used to create realistic but controlled ionospheric scenarios and the errors are evaluated after recovering those scenarios with the TLIM. The error assessment is performed in the Central and the northern part of the South American continents, a re...

2011-01-01

265

Scientific perspectives on greenhouse problem. Part 2  

International Nuclear Information System (INIS)

The spectre of major climate change caused by the greenhouse effect has generated intensive research, heated scientific debate and a concerted international effort to draft agreements for the reduction of greenhouse gas emissions. This report of Scientific Perspectives on the greenhouse problem explains the technical issues in the debate in language readily understandable to the non-specialist. The inherent complexities of attempts to simulate the earth's climate are explained, particularly with regard to the effects of clouds and the circulation of the oceans, which together represent the largest factors of uncertainty in current global warming forecasts. Results of the search for the 'greenhouse signal' in existing climate records aredescribed in chapter 3 (part two). Chapter 5 (part two) develops a projection of 21st-century warming based on relatively firm evidence of the earth's actual response to known increases in greenhouse gas ...

266

Science & Technology Review July/August 2005  

Energy Technology Data Exchange (ETDEWEB)

This journal contains the following articles (1) The Grand Challenge of Thermonuclear Ignition--Commentary by Edward I. Moses; (2) Orchestrating the World's Most Powerful Laser--The computer control system for the National Ignition Facility will soon have about 1.4-million lines of code running on more than 750 computers; (3) A Randon Walk through Time and Space--Albert einstein's 1905 papers on Brownian motion, random fluctuations, and statistical mechanics are fundamental to many Livermore research projects; (4) The Search for Methane in Earth's Mantle--Scientists are discovering that Earth's mantle may have untapped reserves of methane; and (5) Testing the Physics of Nuclear Isomers--Results from a tri-laboratory project contradict claims of accelerated release of energy from the nuclear isomer hafnium-178.

2005-06-14

267

School of Earth and Environment  

Wastenet

... Project Details Title: Influence of increasing droplet concentrations on properties of stratocumulus clouds and climate Supervisor: Dr Alan Gadian Funded by: Engineering and Physical Sciences Research Council (EPSRC) Start date: October 2006 My project involves use of the UK Met Office Unified Model (UM) to calculate the global effect of modifying stratocumulus droplet concentrations on the earth's radiation balance, as well as use of ... Publications Latham, J; Rasch, P; Chen, CC; Kettles, L; Gadian, A; Gettelman, A; Morrison, H; Bower, K; Choularton, T (2008) Global temperature stabilization via controlled albedo enhancement of low-level maritime clouds, Philos. Trans. Roy. Soc. A, 366(1882), pp3969-3987. doi:10.1098/rsta.2008.0137 Current Students | Internal ...

268

Microstructure-property relationships in beryllia-ceramics sintered to near theoretical density  

Energy Technology Data Exchange (ETDEWEB)

The use of selective additives such as MgO as a sintering aid and a rare earth oxide as a grain growth inhibitor, has allowed the manufacture of beryllia ceramics having close to theoretical density. The grain size and grain size distribution can be controlled by an optimum firing schedule leaving a remnant porosity which is extremely fine (0.2 {mu}m). This structure is compared with conventional BeO ceramics, densified by liquid phase sintering, which develops a glassy grain boundary and retains large pores up to 3 {mu}m. The significantly improved strength properties, extremely fine pores,the 'pinning effect' of rare earth oxide, and the superior surface finish both in the as-fired and polished state are discussed in relation to the micro-structure. (orig.).

1989-01-01

269

Methodology for Rare Earth Element Determinations of Uranium Oxides by Ion Microprobe  

British Library Electronic Table of Contents (United Kingdom)

A methodology for the determination of the rare earth elements in uranium oxides by ion microprobe has been set up on a Cameca ims-3f instrument. An uranium oxide reference material from a syn-metamorphic uranium deposit related to albitisation has also been developed for this type of analysis. Applications of the methodology are presented for a series of uranium oxides selected from some major uranium deposit types: from the world's highest grade unconformity-related uranium deposit from the Athabasca Basin (Saskatchewan, Canada; the Shea Creek and the McArthur River examples), a perigranitic vein-type deposit (Pen Ar Ran, Vendee, France) and a volcanic caldera-related deposit (Streltsovkoye, Transbaikalia, Russia). Each type of uranium deposit appears to have a specific REE signature. Al...

2007-01-01

270

Light weight underground pipe or cable installing device  

Energy Technology Data Exchange (ETDEWEB)

This invention pertains to a light weight underground pipe or cable installing device adapted for use in a narrow and deep operating trench. More particularly this underground pipe installing device employs a pair of laterally movable gates positioned adjacent the bottom of the operating trench where the earth is more solid to securely clamp the device in the operating trench to enable it to withstand the forces exerted as the actuating rod is forced through the earth from the so-called operating trench to the target trench. To accommodate the laterally movable gates positioned adjacent the bottom of the narrow pipe installing device, a pair of top operated double-acting rod clamping jaws, operated by a hydraulic cylinder positioned above the actuating rod are employed.

1985-01-08

271

Investigation and analytical use of rare earth ionic associates with benzilic acid and rhodamine B  

International Nuclear Information System (INIS)

Ions of rare earth elements (r.e.e.) have been found to form with benzilic acid and rhodamine B precipitates hardly soluble in water and extractable by toluene. The conditions of La and Pr determination by extraction-spectrophotometry method are studied. Relative square deviation does not exceed 0.027 and 0.034 respectively. The method can be used for determination of other cerium sub-group r.e.e. in their salts and cannot be employed for determination of lighter r.e.e. in the presence of heavier r.e.e., because the latter form low soluble precipitates capturing the r.e.e. situated in the beginninq of the r.e.e. series.

1977-01-01

272

Introduction to 'MINEO' project of European community and its enlightenments to monitoring and assessment of environmental impacts caused by mining in China  

Energy Technology Data Exchange (ETDEWEB)

In order to promote environmental damage monitoring and environmental impacts assessment caused by mining in China, the most significant project that uses advanced Earth Observation technology to assess environmental impacts caused by mining, namely MINEO (assessment and monitoring the environmental impact of mining activities in Europe using advanced Earth Observation technology) was introduced and its enlightenment to China were investigated. It was proposed that an integrated technical framework of monitoring environmental impacts caused by mining be designed, quantitative inversion of biological and environmental parameters from RS data be emphasised, hyperspectral Remote Sensing be applied, RS and GIS be integrated with professional models, multi-object applications of RS be implemented, and related standards and specification be drawn up based on typical case study sites. 23 refs., 1 fig.

2008-01-15

273

Innovative methods of correlation and orbit determination for space debris  

Science.gov (United States)

We propose two algorithms to provide a full preliminary orbit of an Earth-orbiting object with a number of observations lower than the classical methods, such as those by Laplace and Gauss. The first one is the Virtual debris algorithm, based upon the admissible region, that is the set of the unknown quantities corresponding to possible orbits for a given observation for objects in Earth orbit (as opposed to both interplanetary orbits and ballistic ones). A similar method has already been successfully used in recent years for the asteroidal case. The second algorithm uses the integrals of the geocentric 2-body motion, which must have the same values at the times of the different observations for a common orbit to exist. We also discuss how to account for the perturbations of the 2-body motion, e.g., the J 2 effect.

2010-06-01

274

Improved model of high-latitude F-region scintillation (WBMOD version 13). Final report, 1 September 1993-31 August 1994  

Energy Technology Data Exchange (ETDEWEB)

Many modern military systems used for communications, command and control, navigation, and surveillance depend on reliable and relatively noise-free transmission of radiowave signals through the earth`s ionosphere. Small-scale irregularities in the ionospheric density can cause severe distortion, known as radiowave scintillation, of both the amplitude and phase of these signals. The WBMOD computer program can he used to estimate these effects on a wide range of systems. The objective of this study is to investigate improvements to the WBMOD model based on extensive data sets covering both the equatorial and high-latitude regimes. This report summarizes the work completed during the third year of this project, which includes completion of the new model for the high-latitude (auroral and polar cap) region of the WBMOD model.

1994-08-31

275

Gradiometry coexperiments to the gravity probe B and step missions  

Energy Technology Data Exchange (ETDEWEB)

The Gravity Probe-B (GP-B) spacecraft, designed to test predictions of general relativity, will fly in the mid 1990s. It will carry four electrostatically suspended gyroscopes in a cryogenic environment and will have a drag-free control system to minimize disturbances on the gyroscopes. The Stanford Test of Equivalence Principle (STEP) spacecraft, to fly later, will carry a set of test masses under very similar conditions. The possibility of using differential measurements of the GP-B gyroscopes suspension forces and the STEP tests mass displacement readout to form single-axis gravity gradiometers is explored. It is shown that the noise in the suspension systems is sufficiently small in the relevant frequency range, and that enough information is collected to compensate for the spacecrafts' attitude motion. Finally, using Breakwell's flat-earth approximation, these experiments are compared to other geodesy experiments and predict the contribution ...

1990-01-01

276

GPS and Google Earth based 3D assisted driving system for trucks in surface mines  

British Library Electronic Table of Contents (United Kingdom)

In order to reduce the number of surface mining accidents related to low visibility conditions and blind spots of trucks and to provide 3D information for truck drivers and real time monitored truck information for the remote dispatcher, a 3D assisted driving system (3D-ADS) based on the GPS, mesh-wireless networks and the Google-Earth engine as the graphic interface and mine-mapping server, was developed at Virginia Tech. The research results indicate that this 3D-ADS system has the potential to increase reliability and reduce uncertainty in open pit mining operations by customizing the local 3D digital mining map, constructing 3D truck models, tracking vehicles in real time using a 3D interface and indicating available escape routes for driver safety.

2010-01-01

277

Fractionation of isotopes of alkali metals and alkaline earth metals in ion exchange chromatography  

International Nuclear Information System (INIS)

Fractionation of isotopes of the alkali metals and the alkaline earth metals in ion exchange chromatography of their chlorides was studied. The heavier isotopes of potassium and rubidium were found to be preferentially fractionated into the ion exchanger phase while the lighter isotopes of lithium, magnesium, calcium and strontium were enriched in the exchanger phase. This can be interpreted as a resultant of the relative significance of isotope effect upon dehydration and isotope effect accompanying the phase change of the hydrated metal ion. Found was no evidence of anomalous isotope effect attributable to the odd-even difference in mass number of isotopes. Based on the spectroscopic and solution chemical data (experimental and theoretical), the isotopic reduced partition function ratios of the hydrated alkaline metal ions and stretching force constants of metal ion-hydrating water bonds were estimated. (author).

278

Determination of rare earths in eluates after chromatographic separation  

International Nuclear Information System (INIS)

Spectrophotometry was used to study the conditions under which three-component complexes are formed of rare-earth elements (REE) with aminopolycarboxylic complexes and #beta#-diketones; the molar extinction coefficients of the above REE complexes were also found. A procedure is suggested for determining REE in chromatographic eluates with lower boundary of the contents determined being at 0.6-1.5 #mu#g/ml (Pr, Nd, Ho and Er) and 5-7 #mu#g/ml (Sm and Tm) with account for oxides. Luminescent techniques were also suggested for determining terbium in the presence of EDTA and terbium in an eluate containing EDTA and oxyethyl ethylene diamine triacetic acid, both acids being characterized by a relative standard deviation equal to 0.015-0.03.

1977-01-01

279

Basic mechanisms of radiation effects in the natural space radiation environment  

Energy Technology Data Exchange (ETDEWEB)

Four general topics are covered in respect to the natural space radiation environment: (1) particles trapped by the earth`s magnetic field, (2) cosmic rays, (3) radiation environment inside a spacecraft, (4) laboratory radiation sources. The interaction of radiation with materials is described by ionization effects and displacement effects. Total-dose effects on MOS devices is discussed with respect to: measurement techniques, electron-hole yield, hole transport, oxide traps, interface traps, border traps, device properties, case studies and special concerns for commercial devices. Other device types considered for total-dose effects are SOI devices and nitrided oxide devices. Lastly, single event phenomena are discussed with respect to charge collection mechanisms and hard errors. (GHH)

1994-06-01

280

Atmospheric chemistry on Venus, Earth, and Mars: Main features and comparison  

British Library Electronic Table of Contents (United Kingdom)

This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO"2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO"2. O stimulates cooling by the emission at 15@mm in the collisions with CO"2. ...

2011-01-01

281

Are Stars with Planets Polluted?  

CERN Document Server

We compare the metallicities of stars with radial velocity planets to the metallicity of a sample of field dwarfs. We confirm recent work indicating that the stars-with-planet sample as a whole is iron rich. However, the lowest mass stars tend to be iron poor, with several having [Fe/H]0.48) that contributes to but does not explain the mass-metallicity trend in the stars-with-planets sample. We use Monte Carlo models to show that adding an average of 6.5 Earth masses of iron to each star can explain both the mass-metallicity and the age-metallicity relations of the stars-with-planets sample. However, for at least one star, HD 38529, there is good evidence that the bulk metallicity is high. We conclude that the observed metallicities and metallicity trends are the result of the interaction of three effects; accretion of about 6 Earth masses of iron rich material, selection effects, and in some cases, high intrinsic metallicity.

2002-01-01

282

2D SPH simulations of a single planet migration in a protoplanetary disc  

Science.gov (United States)

Migration of protoplanets inside an accretion disc of a forming star is the most probable scenario for planetary system formation according to current models. Unsolved problems exist, concerning migration times and mechanisms. We report here the results of a 2D hydrodynamic study within an SPH scheme, analysing migration of an Earth-like or a Jupiter-like planet inside an inviscid sub-Keplerian accretion disc, as a function of the initial specific angular momentum of the infalling accretion disc matter. Particle capture by the protoplanet causes a rapid migration, within a few orbits, for the Earth like planet, and about 104 orbits for the Jupiter like planets. The effect of a planet pseudo-atmosphere is also discussed.

2010-01-01

283

Structure and catalysis of highly dispersed hydrodesulfurization catalysts  

Energy Technology Data Exchange (ETDEWEB)

It is demonstrated that highly dispersed molybdenum sulfide catalysts are prepared by using Mo(CO){sub 6} adsorbed on the support. The structure of ultradispersed molybdenum sulfide is suggested by EXAFS techniques to be different from that of MoS{sub 2}. The TOF of the thiophene HDS is almost invariant with the dispersion of molybdenum sulfide at a high molybdenum dispersion, whereas the TOF of the hydrogenation greatly increases with increasing dispersion. On the basis of the HDS activity and optimum Co/Mo ratio of Co-Mo/Al{sub 2}O{sub 3} catalysts having a variety of molybdenum dispersion fabricated by using carbonyl complexes, it is demonstrated that highly active HDS catalysts are prepared by highly dispersing molybdenum sulfide phases. Edge decorations of molybdenum sulfides by cobalt are suggested for the synergy generation between cobalt and molybdenum sulfides. (orig.) [Deutsch] Unter Verwendung von auf dem Traeger adsorbierten ...

1994-12-01

284

Oxydehydrogenation of propane to propylene with metal molybdates  

Energy Technology Data Exchange (ETDEWEB)

Single and binary metal molybdates of the formula AMoO{sub 4}, where A=Ni, Co, Mg,Mn and/or Zn, were investigated for the oxydehydrogenation of propane to propylene, as well as some ternary molybdates of the formula NiO{sub 0.45}Co{sub 0.45}X{sub 0.066}MoO{sub 4} where X=P, Bi, Fe, Cr, V and Ce. All catalysts were supported on SiO{sub 2} with an active phase/support ratio of 80/20 (wt%). The reaction is catalytic and not a gas phase initiated reaction. It is first order in propane, consistent with the abstraction of the methylene hydrogen being the rate limiting step. Propane conversions and propylene yields vary greatly depending on the metal of the molybdate and surface area of the catalyst. Highest propylene yields (16% at 26.6% propane conversion) are obtained with NiMoO{sub 4}/SiO{sub 2}. Conversion and yield are significantly influenced by the molybdenum content of the compositions. The effect is biggest in the nickel molybdate system. Its optimum activity lies at the ...

1996-10-01

285

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

Energy Technology Data Exchange (ETDEWEB)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Two approaches have been adopted to get a stable cathode material. First approach is the use of LiNi{sub 0.8}Co{sub 0.2}O{sub 2}, a commercially available lithium battery cathode material and the second is the use of tape cast electrodes prepared from cobalt coated nickel powders. The morphology and the structure of LiNi{sub 0.8}Co{sub 0.2}O{sub 2} and tape cast Co coated nickel powder electrodes were studied using scanning ...

2002-04-01

286

Mechanisms of cobalt uptake in plants: {sup 60}Co uptake and distribution in Chara  

Energy Technology Data Exchange (ETDEWEB)

The mechanism of cobalt uptake was investigated using cells of the giant alga Chara corallina in which it is possible to resolve separately uptake by the cell wall and actual influx across the cell membrane. The absorption of {sup 60}Co by Chara cells appeared to saturate within 2 h. but this was mainly due to rapid uptake into the cell wall which accounted for 87-92% of the total activity. Even after prolonged desorption most of the cell-associated {sup 60}Co was found on the cell wall. The intracellular distribution of absorbed {sup 60}Co was investigated by fractionating the cell into cytoplasm and vacuole. It was shown that {sup 60}Co influx to the vacuole occurs simultaneously with influx to the cytoplasm. The transported species appears to be Co{sup 2+} rather than the less charged Co(OH){sup +} or Co(O){sub 2}. {sup 60}Co influx is pH dependent (optimum pH 7-9), and is sensitive to some other divalent metals. Influx from solutions containing 1 {mu}M {sup ...

1998-12-31

287

Mechanisms of cobalt uptake in plants: "6"0Co uptake and distribution in Chara  

International Nuclear Information System (INIS)

The mechanism of cobalt uptake was investigated using cells of the giant alga Chara corallina in which it is possible to resolve separately uptake by the cell wall and actual influx across the cell membrane. The absorption of "6"0Co by Chara cells appeared to saturate within 2 h. but this was mainly due to rapid uptake into the cell wall which accounted for 87-92% of the total activity. Even after prolonged desorption most of the cell-associated "6"0Co was found on the cell wall. The intracellular distribution of absorbed "6"0Co was investigated by fractionating the cell into cytoplasm and vacuole. It was shown that "6"0Co influx to the vacuole occurs simultaneously with influx to the cytoplasm. The transported species appears to be Co"2"+ rather than the less charged Co(OH)"+ or Co(O)_2. "6"0Co influx is pH dependent (optimum pH 7-9), and is sensitive to some other divalent metals. Influx from solutions containing 1 #mu#M "6"0Co was inhibited by 5 #mu#M Cd"2"+, ...

1998-01-01

288

Magnetic resonance imaging of stents. Quantitative in vitro examination at 3 Tesla; Magnetresonanztomographie von Stents. Quantitative MR-Untersuchungen in vitro bei 3 Tesla  

Energy Technology Data Exchange (ETDEWEB)

The aim of this study was to qualitatively and quantitatively study MR artifacts of various stents on the basis of in vitro experiments. We were particularly interested whether sequence type and orientation of the stent with respect to the static magnetic field influences the artifact. We examined 18 stents of different material (nitinol, stainless steel, cobalt alloy), different design of the stent meshes (AccuLink, OmniLink, DynaLink, Xact, Protoge, Wallstent Monorail), different diameter (5-10 mm) and different length (18-58 mm) with a turbo spin echo (TSE), a 2D-fast low angle shot (FLASH) and a 3D-FLASH sequence. The MR images were examined qualitatively with respect to possible artifacts. Furthermore we examined the MR data quantitatively: The contrast-noise-ratio (CNR) was determined both within the stent and outside (within the tube); based on these values we calculated the transparency factor P, furthermore we calculated the apparent vascular lumen within ...

2009-07-01

289

Evaluation of cobalt mobility in soils from the Nevada Test Site  

Energy Technology Data Exchange (ETDEWEB)

Nuclear testing at and around the Nevada Test Site (NTS) resulted in widespread contamination from transuranic and other radionuclides, as well as from other toxic inorganic and organic contaminants. The type of contamination, including spatial distribution and type of radionuclides present, depends on the type of testing performed. Remediation of the contaminated areas is currently under way. The optimum in situ or ex situ remediation technology depends on the degree of interaction between the particular radionuclide, or contaminant in general, and the soil matrix, among other factors. The objective of this project was to evaluate the sorption affinity of NTS soils for common non-transuranic radionuclides. The sorption of cobalt (Co) on soils from two different areas of the NTS, namely the Little Feller and Cabriolet event sites, was studied. Experiments were conducted as a function of pH, solid concentration, total Co concentration, ionic strength, and particle ...

1996-09-01

290

Effect of thermal treatments on the properties of nickel and cobalt activated-charcoal-supported catalysts  

Energy Technology Data Exchange (ETDEWEB)

The effect of thermal pretreatment in N[sub 2] up to 723 K and the activation treatments in H[sub 2] and an inert atmosphere on the properties of Ni and Co activated-charcoal-supported catalysts were studied. Catalysts were characterized by means of N[sub 2] adsorption at 77 K, H[sub 2] chemisorption at room temperature, thermogravimetric analysis (TGA), X-ray diffraction (XRD), and transmission electron microscopy (TEM). The catalysts' activity and selectivity for acetone hydrogenation to 2-propanol under unusual and severe conditions (473 K and high overall acetone conversion) were also measured. TGA and XRD evidence was found for the charcoal-support-promoted NiO and CoO reduction to the metallic states when the catalysts were subjected to an inert atmosphere above 723 K caused a loss of acetone hydrogenation activity (calculated on a metal load basis) for both the Ni and Co activated-charcoal-supported catalysts, with respect to that of the low-temperature (573 K) ...

1994-02-01

291

Decontamination of cesium, strontium, and cobalt from aqueous solutions by bentonite  

Energy Technology Data Exchange (ETDEWEB)

Sorption studies of cesium, strontium, and cobalt (Cs, Sr, and Co) on bentonite under various experimental conditions, such as contact time, pH, sorbent and sorbate concentration, and temperature, have been performed. The sorption data for all these metals have been interpreted in terms of Freundlich, Langmuir, and Dubinin-Radushkevich equations. Thermodynamics parameters, such as heat of sorption {Delta}H{degrees}, free energy change {Delta}G{degrees}, and entropy change {Delta}S{degrees}, for the sorption of these metals on bentonite have been calculated. The value of {Delta}H{degrees} shows that the sorption of Cs was exothermic, while the sorption of Sr and Co on bentonite were endothermic in nature. The value of {Delta}G{degrees} for their sorption was negative, showing the spontaneity of the process. The maximum loading capacity of Cs, Sr, and Co were 75.5, 22, and 27.5 meq, respectively, for 100 g of bentonite. The mean free energy E of Cs, Sr, and Co ...

1996-12-31

292

Cobalt and organics removal effect using fiber filter/reverse osmosis combination process for LLRW from korean PWR NPP  

Energy Technology Data Exchange (ETDEWEB)

Evaporation system for liquid radioactive waste process has been used in Korean PWR nuclear power plants. The system is the most desirable process for decontamination factor (DF) theoretically. However, during the operation of the system, various problems have been arising such as scaling, carry over, etc. Because these problems make DF low, advanced technologies for liquid radwaste process have been world widely developed instead of keeping evaporation system. The main goal of new technologies is ALARA, ease of operation, cost effectiveness and minimization of environmental effect. Korea Electric Power Corporation is currently developing a combined treatment process for liquid radwaste using Micro-filter, Ultra-filter, Reverse Osmosis (RO) membrane, etc for the purpose of partly enhancement of evaporator and of having an alternative liquid radwaste process system for new reactors. As a part of the above project, the feasibility study using the Rolled Fiber-Filter (RFF) and RO membrane ...

2001-07-01

293

Catalyst for utilization of methane in selective catalytic reduction of NO{sub x}, Task 2.6  

Energy Technology Data Exchange (ETDEWEB)

Selective catalytic reduction (SCR) of nitrogen oxides(NO{sub x}) in flue gas or engine exhaust gas with hydrocarbons as the reductant has great potential for less expense, less pollution, and easier operation than SCR with ammonia. Methane is the preferred reducing gas because of its low cost and low toxicity. Stable, low-cost catalysts for SCR with methane are required to demonstrate this technology for controlling NO{sub x} emissions. Several cobalt and nickel catalysts on synthetic clay and uranium oxide supports were investigated for their activities in reducing NO{sub x} with methane in the presence of air. The efficiency of the synthetic clay-supported nickel and cobalt catalysts for nitric oxide (NO) reduction with methane as the reducing gas was poor. The nickel oxide-uranium oxide catalyst, which was chosen for its high stability, was also ineffective. Results from the two-step experiments conducted at two-temperatures produced some ...

1996-02-01

294

course - View our MSc Engineering in the Coastal Environment post graduate masters course\\  

Wastenet

... This course is jointly taught between the School of Civil Engineering and the Environment and the School of Ocean and Earth Sciences. Scholarships 2 UK/EU fees only Scholarships are available for the academic year 2010/11. Awards will be given on the basis of merit. Flexible part-time study route available Back to top Home | About Us | Prospective Students |...

295

Use of Eu"3"+ as an oxygen environment probe in alkali-alkaline earth-lanthanide phosphates with the #beta#-K_2SO_4 structure  

International Nuclear Information System (INIS)

The use of europium as a local structural probe allows the various phases appearing in the NaCaPO_4-Na_3Eu(PO_4)_2 and NaSrPO_4-Na_3Eu(PO_4)_2 systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO_4 groups. (Auth.).

1983-09-01

296

Urban Atmospheric Science  

Environmental Research Database

DescriptionThis new research programme activity on Urban Atmospheric Science will deliver aspects of the NERC strategy: Next Generation Science for Planet Earth. It has been developed as part of the Environment, Pollution & Human Health theme. Research in the Environment, Pollution & Human Health theme is directed at elucidating key environmental processes that form part of a causal pathway between an environmental hazard and disease outcome, and providing a predictive capability of the risk to human heal [continued...

2012-01-01

297

Tribromo-chlorophosphonazo used for photospectrometric determination of total rare earth in high-level liquid waste  

International Nuclear Information System (INIS)

The Procedure determining the concentrations of total rare earth and their determination with a new reagent, tribromochlorophosphonazo (CPA-tB), that is 7-[1-(2, 4, 6-tribromo-phenyl) azo]-2-[1-(2-phosphono-4-chloro-phenyl) azo]-chromotropic acid, in high-level liquid waste and some characters of CPA-tB are studied. CPA-tB and its complexes of rare earth elements are stable in the glycol-H_2O system. Adding glycol shifts the absorption spectrum to left and increases the molar extinction coefficient. The molar extinction coefficients are respectively 7.16 x 10"4 (Y), 11.9 x 10"4 (La), 11.7 x 10"4 (Ce, Pr), 11.9 x 10"4 (Nd), 11.6 x 10"4 (Sm, Eu), 11.4 x 10"4 (Gd) and 11.4 x 10"4 (RE) in the glycol-H_2C_2O_4-H_3PO_4-H_2O system at 643 nm. Th interferes severely the determination of total rare earth, and other elements, U(<100 #mu#g), Al(<20 #mu#g), Fe(<400 #mu#g), Ni,Zr(<100 #mu#g respectively) and some anions, ...

1992-01-01

298

The trick with the heat pump; Der Trick mit der Waermepumpe  

Energy Technology Data Exchange (ETDEWEB)

The brochure reports on the construction and method of operation of heat pumps: - Efficiency and temperature difference - output figure - circuit processes - saving of primary energy - monovalent and bivalent plants - absorber, earth collectors - heat recovery. (HW) [Deutsch] Die Broschuere berichtet ueber den Aufbau und die Wirkungsweise von Waermepumpen: - Wirkungsgrad und Temperaturdifferenz - Leistungszahl - Kreisprozesse - Einsparung von Primaerenergie - monovalente und bivalente Anlagen - Absorber, Erdkollektoren - Waermerueckgewinnung. (HW)

1997-12-31

299

Solar effects on communications  

International Nuclear Information System (INIS)

This paper focuses on potential effects of solar phenomena on communication systems used by the electric utility industry. It begins with a discussion of solar phenomena fundamentals and discussion of the interaction between solar emissions and the earth's ionosphere and magnetosphere. It continues with a discussion of the resulting impacts on communication systems including radio, satellite, wireline, fiber optic, and powerline systems and concludes with a discussion of mitigation techniques and a call for observers to report suspected solar impact experiencexperiences.

300

Risk assessment for heavy ions of parts tested with protons  

International Nuclear Information System (INIS)

An internuclear cascade-evaporation code is used to model energy deposition in thin slabs of silicon. This model shows that protons produce a significant number of events with effective Linear Energy Transfer (LET) greater than 8 MeV cm"2/mg and demonstrates that proton testing of microelectronic components can be an effective way to screen devices for low earth orbit susceptibility to heavy ions.

1997-12-01

301

Report on the special program 78 satellite geodesy of the technical university of Munich  

Energy Technology Data Exchange (ETDEWEB)

Various topics include: (1) direction finding, (2) range finding, (3) Doppler measurements, (4) construction of a receiver for radio interferometry, (5) mobile laser range finding system, (6) figure-and field parameter determination/geopotential, (7) dynamics of the Earth-Moon system, and (8) kinematics of geodetic point fields.

1981-01-01

302

Rachel Cave  

Wastenet

... Rachel has also studied Geological Oceanography at the School of Ocean and Earth Sciences, University of Wales, Bangor, including a year spent at the Institute of Oceanographic Sciences Deacon Laboratory, Surrey, as a student researcher for the British Mid-Ocean Ridge Initiative (BRIDGE). Rachel has authored the following 1 Working Papers: 2002 ecm-2002-05 Towards Integrated Catchment/Coastal Management: Science, Policy ...

303

Presentation of twentieth century atmospheric carbon dioxide record in Smithsonian spectrographic plates  

Energy Technology Data Exchange (ETDEWEB)

The observed strength of the carbon dioxide absorption bands recorded on spectrobolograms of the transparency of the earth's atmosphere between wavelengths 300 and 2500 nanometers as part of the Smithsonian Solar Constant Program were used to extract the abundance of carbon dioxide in the atmosphere. The details of the analysis and the sources of error are discussed. 11 references, 5 figures, 1 table. (ACR)

1983-11-01

304

Port Pirie rare earths plant stage 3  

International Nuclear Information System (INIS)

SX Holdings Limited intends to establish a rare earths plant at Port Pirie, South Australia. The proposal involves three stages of development, Stage 3 being to develop a monazite cracking plant and associated rare earths separation facility with the capacity to process up to 8,000 t/a of monazite-type ores. The proposed initial capacity is 4,000 t/a. This Draft Environmental Impact Statement relates to Stage 3 and is based on a monazite processing capacity of 8,000 t/a. The justification of the project is given in terms of use and the market for rare earths, the economic and environmental benefits of the proposal, the site selection process, site rehabilitation, and the consequences of not proceeding. A detailed description of the project is given, including the treatment process, site development and facilities, the supply of raw materials, product and waste handling, transport and storage, plant commissioning, operation ...

305

Ozone layer  

Energy Technology Data Exchange (ETDEWEB)

Governments around the world will soon make decisions on policies that could determine the fate of the ozone layer-the Earth's shield from harmful ultraviolet radiation. The Vienna Convention for the Protection of the Ozone Layer, signed on March 22, 1985, created a framework for scientific cooperation and information exchange that will form the basis for a protocol for controlling substances thought to threaten the ozone layer. As of mid-1987, 29 countries had signed the Convention, including the major producers and users of chlorofluorocarbons (CFCs), the most important of suspect chemicals.

1987-12-01

306

Our campuses :: University of Southampton  

Wastenet

... The National Oceanography Centre, Southampton is one of the world's leading research centres for the study of ocean and earth sciences. Southampton General Hospital One of the country's leading teaching hospitals and the base for the University's School of Medicine. Winchester School of Art Founded in 1863, Winchester School of Art is based 12 miles (20 kilometres) north of Southampton in the historic city of Winchester,...

307

Optical spectroscopy of uranium monochalcogenides and monopnictides  

International Nuclear Information System (INIS)

The optical properties of uranium monochalcogenides and monopnictides are discussed in terms of their electronic structure. A comparison is made with corresponding rare earth compounds. It is shown that there are close similarities to mixed valence CeN. the results support the occurrence of a dip in the density of d states near Esub(F), where the f density of states has its maximum. Empirical energy level schemes are derived which are found to agree with the existing information from XPS measurements and recent theories. (orig.).

1980-12-01

308

On the effect of misch metal addition on corrosion behaviour of aluminium in inorganic and organic acids  

Energy Technology Data Exchange (ETDEWEB)

The effect of small misch metal additions (0.25 to 1 wt.%) on the corrosion behaviour of aluminium was studied through electrochemical polarization in 0.1 N inorganic and organic acids at room temperature. It has been observed that rare earth addition improves the corrosion resistance of aluminium. (orig.).

1992-10-01

309

Nuclear Thermal Propulsion engine based on Particle Bed Reactor using light water steam as a propellant  

Energy Technology Data Exchange (ETDEWEB)

In this paper the possibility of configuring a water cooled Nuclear Thermal Propulsion (NTP) rocket, based on a Particle Bed Reactor (PBR) is investigated. This rocket will be used to operate on water obtained from near earth objects. The conclusions reached in this paper indicate that it is possible to configure a PBR based NTP rocket to operate on water and meet the mission requirements envisioned for it. No insurmountable technology issues have been identified.

1993-06-01

310

NAME=\\  

Wastenet

... Electro-Osmotic Pulse (EOP) technology forces moisture to flow through concrete surfaces against the hydraulic gradient when an electric field is applied to an embedded anode system. This flow is initiated by the movement of cations (positively charged ions) present in a porous medium such as concrete toward the negative earth. Water surrounding the cations moves with them. The Corps of Engineers owns and maintains many buried ...

311

Monitoring for Xenon Radionuclides and CTBT Verification  

International Nuclear Information System (INIS)

The Comprehensive Nuclear-Test-Ban-Treaty (CTBT), which was opened for signature in 1996, bans all nuclear explosions in all environments. Republic of Korea has been working to monitor compliance with CTBT by deterring and detecting any nuclear explosions conducted anywhere on Earth. For the verification of CTBT, several techniques are implemented. Radionuclide monitoring is of particular importance since it is the only method which can provide absolute assurance that a nuclear detonation has occurred

2010-10-01

312

Manitoba Hydro's earth power program and Manitoba market update  

International Nuclear Information System (INIS)

An outline of Manitoba Hydro's Earth Power program was presented. Details of the heat pump market in Manitoba were provided, including details of residential and commercial sales. Total residential heat pump sales amounted to 577 units in 2004, equivalent to over $11.2 million in sales. Commercial installations amounted to approximately $12.7 million. An outline of industry players was presented. The goals of Manitoba Hydro were outlined in relation to geothermal energy and the Power Smart program. Their objectives included increasing awareness of geothermal energy, making heat pumps more accessible, and improving industry infrastructure. Other objectives included educating the public about life-cycle cost implications, residential loans and commercial incentives. To date, the residential power loan has provided financing to over 300 Manitoba home owners for installations, with electrical savings of over 1.34 Gwh and natural gas savings of 279,425 m"3. The program ...

2005-02-24

313

Major directions for prospecting and exploration by the Azneft' association in the eleventh five-year plan  

Energy Technology Data Exchange (ETDEWEB)

In accordance with the comprehensive plan in the eleventh five-year period the main content of prospecting and exploration on land in Axerbaidzhan by the Axneft' association will be done in the central and Western regions of the republic, where Paleogene-Mesozoic deposits will be inspected. Discussed in detail are the directions and volumes of prospecting and exploration in individual regions of Azerbaidzhan. They are determined with consideration of the degree of exploration of the earth's interior, the prospects for the deposits comprising them, and the development of the resources of oil.

1981-01-01

314

MILSTAR/FEP (FLTSATCOM EHF package) emphemeris package  

Science.gov (United States)

Design constraints require that as Earth terminal attempting communications with a FLTSATCOM EHF Package (FEP) located onboard a FLTSATCOM satellite be provided with an accurate FEP package. To be precise, the terminal is provided with a coefficient element set from which the ephemeris of a satellite may be computed. This report describes the operation of a user friendly computer program that produces the above mentioned coefficient set so as to provide reference benchmarks from which the ephemeris related operations of the terminal can be judged.

1986-08-01

315

Indirect Dark Matter Detection with Cosmic Antimatter  

CERN Document Server

The indirect detection of particle dark matter (DM) is based on the search for anomalous components in cosmic rays (CRs) due to the annihilation of DM pairs in the galactic halo, on the top of the standard astrophysical production. These additional exotic components are potentially detectable at Earth as spectral distortions for the various cosmic radiations: $\\chi + \\chi \\to q \\bar{q}, W^+ W^-, ... \\to \\bar{p}, \\bar{D}, e^+ \\gamma and \

2010-01-01

316

Hydrothermal synthesis of tobermorite/hydroxyapatite composites  

British Library Electronic Table of Contents (United Kingdom)

A tobermorite/hydroxyapatite composite was prepared by hydrothermal treatment using diatomaceous earth, ?-tricalcium phosphate and slaked lime starting materials. The XRD patterns of the composite confirmed that tobermorite and hydroxyapatite were formed after the hydrothermal process. The bending strength of the composite reached a level higher than 9?MPa after the hydrothermal process. The development of the bending strength was due to the formation of tobermorite and hydroxyapatite during the hydrothermal process. The composite had a high specific surface area due to these newly formed crystals.

2008-01-01

317

High critical current superconducting tapes  

Energy Technology Data Exchange (ETDEWEB)

Improvements in critical current capacity for superconducting film structures are disclosed and include the use of a superconducting RE-BCO layer including a mixture of rare earth metals, e.g., yttrium and europium, where the ratio of yttrium to europium in the RE-BCO layer ranges from about 3 to 1 to from about 1.5 to 1.

2003-09-23

318

Geology and our future: summary of a workshop report  

Energy Technology Data Exchange (ETDEWEB)

This report highlights the significance of the geological sciences to the nation and to society. Discussions include understanding plate tectonics and surface processes, exploring the continental crust, ocean basins and the deep earth, applications of geology to social problems such as mineral resources, waste disposal, siting of critical facilities, geological hazards, water resources management, and coastal zones. The state of health of geological research is also discussed. (ACR)

1983-01-01

319

Friends of the Earth: Bike repair for dummies: Green Blog  

Wastenet

... My road safety has come a long way since a bus driver yelled 'Go and read the Highway Code!' at me in my first wobbly week. I've got over my bike theft paranoia and happily leave my trusty steed shackled to lampposts around London. And I've figured out the optimum skirt-length for pedaling - neither flasher short nor so long it gets stuck in the oily spokes. But ...

320

Forum: Science and Innovation for Sustainable Development - Problems and Solutions  

Wastenet

...ENSO Applications Center (PEAC) Institutional Affiliation: PEAC's core members are The National Oceanic and Atmospheric Administration - Office of Global Programs (NOAA/OGP) The NOAA National Weather Service - Pacific Region (NWS-PR), The University of Hawaii - School of Ocean and Earth Science and Technology UH/SOEST, The University of Guam - Water and Energy Research Institute (UOG/WERI), and a regional association of the USAPI Governments, the Pacific Basin ...

321

Faculties :: University of Southampton  

Wastenet

...Modern Languages Music Philosophy Faculty of Medicine Faculty of Medicine page Academic unit: Medicine Faculty of Natural and Environmental Sciences Faculty of Natural and Environmental Sciences page Academic units: Biological Sciences Chemistry National Oceanography Centre, Southampton Ocean and Earth Science Faculty of Physical and Applied Sciences Faculty of Physical and Applied Sciences page Academic units: Electronics and Computer Science Optoelectronics Research Centre Physics and Astronomy Faculty of Social and Human Sciences ...

322

Extraction-spectrophotometric determination of terbium in its mixture with lanthanum  

International Nuclear Information System (INIS)

A spectrophotometric study of the extraction with isobutanol of rare-earth elements in the form of complexes with quinoilizarin and N-benzene-N-phenylhydroxylamine has been made. The purpose of the study is to find out whether this reaction can be used in determining the concentration of elements in the presence of other rare-earth elements. In determining the relationship between the pH and light absorption the pH of the solution is measured after the extraction. The extraction of complexes begins at pH approximately 4 and reaches a maximum at pH7-8 (for La) and pH6-9 (for Er). The complexes underge decomposition when pH of the solution increased. The composition of complex compounds is determined by spectrophotometric methods for isomolar series, molar ratios and from the slope of logarithmic plots. Under optimal conditions (pH7.5) aAd at the measured ratio of the component for each ion of rare-earth elements, the molar ...

1975-01-01

323

Estimation of a stress field in the earth`s crust using drilling-induced tensile fractures observed at well WD-1 in the Kakkonda geothermal field; Kakkonda WD-1 sei de kansokusareta drilling induced tensile fracture ni yoru chikaku oryokuba no suitei  

Energy Technology Data Exchange (ETDEWEB)

This paper describes estimation of a stress field in the earth`s crust in the Kakkonda geothermal field. Formation micro imager (FMI) logging known as a crack detecting logging was performed in the well WD-1. This FMI logging has made observation possible on cracks along well axis thought to indicate size and direction of the crust stress, and drilling-induced tensile fractures (DTF). It was verified that these DTFs are generated initially in an azimuth determined by in-situ stress (an angle up to the DTF as measured counterclockwise with due north as a starting point, expressed in {theta}) in the well`s circumferential direction. It was also confirmed that a large number of cracks incline at a certain angle to the well axis (an angle made by the well axis and the DTF, expressed in {gamma}). The DTF is a crack initially generated on well walls as a result of such tensile stresses as mud pressure and thermal stress acting on the well walls during well excavation, ...

1997-05-27

324

Environmental Sciences Division annual progress report for period ending September 30, 1981  

Energy Technology Data Exchange (ETDEWEB)

Research programs from the following sections and programs are summarized: aquatic ecology, environmental resources, earth sciences, terrestrial ecology, advanced fossil energy program, toxic substances program, environmental impacts program, biomass, low-level waste research and development program, US DOE low-level waste management program, and waste isolation program.

1982-04-01

325

Effect of Atmospheric Conditions on LIBS Spectra  

Energy Technology Data Exchange (ETDEWEB)

Laser-induced breakdown spectroscopy (LIBS) is typically performed at ambient Earth atmospheric conditions. However, interest in LIBS in other atmospheric conditions has increased in recent years, especially for use in space exploration (e.g., Mars and Lunar) or to improve resolution for isotopic signatures. This review focuses on what has been reported about the performance of LIBS in reduced pressure environments as well as in various gases other than air.

2010-05-01

326

EcoEarth.Info Environment Links: Ocean/Information  

Wastenet

... 01, 2009 | Rate It Marine Technology Society https://www.mtsociety.org/home.aspx emphasizes the importance of marine technology as it applies to global issues, encourages marine technology education and facilitates the use of marine technology in managing marine resources Added: Mar. 11, 2010 |...

327

EOP-MOD Ver 2.0 2444055.5 1.0 11875 UT1-TAI UNDEF # Earth ...  

Science.gov (United States)

... 2.3385 -27064396 0.0037 0.0030 15. .000 .000 .000 2449038.5 1.9466 2.3213 - 27066977 0.0037 0.0035 12. .000 .000 .000 2449039.5 1.9312 2.3064 -27069688 ...

328

Development and evaluation for passive dosimeter using several solid dosimeters  

International Nuclear Information System (INIS)

Passive dosimeters for personal and area radiation monitor in space have been developed mainly for dosimetry in low-earth-orbit (LEO) radiation environments of Space Shuttles and the International Space Station. The responses of several dosimeters have been evaluated by heavy ions and also its variation for individual dosimeter element. (author)

2005-05-01

329

Densities and molar volumes of molten alkaline earth bromide - alkali bromide salt mixtures  

International Nuclear Information System (INIS)

The temperature and concentration dependence of the densities of binary CaBr_2-(Li, Na, K, Rb, Cs)Br, NaBr-(Sr, Ba)Br_2 and KBr-SrBr_2 mixtures have been measured using the method of hydrostatic weighing. With exception of the systems LiBr-CaBr_2 and NaBr-(Sr, Ba)Br_2 the calculated molar excess volumes are positiv in the investigated mixtures. (author).

1980-01-01

330

Crystal field in RNiAl compounds studied by inelastic neutron scattering  

Energy Technology Data Exchange (ETDEWEB)

We present a study of the crystal field in PrNiAl, NdNiAl, ErNiAl and ErCuAl intermetallic compounds based on inelastic neutron spectroscopy. These compounds crystallize in the ZrNiAl-type hexagonal structure with an orthorhombic symmetry on rare-earth sites. The results are compared with the specific-heat data, and the lower parts of the crystal-field energy-level schemes are determined. (orig.)

2002-07-01

331

Crystal field in RNiAl compounds studied by inelastic neutron scattering  

International Nuclear Information System (INIS)

We present a study of the crystal field in PrNiAl, NdNiAl, ErNiAl and ErCuAl intermetallic compounds based on inelastic neutron spectroscopy. These compounds crystallize in the ZrNiAl-type hexagonal structure with an orthorhombic symmetry on rare-earth sites. The results are compared with the specific-heat data, and the lower parts of the crystal-field energy-level schemes are determined. (orig.)

2002-01-01

332

Coastal metabolism and the oceanic organic carbon balance  

Energy Technology Data Exchange (ETDEWEB)

The metabolism of organic matter in the coastal regions of the ocean may significantly affect the oceanic carbon budget. This paper describes the high percentage (30%) of oceanic oxidation that occurs in coastal areas and the impact of this metabolism on the carbon cycle and climate of earth. Organic metabolism in the ocean appears to be a source of carbon dioxide release into the atmosphere. Oxidation in the coastal zone is of special interest, as it is likely influenced by anthropogenic activity. Recommendations for future research on this topic are proposed. 129 refs., 2 figs., 6 tabs.

1993-02-01

333

CRC handbook of physical properties of rocks. Volume III  

Energy Technology Data Exchange (ETDEWEB)

This book presents topics on: Density of rocks and minerals, includes histograms of density ranges; elastic constants of minerals, elastic moduli, thermal properties; inelastic properties, strength and rheology for rocks and minerals, rock mechanics and friction, and stress-strain relations; radioactivity, decay constants and heat production of isotope systems in geology; seismic attenuation, in rocks, minerals, and the earth, with application to oil exploration and terrestrial studies; and index.

1984-01-01

334

CCMAP Contract  

Environmental Research Database

DescriptionCEH - Quest CCMAP see http://quest.bris.ac.uk/research/themes/CCMAP.html CCMAP (Climate-carbon modelling, assimilation and prediction) Leader: Dr. Eleanor Blyth (CEH, Wallingford) Overview and Goals CCMAP is one of QUEST's Theme 1 projects and is about to be commissioned to the Centre for Ecology and Hydrology at Wallingford. The Principal Investigator will be Dr. Eleanor Blyth, with subcontracts to the Universities of Bristol (Dr. Wolfgang Knorr, Earth Sciences and QUEST; Andy Ridgw [continued...

335

Atmospheric environmental implications of propulsion systems  

Energy Technology Data Exchange (ETDEWEB)

Three independent studies have been conducted for assessing the impact of rocket launches on the earth`s environment. These studies have addressed issues of acid rain in the troposphere, ozone depletion in the stratosphere, toxicity of chemical rocket exhaust products, and the potential impact on global warming from carbon dioxide emissions from rocket launches. Local, regional, and global impact assessments were examined and compared with both natural sources and anthropogenic sources of known atmospheric pollutants with the following conclusions: (1) Neither solid nor liquid rocket launches have a significant impact on the earth`s global environment, and there is no real significant difference between the two. (2) Regional and local atmospheric impacts are more significant than global impacts, but quickly return to normal background conditions within a few hours after launch. And (3) vastly increased space launch activities equivalent to 50 ...

1995-03-01

336

Amazon.com: Products tagged with intelligence  

Wastenet

...book recommendations (46) brain (50) brilliant (32) bush (41) business (59) christianity (34) cia (348) cognitive psychology (40) cognitive science (60) cold war (100) communism (37) conspiracy (47) counterintelligence (61) covert operations (58) creativity (57) decision making (32) dvd (35) earth (155) economics (53) education (76) espionage (492) ethics (163) evolution (50) fbi (74) fiction (52) finance (32)...

337

Adsorption of di-2-ethylhexylphosphoric acid from toluene the interface with inorganic salt aqueous solutions  

International Nuclear Information System (INIS)

Interfacial tension in the system toluene solution of di-2-ethylhexylphosphoric acid HDEHP-aqueous solutions of inorganic salts has been measured by the drop volume method. The ion-exchange constants in the monolayers formed by HDEHP and alkaline-earth metals have been measured.

338

European Space Agency announces contest to "Name the Cluster Quartet"  

Science.gov (United States)

1. Contest rules The European Space Agency (ESA) is launching a public competition to find the most suitable names for its four Cluster II space weather satellites. The quartet, which are currently known as flight models 5, 6, 7 and 8, are scheduled for launch from Baikonur Space Centre in Kazakhstan in June and July 2000. Professor Roger Bonnet, ESA Director of Science Programme, announced the competition for the first time to the European Delegations on the occasion of the Science Programme Committee (SPC) meeting held in Paris on 21-22 February 2000. The competition is open to people of all the ESA member states (*). Each entry should include a set of FOUR names (places, people, or things from history, mythology, or fiction, but NOT living persons). Contestants should also describe in a few sentences why their chosen names would be appropriate for the four Cluster II satellites. The winners will be those which are considered most suitable and relevant for the Cluster II mission. ...

2000-02-01

339

Volume reduction of reactor wastes by spray drying  

International Nuclear Information System (INIS)

Three simulated low-level reactor wastes were dried using a spray dryer-baghouse system. The three aqueous feedstocks were sodium sulfate waste characteristic of a BWR, boric acid waste characteristic of a PWR, and a waste mixture of ion exchange resins and filter aid. These slurries were spiked with nonradioactive iron, cobalt, and manganese (representing corrosion products) and nonradioactive cesium and iodine (representing fission products). The throughput for the 2.1-m-diameter spray dryer and baghouse system was 160-180 kg/h, which is comparable to the requirements for a full-scale commercial installation. A free-flowing, dry product was produced in all of the tests. The volume reduction factor ranged from 2.5 to 5.8; the baghouse decontamination factor was typically in the range of 10"3 to 10"4. Using an overall system decontamination factor of 10"6, the activity of the off-gas was calculated to be one to two orders of magnitude less than the nuclide release ...

340

Trace metal characterization of the U-Al matrix by atomic spectroscopy  

International Nuclear Information System (INIS)

Uranium-aluminum alloys with a significant enrichment of uranium with "2"3"3U or "2"3"5U serve as nuclear fuels in research reactors. The quality assurance of this fuel requires, among other things, precise knowledge that all trace metal constituents that affect neutron economy, fuel integrity, and fuel fabrication process parameters are well within the specification limits. Trace metal characterization of "2"3"5U-Al alloy has been carried out by atomic spectrometry. The trace metal constituents of interest are grouped into common metals (silver, boron, calcium, cadmium, cobalt, chromium, copper, iron, magnesium, manganese, molybdenum, sodium, nickel, lead, silicon, tin, titanium, vanadium, tungsten, and zinc) and lanthanides (cerium, dysprosium, europium, gadolinium, holminium, lutetium, samarium, and terbium). The elements yttrium and zirconium are grouped with the latter in view of the chemical separation procedure used. The alloy samples are dissolved in 6 M ...

341

Thermal expansion of gamma irradiated nylon 66 from 10 K to 340 K  

Energy Technology Data Exchange (ETDEWEB)

Samples of nylon 66 rods were irradiated using a cobalt-60 gamma ray source at a dose rate of 0.25 Mrad h[sup -1] in air at room temperature to a maximum dose of 500 Mrad. The linear coefficient of thermal expansion ([alpha]) was measured using a three-terminal capacitance technique reported previously. The variation of [alpha] with temperature between 10 K and 340 K was investigated for an unirradiated sample and two samples irradiated to 300 Mrad and 500 Mrad. In the range 10K to 160K, [alpha] is almost invariant with radiation dose and there is little difference between the values for the unirradiated and the 300 Mrad irradiated samples above 160 K. The sample irradiated to 500 Mrad does show a 6% increase in [alpha] over the other samples in the higher temperature range. All samples show an increase overall in the value of [alpha] with temperature. The melting point of each sample was also determined and was shown to decrease with radiation dose. (1 figure, 1 ...

1994-08-15

342

The effect of irradiation on packaging materials  

International Nuclear Information System (INIS)

Ionizing radiation, mainly in the form of #gamma#-rays from the radioisotope cobalt 60, is being used increasingly for the inactivation of contaminants in cosmetic and toiletry preparations. The treatment is applied to the product in its final pack, and therefore, it is important to recognize that the properties of the packaging materials could be affected, particularly if high radiation doses are used. The stability of a wide range of materials is discussed. The nature and extent of chemical and physical changes in plastics very much depends on the presence of antioxidants and other additives, and on the environmental conditions during irradiation. Some useful information is available from research into the use of radiation for the preservation of food - many films and laminates have been cleared for use in the United States. The low radiation doses used for the control of contaminants in cosmetic products are quite unlikely to cause changes in packaging materials ...

343

The Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama  

Science.gov (United States)

The investigation of various Two-Stage Liquefaction (TSL) process configurations was conducted at the Wilsonville Advanced Coal Liquefaction R D Facility between July 1982 and September 1986. The facility combines three process units. There are the liquefaction unit, either thermal (TLU) or catalytic, for the dissolution of coal, the Critical Solvent Deashing unit (CSD) for the separation of ash and undissolved coal, and a catalytic hydrogenation unit (HTR) for product upgrading and recycle process solvent replenishment. The various TSL process configurations were created by changing the process sequence of these three units and by recycling hydrotreated solvents between the units. This report presents a description of the TSL configurations investigated and an analysis of the operating and performance data from the period of study. Illinois No. 6 Burning Star Mine coal Wyodak Clovis Point Mine coal were processed. Cobalt-molybdenum and disposable iron-oxide ...

1990-05-01

344

Synthesis, characterization and biological evaluation of mononuclear Co(II), Ni(II), Cu(II) and Pd(II) complexes with new N2O2 Schiff base ligands.  

Science.gov (United States)

New tetradentate N(2)O(2) donor Schiff bases and their mononuclear Co(II), Ni(II), Cu(II), and Pd(II) complexes were synthesized and characterized extensively by IR, (1)H-, (13)C-NMR, mass, ESR, conductivity measurements, elemental and thermal analysis. Specifically the magnetic and electronic spectral measurements demonstrate the octahedral structures of cobalt(II), nickel(II) complexes and square planar geometries of copper(II), palladium(II) complexes. All the ligands and complexes were screened for their in vitro antibacterial activity against two gram-positive bacteria (Bacillus subtilis, Staphylococcus aureus) and two gram-negative bacteria (Escherichia coli, Klebsiella pneumonia). In this study, Pd(II) complexes exhibited potent antibacterial activity against B. subtilis, S. aureus whereas other metal complexes also exerted good activity towards all tested strains even than standard drugs streptomycin and ampicillin. PMID:21297294

2011-02-01

345

Sintering of nano-sized WC-Co powders produced by a gas reduction-carburization process  

Energy Technology Data Exchange (ETDEWEB)

Nanocrystalline cemented tungsten carbide has attracted considerable interests for use in cutting tool because of its superior mechanical properties. In this study, nano-sized powders of mixed WC and Co were prepared from attrition-milled oxides by a gas reduction-carburization process. The effects of compacting pressure, heating schedule, additional ball-milling, and the presence of a grain growth inhibitor on the sintering properties of the nano-sized WC-Co powders were examined. The grain size and phases in WC-Co alloy were clearly affected by compacting pressure. Because of the trapped gases and the lower melting point of the cobalt binder, when a compact of nano-sized WC-Co powder was sintered through a heating schedule with holding steps, the sintered alloy maintained the small size of WC grains without any {eta} phase. In addition, the additional ball-milling improved the microstructure and mechanical properties of the nano-sized WC-Co powder by producing a ...

2006-08-10

346

Sintering of nano-sized WC-Co powders produced by a gas reduction-carburization process  

International Nuclear Information System (INIS)

Nanocrystalline cemented tungsten carbide has attracted considerable interests for use in cutting tool because of its superior mechanical properties. In this study, nano-sized powders of mixed WC and Co were prepared from attrition-milled oxides by a gas reduction-carburization process. The effects of compacting pressure, heating schedule, additional ball-milling, and the presence of a grain growth inhibitor on the sintering properties of the nano-sized WC-Co powders were examined. The grain size and phases in WC-Co alloy were clearly affected by compacting pressure. Because of the trapped gases and the lower melting point of the cobalt binder, when a compact of nano-sized WC-Co powder was sintered through a heating schedule with holding steps, the sintered alloy maintained the small size of WC grains without any #eta# phase. In addition, the additional ball-milling improved the microstructure and mechanical properties of the nano-sized WC-Co powder by producing a ...

2006-08-10

347

Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material  

Energy Technology Data Exchange (ETDEWEB)

An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to ...

1996-01-01

348

Radiotherapy for ocular lesions by electron beam therapy  

Energy Technology Data Exchange (ETDEWEB)

Radiotherapy can be very significant as the treatment for ocular lesions, eyes need to be preserved as properly as possible on their functions and cosmetics. The application of conventional X ray therapy has been gradually abandoned as conventional X ray therapy ceased to be accepted as the general treatment for malignant tumors. Consequently the necessity of electron beam therapy has been rising even as the substituted method for conventional X ray therapy. The department of radiology of Gunma University was obliged to establish a new therapy for ocular lesions, and has been trying electron beam therapy since 1973. It is concluded that electron beam therapy is not at all inferior to conventional X ray therapy as reported above. Basic therapeutic methods for ocular lesions are the following: 1) For epidermoid carcinoma, 600 rads at a time, 3600 - 4200 rads in total is applied by 8 MeV electron twice a week method. 2) For malignant melanoma, 1000 rads at a time, 4000 - 5000 rads in ...

1981-11-01

349

Preparation of immission dust samples for the analysis of toxic substances in dust by atomic emission spectroscopy with inductively coupled plasma  

International Nuclear Information System (INIS)

Samples of air-dust-concentration- and air-dust-deposit measurements were digested by a standardized wet digestion procedure and the amounts of substances in the dust according to class I TA Luft by Atomic Emission Spectroscopy with Inductively Coupled Plasma (AES-ICP). The characteristic values for procedures according to VDI 2449, sheet 1, were determined for lead, vanadium, cadmium, chromium, copper, nickel and zinc. By partial automatic control of the digestion procedure the personel expenditure of work could be reduced by a factor 13. Dust filter samples were analysed without sample preparation by evaporating the material with a solid state laser. The absolute detection limit was between 1 and 100 ng/cm"2 for the elements arsenic, cadmium, cobalt, chromium, mercury, antimony, selen and thallium. For sampling by means of the Beta-Staubmeter the relative detection limits for the laser-ICP were 10-fold lower than by use of a nebulizer. (orig.).

350

Oxidation/sulfidation of material candidates for distributed solar receiver thermochemical transport program  

Energy Technology Data Exchange (ETDEWEB)

Metals for potential use in the dissociator and the synthesizer reactors of a distributed solar receiver thermochemical transport loop utilizing SO/sub 3//SO/sub 2//O/sub 2/ molecular chemistry includes stainless steels and iron-base, nickel-base and cobalt-base superalloys. We tested these alloys in SO/sub 2//O/sub 2/ mixtures and SO/sub 3/ gas at 500/sup 0/C and 900/sup 0/C, respectively, for times of up to four weeks. Weight gain measurements were used to determine the oxidation/sulfidation kinetics and electron microprobe analysis was used to measure penetration of oxygen and sulfur into the metal and to identify the formation of internal oxides and sulfides. Results of these tests showed that the most promising candidates are those containing sufficient quantities of both aluminum and chromium alloying additions to be alumina and chromia formers, such as Kanthal A-1, Nimonic 105 and Cabot 214.

1986-01-01

351

Mine dumps as a source of radon impact on buildings  

Energy Technology Data Exchange (ETDEWEB)

More than 100 old mine dumps active mine tailing ponds and granite quarries were investigated in South-West Germany to evaluate their potential impact on the environment caused by natural radioactive materials and by toxic metals. Five mine sites were monitored for a longer period according to their radon impact on the environment. They showed seasonal variations greater than a factor of 5 at some places. The annual mean radon concentration over granitic soil was found to be about 44 Bq.m/sup -3/ while very near the dumps more than 370 Bq.m/sup -3/ were usual. Radium concentrations up to 185 Bq.kg/sup -1/ were found in certain types of abandoned mine dumps. Some of the waste rock piles investigated are in the immediate neighbourhood of buildings and some old mine establishments are now used as homes. In these dwellings passive time integrating radon dosemeters have been exposed for up to a three month period. The average radon concentrations in the buildings influenced by mining ranged ...

1984-01-01

352

Microstructural and mechanical characterization of high energy ball milled and sintered WC-10wt%Co-xTaC nano powders  

British Library Electronic Table of Contents (United Kingdom)

Ultra fine tungsten carbide and cobalt powders were milled by high energy planetary ball mill at different ball to powder weight ratios (BPR) to produce particles of WC-10wt%Co hard metal in nanometer scale size. Microstructural characterizations by TEM show that the particle size of tungsten carbide was achieved to 32nm after milling at 15 BPR during 10h. In order to reduce the WC grain growth during the sintering process, tantalum carbide was added to the hard metal as a WC grain growth inhibitor. The nano hard metal powders were compacted at 200MPa pressure and sintered at 1370-1450degreeC temperatures in a high purity hydrogen atmosphere. The results show that the addition of 0.6wt% of TaC improves the hardness and fracture toughness from 1493 HV30 and 11.8MPam (for TaC free sample) to...

2009-01-01

353

Kinetics and mechanism of superoxide radical reactions with some biologically important compounds in aqueous solutions. Pulse radiolysis  

International Nuclear Information System (INIS)

Microsecond pulse radiolysis of oxygenated aqueous solutions containing 0.02 mol dm"-"3 sodium formate and 2 mmol dm"-"3 phosphate buffer at pH 7 was used to generate superoxide anion radicals. The influence of some biologically important compounds upon the rate of O_2"."-"b"a"r decay as monitored spectrophotometrically in the range of 245-300 nm. Hematoporphyrin (HP), hemin C (HC), catalase (Cat), cobalt sulfophthalocyanine (CoTSPc) were studied. Among the investigated compounds only Cat was found to show a high catalytic efficiency towards the self-decay of O_2"."-"b"a"r. A red shift of 0_2"."-"b"a"r absorption band and slowing down of its decay were observed to take place by adding HP or CoTSPc to the solutions containing formate ions in excess. This effect is associated with the formation of a transient superoxo-complex. An appearance of an intermediate species with absorption maxima at 350 nm and half-life of about 2 s was observed to accompany the ...

354

Incorporation of Reaction Kinetics into a Multiphase, Hydrodynamic Model of a Fischer Tropsch Slurry Bubble Column Reactor  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the development of a computational multiphase fluid dynamics (CMFD) model of the Fischer Tropsch (FT) process in a Slurry Bubble Column Reactor (SBCR). The CMFD model is fundamentally based which allows it to be applied to different industrial processes and reactor geometries. The NPHASE CMFD solver [1] is used as the robust computational platform. Results from the CMFD model include gas distribution, species concentration profiles, and local temperatures within the SBCR. This type of model can provide valuable information for process design, operations and troubleshooting of FT plants. An ensemble-averaged, turbulent, multi-fluid solution algorithm for the multiphase, reacting flow with heat transfer was employed. Mechanistic models applicable to churn turbulent flow have been developed to provide a fundamentally based closure set for the equations. In this four-field model formulation, two of the fields are used to track the gas phase (i.e., small spherical and ...

2008-11-01

355

Immobilization of stationary phases onto chromatographic supports by gamma radiation  

International Nuclear Information System (INIS)

Cobalt-60 gamma radiation has been found to be an effective means of immobilizing stationary phases onto gas and liquid chromatographic supports. The ability of a phase to crosslink was determined to be highly dependent on its chemical structure. Gamma radiation was employed to immobilize Se-30, a methylsilicone, and 216 PS onto Chromosorb WHP for packed column chromatography. The resultant columns exhibited increased thermal stability and a high degree of efficiency. Several blended phases containing varying ratios of Se-30:216 PS were also immobilized onto chromatographic packings. This work was further extended to the immobilization of Se-30 and 216 PS onto fused silica capillaries via gamma radiation. Columns exhibited excellent efficiency and improved thermal stability. An investigation into the role of immobilization of polymeric phases for HPLC was undertaken. Results indicate that gamma radiation can immobilzied polyoctadecylsiloxane and polyoctylsiloxane ...

356

Feasibility study of a new zinc-air battery concept using flowing alkaline electrolyte  

Energy Technology Data Exchange (ETDEWEB)

Proof-of-principle experiments are reported for a new concept in electrically rechargeable zinc-air battery. The zinc electrode is a porous flow-thru type using a copper foam metal substrate with zinc deposition onto the foam metal from concentrated zincate electrolyte (as used in zinc-slurry type batteries). The bifunctional air electrode employs low-cost materials, being fabricated entirely from carbon-based precursors and small amounts of nickel and/or cobalt oxide. Corrosion measurements on the graphite materials in the air electrode indicate sufficient corrosion resistance for 8000 h life on charge. A prototype single cell was constructed having 1.5 Ah capacity producing 1.2 V discharge -2.0 charge at the three hour rate and has produced stable voltages for more than 150 cycles. Based on the 1.5 Ah prototype characteristics, design calculations for a 32 kWh battery project an energy density of about 110 Wh/kg, peak power density of 140 W/kg, electrical ...

1986-04-01

357

Evaluation of the increase of superficial dose due to thermoplastic immobilizing in radiotherapy; Avaliacao dos efeitos de superficializacao de dose por imobilizadores termoplasticos em radioterapia  

Energy Technology Data Exchange (ETDEWEB)

Perforated thermoplastic masks are used to provide patients immobilization. This procedure inserts a material in the path of the radiation beam, that attenuates and modifies the beam fluence and flatness. The present study evaluates the increase in skin dose as a result of using thermoplastic masks. Relative doses were measured on the surface of a solid water phantom, in the presence and absence of masks. These masks were stretched according to deformation patterns observed in clinical routine. The measurements were obtained with a plane-parallel chamber (Markus type 23343) and radiochromic film (EBT Gafchromic) for 6MV X-rays from a linear accelerator, and for a radiation beam from a cobalt therapy unit. The results showed that thermoplastic masks, whose thickness varied between 2 and 3 mm, increased the dose on the surface by a factor of 3. Due to the variations in the skin dose distribution, clinical procedures were suggested to minimize radiobiological damages ...

2010-07-01

358

Evaluation of the increase of superficial dose due to thermoplastic immobilizing in radiotherapy  

International Nuclear Information System (INIS)

Perforated thermoplastic masks are used to provide patients immobilization. This procedure inserts a material in the path of the radiation beam, that attenuates and modifies the beam fluence and flatness. The present study evaluates the increase in skin dose as a result of using thermoplastic masks. Relative doses were measured on the surface of a solid water phantom, in the presence and absence of masks. These masks were stretched according to deformation patterns observed in clinical routine. The measurements were obtained with a plane-parallel chamber (Markus type 23343) and radiochromic film (EBT Gafchromic) for 6MV X-rays from a linear accelerator, and for a radiation beam from a cobalt therapy unit. The results showed that thermoplastic masks, whose thickness varied between 2 and 3 mm, increased the dose on the surface by a factor of 3. Due to the variations in the skin dose distribution, clinical procedures were suggested to minimize radiobiological damages ...

2010-08-18

359

Environmental monitoring carried out by an association: the citizen watchdog of radioactivity in the environment; La surveillance de l'environnement exercee par une association: l'observatoire citoyen de la radioactivite dans l'environnement  

Energy Technology Data Exchange (ETDEWEB)

ACRO, a NGO equipped with a laboratory to measure radioactivity, runs the Citizen Watchdog of Radioactivity in the Environment. Involving many volunteers, it monitors regularly the French coast of the Channel and many rivers of the North half of France. It also makes investigations in other places. Such an action is aimed to supplement the official monitoring, not to replace it, in order to answer to the worries of the population. This monitoring shows that some radioelements, such as iodine 129, cobalt 60, tritium, etc. released in the environment by nuclear facilities can be detected on very large areas. Carbon 14 was detected up to almost 4 times the background in vegetables around the reprocessing plant of La Hague. ACRO also sits in many official committees to transmit the point of view of the populations exposed to the radioactive pollution. It is lobbying for a decrease of the release authorization, especially for the elements that are discharged in large ...

2010-06-15

360

Effects of an acute dose of gamma radiation exposure on stem diameter growth, carbon gain, and biomass partitioning in Helianthus annuus  

Energy Technology Data Exchange (ETDEWEB)

Nineteen-day-old dwarf sunflower plants (Helianthus annuus, variety NK894) received a variable dose (0-40 Gy) from a cobalt-60 gamma source. A very sensitive stem monitoring device, developed at Battelle's Pacific Northwest Laboratories, Richland, Washington was used to measure real-time changes in stem diameter. Exposure of plants caused a significant reduction in stem growth and root biomass. Doses as low as 5 Gy resulted in a significant increase in leaf density, suggesting that nonreversible morphological growth changes could be induced by very low doses of radiation. Carbohydrate analysis of 40-Gy irradiated plants demonstrated significantly more starch content in leaves and significantly less starch content in stems 18 days after exposure than did control plants. In contrast, the carbohydrate content in roots of 40-Gy irradiated plants were not significantly different from unirradiated plants 18 days after exposure. These results indicate that ...

1988-05-25

361

Effect of gamma irradiation on the antimicrobial and free radical scavenging activities of Glycyrrhiza glabra root  

International Nuclear Information System (INIS)

The efficacy of gamma irradiation as a method of decontamination for food and herbal materials is well established. In the present study, Glycyrrhiza glabra roots were irradiated at doses 5, 10, 15, 20 and 25 kGy in a cobalt-60 irradiator. The irradiated and un-irradiated control samples were evaluated for phenolic contents, antimicrobial activities and DPPH scavenging properties. The result of the present study showed that radiation treatment up to 20 kGy does not affect the antifungal and antibacterial activity of the plant. While sample irradiated at 25 kGy does showed changes in the antibacterial activity against some selected pathogens. No significant differences in the phenolic contents were observed for control and samples irradiated at 5, 10 and 15 kGy radiation doses. However, phenolic contents increased in samples treated with 20 and 25 kGy doses. The DPPH scavenging activity significantly (p<0.05) increased in all irradiated samples of the plant.

2010-04-01

362

Effect of antioxidants on aging of nuclear plant cable insulation  

International Nuclear Information System (INIS)

The effects of various antioxidants and antioxidant concentrations on the radiation and thermal stability of EPDM and XLPE polymers used for insulation of electric cable in nuclear power plants were measured. The objective was to determine if particular antioxidants could be identified as being especially effective for stabilization against radiation aging and combined thermal and radiation aging. Elongation to rupture was used as the measure of stability. Materials were irradiated to doses up to 2 MGy (200 Mrad) at a dose rate of 200 to 300 Gy/h in the Cobalt-60 Gamma Irradiation Facility at the University of Virginia. All of the antioxidants tested, which were known to provide excellent thermal stability, also provided good stability for radiation aging and combined thermal/radiation aging, although small differences between antioxidants were noted. No antioxidant or antioxidant combination was identified as being especially outstanding. Stabilization against ...

363

Eco-profiling Inco Limited production : a case study  

Energy Technology Data Exchange (ETDEWEB)

Inco Ltd., a primary producer of nickel and an important producer of copper, cobalt, precious metals and sulphur products, initiated a project in 1997 to conduct eco-profiles of its worldwide metal production in an effort to improve its internal processing, marketing and environmental management. The study made it possible to recognize some internal and external benefits including the opportunity to gain operating efficiencies and improved process/product design, the development of better environmental performance indicators to guide decision making, and the availability of comprehensive product related environmental data to meet the informational needs of customers, designers, engineers and governments. This paper described the life cycle assessment (LCA) process used by Inco to conduct the study. A life cycle inventory (LCI) was used to quantitatively calculate resource requirements and environmental burdens associated with a product system over the life cycle of ...

2000-07-01

364

Dynamics of accumulation and disappearance of cobalt-60 in wheat-soil system  

International Nuclear Information System (INIS)

The dynamics of transportation, accumulation, disappearance and distribution of "6"0Co in the wheat-soil system was studied by using isotope-tracer techniques for simulated pollutants, and the mathematical model of the behavior was established. Rescilts showed that (1) "6"0Co was transported rapidly in the system after the application on soil surface layer. The uptake of "6"0Co by wheat was mainly via root, and redistribution in all parts of wheat occurred consequently. The concentration in root was much higher than that in other parts of wheat plant. The specific activity of "6"0Co in wheat plant rapidly increased to a maximum value, then decreased. The specific activity of "6"0Co in each part of wheat plant was found in the order of root > straw > husk > seed. (2) "6"0Co is mainly detained with in 6cm of soil surface, and specific activity of "6"0Co in soil present a simple exponential declining with depth of soil. (3) The dynamic law can be described as multinomial ...

2008-10-01

365

Diagnostic possibilities following implantation of carbon-fibre-reinforced plastic (CFRP) total hip arthroplasty  

International Nuclear Information System (INIS)

Introduction: There are many problems in the radiological diagnosis of aseptic loosening in total hip arthroplasty. Computed tomography (CT) and magnetic resonance tomography (MRT) are not usable for metallic implants (stainless steel, cobalt alloy, titanium alloy). Material and Methods: From April 1993 to December 1993 15 CFRP non-cemented hip prostheses have been implanted. In a prospective clinical study plane radiographs, CT and MRT have been analysed. Results: Three stems were revised (1 femoral fracture, 1 severe thigh pain, 1 aseptic loosening). CFRP are not visible in plane radiographs. There was a complete (two-third of the cases) or nearly complete (one-third of the cases) small sclerotic interface between the prosthesis and the bone, these were apparent in CT and MRT in stable implant cases and did not have any clinical correlations. Discussion: The small sclerotic interface is quite different in comparison to so called 'Reactive lines'. In one case of ...

366

Changes of hypoxia inducible factor-1 ? in hepatoma cells irradiated by gamma ray and their mechanism  

International Nuclear Information System (INIS)

This paper reports regulation of hypoxia inducible factor-1 ? (HIF-1 ?)in hepatoma cells by irradiation. Cobalt chloride (CoCl2), a chemical mimic agent for hypoxia research, was utilized to induce the stable expression of HIF-1 ? in HepG2 cells. The HepG2 cells were irradiated to different doses to observe the changes of HIF-1 ?. The level of intracellular reactive oxygen species (ROS) was assayed by fluorescent microscope and flow cytometry (FCM). The results showed that there were obvious changes in expression of HIF-1 ? after HepG2 cells exposed to radiation, and the changes were positively related with the irradiation dose from 1 Gy to 5 Gy. Moreover, contents of incellular ROS were negatively correlated with above levels of HIF-1 ? from 1 Gy to 3 Gy. The results indicate that irradiation may enhance hypoxic cells HIF-1 ?, and the reduction of intracellular ROS can contribute to the regulation of ionizing radiation on HIF-1 ?. (authors)

2007-10-01

367

Catalytic behavior of Co/(Nanob-Zeolite) bifunctional catalysts for Fischer-Tropsch reactions  

British Library Electronic Table of Contents (United Kingdom)

Cobalt supported on Beta zeolite catalysts were prepared by impregnation of metal salts in aqueous solution and were tested for the Fischer Tropsch reaction. The support consisted of a Beta zeolite composed by crystallites of nanometric dimensions and a SiO2/Al2O3 molar ratio of about 50. This support was impregnated with Co(NO3)2 aqueous solution using different metal loads of 7.5, 10, 15 and 20wt% Co. These materials were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), N2 adsorption (BET), thermal programmed reduction (TPR) and FTIR of adsorbed pyridine (i.e., surface acid sites distribution). All the catalysts showed a significant catalytic activity for the F-T reaction from synthesis gas (CO+2H2), in a continuous fixed bed reactor sys...

2011-01-01

368

Batch test equilibration studies examining the removal of Cs, Sr, and Tc from supernatants from ORNL underground storage tanks by selected ion exchangers  

Energy Technology Data Exchange (ETDEWEB)

Bench-scale batch equilibration tests have been conducted with supernatants from two underground tanks at the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to determine the effectiveness of selected ion exchangers in removing cesium, strontium, and technetium. Seven sorbents were evaluated for cesium removal, nine for strontium removal, and four for technetium removal. The results indicate that granular potassium cobalt hexacyanoferrate was the most effective of the exchangers evaluated for removing cesium from the supernatants. The powdered forms of sodium titanate (NaTiO) and cystalline silicotitanate (CST) were superior in removing the strontium; however, for the sorbents of suitable particle size for column use, titanium monohydrogen phosphate (TiHP {phi}), sodium titanate/polyacrylonitrile (NaTiO-PAN), and titanium monohydrogen phosphate/polyacrylonitrile (TiP-PAN) gave the best results and were about equally effective. ...

1995-06-01

369

Assessment of the historical trace metal contamination of sediments in the Elizabeth River, Virginia  

International Nuclear Information System (INIS)

Two sediment cores (Southern Branch, PC-1, and Western Branch, WB-2) were taken from the highly industrialized Elizabeth River, Virginia. The concentrations of trace metals cadmium, cobalt, chromium, copper, nickel, lead and zinc, major elements iron, manganese and aluminum, organic carbon content and the specific surface area of the sediments were determined in each of the cores. Down-core variations in metals varied significantly in each core with maximum contamination events occurring at different times in different portions of the river. In PC-1, maximum metal concentrations were seen after the appearance of "1"3"7Cs. In contrast, the highest levels in WB-2 occurred well before the appearance of "1"3"7Cs. Although stricter environmental regulations have caused a decrease in metal concentrations since the 1980s, the concentrations in the surface sediments of many trace metals were elevated to levels 2-5 times higher than the levels at the bottom of the cores in ...

2007-04-01

370

A small size continuous run industrial gamma irradiator  

Energy Technology Data Exchange (ETDEWEB)

A new small size gamma irradiator is being set up at Instituto de Pesquisas Energeticas e Nucleares (IPEN-CNEN/SP), Brazil, with a revolutionary design. The developed technology for this facility consists of continuous tote box transport system, comprising a single concrete vault, where the automated transport system of products inside and outside of the irradiator utilizes a rotating door, integrated with the shielding, avoiding the traditional maze configuration. Covering 76 m{sup 2} of floor area, the irradiator design is product overlap sources and the maximum capacity of Cobalt-60 wet sources is 37 PBq (1 MCi). The irradiator is being installed in a Governmental Institution and it will be used as a demonstration facility for manufacturers, who need an economic and logistic in-house irradiation system alternative. Also, it will be useful for supporting the local scientific community on development of products and process using gamma radiation, assisting the ...

2004-10-01

371

Transfer of elements into mother's milk; Transfer von Elementen in die Muttermilch  

Energy Technology Data Exchange (ETDEWEB)

This research project aimed to determine the factors for the transfer of the elements silver (Ag), cerium (Ce), cobalt (Co), chrome (Cr), gallium (Ga), lanthanum (La), molybdenum (Mo), niobium (Nb), radium (Ra), ruthenium (Ru), antimony (sb), thorium (Th), titanium (Ti) and uranium (U) from food into the mother's milk. This factors will be used as a basic to check and derive activity values for the contamination of food and for radiation protection at working places of suckling women. For this purpose 19 mothers collected samples daily (2-8 weeks), using the duplicate method, of all the food they consumed as well as of their milk. After microwave-assisted digestion the element contents were analysed by mass-spectroscopy with inductive coupled plasma (ICP-MS). The results of the mothers who participate for more than 5 weeks were used to make a time lapse between the intake and transfer of the elements in the mothers milk visible. (orig.) [German] Ziel ...

2000-08-01

372

64-slice multidetector coronary CT angiography: in vitro evaluation of 68 different stents  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study was to test a large sample of different coronary artery stents using four image reconstruction approaches with respect to lumen visualization, lumen attenuation, and image noise in 64-slice multidetector-row computed tomography (MDCT) in vitro and to provide a catalogue of currently used coronary artery stents when imaged with state-of the-art MDCT. We examined 68 different coronary artery stents (57 stainless steel, four cobalt-chromium, one cobalt-alloy, two nitinol, four tantalum) in a coronary artery phantom (vessel diameter 3 mm, intravascular attenuation 250 HU, extravascular density -70). Stents were imaged in axial orientation with standard parameters: 32x0.6 collimation, pitch 0.24, 680 mAs, 120 kV, rotation time 0.37 s. Four different image reconstructions were obtained with varying convolution kernels and section thicknesses: (1) soft, 0.6 mm, (2) soft, 0.75, (3) medium soft, 0.6, and (4) stent-optimized ...

2006-04-15

373

Visions of tomorrow: a focus on national space transportation issues; Proceedings of the Twenty-fifth Goddard Memorial Symposium, Greenbelt, MD, Mar. 18-20, 1987  

Science.gov (United States)

The present conference on U.S. space transportation systems development discusses opportunities for aerospace students in prospective military, civil, industrial, and scientific programs, current strategic conceptualization and program planning for future U.S. space transportation, the DOD space transportation plan, NASA space transportation plans, medium launch vehicle and commercial space launch services, the capabilities and availability of foreign launch vehicles, and the role of commercial space launch systems. Also discussed are available upper stage systems, future space transportation needs for space science and applications, the trajectory analysis of a low lift/drag-aeroassisted orbit transfer vehicle, possible replacements for the Space Shuttle, LEO to GEO with combined electric/beamed-microwave power from earth, the National Aerospace Plane, laser propulsion to earth orbit, and a performance analysis for a laser-powered SSTO ...

1987-01-01

374

Ultraviolet radiation in Finland  

Energy Technology Data Exchange (ETDEWEB)

Solar ultraviolet radiation is damaging for living organisms due to its high energy pro each photon. The UV radiation is often separated into three regions according to the wavelength: UVC (200-280 nm), UVB (280-320 nm) and UVA (320-400 nm). The most hazardous part, UVC is absorbed completely in the upper atmosphere by molecular oxygen. UVB radiation is absorbed by atmospheric ozone partly, and it is reaching Earth`s surface, as UVA radiation. Besides atmospheric ozone, very important factors in determining the intensity of UVB radiation globally are the solar zenith angle and cloudiness. It may be calculated from global ozone changes that the clear-sky UVB doses may have enhanced by 10-15 % during spring and 5-10 % during summer at the latitudes of Finland, following the decrease of total ozone between 1979-90. The Finnish ozone and UV monitoring activities have become a part of international activities, especially the EU Environment and Climate Programme`s ...

1996-12-31

375

Thermodynamic prediction of distribution coefficients for the solvent extraction of the rare earth metals  

International Nuclear Information System (INIS)

A thermodynamic model for predicting the distribution coefficients has been developed by taking into account the extraction mechanism and the chloride complexation when Sm, Eu, Gd, Tb, Dy and Ho for single component systems are extracted from acidic chloride solutions by di-2-ethylhexyl ester in kerosene, respectively. The model equation includes two constants, of which one corresponds to the apparent extraction equilibrium constant and the other is due to the variation of the activity coefficients of organic species. These values are determined from a few experimental data by the curve fitting method. Then, the distribution coefficients under untried calculations, Bromley's formulation is used to estimate the activity coefficients of aqueous species and the interaction parameters for some rare earth chlorides are reported in terms of morality and molarity using data from Spedding et al. According to the authors the validity of this method has been confirmed by ...

376

The potential of III-V semiconductors as terrestrial photovoltaic devices  

Energy Technology Data Exchange (ETDEWEB)

III-V semiconductors, GaAs and in particular InGaP, are used in many different electronic applications, such as high power and high frequency devices, laser diodes and high brightness LED. Their direct bandgap and high reliability make them ideal candidates for the realisation of high efficiency solar cells: in the past years they have been successfully used as power sources for satellites in space, where they are able to produce electricity from sunlight with an overall efficiency of around 30%. Nowadays, the use of arsenides and phosphides as photovoltaic (PV) devices is confined only to space applications since their price is much higher than conventional Si flat panel modules, the leading PV market technology. But with the introduction of multijunction solar cells capable of operating in high concentration solar light, the area and, therefore, the cost of these cells can be reduced and will eventually find an application and market also on Earth. This article ...

2006-07-01

377

The Magdalena Ridge Observatory 2.4 m Telescope  

Science.gov (United States)

EOS Technologies has been commissioned to design and build a unique 2.4m astronomical telescope for the Magdalena Ridge Observatory. This telescope utilizes a high quality primary mirror and cell from a now decommissioned military application. This paper describes the project and gives an overview of the telescope design. The Magdalena Ridge Observatory (MRO) 2.4 meter telescope will be primarily utilized to observe, track, and characterize solar system astronomical targets, Earth satellites, space vehicles, and terrestrial military targets. The telescope's rapid tracking (slew rates are 10o/sec) will allow it to move to any target and acquire data within one minute of receipt of notice. In this way, the telescope will be used to capitalize on targets of opportunity that occur in asteroid studies (e.g., Near Earth Objects) and in astrophysics, such as gamma ray bursts and other transient phenomena. Planned instrumentation includes a CCD imager, ...

2006-07-01

378

Survey of implementation plan constructed for `the New Earth 21 Project`; Chikyu saisei keikaku no jisshi keikaku sakusei ni kansuru chosa jigyo  

Energy Technology Data Exchange (ETDEWEB)

It is necessary to establish scenarios for reducing CO2 emissions and for developing CO2 emission control technologies to obtain a global consensus, using appropriate analytical models. For modification of the DNE-21 (Dynamic New Earth 21) model, it has a category designated as innovative technologies not involving CO2 emission and an optional consideration for the absorption of atmospheric CO2 by biomass. A global carbon circulation model, including vegetation in its scope, is also incorporated. Major results of the simulation are shown. When 20% reduction in CO2 emissions is required for only OECD countries after the year 2020, it has been demonstrated that CO2 concentration in the atmosphere will reach as high as about 900 ppm in 2100 due to CO2 emission by developing countries, and will not be a tolerable level. Under the condition that CO2 concentration in the atmosphere is controlled at 450 ppm in 2100, the amount of renewable source of energy from ...

1997-03-01

379

Study on the correlation between chemical and mineral composition of coal ashes; Sekitanbaibun no kobutsu soseigakuteki kento kagakubutsu sosei to kobutsugakuteki sosei no sokan  

Energy Technology Data Exchange (ETDEWEB)

Coal ash is a substance that has been mixed into minerals in the earth`s crust during their coalification process. Estimation was made on what kinds of mineral composition have been mixed into coals. Noted first was the kinds of compounds contained in the ash, wherein the ratios of mass in the compounds and minerals were correlated, and selection was made on minerals which are thought correlated. The selection criterion was based on minerals containing silica, alumina, iron oxide, lime and magnesium as compounds. Then, a phase equilibrium line diagram was used to estimate compositions and melting points of minerals which are thought to have been produced from these compounds. By comparing the estimation with the measured melting points of the ashes, mineral compositions thought reasonable were all selected. Assumption was possible on minerals that are thought to have been transferred into coal ash. Compound indications of ashes from 29 kinds of the world`s typical ...

1996-10-28

380

Study on the application of a geothermal heat pump; Etude sur l`application d`une pompe a chaleur geothermique  

Energy Technology Data Exchange (ETDEWEB)

The heating system of the `Centre integre de mecanique industrielle de la Chaudiere`, in Saint-Georges, Quebec, is based on a solar wall and a geothermal heat pump with a glycol/water mixture circulating in 44 wells that are 100 m deep. With installation costs below $25 per sq.m, more than 85 per cent of the heating needs of the 9500 sq.m centre were supplied by geothermal power. The geothermal heat pump is composed of a well field and two 211-kW cooling units, each equipped with four coiled compressors. In winter, heat is pumped from the earth and in summer, a heat exchanger with control valves allows to heat to be dumped back into the earth. The monitoring and simulation of the system proved its efficiency, considering the climatic conditions in Quebec. The annual consumption of geothermal heating is 0.146 GJ per sq.m, which is very low compared to the consumption of electric heating (0.286 GJ per sq.m) or oil heating (0.419 GJ per sq.m). 4 ...

1996-12-01

381

Space nuclear power requirements for ozone layer modification  

International Nuclear Information System (INIS)

This work estimates the power requirements for using photochemical processes driven by space nuclear power to counteract the Earth's ozone layer depletion. The total quantity of ozone (O_3) in the Earth's atmosphere is estimated to be about 4.7 x 10"3"7 molecules. The ozone production and destruction rates in the stratosphere are both on the order of 4.9 x 10"3"1 molecules/s, differing by a small fraction so that the net depletion rate is about 0.16 to 0.26% per year. The delivered optical power requirement for offsetting this depletion is estimated to be on the order of 3 GW. If the power were produced by satellite reactors at 800 km altitude (orbit decay time #approx# 300 years), some means of efficient power beaming would be needed to deliver the power to stratospheric levels (10--50 km). Ultraviolet radiation at 140--150 nm could have higher absorption rates in O_2 (leading to production of atomic oxygen, which can combine with O_2 to form ...

1992-01-13

382

Recommendations to the NRC for review criteria for alternative methods of low-level radioactive waste disposal: Task 2b: Earth-mounded concrete bunkers  

International Nuclear Information System (INIS)

The US Army Engineers Waterways Experiment Station (WES) and US Army Engineer Division, Huntsville (HNDED) have developed general design criteria and specific design review criteria for the earth-mounded concrete bunker (EMCB) alternative method of low-level radioactive waste (LLW) disposal. An EMCB is generally described as a reinforced concrete vault placed below grade, underneath a tumulus, surrounded by filter-blanket and drainage zones. The tumulus is covered over with a low permeability cover layer and top soil with vegetation. Eight major review criteria categories have been developed ranging from the loads imposed on the EMCB structure through material quality and durability considerations. Specific design review criteria have been developed in detail for each of the eight major categories. 63 refs., 13 figs., 2 tabs.

383

Reappraisal of solid selective emitters  

Energy Technology Data Exchange (ETDEWEB)

New rare earth oxide emitters show greater efficiency than previous emitters. As a result, based on a simple model the efficiency of these emitters was calculated. Results indicate that the emission band of the selective emitter must be at relatively low energy (less than or equal to .52 eV) to obtain maximum efficiency at moderate emitter temperatures (less than or equal to 1500 K). Thus low bandgap energy PV materials are required to obtain an efficient thermophotovoltaic (TPV) system. Of the 4 specific rare earths (Nd, Ho, Er, Yb) studied Ho has the largest efficiency at moderate temperatures (72 percent at 1500 K). A comparison was made between a selective emitter TPV system and a TPV system that uses a thermal emitter plus a band pass filter to make the thermal emitter behave like a selective emitter. Results of the comparison indicate that only for very optimistic filter and thermal emitter properties will the filter TPV system have a ...

1990-05-01

384

Rare-earth-rich tellurides: Gd_4NiTe_2 and Er_5M_2Te_2 (M=Co, Ni)  

International Nuclear Information System (INIS)

Three new rare earth metal-rich compounds, Gd_4NiTe_2, and Er_5M_2Te_2 (M=Ni, Co), were synthesized in direct reactions using R, R_3M, and R_2Te_3 (R=Gd, Er; M=Co, Ni) and single-crystal structures were determined. Gd_4NiTe_2 is orthorhombic and crystallizes in space group Pnma with four formula units per cell. Lattice parameters at 110(2)K are a=15.548(9), b=4.113(2), c=11.7521(15)A. Er_5Ni_2Te_2 and Er_5Co_2Te_2 are isostructural and crystallize in the orthorhombic space group Cmcm with two formula units per cell. Lattice parameters at 110(2)K are a=3.934(1), b=14.811(4), c=14.709(4)A, and a=3.898(1), b=14.920(3), c=14.889(3)A, respectively. Metal-metal bonding correlations were analyzed using the empirical Pauling bond order concept.

2004-11-01

385

Radiative performance of rare earth garnet thin film selective emitters  

Energy Technology Data Exchange (ETDEWEB)

In this paper the authors present the first emitter efficiency results for the thin film 40 percent Er-1.5 percent Ho YAG (Yttrium Aluminum Garnet, Y3Al5O12) and 25 percent Ho YAG selective emitter at 1500 K with a platinum substrate. Spectral emittance and emissive power measurements were made (1.2 less than lambda less than 3.2 microns). Emitter efficiency and power density are significantly improved with the addition of multiple rare earth dopants. Predicted efficiency results are presented for an optimized (equal power density in the Er, (4)I[sub 15/2]-(4)I[sub 13/2] at 1.5 microns, and Ho, (5)I[sub 7]-(5)I[sub 8] at 2.0 micron emission bands) Er-Ho YAG thin film selective emitter.

1994-08-01

386

Progress Report 2008: A Scalable and Extensible Earth System Model for Climate Change Science  

Energy Technology Data Exchange (ETDEWEB)

This project employs multi-disciplinary teams to accelerate development of the Community Climate System Model (CCSM), based at the National Center for Atmospheric Research (NCAR). A consortium of eight Department of Energy (DOE) National Laboratories collaborate with NCAR and the NASA Global Modeling and Assimilation Office (GMAO). The laboratories are Argonne (ANL), Brookhaven (BNL) Los Alamos (LANL), Lawrence Berkeley (LBNL), Lawrence Livermore (LLNL), Oak Ridge (ORNL), Pacific Northwest (PNNL) and Sandia (SNL). The work plan focuses on scalablity for petascale computation and extensibility to a more comprehensive earth system model. Our stated goal is to support the DOE mission in climate change research by helping ... To determine the range of possible climate changes over the 21st century and beyond through simulations using a more accurate climate system model that includes the full range of human and natural climate feedbacks with increased realism and ...

2009-01-01

387

Production of rare earth enriched isotopes and americium 242 using metallphthalocyanines  

International Nuclear Information System (INIS)

A technique of producing radioactive isotopes of rare earth elements (r.e.e.) and carrier free "2"4"2Am is suggested. The technique makes use of ''sandwich'' phthalocya=- nine complexes of r.e.e. and americium placed on sorbent. This is a new type of r.e.e. compounds and actinides (C_3_2H_1_6N_8)_2M (M is a metal ion) which are thermally, radiationally and chemically stable, dissolve well in some organic solvents and do not dissolve in water. Radiation and chemically stable activated carbon is used as a sorbent carrier. After irradiation the target is treated by a weakly acid solution or complex-former solution. Radioactive atoms formed due to (n, #gamma#)-reaction and desoleting the complex because of recoil transfer into the solution. When irradiating in the flux of 10"1"3 neutr./cm"2 x s for 1 hour it is possible to produce radioactive isotopes with the yield from 20 to 90%, for example "1"6"0Tb, "1"6"6Ho with enrichment factor > 100 and "2"4"2Am with ...

388

Photoluminescence properties and local electronic structures of rare earth-activated Sr3AlO4F  

British Library Electronic Table of Contents (United Kingdom)

Photoluminescence properties and local electronic structures of rare earth (Eu^3^+ and Ce^3^+) activated Sr3AlO4F have been studied. X-ray powder diffraction data indicated that the activator ions of Eu^3^+ and Ce^3^+ can be incorporated into the Sr3AlO4F lattice and formed limited solid solutions of Sr3-2xLnxNaxAlO4F (Ln=Eu, Ce) with Na^+ as a charge compensator ion. The local structure around Sr sites was initially explored using Eu-activated Sr3AlO4F as a structural probe. Sr3AlO4F:Eu^3^+ exhibits orange-red emission ranging from 520 to 740nm with a maximum peak at about 619nm mainly originating from the ^5D0->^7FJ (J=0, 1, 2, 3, 4) transitions, indicating that Eu exists mainly in the trivalent state due to a strong oxidative lattice in Sr3AlO4F. Sr3AlO4F:Ce^3^+ shows an unusual long-wa...

2010-01-01

389

Paramagnetic susceptibility of nonstoichiometric fluorides with the fluorite-type structure  

Energy Technology Data Exchange (ETDEWEB)

Magnetic properties of single crystals of nonstoichiometric fluorides M[sub 1-x]R[sub x]F[sub 2+x] (M = Ca, Sr, Ba; R = Ce, Pr, Nd, Gd, Ho, Er, Tm, Yb; with 0.05 [le] x [le] 0.28) with the fluorite-type structure have been studied for the first time. The magnetic susceptibility was measured using a Faraday balance in the 15-300 K temperature range. The samples are paramagnetic following the Curie-Weiss law. The values of paramagnetic Curie temperatures and effective magnetic moments of rare-earth ions have been found. Deviations of the temperature dependence of magnetic susceptibility from the Curie-Weiss law are observed for some nonstoichiometric fluorides at temperatures ranging from 60 to 85 K. Possible reaons for these deviations are discussed. Measurements of magnetic susceptibility provide an effective technique for a rapid and accurate determination of the concentration of rare-earth ions in nonstoichiometric fluorides.

1993-01-01

390

Oxide acid-base reaction relating to the inhibition of vandium attack on REY zeolite catalysts. [Rare earth-exchanged yttrium  

Science.gov (United States)

Certain materials, especially Sn, passivate the rare earth-exchanged Y zeolite (REY) used in petrochemical fluid-cracking catalysts against vanadium degradation caused by V impurities in the feed oil. The mechanism of passivation was investigated here from the standpoint of high-temperature oxide acid-base reaction; i.e., where the controlling factors were considered to be Lewis acid-base reactions between V{sub 2}O{sub 5}, the RE oxides, SnO{sub 2}, etc. Molten salt tests at 680{degree}C showed SnO{sub 2}, presumably because of its acidic nature, to be essentially nonreactive with V{sub 2}O{sub 5} or Na{sub 2}O-V{sub 2}O{sub 5} compounds. A hypothesis was developed to explain how the passivation effect by Sn might result from the unique resistivity of SnO{sub 2} to reaction with V{sub 2}O{sub 5}.

1991-05-01

391

Oxidative dehydrogenation of ethane on rare-earth oxide-based catalysts  

Energy Technology Data Exchange (ETDEWEB)

Results on the oxidative dehydrogenation of ethane on rare-earth oxide (REO) based catalysts (Na-P-Sm-O, Sm-Sr(Ca)-O, La-Sr-O and Nd-Sr-O) are described. Oxygen adsorption was found to be a key factor which determines the activity of this type of catalysts. Continuous flow experiments in the presence of catalysts which reveal strong oxygen adsorption showed that the reaction mixture is ignited resulting in an enhanced heat generation at the reactor inlet. The heat produced by the oxidative reactions was sufficient under the conditions chosen for the endothermic thermal pyrolysis which takes place preferentially in the gas phase. Ignition of the reaction mixture is an important catalyst function. Contrary to non-catalytic oxidative dehydrogenation, reaction temperatures above 700 C could be achieved without significant external heat input. Ethylene yields of up to 34-45% (S=66-73%) were obtained on REO-based catalysts under non-isothermal conditions (T{sub ...

1998-12-31

392

Measurement of the antiproton/proton ratio at few-TeV energies with the ARGO-YBJ experiment  

CERN Document Server

Cosmic ray antiprotons provide an important probe for the study of cosmic-ray propagation in the interstellar space and to investigate the existence of Galactic dark matter. Cosmic rays are hampered by the Moon, therefore a deficit of cosmic rays in its direction is expected (the so-called "Moon shadow"). The Earth-Moon system acts as a magnetic spectrometer. In fact, due to the geomagnetic field the center of the Moon shifts westward by an amount depending on the primary cosmic ray energy. Paths of primary antiprotons are therefore deflected in an opposite sense in their way to the Earth. This effect allows, in principle, the search of antiparticles in the opposite direction of the observed Moon shadow. The ARGO-YBJ experiment, in stable data taking since November 2007 with an energy threshold of a few hundreds of GeV, is observing the Moon shadow with high statistical significance. Using about 1 year data, an upper limit of the antip/p flux ...

2009-01-01

393

Magnetic moment measurements of gadolinium, holmium and ytterbium tartrate trihydrate crystals  

British Library Electronic Table of Contents (United Kingdom)

Magnetic moment and susceptibility of single crystals of rare earth tartrates of the type R(C4H4O6)(C4H5O6)3H2O (where R = Gd, Ho, and Yb), using a vibration sample magnetometer are reported. The experimental values of molar susceptibilities for Gd(C4H4O6)(C4H5O6)3H2O, Ho(C4H4O6)(C4H5O6)3H2O, and Yb(C4H4O6)(C4H5O6)3H2O are 2.58x10-2, 4.66x10-2, and 8.03x10-3 (in cgs em units), respectively. The calculated effective magnetic moments are in good agreement with the theoretical predictions on rare earth ions.

2008-01-01

394

Low concentration ratio solar array for low Earth orbit multi-100kW application. Volume 2: Drawings. Final Report  

Energy Technology Data Exchange (ETDEWEB)

A preliminary design effort directed toward a low concentration ratio photovoltaic array system based on 1984 technology and capable of delivering multi-hundred kilowatts (300 kW to 100 kW range) in low Earth orbit is described. The array system consists of two or more array modules each capable of delivering between 113 kW to 175 kW using silicon solar cells or gallium arsenide solar cells, respectively. The array module deployed area is 1320 square meters and consists of 4356 pyramidal concentrator elements. The module, when stowed in the Space Shuttle's payload bay, has a stowage volume of a cube with 3.24 meters on a side. The concentrator elements are sized for a geometric concentration ratio (GCR) of six with an aperture area of 0.5 meters x 0.5 meters. Drawings for the preliminary design configuration and for the test hardware that was fabricated for design evaluation and test are provided.

1982-07-01

395

Low concentration ratio solar array for low Earth orbit multi-100 kW application. Volume 1: Design, analysis and development tests. Final Report  

Energy Technology Data Exchange (ETDEWEB)

A preliminary design effort directed toward a low concentration ratio photovoltaic array system capable of delivering multihundred kilowatts (300 kW to 1000 kW range) in low earth orbit is described. The array system consists of two or more array modules each capable of delivering between 113 kW to 175 kW using silicon solar cells or gallium arsenide solar cells, respectively. The array module deployed area is 1320 square meters and consists of 4356 pyramidal concentrator elements. The module, when stowed in the Space Shuttle's payload bay, has a stowage volume of a cube with 3.24 meters on a side. The concentrator elements are sized for a geometric concentration ratio (GCR) of six with an aperture area of .25 sq. m. The structural analysis and design trades leading to the baseline design are discussed. It describes the configuration, as well as optical, thermal and electrical performance analyses that support the design and overall performance estimates ...

1983-07-01

396

In situ ellipsometric studies of formation kinetics of rare earth metal conversion coatings on magnesium alloy  

International Nuclear Information System (INIS)

In situ spectroscopic ellipsometry was employed to investigate the initial regime of rare earth metal (REM) conversion coatings formation on AZ31 magnesium alloy. Three REM salts solutions, 0.05 mol.dm"-"3 Ce(NO_3)_3, La(NO)_3 and Sm(NO)_3 solutions, were used for REM conversion coatings preparation. By deconvoluting the ellipsometric data, the surface of the fresh well-polished AZ31 magnesium alloy was found to be covered with 15.80 nm thick native (hydr)oxide film; the refractive indices and the thickness of Ce, La and Sm conversion coatings were obtained. The formation kinetics of three REM coatings follows different exponential functions and the coatings exhibit different optical properties. La conversion coating has the largest n values and the lowest k values while Sm conversion coating is just opposite. Moreover, the pH variation of the bulk conversion solutions upon the coatings formation was recorded. It is confirmed that the reduction of protons leads to ...

2008-05-01

397

High-frequency electrostatic waves near Earth's bow shock  

International Nuclear Information System (INIS)

Electrostatic wave measurements from the Active Magnetospheric Particle Tracer Explorer Ion Release Module have been used to investigate the wave modes and their possible generation mechanisms in the Earth's bow shock and magnetosheath. It is demonstrated that electrostatic waves are present in the bow shock and magnetosheath with frequencies above the maximum frequency for Doppler-shifted ion acoustic waves, yet below the plasma frequency. Waves in this frequency range are tentatively identified as electron beam mode waves. Data from 45 bow shock crossings are then used to investigate possible correlations between the electrostatic wave properties and the near-shock plasma parameters. The most significant relationships found are anticorrelations with Alfven Mach number and electron beta. Mechanisms which might produce electron beams in the shock and magnetosheath are discussed in terms of the correlation study results. These mechanisms include acceleration by the ...

398

High temperature susceptibilities of actinide monopnictides and monochalcogenides  

International Nuclear Information System (INIS)

The inverse susceptibilities of the monopnictides and monochalcogenides of the light rare earths plotted vs. temperature flatten off at high temperatures. This behaviour is well explained by van Vleck paramagnetism of the excited states of the multiplet. For almost all actinide pnictides and chalcogenides a similar flattening-off is observed. Since spin orbit coupling is much stronger than in the light rare earth compounds an analogous interpretation is not possible. Susceptibility curves for uranium compounds can be fitted by adding a temperature dependent enhanced Pauli paramagnetism to the Curie-Weiss term (modified Curie-Weiss law). The high temperature susceptibility behaviour of neptunium compounds is very similar to uranium compounds i.e. an appreciable deviation from the Curie-Weiss law is only visible for the chalcogenides. The plutonium chalcogenides show a temperature independent paramagnetism, which can be explained either by a ...

1998-06-12

399

High efficiency direct thermal to electric energy conversion from radioisotope decay using selective emitters and spectrally tuned solar cells  

International Nuclear Information System (INIS)

Thermophotovoltaic (TPV) systems are attractive possibilities for direct thermal-to-electric energy conversion, but have typically required the use of black body radiators operating at high temperatures. Recent advances in both the understanding and performance of solid rare-earth oxide selective emitters make possible the use of TPV at temperatures as low as 1200K. Both selective emitter and filter system TPV systems are feasible. However, requirements on the filter system are severe in order to attain high efficiency. A thin-film of a rare-earth oxide is one method for producing an efficient, rugged selective emitter. An efficiency of 0.14 and power density of 9.2 W/KG at 1200K is calculated for a hypothetical thin-film neodymia (Nd2O3) selective emitter TPV system that uses radioisotope decay as the thermal energy source.

1993-08-23

400

Fly on the wings of the sun - a study of solar-powered aircraft  

Energy Technology Data Exchange (ETDEWEB)

Solar High Altitude Powered Platform (Solar HAPP) aircraft are unmanned remote sensing vehicles designed for cruises lasting up to one year at 20-km altitude, while carrying up to 250 pounds of cameras and electrooptic sensors in an underslung payload pod. It is anticipated that real time IR and UV images of earth features may be more inexpensively and accurately obtained by this means than by the conventional geosynchronous earth resources satellites. Solar HAPPs, with wing spans of over 300 ft and weights of only 2000 lb, require ultralight composite structures with external wire bracing. Solar cells will cover both sides of the vertical wing stabilizers and wing tips, which hinge up in daytime to capture the maximum amount of sunlight. A 15-hp electric propulsion unit drives a low-rpm, large diameter propeller; power will be derived from the solar cells diurnally, and from hydrogen-oxygen fuel cells nocturnally. The fuel gases will be ...

1985-06-01

401

Evidence of polarisation in the prompt gamma-ray emission from GRB 930131 and GRB 960924  

CERN Document Server

The true nature of the progenitor to GRBs remains elusive; one characteristic that would constrain our understanding of the GRB mechanism considerably is gamma-ray polarimetry measurements of the initial burst flux. We present a method that interprets the prompt GRB flux as it Compton scatters off the Earth's atmosphere, based on detailed modelling of both the Earth's atmosphere and the orbiting detectors. The BATSE mission aboard the \\textit{CGRO} monitored the whole sky in the 20 keV - 1 MeV energy band continuously from April 1991 until June 2000. We present the BATSE Albedo Polarimetry System (BAPS), and show that GRB 930131 and GRB 960924 provide evidence of polarisation in their prompt flux that is consistent with degrees of polarisation of $\\Pi>35$% and $\\Pi>50$% respectively. While the evidence of polarisation is strong, the method is unable to strongly constrain the degree of polarisation beyond a systematics based estimation. ...

2005-01-01

402

Effect of microalloying and thermomechanical processing on the structure and mechanical properties of constructional steel  

Energy Technology Data Exchange (ETDEWEB)

The effect of microalloying with carbide-forming (V,Ti,Nb) and rare-earth elements and of high-temperature thermomechanical processing (HTMP) on the structure, mechanical properties and low temperature behaviour of 38CrSi steel has been investigated. It has been shown that in the case of dissolution of carbides during heating for quench hardening, the tempering resistance of the steel increases. It has also been found that - as a result of HTMP - the susceptibility of the steel irreversible temper brittleness decreases, irrespective of the steel having been microalloyed or not. The data, originating from tensile testing and impact testing (with the help of laser interferometry) in the temperature range from +20 to -196 degC, has been explained in terms of fractographic analysis. It has been shown that microalloying and HTMP favour the occurrence of ductile microvoids in the fracture. On the other hand, HTMP and rare-earth elements changes the ...

1998-10-01

403

Effect of Ho"3"+ substitutions on the structural and magnetic properties of BaFe_1_2O_1_9 hexaferrites  

International Nuclear Information System (INIS)

Holmium doped barium based hexaferrites BaFe_1_2_-_2_xHo_2_xO_1_9 with (x = 0.0-1.0) were synthesized by solid state reaction method. Structural and magnetic characterization of these ferrites provide significant information about their reactive physical properties. X-ray analysis reveals that in all samples M-type structure exist with few secondary phases. Scanning electron microscope revealed the grain size of the specimen. The results show that grain size decreases with the substitution degree of Holmium. Thus rare earth element Holmium Ho"3"+ acts as a grain growth inhibitor. The magnetic hysteresis loops show the variation in the values of magnetic parameters like saturation magnetization (M_s), remanent magnetization (M_r) and coercivity (H_c) were observed by changing Ho"3"+ content in BaFe_1_2_-_2_xHo_2_xO_1_9 ferrites. Coercivity showed a maximum value of 2230 Oe for (x = 0.4) and then decreasing trend were observed in the values of H_c, M_r and M_s with ...

2010-04-09

404

Development of pyrometallurgical partitioning of transuranium elements from high-level liquid waste. Improvement to pyrometallurgical partitioning process and process demonstration  

Energy Technology Data Exchange (ETDEWEB)

The partitioning of transuranium elements (TRUs) from high-level liquid waste (HLLW) through the use of pyrometallurgical technology has been underway since 1986, for the purpose of the improving the safety and public acceptance of the disposal of high-level vitrified waste. Prior to the pyrometallurgical partitioning process, the alkali metals can be separated at the denitration process for oxide conversion of HLLW, chlorination in a chloride salt bath can be used to effectively convert oxides to chlorides, and evaporated chlorides can be captured with high efficiency in another adopted chloride salt bath. The higher separation factors between actinides and rare earths are obtained in a LiCl-KCl/Bi system than in a LiCl-KCl/Cd system. Based on the results, we propose a practical process flow for partitioning TRUs from HLLW by pyrometallurgical technology. This process was demonstrated successfully using simulated purex waste. Each element of the TRUs was separated ...

1998-10-01

405

Desorption of uranium from titanium-activated carbon composite adsorbent with acidic eluent, 2  

Energy Technology Data Exchange (ETDEWEB)

The desorption of uranium from the granular titanium-activated carbon composite adsorbent (concentration of uranium: 25.5 mg/l-Ad), which adsorbed uranium from natural sea water, was examined by the column process with acidic eluent at room temperature. The column operation was able to be carried out without destruction of the granular adsorbent by the generation of the carbon dioxide, and free from disturbance of the eluent flow by precipitate of calcium sulfate dihydrate with sulfuric acid eluent. The amount of acid consumption by the adsorbent was 0.87 eq/l-Ad. The alkaline earth metals were eluted in the range of elution volume below 2l/l-Ad, whereas uranium, iron, and titanium were eluted above 2l/l-Ad. Therefore, uranium was separable from the alkaline earth metals which were adsorbed in the most quantity in the adsorbent. In the range of elution volume 2 to 12l/l-Ad, the percentage of desorbed uranium and the concentration ratio of ...

1984-01-01

406

3-D modelling the electric field due to ocean tidal flow and comparison with observations  

DEFF Research Database (Denmark)

The tidal motion of the ocean water through the ambient magnetic field, generates secondary electric field. This motionally induced electric field can be detected in the sea or inland and has a potential for electrical soundings of the Earth. A first goal of the paper is to gain an understanding of the global distribution of the electric signal due to tidal ocean flow. We simulate the electric signals for two tidal constituents - lunar semidiurnal (M2) and diurnal (O1) tides. We assume a realistic Earth's conductivity model with a surface thin shell and 1-D mantle underneath. Simulations demonstrate that in some coastal regions the amplitudes of the electric field can reach 100 mV/km and 10 mV/km for M2 and O1 tides respectively. The changes of lithosphere resistance produce detectable changes in the tidal electric signals. We show that our predictions are in a good agreement with observations.

2006-01-01

407

What's happening out there? (Climatic change impacts)  

International Nuclear Information System (INIS)

This article briefly comments on some stumbling-blocks to climatic change modelling accuracy - in assessments of the greenhouse effect, 25% (missing link) of atmospheric carbon dioxide absorption is still unaccounted for; 1989 World Bank estimates of the Amazon rain forest deforestation rate have since proven to be inaccurate; there are difficulties in assessing the movement of the earth's crust relative to variations in sea level; and different studies vary in results relative to global temperature measurement and trend assessment. The need for an assessment of the economic impacts of increased atmospheric concentrations of carbon dioxide is also pointed out.

1990-01-01

408

Use of Eu/sup 3 +/ as an oxygen environment probe in alkali-alkaline earth-lanthanide phosphates with the. beta. -K/sub 2/SO/sub 4/ structure  

Energy Technology Data Exchange (ETDEWEB)

The use of europium as a local structural probe allows the various phases appearing in the NaCaPO/sub 4/-Na/sub 3/Eu(PO/sub 4/)/sub 2/ and NaSrPO/sub 4/-Na/sub 3/Eu(PO/sub 4/)/sub 2/ systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO/sub 4/ groups.

1983-09-15

409

Thulium-doped vanadate crystals: Growth, spectroscopy and laser performance  

British Library Electronic Table of Contents (United Kingdom)

This work is concentrated on growth, spectroscopy and laser performance of thulium-doped vanadate crystals. At the beginning the growth techniques are analyzed and then the matrix of vanadates crystal, its structure and physicochemical properties are explained together with the rare earth activators influence. Detailed spectroscopy of the thulium-doped vanadate crystals then follows. On the background of this theoretical analysis and state of the art of the subject the description of thulium vanadate lasers (especially Tm:YVO"4, Tm:GdVO"4, and Tm:LuVO"4) together with their generated output radiation characteristics are presented.

2011-01-01

410

The identification of the 1/2"+[660] proton orbitals at high spins in rare-earth nuclei  

International Nuclear Information System (INIS)

Decay sequences based on the 1/2"+[660] proton orbital have been identified in "1"7"1Ta and "1"7"7Re based on spin, parity, and large alignment. This decay sequence is observed higher in energy than predicted in cranking calculations based on modified oscillator potentials. Similarly known 1/2"-[541] decay sequences in these and other neighbouring isotopes are observed lower in energy than predicted. A reduction in the strength of the spin-orbit potential for protons is suggested as a solution to these problem. (orig.).

411

The electric Earth: Cosmic influences on the atmosphere  

DEFF Research Database (Denmark)

The universe is full of exotic particles and waves. Some, such as neutrinos, pass through our neighbourhood unnoticed; others, such as extreme uv radiation, are absorbed by the upper atmosphere before they are able to do too much damage. For a long time, any systematic attempt to understand how our weather can be affected by extra-terrestrial sources other than solar visible and infrared radiation has been a lively and often controversial diversion from mainstream research. But recent scientific and technological breakthroughs and concern over long-term climate change have brought this subject into the spotlight.

2002-01-01

412

The effect of temperature on the radiative performance of Ho-YAG thin film selective emitters  

Energy Technology Data Exchange (ETDEWEB)

The authors present the emitter efficiency results for the thin film 25 percent Ho YAG (Yttrium Aluminum Garnet, Y3Al5O12) selective emitter from 1000 to 1700 K with a platinum substrate. Spectral emittance and emissive power measurements were made (1.2 less than lambda less than 3.2 microns) and used to calculate the radiative efficiency. The radiative efficiency and power density of rare earth doped selective emitters are strongly dependent on temperature and experimental results indicate an optimum temperature (1650 K for Ho YAG) for thermophotovoltaic (TPV) applications.

1995-01-01

413

The AMPTE program's contribution to studies of the solar wind-magnetosphere-ionosphere interaction  

Energy Technology Data Exchange (ETDEWEB)

The Active Magnetospheric Particle Tracer Explorers (AMPTE) program provided important information on the behavior of clouds of plasma artificially injected into the solar wind and the earth's magnetosphere. Now that the releases are over, data from the satellites are being analyzed to investigate the processes by which the ambient solar wind mass, momentum, and energy are transferred to the magnetosphere. Work in progress at APL indicates that the solar wind is much more inhomogeneous than previously believed, that the solar wind constantly buffets the magnetosphere, and that ground observers may remotely sense these interactions as geomagnetic pulsations. 8 refs.

1990-12-01

414

Target identification of buried coated objects  

Scientific Electronic Library Online (English)

Abstract in english We consider the three dimensional electromagnetic inverse scattering problem of determining information about a buried coated object from a knowledge of the electric and magnetic fields measured on the surface of the earth corresponding to time harmonic electric dipoles as incident fields. We assume that the buried object is a perfect conductor that is (possibly) partially coated by a thin dielectric layer. No a priori assumption is made on the extent of the coating, i.e. (more) the object can be fully coated, partially coated or not coated at all. We present an algorithm based on the linear sampling method and reciprocity gap functional for reconstructing the shape of the scattering obstacle together with an estimate of the surface impedance of the coating.

2006-01-01

415

SiAlON hardmetal materials  

International Nuclear Information System (INIS)

Sialons are phases in the Si-Al-O-N and M-Si-Al-O-N systems where M includes Li, Mg, Ca, Sc, Y and the rare earth elements. They are comparable in variety with the mineral silicates and are built up of one-, two-, and three-dimensional arrangements of (Si,Al)(O,N)/sub 4/ tetrahedra in the same way that the structural units of the silicates are SiO/sub 4/ tetrahedra. These new materials include N-containing ceramics, glasses and glass-ceramics that are being explored for their thermal, chemical and physical properties.

416

Searching for modifications to the exponential radioactive decay law with the Cassini spacecraft  

CERN Document Server

Data from the power output of the radioisotope thermoelectric generators aboard the Cassini spacecraft are used to test the conjecture that small deviations observed in terrestrial measurements of the exponential radioactive decay law are correlated with the Earth-Sun distance. No significant deviations from exponential decay are observed over a range of 0.7 - 1.6 A.U. A 90% Cl upper limit of 0.84 x 10^-4 is set on a term in the decay rate of Pu-238 proportional to 1/R^2 and 0.99 x 10^-4 for a term proportional to 1/R.

2008-01-01

417

School of Earth and Environment  

Wastenet

...Verheggen, B; Dommen, J; Duplissy, J; Prevot, AS; Weingartner, E; Riipinen, I; Kulmala, M; Spracklen, DV; Carslaw, KS; ...Carslaw, KS; Boucher, O; Spracklen, DV; Mann, GW; Rae, JGL; Woodward, S; Kulmala, M (2010) A review of natural aerosol interactions ...Pickering, S; Ogren, JA; Andrews, E; Baltensperger, U; Weingartner, E; Boy, M; Kulmala, M; Laakso, L; Lihavainen, H; ...Fastrup, B; Gagne, S; Hahn, F; Harrison, RG; Kellett, B; Kirkby, J; Kulmala, M; Laakso, L; Laaksonen, A; ...

418

Report on scientific research in geodesy 1987-1991. Soobshchenie o nauchnykh rabotakh po geodezii 1987-1991  

Energy Technology Data Exchange (ETDEWEB)

The symposium reports results of investigations in geodesy conducted between 1987 and 1991 in the Soviet Union. The five sections of the report deal with several aspects of physical geodesy, with particular attention given to studies of the earth's gravitational field; geodetic positioning and geodetic networks; gravimetry, including high-precision gravimetry, marine gravimetry, and nontidal gravity variations; satellite geodesy; and recent crustal movements. Each section is supplied with a detailed bibliography.

1991-01-01

419

Production of Group IIA atomic and molecular negative ion beams in a cesium-sputter negative ion source  

Energy Technology Data Exchange (ETDEWEB)

The results of an investigation on the production of Group IIA atomic and molecular negative ion beams formed in a cesium-sputter negative ion source are presented. The sputtering material was formed by pressing pellets of stoichiometric mixtures of the Group IIA element carbonates and 10% copper powder. Negative ions of several alkaline-earth elements and their oxides have been observed. Beam intensities as high as 180 pA have been observed for Sr{sup -}and 20 nA for SrO{sup -}. (orig.).

1996-09-11

420

Production of Group IIA atomic and molecular negative ion beams in a cesium-sputter negative ion source  

International Nuclear Information System (INIS)

The results of an investigation on the production of Group IIA atomic and molecular negative ion beams formed in a cesium-sputter negative ion source are presented. The sputtering material was formed by pressing pellets of stoichiometric mixtures of the Group IIA element carbonates and 10% copper powder. Negative ions of several alkaline-earth elements and their oxides have been observed. Beam intensities as high as 180 pA have been observed for Sr"-and 20 nA for SrO"-. (orig.).

1996-09-01

421

Physical aspects of FGD by-products  

Energy Technology Data Exchange (ETDEWEB)

Air pollution constraints continue to intensify, resulting in solid waste volume increases. An example of this is coal burning power plant flue gas desulfurization by scrubbing. The aqueous suspensions of calcium sulfate hemihydrate or calcium sulfate dihydrate will exceed 200 million tons annually by the year 2000. Disposal of these wastes can have massive environmental effects, due to physical instability and leaching to groundwater. One alternate disposal technique is sulfopozzolanic fixation, converting the FGD waste by addition of fine coal ash and an alkaline earth additive, into a monolithic mass. 6 refs., 17 figs., 3 tabs.

1992-01-01

422

Optical SETI with Air Cerenkov Telescopes  

CERN Document Server

We propose using large Air Cerenkov Telescopes (ACT's) to search for optical, pulsed signals from extra-terrestrial intelligence. Such dishes collect tens of photons from a nanosecond-scale pulse of isotropic equivalent power of tens of solar luminosities at a distance of 100 pc. The field of view for giant ACT's can be on the order of ten square degrees, and they will be able to monitor 10 to 10$^2$ stars simultaneously for nanosecond pulses of about 6th mag or brighter. Using the Earth's diameter as a baseline, orbital motion of the planet could be detected by timing the pulse arrival times.

2001-01-01

423

Operation of a high temperature ion source at the helium-jet on-line isotope separator facility HELIOS  

Energy Technology Data Exchange (ETDEWEB)

The performance of a high temperature ion source coupled to a helium gas-jet transport system for an efficient mass separation of neutron-rich alkaline earth and lanthanide isotopes is reported and the results of overall efficiency measurements using different cluster materials in the gas-jet are given. A fast, microprocessor controlled tape transport system for ..gamma..-spectroscopic studies on short-lived isotopes is described. Some results on the decay of 3.8sub(-s) /sup 152/Pr are presented. (orig.).

1985-02-01

424

Operation of a high temperature ion source at the helium-jet on-line isotope separator facility HELIOS  

Energy Technology Data Exchange (ETDEWEB)

The performance of a high temperature ion source coupled to a helium gas-jet transport system for an efficient mass separation of neutron-rich alkaline earth and lanthanide isotopes is reported and the results of overall efficiency measurements using different cluster materials in the gas-jet are given. A fast, microprocessor controlled tape transport system for ..gamma..-spectroscopic studies on short-lived isotopes is described. Some results on the decay of 3.8sub(-s) /sup 152/Pr are presented.

1985-02-01

425

On the validity of the pseudo-spin concept for axially symmetric deformed nuclei  

International Nuclear Information System (INIS)

The average single-particle field shows a very small pseudo-spin-orbit splitting in the pseudo-spin representation. If this splitting is neglected, pseudo-spin becomes a good quantum number and the resulting scheme (the pseudo-Nilsson model) has a very simple interpretation. The pseudo-spin symmetry embodied in the realistic deformed average field is explored by comparing the single-particle energies and wave functions of the deformed Woods-Saxon model with the corresponding results of the pseudo-Nilsson model. The scheme is used to calculate the magnetic moments of deformed odd-A nuclei of the rare-earth region. (orig.).

426

On the magnetic behaviour of REBa_2F_7 compounds (RE=Eu, Dy, Ho, Er, Tm and Yb)  

International Nuclear Information System (INIS)

The DC magnetic susceptibility of the REBa_2F_7 compounds was measured by a SQUID magnetometer in the temperature range 5-300 K. Except for Eu, the other compounds show either Curie law or Curie-Weiss law with relatively small values of paramagnetic Curie temperature, #theta#_p, with effective magnetic moments in the range expected of electronic ground state of the trivalent rare earth ion with appropriate J value. The behaviour of Eu is complex. (orig.).

427

Non-gravitational perturbations and satellite geodesy  

Energy Technology Data Exchange (ETDEWEB)

This book presents the basic ideas of the physics of non-gravitational perturbations and the mathematics required to compute their orbital effects. It conveys the relevance of the different problems that must be solved to achieve a given level of accuracy in orbit determination and in recovery of geophysically significant parameters. Selected Contents are: Orders of Magnitude of the Perturbing Forces, Tides and Apparent Forces, Tools from Celestial Mechanics, Solar Radiation Pressure-Direct Effects: Satellite-Solar Radiation Interaction, Long-Term Effects on Semi-Major Axis, Radiation Pressure-Indirect Effects: Earth-Reflected Radiation Pressure, Anisotropic Thermal Emission, Drag: Orbital Perturbations by a Drag-Like Force, and Charged Particle Drag.

1987-01-01

428

New coumarin-based sensor molecule for magnesium and calcium ions  

British Library Electronic Table of Contents (United Kingdom)

A new coumarin-based sensor molecule (L1) has been synthesized and this was found to bind calcium and magnesium ions more effectively as compared to other alkali/alkaline earth/lanthanide and certain transition metal ions. A significant enhancement in fluorescence intensity was observed on binding to Ca2+ and Mg2+ ions; while a minor quenching was observed for weakly bound Hg2+, Ni2+, Fe3+, and Co2+ ions. PET process, coupled with the ICT process, is proposed to explain the observed spectral response.

2009-01-01

429

National Earth Comfort Program, Geothermal Heat Pump Market Mobilization and Technology Demonstration  

Energy Technology Data Exchange (ETDEWEB)

Late 1994, the Geothermal Heat Pump Consortium (GHPC) was launched as a non-profit collaborative effort between the United States Department of Energy, US electric utilities and the GeoExchange (geothermal heat pump) industry to make ''geothermal heat pumps'' a significant component of the HVAC industry and avoid 1.5 million metric tons of carbon equivalent per year. The goal was to create a self-sustainable GeoExchange market. This report offers a summary of some of the lessons learned and an overview of some of the programs major accomplishments.

2001-04-30

430

JEFI OLD: Joint seismic/electrical measurement of gas hydrate content in continental margin sediments  

Environmental Research Database

ObjectivesNot EnteredDescriptionMethane hydrate in an ice-like substance consisting of molecules of methane gas combined chemically with water. It is stable at high pressures and low temperatures. Since the ocean floor is normally cold, but temperatures increase with depth inside the Earth, such conditions normally prevail for a few hundred meters below the seafloor where the ocean depth is more than a few hundred metres. Methane beneath the ocean floor is formed by the decomposition of organic material. At the edges of the co [continued...

2006-01-30

431

Identification of the 1/2/sup +/(660) proton orbitals at high spins in rare-earth nuclei  

Energy Technology Data Exchange (ETDEWEB)

Decay sequences based on the 1/2/sup +/(660) proton orbital have been identified in /sup 171/Ta and /sup 177/Re based on spin, parity, and large alignment. This decay sequence is observed higher in energy than predicted in cranking calculations based on modified oscillator potentials. Similarly known 1/2/sup -/(541) decay sequences in these and other neighbouring isotopes are observed lower in energy than predicted. A reduction in the strength of the spin-orbit potential for protons is suggested as a solution to these problem.

1983-12-08

432

Hybridisation and crystal field in YbPd sub 2 Si sub 2  

Energy Technology Data Exchange (ETDEWEB)

Experimental data in the hybridised compound YbPd{sub 2}Si{sub 2} is compared with the results obtained with a recently proposed hybridisation model, based on the ''large-degeneracy expansion'' approximation, which takes into account the crystal field splittings of the rare earth ion energy levels. With a unique set of parameters, satisfactory agreement is simultaneously obtained for the thermal variation of the electronic specific heat, of the magnetic susceptibility and of the electric field gradient at the Yb site, as well as for the field variation of the low temperature magnetisation. (orig.).

1991-02-01

433

Geothermal heat pump applications: Industrial/commercial  

Energy Technology Data Exchange (ETDEWEB)

The fastest rate of growth in the space conditioning market has been attributed to the application of geothermal heat pumps to the industrial and commercial markets. The author reviews and provides examples of the three most popular components of a large geothermal heat pump system: geothermal earth coupling, heat pumps and heat exchangers, and building side terminals. These components are applied to three example geothermal installations: a library, an office building, and a school. Examples of energy use before and after the installation of a geothermal space conditioning system are summarized. General design and cost guidelines and comments on the use of geothermal heat pump in these and similar applications are discussed.

1999-07-01

434

From Earth to Mars in 15 days with an americium-propelled space ship; De la terre a mars en 15 jours avec un vaisseau spatial propulse a l'americium  

Energy Technology Data Exchange (ETDEWEB)

This digest paper presents the theoretical project of a fission engine for space ship as imagined by Y. Ronen from the Ben-Gourion Univ. (Israel). In this engine, the combustion chamber is covered with metastable {sup 242}Am thin sheets. The fission reaction is triggered with a bombardment of neutrons and the fission fragments ionize a gas (hydrogen, for instance) which is overheated and ejected through the engine nozzle. (J.S.)

2002-01-01

435

Friends of the Earth: Help Paraguay fight the soy invasion : Environmental Justice : Campaign Actions  

Wastenet

...soy, rights, justice, contamination, water, cargill, port soy, rights, justice, contamination, water, cargill, port Friends of the ... The global food giant Cargill has built its own port on the banks of the River Paraguay with plans to expand. It's ...allows Puerto Union, the port facility belonging to the transnational food giant Cargill, to continue operating. This decree was issued despite the ... The Cargill port facility represents a hazard to the water supply of the entire population of the city, and any accident such ...

436

FORTE antenna element and release mechanism design  

Energy Technology Data Exchange (ETDEWEB)

The Fast On-Orbit Recording of Transient Events (FORTE) satellite being built by Los Alamos National Laboratory (LANL) and Sandia National Laboratories (SNL) has as its most prominent feature a large deployable (11 m by 5 m) log periodic antenna to monitor emissions from electrical storms on the Earth. This paper describes the antenna and the design for the long elements and explains the dynamics of their deployment and the damping system employed. It also describes the unique paraffin-actuated reusable tie-down and release mechanism employed in the system.

1995-02-01

437

Extraction of lithium from neutral salt solutions with fluorinated #beta#-diketones  

International Nuclear Information System (INIS)

Lithium was selectively extracted from near-neutral aqueous solutions of alkali metal salts. The mechanism by which this was achieved involves the formation of the trioctylphosphine oxide adduct of a lithium chelate of a fluorinated #beta#-diketone, which is then readily extractable into an organic diluent. High separation factors were obtained from sodium, potassium, rubidium, and cesium. The selectivity of the fluorinated #beta#-diketones for lithium over the alkaline earths was found to be poor. A suggested general flowsheet for the recovery of lithium from a salt brine concentrate is included. (author).

438

Emittance theory for thin film selective emitter  

Energy Technology Data Exchange (ETDEWEB)

Thin films of high temperature garnet materials such as yttrium aluminum garnet (YAG) doped with rare earths are currently being investigated as selective emitters. This paper presents a radiative transfer analysis of the thin film emitter. From this analysis the emitter efficiency and power density are calculated. Results based on measured extinction coefficients for erbium-YAG and holmium-YAG are presented. These results indicated that emitter efficiencies of 50 percent and power densities of several watts/sq cm are attainable at moderate temperatures (less than 1750 K).

1994-08-01

439

Effect of yttrium on mechanical properties of 9Cr-2WVTa low active martensite steel  

International Nuclear Information System (INIS)

The effect of the rare earth element, yttrium, on the mechanical properties of 9Cr-2WVTa low active martensite steel for fusion reactor was studied and the metallurgical behavior of yttrium in the steel was primarily analyzed. The results show that it is easy for yttrium to aggregate and form the blocky yttrium rich inclusions in the steel, which can dissever the continuity of the matrix and produce micro-cracks for fracture. The yttrium rich inclusions were distributed along the rolling direction, which made the fracture surface delaminated in the tensile and impact samples, and reduced the mechanical properties of the steel. (authors)

2009-03-01

440

Effect of temperature gradient on thick film selective emitter emittance  

Energy Technology Data Exchange (ETDEWEB)

A temperature gradient across a thick ({ge}.1mm) film selective emitter will produce a significant reduction in the spectral emittance from the no temperature gradient case. Thick film selective emitters of rare earth doped host materials such as yttrium-aluminum-garnet (YAG) are examples where temperature gradient effects are important. In this paper a model is developed for the spectral emittance assuming a linear temperature gradient across the film. Results of the model indicate that temperature gradients will result in reductions the order of 20{percent} or more in the spectral emittance. {copyright} {ital 1997 American Institute of Physics.}

1997-03-01

441

ESR study of X-ray irradiated rare earth (Ln) ion-doped glaserite and Ln ion-doped langbeinite  

Energy Technology Data Exchange (ETDEWEB)

X-ray irradiation-induced paramagnetic radicals in rare earth (Ln) ion-doped glaserite and Ln ion-doped langbeinite were studied by means of ESR technique, aiming at developing the highly sensitive sensor for an ESR dosimetry. The samples were prepared by two kinds of procedures as follows. In one process, the glaserite (K{sub 3}Na(SO{sub 4}){sub 2}) matrix or the langbeinite (K{sub 2}Mg{sub 2}(SO{sub 4}){sub 3}) matrix were synthesized by heating the mixture of K{sub 2}SO{sub 4} and Na{sub 2}SO{sub 4} or the mixture of K{sub 2}SO{sub 4} and MgSO{sub 4} at 1023 K for 1 hour in He flow. The matrices obtained were mixed well with a fixed amount of Ln{sub 2}(SO{sub 4}){sub 3} (Ln=La, Eu, Gd, Lu) powder and heated at 1023 K for 1 hour in He flow. In the other process, the homogeneous mixture of a fixed amount of K{sub 2}SO{sub 4}, Na{sub 2}SO{sub 4} and Ln{sub 2}(SO{sub 4}){sub 3} powders or a fixed amount of K{sub 2}SO{sub 4}, MgSO{sub 4} and Ln{sub 2}(S0{sub 4}){sub ...

1992-06-01

442

Dynamics of the controlled environment conditions in SVET greenhouse in flight  

Energy Technology Data Exchange (ETDEWEB)

The dynamics of the controlled environment conditions in the SVET-4 space greenhouse model were investigated, using computerized equipment to continuously measure and collect the values of the inside environment parameters, which were then sent to earth. The on-ground analysis of telemetric data for the first 29 days indicated that radishes and the Chinese cabbage plants planted in SVET-4 grew under normal temperature conditions, but in insufficient substrate moisture. After supplying the necessary quantity of water, the analysis of the first 54 days of experiment is continuing. 2 refs.

1992-01-01

443

Capability of the PAMELA Time-Of-Flight to identify light nuclei: results from a beam test calibration  

CERN Document Server

PAMELA is a space telescope orbiting around the Earth since June 2006. The scientific objectives addressed by the mission are the measurement of the antiprotons and positrons spectra in cosmic rays, the hunt for anti-nuclei as well as the determination of light nuclei fluxes from Hydrogen to Oxygen in a wide energy range and with very high statistics. In this paper the charge discrimination capabilities of the PAMELA Time-Of-Flight system for light nuclei, determined during a beam test calibration, will be presented.

2008-01-01

444

Bringing robotics technology down to Earth  

International Nuclear Information System (INIS)

Robotics technology is successfully being transitioned from space to terrestrial applications. It is being modified and enhanced to help in the US DOE's Environmental Restoration and Waste Management Program. Some examples of these applications, ranging from large multijointed manipulators to autonomously navigated remote vehicles, are outlined in this article. They include the following: underground storage tank technology demonstration; light-duty utility arm system; remotely controlled material-handling system; remotely operated excavator; self-guided transfer vehicle. 10 figs.

445

Beginning Scala  

CERN Document Server

The open source Scala language is a Java--based dynamic scripting, functional programming language. Moreover, this highly scalable scripting language lends itself well to building Cloud--based/deliverable Software as a Service (SaaS) online applications. Written by Lift Scala web framework founder and lead Dave Pollak, Beginning Scala takes a down--to--earth approach to teaching Scala that leads you through simple examples that can be combined to build complex, scalable systems and applications. This book introduces you to the Scala programming language and then guides you through Scala constr

2009-01-01

446

Automatic interpretation of Schlumberger soundings  

Energy Technology Data Exchange (ETDEWEB)

The automatic interpretation of apparent resistivity curves from horizontally layered earth models is carried out by the curve-fitting method in three steps: (1) the observed VES data are interpolated at equidistant points of electrode separations on the logarithmic scale by using the cubic spline function, (2) the layer parameters which are resistivities and depths are predicted from the sampled apparent resistivity values by SALS system program and (3) the theoretical VES curves from the models are calculated by Ghosh's linear filter method using the Zhody's computer program. Two soundings taken over Takenoyu geothermal area were chosen to test the procedures of the automatic interpretation.

1980-09-01

447

APSIS - an Artificial Planetary System in Space to probe extra-dimensional gravity and MOND  

CERN Document Server

A proposal is made to test Newton's inverse-square law using the perihelion shift of test masses (planets) in free fall within a spacecraft located at the Earth-Sun L2 point. Such an Artificial Planetary System In Space (APSIS) will operate in a drag-free environment with controlled experimental conditions and minimal interference from terrestrial sources of contamination. We demonstrate that such a space experiment can probe the presence of a "hidden" fifth dimension on the scale of a micron, if the perihelion shift of a "planet" can be measured to sub-arc-second accuracy. Some suggestions for spacecraft design are made.

2006-01-01

448

A versatile method for estimating the characteristics of radon transport in soil  

Energy Technology Data Exchange (ETDEWEB)

A versatile method for estimating the characteristics of radon transport in soil is developed. The method allows the following characteristics to be estimated: depth distribution function of the soil gas radon concentration, equilibrium radon concentration in the soil air, depth at which the radon concentration reaches its equilibrium value, radon flux density from the Earth's surface, and convective radon transport velocity. The method is based on soil gas radon concentration measurements and is appropriate in the case of relatively uniform geology. (orig.)

2003-07-01

449

[Magnetic thin film research]: Progress report year 2  

Energy Technology Data Exchange (ETDEWEB)

The work in the past year has primarily involved four areas of magnetic thin films: amorphous rare earth-transition metal alloys, epitaxial CoPt{sub 3} and Ni-Pt alloy thin films, amorphous rare earth doped Si (a new class of dilute magnetic semiconductor with large negative magnetoresistance which the authors have discovered), and exchange-coupled antiferromagnetic insulators. In the amorphous alloys, they made a systematic study of the effects of local anisotropy, macroscopic (perpendicular) anisotropy, and exchange constant on the fundamental (and practical) properties of these magnetic alloys, as originally described in the grant proposal. The work on the epitaxial Co-Pt (and more recently Ni-Pt) alloys was originally undertaken as a comparison study to the amorphous alloys. Crystalline Co-Pt alloys have many striking similarities to the amorphous rare earth-transition metal alloys: perpendicular magnetic anisotropy, ...

1996-09-01

450

The life span of the biosphere revisited  

Energy Technology Data Exchange (ETDEWEB)

A decade ago, Lovelock and Whitfield raised the question of how much longer the biosphere can survive on Earth. They pointed out that, despite the current fossil-fuel induced increase in the atmospheric CO[sub 2] concentration, the long-term trend should be in the opposite direction: as increased solar luminosity warms the Earth, silicate rocks should weather more readily, causing atmospheric CO[sub 2] to decrease. In their model, atmospheric CO[sub 2] falls below the critical level for C3 photosynthesis, 150 parts per million (p.p.m.), in only 100 Myr, and this is assumed to mark the demise of the biosphere as a whole. Here, this problem is re-examined using a more elaborate model that includes a more accurate treatment of the greenhouse effect of CO[sub 2] a biologically mediated weathering parameterization, and the realization that C4 photosynthesis can persist to much lower concentrations of atmospheric CO[sub 2] ([lt]10 p.p.m.). It was ...

1992-12-24

451

The earth is warming up while the sky is getting a chill; La terre se rechauffe, le ciel a un coup de froid  

Energy Technology Data Exchange (ETDEWEB)

The phenomenon of global warming, its causes and implications for the future, and the relationship between global warming and the depletion of the ozone layer are discussed. The Shindell model of the greenhouse effect, which is responsible for planetary warming, also contributes to the high altitude thinning of the ozone layer. While greenhouse gas emissions contribute to retaining infrared radiation, thus warming the surface of the earth, their effect is reduced at stratospheric altitudes resulting in reduced temperatures in this region. At this altitude temperatures can reach minus 90 degrees C, creating a whirlwind effect, with ice crystals forming at the heart of the vortex, causing the surface to accelerate chemical reactions which in turn leads to destruction of ozone. Although since the signing of the Montreal Protocol in 1987 the industrialized countries have significantly reduced their emissions of refrigerating gas (chlorofluorocarbons or CFC), which were ...

2001-03-01

452

Strategic environmental management: The emergence of a new competitive requirement for American industry  

Energy Technology Data Exchange (ETDEWEB)

The environmental management infrastructure that has evolved in the United States over the last 25 years or so, since {open_quotes}the environment{close_quotes} burst into the national consciousness with events like Love Canal and Earth Day in the early 1970s. Increasingly, U.S. businesses must successfully compete with those of other nations to survive. Organizational re-engineering, cycle-time management, concurrent engineering, and lean manufacturing are just a few examples of corporate efforts to become better global competitors. U.S. environmental management systems, with their various inefficiencies, can hardly be excluded from these improvement initiatives. Businesses must find ways to reduce or control their environmental costs and, where possible, find ways that {open_quotes}environment{close_quotes} can add positive value to their goods and services. Secondly, although considerable progress has been made in some areas, such as the development of cleaner ...

1995-09-01

453

Hydrogeologic investigations related to seepage and instability phenomena within and adjacent the earth structures at Grand Rapids Generating Station, Manitoba  

Energy Technology Data Exchange (ETDEWEB)

This study evaluated potential hydrogeologic mechanisms that may account for increasing moisture content conditions within the sediments of hydroelectric earth dams. Many such dams in Canada are reaching their life spans of approximately 40 years, therefore this study is considered to be an important and timely undertaking. The objective was to develop a method to numerically assess transient groundwater flow processes within old earth structures. The focus of this study was central Manitoba's Grand Rapids Generating Station where progressive movement within the till overburden has been observed since 1977. The possible source of water which is causing higher moisture content and weakness in the overburden material may be the slow wetting-up of the core and progressive increase in seepage to the downstream side. The evolution of flow through the core was evaluated with a modelling program called FRAC3D-VS which accounts for transient ...

2002-07-01

454

Crystalline electric field of the rare-earth nickelates RniO{sub 3} (R = Pr, ND, Sm, Eu, and Pr{sub 1-x}La{sub x},0 {le} X {le} 0.7) determined by inelastic neutron scattering.  

Energy Technology Data Exchange (ETDEWEB)

The rare-earth based nickelates RNiO{sub 3} (R = Pr, Nd, Sm, Eu, and Pr{sub 1-x}La{sub x}, 0{<=}x{<=}0.7) were studied by inelastic neutron scattering. Energy splittings due to the crystalline-electric-field (CEF) interaction at the R{sup 3+} site within the electronic ground-state J multiplet (for R = Pr, Nd, and Pr{sub 1-x}La{sub x}) as well as within the two lowest-lying J multiplets (for R = Sm and Eu) were directly observed, and the corresponding CEF energy-level schemes were reconstructed. The latter were rationalized in terms of CEF parameters, which vary smoothly over the rare-earth series and give magnetic properties associated with the R sublattice in agreement with results from neutron powder diffraction experiments. Across the metal-insulator transition, a continuous change in the electronic part of the CEF parameters is observed. However, an attempt to quantify a charge transfer from the observed variation of the CEF ...

1999-12-01

455

Crystalline electric field of the rare-earth nickelates RNiO{sub 3} (R=Pr, Nd, Sm, Eu, and Pr{sub 1-x}La{sub x}, 0{<=}x{<=}0.7) determined by inelastic neutron scattering  

Energy Technology Data Exchange (ETDEWEB)

The rare-earth based nickelates RNiO{sub 3} (R=Pr, Nd, Sm, Eu, and Pr{sub 1-x}La{sub x}, 0{<=}x{<=}0.7) were studied by inelastic neutron scattering. Energy splittings due to the crystalline-electric-field (CEF) interaction at the R{sup 3+} site within the electronic ground-state J multiplet (for R=Pr, Nd, and Pr{sub 1-x}La{sub x}) as well as within the two lowest-lying J multiplets (for R=Sm and Eu) were directly observed, and the corresponding CEF energy-level schemes were reconstructed. The latter were rationalized in terms of CEF parameters, which vary smoothly over the rare-earth series and give magnetic properties associated with the R sublattice in agreement with results from neutron powder diffraction experiments. Across the metal-insulator transition, a continuous change in the electronic part of the CEF parameters is observed. However, an attempt to quantify a charge transfer from the observed variation of the CEF ...

1999-12-01

456

Crystalline electric field of the rare-earth nickelates RNiO_3 (R=Pr, Nd, Sm, Eu, and Pr_1_-_xLa_x, 0#<=#x#<=#0.7) determined by inelastic neutron scattering  

International Nuclear Information System (INIS)

The rare-earth based nickelates RNiO_3 (R=Pr, Nd, Sm, Eu, and Pr_1_-_xLa_x, 0#<=#x#<=#0.7) were studied by inelastic neutron scattering. Energy splittings due to the crystalline-electric-field (CEF) interaction at the R"3"+ site within the electronic ground-state J multiplet (for R=Pr, Nd, and Pr_1_-_xLa_x) as well as within the two lowest-lying J multiplets (for R=Sm and Eu) were directly observed, and the corresponding CEF energy-level schemes were reconstructed. The latter were rationalized in terms of CEF parameters, which vary smoothly over the rare-earth series and give magnetic properties associated with the R sublattice in agreement with results from neutron powder diffraction experiments. Across the metal-insulator transition, a continuous change in the electronic part of the CEF parameters is observed. However, an attempt to quantify a charge transfer from the observed variation of the CEF parameters in an effective point charge ...

1999-12-01

457

Crystal structure of ABPO{sub 5} and optical study of Pr{sup 3+} embedded in these compounds  

Energy Technology Data Exchange (ETDEWEB)

The crystal structure of borophosphates ABPO{sub 5} (A = alkaline earth or Pb) was resolved on a polycrystalline sample using the Rietveld method. The x-ray diffraction patterns data show that ABPO{sub 5} crystallize in a centrosymmetric space group P3{sub 1}21 and their structure is related to the borogermanates REBGeO{sub 5} with a stillwellite-type structure. Pr{sup 3+} ion was used as a local structural probe to corroborate the structural resolution results. Absorption and fluorescence spectra of A{sub 1-x}Pr{sub x}BP{sub 1-x}Ge{sub x}O{sub 5} (A alkaline earth or Pb; x = 0.05) have been investigated at different temperatures. At 9 K the 3{sup H}{sub 4}{yields}{sup 3}P{sub 0} transition of trivalent praseodymium ion (4f{sup 2} configuration) is observed as a single line. This indicates a unique crystallographic site for the rare earth ion in these compounds replacing the divalent cation. Energy level schemes were ...

2001-10-22

458

Crystal structure of ABPO_5 and optical study of Pr"3"+ embedded in these compounds  

International Nuclear Information System (INIS)

The crystal structure of borophosphates ABPO_5 (A = alkaline earth or Pb) was resolved on a polycrystalline sample using the Rietveld method. The x-ray diffraction patterns data show that ABPO_5 crystallize in a centrosymmetric space group P3_121 and their structure is related to the borogermanates REBGeO_5 with a stillwellite-type structure. Pr"3"+ ion was used as a local structural probe to corroborate the structural resolution results. Absorption and fluorescence spectra of A_1_-_xPr_xBP_1_-_xGe_xO_5 (A alkaline earth or Pb; x = 0.05) have been investigated at different temperatures. At 9 K the 3"H_4#->#"3P_0 transition of trivalent praseodymium ion (4f"2 configuration) is observed as a single line. This indicates a unique crystallographic site for the rare earth ion in these compounds replacing the divalent cation. Energy level schemes were deduced from the low-temperature spectroscopic measurements. Comparing the ...

2001-10-22

459

Characteristics of oxidation reaction of rare-earth chlorides for precipitation in LiCl-KCl molten salt by oxygen sparging  

International Nuclear Information System (INIS)

The precipitation reaction of some rare earth chlorides (La/Ce/Nd/GdCl3) in a LiCl-KCl molten salt has been carried out by using the oxygen sparging method. In this study, regardless of the oxygen sparging time and the molten salt temperature, oxychlorides (REOCl) for LaCl3, NdCl3 and GdCl3, and an oxide (REO2) for CeCl3 are formed as a precipitate. The conversion of rare-earth chlorides into insoluble precipitates was described by using a conversion ratio. The conversion ratio increased exponentially with the oxygen sparging time and finally showed asymptotic value at 1,023K of the molten salt temperature condition. The conversion ratios of LaCl3, NdCl3 and GdCl3 were increased with the molten salt temperature, however, even though the conversion ratio was increased from 0.660 to 0.995 with increasing molten salt temperature from 823 to 923 K at 60 min of a sparging time, the values of the conversion ratio of CeCl3 were nearly constant (over ...

2006-10-01

460

The genesis solar-wind sample return mission  

Energy Technology Data Exchange (ETDEWEB)

The compositions of the Earth's crust and mantle, and those of the Moon and Mars, are relatively well known both isotopically and elementally. The same is true of our knowledge of the asteroid belt composition, based on meteorite analyses. Remote measurements of Venus, the Jovian atmosphere, and the outer planet moons, have provided some estimates of their compositions. The Sun constitutes a large majority, > 99%, of all the matter in the solar system. The elemental composition of the photosphere, the visible 'surface' of the Sun, is constrained by absorption lines produced by particles above the surface. Abundances for many elements are reported to the {+-}10 or 20% accuracy level. However, the abundances of other important elements, such as neon, cannot be determined in this way due to a relative lack of atomic states at low excitation energies. Additionally and most importantly, the isotopic composition of the Sun cannot be ...

2009-01-01

461

The influence of CeO_2 on the corrosion resistance of laser remelted alloy spray coatings on steel  

International Nuclear Information System (INIS)

The main compositions of iron-base amorphous self-fluxing alloy powders of 150 mesh, used in this work, are Fe, Cr, Ni, W, Mo, B, Si and C. The ranges of each element in at% are (65-70)Fe, (3-5)Cr, (2-4)Ni, (2-4)W, (1-2)Mo, (10-14)B, (4-7)Si and (2-3)C. The atomic ratio of metal-metalloid is about 80:20, so this alloy is abbreviated as M_8_0X_2_0. The material on which coatings were deposited is 1020 steel, austenitized for 1h at 880 C, water quenched, and tempered at 180 C for 1h. This heat treatment resulted in a low carbon martensite structure with a hardness of HRC35-45. After cleaning, shot blasting and preheating the steel to about 200 C, the authors sprayed a thin Ni-Al alloy layer of about 0.1--0.15mm in thickness onto the specimen by means of an oxygen-acetylene torch to provide better bonding of the coating with substrate. Then the M_8_0X_2_0 and M_8_0X_2_0+8%CeO_2 alloy coatings were sprayed to a thickness of about 0.6--0.8mm. The CeO_2 was added as particles of 200 mesh, ...

462

The GEOFLOW experiment missions in the Fluid Science Laboratory on ISS  

Science.gov (United States)

The GEOFLOW I experiment has been successfully performed on the International Space Sta-tion (ISS) in 2008 in the Columbus module in order to study the stability, pattern formation and transition to turbulence in a viscous incompressible fluid layer enclosed in two concentric co-rotating spheres subject to a radial temperature gradient and a radial volumetric force field. The objective of the study is the experimental investigation of large scale astrophysical and geophysical phenomena in spherical geometry stipulated by rotation, thermal convections and radial gravity fields. These systems include earth outer core or mantle convection, differen-tial rotation effects in the sun, atmosphere of gas planets as well as a variety of engineering applications. The GEOFLOW I experimental instrument consists of an experiment insert for operation in the Fluid Science Laboratory, which is part of the Columbus Module of the ISS. It was first launched in February 2008 together ...

2010-01-01

463

Rare earth metal rich magnesium compounds RE4NiMg (RE=Y, Pr-Nd, Sm, Gd-Tm, Lu)-Synthesis, structure, and hydrogenation behavior  

International Nuclear Information System (INIS)

The rare earth metal rich compounds RE4NiMg (RE=Y, Pr-Nd, Sm, Gd-Tm, Lu) were synthesized from the elements in sealed tantalum tubes in an induction furnace. All compounds were investigated by X-ray diffraction on powders and single crystals: Gd4RhIn type, space group F4-bar 3m, Z=16, a=1367.6(2) pm for Y4NiMg, a=1403.7(3) pm for Pr4NiMg, a=1400.7(1) pm for Nd4NiMg, a=1386.5(2) pm for Sm4NiMg, a=1376.1(2) pm for Gd4NiMg, a=1362.1(1) pm for Tb4NiMg, a=1355.1(2) pm for Dy4NiMg, a=1355.2(1) pm for Ho4NiMg, a=1354.3(2) pm for Er4NiMg, a=1342.9(3) pm for Tm4NiMg, and a=1336.7(3) pm for Lu4NiMg. The nickel atoms have trigonal prismatic rare earth coordination. These NiRE6 prisms are condensed via common edges to a three-dimensional network which leaves voids for Mg4 tetrahedra and the RE1 atoms which show only weak coordination to the nickel atoms. The single crystal data indicate two kinds of solid solutions. The RE1 positions reveal small RE1/Mg ...

2009-02-01

464

Uptake of Pb by human skeleton and comparative metabolism of Pb and alkaline earth elements  

Energy Technology Data Exchange (ETDEWEB)

Measurements of the retention of /sup 47/Ca and of /sup 203/Pb were made following their administration by intravenous injection. Translocation to bone was measured by ..gamma.. counting the feet of subjects. Uptake by bone of /sup 203/Pb was comparatively slow and extrapolation to the whole skeleton indicated that 20% of the dose has been taken up within 20 days. By time, a similar fraction of the dose has been excreted in urine. Uptake by bone of /sup 47/Ca was about 1.5-2 times the amount excreted in urine. Both the uptake by bone, and its excretion in urine, were more rapid than that of /sup 203/Pb due to the greater attachment of the latter to red blood cells. However, the plasma clearance rate for Pb, like that of Sr, was greater than that of Ca.

1984-12-01

465

The kinematics of coronal mass ejections using multiscale methods  

CERN Document Server

The diffuse morphology and transient nature of coronal mass ejections (CMEs) make them difficult to identify and track using traditional image processing techniques. We apply multiscale methods to enhance the visibility of the faint CME front. This enables an ellipse characterisation to objectively study the changing morphology and kinematics of a sample of events imaged by the Large Angle Spectrometric Coronagraph (LASCO) onboard the Solar and Heliospheric Observatory (SOHO) and the Sun Earth Connection Coronal and Heliospheric Investigation (SECCHI) onboard the Solar Terrestrial Relations Observatory (STEREO). The accuracy of these methods allows us to test the CMEs for non-constant acceleration and expansion. We exploit the multiscale nature of CMEs to extract structure with a multiscale decomposition, akin to a Canny edge detector. Spatio-temporal filtering highlights the CME front as it propagates in time. We apply an ellipse parameterisation of the front to ...

2009-01-01

466

The impact of solar flares and magnetic storms on humans  

International Nuclear Information System (INIS)

Three classes of solar emanations, namely, photon radiation from solar flares, solar energetic particles, and inhomogeneities in the solar wind that drive magnetic storms, are examined, and their effects on humans and technological systems are discussed. Solar flares may disrupt radio communications in the HF and VLF ranges. Energetic particles pose a special hazard at low-earth orbit and above, where they can penetrate barriers such as spacesuits and aluminum and destroy cells and solid state electronics. Energetic solar particles also influence terrestrial radio waves propagating through polar regions. Magnetic storms may disturb the operation of navigation instruments, power lines and pipelines, and satellites; they give rise to ionospheric storms which affect radio communication at all latitudes. There is also a growing body of evidence that changes in the geomagnetic field affect biological systems. 3 refs.

467

The Huqf Supergroup of Oman: Basin development and context for Neoproterozoic glaciation  

British Library Electronic Table of Contents (United Kingdom)

The Huqf Supergroup of the Sultanate of Oman provides important information on the geological evolution of the Arabian?Persian Gulf region during a protracted period of continental dispersal and reassembly on the periphery of the Gondwanan supercontinent during the Neoproterozoic, and also provides important constraints on the nature of extreme climate swings during this critical period in the evolution of Earth's biosphere. The Huqf Supergroup spans the period ca. 725?540?Ma, and is composed of three groups. The Abu Mahara Group (ca. 725 to ca.ca. 547?540?Ma), which is known mostly from the subsurface, comprises carbonates, evaporites and organic-rich shales, with interbedded ashes, deposited in a large number of N?S trending troughs and platforms.The three groups of the Huqf Supergroup c...

2007-01-01

468

Surface analysis by Fourier-transform infrared (FTIR) spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

A diffuse-reflectance capability for the Fourier transform infrared spectrometer at the Y-12 Plant Laboratory has been implemented. A sample cell with a 25 to 400/sup 0/C temperature-controlled sample stage and an ultrahigh-vacuum-to-atmospheric pressure gas-handling capability has been developed. Absorbance of light from the spectrometer beam, resulting from the beam being scattered from a powder sample, can be measured. This capability of detecting molecular species on and in powders is to be used to study chemisorption on actinide and rare-earth metals, alloys, and compounds. Cell design is described along with experiments demonstrating its performance in detecting moisture absorption on uranium oxide, moisture and carbon dioxide absorption on the lithium hydride/hydroxide system, and carbon dioxide absorption on potassium borohydride. 13 figures.

1981-08-12

469

Superconductivity on the threshold of magnetism in CePd{sub 2}Si{sub 2} and CeIn{sub 3}  

Energy Technology Data Exchange (ETDEWEB)

The magnetic ordering temperature of some rare-earth-based heavy-fermion compounds is strongly pressure dependent and can be completely suppressed at a critical pressure, p{sub c}, making way for novel correlated electron states close to this quantum critical point. We have studied the clean heavy-fermion antiferromagnets CePd{sub 2}Si{sub 2} and CeIn{sub 3} in a series of resistivity measurements at high pressures up to 3.2 GPa and down to temperatures in the mK region. In both materials, superconductivity appears in a small window of a few tenths of a GPa on either side of p{sub c}. We present detailed measurements of the superconducting and magnetic temperature-pressure phase diagram, which indicate that superconductivity in these materials is enhanced, rather than suppressed, by the closeness to magnetic order. (author)

2001-03-26

470

Superconductivity on the threshold of magnetism in CePd_2Si_2 and CeIn_3  

International Nuclear Information System (INIS)

The magnetic ordering temperature of some rare-earth-based heavy-fermion compounds is strongly pressure dependent and can be completely suppressed at a critical pressure, p_c, making way for novel correlated electron states close to this quantum critical point. We have studied the clean heavy-fermion antiferromagnets CePd_2Si_2 and CeIn_3 in a series of resistivity measurements at high pressures up to 3.2 GPa and down to temperatures in the mK region. In both materials, superconductivity appears in a small window of a few tenths of a GPa on either side of p_c. We present detailed measurements of the superconducting and magnetic temperature-pressure phase diagram, which indicate that superconductivity in these materials is enhanced, rather than suppressed, by the closeness to magnetic order. (author)

2001-03-26

471

Superconductivity in the ternary rare-earth (Y, La, and Lu) compounds RPd_2Si_2 and RRh_2Si_2  

International Nuclear Information System (INIS)

We have investigated the superconducting and metallurgical properties of the ternary compounds RPd_2Si_2 and RRh_2Si_2 with R = Y, La, and Lu. All RPd_2Si_2 compounds and LaRh_2Si_2 were found to be type-I superconductors below 1 K. A detailed metallurgical analysis shows that segregation of second phases can easily mask the intrinsic (stoichiometric ratio 1:2:2) intermetallic-compound properties. Two sample-preparation techniques, viz., single crystals and off-stoichiometry, were utilized to establish where bulk superconductivity occurs. The type-I behavior of these compounds is explained with an analogous model as is used for the heavy-fermion superconductors CeCu_2Si_2 and URu_2Si_2.

472

Structures and properties of functional metal iodates  

British Library Electronic Table of Contents (United Kingdom)

Metal iodates with a lone-pair containing I(V) that is in an asymmetric coordination geometry can form a diversity of unusual structures and many of them are promising new second homonic generation (SHG) materials. They exhibit wide transparency wavelength regions, large SHG coefficients and high optical-damage thresholds as well as moderately high thermal stability. In this paper, the structures and properties of the metal iodates are reviewed. The combination of d0 transition-metal cations with the iodate groups afforded a large number of metal iodates, with cations covering alkali metal, alkaline earth and lanthanide elements. Many of them are noncentrosymmetric (NCS) and display excellent SHG properties due to the additive effects of polarizations from both types of the asymmetric unit...

2011-01-01

473

Spectroscopic properties of Pr"3"+ doped LaWO_4Cl and La_3WO_6Cl_3  

International Nuclear Information System (INIS)

The spectroscopic properties of Pr"3"+ doping two lanthanum chlorotungstate hosts: the orthorhombic LaWO4Cl (1-1) and the hexagonal La3WO4Cl6 (3-1), as well as those of PrWO4Cl and Pr3wO613 have been investigated. The simulations of the energy level schemes are carried out within the crystal field theory frame. Each simulation involves 7 free ion parameters and 14 non-zero crystal field parameters (cfps), corresponding to the C_s point symmetry of the site occupied by the rare earth, in both structures.

1992-01-01

474

Spectroscopic properties of Pr sup 3+ doped LaWO sub 4 Cl and La sub 3 WO sub 6 Cl sub 3  

Energy Technology Data Exchange (ETDEWEB)

The spectroscopic properties of Pr{sup 3+} doping two lanthanum chlorotungstate hosts: the orthorhombic LaWO4Cl (1-1) and the hexagonal La3WO4Cl6 (3-1), as well as those of PrWO4Cl and Pr3wO613 have been investigated. The simulations of the energy level schemes are carried out within the crystal field theory frame. Each simulation involves 7 free ion parameters and 14 non-zero crystal field parameters (cfps), corresponding to the C{sub s} point symmetry of the site occupied by the rare earth, in both structures.

1992-01-01

475

Source and mobility of minor and trace elements in a volcanic aquifer system: Mt. Vulture (southern Italy)  

British Library Electronic Table of Contents (United Kingdom)

In this paper we provide a geochemical investigation on 34 groundwater samples in the Mt. Vulture volcanic aquifer representing one of the most important groundwater resources of the southern Italy pumped for drinking and irrigation supply. The present study includes the first data on the abundance and mobility of minor and trace elements and the thermodynamic considerations on water-rock interaction processes in order to evaluate the conditions of alkali basalt weathering by waters enriched in magma-derived CO2. The results highlight the occurrence of two hydrofacies: bicarbonate alkaline-earth and alkaline waters deriving from low-temperature leaching of volcanic rocks of Mt. Vulture, and bicarbonate-sulfate-alkaline waters (high-salinity waters) related to prolonged water circulation in...

2011-01-01

476

Separation of rubidium from irradiated aluminum-encapsulated uranium  

International Nuclear Information System (INIS)

A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.

1993-05-01

477

Separation of rubidium from irradiated aluminum-encapsulated uranium  

Energy Technology Data Exchange (ETDEWEB)

A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.

1982-01-01

478

Probing Student Understanding of Scientific Thinking in the Context of Introductory Astrophysics  

Science.gov (United States)

Common forms of testing of student understanding of science content can be misleading about their understanding of the nature of scientific thinking. Observational astronomy integrated with related ideas of force and motion is a rich context to explore the correlation between student content knowledge and student understanding of the scientific thinking about that content. In this paper, we describe this correlation in detail with a focus on a question about the relative motion of the Sun and the Earth. We find that high achieving high school students throughout New York City struggle with what constitutes scientific justification and thought processes, but can improve these skills tremendously in an inquiry-oriented summer astronomy-physics program. (Contains 3 tables and 4 figures.)

2008-12-01

479

Possible observation of the coexistence of superconductivity and long-range magnetic order in NdRh_4B_4  

International Nuclear Information System (INIS)

The ternary rare earth compound NdRh_4B_4 has been studied by means of critical field, low temperature heat capacity, and static magnetic susceptibility measurements. Features in the upper critical field and heat capacity data at 1.31 K and 0.89 K suggest the occurrence of long-range magnetic order in the superconducting state. The temperature dependence of the static magnetic susceptibility follows a Curie-Weiss law with an effective magnetic moment #mu#sub(eff) = 3.58 +- 0.05 #mu#sub(B) and a Curie-Weiss temperature thetasub(p) = -6.2 +- 1.0 K between 20 K and room temperature. However, magnetization vs. applied magnetic field isotherms suggest the development of a ferromagnetic component in the Nd"3"+ magnetization at low temperatures. (author).

1979-01-01

480

Physicochemical investigation of the behavior of elements in chloride melts in the presence of solid phases based on phosphates of polyvalent elements. II. Behavior of strontium and barium  

Energy Technology Data Exchange (ETDEWEB)

The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.

1987-07-01

481

Phylogeography of rabies virus isolated from dogs in Brazil between 1985 and 2006  

British Library Electronic Table of Contents (United Kingdom)

To establish the phylogeographic relationships in rabies viruses in Brazil, we studied a dataset retrieved from GenBank consisting of 71 genetic sequences from the coding region of the N gene of rabies viruses isolated in dogs over a period of 22?years. The Bayesian Markov chain Monte Carlo method available in the BEAST package was used with the GTR+G+?4 evolutionary model in conjunction with the relaxed uncorrelated lognormal molecular clock model and an exponential growth tree prior. A discrete phylogeographic diffusion model was also analyzed using a standard continuous-time Markov chain viewed with Google Earth to provide a spatial projection of the diffusion of genetic lineages based on their phylogeographic relationships. The topology of the time and substitution phylogenetic trees a...

2011-01-01

482

Numerical modeling of a Global Navigation Satellite System in a general relativistic framework  

CERN Document Server

In this article we model a Global Navigation Satellite System (GNSS) in a Schwarzschild space-time, as a first approximation of the relativistic geometry around the Earth. The closed time-like and scattering light-like geodesics are obtained analytically, describing respectively trajectories of satellites and electromagnetic signals. We implement an algorithm to calculate Schwarzschild coordinates of a GNSS user who receives proper times sent by four satellites, knowing their orbital parameters; the inverse procedure is implemented to check for consistency. The constellation of satellites therefore realizes a geocentric inertial reference system with no \\emph{a priori} realization of a terrestrial reference frame. We show that the calculation is very fast and could be implemented in a real GNSS, as an alternative to usual post-Newtonian corrections. Effects of non-gravitational perturbations on positioning errors are assessed, and methods to reduce them are ...

2010-01-01

483

New correlated electron physics from new materials  

British Library Electronic Table of Contents (United Kingdom)

Many important advances in the physics of strongly correlated electron systems have been driven by the development of new materials: for instance the filled skutterudites Formula Not Shown ( Formula Not Shown metal, alkaline earth, lanthanide, or actinide; Formula Not Shown , Ru, or Os; Formula Not Shown , As, or Sb), certain lanthanide and actinide intermetallic compounds such as Formula Not Shown and Formula Not Shown ( Formula Not Shown , Rh, or Ir), and layered oxypnictides and related materials. These types of complex multinary d- and f-electron compounds have proven to be a vast reservoir of novel strongly correlated electron ground states and phenomena. In these materials, the occurrence of such a wide range of ground states and phenomena arises from a delicate interplay between com...

2009-01-01

484

Neutron powder diffraction and solid-state deuterium NMR studies of Ca{sub 2}RuD{sub 6} and the stability of transition metal hexahydride salts  

Energy Technology Data Exchange (ETDEWEB)

The crystal structure of Ca{sub 2}RuD{sub 6} has been determined by neutron powder diffraction: space group Fm3m, K{sub 2}PtCl{sub 6} structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340 K and 50 K. The deuterium nuclear quadrupole coupling constant, 54.7 kHz, leads to an ionic character of the Ru-D bond of 76%. The known trends in the behaviour of A{sub 2}MH{sub 6} salts are interpreted in terms of the ionization energies of the cation and the central metal atom.

2008-07-28

485

Neutron powder diffraction and solid-state deuterium NMR studies of Ca2RuD6 and the stability of transition metal hexahydride salts  

British Library Electronic Table of Contents (United Kingdom)

The crystal structure of Ca2RuD6 has been determined by neutron powder diffraction: space group Fm3m, K2PtCl6 structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340K and 50K. The deuterium nuclear quadrupole coupling constant, 54.7kHz, leads to an ionic character of the Ru-D bond of 76%. The known trends in the behaviour of A2MH6 salts are interpreted in terms of the ionization energies of the cation and the central metal atom.

2008-01-01

486

Modelling Of Monazite Ore Break-Down By Alkali Process Spectrometry  

International Nuclear Information System (INIS)

A computer modelling has been developed for the calculation of mass balance of monazite ore break-down by alkali process at Rare Earth Research and Development Center. The process includes the following units : ore digestion by concentrate NaOH, dissolution of digested ore by HCl, uranium and thorium precipitation and crystallization of Na3PO4 which is by-product from this process. The model named RRDCMBP was prepared in Visual Basic language. The modelling program can be run on personal computer and it is interactive and easy to use. User is able to choose any equipment in each unit process and input data to get output of mass balance results. The model could be helpful in the process analysis for the further process adjustment and development.

2005-10-18

487

Modeling and numerical simulation of linear and nonlinear spacecraft attitude dynamics and gravity gradient moments: A comparative study  

British Library Electronic Table of Contents (United Kingdom)

In this paper linear and nonlinear models of spacecraft attitude dynamics equations and gravity gradient moments are investigated. In addition, effects of gravity gradient moments on attitude dynamics of the satellite are studied. The purpose of this paper is to present a comparison between nonlinear and linear models of spacecraft attitude dynamics and gravity gradient moments in order to determine divergence of linear approximation from the nonlinear model. Simulation results indicate that designer of spacecraft attitude control subsystem should be meticulous in applying linear approximation of equations especially in low earth orbits. Consequently, finding an upper bound for small angle to keep the linear model valid and precise enough would be a vital part of using linear approximation...

2012-01-01

488

Microstructure and mechanical behaviour of an elevated temperature Mg-rare earth based alloy  

International Nuclear Information System (INIS)

AM-SC1 is a heat treatable magnesium alloy that has been specifically developed to achieve the elevated temperature strength and creep properties necessary for engine block applications. This paper describes the interrelationship between the microstructure and the mechanical properties of AM-SC1. The compressive and tensile strengths are relatively insensitive to temperature up to and including 450 K and the tensile yield behaviour deviates from a standard Hall-Petch relationship at grain sizes below 200 ?m. The microstructural features contributing to the creep resistance are both inter- and intra-granular in nature and are on length scales from nanometers to micrometers. The creep behaviour at 423 K and 450 K is diffusion controlled, with any contribution from the grain boundaries being negligible.

2009-04-15

489

Magnetic separation anxiety  

International Nuclear Information System (INIS)

This paper reports that only a few years ago superconducting magnetic separation was viewed as the next major market for superconducting magnets. The first commercial units had been installed, worked flawlessly, and demonstrated real economic viability. The potential market was seen as quite large, and many people believed that superconducting magnetic separation would soon show the same rapid growth that MRI had demonstrated after its initial success. These hopes even prompted IGC, one of the top MRI magnet builders, to form a separate division devoted to magnetic separation. Despite the existence of Magstream, IGC has not been overly active in the market. As a technology that has applications from the clay on the Earth to the soil on the moon, superconducting magnetic separation has yet to become widely used.

1992-01-01

490

Magnetic properties of RPd_2Si ternary compounds with (R = Gd, Tb, Dy, Ho and Er)  

International Nuclear Information System (INIS)

Magnetic properties of polycrystalline samples of RPd_2Si compounds (R = Gd, Tb, Dy, Ho and Er) are presented. The Gd and Tb based compounds are antiferromagnetic with Neel temperatures of 13.5 and 21 K respectively. For both compounds a metamagnetic transition is observed in low field. Moreover, in TbPd_2Si a transition between two different antiferromagnetic phases is observed at 8.5 K. The Dy, Ho and Er based compounds are ferromagnetic with Curie temperatures of 9, 3.5 ad 2.8 K respectively. The observed properties result from indirect exchange interactions and crystal field effects acting on rare earth ions which lie in a very low symmetry site. (author).

491

Magnetic properties of RPd/sub 2/Si ternary compounds with (R = Gd, Tb, Dy, Ho and Er)  

Energy Technology Data Exchange (ETDEWEB)

Magnetic properties of polycrystalline samples of RPd/sub 2/Si compounds (R = Gd, Tb, Dy, Ho and Er) are presented. The Gd and Tb based compounds are antiferromagnetic with Neel temperatures of 13.5 and 21 K respectively. For both compounds a metamagnetic transition is observed in low field. Moreover, in TbPd/sub 2/Si a transition between two different antiferromagnetic phases is observed at 8.5 K. The Dy, Ho and Er based compounds are ferromagnetic with Curie temperatures of 9, 3.5 ad 2.8 K respectively. The observed properties result from indirect exchange interactions and crystal field effects acting on rare earth ions which lie in a very low symmetry site.

1984-01-01

492

K S Krishnan and the early experimental evidences for the Jahn-Teller Theorem  

CERN Document Server

Jahn-Teller theorem, proposed in 1937, predicts a distortional instability for a molecule that has symmetry based degenerate electronic states. In 1939 Krishnan emphasized the importance of this theorem for the arrangement of water molecules around the transition metal or rare earth ions in aqueous solutions and hydrated saltes, in a short and interesting paper published in Nature by pointing out atleast four existing experimental results in support of the theorem. This paper of Krishnan has remained essentially unknown to the practitioners of Jahn-Teller effect, eventhough it pointed to the best experimental results that were available, in the 30's and 40's, in support of Jahn-Teller theorem. Some of the modern day experiments are also in conformity with some specific suggestions of Krishnan.

1998-01-01

493

High frequency converters for thermophotovoltaic applications  

Energy Technology Data Exchange (ETDEWEB)

Thermophotovoltaic (TPV) converters were developed and tested at the heat source operating temperature of 1,700 K. Rare-earth-doped yttrium aluminum garnet (YAG) and lutetium yttrium aluminum garnet (Lu, YAG) selective emitters, as well as a blackbody emitter, were coupled to InGaAs/InP photovoltaic (PV) cells and bandpass/infrared (IR) reflector filters. YAG-based selective emitters were adopted with Ho, Tm, and Er. PV cells had bandgaps of 0.51, 0.57, and 0.69 eV. Converter energy conversion efficiencies approaching 30%, as well as electrical output power densities near 2 W/cm{sup 2} were demonstrated. The overall performance of the filtered blackbody-based converter was found to be superior to the selective emitter YAG-based converters. The details of the measurements performed on the above converters and their individual components are presented.

1996-12-31

494

Enhanced catalytic activity of Fe bimetallic modified PAN fiber complexes prepared with different assisted metal ions for degradation of organic dye  

British Library Electronic Table of Contents (United Kingdom)

Two transition metal ions (Cu^2^+ and Co^2^+) and two rare earth metal ions (Ce^3^+ and La^3^+) were used as the assisted metal ions, respectively to prepare the transition metal and rare metal assisted Fe bimetallic amidoximated polyacrylonitrile (AO-PAN) fiber complexes. And their coordination configuration and visible light adsorption properties were examined by coordination number determination and UV-vis-DRS. Then the catalytic performance of these complexes was evaluated as the heterogeneous Fenton catalysts in Rhodamine B degradation by changing the nature and dosage of the assisted ions added. The results indicated that the incorporation of the assisted metal ions led to Fe bimetallic AO-PAN complexes with the more unsaturated configurations than Fe monometallic AO-PAN complex due ...

2011-01-01

495

Computer system for digitizing, analyzing and plotting well log data (a user's guide to WELLOG. Rev. 1)  

Energy Technology Data Exchange (ETDEWEB)

WELLOG is a system of programs developed at the Earth Science Laboratory to be used to digitize well logs and perform some analysis and plotting of the data. Multiple logs can be plotted side by side for correlation analysis and up to three logs can be plotted in a cross plot. Data entry and editing functions are also provided by the programs. This system of well log interpretation programs is presently operating on the University of Utah UNIVAC 1108 computer. Digitizing of well logs is accomplished by an old model CALMA (off-line) digitizer. Those parts of WELLOG that handle the digitized data tapes are extremely machine dependent. The parts of WELLOG that produce the plots and handle the data beyond the digitized data tape are more portable.

1980-03-01

496

Comparison of effectiveness of three radon detectors (LR115, CR39 and silicon diode pin) placed in a cylindrical device -theory and experimental techniques  

Energy Technology Data Exchange (ETDEWEB)

Researchers at the Laboratory of Nuclear Microanalysis in Besancon (France) are developing and improving radon measurements in order to detect and analyse, more precisely radon emanation anomalies in both fields of Earth Sciences and Radioprotection. In order to characterize radon emanation, two complementary techniques are developed; continuous measurement through a portable proportional counter and passive measurements by nuclear track detectors for both fieldwork and laboratory analysis. A mathematical model is being devised to interpret the nuclear track detector response. This model is performed according to the device characteristics: type of detectors, shape and size of cells and whether a membrane is used or not. In addition to the theoritical study, experimental radon concentration measurements will be reported. (author).

1993-12-31

497

Comparison of effectiveness of three radon detectors (LR115, CR39 and silicon diode pin) placed in a cylindrical device -theory and experimental techniques  

International Nuclear Information System (INIS)

Researchers at the Laboratory of Nuclear Microanalysis in Besancon (France) are developing and improving radon measurements in order to detect and analyse, more precisely radon emanation anomalies in both fields of Earth Sciences and Radioprotection. In order to characterize radon emanation, two complementary techniques are developed; continuous measurement through a portable proportional counter and passive measurements by nuclear track detectors for both fieldwork and laboratory analysis. A mathematical model is being devised to interpret the nuclear track detector response. This model is performed according to the device characteristics: type of detectors, shape and size of cells and whether a membrane is used or not. In addition to the theoritical study, experimental radon concentration measurements will be reported. (author).

498

CRC handbook of NASA future missions and payloads  

Energy Technology Data Exchange (ETDEWEB)

The author presents a detailed and quantitative description of all of the programs, systems, sensors and experiments associated with the next 30 years of space endeavors by the National Aeronautics and Space Administration. Derived from the fifth issue of the NASA Space Systems Technology Model, the missions and payloads are categorized by applications area: solar system exploration, astrophysics, earth sciences, communications, space transportation and utilization of the space environment. Far-term missions are described as opportunity missions and landmark missions, for the distant future. Technology requirements are collected by discipline: power, propulsion, materials, structures, information systems, navigation, guidance and control. Payload technology requirements are organized by instrument sensing range. This information defines in quantitative terms, the opportunities and limits for future civilian space system capabilities.

1986-01-01

499

Assessing variability of water quality in a groundwater-fed perennial lake of Kashmir Himalayas using linear geostatistics  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a study on Manasbal lake, which is one of the high altitude lakes in the Kashmir Valley, India. Eighteen water samples were analysed for major ions and trace elements to assess the variability of water quality of the lake for various purposes. Geostatistics, the theory of regionalized variables, was then used to enhance the dataset and estimate some missing spatial values. Results indicated that the concentration of major ions in the water samples in winter was higher than in summer. The scatter diagrams suggested the dominance of alkaline earths over the alkali elements. Three types of water were identified in the lake that are referred to as Ca?HCO3, Mg?HCO3 and hybrid types. The lake water was found to be controlled by rock?water interaction with carbonate lithology ...

2011-01-01

500

An introduction to climate change: a Canadian perspective  

Energy Technology Data Exchange (ETDEWEB)

Current scientific knowledge of climate change and its global impact is summarized in the first four chapters. The earth's natural climate, greenhouse gases, climate prediction models, and impact of a warmer world on natural terrestrial ecosystems, agricultural ecosystems, and coastal regions are discussed. The possible impacts on Canada are described in chapter five, which considers forests, agriculture, water resources, fisheries, coastal zones, transportation, human health and well being, energy production and use, and global security. Chapter six considers ways to respond to climate change. These include enhancing knowledge of climate change, working toward a consensus on the need for action, global political response, the Canadian response, and the role of the individual. 15 refs., 35 figs.

2005-10-15