Abstract in english We consider the three dimensional electromagnetic inverse scattering problem of determining information about a buried coated object from a knowledge of the electric and magnetic fields measured on the surface of the earth corresponding to time harmonic electric dipoles as incident fields. We assume that the buried object is a perfect conductor that is (possibly) partially coated by a thin dielectric layer. No a priori assumption is made on the extent of the coating, i.e. (more) the object can be fully coated, partially coated or not coated at all. We present an algorithm based on the linear sampling method and reciprocity gap functional for reconstructing the shape of the scattering obstacle together with an estimate of the surface impedance of the coating.
In situ spectroscopic ellipsometry was employed to investigate the initial regime of rare earth metal (REM) conversion coatings formation on AZ31 magnesium alloy. Three REM salts solutions, 0.05 mol.dm"-"3 Ce(NO_3)_3, La(NO)_3 and Sm(NO)_3 solutions, were used for REM conversion coatings preparation. By deconvoluting the ellipsometric data, the surface of the fresh well-polished AZ31 magnesium alloy was found to be covered with 15.80 nm thick native (hydr)oxide film; the refractive indices and the thickness of Ce, La and Sm conversion coatings were obtained. The formation kinetics of three REM coatings follows different exponential functions and the coatings exhibit different optical properties. La conversion coating has the largest n values and the lowest k values while Sm conversion coating is just opposite. Moreover, ...
The main compositions of iron-base amorphous self-fluxing alloy powders of 150 mesh, used in this work, are Fe, Cr, Ni, W, Mo, B, Si and C. The ranges of each element in at% are (65-70)Fe, (3-5)Cr, (2-4)Ni, (2-4)W, (1-2)Mo, (10-14)B, (4-7)Si and (2-3)C. The atomic ratio of metal-metalloid is about 80:20, so this alloy is abbreviated as M_8_0X_2_0. The material on which coatings were deposited is 1020 steel, austenitized for 1h at 880 C, water quenched, and tempered at 180 C for 1h. This heat treatment resulted in a low carbon martensite structure with a hardness of HRC35-45. After cleaning, shot blasting and preheating the steel to about 200 C, the authors sprayed a thin Ni-Al alloy layer of about 0.1--0.15mm in thickness onto the specimen by means of an oxygen-acetylene torch to provide better bonding of the coating with substrate. Then the M_8_0X_2_0 and M_8_0X_2_0+8%CeO_2 alloy coatings were sprayed to a thickness of ...
Power plant components exposed to environments such as water and soil are susceptible to severe corrosion. Many times the effect of corrosion in power plant components can be catastrophic. The problem is aggravated for underground pipelines due to additional factors such as large network of pipelines, proximity to earth mat, high voltage transmission lines, corrosive chemicals, inadequate approach etc. Other components such as condenser water boxes, internals of pipelines, clarifier bridge structures, cooling water inlet gates and pipes etc. which are in continuous contact with water, are subjected to severe corrosion. The nature and locations of all such components are at places which are not accessible for routine maintenance and hence they require long term reliable protection against corrosion. Experience has shown that anti-corrosive coatings are inadequate in preventing corrosion and due to their location regular maintenance ...
Buffer layers with 100% lattice match with YBa2Cu3O7 - ? (YBCO) were prepared from mixed rare-earth-oxides applying a simple sol-gel process and dip-coating method. Structural analysis of the sol-gel derived powder by X-ray diffraction revealed that the mixing parameter, which eliminates the lattice mismatch with YBCO, is x = 0.2382, 0.1852, 0.1252, 0.0906, 0.0793 and 0.0395 in (Eu1 - xHox)2O3, (Eu1 - xErx)2O3, (Eu1 - xYbx)2O3, (Gd1 - xHox)2O3, (Gd1 - xYx)2O3 and (Gd1 - xYbx)2O3, respectively. Microstructural investigations were carried out for Gd1.819Ho0.181O3 films epitaxially grown on cube-textured Ni (100) substrates by sol-gel dip-coating process. X-ray diffraction of the buffer showed strong out-of-plane orientation on Ni tape. The (Gd1 - xHox)2O3 (222) pole figure indicated a single cube-on-cube textured structure. The omega and phi scans revealed good out-of-plane and in-plane alne alignments. The full-width at ...
Magmatic sulfide deposits are the most significant source of platinum-group elements (PGE) in the world. Key to understanding their genesis is determining the processes and timing of sulfide saturation, metal enrichment and crustal contamination. In this study, we have identified droplets of magmatic sulfide from the Platreef, South Africa, where droplets of sulfide have been trapped in the earliest crystallising phase, chromite. Due to their early entrapment at high temperatures, metal concentrations and ratios that they display are indicative of a very early-stage sulfide liquid in the system, as they will have cooled and fractionated within an essentially closed system, unlike interstitial blebs that crystallise in an open system as the magma cools. Analysis of these droplets in an opaque mineral like chromite by LA-ICP-MS is problematic as some of the fractionated inclusion is necessarily lost during cutting and polishing to initially ...
In this paper coating developments for advanced gas turbine engines (diffusion aluminide coatings, overlay coatings, and ceramic thermal barrier coatings) were desorbed, a selection of current metallic coatings was made and their performance as outlined. Finally coating developments for advanced diesel engines with a view to improved turbocharging or to low heat rejection engines (adiabatic diesel concept) were dealt with. (IHOE).
The fatigue properties of EP539LM alloy with an Al-Nb-Si fused slurry coating and a Co-Cr-Al-Y electron-beam coating are investigated experimentally in vacuum and in air at 900 C. It is found that the protective coatings reduce the fatigue life of the specimens both in vacuum and in air, with the electron-beam coating affecting the fatigue life of the alloy to a lesser degree than the fused slurry coating. The negative effect of the coatings on the fatigue life of the alloy is attributed largely to the properties of the coating material. 7 references.
In vitro cytocompatibility and cellular interactions of lauric acid and dextran-coated magnetite nanoparticles were evaluated with two different cell lines (mouse fibroblast and human cervical carcinoma). Lauric acid-coated magnetite nanoparticles were less cytocompatible than dextran-coated magnetite nanoparticles and cellular uptake of lauric acid-coated magnetic nanoparticles was more than that of dextran-coated magnetite nanoparticles. Lesser cytocompatibility and higher uptake of lauric acid-coated magnetite nanoparticles as compared to dextran-coated magnetic nanoparticles may be due to different cellular interactions by coating material. Thus, coating plays an important role in modulation of biocompatibility and cellular interaction of magnetic nanoparticles.
In vitro cytocompatibility and cellular interactions of lauric acid and dextran-coated magnetite nanoparticles were evaluated with two different cell lines (mouse fibroblast and human cervical carcinoma). Lauric acid-coated magnetite nanoparticles were less cytocompatible than dextran-coated magnetite nanoparticles and cellular uptake of lauric acid-coated magnetic nanoparticles was more than that of dextran-coated magnetite nanoparticles. Lesser cytocompatibility and higher uptake of lauric acid-coated magnetite nanoparticles as compared to dextran-coated magnetic nanoparticles may be due to different cellular interactions by coating material. Thus, coating plays an important role in modulation of biocompatibility and cellular interaction of magnetic nanoparticles.
A chromium-free conversion coating for magnesium alloys were described. The conversion coating could be obtained when AZ31D magnesium alloy was immersed in a solution containing a manganese salt, phosphate and an inhibitor. Corrosion resistance of the chemical conversion coating was evaluated by anodizing polarization curve and salt immersion. XRD analysis showed that the conversion coating was mainly composed of Mn{sub 3}(PO{sub 4}){sub 2}. The morphology of the coating is observed by using SEM. The effect of electrolyte pH and concentration of inhibitor on coating growth are investigated. (orig.)
MCrAlY coatings are widely used on hot section components of gas turbines to provide hot corrosion and/or oxidation protection by formation of an oxide layer on the surface. As the protective oxide scale exfoliates during service, aluminum from the coating diffuses outward for reformation of the protective scale. Aluminum may also diffuse inward due to the differences in composition between the coating and the substrate. Thus, the coatings degrade due to oxidation, oxide scale spallation, and inward and outward diffusion of aluminum. Service life of these coatings is controlled by the aluminum content in the coating, operating temperature and start- shutdown cycles. In-service degradation of CoCrAlY and CoNiCrAlY coatings is presented. A procedure to predict the remaining service life of coatings under oxidizing ...
Technology of plasma sputtering, structure and properties of zirconium dioxide coatings were studied. Necessity of void number increase to enhance coating heat-resistance is shown. Optimal powder particle size (20-60 #mu#m) providing optimal coating porosity was determined. Weight part of stabilizating oxide (Y_2O_3) in ZrO_2 for formation in coating of microcracks serving as barriers for macro-cracks propagation was determined.
Jun 8, 2006 ... It also reflects the large amount of deforestation that has occurred on the Haitian side of the border. One can easily see from satellite imagery ...
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Mar 30, 2007 ... Tropical forests are home to half the Earth's species, and their trees are an immense standing reservoir of carbon. Deforestation will have ...
Jul 26, 2011 ... The Gateway to Astronaut Photography of Earth hosts the best and most complete online collection of astronaut photographs of the Earth.
... of this material is, however, outside the currently approved earth fill materials collection area ... fill material suitable for its intended use. The currently approved site contains material that is ...
PVD-chromium-nitride coated samples of substrates of the magnesium alloy AZ91hp and the roller and ball bearing steel 100Cr6 were investigated regarding structure, mechanical characteristics, adhesion and internal stresses. For the coatings the parameters layer thickness and substrate BIAS voltage were varied. Both substrate materials were coated in one lad. Results of the X-ray analysis of the internal stresses show significant differences between the coated magnesium and the coated steel substrates. In the case of the variation of the substrate BIAS voltage, for the coated steel a dependency of the internal stresses to coating parameters could be obtained. For the coated magnesium no dependency was recognizable. The coating structure was examined with scanning electron microscopy. Element depth ...
An investigation was conducted to determine the cause of coating residue found in the test gun chambers during qualification firing of 120-mm combustible cartridge case (CCC) ammunition for the MlAl/A2 main battle tank. The CCC is coated with a clear epox...
A review of chemical decontamination methods for coatings indicates the following: the ease of both contamination and decontamination is a function of the radionuclide and the pH of the environment; the coating type is important in determining whether the contamination is loosely adsorbed, complexed, or contained in porous filler material; the condition of the coating is important to the decontamination factor obtained. Thus coatings can be decontaminated provided the solvent is sufficiently acid to solubilize the radionuclide and the complexant strength of the solvent is greater than that of the coating. Difficulties arise if the contamination is associated with fillers. Furthermore, though nothing has been said about temperature, decontamination of metal goes faster and, usually, with better efficiency at high temperatures. 11 references, 3 figures.
The purpose of this study is to investigate the influence of tungsten carbide/carbon (WC/C) coating on the surface durability of casehardened steel gear. Two kinds of WC/C coatings were deposited on the ground gear pair made of chromium molybdenum steel with carburizing and quenching. One is the conventional WC/C coating, and the other is WC/C coating with about 1 ?m CrN interlayer. Here, the WC/C-coated test pinion and the WC/C-coated one with CrN interlayer are represented by WT and ST, respectively. Non-coated test pinion is represented by NT. The surface roughness along the tooth profile direction of WT and ST was almost the same as that of NT. A spur gear test was carried out with an IAE power circulating type gear test rig under EP gear oil lubricating condition. The fatal failure mo...
... Mirrors (Preprint) Ryan Conk et al. 15 September 2006 ... 4. TITLE AND SUBTITLE Stress Coatings for Large Scale Membrane Mirrors (Preprint) 5a. ...
A waterjet coating-removal system was developed at NASA's Marshall Space Flight Center in Huntsville, Ala., to remove thermal protective coatings from the ...
Ceramic coatings with high emission were fabricated on Ti6Al4V alloy by microarc oxidation (MAO) with additive FeSO4 into the electrolyte. The microstructure, chemical composition and chemical state of the coatings were determined by SEM, XRD, EDS and XPS, respectively. The bonding strength between the coating and substrate was studied by tensile strength test, together with the thermal shock resistance of the coating. The results showed that Fe content in the coating layer significantly affect its thermal emissivity. The relative content of Fe in the coatings surface increased at first and then decreased with increasing the concentration of FeSO4 in electrolytes, so does the emissivity of the coatings. The bonding strength became weaker with increasing the concentration of FeSO4. In addit...
Hexavalent chromium in corrosion preventive coating 64 ...To prevent corrosion of rims, weights can be provided with a coating. ...integrated clips brought up technical problems due to corrosion
Hard Nano-Strutural Coatings Resistant to the Extreme Conditions of Chemical, Abrasive and High Energy Media for Thermonuclear Power, Oil and Gas and Chemical Industries
Results showed that a simple yttrium coating offered more potential for ... was from 70 to 150 K (125' to 200' F) above that for the yttrium coating. ...
The electrogeometric model cannot consider the influence of some parameters on the screening of the wire conductor of the H.V. lines. For analysing the influence of these parameters (the conductor potential, the influence of the distance from phase conductor to earth wire, the influence of the reducing factor of the striking earth distance, the earth slope, etc.), the Monte Carlo method is preferable. The influence of the earth slope on the screening effect of the wire conductor for different conditions is presented in this paper. (author)
The SIEN 2009 symposium organized by Romanian Nuclear Energy Association, AREN, in co-operation with Romanian Atomic Forum, ROMATOM, was primarily targeting the expert community involved in developing new nuclear power projects and implementing the National Nuclear Program. The symposium was also open as a discussion and information forum for scientists, engineers, technicians and students interested in scientific and technologic topics of Nuclear Power. It was structured in the following 6 sections: - Nuclear new builds and developments; - Operation, inspection and maintenance; - Increasing nuclear safety features; - Fuel cycle and decommissioning; - Public perception and confidence strengthening; - Environmental management. The symposium began with three plenary lectures dealing with: - Sustainable Nuclear Energy European Technology Platform; - Nuclear new-build; - Current issues of nuclear equipment standardization in Romania. A poster session of 5 presentations and a workshop ...
This paper describes a feasibility demonstration of a thermal scanning NDE system for thermal spray coatings. Non-bonds were detected between several types of coatings and their substrates. Aluminum anti-skid coatings having very rough surfaces were included. A technique for producing known non-bond areas for calibrating and demonstrating NDE methods was developed.
The bibliography contains citations concerning the structural properties of sputtered tantalum and tantalum compounds. The preparation of thin film capacitors and resistors is described. The electrical properties of the sputtered films are also included. The influence of the substrate on the properties of the coatings is considered, including adherence of the coating to the substrate, and the effects of impurities on coating integrity. (Contains 250 citations and includes a subject term index and title list.)
Non-destructive methods for measuring the remaining anticorrosive or antioxidative ability of coatings are investigated. For anticorrosive chromium coatings the increasing ferromagnetism caused by loss of chromium is measured by a permeability probe. Measured values on blades after operation are correlated with the progress of corrosion as determined by metallographic methods. For antioxidative aluminum coatings the diminishing layer thickness is taken as indication for the exhaustion of their protection ability. The layer thickness is measured eddy current probes, especially developed for this application.
The structure and properties of composite powder coatings on the base of titanium carbide are studied. It is shown the electron-beam welding deposition of powders on the base of nickel and titanium carbide allows to produce of high-quality wear-resistant coatings which superior in density and hardness compared with sputtered ones. Changes of hardening phase volume percentage as well as composition of metal matrix make possible to control coatings hardness
Simulated atmospheric corrosion studies were performed to determine the corrosion protection provided by galvanized zinc coatings on depleted uranium, U-0.75 Ti alloy, and U-6 Nb alloys. The accelerated ASTM tests consisted of exposing the galvanized samples to aqueous and aqueous chloride environments. The test results showed that anodic protection was provided by the electronegative zinc coatings on uranium and uranium alloys. Treating zinc with chromate conversion coatings also provided more protection.
Aluminum hydroxide coating thicknesses were measured on fuel elements stored in aluminum canisters in K West Basin using specially developed eddy current probes . The results were used to estimate coating inventories for MCO fuel,loading. Brushing tests successfully demonstrated the ability to remove the coating if deemed necessary prior to MCO loading.
The effect of heat treatment on the corrosion behavior of reactive plasma sprayed TiN coatings in simulated seawater was investigated by electrochemical methods such as the corrosion potential-time curve (Ecorr-t), potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and SEM, etc. The results showed that the corrosion potential of TiN coatings increased after heat treatment; the corrosion current of the TiN coatings after heat treatment (be hereafter referred to as HT-TiN) was 13.3% of the untreated coatings (be hereafter referred to as UT-TiN), and the polarization resistance of HT-TiN was 20 times of UT-TiN, which indicated that the heat treatment had significantly increased the corrosion resistance of the coatings. The corrosion behavior of the coatings was mainly ...
The Ti and Ti-Al coatings were deposited onto hot-worked AISI H11 steel substrates and plasma nitrided at 900 C. The Ti coated samples were successfully nitrided, while cracking and delamination of the Ti-Al coating was observed during nitriding. The formation of [delta]-TiN and [epsilon]-Ti[sub 2]N phases were detected after plasma nitriding of the Ti coating. During plasma treatment of the Ti-Al coating, the initial Ti[sub 3]Al and Al phases were paartially transformed into TiAl phase. The martensite transformation of the substrate material was found. The as-deposited Ti coating has a fibrous structure, while the structure of the as-sputtered Ti-Al coating is columnar. The superficial Vickers microhardness of plasma-nitrided Ti coating was 2200 HV 0.03 and the critical load of higher than 50 N indicates very good ...
There is an increasing number of applications for hard coatings in engineering where the properties of the single-layer coating are not sufficient. One way to solve this problem is to use a multilayer coating that combines the properties of several coating materials. In this study, TiN-CrAlN and CrN-CrAlN multilayer coatings were deposited on 100Cr6 and S6-5-2 (DIN) steel substrates, by means of unbalanced magnetron sputtering. For comparison, TiN, CrN and CrAlN single-layer coatings were also prepared. For all depositions the coating temperature was below 473 K. Indentation testing, hardness measurements and scratch tests were performed to characterize the mechanical properties. The correlation between the wear behavior in rolling contact and the mechanical properties of the multilayer coatings is reported. A ball ...
From a macroscopic point of view, corrosion of Zn alloy coated steel sheet occurs by the coating preceding corrosion mechanism; microscopically, however, the coated layer corrosion velocity in the tip of corrosion is different. In order to find the main factors of under-film corrosion of Zn and Zn-Fe alloy coatings in the salt water spray atmospheric exposure test, the correlation between point inflation-exfoliation width and chlorine penetration behavior, point adhesion, and the difference in chlorine penetration behavior due to alloy coating components were investigated. Consequently, the following results were obtained: 1. The better correlation was observed between chlorine penetration distance and point inflation-point exfoliation width. 2. The durability of coating against chlorine penetration improved by increase in point adhesion and Zn content in the ...
The effect of a substrate on the results of measuring tantalum coating thickness in two-layer compositions according to gamma radiation scattered by the substrate is studied. It is shown that by means of an albedo-radiometer realizing the physical model absorber-scatterer one can determine the thickness (application uniformity) of tantalum coatings up to 150-300 #mu#m depending on the substrate material (plexiglas, aluminium, iron, copper). In case of testing coatings on substrates of alloys and high-alloy steels in order to ensure high accuracy of measrurement it is expedient with the above albedo-radiometer to determine the value of the backscattered radiation flux for the substrate before coating application.
For the protection of buried steel pipeline, it is common practice to coat the pipelines with highly insulating coating and apply a cathodic current to insulate the pipe from the aggressive environment. Cathodic current protects holidays or damaged area of coating which required less current than would be needed for an uncoated pipe, but because of the cathodic reactions evolution will be taken H{sub 2} and OH{sup -} on holidays which exposed metal to the environment place. This effect is to cause loss bond of coating around the holidays called cathodic dis-bonding. In this paper we measured cathodic dis-bonding of three types of coatings at - 1.5 V(Cu/CuSO{sub 4}) according to ASTM G8. We studied on cathodic dis-bonding resistance of petroleum-base, coal tar-base and polyethylene plastic tape coatings. After 30 days immersion in electrolyte it was found that ...
Hybrid organic-inorganic coatings with phosphonate functionalities have been synthesized and evaluated as prospective surface treatments for magnesium materials. These coatings have been processed via a sol-gel route by hydrolysis and condensation of a mixture of diethylphosphonatoethyltriethoxy-silane and tetraethoxy-silane with variable molar ratios. The coatings morphology and the surface chemistry at the coating/substrate interface have been characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, "3"1P nuclear magnetic resonance spectroscopy, and time-of-flight secondary ion mass spectrometry. The corrosion protection performance of the coatings deposited on magnesium alloy AZ31B has been examined by a group of electrochemical techniques including potentiodynamic polarization and electrochemical impedance spectroscopy. In addition, a scanning Kelvin ...
This paper describes the effects of SiC coating on the oxidation resistance of C/C composites in combusting fields, which are expected to be applied to high temperature structural materials at over 1770K. The coating methods employed were CVD and pack cementation. The time changes in weight loss of the specimens were measured at temperatures of 1770K and 1900K under the equivalence ratio of 0.9 generated by methane-air combustion, and the surface of the specimens before and after the experiment was observed by SEM. Although the weight loss of the specimens coated by the CVD method was minimal, the coating layer was easily peeled off from the substrate. On the other hand, the layer of the specimens coated by the pack cementation method was stable and adhered to the substrate, but the substrate was degraded because of penetration of oxygen through the pores in the layer. To cover the ...
In the framework of the European Fusion Technology Programme ECN participates in a NET task PSM-8 `Coatings and Surface Effects on Stainless Steel 316L`. High emissivity coatings were developed for enhanced heat transfer from graphite tiles to a Stainless Steel First Wall. Four candidate materials, Cr{sub 2}O{sub 3}, Black Cr, Al{sub 2}O{sub 3}/TiO{sub 2} and TiC were tested as candidate high emissivity coatings. These coatings were manufactured by atmospheric and vacuum plasma spraying technique and the Black Chromium coatings were manufactured by a galvanic coating technique. The tests included total emissivity measurements and Low Cycle Fatigue (LCF) experiments. The total emissivity of two TiC coatings at 525 K appeared to be 0.62 and 0.64. The total emissivity of the TiC and 5 wt% TiO{sub 2}/Al{sub 2}O{sub 3} ...
of satellite, aircraft and ground-based observations. In ..... swarm traps by Utah Department of Food and Agriculture (DAF) personnel. Preliminary Results ..... the 150th anniversary of the book's publication and the 200th anniversary of Darwin's birth. ...... cold war submarine missions to find that Arctic Ocean ...
Al Fleig, PITA Analytic Sciences. 7th Earth Science Data Systems Working Group Meeting ..... The Reuse Industry in Brazil, CESAR, and the Reuse in Software ...
Rare Earth Cobalt (REC) permanent magnets have unique properties that permit solutions to some optical tasks that cannot be accomplished with conventional magnets. A review of design and of performance characteristics of these magnets includes an analytical description of the three dimensional fringe fields of REC quadrupoles.
The estimation of numerical values of the mean distance of closest approach of ions, a, of alkaline-earth metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.
This frequently-asked-questions feature provides answers about earthquakes, faults, plate tectonics, and earth structure. Maps and diagrams are provided with some answers, and links to additional information and to related topics are included.
The Grover S and X-band dual-wavelength radar system has been ...... A. H. Watkins (U.S. Geological Survey, Earth Resources. Observation Systems Data Center ...
We calculate the expected fluxes of cosmic ray nuclei with charge 5 ≤ Z ≤ 28 at various depths in the earth's atmosphere, taking into account the initial charge distribution,...Full Text Available
In this paper, the influence of plasma nitriding at temperature 720 deg. C for 20 h on the surface microstructure and interface microstructure of electroplated chromium coating was investigated. In these conditions, interdiffusion, mixing and reaction phenomena of elements originating from the substrate and coating material are more likely to occur, thus increasing the bonding strength between the coating and carbon steel substrate. The change of the structures from the substrate side to the coating surface, and the effect of the substrate steel on the interface structure were studied by cross-sectional transmission electron microscope observation (XTEM). The nitride layer formed on the surface was analyzed by X-ray diffraction method (XRD). After treatment at above conditions a 6-7 {mu}m thick nitride compound layer was formed in surface region and the same thick carbide compound layer was also formed ...
In this paper, the influence of plasma nitriding at temperature 720 deg. C for 20 h on the surface microstructure and interface microstructure of electroplated chromium coating was investigated. In these conditions, interdiffusion, mixing and reaction phenomena of elements originating from the substrate and coating material are more likely to occur, thus increasing the bonding strength between the coating and carbon steel substrate. The change of the structures from the substrate side to the coating surface, and the effect of the substrate steel on the interface structure were studied by cross-sectional transmission electron microscope observation (XTEM). The nitride layer formed on the surface was analyzed by X-ray diffraction method (XRD). After treatment at above conditions a 6-7 #mu#m thick nitride compound layer was formed in surface region and the same thick carbide compound layer was also formed ...
Phosphate/chromate and accelerated chromate coatings were produced on commercially available aluminium. The Cr, P and Fe components of the conversion coatings were determined by radioactive tracer technique. The tracer technique was combined with ion-exchange and film-sectioning methods to determine the chromium(III)/total chromium ratio in the accelerated chromate coating. It was found that during the acidic dissolution of the conversion coating the chromium(III)/total chromium ratio may suffer changes. The film-forming components in the metal/bath interface are supersaturated and deposited onto the aluminium. The identified components of the accelerated chromate coatings are Cr(OH)sub(3), Cr(OH)CrOsub(4) and Crsub(4)(Fe(CN)sub(6))sub(3) and the chromium(III)/total chromium ratio was found to be cca. 2/3. (author). 11 refs.; 5 figs.
In situ composite coating of hydroxyapatite (HA)/TiO2 were produced on titanium (Ti) substrate by micro-arc oxidation coupled with electrophoretic deposition (MAO&EPD) technique with different concentrations of HA particles in the 0.2M NaOH electrolyte solution. The surface morphology and chemical composition of the hybrid coating were effected by HA concentration. The amount of HA particles incorporated into coating layer increased with increasing HA concentration used in the electrolyte solution. The corrosion behavior of the coating layer in simulated body fluids (SBF) was evaluated using a potentiodynamic polarization test. The corrosion resistance of the coated sample was increased compared to the untreated Ti sample. The in vitro bioactivity assessment showed that the MAO&EPD treated...
The electroless nickel plating/poly(dl-lactide-co-glycolide) composite coating (EN-plating/PLGA composite coating) was fabricated on the surface of the micro-arc oxidation (MAO) film of the magnesium alloy AZ81 to double control the corrosion and drug release in the hanks' solution. The EN-plating was fabricated on the MAO coating to improve the corrosion resistance by overlaying most pores and micro-cracks on the surface of the MAO film. Meanwhile, a double layered organic poly(dl-lactide-co-glycolide)/paclitaxel (PLGA/PTX) drug releasing coating with a top layered PLGA drug controlled releasing coating on EN plating was prepared to control the drug release rate by adjusting the different lactide: glycolide (LA:GA) ratio of PLGA. Scanning electron microscopy (SEM) and the X-ray powder dif...
Assembly of icosahedral capsids of proper size and symmetry is not understood. Residue F170 in bacteriophage P22 coat protein is critical for conformational switching during assembly. Substitutions at this site cause assembly of tubes of hexamerically arranged coat protein. Intragenic suppressors of the ts phenotype of F170A and F170K coat protein mutants were isolated. Suppressors were repeatedly found in the coat protein telokin-like domain at position 285, which caused coat protein to assemble into petite procapsids and capsids. Petite capsid assembly strongly correlated to the side chain volume of the substituted amino acid. We hypothesize that larger side chains at position 285 torque the telokin-like domain, changing flexibility of the subunit and intercapsomer contacts. Thus, a sing...
The prospect for the recovery of rare earths from red mud, the bauxite tailings from the production of alumina is examined. The Jamaican red mud by far has the higher trace concentrations of lanthanum, cerium, neodymium, and yttrium. Scandium is also present. The dissolution of the rare earth is a major extraction problem because of the large volume of other materials. The recovery processes that have been proposed include the production of co-products such as iron, alumina, and titanium concentrates, with the rare earths going with the titanium. In this paper a critical examination of the possible processes are presented with the recommended research projects to be carried out.
NASA's Glory spacecraft is equipped to survey and map aerosols in Earth's atmosphere during a mission marking the return to flight of the Taurus XL rocket.
This paper presents an analysis of the performance of a selective emitter using small particles of rare earth compounds stable at high temperatures in a low emittance inert gas stream. An expression for the spectral emissive power excluding radiation scattering was derived to include the radiation in the emission band, produced by electronic transitions of the rare earth ion, and the continuum radiation outside the emission band produced by the rare earth host. Preliminary results suggest that a selective emitter based on suspended rare earth oxide particles will have high efficiency and merits further experimental investigation. {copyright} {ital 1996 American Institute of Physics.}
The rare earth antimonates RE_3Sb_5O_1_2 constitute an isostructural series, where the rare earth site symmetry is S_4. The spectroscopic properties of pure or doped compounds of this family are studied in order to derive their energy level schemes and to simulate them through the crystal field theory, by using the approximated D_2_d potential. The paramagnetic susceptibilities are calculated with the derived wavefunctions and compared to experiment.
In this thesis the results are described of an investigation into the radiationless transfer of electronic excitation energies in various Eu"3"+ and Tb"3"+ compounds, which show structural peculiarities in the rare-earth sublattice. These peculiarities are an one-dimensional sublattice as well as two different crystallographic locations for the rare-earth ion. 154 refs.; 43 figs.; 12 tabs.
We calculated the matter effect, including both the Earth and supernova, on the detection of neutrinos from type II supernovae at the proposed Daya Bay reactor neutrino experiment. It is found that apart from the dependence on the flip probability P_H inside the supernova and the mass hierarchy of neutrinos, the amount of the Earth matter effect depends on the direction of the incoming supernova neutrinos, and reaches the biggest value when the incident angle of neutrinos is around 93^\\circ. In the reaction channel \\bar{\
Several metallurgical coatings have been developed that provide good tribological performances in high-temperature liquid sodium and that are relatively unaffected by neutron fluences to 6 X 10/sup 22/ n/cm/sup 2/ (E > 0.1 MeV). The coatings that have consistently provided the best tribological performance have been the nickel aluminide diffusion coatings created by the pack cementation process, chromium carbide or Tribaloy 700 trade mark (a nickel-base hardfacing alloy) applied by the detonation-gun process, and chromium carbide and other hardfacing alloy) applied by the detonation-gun process, and chromium carbide and other hardfacing materials applied by the electro-spark deposition process. The latter process is a relatively recent development for nuclear applications and is expected to find wide usage. Other coating processes, such as plasma-spray coating, sputtering, and ...
The purpose of this study was to synthesize biocompatible polyvinylpyrrolidone (PVP)-coated iron oxide (PVP-IO) nanoparticles and to evaluate their efficacy as a magnetic resonance imaging (MRI)...Full Text Available
Duplex-coating procedures consisting of plasma nitriding and Me-C:H hard coating lead to an improved performance of the devices because the Me-C:H coating is supported by the nitrided phase and, therefore, the `eggshell-effect` is avoided. Furthermore, this support leads to a higher load-bearing capacity of the thin film. Two standard procedures (classical high-pressure plasma nitriding and unbalanced magnetron sputtering of Ti-C:H) were performed subsequently to prepare the duplex coatings on X20Cr13 ferritic stainless steel. The corrosion resistance of the steel could be improved by nitriding at 450 C compared to the untreated ferritic substrate. The roughness is determined by the nitriding step. The weakest point of the coating is the transition zone between the nitrided and the untreated substrate and not the interface between the Ti-C:H coating and the ...
The objective of this work was to evaluate the physical properties and in vivo circulation of chitosan (CH)-coated liposomes of mitoxantrone (MTO). Changes in particle size and zeta...Full Text Available
The industrial radiation processing using low energy electron beam (EB) accelerators lower than 300 keV offers high speed, safe technologies for the chemical conversion of thin layer coatings. Because of the nonselective mode of initiating chain reaction polymerization involving free radicals in synthetic coating layers and suitable substrates, the EB curing of the coatings on woods and papers has particular advantage. Hungary decided to start an up-to-date EB line to process cement-bound (CB) wood chipboards with pigmented acrylic coatings. The CB wood chipboards contain more than 60 % of portland cement and up to 40 % of wood particles. They are produced as large boads of 6 - 16 mm thickness. In their fireproof character and other aspects, they are similar to asbestos-cement boards without containing carcinagenic asbestos, and are stable against moisture and atmospheric influences. EB-cured acrylate ...
A serological trapping technique for detecting rotaviruses is described which involves coating electron microscope grids with protein A and specific rotavirus antiserum. The presence of a layer of antibodies...Full Text Available
Computer-assisted analysis revealed a striking sequence similarity between the putative 24-kDa protein (p24) encoded by open reading frame (ORF) 5 of beet yellows closterovirus and the coat protein...Full Text Available
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two sha...
The extraction of rare earth elements, yttrium and aluminium from red mud resulting from alumina production with the ion-exchange resin KU-2-8n was studied. Experimental results are presented. The technology of hydrometallurgical processing of pulps obtained by sorption extraction of scandium from red mud is developed. It is shown that in the process of precipitation from sulfate sulfuric acid desorbate it became possible to obtain a high degree of rare earths deposition. The use of sodium hydroxide makes it possible to obtain a maximum deposition of rare earths and aluminium - 99.9 %. Aluminium leaching from crude composite concentrate gives a possibility to get concentrates which 15 - 20 times richer in yttrium and rare earths
The possible physical linkage between galactic cosmic rays intensity and the Earth's cloud cover is discussed using the analysis of the first indirect aerosol effect (Twomey effect) and its experimental representation as the dependence of average cloud droplet effective radius on aerosol index characterizing the aerosol concentration in the atmospheric air column of unit section. It is shown that the basic kinetic equation of the Earth's climate energy-balance model is described by the bifurcation equation (with respect to the temperature of the Earth's surface) in the form of fold catastrophe with two governing parameters defining the variations of insolation and Earth's magnetic field (or galactic cosmic rays intensity in the atmosphere), respectively. The principle of hierarchical climatic models construction, which consists in the structural invariance of balance equations of these models evolving ...
The metal-semiconductor solar cell is a potential candidate for converting solar energy to electrical energy for space and terrestrial application. In this paper, a method for obtaining parameters of practical antireflection (AR) coatings for the metal-semiconductor solar cells is given. This method utilizes the measured equivalent index of refraction obtained from ellipsometry, since the surface to be AR coated has a multilayer structure. Both the experimental results and theoretical calculations of optical parameters for Ta/sub 2/O/sub 5/ AR coatings on Au-GaAs and Au-GaAs/sub 0.78/P/sub 0.22/ solar cells are presented for comparison. (AIP)
A report is given on an improved filler-binder mixing method in the manufacture of artificial graphite, the so-called coat-mix process. The individual graphite-filler grains are coated completely with uniform binder coatings (phenol formaldehyde resin) in a continuous process. Methanol is used as solvent for the resin. In a modified further development of the process, the use of organic solvents can be disregarded by dissolving the binder resin in caustic soda and injecting the slurry into water diluted acid. The manufacture of casting molds from coat-mix powders, their properties and industrial application are given. Finally, the advantages of using carbon bodies of coal-mix material for conversion to silicon carbide are indicated. (IHOE).
New data about the structure of high-temperature resistant metalloceramic plasma sprayed coatings in micro and nano areas are presented. Application of the new instrumental methods: transmission electron microscopy combined with selected area electron diffraction mode is possible to obtain these data. The first layer in Ni based metallic bond coat shows nanocrystalline structure. External ceramic layer based on stabilised ZrO_2 is polycrystalline and contains both cubic and tetragonal crystalline phases. Local inhomogeneities in coatings phase composition are determined. (author)
The refractory nature and high ductility of body centered cubic (bcc) phase tantalum makes it a suitable material for corrosion- and wear-resistant coatings on surfaces that are subjected to high stresses and harsh chemical and erosive environments. Sputter deposition can produce thick tantalum films but is prone to forming the brittle tetragonal beta phase of this material. Efforts aimed at forming thick bcc phase tantalum coatings in both flat plate and cylindrical geometries by high-rate triode sputtering methods are discussed. In addition to substrate temperature, the bcc-to-beta phase ratio in sputtered tantalum coatings is shown to be sensitive to other substrate surface effects.
There is increasing demand to functionalize meso- and nano-porous materials by coating and make the porous substrate biocompatible or environment friendly. However, coating on a meso-porous substrate poses great challenges, especially if the pore aspect ratio is high. In the current work the pulsed laser deposition (PLD) method is used for coating Ni{sub 3}Al-based meso-porous membranes with diamond-like carbon (DLC) layers of high thickness homogeneity and adhesion. (orig.)
The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.
With the deposition of PVD hard coatings on the tools applied in machining operations it is possible to achieve significant improvements in the performance and quality of the machining processes. Depending on the machined material and the operating principle, e.g. turning, milling or drilling, not only different machining parameters but also different coating materials are necessary. In interrupted cut machining of tempered steel, for example, the life time of Ti-C-N coated inserts is several times greater than the Ti-C-N coated ones. This is a result of the favourable thermophysical and tribological properties of Ti-N-C. The potential for tool protection by CrN coatings is a result of the high ductility and low internal stress of this coating materials. CrN films can be deposited with greater film thickness, still maintaining very good adhesion. This paper ...
One requirement of a thermophotovoltaic (TPV) radiator is to efficiently emit photons at high temperatures to TPV cells for conversion to electric power. Because many candidate radiator materials with adequate structural properties display low emissivity, coatings or other surface modifications are required for enhancement of emissivity. Six plasma sprayed coatings and one textured surface demonstrated adequate thermal stability and emittance values of 0.8 or greater. Promising attributes of modified surfaces are identified.
The cathodic vacuum arc provides a means of producing large currents of positive ions of a wide variety of materials. These ions can be utilized to produce coatings with improved properties such as higher density and adhesion. The processing is particularly useful in reactive deposition of ceramic coatings having excellent stoichiometry. In this review, emerging aspects of the technology are emphasized.
The method of production of xAl{sub 2}O{sub 3}-yTiO{sub 2} compositions provides for the depth distribution of coating components and specifies its mechanical properties. In case of the composition obtained by cladding, titanium is mainly concentrated at the substrate. In case of mechanical mixture or composition obtained by sintering the oxides, the depth distribution of coating components is random.
An improved coating for Advanced Gas Cooled Nuclear Reactor austenitic stainless steel fuel cans is described which, tests have shown, inhibits the deposition of carbon on the cans in carbon-containing ionising radiation environments. The coating comprises a refractory oxide which has been prepared by a vapour phase condensation method, in combination with a noble metal. (U.K.).
The method of the present invention comprises a step of previously coating a positive type resist on the surface of equipment, a step of solidifying the coated positive type resist and a step of bringing the coated equipment to circumstances for use and cleaning the positive type resist. With such procedures, the amount of radioactive materials deposited on the equipment can be reduced, and redeposition of nuclides on the surface to be cleaned can be prevented. (T.M.)
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO{sub 2}, PrO{sub 2}), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of ...
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare ...
Radioactive rare earth chlorides in waste LiCl-KCl molten salts have to be separated as a stable form to minimize waste volume and to achieve stable solidification. In this work, thermal behavior of rare earth chlorides (CeCl3, GdCl3, NdCl3, PrCl3) was investigated in an oxygen condition to recover rare earth oxides from a LiCl-KCl-RECl3 system. The rare earth chlorides in the LiCl-KCl molten salts were smoothly converted to an oxychloride form at a higher temperature than 650degreeC, except for CeCl3. CeCl3 was totally converted to an oxide from at a higher temperature than 450degreeC. The rare earth oxychlorides (GdOCl, NdOCl, PrOCl) were effectively converted to oxide forms at a higher temperature than 1100degreeC. It was confirmed that rare earth oxides can be recovered from a LiCl-KCl...
Uranium dendrites which were deposited at a solid cathode of an electrorefiner contained a certain amount of salts. These salts should be removed for the recovery of pure metal using a cathode processor. In the uranium deposits from the electrorefining process, there are actinide chlorides and rare earth chlorides in addition to uranium chloride in the LiCl-KCl eutectic salt. The evaporation behaviors of the actinides and rare earth chlorides in the salts should be investigated for the removal of salts in the deposits. Experiments on the salt evaporation of rare earth chlorides in a LiCl-KCl eutectic salt were carried out. Though the vapor pressures of the rare earth chlorides were lower than those of the LiCl and KCl, the rare earth chlorides were co-evaporized with the LiCl-KCl eutectic salt. The Hertz-Langmuir relation was applied for this evaporation, and also the evaporation ...
Most of the presently identified exoplanets have masses similar to that of Jupiter and therefore are assumed to be gaseous objects. With the ever-increasing interest in discovering lower-mass planets, several of the so-called super-Earths (i.e., with masses in the interval 1 M_earth < M < 10 M_earth), which are predicted to be rocky, have already been found. Here we report the possible discovery of a planet around the M-type star GJ 436 with a minimum mass of 4.8+/-0.6 M_earth and a true mass of ~5 M_earth, which makes it the least massive planet around a main-sequence star found to date. In contrast with other discoveries, the planet is identified from its perturbations on an inner Neptune-mass transiting planet (GJ 436b), by pumping eccentricity and producing secular variations in the orbital inclination. Analysis of published radial velocity measurements indeed reveals a ...
Tungsten (W) coating on fusion candidate V-4Cr-4Ti (NIFS-HEAT-2) substrate was demonstrated with plasma spray process for the purpose of applying to protection of the plasma facing surface of a fusion blanket. Increase in plasma input power and temperature of the substrate was effective to reduce porosity of the coating, but resulted in hardening of the substrate and degradation of impact property at 77 K. The hardening seemed to be due to contamination with gaseous impurities and deformation by thermal stress during the coating process. Since all the samples showed good ductility at room temperature, further heating seems to be acceptable for the vanadium substrate. The fracture stress of the W coating was estimated from bending tests as at least 313 MPa, which well exceeds the design stress for the vanadium structure in fusion blanket. (author)
Research highlights: ? Reports a high protection system for the alloy in corrosive environment. ? Describes an interfacial process with self-healing properties. ? Reports the influence of substrate pre-treatment in the coating performance. - Abstract: In this paper the interface of poly(vinylidene fluoride) coatings prepared by the dip coating method and HF-treated AZ31 magnesium alloy was evaluated. The best performance of this system in corrosion tests compared to ground, as-received and acetic acid cleaned substrates is related to an acid-base interaction at the interface and to interfacial reactions which resulted in a self-healing process. The protectiveness of the samples was investigated using impedance and immersion tests while the coating morphology and interface stability were investigated by scanning electron microscopy, X-ray photoelectron spectroscopy and adhesion tests.
This study investigated the effect of board type (unmodified vs. MAPE modified) on the surface quality and thickness swelling-water absorption properties of recycled high density polyethylene (HDPE) based wood plastic composites. Additionally, two commercially available coatings (cellulosic coating and polyurethane lacquer coating) were also applied to composite surfaces and their adhesion strength, abrasion and scratch resistance, and gloss values were determined. This study showed that modification of the composites with MAPE coupling agent increased the surface smoothness and reduced the water absorption and thickness swelling of the panels. Abrasion resistance of the composites was also improved through MAPE modification. Regardless of board type, higher scratch resistance and gloss values were observed for polyurethane lacquer coated samples compared to those of cellulosic varnish ...
The effect of the coated composite surface of particles on the mechanical properties of the powder bed was investigated. Polyethylene-silica surface composite powder was prepared at several coating ratios with Hybridizer. Various tests on mechanical properties of the powder bed were carried out with the prepared powder, and the following results were obtained: The ultimate tensile strength depends only on the cohesive force between particles, and the contact probability model of composite particles led to good agreement between the experimental and calculated values. The coefficient of internal friction and cohesive shear strength were influenced due to the interlocking effect of the surface roughness of composite particles. The effects of coating particles became small with dynamic properties like angle of repose. It is possible to control the mechanical properties in a step wise fashion by changing the ...
Experiment was conducted to study the effect of gamma irradiation, growth retardants and coatings (coconut oil, mustard oil and liquid paraffin) on shelf life of winter guava fruits during storage. The results revealed that the superiority of coconut oil coating over other post harvest treatments. Physiological loss in weight (7.1%), marketable fruits retained over control (86.7%), total soluble solid (16.1%), ascorbic acid (195 mg/100 g pulp) and total sugar (10%) of fruit were positively influenced by coconut oil coating up to 12 days of storage. The treatment was found significantly effective in increasing the post harvest life of fruits for 12 days over control without adversely affecting the fruit quality. Coconut oil coating gave highest consumer acceptability while, maintaining suff...
Analysis reproducibility and detection sensitivity of capillary electrophoresis (CE) are often questioned by applied scientists, which has hindered its application as a routine method. To address these issues, a simple, precise, and reproducible dynamic coating method was developed by applying carboxymethyl chitosan (CMC) dynamic coating on fused silica capillary. The proposed coating was accomplished by simply rinsing the capillary with CMC solution for 1?min in between runs, with no regeneration procedure or buffer additives needed. Electroosmotic flow could be well controlled by adjusting the pH of background electrolyte, and the adsorption of analytes onto the capillary inner wall was effectively eliminated. The main parameters of the coating condition were optimized, and extensive app...
The purpose of this study was to investigate whether hydroxyapatite (HAp) coating could induce polyethylene terephthalate (PET) artificial ligament graft osseointegration in the bone tunnel. Twenty-four New Zealand white rabbits underwent artificial ligament graft transplantation in bilateral proximal tibia tunnels. One limb was implanted with HAp-coated PET graft, and the contralateral limb was implanted with non-HAp-coated PET graft as control. The rabbits were randomly sacrificed at four and eight?weeks after surgery. The loads to failure of the experimental group at eight?weeks were significantly higher than those of the control group (p?=?0.0057). Histologically, application of HAp coating induced new bone formation between graft and bone at eight?weeks compared with the controls. Rea...
Ion storage CeO{sub 2} and CeO{sub 2}/SnO{sub 2} coatings were prepared by sol-gel dip-coating method using aqueous-based process. The influence of added SnO{sub 2} in the CeO{sub 2} oxide coatings on the inserted/extracted charge was determined by chronocoulometric measurements. It was found that for 60 nm thick film the inserted/extracted charge was twice larger (Q = 10mC/cm{sup 2}) for films containing 17 mol % SnO{sub 2} if compared to pure CeO{sub 2}. The addition of SnO{sub 2} to the mixed oxides coatings on their optical properties and structural characteristics were studied.
The carbon fibers (CF) were pre-treated in two different ways: no pre-treatment, and activation in HNO3 plus application of toluene-2,4-diisocyanate (TDI). Carbon fibers have been introduced into polyurethane (PU) composite coatings. The tribological behaviors of the polyurethane composite coating filled with CF or TDI-modified CF (TDI-CF) were studied using a ring-on-block wear tester under dry sliding, and the worn surfaces of the filled PU coatings and transfer films formed on the surface of the counterpart ring sliding against the PU coating were investigated by SEM and optical microscope (OM), respectively. Owing to the effective improvement of the interfacial adhesion between the CF and polyurethane matrix, compared with the cases of untreated CF, the employment of low content TDI-CF...
The determination of residual stress (RS) in case-hardened steel gear truck synchronisers coated with thermal sprayed molybdenum was carried out using neutron and synchrotron X-ray diffraction. Two samples with different coating thicknesses (about 120 ?m and 1.4 mm) and different steel substrates (16MnCr5 and SAE4140, respectively) were investigated. Microanalysis revealed substantial porosity in both samples and some debonding was observed between the thin coating and the substrate. The bulk hardness of the SAE 4140 proved to be much higher than the 16MnCr5 and the surface case-hardening increased it by a further 20%. The full three-dimensional stress depth-profile was determined by neutron diffraction (ND) in both the coatings and the substrates, while synchrotron radiation allowed a dep...
We have developed efficient spectrally selective infrared (IR) emitters that can be utilized for thermophotovoltaic (TPV) power generation by using stainless steel (SUS304) substrates coated with b- FeSi2 thin films. To develop spectrally selective emitters, we theoretically propose antireflection (AR) coatings consisting of a single layer of a dielectric material having a high refractive index (~5) and are appropriate for use with metals such as stainless steels in the IR region. This type of AR coating is fabricated by sputtering a b- FeSi2 thin film on a polished SUS304 substrate. The reflectance in the IR region is successfully reduced to less than 10%. In addition, the AR properties are stable even at 700 K in air. Therefore, metals with AR coatings of b- FeSi2 can be applied to IR em...
Abstract Introduction.- Infection is the worst complication seen with inflatable penile prosthesis (IPP). Both the American Medical Systems (AMS) and Coloplast IPP have infection retardant coatings. AMS is coated at the factory with rifampicin and minocycline (InhibiZone). The Coloplast IPP has a hydrophilic coating covalently bonded to its components that will absorb any aqueous solution before implantation and provides increased surface lubricity to decrease bacterial adherence. Aim.- We tested several antibiotic dips comparing zones of inhibition (ZOI) against five commonly infecting bacteria with coated Coloplast implants. Results were compared with those ZOI created with strips of an AMS IPP precoated with InhibiZone. Methods.- Pieces of sterile Coloplast Titan IPP were dipped in (i) ...
We analyse numerically the acoustic stop band properties of an array of orthotropic coated cylinders whose elastic parameters are deduced from a geometric transform [H. Chen, C.T. Chan, Acoustic cloaking in three dimensions using acoustic metamaterials, Appl. Phys. Lett. 91 (2007) 183518]. We find that whereas a single coated inclusion is acoustically neutral at any frequency, an array of them might display some stop bands. More precisely, an array of freely vibrating coated voids is always neutral, whereas an array of clamped coated inclusions might display a zero frequency stop band. Interestingly, an array of radially symmetric coated inclusions behaves as local Helmholtz resonators, for which the eigenfield within each cloak is obtained in closed form, leading to a frequency estimate a...
The combined processes of plasma nitriding and cathodic arc deposition of (Ti,Cr,Nb)CN coatings were applied to HSS substrates. The nitrided layers, obtained in a mixture of H2 (70%) and N2 (30%) at two different temperatures (480^oC and 510^oC), were examined for the microhardness depth profiles. Characterization of the duplex coatings was performed by investigating elemental and phase composition, texture, hardness, friction and wear. XRD and XPS analyses revealed the formation of a mixture of a carbonitride fcc solid solution, in a dominant proportion, and metallic chromium. The film hardness was measured to be ~34GPa. The duplex (Ti,Cr,Nb)CN coatings exhibited superior tribological behavior as compared to both nitrided layers and non-duplex coatings.
The physical, chemical and mechanical properties of magnesium alloys make them attractive materials for automotive and aerospace applications. However, these materials are susceptible to corrosion and wear. This work discusses the potential of using sol-gel based coatings consisting of ZrO_2 and 15 wt.% of CeO_2. The CeO_2 component provides enhanced corrosion protection, while ZrO_2 impart corrosion as well as wear resistance. Coating deposition was performed by the dip coating technique on two magnesium alloy substrates with different surface finishes: AZ91D (as-casted, sand-blasted, and machined) and AZ31 (rolled and machined). All as-deposited coatings (xerogel coatings) were then subjected to 10 h annealing: a temperature of 180 C was applied to the AZ91D alloy and 140 C to the AZ31 alloy. Morphological and structural properties of the annealed coatings ...
A Ni3Al coating was prepared by plasma spraying technique on the surface of titanium alloy. Ni-Al mixed powders, coatings and reaction products were investigated by scanning electron microscope, EDS, DSC and XRD. A tight bonding between the coating and the substrate was formed. The X-ray diffraction analysis of the patterns showed that the coating not only had Ni3Al phase, but also had NiO and Al2O3 phase microcontent. Comparing Ni coated Al to Ni3Al at 900^oC, the diffusion was stronger and the diffusion layer was thicker. A minute pore structure was formed at 1200^oC in the front edge of solid-state reaction layer. So Ni3Al restrained the solid-state reaction of the coating with the substrate, and as a whole weakened the entry of oxygen atoms into the substrate and quenched the out-diffu...
A focused ion beam (FIB) technique was applied to cross-sectional specimen preparation to observe an interface between a plasma sprayed coating and an aluminum (Al) substrate by transmission electron microscopy (TEM). The surface of the sprayed coating film has a roughness of several tens of microns. Sputter rates for the coating film and the substrate are greatly different. The rough surface and the difference in sputter rate cause problems in making TEM specimens with smooth side walls. The top surface of the coating film was planerized by the FIB before fabricating the TEM specimen. The interfaces were investigated by TEM and energy-dispersive X-ray (EDX) analysis. The TEM observation revealed that there is a 10 nm thick amorphous layer at the interface between the coating film and substrate. The coating film consists of two kinds of sublayers with bright and ...
When the foundations of the building are designed and worked, the prediction calculation of immediate settlement of the building exercised practically is to calculate assuming the earth is a linear elastic body, but the actual stress-strain relationship of the earth is nonlinear and rigidity of the earth becomes lower as strain (or stress) increases. Hence in order to grasp the actual settling behavior of the earth, it is necessary to elucidate the nonlinear relationship between stress and strain. In this article, a prediction method of building settlement is introduced which uses an analytical technique of the multi-layered earth by the linear elasticity theory and takes into consideration strain dependency of rigidity of the earth. Part of the conclusion is as follows which has been obtained by studying the settling behaviors observed in examples of vertical ...
The rare earth antimonates RE{sub 3}Sb{sub 5}O{sub 12} constitute an isostructural series, where the rare earth site symmetry is S{sub 4}. The spectroscopic properties of pure or doped compounds of this family are studied in order to derive their energy level schemes and to simulate them through the crystal field theory, by using the approximated D{sub 2d} potential. The paramagnetic susceptibilities are calculated with the derived wavefunctions and compared to experiment.
A method to achieve NMR of dilute samples in the earth's magnetic field by applying para-hydrogen induced polarization is presented. Maximum achievable polarization enhancements were calculated by numerically simulating the experiment and compared to the experimental results and to the thermal equilibrium in the earth's magnetic field. Simultaneous 19F and 1H NMR detection on a sub-milliliter sample of a fluorinated alkyne at millimolar concentration (1018 nuclear spins) was realized with just one single scan. A highly resolved spectrum with a signal/noise ratio higher than 50:1 was obtained without using an auxiliary magnet or any form of radio frequency shielding.
Abstract The creation of chirality on Earth and the development of chiral life have been discussed in this highlight. Convincing evidence for the introduction of chirality on Earth is still fragmentary. We believe that by a combination of chiral crystallization and formation of helical polymers with preferred chiral conformational structure is the key to this question. This concept of macromolecular asymmetry has inspired ideas and resulted in possible rules for how chiral life as we know it, could have been introduced. These investigations needed the understanding of the requirements for chiral crystallization, for the stereochemistry of the initial formation of helical polymers, the measurements of optical activity of solids and their coordination with the fundamentals of chirality. Spac...
There is presently considerable interest in wear resistant coatings produced using closed field unbalanced magnetron sputtering technology. For example, layered films of diamond-like carbon (DLC) with tungsten or titanium additions have been widely reported. The benefit is that the mechanical properties are enhanced (e.g. giving greater toughness); also it is possible to control the stress state and enhance adhesion. Here we report the further development of this concept by the addition of TiN, TiCN and TiC layers in DLC-based composites, utilizing an additional source of electrons in the vicinity of substrate to enhance ionisation of the plasma and increase coating density. Composite coatings of ceramics TiN, TiC{sub x}N{sub y}, TiC, CrN, TiCrN, TiCrCN, TiCrC, metal doped Ti{sub x%}-DLC and their combinations were deposited on 316 stainless steel substrates. The mass flow of reactive gases into the chamber was controlled ...
Copper coatings deposited on Al-6061 substrates by radio frequency magnetron sputtering, to prevent the retention and permeation of energetically implanted tritium in Al-6061, were evaluated by a variety of characterization techniques. The coatings, weighing in the 0.03 to 0.088 kg/m{sup 2} range, were smooth and had a fine grain structure. They contained the intermetallic phases Cu{sub 9}Al{sub 4} and CuAl{sub 2} as well as copper. The fractions of Al and Cu in any coating increased and decreased, respectively, with increasing depth below the surface. Furthermore, the fractions of Al and Cu on the coating surface decreased and increased, respectively, with increasing coating weight. There was no texture or preferred orientation in the Cu phase of the coatings. A significant amount of oxygen was also detected at the original substrate surface. Residual stress ...
Research highlights: The dental implant of titanium could be modified by anodic oxidation. It was found that incorporation of strontium ions into the matrix increase the bone formation. In this study, we try to investigate the effect of corrosion property and bioactivity on coatings containing strontium by anodic oxidation. The results suggest that coatings containing strontium on titanium by anodic oxidation has the potential to show the stability and bioactivity in the clinical use. - Abstract: Pure titanium (Ti) and titanium alloys are considered as bio-inert materials in clinical use. Bioactivity is the ability to induce bone-like apatite on the material surface. The micro-arc oxidation (MAO) technique is an effective method for improving the surface properties of titanium. The aim of this study was to investigate the bioactivity and corrosion behavior of MAO coatings containing strontium, which is beneficial for ...
The gravitational torque applied on the Earth by the other celestial bodies generates periodic variations in the orientation of the Earth's rotation axis in space which are called nutations. Observations of Earth's nutations allow for insights into the physical properties of the inner core because of the presence of a normal mode, the Free Inner Core Nutation (FICN), which is characterized by a tilt of the inner core figure and rotation axes with respect to the mantle and outer core. The frequency of the FICN is controlled by the strength of the mechanical coupling acting at the inner core boundary (ICB) and by the ability of the inner core to deform under the action of centrifugal and gravitational forces. Attenuation of the FICN reflects energy dissipated by electromagnetic (EM) and visc...
Nov 8, 2010 ... Ihring Mission 11, the radiation dosimetry measurement system functioned normally and provided data on the Earth's trapped radiation belts ...
Aug 25, 2004 ... The Tropical Rainfall Measuring Mission or TRMM satellite provided this image of Typhoon Aere over the western Philippine Sea as it was ...
An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements.
An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements
... Astronomy & Space Biology Chemistry & Materials Computing Earth & Environment Education ... Materials Research Center at the University of Chicago, one of nearly 30 NSF-supported Materials ...
Jan 5, 2004 ... Even if dinosaurs were cold-blooded, in the Mesozoic Era (when dinosaurs roamed the Earth), Antarctica was warm enough to have them. ...
... rivers of the world, the Zaire is not an efficient transportation link because of many rapids and falls to negotiate between Kinshasa and the port city of Matadi. ...
Apr 22, 2010 ... I believe that space exploration is not a ... plan for space exploration, especially in .... space exploration beyond low Earth orbit. ...
Federal regulators were set to vote on a plan to protect deep water corals and other sensitive fish habitats that will likely include a permanent ban on ...
The geographical arrangement of people on the surface of the earth is approximated by a mathematical equation of 361 terms. This is a convenient form for comparison with other distributions and for...Full Text Available
This study presents new software, called Google Earth-based Optimal HAulage RouTing System (GEOHARTS), to improve the functionality of Google Earth for optimal haulage routing of off-road dump trucks in construction and mining sites. A modified least-cost path algorithm, which is applicable to working areas with both paved and unpaved temporary roads and can consider the effects of terrain relief and curves along a route on the route planning, was proposed and utilized for the software development. GEOHARTS can determine optimal haulage routes between loaders and dumps that ensure the least travel time or fuel consumption of off-road dump trucks and can visualize the results using an embedded 3D render window of Google Earth. The application to the Pasir open-pit coal mine in Indonesia dem...
Satellite Observations of the Southeast Pacific Intertropical Convergence Zone During 1993-1998, Halpern, D.; Hung, C.-W., Journal of Geophysical Research ? ...
Earth degassing specifically of carbon dioxide CO2 is of increasing interest with respect to the global carbon budget, related climate effects, earthquake and volcano eruption mechanisms, as well as plant physiological reactions in gas-rich environments. Investigations in all of these disciplines require the detection of surface CO2 degassing structures and quantification of their emissions. We introduce minimal thermal change detection based on infrared imaging as a new remote sensing tool for the detection of earth surface thermal anomalies suiting among others to discover earth degassing locations of any origin. The method allows for seamless areal search and monitoring of degassing structures in any terrain. As proof of concept infrared imaging measurements were performed at the Bossol...
of Earth Science data and information management capabilities. Dale Schulz/400 . For your exceptional achievement in leading the joint LaRC/GSFC team in ...
... Zinn, J., Hoerlin, H., and Petschek, AG, "The Motion of Bomb Debris Follow- ing the Starfish Test," Radiation Trapped in the Earth's Magnetic Field ...
The portion of the Waterpocket Fold illustrated in this image includes layered rocks formed during the Mesozoic Era (~ 250 65 million years ago) the oldest ...
Hie synthesis of diverse biologically important compounds, under condi- tions which existed on the earth in the initial period of its evolution, ha; ...
The abstract is additional with repect to the paper published in JGCD. Ordinary Earth satellites are usually placed into five categories of special orbits: sun-synchronous orbits, orbits at the critical inclination, frozen orbits, repeating ground track orbits, and geostationary orbits. This paper investigates their counterparts around Mars and examines the basic nature of these orbits, which are of special interest for missions conducted around Mars, including Mars reconnaissance. Mars' gravity field is much more complicated, with relatively smaller J2, compared to Earth's, which makes the behaviors of these Martian orbits different from those of Earth. Analytical formulations and numerical simulations are used to analyze these Martian orbits and compare them with their Earth counterparts. First, mean element theory is employed to describe variations of orbital elements and give the constraint ...
The SHARP cannon. Hydrogen is compressed in the tube on top, the gun barrel is on bottom. When Jules Verne wrote in 1865 "From Earth to the Moon" he ...
Turbine Afterword The SHARP cannon. Hydrogen is compressed in the tube on top, the gun barrel is on bottom. When Jules Verne wrote in 1865 "From Earth to the Moon" he envisioned...
Extraction of rare earths (La, Ce, Pr, Eu, Gd, Er, Yb) from nitrate solutions by melts of carboxylic acids of the C/sub 17/-C/sub 20/ fraction and stearic acid with paraffin, depending on the temperature (60-90 deg), phase contact time and their volume ratio (O:B from 1:5 up to 1:100), pH of the aqueous phase (2-6), rare earth concentration (10/sup -6/-10/sup -3/ m) is studied. It is shown that in the whole concentration range investigated rare earths are extracted quantitatively into the carboxylic acid melt of C/sub 17/-C/sub 20/ fraction at the equilibrium value of pH>=3.8, while into the melt of 0.1 M stearic acid in paraffin at pH>=4.5.
Aug 23, 2011 ... Earthquakes, Hurricanes and Stubborn Instruments ... And if earthquakes and stubborn instruments aren't enough, there's this giant hurricane ...
World demand for rare-earth elements and the metal yttrium?which are crucial for novel electronic equipment and green-energy technologies?is increasing rapidly. Several types of seafloor sediment harbour high concentrations of these elements. However, seafloor sediments have not been regarded as a rare-earth element and yttrium resource, because data on the spatial distribution of these deposits are insufficient. Here, we report measurements of the elemental composition of over 2,000 seafloor sediments, sampled at depth intervals of around one metre, at 78 sites that cover a large part of the Pacific Ocean. We show that deep-sea mud contains high concentrations of rare-earth elements and yttrium at numerous sites throughout the eastern South and central North Pacific. We estimate that an a...
switch when this cavity matching condition is determined. This results is a ... MHz offset is provided by an acousto-optic modulator. (AOM). The AOM will be shut ...
Zinn, John;. Hoerlin,. Herman; and Petschek,. Albert. G.: The Motion of Bomb. Debris. Following the Starfish. Test. Radiation. Trapped in the Earth's ...
Titanium alloys are characterized by poor tribological properties, and the traditional use of titanium alloys has been restricted to nontribological applications. The deposition of a well adherent diamond coating is a promising way to solve this problem. In this study, the tribological properties of diamond-coated titanium were studied using a pin-on-disk tribometer, and the results were compared with those of pure titanium and plasma nitrided titanium. The tribological behavior of pure titanium was characterized by high coefficient of friction and rapid wear of materials. Plasma nitriding improved the wear resistance only under low normal load; however, this hardened layer was not efficient in improving the wear resistance and the friction properties under high normal load. Diamond coating on pure titanium improved the wear resistance of titanium significantly. Surface profilometry measurement indicated that little or no ...
This paper describes an investigation of electrodeposited Zn-14% Ni and aluminium-based SermeTel 1140/962 coatings as possible replacements for cadmium. Slow strain rate tests were performed to measure the extent of direct hydrogen embrittlement of a high strength steel substrate as a result of the coating process and of hydrogen re-embrittlement caused by coating corrosion. The level of re-embrittlement was shown to depend on both the electrochemical potential of the coating and its barrier properties. Zn-14% Ni coatings caused the most re-embrittlement as they had the most active potential and contained through-thickness defects which left the steel exposed to hydrogen uptake. The microstructure of the high strength steel was also shown to be an important factor affecting the extent of embrittlement. AerMet 100 steel was more resistant than 300M steel and this was attributed to ...
Today, as a result of increase in oil prices, limited fossil fuel resources, environmental consideration and global warming, the methyl ester fuels have been focused on alternative fuels. Methyl ester fuels can be used more efficiently in low heat rejection engines (LHR), in which the temperature of combustion chamber is increased by creating a thermal barrier. In this study, the piston, cylinder head, exhaust and inlet valves of a diesel engine were coated with the ceramic material Al{sub 2}O{sub 3}-TiO{sub 2} by the plasma spray method. Thus, a thermal barrier was provided for the parts of the combustion chamber with these coatings. The effects of corn oil methyl ester that produced by the transesterification method, and No. D2 fuels' performance and exhaust emissions' rate were studied by using equal in every respect coated and uncoated engines. Tests were performed on the uncoated engine, and then ...
Several types of coatings have previously been visually identified on the surface of 105-K East and 105-K West Basins fuel elements. One type of coating (found only in K West Basin) in particular was found to be a thick translucent material that was often seen to be dislodged from the elements as flakes when the elements were handled during visual examinations (Pitner 1997). Subsequently it was determined (for one element only in a hot cell) that this material, in the dry condition, could easily be removed from the element using a scraping tool. The coating was identified as Al(OH){sub 3} through X-ray diffraction (XRD) analyses and to be approximately 60 {micro}m thick via scanning electron microscopy (SEM). However, brushing under water in the basin using numerous mechanical strokes failed to satisfactorily remove these coatings in their thickest form as judged by appearance. Such brushing was done ...
This report outlines on the corrosive damage which is inherent to a high temperature environment and introduces on thermal spraying system taking an example of a gas turbine. The recent coatings by thermal spraying for high temperature environment are positively used in such applications as a hearth roll for continuous annealing, a roll for hot dipped steelplate, a solid electrolyte for fuel cell, boilers and rockets. The coating formed will be positively used because of a convenient thermal spraying and availability of various sprayable materials. This report describes the following items. Corrosive damage under the high temperature environment. Types of high temperature corrosive coating by a thermal spraying and utilization thereof. Outline of MCrAlX alloy, and merits thereof. Coating to a turbine wing by rduced pressure plasma thermal spraying. In general, it is urgently needed to establish the ...
The photon rupture method, by which oxide film and metal are removed by focused pulsed Nd-YAG laser beam irradiation, was applied to form artificial micro-pits in Zn-5 mass% Al alloy-coated steel. The zinc alloy-coated layer was removed by pulsed laser irradiation treatment for about one second in a neutral buffer solution with NaCl. The rest potential transient with the laser treatment was measured. In the early stage of the laser treatment the rest potential of zinc alloy-coated steel changed to the negative direction immediately after every irradiation of a laser pulse and then returned to the previous value. However, after the steel substrate was exposed to the solution, the rest potential moved to the positive direction immediately after every irradiation of a laser pulse and then returned to the previous value. The amplitude and duration of the potential change after the laser irradiation increased with repetition of ...
The hydrogen evolution reaction (HER) was studied on bare brass (B), nickel coated brass (B/Ni), nickel-zinc alloy coated brass (B/NiZn, leached Zn), nickel (under layer)/nickel-zinc alloy coated (top layer) brass electrodes (B/Ni/NiZn, leached Zn) in 1 M NaOH solution using electrolysis, cathodic polarization and electrochemical impedance spectroscopy (EIS) techniques. Long term tests were performed in order to evaluate the electrocatalytic activity and corrosion performance of the prepared electrodes with operation time. The results showed that leached electrodes, especially B/Ni/NiZn electrode, have a smaller overpotential than the others and a good electrocatalytic activity for the HER. Its electrocatalytic activity is also stable over electrolysis time. Contrary to the HER performance, B/NiZn cannot provide an adequate corrosion protection. However, when a thin Ni layer was coated under the NiZn ...
Lower cost painting flock-like in appearance and touch feeling was developed as a new surface softening method for automobile interior plastic molded parts. The base coat with the same color as piles mixed into a top coat was first painted on the surface of a plastic molded part after cleaning, and after the top coat with less pitch mixed with piles was painted on the wet base coat and dried by a heater, excess piles were removed with suction and air blowing to produce flock-like appearance. Nylon 66 of 0.4mm in length was used as piles, and mixed into the top coat by 8.0wt% in content. This painting method was applicable to even such parts as one with a complex configuration, and one impossible to set piles on it by conventional methods because of poor durability. As a certain amount of piles with different colors were mixed into the top coat, sprinkly colored ...
Researchers are developing polymer-based coating systems to reduce scaling and corrosion of air-cooled condensers that use a geothermal fluid spray for heat transfer augmentation. These coating systems act as barriers to corrosion to protect aluminum fins and steel tubing; they are formulated to resist the strong attachment of scale. Field tests have been done to determine the corrosion and scaling issues related to brine spraying and a promising organometallic polymer has been evaluated in salt spray tests.
The authors describe measurements of emittance made on samples of solar cell coverglasses incorporating new coatings both on C-7940 fused silica and on CMX ceria doped microsheet. Samples of a conventional, MgF_2 coating on the same two types of coverglass substrates were included in the measurements as controls. Measurements were made by the calorimetric method of total hemispherical emittance within a cooled chamber as well as by the more common infrared reflectance method. Emittance enhancements from 1 to 4% were measured for the new coatings.
A zinc/air battery is claimed whose performance is improved by omitting separating elements such as diaphragms etc. The cathode and anode spaces are separated by a collector with holes big enough to permit the electrons to pass freely while restraining the anode material. Further, the active material consists of a spherical care of inert material with a zinc coating. Under the zinc coating, the spherical particles have another thin coating of an electropositive material, e.g. nickel. The cell also contains means for circulating the anode suspension.
Electron paramagnetic resonance was used to investigate surface-coated magnetite-based magnetic fluids doped with TEMPOL. Two magnetic fluid samples, having magnetite nanoparticles with average diameter of 94 A and coated with different coating layers (lauric acid plus ethoxylated polyalcohol in one case and oleoylsarcosine in the other case), were doped with TEMPOL (6 mM and pH 7.4) and investigated as a function of the nanoparticle concentration. The resonance field and the resonance linewidth both scale linearly with the nanoparticle concentration.
On the basis of cylindrical roller thrust bearings it was systematically examined to what extent PVD-coatings are able to take over the function of EP/AW-additives. The bearings were tested under heavy-duty conditions in order to distinguish very fast the efficiency of different coating-substrate-systems. Several coatings were tested for their ability to protect an un-coated counterpart. So just the washers of the roller bearings were coated, the rollers stayed un-coated. Four Me-C:H-coatings showed the best performance and fulfilled the required criterion for roller bearings in the boundary friction: low loss of mass and hardly surface deviation. Material carryover from the carbonaceous coating to the 100Cr6 steel surface was developed by the Me-C:H-coatings during the tests. This mechanism was able ...
A stable BSA blocking poly(dimethylsiloxane) (PDMS) microchannel was prepared based on in situ synthesized PDMS-gold nanoparticles composite films. The modified microchip could successfully suppress protein adsorption. The assembly was followed by contact angle, charge-coupled device (CCD) imaging, electroosmotic flow (EOF) measurements and electrophoretic separation methods. Contact angle measurements revealed the coated surface was hydrophilic, water contact angle for coated chips was 45.2^o compared to a water contact angle for native PDMS chips of 88.5^o. The coated microchips exhibited reproducible and stable EOF behavior. With FITC-labeled myoglobin incubation in the coated channel, no fluorescence was observed with CCD image, and the protein exhibited good electrophoretic effect in ...
Performance and emissions data were gathered on a normally aspirated single cylinder DI engine with various combinations of ceramic coatings installed. Thin ceramic thermal barrier coatings were applied to the piston crown and bowl, the head and valves, and the cylinder liner. The coated piston and head were run singly and in combination with the cylinder liner to investigate the effects of these different coated surfaces on emissions and performance. Coating the piston crown alone results in generally lower cylinder pressure, lower brake specific fuel consumption and lower NO(x) emission compared to the baseline engine. Soot emission is typically increased below 2000 RPM and decreased above 2000 RPM. Coating the head alone reduces cylinder pressure, but generally increases specific fuel consumption and NO(x) and soot emission. The KIVA-II code was used to model ...
drical Enclosures Using a Numerical Ray Tracing Technique. NASA. TM-I02527, 1990 . Buckley, H.: Radiation from the Interior of a Reflecting Cylinder. Philos. ...
Aluminium AA5182 coupons covered by a polyaniline film in the emeraldine base (EB) form showed increasing corrosion potential and decreasing corrosion current as a function of the thickness of the polymer layer. The cathodic reaction was proved not limited by diffusion of species inside the electrolyte solution and oxygen had no effect on the electrochemical behaviour of the coated samples. An EB coating on indium tin oxide conducting layer appeared slightly electroactive in neutral media. The IR spectra of aluminium coated samples, before and after heating in argon atmosphere, confirmed a redox reaction between the polymer film and the metal. This galvanic coupling can explain the good protective behaviour of emeraldine base against corrosion of aluminium.
COATINGS FOR THE METAL-SEMICONDUCTOR SOLAR CELLS 3S GIVEN. THIS METHOD UTILIZES THE MEASURED EQUIVALENT INDEX OF. REFRACTION OBTAINED FROM ELLIPSOMETRY ...
The mechanical stability of diamond-like carbon (DLC) films coated on nitinol vascular stents was investigated under cyclic loading condition by employing a stent crimping system. DLC films were coated on the vascular stent of a three dimensional structure by using a hybrid ion beam system with rotating jig. The cracking or delamination of the DLC coating occurred dominantly near the hinge connecting the V-shaped segments of the stent where the maximum strain was induced by a cyclic loading of contraction and extension. However the failures were significantly suppressed as the amorphous Si (a-Si) buffer layer thickness increased. Interfacial adhesion strength was estimated from the spalled crack size in the DLC coating for various values of the a-Si buffer layer thickness.
The main purpose of solid or fluid lubricants in ball-bearings is to separate the balls and races from contacting each other in so-called asperity collisions. Steel to steel contacts lead to microwelds which roughen functional rolling-contacting surfaces and deteriorate the lubricant. By using balls with a ceramic TiC coating, two goals are achieved. First, there are fewer asperity collisions because of the extreme smoothness of the high precision polished TiC coated balls. Second, if collisions do occur, there is practically no microwelding taking place, leaving the surfaces and the lubricant in good condition. Examples are given where the bearing lifetime is increased up to 10 times if the steel balls are replaced by TiC-coated balls. (orig.).
• Background and Aims The occurrence of stomata in seed coats is uncommon and there is limited information about their function(s). The aim of this study was to verify the distribution...Full Text Available
The refractory nature and high ductility of body centered cubic (bcc) phase tantalum makes it a suitable material for corrosion- and wear-resistant coatings on surfaces which are subjected to high stresses and harsh chemical and erosive environments. Sputter deposition can produce thick tantalum films but is prone to forming the brittle tetragonal beta phase of this material. Efforts aimed at forming thick bcc phase tantalum coatings in both flat plate and cylindrical geometries by high-rate triode sputtering methods are discussed. In addition to substrate temperature, the bcc-to-beta phase ratio in sputtered tantalum coatings is shown to be sensitive to other substrate surface effects.
Polymer-coated magnetic nanoparticles (MNPs) have been prepared and used as an immobilization matrix for the fabrication of solid-state tris(2,2prime-bipyridyl)ruthenium(II) (Ru(bpy)32+) electrogenerated chemiluminescence (ECL) sensor. The pre-synthesized maghemite (g-Fe2O3) MNPs were coated with poly(3-thiopheneacetic acid) based on an oxidative polymerization method using KMnO4. The poly(3-thiopheneacetic acid)-coated MNPs have formed the clusters with average diameter of 200-500nm. The multilayer films of poly(3-thiopheneacetic acid)-coated MNPs were uniformly formed on the surface of a Pt electrode by an external magnet. The Ru(bpy)32+ was rapidly incorporated into the multilayer films within 5min through the electrostatic interaction between the Ru(bpy)32+ and the negatively charged c...
Herein, we demonstrate the structure of the PS colloidal crystals which were fabricated on the hydrophilic/hydrophobic Si wafers by a spin-coating technique. Monodisperse PS colloids are spin-coated onto self-assembled monolayers of 3-(aminopropyl)triethoxysilane and propyltrimethoxysilane coated Si wafers. PS spheres organized as ordered close-packed face-centered cubic structure with (111) planes on the hydrophilic surface while they gathered without the crystal structure on the hydrophobic surface. This paper also reports a simple and rapid method to fabricate the close-packed structure of hollow TiO2 spheres. The colloidal crystal of TiO2 hollow spheres was prepared using the PS sphere template on the hydrophobic surface. The mechanism for the growing multilayers of self-assembled PS p...
A test bench was designed and assembled to carry out impact tests on samples and components. The system allows simple and rapid adjustment of the test parameters, such as the shot size and air pressure, with good repeatability of the results. Tests on steel and light alloys were carried out under both as-produced condition and on thin hard-coated samples. Significant reductions in dimple dimensions were seen after coating. FE models simulating the experiments overestimated the dimple depths, although the parameter trend was satisfactorily captured. The residual stresses from coating and shot peening determined numerically are believed to have been proven effective against fatigue.
Ni-Co/SiC nanocomposite coatings were electrodeposited in a modified watt type of Ni-Co bath containing 20nm SiC particles to be codeposited. Potentiodynamic polarization tests were conducted to study the effect of the SiC particulates on the electrodeposition of Ni and Co. Scanning electron microscopy was used to assess the morphology of the Ni-Co alloy and Ni-Co/SiC nanocomposite coatings. The distribution of the particulates in the matrix was considered by means of transmission electron microscopy. Applying nanomechanical testing instruments coupled to atomic force microscopy, mechanical properties of the alloy and composite coatings were studied and compared. The presence of 11vol.% SiC in the Ni-Co matrix increased hardness more than 60%. The average depth of scratch in the mentioned ...
Fluorocarbon polymers are used to enhance thermal stability and electrostatic protection of composite propellant compositions. A precipitation technique has been developed to coat ammonium perchlorate (AP) using a copolymer of hexafluoropropylene and vinylidene fluoride (HFP-VF) with the help of solvent-counter solvent method. The coated AP has been used to prepare propellant compositions in different ratio based on hydroxyl terminated polybutadiene (HTPB), aluminium powder along with uncoated AP and studied for viscosity build-up and visco-elastic behaviour as well as mechanical, ballistic, thermal and sensitivity properties keeping 86% solid loading. The data on viscosity build-up indicate that as the percentage of viton coated AP increases end of mix viscosity and viscosity build-up inc...
TiB{sub 2} appears to be a promising material for the wear protection in various tribological systems, e.g. the diecasting of Al. This study focuses on the development of titanium boride coatings deposited by PACVD, a deposition method which is most suitable for the coating of substrates with complex shapes. All layers analysed are very smooth and exhibit a quasi-amorphous fracture surface. XRD and TEM analysis indicate a nanocrystalline structure with grain sizes in the order of 2 nm. The diffraction patterns can well be correlated to titanium diboride. WDS reveals an over stoichiometric B/Ti ratio. The layer hardness reaches the value of 33 GPa and the critical load in scratch tests rises to 35 N. Neither 100Cr6 nor Al as a counterpart in pin-on-disk tests leads to wear of the coating. (orig.)
Plasma Technologies in Institute of Plasma Physics of the NSC KIPT are recently developed in the following directions. Material surfaces modification under their irradiation with pulsed plasma streams of different working gases. Besides traditional analysis of improvements of tribological characteristics and structural-phase changes of the modified layers recently we started investigations of material corrosions characteristic improvement under influence of pulsed plasma on the material surfaces. As to the surface coatings in arc discharges of Bulat type devices, new trends are related with multi-layers coatings, using Ti-AI-N coatings in cutting tools, using high frequency discharges or combined HF- and arc discharges for increasing the nomenclature of goods to be coated. Development of ozonators is respectively new area for IPP NSC KIPT. On the base of barrier high-frequency discharge there were ...
Amino-rich polymeric coatings are widely used in biomedical applications, since they promote adsorption of diverse biomolecules or facilitate cell growth. As a consequence, there is a growing interest in fabrication of such coatings that is focused predominantly on the optimization of the deposition process in terms of high density of primary amino groups. In addition, the nature of biomedical applications requires also sufficient stability of the films in aqueous environments. This aspect is investigated in this contribution. In particular, the effect of water and phosphate buffer saline on the coatings prepared by RF magnetron sputtering of Nylon 6,6 in Ar/N2 and N2/H2 gas mixtures is evaluated. The samples exposed to liquids are characterized by various diagnostic methods and their prop...
Corrosion behavior of deposition coated specimens prepared by the technique proposed by the authors is investigated in salt immersion tests, and also those of pure magnesium, 3N, 4N and 6N grades, and magnesium alloys, AZ31 and AZ91E, are investigated for comparison. Inhomogeneous corrosion occurs in AZ31 and AZ91E alloys when buffered solutions with pH values of 6.5 and 9.0 including 1% NaCl and a conventional 3% NaCl solution are used for immersion tests, while 6N-Mg shows homogeneous corrosion in such solutions. Corrosion behavior of the deposition coated specimen resembles that of 6N-Mg. Purification process included in the deposition coating technique provides homogeneity in microstructural and electrochemical terms, which results in improving corrosion resistance. (orig.)
In the present study, surfaces of cylinder head, piston, exhaust and inlet valve of a four-stroke, direct injection, single cylinder diesel engine were coated with molybdenum (Mo) by plasma spray method. Thus, thermal barrier characteristic was brought to these parts. Variances in performance and emission values of cotton methyl ester and 2D fuel mixtures were studied in the ceramic coated and uncoated engines under the same running conditions. Performance (6.0% for specific fuel consumption) and emission values (up to 18.0% for CO, 8.0% for smoke density) of the test fuel were improved in the coated engine compared with the uncoated engine. NO_x increase (4.5%) with the increased temperatures expected in the coated engine.
Alloy 800 and Alloy 600 are well known for their resistance to corrosion in an aqueous medium at high pressure and temperature, for which they have been widely used for more than 3 decades in different structural components of water refrigerated nuclear reactors, especially as material for the steam generator tubes (SG) in these nuclear plants. The SG tubes in the Atucha I and Embalse Nuclear Plants are made with Alloy 800. The speed of corrosion of these materials in a reactor's refrigerant medium, while very small is perfectly measurable and can be described by parabolic or logarithmic type kinetics. In other words this speed is high in the first states of growth during the formation of a protective oxide film but then drops to almost stationary values. One characteristic of these films is the formation of a double layer (or duplex): i) an internal adhering layer, of approximately constant thickness, formed by small microcrystals (#<=#0.05 mm), ii) a less adhering external one, ...
In this paper, we first discuss the detection of supernova neutrino on Earth. Then we propose a possible method to acquire information about $\\theta_{13}$ smaller than $1.5^\\circ$ by detecting the ratio of the event numbers of different flavor supernova neutrinos. Such an sensitivity cannot yet be achieved by the Daya Bay reactor neutrino experiment.
Aimed at post-graduate and post-doctoral researchers in geochemistry, this book reflects the rapid changes in the applications of radioactive and stable isotope analysis to a range of geological and geochemical problems. Isotropic chemistry and methods used in mass spectroscopy are discussed initially. The second section deals with radiometric dating methods. The role of isotopes in climate and environmental research is also explored. The book closes with a section on extra-terrestrial matter, geothermometry and the isotopic geochemistry of the Earth`s lithosphere. (UK).
Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)
Clays and zeolites are among the most important of natural dusts by virtue of their occurrence through out the world on the earth`s surface and their important industrial uses. (The 1:1 layer silicates, including the serpentine and kaolin minerals, are not addressed in this chapter.) This chapter provides basic information on a variety of important aspects of each mineral, including crystal structure diagrams of each and references to more detailed discussions. 110 refs., 20 figs.
Measurement of the magnetic susceptibility of powder samples of heavy rare-earth (Tb, Dy, Ho, Er, Tm and Yb) tungstates have been reported in the temperature range 300 to 900 K. Curie-Weiss law behaviour has been observed for all samples. The Curie constant, paramagnetic Curie temperature and magneton number for the magnetic ions have also been evaluated for each material. (author).
Among the billions of planetary systems that fill the Universe, we would like to know how ours fits in. Exoplanet data can already be used to address the question: How common are Jupiters? Here we discuss a simple analysis of recent exoplanet data indicating that Jupiter is a typical massive planet rather than an outlier. A more difficult question to address is: How common are Earths? However, much indirect evidence suggests that wet rocky planets are common.
Summaries of the highlights of programs in the Earth Sciences Division are presented under four headings; Geosciences, Geothermal Energy Development, Nuclear Waste Isolation, and Marine Sciences. Utilizing both basic and applied research in a wide spectrum of topics, these programs are providing results that will be of value in helping to secure the nation's energy future. Separate abstracts have been prepared for each project for inclusion in the Energy Data Base. (DMC)
...Observatory Edinburgh SkyView Virtual Observatory Solar System Simulator Space Telescope Science Institute Space Weather : A Research Perspective Subaru Telescope Project Two Micron All ...Universities for Research in Astronomy Subjects: space observation DeweyClass: 522 Resource type: index Space Weather : A Research Perspective Documents discussing space weather , the ...elements of near-Earth space, Earth-space meteorology and practical consequences of space weather . Glossary included. Author: National Academy of ...
...6 Resource type: reference data Global Change Master Directory An extensive source of information about satellite and in situ Earth science data, with broad coverage of the atmosphere, hydrosphere, oceans, solid earth, and biosphere. Author: NASA Subjects: climatology, global change, oceanographic data DeweyClass: 551.6 Resource type: documents, news International ...
When a bipolar HVDC transmission system is operating monopolar using the earth as a return path, it is often desired to divert the return current from the earth to the line from the unused pole. To do so requires either that the system be shut down temporarily or that a dc circuit breaker be used. This paper describes the development of such a new dc circuit breaker, and its application on the Pacific Intertie as a Metallic Return Transfer Breaker (MRTB).
An electric propulsion concept suitable for delivering heavy payloads from low earth orbit (LEO) to high energy earth orbit is proposed. The system consists of a number of pulsed inductive plasma thrusters powered by a 100 kWe space nuclear power system. The pulsed plasma thruster is a relatively simple electrodeless device. It also exhibits adequate conversion to thrust power in the desired I sub sp regime of 1500 to 3000 seconds for optimal payload transfer from low earth to high earth orbit. Because of these features and the fact that the nuclear power unit will be capable of delivering sustained high power levels throughout the duration of any given mission, the system presented appears to be a very promising propulsion candidate for advanced orbital transfer vehicle (OTV) applications. An OTV, which makes use of this propulsion system and which has been designed to lift a 9000-lb payload into ...
The bright star 55 Cancri is known to host five planets, including a transiting super-Earth. The interferometric study presented here yields directly determined values for 55 Cnc's stellar astrophyiscal parameters: $R=0.943 \\pm 0.010 R_{\\odot}$, $T_{\\rm EFF} = 5196 \\pm 24$ K. We use isochrone fitting to determine 55 Cnc's age to be 10.2 $\\pm$ 2.5 Gyr, implying a stellar mass of $0.905 \\pm 0.015 M_{\\odot}$. Our analysis of the location and extent of the system's habitable zone (0.67--1.32 AU) shows that planet f ($M \\sin i = 0.155 M_{Jupiter}$) spends the majority of the duration of its elliptical orbit in the circumstellar habitable zone, where, with moderate greenhouse heating, it could harbor liquid water. Finally, our direct value for 55 Cancri's stellar radius allows for a model-independent calculation of the physical diameter of the transiting super-Earth 55 Cnc e ($\\sim 2.05 \\pm 0.15 R_{\\earth}$), which, ...
Micron-size Ni-base alloy (NBA) powders were mixed with both 1.5 wt.% (hereinafter %) micron-size CeO{sub 2} (m-CeO{sub 2}) and also 1.5% and 3.0% nano-size CeO{sub 2} (n- CeO{sub 2}) powders. These mixtures were coated on low-carbon steel (Q235) by 2.0 kW CO{sub 2} laser cladding. The effects on the microstructures, phases and electrochemical corrosion of the coatings upon the addition of m- and n- CeO{sub 2} powders to NBA (m- and n- CeO{sub 2} /NBA) have been investigated. The results showed that a smooth coating was prepared under suitable processing parameters (P= 2.0 kW, V= 180 mm min{sup -1}) by adding 1.5% n- CeO{sub 2}. In addition to the primary phases of {gamma}-Ni, Cr{sub 23} C{sub 6} and Ni{sub 3} B in the Ni-base alloy coating, CeNi{sub 3} was formed in Ni-base alloy coatings with both n- CeO{sub 2} and m-CeO{sub 2} particles, and CeNi{sub 5} appeared in the ...
The high temperature abrasive wear resistant of the composites with different Al{sub 2}O{sub 3} volume fractions, particle coating and size were investigated and the failure action of composites under different conditions at high temperature was analyzed. The results showed that the high temperature abrasive wear resistant of composite with Ni coating and wide size and 39% volume fraction of particle is the best among all composites examined. (orig.)
PVD-coatings based on TiB{sub 2} are expected to show high wear resistance and low tendency of adhesion on metal forming tools. Coating adhesion and morphology can be modified over a wide range by varying the content of nitrogen (N{sub 2}) and the deposition parameters power and bias voltage. All coatings were deposited using commercial unbalanced magnetron equipment, the deposition was homogeneous in a volume of 400 x 400 x 400 mm{sup 3}. Hipped and hot pressed TiB{sub 2}-targets were used, nitrogen (N{sub 2}) was added as gas, Ti and Al by a solid Ti-Al-target. The tribological behaviour was tested by a pin-on-disc wear test. The coatings investigated were TiB{sub 2}, TiAlB(N), TiAl(N) and TiB{sub 2}/TiAl(N). As counterpart in the pin-on-disc wear test, 6 mm diameter spheres of steel (100Cr6), aluminium, brass and bronze were used. The experiments showed a non-uniform wear behaviour. For the ...
This rebuttal to a previous article provides new insight into the use of sprayed sealants in uranium mines. The author rejects the idea that the value of rock sealant on radon control is destroyed by changes in barometric pressure, showing that this is not necessarily true. The analyses described demonstrate that radon contamination resulting from changing barometric pressures is reduced by a rock coating. The overall use of coatings depends on their costs and effectiveness as compared with other radon control measures. 6 refs.
This Test Plan outlines the testing to be done on the Special Protective Coating (SPC) Polyurea which includes: Tank Waste Compatibility, Decontamination Factor Testing, and Adhesion Strength Testing after a sample has been exposed to Radiation.
A super-hydrophobic coating was prepared by combining a rigid base film with crater-like hemispherical holes and acicular nanoparticles. The acicular boehmite powder provides a high contact angle on the film surface. The rigid base film with crater-like hemispherical holes inhibits the rapid decrease of contact angle by surface rubbing. The combination of different roughness is an effective method for improving the abrasion resistance of super-hydrophobic films.
The effectiveness of an acrylic latex wall sealant in limiting the escape of radon from rock in underground mines is the subject of this paper. Application of the latex as a two-coat system over a fillter coat of gunite produced a reduction of radon concentration from an initial level of 80 to 100 pCi/L to a final average of 25 to 30 pCi/L under similar conditions.
Thin solid films of CeO[sub 2] and mixed CeO[sub 2]-TiO[sub 2] were prepared by the sol-gel route via the dip-coating technique. Particulate sols of ceria were made from inorganic ((NH[sub 4])[sub 2]Ce(NO[sub 3])[sub 6]) precursor which were used for preparation of CeO[sub 2] thin solid films while CeO[sub 2]-TiO[sub 2] coatings have been made by using mixed organic-inorganic (Ti(OiPr)[sub 4] and CeCl[sub 3].7H[sub 2]O) precursors. The solar transmission values (T[sub s]) of both coatings are in the range 0.6-0.8 and depend on coating thickness. Cyclic voltammetric (CV) measurements show that the CeO[sub 2]/LiOH system exhibits higher overall electrochemical reversibility when compared to the CeO[sub 2]-TiO[sub 2]/LiOH system. The CeO[sub 2]/LiOH system is also less sensitive with regard to the coating thickness. Coulometric measurements show that CeO[sub 2] exhibits a larger ...
Four subprojects were completed: development and evaluation of die coatings, accelerated die life characterization of die materials, evaluation of fluid flow and solidification modeling programs, selection and characterization of Al-based die casting alloys, and influence of die materials and coatings on die casting quality.
A portable fiber optic detector that senses the presence of specific target chemicals by electrostatically attracting the target chemical to an aromatic compound coating on an optical fiber. Attaching the target chemical to the coated fiber reduces the fluorescence so that a photon sensing detector records the reduced light level and activates an appropriate alarm or indicator.
This heat exchanger is a critical step in the development of the Externally Fired Combined Cycle power system, a direct-coal combustion power plant (gas turbine). SiC is the only material with the needed resistance to creep, thermal shock, and oxidation; however a protective coating is needed. Ten candidate materials were identified: alumina-based materials, materials stable with SiO, and low expansion materials. An initial screening study should be performed.
Coatings and sensors having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided.
Chromium nitride/Cr coating has been deposited on surface of 316L stainless steel to improve conductivity and corrosion resistance by physical vapor deposition (PVD) technology. Electrochemical behaviors of the chromium nitride/Cr coated 316L stainless steel are investigated in 0.05 M H{sub 2}SO{sub 4}+2 ppm F{sup -} simulating proton exchange membrane fuel cell (PEMFC) environments, and interfacial contact resistance (ICR) are measured before and after potentiostatic polarization at anodic and cathodic operation potentials for PEMFC. The chromium nitride/Cr coated 316L stainless steel exhibits improved corrosion resistance and better stability of passive film either in the simulated anodic or cathodic environment. In comparison to 316L stainless steel with air-formed oxide film, the ICR between the chromium nitride/Cr coated 316L stainless steel and carbon paper is about 30 m{omega} cm{sup 2} that is ...
An industrial EB processing line is started to produce cement-bound /CB/ chipboard with radiation cured acrylic coating. The basic features of this line are presented here. The main technological parameters of coating such as: effect of oligomer- and monomer reactivity, monomer functionality, dose-rate and inerting atmosphere on the progress of curing have been discussed. The EB processed CB board is an advanced composite material for the modern lightweight architecture.
The dispersion of more than 20 vol pct submicrometer ceramic particles within a metallic matrix and the deposition of such a cermet to form a thick and tough coating presents problems. Most of the coating techniques have failed in attempting to homogeneously disperse very fine and hard particles in large amounts while avoiding their decomposition or reaction with the metal matrix during the deposition process. A simple and efficient method has been developed for producing ceramic-containing composite coatings. It consists in synthesizing cermet-based materials and in depositing them by a rapid solidification process, such as thermal spraying. Boride- and carbide-based materials have been successfully obtained by plasma spraying reactive powders comprising the basic reagents. These materials, with a microstructure of submicrometer ceramic particles dispersed in a metallic matrix, exhibit good wear-resistant properties ...
In this work a comprehensive metallophysical study was carried out for two aluminosilicide slip coatings of the systems Al-Si and Al-Nb-Si and an electron-beam Co-Cr-Al-Y coating on alloy EP-539 (17...19% Cr, 4...6% Co, 2.5...4% W, 4.5...6.5% Mo, 2...3% Ti, 3...4% Al, 1.4...2% Nb, balance Ni) after high-temperature testing. The protective properties of the coatings were evaluated from the results of laboratory tests for heat resistance at 1000/sup 0/C in the combustion products of diesel fuel with added sulfur at 970, 1000, and 1060/sup 0/C for 100 h and after full-scale tests for 150, 250, 400, and 700 h. Metallographic, hardness, x-ray, and micro x-ray studies of the coating were carried out. Layer-by-layer phase composition and the lattice spacing of the main phases were determined. X-ray analysis was carried out in an a DRON-1 diffractometer in copper K/sub ..-->../-radiation, and x-ray ...
There has been a growing interest in new laser systems for use at mid-infra-red wavelengths, driven by requirements for a number of diverse applications. Developments in mid-IR coating technology are following three major thrusts. In the first, the potential of ion-assisted process is being exploited and the technology is already becoming well established in the optical coating industry. In the second, the benefits of using gas-phase precursors are being explored, driven by the potential of avoiding the generation of second phase inclusion in the coatings with associated reduction in laser damage threshold. Research is also addressing the use of nanocomposite materials with an engineered microstructure to produce coatings with dielectric properties of choice. This paper presents a review of progress in some of these areas with special emphasis on the comparison of the properties of materials at DF laser ...
This paper introduces a new method to produce nano-composite powder for the preparation of high performance ZnO varistors. ZnO particles were coated with Bi{sub 2}O{sub 3}, Sb{sub 2}O{sub 3}, Co{sub 2}O{sub 3}, Cr{sub 2}O{sub 3} and other additives via liquid nano-coating technique. Then the prepared powder was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravity and differential scanning calorimetry (TG-DSC) and particle size distribution. The results showed that the ZnO composite powder is homogeneously coated and ultrafine. The densification, phase composition and microstructure of ZnO varistors was studied by linear shrinkage, X-ray diffraction (XRD) and SEM, respectively. The preliminary electrical parameters of ZnO varistors showed that the breakdown voltage V {sub b} (1 mA/cm{sup 2}) and nonlinear coefficient {alpha} is 5400 V/cm and 50, respectively, much ...
This paper presents the first results on formation and study of structure and properties of micro- and nanocomposite combined coatings. By means of modeling the deposition processes (deposition conditions, current density-discharge, plasma composition and density, voltage) we formed the three-layer nanocomposite coatings of Ti-Al-N/Ti-N/Al_2O_3. The coating composition, structure and properties were studied using physical and nuclear-physical methods. The Rutherford proton and helium ion backscattering, scanning electron microscopy with microanalysis, grazing incidence X-ray diffraction, as well as nanohardness tests (hardness) were used. Measurements of wear resistance and corrosion resistance in NaCl, HCl and H_2SO_4 solutions were also performed. For testing mechanical properties such characteristics of layered structures as hardness H, elastic modulus E: H"3/E"2 etc. were measured. It is demonstrated that the formed ...
Multilayer mirror coatings which reflect extreme ultraviolet (EUV) radiation are a key enabling technology for EUV lithography. Mo/Si multilayers with reflectances of 67.5% at 13.4 nm are now routinely achieved and reflectances of 70 2% at 11.4 nm were obtained with MO/Be multilayers. High reflectance is achieved with careful control of substrate quality, layer thicknesses, multilayer materials, interface quality, and surface termination. Reflectance and film stress were found to be stable relative to the requirements for application to EUV lithography. The run-to-run reproducibility of the reflectance peak position was characterized to be better than 0.2%, providing the required wavelength matching among the seven multilayer-coated mirrors used in the present lithography system design. Uniformity of coating was improved to better than 0.5% across 150 mm diameter substrates. These improvements in EUV multilayer mirror ...
Non-evaporable thin film getters of various compositions have been produced by sputtering. Among about 20 materials which have been studied, the lowest activation temperature (about 180 degree C) has been displayed by a Ti-Zr-V coating obtained from a cathode made of intertwisted elemental wires. In order to optimize the vacuum properties of this film various production parameters, including the substrate temperature during coating, have been varied. The films have been characterized by pumping speed measurement, secondary electron microscopy, and X-ray diffraction. It has been found that the substrate coating temperature affects significantly the activation temperature, the pumping speed and the gas surface capacity. The highest pumping speed values, obtained for substrate coating temperatures of 250 degree C and 300 degree C, are clearly correlated with the increased surface roughness and porosity of ...
Infrared astronomical instruments require absorptive coatings on internal surfaces to trap scattered and stray photons. This is typically accomplished with any one of a number of black paints. Although inexpensive and simple to apply, paint has several disadvantages. Painted surfaces can be fragile, prone to shedding particles, and difficult to clean. Most importantly, the vacuum performance is poor. Recently a plasma enhanced chemical vapor deposition (PECVD) process was developed to apply thick (30 {micro}m) diamond-like carbon (DLC) based protective coatings to the interior of oil pipelines. These DLC coatings show much promise as an infrared black for an ultra high vacuum environment. The coatings are very robust with excellent cryogenic adhesion. Their total infrared reflectivity of < 10% at normal incidence approaches that of black paints. We measured outgas rates of <10{sup -12} ...
The properties of polycrystalline (Ti, Al)N coatings deposited on non-nitrided, classically plasma-nitrided and low pressure plasma-nitrided AISI H11 steel samples were investigated. The plasma deposition and low pressure plasma nitriding were performed in a Z700-LH magnetron sputter ion plating unit, while a separate unit was used for plasma nitriding of specimens at a pressure of several millibars. The (Ti, Al)N coating was deposited onto all the samples using the same equipment as for the plasma deposition and low pressure plasma nitriding. For the characterization of the composite structures, the following methods were used: scratch test, X-ray diffraction analysis, scanning electron microscopy, scanning tunnelling microscopy and microhardness testing. It was found that plasma nitriding prior to coating deposition strongly affects the growth and properties of hard coatings, such as the ...
Intermetallic compound (IMC) growth at the interface between a Sn coating and a Cu substrate with or without a Ni underlayer and its related stress state was evaluated by real-time measurements using the flexure beam method. For the Sn coating without a Ni underlayer, pyramid-shaped IMC grains of Cu6Sn5 grew along the grain boundaries of Sn from the Cu substrate, especially at the triple grain boundary junctions and the IMC grains rapidly increased their volume during the initial 3?days, During this time, the IMC growth rate was 2.3??m3/day and the compressive stress in the Sn coating rapidly developed and became saturated at about ?11?MPa. In contrast, platelet IMC grains of Ni3Sn4 formed at the surface of the Ni underlayer and the IMCs grew at a rate of 1.0??m3/day for the Sn/Ni coating....
A device for detecting neutrons includes a semi-insulated bulk semiconductor substrate having opposed polished surfaces. A blocking Schottky contact comprised of a series of metals such as Ti, Pt, Au, Ge, Pd, and Ni is formed on a first polished surface of the semiconductor substrate, while a low resistivity ("ohmic") contact comprised of metals such as Au, Ge, and Ni is formed on a second, opposed polished surface of the substrate. In one embodiment, n-type low resistivity pinout contacts comprised of an Au/Ge based eutectic alloy or multi-layered Pd/Ge/Ti/Au are also formed on the opposed polished surfaces and in contact with the Schottky and ohmic contacts. Disposed on the Schottky contact is a neutron reactive film, or coating, for detecting neutrons. The coating is comprised of a hydrogen rich polymer, such as a polyolefin or paraffin; lithium or lithium fluoride; or a heavy metal fissionable material. By varying the ...
Kitchen oils (olive, soybean and butter) are selected for carbon coatings on LiFePO{sub 4}. The surface properties of LiFePO{sub 4} are unknown or vary depending on synthetic methods. The multi-functional groups of fatty acids in the oils can orient properly to cope with the variable surface properties of LiFePO{sub 4}, which can lead to dense carbon coatings. The low price and low toxicity of kitchen oils are other advantages of the coating process. LiFePO{sub 4} (D{sub 50} = 121 nm)combined with the carbon coating enhances the rate capability. Capacities at the 2C rate reach 150 mAh g{sup -1} or higher. The charge retention values of 2.0C/0.2C are between 94.4 and 98.9%. (author)
Chromium containing amorphous hydrogenated carbon films (a-C : H/Cr) have been prepared by simultaneous rf plasma activated chemical vapour deposition of methane and magnetron sputtering of a chromium target. During deposition the substrates were heated (up to 300C) and DC biased (-200 and -600 V) in order to obtain films with high chemical stability. Constant temperature tests were performed at 250C in air with coatings deposited on silicon substrates. The degradation of the coatings was monitored by Raman spectroscopy and reflectance and transmission measurements. The main degradation mechanisms are discussed and the relevant parameters which improve the durability of the coatings are presented. Furthermore, the durability of solar selective, multilayered coatings which were deposited on copper sheets was investigated. Based on accelerated aging tests at different temperature loads in air (at 220C, ...
Direct visualization of rare earths in @a- and @b-SiAlON unit-cells is performed through Z-contrast imaging technique in an aberration-corrected scanning transmission electron microscope. The preferential occupation of Yb and Ce atoms in different interstitial locations of @b-SiAlON lattice is demonstrated, yielding higher solubility for Yb than Ce. The triangular-like host sites in @a-SiAlON unit cell accommodate more Ce atoms than hexagonal sites in @b-SiAlON. We think that our results will be applicable as guidelines for many kinds of rare-earth-doped materials.
The need for alternative energy increases steadily???especially due to the climate change and the limited availability of fossil fuels. Geothermal power uses the intrinsic heat which is stored in the accessible part of the Earth???s crust. Its importance among the renewable energy resources originates from the almost unlimited energy supply of the Earth and its independence from external influences such as seasonal or even daily climatic variability. Nevertheless, there are risks which have to be assessed. From a mathematical point of view there are four building blocks of the characterization of deep geothermal systems: seismic exploration, gravimetry, modeling transport processes, and modeling the stress field. In particular, local depletion poses a significant risk during the industrial...
'Glass Earth' represents a number of current and planned projects within CSIRO aimed at making 'transparent' the top 1000 m of the Earth's crust It builds upon current technologies developed within a number of CSIRO divisions as well as the Australian Mineral Exploration Technologies CRC (AMET CRC), the Australian Geodynamics CRC (AG CRC) and the CRC for Landscape Evolution and Mineral Exploration (CRC LEME). New geophysical and geochemical technologies will be developed to complement these, together with new capabilities in modelling, data integration and visualisation, including hydrogeochemistry, hydrogeology, surface geochemistry and isotope geochemistry, modelling of chemical, fluid and heat flows in rock and regolith, advanced visualisation and data fusion. This paper describes some recent work in the field of isotope geochemistry, with the principal aim of 'seeing through' cover to understand basement geology and detect hidden ore ...
The desire to study negative ion structure and negative ion-photon interactions has spurred the development of ion sources for use in research and industry. The many different types of negative ion sources available today differ in their characteristics and abilities to produce anions of various species. Thus the importance of choosing the correct type of negative ion source for a particular research or industrial application is clear. In this study, the results of an investigation on the production of beams composed of negatively-charged rare-earth ions from a cylindrical-cathode-geometry, cesium-sputter-type negative ion source are presented. Beams of atomic anions have been observed for most of the first-row rare-earth elements, with typical currents ranging from hundreds of picoamps to several nanoamps.
The paramagnetic susceptibilities of all the RCo_2 compounds for which measurements are available are found to obey a Curie-Weiss law consistent with the modified indirect exchange model. The rare-earth ions are in a well defined tripositive valence state. Paramagnetic moments and paramagnetic Curie temperatures are obtained for these materials for the first time. The paramagnetic moments of these materials are changed from their free-ion values by the effects of itinerant electron polarisation, an effect which is particularly large for SmCo_2 whose paramagnetic moment is almost three times greater than the free-ion value. The modified indirect exchange model is found to be able to give a full description of the magnitude of the rare-earth, cobalt and diffuse moments in polarised neutron experiments. The band structures of the light RCo_2 compounds are found to be distinctly different to those of the heavy RCo_2 compounds. (author).
A study has been made of the colour reaction involved in the interaction or rare-earth elements with the reagent orthanyl K, the optimum conditions for the reaction being: pH=4.0-4.5 and lambda=660-670 nm. The ratio of components in the complex is Me:R=1:2. Consideration of the relative optical density values of the complex solutions as a function of the serial number of the rare-earth elements made it possible to recommend orthanyl K as a selective reagent for determining La, Ce, Pr and Nb in a mixture of Tu, Yb, Lu and Y oxides. The molar extinction coefficients, the sensitivity of the reaction and the concentration limits where Beer's law applies were calculated. Lanthanum was determined in a binary mixture with thulium and yttrium. (author).
The object of this program was to design and build a self-contained system for remote monitoring of the atmosphere in mines. The system developed uses the mine pager phone line as the primary communication channel and also has the capability of using 208 Hz in the ELF band for wireless transmission through the earth. The depth for through-the-earth transmission is expected to be about 80 to 90 meters in high conductivity soil and is limited by the noise level in the ELF band-pass filters. The underground components of the TEM System are energized by mine power through a battery charger-storage battery power supply. In the event of mine power failure the battery capacity is more than sufficient for 1 week's operation with interrogations every 4 hours.
Spacecraft studies of the three terrestrial planets with atmospheres have made it possible to make meaningful comparisons that shed light on their common origin and divergent evolutionary paths. Early in their histories, all three apparently had oceans and extensive volcanism; Mars and Earth, at least, had magnetic fields, and Earth, at least, had life. All three currently have climates determined by energy balance relationships involving carbon dioxide, water and aerosols, regulated by solar energy deposition, atmospheric and ocean circulation, composition, and cloud physics and chemistry. This paper addresses the extent to which current knowledge allows us to explain the observed state of each planet, its planetology, climatology and biology, within a common framework. Areas of ignorance...
We present an empirical model for periodic variations of diurnal and sub-diurnal Earth rotation parameters (ERPs) that was derived based on the transformation of normal equation (NEQ) systems of Very Long Baseline Interferometry (VLBI) observing sessions. NEQ systems that contain highly resolved polar motion and UT1-TAI with a temporal resolution of 15?min were generated and then transformed to the coefficients of the tidal ERP model to be solved for. To investigate the quality of this model, comparisons with empirical models from the Global Positioning System (GPS), another VLBI model and the model adopted by the conventions of the International Earth Rotation and Reference Systems Service (IERS) were performed. The absolute coefficients of these models agree almost completely within 7.5?...
The use of polymer matrix composites in aerospace propulsion applications is currently limited by insufficient resistance to erosion by abrasive media. Erosion resistant coatings may provide necessary protection; however, adhesion to many high temperature polymer matrix composite (PMC) materials is poor. A low pressure oxygen plasma treatment process was developed to improve adhesion of CN_x coatings to a carbon reinforced, fluorinated polymer matrix composite. Fullerene-like CN_x was selected as an erosion resistant coating for its high hardness-to-elastic modulus ratio and elastic resilience which were expected to reduce erosion from media incident at different angles (normal or glancing) relative to the surface. In situ x-ray photoelectron spectroscopy was used to evaluate the effect of the plasma treatment on surface chemistry, and electron microscopy was used to identify changes in the surface morphology of the PMC ...
CeO{sub 2}-coated LiMn{sub 2}O{sub 4} spinel cathode was synthesized using two-step synthesis method. All the samples exhibited a pure cubic spinel structure without any impurities in the XRD patterns. The results of the electrochemical performances on CeO{sub 2}-coated electrode are compared to those of electrodes based on LiMn{sub 2}O{sub 4} spinel without CeO{sub 2} coating. CeO{sub 2}-coated LiMn{sub 2}O{sub 4} cathode improved the cycling stability of the electrode. The capacity retention of 2 wt% CeO{sub 2}-coated LiMn{sub 2}O{sub 4} was more than 82% after 150 cycles between 3.0 and 4.4 V at room temperature and 82% after 40 cycles at elevated temperature of 60 C. The amounts of dissolved manganese-ions in CeO{sub 2}-coated LiMn{sub 2}O{sub 4} significantly are smaller than pristine LiMn{sub 2}O{sub 4} systems especially at elevated temperatures. ...
We have investigated the growth behaviors of high temperature compatible ZrO_2 insulation coatings on Ag and AgMg sheathed Bi_2Sr_2Ca_1Cu_2O_x superconducting tapes depending on number of dipping and thermal conditions. The coatings were fabricated on long-length superconducting tape substrates using a solution derived from Zr tetrabutoxide, solvent and chelating agent for high magnetic field magnets. The layer-on-layer growth behaviors were characterized by environmental scanning electron microscope (ESEM), energy dispersive spectroscopy (EDS), X-ray maps and X-ray diffraction (XRD). This research showed that the ZrO_2 coatings were regularly grown on Ag-based tape substrates and coating thickness increased with increasing number of dipping. It was found that ceramic oxides formed at temperature range 450 and 550 deg. C. The final coating thickness changed between 6 and 8 #mu#m ...
The possibilities to electrodeposit thick coatings composed of nanoparticles of Sb and Sb{sub 2}O{sub 3} for use as high-capacity anode materials in Li-ion batteries have been investigated. It is demonstrated that the stability of the coatings depends on their Sb{sub 2}O{sub 3} concentrations as well as microstructure. The electrodeposition reactions in electrolytes with different pH and buffer capacities were studied using chronopotentiometry and electrochemical quartz crystal microbalance measurements. The obtained deposits, which were characterised with XRD and SEM, were also tested as anode materials in Li-ion batteries. The influence of the pH and buffer capacity of the deposition solution on the composition and particle size of the deposits were studied and it is concluded that depositions from a poorly buffered solution of antimony-tartrate give rise to good anode materials due to the inclusion of precipitated Sb{sub 2}O{sub 3} ...
As surface treated steel sheets, steel sheets with Zn-Fe coatings as well as double-layer steel sheets with Fe-P alloy coatings on Zn-Fe alloy coatings are often used practically. Two treatment methods, which are used to dissolve only alloy layers without dissolving steel sheets in order to find amount and composition of alloy layersr have already been reported. This report investigates the mechanisms of these methods, particularly the mechanisms to control dissolution of steel sheets. In the alkali-dissolution method, Zn-Fe alloy coatings are dissolved in a strong alkaline solution(NaOH-triethanolamine (TEA)-H{sub 2}O{sub 2}). In this case, steel sheets are insoluble because passive films are formed on the surface. In the cathodic polarization electrolysis method, alloy layers are electrolyzed({minus}l.2V) and dissolved in an ammonium nitrate-0-phen electrolyte. At this potential, dissolution of steel ...
Incoming solar energy had to be assimilated to sustain it. .... Roll stability was achieved with an Earth sensor mounted on the directional antenna. .... Once more a rocket becomes the means of producing a vector change in velocity. ...
Wildlife Monitoring System Schematic .......................... 40 ...... sentinel species - healthy fish are placed in an environment of water (where they arc not .... The way ir! which data for the fnre mdor study groups will be gathered tor managciacilt ...... Earth Resources Aircraft Program (ERAP) Camera ...
BackgroundDinoflagellates are unicellular, often photosynthetic protists that play a major role in the dynamics of the Earth's oceans and climate. Sequencing of dinoflagellate nuclear...Full Text Available
In this activity, students create two- and three-dimensional maps by using a data grid of an imaginary section of Earth's surface. They are challenged to create six different maps of various surface features and answer questions about them.
Dolores Beasley Headquarters, Washington, DC July 19, 2000 (Phone: 202/358- 1753) Bill Steigerwald Goddard Space Flight Center, Greenbelt, MD (Phone: ...
Oct 2, 2007 ... The Payload combines some of the most sensitive particle sensors .... provide state-of-the-art measurements of incoming x-ray, ultraviolet, .... It will be launched into a low-Earth orbit on a Delta 7320 rocket in September 2004. ...
BackgroundGeographic Information Systems (GIS) can provide valuable insight into patterns of human activity. Online spatial display applications, such as Google Earth, can democratise...Full Text Available
As the presence of humans in space expands in scope and duration, the quality of life in space as well as on Earth becomes pertinent. .... Military uses of space, such as the introduction of space-based laser or particle beam weapons, may have a major impact on the way people think and relate to .... AIAA Student Journal. ...
Types of disorders in the earth's surface as a result of open pit mining operations are analyzed. Trends for recultivation of lands are defined. Formulas are presented for calculating the economic expediency of the selected direction of recultivation.
More than 30 years ago, human beings looked back from the Moon to see the magnificent spectacle of Earth-rise. The technology that put us into space has since been used to assess the damage...Full Text Available
A procedure was developed to monitor boundaries within which secondary mining operations can be applied. Principal techniques include instrument and operative-remote observations of earth shifts and aerial photography of displacements on the surface of the trough.
ISS022, E, 8269, CHILE, OPEN PIT MINING OPERATIONS E. OF SIERRA GORDA, ROADS, DRAINAGE, -22.9, -69.1, 20091209. ISS022, E, 8270, CHILE, OPEN PIT MINING ...
The Earth`s troposphere and hydrosphere contain abundant naturally generated dust. The ultimate source materials from which the terrestrially produced dust is generated are the various rock types exposed at the Earth`s surface. Natural dust is a composite of (1) lithic, primary mineral grains; (2) mineral grains formed by secondary chemical reactions; (3) volcanic ash and dust; (4) salts from sea sprays; (5) extra-terrestrial dust; and (6) biologic materials. In this paper the various pathways to the natural generation of dust (via the hydrologic cycle) will be discussed, and two geologically well-known natural dust sources will be described, paying particular attention to quantitative measurements of the dusts from these areas. General dust studies that provide data on possibly global background levels will be presented as well.. A few general aspects of the mineralogical characterization of dust particles and a discussion of some of the ...
5 days ago... Sun sensors, 2 secondary Sun sensors, and an Earth sensor. ... This continued intermittently until the rocket burn, at which time ... with incoming asymptotic direction at an angle of -13.6 degrees from the lunar equator. ...
Instrumental neutron activation analysis (INAA) and radionuclide X-ray fluorescence analysis (RXFA) were used for the determination of rare earth elements. For INAA, solution obtained by sample decomposition was dripped onto filter paper, enclosed and sealed into a polyethylene foil. The sample was activated in reactor WWR-S over a period of 4 to 6 hours with a neutron fluence of 10"1"3cm"-"2. Gamma radiation measurement was carried out with a planar and a coaxial HP-Ge detector in three decay periods. La, Ce, Nd, Sm, Eu, Gd, Tb, Ho, Tm, Yb and Lu were determined. The advantage of the method is its accuracy and high sensitivity, the disadvantage is the time-consuming analysis. The RXFA method was used as a rapid and operative method for the analysis of loose ore samples, aqueous and organic solutions of rare earth elements. For exciting X-ray radiation, "2"4"1Am was used and the radiation of K-lines was detected with a planar Si(Li) detector. ...
Absorption and emission measurements at liquid-helium temperature, liquid-nitrogen temperature and room temperature have been performed on tetragonal scheelite-type rare earth sodium double molybdates Na[sub 5]RE(MoO[sub 4])[sub 4] and on RE-doped Na[sub 5]Gd(MoO[sub 4])[sub 4] samples. The rare earth occupies one single crystallographic position with S[sub 4] as point symmetry. The spectra were analysed according to the crystal field theory. From the experimental data, nearly complete energy level schemes of the Pr[sup 3+] and Nd[sup 3+], on the 4f [sup 2] and 4f [sup 3] configurations were derived. Very good correlation was obtained between the experimental and simulated energy level schemes, first for the approximated D[sub 2d] and then for the true S[sub 4] symmetries. The crystal field parameters vary smoothly with the atomic number of the rare earth, when compared with those determined previously for Eu[sup 3+] in the ...
Recent proposals have shown that a quantum degenerate gas of alkaline earth atoms can be used for a number of novel quantum computing and quantum simulation experiments. Strontium is a good candidate for such experiments because it can be controlled with high precision, as demonstrated in recent atomic clock experiments. Unfortunately, the small scattering length of strontium is not amenable to evaporative cooling techniques that are used to reach quantum degeneracy. Furthermore, increasing the scattering length of alkaline earths with a magnetic Feshbach resonance is not possible due to their spinless electronic ground state configuration. However, recent theoretical and experimental work suggests the possibility of changing scattering lengths in alkaline earths with laser light. Using this optical Feshbach resonance near strontium's narrow ^1S0->^3P1 intercombination transition might allow its scattering length to be ...
Apr 25, 2010... oil per day were leaking from an oil well in the Gulf of Mexico in late April, following an explosion at an offshore drilling rig on April 20, 2010. ...
BackgroundNematoda diverged from other animals between 600–1,200 million years ago and has become one of the most diverse animal phyla on earth. Most nematodes are free-living...Full Text Available
In 18 months the Canadian Medical Discoveries Fund (CMDF) has attracted investments worth $180 million to spend on biotechnology and medical research. Although eight initial investments totalled only...Full Text Available
BackgroundLake Tanganyika (LT) is the oldest of the African Rift Lakes and is one of the richest freshwater ecosystems on Earth, with high levels of faunal diversity and endemism....Full Text Available
An introduction to time-of-flight neutron spectroscopy is presented in the context of the study of magnetic materials. Examples are taken from the class of rare earth and actinide magnetic materials known as `strongly correlated electron` systems. (author) 11 figs., 24 refs.
Features: CHUQUICAMATA, LARGE OPEN PIT MINING OPERATIONS, ROADS, HILLS Center Point Latitude: -22.3 Center Point Longitude: -68.9 (Negative numbers indicate ...
Features: CHUQUICAMATA, LARGE OPEN PIT MINING OPERATIONS, ROADS, HILLS Center Point Latitude: -22.3 Center Point Longitude: -68.9 (Negative numbers indicate ...
From the gross conservation laws of thermodynamics in a convecting material we derive a bound on the ratio of the rate of production of mechanical or magnetic energy to the rate of internal radioactive...Full Text Available
It was thus actually the fourth stage of the rocket assembly. ... package, and several temperature sensors - was mounted in the cross-lattice frame. ... Earth's geomagnetic field and incoming charged particles from the Sun and extra-solar space. ...
retrieve detailed aerosol and cloud particle size distribution and shape ...... but on rain types, and hydrometeor characteristics. ..... of ice streams, decreasing sea ice cover in the Arctic, poleward movement of forest cover, and ...
... say for sure if the signal is coming from hail, lots of graupel, or some other hydrometeor . ... Precipitation forms when cloud droplets or ice particles in clouds grow and .... A landslide is the movement of rock, debris, or earth down a slope. ...
Sep 9, 2009... a French Ariane rocket successfully launched a new Earth-observing satellite ... The payload is a pair of identical sensors known as "high-resolution ... the resulting image) are activated simultaneously by incoming radiation; ...
... 03, 2001 | Rate It Lake Superior Streams http://www.lakesuperiorstreams.org/ (1 vote) interactively examine real-time water quality data from 5 ...north shore Lake Superior trout streams and learn about other streams in the region, how they \\
... In recent years workers in this field have focused on nucleation by nano-porous materials . This was in part motivated by a theoretical study by Page and Sear (2006) who proposed a two step model for nucleation in pores which suggest that there is ...
...October 2006 - present: University of Leeds, UK PhD Candidate in Geochemistry Thesis Title: Magnetite formation in reducing natural environments Supervisors: Dr Liane G. Benning ...Germany Bachelor of Science in Geosciences and Astrophysics Project Details Project Title: \\
One tiny marine plant makes life on Earth possible: phytoplankton. These microscopic photosynthetic drifters form the basis of the marine food web, they regulate carbon in the atmosphere, and are responsible for half of the photosynthesis that takes place on this planet.
BackgroundDengue fever is a mosquito-borne illness that places significant burden on tropical developing countries with unplanned urbanization. A surveillance system using Google...Full Text Available
The broad bands in the room-temperature excitation spectra of Sm"3"+-, Dy"3"+- and Tm"3"+-activated Ca-#alpha#-SiAlON phosphors are interpreted as the N"3"--to-rare earth charge transfer transition (CTT). From the energies of the charge transfer transitions and from the optical data presented for the Eu"2"+ ion, the location of the divalent rare earth ion energy levels relative to the valence and the conduction band of Ca-#alpha#-SiAlON is derived. The salient features of the energy-level diagram are shown to be practical in explaining the temperature-dependent variations of the Eu"2"+ and Yb"2"+ luminescence efficiency in Ca-#alpha#-SiAlON. A comparative study pertaining to the nature of the Yb"2"+ and Eu"2"+ ion luminescence in Ca-#alpha#-SiAlON and in SrSi_2O_2N_2 is presented. A tentative energy-level diagram of the trivalent rare earth ions in Ca-#alpha#-SiAlON is also constructed.
Investigations of psychrotrophic microorganisms have been limited even though the dominant environment of the Earth is cold and enzymes with high activities at low temperatures could have commercial...Full Text Available
is approximately 327000 km from the Earth's center (58000 km from the Moon's ...... source (figure 7-4). NEXT developed funding requirements for those ...... Code SF 2. 2101 NASA Rd. 1. Houston, TX 77058. Phone: (281) 483-7224 ...
ISS022, E, 8260, CHILE, CHUQUICAMATA, LARGE OPEN PIT MINING OPERATIONS, ROADS, HILLS, -22.3, -68.9, 20091209. ISS022, E, 8261, CHILE, CHUQUICAMATA, ...
Expedition 22 Commander Jeff Williams, aboard the International Space Station 220 miles above Earth, responds to questions posted on YouTube concerning the station's orientation, life in space and the recent butterfly experiment.
Sep 9, 2009 ... You are here: GES DISC Home Geomorphology from Space By Location Landforms by Location: Asia. Info. Landforms by Location: Asia. KEY, ASIA ...
Aluminium is an abundant metal consisting about 8 per cent of the earth's crust. It has long been considered as essentially nontoxic and nonabsorbable from the gastrointestinal tract. More recent studies have, however, due to better analytical capabilitie...
An ascending node occurs when the subsatellite point crosses the earth's equator going from .... 11dB sigma-naught. This error budget includes the altimeter noise, ...... it is also recommended to filter the data as follows to ...
Silica microspheres were deposited into two-dimensional periodic arrays and coated with a thin layer of silicon nanocrystals. The luminescence from the silicon nanocrystals coupled into the whispering gallery modes of the spheres, with Q factors that depended on a range of parameters including sphere size, position on the sphere, viewing direction, and thickness of the nanocrystal coating. Scattering from the film-sphere and/or the sphere-substrate contacts resulted in a lower Q for modes that intersect these regions. The highest Q factors obtained in this work were {approx}1500. The results suggest that silica microspheres may be promising candidates for high-Q cavities that incorporate silicon nanocrystals for cavity QED or nonlinear optical effects.
In this study, the effects of channel surface wettability, cross-sectional geometry and orientation on the two-phase flow in parallel gas channels of proton exchange membrane fuel cells (PEMFCs) are investigated. Ex situ experiments were conducted in flow channels with three different surface wettability (hydrophilically coated, uncoated, and hydrophobically coated), three cross-sectional geometries (rectangular, sinusoidal and trapezoidal), and two orientations (vertical and horizontal). Flow pattern map, individual channel flow variation due to maldistribution, pressure drop and flow visualization images were used to analyze the two-phase flow characteristics. It is found that hydrophilically coated gas channels are advantageous over uncoated or slightly hydrophobic channels regarding un...
Steel structures immersed in seawater are protected from corrosion using cathodic protection systems (sacrificial anodes or impressed current), by paint coatings or by duplex systems in which cathodic protection hinders corrosion at coating's failure sites. The main problem related to those duplex systems is how to avoid cathodic delamination due to the alkalinity generated at cathodic sites. The present paper analyses the effectiveness of red mud suspensions as pre-treatment to avoid cathodic delamination. The study was conducted using mainly electrochemical impedance spectroscopy (EIS). The evolution of the electrode potential with immersion time was also recorded because it concerns the practical aspect of current density necessary to reach the protection potential. The study shows that red mud pre-treatments are effective in avoiding coating's delamination. (author)
In order to improve the well-known short operational life time of BF3 counters, three potential adsorbents for impurity gases (graphite, activated charcoal and a zirconium-aluminum mixture) were introduced into BF3 counters in the form of coating on the aluminum cathode surface. Tests in el fields revealed that a partial coating of activated charcoal provides the best result. The improvement of their operational life in el fields was about three orders of magnitude in terms of tolerable exposure. Many counters with a partial coating of activated charcoal were further tested from the following viewpoints: background noise, vibration and shock, el pulse discrimination, operational life in a neutron field and non-operational in-reactor exposure life. The results were satisfactory for reactor control and protection usage. (author).
Anti-reflective coatings made with Teflon AF2400 had the highest damage thresholds recorded for physical vapor deposited coatings at the Lawrence Livermore National Laboratory damage facility. Physical vapor deposited layers of Teflon AF2400, a perfluorinated amorphous polymer, maintained the bulk optical properties of a high transmittance from 200 nm to 1600 nm, and a low refractive index. In addition, the refractive index can be intentionally reduced by control of two common deposition parameters, deposition rate and substrate temperature. Scanning electron microscopy and nuclear magnetic resonance observations indicated that morphological changes caused the variations in the refractive index rather than compositional changes. The coatings adhered to fused silica and silicon wafers under normal laboratory handling conditions.
The formation of a porous coating is the decisive feature for the bio-compatibility of silica-free calcium phosphate glass ceramics on alloy surfaces like the #beta#-Ti structured Ti-29Nb-13Ta-4.6Zr used in this work. The ceramic composition is highly important: 50CaO-40P_2O_5-7Na_2O-3TiO_2 glass powder produces a pore-free coating unable to bind hydroxyapatite, whereas 60CaO-30P_2O_5-7Na_2O-3TiO_2 glass incorporates pores from which a crystalline hydroxyapatite phase can grow over the surface from simulated body fluid (see Figure). (Abstract Copyright [2003], Wiley Periodicals, Inc.)
Full text: Institute for Nuclear Research, Pitesti-Mioveni, Romania in direct cooperation with the National Institute for Laser, Plasma and Radiation Physics, Magurele, Bucharest studied and prepared for coating more than 1000 tiles made of Inconel with 7-9 #mu#m of beryllium for nuclear fusion applications at JET, Culham, UK. The principles of manufacturing processes using thermal evaporation and plasma ignited in pure metal vapors as well as by Thermionic Vacuum Arc (TVA) method and the properties of the Ni and Be coatings are presented. The prepared beryllium layers were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and atomic force microscopy. (authors)
Apparatus for solid-phase antibody separation techniques used in radioimmunoassays is described in this invention. It consists of a rectangular prism tray with multiple wells protruding into its interior from one side. Near the base of the tray is an orifice used for creating evacuated condition within the structure. At the base of each well there is an orifice of such size and shape as to retain an aqueous liquid under given pressure conditions but permit the evacuation of this liquid at reduced pressure. The outlet of these orifices is in the shape of an inverted conical frustrum. Each of the wells contains an antibody coated disc of porous cellulose paper surrounded by a plastic support. The porous nature of the cellulose paper ensures contact between the antibody coating and the antigen. The use of antibody coated porous cellulose paper in combination with the vacuum operated apparatus simplifies the manipulative steps ...
Kawasaki Steel has constructed many facilities for 15 years to produce cold rolled products and galvanized products in Mizushima Works and Chiba Works. To efficiently and stably produce high and uniform quality products, various new control methods have been developed and applied to these new facilities. Especially, temperature control in a continuous annealing line, zinc coating control in a continuous galvanizing line or paint coating control in a multi-purpose coating line and tension control to achieve stable processing are the most advanced technologies and are introduced in this paper. (author)
In this study, a novel graphene nanosheets (GNSs) coated solid phase microextraction (SPME) fiber was prepared by immobilizing microwave synthesized GNSs on a stainless steel wire. Microwave synthesized GNSs were verified by X-ray diffraction, field emission-scanning electron microscopy (FE-SEM) and transmission electron microscope (TEM). GNS-SPME fiber was characterized using FE-SEM and the results showed the GNS coating was homogeneous, porous, and highly adherent to the surface of the stainless steel fiber. The performance and feasibility of the GNS-SPME fiber was evaluated under one-step microwave assisted (MA) headspace (HS) SPME followed by gas chromatography with electron capture detection for five organochlorine pesticides (OCPs) in aqueous samples. Parameters influencing the extra...
Rare-earth oxides are doped into ZnO varistors as grain growth inhibitors for increasing the varistors' voltage gradients. However, their leakage currents become large and their nonlinear coefficients decrease at the same time. The reasonable explanation for such a phenomenon has not yet been available. In this paper, the temperature dependences of varistor samples' leakage currents are investigated, which reveal that the increased leakage currents of ZnO varistors with Y2O3 doping are mainly due to the bypass paths through the intergranular materials at grain corners.
The luminescence spectra of trivalent europium ion embedded in various rare earth chromates were analysed. The spectroscopic data in most of chromates are in agreement with the structural determination but for some others the discrepancy between two methods is underlined. Energy level schemes were deducted from the experimental emission spectra and the crystal field simulation has been performed. The maximum splitting of the "7F_1 manifold of the Eu"3"+ ion as a function of N_v, the so-called crystal field strength parameter, is given. This allows us to classify the compounds according to their crystal field extent. (author)
This paper summarizes the establishment and current development of space activities in the Bolivarian Republic of Venezuela. Space activities in Venezuela are focused on the areas of telecommunications, Earth observation and research on the physical properties of the Earth, and have as a primary goal the satisfaction of social needs. Current development of space activities started in 1999 when the new National Constitution recognized the value of outer space as the common heritage of mankind, and the key role of science and technology in promoting human welfare. The Bolivarian Agency for Space Activities (ABAE) was created in 2007. Its legal framework recognizes three key elements that drive its policy: the participation of society, capacity building and human training, and international c...
The statistical {gamma}-spectra of highly excited even-even rare earth nuclei are simulated applying appropriate level density and strength function to a given nucleus. Hindrance effects due to K-conservation are taken into account. Simulations are compared to experimental data from the {sup 163}Dy({sup 3}He,{alpha}){sup 162}Dy and {sup 173}Yb({sup 3}He,{alpha}){sup 172}Yb reactions. The influence of the K quantum number at higher energies is discussed. 21 refs., 7 figs., 2 tabs.
When in resonance, Raman scattering exhibits strong enhancement ranging from four to six orders of magnitude. This physical phenomenon has been applied to remote sensing of the Earth`s atmosphere. With a 16 inch Cassegrain telescope and spectrometer/ CCD-detector system, 70-150 ppm-m of SO{sub 2} in the atmosphere has been detected at a distance of 0.5 kilometer. This system can be used to detect/monitor chemical effluence in the atmosphere by their unique Raman fingerprints. Experimental result together with detailed resonance Raman and atmospheric laser propagation effects will be discussed.
Radon is often used as a natural tracer for geochemical studies. In many cases radon interacts with water. The aim of this study is to assess the time required for radon to dissolve in water and reciprocally to degas from it, and to estimate the partition ratio between the two phases. A special setup has been devised and built for this purpose. Several experiments carried out with this equipment show that both dissolution and degassing are rapidly achieved phenomena. The qualitative consequence of these results in the field of Earth science are shortly discussed in the paper.
This patent describes a process for preparing poly(aryl ether ketones) by nucleophilic displacement polymerization in the presence of at least one alkali metal base selected from potassium, rubidium or cesium, and fluoride ions, which comprises adding to the polymerization: (a) an effective amount of at least one metal salt selected from lithium, sodium, alkaline earth or lanthanide chloride, bromide, iodide, sulfate, alkyl or aryl carboxylate, cyanide, borate or phosphate to slow or stop advancement of molecular weight and (b) an end-capping agent.
We discuss how magnetic phenomena affect superconductivity in simple metals, transition metals and alloys thereof, and dilute Rare-Earth alloys. It is shown both qualitatively and quantitatively that superconductors are sensitive probes for studying itinerant spin excitations, local spin excitations associated with nearly magnetic impurities, the effect of the atomic environment on the stability of local magnetic moments, and the nature of the spin order in Rare-Earth alloys. Also, we discuss how magnetic impurities can be used to study the electronic configuration which is responsible for superconductivity in Laves-phase crystals like A-15 compounds and ..beta..-W crystals, for example.
Protecting Earth and planets against the invasion of 'alien life forms' is not military science fiction, but it is the peaceful daily job of engineers and scientists of space agencies. 'Planetary Protection' is preventing microbial contamination of both the target planet and the Earth when sending robots on interplanetary space mission. It is important to preserve the 'natural' conditions of other planets and to not bring with robots 'earthly microbes' (forward contamination) when looking for 'spores of extra terrestrial life'. The Earth and its biosphere must be protected from potential extraterrestrial biological contamination when returning samples of other planets to the Earth (backward contamination). The NASA-Caltech Laboratory for Planetary Protection of Dr. Kasthuri Venkateswaran at the Jet Propulsion Laboratory (JPL) (California, USA) routinely monitors and characterizes ...
Climates at regional scale are strongly dependent on the interaction between atmosphere and its lower boundary, the oceans and the land surface mosaic. Land surfaces influence climate through their albedo, and the aerodynamic roughness, the processes of the biosphere and many soil hydrological properties; all these factors vary considerably geographically. Land surfaces receive a certain portion of the solar irradiance depending on the cloudiness, atmospheric transparency and surface albedo. Short-wave solar irradiance is the source of the heat energy exchange at the earth`s surface and also regulates many biological processes, e.g. photosynthesis. Methods for estimating solar irradiance, atmospheric transparency and surface albedo were reviewed during the course of this project. The solar energy at earth`s surface is consumed for heating the soil and the lower atmosphere. Where moisture is available, evaporation is one of the key components of ...
Oct 20, 1997 ... The following requirements apply to the solar array: ..... housings will be coated with material meeting the program's outgassing requirements. ... The solar array temperature testing requirements will be determined by analysis. .... The ADS also generates attitude products for the project and science team. ...
Synthetic oligoribonucleotides have been used to probe the interaction of MS2 coat protein with the translational operator of the MS2 replicase gene. We have investigated the possible formation of a...Full Text Available
In the present paper the tribological behavior of the coatings are discussed. Duplex coatings were applied on cold working steel 100Cr6. Samples were plasma nitrided at different thickness of plasma surface layers. TiN was deposited with a classic BALZERS PVD equipment and subsequent ion implantation. Ion implantation was provided with N{sup 5+} ions. The other samples were produced with IBAD technology in DANFYSIK chamber. Wear resistance and exchanges of friction coefficient were measured with on-line test using special designed tribology equipment. Following the tests, the wear zone morphology and characteristics of surface layer structure as well as important properties were investigated by scanning electron microscopy (SEM) and X-ray diffraction analysis (XRD). Scratch adhesion testing was performed using commercially available equipment. Energy dispersive X-ray analysis (EDAX) of the wear-scars on pins provided essential information on ...
Amperostatic coulometry was applied for the thickness measurement of Sn-Ag hot dip coatings, which comprise an extended Sn-Cu interdiffusion layer. Complementary measurements, notably weight loss, X-ray photoelectron spectroscopy, energy-dispersive X-ray spectroscopy, X-ray fluorescence (XRF), and dynamic secondary ion mass spectroscopy were performed in order to obtain a better interpretation of the coulometry results. Based on the experimental results presented in this article, the three potential changes observed during coulometry measurements are ascribed to (i) the entire dissolution of pure Sn, (ii) the formation of a CuCl salt layer, and (iii) the surface passivation. The measurement of the pure Sn mass is well reproducible despite strong coating thickness variations detected by XRF. Several experimental problems, in particular, a coating undercutting, hamper the determination of the Sn mass in the intermetallic ...
We tried to apply a quartz crystal as a sensor by using the resonant frequency and the resistance properties of quartz crystals. Four kinds of fatty acids that have the same head groups were coated on the surfaces of the quartz crystals, and the shift of the resonant frequency and the resistance were observed based on the lengths of the tail groups. Myristic acid (C{sub 14}), palmitic acid (C{sub 16}), stearic acid (C{sub 18}), and arachidic acid (C{sub 20}) were deposited on the surfaces of quartz crystals by using the Langmuir-Blodgett (LB) method. As a result, the resonant frequency change was more sensitive to high molecular-weight fatty acids than to low molecular-weight ones. We also observed the effect of temperature on stearic acid LB films, and the response properties of quartz crystals coated with stearic-acid LB films to organic gases were investigated. As a result, the sensitivity of quartz crystals to organic gases was higher for ...
This work showed the formation of phospholipid vesicle coating on inorganic sericite surface with characterization by combining electron microscopy of FE-SEM, TEM, AFM, and qualitatively evaluated the coated phospholipid vesicle by XPS as a function of etching time. The possibility of phospholipid vesicle mobility on the surface was restrained by the chelation effect of magnesium cation. The stabilization properties of phospholipid vesicles on sericite surface were demonstrated by the various concentration of magnesium cation. The presence of magnesium was found to have a much more pronounced influence on the lipid deposition process. The Mg cation plays an important role for attaching the phospholipids with optimum concentration of 7 mM. Totally, the phospholipid vesicles coating on inorganic powder could be useful for bio-related fields such as cosmetics and drug delivery system as the key functional compounds. We hope ...
In recent years, the interest in the use of bacteria for biological control of plant-pathogenic fungi has increased. We studied the possible side effects of coating barley seeds with the antagonistic...Full Text Available
Background.The air bubbles and foam that develop during the preparation of platelet units have traditionally been considered to interact with the platelets, causing activation and...Full Text Available
An immunoassay employing 125I-labeled enterotoxin B and polystyrene tubes coated with specific antibody was used for assaying purified and crude enterotoxin. Antibody was adsorbed to untreated...Full Text Available
An antigen-antibody system of polystyrene tubes coated with immunoglobulin antibody was used for quantitating immunoglobulins. A similar radioimmunoassay method was adapted for a viral antigen-antibody...Full Text Available
Enzymes are versatile catalysts in laboratories and on an industrial scale; improving their immobilization would be beneficial to broadening their applicability and ensuring their (re)use. Lipid-coated...Full Text Available
This work analyzes the unoptimized prototype triode-sputtered, 150 microns thick tantalum coatings deposited with a 2.5 microns niobium underlayer on the bore of a large-diameter A723 steel cylinder. The coating was deposited for wear and erosion protection by Pacific Northwest National Laboratory. The phase determination was based on X ray diffraction analysis, wavelength dispersive X ray fluorescence analysis, energy dispersive X ray analysis, and hardness and electrical resistivity measurements. Both X ray diffraction and radius-of- curvature methods were used to determine residual stresses. A locally developed high-resolution pole figure technique was used to perform texture analysis. The post-firing, debonded coating showed alpha-tantalum, preferred 110 orientation, high surface stresses, tantalum oxides, entrapped krypton sputtering gas, interstitial oxygen, and other impurities. The surface and subsurface pole ...
A major problem in the maintenance and rehabilitation of pipelines is the removal of the original coating system, particularly in cases where the coating contains sticky components or adhesives. It has been found that such coatings can be removed by use of a cleaning machine with a plurality of counter-rotating carbide-tipped tools mounted to an oscillating head embracing the pipe, and which is operable at the same time to travel along the length of the pipe. Such a machine can be designed to effect a positive, gentle milling operation on the pipe surface to remove the coating efficiently and at relatively low power consumption. A particular advantage of the pipe cleaning machine of the invention is that its design and manner of operation allows it to be used in the field to clean an uncovered section of pipeline, for example a natural gas pipeline, without the requirement of removing the pipeline ...
As a result of health and safety issues surrounding the use of radioactive materials on coated optical components, there has been renewed interest in coating materials whose optical and mechanical properties approach those offered by their radioactive counterparts. Due to the radioactive nature of ThF{sub 4} and its widespread use in optical coatings, the coating industry is examining other low index and non-radioactive fluorides as possible alternatives. In this paper, the authors present the results of an experimental study on the optical and mechanical properties of thermally evaporated ThF{sub 4}, DyF{sub 3}, CeF{sub 3}, LiF, HfF{sub 4}, IRX, and IRB thin films, where the materials were deposited at different substrate temperatures. The objective is to examine this series of fluorides under comparable deposition conditions and with respect to such material properties as: n and k, film stress, and ...
Progress is reported in fabrication and coating activities being conducted for the weapons program, nuclear test program, nuclear design program, magnetic fusion program, and miscellaneous applications. (DLC)
A latex agglutination (LA) test was evaluated for the detection of human rotaviruses in stool specimens. Both antiserum and immunoglobulin G (IgG)-sensitized latex particles were used, with IgG-coated...Full Text Available
In this paper, we present experimentally determined reflection factors of mirrors based on the depleted uranium and dependence of reflection factor on time of presence of samples on air.
The display of proteins such as feed enzymes at the surface of bacterial spore systems has a great potential use for animal feed. Feed enzymes increase the digestibility of nutrients, leading to greater...Full Text Available
Magnetic particles (MAG*SEP"S"M) coated with various absorbents were evaluated for the separation and recovery of low concentrations of cesium from nuclear waste solutions. The MAG*SEP"S"M particles were coated with (1) clinoptilolite, (2) transylvanian volcanic tuff, (3) resorcinol formaldehyde, and (4) crystalline silico-titanate, and then were contacted with a Hanford supernatant simulant. Particles coated with the crystalline silico-titanate were identified by Bradtec as having the highest capacity for cesium removal under the conditions tested (variation of pH, ionic strength, cesium concentration, and absorbent/solution ratio). The MAG*SEP"S"M particles coated with resorcinol formaldehyde had high distribution ratios values and could also be used to remove cesium from Hanford supernant simulant. Gamma irradiation studies were performed on the MAG*SEP"S"M particles with a gamma dose equivalent to ...
In support of a new clinical trial designed to compare the effects of crushed fresh garlic and two types of garlic supplement tablets (enteric-coated dried fresh garlic and dried aged garlic...Full Text Available
A solid-phase radioimmunoassay employing 125I-labeled enterotoxins and polystyrene tubes coated with specific antibody has been developed for assaying the relative concentrations of antibodies...Full Text Available
This paper reports that the co-deposition of chromium and silicon into a 2.25Cr-1.0Mo-0.15C steel, alloy 800, and type 304 stainless steel has been achieved using the pack cementation process. The ferritic coating produced on the 2.25 Cr-1.0Mo steel was approximately 225 {mu}m (9 mils) thick, whereas the inward diffusion of chromium and silicon produced a two-phase structure of ferrite and austenite for type 304. Chromium and silicon were incorporated into the austenitic solid solution upon diffusion into alloy 800. All coatings had approximately 25 to 35 wt% Cr and 2 to 3% Si at the surface. Cyclic oxidation testing in air of the coated 2.25Cr-1.0Mo steel (T = 700{degrees} C) and type 304 (T = 1035{degrees} C) showed a dramatic decrease in the oxidation kinetics compared to the original uncoated alloys. The cyclic oxidation of alloy 800 was also improved.
Effects of dopant and coating carbon nanotube on anodic performance of Si were studied for metallic anode Li ion rechargeable battery with large capacity. Although the large Li intercalation capacity higher than 1500mAhg{sup -1} is exhibited on pure Si, it decreased drastically with increasing cycle number. Increasing the electrical conductivity by doping Cr or B is effective for increasing the initial capacity and the cycle stability of Si for Li intercalation. Coating semiconductive Si with the carbon nanotube by decomposition of hydrocarbon is effective for increasing the cycle stability, though the initial Li intercalation capacity slightly decreased. Conducting binder is also important for increasing the cycle stability and it was found that Li intercalation capacity higher than 1500mAhg{sup -1} can be sustained by using poly vinyliden fruolide. Consequently, reversible Li intercalation capacity of 1500mAhg{sup -1} was successfully ...
To maximize energy efficiency, gas turbine engines used in airplanes and for power generation operate at very high temperatures, even above the melting point of the metal alloys from which they are...Full Text Available
Strippable or temporary coatings are innovative technologies for decontamination that effectively reduce loose contamination at low cost. These coatings have become a viable option during the deactivation and decommissioning of both US Department of Energy (DOE) and commercial nuclear facilities to remove or fix loose contamination on both vertical and horizontal surfaces. The ALARA{trademark} 1146 strippable coating was demonstrated as part of the Savannah River Site LSDDP and successfully removed transferable (surface) contamination from multiple surfaces (metal and concrete) with an average decontamination factor for alpha contamination of 6.68 and an average percentage of alpha contamination removed of 85.0%. Beta contamination removed was an average DF of 5.55 and an average percentage removed of 82.0%. This paper is an Innovative Technology Summary Report designed to provide potential users with the information they ...
Extra-fine powdered activated charcoal has been used as stationary phase (coating layer) in solid-phase microextraction (SPME). The efficiency and reliability of the prepared device have been investigated for the extraction of some volatile organic compounds such as benzene, toluene, ethylbenzene and xylene isomers (BTEX) from the headspace of water samples. Monitoring of the extracted compounds and further quantitative analysis of the real samples have been performed by capillary GC-FID. Effects of several factors such as temperature, addition of salt, and stirring speed on extraction efficiency and exposure time have been studied. Under optimum conditions, extraction recoveries for these compounds from 50 mL water were >95%. The calibration graphs were linear in the range 5 to 10{sup 4} pg mL{sup -1} and the detection limit for each BTEX compound was 1.5-2 pg mL{sup -1}. The results obtained by use of this porous layer activated charcoal ...
DNA antoantibodies in serum will bind to antigen-coated polystyrene tubes and can be detected by radiolabelled anti-immunoglobulin. The method is quantitative, gives information on the antibody class...Full Text Available
Deposition of hard coatings may influence the mechanical properties of the bulk material and its corrosion resistance. In this work we study the hardness of the coated and the back side of 100Cr6 steel plates. Electrochemical corrosion tests were performed in O{sub 2}-saturated acetate buffer of pH 5.6 at 25degC. Chromium nitride and titanium nitride coatings prepared by different physical vapour deposition processes, such as arc, thermionic arc evaporation, magnetron sputtering and ion-beam-assisted deposition (IBAD) were compared. The results show that, for sufficient corrosion protection, chromium nitride layers have to be thicker than 500 nm. An increased nitrogen partial pressure in the evaporation chamber of the IBAD process improves the corrosion resistance significantly. The hardness of the substrates was reduced in the case of thermoionic arc evaporation only, indicating a deposition temperature of more than ...
Certain applications are described of radionuclide X-ray fluorescence analysis in the ore dressing industry, in the manufacture of building materials, in metallurgy, pharmacy, in the chemical, photographic and paper industries, in space exploration, in archeology and for measuring the thicknesses of thin layers of coatings. (ES).
Laser surface alloying with gaseous nitrogen was utilized to improve the wear resistance of a Ti-6Al-4V alloy. Wear-resistant composite coatings reinforced by hard TiN dendrites were produced 'in-situ' on a substrate of a Ti-6Al-4V alloy. The hardness and wear resistance of the laser alloyed coating under two-body abrasive and block-on-ring full-sliding wear conditions were significantly enhanced. (orig.)
A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.))
A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.)).
In fluid bed processing in the chemical, food or pharmaceutical industries, pneumatic nozzles are typically used to convert binder or coating liquids into droplets. Producing fine droplets from liquids in a gas phase is termed atomisation, and it involves complex phenomena which are not yet fully understood. This paper provides a systematic and up-to-date review of two-fluid nozzle designs and principles together with a presentation of nozzle fundamentals introducing basic nozzle theory and thermodynamics. Correlations for the prediction of mean droplet diameters are reviewed, compared and accompanied by a discussion of their use.
The performance of a thermophotovoltaic (TPV) converter for solar energy is compared with that of direct solar energy conversion by silicon and germanium solar cells. The optical selectivity of an intermediate emitter is computed. Experimental results on selective emission, based on selectively emitting materials and on antireflection coatings on metals, are reported. For a TPV converter equipped with silicon solar cells, no selective emitter is found to yield better results than would be obtained by direct conversion. A TPV converter with germanium cells operating with a ThO/sub 2/-coated tungsten emitter, however, may achieve a conversion efficiency superior to that of direct solar energy conversion by either silicon or germanium solar cells.
The bibliography contains citations concerning plasma immersion ion implantation (PIII) and equipment. PIII is a new technique to implant plasma ions into materials for surface modification and treatment. Topics include plasma nitriding, semiconductor doping, ion energy distribution, ion dose, pulsed plasma, metal plasma, and defect passivation. References also review applications in semiconductor device and integrated circuit manufacture, silicon material fabrication, aerospace bearings, carbon coatings on metals, and ceramic coatings. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)
In this paper, an environmentally friendly metal corrosion inhibitor, phytic acid, was assembled into the walls of silica nanoparticles via layer-by-layer self-assembly technique (LbL) with poly(allylamine hydrochloride). Such functionalized nanoparticles were uniformly distributed into sol-gel films for metal anticorrosion. The films showed very pronounced and lasting protective efficiency in concentrated salt aqueous solutions as indicated by electrochemical impedance spectroscopy (EIS) measurement. These results may provide a new route for the preparation of environment-friendly anticorrosion coatings.
The principle is described of a method using low-activity emitters as the primary radiation source for analysis. The selection of the radiation source and the detection methods including the assessment of the applicability of various radiation detectors are discussed. The benefits and the constraints of the method are considered. Practical examples are presented showing the application possibilities of the method for testing the thickness of bearing layers, piston ring coats, lead layers, etc. The possibility is shown of applying the rapid test for the composition of tungsten and chromium alloyed metal materials in testing complex systems. (J.K.).
In the early 1970s Yang and Menichelli demonstrated that direct laser illumination of low-density secondary explosive prr:ssings through a transparent window could produce detonation. 'The energy requirement for threshold initiation of detonation was reduced when a thin metal coating of metal covered the side of the window against which the low-density explosive was pressed. We have obtained experimental results that are in general agreement with the results of Renllund, Stanton and Trott (1 989) and recent: work by Nagayama, hou and Nakahara (2001). We report exploration of the effects of laser beam diameter, PEiTN density and specific surface area, and thickness of a titanium coating on the window.
In this study samples of AISI 4140 steel were pretreated by plasma nitriding and coated with two different physical vapour deposited coatings (TiN and TiAlN). A hardened AISI 4140 sample and a coated sample were also included in the investigation. To examine the influence of the nitrided zone on the performance of the coating-substrate composite, two different nitriding conditions - a conventional 25% N{sub 2} and an N{sub 2}-poor gas mixture - were used. The specimens were investigated with respect to their microhardness, surface roughness, scratch adhesion and dry sliding wear resistance. Wear tests in which the duplex-treated pins were mated to hardened ball bearing steel discs were performed in a pin-on-disc machine under dry sliding conditions. Metallography, scanning electron microscopy and profilometry were used to analyse the worn surfaces in order to determine the dominant friction and wear ...
The interdiffusion behaviour of MCrAlY-coats on polycrystalline and single-crystalline materials of a similar composition (IN 738 LC/SC 16)shows similar interdiffusion characteristics. TCF-tests, where stress is generated by temperature and sample geometry at the edges of a disk-shaped sample, show that it is possible to differentiate betwee crack resistance of coated and uncoated samples. This method is also suitable for screening tests with different coat thicknesses. Coating of the edge area must, however, be done with great diligence in order to prevent coat thickness variation as results would then not be reproducable. Contrary to TCF (thermal cycle fatigue) TMF-tests (thermal mechanical fatigue)allow to set the stress states that one wishes to test. This method is therefore well suited for testing under operating conditions.(orig.) [German] Im Rahmen dieser Arbeit wurde ...
In support of the efforts to apply ceramics in advanced heat engines, a study was made of the sliding performance of ceramics at the ring/cylinder interface of low heat rejection engines. The objective was to understand the basic mechanisms controlling the wear of candidate ceramics and thereby identify means for applying these ceramics effectively. Attempts to operate three different zirconias, silicon carbide, silicon nitride, and several plasma-sprayed ceramic coatings without lubrication were unsuccessful because of high friction and high wear rates. Experiments using a polyalphaolefin lubricant at temperatures to 260 C identified several combinations having wear rates in the general range likely to be acceptable for engines. Plasma-sprayed coatings of chromium oxide and hypersonic powder flame sprayed coatings of cobalt-bonded tungsten carbide performed particularly well as ring coatings. Similar ...
After being pre-plated a zinc layer, an amorphous Al-Mn alloy coating was applied onto the surface of AZ31B magnesium alloy with a bath of molten salts. Then the corrosion performance of the coated magnesium alloy was examined in 3.5% NaCl solution by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results showed that the single Zn layer was active in the test solution with a high corrosion rate while the Al-Mn alloy coating could effectively protect AZ31B magnesium alloy from corrosion in the solution. The high corrosion resistance of Al-Mn alloy coating was ascribed to an intact and stable passive film formed on the coating. The performances of the passive film on Al-Mn alloy were further investigated by Mott-Schottky curve and X-ray photoelectron spectroscopy (XPS) analysis. It was confirmed that the passive film exhibited n-type semiconducting ...
Wear-resistant TiN coatings deposited on tool steels are used frequently in industry. There is a trend towards further optimizing these coatings, e.g. by plasma nitriding the tool surface prior to TiN deposition. In this work the influence of the nitriding conditions on the surface properties of AISI 304 and ASP 23 tool steels was investigated. The plasma nitriding was carried out in a triode ion plating configuration normally used to deposit TiN coatings. At the surface of AISI 304 stainless steel, only a thin compound layer (Fe{sub 4}N, Fe{sub 3}N) was found, probably as a consequence of the rather slow nitrogen diffusion in the austenite matrix. For ASP 23 high speed steel, the different nitriding behaviour of the martensitic matrix causes the formation of a diffusion layer which results in an increase in hardness at the surface. On an analogous set of specimens the TiN deposition was started immediately after the plasma ...
Natural bone consists of hard nanostructured hydroxyapatite (HA) in a nanostructured protein-based soft hydrogel template (ie, mostly collagen). For this reason, nanostructured HA has been an intriguing coating material on traditionally used titanium for improving orthopedic applications. In addition, helical rosette nanotubes (HRNs), newly developed materials which form through the self-assembly process of DNA base pair building blocks in body solutions, are soft nanotubes with a helical architecture that mimics natural collagen. Thus, the objective of this in vitro study was for the first time to combine the promising attributes of HRNs and nanocrystalline HA on titanium and assess osteoblast (bone-forming cell) functions. Different sizes of nanocrystalline HA were synthesized in this study through a wet chemical precipitation process following either hydrothermal treatment or sintering. Transmission electron microscopy images showed that HRNs aligned with ...
Based on results from recent studies of elemental dietary intake and organ or tissue content for adult Chinese men, quoted nationwide elemental concentrations in Chinese soil and newly published national average consumption of dietary foods, values of both transfer coefficients and discrimination factor (DF) for transfer from soil via the diet to both critical organs and the whole body have been calculated for important elements in radiation protection, including alkaline earths, alkali metals, rare earths and other related elements. These calculations have used both the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) model and the DF method. In the UNSCEAR model, the basic parameters used to describe the transport of radionuclides are the transfer coefficients P_i_j, which describe the relationship of concentrations or other amounts between compartment i and the following compartment j, whereas the DF is the ...
Earth`s history has been witness to recurrently alternating phases of catastrophic evolution and dominant tectonic deformations, contractions and extension of rifting and spreading leading to quasi-cyclic changes in sedimentary environment and various earth processes. Recent studies have shown quasi-periodicities of 32{+-}2 Million years (Myr) in various endogenic (geomagnetic reversals, magmatic events, mantle convection, various tectonic activities, climate change and biological extinctions) and exogenic (impact catering) processes indicating a remarkable kinship. A time series analysis is presented of the available CO{sub 2} record over the past 250 Myr decoded from global CaCO{sub 3} accumulation rates in sedimentary environment. The time series analysis reveals an intriguing evidence of a dominant periodicity of 33{+-}2 Myr which matches closely with a `common catastrophic periodicity` of 32 Myr identified in various terrestrial and ...
We investigate the influence of lunar-like satellites on the infrared orbital light curves of Earth-analog extra-solar planets. Such light curves will be obtained by NASA's Terrestrial Planet Finder (TPF) and ESA's Darwin missions as a consequence of repeat observations to confirm the companion status of a putative planet. We use an energy balance model to calculate disk-averaged infrared (bolometric) fluxes from planet-satellite systems over a full orbital period (one year). The satellites are assumed to lack an atmosphere, have a low thermal inertia like that of the Moon and span a range of plausible radii. The planets are assumed to have thermal and orbital properties that mimic those of the Earth while their obliquities and orbital longitudes of inferior conjunction remain free parameters. Even if the gross thermal properties of the planet can be independently constrained (e.g. via spectroscopy or visible-wavelength detection of specular ...
Silicon nitride-based ceramics behavior is strongly influenced by microstructural parameters, which, in turn are determined by chosen densification method. Highly covalent Si-N bond hind are the silicon nitride densification. Therefore, metal oxides are used in order to get high density. However, such oxides must be carefully selected, because they affect the general macroscopic properties of sintered bodies. In the present work, the viability of rare earth concentrate use to produce #beta#--Si_6_-_xAl_xO_xN_8_-_x and its effect on mechanical properties of the sintering ceramics are studied. Additive composition, heating rate, soaking time and sintering temperature were took as variables. Hardness, fracture toughness, Young's modulus and flexural strength were investigated. Lattice parameter compositional dependence and secondary phases crystallized after past-sintering heat treatment were also determined. The results show that rare earth ...
Hard X-ray/gamma-ray spectrometers aboard two interplanetary spacecraft, Ulysses and Pioneer Venus Orbiter (PVO), and two near-Earth spacecraft, Yohkoh and Compton Gamma Ray Observatory (GRO/BATSE), are currently in operation. A unique set of circumstances have permitted the observation of the 15 November 1991 (2238 UT) flare by all the four instruments. This intense flare (GOES class X 1.5) was associated with the bright (3B) H-alpha flare located on the disk (S13, W19) in the active region 6919. At the time of the flare, the Ulysses and PVO spacecraft were located respectively 101[degree] and 52[degree] west of the Sun-Earth line. Thus the view angles for the PVO and Ulysses instruments were quite different from those of the near-Earth instruments on GRO and Yohkoh. The preliminary photon energy spectra observed by the four instruments at different times during the flare will be presented and their implications regarding ...
In this paper, we first calculate the realistic Earth matter effects on the detection of type II supernova neutrinos at the Daya Bay reactor neutrino experiment which is currently under construction. It is found that the Earth matter effects depend on the neutrino incident angle \\theta, the neutrino mass hierarchy \\Delta m_{31}^{2}, the crossing probability at the high resonance region inside the supernova, P_H, the neutrino temperature, T_{\\alpha}, and the pinching parameter in the neutrino spectrum, \\eta_{\\alpha}. We give the expression for the dependence of P_H on the neutrino mixing angle \\theta_{13}. With this we obtain the relations between \\theta_{13} and the event numbers for various reaction channels of supernova neutrinos. Using these relations, we propose a possible way to measure \\theta_{13} smaller than 1.5^\\circ. Such a sensitivity cannot be achieved by the Daya Bay neutrino experiment (the sensitivity of the Daya Bay ...
Since living things began their activities on the earth, the extermination of living things in large number on global scale occurred twice 230 million years ago (P-Tr boundary) and 65 million years ago (K-T boundary). As to the cause of exterminating living things in short period, there are volcano eruption theory, meteorite collision theory and so on, but still it is not decided. Therefore, as to the strata of P-Tr boundary in south-western part of China where it has been known the preservation of P-Tr strata is especially good, the existence of elements was measured by instrument neutron activation analysis and ICP-MS, and the state of change was examined. According to the results, the change occurred at the P-Tr boundary on the earth, and further, the possibility of meteorite collision by paying attention to Ir were examined. The samples, the neutron activation analysis, the ICP-MS and the results are reported. The distinction by strata and ...
We have begun the ExploreNEOs project in which we observe some 700 Near-Earth Objects (NEOs) at 3.6 and 4.5 ?m with the Spitzer Space Telescope in its Warm Spitzer mode. From these measurements and catalog optical photometry we derive albedos and diameters of the observed targets. The overall goal of our ExploreNEOs program is to study the history of near-Earth space by deriving the physical properties of a large number of NEOs. In this paper, we describe both the scientific and technical construction of our ExploreNEOs program. We present our observational, photometric, and thermal modeling techniques. We present results from the first 101 targets observed in this program. We find that the distribution of albedos in this first sample is quite broad, probably indicating a wide range of compositions within the NEO population. Many objects smaller than 1 km have high albedos (?>0.35), but few objects larger than 1 km have high albedos. This ...
The collision of the Earth with extra-terrestrial ice-volatile bodies is proposed as a mechanism to produce rapid changes in the geologic record. These bodies would be analogs of the ice satellites found for the Jovian planets and suspected for comets and certain low density bodies in the Asteroid belt. Five generic end-members are postulated: (1) water ice; (2) dry ice: carbon-carbon dioxide rich, (3) oceanic (chloride) ice; (4) sulfur-rich ice; (5) ammonia hydrate-rich ice; and (6) clathrate: methane-rich ice. Due to the volatile nature of these bodies, evidence for their impact with the Earth would be subtle and probably best reflected geochemically or in the fossil record. Actual boloids impacting the Earth may have a variable composition, generally some admixture with water ice. However for discussion purposes, only the effects of a dominant component will be treated. The general geological effects of such collisions, ...
A low pressure nuclear thermal rocket (LPNTR) is configured to meet the requirements of a nuclear stage for manned Mars exploration. Safety, reliability and performance are given equal consideration in selecting the stage configuration. Preliminary trade studies are conducted to size the engine thrust and determine the thrust chamber pressure. A weight breakdown and mechanical configuration for the selected LPNTR concept are defined. A seven engine stage configuration is selected which gives a two engine out capability and eliminates the need for engine gimbaling. The stage can be ground assembled and launched as a unit including tankage for trans Earth injection and Earth orbital capture. The tankage is configured to eliminate the need for an inert shield. The small engine will be cheaper to develop than a single engine providing full thrust, and will be compatible with stages for Earth orbital, Lunar and deep space ...
The thermal stability of low-friction Me-C/a-C:H coatings is important for their potential applications in the tool and automotive industry. Recently we showed that CrC _x/a-C:H coatings prepared by unbalanced magnetron sputtering of a Cr target in Ar + CH_4 glow discharges exhibit a nanocomposite structure where metastable fcc CrC nanocrystals are encapsulated by an a-C:H phase. Here, we present the structural evolution of these nanocomposite CrC/a-C:H coatings during annealing. High-temperature X-ray diffraction in vacuum and differential scanning calorimetry (DSC) combined with thermo-gravimetric analysis in Ar atmosphere indicate decomposition of the formed metastable fcc CrC phase and subsequent formation of Cr_3C_2 and Cr_7C_3 and structural transformation of the a-C:H matrix phase towards higher sp"2 bonding contents at temperatures above 450 deg. C. Combined DSC and mass spectrometer analysis as well as elemental ...
Suspension direct current plasma spraying allows achieving finely structured coatings whose thickness is between few tens and few hundreds of micrometres. Drops (200-300 ?m in diameter) or liquid jets are mechanically injected in the plasma jet. With radial injection they are rapidly (a few ?s) fragmented into droplets (a few ?m in diameter). The latter are vaporized (in a few ?s) and the solid particles contained in suspension droplets are accelerated and melted by the plasma jet. As in conventional plasma spraying (CPS), much smaller splats (with diameters between 0.2 and 3 ?m and thicknesses between 30 and 200 nm) are arranged in layers up to form the coating. The low inertia of particles requires spray distances between 40 and 60 mm which induces plasma heat fluxes up to 22 MW m-2 participating in coating densification. Even more than in CPS, the plasma jet fluctuations, particularly for plasmas containing di-atomic ...
Full text of publication follows: As SiCf/SiC composites are very low activation materials, their use as structural material for the reactor blanket and first wall components appears essential to demonstrate the potential of D-T fusion power reactor. Positive features of SiCf/SiC are their high performances at elevated operating temperature and the ability to produce a specific component. Critical issues of SiCf/SiC are the mechanical properties, radiation stability and, with regard to technological issues, their hermeticity and joining processes. Improvement of joining processes for SiC/SiC components is also needed. Recently, several blanket designs have been studied: the TAURO blanket concept in the European Union, the ARIESAT concept in the US and the DREAM concept in Japan. In those reactors, hermetic SiCf/SiC or self-sealing coatings are mandatory. The basic idea of self sealing concept is to manufacture a coating with specific ...
The HT-28 and 29 irradiation capsules are part of a cooperative agreement between GA and ORNL designed to evaluate irradiation performance of unbonded BISO and TRISO coated ThO_2 fertile fuel particles. The capsules will contain a total of 44 different positions uniformly divided between each capsule. The positions in HT-29 are designated for operation at 900"0C over a fast fluence increment between 5.4 to 10.7 x 10"2"1 n/cm"2 (E > 0.18 MeV)/sub HFIR/. Positions in HT-28 are divided into two sections: 11 positions at 1250"0C to receive a fast fluence exposure between 7.8 and 8.6 x 10"2"1 n/cm"2 (E > 0.18 MeV)/sub HFIR/ and 11 positions at 900"0C designed for a 4.3 to 6.9 x 10"2"1 n/cm"2 (E > 0.18 MeV)/sub HFIR/ fast fluence exposure. Both capsuls are to serve as an evaluation test to characterize the performance of BISO OPyC coatings deposited from mixed-gas (acetylene-propylene). The OPyC variables tested will be density, ...
The surface of low alloy steel (En40B) has been engineered in the plasma of a glow discharge via plasma nitriding and ion plating of titanium nitride (TiN) coatings on the nitrided substrates with the purpose of enhancing the surface properties and fatigue strength. The nitriding response of the steel has been accessed by the evaluation of phase composition, layer thickness, hardness profile, residual stresses and nitrogen and carbon distributions. The wear and fatigue characteristics of the plasma-nitrided steel have been investigated and simple models have been developed to describe the influence of such properties as depth and strength of the nitrided case on the fatigue limit and load-bearing capacity of the nitrided steel. In order to further improve the tribological properties and load-bearing capacity of the low alloy steel, a duplex plasma surface-engineering technique has been developed. This is achieved by plasma nitriding the steel first so as to produce ...
The particle surface of Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} was modified by AlF{sub 3} as a new coating material to improve the electrochemical properties in the high cutoff voltage of 4.5 V. The AlF{sub 3}-coated Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} showed no difference in the bulk structure compared with the pristine one and the uniform AlF{sub 3} coating layers whose thickness is of about 10 nm covered Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} particles, as confirmed by a transmission electron microscopy. The AlF{sub 3} coating on Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} particles improved the overall electrochemical properties such as the cyclability, rate capability and thermal stability compared with those of the pristine Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2}. Such enhancements were attributed to the presence of the stable AlF{sub 3} layer which acts as the ...
The concepts of ''fast'' and ''slow'' time scale valence measurements are emphasized by a comparison of L/sub III/ absorption and Mossbauer effect measurements on the temperature induced valence change in EuPd/sub 2/Si/sub 2/. Further the authors show how synchrotron radiation based L/sub III/ measurements of the Ce-valence state can be used to demonstrate electronic structure trends under wide changes in chemical environment. The purpose of this paper is to provide an introduction to researchers in the People's Republic of China to the field of mixed valent rate earth compounds. They hope to illustrate some of the basic concepts in this field, how the field is contributing to the overall insight into the chemical physics of solids and finally how synchrotron radiation measurements in particular are playing a key role in this field.
Biofuels may contribute to both rural economic development and climate change mitigation and adaptation. The Gota Verde Project in Yoro, Honduras, attempts to demonstrate the technical and economic feasibility of small-scale biofuel production for local use by implementing a distinctive approach to feedstock production that encourages small farm sizes, mixed cropping of biofuel feedstock from Jatropha and food crops, particularly corn and beans, grown side by side on the same farmland and the total involvement of small rural farmers. But is the project sustainable? Using EC-Assess, the Earth Charter ethics-based assessment tool, to assess the sustainability of this project, the author found that in some assessment categories the actions surpassed the intended objectives, showing that the project was achieving certain Earth Charter goals without specifically stating its intention to address them. (Contains 3 images, 3 figures and 2 notes.)
Motivated by the discovery of superconductivity in alkali and alkaline earth fullerides, this program was undertaken both to understand the nature of and expand the range of materials demonstrating superconductivity. The first approach involved attempts to modify the fullerene cage by incorporating heteroatoms in the structure and the preparation and photophysical properties of nitrogen and sulfur doped fullerenes were studied in detail. The second approach involved examining the stoichiometry and effect of preparative conditions on the behavior of alkali, alkaline earth, lanthanide and mixed ion fullerides. In particular, the authors have elaborated on a technique for making such salts using liquid ammonia or aliphatic amines as solvents. Thirdly, modeling studies were undertaken to predict the properties of heterohedral fullerines and metal - C60 complexes, and theoretical guidelines were developed for understanding the reactivity of the ...
Three new phases with compositions, LaSr_2FeTiO_7, NdSr_2FeTiO_7 and GdSr_2FeTiO_7, were prepared by the traditional ceramic method. Lazy-Pulverix analysis of the X-ray diffraction data suggests that the phases crystallize in the RP-type (n = 2) structure in the space group, I4/mmm. The cell dimensions along the c-axis decrease with decrease in size of the rare earth ions. Electrical resistivity, as a function of temperature, shows that the materials are insulators and the resistivity decreases with decrease in the size of the rare earth ion, which is attributed to increase in the three-dimensional character. (author)
The luminescence spectra of trivalent europium ion embedded in various rare earth chromates were analysed. The spectroscopic data in most of chromates are in agreement with the structural determination but for some others the discrepancy between two methods is underlined. Energy level schemes were deducted from the experimental emission spectra and the crystal field simulation has been performed. The maximum splitting of the {sup 7}F{sub 1} manifold of the Eu{sup 3+} ion as a function of N{sub v}, the so-called crystal field strength parameter, is given. This allows us to classify the compounds according to their crystal field extent. (author) 11 refs, 8 figs, 2 tabs
This work aims to contribute to the understanding of the influence of the ionospheric layer height (ILH) on the thin layer ionospheric model (TLIM) used to retrieve ionospheric information from the GNSS observations. Particular attention is paid to the errors caused on the estimation of the vertical total electron content (vTEC) and the GNSS satellites and receivers inter-frequency biases (IFB), by the use of an inappropriate ILH. The work relies upon numerical simulations performed with an empirical model of the Earth?s ionosphere: the model is used to create realistic but controlled ionospheric scenarios and the errors are evaluated after recovering those scenarios with the TLIM. The error assessment is performed in the Central and the northern part of the South American continents, a re...
The spectre of major climate change caused by the greenhouse effect has generated intensive research, heated scientific debate and a concerted international effort to draft agreements for the reduction of greenhouse gas emissions. This report of Scientific Perspectives on the greenhouse problem explains the technical issues in the debate in language readily understandable to the non-specialist. The inherent complexities of attempts to simulate the earth's climate are explained, particularly with regard to the effects of clouds and the circulation of the oceans, which together represent the largest factors of uncertainty in current global warming forecasts. Results of the search for the 'greenhouse signal' in existing climate records aredescribed in chapter 3 (part two). Chapter 5 (part two) develops a projection of 21st-century warming based on relatively firm evidence of the earth's actual response to known increases in greenhouse gas ...
This journal contains the following articles (1) The Grand Challenge of Thermonuclear Ignition--Commentary by Edward I. Moses; (2) Orchestrating the World's Most Powerful Laser--The computer control system for the National Ignition Facility will soon have about 1.4-million lines of code running on more than 750 computers; (3) A Randon Walk through Time and Space--Albert einstein's 1905 papers on Brownian motion, random fluctuations, and statistical mechanics are fundamental to many Livermore research projects; (4) The Search for Methane in Earth's Mantle--Scientists are discovering that Earth's mantle may have untapped reserves of methane; and (5) Testing the Physics of Nuclear Isomers--Results from a tri-laboratory project contradict claims of accelerated release of energy from the nuclear isomer hafnium-178.
... Project Details Title: Influence of increasing droplet concentrations on properties of stratocumulus clouds and climate Supervisor: Dr Alan Gadian Funded by: Engineering and Physical Sciences Research Council (EPSRC) Start date: October 2006 My project involves use of the UK Met Office Unified Model (UM) to calculate the global effect of modifying stratocumulus droplet concentrations on the earth's radiation balance, as well as use of ... Publications Latham, J; Rasch, P; Chen, CC; Kettles, L; Gadian, A; Gettelman, A; Morrison, H; Bower, K; Choularton, T (2008) Global temperature stabilization via controlled albedo enhancement of low-level maritime clouds, Philos. Trans. Roy. Soc. A, 366(1882), pp3969-3987. doi:10.1098/rsta.2008.0137 Current Students | Internal ...
The use of selective additives such as MgO as a sintering aid and a rare earth oxide as a grain growth inhibitor, has allowed the manufacture of beryllia ceramics having close to theoretical density. The grain size and grain size distribution can be controlled by an optimum firing schedule leaving a remnant porosity which is extremely fine (0.2 {mu}m). This structure is compared with conventional BeO ceramics, densified by liquid phase sintering, which develops a glassy grain boundary and retains large pores up to 3 {mu}m. The significantly improved strength properties, extremely fine pores,the 'pinning effect' of rare earth oxide, and the superior surface finish both in the as-fired and polished state are discussed in relation to the micro-structure. (orig.).
A methodology for the determination of the rare earth elements in uranium oxides by ion microprobe has been set up on a Cameca ims-3f instrument. An uranium oxide reference material from a syn-metamorphic uranium deposit related to albitisation has also been developed for this type of analysis. Applications of the methodology are presented for a series of uranium oxides selected from some major uranium deposit types: from the world's highest grade unconformity-related uranium deposit from the Athabasca Basin (Saskatchewan, Canada; the Shea Creek and the McArthur River examples), a perigranitic vein-type deposit (Pen Ar Ran, Vendee, France) and a volcanic caldera-related deposit (Streltsovkoye, Transbaikalia, Russia). Each type of uranium deposit appears to have a specific REE signature. Al...
This invention pertains to a light weight underground pipe or cable installing device adapted for use in a narrow and deep operating trench. More particularly this underground pipe installing device employs a pair of laterally movable gates positioned adjacent the bottom of the operating trench where the earth is more solid to securely clamp the device in the operating trench to enable it to withstand the forces exerted as the actuating rod is forced through the earth from the so-called operating trench to the target trench. To accommodate the laterally movable gates positioned adjacent the bottom of the narrow pipe installing device, a pair of top operated double-acting rod clamping jaws, operated by a hydraulic cylinder positioned above the actuating rod are employed.
Ions of rare earth elements (r.e.e.) have been found to form with benzilic acid and rhodamine B precipitates hardly soluble in water and extractable by toluene. The conditions of La and Pr determination by extraction-spectrophotometry method are studied. Relative square deviation does not exceed 0.027 and 0.034 respectively. The method can be used for determination of other cerium sub-group r.e.e. in their salts and cannot be employed for determination of lighter r.e.e. in the presence of heavier r.e.e., because the latter form low soluble precipitates capturing the r.e.e. situated in the beginninq of the r.e.e. series.
In order to promote environmental damage monitoring and environmental impacts assessment caused by mining in China, the most significant project that uses advanced Earth Observation technology to assess environmental impacts caused by mining, namely MINEO (assessment and monitoring the environmental impact of mining activities in Europe using advanced Earth Observation technology) was introduced and its enlightenment to China were investigated. It was proposed that an integrated technical framework of monitoring environmental impacts caused by mining be designed, quantitative inversion of biological and environmental parameters from RS data be emphasised, hyperspectral Remote Sensing be applied, RS and GIS be integrated with professional models, multi-object applications of RS be implemented, and related standards and specification be drawn up based on typical case study sites. 23 refs., 1 fig.
We propose two algorithms to provide a full preliminary orbit of an Earth-orbiting object with a number of observations lower than the classical methods, such as those by Laplace and Gauss. The first one is the Virtual debris algorithm, based upon the admissible region, that is the set of the unknown quantities corresponding to possible orbits for a given observation for objects in Earth orbit (as opposed to both interplanetary orbits and ballistic ones). A similar method has already been successfully used in recent years for the asteroidal case. The second algorithm uses the integrals of the geocentric 2-body motion, which must have the same values at the times of the different observations for a common orbit to exist. We also discuss how to account for the perturbations of the 2-body motion, e.g., the J 2 effect.
Many modern military systems used for communications, command and control, navigation, and surveillance depend on reliable and relatively noise-free transmission of radiowave signals through the earth`s ionosphere. Small-scale irregularities in the ionospheric density can cause severe distortion, known as radiowave scintillation, of both the amplitude and phase of these signals. The WBMOD computer program can he used to estimate these effects on a wide range of systems. The objective of this study is to investigate improvements to the WBMOD model based on extensive data sets covering both the equatorial and high-latitude regimes. This report summarizes the work completed during the third year of this project, which includes completion of the new model for the high-latitude (auroral and polar cap) region of the WBMOD model.
The Gravity Probe-B (GP-B) spacecraft, designed to test predictions of general relativity, will fly in the mid 1990s. It will carry four electrostatically suspended gyroscopes in a cryogenic environment and will have a drag-free control system to minimize disturbances on the gyroscopes. The Stanford Test of Equivalence Principle (STEP) spacecraft, to fly later, will carry a set of test masses under very similar conditions. The possibility of using differential measurements of the GP-B gyroscopes suspension forces and the STEP tests mass displacement readout to form single-axis gravity gradiometers is explored. It is shown that the noise in the suspension systems is sufficiently small in the relevant frequency range, and that enough information is collected to compensate for the spacecrafts' attitude motion. Finally, using Breakwell's flat-earth approximation, these experiments are compared to other geodesy experiments and predict the contribution ...
In order to reduce the number of surface mining accidents related to low visibility conditions and blind spots of trucks and to provide 3D information for truck drivers and real time monitored truck information for the remote dispatcher, a 3D assisted driving system (3D-ADS) based on the GPS, mesh-wireless networks and the Google-Earth engine as the graphic interface and mine-mapping server, was developed at Virginia Tech. The research results indicate that this 3D-ADS system has the potential to increase reliability and reduce uncertainty in open pit mining operations by customizing the local 3D digital mining map, constructing 3D truck models, tracking vehicles in real time using a 3D interface and indicating available escape routes for driver safety.
Fractionation of isotopes of the alkali metals and the alkaline earth metals in ion exchange chromatography of their chlorides was studied. The heavier isotopes of potassium and rubidium were found to be preferentially fractionated into the ion exchanger phase while the lighter isotopes of lithium, magnesium, calcium and strontium were enriched in the exchanger phase. This can be interpreted as a resultant of the relative significance of isotope effect upon dehydration and isotope effect accompanying the phase change of the hydrated metal ion. Found was no evidence of anomalous isotope effect attributable to the odd-even difference in mass number of isotopes. Based on the spectroscopic and solution chemical data (experimental and theoretical), the isotopic reduced partition function ratios of the hydrated alkaline metal ions and stretching force constants of metal ion-hydrating water bonds were estimated. (author).
Spectrophotometry was used to study the conditions under which three-component complexes are formed of rare-earth elements (REE) with aminopolycarboxylic complexes and #beta#-diketones; the molar extinction coefficients of the above REE complexes were also found. A procedure is suggested for determining REE in chromatographic eluates with lower boundary of the contents determined being at 0.6-1.5 #mu#g/ml (Pr, Nd, Ho and Er) and 5-7 #mu#g/ml (Sm and Tm) with account for oxides. Luminescent techniques were also suggested for determining terbium in the presence of EDTA and terbium in an eluate containing EDTA and oxyethyl ethylene diamine triacetic acid, both acids being characterized by a relative standard deviation equal to 0.015-0.03.
Four general topics are covered in respect to the natural space radiation environment: (1) particles trapped by the earth`s magnetic field, (2) cosmic rays, (3) radiation environment inside a spacecraft, (4) laboratory radiation sources. The interaction of radiation with materials is described by ionization effects and displacement effects. Total-dose effects on MOS devices is discussed with respect to: measurement techniques, electron-hole yield, hole transport, oxide traps, interface traps, border traps, device properties, case studies and special concerns for commercial devices. Other device types considered for total-dose effects are SOI devices and nitrided oxide devices. Lastly, single event phenomena are discussed with respect to charge collection mechanisms and hard errors. (GHH)
This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO"2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO"2. O stimulates cooling by the emission at 15@mm in the collisions with CO"2. ...
We compare the metallicities of stars with radial velocity planets to the metallicity of a sample of field dwarfs. We confirm recent work indicating that the stars-with-planet sample as a whole is iron rich. However, the lowest mass stars tend to be iron poor, with several having [Fe/H]0.48) that contributes to but does not explain the mass-metallicity trend in the stars-with-planets sample. We use Monte Carlo models to show that adding an average of 6.5 Earth masses of iron to each star can explain both the mass-metallicity and the age-metallicity relations of the stars-with-planets sample. However, for at least one star, HD 38529, there is good evidence that the bulk metallicity is high. We conclude that the observed metallicities and metallicity trends are the result of the interaction of three effects; accretion of about 6 Earth masses of iron rich material, selection effects, and in some cases, high intrinsic metallicity.
Migration of protoplanets inside an accretion disc of a forming star is the most probable scenario for planetary system formation according to current models. Unsolved problems exist, concerning migration times and mechanisms. We report here the results of a 2D hydrodynamic study within an SPH scheme, analysing migration of an Earth-like or a Jupiter-like planet inside an inviscid sub-Keplerian accretion disc, as a function of the initial specific angular momentum of the infalling accretion disc matter. Particle capture by the protoplanet causes a rapid migration, within a few orbits, for the Earth like planet, and about 104 orbits for the Jupiter like planets. The effect of a planet pseudo-atmosphere is also discussed.
Superparamagnetic MFe{sub 2}{sup 3+}O{sub 4} (M=Mn{sup 2+}, Fe{sup 2+} and Co{sup 2+}) inverse spinel ferrite (ISF) nanoparticles with narrow size distribution having average diameters of 6-8 nm were synthesized by a diol reduction of organic metals and the surface was modified to be hydrophilic by coating with succimer. Magnetic resonance imaging (MRI) contrast enhancement by dipolar coupling defined interactions between the synthesized ISFs and protons in the bulk water was investigated with initial susceptibility, magnetization and anisotropy of the succimer-coated ISFs. The relaxivity ratios, r{sub 2}/r{sub 1}, for MnFe{sub 2}O{sub 4}, Fe{sub 3}O{sub 4} and CoFe{sub 2}O{sub 4} were measured to be 12.2, 23.1 and 62.3, respectively, which demonstrate the potential usefulness of these magnetic nanoparticles as T{sub 2} contrast agents for MRI.
Superparamagnetic MFe23+O4 (M=Mn2+, Fe2+ and Co2+) inverse spinel ferrite (ISF) nanoparticles with narrow size distribution having average diameters of 6-8 nm were synthesized by a diol reduction of organic metals and the surface was modified to be hydrophilic by coating with succimer. Magnetic resonance imaging (MRI) contrast enhancement by dipolar coupling defined interactions between the synthesized ISFs and protons in the bulk water was investigated with initial susceptibility, magnetization and anisotropy of the succimer-coated ISFs. The relaxivity ratios, r2/r1, for MnFe2O4, Fe3O4 and CoFe2O4 were measured to be 12.2, 23.1 and 62.3, respectively, which demonstrate the potential usefulness of these magnetic nanoparticles as T2 contrast agents for MRI.
The alloying of steel surface with aluminum (Al) using Microsecond-pulsed Intense Electron Beams (MIEB-Al) was developed and optimized in order to be used for improving the corrosion resistance of the 316, 1.4970 and T91 steels, exposed to liquid Pb and Pb-Bi-eutectic. The procedure consists in two steps: (i) coating the steel surface with Al or an Al-containing alloy layer and (ii) melting the coating layer and the steel surface layer using intense pulsed electron beam. In order to cover the steel surface with an homogeneous and crack-free Al-alloyed layer, the following experimental conditions are required: Al coating thickness range 5-10mm, electron kinetic energy 120keV; pulse duration 30ms; energy density 40-45J/cm2; number of pulses 2-3. Using the mentioned procedure, the corrosion r...
We have investigated the possibility to use a microwire of BiSn to design an anisotropic thermoelectric generator. The glass-coated microwire of pure and Sn-doped bismuth was obtained by the Ulitovsky method; it was a cylindrical single-crystal with orientation (1011) along the wire axis; the C3 axis was inclined at an angle of 70 degrees to the microwire axis. It is found that doping of bismuth wires with tin increases the thermopower anisotropy in comparison with Bi by a factor of 2 - 3 in the temperature range of 200-300 K. For a Bi microwire with a core diameter of 10 ?m with a glass coating with outer diameter of 35 ?m, the transverse thermopower is ? 150 ?V/(K*cm); for BiSn, 300 ?V/(K*cm). The design of an anisotropic thermogenerator based on BiSn microwire is proposed. The miniature thermogenerator will be efficient for power supply of devices with low useful current. In addition to the considerable thermopower anisotropy of BiSn wires ...
The present invention provides a fuel cladding tube having an excellent corrosion resistance and thus a long life, and a suitable manufacturing method therefor. Namely, in the fuel cladding tube, the outer circumference of an inner layer made of a zirconium base alloy is coated with an outer layer made of a metal more corrosion resistant than the zirconium base alloy. Ti or a titanium alloy is suitable for the corrosion resistant metal. In addition, the outer layer can be coated by a method such as vapor deposition or plating, not limited to joining of the inner layer material and the outer layer material. Specifically, a composite material having an inner layer made of a zirconium alloy coated by the outer material made of a titanium alloy is applied with hot fabrication at a temperature within a range of from 500 to 850degC and at a fabrication rate of not less than 5%. The fabrication method includes any of extrusion, ...
A systematic study was made on MoSi{sub 2}-based nanolayer coatings. Alternating layers with thickness 1-20 nm were prepared by sputtering. Nitrided MoSi{sub 2} has a very high crystallization temperature, >1000 C, and MoSi{sub 2}Nx (x=3-4) can be used as a stable second phase reinforcement or diffusion barrier coatings. Mechanical properties depend strongly on phase and morphology of the layers: hardness and modulus is significantly increased in the crystallization. The nanolayers have much higher hardness but lower modulus (which project higher toughness in the nanolayers). Wear resistance is improved with decreasing layer thickness. Single phase MoSi{sub 2}Nx (x=0-4.2) has a wide range of hardness and modulus with varying N content and annealing, suggesting the possibility of engineering MoSi{sub 2}Nx to produce different material properties for different mechanical applications. Most of this paper is made up of viewographs.
Slurry aluminizing is one method of protecting titanium alloys and intermetallics at temperatures at which oxidation would otherwise significantly degrade mechanical properties. The technique produces a continuous layer of alumina-forming TiAl_3 on exposed surfaces. The influence of composition, film thickness, and diffusion temperature upon the oxidation resistance of these slurry aluminides was studied in cyclic tests to 816degC (1500deg F). Degradation of slurry aluminized #beta#-titanium alloy and #alpha#-Z titanium aluminide intermetallic occurs by localized oxidation at cracks in the coating layer. These cracks are probably due to mismatch of coefficients of thermal expansion between the coatings and substrates. Addition of silicon to the slurry modifies the oxidation behaviour around a crack by introducing a continuous layer of titanium silicide at the boundary of the aluminide coating and substrate, thereby ...
High-quality solar cells have been fabricated by utilizing localized argon-ion laser decomposition of silver neodecanoate spun onto diffused silicon substrates and subsequent electroplating. Early adhesion problems during electroplating have been carefully studied and finally solved using a novel coating procedure. The laser-metallized solar cells have been characterized using lighted and dark current-voltage measurements and compared with baseline cells metallized using standard photolithographic procedures. Non-AR-coated cell efficiencies ranging from 10 to over 11% have been obtained for the laser-metallized cells, comparable with the best baseline cells. The laser-metallized cells have 30 to 40% lower series resistance than the unsintered baseline cells, indicating that in-situ sintering takes place during laser writing. A dramatic new and simpler laser metallization process on which patent protection is currently being sought has yielded ...
Functionalizing nanoparticle surfaces is essential for achieving homogeneous dispersions of monodisperse particles in polymer nanocomposites for successful utilization in engineering applications. Functionalization reduces the surface energy of the nanoparticles, thereby limiting the tendency to agglomerate. Moreover, reactive groups on the surface can also participate in the polymerization, creating covalent bonds between the inorganic and organic phases. In this paper, a fluidized bed inductively coupled plasma (FB-ICP) reactor is used to break apart the agglomerates and functionalize commercial TiO2 nanoparticle powders in a batch of several grams. The fluidized bed could be implemented into a continuous flow reactor, potentially making this a viable method to treat larger quantities of commercial powders. The particles are treated with acrylic acid (AA) and tetraethylorthosilicate (TEOS) plasma and the functionalized particles were collected separately from bulk powder. High ...
The major objective of this work is to seek for new solutions that can lead to significant lifetime improvement of submerse lines which experience severe wear processes on the polymeric layer coating used for protection of the touch down point (TDP) region. Four different materials were selected as possible candidates for the coating layer of this critical region. They are commercially available and posses well known processing technologies. The materials are two polymers: nylon 66 and polyacetal; and two composites: nylon 66 reinforced with 13 or 33% glass fiber. Stress-strain behavior was evaluated using two deformation rates in order to characterize the viscoelastic behavior proper of polymeric materials. It was observed that increasing the amount of glass fiber in the matrix leads to a stronger material and a consequent decrease of elongation to break. Additionally, abrasion tests were carried out using a Taber equipment in three distinct ...
The University of Georgia, in collaboration with GE Global Research, has investigated the relevant quenching mechanism of phosphor coatings used in white light devices based on UV LEDs. The final goal of the project was the design and fabrication of a high-efficacy white light UV-LED device through improved geometry and optimized phosphor coatings. At the end of the research period, which was extended to seamlessly carry over the research to a follow-up program, we have demonstrated a two-fold improvement in the conversion efficiency of a white light LED device, where the increase efficacy is due to both improved phosphor quantum efficiency and lamp geometry. Working prototypes have been displayed at DOE sponsored meetings and during the final presentation at the DOE Headquarters in Washington, DC. During the first phase of the project, a fundamental understanding of quenching processes in UV-LEDs was obtained, and the relationships that ...
The University of Georgia, in collaboration with GE Global Research, has investigated the relevant quenching mechanism of phosphor coatings used in white light devices based on UV LEDs. The final goal of the project was the design and fabrication of a high-efficacy white light UV-LED device through improved geometry and optimized phosphor coatings. At the end of the research period, which was extended to seamlessly carry over the research to a follow-up program, we have demonstrated a two-fold improvement in the conversion efficiency of a white light LED device, where the increase efficacy is due to both improved phosphor quantum efficiency and lamp geometry. Working prototypes have been displayed at DOE sponsored meetings and during the final presentation at the DOE Headquarters in Washington, DC. During the first phase of the project, a fundamental understanding of quenching processes in UV-LEDs was obtained, and the relationships that ...
A novel composite film, comprising of hydrophobic ionic liquid (IL), multi-walled carbon nanotubes (MWNTs) and gold nanoparticles (GNP), was fabricated and characterized. The GNP was introduced through electrochemical deposition on IL-MWNT gel film coated glassy carbon electrodes (GCE). Experiments showed that both IL and MWNTs could facilitate the GNP deposition. With GNP the composite film exhibited smaller electron transfer resistance and higher sensitivity in sensing guanine (G) and adenine (A). Under the optimized experimental conditions, the anodic peak currents were linear to the analyte concentration in the ranges of 0.008-2.0 {mu}M. The detection limits were down to nanomole level after an accumulation of 150 s on open-circuit. In addition, on the composite film coated GCE, the anodic peaks of G and A were well separated, and their response sensitivities kept almost unchanged no matter whether they coexisted or not. This proposed ...
A novel composite film, comprising of hydrophobic ionic liquid (IL), multi-walled carbon nanotubes (MWNTs) and gold nanoparticles (GNP), was fabricated and characterized. The GNP was introduced through electrochemical deposition on IL-MWNT gel film coated glassy carbon electrodes (GCE). Experiments showed that both IL and MWNTs could facilitate the GNP deposition. With GNP the composite film exhibited smaller electron transfer resistance and higher sensitivity in sensing guanine (G) and adenine (A). Under the optimized experimental conditions, the anodic peak currents were linear to the analyte concentration in the ranges of 0.008-2.0 ?M. The detection limits were down to nanomole level after an accumulation of 150 s on open-circuit. In addition, on the composite film coated GCE, the anodic peaks of G and A were well separated, and their response sensitivities kept almost unchanged no matter whether they coexisted or not. This proposed ...
The information reported is for the period October I to December 31, 1993. During this quarter, activities were undertaken in Task 2. Oxygen concentrations were measured in the post-flame region of the entrained flow reactor. The sampling probe was used for the hot gas tests to sample the gas stream. Samples were injected into a gas chromatograph to determine the oxygen concentration. Results agreed with thermoequilibrium calculations that yield equilibrium compositions based on the stoichiometry of the feed gases. The axial temperature distribution along the reactor centerline was measured using a silica-coated platinum-rhodium thermocouple. Two coating techniques were tested and it was found that flame-plating silica to the thermocouple wires produced a thinner coating than a ceramic adhesive technique and therefore a smaller radiation correction. Other activities this quarter included the fabrication of a solids sampling ...
A combined PVD/PECVD process for the vacuum deposition of titanium containing amorphous hydrogenated carbon films is described. Elemental compositions of the deposited films have been determined by in situ core level photoelectron spectroscopy (XPS). The long-term stability of the plasma process has been demonstrated. Target poisoning has not been observed. We have fabricated optical selective surfaces by the deposition of a-C:H/Ti multilayers onto aluminum substrates. Even though we have not optimized layer thicknesses and stoichiometries so far, the experimental results are promising: solar absorptance {alpha}{sub S} of 0.876 and thermal emittance {epsilon}{sub 100C} of 0.061 have been achieved yielding an optical selectivity sis defined as{alpha}{sub S}/{epsilon}{sub 100C} of 14.4. Accelerated aging tests of these coatings have demonstrated their aging stability: the service lifetime is predicted to amount to more than 25 years. Raman spectroscopy has been used ...
Phenolic resins have made a major breakthrough in the field of high technology in 80's. These are now active participants of "high tech' areas ranging from electronics, computers, communication, outer space, aerospace, advanced materials, bio materials and technology. A phenol - formaldehyde (1:1.5) resin having resin content of 70% synthesized in the laboratory has been applied for wood coating and reinforcing glass fiber. The weatherability and solvent resistance of these items have been studied and results discussed keeping in view the envisaged application for structural materials and chemical equipment. The toxic materials released during contact with solvents for chemical applications and during degradation general have been monitored. The results are discussed with reference to environmental pollution due to these resins and their composites under different conditions. (authors)
This paper describes the basic principles underlying the operation of low heat loss engines and the magnitude of the efficiency improvements that are theoretically achievable. The effect of varying degrees of thermal insulation on various operating parameters is examined in some detail, as is the relationship between degree of insulation and ceramic coating thickness. The effect on ceramic materials of severe surface temperature oscillations and the resultant thermal stress gradients is also discussed. In the following section, the paper describes methods of construction adopted both for ceramic inserts and coatings, and rig tests for the assessment of thermal fatigue under both load and firing cycling. The paper does not attempt to draw any general conclusions.
Environmental scanning electron microscopy (ESEM) allows the examination of hydrated and dried specimens without a conductive metal coating which could be advantageous in the imaging of biological and medical objects. The aim of this study was to assess the performance and benefits of wet-mode and low vacuum ESEM in comparison to high vacuum scanning electron microscopy (SEM) using the choroid plexus of chicken embryos as a model, an organ of the brain involved in the formation of cerebrospinal fluid in vertebrates. Specimens were fixed with or without heavy metals and examined directly or after critical point drying with or without metal coating. For wet mode ESEM freshly excised specimens without any pre-treatment were also examined. Conventional high vacuum SEM revealed the characterist...
Alumina-reinforced carbon nanofiber nanocomposites were prepared using different routes; powders mixture, colloidal route and sol?gel process followed by spark plasma sintering (SPS). CNFs/xAl2O3 (x = 10?50 vol.%) were prepared through nanopowders mixing in a high-energy attrition milling. The main limitations in the preparation of this kind of nanocomposites are related to the difficulty in obtaining materials with a homogeneous distribution of both phases and the different chemical nature of CNFs and Al2O3, which causes poor interaction between them. A surface coating of CNFs by wet chemical routes with an alumina precursor is proposed as a very effective way to improve the interaction between CNFs and Al2O3. An improvement of 50% in fracture strength was found for similar nanocomposite ...
The influence of selenium dioxide (SeO2) on the microstructure and electrodeposition of manganese coatings obtained from a sulfate based neutral solution was investigated by material characterization methods and electrochemical techniques. The crystal structure and surface morphology of these coatings were studied by scanning electron microscopy (SEM) and powder X-ray diffraction spectroscopy (XRD), respectively. The SEM and XRD data showed that SeO2 could effectively accelerate phase transformation, and facilitate leveled and fine grain growth. The electrochemical results indicated that SeO2 could inhibit hydrogen evolution reaction and promote manganese deposition. The action of selenium dioxide in manganese deposition was found to be a reduction and adsorption mechanism. The process cou...
Carbon steel is frequently used to construct concentrated sulphuric acid storage tanks. This paper discussed the corrosion performance of carbon steel tanks and outlined the underlying mechanisms responsible for major corrosion modes. Analyses of hydrogen grooving and dilute acid corrosion failure mechanisms were presented. Recent corrosion-induced leak failures were also discussed. The use of anodic protection and organic coatings as a corrosion control measure was also evaluated. The results of laboratory studies that were conducted to understand corrosion-induced failures showed that carbon steel electrodes exhibited transpassive corrosion at relatively high anodic potentials, while stainless steel electrodes exhibited transpassive corrosion at anodic potentials less than 1 V. It was concluded that corrosion-induced leaks can be prevented by using anodic protection and baked phenolic coating technologies. 23 refs., 9 figs.
In the beam pipe of the positron damping ring of the Next Linear Collider, electrons will be created by beam interaction with the surrounding vacuum chamber wall and give rise to an electron cloud. Several solutions are possible for avoiding the electron cloud, without changing the bunch structure or the diameter of the vacuum chamber. Some of the currently available solutions for preventing this spurious electron load include reducing residual gas ionization by the beam, minimizing beam photon-induced electron production, and lowering the secondary electron yield (SEY) of the chamber wall. We will report on recent SEY measurements performed at SLAC on TiN coatings and TiZrV non-evaporable getter thin films.
One of the significant factors of neutron radiographic image degradation is scattering blur from the object. A practical method is described to enhance image quality by eliminating the overlapping of scattered thermal neutrons component from the objects in ETRR-2 neutron radiography facility, using aluminum Gd-coated antiscatter grid. The MCNP code was used to determine the optimum grid dimensions that will reduce the scattered thermal neutrons from the object. An experiment was performed to determine the optimum grid height and irradiation time that gives the best image with acceptable geometric unsharpness. Using the MCNP code it was found that 97% of the scattered neutrons were removed by the grid. The wall dimensions and Gd coating are so small that the facility resolution cannot detect the image pattern superposition on the film.
This is a process for manufacturing a semi-rigid, folding solar generator manufactured from several coated solar cells (Cics), which has at least two folding parts connected together so as to turn by hinges, characterized by the following stages of the process: a) On the back of matrix subsections, in order to cover the connector, carbon fibre strips are glued on, which project over the upper or lower edge of each matrix subsection. b) The projecting ends of adjacent carbon fiber strips are connected with two carbon fibre strips. c) At least two matrix subsections are fixed in separately manufactured carbon fiber frames, and d) the carbon fiber frames, together with the matrix subsections are connected via hinges to a solar generator.
This paper described a risk control management tool that has been developed by Petrobras Petroleo, the largest Brazilian oil company and one of the world's leading oil companies. The system covers health, safety and environmental (HSE) issues regarding pipeline construction projects. The limitations of traditional safety management systems for coping with the critical problems related to environmental safety issues were discussed. In particular, this paper described how the HSE tool evaluates the risks resulting from the following aspects of onshore pipeline construction and assembly: establishing right-of-way and route locations, transporting pipe, developing the construction site, opening the trench, pipe laying, pipe bending, concrete external coating, welding, external anticorrosive coatings, pipe placement backfilling, hydrostatic testing, maintenance operations, and pipeline commissioning. 6 refs., 1 tab.
The major goal of this contract is to define fine grid lines using laser-assisted metallization and to demonstrate the fabrication of high-efficiency cells using this process. During this period a solar cell run was completed using low-resistivity float-zone silicon. Grid lines were written by spinning silver neodecanoate solution after the Ti-Pd evaporation. This run produced cell efficiencies as high as 11.2% prior to antireflection coating and 16.6% after the AR coating. Open-circuit voltage was approx.604 mV and short-circuit current density was approx.35 mA/cmS.
Methods for improving the sensitivity of scintillation cells for radon concentration measurements were studied with emphasis on improving light collection efficiency. This allows the length and hence the volume of the cell to be increased. Variables studied were choice of scintillator material, its method of application and thickness, length of cell, cell material, type and configuration of reflectors, choice of photomultipliers, and factors affecting background. Response from various areas of the cell surface was studied with an alpha source and with radon filling. Coating the window with phosphor was found to be counter-productive. The optimum results obtained were with the inside of the cell (other than the window) covered with a thick layer of ZnS(Ag), or with a thick layer of reflective material coated with a thin layer of phosphor. With it, a 10 cm diameter plexiglass cell can be extended to at least 50 cm length without difficulty from ...
Methods for improving the sensitivity of scintillation cells for radon concentration measurements were studied with emphasis on improving light collection efficiency. This allows the length and hence the volume of the cell to be increased. Variables studied were choice of scintillator material, its method of application and thickness, length of cell, cell material, type and configuration of reflectors, choice of photomultipliers, and factors affecting background. Response from various areas of the cell surface was studied with an alphy source and with radon filling. Coating the window with phosphor was found to be counter-productive. The optimum results obtained were with the inside of the cell (other than the window) covered with a thick layer of ZnS(Ag), or with a thick layer of reflective material coated with a thin layer of phosphor. With it, a 10 cm diameter plexiglass cell can be extended to at least 50 cm length without difficulty from ...
DZ4 substrates were coated with NiCoCrAlY by plasma spray and subsequently treated by high current pulsed electron beams(HCPEB) of different parameters. The surface microstructure, phase structure and high temperature oxidation resistance were studied. It has been shown that as a result of the HCPEB treatment the loose and rough structure remelted and the surface became smooth. Smooth microregion, craters and cracks appeared on the surface. The ?' phase manifolded and there was no visible thermal stress. The oxidation test at 900 degree C for 100 h showed that a more compact and successive ?-Al_2O_3 scale was formed on the surface of the samples after HCPEB irradiation, which improved the oxidation resistance of the NiCoCrAlY coatings obviously. (authors)
Means of intensifying heat transfer with nucleate boiling, based on boiling under constrained conditions (in slots, on a capillary-porous surface) are the most promising since a high intensity of heat transfer is ensured. In the present work we attempt to evolve the main assumptions for the physical model of the process of vapour formation under constrained conditions and to extend them to the boiling of cryogenic liquids on surfaces with a capillary-porous deposit; also, the results are given of experimental investigations of heat transfer with the boiling of nitrogen, oxygen and hydrogen at atmospheric perssures and below on capillary-porous surfaces of various metals of different structure produced by an electric arc method of gasothermal spray coating.
The influences of maltodextrin (MD) addition and multi-layer formation on the freeze-thaw stability of ?-lactoglobulin (?-Lg)-stabilized oil-in-water beverage emulsions (0.1 wt% corn oil, 0.006 wt% ?-Lg) were investigated. Various beverage emulsions were prepared depending on MD concentration (0?20 wt%), its dextrose equivalent (M150 or M250), and the presence or absence of additional polysaccharides (pectin, alginate, or ?-carrageenan) coatings around the emulsion droplets. All emulsions (?-Lg- and ?-Lg-polysaccharide-coated emulsions) were unstable to experimental freeze-thaw cycling in the absence of MD. In the presence of MD, all emulsions containing M250 had better stability to droplet aggregation than those with M150, regardless of MD concentrations and freeze-thawing. The optimum co...
b-carotene, a natural antioxidant, beneficial form human health prospective. In this study we had examined the recovery of b-carotene form mesoporous carbon coated monolith (MCCM) by batch process. Desorption kinetics and isotherm studies were carried out by using n-hexane as an eluent. Isotherm studies showed better applicability of Langmuir model. The first-order two-compartment three-parameter kinetics model as a function of initial loading concentration and reaction temperature was applied. It was observed that b-carotene desorption process is controlled by both rapid and slow desorption. Results showed that the slow desorption fraction increases from 0.8446 to 0.9007 with increase in initial loading concentration from 10.83 to 39.72mg/g while, the slow desorption fraction decreases fr...
An innovative hybrid powder prepared using computer simulation allowed development of a new foundation having a fine, smooth texture that has never been achieved before. The optical structure/design of the powder was based on the results of measurements and analyses conducted on the optical characteristics of a baby's delicate skin, which is the envy of many women. To obtain the optimal optical characteristics, the finite differential time domain (FDTD) method for solving Maxwell's differential equation by difference and time domain was applied to the computer simulation method. For synthesis of the hybrid powder based on the optical model, a proprietary shape regulation coating technology was used in which flaky substrates were coated with microspherical forms of barium sulfate crystals. ...
Abstract A novel and convenient protocol for the preparation of an open-tubular column coated with chitosan-silica hybrid using chitosan and silane-coupling agent (-glycidoxy-propyltrimethoxysilane) was developed for CEC, in which, chitosan was covalently bonded to the inner wall of a fused-silica capillary using -glycidoxy-propyltrimethoxysilane as a cross-linking agent. The stationary phase was hydrophilic due to the chitosan-silica hybrid with abundant amine and hydroxyl functional groups. The chromatographic characteristics of the column were evaluated by the separation of some organic acids and inorganic anions. The column showed good selectivity for nucleotides, aromatic acids, and inorganic anions. The mechanism for the separation of these compounds was primarily based on the hydrop...
A study of the stability of conducting fabrics of polyester (PES) coated with polypyrrole/PW12O40^3^- (organic/inorganic hybrid material) in different pH solutions (1, 7, 13) has been done. Washing tests were also done in views of its possible application in electronic textiles such as antistatic clothing. X-ray photoelectron spectroscopy (XPS) studies have been done to quantify the amount of counter ion that remains in the polymer matrix and determine the doping ratio (N^+/N) after the different tests. Scanning electron microscopy (SEM) was also used to observe morphological differences after the different tests. Surface resistivity changes were measured by means of electrochemical impedance spectroscopy (EIS). Scanning electrochemical microscopy (SECM) was employed to measure changes in ...
Superalloys, such as Inconels and Incoloys, are extensively used where high strength is a requirement. However, where these materials are required to slide against one another, particularly with poor or no lubrication, high friction levels and seizure are commonly seen to occur, which can cause component failure. In this work seizure characteristics of three superalloys (Inconel 718 and Incoloys 945 and 945X) were investigated, uncoated, coated with Armoloy (a hard, thin, dense chrome coating with a micro-nodular surface texture) and plasma nitrided in dry sliding conditions. A rig purpose built for initiating seizure was used. It involves sliding a ball against a disc at constant speed while the load is increased. Tests are designed to last less than one rotation so that the wear scar can...
It is generally known that a number of metallic glasses have excellent corrosion resistance in a variety of chemically hostile environments. Consequently, the use of laser cladding to coat a massive crystalline material such as aluminium with a layer of a metallic glass has obvious advantages. In this paper, the authors will show that the formation of a predominantly amorphous layer of Zr_6_0Al_1_5NI_2_5 alloy by laser processing is possible, if the obstacles to amorphization are overcome. In addition, evidence of the excellent corrosion resistance of this alloy in a NaCl solution will be given. A comparative study of the corrosion behavior of this amorphous alloy with pure aluminium and Al-Cr alloy will be done, in order to complete previous studies of laser processed coatings of aluminum substrates.
It is necessary to identify those measurable soil parameters which dictate the severity of the corrosion problem for coated irons and steels. When this is done, meaningful accelerated aging tests can be designed to validate the reduced corrosion rate for the planned coating. The following discussion introduces the important concepts and measurement parameters in the (a) design of accelerated aging tests, and (b) evaluation of the planned installation site for corrosion potential. Certain combinations of soil oxidation reduction potential (ORP) or electric potential (Eh), acidity (pH), fertilizer, water table, and soil hydraulic conductivity can result in severe corrosion of buried steel/iron vessels. If there are power lines nearby, additional loss of vessel material to the soil will occur. These factors are discussed.
Corrosion is said to be the most dominant factor which affects the physical life of ships and offshore structures. In order to secure the structural safety of ships and offshore structures, it is necessary to take measures to corrosion based on the prediction of condition of progressive corrosion. But such prediction is difficult because the behavior of corrosion`s progress is probabilistic. In this paper, probabilistic model, which could evaluate the degradation of coatings and the successive corrosion of steel members, was proposed in order to explain the tendency of the actual corrosion conditions of existing ships. Then, statistical inferences on the proposed model were made by applying the actual data on plate thickness measurements of Bulk Carriers` Cargo Hold. And validity of the proposed model was verified.
Background: As the global population ages, support for family caregivers who provide the bulk of care to community-dwelling older people is becoming ever more important. However, in many countries, homecare-service practitioners currently do not follow a systematic approach to assessing and responding to caregiver needs. Objectives: The aim of this study was to explore the experiences of caregivers and practitioners who took part in a field test of the Family Caregivers Support Agreement (FCSA) tool, a modified version of the Carers Outcome Agreement Tool (COAT) initially developed as the result of an Anglo-Swedish study. Both the COAT and the FCSA are designed to facilitate partnerships between caregivers and practitioners so that needs assessment and subsequent support services are negot...
A superhydrophobic SiO2/nylon 6,6 nanocomposite coating was fabricated by a facile casting process. Compared with the intrinsically hydrophilic pure nylon 6,6, the as-prepared coating displayed a superhydrophobic property in the pH range from 1 to 14. It was also found that the resulting water contact angles of the as-prepared surface were always larger than 159?, but the sliding angles had an obvious decrease from about 33.4??1? as the content of SiO2 nanoparticles increased. In addition, a transition from the transitional superhydrophobic state between Wenzel?s and Cassie?s state to the Cassie?s state was observed.
The use of europium as a local structural probe allows the various phases appearing in the NaCaPO_4-Na_3Eu(PO_4)_2 and NaSrPO_4-Na_3Eu(PO_4)_2 systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO_4 groups. (Auth.).
DescriptionThis new research programme activity on Urban Atmospheric Science will deliver aspects of the NERC strategy: Next Generation Science for Planet Earth. It has been developed as part of the Environment, Pollution & Human Health theme. Research in the Environment, Pollution & Human Health theme is directed at elucidating key environmental processes that form part of a causal pathway between an environmental hazard and disease outcome, and providing a predictive capability of the risk to human heal [continued...
This paper focuses on potential effects of solar phenomena on communication systems used by the electric utility industry. It begins with a discussion of solar phenomena fundamentals and discussion of the interaction between solar emissions and the earth's ionosphere and magnetosphere. It continues with a discussion of the resulting impacts on communication systems including radio, satellite, wireline, fiber optic, and powerline systems and concludes with a discussion of mitigation techniques and a call for observers to report suspected solar impact experiencexperiences.
Various topics include: (1) direction finding, (2) range finding, (3) Doppler measurements, (4) construction of a receiver for radio interferometry, (5) mobile laser range finding system, (6) figure-and field parameter determination/geopotential, (7) dynamics of the Earth-Moon system, and (8) kinematics of geodetic point fields.
The observed strength of the carbon dioxide absorption bands recorded on spectrobolograms of the transparency of the earth's atmosphere between wavelengths 300 and 2500 nanometers as part of the Smithsonian Solar Constant Program were used to extract the abundance of carbon dioxide in the atmosphere. The details of the analysis and the sources of error are discussed. 11 references, 5 figures, 1 table. (ACR)
Governments around the world will soon make decisions on policies that could determine the fate of the ozone layer-the Earth's shield from harmful ultraviolet radiation. The Vienna Convention for the Protection of the Ozone Layer, signed on March 22, 1985, created a framework for scientific cooperation and information exchange that will form the basis for a protocol for controlling substances thought to threaten the ozone layer. As of mid-1987, 29 countries had signed the Convention, including the major producers and users of chlorofluorocarbons (CFCs), the most important of suspect chemicals.
The optical properties of uranium monochalcogenides and monopnictides are discussed in terms of their electronic structure. A comparison is made with corresponding rare earth compounds. It is shown that there are close similarities to mixed valence CeN. the results support the occurrence of a dip in the density of d states near Esub(F), where the f density of states has its maximum. Empirical energy level schemes are derived which are found to agree with the existing information from XPS measurements and recent theories. (orig.).
The effect of small misch metal additions (0.25 to 1 wt.%) on the corrosion behaviour of aluminium was studied through electrochemical polarization in 0.1 N inorganic and organic acids at room temperature. It has been observed that rare earth addition improves the corrosion resistance of aluminium. (orig.).
In this paper the possibility of configuring a water cooled Nuclear Thermal Propulsion (NTP) rocket, based on a Particle Bed Reactor (PBR) is investigated. This rocket will be used to operate on water obtained from near earth objects. The conclusions reached in this paper indicate that it is possible to configure a PBR based NTP rocket to operate on water and meet the mission requirements envisioned for it. No insurmountable technology issues have been identified.
The Comprehensive Nuclear-Test-Ban-Treaty (CTBT), which was opened for signature in 1996, bans all nuclear explosions in all environments. Republic of Korea has been working to monitor compliance with CTBT by deterring and detecting any nuclear explosions conducted anywhere on Earth. For the verification of CTBT, several techniques are implemented. Radionuclide monitoring is of particular importance since it is the only method which can provide absolute assurance that a nuclear detonation has occurred
An outline of Manitoba Hydro's Earth Power program was presented. Details of the heat pump market in Manitoba were provided, including details of residential and commercial sales. Total residential heat pump sales amounted to 577 units in 2004, equivalent to over $11.2 million in sales. Commercial installations amounted to approximately $12.7 million. An outline of industry players was presented. The goals of Manitoba Hydro were outlined in relation to geothermal energy and the Power Smart program. Their objectives included increasing awareness of geothermal energy, making heat pumps more accessible, and improving industry infrastructure. Other objectives included educating the public about life-cycle cost implications, residential loans and commercial incentives. To date, the residential power loan has provided financing to over 300 Manitoba home owners for installations, with electrical savings of over 1.34 Gwh and natural gas savings of 279,425 m"3. The program ...
Design constraints require that as Earth terminal attempting communications with a FLTSATCOM EHF Package (FEP) located onboard a FLTSATCOM satellite be provided with an accurate FEP package. To be precise, the terminal is provided with a coefficient element set from which the ephemeris of a satellite may be computed. This report describes the operation of a user friendly computer program that produces the above mentioned coefficient set so as to provide reference benchmarks from which the ephemeris related operations of the terminal can be judged.
The indirect detection of particle dark matter (DM) is based on the search for anomalous components in cosmic rays (CRs) due to the annihilation of DM pairs in the galactic halo, on the top of the standard astrophysical production. These additional exotic components are potentially detectable at Earth as spectral distortions for the various cosmic radiations: $\\chi + \\chi \\to q \\bar{q}, W^+ W^-, ... \\to \\bar{p}, \\bar{D}, e^+ \\gamma and \
A tobermorite/hydroxyapatite composite was prepared by hydrothermal treatment using diatomaceous earth, ?-tricalcium phosphate and slaked lime starting materials. The XRD patterns of the composite confirmed that tobermorite and hydroxyapatite were formed after the hydrothermal process. The bending strength of the composite reached a level higher than 9?MPa after the hydrothermal process. The development of the bending strength was due to the formation of tobermorite and hydroxyapatite during the hydrothermal process. The composite had a high specific surface area due to these newly formed crystals.
This report highlights the significance of the geological sciences to the nation and to society. Discussions include understanding plate tectonics and surface processes, exploring the continental crust, ocean basins and the deep earth, applications of geology to social problems such as mineral resources, waste disposal, siting of critical facilities, geological hazards, water resources management, and coastal zones. The state of health of geological research is also discussed. (ACR)
Research programs from the following sections and programs are summarized: aquatic ecology, environmental resources, earth sciences, terrestrial ecology, advanced fossil energy program, toxic substances program, environmental impacts program, biomass, low-level waste research and development program, US DOE low-level waste management program, and waste isolation program.
Laser-induced breakdown spectroscopy (LIBS) is typically performed at ambient Earth atmospheric conditions. However, interest in LIBS in other atmospheric conditions has increased in recent years, especially for use in space exploration (e.g., Mars and Lunar) or to improve resolution for isotopic signatures. This review focuses on what has been reported about the performance of LIBS in reduced pressure environments as well as in various gases other than air.
... 01, 2009 | Rate It Marine Technology Society https://www.mtsociety.org/home.aspx emphasizes the importance of marine technology as it applies to global issues, encourages marine technology education and facilitates the use of marine technology in managing marine resources Added: Mar. 11, 2010 |...
The temperature and concentration dependence of the densities of binary CaBr_2-(Li, Na, K, Rb, Cs)Br, NaBr-(Sr, Ba)Br_2 and KBr-SrBr_2 mixtures have been measured using the method of hydrostatic weighing. With exception of the systems LiBr-CaBr_2 and NaBr-(Sr, Ba)Br_2 the calculated molar excess volumes are positiv in the investigated mixtures. (author).
We present a study of the crystal field in PrNiAl, NdNiAl, ErNiAl and ErCuAl intermetallic compounds based on inelastic neutron spectroscopy. These compounds crystallize in the ZrNiAl-type hexagonal structure with an orthorhombic symmetry on rare-earth sites. The results are compared with the specific-heat data, and the lower parts of the crystal-field energy-level schemes are determined. (orig.)
We present a study of the crystal field in PrNiAl, NdNiAl, ErNiAl and ErCuAl intermetallic compounds based on inelastic neutron spectroscopy. These compounds crystallize in the ZrNiAl-type hexagonal structure with an orthorhombic symmetry on rare-earth sites. The results are compared with the specific-heat data, and the lower parts of the crystal-field energy-level schemes are determined. (orig.)
The metabolism of organic matter in the coastal regions of the ocean may significantly affect the oceanic carbon budget. This paper describes the high percentage (30%) of oceanic oxidation that occurs in coastal areas and the impact of this metabolism on the carbon cycle and climate of earth. Organic metabolism in the ocean appears to be a source of carbon dioxide release into the atmosphere. Oxidation in the coastal zone is of special interest, as it is likely influenced by anthropogenic activity. Recommendations for future research on this topic are proposed. 129 refs., 2 figs., 6 tabs.
This book presents topics on: Density of rocks and minerals, includes histograms of density ranges; elastic constants of minerals, elastic moduli, thermal properties; inelastic properties, strength and rheology for rocks and minerals, rock mechanics and friction, and stress-strain relations; radioactivity, decay constants and heat production of isotope systems in geology; seismic attenuation, in rocks, minerals, and the earth, with application to oil exploration and terrestrial studies; and index.
DescriptionCEH - Quest CCMAP see http://quest.bris.ac.uk/research/themes/CCMAP.html CCMAP (Climate-carbon modelling, assimilation and prediction) Leader: Dr. Eleanor Blyth (CEH, Wallingford) Overview and Goals CCMAP is one of QUEST's Theme 1 projects and is about to be commissioned to the Centre for Ecology and Hydrology at Wallingford. The Principal Investigator will be Dr. Eleanor Blyth, with subcontracts to the Universities of Bristol (Dr. Wolfgang Knorr, Earth Sciences and QUEST; Andy Ridgw [continued...
Three independent studies have been conducted for assessing the impact of rocket launches on the earth`s environment. These studies have addressed issues of acid rain in the troposphere, ozone depletion in the stratosphere, toxicity of chemical rocket exhaust products, and the potential impact on global warming from carbon dioxide emissions from rocket launches. Local, regional, and global impact assessments were examined and compared with both natural sources and anthropogenic sources of known atmospheric pollutants with the following conclusions: (1) Neither solid nor liquid rocket launches have a significant impact on the earth`s global environment, and there is no real significant difference between the two. (2) Regional and local atmospheric impacts are more significant than global impacts, but quickly return to normal background conditions within a few hours after launch. And (3) vastly increased space launch activities equivalent to 50 ...
Interfacial tension in the system toluene solution of di-2-ethylhexylphosphoric acid HDEHP-aqueous solutions of inorganic salts has been measured by the drop volume method. The ion-exchange constants in the monolayers formed by HDEHP and alkaline-earth metals have been measured.