WorldWideScience
1

Graphite as negative electrode in Li-ion batteries; Le graphite comme electrode negative dans les accumulateurs Li-ion  

Energy Technology Data Exchange (ETDEWEB)

The last developments in lithium batteries design have demonstrated the advantages of graphite: competitive cost, flat output curve, high capacity thanks to the obtention of a final compound close to LiC{sub 6}, good behaviour during cycling and a high mass energy. However, these advantages are slightly tarnished by parasite secondary reactions during the evolution of the element. Two different cases are encountered: the formation of a passivation layer (loss of Li ions and formation of irreversible bounds) and the formation of a passivation layer with a reaction between graphite and the solvent (partial destruction of the graphite crystal lattice). In the first case, the theoretical graphite insertion capacity remains at 372 mAh/g while in the second case the insertion capacity is greatly reduced. Abstract only. (J.S.)

1996-12-31

3

Ambassade Des Etats-Unis Kinshasa, Congo - Accueil  

Science.gov (United States)

sur la médiatisation des élections Il s'est ouverte le 16 septembre 2011 à Matadi dans le Bas-Congo une formation sur la médiatisation des questions électorales,...

2011-10-13

4

Scenario-Based Actions to Upgrade Small-Scale Furniture Producers and their Impacts on Women in Central Java, ...  

Science.gov (United States)

... Producers and their Impacts on Women in Central Java, IndonesiaActions basées sur des scénarios visant à élever ... impact sur les femmes dans le centre de Java, en IndonésieInvestigación-acción basada en...

5

A progress for the health of south countries. The solar refrigerator; Un progres pour la sante dans les pays du Sud. Le refrigerateur solaire  

Energy Technology Data Exchange (ETDEWEB)

In order to conserve vaccines in hot countries a solar refrigerator has been made by a French university. It is a photothermal refrigerator without batteries. It uses two gases: ammonia and calcium chloride. The refrigerator is autonomous and can work eleven days without sun. (N.C.)

1998-05-01

6

LA GOUVERNANCE PAR L EVALUATION. LES QUASI MARCHES DANS LES SERVICES A DOMICILE  

British Library Electronic Table of Contents (United Kingdom)

RESUME: Cet article propose une tude du r le croissant que joue l valuation dans la gouvernance des services domicile en Europe. L introduction de quasi march s dans plusieurs pays europ ens va de pair avec un processus d autonomisation de la fonction d valuation qui devient un v ritable outil de r gulation de la concurrence. Une analyse compar e des situations en Belgique, France et Royaume Uni, tant de la demande que de l offre de services, met en vidence les tensions r currentes dans les objectifs de l valuation (qualit des services, ma trise des budgets sociaux, cr ation d emploi), la faible prise en compte de la qualit de l emploi ainsi que les limites des dispositifs standardis s d valuation au regard de la rh torique du libre choix de l usager (consommateur).

2010-01-01

7

Multicentre, randomised, controlled study of the impact of continuous sub-cutaneous glucose monitoring (GlucoDay) on glycaemic control in type 1 and type 2 diabetes patients  

British Library Electronic Table of Contents (United Kingdom)

ResumeObjectif determiner dans une etude randomisee l'impact d'un enregistrement continu du glucose sous-cutane pendant 48 heures sur le controle glycemique trois mois plus tard chez des patients presentant un diabete de type 1 (DT1) ou de type 2 (DT2). Methodes Quarante-huit patients avec un mauvais equilibre glycemique (HbA1c : 8-10,5 %) ont beneficie d'un enregistrement continu du glucose sous-cutane pendant 48 heures avec le systeme GlucoDay (A. Menarini Diagnostics) et ont ete randomises en deux groupes : ajustement de traitement en fonction de l'autosurveillance glycemique capillaire (groupe ASG) ou du profil d'enregistrement continu du glucose sous-cutane (groupe CGM). Le dosage d'HbA1c et le port du GlucoDay ont ete renouveles trois mois plus tard. Resultats Trente-quatre patients ...

2009-01-01

8

Development of time-resolved laser fluorescence spectrometry for on-line uranium checking in solutions of the Purex reprocessing process; Developpement de la spectrofluorimetrie laser a resolution temporelle pour le controle en ligne de l`uranium dans les solutions du procede de retraitement purex  

Energy Technology Data Exchange (ETDEWEB)

The Purex process and the fluorescence spectrometry are first recalled, then uranyl fluorescence is studied in a pure nitric medium without other elements to establish a theoretical model, allowing the description of uranium fluorescence signal with a general equation. The influence of different parameters (temperature, inhibitors, dynamic quenching of iron and cerium) is investigated to develop the model. A quantitative analysis method without addition of reagents is proposed to validate the model.

1992-02-25

9

Description of modelling to be implemented in the fuel rod thermomechanics code Cyrano3; Description des modeles a introduire dans le logiciel de thermomecanique du crayon combustible Cyrano3  

Energy Technology Data Exchange (ETDEWEB)

CYRANO3 is the new EDF thermomechanical code developed to evaluate the overall fuel rod behavior under irradiation. In that context, this paper presents the phenomena to be simulated and the correlations adopted for modelling purposes. The empirical models presented are taken from the CYRANO2 code and a compilation of the relevant literature. The present revision corrects and supplements version B on the basis of its use during the software coding phase from January 1991 to May 1993. (authors). figs., tabs., 120 refs.

1993-06-01

10

Certified Reference Materials (CRM) for the quality control of metals chemical forms determinations in environment, in support to the European Union legislation; Materiaux de reference certifies pour le controle de qualite des determinations de formes chimiques des metaux dans l`environnement, en soutien a la legislation de l`Union Europeenne  

Energy Technology Data Exchange (ETDEWEB)

This work gives a global view of legislations in which are included metals chemical states, briefly recalls the conditions to be respected for the CRM (Certified Reference Materials), and describes the results of some current plans for the Norms, Measures and Tests program. (O.M.) 23 refs.

1997-03-01

11

Adsorption based processes as alternative to common gas conditioning at underground storage facilities using Sorbead; Procedes bases sur l'adsorption comme solution de rechange dans le conditionnement du gaz dans des lieux de stockage souterrains a l'aide de Sorbead  

Energy Technology Data Exchange (ETDEWEB)

The European gas market is continuing to expand due to increased industrial, domestic and power generation demand. As a result of this demand, and the trend toward liberalization of the market, the need for storage of gas is also increasing. One key segment of the large scale storage of gas is underground storage, either in partially depleted gas or oil fields, naturally occurring caverns, aquifers and salt cavities. In most cases the gas produced after storage requires conditioning to meet the water of hydrocarbon dew point specification of the gas transmission system. For that reason export gas from storage will require gas conditioning in order to meet pipeline specifications. Adsorption as a feasible and reliable process will be presented in detail and especially in regards to hydrocarbon dew-pointing compared with other process options. (author)

2000-07-01

12

Use of semi-detailed kinetic schemes for a study of the temperature dependence in the reforming of fuels without catalyst; L'utilisation de schemas cinetiques semi-detailles pour une etude de l'influence de la temperature dans le reformage de combustibles sans catalyseur  

Energy Technology Data Exchange (ETDEWEB)

In order to avoid the use of catalysts in the process of auto-thermal reforming, it is possible to adopt a running at high temperature. In this study are presented the results of simulations of an auto-thermal/recuperator hybrid reforming system; these results are obtained with the oxidation model of alkanes developed by Ranzi and Faravelli. An isothermal configuration at high temperature improves the hydrogen yield and avoids the formation of soots. The analysis of the powers to be furnished to assure such an experimental mode, and the global approach of the fuel cell system show that the management of the heat exchanges is a key parameter in this process. (O.M.)

2000-07-01

13

Radon as a tracer of fluids motion in karstic aquifers; Le radon: traceur des circulations fluides dans les aquiferes karstiques  

Energy Technology Data Exchange (ETDEWEB)

Radon ({sup 222}Rn) is a naturally occurring radioactive gas and can be used as a tracer in hydrogeologic studies. Radon concentration measurements have been achieved in ground-air and in groundwater by means of nuclear track detectors to estimate long-term variations. Continuous measurements have been conducted using an electronic automatic probe, to evaluate short-term variations. The results obtained from bore-holes show a good correlation between the aquifer`s structural characteristics and the radon concentrations. The continuous measurements specify rainfall influence. (author). 10 refs., 7 figs., 2 tabs.

1995-04-01

14

Unique effect of mechanical crushing on the electrochemical intercalation of lithium in carbons of different morphologies; Effet unique du broyage mecanique sur l`intercalation electrochimique du lithium dans des carbones de morphologies differentes  

Energy Technology Data Exchange (ETDEWEB)

Lithium ion batteries use an oxide as a positive electrode and a carbon material as a negative electrode. The performances of carbon electrodes have rapidly evolved during the last years thanks to the substitution of soft carbons of Conoco or MCMB-2510 type by graphites (F-399, MCMB-2528) and then by hard carbons. These high capacity carbons (700 mAh/g) have higher service life and volume capacity than graphites but their irreversible losses are greater (>20%). In this work, materials with similar electrochemical performances are prepared by mechanical crushing. Mechanical crushing allows to obtain a wide range of carbon materials with various morphologies, specific surfaces and levels of disorder. The formation of the passivation film is directly linked with the surface of materials. A reaction scheme of the reversible and irreversible capacities has been defined and has permitted to obtain compounds with reversible capacities of 720 mAh/g ...

1996-12-31

15

Temporal measures and controls in ultrafast laser domain; Mesures et controles temporels dans le domaine des lasers ultrabrefs  

Energy Technology Data Exchange (ETDEWEB)

This work presents the development of a streak camera 'jitter free' sweep unit synchronized on a femtosecond laser. This application of high voltage photoconductive switches ('High voltage Auston switch') yields subpicosecond resolution for accumulated images on streak camera on a few hundreds micro joule femtosecond laser. Two others applications of these photoconductive switches are studied: - ultrafast optical commutation by a Pockels cell directly driven by a photoconductive switch (rising edge < 100 ps and jitter < 2 ps), - laser pulse energy self-stabilization experimentally proving that driving a Pockels cell by a photoconductive switch can increase the stability of the laser pulse energy from 7 % to 0.7 % rms. Additionally, the application of the acoustic-optical programmable dispersive filter (Dazzler) to the self referenced spectral phase measurement is presented. As these measurements require a linear filter combined with a ...

2004-12-15

16

Solar energy in buildings; L'energie solaire dans le batiment  

Energy Technology Data Exchange (ETDEWEB)

This document gathers the presentations given at the first French national meetings of solar energy for the development of solar systems in buildings. The meeting was organized over two days. The first day comprises 4 workshops about: urbanism and planning, cultural acceptability of solar energy in buildings (the OPAC 38 housing association, point of view on an energy information point, the Freiburg (Germany) solar region and marketing examples), technical integration to the structure (Clipsol solutions), and economical criteria (compared impacts of R and D public photovoltaic programs (USA, Japan, Germany, France, Italy), financing of rehabilitation projects, global approach of solar photovoltaic energy, technical solutions and strategy of products development, why and how to make an economical analysis of solar energy applications in the building industry). The second day comprises a plenary session and a round table: global status of solar energy development in Europe, status of ...

2003-07-01

17

Photovoltaic solar power in building engineering. Experience feedback in France of the European Hip Hip project. Advances and realizations; L'electricite solaire photovoltaique dans le batiment. Retour d'experience en France du Projet Europeen Hip Hip. Avancees et realisations  

Energy Technology Data Exchange (ETDEWEB)

The European demonstration project Hip Hip (house integrated photovoltaic high-tech in public) led the French photovoltaic market to reach a level comparable to those of the other European countries in terms of relevance of implemented solutions and costs. This document presents the best realizations and the experience gained through the Hip Hip project. Its aim is to convince the designers and managers of building projects of the advantages of photovoltaic installations integrated to the structure and connected to the power distribution grid: 1 - presentation of the technology; 2 - status of the Hip Hip demonstration project (goals, results: main innovations and impact on the French market); 3 - different possibilities of integration to the building structure; 4 - examples of projects realized in France in the framework of the Hip Hip project: integration in glass roof, frontage, added elements, fitting on roofs. (J.S.)

2003-07-01

18

Methods of selection in heavy ion collisions at Fermi energies and de-excitation modes with the INDRA multi-detector; Methodes de tri dans les collisions d'ions lourds aux energies de Fermi et modes de desexcitation avec le multidetecteur INDRA  

Energy Technology Data Exchange (ETDEWEB)

The progress made in particle detection, particularly the design of multi-detectors, like INDRA, that cover a solid angle of almost 4{pi}, have given a new impetus to heavy ion collisions. These detectors are demanding for an efficient way of selecting events that have a common history or similar features, for instance the events representing the de-excitation of a unique emitter. The problem is to find the adequate variable on which the discrimination can be based. Different methods are proposed in this work, the common point is that they require efficient models to reproduce and analyse experimental data in order to apprehend the equation of state of nuclear matter. Most of these models are based on the numerically solving of the nuclear Boltzmann equation. The application to the Ni + Ni reaction with an energy ranging from a few A.MeV to more than 50 A.MeV illustrates this work. (A.C.)

2005-11-15

19

Lessons drawn from the accidents occurred in the framework of conventional external radiotherapy;Lecons tirees des accidents survenus dans le cadre de la radiotherapie externe conventionnelle  

Energy Technology Data Exchange (ETDEWEB)

This study examines some radiation accidents occurred in the past. This information has been systematically assessed to get global lessons. The experience feedback shows that the most of accidents happened in certain conditions. These conditions can be distributed in four categories: 1- perception and vigilance in occupation: accidental exposure happened by lack of vigilance in details and lack of vigilance and perception; 2- procedures: accidental exposure happened following a lack of procedures or control that were not enough complete, not enough documented or not completely implemented; 3- training and understanding: accidental exposures happened because the personnel was not enough qualified and educated, did not get the general training nor the the necessary specialized training; 4- liabilities: accidental exposures happened following lacks and ambiguity in the definition of functions of the personnel and in the hierarchy liabilities. In these precise cases the safety tasks have ...

2009-12-15

20

France, an international partner in the climate change field; La France, partenaire international dans le domaine du changement climatique  

Energy Technology Data Exchange (ETDEWEB)

Cooperation for low carbon and energy efficient development is a high priority for France, in line with the United Nations Framework Convention on Climate Change. France contributes to tackling climate change by working with its partners on all continents to implement projects both to mitigate greenhouse gas emissions and to adapt to climate change. Within the framework of the Marrakech Accords, France also encourages the implementation of the Kyoto Protocol Clean Development Mechanism, in particular between French business and non-Annex I countries; this mechanism will facilitate the financing of mitigation projects and contribute to the sustainable development of host countries in the South. At multilateral level, France is a major donor. At a bilateral level, an initial analysis of cooperation projects which are strongly linked to tackling climate change identified public support of 136 millions euros per year, as an average over the past few years. Some project examples, mostly ...

2004-07-01

21

Eddy currents signal processing for steam generator inspection in PWR nuclear power plants; Traitement des signaux de courants de Foucault pour le controle des tubes de generateurs de vapeur dans les centrales nucleaires REP  

Energy Technology Data Exchange (ETDEWEB)

Steam generator tubes in nuclear power plants are periodically checked by means of eddy current probes. The output of a probe is composed of three types of signals: known events (rolling zone, support plates, U-bend part), noise (mainly metallurgical noise) and possible flaws. The latter are random transients, both in arrival time and in shape: they have to be detected and then estimated, before to be fed to the high level stages of a diagnostics system. The objective of the study presented is to develop a semi-automatic system, which could manage and process more than 1 M-bytes of data per tube and provide an operator with reliable diagnostics proposals within a few minutes. This can be achieved only by cooperation of several digital signal processing techniques: detection, segmentation, estimation, noise subtraction, adaptive filtering, modelization, pattern recognition. The paper describes some of these items.

1991-07-01

22

Eddy currents signal processing for steam generator inspection in PWR nuclear power plants. Traitement des signaux courants de Foucault pour le controle des tubes de generateurs de vapeur dans les centrales nucleaires REP  

Energy Technology Data Exchange (ETDEWEB)

Steam generator tubes in nuclear power plants are periodically checked by means of eddy current probes. The output of a probe is composed of three types of signals: known events (rolling zone, support plates, U-bend part), noise (mainly metallurgical noise) and possible flaws. The latter are random transients, both in arrival time and in shape: they have to be detected and then estimated, before to be fed to the high level stages of a diagnostic system. The objective of the study presented is to develop a semi-automatic system, which could manage and process more than 1 M-bytes of data per tube and provide an operator with reliable diagnostics proposals within a few minutes. This can be achieved only by cooperation of several digital signal processing techniques: detection, segmentation, estimation, noise subtraction, adaptive filtering, modelization, pattern recognition. The paper describes some of these items.

1992-01-01

23

Are the French authorities beginning to prepare for nuclear accident?; Introduction a la prise en compte de l'accident nucleaire par les autorites francaises?  

Energy Technology Data Exchange (ETDEWEB)

This article, published in issue 80 of 'l'ACROnique du nucleaire', aims to retrace the early steps in the consideration of the possibility of a nuclear accident in France, with the inclusion of 'non-institutional' participants and applying the lessons learned in Belarus in the contaminated territories around the Chernobyl nuclear power plant. After a review of the origin of the involvement of the Association pour le Controle de la Radioactivite dans l'Ouest (ACRO) in addressing post-accident issues alongside the populations living in an environment polluted by radioactivity, it discusses, from the critical viewpoint of an NGO, the context and the working method adopted for this examination. This is followed by some key elements of the programme and unresolved questions about the available body of knowledge which motivates research and about the method adopted for the work. The conclusion, ...

2008-07-15

24

Law project adopted by the Senate and authorizing the ratification of the additional protocol to the agreement between France, the European atomic energy community and the international atomic energy agency relative to the application of warranties in France; Projet de loi adopte par le Senat autorisant la ratification du protocole additionnel a l'accord entre la France, la Communaute europeenne de l'energie atomique et l'Agence internationale de l'energie atomique relatif a l'application de garanties en Franc  

Energy Technology Data Exchange (ETDEWEB)

This project of law concerns an additional protocol to the agreement of warranties signed on September 22, 1998 between France, the European atomic energy community and the IAEA. This agreement concerns the declaration of all information relative to the R and D activities linked with the fuel cycle and involving the cooperation with a foreign country non endowed with nuclear weapons. These information include the trade and processing of nuclear and non-nuclear materials and equipments devoted to nuclear reactors (pressure vessels, fuel loading/unloading systems, control rods, force and zirconium tubes, primary coolant pumps, deuterium and heavy water, nuclear-grade graphite), to fuel reprocessing plants, to isotope separation plants (gaseous diffusion, laser enrichment, plasma separation, electromagnetic enrichment), to heavy water and deuterium production plants, and to uranium conversion plants. (J.S.)

2002-10-01

25

Trace elements and radioactivity measurements in some terrestrial food crops in Jos-plateau, north central, Nigeria; Elements traces et mesures de la radioactivite dans quelques recoltes vivrieres terrestres du plateau de Jos dans le centre-nord du Nigeria  

Energy Technology Data Exchange (ETDEWEB)

Some crops of important nutritive requirements have been collected from farmlands located in Bitsichi an old tin mining town in north central region of Nigeria. The food crops were analyzed in order to determine trace element concentrations level using Neutron Activation Analysis (NAA). The activity concentrations due to natural radionuclides in the food samples and soil samples collected within the root zone of the crops were also determined using gamma-ray spectrometry (GRS). The NAA results obtained showed higher concentration of Potassium among the essential elements in all the crops. Calcium concentration in both maize and Guinea corn was below detection limit and also Zn in Green beans, sweet potato and cassava. The trace elements; Sc, Hf, Sm, and Th, were below detection limit in all the crops except in Green beans. Rubidium (Rb) and lanthanum (La) were below detection limits only in Cabbage. The activity concentrations of the natural radionuclides in the food samples were found ...

2007-01-15

26

Damage and Repair of the APS Graphite/Epoxy Composite ...  

Science.gov (United States)

... Abstract : High temperature testing of graphite/epoxy laminates and composite sandwich panels was performed while the Shuttle was on orbit to ...

1982-10-12

27

World review of ozone forecasting methods and roles; Prevision des episodes d`ozone: etat de l`art dans le monde  

Energy Technology Data Exchange (ETDEWEB)

The growing concern of the population with regards to the problem of atmospheric pollution has induced a change in the role of air quality monitoring networks, especially those monitoring air pollution in large cities which suffer from summer smog. The population is no longer satisfied with real-time measurements but wants to be warmed of high pollutants concentrations in advance. Some countries have been forecasting air pollution, and especially ozone, for a large number of years. Although most of them use statistical models based on the analyses of past conditions which induced high pollution episodes, some predict ozone levels using only their knowledge of the meteorological situation. Nowadays two trends appear regarding ozone forecasting: either very basic statistical methods, such as regression, or more sophisticated ones, such as neural networks. The paper then reviews several behaviours common to most forecasting models: the uncertainly due to the great dependence upon the ...

1997-04-01

28

Search for supersymmetry in 2 different topologies with the L3 detector at Lep; Recherche de supersymetrie dans les canaux avec un ou deux leptons avec le detecteur L3 a LEP  

Energy Technology Data Exchange (ETDEWEB)

The present thesis presents two different aspects of my work in the L3 experiment, which are on one side the search for supersymmetric particles, the scalar leptons, in two different topologies 'electron + X + E' and '2 leptons + 2 photons + E', each of them being related to two theoretical SUSY models, m-SUGRA and GMSB. On the other side my work has been completed by the study of the BGO crystal electromagnetic calorimeter of L3, and the calibration of the electromagnetic calorimeter EGAP. After the essential motivations being reviewed, the production and disintegration modes are detailed concerning the scalar lepton sector at LEP. Then one presents the analysis techniques which I used to perform my selection, and also the results obtained from the data collected by L3 for center of mass energies between {radical} S =183 GeV and 202 GeV. The selection criteria that allow to isolate the events I looked for, including efficiencies but also the ...

2000-11-13

29

Search for new physics in the jets and missing transverse energy topology with the D0 detector at the Tevatron; Recherche de nouvelle physique dans la topologie a jets et energie transverse manquante avec le detecteur D0 au TeVatron  

Energy Technology Data Exchange (ETDEWEB)

Although the standard model of particle physics agrees perfectly with experimental data, it is unlikely the final theory describing particles and their interactions. New phenomena has been searched in the jets and missing transverse energy topology. Such phenomena may be due to the pair production of leptoquarks decaying into a quark and a neutrino or the pair production of stops decaying into a charm and a neutralino which is assumed to be the lightest supersymmetric particle. These searches have been performed with the Ddiamter detector at hadronic collider TeVatron with a center of mass energy of 1.96 TeV. This kind of searches needs a good understanding of the jet energy calibration. The determination of the relative jet energy scale has allowed us to reduce the systematic uncertainties on the jet energy measurement when comparing the data and the simulation. Moreover a new method has been developed in order to correct simulated jets for the differences observed in the jet energy ...

2006-05-15

30

Proceedings of MEND 2000 symposium : research on innovative methods to control acid mine drainage; Comptes rendus du NEDEM 2000 : colloque sur la recherche de methodes innovatrices pour le controle du drainage minier acide  

Energy Technology Data Exchange (ETDEWEB)

The 24 papers presented at the conference on Neutralisation des eaux de drainage dans l'environnement minier (NEDEM) (Mine Environment Neutral Drainage (MEND)) 2000 symposium on research on innovative methods to control acid mine drainage, covered eight sessions with both technical and general interest papers. The technical papers covered the topics of acid mine drainage and remediation measures, such as flooding, soil cover with various materials, encapsulation, and others. Other topics discussed included the freeze-thaw cycle and its effect on the performance of soil covers. The environmental impacts of acid mine drainage were also described. Some case studies were included to further illustrate the environmental impacts of acid mine drainage and to demonstrate the effectiveness of remedial actions in specific situations. Most of the cases studied were mines located in Quebec and Northern Ontario, with some in British Columbia. The general interest ...

2000-07-01

32

A.C.R.O. activity report 2003; A.C.R.O. rapport d'activite 2003  

Energy Technology Data Exchange (ETDEWEB)

A.C.R.O. (Association pour le Controle de la Radioactivite dans l'Ouest) is a French non governmental organisation that operates a laboratory for radioactivity analysis. It was created in 1986 as a response to people demands for information and reliable, independent testing. The organisation mainly carries out missions of information and training for its correspondents and more generally for a wide audience, particularly for people who worry about problems of environment, health, management of radioactive waste and emissions. Thanks to its structure, it enables citizens to involve themselves together with scientists so as to gain access to information that was hither to reserved to specialists. The organisation can vouchsafe its independence from the diversity of its members and volunteers, as well as from the diversity of its money resources. Besides its headquarters situated on the city of Caen area (Normandy), three branches ...

2003-07-01

33

The influence of an intramolecular H-bond on the adsorption of sulfur-containing amino acids on graphitized thermal carbon black  

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption of sulfur-containing amino acids and their derivatives on the surface of graphitized thermal carbon black were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the S atom in amino acids and the graphite C atom were determined. It was shown that an intramolecular H-bond influenced the adsorption of amino acids on the surface of graphitized thermal carbon black.

2009-01-01

34

The influence of an intramolecular H-bond on the adsorption of sulfur-containing amino acids on graphitized thermal carbon black  

Science.gov (United States)

The thermodynamic characteristics of adsorption of sulfur-containing amino acids and their derivatives on the surface of graphitized thermal carbon black were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the S atom in amino acids and the graphite C atom were determined. It was shown that an intramolecular H-bond influenced the adsorption of amino acids on the surface of graphitized thermal carbon black.

2009-04-01

37

Theoretical calculation for the elastic wave velocities and thermodynamic functions of graphite  

International Nuclear Information System (INIS)

Based on the generalized gradient approximation (GGA) of density functional theory (DFT) and the full-potential linearized augmented plane wave (FLAPW) at the level including all electrons, the lattice parameters of graphite are calculated and optimized. Some elastic wave velocities transmitted in graphite are deduced. Using the methods of elastic wave velocity method and the atomic displacement method, the Debye frequency of graphite is obtained. The standard heat capacity, entropy, sublimation enthalpy of graphite is deduced at 289.5 k and 1 atm. The calculated results are discussed and compared with experimental data. (authors)

2006-06-01

38

Development of Lead-Free Copper Alloy-Graphite Castings  

Energy Technology Data Exchange (ETDEWEB)

In this project, graphite is used as a substitute for lead in order to maintain the machinability of plumbing components at the level of leaded brass. Graphite dispersed in Cu alloy was observed to impart good machinability and reduce the sizes of chips during machining of plumbing components in a manner similar to lead. Copper alloys containing dispersed graphite particles could be successfully cast in several plumbing fixtures which exhibited acceptable corrosion rate, solderability, platability, and pressure tightness. The power consumption for machining of composites was also lower than that of the matrix alloy. In addition, centrifugally cast copper alloy cylinders containing graphite particles were successfully made. These cylinders can therefore be used for bearing applications, as substitutes for lead-containing copper alloys. The results indicate that copper graphite alloys ...

1999-10-01

39

Development of lead-free copper alloy-graphite castings. Technical report, January 1994--December 1994  

Energy Technology Data Exchange (ETDEWEB)

Water model experiments were conducted to develop a two-stage stirring method for obtaining higher yields and a more uniform distribution of graphite particles in copper alloys. This was followed by several melts for synthesis of copper-graphite alloys in which Ti was used as a wetting agent to improve the wettability of graphite in the copper melt. In the first stage, a vortex method was employed to facilitate the addition of graphite particles into the copper melt. In the second stage, a specially designed stirrer was used for uniform particle distribution while avoiding the formation of vortex in the melt. The two-stage stirring was found to considerably improve the recovery of graphite, over those obtained with the prior practice of single-stage stirring and resulting in a more uniform particle distribution. In addition, graphite recoveries increased with ...

1995-07-01

40

Development of lead-free copper alloy graphite castings. Annual report, January--December 1995  

Energy Technology Data Exchange (ETDEWEB)

The distribution of graphite particles in graphite containing copper alloy was further improved very significantly using several procedures and technological modifications. The developed techniques attacked the graphite distribution problem in two ways. Realizing that clustering of very fine (5um) graphite particles is one of the two major problems, a pretreatment process has been developed using aluminum powders to deagglomerate graphite particles. Along with this, a two-stage stirring technique was used to first incorporate and then to distribute uniformly the deagglomerated particles in the melt. During this year, based on these developments, several components were cast to evaluate the castability of Cu alloy-graphite melts. In addition, machinability tests were done to clearly established that addition of graphite particles improve the ...

1996-10-01

41

Electrochemical properties of Si/Ni alloy-graphite composite as an anode material for Li-ion batteries  

International Nuclear Information System (INIS)

Si/Ni alloy and graphite composites were synthesized using arc-melting followed by high energy mechanical milling (HEMM). Alloy particles comprising of NiSi2, NiSi and Si phases were distributed finely and uniformly on the surface of graphite in the composites obtained after Hem. The composite containing 60 wt.% of Si/Ni alloy exhibited a stable capacity of ?780 mAh/g. Fourier transform infrared spectroscopy (FTIR) analysis confirmed that some bonds were formed between alloy and graphite after HEMM, which appeared to retain the electrical connection between alloy and graphite during cycling. X-ray diffraction (XRD) analysis indicated that NiSi2 and NiSi phases, which acted as an inactive alloy matrix remained invariant during charge and discharge. In addition to NiSi2 and NiSi phases, disordered graphite layers also played the role of media for the accommodation of large volume ...

2005-09-30

43

Single-Walled Carbon Nanotubes Targeted to the Tumor ...  

Science.gov (United States)

... 1981. Retention of diphenyls, terphenyls, phenylalkanes and fluorene on graphitized thermal carbon black. Chromatographia 14:510-514. ...

2009-09-01

45

Calculation of henry constants for the adsorption of isomeric phenylenediamines on graphitized thermal carbon black  

British Library Electronic Table of Contents (United Kingdom)

Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433?479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.

2009-01-01

46

Calculation of henry constants for the adsorption of isomeric phenylenediamines on graphitized thermal carbon black  

Science.gov (United States)

Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433-479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.

2009-12-01

47

A.C.R.O. activity report 2002; A.C.R.O. rapport d'activite 2002  

Energy Technology Data Exchange (ETDEWEB)

A.C.R.O. (Association pour le Controle de la Radioactivite dans l Ouest) is a French non governmental organisation that operates a laboratory for radioactivity analysis. It was created in 1986 as a response to people demands for information and reliable, independent testing. The organisation mainly carries out missions of information and training for its correspondents and more generally for a wide audience, particularly for people who worry about problems of environment, health, management of radioactive waste and emissions. Thanks to its structure, it enables citizens to involve themselves together with scientists so as to gain access to information that was hither to reserved to specialists. The organisation can vouchsafe its independence from the diversity of its members and volunteers, as well as from the diversity of its money resources. Besides its headquarters situated on the city of Caen area (Normandy), three branches situated in ...

2002-07-01

48

Study on the structural evolution of modified phenol-formaldehyde resin adhesive for the high-temperature bonding of graphite  

International Nuclear Information System (INIS)

A novel adhesive for carbon materials composed of phenol-formaldehyde resin, boron carbide and fumed silica, was prepared. The adhesive property of graphite joints bonded by the above adhesive treated at high-temperatures was tested. Results showed that the adhesive was found to have outstanding high-temperature bonding properties for graphite. The adhesive structure was dense and uniform even after the graphite joints were heat-treated at 1500 deg. C. Bonding strength was 17.1 MPa. The evolution of adhesive structure was investigated. The results indicated that the addition of the secondary additive, fumed silica, improved the bonding performance greatly. Borosilicate phase with better stability was formed during the heat-treatment process, and the volume shrinkage was restrained effectively, which was responsible for the satisfactory high-temperature bonding performance of graphite.

2006-01-01

49

Graphite Technology Development Plan  

Energy Technology Data Exchange (ETDEWEB)

This technology development plan is designed to provide a clear understanding of the research and development direction necessary for the qualification of nuclear grade graphite for use within the Next Generation Nuclear Plant (NGNP) reactor. The NGNP will be a helium gas cooled Very High Temperature Reactor (VHTR) with a large graphite core. Graphite physically contains the fuel and comprises the majority of the core volume. Considerable effort will be required to ensure that the graphite performance is not compromised during operation. Based upon the perceived requirements the major data needs are outlined and justified from the perspective of reactor design, reatcor performance, or the reactor safety case. The path forward for technology development can then be easily determined for each data need. How the data will be obtained and the inter-relationships between the experimental and modeling ...

2007-09-01

52

Huo-Luo-Xiao-Ling Dan modulates antigen-directed immune response in adjuvant-induced inflammation  

UK PubMed Central (United Kingdom)

Ethnopharmacological relevanceHLXL is a traditional Chinese medicine that has long been used in folk medicine for the treatment of chronic inflammatory diseases....Full Text Available

2009-05-04

53

* NASA TECHNICAL TRANSLATION NASA TT F-11435 INFLUENCE OF ...  

Science.gov (United States)

isotherme, dans un courant d'azote ou sous vide entretenu. I t. Comptes Rendus Scientific Academy, Paris, Vol. 265 pyrolyse du carbonate de calcium, ...

54

Contribution of the pectin in the cesium elimination in organism. results of analysis on Belarus children; Du role de la pectine dans l'elimination du cesium dans l'organisme. Resultats d'analyses sur des enfants bielorusses  

Energy Technology Data Exchange (ETDEWEB)

The results make appear that the cesium 137 would be eliminated less quick than what the ICRP considered for its models. Pectin would accelerate the cesium elimination but less quick than what is announced by its promotors. Politically speaking, the pectin is ignored by the officials of medicine and radiation protection at the pretext that its efficiency is not proved but no study is made. (N.C.)

2007-07-01

55

COURSE D'ORIENTATION  

CERN Multimedia

  Le Club d’Orientation du CERN vous propose de venir participer à la cinquième étape de la coupe d’automne Genevoise. Celle-ci sera organisée samedi 16 octobre par le club de Lausanne-Jorat (Canton de Vaud). Un fléchage depuis le Mont-sur-Lausanne en direction de Cugy vous conduira au Chalet à Gobet. 5 circuits seront proposés sur la carte Le Flon. Les inscriptions et les départs se feront sur place de 13h à 15h. Il est prévu une initiation à 13h30 pour les débutants. Les deux dernières étapes de la coupe d’automne sont prévues pour vendredi 22 octobre au soir et samedi 23 octobre après-midi. Le Club d’Orientation du CERN Informations sur ...

2010-01-01

59

National Response Center Intro Page  

Science.gov (United States)

operations and defense, personnel misconduct (PM), law enforcement (LE), and counterintelligence (CI) investigations.- At any time, the USG may inspect and seize data stored on...

2011-02-28

60

Inventarisatie telematica-ontwikkelingen Natco (Inventory ...  

Science.gov (United States)

... In Nederland wordt het telewerken bevorderd door bet Nederlands Telewerk Forum, waarin zowel de overheid als verschillende industri~le ...

1998-05-01

61

Analyse Exploitatiekosten: Registratie, Beheersing en ...  

Science.gov (United States)

... Opbrengsten in LCC analyses: baten. bate n- lastenstelIselI bij de overheid ell baten le bepalen. " Onzekerheid in LCC analyses. ...

2007-10-01

62

An experimental and molecular-statistical study of the adsorption of the iodobenzene, 2-iodothiophene, and isomeric iodoadamantane molecules on the graphite basal face surface  

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption of iodobenzene, 2-iodothiophene, and 1- and 2-iodoadamantanes on the surface of graphitized thermal carbon black were determined experimentally. The influence of the special features of the molecular structure of the adsorbates on the thermodynamic characteristics of adsorption was studied. The atom-atom approximation of the semiempirical molecular-statistical theory of adsorption was used to calculate the thermodynamic characteristics of adsorption of the adsorbates using the newly determined potential function parameters of pair intermolecular interaction (?(r)) of I with C atoms of the basal graphite face. For the example of isostructural monohalogenated benzenes, thiophenes, and adamantanes, a comparative analysis of the contributions of ...

2011-01-01

63

Ultimate Compressive Strength and Nonlinear Stress-Strain ...  

Science.gov (United States)

... Accession Number : ADD421949. Title : Ultimate Compressive Strength and Nonlinear Stress-Strain Curves of Graphite/Epoxy Laminates,. ...

1976-10-12

64

Search Results - NASA Technical Reports Server  

Science.gov (United States)

The influence of ablation on stagnation region convective heating for ... and thermal properties of this fiber depend on the fluorination process ... However, these properties are between those of graphite and those of PTFE (Teflon). ...

65

Molten Boron Phase-Change Thermal Energy Storage ...  

Science.gov (United States)

... Advanced thermal storage systems based on very high temperature solid materials such as boron carbide or graphite have been investigated for ...

2011-06-01

66

Light Weight Composite Mirrors for Science Instruments  

Science.gov (United States)

Light Weight Composite Mirrors for Science Instruments. Composite Optics, Inc. San Diego, CA. INNOVATION. Light weight, large aperture reflectors of graphite ...

67

General Disclaimer One or more of the Following Statements may ...  

Science.gov (United States)

Wit?,-grain ultimate compressive strength of multiply extruded graphite rods made with G-18 flour,. V. 5. " TOTAL n ACCESSIBLE TO Hp AT 2600 psi ...

68

ENGIN\\EE=RING  

Science.gov (United States)

Graphitized thermal carbon black has also been reported by Kalaschinikova et al. (11) to have excellent adsorption properties for CI-C6 alkanes, ...

69

Cycleable graphite/FeSi{sub 6} alloy composite as a high capacity anode material for Li-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

FeSi{sub 6}/graphite composite was prepared by mechanical ball milling. The FeSi{sub 6} alloy particles consist of an electrochemically active silicon phase and inactive phases FeSi{sub 2}, distributed uniformly in the graphite matrix. The composite anode offers a large reversible capacity (about 800 mAh g{sup -1}) and good cycleability, due to the buffering effect of the inactive FeSi{sub 2} phase and graphite layers on the volumetric changes of Si phase during lithium-Si alloying reaction. Since FeSi{sub 6} alloy is a low-cost industrial material, this alloy compound provides a possible alternative for development of high capacity lithium-ion batteries. (author)

2008-10-01

70

An experimental and molecular-statistical study of the adsorption of the iodobenzene, 2-iodothiophene, and isomeric iodoadamantane molecules on the graphite basal face surface  

Science.gov (United States)

The thermodynamic characteristics of adsorption of iodobenzene, 2-iodothiophene, and 1- and 2-iodoadamantanes on the surface of graphitized thermal carbon black were determined experimentally. The influence of the special features of the molecular structure of the adsorbates on the thermodynamic characteristics of adsorption was studied. The atom-atom approximation of the semiempirical molecular-statistical theory of adsorption was used to calculate the thermodynamic characteristics of adsorption of the adsorbates using the newly determined potential function parameters of pair intermolecular interaction (?( r)) of I with C atoms of the basal graphite face. For the example of isostructural monohalogenated benzenes, thiophenes, and adamantanes, a comparative analysis of the contributions of the F, Cl, Br, and I atoms to the thermodynamic characteristics of adsorption was performed for the nonspecific adsorption of these compounds on a plane ...

2011-04-01

71

8 - NASA Technical Reports Server  

Science.gov (United States)

The influence of ablation on stagnation region convective heating for ... and thermal properties of this fiber depend on the fluorination process ... However, these properties are between those of graphite and those of PTFE (Teflon). ...

72

(Hadamard transform imaging)  

Science.gov (United States)

This report describes the design of, and image reconstruction capacity of a Hadamard Raman Microscopic imager. Microscopy of benzoic acid and graphite electrodes, as well as electrophoretic blotting, are described. (CBS)

1990-01-01

73

On the Metastable Level in Ni-like Ions  

Energy Technology Data Exchange (ETDEWEB)

The lowest excited level in Ni-like ions, 3d{sup 9}4s {sup 3}D{sub 3}, decays only via a magnetic octupole (M3) decay. They present calculated values of transition wavelengths and rates for ions with 30 {le} Z {le} 100. They have observed this line in Xe{sup 26+}, using the Livermore EBIT-I electron beam ion trap and a microcalorimeter, as well as a high-resolution flat-field grating spectrometer.

2004-09-14

74

Malignant pulmonary lesion. Possible causes of CT misdiagnosis; Possibilita' di falsi negativi nella diagnosi delle neoplasie polmonari con Tomografia Computerzzata  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work is to describe the radiological appearance of overlooked malignant pulmonary lesions at CT and to analyze the reasons of misdiagnosis. Ten patient with pulmonary lesion (PML) overlooked at forst CT examination were selected among patients with lung cancer. Endobronchial location of the tumors and their small size were the most frequent causes of misdiagnosis of PML at chest CT in the series. However, a systematic evaluation of CT scans can reduce the percentage of missed lesions. [Italian] Scopo del presente lavoro e' di descrivere le caratteristiche radiologiche delle lesioni polmonari maligne non identificate con la Tomografia Computerizzata (TC) e definire le possibili cause di errore. Sono stati esaminato 10 pazienti con tumore polmonare. Le sedi endobronchiale e centrale nonche' le piccole dimensioni delle lesioni polmonari maligne rappresentano ...

1999-06-01

75

The influence of intramolecular H-bond on chromatographic behavior of phenylalkylamines  

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption on the surface of graphitized thermal carbon black at 300 K were determined by the molecular statistical method for three phenylalklylamines. The influence of the intramolecular H-bond on the conformation of the molecules compared with structurally related n-alkyl-benzenes was considered. It was shown that the conformations of the molecules could influence chromatographic retention. Conformational isomers stabilized by intramolecular H-bonds were found to retain their structure in adsorption on graphitized thermal carbon black.

2009-01-01

76

The influence of intramolecular H-bond on chromatographic behavior of phenylalkylamines  

Science.gov (United States)

The thermodynamic characteristics of adsorption on the surface of graphitized thermal carbon black at 300 K were determined by the molecular statistical method for three phenylalklylamines. The influence of the intramolecular H-bond on the conformation of the molecules compared with structurally related n-alkyl-benzenes was considered. It was shown that the conformations of the molecules could influence chromatographic retention. Conformational isomers stabilized by intramolecular H-bonds were found to retain their structure in adsorption on graphitized thermal carbon black.

2009-04-01

77

Silicon nanopowder as active material for hybrid electrodes of lithium-ion batteries  

British Library Electronic Table of Contents (United Kingdom)

Cycling parameters (reversible specific capacity, first-cycle coulombic efficiency, accumulated irreversible capacity, and reversible capacity retention) of hybrid electrodes based on mechanical mixtures of a silicon nanopowder with KS6 and MAG-20 synthetic graphites and binders of varied nature were subjected to an integrated analysis in comparison with graphite electrodes.

2011-01-01

78

Separation of isomers of saturated polycyclic hydrocarbons in packed capillary columns with graphitized thermal carbon black  

Energy Technology Data Exchange (ETDEWEB)

Using the example of perhydrophenanthrene, perhydroanthracene and cyclopentanodecalin isomers a possibility is shown to use packed capillary columns containing graphitized thermal carbon black for a complete separation of high-boiling mixtures of polycyclic saturated hydrocarbon isomers in accordance with the geometric structure of their molecules.

1981-03-01

79

Molecular statistical calculations of the adsorption of proline and its hydroxy derivatives on graphitized thermal carbon black  

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption of proline and its hydroxy derivatives on the surface of graphitized thermal carbon black (GTCB) were calculated. The arrangement of hydroxyl groups in the amino acid molecule was shown to influence their adsorption on GTCB. The influence of internal rotation angles in proline and its hydroxy derivative molecules on their adsorption on GTCB was studied.

2009-01-01

80

Molecular statistical calculations of the adsorption of proline and its hydroxy derivatives on graphitized thermal carbon black  

Science.gov (United States)

The thermodynamic characteristics of adsorption of proline and its hydroxy derivatives on the surface of graphitized thermal carbon black (GTCB) were calculated. The arrangement of hydroxyl groups in the amino acid molecule was shown to influence their adsorption on GTCB. The influence of internal rotation angles in proline and its hydroxy derivative molecules on their adsorption on GTCB was studied.

2009-04-01

81

Doublet III limiter/armor update  

Energy Technology Data Exchange (ETDEWEB)

The Doublet III device is operating with an extensive system of plasma limiters and wall protective armor. Operations with up to 8MW of neutral beam power and 1.5MA plasma current are planned. Design and operational performance of the following systems are discussed: 1. Water-cooled graphite moveable limiter. 2. Water-cooled graphite fixed limiter and neutral beam wall armor. 3. Radiatively cooled Inconel divertor plates.

1983-12-01

82

Accommodation coefficients of helium, neon, argon, hydrogen and deuterium on graphitized carbon  

Energy Technology Data Exchange (ETDEWEB)

The thermal accommodation coefficients of helium, neon, argon, hydrogen and deuterium have been measured in the temperature range of 77-340 K on the surface of a graphitized carbon filament. The dependence of the accommodation coefficient upon the molecular weight as well as the temperature of measurement, and the conversion from orthohydrogen to parahydrogen, have been discussed.

1987-07-30

83

Thermal Stability of Furfuryl Alcohol/Graphite Powder Mixtures for Impregnation of Carbonaceous Composite  

Energy Technology Data Exchange (ETDEWEB)

We examined, using thermo analytical methods, the effects of 2000 deg. C heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnation but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30 wt%. graphite powders of furfuryl alcohol and the heating rate 35 deg. C/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above 1000 deg. C was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization {yields} impregnation {yields} cure {yields} re-carbonization) required to density a carbonaceous composite. (author). 9 refs., 8 ...

1998-04-01

84

A method for sorting irradiated substances through coloration  

International Nuclear Information System (INIS)

L'invention concerne un procede de triage de cristaux irradies. Ce procede non destructeur comporte l'irradiation des cristaux par un rayonnement ionisant pendant une duree et avec une intensite telles qu'il se forme des centres colores distinctifs dans les matieres contenant des ions aluminium. Les cristaux colores qui correspondent en teinte et en profondeur de couleur a des teneurs en aluminium en dehors de la teneur desiree peuvent etre separes. On peut isoler ainsi des matieres de quartz, de verre, de silicates exemptes d'aluminium dans un melange, ou bien on peut choisir des fractions de ces matieres, chacune contenant une teneur uniforme en aluminium.

85

Radiation resistance of flexible graphites  

International Nuclear Information System (INIS)

Polymer sealing parts are widely used in various branches of engineering as detachable joints that operate at normal and cryogenic temperatures. They are also used in nuclear-power engineering to seal pumps, pipelines, etc., where they operate at 600-650 K under a neutron fluence of around 10"1"6 cm"-"2 (E #>=# 0.18 MeV) and concomitant #gamma#-irradiation of about 10"6 R. The fluoroplastic-based materials currently used degrade when irradiated in water at 320-360 K with a neutron fluence of 10"1"5 cm"-"2 (thermal neutrons) or 10"1"4 cm"-"2 (fast neutrons), and a concomitant #gamma#-irradiation dose of 2 x 10"6 R. The strength of these fluoroplastics decreases markedly after #gamma#-irradiation (from a cobalt source) at room temperature at doses above 10"6 R. For this reason, flexible and swelling graphites are finding ever increasing application. Graflex foils made of extra-pure natural graphite were found to be radiation-resistant and ...

86

Evaluation of 1-site and 5-site models of methane on its adsorption on graphite and in graphitic slit pores.  

Science.gov (United States)

In this paper, we evaluate the performance of the 1- and 5-site models of methane on the description of adsorption on graphite surfaces and in graphitic slit pores. These models have been known to perform well in the description of the fluid-phase behavior and vapor-liquid equilibria. Their performance in adsorption is evaluated in this work for nonporous graphitized thermal carbon black, and simulation results are compared with the experimental data of Avgul and Kiselev (Chemistry and Physics of Carbon; Dekker: New York, 1970; Vol. 6, p 1). On this nonporous surface, it is found that these models perform as well on isotherms at various temperatures as they do on the experimental isosteric heat for adsorption on a graphite surface. They are then tested for their performance in predicting the adsorption isotherms in graphitic slit pores, in which we would like to explore the effect ...

2005-10-20

87

Multiple ordered phases in the filled skutterudite compound PrOs4As12  

Energy Technology Data Exchange (ETDEWEB)

Magnetization, specific heat, and electrical resistivity measurements were made on single crystals of the filled skutterudite compound PrOs{sub 4}As{sub 12}. Specific heat measurements indicate an electronic specific heat coefficient {gamma} {approx} 50-200 mJ/mol K{sup 2} at temperatures 10 K {le} T {le} 18 K, and {approx} 1 J/mol K{sup 2} for t {le} 1.6 K. Magnetization, specific heat, and electrical resistivity measurements reveal the presence of two, or possibly three, ordered phases at temperatures below {approx} 2.3 K and in fields below {approx} 3 T. The low temperature phase displays antiferromagnetic characteristics, while the nature of the ordering in the other phase(s) has yet to be determined.

2006-03-20

88

Calcified metastases of the kidney. Etiology, pathogenesis, CT findings and diagnostic problems; Metastasi renali calcificate: eziologia, patogenesi, aspetti con tomografia computerizzata e diagnostica differenziale  

Energy Technology Data Exchange (ETDEWEB)

Aim of the work was to describe computerised tomography (CT) findings of calcified renal metastases focusing on differential diagnosis problems. Abdominal CT scans of 8000 patients with tumor, performed from 1984 to 1998, have been retrospectively reviewed. [Italian] Scopo del lavoro e' quello di descrivere gli aspetti con tomografia computerizzata delle metastasi renali calcificate enfatizzando le problematiche diagnostico differenziali. Sono state valutate retrospettivamente le indagini TC addominali di 8000 pazienti affetti da tumore nel periodo 1984-1998, analizzando le lesioni calcificate riscontrate.

2000-03-01

89

One-step synthesis of reduced graphite oxide-silver nanocomposite  

British Library Electronic Table of Contents (United Kingdom)

Here, a general approach for the preparation of reduced graphite oxide (rGO)-silver nanocomposite has been investigated. Graphite oxide (GO) sheets are used as the nanoscale substrates for the formation of rGO-silver composite. GO sheets and Ag ions can be reduced at the same time, under a mild condition using l-ascorbic acid (l-AA) as reducing agent. This simple approach should find practical applications in the production of rGO-silver nanocomposite. The SEM analysis indicates that the silver particles are dispersed on graphene sheets. Raman signals of rGO in the composite are increased by the attached silver nanoparticles, displaying surface-enhanced Raman scattering activity. The degree of enhancement can be adjusted by varying the quantity of silver nanoparticles in the composite. In ...

2011-01-01

90

Non-linearity and hysteresis of Hall effect in magnetorheological suspensions with conducting carrier  

Energy Technology Data Exchange (ETDEWEB)

In this article a production method of a magnetorheological suspension composed with silicon steel particles of size 0.1-0.15 mm and 4% silicon content is described. Steel particles were dispersed in a conducting carrier of a by mixture of graphite particles with size 2-5 {mu}m and cedar wood oil. The filling factor of the suspension with the silicon steel particles and with graphite particles amounted to 0.25-0.40. Samples of this suspension were placed in a rectangular vessel with electrodes and used for the investigation of the Hall effect in magnetic field with induction 0-8 T, generated by Bitter-type magnet. A non-linear dependence of Hall voltage on the induction of the applied magnetic field and a hysteresis loop of this voltage in the shape of inclined digit eight were found. The causes of the observed effects is the ordering of silicon steel particles and graphite particles along the side of magnetic field lines.

2003-08-01

91

Nano silicon for lithium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

New results for two types of nano-size silicon, prepared via thermal vapour deposition either with or without a graphite substrate are presented. Their superior reversible charge capacity and cycle life as negative electrode material for lithium-ion batteries have already been shown in previous work. Here the lithiation reaction of the materials is investigated more closely via different electrochemical in situ techniques: Raman spectroscopy, dilatometry and differential electrochemical mass spectrometry (DEMS). The Si/graphite compound material shows relatively high kinetics upon discharge. The moderate relative volume change and low gas evolution of the nano silicon based electrode, both being important points for a possible future use in real batteries, are discussed with respect to a standard graphite electrode. (author)

2006-11-12

92

Molecular statistical calculation of thermodynamic characteristics of adsorption of O-, S-, and Se-containing heteroadamantanes on graphitized thermal carbon black  

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption (TCA) on the basal face of graphite have been calculated in terms of the semiempirical molecular statistical theory of adsorption for molecules of O-, S-, and Se-containing heteroadamantanes of different structure and isostructural cyclohexane derivatives. The influence of the nature, number, and position of heteroatoms in the adamantane framework on the TCA values was studied in detail, which made it possible to predict the retention of the compounds considered on the surface of graphitized thermal carbon black under the conditions of equilibrium gas adsorption chromatography. The introduction of each subsequent heteroatom into a polyheteroadamantane molecule makes a non-additive contribution to the TCA values. The contributions of various f...

2010-01-01

93

Effects of surface mediation on the adsorption isotherm and heat of adsorption of argon on graphitized thermal carbon black  

British Library Electronic Table of Contents (United Kingdom)

In this paper, the effects of surface mediation on the adsorption isotherm and isosteric heat of adsorption on a graphite surface were investigated, as the surface mediation is known to affect the intermolecular interaction of adsorbed molecules close to the surface. Kim and Steele (Phys. Rev. B 45 (11) (1992) 6226-6233) and others have assumed that the surface mediation is confined only to the first layer. This will be tested in this paper with a combined experimental and Grand Canonical Monte Carlo (GCMC) simulation of adsorption of argon on graphitized thermal carbon black (GTCB) over a range of temperatures (77-95.25K). By matching the simulation results against the experimental data, we have found that the surface mediation is extended up to the fourth layer, rather than only the firs...

2010-01-01

94

Density separation of combustion-derived soot and petrogenic graphitic black carbon: Quantification and isotopic characterization  

Energy Technology Data Exchange (ETDEWEB)

The black carbon continuum is composed of a series of carbon-rich components derived from combustion or metamorphism and characterized by contrasting environmental behavior and susceptibility to oxidation. In this work, we present a micro-scale density fractionation method that allows isolating the small quantities of soot-like and graphitic material usually found in natural samples. Organic carbon and {delta}{sup 13}C mass balance calculations were used to quantify the relative contributions of the two fractions to thermally-stable organic matter from a series of aquatic sediments. Varying proportions of soot-like and graphitic material were found in these samples, with large variations in {delta}{sup 13}C signatures suggesting important differences in their origin and/or dynamics in the environment.

2009-01-01

95

Bulk and surface electronic structure of hexagonal boron nitride  

International Nuclear Information System (INIS)

Accurate full-potential self-consistent linearized augmented-plane-wave (FLAPW) calculations have been carried out for hexagonal boron nitride. The resulting energy-band structure indicates that this material is an indirect-gap insulator and shows the existence of two unoccupied interlayer bands, similar to those found in graphite and graphite intercalation compounds. Chemical bonding is mainly covalent, with a small charge transfer towards the nitrogen atoms. Moreover, model-potential calculations, based on first-principles FLAPW wave functions and potentials, have been used to study slabs of thickness up to 35 layers. Contrary to the case of graphite, our results do not provide evidence of surface states associated with the interlayer bands.

96

Advice about the safety of graphite storage silos of Saint Laurent des Eaux facility; Avis sur la surete des silos de stockage de graphite de Saint Laurent des Eaux  

Energy Technology Data Exchange (ETDEWEB)

This document is the safety analysis made by the national association of the local commissions of information about nuclear activities (ANCLI), about the safety of graphite storage silos of Saint Laurent des Eaux nuclear facility. The analysis covers: the operation safety and the accident hypothesis, the monitoring of indoor and outdoor contamination in routine situation, the geotechnical characteristics of the site environment, the isotopic inventory and the estimation of radioactivity in routine and accidental situation, the estimation of doses received by the population in accidental situation and the internal emergency plan. After examination of these different points, the scientific committee of the ANCLI considers that a new global evaluation of risks, which integrates more recent exposure data, has to be carried out. (J.S.)

2005-07-01

97

Transformation Isotherme beta to alpha Dans L 'uranium Pur et Faiblement Allie (Beta to alpha Isothermal Transformation in Pure and Weakly Alloyed Uranium).  

Science.gov (United States)

The TTT diagrams describing the beta to alpha isothermal transformation have been made by isothermal dilatometry for pure uranium and 21 alloys based on chromium, silicon, molybdenum, iron, aluminium, zirconium. The thermal cycle preceeding the isothermal...

1966-01-01

98

Domestic and industrial applications of microwaves; Les micro-ondes dans les applications domestiques et/ou industrielles  

Energy Technology Data Exchange (ETDEWEB)

In addition to their use in high-speed ovens, microwaves are also finding applications in industrial manufacture, quality control and storage - anywhere where the high-frequency transmission or reflection properties of a material can be exploited. Microwaves are also being used in medical applications for the characterization of certain type of tumours. They are also being used in research into ultrasonic cavitation. (authors) 5 refs.

1999-01-01

99

Characterization of polluted sites. Assessment of pollutant behaviour and transfer in mediums; Caracterisation des sites pollues. L`evaluation du comportement et du transfert des polluants dans les milieux  

Energy Technology Data Exchange (ETDEWEB)

After a presentation of methods and tools for the basic and extensive characterization of polluted sites and the study of evolution and transfer of current organic pollutants in the ground, the example of the rehabilitation of an old Rhone-Poulenc site (at Chauny, France) polluted with metals and arsenic, is described: soil and aquifer diagnosis, risk analysis and determination of migration schemes

1996-12-31

100

lib_general.pro - ECCO2  

Science.gov (United States)

Returns singular values (sigma), ;left field (x) vectors, ..... n) do begin point=ngbrs(i) if (point+tau le nt-1) then begin if (x(point+tau,0) ne q) then .... ;FILTER ;applies a gaussian filter in the frequency domain function filter, x ...

101

an expert system for estimating forest harvesting productivity and cost  

Science.gov (United States)

Sep 1, 2011 ... Title: THINEX - an expert system for estimating forest harvesting productivity and cost. Author: LeDoux, C. B.; Gopalakrishnan, B.; Pabba, R. S. ...

102

When and how to reactivate the activated charcoal?; Quand et comment regenerer le charbon actif?  

Energy Technology Data Exchange (ETDEWEB)

The activated charcoal is very appreciates for the water treatment. It do not generate by-product of treatment. In return it is saturated after some time and may releases pollutant compounds. When and how to get to its regeneration?.

2000-03-01

103

System Design and Applications of the Ultra Small ... - GLTRS - NASA  

Science.gov (United States)

The advanced technologies of Ka-Band systems such as high gain spot .... sometimes used based on link requirements for a specific application. .... received at NASA LeRC from a Ku-band satellite and retransmitted to the USAT at Ka-Band. .... and to the Office of Management and Budget, Paperwork Reduction Project ...

104

Speech Communication in Noise  

Science.gov (United States)

... Un jeu de DVD créés à partir de boucles de bruit sur bande audionumérique ont été étalonnés de manière à produire le même spectre de bruit ...

2008-05-13

105

Flies In Space - Drosophila - NASA Quest  

Science.gov (United States)

Aqu? va a poder aprender acerca de la Dros?fila Melanogaster, a la cual se le conoce como la mosca de la fruta! Usted podr?. Interpretar por qu? las moscas ...

106

Feynman lectures on physics, quantum mechanics; Le cours de physique de Feynman mecanique quantique  

Energy Technology Data Exchange (ETDEWEB)

This course is based upon lectures in physics given by Professor Feynman at the California institute of technology during 1961 and 1962. This volume is dedicated to quantum physics, semiconductors, symmetry and advanced principles of physics.

2000-07-01

108

CASE FI LE COPY - NASA Technical Reports Server  

Science.gov (United States)

1.9312. 1"6898. 1,3036 .7846 .313g .0121. Bright hess values. 263.291. 332.278. 382.911. 481.013. 575"949. 693.038. 886.076. 1025.316. 1291.139 ...

109

A Reproduced Copy - NASA Technical Report Server (NTRS)  

Science.gov (United States)

Ccna othf>r projecto, for c~le, on cl~te ZL.')d focxl syute:s in "cxico AIld. IndiA and on idantification of cli=atn-aono!tivG ~cctora, ...

110

A Grafcet-based expert system for process control; Un systeme expert base sur le Grafcet pour le controle de procede  

Energy Technology Data Exchange (ETDEWEB)

This article describes a hierarchical and functional model for continuous process control aid. The expertise is represented by graphs from a simple functional restructuring of the Grafcet, which is the formalism used by the designers of the command-control program. The new structure is familiar to the operator, and it is settled in an expert system. The application built on the basis of this method detects some default types which are not detected by the control-command. It proposes a diagnosis to the operator, and can explain and justify the state of the process. (authors) 9 refs.

1997-11-01

111

Mechanism of the dissolution of coals in a mixture of concentrated sulfuric and nitric acids  

British Library Electronic Table of Contents (United Kingdom)

In this work, coals of various ranks were dissolved in an acid melange. With the use of IR spectroscopy, it was found that the mechanism of coal dissolution consists in the grafting of polar groups to the peripheral benzene rings of graphite-like systems.

2011-01-01

112

Mechanical properties of an as-cast heavy-sectioned ferritic spheroidal graphite cast iron  

Energy Technology Data Exchange (ETDEWEB)

In the production of heavy-sectioned ferritic spheroidal graphite iron castings for such parts as spent fuel shipping container (cask), undesirable structures like abnormal graphite lamella, pearlite or so-called chinese script type of inclusions tend to appear, deteriorating the mechanical properties at the central part of the section where molten iron freezes last. 500 mm thick cylindrical vessels with bottom, weighing 18 tons and 33 tons, were poured as trial products of casks. Solidification structure and mechanical properties were examined at many portions of the castings. By controlling chemical composition, solidification time and inoculation process the structure and the mechanical properties in the last portion of the section to solidify were improved. Sufficiently homogeneous heavy-sectioned ferritic spheroidal graphite iron castings were successfully produced in the as-cast state. In addition, quality assurance ...

1987-11-01

113

Doublet III vacuum vessel neutral beam armor  

Science.gov (United States)

The evolution of the Doublet III neutral beam armor is followed from the initial design of a radiation cooled metallic tile to the present actively cooled graphite design. Results of the thermal and stress analyses that dictated the present design are reviewed.

1979-11-01

114

Displaced capillary dies  

Energy Technology Data Exchange (ETDEWEB)

An asymmetrical shaped capillary die made exclusively of graphite is used to grow silicon ribbon which is capable of being made into solar cells that are more efficient than cells produced from ribbon made using a symmetrically shaped die.

1982-01-01

115

Chemistry and morphology of coal liquefaction. Quarterly report, January 1-March 30, 1981  

Science.gov (United States)

In the course of observing by means of Auger spectroscopy graphite gasification reactions catalyzed by metals, it has been found that in the presence of hydrogen, nickel appears to diffuse from the surface into the bulk of the graphite. When potassium is deposited on graphite, it is volatilized above 400/sup 0/C. Surprisingly the production of methane and carbon dioxide from the reaction of graphite and steam was catalyzed by potassium at as low a temperature as 250/sup 0/C. It has been shown that literature on the alkylation of benzene with synthesis gas is erroneous and that the products reported are due to Lewis acid catalyzed cracking of benzene. A novel cobalt mediated, reversible cleavage of a vinyl-hydrogen bond has been discovered. All products from the thermal decomposition of tetralin have been identified. The stereochemistry of cis-1, 2 dihydrotetralin was determined. In the utilization of ...

1981-03-01

116

Adsorption of argon from sub- to supercritical conditions on graphitized thermal carbon black and in graphitic slit pores: A grand canonical Monte Carlo simulation study  

Science.gov (United States)

In this paper we consider the adsorption of argon on the surface of graphitized thermal carbon black and in slit pores at temperatures ranging from subcritical to supercritical conditions by the method of grand canonical Monte Carlo simulation. Attention is paid to the variation of the adsorbed density when the temperature crosses the critical point. The behavior of the adsorbed density versus pressure (bulk density) shows interesting behavior at temperatures in the vicinity of and those above the critical point and also at extremely high pressures. Isotherms at temperatures greater than the critical temperature exhibit a clear maximum, and near the critical temperature this maximum is a very sharp spike. Under the supercritical conditions and very high pressure the excess of adsorbed density decreases towards zero value for a graphite surface, while for slit pores negative excess density is possible at extremely high pressures. For imperfect ...

2005-08-01

117

New materials to manufacture casting molds  

International Nuclear Information System (INIS)

A report is given on an improved filler-binder mixing method in the manufacture of artificial graphite, the so-called coat-mix process. The individual graphite-filler grains are coated completely with uniform binder coatings (phenol formaldehyde resin) in a continuous process. Methanol is used as solvent for the resin. In a modified further development of the process, the use of organic solvents can be disregarded by dissolving the binder resin in caustic soda and injecting the slurry into water diluted acid. The manufacture of casting molds from coat-mix powders, their properties and industrial application are given. Finally, the advantages of using carbon bodies of coal-mix material for conversion to silicon carbide are indicated. (IHOE).

118

Local secondary-electron emission spectra of graphite and gold surfaces obtained using the Scanning Probe Energy Loss Spectrometer (SPELS)  

International Nuclear Information System (INIS)

Secondary-electron emission (SEE) spectra have been obtained with the Scanning Probe Energy Loss Spectrometer at a tip-sample distance of only 50 nm. Such short working distances are required for the best theoretical spatial resolution (<10 nm). The SEE spectra of graphite, obtained as a function of tip bias voltage, are shown to correspond to unoccupied states in the electronic band structure. The SEE spectra of thin gold films demonstrate the capability of identifying (carbonaceous) surface contamination with this technique.

2009-11-25

119

Description of alkane and benzene halogen derivatives adsorption on graphitized thermal carbon black based on the model of ideal two-dimensional gas  

International Nuclear Information System (INIS)

By comparison of standard entropies theoretically calculated and determined from gas-chromatographic data for 40 halo-aliphatic and halo-aromatic compounds 8 organic iodine compounds among them, adsorbed on graphitized thermal carbon black it was found that in all the cases the molecular model of ideal two-dimensional gas is a sufficiently good approximation. It was shown that for a number of systems the agreement can be improved if the vibrations of the center of molecular mass relative to the surface are taken into account

120

Adsorption of benzyl alcohol and 1-phenylethanol on graphitized thermal carbon black  

British Library Electronic Table of Contents (United Kingdom)

The adsorption of benzyl alcohol and 1-phenylethanol on graphitized thermal carbon black at 300 K is investigated. Thermodynamic characteristics of the adsorption of conformers stable in the gas phase and in the adsorbed state are determined by a molecular statistics method. The geometry of the molecules is optimized using the MP2 and B3LYP methods with a 6-311++G(d,p) basis set. Using the PBE0/6-31G(d) method, it is established that, in the adsorption of benzyl alcohol, two types of interactions, CH?O and OH??GTCB, occur. It is shown that, in 1-phenylethanol, intramolecular interactions are maintained.

2010-01-01

121

Comparisons of graphite and spinel Li1.33Ti1.67O4 as anode materials for rechargeable lithium-ion batteries  

International Nuclear Information System (INIS)

The aim of this work was to compare the electrochemical behaviors and safety performance of graphite and the lithium titanate spinel Li1.33Ti1.67O4 with half-cells versus Li metal. Their electrochemical properties in 1 M LiPF6/EC + DEC (1:1 w/w) or 1 M LiPF6/PC + DEC (1:1 w/w) at room and elevated temperatures (30 and 60 deg C) have been studied using galvanostatic cycling. At 30 deg C graphite has higher reversible capacity than Li1.33Ti1.67O4 when using the LiPF6/EC + DEC as electrolyte. At 60 deg C graphite declines in cell capacity yet Li1.33Ti1.67O4 remains almost unchanged. In a propylene carbonate (PC) containing electrolyte, graphite electrode exfoliates and loses its mechanical integrity while Li1.33Ti1.67O4 electrode is very stable. An accelerating rate calorimeter (ARC) and microcalorimeter have been used to compare the thermal stability of lithiated lithium titanate spinel and ...

2005-07-25

122

Carbon fibers and composites modified by intercalation  

International Nuclear Information System (INIS)

The aim of this paper was to describe ability to intercalation of laboratory prepared carbon composites and their constituents. In work the following materials were tested; pinch-based fibres of P-120 and K-1100 manufacturer's designations, carbon matrix and resulting composites. To prepare a matrix of composites, phenol-formaldehyde resin (Z) and pinch-based precursor (PAK) were used. After initial carbonization, the carbon matrix was heated to 2150 "oC i to improve ability to the future intercalation. Three kinds of composites (P/Z, K/Z and K/PAK), with two directional reinforcement (2D), were prepared. All carbon samples were intercalated with copper chloride(II). To study the structure of all materials, before and after intercalation, X-ray diffraction method was used. It enabled to measure microstructure parameters (L_c and L_a), interplanar distance (d_0_0_2) thickness of an intercalation layer (d_i). Before intercalation, graphite fibers are characterized by ...

123

Which differential circuit breaker in tomorrows accommodation?; Quel disjoncteur differentiel dans l'habitat de demain?  

Energy Technology Data Exchange (ETDEWEB)

Since several years, several manufacturers of circuit breakers from various countries (South Africa, UK, The Netherlands, USA..) try to impose in accommodations a highly sensitive electronic-type of differential circuit-breaker initially devoted to industrial installations where qualified and experienced professionals are present. This technical paper presents first the principles of the classical electromechanical circuit breakers and of the electronic circuit breaker, and then compares their relative efficiency and level of safety in residential use conditions (grounding schemes, voltage drops, rupture of the neutral conductor, rupture of the phase conductor, overvoltages). (J.S.)

2000-04-01

124

In-situ study of the dendritic growth in lithium/polymer electrolyte-salt/lithium cells; Etude in-situ de la croissance dendritique dans des cellules lithium/POE-sel/lithium  

Energy Technology Data Exchange (ETDEWEB)

The in-situ observation of dendritic growth in lithium/polymer electrolyte-LiTFSI/lithium battery cells shows that dendrites grow up with about the same rate as anion migration. Memory effects have been evidenced in cycling experiments and limit the dendrites length. An overall movement of the electrolyte due to variations of electrolyte concentration in the vicinity of the electrodes has been observed too. (J.S.) 13 refs.

1996-12-31

125

Improving air quality in tertiary buildings; Ameliorer la qualite de l'air dans les batiments tertiaires  

Energy Technology Data Exchange (ETDEWEB)

In order to promote the use of natural gas air-conditioning systems in the tertiary sector, Gaz de France (the French gas utility) in association with Electricite de France (EdF) and the French chamber of council engineers (CICF) have created the Acerclim organization which aims at certifying the quality of the design, realization and exploitation of air processing and air-conditioning installations according to the ISO 9001 criteria. This article describes this quality procedure named 'CHSB Air'. (J.S.)

2002-07-01

126

Electrochemical reduction of graphited materials in LiClO{sub 4}-EC and LiClO{sub 4}-PC media: characterization of interface products by transmission electron microscopy; Reduction electrochimique de materiaux graphites en milieux LiCIO{sub 4}-EC et LiCIO{sub 4}-PC: caracterisation des produits d`interface par microscopie electronique a transmission  

Energy Technology Data Exchange (ETDEWEB)

The electrochemical intercalation of non-solvated lithium in different graphited materials has been performed in LiClO{sub 4}-ethylene carbonate (EC) medium. The irreversible capacity observed during the first output is mainly due to the formation of a passivation layer made of electrolyte reduction products. These products have been characterized for different electrode reduction potentials using transmission electron microscopy (image, diffraction) and electron energy loss spectroscopy (EELS). EC reduction on the electrode surface in presence of LiClO{sub 4} leads to the formation of Li{sub 2}CO{sub 3} for potentials close to 0.8 V vs Li{sup +}/Li. For lower potentials, the electrolyte reduction reaction goes on with the formation of different lithium alkyl-carbonates. In LiClO{sub 4}-propylene carbonate (PC) medium, the interface phenomena are different. The reduction of a graphite electrode is characterized by the exfoliation phenomenon ...

1996-12-31

127

Adsorption of argon on homogeneous graphitized thermal carbon black and heterogeneous carbon surface.  

Science.gov (United States)

In this paper we investigate the effects of surface mediation on the adsorption behavior of argon at different temperatures on homogeneous graphitized thermal carbon black and on heterogeneous nongraphitized carbon black surface. The grand canonical Monte Carlo (GCMC) simulation is used to study the adsorption, and its performance is tested against a number of experimental data on graphitized thermal carbon black (which is known to be highly homogeneous) that are available in the literature. The surface-mediation effect is shown to be essential in the correct description of the adsorption isotherm because without accounting for that effect the GCMC simulation results are always greater than the experimental data in the region where the monolayer is being completed. This is due to the overestimation of the fluid-fluid interaction between particles in the first layer close to the solid surface. It is the surface mediation that reduces this ...

2005-07-15

128

The magnetoresonance operation of microwiggler on the piezoelectrics with a strong magnetic guide field  

Energy Technology Data Exchange (ETDEWEB)

We proposed that a new type of the electrostatic microwiggler with a wiggler period (0.1 mm {le}1{sub w}{le}1 mm) and the wiggler field strength (E{sub w}{le} 100 kV/m) can be produced on the surface of a PZT when a high power and high frequency ultrasonic wave travels through a PZT bar. Numerical simulations in the linear and nonlinear gain regime show that a weak microwiggler (E{sub w}100 kV/m,{lambda}{sub w}{approx}100 periods), operating in magnetoresonance with a strong guide field (B{sub o}{approx} 3.6T), can generate a millimeter and submillimeter radiations with medium electronic efficiency of few percents. It is shown that the maximum output power of the compact FEL using the wiggler system generated on the surface of the piezoelectric material may be upto a few Watts with a relatively low energy and low current electron beam (Ew {approx}100 keV and I{sub b}1 mA).

1995-12-31

129

Separation of Minor Actinides and Lanthanides with Carbon Nano-materials  

Energy Technology Data Exchange (ETDEWEB)

Recently we have found that carbon nano-materials have ability to recognize softer actinides(III). In this presentation, separation of americium(III) from lanthanides(III) by chromatography with carbon nano-materials, such as carbon nano-tubes and graphite, has been investigated by batch adsorption experiments and chromatography. The separation factor (SF) between americium(III) and lanthanide(III) was about 2 in the range of pH from 1 to 4 by using carbon nano-tube, graphite and activated charcoal. The separation factor depended on the diameter of carbon nano-tubes. Smaller one, 3-20 nm diameter, showed the best selectivity for americium(III), which separation factor was about 2.0, although larger one, 40-70 nm, showed almost no selectivity. The same behavior has been observed by using graphite powder and activated charcoal although acid- or alkali pretreated activated charcoal which generally has acidic functional group ...

2009-06-15

130

Natural convection cooling of a close-packed array of AGR fuel pins surrounded by graphite debris  

International Nuclear Information System (INIS)

Certain postulated faults during refuelling of AGRs may give rise to compacted fuel and graphite sleeve debris. This debris must be maintained below some safe limiting temperature. As part of a programme to assess the benefits of natural convection in cooling such debris in a region experiencing no forced cooling, a simple geometry incorporating typical debris has been studied both experimentally and by prediction. The experiment comprised an array of electrically heated fuel rods mounted co-axially in a closed cylindrical vessel and surrounded by fragments of graphite. The vessel was cooled on its cylindrical surface, the ends being insulated. Rods and vessel wall were thermocoupled. Tests covered a range of temperature and pressures in both CO_2 and N_2. Significant natural convection heat removal was demonstrated, particularly at high pressure. Predictions utilising the PHOENICS code agreed well with measured temperatures over a wide range ...

131

Nanostructuring the graphite basal plane by focused ion beam patterning and oxygen etching  

International Nuclear Information System (INIS)

Ga"+ focused ion beam (FIB) patterning was used to structure highly oriented pyrolytic graphite surfaces with square, periodic arrays of amorphous carbon defects (mesh sizes: 300 nm-2 #mu#m). Controlled oxygen etching of these arrays leads to matrices of uniform, orientationally aligned, nm-sized, hexagonal holes. The properties of the resulting hole assembly (hole depths and lateral hole dimensions) have been investigated by means of atomic force microscopy, scanning electron microscopy and FIB sectioning. The hole dimensions and uniformity both depend on the FIB parameters and etching conditions. Etching temperatures from 500 to 700 deg. C were applied. Initial etch rates of up to 10"6 C s"-"1 per individual hole were observed when using oxygen pressures of 200 mbar. For an etch temperature of 590 deg. C the rate of etching of individual holes was found to depend measurably on the inter-hole separation. This confirms that the associated reaction kinetics is ...

2006-12-14

132

Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries.  

Science.gov (United States)

The lithium storage properties of graphene nanosheet (GNS) materials as high capacity anode materials for rechargeable lithium secondary batteries (LIB) were investigated. Graphite is a practical anode material used for LIB, because of its capability for reversible lithium ion intercalation in the layered crystals, and the structural similarities of GNS to graphite may provide another type of intercalation anode compound. While the accommodation of lithium in these layered compounds is influenced by the layer spacing between the graphene nanosheets, control of the intergraphene sheet distance through interacting molecules such as carbon nanotubes (CNT) or fullerenes (C60) might be crucial for enhancement of the storage capacity. The specific capacity of GNS was found to be 540 mAh/g, which is much larger than that of graphite, and this was increased up to 730 mAh/g and 784 mAh/g, respectively, by the incorporation of ...

2008-07-24

133

Effect of surface-perturbed intermolecular interaction on adsorption of simple gases on a graphitized carbon surface.  

Science.gov (United States)

In this paper, we investigate the effect of the solid surface on the fluid-fluid intermolecular potential energy. This modified fluid-fluid interaction energy due to the inducement of a solid surface is used in the grand canonical Monte Carlo (GCMC) simulation of various noble gases, nitrogen, and methane on graphitized thermal carbon black. This effect is such that the effective interaction potential energy between two particles close to surface is less than the potential energy if the solid substrate is not present. With this modification the GCMC simulation results agree extremely well with the experimental data over a wide range of pressures while the simulation results with the unmodified potential energy give rise to a shoulder near the neighborhood of monolayer coverage and the significant overprediction of the second and higher layer coverages. In particular the unmodified GCMC results exhibit very sharp change in those higher layers while the experimental ...

2004-08-31

134

Comparison of two dose-area-product ionization chambers with different conductive surface coating for over-table and under-table tube configurations  

Energy Technology Data Exchange (ETDEWEB)

A custom-built graphite-coated transmission ionization chamber is compared to the VacuDAP 2001 (VacuTec, Dresden, Germany), which has transparent conductive electrodes. A study was made of the dependence of response on x-ray tube potential for both types of chamber under identical conditions of exposure using over-table and under-table x-ray tubes. Since the calibration factor is the dose-area product of the radiation incident on the patient per chamber reading, it depends on the intrinsic response of the chamber as well as the effect of material in the beam between the x-ray tube and patient. Differences of about 20% were measured between the intrinsic and the over-table calibration factors and between the over-table and the under-table calibration factors for both chambers. The VacuDAP display is specifically calibrated for the over-table condition and would overstate the actual DAP in the under-table case. The intrinsic response of the ...

2000-03-01

135

Phenomenology of light systems using R-matrix theory.  

Energy Technology Data Exchange (ETDEWEB)

Over the last 30 years, a program of R-matrix analyses has been carried out at Los Alamos in the mass range 2 {le} A {le} 18 that gives useful information about the light systems. These analyses provide data for astrophysics, as well as for neutronic and thermonuclear applications, and can yield important constraints from the experimental measurements on the nature of few-body interactions. Following a brief introduction to R-matrix theory, I will describe recent work on reactions in the A=2 (NN) and A=4 systems. Finally, some comments will be made about extending the theory to complex energies in order to obtain information about resonances and other types of S-matrix singularities.

2001-01-01

136

One-step synthesis of Pt-supported carbon nanohorns for fuel cell electrode by arc plasma in liquid nitrogen  

International Nuclear Information System (INIS)

One-step synthesis of Pt-loaded carbon nanoparticles including single-wall carbon nanohorns (SWNHs) by arc plasma in liquid nitrogen was demonstrated using Pt-contained graphite anode. The size distribution of Pt particles can be controlled by adjusting the concentration of Pt in the graphite anode. In the observation by transmission electron microscope, the diameter of less than 5 nm of Pt particles were observed as approximately 90% among the Pt particles when Pt was contained in the anode at 1.3 at.%. When Pt concentration in the anode was decreased to 0.4 at.%, the percentage of Pt particles whose diameter is less than 5 nm decreased to approximately 60%. It was verified that the as-grown Pt-loaded products produced by this method can be useful for the power generation by polymer electrolyte fuel cell.

2006-10-10

137

Nanowires of silicon carbide and 3D SiC/C nanocomposites with inverse opal structure  

International Nuclear Information System (INIS)

Synthesis, morphology, structural and optical characteristics of SiC NWs and SiC/C nanocomposites with an inverse opal lattice have been investigated. The samples were prepared by carbothermal reduction of silica (SiC NWs) and by thermo-chemical treatment of opal matrices (SiC/C) filled with carbon compounds which was followed by silicon dioxide dissolution. It was shown that the nucleation of SiC NWs occurs at the surface of carbon fibers felt. It was observed three preferred growth direction of the NWs: [111], [110] and [112]. HRTEM studies revealed the mechanism of the wires growth direction change. SiC/C- HRTEM revealed in the structure of the composites, except for silicon carbide, graphite and amorphous carbon, spherical carbon particles containing concentric graphite shells (onion-like particles).

2011-07-07

138

Molecular structure and retention behaviour of some polycyclic aromatic and perhydroaromatic hydrocarbons on graphitized carbon black  

Energy Technology Data Exchange (ETDEWEB)

On efficient glass capillary columns packed with graphitized thermal carbon black (GTCB) the stereoisomers of aromatic and saturated tricyclic hydrocarbons are completely separated and identified. The Henry's adsorption constants of the individual isomers were determined from mixture at different temperatures. Five isomers of perhydroanthracene, five isomers of perhydrofluorene, two isomers of perhydrophenalene, four isomers of perhydroacenaphthene, as well as phenalene, dihydrophenalene, acenaphthene and acenaphthylene were investigated. The increase of the hydrogenization degree of unsaturated tricyclic hydrocarbons reduces the retention. Among the saturated tricyclic isomers the retention becomes shorter with the larger bending of the molecules, i.e. from the molecule having more equatorial bonds to the molecules having more axial connections. The experimentally determined Henry's constants were qualitatively compared with the structure of the ...

1984-04-01

139

Gas chromatography - mass-spectrometry of volatiles released from plastics used as building materials  

Energy Technology Data Exchange (ETDEWEB)

The possibility of employing a number of adsorbents (polyphenylquinoxaline, Tenax GC, Carbopak C, graphitized thermal carbon black, silica gels modified with pyrocarbon or hexamethyldisilazane) for the trapping of organic traces from air has been investigated. Adsorption capacities of these adsorbents with respect to a number of volatiles released from certain plastics used as building material (polyvinylchloride, Relin, Acronal, etc.) have been measured. A number of the volatiles were identified by gas chromatography - mass-spectrometry after trapping on the adsorbents investigated. Chromatographic separation after trapping on the adsorbents was carried out on wall-coated open-tubular capillary columns as well as in capillary columns packed with graphitized thermal carbon black.

1983-10-01

140

Transcription from the SV40 early-early and late-early overlapping promoters in the absence of DNA replication.  

UK PubMed Central (United Kingdom)

Transcription for a hybrid SV40 promoter-beta globin coding sequence recombinant initiates from both early-early (EE) and late-early (LE) SV40 start sites (EES and LES) in the absence of DNA replication....Full Text Available

1983-01-01

141

The renaissance of solar homes; Le renouveau des maisons solaires  

Energy Technology Data Exchange (ETDEWEB)

This publication of the Areva Group, a world nuclear industry leader, provides information on the energy in many domains. This issue deals with the nuclear fuel cycle, the biofuels, the everyday geothermal power, the Unites States energy supply and types, the Bertrand Picard solar aircraft, the kyoto protocol and the wind power leaders. A special chapter is devoted to the renaissance of solar homes. (A.L.B.)

2004-07-01

142

The molybdenum iron-sulphur protein from Desulfovibrio gigas as a form of aldehyde oxidase.  

UK PubMed Central (United Kingdom)

The molybdenum iron-sulphur protein originally isolated from Desulfovibrio gigas by Moura, Xavier, Bruschi, Le Gall, Hall & Cammack [(1976) Biochem. Biophys. Res. Commun. 72, 782-789] has been...Full Text Available

1987-05-01

143

The building tomorrow and after..; Le batiment demain et apres-demain..  

Energy Technology Data Exchange (ETDEWEB)

During its jubilee, the French building technical and scientific centre (CSTB) has organized a colloquium about the future tendencies of buildings evolution in the 20 forthcoming years: autonomy in energy production and wastes or effluents management, reduction of water consumption and management of water, hot water production and space heating, bio-sensors for the management of indoor air-quality, control of noise environment using active acoustic systems etc.. (J.S.)

1998-01-01

144

Studies of neural networks for engine control: application to the electromechanical valves engine; Etudes des reseaux de neurones pour le controle moteur: application a soupapes electromecaniques  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the control of an electromechanical valves engine. The control uses neural networks in order to build a non-linear model of engine filing which depends on the driven inlets. The aim is to build this real-time model and to integrate this model to a control system which performs an iterative inversion. (J.S.)

1997-12-31

145

Solar rises in the south; Le solaire se leve au sud  

Energy Technology Data Exchange (ETDEWEB)

This autumn, Nice welcomed the thirteen European photovoltaic conference. It was the occasion for the world of solar energy to measure technical progress which were carried out and the market which are still to win. If developing countries are a reserve of new markets, they are not solvent and programmes depend on North/South negotiations. (N.C.).

1996-01-01

146

Recommendations and quality control in brachytherapy; Recommandations pour le controle de qualite en curietherapie  

Energy Technology Data Exchange (ETDEWEB)

Brachytherapy consists of sealed radioactive source implantation. The diversity in the nature of radioelements, in their energy and activity requires strict implantation and utilization rules. These rules include radioactive source physical parameters check, after-loading machine and treatment planning system quality assurance and safe and reproducible dosimetric systems. Patient and medical workers information guarantee radioprotection and prevention of accidental exposures. (authors)

2002-11-01

147

Quality control in Nuclear Magnetic Resonance Imaging. Indications et strategies pour le controle de qualite en IRM  

Energy Technology Data Exchange (ETDEWEB)

In this article, the authors recall the factors apt to influence image quality in NMR Imaging and present the european works that have been developed in MRIQA to set 5 quality assurance tests: EUROSPIN 1 to 5.

1993-01-01

148

Plugging indicator for controlling the sodium quality. Indicateur de bouchage pour le controle de la qualite du sodium  

Energy Technology Data Exchange (ETDEWEB)

This device has and head-race pipe with an external part and a coaxial inner part. A measuring head is mounted movable between these 2 parts and has at least a thermocouple and a mobile grid for varying the section and the sodium flow to facilitate the impurities dissolution. This ensemble is completed by a longitudinal body containing the main parts of the indicator and surrounded by a thermal exchanger to cool the sodium.

1991-09-20

149

Neutronic detection device with extended flux range for control of nuclear reactors. Dispositif de detection neutronique a dynamique etendue pour le controle et la commande des reacteurs nucleaires  

Energy Technology Data Exchange (ETDEWEB)

The neutron detector is cased in a metal envelop and has one detector with a very sensitive fission chamber and a second detector with a fission chamber less sensitive that the first one and a boron coated ionisation chamber for reducing gamma radiation detection.

1992-06-12

150

Microwaves as low frequency radiation in degradations of pollutants; Le microonde come attivatori della degradazione di inquinanti  

Energy Technology Data Exchange (ETDEWEB)

The proposed aim of the work is to verify the effects produced on different kinds of environmental pollutants after exposure to a low frequency radiation such as microwaves. They have proved capable of producing minimum heating of the matrix as well as modifications in the structure of the molecules at the level of simple bonds. Steps were also taken ti check whether the degradation action of the microwaves could be boosted by sunlight. For this reason tests were run also on samples irradiated using microwaves and a lamp capable of simulating the sun's spectrum, as well as in the presence of a single lamp. [Italian] Lo scopo di questa ricerca e' di verificare gli effetti prodotti su inquinanti ambientali, di diversa natura, a seguito di un'esposizione ad una radiazione a bassa frequenza come le microonde. Le microonde possono produrre minimi riscladamenti della matrice e modificazioni della struttura delle molecole, a ...

1999-09-01

151

From tomography to voludensitometry: radiation detectors for industrial control and medical instrumentation; De la tomographie a la voludensitometrie: les capteurs pour le controle industriel et l`instrumentation medicale  

Energy Technology Data Exchange (ETDEWEB)

In this article, the author presents the main technological solutions, available or in development, on X-ray detectors in order to obtain a digital image in biomedical radiography or in industrial radiography: linear x-ray detectors and bidimensional x-ray detectors (memory radioluminescent screens, matrix plan detectors).

1993-12-01

152

Electric-field dependence of electroreflectance and photocurrent spectra at visible wavelengths in MOVPE-grown InAlGaP multiple strained quantum-well structures  

Science.gov (United States)

The authors present electric-field dependent electroreflectance and photocurrent spectra of visible-bandgap In{sub x}(Al{sub y}Ga{sub 1{minus}y}){sub 1{minus}x}P/In{sub x{prime}}(Al{sub y{prime}}Ga{sub 1{minus}y{prime}}){sub 1{minus}x{prime}}P multiple-quantum-well (MQW) structures. These structures, grown by metal-organic vapor phase epitaxy on 6{degrees}-misoriented (100) GaAs substrates, have undoped MQWs sandwiched between doped In{sub 0.5}Al{sub 0.5}P layers, forming p-i-n diodes. Quantum-well compositions in the range 0.46{le}x{le}0.52 and 0{le}y{le}0.4, corresponding to bandgaps in the red to yellow-green range, were used. The Stark shifts in these various samples were measured and found to depend on the details of the Mg p-type doping profile, confirming important diffusion effects, in agreement with secondary ion mass spectrometry and capacitance-voltage data. The results show that these new materials are promising for ...

1993-12-31

154

Application of an on-line measurement system for HF emission control (2. part); Application d'un systeme de mesure en ligne pour le controle des emissions de fluor (2. partie)  

Energy Technology Data Exchange (ETDEWEB)

In the last issue of 'L'Industrie ceramique et verriere', we presented the first part of this study. We describe in this issue the experimental procedure, the results and the conclusions of this work. (authors)

2005-02-01

155

Thin Wall Iron Castings  

Energy Technology Data Exchange (ETDEWEB)

Results of an investigation made to develop methods of making iron castings having wall thicknesses as small as 2.5 mm in green sand molds are presented. It was found that thin wall ductile and compacted graphite iron castings can be made and have properties consistent with heavier castings. Green sand molding variables that affect casting dimensions were also identified.

2001-10-31

156

Synthesis of new ternary alkali metal GICs at high pressures  

Energy Technology Data Exchange (ETDEWEB)

Graphite intercalation compounds, Rb{sub x}KC{sub 8}, Cs{sub x}KC{sub 8} and Na{sub x}KC{sub 8}, x{approx equal}1-1.3, are obtained under pressures up to 80 kbar using KC{sub 8} as the initial compound. Total contents of alkali metals in these compounds correspond to the formula MC{sub 3.5-4.0}. (orig.).

1992-07-01

157

Study of retention of isomeric aromatic hydrocarbons on GTCB and cyclodextrins  

Energy Technology Data Exchange (ETDEWEB)

A study has been made of the interaction between graphitized thermal carbon-black and cyclodextrins and a series of 28 derivatives of benzene (benzene, alkyl-, isoalkyl-, dialkyl-, trialkylbenzenes, vinyl-, and allyl-benzene). The specific retention volumes form the basis for a discussion of the mechanism of interaction and drawing conclusions for the practical separation of isomeric compounds. (orig.).

1992-01-01

158

Monte Carlo design calculations for a neutron imaging facility collimator  

Energy Technology Data Exchange (ETDEWEB)

A thermal neutron imaging facility for computed tomography and real-time neutron radiography is being developed at the University of Texas at Austin. The TRIGA reactor is a graphite-reflected Mark It pool-type research reactor. The neutron imaging facility will use beam port, which is at one end of a through part. Monte Carlo calculations were used to design the neutron collimator for this facility.

1996-12-31

159

Methods and results of gas chromatographicmass spectrometric determination of volatile organic substances in an urban atmosphere  

Energy Technology Data Exchange (ETDEWEB)

The method and results of the quantitative gas chromatographic determination of volatile organic substances in an urban atmosphere are presented. The concentration of organic substances was determined by using a mixed adsorber consisting of graphitized thermal carbon black and activated charcoal modified by pyrocarbon. Average, maximum and minimum concentrations of constant organic components in the atmosphere of Leningrad as a typical large industrial city are reported.

1983-01-01

160

Examination of graphitization products of coal by using radial distribution function method  

Energy Technology Data Exchange (ETDEWEB)

The radial distribution function (RDF) derived from wide angle X-ray diffraction patterns gives additional information about the spatial distribution of atoms. Their radial distances and relative average coordination numbers can be calculated using appropriate mathematical procedures. 7 refs.

1991-01-01

161

Electrochemical stability of silicon/carbon composite anode for lithium ion batteries  

International Nuclear Information System (INIS)

Silicon/carbon composite anode materials were prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with silicon and graphite powders. Scanning electron microscopic (SEM) observation showed that the morphology stability of the composite electrodes can be retained during cycling. A structure evolution mechanism is proposed to illuminate the enhancement of cycleability of the composite electrode. The composite used as anode material for lithium ion batteries possesses a reversible capacity of over 700 mAh/g.

2007-04-20

162

Effects of potential models on the adsorption of ethane and ethylene on graphitized thermal carbon black. Study of two-dimensional critical temperature and isosteric heat versus loading.  

Science.gov (United States)

Adsorption of ethylene and ethane on graphitized thermal carbon black and in slit pores whose walls are composed of graphene layers is studied in detail to investigate the packing efficiency, the two-dimensional critical temperature, and the variation of the isosteric heat of adsorption with loading and temperature. Here we used a Monte Carlo simulation method with a grand canonical Monte Carlo ensemble. A number of two-center Lennard-Jones (LJ) potential models are investigated to study the impact of the choice of potential models in the description of adsorption behavior. We chose two 2C-LJ potential models in our investigation of the (i) UA-TraPPE-LJ model of Martin and Siepmann for ethane and Wick et al. for ethylene and (ii) AUA4-LJ model of Ungerer et al. for ethane and Bourasseau et al. for ethylene. These models are used to study the adsorption of ethane and ethylene on graphitized thermal carbon black. It is found that the solid-fluid ...

2004-12-01

163

Corrosion of materials. A tabular survey. Korrosionsverhalten von Werkstoffen. Eine tabellarische Uebersicht  

Energy Technology Data Exchange (ETDEWEB)

This compact book of tables attempts to give practicians a survey of the corrosion behaviour of common structural and coating materials. Corrosion resistances are presented for steels, alloys, plastics, elastomers, graphite, glasses, and stoneware in environments of NaOH, HNO{sub 3}, SO{sub 2}, ZnCl{sub 2}, NH{sub 3}, H{sub 2}O{sub 2}, ethyl chloride, sodium acetate, and many others. (MM).

1990-01-01

164

Carbon nitride film deposition by active screen plasma nitriding  

British Library Electronic Table of Contents (United Kingdom)

Deposition of CN-based films by a novel version of active screen plasma nitriding, aiming at surface modification of polymers, is reported. The approach relies on the use of pure graphite as the grid material, which was found to act both as an active screen and as a dry source of carbon atoms for the synthesis of thin films consisting mainly of a stoichiometric CN layer with columnar-type structure and dome-like nanostructured morphology.

2011-01-01

165

Adsorption of ethylene on graphitized thermal carbon black and in slit pores: a computer simulation study.  

Science.gov (United States)

In this paper, we studied vapor-liquid equilibria (VLE) and adsorption of ethylene on graphitized thermal carbon black and in slit pores whose walls are composed of graphene layers. Simple models of a one-center Lennard-Jones (LJ) potential and a two-center united atom (UA)-LJ potential are investigated to study the impact of the choice of potential models in the description of VLE and adsorption behavior. Here, we used a Monte Carlo simulation method with grand canonical Monte Carlo (GCMC) and Gibbs ensemble Monte Carlo ensembles. The one-center potential model cannot describe adequately the VLE over the practical range of temperature from the triple point to the critical point. On the other hand, the two-center potential model (Wick et al. J. Phys. Chem. B 2000, 104, 8008-8016) performs well in the description of VLE (saturated vapor and liquid densities and vapor pressure) over the wide range of temperature. This UA-LJ model is then used in the study of ...

2004-08-17

166

Adsorption of benzene on graphitized thermal carbon black: reduction of the quadrupole moment in the adsorbed phase.  

Science.gov (United States)

The performance of intermolecular potential models on the adsorption of benzene on graphitized thermal carbon black at various temperatures is investigated. Two models contain only dispersive sites, whereas the other two models account explicitly for the dispersive and electrostatic sites. Using numerous data in the literature on benzene adsorption on graphitized thermal carbon black at various temperatures, we have found that the effect of surface mediation on interaction between adsorbed benzene molecules must be accounted for to describe correctly the adsorption isotherm as well as the isosteric heat. Among the two models with partial charges tested, the WSKS model of Wick et al. that has only six dispersive sites and three discrete partial charges is better than the very expensive all-atom model of Jorgensen and Severance. Adsorbed benzene molecules on graphitized thermal carbon black have a complex orientation with ...

2006-01-31

167

A study of the effect of Yttria additions on densification of #beta#-sialon  

International Nuclear Information System (INIS)

In this paper the effect of adding commercially pure yttria concentrate and yttrium carbonate concentrate (NUCLEMON) on the densification of #beta#-Sialon has been studied. The specimens were sintered in graphite furnace at 1720 and 175 deg C, for 1 hour in a nitrogen atmosphere. Densities of up to 99% of the theoretical density were obtained. Microstructural analyses of the specimens were carried out with the aid of an X ray diffractometer and a scanning electron microscope. (author)

1995-06-10

168

100 Areas: (For Technical Progress Letter No. 97), May 7--13  

Science.gov (United States)

Physics information for the D and F piles is presented. Thermal conductivity, reactivity, and irradiation levels are included. Concerning the cooling systems: process water control, pressure drip studies, purging studies, corrosion, and gun barrel clearance of expanded graphite are discussed. (GHH)

1946-05-17

169

The construction of a managerial education discourse and the involvement of philanthropic entrepreneurs: the case of Israel  

British Library Electronic Table of Contents (United Kingdom)

Similar to many other countries, an educational reform anchored in a managerial discourse was proposed in Israel in 2004 by the Dovrat Committee, encouraged by the 'inter-state education gap' social problem that economist Dan Ben-David formulated on the basis of international examinations, such as PISA and TIMMS. Through a neo-Weberian approach this study follows the construction of a managerial discourse from the 1970s onwards that led to the Dovrat report. In the first period, managerial discourse was constructed around decentralization, parent choice and school autonomy 'social objects' by an expanding reformist network of educational scholars and figures from the Ministry of Education and local authorities. The pervasion of managerial discourse paved the way for the nomination of Shlom...

2011-01-01

170

Surface passivation: a new way to reduce self-output in LiMn{sub 2}O{sub 4}/Li lithium ion rechargeable batteries; Passivation de surface: une nouvelle voie pour reduire l`autodecharge dans les batteries rechargeables a ions lithium LiMn{sub 2}O{sub 4}/Li  

Energy Technology Data Exchange (ETDEWEB)

The new generation of performing rechargeable lithium-ion batteries (``rocking-chair``-type) are penalized by important self-output phenomena linked with the use of highly oxidizing positive electrodes. In order to limit this problem in LiMn{sub 2}O{sub 4}/C batteries, two different passivation techniques were used in order to limit the surface contact between the positive electrode and the electrolyte. Thanks to these treatments, a significant reduction of the percentage of irreversible capacity losses is effectively observed. (J.S.) 3 refs.

1996-12-31

171

Subaqueous deposition of reactive mine tailings in an open trench; Deposition subaquatique de residus miniers reactifs dans une fosse a ciel ouvert  

Energy Technology Data Exchange (ETDEWEB)

This poster presentation gave an overview of the subaqueous deposition of reactive mine tailings in the open trench Don Rouyn, located near Rouyn-Noranda, Quebec. The author began by providing a brief background of subaqueous mine tailing storage, and discussed the interest of the Don Rouyn trench. The site was described according to geomorphological and geological aspects. The hydrology conditions existing at the site were mentioned, and the results of the hydrology analysis performed were indicated. Close monitoring of the situation was maintained, and the chemical and physical stability of the tailings were evaluated. The conditions that prevailed both before and after the flooding of the site were explained. Water quality is being monitored, and the results obtained at this site might be used at other locations. 40 figs.

2000-07-01

172

Study of protein-protein interactions in under saturated and supersaturated lysozyme solutions in heavy water as a function of temperature; Etude des interactions proteine-proteine en solutions sous-saturees et sursaturees de lysozyme dans l`eau lourde en fonction de la temperature  

Energy Technology Data Exchange (ETDEWEB)

We have studied freshly prepared lysozyme solutions in heavy water for two NaCl concentrations as a function of temperature. Lysozyme solubilities in this solvent are determined by static light scattering. By small angle neutron scattering, we evidence that interactions between lysozyme molecules are characterized by a second virial coefficient A{sub 2} whether the solution is under-saturated or supersaturated. From the variation of A{sub 2} as a function of temperature we have evaluated the enthalpy corresponding to the interaction between lysozyme molecules. We show that the interactions between protein molecules are higher in heavy water than in light water. (authors). 13 refs., 3 figs.

1996-04-01

173

Study of oxygen diffusion in YBaCuO by isothermal internal friction. Etude par frottement interieur isotherme de la diffusion de l'oxygene dans YBaCuO  

Energy Technology Data Exchange (ETDEWEB)

The elastic behaviour of YBaCuO specimens has been studied by very low-frequency isothermal internal-friction measurements. A relaxation peak is observed which is attributed to oxygen atom jumps, between A(1/2 0 0) and B(0 1/2 0) sites, in the CuO planes of the orthorhombic phase. A limit relaxation time {tau}{sub 0}, 2.6 {center dot} 10{sup -15}s, and an activation energy, 1.3eV, have been obtained from the shift of the maximum damping frequency observed when the measurement temperature is changed. The proposed values for the limit relaxation time and the activation energy are in good agreement with those previously proposed in the literature.

1992-02-07

174

Reconfigurations dynamiques de services dans un intergiciel a composants CORBA CCM  

CERN Document Server

Today, component oriented middlewares are used to design, develop and deploy easily distributed applications, by ensuring the heterogeneity, interoperability, and reuse of the software modules, and the separation between the business code encapsulated in the components and the system code managed by the containers. Several standards answer this definition such as: CCM (CORBA Component Model), EJB (Enterprise Java Beans) and .Net. However these standards offer a limited and fixed number of system services, removing any possibility to add system services or to reconfigure dynamically the middleware. Our works propose mechanisms to add and to adapt dynamically the system services, based on a reconfiguration language which is dynamically adaptable to the need of the reconfiguration, and on a tool of dynamic reconfiguration, a prototype was achieved for the OpenCCM platform, that is an implementation of the CCM specification. This work was partially financed by the european project ...

2004-01-01

175

Non-isothermal Smoluchowski-Poisson equations as a singular limit of the Navier-Stokes-Fourier-Poisson system  

British Library Electronic Table of Contents (United Kingdom)

ResumeLa convergence des solutions faibles du systeme de Navier-Stokes-Fourier-Poisson compressible avec un terme de frottement est etudiee dans la limite dun frottement infini, la loi de pression incluant, comme cas particulier, celle correspondant aux particules de Fermi-Dirac. La limite se trouve etre une solution faible dun systeme de Smoluchowski-Poisson non isotherme, la temperature ne dependant que de la variable temporelle et etant determinee par la conservation de lenergie totale.

2007-01-01

176

New Public Management et professions dans l'Etat : au-dela des oppositions, quelles recompositions ?  

British Library Electronic Table of Contents (United Kingdom)

More and more reforms in public administrations are being conducted that are based on the principles and instruments of ''new public management''. They have set off protest and collective actions by several professional groups in various sectors (health, education, justice, social work, research...), whence questions about the future of professional groups in public services, in particular about their autonomy, which these reforms threaten. The opposition between this new public management and certain professional groups, is not the final explanation to draw from an analysis of this situation. Should these changes be seen as the decline of professional groups and of their autonomy, as a mutation of professional models, an overhaul of professionalism, etc.? These questions, which current ev...

2011-01-01

177

Healthy buildings and installations. Trends at the Healthy Buildings Conference 2003; Gezonde gebouwen en installaties. Trends op Healthy Buildings 2003  

Energy Technology Data Exchange (ETDEWEB)

At the 7th Healthy Buildings Conference, which was held in Singapore, 7-11 December 2003, more than 500 articles to improve public health and productivity of workers in buildings and the performance of installations. Special attention is paid to indoor air quality and thermal comfort in relation to energy efficiency. [Dutch] Op de laatste Healthy Buildings conferentie, december 2003 in Singapore, werden meer dan 500 artikelen gepresenteerd over het creeren van gezonde, productiviteit verhogende gebouwen en installaties. Deze keer lag de nadruk op binnenluchtkwaliteit en thermisch binnenklimaat, onder andere op het aspect energiezuinigheid. Opvallend was ook de aandacht die de problemen met binnenluchtkwaliteit in ontwikkelingslanden kreeg.

2004-02-01

178

Analysis of conditions concerning the natural gas internal market organization in four european countries: Germany, Spain, Netherlands and United Kingdom; Analyse des conditions encadrant l'organisation du marche interieur du gaz naturel dans quatre pays europeens: Allemagne, Espagne, Pays-Bas, Royaume-Uni  

Energy Technology Data Exchange (ETDEWEB)

The aim of this economic study is the wording of a synthetic document for the public information in the framework of the 98/30/CE european directive transposition to the gas internal market. It is writing in four main chapters, one for each country concerned: the Germany, the Spain, the Netherlands and the United Kingdom. Each one presents the historical context, the actors of the natural gas industry and the main provisions. (A.L.B.)

2000-02-01

179

Air conditioning in the industry. A solution to production constraints; Clim dans l`industrie. Une solution aux contraintes de production  

Energy Technology Data Exchange (ETDEWEB)

Industrial premises bear more and more important thermal constraints which can commonly reach 150 W/m{sup 2} and more. The reason is the general development of automation and automatic devices and the better thermal insulation of buildings. Production quality requires also more and more strict ambient conditions (temperature, humidity, air quality, air flow etc..). Thus, the air-conditioning market in the industrial sector is more linked to economic factors such as productivity and profit than to thermal comfort of workers. However, the air-conditioning potentialities in the industrial sector remains under-exploited in France. This paper analyzes the reasons of this situation in terms of investments and equipments. (J.S.)

1997-09-01

180

Air conditioning in high rise buildings; conditionnement d'air dans les immeubles de grande hauteur  

Energy Technology Data Exchange (ETDEWEB)

This book brings together the 103 presentations given at the 2. conference of the international institute of refrigeration (IIF/IIR) about air conditioning in high rise office buildings. The main themes are: design of air conditioning equipment for high buildings; air quality and thermal comfort inside these buildings; constraints and possible improvements of the refrigeration equipment used; energy conservation; fire protection and smokes detection. All themes are presented both on the technical and economical points of view and concern more particularly the buildings of Chinese cities. This publication is available both on the book and CD-Rom forms. (J.S.)

2000-07-01

181

Air conditioning in high rise buildings; Conditionnement d'air dans les immeubles de grande hauteur  

Energy Technology Data Exchange (ETDEWEB)

This two-tomes book brings together the 108 presentations given at the first conference of the international institute of refrigeration (IIF/IIR) about air conditioning in high rise office buildings. The main themes are: general design and control systems, including split systems, radiant panels, fluctuating and gravity ventilation etc..; energy consumption, optimization and heat recovery; cold storage for peak shaving, including ice slurry circulation; indoor air quality; fire and smokes protection, protection against chimney effects and lighting spots; use of fuzzy logic and of neural networks. It includes also a description of the high rise building situation and works in progress in China, Japan and in some other countries. (J.S.)

1997-07-01

182

The carrying out process of Kyoto Protocol in Italy. Methods, scenarios and policy evaluation; Il processo di attuazione del Protocollo di Kyoto in Italia. Metodi, scenari e valutazione di politiche e misure  

Energy Technology Data Exchange (ETDEWEB)

This paper reports some technical contributes related to the Kyoto Protocol and its application in Italian decision making policy. [Italian] Il presente volume raccoglie una decina di contributi tecnici originariamente preparati o commissionati dall'ENEA, Ente Nazionale per le Nuove Tecnologie, l'Energia e l'Ambiente, in vista della Conferenza Nazionale Energia e Ambiente. Questa fotografia di una situazione in rapida evoluzione e' stata preparata da esperti del settore che contribuiscono a redigere il materiale tecnico di base utilizzato dai negoziatori nazionali durante le trattative internazionali e dai responsabili nazionali per avviare il processo di presa di decisioni in materia.

2000-07-01

183

Quarkonia and QGP studies  

CERN Document Server

We summarize results of recent studies of heavy quarkonia correlators and spectral functions at finite temperatures from lattice QCD and systematic T-matrix studies using QCD motivated finite-temperature potentials. We argue that heavy quarkonia dissociation shall occur in the temperature range $1.2 \\le T_d/T_c \\le 1.5$ by the interplay of both screening and absorption in the strongly correlated plasma medium. We discuss these effects on the quantum mechanical evolution of quarkonia states within a time-dependent harmonic oscillator model with complex oscillator strength and compare the results with data for $R_{\\rm AA}/R_{\\rm AA}^{\\rm CNM}$ from RHIC and SPS experiments. We speculate whether the suppression pattern of the rather precise NA60 data from In-In collisions may be related to the recently discovered X(3872) state. Theoretical support for this hypothesis comes from the cluster expansion of the plasma Hamiltonian for heavy ...

2011-01-01

184

Paramagnetic susceptibility of nonstoichiometric fluorides with the fluorite-type structure  

Energy Technology Data Exchange (ETDEWEB)

Magnetic properties of single crystals of nonstoichiometric fluorides M[sub 1-x]R[sub x]F[sub 2+x] (M = Ca, Sr, Ba; R = Ce, Pr, Nd, Gd, Ho, Er, Tm, Yb; with 0.05 [le] x [le] 0.28) with the fluorite-type structure have been studied for the first time. The magnetic susceptibility was measured using a Faraday balance in the 15-300 K temperature range. The samples are paramagnetic following the Curie-Weiss law. The values of paramagnetic Curie temperatures and effective magnetic moments of rare-earth ions have been found. Deviations of the temperature dependence of magnetic susceptibility from the Curie-Weiss law are observed for some nonstoichiometric fluorides at temperatures ranging from 60 to 85 K. Possible reaons for these deviations are discussed. Measurements of magnetic susceptibility provide an effective technique for a rapid and accurate determination of the concentration of rare-earth ions in nonstoichiometric fluorides.

1993-01-01

185

Influence of vanadium doping on the electrochemical behaviour of MnO{sub 2} rutile; Influence du dopage par le vanadium sur le comportement electrochimique de MnO{sub 2} rutile  

Energy Technology Data Exchange (ETDEWEB)

Vanadium doped manganese bi-oxide has been obtained from a solution containing both cations. The X-ray diffraction of this material indicates a rutile-type phase but the enlargement of some lines supports the existence of several lattice defects. Also the particle size of the doped material is significantly smaller than the one of the non-doped material obtained in the same conditions. The presence of pentavalent vanadium inside the lattice leads to a small amount of trivalent manganese. Electron microscopy shows the existence of defects which have a tendency of becoming well-ordered and to stabilize a sur-structure. At ambient temperature, the electrochemical behaviour of doped manganese bi-oxide is greatly improved when compared to the non-doped phase. This behaviour is due to the presence of numerous lattice defects and to the smaller size of crystallites. In polymer batteries, the behaviour is similar the one of the non-doped material for which the kinetics performances are ...

1996-12-31

186

Indentation modulus and hardness in heteroepitaxial Al{sub x}Ga{sub 1{minus}x}P films  

Energy Technology Data Exchange (ETDEWEB)

Al{sub x}Ga{sub 1{minus}x}P layers (0 {le} x {le} 0.7), with thicknesses of {ge}1 {micro}m were grown on Si (100) wafers by metal-organic molecular beam epitaxy (MOMBE) at 450 C. Transmission electron micrographs of the single crystal films revealed that the microstructure contains stacking faults and microtwins especially near the interface as well as both threading and misfit dislocations. Hardness and elastic modulus were measured using a Nanotest 500 indenter, which can probe the film properties without influence from the substrate. The hardness H varies linearly according to (11.8 {minus} 2.3x) GPa. The absence of alloy hardening is due to the fact that there is no difference in atomic size of Al and Ga. The indentation modulus E/(1{minus}v{sup 2}) decreases monotonically from 136 GPa for GaP to 129 GPa for Al{sub 0.7}Ga{sub 0.3}P and bows only slightly (about 2%) below the straight line of linear interpolation.

1997-05-01

187

Field-induced valence transition of Eu(Pd{sub 1{minus}x}Pt{sub x}){sub 2}Si{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

The magnetic susceptibility and high-field magnetization have been measured for the intermediate valence system Eu(Pd{sub 1{minus}x}Pt{sub x}){sub 2}Si{sub 2} with 0{le}x{le}0.15. A first-order valence transition is observed for all the compounds under high field of 100 T at low temperatures. This valence transition is of first order accompanied with a large hysteresis, which is in contrast to a continuous valence change against temperature. Based on the interconfigurational fluctuation (ICF) model, the temperature- and field-induced valence transitions are discussed. It is found that a first-order valence transition can be induced by magnetic field, even if the system shows a continuous valence transition against temperature. Metamagnetic behavior at finite temperatures is also understood qualitatively by the ICF model. {copyright} {ital 1997} {ital The American Physical Society}

1997-05-01

188

Dosimetry in dental radiology. Dentascan spiral CT versus panoramic radiography; Dosimetria nella radiologia odontostomatologica: confronto tra tomografia computerizzata spirale e ortopantomografia  

Energy Technology Data Exchange (ETDEWEB)

The study compares the doses absorbed by the dentomaxillary area in spiral CT and panoramic examinations. The dose measurements demonstrate that patients receive smaller doses with panoramic radiography than with spiral CT with Dentascan. After following for some variations from instrumental differences, they are in substantial agreement with literature data. Further investigations are needed considering the radiobiological risk related to the growing spread of Dentascan examinations. [Italian] Questo lavoro intende confrontare le dosi assorbite nel distretto dento-mascellare, con le due principali tecniche utilizzate in questo campo: TC spirale e ortopantomografia. Emerge come l'esame panoramico delle arcate dentarie eseguito con l'ortopantomografo comporti la'ssorbimento di dosi inferiori rispetto a quelle dell'esame TC spirale con programma Dentascan. Questi dati, pur essendo soggetti a ...

1999-05-01

189

Cosmic-Ray Nuclei, Antiprotons and Gamma-rays in the Galaxy: a New Diffusion Model  

CERN Document Server

We model the transport of cosmic ray nuclei in the Galaxy by means of a new numerical code. Differently from previous numerical models we account for a generic spatial distribution of the diffusion coefficient. We found that in the case of radially uniform diffusion, the main secondary/primary ratios (B/C, N/O and sub-Fe/Fe) and the modulated antiproton spectrum match consistently the available observations. Convection and re-acceleration do not seem to be required in the energy range we consider: $1 \\le E \\le 10^3$ GeV/nucleon. We generalize these results accounting for radial dependence of the diffusion coefficient, which is assumed to trace that of supernova remnants. While this does not affect the prediction of secondary/primary ratios, the simulated longitude profile of the diffuse $\\gamma$-ray emission is significantly different from the uniform case and may agree with EGRET measurements without invoking {\\it ad hoc} assumptions on ...

2008-01-01

190

Understanding and profitably managing customer loyalty  

British Library Electronic Table of Contents (United Kingdom)

Purpose - The purpose of the paper is to draw together the salient issues surrounding customer loyalty and customer relationship management (CRM) into a single coherent discussion. Various schools of academic thought are examined. The paper concludes with practical implications for managers. Design/methodology/approach - The literature surrounding customer loyalty, customer satisfaction, effective CRM and managing loyalty in a profitable manner are all reviewed. The paper allows managers to consider a wide range of material in the context of their business. Findings - The need for businesses to retain customers is an important issue in today's global marketplace. To retain customers, a business must forge loyal and long-term relationships with profitable customers. Reasons why customers le...

2008-01-01

191

Thermodynamic Model of Aluminum Combustion in SDF Explosions  

Energy Technology Data Exchange (ETDEWEB)

Thermodynamic states encountered during combustion of Aluminum powder in Shock-Dispersed-Fuel (SDF) explosions were analyzed with the Cheetah code. Results are displayed in the Le Chatelier diagram: the locus of states of specific internal energy versus temperature. Accuracy of the results was confirmed by comparing the fuel and products curves with the heats of detonation and combustion, and species composition as measured in bomb calorimeter experiments. Results were fit with analytic functions u = f(T) suitable for specifying the thermodynamic properties required for gas-dynamic models of combustion in explosions.

2006-06-19

192

The regional control of the canadian energy production; Le contraste provincial de la production energetique canadienne  

Energy Technology Data Exchange (ETDEWEB)

This document provides information and presents data on the energy situation in many regions of Canada. The first part deals with the petroleum and the bitumen shales of Alberta (reserves, exploitation and production, environmental impacts), the second part discusses with the hydroelectricity choice of Quebec and the 2004 crisis. The nuclear situation of Ontario is presented in the third part (nuclear park, programs, uranium reserves, research and development on Candu reactors), while the fourth part deals with the renewable energies (wind power and biomass). The canadian situation facing the Kyoto protocol is discussed in the last part. (A.L.B.)

2004-12-01

193

The oil at 50$: reserves depletion or OPEC revenge?; Le petrole a 50$: epuisement des reserves ou revanche de l'OPEP?  

Energy Technology Data Exchange (ETDEWEB)

Although the oil price is still far from its historical maximum, the oil market is today in crisis. To explain this situation the author discusses the nature of the supply constraints. The reserves are today better known and so more plentiful than at a previous period of the oil history and the russian production since 2004 is stagnating. The main factor seems to be the OPEC policy and in particular the will of limiting the oil production to defend upper prices. (A.L.B.)

2005-06-15

194

Surveillance and control. A new edition of the BETCGB guidebook for the control of dams in exploitation; Surveillance et controle. Une nouvelle edition du guide du BETCGB pour le controle des barrages en exploitation  

Energy Technology Data Exchange (ETDEWEB)

The French office for technical studies and control of big dams (BETCGB), has recently reedited the `guidebook for the control of dams in exploitation`. The aim of this document is to provide to the regional directions of industry, research and environment (DRIRE) a methodological help for their control actions of hydroelectric dams granted for exploitation. It comprises 6 chapters dealing with: the different type of dams, the inspection, the surveillance, the floods evacuation, the flood instructions, and the particular emergency plans. (J.S.)

1998-12-31

195

Radiology of facial injury  

Energy Technology Data Exchange (ETDEWEB)

The authors present a guide to the imaging of facial fractures. It is illustrated with conventional radiographs and computed tomograms; the magnetic resonance images primarily suggest the potential applications of this technique. This book provides a source of imaging information on facial trauma. A section on pertinent anatomy is followed by a systematic discussion of the common isolated and complex facial fractures. Perspectives are offered on some commonly seen but infrequently described relationships, such as the tripod-LeFort II association. Consideration is also given to related soft-tissue injuries. The book includes a brief chapter on the type and utility of supplementary imaging studies in the evaluation of those intracranial injuries that may occur concurrently.

1988-01-01

196

Principles for occupational exposure control; Principes pour le controle des expositions professionnelles  

Energy Technology Data Exchange (ETDEWEB)

A major component of the 1990 recommendations of ICRP (ICRP, 1991a) was the revision of the dose limits. But other changes were introduced which necessitated a review of earlier guidance. In particular, ICRP set up a Task Group in 1993 to prepare a report on the principles for the protection of workers. The report was adopted in 1997 and has now been published as ICRP Publication 75 (ICRP, 1997). It is for others to judge the real significance of the guidance provided; what follows are some of the main points. (author)

1997-10-01

197

Penetrants for hot surfaces in welding inspection: experimental work and first results; Penetrants pour le controle de surfaces chaudes lors du soudage: etude experimentale et premiers resultats obtenus  

Energy Technology Data Exchange (ETDEWEB)

Preliminary results of studies into penetrant testing at high surface temperature (up to 200 deg.C), are presented. Tests were performed to assess the effectiveness of red dye penetrants using Al and NiCr samples containing artificial as well as natural discontinuities. The test results will be used in due course to formulate a specification for non-destructive testing procedure qualification at non-standard (i.e. outside 16-52 deg.C) temperatures.

2000-04-01

198

On the Generic vanishing of certain Koszul cohomology groups  

CERN Document Server

We propose a new approach to study Koszul cohomology of general $g^r_d$'s on general curves via degenerations and deformations. As an application of this new method, we prove projective normality for general line bundles $L$ on general curves with $h^1(L)\\le1$ and degree greater than roughly $(5/4)g$. This improves the bound in a classical theorem of Green and Lazarsfeld. Also we give some partial results on vanishing of higher syzygies for line bundles with $h^1(L)=1$.

2011-01-01

199

Malnutrition, Gut-Microbial Interactions and Mucosal Immunity to Vaccines, 07 Nov 2011 - 11 Nov 2011, Le Meridien New Delhi, New Delhi, India - SciDe  

Wastenet

... A better understanding of the links between nutrients, the gut microbiome and the intestinal immune system is likely to pave the way to the development of innovative approaches that target activation of specific immunological pathways for promoting the hostrsquo;s gut defense. Such knowledge should positively impact on the development of vaccine formulations and intervention strategies for improved control of enteric infections in developing countries. Registration fees # The Registration Fee is $715.00 on and before September 7, 2011. # After September 7, 2011, the ...

200

Le LHC, un projet mondial  

CERN Multimedia

Since the mid-1980s the number of scientists from all over the world using CERN's facilities has increased enormously. Currently more than 6,000 users, over half of the planet's high-energy physicists, carry out fundamental research at CERN. This user community is living proof that CERN welcomes inter- regional collaboration which benefits all and boosts the progress of science. The LHC, the only machine capable of addressing problems way beyond today's frontiers of high energy physics, offers an unique opportunity for extending world wide collaboration.

1994-01-01

201

Interest of a two-dimensional matrix of detectors for the quality control of beams in static or dynamic mode; Interet d'une matrice bidimensionnelle de detecteurs pour le controle de qualite des faisceaux en mode statique ou dynamique  

Energy Technology Data Exchange (ETDEWEB)

A 2D matrix allows a fairly rapid verification of irradiation parameters transferred on computer processing equipment without expanding the dosimetry means to implement. Associated to 'Multicheck and Verisoft' software it will handle some of the regulatory recommendations of the A.F.S.S.A.P.S. for quality control of accelerators and ensure the traceability of testing carried out. (N.C.)

2007-11-15

202

Gunshot wounds of abdomen detected at CT. Personal experience in 30 patients; Ferite da arma da fuoco dell'addome studiate con tomografia computerizzata: esperienza personale in 30 casi  

Energy Technology Data Exchange (ETDEWEB)

The paper investigates the yield and the role of the computerized tomography in diagnosing abdominal gunshot wounds, with their rich and varied radiological signs and associated injuries, and subsequently used in the diagnosis. [Italian] Scopo del lavoro e' riportare l'esperienza personale nell'uso della tomografia computerizzata per riconoscere le lesioni da arma da fuoco dell'addome e nelle fasi successive dell'approfondimento diagnostico.

1999-09-01

203

Cosmic no-hair theorem in power-law inflation  

Energy Technology Data Exchange (ETDEWEB)

We prove a cosmic no-hair theorem for Bianchi models in power-law inflation. Provided that the potential of an inflaton {phi} is exp({minus}{lambda}{kappa}{phi}) with 0{le}{lambda}{lt} {radical}2/3 , we find that the isotropic power-law solution is the unique attractor for any initially expanding Bianchi-type models except type IX. For Bianchi type IX, this conclusion is also true if the initial ratio of the vacuum energy to the maximum three-curvature is larger than one half.

1992-02-15

204

Bone geometry, biomechanics, and mineral content of the distal radius in uremic patients with severe hyperparathyroidism; Valutazione delle proprieta' geometriche, biomeccaniche e osteodensitometriche del radio ultradistale mediante tomografia computerizzata quantitativa periferica nei pazienti uremici affetti da iperparatiroidismo grave  

Energy Technology Data Exchange (ETDEWEB)

Bone integrity and mineral status were studied with a noninvasive method in uremic patients with severe secondary hyperparathyroidism undergoing maintenance hemodialysis. [Italian] Gli autori propongono un metodo non invasivo per studiare la densita' minerale e le caratteristiche geometriche e biomeccaniche dell'osso nei pazienti uremici affetti da iperparatiroidismo secondario grave.

1999-04-01

205

Use of carbon stable isotope to investigate chloromethane formation in the electrolytic dechlorination of trichloroethylene  

International Nuclear Information System (INIS)

Carbon stable isotope trichloroethylene ("1"3C TCE) was used to investigate the formation of chloromethane (CM) during the electrolytic dechlorination of trichloroethylene (TCE) at a granular-graphite packed cathode. A method was developed to use a conventional GC/MS to analyze and quantify regular and "1"3C TCE and their dechlorination products. The concentration of a "1"3C compound can be calculated, based on the concentration of its regular counterpart, from the response ratio of two fragments of different mass per charge values from the compounds in a sample and two characteristic MS spectrum ratios: one is the response ratio of the two fragments of the regular compound, and the other is the response ratio of the corresponding fragments of the regular and "1"3C compounds at the same concentrations. The method was used to analyze the regular and "1"3C compounds observed in an experiment of dechlorination in an ammonium acetate solution that contained both ...

2007-03-22

206

Study of the carbon material / electrolyte interface; Etude de l`interface materiau carbone / electrolyte  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is the comparative study of the properties of the natural graphite/liquid organic electrolyte interface by impedance spectroscopy with respect to different lithium salts (LiX with X = ClO{sub 4}{sup -}, BF{sub 4}{sup -}, CF{sub 3}SO{sub 3}{sup -}, N(CF{sub 3}SO{sub 2}){sub 2}{sup -}, PF{sub 6}{sup -}). The evolution of the interface properties during the first electrochemical reduction suggests different mechanisms of formation of passivation films. A more stable, thin and homogenous film seems to develop when the LiN(CF{sub 3}SO{sub 2}){sub 2} or LiPF{sub 6} lithium salts are used. The chemical diffusion coefficient of lithium in graphite has been determined by impedance spectroscopy. (J.S.) 16 refs.

1996-12-31

207

Structure-retention correlations of hydrocarbons in gas-liquid and gas-solid chromatography. Cycloalkenes and cycloalkadienes  

Energy Technology Data Exchange (ETDEWEB)

The retention indices of cycloalkenes and cycloalkadienes with C/sub 6/-C/sub 13/ rings are determined by gas-liquid chromatography (GLC) on glass capillary columns coated with OV-1 and Ucon LB 550X and by gas-solid chromatrography (GSC) on a microcolumn packed with uncoated graphitized thermal carbon black (GTCB). Structure-retention correlations are derived on using index differences such as H/sup OV/, H/sup GTCB/ and ..delta..I values, considering the differences in the stereochemistry of these compounds. It is shown that the combined application of index increments obtained in GLC and GSC provides more detaled structure informations. The value of the retention index units agree with the most stable conformations of the alicyclic compounds. The high value for the energy equivalent to an index unit (..delta..G/sub I.U./ = 4.18 kJ/mol) confirms that graphitized thermal carbon black causes much stronger dispersive interactions than any nonpolar ...

1987-08-01

208

Solid-state lithium battery with graphite anode  

Energy Technology Data Exchange (ETDEWEB)

Solid-state lithium batteries with a unique construction are reported in this paper. These batteries contain two kinds of lithium ion-conductive solid electrolytes, LiI-Li{sub 2}S-P{sub 2}S{sub 5} glass contacted with the anode material and Li{sub 3}PO{sub 4}-Li{sub 2}S-SiS{sub 2} glass or Li{sub 2}S-GeS{sub 2}-P{sub 2}S{sub 5} crystalline material contacted with the cathode. The former electrolyte was selected as that stable to electrochemical reduction, and the latter two to oxidation. This construction made it possible to use graphite as the anode and LiCoO{sub 2} as the cathode in the solid-state lithium battery. The energy density of the battery is 390 W h{center_dot}l{sup -1} and 160 W h{center_dot}kg{sup -1} per total volume and weight of the cathode and anode layers, respectively, which are comparable to those of commercialized Li-ion batteries.

2003-03-01

209

Radiotracer study of the preatomization behavior of lead in the graphite furnace  

Energy Technology Data Exchange (ETDEWEB)

The behavior of lead in the graphite furnace during the individual steps of the temperature program was investigated by means of /sup 203/Pb as a radiotracer. The matrix systems include HCl and HNO/sub 3/ solutions, 1% NaCl solution, blood, serum, urine, and the solid samples bovine liver and orchard leaves. Without matrix modificaton, a pyrolysis temperature of up to 500/sup 0/C can be used for all samples. Significant stabilization effects can be achieved in the preatomization steps by using NH/sub 4/H/sub 2/PO/sub 4/ and ammonia as matrix modifiers and by addition of hydrogen to the flowing argon gas. It was found that the use of a L'vov platform also helps to eliminate the matrix effects. With respect to lead stabilization and elimination of matrix effects, optimum experimental conditions are achieved by simultaneous use of a L'vov platform and NH/sub 4/H/sub 2/PO/sub 4/ as the matrix modifier. 34 references, 5 figures, 1 table.

1985-01-01

210

Radiotracer study of the preatomization behavior of lead in the graphite furnace  

International Nuclear Information System (INIS)

The behavior of lead in the graphite furnace during the individual steps of the temperature program was investigated by means of "2"0"3Pb as a radiotracer. The matrix systems include HCl and HNO_3 solutions, 1% NaCl solution, blood, serum, urine, and the solid samples bovine liver and orchard leaves. Without matrix modificaton, a pyrolysis temperature of up to 500"0C can be used for all samples. Significant stabilization effects can be achieved in the preatomization steps by using NH_4H_2PO_4 and ammonia as matrix modifiers and by addition of hydrogen to the flowing argon gas. It was found that the use of a L'vov platform also helps to eliminate the matrix effects. With respect to lead stabilization and elimination of matrix effects, optimum experimental conditions are achieved by simultaneous use of a L'vov platform and NH_4H_2PO_4 as the matrix modifier. 34 references, 5 figures, 1 table.

211

RCRA closure of the Building 3001 Storage Canal  

Energy Technology Data Exchange (ETDEWEB)

The 3001 Storage Canal is located under portions of Buildings 3001 and 3019 at Oak Ridge National Laboratory (ORNL) and has a capacity of approximately 62,000 gallons of water. The term canal has historically been used to identify this structure, however, the canal is an in-ground reinforced concrete structure satisfying the regulatory definition of a tank. From 1943 through 1963, the canal in Building 3001 was designed to be an integral part of the system for handling irradiated fuel from the Oak Ridge Graphite Reactor. Because one of the main initial purposes of the reactor was to produce plutonium for the chemical processing pilot plant in Building 3019, the canal was designed to be the connecting link between the reactor and the pilot plant. During the war years, natural uranium slugs were irradiated in the reactor and then pushed out of the graphite matrix into the system of diversion plates and chutes which directed the fuel into the deep ...

1992-09-01

212

Porous tooling process for manufacture of graphite/polyimide composites. Final report  

Energy Technology Data Exchange (ETDEWEB)

A porous tooling system was selected for the processing of Graphite/PMR-15 Polyimide laminates in thickness up to 3.2 mm. (0.125 inch). This tool system must have a reasonable strength, permeability dimensional stability, and thermal conductivity to accomplish curing at 600 F and 200 psi and 200 psi autoclave temperature and pressure. A permeability measuring apparatus was constructed and permeability vs. casting water level determined to produce tools at three different permeability levels. On these tools, laminates of 5, 11, and 22 plies (.027, .060, and 0.121 inch) were produced and evaluated by ultrasonic, mechanical, and thermal tests to determine the effect of the tool permeability on the cured laminates. All tools produced acceptable laminates at 5 and 11 plies but only the highest permeability produced acceptable clear ultrasonic C-Scans. Recommendations are made for future investigations of design geometry, and strengthening techniques for porous ceramic ...

1981-01-01

213

Nuclear Reactor Sharing Program  

Energy Technology Data Exchange (ETDEWEB)

The Ohio State University Research Reactor (OSURR) is licensed to operate at a maximum power level of 500 kW. A pool-type reactor using flat-plate, low enriched fuel elements, the OSURR provides several experimental facilities including two 6-inch i.d. beam ports, a graphite thermal column, several graphite-isotope-irradiation elements, a pneumatic transfer system (Rabbit), various dry tubes, and a Central Irradiation Facility (CIF). The core arrangement and accessibility facilitates research programs involving material activation or core parameter studies. The OSURR control room is large enough to accommodate laboratory groups which can use control instrumentation for monitoring of experiments. The control instrumentation is relatively simple, without a large amount of duplication. This facilitates opportunities for hands-on experience in reactor operation by nuclear engineering students making reactor parameter measurements. For neutron ...

1994-09-01

214

Method for forming a bladder for fluid storage vessels  

Energy Technology Data Exchange (ETDEWEB)

A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable for hydrogen, gas mixtures, and oxygen ...

2000-01-01

215

Lightweight bladder lined pressure vessels  

Energy Technology Data Exchange (ETDEWEB)

A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable for hydrogen, gas mixtures, and oxygen ...

1998-01-01

216

Graphite electrode arc melter demonstration Phase 2 test results  

Energy Technology Data Exchange (ETDEWEB)

Several U.S. Department of Energy organizations and the U.S. Bureau of Mines have been collaboratively conducting mixed waste treatment process demonstration testing on the near full-scale graphite electrode submerged arc melter system at the Bureau`s Albany (Oregon) Research Center. An initial test series successfully demonstrated arc melter capability for treating surrogate incinerator ash of buried mixed wastes with soil. The conceptual treatment process for that test series assumed that buried waste would be retrieved and incinerated, and that the incinerator ash would be vitrified in an arc melter. This report presents results from a recently completed second series of tests, undertaken to determine the ability of the arc melter system to stably process a wide range of {open_quotes}as-received{close_quotes} heterogeneous solid mixed wastes containing high levels of organics, representative of the wastes buried and stored at the Idaho National Engineering ...

1996-06-01

217

Friction properties of WS{sub 2}/graphite fluoride thin films grown by pulsed laser deposition  

Energy Technology Data Exchange (ETDEWEB)

Graphite fluoride (CF{sub x}) is investigated as an additive for WS{sub 2} thin films to reduce its sensitivity to moisture. The films are grown onto hardened 440C stainless steel disks by pulsed laser deposition using the 248 nm line from an excimer laser. Substrate temperature and additive concentration are varied to control film chemistry and crystal structure. The effect of relative humidity (i.e., < 1 to 85% RH) on friction is evaluated. Coatings grown at RT from targets with a low concentration of CF{sub x} exhibit ultra-low friction (ULF) behavior in dry air (i.e., {mu} {<=} 0.01), but friction increases with RH. Mechanisms for the ULF behavior are proposed which suggest that further reductions in friction are possible. Films grown at 300 C or with higher concentrations of CF{sub x} are relatively insensitive to humidity, but have more typical friction coefficients ({mu} {<=} 0.04) in dry air. (orig.)

1995-12-01

218

Cellulose as a binding material in graphitic anodes for Li ion batteries: a performance and degradation study  

Energy Technology Data Exchange (ETDEWEB)

Four types of cellulose, in particular carboxy methyl cellulose (CMC), are tested as potential binding materials in graphitic anodes for lithium ion batteries. It is shown that a minimum content of a cellulose which gives acceptable anode properties (reversible capacity > 300 mA hg{sup -1} during the first 10 cycles, irreversible loss < 20%) is about 2 wt.%, which is less than in the case of conventional polymeric binders (5-10 wt.%). Kinetics of insertion-deinsertion and passivation processes seem not to be affected by the presence of cellulose. Explanation for the electrode failure at cellulose contents lower than 1 wt.% is given based on X-ray diffraction and microscopy investigations. Finally, the structure (distribution) of cellulose in the composite anode material is discussed and (indirectly) checked with a series of experiments. Most results are compared with the corresponding results obtained either with gelatin or conventional polymeric ...

2003-02-20

219

Bypass Flow and Hot Spot Analysis for PMR200 Block-Core Design with Core Restraint Mechanism  

Energy Technology Data Exchange (ETDEWEB)

The accurate prediction of local hot spot during normal operation is important to ensure core thermal margin in a very high temperature gas-cooled reactor because of production of its high temperature output. The active cooling of the reactor core determining local hot spot is strongly affected by core bypass flows through the inter-column gaps between graphite blocks and the cross gaps between two stacked fuel blocks. The bypass gap sizes vary during core life cycle by the thermal expansion at the elevated temperature and the shrinkage/swelling by fast neutron irradiation. This study is to investigate the impacts of the variation of bypass gaps during core life cycle as well as core restraint mechanism on the amount of bypass flow and thus maximum fuel temperature. The core thermo fluid analysis is performed using the GAMMA+ code for the PMR200 block-core design. For the analysis not only are some modeling features, developed for solid conduction and bypass flow, ...

2009-10-15

220

Bypass Flow and Hot Spot Analysis for PMR200 Block-Core Design with Core Restraint Mechanism  

International Nuclear Information System (INIS)

The accurate prediction of local hot spot during normal operation is important to ensure core thermal margin in a very high temperature gas-cooled reactor because of production of its high temperature output. The active cooling of the reactor core determining local hot spot is strongly affected by core bypass flows through the inter-column gaps between graphite blocks and the cross gaps between two stacked fuel blocks. The bypass gap sizes vary during core life cycle by the thermal expansion at the elevated temperature and the shrinkage/swelling by fast neutron irradiation. This study is to investigate the impacts of the variation of bypass gaps during core life cycle as well as core restraint mechanism on the amount of bypass flow and thus maximum fuel temperature. The core thermo fluid analysis is performed using the GAMMA+ code for the PMR200 block-core design. For the analysis not only are some modeling features, developed for solid conduction and bypass flow, ...

2009-10-01

221

A water calorimeter for high energy x-rays and electrons  

CERN Document Server

The current primary standards at NPL for the measurement of absorbed dose to water in high energy photon and electron beams are graphite calorimeters. However, the quantity of interest in radiation dosimetry is absorbed dose to water. Therefore, a new absorbed dose to water standard based on water calorimetry has been developed for use in high energy photon and electron beams. The calorimeter operates at 4 deg C, with temperature control being provided by liquid cooling. The sealed glass inner vessel of the calorimeter was designed to minimise the effect of non-water materials on the measurement of absorbed dose. The temperature sensing thermistor probes were designed and constructed so that glass is the only material in contact with high purity water inside the vessel. Initial measurements of absorbed dose to water made in 6, 10, and 19 MV photons, and 16 MeV electrons agreed, within the measurement uncertainties of approximately 1.5% (95% c.l.), with those ...

2000-01-01

222

A study of kerf characteristics in abrasive waterjet machining of graphite/epoxy composite  

Energy Technology Data Exchange (ETDEWEB)

Kerf geometry, kerf wall features, and cutting front characteristics of an Abrasive Waterjet (AWJ) machined Graphite/Epoxy (Gr/Ep) laminate were studied. A macroscopic analyses suggests that geometrical features associated with AWJ machining of Gr/Ep laminates are influenced by three macro regions along the cutting depth. The presence of these regions, including initial damage at jet entry, smooth cutting, and rough cutting near the jet exit, depends on the operating conditions. Design of experiments and analysis of variance were used to determine the effect of cutting parameters on kerf characteristics and to develop empirical models for kerf profile and features of the three distinct macroscopic regions. Cutting front analysis revealed that the mechanisms of material removal in AWJ machining of Gr/Ep do not change over the jet penetration depth. In general, high quality uniform cuts may be obtained by minimizing initial damage at the jet entry and by extending ...

1996-04-01

223

Comparative cold resistance of three Columbia River organisms  

Science.gov (United States)

Resistance to abrupt and gradual cold shock was determined in bioassays with pumpkinseed (Lepomis gibbosus), rainbow trout (Salmo gairdneri), and a northwestern crayfish (Pacifastacus leniusculus) acclimated to higher temperatures at 5 C increments. Test criteria were median tolerance limits (TLm) for 96-h exposures after abrupt cold shock, and 50 percent loss of equilibrium (LE50) for decline rates of 18, 15, 10, 5, and 1 C/h during gradual cold shock. Cold resistance depended on original acclimation temperature (AT) and varied among species under both test conditions in the order: pumpkinseed less than rainbow trout less than crayfish. The lower TLm limit for pumpkinseed was 12.3 C at 30 C AT, 9.6 C at 25 C AT, 4.5 C at 20 C AT, and 2.7 C at 15 C AT. Rainbow trout at 20, 15 and 10 C AT survived abrupt exposures to cold down to 3.3, 1.4 and 0.5 C, respectively. Crayfish at 25, 20 and 15 C AT survived exposures down to 2.5, 0.4 and 0.0 C, respectively. TLm values ...

1977-03-01

224

A nonmolecular derivation of Maxwell's thermal-creep boundary condition in gases and liquids via application of the LeChatelier-Braun principle to Maxwell's thermal stress  

Science.gov (United States)

According to the LeChatelier-Braun principle, when a closed quiescent system initially in an equilibrium or unstressed steady state is subjected to an externally imposed ``stress'' it responds in a manner tending to alleviate that stress. Use of this entropically based qualitative rule, in combination with the notion of Maxwell thermal stresses existing in nonisothermal gases and liquids, enables one to (i) derive Maxwell's thermal-creep boundary condition prevailing at the boundary between a solid and a fluid (either gas or liquid) and (ii) rationalize the phenomenon of thermophoresis in liquids, for which, in contrast with the case of gases, an elementary explanation is currently lacking. These two objectives are achieved by quantitatively interpreting the heretofore qualitative LeChatelier-Braun notion of stress in the present context as being the fluid's stress tensor, the latter including Maxwell's thermal stress. In effect, thermophoretic ...

2009-05-01

225

X-ray observation of a. sqrt. 3 x. sqrt. 3 superlattice in KC/sub 8/ at high pressure  

Energy Technology Data Exchange (ETDEWEB)

A single-crystal x-ray study under pressure reveals a phase transition from an in-plane 2x2 commensurate potassium superstructure to a new ..sqrt..3x..sqrt..3 commensurate superstructure. This is the first such transition to be observed; it is related to the recently discovered staging transition of KC/sub 8/ under pressure. In addition this staging transition was observed to occur more slowly and at much lower pressures than in the reported neutron-scattering experiment on highly oriented pyrolytic graphite samples. 13 references, 2 figures.

1985-05-15

226

Wear and friction measurements on CVD coated carbon alloy bearing surfaces  

Energy Technology Data Exchange (ETDEWEB)

A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.))

1995-03-01

227

Wear and friction measurements on CVD coated carbon alloy bearing surfaces  

International Nuclear Information System (INIS)

A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.)).

228

Testing of 12Kh18N10T tube steel samples tendency to intergranular corrosion  

International Nuclear Information System (INIS)

Tendency of 12Kh18N10T steel tube samples to intergranular corrosion (IGC) is investigated by an express electrochemical method in the 10% solution of H_2SO_4+0.0025 g/l of KCNS. Tendency to IGC is mainly detected on the internal surface of tube samples. It is shown that the tendency to INC under plant conditions is caused by surface carburization under its incomplete purification from the graphite lubrication.

1993-01-01

229

Real time neutron diffraction study on the intercalation of deuterobenzene into RbC/sub 24/  

Energy Technology Data Exchange (ETDEWEB)

The reaction of RbC/sub 24/ with C/sub 6/D/sub 6/ vapour was studied by neutron diffraction on a time scale of 5 min/spectrum. As for the reaction of KC/sub 24/, a second stage phase RbC/sub 24/(C/sub 6/D/sub 6/)sub(y) is initially formed and subsequently transformed into a first stage phase. Model calculations indicate that the benzene rings are canted against the graphite planes both in the first and in the second stage phase.

1983-11-01

230

On the threshold of the 21st Century in the Soviet Union  

International Nuclear Information System (INIS)

In the last 30 years the production of electricity in the USSR has increased 14-fold, probably attaining 1540 billion kWH in 1985. Nuclear generation will provide the bulk of future increases of consumption, using both water-cooled and uranium/graphite reactors; stations of up to 1.5 million kW are in service. The USSR is also in the fore-front of attempts to exploit thermonuclear power. The USSR is also conducting experiments with renewable sources of energy such as solar, geothermal, wind and wave power and with magnetohydrodynamic generation. (D.A.J.).

231

Metastable carbon in two chondritic porous interplanetary dust particles  

International Nuclear Information System (INIS)

An analytical electron microscope study is presented on carbonaceous material in two chondritic porous aggregates, W7029* A and W7010* A2, from the Johnson Space Center Cosmic Dust Collection. The finding of well-ordered carbon-2H (lonsdaleite) in the two aggregates suggests that a record of hydrocarbon carbonization may be preserved in these materials. This carbon is a metastable phase resulting from hydrous pyrolysis below 300-350"0C and may be a precursor to poorly graphitized carbons in primitive extra terrestrial materials. (UK).

232

Interrelation between the spatial structure of unsaturated hydrocarbon molecules and heats of their adsorption  

British Library Electronic Table of Contents (United Kingdom)

The total area (s m) of Voronoi-Dirichlet polyhedron faces corresponding to all intermolecular contacts of one molecule in the structure of crystals and the total volume of pyramids (V m) built on such faces and containing the nuclei of atoms participating in intermolecular contacts in their vertices were determined for 19 unsaturated hydrocarbons. The differential molar heat of adsorption of the hydrocarbons on graphitized thermal carbon black was found to be linearly related to the s m or V m integral parameters of their Voronoi-Dirichlet polyhedra. Aromatic hydrocarbons on the one hand and saturated hydrocarbons, olefins, and acetylene on the other are characterized by different dependences because of the special shapes of their molecular Voronoi-Dirichlet polyhedra.

2008-01-01

233

Interrelation between the spatial structure of unsaturated hydrocarbon molecules and heats of their adsorption  

Science.gov (United States)

The total area ( s m) of Voronoi-Dirichlet polyhedron faces corresponding to all intermolecular contacts of one molecule in the structure of crystals and the total volume of pyramids ( V m) built on such faces and containing the nuclei of atoms participating in intermolecular contacts in their vertices were determined for 19 unsaturated hydrocarbons. The differential molar heat of adsorption of the hydrocarbons on graphitized thermal carbon black was found to be linearly related to the s m or V m integral parameters of their Voronoi-Dirichlet polyhedra. Aromatic hydrocarbons on the one hand and saturated hydrocarbons, olefins, and acetylene on the other are characterized by different dependences because of the special shapes of their molecular Voronoi-Dirichlet polyhedra.

2008-08-01

234

High capacity anode materials for rechargeable sodium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Electrochemical techniques have been used to study the reversible insertion of sodium into hard-carbon host structures at room temperature. In this paper the authors compare these results with those for lithium insertion in the same materials and demonstrate the presence of similar alkali metal insertion mechanisms in both cases. Despite the gravimetric capacities being lower for sodium than lithium insertion, the authors achieved a reversible sodium capacity of 300 mAh/g, close to that for lithium insertion in graphitic carbon anode materials. Such materials may therefore be useful as anodes in rechargeable sodium-ion batteries.

2000-04-01

235

Graphitic nano tubes and aligned nano tubes films  

Energy Technology Data Exchange (ETDEWEB)

Carbon nano tubes are easily produced in macroscopic quantities, however their characterisation and possible applications are still rather limited. We have developed a new method to make aligned nano tube films which open new opportunities, not only for basic research but also for eventual applications. With this method the tubes can be aligned either parallel or perpendicular to the surface. We give a short review of the microscopic properties of single tubes and the bulk properties of the aligned films. (author). 24 refs., 6 figs.

1996-03-01

236

Experimental 1 kW 20 cell PEFC stack  

Energy Technology Data Exchange (ETDEWEB)

A 20-cell PEFC stack was designed and built. Resin impregnated graphite was used as bipolar plate material. The air cooling of the stack was optimized by introducing high surface structures into the open space of the cooling plates. At {eta} (H{sub 2} LHV) = 0.5 a power of 880 W was obtained under conditions of low gas-pressures of 1.15 bar{sub a}. The auxiliary power for process air supply and cooling at 880 W power is less than 7% of the power output, indicating that the described system may be operated at a high efficiency. (author) 5 figs., 2 refs.

1999-08-01

237

Alpha-particle emission from carbon bombarded with neutrons below 30 MeV  

Energy Technology Data Exchange (ETDEWEB)

Alpha-particle emission induced by neutron bombardment of carbon has been studied from threshold to over 30 MeV using the spallation neutron source at WNR/LAMPF. Targets include thin foils of CH{sub 2} and thicker foils of CH and polycrystalline graphite. Comparisons are made with evaluated data. Values for KERMA (kinetic energy released in materials) based on the results will be presented and compared with those obtained through other experimental approaches.

1994-07-01

238

Adsorption properties of. cap alpha. -modification of boron nitride  

Science.gov (United States)

The adsorption properties of four samples of ..cap alpha..-BN were studied by means of gas chromatography. The particles of ..cap alpha..-BN particles, according to data obtained by electron microscopy, have the shape of thin platelets. A sample of ..cap alpha..-BN prepared from magnesium polyboride was found to be the most nearly homogeneous adsorbent. For a number of n-alkanes, benzene, and alkylbenzenes, data have been obtained on the retention volumes (Henry constants) and the differential heats of adsorption for surface coverages approaching zero. These thermodynamic data on the adsorption showed that ..cap alpha..-BN, like graphitized thermal carbon black, is a nonspecific adsorbent.

1986-11-01

239

Adsorption properties of #alpha#-modification of boron nitride  

International Nuclear Information System (INIS)

The adsorption properties of four samples of the #alpha#-modification of boron nitride (#alpha#-BN) were investigated by the gas-chromatographic method. According to the electron microscopy data, the #alpha#-BN particles possess the shape of thin plates. An #alpha#-BN sample prepared from magnesium polyboride, is the most uniform adsorbent. For a series of n-alkanes, benzene, and alkyl benzenes, by testing the #alpha#-BN samples one has obtained the retained volumes (Henry constants) and the values of the differential adsorption heat, which are close to those of the surface zero filling. These thermodynamic characteristics of adsorption have shown that the #alpha#-BN, line the graphitized thermal carbon black, is not a specific adsorbent.

240

A real time neutron diffraction study on the intercalation of deuterobenzene into RbC_2_4  

International Nuclear Information System (INIS)

The reaction of RbC_2_4 with C_6D_6 vapour was studied by neutron diffraction on a time scale of 5 min/spectrum. As for the reaction of KC_2_4, a second stage phase RbC_2_4(C_6D_6)sub(y) is initially formed and subsequently transformed into a first stage phase. Model calculations indicate that the benzene rings are canted against the graphite planes both in the first and in the second stage phase. (Auth.).

1983-01-01

241

Pre-oxidized and nitrided stainless steel alloy foil for proton exchange membrane fuel cell bipolar plates. Part 2: Single-cell fuel cell evaluation of stamped plates  

Energy Technology Data Exchange (ETDEWEB)

Thermal (gas) nitridation of stainless steel alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant nitride containing surface layers (Cr{sub 2}N, CrN, TiN, V{sub 2}N, VN, etc.) of interest for fuel cells, batteries, and sensors. This paper presents results of proton exchange membrane (PEM) single-cell fuel cell studies of stamped and pre-oxidized/nitrided developmental Fe-20Cr-4V weight percent (wt.%) and commercial type 2205 stainless steel alloy foils. The single-cell fuel cell behavior of the stamped and pre-oxidized/nitrided material was compared to as-stamped (no surface treatment) 904L, 2205, and Fe-20Cr-4V stainless steel alloy foils and machined graphite of similar flow field design. The best fuel cell behavior among the alloys was exhibited by the pre-oxidized/nitrided Fe-20Cr-4V, which exhibited {proportional_to}5-20% better peak power output than untreated Fe-20Cr-4V, 2205, and 904L metal stampings. ...

2010-09-01

242

Pre-Oxidized and Nitrided Stainless Steel Foil for Proton Exchange Membrane Fuel Cell Bipolar Plates: Part 2- Single-Cell Fuel Cell Evaluation of Stamped Plates  

Energy Technology Data Exchange (ETDEWEB)

Thermal (gas) nitridation of stainless steel alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant nitride containing surface layers (Cr{sub 2}N, CrN, TiN, V{sub 2}N, VN, etc.) of interest for fuel cells, batteries, and sensors. This paper presents results of proton exchange membrane (PEM) single-cell fuel cell studies of stamped and pre-oxidized/nitrided developmental Fe-20Cr-4V weight percent (wt.%) and commercial type 2205 stainless steel alloy foils. The single-cell fuel cell behavior of the stamped and pre-oxidized/nitrided material was compared to as-stamped (no surface treatment) 904L, 2205, and Fe-20Cr-4V stainless steel alloy foils and machined graphite of similar flow field design. The best fuel cell behavior among the alloys was exhibited by the pre-oxidized/nitrided Fe-20Cr-4V, which exhibited {approx}5-20% better peak power output than untreated Fe-20Cr-4V, 2205, and 904L metal stampings. Durability ...

2010-09-01

243

Modeling of adsorption on nongraphitized carbon surface: GCMC simulation studies and comparison with experimental data.  

Science.gov (United States)

We model nongraphitized carbon black surfaces and investigate adsorption of argon on these surfaces by using the grand canonical Monte Carlo simulation. In this model, the nongraphitized surface is modeled as a stack of graphene layers with some carbon atoms of the top graphene layer being randomly removed. The percentage of the surface carbon atoms being removed and the effective size of the defect (created by the removal) are the key parameters to characterize the nongraphitized surface. The patterns of adsorption isotherm and isosteric heat are particularly studied, as a function of these surface parameters as well as pressure and temperature. It is shown that the adsorption isotherm shows a steplike behavior on a perfect graphite surface and becomes smoother on nongraphitized surfaces. Regarding the isosteric heat versus loading, we observe for the case of graphitized thermal carbon black the increase of heat in the submonolayer coverage ...

2006-09-01

244

Effects of surface mediation on the adsorption isotherm and heat of adsorption of argon on graphitized thermal carbon black.  

Science.gov (United States)

In this paper, the effects of surface mediation on the adsorption isotherm and isosteric heat of adsorption on a graphite surface were investigated, as the surface mediation is known to affect the intermolecular interaction of adsorbed molecules close to the surface. Kim and Steele (Phys. Rev. B 45 (11) (1992) 6226-6233) and others have assumed that the surface mediation is confined only to the first layer. This will be tested in this paper with a combined experimental and Grand Canonical Monte Carlo (GCMC) simulation of adsorption of argon on graphitized thermal carbon black (GTCB) over a range of temperatures (77-95.25K). By matching the simulation results against the experimental data, we have found that the surface mediation is extended up to the fourth layer, rather than only the first as suggested by Kim and Steele, and the extent of this mediation is reduced with distance from the surface. This reinforces the important role of surface on ...

2009-11-14

245

Computational fluid dynamic analysis of core bypass flow phenomena in a prismatic VHTR  

International Nuclear Information System (INIS)

The core bypass flow in a prismatic very high temperature reactor (VHTR) is an important design consideration and can have considerable impact on the condition of reactor core internals including fuels. The interstitial gaps are an inherent presence in the reactor core because of tolerances in manufacturing the blocks and the inexact nature of their installation. Furthermore, the geometry of the graphite blocks changes over the lifetime of the reactor because of thermal expansion and irradiation damage. The occurrence of hot spots in the core and lower plenum and hot streaking in the lower plenum (regions of very hot gas flow) are affected by bypass flow. In the present study, three-dimensional computational fluid dynamic (CFD) calculations of a typical prismatic VHTR are conducted to better understand bypass flow phenomena and establish an evaluation method for the reactor core using the commercial CFD code FLUENT. Parametric calculations changing several factors ...

2010-09-01

246

Adsorption of carbon tetrachloride on graphitized thermal carbon black and in slit graphitic pores: five-site versus one-site potential models.  

Science.gov (United States)

The performance of intermolecular potential models on the adsorption of carbon tetrachloride on graphitized thermal carbon black at various temperatures is investigated. This is made possible with the extensive experimental data of Machin and Ross(1), Avgul et al.,(2) and Pierce(3) that cover a wide range of temperatures. The description of all experimental data is only possible with the allowance for the surface mediation. If this were ignored, the grand canonical Monte Carlo (GCMC) simulation results would predict a two-dimensional (2D) transition even at high temperatures, while experimental data shows gradual change in adsorption density with pressure. In general, we find that the intermolecular interaction has to be reduced by 4% whenever particles are within the first layer close to the surface. We also find that this degree of surface mediation is independent of temperature. To understand the packing of carbon tetrachloride in slit pores, we compared the ...

2006-05-18

247

Contamination by depleted uranium (Du) in South Serbia  

Energy Technology Data Exchange (ETDEWEB)

The paper present the results of the study on D.U. (depleted uranium) contamination in the environment and possible effects on animal healths in the region o f Bujanovac. Samples of soil, feed, leaves, grass, lichen, moss, honey and water were collected randomly in 2003/2004 in the vicinity of the target area (500-1000 m) and 5 km from the target area. Activity of the radionuclides ({sup 226}Ra, {sup 232}Th, {sup 40}K, {sup 210}Pb, {sup 238}U, {sup 235}U, {sup 137}Cs, {sup 7}Be) in soils, grass, lichen, moss and honey was determined on Hp Ge detector (Canberra, relative efficiency 23%) by standard gamma spectrometry. Total alpha and beta activity in water was determined on proportional alpha/beta counter (Canberra 2400, efficiency for alpha emitters 11%, efficiency for beta emitters 30%). Non significantly higher values of concentrations of {sup 226}Ra, {sup 232}Th, {sup 238}U and {sup 235}U were measured in the immediate vicinity of the targeted site, but {sup 235}U/{sup 238}U ...

2006-07-01

248

Water and oxygen transfer in a waste rock pile constructed by mixing layers; Transfert de l'eau et de l'oxygene dans une halde de steriles construite par entremelement par couches  

Energy Technology Data Exchange (ETDEWEB)

Acid mine drainage represents one of the most important environmental problem facing the mining industry. If the tailings contain sulphur, acid mine drainage will be generated as soon as the tailings are exposed to oxygen. In this paper, the authors discussed a technique for the storage of acid mine drainage generating tailings that delays and even eliminates the occurrence. It was suggested that tailings should be piled by incorporating, at regular intervals, compacted waste rock. Thermal convection and diffusion will prevent oxygen from reaching the tailings, and limit water circulation. The modelling of transfer processes (heat, water, oxygen) in a well known tailings dump, the Doyon Mine, was performed, and the results compared to the modelling where compacted waste rock had been incorporated at regular intervals. The results indicated that by remaining saturated, the layers acted as capillary barriers preventing oxygen from reaching the tailings, therefore reducing significantly ...

2000-07-01

249

Thermodynamic modeling of LPG combustion in dual-fuel engines; Modelisation thermodynamique de la combustion du GPL dans les moteurs dual-fuel  

Energy Technology Data Exchange (ETDEWEB)

Dual-fuel engines are modified diesel engines burning simultaneously two fuels inside the cylinder: a gaseous one, called the primary fuel and a liquid one, called the pilot fuel. The thermal efficiency of the dual-fuel engine and of the diesel engine are comparable; the level of emissions is lower compared to the diesel one. This article presents a new procedure for the combustion modeling in a LPG-diesel dual-fuel engine. The procedures deals with the ignition delay period and with the rate of heat release inside the cylinder. This procedure is validated using experimental data issued front a collaboration with the Indian Institute of Technology from Madras, India. The used engine is a single-cylinder one, air-cooled. The pilot fuel is direct injected inside the cylinder The engine was run at constant load and with different diesel substitutions, i.e. for different air to fuel ratios of the primary fuel-air mixture. The general error of the procedure is below 10%. (authors)

2002-07-01

250

Study of the effects of interactions quantum interference and disorder in GaAs and of GaAs jointed to a superconductor; Etude des effets d`interference quantique et de desordre dans GaAs avec interactions et GaAs connecte a un supraconducteur  

Energy Technology Data Exchange (ETDEWEB)

The aim of this thesis is to study the coherent transport in semiconducting-superconducting junctions. The SnPb-GaAs system has been studied. It has been shown that the behaviour of this junction is controlled by the disordered area induced by the annealing of the connection near the interface. For a few resistant junction, a conductance anomaly under the gap has been observed and has been explained by a mesoscopic effect in the limit of the very high disorders. The conductance of more resistant junctions has only been bound to the properties of the very disordered area of the semiconductor. The part of the electron-electron interactions on the phase coherence length and on the conductance has been studied. The evolving of the correction of the conductance due to interactions in magnetic field has been followed. The effect of the spin degeneration suppression in CdTe and the GaAs sign inversion in Shubnikov de Haas oscillations rate has been observed. At last has been studied the ...

1997-11-07

251

Reduction of nitrogen oxides (NO{sub x}) production in a liquid fuel-oil diffusion flame by acoustic excitation; Reduction de la production des oxydes d`azote (NO{sub x}) dans une flamme de diffusion a fioul liquide par excitation acoustique  

Energy Technology Data Exchange (ETDEWEB)

The control of nitrogen oxides (NO{sub x}) emissions will become a major challenge in the forthcoming years, in the domain of automotive industry or industrial burners. Pulsed combustion offers an imaginative solution which does not affect the combustion efficiency. In this paper, the efficiency of this method is demonstrated using the burner of a 20 kW domestic boiler. The actuator is simply installed on the air intake. Two types of actuators have been tested successfully: a loudspeaker and a rotative valve. Both can produce 100 to 1000 Hz frequencies and can lead to a reduction of 20% of NO{sub x} emissions. The feasibility of the concept is also demonstrated on a 840 kW liquid fuel-oil burner. The mechanisms involved during an excitation are explained using the CH{sup *} radical imaging. Results show an important reorganization of the flow and of the flame structure. During each excitation cycle, an annular swirl occurs at the leading edge of the flame catching and develops during ...

1996-12-31

252

Proposal of a numerical modeling of reactive flows in combustion chambers of turbojet engines; Proposition d`une modelisation numerique des ecoulements reactifs dans les foyers de turboreacteurs  

Energy Technology Data Exchange (ETDEWEB)

Simplifying hypotheses are required when combustion and aerodynamic phenomena are considered simultaneously. In this paper, a turbulent combustion model is proposed, in which the combustion chemistry is reduced to a single reaction. In this way, only two variables are needed to describe the problem and combustion can be characterized by the consumption of one of the two reactive species. In a first step, the instantaneous consumption rate is obtained using the Lagrangian form of the mass fraction equation of the species under consideration, and by considering the equilibrium state only. This state is determined in order to preserve the consistency with results that should be obtained using a complete kinetics scheme. In a second step, the average rate is determined using the instantaneous consumption term and a probabilistic density function. This model was tested on various configurations and in particular on an experimental main chamber and on a reheating chamber. Results indicate ...

1996-12-31

253

Properties of the passive films on cold worked stainless steels in conditions of susceptibility to stress corrosion cracking; Proprietes des couches passives formees sur les aciers inoxydables ecrouis dans des conditions de susceptibilite a la corrosion sous contrainte  

Energy Technology Data Exchange (ETDEWEB)

Passive films, formed on annealed and cold worked AISI 304 stainless steel in hot chloride media, were examined using polarization resistance and impedance measurements. The obtained results show the influence of cold work on film conductivity, which can be correlated to conditions of susceptibility to stress corrosion cracking. Capacitance measurements, using the Mott-Schottky approach, revealed that a change from n to p type semi-conductivity is associated to susceptible conditions with an increase in the doping density estimated for cold worked samples in the presence of chloride. It is assumed that p-type semi-conductivity of the passive film together with the position of the flat band potential has a strong influence on the dissolution processes at the corrosion potential. Based on this analysis the influence of plastic deformation, at the dislocation scale, is discussed. (authors)

2004-06-01

254

Preliminary study of the {sup 129}I distribution in environment of La Hague reprocessing plant with the help of a terrestrial moss: Homalotecium sericeum. Study report; Etude preliminaire de la repartition de {sup 129}I dans l'environnement de l'usine de retraitement de La Hague a l'aide d'une mousse terrestre: Homalotecium sericeum. Rapport d'etude  

Energy Technology Data Exchange (ETDEWEB)

The preliminary study of the {sup 129}I distribution has allowed to underline the limits of use of a Homalotecium sericeum type terrestrial moss as biological indicator. However, this preliminary study allowed all the same to give a spatial distribution of this radioelement around La Hague reprocessing plant (source term) that underlines the existence of four geographic areas in function of collected activities. The levels are generally under 99 Bq/kg dry. It is recommended to improve the knowledge that we can have of transfers and quantity of iodine 129 from the marine environment to the terrestrial environment, but also, the one that we can have of factors able to modify the spatial distribution of this radionuclide. (N.C.)

1999-07-01

255

Predictions of nitrogen oxides production in diffusion turbulent flames; Predictions de la production des oxydes d`azote dans les flammes turbulentes de diffusion  

Energy Technology Data Exchange (ETDEWEB)

The suitability of the turbulent combustion flamelets model in order to predict the index of NO{sub x} production in turbulent flames of hydrogen diffusion is analyzed. In the flamelet approach, the turbulent flame is equivalent to a group of laminar flames submitted to a mechanical stretching which generates a chemical disequilibrium. This effect can be described by the stretching or by the scalar dissipation ratio. A numerical modeling is performed in order to evaluate the advantages of both approaches and to compare the behaviour of the NO{sub x} emission index with the experiments of Chen and Driscoll. This study shows that predictions of NO{sub x} emission indexes have a correct behaviour with respect to the Damkoehler number only when the scalar dissipation ratio is used as a parameter to describe the chemical state outside equilibrium. Predictions of the flamelet models are improving when the Damkoehler number increases. On the other hand, the absolute NO{sub x} concentrations ...

1996-12-31

256

New process for loading highly active platinum on carbon black surface for application in polymer electrolyte fuel cell; Nouvelle methode pour deposer du platine actif a la surface du carbone pour utilisation dans les piles a combustible  

Energy Technology Data Exchange (ETDEWEB)

The deposition of platinum on various carbon blacks was carried out by forming active functional groups on the surface of the carbon support, and exchanging these active groups with different platinum complexes. Using H{sub 2}PtCl{sub 6} solution, an impregnation rather than an exchange takes place. However, using divalent platinum complexes [Pt(NH{sub 3}){sub 4}]{sup 2+}, a fast exchange takes place which leads to extremely small platinum particles highly dispersed on the surface of carbon black. A comparison of the catalytic activities of platinum supported on various carbon blacks was also carried out. The performances of PEFC (Polymer Electrolyte Fuel Cell) based on the process of the ion exchange are reported. (authors) 3 refs.

1998-01-01

257

Natural attenuation in soils: an alternative to usual remedial methods: A case study of its application for diesel contamination; L`attenuation naturelle dans les sols: une alternative aux methodes usuelles de restauration: etude de cas applicable a une contamination en diesel  

Energy Technology Data Exchange (ETDEWEB)

Various pollution abatement measures available to combat oil spills were reviewed with emphasis on biodegradation. Microorganisms naturally found in soils and groundwater can efficiently degrade a variety of organic contaminants. For certain sites, local temperature allows the microorganisms to reduce the contaminant concentrations without human intervention. In April 1994, a diesel fuel leak was found at a telecommunication station located in a park. The leak had already contaminated the surrounding soil. The first step of the clean-up procedure was to excavate the contaminated soil, followed by an evaluation to determine the extent of the remaining contamination. It was concluded that by using natural attenuation the deforestation of the remaining affected area could be prevented. In this instance, the natural attenuation process is expected to take five years for completion. 4 refs., 1 tab., 1 fig.

1998-04-01

258

Lithium intercalation in the LiLaNb{sub 2}O{sub 7} perovskite structure; Intercalation du lithium dans la structure perovskite LiLaNb{sub 2}O{sub 7}  

Energy Technology Data Exchange (ETDEWEB)

ABO{sub 3} perovskite-type oxides having vacancies in the A-sites of their structure are interesting candidates for solid electrolytes when their A-sites are occupied by Li{sup +} ions having a high mobility. This is the case with the [Li{sub 3x}La{sub 2/3-x}]TiO{sub 3} solid solution compound which has a 10{sup -3} S cm{sup -1} ionic conductivity at ambient temperature. Electrochemical intercalation in this material is possible thanks to the presence of Ti{sup 4+} but the small amount of vacancies (0.33 maximum) leads to a low intercalation rate. In order to solve this problem, the LiLaNb{sub 2}O{sub 7} material which has a greater amount of vacancies has been studied and the results relative to the electrochemical intercalation of lithium in this perovskite are presented. The thermodynamical and kinetics properties of the lithium intercalation reaction have been studied by intermittent galvano-static discharges and impedance spectroscopy in LiClO{sub 4}-propylene carbonate medium. ...

1996-12-31

259

LiPF{sub 6}. Synthesis and stability in EC/DMC and PC/DMC mixtures; LiPF{sub 6}. Synthese et stabilite dans les melanges EC/DMC et PC/DMC  

Energy Technology Data Exchange (ETDEWEB)

Lithium hexa-fluoro-phosphate LiPF{sub 6} is recommended for the replacement of the toxic LiAsF{sub 6} and the explosive perchlorates (like LiClO{sub 4}) in rechargeable lithium electrochemical generators. The aim of this work is to develop a new method of synthesis of this salt and to check its stability with respect to carbonated solvents: ethylene carbonate (EC), propylene carbonate (PC) and dimethyl-carbonate (DMC) in already optimized EC/DMC and PC/DMC binary mixtures. Two methods using HPF{sub 6} are proposed: the first one uses the direct neutralization of this commercial acid by LiOH in aqueous, alcoholic or acetonitrile environment, while in the second one LiPF{sub 6} is obtained from pyridinium hexa-fluoro-phosphate synthesized from HPF{sub 6} using a new and simple protocol. (J.S.) 24 refs.

1996-12-31

260

Iridium and PGE in sedimentary rocks; Iridium et platinoides dans les roches sedimentaires  

Energy Technology Data Exchange (ETDEWEB)

The detection limit of Instrumental Neutron Activation Analysis (INAA), about a few microgram per kg, is not sufficient to determine iridium concentrations in most geological samples. Use of the coincidence counting of the 316 and 468 keV gamma-rays emitted during the decay of {sup 192}Ir, improved the sensitivity (0.01 microgram per kg). The high iridium content of the clay layers from the Cretaceous-Tertiary transition (KTB) has been considered as an evidence of the extra-terrestrial origin of the KTB mass extinction. However some results indicate that a significant part of the iridium content in sediments has a volcanic origin. Radiochemical Neutron Activation Analysis (RNAA) in some KTB samples and in basic and ultra-basic rocks show that, unlike in volcanic products, no PGE (platinoids) fractionation appears in KTB samples. The nearby chondritic PGE pattern supports an extra-terrestrial origin for the KTB iridium anomaly. 2 figs., 2 tabs., 37 refs.

1994-12-31

261

Individual monitoring of internal exposure to uranium oxides in two fuel fabrication plants. La surveillance individuelle de l'exposition interne aux oxydes d'uranium dans deux usines de fabrication du combustible  

Energy Technology Data Exchange (ETDEWEB)

Individual monitoring of personal exposure to inhalation of uranium oxides throughout the manufacture of fuel for pressurized water reactor (PWR) includes lung gamma-spectrometry, fecal analysis and urine analysis. Examination of the results shows the following: internal exposure is the consequence of repeated intake incidents as revealed by early peaks of urinary and particularly fecal elimination; a shift is often observed with the results of aerosol concentration measured through air collectors; the measured variations of uranium lung incorporations are relatively fast (apparent mean period 165 d). Correct evaluation of the effective dose equivalent from inhalation requires further information concerning the aerosol size distribution at work stations, the physico-chemical characteristics of the product leading to an estimate of its actual biological solubility, and the measurement of the fraction of aerosol liable to intake with an individual portable collector.

1989-01-01

262

In-situ IR reflexion spectroscopy characterization of the passivation layer developed on the surface of lithium electrodes in organic medium; Passivation de surface: une nouvelle voie pour reduire l`autodecharge dans les batteries rechargeables a ions lithium LiMn{sub 2}O{sub 4}/Li  

Energy Technology Data Exchange (ETDEWEB)

the development of lithium metal batteries is hindered by the bad reversibility of the Li{sup +}/Li pair, due to dendrites formation which limits the amount of active matter and can generate short-circuits. The chemical and electrochemical phenomena which take place at the electrode/organic electrolyte interface lead to the formation of a complex passivation film which is of prime importance for the functioning of this type of batteries. The in-situ infrared reflection spectroscopy is well adapted to the chemical study of the passivation layer. Two different techniques were used: the substraction normalized interfacial transform infrared spectroscopy (SNIFTIRS) and the electro-chemically modulated infrared reflectance spectroscopy. These methods have shown that the passivation layer that develops on the surface of the lithium electrode in contact with organic solutions (propylene carbonate, ethylene carbonate and dimethoxyethane) is mainly made of lithium alkyl carbonates (ROCO{sub ...

1996-12-31

263

Expert system for the real-time management of alarms in an electric grid. Un systeme expert pour la gestion en temps reel des alarmes dans un reseau electrique  

Energy Technology Data Exchange (ETDEWEB)

A model-base expert system is presented for the processing of alarm messages in power networks' control centers. This alarm processor, called GESTAL, generates concise diagnoses identifying the causes(s) of network disturbances and describing the operation of the protection and alarm systems which operate to isolate faulty components. Essentially, the alarm processor is an agenda driven expert system which is composed of a model of the power network's alarm and protection systems as well as several sets of rules. Based on the nextwork model, graph structures are constructed which represent relationships between alarms as they are received. These graph structures are then analysed in order to diagnose the disturbances(s). The alarm processor has been developed using the ART 3.0 programming language in a Symbolics Lisp-machine environment. Background material on expert systems, electric power networks, and alarm processing software is included, as well as a description ...

1987-01-01

264

Environmental monitoring carried out by an association: the citizen watchdog of radioactivity in the environment; La surveillance de l'environnement exercee par une association: l'observatoire citoyen de la radioactivite dans l'environnement  

Energy Technology Data Exchange (ETDEWEB)

ACRO, a NGO equipped with a laboratory to measure radioactivity, runs the Citizen Watchdog of Radioactivity in the Environment. Involving many volunteers, it monitors regularly the French coast of the Channel and many rivers of the North half of France. It also makes investigations in other places. Such an action is aimed to supplement the official monitoring, not to replace it, in order to answer to the worries of the population. This monitoring shows that some radioelements, such as iodine 129, cobalt 60, tritium, etc. released in the environment by nuclear facilities can be detected on very large areas. Carbon 14 was detected up to almost 4 times the background in vegetables around the reprocessing plant of La Hague. ACRO also sits in many official committees to transmit the point of view of the populations exposed to the radioactive pollution. It is lobbying for a decrease of the release authorization, especially for the elements that are discharged in large quantity in the ...

2010-06-15

265

Effects of freeze-thaw cycles on the performance of soft materials used in soil covers with capillary barrier; Effets des cycles de gel-degel sur la performance des materiaux meubles utilises dans les couvertures a effets de barriere capillaire  

Energy Technology Data Exchange (ETDEWEB)

Freezing and thaw have an effect on soils, and the effect of the freeze-thaw cycle on soil covers used in the control of acid mine drainage was discussed in this poster presentation. The purpose of soil covers in cases involving acid mine drainage (AMD) is to reduce the exposure of tailings to oxygen which cause AMD. The effect of this freezing-thaw cycle on soft materials used in soil covers with capillary effect was studied. Some laboratory experiments were conducted to evaluate the properties of the moisture retention layer. The preliminary results were presented. The results indicated that the freeze-thaw cycle might affect the performance of soil covers in the long term, depending on the type of materials selected. Further research is undergoing. 26 figs.

2000-07-01

266

Analysis of radioactivity levels in the surrounding of the Aube storage plant (F.M.A.-V.C.). year 2007. Presentation, results and methods; Analyse des niveaux de la radioactivite dans les environs du centre de stockage F.M.A.-V.C. de l'Aube. Annee 2007. Presentation, resultats et methodes  

Energy Technology Data Exchange (ETDEWEB)

The study had three objectives: to collect information that explain the impact of the Aube storage center (C.S.A.) on environment and allow to evaluate the consequences for man, secondly, to build a referential for any future inquiry or follow-up, thirdly, to allow to the local commission of information to elaborate an information towards the side residents and local actors that take into account their questions. Trees, waters, sediments, soils, grass, products of gardens and vineyards were the object of sampling, their dosimetry is given in this report. Other dosimetry measures were made along the nuclear site and the results are equally in this report. (N.C.)

2007-07-01

267

A healthy climate for the Printer house. Indoor climate improved by means of adjucting the air conditioning installation; Een gezond klimaat voor het Printerhuis. Binnenklimaat verbetert dankzij aanpassing LBK  

Energy Technology Data Exchange (ETDEWEB)

In the first part of the nineties many office buildings were equipped with indoor climate installations which do not meet present standards. Several options are available to improve such installations for ventilation capacity, cooling capacity, thermal comfort and air quality. One of the options concern the installation of an air conditioner in combination with heat recovery. In this article attention is paid to the renovation of the air conditioning system in the Printer house, an office building in Zwolle, Netherlands. [Dutch] Begin jaren negentig zijn veel kantoorpanden gebouwd waarvan de klimaatinstallatie tegenwoordig niet meer voldoet. De ventilatiecapaciteit is ontoereikend en koeling is mondjesmaat aanwezig, of slechts als topkoeling. Het comfort en de luchtkwaliteit zijn dan ook onder de maat. Er zijn verschillende mogelijkheden om dit te verbeteren. Plaatsing van een nieuwe luchtbehandelingskast met warmteterugwinning is daar een van. In dit artikel wordt ...

2007-05-15

268

X-ray imaging dose due to the digital imaging devices used in radiation therapy for patient positioning and repositioning: How to take it into account?; Les doses dues a l'imagerie numerique pour le controle de positionnement du patient en radiotherapie: comment les prendre en compte?  

Energy Technology Data Exchange (ETDEWEB)

The patient positioning and repositioning control in radiation therapy all along the treatment can be conducted using a variety of X-ray sources and imaging detector devices. The development of image guided radiation therapy techniques leads to more frequent use of this imaging control. In this article we summarize the current methods for measuring the dose delivered by X-ray imaging devices used in radiation therapy, as well as basic proposals to take account of these imaging doses for prescribing, recording and reporting radiation therapy treatment. (authors)

2008-12-15

269

Verification of knowledge bases based on containment checking  

Energy Technology Data Exchange (ETDEWEB)

Building complex knowledge based applications requires encoding large amounts of domain knowledge. After acquiring knowledge from domain experts, much of the effort in building a knowledge base goes into verifying that the knowledge is encoded correctly. We consider the problem of verifying hybrid knowledge bases that contain both Horn rules and a terminology in a description logic. Our approach to the verification problem is based on showing a close relationship to the problem of query containment. Our first contribution, based on this relationship, is presenting a thorough analysis of the decidability and complexity of the verification problem, for knowledge bases containing recursive rules and the interpreted predicates =, {le}, < and {ne}. Second, we show that important new classes of constraints on correct inputs and outputs can be expressed in a hybrid setting, in which a description logic class hierarchy is also considered, and we present the first ...

1996-12-31

270

Topological Analysis of Large-scale Biomedical Terminology Structures  

British Library Electronic Table of Contents (United Kingdom)

ObjectiveTo characterize global structural features of large-scale biomedical terminologies using currently emerging statistical approaches.DesignGiven rapid growth of terminologies, this research was designed to address scalability. We selected 16 terminologies covering a variety of domains from the UMLS Metathesaurus, a collection of terminological systems. Each was modeled as a network in which nodes were atomic concepts and links were relationships asserted by the source vocabulary. For comparison against each terminology we created three random networks of equivalent size and density.MeasurementsAverage node degree, node degree distribution, clustering coefficient, average path length.ResultsEight of 16 terminologies exhibited the small-world characteristics of a short average path le...

2007-01-01

271

Three-Dimensional Mixed Convection Heat and Mass Transfer in a Rectangular Duct: Case of Longitudinal Rolls  

British Library Electronic Table of Contents (United Kingdom)

This article presents numerical study of 3-D thermosolutale mixed convection (TSMC) in horizontal rectangular channels. The contribution of this work is to characterize the travelling wave's appearance and to generalize the behavior of Poiseuille-Rayleigh-Benard (PRB) systems for a broad range of dimensionless parameters, which control the double diffusive mixed convection. The numerical results consist of analyzing the flow regimes of the steady longitudinal thermoconvectives rolls for the case of purely thermal mixed convection (TMC) and for both thermal and mass transfer (TSMC). The transition from opposed volume forces to cooperating ones at fixed Rayleigh (Ra), Reynolds (Re), and Lewis (Le) numbers, considerably affects the birth and the development of the longitudinal rolls (noted R/...

2011-01-01

272

The whole risks and the choice for a type of financing; L`ensemble des risques et le choix du type de financement  

Energy Technology Data Exchange (ETDEWEB)

Energy projects are extremely capitalistic and the costs involved have a significant weight on the balance sheets of companies. This paper describes the general rules of financing policies used by companies from the natural gas and petroleum industries: constraints (external and financial markets, partnership, warranties..); implication of financiers; risk analysis (political (nationalization, civil or military troubles, difficult transfer of profits outside the project..), financial (property developer, nature of the project, delay, cost overruns, performance, market..)); financial instruments (proper funds and debt, bankers and insurers, loans etc..). These rules are illustrated with several examples of recent projects of gas pipelines and exploitation of oil fields abroad. (J.S.)

1997-07-01

273

The Formation of the Low-sized High Density Plasma Structures in the Self-maintained Plasma-beam Discharge  

International Nuclear Information System (INIS)

The opportunity of use self-maintained plasma-beam discharge in an extended pulsing plasma diode of low pressure for making powerful sources of the soft X-rays is investigated. Conditions of formation of the self-maintained plasma-beam discharge are determined. The mode of making of dense high-temperature plasma on the basis of stannum ions in the discharge is shown. The stannum ions are used as a working element of a radiation sources at pulsing power of electron beam P?10...100 MW. Results of the examination on formation of the dense (np?1016 cm3), small sizes (le?100 eV in conditions of working material evaporation from the anode are given. The total contribution of energy to the discharge has made W < 20 J.

2006-01-01

274

System performance of a solar thermophotovoltaic system for space and terrestrial application  

Energy Technology Data Exchange (ETDEWEB)

Solar thermophotovoltaics (STPV) potentially have high system power efficiency together with other attractive attributes for both space and terrestrial applications. This paper presents a summary of work that has been conducted by NASA Lewis Research Center (LeRC) and McDonnell Douglas Aerospace (MDA). The paper discusses analytical modeling and subsystem testing, laboratory, and field testing that has been conducted. The features which make solar thermophotovoltaics attractive for both space and terrestrial applications are discussed. Based upon these investigations and the work of others, a conceptual design has been formulated, and an estimate of system performance is presented. This estimate indicates a solar thermophotovoltaics system can result in competitive energy costs for the utility electrical market applications and a high power-to-mass ratio for space power applications.

1995-12-31

275

Reconstructions of archaeological contexts in OpenGl environments; Intelligenza artificiale per i beni culturali e le biblioteche digitali. Atti del Workshop  

Energy Technology Data Exchange (ETDEWEB)

DVR project concerns the creation of a virtual reality OpenGL system for desktop applications in archaeology. The main goal is the creation of a 3D information system using the real time interaction of OpenGL environments. The first case study implemented is the Vettii House, one of the most important and outstanding monuments in Pompei. The virtual reconstruction of these architectural models is based on very detailed photogrammetric surveys and it is connected with information layers and archaeometric data-bases regarding the state of conservation of walls, structures and any type of materials of the monument. A full 3D interface characterizes the system, comprising a high resolution texturing with detailed volumetric and geometric data. Finally, for the future, the project plans to fit the system for scientific and end users through the installation of stations on site.

2001-07-01

276

Pore-structure models of hydraulic conductivity for permeable pavement  

British Library Electronic Table of Contents (United Kingdom)

SummaryPermeable pavement functions as a porous infrastructure interface allowing the infiltration and evaporation of rainfall-runoff while functioning as a relatively smooth load-bearing surface for vehicular transport. Hydraulic conductivity (k) of permeable pavement is an important hydraulic property and is a function of the pore structure. This study examines k for a cementitious permeable pavement (CPP) through a series of pore-structure models. Measurements utilized include hydraulic head as well as total porosity, (t), effective porosity (e), tortuosity (Le/L) and pore size distribution (PSD) indices generated through X-ray tomography (XRT). XRT results indicate that the permeable pavement pore matrix is hetero-disperse, with high tortuosity and t!=e. Power law models of k-t and k-e...

2011-01-01

277

On the selection and validation of biological treatment processes. The GDF experience; Le choix et la validation des procedes de traitement biologique. L`experience de GDF  

Energy Technology Data Exchange (ETDEWEB)

The biological treatment process was selected by Gaz de France (GDF), the French national gas utility, for the de-pollution of an old gas works where the main pollutants are coal tars containing polycyclic aromatic hydrocarbons. Microorganism-based biological treatment techniques may involve bio-reactors, static ground knolls (where oxygen is brought through drains) and dynamic knolls (where oxygenation is carried out by turning up the soil). Issues on sampling, sorting, process testing, site preparation, process control, etc. are reviewed

1996-12-31

278

New NDT developments for the control of components in the FA3 EPR nuclear reactor at Flamanville; Nouveau developpement END pour le controle de composants de la tranche EPR de Flamanville (FA3)  

Energy Technology Data Exchange (ETDEWEB)

New Non Destructive Testing techniques are currently being developed for the inspection of two groups of components in the FA3 EPR nuclear reactor at Flamanville. The first group of components to be controlled is constituted by the welds of the (89) rod cluster control assemblies' containment; two control types are to be used: an ultrasonic technique (UT) evaluation from the outside of the flange-casing weld, and an ET control from the inside of the three other welds. The second group of components is formed by the 44 welded joints of the primary circuit, which will be inspected through ultrasonic testing. Details of the components, control devices and sensors are given and some test results are presented

2009-07-01

279

Moufang loops that share associator and three quarters of their multiplication tables  

CERN Document Server

Two constructions due to Dr\\'apal produce a group by modifying exactly one quarter of the Cayley table of another group. We present these constructions in a compact way, and generalize them to Moufang loops, using loop extensions. Both constructions preserve associators, the associator subloop, and the nucleus. We conjecture that two Moufang 2-loops of finite order $n$ with equivalent associator can be connected by a series of constructions similar to ours, and offer empirical evidence that this is so for $n=16$, 24, 32; the only interesting cases with $n\\le 32$. We further investigate the way the constructions affect code loops and loops of type $M(G, 2)$. The paper closes with several conjectures and research questions concerning the distance of Moufang loops, classification of small Moufang loops, and generalizations of the two constructions.

2006-01-01

280

MEND manual; Le manuel NEDEM  

Energy Technology Data Exchange (ETDEWEB)

This poster presentation details the procedure that was followed for the development of the Mine Environment Neutral Drainage (MEND) manual. This manual was developed to provide a detailed summary of the important results obtained through studies sponsored by the MEND program and other studies conducted on topics related to acid mine drainage. The manual was divided into volumes dealing with topics such as summary, sampling and analysis, predictions, prevention and control, treatment, and monitoring. Details concerning the format, research conducted under the auspices of MEND, utilization and limitations, methodology, variations, costs, and references were also discussed. The author stated that the manual is to be used as a guide. The proposed English publication dates for the volumes were indicated, and they ranged from the fall of 2000 for volumes 3, 5, and 6, to the CD-ROM publication in March 2001. The French publication is expected to be in print by mid 2001. 26 figs.

2000-07-01

281

Liquid metal flow measurement by neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd{sub 3}) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).

1996-07-21

282

Liquid metal flow measurement by neutron radiography  

International Nuclear Information System (INIS)

Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd_3) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).

1996-07-01

283

Intervention device, especially for control, inspection and maintenance of heat exchangers. Dispositif d'intervention, notamment pour le controle, l'inspection et la maintenance des echangeurs de chaleur  

Energy Technology Data Exchange (ETDEWEB)

The steam generator inspection and maintenance device has an articulated arm formed at least by two rigid segments connected by a pivot and two plates on the ends of the arms by articulated joints which enable them to rotate about two orthogonal axis. One of the axis is parralel to the axis of the pivot between the arm sections while the other is perpendicular to the surface of the corresponding plate. Each of the plates carries coupling elements which are able to engage with the perforations of the heat exchanger tube plates and also a support for a maintenance tool.

1990-09-21

284

Innovating methodologies brought into operation by Framatome for the Phenix control; Methodologies innovatrices mises en oeuvre par Framatome pour le controle de Phenix  

Energy Technology Data Exchange (ETDEWEB)

The renovation programme of the Phenix nuclear power plant (fast neutrons reactor situated at Marcoule) has for objective to ensure the reactor operation lengthening. In this frame, expertise and monitoring operation in situ of materials have been started. The presence of sodium and a temperature at the cold breakdown of the primary circuit between 150 and 180 degrees (Celsius) imply, for fast reactors, very special conditions. In this context, Framatome has realised three intervening in the area of nondestructive testing: the inspection of the cone-shaped support ring, the monitoring of the upper part of the primary vessel and the monitoring of the intermediary exchanger equipment. (N.C.)

2000-06-01

285

Increased capability of Strassy: the decision making aid for the inspection of nuclear materials; Prolongement des capacites de Strassy: systeme d`aide a la decision pour le controle des matieres nucleaires  

Energy Technology Data Exchange (ETDEWEB)

The paper describes the latest developments in STRASSY (Strategy Assistance System), the strategy assistance system for the inspection of nuclear materials. The user can now select the fuel cycle he wishes to investigate from an initial range of 19 facilities. An inspection interface has been developed to enable the details and dates of inspections to be modified. One of the special features of the application of STRASSY in international safeguards is the taking into account of timeliness of detection; certain aspects of the time manager algorithms are presented and analysed, including the guaranteed existence of a solution. The results of a study of diversion paths in a simplified cycle consisting of our facilities are presented. Finally, the modifications necessary to enable STRASSY to be used for a posterior analysis of inspection results are discussed. (authors). 7 refs., 3 figs.

1994-12-31

286

ITER baffle module small-scale mock-ups: first wall thermo-mechanical testing results  

International Nuclear Information System (INIS)

The EU-home team is in charge of the R and D related to the ITER baffle first wall. Five small-scale mock-ups, using Be, CFC and W tiles and different armour/heat-sink material joints under development, have been fabricated and thermomechanically tested in FE200 (Le Creusot) and JUDITH (Juelich) electron beam facilities. The small-scale mock-ups have been submitted to thermo-mechanical fatigue tests (up to failure using accelerating techniques). The objective was to determine the performances of the armour material joints under high heat flux cycles. (orig.)

1998-09-01

287

For its batteries, the automobile imitates the cellular phone; Pour ses batteries, la voiture imite le telephone mobile  

Energy Technology Data Exchange (ETDEWEB)

To gain in efficiency, lightness and volume, the hybrid and electric-powered cars will certainly follow the cellular phone path. The key of success of todays hybrid cars is the Ni-MH battery developed by Matsushita (87.5% of the market in 2004). The lithium-ion batteries will be the next step and would allow to supply 80 to 100% of the energy of the vehicle, the thermal engine becoming just an auxiliary system for additional power, autonomy and air-conditioning. Prototypes can reach today 200 to 450 km of autonomy and 130 km/h speeds with batteries of about 200 kg. If most of the safety problems linked with the Li technology have been solved, the main drawback remains the cost of the Li-ion technology. Short paper. (J.S.)

2005-09-28

288

Eddy current probe development based on a magnetic sensor array; Developpement d'un imageur magnetique pour le controle non destructif par courants de Foucault  

Energy Technology Data Exchange (ETDEWEB)

This research deals with in the study of the use of innovating magnetic sensors in eddy current non destructive inspection. The author reports an analysis survey of magnetic sensor performances. This survey enables the selection of magnetic sensor technologies used in non destructive inspection. He presents the state-of-the-art of eddy current probes exploiting the qualities of innovating magnetic sensors, and describes the methods enabling the use of these magnetic sensors in non destructive testing. Two main applications of innovating magnetic sensors are identified: the detection of very small defects by means of magneto-resistive sensors, and the detection of deep defects by means of giant magneto-impedances. Based on the use of modelling, optimization, signal processing tools, probes are manufactured for these both applications.

2007-06-15

289

Development of a petrographic technique for the quality control of concrete mixes used in mines. Final report; Mise au point d`une technique petrographique pour le controle de qualite des betons miniers. Rapport final  

Energy Technology Data Exchange (ETDEWEB)

Petrographical analysis is a microscopical analytical tool which allows definition of the exact nature of the components of different concrete mixes, as well as definition of internal structures and alteration processes. In order to improve the precision and the swiftness of the petrographical analysis, an automated image analysis system has been developed. In the next stage of this study, which consisted in the testing of new concrete mixes containing fluidised bed ashes, petrography has been used, not only to identify the nature of the mix components, but also assess the behaviour of these new concrete mixes when exposed to aggressive conditions.

1997-11-01

290

Determination of poisoning schemes for the innovating fuels reactivity. Application to plutonium CERCER and CERMET control; Determination de schemas d'empoisonnement pour le controle de la reactivite de combustibles innovants. Application au Cercer et Cermet au plutonium  

Energy Technology Data Exchange (ETDEWEB)

In the framework of the plutonium production optimization in the PWR, many solutions are studied to decrease or recycle the plutonium of the nuclear fuels. Among these solutions, the inert matrix fuels (IMF) are proposed in this thesis. In seven chapters the author presents, the context and the state of the art, the different matrix, the calculi codes such as APOLLO2 or TRIPOLI4 needed to the neutronic analysis, the different fuel assemblies (CERMET UO{sub 2}, MOX, PuO{sub 2} and PuO{sub 2}-UO{sub 2}), the efficiency of the control rods in the case of the PWR, the cross sections problem, preliminary reflexions on critical accidents. (A.L.B.)

2000-03-01

291

Design of the decision aiding system for the control of the research nuclear reactor; Conception d'un systeme d'aide a la decision pour le controle d'un reacteur nucleaire de recherche  

Energy Technology Data Exchange (ETDEWEB)

Intelligent and decision aiding systems as support to operators are becoming increasingly a necessity in nuclear installations and in nuclear reactors in particular, specially after the Tree Mile Island. Development of new technologies based on linguistic approaches such as fuzzy logic has given rise to much interest during the last years. Fuzzy logic controller (FLC) has many advantage compared to conventional controllers using classical techniques. The aim of the present work is to use a fuzzy logic controller in parallel to actual semi-automatic controller in order to supervise in real time the operation of the research nuclear reactor. The principal of this controller is based on rules which are established previous from experiment using the semi-automatic controller and from the knowledge of the operators. (authors)

2003-07-01

292

Design of a GaAs/Ge solar array for unmanned aerial vehicles  

Energy Technology Data Exchange (ETDEWEB)

Unmanned Aerial Vehicles (UAV) are being proposed for many applications including surveillance, mapping and atmospheric studies. These applications require a lightweight, low speed, medium to long duration airplane. Due to the weight, speed, and altitude constraints imposed on such aircraft, solar array generated electric power is a viable alternative to air-breathing engines. Development of such aircraft is currently being funded under the Environmental Research Aircraft and Sensor Technology (ERAST) program. NASA Lewis Research Center (LeRC) is currently building a Solar Electric Airplane to demonstrate UAV technology. This aircraft utilizes high efficiency Applied Solar Energy Corporation (ASEC) GaAs/Ge space solar cells. The cells have been provided by the Air Force through the ManTech Office. Expected completion of the plane is early 1995, with the airplane currently undergoing flight testing using battery power.

1995-03-01

293

Decision making information systems and data base management; Applicazioni dei sistemi di supporto alle decisioni manageriali in un ente fortemente decentrato. Sviluppo di un prototipo per la valutazione di nuovi progetti  

Energy Technology Data Exchange (ETDEWEB)

In these years Information Technology has been used in activities that require an intelligent intervention. In this context take placing Decision Support Systems, since they use Information Technology to support users in decision processes, that is problems of logical level greater then problems normally treated by traditional information systems. The purpose of this work is to describe Decision Support Systems specifying what they are, their functionally and structure, identifying, furthermore, user types referred to and interaction modality between them; and to present a prototype of these systems. From a preliminary analyses phase of ENEA being and its Information Systems to understand which topics can be supported by systems of this type, it deals with one of these topics: weighing of new project, finding parameters, or key quantity, that affect and determine decisions. It describes, then, models, conceived form parameters, that permit to the user, through a simple representation ...

1997-01-01

294

Current status and future prospects of rocket propellants  

Energy Technology Data Exchange (ETDEWEB)

This paper presents the current status and future prospects of rocket propellants and the development of rocket engines. The combinated rocket propellant of liquid oxygen (LO/sub 2/) and liquid hydrogen (LH/sub 2/) is so much effective that it is typically used for the main engine of the space shuttle of the U.S. LE-7 engine with the thrust output of 100 tons is being developed for H-2 launcher following H-1 launcher in Japan. Meanwhile, HM-60 engine is being developed for ARIANE-5 launcher in Europe. Although the LO/sub 2//LH/sub 2/ engine predominates in this field at present, a dual fuel engine combining LO/sub 2//LH/sub 2/ and LO/sub 2//hydrocarbon will be realized in near future. The fuel such as LNG (methane) and LPG (propane) will be used for rocket and ramjet engines. (10 refs, 2 figs, 3 tabs)

1987-06-20

295

Constitution of a centralised data base for the internal quality control in radiotherapy; Constitution d'une base de donnees centralisee pour le controle de qualite interne en radiotherapie  

Energy Technology Data Exchange (ETDEWEB)

The objective of this project was to implement a centralised data base of internal quality control in radiotherapy according to the criteria of the decree of A.f.s.s.a.p.s. (French agency of sanitary safety of health products on 27 july 2007, about the internal quality control of external radiotherapy facilities. The software on one year meets the objectives: compliance by comparison with A.f.s.s.a.p.s. criteria but particularly optimization of the centralisation and analysis of the internal quality controls. (N.C.)

2009-10-15

296

Combined inverse modeling approach and load duration curve method for variable nitrogen total maximum daily load development in an agricultural watershed  

British Library Electronic Table of Contents (United Kingdom)

Purpose Nonpoint sources (NPS) pollution has been an important cause for water quality impairment worldwide. To take the temporal variations of both NPS pollution and in-stream attenuation into consideration, an inverse modeling approach and the load duration curve (LDC) method were combined for variable nutrient total maximum daily load (TMDL) development. Methods Water quality and hydrological parameters were monitored monthly along the ChangLe River system in 2004?2008. The catchment NPS export load (EL) and TMDL for total nitrogen (TN) were estimated by the inverse format of an existing stream nutrient transport equation. The LDC method was used to describe the variability of EL, TMDL, requiring load (RLR) and percent (the ratio between the RLR and the EL, RPR) reduction, and then to s...

2011-01-01

297

Wear resistant composite structure of vitreous carbon containing convoluted fibers  

Energy Technology Data Exchange (ETDEWEB)

Very good friction and wear measurements are reported for MRCC (metal reinforced carbon composites), made from low-wear non-graphitic carbon matrix with metal-fiber reinforcement. Counterfaces include austenitic and martensitic stainless steels, Si nitride, and alumina. Effects of high load, high temperature, and gaseous environments are reported: removal of humidity, atm. oxygen have little effect on friction, wear for MRCC sliding against ceramic or stainless steel. Wear of Al oxide riders on MRCC is very low, not affected by contact load. 260 C temperatures do not degrade performance of 440-C riders on MRCC disks or raise friction. In small or large sizes, MRCC is made in a single-pass process for about the same volume cost as cast iron. It can survive heating in nitrogen above 1600 C without loss of integrity or major change of dimensions.

1995-02-01

298

UPS fine structures of highest occupied band in vanadyl-phthalocyanine ultrathin film  

Energy Technology Data Exchange (ETDEWEB)

Ultraviolet photoelectron spectra were measured for vanadyl phthalocyanine (VOPc) ultrathin films prepared on graphite to study effects of the molecular orientation and the electric dipole layer on the organic electronic states. VOPc has a permanent electric dipole perpendicular to the molecular plane, hence a well-defined electric dipole layer could be intentionally prepared by using the oriented monolayer. The observed binding-energy difference of the highest occupied molecular orbital (HOMO) bands between the oriented monolayer and the double layer was found to agree with the vacuum level shift, leading to a conclusion that the molecular energy level with respect to the substrate Fermi level is changed when the molecule is in the electric dipole layer.

2005-06-15

299

The thermodynamic characteristics of retention of tricyclo[5.2.1.02,6]decane isomer molecules on different sorbents in gas chromatography  

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of sorption of the isomeric tricyclo[5.2.1.02.6]decane (tetrahydrodicyclopentadiene, TDCPD) molecules were for the first time determined experimentally and by molecular statistical methods under the conditions of gas-adsorption chromatography on graphitized thermal carbon black and gas-liquid chromatography on stationary liquid phases of different polarities (Apiezon L and Carbowax 20M). The effects of the chemical nature of sorbents on the retention of the TDCPD isomers are considered. A procedure for calculating the thermodynamic characteristics of adsorption of molecules with a complex structure is suggested within the framework of the atom-atom approximation of the semiempirical molecular statistical theory of adsorption for the example of isostructura...

2008-01-01

300

The special features of equilibrium adsorption of argon on homogeneous and inhomogeneous surfaces  

British Library Electronic Table of Contents (United Kingdom)

Comparative patterns of equilibrium adsorption of argon on the surface of graphitized thermal carbon black (GCB) and the inhomogeneous surfaces of nongraphitized carbon black and silica at 77 and 87.3 K were considered. It was shown that argon acquires the properties of a special phase with a layered structure and exhibits two-dimensional phase transitions with the formation of crystal-like layers near the homogeneous surface of GCB even at a temperature exceeding the triple point. However, already at a distance of three-four molecular diameters from the surface, adsorbed argon behaves as a bulk phase in a weak external field. The defect surface of nongraphitized carbon black and the amorphous surface structure of silica destroy the longrange order of adsorbed argon and lower its solidific...

2008-01-01

301

The effects of curvature and surface heterogeneity on the adsorption of water in finite length carbon nanopores: a computer simulation study  

British Library Electronic Table of Contents (United Kingdom)

The effects of pore curvature and surface heterogeneity on the adsorption of water on a graphitic surface at 298 K were investigated using a Grand Canonical Monte Carlo (GCMC) simulation. Slit and cylindrical pores are used to study the curvature effects. To investigate the surface heterogeneity the functional group and the structural defect on the surface were specifically considered. The hydroxyl group (OH) is used as a model for the functional group and the water potential model proposed by Muller et al. is used to calculate the water interaction. For the homogeneous cylinder, the pore filling occurs at a pressure lower than the saturation pressure of the water model, while it is greater in the case of homogeneous slit pore. The size of hysteresis loop is more sensitive to the length of...

2008-01-01

302

The SUERC AMS laboratory after 3 years  

British Library Electronic Table of Contents (United Kingdom)

The new SUERC AMS Laboratory was described at AMS-9. Since then there have been technological developments, added and improved analysis capability, the formation of additional complementary groups, the purchase of another instrument, and many samples measured. Be, C, Al, Cl, Ca and I-AMS are established with measured species changing weekly. Full-terminal potential running is now routine and 5MV is proving sufficient for all species. Ion detection and evaluation has also been improved by the use of even thinner detector windows as necessary and a more powerful on-line data analysis system. Routine radiocarbon measurement is to 4permil reproducibility at middling current and graphite samples of as little as 100mg C can be accommodated. Even smaller samples can be measured as CO2 using He ca...

2007-01-01

303

Test blast furnace smeltings on coke from a charge containing Vorga-Shora coal  

Science.gov (United States)

Changes in the supply situation have necessitated the use of poorly-caking coals in blends for blast furnace coke. This has led to impairment of the coke rate (up to 9 kg/t iron) and furnace throughput (down 3.8%). Coke strength has suffered and leads to difficulties in the hearth area. Despite maintained pressure gradient between throat and tuyeres, blast figures were lower, suggesting decreased permeability of the charge and a general deterioration in heat utilization. Coke breeze became excessive and had to be removed on several occasions. Other factors which may be involved include the graphitization of the coke and its combustibility, neither of which were included in this study; coke quality, however, remains of prime importance to projected increases in furnace capacity.

1982-08-01

304

Simulation study on retention and reflection from tungsten carbide under high fluence of helium ions  

Energy Technology Data Exchange (ETDEWEB)

We have studied, by a Monte Carlo simulation code ACAT-DIFFUSE, the fluence-dependence of the amount of retained helium atoms in tungsten carbide at room temperature under helium ion bombardment. The retention behavior may be understood qualitatively in terms of irradiation-dependent diffusion coefficient assumed and range. The emission processes from tungsten carbide under helium ion irradiation derived were compared with each other. We have discussed the retention curves for incident energy of 5 keV at incident angles of 0deg and 80deg and of 500 eV at 0deg. The energy spectra of helium atoms reflected from tungsten carbide for incident energy of 500 eV at 0deg and 80deg were compared with those from graphite and tungsten. (author)

2000-08-01

305

Scuffing behavior of gray iron and 1080 steel in reciprocating and rotational sliding  

British Library Electronic Table of Contents (United Kingdom)

Scuffing damage is catastrophic and typically not self-healing. It severely affects the life and reliability of engineering components, such as cams, roller bearings, piston rings, cylinder bores and gears. Gray iron and 1080 steel are important materials for these extremely demanding structural components. There have been several scuffing studies done in the past with various types of steel and cast iron. However, in these studies there was no attempt to compare the scuffing resistance of cast iron and steel materials with similar matrices. In the present study, scuffing tests were performed with the matrices of gray iron and 1080 steel being fully pearlitic. This allows for a direct evaluation of the effect of the graphite flakes on scuffing resistance. The scuffing behavior for these ma...

2011-01-01

306

Positive safety features of US nuclear reactors: technical lessons confirmed at Chernobyl. Hearing before the Subcommittee on Energy Research and Production of the Committee on Science and Technology, US House of Representatives, Ninety-Ninth Congress, Second Session, May 14, 1986, No. 138  

Science.gov (United States)

Dr. Rudolf Schulten of West Germany and expert witnesses from national laboratories, utilities, and the nuclear industry testified on reactor safety issues as they relate to the Chernobyl accident and public concern that modern technology has not paid enough attention to public safety. Each of the witnesses contributed safety-related information based on what has been learned from the Soviet incident. Particular focus went to similarities and differences between the Chernobyl and US reactors in safety design and engineering and to the environmental effects of the accident. The N reactor near Richland and a commercial reactor at Fort St. Vrain, Colorado are the only two operating graphite reactors, but neither is a boiling water reactor.

1986-01-01

307

Positive safety features of US nuclear reactors: technical lessons confirmed at Chernobyl. Hearing before the Subcommittee on Energy Research and Production of the Committee on Science and Technology, US House of Representatives, Ninety-Ninth Congress, Second Session, May 14, 1986, No. 138  

International Nuclear Information System (INIS)

Dr. Rudolf Schulten of West Germany and expert witnesses from national laboratories, utilities, and the nuclear industry testified on reactor safety issues as they relate to the Chernobyl accident and public concern that modern technology has not paid enough attention to public safety. Each of the witnesses contributed safety-related information based on what has been learned from the Soviet incident. Particular focus went to similarities and differences between the Chernobyl and US reactors in safety design and engineering and to the environmental effects of the accident. The N reactor near Richland and a commercial reactor at Fort St. Vrain, Colorado are the only two operating graphite reactors, but neither is a boiling water reactor.

308

Polyamide/Polystyrene Blend Compatibilisation by Montmorillonite Nanoclay and its Effect on Macroporosity of Gas Diffusion Layers for Proton Exchange Membrane Fuel Cells  

British Library Electronic Table of Contents (United Kingdom)

This work deals with a new route to modify polymer blend morphology in order to improve the porosity of gas diffusion layers (GDLs) for proton exchange membrane fuel cells (PEMFCs). First, electrically conductive polymer-based blends were carefully formulated using a twin-screw extrusion process. Blend electrical conductivity was ensured by the addition of high specific surface area carbon black and synthetic graphite flakes. Final GDL porosity, in particular its macroporosity, was generated by melt blending polyamide 11 (PA11) matrix with polystyrene (PS) followed by PS extraction with tetrahydrofuran (THF) solvent at room temperature. In order to improve GDL porosity by the optimisation of PS dispersion in the PA11 matrix, PA11/PS blends were compatibilised by the addition of 2 wt.-% of ...

2007-01-01

309

Plasma nitrided titanium as a bipolar plate for proton exchange membrane fuel cell  

Energy Technology Data Exchange (ETDEWEB)

Plasma nitriding was applied to improve the surface performance of titanium bipolar plate. XRD and SEM results showed a titanium nitride layer was formed after nitridation. In comparison with pure titanium, the interfacial contact resistance of plasma nitrided titanium was reduced to some extent by the nitridation treatment. However, high corrosion current was observed under electrochemical tests in 0.5 M H{sub 2}SO{sub 4} + 5 ppm HF. Both the electrical conductivity and corrosion resistance of the surface of plasma nitriding titanium did not reach the level of graphite. Some more improvements are expected in the plasma nitriding process or another surface modification on pure titanium. (author)

2009-02-15

310

On the anatomy of the adsorption heat versus loading as a function of temperature and adsorbate for a graphitic surface  

British Library Electronic Table of Contents (United Kingdom)

In this paper we review and classify the various patterns of isosteric heat versus loading for adsorption of gases on graphitised thermal carbon black at temperatures ranging from below the 3D triple point to temperatures above it, but less than the 3D critical point. We have identified the features of heat curve and highlighted the microscopic origin of these features. The patterns vary with temperature and with the relative strength of the fluid-fluid interaction and solid-fluid interaction. For simple adsorptives (by simple we meant there is no strong association between fluid particles), the heat curve is typified by fluid-fluid attraction and layering phenomena. For adsorptives showing strong association such as water, ammonia and methanol, the heat curve essentially begins below the ...

2008-01-01

311

Neutron physical investigations on the shutdown effect of small boronated absorbing spheres for pebble-bed high-temperature gas-cooled reactors  

Energy Technology Data Exchange (ETDEWEB)

An emergency shutdown system for high-temperature gas-cooled pebble-bed reactors is proposed in addition to the common absorber rod shutdown system. This system is based on the strongly absorbing effect of small boronated graphite spheres (called KLAK), which trickle in case of emergency by gravity from the top reflector into the reactor core. The inner reflector of the Siemens-Argonaut reactor was substituted by an assembly of spherical Arbeitsgemeinschaft Versuchsreaktor fuel elements, and the shutdown effect was examined by installing well-defined KLAK nests inside this assembly. The purpose was to develop and prove a calculational procedure for determining criticality values for assemblies of large fuel spheres and small absorbing spheres.

1987-09-01

312

Microanalytical method development for Fe, Cu and Zn determination in colorectal cancer cells  

British Library Electronic Table of Contents (United Kingdom)

Microanalytical methods suitable for the determination of Fe, Cu in HT-29 (human colon adenocarcinoma) cells treated with different iron compounds (Fe(II) sulfate, Fe(III) chloride, Fe(III) citrate and Fe(III) transferrin) and cultured in medium supplemented or not with 10% (v/v) fetal calf serum (FCS) by total reflection X-ray fluorescence spectrometry (TXRF) and simultaneous graphite furnace atomic absorption spectrometry (GF-AAS) were developed. The developed TXRF method was also suitable for Zn determination in the samples. The main advantage of the proposed methods is the execution of all sample preparation steps following incubation and prior to the elemental analysis in the same Eppendorf tubes. Sample preparation was performed at microscale (115mL sample volume) with 65% nitric aci...

2011-01-01

313

Method and apparatus for spraying molten materials  

Energy Technology Data Exchange (ETDEWEB)

A metal spray apparatus is provided with a supersonic nozzle. Molten metal is injected into a gas stream flowing through the nozzle under pressure. By varying the pressure of the injected metal, the droplet can be made in various selected sizes with each selected size having a high degree of size uniformity. A unique one piece graphite heater provides easily controlled uniformity of temperature in the nozzle and an attached tundish which holds the pressurized molten metal. A unique U-shaped gas heater provides extremely hot inlet gas temperatures to the nozzle. A particularly useful application of the spray apparatus is coating of threads of a fastener with a shape memory alloy. This permits a fastener to be easily inserted and removed but provides for a secure locking of the fastener in high temperature environments.

1996-01-01

314

Lithium carbon batteries with solid polymer electrolyte; Accumulateur lithium carbone a electrolyte solide polymere  

Energy Technology Data Exchange (ETDEWEB)

The lithium carbon batteries studied in this paper use plasticized polymer electrolytes made with passive polymer matrix swollen by a liquid electrolyte with a high ionic conductivity (> 10{sup -3} S/cm at 25 deg. C). The polymers used to prepare the gels are polyacrylonitrile (PAN) and vinylidene poly-fluoride (PVdF). The electrochemical and physical properties of these materials are analyzed according to their composition. The behaviour of solid electrolytes with different materials of lithium ion insertion (graphite and LiNiO{sub 2}) are studied and compared to liquid electrolytes. The parameters taken into account are the reversible and irreversible capacities, the cycling performance and the admissible current densities. Finally, complete lithium ion batteries with gelled electrolytes were manufactured and tested. (J.S.) 2 refs.

1996-12-31

315

Linearized augmented-plane-wave method for quasi-unidimensional systems: Carbyne and nanotube (Sc@C{sub 20})  

Energy Technology Data Exchange (ETDEWEB)

The advent of carbon nanotubes, which are graphite layers convoluted in cylinders several nanometers in diameter and several micrometers in length, as well as the experiments on implanting metal atoms in such tubes open the way to producing nanoconductors and other materials with unique properties. For theorists, the basic challenge is interpreting and predicting the structure and properties of these systems. The linearized augmented-plane-wave method (LAPW) is one of the most accurate methods in the theory of the electronic structure of solids. A generalization of this method for quasi-two-dimensional systems, surface electronic states, and layered crystals is known. The LAPW theory for quasi-unidimensional systems, which exhibit translational symmetry in one direction, has been absent thus far. In this paper, the authors suggest a version of such a theory and use this method to calculate the electronic structure of carbyne (a linear chain of carbon atoms) and ...

1995-10-01

316

Kinetics of pore coarsening in glassy carbon  

Energy Technology Data Exchange (ETDEWEB)

One third of the microstructure of glassy carbon (GC) consists of closed pores. Density measurements indicate that the total pore volume depends only on the heat treatment temperature and not on the heat treatment time, a characteristic of coarsening. The kinetics of coarsening of these pores on heat treatment has been investigated by analyzing the changes in specific surface area of the pores as determined by the small angle X-ray scattering (SAXS) technique. A part of the surface area change is due to thermal expansion induced microcracking. Both the superposition method after correcting the thermal expansion induced surface area change and the curve fitting method give an activation energy of 64 +/- 10 kcal/mole. This value is compared with the activation energies of various rate processes in graphite. A model of coarsening of the pores based on a vacancy migration mechanism is proposed.

1981-01-01

317

Infrared monitoring of the Doublet III beam armor plate  

Energy Technology Data Exchange (ETDEWEB)

An 80 keV, 3.6 MW neutral beam injection system has recently been installed on Doublet III, and the installation of a second system is scheduled within several months. Armor plate consisting of /approximately equals/100 graphite tiles (10 cm x 10 cm) coated with TiC has been plated over portions of the inner vacuum wall lying in the line of sight of the ion sources. In order to monitor the condition of the armor plate an infrared camera and a set of optical pyrometers have been installed alongside the beamline and view the armor plate through a CaF/sub 2/ window. The pyrometers measure the temperature of the armor plate associated with the maximum of the intensity distribution of each ion source.

1981-01-01

318

Hydrogen production from solar thermal dissociation of natural gas: development of a 10kW solar chemical reactor prototype  

British Library Electronic Table of Contents (United Kingdom)

This study addresses the solar thermal decomposition of natural gas for the co-production of hydrogen, as well as Carbon Black as a high-value nano-material, with the bonus of zero CO2 emissions. The work focused on the development of a medium-scale solar reactor (10kW) based on the concept of indirect heating. The solar reactor is composed of a cubic cavity receiver (20cm side), which absorbs concentrated solar irradiation through a quartz window via a 9cm-diameter aperture. The reacting gas flows inside four graphite tubular reaction zones that are settled vertically inside the cavity. Experimental results were as follows: methane conversion and hydrogen yield of up to 98% and 90%, respectively, were achieved at 1770K, and acetylene was the most important by-product, with a mole fraction...

2009-01-01

319

Grafoil applications on-plant  

International Nuclear Information System (INIS)

Presented in this report are the quantitative and qualitative aspects of the more than 5,800 applications of Grafoil on-plant. The subject all-graphite product was originally made by the Union Carbide Corporation. Its utilization in the forms of valve packing, gasketing and sealant tapes for leak repair and prevention on-plant since March 1970 is marked with typical zero-leak results. For all practical purposes, the successful results with Grafoil implementation indicate an unqualified control of leakage problems that began in 1967 with the V-11 and V-12 valves in the primary system of N Reactor. Meaningfully, the accruals of savings with existing and future applications shall continue to be incalculable in personnel exposure, maintenance, and capital. Inherent in the savings are the devised methodology and innovative developments coordinately employed in resolving the leak repair problems.

320

Gas chromatographic, quentum-chemical, and molecular statistical studies of cluster adsorption of water and methanol molecules on hydrophilic surface sites of hydrophobic adsorbents  

British Library Electronic Table of Contents (United Kingdom)

The comprehensive theoretical and experimental study of the adsorption of water and methanol molecules on active sites (carboxyl and phenol hydroxyl groups) on the graphitized thermal carbon black is performed. It is shown that microclusters formed upon the adsorption of these molecules on such sites are characterized by the cyclic structure comprising 4?5 molecules similar to that whose existence was revealed previously in liquid water and on the surface of silver iodide. The analysis of the studied adsorption clusters demonstrated that the formation of such cycles is governed primarily by the hydrogen bonding; however, a definite role is played also by energy effects associated with the changes in the state of molecular motion during adsorption. It is shown that the generalized Langmuir ...

2008-01-01

321

Feasibility investigations of growing and characterizing gallium arsenide crystals in ribbon form. Quarterly progress report 1 Jan-31 Mar 1975  

International Nuclear Information System (INIS)

The feasibility of continuous production of gallium arsenide ribbon single crystals, by passage of a molten zone through boron-oxide encapsulated GaAs feedstock, is being investigated. Polycrystalline GaAs ribbons have been grown in graphite boats by passage of a wide zone through B2O3-encapsulated feed-stock, confined by a quartz cover plate. Failure to remove the encapsulant above its glass transition temperature, however, resulted in cracking of the ribbons on cooling to room temperature. In order to study the crucial zone melting step in isolation from the encapsulation steps of the continuous process, a constrained-zone melting apparatus has been constructed in which the boron oxide serves only as a sealant to suppress arsenic vaporization. Large grained polycrystalline samples have been produced with this apparatus.

322

Experimental and theoretical investigation of amino acids dimers and associates adsorption on carbon surface  

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption (the Henry constant, the heat and entropy of adsorption) of amino acids associates with acetic, trifluoroacetic, nonafluoropentanoic acids and formamide with different values of hydrogen bond lengths and various conformations on a graphitized thermal carbon black (GTCB) were calculated. The experimental results, as the Henry constant, lnK1, and the differences in the molar Gibbs energies, d(DG), obtained by a high performance liquid chromatography (HPLC) on a carbon sorbent Hypercarb, were compared with the values of thermodynamic characteristics of adsorption of the amino acids on the GTCB surface calculated by a molecular-statistical method. A satisfactory correlation was observed between the experimental and calculated values with a coeffi...

2011-01-01

323

Electrogenerated Chemiluminescence Sensor Based on Tris(2,2prime-bipyridine)ruthenium(II)-Immobilized Natural Clay and Ionic Liquid  

British Library Electronic Table of Contents (United Kingdom)

A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2prime-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.

2010-01-01

324

Electrodeposition and magnetic properties of three-dimensional bulk and shell nickel mesostructures  

British Library Electronic Table of Contents (United Kingdom)

In this paper we demonstrate the electrodeposition of nickel, a common ferromagnetic material, in various magnetically desirable shapes including nanowires, nanoparticles and highly faceted shells. In order to obtain three dimensional mesostructures, the electrochemical deposition of nickel was performed on highly oriented pyrolytic graphite (HOPG) under different electrolyte composition and deposition potential conditions. Under potentiostatic deposition at one distinct potential negative with respect to the reversible potential of nickel, three stages of nucleation and growth take place leading to a complex morphology of deposits. However, dual-pulse potential deposition and electrodeposition in low pH solutions causing hydrogen evolution, lead to nickel deposits in the form of nanowires...

2011-01-01

325

Electrochemical impedance of electrolyte/electrode interfaces of lithium-ion rechargeable batteries  

Energy Technology Data Exchange (ETDEWEB)

It is well known that a protective film is formed on the graphite negative electrode in ethylene carbonate (EC) electrolyte solution. This film is lithium-ion conductive and protects the decomposition of the electrolyte solution. In the present paper, the electrode/electrolyte interfaces in lithium-ion rechargeable batteries were characterized by three-dimensional complex impedance plots, whose axes are real, imaginary parts and time. The film resistance R {sub sei} and charge transfer resistance R {sub ct} were determined for negative electrodes in EC/ethyl methyl carbonate (EMC) electrolyte solution, and the formation mechanisms of the interfacial film were discussed. Furthermore, the contributions of vinylene carbonate and ethylene sulfite, which are added into the electrolyte solution for the film formation, were investigated.

2006-01-20

326

Electrochemical impedance of electrolyte/electrode interfaces of lithium-ion rechargeable batteries  

International Nuclear Information System (INIS)

It is well known that a protective film is formed on the graphite negative electrode in ethylene carbonate (EC) electrolyte solution. This film is lithium-ion conductive and protects the decomposition of the electrolyte solution. In the present paper, the electrode/electrolyte interfaces in lithium-ion rechargeable batteries were characterized by three-dimensional complex impedance plots, whose axes are real, imaginary parts and time. The film resistance R _s_e_i and charge transfer resistance R _c_t were determined for negative electrodes in EC/ethyl methyl carbonate (EMC) electrolyte solution, and the formation mechanisms of the interfacial film were discussed. Furthermore, the contributions of vinylene carbonate and ethylene sulfite, which are added into the electrolyte solution for the film formation, were investigated.

2006-01-20

327

Development of long-life BF3 counters  

Energy Technology Data Exchange (ETDEWEB)

In order to improve the well-known short operational life time of BF3 counters, three potential adsorbents for impurity gases (graphite, activated charcoal and a zirconium-aluminum mixture) were introduced into BF3 counters in the form of coating on the aluminum cathode surface. Tests in el fields revealed that a partial coating of activated charcoal provides the best result. The improvement of their operational life in el fields was about three orders of magnitude in terms of tolerable exposure. Many counters with a partial coating of activated charcoal were further tested from the following viewpoints: background noise, vibration and shock, el pulse discrimination, operational life in a neutron field and non-operational in-reactor exposure life. The results were satisfactory for reactor control and protection usage. (author).

1985-02-01

328

Development of large scale parallel visco-elastic analysis system with mesoscopic material model  

International Nuclear Information System (INIS)

We develop a large scale parallel viscous-elastic analysis program incorporating a mesoscopic self-consistent model developed by Laws. In the model, macroscopic elastic constants are treated as variables depending on the shape and statistical properties of pre-existing microscopic pores and change due to neutron irradiation. We apply this program to the visco-elastic analysis of nuclear graphite structures under neutron irradiation environment in High Temperature Gas-cooled Reactor (HTGR), as an example problem. Furthermore the calculated results by this parallel computational program are compared with those by one of commercial finite element analysis codes, FINAS, for validating elastic and thermal stress analysis function. (author)

2000-09-01

329

Determination of selected microelements in polish herbs and their infusions  

Energy Technology Data Exchange (ETDEWEB)

Ba, Cd, Cr, Cu, Fe, Ni, Pb and Zn were determined in birch leaves (Folium Betulae), dandelion roots (Radix Taraxacae), hawthorn blossom (Inflorescentia Crataegi) and their infusions by graphite furnace atomic absorption spectrometry (GFAAS) after microwave digestion of plant samples. Infusions were made from herbs according to prescription for patients, provided by the producer of medicine on the package. The results obtained were compared with daily requirements for each element. Results show high content of cadmium in the medicinal plants analyzed. The highest level in infusions was observed for Ni and Zn (over 90% of the total element concentration for Ni and in most cases over 50% for Zn), and the lowest for Cd and Pb. The calculated daily intake of majority of the analyzed elements was very low (under 1% of daily requirements)

2007-08-01

330

Decontamination of a gas-cooler by means of chemical reagent loaded foams  

Energy Technology Data Exchange (ETDEWEB)

This paper briefly describes an industrial application of the foam decontamination process applied to large volume components. The process is based on the filling of the component with liquid foam containing suitable chemical reagents, and a circulation loop enables its continuous recycling. The process was successfully validated during the decontamination of a graphite gas-cooler representing a developed area of 1000 m{sup 2}. A decontamination factor up to 190 was obtained leading to a residual activity below 1 Bq/cm{sup 2}. The process only produced 6 m{sup 3} of effluent i.e. about ten times less than for a chemical solution technique. (authors) 2 refs.

1995-12-31

331

Behavior of trace refractory minerals in the lithium metaborate fusion-acid dissolution procedure  

Science.gov (United States)

The feasibility of this procedure was investigated using minerals and ore specimens. The substances were ground then fused using LiBO/sub 2/, quenched with 3% HNO/sub 3/ or mixtures of the acid with 2.5% tartaric acid or 30% H/sub 2/O/sub 2/. The quenched melt was usually completely dissolved within 20 min by placing the beakers in an ultrasonic bath. If any residue was detected, appropriate changes were made in the procedure. Once the procedure has been optimized, any remaining black particles were filtered. If these particles disappeared upon subsequent ignition, they were presumed to have been graphite. Most of the refractory minerals investigated should be expected to be converted to soluble form by this process. 1 table.

1983-12-01

332

A novel electrogenerated chemiluminescence sensor for pyrogallol with core-shell luminol-doped silica nanoparticles modified electrode by the self-assembled technique  

British Library Electronic Table of Contents (United Kingdom)

The core-shell luminol-doped SiO2 nanoparticles were synthesized and immobilized on the surface of chitosan film coating graphite electrode by the self-assembled technique. Then, a novel electrogenerated chemiluminescence (ECL) sensor for pyrogallol was developed based on its ECL enhancing effect for the core-shell luminol-doped silica nanoparticles. The ECL analytical performances and the sensing mechanism of this ECL sensor for pyrogallol were investigated in detail. The corresponding results showed that: compared with the conventional ECL reaction procedures by luminol ECL reaction system, the electrochemical (EC) reaction of pyrogallol and its subsequent chemiluminescence (CL) reaction occurred in the different spatial region whilst offering a high efficiency to couple the EC with the ...

2006-01-01

333

A miniaturized spatial temperature gradient capillary electrophoresis system with radiative heating and automated sample introduction for DNA mutation detection  

British Library Electronic Table of Contents (United Kingdom)

Abstract A miniaturized spatial temperature gradient CE system with automated sample introduction for DNA mutation detection was established. Continuous electrokinetic sample injection was achieved by combining an automated slotted vial array sample introduction device to the spatial temperature gradient CE system. The temperature gradient was produced by a radiative heating system with a single graphite block heater, and the stability of the temperature gradient was investigated. The temperature variation of each measure point was 0.12 0.21% RSD (n=7) within 6 h. A 14 cm Teflon AF coated silica capillary was used both as the separation channel and as the liquid core waveguide tube of fluorescence signal. Under a temperature gradient from 54.8 to 59.5 C, a low range control mutation standa...

2010-01-01

334

Visible (657 nm) InGaP/InAlGaP strained quantum well vertical-cavity surface-emitting laser  

Science.gov (United States)

We report the first visible (657 nm) vertical-cavity surface-emitting laser. The photopumped undoped structure was grown using low-pressure metalorganic vapor-phase epitaxy in a single-growth sequence on misoriented GaAs substrates. The optical cavity consists of an In{sub 0.54}Ga{sub 0.46}P/In{sub 0.48}(Al{sub 0.7}Ga{sub 0.3}){sub 0.52} P strained quantum-well active region and a lattice-matched In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52} P (0.7{le}{ital y}{le}1.0) graded spacer region, while the distributed Bragg reflectors are composed of Al{sub 0.5}Ga{sub 0.5}As/AlAs quarter-wave stacks. Room-temperature optically pumped lasing was achieved with a very low-threshold power, clearly demonstrating the viability of this new technology. These results provide the foundation for visible semiconductor laser-diode arrays for a number of applications including laser projection displays, holographic memories, and plastic fiber ...

1992-04-13

335

Photovoltaic plants in the electronic system; Gli impianti fotovolatici nel sistema elettrico. Stato e prospettive  

Energy Technology Data Exchange (ETDEWEB)

The article provides a 1998 updated picture of Italy's and the world's photovoltaic market in terms of produced modules and total installed capacity, as well as market growth forecasts up to 2010. After a short description of the state-of-the-art of cell and module manufacturing, ana analysis of the cost of producing a photovoltaic kw is reported for different plant types: stand-alone plants with energy storage batteries, plants connected to low low voltage networks or intended for supporting medium voltage networks, hybrid plants with diesel sets. The article is concluded by illustrating ENEL's (Electric Power Production Company) engagement in the field of photovoltaic solar energy as regards theoretical studies, research and testing of new technologies, and installing plants; over nearly twenty years of activity, ENEL has designed and built a few hundreds of photovoltaic plants for a total capacity of about 4.000 kw, and is currently in the process of ...

1999-04-01

336

Photoluminescence linewidths in metalorganic vapor phase epitaxially grown ordered and disordered InAlGaP alloys  

Science.gov (United States)

The dependence of the photoluminescent properties of In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52}P alloys (0{le}{ital y}{le}0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ordered'' domains and the disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a ...

1992-12-01

337

Photoluminescence linewidths in metalorganic vapor phase epitaxially grown ordered and disordered InAlGaP alloys  

Energy Technology Data Exchange (ETDEWEB)

The dependence of the photoluminescent properties of In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52}P alloys (0{le}{ital y}{le}0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ordered'' domains and the disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a ...

1992-12-01

338

Measurements of water vapor adsorption on the Geysers rocks  

Energy Technology Data Exchange (ETDEWEB)

The ORNL high temperature isopiestic apparatus was adapted for adsorption measurements. The quantity of water retained by rock samples taken from three different wells of The Geysers was measured at 150 °C and at 200 °C as a function of pressure in the range 0.00 &le; p/p0 &le; 0.98, where p0 is the saturated water vapor pressure. The rocks were crushed and sieved into three fractions of different grain sizes (with different specific surface areas). Both adsorption (increasing pressure) and desorption (decreasing pressure) runs were made in order to investigate the nature and extent of the hysteresis. Additionally, BET surface area analyses were performed by Porous Materials Inc. on the same rock samples using nitrogen or krypton adsorption measurements at 77 K. Specific surface areas and pore volumes were determined. These parameters are important in estimating water ...

1996-01-24

339

Light charged particles and intermediate mass fragments from the reactions 486, 550, 640, and 730 MeV [sup 86]Kr + [sup 63]Cu  

Energy Technology Data Exchange (ETDEWEB)

A study has been made of the reaction [sup 86]Kr + [sup 63]Cu at incident energies of 486, 550, 640, and 730 MeV. Measurements include cross sections, angular distributions, and energy spectra for light charged particles ([sup 1,2,3]H and [sup 4]He), intermediate mass fragments (IMF) (4 [le] Z [le] 17), and heavy fragments (Z [ge] 18). Coincidences between light charged particles and between particles and fragments have been measured to obtain cross sections, energy spectra, and angular distributions. Statistical model analysis of the energy spectra for [sup 1]H and [sup 4]He detected in coincidence with the fragments has allowed estimation of [sup 1]H and [sup 4]He multiplicities associated with the evaporation residues, fragments, and composite nuclei prior to scission. A comparison of cross sections, energy spectra, angular distributions, and particle multiplicities for these matched entrance channels has provided the means for a detailed ...

1992-01-01

340

Crystalline electric field of the rare-earth nickelates RniO{sub 3} (R = Pr, ND, Sm, Eu, and Pr{sub 1-x}La{sub x},0 {le} X {le} 0.7) determined by inelastic neutron scattering.  

Energy Technology Data Exchange (ETDEWEB)

The rare-earth based nickelates RNiO{sub 3} (R = Pr, Nd, Sm, Eu, and Pr{sub 1-x}La{sub x}, 0{<=}x{<=}0.7) were studied by inelastic neutron scattering. Energy splittings due to the crystalline-electric-field (CEF) interaction at the R{sup 3+} site within the electronic ground-state J multiplet (for R = Pr, Nd, and Pr{sub 1-x}La{sub x}) as well as within the two lowest-lying J multiplets (for R = Sm and Eu) were directly observed, and the corresponding CEF energy-level schemes were reconstructed. The latter were rationalized in terms of CEF parameters, which vary smoothly over the rare-earth series and give magnetic properties associated with the R sublattice in agreement with results from neutron powder diffraction experiments. Across the metal-insulator transition, a continuous change in the electronic part of the CEF parameters is observed. However, an attempt to quantify a charge transfer from the observed variation of the CEF parameters in an effective point charge ...

1999-12-01

341

Sizes, graphitic structures and fractal geometry of light-duty diesel engine particulates.  

Energy Technology Data Exchange (ETDEWEB)

The particulate matter of a light-duty diesel engine was characterized in its morphology, sizes, internal microstructures, and fractal geometry. A thermophoretic sampling system was employed to collect particulates directly from the exhaust manifold of a 1.7-liter turbocharged common-rail direct-injection diesel engine. The particulate samples collected at various engine-operating conditions were then analyzed by using a high-resolution transmission electron microscope (TEM) and an image processing/data acquisition system. Results showed that mean primary particle diameters (dp), and radii of gyration (Rg), ranged from 19.4 nm to 32.5 nm and 77.4 nm to 134.1 nm, respectively, through the entire engine-operating conditions of 675 rpm (idling) to 4000 rpm and 0% to 100% loads. It was also revealed that the other important parameters sensitive to the particulate formation, such as exhaust-gas recirculation (EGR) rate, equivalence ratio, and temperature, affected particle sizes ...

2003-01-01

342

Raman spectroscopic studies of carbon in extra-terrestrial materials  

International Nuclear Information System (INIS)

The measurements obtained here indicate ways in which micro-Raman spectroscopy can be used to elucidate structural characteristics and distribution of carbon in meteorites and interplanetary dust particles (IDPs). Existing information about structurally significant aspects of Raman measurements of graphite is combined with structurally relevant findings from the present micro-Raman studies of carbons prepared by carbonization of polyvinylidine chloride (PVDC) at various temperatures and natural material, as well as several acid residues from the Allende and Murchison meteorites in order to establish new spectra-structure relationships. Structural features of many of the materials in this study have been measured by x ray analysis and electron microscopy: thus, their structural differences can be directly correlated with differences in the Raman spectra. The spectral parameters consequently affirmed as indicators of structure are used as a measure of structure in ...

1990-04-01

343

On the anatomy of the adsorption heat versus loading as a function of temperature and adsorbate for a graphitic surface.  

Science.gov (United States)

In this paper we review and classify the various patterns of isosteric heat versus loading for adsorption of gases on graphitised thermal carbon black at temperatures ranging from below the 3D triple point to temperatures above it, but less than the 3D critical point. We have identified the features of heat curve and highlighted the microscopic origin of these features. The patterns vary with temperature and with the relative strength of the fluid-fluid interaction and solid-fluid interaction. For simple adsorptives (by simple we meant there is no strong association between fluid particles), the heat curve is typified by fluid-fluid attraction and layering phenomena. For adsorptives showing strong association such as water, ammonia and methanol, the heat curve essentially begins below the condensation heat and then approaches it as loading is increased. This is mainly due to the strong hydrogen bonding in these fluids. A third group includes adsorptives such as benzene, where the heat ...

2008-05-24

344

ORALLOY (93.2 235U) METAL CYLINDER WITH BERYLLIUM TOP REFLECTOR  

International Nuclear Information System (INIS)

A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, one experiment was comprised of a stack of approximately 7-inch-diameter metal discs. The bottom of the stack consisted of uranium with an approximate height of 4-1/8 inches. The top of the stack consisted of beryllium with an approximate height of ...

345

Heat transfer augmentation by gas-particle two-phase flow  

International Nuclear Information System (INIS)

The helium-cooled HTGR (High Temperature Gas-cooled Reactor) will take an important position in the global energy strategy. It is expected to supply not only electricity but also high quality thermal energy for various industries and local utilities without exhausting any green house effect gas or acid rain gas. The key R and D issue of the HTGR is economical competitiveness, particularly against light water reactors. Due to the poor heat transfer of the single phase helium, the HTGR's volumetric power density is restricted to tenth of corresponding PWR's value so that increasing the power density by improving heat transfer is strongly desired. The standstill can be broken through by adopting gas-solid suspension medium. Its heat transfer performance is quite excellent. Its heat capacity can be increased drastically without excessive pressurization. Although the thermal radiation is a dominant heat transfer mode in high temperature region, the helium which is always used in high ...

1995-06-01

346

Dynamics of a very intense pulsed electron beam  

Energy Technology Data Exchange (ETDEWEB)

A unique beam of pulsed electrons has been developed using the 19-MeV, 700-kA Hermes-III accelerator. The extended planar-anode diode is used to extract at large radius an annular electron beam from the accelerator and inject the resulting beam at small angle into a low-pressure gas cell, where the beam is rapidly charge neutralized and almost current neutralized. Under these conditions, the beam propagates nearly ballistically to a focus downstream of injection, where objects can be placed for irradiation and study. For a focal length of 78 cm, measurements with a segmented calorimeter show that this configuration can deliver an energy deposition of 200 J/g [20 Mrad] over a useful area of 70 cm{sup 2} and a 4-cm depth in graphite in 25 ns. Increasing the injection angle by reducing the AK gap permits higher doses over smaller areas to be achieved. Such beams are of interest for the study of material property changes from short-pulse high-energy depositions and for ...

1994-12-31

347

Computational Fluid Dynamic Analysis of Core Bypass Flow Phenomena in a Prismatic VHTR  

Energy Technology Data Exchange (ETDEWEB)

The core bypass flow in a prismatic very high temperature gas-cooled reactor (VHTR) is one of the important design considerations which impacts considerably on the integrity of reactor core internals including operating fuels. The interstitial gaps are an inherent presence in the reactor core because of tolerances in manufacturing the blocks and the inexact nature of their installation. Furthermore, the geometry of the graphite blocks changes over the lifetime of the reactor because of thermal expansion and irradiation damage. The occurrence of hot spots in the core and lower plenum and hot streaking in the lower plenum (regions of very hot gas flow) will be affected by the bypass flow. In the present study, three-dimensional computational fluid dynamic (CFD) calculations of a typical prismatic VHTR are conducted to understand better the bypass flow phenomenon and establish the evaluation method in the reactor core using commercial CFD code FLUENT. Parametric ...

2010-09-01

348

Study of the {sup 60}Co speciation in the aqueous radioactive waste of the la Hague nuclear reprocessing plant; environmental behaviour after discharges in the waters of the channel; Etude de la speciation du {sup 60}Co dans les effluents de l'usine de retraitement de combustibles irradies de la Hague; devenir apres rejet dans les eaux de la Manche  

Energy Technology Data Exchange (ETDEWEB)

{sup 60}Co is produced as an activation product and is present in the low-level aqueous radioactive waste released from the La Hague plant. At present, the concentration in the sea (non filtered at 0.45 {mu}m) at the Goury site are close to or even below, the detection limit: 0.2 mBq.l{sup -1}. The {sup 60}Co speciation depends on the type of effluent considered: in the effluent A ('active'), the cobalt is in the form of a stable trivalent complex; in the effluent V (to be checked), the cobalt is in majority (50% of the activity release) in the form of particles (>0.45 {mu}m), and then in the form of two soluble species: ionic divalent (Co{sup 2+}) and some stable complexes. The evolution of the reprocessing techniques used does not affect the speciation. So, since the nuclear reprocessing plant started at the La Hague plant in 1966, the chemical species discharged in the sea shows time variation related to the evolution of the type of effluent discharged. ...

1999-07-01

349

Study of the origin of elements of the uranium-235 family observed in excess in the vicinity of the experimental nuclear EL4 reactor under dismantling. Lessons got at this day and conclusions; Etude de l'origine des elements de la famille de l'uranium-235 observes en exces dans les environs du reacteur nucleaire experimental EL4 en cours de demantelement. Enseignements retires a ce jour et conclusion  

Energy Technology Data Exchange (ETDEWEB)

This study resumes the discovery of an excess of actinium 227 found around by EL4 nuclear reactor actually in dismantling. The search for the origin of this excess revealed a real inquiry of investigation during three years. Because a nuclear reactor existed in this area a particular attention will have concerned this region. The doubt became the line of conduct to find the answer to the human or natural origin of this excess. Finally and against any evidence, it appears that the origin of this phenomenon was natural, consequence of the particular local geology. The detail of the different investigations is given: search of a possible correlation with the composition of elevations constituent of lanes, search (and underlining) of new sites in the surroundings of the Rusquec pond and the Plouenez station, study of the atmospheric deposits under winds of the nuclear power plant and in the east direction, search of a possible relationship with the gaseous effluents of the nuclear power ...

2007-07-01

350

Study of the action of a phosphonate additive on steel scale deposit and corrosion in the hydrodynamic conditions of a channel flow cell; Etude de l'action d'un additif phosphone sur l'entartrage et sur la corrosion de l'acier dans les conditions hydrodynamiques d'une cellule a canal  

Energy Technology Data Exchange (ETDEWEB)

In cooling systems, an improved control of scale deposit and corrosion processes is a major challenge and an realistic evaluation tool for water treatments is of the utmost economic importance. In this study, a channel flow cell was used to allow in-situ electrochemical measurements in well defined electrolyte tube flowing conditions. An expression of the mass transfer towards the electrode was established where the diffusion-limited current is a function of Re{sup 1/3} in the laminar regime and was verified experimentally using the redox couples Fe[CN]{sub 6}{sup 4-}/ Fe[CN]{sub 6}{sup 3-} and O{sub 2}/OH{sup -}. This hydrodynamically controlled experimental device was developed to investigate scale deposit processes and to evaluate scale inhibitor efficiency using a electrochemical quartz crystal microbalance. Experiments were performed on three different waters, at various flow rates and temperatures. The efficiency of a well known phosphonate (HEDP) was tested at different ...

2000-10-17

351

Study of structural, thermodynamical and dynamical properties of molecular liquids confined in nano-porous materials; Etude des proprietes structurales, thermodynamiques et dynamiques de liquides moleculaires confines dans des materiaux nanoporeux modeles  

Energy Technology Data Exchange (ETDEWEB)

When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, T{sub g}, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of T{sub g} is observed for small pore sizes and attractive surface while T{sub g} decreases for non attractive surface, whatever the pore size. ...

2006-11-15

352

States with several particles in e{sup +}e{sup -} and {gamma}{gamma} colliders: technique of calculation and launch of a new physics; Etats a plusieurs particules dans les collisionneurs e{sup +}e{sup -} et {gamma}{gamma}: techniques de calcul et effets d'une nouvelle physique  

Energy Technology Data Exchange (ETDEWEB)

The mass generation in the Standard Model of Particles Physics relies on a spontaneous symmetry breaking mechanism. Its implementation is recalled, along with its constraints, both theoretical (Naturalness, Stability, Triviality, Unitarity) and experimental (limits of direct and indirect searches, prospects). Calculation techniques for observables evaluation in Perturbative Field Theory are described, particularly Helicity Amplitude method, which is given in details: fermions and vector bosons, massless and massive. Monte-Carlo integration, and structure functions approximations (which allows non-perturbative calculations) are also detailed. With these tools, a process giving to Physics beyond the Standard Model is studied: it leads to an experimental prediction for the LEP collision ring, taking the classical background into account. Technical aspects of a future photon linear collider are reviewed. The production of heavy vector bosons, either the classical Z for the hypothetical ...

1996-10-22

353

Software framework and jet energy scale calibration in the ATLAS experiment; Environnement logiciel et etalonnage de l'echelle en energie des jets dans l'experience ATLAS  

Energy Technology Data Exchange (ETDEWEB)

This thesis presents the work achieved to instrument the ATLAS software framework, ATHENA, with a library of tools and utensils for the physics analysis as well as the extraction of the jet energy scale using physics events (in-situ calibration). The software part presents the various components of the ATHENA framework which handles the simulated and reconstructed data flow as well as the different stages of this process, before and during the data taking. The building of a library of tools easing the reconstruction of physics objects, their association with Monte-Carlo particles and their API is then explained. The need for common language and collaboration-wide utensils is emphasised as it allows to share the workload of validating these tools and to get reproducible physics results. The analysis part deals with the implementation of a light jet energy scale calibration algorithm within the C++ framework. This calibration algorithm makes use of W bosons decaying into light jets ...

2006-07-01

354

Numerical simulation of the unsteady and turbulent flow in a high-pressure turbine stage; Simulation numerique de l'ecoulement instationnaire et turbulent dans un etage de turbine haute pression  

Energy Technology Data Exchange (ETDEWEB)

The aim of this study concerns the use of numerical methods for the resolution of the Reynolds Averaged Navier Stokes equations adapted to the simulation of the cooling of the trailing edge of a stator in a high pressure turbine. These methods, based on the elsA solver developed at ONERA, use a four steps Runge Kutta time discretization scheme and a Jameson centered space discretization scheme. The scheme is applied through a finite volume approach on control volume centered on the cells of a multi-block structured mesh. Turbulence is simulated either through the algebraic Michel model, or through the one-transport-equation Spalart-Allmaras model, or through the two-transport-equations k 1, k {omega} and k {epsilon} models, and through ASM model. A simulation of the flow in a bidimensional stator, without cooling, is carried out. The cooling, which is realized with trailing edge slots, is then simulated on a bidimensional stator. Because the slot is represented by meshes overlapping ...

2004-09-15

355

Monitoring of natural radioactive elements in some foliose lichens; Recherche d`elements radioactifs naturels dans quelques lichens foliaces  

Energy Technology Data Exchange (ETDEWEB)

Samples of Parmelia sulcata and Xanthoria parietina from different biotopes have been analysed for elements of the series of uranium 238 and thorium 232. These species have been used as bio-monitors in different cases : urban areas, coal fired power plant, tip for uranium-mining residues. The concentration of most of these elements in lichens is decreasing as follows: radium waste-disposal site > area with uranium-rich soil > urban area > rural area. Road traffic was not found to increase notably the presence of radioactive lead in the environment. The two foliose lichens seem to have a comparable concentration ability, but Parmelia sulcata appeared to be more reliable. Some of the elements under investigation could be particularly problematic from a sanitary point of view: the intake limits in case of inhalation are very low and the atmospheric deposition is not negligible; this is particularly so for lead 210 and thorium 228. These elements should not only be monitored on a ...

1996-12-31

356

Memento of decision makers: the national organizations involved in the mastery of greenhouse gas emissions; Memento des decideurs: les collectivites territoriales engagees dans la maitrise des emissions de gaz a effet de serre  

Energy Technology Data Exchange (ETDEWEB)

In front of the risks linked with the increase of the greenhouse gas emissions in the atmosphere, the decision makers must take into consideration first, the scientific advice of climatic change experts, and second, the considerable inertia of the climatic system. Thus, any action implemented so far will have an impact all along the 21. century and later whatever the future human activities. The aim of this memento is to sensibilize the decision makers about the possible consequences of their choice in terms of volume of greenhouse gases and of medium- and long-term evolution: 1 - stakes, role of local decision-makers (greenhouse effect and climatic change, France's international commitment, stakes, liabilities of local decision makers, decentralization laws, local plans of fight against greenhouse effect, public information and dialogue); 2 - urbanism and transports (urban displacements, alternatives to individual cars, collective transportation systems, parking, inter-region ...

2003-07-01

357

Measurement of the {beta}-{nu} angular correlation parameter in the decay of {sup 6}He using a Paul trap; Mesure du coefficient de correlation angulaire {beta}-{nu} dans la decroissance de {sup 6}He a l'aide d'un piege de Paul  

Energy Technology Data Exchange (ETDEWEB)

The central topic of this work is the study of the properties and the implementation of a Paul trap used for the measurement of the beta-neutrino angular correlation parameter in the decay of {sup 6}He. This coefficient provides a signature of the nature of the interactions involved in the weak interaction. The value of this coefficient can be deduced from the kinematical distribution of the decay events. An electromagnetic trap is used for the trapping of {sup 6}He{sup +} ions in a small volume. This trap has an open geometry that enables the detection in coincidence of the electron and the recoil ion emitted in the beta decay. A dedicated detection set up is used for the measurement of the electron energy, the ion time of flight and the position of the two particles for each event. A general description of the LPCTrap facility and of its performances is presented and shows that this set up is able to fulfill the proposed measurement. Especially, a comparison is made between the ...

2007-07-15

358

Measurement of the triple gauge-boson couplings {gamma}WW and ZWW in ALEPH and at LEP; Mesure des couplages {gamma}WW et ZWW dans ALEPH et au LEP  

Energy Technology Data Exchange (ETDEWEB)

This document deals with the couplings between the W boson and Z and gamma particles. WWZ and WW{gamma} vertex are predicted by the electroweak theory based on the symmetry group SU(2){sub L}*U(1){sub Y}, their existence is confirmed by the measurement of the production cross-section of W pairs at LEP. The effective values of the couplings are modified by the introduction of standard model particle loops at the vertex level, the impact on the coupling value is assessed to reach 10{sup -3}. These loops can also include beyond-the-standard-model particles, their impact is in the magnitude order of 10{sup -3} for most models. The fully description of these loops requires the values of 14 complex parameters whose measurement will give information about the existence of new particles. Nevertheless the number of events at LEP is not sufficient to measure all the parameters simultaneously. As a consequence the analysis is limited to the 3 most promising parameters: g{sub 1}{sup Z}, ...

2005-03-15

359

Lithium insertion in V{sub 2}O{sub 5}, M{sub x}V{sub 2}O{sub 5} (M = Fe, Cr, Al, La) mixed oxides; Insertion du lithium dans les oxydes mixtes de V{sub 2}O{sub 5}, M{sub x}V{sub 2}O{sub 5} (M = Fe, Cr, Al, La)  

Energy Technology Data Exchange (ETDEWEB)

V{sub 2}O{sub 5} based compounds are interesting low potential materials for rechargeable cathodes of lithium electrochemical generators. However, the ionic conductivity and the reversibility of electrochemical cycling of V{sub 2}O{sub 5} are limited by the possibilities of lithium insertion. This work shows that the doping of vanadium pentoxide by a M{sup 3+} trivalent transition element (M Fe, Al, Cr or La) allows to intercalate a more important amount of lithium and to improve the behaviour of the material during cycling. These materials of M{sub 0.11}V{sub 2}O{sub 5.16} formula are obtained by sol-gel synthesis. the electrochemical study of the Fe compound has shown that it is a mixed oxide with a behaviour similar to V{sub 2}O{sub 5}. The maximum capacity is of about 2 F/mole in the case of Fe, Al and Cr compounds and of about 1.7 F/mole in the case of La. The structural evolution of the Fe compound has been followed during the chemical insertion of Li and the same succession of ...

1996-12-31

360

High air quality and low energy consumption. Performance of hybrid ventilation with CO2-sensors; Hoge luchtkwaliteit en lage energiebesparing. Goede prestaties van hybride ventilatie met CO2-sensoren  

Energy Technology Data Exchange (ETDEWEB)

The school building complex Waterland in The Hague, Netherlands, was built with a hybrid ventilation system. The indoor environment and energy consumption were monitored for one year. Air quality and thermal comfort are of a high quality and the consumption of energy for heating is circa 35% lower than normal. The Waterland project was one of eight demonstration projects, carried out within the framework of the ECBS-Annex 35: Hybrid ventilation in New and retrofitted Office Buildings. ECBS stands for the IEA-program Energy Conservation in Buildings and Community Systems. [Dutch] In ECBCs-annex 35 (ECBS staat voor het IEA-programma Energy Conservation in Buildings and Community Systems) is uitgebreid onderzoek gedaan naar hybride ventilatiesystemen in kantoren en scholen. Dit project heeft geleid tot acht internationale voorbeeldprojecten, waarvan scholencomplex Waterland te Den Haag er een van is. Het scholencomplex is in 2003 opgeleverd met een hybride ventilatiesysteem. Het ...

2005-11-01

361

Fuel management optimization in CANDU reactors cooled with light water; Optimisation de la gestion du combustible dans les reacteurs CANDU refroidis a l'eau lege  

Energy Technology Data Exchange (ETDEWEB)

This research has two main goals. First, we wanted to introduce optimization tools in the diffusion code DONJON, mostly for fuel management. The second objective is more practical. The optimization capabilities are applied to the fuel management problem for different CANDU reactors at refueling equilibrium state. Two kinds of approaches are considered and implemented in this study to solve optimization problems in the code DONJON. The first methods are based on gradients and on the quasi-linear mathematical programming. The method initially developed in the code OPTEX is implemented as a reference approach for the gradient based methods. However, this approach has a major drawback. Indeed, the starting point has to be a feasible point. Then, several approaches have been developed to be more general and not limited by the initial point choice. Among the different methods we developed, two were found to be very efficient: the multi-step method and the mixte method. The second kind of ...

2006-07-01

362

Considering uncertainties in the reservoir interpretation of geophysical data. Application to segmentation; Prise en compte des incertitudes dans l'interpretation reservoir des donnees geophysiques. Application a la segmentation  

Energy Technology Data Exchange (ETDEWEB)

Qualitative interpretation of data of different nature and sources, based on segmentation techniques such as discriminant analysis, is useful to characterize and monitor hydrocarbon reservoirs. In order to make this interpretation more reliable, it is necessary to characterize uncertainties attached to data and then, to propagate them in the interpretation work-flow. In this thesis, uncertainties are represented by intervals, because usually, little is known about input data errors. The uncertainty characterization issue is dealt with specifically for each case study. The uncertainty propagation issue is treated by a new technique, based on interval analysis, which consists in extending to intervals various popular approaches (non parametric, quadratic and linear) to discriminant analysis: Firstly, a learning phase allows calibrating an imprecise classifying model on the basis of pre-interpreted data. If the quality of this model is good enough, it is used to interpret the whole set of ...

2001-10-01

363

A fundamental approach to better understand the lithium insertion mechanisms in electrode materials; Une approche fondamentale pour mieux comprendre les mecanismes d`insertion du lithium dans les materiaux d`electrodes  

Energy Technology Data Exchange (ETDEWEB)

The development of rechargeable lithium batteries with a high mass capacity, made with non-toxic and low cost materials is an important industrial challenge. Morphological and structural modifications occurring in the electrode materials during charge-output cycles should not lower the electrochemical characteristics and the cycling properties of the battery. Thus the structure of electrode materials must be sufficiently deformable and stable to support the constraints linked with lithium intercalation and de-intercalation (ions and electrons absorption/extraction). The aim of this work is to explain some characteristics (mass capacity, ions and electrons mobility, cycling) using the relation between some mechanisms of lithium insertion (sites occupation, lattice reduction mods) and the nature of atoms and chemical bonds (covalence, ionicity). This approach is developed on 2-D models of crystallized and vitreous sulfur compounds (CdI{sub 2} type) with a large inter-sheet distance, and ...

1996-12-31

364

XPS/AES Study of Electrical and Chemical Properties of Pd/SiC Interface  

Science.gov (United States)

Silicon carbide (SiC) based electronic devices are of great importance for applications under the condition of high temperature, high power and high radiation. Schottky diodes of Palladium/SiC are good candidates for hydrogen and hydrocarbon gas sensors at elevated temperature. The detection sensibility of the diodes has been found heavily temperature dependent. In this work, the electrical and chemical properties of Pd/SiC Schottky contacts were studied by XPS and AES at different annealing temperatures. Schottky diodes were made by depositing ultra-thin palladium films onto a silicon carbide substrate. No significant change in the Schottky barrier height of the Pd/SiC contact was found in the temperature range of 300-673K. Palladium diffusion into SiC and the formation of palladium silicides were observed at room temperature and became significant at 300^oC and higher temperature. The mechanism of diffusion and reaction at the Pd/SiC interface will be discussed. The XPS/AES results ...

1997-11-01

365

Vorticity-velocity method for the Graetz problem and the effect of natural convection in a horizontal rectangular channel with uniform wall heat flux  

Energy Technology Data Exchange (ETDEWEB)

Numerical solutions given by a vorticity-velocity method are presented for combined free and forced laminar convection in the thermal entrance region of a horizontal rectangular channel without the assumptions of large Prandtl number and small Grashof number. The channel wall is heated with a uniform wall heat flux. Typical developments of temperature profile, secondary flow, and axial velocity at various axial positions in the entrance region are presented. Local friction factor and Nusselt number variations are shown for Rayleigh numbers Ra = 10{sup 4}, 3 {times} 10{sup 4}, 6 {times} 10{sup 4}, and 10{sup 5} with the Prandtl number as a parameter. The solution for the limiting case of large Prandtl number and small Grashof number obtained from the present study confirms the data of existing literature. It is observed that the large Prandtl number assumption is valid for Pr = 10 when Ra {le} 3 {times} 10{sup 4} but for a larger Prandtl number when the Rayleigh ...

1987-08-01

366

Use of neutron activation analysis for the control of air pollution of Algiers; Utilisation de l'analyse par activation neutronique pour le controle de la pollution de l'air d'Alger  

Energy Technology Data Exchange (ETDEWEB)

The urban zone needs clean air to assure public health. To achieve this goal several filter samples were collected in different sites in Algiers city. Toxic elements such as: Na, Mg, Cl, Sc, Cr, Ti, V, Fe, Co, Cu, Zn, Se, Br, Ag, Sb, Ce, La, Hf, Ta and Hg have been measured in the filters using neutron activation analysis technique. Irradiation of filter samples and standards were carried out in Es-Salem reactor. The experimental procedure and the results are discussed. We noted during this work that the upper limit values for suspended dusts and the high concentrations for some toxic elements found are due to the weather conditions and intense road traffic around collecting sites. (authors)

2010-07-15

367

Tribo-characteristics of self-lubricating ball bearings for the LE-7 liquid hydrogen rocket-turbopump  

Energy Technology Data Exchange (ETDEWEB)

The tribo characteristics of self-lubricating 40-mm-bore ball bearings with a retainer of glass cloth-polytetrafluoroethylene (PTFE) laminate, which has elliptical pockets with a large pocket clearance, were tested under thrust loads at speeds up to 50,000 rpm, 2 million DN, in liquid hydrogen (LH2) and in liquid nitrogen (LN2). During testing, the bearing torque, outer-race temperature, and electric resistance between the inner and outer races were monitored to verify the formation and rupture of a PTFE transfer film. Testing showed that the bearings having the elliptical retainer pockets were superior to the conventional bearings with circular pockets. It was determined that, at the maximum inner race spinning velocity of about 5 m/s, a PTFE transfer film could sustain the maximum Hertz stress, up to about 2000 N/sq mm, in LH2, without severe film rupture resulting in bearing seizure. In LN2, the critical load capacity of PTFE transfer film with bearing seizure was about 2700 N/sq ...

1993-07-01

368

Torsion sur rate baladeuse chez l?enfant: ? propos d?un cas  

British Library Electronic Table of Contents (United Kingdom)

R?sum? La rate baladeuse est une anomalie rare chez l?enfant. Elle est souvent d?crite chez l?adulte, particuli?rement la femme enceinte. Elle est due ? un d?faut de fixit? anatomique de la rate avec les organes de voisinage. Ses manifestations cliniques sont variables, mais la complication la plus redoutable est la survenue d?une torsion du p?dicule spl?nique. Nous rapportons le cas d?une fille de 11 ans qui s?est pr?sent?e avec des douleurs abdominales aigu?s et des vomissements. Les examens radiologiques ont montr? une absence de la vascularisation spl?nique. ? l?exploration chirurgicale, on a d?couvert une torsion du p?dicule spl?nique avec une isch?mie tissulaire avanc?e. La rate ?tait d?pourvue d?attaches ligamentaires. La d?torsion n?a pas permis de sauvegarder la rate, et une spl?n...

2009-01-01

369

The sanitary consequences of chronicle internal contaminations by radionuclides. Advice on the C.E.R.I. report 'study of sanitary effects of exposure to low doses of ionizing radiation to radiation protection purposes ' and I.R.S.N. recommendations; Les consequences sanitaires des contaminations internes chroniques par des radionucleides. Avis sur le rapport CERI 'Etudes des effets sanitaires de l'exposition aux faibles doses de radiations ionisantes a des fins de radioprotection' et recommandations de l'IRSN  

Energy Technology Data Exchange (ETDEWEB)

The report published in 2003 by the European committee on the risk of irradiation (C.E.R.I.) criticizes a part of the ICRP recommendations relative to the internal contaminations.Consequently, I.R.S.N. wishes to supply its own analysis. The present report points the questions linked to the internal contamination and to the difficulties inherent to the risk incurred after chronic exposure.Consequently it does not treat all the problems of the workers and populations radiation protection. (N.C.)

2005-07-01

370

The national plan of fight against greenhouse effect; Le plan national de lutte contre l'effet de serre  

Energy Technology Data Exchange (ETDEWEB)

France has committed herself to keep in 2010 the same levels of greenhouse gas emissions as those of 1990, i.e. 144 millions of tons of carbon equivalent (MtCe). However, taking into account the existing pollution abatement measures and the measurements performed so far, the greenhouse gases level should reach 160 MtCe in 2010. Therefore, the inter-ministry commission on greenhouse effect decided on November 27, 1998 to elaborate a new national plan of fight against greenhouse effect. The elaboration of the new plan has fallen under the responsibility of the inter-ministry mission of greenhouse effect (MIES). The new plan was presented by the prime minister, L. Jospin, on January 19, 2000. This document summarises the content of the new plan: architecture (modalities of elaboration, content), measures for the reduction of greenhouse gas emissions (industry, transportation sector, buildings, agriculture-forestry, wastes valorization, development of renewable energies, refrigerants), new ...

2000-07-01

371

The interstitial fraction of diffusivity of common dopants in Si  

Energy Technology Data Exchange (ETDEWEB)

The relative contributions of interstitials and vacancies to diffusion of a dopant A in silicon are specified by the interstitial fraction of diffusivity, f{sub A}. Accurate knowledge of f{sub A} is required for predictive simulations of Si processing during which the point defect population is perturbed, such as transient enhanced diffusion. While experimental determination of f{sub A} is traditionally based on an underdetermined system of equations, we show here that it is actually possible to derive expressions that give meaningful bounds on f{sub A} without any further assumptions but that of local equilibrium. By employing a pair of dopants under the same point-defect perturbance, and by utilizing perturbances very far from equilibrium, we obtain experimentally f{sub Sb}{le}0.012 and f{sub B}{ge}0.98 at temperatures of {approximately}800{degree}C, which are the strictest bounds reported to date. Our results are in agreement with a theoretical expectation that ...

1997-12-01

372

The electron diffraction: a prime technique to characterize the behaviour of the Li{sub 1-x}C{sub y} / Li{sub x}NiO{sub 2} positive electrode; La diffraction electronique: une technique de choix pour caracteriser le comportement de l`electrode positive Li{sub 1-x}C{sub y} / Li{sub x}NiO{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

LiNiO{sub 2} is one of the most promising material for positive electrodes of lithium-ion batteries. However, its behaviour during cycling and the existence of several phase transitions induced by the lithium ions de-intercalation process has not been explained so far. A transition electron microscopy study of various Li{sub x}NiO{sub 2} (0.25

1996-12-31

373

The behavior of waste rock piles; Le comportement des haldes de steriles  

Energy Technology Data Exchange (ETDEWEB)

Under the auspices of the Mine Environment Neutral Drainage (MEND) Program, several waste rock piles were monitored and characterized. Acid rock drainage (ARD) became a mechanism better understood based on the data acquired during these projects. Numerical simulation was used to better comprehend the quantitative issues associated with the characterization of three specific sites for the purpose of this study. The sites selected were the south waste rock pile of the Doyon Mine in Quebec, the Northdale of the mining district of Ronnenberg in Germany, and the waste rock pile of the Sugar Shack South of the Questa mine in New Mexico. The observed and simulated conditions were very distinct from one mine to another, even if the same mechanisms were involved. The dominant oxygen and heat transfer mechanisms displayed the most varied behavior between the sites. ARD control or site rehabilitation decisions were based on the quantitative understanding gained from the monitoring and led to ...

2000-07-01

374

The ''passivhaus'' standard: from energy efficiency to 'green' building; Le standard ''passivhaus'': de la performance energetique a la construction ''verte''  

Energy Technology Data Exchange (ETDEWEB)

The German voluntary standard 'Passivhaus' (passive house) leads to buildings with practically no energy consumption. The first residential buildings of this type were built in 1998 and the first tertiary buildings in 2000. Such a passive house must fulfill 5 efficiency criteria: annual space heating needs {<=} 15 kWh/m{sup 2}, U{sub v} envelope coefficient lower than 0.15 W/(m{sup 2}.K), U{sub v} of openings lower than 0.8 W/(m{sup 2}.K), airtightness {<=} 0.6 volume/hour, and total energy needs (space heating, hot water, ventilation, lighting and domestic uses) measured at the meter lower than 42 kWh/m{sup 2}.year. This article makes a status of the effective efficiency of existing passive buildings both in the residential and tertiary sectors and presents some possible ways of improvement. (J.S.)

2005-10-01

375

Structure of the triplet of low-lying states in sup 101 Mo  

Energy Technology Data Exchange (ETDEWEB)

The properties of the triplet of low-lying states in {sup 101}Mo have been studied through spectroscopy of the {gamma} radation following thermal neutron capture in {sup 100}Mo and {beta}-decay of {sup 101}Nb and through a measurement of the proton angular distributions in the {sup 100}Mo(d, p) reaction with 14 MeV deuteron energy. The half-lives of the 13.5 keV state and the 57.0 keV 5/2{sup +} state have been measured as 226(7) and 133(7) ns, respectively. These values and the quadrupole/dipole mixing ratios of the 13.5 keV and 43.5 keV transitions yield spin and parity 3/2{sup +} for the 13.5 keV level. The E2 components in the 13.5 (3/2{sup +}->1/2{sup +}) and 43.5 keV (5/2{sup +}->3/2{sup +}) transitions are {le} 8x10{sup -4} and 54(9)%, respectively. The possibility of an additional state near to the 57.0 keV level is discussed. IBFM/PTQM calculations, taking into consideration the transitional character of the {sup 100}Mo boson core, account for the ...

1991-06-01

376

Self-lubricating performance and durability of ball bearings for the LE-7 liquid oxygen rocket-turbopump  

Energy Technology Data Exchange (ETDEWEB)

The durability of ball bearings, 32-mm- and 45-mm-bore, with a retainer or glass cloth-polytetrafluoroethylene (PTFE) laminate was tested under a high radial load at a speed of 20,000 rpm in LOX or LN2. The retainers were characterized as good self-lubricators because the abrasive glass-cloth fiber tips exposed on the retainer were chemicaly etched away with hydrofluoric acid (HF). During testing, the bearing-cartridge-acceleration was monitored to detect bearing damage. Testing in LOX for about 2.2 hr showed that excellent lubricating conditions were obtained for all bearings. Testing in LN2 for about 5.1 hr detected that the fatigue life of the bearing was about the same as the calculated B10 fatigue life. The HF chemical treatment resulted in a reacted fluoride-oxide material which remained in the etched part of the glass fiber. Several chemical products, particularly MgO, CaO, and CaCO3, enhanced adhesion of PTFE transfer film to the counterface, resulting in the formation of a ...

1993-09-01

377

Second mission of North-Cotentin radio-ecology group. The uncertainty calculation; Deuxieme mission du Groupe Radio-ecologie Nord-Cotentin. Le calcul d'incertitude  

Energy Technology Data Exchange (ETDEWEB)

The present study treats only the collective risk of ex-utero leukaemia associated with the routine releases of the nuclear industrial installations of the North Cotentin (0.0009 cases over the considered period) the uncertainty on the contribution to the collective risk of the incidents and the accidents of the nuclear installations (notably the drilling of the pipe of release in sea arisen in 1979-1980 and the fire of the waste silo on January 6. 1981, for the reprocessing plant of La Hague has not been considered. Only 45% of the risk are taken into account by the study. Every calculated value remains very inferior to the number of leukemia cases observed (4 cases observed for two expected cases) and to the risk of radioinduced leukemia any merged exposure sources, that is to say 0.84 cases. It appears thus not very probable that the nuclear installations of the North - Cotentin can explain the tendency to the excess of observed leukaemia. The limits of the study become attached for ...

2003-03-15

378

Safety and exploitation of dams: quality approach for the control of dams in Drire Provence-Alpes-Cote-d'Azur. Dams life. Activities of the control services; Securite et exploitation des barrages: demarche qualite pour le controle des barrages en Drire Provence-Alpes-Cote-d'Azur. La vie des barrages. Activites des services du controle  

Energy Technology Data Exchange (ETDEWEB)

This issue of Barrages newsletter comprises three articles. The first article treats of the quality approach relative to the organization of the inspections of big and medium size dams. It summarizes the improvements of this approach added in 2003 after analysis of the experience feedback. The second article presents the conclusions of the decennial and annual inspections of dams in exploitation. Only the observations requiring a special follow-up are reported. The last article summarizes the activities of the control services for the third quarter of 2003: decennial and annual visits, important facts, administrative instructions, studies, projects and works, organization of services, technical studies etc.. (J.S.)

2003-07-01

379

Radiotherapy quality insurance by individualized in vivo dosimetry: state of the art; Dosimetrie individuelle in vivo pour le controle de qualite en radiotherapie: etat de l'art  

Energy Technology Data Exchange (ETDEWEB)

The quality insurance in radiotherapy in the frame of highly complex technical process as Intensity modulated radiotherapy (I.M.R.T.) needs independent control of the delivered dose to the patient. Actually, up to now, most of the radiotherapy treatments rely only on computed dosimetry through a rather complicated series of linked simulation tool. This dosimetry approach requires also qualified treatment means based on cautious quality insurance procedures. However, erroneous parameters could be difficult to detect and systematical errors could happen leading to radiotherapy accidents. In this context, in vivo dosimetry has a critical role of final control of the delivered dose. As many beam incidences and ports are used for any photon therapy treatment, external control could be very tedious and time consuming. Therefore, innovations are needed for in vivo dosimetry to provide ergonomic and efficient tools for these controls. This paper presents a review of technologies and products ...

2009-06-15

380

Production of a cellulolytic enzyme system in mixed-culture solid-state fermentation of soybean hulls supplemented with wheat bran  

British Library Electronic Table of Contents (United Kingdom)

Solid-state fermentation of soybean hulls supplemented with wheat bran using a co-culture of Trichoderma reesei and Aspergillus oryzae was performed. Three parameters - initial moisture content, incubation temperature, and initial pH - were optimized in culture flasks using response surface methodology. Parameter optimization was carried out with respect to filter paper activity and b-glucosidase activity in the culture. Temperature of 30^oC, pH of 5, and moisture content of 70% were found to be optimum. Optimized parameters were used for laboratory scale-up in static tray fermenters. The maximum filter paper activity of 10.7FPU/g-ds and b-glucosidase of 10.7IU/g-ds were obtained after 96-h incubation period in static tray fermenters in agreement with optimized activities at shake flask le...

2010-01-01

381

Preparation and realization of industrial radiography for the non destructive testing of welds in Nuclear Power Plants: A spatial cognition analysis; Analyse de la preparation et de la realisation Des tirs radiographiques pour le controle non destructif des soudures en Centre Nucleaire de Production d'Electricite sous l'angle de la cognition spatiale  

Energy Technology Data Exchange (ETDEWEB)

Controls of welds by radiographies are an efficient non destructive technique but it can be dangerous if not managed following a strict set of rules. EDF acts to avoid risks via several ways (adapted tools, best practices) and seeks for an integration of the radiographies with respect to the other maintenance operations, in order to raise the ratio of availability of the electricity production unit. This study explores an original analysis of industrial radiography: the influence of the representations of the workplace and its utilizations. This document supports the utilization of some space constraints as explanations of difficulties in the industrial radiography activity. The document proposes innovative points of view coming for on-site observations and from a theoretical background 'cognitive sciences' completed by technical propositions. (author)

2008-07-15

382

Plastic instability in an omega forming Ti-l5% Mo alloy  

International Nuclear Information System (INIS)

The plastic flow behavior of a #beta#-titanium alloy (Ti-15% Mo) was investigated over a wide range of temperatures and strain rates covering those conditions where the #omega#-phase forms dynamically. Portevin-Le Chatelier (PLC) effect was observed in this alloy at temperatures between 575 and 775 K at a strain rate of 1.31 x 10"-"4 s"-"1. The serrated flow behavior of this alloy could be suppressed by rendering the matrix #beta#-phase more stable against the #beta# to #omega# transformation. PLC bands formed in this alloy, studied at different levels of magnification using light, scanning electron and transmission electron microscopy, showed a high density of deformation bands within the macroscopic PLC band. The following mechanism of serrated flow is proposed; the load drop is ascribed to the sudden flow associated with the formation of deformation bands within which #omega#-particles were destroyed while the subsequent load rise results from pinning of ...

383

Photocorrosion of passive films on titanium in sulfuric acid  

Energy Technology Data Exchange (ETDEWEB)

Passive films formed anodically on titanium (Ti) plates in 0.5 M sulfuric acid were corroded in aqueous solutions of H{sub 2}SO{sub 4} in the dark and under illumination of a 250-W mercury lamp. The corrosion depth was determined by calculating the thickness of the oxide layers from interference patterns of reflection spectra in the visible region. Corrosion was observed at pH {le} 3, with the corrosion rate increasing exponentially with decreasing pH and achieving a maximum value at pH {approximately} 1. Photocorrosion generally was quicker than corrosion occurring in the dark in all cases (i.e., open-circuit, short-circuit, bias conditions) and increased under anodic polarization of the oxide electrode together with the photocurrent. Corrosion occurring in the dark decreased very weakly under anodic polarization. Long-term corrosion experiments indicated the initial corrosion rate for a thick anodic oxide was higher than the later rates, probably because of the ...

1995-03-01

384

P431 - Reaction hemolytique differee post-transfusionnelle chez une drepanocytaire  

British Library Electronic Table of Contents (United Kingdom)

Une enfant drepanocytaire homozygote SS de 14 ans (sans deficit en G6PD), non transfusee anterieurement, a une cholecystectomie pour lithiase decouverte a un bilan systematique. L'intervention est encadree de 2 transfusions de concentres erythrocytaires (CGR) phenotypes ABO Rh Kell, compatibilises. Quinze jours apres, elle presente une hemolyse aigue associant fievre, ictere, insuffisance renale tubulaire, hemoglobinurie et anemie profonde (Hb 3,6 g/dL). Les RAI deviennent positives avec, entre autres, un auto anticorps anti D suspecte, le test de Coombs direct est positif de type mixte. L'enfant n'est pas retransfusee, mais recoit 1 mg/kg/j de corticoides IV pendant 10 jours. L'hemoglobine retrouve sa valeur de base (9 g/dL) apres 15 jours. Un antigene RH1(D) partiel de type DAR est ulter...

2010-01-01

385

Metal leaching and acid mine drainage in British Columbia; La lixiviation des metaux et le drainage acide en Colombie-Britannique  

Energy Technology Data Exchange (ETDEWEB)

This poster presentation dealt with a brief overview of the practices in effect in British Columbia related to metal leaching and acid mine drainage. The metals mined in the province include coal, gold, silver, copper, molybdenum, lead, and zinc. Some mines operate under the surface, while others are strip mines, etc. under a variety of climactic conditions and a host of different mining companies, such as Cominco, Placer Dome and Noranda. The primary objective is the prevention of negative environmental impacts on land and in the water. Salmon and other fish need to be protected. A secondary objective is the minimization of impacts on the biota, which requires a detailed study of ecological risks. The solution often lies in soil covering. To illustrate, the author described the situation at Huckleberry Mines Ltd. and the remedial action that was implemented, and discussed the results on the beavers. In conclusion, the author discussed the strategies implemented by the British Columbia ...

2000-07-01

386

Mesenchymal tumors of the pancreas. CT patterns; Tumori mesenchimali del pancreas: aspetti con tomografia computerizzata  

Energy Technology Data Exchange (ETDEWEB)

Purpose of this item is to report the CT patterns of pancreatic mesenchymal lesions and to investigate the capabilities and limitations of this technique in terms of characterization. In selected cases, CT can provide virtually diagnostic information (lipoma and teratoma), or at least highly suggestive findings (NHL, plexiform neurofibroma, lymphangioma). Moreover, knowledge of the variable morphostructural patterns of mesenchymal hisototypes (SCH, Sarcoma etc.) permits to include them in the differential diagnosis of pancreatic masses. [Italian] Scopo di questo rapporto e' descrivere gli aspetti semeiologici dei tumori mesenchimali del pancreas con la TC verificandone le possibilita e i limiti per la caratterizzazione. Pur nella rarita' dei reperti considerati, la TC puo' consentire l'effettiva caratterizzazione in alcuni casi (lipoma, neurofibroma plessiforme, linfangioma) o includere anche istotipi meno comuni (Schwannoma, ...

1999-10-01

387

Lifetimes of superdeformed nuclei in the mass region A {approx}150 with the Eurogam multidetector array; Durees de vie de noyaux superdeformes de la region de masse A {approx}150 mesurees avec le multicompteur Eurogam  

Energy Technology Data Exchange (ETDEWEB)

This work concerns the study of the nuclear superdeformation phenomenon in the rare earth region (A {approx} 150). The superdeformed (SD) states in Gadolinium and Dysprosium isotopes were produced via heavy-ion induced reactions and studied with the (EUROGAM EUROpean GAmma-ray Microscope) gamma multidetector array. Precise level attenuation method (DSAM). From the derived quadrupole moments, we find large differences in deformation between the yrast bands in neighbour nuclei explained in terms of the case of nuclei corresponding to an axis ratio of 2:1, the shell gaps are not fixed at a specific particle number and deformation. Furthermore the present results indicate that the deformations associated with identical bands are different supporting the picture that mass and deformation changes tend to compensate in SB bands with the same moments of inertia. (author). 114 refs.

1996-05-13

388

L'exercice physique d'endurance est plus efficace que l'exercice aerobie pour le controle par la pression arterielle sur 24heures chez des diabetiques de type 2  

British Library Electronic Table of Contents (United Kingdom)

Aim: The study aimed to analyze blood pressure (BP) responses in individuals with type 2 diabetes (T2D) over a 24h period following resistance (RES) and aerobic (AER) exercise. Methods: Ten adults with T2D (age: 55.8+/-7.7 years; weight: 79.4+/-14.0kg; fasting glucose: 133.0+/-36.7mg.dL^-^1) underwent: (1) AER: 20min of cycling at 90% lactate threshold (90% LT); (2) RES: three laps of a circuit of six exercises with eight repetitions at 70% 1-RM and 40s of recovery; and (3) a control session of no exercise. Heart rate (HR), and systolic (SBP), diastolic (DBP), mean arterial (MAP) and pulse (PP) BP, as well as lactataemia (Lac), VO2, respiratory exchange ratio (RER) and rate of perceived exertion (RPE) were measured at rest, during exercise and control (CON) periods, and 60min after interve...

2011-01-01

389

Is intraoperative ultrasound (IOUS) still useful for the detection of liver metastases?  

British Library Electronic Table of Contents (United Kingdom)

SommarioScopo Valutare limpatto clinico negli anni dellecografia intraoperatoria (IOUS) nella identificazione delle metastasi epatiche rispetto alle altre metodiche di imaging. Materiali e metodi risultati delle ecografie intraoperatorie effettuate per lidentificazione delle metastasi epatiche in un periodo compreso tra gli anni 2000 e 2006 sono stati retrospettivamente revisionati e comparati con le metodiche di imaging preoperatorio: Ecografia (US), Tomografia Computerizzata (TC) e/o Risonanza Magnetica (RM). Tutti i casi sono stati patologicamente provati. Sono stati calcolati per anno i casi discordanti in termini di presenza/assenza di lesione focale epatica. Il confronto statistico e stato effettuato con il test di McNemar. Un valore del p<0,05 e stato considerato statisticamente sig...

2009-01-01

390

High frequency individual cylinder estimation for control of diesel engines; Observateur cylindre a cylindre haute frequence pour le controle des moteurs diesel  

Energy Technology Data Exchange (ETDEWEB)

Increasingly stringent pollution regulations have spurred a broad interest in the reduction of engine emissions. Two strategies can be considered: after-treatment or engine emissions reduction. For Diesel engines, after-treatment has a high cost induced by the required technology and implementation issues. In this context, the Highly Premixed Combustion combustion mode (HP C) has emerged as a topic of major interest in recent years. It represents one of the most promising ways for new generation of CI engines using high Exhaust Gas Recirculation (EGR) rates. Experimentation on the test bench brought the proof of significant emission reduction. However, actual vehicle implementation implies frequent transient which fall far beyond steady state experimentation on the test bench. Several key challenges have to be addressed. With this combustion technology; accurate torque balancing at all engine modes is a requirement. Even slight unbalance between the cylinders can have dramatic ...

2006-07-01

391

Helical CT defecography; La defecografia con Tomografia Computerizzata spirale  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work is to investigate the possible role of Helical CT defecography in pelvic floor disorders by comparing the results of the investigations with those of conventional defecography. The series analyzed consisted of 90 patients, namely 62 women and 28 men, ranging in age 24-82 years. They were all submitted to conventional defecography, and 18 questionable cases were also studied with Helical CT defecography. The conventional examination was performed during the 4 standard phases of resting, squeezing, Valsalva and straining; it is used a remote-control unit. The parameters for Helical CT defecography were: 5 mm beam collimation, pitch 2, 120 KV, 250 m As and 18-20 degrees gantry inclination to acquire coronal images of the pelvic floor. The rectal ampulla was distended with a bolus of 300 mL nonionic iodinated contrast agent (dilution: 3g/cc). The patient wore a napkin and was seated on the table, except for those who could not hold the position and were thus ...

1999-11-01

392

Growth and reproduction of nematodes isolated from tap water; Suidosui kara bunrisareta senchurui no zoshoku tokusei  

Energy Technology Data Exchange (ETDEWEB)

This paper elucidates morphological characteristics, reproduction forms and ecological characteristics of Plectus sp. and Rhabditis sp. which are most frequently detected nematodes separated from tap water. The paper also discussed experimentally establishment of cultivating conditions for these nematodes, and behavior and reproduction characteristics of nematodes under widely ranging conditions of temperatures, bacteria concentrations and pH. Plectus sp. grows in hermaphroditic individuals, while Rhabditis sp. grows only in female. An LE culture medium can cultivate nematodes that appear in tap water, and is suitable for subculture of nematodes. Conditions of temperatures from 20{degree}C to 25{degree}C, pH and inoculated concentration of bacteria at 10{sup 8} cell {center_dot} ml{sup -1} are suitable for reproduction of Plectus sp. and Rhabditis sp. Plectus sp. and Rhabditis sp. prefer mild temperatures for reproduction, cannot reproduce below about 5{degree}C, ...

1996-08-10

393

Gastric stromal tumors. CT findings; Tumori stromali gastrici. Aspetti con Tomografia Computerizzata  

Energy Technology Data Exchange (ETDEWEB)

Gastric stromal tumors are an ill-defined group of lesions arising from muscle wall cells and characterized by extremely variable biological patterns. Thanks to modern immunohistochemical and ultrastructural techniques, four main classes of these lesions have been identified, namely: (1) tumors with differentiation toward smooth muscle cells; (2) tumors with differentiation toward neural elements; (3) tumors with differentiation toward neural elements; (3) tumors with dual differentiation toward either cell type. It was investigated the yield of CT in diagnosing and characterizing gastric stromal tumors. It was retrospectively reviewed the CT findings of 38 patients (15 men and 23 women; mean age 51 years) with pathologically proven gastric stromal tumors, namely 31 of myoid origin, 4 of neural origin, 2 with both muscle and neural differentiation, 1 lacking differentiation with either cell type. The myoid tumors involved gastric fundus in 9/13 and 5/7 benign lesions and lesions with ...

2000-02-01

394

Gamma Ray Bursts from the First Stars Neutrino Signals  

CERN Document Server

If the first (PopIII) stars were very massive, their final fate is to collapse into very massive black holes. Once a proto-black hole has formed into the stellar core, accretion continues through a disk. It is widely accepted, although not confirmed, that magnetic fields drive an energetic jet which produces a burst of TeV neutrinos by photon-meson interaction, and eventually breaks out of the stellar envelope appearing as a Gamma Ray Burst (GRB). Based on recent numerical simulations and neutrino emission models, we predict the expected neutrino diffuse flux from these PopIII GRBs and compare it with the capabilities of present and planned detectors as AMANDA and IceCube. If beamed into 1% of the sky, we find that the rate of PopIII GRBs is $\\le 4 \\times 10^6$ yr$^{-1}$. High energy neutrinos from PopIII GRBs could dominate the overall flux in two energy bands [$10^4 - 10^5$] GeV and [$10^5 - 10^6$] GeV of neutrino telescopes. The enhanced sensitivities of ...

2002-01-01

395

Evaluation of a convenient method of assessing rodent visual function in safety pharmacology studies: Effects of sodium iodate on visual acuity and retinal morphology in albino and pigmented rats and mice  

British Library Electronic Table of Contents (United Kingdom)

Introduction: We have evaluated the ability of a semi-automated, optomotor reflex method to assess drug-induced visual dysfunction, in albino and pigmented rats and mice. Methods: Male Han Wistar (HW) and Long Evans (LE) rats and mice (CD-1 and C57BL/6) were tested in a chamber formed by 4 computer monitors displaying a rotating vertical grating, to elicit head-tracking movements. The highest visible grating frequency was taken as the threshold of visual acuity, in cycles per degree (c/d). Animals received an intravenous infusion of either sodium iodate (50mg/kg) or 0.9% w/v NaCl (aq). They were tested 2h later, then re-tested daily for a further 3days. The time course of the effect was assessed in HW rats over a 6-week period, including electron microscopy, and immunohistochemical analysi...

2011-01-01

396

Enzymatic mechanism in low chloride media: influence of glucose oxidase on the electrochemical behaviour of AISI 316L stainless steel; Mecanisme enzymatique en milieux faiblement chlorures: influence de la glucose oxydase sur le comportement electrochimique de l'acier inoxydable AISI 316L  

Energy Technology Data Exchange (ETDEWEB)

The open circuit potential (OCP) of stainless steels immersed in natural waters generally increases with time. This phenomenon is strongly linked to the formation of a bio-film on the surface. Several studies have proved that the bio-film modifies the reaction of reduction of dissolved oxygen and that it acts mainly on the cathodic processes. One of the hypotheses explaining the action of the bio-film involves certain bacteria which use dissolved oxygen and extracellular enzymes to produce reactive oxygen species. Among this kind of metabolites is hydrogen peroxide H{sub 2}O{sub 2}. This compound interacts with the passive layer of stainless steels and affects their electrochemical behaviour, even when the chloride concentration is low. The aim of this work is to study the influence of an enzymatic reaction (of the oxidoreductase type) on anodic and cathodic processes on AISI 316L stainless steel. Experiments are carried out in two artificial electrolytes simulating natural fresh ...

2006-07-01

397

Effects of the structural nature of the anionic additives on the rheological behavior of bentonite suspensions; Effets de la nature structurelle des additifs anioniques sur le comportement rheologique de suspensions de bentonite  

Energy Technology Data Exchange (ETDEWEB)

Different experimental measurements (Theology, granulometry, XRD) were carried out in order to study the main properties of bentonite suspensions in presence of anionic additives at different concentrations. These additives are: Sodium Dodecyl Sulfate (SDS) as surfactant, a flexible polymer (Sodium Carboxy Methyl Cellulose, CMC) and a semi-rigid polymer (Xanthan gum). It has been shown that the structural nature of anionic additive influences directly the mixtures viscoelastic and flow behavior. The steric effect of the surfactant modifies the Face-Edge interactions and yields changes of the mixtures rheological behavior at low deformation rates. Polymers act by coating each clay particle and prevent their agglomeration. Therefore, bentonite has no direct effect on the rheological behavior of the mixtures: the additives are responsible for the mechanisms of de-structuration and structure reorganization as well as the mixtures viscous and viscoelastic behavior. (author)

2005-07-01

398

Diagnostic imaging and interventional radiology of the amoebic liver abscess. Personal experience; Diagnostica per immagini e radiologia interventistica degli ascessi amebici del fegato: esperienza personale  

Energy Technology Data Exchange (ETDEWEB)

The diagnostic imaging findings in hepatic amoebiasis and the capabilities of percutaneous drainage have already been described but some debate is open on both diagnosis and treatment. It is reported the experience with the ultrasound (US) and Computed Tomography (CT) studies of the hepatic amoebic abscess and its management. [Italian] I reperti con diagnostica per immagini nell'amebiasi epatica e le possibilita' del drenaggio percutaneo sono stati gia' illustrati; esistono tuttavia controversie sul piano sia diagnostico che terapeutico. Obiettivo di questo lavoro e' quello di riportare l'esperienza personale nella diagnostica con ecografia e tomografia computerizzata (TC) e nel trattamento degli ascessi amebici del fegato.

1999-10-01

399

Determination of seepage path in a river levee; Sulla determinazione della linea d'infiltrazione al'interno di un argine fluviale  

Energy Technology Data Exchange (ETDEWEB)

After a short review of the classical simplified expressions able to evaluate the seepage path in the core of a river levee, this paper first discusses the results obtained assuming the Dupuit approximation. Dimensionless nomographs are then showed, obtained by means of numerical integration of the seepage equations, These nomographs allow a quick levee design to be developed, after the definition of flood hydrography, seepage and embankment characteristics. [Italian] Dopo un sintetico richiamo di alcune classiche formulazioni semplificate per la determinazione dell'andamento della linea di infiltrazioner in un rilevato arginale, nell'articolo vengono presentati e discussi i risultati conseguiti prima assumendo la sola ipotesi di Dupuit e, successivamente, risolvendo l'equazione completa del moto di filtrazione. In particolare, vengono forniti abachi adimensionali che consentono, una volta fissate le caratteristiche ...

1999-10-01

400

Degradation of recalcitrant organic pollutants by mixed catalysts; Degradazione di inquinanti organici recalcitranti mediante catalizzatori misti  

Energy Technology Data Exchange (ETDEWEB)

The photodegradation of two well known recalcitrant compounds was studied. At this aim, a photosystem constituted by titanium dioxide and polyaniline, both immobilised in a PVC membrane, and a sunlight simulating irradiation source was used. The optimisation of the experimental conditions, ph, ionic strength and, when operating on soils, humic acid concentration, allowed the photodegradation of Paraquat at a nearly 100% extent, while, an oxidation by hypochlorite was needed to degrade cyanuric acid. [Italian] E' stata studiata la fotodegradazione di due composti notoriamente recalcitranti a questo tipo di rimozione. Con un sistema fotocatalitico costituito da biossido di titanio e polianilina immobilizzati in una membrana di PVC ed operando con luce solare simulata e' possibile, ottimizzando le condizioni sperimentali di pH, forza ionica e - operando su terreno - concentrazione di acidi umici, ottenere la degradazione del paraquat fino a valori ...

2001-05-01

401

Cosmic gamma ray detection and discovery potential with the AMS-2 spectrometer; Detection de rayons {gamma} cosmiques et potentiel de decouvertes avec le spectrometre AMS-02  

Energy Technology Data Exchange (ETDEWEB)

Yet designed to measure charged component of the cosmic rays, the foreseen Alpha Magnetic Spectrometer (AMS-02) could also release {gamma}-ray studies, in the energy range from GeV to TeV, using the tracker system, for {gamma}-rays converted in e{sup +}e{sup -} pair, and the electromagnetic calorimeter. In the first part of the thesis are described the calibrations and the performances of the engineering model of the calorimeter, obtained from the analysis of data taken during a test-beam performed at CERN in July 2002. In the second part of the thesis, the AMS-02 discovery potential for {gamma}-astrophysics is presented. While exposure maps of the {gamma}--sky are computed for one year of data taking with the {gamma}--detectors, the acceptance of the calorimeter is obtained from Monte-Carlo simulations. The AMS-02 potential is then estimated for signals from the Vela pulsar and for some supersymmetric signals from the Galactic Center. (author)

2004-12-15

402

Cd speciation in biomass fly ash particles after size separation by centrifugal SPLITT  

Energy Technology Data Exchange (ETDEWEB)

The finest particle size fractions ({le} 25 {mu}m) in four fly ash samples from fluidised bed combustion of three biomass based fuels and a municipal solid waste fuel were size separated using a centrifugal SPLITT fractionation cell. The ashes were separated into different size fractions and the cadmium concentration, partition and speciation in each separated fraction were then investigated in relation to their possible leaching. The fractionation was evaluated by environmental scanning electron microscopy, which also provided indications of the associations between Cd and other main elements on the particles through the use of X-ray fluorescence mapping. The total concentration of Cd in each fraction was determined by AAS analysis which showed different dependence on the ash particle size in the case of biomass or waste fuels. In addition, the speciation of Cd in each fraction, investigated by sequential chemical extractions and X-ray powder diffraction analysis, ...

2002-08-01

403

Osteoporosis and prevention. Assessment of mineral density, geometry and biomechanics of bone by means of peripheral quantitative Computed Tomography (pQCT) in premenopausal women assuming phytoestrogens; Osteoporosi e fitoestrogeni: valutazione della densita' minerale ossea mediante tomografia computerizzata quantitativa periferica nelle donne lattoovovegetariane nella premenopausa  

Energy Technology Data Exchange (ETDEWEB)

Aim of the work was to describe the noninvasive assessment of bone mineral density, geometrical and biochemical properties in premenopausal women with dietary intake of phytoestrogens and comparison of these parameters with those of age-matched female subjects with Mediterranean dietary intake lacking in these substances. Volumetric cortical, trabecular and total mineral density and bone geometrical properties were evaluated with peripheral quantitative computed tomography (pQCT) at the distal radius of the non dominant forearm. pQCT showed higher bone mineral density (total and trabecular) and SSI values in premenopausal with dietary intake of phytoestrogens. Despite the lack of statistical significance, these preliminary results, should further support the few literature findings about the potential role of phytoestrogens consumption in preventing trabecular bone loss. However, further studies are warranted to evaluate definitively postmenopausal osteoporosis. [Italian] Scopo del ...

2000-04-01

404

Integration of SPECT with CT to plan radiotherapy fields. n application to conformal irradiation for lung carcinoma; Integrazione delle immagini della Tomografia Computerizzata con emissione di fotone singolo in un sistema commerciale per l'elaborazione dei piani di radioterapia. Applicazione all'irradiazione conformazionale del carcinoma polmonare  

Energy Technology Data Exchange (ETDEWEB)

Single photon emission computed tomography (SPECT) of lung perfusions permits to map functioning lung parenchyma with higher sensitivity than CT. Delivering higher radiations doses it used to increase local control in lung carcinoma; this strategy is based on radiobiological and clinical studies. Lung parenchyma is a dose-limiting tissue in patients irradiated for lung cancer. Functional mapping based on SPECT and CT findings permits to design radiation beams such as to minimize irradiation of functioning lung. [Italian] L'integrazione delle immagini diagnostiche aventi diverso contenuto informativo anatomico-funzionale puo' essere utilizzata nella radioterapia per migliorare le procedure diagnostiche e ottimizzare la geometria dell'irraggiamento. I sistemi per l'elaborazione di piani di radioterapia oggi in uso sono direttamente interfacciati con gli apparecchi di Tomografia Computerizzata (TC) e l'impiego di immagini ...

1999-04-01

405

Use of the WNR spallation neutron source at LAMPF to determine the absolute efficiency of a neutron scintillation detector  

Energy Technology Data Exchange (ETDEWEB)

Prompt fission neutron spectrum measurements at the University of Massachusetts Lowell 5.5 MV Van de Graaff accelerator laboratory require that the neutron detector efficiency be well known over a neutron energy range of 100 keV to 20 MeV. The efficiency of the detector, has been determined for energies greater than 5.0 MeV using the Weapons Neutron Research (WNR) white neutron source at the Los Alamos Meson Physics Facility (LAMPF) in a pulsed beam, time-of-flight (TOF) experiment. Carbon matched polyethylene and graphite scatterers were used to obtain a hydrogen spectrum. The detector efficiency was determined using the well known H(n,n) scattering cross section. Results are compared to the detector efficiency calculation program SCINFUL available from the Radiation Shielding Information Center at Oak Ridge National Laboratory.

1994-06-01

406

Use of genetic parameters in coal classification  

Science.gov (United States)

The extensive reserves of mined coal types, their great variety and the complexity of the composition and properties, as well as their important role as an energy fuel and industrial feedstock, cause one to give special attention to their classification. Of course, one of the principal fields of technological processing of coal is coking. In addition to the production of blast furnace coke, in the future specialized plants will be developed for production of coke and other carbonized materials for non-blast-furnace processes (electrothermal processes, production of calcium carbide, ferroalloys, zinc, yellow phosphorus, copper, etc.). One important area is new nonfuel uses, including a number of processes for processing of coal feedstocks to obtain a wide range of carbonaceous materials (coal-graphite products, carbon black, adsorbents, etc.), liquid fuels, and chemical products. In choosing a given area of coal utilization a determining factor is the ...

1984-01-01

407

The thermodynamic characteristics of retention of tricyclo[5.2.1.02,6]decane isomer molecules on different sorbents in gas chromatography  

Science.gov (United States)

The thermodynamic characteristics of sorption of the isomeric tricyclo[5.2.1.02.6]decane (tetrahydrodicyclopentadiene, TDCPD) molecules were for the first time determined experimentally and by molecular statistical methods under the conditions of gas-adsorption chromatography on graphitized thermal carbon black and gas-liquid chromatography on stationary liquid phases of different polarities (Apiezon L and Carbowax 20M). The effects of the chemical nature of sorbents on the retention of the TDCPD isomers are considered. A procedure for calculating the thermodynamic characteristics of adsorption of molecules with a complex structure is suggested within the framework of the atom-atom approximation of the semiempirical molecular statistical theory of adsorption for the example of isostructural norbornane molecules. The procedure involves simultaneous variation of geometric parameters and refinement of the parameters that determine the special features of the ...

2008-07-01

408

The special features of equilibrium adsorption of argon on homogeneous and inhomogeneous surfaces  

Science.gov (United States)

Comparative patterns of equilibrium adsorption of argon on the surface of graphitized thermal carbon black (GCB) and the inhomogeneous surfaces of nongraphitized carbon black and silica at 77 and 87.3 K were considered. It was shown that argon acquires the properties of a special phase with a layered structure and exhibits two-dimensional phase transitions with the formation of crystal-like layers near the homogeneous surface of GCB even at a temperature exceeding the triple point. However, already at a distance of three-four molecular diameters from the surface, adsorbed argon behaves as a bulk phase in a weak external field. The defect surface of nongraphitized carbon black and the amorphous surface structure of silica destroy the longrange order of adsorbed argon and lower its solidification temperature. Therefore, argon adsorbed at a temperature of 77 K, i.e., below the triple point, exhibits the properties of a supercooled liquid. The applicability of density ...

2008-12-01

409

Spherical nanostructured Si/C composite prepared by spray drying technique for lithium ion batteries anode  

International Nuclear Information System (INIS)

Spherical nanostructured Si/C composite was prepared by spray drying technique, followed by heat treatment, in which nanosized silicon and fine graphite particles were homogeneously embedded in carbon matrix pyrolyzed by phenol formaldehyde resin. Cyclic voltammetry tests showed two pairs of redox peaks corresponding to lithiation and delithiation of Si/C composite. The Si/C composite exhibited a reversible capacity of 635 mAh g"-"1 and good cycle performance used in lithium ion batteries. To improve cycle performance of this Si/C composite further, the carbon-coated Si/C composite was synthesized by the second spray drying and heat treatment processing. The cycle performance of carbon-coated Si/C composite was improved significantly, which was attributed to the formation of stable SEI passivation layers on the outer surface of carbon shell which protected the bared silicon from exposing to electrolyte directly.

2006-07-15

410

Replacement of nickel sealing rings by expanded graphite sealing rings -upgrading of SG primary collector flange connection  

Energy Technology Data Exchange (ETDEWEB)

One of the most loaded parts of a steam generator of VVER 440 MW type are the bolts and thread holes of the primary collector cover sealing set. The strength calculations and tensometric measurings performed during operation proved the high degree of a load on the bolts. The conditions of the stress limitation are not met in some cases according to the pertinent standards. The untightnesses at nickel rings occurred during putting the units of Jaslovske Bohunice and Dukovany nuclear power stations into operation. With regard to improve the reliability, the producer has taken measures to improve the quality of the rings and users have introduced more strict regulations for bolts tightening. Due to these measures the high reliability of the set has been obtained from point of view of the tightness, but substantial reduction of bolts and holes threads loading have not been obtained. Several years operation experience proved relatively low service of bolts, damage of thread holes and ...

1997-12-31

411

Properties of carbon films prepared by magnetron sputtering of woodceramics; Uddo seramikkusu kara seikeishita magunetoronsu pattaringu ni yoru tansomaku no tokusei  

Energy Technology Data Exchange (ETDEWEB)

Highly resistant, high-transmittance woodceramic thin films were prepared using rf magnetron sputtering of a woodceramic disk in argon plasma. A film series was deposited based on substrate temperature, which was varied from 50 to 500 degree C. The film's electrical and optical properties depended on substrate temperature. Films deposited below 300 degree C were insulative, {rho}>10{sup 10} {omega} {center_dot} cm. Films deposited at 50 degree C had a density of 1.9-2.2 g/cm{sup 3} comparable to that of single crystal graphite. Below 200 degree C, films had higher transmittance than typical DLC films in the visible and infrared region. Infrared C-H absorption spectrum was observed by Ft-IR and there exist two types of bonding corresponding to sp{sup 2} or SP{sup 3}. (author)

1999-08-01

412

Pre-oxidized and nitrided stainless steel alloy foil for proton exchange membrane fuel cell bipolar plates. Part 2: Single-cell fuel cell evaluation of stamped plates  

British Library Electronic Table of Contents (United Kingdom)

Thermal (gas) nitridation of stainless steel alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant nitride containing surface layers (Cr2N, CrN, TiN, V2N, VN, etc.) of interest for fuel cells, batteries, and sensors. This paper presents results of proton exchange membrane (PEM) single-cell fuel cell studies of stamped and pre-oxidized/nitrided developmental Fe-20Cr-4V weight percent (wt.%) and commercial type 2205 stainless steel alloy foils. The single-cell fuel cell behavior of the stamped and pre-oxidized/nitrided material was compared to as-stamped (no surface treatment) 904L, 2205, and Fe-20Cr-4V stainless steel alloy foils and machined graphite of similar flow field design. The best fuel cell behavior among the alloys was exhibited...

2010-01-01

413

Polyamide/Polystyrene blend compatibilisation by montmorillonite nanoclay and its effect on macroporosity of gas diffusion layers for proton exchange membrane fuel cells  

Energy Technology Data Exchange (ETDEWEB)

This work deals with a new route to modify polymer blend morphology in order to improve the porosity of gas diffusion layers (GDLs) for proton exchange membrane fuel cells (PEMFCs). First, electrically conductive polymer-based blends were carefully formulated using a twin-screw extrusion process. Blend electrical conductivity was ensured by the addition of high specific surface area carbon black and synthetic graphite flakes. Final GDL porosity, in particular its macroporosity, was generated by melt blending polyamide 11 (PA11) matrix with polystyrene (PS) followed by PS extraction with tetrahydrofuran (THF) solvent at room temperature. In order to improve GDL porosity by the optimisation of PS dispersion in the PA11 matrix, PA11/PS blends were compatibilised by the addition of 2 wt.-% of clay. It was observed that both macroporosity and pore size distribution were beneficially modified after blend compatibilisation. Final GDL conductivity of about 1.25 S cm{sup ...

2007-12-15

414

Performances of a lithium-carbon ``lithium ion``battery for electric powered vehicle; Performances d`un accumulateur au lithium-carbone ``Lithium Ion`` pour vehicule electrique  

Energy Technology Data Exchange (ETDEWEB)

The lithium battery, also called `lithium-carbon` or `lithium ion`, is today the most promising candidate that can reach the expected minimum traction performances of electric powered vehicles. Thanks to a more than 20 years experience on lithium generators and to a specific research program on lithium batteries, the SAFT company has developed a 100 Ah electrochemical system, and full-scale prototypes have been manufactured for this application. These prototypes use the Li{sub x}NiO{sub 2} lithiated graphite electrochemical pair and were tested in terms of their electrical performances. Energy characteristics of 125 Wh/kg and 265 Wh/dm{sup 3} could be obtained. The possibility of supplying a power greater than 200 W/kg, even at low temperature (-10 deg. C) has been demonstrated with these elements. A full battery set of about 20 kWh was built and its evaluation is in progress. It comprises the electronic control systems for the optimum power management during ...

1996-12-31

415

Neutron capture therapy beam on the LVR-15 reactor  

Energy Technology Data Exchange (ETDEWEB)

Several configurations of moderating and shielding materials have been designed and measured on the LVR-15 reactor for boron neutron capture therapy (BNCT) purposes. To determine the neutron and gamma ray space-energy distributions in the cylindrical geometry, the two-dimensional code DOT with the coupled neutron-gamma data library DLC-36 was used. The experimental verification of the beam parameters was performed in the LVR-15 reactor thermal column empty space with layers of graphite, aluminium, alumina, lead and bismuth. Attention was paid to establishing techniques and instrumentation for monitoring the neutron and gamma ray dose and beam quality. The thermal and epithermal flux densities were measured by activation foils, the neutron spectrum was determined with a Bonner spectrometer and gamma ray background with a scintillation spectrometer. The distribution of thermal neutrons in the human head phantom was mapped with a small semiconductor detector (Si[sup ...

1992-01-01

416

Neutron capture therapy beam on the LVR-15 reactor  

International Nuclear Information System (INIS)

Several configurations of moderating and shielding materials have been designed and measured on the LVR-15 reactor for boron neutron capture therapy (BNCT) purposes. To determine the neutron and gamma ray space-energy distributions in the cylindrical geometry, the two-dimensional code DOT with the coupled neutron-gamma data library DLC-36 was used. The experimental verification of the beam parameters was performed in the LVR-15 reactor thermal column empty space with layers of graphite, aluminium, alumina, lead and bismuth. Attention was paid to establishing techniques and instrumentation for monitoring the neutron and gamma ray dose and beam quality. The thermal and epithermal flux densities were measured by activation foils, the neutron spectrum was determined with a Bonner spectrometer and gamma ray background with a scintillation spectrometer. The distribution of thermal neutrons in the human head phantom was mapped with a small semiconductor detector (Si"6Li). ...

1991-10-01

417

Isotope exchange reaction between tritiated water and hydrogen on SiC  

Energy Technology Data Exchange (ETDEWEB)

SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10{sup 6} Bq/cm{sup 2}. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method applying the serial reactor model. The reaction rate was ...

2003-11-15

418

Isotope exchange reaction between tritiated water and hydrogen on SiC  

International Nuclear Information System (INIS)

SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method applying the serial reactor model. The reaction rate was observed to be ...

2003-11-15

419

Investigation of #alpha#-sialon formation by high temperature X-ray diffraction  

International Nuclear Information System (INIS)

A technique for following sialon formation in situ by high temperature X-ray diffraction (HT-XRD) was developed. The composition chosen for study was an yttrium #alpha#-sialon with x=0.4. Powder compacts containing silicon nitride, aluminum nitride and yttria powders were pre-sintered at 1350 C and then studied by HT-XRD at temperatures between 1450 and 1580 C and nitrogen pressures of 0.11 MPa. The furnace was made from graphite coated with porous silicon nitride/silicon carbide. The coating prevented silicon carbide formation in the sample up to 1600 C. X-ray diffraction results show the formation of a Y_1_0Al_2Si_3O_1_8N_4 phase at 1350 C, which dissolved to form #alpha#-sialon and other phases at higher temperatures. The amounts of #alpha#-sialon formed are similar to the amounts reported by other authors. An empirical method was used for the calculation of activation energy for the silicon nitride to #alpha#-sialon transformation and resulted in a value of 330 ...

1993-10-04

420

Free electron laser experiments using a long pulse induction linac  

International Nuclear Information System (INIS)

The NRL Long Pulse Induction Linac is being employed in a Free Electron Laser (FEL) experiment. The authors present results of beam transport and focusing experiments as well as measurements of the output radiation generated by various magnetic wigglers. The electron gun of the accelerator presently has a 17-cmdiam. cold cathode which is located in a nearly zero magnetic field (B /SUB z/ less than or equal to 5 G). The gun voltage is flat to within approx. = + or - 5% for 1.5 #mu#sec with this graphite brush cathode. The beam is focused by a series of solenoidal coils as it propagates through the 4-m-long accelerator."2 A solenoidal field which can be varied from 1-10 kG confines the beam in the FEL interaction region. Previous experiments were limited by poor beam transport, focusing, and matching into the relatively large solenoidal field in the FEL region. By smoothing the axial magnetic field profile in the accelerator and making a more adiabatic transition ...

421

Feasibility study of a new zinc-air battery concept using flowing alkaline electrolyte  

Energy Technology Data Exchange (ETDEWEB)

Proof-of-principle experiments are reported for a new concept in electrically rechargeable zinc-air battery. The zinc electrode is a porous flow-thru type using a copper foam metal substrate with zinc deposition onto the foam metal from concentrated zincate electrolyte (as used in zinc-slurry type batteries). The bifunctional air electrode employs low-cost materials, being fabricated entirely from carbon-based precursors and small amounts of nickel and/or cobalt oxide. Corrosion measurements on the graphite materials in the air electrode indicate sufficient corrosion resistance for 8000 h life on charge. A prototype single cell was constructed having 1.5 Ah capacity producing 1.2 V discharge -2.0 charge at the three hour rate and has produced stable voltages for more than 150 cycles. Based on the 1.5 Ah prototype characteristics, design calculations for a 32 kWh battery project an energy density of about 110 Wh/kg, peak power density of 140 W/kg, electrical ...

1986-04-01

422

Evaluation of Core Bypass Flow in the Prismatic VHTR with a Multi-block Experiment  

International Nuclear Information System (INIS)

The core of Prismatic Modular Reactor (PMR) consists of assemblies of hexagonal graphite fuel and reflector elements. The core bypass flow of Very High Temperature Reactor (VHTR) is defined as the core flow that does not pass through the coolant channels but passes through the bypass gap between fuel elements. The increase in bypass flow makes the decrease in effective coolant flow. Since the core bypass flow has a negative impact on safety and efficiency of VHTR, core bypass phenomena have to be investigated to improve the core thermal margin of VHTR. For this purpose, the international project, I-NERI project, has been carried out since 2008. I-NERI project is collaborative project that KAERI and SNU of Korea side and INL, ANL and TAMU of U.S side are involved. In order to evaluate the core bypass flow, the multicolumn and multi-layer experimental facility is designed by SNU. In this experiment, the effect of cross-flow and local variation of bypass gap on the ...

2010-10-01

423

Ellipsometry studies on nitrogenated diamond-like carbon (DLC) thin films produced by RF magnetron sputtering  

International Nuclear Information System (INIS)

Nitrogen doped Diamond-like carbon thin films were deposited on n-Si and SiO_2 substrates by rf magnetron sputtering using pure graphite (99.999%) as the target material and mixtures of Ar, N_2 and H_2 for plasma generation. The dependence of structural and optical properties on nitrogen content was investigated using XPS, Raman spectroscopy, FT-IR spectroscopy, and Ellipsometry studies. It was found that as the nitrogen content was increased in the plasma, sp"2 bonding favored. Also it was observed that oxygen contamination increased with nitrogen content. Typical C-H stretching modes connected with diamond-like carbon could be seen in FT-IR spectra. The I_D and I_G bands were well defined and it was observed that as nitrogen content increased I_G band was enhanced. Ellipsometry studies revealed that the optical constants like refractive index (n) and extinction co-efficient (k) increased with increase in nitrogen content as well as substrate temperature. (author)

2003-03-01

424

Electricity generation and microbial community changes in microbial fuel cells packed with different anodic materials.  

Science.gov (United States)

Four materials, carbon felt cube (CFC), granular graphite (GG), granular activated carbon (GAC) and granular semicoke (GS) were tested as packed anodic materials to seek a potentially practical material for microbial fuel cells (MFCs). The microbial community and its correlation with the electricity generation performance of MFCs were explored. The maximum power density was found in GAC, followed by CFC, GG and GS. In GAC and CFC packed MFCs, Geobacter was the dominating genus, while Azospira was the most populous group in GG. Results further indicated that GAC was the most favorable for Geobacter adherence and growth, and the maximum power densities had positive correlation with the total biomass and the relative abundance of Geobacter, but without apparent correlation with the microbial diversity. Due to the low content of Geobacter in GS, power generated in this system may be attributed to other microorganisms such as Synergistes, Bacteroidetes and ...

2011-09-20

425

Effects of the insertion of a thick sp"2 buffer layer on the adhesion of cBN-rich film  

International Nuclear Information System (INIS)

A method was proposed and examined to deposit thick cubic boron nitride (cBN)-rich layer of good adhesion to silicon substrate. The method combined (i) the insertion of a thick sp"2 buffer layer, and (ii) the use of an appropriate assist ion beam energy for the growth of the cBN-rich top layer. The sp"2-bonded boron nitride buffer layer was deposited under irradiation of ions with energies in the range of 200-360 eV. The buffer layer was found to contain curled graphitic basal planes, and so was supposed to be relatively deformable, and facilitate the relaxation of stresses in the cBN-rich top layer. The ion assist introduced during the growth of the cBN-rich layer was supposed to both create and annihilate defects, and so resulted in the generation and relaxation of internal stresses. Results showed that the insertion of a 492 nm sp"2 buffer layer, and the use of a beam energy of 450 eV for assisting the growth of the top layer can produce a 643-nm-thick cBN-rich ...

2004-05-01

426

Effect of substrate temperature on structural properties and corrosion resistance of carbon thin films used as bipolar plates in polymer electrolyte membrane fuel cells  

International Nuclear Information System (INIS)

In this work, the effects of substrate temperature that was changed from 100 to 500 "oC on the structural, chemical and electrical properties of carbon films, prepared by direct current magnetron sputtering technique, on 316L stainless steel as bipolar plate had been investigated. Raman spectroscopy and scanning electron microscopy (SEM) were performed to study the structure and the morphology of the deposited films, respectively. The corrosion resistance and the electrical resistivity were carried out by using corrosion tests and four point-probe technique. The results show that the carbon films change the structure from amorphous to graphite-like by increasing temperatures. At the temperatures higher than 300 "oC, the holes and porosities are formed on the film indicating a decrease of film quality. According to our results, corrosion resistance and electrical properties are depended strongly on the substrate temperature.

2010-07-23

427

Effect of burn-off on physical and chemical properties of coal char; Gas ka shinko ni tomonau sekitan char no tokusei henka  

Energy Technology Data Exchange (ETDEWEB)

For high-efficiency coal gasification, investigations were given on effect of coal chars with different conversion rates on coal gasification reactivity. In coal gasification, reactivity of char after pyrolysis governs the efficiency. The reference char conversion in CO2 gasification of coal (weight loss) changes linearly in the initial stage of the reaction, but the reactivity declines as the end point is approached. Char surface area is as large as 400 m{sup 2}/g in the initial stage with the conversion at 20%, but it decreases in the final stage. This phenomenon relates closely with changes in pore size and crystalline structure. Change in the Raman value R which shows incompleteness of char graphite structure and amorphous carbon ratio suggests that an active portion with high reactivity is oxidized preferentially, and a portion with low reactivity remains finally. Minerals in coal are known to accelerate the gasification. However, their catalytic effect is ...

1996-10-28

428

Design experience of the JRR-2 BNCT facility in JAERI  

Energy Technology Data Exchange (ETDEWEB)

The thermal neutron column of the JRR-2 reactor was remodelled in order to install a medical irradiation facility. The design experience and the cource of this remodelling are presented. At first, the thermal neutron flux was lower than expected, and the expected radiation condition was achieved by the following improvements: (1) removal of graphite from the thermal neutron column to increase the neutron flux, (2) twice increase of bismuth shielding and the shift of its position to improve the shielding effect against gamma ray, (3) application of B{sub 4}C rubber on the both surfaces of the shielding door to suppress the secondary gamma ray generation from the structural materials, (4) LiF tiles are applied on the inner face of the neutron beam exit hole to suppress the secondary gamma ray from the beam exit, and (5) installment a cone-shape polyethylene collimator to relieve the decay of thermal neutron. After the improvements, medical irradiation treatments have ...

1994-06-01

429

Decontamination of a gas cooler using foams containing chemical reagents  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with an industrial application of the foam decontamination process applied to large volume components. The work presented below was achieved within the context of a CEC contract. The objective of this 4-year programme was to study, develop and demonstrate an effective in-situ decontamination process using foams containing suitable chemical reagents. Laboratory tests were first performed to optimize the chemical formulation of the foams. Pilot tests were then conducted to study the hydrodynamic features of the fluids and to adapt a technique of permanent foam circulation. With these tests completed, it was essential to validate the foam process on an industrial scale and on a representative nuclear component. The objective was successfully achieved. The process was effectively validated during the decontamination of a graphite-gas cooler representing a developed area of 1000 m{sup 2}. Results were quite convincing since the residual activity of the ...

1994-12-31

430

Co-production of hydrogen and carbon black from solar thermal methane splitting in a tubular reactor prototype  

British Library Electronic Table of Contents (United Kingdom)

This study addresses the solar thermal decomposition of natural gas for the co-production of hydrogen and carbon black (CB) as a high-value nano-material with the bonus of zero CO2 emission. The work focused on the development of a medium-scale solar reactor (10kW) based on the indirect heating concept. The solar reactor is composed of a cubic cavity receiver (20cm-side), which absorbs concentrated solar irradiation through a quartz window by a 9cm-diameter aperture. The reacting gas flows inside four graphite tubular reaction zones that are settled vertically inside the cavity. Experimental results in the temperature range 1740-2070K are presented: acetylene (C2H2) was the most important by-product with a mole fraction of up to about 7%, depending on the gas residence time. C2H2 content i...

2011-01-01

431

Characterization of coatings and the low cycle fatigue behaviour of 316L  

Energy Technology Data Exchange (ETDEWEB)

In the framework of the European Fusion Technology Programme ECN participates in a NET task PSM-8 `Coatings and Surface Effects on Stainless Steel 316L`. High emissivity coatings were developed for enhanced heat transfer from graphite tiles to a Stainless Steel First Wall. Four candidate materials, Cr{sub 2}O{sub 3}, Black Cr, Al{sub 2}O{sub 3}/TiO{sub 2} and TiC were tested as candidate high emissivity coatings. These coatings were manufactured by atmospheric and vacuum plasma spraying technique and the Black Chromium coatings were manufactured by a galvanic coating technique. The tests included total emissivity measurements and Low Cycle Fatigue (LCF) experiments. The total emissivity of two TiC coatings at 525 K appeared to be 0.62 and 0.64. The total emissivity of the TiC and 5 wt% TiO{sub 2}/Al{sub 2}O{sub 3} coating was about 0.7. (orig.)

1993-03-01

432

Assessment of cadmium in aquatic sediment using dialysis samplers with ion-exchange-resin collection  

Energy Technology Data Exchange (ETDEWEB)

Simultaneously extracted metals (SEM) and acid volatile sulfide (AVS) show the potential for toxicity on the basis of their ratio. Accordingly, the authors spiked cadmium in a range for which Cd/AVS ratios were from 0.2 to 10 in the sediment with its weight about 8 kg in each batch. Dialysis samplers with a cation ion-exchange resin (Dowex 50W-X4) collection were used in a laboratory for the determination of free cadmium concentrations in pore water of the collected sediment. When equilibrium was reached among cadmium in pore water, sediment, and ion-exchange resin, cadmium exchanged onto resin phase was regenerated with 1 N hydrochloric acid (OPTIMA grade) and determined using an atomic absorption spectrophotometer (Zeeman 5000) with a graphite furnace accessory. Cadmium determined using the dialysis sampler is considered as free cadmium which is related to the metal bioavailability toward aquatic biota. The developed methodology provides a new technique for ...

1998-05-01

433

Assessment of RELAP5 model for the University of Massachusetts Lowell research reactor  

International Nuclear Information System (INIS)

RELAP5 (Reactor Excursion and Leak Analysis Program) is a system code developed at the Idaho National Environmental and Engineering Laboratory for thermal hydraulic analysis of nuclear reactors. The code RELAP5 is widely used for safety analysis studies of commercial nuclear power plants. However, recent released version of RELAP5/3.2 and over present significant capabilities for analysis of nuclear reactor research systems. As a contribution to the assessment of RELAP5/3.3 for research reactor safety analysis, experimental data from the University of Massachusetts Lowell Research Reactor UMLRR are used. The UMLRR is a 1 MW, light water moderated and cooled, graphite-reflected, open-pool type research reactor. This paper presents the development and the validation of a UMLRR-RELAP model using experimental data. For this purpose, a series of experiments were performed for benchmarking RELAP5 calculations for research reactor systems. As a result of this study, the ...

434

An investigation of the capacitance dispersion on the fractal carbon electrode with edge and basal orientations  

Energy Technology Data Exchange (ETDEWEB)

Capacitance dispersion on the fractal carbon electrode with edge and basal orientations was investigated using atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and a.c.-impedance spectroscopy. For this purpose, four types of as-received pyrolytic graphite electrode, as-received, mechanically polished, and as-activated glassy carbon electrodes were prepared with different surface irregularities and amounts of edge orientations. The apparent self-similar fractal dimensions of the carbon electrodes were determined from the analyses of AFM images based upon triangulation method. The amounts of edge orientations on the surface of the carbon electrodes were qualitatively estimated from the XPS analysis of surface acidic functional groups that were preferably formed on the edge planes by the heat treatment of the carbon electrodes. The values of the constant phase element exponent {alpha} determined from the apparent self-similar fractal dimensions ...

2003-10-15

435

Air liquefaction and enrichment system propulsion in reusable launch vehicles  

Energy Technology Data Exchange (ETDEWEB)

A concept is shown for a fully reusable, Earth-to-orbit launch vehicle with horizontal takeoff and landing, employing an air-turborocket for low speed and a rocket for high-speed acceleration, both using liquid hydrogen for fuel. The turborocket employs a modified liquid air cycle to supply the oxidizer. The rocket uses 90% pure liquid oxygen as its oxidizer that is collected from the atmosphere, separated, and stored during operation of the turborocket from about Mach 2 to 5 or 6. The takeoff weight and the thrust required at takeoff are markedly reduced by collecting the rocket oxidizer in-flight. This article shows an approach and the corresponding technology needs for using air liquefaction and enrichment system propulsion in a single-stage-to-orbit (SSTO) vehicle. Reducing the trajectory altitude at the end of collection reduces the wing area and increases payload. The use of state-of-the-art materials, such as graphite polyimide, in a direct substitution for ...

1994-07-01

436

A novel high temperature stable lithium salt (Li{sub 2}B{sub 12}F{sub 12}) for lithium ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Basic properties and battery performances of the novel high temperature stable lithium salt (Li{sub 2}B{sub 12}F{sub 12}, Dilithium Dodecafluorododecaborate; Li{sub 2}DFB) were studied using a Mn-based cathode and anode composed of a hard carbon and graphite mixture. The effect of co-solvents (mainly linear carbonate in electrolyte formulation of PC/EC/co-solvent (5/30/65 vol% mixture)) on conductivity, viscosity, charge-discharge capacities, rate performance, temperature performance, cycle life and storage life at 60 C was investigated. Conductivity of Li{sub 2}DFB electrolyte increased with reducing its viscosity by changing co-solvent and increasing the volume of the higher dielectric solvent. Li{sub 2}DFB electrolytes showed comparable discharge capacity and columbic efficiency against LiPF{sub 6} electrolyte. Li{sub 2}DFB electrolytes improved the storage life and cycle life of a Mn-based cell at 60 C. (author)

2009-09-05

437

ORALLOY (93.15 235U) METAL ANNULI WITH BERYLLIUM CORE  

International Nuclear Information System (INIS)

A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, two were performed that consisted of uranium metal annuli with a solid beryllium metal core. The outer diameter of the annuli was approximately 13 or 15 inches with an inner diameter of 7 inches. The diameter of the core was approximately 7 inches. ...

438

Liver trauma from penetrating injuries. Miscellanea, personal series, clinical and CT findings; Traumi epatici da lesioni penetranti. Miscellanea, casistica personale, aspetti clinici e con Tomografia Computerizzata  

Energy Technology Data Exchange (ETDEWEB)

Penetrating liver wounds are related to many causes and rank second after blunt abdominal and liver trauma. In this report are examined the clinical and radiological findings of personal series of patients with penetrating trauma, especially by firearms and stab and cut wounds. It will also tried to define the diagnostic workup of these traumas, which is especially based on CT signs of liver damage and associated changes and which is of basic importance for following treatment, both surgical or conservative. In the last seven years it was retrospectively reviewed 31 cases of penetrating liver trauma. The patients were 19 men and 12 women, ranging in age 18 to 73 (mean 42), with penetrating liver injuries from firearms (16 patients) and stab (9 cases) wounds; 6 patients had injuries from different cases. Abdominal CT was carried out in emergency with the CT Angiography (CTA) technique in all patients. In the patients with suspected chest and abdomen involvement CT was performed from the ...

2000-12-01

439

Plutonium distribution and remobilization in sediments of the Rhone River mouth (North-Western Mediterranean); Distribution et remobilisation du plutonium dans les sediments du prodelta du Rhone (Mediterranee nord-occidentale)  

Energy Technology Data Exchange (ETDEWEB)

The aim of the present study was to describe the distribution and remobilization of plutonium (Pu) in the sediments off the Rhone river mouth. Most of the {sup 238}Pu and {sup 239,240}Pu isotopes introduced into the Rhone River were discharged by the liquid effluents released from the Marcoule reprocessing plant, located 120 km upstream the river mouth. Due to its high affinity for particles and its long half life, {sup 238}Pu is a promising tracer to follow the dispersion of particulate matter from the Rhone River to the Mediterranean Sea. During the 3 REMORA cruises, sediment samples were specifically collected in the Rhone pro-delta area and more offshore on the whole continental shelf of the Gulf of Lions. The measurements of alpha emitters gave a first detailed spatial distribution of Pu isotope concentrations in surface sediments off the Rhone mouth. Using {sup 137}Cs concentrations and their correlations with Pu isotopes, we were able to give a first estimate of Pu inventories ...

2004-06-15

440

Computed Tomography of the diabetic kidney; La Tomografia Computerizzata nello studio del rene diabetico  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work is to investigate whether any morphometric or densitometric are detectable in the kidneys of type 2 diabetic patients. 40 diabetic patients were examined and of 20 non-diabetics (the control group) were submitted to triphasic helical CT for different abdominal conditions. The type 2 diabetic patients were 23 men and 17 women, mean age 62 years, while the nondiabetic controls were 12 men and 8 women, mean age 58 years. All the CT images were analyzed using the Multiplanar Reconstruction (MPR) software. It was evaluated morphometric features, such as the presence of parenchymal or vascular calcifications, axial and coronal renal diameters, coronal renal area, and cortico medullary ratio, and densitometric and functional features, such as unenhanced renal density, cortical and medullary density in the arterial phase, parenchymal density in the nephrographic phase, and contrast elimination. It was also compared the results in the subgroups of patients with those in ...

2000-02-01

441

Scientific information and public opinion. Daily press analysis about ozone hole in the years 1996-1997; Informazione scientifica e opinione pubblica. Analisi della stampa quotidiana italiana negli anni 1996-1997 sul tema del buco dell'ozono  

Energy Technology Data Exchange (ETDEWEB)

One of ENEA's many activities consists in dealing with the analysis of information strategies. In this case the analysis concerns an environmental issue, the ozone hole which, in spite of the consideration given by the media, is not sufficiently highlighted, as well as in the case of climate changes issue. A survey of the coverage of four daily newspapers was realized; the time period covered by the analysis spans form January 1996 to December 1997, 77 articles in total. The newspapers involved are: La Repubblica, Il Corriere della Sera, L'Unita' on a national scale, and Il Resto del Carlino on a regional scale. The number of articles analyzed is divided as follows: 26 for the Repubblica, 24 for the Corriere della Sera, 21 for the Unita', 6 for the Resto del Carlino. The purpose of the work was to detect quality and quantity indicators of the Italian press about the ozone hole issue and possible environmental risks conveyed to the public, using the ...

1999-07-01

442

Nephron-sparing percutaneous ablation of a 5 cm renal cell carcinoma by superselective embolization and percutaneous RF-ablation  

Energy Technology Data Exchange (ETDEWEB)

Purpose: To report on the nephron-sparing, percutaneous ablation of a large renal cell carcinoma by combined superselective embolization and percutaneous radiofrequency ablation. Materials and Methods: A 5 cm renal cell carcinoma of a 43-year-old drug abusing male with serologically proven HIV, hepatitis B and C infection, who refused surgery, was superselectively embolized using microspheres (size: 500 - 700 {mu}m) and a platinum coil under local anesthesia. Percutaneous radiofrequency ablation using a 7F LeVeen probe (size of expanded probe tip: 40 mm) and a 200 Watt generator was performed one day after transcatheter embolization under general anesthesia. Results: The combined treatment resulted in complete destruction of the tumor without relevant damage of the surrounding healthy renal tissue. The patient was discharged 24 hours after RF ablation. No complications like urinary leaks or fistulas were observed and follow up CT one day and 4 weeks after the ...

2001-11-01

443

The microzooplankton and its distribution in different aquatic environment; Il microzooplancton e la sua distribuzione nei diversi ambienti  

Energy Technology Data Exchange (ETDEWEB)

In this work some examples of studies performed with the use of microzooplankton as biological indicator are reported. [Italian] Scopo del lavoro e' quello di dimostrare come lo studio della distribuzione del microzooplancton in ambienti aquatici, possa permettere la caratterizzazione trofica dell'ambiente oggetto di studio. Il microzooplancton, infatti, essendo un componente fondamentale della catena trofica di differenti ambienti acquatici, puo' essere considerato un buon {sup i}ndicatore biologico{sup .} E' quindi riportata un'ampia ed approfondita analisi sistematica, necessaria al fine di individuarne le diverse specie dalla cui presenza (oltreche' dal numero degli esemplari) e' possibile desumere lo stato chimico-fisico e trofico di un determinato ambiente acquatico. Sono poi indicati i diversi metodi per il campionamento, la conservazione, la concentrazione ed il conteggio del microzooplancton; ...

1999-07-01

444

The earth is warming up while the sky is getting a chill; La terre se rechauffe, le ciel a un coup de froid  

Energy Technology Data Exchange (ETDEWEB)

The phenomenon of global warming, its causes and implications for the future, and the relationship between global warming and the depletion of the ozone layer are discussed. The Shindell model of the greenhouse effect, which is responsible for planetary warming, also contributes to the high altitude thinning of the ozone layer. While greenhouse gas emissions contribute to retaining infrared radiation, thus warming the surface of the earth, their effect is reduced at stratospheric altitudes resulting in reduced temperatures in this region. At this altitude temperatures can reach minus 90 degrees C, creating a whirlwind effect, with ice crystals forming at the heart of the vortex, causing the surface to accelerate chemical reactions which in turn leads to destruction of ozone. Although since the signing of the Montreal Protocol in 1987 the industrialized countries have significantly reduced their emissions of refrigerating gas (chlorofluorocarbons or CFC), which were considered to have ...

2001-03-01

445

The carbonate feedback system: interaction between stratigraphic accommodation, ecological succession and the carbonate factory; Le systeme de feed-back des carbonates: une interaction entre accomodation stratigraphique, succession ecologique et l`usine des carbonates  

Energy Technology Data Exchange (ETDEWEB)

In this paper, the analysis of carbonate depositional systems, using high resolution sequence stratigraphy, studies the ratio between change in accommodation space and skeletal carbonate production. This approach establishes the concurrent change in nature of facies belts (expansion, retraction and type) and fossil communities, within the detailed time frame in accommodation. Carbonate production is generally considered to be a fairly simple function of environmental conditions such as climate and water depth. However, data from several case studies also show a covariance between change in stratigraphic architecture of carbonate systems (the seaward or landward stepping stacking patterns of stratigraphic units) and charge in facies. Case studies include Carboniferous algal mound development in the Paradox Basin (USA), Devonian stromatoporoid reef development in Alberta (Canada), and Cenomanian rudistid shoal development in Oman. The hypotheses are tested on cases taken from the ...

1996-12-31

446

The EIB and the financing of renewable energy sources; La BEI et le financement des energies renouvelables  

Energy Technology Data Exchange (ETDEWEB)

As a financial institution o the European Union, The European Investment Bank is working and to add substance to the commitments made by the Union and its Member States at Kyoto and subsequently at Johannesburg. Over the last two years, renewable energy sources have attracted funding of more than 1.1 billion from the bank, equivalent to 14% of the total loans granted to the energy sector 7.8 billion), compared to an average o 7.9 % over the previous five years. In order to obviate the detrimental characteristics presented by these investments from a financial viewpoint, in March, 2004 the bank set up a 'CCFF' (Climate Change Financing Facility) of 500 million. Additionally, along with the other financial institutions, the EIB is looking into he possibility of supporting the establishment of European carbon credit trading hubs. Where the economic assessment of these projects is concerned, the bank has decided to take account of external environmental and technological ...

2004-10-01

447

Test facilities for hybrid and electric drive trains; Stazione di prova sistemi di trazione ibridi ed elettrici  

Energy Technology Data Exchange (ETDEWEB)

ENEA (Italian National Agency for New Technologies, Energy and the Environment) is conducting a large research and development programme on innovative vehicles with high energy efficiency and low environmental impact. In particular conducts activities on electric and hybrid vehicles. Testing and evaluation activities play a strong role in this programme. A complete characterization chain has been then defined and set up with a network of facilities which covers main testing needs for single components, subsystems and complete vehicles, in simulated and real operating conditions. The test facility which has been realised is able to experiment and fully characterise complete drive-trains (and subsystems) for pure electric and hybrid vehicles. It is composed by a different section for each subsystem: 1) power generation; 2) energy storage and management; 3) driving motors. Each section acts as an experimental island, able to operate alone or jointly with the other sections. In fact, all ...

1998-12-31

448

Sensors and instrumentation for atmospheric pollutions control; Capteurs et instrumentation pour le controle des pollutions atmospheriques  

Energy Technology Data Exchange (ETDEWEB)

Reinforcement of the legislation concerning the emission of atmospheric pollutants, aerosols, refrigerants, solvents etc and the reduction of the greenhouse effect, has led to the development of performing instruments for the survey and control of ambient air quality and for the limitation of exhaust gases, combustion products, volatile organic compounds (VOC), particulates and noxious compounds in the atmosphere. This study is divided in 4 main parts. The first part describes the context of the air quality control: the problems linked with the environment and health, the pollutants characteristics, the pollution levels and the detection sensitivity of instruments according to the different type of pollutants (petroleum products, VOCs, ozone compounds, particulates, smells..), the protocols of air pollution measurements and their application (chimney smokes, industrial volatile compounds, indoor and ambient air quality, exhaust gases from automobiles), and the French, European and ...

1996-11-01

449

Self-construction of a solar water heater; Calentador solar de agua de auto-construccion  

Energy Technology Data Exchange (ETDEWEB)

In this work a flat receiver of self construction is shown with relatively low cost and easy manufacture, but with a thermal efficiency superior to 40% for applications at temperatures less than 60 degrees Celsius, that allows satisfying international standards in this respect. The heater has been matter of study in open courses distributed in the Universidad Autonoma de la Ciudad de Mexico (UACM) oriented to that the participants construct their own system, in addition to its installation and tests. The obtained results have been excellent. The massive use of efficient solar receivers of self-construction can truly help to the decreasing of the gas discharges of greenhouse effect. [Spanish] En este trabajo se presenta un captador plano de auto construccion con relativamente bajo costo y facil manufactura, pero con un rendimiento termico superior a 40% para aplicaciones a temperatura menos de 60 grados centigrados que le permite satisfacer estandares ...

2009-07-01

450

Probing quantum gravity using photons from a flare of the active galactic nucleus Markarian 501 observed by the MAGIC telescope  

Energy Technology Data Exchange (ETDEWEB)

We analyze the timing of photons observed by the MAGIC telescope during a flare of the active galactic nucleus Mkn 501 for a possible correlation with energy, as suggested by some models of quantum gravity (QG), which predict a vacuum refractive index {approx_equal}1+(E/M{sub QGn}){sup n}, n=1,2. Parametrizing the delay between {gamma}-rays of different energies as {delta}t={+-}{tau}{sub l}E or {delta}t={+-}{tau}{sub q}E{sup 2}, we find {tau}{sub l}=(0.030{+-}0.012) s/GeV at the 2.5-{sigma} level, and {tau}{sub q}=(3.71{+-}2.57)x10{sup -6} s/GeV{sup 2}, respectively. We use these results to establish lower limits M{sub QG1}>0.21x10{sup 18} GeV and M{sub QG2}>0.26x10{sup 11} GeV at the 95% C.L. Monte Carlo studies confirm the MAGIC sensitivity to propagation effects at these levels. Thermal plasma effects in the source are negligible, but we cannot exclude the importance of some other source effect.

2008-10-16

451

PbZrO sub 3 -doped (Ba,Sr)TiO sub 3 -based dielectrics for high-voltage capacitor applications  

Energy Technology Data Exchange (ETDEWEB)

This paper reports that high-dielectric ceramics with the composition (94.7% {minus} x) (Ba,Sr)TiO{sub 3} + PbZrO{sub 3} + 5Bi{sub 2}Ti{sub 3}O{sub 9} + 0.3MnO{sub 2}, where the ration (Ba)/(Sr) = 1.25 and x {le} 15 mol%, have been developed for high-voltage capacitors. The dielectric constant of the ceramics is in the range 1200 to 1900 at room temperature, and the room-temperature dielectric loss, tan{delta}, is less than 0.3%, except when 15 mol% PbZrO{sub 3} is added with sintering at 1180{degrees}C to 1240{degrees}C for 2 h. Ceramics with more than 8 mol% zirconate show the Y5S characteristic of capacitance, and those with less than 8 mol% additive exhibit the Z5S characteristic. The dielectric constant gradually increases with increment in the ac signal voltage at 60 Hz, but decreases beyond a threshold value that varies with zirconate content and sintering conditions. The variation of the dielectric constant at 2 kVrms/mm (with respect to 0.25 kVrms/mm) is ...

1991-11-01

452

Nuclear magnetic resonance spectroscopy in biomedicine. Course organized by the Istituto Superiore di Sanita`. Marciana Marina (Isola d`Elba), September 18-23, 1995; Spettroscopia di risonanza magnetica nucleare in biomedicina. Corso organizzato dall`Istituto Superiore di Sanita`. Marciana Marina (Isola d`Elba), 18-23 settembre 1995  

Energy Technology Data Exchange (ETDEWEB)

Nuclear magnetic resonance is a powerful technique that can be used in a wide range of applications, such as the structural characterization of high molecular weight molecules, conformational studies on enzymes in solution, enzyme-substrate or DNA-protein interactions, monitoring of cell metabolism in vivo, and for diagnostic purposes, employing spectroscopic and imaging techniques. This course was organized in order to introduce the participants to the fundamentals of NMR spectroscopy, and offer practical advice on performing NMR experiments on cell systems, cell and tissue extracts and animal models. The main implications regarding human experiments were also discussed. Finally the quantification of information and the interpretation of data were considered with regard to the main nuclei observed. [Italiano] La risonanza magnetica nucleare e` una delle tecniche spettroscopiche che meglio risponde all`ampio spettro di condizioni imposto dalla ricerca in biofisica e biomedicina. Il ...

1997-12-01

453

Lung studies with spiral CT. pitch 1 versus pitch 2; Confronto tra diversi parametri (pitch 1 e 2) nello studio del polmone con Tomografia Computerizzata spirale  

Energy Technology Data Exchange (ETDEWEB)

In Spiral CT, the pitch is the ratio of the distance to tabletop travels per 360 degrees rotation to nominal slice width, expressed in mm. Performing Spiral CT examination with pitch 2 allows to reduce examination time, exposure and contrast dose, and X-ray tube overload. The authors investigated the yield of pitch 2 in lung parenchyma studies, particular relative to diagnostic image quality. [Italian] Nella Tomografia Computerizzata (TC) spirale il rapporto tra la distanza percorsa dal lettino portapaziente in una rotazione e lo spessore nominale dello strato, entrambi espressi in millimetri, si definische pitch. Se i due valori del rapporto coincidono si avra' pitch uguale a 1, mentre raddoppiando la distanza percorsa dal lettino portapaziente, per il medesimo spessore nominale, conseguentemente raddoppia il pitch (pitch 2). Eseguire gli esami TC spirale utilizzando pitch 2, consente di ridurre la durata dell'esame, la dose di esposizione, il consumo mdc e ...

1999-03-01

454

Le leucodistrofie: aspetti clinici e quadri con Tomografia Computerizzata e con Risonanza Magnetica  

International Nuclear Information System (INIS)

Leukodystrophies are inherited white matter diseases due to abnormalities occurring in myelin synthesis and/or maintenance. The most common types of these rare childhood conditions are represented by adrenoleukodystrophy, metachromatic leukodystrophy, Canavan's, Alexander's, Krabbe's, and Pelizaeus-Merzbacher's diseases. Most of them are lethal during childhood, with the exception of the adrenoleukodystrophy-adrenomyeloneuropathy complex, which sometimes, during its early phases, may be cured with a dietary therapy. The aims of this paper are: 1) the description of inheritance factors, pathogenesis, pathological and clinical findings of each of the most frequent childhood leukodystrophies; 2) the description of the most common patterns of these conditions on CT and MR imaging; 3) the evaluation of the diagnostic capabilities of these two imaging techniques and the comparison of their results. Finally, some of the therapies suggested for the mild forms of these conditions are discussed. ...

1991-01-01

455

In situ scanning tunneling microscope study of the passivation of Cu(111)  

Energy Technology Data Exchange (ETDEWEB)

In situ scanning tunneling microscopy has been used to study the nucleation and growth mechanisms and the structure of passive films formed on Cu(111) surfaces in 0.1 M borate buffer solution (pH 9.3). A surface topography characterized by terraces with monoatomic steps is obtained after potentiodynamic reduction down to {minus}1.12 V/standard hydrogen electrode (SHE), of the electropolished surface exposed to air. The formation of a single Cu{sub 2}O passive layer at 0.03 V/SHE proceeds first by a roughening of the steps assigned to a locally blocked step flow process due to a competition between dissolution and preferential nucleation of the oxide at the steps. The observed oxide nuclei are 2--3 nm wide and about one atomic plane high. This process leads to the complete coverage of the terraces by a grain-like structure of the oxide film. The initial terrace topography is completely altered. Thickening of this oxide layer leads to unstable scanning tunneling microscope imaging, ...

1999-02-01

456

Hydrogeochemical properties of caulk dykes : impact on underground stowing and surface storage; Proprietes hydrogeochimiques des remblais en pate : impact sur le remblayage souterrain et l'entreposage en surface  

Energy Technology Data Exchange (ETDEWEB)

Samples from three mine tailings, the Hemlo Mine (located in Northern Ontario), the Louvicourt Mine, and the Laronde Mine (both located in Northwestern Quebec) and four different types of hydraulic binder in three different proportions (3, 4.5, 6 per cent of total dry weight of tailings) were used to prepare 33 recipes for cement caulk. The sulphur content of the three tailings is, respectively, 5 per cent, 16 per cent, and 32 per cent. Three of the four hydraulic binders are in fact a mix of two cement types: binder based on Portland cement (CP), binder based on fly ash (FA), and binder based on dross (CL). The fourth binder is based mainly on dross. The coupons of caulk dykes were flushed at 14, 28, 56, and 91 days in a humid chamber. At each of these steps, the samples were characterized for chemical, geochemical, physical, microstructural, and mechanical attributes to better understand the hydrogeochemical properties of the caulk dykes. The geochemical characterization indicated no ...

2000-07-01

457

High temperature oxidation of metals: vacancy injection and consequences on the mechanical properties; Consequences de l'oxydation haute temperature sur l'injection de defauts et le comportement mecanique des materiaux metalliques  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to account for the effects of the high temperature oxidation of metals on their microstructure and their mechanical properties. 'Model' materials like pure nickel, pure iron and the Ni-20Cr alloy are studied. Nickel foils have been oxidised at 1000 C on one side only in laboratory air, the other side being protected from oxidation by a reducing atmosphere. After the oxidation treatment, the unoxidized face was carefully examined by using an Atomic Force Microscope (AFM). Grain boundaries grooves were characterised and their depth were compared to the ones obtained on the same sample heat treated in the reducing atmosphere during the same time. They are found to be much deeper in the case of the single side oxidised samples. It is shown that this additional grooving is directly linked to the growth of the oxide scale on the opposite side and that it can be explained by the diffusion of the vacancies produced at the oxide scale - metal interface, ...

2004-11-15

458

FY1995 next generation highly parallel database / dataminig server using 100 PC's and ATM switch; 1995 nendo tasudai no pasokon wo ATM ketsugoshita jisedai choheiretsu database mining server no kaihatsu  

Energy Technology Data Exchange (ETDEWEB)

The objective of the research is first to build a highly parallel processing system using 100 personal computers and an ATM switch. The former is a commodity for computer, while the latter can be regarded as a commodity for future communication systems. Second is to implement parallel relational database management system and parallel data mining system over the 100-PC cluster system. Third is to run decision-support queries typicalto data warehouses, to run association rule mining, and to prove the effectiveness of the proposed architecture as a next generation parallel database/datamining server. Performance/cost ratio of PC is significantly improved compared with workstations and proprietry systems due to its mass production. The cost of ATM switch is also considerably decreasing since ATM is being widely accepted as a communication-on infrastructure. By combining 100 PCs as computing commodities and ATM switch as a communication commodity, we built large sca-le ...

1997-03-01

459

Environmental management; La gestione ambientale  

Energy Technology Data Exchange (ETDEWEB)

Nowadays, unlike in the past, companies have to operate in a context of sustainable development, in which the economic and social development, production and consumption have to take into account the medium and long term impact on environment. The article sets forth some considerations about these subjects, which are assuming a growing importance in the management of companies: the variable environment may for instance be a factor of discrimination between being competitive or not. In order to characterise the context within which the environmental management has to be applied, some basic concepts about environmental management systems, Life Cycle Assessment, and Eco labeling are illustrated. As an example of application of the methodology described, a brief reference to the Italgas Group Environmental Report is given. [Italian] Oggi, a differenza del passato, le imprese si trovano ad operare in un contesto di sviluppo sostenibile, nel quale l'evoluzione ...

2000-04-01

460

Electron-ion recombination of neutral iron  

Energy Technology Data Exchange (ETDEWEB)

The total and state-specific electron-ion recombination rate coefficients are obtained for FeI. The calculations are carried out using a new ab initio method that incorporates both the radiative and the dielectronic recombination processes in an unified and self-consistent manner. The computations employ the close coupling approximation and the R-matrix method from atomic collision theory. A 52 state close coupling eigenfunction expansion dominated by the states of the ground 3d{sup 6}4s and excited 3d{sup 7}, 3d{sup 6}4p, 3d{sup 5}4s{sup 2}, and 3d{sup 5}4s4p configurations of FeII are used in the present calculations. The important electron correlation and radiation damping effects are included via explicit coupling of autoionization and radiative channels. This is the first detailed atomic calculation for the recombination rates for FeI. The present rates are considerably higher than the radiative recombination rates being used currently in the low-temperature region, ...

1997-04-01

461

Eco-compatible products and processes development. ENEA promotion actions; Sviluppo di prodotti e processi ecocompatibili. Le attivita' dell'ENEA  

Energy Technology Data Exchange (ETDEWEB)

The new industrial political tools based on the Sustainable development of productive activities and originating at the Rio Conference in 1992, late introduced by the EU, the Government and voluntary organizations (ISO, CEM, UNI) are gradually entering the market, thereby underlying their effect in terms of industrial competitiveness. The main tools were examined in this report and mostly refer to the voluntary ones which, in surpassing the Command and Control logic, increasingly tend to get close to traditional fiscal, tariff and financial ones. [Italian] I nuovi strumenti di politica industriale orientali allo Sviluppo Sostenibile delle attivita' produttive che traggono origine dalla Conferenza di Rio del 1992 e sono stati introdotti successivamente da pare della Comunita' Europea, dal Governo e dagli Organismi di normazione volontaria (ISO, CEN, UNI), stanno gradualmente penetrando sul mercato facendo valere i loro effetti in termini di competitivita' ...

2001-07-01

462

Dosimetric evaluation and therapeutic response to iodine-131 labelled lipiodol in treatment of hepatocellular carcinomas; Evaluation dosimetrique et reponse therapeutique de la curietherapie metabolique des hepatocarcinomes par le lipiodol marque par l'iode 131  

Energy Technology Data Exchange (ETDEWEB)

Faced with increasing indications for the use of iodine-131 labelled lipiodol in the treatment of hepatocellular carcinoma (HCC), it appears essential to develop an individualized dosimetrY so we can predict the potential effectiveness of this treatment and adjust the activity to be injected. We developed a dosimetric protocol based on imagery and dedicated to calculation of the tumoral dose during the treatment of hepatocellular carcinoma by iodine-131 labelled lipiodol. This concept was developed on a SPECT- CT gantry, and integrates corrections for the phenomena of attenuation, diffusion and dead time. The dose is calculated according to the formalism proposed by the Medical Internal Radiation Dose Committee (MIRD). This protocol was applied to a series of 41 patients in the framework of a retrospective study. The results obtained in terms of biodistribution are compatible with previously published data. The total biological response rate is 42% (n= 41) for the first treatment and ...

2006-12-15

463

Development of a 3-D model for eddy current testing: application for fastened structures in aeronautics; Developpement d'un modele pour le controle non destructif par courants de Foucault de structures rivetees en aeronautique  

Energy Technology Data Exchange (ETDEWEB)

One of the Eddy Current Testing issues in aeronautics is the inspection of fastened structures to detect flaws nearby rivets which can grow because of mechanical stress. EADS and the CEA LIST have started a collaborative work with the support of the Ile-de-France Region to develop a simulation tool of EC fastened structures testing, integrated to the CIVA platform, aimed at conceiving testing methods, optimizing and qualifying it. The volume integral method using the Green dyadics formalism has been chosen in order to get a fast resolution of Maxwell equations. A first milestone was to build a simulation model of multilayer structures testing, thanks to the use of the multilayer Green dyads. Because of the rivet volume, 60 times bigger than the one of a typical flaw, a large number of discretization cells are needed. Therefore an iterative method has been developed in order to numerically solve large calculation zones. Finally, the flaw response simulation mostly has to cope with a ...

2007-12-15

464

Closure relations for the multi-species Euler system. Construction and study of relaxation schemes for the multi-species and multi-components Euler systems; Relations de fermeture pour le systeme des equations d'Euler multi-especes. Construction et etude de schemas de relaxation en multi-especes et en multi-constituants  

Energy Technology Data Exchange (ETDEWEB)

After having recalled the formal convergence of the semi-classical multi-species Boltzmann equations toward the multi-species Euler system (i.e. mixture of gases having the same velocity), we generalize to this system the closure relations proposed by B. Despres and by F. Lagoutiere for the multi-components Euler system (i.e. mixture of non miscible fluids having the same velocity). Then, we extend the energy relaxation schemes proposed by F. Coquel and by B. Perthame for the numerical resolution of the mono-species Euler system to the multi-species isothermal Euler system and to the multi-components isobar-isothermal Euler system. This allows to obtain a class of entropic schemes under a CFL criteria. In the multi-components case, this class of entropic schemes is perhaps a way for the treatment of interface problems and, then, for the treatment of the numerical mixture area by using a Lagrange + projection scheme. Nevertheless, we have to find a good projection stage in the ...

2001-07-01

465

ARDEC transition armature study. Progress report No. 3, October 1--November 30, 1991  

Energy Technology Data Exchange (ETDEWEB)

This third report covers the period October 1 to November 30, 1991. During this period the authors: (1) fabricated a test fixture for studying hybrid armature brush behavior, (2) reactivated a 140kJ, 1MA capacitor bank, (3) reactivated 25 channels digital data acquisition and reduction system and (4) concluded the use of a DNA funded railgun would serve as the most expedient means to acquire a railgun test bed. Fabrication of a plasma brush test fixture for studying the formation, evolution and stability of plasma brushes was completed. The fixture will serve to study plasma brush parameters, such as brush length and voltage drop, as a function of initial solid foil mass, gap size and current concentration. A 4OkV, 168{mu}f, 140kJ capacitor bank capable of providing more than 1MA of current was reactivated. (The LLNL bank had been developed for opening switch research which was successfully completed.) The bank will be used to power the test fixture with 10{mu}s, flat top current ...

1992-05-13

466

"Eztrack": A single-vehicle deterministic tracking algorithm  

Energy Technology Data Exchange (ETDEWEB)

A variety of surveillance operations require the ability to track vehicles over a long period of time using sequences of images taken from a camera mounted on an airborne or similar platform. In order to be able to see and track a vehicle for any length of time, either a persistent surveillance imager is needed that can image wide fields of view over a long time-span or a highly maneuverable smaller field-of-view imager is needed that can follow the vehicle of interest. The algorithm described here was designed for the persistence surveillance case. In turns out that most vehicle tracking algorithms described in the literature[1,2,3,4] are designed for higher frame rates (> 5 FPS) and relatively short ground sampling distances (GSD) and resolutions ({approx} few cm to a couple tens of cm). But for our datasets, we are restricted to lower resolutions and GSD's ({ge}0.5 m) and limited frame-rates ({le}2.0 Hz). As a consequence, we designed our own ...

2007-12-20

467

Zinc/air battery R and D research and development of bifunctional oxygen electrode: Tasks I and II, Final report  

Energy Technology Data Exchange (ETDEWEB)

Studies were conducted of the bifunctional oxygen electrode. The development of a rechargeable metal-oxygen (air) cell has been hampered to a great extent by the lack of a stable and cost effective oxygen electrode capable of use during both charge and discharge. The first type of bifunctional electrode consists of two distinct catalytifc layers. The oxygen reduction catalyst layer containing a supported gold catalyst is in contact with a hydrophilic nickel layer in which evolution of oxygen takes place. Loadings of gold from 0.5 to 1.0 mg/cm/sup 2/ were investigated; carbon, graphite, metal, and spinel oxides were evaluated as substrates. The second part of the research effort was centered on developing a reversible oxygen electrode containing only one catalytic layer for both reduction and evolution of oxygen. The work was directed specifically to the study of perovskite type of oxides with the composition AA/sup 1/BO/sub 3/ where A is an element of the ...

1986-12-01

468

Tritium contamination and decontamination study on materials for ITER remote handling equipment  

Energy Technology Data Exchange (ETDEWEB)

Several materials, lenses, dry bearings and cables were exposed to a tritiated moisture environment to study the behavior of tritium contamination on candidate materials for ITER remote handling equipment. To optimize the tritium removal procedure, decontamination experiments using a gas purge with three different moisture concentrations were also performed. The surface tritium concentrations of CeO{sub 2} containing alkaline barium glass (NB), CeO{sub 2} containing lead glass (LX) and synthetic quartz (Quartz) after the exposure experiments were 7.80, 10.94 and 0.67 Bq/cm{sup 2}, respectively. It was found that the tritium concentration was influenced by the compositions of the materials. The concentrations of tritium on type 831 (solid lubrication material: graphite) and type 237 (solid lubrication material: tungsten disulfate) dry bearings after the exposure experiments were 89.80 and 31.78 Bq/cm{sup 2}, respectively. The tritium concentration in an electric ...

2001-09-01

469

Tritium contamination and decontamination study on materials for ITER remote handling equipment  

International Nuclear Information System (INIS)

Several materials, lenses, dry bearings and cables were exposed to a tritiated moisture environment to study the behavior of tritium contamination on candidate materials for ITER remote handling equipment. To optimize the tritium removal procedure, decontamination experiments using a gas purge with three different moisture concentrations were also performed. The surface tritium concentrations of CeO_2 containing alkaline barium glass (NB), CeO_2 containing lead glass (LX) and synthetic quartz (Quartz) after the exposure experiments were 7.80, 10.94 and 0.67 Bq/cm"2, respectively. It was found that the tritium concentration was influenced by the compositions of the materials. The concentrations of tritium on type 831 (solid lubrication material: graphite) and type 237 (solid lubrication material: tungsten disulfate) dry bearings after the exposure experiments were 89.80 and 31.78 Bq/cm"2, respectively. The tritium concentration in an electric cable tested was 5014 ...

2001-09-01

470

The thermal neutron sensitivities of SEI and Toshiba FD-P10-7 radiophotoluminescent glass dosimeters  

Energy Technology Data Exchange (ETDEWEB)

The themal neutron sensitivities of SEI and Toshiba FD-P10-7 radiophotoluminescent silver activated metaphosphate glass dosimeters have been measured and studied theoretically. The graphite thermal neutron column attached to the AEEW reactor NESTOR was utilised as a source of thermal neutrons with minimal fast neutron and gamma-ray contamination. Both the neutron removal and gamma correction measurement techniques were applied and these gave consistent results. It was found that the thermal neutron sensitivity of the Toshiba dosimeters is comparable to the most neutron intensitive thermoluminescent materials available. Because of their larger size and higher silver concentration, however, SEI dosimeters are an order of magnitude more neutron sensitive. The neutron sensitivity of FD-7 glass has not been reported previously, whereas in the case of SEI glass, there exists a modest body of previous work on dosimeters of nominally identical composition. The present ...

1990-01-01

471

The thermal neutron sensitivities of SEI and Toshiba FD-P10-7 radiophotoluminescent glass dosimeters  

International Nuclear Information System (INIS)

The themal neutron sensitivities of SEI and Toshiba FD-P10-7 radiophotoluminescent silver activated metaphosphate glass dosimeters have been measured and studied theoretically. The graphite thermal neutron column attached to the AEEW reactor NESTOR was utilised as a source of thermal neutrons with minimal fast neutron and gamma-ray contamination. Both the neutron removal and gamma correction measurement techniques were applied and these gave consistent results. It was found that the thermal neutron sensitivity of the Toshiba dosimeters is comparable to the most neutron intensitive thermoluminescent materials available. Because of their larger size and higher silver concentration, however, SEI dosimeters are an order of magnitude more neutron sensitive. The neutron sensitivity of FD-7 glass has not been reported previously, whereas in the case of SEI glass, there exists a modest body of previous work on dosimeters of nominally identical composition. The present ...

472

Radiological characterization of the GRR-1 pool  

International Nuclear Information System (INIS)

GRR-1 is a 5MW open pool type research reactor with MTR-type fuel elements cooled and moderated by light water with beryllium reflectors at the two opposing sides of the core. A graphite thermal neutron column is adjusted to one side of the core. Six radial horizontal beam tubes are available, of which three contain in-pile collimators for neutron scattering instruments. The reactor is currently out of operation for inspection and refurbishment purposes. The core has been dismantled and the fuel elements are stored in the used fuel storage tank. The GRR-1 inspection and refurbishment plan involves inspection and eventually replacement of the reactor's primary cooling circuit. The health physics procedures to be implemented during inspection of the main water outlet are divided in three stages: a) pool dose rate survey from pool top, b) pool drainage by decreasing water level in steps and c) inspection of the water main outlet. urpose of the present work is the ...

2007-11-05

473

Production of high-q ions by laser bombardment method  

International Nuclear Information System (INIS)

The expanding plasma produced when an intense pulse of laser radiation is focused in vacuum onto a solid target has been used as a source of highly stripped ions for collision cross-section measurements. Usable fluxes of carbon nuclei at energies of a few hundred eV/charge have been obtained by irradiation of graphite with pulses of CO"2 laser radiation at a focused power density of 3 x 10_1_0 W/cm_2. Bombardment of aluminum and iron targets at comparable power levels have yielded ions of maximum charges of 9 and 16 respectively. A time-of-flight apparatus has been constructed to utilize the laser source for measurement of electron capture cross sections for highly stripped ions in gases at energies in the few hundred eV/charge range. Apertures collimate an ion beam from the plasma blowoff, and an electrostatic analyzer selects ions from the expanding plasma which have the same energy per charge. The beam is directed through a gas target cell, charge anlyzed once ...

1981-01-01

474

Nitrite removal from marine aquaculture wastewater using electrochemical process  

International Nuclear Information System (INIS)

The hazardous and toxic nature of some of the constituent such as nitrite in the aquaculture wastewater is of major concern. Present study focuses the removal of nitrite from the aquaculture wastewater prior to disposal. Effect of certain operational parameters such as electrode material, current density, initial pH, and electrode spacing on nitrite removal from aquaculture wastewater was elucidated. Better nitrite removal efficiency achieved when nickel used as compared to stainless steel, graphite and aluminum electrodes. Nitrite removal is positively related to the current density however, increase is up to 31.4% when current density increased from 2.5 to 9.3 mA/cm/sup 2/. Further increase in current density does not improve the process efficiency. Removal efficiency of electrochemical process decreased with the increase in initial pH of test solution. However, with the passage of time this difference is diminishing. This may be attributed to the presence of ...

3183-01-01

475

NGNP Composites R&D Technical Issues Study  

Energy Technology Data Exchange (ETDEWEB)

This study identifies potential applications and design requirements for ceramic materials (CMs) and ceramic composite materials (CCMs) in the NGNP hightemperature gas-cooled reactor (HTGR) primary circuit. Components anticipated for fabrication from non-graphite CMs and CCMs are identified along with recommended normal and off-normal operating conditions. The evaluation defines required dimensions and material properties of the candidate materials for normal operating conditions (NOC), anticipated transients, abnormal events, and design basis events. The report also identifies additional activities required for codifying the selected materials. The activities include ASTM Standard and ASME Code development and other work to support NRC licensing of the plant. Evaluation of the NGNP baseline design indicates components requiring either CMs or CCMs depend upon the reactor operating temperatures. For a reactor outlet temperature of 900 oC, four of the five evaluated ...

2008-09-01

476

Light-weight free-standing carbon nanotube-silicon films for anodes of lithium ion batteries.  

Science.gov (United States)

Silicon is an attractive alloy-type anode material because of its highest known capacity (4200 mAh/g). However, lithium insertion into and extraction from silicon are accompanied by a huge volume change, up to 300%, which induces a strong strain on silicon and causes pulverization and rapid capacity fading due to the loss of the electrical contact between part of silicon and current collector. Si nanostructures such as nanowires, which are chemically and electrically bonded to the current collector, can overcome the pulverization problem, however, the heavy metal current collectors in these systems are larger in weight than Si active material. Herein we report a novel anode structure free of heavy metal current collectors by integrating a flexible, conductive carbon nanotube (CNT) network into a Si anode. The composite film is free-standing and has a structure similar to the steel bar reinforced concrete, where the infiltrated CNT network functions as both mechanical support and ...

2010-07-27

477

Large sample NAA facility at GRR-1 research reactor: Design and applications  

International Nuclear Information System (INIS)

Full text: A Large Sample Neutron Activation Analysis (LSNAA) facility is under development at GRR-1 research reactor, NCSR 'Demokritos'. The LSNAA facility design incorporates sample irradiation in the reactor's graphite thermal neutron column and subsequent measurement of the activity induced at a gamma spectroscopy system with gamma ray transmission measurement options included. Monte Carlo neutron and photon transport code MCNP-4C was used to model the facility. Appropriate correction factors accounting for neutron field perturbation during sample irradiation, high purity germanium detector efficiency for the volume source and gamma ray self-absorption within the sample itself were derived. The results of the computations were experimentally verified by activation foil measurements for a set of known materials and a range of sample sizes extending up to 10 litters. Moreover, the special issue of large sample analysis of non-homogeneous samples is examined and ...

2003-06-09

478

Inherent safe heat removal in advanced medium-sized high-temperature reactors  

International Nuclear Information System (INIS)

One of the main points for the inherent safety of a pebble bed high temperature reactor (HTR) is to guarantee the safe removal of the after-heat in case of a break-down of all active cooling systems like heat-exchangers or liner-cooling. This will be necessary because it is well known today that graphite pebble bed fuel elements stay intact, if the accident temperature is below 1600 deg. C. Therefore the heat must be taken out of the reactor system by passive, natural law heat-transfer mechanism so that the maximum fuel temperature stays below the specified limit. Today medium-sized HTRs with a power of 750 MW_t_h and more (TGTR-300, HTR 500) reach temperatures of more than 2400 deg. C in small parts of the core in such hypothetical accidents. A possible way to realize the inherent safe heat removal in advanced medium-sized HTRs is to change the form of the core. Instead of employing the standard cylindrical geometry a plate shaped core should be preferred, ...

1990-04-01

479

Influence of phosphorus vapor ambient for InGaAsP growth on GaAs substrate  

Science.gov (United States)

For visible-light-emitting laser diodes, InGaAsP double heterostructures have been grown on GaAs substrates using liquid-phase epitaxy. As the growth temperature is as high as about 780 /sup 0/C, a large amount of phosphorus evaporates from the solutions for the cladding layers during the growth process. The phosphorus vapor disturbs the solution composition for the active layer, so that very thin and uniform active layers cannot be obtained. By using In-P-Sn solution and supplying the phosphorus partial pressure around the graphite boat, the influence of phosphorus vapor ambient for InGaAsP (lambda/sub P//sub L/ = 805 nm) growth is confirmed. When the phosphorus partial pressure increases, the surface of epitaxial layer becomes rough and the substrate is partly etched back. From x-ray diffraction and photoluminescence spectral measurements, the composition of the grown layer is also found to be changed. As a result of increasing the flow rate of H/sub 2/ gas in ...

1986-12-01

480

Graded layer design for stress-reduced and strongly adherent superhard amorphous carbon films  

Energy Technology Data Exchange (ETDEWEB)

Diamond-like carbon thin films for tribological applications were deposited by d.c.-magnetron sputtering of a graphite target in a pure argon atmosphere or in a reactive hydrogen or methane atmosphere at pressures between 0.1 and 1 Pa in a graded constitution to improve adhesion and reduce residual stress. The temperature of the metallic, carbon- and ceramic-like substrates was below 100 C. The mechanical, thermal, electronic and optical properties of the carbon thin films show a significant dependence on the ion energy. Below 220 eV, strongly adherent black conductive films with hardness values up to 2000 HV0.05 were obtained. Hard and superhard diamond-like carbon thin films were deposited in an energy range between 220 and 370 eV with hardness values up to 4000 HV0.05. They are insulating, optically transparent and show a high degree of hardness combined with high compressive stress in the order of 4 GPa as well as a low adhesion, which means that the critical ...

1999-09-01

481

Enhancement of Au nanoparticles formed by in situ electrodeposition on direct electrochemistry of myoglobin loaded into layer-by-layer films of chitosan and silica nanoparticles.  

Science.gov (United States)

In the present work, a new kind of myoglobin (Mb)/Au nanoparticles composite film was fabricated on pyrolytic graphite (PG) electrodes. Oppositely charged chitosan (CS) and silica (SiO(2)) nanoparticles were alternately adsorbed on the PG surface by the electrostatic interaction between them, forming {CS/SiO(2)}(5) layer-by-layer films. Mb and HAuCl(4) in solution were then simultaneously loaded into {CS/SiO(2)}(5) films. The loaded Au(III) in the films were electrochemically reduced into Au nanoparticles, forming nanocomposite films, designated as {CS/SiO(2)}(5)-Mb-Au. Various techniques such as cyclic voltammetry (CV), square wave voltammetry (SWV), quartz crystal microbalance (QCM), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), and energy dispersive X-ray (EDX) analysis were used to characterize the films. Compared with {CS/SiO(2)}(5)-Mb films without Au nanoparticles inside, the {CS/SiO(2)}(5)-Mb-Au films exhibited much ...

2008-12-01

482

Development of Pyro-separation Technology Based on Molten Salt Electrolysis  

International Nuclear Information System (INIS)

The focus of this study was to develop recovery technologies in the pyroprocessing. The unit processes of the project can be classified into two groups; electro-refining process to recover uranium and long-lived nuclides, and cathode processing to produce a metal ingot both from a salt-contained metal and from Cd-contained metal. This project has been carried out for the third phase period of the long-term nuclear R and D program, and focused on the development of key technologies of the pyroprocessing such as electrorefining, draw down and cathode processing. Mock-up system of 1 kg-U/batch was built for performance tests which were conducted to ensure the adequacy of the research and development of the pyroprocessing technology. The experiments were carried out through bench-scale inactive tests except for uranium. In particular, the sticking problem was inevitable in the US's Mark-V and PEER electrorefiner. As a result of this study, a graphite cathode was ...

2001-07-18

483

Criticality calculations of the fixed bed nuclear reactor  

Energy Technology Data Exchange (ETDEWEB)

The Fixed Bed Nuclear Reactor (FBNR) is a small 40 MWe reactor based on the Pressurized Water Reactor (PWR) technology. FBNR is an integrated primary circuit and simple in design. It has the characteristics of being small, modular, proliferation resistant, inherently safe and passively cooled reactor with reduced adverse environmental impact. It utilizes the fuel designed for high temperature reactors operating in a relatively low temperature of PWR environment The 15 mm diameter spherical fuel elements are made of TRISO type microspheres embedded in graphite and cladded by SiC. The coolant flow transfers them from the fuel chamber into the core and become fixed forming a suspended core. Any accident signal will cut off the power to the coolant pump causing a stop in the flow. This results in making the fuel elements fall out of the reactor core by the force of gravity and return into the fuel chamber where they are passively cooled under subcritical condition. ...

2007-07-01

484

Comparative study of polymer matrices for gelled electrolytes of lithium batteries; Etude comparative de matrices polymeres pour electrolytes gelifies de batteries au lithium  

Energy Technology Data Exchange (ETDEWEB)

A solid electrolyte for lithium batteries requires several properties: a good ionic conductivity of about 10{sup -3} S/cm at 298 deg. K, a high cationic transport number (greater than 0.5), a redox stability window higher than 4.5 V, a good stability of the interface with the lithium electrode, and a sufficient mechanical stability. The family of gelled or hybrid electrolytes seems to meet all these requirements. Thus, a systematic study of the gelling of an ethylene carbonate and lithium bistrifluorosulfonimide (LiTFSI) based electrolyte has been carried out. The polymers used for gel or pseudo-gel synthesis are POE, PMMA and PAN which represent 3 different cases of interaction with the electrolyte. All the properties mentioned above have been studied according to the nature of the polymer and to the concentration of lithium salt, showing the advantages and drawbacks of each polymer. The possibility of using some of these gels in lithium-ion batteries has been tested by lithium ...

1996-12-31

485

Two-phase flow modeling in the rod bundle subchannel analysis; Modelisation d'ecoulement a deux phases dans l'analyse du sous-canal de grappe d'assemblages  

Energy Technology Data Exchange (ETDEWEB)

In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic modeling approach. They should include also influences of the multi-dimensional ...

2006-07-01

486

Impacts of climate change in the Netherlands; Effecten van klimaatverandering in Nederland  

Energy Technology Data Exchange (ETDEWEB)

The main conclusion of the study on the title subject is that the impacts of climatic change in the Netherlands are still limited. However, the impacts will be stronger in the next decades and will be even problematic at the end of this century. In this book an overview is given of probable changes in the climate for the Netherlands, danger for flooding in specific areas of the Netherlands, changes of the nature, impacts for agriculture, tourism and recreation, and industry and businesses, and risks for public health. [Dutch] De effecten van klimaatverandering in Nederland zijn nu nog beperkt. Ze zullen echter de komende decennia toenemen, maar pas tegen het eind van deze eeuw problematisch worden. Dat is de hoofdboodschap van de titelstudie. De studie is opgesteld in samenwerking met een reeks instellingen, die zijn verenigd in het Platform Communicatie Klimaatverandering (PCCC). Het klimaat verandert: de zeespiegel stijgt, de afvoeren van de rivieren nemen toe. De natuur reageert al ...

2005-10-01

487

The law aspects of biotechnology patenting. The living source between discovery and invention; Aspetti giuridici del brevetto biotecnologico. La materia vivente tra scoperta e invenzione  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to provide a comprehensive and consistent description of the complexity of laws regulating the field of biotechnology, mainly focusing on the definition of items to be patented, which is one of the most important and also controversial issues within the new 98/44/EC set of rules. As biotechnology is a specialist and multidisciplinary field, it has begun by giving a general description of the field, outlining the grounds for the new rules, and then thoroughly examined and evaluated previous national and international laws especially with regard to patenting. This was followed by an evaluation of what can be patented according to the new instructions by systematically assessing the section defining items to be patented in the field of biotechnology. It is used to be a matter of opinion whether biotechnological material was to be considered a discovery or an invention, the former being impatentable according to patenting laws. The new law pays particular attention ...

2001-07-01

488

CT assessment of thoracic gunshot wounds. Our personal experience; Ruolo della Tomografia Computerizzata nelle lesioni da arma da fuoco del torace. Esperienza personale  

Energy Technology Data Exchange (ETDEWEB)

CT is a valuable tool in assessing thoracic gunshot wounds. CT is also the method of choice in emergency, because it permits rapid depiction of bullet damage to the chest and to other body districts. This in turn permits correct assessment of the main thoracic injuries, plus adequate and prompt planning of surgical treatment or support intensive care. It is reported on the role of CT in diagnosing the complex pleuropulmonary, cardiovascular and thoracic wall injuries caused by gunshot wounds, with their specific and acute signs which differ greatly fro those of other types of chest trauma. In the last 4 years, it was observed an amount of 76 cases of gunshot injury, twenty-six of them involved the chest. The patients, 25 men and 1 woman (mean age: 32 years, range: 17-48), were all submitted to emergency CT with iv contrast agent injection and the CT-angiography technique. The reanimator was always presented to monitor the patients' vital functions and shock state. CT of the ...

1999-11-01

489

Anatomic and radiologic correlations in spontaneous hematomas of the rectus abdomninis muscles; Correlazioni anatomo-radiologiche negli ematomi spontanei dei muscoli retti dell'addome  

Energy Technology Data Exchange (ETDEWEB)

Rectus sheath hematomas are a frequent but sometimes misdiagnosed disease in patients under anticoagulative drugs, hemodialysis, or simply in the elderly. The most frequent localization is in the lower part of the abdomen: the explanation lies in the anatomy of the abdominal wall, especially in the arcuate line of the rectus sheath. Aim of this work is to explain the reason of the almost constant location correlating the anatomy with the CT features. The rectus abdominis muscle lies between the aponeuroses of the transverse and oblique muscles which form the so called rectus sheath. This arrangement is found from the costal arch to a level approximately between the umbilicus and the pubic symphisis, where the rear layer of the rectus sheath ends with a curved edge, called the arcuate or semicircular line of Douglas. Beneath this line the aponeuroses of the three muscles pass in front of the rectus which is separated from the peritoneum only by the fascia trasversalis, a thin connective ...

2000-06-01

490

Abdominal adipose tissue distribution in obese children. US versus CT measurements; Valutazione della distribuzione del tessuto adiposo addominale nei bambini obesi. Confronto tra ecografia e Tomografia Computerizzata  

Energy Technology Data Exchange (ETDEWEB)

Computed Tomography (CT) and, more recently, ultrasound (US), have proved excellent tools for quantifying adipose tissue distribution. Body fat distribution is an important factor in the treatment of obesity and its complications. In this work it is investigated the correlation between CT and US measurements in pediatric obesity. Forty obese children and adolescents aged 4.1-14.8 years were submitted to CT and US. Intra-abdominal, subcutaneous and total body fat were calculated (in cm{sup 2}), with the CT image analysis software. The rectus muscle-spine and rectus muscle-aorta distances, as indicative of visceral fat thickness, were measured on US images with(out) compression. The distance between skin fat and fat-rectus muscle interfaces was measured as subcutaneous fat thickness. US-CT findings have been compared with other morphometric variables-i.e., patient's (ideal) body weight and skin fold measures. A statistically significant correlation was found between the CT ...

1999-12-01

491

AIDS and lung infection by Mycobacterium xenopi. Role of Computed Tomography; Sindrome da immunodeficienza acquisita e malattie polmonari da Mycobacterium xenopi. Ruolo della Tomografia Computerizzata  

Energy Technology Data Exchange (ETDEWEB)

Mycobacterium xenopi is one of the most common agents responsible for nontubercolar mycobacterial pulmonary disease on AIDS patients. These lesions have been studied with conventional radiography while CT has been used in patients with aspecific mycobacterioses or non-AIDS pulmonary conditions from Mycobacterium xenopi. 12 AIDS patients were examined. They had pulmonary lesions from Mycobacterium xenopi, patients age ranged 30 to 46 years. All patients had CD4 blood levels lower than 250 cells/mL and Mycobacterium xenopi in the sputum. All patients underwent a standard chest radiograph and a CT examination. CT images were evaluated by three radiologists independently and the definitive diagnosis was made in the presence of a fourth radiologist. Chest CT showed parenchymal consolidation in 66% of cases, associated with bilateral basal bands in 16% of cases. Consolidation was unilateral in 41% of cases and most frequently involved the right lower lobe. Bilateral reticular interstitial ...

2000-06-01

492

Gunshot wounds to the head. Correlations between CT and clinical findings, neurosurgical treatment and long-term sequels; Traumi cranio-encefalici da proiettile: correlazione tra tomografia computerizzata, clinica, trattamento neurochirurgico e sequele a distanza  

Energy Technology Data Exchange (ETDEWEB)

With the aim of demonstrating the usefulness of computerised tomography (CT) findings in the planning of brain neurosurgery in gunshot victims, for prompt and successful treatment, 30 patients with brain gunshot wounds were examined with CT over 5 years. The mortality rate of firearm wounds of the skull base was 34% higher than that of the hemisphere; this is due to carotid hemorrhage and midbrain damage. Such traumas require emergency radiological diagnosis and neurosurgical treatment because of their severity and early irreversible complications. Complex operations and skilled surgeons may prevent disabling postoperative sequels. CT findings are indispensable and must be correctly interpreted. The radiologist and the neurosurgeon must collaborate closely and both must consider several diagnostic factors affecting surgical planning. [Italian] Scopo dello studio e' stato quello di dimostrare l'utilita' della semeiologia della tomografia computerizzata in ...

2000-03-01

493

Decommissioning of French nuclear submarines  

Energy Technology Data Exchange (ETDEWEB)

Since the beginning of the sixties, France has developed a fleet of nuclear powered vessels. Insofar as the ships of the 2. generation are being built, the older ones are decommissioned and enter the dismantling process. The average rate is presently one submarine decommissioned every two or three years. The overall strategy for the decommissioning of French nuclear submarines can be brought down to 3 phases: 1. Level 1 dismantling which essentially consists in: - unloading the spent fuel and storing it in a pool ; - possibly emptying the circuits which contain radioactive liquids. The level 1 is easily achieved, as it is not very different from the plant situation during ship overhaul or major refits. 2. Level 2 dismantling which consists in isolating the nuclear reactor compartment from the rest of the submarine and conditioning it for interim storage on a ground facility located inside Cherbourg Naval Dockyard. The rest of the ship is decontaminated, controlled and set for scrap ...

2003-07-01

494

Coupled effects of the precipitation of secondary species on the mechanical behaviour and chemical degradation of concretes; Les effets couples de la precipitation d'especes secondaires sur le comportement mecanique et la degradation chimique des betons  

Energy Technology Data Exchange (ETDEWEB)

Sulfate attack of cement-based materials remains an important problem for the durability assessment of containers and disposal engineering barriers dedicated to the long-term storage of radioactive wastes since underground water which may reach these elements contains small quantities of sulfates (7-31 mmol/1). This work contributes to the study of sulfate-induced damage mechanisms, to their understanding and modelling. The experimental phases of this study aimed at the understanding of the different physico-chemical phenomena involved during an external sulfate attack at following their evolution and their impact on the transport and mechanical properties of the material. Leaching experiments in pure water and in a solution of sodium sulfate (with a sulfate content of 15 mmol/1), have been performed simultaneously on OPC paste (w/c 0,4)in order to allow a comparison of test results. The frequent analysis of the leachant has shown a consumption of sulfate ions by the matrix, ...

2002-06-01

495

Helical CT of traumatic injuries of the thoracic aorta; Applicazioni della Tomografia Computerizzata spirale nello studio delle lesioni traumatiche dell'aorta toracica  

Energy Technology Data Exchange (ETDEWEB)

Acute thoracic aortic injuries account for up to 10-20% of fatalities in high-speed deceleration road accidents and have an estimated immediate fatality rate of 80-90%. Untreated survivors to acute trauma (10-20%) have a dismal prognosis: 30% of them die within 6 hours, 40-50% die within 24 hours, and 90% within 4 months. It was investigated the diagnostic accuracy of Helical Computed Tomography (Helical CT) in acute traumatic injuries of the thoracic aorta, and the role of this technique in the diagnostic management of trauma patients with a strong suspicion of aortic rupture. It was compared retrospectively the chest Helical CT findings of 256 trauma patients examined June 1995 through August 1999. Chest Helical CT examinations were performed according to trauma score, to associated traumatic lesions and to plain chest radiographic findings. All the examinations were performed with no intravenous contrast agent administration and the pitch 2 technique. After a previous baseline ...

2000-09-01

496

ZZ GEFF-2-MATXS, Coupled Neutron-Gamma Fusion Neutronics Library in MATXS Format  

International Nuclear Information System (INIS)

1 - Description of program or function: This library for fusion neutronics calculations, to be used in conjunction with the TRANSX code, is the MATXS format version of ZZ-GEFF-2-GENDF from which it has been derived by means of the MATXSR NJOY module. It has a 175 neutron, 42 photon VITAMIN-J group structure with the standard weighting function: Maxwellian (at the temperature to which the material is referenced) + 1/E + fission spectrum + 1/E + fusion peak + 1/E. It includes 93 materials from 1-H-1 to Bi-209 - almost all from EFF-2 basic data; but Ag-107, Ag-109, natural Cd, the 6 Hf isotopes and the 4 W isotopes have been taken from JEF-2.2 - at 3 temperatures and 6 dilution cross section values; 10 thermal groups are provided below 3 eV. Neutron cross sections and diffusion matrices, photon and gas production, kerma and DPA are given. The library includes H in H2O, metallic Be and Graphite for which an accurate treatment with S(alpha, beta) matrices has been ...

1997-04-01

497

Development of SiC-AlN and SiC-SiAlON refractory composites  

International Nuclear Information System (INIS)

SiC-AlN and SiC-SiAlON refractory composites were obtained by means of nitridation of the mixtures of silicon carbide (SiC) powder with a broad granulometric distribution and powders of aluminium (Al) and aluminium-silicon (Al-Si) mixtures. The mixtures of the composition Al-25% Si, Al-50% Si and Al-75% Si were previously prepared by means of 'mechanical alloying' technique. Thermodynamic analysis was accomplished in order to evaluate the viability of SiC-SiAlON and SiC-AlN refractories production by the chosen processing method, and the results confirmed viability of such. Investigation of nitridation of Al and Al-Si powder compacts in order to obtain the AlN and #beta#-SiAlON matrix phases of the composite was accomplished by means of differential thermal analysis (DTA) and thermogravimetric analysis (TG). The results of the thermal analysis show that nitridation of the Al-25% Si, Al-50% Si and Al-75% Si resulting in p-SiAlON formation occur at temperatures of 910 deg C, 811 deg C ...

498

Blood cadmium concentrations in the general population of Umbria, Central Italy  

Energy Technology Data Exchange (ETDEWEB)

The aims of this study were (a) to assess blood cadmium (B-Cd) concentrations and to establish a tentative reference interval; (b) to identify significant determinants of B-Cd, in a population from Umbria, Central Italy, which was not occupationally exposed to cadmium (Cd). Four hundred and thirty-four healthy blood-donors volunteered to answer a questionnaire and provide a blood sample for B-Cd analysis, which was performed by graphite furnace atomic absorption spectrophotometry. Blood Cd concentrations ranged from non-detectable values, i.e. below 0.1 {mu}g/l up to 3.4 {mu}g/l and were not normally distributed. The median values and the 95th percentiles were 0.7 and 2.0 {mu}g/l, respectively. Concentrations of B-Cd were more than double in smokers than in non-smokers, median values being 1.1 {mu}g/l and 0.5 {mu}g/l, respectively. In current smokers, B-Cd values correlated with the number of cigarettes smoked daily (r{sub s}=0.40, P=0.0001) and with the cumulative ...

1999-02-02