Classical Nucleation Theory- Power Remarks
Němec, T.; Maršík, František
Kyoto : Maruzen Co., Ltd, 2005 - (Nakahara, M.; Matubayasi, N.; Ueno, M.; Yasuoka, K.; Watanabe, K.), s. 220-225 ISBN 4-621-07596-9. [International Conference on the Properties of Water and Steam /14./. Kyoto (JP), 29.08.2004-03.09.2004] R&D Projects: GA AV ČR(CZ) IBS2076003; GA ČR(CZ) GA101/02/0364 Institutional research plan: CEZ:AV0Z20760514 Keywords : binary * nucleation * power cycle chemistry Subject RIV: BJ - Thermodynamic s
Revision of the classical nucleation theory for supersaturated solutions
Borisenko, Alexander
2015-01-01
During the processes of nucleation and growth of a precipitate cluster from a supersaturated solution, the diffusion flux between the cluster and the solution changes the solute concentration near the cluster-solution interface from its average bulk value. This feature affects the rates of attachment and detachment of solute atoms at the interface and, therefore, alters the entire nucleation kinetics. Unless quite obvious, this effect has been ignored in the classical nucleation theory. To illustrate the results of this new approach, for the case of homogeneous nucleation, we calculate the total solubility (including the contribution from heterophase fluctuations) and the nucleation rate as functions of two parameters of the model and compare these results to the classical ones. One can conclude that discrepancies with the classical nucleation theory are great in the diffusion-limited regime, when the bulk diffusion mobility of solute atoms is small compared to the interfacial one, while in the opposite inter...
Ice Nucleation on Carbon Surface Supports the Classical Theory for Heterogeneous Nucleation
Cabriolu, Raffaela
2015-01-01
The prevalence of heterogeneous nucleation in nature was explained qualitatively by the classical theory for heterogeneous nucleation established over more than 60 years ago, but the quantitative validity and the key conclusions of the theory have remained unconfirmed. Employing the forward flux sampling method and the coarse-grained water model mW, we explicitly computed the heterogeneous ice nucleation rates in the supercooled water on a graphitic surface at various temperatures. The independently calculated ice nucleation rates were found to fit well according to the classical theory for heterogeneous nucleation. The fitting procedure further yields the estimate of the potency factor which measures the ratio of the heterogeneous nucleation barrier to the homogeneous nucleation barrier. Remarkably, the estimated potency factor agrees quantitatively with the volumetric ratio of the critical nuclei between the heterogeneous and homogeneous nucleation. Our numerical study thus provides a strong support to the ...
Refining Predictions of the Classical Nucleation Theory
Němec, Tomáš; Maršík, František; Krejčí, A. Petr
Mount Laurel : AAAR, 2006 - (Biswas, P.; Chen, D.; Hering, S.), s. 1599-1600 ISBN 0-9788735-0-5. [IAC 2006 /7./. St. Paul (US), 10.09.2006-15.09.2006] R&D Projects: GA MŠk(CZ) 1P05ME726 Institutional research plan: CEZ:AV0Z20760514 Keywords : binary nucleation * microscopic surface tension Subject RIV: BJ - Thermodynamics
Classical nucleation theory for cavitation processes in water
Němec, Tomáš; Maršík, František
Antalya : HEFAT, 2010 - (Meyer, J.), s. 2035-2040 ISBN 978-1-86854-818-7. [International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics (HEFAT2010) /7./. Antalya (TR), 19.07.2010-21.07.2010] R&D Projects: GA ČR(CZ) GA106/08/0557; GA ČR GAP101/10/1819 Institutional research plan: CEZ:AV0Z20760514 Keywords : cavitation * classical nucleation theory * water Subject RIV: BJ - Thermodynamics
Fluctuations, temperature, and detailed balance in classical nucleation theory
McGraw, R. [Environmental Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973 (United States); LaViolette, R.A. [Idaho National Engineering Laboratory, P.O. Box 1625, Idaho Falls, Idaho 83415 (United States)
1995-06-08
The role of temperature in classical nucleation theory is examined. It is shown that while even small clusters are assigned a temperature in the classical theory, this must be a fluctuating quantity. Stochastic simulations of cluster evaporation and growth are presented to track the temperature fluctuations in time. The relation {l_angle}{vert_bar}{delta}{ital T}{vert_bar}{sup 2}{r_angle}={ital kT}{sup @2}{ital d}0/{ital C}{sub {nu}} for the mean square temperature fluctuation is confirmed, where {ital k} is the Boltzmann constant, {ital C}{sub {nu}} is the cluster heat capacity, and {ital T}{sub 0} is the bath temperature. For small capillary drops (50--100 molecules), the resulting rms temperature fluctuations of 10{degree}--20{degree} might be expected to have a significant effect on the nucleation rate. However, the simulations reveal a cluster temperature distribution that is centered several degrees below {ital T}{sub 0}. A theory is presented to explain this effect. To first order, which includes Gaussian fluctuations of the cluster temperature {ital T}, we find that the effective temperature for cluster evaporation is {ital T}{minus}{ital h}/2{ital C}{sub {nu}}, where {ital h} is the latent heat. This temperature correction is precisely that required by detailed balance and results both in a centering of the cluster temperature distribution on {ital T}{sub 0} and a cancellation of any significant effect of temperature fluctuations on the nucleation rate.
Microscopic Surface Tension in the Classical Nucleation Theory
Němec, Tomáš; Maršík, František
Praha : Institute of Chemical Process Fundamentals ASCR, v.v , Czech Aerosol Society, 2009 - (Smolík, J.; O´Dowd, C.), s. 561-654 ISBN 978-80-02-12161-2. [International Conference Nucleation and Atmospheric Aerosol /18./. Praha (CZ), 10.08.2009-14.08.2009] R&D Projects: GA AV ČR KJB400760701 Institutional research plan: CEZ:AV0Z20760514 Keywords : nucleation theory * multicomponent condensation * surface adsorption Subject RIV: BK - Fluid Dynamics
Limits of the applicability of the classical nucleation theory
Kožíšek, Zdeněk; Demo, Pavel; Sveshnikov, Alexey
Valencia: American Scientific Publishers, 2015 - (Kožíšek, Z.; Nitsch, K.; Koman, M.; Behúlová, M.), s. 316-320 ISSN 2164-6627. [Development of Materials Science and Education 2013 (DMSRE23). Kežmarské Žľaby (SK), 09.09.2013-13.09.2013] R&D Projects: GA ČR GAP108/12/0891 Institutional support: RVO:68378271 Keywords : nucleation * encapsulated systems Subject RIV: BM - Solid Matter Physics ; Magnetism
Limits of the applicability of classical nucleation theory
Kožíšek, Zdeněk; Demo, Pavel; Sveshnikov, Alexey
Bratislava: Slovak Expert Group of Solid State Chemistry and Physics, 2013 - (Koman, M.; Jorík, V.; Kožíšek, Z.). s. 27 ISBN 978-80-970896-5-8. [Joint Seminar Development of Materials Science in Research and Education /23./. 09.09.2013-13.09.2013, Kežmarské Žĺaby] R&D Projects: GA ČR GAP108/12/0891 Institutional support: RVO:68378271 Keywords : nucleation * phase transition Subject RIV: BM - Solid Matter Physics ; Magnetism http:// dms .fzu.cz/proceedings/ DMS RE23.pdf
Borisenko, Alexander
2016-05-01
During the processes of nucleation and growth of a precipitate cluster from a supersaturated solution, the diffusion flux between the cluster and the solution changes the solute concentration near the cluster-solution interface from its average bulk value. This feature affects the rates of attachment and detachment of solute atoms at the interface, and, therefore, the entire nucleation-growth kinetics is altered. Unless quite obvious, this effect has been ignored in classical nucleation theory. To illustrate the results of this approach, for the case of homogeneous nucleation, we calculate the total solubility and the nucleation rate as functions of two parameters of the model (the reduced interface energy and the inverse second Damköhler number), and we compare these results to the classical ones. One can conclude that discrepancies with classical nucleation theory are great in the diffusion-limited regime, when the rate of bulk diffusion is small compared to the rate of interface reactions, while in the opposite interface-limited case they vanish.
Chen, Xuelian; Schröder, Jan; Hauschild, Stephan; Rosenfeldt, Sabine; Dulle, Martin; Förster, Stephan
2015-10-27
Despite the increasing interest in the applications of functional nanoparticles, a comprehensive understanding of the formation mechanism starting from the precursor reaction with subsequent nucleation and growth is still a challenge. We for the first time investigated the kinetics of gold nanoparticle formation systematically by means of a lab-based in situ small-angle X-ray scattering (SAXS)/wide-angle X-ray scattering (WAXS)/UV-vis absorption spectroscopy experiment using a stopped-flow apparatus. We thus could systematically investigate the influence of all major factors such as precursor concentration, temperature, the presence of stabilizing ligands and cosolvents on the temporal evolution of particle size, size distribution, and optical properties from the early prenucleation state to the late growth phase. We for first time formulated and numerically solved a closed nucleation and growth model including the precursor reaction. We observe that the results can be well described within the framework of classical nucleation and growth theory, including also results of previous studies by other research groups. From the analysis, we can quantitatively derive values for the rate constants of precursor reaction and growth together with their activation free enthalpies. We find the growth process to be surface-reaction limited with negligible influence of Ostwald ripening yielding narrow disperse gold nanoparticles. PMID:26393805
Scaling relations are developed for the number g* of molecules in the critical nucleus and the nucleation barrier height W*. Density functional (DF) calculations for vapor-liquid nucleation confirm these relations and show systematic departure of the ratio W*/g*Δμ from its classical value of 1/2 with increasing difference Δμ in the chemical potential between the supersaturated vapor and bulk condensed phase. Discrepancies between classical and DF nucleation theories and between the classical theory and experiment are interpreted using these results. copyright 1996 The American Physical Society
Němec, Tomáš
Vol. 1. Liberec: Technical University of Liberec, 2010 - (Vít, T.; Dančová, P.), s. 439-451 ISBN 978-80-7372-670-6. [International Conference Experimental Fluid Mechanics 2010. Liberec (CZ), 24.11.2010-26.11.2010] R&D Projects: GA ČR GAP101/10/1819; GA ČR GAP101/10/1428 Institutional research plan: CEZ:AV0Z20760514 Keywords : cavitation * nucleation rate * refrigerants Subject RIV: BJ - Thermodynamics
A rigorous thermodynamic formulation of the geometric model for heterogeneous nucleation including line tension effect is missing till date due to the associated mathematical hurdles. In this work, we develop a novel thermodynamic formulation based on Classical Nucleation Theory (CNT), which is supposed to illustrate a systematic and a more plausible analysis for the heterogeneous nucleation on a planar surface including the line tension effect. The appreciable range of the critical microscopic contact angle (θc), obtained from the generalized Young’s equation and the stability analysis, is θ∞ < θc < θ′ for positive line tension and is θM < θc < θ∞ for negative line tension. θ∞ is the macroscopic contact angle, θ′ is the contact angle for which the Helmholtz free energy has the minimum value for the positive line tension, and θM is the local minima of the nondimensional line tension effect for the negative line tension. The shape factor f, which is basically the dimensionless critical free energy barrier, becomes higher for lower values of θ∞ and higher values of θc for positive line tension. The combined effect due to the presence of the triple line and the interfacial areas (fL + fS) in shape factor is always within (0, 3.2), resulting f in the range of (0, 1.7) for positive line tension. A formerly presumed appreciable range for θc(0 < θc < θ∞) is found not to be true when the effect of negative line tension is considered for CNT. Estimation based on the property values of some real fluids confirms the relevance of the present analysis
Sahyoun, Maher; Wex, Heike; Gosewinkel, Ulrich; Šantl-Temkiv, Tina; Nielsen, Niels W.; Finster, Kai; Sørensen, Jens H.; Stratmann, Frank; Korsholm, Ulrik S.
2016-08-01
Bacterial ice-nucleating particles (INP) are present in the atmosphere and efficient in heterogeneous ice-nucleation at temperatures up to -2 °C in mixed-phase clouds. However, due to their low emission rates, their climatic impact was considered insignificant in previous modeling studies. In view of uncertainties about the actual atmospheric emission rates and concentrations of bacterial INP, it is important to re-investigate the threshold fraction of cloud droplets containing bacterial INP for a pronounced effect on ice-nucleation, by using a suitable parameterization that describes the ice-nucleation process by bacterial INP properly. Therefore, we compared two heterogeneous ice-nucleation rate parameterizations, denoted CH08 and HOO10 herein, both of which are based on classical-nucleation-theory and measurements, and use similar equations, but different parameters, to an empirical parameterization, denoted HAR13 herein, which considers implicitly the number of bacterial INP. All parameterizations were used to calculate the ice-nucleation probability offline. HAR13 and HOO10 were implemented and tested in a one-dimensional version of a weather-forecast-model in two meteorological cases. Ice-nucleation-probabilities based on HAR13 and CH08 were similar, in spite of their different derivation, and were higher than those based on HOO10. This study shows the importance of the method of parameterization and of the input variable, number of bacterial INP, for accurately assessing their role in meteorological and climatic processes.
Unification of classical nucleation theories via a unified Itô-Stratonovich stochastic equation.
Durán-Olivencia, Miguel A; Lutsko, James F
2015-09-01
Classical nucleation theory (CNT) is the most widely used framework to describe the early stage of first-order phase transitions. Unfortunately, the different points of view adopted to derive it yield different kinetic equations for the probability density function, e.g., Zeldovich-Frenkel or Becker-Döring-Tunitskii equations. Starting from a phenomenological stochastic differential equation, a unified equation is obtained in this work. In other words, CNT expressions are recovered by selecting one or another stochastic calculus. Moreover, it is shown that the unified CNT thus obtained produces the same Fokker-Planck equation as that from a recent update of CNT [J. F. Lutsko and M. A. Durán-Olivencia, J. Chem. Phys. 138, 244908 (2013)10.1063/1.4811490] when mass transport is governed by diffusion. Finally, we derive a general induction-time expression along with specific approximations of it to be used under different scenarios, in particular, when the mass-transport mechanism is governed by direct impingement, volume diffusion, surface diffusion, or interface transfer. PMID:26465482
Witharana, S; Strobel, S; Kim, H D; McKrell, T; Chang, J -B; Buongiorno, J; Berggren, K K; Chen, L; Ding, Y
2012-01-01
Recently-reported data suggest that bubble nucleation on surfaces with nano-sized features (cavities and posts) may occur close to the thermodynamic saturation temperature. However, according to the traditional theory of heterogeneous bubble nucleation, such low nucleation temperatures are possible only for surfaces with micro-scale cavities. Motivated by this apparent contradiction, we have used infrared thermometry to measure the nucleation temperature of water on custom-fabricated nano- to micro-scale cavities (from 90 nm to 4.5 um in diameter) and posts (from 60 nm to 5 um in diameter), machined on ultra-smooth and clean silicon wafers using electron beam lithography. Our cavity data are in agreement with the predictions of the Young-Laplace equation, thus re-affirming the correctness of the classic view of heterogeneous bubble nucleation, at least for the water-silicon system investigated here. The data also suggest that individual posts of any size have an insignificant effect on bubble nucleation, as e...
Němec, Tomáš
Londýn: British & Irish Association for Properties of Water and Steam (BIAPWS) a Institution of Mechanical Engineers, 2013, 063-063. [International Conference on the Properties of Water and Steam /16./ ICPWS. University of Greenwich, Londýn (GB), 01.09.2013-05.09.2013] R&D Projects: GA ČR GAP101/10/1819 Institutional research plan: CEZ:AV0Z20760514 Keywords : ice nucleation * interfacial energy * supercooled water
Comment on "Simple improvements to classical bubble nucleation models"
Schmelzer, Jürn W. P.; Baidakov, Vladimir G.
2016-08-01
A critical analysis of several statements concerning experimental studies, molecular dynamics simulations, and the theoretical interpretation of bubble nucleation processes is performed. In particular, it is shown that the Tolman equation does not supply us, in general, with a satisfactory theoretically founded description of the curvature dependence of the surface tension and the dependence of the steady-state nucleation rate of bubbles and droplets on supersaturation in the framework of classical nucleation theory.
Principles of nucleation theory
The nucleation of small stable species is described in the problem of void growth by discrete rate equations. When gas is being produced the problem reduces to one of calculating the incubation dose for the gas bubble to void transition. A general expression for the steady state nucleation rate is derived for the case when voids are formed by vacancy fluctuations which enable an effective nucleation barrier to be crossed. (author)
Němec, Tomáš
2013-01-01
Roč. 583, September (2013), s. 64-68. ISSN 0009-2614 R&D Projects: GA ČR GAP101/10/1819 Institutional research plan: CEZ:AV0Z20760514 Institutional support: RVO:61388998 Keywords : ice nucleation * supercooled water * interfacial energy Subject RIV: BJ - Thermodynamics Impact factor: 1.991, year: 2013 http://www.sciencedirect.com/science/article/pii/S0009261413009913
A nanoscale temperature-dependent heterogeneous nucleation theory
Cao, Y. Y. [Nanosurface Science and Engineering Research Institute, College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen, 518060 Guangdong (China); Yang, G. W., E-mail: stsygw@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, Nanotechnology Research Center, School of Materials Science and Engineering, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou, 510275 Guangdong (China)
2015-06-14
Classical nucleation theory relies on the hypothetical equilibrium of the whole nucleation system, and neglects the thermal fluctuations of the surface; this is because the high entropic gains of the (thermodynamically extensive) surface would lead to multiple stable states. In fact, at the nanometer scale, the entropic gains of the surface are high enough to destroy the stability of the thermal equilibrium during nucleation, comparing with the whole system. We developed a temperature-dependent nucleation theory to elucidate the heterogeneous nucleation process, by considering the thermal fluctuations based on classical nucleation theory. It was found that the temperature not only affected the phase transformation, but also influenced the surface energy of the nuclei. With changes in the Gibbs free energy barrier, nucleation behaviors, such as the nucleation rate and the critical radius of the nuclei, showed temperature-dependent characteristics that were different from those predicted by classical nucleation theory. The temperature-dependent surface energy density of a nucleus was deduced based on our theoretical model. The agreement between the theoretical and experimental results suggested that the developed nucleation theory has the potential to contribute to the understanding and design of heterogeneous nucleation at the nanoscale.
Duplissy, J.; Merikanto, J.; Franchin, A.; Tsagkogeorgas, G.; Kangasluoma, J.; Wimmer, D.; Vuollekoski, H.; Schobesberger, S.; Lehtipalo, K.; Flagan, R. C.; Brus, D.; Donahue, N. M.; Vehkamäki, H.; Almeida, J.; Amorim, A.; Barmet, P.; Bianchi, F.; Breitenlechner, M.; Dunne, E. M.; Guida, R.; Henschel, H.; Junninen, H.; Kirkby, J.; Kürten, A.; Kupc, A.; Määttänen, A.; Makhmutov, V.; Mathot, S.; Nieminen, T.; Onnela, A.; Praplan, A. P.; Riccobono, F.; Rondo, L.; Steiner, G.; Tome, A.; Walther, H.; Baltensperger, U.; Carslaw, K. S.; Dommen, J.; Hansel, A.; Petäjä, T.; Sipilä, M.; Stratmann, F.; Vrtala, A.; Wagner, P. E.; Worsnop, D. R.; Curtius, J.; Kulmala, M.
2016-02-01
We report comprehensive, demonstrably contaminant-free measurements of binary particle formation rates by sulfuric acid and water for neutral and ion-induced pathways conducted in the European Organization for Nuclear Research Cosmics Leaving Outdoor Droplets chamber. The recently developed Atmospheric Pressure interface-time of flight-mass spectrometer was used to detect contaminants in charged clusters and to identify runs free of any contaminants. Four parameters were varied to cover ambient conditions: sulfuric acid concentration (105 to 109 mol cm-3), relative humidity (11% to 58%), temperature (207 K to 299 K), and total ion concentration (0 to 6800 ions cm-3). Formation rates were directly measured with novel instruments at sizes close to the critical cluster size (mobility size of 1.3 nm to 3.2 nm). We compare our results with predictions from Classical Nucleation Theory normalized by Quantum Chemical calculation (QC-normalized CNT), which is described in a companion paper. The formation rates predicted by the QC-normalized CNT were extended from critical cluster sizes to measured sizes using the UHMA2 sectional particle microphysics model. Our results show, for the first time, good agreement between predicted and measured particle formation rates for the binary (neutral and ion-induced) sulfuric acid-water system. Formation rates increase with RH, sulfuric acid, and ion concentrations and decrease with temperature at fixed RH and sulfuric acid concentration. Under atmospheric conditions, neutral particle formation dominates at low temperatures, while ion-induced particle formation dominates at higher temperatures. The good agreement between the theory and our comprehensive data set gives confidence in using the QC-normalized CNT as a powerful tool to study neutral and ion-induced binary particle formation in atmospheric modeling.
Nucleation theory beyond the deterministic limit. I. The nucleation stage.
Dubrovskii, V G; Nazarenko, M V
2010-03-21
This work addresses theory of nucleation and condensation based on the continuous Fokker-Plank type kinetic equation for the distribution of supercritical embryos over sizes beyond the deterministic limit, i.e., keeping the second derivative with respect to size. The first part of the work treats the nucleation stage. It is shown that the size spectrum should be generally obtained by the convolution of the initial distribution with the Gaussian-like Green function with spreading dispersion. It is then demonstrated that the fluctuation-induced effects can be safely neglected at the nucleation stage, where the spectrum broadening due to the nonlinear boundary condition is much larger than the fluctuational one. The crossover between the known triangular and double exponential distributions under different conditions of material influx into the system is demonstrated. Some examples of size distributions at the nucleation stage in different regimes of material influx are also presented. PMID:20331305
Theory and Simulation of Nucleation
Kuipers, J.
2009-01-01
Nucleation is the process where a stable nucleus spontaneously emerges in a metastable environment. Examples of nucleation abound, for instance the formation of droplets in undercooled gasses and of crystals in undercooled liquids. The process is thermally activated and is key to understanding vario
Classical and quantum effective theories
Polonyi, Janos
2014-01-01
A generalization of the action principle of classical mechanics, motivated by the Closed Time Path (CTP) scheme of quantum field theory, is presented to deal with initial condition problems and dissipative forces. The similarities of the classical and the quantum cases are underlined. In particular, effective interactions which describe classical dissipative forces represent the system-environment entanglement. The relation between the traditional effective theories and their CTP extension is briefly discussed and few qualitative examples are mentioned.
Recent developments in the kinetic theory of nucleation.
Ruckenstein, E; Djikaev, Y S
2005-12-30
, but the hierarchy of time scales does allow one to reduce it to the Fokker-Plank equation in the energy space. The new theory provides an equation for the critical radius of a new-phase particle which in the limit of large clusters (low supersaturations) yields the Kelvin equation and hence an expression for the macroscopic surface tension. The theory was illustrated with numerical calculations for a molecular pair interaction potential combining the dispersive attraction with the hard-sphere repulsion. The results for the liquid-to-solid nucleation clearly show that at given supersaturation the nucleation rate depends on the cluster structure (for three cluster structures considered-amorphous, fcc, and icosahedral). For both the liquid-to-solid and vapor-to-liquid nucleation, the predictions of the theory are consistent with the results of classical nucleation theory (CNT) in the limit of large critical clusters (low supersaturations). For small critical clusters the new theory provides higher nucleation rates than CNT. This can be accounted for by the fact that CNT uses the macroscopic interfacial tension which presumably overpredicts the surface tension of small clusters, and hence underpredicts nucleation rates. PMID:16137628
Nucleation theory and growth of nanostructures
Dubrovskii, Vladimir G
2013-01-01
Semiconductor nanostructures such as nanowires are promising building blocks of future nanoelectronic, nanophotonic and nanosensing devices. Their physical properties are primarily determined by the epitaxy process which is rather different from the conventional thin film growth. This book shows how the advanced nucleation theory can be used in modeling of growth properties, morphology and crystal phase of such nanostructures.
Effective binary theory of multi-component nucleation
Classical theory of multi-component nucleation [O. Hirschfelder, J. Chem. Phys. 61, 2690 (1974)] belongs to the class of the so-called intractable problems: it requires computational time which is an exponential function of the number of components N. For a number of systems of practical interest with N > 10, the brute-force use of the classical theory becomes virtually impossible and one has to resort to an effective medium approach. We present an effective binary model which captures important physics of multi-component nucleation. The distinction between two effective species is based on the observation that while all N components contribute to the cluster thermodynamic properties, there is only a part of them which trigger the nucleation process. The proposed 2D-theory takes into account adsorption by means of the Gibbs dividing surface formalism and uses statistical mechanical considerations for the treatment of small clusters. Theoretical predictions for binary-, ternary-, and 14-component mixtures are compared with available experimental data and other models
Identity from classical invariant theory
A simple derivation is given of a well-known relation involving the so-called Cayley Operator of classical invariant theory. The proof is induction-free and independent of Capelli's identity; it makes use only of a known-theorem in the theory of determinants and some elementary combinatorics
Classical theory of algebraic numbers
Ribenboim, Paulo
2001-01-01
Gauss created the theory of binary quadratic forms in "Disquisitiones Arithmeticae" and Kummer invented ideals and the theory of cyclotomic fields in his attempt to prove Fermat's Last Theorem These were the starting points for the theory of algebraic numbers, developed in the classical papers of Dedekind, Dirichlet, Eisenstein, Hermite and many others This theory, enriched with more recent contributions, is of basic importance in the study of diophantine equations and arithmetic algebraic geometry, including methods in cryptography This book has a clear and thorough exposition of the classical theory of algebraic numbers, and contains a large number of exercises as well as worked out numerical examples The Introduction is a recapitulation of results about principal ideal domains, unique factorization domains and commutative fields Part One is devoted to residue classes and quadratic residues In Part Two one finds the study of algebraic integers, ideals, units, class numbers, the theory of decomposition, iner...
Classical theory of radiating strings
Copeland, Edmund J.; Haws, D.; Hindmarsh, M.
1990-01-01
The divergent part of the self force of a radiating string coupled to gravity, an antisymmetric tensor and a dilaton in four dimensions are calculated to first order in classical perturbation theory. While this divergence can be absorbed into a renormalization of the string tension, demanding that both it and the divergence in the energy momentum tensor vanish forces the string to have the couplings of compactified N = 1 D = 10 supergravity. In effect, supersymmetry cures the classical infinities.
Scaled nucleation theory for bubble nucleation of lower alkanes
Němec, Tomáš
2014-01-01
Roč. 37, č. 111 (2014), s. 69-75. ISSN 1292-8941 R&D Projects: GA ČR GAP101/10/1819; GA ČR GAP101/10/1428 Institutional support: RVO:61388998 Keywords : bubble nucleation * corresponding states * scaled nucleation rate Subject RIV: BJ - Thermodynamics Impact factor: 1.757, year: 2014
Advances In Classical Field Theory
Yahalom, Asher
2011-01-01
Classical field theory is employed by physicists to describe a wide variety of physical phenomena. These include electromagnetism, fluid dynamics, gravitation and quantum mechanics. The central entity of field theory is the field which is usually a multi component function of space and time. Those multi component functions are usually grouped together as vector fields as in the case in electromagnetic theory and fluid dynamics, in other cases they are grouped as tensors as in theories of gravitation and yet in other cases they are grouped as complex functions as in the case of quantum mechanic
Systematic coarse-graining in nucleation theory
In this work, we show that the standard method to obtain nucleation rate-predictions with the aid of atomistic Monte Carlo simulations leads to nucleation rate predictions that deviate 3 − 5 orders of magnitude from the recent brute-force molecular dynamics simulations [Diemand et al., J. Chem. Phys. 139, 074309 (2013)] conducted in the experimental accessible supersaturation regime for Lennard-Jones argon. We argue that this is due to the truncated state space the literature mostly relies on, where the number of atoms in a nucleus is considered the only relevant order parameter. We here formulate the nonequilibrium statistical mechanics of nucleation in an extended state space, where the internal energy and momentum of the nuclei are additionally incorporated. We show that the extended model explains the lack in agreement between the molecular dynamics simulations by Diemand et al. and the truncated state space. We demonstrate additional benefits of using the extended state space; in particular, the definition of a nucleus temperature arises very naturally and can be shown without further approximation to obey the fluctuation law of McGraw and LaViolette. In addition, we illustrate that our theory conveniently allows to extend existing theories to richer sets of order parameters
Systematic coarse-graining in nucleation theory
Schweizer, M.; Sagis, L. M. C.
2015-08-01
In this work, we show that the standard method to obtain nucleation rate-predictions with the aid of atomistic Monte Carlo simulations leads to nucleation rate predictions that deviate 3 - 5 orders of magnitude from the recent brute-force molecular dynamics simulations [Diemand et al., J. Chem. Phys. 139, 074309 (2013)] conducted in the experimental accessible supersaturation regime for Lennard-Jones argon. We argue that this is due to the truncated state space the literature mostly relies on, where the number of atoms in a nucleus is considered the only relevant order parameter. We here formulate the nonequilibrium statistical mechanics of nucleation in an extended state space, where the internal energy and momentum of the nuclei are additionally incorporated. We show that the extended model explains the lack in agreement between the molecular dynamics simulations by Diemand et al. and the truncated state space. We demonstrate additional benefits of using the extended state space; in particular, the definition of a nucleus temperature arises very naturally and can be shown without further approximation to obey the fluctuation law of McGraw and LaViolette. In addition, we illustrate that our theory conveniently allows to extend existing theories to richer sets of order parameters.
Applications of classical detonation theory
Davis, W.C.
1994-09-01
Classical detonation theory is the basis for almost all calculations of explosive systems. One common type of calculation is of the detailed behavior of inert parts driven by explosive, predicting pressures, velocities, positions, densities, energies, etc as functions of time. Another common application of the theory is predicting the detonation state and expansion isentrope of a new explosive or mixtures, perhaps an explosive that has not yet been made. Both types of calculations are discussed.
Classical isodual theory of antimatter
Santilli, R M
1997-01-01
An inspection of the contemporary physics literature reveals that, while matter is treated at all levels of study, from Newtonian mechanics to quantum field theory, antimatter is solely treated at the level of second quantization. For the purpose of initiating the restoration of full equivalence in the treatments of matter and antimatter in due time, in this paper we present a classical representation of antimatter which begins at the primitive Newtonian level with expected images at all subsequent levels. By recalling that charge conjugation of particles into antiparticles is anti-automorphic, the proposed theory of antimatter is based on a new map, called isoduality, which is also anti-automorphic, yet it is applicable beginning at the classical level and then persists at the quantum level. As part of our study, we present novel anti-isomorphic isodual images of the Galilean, special and general relativities and show the compatibility of their representation of antimatter with all available classical experi...
无
2001-01-01
Based on the classic diffusion controlled nucleation and growth theory, the sympathetic nucleationledgewise growth mechanism of bainite was studied theoretically for Iow carbon Fe-C alloys. The rationality of the occurrence of sympathetic nucleation on the terraces of ledges competing with lateral ledge growth and other sites nucleation was demonstrated by the present work quantitatively. The calculations indicated that Iow reaction temperatures and high carbon concentrations may favor the sympathetic nucleation, thus accounting for the formation of multilayer structures of bainite.
Systematic Coarse-Graining in Nucleation Theory
Schweizer, Marco
2015-01-01
We present a novel approach to nucleation processes based one the GENERIC framework (general equation for the nonequilibrium reversible-irreversible coupling). Solely based on the GENERIC structure of time-evolution equations and thermodynamic consistency arguments of exchange processes between a metastable phase and a nucleating phase, we derive the fundamental dynamics for this phenomenon, based on continuous Fokker-Planck equations. We are readily able to treat non-isothermal nucleation even when the nucleating cores cannot be attributed intensive thermodynamic properties. In addition, we capture the dynamics of the time-dependent metastable phase being continuously expelled from the nucleating phase, and keep rigorous track of the volume corrections to the dynamics. Within our framework the definition of a thermodynamic nuclei temperature is manifest. For the special case of nucleation of a gas phase towards its vapor-liquid coexistence, we illustrate that our approach is capable of reproducing recent lit...
Classical Electron Theory and Conservation Laws
Kiessling, Michael K. -H.
1999-01-01
It is shown that the traditional conservation laws for total charge, energy, linear and angular momentum, hold jointly in classical electron theory if and only if classical electron spin is included as dynamical degree of freedom.
Nucleation theory - Is replacement free energy needed?. [error analysis of capillary approximation
Doremus, R. H.
1982-01-01
It has been suggested that the classical theory of nucleation of liquid from its vapor as developed by Volmer and Weber (1926) needs modification with a factor referred to as the replacement free energy and that the capillary approximation underlying the classical theory is in error. Here, the classical nucleation equation is derived from fluctuation theory, Gibb's result for the reversible work to form a critical nucleus, and the rate of collision of gas molecules with a surface. The capillary approximation is not used in the derivation. The chemical potential of small drops is then considered, and it is shown that the capillary approximation can be derived from thermodynamic equations. The results show that no corrections to Volmer's equation are needed.
A novel approach to the theory of homogeneous and heterogeneous nucleation.
Ruckenstein, Eli; Berim, Gersh O; Narsimhan, Ganesan
2015-01-01
A new approach to the theory of nucleation, formulated relatively recently by Ruckenstein, Narsimhan, and Nowakowski (see Refs. [7-16]) and developed further by Ruckenstein and other colleagues, is presented. In contrast to the classical nucleation theory, which is based on calculating the free energy of formation of a cluster of the new phase as a function of its size on the basis of macroscopic thermodynamics, the proposed theory uses the kinetic theory of fluids to calculate the condensation (W(+)) and dissociation (W(-)) rates on and from the surface of the cluster, respectively. The dissociation rate of a monomer from a cluster is evaluated from the average time spent by a surface monomer in the potential well as obtained from the solution of the Fokker-Planck equation in the phase space of position and momentum for liquid-to-solid transition and the phase space of energy for vapor-to-liquid transition. The condensation rates are calculated using traditional expressions. The knowledge of those two rates allows one to calculate the size of the critical cluster from the equality W(+)=W(-) as well as the rate of nucleation. The developed microscopic approach allows one to avoid the controversial application of classical thermodynamics to the description of nuclei which contain a few molecules. The new theory was applied to a number of cases, such as the liquid-to-solid and vapor-to-liquid phase transitions, binary nucleation, heterogeneous nucleation, nucleation on soluble particles and protein folding. The theory predicts higher nucleation rates at high saturation ratios (small critical clusters) than the classical nucleation theory for both solid-to-liquid as well as vapor-to-liquid transitions. As expected, at low saturation ratios for which the size of the critical cluster is large, the results of the new theory are consistent with those of the classical one. The present approach was combined with the density functional theory to account for the density
Three Approaches to Classical Thermal Field Theory
Gozzi, E.; Penco, R.
2010-01-01
In this paper we study three different functional approaches to classical thermal field theory, which turn out to be the classical counterparts of three well-known different formulations of quantum thermal field theory: the Closed-Time Path (CTP) formalism, the Thermofield Dynamics (TFD) and the Matsubara approach.
Three approaches to classical thermal field theory
Gozzi, E.; Penco, R.
2011-04-01
In this paper we study three different functional approaches to classical thermal field theory, which turn out to be the classical counterparts of three well-known different formulations of quantum thermal field theory: the closed-time path (CTP) formalism, the thermofield dynamics (TFD) and the Matsubara approach.
Classical-field theory of thermal radiation
Rashkovskiy, Sergey A
2016-01-01
In this paper, using the viewpoint that quantum mechanics can be constructed as a classical field theory without any quantization I build a fully classical theory of thermal radiation. Planck's law for the spectral energy density of thermal radiation and the Einstein A-coefficient for spontaneous emission are derived in the framework of classical field theory without using the concept of "photon". It is shown that the spectral energy density of thermal radiation is apparently not a universal function of frequency, as follows from the Planck's law, but depends weakly on the nature of atoms, while Planck's law is valid only as an approximation in the limit of weak excitation of atoms.
Cloud base levels for Jupiter and Venus and the heteromolecular nucleation theory
Stauffer, D.; Kiang, C. S.
1974-01-01
For purified binary gas mixtures like NH3-H2O or HCl-H2O, partial pressures appreciably greater than the two saturation partial pressures are needed to condense the gas mixture into small solution droplets (homogeneous heteromolecular nucleation). Thus without foreign nuclei, clouds are not as easily formed as in the theories of Lewis; the latter should be valid only if large condensation nuclei are available. We calculate here from classical homogeneous heteromolecular nucleation theory the threshold partial pressures necessary to achieve droplet nucleation for the gas mixtures NH3-H2O (Jupiter), HCl-H2O (Venus), H2SO4-H2O (Venus), and C2H5OH-H2O (laboratory).
Classical theory of electric and magnetic fields
Good, Roland H
1971-01-01
Classical Theory of Electric and Magnetic Fields is a textbook on the principles of electricity and magnetism. This book discusses mathematical techniques, calculations, with examples of physical reasoning, that are generally applied in theoretical physics. This text reviews the classical theory of electric and magnetic fields, Maxwell's Equations, Lorentz Force, and Faraday's Law of Induction. The book also focuses on electrostatics and the general methods for solving electrostatic problems concerning images, inversion, complex variable, or separation of variables. The text also explains ma
Classical Electrodynamics in a Unified Theory
Ghose, Partha
2016-01-01
Some consequences of a fully classical unified theory of gravity and electromagnetism are worked out for the electromagnetic sector such as the occurrence of classical light beams with spin and orbital angular momenta that are topologically quantized in units of $q_e q_m=\\sigma$, independent of the beam size. Empirical fits require $\\sigma = \\hbar$. The theory also predicts a generalized coherency matrix whose consequences are testable.
Quantum feedback control and classical control theory
Doherty, Andrew C.; Habib, Salman; Jacobs, Kurt; Mabuchi, Hideo; Tan, Sze M.
1999-01-01
We introduce and discuss the problem of quantum feedback control in the context of established formulations of classical control theory, examining conceptual analogies and essential differences. We describe the application of state-observer-based control laws, familiar in classical control theory, to quantum systems and apply our methods to the particular case of switching the state of a particle in a double-well potential.
FROM CLASSICAL TO EPISTEMIC GAME THEORY
ANDRÉS PEREA
2014-01-01
In this paper, we give a historical overview of the transition from classical game theory to epistemic game theory. To that purpose we will discuss how important notions such as reasoning about the opponents, belief hierarchies, common belief, and the concept of common belief in rationality arose, and gradually entered the game theoretic picture, thereby giving birth to the field of epistemic game theory. We will also address the question why it took game theory so long before it finally inco...
A Classical Introduction to Galois Theory
Newman, Stephen C
2012-01-01
This book provides an introduction to Galois theory and focuses on one central theme - the solvability of polynomials by radicals. Both classical and modern approaches to the subject are described in turn in order to have the former (which is relatively concrete and computational) provide motivation for the latter (which can be quite abstract). The theme of the book is historically the reason that Galois theory was created, and it continues to provide a platform for exploring both classical and modern concepts. This book examines a number of problems arising in the area of classical mathematic
Dynamics of homogeneous nucleation
Toxværd, Søren
2015-01-01
clusters fluctuates, but the mean temperature remains below the temperature in the supersaturated gas until they reach the critical nucleation size. The critical nuclei have, however, a temperature equal to the supersaturated gas. The kinetics of homogeneous nucleation is not only caused by a grow or......The classical nucleation theory for homogeneous nucleation is formulated as a theory for a density fluctuation in a supersaturated gas at a given temperature. But molecular dynamics simulations reveal that it is small cold clusters which initiates the nucleation. The temperature in the nucleating...
Beam structures classical and advanced theories
Carrera, Erasmo; Petrolo, Marco
2011-01-01
Beam theories are exploited worldwide to analyze civil, mechanical, automotive, and aerospace structures. Many beam approaches have been proposed during the last centuries by eminent scientists such as Euler, Bernoulli, Navier, Timoshenko, Vlasov, etc. Most of these models are problem dependent: they provide reliable results for a given problem, for instance a given section and cannot be applied to a different one. Beam Structures: Classical and Advanced Theories proposes a new original unified approach to beam theory that includes practically all classical and advanced models for be
Prototype Theory and Classical Theory:An Explanation and Comparison
刘莹
2014-01-01
This paper discusses two different ways to understand categorization, which are classical theory and prototype theory. There is a deep exploration on how to understand categories, and different theoretical backgrounds of the two categorization the⁃ories. Furthermore, it reviews the limitations and advantages of both theories. And the comparison of the theories gives a clearer angle to understand their similarities and differences.
Emergence of classical theories from quantum mechanics
Hajicek, Petr
2012-01-01
Three problems stand in the way of deriving classical theories from quantum mechanics: those of realist interpretation, of classical properties and of quantum measurement. Recently, we have identified some tacit assumptions that lie at the roots of these problems. Thus, a realist interpretation is hindered by the assumption that the only properties of quantum systems are values of observables. If one simply postulates the properties to be objective that are uniquely defined by preparation then all difficulties disappear. As for classical properties, the wrong assumption is that there are arbitrarily sharp classical trajectories. It turns out that fuzzy classical trajectories can be obtained from quantum mechanics by taking the limit of high entropy. Finally, standard quantum mechanics implies that any registration on a quantum system is disturbed by all quantum systems of the same kind existing somewhere in the universe. If one works out systematically how quantum mechanics must be corrected so that there is ...
Lagrangian formulation of classical BMT-theory
Full text: The most popular classical theory of electron has been formulated by Bargmann, Michel and Telegdi (BMT) in 1959. The BMT equations give classical relativistic description of a charged particle with spin and anomalous magnetic momentum moving in homogeneous electro-magnetic field. This allows to study spin dynamics of polarized beams in uniform fields. In particular, first experimental measurements of muon anomalous magnetic momentum were done using changing of helicity predicted by BMT equations. Surprisingly enough, a systematic formulation and the analysis of the BMT theory are absent in literature. In the present work we particularly fill this gap by deducing Lagrangian formulation (variational problem) for BMT equations. Various equivalent forms of Lagrangian will be discussed in details. An advantage of the obtained classical model is that the Lagrangian action describes a relativistic spinning particle without Grassmann variables, for both free and interacting cases. This implies also the possibility of canonical quantization. In the interacting case, an arbitrary electromagnetic background may be considered, which generalizes the BMT theory formulated to the case of homogeneous fields. The classical model has two local symmetries, which gives an interesting example of constrained classical dynamics. It is surprising, that the case of vanishing anomalous part of the magnetic momentum is naturally highlighted in our construction. (author)
Classical theory of the hydrogen atom
Rashkovskiy, Sergey
2016-01-01
It is shown that all of the basic properties of the hydrogen atom can be consistently described in terms of classical electrodynamics instead of taking the electron to be a particle; we consider an electrically charged classical wave field, an "electron wave", which is held in a limited region of space by the electrostatic field of the proton. It is shown that quantum mechanics must be considered to be not a theory of particles but a classical field theory in the spirit of classical electrodynamics. In this case, we are not faced with difficulties in interpreting the results of the theory. In the framework of classical electrodynamics, all of the well-known regularities of the spontaneous emission of the hydrogen atom are obtained, which is usually derived in the framework of quantum electrodynamics. It is shown that there are no discrete states and discrete energy levels of the atom: the energy of the atom and its states change continuously. An explanation of the conventional corpuscular-statistical interpre...
"Scars" connect classical and quantum theory
Monteiro, T
1990-01-01
Chaotic systems are unstable and extremely sensitive to initial condititions. So far, scientists have been unable to demonstrate that the same kind of behaviour exists in quantum or microscopic systems. New connections have been discovered though between classical and quantum theory. One is the phenomena of 'scars' which cut through the wave function of a particle (1 page).
The classical theory of fields electromagnetism
Helrich, Carl S
2012-01-01
The study of classical electromagnetic fields is an adventure. The theory is complete mathematically and we are able to present it as an example of classical Newtonian experimental and mathematical philosophy. There is a set of foundational experiments, on which most of the theory is constructed. And then there is the bold theoretical proposal of a field-field interaction from James Clerk Maxwell. This textbook presents the theory of classical fields as a mathematical structure based solidly on laboratory experiments. Here the student is introduced to the beauty of classical field theory as a gem of theoretical physics. To keep the discussion fluid, the history is placed in a beginning chapter and some of the mathematical proofs in the appendices. Chapters on Green’s Functions and Laplace’s Equation and a discussion of Faraday’s Experiment further deepen the understanding. The chapter on Einstein’s relativity is an integral necessity to the text. Finally, chapters on particle motion and waves in a dis...
Quantum field theory from classical statistics
Wetterich, C
2011-01-01
An Ising-type classical statistical model is shown to describe quantum fermions. For a suitable time-evolution law for the probability distribution of the Ising-spins our model describes a quantum field theory for Dirac spinors in external electromagnetic fields, corresponding to a mean field approximation to quantum electrodynamics. All quantum features for the motion of an arbitrary number of electrons and positrons, including the characteristic interference effects for two-fermion states, are described by the classical statistical model. For one-particle states in the non-relativistic approximation we derive the Schr\\"odinger equation for a particle in a potential from the time evolution law for the probability distribution of the Ising-spins. Thus all characteristic quantum features, as interference in a double slit experiment, tunneling or discrete energy levels for stationary states, are derived from a classical statistical ensemble. Concerning the particle-wave-duality of quantum mechanics, the discret...
Optimal search behavior and classic foraging theory
Random walk methods and diffusion theory pervaded ecological sciences as methods to analyze and describe animal movement. Consequently, statistical physics was mostly seen as a toolbox rather than as a conceptual framework that could contribute to theory on evolutionary biology and ecology. However, the existence of mechanistic relationships and feedbacks between behavioral processes and statistical patterns of movement suggests that, beyond movement quantification, statistical physics may prove to be an adequate framework to understand animal behavior across scales from an ecological and evolutionary perspective. Recently developed random search theory has served to critically re-evaluate classic ecological questions on animal foraging. For instance, during the last few years, there has been a growing debate on whether search behavior can include traits that improve success by optimizing random (stochastic) searches. Here, we stress the need to bring together the general encounter problem within foraging theory, as a mean for making progress in the biological understanding of random searching. By sketching the assumptions of optimal foraging theory (OFT) and by summarizing recent results on random search strategies, we pinpoint ways to extend classic OFT, and integrate the study of search strategies and its main results into the more general theory of optimal foraging.
Emergence of classical theories from quantum mechanics
Three problems stand in the way of deriving classical theories from quantum mechanics: those of realist interpretation, of classical properties and of quantum measurement. Recently, we have identified some tacit assumptions that lie at the roots of these problems. Thus, a realist interpretation is hindered by the assumption that the only properties of quantum systems are values of observables. If one simply postulates the properties to be objective that are uniquely defined by preparation then all difficulties disappear. As for classical properties, the wrong assumption is that there are arbitrarily sharp classical trajectories. It turns out that fuzzy classical trajectories can be obtained from quantum mechanics by taking the limit of high entropy. Finally, standard quantum mechanics implies that any registration on a quantum system is disturbed by all quantum systems of the same kind existing somewhere in the universe. If one works out systematically how quantum mechanics must be corrected so that there is no such disturbance, one finds a new interpretation of von Neumann's 'first kind of dynamics', and so a new way to a solution of the quantum measurement problem. The present paper gives a very short review of this work.
Emergence of classical theories from quantum mechanics
Hájíček, P.
2012-05-01
Three problems stand in the way of deriving classical theories from quantum mechanics: those of realist interpretation, of classical properties and of quantum measurement. Recently, we have identified some tacit assumptions that lie at the roots of these problems. Thus, a realist interpretation is hindered by the assumption that the only properties of quantum systems are values of observables. If one simply postulates the properties to be objective that are uniquely defined by preparation then all difficulties disappear. As for classical properties, the wrong assumption is that there are arbitrarily sharp classical trajectories. It turns out that fuzzy classical trajectories can be obtained from quantum mechanics by taking the limit of high entropy. Finally, standard quantum mechanics implies that any registration on a quantum system is disturbed by all quantum systems of the same kind existing somewhere in the universe. If one works out systematically how quantum mechanics must be corrected so that there is no such disturbance, one finds a new interpretation of von Neumann's "first kind of dynamics", and so a new way to a solution of the quantum measurement problem. The present paper gives a very short review of this work.
Classical solutions in quantum field theories
Quantum field theories are difficult to solve because they are governed by nonlinear operator equations. A one-dimensional example, termed the kink, is presented of a classical solution. Topological and nontopological solitons in more than one spatial dimension are also discussed. Euclidean solutions and barrier penetration are also reviewed, focusing on vacuum decay by tunneling, Yang-Mills Instantons, the physical consequences of vacuum tunneling, and thermal fluctuations and sphalerons. 119 refs., 2 figs
Nucleation for Lennard-Jones Fluid by Density Functional Theory
FU Dong
2005-01-01
@@ A non-mean field density functional theory is employed to investigate the vapour-liquid nucleation. The excess Helmholtz free energy functional is formulated in terms of a local density approximation for short ranged repulsion and a density-gradient expansion for long-ranged attractions. An analytical expression for the direct correlation function of a Lennard-Jones fluid is utilized to take into account the effect of long-ranged attractions on intermolecular correlations. With the predicted bulk properties and surface tension as input, the nucleation properties including density profile, work of formation and number of particles at the reduced temperatures T* = 0.694 and 0.741 are inuestigated. The obtained number of particles in the critical nucleus agrees well with the simulation data.
A New Theory of Nucleate Pool Boiling in Arbitrary Gravity
Buyevich, Y. A.; Webbon, Bruce W.
1995-01-01
Heat transfer rates specific to nucleate pool boiling under various conditions are determined by the dynamics of vapour bubbles that are originated and grow at nucleation sites of a superheated surface. A new dynamic theory of these bubbles has been recently developed on the basis of the thermodynamics of irreversible processes. In contrast to other existing models based on empirically postulated equations for bubble growth and motion, this theory does not contain unwarrantable assumptions, and both the equations are rigorously derived within the framework of a unified approach. The conclusions of the theory are drastically different from those of the conventional models. The bubbles are shown to detach themselves under combined action of buoyancy and a surface tension force that is proven to add to buoyancy in bubble detachment, but not the other way round as is commonly presumed. The theory ensures a sound understanding of a number of so far unexplained phenomena, such as effect caused by gravity level and surface tension on the bubble growth rate and dependence of the bubble characteristics at detachment on the liquid thermophysical parameters and relevant temperature differences. The theoretical predictions are shown to be in a satisfactory qualitative and quantitative agreement with observations. When being applied to heat transfer at nucleate pool boiling, this bubble dynamic theory offers an opportunity to considerably improve the main formulae that are generally used to correlate experimental findings and to design boiling heat removal in various industrial applications. Moreover, the theory makes possible to pose and study a great deal of new problems of essential impact in practice. Two such problems are considered in detail. One problem concerns the development of a principally novel physical model for the first crisis of boiling. This model allows for evaluating critical boiling heat fluxes under various conditions, and in particular at different
Introduction to classical and quantum field theory
This is the first introductory textbook on quantum field theory to be written from the point of view of condensed matter physics. As such, it presents the basic concepts and techniques of statistical field theory, clearly explaining how and why they are integrated into modern quantum (and classical) field theory, and includes the latest developments. Written by an expert in the field, with a broad experience in teaching and training, it manages to present such substantial topics as phases and phase transitions or solitons and instantons in an accessible and concise way. Divided into three parts, the first part covers fundamental physics and the mathematics background needed by students in order to enter the field, while the second part introduces more advanced concepts and techniques. Part III discusses applications of quantum field theory to a few basic problems. The emphasis here lies on how modern concepts of quantum field theory are embedded in these approaches, and also on the limitations of standard quantum field theory techniques in facing, 'real' physics problems. Throughout there are numerous end-of-chapter problems, and a free solutions manual is available for lecturers. (orig.)
Differential formalism aspects of the gauge classical theories
The classical aspects of the gauge theories are shown using differential geometry as fundamental tool. Somme comments are done about Maxwell Electro-dynamics, classical Yang-Mills and gravitation theories. (L.C.)
RELEVANCE OF CLASSICALAND NEO-CLASSICAL THEORIES IN PRESENT WORLD
Heena Kashyap
2015-01-01
This paper attempts to explain the impact of various management theories on Modern organisations. Primary purpose of this paper is to explain the relevance of studying Classical and Neo classical theories in the present world. Though these theories don’t consider external environmental changes in Management of Organisation, but they still hold significant place in present scenario. Classical and Neo Classical theories provide foundations for understanding continuous changes in ...
Polynomial Invariant Theory of the Classical Groups
Westrich, Quinton
2011-01-01
The goal of invariant theory is to find all the generators for the algebra of representations of a group that leave the group invariant. Such generators will be called \\emph{basic invariants}. In particular, we set out to find the set of basic invariants for the classical groups GL$(V)$, O$(n)$, and Sp$(n)$ for $n$ even. In the first half of the paper we set up relevant definitions and theorems for our search for the set of basic invariants, starting with linear algebraic groups and then discussing associative algebras. We then state and prove a monumental theorem that will allow us to proceed with hope: it says that the set of basic invariants is finite if $G$ is reductive. Finally we state without proof the First Fundamental Theorems, which aim to list explicitly the relevant sets of basic invariants, for the classical groups above. We end by commenting on some applications of invariant theory, on the history of its development, and stating a useful theorem in the appendix whose proof lies beyond the scope ...
Robust topological degeneracy of classical theories
Vaezi, Mohammad-Sadegh; Ortiz, Gerardo; Nussinov, Zohar
2016-05-01
We challenge the hypothesis that the ground states of a physical system whose degeneracy depends on topology must necessarily realize topological quantum order and display nonlocal entanglement. To this end, we introduce and study a classical rendition of the Toric Code model embedded on Riemann surfaces of different genus numbers. We find that the minimal ground state degeneracy (and those of all levels) depends on the topology of the embedding surface alone. As the ground states of this classical system may be distinguished by local measurements, a characteristic of Landau orders, this example illustrates that topological degeneracy is not a sufficient condition for topological quantum order. This conclusion is generic and, as shown, it applies to many other models. We also demonstrate that certain lattice realizations of these models, and other theories, display a ground state entropy (and those of all levels) that is "holographic", i.e., extensive in the system boundary. We find that clock and U (1 ) gauge theories display topological (in addition to gauge) degeneracies.
Pólya distribution and its asymptotics in nucleation theory
Dubrovskii, V. G.
2014-02-01
A model of condensation-decay rate constants that are linear with respect to the number of monomers in the nucleus is considered. In a particular case of stable growth, this model leads to an exact solution of discrete kinetic equations of the theory of heterogeneous nucleation in the form of the Pólya distribution function. An asymptotic solution in the region of large nucleus sizes that satisfies the normalization condition and provides correct mean nucleus size has been found. It is shown that, in terms of the logarithmic invariant size, the obtained distribution has a universal time-independent form. The obtained solution, being more general than the double-exponent distribution used previously, describes both Gaussian and asymmetric distributions depending on the rate constant of condensation on a bare core. The obtained results are useful for modeling processes in some systems, in particular, the growth of linear chains, two-dimensional clusters, and filamentary nanocrystals.
An approximate classical unimolecular reaction rate theory
Zhao, Meishan; Rice, Stuart A.
1992-05-01
We describe a classical theory of unimolecular reaction rate which is derived from the analysis of Davis and Gray by use of simplifying approximations. These approximations concern the calculation of the locations of, and the fluxes of phase points across, the bottlenecks to fragmentation and to intramolecular energy transfer. The bottleneck to fragment separation is represented as a vibration-rotation state dependent separatrix, which approximation is similar to but extends and improves the approximations for the separatrix introduced by Gray, Rice, and Davis and by Zhao and Rice. The novel feature in our analysis is the representation of the bottlenecks to intramolecular energy transfer as dividing surfaces in phase space; the locations of these dividing surfaces are determined by the same conditions as locate the remnants of robust tori with frequency ratios related to the golden mean (in a two degree of freedom system these are the cantori). The flux of phase points across each dividing surface is calculated with an analytic representation instead of a stroboscopic mapping. The rate of unimolecular reaction is identified with the net rate at which phase points escape from the region of quasiperiodic bounded motion to the region of free fragment motion by consecutively crossing the dividing surfaces for intramolecular energy exchange and the separatrix. This new theory generates predictions of the rates of predissociation of the van der Waals molecules HeI2, NeI2 and ArI2 which are in very good agreement with available experimental data.
Hilbert space theory of classical electrodynamics
RAJAGOPAL A K; GHOSE PARTHA
2016-06-01
Classical electrodynamics is reformulated in terms of wave functions in the classical phase space of electrodynamics, following the Koopman–von Neumann–Sudarshan prescription for classical mechanics on Hilbert spaces sans the superselection rule which prohibits interference effects in classical mechanics. This is accomplished by transforming from a set of commutingobservables in one Hilbert space to another set of commuting observables in a larger Hilbert space. This is necessary to clarify the theoretical basis of the much recent work on quantum-like features exhibited by classical optics. Furthermore, following Bondar et al, {\\it Phys. Rev.} A 88, 052108 (2013), it is pointed out that quantum processes that preserve the positivity or nonpositivity of theWigner function can be implemented by classical optics. This may be useful in interpreting quantum information processing in terms of classical optics.
Confining properties of the classical SU(3) Yang - Mills theory
Dzhunushaliev, V D
1996-01-01
The spherically and cylindrically symmetric solutions of the $SU(3)$ Yang - Mills theory are obtained. The corresponding gauge potential has the confining properties. It is supposed that: a) the spherically symmetric solution is a field distribution of the classical ``quark'' and in this sense it is similar to the Coulomb potential; b) the cylindrically symmetric solution describes a classical field ``string'' (flux tube) between two ``quarks''. It is noticed that these solutions are typically for the classical $SU(3)$ Yang - Mills theory in contradiction to monopole that is an exceptional solution. This allows to conclude that the confining properties of the classical $SU(3)$ Yang - Mills theory are general properties of this theory.
The Possibility of Reconciling Quantum Mechanics with Classical Probability Theory
Slavnov, D. A.
2007-01-01
We describe a scheme for constructing quantum mechanics in which a quantum system is considered as a collection of open classical subsystems. This allows using the formal classical logic and classical probability theory in quantum mechanics. Our approach nevertheless allows completely reproducing the standard mathematical formalism of quantum mechanics and identifying its applicability limits. We especially attend to the quantum state reduction problem.
Introducing quantum effects in classical theories
Fabris, J C; Rodrigues, D C; Daouda, M H
2015-01-01
In this paper, we explore two different ways of implementing quantum effects in a classical structure. The first one is through an external field. The other one is modifying the classical conservation laws. In both cases, the consequences for the description of the evolution of the universe are discussed.
Nucleation theory beyond the deterministic limit. II. The growth stage.
Dubrovskii, V G; Nazarenko, M V
2010-03-21
This work addresses theory of nucleation and condensation based on the continuous Fokker-Plank type kinetic equation for the distribution of supercritical embryos over sizes beyond the deterministic limit. The second part of the work treats the growth stage and the beginning of the Ostwald ripening. We first study in detail the fluctuation-induced spreading of size spectrum at the growth stage. It is shown that the spectrum should be generally obtained by the convolution of the initial distribution with the Gaussian-like Green function with spreading dispersion. The increase in dispersion depends, however, on the growth index m as well as on the space dimension, and the mode of material influx. In particular, we find that the spreading effect on two-dimensional islands growing at a constant material influx is huge at m=1 but almost absent at m=2. Analytical and numerical solutions for the mean size, the dispersion, and the size spectrum are presented in different cases. Finally, the general condition for the stage of Ostwald ripening in an open system with material influx is discussed. PMID:20331306
Gauge-fields and integrated quantum-classical theory
Physical situations in which quantum systems communicate continuously to their classically described environment are not covered by contemporary quantum theory, which requires a temporary separation of quantum degrees of freedom from classical ones. A generalization would be needed to cover these situations. An incomplete proposal is advanced for combining the quantum and classical degrees of freedom into a unified objective description. It is based on the use of certain quantum-classical structures of light that arise from gauge invariance to coordinate the quantum and classical degrees of freedom. Also discussed is the question of where experimenters should look to find phenomena pertaining to the quantum-classical connection. 17 refs
Characterizing protein crystal nucleation
Akella, Sathish V.
We developed an experimental microfluidic based technique to measure the nucleation rates and successfully applied the technique to measure nucleation rates of lysozyme crystals. The technique involves counting the number of samples which do not have crystals as a function of time. Under the assumption that nucleation is a Poisson process, the fraction of samples with no crystals decays exponentially with the decay constant proportional to nucleation rate and volume of the sample. Since nucleation is a random and rare event, one needs to perform measurements on large number of samples to obtain good statistics. Microfluidics offers the solution of producing large number of samples at minimal material consumption. Hence, we developed a microfluidic method and measured nucleation rates of lysozyme crystals in supersaturated protein drops, each with volume of ˜ 1 nL. Classical Nucleation Theory (CNT) describes the kinetics of nucleation and predicts the functional form of nucleation rate in terms of the thermodynamic quantities involved, such as supersaturation, temperature, etc. We analyzed the measured nucleation rates in the context of CNT and obtained the activation energy and the kinetic pre-factor characterizing the nucleation process. One conclusion is that heterogeneous nucleation dominates crystallization. We report preliminary studies on selective enhancement of nucleation in one of the crystal polymorprhs of lysozyme (spherulite) using amorphous mesoporous bioactive gel-glass te{naomi06, naomi08}, CaO.P 2O5.SiO2 (known as bio-glass) with 2-10 nm pore-size diameter distribution. The pores act as heterogeneous nucleation centers and claimed to enhance the nucleation rates by molecular confinement. The measured kinetic profiles of crystal fraction of spherulites indicate that the crystallization of spherulites may be proceeding via secondary nucleation pathways.
Introduction to Classical Density Functional Theory by a Computational Experiment
Jeanmairet, Guillaume; Levy, Nicolas; Levesque, Maximilien; Borgis, Daniel
2014-01-01
We propose an in silico experiment to introduce the classical density functional theory (cDFT). Density functional theories, whether quantum or classical, rely on abstract concepts that are nonintuitive; however, they are at the heart of powerful tools and active fields of research in both physics and chemistry. They led to the 1998 Nobel Prize in…
HCI Theory Classical, Modern, and Contemporary
Rogers, Yvonne
2012-01-01
Theory is the bedrock of many sciences, providing a rigorous method toadvance knowledge through testing and falsifying hypotheses aboutobservable phenomena. To begin with, the nascent field of HCI followedsuit, borrowing theories from cognitive science to test theories aboutuser performance at the interface.But HCI has emerged as an eclectic interdiscipline rather than a welldefinedscience. It now covers all aspects of human life, from birth tobereavement, through all manner of computing, from device ecologiesto nanotechnology. It comes as no surprise that the role of theory in HCIhas also gre
Dense matter theory a simple classical approach
Savic, P
1998-01-01
In the sixties,the first author and R.Kasanin have started developing a mean field theory of dense matter.This paper presents a short review of the basic ideas of the theory,and discusses some examples of its applications,which range from DAC experiments to modelling of planetary interiors.
Functional Approach to Classical Yang-Mills Theories
Carta, P
2002-01-01
Sometime ago it was shown that the operatorial approach to classical mechanics, pioneered in the 30's by Koopman and von Neumann, can have a functional version. In this talk we will extend this functional approach to the case of classical field theories and in particular to the Yang-Mills ones. We shall show that the issues of gauge-fixing and Faddeev-Popov determinant arise also in this classical formalism.
Evaluation of time-dependent void nucleation theory under ion bombardment conditions
The applicability of a steady state and time-dependent homogeneous void nucleation theory to charged-particle irradiation experiments was investigated. The steady-state theory was found to be inappropriate, since significant changes in a metal's microstructure would likely occur before the void nucleation rate could reach steady state. Two types of time dependence were examined, that of the point defect concentrations at the beginning of an irradiation and the longer-term time dependence of void nucleation. It was found that vacancy and interstitial clustering significantly reduce the relaxation time for the point defect concentrations. An efficient form of time-dependent homogeneous nucleation theory was applied to ion bombardment conditions to predict void size distributions
Classical conformality in the Standard Model from Coleman's theory
Kawana, Kiyoharu
2016-01-01
The classical conformality is one of the possible candidates for explaining the gauge hierarchy of the Standard Model. We show that it is naturally obtained from the Coleman's theory on baby universe.
Experimental assessment of unvalidated assumptions in classical plasticity theory.
Brannon, Rebecca Moss (University of Utah, Salt Lake City, UT); Burghardt, Jeffrey A. (University of Utah, Salt Lake City, UT); Bauer, Stephen J.; Bronowski, David R.
2009-01-01
This report investigates the validity of several key assumptions in classical plasticity theory regarding material response to changes in the loading direction. Three metals, two rock types, and one ceramic were subjected to non-standard loading directions, and the resulting strain response increments were displayed in Gudehus diagrams to illustrate the approximation error of classical plasticity theories. A rigorous mathematical framework for fitting classical theories to the data, thus quantifying the error, is provided. Further data analysis techniques are presented that allow testing for the effect of changes in loading direction without having to use a new sample and for inferring the yield normal and flow directions without having to measure the yield surface. Though the data are inconclusive, there is indication that classical, incrementally linear, plasticity theory may be inadequate over a certain range of loading directions. This range of loading directions also coincides with loading directions that are known to produce a physically inadmissible instability for any nonassociative plasticity model.
Classical gravity coupled to Liouville theory
We consider the two dimensional Jackiw-Teitelboim model of gravity. We first couple the model to the Liouville action and c scalar fields and show, treating the combined system as a non linear sigma model, that the resulting theory can be interpreted as a critical string moving in a target space of dimension D = c + 2. We then analyse perturbatively a generalized model containing a kinetic term and an arbitrary potential for the auxiliary field. We use the background field method and work covariant gauges. We show that the renormalizability of the theory depends on the form of the potential. For a general potential, the theory can be renormalized as a non linear sigma model. In the particular case of a Liouville-like potential, the theory is renormalized in the usual sense. (author). 31 refs
Classical gravity coupled to Liouville theory
We consider the two dimensional Jackiw-Teitelboim model of gravity. We first couple the model to the Liouville action and c scalar fields and show, treating the combined system as a non linear sigma model, that the resulting theory can be interpreted as a critical string moving in a target space of dimension D=c+2. We then analyze the model from a perturbative point of view. We show in particular that the results of conformal field theory are exactly reproduced at the one-loop level. We also show that the theory is one loop finite if the cosmological constant Λ is equal to zero. When Λ is different from zero the one loop divergences are gauge-fixing dependent even on-shell. However, the theory can be renormalized as a non linear sigma model if a kinetic term is included for the auxiliary field. (author). 27 refs
Heterogeneous nucleation of calcium oxalate on native oxide surfaces
The aqueous deposition of calcium oxalate onto colloidal oxides has been studied as a model system for understanding heterogeneous nucleation processes of importance in biomimetic synthesis of ceramic thin films. Calcium oxalate nucleation has been monitored by measuring induction times for nucleation using Constant Composition techniques and by measuring nucleation densities on extended oxide surfaces using an atomic force microscope. Results show that the dependence of calcium oxalate nucleation on solution supersaturation fits the functional form predicted by classical nucleation theories. Anionic surfaces appear to promote nucleation better than cationic surfaces, lowering the effective energy barrier to heterogeneous nucleation
Conformal Invariance in Classical Field Theory
Grigore, D. R.
1993-01-01
A geometric generalization of first-order Lagrangian formalism is used to analyse a conformal field theory for an arbitrary primary field. We require that global conformal transformations are Noetherian symmetries and we prove that the action functional can be taken strictly invariant with respect to these transformations. In other words, there does not exists a "Chern-Simons" type Lagrangian for a conformally invariant Lagrangian theory.
The semi classical laser theory and some applications of laser
The semi classical laser theory is concerned with the interaction between light and matter in such a way that the matter is treated quantum-mechanically whereas light is treated in terms of the classical electromagnetic equations. In this work the Maxwell-Bloch equations are employed to describe the interaction between light and matter. Applications of the theory as well as different types of lasers are reviewed. (Author)
Vibration of Timoshenko Beams Using Non-classical Elasticity Theories
J.V. Araújo dos Santos; J.N. Reddy
2012-01-01
This paper presents a comparison among classical elasticity, nonlocal elasticity, and modified couple stress theories for free vibration analysis of Timoshenko beams. A study of the influence of rotary inertia and nonlocal parameters on fundamental and higher natural frequencies is carried out. The nonlocal natural frequencies are found to be lower than the classical ones, while the natural frequencies estimated by the modified couple stress theory are higher. The modified couple stress theor...
From Classical to Quantum Shannon Theory
Wilde, Mark M
2011-01-01
The aim of this book is to develop "from the ground up" all of the major, exciting, pre- and post-millenium developments in the general area of study known as quantum Shannon theory. As such, we spend a significant amount of time on quantum mechanics for quantum information theory (Part II), we give a careful study of the important unit protocols of teleportation, super-dense coding, and entanglement distribution (Part III), and we develop many of the tools necessary for understanding information transmission or compression (Part IV). Parts V and VI are the culmination of this book, where all of the tools developed come into play for understanding many of the important results in quantum Shannon theory.
[The establishment, contributions, and final results of classical medical theories].
Wang, Tai
2013-01-01
In countries with ancient civilization of both Eastern world and Western world, after the accumulation of clinical experiences of "empirical medicine" to a sufficient amount; in accordance of their primitive philosophical thoughts, classical medical theories were established to play an important role in guiding the clinical practice of "empirical medicine". Because of the similarity of philosophical thoughts all over the ancient world, their medical theories were also very similar to each other. After the scientific evaluation and improvement, Greek classical medical theories were inherited, refined or abandoned, and then eventually finished their historical mission. Chinese classical medical theories also need the similar scientific identification and improvement for flowing into the authorized main stream of modern medical theory systems to continuously apply their guiding roles in clinical practice. Scholars would better consider the developmental principles of cultures and sciences with a historical viewpoint and an open mind to avoid making mistakes from haughty and prejudice. PMID:23596779
Deliquescence and efflorescence of small particles: Unifying perspectives from nucleation theory
McGraw,R.; Lewis, E.
2009-02-23
We examine size dependent deliquescence/efflorescence phase transformation for particles down to several nanometers in size. A thin layer criterion (TLC) is introduced to define a deliquescence relative humidity (DRH) for small particles. The usual bulk deliquescence conditions are recovered in the limit of large dry particle size. Nano-size particles are shown to deliquesce to metastable states via a nucleation process at relative humidity just below the DRH. The nucleation barrier is located at a critical solution layer thickness and vanishes at the DRH defined by the TLC. Methods from nucleation theory form the basis for the analysis and yield new insights into the theory, facilitate the interpretation of measurements, and point to unification of deliquescence and efflorescence processes for particles in the nano regime. Methods include thermodynamic area constructions, Legendre transforms relating the binary free-energy surfaces for deliquescence and efflorescence processes, and application of nucleation theorems.
Reexamination of Correlations for Nucleate Site Distribution on Boiling Surface by Fractal Theory
YangChunxin
1997-01-01
Nucleate site distribution plays an essential role in nucleate boiling process.In this paper,it is pointed out that the size and spatial distributioin density of nucleate sites presented on real boiling surface can be described by the normalized fractal distribution function,and the physical meaning of parameters involved in some experimental correlations proposed by early investigations are identified according to fractal distribution function.It is further suggested that the surface micro geometry characteristics such as the shape of cavities should be described and analyzed qualitatively by using fractal theory.
Classical Coupled Mode Theory of Optomechanical Crystals
Khorasani, Sina
2016-01-01
Acousto-optic interaction in optomechanical crystals allows unidirectional control of elastic waves over optical waves. However, as a result of this nonlinear interaction, infinitely many optical modes are born. This article presents an exact formulaion of coupled mode theory for interaction between elastic Bloch wave waves and photonic Bloch waves moving in a phonotonic waveguide. In general, an optical wavefront is strongly diffracted by an elastic wave in frequency and wavevector, and thus infinite modes with different frequencies and wavevectors appear. We discuss resonance and mode conversion conditions, and present a rigorous method to derive coupling rates and mode profiles. We also find a conservation law which rules over total optical power from interacting individual modes. Modifications of the theory to phonotonic cavities are also discussed. We present application examples including switch, frequency shifter, and reflector.
Computation Of Nucleation Rates For N-Nonane Using The Gradient Theory
Labetski, D.G.; Hrubý, Jan; Vinš, Václav; Dongen, M. E. H.
Vienna : Springer Netherlands , 2007, s. 97-101. ISBN 978-1-4020-6474-6. [Nucleation and Atmospheric Aerosols International Conference /17./. Galway (IE), 13.08.2007-17.08.2007] R&D Projects: GA ČR GA101/05/0136 Institutional research plan: CEZ:AV0Z20760514 Keywords : homogeneous nucleation * gradient theory * nonane Subject RIV: BJ - Thermodynamics http://www.springerlink.com/content/r278044g8244v561/
Satin, Seema
2015-01-01
We attempt to introduce an new approach towards study of certain interesting issues in classical gravity. This can be done for few confined, but interesting and meaningful physical situations, which can be modeled by a classical stochastic Einstein equation. The Einstein equation can be looked upon as an equation of motion, while introducing to it a classical stochastic source or classical fluctuations as driving source. This is analogous to the Langevin equation formalism, in Brownian motion studies. A justification for the validity of such an ansatz for classical gravity is given. The regime of validity of such an approach and the consequences and possible outcomes of this formulation are discussed. We also mention, further relevant directions and applications of the same,that act as motivation towards the new proposal. This field of study can be seen to emerge out of well established ideas and results in Brownian motion theory as well as the Stochastic Semiclassical Gravity (which is already an active area...
Bleb Nucleation through Membrane Peeling
Alert, Ricard
2016-01-01
We study the nucleation of blebs, i.e., protrusions arising from a local detachment of the membrane from the cortex of a cell. Based on a simple model of elastic linkers with force-dependent kinetics, we show that bleb nucleation is governed by membrane peeling. By this mechanism, the growth or shrinkage of a detached membrane patch is completely determined by the linker kinetics, regardless of the energetic cost of the detachment. We predict the critical nucleation radius for membrane peeling and the corresponding effective energy barrier. These may be typically smaller than those predicted by classical nucleation theory, implying a much faster nucleation. We also perform simulations of a continuum stochastic model of membrane-cortex adhesion to obtain the statistics of bleb nucleation times as a function of the stress on the membrane. The determinant role of membrane peeling changes our understanding of bleb nucleation and opens new directions in the study of blebs.
Bleb Nucleation through Membrane Peeling
Alert, Ricard; Casademunt, Jaume
2016-02-01
We study the nucleation of blebs, i.e., protrusions arising from a local detachment of the membrane from the cortex of a cell. Based on a simple model of elastic linkers with force-dependent kinetics, we show that bleb nucleation is governed by membrane peeling. By this mechanism, the growth or shrinkage of a detached membrane patch is completely determined by the linker kinetics, regardless of the energetic cost of the detachment. We predict the critical nucleation radius for membrane peeling and the corresponding effective energy barrier. These may be typically smaller than those predicted by classical nucleation theory, implying a much faster nucleation. We also perform simulations of a continuum stochastic model of membrane-cortex adhesion to obtain the statistics of bleb nucleation times as a function of the stress on the membrane. The determinant role of membrane peeling changes our understanding of bleb nucleation and opens new directions in the study of blebs.
Introduction to Classical Density Functional Theory by Computational Experiment
Jeanmairet, Guillaume; Levesque, Maximilien; Borgis, Daniel
2014-01-01
We present here an introductory practical course to classical density functional theory (cDFT). Density functional theories, whether quantum or classical, rely largely on nonintuitive abstract concepts and applied mathematics. They are nevertheless a powerful tool and an active field of research in physics and chemistry that led to the 1998 Nobel prize in chemistry. We here illustrate the DFT in its most mathematically simple and yet physically relevant form: the classical density functional theory of an ideal fluid in an external field, as applied to the prediction of the structure of liquid neon at the molecular scale. This introductory course is built around the production of a cDFT code written by students using the Mathematica language. In this way, they are brought to deal with (i) the cDFT theory itself, (ii) some basic concepts around the statistical mechanics of simple fluids, (iii) the underlying mathematical and numerical problem of functional minimization, and (iv) a functional programming languag...
Lectures on Classical and Quantum Theory of Fields
Arodź, Henryk
2010-01-01
This textbook on classical and quantum theory of fields addresses graduate students starting to specialize in theoretical physics. It provides didactic introductions to the main topics in the theory of fields, while taking into account the contemporary view of the subject. The student will find concise explanations of basic notions essential for applications of the theory of fields as well as for frontier research in theoretical physics. One third of the book is devoted to classical fields. Each chapter contains exercises of varying degree of difficulty with hints or solutions, plus summaries and worked examples as useful. The textbook is based on lectures delivered to students of theoretical physics at Jagiellonian University. It aims to deliver a unique combination of classical and quantum field theory in one compact course.
Lectures on classical and quantum theory of fields
This textbook on classical and quantum theory of fields addresses graduate students starting to specialize in theoretical physics. It provides didactic introductions to the main topics in the theory of fields, while taking into account the contemporary view of the subject. The student will find concise explanations of basic notions essential for applications of the theory of fields as well as for frontier research in theoretical physics. One third of the book is devoted to classical fields. Each chapter contains exercises of varying degree of difficulty with hints or solutions, plus summaries and worked examples as useful. The textbook is based on lectures delivered to students of theoretical physics at Jagiellonian University. It aims to deliver a unique combination of classical and quantum field theory in one compact course. (orig.)
The Jackiw-Pi model: Classical theory
Full text: One of the central problems in the framework of gauge field theories is the issue of gauge field mass. Gauge symmetry is not, in principle, conflicting with the presence of a massive gauge boson. In two space-time dimensions, the well-known Schwinger model puts in evidence the presence of a massive photon without the breaking of gauge symmetry. Another evidence for the compatibility between gauge symmetry and massive vector fields comes from the study of three-dimensional gauge theories. A topological mass term referred to as the Chern-Simons Lagrangian, once added to the Yang-Mills term, shifts the photon mass to a non-vanishing value without breaking gauge invariance, however parity symmetry is lost. In 1997, a massive even-parity non- Abelian gauge model in three space-time dimensions has been proposed by Jackiw and Pi, which is studied, at the tree-level, in this work. The propagators are computed and the spectrum consistency is analyzed, besides, the symmetries of the model are collected and established through BRS invariance and Slavnov-Taylor identity. In the Landau gauge, thanks to the antighost equations and the Slavnov-Taylor identity, two rigid symmetries are identified by means of Ward identities. It is presented here a promising path for perturbatively quantization of the Jackiw-Pi model and a hint concerning its possible quantum scale invariance is also pointed out. (author)
Grigorenko, Alexander Ya; Grigorenko, Yaroslav M; Vlaikov, Georgii G
2016-01-01
This volume focuses on the relevant general theory and presents some first applications, namely those based on classical shell theory. After a brief introduction, during which the history and state-of-the-art are discussed, the first chapter presents the mechanics of anisotropic heterogeneous shells, covering all relevant assumptions and the basic relations of 3D elasticity, classical and refined shell models. The second chapter examines the numerical techniques that are used, namely discrete orthogonalization, spline-collocation and Fourier series, while the third highlights applications based on classical theory, in particular, the stress-strain state of shallow shells, non-circular shells, shells of revolution, and free vibrations of conical shells. The book concludes with a summary and an outlook bridging the gap to the second volume.
Classical Solutions in Quantum Field Theory
Quantum field theory has evolved from its early beginnings as a tool for understanding the interaction of light with matter into a rather formidable technical paradigm, one that has successfully provided the mathematical underpinnings of all non-gravitational interactions. Over the eight decades since it was first contemplated the methods have become increasingly more streamlined and sophisticated, yielding new insights into our understanding of the subatomic world and our abilities to make clear and precise predictions. Some of the more elegant methods have to do with non-perturbative and semiclassical approaches to the subject. The chief players here are solitons, instantons, and anomalies. Over the past three decades there has been a steady rise in our understanding of these objects and of our ability to calculate their effects and implications for the rest of quantum field theory. This book is a welcome contribution to this subject. In 12 chapters it provides a clear synthesis of the key developments in these subjects at a level accessible to graduate students that have had an introductory course to quantum field theory. In the author's own words it provides both 'a survey and an overview of this field'. The first half of the book concentrates on solitons-–kinks, vortices, and magnetic monopoles-–and their implications for the subject. The reader is led first through the simplest models in one spatial dimension, into more sophisticated cases that required more advanced topological methods. The author does quite a nice job of introducing the various concepts as required, and beginning students should be able to get a good grasp of the subject directly from the text without having to first go through the primary literature. The middle part of the book deals with the implications of these solitons for both cosmology and for duality. While the cosmological discussion is quite nice, the discussion on BPS solitons, supersymmetry and duality is
Classical theory of nonlinear Compton scattering
The covariant dynamics of a single electron subjected to the electromagnetic field of an intense, ultrashort laser pulse in vacuum is studied theoretically at arbitrary intensities, in the context of the Dirac-Lorentz equation, which has long been suggested as a possible theory including the radiative reaction due to the electron self-interaction. A brief review of the Lorentz-Maxwell electrodynamics including canonical invariants and scattered light spectra will be given, with a special emphasis on frequency modulation effects associated to the nonlinear relativistic Doppler shift induced by radiation pressure on the backscattered radiation. For circular polarization, an exact analytical expression for the full nonlinear spectrum is derived, and is presented. It is found that the scattering of coherent light by an electron describing a well-behaved trajectory can yield chaotic spectra when the laser ponderomotive force strongly modulates the electron's proper time. The Dirac-Lorentz equation is then derived and integrated numerically backward in time to ensure convergence towards the unique acausal solution satisfying the Dirac-Rohrlich asymptotic conditions (no runaway, law of inertia), and its consequences are investigated in terms of nonlinear Compton scattering. The relevance of this work to laser acceleration, as well as ongoing nonlinear Compton scattering experiments at SLAC and to the proposed γ-γ collider will also be discussed
A classical theory of continuous spin and hidden gauge invariance
We present a classical higher derivative point particle theory whose quantization gives Wigner's continuous spin representation of the Poincare group. Although the theory is not reparameterization invariant in the usual sense, it does possess a hidden gauge invariance that provides a non-local representation of the reparameterization group. The Hamiltonian of the theory does not vanish and its value is the continuous spin parameter. The theory presented here represents the simplest example of a wide class of higher derivative theories possessing a hidden gauge invariance
A classical theory of continuous spin and hidden gauge invariance
Zoller, D.
1991-01-01
We present a classical higher derivative point particle theory whose quantization gives Wigner's continuous spin representation of the Poincare group. Although the theory is not reparameterization invariant in the usual sense, it does possess a hidden gauge invariance that provides a non-local representation of the reparameterization group. The Hamiltonian of the theory does not vanish and its value is the continuous spin parameter. The theory presented here represents the simplest example of a wide class of higher derivative theories possessing a hidden gauge invariance.
A classical theory of continuous spin and hidden gauge invariance
Zoller, D.
1991-12-31
We present a classical higher derivative point particle theory whose quantization gives Wigner`s continuous spin representation of the Poincare group. Although the theory is not reparameterization invariant in the usual sense, it does possess a hidden gauge invariance that provides a non-local representation of the reparameterization group. The Hamiltonian of the theory does not vanish and its value is the continuous spin parameter. The theory presented here represents the simplest example of a wide class of higher derivative theories possessing a hidden gauge invariance.
Quantum Mind from a Classical Field Theory of the Brain
Zizzi, Paola
2011-01-01
We suggest that, with regard to a theory of quantum mind, brain processes can be described by a classical, dissipative, non-abelian gauge theory. In fact, such a theory has a hidden quantum nature due to its non-abelian character, which is revealed through dissipation, when the theory reduces to a quantum vacuum, where temperatures are of the order of absolute zero, and coherence of quantum states is preserved. We consider in particular the case of pure SU(2) gauge theory with a special anzat...
Quantum fermions and quantum field theory from classical statistics
Wetterich, C.
2012-01-01
An Ising-type classical statistical ensemble can describe the quantum physics of fermions if one chooses a particular law for the time evolution of the probability distribution. It accounts for the time evolution of a quantum field theory for Dirac particles in an external electromagnetic field. This yields in the non-relativistic one-particle limit the Schr\\"odinger equation for a quantum particle in a potential. Interference or tunneling arise from classical probabilities.
Resonances and adiabatic invariance in classical and quantum scattering theory
Jain, S R
2004-01-01
We discover that the energy-integral of time-delay is an adiabatic invariant in quantum scattering theory and corresponds classically to the phase space volume. The integral thus found provides a quantization condition for resonances, explaining a series of results recently found in non-relativistic and relativistic regimes. Further, a connection between statistical quantities like quantal resonance-width and classical friction has been established with a classically deterministic quantity, the stability exponent of an adiabatically perturbed periodic orbit. This relation can be employed to estimate the rate of energy dissipation in finite quantum systems.
Classical theory of atomic collisions - The first hundred years
Grujić, Petar V.
2012-05-01
Classical calculations of the atomic processes started in 1911 with famous Rutherford's evaluation of the differential cross section for α particles scattered on foil atoms [1]. The success of these calculations was soon overshadowed by the rise of Quantum Mechanics in 1925 and its triumphal success in describing processes at the atomic and subatomic levels. It was generally recognized that the classical approach should be inadequate and it was neglected until 1953, when the famous paper by Gregory Wannier appeared, in which the threshold law for the single ionization cross section behaviour by electron impact was derived. All later calculations and experimental studies confirmed the law derived by purely classical theory. The next step was taken by Ian Percival and collaborators in 60s, who developed a general classical three-body computer code, which was used by many researchers in evaluating various atomic processes like ionization, excitation, detachment, dissociation, etc. Another approach was pursued by Michal Gryzinski from Warsaw, who started a far reaching programme for treating atomic particles and processes as purely classical objects [2]. Though often criticized for overestimating the domain of the classical theory, results of his group were able to match many experimental data. Belgrade group was pursuing the classical approach using both analytical and numerical calculations, studying a number of atomic collisions, in particular near-threshold processes. Riga group, lead by Modris Gailitis [3], contributed considerably to the field, as it was done by Valentin Ostrovsky and coworkers from Sanct Petersbourg, who developed powerful analytical methods within purely classical mechanics [4]. We shall make an overview of these approaches and show some of the remarkable results, which were subsequently confirmed by semiclassical and quantum mechanical calculations, as well as by the experimental evidence. Finally we discuss the theoretical and
Introduction to classical and quantum Lagrangian field theory. 9
The basic principles of relativistic Lagrangian field theory are introduced, first in the classical context and later in the quantized form. Various free fields are discussed, their quantization, Lorentz invariance and the important discrete symmetries. Going on to interacting quantum fields, the invariant perturbation theory and Feynman graphs are succinctly discussed. Renormalizability and renormalization methods are covered with emphasis on the method of dimensional regularization. (author).3 refs.; 7 figs
Classical electromagnetic field theory in the presence of magnetic sources
Chen, W J; Naón, C M; Chen, Wen-Jun; Li, Kang
2001-01-01
Using two new well defined 4-dimensional potential vectors, we formulate the classical Maxwell's field theory in a form which has manifest Lorentz covariance and SO(2) duality symmetry in the presence of magnetic sources. We set up a consistent Lagrangian for the theory. Then from the action principle we get both Maxwell's equation and the equation of motion of a dyon moving in the electro-magnetic field.
Classical Electromagnetic Field Theory in the Presence of Magnetic Sources
LI Kang(李康); CHEN Wen-Jun(陈文俊); NAON Carlos M.
2003-01-01
Using two new well-defined four-dimensional potential vectors, we formulate the classical Maxwell field theory in a form which has manifest Lorentz covariance and SO(2) duality symmetry in the presence of magnetic sources.We set up a consistent Lagrangian for the theory. Then from the action principle we obtain both Maxwell's equation and the equation of motion of a dyon moving in the electromagnetic field.
Representational Realism, Closed Theories and the Quantum to Classical Limit
de Ronde, Christian
2016-01-01
In this paper we discuss the representational realist stance as a pluralist ontic approach to inter-theoretic relationships. Our stance stresses the fact that physical theories require the necessary consideration of a conceptual level of discourse which determines and configures the specific field of phenomena discussed by each particular theory. We will criticize the orthodox line of research which has grounded the analysis about QM in two (Bohrian) metaphysical presuppositions -accepted in the present as dogmas that all interpretations must follow. We will also examine how the orthodox project of "bridging the gap" between the quantum and the classical domains has constrained the possibilities of research, producing only a limited set of interpretational problems which only focus in the justification of "classical reality" and exclude the possibility of analyzing the possibilities of non-classical conceptual representations of QM. The representational realist stance introduces two new problems, namely, the ...
On the variational formulation of classical Abelian gauge field theories
It is shown how one can formulate an action principle for classical Abelian gauge theories not by means of gauge potentials and currents but in terms of the gauge invariant field strengths and gauge variant stream potentias. The discussion is on a general formal level in n=s+t space-time dimensions and uses, for brevity, the language of differential forms
Fradera, J., E-mail: jfradera@ubu.es; Cuesta-López, S., E-mail: scuesta@ubu.es
2013-12-15
Highlights: • The work presented in this manuscript provides a reliable computational tool to quantify the He complex phenomena in a HCLL. • A model based on the self-consistent nucleation theory (SCT) is exposed. It includes radiation induced nucleation modelling and surface tension corrections. • Results informed reinforce the necessity of conducting experiments to determine nucleation conditions and bubble transport parameters in LM breeders. • Our findings and model provide a good qualitative insight into the helium nucleation phenomenon in LM systems for fusion technology and can be used to identify key system parameters. -- Abstract: Helium (He) nucleation in liquid metal breeding blankets of a DT fusion reactor may have a significant impact regarding system design, safety and operation. Large He production rates are expected due to tritium (T) fuel self-sufficiency requirement, as both, He and T, are produced at the same rate. Low He solubility, local high concentrations, radiation damage and fluid discontinuities, among other phenomena, may yield the necessary conditions for He nucleation. Hence, He nucleation may have a significant impact on T inventory and may lower the T breeding ratio. A model based on the self-consistent nucleation theory (SCT) with a surface tension curvature correction model has been implemented in OpenFOAM{sup ®} CFD code. A modification through a single parameter of the necessary nucleation condition is proposed in order to take into account all the nucleation triggering phenomena, specially radiation induced nucleation. Moreover, the kinetic growth model has been adapted so as to allow for the transition from a critical cluster to a macroscopic bubble with a diffusion growth process. Limitations and capabilities of the models are shown by means of zero-dimensional simulations and sensitivity analyses to key parameters under HCLL breeding unit conditions. Results provide a good qualitative insight into the helium
Highlights: • The work presented in this manuscript provides a reliable computational tool to quantify the He complex phenomena in a HCLL. • A model based on the self-consistent nucleation theory (SCT) is exposed. It includes radiation induced nucleation modelling and surface tension corrections. • Results informed reinforce the necessity of conducting experiments to determine nucleation conditions and bubble transport parameters in LM breeders. • Our findings and model provide a good qualitative insight into the helium nucleation phenomenon in LM systems for fusion technology and can be used to identify key system parameters. -- Abstract: Helium (He) nucleation in liquid metal breeding blankets of a DT fusion reactor may have a significant impact regarding system design, safety and operation. Large He production rates are expected due to tritium (T) fuel self-sufficiency requirement, as both, He and T, are produced at the same rate. Low He solubility, local high concentrations, radiation damage and fluid discontinuities, among other phenomena, may yield the necessary conditions for He nucleation. Hence, He nucleation may have a significant impact on T inventory and may lower the T breeding ratio. A model based on the self-consistent nucleation theory (SCT) with a surface tension curvature correction model has been implemented in OpenFOAM® CFD code. A modification through a single parameter of the necessary nucleation condition is proposed in order to take into account all the nucleation triggering phenomena, specially radiation induced nucleation. Moreover, the kinetic growth model has been adapted so as to allow for the transition from a critical cluster to a macroscopic bubble with a diffusion growth process. Limitations and capabilities of the models are shown by means of zero-dimensional simulations and sensitivity analyses to key parameters under HCLL breeding unit conditions. Results provide a good qualitative insight into the helium nucleation
Theory of Optimal Currency Zones: from Classics until Today
Pinchuk Anastasiya K.
2013-12-01
Full Text Available The article analyses evolution of the theory of optimal currency zones (OCZ, starting from its classical provisions until moder developments. Based on the critical analysis of classical criteria of OCZ, the article develops a scheme of selection of the currency mode by the Robert Mundell theory. It considers achievements of the alternative OCZ theory, the main provisions of which are shown schematically in the form of illustrations of evolution of the theory of optimal currency zones. In the result of analysis of classical criteria of optimal currency zones and generalisation of developments of the new OCZ theory, the article develops a universal algorithm of identification of optimal conditions for an efficient currency zone. Using this algorithm allows identification of a system of quantitative indicators of expediency of regional joining the OCZ, on the basis of which one can build an economic model of an optimal currency zone, which reflects the degree of readiness of any country to join or develop the OCZ. Development of this model is necessary for many countries that face the need to select the currency integration. This model is of special importance for Ukraine, for which it is important to select the course of external integration, since various directions of foreign policy significantly influence efficiency of the domestic economic policy in the country.
Momentum Maps and Classical Relativistic Fields; 1, Covariant Field Theory
Gotay, M J; Marsden, J E; Gotay, Mark J.; Isenberg, James; Marsden, Jerrold E.
1998-01-01
This is the first paper of a four part work in which we study the Lagrangian and Hamiltonian structure of classical field theories with constraints. Our goal is to explore some of the connections between initial value constraints and gauge transformations in such theories (either relativistic or not). To do this, in the course of these four papers, we develop and use a number of tools from symplectic and multisymplectic geometry. Of central importance in our analysis is the notion of the ``energy-momentum map'' associated to the gauge group of a given classical field theory. We hope to demonstrate that many different and apparently unrelated facets of field theories can be thereby tied together and understood in an essentially new way. In Part I we develop some of the basic theory of classical fields from a spacetime covariant viewpoint. We begin with a study of the covariant Lagrangian and Hamiltonian formalisms, on jet bundles and multisymplectic manifolds, respectively. Then we discuss symmetries, conserva...
Classical Bianchi Type I Cosmology in K-Essence Theory
2014-01-01
We use one of the simplest forms of the K-essence theory and we apply it to the classical anisotropic Bianchi type I cosmological model, with a barotropic perfect fluid ( p=γρ ) modeling the usual matter content and with cosmological constant Λ . Classical exact solutions for any γ≠1 and Λ=0 are found in closed form, whereas solutions for Λ≠0 are found for particular values in the barotropic parameter. We present the possible isotropization of the cosmological model Bianchi I using the ratio ...
THE NEW CLASSICAL THEORY AND THE REAL BUSINESS CYCLE MODEL
Oana Simona HUDEA (CARAMAN
2014-11-01
Full Text Available The present paper aims at describing some key elements of the new classical theory-related model, namely the Real Business Cycle, mainly describing the economy from the perspective of a perfectly competitive market, characterised by price, wage and interest rate flexibility. The rendered impulse-response functions, that help us in revealing the capacity of the model variables to return to their steady state under the impact of a structural shock, be it technology or monetary policy oriented, give points to the neutrality of the monetary entity decisions, therefore confirming the well-known classical dichotomy existing between the nominal and the real factors of the economy.
Fradera, Jorge
2013-01-01
Helium (He) nucleation in liquid metal breeding blankets of a DT fusion reactor may have a significant impact regarding system design, safety and operation. Large He production rates are expected due to tritium (T) fuel self-sufficiency requirement, as both, He and T, are produced at the same rate. Low He solubility, local high concentrations, radiation damage and fluid discontinuities, among other phenomena, may yield the necessary conditions for He nucleation. Hence, He nucleation may have a significant impact on T inventory and may lower the T breeding ratio. A model based on the self-consistent nucleation theory (SCT) with a surface tension curvature correction model has been implemented in OpenFoam(r) CFD code. A modification through a single parameter of the necessary nucleation condition is proposed in order to take into account all the nucleation triggering phenomena, specially radiation induced nucleation. Moreover, the kinetic growth model has been adapted so as to allow for the transition from a cr...
Classic Grounded Theory to Analyse Secondary Data: Reality and Reflections
Lorraine Andrews
2012-06-01
Full Text Available This paper draws on the experiences of two researchers and discusses how they conducted a secondary data analysis using classic grounded theory. The aim of the primary study was to explore first-time parents’ postnatal educational needs. A subset of the data from the primary study (eight transcripts from interviews with fathers was used for the secondary data analysis. The objectives of the secondary data analysis were to identify the challenges of using classic grounded theory with secondary data and to explore whether the re-analysis of primary data using a different methodology would yield a different outcome. Through the process of re-analysis a tentative theory emerged on ‘developing competency as a father’. Challenges encountered during this re-analysis included the small dataset, the pre-framed data, and limited ability for theoretical sampling. This re-analysis proved to be a very useful learning tool for author 1(LA, who was a novice with classic grounded theory.
Quantum Mind from a Classical Field Theory of the Brain
Zizzi, Paola
2011-01-01
We suggest that, with regard to a theory of quantum mind, brain processes can be described by a classical, dissipative, non-abelian gauge theory. In fact, such a theory has a hidden quantum nature due to its non-abelian character, which is revealed through dissipation, when the theory reduces to a quantum vacuum, where temperatures are of the order of absolute zero, and coherence of quantum states is preserved. We consider in particular the case of pure SU(2) gauge theory with a special anzatz for the gauge field, which breaks Lorentz invariance. In the ansatz, a contraction mapping plays the role of dissipation. In the limit of maximal dissipation, which corresponds to the attractive fixed point of the contraction mapping, the gauge fields reduce, up to constant factors, to the Pauli quantum gates for one-qubit states. Then tubuline-qubits can be processed in the quantum vacuum of the classical field theory of the brain, where decoherence is avoided due to the extremely low temperature. Finally, we interpret...
Podmaniczky, Frigyes; Tóth, Gyula I.; Tegze, György; Gránásy, László
2015-11-01
Crystallization of supersaturated liquids usually starts by epitaxial growth or by heterogeneous nucleation on foreign surfaces. Herein, we review recent advances made in modeling heteroepitaxy and heterogeneous nucleation on flat/modulated surfaces and nanoparticles within the framework of a simple dynamical density functional theory, known as the phase-field crystal model. It will be shown that the contact angle and the nucleation barrier are nonmonotonous functions of the lattice mismatch between the substrate and the crystalline phase. In continuous cooling studies for substrates with lattice mismatch, we recover qualitatively the Matthews-Blakeslee mechanism of stress release via the misfit dislocations. The simulations performed for particle-induced freezing will be confronted with recent analytical results, exploring thus the validity range of the latter. It will be demonstrated that time-dependent studies are essential, as investigations based on equilibrium properties often cannot identify the preferred nucleation pathways. Modeling of these phenomena is essential for designing materials on the basis of controlled nucleation and/or nano-patterning.
Classical field theory on electrodynamics, non-Abelian gauge theories and gravitation
Scheck, Florian
2012-01-01
The book describes Maxwell's equations first in their integral, directly testable form, then moves on to their local formulation. The first two chapters cover all essential properties of Maxwell's equations, including their symmetries and their covariance in a modern notation. Chapter 3 is devoted to Maxwell theory as a classical field theory and to solutions of the wave equation. Chapter 4 deals with important applications of Maxwell theory. It includes topical subjects such as metamaterials with negative refraction index and solutions of Helmholtz' equation in paraxial approximation relevant for the description of laser beams. Chapter 5 describes non-Abelian gauge theories from a classical, geometric point of view, in analogy to Maxwell theory as a prototype, and culminates in an application to the U(2) theory relevant for electroweak interactions. The last chapter 6 gives a concise summary of semi-Riemannian geometry as the framework for the classical field theory of gravitation. The chapter concludes wit...
Zatloukal, Václav
2016-04-01
Classical field theory is considered as a theory of unparametrized surfaces embedded in a configuration space, which accommodates, in a symmetric way, spacetime positions and field values. Dynamics is defined by a (Hamiltonian) constraint between multivector-valued generalized momenta, and points in the configuration space. Starting from a variational principle, we derive local equations of motion, that is, differential equations that determine classical surfaces and momenta. A local Hamilton-Jacobi equation applicable in the field theory then follows readily. The general method is illustrated with three examples: non-relativistic Hamiltonian mechanics, De Donder-Weyl scalar field theory, and string theory.
Quiver Theories for Moduli Spaces of Classical Group Nilpotent Orbits
Hanany, Amihay
2016-01-01
We approach the topic of Classical group nilpotent orbits from the perspective of their moduli spaces, described in terms of Hilbert series and generating functions. We review the established Higgs and Coulomb branch quiver theory constructions for A series nilpotent orbits. We present systematic constructions for BCD series nilpotent orbits on the Higgs branches of quiver theories defined by canonical partitions; this paper collects earlier work into a systematic framework, filling in gaps and providing a complete treatment. We find new Coulomb branch constructions for above minimal nilpotent orbits, including some based upon twisted affine Dynkin diagrams. We also discuss aspects of 3d mirror symmetry between these Higgs and Coulomb branch constructions and explore dualities and other relationships, such as HyperKahler quotients, between quivers. We analyse all Classical group nilpotent orbit moduli spaces up to rank 4 by giving their unrefined Hilbert series and the Highest Weight Generating functions for ...
Quantum to classical transition in quantum field theory
Lombardo, F C
1998-01-01
We study the quatum to classical transition process in the context of quantum field theory. Extending the influence functional formalism of Feynman and Vernon, we study the decoherence process for self-interacting quantum fields in flat space. We also use this formalism for arbitrary geometries to analyze the quantum to classical transition in quantum gravity. After summarizing the main results known for the quantum Brownian motion, we consider a self-interacting field theory in Minkowski spacetime. We compute a coarse grained effective action by integrating out the field modes with wavelength shorter than a critical value. From this effective action we obtain the evolution equation for the reduced density matrix (master equation). We compute the diffusion coefficients for this equation and analyze the decoherence induced on the long-wavelength modes. We generalize the results to the case of a conformally coupled scalar field in de Sitter spacetime. We show that the decoherence is effective as long as the cri...
THE NEW CLASSICAL THEORY AND THE REAL BUSINESS CYCLE MODEL
Oana Simona HUDEA (CARAMAN); Sorin George TOMA; Marin BURCEA
2014-01-01
The present paper aims at describing some key elements of the new classical theory-related model, namely the Real Business Cycle, mainly describing the economy from the perspective of a perfectly competitive market, characterised by price, wage and interest rate flexibility. The rendered impulse-response functions, that help us in revealing the capacity of the model variables to return to their steady state under the impact of a structural shock, be it technology or monetary policy oriented, ...
On Covariant Poisson Brackets in Classical Field Theory
Forger, Michael; Salles, Mário O.
2015-01-01
How to give a natural geometric definition of a covariant Poisson bracket in classical field theory has for a long time been an open problem - as testified by the extensive literature on "multisymplectic Poisson brackets", together with the fact that all these proposals suffer from serious defects. On the other hand, the functional approach does provide a good candidate which has come to be known as the Peierls - De Witt bracket and whose construction in a geometrical setting is now well unde...
A magnetic condensate solution of the classical electroweak theory
According to the electroweak theory a large homogeneous magnetic field exceeding m2w/e is unstable. We present a different solution of the classical electroweak field equations which is a condensate of magnetic fluxes induced by an anti-Lenz current of the charged vector bosons. The anti-Lenz mechanism is a consequence of asymptotic freedom. The range of validity of this solution depends on the Weinberg angle θ. (orig.)
A New Fuzzy Set Theory Satisfying All Classical Set Formulas
Qing-Shi Gao; Xiao-Yu Gao; Yue Hu
2009-01-01
A new fuzzy set theory, C-fuzzy set theory, is introduced in this paper. It is a particular case of the classical set theory and satisfies all formulas of the classical set theory. To add a limitation to C-fuzzy set system, in which all fuzzy sets must be "non-uniform inclusive" to each other, then it forms a family of sub-systems, the Z-fuzzy set family. It can be proved that the Z0-fuzzy set system, one of Z-fuzzy set systems, is equivalent to Zadeh's fuzzy set system. Analysis shows that 1) Zadeh's fuzzy set system defines the relations A = B and A ∈B between two fuzzy sets A and B as "Vu e U,(u A E (u)=μB(U))" and "Au ∈ U, (μA(U) ≤μB(μ))" respectively is inappropriate, because it makes all fuzzy sets be "non-uniformly inclusive"; 2) it is also inappropriate to define two fuzzy sets' union and intersection operations as the max and rain of their grades of membership, because this prevents fuzzy set's ability to correctly reflect different kinds of fuzzy phenomenon in the natural world. Then it has to work around the problem by invent unnatural functions that are hard to understand, such as augmenting max and min for union and intersection to min{a + b, 1} and max{a + b - 1, 0}, but these functions are incorrect on inclusive case. If both pairs of definitions are used together, not only are they unnatural, but also they are still unable to cover all possible set relationships in the natural world; and 3) it is incorrect to define the set complement as 1 -μA(μ), because it can be proved that set complement cannot exist in Zadeh's fuzzy set, and it causes confusion in logic and thinking. And it is seriously mistaken to believe that logics of fuzzy sets necessarily go against classical and normal thinking, logic, and conception. The C-fuzzy set theory proposed in this paper overcomes all of the above errors and shortcomings, and more reasonably reflects fuzzy phenomenon in the natural world. It satisfies all relations, formulas, and operations of the
Geometric aspects in extended approach of equilibrium classical fluctuation theory
Velazquez, L.
2011-11-01
Previously, an extended approach of equilibrium classical fluctuation theory was developed compatible with the existence of anomalous response functions, e.g. states with negative heat capacities. Now, the geometric aspects associated with this new framework are analyzed. The analysis starts from the so-called reparametrization invariance: a special symmetry of distribution functions dp (I|θ) employed in classical equilibrium statistical mechanics that allows us to express the thermo-statistical relations in the same mathematical appearance in different coordinate representations. The existence of reparametrization invariance can be related to three different geometric frameworks: (1) a non-Riemannian formulation for classical fluctuation theory based on the concept of reparametrization dualities; (2) a Riemannian formulation defined on the manifold {P} of control parameters θ, where the main theorems of inference theory appear as dual counterparts of general fluctuation theorems, and Boltzmann-Gibbs distributions ωBG(I|θ) = exp(-θiIi)/Z(θ) admit a geometric generalization; and finally, (3) a Riemannian formulation defined on the manifold {M}_{\\theta } of macroscopic observables I, which appears as a counterpart approach of inference geometry.
Olhac, X.; Fillet, C. [CEA Valrho, Dir. de l' Energie Nucleaire, DEN, 30 - Marcoule (France); Phalippou, J. [Montpellier-2 Univ., Lab. des Verres, 34 (France)
1997-07-01
Since the quality of the glass will be affected by its thermal history, an assessment of thermal stability of waste glasses is necessary. A brief review of the classical nucleation theory in glass forming systems is presented. Particular emphasis is given to the driving force and the kinetic barrier which control the beginning of nucleation. The general theory of phase transformation kinetics derived by Kolmogorov-Johnson-Mehl-Avrami is also exposed, including an application of this model to follow the overall crystallization. Special attention is given to devitrification at low temperature. The long time storage of waste glasses at low temperature (below Tg) is next studied with regard to crystallization. Some provisional studies of devitrification rates at low temperature are introduced, based on extrapolation of high temperature measures. Furthermore, in order to understand the mechanisms occurring in the low temperature range, others experiments in concern with specific properties (viscosity, diffusion) are presented. They demonstrate that the occurrence of nucleation and crystal growth at low temperature indicates a decoupling between the kinetic coefficient for transport at the crystal/glass interface and the bulk viscosity. (authors)
Investigation of Vapor-Liquid Nucleation for Associating Fluids by Density Gradient Theory
FU Dong; LIU Jianmin
2009-01-01
An equation of state (EOS) applicable to both the uniform and non-uniform associating fluids was established by using the density-gradient expansion, in which the influence parameter κis formulated as a function of tempera-ture. The molecular parameters were regressed by fitting to the experimental data of vapor pressures and liquid den-sities. Within the framework of density gradient theory (DGT), the nucleation rates for water, heavy water, metha-nol, ethanol, 1-propanoi, 1-butanol, 1-pentanol and 1-hexanol were calculated. The results were satisfactory com-pared with the experimental data. Our study shows that DGT preserves all the advantages of density functional the-ory (DFT) in capturing the structure and properties of nucleus but gives much more accurate nucleation rates by adjusting the influence parameter.
Self-consistent nonperturbative theory for classical systems.
Mederos, L; Navascués, G; Velasco, E
2002-01-01
We construct a self-consistent nonperturbative theory for the structure and thermodynamics of a classical system of particles that goes beyond the usual approaches based on perturbation theory. Our theory, which gives accurate predictions for the phase diagram, is based on two ingredients: first, use is made of an exact expression for the free energy of a many-body system in terms of a reference system and a coupling integral connecting the latter to the final system; second, correlation functions may be very accurately approximated using a number of sum rules relating the radial distribution function with thermodynamic quantities. Consistency between the coupling integral expression and the sum rules may be achieved by means of a self-consistent process. PMID:11800760
On some classical problems of descriptive set theory
The centenary of P.S. Novikov's birth provides an inspiring motivation to present, with full proofs and from a modern standpoint, the presumably definitive solutions of some classical problems in descriptive set theory which were formulated by Luzin [Lusin] and, to some extent, even earlier by Hadamard, Borel, and Lebesgue and relate to regularity properties of point sets. The solutions of these problems began in the pioneering works of Aleksandrov [Alexandroff], Suslin [Souslin], and Luzin (1916-17) and evolved in the fundamental studies of Goedel, Novikov, Cohen, and their successors. Main features of this branch of mathematics are that, on the one hand, it is an ordinary mathematical theory studying natural properties of point sets and functions and rather distant from general set theory or intrinsic problems of mathematical logic like consistency or Goedel's theorems, and on the other hand, it has become a subject of applications of the most subtle tools of modern mathematical logic
Common Axioms for Inferring Classical Ensemble Dynamics and Quantum Theory
Parwani, R R
2005-01-01
Within a hamiltonian framework, the same set of physically motivated axioms is used to construct both the classical ensemble Hamilton-Jacobi equation and Schrodingers equation. Crucial roles are played by the assumptions of universality and simplicity (Occam's Razor) which restrict the number and type of of arbitrary constants that appear in the hamiltonian. In this approach, non-relativistic quantum theory is seen as the unique single parameter extension of the classical ensemble dynamics. The method is contrasted with other related constructions in the literature. Possible generalisation to the relativistic case, and some consequences of relaxing the axioms, are also discussed: for example, simple extensions of the linear Schrodinger equation lead to higher-derivative nonlinear corrections that are possibly related to gravity.
The theory of variational hybrid quantum-classical algorithms
McClean, Jarrod R; Babbush, Ryan; Aspuru-Guzik, Alán
2015-01-01
Many quantum algorithms have daunting resource requirements when compared to what is available today. To address this discrepancy, a quantum-classical hybrid optimization scheme known as "the quantum variational eigensolver" was developed with the philosophy that even minimal quantum resources could be made useful when used in conjunction with classical routines. In this work we extend the general theory of this algorithm and suggest algorithmic improvements for practical implementations. Specifically, we develop a variational adiabatic ansatz and explore unitary coupled cluster where we establish a connection from second order unitary coupled cluster to universal gate sets through relaxation of exponential splitting. We introduce the concept of quantum variational error suppression that allows some errors to be suppressed naturally in this algorithm on a pre-threshold quantum device. Additionally, we analyze truncation and correlated sampling in Hamiltonian averaging as ways to reduce the cost of this proced...
BOOK REVIEW: Classical Solutions in Quantum Field Theory Classical Solutions in Quantum Field Theory
Mann, Robert
2013-02-01
Quantum field theory has evolved from its early beginnings as a tool for understanding the interaction of light with matter into a rather formidable technical paradigm, one that has successfully provided the mathematical underpinnings of all non-gravitational interactions. Over the eight decades since it was first contemplated the methods have become increasingly more streamlined and sophisticated, yielding new insights into our understanding of the subatomic world and our abilities to make clear and precise predictions. Some of the more elegant methods have to do with non-perturbative and semiclassical approaches to the subject. The chief players here are solitons, instantons, and anomalies. Over the past three decades there has been a steady rise in our understanding of these objects and of our ability to calculate their effects and implications for the rest of quantum field theory. This book is a welcome contribution to this subject. In 12 chapters it provides a clear synthesis of the key developments in these subjects at a level accessible to graduate students that have had an introductory course to quantum field theory. In the author's own words it provides both 'a survey and an overview of this field'. The first half of the book concentrates on solitons--kinks, vortices, and magnetic monopoles--and their implications for the subject. The reader is led first through the simplest models in one spatial dimension, into more sophisticated cases that required more advanced topological methods. The author does quite a nice job of introducing the various concepts as required, and beginning students should be able to get a good grasp of the subject directly from the text without having to first go through the primary literature. The middle part of the book deals with the implications of these solitons for both cosmology and for duality. While the cosmological discussion is quite nice, the discussion on BPS solitons, supersymmetry and duality is rather condensed. It is
Motion of small bodies in classical field theory
I show how prior work with R. Wald on geodesic motion in general relativity can be generalized to classical field theories of a metric and other tensor fields on four-dimensional spacetime that (1) are second-order and (2) follow from a diffeomorphism-covariant Lagrangian. The approach is to consider a one-parameter-family of solutions to the field equations satisfying certain assumptions designed to reflect the existence of a body whose size, mass, and various charges are simultaneously scaled to zero. (That such solutions exist places a further restriction on the class of theories to which our results apply.) Assumptions are made only on the spacetime region outside of the body, so that the results apply independent of the body's composition (and, e.g., black holes are allowed). The worldline 'left behind' by the shrinking, disappearing body is interpreted as its lowest-order motion. An equation for this worldline follows from the 'Bianchi identity' for the theory, without use of any properties of the field equations beyond their being second-order. The form of the force law for a theory therefore depends only on the ranks of its various tensor fields; the detailed properties of the field equations are relevant only for determining the charges for a particular body (which are the ''monopoles'' of its exterior fields in a suitable limiting sense). I explicitly derive the force law (and mass-evolution law) in the case of scalar and vector fields, and give the recipe in the higher-rank case. Note that the vector force law is quite complicated, simplifying to the Lorentz force law only in the presence of the Maxwell gauge symmetry. Example applications of the results are the motion of 'chameleon' bodies beyond the Newtonian limit, and the motion of bodies in (classical) non-Abelian gauge theory. I also make some comments on the role that scaling plays in the appearance of universality in the motion of bodies.
Local gauge invariant Lagrangeans in classical field theories
We investigate the most general local gauge invariant Lagrangean in the framework of classical field theory. We rederive esentially Utiyama's result with a slight generalization. Our proof makes clear the importance of the so called current conditions, i.e. the requirement that the Noether currents are different from zero. This condition is of importance both in the general motivation for the introduction of the Yang-Mills fields and for the actual proof. Some comments are made about the basic mathematical structure of the problem - the gauge group. (author)
Lie Groupoids in Classical Field Theory I: Noether's Theorem
Costa, Bruno T; Pêgas, Luiz Henrique P
2015-01-01
In the two papers of this series, we initiate the development of a new approach to implementing the concept of symmetry in classical field theory, based on replacing Lie groups/algebras by Lie groupoids/algebroids, which are the appropriate mathematical tools to describe local symmetries when gauge transformations are combined with space-time transformations. Here, we outline the basis of the program and, as a first step, show how to (re)formulate Noether's theorem about the connection between symmetries and conservation laws in this approach.
Topics In False Vacuum Decay (bubble Nucleation, Gauge Dependence, Quantum Field Theory)
Metaxas, D
1998-01-01
I review the formalism for the computation of the rate of false vacuum decay in field theories with a metastable vacuum state. I then proceed to consider the case of field theories where the false vacuum arises as a result of radiative corrections. There the calculation of the rate of false vacuum decay by bubble nucleation depends on the effective potential and the other functions that appear in the derivative expansion of the effective action. Beginning with the Nielsen identity, I derive a series of identities that describe the gauge dependence of these functions...
Inada, Takaaki; Koyama, Toshie; Goto, Fumitoshi; Seto, Takafumi
2011-06-23
Antifreeze protein (AFP) III and poly(vinyl alcohol) (PVA) are known as anti-ice nucleating agents (anti-INAs), which inhibit heterogeneous ice nucleation. However, the effectiveness of these anti-INAs in inhibiting ice nucleation in water-in-oil (W/O) emulsions, in which homogeneous ice nucleation can be experimentally simulated, is unclear. In this study, the ice nucleation temperature in emulsified solutions of AFP III, PVA, and other nonanti-INA polymers was measured, and then the nucleation rate was analyzed based on classical nucleation theory. Results showed that ice nucleation was surface-initiated and, except for PVA solutions, probably caused heterogeneously by the emulsifier, SPAN 65, at the droplet surfaces. In this nucleation mode, AFP III had no significant effect on the ice nucleation rate. In contrast, PVA exhibited ice-nucleating activity only at the droplet surfaces, suggesting that the nucleation is due to the interaction between PVA and SPAN 65. PMID:21619040
Emergence Of A Classical World From Within Quantum Theory
Poulin, D
2005-01-01
The starting point of this dissertation is that a quantum state represents the observer's knowledge about the system of interest. As it has been pointed out several times by the opponents of this epistemic interpretation, it is difficult to reconcile this point of view with our common notion of “physical reality”, which exists independently of our monitoring, and can be discovered without disturbance. Indeed, if quantum theory is correct, it should apply to classical systems—including measurement devices—as well as to any other system. In this dissertation, we will study the quantum mechanisms responsible for our perception of the world and demonstrate how they lead to the emergence of an operational objective reality from within quantum theory: several observers gathering information through these mechanisms will arrive at a common consensus about the properties of the world. The two mechanisms we study in great detail are the redundant proliferation of information in ...
Stochastic theory for classical and quantum mechanical systems
From first principles a theory of stochastic processes in configuration space is formulated. The fundamental equations of the theory are an equation of motion which generalizes Newton's second law and an equation which expresses the condition of conservation of matter. Two types of stochastic motion are possible, both described by the same general equations, but leading in one case to classical Brownian motion behavior and in the other to quantum mechanical behavior. The Schroedinger equation, which is derived with no further assumption, is thus shown to describe a specific stochastic process. It is explicitly shown that only in the quantum mechanical process does the superposition of probability amplitudes give rise to interference phenomena; moreover, the presence of dissipative forces in the Brownian motion equations invalidates the superposition principle. At no point are any special assumptions made concerning the physical nature of the underlying stochastic medium, although some suggestions are discussed in the last section
Marshaling Resources: A Classic Grounded Theory Study of Online Learners
Barbara Yalof
2014-06-01
Full Text Available Classic grounded theory (CGT was used to identify a main concern of online students in higher education. One of the main impediments to studying online is a sense of isolation and lack of access to support systems as students navigate through complex requirements of their online programs. Hypothetical probability statements illustrate the imbalance between heightened needs of virtual learners and perceived inadequate support provided by educational institutions. The core variable, marshaling resources, explains how peer supports sustain motivation toward successful program completion. Understanding the critical contribution virtual interpersonal networks make towards maximizing resources by group problem solving is a significant aspect of this theory. Keywords: Online learning, e-learning, personal learning networks, peer networks
Gauge independence of the bubble nucleation rate in theories with radiative symmetry breaking
Metaxas, D.; Weinberg, E.J. [Department of Physics, Columbia University, New York, New York 10027 (United States)
1996-01-01
In field theories where a metastable false vacuum state arises as a result of radiative corrections, the calculation of the rate of false vacuum decay by bubble nucleation depends on the effective potential and the other functions that appear in the derivative expansion of the effective action. Beginning with the Nielsen identity, we derive a series of identities that govern the gauge dependence of these functions. Using these, we show, to leading nontrivial order, that, even though these functions are individually gauge dependent, one obtains a gauge-independent result for the bubble nucleation rate. Our formal arguments are complemented by explicit calculations for scalar electrodynamics in a class of {ital R}{sub {xi}} gauges. {copyright} {ital 1996 The American Physical Society.}
Gauge independence of the bubble nucleation rate in theories with radiative symmetry breaking
Metaxas, D; Metaxas, Dimitrios; Weinberg, Erick J
1996-01-01
In field theories where a metastable false vacuum state arises as a result of radiative corrections, the calculation of the rate of false vacuum decay by bubble nucleation depends on the effective potential and the other functions that appear in the derivative expansion of the effective action. Beginning with the Nielsen identity, we derive a series of identities that govern the gauge dependence of these functions. Using these, we show, to leading nontrivial order, that even though these functions are individually gauge-dependent, one obtains a gauge-independent result for the bubble nucleation rate. Our formal arguments are complemented by explicit calculations for scalar electrodynamics in a class of R_\\xi gauges.
Binary Nucleation of Water and Sodium Chloride
Nemec, Thomas [Institute of Thermomechanics ASCR, Prague, Czech Republic; Marsik, Frantisek [Institute of Thermomechanics ASCR, Prague, Czech Republic; Palmer, Donald [ORNL
2005-01-01
Nucleation processes in the binary water-sodium chloride system are investigated in the sense of the classical nucleation theory (CNT). The CNT is modified to be able to handle the electrolytic nature of the system and is employed to investigate the acceleration of the nucleation process due to the presence of sodium chloride in the steam. This phenomenon, frequently observed in the Wilson zone of steam turbines, is called early condensation. Therefore, the nucleation rates of the water-sodium chloride mixture are of key importance in the power cycle industry.
Quasiperiodical orbits in the scalar classical lambdaphi4 field theory
New numerical and theoretical results of resonance kink-antikink (Kanti K) interactions in the classical one-dimentional space Higgs theory are presented. Earlier studies of these interactions revealed nine initial relative velocity-intervals with two-bounce Kanti K-collisions followed by the escape of kinks to infinite separations, the breathing solution was formed outside those intervals. Two-bounce Kanti K-interactions with the number of small oscillations between Kanti K-bounces up to 35 in the initial kink velocity interval 0.18 <= Vsub(infinite) <= 0.26 were found. Several examples for n-bounces Kanti K-interaction (n <= 6) are also found. The observed phenomenon can be explaned by the existence of quasi-two-periodical solutions of the nonlinear wave equation. The simple Hamiltonian with two degrees of freedom is studied. This model supplies quantitative descrtiptions of all numerical results for the field theory considered above. The considered phenomenon may be called ''autoquantization'' of a nonlinear classical scalar selfinteracting field
Emergence of a classical world from within quantum theory
Poulin, David
The starting point of this dissertation is that a quantum state represents the observer's knowledge about the system of interest. As it has been pointed out several times by the opponents of this epistemic interpretation, it is difficult to reconcile this point of view with our common notion of "physical reality", which exists independently of our monitoring, and can be discovered without disturbance. Indeed, if quantum theory is correct, it should apply to classical systems---including measurement devices---as well as to any other system. In this dissertation, we will study the quantum mechanisms responsible for our perception of the world and demonstrate how they lead to the emergence of an operational objective reality from within quantum theory: several observers gathering information through these mechanisms will arrive at a common consensus about the properties of the world. The two mechanisms we study in great detail are the redundant proliferation of information in the environment and the direct measurement of a macroscopic observable. An example of the first mechanism is the photon environment which provides us with our visual data about the world. Several independent observers learning about their surroundings in this indirect fashion will agree on their findings. An example of the second mechanism is our tactile information: when the tip of our finger touches an object, it interacts collectively with a very large number of molecules. Again, under realistic assumptions, this type of information acquisition will lead to a classical perception of the world.
Wu, Ning; Zhang, Dahua
2005-01-01
A systematic method is developed to study classical motion of a mass point in gravitational gauge field. First, the formulation of gauge theory of gravity in arbitrary curvilinear coordinates is given. Then in spherical coordinates system, a spherical symmetric solution of the field equation of gravitational gauge field is obtained, which is just the Schwarzschild solution. In gauge theory of gravity, the equation of motion of a classical mass point in gravitational gauge field is given by Ne...
Complex analysis fundamentals of the classical theory of functions
Stalker, John
1998-01-01
This clear, concise introduction to the classical theory of one complex variable is based on the premise that "anything worth doing is worth doing with interesting examples." The content is driven by techniques and examples rather than definitions and theorems. This self-contained monograph is an excellent resource for a self-study guide and should appeal to a broad audience. The only prerequisite is a standard calculus course. The first chapter deals with a beautiful presentation of special functions. . . . The third chapter covers elliptic and modular functions. . . in much more detail, and from a different point of view, than one can find in standard introductory books. . . . For [the] subjects that are omitted, the author has suggested some excellent references for the reader who wants to go through these topics. The book is read easily and with great interest. It can be recommended to both students as a textbook and to mathematicians and physicists as a useful reference. ---Mathematical Reviews Mainly or...
Non-linear coupling of quantum theory and classical gravity
The possibility that the non-linear evolution proposed earlier for a relativistic quantum field theory may be related to its coupling to a classical gravitational field is discussed. Formally, in the Schroedinger picture, it is shown how both the Schroedinger equation and Einstein's equations (with the expectation value of the energy-momentum tensor on the right) can be derived from a variational principle. This yields a non-linear quantum evolution. Other terms can be added to the action integral to incorporate explicit non-linearities of the type discussed previously. The possibility of giving a meaning to the resulting equation in a Heisenberg or interaction-like picture, is briefly discussed. (author)
Deformation Quantization of Principal Fibre Bundles and Classical Gauge Theories
Wei\\ss, Stefan
2010-01-01
In this dissertation the notion of deformation quantization of principal fibre bundles is established and investigated in order to find a geometric formulation of classical gauge theories on noncommutative space-times. As a generalization, the notion of deformation quantization of surjective submersions is also discussed. It is shown that deformation quantizations of surjective submersions and principal fibre bundles always exist and are unique up to equivalence. These statements concerning complex-valued functions are moreover formulated and proved for sections of arbitrary vector bundles over the total space, in particular equivariant vector bundles. The commutants of the deformed right module structures within the differential operators, playing an inportant role with regard to the infinitesimal gauge transformations, are computed explicitly in each case. Depending on the choice of specific covariant derivatives and connections the commutants are isomorphic to the formal power series of the respective vert...
Geometry of Lagrangian first-order classical field theories
We construct a lagrangian geometric formulation for first-order field theories using the canonical structures of first-order jet bundles, which are taken as the phase spaces of the systems in consideration. First of all, we construct all the geometric structures associated with a first-order jet bundle and, using them, we develop the lagrangian formalism, defining the canonical forms associated with a lagrangian density and the density of lagrangian energy, obtaining the Euler-Lagrange equations in two equivalent ways: as the result of a variational problem and developing the jet field formalism (which is a formulation more similar to the case of mechanical systems). A statement and proof of Noether's theorem is also given, using the latter formalism. Finally, some classical examples are briefly studied. (orig.)
Latfield2: A c++ library for classical lattice field theory
David, Daverio; Bevis, Neil
2015-01-01
latfield2 is a C++ library designed to simplify writing parallel codes for solving partial differen- tial equations, developed for application to classical field theories in particle physics and cosmology. It is a significant rewrite of the latfield framework, moving from a slab domain decomposition to a rod decomposition, where the last two dimension of the lattice are scattered into a two dimensional process grid. Parallelism is implemented using the Message Passing Interface (MPI) standard, and hidden in the basic objects of grid-based simulations: Lattice, Site and Field. It comes with an integrated parallel fast Fourier transform, and I/O server class permitting computation to continue during the writing of large files to disk. latfield2 has been used for production runs on tens of thousands of processor elements, and is expected to be scalable to hundreds of thousands.
Geometry of Lagrangian first-order classical field theories
Echeverria-Enriquez, A. [Univ. Politecnica de Cataluna, Barcelona (Spain). Departamento de Matematica Aplicada y Telematica; Munoz-Lecanda, M.C. [Univ. Politecnica de Cataluna, Barcelona (Spain). Departamento de Matematica Aplicada y Telematica; Roman-Roy, N. [Univ. Politecnica de Cataluna, Barcelona (Spain). Departamento de Matematica Aplicada y Telematica
1996-10-01
We construct a lagrangian geometric formulation for first-order field theories using the canonical structures of first-order jet bundles, which are taken as the phase spaces of the systems in consideration. First of all, we construct all the geometric structures associated with a first-order jet bundle and, using them, we develop the lagrangian formalism, defining the canonical forms associated with a lagrangian density and the density of lagrangian energy, obtaining the Euler-Lagrange equations in two equivalent ways: as the result of a variational problem and developing the jet field formalism (which is a formulation more similar to the case of mechanical systems). A statement and proof of Noether`s theorem is also given, using the latter formalism. Finally, some classical examples are briefly studied. (orig.)
On the Classical String Solutions and String/Field Theory Duality
Aleksandrova, D.; Bozhilov, P.
2003-01-01
We classify almost all classical string configurations, considered in the framework of the semi-classical limit of the string/gauge theory duality. Then, we describe a procedure for obtaining the conserved quantities and the exact classical string solutions in general string theory backgrounds, when the string embedding coordinates depend non-linearly on the worldsheet time parameter.
Semi-classical theory of quiet lasers. I: Principles
Arnaud, J; Philippe, F; Arnaud, Jacques; Chusseau, Laurent; Philippe, Fabrice
2006-01-01
When light originating from a laser diode driven by non-fluctuating electrical currents is incident on a photo-detector, the photo-current does not fluctuate much. Precisely, this means that the variance of the number of photo-electrons counted over a large time interval is much smaller that the average number of photo-electrons. At non-zero Fourier frequency $\\Omega$ the photo-current power spectrum is of the form $\\Omega^2/(1+\\Omega^2)$ and thus vanishes as $\\Omega\\to 0$, a conclusion equivalent to the one given above. The purpose of this paper is to show that results such as the one just cited may be derived from a (semi-classical) theory in which neither the optical field nor the electron wave-function are quantized. We first observe that almost any medium may be described by a circuit and distinguish (possibly non-linear) conservative elements such as pure capacitances, and conductances that represent the atom-field coupling. The theory rests on the non-relativistic approximation. Nyquist noise sources (...
A course in mathematical physics 2 classical field theory
Thirring, Walter
1978-01-01
In the past decade the language and methods ofmodern differential geometry have been increasingly used in theoretical physics. What seemed extravagant when this book first appeared 12 years ago, as lecture notes, is now a commonplace. This fact has strengthened my belief that today students of theoretical physics have to learn that language-and the sooner the better. Afterall, they willbe the professors ofthe twenty-first century and it would be absurd if they were to teach then the mathematics of the nineteenth century. Thus for this new edition I did not change the mathematical language. Apart from correcting some mistakes I have only added a section on gauge theories. In the last decade it has become evident that these theories describe fundamental interactions, and on the classical level their structure is suffi cientlyclear to qualify them for the minimum amount ofknowledge required by a theoretician. It is with much regret that I had to refrain from in corporating the interesting developments in Kal...
Raykov, Tenko; Marcoulides, George A.
2016-01-01
The frequently neglected and often misunderstood relationship between classical test theory and item response theory is discussed for the unidimensional case with binary measures and no guessing. It is pointed out that popular item response models can be directly obtained from classical test theory-based models by accounting for the discrete…
Effects of shear flow on phase nucleation and crystallization
Mura, Federica; Zaccone, Alessio
2016-04-01
Classical nucleation theory offers a good framework for understanding the common features of new phase formation processes in metastable homogeneous media at rest. However, nucleation processes in liquids are ubiquitously affected by hydrodynamic flow, and there is no satisfactory understanding of whether shear promotes or slows down the nucleation process. We developed a classical nucleation theory for sheared systems starting from the molecular level of the Becker-Doering master kinetic equation and we analytically derived a closed-form expression for the nucleation rate. The theory accounts for the effect of flow-mediated transport of molecules to the nucleus of the new phase, as well as for the mechanical deformation imparted to the nucleus by the flow field. The competition between flow-induced molecular transport, which accelerates nucleation, and flow-induced nucleus straining, which lowers the nucleation rate by increasing the nucleation energy barrier, gives rise to a marked nonmonotonic dependence of the nucleation rate on the shear rate. The theory predicts an optimal shear rate at which the nucleation rate is one order of magnitude larger than in the absence of flow.
Merikanto, Joonas; Duplissy, Jonathan; Määttänen, Anni; Henschel, Henning; Donahue, Neil M.; Brus, David; Schobesberger, Siegfried; Kulmala, Markku; Vehkamäki, Hanna
2016-02-01
We derive a version of Classical Nucleation Theory normalized by quantum chemical results on sulfuric acid-water hydration to describe neutral and ion-induced particle formation in the binary sulfuric acid-water system. The theory is extended to treat the kinetic regime where the nucleation free energy barrier vanishes at high sulfuric acid concentrations or low temperatures. In the kinetic regime particle formation rates become proportional to sulfuric acid concentration to second power in the neutral system or first power in the ion-induced system. We derive simple general expressions for the prefactors in kinetic-type and activation-type particle formation calculations applicable also to more complex systems stabilized by other species. The theory predicts that the binary water-sulfuric acid system can produce strong new particle formation in the free troposphere both through barrier crossing and through kinetic pathways. At cold stratospheric and upper free tropospheric temperatures neutral formation dominates the binary particle formation rates. At midtropospheric temperatures the ion-induced pathway becomes the dominant mechanism. However, even the ion-induced binary mechanism does not produce significant particle formation in warm boundary layer conditions, as it requires temperatures below 0°C to take place at atmospheric concentrations. The theory successfully reproduces the characteristics of measured charged and neutral binary particle formation in CERN CLOUD3 and CLOUD5 experiments, as discussed in a companion paper.
Phase-field modeling of submonolayer growth with the modulated nucleation regime
Dong, X.L.; Xing, H.; Chen, C.L., E-mail: chenchl@nwpu.edu.cn; Wang, J.Y.; Jin, K.X.
2015-10-16
In this letter, we perform the phase-field simulations to investigate nucleation regime of submonolayer growth via a quantified nucleation term. Results show that the nucleation related kinetic coefficients have changed the density of islands and critical sizes to modulate the nucleation regime. The scaling behavior of the island density can be agreed with the classical theory only when effects of modulations have been quantified. We expect to produce the quantitative descriptions of nucleation for submonolayer growth in phase-field models. - Highlights: • The phase-field simulations are systematically compared with the classical nucleation rate theory. • The modulations of nucleation regime by the different kinetic coefficients have been studied. • Appropriate kinetic coefficients contribute to the agreed nucleation regime with the scaling law.
Plimak, L. I.; Ivanov, Misha; Aiello, A.; Stenholm, S.
2015-08-01
Quantum electrodynamics under conditions of distinguishability of interacting matter entities, and of controlled actions and back-actions between them, is considered. Such "mesoscopic quantum electrodynamics" is shown to share its dynamical structure with the classical stochastic electrodynamics. In formal terms, we demonstrate that all general relations of the mesoscopic quantum electrodynamics may be recast in a form lacking Planck's constant. Mesoscopic quantum electrodynamics is therefore subject to "doing quantum electrodynamics while thinking classically," allowing one to substitute essentially classical considerations for quantum ones without any loss in generality. Implications of these results for the quantum measurement theory are discussed.
On Classical de Sitter Vacua in String Theory
Wrase, Timm
2010-01-01
We review the prospect of obtaining tree-level de Sitter (dS) vacua and slow-roll inflation models in string compactifications. Restricting ourselves to the closed string sector and assuming the absence of NSNS-sources, we classify the minimal classical ingredients that evade the simplest no-go theorems against dS vacua and inflation. Spaces with negative integrated curvature together with certain combinations of low-dimensional orientifold planes and low-rank RR-fluxes emerge as the most promising setups of this analysis. We focus on two well-controlled classes that lead to an effective 4D, N=1 supergravity description: Type IIA theory on group or coset manifolds with SU(3)-structure and O6-planes, as well as type IIB compactifications on SU(2)-structure manifolds with O5- and O7-planes. While fully stabilized AdS vacua are generically possible, a number of problems encountered in the search for dS vacua are discussed.
On covariant Poisson brackets in classical field theory
Forger, Michael [Instituto de Matemática e Estatística, Universidade de São Paulo, Caixa Postal 66281, BR–05315-970 São Paulo, SP (Brazil); Salles, Mário O. [Instituto de Matemática e Estatística, Universidade de São Paulo, Caixa Postal 66281, BR–05315-970 São Paulo, SP (Brazil); Centro de Ciências Exatas e da Terra, Universidade Federal do Rio Grande do Norte, Campus Universitário – Lagoa Nova, BR–59078-970 Natal, RN (Brazil)
2015-10-15
How to give a natural geometric definition of a covariant Poisson bracket in classical field theory has for a long time been an open problem—as testified by the extensive literature on “multisymplectic Poisson brackets,” together with the fact that all these proposals suffer from serious defects. On the other hand, the functional approach does provide a good candidate which has come to be known as the Peierls–De Witt bracket and whose construction in a geometrical setting is now well understood. Here, we show how the basic “multisymplectic Poisson bracket” already proposed in the 1970s can be derived from the Peierls–De Witt bracket, applied to a special class of functionals. This relation allows to trace back most (if not all) of the problems encountered in the past to ambiguities (the relation between differential forms on multiphase space and the functionals they define is not one-to-one) and also to the fact that this class of functionals does not form a Poisson subalgebra.
On covariant Poisson brackets in classical field theory
How to give a natural geometric definition of a covariant Poisson bracket in classical field theory has for a long time been an open problem—as testified by the extensive literature on “multisymplectic Poisson brackets,” together with the fact that all these proposals suffer from serious defects. On the other hand, the functional approach does provide a good candidate which has come to be known as the Peierls–De Witt bracket and whose construction in a geometrical setting is now well understood. Here, we show how the basic “multisymplectic Poisson bracket” already proposed in the 1970s can be derived from the Peierls–De Witt bracket, applied to a special class of functionals. This relation allows to trace back most (if not all) of the problems encountered in the past to ambiguities (the relation between differential forms on multiphase space and the functionals they define is not one-to-one) and also to the fact that this class of functionals does not form a Poisson subalgebra
On covariant Poisson brackets in classical field theory
Forger, Michael; Salles, Mário O.
2015-10-01
How to give a natural geometric definition of a covariant Poisson bracket in classical field theory has for a long time been an open problem—as testified by the extensive literature on "multisymplectic Poisson brackets," together with the fact that all these proposals suffer from serious defects. On the other hand, the functional approach does provide a good candidate which has come to be known as the Peierls-De Witt bracket and whose construction in a geometrical setting is now well understood. Here, we show how the basic "multisymplectic Poisson bracket" already proposed in the 1970s can be derived from the Peierls-De Witt bracket, applied to a special class of functionals. This relation allows to trace back most (if not all) of the problems encountered in the past to ambiguities (the relation between differential forms on multiphase space and the functionals they define is not one-to-one) and also to the fact that this class of functionals does not form a Poisson subalgebra.
Rayleigh Scattering Density Measurements, Cluster Theory, and Nucleation Calculations at Mach 10
Balla, R. Jeffrey; Everhart, Joel L.
2012-01-01
In an exploratory investigation, quantitative unclustered laser Rayleigh scattering measurements of density were performed in the air in the NASA Langley Research Center's 31 in. Mach 10 wind tunnel. A review of 20 previous years of data in supersonic and Mach 6 hypersonic flows is presented where clustered signals typically overwhelmed molecular signals. A review of nucleation theory and accompanying nucleation calculations are also provided to interpret the current observed lack of clustering. Data were acquired at a fixed stagnation temperature near 990Kat five stagnation pressures spanning 2.41 to 10.0 MPa (350 to 1454 psi) using a pulsed argon fluoride excimer laser and double-intensified charge-coupled device camera. Data averaged over 371 images and 210 pixels along a 36.7mmline measured freestream densities that agree with computed isentropic-expansion densities to less than 2% and less than 6% at the highest and lowest densities, respectively. Cluster-free Mach 10 results are compared with previous clustered Mach 6 and condensation-free Mach 14 results. Evidence is presented indicating vibrationally excited oxygen and nitrogen molecules are absorbed as the clusters form, release their excess energy, and inhibit or possibly reverse the clustering process. Implications for delaying clustering and condensation onset in hypersonic and hypervelocity facilities are discussed.
Qian, Xiao-Feng; Howell, John C; Eberly, J H
2015-01-01
The growing recognition that entanglement is not exclusively a quantum property, and does not even originate with Schr\\"odinger's famous remark about it [Proc. Camb. Phil. Soc. {\\bf 31}, 555 (1935)], prompts examination of its role in marking the quantum-classical boundary. We have done this by subjecting correlations of classical optical fields to new Bell-analysis experiments, and report here values of the Bell parameter greater than ${\\cal B} = 2.54$. This is many standard deviations outside the limit ${\\cal B} = 2$ established by the Clauser-Horne-Shimony-Holt (CHSH) Bell inequality [Phys. Rev. Lett. {\\bf 23}, 880 (1969)], in agreement with our theoretical classical prediction, and not far from the Tsirelson limit ${\\cal B} = 2.828...$. These results cast a new light on the standard quantum-classical boundary description, and suggest a reinterpretation of it.
The reinterpretation of the BRS equations of Quantum Field Theory as the Maurer Cartan equation of a classical principal fiber bundle leads to a simple gauge invariant classification of the anomalies in Yang Mills theory and gravity
In this paper, a detailed numerical comparison of the high-harmonic generation (HHG) from free electrons in intense laser fields in both classical and semi-classical frameworks has been presented. These two frameworks have been widely used in the literature. It has been found that the HHG spectra display distinct quantitative differences for high-energy electrons. In some special situations, qualitative differences appear. Even if the radiation reaction is included in the electron classical dynamics, no consistent result can be obtained. Hence it should be of critical importance to submit the present HHG theory for high-precision experimental tests, which can help us not only to justify the present theories, but also to check the QED predictions in the high-intensity regime. (paper)
Restrictions imposed on relativistic two-body interactions by classical relativistic field theory
We show that various relativistic potential models (all sharing exact relativistic two-body kinematics and a common nonrelativistic limit) can be distinguished by agreement or disagreement with relativistic corrections produced by classical field theory. We find that the only one of these models whose relativisic corrections duplicate those of classical field theory is the minimal Todorov equation. Conversely, we derive the Todorov equation from the semirelativistic dynamics of classical field theory, thus exposing the classical field-theoretic origins of its characteristic minimal potential structures and dependences on effective one-body variables
A reappraisal of classical archetype theory and its implications for theory and practice.
Merchant, John
2009-06-01
This paper begins with an overview of contemporary approaches to archetype theory and notes the radical nature of certain deductions. Some argue that there is no 'archetype-as-such' as a pre-existing entity at the core of a complex driving its formation whilst the findings of current neuroscience are calling into question one very thing on which the classical theory is built--innatism. Knox's argument for image schemas raises the question as to the extent to which archetypes can be conceived in any preformationist sense. The question is then posed--to what extent can Jung's classical theory of archetypes be read in light of these current models? The case examples Jung uses to evidence the existence of archetypes, his explications of synchronicity and his own Philemon experience are then reappraised. The conclusion is drawn that it is difficult to evidence the existence of autonomous archetypes unrelated to personal affective experience. Not only would this be expected by emergent/developmental models of archetype but it can explain many of Jung's disjunctive statements about archetype constellation; the difficulties in separating personal and collective psychic content and Jung's apparent Lamarckianism. The implications of these models for theory, clinical practice and analyst training are then offered for discussion. PMID:19531124
Traffic breakdown at a signal: classical theory versus the three-phase theory of city traffic
Physical reasons for a crucial difference between the results of a three-phase theory developed recently (Kerner 2011 Phys. Rev. E 84 045102(R); 2013 Europhys. Lett. 102 28010; 2014 Physica A 397 76) and the classical theory are explained. Microscopic characteristics of traffic passing a traffic signal during the green signal phase and their dependence on the duration of the green phase have been found. It turns out that a moving synchronized flow pattern (MSP), which occurs in under-saturated traffic at the signal, causes ‘compression’ of traffic flow: the rate of MSP discharge can be considerably larger than the saturation flow rate of the classical traffic theory of city traffic. This leads to a considerably larger rate of traffic passing the signal in comparison with the saturation flow rate. This effect together with traffic behavior at the upstream queue front explains the metastability of under-saturated traffic with respect to a random time-delayed traffic breakdown. (paper)
Traffic breakdown at a signal: classical theory versus the three-phase theory of city traffic
Kerner, Boris S.; Klenov, Sergey L.; Schreckenberg, Michael
2014-03-01
Physical reasons for a crucial difference between the results of a three-phase theory developed recently (Kerner 2011 Phys. Rev. E 84 045102(R); 2013 Europhys. Lett. 102 28010; 2014 Physica A 397 76) and the classical theory are explained. Microscopic characteristics of traffic passing a traffic signal during the green signal phase and their dependence on the duration of the green phase have been found. It turns out that a moving synchronized flow pattern (MSP), which occurs in under-saturated traffic at the signal, causes ‘compression’ of traffic flow: the rate of MSP discharge can be considerably larger than the saturation flow rate of the classical traffic theory of city traffic. This leads to a considerably larger rate of traffic passing the signal in comparison with the saturation flow rate. This effect together with traffic behavior at the upstream queue front explains the metastability of under-saturated traffic with respect to a random time-delayed traffic breakdown.
Binary nucleation beyond capillarity approximation
Kalikmanov, V.I.
2010-01-01
Large discrepancies between binary classical nucleation theory (BCNT) and experiments result from adsorption effects and inability of BCNT, based on the phenomenological capillarity approximation, to treat small clusters. We propose a model aimed at eliminating both of these deficiencies. Adsorption is taken into account within Gibbsian approximation. Binary clusters are treated by means of statistical-mechanical considerations: tracing out the molecular degrees of freedom of the more volatil...
Classical irregular block, N=2 pure gauge theory and Mathieu equation
Piatek, Marcin
2014-01-01
Combining the semiclassical/Nekrasov-Shatashvili limit of the AGT conjecture and the Bethe/gauge correspondence results in a triple correspondence which identifies classical conformal blocks with twisted superpotentials and then with Yang-Yang functions. In this paper the triple correspondence is studied in the simplest, yet not completely understood case of pure SU(2) super-Yang-Mills gauge theory. A missing element of that correspondence is identified with the classical irregular block. Explicit tests provide a convincing evidence that such a function exists. In particular, it has been shown that the classical irregular block can be recovered from classical blocks on the torus and sphere in suitably defined decoupling limits of classical external conformal weights. These limits are "classical analogues" of known decoupling limits for corresponding quantum blocks. An exact correspondence between the classical irregular block and the SU(2) gauge theory twisted superpotential has been obtained as a result of a...
A critical experimental study of the classical tactile threshold theory
Medina Leonel E
2010-06-01
Full Text Available Abstract Background The tactile sense is being used in a variety of applications involving tactile human-machine interfaces. In a significant number of publications the classical threshold concept plays a central role in modelling and explaining psychophysical experimental results such as in stochastic resonance (SR phenomena. In SR, noise enhances detection of sub-threshold stimuli and the phenomenon is explained stating that the required amplitude to exceed the sensory threshold barrier can be reached by adding noise to a sub-threshold stimulus. We designed an experiment to test the validity of the classical vibrotactile threshold. Using a second choice experiment, we show that individuals can order sensorial events below the level known as the classical threshold. If the observer's sensorial system is not activated by stimuli below the threshold, then a second choice could not be above the chance level. Nevertheless, our experimental results are above that chance level contradicting the definition of the classical tactile threshold. Results We performed a three alternative forced choice detection experiment on 6 subjects asking them first and second choices. In each trial, only one of the intervals contained a stimulus and the others contained only noise. According to the classical threshold assumptions, a correct second choice response corresponds to a guess attempt with a statistical frequency of 50%. Results show an average of 67.35% (STD = 1.41% for the second choice response that is not explained by the classical threshold definition. Additionally, for low stimulus amplitudes, second choice correct detection is above chance level for any detectability level. Conclusions Using a second choice experiment, we show that individuals can order sensorial events below the level known as a classical threshold. If the observer's sensorial system is not activated by stimuli below the threshold, then a second choice could not be above the chance
On the concept of Bell’s local causality in local classical and quantum theory
The aim of this paper is to implement Bell’s notion of local causality into a framework, called local physical theory. This framework, based on the axioms of algebraic field theory, is broad enough to integrate both probabilistic and spatiotemporal concepts and also classical and quantum theories. Bell’s original idea of local causality will arise as the classical case of our definition. Classifying local physical theories by whether they obey local primitive causality, a property rendering the dynamics of the theory causal, we then investigate what is needed for a local physical theory to be locally causal. Finally, comparing local causality with the common cause principles and relating both to the Bell inequalities we find a nice parallelism: Bell inequalities cannot be derived neither from local causality nor from a common cause unless the local physical theory is classical or the common cause is commuting, respectively
Liquid Nucleation at Superheated Grain Boundaries
Frolov, T.; Mishin, Y.
2011-04-01
Grain boundaries with relatively low energies can be superheated above the melting temperature and eventually melt by heterogeneous nucleation of liquid droplets. We propose a thermodynamic model of this process based on the sharp-interface approximation with a disjoining potential. The distinct feature of the model is its ability to predict the shape and size of the critical nucleus by using a variational approach. The model reduces to the classical nucleation theory in the limit of large nuclei but is more general and remains valid for small nuclei. Contrary to the classical nucleation theory, the model predicts the existence of a critical temperature of superheating and offers a simple formula for its calculation. The model is tested against molecular dynamic simulations in which liquid nuclei at a superheated boundary were obtained by an adiabatic trapping procedure. The simulation results demonstrate a reassuring consistency with the model.
Quantization, Classical and Quantum Field Theory and Theta - Functions
Tyurin, Andrey N.
2002-01-01
In the abelian case (the subject of several beautiful books) fixing some combinatorial structure (so called theta structure of level k) one obtains a special basis in the space of sections of canonical polarization powers over the jacobians. These sections can be presented as holomorphic functions on the "abelian Schottky space". This fact provides various applications of these concrete analytic formulas to the integrable systems, classical mechanics and PDE's. Our practical goal is to do the...
On inert properties of particles in classical theory
Kosyakov, B. P.
2002-01-01
This is a critical review of inert properties of classical relativistic point objects. The objects are classified as Galilean and non-Galilean. Three types of non-Galilean objects are considered: spinning, rigid, and dressed particles. In the absence of external forces, such particles are capable of executing not only uniform motions along straight lines but also Zitterbewegungs, self-accelerations, self-decelerations, and uniformly accelerated motions. A free non-Galilean object possesses th...
Antigravity and classical solutions of five-dimensional Kaluza-Klein theory
Pollard, D. (Imperial Coll. of Science and Technology, London (UK). Blackett Lab.)
1983-02-21
Classical solutions are exhibited of a graviton-graviphoton-graviscalar field theory which are antigravitating in the weak-field approximation. The theory itself is obtained by a Kaluza-Klein type reduction from five to four dimensions. The solutions are dyonic black holes with scalar charge. They share some similarities with the extreme Reissner-Nordstrom black holes of Einstein-Maxwell theory.
Hyperdense coding and superadditivity of classical capacities in hypersphere theories
Massar, Serge; Pironio, Stefano; Pitalúa-García, Damián
2015-01-01
In quantum superdense coding, two parties previously sharing entanglement can communicate a two bit message by sending a single qubit. We study this feature in the broader framework of general probabilistic theories. We consider a particular class of theories in which the local state space of the communicating parties corresponds to Euclidean hyperballs of dimension n (the case n = 3 corresponds to the Bloch ball of quantum theory). We show that a single n-ball can encode at most one bit of i...
Lange, Elizabeth
2015-01-01
This article argues that sociology has been a foundational discipline for the field of adult education, but it has been largely implicit, until recently. This article contextualizes classical theories of sociology within contemporary critiques, reviews the historical roots of sociology and then briefly introduces the classical theories…
Quantum Electrodynamics Basis of Classical-Field High-Harmonic Generation Theory
王兵兵; 高靓辉; 傅盘铭; 郭东升; R. R. Freeman
2001-01-01
From the nonperturbative quantum electrodynamics theory, we derive the Landau-Dykhne formula which represents the quantum-mechanical formulation of the three-step model. These studies provide a basis for the classical-field approaches to high-order harmonic generation and justify some assumptions used in classical-field modelling.
The Poisson algebra of classical Hamiltonians in field theory and the problem of its quantization
Stoyanovsky, A.
2010-01-01
We construct the commutative Poisson algebra of classical Hamiltonians in field theory. We pose the problem of quantization of this Poisson algebra. We also make some interesting computations in the known quadratic part of the quantum algebra.
A2: Mathematical relativity and other progress in classical gravity theory - a session report
Chruściel, Piotr T.; Paetz, Tim-Torben
2013-01-01
We report on selected oral contributions to the A2 session "Mathematical relativity and other progress in classical gravity theory" of "The 20th International Conference on General Relativity and Gravitation (GR20)" in Warsaw.
Classical Belief Conditioning and its Generalization to DSm Theory
Daniel, Milan
2008-01-01
Roč. 2, č. 4 (2008), s. 267-279. ISSN 1752-8917 R&D Projects: GA AV ČR 1ET100300419 Institutional research plan: CEZ:AV0Z10300504 Keywords : belief functions * Dempster-Shafer theory * belief conditioning * DSm theory * overlapping elements * hyper-power set * DSm model Subject RIV: BA - General Mathematics http://www.worldacademicunion.com/journal/jus/jusVol02No4paper04.pdf
Fu Dong; Liao Tao
2007-01-01
The excess Helmholtz free energy functional for nonpolar chain-like molecules is formulated in terms of a weighted density approximation (WDA) for short-range interactions and a Weaks-Chandler-Andersen (WCA) approximation and a Barker-Henderson (BH) theory for long-range attraction. Within the framework of density functional theory (DFT), vapour-liquid interfacial properties including density profile and surface tension, and vapour-liquid nucleation properties including density profile, work of formation and number of particles are investigated for spherical and chainlike molecules. The obtained vapour-liquid surface tension and the number of particles in critical nucleus for LennardJones (L J) fluids are consistent with the simulation results. The influences of supersaturation, temperature and chain length on vapour-liquid nucleation properties are discussed.
On one classical problem in the radial orbit instability theory
Polyachenko, E. V.; Shukhman, I. G.
2016-02-01
Antonov's classical problem of stability of a collisionless sphere with a purely radial motion of stars is considered as a limit of the problem in which stars move in nearly radial orbits. We provide the proper limiting equations that take into account the singularity in the density distribution at the sphere center and give their solutions. We show that there is instability for even and odd spherical harmonics, with all unstable modes being not slow. The growth rates of aperiodic even modes increase indefinitely when approaching purely radial models. The physics of the radial orbit instability is discussed.
Scattering theory for the quantum envelope of a classical system
Classical dynamics, reformulated in terms of its quantum envelope is studied for the stationary states of the interacting system. The dynamical variable of ''elapsed time'' plays a crucial role in this study. It is shown that the perturbation series for the elapsed time can be summed in various simple cases even when standard perturbation series diverge. For the special class of systems where the interactions fall off sufficiently fast at infinity one could define ''in'' and ''out'' states; and consequently the wave matrices and scattering matrices. The scattering phase shifts bear a simple relation to the time delay in scattering
Classical optics in generalized Maxwell Chern-Simons theory
The authors consider the propagation of electromagnetic waves in a two-dimensional polarizable medium endowed with Chern-Simons terms. The dispersion relation (refractive index) of the waves is computed and the existence of linear birefringence and anomalous dispersion is shown. When absorption is taken into account, the classic signature of a Voigt effect is found. In the case where linearly-polarized, three-dimensional waves pass through a two-dimensional plane, it is shown that there is optical activity, and the analogue of Verdet's constant is computed. 19 refs., 2 figs
On inert properties of particles in classical theory
Kosyakov, B P
2002-01-01
This is a critical review of inert properties of classical relativistic point objects. The objects are classified as Galilean and non-Galilean. Three types of non-Galilean objects are considered: spinning, rigid, and dressed particles. In the absence of external forces, such particles are capable of executing not only uniform motions along straight lines but also Zitterbewegungs, self-accelerations, self-decelerations, and uniformly accelerated motions. A free non-Galilean object possesses the four-velocity and the four-momentum which are in general not collinear, therefore, its inert properties are specified by two, rather than one, invariant quantities. It is shown that a spinning particle need not be a non-Galilean object. The necessity of a rigid mechanics for the construction of a consistent classical electrodynamics in spacetimes of dimension D+1 is justified for D+1>4. The problem of how much the form of fundamental laws of physics orders four dimensions of our world is revised together with its soluti...
A course in mathematical physics 1 and 2 classical dynamical systems and classical field theory
Thirring, Walter
1992-01-01
The last decade has seen a considerable renaissance in the realm of classical dynamical systems, and many things that may have appeared mathematically overly sophisticated at the time of the first appearance of this textbook have since become the everyday tools of working physicists. This new edition is intended to take this development into account. I have also tried to make the book more readable and to eradicate errors. Since the first edition already contained plenty of material for a one semester course, new material was added only when some of the original could be dropped or simplified. Even so, it was necessary to expand the chap ter with the proof of the K-A-M Theorem to make allowances for the cur rent trend in physics. This involved not only the use of more refined mathe matical tools, but also a reevaluation of the word "fundamental. " What was earlier dismissed as a grubby calculation is now seen as the consequence of a deep principle. Even Kepler's laws, which determine the radii of the ...
New views on classical and quantum Brans-Dicke theory
Fabris, Júlio C; Rodrigues, Davi C; Almeida, Carla R; Piattella, Oliver F
2016-01-01
The Brans-Dicke action is one of the most natural extensions of the Einstein-Hilbert action. It is based on the introduction of a fundamental scalar field that effectively incorporates a dynamics to the gravitational coupling $G$. In spite of the diverse motivations and the rich phenomenology that comes from its solutions, Solar System tests impose strong constraints on the Brans-Dicke theory, rendering it indistinguishable from General Relativity. In the present text, new perspectives for the Brans-Dicke theory are presented, based on the possibility that the scalar field presented in the BD theory can be external, as well as on the applications to black hole physics and the primordial universe.
Quantization of light energy directly from classical electromagnetic theory in vacuum
She Wei-Long
2005-01-01
It is currently believed that light quantum or the quantization of light energy is beyond classical physics, and the picture of wave-particle duality, which was criticized by Einstein but has attracted a number of experimental researches, is necessary for the description of light. It is shown in this paper, however, that the quantization of light energy in vacuum, which is the same as that in quantum electrodynamics, can be derived directly from the classical electromagnetic theory through the consideration of statistics based on classical physics. Therefore, the quantization of energy is an intrinsic property of light as a classical electromagnetic wave and has no need of being related to particles.
3D gravity with dust: classical and quantum theory
Husain, Viqar
2015-01-01
We study the Einstein gravity and dust system in three spacetime dimensions as an example of a non-perturbative quantum gravity model with local degrees of freedom. We derive the Hamiltonian theory in the dust time gauge and show that it has a rich class of exact solutions. These include the Ba\\~nados-Teitelboim-Zanelli black hole, static solutions with naked singularities and travelling wave solutions with dynamical horizons. We give a complete quantization of the wave sector of the theory, including a definition of a self-adjoint spacetime metric operator. This operator is used to demonstrate the quantization of deficit angle and the fluctuation of dynamical horizons.
Classical Belief Conditioning and its Generalization to DSm Theory
Daniel, Milan
San Luis Obispo : California Polytechnic State University, 2007 - (Lee, T.; Liu, Y.; Zhao, X.), s. 596-603 ISSN 1539-2023. - (Series of Information & Management Sciences. 6). [International Conference on Information and Management Sciences /6./. Lhasa (CN), 01.06.2007-06.06.2007] R&D Projects: GA AV ČR 1ET100300419 Institutional research plan: CEZ:AV0Z10300504 Keywords : belief functions * Dempster-Shafer theory * belief conditioning * DSm theory * overlapping elements * hyper-power set * DSm model Subject RIV: BA - General Mathematics
Topics in the theory of quantum and classical networks
Almaas, Eivind
We study both quantum and classical networks. The quantum networks consist of 1D and 2D arrays of Josephson junctions coupled to a resonant cavity. We derive dynamical equations for these arrays by applying the Heisenberg equations of motion to a model Hamiltonian. By means of a canonical transformation, we also show that, in the absence of an applied current and dissipation, our model reduces to one used to describe coupled qubits, and that the cavity-junction coupling corresponds to a capacitive coupling between the array and the cavity mode. From extensive numerical solutions of the model in both 1D and 2D, we find that the array locks into a coherent, periodic state above a critical number of active junctions, that the current-voltage characteristics of the array have self-induced resonant steps (SIRS's), that when N a active junctions are synchronized on a SIRS, the energy emitted into the resonant cavity is quadratic in Na, and that when a fixed number of junctions is biased on a SIRS, the energy is linear in the input power. All these results are in agreement with recent experiments. We conclude that most of the experimental data can be understood from classical equations of motion. Our study of classical networks is divided into two parts. In the first, we study the structural properties of 'small-world' networks (SWN)---networks that display properties of both regular and random graphs. We generalize the model for generating such networks that was first introduced by Watts and Strogatz. For this model, we study the distribution function for minimal paths, derive its general form and also discuss its scaling properties. Using this distribution function, we derive exact expressions for several network properties, like the average minimal distance, ℓ¯ and its variance, sigma2. These exact relations are independent of the 'degree distribution', i.e. the distribution of nearest-neighbor connections. In the second, we study how the structure of the network
k-Cosymplectic Classical Field Theories: Tulczyjew and Skinner–Rusk Formulations
The k-cosymplectic Lagrangian and Hamiltonian formalisms of first-order classical field theories are reviewed and completed. In particular, they are stated for singular and almost-regular systems. Subsequently, several alternative formulations for k-cosymplectic first-order field theories are developed: First, generalizing the construction of Tulczyjew for mechanics, we give a new interpretation of the classical field equations. Second, the Lagrangian and Hamiltonian formalisms are unified by giving an extension of the Skinner–Rusk formulation on classical mechanics.
Haataja, Mikko; Gránásy, László; Löwen, Hartmut
2010-08-01
, about a half of which are related to the theoretical materials science community and the other half came from the soft-matter community. We begin by discussing papers related to PFC. Diverse subjects related to the phase-field crystal model include exciting topics such as predicting/controlling the equilibrium phase behavior [19, 18, 17] and kinetics of epitaxial island formation on nano-membranes [20]. Moreover, phase-field crystal modeling has proved to be very successful in simulating homogeneous and heterogeneous crystal nucleation and growth, and several aspects of these phenomena are discussed in this issue [18, 21]. Finally, it is shown how to incorporate additional orientational degrees of freedom within the PFC approach to model liquid crystals [22]. On the DFT side, the other papers in this special issue deal with problems associated with advanced DFT techniques and applications. The existence of a structural instability in sub-critical crystalline fluctuations in a supercooled liquid within a square-gradient theory is discussed in [23]. Fundamental measure theory for hard-body systems is improved by discussing a correction term in detail, as discussed in [24]. A mean-field-like density functional for charges is applied to the effective interaction between charged colloids obtained within a cell model [25]. The remaining articles provide fundamental insight into how to supplement DDFT-type methods with hydrodynamics [26, 27], highlight the role of the projection operator technique in deriving dynamical density functional theories [28], and demonstrate how perturbation methods can be employed to compute the properties of solid-liquid interfaces [29]. This particular collection of papers demonstrates rather convincingly the significant potential that classical density functional techniques possess in modeling complex systems built of either soft or hard matter (or combinations thereof). While the PFC approach offers a simple and appealing means to simulate
Foundations of the classical theory of partial differential equations
Egorov, Yu V
1998-01-01
From the reviews of the first printing, published as volume 30 of the Encyclopaedia of Mathematical Sciences: "... I think the volume is a great success and an excellent preparation for future volumes in the series. ... the introductory style of Egorov and Shubin is .. attractive. ... a welcome addition to the literature and I am looking forward to the appearance of more volumes of the Encyclopedia in the near future. ..." The Mathematical Intelligencer, 1993 "... According to the authors ... the work was written for nonspecialists and physicists but in my opinion almost every specialist will find something new ... in the text. The style is clear, the notations are chosen luckily. The most characteristic feature of the work is the accurate emphasis on the fundamental notions ..." Acta Scientiarum Mathematicarum, 1993 "... On the whole, a thorough overview on the classical aspects of the topic may be gained from that volume." Monatshefte für Mathematik, 1993 "... It is comparable in scope with the great Coura...
Classical theory of thermal radiation from a solid.
Guo, Wei
2016-06-01
In this work, a solid at a finite temperature is modeled as an ensemble of identical atoms, each of which moves around a lattice site inside an isotropic harmonic potential. The motion of one such atom is studied first. It is found that the atom moves like a time-dependent current density and, thus, can emit electromagnetic radiation. Since all the atoms are identical, they can radiate, too. The resultant radiation from the atoms is the familiar thermal radiation from the solid. After its general expression is obtained, the intensity of the thermal radiation is discussed for its properties, and specifically calculated in the low-temperature limit. Both atomic motion and radiation are formulated in the classical domain. PMID:27409442
Classical instanton and wormhole solutions of Type IIB string theory
Kim, Jin Young; Lee, H. W.; Myung, Y. S.
1996-01-01
We study $p=-1$ D-brane in type IIB superstring theory. In addition to RR instanton, we obtain the RR charged wormhole solution in the Einstein frame. This corresponds to the ten-dimensional singular wormhole solution with infinite euclidean action.
Collaboration in classical political economy and noncooperative game theory.
McCain, Roger A
2014-06-01
This commentary suggests (1) that there are precedents for Smaldino's "collaboration" in the history of economic thought before 1900 and (2) that the distinction of collaboration from what is thought of as cooperation in game theory is less clear than Smaldino suggests. PMID:24970411
Regulating photon mass in classical 5D gauge theory
Full Text:Off-shell electrodynamics, the local gauge theory associated with a covariant symplectic mechanics developed by Stueckelberg, describes instantaneous interactions between spacetime events, mediated by five massive gauge fields. Event evolution in this formalism is parameterized by an independent, monotonically increasing, Poincare-invariant parameter, and not by the proper time of the motion, and so one is led to a dynamical theory in which mass conservation is demoted from the status of an a priori constraint to that of a Noether current conserved for a certain class or interactions. While the total mass-energy of particles and fields is conserved, particles and photons may, in general, exchange mass. In the equilibrium limit, photons are pushed onto the Maxwell zero-mass shell, but during interaction, photons may acquire any mass, even pushing particle trajectories far into the spacelike region. We discuss a higher derivative correction to the photon kinetic term, which regulates the photon mass while preserving gauge invariance and Poincare covariance of the original theory. We discuss an information-theoretic interpretation of this mechanism, and demonstrate that the resulting quantum field theory is made super-renormalizable
Fradera, Jorge; Cuesta-López, Santiago
2013-01-01
Helium (He) nucleation in liquid metal breeding blankets of a DT fusion reactor may have a significant impact regarding system design, safety and operation. Large He production rates are expected due to tritium (T) fuel self-sufficiency requirement, as both, He and T, are produced at the same rate. Low He solubility, local high concentrations, radiation damage and fluid discontinuities, among other phenomena, may yield the necessary conditions for He nucleation. Hence, He nucleation may have ...
Universality principle and the development of classical density functional theory
周世琦; 张晓琪
2002-01-01
The universality principle of the free energy density functional and the ‘test particle' trick by Percus are combined to construct the approximate free energy density functional or its functional derivative. Information about the bulk fluid ralial distribution function is integrated into the density functional approximation directly for the first time in the present methodology. The physical foundation of the present methodology also applies to the quantum density functional theory.
Effect of oxygen partial pressure on the nucleation kinetics of orthorhombic YBCO
Effect of oxygen partial pressure on the nucleation kinetics of orthorhombic YBCO from tetragonal phase has been studied using classical nucleation theory. The free energy of formation of orthorhombic YBCO has been evaluated as a function of oxygen partial pressure. (Abstract Copyright [2002], Wiley Periodicals, Inc.)
Opportunizing: A classic grounded theory study on business and management
Ólavur Christiansen
2006-11-01
Full Text Available Opportunizing emerged as the core variable of this classic GT study on business and management. Opportunizing is the recurrent main concern that businesses have to continually resolve, and it explains how companies recurrently create, identify, seize or exploit situations to maintain their growth or survival. Opportunizing is the recurrent creation and re-creation of opportunities in business. Opportunizing is basically what business managers do and do all the time. The problematic nature of opportunizing is resolved by a core social process ofopportunizing and its attached sub-processes that account for change over time and for the variations of the problematic nature of its resolution.Opportunizing has five main facets. These are conditional befriending (confidence building & modifying behavior,prospecting (e.g. information gaining, weighing up (information appraisal & decision-making, moment capturing (quick intervention for seizing strategic opportunities, andconfiguration matching (adjusting the business organization to abet the other activities of opportunizing.On a more abstract level, opportunizing has three more organizational facets: the physically boundary-less, the valuehierarchical, and the physically bounded. The first of these called perpetual opportunizing. This emerges from the conjunction of conditional befriending and prospecting. The second facet is called triggering opportunizing. It arises from the coming together of weighing up and moment capturing. The final facet is called spasmodic opportunizing. This happens when moment capturing and configuration matching unite.
Semi-classical theory of fluctuations in nuclear matter
At intermediate energies the heavy ion collisions can be studied within the framework of a semi-classical approach based on the Vlasov-Uehling-Uhlenbeck (VUU) equation. Such an approach reduces the N-body problem to its description in terms of the one-body distribution function and constitutes the basis of several successful simulation models. Our aim in this work is to extend these average approaches to treat fluctuations. Within the framework of a linear approximation, we derived a Fokker-Planck transport equation in the one-body phase space. When it is reduced to its first moments, one recovers the VUU equation for the average dynamics together with the time evolution equation for the correlations. The collective transport coefficients are then obtained by projection on the one-body collective space. Independently, using a projection method introduced by Van Kampen, based on the constants of motion, we deduce the stationary expressions for the covariance matrix in phase space. We extract then, the equilibrium dispersions of one-body observables in a homogeneous case and in a spherical symmetric one. These results are compared with two types of simulation models in a relaxation time approximation. In the first one which is of Lagrangian type, the collective transport coefficients are directly extracted from the simulation and consequently the numerical fluctuations are washed out. The second model, due to its Eulerian character, allows us to make a microscopical comparison. (author)
Reese, Lynda M.
This study extended prior Law School Admission Council (LSAC) research related to the item response theory (IRT) local item independence assumption into the realm of classical test theory. Initially, results from the Law School Admission Test (LSAT) and two other tests were investigated to determine the approximate state of local item independence…
A modification of Amiet's classical trailing edge noise theory for strictly two dimensional flows
Sandberg, Richard D.; Sandham, Neil D.
2007-01-01
The aim of this report is to derive theoretical expressions for the far-field pressure generated by disturbances convecting over a trailing edge. First, a general calculation of the far-field pressure is discussed. Then the classical theory of Amiet (1976b) is reviewed, listing the most relevant assumptions. Amiet's theory is then revised for two-dimensional flows.
Matrix Analogues to Some Classical Problems in Number Theory
Niwa, Masahiko
1996-01-01
The aim of this paper is to give a few results on some problems in the matrix ring Mn(R) over a commutative ring R analogous to some classical problems in number theory, which are handled in L. N. Vaserstein[4]. As for Matrix Goldbach Problem we can easily give an affirmative solution in Mn(R)(any n≧2), contrary to the difficulty of the original conjecture. As for Matrix Fermat Problem we will explain the connection of this problem with elements of finite order of the group GLn(R) of uni...
Perturbative quantization of Yang-Mills theory with classical double as gauge algebra
Perturbative quantization of Yang-Mills theory with a gauge algebra given by the classical double of a semisimple Lie algebra is considered. The classical double of a real Lie algebra is a nonsemisimple real Lie algebra that admits a nonpositive definite invariant metric, the indefiniteness of the metric suggesting an apparent lack of unitarity. It is shown that the theory is UV divergent at one loop and that there are no radiative corrections at higher loops. One-loop UV divergences are removed through renormalization of the coupling constant, thus introducing a renormalization scale. The terms in the classical action that would spoil unitarity are proved to be cohomologically trivial with respect to the Slavnov-Taylor operator that controls gauge invariance for the quantum theory. Hence they do not contribute gauge invariant radiative corrections to the quantum effective action and the theory is unitary. (orig.)
Perturbative quantization of Yang-Mills theory with classical double as gauge algebra
Ruiz Ruiz, F.
2016-02-01
Perturbative quantization of Yang-Mills theory with a gauge algebra given by the classical double of a semisimple Lie algebra is considered. The classical double of a real Lie algebra is a nonsemisimple real Lie algebra that admits a nonpositive definite invariant metric, the indefiniteness of the metric suggesting an apparent lack of unitarity. It is shown that the theory is UV divergent at one loop and that there are no radiative corrections at higher loops. One-loop UV divergences are removed through renormalization of the coupling constant, thus introducing a renormalization scale. The terms in the classical action that would spoil unitarity are proved to be cohomologically trivial with respect to the Slavnov-Taylor operator that controls gauge invariance for the quantum theory. Hence they do not contribute gauge invariant radiative corrections to the quantum effective action and the theory is unitary.
Perturbative quantization of Yang-Mills theory with classical double as gauge algebra
Ruiz Ruiz, F. [Universidad Complutense de Madrid, Departamento de Fisica Teorica I, Madrid (Spain)
2016-02-15
Perturbative quantization of Yang-Mills theory with a gauge algebra given by the classical double of a semisimple Lie algebra is considered. The classical double of a real Lie algebra is a nonsemisimple real Lie algebra that admits a nonpositive definite invariant metric, the indefiniteness of the metric suggesting an apparent lack of unitarity. It is shown that the theory is UV divergent at one loop and that there are no radiative corrections at higher loops. One-loop UV divergences are removed through renormalization of the coupling constant, thus introducing a renormalization scale. The terms in the classical action that would spoil unitarity are proved to be cohomologically trivial with respect to the Slavnov-Taylor operator that controls gauge invariance for the quantum theory. Hence they do not contribute gauge invariant radiative corrections to the quantum effective action and the theory is unitary. (orig.)
Ternary nucleation of H2SO4, NH3 and H2O
Kulmala, M.; Korhonen, P.; Laaksonen, A.; Viisanen, Y.; McGraw, R; Seinfeld, J. H.
2000-01-01
A classical theory of the ternary homogeneous nucleation of sulfuric acid—ammonia—water is presented. For NH3 mixing ratios exceeding 1 ppt, the presence of ammonia enhances the binary (sulfuric acid—water) nucleation rate by several orders of magnitude. However, the limiting component for ternary nucleation—as for binary nucleation—is sulfuric acid. The sulfuric acid concentration needed for significant ternary nucleation is several orders of magnitude below that required in binary case....
Modelling microscopic clusters of sulphuric acid and water relevant to atmospheric nucleation
Stinson, J
2015-01-01
Classical nucleation theory has been a useful tool for predicting the phenomena of nucleation for the past seventy years. However the model has several limitations, which in some examples give rise to predicted rates that are several orders of magnitude in error. One such example is that of sulphuric acid and water nucleation which has long been framed as an important source of cloud condensation nuclei and therefore has implications for the climate, both locally and globally. In addition str...
Pseudo-one-dimensional nucleation in dilute polymer solutions
Zhang, Lingyun; Schmit, Jeremy D.
2016-06-01
Pathogenic protein fibrils have been shown in vitro to have nucleation-dependent kinetics despite the fact that one-dimensional structures do not have the size-dependent surface energy responsible for the lag time in classical theory. We present a theory showing that the conformational entropy of the peptide chains creates a free-energy barrier that is analogous to the translational entropy barrier in higher dimensions. We find that the dynamics of polymer rearrangement make it very unlikely for nucleation to succeed along the lowest free-energy trajectory, meaning that most of the nucleation flux avoids the free-energy saddle point. We use these results to construct a three-dimensional model for amyloid nucleation that accounts for conformational entropy, backbone H bonds, and side-chain interactions to compute nucleation rates as a function of concentration.
On the Foundational Equations of the Classical Theory of Electrodynamics
Mansuripur, Masud
2014-01-01
A close examination of the Maxwell-Lorentz theory of electrodynamics reveals that polarization and magnetization of material media need not be treated as local averages over small volumes - volumes that nevertheless contain a large number of electric and/or magnetic dipoles. Indeed, Maxwell's macroscopic equations are exact and self-consistent mathematical relations between electromagnetic fields and their sources, which consist of free charge, free current, polarization, and magnetization. When necessary, the discrete nature of the constituents of matter and the granularity of material media can be handled with the aid of special functions, such as Dirac's delta-function. The energy of the electromagnetic field and the exchange of this energy with material media are treated with a single postulate that establishes the Poynting vector S = ExH as the rate of flow of electromagnetic energy under all circumstances. Similarly, the linear and angular momentum densities of the fields are simple functions of the Poy...
On a Gauge Invariant Quantum Formulation for Non-gauge Classical Theory
I.L. Buchbinder; Pershin, V. D.; Toder, G. B.
1996-01-01
We propose a method of constructing a gauge invariant canonical formulation for non-gauge classical theory which depends on a set of parameters. Requirement of closure for algebra of operators generating quantum gauge transformations leads to restrictions on parameters of the theory. This approach is then applied for illustration to bosonic string theory coupled to background tachyonic field. It is shown that within the proposed canonical formulation the known mass-shell condition for tachyon...
Methods of geometric function theory in classical and modern problems for polynomials
This paper gives a survey of classical and modern theorems on polynomials, proved using methods of geometric function theory. Most of the paper is devoted to results of the author and his students, established by applying majorization principles for holomorphic functions, the theory of univalent functions, the theory of capacities, and symmetrization. Auxiliary results and the proofs of some of the theorems are presented. Bibliography: 124 titles.
Antigravity and classical solutions of five-dimensional Kaluza-Klein theory
Classical solutions are exhibited of a graviton-graviphoton-graviscalar field theory which are antigravitating in the weak-field approximation. The theory itself is obtained by a Kaluza-Klein type reduction from five to four dimensions. The solutions are dyonic black holes with scalar charge. They share some similarities with the extreme Reissner-Nordstrom black holes of Einstein-Maxwell theory. (author)
Impurity mediated nucleation in hexadecane-in-water emulsions
Herhold, Amy; Ertas, Deniz; Levine, Alex J.; King Jr, H. E.
1998-01-01
We report detailed nucleation studies on the liquid-to-solid transition of hexadecane using nearly monodisperse hexadecane-in-water emulsions. A careful consideration of the kinetics of isothermal and nonisothermal freezing show deviations from predictions of classical nucleation theory, if one assumes that the emulsion droplet population is homogeneous. Similar deviations have been observed previously. As an explanation, we propose a novel argument based on the dynamic generation of droplet ...
The one loop effective action in quantum field theory can be expressed as a quantum mechanical path integral over world lines, with internal symmetries represented by Grassmanian variables. In this paper, we develop a real time, many body, world line formalism for the one loop effective action. In particular, we study hot QCD and obtain the classical transport equations which, as Litim and Manuel have shown, reduce in the appropriate limit to the non-Abelian Boltzmann-Langevin equation first obtained by Boedeker. In the Vlasov limit, the classical kinetic equations are those that correspond to the hard thermal loop effective action. We also discuss the imaginary time world line formalism for a hot φ4 theory, and elucidate its relation to classical transport theory. (c) 2000 The American Physical Society
Jalilian-Marian, J; Venugopalan, R; Wirstam, J; Jalilian-Marian, Jamal; Jeon, Sangyong; Venugopalan, Raju; Wirstam, Jens
2000-01-01
The one loop effective action in quantum field theory can be expressed as a quantum mechanical path integral over world lines, with internal symmetries represented by Grassmanian variables. In this paper, we develop a real time, many body, world line formalism for the one loop effective action. In particular, we study hot QCD and obtain the classical transport equations which, as Litim and Manuel have shown, reduce in the appropriate limit to the non-Abelian Boltzmann-Langevin equation first obtained by Bödeker. In the Vlasov limit, the classical kinetic equations are those that correspond to the hard thermal loop effective action. We also discuss the imaginary time world line formalism for a hot $\\phi^4$ theory, and elucidate its relation to classical transport theory.
Treatise on classical elasticity theory and related problems
Teodorescu, Petre P
2013-01-01
Deformable solids have a particularly complex character; mathematical modeling is not always simple and often leads to inextricable difficulties of computation. One of the simplest mathematical models and, at the same time, the most used model, is that of the elastic body – especially the linear one. But, notwithstanding its simplicity, even this model of a real body may lead to great difficulties of computation. The practical importance of a work about the theory of elasticity, which is also an introduction to the mechanics of deformable solids, consists of the use of scientific methods of computation in a domain in which simplified methods are still used. This treatise takes into account the consideration made above, with special attention to the theoretical study of the state of strain and stress of a deformable solid. The book draws on the known specialized literature, as well as the original results of the author and his 50+ years experience as Professor of Mechanics and Elasticity at the University o...
Momentum relation and classical limit in the future-not-included complex action theory
Nagao, Keiichi
2013-01-01
Studying the time development of the expectation value in the future-not-included complex action theory we point out that the momentum relation (relation analogous to $p=\\frac{\\partial L}{\\partial \\dot{q}}$), which was derived via Feynman path integral and was shown to be right in the future-included theory in our previous papers, is not valid in the future-not-included theory. We provide the correct momentum relation in the future-not-included theory, and argue that the future-not-included classical theory is described by a certain real action. In addition we provide another way to understand the time development of the future-not-included theory by utilizing the future-included theory. Furthermore, applying the method used in our previous paper to the future-not-included theory properly by introducing a formal Lagrangian, we derive the correct momentum relation in the future-not-included theory.
A generalization of a classical model in contract theory: The agent behavior
Gutiérrez, Francisco; Moreno, Stefany
2011-01-01
We present a first approximation of agent behaviour in a generalized model in contract theory. This model relaxes some of the the assumptions of one of the classical models allowing to include a broader range of agents. We introduce the motivation for the agent and reinterpret the classical definition of risk perception. Besides, we analyze different scenarios for the relation between the effort exerted by the agent and the probability that he gets an especfic result.
Development of a unified viscoplasticity constitutive model based on classical plasticity theory
GUAN Ping; LIU ChangChun; L(U) HeXiang
2009-01-01
The traditional unified viscoplasticity constitutive model can be only applied to metal materials. The study of the unified constitutive theory for metal materials has discovered the correlation between the classical plasticity theory and the unified viscoplasticity constitutive model, thus leading to the con-cepts of the classic plastic potential and yield surface in the unified constitutive model. Moreover, this research has given the continuous expression of the classical plastic multiplier and presented the corresponding constructive method, which extends its physical significance and lays down a good foundation for the application of the unified constitutive theory to the material analysis in more fields.This paper also introduces the unified constitutive model for metal materials and geo-materials. The numerical simulation indicates that the construction should be both reasonable and practical.
Development of a unified viscoplasticity constitutive model based on classical plasticity theory
无
2009-01-01
The traditional unified viscoplasticity constitutive model can be only applied to metal materials.The study of the unified constitutive theory for metal materials has discovered the correlation between the classical plasticity theory and the unified viscoplasticity constitutive model,thus leading to the con-cepts of the classic plastic potential and yield surface in the unified constitutive model.Moreover,this research has given the continuous expression of the classical plastic multiplier and presented the corresponding constructive method,which extends its physical significance and lays down a good foundation for the application of the unified constitutive theory to the material analysis in more fields.This paper also introduces the unified constitutive model for metal materials and geo-materials.The numerical simulation indicates that the construction should be both reasonable and practical.
Classical and quantum contents of solvable game theory on Hilbert space
A simple and general formulation of the quantum game theory is presented, accommodating all possible strategies in the Hilbert space for the first time. The theory is solvable for the two strategy quantum game, which is shown to be equivalent to a family of classical games supplemented by quantum interference. Our formulation gives a clear perspective to understand why and how quantum strategies outmaneuver classical strategies. It also reveals novel aspects of quantum games such as the stone-scissor-paper phase sub-game and the fluctuation-induced moderation
Theory for nucleation at an interface and magnetization reversal of a two-layer nanowire
Loxley, P.N.; Stamps, R. L.
2006-01-01
Nucleation at the interface between two adjoining regions with dissimilar physical properties is investigated using a model for magnetization reversal of a two-layer ferromagnetic nanowire. Each layer of the nanowire is considered to have a different degree of magnetic anisotropy, representing a hard magnetic layer exchange-coupled to a softer layer. A magnetic field applied along the easy axis causes the softer layer to reverse, forming a domain wall close to the interface. For small applied...
Neo-classical theory of competition or Adam Smith's hand as mathematized ideology
McCauley, Joseph L.
2001-10-01
Orthodox economic theory (utility maximization, rational agents, efficient markets in equilibrium) is based on arbitrarily postulated, nonempiric notions. The disagreement between economic reality and a key feature of neo-classical economic theory was criticized empirically by Osborne. I show that the orthodox theory is internally self-inconsistent for the very reason suggested by Osborne: lack of invertibility of demand and supply as functions of price to obtain price as functions of supply and demand. The reason for the noninvertibililty arises from nonintegrable excess demand dynamics, a feature of their theory completely ignored by economists.
a Classical Isodual Theory of Antimatter and its Prediction of Antigravity
Santilli, Ruggero Maria
An inspection of the contemporary physics literature reveals that, while matter is treated at all levels of study, from Newtonian mechanics to quantum field theory, antimatter is solely treated at the level of second quantization. For the purpose of initiating the restoration of full equivalence in the treatment of matter and antimatter in due time, and as the classical foundations of an axiomatically consistent inclusion of gravitation in unified gauge theories recently appeared elsewhere, in this paper we present a classical representation of antimatter which begins at the primitive Newtonian level with corresponding formulations at all subsequent levels. By recalling that charge conjugation of particles into antiparticles is antiautomorphic, the proposed theory of antimatter is based on a new map, called isoduality, which is also antiautomorphic (and more generally, antiisomorphic), yet it is applicable beginning at the classical level and then persists at the quantum level where it becomes equivalent to charge conjugation. We therefore present, apparently for the first time, the classical isodual theory of antimatter, we identify the physical foundations of the theory as being the novel isodual Galilean, special and general relativities, and we show the compatibility of the theory with all available classical experimental data on antimatter. We identify the classical foundations of the prediction of antigravity for antimatter in the field of matter (or vice-versa) without any claim on its validity, and defer its resolution to specifically identified experiments. We identify the novel, classical, isodual electromagnetic waves which are predicted to be emitted by antimatter, the so-called space-time machine based on a novel non-Newtonian geometric propulsion, and other implications of the theory. We also introduce, apparently for the first time, the isodual space and time inversions and show that they are nontrivially different than the conventional ones, thus