Fault Length Vs Fault Displacement Evaluation In The Case Of Cerro Prieto Pull-Apart Basin (Baja California, Mexico) Subsidence

Science.gov (United States)

Glowacka, E.; Sarychikhina, O.; Nava Pichardo, F. A.; Farfan, F.; Garcia Arthur, M. A.; Orozco, L.; Brassea, J.

2013-05-01

The Cerro Prieto pull-apart basin is located in the southern part of San Andreas Fault system, and is characterized by high seismicity, recent volcanism, tectonic deformation and hydrothermal activity (Lomnitz et al, 1970; Elders et al., 1984; Suárez-Vidal et al., 2008). Since the Cerro Prieto geothermal field production started, in 1973, significant subsidence increase was observed (Glowacka and Nava, 1996, Glowacka et al., 1999), and a relation between fluid extraction rate and subsidence rate has been suggested (op. cit.). Analysis of existing deformation data (Glowacka et al., 1999, 2005, Sarychikhina 2011) points to the fact that, although the extraction changes influence the subsidence rate, the tectonic faults control the spatial extent of the observed subsidence. Tectonic faults act as water barriers in the direction perpendicular to the fault, and/or separate regions with different compaction, and as effect the significant part of the subsidence is released as vertical displacement on the ground surface along fault rupture. These faults ruptures cause damages to roads and irrigation canals and water leakage. Since 1996, a network of geotechnical instruments has operated in the Mexicali Valley, for continuous recording of deformation phenomena. To date, the network (REDECVAM: Mexicali Valley Crustal Strain Measurement Array) includes two crackmeters and eight tiltmeters installed on, or very close to, the main faults; all instruments have sampling intervals in the 1 to 20 minutes range. Additionally, there are benchmarks for measuring vertical fault displacements for which readings are recorded every 3 months. Since the crackmeter measures vertical displacement on the fault at one place only, the question appears: can we use the crackmeter data to evaluate how long is the lenth of the fractured fault, and how quickly it grows, so we can know where we can expect fractures in the canals or roads? We used the Wells and Coppersmith (1994) relations between

Criteria to determine the depth of the production interval in wells of the Cerro Prieto geothermal field, Mexico; Criterios para determinar la profundidad del intervalo productor en pozos del campo geotermico de Cerro Prieto, Mexico

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Leon Vivar, Jesus Saul de [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)]. E-mail: jesus.deleon@cfe.gob.mx

2006-07-15

Ways to select the depth of the production interval or to complete wells in the Cerro Prieto geothermal field have changed during the development of the field. From 1961 when drilling began to the middle of 2005, a total of 325 wells were drilled. The paper compares the approaches used in the past with those of the last ten years. The Cerro Prieto system has been classified as being of liquid-dominated and high-temperature. Today, after 33 years of commercial exploitation, it has experienced a series of thermal and geochemical fluid changes making it necessary to modify the ways to select the depth of the well production intervals, according to the observed behavior of the reservoir. The new criteria include the thermal approach, the geological approach, the geochemical approach and a comparative approach with neighboring wells. If most of these criteria are interpreted correctly, the success of a well is ensured. [Spanish] Los criterios para seleccionar la profundidad del intervalo productor o la terminacion de los pozos en el campo geotermico de Cerro Prieto han cambiado durante el desarrollo del mismo. De 1961, cuando se perforaron los primeros pozos, hasta mediados del 2005 se han perforado un total de 325 pozos. En el presente articulo se hara una breve revision de cuales han sido los criterios usados en el pasado y los que se han venido empleando en los ultimos diez anos. El yacimiento de Cerro Prieto ha sido clasificado como de liquido dominante, de alta temperatura, pero actualmente, despues de 33 anos de explotacion comercial, ha sufrido una serie de cambios termicos y geoquimicos en sus fluidos, por lo que ha sido necesario modificar los criterios para seleccionar la profundidad del intervalo productor de los pozos de acuerdo al comportamiento observado en el yacimiento. Los criterios actuales se dividen en cuatro: 1. Criterio termico, 2. Criterio geologico, 3. Criterio geoquimico y 4. Criterio comparativo de los pozos vecinos. Cuando la mayoria de estos

Reservoir Simulation on the Cerro Prieto Geothermal Field: A Continuing Study

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Castaneda, M.; Marquez, R.; Arellano, V.; Esquer, C.A.

1983-12-15

The Cerro Prieto geothermal field is a liquid-dominated geothermal reservoir of complex geological and hydrological structure. It is located at the southern end of the Salton-Mexicali trough which includes other geothermal anomalies as Heber and East Mesa. Although in 1973, the initial power plant installed capacity was 75 MW of electrical power, this amount increased to 180 MW in 1981 as field development continued. It is expected to have a generating capacity of 620 MW by the end of 1985, when two new plants will be completely in operation. Questions about field deliverability, reservoir life and ultimate recovery related to planned installations are being presently asked. Numerical modeling studies can give very valuable answers to these questions, even at the early stages in the development of a field. An effort to simulate the Cerro Prieto geothermal reservoir has been undergoing for almost two years. A joint project among Comision Federal de Electricidad (CFE), Instituto de Investigaciones Electricas (IIE) and Intercomp of Houstin, Texas, was created to perform reservoir engineering and simulation studies on this field. The final project objective is tosimulate the behavior of the old field region when production from additional wells located in the undeveloped field zones will be used for feeding the new power plants.

Progress on the biphase turbine at Cerro Prieto

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Cerini, D.; Hays, L.; Studhalter, W. [Douglas Energy Company, Placentia, CA (United States)

1997-12-31

The status of a Biphase turbine power plant being installed at the Cerro Prieto geothermal field is presented. The major modules for the power plant are completed except for a back pressure steam turbine. The power plant will be started in April 1997 with the Biphase turbine alone followed by the addition of the steam turbine module two months later. The current power plant performance level is 2780 kWe due to a decline in the well. An increase in power output to 4060 kWe by adding the flow from another well is planned. The addition of five Biphase power plants with a total power output of 21.2 megawatts is described.

Analysis of the Nuevo Leon magnetic anomaly and its possible relation to the Cerro Prieto magmatic-hydrothermal system

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Goldstein, N.E.; Wilt, M.J.; Corrigan, D.J.

1982-10-01

The broad dipolar magnetic anomaly whose positive peak is centered near Ejido Nuevo Leon, some 5 km east of the Cerro Prieto I Power Plant, has long been suspected to have a genetic relationship to the thermal source of the Cerro Prieto geothermal system. This suspicion was reinforced after several deep geothermal wells, drilled to depths of 3 to 3.5 km over the anomaly, intersected an apparent dike-sill complex consisting mainly of diabase but with minor rhyodacite. A detailed fit of the observed magnetic field to a computer model indicates that the source may be approximated by a tabular block 4 by 6 km in area, 3.7 km in depth, 2.3 km thick, and dipping slightly to the north. Mafic dike chips from one well, NL-1, were analyzed by means of electron microprobe analyses which showed tham to contain a titanomagnetite that is paramagnetic at in-situ temperature conditions. As the dike mineralogy does not account for the magnetic anomaly, the magnetic source is believed to be a deeper, magnetite-rich assemblage of peridotite-gabbro plutons. the suite of igneous rocks was probably passively emplaced at a shallow depth in response to crustal extension and thinning brought on by strike-slip faulting. The bottom of the magnetic source body, at an estimated depth of 6 km, is presumed to be at or near that of the Curie isotherm (575/sup 0/C) for magnetite, the principal ferromagnetic mineral in peridotitic-gabbroic rocks. The geological model derived from the magnetic study is generally supported by other geophysical data. In particular, earthquake data suggest dike injection is occurring at depths of 6 to 11 km in an area beneath the magnetic source. Thus, it is possible that heat for the geothermal field is being maintained by continuing crustal extension and magmatic activity.

Evolution of the CP-I sector of the Cerro Prieto geothermal reservoir, BC, and exploitation alternatives; Evolucion del sector CP-I del yacimiento geotermico de Cerro Prieto, BC, y alternativas de explotacion

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Rodriguez Rodriguez, Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

2010-01-15

After 35 years of exploitation of the CP-I (Cerro Prieto I) sector of the Cerro Prieto geothermal field, its thermal conditions have been declined substantially; the number of production wells is reduced and exploitation has been abandoned in some zones. However with a binary cycle, it is still possible to generate electricity from the remaining reservoir energy. To do so, one needs to know a detailed reservoir history of the sector, identifying the best potential strata to be assessed. In this paper, the CP-I reservoir evolution is presented and its exploitation and main reservoir characteristics -which play important roles- are identified. The CP-I zones offering the best conditions for binary cycle exploitation are identified. Exploiting partially abandoned reservoir sections is crucial for the future of the field. If such sections can be made to produce, this will help reduce the progressive steam-production decline in the occurring since production began. The production decline had been mitigated by a large area available for drilling replacement production wells, but such an area is limited now, due to the vast number of operating wells. [Spanish] Despues de 35 anos de explotacion del yacimiento en el sector de CP-I (Cerro Prieto I) del campo geotermico de Cerro Prieto, BC, sus condiciones termicas han declinado considerablemente, por lo que el numero de pozos productores ha disminuido, dejando algunas zonas abandonadas a la explotacion. Sin embargo, aun es posible aprovechar la energia que contiene este sector del yacimiento para la generacion de electricidad mediante ciclo binario. Para ello primeramente se debe conocer en detalle cual ha sido la evolucion del yacimiento en este sector, identificando los estratos de mejor potencial para evaluarlos posteriormente. En este estudio se presenta la evolucion del yacimiento de CP-I como respuesta a su explotacion, identificando las principales caracteristicas del yacimiento que determinan su comportamiento. Asi

Changes in steam production due to the reservoir conditions in Cerro Prieto, Baja California; Cambios en la produccion de vapor debido a las condiciones del yacimiento en Cerro Prieto, Baja California

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Morales Cardenas, Ramon; Rodriguez Rodriguez, Marco H. [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)]. E-mail: marco.rodriguez01@gfe.gob.mx

2011-07-15

In more than 35 years of exploitation, thermodynamic conditions have changed in the Cerro Prieto geothermal reservoir. The effects are analyzed of the changes to the reservoir and their consequences to steam production in different field zones. For steam production, the most important features of reservoir fluids are enthalpies and pressures. The evolution of these features is presented in an enthalpy-pressure diagram. Here it can be seen that some reservoir zones have almost reached abandonment conditions. [Spanish] En mas de 35 anos de explotacion el yacimiento geotermico de Cerro Prieto ha experimentado cambios en sus condiciones termodinamicas. En este trabajo se analiza el efecto de esos cambios del yacimiento y su repercusion en la produccion de vapor para las diferentes zonas en las que se ha dividido el campo. Las propiedades mas importantes del fluido en el yacimiento para la produccion de vapor son su entalpia y su presion, por lo que se presenta la evolucion de esas propiedades en un diagrama de presion-entalpia, en el que se observa que hay zonas del yacimiento que estan proximas a alcanzar condiciones de abandono.

Hydraulic model of the steam-lines network of the Cerro Prieto, B.C., geothermal field; Modelo hidraulico de la red de vaporductos del campo geotermico de Cerro Prieto, B.C.

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Salaices, E; Garcia, A; Martinez J I; Ovando, R; Cecenas, M; Hernandez A F [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: salaices@iie.org.mx; Canchola, I; Mora, O; Miranda, C; Herandez, M; Lopez, S; Murillo, I [Comision Federal de Electricidad, B.C (Mexico)

2007-01-15

The steam-line network of the Cerro Prieto geothermal field is composed of 184 wells, and 162 of the wells are integrated and connected by pipes. Thirteen power units, with an installed electrical capacity of 720 MW, are fed by that network. The network length is 120 km, including pipes of several diameters with branches and interconnections. The extension and complexity of the steam-line system make it difficult to analyze the transport and supply of steam to the power plants. For that it was necessary to have a tool capable of analyzing the system and the performance of the network as a whole, as well as the direction and flow volumes in each part of the system. In this paper, a hydraulic model of the Cerro Prieto steam-line network is presented. The model can determine the performance of the whole network by quantifying the pressure drops, flows and heat losses of the components. The model analyses the consequences of changes in operating conditions, steam production, maintenance activities and design (such as the integration of new wells). The model was developed using PIPEPHASE 9.0, a numeric simulator of multi-phase flow in steady state with heat transfer. It is used to model systems and pipe networks for steam- and condensate-transport. [Spanish] La red de vaporductos del campo geotermico de Cerro Prieto esta compuesta por un conjunto de 184 pozos, de los cuales 162 son pozos integrados, interconectados entre si a traves de una red de tuberias. Por medio de esta red se alimentan 13 unidades generadoras de electricidad con una capacidad total instalada de 720 MWe. La red tiene una longitud aproximada de 120 kilometros y esta compuesta por tuberias de diferentes diametros, ramales, interconexiones, etc. La complejidad y extension del sistema de vaporductos hace muy dificil el analisis del transporte y suministro de vapor a las plantas generadoras. Lo anterior creo la necesidad de contar con una herramienta que ayudara en el analisis del sistema con el fin de

Land subsidence in the Cerro Prieto Geothermal Field, 1 Baja California, Mexico, from 1994 to 2005. An integrated analysis of DInSAR, levelingand geological data.

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Sarychikhina, O; Glowacka, E; Mellors, R; Vidal, F S

2011-03-03

Cerro Prieto is the oldest and largest Mexican geothermal field in operation and has been producing electricity since 1973. The large amount of geothermal fluids extracted to supply steam to the power plants has resulted in considerable deformation in and around the field. The deformation includes land subsidence and related ground fissuring and faulting. These phenomena have produced severe damages to infrastructure such as roads, irrigation canals and other facilities. In this paper, the technique of Differential Synthetic Aperture Radar Interferometry (DInSAR) is applied using C-band ENVISAR ASAR data acquired between 2003 and 2006 to determine the extent and amount of land subsidence in the Mexicali Valley near Cerro Prieto Geothermal Field. The DInSAR results were compared with published data from precise leveling surveys (1994- 1997 and 1997-2006) and detailed geological information in order to improve the understanding of temporal and spatial distributions of anthropogenic subsidence in the Mexicali Valley. The leveling and DInSAR data were modeled to characterize the observed deformation in terms of fluid extraction. The results confirm that the tectonic faults control the spatial extent of the observed subsidence. These faults likely act as groundwater flow barriers for aquifers and reservoirs. The shape of the subsiding area coincides with the Cerro Prieto pull-apart basin. In addition, the spatial pattern of the subsidence as well as changes in rate are highly correlated with the development of the Cerro Prieto Geothermal Field.

Areas to explore surrounding the Cerro Prieto geothermal field, BC; Areas para exploracion en los alrededores del campo geotermico de Cerro Prieto, BC

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Aguilar Dumas, Alvaro [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: alvaro.aguilar@cfe.gob.mx

2009-07-15

Exploration plays an important role in tapping underground natural resources-whether water, oil, natural gas or minerals. Exploratory data allow us to learn reservoir conditions, increasing probable reserves and reservoir life span. Around the Cerro Prieto geothermal field, BC, and in the Mexicali Valley in general, exploration had almost stopped but recently was resumed by the Studies Division of Comision Federal de ELectricidad (CFE)'s Gerencia de Proyectos Geotermoelectricos. The division sent technical personnel to structurally map the northern and eastern portions of Laguna Salada. The paper offers a general outline of the main zones undergoing exploratory studies-studies perhaps culminating in siting exploratory wells to locate more geothermal resources (and ultimately producing them using binary power plants). CFE also wants to site injection wells west of the current production zone, and this is covered, as well. All activities are meant to increase the productive lifespan of the geothermal reservoir. [Spanish] Cuando se trata de la explotacion de recursos naturales del subsuelo, sea agua, gas, petroleo o minerales, la exploracion juega un papel muy importante, ya que permite conocer las condiciones del yacimiento que pudieran llevar a incrementar las reservas de los recursos explotados y extender su vida util. En las zonas aledanas al campo geotermico de Cerro Prieto, BC, y en general en el Valle de Mexicali, la exploracion estaba practicamente detenida habiendose reactivado a raiz de que la Subgerencia de Estudios de la Gerencia de Proyectos Geotermoelectricos de la Comision Federal de Electricidad (CFE) envio personal para realizar mapeos estructurales en las porciones norte y oriente de la Laguna Salada. Este trabajo presenta un panorama general de las areas prioritarias para realizar estudios exploratorios y poder programar, con mas bases, pozos exploratorios enfocados a localizar mas recursos geotermicos, inclusive para generar energia por medio

Evaluation of geologic characteristics at Cerro Prieto

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Howard, J.H.; Halfman, S.E.; Vonder Haar, S.P.

1981-01-01

Computerized well-log analysis of Cerro Prieto has led to the identification of a relatively large and irregular low-density volume extending from near the surface in the vicinity of Laguna Volcano to greater depths toward the northeast. This low-density volume is located about a plane of symmetry of a self-potential anomaly and a group of northeast trending active faults. The presence of a volume of relatively high-density rock has been recognized at shallow depths in the initially developed part of the resource. It is believed to be due to minerals deposited by cooled, rising geothermal brine. Storativity calculated from well logs at the south end of the western part of the field shows acceptable comparison with storativity calculated from well tests. The amount of fluid produced from the field during the period 1973-1977 is greater than the amount in situ calculated from the completed interval thicknesses. Because this part of the field is still producing today, fluid must be recharging this part of the field.

Groundwater Chemistry and Overpressure Evidences in Cerro Prieto Geothermal Field

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Ivan Morales-Arredondo

2017-01-01

Full Text Available In order to understand the geological and hydrogeological processes influencing the hydrogeochemical behavior of the Cerro Prieto Geothermal Field (CP aquifer, Mexico, a characterization of the water samples collected from geothermal wells was carried out. Different hydrochemical diagrams were used to evaluate brine evolution of the aquifer. To determine pressure conditions at depth, a calculation was performed using hydrostatic and lithostatic properties from CP, considering geological characteristics of the study area, and theoretical information about some basin environments. Groundwater shows hydrogeochemical and geological evidences of the diagenetic evolution that indicate overpressure conditions. Some physical, chemical, textural, and mineralogical properties reported in the lithological column from CP are explained understanding the evolutionary process of the sedimentary material that composes the aquifer.

Mineralogy of the silica-epidote mineralized zone (SEMZ) in the Cerro Prieto geothermal reservoir, B.C., Mexico; Mineralogia de la zona mineralizada de silice-epidota (ZMSE) del yacimiento geotermico de Cerro Prieto, B.C., Mexico

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Izquierdo, Georgina; Aragon, Alfonso; Portugal, Enrique; Arellano; Victor M [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Cuernavaca, Morelos (Mexico)]. E-mail: gim@iie.org.mx; Leon, Jesus de; Alvarez, Julio [Comision Federal de Electricidad, B.C. (Mexico)

2006-07-15

The distribution of hydrothermal minerals, mineral assemblages and fluid inclusion data were taken from drill cuttings from the production zone of wells all over the Cerro Prieto geothermal field. The production zone has been termed the silica-epidote mineralized zone (SEMZ), and is located in the deep part of the gray shale where thick layers of sandstone are found. Common mineral assemblages show three temperature ranges in the SEMZ: <200 degrees Celsius, 200-250 degrees Celsius and 250-300 degrees Celsius. The first range is characterized by clays, calcite and quartz; the second by quartz, epidote, chlorite and mica, and the third by epidote, amphibole, illite and chlorite. The study of fluid inclusions in authigenic grain quartz has shown two-phase fluid inclusions (liquid + vapor) of different salinities. A wide range exists of homogenization temperatures (Th) and for some wells there is a good agreement between Th and direct temperature measurements. [Spanish] Se determino la distribucion de minerales hidrotermales y las asociaciones parageneticas y se realizo el estudio microtermometrico de inclusiones fluidas a partir de recortes de perforacion de pozos de las distintas areas del campo geotermico de Cerro Prieto. Las muestras de recortes y nucleos de perforacion estudiados provienen de la zona de produccion a la que se le ha denominado Zona Mineralizada de Silice-Epidota (ZMSE), que se encuentra en la parte profunda de la lutita gris con importantes horizontes de areniscas. En esta zona las asociaciones parageneticas mas comunes han mostrado tres intervalos de temperatura para la ZMSE: <200 degrees Celsius, 200-250 degrees Celsius, 250-300 degrees Celsius. El primer intervalo esta caracterizado principalmente por arcillas, calcita y cuarzo; el segundo por cuarzo, epidota, clorita y micas, y el tercero por epidota, anfiboles, illita y clorita. El estudio de inclusiones fluidas en fragmentos de cuarzo autigenico mostro la presencia de inclusiones de dos fases

Noise reduction in steam-vent points at the Cerro Prieto geothermal field, BC; Reduccion del ruido en puntos de desfogue en el campo geotermico de Cerro Prieto, BC

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Miranda Herrera, Carlos A [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, B.C (Mexico)]. E-mail: carlos.miranda02@cfe.gob.mx

2008-01-15

Steam silencers have been placed on the power units regulation system of the Cerro Prieto geothermal field, but not where the steam-pipes vent high-pressure steam (rupture disks). Moreover, the power-unit silencers are large and their abilities to reduce noise depend on an external, uncontrollable factor: pores sizes in the volcanic rocks they are made of. Thus a compact, economic and relatively easy to construct metallic silencer was designed to be used at several points of dry-steam venting to minimize the noise. The design was based on orifice-plate equations and a prototype was constructed and tested. It proved capable of reducing noise by 30 decibels for atmospheric discharges of primary steam at operating pressures. The size of the silencer can be adjusted to the particular needs of each vent case. [Spanish] En el campo geotermico de Cerro Prieto solo existen silenciadores de vapor en el sistema de regulacion de las plantas generadoras, pero no en los sitios de desfogue de vapor a alta presion en los vaporductos (discos de ruptura). Ademas, los silenciadores de las plantas son muy robustos y su capacidad de reduccion del ruido depende de un factor externo no controlable, como es el tamano del poro de la roca volcanica con el que estan construidos. Por lo tanto, se diseno un silenciador metalico compacto, economico y relativamente facil de fabricar, para utilizarse en diversos puntos de descarga de vapor seco a fin de minimizar el ruido. El diseno se realizo con base en las ecuaciones de la placa de orificio. Se construyo un prototipo cuyas pruebas demostraron que es capaz de reducir el ruido hasta en 30 decibeles, al descargar desde la presion de operacion de vapor primario hacia la presion atmosferica. Las dimensiones del silenciador pueden ajustarse a las necesidades particulares de cada caso de desfogue.

Performance of casings in Cerro Prieto production wells

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Dominguez A, B.; Vital B, F.; Bermejo M, F.; Sanchez G, G.

1981-01-01

A careful evaluation of different production casings used at Cerro Prieto from 1964 to date has shown that the following casings have yielded particularly impressive results: 7 5/8-in. diameter, J-55, 26 lb/ft; 7 5/8-in. diameter, K-55, 45.3 lb/ft; and 5-in. diameter, K-55, 23.2 lb/ft. These casings differ from others of the same diameter but lighter weight which were also used at the field. The results are favorable in spite of severe construction problems, especially the loss of circulation during cementing operations, which we encountered in some of the wells where these casings were used. The use of gravity-fed fine sand as packing material and the arrangement of the production and intermediate casings were important in avoiding damage due to tension-compression stresses and, above all, damage due to internal or external corrosion over time. This situation is clearly evidenced if we compare the damage to the above casings with that experienced by grade N-80 production casings, especially in a corrosive environment.

Geohydrologic conditions of the shallow aquifer in the Cerro Prieto geothermal field zone; Condiciones geohidrologicas del acuifero somero en la zona del campo geotermico de Cerro Prieto

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Vazquez Gonzalez, Rogelio [CICESE, Ensenada, Baja California (Mexico)

1999-04-01

Based on geohydrologic information reported by Comision Nacional del Agua, Comision Federal de Electricidad and several academic institutions, we have performed an analysis to establish in general terms, the past and present behavior of the shallow aquifer in the Cerro Prieto geothermal zone (CPGZ). The main features of the aquifer, derived from the interpretation of the results obtained with several disciplines, are as follows: The shallow aquifer in CPGZ is part of the regional hydrologic system of the Mexicali valley basin. The basin is filled with unconsolidated delta deposits interbedded with alluvial sediments from the Sierra Cucapa, which forms an impervious boundary. Because the lack of information about the hydraulic properties of the sediments, just possible ranges of values were obtained for the hydraulic conductivity and storativity corresponding to three deposit environments: a) delta flood plain facies, b) estuarine or lagoon environment facies, c) distal alluvial fan facies. [Spanish] Con base en la informacion geohidrologica de la Comision Nacional del Agua, la Comision Federal de Electricidad e instituciones academicas, se realizo un analisis para establecer las condiciones geohidrologicas y el panorama general del comportamiento historico y actual del acuifero somero en la zona del campo geotermico de Cerro Prieto (CGCP). De la interpretacion e integracion de los resultados obtenidos de las diferentes disciplinas utilizadas en el desarrollo del estudio, se derivan las siguientes conclusiones: El acuifero somero en la zona del CGCP forma parte del acuifero regional del valle de Mexicali. La secuencia litologica en el area de estudio esta constituida por sedimentos no consolidados de origen deltaico interdigitados con sedimentos aluviales provenientes de la Sierra Cucapa, que sirve como frontera impermeable. La informacion sobre las propiedades hidraulicas de los materiales en el area de interes es limitada, por lo cual solo se determinan los

Cost model for geothermal wells applied to the Cerro Prieto geothermal field case, BC Abstract; Modelo de costeo de pozos geotermicos aplicado para el caso del campo geotermico de Cerro Prieto, BC

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Vaca Serrano, Jaime M.E [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico)]. E-mail: jaime.vaca@cfe.gob.mx

2008-01-15

A project for drilling geothermal wells to produce electrical energy can be defined as a sequence of plans to get steam or geothermal fluids to satisfy a previously known demand, and, under the best possible conditions, to obtain payment. This paper presents a cost model for nine wells drilled at the Cerro Prieto geothermal field in 2005 and 2006 to supply steam to the power plants operating in the field. The cost model is based on the well cost, the initial steam production, the annual decline of steam, the drilling schedule and the break-even point for each well. The model shows the cost of steam by the ton and the sale price needed to determine the discount rate and the investment return time. [Spanish] Un proyecto de perforacion de pozos geotermicos puede definirse como una secuencia o sucesion de planes para obtener vapor o fluidos geotermicos destinados a satisfacer una demanda previamente determinada, que se emplearan principalmente para generar energia electrica, bajo las mejores condiciones para obtener un pago. Este trabajo presenta un modelo de costeo para nueve pozos en el campo geotermico de Cerro Prieto, que fueron perforados entre 2005 y 2006 como parte del suministro de vapor para las plantas generadoras que operan en este campo. El modelo de costeo se basa en el costo por pozo, la produccion inicial de vapor, la declinacion anual de vapor, los intereses de las obras de perforacion y el punto de equilibrio para cada pozo. Los resultados permiten conocer el costo de la tonelada de vapor y el precio de venta para determinar la tasa de descuento y el tiempo de retorno de la inversion.

Hydrothermal alteration zones and present reservoir conditions: an approach to define production zones at the eastern portion of the Cerro Prieto geothermal field, BC; Zonas de alteracion hidrotermal y condiciones actuales del yacimiento: un enfoque para determinar zonas productoras al oriente del campo geotermico de Cerro Prieto, BC

Energy Technology Data Exchange (ETDEWEB)

Camacho Hernandez, Juan Manuel [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: juan.camacho02@cfe.gob.mx

2009-07-15

Geological factors are as essential for locating new wells as they are for defining the production zones of these wells. At the Cerro Prieto geothermal field (CGCP), one of the most important geological factors is identification of the hydrothermal alteration zones (ZAH). These are divided into silica and epidote mineralogical zones (ZMSE), without CaCO{sub 3}, and silica and epidote mineralogical transition zones (ZTMSE), with CaCO{sub 3}. It has been observed that the continuous variation of reservoir thermodynamic conditions (temperature, pressure and enthalpy) is due mainly to the exploitation of geothermal resources. The presence of new thermodynamic conditions recorded at the reservoir has led to the re-location of production wells originally located during the drilling campaign of 2004 to 2006. At the geological sections on the eastern part of the CGCP, adjustments made to the well completions lie on the limits between the ZMSE and ZTMSE zones. In turn, this is related to the current, superior, thermodynamic reservoir conditions. Based on this, a new geologic approach is proposed to define possible production zones for new wells, relating the ZAH zones to current thermodynamic reservoir conditions. [Spanish] Los factores geologicos son determinantes, tanto para establecer nuevos sitios de perforacion como para determinar el intervalo productor de un pozo nuevo. En el campo geotermico de Cerro Prieto (CGCP) una de los factores mas importantes es la determinacion de las zonas de alteracion hidrotermal (ZAH) que se dividen en dos: zona mineralogica de silice y epidota (ZMSE), sin presencia de CaCO{sub 3}, y zona de transicion mineralogica de silice y epidota (ZTMSE), con presencia de CaCO{sub 3}. Por otra parte, tambien se ha constatado que la continua variacion de las condiciones termodinamicas del yacimiento (temperatura, presion y entalpia) es originada en buena medida por la explotacion del recurso geotermico. La ocurrencia de nuevas condiciones

Presence of cross flow in the Cerro Prieto geothermal field, BC; Presencia de flujo cruzado en el campo geotermico de Cerro Prieto, BC

Energy Technology Data Exchange (ETDEWEB)

Rodriguez Rodriguez, Marco Helio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

2011-01-15

During the development of Cerro Prieto geothermal field, BC, exploitation has increased gradually, causing a continuous drop in pressure to almost 100 bars in the central and eastern parts of the field. This has occurred despite the high natural recharge induced by the reservoir exploitation and helped by the high permeability of the reservoir and the wide availability of natural recharge of low-temperature water in the vicinity. The strata above the production zones have significantly lower temperatures than these zones, but due to the particular characteristics of the reservoir, do not have pressure drops. As the pressure of producing strata declines, the hydraulic pressure differential between them and the overlying strata increases. Thus in recent years the phenomenon of cross flow occurs with greater frequency and severity. In this paper, this phenomenon is analyzed, detailing the specific mechanisms favoring it and identifying the stage (drilling or workover) in which it commonly occurs. Rigorous supervision during these stages is crucial to identifying cross flow and to taking necessary measures to save the well. Cross flow cases are presented at different stages in the history of a well: during drilling, repair, before and during the stimulation, and during production. [Spanish] Durante el desarrollo del campo geotermico de Cerro Prieto, BC, la explotacion se ha incrementado en forma gradual provocando una continua caida de presion, que en las porciones central y oriente ha sido de casi 100 bars. Esto ha ocurrido a pesar de la enorme recarga natural inducida por la explotacion, favorecida por la alta permeabilidad del yacimiento y la gran disponibilidad de recarga natural de agua de baja temperatura en los alrededores del mismo. Los estratos ubicados encima de las zonas productoras presentan temperaturas significativamente menores que estos, pero debido a las caracteristicas particulares del yacimiento, no han presentado abatimiento en su presion. En la

Application of oil-field well log interpretation techniques to the Cerro Prieto Geothermal Field

Energy Technology Data Exchange (ETDEWEB)

Ershaghi, I.; Phillips, L.B.; Dougherty, E.L.; Handy, L.L.

1979-10-01

An example is presented of the application of oil-field techniques to the Cerro Prieto Field, Mexico. The lithology in this field (sand-shale lithology) is relatively similar to oil-field systems. The study was undertaken as a part of the first series of case studies supported by the Geothermal Log Interpretation Program (GLIP) of the US Department of Energy. The suites of logs for individual wells were far from complete. This was partly because of adverse borehole conditions but mostly because of unavailability of high-temperature tools. The most complete set of logs was a combination of Dual Induction Laterolog, Compensated Formation Density Gamma Ray, Compensated Neutron Log, and Saraband. Temperature data about the wells were sketchy, and the logs had been run under pre-cooled mud condition. A system of interpretation consisting of a combination of graphic and numerical studies was used to study the logs. From graphical studies, evidence of hydrothermal alteration may be established from the trend analysis of SP (self potential) and ILD (deep induction log). Furthermore, the cross plot techniques using data from density and neutron logs may help in establishing compaction as well as rock density profile with depth. In the numerical method, R/sub wa/ values from three different resistivity logs were computed and brought into agreement. From this approach, values of formation temperature and mud filtrate resistivity effective at the time of logging were established.

Analysis of the automation and control of the well production conditions in the Cerro Prieto geothermal field, Mexico; Analisis de la automatizacion y del control de las condiciones de produccion de los pozos del campo geotermico de Cerro Prieto, BC, Mexico

Energy Technology Data Exchange (ETDEWEB)

Murillo Zamora, Isaac [Comision Federal de Electricidad, Mexicali, BC, (Mexico); Ocampo Diaz, Juan de Dios [Universidad Autonoma de Baja California, Mexicali, BC, (Mexico); De la Pena Reyna, Gilberto [Comision Federal de Electricidad, Morelia, Michoacan (Mexico)

2005-12-01

Through 31 years of development of the Cerro Prieto geothermal field, the number of wells in operation and the distances between them has been increasing. Now there are 150 wells producing a mixture of water and steam at different ratios, depending on the reservoir characteristics (pressure, temperature, depth, etc.) and the operation conditions in the superficial installations (obstructions in the orifice plates diameter, separator pressures, etc.). Therefore, Comision Federal de Electricidad (CFE) has started a pilot plan to handle the automation and control of the operating conditions of production wells, and to install a data production acquisition system. The initial results of the system are in this paper. [Spanish] A traves de los 31 anos de desarrollo del campo geotermico de Cerro Prieto el numero de pozos en operacion asi como la distancia entre ellos se ha estado incrementando. Ahora hay mas de 150 pozos produciendo una cantidad de mezcla de agua y vapor a diferentes rangos, dependiendo de las caracteristicas del yacimiento (presion, temperatura, profundidad, etc.) y de las condiciones de operacion de las instalaciones superficiales (diametros de placas de orificio obstruidos, presion de los separadores, etc.). Como resultado la Comision Federal de Electricidad (CFE) ha dado inicio a un plan de pruebas para llevar a cabo la automatizacion y control de las condiciones de operacion de los pozos productores, e instalar un sistema con equipos para recoleccion de datos del campo, cuyos primeros resultados se presentan en este articulo.

Configuration of the mudstones, gray- and coffee-colored shale lithologic units, zones of silica and epidote, and their relation to the tectonics of the Cerro Prieto geothermal field

Energy Technology Data Exchange (ETDEWEB)

Cobo R, J.M.

1981-01-01

Based on well cuttings, five lithological units have been recognized within the area of what is now the Cerro Prieto geothermal field. These five units are described. Differences in origin, mineralogy, grading, color, compaction, etc., are shown.

Studies for recovering injection capacity in wells of the Cerro Prieto, BC, geothermal field; Estudios para recuperar la capacidad de aceptacion en pozos inyectores del campo geotermico de Cerro Prieto, BC

Energy Technology Data Exchange (ETDEWEB)

Alvarez Rosales, Julio [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: julio.alvarez@cfe.gob.mx

2010-01-15

As in geothermal fields around the world, at Cerro Prieto geothermal field, Baja California, former exploratory and production wells are used to inject residual brine. Since the 1980s, studies and activities have been carried out to find ways to recharge the reservoir and dispose of brine without harming the environment or underground aquifers. These include infiltration and cold-and-hot injection. Some of the studies are presented here, including analyses of litho-facies; core samples; pressure, temperature and spinner logs; well tests and injection rates-plus some studies on the shallow aquifer. All have been useful in fulfilling requirements made by environmental authorities. Because injection rates constantly decrease due to formation damage, it is proposed an additional technique be used to reduce such damages and prolong the lifetime of cold-and-hot injection wells-while ensuring the environment and shallow aquifers are not affected. [Spanish] Al igual que en diversos campos geotermicos en el mundo, en el de Cerro Prieto, Baja California se han utilizado tanto pozos inyectores perforados ex profeso como antiguos pozos exploratorios y productores para inyectar el fluido residual al subsuelo. Desde la decada de los 80 se han realizado diversos estudios y acciones en ese campo geotermico para recargar al yacimiento y para disponer del fluido residual, sin ocasionar danos al ambiente ni a los cuerpos hidricos del subsuelo, que van desde la infiltracion hasta la inyeccion en frio y en caliente. Este articulo presenta los diferentes estudios realizados con ese objetivo en el campo, incluyendo el analisis de litofacies, de nucleos de formacion, de registros de presion, temperatura y spinner, las pruebas en pozos y analisis de tasas de aceptacion, asi como los efectuados en el acuifero superficial. Todos ellos han sido de utilidad para atender los requerimientos de las autoridades ambientales. Finalmente, y en virtud de que las tasas de aceptacion de los pozos

Production induced boiling and cold water entry in the Cerro Prieto geothermal reservoir indicated by chemical and physical measurements

Energy Technology Data Exchange (ETDEWEB)

Grant, M.A. (DSIR, Wellington, New Zealand); Truesdell, A.H.; Manon, A.

1981-01-01

Chemical and physical data suggest that the relatively shallow western part of the Cerro Prieto reservoir is bounded below by low permeability rocks, and above and at the sides by an interface with cooler water. There is no continuous permeability barrier around or immediately above the reservoir. Permeability within the reservoir is dominantly intergranular. Mixture with cooler water rather than boiling is the dominant cooling process in the natural state, and production causes displacement of hot water by cooler water, not by vapor. Local boiling occurs near most wells in response to pressure decreases, but no general vapor zone has formed.

Comments on some of the drilling and completion problems in Cerro Prieto geothermal wells

Energy Technology Data Exchange (ETDEWEB)

Dominguez A, B.; Sanchez G, G.

1981-01-01

From 1960 to the present, 85 wells with a total drilling length exceeding 160,000 m have been constructed at Cerro Prieto, a modest figure compared to an oil field. This activity took place in five stages, each characterized by changes and modifications required by various drilling and well-completion problems. Initially, the technical procedures followed were similar to those used in the oil industry. However, several problems emerged as a result of the relatively high temperatures found in the geothermal reservoir. The various problems that have been encountered can be considered to be related to drilling fluids, cements and cementing operations, lithology, geothermal fluid characteristics, and casings and their accessories. As the importance of high temperatures and the characteristics of the geothermal reservoir fluids were better understood, the criteria were modified to optimize well-completion operations, and satisfactory results have been achieved to date.

Two-phase characteristics of the feeding fluid of Cerro Prieto IV wells (Mexico) obtained by gas equilibrium; Caracteristicas bifasicas del fluido de alimentacion de pozos de Cerro Prieto IV (Mexico), obtenidas por equilibrio gaseoso

Energy Technology Data Exchange (ETDEWEB)

Barragan-Reyes, Rosa Maria; Arellano-Gomez, Victor Manuel; Portugal-Marin, Enrique [Instituto de Investigaciones Electricas (Mexico); De Leon-Vivar, Jesus [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)

2008-10-15

The gas composition of fluids produced by CP IV geothermal wells from the Cerro Prieto field was studied in order to identify different types of fluids entering the wells by estimating their temperature and excess steam. A method based on the Fischer Tropsch reaction and H2S equilibrium with pyrite-pyrrhotite as mineral buffer (FTHSH3) was used. The results for the reservoir natural state indicated the presence of fluids with heterogeneous reservoir temperature (between 275 and 310 degrees Celsius) and excess steam values, which were found from negative (boiled liquid that has lost steam when flowing to the well) to one (steam phase with zero liquid saturation). The study for individual wells in which boiling processes were identified, showed that through time, the feeding fluids consist of a two-phase mixture with different liquid/steam proportions. Also, the results suggested that a steam phase could occur at CP IV which is added to the feeding fluid, depending on the operation conditions of the wells. The origin of this steam could be the boiling of the deeper liquid due to a pressure drop. [Spanish] Se estudio la composicion gaseosa de los fluidos producidos por pozos geotermicos del sector CP IV del campo de Cerro Prieto para tratar de distinguir aportes de fluidos diferentes mediante la estimacion de su temperatura de yacimiento y del exceso de vapor. Se utilizo un metodo de equilibrio gaseoso basado en la reaccion de Fischer Tropsch y el equilibrio combinado pirita-pirrotita (FT-HSH3). Los resultados obtenidos indican que en el estado inicial del yacimiento existen fluidos que muestran heterogeneidad en los valores de temperatura de yacimiento (entre 275 y 310 grados Celsius), asi como en el exceso de vapor con valores desde negativos (liquido que despues de ebullir ha perdido vapor en su trayecto hacia el pozo) hasta uno (vapor con cero saturacion de liquido). El estudio individual de los pozos con fenomenos de ebullicion muestra que a traves del tiempo

Analysis of productive evolution of well M-19A, Cerro Prieto geothermal field, BC; Analisis de la evolucion productiva del pozo M-19A del campo geotermico de Cerro Prieto, BC

Energy Technology Data Exchange (ETDEWEB)

Rodriguez-Rodriguez, Marco H; Romero-Rios, Francisco [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)]. E-mail: marco.rodriguez01@cfe.gob.mx

2007-07-15

Well M-19A has been the most productive in the Cerro Prieto field, producing around 40 million tons of fluid. The well went on line in February 1975 and was in continuous operation until June 2006. Monthly measurements for over 30 years of operating conditions and chemical and isotopic analyses of the fluids allow identification of the most significant processes occurring in the zone where the well is located. Three dominant recharge types have been identified, each lasting about 10 years. They are a) a recharge of fluids of lower temperature than the production fluids, even though the chemical and isotopic compositions are similar; b) a recharge of lower-temperature fluids with diluted chemical and isotopic compositions; and c) a progressive recharge of reinjected water with a higher chloride concentration and heavy isotopic composition. The production and reinjection rates for over 30 years of production history in the M-19A well zone allow for speculation of a reservoir pressure recovery, which is confirmed with a calculation using production data from well M-19A. The evolution of the reservoir pressure in the zone contrasts with the rest of the reservoir, where a constant pressure drop is observed, particularly toward the central and eastern parts of the field. [Spanish] El pozo M-19A ha sido el mas productivo del campo geotermico de Cerro Prieto, BC, alcanzando una extraccion de mas de 40 millones de toneladas de fluido. Fue integrado a produccion en febrero de 1975 y hasta junio de 2006 ha permanecido en produccion en forma continua. Las mediciones mensuales de sus condiciones operativas y los analisis quimicos e isotopicos del agua producida permiten identificar los procesos mas significativos que han ocurrido a lo largo de esos mas de 30 anos en la zona donde se localiza el pozo. Se han identificado tres tipos de recarga dominantes que se presentan durante un periodo cercano a 10 anos cada uno, los cuales son: a) una recarga de fluidos de menor temperatura

Geological and production analyses focused on exploration of the eastern part of the Cerro Prieto geothermal field, BC; Analisis geologico-productivo enfocado a la exploracion de la parte oriental del campo geotermico de Cerro Prieto, BC

Energy Technology Data Exchange (ETDEWEB)

Aguilar Dumas, Alvaro [Comision Federal de Electricidad, Residencia General de Cerro Prieto, B.C (Mexico)]. E-mail: alvaro.aguilar@cfe.gob.mx

2008-01-15

The eastern part of the Cerro Prieto geothermal field (CGCP), known as Poligono Nuevo Leon, is an area with proven geothermal resources, as confirmed by seven directional wells located toward the east and by vertical well M-200 located inside the polygon. Well M-200 was drilled in 1984 and has produced about 4 million tons of steam to date. It is integrated into the CP-2 sector, producing 68 t/h of steam. Presently the eastern part of CGCP, representing 25% of the total field area, is producing over half of the steam for the entire field. In the last few years, the steam has come only after increasing the number of production wells located in the eastern zone of CGCP (Rodriguez, 2006), where pressure, enthalpy and temperature conditions are better than in other parts of the field. However in the long term it will be necessary to incorporate Poligono Nuevo Leon into the productive area to expand the productive life of CGCP. This paper includes a geological analysis, plus models for steam production, temperature and enthalpy for Poligono Nuevo Leon. [Spanish] La parte oriental del Campo Geotermico de Cerro Prieto (CGCP), conocida como Poligono Nuevo Leon, representa una area potencial con recursos geotermicos comprobados, lo que demuestran siete pozos direccionales que se han perforado hacia el este, asi como el pozo vertical M-200, localizado dentro del poligono. El pozo M-200 se perforo en 1984 y ha producido a la fecha alrededor de 4 millones de toneladas de vapor, estando integrado al sector CP-2 una produccion de 68 t/h de vapor. Actualmente la parte oriental del CGCP, que representa el 25% del area total del campo, produce mas de la mitad del total de vapor del campo. El suministro de vapor en los ultimos anos se ha logrado cubrir aumentando el numero de pozos en operacion localizados en la zona oriente del CGCP (Rodriguez, 2006), ya que es aqui donde hay condiciones de presion, entalpia y temperatura del yacimiento que son mejores que en otras areas del campo

Soil mercury levels in the area surrounding the Cerro Prieto geothermal complex, MEXICO.

Science.gov (United States)

Pastrana-Corral, M A; Wakida, F T; García-Flores, E; Rodriguez-Mendivil, D D; Quiñonez-Plaza, A; Piñon-Colin, T D J

2016-08-01

Even though geothermal energy is a renewable energy source that is seen as cost-effective and environmentally friendly, emissions from geothermal plants can impact air, soil, and water in the vicinity of geothermal power plants. The Cerro Prieto geothermal complex is located 30 km southeast of the city of Mexicali in the Mexican state of Baja California. Its installed electricity generation capacity is 720 MW, being the largest geothermal complex in Mexico. The objective of this study was to evaluate whether the emissions generated by the geothermal complex have increased the soil mercury concentration in the surrounding areas. Fifty-four surface soil samples were collected from the perimeter up to an approximate distance of 7660 m from the complex. Additionally, four soil depth profiles were performed in the vicinity of the complex. Mercury concentration in 69 % of the samples was higher than the mercury concentration found at the baseline sites. The mercury concentration ranged from 0.01 to 0.26 mg/kg. Our results show that the activities of the geothermal complex have led to an accumulation of mercury in the soil of the surrounding area. More studies are needed to determine the risk to human health and the ecosystems in the study area.

Gaseous equilibrium in sector CP IV of the Cerro Prieto, B.C. Mexico geothermal field; Equilibrio gaseoso en el sector CP IV del campo geotermico Cerro Prieto, B.C., Mexico

Energy Technology Data Exchange (ETDEWEB)

Barragan Reyes, Rosa Maria; Arellano Gomez, Victor Manuel; Portugal Marin, Enrique [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); De Leon Vivar, Jesus [Comision Federal de Electricidad, Campo Geotermico Cerro Prieto, Cerro Prieto, B. C. (Mexico)

2007-07-01

Sector CP IV is located in the NE portion of the Cerrro Prieto geothermal field. The wells of this zone produce two-phase fluids, with different characteristics as far as their steam fraction content; in the central part and towards the NW the fluids are of dominant liquid type whereas towards the E and the S, the fluid contains a relatively higher steam fraction. The results of gaseous equilibrium FT- HSH3 showed that the fluids in the deposit are at temperatures between 275 Celsius degrees and 310 Celsius degrees and contain steam fractions between 0.01 and 0.5. The data found for the natural state are aligned in a tendency defined in the diagram FT- HSH3, that suggest the wells receive different proportions from preexisting steam in the deposit, which are mixed with the liquid phase to produce the observed discharges. The present data, besides showing the presence of deposit steam, also indicates the entrance of lower temperature fluid in the central part of sector CP IV. [Spanish] El sector CP IV se localiza en la porcion NE del campo geotermico Cerro Prieto. Los pozos de esta zona producen fluidos bifasicos, con diferentes caracteristicas en cuanto a su contenido de fraccion de vapor: en la parte central y hacia el NW los fluidos son de tipo liquido dominante mientras que hacia el E y hacia el S, el fluido contiene una fraccion relativamente alta de vapor. Los resultados de equilibrio gaseoso FT-HSH3 mostraron que los fluidos en el yacimiento se encuentran a temperaturas de entre 275 grados Celsius y 310 grados Celsius y contienen fracciones de vapor de entre -.01 y .5. Los datos hallados para el estado natural se alinean en una tendencia definida en el diagrama FT-HSH3, que sugiere que los pozos reciben diferentes proporciones de vapor pre-existente en el yacimiento, que se mezclan con fase liquida para producir las descargas que se observan. Los datos actuales, ademas de mostrar la presencia de vapor de yacimiento, tambien indican la entrada de fluidos de

A preliminary interpretation of gas composition in the CP IV sector wells, Cerro Prieto geothermal field, Mexico

Energy Technology Data Exchange (ETDEWEB)

Barragan Reyes, Rosa Maria; Arellano Gomez, Victor M; Portugal Marin, Enrique [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Morelos (Mexico)]. E-mail: rmb@iie.org.mx; Perez Hernandez, Alfredo; Rodriguez Rodriguez, Marco Helio; Leon Vivar, Jesus de [Comision Federal de Electricidad, Residencia General Cerro Prieto, B.C. (Mexico)

2007-07-15

To increase the electrical generation capacity of the Cerro Prieto geothermal field from 620 MW to 720 MW, the Cerro Prieto IV (CP IV) sector of the field was developed in the NE portion of the exploited field. Fourteen new wells have been drilled there since 2000. The wells in CP IV zone produce two-phase fluids at wellhead with heterogeneous steam fraction characteristics: at the central zone and towards the NW, the wells are liquid-dominated while those towards the E and S produce a relatively high steam fraction. This work studies the gas compositions of produced fluids to obtain reservoir parameters such as temperature and steam fraction and identify different sources of fluids in the wells. A method was used based on the Fischer Tropsch reaction and H{sub 2}S equilibria with pyrite-pyrrhotite as a mineral buffer (FT-HSH3). The results for the natural state showed the presence of fluids with reservoir temperatures from 275 to 310 degrees Celsius and excess steam values from -1 to 50%. Data are aligned in a FT-HSH3 trend, suggesting that the well discharges consist of a mixture in different proportions of the two end members. One seems to be a liquid with a temperature of over 300 degrees Celsius with negative or negligible excess steam. The other seems to be a two-phase fluid with a temperature of about 275 degrees Celsius and an excess steam fraction of about 0.5. According to the data for single wells and depending on the production conditions of the wells, reservoir fluid mixtures could occur in different proportions of liquid and steam. Data for 2005 that included wells drilled after 2000 suggest the presence of a steam phase in the reservoir. The steam could be generated with the boiling of deep reservoir fluid from a pressure drop. The mixing trend obtained for the natural state was also seen for 2005 data but lower temperatures (from 265 to 295 degrees Celsius) were obtained compared with those for natural conditions. The entry of lower

Calc-silicate mineralization in active geothermal systems

Energy Technology Data Exchange (ETDEWEB)

Bird, D.K.; Schiffman, P.; Elders, W.A.; Williams, A.E.; McDowell, S.D.

1983-01-01

The detailed study of calc-silicate mineral zones and coexisting phase relations in the Cerro Prieto geothermal system were used as examples for thermodynamic evaluation of phase relations among minerals of variable composition and to calculate the chemical characteristics of hydrothermal solutions compatible with the observed calc-silicate assemblages. In general there is a close correlation between calculated and observed fluid compositions. Calculated fugacities of O{sub 2} at about 320{degrees}C in the Cerro Prieto geothermal system are about five orders of magnitude less than that at the nearby Salton Sea geothermal system. This observation is consistent with the occurrence of Fe{sup 3+} rich epidotes in the latter system and the presence of prehnite at Cerro Prieto.

Heat losses estimation associated with the physical state of the thermal insulation of pipes vaporductos network in Cerro Prieto geothermal field; Estimacion de perdidas de calor asociadas al estado fisico del aislamiento termico de las tuberias de la red de vaporductos del campo geotermico Cerro Prieto

Energy Technology Data Exchange (ETDEWEB)

Ovando Castelar, Rosember; Martinez Estrella, Juan Ignacio; Garcia Gutierrez, Alfonso [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rovando@iie.org.mx; jime@iie.org.mx; aggarcia@iie.org.mx; Canchola Felix, Ismael; Miranda Herrera, Carlos; Jacobo Galvan, Paul [Campo Geotermico de Cerro Prieto, Comision Federal de Electricidad, Mexicali, B.C. (Mexico)

2010-11-15

The Cerro Prieto Geothermal Field (CPGF) steam transportation network is constituted by 140 km of pipes with diameters ranging from 8 to 48 inches, which transport the steam of 165 producing wells to 13 power plants which have a total installed capacity of 720 MWe. Originally, the pipes are thermally insulated with a mineral wool or fiber glass layer and an external aluminum or iron cover. Due to the insulation material has been exposed to weather conditions during the field operation it shows nowadays different grades of wear-out, or even it is lacking in some parts of the network, causing higher heat losses from the pipes to the environment. In this work, the magnitude of the heat losses related with the present condition of the thermal insulation throughout the pipeline network is assessed. This involved determining the longitude and diameter, as well as the insulation condition of each single pipeline section, and the calculation of the heat transfer coefficients for the different thermal insulation conditions defined for this study. [Spanish] La red de transporte de vapor del campo geotermico Cerro Prieto (CGCP) esta constituida por aproximadamente 140 km de tuberias de 8 a 48 pulgadas de diametro, las cuales conducen el vapor producido por 165 pozos hacia 13 plantas generadoras, cuya capacidad instalada es de 720 MWe. Originalmente, estas tuberias son aisladas termicamente con una capa de 2 pulgadas de material aislante a base de lana mineral o fibra de vidrio, y una proteccion exterior de aluminio o hierro. Debido principalmente al impacto de las condiciones meteorologicas durante el tiempo de operacion del campo, en algunas porciones de la red el aislante presenta actualmente distintos grados de deterioro, o incluso se encuentra ausente, lo cual se traduce en una mayor perdida de calor desde las tuberias hacia el medio ambiente. En el presente trabajo se evalua la magnitud de las perdidas de calor asociadas al estado fisico del aislamiento termico de las

Origin and evolution of geothermal fluids from Las Tres Vírgenes and Cerro Prieto fields, Mexico – Co-genetic volcanic activity and paleoclimatic constraints

International Nuclear Information System (INIS)

Birkle, Peter; Marín, Enrique Portugal; Pinti, Daniele L.; Castro, M. Clara

2016-01-01

during the final stage of the Last Glacial Pluvial period. Quaternary recharge of the LTV geothermal reservoir is related to elevated precipitation rates during cooler-humid climate intervals in the Late Pleistocene and Early Holocene. The probable replacement of connate water or pore fluids by infiltrating surface water might have been triggered by enhanced fracture and fault permeability through contemporaneous tectonic–volcanic activity in the Las Tres Vírgenes region. Fast hydrothermal alteration processes caused a secondary, positive δ 18 O-shift from 4‰ to 6‰ for LTV and from 2‰ to 4‰ for CP geothermal fluids since the Late Glacial infiltration. - Highlights: • U-Th/He ages for Cerro Prieto fluids show 4 He flux from granite basement or brines. • LTV geothermal water is composed of Quaternary meteoric water and fossil seawater. • 14 C and 4 He suggest Quaternary recharge of Las Tres Vírgenes geothermal reservoir. • Paleotemperatures point to cooler-humid climate in NW-Mexico during recharge.

Determination of heat losses in the Cerro Prieto, Baja California, geothermal field steam transportation network based on the thermal insulation condition of the steam pipelines; Determinacion de perdidas de calor en la red de transporte de vapor del campo geotermico de Cerro Prieto, Baja California, con base en el estado fisico del aislamiento termico de vaporductos

Energy Technology Data Exchange (ETDEWEB)

Ovando Castelar, Rosember; Garcia Gutierrez, Alfonso; Martinez Estrella, Juan Ignacio [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rovando@iie.org.mx; Canchola Felix, Ismael; Jacobo Galvan, Paul; Miranda Herrera, Carlos; Mora Perez, Othon [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia General de Cerro Prieto, Mexicali, B.C. (Mexico)

2011-07-15

In Cerro Prieto Geothermal Field (CPGF), the steam from producing wells is transported to power plants through a large and complex system of pipes thermally insulated with a 2 inches thick mineral wool or a fiber glass layer and an external aluminum or iron cover. The insulation material has been exposed to weather conditions during the field operation and has suffered density and thickness changes. In some cases the insulation has been lost completely, increasing heat transfer from the pipes to the environment. This paper analyzes the impact of the conditions of thermal insulation on heat losses in the CPGF steam-pipeline network. The heat losses are calculated by applying an iterative method to determine the surface temperature based on a heat balance calculated from the three basic mechanisms of heat transfer: conduction, convection, and radiation. Finally, using length and diameter data corresponding to the condition of the thermal insulation of each pipeline-and field operation data, the overall heat losses are quantified for steam lines throughout the pipeline network in the field. The results allow us to evaluate the magnitude of the heat losses in comparison with the overall energy losses occurring during steam transport from wells to the power plants. [Spanish] En el Campo Geotermico de Cerro Prieto (CGCP), BC, el transporte de vapor desde los pozos hasta las plantas generadoras de electricidad se lleva a cabo mediante un extenso y complejo sistema de tuberias que tipicamente se encuentran aisladas termicamente con una capa de 2 pulgadas de material aislante a base de lana mineral o fibra de vidrio, y una proteccion mecanica de aluminio o hierro galvanizado. Debido a la exposicion a las condiciones meteorologicas a traves del tiempo de operacion del campo, el aislamiento ha experimentado cambios en su densidad y espesor y en ocasiones se ha perdido por completo, lo cual repercute en una mayor transferencia de calor de las tuberias hacia el medio ambiente

Structure of the Wagner Basin in the Northern Gulf of California From Interpretation of Seismic Reflexion Data

Science.gov (United States)

Gonzalez, M.; Aguilar, C.; Martin, A.

2007-05-01

The northern Gulf of California straddles the transition in the style of deformation along the Pacific-North America plate boundary, from distributed deformation in the Upper Delfin and Wagner basins to localized dextral shear along the Cerro Prieto transform fault. Processing and interpretation of industry seismic data adquired by Petroleos Mexicanos (PEMEX) allow us to map the main fault structures and depocenters in the Wagner basin and to unravel the way strain is transferred northward into the Cerro Prieto fault system. Seismic data records from 0.5 to 5 TWTT. Data stacking and time-migration were performed using semblance coefficient method. Subsidence in the Wagner basin is controlled by two large N-S trending sub-parallel faults that intersect the NNW-trending Cerro Prieto transform fault. The Wagner fault bounds the eastern margin of the basin for more than 75 km. This fault dips ~50° to the west (up to 2 seconds) with distinctive reflectors displaced more than 1 km across the fault zone. The strata define a fanning pattern towards the Wagner fault. Northward the Wagner fault intersects the Cerro Prieto fault at 130° on map view and one depocenter of the Wagner basin bends to the NW adjacent to the Cerro Prieto fault zone. The eastern boundary of the modern depocenter is the Consag fault, which extends over 100 km in a N-S direction with an average dip of ~50° (up to 2s) to the east. The northern segment of the Consag fault bends 25° and intersects the Cerro Prieto fault zone at an angle of 110° on map view. The acoustic basement was not imaged in the northwest, but the stratigraphic succession increases its thickness towards the depocenter of the Wagner basin. Another important structure is El Chinero fault, which runs parallel to the Consag fault along 60 km and possibly intersects the Cerro Prieto fault to the north beneath the delta of the Colorado River. El Chinero fault dips at low-angle (~30°) to the east and has a vertical offset of about 0

The aggressiveness of the geothermal steam controlled; La agresividad del vapor geotermico controlada

Energy Technology Data Exchange (ETDEWEB)

Mercado, Sergio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1990-12-31

The first two units of Cerro Prieto have generated electric energy since 1973; in 1988 completed 15 years of continuous operation, without corrosion problems in the turbines in spite of the utilization of geothermal steam. The experience and the good results obtained during the first years of operation of these two units of 37.5 MW each, were of great help for the Cerro Prieto extension, having as of this date an installed capacity of 620 MW. [Espanol] Las dos primeras unidades de Cerro Prieto han generado energia electrica desde 1973; cumplieron 15 anos de operacion continua en 1988, sin problemas de corrosion en las turbinas a pesar del uso de vapor geotermico. La experiencia y los buenos resultados obtenidos durante los primeros anos de operacion de estas dos unidades de 37.5 MW cada una fueron de gran apoyo para la aplicacion de Cerro Prieto, teniendose a la fecha 620 MW de capacidad instalada.

The aggressiveness of the geothermal steam controlled; La agresividad del vapor geotermico controlada

Energy Technology Data Exchange (ETDEWEB)

Mercado, Sergio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1989-12-31

The first two units of Cerro Prieto have generated electric energy since 1973; in 1988 completed 15 years of continuous operation, without corrosion problems in the turbines in spite of the utilization of geothermal steam. The experience and the good results obtained during the first years of operation of these two units of 37.5 MW each, were of great help for the Cerro Prieto extension, having as of this date an installed capacity of 620 MW. [Espanol] Las dos primeras unidades de Cerro Prieto han generado energia electrica desde 1973; cumplieron 15 anos de operacion continua en 1988, sin problemas de corrosion en las turbinas a pesar del uso de vapor geotermico. La experiencia y los buenos resultados obtenidos durante los primeros anos de operacion de estas dos unidades de 37.5 MW cada una fueron de gran apoyo para la aplicacion de Cerro Prieto, teniendose a la fecha 620 MW de capacidad instalada.

Micas at magmatic and hydrothermal stages in the environment of the Cerro Verde Santa Rosa porphyry copper type deposit

Energy Technology Data Exchange (ETDEWEB)

Le Bel, L

1979-01-01

The chemical composition of biotites and sericites from the Cerro Verde porphyry copper type deposit have been investigated in detail, using an electron microprobe. The main results of the study are: Al/sup vi/ and Ti contents of biotites of magmatic as well as hydrothermal origin may be related to the temperature of crystallization estimed by independent methods. On the other hand the Mg/Fe and Mg/(Mg + Fe) ratios are almost constant. This fact is interpreted in terms of fO/sub 2/; sericites have a phengitic composition in which the solubilities of the two end-members celadonite and paragonite are controlled by a fluid phase under P, T conditions that could be estimated.

Operation and Performance of a Biphase Turbine Power Plant at the Cerro Prieto Geothermal Field (Final Report)

Energy Technology Data Exchange (ETDEWEB)

Hays, Lance G. [Douglas Energy Company, Placentia, CA (United States)

2000-09-01

A full scale, wellhead Biphase turbine was manufactured and installed with the balance of plant at Well 103 of the Cerro Prieto geothermal resource in Baja, California. The Biphase turbine was first synchronized with the electrical grid of Comision Federal de Electricidad on August 20, 1997. The Biphase power plant was operated from that time until May 23, 2000, a period of 2 years and 9 months. A total of 77,549 kWh were delivered to the grid. The power plant was subsequently placed in a standby condition pending replacement of the rotor with a newly designed, higher power rotor and replacement of the bearings and seals. The maximum measured power output of the Biphase turbine, 808 kWe at 640 psig wellhead pressure, agreed closely with the predicted output, 840 kWe. When combined with the backpressure steam turbine the total output power from that flow would be increased by 40% above the power derived only from the flow by the present flash steam plant. The design relations used to predict performance and design the turbine were verified by these tests. The performance and durability of the Biphase turbine support the conclusion of the Economics and Application Report previously published, (Appendix A). The newly designed rotor (the Dual Pressure Rotor) was analyzed for the above power condition. The Dual Pressure Rotor would increase the power output to 2064 kWe by incorporating two pressure letdown stages in the Biphase rotor, eliminating the requirement for a backpressure steam turbine. The power plant availability was low due to deposition of solids from the well on the Biphase rotor and balance of plant problems. A great deal of plant down time resulted from the requirement to develop methods to handle the solids and from testing the apparatus in the Biphase turbine. Finally an online, washing method using the high pressure two-phase flow was developed which completely eliminated the solids problem. The availability of the Biphase turbine itself was 100

Geophysical characterization of subaerial hydrothermal manifestations in Punta Banda, Baja California, Mexico.

Science.gov (United States)

Flores-Marquez, L.; Prol-Ledesma, R. M.; Arango, C.; Canet, C.

2009-04-01

Important growth of population in Baja California Peninsula has triggered the need for energy and fresh water. The most sustainable possibility for increasing the availability of fresh water is the use of renewable energy sources in desalination plants. The abundance of geothermal manifestations in the peninsula provides a reliable energy source for desalination purposes. Geothermal development of the Baja California Peninsula dates from the 70's, when the Cerro Prieto geothermal field started producing electricity. Two important cities, Tijuana and Ensenada, are located in the north-western area of Baja California. The city of Ensenada has a desalination plant that is due to be replaced and the geothermal resources of the area could be an option for the new desalination plant. Punta Banda, a region near Ensenada, was specially investigated to determine its geothermal potential. Subaerial springs and the submarine vents were sampled and studied in this work, also geological and geochemical studies were performed, moreover geoelectrical surveys were accomplished to characterize the hydrothermal system at depth. Even though saline intrusion is a severe problem in Ensenada (TDS higher than 3000), thermal springs away from the coast and coastal springs have salinities lower than sea water. According to the geoelectrical models obtained from profiles, the inferred conductive features can be related to thermal anomalies. The existence of hot springs located along a trend suggests that the dynamic of the thermal fluid is restricted by secondary faults.

Evaluation of a process for the removal of gases contained in geothermal steam through condensation and re-evaporation; Evaluacion de un proceso de remocion de gases contenidos en el vapor geotermico, por medio de la condensacion y de revaporacion

Energy Technology Data Exchange (ETDEWEB)

Angulo C, Raul; Lam Rea, Luis; Garmino, Hector; Jimenez, Humberto [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1986-12-31

The Cerro Prieto I Geothermal Field, developed and operated by the Comision Federal de Electricidad (CFE), has currently an installed electric power generation capacity of 180 MW and is at a very advanced stage in the development of Cerro Prieto II and III, which will allow to raise the generation capacity to 620 MW. During the exploitation of a geothermal field, in producing steam with the purpose of generating electricity, brines and waste gases are obtained. The hydrogen sulfide exhaust to the environment implies pollution problems, for this reason processes have been developed for the oxidation of these gases downstream the turbogenerator either in the flow of separated gases in the steam condensation or in the condensate produced. The Instituto de Investigaciones Electricas (IIE) has collaborated with CFE in the evaluation of the environmental impact of this gas and in the development of the processes for its abatement. [Espanol] El campo geotermico de Cerro Prieto I, desarrollado y operado por la Comision Federal de Electricidad (CFE), actualmente tiene una capacidad instalada de generacion de energia electrica de 180 MW, y se encuentra en etapa muy avanzada, el desarrollo de Cerro Prieto II y III, lo que permitira incrementar la capacidad de generacion a 620 MW. Durante la explotacion de un campo geotermico, al producir vapor con el proposito de generar electricidad, se obtienen salmueras y gases de desecho. La descarga de acido sulfhidrico a la atmosfera implica problemas de contaminacion, por esta razon se han desarrollado procesos para la oxidacion de este gas aguas abajo de la turbina generadora, ya sea en la corriente de gases que se separan en la condensacion del vapor o en el condensado producido. El Instituto de Investigaciones Electricas (IIE) ha colaborado con la CFE en la evaluacion del impacto ambiental de este gas y en el desarrollo de sus procesos de abatimiento.

Evaluation of a process for the removal of gases contained in geothermal steam through condensation and re-evaporation; Evaluacion de un proceso de remocion de gases contenidos en el vapor geotermico, por medio de la condensacion y de revaporacion

Energy Technology Data Exchange (ETDEWEB)

Angulo C, Raul; Lam Rea, Luis; Garmino, Hector; Jimenez, Humberto [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1985-12-31

The Cerro Prieto I Geothermal Field, developed and operated by the Comision Federal de Electricidad (CFE), has currently an installed electric power generation capacity of 180 MW and is at a very advanced stage in the development of Cerro Prieto II and III, which will allow to raise the generation capacity to 620 MW. During the exploitation of a geothermal field, in producing steam with the purpose of generating electricity, brines and waste gases are obtained. The hydrogen sulfide exhaust to the environment implies pollution problems, for this reason processes have been developed for the oxidation of these gases downstream the turbogenerator either in the flow of separated gases in the steam condensation or in the condensate produced. The Instituto de Investigaciones Electricas (IIE) has collaborated with CFE in the evaluation of the environmental impact of this gas and in the development of the processes for its abatement. [Espanol] El campo geotermico de Cerro Prieto I, desarrollado y operado por la Comision Federal de Electricidad (CFE), actualmente tiene una capacidad instalada de generacion de energia electrica de 180 MW, y se encuentra en etapa muy avanzada, el desarrollo de Cerro Prieto II y III, lo que permitira incrementar la capacidad de generacion a 620 MW. Durante la explotacion de un campo geotermico, al producir vapor con el proposito de generar electricidad, se obtienen salmueras y gases de desecho. La descarga de acido sulfhidrico a la atmosfera implica problemas de contaminacion, por esta razon se han desarrollado procesos para la oxidacion de este gas aguas abajo de la turbina generadora, ya sea en la corriente de gases que se separan en la condensacion del vapor o en el condensado producido. El Instituto de Investigaciones Electricas (IIE) ha colaborado con la CFE en la evaluacion del impacto ambiental de este gas y en el desarrollo de sus procesos de abatimiento.

The age and thermal history of Cerro Rico de Potosi, Bolivia

Science.gov (United States)

Cunningham, C.G.; Zartman, R.E.; McKee, E.H.; Rye, R.O.; Naeser, C.W.; Sanjines, V.O.; Ericksen, G.E.; Tavera, V.F.

1996-01-01

Cerro Rico de Potosi, Bolivia, is the world's largest silver deposit and has been mined since the sixteenth century for silver, and for tin and zinc during the twentieth century, together with by-product copper and lead. The deposit consists primarily of veins that cut an altered igneous body that we interpret to be a dacitic volcanic dome and its underlying tuff ring and explosion breccia. The deposit is compositionally and thermally zoned, having a core of cassiterite, wolframite, bismuthinite, and arsenopyrite surrounded by a peripheral, lower-temperature mineral assemblage consisting principally of sphalerite, galena, lead sulfosalt, and silver minerals. The low-temperature assemblage also was superim-posed on the high-temperature assemblage in response to cooling of the main hydrothermal system. Both the dacite dome and the ore fluids were derived from a larger magmatic hydrothermal source at depth. The dome was repeatedly fractured by recurrent movement on the fault system that guided its initial emplacement. The dome was extruded at 13.8 ?? 0.2 Ma (2??), based on U-Th-Pb dating of zircon. Mineralization and alteration occurred within about 0.3 my of dome emplacement, as indicated by a 40Ar/39Ar date of 13.76 ?? 0.10 Ma (1??) for sericite from the pervasive quartz-sericite-pyrite alteration associated with the main-stage, high-temperature, mineralization. The last thermal event able to reset zircon fission tracks occurred no later than 12.5 ?? 1.1 Ma (1??). as indicated by fission-tract dating. Minor sericite. and magmatic-steam alunite veins, were episodically formed around 11 Ma and between 8.3 and 5.7 Ma; the younger episodes occurring at the time of extensional fracturing at Cerro Rico and widespread volcanism in the adjacent Los Frailes volcanic field. None of these younger events appear to be signific-ant thermal/mineralizing events: the exceptionally flat thermal release pattern of 39Ar from sericite and the results of the fission-tract dating of

Cerro Largo South orientation

International Nuclear Information System (INIS)

Pradier, B.

1982-01-01

This work is about Cerro Largo South orientation. The site is located in the northeast of Uruguay in the south of Melo city, Department of Cerro Largo. The study was carried out in the young edge socket in the East side of a small valley. This metamorphic socket constituted by gneisses and crystalline limestone are in contact with upper carboniferous formations and basal deposits composed by sandstones and conglomerates

Imperial County geothermal development annual meeting: summary

Energy Technology Data Exchange (ETDEWEB)

1983-01-01

All phases of current geothermal development in Imperial County are discussed and future plans for development are reviewed. Topics covered include: Heber status update, Heber binary project, direct geothermal use for high-fructose corn sweetener production, update on county planning activities, Brawley and Salton Sea facility status, status of Imperial County projects, status of South Brawley Prospect 1983, Niland geothermal energy program, recent and pending changes in federal procedures/organizations, plant indicators of geothermal fluid on East Mesa, state lands activities in Imperial County, environmental interests in Imperial County, offshore exploration, strategic metals in geothermal fluids rebuilding of East Mesa Power Plant, direct use geothermal potential for Calipatria industrial Park, the Audubon Society case, status report of the Cerro Prieto geothermal field, East Brawley Prospect, and precision gravity survey at Heber and Cerro Prieto geothermal fields. (MHR)

Geophysical Investigations of Magma Plumbing Systems at Cerro Negro Volcano, Nicaragua

Science.gov (United States)

MacQueen, Patricia Grace

Cerro Negro near Leon, Nicaragua is a very young (163 years), relatively small basaltic cinder cone volcano that has been unusually active during its short lifespan (recurrence interval 6--7 years), presenting a significant hazard to nearby communities. Previous studies have raised several questions as to the proper classification of Cerro Negro and its relation to neighboring Las Pilas-El Hoyo volcano. Analysis of Bouguer gravity data collected at Cerro Negro has revealed connected positive density anomalies beneath Cerro Negro and Las Pilas-El Hoyo. These findings suggest that eruptions at Cerro Negro may be tapping a large magma reservoir beneath Las Pilas-El Hoyo, implying that Cerro Negro should be considered the newest vent on the Las Pilas-El Hoyo volcanic complex. As such, it is possible that the intensity of volcanic hazards at Cerro Negro may eventually increase in the future to resemble those pertaining to a stratovolcano. Keywords: Cerro Negro; Las Pilas-El Hoyo; Bouguer gravity; magmatic plumbing systems; potential fields; volcano.

Update of Geothermics in Mexico

Energy Technology Data Exchange (ETDEWEB)

Gutierrez Negrin, Luis C.A.; Quijano Leon, Jose Luis [Comision Federal de Electricidad, Morelia, Michoacan (Mexico)

2004-12-01

Four geothermal fields are currently operating in Mexico (Cerro Prieto, Los Azufres, Los Humeros and Las Tres Virgenes), with a total installed geothermal-electric capacity of 953 megawatts (MW). This means the country is located in third place, worldwide, just behind the USA and Philippines. Thirty-six power plants of several types (condensing, back pressure and binary cycle), between 1.5 and 110 MW, operate in the fields, fed by 197 wells with a combined production of 7,700 metric tons of steam per hour (t/h). These production wells have depths between 600 and 4,400 meters. Steam comes with 8,750 t/h of brine that is injected through 19 injection wells or treated in a solar evaporation pond of 14 km2 in Cerro Prieto. During 2003, steam produced in those fields equaled 67.5 million metric tons, and the power plants generated 6,282 gigawatt-hours (GWh), which represented 3.1% of the electric energy produced in Mexico. All the power plants and the geothermal fields are operated bye the public utility, the Comision Federal de Electricidad (Comision Federal de Electricidad (CFE)). [Spanish] Actualmente se operan en Mexico cuatro campos geotermicos (Cerro Prieto, Los Azufres, Los Humeros y Las Tres Virgenes), con una capacidad geotermoelectrica total de 953 megawatts (MW). Esto coloca al pais en el tercer lugar mundial, detras de Estados Unidos y Filipinas. En esos campos operan treinta y seis unidades de tipos diversos (a condensacion, a contrapresion y de ciclo binario), entre 1.5 y 110 MW, alimentadas por 197 pozos con una produccion combinada de 7,700 toneladas de vapor por hora (t/h). Estos pozos productores tienen profundidades entre 600 y 4,400 metros. El vapor sale acompanado por 8,750 t/h de salmuera, que se inyecta en 19 pozos inyectores o se trata en una laguna de evaporacion solar de 14 km2 en Cerro Prieto. Durante 2003 el vapor producido en los campos sumo 67.5 millones de toneladas y las unidades generaron 6,282 gigawatts-hora (GWh), lo que represento el

Research on heat pumps in Mexico operating with geothermal energy and waste heat; Investigacion sobre bombas de calor en Mexico operando con energia geotermica y calor de desecho

Energy Technology Data Exchange (ETDEWEB)

Garcia-Gutierrez, A; Barragan-Reyes, R.M; Arellano-Gomez, V [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: aggarcia@iie.org.mx

2008-01-15

The Instituto de Investigaciones Electricas and the Comision Federal de Electricidad have done research and development (R&D) on heat pumps (HP) in past years. Tested systems include mechanical compression, absorption and heat-transformers. The main R&D aspects on HP are briefly described, and also a more detailed description about three of the main studies is presented: (a) a mechanical compression HP of the water-water type operated with low-pressure geothermal steam at the Los Azufres; Mich., geothermal field, and designed for purification of brine; (b) an absorption HP for cooling and refrigeration operating with ammonia-water and low-enthalpy geothermal energy, which was tested in the Los Azufres and Cerro Prieto, BC, geothermal fields; and (c) a heat-transformer by absorption-Absorption Heat Pump Type II-tested to assess the performance of several ternary solutions as work fluids. Plans exist to install and test a geothermal heat pump at Cerro Prieto or Mexicali, BC. [Spanish] El Instituto de Investigaciones Electricas y la Comision Federal de Electricidad han realizado trabajo de investigacion y desarrollo (I&D) sobre bombas de calor (BC) en el pasado. Los sistemas probados incluyen compresion mecanica, absorcion y transformadores termicos. Este trabajo describe brevemente los principales aspectos de I&D sobre bombas de calor en forma general, y se da una descripcion mas detallada de tres de los principales estudios: (a) una BC por compresion mecanica tipo agua-agua disenada para purificacion de salmueras operando con vapor geotermico de baja presion en el campo geotermico de Los Azufres, Mich.; (b) una BC por absorcion para enfriamiento y refrigeracion operando con amoniaco-agua y energia geotermica de baja entalpia, la cual fue probada en los campos geotermicos de Los Azufres y Cerro Prieto, BC; y (c) un transformador termico por absorcion -llamado Bomba de Calor por Absorcion Tipo II--, el cual fue probado para evaluar el comportamiento de diversas

First evidence of lamprophyric magmatism within the Subbetic Zone (Southern Spain)

NARCIS (Netherlands)

Puga, E.; Beccaluva, L.; Bianchini, G.; De Federico, A.D.; Puga, M.A.D.; Alvarez-Valero, A.M.; Galindo-Zaldivar, J.; Wijbrans, J.R.

2010-01-01

Two drillings carried out at Cerro Prieto (Province of Málaga), together with additional geophysical data, revealed the existence of an igneous body formed of rock-types previously unknown in the Subbetic zone. The recovered rocks, emplaced under hypoabyssal conditions, are predominantly porphyric,

Simulator of a geotermoelectric unit for the training of operators; Simulador de una unidad geotermoelectrica para entrenamiento de operadores

Energy Technology Data Exchange (ETDEWEB)

Tavira Mondragon, Jose Antonio; Lopez Aguilera, Diana Monica; Roldan Villasana, Edgardo Javier; Rodriguez Lozano, Saul [Instituto de Investigaciones Electricas, Temixco, Morelos (Mexico)

1999-07-01

The use of simulators replica in real time for operators training has demonstrated to be one of the best forms to enable the personnel of the Comision Federal de Electricidad (CFE). This article shows the basic characteristics of a simulator replica of the Cerro Prieto geotermoelectric power station of Baja California. It is expected that with this simulator 400 people between operators, shift superintendents and operation and maintenance auxiliary personnel become qualified. [Spanish] El uso de simuladores replica en tiempo real para entrenamiento de operadores de centrales generadoras ha demostrado ser una de las mejores formas de capacitar al personal de la Comision Federal de Electricidad (CFE). Este articulo muestra las caracteristicas principales de un simulador replica de la central geotermoelectrica de Cerro Prieto Baja California. Se espera que con este simulador se capaciten 400 personas entre operadores, superintendentes de turno y auxiliares de operacion y mantenimiento.

Seismicity and arrival-time residuals from the Victoria Earthquake of June 9, 1980

Energy Technology Data Exchange (ETDEWEB)

Wong, V.; Frez, J.

1981-01-01

Hypocenter distribution in space and time of the aftershock activity from the Victoria Earthquake of June 9, 1980 was studied. It was concluded that the main event excited aftershocks in several pre-existing nests at the northwest end of the Cerro Prieto Fault, but no significant activity occurred at the immediate neighborhood of the main event. The depth of the aftershocks increases with the distance from the northwest end of the fault and this feature might be related with the higher temperatures and the spreading center located between the ends of the Imperial and Cerro Prieto Faults. The significance of the arrival-times residuals for local and regional stations is discussed both for P and S-waves and the importance of obtaining station corrections is emphasized. The non-uniqueness in determining a structure which minimizes the residuals is illustrated. Two different structures which satisfy the local data are presented.

Cerro Prieto geothermal field: exploration during exploitation

Energy Technology Data Exchange (ETDEWEB)

1982-07-01

Geological investigations at Momotombo included photogeology, field mapping, binocular microscope examination of cuttings, and drillhole correlations. Among the geophysical techniques used to investigate the field sub-structure were: Schlumberger and electromagnetic soundings, dipole mapping and audio-magnetotelluric surveys, gravity and magnetic measurements, frequency domain soundings, self-potential surveys, and subsurface temperature determinations. The geochemical program analyzed the thermal fluids of the surface and in the wells. The description and results of exploration methods used during the investigative stages of the Momotombo Geothermal Field are presented. A conceptual model of the geothermal field was drawn from the information available at each exploration phase. The exploration methods have been evaluated with respect to their contributions to the understanding of the field and their utilization in planning further development.

Photosynthesis within Mars' volcanic craters?: Insights from Cerro Negro Volcano, Nicaragua

Science.gov (United States)

Rogers, K. L.; Hynek, B. M.; McCollom, T. M.

2011-12-01

Discrete locales of sulfate-rich bedrocks exist on Mars and in many cases represent the products of acid-sulfate alteration of martian basalt. In some places, the products have been attributed to hydrothermal processes from local volcanism. In order to evaluate the habitability of such an environment, we are investigating the geochemical and biological composition of active fumaroles at Cerro Negro Volcano, Nicaragua, where fresh basaltic cinders similar in composition to martian basalts are altered by acidic, sulfur-bearing gases. Temperatures at active fumaroles can reach as high as 400°C and the pH of the steam ranges from Cyanobacteria and Ktedonobacteria, however Actinobacteria, alpha-Proteobacteria and Acidobacteria were also identified. Many of the cyanobacterial sequences were similar to those of the eukaryotic Cyanidiales, red algae that inhabit acidic, geothermal environments. Many of sequences related to Ktedonobacteria and Actinobacteria have also been found in acid mine drainage environments. The Archaeal community was far less diverse, with sequences matching those of unclassified Desulfurococcales and unclassified Thermoprotei. These sequences were more distant from isolated species than the bacterial sequences. Similar bacterial and archaeal communities have been found in hot spring environments in Yellowstone National Park, Greenland, Iceland, New Zealand and Costa Rica. Some of Mars' volcanoes were active for billions of years and by analogy to Cerro Negro, may have hosted photosynthetic organisms that could have been preserved in alteration mineral assemblages. Even on a generally cold and dry Mars, volcanic craters likely provided long-lived warm and wet conditions and should be a key target for future exploration assessing habitability.

Research and technological development on heat pumps in Mexico operating with geothermal energy; Investigacion y desarrollo tecnologico sobre bombas de calor en Mexico operando con energia geotermica

Energy Technology Data Exchange (ETDEWEB)

Garcia Gutierrez, Alfonso; Barragan Reyes, Rosa Maria; Arellano Gomez, Victor Manuel [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

2008-07-01

The Instituto de Investigaciones Electricas (IIE) and the Comision Federal de Electricidad (CFE) carried out in the past an extensive work of research and development (R&D) on heat pumps (HP). The systems tried on include heat pumps by mechanical compression, thermal absorption and thermal transformers. This paper briefly describes the main aspects of R&D on heat pumps and presents a more detailed description of three of the main studies: a) a Heat Pump (HP) by mechanical compression water-water type, designed for brine purification, operating with low pressure geothermal steam at the geothermal field Los Azufres, Michoacan, Mexico; b) a HP by absorption for cooling and refrigeration, operating with ammoniac/water and low enthalpy geothermal energy, which was tested in the geothermal fields of Los Azufres, Michoacan and Cerro Prieto, Baja California, and c) a thermal transformer by absorption, named Heat Pump by Absorption Type 2, which was tested to evaluate the behavior of diverse ternary solutions as working fluids. To date, there are plans to install and test a geothermal heat pump (connected to the subsoil), in Cerro Prieto, Mexicali, Baja California, Mexico. [Spanish] El Instituto de Investigaciones Electricas (IIE) y la Comision Federal de Electricidad (CFE) realizaron un trabajo extenso de investigacion y desarrollo (I&D) sobre bombas de calor (BC) en el pasado. Los sistemas que se probaron incluyen bombas de calor por compresion mecanica, absorcion y transformadores termicos. Este trabajo describe brevemente los principales aspectos de I&D sobre bombas de calor y se da una descripcion mas detallada de tres de los principales estudios: a) una Bomba de Calor (BC) por compresion mecanica tipo agua-agua, disenada para purificacion de salmueras, operando con vapor geotermico de baja presion en el campo geotermico de Los Azufres, Michoacan; b) una BC por absorcion para enfriamiento y refrigeracion, operando con amoniaco/agua y energia geotermica de baja entalpia

Geophysical investigations of magma plumbing systems at Cerro Negro volcano, Nicaragua

OpenAIRE

MacQueen, Patricia Grace

2013-01-01

Cerro Negro near Léon, Nicaragua is a very young (163 years), relatively small basaltic cinder cone volcano that has been unusually active during its short lifespan (recurrence interval 6-7 years), presenting a significant hazard to nearby communities. Previous studies have raised several questions as to the proper classification of Cerro Negro and its relation to neighboring Las Pilas-El Hoyo volcano. Analysis of Bouguer gravity data collected at Cerro Negro has revealed connected positive d...

Magnetotelluric studies at the Cerro Prieto geothermal field

Energy Technology Data Exchange (ETDEWEB)

Goubau, W.M. (Lawrence Berkeley Lab., CA); Goldstein, N.E.; Clarke, J.

1981-01-01

During three years of magnetotelluric surveying, data were acquired at 26 sites distributed over 190 km/sup 2/ around the production area. A relatively well-defined strike of N27W +- 1.5/sup 0/ (magnetic) was established. The simple model shown suggests a lateral discontinuity in the vicinity of Nueva Leon.

Drilling rate for the Cerro Prieto stratigraphic sequence

Energy Technology Data Exchange (ETDEWEB)

Prian C, R.

1981-01-01

Drilling practice at the field has been modified in several ways as better information is being obtained. The stratigraphic sequence of the area is made up of three sedimentary rock units of deltaic origin having different densities. These units have been named non-consolidated, semi-consolidated, and consolidated rocks; the thermal reservoirs are located in the latter. To investigate how the drilling rates are affected by the three rock units, plots of drilling advance versus time were made for a large number of wells. A typical plot is shown and drilling rates are practically constant in three different zones; that is, the drilling rate has only two breaks or changes in slope.

Uruguay mining Inventory: geochemical prospecting results of Cerro de las Cuentas mapping

International Nuclear Information System (INIS)

Spangenberg, J.; Filippini, J.

1986-01-01

This work is about the geochemical prospecting carried out into the Uruguay mining inventory framework. In this case the survey was in Cerro de las Cuentas mapping. Cerro Largo department. Scale 1 / 50000.

Cerro Baúl: un enclave wari en interacción con Tiwanaku

OpenAIRE

Williams, Patrick Ryan; Isla, Johny A.; Nash, Donna J.

2012-01-01

Cerro Baul: A Wari Enclave Interacting with TiwanakuWari expansion to the extreme south of Peru is a phenomenon whose study began 20 years ago, with the discovery of a great arquitectonic complex at Cerro Baul. The excavations undertaken in the last 3 years have revealed that Cerro Baul was more than a military fortress; it was the most important political and religious center that Wari established in the only region where there is direct evidence of interaction with Tiwanaku, the altiplano s...

Refined localization of the Prieto-syndrome locus

Energy Technology Data Exchange (ETDEWEB)

Martinez, F.; Prieto, F. [Unidad de Genetica, Valencia (Spain); Gal, A. [Universitaets-Krankenhaus Eppendorf, Hamburg (Germany)

1996-07-12

PRS designates the locus for a syndromal form of X-linked mental retardation (Prieto syndrome) characterized by minor facial anomalies, ear malformation, abnormal growth of teeth, clinodactyly, sacral dimple, patellar luxation, malformation of lower limbs, abnormalities of the fundus of the eye, and subcortical cerebral atrophy. Linkage analysis localized the disease locus between DXS84 (Xp21.1) and DXS255. Here we present additional linkage data that provide further support and refinement of this localization. Individual III-18 gave birth to a male, currently aged 2 7/12 years, who clearly shows delayed psychomotor development. He began to walk at 23 months and his speech is delayed. In addition, he shows the characteristic facial anomalies, {open_quotes}dysplastic{close_quotes} ears, sacral dimple, and clinodactyly, as do all other affected males in this family. 7 refs., 1 tab.

Connected magma plumbing system between Cerro Negro and El Hoyo Complex, Nicaragua revealed by gravity survey

Science.gov (United States)

MacQueen, Patricia; Zurek, Jeffrey; Williams-Jones, Glyn

2016-11-01

Cerro Negro, near León, Nicaragua is a young, relatively small basaltic cinder cone volcano that has been unusually active during its short lifespan. Multiple explosive eruptions have deposited significant amounts of ash on León and the surrounding rural communities. While a number of studies investigate the geochemistry and stress regime of the volcano, subsurface structures have only been studied by diffuse soil gas surveys. These studies have raised several questions as to the proper classification of Cerro Negro and its relation to neighboring volcanic features. To address these questions, we collected 119 gravity measurements around Cerro Negro volcano in an attempt to delineate deep structures at the volcano. The resulting complete Bouguer anomaly map revealed local positive gravity anomalies (wavelength 0.5 to 2 km, magnitude +4 mGal) and regional positive (10 km wavelength, magnitudes +10 and +8 mGal) and negative (12 and 6 km wavelength, magnitudes -18 and -13 mGal) Bouguer anomalies. Further analysis of these gravity data through inversion has revealed both local and regional density anomalies that we interpret as intrusive complexes at Cerro Negro and in the Nicaraguan Volcanic Arc. The local density anomalies at Cerro Negro have a density of 2700 kg m-3 (basalt) and are located between -250 and -2000 m above sea level. The distribution of recovered density anomalies suggests that eruptions at Cerro Negro may be tapping an interconnected magma plumbing system beneath El Hoyo, Cerro La Mula, and Cerro Negro, and more than seven other proximal volcanic features, implying that Cerro Negro should be considered the newest cone of a Cerro Negro-El Hoyo volcanic complex.

Mineralized breccia clasts: a window into hidden porphyry-type mineralization underlying the epithermal polymetallic deposit of Cerro de Pasco (Peru)

Science.gov (United States)

Rottier, Bertrand; Kouzmanov, Kalin; Casanova, Vincent; Bouvier, Anne-Sophie; Baumgartner, Lukas P.; Wälle, Markus; Fontboté, Lluís

2018-01-01

Cerro de Pasco (Peru) is known for its large epithermal polymetallic (Zn-Pb-Ag-Cu-Bi) mineralization emplaced at shallow level, a few hundred meters below the paleo-surface, at the border of a large diatreme-dome complex. Porphyry-style veins crosscutting hornfels and magmatic rock clasts are found in the diatreme breccia and in quartz-monzonite porphyry dikes. Such mineralized veins in clasts allow investigation of high-temperature porphyry-style mineralization developed in the deep portions of magmatic-hydrothermal systems. Quartz in porphyry-style veins contains silicate melt inclusions as well as fluid and solid mineral inclusions. Two types of high-temperature (> 600 °C) quartz-molybdenite-(chalcopyrite)-(pyrite) veins are found in the clasts. Early, thin (1-2 mm), and sinuous HT1 veins are crosscut by slightly thicker (up to 2 cm) and more regular HT2 veins. The HT1 vein quartz hosts CO2- and sulfur-rich high-density vapor inclusions. Two subtypes of the HT1 veins have been defined, based on the nature of mineral inclusions hosted in quartz: (i) HT1bt veins with inclusions of K-feldspar, biotite, rutile, and minor titanite and (ii) HT1px veins with inclusions of actinolite, augite, titanite, apatite, and minor rutile. Using an emplacement depth of the veins of between 2 and 3 km (500 to 800 bar), derived from the diatreme breccia architecture and the supposed erosion preceding the diatreme formation, multiple mineral thermobarometers are applied. The data indicate that HT1 veins were formed at temperatures > 700 °C. HT2 veins host assemblages of polyphase brine inclusions, generally coexisting with low-density vapor-rich inclusions, trapped at temperatures around 600 °C. Rhyolitic silicate melt inclusions found in both HT1 and HT2 veins represent melt droplets transported by the ascending hydrothermal fluids. LA-ICP-MS analyses reveal a chemical evolution coherent with the crystallization of an evolved rhyolitic melt. Quartz from both HT1 and HT2 veins

Geology and geochemistry of Pelagatos, Cerro del Agua, and Dos Cerros monogenetic volcanoes in the Sierra Chichinautzin Volcanic Field, south of México City

Science.gov (United States)

Agustín-Flores, Javier; Siebe, Claus; Guilbaud, Marie-Noëlle

2011-04-01

This study focuses on the geology and geochemistry of three closely-spaced monogenetic volcanoes that are located in the NE sector of the Sierra Chichinautzin Volcanic Field near México City. Pelagatos (3020 m.a.s.l.) is a small scoria cone (0.0017 km 3) with lava flows (0.036 km 3) that covered an area of 4.9 km 2. Cerro del Agua scoria cone (3480 m.a.s.l., 0.028 km 3) produced several lava flows (0.24 km 3) covering an area of 17.6 km 2. Dos Cerros is a lava shield which covers an area of 80.3 km 2 and is crowned by two scoria cones: Tezpomayo (3080 m.a.s.l., 0.022 km 3) and La Ninfa (3000 m.a.s.l., 0.032 km 3). The eruptions of Cerro del Agua and Pelagatos occurred between 2500 and 14,000 yr BP. The Dos Cerros eruption took place close to 14,000 yr BP as constrained by radiocarbon dating. Rocks from these three volcanoes are olivine-hypersthene normative basaltic andesites and andesites with porphyritic, aphanitic, and glomeroporphyritic textures. Their mineral assemblages include olivine, clinopyroxene, and orthopyroxene phenocrysts (≤ 10 vol.%) embedded in a trachytic groundmass which consists mainly of plagioclase microlites and glass. Pelagatos rocks also present quartz xenocrysts. Due to their high Cr and Ni contents, and high Mg#s, Pelagatos rocks are considered to be derived from primitive magmas, hence the importance of this volcano for understanding petrogenetic processes in this region. Major and trace element abundances and petrography of products from these volcanoes indicate a certain degree of crystal fractionation during ascent to the surface. However, the magmas that formed the volcanoes evolved independently from each other and are not cogenetically related. REE, HFSE, LILE, and isotopic (Sr, Nd, and Pb) compositions point towards a heterogeneous mantle source that has been metasomatized by aqueous/melt phases from the subducted Cocos slab. There is no clear evidence of important crustal contributions in the compositions of Pelagatos and

Optical atmospheric extinction over Cerro Paranal

NARCIS (Netherlands)

Patat, F.; Moehler, S.; O'Brien, K.; Pompei, E.; Bensby, T.; Carraro, G.; de Ugarte Postigo, A.; Fox, A.; Gavignaud, I.; James, G.; Korhonen, H.; Ledoux, C.; Randall, S.; Sana, H.A.A.; Smoker, J.; Stefl, S.; Szeifert, T.

2011-01-01

Aims. The present study was conducted to determine the optical extinction curve for Cerro Paranal under typical clear-sky observing conditions, with the purpose of providing the community with a function to be used to correct the observed spectra, with an accuracy of 0.01 mag airmass-1.

Geological map of Uruguay Esc 1,100,000. Cerro Partido Sheet F-24

International Nuclear Information System (INIS)

Diaz, R; Albanell, H.; Bossi, J.

1990-01-01

This work is about the geological map of Uruguay Esc.1.100.000 (Cerro Partido) and the explanatory memoranda which describes the geological , lithological and sedimentological characteristics soils. The area corresponding to the Cerro Partido fotoplano is located in the orogenic belt or Don Feliciano belt

The Marianas-San Marcos vein system: characteristics of a shallow low sulfidation epithermal Au-Ag deposit in the Cerro Negro district, Deseado Massif, Patagonia, Argentina

Science.gov (United States)

Vidal, Conrado Permuy; Guido, Diego M.; Jovic, Sebastián M.; Bodnar, Robert J.; Moncada, Daniel; Melgarejo, Joan Carles; Hames, Willis

2016-08-01

The Cerro Negro district, within the Argentinian Deseado Massif province, has become one of the most significant recent epithermal discoveries, with estimated reserves plus resources of ˜6.7 Moz Au equivalent. The Marianas-San Marcos vein system contains about 70 % of the Au-Ag resources in the district. Mineralization consists of Upper Jurassic (155 Ma) epithermal Au- and Ag-rich veins of low to intermediate sulfidation style, hosted in and genetically related to Jurassic intermediate composition volcanic rocks (159-156 Ma). Veins have a complex infill history, represented by ten stages with clear crosscutting relationships that can be summarized in four main episodes: a low volume, metal-rich initial episode (E1), an extended banded quartz episode with minor mineralization (E2), a barren waning stage episode (E3), and a silver-rich late tectonic-hydrothermal episode (E4). The first three episodes are interpreted to have formed at the same time and probably from fluids of similar composition: a 290-230 °C fluid dominated by meteoric and volcanic waters (-3‰ to -0‰ δ18Owater), with geothermal features. The last tectonic-hydrothermal mineralization episode (E4), interpreted to have formed at lower temperatures, could be related to this late tectonic and hydrothermal activity.

Investigating the subsurface connection beneath Cerro Negro volcano and the El Hoyo Complex, Nicaragua

Science.gov (United States)

Venugopal, Swetha; Moune, Séverine; Williams-Jones, Glyn

2016-10-01

Cerro Negro, the youngest volcano along the Central American Volcanic Belt (CAVB), is a polygenetic cinder cone with relatively frequent basaltic eruptions. The neighbouring El Hoyo complex, of which Las Pilas is the dominant edifice, is a much larger and older complex with milder and less frequent eruptions. Previous studies have suggested a deep link beneath these two closely spaced volcanoes (McKnight, 1995; MacQueen, 2013). Melt inclusions were collected from various tephra samples in order to determine whether a connection exists and to delineate the features of this link. Major, volatile, and trace elemental compositions reveal a distinct geochemical continuum with Cerro Negro defining the primitive endmember and El Hoyo representing the evolved endmember. Magmatic conditions at the time of melt inclusion entrapment were estimated with major and volatile contents: 2.4 kbar and 1170 °C for Cerro Negro melts and 1.3 kbar and 1130 °C for El Hoyo melts with an overall oxygen fugacity at the NNO buffer. Trace element contents are distinct and suggest Cerro Negro magmas fractionally crystallise while El Hoyo magmas are a mix between primitive Cerro Negro melts and residual and evolved El Hoyo magma. Modelling of end member compositions with alphaMELTS confirms the unique nature of El Hoyo magmas as resulting from incremental mixing between Cerro Negro and residual evolved magma at 4 km depth. Combining all available literature data, this study presents a model of the interconnected subsurface plumbing system. This model considers the modern day analogue of the Lemptégy cinder cones in Massif Central, France and incorporates structurally controlled dykes. The main implications of this study are the classification of Cerro Negro as the newest conduit within the El Hoyo Complex as well as the potential re-activation of the El Hoyo edifice.

Sedimentary rocks Uranium in Cerro Largo Province; Uranio en rocas sedimentarias en el departamento de Cerro Largo

Energy Technology Data Exchange (ETDEWEB)

Scaron, P; Garau Tous, M

1976-07-01

With the aim of the uranium minerals exploration has been carried out several studies by UTE technicians in Cerro Largo Province from 1968 to 1969. In uranium concentration has been found pyrite, phosphate, iron oxides and manganese in uranium. Furthermore in La Divisa Ore were studied concentration Uranium enrichment has been studied in La Divisa ore.

Daniel Prieto Castillo y la utopía pedagógica

Directory of Open Access Journals (Sweden)

Kintto Lucas

2015-01-01

Full Text Available En la entrevista realizada a Daniel Prieto Castillo, éste afirma que entre lo que produce la cultura, las prácticas, los saberes y quienes están en situación de aprender siempre hay mediaciones sociales. Al opinar sobre la educación alternativa dice que hay una explosión de lo alternativo porque hay una explosión de la sociedad civil en todos, los campos. Discrepa de los programas infantiles como el dirigido por XUXA por su terrible violencia referida a la saturación de sonido de la animadora no hay silencio, pausa o respiro solo gritos, es de un manipuleo insoportable.

Sedimentary rocks Uranium in Cerro Largo Province

International Nuclear Information System (INIS)

Scaron, P.; Garau Tous, M.

1976-01-01

With the aim of the uranium minerals exploration has been carried out several studies by UTE technicians in Cerro Largo Province from 1968 to 1969. In uranium concentration has been found pyrite, phosphate, iron oxides and manganese in uranium. Furthermore in La Divisa Ore were studied concentration Uranium enrichment has been studied in La Divisa ore

Origin and evolution of mineralizing fluids and exploration of the Cerro Quema Au-Cu deposit (Azuero Peninsula, Panama) from a fluid inclusion and stable isotope perspective

Science.gov (United States)

Corral, Isaac; Cardellach, Esteve; Corbella, Merce; Canals, Angels; Griera, Albert; Gomez-Gras, David; Johnson, Craig A.

2017-01-01

Cerro Quema is a high sulfidation epithermal Au-Cu deposit with a measured, indicated and inferred resource of 35.98 Mt. @ 0.77 g/t Au containing 893,600 oz. Au (including 183,930 oz. Au equiv. of Cu ore). It is characterized by a large hydrothermal alteration zone which is interpreted to represent the lithocap of a porphyry system. The innermost zone of the lithocap is constituted by vuggy quartz with advanced argillic alteration locally developed on its margin, enclosed by a well-developed zone of argillic alteration, grading to an external halo of propylitic alteration. The mineralization occurs in the form of disseminations and microveinlets of pyrite, chalcopyrite, enargite, tennantite, and trace sphalerite, crosscut by quartz, barite, pyrite, chalcopyrite, sphalerite and galena veins.Microthermometric analyses of two phase (L + V) secondary fluid inclusions in igneous quartz phenocrysts in vuggy quartz and advanced argillically altered samples indicate low temperature (140–216 °C) and low salinity (0.5–4.8 wt% NaCl eq.) fluids, with hotter and more saline fluids identified in the east half of the deposit (Cerro Quema area).Stable isotope analyses (S, O, H) were performed on mineralization and alteration minerals, including pyrite, chalcopyrite, enargite, alunite, barite, kaolinite, dickite and vuggy quartz. The range of δ34S of sulfides is from − 4.8 to − 12.7‰, whereas δ34S of sulfates range from 14.1 to 17.4‰. The estimated δ34SΣS of the hydrothermal fluid is − 0.5‰. Within the advanced argillic altered zone the δ34S values of sulfides and sulfates are interpreted to reflect isotopic equilibrium at temperatures of ~ 240 °C. The δ18O values of vuggy quartz range from 9.0 to 17.5‰, and the δ18O values estimated for the vuggy quartz-forming fluid range from − 2.3 to 3.0‰, indicating that it precipitated from mixing of magmatic fluids with surficial fluids. The δ18O of kaolinite ranges from 12.7 to 18.1‰ and �

Design of a seismic energy dissipator for an interruptor type 3AS2-45; Diseno de un disipador de energia sismica para un interruptor tipo 3AS2-45

Energy Technology Data Exchange (ETDEWEB)

Castro Felix, Jaime

2004-02-15

With the aid of the theory behind seismically isolated structures and the bi-linear behavior of an isolated system of Multiple Degrees of Freedom (MDOF), the information obtained on the spectral analysis is complemented with the purpose of simulating one itself for the design of a dissipator of seismic energy. The seismicity in the world is briefly explained, (in Mexico in special for the Geothermal Field of Cerro Prieto), the types of earthquakes, etc., to give way to a documentation of the state-of-the-art in advanced seismic resistant systems and to a procedure to establish the level of seismic qualification of electrical equipment from the level of seismic performance for the Mexican Republic. [Spanish] Con la ayuda de la teoria detras de estructuras aisladas sismicamente y el comportamiento bilineal de un sistema de aislamiento de Multiples Grados de Libertad (MDOF), se complementa la informacion recabada sobre el analisis espectral con el fin de simular uno propio para el diseno de un disipador de energia sismica. Se explica brevemente la sismicidad en el mundo, en Mexico, en especial el Campo Geotermico de Cerro Prieto, los tipos de sismos, etc., para dar paso a una documentacion del estado del arte en sistemas sismorresistentes avanzados y a un procedimiento para establecer el nivel de calificacion sismica de equipos electricos a partir del Nivel de desempeno sismico para la Republica Mexicana.

Evaluation of the Cerro Solo nuclear ore, province of Chubut. The Cerro Solo project within the frame of uranium exploration in Argentina. Pt. 1

International Nuclear Information System (INIS)

Solis, R.J.; Navarra, P.R.; Benitez, A.F.; Gallucci, A.R.

1993-01-01

The Cerro Solo ore deposit was selected by the CNEA to invest in an assessment project because of their promising grade and amount of known and potential resources, significant to Argentina's uranium requirements. The deposit, which is located in the central region of the Chubut Province, belongs to the sandstone type and is hosted by the cretaceous Chubut Group. Technical studies carried out forecast an important growth of nuclear capacity to meet Argentina's energy requirements in the first two decades of of the the next century. To be in position to confront the challenge presented by increasing uranium resources to fuel the nuclear powers plants it is very important, as a first step, to improve the geological knowledge of uranium favorability in the country. The preliminary results of the Cerro Solo project indicate that the eastern slope of the Pichinan hills is a promising area for development of uranium resources, increasing the favorability of the San Jorge Basin in order to allow contributing to meet future uranium requirements. The Cerro Solo Project was planned in a sequential manner, as a multidisciplinary effort which includes studies on: geologic setting of mineralization, resource estimates, costs of mining and milling methods, economic analysis and environmental impact research. Among the mining methods, studies include the alternative of the in-situ leaching technology, which is becoming a low producing cost interesting possibility. (Author)

Mineralogy, structural control and age of the Incachule Sb epithermal veins, the Cerro Aguas Calientes collapse caldera, Central Puna

Science.gov (United States)

Salado Paz, Natalia; Petrinovic, Iván; Do Campo, Margarita; Brod, José Affonso; Nieto, Fernando; da Silva Souza, Valmir; Wemmer, Klauss; Payrola, Patricio; Ventura, Roberto

2018-03-01

The Incachule Sb epithermal veins is located near to the N-E rim of the Cerro Aguas Calientes collapse caldera (17.5-10.8 Ma), in the geologic province of Puna, Salta- Argentina. It is hosted in Miocene felsic volcanic rocks with continental arc signature. The district includes twelve vein systems with mineralization of Sb occurring in hydrothermal breccias and stockwork. The veins are composed of quartz-sulfide with pyrite, stibnite and arsenopyrite. All around the veins, wall rocks are variably altered to clay minerals and sulfates in an area of around 2.5 km wide by more than 7 km long. The hydrothermal alterations recognized are: silicic, phyllic and argillic. The veins are characterized by high contents of Sb, As, and Tl and intermediate contents of Pb-Zn-Cu, and traces of Ag and Au. Homogenization and ice-melting temperatures of fluid inclusions vary from 125 °C to 189 °C and -2.4 °C to -0.8 °C. The isotopic data indicated a range of δ34S -3.04‰ to +0.72‰ consistent with a magmatic source for sulfur. We present the firsts K-Ar ages for hydrothermal illite/smectite mixed layers (I/SR1, 60% illite layers) and illite that constrain the age of the ore deposit (8.5-6.7 ± 0.2 Ma). The data shown here, let characterized the Incachule district as a shallow low sulfidation epithermal system hosted in a collapse caldera. Our data also indicate that mineralization is structurally controlled by a fault system related to the 10.3 Ma collapse of Aguas Calientes caldera. The interpreted local stress field is consistent with the regional one.

Report of mortmorilloniticas clay in the Medina swamp (Cerro Largo district)

International Nuclear Information System (INIS)

Gomez Rifas, C.; Heinzen, W.; Theune, C.

1980-01-01

This report describes the prospect ion work for the montmorillonitics clay in the region of Medina swamp in Cerro Largo district. The existence of new deposits was detected by cartography and geological study.

Análisis de la estabilidad del cerro Shishio mediante el empleo de técnicas numéricas

OpenAIRE

Vintimilla Avila, Maribel Cristina

2011-01-01

La presente investigación analiza la estabilidad existente en el Cerro Shishio ubicado en el sector de La Josefina por medio de técnicas numéricas. El deslizamiento del cerro Shishio provocado por el desfogue de las aguas represadas por el deslizamiento del cerro Tamuga, se originó en el material de la Formación Tarqui, el mismo que se deslizó sobre un roca intrusiva muy alterada. En la actualidad se puede observar el material deslizado acumulado al pie del talud, que ahora sirve de soporte ...

Intense Seismic Activity at Chiles and Cerro Negro Volcanoes on the Colombia-Ecuador Border

Science.gov (United States)

Torres, R. A.; Cadena, O.; Gomez, D.; Ruiz, M. C.; Prejean, S. G.; Lyons, J. J.; White, R. A.

2015-12-01

The region of Chiles and Cerro Negro volcanoes, located on the Colombian-Ecuadorian border, has experienced an ongoing seismic swarm beginning in Aug. 2013. Based on concern for local residents and authorities, a cooperative broadband monitoring network was installed by the Servicio Geológico Colombiano in Colombia and the Instituto Geofísico of the Escuela Politécnica Nacional in Ecuador. Since November 2013 more than 538,000 earthquakes were recorded; although since May 2015 the seismicity has decreased significantly to an average of 70 events per day. Three large earthquake swarms with increasing energy occurred in Aug.-Oct. 2013, March-May 2014, and Sept.-Dec. 2014. By the end of 2014, roughly 400 earthquakes greater than M 3 had occurred with a maximum rate of 8000 earthquakes per day. The largest earthquake was a 5.6 ML on Oct. 20, 2014. This event produced an InSAR coseismic deformation of ~23 cm (S. Ebmeier, personal communication). Most events are typical brittle failure volcano-tectonic (VT) earthquakes that are located in a cluster beneath the southern flank of Chiles volcano, with depths between 1.5 and 10 km. Although the great majority of earthquakes are VT, some low-frequency (LF, ~0.5 Hz) and very-low-frequency (VLF) events have occurred. Particle motion analysis suggests that the VLF source migrated with time. While a VLF on Oct. 15, 2014 was located south of Chiles volcano, near the InSAR source, the VLF registered on Feb. 14, 2015 was likely located very close to Chiles Volcano. We infer that magma intrusion and resulting fluid exsolution at depths greater than 5 km are driving seismicity in the Chiles-Cerro Negro region. However earthquakes are failing in a manner consistent with regional tectonics. Relative relocations reveal a structure consistent with mapped regional faults. Thus seismicity is likely controlled by an interaction of magmatic and tectonic processes. Because the regional stress field is highly compressional and the volcanoes

Miguel Prieto y la escenografía en la España de los años treinta

Directory of Open Access Journals (Sweden)

Cabañas Bravo, Miguel

2011-12-01

Full Text Available The artist Miguel Prieto (1907-1956 worked in three main areas: painting-drawing, graphic design and set design. The latter was the one in which he demonstrated most interest in avant-garde and political commitment during the thirties, but due to his subsequent Mexican exile, has not been dealt with in recent research. This article, focused on his years in Spain, analyses his contributions to scenic design. Prieto’s first professional period, when he worked for the puppet theatre, coincided with the young Second Republic and then the convulsion of the Civil War. This popular genre was utilized for agitation, propaganda and the revolutionary theatre, and adopted both the classical repertoire and modern works by Alberti, Dieste, Lorca and other committed youthful intellectuals.

Las tres grandes vertientes en las que el pintor Miguel Prieto (1907-1956 plasmó su creatividad fueron la pintura-dibujo, el diseño gráfico y la escenografía. Esta última, que fue en la que más énfasis puso tanto en su acercamiento a la vanguardia y el compromiso socio-político de los años treinta, como en los años finales de su trayectoria en el exilio mexicano, no ha sido suficientemente atendida. Este artículo, centrado en esa etapa española, analiza y pone en valor la aportación a la escena de Prieto coincidente con esos momentos de construcción de la joven II República y la convulsión de la Guerra Civil, que principalmente se plasmó en la escenificación de espectáculos de guiñol (extraídos del repertorio clásico o expresamente escritos por Alberti, Dieste, Lorca y otros jóvenes inquietos, ya que su tradición y clara aceptación popular los convertían en adecuado instrumento para encauzar la agitación y propaganda que querían sembrar el teatro revolucionario y la creatividad más avanzada y comprometida.

Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

Science.gov (United States)

Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.

2009-01-01

Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confi ning pressure causes fluids to fl ash to steam, resulting in signifi cant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially signifi cant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identifi ed; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ??1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing

Report of boring made in the South of Cerro Largo district (Cerro Largo) 1977-1978

International Nuclear Information System (INIS)

Massa, E.

1984-01-01

The present work are within the framework and compiles the data obtained by means of the study of the perforations executed in the District Cerro Largo Sur of the detailed prospection of uranium minerals. This study was carried out by technicians of Geologic ex--Institute of Uruguay (IGU) - at the moment National Direction of Mining and Geology. (DINAMIGE). The works began at the beginning of 1977 and continued until 1978 July; The headquarters of the program of prospection of uranium was carried out by Ing. Hector Goso. In this report the conclusions drawn at the time of the detection of the works in the District already published, as well as the litologicos cuts of all the executed perforations are included

Hidrogeologic and geophysical studies into Agro school Melo UTU Cerro Largo province

International Nuclear Information System (INIS)

Heinzen, W.; Santana, I.; Mari, C.

1986-01-01

The technical University UTU of Uruguay requested and Hidrogeologic study with the aim to analyze the factibility to discover underground stream waters which supply groundwaters into agro school Ing Agr. Alcides E Pintos Melo, Cerro Largo province.

Characterization of pottery from Cerro de Las Ventanas, Zacatecas, Mexico

International Nuclear Information System (INIS)

Lopez-del-Rio, H.; Mireles-Garcia, F.; Mendez-Cardona, R.Y.; Nicolas-Caretta, M.; Speakman, R.J.; Glascock, M.D.

2009-01-01

With the aim of classifying prehispanic pottery from Cerro de Las Ventanas site, Juchipila, Zacatecas, Mexico, instrumental neutron activation analysis (INAA) was used to analyze ceramic samples at the University of Missouri Research Reactor Center. Thirty-two chemical elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Two multivariate statistical methods, cluster analysis and principal component analysis, were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Mesoamerican ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Malpaso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de Las Ventanas represent a new and unique chemical fingerprint in the region. (orig.)

Characterization of pottery from Cerro de Las Ventanas, Zacatecas, Mexico

Energy Technology Data Exchange (ETDEWEB)

Lopez-del-Rio, H.; Mireles-Garcia, F. [Unidad Academica de Estudios Nucleares, UAZ, Zacatecas (Mexico); Mendez-Cardona, R.Y. [Unidad Academica de Antropologia, UAZ, Zacatecas (Mexico); Nicolas-Caretta, M. [INAH Delegacion Zacatecas (Mexico); Coordinacion de Ciencias Sociales y Humanidades, UASLP, Fracc. Talleres, SLP (Mexico); Speakman, R.J. [Museum Conservation Inst., Smithsonian Institution, Suitland, MD (United States); Glascock, M.D. [Research Reactor Center, Univ. of Missouri, Columbia, MO (United States)

2009-09-15

With the aim of classifying prehispanic pottery from Cerro de Las Ventanas site, Juchipila, Zacatecas, Mexico, instrumental neutron activation analysis (INAA) was used to analyze ceramic samples at the University of Missouri Research Reactor Center. Thirty-two chemical elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Two multivariate statistical methods, cluster analysis and principal component analysis, were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Mesoamerican ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Malpaso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de Las Ventanas represent a new and unique chemical fingerprint in the region. (orig.)

ALFONSO X EL SABIO, General Estoria, VI partes (tomos I-X, Pedro SÁNCHEZ-PRIETO (coord.,

Directory of Open Access Journals (Sweden)

Irene SALVO GARCÍA

2010-06-01

Full Text Available La General Estoria compuesta en el taller historiográfico de Alfonso X (1221-1284 se publica íntegra por primera vez gracias a esta edición dirigida por Pedro Sánchez-Prieto y patrocinada por la Biblioteca Castro. Por las características intrínsecas de la obra y por la calidad y rigurosidad editorial esta publicación supone un acontecimiento de importantísimas consecuencias para las letras castellanas medievales que hasta ahora se encontraban incompletas sin la edición íntegra de la obra alf...

Report of the Cerro Chato ultrabasic geophysical studies

International Nuclear Information System (INIS)

Cicalese, H.; Mari, C.; Lema, F.; Valverde, C.; Haut, R.

1987-01-01

This report refers to the obtained results of geophysical practiced during the year 1985 in the area of the ultrabasic of Cerro Chato, located in the area called Puntas del Malbajar in Durazno province. The aim was rehearsed an answer of an ultrabasic behaviour of the geophysical prospecting methods.They were carried out studies in magnetometry, induced polarization, electromagnetism and resistivity measurements in electric vertical sound. As well conclusions as recommendations express that applied geophysical methods allow to make ultrabasic charts or maps.

LA CERÁMICA CERRO LOS HORNOS, PRESENCIA INKA EN LA COSTA DE TACNA, SUR DEL PERÚ

OpenAIRE

Vela Velarde, Carlos

2004-01-01

Se estudia el sitio Cerro Los Hornos, ubicado en la costa de Tacna, sur del Perú. Presenta cerámica con filiación Inka Imperial o Cuzco Policromo, pero de fabricación local; esta presencia cultural es consecuencia del proceso de expansión Inka a la costa sur del Perú, la cual establece relaciones con la sociedad local The place studied is Cerro Los Hornos located in the coast of Tacna, south of Peru, presents ceramic with filiation Inka Imperial or Cuzco Policromo, but of local production;...

The last glacial cycle and palaeolake synchrony in the southern bolivian Altiplano: Cerro Azanaques case study

Directory of Open Access Journals (Sweden)

1995-01-01

Full Text Available SYNCHRONISME ENTRE LE DERNIER CYCLE GLACIAIRE ET L'EXTENSION DES PALÉOLACS DANS LE SUD DE L'ALTIPLANO BOLIVIEN : EXEMPLE DU CERRO AZANAQUES. Dans la Cordillère Orientale, au niveau du Cerro Azanaques (18°S, Bolivie, des moraines, des sédiments glaciaires, des rivages paléolacustres, des deltas et des stromatolites qui se sont préservés, révèlent des conditions climatiques fortement différentes dans le passé. La culmination de la dernière avancée du glacier Lijunimani a été datée par la méthode du radiocarbone à 13 000 ans BP à partir de sédiments glaciaires ayant remanié un horizon organique de tourbe. La cartographie de cette diacmitite argileuse particulière révèle un delta en forme de cône bordé par un glacier cela montre que les glaciers et les anciens systèmes lacustres font partie d'un processus d'expansion simultanée. L'étude stratigraphique détaillée réalisée au Cerro Azanaques fournit de fortes évidences allant dans le sens d'une réponse commune des glaciers et des lacs à un signal piloté par un changement climatique les lacs ne sont donc pas le simple résultat de la fonte des glaciers des cordillères. SINCRONISMO ENTRE EL ÚLTIMO CICLO GLACIAL Y LA EXTENSIÓN DE LOS PALEOLAGOS EN EL SUR DEL ALTIPLANO BOLIVIANO: CASO DEL CERRO AZANAQUES. En la Cordillera Oriental, a la altura del Cerro Azanaques (18º S, Bolivia aparecen preservadas morrenas y sedimentos glaciares, líneas de costa paleolacustres, deltas y estromatolitos, lo que revela condiciones climáticas pasadas significativamente diferentes. La culminación del último avance del glaciar Lijunimani ha sido fechada mediante radiocarbono a 13 000 años BP a partir de sedimentos glaciares que han desplazado un horizonte orgánico de turba. La cartografía de esta particular diamictita arcillosa revela un delta en forma de abanico con hielo en sus márgenes lo que indica que los glaciares y los sistemas paleolacustres sufrieron un proceso

Mining inventory of Uruguay. Results of geochemical prospecting of Cerro Partido fotoplano

International Nuclear Information System (INIS)

Zeegers, H.; Artignan, D.; Vairon, P.

1982-01-01

This work is about the analitical results of the geological prospection carried out in Cerro Partido zone within the framework of Mining inventory of Uruguay. In this fotoplano (Esc. 1/50.000 and 1/400.000 there are metamorphic, mesozoic and carbonated formations

U-Pb and K-Ar geochronology from the Cerro Empexa Formation, 1st and 2nd Regions, Precordillera, northern Chile

International Nuclear Information System (INIS)

Tomlinson, A.J; Martin, M.W; Blanco, N.; Perez de Arce, C

2001-01-01

The Cerro Empexa Formation (Galli, 1957) is a regionally distributed andesitic volcanic and continental sedimentary unit exposed in the Precordillera of the 1st and 2nd Regions of northern Chile. The formation has generally been considered to lie within the Lower or 'mid' Cretaceous, however, this assignment is based on scant, unreliable geochronologic data. Furthermore, there are conflicting interpretations as to whether the unit predates or postdates the first major Mesozoic shortening event affecting northern Chile. Because of the formation's presumed mid-Cretaceous age and its stratigraphic position over older back-arc sedimentary successions, the unit has been interpreted to represent products of the first eastward jump in the Andean magmatic arc from the arc's initial position in the Cordillera de la Costa (Scheuber and Reutter, 1992). In this paper we present the results of mapping and field observations that indicate exposures previously assigned to the Cerro Empexa Formation include two andesitic volcanic units separated by a major unconformity. The Cerro Empexa Formation proper lies above this unconformity. We also present U-Pb zircon and K-Ar geochronology that indicate the Cerro Empexa Formation is latest Cretaceous in its lower levels, and integrate our data with previously reported 40 Ar/ 39 Ar and fission-track data in the Cerros de Montecristo area (Maksaev, 1990; Maksaev and Zentilli, 1999) to show that 1800±600 m of rocks were deposited within ca. 2.5 m.y (au)

Proceedings: third symposium on the Cerro Prieto geothermal field, Baja California, Mexico

Energy Technology Data Exchange (ETDEWEB)

1981-01-01

These proceedings include both English and Spanish versions of each paper presented at the symposium. Illustrations and tables, which have been placed between the two versions, include captions in both languages. Forty-one papers are included. Five papers were indexed for EDB previously. Separate abstracts were prepared for thirty-three papers and three were listed by title.

Elemental analysis of pottery from Cerro de las Ventanas, Zacatecas, by INAA

Energy Technology Data Exchange (ETDEWEB)

Lopez del Rio, H.; Mireles G, F. [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Calle Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas (Mexico); Mendez C, R. Y. [Universidad Autonoma de Zacatecas, Unidad Academica de Antropologia, Apdo. Postal 555 Suc. C, Zacatecas (Mexico); Nicolas C, M. [Universidad Autonoma de San Luis Potosi, Coordinacion de Ciencias Sociales y Humanidades, Av. Industrias 101-A, Fracc. Talleres, 78494 San Luis Potosi (Mexico); Speakman, R. J. [Museum Conservation Institute, Smithsonian Institution, Suitland, 20746 Maryland (United States); Glascock, M. D. [Reactor Center, University of Missouri, Columbia, 65211 Missouri (United States)

2009-10-15

Fifteen ceramic fragments samples from Cerro de las Ventanas site, Zacatecas, were analyzed by instrumental neutron activation analysis. Thirty-two elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Cluster analysis and principal component analysis were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Meso american ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Mal paso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de las Ventanas represent a new and unique chemical fingerprint in the region. (Author)

Elemental analysis of pottery from Cerro de las Ventanas, Zacatecas, by INAA

International Nuclear Information System (INIS)

Lopez del Rio, H.; Mireles G, F.; Mendez C, R. Y.; Nicolas C, M.; Speakman, R. J.; Glascock, M. D.

2009-10-01

Fifteen ceramic fragments samples from Cerro de las Ventanas site, Zacatecas, were analyzed by instrumental neutron activation analysis. Thirty-two elements were measured: Al, As, Ba, Ca, Ce, Co, Cr, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Ti, Th, U, V, Yb, Zn, and Zr. Cluster analysis and principal component analysis were performed on the dataset to examine similarities between samples and to establish compositional groups. The statistical analyses of the dataset suggest that the pottery samples form a unique chemically homogeneous group, with the exception of one pottery sample. The compositional data were compared to an existing Meso american ceramic database. It was found that the newly generated data fit best with data from a previous chemical analysis of pottery from the Mal paso Valley. However, despite the apparent similarity, pottery samples from the site of Cerro de las Ventanas represent a new and unique chemical fingerprint in the region. (Author)

Magma-Tectonic Interactions along the Central America Volcanic Arc: Insights from the August 1999 Magmatic and Tectonic Event at Cerro Negro, Nicaragua

Science.gov (United States)

La Femina, P.; Connor, C.; Strauch, W.

2002-12-01

Volcanic vent alignments form parallel to the direction of maximum horizontal stress, accommodating extensional strain via dike injection. Roughly east-west extension within the Central America Volcanic Arc is accommodated along north-northwest-trending basaltic vent alignments. In Nicaragua, these alignments are located in a northwest-trending zone of dextral shear, with shear accommodated along northeast trending bookshelf faults. The recent eruption of Cerro Negro volcano, Nicaragua and Marabios Range seismic swarm revealed the interaction of these fault systems. A low energy (VEI 1), small volume (0.001 km3 DRE) eruption of highly crystalline basalt occurred at Cerro Negro volcano, Nicaragua, August 5-7, 1999. This eruption followed three tectonic earthquakes (each Mw 5.2) in the vicinity of Cerro Negro hours before the onset of eruptive activity. The temporal and spatial pattern of microseismicity and focal mechanisms of the Mw 5.2 earthquakes suggests the activation of northeast-trending faults northwest and southeast of Cerro Negro within the Marabios Range. The eruption was confined to three new vents formed on the southern flank of Cerro Negro along a preexisting north-northwest trending alignment; the El Hoyo alignment of cinder cones, maars and explosion craters. Surface ruptures formed > 1 km south and southeast of the new vents suggest dike injection. Numerical simulations of conduit flow illustrate that the observed effusion rates (up to 65 ms-1) and fountain heights (50-300 m) can be achieved by eruption of magma with little or no excess fluid pressure, in response to tectonic strain. These observations and models suggest that 1999 Cerro Negro activity is an excellent example of tectonically induced small-volume eruptions in an arc setting.

Report of boring made in the South of Cerro Largo district (Cerro Largo) 1977-1978[Study of Uranium prospection in Uruguay]; Informe de los trabajos de perforacion efectuados en el distrito Cerro Largo Sur (Dpto. Cerro Largo) 1977 - 1978

Energy Technology Data Exchange (ETDEWEB)

Massa, E

1984-07-01

The present work are within the framework and compiles the data obtained by means of the study of the perforations executed in the District Cerro Largo Sur of the detailed prospection of uranium minerals. This study was carried out by technicians of Geologic ex--Institute of Uruguay (IGU) - at the moment National Direction of Mining and Geology. (DINAMIGE). The works began at the beginning of 1977 and continued until 1978 July; The headquarters of the program of prospection of uranium was carried out by Ing. Hector Goso. In this report the conclusions drawn at the time of the detection of the works in the District already published, as well as the litologicos cuts of all the executed perforations are included.

Un proyecto de Francisco Prieto-Moreno de cuatro casas en la Huerta de los Ángeles

Directory of Open Access Journals (Sweden)

Miguel Ángel Sorroche Cuerva

2009-12-01

Full Text Available La realización de promociones de viviendas en algunos sectores de Granada, adquirió unas especiales características en el barrio del Realejo. En torno a la calle Molinos se consolidó en los años cuarenta del siglo XX, un modelo de urbanización con viviendas unifamiliares que adquirió tintes de lujo, curiosamente a partir de iniciativas sociales. La presencia de arquitectos como Francisco Prieto-Moreno, habla de las pretensiones de algunos de estos proyectos que ayudaron a conformar la imagen residencial de esta zona de Granada, y que a lo largo del siglo XIX comenzaría a configurar el aspecto que hoy la caracteriza.

Role of forest conservation in lessening land degradation in a temperate region: the Monarch Butterfly Biosphere Reserve, Mexico.

Science.gov (United States)

Manzo-Delgado, Lilia; López-García, José; Alcántara-Ayala, Irasema

2014-06-01

With international concern about the rates of deforestation worldwide, particular attention has been paid to Latin America. Forest conservation programmes in Mexico include Payment for Environmental Services (PES), a scheme that has been successfully introduced in the Monarch Butterfly Biosphere Reserve. To seek further evidence of the role of PES in lessening land degradation processes in a temperate region, the conservation state of the Cerro Prieto ejido within the Reserve was assessed by an analysis of changes in vegetation cover and land-use between 1971 and 2013. There were no changes in the total forest surface area, but the relative proportions of the different classes of cover density had changed. In 1971, closed and semi-closed forest occupied 247.81 ha and 5.38 ha, 82.33% and 1.79% of the total area of the ejido, respectively. By 2013, closed forest had decreased to 230.38 ha (76.54% of the ejido), and semi-closed cover was 17.23 ha (5.72% of the ejido), suggesting that some semi-closed forest had achieved closed status. The final balance between forest losses and recovery was: 29.63 ha were lost, whereas 13.72 ha were recovered. Losses were mainly linked to a sanitation harvest programme to control the bark beetle Scolytus mundus. Ecotourism associated with forest conservation in the Cerro Prieto ejido has been considered by inhabitants as a focal alternative for economic development. Consequently, it is essential to develop a well-planned and solidly structured approach based on social cohesion to foster a community-led sustainable development at local level. Copyright © 2013 Elsevier Ltd. All rights reserved.

Argentine hydrothermal panorama

Energy Technology Data Exchange (ETDEWEB)

1976-12-01

An attempt is made to give a realistic review of Argentine thermal waters. The topics discussed are the characteristics of the hydrothermal resources, classification according to their mineral content, hydrothermal flora and fauna, uses of hydrothermal resources, hydrothermal regions of Argentina, and meteorology and climate. A tabulation is presented of the principal thermal waters. (JSR)

The Cerro Grande Fire - From Wildfire Modeling Through the Fire Aftermath

Energy Technology Data Exchange (ETDEWEB)

Rudell, T. M. (Theresa M.); Gille, R. W. (Roland W.)

2001-01-01

The Cerro Grande Fire developed from a prescribed burn by the National Park Service at Bandelier National Monument near Los Alamos, New Mexico. When the burn went out of control and became a wildfire, it attracted worldwide attention because it threatened the birthplace of the atomic bomb, Los Alamos National Laboratory (LANL). Was LANL prepared for a fire? What lessons have been learned?

The Cerro Grande Fire - From Wildlife Modeling Through the Fire Aftermath

Energy Technology Data Exchange (ETDEWEB)

Rudell, T. M. (Theresa M.); Gille, R. W. (Roland W.)

2001-01-01

The Cerro Grande Fire developed from a prescribed burn by the National Park Service at Bandelier National Monument near Los Alamos, New Mexico. When the burn went out of control and became a wildfire, it attracted worldwide attention because it threatened the birthplace of the atomic bomb, Los Alamos National Laboratory (LANL). Was LANL prepared for a fire? What lessons have been learned?

Minería, conflicto y mediadores locales: Minera San Xavier en Cerro de San Pedro, México Mineira, conflito e mediadores locais: Minera San Xavier em Cerro de San Pedro Mining, conflict and local brokers: Minera San Xavier in Cerro de San Pedro

Directory of Open Access Journals (Sweden)

Hernán Horacio Schiaffini

2011-12-01

Full Text Available Este trabajo indaga en las instancias de mediación que intervienen en la articulación de procesos económicos de gran escala y su puesta en práctica local. Basándonos en el conflicto que se produjo en el Municipio de Cerro de San Pedro (San Luis Potosí, México entre la empresa Minera San Xavier y el Frente Amplio Opositor (FAO a la misma, aplicamos el método etnográfico con el objetivo de describir las estructuras locales de mediación política y analizar sus prácticas y racionalidad. Intentamos demostrar así la importancia de los factores políticos locales en las vinculaciones entre estado, empresa y población.Este trabalho indaga nas instâncias de mediação que intervêm em processos econômicos de grande escala e sua posta em prática local. Baseando-nos no conflito no Cerro de San Pedro (San Luis Potosí, México entre a empresa Minera San Xavier e a Frente Amplio Opositor (FAO aplicamos o método etnográfico pra descrever as estruturas de mediação política locais e analisar suas práticas e racionalidade. Tenta-se demonstrar assim a importância dos fatores políticos locais nas vinculações entre estado, empresa e população.This paper investigates in instances of mediation involved in large-scale economic processes and local implementation. Analyzing the conflict in Cerro de San Pedro (San Luis Potosí, México among San Xavier mining company and the Frente Amplio Opositor (FAO, it applies an ethnographic approach to describe the local structures of political mediation and its practices and rationality. The work shows the relevance of local factors in the relationships between State, company and people.

Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza Geology of Cerro Guanaquero region, Diamante River, Mendoza

OpenAIRE

Federico Fuentes; Victor A. Ramos

2008-01-01

El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánic...

Forecast of environmental impact in the evaluation of Cerro Solo nuclear mine

International Nuclear Information System (INIS)

Gallucci, A.R.

1993-01-01

This work presents a project for the study of the environmental impact of the Cerro Solo uranium mine. The survey is to be carried out performing different kinds of studies: mineralization, tectonics, hydrogeology, preliminary studies on different exploitation methods, costs, reserves estimation, economical studies and preliminary studies on possible environmental impacts. (author). 24 refs., 1 fig., 1 tab

Burn Severities, Fire Intensities, and Impacts to Major Vegation Types from the Cerro Grande Fire

International Nuclear Information System (INIS)

Balice, R.G.; Bennett, K.D.; Wright, M.A.

2005-01-01

The Cerro Grande Fire resulted in major impacts and changes to the ecosystems that were burned. To partially document these effects, we estimated the acreage of major vegetation types that were burned at selected burn severity levels and fire intensity levels. To accomplish this, we adopted independently developed burn severity and fire intensity maps, in combination with a land cover map developed for habitat management purposes, as a basis for the analysis. To provide a measure of confidence in the acreage estimates, the accuracies of these maps were also assessed. In addition, two other maps of comparable quality were assessed for accuracy: one that was developed for mapping fuel risk and a second map that resulted from a preliminary application of an evolutionary computation software system, called GENIE. According to the burn severity map and the fire intensity map, the Cerro Grande Fire is estimated to have covered 42,885.4 acres and 42,854.7 acres, respectively. Of this, 57.0 percent was burned at low severity and 34.7 percent was burned at high severity. Similarly, 40.0 percent of the Cerro Grande Fire burned at high fire intensity, greater than 70 percent mortality, while 33.1 percent burned at moderately low intensity, 10 to 40 percent mortality. The most frequently burned cover types over the entire Cerro Grande Fire were ponderosa pine forest and mixed conifer forest, at approximately 43 percent each. However, portions of the fire that burned on Los Alamos National Laboratory (LANL) property were predominantly in ponderosa pine forests, whereas the Cerro Grande Fire burned primarily in mixed conifer forests on lands managed by other agencies. Some of the polygons of burn severities and fire intensities were extensive. The two largest burn severity polygons were 10,111 acres and 10,903 acres and these were burned at low severity. The next two largest polygons were 8999 acres (14 square miles) and 1551 acres (2.4 square miles) and both of these polygons

Subsurface Connections and Magma Mixing as revealed by Olivine- and Pyroxene-Hosted Melt Inclusions from Cerro Negro Volcano and the Las Pilas-El Hoyo Complex, Nicaragua.

Science.gov (United States)

Venugopal, S.; Moune, S.; Williams-Jones, G.

2015-12-01

Cerro Negro, the youngest volcano in the Central American Volcanic Belt, is a polygenetic cinder cone with relatively frequent explosive basaltic eruptions. Las Pilas, on the other hand, is a much larger and older complex with milder and less frequent eruptions. Based on historical data, these two closely spaced volcanoes have shown concurrent eruptive behavior, suggesting a subsurface connection. To further investigate this link, melt inclusions, which are blebs of melt trapped in growing crystals, were the obvious choice for optimal comparison of sources and determination of pre-eruptive volatile contents and magmatic conditions. Olivine-hosted inclusions were chosen for both volcanoes and pyroxene-hosted inclusions were also sampled from Las Pilas to represent the evolved melt. Major, volatile and trace elements reveal a distinct geochemical continuum with Cerro Negro defining the primitive end member and Las Pilas representing the evolved end member. Volatile contents are high for Cerro Negro (up to 1260 ppm CO2, 4.27 wt% H2O and 1700 ppm S) suggesting that volatile exsolution is likely the trigger for Cerro Negro's explosive eruptions. Las Pilas volatile contents are lower but consistent with degassing and evolutionary trends shown by major oxides. Trace element contents are rather unique and suggest Cerro Negro magmas fractionally crystallize while Las Pilas magmas are the products of mixing. Magmatic conditions were estimated with major and volatile contents: at least 2.4 kbar and 1170 °C for Cerro Negro melts and 1.3 kbar and 1130 °C for Las Pilas melts with an overall oxygen fugacity at the NNO buffer. In combination with available literature data, this study suggests an interconnected subsurface plumbing system and thus Cerro Negro should be considered as the newest vent within the Las Pilas-El Hoyo Complex.

Rock-magnetism and ore microscopy of the magnetite-apatite ore deposit from Cerro de Mercado, Mexico

Science.gov (United States)

Alva-Valdivia, L. M.; Goguitchaichvili, A.; Urrutia-Fucugauchi, J.; Caballero-Miranda, C.; Vivallo, W.

2001-03-01

Rock-magnetic and microscopic studies of the iron ores and associated igneous rocks in the Cerro de Mercado, Mexico, were carried out to determine the magnetic mineralogy and origin of natural remanent magnetization (NRM), related to the thermo-chemical processes due to hydrothermalism. Chemical remanent magnetization (CRM) seems to be present in most of investigated ore and wall rock samples, replacing completely or partially an original thermoremanent magnetization (TRM). Magnetite (or Ti-poor titanomagnetite) and hematite are commonly found in the ores. Although hematite may carry a stable CRM, no secondary components are detected above 580°, which probably attests that oxidation occurred soon enough after the extrusion and cooling of the ore-bearing magma. NRM polarities for most of the studied units are reverse. There is some scatter in the cleaned remanence directions of the ores, which may result from physical movement of the ores during faulting or mining, or from perturbation of the ambient field during remanence acquisition by inhomogeneous internal fields within these strongly magnetic ore deposits. The microscopy study under reflected light shows that the magnetic carriers are mainly titanomagnetite, with significant amounts of ilmenite-hematite minerals, and goethite-limonite resulting from alteration processes. Magmatic titanomagnetites, which are found in igneous rocks, show trellis, sandwich, and composite textures, which are compatible with high temperature (deuteric) oxy-exsolution processes. Hydrothermal alteration in ore deposits is mainly indicated by martitization in oxide minerals. Grain sizes range from a few microns to >100 mm, and possible magnetic state from single to multidomain, in agreement with hysteresis measurements. Thermal spectra, continuous susceptibility measurements, and IRM (isothermal remanent magnetization) acquisition suggest a predominance of spinels as magnetic carriers, most probably titanomagnetites with low

Tectonoestratigraphic and Thermal Models of the Tiburon and Wagner Basins, northern Gulf of California Rift System

Science.gov (United States)

Contreras, J.; Ramirez Zerpa, N. A.; Negrete-Aranda, R.

2014-12-01

The northern Gulf of California Rift System consist sofa series faults that accommodate both normal and strike-slip motion. The faults formed a series of half-greens filled with more than 7 km of siliciclastic suc­cessions. Here, we present tectonostratigraphic and heat flow models for the Tiburón basin, in the southern part of the system, and the Wag­ner basin in the north. The models are constrained by two-dimensional seis­mic lines and by two deep boreholes drilled by PEMEX­-PEP. Analysis of the seismic lines and models' results show that: (i) subsidence of the basins is controlled by high-angle normal faults and by flow of the lower crust, (ii) basins share a common history, and (iii) there are significant differences in the way brittle strain was partitioned in the basins, a feature frequently observed in rift basins. On one hand, the bounding faults of the Tiburón basin have a nested geometry and became active following a west-to-east sequence of activation. The Tiburon half-graben was formed by two pulses of fault activity. One took place during the protogulf extensional phase in the Miocene and the other during the opening of Gulf of California in the Pleistocene. On the other hand, the Wagner basin is the result of two fault generations. During the late-to middle Miocene, the west-dipping Cerro Prieto and San Felipe faults formed a domino array. Then, during the Pleistocene the Consag and Wagner faults dissected the hanging-wall of the Cerro Prieto fault forming the modern Wagner basin. Thermal modeling of the deep borehole temperatures suggests that the heat flow in these basins in the order of 110 mW/m2 which is in agreement with superficial heat flow measurements in the northern Gulf of California Rift System.

Trilobite-based biostratigraphy (arthropoda-trilobita) and related faunas of the Cambrian from Sonora, Mexico

Science.gov (United States)

Cuen-Romero, F. J.; Valdez-Holguín, J. E.; Buitrón-Sánchez, B. E.; Monreal, R.; Enríquez-Ocaña, L. F.; Aguirre-Hinojosa, E.; Ochoa-Granillo, J. A.; Palafox-Reyes, J. J.

2018-04-01

A biostratigraphic analysis based on trilobites of the main Cambrian outcrops from Sonora, Mexico is performed. The data are based on a combination of field work and published sources, including four previously studied locations from northern and eastern Sonora (Caborca, Cananea, Mazatán, and Arivechi) as well as a new location in the central part of the state of Sonora (San José de Gracia). Chronostratigraphic positions are assigned to the Cambrian outcrops according to Peng et al., 2012 and Cohen et al., 2017. In the Caborca area, the Puerto Blanco, Proveedora, Buelna, Cerro Prieto, Arrojos and El Tren formations comprise a wide range of biozones, which starts from the Fritzaspis Zone until the Glossopleura walcotti Zone (Begadean-Lincolnian Series, global Stage 3-Stage 5, Series 2-Series 3). The Bolsa Quartzite and the Abrigo Limestone exposed in Cananea area are assigned to the Cedaria/Cedarina dakotaensis Zone until the Crepicephalus Zone (Lincolnian Series-Marjuman Stage, global Series 3-Guzhangian). In the San José de Gracia area, The Proveedora, Buelna, Cerro Prieto and El Gavilán formations range from the ?Bristolia mohavensis or ?Bristolia insolens zones until the upper part of Mexicella mexicana Zone, Albertella highlandensis Subzone (Series 2-Series 3, Stage 4-Stage 5). In the Arivechi area, the La Sata, El Mogallón, La Huerta and the Milpillas formations range from Poliella denticulata Zone to the Elvinia Zone (Lincolnian-Millardan, Delamaran-Steptoean, global Series 3-Furongian, Stage 5-Paibian). Paleozoic marine fauna distribution in northwest Mexico and the southwest United States of America, suggest that during this time an extensive faunal province existed, containing a great variety of marine invertebrates with notorious intraspecific affinity. The biotic association includes poriferans, archaeocyathids, brachiopods, mollusks, arthropods and echinoderms as predominant elements.

Analysis of exploratory wells in the Cerro Prieto Field and the Mexicali Valley

Energy Technology Data Exchange (ETDEWEB)

Cobo R., J.M.; Bermejo M., F.J.

1982-08-10

Agricultural development in the Mexicali Valley and in the high cost of electric power required to operate the irrigation wells in the Valley prompted the Mexican government to investigate the possibility of taking advantage of thermal manifestations in the area located 28 km southeast of the city of Mexicali to generate electric power and thereby partially decrease the flight of foreign exchange. In 1958, a geologic study of the southern and southeastern zone of Mexicali was conducted to identify the possibilities of tapping geothermal resources. The purpose of this study was to gain knowledge of the geologic conditions in this area and, if possible, to establish the location of exploratory and production wells and, on the basis of the results of the former, examine the geologic history in order to gain knowledge and understanding of the structural control of the steam. On the basis of this study, it was recommended that 3 exploratory wells should be drilled in order to locate weak zones that would easily allow for steam flow.

Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

Energy Technology Data Exchange (ETDEWEB)

None

1989-12-01

On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt. The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degrees} C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3--5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

Energy Technology Data Exchange (ETDEWEB)

Carbognani, L.; Hazos, M.; Sanchez, V. (INTEVEP, Filial de Petroleos de Venezuela, SA, Caracas (Venezuela)); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

1989-12-01

On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

Impact of Santiago de Chile urban atmospheric pollution on anthropogenic trace elements enrichment in snow precipitation at Cerro Colorado, Central Andes

Science.gov (United States)

Cereceda-Balic, F.; Palomo-Marín, M. R.; Bernalte, E.; Vidal, V.; Christie, J.; Fadic, X.; Guevara, J. L.; Miro, C.; Pinilla Gil, E.

2012-02-01

Seasonal snow precipitation in the Andes mountain range is evaluated as an environmental indicator of the composition of atmospheric emissions in Santiago de Chile metropolitan area, by measuring a set of representative trace elements in snow samples by ICP-MS. Three late winter sampling campaigns (2003, 2008 and 2009) were conducted in three sampling areas around Cerro Colorado, a Central Andes mountain range sector NE of Santiago (36 km). Nevados de Chillán, a sector in The Andes located about 500 km south from the metropolitan area, was selected as a reference area. The experimental results at Cerro Colorado and Nevados de Chillán were compared with previously published data of fresh snow from remote and urban background sites. High snow concentrations of a range of anthropogenic marker elements were found at Cerro Colorado, probably derived from Santiago urban aerosol transport and deposition combined with the effect of mining and smelting activities in the area, whereas Nevados de Chillán levels roughly correspond to urban background areas. Enhanced concentrations in surface snow respect to deeper samples are discussed. Significant differences found between the 2003, 2008 and 2009 anthropogenic source markers profiles at Cerro Colorado sampling points were correlated with changes in emission sources at the city. The preliminary results obtained in this study, the first of this kind in the southern hemisphere, show promising use of snow precipitation in the Central Andes as a suitable matrix for receptor model studies aimed at identifying and quantifying pollution sources in Santiago de Chile.

Hydrothermal Processes

Science.gov (United States)

German, C. R.; von Damm, K. L.

2003-12-01

What is Hydrothermal Circulation?Hydrothermal circulation occurs when seawater percolates downward through fractured ocean crust along the volcanic mid-ocean ridge (MOR) system. The seawater is first heated and then undergoes chemical modification through reaction with the host rock as it continues downward, reaching maximum temperatures that can exceed 400 °C. At these temperatures the fluids become extremely buoyant and rise rapidly back to the seafloor where they are expelled into the overlying water column. Seafloor hydrothermal circulation plays a significant role in the cycling of energy and mass between the solid earth and the oceans; the first identification of submarine hydrothermal venting and their accompanying chemosynthetically based communities in the late 1970s remains one of the most exciting discoveries in modern science. The existence of some form of hydrothermal circulation had been predicted almost as soon as the significance of ridges themselves was first recognized, with the emergence of plate tectonic theory. Magma wells up from the Earth's interior along "spreading centers" or "MORs" to produce fresh ocean crust at a rate of ˜20 km3 yr-1, forming new seafloor at a rate of ˜3.3 km2 yr-1 (Parsons, 1981; White et al., 1992). The young oceanic lithosphere formed in this way cools as it moves away from the ridge crest. Although much of this cooling occurs by upward conduction of heat through the lithosphere, early heat-flow studies quickly established that a significant proportion of the total heat flux must also occur via some additional convective process (Figure 1), i.e., through circulation of cold seawater within the upper ocean crust (Anderson and Silbeck, 1981). (2K)Figure 1. Oceanic heat flow versus age of ocean crust. Data from the Pacific, Atlantic, and Indian oceans, averaged over 2 Ma intervals (circles) depart from the theoretical cooling curve (solid line) indicating convective cooling of young ocean crust by circulating seawater

Fire Management Lessons Learned From the Cerro Grande (Los Alamos) Fire and Actions Needed to Reduce Fire Risks

National Research Council Canada - National Science Library

Hill, Barry

2000-01-01

We are here today to discuss two related issues, lessons learned from the recent Cerro Grande fire, and, on a broader note, actions needed to mitigate current hazardous forest conditions in the interior West...

New K-Ar ages of volcanic rocks and associated mineralization in Canada Honda district, San Luis, Argentina

International Nuclear Information System (INIS)

Urbina, N.E.; Oggier, F.P

2001-01-01

New K-Ar ages in the Late Tertiary gold-bearing volcanic belt of the Sierras Pampeanas of San Luis, Argentina are presented. At Canada Honda district, an age of 8.49±0.2 Ma yielded by Cerro del Valle andesite indicates that the dome emplacement postdates the Diente Verde eruptive event. An even younger age of 7.3±0.2 Ma was obtained for illite from hydrothermal alteration at La Reynela mineralization which is hosted by Cerro del Valle andesite (au)

Mexican geothermal development and the future

International Nuclear Information System (INIS)

Serrano, J.M.E.V.

1998-01-01

Geothermics in Mexico started in 1954, by drilling the first geothermal well in Pathe, State of Hidalgo, which reached a depth of 237 meters. In 1959 electrical generation from geothermal origin began, with an installed capacity of 3.5 MW. From 1959 to 1994 Mexico increased its installed capacity to 753 MW, by developing three geothermal fields: Cerro Prieto, Los Azufres, and Los Humeros. Currently, 177 wells produce steam at a rate of 36 tons per hour (t/h) each. Comision Federal de Electricidad (CFE, Federal Commission of Electricity) has planned to increase the geothermal-electric installed capacity through construction and installation of several projects. Repowering of operating units and development of new geothermal zones will also allow Mexican geothermal growth

Cerro Grande Fire Impact to Water Quality and Stream Flow near Los Alamos National Laboratory: Results of Four Years of Monitoring

Energy Technology Data Exchange (ETDEWEB)

B.M. Gallaher; R.J. Koch

2004-09-15

In May 2000, the Cerro Grande fire burned about 7400 acres of mixed conifer forest on the Los Alamos National Laboratory (LANL), and much of the 10,000 acres of mountainside draining onto LANL was severely burned. The resulting burned landscapes raised concerns of increased storm runoff and transport of contaminants by runoff in the canyons traversing LANL. The first storms after the fire produced runoff peaks that were more than 200 times greater than prefire levels. Total runoff volume for the year 2000 increased 50% over prefire years, despite a decline in total precipitation of 13% below normal and a general decrease in the number of monsoonal thunderstorms. The majority of runoff in 2000 occurred in the canyons at LANL south of Pueblo Canyon (70%), where the highest runoff volume occurred in Water Canyon and the peak discharge occurred in Pajarito Canyon. This report describes the observed effects of the Cerro Grande fire and related environmental impacts to watersheds at and near Los Alamos National Laboratory (LANL) for the first four runoff seasons after the fire, from 2000 through 2003. Spatial and temporal trends in radiological and chemical constituents that were identified as being associated with the Cerro Grande fire and those that were identified as being associated with historic LANL discharges are evaluated with regard to impacts to the Rio Grande and area reservoirs downstream of LANL. The results of environmental sampling performed by LANL, the New Mexico Environment Department (NMED), and U.S. Geological Survey (USGS) after the Cerro Grande fire are included in the evaluation. Effects are described for storm runoff, baseflow, stream sediments, and area regional reservoir sediment.

El recorrido al Cerro Gordo y el ritual tepehuano de las ofrendas en los cerros de la comunidad de San Bernardino de Milpillas

Directory of Open Access Journals (Sweden)

Chantal CRAMAUSSEL

2014-01-01

Full Text Available El ritual de las ofrendas es una ceremonia propiciatoria de la lluvia que se efectúa al terminar la estación seca en los cerros más altos de la comunidad de San Bernardino de Milpillas Chico, en la Sierra Tepehuana del estado de Durango. A esos rituales distintos de los cató- licos que forman parte del ciclo anual de costumbre concurren las autoridades civiles, los curanderos y miembros del Consejo de ancianos. Es un momento muy importante en el que se refuerza la cohesión de los tepehuanos que tienen un patrón de asentamiento muy disperso, como los demás grupos del norte, pero sus rituales presentan también similitudes con los mesoamericanos.

Petrografía, caracterización geoquímica y análisis microestructural del granito del cerro Siempre Amigos, sierras de Azul, Tandilia

OpenAIRE

Angeletti, Melisa; Frisicale, María Cristina; Dimieri, Luis V

2016-01-01

El cerro Siempre Amigos integra las sierras de Azul, Tandilia, distante 28 km al sur de la ciudad de Azul y 3 km al norte de la megacizalla de Azul, zona de cizalla subvertical donde el basamento se encuentra deformado a milonitas y ultramilonitas. La litología predominante en el cerro Siempre Amigos es un granito paleoproterozoico deformado que en el centro y hacia los bordes se encuentra interdigitado con una roca gnéisica y cuerpos de anfibolitas subverticales de rumbo similar a la foliaci...

Complexing and hydrothermal ore deposition

CERN Document Server

Helgeson, Harold C

1964-01-01

Complexing and Hydrothermal Ore Deposition provides a synthesis of fact, theory, and interpretative speculation on hydrothermal ore-forming solutions. This book summarizes information and theory of the internal chemistry of aqueous electrolyte solutions accumulated in previous years. The scope of the discussion is limited to those aspects of particular interest to the geologist working on the problem of hydrothermal ore genesis. Wherever feasible, fundamental principles are reviewed. Portions of this text are devoted to calculations of specific hydrothermal equilibriums in multicompone

ANALYSIS OF MUNICIPAL WASTEWATER AND ACID MINE DRAINAGE PASSIVE CO-TREATMENT AT CERRO RICO DE POTOSÍ, BOLIVIA

Directory of Open Access Journals (Sweden)

William H.J. Strosnider

2015-06-01

Full Text Available Acid mine drainage (AMD is a worldwide environmental problem. The passive co-treatment of AMD with municipal waste water (MWW is a cost effective approach that uses nutrients in MWW in order to treat high concentrations of metals and sulfate found in AMD. Cerro Rico de Potosí in Bolivia is one of the biggest mining cities in the world, and it is constantly facing problems with AMD. The goal of this study was to determine the reaction rates of Al, Fe, Mn, Zn, and other metals found in an AMD discharge from Cerro Rico by a three-stage reactor system. The AMD had a pH of 3.58 and acidity of 1080 mg/L as CaCO3 equivalent containing 12, 68, 17 and 550 mg/L of dissolved Al, Fe, Mn, and Zn respectively. The reaction rates of Al, Fe, Mn, and Zn were 1.43, 2.09, 0.01, and 0.10 d-1, respectively.

Spanish exiles and the dilemma of the Cold War. Prieto, Esplá, Araquistáin and Llopis | Exiliados españoles en la encrucijada de la Guerra Fría. Prieto, Esplá, Araquistáin y Llopis

Directory of Open Access Journals (Sweden)

Pedro Luis Angosto Vélez

2003-12-01

Full Text Available Personal attitudes were a determining factor in the position of Spanish Republican exiles regarding the question of restoring democracy in Spain at the beginning of the Cold War. After the Second World War had ended, many exiles came cherish a hope that such a development might be possible with the help of the victorious democracies, particularly the United States and the United Kingdom. They failed, however, to reach agreement as to which tactic to use in order to enlist this help, with some arguing in favour of giving the leading role to the government in exile, while others felt it was preferable to strike an agreement between all Spanish anti-Francoist groups in order to present a united democratic front to the new international institutions which had emerged in the post-war climate. The subtleties of both positions may be examined through a study of influential figures such as Indalecio Prieto, Carlos Esplá, Rodolfo Llopis and Luis Araquistán, of whom we now have a greater knowledge thanks to recent biographies, which form the basis of this work. | Las actitudes personales es un factor determinante de la posición del exilio republicano español ante el problema de la restauración de la democracia en España en la coyuntura del inicio de la Guerra Fría. Finalizada la Segunda Guerra Mundial, en los medios del exilio se generalizó la esperanza de que tal cosa era posible gracias a la ayuda de las democracias vencedoras, en particular de Estados Unidos y el Reino Unido. Sin embargo, no hubo unanimidad sobre la táctica a seguir para recabar esa ayuda, pues mientras unos abogaron por conceder el máximo protagonismo al gobierno en el exilio, otros consideraron más oportuno establecer un acuerdo entre las fuerzas antifranquistas españolas para presentar un frente democrático unido ante las nuevas instituciones internacionales surgidas del conflicto mundial. Ambas posturas presentan matices que pueden ser examinados a partir del talante

LA ARQUITECTURA DE TIERRA Y LAS OCUPACIONES HUMANAS EN EL SITIO ARQUEOLÓGICO CERRO PUÑAY, CANTÓN CHUNCHI, PROVINCIA DE CHIMBORAZO, ECUADOR (Earth Architecture and Human Occupations at Cerro Puñay Archaeological Site, Chunchi Canton, Chimborazo Province, Ecuador

Directory of Open Access Journals (Sweden)

Mary Jadán V.

2017-06-01

Full Text Available Este artículo se refiere a la arquitectura de tierra del sitio arqueológico Cerro Puñay, ubicado al sur de la provincia de Chimborazo. Algunos perfiles estratigráficos de diferentes partes del cerro demuestran que existen cambios relacionados con la estructura del sitio: un reforzamiento de talud en la cima central, arqueosedimentos en ciertos sectores, nivelación de las cimas, construcción de terrazas, entre otras modificaciones. Aunque hay evidencias de ocupación desde el Formativo Tardío con la cultura narrío (2000-1600 a. C., las edificaciones se iniciaron con la sociedad cañari (500-1460 d. C.. Por otra parte, el sitio evidencia una reconstrucción y utilización por parte de la sociedad inca (1460-1533 d. C.. ENGLISH: This article refers to the land architecture of the Cerro Puñay archaeological site, located to the south of the province of Chimborazo. Some stratigraphic profiles, from different parts of the hill, show that there are changes related to the structure of the site: a reinforcement of slope in the central summit, archaeological sediments in certain sectors, leveling of the tops, and construction of terraces, among other modifications. Although there is evidence of occupation from the Late Formative with the Narrío culture (2000–1600 BC, the construction started with the Cañari society (500–1460 AD. On the other hand, the site shows evidence of a reconstruction and use by the Inca society (1460–1533 AD.

Hydrothermal liquefaction of biomass

DEFF Research Database (Denmark)

Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

2011-01-01

This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

Hydrothermal Growth of Polyscale Crystals

Science.gov (United States)

Byrappa, Kullaiah

In this chapter, the importance of the hydrothermal technique for growth of polyscale crystals is discussed with reference to its efficiency in synthesizing high-quality crystals of various sizes for modern technological applications. The historical development of the hydrothermal technique is briefly discussed, to show its evolution over time. Also some of the important types of apparatus used in routine hydrothermal research, including the continuous production of nanosize crystals, are discussed. The latest trends in the hydrothermal growth of crystals, such as thermodynamic modeling and understanding of the solution chemistry, are elucidated with appropriate examples. The growth of some selected bulk, fine, and nanosized crystals of current technological significance, such as quartz, aluminum and gallium berlinites, calcite, gemstones, rare-earth vanadates, electroceramic titanates, and carbon polymorphs, is discussed in detail. Future trends in the hydrothermal technique, required to meet the challenges of fast-growing demand for materials in various technological fields, are described. At the end of this chapter, an Appendix 18.A containing a more or less complete list of the characteristic families of crystals synthesized by the hydrothermal technique is given with the solvent and pressure-temperature (PT) conditions used in their synthesis.

Description of a New Galapagos Giant Tortoise Species (Chelonoidis; Testudines: Testudinidae from Cerro Fatal on Santa Cruz Island.

Directory of Open Access Journals (Sweden)

Nikos Poulakakis

Full Text Available The taxonomy of giant Galapagos tortoises (Chelonoidis spp. is currently based primarily on morphological characters and island of origin. Over the last decade, compelling genetic evidence has accumulated for multiple independent evolutionary lineages, spurring the need for taxonomic revision. On the island of Santa Cruz there is currently a single named species, C. porteri. Recent genetic and morphological studies have shown that, within this taxon, there are two evolutionarily and spatially distinct lineages on the western and eastern sectors of the island, known as the Reserva and Cerro Fatal populations, respectively. Analyses of DNA from natural populations and museum specimens, including the type specimen for C. porteri, confirm the genetic distinctiveness of these two lineages and support elevation of the Cerro Fatal tortoises to the rank of species. In this paper, we identify DNA characters that define this new species, and infer evolutionary relationships relative to other species of Galapagos tortoises.

Status of geothermal resources in Mexico

International Nuclear Information System (INIS)

Le-Bert, G.

1990-01-01

Except for some isolated instances with tourist or therapeutic objectives and some attempts in the Cerro Prieto geothermal field, there are no projects for direct heat utilization of geothermal resources in Mexico. Therefore, all places that are studied are studied with geothermal-electric objectives. It is convenient to keep in mind that in Mexico, by law, the Comision Federal de Electricidad (CFE) is the public utility in charge of electrical energy service. This institution is directly responsible for the exploration, development and commercial use of geothermal energy for electrical generation. Therefore, this paper includes the present and planned exploration and utilization of geothermal resources only for electricity generation for the period 1985 to the present. Likewise, starting 5 years ago, the CFE efforts have been directed toward the development of high enthalpy fields

Distribution of hydrothermal fluid around the ore body in the subseafloor of the Izena hydrothermal field

Science.gov (United States)

Toki, T.; Otake, T.; Ishibashi, J. I.; Matsui, Y.; Kawagucci, S.; Kato, H.; Fuchida, S.; Miyahara, R.; Tsutsumi, A.; Kawakita, R.; Uza, H.; Uehara, R.; Shinjo, R.; Nozaki, T.; Kumagai, H.; Maeda, L.

2017-12-01

From 16th November to 15th December 2016, D/V Chikyu drilled the sea bottom around hydrothermal fields at HAKUREI site in the Izena Hole, Okinawa Trough. Site C9025, C9026, C9027, C9028, and C9032 are located along the transect line from the top of the northern mound of HAKUREI site to the eastward, and Site C9030 for the control site is located about 500 m northwest of the mound. Mg concentrations have generally been used to estimate mixing ratios between hydrothermal end-member and seawater in samples from hydrothermal vents. Higher Mg concentrations, however, were detected in the interstitial water than that of seawater, which could be due to artificially dissolution of Mg-bearing minerals that had formed in in-situ environments, when the cored sediments had become cool after their recovery on ship. Similar features were observed with regard to sulfate concentrations, and it suggests that these chemical species are not suitable to estimate quantitatively the contribution of hydrothermally-derived components. In some layers, chloride concentrations were different from that of seawater, indicating that hydrothermal fluids that had been suffered from phase separation flowed into the layers. The deviation, however, was positive or negative relative to that of seawater for an influence of brine or vapor phase, respectively. Therefore chloride concentrations are also not suitable to evaluate a quantitative contribution of hydrothermal end-member. On the other hand, K and B showed only enrichments relative to the seawater, and their highest concentrations are consistent with the reported hydrothermal end-members of each species at HAKUREI site. Using the concentrations of K and B can be evaluated for an influence of hydrothermal components. Furthermore, the headspace gas data are useful in the layers of sulfide minerals and silicified rocks, even though the interstitial waters could not be obtained because of their hardness. Based on these indices, hydrothermal fluids

Uranium prospecting in Cerro Partido Region-Encruzilhada do Sul Basin-RS, Brazil

International Nuclear Information System (INIS)

Fraenkel, M.O.

1974-01-01

The Cerro Partido residual basin is a shallow (85 meters) and small (25km 2 ) sedimentary basin, a remainder of the erosive cicle, enclosed in the pre-cambrian granitic rocks of the Rio Grande do Sul Shield. Grades of 0.2 + U 3 O 8 were found in its upper-paleozoic sandstones and shales drilles for uranium. The small size and thicknesses of these concentrations prevent their economic mining. However, the different levels of the shield exposed by tectonics, the intrusive granitic, riolitic and syenitic rocks, the anomalous uranium contents in sedimentary and crystalline rocks recommend further investigations on the shield area

Radiogeochemical features of hydrothermal metasomatic formations

International Nuclear Information System (INIS)

Plyushchev, E.V.; Ryabova, L.A.; Shatov, V.V.

1978-01-01

Considered are the most general peculiarities of uranium and thorium distributions in hydrothermal-metasomatic formations of three levels of substance formation: 1) in hydrothermal minerals; 2) in natural associations of these minerals (in the altered rocks, metasomatites, ores, etc.); 3) ordened series of zonally and in stage conjugated hydrothermal-metasomatic formations. Statistically stable recurrence of natural combinations of hydrothermal-metasomatic formations points out conjugation of their formation in the directed evolution in the general hydrothermal process. Series of metasomatic formations, the initial members of which are potassium metasomatites, mostly result in accumulation up to industrial concentrations of radioactive elements in final members of these formations. Development of midlow-temperature propylitic alterations in highly radiative rocks causes the same accumulation

Consideration of the ultramafic intrusive rocks in Arroyo Las Palmas (ex Cerro Chato - Las Canias) Durazno. R. O. del Uruguay

International Nuclear Information System (INIS)

Coronel, N.

1987-01-01

This work is about the ultramafic rocks which its chemistry composition fluctuate since the basic to the ultra basic field and appear in the nascent of the Las Palmas stream near Las Canias and Cerro Chato district.

Synthesis of the works of geophysical (electrical soundings) carried out in the region of the anomalies of Yerba Sola (Cerro Largo) Uruguay

International Nuclear Information System (INIS)

Perrin, J.

1983-01-01

In this report has been studied geographical localization, geology, geophysics prospection, equipment and methods used and their results in Yerba Sola anomalies Province Cerro Largo and Fraile Muerto formation

Importaciones áticas del siglo V a.C. del Cerro del Prado (Algeciras, Cádiz

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Cabrera, Paloma

1996-12-01

Full Text Available In this paper we analyze a group of Attic imports, found in the excavations of Cerro del Prado, a settlement situated in the Bahía de Algeciras (Cádiz. The great interest of this group lies in the fact that it belongs to a particular chronological period, the last third of the 5th century B.C., as we have not found later imports, and in the almost exclusive presence of black glazed vases, which gives US an idea of a very definitive demand of the punic society of the Iberian Peninsula regarding the trade of greek goods.

Presentamos en este trabajo un conjunto de importaciones áticas halladas en las excavaciones del Cerro del Prado, situado en la bahía de Algeciras (Cádiz. El interés de este conjunto reside en su pertenencia a un momento cronológico muy concreto: el último tercio del siglo V a.C., no habiéndose hallado importaciones más modernas y en la presencia absoluta de vasos de barniz negro, lo que nos habla de una demanda muy determinada de la sociedad púnica peninsular frente al comercio de productos griegos.

Evaluation of the Cerro Solo nuclear ore, province of Chubut. Geological characteristics of the deposit and of the basin. Pt. 2

International Nuclear Information System (INIS)

Benitez, A.F.; Fuente, A.; Maloberti, A.; Landi, V.A.; Bianchi, R.E.; Marveggio de Bianchi, N.; Gayone, M.R.

1993-01-01

The Cerro Solo uranium ore deposit, is located 420 km west from Trelew city, Chubut province, in the extra-andean. The geologic environment belongs to the northwest edge portion of the intracratonic San Jorge Gulf Basin. The uraniferous district is named Pichinanes Ridge district. The mineralization lies 25 to 130 m depth, and is hosted by Los Adobes formation aged Aptian-Albian, made up by conglomerates, sandstones, coarse-sandstones and less abundant siltstones and claystones. The Cerro Solo ore deposit that belongs to the sandstone type-uranium occurrences are lenticular or tabular shaped, associated with organic material and pyrite, generally roughly parallel to the bedding (Trend-Type). The uranium minerals are uraninite and coffinite associated with organic material and pyrite, and frequently hematite, goethite, calcite, siderite and barite are observed. (Author)

Seawater bicarbonate removal during hydrothermal circulation

Science.gov (United States)

Proskurowski, G. K.; Seewald, J.; Sylva, S. P.; Reeves, E.; Lilley, M. D.

2013-12-01

High temperature fluids sampled at hydrothermal vents represent a complex alteration product of water-rock reactions on a multi-component mixture of source fluids. Sources to high-temperature hydrothermal samples include the 'original' seawater present in the recharge limb of circulation, magmatically influenced fluids added at depth as well as any seawater entrained during sampling. High-temperature hydrothermal fluids are typically enriched in magmatic volatiles, with CO2 the dominant species, characterized by concentrations of 10's-100's of mmol/kg (1, 2). Typically, the high concentration of CO2 relative to background seawater bicarbonate concentrations (~2.3 mmol/kg) obscures a full analysis of the fate of seawater bicarbonate during high-temperature hydrothermal circulation. Here we present data from a suite of samples collected over the past 15 years from high-temperature hydrothermal vents at 9N, Endeavour, Lau Basin, and the MAR that have endmember CO2 concentrations less than 10 mmol/kg. Using stable and radiocarbon isotope measurements these samples provide a unique opportunity to examine the balance between 'original' seawater bicarbonate and CO2 added from magmatic sources. Multiple lines of evidence from multiple hydrothermal settings consistently points to the removal of ~80% of the 'original' 2.3 mmol/kg seawater bicarbonate. Assuming that this removal occurs in the low-temperature, 'recharge' limb of hydrothermal circulation, this removal process is widely occurring and has important contributions to the global carbon cycle over geologic time. 1. Lilley MD, Butterfield DA, Lupton JE, & Olson EJ (2003) Magmatic events can produce rapid changes in hydrothermal vent chemistry. Nature 422(6934):878-881. 2. Seewald J, Cruse A, & Saccocia P (2003) Aqueous volatiles in hydrothermal fluids from the Main Endeavour Field, northern Juan de Fuca Ridge: temporal variability following earthquake activity. Earth and Planetary Science Letters 216(4):575-590.

Experimental and petrological constraints on long-term magma dynamics and post-climactic eruptions at the Cerro Galán caldera system, NW Argentina

Science.gov (United States)

Grocke, Stephanie B.; Andrews, Benjamin J.; de Silva, Shanaka L.

2017-11-01

Cerro Galán in NW Argentina records > 3.5 Myr of magmatic evolution of a major resurgent caldera complex. Beginning at 5.72 Ma, nine rhyodacitic ignimbrites (68-71 wt% SiO2) with a combined minimum volume of > 1200 km3 (Dense Rock Equivalent; DRE) have been erupted. The youngest of those ignimbrites is the eponymous, geochemically homogenous, caldera-forming 2.08 ± 0.02 Ma Cerro Galán Ignimbrite (CGI; > 630 km3 DRE). Following this climactic supereruption, structural and magmatic resurgence led to the formation of a resurgent dome and post-climactic lava domes and their associated pyroclastic deposits. A clear transition from amphibole to sanidine-bearing magmas occurred during the evolution of Cerro Galán and is inferred to represent a shallowing of the magma system. We test this hypothesis here using experimental phase equilibria. We conducted a series of phase equilibria experiments on the post-climactic dome lithologies under H2O-saturated conditions using cold seal Waspaloy pressure vessels with an intrinsic log fO2 of NNO + 1 ± 0.5 across a temperature-pressure range of 750-900 °C and 50-200 MPa (PH2O = Ptotal), respectively. Petrologic and geochemical analysis of the post-climactic lithologies shows that the natural phase assemblage (plagioclase + quartz + biotite + sanidine + Fe-Ti oxides ± apatite ± zircon) is stable at history of Cerro Galán is informed through a detailed investigation of the textural differences among the post-climactic dome lithologies, and a comparison of those textures with previously published decompression experiments. These suggest that the highly vesiculated, pumiceous clasts with rare microlites represent magma stored within the core of the lava dome that decompressed relatively rapidly (0.003-0.0003 MPa s-1) and evolved via closed system degassing. Resulting over-pressure of the dome may have triggered superficial explosion. In contrast, dense clasts with abundant crystalline silica precipitates represent more typical

ESTUDIO PRELIMINAR DE LA FAUNA AMPHIBIA EN EL CERRO MURRUCUCÚ, PARQUE NATURAL NACIONAL PARAMILLO Y ZONA AMORTIGUADORA, TIERRALTA, CÓRDOBA, COLOMBIA

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ROMERO-MARTÍNEZ HERÓN JOSÉ

2008-07-01

Full Text Available Con el objetivo de estudiar la fauna anfibia en el Cerro Murrucucú (PNN Paramillo,Tierralta, Córdoba, se realizaron muestreos durante los meses de diciembre de2004, enero y febrero de 2005 en diferentes localidades; se utilizaron dos estrategiasde muestreo (búsqueda libre por inspección visual y trampas de caída. En primerainstancia se comparó la riqueza y la abundancia de las especies en tres zonasaltitudinales en uno de los sectores mejor conservados del Cerro. Se encontró queen la parte baja y media predominan las especies de la familia Hylidae, mientras queen la parte alta predominan representantes de la familia Brachycephalidae, en sumayoría especies del género Eleutherodactylus. Se registran 52 especies para el CerroMurrucucú, que representan el 8% del total de especies en Colombia y más del 80% delas documentadas para el Departamento de Córdoba; las cuales están agrupadas en dosórdenes, 10 familias y 26 géneros. Las familias más representativas, Brachycephalidaee Hylidae, concentran un poco más del 50% de las especies. También se registraronpor primera vez 18 especies para el Departamento de Córdoba y se amplia el rangode distribución geográfico de 18 especies y altitudinal de siete de estas. Se tiene elprimer registro de Eleutherodactylus cruentus para Colombia y el primero de E. viejaspara la Cordillera Occidental Colombiana

Chemical environments of submarine hydrothermal systems

Science.gov (United States)

Shock, Everett L.

1992-01-01

Perhaps because black-smoker chimneys make tremendous subjects for magazine covers, the proposal that submarine hydrothermal systems were involved in the origin of life has caused many investigators to focus on the eye-catching hydrothermal vents. In much the same way that tourists rush to watch the spectacular eruptions of Old Faithful geyser with little regard for the hydrology of the Yellowstone basin, attention is focused on the spectacular, high-temperature hydrothermal vents to the near exclusion of the enormous underlying hydrothermal systems. Nevertheless, the magnitude and complexity of geologic structures, heat flow, and hydrologic parameters which characterize the geyser basins at Yellowstone also characterize submarine hydrothermal systems. However, in the submarine systems the scale can be considerably more vast. Like Old Faithful, submarine hydrothermal vents have a spectacular quality, but they are only one fascinating aspect of enormous geologic systems operating at seafloor spreading centers throughout all of the ocean basins. A critical study of the possible role of hydrothermal processes in the origin of life should include the full spectrum of probable environments. The goals of this chapter are to synthesize diverse information about the inorganic geochemistry of submarine hydrothermal systems, assemble a description of the fundamental physical and chemical attributes of these systems, and consider the implications of high-temperature, fluid-driven processes for organic synthesis. Information about submarine hydrothermal systems comes from many directions. Measurements made directly on venting fluids provide useful, but remarkably limited, clues about processes operating at depth. The oceanic crust has been drilled to approximately 2.0 km depth providing many other pieces of information, but drilling technology has not allowed the bore holes and core samples to reach the maximum depths to which aqueous fluids circulate in oceanic crust. Such

Hydrothermal synthetic strategies of inorganic semiconducting nanostructures.

Science.gov (United States)

Shi, Weidong; Song, Shuyan; Zhang, Hongjie

2013-07-07

Because of their unique chemical and physical properties, inorganic semiconducting nanostructures have gradually played a pivotal role in a variety of research fields, including electronics, chemical reactivity, energy conversion, and optics. A major feature of these nanostructures is the quantum confinement effect, which strongly depends on their size, shape, crystal structure and polydispersity. Among all developed synthetic methods, the hydrothermal method based on a water system has attracted more and more attention because of its outstanding advantages, such as high yield, simple manipulation, easy control, uniform products, lower air pollution, low energy consumption and so on. Precise control over the hydrothermal synthetic conditions is a key to the success of the preparation of high-quality inorganic semiconducting nanostructures. In this review, only the representative hydrothermal synthetic strategies of inorganic semiconducting nanostructures are selected and discussed. We will introduce the four types of strategies based on exterior reaction system adjustment, namely organic additive- and template-free hydrothermal synthesis, organic additive-assisted hydrothermal synthesis, template-assisted hydrothermal synthesis and substrate-assisted hydrothermal synthesis. In addition, the two strategies based on exterior reaction environment adjustment, including microwave-assisted and magnetic field-assisted hydrothermal synthesis, will be also described. Finally, we conclude and give the future prospects of this research area.

Paracas Cultural Readaptation To The Nasca Entity: An Approach From The Settlement Of Cerro Cordova

OpenAIRE

Llanos Jacinto, Oscar Daniel

2017-01-01

Except rare exceptions, the Paracas society of the Ica valley has been extensively studied from decontextualized materials, including pottery collected from clandestine tomb excavations in the Ocucaje basin. From the stylistic analysis of these pieces, which also included Nasca specimens, the hypothesis was elaborated that assumed the birth from the Paracas, expressed in the well-known axiom «transition paracas-nasca». The works carried out in Cerro Córdova and those that since 2009 are carri...

Works carried out in the south of Cerro Largo district. Uranium prospection programme. Preliminary report

International Nuclear Information System (INIS)

Goso, H.

1978-01-01

During the carried out work of radimetric preliminary Investigation in the northeast of the uraniferous country were detected radimetric anonalias which are associated to the formation San Gregorio and Tres Islas. Later the works of prospection ratified those anomalies to which they defined in the environs other anomalies. The studies of revision of these conducted anomalies they took to conclude the necessity to carry out a detailed study of the area to that district was denominated Cerro Largo Sur

The rules of urban planning and administrative responsibilities in protecting to the vulnerability and risk of Cerro Tapezco in Santa Ana

International Nuclear Information System (INIS)

Castro Leiton, Karina

2014-01-01

An analysis of regulation is made of land use and administrative management of the Cerro Tapezco to show that as the years have passed it has been verified that the Costa Rican law on town planning has been inadequate for current problems due to lack of updating of various scientific and technical sources also dispersion and proliferation of competences of administrative authorities. The physical setting and planning rules is identified for CerroTapezco and surrounding towns. Local actions are explored in the elaboration of improvement and reform of the regulatory plan of Santa Ana. The administrative entities and institutions with competence in the development and implementation of plans have been identified, assessing deficiencies, inconsistencies and administrative omissions in urban planning of the city of Santa Ana and recommending changes necessary for the proper application of the Costa Rican law [es

Grado de discapacidad en pacientes hemipléjicos del "Policlínico Docente Universitario del Cerro" Evaluation of disability in hemiplegic patients from Cerro university teaching polyclinic

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Abel Estévez Perera

2012-12-01

Full Text Available Introducción: la hemiplejía como consecuencia de un ictus constituye una importante causa de discapacidad. La continuidad y calidad en el proceso rehabilitador supone mejores perspectivas en el pronóstico de los pacientes. Objetivo: evaluar el grado de discapacidad en los pacientes hemipléjicos del área de salud del Policlínico Docente Universitario del Cerro. Métodos: estudio descriptivo, transversal en los pacientes que acudieron consecutivamente al área de rehabilitación del citado policlínico, desde septiembre de 2009 hasta julio de 2011. La muestra estuvo constituida por 124 hemipléjicos por enfermedad cerebrovascular mayores de 15 años, los cuales fueron evaluados con la Escala de Discapacidad de Rosetón. Se excluyeron los enfermos con afasia sensorial o mixta y aquellos que se negaron a participar. Resultados: en 84 (67,8 % pacientes se encontró independencia para la orientación y predominó la semidependencia para el desplazamiento y las necesidades físicas. Para la higiene personal, 48 (38,7 % pacientes resultaron ser dependientes. La falta de motivación para ocupar el tiempo libre se encontró en 92 (74,2 % pacientes, casi siempre por dificultades en la convivencia y en las relaciones familiares. Conclusiones: el grado de discapacidad de los pacientes hemipléjicos evaluados viene dado por la semidependencia en el desplazamiento y las necesidades físicas y la dependencia para el autocuidado. Las dificultades en la convivencia y las relaciones familiares interfieren en la motivación del paciente para ocupar el tiempo libre.Introduction: hemiplegia is an important cause of disability as a result of a stroke. The persistence and quality of the rehabilitative process lead to better results in the patient prognosis. Objective: to evaluate the extent of disability in hemiplegic patients from the health area under "Cerro" university teaching polyclinics. Methods: a cross-sectional and descriptive study was conducted in

Dynamics of the Yellowstone hydrothermal system

Science.gov (United States)

Hurwitz, Shaul; Lowenstern, Jacob B.

2014-01-01

The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.

Cerro Amarillo rhyolites, advanced AFC in the northern SVZ, Chile

International Nuclear Information System (INIS)

Godoy, E; Hildreth, W

2001-01-01

Cerro Amarillo is a Quaternary medium size (500m high, 2 km 2 ) rhyolite dome complex located close to the Chile-Argentina border, reaching a height of 4162 m, between the headwaters of the Rio Colina and the Nieves Negras Pass. It overlies a broad anticline of thick Middle Jurassic pelites (Alvarez et al., 1997). Thiele (1980) includes this complex in his 'Unidad Volcanica Antigua', a Pleistocene composite map unit made up of andesites and trachyandesites. Ramos et al. (1997), while recognizing its rhyolitic character, assigned a Tertiary age to the lava domes, most likely based on the late Pliocene age of silicic dikes outcropping eastward, in Argentina. Both the lack of younger overlying units and freshness of its components, together with preservation of the unconsolidated, easily eroded pyroclastic deposits at its base, suggest, however, that it is not older than Pleistocene (au)

Trace Element Geochemistry of Silica Phases: Understanding the Evolution of the Cerro Pabellón Geothermal System

Science.gov (United States)

Alvear, B.; Morata, D.; Leisen, M.; Reich, M.; Barra, F.

2017-12-01

The study of mineral textures coupled with trace element geochemistry has proven to be a useful tool to understand the evolution of geological environments. The purpose of this study is to provide new constrains on the formation of an active geothermal system, specifically the Cerro Pabellón field. The Cerro Pabellón system is located at 4500 m above sea level and is the first geothermal power plant in operation in Chile and South America. Thirteen samples were collected from a 550 m long drill core. Samples were first studied under petrographic microscopy followed by scanning electron microscopy coupled with a cathodoluminescence detector (CL-SEM). The different textures recognized using petrography and the CL-SEM technique were later analyzed by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) in order to determine variations in the trace element concentrations as a function of silica textures. Two vein types (A and B) with different silica polymorphs were identified by CL-SEM. Vein type A has only a colloform texture, whereas vein type B, younger and crosscutting the type A, shows zonation, colloform, and jigsaw textures. LA-ICPMS results show high concentrations of Li, Al, Na, K, As, and Sb for all types of silica. A comparison between vein type A and B, show that vein type A is Al-Na-K-Li poor (2088, 36, 309, and 122 ppm average, respectively) and As-Sb rich (43 and 249 ppm average, respectively). On the other hand, vein type B has variable concentrations of Al-Na-K-Li-Sb, but usually higher than in vein type A. Overall, the Cerro Pabellón geothermal system shows high concentrations of Li and Sb, reaching up to 360 and 703 ppm, respectively. Our preliminary results show that the trace element geochemistry is strongly related to the different silica textures, which formed as a response to different thermodynamic conditions and fluid-rock ratios. This work is a contribution to the FONDAP-CONICYT 15090013 Project.

A thermoelectric cap for seafloor hydrothermal vents

International Nuclear Information System (INIS)

Xie, Yu; Wu, Shi-jun; Yang, Can-jun

2016-01-01

Highlights: • We developed a thermoelectric cap (TC) to harvest hydrothermal energy. • The TC was deployed at a hydrothermal vent site near Kueishantao islet, Taiwan. • The TC monitored the temperature of the hydrothermal fluids during the field test. • The TC could make the thermal energy of hydrothermal fluids a viable power source. - Abstract: Long-term in situ monitoring is crucial to seafloor scientific investigations. One of the challenges of operating sensors in seabed is the lifespan of the sensors. Such sensors are commonly powered by batteries when other alternatives, such as tidal or solar energy, are unavailable. However, the batteries have a limited lifespan and must be recharged or replaced periodically, which is costly and impractical. A thermoelectric cap, which harvests the thermal energy of hydrothermal fluids through a conduction pipe and converts the heat to electrical energy by using thermoelectric generators, was developed to avoid these inconveniences. The thermoelectric cap was combined with a power and temperature measurement system that enables the thermoelectric cap to power a light-emitting diode lamp, an electronic load (60 Ω), and 16 thermocouples continuously. The thermoelectric cap was field tested at a shallow hydrothermal vent site near Kueishantao islet, which is located offshore of northeastern Taiwan. By using the thermal gradient between hydrothermal fluids and seawater, the thermoelectric cap obtained a sustained power of 0.2–0.5 W during the field test. The thermoelectric cap successfully powered the 16 thermocouples and recorded the temperature of the hydrothermal fluids during the entire field test. Our results show that the thermal energy of hydrothermal fluids can be an alternative renewable power source for oceanographic research.

The Guaymas Basin hiking guide to hydrothermal mounds, chimneys and microbial mats: complex seafloor expressions of subsurface hydrothermal circulation

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Andreas eTeske

2016-02-01

Full Text Available The hydrothermal mats, mounds and chimneys of the southern Guaymas Basin are the surface expression of complex subsurface hydrothermal circulation patterns. In this overview we document the most frequently visited features of this hydrothermal area with photographs, temperature measurements, and selected geochemical data; many of these distinct habitats await characterization of their microbial communities and activities. Microprofiler deployments on microbial mats and hydrothermal sediments show their steep geochemical and thermal gradients at millimeter-scale vertical resolution. Mapping these hydrothermal features and sampling locations within the southern Guaymas Basin suggest linkages to underlying shallow sills and heatflow gradients. Recognizing the inherent spatial limitations of much current Guaymas Basin sampling calls for a wider survey of the entire spreading region.

Diameter characterization of timber species in primary forests of Cerro Murrucucu

International Nuclear Information System (INIS)

Villa G, Ana Maria

2006-01-01

This study in Cerro Murrucucu forests establishes the minimum fell diameter (DMC) and its fell cycle (C). It classifies the forest in 1 (Iess damaged) and 2 (severely damaged). Ten species were selected by means of the importance Value Index (IVI) and the DMC was determined. C was estimated through the times of step method. Pentaclethra macroloba showed the highest IVI (21.5% and 21.09% for forests 1 and 2, respectively). In spite of the deterioration of forest 2 the species still showed highest importance. In forest 1 an equilibrium can be deduced, whereas in forest 2 most of the considered species show instability. The DMC for forests 1 and 2 were 30 and 20 cm respectively, indicating extractive activities are deteriorating the latest. C was 51.8 years

Geología de la región del Cerro Guanaquero, Río Diamante, Mendoza

OpenAIRE

Federico Fuentes; Victor A. Ramos

2008-01-01

El estudio realizado presenta nuevos datos sobre un sector poco conocido de la Cordillera Principal de Mendoza, en la alta cuenca del río Diamante en las adyacencias del cerro Guanaquero, y los primeros datos geocronológicos de sus rocas volcánicas. Las unidades geológicas presentes en el área se dividen en cuatro grupos principales: secuencias sedimentarias mesozoicas marinas y continentales intensamente plegadas y falladas; intrusivos y volcanitas intermedias de edad neógena; rocas volcánic...

Age and kinematics of ductile deformation in the Cerro Durazno area, NW Argentina: Significance for orogenic processes operating at the western margin of Gondwana during Ordovician - Silurian times

Science.gov (United States)

Wegmann, Maja I.; Riller, Ulrich; Hongn, Fernando D.; Glodny, Johannes; Oncken, Onno

2008-07-01

The Cerro Durazno Pluton belongs to a suite of Paleozoic granitoid intrusions in NW-Argentina, that are central for understanding the tectonic setting of the western margin of Gondwana in Ordovician and Silurian times. The pluton and its host rocks were tectonically overprinted by metamorphic mineral shape fabrics formed under middle greenschist-facies metamorphic conditions and associated with the nearby Agua Rosada Shear Zone. Kinematic analysis of the shear zone based on the geometric relationship between individual segments of the shear plane and principal axes of mineral fabric ellipsoids indicates reverse-sense of shear with a minor component of left-lateral displacement. This is compatible with the kinematics of other ductile deformation zones in this area, collectively forming a network, which accomplished orogen-parallel extension in addition to vertical thickening. Using the Rb-Sr isotopic system, an undeformed pegmatite dike of the Cerro Durazno Pluton was dated at 455.8 ± 3.6 Ma and mineral fabrics of the Agua Rosada Shear Zone formed at middle greenschist-facies metamorphism gave deformation ages of 437.0 ± 3.8 Ma and ⩽428.4 ± 4.5 Ma. Thus, tectonic overprint at low metamorphic grade occurred about 20-30 Ma after terminal magmatism in the Cerro Durazno area. Our data from the Cerro Durazno area and regional considerations suggest that the western margin of Gondwana was characterized by orogen-parallel extension in addition to crustal thickening as well as episodes of magmatism and ductile deformation that varied greatly in time and space.

Modelling of hydrothermal characteristics of centrifugal nozzles

International Nuclear Information System (INIS)

Yarkho, A.A.; Omelchenko, M.P.; Borshchev, V.A.

1990-01-01

Presented for the first time is a method of recalculating the hydrothermal characteristics of centrifugal nozzles obtained in laboratory conditions for full-scale nozzles. From the experimental hydrothermal characteristics of nozzles observed in the laboratory it is allowed to calculate the hydrothermal characteristics of any other centrifugal nozzle whose diameter and dimensionless geometric characteristic are known

Comentarios a las ponencias de Lourenzo Fernández Prieto y Marcela Sabaté Sort

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Ricardo ROBLEDO HERNÁNDEZ

2010-02-01

Full Text Available La ponencia de Lorenzo Fernández Prieto empieza por reivindicar los problemas del presente como punto de partida en la construcción de la historia aconsejando tener en cuenta como referente la crisis del modelo de modernización y el fin de la ideología del progreso. Resulta llamativo que al mismo tiempo, aunque sea de forma marginal, eche una lanza a favor de Fukuyama, tildado habitualmente de ideología conservadora. Pero esto, por decirlo de algún modo, es casi una anécdota puesto que el principal foco de atención es la historia rural como el ámbito más pertinente de historia transnacional. Su ponencia es un alegato más que engrosa la corriente de opinión cada vez más caudalosa en contra de la tesis del fracaso o del excepcionalismo hispánicos. Casi hace treinta años que se está hablando en esta dirección, desde que Martínez Alier y Naredo descartaron que existiera una evolución muy diferente de la agricultura española y que el comportamiento de los grandes labradores o el carácter de las instituciones fueran factores explicativos relevantes en esa supuesta diferenciación.

Study on the hydrothermal treatment of Shenhua coal

Energy Technology Data Exchange (ETDEWEB)

Zhicai Wang; Hengfu Shui; Zhanning Pei; Jinsheng Gao [Anhui University of Technology, Ma' anshan (China). School of Chemistry and Chemical Engineering

2008-04-15

In this paper, the hydrothermal treatment of Shenhua coal was carried out under 0.1 MPa (initial pressure) nitrogen and different temperature. Effects of hydrothermal treatment on the structure and the hydro-liquefaction activity of Shenhua coal were investigated by the ultimate and proximate analyses, the FTIR measurements and TG analyses of hydrothermally treated coals, and the characterizations of extraction and swelling properties, and the batch hydro-liquefaction of treated coal were also carried out. The results indicate that hydrothermal treatment above 200{sup o}C can increase the hydrogen content of treated coal and decrease the yield of volatiles and the content of ash, especially a large amount of CO and CH{sub 4} are found in gas products obtained by the hydrothermal treatment above 250{sup o}C. Hydrothermal treatment disrupts the weak covalent bond such as ether, ester and side-chain substituent by hydrolysis and pyrolysis, and changes the distribution of H-bond in coal. The swelling ratio and the Soxhlet extraction yield of treated coal decrease with the increase of hydrothermal treatment temperature. The conversion of liquefaction and the yield of CS{sub 2}/NMP mixed solvent extraction at ambient temperature are enhanced by hydrothermal treatment at 300{sup o}C. Therefore hydrogen donation reactions and the rupture of non-covalent bond and weak covalent bonds present in the process of hydrothermal treatment resulting in the changes of structure and reactivity of Shenhua coal. The results show that the hydro-liquefaction activity of Shenhua coal can be improved by hydrothermal pretreatment between 250{sup o}C and 300{sup o}C. 15 refs., 5 figs., 4 tabs.

El sistema de yacimientos de mamíferos miocenos del Cerro de los Batallones, Cuenca de Madrid: estado actual y perspectivas

NARCIS (Netherlands)

Morales, J.; Pozo, M.; Silva, P.G.; Domingo, M.S.; López-Antoñanzas, R.; Álvarez Sierra, A.; Antón, M.; Martín Escorza, C.; Quiralte, V.; Salesa, M.J.; Sánchez, I.M.; Azanza, B.; Calvo, J.P.; Carrasco, P.; García-Paredes, I.; Knoll, F.; Hernández Fernández, M.; Hoek Ostende, van den L.W.; Merino, L.; Meulen, van der A.J.; Montoya, P.; Peigné, S.; Peláez-Campomanes, P.; Sánchez-Marco, A.; Turner, A.; Abella, J.; Alcalde, G.M.; Andrés, M.; DeMiguel, D.; Cantalapiedra, J.L.; Fraile, S.; García Yelo, B.A.; Gómez Cano, A.R.; López Guerrero, P.; Oliver Pérez, A.; Siliceo, G.

2008-01-01

The Cerro de los Batallones (Los Batallones Butte) is located in the central-northern area of the Madrid Basin, central Spain. Nine vertebrates localities containing a large variety of mammals of Upper Vallesian Age (Late Miocene) have been found associated with the sediments forming the butte. From

Downwelling Far-Infrared Emission Spectra Measured By First at Cerro Toco, Chile and Table Mountain, California

Science.gov (United States)

Mast, J. C.; Mlynczak, M. G.; Cageao, R.; Kratz, D. P.; Johnson, D. G.; Mlawer, E. J.; Turner, D. D.

2014-12-01

The Far-Infrared Spectroscopy of the Troposphere (FIRST) instrument is a Fourier transform spectrometer developed to measure the important far-infrared spectrum between 100 and 650 cm-1. Presented here are measurements made by FIRST during two successful deployments in a ground-based configuration to measure downwelling longwave radiation at Earth's surface. The initial deployment was to Cerro Toco, Chile, where FIRST operated from August to October, 2009 as part of the Radiative Heating in Underexplored Bands Campaign (RHUBC-II) campaign. After recalibration, FIRST was deployed to the Table Mountain Facility from September through October, 2012. Spectra observed at each location are substantially different, due in large part to the order of magnitude difference in integrated precipitable water vapor (0.3 cm at Table Mountain, 0.03 cm at Cerro Toco). Dry days for both campaigns are chosen for analysis - 09/24/2009 and 10/19/2012. Also available during both deployments are coincident radiosonde temperature and water vapor vertical profiles which are used as inputs a line-by-line radiative transfer program. Comparisons between measured and modeled spectra are presented over the 200 to 800 cm-1 range. An extensive error analysis of both the measured and modeled spectra is presented. In general, the differences between the measured and modeled spectra are within their combined uncertainties.

Evolución de las relaciones nutricionales suelo-planta desarrolladas en suelos de la D. O. "Tierra de León" dedicados al cultivo de Vitis vinífera L. cv. Prieto Picudo

OpenAIRE

Olego Morán, Miguel Ángel

2013-01-01

Se constata la gran influencia e importancia que tiene el pH de los suelos, sobre la biodisponibilidad de los nutrientes minerales presentes en los mismos. Se ha constatado que los nutrientes minerales Mg y Cu de los tejidos vegetales de Vitis vinífera L. cv. Prieto Picudo, aparecen con una interacción antagónica y significativa, lo cual reviste gran importancia, dada la escasez del nutriente Mg en estos suelos, y los continuos tratamientos con base cúprica que actualmente se realizan

A re-appraisal of the stratigraphy and volcanology of the Cerro Galán volcanic system, NW Argentina

Science.gov (United States)

Folkes, Christopher B.; Wright, Heather M.; Cas, Ray A.F.; de Silva, Shanaka L.; Lesti, Chiara; Viramonte, Jose G.

2011-01-01

From detailed fieldwork and biotite 40Ar/39Ar dating correlated with paleomagnetic analyses of lithic clasts, we present a revision of the stratigraphy, areal extent and volume estimates of ignimbrites in the Cerro Galán volcanic complex. We find evidence for nine distinct outflow ignimbrites, including two newly identified ignimbrites in the Toconquis Group (the Pitas and Vega Ignimbrites). Toconquis Group Ignimbrites (~5.60–4.51 Ma biotite ages) have been discovered to the southwest and north of the caldera, increasing their spatial extents from previous estimates. Previously thought to be contemporaneous, we distinguish the Real Grande Ignimbrite (4.68 ± 0.07 Ma biotite age) from the Cueva Negra Ignimbrite (3.77 ± 0.08 Ma biotite age). The form and collapse processes of the Cerro Galán caldera are also reassessed. Based on re-interpretation of the margins of the caldera, we find evidence for a fault-bounded trapdoor collapse hinged along a regional N-S fault on the eastern side of the caldera and accommodated on a N-S fault on the western caldera margin. The collapsed area defines a roughly isosceles trapezoid shape elongated E-W and with maximum dimensions 27 × 16 km. The Cerro Galán Ignimbrite (CGI; 2.08 ± 0.02 Ma sanidine age) outflow sheet extends to 40 km in all directions from the inferred structural margins, with a maximum runout distance of ~80 km to the north of the caldera. New deposit volume estimates confirm an increase in eruptive volume through time, wherein the Toconquis Group Ignimbrites increase in volume from the ~10 km3 Lower Merihuaca Ignimbrite to a maximum of ~390 km3 (Dense Rock Equivalent; DRE) with the Real Grande Ignimbrite. The climactic CGI has a revised volume of ~630 km3 (DRE), approximately two thirds of the commonly quoted value.

Reconstruction of Ancestral Hydrothermal Systems on Mount Rainier Using Hydrothermally Altered Rocks in Holocene Debris Flows and Tephras

Science.gov (United States)

John, D. A.; Breit, G. N.; Sisson, T. W.; Vallance, J. W.; Rye, R. O.

2005-12-01

Mount Rainier is the result of episodic stages of edifice growth during periods of high eruptive activity and edifice destruction during periods of relative magmatic quiescence over the past 500 kyr. Edifice destruction occurred both by slow erosion and by catastrophic collapses, some of which were strongly influenced by hydrothermal alteration. Several large-volume Holocene debris-flow deposits contain abundant clasts of hydrothermally altered rocks, most notably the 4-km3 clay-rich Osceola Mudflow which formed by collapse of the northeast side and upper 1000+ m of the edifice about 5600 ya and flowed >120 km downstream into Puget Sound. Mineral assemblages and stable isotope data of hydrothermal alteration products in Holocene debris-flow deposits indicate formation in distinct hydrothermal environments, including magmatic-hydrothermal, steam-heated (including a large fumarolic component), magmatic steam (including a possible fumarolic component), and supergene. The Osceola Mudflow and phreatic components of coeval tephras contain the highest-temperature and inferred most deeply formed alteration minerals; assemblages include magmatic-hydrothermal quartz-alunite, quartz-topaz, quartz-pyrophyllite and quartz-illite (all +pyrite), in addition to steam-heated opal-alunite-kaolinite and abundant smectite-pyrite. In contrast, the Paradise lahar, which formed by a collapse of the surficial upper south side of the edifice, contains only steam-heated assemblages including those formed largely above the water table from condensation of fumarolic vapor (opal-alunite-jarosite). Younger debris-flow deposits on the west side of the volcano (Round Pass lahar and Electron Mudflow) contain only smectite-pyrite alteration, whereas an early 20th century rock avalanche on Tahoma Glacier also contains magmatic-hydrothermal alteration that is exposed in the avalanche headwall of Sunset Amphitheater. Mineralogy and isotopic composition of the alteration phases, geologic and

La «embajada oficiosa» de Indalecio Prieto en México durante la presidencia de Lázaro Cárdenas, 1939-1940

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Mateos, Abdón

2003-08-01

Full Text Available The author tries to set Indalecio Prieto’s mission in Cárdenas’ Mexico within its political context, emphasizing the background of the relationship between the Spanish republican socialists and the Mexican leftist nationalists and its development from the 1920’s onwards. The present monograph is an account of the JARE’s management and of President L. Cárdenas’ policy towards the Spanish republican refugees until the beginning of Ávila Camacho’s presidency

El autor contextualiza la misión de Indalecio Prieto en el México cardenista, destacando los antecedentes de las relaciones entre los republicanos-socialistas españoles y la izquierda nacionalista mexicana establecidas desde los años veinte. La monografía analiza la gestión de la JARE y la política de Lázaro Cárdenas hacia los refugiados republicanos españoles hasta el comienzo de la presidencia de Manuel Ávila Camacho.

Application of Hydrothermal and Non-Hydrothermal TiO2 Nanoporous Materials as New Adsorbents for Removal of Heavy Metal Ions from Aqueous System

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Mansoor Anbia

2016-06-01

Full Text Available Hydrothermal and non-hydrothermal spherical TiO2 nanoporous with crystalline framework were prepared by sol-gel method. The Crystalline structures, morphologies and surface texturing of materials were determined by X-ray diffraction (XRD, scanning electron microscopy (SEM and N2 adsorption-desorption isotherms. The Hydrothermal spherical TiO2 nanoporous was found to have a narrow and strong pore size distribution peaks with average of 37.8 Å and pore volume of 0.41 cm3/g and the (Brunauer–Emmett–TellerBET specific surface area of 365 m2/g. Hydrothermal and non-hydrothermal spherical TiO2 nanoporous have been used as adsorbent to study of the adsorption behavior of Pb(II, Co(II and Ni(II ions from aqueous system in a batch system. Effect of equilibrium time on adsorption Pb(II, Co(II and Ni(II ions on these adsorbent was studied The results show that the shaking time 0.5 to 10h has no serious effect on the percentage of ions removal, and the adsorption is fast in all cases. The maximum uptake capacities of Hydrothermal and non-hydrothermal spherical TiO2 nanoporous was calculated. Both hydrothermal and non-hydrothermal TiO2 nanoporous materials were found to have very good potential as new adsorbents in removal of these ions. In batch systems the maximum uptake capacities of Pb(II, Ni(II and Co(II on the hydrothermal and non-hydrothermal TiO2 nanoporous materials was Co(II > Pb(II > Ni(II and Co(II > Ni(II > Pb(II, respectively.

Changing fluvial styles in volcaniclastic successions: A cretaceous example from the Cerro Barcino Formation, Patagonia

Science.gov (United States)

Umazano, A. Martín; Krause, J. Marcelo; Bellosi, Eduardo S.; Perez, Mariano; Visconti, Graciela; Melchor, Ricardo N.

2017-08-01

The Cretaceous Puesto La Paloma (PLPM) and Cerro Castaño (CCM) members (Cerro Barcino Formation, Chubut Group) are pyroclastic-rich, alluvial successions deposited in the Somuncurá-Cañadón Asfalto Basin during sag and endorheic conditions. The PLPM comprises sheet-like tuffaceous sandstone strata, whereas the overlying CCM includes sheet-to ribbon-channel sandstone bodies intercalated within tuffaceous and fine-grained sediments. In this context, the goals of this contribution were: i) to make a detailed documentation of the contrasting sedimentary palaeonvironments; and ii) to infer the allocyclic controls that governed the sedimentation of both units. The study area is located in the western sector of the basin, where six localities, which were studied. Six facies associations were defined including ash-falls, sheet-floods, shallow lakes, aeolian, fluvial channel-belts, and reworked debris-flows. We defined four stratigraphic intervals for the studied sections, denominated 1 to 4 in chronological order of deposition, which increase their thicknesses toward the Puesto Mesa-Cerro León site. The interval 1 (18-42 m thick) corresponds to the PLPM and includes numerous pedogenized sheet-flood deposits, carbonate-rich lacustrine, aeolian sandy facies, and ash-fall beds. The interval 1 is interpreted as an ephemeral and unconfined alluvial system that interacted with aeolian dunes and dry interdune zones. The interval 2 (20-47 m thick) represents the lower part of the CCM. It shows an alternation of fluvial channel-belt deposits and vegetated floodplain facies with sediments originated from sheet-floods, lakes, and few ash-falls and debris-flows. The mean palaeoflow was toward E-SE, except in the northernmost locality where the drainage was towards SW. Proportion of channel-belt bodies ranges from 10 to 36%, reaching higher values in the northern part of the study area, where they are also thicker. The interval 2 represents a permanent, meandering or locally low

Ideas and perspectives: hydrothermally driven redistribution and sequestration of early Archaean biomass - the "hydrothermal pump hypothesis"

Science.gov (United States)

Duda, Jan-Peter; Thiel, Volker; Bauersachs, Thorsten; Mißbach, Helge; Reinhardt, Manuel; Schäfer, Nadine; Van Kranendonk, Martin J.; Reitner, Joachim

2018-03-01

Archaean hydrothermal chert veins commonly contain abundant organic carbon of uncertain origin (abiotic vs. biotic). In this study, we analysed kerogen contained in a hydrothermal chert vein from the ca. 3.5 Ga Dresser Formation (Pilbara Craton, Western Australia). Catalytic hydropyrolysis (HyPy) of this kerogen yielded n-alkanes up to n-C22, with a sharp decrease in abundance beyond n-C18. This distribution ( ≤ n-C18) is very similar to that observed in HyPy products of recent bacterial biomass, which was used as reference material, whereas it differs markedly from the unimodal distribution of abiotic compounds experimentally formed via Fischer-Tropsch-type synthesis. We therefore propose that the organic matter in the Archaean chert veins has a primarily microbial origin. The microbially derived organic matter accumulated in anoxic aquatic (surface and/or subsurface) environments and was then assimilated, redistributed and sequestered by the hydrothermal fluids (hydrothermal pump hypothesis).

ANALISIS DEL CO-TRATAMIENTO PASIVO DE AGUAS RESIDUALES MUNICIPALES Y DRENAJE ACIDO DE MINAS EN CERRO RICO DE POTOSÍ, BOLIVIA

Directory of Open Access Journals (Sweden)

William H.J. Strosnider

2015-01-01

Full Text Available El drenaje acido de minas (DAM es un problema a nivel mundial. El co-tratamiento pasivo de DAM con aguas residuales municipales (ARM es una manera efectiva y de bajo costo que utiliza los nutrientes de ARM para tratar las concentraciones de metales y sulfato en DAM. Cerro Rico de Potosí, Bolivia es una de las grandes ciudades mineras en el mundo que tiene muchos problemas con el DAM. El objetivo de este estudio fue determinar velocidades de reacción de Al, Fe, Mn, Zn, y otros metales en DAM provenientes de un flujo de agua en Cerro Rico usando un sistema reactor de tres etapas. El DAM tenía un pH de 3.58, acidez de 1080 mg/L equivalente a CaCO3 conteniendo concentraciones de 12, 68, 17, y 550 mg/L de Al, Fe, Mn y Zn respectivamente. Las velocidades de reacción de Al, Fe, Mn y Zn fueron de 1.43, 2.09, 0.01 y 0.10 d-1, respectivamente.

Uranium and Molybdenum extraction from a Cerro Solo deposit ore

International Nuclear Information System (INIS)

Becquart, Elena T.; Arias, Maria J.; Fuente, Juan C. de la; Misischia, Yamila A.; Santa Cruz, Daniel E.; Tomellini, Guido C.

2009-01-01

Cerro Solo, located in Chubut, Argentina, is a sandstone type uranium-molybdenum deposit. Good recovery of both elements can be achieved by acid leaching of the ore but the presence of molybdenum in pregnant liquors is an inconvenient to uranium separation and purification. A two steps process is developed. A selective alkaline leaching of the ore with sodium hydroxide allows separating and recovering of molybdenum and after solid-liquid separation, the ore is acid leached to recover uranium. Several samples averaging 0,2% uranium and 0,1% molybdenum with variable U/Mo ratio have been used and in both steps, leaching and oxidant reagents concentration, temperature and residence time in a stirred tank leaching have been studied. In alkaline leaching molybdenum recoveries greater than 96% are achieved, with 1% uranium extraction. In acid leaching up to 93% of the uranium is extracted and Mo/U ratio in solvent extraction feed is between 0,013 and 0,025. (author)

Stratigraphic and tectonic revision of Cerro Olivo Complex located of Southeastern of Uruguay

International Nuclear Information System (INIS)

Masquelin, E.

2004-01-01

This paper presents a stratigraphic and tectonic revision of Cerro Olivo Complex, located in the Southeastern part of the Uruguayan Predevonian Shield. This informal lithostratigraphic unit constitutes the country rock for the emplacement of late-orogenic granitoids, during Neoproterozoic to Cambrian times. This unit groups all the lithodemes affected by deformation and metamorphism. Recent studies indicate the presence of straight gneisses of quartzo-feldspathic composition in the coast of Maldonado Department. These rocks were interpreted as the result of intense deformation in high temperature. These tectonites base a new stratigraphic insight for the complex. They allow their lithotypes to be organized by petrotectonic features, being a function of PT conditions for every last strain process [es

Hydrothermal treatment followed by enzymatic hydrolysis and hydrothermal carbonization as means to valorise agro- and forest-based biomass residues.

Science.gov (United States)

Wikberg, Hanne; Grönqvist, Stina; Niemi, Piritta; Mikkelson, Atte; Siika-Aho, Matti; Kanerva, Heimo; Käsper, Andres; Tamminen, Tarja

2017-07-01

The suitability of several abundant but underutilized agro and forest based biomass residues for hydrothermal treatment followed by enzymatic hydrolysis as well as for hydrothermal carbonization was studied. The selected approaches represent simple biotechnical and thermochemical treatment routes suitable for wet biomass. Based on the results, the hydrothermal pre-treatment followed by enzymatic hydrolysis seemed to be most suitable for processing of carbohydrate rich corn leaves, corn stover, wheat straw and willow. High content of thermally stable components (i.e. lignin) and low content of ash in the biomass were advantageous for hydrothermal carbonization of grape pomace, coffee cake, Scots pine bark and willow. Copyright © 2017 Elsevier Ltd. All rights reserved.

Volcanic hazard map for Telica, Cerro Negro and El Hoyo volcanoes, Nicaragua

Science.gov (United States)

Asahina, T.; Navarro, M.; Strauch, W.

2007-05-01

A volcano hazard study was conducted for Telica, Cerro Negro and El Hoyo volcanoes, Nicaragua, based on geological and volcanological field investigations, air photo analyses, and numerical eruption simulation. These volcanoes are among the most active volcanoes of the country. This study was realized 2004-2006 through technical cooperation of Japan International Cooperation Agency (JICA) with INETER, upon the request of the Government of Nicaragua. The resulting volcanic hazard map on 1:50,000 scale displays the hazards of lava flow, pyroclastic flows, lahars, tephra fall, volcanic bombs for an area of 1,300 square kilometers. The map and corresponding GIS coverage was handed out to Central, Departmental and Municipal authorities for their use and is included in a National GIS on Georisks developed and maintained by INETER.

High-resolution carbonate isotopic study of the Mural Formation (Cerro Pimas section), Sonora, México: Implications for early Albian oceanic anoxic events

Science.gov (United States)

Madhavaraju, J.; Lee, Yong Il; Scott, R. W.; González-León, C. M.; Jenkyns, H. C.; Saucedo-Samaniego, J. C.; Ramasamy, S.

2018-03-01

The 420-m thick stratigraphic section of the Mural Formation that is exposed in the Cerro Pimas area of northern Sonora, Mexico, is composed of limestone lithofacies ranging from bioclastic wackestone to boundstone, whose biota is characterized by low diversity. Prominent age-diagnostic fossils are benthic foraminifera and long-ranging calcareous algae that indicate the Aptian/Albian boundary is close to the base of the Los Coyotes Member. The carbonates of this formation have negative to positive δ13C values (-4.63 to +2.6‰) and highly depleted δ18O values that range from -12.74 to -8.34‰. The absence of correlation between δ13C and δ18O values supports a primary marine origin for the δ13C values of these limestones. The carbon-isotopic curve of the Cerro Pimas stratigraphic section has well-defined δ13C segments (C8 - C15) that compare with published curves of similar age. In the lower part of the early Albian Los Coyotes Member, the presence of OAE 1b is indicated by an increase followed by a decrease in δ13C values, suggesting correlation with the Kilian Event. The middle part of the Los Coyotes Member has a significant negative carbon-isotope excursion correlated with the globally recognizable early Albian Paquier event. Moreover, another significant negative carbon-isotope shift is observed in the upper part of the Los Coyotes Member, which can be correlated with the Leenhardt Event. The occurrence of the Kilian, Paquier and Leenhardt Events (OAE 1b cluster) in the Cerro Pimas stratigraphy confirms the global nature of these early Albian disturbances of the carbon cycle.

Whole Algae Hydrothermal Liquefaction Technology Pathway

Energy Technology Data Exchange (ETDEWEB)

Biddy, M.; Davis, R.; Jones, S.

2013-03-01

This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Summary of a Gas Transport Tracer Test in the Deep Cerros Del Rio Basalts, Mesita del Buey, Los Alamos NM.

Energy Technology Data Exchange (ETDEWEB)

Stauffer, Philip H. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rahn, Thomas A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ortiz, John Philip [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Salazar, Larry Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Boukhalfa, Hakim [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Snyder, Emily Elisabeth [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2018-01-16

Here we describe results from a tracer test in the Cerros del Rio basalt beneath Mesita del Buey, Technical Area 54 (TA-54) at Los Alamos National Laboratory (LANL or the Laboratory). This report follows from plans outlined in our previous Tracer Test Work Plan (LANL 2016). These activities were conducted by LANL to further characterize subsurface properties of the Cerros del Rio basalts at Material Disposal Area (MDA) L (Figure 1.1-1). The work presented follows from the “Interim Measures Work Plan for Soil-Vapor Extraction of Volatile Organic Compounds from Material Disposal Area L, Technical Area 54, Revision 1,” submitted to the New Mexico Environment Department (NMED) in September 2014 (LANL 2014). Remediation of the MDA L vapor plume by soil-vapor extraction (SVE) is recommended as part of the final remedy in the “Corrective Measures Evaluation Report for Material Disposal Area L, Solid Waste Management Unit 54-006, at Technical Area 54, Revision 2” to meet a remedial action objective of preventing groundwater from being impacted above a regulatory standard by the transport of volatile organic compounds (VOCs) to groundwater through soil vapor (LANL 2011).

Hydrothermal and alkaline hydrothermal pretreatments plus anaerobic digestion of sewage sludge for dewatering and biogas production: Bench-scale research and pilot-scale verification.

Science.gov (United States)

Li, Chunxing; Wang, Xingdong; Zhang, Guangyi; Yu, Guangwei; Lin, Jingjiang; Wang, Yin

2017-06-15

To test the feasibility and practicability of the process combing hydrothermal pretreatment for dewatering with biogas production for full utilization of sewage sludge, hydrothermal/alkaline hydrothermal pretreatments and in turn anaerobic digestion of the filtrates obtained after dewatering the pretreated sludge were performed at bench- and pilot-scales. The hydrothermal temperature fell within the range of 140 °C-220 °C and the pretreatment time varied from 30 min to 120 min. For the alkaline hydrothermal pretreatment the pH value of the sludge was adjusted to 9.0-11.0 by adding Ca(OH) 2 . The results showed that the dewaterability of the sewage sludge was improved with increasing pretreatment temperature but the impact of the pretreatment time was not significant. The addition of Ca(OH) 2 gave better performance on the subsequent mechanical dewatering of the pretreated sludge compared to pure hydrothermal pretreatment, and the higher the pH value was, the better the dewaterability of the pretreated sludge was. The conditions of 180 °C/30 min and 160 °C/60 min/pH = 10.0 (for hydrothermal and alkaline hydrothermal pretreatments, respectively) resulted in relatively good results in the theoretical energy balance, which were verified in the pilot-scale tests. Based on the data from the pilot tests, the alkaline hydrothermal process realized self-sufficiency in energy at the cost of a proper amount of CaO. Copyright © 2017 Elsevier Ltd. All rights reserved.

Combined hydrothermal liquefaction and catalytic hydrothermal gasification system and process for conversion of biomass feedstocks

Science.gov (United States)

Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

2017-09-12

A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

Anhydrite precipitation in seafloor hydrothermal systems

Science.gov (United States)

Theissen-Krah, Sonja; Rüpke, Lars H.

2016-04-01

The composition and metal concentration of hydrothermal fluids venting at the seafloor is strongly temperature-dependent and fluids above 300°C are required to transport metals to the seafloor (Hannington et al. 2010). Ore-forming hydrothermal systems and high temperature vents in general are often associated with faults and fracture zones, i.e. zones of enhanced permeabilities that act as channels for the uprising hydrothermal fluid (Heinrich & Candela, 2014). Previous numerical models (Jupp and Schultz, 2000; Andersen et al. 2015) however have shown that high permeabilities tend to decrease fluid flow temperatures due to mixing with cold seawater and the resulting high fluid fluxes that lead to short residence times of the fluid near the heat source. A possible mechanism to reduce the permeability and thereby to focus high temperature fluid flow are mineral precipitation reactions that clog the pore space. Anhydrite for example precipitates from seawater if it is heated to temperatures above ~150°C or due to mixing of seawater with hydrothermal fluids that usually have high Calcium concentrations. We have implemented anhydrite reactions (precipitation and dissolution) in our finite element numerical models of hydrothermal circulation. The initial results show that the precipitation of anhydrite efficiently alters the permeability field, which affects the hydrothermal flow field as well as the resulting vent temperatures. C. Andersen et al. (2015), Fault geometry and permeability contrast control vent temperatures at the Logatchev 1 hydrothermal field, Mid-Atlantic Ridge, Geology, 43(1), 51-54. M. D. Hannington et al. (2010), Modern Sea-Floor Massive Sulfides and Base Metal Resources: Toward an Estimate of Global Sea-Floor Massive Sulfide Potential, in The Challenge of Finding New Mineral Resources: Global Metallogeny, Innovative Exploration, and New Discoveries, edited by R. J. Goldfarb, E. E. Marsh and T. Monecke, pp. 317-338, Society of Economic Geologists

Al-doped SnO2 nanocrystals from hydrothermal systems

International Nuclear Information System (INIS)

Jin Haiying; Xu Yaohua; Pang Guangsheng; Dong Wenjun; Wan Qiang; Sun Yan; Feng Shouhua

2004-01-01

Nanoparticles of Al-doped SnO 2 have been hydrothermally synthesized. The influences of the hydrothermal reaction time, the molar ratio of Sn/Al as well as the pH value of the solution have been studied. During the hydrothermal synthesis, the particle's core is rich in Sn and the surface is rich in Al. The Al-rich surface prevents the particles from further growing up either in the hydrothermal condition or during the calcination at 600 deg. C for a short period of time. The optimal hydrothermal synthesis condition of the nanoparticles is pH 5, Sn/Al=4:1 and 12 h at 160 deg. C. The products have been studied by XRD, TEM and 27 Al solid-state NMR

Non-traditional Stable Isotope Systematics of Seafloor Hydrothermal Systems

Science.gov (United States)

Rouxel, O. J.

2009-05-01

Seafloor hydrothermal activity at mid-ocean ridges is one of the fundamental processes controlling the chemistry of the oceans and the altered oceanic crust. Past studies have demonstrated the complexity and diversity of seafloor hydrothermal systems and have highlighted the importance of subsurface environments in controlling the composition of hydrothermal fluids and mineralization types. Traditionally, the behavior of metals in seafloor hydrothermal systems have been investigated by integrating results from laboratory studies, theoretical models, mineralogy and fluid and mineral chemistry. Isotope ratios of various metals and metalloids, such as Fe, Cu, Zn, Se, Cd and Sb have recently provided new approaches for the study of seafloor hydrothermal systems. Despite these initial investigations, the cause of the isotopic variability of these elements remains poorly constrained. We have little understanding of the isotope variations between vent types (black or white smokers) as well as the influence of source rock composition (basalt, felsic or ultrabasic rocks) and alteration types. Here, I will review and present new results of metal isotope systematics of seafloor hydrothermal systems, in particular: (1) determination of empirical isotope fractionation factors for Zn, Fe and Cu-isotopes through isotopic analysis of mono-mineralic sulfide grains lining the internal chimney wall in contact with hydrothermal fluid; (2) comparison of Fe- and Cu-isotope signatures of vent fluids from mid- oceanic and back-arc hydrothermal fields, spanning wide ranges of pH, temperature, metal concentrations and contributions of magmatic fluids enriched in SO2. Ultimately, the use of complementary non-traditional stable isotope systems may help identify and constrain the complex interactions between fluids,minerals, and organisms in seafloor hydrothermal systems.

Pucarilla-Cerro Tipillas volcanic complex: the oldest recognized caldera in the southeastern portion of central volcanic zone of Central Andes?

Energy Technology Data Exchange (ETDEWEB)

Guzman, Silvina; Petrinovic, Ivan [CONICET -IBIGEO. Museo de Cs. Naturales, Universidad de Salta, Mendoza 2 (4400), Salta (Argentina)], E-mail: guzmansilvina@gmail.com

2008-10-01

We recognize the most eastern and oldest collapse caldera structure in the southern portion of the Central Volcanic Zone of the Andes. A description of Middle-Upper Miocene successions related to explosive- effusive events is presented. The location of this centre close to Cerro Galn Caldera attests a recurrence in the volcanism between 12 and 2 Ma in this portion of the Altiplano - Puna Plateau.

Hydrothermal systems and volcano geochemistry

Science.gov (United States)

Fournier, R.O.

2007-01-01

The upward intrusion of magma from deeper to shallower levels beneath volcanoes obviously plays an important role in their surface deformation. This chapter will examine less obvious roles that hydrothermal processes might play in volcanic deformation. Emphasis will be placed on the effect that the transition from brittle to plastic behavior of rocks is likely to have on magma degassing and hydrothermal processes, and on the likely chemical variations in brine and gas compositions that occur as a result of movement of aqueous-rich fluids from plastic into brittle rock at different depths. To a great extent, the model of hydrothermal processes in sub-volcanic systems that is presented here is inferential, based in part on information obtained from deep drilling for geothermal resources, and in part on the study of ore deposits that are thought to have formed in volcanic and shallow plutonic environments.

Ideas and perspectives: hydrothermally driven redistribution and sequestration of early Archaean biomass – the “hydrothermal pump hypothesis”

Directory of Open Access Journals (Sweden)

J.-P. Duda

2018-03-01

Full Text Available Archaean hydrothermal chert veins commonly contain abundant organic carbon of uncertain origin (abiotic vs. biotic. In this study, we analysed kerogen contained in a hydrothermal chert vein from the ca. 3.5 Ga Dresser Formation (Pilbara Craton, Western Australia. Catalytic hydropyrolysis (HyPy of this kerogen yielded n-alkanes up to n-C22, with a sharp decrease in abundance beyond n-C18. This distribution ( ≤  n-C18 is very similar to that observed in HyPy products of recent bacterial biomass, which was used as reference material, whereas it differs markedly from the unimodal distribution of abiotic compounds experimentally formed via Fischer–Tropsch-type synthesis. We therefore propose that the organic matter in the Archaean chert veins has a primarily microbial origin. The microbially derived organic matter accumulated in anoxic aquatic (surface and/or subsurface environments and was then assimilated, redistributed and sequestered by the hydrothermal fluids (hydrothermal pump hypothesis.

Modeling of the fault-controlled hydrothermal ore-forming systems

International Nuclear Information System (INIS)

Pek, A.A.; Malkovsky, V.I.

1993-07-01

A necessary precondition for the formation of hydrothermal ore deposits is a strong focusing of hydrothermal flow as fluids move from the fluid source to the site of ore deposition. The spatial distribution of hydrothermal deposits favors the concept that such fluid flow focusing is controlled, for the most part, by regional faults which provide a low resistance path for hydrothermal solutions. Results of electric analog simulations, analytical solutions, and computer simulations of the fluid flow, in a fault-controlled single-pass advective system, confirm this concept. The influence of the fluid flow focusing on the heat and mass transfer in a single-pass advective system was investigated for a simplified version of the metamorphic model for the genesis of greenstone-hosted gold deposits. The spatial distribution of ore mineralization, predicted by computer simulation, is in reasonable agreement with geological observations. Computer simulations of the fault-controlled thermoconvective system revealed a complex pattern of mixing hydrothermal solutions in the model, which also simulates the development of the modern hydrothermal systems on the ocean floor. The specific feature of the model considered, is the development under certain conditions of an intra-fault convective cell that operates essentially independently of the large scale circulation. These and other results obtained during the study indicate that modeling of natural fault-controlled hydrothermal systems is instructive for the analysis of transport processes in man-made hydrothermal systems that could develop in geologic high-level nuclear waste repositories

Hydrothermal alteration in oceanic ridge volcanics: A detailed study at the Galapagos Fossil Hydrothermal Field

Science.gov (United States)

Ridley, W.I.; Perfit, M.R.; Josnasson, I.R.; Smith, M.F.

1994-01-01

The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85??49???W and 85??55???W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (< 10) conditions following a period of lower-temperature weathering of volcanics within the rift zone. The complex patterns of element enrichment and depletion and strontium isotope variations indicate mixing between pristine seawater and ascending hot fluids to produce a compositional spectrum of fluids. The precipitation of base-metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems

Pinus Culminicola Andresen y Beaman y sus asociaciones en la ladera sur del cerro La Viga, Coahuila

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Rubén Sánchez Silva

1990-01-01

Full Text Available Pinus culminicola was described in 1961 with samples from the Cerro Potosí, State of Nuevo León, Mexico. The species was reported in the Sierras La Marta in 1962, and San Antonio de las Alazanas in 1975, State of Coahuila, indicating that there were not pure associations. In 1979 the species was colected in the Sierra La Viga, Coahuila, at 3 300 m, without data on environmental conditions in which it grows. The distribution of  P. culminicola is restricted to the south slope of the Cerro La Viga. The associations identified and described in this paper are: (1 Scrub of Quercus rugosa – Quercus durifolia – Cercocarpus montanus with elements of P. culminicola; (2 Pinus montezumae–Pseudotsuga macrolepisy with elements of P. culminicola, Quercus spp. and Arbutus xalapensis (3 P. culminicola– Quercus rugosa (both of them as shrubs; (4 P. montezumac–P. macrolepis–Pinus ayacahuite–P. culminicola; (5 pure scrub of P. culminicola; (6 P. culminicola– Dasylirion tezanum (sometimes with Arctostaphylos pungens and Quercus spp., shrublike; (7 Pinus hartwegii–P. culminicola; (8 P. hartwegii with elements of P. macrolepis and P. culminicola; and (9 induced prairie. There are differences in dominance of the species in accordance to the particular characteristics of each place, with presence of herbaceous from high altitudes. The altitude at which these associations occur, varies from 2 900 m to 3 700 m, although isolated elements of P. culminicola–were found at 2 700 m.

Chemical reaction path modeling of hydrothermal processes on Mars: Preliminary results

Science.gov (United States)

Plumlee, Geoffrey S.; Ridley, W. Ian

1992-01-01

Hydrothermal processes are thought to have had significant roles in the development of surficial mineralogies and morphological features on Mars. For example, a significant proportion of the Martian soil could consist of the erosional products of hydrothermally altered impact melt sheets. In this model, impact-driven, vapor-dominated hydrothermal systems hydrothermally altered the surrounding rocks and transported volatiles such as S and Cl to the surface. Further support for impact-driven hydrothermal alteration on Mars was provided by studies of the Ries crater, Germany, where suevite deposits were extensively altered to montmorillonite clays by inferred low-temperature (100-130 C) hydrothermal fluids. It was also suggested that surface outflow from both impact-driven and volcano-driven hydrothermal systems could generate the valley networks, thereby eliminating the need for an early warm wet climate. We use computer-driven chemical reaction path calculation to model chemical processes which were likely associated with postulated Martian hydrothermal systems.

Evaluación Integral del Riesgo Volcánico del Cerro Machín, Colombia

OpenAIRE

Leonel Vega Mora; Fernando Javier Diaz

2013-01-01

El volcán Cerro Machín (VCM) se encuentra situado en la Cordillera Central de Colombia. Por la composición química, magnitud y extensión de sus erupciones pasadas se reconoce como un volcán explosivo de gran potencial de daño, cuya actividad futura podría afectar intensamente y durante mucho tiempo (meses hasta años) una región estratégica para la economía del país, que cubre áreas pertenecientes a los departamentos de Tolima, Quindío, Valle del Cauca y Cundinamarca, en las cuales habitan cer...

The chemistry of hydrothermal magnetite: a review

Science.gov (United States)

Nadoll, Patrick; Angerer, Thomas; Mauk, Jeffrey L.; French, David; Walshe, John

2014-01-01

Magnetite (Fe3O4) is a well-recognized petrogenetic indicator and is a common accessory mineral in many ore deposits and their host rocks. Recent years have seen an increased interest in the use of hydrothermal magnetite for provenance studies and as a pathfinder for mineral exploration. A number of studies have investigated how specific formation conditions are reflected in the composition of the respective magnetite. Two fundamental questions underlie these efforts — (i) How can the composition of igneous and, more importantly, hydrothermal magnetite be used to discriminate mineralized areas from barren host rocks, and (ii) how can this assist exploration geologists to target ore deposits at greater and greater distances from the main mineralization? Similar to igneous magnetite, the most important factors that govern compositional variations in hydrothermal magnetite are (A) temperature, (B) fluid composition — element availability, (C) oxygen and sulfur fugacity, (D) silicate and sulfide activity, (E) host rock buffering, (F) re-equilibration processes, and (G) intrinsic crystallographic controls such as ionic radius and charge balance. We discuss how specific formation conditions are reflected in the composition of magnetite and review studies that investigate the chemistry of hydrothermal and igneous magnetite from various mineral deposits and their host rocks. Furthermore, we discuss the redox-related alteration of magnetite (martitization and mushketovitization) and mineral inclusions in magnetite and their effect on chemical analyses. Our database includes published and previously unpublished magnetite minor and trace element data for magnetite from (1) banded iron formations (BIF) and related high-grade iron ore deposits in Western Australia, India, and Brazil, (2) Ag–Pb–Zn veins of the Coeur d'Alene district, United States, (3) porphyry Cu–(Au)–(Mo) deposits and associated (4) calcic and magnesian skarn deposits in the southwestern United

The BGU/CERN solar hydrothermal reactor

CERN Document Server

Bertolucci, Sergio; Caspers, Fritz; Garb, Yaakov; Gross, Amit; Pauletta, Stefano

2014-01-01

We describe a novel solar hydrothermal reactor (SHR) under development by Ben Gurion University (BGU) and the European Organization for Nuclear Research CERN. We describe in broad terms the several novel aspects of the device and, by extension, of the niche it occupies: in particular, enabling direct off-grid conversion of a range of organic feedstocks to sterile useable (solid, liquid) fuels, nutrients, products using only solar energy and water. We then provide a brief description of the high temperature high efficiency panels that provide process heat to the hydrothermal reactor, and review the basics of hydrothermal processes and conversion taking place in this. We conclude with a description of a simulation of the pilot system that will begin operation later this year.

The Cerro Tololo Inter-American Observatory Summer Student Programs in La Serena, Chile

Science.gov (United States)

Kaleida, Catherine C.; Smith, C.; Van Der Bliek, N. S.; James, D.

2014-01-01

The Cerro Tololo Inter-American Observatory (CTIO) offers positions for U.S. and Chilean student interns during the Chilean summer months of January-March (northern winter semester) at the CTIO offices in La Serena, Chile. CTIO is part of the National Optical Astronomy Observatory (NOAO) of the United States, focused on the development of astronomy in the southern hemisphere. Six undergraduate research assistantships are offered for U.S. physics and astronomy undergraduate students through the NSF-funded Research Experiences for Undergraduates (REU) program. The CTIO-funded Prácticas de Investigación en Astronomía (PIA) program is run concurrently with the REU program, and offers two research assistantships for Chilean undergraduate or 1st or 2nd year masters students, also at the CTIO offices in La Serena, Chile. The CTIO REU and PIA programs provide exceptional opportunities for students considering a career in astronomy to engage in substantive research activities with scientists working at the forefront of contemporary astrophysics. Student participants work on specific research projects in close collaboration with members of the CTIO scientific and technical staff, such as galaxy clusters, gravitational lensing, supernovae, planetary nebulae, stellar populations, star clusters, star formation, variable stars and interstellar medium. The CTIO REU and PIA programs emphasize observational techniques and provide opportunities for direct observational experience using CTIO's state-of-the-art telescopes and instrumentation. The programs run for 10 weeks, from mid-January to the end of March. A two-night observing run on Cerro Tololo and a field trip to another observatory in Chile are included for students of both programs. These positions are full time, and those selected will receive a modest stipend and subsidized housing on the grounds of the offices of CTIO in La Serena, as well as travel costs to and from La Serena. In addition, the students have the

Proyecto de electrificación y alumbrado de la urbanización "Cerro Belmonte" en Madrid

OpenAIRE

García Galiano, Alejandro

2010-01-01

En primer lugar lo que el lector se encontrará será una Memoria Descriptiva donde se explican los elementos constructivos utilizados y diseñados para cumplir con el objetivo de dotar a la Urbanización “Cerro Belmonte” de Madrid de los servicios de Energía Eléctrica y Alumbrado Público. Los servicios de Energía Eléctrica comprenden: • Redes de Media Tensión • Centros de Transformación • Redes de Baja Tensión • Canalizaciones y arquetas Se contempla la definición de e...

Estudio de la líqueno flora encontrada en el Cerro de Quininí, Tibacuy, Cundinamarca

OpenAIRE

Alejandro Parra; Oscar Vivas; Francisco Hormaza

2000-01-01

Se realizó un muestreo de la liquen o flora del cerro de Quininí, Tibacuy, Cundinamarca para estudiar las características morfológicas externas de los géneros de líquenes encontrados en el. A su vez se hizo la revisión bibliográfica acerca de dichos géneros, datando así la riqueza de líquenes en la zona con 8 géneros en total y con respecto al papel de bioindicadores se mostró el grado de intervención para el lugar.

Relación entre la Comunicación y su Eficacia de los Programas Sociales del Ministerio de Desarrollo e Inclusión Social en el Cono Norte Distrito de Cerro Colorado, Arequipa, 2016

OpenAIRE

Llanos Mendoza, Daniela Flora

2017-01-01

La presente tesis cuyo enunciado del problema es: Relación entre la comunicación y su eficacia de los programas sociales del Ministerio de Desarrollo e Inclusión Social en el Cono Norte, distrito de Cerro Colorado de Arequipa “2016”; tiene como objetivo: determinar la relación entre la comunicación y su eficacia de los programas sociales del Ministerio de Desarrollo de Inclusión Social en el Cono Norte, Cerro Colorado, Arequipa. Se planteó la siguiente hipótesis para el presente estudio:...

Base hydrolysis and hydrothermal processing of PBX-9404

International Nuclear Information System (INIS)

Flesner, R.L.; Spontarelli, T.; Dell'Orco, P.C.; Sanchez, J.A.

1994-01-01

Base hydrolysis in combination with hydrothermal processing has been proposed as an environmentally acceptable alternative to open burning/open detonation for degradation and destruction of high explosives. In this report, the authors examine gaseous and aqueous products of base hydrolysis of the HMX-based plastic bonded explosive, PBX-9404. They also examined products from the subsequent hydrothermal treatment of the base hydrolysate. The gases produced from hydrolysis of PBX-9404 are ammonia, nitrous oxide, and nitrogen. Major aqueous products are sodium formate, acetate, nitrate, and nitrite, but not all carbon products have been identified. Hydrothermal processing of base hydrolysate destroyed up to 98% of the organic carbon in solution, and higher destruction efficiencies are possible. Major gas products detected from hydrothermal processing were nitrogen and nitrous oxide

Bacterial Diets of Primary Consumers at Hydrothermal Vents

Science.gov (United States)

Govenar, B.; Shank, T. M.

2008-12-01

Chemical energy produced by mixing hydrothermal fluids and seawater supports dense biological communities on mid-ocean ridges. The base of the food web at deep-sea hydrothermal vents is formed by chemolithoautotrophic bacteria that use the energy from the oxidation of reduced chemicals to fix inorganic carbon into simple sugars. With the exception of a few species that have chemolithoautotropic bacterial symbionts, most of the vent-endemic macrofauna are heterotrophs that feed on free-living bacteria, protists, and other invertebrates. The most abundant and diverse group of primary consumers in hydrothermal vent communities belong to the Gastropoda, particularly the patellomorph limpets. Gastropod densities can be as high as 2000 individuals m-2, and there can be as many as 13 species of gastropods in a single aggregation of the siboglinid tubeworm Riftia pachyptila and more than 40 species along the East Pacific Rise. Some gastropods are ubiquitous and others are found in specific microhabitats, stages of succession, or associated with different foundation species. To determine the mechanisms of species coexistence (e.g. resource partitioning or competition) among hydrothermal vent primary consumers and to track the flow of energy in hydrothermal vent communities, we employed molecular genetic techniques to identify the gut contents of four species of co-occurring hydrothermal vent gastropods, Eulepetopsis vitrea, Lepetodrilus elevatus, Lepetodrilus ovalis and Lepetodrilus pustulosus, collected from a single diffuse-flow hydrothermal vent site on the East Pacific Rise. Unique haplotypes of the 16S gene that fell among the epsilon-proteobacteria were found in the guts of every species, and two species had gut contents that were similar only to epsilon-proteobacteria. Two species had gut contents that also included haplotypes that clustered with delta-proteobacteria, and one species had gut contents that clustered with alpha- proteobacteria. Differences in the diets

Organic sulfur metabolisms in hydrothermal environments.

Science.gov (United States)

Rogers, Karyn L; Schulte, Mitchell D

2012-07-01

Sulfur is central to the metabolisms of many organisms that inhabit extreme environments. While biotic and abiotic cycling of organic sulfur compounds has been well documented in low-temperature anaerobic environments, cycling of organic sulfur in hydrothermal environments has received less attention. Recently published thermodynamic data have been used to estimate aqueous alkyl thiol and sulfide activities in deep-sea hydrothermal systems. Here we use geochemical mixing models to predict fluid compositions that result from mixing end-member hydrothermal fluid from the East Pacific Rise with bottom seawater. These fluid compositions are combined with estimates of methanethiol and dimethylsulfide activities to evaluate energy yields for potential organic sulfur-based metabolisms under hydrothermal conditions. Aerobic respiration has the highest energy yields (over -240 kJ/mol e⁻) at lower temperature; however, oxygen is unlikely to persist at high temperatures, restricting aerobic respiration to mesophilic communities. Nitrite reduction to N₂ has the highest energy yields at higher temperatures (greater than ∼40 °C). Nitrate and nitrite reduction to ammonium also yield significant energy (up to -70 kJ/mol e⁻). Much lower, but still feasible energy yields are calculated for sulfate reduction, disproportionation, and reduction with H₂. Organic compound family and the activity of methanethiol and dimethylsulfide were less important than metabolic strategy in determining overall energy yields. All metabolic strategies considered were exergonic within some portion of the mixing regime suggesting that organic sulfur-based metabolisms may be prevalent within deep-sea hydrothermal vent microbial communities. © 2012 Blackwell Publishing Ltd.

Voltammetric Investigation Of Hydrothermal Iron Speciation

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Charlotte eKleint

2016-05-01

Full Text Available Hydrothermal vent fluids are highly enriched in iron (Fe compared to ambient seawater, and organic ligands may play a role in facilitating the transport of some hydrothermal Fe into the open ocean. This is important since Fe is a limiting micronutrient for primary production in large parts of the world`s surface ocean. We have investigated the concentration and speciation of Fe in several vent fluid and plume samples from the Nifonea vent field, Coriolis Troughs, New Hebrides Island Arc, South Pacific Ocean using competitive ligand exchange - adsorptive cathodic stripping voltammetry (CLE - AdCSV with salicylaldoxime (SA as the artificial ligand. Our results for total dissolved Fe (dFe in the buoyant hydrothermal plume samples showed concentrations up to 3.86 µM dFe with only a small fraction between 1.1% and 11.8% being chemically labile. Iron binding ligand concentrations ([L] were found in µM level with strong conditional stability constants up to log K[L],Fe3+ of 22.9. Within the non-buoyant hydrothermal plume above the Nifonea vent field, up to 84.7% of the available Fe is chemically labile and [L] concentrations up to 97 nM were measured. [L] was consistently in excess of Felab, indicating that all available Fe is being complexed, which in combination with high Felab values in the non-buoyant plume, signifies that a high fraction of hydrothermal dFe is potentially being transported away from the plume into the surrounding waters, contributing to the global oceanic Fe budget.

The Spanish Exile Put to the Test: Polemics in the Pres between Indalecio Prieto and the Mexican Alfonso Junco regarding the gold aboard the yacht “Vita”

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Carlos Sola Ayape

2014-04-01

Full Text Available In November, 1946, just a few days before Miguel Alemán took charge as new president of Mexico, the Mexican press –concretely, the newspaper Novedades– would become an ink-and-paper stage for an important dialectic dispute between Alfonso Junco, a Mexican Catholic hispanicist, and Indalecio Prieto, a Spanish Socialist exile and undoubtedly, one of the most important political references of the Second Spanish Republic. Among the many questions left unanswered, there appeared the edges of one of the major issues that haunted the Spanish pilgrimage during its diaspora: the treasures removed before the end of the Civil War. This was so because the legitimation of Franco's regime was also built from the constant pages of accusations towards the “reds” in exile.

Biosphere in 3.5 Ga submarine hydrothermal system

Energy Technology Data Exchange (ETDEWEB)

Ueno, Yuichiro [Tokyo Univ. (Japan). Dept. of Earth Science and Astronomy

2003-04-01

Abundant organic matter (kerogen) was identified in {approx}3.5 Ga hydrothermal silica dikes from the North Pole area in the Pilbara craton, Western Australia. The silica dikes developed in the uppermost 1000 m of the ancient oceanic crust. Thus, they would have been deposited in the 3.5 Ga sub-seafloor hydrothermal system. The carbon and nitrogen isotopic compositions of the kerogen were analyzed in this study. Their highly {sup 13}C-depleted isotopic compositions ({delta}{sup 13}C = -38 to -33 per mille) strongly suggest that they are originally derived from biologically produced organic matter. The remarkable similarity of the {delta}{sup 13}C values between the kerogen and modern hydrothermal vent organisms may suggest that the kerogen was derived from chemoautotrophic organisms. This idea is also consistent with their nitrogen isotopic compositions ({delta}{sup 15}N = -4 to +4 per mille). The silica dikes consist mainly of fine-grained silica with minor pyrite and sphalerite. These mineral assemblages indicate that the silica dike was deposited from relatively low-temperature (probably less than 150degC) reducing hydrothermal fluid. Thus, anaerobic thermophilic/hyperthermophilic organisms could have survived in the hydrothermal fluid, which formed the silica dikes. Therefore, it is plausible that a chemoautotrophic-based biosphere (possibly methanogenesis) probably existed in the Early Archean sub-seafloor hydrothermal system. (author)

Impact of hydrothermalism on the ocean iron cycle.

Science.gov (United States)

Tagliabue, Alessandro; Resing, Joseph

2016-11-28

As the iron supplied from hydrothermalism is ultimately ventilated in the iron-limited Southern Ocean, it plays an important role in the ocean biological carbon pump. We deploy a set of focused sensitivity experiments with a state of the art global model of the ocean to examine the processes that regulate the lifetime of hydrothermal iron and the role of different ridge systems in governing the hydrothermal impact on the Southern Ocean biological carbon pump. Using GEOTRACES section data, we find that stabilization of hydrothermal iron is important in some, but not all regions. The impact on the Southern Ocean biological carbon pump is dominated by poorly explored southern ridge systems, highlighting the need for future exploration in this region. We find inter-basin differences in the isopycnal layer onto which hydrothermal Fe is supplied between the Atlantic and Pacific basins, which when combined with the inter-basin contrasts in oxidation kinetics suggests a muted influence of Atlantic ridges on the Southern Ocean biological carbon pump. Ultimately, we present a range of processes, operating at distinct scales, that must be better constrained to improve our understanding of how hydrothermalism affects the ocean cycling of iron and carbon.This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'. © 2016 The Author(s).

rights reserved Geophysical Identification of Hydrothermally Altered ...

African Journals Online (AJOL)

ADOWIE PERE

the pole to the magnetic data aided in mapping of various hydrothermally altered structures that may favour gold mineralisation. The interpretation of the aero data set has enhanced a lot of ... water serves as a concentrating, transporting and depositing agent through faults (structures) to the earth's surface. Hydrothermal ...

Comparison of microbial communities associated with three Atlantic ultramafic hydrothermal systems.

Science.gov (United States)

Roussel, Erwan G; Konn, Cécile; Charlou, Jean-Luc; Donval, Jean-Pierre; Fouquet, Yves; Querellou, Joël; Prieur, Daniel; Bonavita, Marie-Anne Cambon

2011-09-01

The distribution of Archaea and methanogenic, methanotrophic and sulfate-reducing communities in three Atlantic ultramafic-hosted hydrothermal systems (Rainbow, Ashadze, Lost City) was compared using 16S rRNA gene and functional gene (mcrA, pmoA and dsrA) clone libraries. The overall archaeal community was diverse and heterogeneously distributed between the hydrothermal sites and the types of samples analyzed (seawater, hydrothermal fluid, chimney and sediment). The Lost City hydrothermal field, characterized by high alkaline warm fluids (pH>11; Tphylum and Methanopyrales order were also retrieved from the Rainbow and Ashadze hydrothermal fluids. However, the methanogenic Methanococcales was the most widely distributed hyper/thermophilic archaeal group among the hot and acidic ultramafic-hosted hydrothermal system environments. Most of the lineages detected are linked to methane and hydrogen cycling, suggesting that in ultramafic-hosted hydrothermal systems, large methanogenic and methanotrophic communities could be fuelled by hydrothermal fluids highly enriched in methane and hydrogen. © 2011 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.

Hydrothermal processing of actinide contaminated organic wastes

International Nuclear Information System (INIS)

Worl, A.; Buelow, S.J.; Le, L.A.; Padilla, D.D.; Roberts, J.H.

1997-01-01

Hydrothermal oxidation is an innovative process for the destruction of organic wastes, that occurs above the critical temperature and pressure of water. The process provides high destruction and removal efficiencies for a wide variety of organic and hazardous substances. For aqueous/organic mixtures, organic materials, and pure organic liquids hydrothermal processing removes most of the organic and nitrate components (>99.999%) and facilitates the collection and separation of the actinides. We have designed, built and tested a hydrothermal processing unit for the removal of the organic and hazardous substances from actinide contaminated liquids and solids. Here we present results for the organic generated at the Los Alamos National Laboratory Plutonium Facility

Hydrothermal processing of inorganic components of Hanford tank sludge

International Nuclear Information System (INIS)

Oldenborg, R.; Buelow, S.J.; Dyer, R.B.; Anderson, G.; Dell'Orco, P.C.; Funk, K.; Wilmanns, E.; Knutsen, K.

1994-09-01

Hydrothermal Processing (HTP) is an attractive approach for the treatment of Hanford tank sludge. Hydrothermal Processing refers to a waste treatment technique in which an aqueous waste stream is fed through a chemical reactor at elevated temperatures and pressures to effect desired chemical transformations and separations. Transformations such as organic and nitrate destruction and sludge reformulation have been demonstrated at pilot scale using simulants of Hanford tank wastes. At sufficiently high temperatures and pressures organics and nitrates are destroyed in seconds, producing primarily simple products such as CO 3 2- , H 2 O, N 2 , N 2 O and OH - , and sludges are reduced in volume and reformulated as rapid settling oxides amenable to downstream separation, or in some cases reformulated as soluble products. This report describes the hydrothermal dissolution of chromium and chromium oxide; the hydrothermal oxidation of chromium with nitrate; hydrothermal dissolution of aluminum-bearing sludges; the solubility of aluminum compounds in caustic hydrothermal media; experimental techniques for the study of solubility and phase behavior; optical cell studies of basic aluminate solution solubilities; and high temperature, low density salt solubility in the packed-bed flow apparatus

TECNOLOGÍA Y SUBSISTENCIA EN EL SITIO ARQUEOLÓGICO CERRO TAPERA VÁZQUEZ (PARQUE NACIONAL PRE-DELTA, REPÚBLICA ARGENTINA

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Mariano Bonomo

2014-10-01

Full Text Available In this paper the results of the studies carried out on ceramic and bone materials recorded at Cerro Tapera Vázquez site (Argentinean Northeast are presented. Taxonomic, anatomic and taphonomic studies of bone assemblages and technological-decorative analysis and refitting of pottery were undertaken. The site is located on a mound next to El Ceibo Creek, where 16 m2 were excavated in 2008. Abundant smooth, incised and modeled pottery (handles and zoomorphic appendages and numerous bones remains of Myocastor coypus (most frequent taxon, Blastocerus dichotomus, Ozotoceros bezoarticus, Cavia aperea, Leopardus geoffroyi, Lycalopex gymnocercus, Hydrochaeris hydrochaeris, birds and fish (Siluriformes and Characiformes were recorded. Except Cavia aperea rodent and Dusicyon gimnocercus fox, all taxa show evidence of anthropic modification (cut marks, fresh fractures and burning. Two radiocarbon dates were obtained: 650 and 520 yrs. BP. The results reached in this study lead to the conclusion that the pre-Hispanic populations that occupied Cerro Tapera Vázquez by the end of the Late Holocene were riverine canoe peoples, with complex ceramic technology and subsistence based on hunting of coypu, capybara and cervids, fishing and small-scale horticulture.

Hydrothermal influence on nearshore sediments of Kos Island, Aegean Sea

Science.gov (United States)

Megalovasilis, Pavlos; Godelitsas, Athanasios

2015-04-01

The Kos-Nisyros volcanic centre is a long-active, Plio-Pleistocene magmatic system in the subduction zone along the easternmost edge of the active Hellenic volcanic arc in the Aegean Sea. Although today there are signs of relative quiescence in volcanic activity, active onshore fumaroles and shallow-sea hydrothermal vents persist on, amongst others, the island of Kos. The present study explores the large-scale imprint of hydrothermally sourced heavy metals and nutrients on the island's coastal marine environment, based on geochemical data collected in September 2007 from hydrothermal waters and surficial nearshore sediments (Kos is severely influenced by ongoing submarine hydrothermal activity, and confirm that shallow-water sediment Fe, Mn, Zn and Pb levels are substantially higher than those of other islands along the Hellenic volcanic arc, and even exceed those of some deep-water hydrothermal vents in other world regions. Evidently, there may be significant metallic sulphide deposits of hydrothermal origin at depth beneath Kos.

Spontaneous and Widespread Electricity Generation in Natural Deep-Sea Hydrothermal Fields.

Science.gov (United States)

Yamamoto, Masahiro; Nakamura, Ryuhei; Kasaya, Takafumi; Kumagai, Hidenori; Suzuki, Katsuhiko; Takai, Ken

2017-05-15

Deep-sea hydrothermal vents discharge abundant reductive energy into oxidative seawater. Herein, we demonstrated that in situ measurements of redox potentials on the surfaces of active hydrothermal mineral deposits were more negative than the surrounding seawater potential, driving electrical current generation. We also demonstrated that negative potentials in the surface of minerals were widespread in the hydrothermal fields, regardless of the proximity to hydrothermal fluid discharges. Lab experiments verified that the negative potential of the mineral surface was induced by a distant electron transfer from the hydrothermal fluid through the metallic and catalytic properties of minerals. These results indicate that electric current is spontaneously and widely generated in natural mineral deposits in deep-sea hydrothermal fields. Our discovery provides important insights into the microbial communities that are supported by extracellular electron transfer and the prebiotic chemical and metabolic evolution of the ocean hydrothermal systems. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hydrothermal systems in small ocean planets.

Science.gov (United States)

Vance, Steve; Harnmeijer, Jelte; Kimura, Jun; Hussmann, Hauke; Demartin, Brian; Brown, J Michael

2007-12-01

We examine means for driving hydrothermal activity in extraterrestrial oceans on planets and satellites of less than one Earth mass, with implications for sustaining a low level of biological activity over geological timescales. Assuming ocean planets have olivine-dominated lithospheres, a model for cooling-induced thermal cracking shows how variation in planet size and internal thermal energy may drive variation in the dominant type of hydrothermal system-for example, high or low temperature system or chemically driven system. As radiogenic heating diminishes over time, progressive exposure of new rock continues to the current epoch. Where fluid-rock interactions propagate slowly into a deep brittle layer, thermal energy from serpentinization may be the primary cause of hydrothermal activity in small ocean planets. We show that the time-varying hydrostatic head of a tidally forced ice shell may drive hydrothermal fluid flow through the seafloor, which can generate moderate but potentially important heat through viscous interaction with the matrix of porous seafloor rock. Considering all presently known potential ocean planets-Mars, a number of icy satellites, Pluto, and other trans-neptunian objects-and applying Earth-like material properties and cooling rates, we find depths of circulation are more than an order of magnitude greater than in Earth. In Europa and Enceladus, tidal flexing may drive hydrothermal circulation and, in Europa, may generate heat on the same order as present-day radiogenic heat flux at Earth's surface. In all objects, progressive serpentinization generates heat on a globally averaged basis at a fraction of a percent of present-day radiogenic heating and hydrogen is produced at rates between 10(9) and 10(10) molecules cm(2) s(1).

Coupling hydrothermal liquefaction and anaerobic digestion for energy valorization from model biomass feedstocks.

Science.gov (United States)

Posmanik, Roy; Labatut, Rodrigo A; Kim, Andrew H; Usack, Joseph G; Tester, Jefferson W; Angenent, Largus T

2017-06-01

Hydrothermal liquefaction converts food waste into oil and a carbon-rich hydrothermal aqueous phase. The hydrothermal aqueous phase may be converted to biomethane via anaerobic digestion. Here, the feasibility of coupling hydrothermal liquefaction and anaerobic digestion for the conversion of food waste into energy products was examined. A mixture of polysaccharides, proteins, and lipids, representing food waste, underwent hydrothermal processing at temperatures ranging from 200 to 350°C. The anaerobic biodegradability of the hydrothermal aqueous phase was examined through conducting biochemical methane potential assays. The results demonstrate that the anaerobic biodegradability of the hydrothermal aqueous phase was lower when the temperature of hydrothermal processing increased. The chemical composition of the hydrothermal aqueous phase affected the anaerobic biodegradability. However, no inhibition of biodegradation was observed for most samples. Combining hydrothermal and anaerobic digestion may, therefore, yield a higher energetic return by converting the feedstock into oil and biomethane. Copyright © 2017 Elsevier Ltd. All rights reserved.

Hydrothermal processing of radioactive combustible waste

International Nuclear Information System (INIS)

Worl, L.A.; Buelow, S.J.; Harradine, D.; Le, L.; Padilla, D.D.; Roberts, J.H.

1998-01-01

Hydrothermal processing has been demonstrated for the treatment of radioactive combustible materials for the US Department of Energy. A hydrothermal processing system was designed, built and tested for operation in a plutonium glovebox. Presented here are results from the study of the hydrothermal oxidation of plutonium and americium contaminated organic wastes. Experiments show the destruction of the organic component to CO 2 and H 2 O, with 30 wt.% H 2 O 2 as an oxidant, at 540 C and 46.2 MPa. The majority of the actinide component forms insoluble products that are easily separated by filtration. A titanium liner in the reactor and heat exchanger provide corrosion resistance for the oxidation of chlorinated organics. The treatment of solid material is accomplished by particle size reduction and the addition of a viscosity enhancing agent to generate a homogeneous pumpable mixture

Tornos de alfarero protohistóricos del Cerro de las Cabezas (Valdepeñas, Ciudad Real = Protohistoric potter’s wheels in the Iberian archaeological site ‘Cerro de las Cabezas’ (Valdepeñas, Ciudad Real

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Domingo Fernández Maroto

2015-11-01

Full Text Available El yacimiento ibérico del “Cerro de las Cabezas” ha proporcionado cuatro piezas líticas que identificamos como pertenecientes a tornos de alfarero. Este oppidum ya ha sido puesto de manifiesto como un centro productor y difusor de cerámica ibérica. A través del análisis e interpretación de estas piezas y de las referencias obtenidas en otros yacimientos de la Península Ibérica y del Próximo Oriente, hemos podido confirmar que dos de estas piezas corresponden a un mismo torno, por lo que podemos considerar esta circunstancia como excepcional, dado que hasta el momento, en la Península Ibérica solo se tienen noticias de hallazgos de piezas descontextualizadas y dispersas. Nos encontramos así, con el primer torno  protohistórico completo adscrito a una cronología en torno al siglo III a.C.The Iberian archaeological site ‘Cerro de las Cabezas’ has provided four stone pieces that we identify as belonging to potter’s wheels. This oppidum has been revealed as a producer and spreading centre of Iberian pottery. Through the analysis and interpretation of these pieces, as well as the references obtained from other sites in the Iberian Peninsula and the Middle East, we are able to confirm that two of these findings correspond to the same potter’s wheel. As a result, we could take into account this fact as an exceptional circumstance, because, so far, we only know about some scattered pieces taken out of context in the Iberian Peninsula. Consequently, we have maybe found the first complete protohistoric slow potter’s wheel dating from around the third century BC.

Hydrothermal Liquefaction of Biomass

Energy Technology Data Exchange (ETDEWEB)

Elliott, Douglas C.

2010-12-10

Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international

MOVIMIENTOS DE LADERA Y PLANEAMIENTO URBANÍSTICO: EL CONFLICTO DEL CERRO DEL OPE, ARCHENA (MURCIA

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María Dolores Gómez Moreno

2009-01-01

Full Text Available Los desprendimientos son un proceso natural que afecta, de forma generalizada en el Valle de Ricote, a las laderas del tipo cantil-talud. Su peligrosidad radica en que los bloques desprendidos del escarpe ruedan con facilidad, talud abajo, cuando son descalzados por efecto de la escorrentía superfi cial o desestabilizados por movimientos sísmicos. El planeamiento urbanístico se convierte en factor inductor del riesgo al clasifi car como urbanizables y urbanos suelos que, por su ubicación en pie de ladera, deberían excluirse de cualquier proceso urbanizador. Este es el caso de Archena en el entorno inmediato del cerro del Ope.

Treatment of urban sludge by hydrothermal carbonization.

Science.gov (United States)

Xu, Xiwei; Jiang, Enchen

2017-08-01

Urban sludge was treated by Hydrothermal carbonization (HTC). The effect of hydrothermal carbonization temperature, mixing with or without catalysts on solid products yield, heavy metal contents, turbidity and COD value was evaluated. The result showed solid products yield decreased from 92.04% to 52.65% when the temperature increased from 180 to 300°C. And the Cu, Zn, and Pb contents under exchangeable states decreased and reached discharge standard. Addition of FeCl 3 or Al(OH) 3 resulted in a significant increase in the exchangeable states of Zn, Pb, Cr, and Cd and decrease in their residual states. The turbidity and COD value of hydrothermal liquid decreased from 450° to 175°, and 13 to 6.8g/L, with increasing hydrothermal temperature. Comparison with HTC, solid productivity from low-temperature pyrolysis is higher. The exchangeable states of Cu, Zn, and Cr exceeded the limiting values. Our results show HTC can facilitate transforming urban sludge into no-pollution and energy-rich products. Copyright © 2017 Elsevier Ltd. All rights reserved.

Water column imaging on hydrothermal vent in Central Indian Ridge

Science.gov (United States)

Koh, J.; Park, Y.

2017-12-01

Water column imaging with Multibeam echosounder systems (MBES) is recently becoming of increasing interest for oceanographic studies. Especially gas bubbles and hot water exposed from hydrothermal vents make acoustic impedance anomalies in cold seawater, water column imaging is very useful for the researchers who want to detect some kinds of hydrothermal activity. We conducted a hydrothermal exploration program, called "INVENT17", using the MBES system, KONGBERG EM122 (12kHz, 1°×1°), mounted on R/V ISABU and we deployed other equipments including video guided hydraulic grab, tow-yo CTD and general CTD with MAPR (Miniature Autonomous Plume Recorder) in 2017. First, to evaluate its capabilities of detection of hydrothermal vent, the surveys using the MBES were conducted at the Solitaire Field, previously identified hydrothermal area of the Central Indian Ridge. The bathymetric data obtained from MBES provided information about detailed morphology of seafloor, but we were not able to achieve the information from the water column imaging data. But the clue of existence of active hydrothermal vent was detected through the values of ΔNTU, dEh/dt, and OPR gained from MAPR, the data means that the hydrothermal activity affects 100m from the seafloor. It could be the reason that we can't find the hydrothermal activity because the range resolution of water column imaging is pretty rough so that the size of 100m-scaled activity has low possibility to distinguish from seafloor. The other reason is there are no sufficient objects to cause strong scattering like as CO2 bubbles or droplets unlike in the mid-Okinawa Trough. And this suggests that can be a important standard to identify properties of hydrothermal vent sites depending on the presence of scattering objects in water mass. To justify this, we should perform more chemical analysis of hot water emanating from hydrothermal vent and collected several bottles of water sample to do that.

Anchoring the landscape: human utilization of the Cerro Gavilán 2 rockshelter, Middle Orinoco, from the Early Holocene to the present

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Kay Scaramelli

Full Text Available Abstract Initial archaeological investigations at Cerro Gavilán 2, a rockshelter located in the Bolívar State of Venezuela, reveal evidence for human activity that spans the Early Holocene to the present. This report summarizes the information obtained through surface collection, limited excavation, and documentation of the surface features and rock art in the cave. Accelerator mass spectrometry (AMS 14C analysis established dates from excavated strata that range between 9250 ± 60 BP to 3440 ± 40 BP, and are associated with a unifacial flake technology and charred faunal and floral remains, whereas surface remains span the known ceramic sequence for the area. Rock art corresponds to distinctive superimposed styles that indicate continual repainting of the cave through time, serving to anchor the site to the landscape for multiple societies inhabiting the region. It is suggested that the shelter may have fulfilled different functions over time and a sequence of seasonal residential, ritual, and funerary activities is proposed. The rich cultural context found in Cerro Gavilán 2 contributes to advances in Amazonian archaeology that are redefining our knowledge of early developments and the complexity of human/environmental interactions in tropical America.

Gestión del agua subterránea en el Barrio Cerro Los Leones de Tandil (Argentina)

OpenAIRE

Rodriguez, Corina Iris; Jacinto, Guillermina; Ruiz de Galarreta, Alejandro; Banda Noriega, Roxana

2010-01-01

En este trabajo se describen y analizan los actores y modos de explotación y uso involucrados en la gestión del recurso hídrico subterráneo en un barrio periférico de Tandil -Cerro Los Leones- (Provincia de Buenos Aires, Argentina), que carece de servicios de agua potable y cloacas. Estudios previos demostraron contaminación química y bacteriológica del agua que pone en riesgo la salud de la población. Se caracterizan los modos de uso y explotación del agua, señalando importantes deficiencias...

Hydrothermal Carbonization of Seaweed For Advanced Biochar Production

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Prakoso Tirto

2018-01-01

Full Text Available Seaweed such as Eucheuma Cottonii is a potential source of biomaterialIts high moisture content makes it suitable for hydrothermal conversion process since it doesn’t need to utilize dry feedstock. The aim of this study is to convert the biomass of red seaweed Eucheuma Cottonii into alternative fuels and high value biomaterials using hydrothermal process. The hydrothermal process seaweed Eucheuma Cottonii produce two types of products, liquid product and char (solid. This research focus on the char product. The char from hydrothermal process was then activated using the tubular furnace. The yield for activated char is 7.5 % and results of SEM analysis of activated char showed the formation of allotropes carbon include carbon micro spheres, carbon micro fibres and graphene. These structures have encountered application in a wide range of technological fields, such as adsorption, catalysis, hydrogen storage or electronics.

Solidification of glass powder by a hydrothermal hot-pressing technique

International Nuclear Information System (INIS)

Nishioka, Mamoru; Yanagisawa, Kazumichi; Yamasaki, Nakamichi

1986-01-01

A borosilicate glass powder was solidified with a NaOH solution or distilled water by the hydrothermal hot-pressing technique. The effect of hydrothermal conditions on the compressive strength was investigated, and the densification mechanism of the glass powder during the hydrothermal hot-pressing was discussed in terms of isothermal shrinkage. The glass powder was successfully solidified by hydrothermal hot-pressing at a reaction temperature lower than that of an ordinary pressure sintering. The solidified body obtained in the presence of distilled water (10 wt%) at 280 deg C had a high compressive strength of about 2300 kg/cm 2 . The analysis of initial densification process of the glass powder in hydrothermal hot-pressing with Murray's rate equation revealed that the densification proceeds both by viscous flow and by rearrangement process. Analysis of the shrinkage rates with a rate equation of hydrothermal reaction suggested that the dissolution of particles into solution controlled the initial densification of the glass powder, and that the alkaline metal acted as a catalyst. (author)

Effect of hydrothermal treatment of coal on its associative structure

Energy Technology Data Exchange (ETDEWEB)

Shui Heng-fu; Wang Zhi-cai; Wang Gao-qiang; Niu Min-feng [Anhui University of Technology, Maanshan (China). School of Chemistry & Chemical Engineering

2006-10-15

4 bituminous coals with different ranks were thermally and hydrothermally treated under different conditions, and the raw and treated coals were extracted with carbon disulfide/N-2-pyrrolidinone (CS{sub 2}/NMP) mixed solvent (1:1 by volume). It is found that the extraction yields of the thermal or hydrothermal treated coals at proper conditions increase in different extent. The increments of extraction yields for hydrothermal treated coals are higher than those of thermal treated coals. FT-IR shows that the adsorption peaks at 3410 cm{sup -1} attributed to OH group for the hydrothermal treated coals decrease, suggesting the dissociation of the coal aggregation structure due to the breakage of hydrogen bonds, resulting in the increase of extraction yields for the treated coals. For higher rank coal, the removal of minerals and the dissociation of {pi}-cation association after hydrothermal treatment of coal may be responsible for the increase of extraction yield. In addition, the mechanism of hydrothermal treatment of coal was discussed. 15 refs., 2 figs., 5 tabs.

Hydrothermal industrialization: direct heat development. Final report

Energy Technology Data Exchange (ETDEWEB)

1982-05-01

A description of hydrothermal resources suitable for direct applications, their associated temperatures, geographic distribution and developable capacity are given. An overview of the hydrothermal direct-heat development infrastructure is presented. Development activity is highlighted by examining known and planned geothermal direct-use applications. Underlying assumptions and results for three studies conducted to determine direct-use market penetration of geothermal energy are discussed.

Mid amphibolite facies metamorphism of harzburgites in the Neoproterozoic Cerro Mantiqueiras Ophiolite, southernmost Brazil

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HARTMANN LÉO A.

2003-01-01

Full Text Available Valuable information is retrieved from the integrated investigation of the field relationships, microstructure and mineral compositions of harzburgites from the Neoproterozoic Cerro Mantiqueiras Ophiolite. This important tectonic marker of the geological evolution of southernmost Brazilian Shield was thoroughly serpentinized during progressive metamorphism, because the oldest mineral assemblage is: olivine + orthopyroxene + tremolite + chlorite + chromite. This M1 was stabilized in mid amphibolite facies - 550-600ºC as calculated from mineral equilibria. No microstructural (e.g. ductile deformation of olivine or chromite or compositional (e.g. mantle spinel remnant of mantle history was identified. A metamorphic event M2 occurred in the low amphibolite facies along 100 m-wide shear zones, followed by intense serpentinization (M3 and narrow 1-3 m-wide shear zones (M4 containing asbestos.

EFFECTS OF HEAT-FLOW AND HYDROTHERMAL FLUIDS FROM ...

African Journals Online (AJOL)

Volcanic intrusions and hydrothermal activity have modified the diagenetic minerals. In the Ulster Basin, UK, most of the authigenic mineralization in the Permo-Triassic sandstones pre-dated tertiary volcanic intrusions. The hydrothermal fluids and heat-flow from the volcanic intrusions did not affect quartz and feldspar ...

Mineralogy and geological significance of hydrothermal deposits from the Okinawa Trough

Science.gov (United States)

Zhang, Xia; Zhai, Shikui; Yu, Zenghui; Wang, Shujie; Cai, Zongwei

2018-04-01

The study of hydrothermal deposits in the Okinawa Trough can help us to uncover the hydrothermal mineralization characteristics in the back-arc basin during the early expanding stage. Mineralogy and geological significance of hydrothermal deposits from both the middle and southern trough are studied in this paper. First of all, using optical microscope to confirm the mineral compositions, characteristics of crystal shape, paragenetic relationship and minerals crystallization order. Then the minerals chemical composition were analyzed in virtue of electron microprobe. On these basis, the paragenetic sequence and the mineralization characteristics of the hydrothermal deposits were discussed. The results show that the hydrothermal deposit from the mid-Okinawa Trough belongs to Zn-Cu-rich type, consisting dominantly of sulfide minerals such as sphalerite, chalcopyrite, pyrite, etc. The minerals crystallization order is first generation pyrite(PyI)-sphalerite-chalcopyrite-galena-second generation pyrite(PyII)-amorphous silica. While the deposit from the southern Okinawa Trough is Ba-Zn-Pb-rich type mainly composing of barite, sphalerite, galena, etc. The minerals crystallization order is barite-pyrite-sphalerite-tetrahedrite-galena-chalcopyrite-amorphous silica. Hydrothermal fluid temperature in the mid-Okinawa Trough undergoes a process from high to low, which is high up to 350 °C in the early stage, but decreasing gradually with the evolution of hydrothermal fluid. On the contrary, the hydrothermal activity in the southern Okinawa Trough is low temperature dominated, but the mineralization environment is unstable and the fluid temperature changes drastically during the period of hydrothermal activity.

Hydrothermal liquefaction of biomass

DEFF Research Database (Denmark)

Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

2014-01-01

Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...

The hydrothermal evolution of the Kawerau geothermal system, New Zealand

Science.gov (United States)

Milicich, S. D.; Chambefort, I.; Wilson, C. J. N.; Charlier, B. L. A.; Tepley, F. J.

2018-03-01

Hydrothermal alteration zoning and processes provide insights into the evolution of heat source(s) and fluid compositions associated with geothermal systems. Traditional petrological techniques, combined with hydrothermal alteration studies, stable isotope analyses and geochronology can resolve the nature of the fluids involved in hydrothermal processes and their changes through time. We report here new findings along with previous unpublished works on alteration patterns, fluid inclusion measurements and stable isotope data to provide insights into the thermal and chemical evolution of the Kawerau geothermal system, New Zealand. These data indicate the presence of two hydrothermal events that can be coupled with chronological data. The earlier period of hydrothermal activity was initiated at 400 ka, with the heat driving the hydrothermal system inferred to be from the magmatic system that gave rise to rhyolite lavas and sills of the Caxton Formation. Isotopic data fingerprint fluids attributed to this event as meteoric, indicating that the magma primarily served as a heat source driving fluid circulation, and was not releasing magmatic fluids in sufficient quantity to affect the rock mineralogy and thus inferred fluid compositions. The modern Kawerau system was initiated at 16 ka with hydrothermal eruptions linked to shallow intrusion of magma at the onset of activity that gave rise to the Putauaki andesite cone. Likely associated with this later event was a pulse of magmatic CO2, resulting in large-scale deposition of hydrothermal calcite enriched in 18O. Meteoric water-dominated fluids subsequently overwhelmed the magmatic fluids associated with this 18O-rich signature, and both the fluid inclusion microthermometry and stable isotope data reflect a change to the present-day fluid chemistry of low salinity, meteoric-dominated waters.

Burning down the brewery: establishing and evacuating an ancient imperial colony at Cerro Baul, Peru.

Science.gov (United States)

Moseley, Michael E; Nash, Donna J; Williams, Patrick Ryan; DeFrance, Susan D; Miranda, Ana; Ruales, Mario

2005-11-29

Before the Inca reigned, two empires held sway over the central Andes from anno Domini 600 to 1000: the Wari empire to the north ruled much of Peru, and Tiwanaku to the south reigned in Bolivia. Face-to-face contact came when both colonized the Moquegua Valley sierra in southern Peru. The state-sponsored Wari incursion, described here, entailed large-scale agrarian reclamation to sustain the occupation of two hills and the adjacent high mesa of Cerro Baúl. Monumental buildings were erected atop the mesa to serve an embassy-like delegation of nobles and attendant personnel that endured for centuries. Final evacuation of the Baúl enclave was accompanied by elaborate ceremonies with brewing, drinking, feasting, vessel smashing, and building burning.

Can Life Begin on Enceladus? A Perspective from Hydrothermal Chemistry.

Science.gov (United States)

Deamer, David; Damer, Bruce

2017-09-01

Enceladus is a target of future missions designed to search for existing life or its precursors. Recent flybys of Enceladus by the Cassini probe have confirmed the existence of a long-lived global ocean laced with organic compounds and biologically available nitrogen. This immediately suggests the possibility that life could have begun and may still exist on Enceladus. Here we will compare the properties of two proposed sites for the origin of life on Earth-hydrothermal vents on the ocean floor and hydrothermal volcanic fields at the surface-and ask whether similar conditions could have fostered the origin of life on Enceladus. The answer depends on which of the two sites would be more conducive for the chemical evolution leading to life's origin. A hydrothermal vent origin would allow life to begin in the Enceladus ocean, but if the origin of life requires freshwater hydrothermal pools undergoing wet-dry cycles, the Enceladus ocean could be habitable but lifeless. These arguments also apply directly to Europa and indirectly to early Mars. Key Words: Enceladus-Hydrothermal vents-Hydrothermal fields-Origin of life. Astrobiology 17, 834-839.

Hydrothermal carbonization and torrefaction of grape pomace: a comparative evaluation.

Science.gov (United States)

Pala, Mehmet; Kantarli, Ismail Cem; Buyukisik, Hasan Baha; Yanik, Jale

2014-06-01

Grape pomace was treated by hydrothermal carbonization (sub-critical water, 175-275°C) and torrefaction (nitrogen atmosphere, 250 and 300°C), with mass yield of solid product (char) ranging between 47% and 78%, and energy densification ratio to 1.42-1.15 of the original feedstock. The chars were characterised with respect to their fuel properties, morphological and structural properties and combustion characteristics. The hydrothermal carbonization produced the char with greater energy density than torrefaction. The chars from torrefaction were found to be more aromatic in nature than that from hydrothermal carbonization. Hydrothermal carbonization process produced the char having high combustion reactivity. Most interesting was the finding that aqueous phase from hydrothermal carbonization had antioxidant activity. The results obtained in this study showed that HTC appears to be promising process for a winery waste having high moisture content. Copyright © 2014 Elsevier Ltd. All rights reserved.

Cuprous oxide thin films grown by hydrothermal electrochemical deposition technique

International Nuclear Information System (INIS)

Majumder, M.; Biswas, I.; Pujaru, S.; Chakraborty, A.K.

2015-01-01

Semiconducting cuprous oxide films were grown by a hydrothermal electro-deposition technique on metal (Cu) and glass (ITO) substrates between 60 °C and 100 °C. X-ray diffraction studies reveal the formation of cubic cuprous oxide films in different preferred orientations depending upon the deposition technique used. Film growth, uniformity, grain size, optical band gap and photoelectrochemical response were found to improve in the hydrothermal electrochemical deposition technique. - Highlights: • Cu 2 O thin films were grown on Cu and glass substrates. • Conventional and hydrothermal electrochemical deposition techniques were used. • Hydrothermal electrochemical growth showed improved morphology, thickness and optical band gap

Hydrothermal dolomite reservoir facies in the Sinian Dengying Fm, central Sichuan Basin

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Yuqiang Jiang

2017-07-01

Full Text Available The Upper Sinian Dengying Fm is the focus of natural gas exploration in the central part of the Sichuan Basin (central Sichuan Basin in recent years. Especially, epigenic karstification and its resulted reservoir-seepage spaces have always been the focal points in researches. Based on the petrographic characteristics of drilling cuttings and core samples, and through experimental analysis by using trace elements, isotopes, and cathodoluminescence, the Dengying Fm dolomite was demonstrated to have matrix recrystallized dolomite (MRD, filled saddle dolomite (FSD (the mean homogenization temperature of inclusion: 178.5 °C, high concentrations of Fe & Mn, slightly positive 87Sr/86Sr value and hydrothermal minerals combination (including sphalerite, galena, pyrite, and quartz, etc.. Thus, it was proposed that hydrothermal dolomite reservoir facies (HDRF exist in the Dengying Fm dolomite, in other words, the dolomite reservoir is composed of hydrothermal dissolved pores, intercrystalline pores of hydrothermal origin, hydrothermal caverns and expanded fractures, and was formed due to the reworking of hydrothermal fluid on tight matrix dolomite. Identification marks are presented in terms of petrography and geochemistry so that hydrothermal dolomite reservoir facies can be effectively recognized and identified. It is concluded that the development of hydrothermal dolomite reservoir facies in this area are preliminary controlled by deep and large basement faults and the strength of hydrothermal fluids.

Paleomagnetism in the Determination of the Emplacement Temperature of Cerro Colorado Tuff Cone, El Pinacate Volcanic Field, Sonora, Mexico.

Science.gov (United States)

Rodriguez Trejo, A.; Alva-Valdivia, L. M.; Vidal Solano, J. R.; Garcia Amador, B.; Gonzalez-Rangel, J. A.

2014-12-01

Cerro Colorado Maar is located at the World Heritage Site, biosphere reserve El Pinacate and Gran Desierto del Altar, at the NNW region of Sonora, Mexico (in El Pinacate Volcanic Field). It is a tuff cone, about 1 km diameter, result of several phreatomagmatic episodes during the late Quaternary. We report paleomagnetic and rock magnetic properties from fusiform volcanic bombs obtained from the borders of Cerro Colorado. This study is based in the thermoremanent magnetization TRM normally acquired by volcanic rocks, which can be used to estimate the emplacement temperature range. We performed the experiments on 20 lithic fragments (10 cm to 20 cm approximately), taking 6-8 paleomagnetic cores from each. Rock magnetic experiments (magnetic susceptibility vs. temperature (k-T), hysteresis curves and FORC analysis, shows that the main magnetic mineral carriers of magnetization are titanomagnetite and titanohematite in different levels of intergrowth. The k-T curves suggest in many cases, only one magnetic phase, but also in other cases a second magnetic phase. Thermal demagnetization was used to demagnetize the specimens in detailed short steps and make a well-defined emplacement temperature determination ranges. We found that temperature emplacement determination range for these two magnetic phases is between 350-450 °C, and 550-580 °C, respectively. These results are consistent with those expected in an eruption of Surtsey type, showing a distinct volcanic activity compared to the other craters from El Pinacate volcanic field.

Impact-generated Hydrothermal Activity at the Chicxulub Crater

Science.gov (United States)

Kring, D. A.; Zurcher, L.; Abramov, O.

2007-05-01

Borehole samples recovered from PEMEX exploration boreholes and an ICDP scientific borehole indicate the Chicxulub impact event generated hydrothermal alteration throughout a large volume of the Maya Block beneath the crater floor and extending across the bulk of the ~180 km diameter crater. The first indications of hydrothermal alteration were observed in the crater discovery samples from the Yucatan-6 borehole and manifest itself in the form of anhydrite and quartz veins. Continuous core from the Yaxcopoil-1 borehole reveal a more complex and temporally extensive alteration sequence: following a brief period at high temperatures, impact- melt-bearing polymict breccias and a thin, underlying unit of impact melt were subjected to metasomatism, producing alkali feldspar, sphene, apatite, and magnetite. As the system continued to cool, smectite-series phyllosilicates appeared. A saline solution was involved. Stable isotopes suggest the fluid was dominated by a basinal brine created mostly from existing groundwater of the Yucatan Peninsula, although contributions from down-welling water also occurred in some parts of the system. Numerical modeling of the hydrothermal system suggests circulation occurred for 1.5 to 2.3 Myr, depending on the permeability of the system. Our understanding of the hydrothermal system, however, is still crude. Additional core recovery projects, particularly into the central melt sheet, are needed to better evaluate the extent and duration of hydrothermal alteration.

Hydrothermal contamination of public supply wells in Napa and Sonoma Valleys, California

International Nuclear Information System (INIS)

Forrest, M.J.; Kulongoski, J.T.; Edwards, M.S.; Farrar, C.D.; Belitz, K.; Norris, R.D.

2013-01-01

Highlights: ► We analyzed the geochemistry of 44 public supply wells in Napa and Sonoma Valleys. ► We investigated mixing of groundwater with hydrothermal fluids. ► We used multivariate statistical analyses and modeling to characterize wells. ► We found that nine public supply wells contained 14–30% hydrothermal fluids. ► Some contaminated wells contain potentially harmful concentrations of As, F and B. - Abstract: Groundwater chemistry and isotope data from 44 public supply wells in the Napa and Sonoma Valleys, California were determined to investigate mixing of relatively shallow groundwater with deeper hydrothermal fluids. Multivariate analyses including Cluster Analyses, Multidimensional Scaling (MDS), Principal Components Analyses (PCA), Analysis of Similarities (ANOSIM), and Similarity Percentage Analyses (SIMPER) were used to elucidate constituent distribution patterns, determine which constituents are significantly associated with these hydrothermal systems, and investigate hydrothermal contamination of local groundwater used for drinking water. Multivariate statistical analyses were essential to this study because traditional methods, such as mixing tests involving single species (e.g. Cl or SiO 2 ) were incapable of quantifying component proportions due to mixing of multiple water types. Based on these analyses, water samples collected from the wells were broadly classified as fresh groundwater, saline waters, hydrothermal fluids, or mixed hydrothermal fluids/meteoric water wells. The Multivariate Mixing and Mass-balance (M3) model was applied in order to determine the proportion of hydrothermal fluids, saline water, and fresh groundwater in each sample. Major ions, isotopes, and physical parameters of the waters were used to characterize the hydrothermal fluids as Na–Cl type, with significant enrichment in the trace elements As, B, F and Li. Five of the wells from this study were classified as hydrothermal, 28 as fresh groundwater, two as

Hydrothermal activity at slow-spreading ridges: variability and importance of magmatic controls

Science.gov (United States)

Escartin, Javier

2016-04-01

Hydrothermal activity along mid-ocean ridge axes is ubiquitous, associated with mass, chemical, and heat exchanges between the deep lithosphere and the overlying envelopes, and sustaining chemiosynthetic ecosystems at the seafloor. Compared with hydrothermal fields at fast-spreading ridges, those at slow spreading ones show a large variability as their location and nature is controlled or influenced by several parameters that are inter-related: a) tectonic setting, ranging from 'volcanic systems' (along the rift valley floor, volcanic ridges, seamounts), to 'tectonic' ones (rift-bounding faults, oceanic detachment faults); b) the nature of the host rock, owing to compositional heterogeneity of slow-spreading lithosphere (basalt, gabbro, peridotite); c) the type of heat source (magmatic bodies at depth, hot lithosphere, serpentinization reactions); d) and the associated temperature of outflow fluids (high- vs.- low temperature venting and their relative proportion). A systematic review of the distribution and characteristics of hydrothermal fields along the slow-spreading Mid-Atlantic Ridge suggests that long-lived hydrothermal activity is concentrated either at oceanic detachment faults, or along volcanic segments with evidence of robust magma supply to the axis. A detailed study of the magmatically robust Lucky Strike segment suggests that all present and past hydrothermal activity is found at the center of the segment. The association of these fields to central volcanos, and the absence of indicators of hydrothermal activity along the remaining of the ridge segment, suggests that long-lived hydrothermal activity in these volcanic systems is maintained by the enhanced melt supply and the associated magma chamber(s) required to build these volcanic edifices. In this setting, hydrothermal outflow zones at the seafloor are systematically controlled by faults, indicating that hydrothermal fluids in the shallow crust exploit permeable fault zones to circulate. While

Parasitosis intestinales en niños ingresados en el Hospital Universitario Pediátrico del Cerro, La Habana, Cuba

OpenAIRE

Núñez, Fidel A.; González, Odalys M.; Bravo, . José R.; Escobedo, Ángel A.; González, Ida

2003-01-01

Se realizó un estudio sobre parasitismo intestinal en 401 niños ingresados en el Hospital Universitario Pediátrico del Cerro entre los meses de mayo y junio de 1999. Para esta finalidad se tomó una muestra representativa, aleatoria y estratificada por servicios. Por cada niño, se recogieron 3 muestras de heces preservadas en formaldehído, las que se procesaron por 3 métodos parasitológicos. La prevalencia de parasitismo intestinal fue de 15 % en el hospital, y no se encontraron diferencias en...

Effects of iron-containing minerals on hydrothermal reactions of ketones

Science.gov (United States)

Yang, Ziming; Gould, Ian R.; Williams, Lynda B.; Hartnett, Hilairy E.; Shock, Everett L.

2018-02-01

Hydrothermal organic transformations occurring in geochemical processes are influenced by the surrounding environments including rocks and minerals. This work is focused on the effects of five common minerals on reactions of a model ketone substrate, dibenzylketone (DBK), in an experimental hydrothermal system. Ketones play a central role in many hydrothermal organic functional group transformations, such as those converting hydrocarbons to oxygenated compounds; however, how these minerals control the hydrothermal chemistry of ketones is poorly understood. Under the hydrothermal conditions of 300 °C and 70 MPa for up to 168 h, we observed that, while quartz (SiO2) and corundum (Al2O3) had no detectable effect on the hydrothermal reactions of DBK, iron-containing minerals, such as hematite (Fe2O3), magnetite (Fe3O4), and troilite (synthetic FeS), accelerated the reaction of DBK by up to an order of magnitude. We observed that fragmentation products, such as toluene and bibenzyl, dominated in the presence of hematite or magnetite, while use of troilite gave primarily the reduction products, e.g., 1, 3-diphenyl-propane and 1, 3-diphenyl-2-propanol. The roles of the three iron minerals in these transformations were further explored by (1) control experiments with various mineral surface areas, (2) measuring H2 in hydrothermal solutions, and (3) determining hydrogen balance among the organic products. These results suggest the reactions catalyzed by iron oxides (hematite and magnetite) are promoted mainly by the mineral surfaces, whereas the sulfide mineral (troilite) facilitated the reduction of ketone in the reaction solution. Therefore, this work not only provides a useful chemical approach to study and uncover complicated hydrothermal organic-mineral interactions, but also fosters a mechanistic understanding of ketone reactions in the deep carbon cycle.

Coastal submarine hydrothermal activity off northern Baja California

International Nuclear Information System (INIS)

Vidal, V.M.V.; Vidal, F.V.; Isaacs, J.D.; Young, D.R.

1978-01-01

In situ observations of submarine hydrothermal activity have been conducted in Punta Banda. Baja Califronia, Mexico, approximately 400 m from the coast and at a seawater depth of 30 m. The hydrothermal activity occurs within the Agua Blanca Fault, a major transverse structure of Northern Baja California. Hot springwater samples have been collected and analyzed. Marked differences exist between the submarine hot springwater, local land hot springwaters, groundwater, and local seawater. SiO 2 , HCO 3 , Ca, K, Li, B, Ba, Rb, Fe, Mn, As, and Zn are enriched in the submarine hot springwater, while Cl, Na, So 4 2 , Mg, Cu, Ni, Cd, Cr, and perhaps Pb are depleted in relation to average and local seawater values. Very high temperatures, at the hydrothermal vents, have been recorded (102 0 C at 4-atm pressure). Visible gaseous emanations rich in CH 4 and N 2 coexist with the hydrothermal solutions. Metalliferous deposits, pyrite, have been encountered with high concentrations of Fe, S, Si, Al, Mn, Ca, and the volatile elements As, Hg, Sb, and Tl, X ray dispersive spectrometry (1500-ppm detection limit). X ray diffraction, and scanning electron microscopy of the isolated metalliferous precipitates indicate that the principal products of precipitation are pyrite and gypsum accompanied by minor amounts of amorphous material containing Si and Al. Chemical analyses and XRD of the reference control rocks of the locality (volcanics) versus the hydrothermally altered rocks indicate that high-temperature and high-pressure water-rock interactions can in part explain the water chemistry characteristics of the submarine hydrothermal waters. Their long residence time, the occurrence of an extensive marine sedimentary formation, their association with CH 4 and their similarities with connate waters of oil and gas fields suggest that another component of their genesis could be in cation exchange reactions within deeply buried sediments of marine origin

Notas sobre la ecología de Phyllodactylus reissi (Phyllodactylidae: Sauria) en el Parque Nacional Cerros de Amotape (Tumbes, Perú)

OpenAIRE

Jordán Arizmendi, Juan Carlos

2012-01-01

Some basics aspects on the ecology of the nocturnal gecko Phyllodactylus reissi from Parque Nacional Cerros de Amotape (Tumbes, Peru) are described. This species used rock boulders (57,4%) and trees (31,9%) as microhabitats primarily, exhibiting a nocturnal activity pattern, with a peak between 2100-2200 hours, remaining active until midnight. Body temperature (mean 24,4 ºC) was correlated with both air and substrate temperature, with the last variable affecting in higher degree (47%) the bod...

Influence of hydrothermal processing on functional properties and grain morphology of finger millet.

Science.gov (United States)

Dharmaraj, Usha; Meera, M S; Reddy, S Yella; Malleshi, Nagappa G

2015-03-01

Finger millet was hydrothermally processed followed by decortication. Changes in color, diameter, density, sphericity, thermal and textural characteristics and also some of the functional properties of the millet along with the grain morphology of the kernels after hydrothermal processing and decortication were studied. It was observed that, the millet turned dark after hydrothermal processing and color improved over native millet after decortication. A slight decrease in grain diameter was observed but sphericity of the grains increased on decortication. The soft and fragile endosperm turned into a hard texture and grain hardness increased by about 6 fold. Hydrothermal processing increased solubility and swelling power of the millet at ambient temperature. Pasting profile indicated that, peak viscosity decreased significantly on hydrothermal processing and both hydrothermally processed and decorticated millet exhibited zero breakdown viscosity. Enthalpy was negative for hydrothermally processed millet and positive for decorticated grains. Microscopic studies revealed that the orderly structure of endosperm changed to a coherent mass after hydrothermal processing and the different layers of seed coat get fused with the endosperm.

Effect of hydrothermal process for inorganic alumina sol on crystal structure of alumina gel

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K. Yamamura

2016-09-01

Full Text Available This paper reports the effect of a hydrothermal process for alumina sol on the crystal structure of alumina gel derived from hydrothermally treated alumina sol to help push forward the development of low temperature synthesis of α-Al2O3. White precipitate of aluminum hydroxide was prepared with a homogeneous precipitation method using aluminum nitrate and urea in aqueous solution. The obtained aluminum hydroxide precipitate was peptized by using acetic acid at room temperature, which resulted in the production of a transparent alumina sol. The alumina sol was treated with a hydrothermal process and transformed into an alumina gel film by drying at room temperature. Crystallization of the alumina gel to α-Al2O3 with 900 °C annealing was dominant for a hydrothermal temperature of 100 °C and a hydrothermal time of 60 min, as production of diaspore-like species was promoted with the hydrothermal temperature and time. Excess treatments with hydrothermal processes at higher hydrothermal temperature for longer hydrothermal time prevented the alumina gel from being crystallized to α-Al2O3 because the excess hydrothermal treatments promoted production of boehmite.

Hydrothermal treatment of coprecipitated YSZ powders

International Nuclear Information System (INIS)

Arakaki, Alexander Rodrigo; Yoshito, Walter Kenji; Ussui, Valter; Lazar, Dolores Ribeiro Ricci

2009-01-01

Zirconia stabilized with 8.5 mol% yttria (YSZ) were synthesized by coprecipitation and resulting gels were hydrothermally treated at 200°C and 220 PSI for 4, 8 and 16 hours. Products were oven dried at 70°C for 24 hours, uniaxially pressed as pellets and sintered at 1500 °C for 1 hour. Powders were characterized for surface area with N 2 gas adsorption, X-ray diffraction, laser diffraction granulometric analysis and scanning and transmission electronic microscopy. Density of ceramics was measured by an immersion method based on the Archimedes principle. Results showed that powders dried at 70°C are amorphous and after treatment has tetragonal/cubic symmetry. Surface area of powders presented a significant reduction after hydrothermal treatment. Ceramics prepared from hydrothermally treated powders have higher green density but sintered pellets are less dense when compared to that made with powders calcined at 800°C for 1 hour due to the agglomerate state of powders. Solvothermal treatment is a promising procedure to enhance density. (author)

Radionuclides in hydrothermal systems as indicators of repository conditions

International Nuclear Information System (INIS)

Wollenberg, H.A.; Flexser, S.; Smith, A.R.

1990-11-01

Hydrothermal systems in tuffaceous and older sedimentary rocks contain evidence of the interaction of radionuclides in fluids with rock matrix minerals and with materials lining fractures, in settings somewhat analogous to the candidate repository site at Yucca Mountain, NV. Earlier studies encompassed the occurrences of U and Th in a ''fossil'' hydrothermal system in tuffaceous rock of the San Juan Mountains volcanic field, CO. More recent and ongoing studies examine active hydrothermal systems in calderas at Long Valley, CA and Valles, NM. At the Nevada Test Site, occurrences of U and Th in fractured and unfractured rhyolitic tuff that was heated to simulate the introduction of radioactive waste are also under investigation. Observations to date suggest that U is mobile in hydrothermal systems, but that localized reducing environments provided by Fe-rich minerals and/or carbonaceous material concentrate U and thus attenuate its migration. 11 refs., 6 figs., 1 tab

Geochemical constraints on chemolithoautotrophic reactions in hydrothermal systems

Science.gov (United States)

Shock, Everett L.; McCollom, Thomas; Schulte, Mitchell D.

1995-06-01

Thermodynamic calculations provide the means to quantify the chemical disequilibrium inherent in the mixing of redeuced hydrothermal fluids with seawater. The chemical energy available for metabolic processes in these environments can be evaluated by taking into account the pressure and temperature dependence of the apparent standard Gibbs free energies of reactions in the S-H2-H2O system together with geochemical constraints on pH, activities of aqueous sulfur species and fugacities of H2 and/or O2. Using present-day mixing of hydrothermal fluids and seawater as a starting point, it is shown that each mole of H2S entering seawater from hydrothermal fluids represents about 200,000 calories of chemical energy for metabolic systems able to catalyze H2S oxidation. Extrapolating to the early Earth, which was likely to have had an atmosphere more reduced than at present, shows that this chemical energy may have been a factor of two or so less. Nevertheless, mixing of hydrothermal fluids with seawater would have been an abundant source of chemical energy, and an inevitable consequence of the presence of an ocean on an initially hot Earth. The amount of energy available was more than enough for organic synthesis from CO2 or CO, and/or polymer formation, indicating that the vicinity of hydrothermal systems at the sea floor was an ideal location for the emergence of the first chemolithoautotrophic metabolic systems.

Burn Severities, Fire Intensities, and Impacts to Major Vegetation Types from the Cerro Grande Fire

Energy Technology Data Exchange (ETDEWEB)

Balice, Randy G. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bennett, Kathryn D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Wright, Marjorie A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2004-12-15

The Cerro Grande Fire resulted in major impacts and changes to the ecosystems that were burned. To partially document these effects, we estimated the acreage of major vegetation types that were burned at selected burn severity levels and fire intensity levels. To accomplish this, we adopted independently developed burn severity and fire intensity maps, in combination with a land cover map developed for habitat management purposes, as a basis for the analysis. To provide a measure of confidence in the acreage estimates, the accuracies of these maps were also assessed. In addition, two other maps of comparable quality were assessed for accuracy: one that was developed for mapping fuel risk and a second map that resulted from a preliminary application of an evolutionary computation software system, called GENIE.

Direct catalytic hydrothermal liquefaction of spirulina to biofuels with hydrogen

Science.gov (United States)

Zeng, Qin; Liao, Hansheng; Zhou, Shiqin; Li, Qiuping; Wang, Lu; Yu, Zhihao; Jing, Li

2018-01-01

We report herein on acquiring biofuels from direct catalytic hydrothermal liquefaction of spirulina. The component of bio-oil from direct catalytic hydrothermal liquefaction was similar to that from two independent processes (including liquefaction and upgrading of biocrude). However, one step process has higher carbon recovery, due to the less loss of carbons. It was demonstrated that the yield and HHV of bio-oil from direct catalytic algae with hydrothermal condition is higher than that from two independent processes.

Genetic diversity of archaea in deep-sea hydrothermal vent environments.

Science.gov (United States)

Takai, K; Horikoshi, K

1999-08-01

Molecular phylogenetic analysis of naturally occurring archaeal communities in deep-sea hydrothermal vent environments was carried out by PCR-mediated small subunit rRNA gene (SSU rDNA) sequencing. As determined through partial sequencing of rDNA clones amplified with archaea-specific primers, the archaeal populations in deep-sea hydrothermal vent environments showed a great genetic diversity, and most members of these populations appeared to be uncultivated and unidentified organisms. In the phylogenetic analysis, a number of rDNA sequences obtained from deep-sea hydrothermal vents were placed in deep lineages of the crenarchaeotic phylum prior to the divergence of cultivated thermophilic members of the crenarchaeota or between thermophilic members of the euryarchaeota and members of the methanogen-halophile clade. Whole cell in situ hybridization analysis suggested that some microorganisms of novel phylotypes predicted by molecular phylogenetic analysis were likely present in deep-sea hydrothermal vent environments. These findings expand our view of the genetic diversity of archaea in deep-sea hydrothermal vent environments and of the phylogenetic organization of archaea.

Fractionation of boron isotopes in Icelandic hydrothermal systems

International Nuclear Information System (INIS)

Aggarwal, J.K.

1995-01-01

Boron isotope ratios have been determined in a variety of different geothermal waters from hydrothermal systems across Iceland. Isotope ratios from the high temperature meteoric water recharged systems reflect the isotope ratio of the host rocks without any apparent fractionation. Seawater recharged geothermal systems exhibit more positive δ 1 1B values than the meteoric water recharged geothermal systems. Water/rock ratios can be assessed from boron isotope ratios in the saline hydrothermal systems. Low temperature hydrothermal systems also exhibit more positive δ 1 1B than the high temperature systems, indicating fractionation of boron due to absorption of the lighter isotope onto secondary minerals. Fractionation of boron in carbonate deposits may indicate the level of equilibrium attained within the systems. (author). 14 refs., 2 figs

Versatile hydrothermal synthesis of one-dimensional composite structures

Science.gov (United States)

Luo, Yonglan

2008-12-01

In this paper we report on a versatile hydrothermal approach developed to fabricate one-dimensional (1D) composite structures. Sulfur and selenium formed liquid and adsorbed onto microrods as droplets and subsequently reacted with metallic ion in solution to produce nanoparticles-decorated composite microrods. 1D composites including ZnO/CdS, ZnO/MnS, ZnO/CuS, ZnO/CdSe, and FeOOH/CdS were successfully made using this hydrothermal strategy and the growth mechanism was also discussed. This hydrothermal strategy is simple and green, and can be extended to the synthesis of various 1D composite structures. Moreover, the interaction between the shell nanoparticles and the one-dimensional nanomaterials were confirmed by photoluminescence investigation of ZnO/CdS.

Calidad de adn de personas impactadas por la minería artesanal en el cerro el toro, huamachuco, la libertad 2010

OpenAIRE

Casanova Herrera, Hugo Enrique

2013-01-01

The present research work is to determine the toxic substances and DNA damage for people impacted by artisanal mining of Cerro El Toro, using the comet assay. Knowing that at present the impact of mining is a problem that affects the global environment and to Peru by the. gold mining in people causing health problems that could reach various cancer diseases, caused by a genotoxic effect of the chemicals used in mining affecting chromosomal DNA. Atomic absorption spectroscopy was used as a met...

Dimensión sociopolítica y religiosa de la Capacocha del Cerro Aconcagua

Directory of Open Access Journals (Sweden)

1996-01-01

Full Text Available DIMENTION SOCIO-POLITIQUE ET RELIGIEUSE DE LA CAPACOCHA DE L'ACONCAGUA. Sur un contrefort de l’Aconcagua un groupe d’andinistes a trouvé une sépulture ayant les caractéristiques d’une capacocha. Dans cet essai nous étudierons et commenterons quelques éléments qui la composent, spécialement des petites figures en métal et mullu avec leurs tenues, en prenant comme référence les informations coloniales et les données de l’archéologie. Parmi les sujets traités nous trouverons : la présence de Huayna Capac au Chili, l’alliance entre Chinchaysuyu et Collasuyu sous la domination inca, les chemins rituels, l’oracle et le maintien du souvenir de l’ancien dieu Con. En un contrafuerte del cerro Aconcagua, un grupo de andinistas encontró un entierro que reúne las condiciones que lo definen como una capacocha. En este ensayo se estudian y comentan algunos de los elementos que la componen -especialmente las figuritas de metal y mullu con sus atuendos- tomando como referencia las noticias coloniales y los datos arqueológicos. Entre los temas tratados tenemos: la presencia de Huayna Capac en Chile la alianza entre Chinchaysuyu y Collasuyu bajo el dominio incaico los caminos rituales el oráculo y la supervivencia del recuerdo del antiguo dios Con. SOCIAL, POLITICAL AND RELIGIOUS DIMENSION OF THE CAPACOCHA OF THE CERRO ACONCAGUA. In a secondary mountain range of the Aconcagua Mt., a group of mountain-climbers found an interment possessing the attributes of a capacocha. In this essay some of the elements composing it namely the small metal and mullu figures with their garments, drawing on colonial documents and archaeological data, are studied and commented upon. Among the subjects considered the following: the presence of Huayna Capac in Chile, the coalition between Chinchaysuyu and Collasuyu under the Inca empire, the ritual roads, the oracle and the survival of the memories of the ancient god Con.

Hydrogen is an energy source for hydrothermal vent symbioses.

Science.gov (United States)

Petersen, Jillian M; Zielinski, Frank U; Pape, Thomas; Seifert, Richard; Moraru, Cristina; Amann, Rudolf; Hourdez, Stephane; Girguis, Peter R; Wankel, Scott D; Barbe, Valerie; Pelletier, Eric; Fink, Dennis; Borowski, Christian; Bach, Wolfgang; Dubilier, Nicole

2011-08-10

The discovery of deep-sea hydrothermal vents in 1977 revolutionized our understanding of the energy sources that fuel primary productivity on Earth. Hydrothermal vent ecosystems are dominated by animals that live in symbiosis with chemosynthetic bacteria. So far, only two energy sources have been shown to power chemosynthetic symbioses: reduced sulphur compounds and methane. Using metagenome sequencing, single-gene fluorescence in situ hybridization, immunohistochemistry, shipboard incubations and in situ mass spectrometry, we show here that the symbionts of the hydrothermal vent mussel Bathymodiolus from the Mid-Atlantic Ridge use hydrogen to power primary production. In addition, we show that the symbionts of Bathymodiolus mussels from Pacific vents have hupL, the key gene for hydrogen oxidation. Furthermore, the symbionts of other vent animals such as the tubeworm Riftia pachyptila and the shrimp Rimicaris exoculata also have hupL. We propose that the ability to use hydrogen as an energy source is widespread in hydrothermal vent symbioses, particularly at sites where hydrogen is abundant.

Burning down the brewery: Establishing and evacuating an ancient imperial colony at Cerro Baúl, Peru

Science.gov (United States)

Moseley, Michael E.; Nash, Donna J.; Williams, Patrick Ryan; deFrance, Susan D.; Miranda, Ana; Ruales, Mario

2005-01-01

Before the Inca reigned, two empires held sway over the central Andes from anno Domini 600 to 1000: the Wari empire to the north ruled much of Peru, and Tiwanaku to the south reigned in Bolivia. Face-to-face contact came when both colonized the Moquegua Valley sierra in southern Peru. The state-sponsored Wari incursion, described here, entailed large-scale agrarian reclamation to sustain the occupation of two hills and the adjacent high mesa of Cerro Baúl. Monumental buildings were erected atop the mesa to serve an embassy-like delegation of nobles and attendant personnel that endured for centuries. Final evacuation of the Baúl enclave was accompanied by elaborate ceremonies with brewing, drinking, feasting, vessel smashing, and building burning. PMID:16293691

Hydrothermal conversion of biomass

NARCIS (Netherlands)

Knezevic, D.

2009-01-01

This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of

Hydrothermal decomposition of liquid crystal in subcritical water

International Nuclear Information System (INIS)

Zhuang, Xuning; He, Wenzhi; Li, Guangming; Huang, Juwen; Lu, Shangming; Hou, Lianjiao

2014-01-01

Highlights: • Hydrothermal technology can effectively decompose the liquid crystal of 4-octoxy-4'-cyanobiphenyl. • The decomposition rate reached 97.6% under the optimized condition. • Octoxy-4'-cyanobiphenyl was mainly decomposed into simple and innocuous products. • The mechanism analysis reveals the decomposition reaction process. - Abstract: Treatment of liquid crystal has important significance for the environment protection and human health. This study proposed a hydrothermal process to decompose the liquid crystal of 4-octoxy-4′-cyanobiphenyl. Experiments were conducted with a 5.7 mL stainless tube reactor and heated by a salt-bath. Factors affecting the decomposition rate of 4-octoxy-4′-cyanobiphenyl were evaluated with HPLC. The decomposed liquid products were characterized by GC-MS. Under optimized conditions i.e., 0.2 mL H 2 O 2 supply, pH value 6, temperature 275 °C and reaction time 5 min, 97.6% of 4-octoxy-4′-cyanobiphenyl was decomposed into simple and environment-friendly products. Based on the mechanism analysis and products characterization, a possible hydrothermal decomposition pathway was proposed. The results indicate that hydrothermal technology is a promising choice for liquid crystal treatment

Hydrothermal stability of microporous silica and niobia-silica membranes

NARCIS (Netherlands)

Boffa, V.; Blank, David H.A.; ten Elshof, Johan E.

2008-01-01

The hydrothermal stability of microporous niobia–silica membranes was investigated and compared with silica membranes. The membranes were exposed to hydrothermal conditions at 150 and 200 °C for 70 h. The change of pore structure before and after exposure to steam was probed by single-gas permeation

INVENTARIO FLORÍSTICO EN EL CERRO DEL CUCHILLO, TAPÓN DEL DARIÉN COLOMBIANO

Directory of Open Access Journals (Sweden)

CÁRDENAS-LÓPEZ DAIRON

2003-06-01

Full Text Available Se presentan los resultados del inventario florístico realizado entre agosto de 1987y julio de 1988, en el Cerro del Cuchillo, municipio de Riosucio (Chocó, Tapón delDarién colombiano. Se efectuaron diez salidas de campo con duración de quincedías cada una . Se registraron 127 familias, 428 géneros y 747 especies. Las divisionesmejor representadas fueron Magnoliophyta con 112 familias, 402 géneros y 705especies; Pteridophyta con trece familias, 23 géneros y 40 especies. Cycadophytaestuvo representada por la familia Zamiaceae con una especie y Gnetophyta por lafamilia Gnetaceae con una especie. Entre las plantas con flores (Magnoliophyta, elgrupo mejor representado fue la clase Magnoliopsida con 94 familias, 324 génerosy 573 especies. La clase Liliopsida estuvo representada por 18 familias, 78 génerosy 132 especies.

Geologic evolution of the Lost City Hydrothermal Field

Science.gov (United States)

Denny, Alden R.; Kelley, Deborah S.; Früh-Green, Gretchen L.

2016-02-01

The Lost City Hydrothermal Field (LCHF) is a novel serpentinite-hosted vent field located on the Atlantis Massif southern wall. Results of 2 m resolution bathymetry, side scan, and video and still imagery, integrated with direct submersible observations provide the first high-resolution geologic map of the LCHF. These data form the foundation for an evolutionary model for the vent system over the past >120,000 years. The field is located on a down-dropped bench 70 m below the summit of the massif. The bench is capped by breccia and pelagic carbonate deposits underlain by variably deformed and altered serpentinite and gabbroic rocks. Hydrothermal activity is focused at the 60 m tall, 100 m across, massive carbonate edifice "Poseidon," which is venting 91°C fluid. Hydrothermal activity declines south and west of the Poseidon complex and dies off completely at distances greater than 200 m. East of Poseidon, the most recent stage of hydrothermal flow is characterized by egress of diffuse fluids from narrow fissures within a low-angle, anastomosing mylonite zone. South of the area of current hydrothermal activity, there is evidence of two discrete previously unrecognized relict fields. Active venting sites defined by carbonate-filled fissures that cut the carbonate cap rock at the summit of the massif mark the present-day northernmost extent of venting. These spatial relationships reflect multiple stages of field development, the northward migration of venting over time, and the likely development of a nascent field at the massif summit.

Reporte de un opilión cavernícola de la familia Gonyleptidae encontrado en el cerro de Quininí, Tibacuy, Cundinamarca

Directory of Open Access Journals (Sweden)

Alejandro Parra

2000-07-01

Full Text Available En la observación bioespelológica en una gruta ubicada en el cerro de Quinini, inspección de policía de Cumaca, Cundinamarca, se encontró una población de Opiliones de la Familia Gonyleptidae ,familia por primera vez reportada para Colombia. Se observó en los opiliones conductas de apareamiento y se realizó un estudio morfológico para una determinación taxonómica profunda.

Reporte de un opilión cavernícola de la familia Gonyleptidae encontrado en el cerro de Quininí, Tibacuy, Cundinamarca

OpenAIRE

Alejandro Parra; Oscar Vivas; Francisco Hormanza

2000-01-01

En la observación bioespelológica en una gruta ubicada en el cerro de Quinini, inspección de policía de Cumaca, Cundinamarca, se encontró una población de Opiliones de la Familia Gonyleptidae ,familia por primera vez reportada para Colombia. Se observó en los opiliones conductas de apareamiento y se realizó un estudio morfológico para una determinación taxonómica profunda.

Distal transport of dissolved hydrothermal iron in the deep South Pacific Ocean.

Science.gov (United States)

Fitzsimmons, Jessica N; Boyle, Edward A; Jenkins, William J

2014-11-25

Until recently, hydrothermal vents were not considered to be an important source to the marine dissolved Fe (dFe) inventory because hydrothermal Fe was believed to precipitate quantitatively near the vent site. Based on recent abyssal dFe enrichments near hydrothermal vents, however, the leaky vent hypothesis [Toner BM, et al. (2012) Oceanography 25(1):209-212] argues that some hydrothermal Fe persists in the dissolved phase and contributes a significant flux of dFe to the global ocean. We show here the first, to our knowledge, dFe (Pacific Ocean, where dFe of 1.0-1.5 nmol/kg near 2,000 m depth (0.4-0.9 nmol/kg above typical deep-sea dFe concentrations) was determined to be hydrothermally derived based on its correlation with primordial (3)He and dissolved Mn (dFe:(3)He of 0.9-2.7 × 10(6)). Given the known sites of hydrothermal venting in these regions, this dFe must have been transported thousands of kilometers away from its vent site to reach our sampling stations. Additionally, changes in the size partitioning of the hydrothermal dFe between soluble (Pacific Rise only leaks 0.02-1% of total Fe vented into the abyssal Pacific, this dFe persists thousands of kilometers away from the vent source with sufficient magnitude that hydrothermal vents can have far-field effects on global dFe distributions and inventories (≥3% of global aerosol dFe input).

Hydrothermal systems on Mars: an assessment of present evidence

Science.gov (United States)

Farmer, J. D.

1996-01-01

Hydrothermal processes have been suggested to explain a number of observations for Mars, including D/H ratios of water extracted from Martian meteorites, as a means for removing CO2 from the Martian atmosphere and sequestering it in the crust as carbonates, and as a possible origin for iron oxide-rich spectral units on the floors of some rifted basins (chasmata). There are numerous examples of Martian channels formed by discharges of subsurface water near potential magmatic heat sources, and hydrothermal processes have also been proposed as a mechanism for aquifer recharge needed to sustain long term erosion of sapping channels. The following geological settings have been identified as targets for ancient hydrothermal systems on Mars: channels located along the margins of impact crater melt sheets and on the slopes of ancient volcanoes; chaotic and fretted terranes where shallow subsurface heat sources are thought to have interacted with ground ice; and the floors of calderas and rifted basins (e.g. chasmata). On Earth, such geological environments are often a locus for hydrothermal mineralization. But we presently lack the mineralogical information needed for a definitive evaluation of hypotheses. A preferred tool for identifying minerals by remote sensing methods on Earth is high spatial resolution, hyperspectral, near-infrared spectroscopy, a technique that has been extensively developed by mineral explorationists. Future efforts to explore Mars for ancient hydrothermal systems would benefit from the application of methods developed by the mining industry to look for similar deposits on Earth. But Earth-based exploration models must be adapted to account for the large differences in the climatic and geological history of Mars. For example, it is likely that the early surface environment of Mars was cool, perhaps consistently below freezing, with the shallow portions of hydrothermal systems being dominated by magma-cryosphere interactions. Given the smaller

Additive effects of acetic acid upon hydrothermal reaction of amylopectin

International Nuclear Information System (INIS)

Sugano, Motoyuki; Katoh, Harumi; Komatsu, Akihiro; Kobayashi, Hiroshi; Okado, Kohta; Kakuta, Yusuke; Hirano, Katsumi

2012-01-01

It is well known that over 0.8 kg kg −1 of starch is consisted of amylopectin (AP). In this study, production of glucose for raw material of ethanol by hydrothermal reaction of AP as one of the model compound of food is discussed. Further, additive effects of acetic acid upon hydrothermal reactions of AP are also investigated. During hydrothermal reaction of AP, production of glucose occurred above 453 K, and the glucose yield increased to 0.48 kg kg −1 at 473 K. Upon hydrothermal reaction of AP at 473 K, prolongation of the holding time was not effective for the increase of the glucose yield. Upon hydrothermal reaction of AP at 473 K for 0 s, the glucose yield increased significantly by addition between 0.26 mol L −1 and 0.52 mol L −1 of acetic acid. However, the glucose yield decreased and the yield of the other constituents increased with the increases of concentration of acetic acid from 0.65 mol L −1 to 3.33 mol L −1 . It was considered that hydrolysis of AP to yield glucose was enhanced due to the increase of the amount of proton derived from acetic acid during hydrothermal reaction with 0.52 mol L −1 of acetic acid. -- Highlights: ► Glucose production by hydrothermal reaction of amylopectin (AP) at 473 K. ► Glucose yield increased to 0.48 kg kg -1 at 473 K. ► Prolongation of holding time was not effective for glucose yield. ► Glucose yield increased significantly by acetic acid (0.26–0.52 mol L-1) addition. ► Hydrolysis of AP to glucose was enhanced due to increase of proton from acetic acid.

Hydrothermal processing of transuranic contaminated combustible waste

International Nuclear Information System (INIS)

Buelow, S.J.; Worl, L.; Harradine, D.; Padilla, D.; McInroy, R.

2001-01-01

Experiments at Los Alamos National Laboratory have demonstrated the usefulness of hydrothermal processing for the disposal of a wide variety of transuranic contaminated combustible wastes. This paper provides an overview of the implementation and performance of hydrothermal treatment for concentrated salt solutions, explosives, propellants, organic solvents, halogenated solvents, and laboratory trash, such as paper and plastics. Reaction conditions vary from near ambient temperatures and pressure to over 1000degC and 100 MPa pressure. Studies involving both radioactive and non-radioactive waste simulants are discussed. (author)

Simulating Electrochemistry of Hydrothermal Vents on Enceladus and Other Ocean Worlds

Science.gov (United States)

Barge, L. M.; Krause, F. C.; Jones, J. P.; Billings, K.; Sobron, P.

2017-12-01

Gradients generated in hydrothermal systems provide a significant source of free energy for chemosynthetic life, and may play a role in present-day habitability on ocean worlds such as Enceladus that are thought to host hydrothermal activity. Hydrothermal vents are similar in some ways to typical fuel cell devices: redox/pH gradients between seawater and hydrothermal fluid are analogous to the oxidant and fuel reservoirs; conductive natural mineral deposits are analogous to electrodes; and, in hydrothermal chimneys, the porous chimney wall can function as a separator or ion-exchange membrane. Electrochemistry, founded on quantitative study of redox and other chemical disequilibria as well as the chemistry of interfaces, is uniquely suited to studying these systems. We have performed electrochemical studies to better understand the catalytic potential of seafloor minerals and vent chimneys, using samples from a black smoker vent chimney as an initial demonstration. Fuel cell experiments with electrodes made from black smoker chimney material accurately simulated the redox reactions that occur in a geological setting with this particular catalyst. Similar methods with other geo-catalysts (natural or synthetic) could be utilized to test which redox reactions or metabolisms could be driven in other hydrothermal systems, including putative vent systems on other worlds.

A new species of Cryptonympha Lugo-Ortiz McCafferty (Ephemeroptera, Baetidae) from Cerro Duida (Venezuela).

Science.gov (United States)

Derka, TomÁŠ; Nieto, Carolina

2018-02-05

The genus Cryptonympha includes three species: C. copiosa Lugo-Ortiz McCafferty, 1998; C. dasilvai Salles Francischetti, 2004 and C. genevievae Thomas, Manchon Glémet, 2013, known only from the nymphal stage. A description of the nymph of a fourth representative, Cryptonympha tracheata sp. n. is provided here, based on material collected in a blackwater stream on the slopes of the Cerro Duida mountain in south-western Venezuela. The nymph of the new species can be easily distinguished from the other species of the genus by very long tracheal gills II-VII, 2.5 times the length of each tergum, gill I small, nearly half length of gill IV and by posterior margin of terga with rounded spines. A complete description of the new species and a key for nymphs of all known Cryptonympha species are provided.

Elemental geochemical records of seafloor hydrothermal activities in the sediments from the Okinawa Trough

Institute of Scientific and Technical Information of China (English)

ZHAI Shikui; YU Zenghui; DU Tongjun

2007-01-01

The major and minor element contents in the sediment core H9 from the hydrothermal fields of the Okinawa Trough show a sharp change at the depth of 80 cm. The elements enriched in the upper 80 cm core are those enriched in the hydrothermal deposits and in the surface sediments recovered from the hydrothermal fields in the trough, which indicates the input of hydrothermal materials. Comparing with other hydrothermal sediments from Mid-ocean Ridges or the Lau Basin, the degree of the enrichment of elements iron, copper, cobalt, and nickel is relatively low. However, the enrichment of elements manganese, lead, arsenic, antimony and mercury is remarkable. The average contents of these elements in the upper 80 cm core sediments are three to six times those in the lower section, and 3 ~ 12 times those in the surface sediments which are not influenced by hydrothermal activities. Hydrothermal activities have contributed significant manganese, lead, arsenic, antimony and mercury to the sediments, and these elements are distinct indicators for the hydrothermal activity in the Okinawa Trough. The significant enrichment of these elements in Core H9 upward from the depth 80 cm indicates the start or the significant enhancing of the hydrothermal activity in this area at about 5 740 aB. P. The average accumulation rate of manganese during this period is about 40 461 μg/( cm2 · ka), which is similar to the hydrothermal sediments in the Lau Basin or the East Pacific Rise.

Comparative study on microwave and conventional hydrothermal pretreatment of bamboo sawdust: Hydrochar properties and its pyrolysis behaviors

International Nuclear Information System (INIS)

Dai, Leilei; He, Chao; Wang, Yunpu; Liu, Yuhuan; Yu, Zhenting; Zhou, Yue; Fan, Liangliang; Duan, Dengle

2017-01-01

Highlights: • Two pretreatments affect differently the hydrochar properties and its pyrolysis behaviors. • Hydrochar by conventional hydrothermal pretreatment shows higher thermal stability. • Microwave hydrothermal pretreatment removes more acetyl. • Hydrochar by microwave hydrothermal pretreatment produces more glucopyranose and less acids. - Abstract: Comparative study on microwave and conventional hydrothermal pretreatment of bamboo sawdust was carried out in this study. Microwave and conventional hydrothermal pretreatment both improved the hydrochar properties and its pyrolysis behaviors. Proximate and elemental analyses show that the properties of hydrochar from microwave hydrothermal pretreatment are better than conventional hydrothermal pretreatment in terms of calorific value and oxygen content except for 150 °C. Microwave hydrothermal pretreatment removes more acetyl groups in hemicellulose compared to conventional hydrothermal pretreatment, which may be attributed to the hot spot effect of microwave irradiation. The peaks of thermogravimetric and derivative thermogravimetric curves of pretreated samples always shifted to higher temperature region. Also, the conventional hydrothermal pretreated samples are more thermally stable than those by microwave heating. In addition, the glucopyranose content in pyrolysis vapors of microwave hydrothermal pretreated bamboo sawdust (190 °C) was 9.82% higher than that from conventional hydrothermal pretreated bamboo sawdust. However, the acids content from microwave hydrothermal pretreated bamboo sawdust (150 °C) was 4.12% lower. In this regard, microwave hydrothermal pretreatment is more suitable for upgrading the pyrolysis oil quality than conventional hydrothermal pretreatment.

Hydrothermal Synthesis of Analcime from Kutingkeng Formation Mudstone

Science.gov (United States)

Hsiao, Yin-Hsiu; Chen, Kuan-Ting; Ray, Dah-Tong

2015-04-01

In southwest of Taiwan, the foothill located in Tainan-Kaohsiung city is the exposed area of Pliocene strata to early Pleistocene strata. The strata are about a depth of five thousand, named as Kutigkeng Formation. The outcrop of Kutigkeng Formation is typical badlands, specifically called 'Moon World.' It is commonly known as no important economic applications of agricultural land. The mineral compositions of Kutingkeng Formation are quartz, clay minerals and feldspar. The clay minerals consist of illite, clinochlore and swelling clays. To study how the phase and morphology of analcime formed by hydrothermal synthesis were affected, analcime was synthesized from the mudstone of Kutinkeng Formation with microwave hydrothermal reaction was investigated. The parameters of the experiment were the reaction temperature, the concentration of mineralizer, solids/liquid ratio and time. The sodium silicate (Na2SiO3) were used as mineralizer. The results showed that the analcime could be synthesized by hydrothermal reaction above 180° from Kutinkeng Formation mudstone samples. At the highest temperature (240°) of this study, the high purity analcime could be produced. When the concentration of Na2SiO3=3~6M, analcime could be synthesized at 240°. The best solids/liquid ratio was approximate 1 to 5. The hydrothermal reaction almost was completed after 4 hours.

Effects of hydrothermal post-treatment on microstructures and morphology of titanate nanoribbons

International Nuclear Information System (INIS)

Yu Huogen; Yu Jiaguo; Cheng Bei; Zhou Minghua

2006-01-01

Titanate nanoribbons were prepared via a hydrothermal treatment of rutile-type TiO 2 powders in a 10 M NaOH solution at 200 deg. C for 48 h. The as-prepared titanate nanoribbons were then hydrothermally post-treated at 150 deg. C for 12-36 h. The titanate nanoribbons before and after hydrothermal post-treatment were characterized with FESEM, XRD, TEM, UV-VIS and nitrogen adsorption-desorption isotherms. The results showed that the hydrothermal post-treatment not only promoted the phase transformation from titanate to anatase TiO 2 , but also was beneficial to the removal of Na + ions remained in the titanate nanoribbons. After hydrothermal post-treatment, the TiO 2 samples retained the one-dimensional structure feature of the titanate nanoribbons and showed an obvious increase in the specific surface area and the pore volume

Hydrothermal Processes in the Archean - New Insights from Imaging Spectroscopy

NARCIS (Netherlands)

Ruitenbeek, F.J.A. van

2007-01-01

The aim of this research was to gain new insights in fossil hydrothermal systems using airborne imaging spectroscopy. Fossil submarine hydrothermal systems in Archean greenstone belts and other geologic terranes are important because of their relationship with volcanic massive sulfide (VMS) mineral

Vein networks in hydrothermal systems provide constraints for the monitoring of active volcanoes.

Science.gov (United States)

Cucci, Luigi; Di Luccio, Francesca; Esposito, Alessandra; Ventura, Guido

2017-03-10

Vein networks affect the hydrothermal systems of many volcanoes, and variations in their arrangement may precede hydrothermal and volcanic eruptions. However, the long-term evolution of vein networks is often unknown because data are lacking. We analyze two gypsum-filled vein networks affecting the hydrothermal field of the active Lipari volcanic Island (Italy) to reconstruct the dynamics of the hydrothermal processes. The older network (E1) consists of sub-vertical, N-S striking veins; the younger network (E2) consists of veins without a preferred strike and dip. E2 veins have larger aperture/length, fracture density, dilatancy, and finite extension than E1. The fluid overpressure of E2 is larger than that of E1 veins, whereas the hydraulic conductance is lower. The larger number of fracture intersections in E2 slows down the fluid movement, and favors fluid interference effects and pressurization. Depths of the E1 and E2 hydrothermal sources are 0.8 km and 4.6 km, respectively. The decrease in the fluid flux, depth of the hydrothermal source, and the pressurization increase in E2 are likely associated to a magma reservoir. The decrease of fluid discharge in hydrothermal fields may reflect pressurization at depth potentially preceding hydrothermal explosions. This has significant implications for the long-term monitoring strategy of volcanoes.

Chemistry of a serpentinization-controlled hydrothermal system at the Lost City hydrothermal vent field

Science.gov (United States)

Ludwig, K. A.; Kelley, D. S.; Butterfield, D. A.; Nelson, B. K.; Karson, J. A.

2003-12-01

The Lost City Hydrothermal Field (LCHF), at 30° N near the Mid-Atlantic Ridge, is an off-axis, low temperature, high-pH, ultramafic-hosted vent system. Within the field, carbonate chimneys tower up to 60 m above the seafloor, making them the tallest vent structures known. The chemistry of the vent structures and fluids at the LCHF is controlled by reactions between seawater and ultramafic rocks beneath the Atlantis massif. Mixing of warm alkaline vent fluids with seawater causes precipitation of calcium carbonate and growth of the edifaces, which range from tall, graceful pinnacles to fragile flanges and colloform deposits. Geochemical and petrological analyses of the carbonate rocks reveal distinct differences between the active and extinct structures. Actively venting chimneys and flanges are extremely porous, friable formations composed predominantly of aragonite and brucite. These structures provide important niches for well-developed microbial communities that thrive on and within the chimney walls. Some of the active chimneys may also contain the mineral ikaite, an unstable, hydrated form of calcium carbonate. TIMS and ICP-MS analyses of the carbonate chimneys show that the most active chimneys have low Sr isotope values and that they are low in trace metals (e.g., Mn, Ti, Pb). Active structures emit high-pH, low-Mg fluids at 40-90° C. The fluids also have low Sr values, indicating circulation of hydrothermal solutions through the serpentinite bedrock beneath the field. In contrast to the active structures, extinct chimneys are less porous, are well lithified, and they are composed predominantly of calcite that yields Sr isotopes near seawater values. Prolonged lower temperature seawater-hydrothermal fluid interaction within the chimneys results in the conversion of aragonite to calcite and in the enrichment of some trace metals (e.g., Mn, Ti, Co, Zn). It also promotes the incorporation of foraminifera within the outer, cemented walls of the carbonate

Spatial Distribution of Viruses Associated with Planktonic and Attached Microbial Communities in Hydrothermal Environments

Science.gov (United States)

Nunoura, Takuro; Kazama, Hiromi; Noguchi, Takuroh; Inoue, Kazuhiro; Akashi, Hironori; Yamanaka, Toshiro; Toki, Tomohiro; Yamamoto, Masahiro; Furushima, Yasuo; Ueno, Yuichiro; Yamamoto, Hiroyuki; Takai, Ken

2012-01-01

Viruses play important roles in marine surface ecosystems, but little is known about viral ecology and virus-mediated processes in deep-sea hydrothermal microbial communities. In this study, we examined virus-like particle (VLP) abundances in planktonic and attached microbial communities, which occur in physical and chemical gradients in both deep and shallow submarine hydrothermal environments (mixing waters between hydrothermal fluids and ambient seawater and dense microbial communities attached to chimney surface areas or macrofaunal bodies and colonies). We found that viruses were widely distributed in a variety of hydrothermal microbial habitats, with the exception of the interior parts of hydrothermal chimney structures. The VLP abundance and VLP-to-prokaryote ratio (VPR) in the planktonic habitats increased as the ratio of hydrothermal fluid to mixing water increased. On the other hand, the VLP abundance in attached microbial communities was significantly and positively correlated with the whole prokaryotic abundance; however, the VPRs were always much lower than those for the surrounding hydrothermal waters. This is the first report to show VLP abundance in the attached microbial communities of submarine hydrothermal environments, which presented VPR values significantly lower than those in planktonic microbial communities reported before. These results suggested that viral lifestyles (e.g., lysogenic prevalence) and virus interactions with prokaryotes are significantly different among the planktonic and attached microbial communities that are developing in the submarine hydrothermal environments. PMID:22210205

Duration of hydrothermal treatment and peeling of 'Murcott' tangor

Directory of Open Access Journals (Sweden)

Ana Luiza Pinheiro

2011-12-01

Full Text Available Hydrothermal treatment facilitates the peeling of 'Pera' sweet orange fruit and does not alter its quality. The aim of this work was to adapt the technology of peeling for the use of hydrothermal treatment in 'Murcott' tangor and to evaluate its influence in the CO2 production and the physicochemical, microbiologic and sensorial characteristics of fruits. The peeling time, the yield of marketable fruits and the internal temperature of fruits during the treatment were also evaluated. The hydrothermal treatment consisted of placing the fruits in a water-bath at 50 ºC for 5, 10, 15, 20, 25 and 30 min. Fruits were peeled by first opening a gap in the peduncle region with a knife and then manually removing the flavedo and albedo. Fruits were stored at 5 ºC for six days. Hydrothermal treatment caused changes in the fruits' CO2 production for only the first few hours after processing. Internal fruit temperature after 30 min of treatment reached 35 ºC. There were no changes in the physicochemical and microbiologic characteristics of the fruits. The treatment did not change the flavor, improved the fruits' appearance, decreased the peeling time of the treated fruits by 57 % and increased the yield of marketable fruits. In conclusion, the hydrothermal treatment accomplished from 5 to 30 min at 50 ºC can be used as part of the peeling process for 'Murcott' tangor.

Kinetics of the hydrothermal treatment of tannin for producing carbonaceous microspheres.

Science.gov (United States)

Braghiroli, F L; Fierro, V; Izquierdo, M T; Parmentier, J; Pizzi, A; Celzard, A

2014-01-01

Aqueous solutions of condensed tannins were submitted to hydrothermal carbonization (HTC) in a stainless steel autoclave, and the kinetics of hydrothermal carbon formation was investigated by changing several parameters: amount of tannin (0.5; 1.0; 1.5; 2.0 g in 16 mL of water), HTC temperature (130, 160, 180 and 200°C) and reaction times (from 1 to 720 h). The morphology and the structure of the tannin-based hydrothermal carbons were studied by TEM, krypton adsorption at -196°C and helium pycnometry. These materials presented agglomerated spherical particles, having surface areas ranging from 0.6 to 10.0 m(2) g(-1). The chemical composition of the hydrothermal carbons was found to be constant and independent of reaction time. HTC kinetics of tannin were determined and shown to correspond to first-order reaction. Temperature-dependent measurements led to an activation energy of 91 kJ mol(-1) for hydrothermal conversion of tannin into carbonaceous microspheres separable by centrifugation. Copyright © 2013 Elsevier Ltd. All rights reserved.

Levulinic acid from orange peel waste by hydrothermal carbonization (HTC)

NARCIS (Netherlands)

Puccini, Monica; Licursi, Domenico; Stefanelli, Eleonora; Vitolo, Sandra; Galletti, Anna Maria Raspolli; Heeres, Hero Jan

2016-01-01

With the awareness of the need for optimal and sustainable use of natural resources, hydrothermal treatment of biomass and biomass waste for energy and resource recovery has received increasing attention. The hydrothermal carbonization (HTC) of a biomass is achieved using water as the reaction

Development of the Cerro solo deposit and uranium favorability of the San Jorge Gulf Basin, province of Chubut

International Nuclear Information System (INIS)

Navarra, P.R.; Benitez, A.F.

1997-01-01

In the future the uranium exploration activities of CNEA would tend to improve the knowledge of geology and uranium favorability; to perform prospection tasks, and research and development in exploration technologies, to contribute to be in a position to meet the requirements of the country in the long term. On the other hand, a strong growth of nuclear capacity is expected in the first two decades of the next century. Based on its promising grade, the Cerro Solo uranium ore deposit was selected in 1990 by the CNEA to carry out an assessment project. The intensive exploration level was accomplished, as follows: definition of general characteristics of the main orebodies; detailed geologic studies; estimation of resources with adequate data; and preliminary selection of mining-milling methods to estimate the potential profitability of the project. The deposit belongs to the sandstone type. The mineralized layers are distributed into the fluvial sandstones and conglomerates of the cretaceous Chubut Group, lying 50 to 130 m deep Resources of the deposit, with an average grade of 0.3% U, in tonnes of recoverable uranium at costs of up to $80/kg U, are: Reasonable Assured Resources (RAR): 800 t U, Estimated Additional Resources, Category I (EAR-I): 2100 t U. Follow-up drilling programmes are being performed at present in some of the target sites defined in the paleochannel that hosts the Cerro Solo deposit, in order to establish the hypothetical resources of the area. The sites were determined as a result of the exploration that CNEA conducted in the Pichinan uranium district. Recently a regional research project was formulated, for the detailed exploration in the San Jorge Gulf Basin, where the Chubut Group is distributed. 17 refs, 4 figs

Understanding the Compositional Variability of the Major Components of Hydrothermal Plumes in the Okinawa Trough

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Zhigang Zeng

2018-01-01

Full Text Available Studies of the major components of hydrothermal plumes in seafloor hydrothermal fields are critical for an improved understanding of biogeochemical cycles and the large-scale distribution of elements in the submarine environment. The composition of major components in hydrothermal plume water column samples from 25 stations has been investigated in the middle and southern Okinawa Trough. The physical and chemical properties of hydrothermal plume water in the Okinawa Trough have been affected by input of the Kuroshio current, and its influence on hydrothermal plume water from the southern Okinawa Trough to the middle Okinawa Trough is reduced. The anomalous layers of seawater in the hydrothermal plume water columns have higher K+, Ca2+, Mn2+, B3+, Ca2+/SO42-, and Mn2+/Mg2+ ratios and higher optical anomalies than other layers. The Mg2+, SO42-, Mg2+/Ca2+, and SO42-/Mn2+ ratios of the anomalous layers are lower than other layers in the hydrothermal plume water columns and are consistent with concentrations in hydrothermal vent fluids in the Okinawa Trough. This suggests that the chemical variations of hydrothermal plumes in the Tangyin hydrothermal field, like other hydrothermal fields, result in the discharge of high K+, Ca2+, and B3+ and low Mg2+ and SO42- fluid. Furthermore, element ratios (e.g., Sr2+/Ca2+, Ca2+/Cl− in hydrothermal plume water columns were found to be similar to those in average seawater, indicating that Sr2+/Ca2+ and Ca2+/Cl− ratios of hydrothermal plumes might be useful proxies for chemical properties of seawater. The hydrothermal K+, Ca2+, Mn2+, and B3+ flux to seawater in the Okinawa Trough is about 2.62–873, 1.04–326, 1.30–76.4, and 0.293–34.7 × 106 kg per year, respectively. The heat flux is about 0.159–1,973 × 105 W, which means that roughly 0.0006% of ocean heat is supplied by seafloor hydrothermal plumes in the Okinawa Trough.

Basin-scale transport of hydrothermal dissolved metals across the South Pacific Ocean.

Science.gov (United States)

Resing, Joseph A; Sedwick, Peter N; German, Christopher R; Jenkins, William J; Moffett, James W; Sohst, Bettina M; Tagliabue, Alessandro

2015-07-09

Hydrothermal venting along mid-ocean ridges exerts an important control on the chemical composition of sea water by serving as a major source or sink for a number of trace elements in the ocean. Of these, iron has received considerable attention because of its role as an essential and often limiting nutrient for primary production in regions of the ocean that are of critical importance for the global carbon cycle. It has been thought that most of the dissolved iron discharged by hydrothermal vents is lost from solution close to ridge-axis sources and is thus of limited importance for ocean biogeochemistry. This long-standing view is challenged by recent studies which suggest that stabilization of hydrothermal dissolved iron may facilitate its long-range oceanic transport. Such transport has been subsequently inferred from spatially limited oceanographic observations. Here we report data from the US GEOTRACES Eastern Pacific Zonal Transect (EPZT) that demonstrate lateral transport of hydrothermal dissolved iron, manganese, and aluminium from the southern East Pacific Rise (SEPR) several thousand kilometres westward across the South Pacific Ocean. Dissolved iron exhibits nearly conservative (that is, no loss from solution during transport and mixing) behaviour in this hydrothermal plume, implying a greater longevity in the deep ocean than previously assumed. Based on our observations, we estimate a global hydrothermal dissolved iron input of three to four gigamoles per year to the ocean interior, which is more than fourfold higher than previous estimates. Complementary simulations with a global-scale ocean biogeochemical model suggest that the observed transport of hydrothermal dissolved iron requires some means of physicochemical stabilization and indicate that hydrothermally derived iron sustains a large fraction of Southern Ocean export production.

SiC-dopped MCM-41 materials with enhanced thermal and hydrothermal stabilities

International Nuclear Information System (INIS)

Wang, Yingyong; Jin, Guoqiang; Tong, Xili; Guo, Xiangyun

2011-01-01

Graphical abstract: Novel SiC-dopped MCM-41 materials were synthesized by adding silicon carbide suspension in the molecular sieve precursor solvent followed by in situ hydrothermal synthesis. The dopped materials have a wormhole-like mesoporous structure and exhibit enhanced thermal and hydrothermal stabilities. Highlights: → SiC-dopped MCM-41 was synthesized by in situ hydrothermal synthesis of molecular sieve precursor combined with SiC. → The dopped MCM-41 materials show a wormhole-like mesoporous structure. → The thermal stability of the dopped materials have an increment of almost 100 o C compared with the pure MCM-41. → The hydrothermal stability of the dopped materials is also better than that of the pure MCM-41. -- Abstract: SiC-dopped MCM-41 mesoporous materials were synthesized by the in situ hydrothermal synthesis, in which a small amount of SiC was added in the precursor solvent of molecular sieve before the hydrothermal treatment. The materials were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, N 2 physical adsorption and thermogravimetric analysis, respectively. The results show that the thermal and hydrothermal stabilities of MCM-41 materials can be improved obviously by incorporating a small amount of SiC. The structure collapse temperature of SiC-dopped MCM-41 materials is 100 o C higher than that of pure MCM-41 according to the differential scanning calorimetry analysis. Hydrothermal treatment experiments also show that the pure MCM-41 will losses it's ordered mesoporous structure in boiling water for 24 h while the SiC-dopped MCM-41 materials still keep partial porous structure.

Preservation of iron(II) by carbon-rich matrices in a hydrothermal plume

Energy Technology Data Exchange (ETDEWEB)

Toner, Brandy M.; Fakra, Sirine C.; Manganini, Steven J.; Santelli, Cara M.; Marcus, Matthew A.; Moffett, James W.; Rouxel, Olivier; German, Christopher R.; Edwards, Katrina J.

2008-09-20

Hydrothermal venting associated with mid-ocean ridge volcanism is globally widespread. This venting is responsible for a dissolved iron flux to the ocean that is approximately equal to that associated with continental riverine runoff. For hydrothermal fluxes, it has long been assumed that most of the iron entering the oceans is precipitated in inorganic forms. However, the possibility of globally significant fluxes of iron escaping these mass precipitation events and entering open-ocean cycles is now being debated, and two recent studies suggest that dissolved organic ligands might influence the fate of hydrothermally vented metals. Here we present spectromicroscopic measurements of iron and carbon in hydrothermal plume particles at the East Pacific Rise mid-ocean ridge. We show that organic carbon-rich matrices, containing evenly dispersed iron(II)-rich materials, are pervasive in hydrothermal plume particles. The absence of discrete iron(II) particles suggests that the carbon and iron associate through sorption or complexation. We suggest that these carbon matrices stabilize iron(II) released from hydrothermal vents in the region, preventing its oxidation and/or precipitation as insoluble minerals. Our findings have implications for deep-sea biogeochemical cycling of iron, a widely recognized limiting nutrient in the oceans.

Effects of hydrothermal treatment of sewage sludge on pyrolysis and steam gasification

International Nuclear Information System (INIS)

Moon, Jihong; Mun, Tae-Young; Yang, Won; Lee, Uendo; Hwang, Jungho; Jang, Ensuk; Choi, Changsik

2015-01-01

Highlights: • Hydrothermal treatment (HT) is energy efficient and increases fuel energy density. • Pyrolysis and steam gasification were performed with sewage sludge before/after HT. • Product gases resembled those from wood chips, particularly at high temperature. • HT increases sludge lignin content, possibly enhancing methane yield of product gas. • HT can improve sewage sludge for use as an alternative to biomass and fossil fuels. - Abstract: Hydrothermal treatment is a promising option for pretreatment drying of organic waste, due to its low energy consumption and contribution to increasing fuel energy density. In this study, the characteristics of hydrothermally treated sewage sludge were investigated, and pyrolysis and steam gasification were performed with the sludge before and after hydrothermal treatment. The overall composition of product gases from treated sludge was similar to that obtained from steam gasification of wood chips, particularly under high-temperature conditions. In addition, the increase in lignin content of sewage sludge following hydrothermal treatment could help enhance methane yield in product gas during pyrolysis and steam gasification. The findings suggest that hydrothermal treatment is an appropriate method for improving sewage sludge for use as an alternative to biomass and fossil fuels

Notes on the ecology of Phyllodactylus reissi (Phyllodactylidae: Sauria in Parque Nacional Cerros de Amotape (Tumbes, Peru

Directory of Open Access Journals (Sweden)

Juan Carlos Jordán Arizmendi

2012-02-01

Full Text Available Some basics aspects on the ecology of the nocturnal gecko Phyllodactylus reissi from Parque Nacional Cerros de Amotape (Tumbes, Peru are described. This species used rock boulders (57,4% and trees (31,9% as microhabitats primarily, exhibiting a nocturnal activity pattern, with a peak between 2100-2200 hours, remaining active until midnight. Body temperature (mean 24,4 ºC was correlated with both air and substrate temperature, with the last variable affecting in higher degree (47% the body temperature of this species. The slightly high body temperature of Phyllodactylus reissi, compared to other Phyllodactylus geckos, could be related to nocturnal microhabitat use and diurnal retreat site selection. More studies on lizard ecology from this endangered ecosystem are needed.

Hydrothermal response to a volcano-tectonic earthquake swarm, Lassen, California

Science.gov (United States)

Ingebritsen, Steven E.; Shelly, David R.; Hsieh, Paul A.; Clor, Laura; P.H. Seward,; Evans, William C.

2015-01-01

The increasing capability of seismic, geodetic, and hydrothermal observation networks allows recognition of volcanic unrest that could previously have gone undetected, creating an imperative to diagnose and interpret unrest episodes. A November 2014 earthquake swarm near Lassen Volcanic National Park, California, which included the largest earthquake in the area in more than 60 years, was accompanied by a rarely observed outburst of hydrothermal fluids. Although the earthquake swarm likely reflects upward migration of endogenous H2O-CO2 fluids in the source region, there is no evidence that such fluids emerged at the surface. Instead, shaking from the modest sized (moment magnitude 3.85) but proximal earthquake caused near-vent permeability increases that triggered increased outflow of hydrothermal fluids already present and equilibrated in a local hydrothermal aquifer. Long-term, multiparametric monitoring at Lassen and other well-instrumented volcanoes enhances interpretation of unrest and can provide a basis for detailed physical modeling.

Subcritical hydrothermal conversion of organic wastes and biomass. Reaction pathways

Directory of Open Access Journals (Sweden)

Alejandro Amadeus Castro Vega

2007-01-01

Full Text Available Hydrothermal conversion is a procedure which emulates organic matter’s natural conversion into bio-crude having physical and chemical properties analogous to petroleum. The artificial transformation of biomass requi- res previous knowledge of the main reaction routes and product availability. The main component of biomass (depolymerisation by hydrolysis is presented in hydrothermal cellulose conversion, producing oligosaccharides which exhibit dehydration and retro-aldol condensation reactions for transforming into furfurals and carboxylic acids. Other biomass components (such as lignin, proteins, and fat esters present both hydrolysis and pyrolysis reaction routes. As long as biomass mainly contains carbohydrates, subcritical hydrothermal conversion products and their wastes will be fundamentally analogous to those displaying cellulose. These substances have added- value by far surpassing raw material’s acquisition cost. When the main hydrothermal conversion products’ O/C, H/C molar ratios as reported in literature are plotted, an evolutionary tralectory for conversion products appears to be closely or even overlapped with fossil fuels’ geological evolution.

Dynamic behavior of Kilauea Volcano and its relation to hydrothermal systems and geothermal energy

Science.gov (United States)

Kauhikaua, Jim; Moore, R.B.; ,

1993-01-01

Exploitation of hydrothermal systems on active basaltic volcanoes poses some unique questions about the role of volcanism and hydrothermal system evolution. Volcanic activity creates and maintains hydrothermal systems while earthquakes create permeable fractures that, at least temporarily, enhance circulation. Magma and water, possibly hydrothermal water, can interact violently to produce explosive eruptions. Finally, we speculate on whether volcanic behavior can be affected by high rates of heat extraction.

Procesos históricos y ambientales en Cerro de San Pedro, San Luis Potosí, México, 1948-1997

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Paula Andrea Martínez Chaves

2010-01-01

Full Text Available Los estudios sobre el municipio Cerro de San Pedro enfatizan la continuidad ambiental aparente que estimula la minería; sin embargo, esta lectura subvalora otras dinámicas que ocurren en la zona. Con base en observaciones directas de trabajo en campo, para realizar análisis de coberturas vegetales, entrevistas con los habitantes de la zona, revisión de cartografía e investigación de archivo, el presente trabajo muestra procesos como la explotación de recursos vegetales y el pastoreo, como actividades económicas paralelas a las labores mineras, y que no habían sido tratados hasta ahora.

Hydrothermal metallurgy for recycling of slag and glass

International Nuclear Information System (INIS)

Tanaka, Toshihiro; Yoshikawa, Takeshi; Hirai, Nobumitsu; Katsuyama, Shigeru

2009-01-01

The authors have applied hydrothermal reactions to develop recycling processing of slag or glass. As an example, under hydrothermal conditions such as 200 300 deg. C and 30 40MPa with H 2 O, powders made of glass can be sintered to become solidified glass materials containing about 10mass% H 2 O. When the glass containing H 2 O is heated again under normal pressure, the glass expands releasing H 2 O to make porous microstructure. H 2 O starts to emit just above the glass transition temperature. Therefore, when we have a glass with low glass transition temperature, we can make low temperature foaming glass. The SiO 2 -Na 2 O-B 2 O 3 glass is a candidate to be such a foaming glass. In this paper, we describe our recent trial on the fabrication of the low temperature foaming glass by using hydrothermal reaction.

Effect of hydrothermal treatment on some properties of Shenhua coal

Energy Technology Data Exchange (ETDEWEB)

Wang Zhi-cai; Shui Heng-fu; Zhang De-xiang; Gao Jin-sheng [East China University of Science and Technology, Shanghai (China). College of Resource and Environmental Engineering

2006-10-15

Effects of hydrothermal treatment on swelling, extraction and liquefaction behavior of Shenhua coal were studied through analyses of element content, ash content, volatile content and IR spectrum of treated coal. The results indicate that hydrogenation of coal is distinctly carried out in the process of hydrothermal pre-treatment and the hydrogen content of treated coal is more than that of raw coal. The contents of ash and volatile matters of treated coal are lower than those of raw coal. With the increase of treatment temperature the volatile content of the hydrothermal treated coal decreases and the ash content of treated coal increases. CO{sub 2} is main gas product and unvaries with the temperature changing, whereas CO and CH{sub 4} are formed when the temperature is above 250{sup o}C and increase with the temperature during hydrothermal treatment. Hydrothermal treatment is not in favor of coal swelling and the swelling ratio of treated coal decreases with the increase of treatment temperature. The swelling ratio of extraction residue by CS{sub 2}/NMP mixed solvent in NMP solvent is lower than that of the corresponding raw coal. The CS{sub 2}/NMP mixed solvent extraction yields of coal treated at appropriate temperature are higher than that of raw coal, but the extraction yields of treated coal obtained by n-hexane, toluene and THF successive Soxhelt extraction are lower. Hydrothermal treatment at 250-300{sup o}C can increase the conversion of treated coal in direct hydro-liquefaction. The gas + oil yield of treated coal is lower than that of raw coal and the preasphaltene yield of treated coal is much higher. IR spectra of treated coals show that the forms of non-covalent bonds are changed by hydrothermal treatment, and the hydrolysis of ester and ether bonds and the pyrolysis of aromatic side chains also maybe occur at high treatment temperature. 21 refs., 3 figs., 4 tabs.

Hydrothermal synthesis, characterization and luminescent ...

Indian Academy of Sciences (India)

Home; Journals; Bulletin of Materials Science; Volume 39; Issue 4. Hydrothermal synthesis, characterization and luminescent properties of lanthanide-doped NaLaF 4 nanoparticles. JIGMET LADOL HEENA KHAJURIA SONIKA KHAJURIA ... Keywords. Citric acid; X-ray diffraction; down-conversion emission; energy transfer.

Synthesis of ZrO2 nanoparticles by hydrothermal treatment

International Nuclear Information System (INIS)

Machmudah, Siti; Widiyastuti, W.; Prastuti, Okky Putri; Nurtono, Tantular; Winardi, Sugeng; Wahyudiono,; Kanda, Hideki; Goto, Motonobu

2014-01-01

Zirconium oxide (zirconia, ZrO 2 ) is the most common material used for electrolyte of solid oxide fuel cells (SOFCs). Zirconia has attracted attention for applications in optical coatings, buffer layers for growing superconductors, thermal-shield, corrosion resistant coatings, ionic conductors, and oxygen sensors, and for potential applications including transparent optical devices and electrochemical capacitor electrodes, fuel cells, catalysts, and advanced ceramics. In this work, zirconia particles were synthesized from ZrCl 4 precursor with hydrothermal treatment in a batch reactor. Hydrothermal treatment may allow obtaining nanoparticles and sintered materials with controlled chemical and structural characteristics. Hydrothermal treatment was carried out at temperatures of 150 – 200°C with precursor concentration of 0.1 – 0.5 M. Zirconia particles obtained from this treatment were analyzed by using SEM, PSD and XRD to characterize the morphology, particle size distribution, and crystallinity, respectively. Based on the analysis, the size of zirconia particles were around 200 nm and it became smaller with decreasing precursor concentration. The increasing temperature caused the particles formed having uniform size. Zirconia particles formed by hydrothermal treatment were monoclinic, tetragonal and cubic crystal

Production of lightweight refractory material by hydrothermal process

International Nuclear Information System (INIS)

Sulejmani, Ramiz B.

2002-01-01

Many different processes of production of lightweight refractories are well known over the World. Traditional production of lightweight refractories is by addition of combustibles or by a special frothing process. This work is concerned with hydrothermal of lightweight refractories from rice husk ash. The rice husk ash, used in present investigations were from Kocani region, R. Macedonia. The chemical analysis of the rice husk ash shows that it contains 91,8 - 93,7% SiO 2 and some alkaline and alkaline earth oxides. Microscopic and X - ray diffraction examinations of the rice husk ash have shown that it is composed of cristobalite, tridimite and amorphous silica. The composition of the mixture for lightweight refractory brick production is 93,4% rice husk ash and 6,6% Ca(OH) 2 . The mixtures were well mixed, moistened and pressed at 5 - 10 MPa. The hydrothermal reactions between calcium hydroxide and rice husk ash over the temperature range 80 - 160 o C were investigated. The period of autoclave treatment was from 2 to 72 h. After the hydrothermal treatment of the samples, the mineralogical composition, bulk density, density, cold crushing strength, porosity, refractoriness and thermal expansion were examined. Analysing the properties of the obtained samples it can be concluded that from rice husk ash and calcium hydroxide under hydrothermal condition it is possible to obtain lightweight acid refractory material with high quality.(Author)

Some genetic aspects of hydrothermal uranium deposits in the Bakulja granitoide (Serbia)

International Nuclear Information System (INIS)

Jelenkovic, Rade

1998-01-01

This paper discusses the influence of temperature and the way of hydrothermal fluids flow in function of both the degree of tectonized granitoid and the origin of solutions, and partly the processes accompanying mineralization expressed through physico-chemical, mineralogical and mechanical alterations of the mother rock. It has been concluded that heat energy exchange is in function of: 1) petrochemical characteristic of a rock the hydrothermal fluids flow through; 2) degree of tectonization of the surrounding mineralized rocks; 3) volume and morphology of the fissured-porous space; 4) form of uranium bonding in mineral carriers; 5) degree of uranium leaching in hydrothermal solutions; 6) the way of hydrothermal fluids flow, and 7) coefficient of heat exchange expressed by distribution of heat energy within a fluid-rock system. It has also been established that contraction of granite volume results from physico-chemical processes that take place within a granitoid-hydrothermal fluid system and its quantification has been carried out. (Author)

Heat flux from magmatic hydrothermal systems related to availability of fluid recharge

Science.gov (United States)

Harvey, M. C.; Rowland, J.V.; Chiodini, G.; Rissmann, C.F.; Bloomberg, S.; Hernandez, P.A.; Mazot, A.; Viveiros, F.; Werner, Cynthia A.

2015-01-01

Magmatic hydrothermal systems are of increasing interest as a renewable energy source. Surface heat flux indicates system resource potential, and can be inferred from soil CO2 flux measurements and fumarole gas chemistry. Here we compile and reanalyze results from previous CO2 flux surveys worldwide to compare heat flux from a variety of magma-hydrothermal areas. We infer that availability of water to recharge magmatic hydrothermal systems is correlated with heat flux. Recharge availability is in turn governed by permeability, structure, lithology, rainfall, topography, and perhaps unsurprisingly, proximity to a large supply of water such as the ocean. The relationship between recharge and heat flux interpreted by this study is consistent with recent numerical modeling that relates hydrothermal system heat output to rainfall catchment area. This result highlights the importance of recharge as a consideration when evaluating hydrothermal systems for electricity generation, and the utility of CO2 flux as a resource evaluation tool.

Hydrothermal plume anomalies over the southwest Indian ridge: magmatic control

Science.gov (United States)

Yue, X.; Li, H.; Tao, C.; Ren, J.; Zhou, J.; Chen, J.; Chen, S.; Wang, Y.

2017-12-01

Here we firstly reported the extensive survey results of the hydrothermal activity along the ultra-slow spreading southwest Indian ridge (SWIR). The study area is located at segment 27, between the Indomed and Gallieni transform faults, SWIR. The seismic crustal thickness reaches 9.5km in this segment (Li et al., 2015), which is much thicker than normal crustal. The anomaly thickened crust could be affected by the Crozet hotspot or highly focused melt delivery from the mantle. The Duanqiao hydrothermal field was reported at the ridge valley of the segment by Tao et al (2009). The Deep-towed Hydrothermal Detection System (DHDS) was used to collect information related with hydrothermal activity, like temperature, turbidity, oxidation-reduction potential (ORP) and seabed types. There are 15 survey lines at the interval of 2 to 3 km which are occupied about 1300 km2 in segment 27. After processing the raw data, including wiping out random noise points, 5-points moving average processing and subtracting the ambient, we got anomalous Nephelometric Turbidity Units values (ΔNTU). And dE/dt was used to identify the ORP anomalous as the raw data is easily influenced by electrode potentials drifting (Baker et al., 2016). According to the results of water column turbidity and ORP distributions, we confirmed three hydrothermal anomaly fields named A1, A2 and A3. The three fields are all located in the western part of the segment. The A1 field lies on the ridge valley, west side of Duanqiao field. The A2 and A3 field lie on the northern and southern of the ridge valley, respectively. We propose that recent magmatic activity probably focus on the western part of segment 27.And the extensive distribution of hydrothermal plume in the segment is the result of the discrete magma intrusion. References Baker E T, et al. How many vent fields? New estimates of vent field populations on ocean ridges from precise mapping of hydrothermal discharge locations. EPSL, 2016, 449:186-196. Li J

Free-living nematode species (Nematoda) dwelling in hydrothermal sites of the North Mid-Atlantic Ridge

Science.gov (United States)

Tchesunov, Alexei V.

2015-12-01

Morphological descriptions of seven free-living nematode species from hydrothermal sites of the Mid-Atlantic Ridge are presented. Four of them are new for science: Paracanthonchus olgae sp. n. (Chromadorida, Cyatholaimidae), Prochromadora helenae sp. n. (Chromadorida, Chromadoridae), Prochaetosoma ventriverruca sp. n. (Desmodorida, Draconematidae) and Leptolaimus hydrothermalis sp. n. (Plectida, Leptolaimidae). Two species have been previously recorded in hydrothermal habitats, and one species is recorded for the first time in such an environment. Oncholaimus scanicus (Enoplida, Oncholaimidae) was formerly known from only the type locality in non-hydrothermal shallow milieu of the Norway Sea. O. scanicus is a very abundant species in Menez Gwen, Lucky Strike and Lost City hydrothermal sites, and population of the last locality differs from other two in some morphometric characteristics. Desmodora marci (Desmodorida, Desmodoridae) was previously known from other remote deep-sea hydrothermal localities in south-western and north-eastern Pacific. Halomonhystera vandoverae (Monhysterida, Monhysteridae) was described and repeatedly found in mass in Snake Pit hydrothermal site. The whole hydrothermal nematode assemblages are featured by low diversity in comparison with either shelf or deep-sea non-hydrothermal communities. The nematode species list of the Atlantic hydrothermal vents consists of representatives of common shallow-water genera; the new species are also related to some shelf species. On the average, the hydrothermal species differ from those of slope and abyssal plains of comparable depths by larger sizes, diversity of buccal structures, presence of food content in the gut and ripe eggs in uteri.

Heavy metals from Kueishantao shallow-sea hydrothermal vents, offshore northeast Taiwan

Science.gov (United States)

Chen, Xue-Gang; Lyu, Shuang-Shuang; Garbe-Schönberg, Dieter; Lebrato, Mario; Li, Xiaohu; Zhang, Hai-Yan; Zhang, Ping-Ping; Chen, Chen-Tung Arthur; Ye, Ying

2018-04-01

Shallow water hydrothermal vents are a source of heavy metals leading to their accumulation in marine organisms that manage to live under extreme environmental conditions. This is the case at Kueishantao (KST) shallow-sea vents system offshore northeast Taiwan, where the heavy metal distribution in vent fluids and ambient seawater is poorly understood. This shallow vent is an excellent natural laboratory to understand how heavy and volatile metals behave in the nearby water column and ecosystem. Here, we investigated the submarine venting of heavy metals from KST field and its impact on ambient surface seawater. The total heavy metal concentrations in the vent fluids and vertical plumes were 1-3 orders of magnitude higher than the overlying seawater values. When compared with deep-sea hydrothermal systems, the estimated KST end-member fluids exhibited much lower concentrations of transition metals (e.g., Fe and Mn) but comparable concentrations of toxic metals such as Pb and As. This may be attributed to the lower temperature of the KST reaction zone and transporting fluids. Most of the heavy metals (Fe, Mn, As, Y, and Ba) in the plumes and seawater mainly originated from hydrothermal venting, while Cd and Pb were largely contributed by external sources such as contaminated waters (anthropogenic origin). The spatial distribution of heavy metals in the surface seawater indicated that seafloor venting impacts ambient seawater. The measurable influence of KST hydrothermal activity, however, was quite localized and limited to an area of heavy metals emanating from the yellow KST hydrothermal vent were: 430-2600 kg Fe, 24-145 kg Mn, 5-32 kg Ba, 10-60 kg As, 0.3-1.9 kg Cd, and 2-10 kg Pb. This study provides important data on heavy metals from a shallow-sea hydrothermal field, and it helps to better understand the environmental impact of submarine shallow hydrothermal venting.

Exploration Method Development for hydrothermal plume hunting by XCTD

Science.gov (United States)

Kitagawa, Y.; Ikeda, M.; Kadoshima, K.; Koizumi, Y.; Nakano, J.; Asakawa, E.; Sumi, T.

2017-12-01

J-MARES (Research and Development Partnership for Next Generation Technology of Marine Resources Survey, JAPAN) has been designing a low-cost and high-efficiency exploration system for seafloor hydrothermal massive sulfide deposits in "Cross-ministerial Strategic Innovation Promotion Program (SIP)" granted by the Cabinet Office, Government of Japan since 2014. We proposed hydrothermal plume hunting by XCTD (eXpendables Conductivity, Temperature and Depth). We applied this method to an area of interest more than 100km x 100km over Okinawa Trough, including some known seafloor massive sulfide deposits. Generally, hydrothermal plume exploration has been by ship mounted with MBES (Multi Beam Echo Sounder) or AUV with sound anomaly observation. However, these methods have to charter the sophisticated ship costly. On the other hand, throw-in type water quality meters (eg. XCTD and XBT) can be low-cost and easily operable. Moreover, that can make a quick look at seawater temperature and conductivity even in rough waters.Firstly, we confirmed XCTD probes position on the seafloor by ROV mounted deep-sea high vision camera. As a result of the test, probes swept downstream about 40 m in horizontal distance from throwing positions with about 1,600m in water depth. Following the previous test results, we had performed to the next test that confirmed detection range of hydrothermal plume at the chimney of North Mound in Izena Cauldron, so we had caught anomaly of seawater temperature and conductivity successfully which could be possibly derived from hydrothermal activities. Although averaged seawater temperature at a depth of 1500 m or more was about 3.95 degrees C, near the chimney was about 4.93 degrees C. The temperature anomalies originated from the hydrothermal plumes could be distributed at most 30m in horizontal distance and became smaller away from the chimney. Moreover, temperature anomaly mass of sea water tended to move upward in depth with distance away from the

Enhanced bioactivity and biocompatibility of nanostructured hydroxyapatite coating by hydrothermal annealing

International Nuclear Information System (INIS)

Hahn, Byung-Dong; Lee, Jeong-Min; Park, Dong-Soo; Choi, Jong-Jin; Ryu, Jungho; Yoon, Woon-Ha; Choi, Joon-Hwan; Lee, Byoung-Kuk; Kim, Jong-Woo; Kim, Hyoun-Ee; Kim, Seong-Gon

2011-01-01

The crystallinity of hydroxyapatite (HA) coatings prepared by aerosol deposition may be increased by heating in air or low-temperature hydrothermal processing. From the X-ray diffraction and Fourier transform infrared spectroscopy results, it was revealed that the crystallinity of the HA coatings significantly increased after the post-annealing. Transmission electron microscopy showed that the conventional furnace heating induced the substantial growth of the HA crystallites, whereas the hydrothermal treatment did not bring about any remarkable change in the HA crystallite size, which remained below 20 nm. The bioactivity of the HA coatings was estimated by the acellular simulated body fluid immersion test. After immersion for 7 days, newly-precipitated apatite crystals were only observed on the surfaces of the samples hydrothermally treated at 170 and 190 deg. C. In addition, the alkaline phosphatase activity of MC3T3-E1 preosteoblast cells cultured on the hydrothermally treated samples was significantly higher than those on the as-deposited coating and conventional furnace heated samples. The enhanced bioactivity and excellent biological in vitro cellular response of the hydrothermally treated samples were attributed to their nanostructured nature and high degree of crystallinity.

Genome-resolved metagenomics reveals that sulfur metabolism dominates the microbial ecology of rising hydrothermal plumes

Science.gov (United States)

Anantharaman, K.; Breier, J. A., Jr.; Jain, S.; Reed, D. C.; Dick, G.

2015-12-01

Deep-sea hydrothermal plumes occur when hot fluids from hydrothermal vents replete with chemically reduced elements and compounds like sulfide, methane, hydrogen, ammonia, iron and manganese mix with cold, oxic seawater. Chemosynthetic microbes use these reduced chemicals to power primary production and are pervasive throughout the deep sea, even at sites far removed from hydrothermal vents. Although neutrally-buoyant hydrothermal plumes have been well-studied, rising hydrothermal plumes have received little attention even though they represent an important interface in the deep-sea where microbial metabolism and particle formation processes control the transformation of important elements and impact global biogeochemical cycles. In this study, we used genome-resolved metagenomic analyses and thermodynamic-bioenergetic modeling to study the microbial ecology of rising hydrothermal plumes at five different hydrothermal vents spanning a range of geochemical gradients at the Eastern Lau Spreading Center (ELSC) in the Western Pacific Ocean. Our analyses show that differences in the geochemistry of hydrothermal vents do not manifest in microbial diversity and community composition, both of which display only minor variance across ELSC hydrothermal plumes. Microbial metabolism is dominated by oxidation of reduced sulfur species and supports a diversity of bacteria, archaea and viruses that provide intriguing insights into metabolic plasticity and virus-mediated horizontal gene transfer in the microbial community. The manifestation of sulfur oxidation genes in hydrogen and methane oxidizing organisms hints at metabolic opportunism in deep-sea microbes that would enable them to respond to varying redox conditions in hydrothermal plumes. Finally, we infer that the abundance, diversity and metabolic versatility of microbes associated with sulfur oxidation impart functional redundancy that could allow it to persist in the dynamic settings of hydrothermal plumes.

How Pore-Fluid Pressure due to Heavy Rainfall Influences Volcanic Eruptions, Example of 1998 and 2008 Eruptions of Cerro Azul (Galapagos)

Science.gov (United States)

Albino, F.; Amelung, F.; Gregg, P. M.

2016-12-01

About 30 worldwide seismic studies have shown a strong correlation between rainfall and earthquakes in the past 22 years (e.g. Costain and Bollinger, 2010). Such correlation has been explained by the phenomenon of hydro-seismicity via pore pressure diffusion: an increase of pore-fluid in the upper crust reduces the normal stress on faults, which can trigger shear failure. Although this pore pressure effect is widely known for earthquakes, this phenomenon and more broadly poro-elasticity process are not widely studied on volcanoes. However, we know from our previous works that tensile failures that open to propagate magma through the surface are also pore pressure dependent. We have demonstrated that an increase of pore pressure largely reduces the overpressure required to rupture the magma reservoir. We have shown that the pore pressure has more influence on reservoir stability than other parameters such as the reservoir depth or the edifice loading. Here, we investigate how small pore-fluid changes due to hydrothermal or aquifer refill during heavy rainfall may perturb the conditions of failure around magma reservoirs and, what is more, if these perturbations are enough to trigger magma intrusions. We quantify the pore pressure effect on magmatic system by combining 1) 1D pore pressure diffusion model to quantify how pore pressure changes from surface to depth after heavy rainfall events and 2) 2D poro-elastic numerical model to provide the evolution of failure conditions of the reservoir as a consequence of these pore pressure changes. Sensitivity analysis is also performed to characterize the influence on our results of the poro-elastic parameters (hydraulic diffusivity, permeability and porosity) and the geometry of the magma reservoir and the aquifer (depth, size, shape). Finally, we apply our methodology to Cerro Azul volcano (Galapagos) where both last eruptions (1998 and 2008) occurred just after heavy rainfall events, without any pre-eruptive inflation. In

Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

Directory of Open Access Journals (Sweden)

Yao Zhang

Full Text Available To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4 concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

Science.gov (United States)

Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi

2012-01-01

To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4)) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4) was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4) concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

Comparative assessment of five potential sites for hydrothermal magma systems: geochemistry

Energy Technology Data Exchange (ETDEWEB)

White, A.F.

1980-08-01

A brief discussion is given of the geochemical objectives and questions that must be addressed in such an evaluation. A summary of the currently published literature that is pertinent in answering these questions is presented for each of the five areas: The Geysers-Clear Lake region, Long Valley, Rio Grand Rift, Roosevelt Hot Springs, and the Salton Trough. The major geochemical processes associated with proposed hydrothermal sites are categorized into three groups for presentation: geochemistry of magma and associated volcanic rocks, geochemistry of hydrothermal solutions, and geochemistry of hydrothermal alteration. (MHR)

Selective oxidation of propylene to acrolein by hydrothermally synthesized bismuth molybdates

DEFF Research Database (Denmark)

Schuh, Kirsten; Kleist, Wolfgang; Høj, Martin

2014-01-01

Hydrothermal synthesis has been used as a soft chemical method to prepare bismuth molybdate catalysts for the selective oxidation of propylene to acrolein. All obtained samples displayed a plate-like morphology, but their individual aspect ratios varied with the hydrothermal synthesis conditions...... of nitric acid during hydrothermal synthesis enhanced both propylene conversion and acrolein yield, possibly due to a change in morphology. Formation of β-Bi2Mo2O9 was not observed under the applied conditions. In general, the catalytic performance of all samples decreased notably after calcination at 550...

Hydrothermal Disintegration and Extraction of Different Microalgae Species

Directory of Open Access Journals (Sweden)

Michael Kröger

2018-02-01

Full Text Available For the disintegration and extraction of microalgae to produce lipids and biofuels, a novel processing technology was investigated. The utilization of a hydrothermal treatment was tested on four different microalgae species (Scenedesmus rubescens, Chlorella vulgaris, Nannochloropsis oculata and Arthorspira platensis (Spirulina to determine whether it has an advantage in comparison to other disintegration methods for lipid extraction. It was shown, that hydrothermal treatment is a reasonable opportunity to utilize microalgae without drying and increase the lipid yield of an algae extraction process. For three of the four microalgae species, the extraction yield with a prior hydrothermal treatment elevated the lipid yield up to six times in comparison to direct extraction. Only Scenedesmus rubescens showed a different behaviour. Reason can be found in the different cell wall of the species. The investigation of the differences in cell wall composition of the used species indicate that the existence of algaenan as a cell wall compound plays a major role in stability.

Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy

OpenAIRE

Daegi Kim; Kunio Yoshikawa; Ki Young Park

2015-01-01

The effect of hydrothermal carbonization on the properties of cellulose present in lignocellulosic biomass was investigated for converting it into a renewable energy resource with high energy recovery efficiency. The biochar obtained from cellulose subjected to hydrothermal carbonization showed a significant increase in its carbon content and a calorific value. 13C NMR spectroscopy showed that when raw cellulose was subjected to hydrothermal carbonization above 220 °C, the resulting biochar h...

Hydrothermal germination models: Improving experimental efficiency by limiting data collection to the relevant hydrothermal range

Science.gov (United States)

Hydrothermal models used to predict germination response in the field are usually parameterized with data from laboratory experiments that examine the full range of germination response to temperature and water potential. Inclusion of low water potential and high and low-temperature treatments, how...

Comparison of anti-corrosive properties between hot alkaline nitrate blackening and hydrothermal blackening routes

Energy Technology Data Exchange (ETDEWEB)

Fattah-alhosseini, A. [Department of Materials Engineering, Bu-Ali Sina University, Hamedan 65178-38695 (Iran, Islamic Republic of); Yazdani Khan, H., E-mail: hamid.yazdanikhan@gmail.com [Department of Materials Engineering, Bu-Ali Sina University, Hamedan 65178-38695 (Iran, Islamic Republic of); Heidarpour, A. [Department of Metallurgy and Materials Engineering, Hamedan University of Technology, Hamedan, 65155-579 (Iran, Islamic Republic of)

2016-08-15

In this study, the oxide films were formed on carbon steel by using hot alkaline nitrate and hydrothermal treatments. A dense and protective oxide film was obtained by hydrothermal method due to application of high pressure and by increasing solution temperature from boiling temperature (155 °C) to 250 °C. Oxide films were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and electrochemical tests including potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). These analyses showed that the magnetite film which was formed on carbon steel surface by hydrothermal treatment offers the best resistance in 3.5 wt.% NaCl solution. Although thicker oxide film could be obtained via hot alkaline nitrate black oxidizing, corrosion resistance was lower as a result of being highly porous and the presence of hematite. - Highlights: • Oxide films have been formed on steel by using of hot alkaline nitrate and hydrothermal treatments. • A dense and protective oxide film was obtained by hydrothermal treatment. • SEM micrographs showed that a dense and protective oxide film was obtained by hydrothermal treatment. • Film formed by hydrothermal treatment could have the best resistance in 3.5 wt.% NaCl solution.

El Cerro de los Santos: paisaje, negociación social y ritualidad entre el mundo ibérico y el hispano

Directory of Open Access Journals (Sweden)

García Cardiel, Jorge

2015-12-01

Full Text Available The Iberian shrine of Cerro de los Santos is located next to one of the main roads in the Southeast of the Meseta, in the middle of an area without any town of some entity. This paper aims to highlight its status as a shrine of passage, i.e. as a sacred, safe point where voyagers could rest overnight under the protection of the god. The creation of a statio by the Romans in such a place and its dedication to the goddess Pales provide more circumstantial evidence for this theory. Furthermore, some domestic material contexts can be defined, probably connected with this activity, and clearly different from the well-known ritual contexts of the shrine.La ubicación del santuario ibérico del Cerro de los Santos junto a una de las principales vías de comunicación del sureste meseteño y en el centro de una comarca desprovista de núcleos urbanos de cierta entidad permite subrayar en este artículo su uso continuado como santuario de paso, lugar sacro y seguro al que los caminantes podrían acogerse para pernoctar bajo la protección de la divinidad. La creación de una statio en el enclave en época romana y su dedicación a la diosa Pales no son sino argumentos ulteriores en este sentido. Se identifican además contextos materiales domésticos, distintos de los espacios de culto bien conocidos del santuario, relacionables con esta otra actividad.

Metallogenic hydrothermal solution system of post volcanic magma in Xiangshan ore field

International Nuclear Information System (INIS)

Xu Hengli; Shao Fei; Zou Maoqin

2009-01-01

This paper has systematically described uranium metallogenic characteristics of Xiangshan ore field.Sources of metallogenic materials are discussed in different temporal and spatial scale. Combining with background analysis of metallogenic tectonic-magmatic-geodynamics, formation and evolution of metallogenic hydrothermal solution system in Xiangshan volcanic basin are studied. Metallogenic hydrothermal solution system in Xiangshan ore field is considered as the objective product of systematic evolution of hydrothermal solution in post volcanic magma constrained by regional tectonic environment. In time scale, metallogenic hydrothermal solution system developed for about 50 Ma, but its active spaces varied in different time domains. So temporal and spatial distribution of uranium mineralization is constrained. Further exploration for the ore field is also suggested in this paper. (authors)

Synthesis and luminescence properties of (Zn,Cd)S:Ag nanocrystals by hydrothermal method

International Nuclear Information System (INIS)

Luo Xixian; Cao Wanghe; Zhou Lixin

2007-01-01

ZnS:Ag and (Zn,Cd)S:Ag nanoparticles with particle sizes of about 50 and 150 nm have been prepared by hydrothermal method. The effects of hydrothermal process on the physical and luminescence characteristics are investigated. The photoluminescence intensities of hydrothermal treatment ZnS:Ag samples are 10 times higher than that of non-treated samples after annealing at 800 deg. C

Decree 343/012. Is regulated the servitude established by Decree-Law 10,383, on several lines of electricity conduction -150 KV to be built in the departments of Florida, Cerro Largo, Maldonado, Flores, San Jose and Tacuarembo

International Nuclear Information System (INIS)

2012-01-01

This decree regulates the establishment of electricity conduction in Florida, Cerro Largo, Maldonado, Flores, San Jose and Tacuarembo towns. These electrical lines are necessary to provide the public service by UTE

Report about drilling works made in 13 Anomaly de Taylor and in the N- NE of its, around Fraile Muerto (Cerro Largo district): Uranium project

International Nuclear Information System (INIS)

Massa, J; Pirelli, H.

1983-01-01

The perforations were carried out to investigate in depth denominated anomaly 13 detected during the Taylor Mission (1975) and extended the punch area of study during you are suitable DINAMIGE-BRGM (Project the present report details the activities realised in the environs Fraile Muerto (Cerro Largo district) by the command team of perforations of the uranium project. Previously and contemporarily to the executed works, prospection became geophysical ground geochemistry geology and, works. (Uranium)

V isotope composition in modern marine hydrothermal sediments

Science.gov (United States)

Wu, F.; Owens, J. D.; Nielsen, S.; German, C. R.; Rachel, M.

2017-12-01

Vanadium is multivalence transition metal with two isotopes (51V and 50V). Recent work has shown that large V isotope variations occur with oxygen variations in modern sediments (Wu et al., 2016 and 2017 Goldschmidt Abstracts), providing its potential as a promising proxy for determining low oxygen conditions. However, the development of V isotopes as a proxy to probe past redox conditions requires a comprehensive understanding of the modern oceanic isotopic mass balance. Therein, the scavenging of V from the hydrous iron oxides in hydrothermal fluid has been shown to be an important removal process from seawater (Rudnicki and Elderfield, 1993 GCA) but remains unquantified. In this study, we analyzed V isotopic compositions of metalliferous sediments around the active TAG hydrothermal mound from the mid-Atlantic Ridge (26° degrees North) and the Eastern Pacific Zonal Transect (GEOTRACES EPZT cruise GP16). The TAG sediments deposited as Fe oxyhydroxides from plume fall-out, and have δ51V values between -0.3 to 0‰. The good correlation between Fe and V for these metalliferous sediments indicate that the accumulation of V in these samples is directly related to the deposition of Fe oxyhydroxides, which also control their V isotope signature. The EPZT samples cover 8,000 km in the South Pacific Ocean with sedimentary areas that underlie the Peru upwelling region and the well-oxygenated deep South Pacific Ocean influenced by hydtorthermal plume material from southern East Pacific Rise (EPR). The sediments collected at the east of the EPR have δ51V values between -1.2 to -0.7‰, similar to previous δ51V of oxic sediments. In contrast, the sediments from the west of the EPR have δ51V values (-0.4 to 0‰) similar to hydrothermal sediments from the mid-Atlantic Ridge, indicating the long transportation (more than 4,000 km, Fitzsimmons et al., 2017 NG) of Fe and Mn from hydrothermal plume and their incorporation into sediments have a major impact on the cycle of V

Evolution of interstellar organic compounds under asteroidal hydrothermal conditions

Science.gov (United States)

Vinogradoff, V.; Bernard, S.; Le Guillou, C.; Remusat, L.

2018-05-01

Carbonaceous chondrites (CC) contain a diversity of organic compounds. No definitive evidence for a genetic relationship between these complex organic molecules and the simple organic molecules detected in the interstellar medium (ISM) has yet been reported. One of the many difficulties arises from the transformations of organic compounds during accretion and hydrothermal alteration on asteroids. Here, we report results of hydrothermal alteration experiments conducted on a common constituent of interstellar ice analogs, Hexamethylenetetramine (HMT - C6H12N4). We submitted HMT to asteroidal hydrothermal conditions at 150 °C, for various durations (up to 31 days) and under alkaline pH. Organic products were characterized by gas chromatography mass spectrometry, infrared spectroscopy and synchrotron-based X-ray absorption near edge structure spectroscopy. Results show that, within a few days, HMT has evolved into (1) a very diverse suite of soluble compounds dominated by N-bearing aromatic compounds (> 150 species after 31 days), including for instance formamide, pyridine, pyrrole and their polymers (2) an aromatic and N-rich insoluble material that forms after only 7 days of experiment and then remains stable through time. The reaction pathways leading to the soluble compounds likely include HMT dissociation, formose and Maillard-type reactions, e.g. reactions of sugar derivatives with amines. The present study demonstrates that, if interstellar organic compounds such as HMT had been accreted by chondrite parent bodies, they would have undergone chemical transformations during hydrothermal alteration, potentially leading to the formation of high molecular weight insoluble organic molecules. Some of the diversity of soluble and insoluble organic compounds found in CC may thus result from asteroidal hydrothermal alteration.

The origin of methanethiol in midocean ridge hydrothermal fluids.

Science.gov (United States)

Reeves, Eoghan P; McDermott, Jill M; Seewald, Jeffrey S

2014-04-15

Simple alkyl thiols such as methanethiol (CH3SH) are widely speculated to form in seafloor hot spring fluids. Putative CH3SH synthesis by abiotic (nonbiological) reduction of inorganic carbon (CO2 or CO) has been invoked as an initiation reaction for the emergence of protometabolism and microbial life in primordial hydrothermal settings. Thiols are also presumptive ligands for hydrothermal trace metals and potential fuels for associated microbial communities. In an effort to constrain sources and sinks of CH3SH in seafloor hydrothermal systems, we determined for the first time its abundance in diverse hydrothermal fluids emanating from ultramafic, mafic, and sediment-covered midocean ridge settings. Our data demonstrate that the distribution of CH3SH is inconsistent with metastable equilibrium with inorganic carbon, indicating that production by abiotic carbon reduction is more limited than previously proposed. CH3SH concentrations are uniformly low (∼10(-8) M) in high-temperature fluids (>200 °C) from all unsedimented systems and, in many cases, suggestive of metastable equilibrium with CH4 instead. Associated low-temperature fluids (<200 °C) formed by admixing of seawater, however, are invariably enriched in CH3SH (up to ∼10(-6) M) along with NH4(+) and low-molecular-weight hydrocarbons relative to high-temperature source fluids, resembling our observations from a sediment-hosted system. This strongly implicates thermogenic interactions between upwelling fluids and microbial biomass or associated dissolved organic matter during subsurface mixing in crustal aquifers. Widespread thermal degradation of subsurface organic matter may be an important source of organic production in unsedimented hydrothermal systems and may influence microbial metabolic strategies in cooler near-seafloor and plume habitats.

Borehole plugging by hydrothermal transport. A feasibility report

International Nuclear Information System (INIS)

Roy, D.M.; White, W.B.

1975-01-01

The possibility of forming borehole plugs by hydrothermal transport was examined with respect to five systems, utilizing available literature data. In general, it would appear possible to create plugs with hydrothermal cements, with hydrothermally transported quartz, and with carbonates precipitated in-situ using carbon dioxide or carbon dioxide and water as reacting fluids. Hydrothermal cements appear to be most feasible from an engineering and economic point of view using a slurry with a lime-alumina-silica composition carried into the hole in a single pipe at temperatures in the range of 200 0 C and requiring only enough pressure to drive the mixture into the hole. Quartz or chalcedony plugs would be the most impervious, have the lowest chemical reactivity with groundwater, the lowest thermal expansion, and be most compatible with the wall rock. Deposition is likely to be slow, and there are severe engineering problems associated with a single pipe system carrying silica-rich solutions at temperatures in excess of 500 0 C at pressure of 2000 bars (30,000 psi). Calcite plugs could be formed as compatible plug materials in contact with a limestone or dolomite wall rock. It is not known whether non-porous plugs can be readily formed and there is also a problem of chemical reaction with percolating groundwater. The clay-water and sulfur-water systems do not appear to be viable plug systems. In-situ reconstitution of the wall rock does not appear to be an economically feasible possibility

A hydrogeological conceptual model of the Suio hydrothermal area (central Italy)

Science.gov (United States)

Saroli, Michele; Lancia, Michele; Albano, Matteo; Casale, Anna; Giovinco, Gaspare; Petitta, Marco; Zarlenga, Francesco; dell'Isola, Marco

2017-09-01

A hydrogeological conceptual model has been developed that describes the hydrothermal system of Suio Terme (central Italy). The studied area is located along the peri-Tyrrhenian zone of the central Apennines, between the Mesozoic and Cenozoic carbonate platform sequences of the Aurunci Mountains and the volcanic sequences of the Roccamonfina. A multi-disciplinary approach was followed, using new hydrogeological surveys, the interpretation of stratigraphic logs of boreholes and water wells, and geophysical data—seismic sections, shear-wave velocity (Vs) crustal model and gravimetric model. The collected information allowed for construction of a conceptual hydrogeological model and characterization of the hydrothermal system. The Suio hydrothermal system is strongly influenced by the Eastern Aurunci hydrostructure. Along the southeastern side, the top of the hydrostructure sinks to -1,000 m relative to sea level via a series of normal faults which give origin to the Garigliano graben. Geological and hydrogeological data strongly suggest the propagation and mixing of hot fluids, with cold waters coming from the shallow karst circuit. The aquitard distribution, the normal tectonic displacements and the fracturing of the karst hydrostructure strongly influence the hydrothermal basin. Carbon dioxide and other gasses play a key role in the whole circuit, facilitating the development of the hydrothermal system. The current level of knowledge suggests that the origin of the Suio hydrothermalism is the result of interaction between the carbonate reservoir of the Eastern Aurunci Mountains and the hot and deep crust of this peri-Tyrrhenian sector, where the Roccamonfina volcano represents the shallowest expression.

Recycling of water, carbon, and sulfur during subduction of serpentinites: A stable isotope study of Cerro del Almirez, Spain

Science.gov (United States)

Alt, Jeffrey C.; Garrido, Carlos J.; Shanks, Wayne C.; Turchyn, Alexandra; Padrón-Navarta, José Alberto; López Sánchez-Vizcaíno, Vicente; Gómez Pugnaire, María Teresa; Marchesi, Claudio

2012-01-01

We use the concentrations and isotope compositions of water, carbon, and sulfur in serpentinites and their dehydration products to trace the cycling of volatiles during subduction. Antigorite serpentinites from the Cerro del Almirez complex, Spain, contain 9–12 wt.% H2O and 910 ± 730 ppm sulfur, and have bulk δ18O values of 8.6 ± 0.4‰, δD = − 54 ± 5‰, and δ34S = 5.0‰, consistent with serpentinization at temperatures of ~ 200 °C by seawater hydrothermal fluids in a seafloor setting. The serpentinites were dehydrated to chlorite–harzburgite (olivine + orthopyroxene + chlorite) at 700 °C and 1.6–1.9 GPa during subduction metamorphism, resulting in loss of water, and sulfur. The chlorite–harzburgites contain 5.7 ± 1.9 wt.% H2O, and have bulk δ18O = 8.0 ± 0.9‰, and δD = − 77 ± 11‰. The rocks contain 650 ± 620 ppm sulfur having δ34S = 1.2‰. Dehydration of serpentinite resulted in loss of 5 wt.% H2O having δ18O = 8–10‰ and δD = − 27 to − 65‰, and loss of 260 ppm sulfur as sulfate, having δ34S = 14.5‰. The contents and δ13C of total carbon in the two rock types overlap, with a broad trend of decreasing carbon contents and δ13C from ~ 1300 to 200 ppm and − 9.6 to − 20.2‰. This reflects mixing between reduced carbon in the rocks (210 ppm, δ13C ≈ − 26‰) and seawater-derived carbonate (δ13C ≈ − 1‰). Our results indicate: 1) Serpentinized oceanic peridotites carry significant amounts of isotopically fractionated water, carbon and sulfur into subduction zones; 2) Subduction of serpentinites to high P and T results in loss of water, and sulfur, which can induce melting and contribute to 18O, D, and 34S enrichments and oxidation of the sub-arc mantle wedge; and 3) Isotopically fractionated water, carbon, and sulfur in serpentinite dehydration products are recycled deeper into the mantle where they can contribute to isotope heterogeneities and may be significant for volatile budgets of the deep Earth.

Hydrothermal synthesis of nanostructured titania

International Nuclear Information System (INIS)

Yoshito, Walter Kenji; Ferreira, Nildemar A.M.; Rumbao, Ana Carolina S. Coutinho; Lazar, Dolores R.R.; Ussui, Valter

2009-01-01

Titania ceramics have many applications due to its surface properties and, recently, its nanostructured compounds, prepared by hydrothermal treatments, have been described to improve these properties. In this work, commercial titanium dioxide was treated with 10% sodium hydroxide solution in a pressurized reactor at 150°C for 24 hours under vigorous stirring and then washed following two different procedures. The first one consisted of washing with water and ethanol and the second with water and hydrochloric acid solution (1%). Resulting powders were characterized by X-ray diffraction, N 2 gas adsorption and field emission gun scanning and transmission electronic microscopy. Results showed that from an original starting material with mainly rutile phase, both anatase and H 2 Ti 3 O 7 phase could be identified after the hydrothermal treatment. Surface area of powders presented a notable increase of one order of magnitude and micrographs showed a rearrangement on the microstructure of powders. (author)

Zinc stannate nanostructures: hydrothermal synthesis

International Nuclear Information System (INIS)

Baruah, Sunandan; Dutta, Joydeep

2011-01-01

Nanostructured binary semiconducting metal oxides have received much attention in the last decade owing to their unique properties rendering them suitable for a wide range of applications. In the quest to further improve the physical and chemical properties, an interest in ternary complex oxides has become noticeable in recent times. Zinc stannate or zinc tin oxide (ZTO) is a class of ternary oxides that are known for their stable properties under extreme conditions, higher electron mobility compared to its binary counterparts and other interesting optical properties. The material is thus ideal for applications from solar cells and sensors to photocatalysts. Among the different methods of synthesizing ZTO nanostructures, the hydrothermal method is an attractive green process that is carried out at low temperatures. In this review, we summarize the conditions leading to the growth of different ZTO nanostructures using the hydrothermal method and delve into a few of its applications reported in the literature. (topical review)

Hydrothermal synthesis of nanostructured titania

International Nuclear Information System (INIS)

Yoshito, W.K.; Ferreira, N.A.M.; Lazar, D.R.R.; Ussui, V.; Rumbao, A.C.S.

2011-01-01

Titania ceramics have many applications due to its surface properties and, recently, its nanostructured compounds, prepared by hydrothermal treatments, have been described to improve these properties. In this work, commercial titanium dioxide was treated with 10% sodium hydroxide solution in a pressurized reactor at 150 deg C for 24 hours under vigorous stirring and then washed following two different procedures. The first one consisted of washing with water and ethanol and the second with water and hydrochloric acid solution (1%). Resulting powders were characterized by X-ray diffraction, N 2 gas adsorption and field emission gun scanning and transmission electronic microscopy. Results showed that from an original starting material with mainly rutile phase, both anatase and H 2 Ti 3 O 7 phase could be identified after the hydrothermal treatment. Surface area of powders presented a notable increase of one order of magnitude and micrographs showed a rearrangement on the microstructure of powders. (author)

Hydrothermal carbonization of biomass waste under low temperature condition

Directory of Open Access Journals (Sweden)

Putra Herlian Eriska

2018-01-01

Full Text Available In this paper, the use of banana peel for energy purposes was investigated. Banana peel is a lignocellulosic waste since it is the most widely produced and consumed fruit in Indonesia. Among the others, hydrothermal carbonization (HTC was chosen as alternative themochemical process, suitable for high moisture biomass. Through a 1 L stirred reactor, hydrothermal treatments were performed under low temperature condition (190, 210 and 230 °C, residence times (30 and 60 min, and biomass to water ratio (1:3, 1:5, and 1:10. Three of product were collected from the process with primary material balance. Solid phase (hydrochar was evaluated in terms of calorific value, proximate and ultimate analysis. The results suggested that the hydrothermal carbonization of banana peel gave high heating value (HHV of 20.09 MJ/kg for its char after dried naturally.

Measurement of radon (222Rn) in thermal water of Cerro Pacho, Coatepeque Caldera, El Salvador

International Nuclear Information System (INIS)

Rodriguez, Ramiro; Olmos, Rodolfo; Payes, Julio

2014-01-01

Radon ( 222 Rn) concentrations and radio ( 226 Ra) evaluation dissolved in thermal spring water are presented to contribute to volcanic monitoring, adapting and validating analytical methodology. Sampling was discreet and monthly type, from June 2011 to March 2013. Radon levels was vary from 0,48 ± 0,1 to 1,54 ± 0,13 Bq/L (average 1,24 Bq/L). Radio concentrations were evaluated from January to December 2012. The values found do not show radio detection confidence level of 95% with respect to the detection limit (4,2 mBq/L). A decrease in radon was observed possibly related to subduction anomalies with epicenter at 143 km from Cerro Pacho, in November 2012, volcanic seismicity was also recorded 40 days before with increments of microearthquakes and volcano-tectonic activity. The first measurements of radon in thermal water have been generated, establishing the baseline to evaluate the behavior of these radionuclides with seismic activity. (author) [es

A high-temperature hydrothermal deposit on the East Pacific Rise near 70N

International Nuclear Information System (INIS)

Boulegue, J.; Stouff, P.; Perseil, E.A.; Bernat, M.; Dupre, B.; Francheteau, J.

1984-01-01

A SEABEAM survey of the East Pacific Rise (EPR) led to the selection of several sites having structural characteristics favorable for hydrothermal activity. Dredging of such an area located at 7 0 N on the EPR resulted in the recovery of sulfides, oxides and fresh basalt. Chemical analyses and isotopic compositions showed that the recovered pyrites were probably precipitated directly from hot vent hydrothermal waters. Chemical analyses and isotopic composition of manganese-iron oxides indicated that they too were of hydrothermal origin. 210 Pb/Pb measurements yielded ages of 90 +- 10 years for the deposits. This site may still be undergoing hydrothermal activity. (orig.)

Mild hydrothermal treatment to prepare highly dispersed multi-walled carbon nanotubes

International Nuclear Information System (INIS)

Zhang Li; Hashimoto, Yoshio; Taishi, Toshinori; Ni Qingqing

2011-01-01

Multi-walled carbon nanotubes (MWCNTs) with improved dispersion property have been prepared by a mild and fast hydrothermal treatment. The hydrothermal process avoids using harsh oxidants and organic solvents, which is environmental friendly and greatly decreases the damage to intrinsic structure of MWCNTs. The modified MWCNTs were highly soluble in polar solvents such as water, ethanol and dimethylformamide. Morphological observation by TEM indicated that the diameter and inherent structure were well reserved in modified MWCNTs. X-ray photoelectron spectroscopy and Raman spectroscopy were used to quantify functional groups created on the MWCNT surface, and to determine rational parameters of hydrothermal process.

The role of magmas in the formation of hydrothermal ore deposits

Science.gov (United States)

Hedenquist, Jeffrey W.; Lowenstern, Jacob B.

1994-01-01

Magmatic fluids, both vapour and hypersaline liquid, are a primary source of many components in hydrothermal ore deposits formed in volcanic arcs. These components, including metals and their ligands, become concentrated in magmas in various ways from various sources, including subducted oceanic crust. Leaching of rocks also contributes components to the hydrothermal fluid—a process enhanced where acid magmatic vapours are absorbed by deeply circulating meteoric waters. Advances in understanding the hydrothermal systems that formed these ore deposits have come from the study of their active equivalents, represented at the surface by hot springs and volcanic fumaroles.

Hydrothermal liquefaction of microalgae's for bio oil production

DEFF Research Database (Denmark)

Toor, Saqib; Reddy, Harvind; Deng, Shuguang

process water for algae cultivation. GC-MS, elemental analyzer, calorimeter and nutrient analysis were used to analyze bio-crude, lipid-extracted algae and water samples produced in the hydrothermal liquefaction process. The highest bio-oil yield of 46% was obtained on Nannochloropsis salina at 310 °C...... and 107 bar. For Spirulina platensis algae sample, the highest bio-oil yield is 38% at 350 °C and 195 bar. Preliminary data also indicate that a lipid-extracted algae solid residue sample obtained in the hydrothermal liquefaction process contains a high level of proteins...

Quantitative characterization of the aqueous fraction from hydrothermal liquefaction of algae

Energy Technology Data Exchange (ETDEWEB)

Maddi, Balakrishna; Panisko, Ellen; Wietsma, Thomas; Lemmon, Teresa; Swita, Marie; Albrecht, Karl; Howe, Daniel

2016-10-01

Aqueous streams generated from hydrothermal liquefaction contain approximately 30% of the total carbon present from the algal feed. Hence, this aqueous carbon must be utilized to produce liquid fuels and/or specialty chemicals for economic sustainability of hydrothermal liquefaction on industrial scale. In this study, aqueous fractions produced from the hydrothermal liquefaction of fresh water and saline water algal cultures were analyzed using a wide variety of analytical instruments to determine their compositional characteristics. This study will also inform researchers designing catalysts for down-stream processing such as high-pressure catalytic conversion of organics in aqueous phase, catalytic hydrothermal gasification, and biological conversions. Organic chemical compounds present in all eight aqueous fractions were identified using two-dimensional gas chromatography equipped with time-of-flight mass spectrometry. Identified compounds include organic acids, nitrogen compounds and aldehydes/ketones. Conventional gas chromatography and liquid chromatography methods were utilized to quantify the identified compounds. Inorganic species in the aqueous stream of hydrothermal liquefaction of algae were identified using ion chromatography and inductively coupled plasma optical emission spectrometer. The concentrations of organic chemical compounds and inorganic species are reported. The amount quantified carbon ranged from 45 to 72 % of total carbon in the aqueous fractions.

Hydrothermal treatment of municipal solid waste incineration fly ash for dioxin decomposition

International Nuclear Information System (INIS)

Hu, Yuyan; Zhang, Pengfei; Chen, Dezhen; Zhou, Bin; Li, Jianyi; Li, Xian-wei

2012-01-01

Highlights: ► The first study to apply Fe-sulfate in hydrothermal treatment of municipal solid waste incineration fly ash for dioxin decomposition. ► The first study to comprehensively evaluate the effect of hydrothermal treatment on dioxin decomposition and heavy metal stabilization in municipal solid waste incineration fly ash. ► Gaussian software chemical computational simulation was performed to investigate the mechanism of dioxin decomposition based on quantum chemistry calculation, and to support the experimental data by the calculation results. - Abstract: Hydrothermal treatment of MSWI fly ash was performed in this paper with a purpose to reduce its dioxin content. First a hydrothermal reactor was set up with a mixture of ferric sulphate and ferrous sulphate serviced as the reactant, then the effects caused by reaction conditions such as reaction temperature, pre-treatment by water-washing and reactant dosage were checked; the results showed that as a promising technology, hydrothermal treatment exhibited considerable high efficiencies in decomposition of PCDDs/PCDFs and good stabilization of heavy metals as well. Experimental results also showed that for dioxin destruction, higher reaction temperature is the most important influencing factor followed by Fe addition, and pre-treatment of raw fly ash by water-washing increased the destruction efficiencies of dioxins only very slightly. Finally with help of Gaussian software chemical computational simulation was performed to investigate the mechanism of dioxin decomposition based on quantum chemistry calculation. The calculation results were supported by the experimental data. The leaching toxicities of hydrothermal products were higher than upper limits defined in the latest Chinese standard GB 16889-2008 for sanitary landfill disposal, thus an auxiliary process is suggested after the hydrothermal treatment for heavy metal stabilization.

ESR dating of submarine hydrothermal activities using barite in sulfide deposition

Science.gov (United States)

Toyoda, S.; Fujiwara, T.; Ishibashi, J.; Isono, Y.; Uchida, A.; Takamasa, A.; Nakai, S.

2012-12-01

The temporal change of submarine hydrothermal activities has been an important issue in the aspect of the evolution of hydrothermal systems which is related with ore formation (Urabe, 1995) and biological systems sustained by the chemical species arising from hydrothermal activities (Macdonald et al., 1980). Determining the ages of the hydrothermal deposit will provide essential information on such studies. Dating methods using disequilibrium between radioisotopes such as U-Th method (e.g. You and Bickle, 1998), 226}Ra-{210Pb and 228}Ra-{228Th method (e.g. Noguchi et al., 2011) have been applied to date submarine hydrothermal deposits. ESR (electron spin resonance) dating method is commonly applied to fossil teeth, shells, and quartz of Quaternay period where the natural accumulated dose is obtained from the intensities of the ESR signals which are created by natural radiation. The natural dose is divided by the dose rate to the mineral/sample to deduce the age. Okumura et al., (2010) made the first practical application of ESR (electron spin resonance) dating technique to a sample of submarine hydrothermal barite (BaSO4) to obtain preliminary ages, where Kasuya et al. (1991) first pointed out that barite can be used for ESR dating. Knowing that ESR dating of barite is promising, in this paper, we will present how we have investigated each factor that contributes ESR dating of barite in submarine hydrothermal sulfide deposition. (1) The best ESR condition for measuring the SO3- signal in barite is with the microwave power of 1mW and modulation amplitude of 0.1mT. (2) As results of heating experiments, the signal was found to be stable for the dating age range of several thousands. (3) 226Ra replacing Ba in barite is the source of the radiation. The amount of radioactive elements in sulfide mineral surrounding barite is negligible. (4) The external radiation from the sea water is negligible even in the submarine hydrothermal area where the radiation level is much

Volcano-hydrothermal energy research at white Island, New Zealand

International Nuclear Information System (INIS)

Allis, R.G.

1994-01-01

This paper presents the White Island (New Zealand) volcano-hydrothermal research project by the N.Z. DSIR and the Geological Survey of Japan, which is investigating the coupling between magmatic and geothermal systems. The first phase of this investigation is a geophysical survey of the crater floor of the andesite volcano, White Island during 1991/1992, to be followed by drilling from the crater floor into the hydrothermal system. (TEC). 4 figs., 8 refs

Comparative analyses of the bacterial community of hydrothermal deposits and seafloor sediments across Okinawa Trough

Science.gov (United States)

Wang, Long; Yu, Min; Liu, Yan; Liu, Jiwen; Wu, Yonghua; Li, Li; Liu, Jihua; Wang, Min; Zhang, Xiao-Hua

2018-04-01

As an ideal place to study back-arc basins and hydrothermal eco-system, Okinawa Trough has attracted the interests of scientists for decades. However, there are still no in-depth studies targeting the bacterial community of the seafloor sediments and hydrothermal deposits in Okinawa Trough. In the present study, we reported the bacterial community of the surface deposits of a newly found hydrothermal field in the southern Okinawa Trough, and the horizontal and vertical variation of bacterial communities in the sediments of the northern Okinawa Trough. The hydrothermal deposits had a relatively high 16S rRNA gene abundance but low bacterial richness and diversity. Epsilonproteobacteria and Bacteroidetes were predominant in hydrothermal deposits whereas Deltaproteobacteria, Gammaproteobacteria and Chloroflexi were abundant across all samples. The bacterial distribution in the seafloor of Okinawa Trough was significantly correlated to the content of total nitrogen, and had consistent relationship with total carbon. Gradual changes of sulfur-oxidizing bacteria were found with the distance away from hydrothermal fields, while the hydrothermal activity did not influence the distribution of the major clades of sulfate-reducing bacteria. Higher abundance of the sulfur cycle related genes (aprA and dsrB), and lower abundance of the bacterial ammonia-oxidizing related gene (amoA) were quantified in hydrothermal deposits. In addition, the present study also compared the inter-field variation of Epsilonproteobacteria among multi-types of hydrothermal vents, revealing that the proportion and diversity of this clade were quite various.

Catalytic Hydrothermal Conversion of Wet Biomass Feedstocks and Upgrading – Process Design and Optimization

DEFF Research Database (Denmark)

Hoffmann, Jessica; Toor, Saqib; Rosendahl, Lasse

Liquid biofuels will play a major role for a more sustainable energy system of the future. The CatLiq® process is a 2nd generation biomass conversion process that is based on hydrothermal liquefaction. Hydrothermal liquefaction offers a very efficient and feedstock flexible way of converting...... biomass to bio-oil. Bio-oils from hydrothermal liquefaction are characterised by their high feedstock flexibility. Upgrading of complete bio-oils derived from hydrothermal conversion has not yet been extensively studied. Purpose of this work is to reduce the oxygen content of the bio-oil to improve...

Electron microscopy study of microbial mat in the North Fiji basin hydrothermal vent

Science.gov (United States)

Park, H.; Kim, J. W.; Lee, J. W.

2017-12-01

Hydrothermal vent systems consisting of hydrothermal vent, hydrothermal sediment and microbial mat are widely spread around the ocean, particularly spreading axis, continental margin and back-arc basin. Scientists have perceived that the hydrothermal systems, which reflect the primeval earth environment, are one of the best places to reveal the origin of life and extensive biogeochemical process of microbe-mineral interaction. In the present study multiline of analytical methods (X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM)) were utilized to investigate the mineralogy/chemistry of microbe-mineral interaction in hydrothermal microbial mat. Microbial mat samples were recovered by Canadian scientific submersible ROPOS on South Pacific North Fiji basin KIOST hydrothermal vent expedition 1602. XRD analysis showed that red-colored microbial mat contains Fe-oxides and Fe-oxyhydroxides. Various morphologies of minerals in the red-colored microbial mat observed by SEM are mainly showed sheath shaped, resembled with Leptothrix microbial structure, stalks shaped, similar with Marioprofundus microbial structure and globule shaped microbial structures. They are also detected with DNA analysis. The cross sectional observation of microbial structures encrusted with Fe-oxide and Fe-oxyhydroxide at a nano scale by Transmission Electron Microscopy (TEM) and Focused Ion Beam (FIB) technique was developed to verify the structural/biogeochemical properties in the microbe-mineral interaction. Systematic nano-scale measurements on the biomineralization in the microbial mat leads the understandings of biogeochemical environments around the hydrothermal vent.

The Final Days of Paracas in Cerro del Gentil, Chincha Valley, Peru

Science.gov (United States)

2016-01-01

This article describes and analyzes a highly significant archaeological context discovered in a late Paracas (400–200 BCE) sunken patio in the monumental platform mound of Cerro Gentil, located in the Chincha Valley, Peru. This patio area was used for several centuries for ritual activities, including large-scale feasting and other public gatherings. At one point late in this historical sequence people deposited a great deal of objects in what is demonstrably a single historical event. This was quickly followed by a series of minor events stratigraphically immediately above this larger event. This entire ritual process included the consumption of liquids and food, and involved the offering of whole pottery, pottery fragments, botanical remains, bone, lithics, baskets, pyro-engraved gourds, mummies, and other objects. We interpret these events as an “abandonment ceremony” or “termination ritual” during the late Paracas period, one that may have lasted for weeks or even months. The subsequent Topará occupation at the site (ca. 200 BCE- AD 100) involved the architectural enhancement of the mound area, but the pattern of use of the patio itself ended. Such a termination ritual signals a reorganization in the regional political structure of Paracas society. PMID:27144824

The importance of shallow hydrothermal island arc systems in ocean biogeochemistry

NARCIS (Netherlands)

Hawkes, J.A.; Connelly, D.P.; Rijkenberg, M.J.A.; Achterberg, E.P.

2014-01-01

Hydrothermal venting often occurs at submarine volcanic calderas on island arc chains, typically at shallower depths than mid-ocean ridges. The effect of these systems on ocean biogeochemistry has been under-investigated to date. Here we show that hydrothermal effluent from an island arc caldera was

Metal mobilisation in hydrothermal sediments at the TAG Hydrothermal Field (MAR, 26°N)

Science.gov (United States)

Dutrieux, A. M.; Lichtschlag, A.; Martins, S.; Barriga, F. J.; Petersen, S.; Murton, B. J.

2017-12-01

Metalliferous sediments in the vicinity of hydrothermal systems are enriched in base metals, but few studies have addressed their potential as mineral resources. These metalliferous sediments have been accumulated by different processes and reflect modifications of the primary mineral deposits by: oxidation of the chimney materials, in situ precipitation of low-temperature minerals and mass wasting. To understand the post-formation processes in metalliferous sediments, we investigated sub-seafloor metal mobilisation in different geological environments. This presentation focuses on the TAG Hydrothermal Field (Mid-Atlantic Ridge, 26°N) and explores sediment and pore water compositions using ICP-MS and ICP-OES. We use reactive transport modelling to interpret the degree of metal remobilisation and to identify the most important geochemical reactions in the different sediments. The pore water concentrations measured in sediments above inactive sulphide mounds present constant major elements composition that indicates this environment is dominated by complete exchange with seawater. The sediments, that are mainly composed of hematite and goethite formed during the oxidation of sulphides, have low Cu concentrations (sediments and capped by more recent sediment slumping. In the depositionary channels, pore waters show metal concentrations affected by diagenesis and redox-sensitive metals are released at depth (e.g. Mn2+ and Cu2+). The leaching of the primary sulphides (e.g. deprecated grains of chalcopyrite), and metal mobilisation lead to an enrichment of Cu and Zn at shallower depth. Here, some stratigraphic horizons scavenge metallic cations back into solid phases and form Mn-oxide crusts between 30 and 60 cm, in which Cu concentrations also increase. Our results demonstrate that metal mobilisation differs depending on the geological environment and their related accumulation processes, causing the absence of Cu on the top of inactive hydrothermal mounds but enriched

Measurements of air contaminants during the Cerro Grande fire at Los Alamos National Laboratory

Energy Technology Data Exchange (ETDEWEB)

Eberhart, Craig

2010-08-01

Ambient air sampling for radioactive air contaminants was continued throughout the Cerro Grande fire that burned part of Los Alamos National Laboratory. During the fire, samples were collected more frequently than normal because buildup of smoke particles on the filters was decreasing the air flow. Overall, actual sampling time was 96% of the total possible sampling time for the May 2000 samples. To evaluate potential human exposure to air contaminants, the samples were analyzed as soon as possible and for additional specific radionuclides. Analyses showed that the smoke from the fire included resuspended radon decay products that had been accumulating for many years on the vegetation and the forest floor that burned. Concentrations of plutonium, americium, and depleted uranium were also measurable, but at locations and concentrations comparable to non-fire periods. A continuous particulate matter sampler measured concentrations that exceeded the National Ambient Air Quality Standard for PM-10 (particles less than 10 micrometers in diameter). These high concentrations were caused by smoke from the fire when it was close to the sampler.

Genifuel Hydrothermal Processing Bench Scale Technology Evaluation Project (WE&RF Report LIFT6T14)

Science.gov (United States)

Hydrothermal Liquefaction (HTL) and Catalytic Hydrothermal Gasification (CHG) proof-of-concept bench-scale tests were performed to assess the potential of the Genifuel hydrothermal process technology for handling municipal wastewater sludge. HTL tests were conducted at 300-350◦C ...

Basin scale permeability and thermal evolution of a magmatic hydrothermal system

Science.gov (United States)

Taron, J.; Hickman, S. H.; Ingebritsen, S.; Williams, C.

2013-12-01

Large-scale hydrothermal systems are potentially valuable energy resources and are of general scientific interest due to extreme conditions of stress, temperature, and reactive chemistry that can act to modify crustal rheology and composition. With many proposed sites for Enhanced Geothermal Systems (EGS) located on the margins of large-scale hydrothermal systems, understanding the temporal evolution of these systems contributes to site selection, characterization and design of EGS. This understanding is also needed to address the long-term sustainability of EGS once they are created. Many important insights into heat and mass transfer within natural hydrothermal systems can be obtained through hydrothermal modeling assuming that stress and permeability structure do not evolve over time. However, this is not fully representative of natural systems, where the effects of thermo-elastic stress changes, chemical fluid-rock interactions, and rock failure on fluid flow and thermal evolution can be significant. The quantitative importance of an evolving permeability field within the overall behavior of a large-scale hydrothermal system is somewhat untested, and providing such a parametric understanding is one of the goals of this study. We explore the thermal evolution of a sedimentary basin hydrothermal system following the emplacement of a magma body. The Salton Sea geothermal field and its associated magmatic system in southern California is utilized as a general backdrop to define the initial state. Working within the general framework of the open-source scientific computing initiative OpenGeoSys (www.opengeosys.org), we introduce full treatment of thermodynamic properties at the extreme conditions following magma emplacement. This treatment utilizes a combination of standard Galerkin and control-volume finite elements to balance fluid mass, mechanical deformation, and thermal energy with consideration of local thermal non-equilibrium (LTNE) between fluids and solids

First Survey For Submarine Hydrothermal Vents In NE Sulawesi, Indonesia

Science.gov (United States)

McConachy, T.; Binns, R.; Permana, H.

2001-12-01

The IASSHA-2001 cruise (Indonesia-Australia Survey for Submarine Hydrothermal Activity) was successfully conducted from June 1 to June 29 on board Baruna Jaya VIII. Preliminary results are reported of the first expedition to locate and study submarine hydrothermal activity in north east Sulawesi. Leg A focussed on Tomini Bay, a virtually unexplored Neogene sedimentary basin. Its objective was to test whether modern sediment-hosted hydrothermal activity occurred on the sea floor. The results of new bathymetric mapping, sediment coring and CTD/transmissometer hydrocasts negate the likely presence in central Tomini Bay of large-scale modern analogues of hydrothermal massive sulfide environments involving hydrothermal venting of basinal or magma-derived fluids into reduced sediments. It is possible that the "heat engine" required to drive circulation of basinal and hydrothermal fluids is today too weak. Surveys around Colo volcano indicate that it may be in its final stage of evolution. Leg B studied the arc and behind-arc sectors of the Sangihe volcanic island chain extending northwards from Quaternary volcanoes on the northeastern tip of Sulawesi's North Arm, near Manado. West of the main active chain and extending northwards from Manado there is a subparallel ridge surmounted by a number of high (>2000 m) seamounts of uncertain age. Fifteen relatively high-standing submarine edifices were crossed during this leg, of which nine were tested for hydrothermal activity by hydrocast and dredging. Eight sites were known from previous bathymetric surveys, and seven are new discoveries made by narrow-beam or multibeam echo sounding. Two submarine edifices at least 1000 m high were discovered in the strait immediately north of Awu volcano on Sangihe Island. One, with crest at 206 m, is surrounded by a circular platform 300m deep which we infer to be a foundered fringing reef to a formerly emergent island. The other, lacking such a platform, appears relatively young and may be

Hydrothermal Synthesis and Electrochemical Properties of Spherical α-MnO2 for Supercapacitors.

Science.gov (United States)

Chen, Ya; Qin, Wenqing; Fan, Ruijuan; Wang, Jiawei; Chen, Baizhen

2015-12-01

In the present work, spherical α-MnO2 with a high specific capacitance was synthesized by a two-step hydrothermal route. MnCO3 precursors were first prepared by a common hydrothermal method, and then converted to α-MnO2 via a hydrothermal reaction between the precursors and KMnO4 solutions. The effects of hydrothermal temperature on the morphology, crystal structure and specific area of the MnO2 were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD) and BET measurements. The electrochemical capacitive properties of the manganese dioxides with different morphologies and structures were evaluated by cyclic voltammetry and galvonostatic charge-discharge tests. The results showed that the temperature in the second hydrothermal step had prominent impact on the capacitive properties of a-MnO2. The MnO2 synthesized at 150 *C exhibited a highest specific capacitance of 328.4 Fx g(-1) at a charge-discharge current density of 100 mA x g(-1).

Improving production of volatile fatty acids from food waste fermentation by hydrothermal pretreatment.

Science.gov (United States)

Yin, Jun; Wang, Kun; Yang, Yuqiang; Shen, Dongsheng; Wang, Meizhen; Mo, Han

2014-11-01

Food waste (FW) was pretreated by a hydrothermal method and then fermented for volatile fatty acid (VFAs) production. The soluble substance in FW increased after hydrothermal pretreatment (⩽200 °C). Higher hydrothermal temperature would lead to mineralization of the organic compounds. The optimal temperature for organic dissolution was 180 °C, at which FW dissolved 42.5% more soluble chemical oxygen demand than the control. VFA production from pretreated FW fermentation was significantly enhanced compared with the control. The optimal hydrothermal temperature was 160 °C with a VFA yield of 0.908 g/g VSremoval. Butyrate and acetate were the prevalent VFAs followed by propionate and valerate. FW fermentation was inhibited after 200 °C pretreatment. The VFAs were extracted from the fermentation broth by liquid-liquid extraction. The VFA recovery was 50-70%. Thus, 0.294-0.411 g VFAs could be obtained per gram of hydrothermally pretreated FW (in dry weight) by this method. Copyright © 2014 Elsevier Ltd. All rights reserved.

Nanogeochemistry of hydrothermal magnetite

Science.gov (United States)

Deditius, Artur P.; Reich, Martin; Simon, Adam C.; Suvorova, Alexandra; Knipping, Jaayke; Roberts, Malcolm P.; Rubanov, Sergey; Dodd, Aaron; Saunders, Martin

2018-06-01

Magnetite from hydrothermal ore deposits can contain up to tens of thousands of parts per million (ppm) of elements such as Ti, Si, V, Al, Ca, Mg, Na, which tend to either structurally incorporate into growth and sector zones or form mineral micro- to nano-sized particles. Here, we report micro- to nano-structural and chemical data of hydrothermal magnetite from the Los Colorados iron oxide-apatite deposit in Chile, where magnetite displays both types of trace element incorporation. Three generations of magnetites (X-Z) were identified with concentrations of minor and trace elements that vary significantly: SiO2, from below detection limit (bdl) to 3.1 wt%; Al2O3, 0.3-2.3 wt%; CaO, bdl-0.9 wt%; MgO, 0.02-2.5 wt%; TiO2, 0.1-0.4 wt%; MnO, 0.04-0.2 wt%; Na2O, bdl-0.4 wt%; and K2O, bdl-0.4 wt%. An exception is V2O3, which is remarkably constant, ranging from 0.3 to 0.4 wt%. Six types of crystalline nanoparticles (NPs) were identified by means of transmission electron microscopy in the trace element-rich zones, which are each a few micrometres wide: (1) diopside, (2) clinoenstatite; (3) amphibole, (4) mica, (5) ulvöspinel, and (6) Ti-rich magnetite. In addition, Al-rich nanodomains, which contain 2-3 wt% of Al, occur within a single crystal of magnetite. The accumulation of NPs in the trace element-rich zones suggest that they form owing to supersaturation from a hydrothermal fluid, followed by entrapment during continuous growth of the magnetite surface. It is also concluded that mineral NPs promote exsolution of new phases from the mineral host, otherwise preserved as structurally bound trace elements. The presence of abundant mineral NPs in magnetite points to a complex incorporation of trace elements during growth, and provides a cautionary note on the interpretation of micron-scale chemical data of magnetite.

Comparison on electrically pumped random laser actions of hydrothermal and sputtered ZnO films

International Nuclear Information System (INIS)

Wang, Canxing; Jiang, Haotian; Li, Yunpeng; Ma, Xiangyang; Yang, Deren

2013-01-01

Random lasing (RL) in polycrystalline ZnO films is an intriguing research subject. Here, we have comparatively investigated electrically pumped RL behaviors of two metal-insulator-semiconductor structured devices using the hydrothermal and sputtered ZnO films as the semiconductor components, i.e., the light-emitting layers, respectively. It is demonstrated that the device using the hydrothermal ZnO film exhibits smaller threshold current and larger output optical power of the electrically pumped RL. The morphological characterization shows that the hydrothermal ZnO film is somewhat porous and is much rougher than the sputtered one, suggesting that in the former stronger multiple light scattering can occur. Moreover, the photoluminescence characterization indicates that there are fewer defects in the hydrothermal ZnO film than in the sputtered one, which means that the photons can pick up larger optical gain through stimulated emission in the hydrothermal ZnO film. Therefore, it is believed that the stronger multiple light scattering and larger optical gain contribute to the improved performance of the electrically pumped RL from the device using the hydrothermal ZnO film

Hydrothermal synthesis of magnetic reduced graphene oxide sheets

International Nuclear Information System (INIS)

Shen, Jianfeng; Shi, Min; Ma, Hongwei; Yan, Bo; Li, Na; Ye, Mingxin

2011-01-01

Graphical abstract: An environmental friendly and efficient route for preparation of magnetic reduced graphene oxide composite with a one-step hydrothermal method was demonstrated. The reducing process was accompanied by generation of magnetic nanoparticles. Highlights: → A one-step hydrothermal method for preparation of MN-CCG was demonstrated. → Glucose was used as the 'green' reducing agent. → The reducing process was accompanied by generation of magnetic nanoparticles. → The prepared MN-CCG is highly water suspendable and sensitive to magnetic field. -- Abstract: We demonstrated an environmental friendly and efficient route for preparation of magnetic reduced graphene oxide composite (MN-CCG). Glucose was used as the reducing agent in this one-step hydrothermal method. The reducing process was accompanied by generation of magnetic nanoparticles. The structure and composition of the nanocomposite was confirmed by Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, thermal gravimetric analysis, atomic force microscopy and transmission electron microscopy. It was found that the prepared MN-CCG is highly water suspendable and sensitive to magnetic field.

Hydro-Thermal Fatigue Resistance Measurements on Polymer Interfaces

Science.gov (United States)

Gurumurthy, Charan K.; Kramer, Edward J.; Hui, Chung-Yuen

1998-03-01

We have developed a new technique based on a fiber optic displacement sensor for rapid determination of hydro-thermal fatigue crack growth rate per cycle (da/dN) of an epoxy/polyimide interface used in flip chip attach microelectronic assembly. The sample is prepared as a trilayered cantilever beam by capillary flow of the epoxy underfill over a polyimide coated metallic beam. During hydro-thermal cycling the crack growth along the interface (from the free end) changes the displacement of this end of the beam and we measure the free end displacement at the lowest temperature in each hydro-thermal cycle. The change in beam displacement is then converted into crack growth rate (da/dN). da/dN depends on the maximum change in the strain energy release rate of the crack and the phase angle in each cycle. The relation between da/dN and maximum strain energy release rate characterizes the fatigue crack growth resistance of the interface. We have developed and used a simple model anhydride cured and a commercially available PMDA/ODA passivation for this study.

Process characteristics for microwave assisted hydrothermal carbonization of cellulose.

Science.gov (United States)

Zhang, Junting; An, Ying; Borrion, Aiduan; He, Wenzhi; Wang, Nan; Chen, Yirong; Li, Guangming

2018-07-01

The process characteristics of microwave assisted hydrothermal carbonization of cellulose was investigated and a first order kinetics model based on carbon concentration was developed. Chemical properties analysis showed that comparing to conventional hydrothermal carbonization, hydrochar with comparable energy properties can be obtained with 5-10 times decrease in reaction time with assistance of microwave heating. Results from kinetics study was in great agreement with experimental analysis, that they both illustrated the predominant mechanism of the reaction depend on variations in the reaction rates of two co-existent pathways. Particularly, the pyrolysis-like intramolecular dehydration reaction was proved to be the predominant mechanism for hydrochar generation under high temperatures. Finally, the enhancement effects of microwave heating were reflected under both soluble and solid pathways in this research, suggesting microwave-assisted hydrothermal carbonization as a more attracting method for carbon-enriched hydrochar recovery. Copyright © 2018 Elsevier Ltd. All rights reserved.

Hydrothermal impacts on trace element and isotope ocean biogeochemistry.

Science.gov (United States)

German, C R; Casciotti, K A; Dutay, J-C; Heimbürger, L E; Jenkins, W J; Measures, C I; Mills, R A; Obata, H; Schlitzer, R; Tagliabue, A; Turner, D R; Whitby, H

2016-11-28

Hydrothermal activity occurs in all ocean basins, releasing high concentrations of key trace elements and isotopes (TEIs) into the oceans. Importantly, the calculated rate of entrainment of the entire ocean volume through turbulently mixing buoyant hydrothermal plumes is so vigorous as to be comparable to that of deep-ocean thermohaline circulation. Consequently, biogeochemical processes active within deep-ocean hydrothermal plumes have long been known to have the potential to impact global-scale biogeochemical cycles. More recently, new results from GEOTRACES have revealed that plumes rich in dissolved Fe, an important micronutrient that is limiting to productivity in some areas, are widespread above mid-ocean ridges and extend out into the deep-ocean interior. While Fe is only one element among the full suite of TEIs of interest to GEOTRACES, these preliminary results are important because they illustrate how inputs from seafloor venting might impact the global biogeochemical budgets of many other TEIs. To determine the global impact of seafloor venting, however, requires two key questions to be addressed: (i) What processes are active close to vent sites that regulate the initial high-temperature hydrothermal fluxes for the full suite of TEIs that are dispersed through non-buoyant hydrothermal plumes? (ii) How do those processes vary, globally, in response to changing geologic settings at the seafloor and/or the geochemistry of the overlying ocean water? In this paper, we review key findings from recent work in this realm, highlight a series of key hypotheses arising from that research and propose a series of new GEOTRACES modelling, section and process studies that could be implemented, nationally and internationally, to address these issues.This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'. © 2015 The Authors.

Synthesis of ZrO{sub 2} nanoparticles by hydrothermal treatment

Energy Technology Data Exchange (ETDEWEB)

Machmudah, Siti, E-mail: machmudah@chem-eng.its.ac.id; Widiyastuti, W., E-mail: machmudah@chem-eng.its.ac.id; Prastuti, Okky Putri, E-mail: machmudah@chem-eng.its.ac.id; Nurtono, Tantular, E-mail: machmudah@chem-eng.its.ac.id; Winardi, Sugeng, E-mail: machmudah@chem-eng.its.ac.id [Chemical Engineering Department, Sepuluh Nopember Institute of Technology, Surabaya 60111 (Indonesia); Wahyudiono,; Kanda, Hideki; Goto, Motonobu [Department of Chemical Engineering, Nagoya University, Nagoya 464-8603 (Japan)

2014-02-24

Zirconium oxide (zirconia, ZrO{sub 2}) is the most common material used for electrolyte of solid oxide fuel cells (SOFCs). Zirconia has attracted attention for applications in optical coatings, buffer layers for growing superconductors, thermal-shield, corrosion resistant coatings, ionic conductors, and oxygen sensors, and for potential applications including transparent optical devices and electrochemical capacitor electrodes, fuel cells, catalysts, and advanced ceramics. In this work, zirconia particles were synthesized from ZrCl{sub 4} precursor with hydrothermal treatment in a batch reactor. Hydrothermal treatment may allow obtaining nanoparticles and sintered materials with controlled chemical and structural characteristics. Hydrothermal treatment was carried out at temperatures of 150 – 200°C with precursor concentration of 0.1 – 0.5 M. Zirconia particles obtained from this treatment were analyzed by using SEM, PSD and XRD to characterize the morphology, particle size distribution, and crystallinity, respectively. Based on the analysis, the size of zirconia particles were around 200 nm and it became smaller with decreasing precursor concentration. The increasing temperature caused the particles formed having uniform size. Zirconia particles formed by hydrothermal treatment were monoclinic, tetragonal and cubic crystal.

Production and analysis of hydroxyapatite from Australian corals via hydrothermal process

International Nuclear Information System (INIS)

Hu, J.; Russell, J.; Ben-Nissan, B.

1999-01-01

Since the 1970s it is well known that if a biocompatible ceramic prosthesis with appropriate interconnected pores is used, growth of hard and soft tissue into the surface pores will be observed. A very strong attachment and hence the resultant mechanical and chemical bond to the existing surrounding tissue will be produced. Current artificial eyes although widely used encounter various problems due to the their motility and fail to deliver natural movement. They also cause sagging of the lids due to unsupported weight of the prosthesis. It is expected that application of a porous bioceramic such as the hydroxyapatite can generate good bonding to the tissue and hence a life-like eye movement. Hydroxyapatite (HAp) and related calcium phosphates have been studied for many years as implant materials, due to their similarity with the mineral phase of bone. From the point of view of biocompatibility, HAp seems to be the most suitable ceramic material for tissue replacement implants. Hydroxyapatite ceramics do not exhibit any cytoxic effects. It shows excellent biocompatibility with hard and soft tissues. Moreover, HAp can directly bond to the bone. Various preparation methods for HAp including the hydrothermal method have been used. The hydrothermal method was first used for hydroxyapatite formation directly from corals in 1974 by Roy and Linnehan. Complete replacement of aragonite by phosphatic material was achieved under 270degC and 103MPa using the hydrothermal process. This process has the disadvantage that the hydrothermal treatment must be carried out at a relatively high temperature under very high pressure. In 1996, HAp derived from Indian coral using hydrothermal process was developed by Sivakumar et al. However, the resultant material was in the form of a powder. Australia has rich variety of corals. Their application for implants have been studied very little. In this study, Australian corals selected were used for hydroxyapatite conversion. A new hydrothermal

Whole Algae Hydrothermal Liquefaction Technology Pathway

Energy Technology Data Exchange (ETDEWEB)

Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

2013-03-31

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

Characterized hydrochar of algal biomass for producing solid fuel through hydrothermal carbonization.

Science.gov (United States)

Park, Ki Young; Lee, Kwanyong; Kim, Daegi

2018-06-01

The aim of this work was to study the characterized hydrochar of algal biomass to produce solid fuel though hydrothermal carbonization. Hydrothermal carbonization conducted at temperatures ranging from 180 to 270 °C with a 60 min reaction improved the upgrading of the fuel properties and the dewatering of wet-basis biomasses such as algae. The carbon content, carbon recovery, energy recovery, and atomic C/O and C/H ratios in all the hydrochars in this study were improved. These characteristic changes in hydrochar from algal biomass are similar to the coalification reactions due to dehydration and decarboxylation with an increase in the hydrothermal reaction temperature. The results of this study indicate that hydrothermal carbonization can be used as an effective means of generating highly energy-efficient renewable fuel resources using algal biomass. Copyright © 2018 Elsevier Ltd. All rights reserved.

Application of Hydrothermal Treatment to High Concentrated Sewage Sludge for Anaerobic Digestion Process

OpenAIRE

M. Orikawa; H. Kamahara; Y. Atsuta; H. Daimon

2013-01-01

Tomato and seaweed were produced by utilizing CO2 and heat discharged from power generation using biogas in Toyogawa biomass park, Japan. The biogas was obtained by anaerobic digestion with hydrothermal treatment. The hydrothermal treatment was applied to the high concentrated sewage sludge (22 % total solids (TS) dewatered sludge). The purpose of this study is to clarify the effect of hydrothermal treatment on the qualities of high concentrated sewage sludge, by analyzing particulate organic...

Hydrothermal signature in the axial-sediments from the Carlsberg Ridge in the northwest Indian Ocean

Science.gov (United States)

Yu, Zenghui; Li, Huaiming; Li, Mengxing; Zhai, Shikui

2018-04-01

30 sediments grabbed from 24 sites between the equator and 10°N along the Carlsberg Ridge (CR) in the northwest Indian Ocean has been analyzed for bulk chemical compositions. Hydrothermal components in the sediments are identified and characterized. They mainly occur at 6.3°N as sulfide debris and at 3.6°N as both sulfide and high temperature water-rock interaction products. The enrichment of chalcophile elements such as Zn, Cu, Pb and the depletion of alkalis metals such as K and Rb are the typical features of hydrothermal components. High U/Fe, low (Nd/Yb)N and negative Ce anomaly infer the uptake of seawater in the hydrothermal deposits by oxidizing after deposition. However, the general enrichment of Mn in hydrothermal plumed-derived materials is not found in the sediments, which may indicate the limited diffusion of fluids or plumes, at least in the direction along the Carlsberg spreading center. The hydrothermal components show their similarity to the hydrothermal deposits from the Indian Ocean Ridge. At 3.6°N ultramafic rocks or gabbroic intrusions, may be involved in the hydrothermal system.

Integration of hydrothermal-energy economics: related quantitative studies

Energy Technology Data Exchange (ETDEWEB)

1982-08-01

A comparison of ten models for computing the cost of hydrothermal energy is presented. This comparison involved a detailed examination of a number of technical and economic parameters of the various quantitative models with the objective of identifying the most important parameters in the context of accurate estimates of cost of hydrothermal energy. Important features of various models, such as focus of study, applications, marked sectors covered, methodology, input data requirements, and output are compared in the document. A detailed sensitivity analysis of all the important engineering and economic parameters is carried out to determine the effect of non-consideration of individual parameters.

Hydrothermal stability of silica, hybrid silica and Zr-doped hybrid silica membranes

NARCIS (Netherlands)

ten Hove, Marcel; Luiten-Olieman, Mieke W.J.; Huiskes, Cindy; Nijmeijer, Arian; Winnubst, Louis

2017-01-01

Hybrid silica membranes have demonstrated to possess a remarkable hydrothermal stability in pervaporation and gas separation processes allowing them to be used in industrial applications. In several publications the hydrothermal stability of pure silica or that of hybrid silica membranes are

Construcciones y cementerios del período Intermedio Tardío en el cerro Ñañañique (departamento de Piura

Directory of Open Access Journals (Sweden)

1989-01-01

Full Text Available Après un abandon de plus d'un millénaire, le site de Cerro Ñañañique est réoccupé sans doute à partir du Xème siècle de notre ère. Les fouilles réalisées ont permis de reconnaître l'existence d'un ensemble monumental, composé de terrasses artificielles, et d'un complexe de bâtiments et structures couvrant tout le sommet du cerro. De petites constructions furent édifiées sur le bas versant Est et au moins cinq cimetières sont connus dans les environs immédiats. L'ensemble de ces vestiges prouve le maintien d'une occupation du secteur jusqu'à la fin de la période préhispanique. L'article est centré sur l'analyse de quatorze contextes funéraires provenant d'un des cimetières de cette époque. Y sont décrits les positions, orientations et associations des différents corps exhumés ainsi que le mobilier funéraire associé. Une comparaison avec les traditions voisines connues permet de confirmer certaines similitudes et en particulier les relations étroites avec les zones méridionales. Después de un abandono de más de un milenio, el sitio de Cerro Ñañañique se reocupó, posiblemente desde el siglo X d.c. Las excavaciones realizadas permitieron reconocer la existencia de un conjunto monumental compuesto de terrazas artificiales y de un complejo de edificios y estructuras que cubre toda la cumbre del cerro. Pequeñas construcciones fueron también edificadas en la parte baja de la vertiente este y hubo, por lo menos, cinco cementerios a proximidad. El conjunto de estos vestigios comprueba la permanencia de una ocupación del sector hasta el final de la época prehispánica. El artículo está centrado en el análisis de catorce contextos funerarios de aquella época. Se describen la posición, la orientación y las asociaciones de los varios cuerpos exhumados, así como el material funerario asociado. Una comparación con las tradiciones vecinas permite confirmar ciertas semejanzas y particularmente las relaciones

Japan-U. S. seminar on magmatic contributions to hydrothermal systems

Energy Technology Data Exchange (ETDEWEB)

Muffler, L. (U. S. Geological Survey, CA (United States)); Hedenquist, J. (Geological Survey of Japan, Tsukuba (Japan)); Kesler, S. (University of Michigan, MI (United States)); Izawa, E. (Kyushu University, Fukuoka (Japan). Faculty of Engineering)

1992-08-31

A multidisciplinary Seminar on Magmatic Contributions to Hydrothermal Systems'' was held at Ebino and Kagoshima at Kyushu, November, 1991. The principal purpose of the Ebino/Kagoshima Seminar was to bring together a small group of individuals which have been conducting active research on magmatic contributions to hydrothermal systems. The Seminar focussed on the porphyry and epithermal ore environments because of the potential to relate these environments to active volcanic and geothermal systems. Disciplines included valcanology, volcanic gas geochemistry, water geochemistry, isotope geochemistry, geochemical modeling, experimental geochemistry, igneous petrology, geothermal geology, economic geology, fluid-inclusion study, geophysics, and physical modeling. This paper summarizes the outline and significance of the Seminar. It was pointed out that understanding magmatic contributions to hydrothermal systems would require augmented experimental investigations, numerical modeling, field studies, and drilling.

Asymmetrical hydrothermal system below Merapi volcano imaged by geophysical data.

Science.gov (United States)

Byrdina, Svetlana; Friedel, Sven; Budi-Santoso, Agus; Suryanto, Wiwit; Suhari, Aldjarishy; Vandemeulebrouck, Jean; Rizal, Mohhamed H.; Grandis, Hendra

2017-04-01

A high-resolution image of the hydrothermal system of Merapi volcano is obtained using electrical resistivity tomography (ERT), self-potential, and CO2 flux mappings. The ERT inversions identify two distinct low-resistivity bodies, at the base of the south flank and in the summit area, that represent likely two parts of an interconnected hydrothermal system. In the summit area, the extension of the hydrothermal system is clearly limited by the main geological structures which are actual and ancient craters. A sharp resistivity contrast at ancient crater rim Pasar-Bubar separates a conductive hydrothermal system (20 - 50 Ωm) from the resistive andesite lava flows and pyroclastic deposits (2000 - 50 000 Ωm). High diffuse CO2 degassing (with a median value of 400g m -2 d -1) is observed in a narrow vicinity of the active crater rim and close to the Pasar-Bubar. The existence of preferential fluid circulation along this ancient crater rim is also evidenced by self-potential data. The total CO2 degassing across the accessible summit area with a surface of 1.4 · 10 5 m 2 is around 20 td -1. Before the 2010 eruption, Toutain et al. (2009) estimated a higher value of the total diffuse degassing from the summit area (about 200 - 230 td -1). This drop in the diffuse degassing can be related to the decrease in the magmatic activity, to the change of the summit morphology or to a combination of these factors. On the south flank of Merapi, the resistivity model shows spectacular stratification. While surficial recent andesite lava flows are characterized by resistivity exceeding 100 000 Ωm, resistivity as low as 10 Ωm has been encountered at a depth of 200 m at the base of the south flank and was interpreted as a presence of the hydrothermal system. We suggest that a sandwich-like structure of stratified pyroclastic deposits on the flanks of Merapi screen and separate the flow of hydrothermal fluids with the degassing occurring mostly through the fractured crater rims

Hydrothermal liquefaction of agricultural and forestry wastes: state-of-the-art review and future prospects.

Science.gov (United States)

Cao, Leichang; Zhang, Cheng; Chen, Huihui; Tsang, Daniel C W; Luo, Gang; Zhang, Shicheng; Chen, Jianmin

2017-12-01

Hydrothermal liquefaction has been widely applied to obtain bioenergy and high-value chemicals from biomass in the presence of a solvent at moderate to high temperature (200-550°C) and pressure (5-25MPa). This article summarizes and discusses the conversion of agricultural and forestry wastes by hydrothermal liquefaction. The history and development of hydrothermal liquefaction technology for lignocellulosic biomass are briefly introduced. The research status in hydrothermal liquefaction of agricultural and forestry wastes is critically reviewed, particularly for the effects of liquefaction conditions on bio-oil yield and the decomposition mechanisms of main components in biomass. The limitations of hydrothermal liquefaction of agricultural and forestry wastes are discussed, and future research priorities are proposed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Magmatic gases in fluid inclusions from hydrothermal ore deposits

Energy Technology Data Exchange (ETDEWEB)

Graney, J.; Kesler, S. (University of Michigan, MI (United States))

1992-08-31

In this study, magmatic gases in fluid inclusions from hydrothermal ore deposits have been analyzed. The gas composition of fluid inclusions from a wide range of extinct hydrothermal systems as represented by different ore deposit types was determined using a quadrupole mass spectrometer. Most samples used for analysis consisted of transparent quartz, although barite, jasperoid, opal, sphalerite, pyrite, chalcopyrite, and bornite were also analyzed. H2O was the dominant volatile component in fluid inclusions, and composed 95-99 mole percent of the inclusion fluid. CO2 comprised most of the remaining volatile component and the other gases were generally present in amounts smaller than 0.1 mole percent. Analysis from porphyry and acid-sulfate deposits, in which magmatic gas contributions are considered to be largest, plotted closest to the fumarolic gas compositions. These inclusion fluid volatile component comparisons have shown that there are systematic differences in inclusion fluids from different hydrothermal systems. 9 refs., 3 figs.

Polymer-Assisted Hydrothermal Synthesis of Hierarchically Arranged Hydroxyapatite Nanoceramic

Directory of Open Access Journals (Sweden)

A. Joseph Nathanael

2013-01-01

Full Text Available Flower-like hydroxyapatite (HA nanostructures were synthesized by a polymer-assisted hydrothermal method. The thickness of the petals/plates decreased from 200 nm to 40 nm as the polymer concentration increased. The thickness also decreased as the hydrothermal treatment time increased from 6 to 12 hr. The HRTEM and SAED patterns suggest that the floral-like HA nanostructures are single crystalline in nature. Structural analysis based on XRD and Raman experiments implied that the produced nanostructure is a pure form of HA without any other impurities. The possible formation mechanism was discussed for the formation of flower-like HA nanostructures during polymer-assisted hydrothermal synthesis. Finally, in vitro cellular analysis revealed that the hierarchically arranged HA nanoceramic had improved cell viability relative to other structures. The cells were actively proliferated over these nanostructures due to lower cytotoxicity. Overall, the size and the crystallinity of the nanostructures played a role in improving the cell proliferation.

Marine Subsurface Microbial Communities Across a Hydrothermal Gradient in Okinawa Trough Sediments

Science.gov (United States)

Brandt, L. D.; Hser Wah Saw, J.; Ettema, T.; House, C. H.

2015-12-01

IODP Expedition 331 to the Okinawa backarc basin provided an opportunity to study the microbial stratigraphy within the sediments surrounding a hydrothermal vent. The Okinawa backarc basin is a sedimented region of the seafloor located on a continental margin, and also hosts a hydrothermal network within the subsurface. Site C0014 within the Iheya North hydrothermal field is located 450 m east of the active vent and has a surface temperature of 5°C with no evidence of hydrothermal alteration within the top 10 meters below sea floor (mbsf). Temperature increases with depth at an estimated rate of 3°C/m and transitions from non-hydrothermal margin sediments to a hydrothermally altered regime below 10 mbsf. In this study, we utilized deep 16S rRNA sequencing of DNA from IODP Expedition 331 Site C0014 sediment horizons in order to assess diversity throughout the sediment column as well as determine the potential limits of the biosphere. Analysis of the amplicon data shows a shift over 15 mbsf from a heterogeneous community of cosmopolitan marine subsurface taxa toward an archaeal-dominated community in the deepest horizons of the predicted biosphere. Notably, the phylum Chloroflexi represents a substantial taxon through most horizons, where it appears to be replaced below 10 mbsf by punctuations of thermophilic and methanotrophic Archaea and Miscellaneous Crenarchaeotic Group abundances. DNA from the aforementioned transition horizons was further analyzed using metagenomic sequencing. Preliminary taxonomic analysis of the metagenomic data agrees well with amplicon data in capturing the shift in relative abundance of Archaea increasing with depth. Additionally, reverse gyrase, a gene found exclusively in hyperthermophilic microorganisms, was recovered only in the metagenome of the deepest horizon. A BLAST search of this protein sequence against the GenBank non-redudnant protein database produced top hits with reverse gyrase from Thermococcus and Pyrococcus, which are

Hydrothermal precipitation of artificial violarite

DEFF Research Database (Denmark)

Jørgensen, W. H.; Toftlund, H.; Warner, T. E.

2012-01-01

The nonstoichiometric nickel-ore mineral, violarite, (Ni,Fe)3S4 was prepared as a phase-pure fine powder by a comparatively quick hydrothermal method from an aqueous solution of iron(II) acetate, nickel(II) acetate and DL-penicillamine in an autoclave at 130 °C for 45 h. Powder-XRD showed that th...

Effect of acid detergent fiber in hydrothermally pretreated sewage sludge on anaerobic digestion process

Science.gov (United States)

Takasaki, Rikiya; Yuan, Lee Chang; Kamahara, Hirotsugu; Atsuta, Youichi; Daimon, Hiroyuki

2017-10-01

Hydrothermal treatment is one of the pre-treatment method for anaerobic digestion. The application of hydrothermal treatment to sewage sludge of wastewater treatment plant has been succeeded to enhance the biogas production. The purpose of this study is to quantitatively clarify the effect of hydrothermal treatment on anaerobic digestion process focusing on acid detergent fiber (ADF) in sewage sludge, which is low biodegradability. The hydrothermal treatment experiment was carried out for 15 minutes between 160 °C and 200 °C respectively. The ADF content was decreased after hydrothermal treatment compared with untreated sludge. However, ADF content was increased when raising the treatment temperature from 160 °C to 200 °C. During batch anaerobic digestion experiment, untreated and treated sludge were examined for 10 days under 38 °C, and all samples were fed once based on volatile solids of samples. From batch anaerobic digestion experiment, as ADF content in sewage sludge increased, the total biogas production decreased. It was found that ADF content in sewage sludge influence on anaerobic digestion. Therefore, ADF could be one of the indicator to evaluate the effect of hydrothermal treatment to sewage sludge on anaerobic digestion.

Mobility of rare earth element in hydrothermal process and weathering product: a review

Science.gov (United States)

Lintjewas, L.; Setiawan, I.

2018-02-01

The Rare Earth Element (REE), consists of La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Lu, Ho, Er, Tm, Yb, are important elements to be used as raw materials of advanced technology such as semiconductors, magnets, and lasers. The research of REE in Indonesia has not been done. Several researches were conducted on granitic rocks and weathering product such as Bangka, Sibolga, West Kalimantan, West Sulawesi and Papua. REE can be formed by hydrothermal processes such as Bayan Obo, South China. The REE study on active hydrothermal system (geothermal) in this case also has the potential to produce mineral deposits. The purpose of this review paper is to know the mobility of REE on hydrothermal process and weathering products. Mobility of REE in the hydrothermal process can change the distribution patterns and REE content such as Ce, Eu, La, Lu, Nd, Sm, and Y. Another process besides the hydrothermal is weathering process. REE mobility is influenced by weathering products, where the REE will experience residual and secondary enrichment processes in heavier minerals.

Arsenic speciation in shrimp and mussel from the Mid-Atlantic hydrothermal vents

DEFF Research Database (Denmark)

Larsen, Erik Huusfeldt; Quetel, C. R.; Munoz, R.

1997-01-01

Specimens of shrimp (Rimicaris exoculata) and mussel (Bathymodiolus puteoserpentis) were collected 3500 m below the ocean surface at the hydrothermal vents of the mid-Atlantic Ridge (TAG and Snake Pit sites, respectively). Arsenic, a potentially toxic element, is among the substances emitted...... by the hydrothermal vents. The hydrothermal vent shrimp, which are known to be a primary consumer of the primary producing chemolithoautotrophic bacteria, contained arsenic at 13 mu g g(-1) almost exclusively as arsenobetaine (AsB). Arsenic was present in the soft:issues of the mussel at 40 mu g g(-1) and the major...... of arsenic species found in the shrimp and mussel species in the deep-sea is similar to that found in their counterparts from the ocean surface. It is concluded that the autotrophic bacteria of the hydrothermal vent ecosystem and the symbiotic bacteria harboured in the mussel species are responsible...

Tecnología para la producción artesanal del Jabón Prieto de Jatropha curcas L

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Enrique Casanovas Cosío

2014-09-01

Full Text Available La producción de jabón artesanal es una práctica local en el Cantón de Chone de la provincia de Manabí, Ecuador, pero que no está descrito el proceso en literatura científica. Se ha tratado de describir la tecnología artesanal de producción del Jabón Prieto con las nueces del piñón (Jatropha curcas L., para lo cual se empleó un diseño observacional apoyado con encuestas a tres productores y una comparación entre tres muestras de producciones de jabones obtenidos del aceite de la Jatropha en laboratorios del INIAP y las artesanales. Los procesos de producción de jabones artesanales son similares y se describe la tecnología en la cual no se encontraron gastos de insumos externos que apunta a la sostenibilidad de su producción. El jabón artesanal es más oscuro y con un olor penetrante parecido al del fruto seco, ambos son de consistencia sólida; que en el jabón artesanal se expresa por la adición de grasa de vaca con ácidos grasos saturados. Los jabones obtenidos presentaron similares valores de pH (alcalinos. El jabón artesanal presentó mayor contenido de humedad (12.73 % y menor contenido de grasa (34.77 %. La variabilidad de los indicadores físico químicos fueron mayores en el jabón artesanal pero siempre con un CV menor de 10.0 %, que indica similitud en los procesos. Desde el punto de vista bacteriológico ambos jabones se declaran aptos para el consumo con recuentos de aerobios mesófilos totales menores que 10 UFC, y ausencia de Echerichia coli, Salmonella sp. y Shigelia sp.

Hydrothermally grown zeolite crystals

International Nuclear Information System (INIS)

Durrani, S.K.; Qureshi, A.H.; Hussain, M.A.; Qazi, N.K.

2009-01-01

The aluminium-deficient and ferrosilicate zeolite-type materials were synthesized by hydrothermal process at 150-170 degree C for various periods of time from the mixtures containing colloidal reactive silica, sodium aluminate, sodium hydroxide, iron nitrate and organic templates. Organic polycation templates were used as zeolite crystal shape modifiers to enhance relative growth rates. The template was almost completely removed from the zeolite specimens by calcination at 550 degree C for 8h in air. Simultaneous thermogravimetric (TG) and differential thermal analysis (DTA) was performed to study the removal of water molecules and the amount of organic template cations occluded inside the crystal pore of zeolite framework. The 12-13% weight loss in the range of (140-560 degree C) was associated with removal of the (C/sub 3/H/sub 7/)/sub 4/ N+ cation and water molecules. X-ray diffraction (XRD) analysis and scanning electron microscope (SEM) techniques were employed to study the structure, morphology and surface features of hydrothermally grown aluminium-deficient and ferrosilicate zeolite-type crystals. In order to elucidate the mode of zeolite crystallization the crystallinity and unit cell parameters of the materials were determined by XRD, which are the function of Al and Fe contents of zeolites. (author)

Synthesis of mesoporous cerium-zirconium mixed oxides by hydrothermal templating method

Institute of Scientific and Technical Information of China (English)

无

2008-01-01

Mesoporous cerium-zirconium mixed oxides were prepared by hydrothermal method using cetyl trimethyl ammonium bromide (CTAB) as template.The effects of amount of template,pH value of solution and hydrothermal temperature on mesostructure of samples were systematically investigated.The final products were characterized by XRD,TEM,FT-IR,and BET.The results indicate that all the cerium-zirconium mixed oxides present a meso-structure.At molar ratio of n(CTAB)/n((Ce)+(Zr))=0.15,pH value of 9,and hydrothermal temperature of 120 ℃,the samples obtained possess a specific surface area of 207.9 m2/g with pore diameter of 3.70 nm and pore volume of 0.19 cm3/g.

Cerro Negro bitumen degradation by a consortium of marine benthic microorganisms

Energy Technology Data Exchange (ETDEWEB)

Potter, T.L.; Duval, B. [USDA-ARA, Tifton, GA (USA). Southeast Watershed Research Laboratory

2001-01-01

Cerro Negro bitumen, separated from an Orimulsion sample, was incubated for up to 120 days with sediments collected at a petroleum-impacted site in Tampa Bay, Florida. Biodegradation conditions were optimized by increasing bitumen surface area, continuous agitation on a shaker apparatus, use of a complete growth medium, and maintenance at 37{degree}C. Aerobic degradation conditions were promoted by maintaining sediment contact with the laboratory atmosphere. Bitumen recovered in solvent extracts when compared to autoclaved controls decreased by up to 40% during the first 56 days. There was no detectable change after this. Molasses addition and use of a culture enriched from the sediments did not change the extent or rate of decrease in bitumen recovery. Chemical fractionation of bitumen control and degraded bitumen showed that aromatic and aliphatic fractions were depleted by {approx} 50%. Accumulation of polars was observed; however, the apparent increase was relatively small when compared to the mass loss of the other fractions. Selected biomarker ratios were not affected by incubation indicating their utility for fingerprinting the source bitumen in environmental samples. PAH distribution in the aromatic fraction favored the higher alkyl-homologues with the relative degree of alkylation increasing as the mass of bitumen recovered decreased with degradation. The study showed that up to 40% of the bitumen was bioaccessible and that bioremediation may be a treatment option for sediments contaminated with bitumen by an Orimulsion spill. 36 refs., 8 figs., 5 tabs.

Far-IR measurements at Cerro Toco, Chile: FIRST, REFIR, and AERI

Science.gov (United States)

Cageao, Richard P.; Alford, J. Ashley; Johnson, David G.; Kratz, David P.; Mlynczak, Martin G.

2010-09-01

In mid-2009, the Radiative Heating in the Underexplored Bands Campaign II (RHUBC-II) was conducted from Cerro Toco, Chile, a high, dry, remote mountain plateau, 23°S , 67.8°W at 5.4km, in the Atacama Desert of Northern Chile. From this site, dominant IR water vapor absorption bands and continuum, saturated when viewed from the surface at lower altitudes, or in less dry locales, were investigated in detail, elucidating infrared (IR) absorption and emission in the atmosphere. Three Fourier Transform InfraRed (FTIR) instruments were at the site, the Far-Infrared Spectroscopy of the Troposphere (FIRST), the Radiation Explorer in the Far Infrared (REFIR), and the Atmospheric Emitted Radiance Interferometer (AERI). In a side-by-side comparison, these measured atmospheric downwelling radiation, with overlapping spectral coverage from 5 to 100μm (2000 to 100cm-1), and instrument spectral resolutions from 0.5 to 0.643cm-1, unapodized. In addition to the FTIR and other ground-based IR and microwave instrumentation, pressure/temperature/relative humidity measuring sondes, for atmospheric profiles to 18km, were launched from the site several times a day. The derived water vapor profiles, determined at times matching the FTIR measurement times, were used to model atmospheric radiative transfer. Comparison of instrument data, all at the same spectral resolution, and model calculations, are presented along with a technique for determining adjustments to line-by-line calculation continuum models. This was a major objective of the campaign.

Resistivity structure and geochemistry of the Jigokudani Valley hydrothermal system, Mt. Tateyama, Japan

Science.gov (United States)

Seki, Kaori; Kanda, Wataru; Tanbo, Toshiya; Ohba, Takeshi; Ogawa, Yasuo; Takakura, Shinichi; Nogami, Kenji; Ushioda, Masashi; Suzuki, Atsushi; Saito, Zenshiro; Matsunaga, Yasuo

2016-10-01

This study clarifies the hydrothermal system of Jigokudani Valley near Mt. Tateyama volcano in Japan by using a combination of audio-frequency magnetotelluric (AMT) survey and hot-spring water analysis in order to assess the potential of future phreatic eruptions in the area. Repeated phreatic eruptions in the area about 40,000 years ago produced the current valley morphology, which is now an active solfatara field dotted with hot springs and fumaroles indicative of a well-developed hydrothermal system. The three-dimensional (3D) resistivity structure of the hydrothermal system was modeled by using the results of an AMT survey conducted at 25 locations across the valley in 2013-2014. The model suggests the presence of a near-surface highly conductive layer of falling largely on a mixing line between magmatic fluids and local meteoric water (LMW). The geochemical analysis suggests that the hydrothermal system includes a two-phase zone of vapor-liquid. A comparison of the resistivity structure and the geochemically inferred structure suggests that a hydrothermal reservoir is present at a depth of approximately 500 m, from which hot-spring water differentiates into the three observed types. The two-phase zone appears to be located immediately beneath the cap rock structure. These findings suggest that the hydrothermal system of Jigokudani Valley exhibits a number of factors that could trigger a future phreatic eruption.

Changes in Fe Oxidation Rate in Hydrothermal Plumes as a Potential Driver of Enhanced Hydrothermal Input to Near-Ridge Sediments During Glacial Terminations

Science.gov (United States)

Cullen, J. T.; Coogan, L. A.

2017-12-01

Recent studies have hypothesized that changes in sea level due to glacial-interglacial cycles lead to changes in the rate of melt addition to the crust at mid-ocean ridges with globally significant consequences. Arguably the most compelling evidence for this comes from increases in the hydrothermal component in near-ridge sediments during glacial-interglacial transitions. Here we explore the hypothesis that changes in ocean bottom water [O2] and pH across glacial-interglacial transitions would lead to changes in the rate of Fe oxidation in hydrothermal plumes. A simple model shows that a several fold increase in the rate of Fe oxidation is expected at glacial-interglacial transitions. Uncertainty in bottom water chemistry and the relationship between oxidation and sedimentation rates prevent direct comparison of the model and data. However, it appears that the null hypothesis of invariant hydrothermal vent fluxes into ocean bottom water that changed in O2 content and pH across these transitions cannot currently be discounted.

Chicxulub: testing for post-impact hydrothermal inputs into the Tertiary ocean

Science.gov (United States)

Rowe, A.; Wilkinson, J.; Morgan, J.

2003-04-01

Large terrestrial impacts produce intense fracturing of the crust and large melt sheets, providing ideal conditions for extensive hydrothermal circulation. In marine settings, such as Chicxulub, there is the potential for downward penetration of cold seawater, heating by the thermal anomaly at the impact site and leaching of metals, prior to buoyancy driven flow back to the surface. There, fluids may undergo venting into the water column. A large proportion of the metals in such vent fluids precipitate close to the site of discharge; however, a proportion of the fluid is dispersed as a hydrothermal plume. Dissolved and particulate materials (in particular manganese and iron oxyhydroxides) can be carried for several hundreds of kilometers, before falling out to form metal-rich sediments. A series of Tertiary core samples has been obtained from the International Continental Drilling Program at Chicxulub (CSDP). These comprise fine-grained cream coloured carbonate sediments with fine laminations. Transmitted light and cathodoluminescence petrography have been used to carry out a preliminary characterization of the samples. Multi-element analysis has also been undertaken by ICP-AES. Samples were reduced to powder and digested using a nitric-perchloric-hydrofluoric acid attack. Rare earth elements (REE) have been analysed by ICP-MS and solutions were prepared using a modified nitric-perchloric-hydrofluoric acid attack. Geochemical analyses have been carried out to test for characteristic signals of hydrothermal input, such as enrichments in Mn, Fe, Cu, Zn, Pb, Mg, Ba, Co, Cr and Ni. The REE are scavenged from seawater onto iron oxide surfaces in the plume; hence anomalous REE concentrations are also indicative of hydrothermal addition. Furthermore, the type of anomaly can differentiate between sediments proximal (+ve Eu) distal (-ve Ce) to the vent site. The stratigraphic extent of any anomalies can be used to constrain the duration of any post-impact circulation. The

Entre el sueño del proyecto y la lógica del lugar. La arquitectura imposible de los cerros de Valparaíso

Directory of Open Access Journals (Sweden)

Pablo M. Millán-Millán

2016-04-01

Full Text Available Valparaíso es el resultado de la unión de dos ciudades en una: la ciudad vertical de los cerros y la ciudad horizontal del Plan –parte plana–. Esta doble naturaleza ha ido configurando una dualidad obligada a convivir y a establecer un continuo diálogo, acabando en la mayoría de los casos en conflicto. Si por un lado está la ciudad global y ortogonal como resultado de la ocupación europea, por otro lado estará la ciudad onírica agarrada a los acantilados ajena a cualquier orden preestablecido. Cada una de estas dos ciudades irá materializando su propia arquitectura: una real y estandarizada, propia de cualquier periferia de ciudad, y otra imposible. Será esta segunda la que vaya evolucionando en un intento continuo de adaptación y será el propio lugar el encargado de rechazar cualquier construcción que no le sea propia. Esta dicotomía quedará plasmada en numerosos proyectos que nunca verán la luz. El objetivo del artículo será mostrar, a partir de numerosos proyectos inéditos descubiertos en Valparaíso, cómo la arquitectura pensada para los cerros nunca llegó a construirse y fue dando paso a unas construcciones a medio camino entre lo real y lo imaginario, entre la lógica y el sueño.

Lipid synthesis under hydrothermal conditions by Fischer-Tropsch-type reactions.

Science.gov (United States)

McCollom, T M; Ritter, G; Simoneit, B R

1999-03-01

Ever since their discovery in the late 1970's, mid-ocean-ridge hydrothermal systems have received a great deal of attention as a possible site for the origin of life on Earth (and environments analogous to mid-ocean-ridge hydrothermal systems are postulated to have been sites where life could have originated or Mars and elsewhere as well). Because no modern-day terrestrial hydrothermal systems are free from the influence of organic compounds derived from biologic processes, laboratory experiments provide the best opportunity for confirmation of the potential for organic synthesis in hydrothermal systems. Here we report on the formation of lipid compounds during Fischer-Tropsch-type synthesis from aqueous solutions of formic acid or oxalic acid. Optimum synthesis occurs in stainless steel vessels by heating at 175 degrees C for 2-3 days and produces lipid compounds ranging from C2 to > C35 which consist of n-alkanols, n-alkanoic acids, n-alkenes, n-alkanes and alkanones. The precursor carbon sources used are either formic acid or oxalic acid, which disproportionate to H2, CO2 and probably CO. Both carbon sources yield the same lipid classes with essentially the same ranges of compounds. The synthesis reactions were confirmed by using 13C labeled precursor acids.

Mechano-hydrothermal preparation of Li-Al-OH layered double hydroxides

Science.gov (United States)

Zhang, Fengrong; Hou, Wanguo

2018-05-01

A mechano-hydrothermal (MHT) method was used to synthesize Li-Al-OH layered double hydroxides (LDHs) from LiOH·H2O, Al(OH)3 and H2O as starting materials. A two-step synthesis was conducted, that is, Al(OH)3 was milled for 1 h, followed by hydrothermal treatment with LiOH·H2O solution. Effects of the LiOH/Al(OH)3 molar ratio (RLi/Al) and hydrothermal temperature (Tht) on the crystallinity, morphology, and composition of the product were examined. The resulting LDHs were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, Fourier transform infrared, and elemental analyses. The results showed that pre-milling plays a key role in the LDH formation during subsequent hydrothermal treatment. The Li/Al molar ratio of the obtained LDHs keeps constant at 0.5, independent from theRLi/Al (0.5-5.0) in the starting materials. An increase in the Tht (20-80 °C) can enhance the crystallinity and morphology regularity of the products. The so-obtained Li-Al-OH LDHs exhibit high crystallinity and well-dispersity, which may have wider applications than the aggregate ones obtained using conventional mechanochemical and Li+-imbibition methods.

Hydrothermal formation and characterization of magnesium oxysulfate whiskers

International Nuclear Information System (INIS)

Xiang, L.; Liu, F.; Li, J.; Jin, Y.

2004-01-01

Magnesium oxysulfate (5Mg(OH) 2 ·MgSO 4 ·3H 2 O) whiskers with a diameter of 0.2-1.0 μm and a length of 20-50 μm were synthesized via the hydrothermal treatment of the slurry formed by mixing the MgSO 4 and NaOH solutions at room temperature. The composition, morphology, structure and thermal behavior of the hydrothermal products were examined with X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermo-gravimetric analysis (TGA) and chemical analysis. The experimental results indicated that the process parameters, such as the concentration of the reactant, the dispersion of the Mg(OH) 2 slurry and the temperature in hydrothermal treatment should be controlled carefully to synthesis 5Mg(OH) 2 ·MgSO 4 ·3H 2 O whiskers and to avoid the formation of the sectorial or granular impurities. 5Mg(OH) 2 ·MgSO 4 ·3H 2 O whiskers were decomposed gradually and converted finally to MgO particles after being heated in air at temperature up to 1050 deg. C. Granular products formed if the heating temperature was above 320 deg. C

Application of cultural algorithm to generation scheduling of hydrothermal systems

International Nuclear Information System (INIS)

Yuan Xiaohui; Yuan Yanbin

2006-01-01

The daily generation scheduling of hydrothermal power systems plays an important role in the operation of electric power systems for economics and security, which is a large scale dynamic non-linear constrained optimization problem. It is difficult to solve using traditional optimization methods. This paper proposes a new cultural algorithm to solve the optimal daily generation scheduling of hydrothermal power systems. The approach takes the water transport delay time between connected reservoirs into consideration and can conveniently deal with the complicated hydraulic coupling simultaneously. An example is used to verify the correctness and effectiveness of the proposed cultural algorithm, comparing with both the Lagrange method and the genetic algorithm method. The simulation results demonstrate that the proposed algorithm has rapid convergence speed and higher solution precision. Thus, an effective method is provided to solve the optimal daily generation scheduling of hydrothermal systems

On the origin of whewellite in a hydrothermal uranium deposit

International Nuclear Information System (INIS)

Galimov, Eh.M.; Tugarinov, A.I.; Nikitin, A.A.

1975-01-01

Whewellite (calcium oxalate - Ca(COO) 2 H 2 O) is one of the rare minerals that occur principally in rocks of sedimentary origin. The authors of the article explained the origin of whewellite selected on a hydrothermal uranium deposit. To do this, they investigated the isotope composition of the carbon contained in the mineral and also of the carbon in the accompanying calcite and carbonaceous material. It was established that hydrothermal whewellite is markedly different in isotope composition from diagenetic whewellite. The whewellite investigated is a product of oxidation-reduction reactions that have taken place in a hydrothermal solution and in which organic substances are involved. U 6+ was reduced and precipitated in the form of pitchblende and the oxidized forms of organic substances including oxalic acid, were formed, with subsequent precipitation of the oxalate in the form of whewellite. (V.Ya.)

Evolution of Morphology and Crystallinity of Silica Minerals Under Hydrothermal Conditions

Science.gov (United States)

Isobe, H.

2011-12-01

Silica minerals are quite common mineral species in surface environment of the terrestrial planets. They are good indicator of terrestrial processes including hydrothermal alteration, diagenesis and soil formation. Hydrothermal quartz, metastable low temperature cristobalite and amorphous silica show characteristic morphology and crystallinity depending on their formation processes and kinetics under wide range of temperature, pressure, acidity and thermal history. In this study, silica minerals produced by acidic hydrothermal alteration related to volcanic activities and hydrothermal crystallization experiments from diatom sediment are examined with crystallographic analysis and morphologic observations. Low temperature form of cistobalite is a metastable phase and a common alteration product occured in highly acidic hydrothermal environment around fumaroles in geothermal / volcanic areas. XRD analysis revealed that the alteration degree of whole rock is represented by abundance of cristobalite. Detailed powder XRD analysis show that the primary diffraction peak of cristobalite composed with two or three phases with different d-spacing and FWHM by peak profile fitting analysis. Shorter d-spacing and narrower FWHM cristobalite crystallize from precursor materials with less-crystallized, longer d-spacing and wider FWHM cristobalite. Textures of hydrothermal cristobalite in altered rock shows remnant of porphylitic texture of the host rock, pyroxene-amphibole andesite. Diatom has amorphous silica shell and makes diatomite sediment. Diatomite found in less diagenetic Quarternary formation keeps amorphous silica diatom shells. Hydrothermal alteration experiments of amorphous silica diatomite sediment are carried out from 300 °C to 550 °C. Mineral composition of run products shows crystallization of cristobalite and quartz progress depending on temperature and run durations. Initial crystallization product, cristobalite grains occur as characteristic lepispheres and

600 kyr of Hydrothermal Activity on the Cleft Segment of the Juan de Fuca Ridge

Science.gov (United States)

Middleton, J. L.; Mukhopadhyay, S.; Langmuir, C. H.; Costa, K.; McManus, J. F.; Katz, R. F.; Huybers, P. J.; Winckler, G.; Li, Y.

2017-12-01

Pressure fluctuations caused by glacially driven variations in sea level may modulate magmatic and hydrothermal output at submarine volcanic centers, with falling sea level driving increased volcanic activity. In turn, glacially paced changes in submarine volcanism could induce globally synchronous variations in the delivery of bioavailable iron and CO2 from mid-ocean ridges and thus provide solid-Earth feedbacks into the climate system. While evaluation of submarine volcanic output on orbital-timescales is technically challenging, near-ridge sediment cores hosting hydrothermal plume precipitates provide continuous, spatially integrated, and datable records to investigate the long-term behavior of hydrothermal systems. We will present new sedimentary records of hydrothermal variability spanning the past 600 kyr on the Cleft Segment of the Juan de Fuca Ridge in the Northeast Pacific. As an intermediate spreading-rate ridge, the Juan de Fuca Ridge is hypothesized to be particularly sensitive to sea level forcing at the Milankovitch frequencies of Pleistocene glacial cycles. Thus, the new records can be used to examine the connection between sea level and hydrothermal activity over multiple glacial cycles. Hydrothermal input is determined from iron and copper, with a titanium-based correction for lithogenic contributions. Sedimentary fluxes are then constrained using excess thorium-230 and extraterrestrial helium-3 as constant flux proxies. Preliminary results indicate 10-fold changes in hydrothermal iron and copper fluxes over the past 600 kyr and suggest a quasiperiodic variability in hydrothermal deposition on 100 to 120 kyr cycles. Comparison of the Juan de Fuca record with model predictions for an intermediate spreading ridge forced by Pleistocene glacial cycles finds frequent coincidence between predicted positive anomalies in magmatic output and observed peaks in hydrothermal deposition. This work encourages the continued exploration of the relationship between

Hydrothermal Fe-Si-Mn oxide deposits from the Central and South Valu Fa Ridge, Lau Basin

International Nuclear Information System (INIS)

Sun Zhilei; Zhou Huaiyang; Yang Qunhui; Sun Zhixue; Bao Shenxu; Yao Huiqiang

2011-01-01

Highlights: → The Fe-Mn crust in the HHF has seawater contribution, whereas the Fe-Si oxide in the MHF is dominated by hydrothermal fluid → The Nd isotope of diffuse flow Fe-Si-Mn deposits indicates the obvious hydrothermal origin. → The Mn/Fe ratio in hydrothermal deposit may be a good indicator of propagating activities of the Valu Fa Ridge. - Abstract: A series of samples from the Hine Hina hydrothermal field (HHF) and the Mariner hydrothermal field (MHF) in the Central and Southern Valu Fa Ridge (VFR), Lau Basin were examined to explain the source origin and formation of the hydrothermal Fe-Si-Mn oxide deposits. The mineralogy was studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), Moessbauer spectroscopy, and energy-dispersive spectroscopy (EDS). For the Fe-Mn oxide crusts in the HHF, varying amounts of volcanic fragments and some seawater contributions were recognized, along with higher concentrations of Mn, Al, Co, Ni, Zn, Sr, Mo, elevated ΣREE and negative Ce anomalies. In contrast, the Si-rich oxide samples of the MHF were enriched in Cu, Pb and Ba, indicative of proximity to a hydrothermal jet. Moreover, conductive cooling of hydrothermal fluid evoked the Si-rich deposit formation in the MHF. The Sr, Nd and Pb isotope data provided further constraints regarding the source and formation of the Fe-Si-Mn deposits in the VFR by showing that the samples of the HHF are a mixture of three components, namely, hydrothermal fluid, seawater and volcanic materials, whereas the samples of the MHF were dominated by hydrothermal fluids. The seawater had a minor influence on the Nd isotope data, and the Pb isotope data exhibited a close association with the substrate rock and preformed volcaniclastic layers in this area. The occurrence of relatively high Mn/Fe ratios in the hydrothermal deposits of this area may be a good indicator of the propagating activities of the VFR over geological time.

Hydrothermal synthesis of hydroxyapatite nanorods using pyridoxal-5′-phosphate as a phosphorus source

Energy Technology Data Exchange (ETDEWEB)

Zhao, Xin-Yu; Zhu, Ying-Jie, E-mail: y.j.zhu@mail.sic.ac.cn; Lu, Bing-Qiang; Chen, Feng; Qi, Chao; Zhao, Jing; Wu, Jin

2014-07-01

Graphical abstract: Hydroxyapatite nanorods are synthesized using biocompatible biomolecule pyridoxal-5′-phosphate as a new organic phosphorus source by the hydrothermal method. - Highlights: • Hydrothermal synthesis of hydroxyapatite nanorods is reported. • Biocompatible pyridoxal-5′-phosphate is used as an organic phosphorus source. • This method is simple, surfactant-free and environmentally friendly. - Abstract: Hydroxyapatite nanorods are synthesized by the hydrothermal method using biocompatible biomolecule pyridoxal-5′-phosphate (PLP) as a new organic phosphorus source. In this method, PLP biomolecules are hydrolyzed to produce phosphate ions under hydrothermal conditions, and these phosphate ions react with pre-existing calcium ions to form hydroxyapatite nanorods. The effects of experimental conditions including hydrothermal temperature and time on the morphology and crystal phase of the products are investigated. This method is simple, surfactant-free and environmentally friendly. The products are characterized by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared (FTIR) spectroscopy, and thermogravimetric (TG) analysis.

Genetic diversity of archaea in deep-sea hydrothermal vent environments.

OpenAIRE

Takai, K; Horikoshi, K

1999-01-01

Molecular phylogenetic analysis of naturally occurring archaeal communities in deep-sea hydrothermal vent environments was carried out by PCR-mediated small subunit rRNA gene (SSU rDNA) sequencing. As determined through partial sequencing of rDNA clones amplified with archaea-specific primers, the archaeal populations in deep-sea hydrothermal vent environments showed a great genetic diversity, and most members of these populations appeared to be uncultivated and unidentified organisms. In the...

Surface-discharging hydrothermal systems at Yucca Mountain: Examining the evidence

International Nuclear Information System (INIS)

Levy, S.S.

1992-01-01

This paper discusses exposures of altered rock that have been thought to form by recent discharge of water from depth. They were examined to address a concern that hydrothermal processes could compromise the isolation capability of a potential high-level nuclear waste repository at Yucca Mountain. Suspected hot-spring and hydrothermal-vent deposits are more likely the products of infiltration of meteoric water into newly deposited and still-hot pyroclastic flows >12 Myr ago

La intrusión de Cerro Redondo (Pérmico Inferior, Cordillera Ibérica, Zaragoza): reconstrucción 3D y modelo de emplazamiento

OpenAIRE

Majarena Serrano, Urbez; Gil Imaz, Andrés; Lago San José, Marceliano; Galé, Carlos

2017-01-01

La intrusión subvolcánica de Cerro Redondo (Cordillera Ibérica, Zaragoza), de edad Pérmico Inferior, muestra una composición dactíca, una naturaleza calcoalcalina y se caracteriza por presentar una marcada estructuración interna determinada por un bandeado subvertical y d e espaciado variable (1-25 cm), que se encuentra afectado por numerosos pliegues d e flujo magmático de distinta escala (desde centimétrica hasta hectométrica). El estudio cartográfico y de la anisotropia de la susceptib...

Unrest of Chiles - Cerro Negro volcanic complex: A binational Ecuador - Colombia effort

Science.gov (United States)

Ruiz, M. C.; Gomez, D.; Torres, R.; Cadena, O.; Mothes, P. A.; Anzieta, J. C.; Pacheco, D. A.; Bernard, B.; Acero, W.; Hidalgo, S.; Enriquez, W.; Cordova, A.

2014-12-01

The increasing seismic activity at the area of Chiles - Cerro Negro volcanic complex, located at the Ecuador-Colombian border, has been jointly monitored by the Instituto Geofisico - Ecuador and the Observatorio Vulcanologico y Sismologico de Pasto OVSP, a division of the Servicio Geologico Colombiano. Since April 2013, three seismic swarms have been detected in this area and more than 100.000 events are recorded since November 2013. The largest and more recent swarm has a daily average of 676 events between March and June 2014. Currently a seismic network of 8 seismic stations (5 in the Colombian and 3 in Ecuadorean side) are deployed in this area. Epicenters of more than 315 seismic events with magnitudes Ml>2.0 and 10 or more phases are located in an area 1-4 km south of Chiles volcano with shallow depths (up to 14 km). Most of events have magnitudes between 1.0 to 4.0. Nine events have magnitudes larger than 4.0 and the largest event occurred on April 30. 2014 with a local magnitude of 4.7 and inverse-transcurrent component focal mechanism. Waveforms and spectral patterns define these events as volcano-tectonic. Events with large magnitudes (above 3.0) show a very long-period component. Hot spring and deformation measurements also show signals of volcanic unrest.

Hydrothermal research and development assessment. Task Force report: projections for direct-heat applications

Energy Technology Data Exchange (ETDEWEB)

1982-04-01

Low and moderate temperature hydrothermal resources suitable for direct-heat applications have been identified in 37 states. The extent to which three resources might be used over the next 20 years were evaluated and the probable impact of Federal programs on hydrothermal resource utilization was assessed. The use types that comprise the bulk of the market were determined. Representative firms and municipalities were interviewed to determine their willingness to use hydrothermal energy, and to determine the investment decision criteria that would influence their actions. (MHR)

Role of triton X-100 and hydrothermal treatment on the morphological features of nanoporous hydroxyapatite nanorods

International Nuclear Information System (INIS)

Iyyappan, E.; Wilson, P.; Sheela, K.; Ramya, R.

2016-01-01

Hydroxyapatite (HA) particles were synthesized using Ca(NO 3 ) 2 ·4H 2 O and (NH 4 ) 2 HPO 4 as precursors with varying contents of non-ionic surfactant viz., triton X-100 (organic modifier) via co-precipitation method followed by hydrothermal treatment. The prepared HA particles have been characterized by X-ray diffraction (XRD), Fourier Transform Infrared spectroscopy (FT-IR), Energy Dispersive X-ray Analysis (EDX), High Resolution Scanning Electron Microscopy (HRSEM), High Resolution Transmission Electron Microscopy (HRTEM) and Nitrogen adsorption–desorption experiments. The XRD and FTIR studies indicate the formation of HA phase in all the synthesized samples. The specific roles of triton X-100 and hydrothermal treatment in dispersing and in directing the crystal growth respectively have been discussed by comparing the observations from individual experiments using triton X-100 and hydrothermal treatment with that of combined protocol involving both. The plausible mechanism for the individual roles of both triton X-100 and hydrothermal treatment have been proposed. - Highlights: • Nanoporous HA nanorods are synthesized via triton X-100 assisted hydrothermal treatment. • Triton X-100 hinder the agglomeration of HA primary particles • Hydrothermal treatment increase the aspect ratio of the HA particles • Oriented attachment of HA particles occurs under hydrothermal treatment facilitated by triton X-100 stabilized HA collides • The percentage of mesopore volume is higher for hydrothermally treated samples

Chemical composition of hydrothermal ores from Mid-Okinawa trough and Suiyo Seamount determined by neutron activation analysis

International Nuclear Information System (INIS)

Noguchi, Takuroh; Taira, Naoto; Oomori, Tamotsu; Taira, Hatsuo; Tanahara, Akira; Takada, Jitsuya

2007-01-01

Neutron activation analysis of 13 hydrothermal ore samples (70 subsamples) collected from the Mid-Okinawa Trough and Suiyo Seamount revealed higher contents of precious metal such as Au and Ag, and those of As, Sb, Ga, and Hg than those from mid-ocean ridge hydrothermal systems. In addition, the Mid-Okinawa Trough samples were richer in Ag and Sb than those from the Suiyo Seamount. The geochemical differences among these hydrothermal ore deposits are regarded as reflecting both differences in the chemical composition of the hosted magma of hydrothermal system and the abundance of sediments that is reacted with hydrothermal fluids. (author)

WO{sub 3} nanorods prepared by low-temperature seeded growth hydrothermal reaction

Energy Technology Data Exchange (ETDEWEB)

Ng, Chai Yan [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Abdul Razak, Khairunisak, E-mail: khairunisak@eng.usm.my [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); NanoBiotechnology Research and Innovation (NanoBRI), Institute for Research in Molecular Medicine (INFORMM), Universiti Sains Malaysia, 11800 USM, Penang (Malaysia); Lockman, Zainovia, E-mail: zainovia@eng.usm.my [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)

2014-03-05

Highlights: • WO{sub 3} nanorods with 5–10 nm diameter were grown directly on seeded tungsten foil. • WO{sub 3} nanorods were successfully grown at low temperature of 80 °C. • WO{sub 3} nanorods were grown on the entire surface of the seed layer after 24 h. • Annealed nanorods showed better electrochromic properties than as-made nanorods. -- Abstract: This work describes the first tungsten oxide (WO{sub 3}) nanorods hydrothermally grown on W foil. WO{sub 3} nanorods were successfully grown at low hydrothermal temperature of 80 °C by seeded growth hydrothermal reaction. The seed layer was prepared by thermally oxidized the W foil at 400 °C for 0.5 h. This work discusses the effect of hydrothermal reaction and annealing period on the morphological, structural, and electrochromic properties of WO{sub 3} nanorods. Various hydrothermal reaction periods (8–24 h) were studied. Monoclinic WO{sub 3} nanorods with 5–10 nm diameter were obtained after hydrothermal reaction for 24 h. These 24 h WO{sub 3} nanorods were also annealed at 400 °C with varying dwelling periods (0.5–4 h). Electrochromic properties of WO{sub 3} nanorods in an acidic electrolyte were analyzed using cyclic voltammetry and UV–vis spectrophotometry. WO{sub 3} nanorods annealed at 400 °C for 1 h showed the highest charge capacity and the largest optical contrast among the 24 h WO{sub 3} films. The sample also showed good cycling stability without significant degradation. Based on the results, the reaction mechanism of WO{sub 3} nanorod formation on W foil was proposed.

Hydrothermal processes in the Edmond deposits, slow- to intermediate-spreading Central Indian Ridge

Science.gov (United States)

Cao, Hong; Sun, Zhilei; Zhai, Shikui; Cao, Zhimin; Jiang, Xuejun; Huang, Wei; Wang, Libo; Zhang, Xilin; He, Yongjun

2018-04-01

The Edmond hydrothermal field, located on the Central Indian Ridge (CIR), has a distinct mineralization history owing to its unique magmatic, tectonic, and alteration processes. Here, we report the detailed mineralogical and geochemical characteristics of hydrothermal metal sulfides recovered from this area. Based on the mineralogical investigations, the Edmond hydrothermal deposits comprise of high-temperature Fe-rich massive sulfides, medium-temperature Zn-rich sulfide chimney and low-temperature Ca-rich sulfate mineral assemblages. According to these compositions, three distinctive mineralization stages have been identified: (1) low-temperature consisting largely of anhydrite and pyrite/marcasite; (2) medium-high temperature distinguished by the mineral assemblage of pyrite, sphalerite and chalcopyrite; and (3) low-temperature stage characterized by the mineral assemblage of colloidal pyrite/marcasite, barite, quartz, anglesite. Several lines of evidence suggest that the sulfides were influenced by pervasive low-temperature diffuse flows in this area. The hydrothermal deposits are relatively enriched in Fe (5.99-18.93 wt%), Zn (2.10-10.00 wt%) and Ca (0.02-19.15 wt%), but display low Cu (0.28-0.81 wt%). The mineralogical varieties and low metal content of sulfides in the Edmond hydrothermal field both indicate that extensive water circulation is prevalent below the Edmond hydrothermal field. With regard to trace elements, the contents of Pb, Ba, Sr, As, Au, Ag, and Cd are significantly higher than those in other sediment-starved mid-ocean ridges, which is indicative of contribution from felsic rock sources. Furthermore, the multiphase hydrothermal activity and the pervasive water circulation underneath are speculated to play important roles in element remobilization and enrichment. Our findings deepen our understanding about the complex mineralization process in slow- to intermediate-spreading ridges globally.

Hydrothermal synthesis of layered iron-chalcogenide superconductors and related compounds

International Nuclear Information System (INIS)

Pachmayr, Ursula Elisabeth

2017-01-01

This thesis provides a new preparative approach to iron-chalcogenide based superconductors. The hydrothermal synthesis of anti-PbO type FeSe, which can be seen as basis structure of the compounds of interest was successfully developed. Along with this, some insights regarding the influence of synthesis parameters were gained featuring a basis for further hydrothermal syntheses of new iron-chalcogenide compounds. The potential of this method, primarily the extension of the so far limited accessibility of iron-chalcogenide based superconductors by solid-state sythesis, was revealed within the present work. The solid-solution FeSe_1_-_xS_x was prepared for the whole substitution range, whereas solid-state synthesis exhibits a solubility limit at x = 0.3. Furthermore, the new compounds [(Li_0_._8Fe_0_._2)OH]FeX (X = Se, S) were synthesized which are exclusively accessible via hydrothermal method. The compounds, where layers of (Li_0_._8Fe_0_._2)OH alternate with FeX layers, feature exceptional physical properties, notably a coexistence of superconductivity and ferromagnetism. They were intensively studied within this work. By combination of solid-state and hydrothermal ion-exchange synthesis even large crystals necessary for subsequent physical measurements are accessible. Apart from these layered iron-chalcogenide superconductors, further compounds which likewise exhibit building blocks of edge-sharing FeSe_4 tetrahedra were found via this synthesis method. The iron selenides A_2Fe_4Se_6 (A = K, Rb, Cs) consist of double chains of [Fe_2Se_3]"1"-, whereas a new compound Na_6(H_2O)_1_8Fe_4Se_8 exhibits [Fe_4Se_8]"6"- 'stella quadrangula' clusters. This structural diversity as well as the associated physical properties of the compounds demonstrates the numerous capabilities of hydrothermal synthesis in the field of iron-chalcogenide compounds. In particular with regard to iron-chalcogenide based superconductors this synthesis strategy is encouraging. It seems probable

Hydrothermal synthesis of layered iron-chalcogenide superconductors and related compounds

Energy Technology Data Exchange (ETDEWEB)

Pachmayr, Ursula Elisabeth

2017-04-06

This thesis provides a new preparative approach to iron-chalcogenide based superconductors. The hydrothermal synthesis of anti-PbO type FeSe, which can be seen as basis structure of the compounds of interest was successfully developed. Along with this, some insights regarding the influence of synthesis parameters were gained featuring a basis for further hydrothermal syntheses of new iron-chalcogenide compounds. The potential of this method, primarily the extension of the so far limited accessibility of iron-chalcogenide based superconductors by solid-state sythesis, was revealed within the present work. The solid-solution FeSe{sub 1-x}S{sub x} was prepared for the whole substitution range, whereas solid-state synthesis exhibits a solubility limit at x = 0.3. Furthermore, the new compounds [(Li{sub 0.8}Fe{sub 0.2})OH]FeX (X = Se, S) were synthesized which are exclusively accessible via hydrothermal method. The compounds, where layers of (Li{sub 0.8}Fe{sub 0.2})OH alternate with FeX layers, feature exceptional physical properties, notably a coexistence of superconductivity and ferromagnetism. They were intensively studied within this work. By combination of solid-state and hydrothermal ion-exchange synthesis even large crystals necessary for subsequent physical measurements are accessible. Apart from these layered iron-chalcogenide superconductors, further compounds which likewise exhibit building blocks of edge-sharing FeSe{sub 4} tetrahedra were found via this synthesis method. The iron selenides A{sub 2}Fe{sub 4}Se{sub 6} (A = K, Rb, Cs) consist of double chains of [Fe{sub 2}Se{sub 3}]{sup 1-}, whereas a new compound Na{sub 6}(H{sub 2}O){sub 18}Fe{sub 4}Se{sub 8} exhibits [Fe{sub 4}Se{sub 8}]{sup 6-} 'stella quadrangula' clusters. This structural diversity as well as the associated physical properties of the compounds demonstrates the numerous capabilities of hydrothermal synthesis in the field of iron-chalcogenide compounds. In particular with regard

PATRONES DE CONSUMO FINAL DE CÉRVIDOS EN EL PARANÁ MEDIO: EL CASO DEL SITIO CERRO AGUARÁ / Cervids final consumption patterns in middle Paraná River: the case of Cerro Aguará archaeological site

Directory of Open Access Journals (Sweden)

Leonardo Mucciolo

2015-06-01

Full Text Available Los cérvidos fueron amplia y regularmente explotados por los cazadores-recolectores que habitaron la macroregión del Paraná-Plata durante el Holoceno tardío. En la cuenca media del Paraná, sin embargo, muy pocos estudios han enfocado sobre las estrategias empleadas para su obtención, procesamiento y consumo. Teniendo en cuenta esto, el objetivo de este trabajo es explorar dichos aspectos a partir del análisis de los conjuntos de cérvidos provenientes del sitio arqueológico Cerro Aguará, localizado en el departamento General Obligado (provincia de Santa Fe. La perspectiva seleccionada propone al consumo como factor preponderante en la configuración del registro zooarqueológico dentro del continuum de actividades que componen la explotación faunística. Desde esta perspectiva, y tomando en consideración que las carcasas de los cérvidos proveen distintos tipos de recursos alimenticios con diferentes costos de extracción (carne, médula y grasa ósea, se evalúan diferentes indicadores para establecer si existió diferente intensidad en su procesamiento. Los resultados indican que las dos especies de cérvidos identificadas en el sitio, Blastocerus dichotomus y Ozotoceros bezoarticus, ocuparon un rol preponderante en la dieta, aunque las carcasas del primero fueron empleadas más intensivamente probablemente en correlación con su mayor disponibilidad de nutrientes internos, tales como la médula y posiblemente la grasa ósea.  Abstract  Cervids were wide and regularly exploited by several Late Holocene hunter-gatherers inhabiting Paraná Plata macroregion. In the middle Paraná river, however, few research has been made on strategies involving their procurement, processing and consumption. The purpose of this article is to explore those aspects from the analysis of cervid assemblages of Cerro Aguará archaeological site (General Obligado, Santa Fe province. The selected perspective proposes final consumption as one of the most

Optical and infrared observations of SN 1987A from Cerro Tololo Inter-American Observatory

International Nuclear Information System (INIS)

Phillips, M.M.

1988-01-01

Results from optical and infrared observations of SN 1987A obtained at Cerro Tololo Inter-American Observatory over the first seven months since core collapse are reviewed. Around 130 days after outburst, the bolometric light curve began to smoothly decline at a rate of ∼ 0.01 mag day-1, providing dramatic confirmation of the prediction that radioactivity had powered the optical display after the first month./ the peculiar color changes are kinks observed beginning on the 25th day probably signaled the initial release of trapped energy from mass 56 material. The bolometric luminosity of SN 1987A was unusually low at first, but reached a value more typical of other type II supernovae by the time that the final exponential decline had begun. Over much of the period covered by these observations, the optical and infrared spectra were characterized by strong absorption lines of Ba II and Sr II. Comparison with the spectra of other type II supernovae at similar stages of evolution supports the suggestion that s-processed elements were enriched in the hydrogen envelope of the progenitor, Sanduleak - 69 degrees 202

3-cerro y 4-mundo: los números del banquete en las ofrendas quechuas

Directory of Open Access Journals (Sweden)

David Lorente Fernández

2010-12-01

Full Text Available Las ofrendas quechuas del sur del Perú son platos alimenticios, banquetes destinados principalmente a la pachamama y los apus, pero también elaborados sistemas matemáticos regidos por operaciones sofisticadas. Sirviéndose de dos números fundamentales, el 3 y el 4, los especialistas rituales son capaces de transmitir mensajes polisémicos. Mediante el número 3 aglutinan clientes, parajes y cerros, en suma, «personas» capaces de interactuar entre sí. El 3 aparece en los k’intus de hojas de coca y en las oraciones que se recitan durante el proceso de realizar la ofrenda. Por el contrario, el número 4 no indica relaciones sino formas espaciales: es un operador geométrico que unifica la servilleta ceremonial (unk’uña, el papel envoltorio y el paquete acabado para representar las cuatro direcciones del mundo y hacer de la ofrenda un mundo en miniatura. Gracias a los dos números el ritualista puede recrear el cosmos, establecer convenios con los dioses y definir nuevas situaciones favorables para la vida de sus clientes.

Comportamiento del asma bronquial en un área de salud del policlínico Cerro Behavior of bronchial asthma in a health area of the "Cerro" polyclinic

Directory of Open Access Journals (Sweden)

Marlene Álvarez Carmenate

2011-03-01

Full Text Available Introducción: el asma bronquial es la enfermedad crónica más frecuente en pediatría y una de las principales causas de consulta. Objetivo: describir el comportamiento del asma bronquial como problema de salud. Métodos: trabajo descriptivo, prospectivo, de corte longitudinal, en 309 niños con edades comprendidas entre 0 y 19 años con el diagnóstico de asma bronquial, atendidos en los 15 consultorios médicos del grupo básico de trabajo A del policlínico universitario "Cerro", en el período comprendido entre el 1º de enero de 2007 y el 31 de diciembre de 2007. Método empírico para la obtención de los datos clínicos epidemiológicos, y como técnica, la encuesta a través de un cuestionario. Resultados: 148 pacientes (48 % se encontraban entre 10 y 14 años, 175 (56,6 % del sexo masculino, 136 (44 % fueron clasificados como persistentes ligeros, 140 (58 % presentaron rinitis y 57 (24 % dermatitis. Había fumadores en las viviendas de 303 pacientes (98 %, hacinamiento en 290 casos (94 % y el polvo en el hogar 284 (92 %. Conclusiones: predominio en el grupo de edades de 10 a 14 años, sexo masculino. En cuanto a la severidad de la enfermedad predominó la forma persistente ligera, las manifestaciones atópicas más frecuentes fueron la rinitis y la dermatitis, los principales factores de riesgo fueron el humo del tabaco, el polvo en el hogar y el hacinamiento, y el tratamiento de elección fue el de la crisis. Se observó la falta de organización y unidad de criterios para el enfoque integral de la política intercrisis o de sostén en la atención de los pacientes.Introduction: bronchial asthma is the more frequent chronic disease in Pediatrics and one of the major causes of consultation. Objective: to describe the behavior of bronchial asthma as a health problem. Methods: a longitudinal, prospective and descriptive study was conducted in 309 children aged between 0 and 19 diagnosed with bronchial asthmas seen in the 15 medical

Report about drilling works made in 13 Anomaly de Taylor and in the N- NE of its, around Fraile Muerto (Cerro Largo district): Uranium project[Study of Uranium prospection in Uruguay]; Informe sobre los trabajos de perforacion efectuados en la Anomalia 13 de Taylor y al N-NE de la misma , en los alrededores de Fraile Muerto (Departamento de Cerro Largo). Proyecto Uranio

Energy Technology Data Exchange (ETDEWEB)

Massa, J; Pirelli, H

1983-07-01

The perforations were carried out to investigate in depth denominated anomaly 13 detected during the Taylor Mission (1975) and extended the punch area of study during you are suitable DINAMIGE-BRGM (Project the present report details the activities realised in the environs Fraile Muerto (Cerro Largo district) by the command team of perforations of the uranium project. Previously and contemporarily to the executed works, prospection became geophysical ground geochemistry geology and, works. (Uranium)

Hydrothermal activity, functional diversity and chemoautotrophy are major drivers of seafloor carbon cycling

NARCIS (Netherlands)

Bell, J.B.; Woulds, C.; van Oevelen, D.

2017-01-01

Hydrothermal vents are highly dynamic ecosystems and are unusually energy rich in the deep-sea. Insitu hydrothermal-based productivity combined with sinking photosynthetic organic matter in a softsedimentsetting creates geochemically diverse environments, which remain poorly studied. Here,we use

Charnockitic ortho gneisses and mafic granulites of Cerro Olivo complex, proterozoic basement of SE Uruguay, Part 1: Geology

International Nuclear Information System (INIS)

Masquelin, H.

2008-01-01

Charnockitic ortho gneisses and mafic granulite s exposed in the Cerro Bori Block, in the center of Punta del Este terrain, were the first document occurrence of granulitic rocks from SE sector of the Uruguayan Shield. We present here their main geological features, with the purpose to suggest some petrologic and structural interesting problems for a future lithogeochemical, mineral chemistry, stable isotopes and fluid inclusion studies about these rocks. We propose some speculation form field-based studies considering a cognate magmatic origin of both kinds of rocks, previous to a homogeneous granulitic metamorphism. Some structural evidences indicate that after their uplift, these rocks were located on over thickened crust, at great to medium deepness. A cataclasis during anatexis and amphibolite-facies mineral association stabilization are common phenomena. Other evidences suggest a polycyclic character for the regional geologic evolution

rights reserved Geophysical Identification of Hydrothermally Altered

African Journals Online (AJOL)

ADOWIE PERE

Geophysical Identification of Hydrothermally Altered Structures That Favour .... aircraft. Total line kilometers of 36,500 were covered in the survey. Magnetic ... tie lines occur at about 2000 metres interval in the ... visual inspection of the map.

Unveiling the transformation and bioavailability of dissolved organic matter in contrasting hydrothermal vents using fluorescence EEM-PARAFAC.

Science.gov (United States)

Yang, Liyang; Zhuang, Wan-E; Chen, Chen-Tung Arthur; Wang, Bing-Jye; Kuo, Fu-Wen

2017-03-15

The submarine hydrothermal systems are extreme environments where active cycling of dissolved organic matter (DOM) may occur. However, little is known about the optical properties and bioavailability of hydrothermal DOM, which could provide valuable insights into its transformation processes and biogeochemical reactivity. The quantity, quality, and bioavailability of DOM were investigated for four very different hydrothermal vents east of Taiwan, using dissolved organic carbon (DOC), absorption spectroscopy, and fluorescence excitation-emission matrices-parallel factor analysis (EEM-PARAFAC). The DOC and absorption coefficient a 280 were both lower in the two hydrothermal vents off the Orchid Island and on the Green Island than in the surrounding seawater and the two vents off the Kueishantao Island, indicating effective removals of DOM in the former two hydrothermal systems owing to possible adsorption/co-precipitation and thermal degradation respectively. The four hydrothermal DOM showed notable differences in the absorption spectral slope S 275-295 , humification index HIX, biological index BIX, EEM spectra, and the relative distributions of seven PARAFAC components. The results demonstrated a high diversity of chemical composition and transformation history of DOM under contrasting hydrothermal conditions. The little change in the hydrothermal DOC after 28-day microbial incubations indicated a low bioavailability of the bulk DOM, and different PARAFAC components showed contrasting bioavailability. The results have profound implications for understanding the biogeochemical cycling and environmental effects of hydrothermal DOM in the marine environments. Copyright © 2017 Elsevier Ltd. All rights reserved.

Role of triton X-100 and hydrothermal treatment on the morphological features of nanoporous hydroxyapatite nanorods

Energy Technology Data Exchange (ETDEWEB)

Iyyappan, E.; Wilson, P., E-mail: catwils@gmail.com; Sheela, K.; Ramya, R.

2016-06-01

Hydroxyapatite (HA) particles were synthesized using Ca(NO{sub 3}){sub 2}·4H{sub 2}O and (NH{sub 4}){sub 2}HPO{sub 4} as precursors with varying contents of non-ionic surfactant viz., triton X-100 (organic modifier) via co-precipitation method followed by hydrothermal treatment. The prepared HA particles have been characterized by X-ray diffraction (XRD), Fourier Transform Infrared spectroscopy (FT-IR), Energy Dispersive X-ray Analysis (EDX), High Resolution Scanning Electron Microscopy (HRSEM), High Resolution Transmission Electron Microscopy (HRTEM) and Nitrogen adsorption–desorption experiments. The XRD and FTIR studies indicate the formation of HA phase in all the synthesized samples. The specific roles of triton X-100 and hydrothermal treatment in dispersing and in directing the crystal growth respectively have been discussed by comparing the observations from individual experiments using triton X-100 and hydrothermal treatment with that of combined protocol involving both. The plausible mechanism for the individual roles of both triton X-100 and hydrothermal treatment have been proposed. - Highlights: • Nanoporous HA nanorods are synthesized via triton X-100 assisted hydrothermal treatment. • Triton X-100 hinder the agglomeration of HA primary particles • Hydrothermal treatment increase the aspect ratio of the HA particles • Oriented attachment of HA particles occurs under hydrothermal treatment facilitated by triton X-100 stabilized HA collides • The percentage of mesopore volume is higher for hydrothermally treated samples.

Inversion Approach For Thermal Data From A Convecting Hydrothermal System

Energy Technology Data Exchange (ETDEWEB)

Kasameyer, P.; Younker, L.; Hanson, J.

1985-01-01

Hydrothermal systems are often studied by collecting thermal gradient data and temperature depth curves. These data contain important information about the flow field, the evolution of the hydrothermal system, and the location and nature of the ultimate heat sources. Thermal data are conventionally interpreted by the ''forward'' method; the thermal field is calculated based on selected initial conditions and boundary conditions such as temperature and permeability distributions. If the calculated thermal field matches the data, the chosen conditions are inferred to be possibly correct. Because many sets of initial conditions may produce similar thermal fields, users of the ''forward'' method may inadvertently miss the correct set of initial conditions. Analytical methods for ''inverting'' data also allow the determination of all the possible solutions consistent with the definition of the problem. In this paper we suggest an approach for inverting thermal data from a hydrothermal system, and compare it to the more conventional approach. We illustrate the difference in the methods by comparing their application to the Salton Sea Geothermal Field by Lau (1980a) and Kasameyer, et al. (1984). In this particular example, the inverse method was used to draw conclusions about the age and total rate of fluid flow into the hydrothermal system.

Origin of Magnetism in Hydrothermally Aged 2-Line Ferrihydrite Suspensions.

Science.gov (United States)

Cao, Liang; Jiang, Zhao-Xia; Du, Yong-Hua; Yin, Xin-Mao; Xi, Shi-Bo; Wen, Wen; Roberts, Andrew P; Wee, Andrew T S; Xiong, Yi-Min; Liu, Qing-Song; Gao, Xing-Yu

2017-03-07

As an iron oxyhydroxide, nanosized ferrihydrite (Fh) is important in Earth science, biology, and industrial applications. However, its basic structure and origin of its magnetism have long been debated. We integrate synchrotron-based techniques to explore the chemical structures of 2-line ferrihydrite and to determine the origin of its magnetism during hydrothermal aging in air. Our results demonstrate that both the magnetism and X-ray magnetic circular dichroism (XMCD) signal of 2-line ferrihydrite are enhanced with aging time, and that XMCD spectral patterns resemble that of maghemite (γ-Fe 2 O 3 ) rather than magnetite (Fe 3 O 4 ). Fe L-edge and K-edge X-ray absorption spectroscopy (XAS) further indicate formation of both maghemite and hematite (α-Fe 2 O 3 ) with increasing concentrations with longer hydrothermal aging time. Thus, magnetic enhancement with longer hydrothermal aging time is attributed to increasing maghemite concentration instead of a magnetically ordered ferrihydrite as previously reported. Moreover, L-edge and K-edge XAS spectra with different probing depths yield different ratios of these Fe oxides, which suggest the formation of a core (ferrihydrite-rich)-shell (with a mixture of both allotropes; α-Fe 2 O 3 and γ-Fe 2 O 3 ) structure during hydrothermal aging. Our results provide insights into the chemical evolution of 2-line ferrihydrite that reveal unambiguously the origin of its magnetism.

Self-excited hydrothermal waves in evaporating sessile drops

Science.gov (United States)

Sefiane, K.; Moffat, J. R.; Matar, O. K.; Craster, R. V.

2008-08-01

Pattern formation driven by the spontaneous evaporation of sessile drops of methanol, ethanol, and FC-72 using infrared thermography is observed and, in certain cases, interpreted in terms of hydrothermal waves. Both methanol and ethanol drops exhibit thermal wave trains, whose wave number depends strongly on the liquid volatililty and substrate thermal conductivity. The FC-72 drops develop cellular structures whose size is proportional to the local thickness. Prior to this work, hydrothermal waves have been observed in the absence of evaporation in shallow liquid layers subjected to an imposed temperature gradient. In contrast, here both the temperature gradients and the drop thickness vary spatially and temporally and are a natural consequence of the evaporation process.

Porosity evolution in Icelandic hydrothermal systems

Science.gov (United States)

Thien, B.; Kosakowski, G.; Kulik, D. A.

2014-12-01

Mineralogical alteration of reservoir rocks, driven by fluid circulation in natural or enhanced hydrothermal systems, is likely to influence the long-term performance of geothermal power generation. A key factor is the change of porosity due to dissolution of primary minerals and precipitation of secondary phases. Porosity changes will affect fluid circulation and solute transport, which, in turn, influence mineralogical alteration. This study is part of the Sinergia COTHERM project (COmbined hydrological, geochemical and geophysical modeling of geotTHERMal systems, grant number CRSII2_141843/1) that is an integrative research project aimed at improving our understanding of the sub-surface processes in magmatically-driven natural geothermal systems. These are typically high enthalphy systems where a magmatic pluton is located at a few kilometers depth. These shallow plutons increase the geothermal gradient and trigger the circulation of hydrothermal waters with a steam cap forming at shallow depth. Field observations suggest that active and fossil Icelandic hydrothermal systems are built from a superposition of completely altered and completely unaltered layers. With help of 1D and 2D reactive transport models (OpenGeoSys-GEM code), we investigate the reasons for this finding, by studying the mineralogical evolution of protoliths with different initial porosities at different temperatures and pressures, different leaching water composition and gas content, and different porosity geometries (i.e. porous medium versus fractured medium). From this study, we believe that the initial porosity of protoliths and volume changes due to their transformation into secondary minerals are key factors to explain the different alteration extents observed in field studies. We also discuss how precipitation and dissolution kinetics can influence the alteration time scales.

Evaluation of the Cerro Solo nuclear ore, province of Chubut. On the economic parameters of the deposit. Pt. 3

International Nuclear Information System (INIS)

Navarra, P.R.; Sardin, P.G.; Urquiza, L.; Bernal, G.J.; Guzman Lobos, D.

1993-01-01

Preliminary results of the resources estimation carried out in the Cerro Solo uranium ore deposit, located in the Chubut Province, 1900 km SW from Buenos Aires and 380 Km W from Trelew, presented in tonnes of uranium recoverable at costs up to U$S 80/kgU, are as follows: a) Reasonable assured resources (indicated): 800 tU; b) Estimates Additional Resources (inferred): 2200 tU. Economic evaluation at the order-of-magnitude level, performed using the grade-tonnage model of the deposit, resulted a useful tool in the different stages of the project to identify the influence of technical parameters on the potential profitability. Research about feasibility of in-situ leaching method of exploitation for this deposit introduces an interesting alternative for future uranium production in the country. (Author)

Sediment Microbial Communities Influenced by Cool Hydrothermal Fluid Migration

Directory of Open Access Journals (Sweden)

Laura A. Zinke

2018-06-01

Full Text Available Cool hydrothermal systems (CHSs are prevalent across the seafloor and discharge fluid volumes that rival oceanic input from rivers, yet the microbial ecology of these systems are poorly constrained. The Dorado Outcrop on the ridge flank of the Cocos Plate in the northeastern tropical Pacific Ocean is the first confirmed CHS, discharging minimally altered <15°C fluid from the shallow lithosphere through diffuse venting and seepage. In this paper, we characterize the resident sediment microbial communities influenced by cool hydrothermal advection, which is evident from nitrate and oxygen concentrations. 16S rRNA gene sequencing revealed that Thaumarchaea, Proteobacteria, and Planctomycetes were the most abundant phyla in all sediments across the system regardless of influence from seepage. Members of the Thaumarchaeota (Marine Group I, Alphaproteobacteria (Rhodospirillales, Nitrospirae, Nitrospina, Acidobacteria, and Gemmatimonadetes were enriched in the sediments influenced by CHS advection. Of the various geochemical parameters investigated, nitrate concentrations correlated best with microbial community structure, indicating structuring based on seepage of nitrate-rich fluids. A comparison of microbial communities from hydrothermal sediments, seafloor basalts, and local seawater at Dorado Outcrop showed differences that highlight the distinct niche space in CHS. Sediment microbial communities from Dorado Outcrop differ from those at previously characterized, warmer CHS sediment, but are similar to deep-sea sediment habitats with surficial ferromanganese nodules, such as the Clarion Clipperton Zone. We conclude that cool hydrothermal venting at seafloor outcrops can alter the local sedimentary oxidation–reduction pathways, which in turn influences the microbial communities within the fluid discharge affected sediment.

Age and kinematics of ductile deformation in the Cerro Durazno area, NW Argentina: Significance for orogenic processes operating at the western margin of Gondwana during Ordovician-Silurian times

OpenAIRE

M. I. Wegmann; U. Riller; F. D. Hongn; Johannes Glodny; Onno Oncken

2008-01-01

The Cerro Durazno Pluton belongs to a suite of Paleozoic granitoid intrusions in NWArgentina, that are central for understanding the tectonic setting of the western margin of Gondwana in Ordovician and Silurian times. The pluton and its host rocks were tectonically overprinted by metamorphic mineral shape fabrics formed under middle greenschist-facies metamorphic conditions and associated with the nearby Agua Rosada Shear Zone. Kinematic analysis of the shear zone based on the geometric relat...

Moessbauer spectroscopy study on the hydrothermal transformation α-FeOOH → α-Fe2O3

International Nuclear Information System (INIS)

Barb, D.; Diamandescu, L.; Mihaila-Tarabsanu, D.; Rusi, A.; Moraria, M.

1990-01-01

The reaction kinetics of the hydrothermal transformation α-FeOOH→α-Fe 2 O 3 was studied by means of Moessbauer spectroscopy. From the reaction isotherms, a monomolecular, first order reaction was found to characterise the hydrothermal transformation of alpha oxihydroxide to the alpha iron oxide. The rate constant as well as the activation energy of this process were determined. No intermediate phases were identified in the hydrothermal samples. The thermodynamic properties of the hydrothermal system α-FeOOH→α-Fe 2 O 3 in correlation with Moessbauer spectroscopy data are discussed. (orig.)

IMPACT OF ADDITIONALS CONTAMINANTS DUE TO ACID MINE DRAINAGE IN TRIBUTARIES OF THE PILCOMAYO RIVER FROM CERRO RICO, POTOSÍ, BOLIVIA

Directory of Open Access Journals (Sweden)

William H.J. Strosnider

2014-09-01

Full Text Available Intensive mining and processing of the polymetallic sulfide ore body of Cerro Rico de Potosí (Bolivia has occurred since 1545. To further investigate acid mine drainage (AMD discharges and their link to downstream contamination, data were gathered during two sampling events during the most extreme periods of the dry and wet seasons of one year. Concentrations of Ag, B, Ba, Mo, Sb, Se, Sn and V in AMD and receiving streams were greater than Bolivian discharge limits and receiving water body guidelines as well as international agricultural use standards. High concentrations of rare earth metals have been documented in this area. Results indicate that contamination from mining has a larger scope than previously thought and underscore the importance of remediation.

Effect of hydrothermal modification on the structure of REY zeolite studied by PAS

International Nuclear Information System (INIS)

Zhu Jun; Wang Shaojie

2003-01-01

The effect of temperature of the hydrothermal modification on the structure of Rare-earth Y zeolite (REY) was studied by positron annihilation spectroscopy. We measured the positron lifetime spectrum as a function of the temperature (300-800 degree C) of one hour hydrothermal modification for the REY zeolite after through pre-heated dehydration at 150 degree C. All lifetime spectra could be resolved into five components. The fifth lifetime component and its intensity were found to be related to the size and number of the secondary pores. The experimental results showed that the secondary pore in REY zeolite was produced by hydrothermal modification in some temperature range, and the largest size and the greatest quantity of the secondary pores were observed in the sample treated at 500 degree C for 1 hour. The effect of hydrothermal modification on REY zeolite without pre-heated dehydration was also discussed

Metal concentration and structural changes in Corallina elongata (Corallinales, Rhodophyta) from hydrothermal vents

International Nuclear Information System (INIS)

Couto, Ruben P.; Neto, Ana I.; Rodrigues, Armindo S.

2010-01-01

Shallow-water hydrothermal activity is widely present at Azores archipelago. Organisms in such environments present great potential as sentinels of the effects derived from chronically exposure to increased temperature, metal concentrations and reduced pH. This study aimed to evaluate metal concentration in Corallina elongata collected at locations exposed and not exposed to shallow-water hydrothermal activity and evaluate changes in its calcareous structure. Elemental concentration was determined and morphometric analysis was performed by scanning electron microscopy. Thicker cell walls and a bleached appearance were observed on C. elongata specimens from the hydrothermally active location, as well as increased concentrations of elements associated to volcanic activity. This study reports on metal accumulation and morphometric changes in the calcareous structure of C. elongata from a hydrothermally active location, adding new data for further research on such habitats and communities, providing an insight on how coralline algae might be affected by ocean acidification.

Primary Formation Path of Formaldehyde in Hydrothermal Vents

Science.gov (United States)

Inaba, Satoshi

2018-03-01

Formaldehyde is abundant in the universe and one of the fundamental molecules for life. Hydrothermal vents produce a substantial amount of hydrogen molecules by serpentinization and promote reductive reactions of single carbon compounds. The abundance of formaldehyde is expected to be low due to the high Gibbs free energy in hydrothermal vents. We consider two competing formation pathways of formaldehyde: (1) the reduction of CO by H2 and (2) the reduction of HCOOH by H2 to form a methanediol, followed by the dehydration of the methanediol. We performed a number of quantum chemical simulations to examine the formation of formaldehyde in the gas phase as well as in aqueous solution. The energy barrier is significantly reduced by the catalytic effect of water molecules in aqueous solution and becomes lowest when a water cluster consisted of 5 water molecules catalyzes the reduction. The energy barrier to form a methanediol by the reduction of HCOOH is lower by 17.5 kcal/mol than that to form a formaldehyde by the reduction of CO. Considering the low energy barrier to dehydrate methanediol, the primary pathway to form formaldehyde in hydrothermal vents is concluded to be the reduction of HCOOH by H2, followed by the dehydration of methanediol.

A simulation of the hydrothermal response to the Chesapeake Bay bolide impact

Science.gov (United States)

Sanford, W.E.

2005-01-01

Groundwater more saline than seawater has been discovered in the tsunami breccia of the Chesapeake Bay impact Crater. One hypothesis for the origin of this brine is that it may be a liquid residual following steam separation in a hydrothermal system that evolved following the impact. Initial scoping calculations have demonstrated that it is feasible such a residual brine could have remained in the crater for the 35 million years since impact. Numerical simulations have been conducted using the code HYDROTHERM to test whether or not conditions were suitable in the millennia following the impact for the development of a steam phase in the hydrothermal system. Hydraulic and thermal parameters were estimated for the bedrock underlying the crater and the tsunami breccia that fills the crater. Simulations at three different breccia permeabilities suggest that the type of hydrothermal system that might have developed would have been very sensitive to the permeability. A relatively low breccia permeability (1 ?? 10-16 m2) results in a system partitioned into a shallow water phase and a deeper superheated steam phase. A moderate breccia permeability (1 ?? 10-15 m2 ) results in a system with regionally extensive multiphase conditions. A relatively high breccia permeability (1 ?? 10-14 m2 ) results in a system dominated by warm-water convection cells. The permeability of the crater breccia could have had any of these values at given depths and times during the hydrothermal system evolution as the sediments compacted. The simulations were not able to take into account transient permeability conditions, or equations of state that account for the salt content of seawater. Results suggest, however, that it is likely that steam conditions existed at some time in the system following impact, providing additional evidence that is consistent with a hydrothermal origin for the crater brine. ?? Blackwell Publishing Ltd.

Geophysical image of the hydrothermal system of Merapi volcano

Science.gov (United States)

Byrdina, S.; Friedel, S.; Vandemeulebrouck, J.; Budi-Santoso, A.; Suhari; Suryanto, W.; Rizal, M. H.; Winata, E.; Kusdaryanto

2017-01-01

We present an image of the hydrothermal system of Merapi volcano based on results from electrical resistivity tomography (ERT), self-potential, and CO2 flux mappings. The ERT models identify two distinct low-resistivity bodies interpreted as two parts of a probably interconnected hydrothermal system: at the base of the south flank and in the summit area. In the summit area, a sharp resistivity contrast at ancient crater rim Pasar-Bubar separates a conductive hydrothermal system (20-50 Ω m) from the resistive andesite lava flows and pyroclastic deposits (2000-50,000 Ω m). The existence of preferential fluid circulation along this ancient crater rim is also evidenced by self-potential data. The significative diffuse CO2 degassing (with a median value of 400 g m-2 d-1) is observed in a narrow vicinity of the active crater rim and close to the ancient rim of Pasar-Bubar. The total CO2 degassing across the accessible summital area with a surface of 1.4 ṡ 105 m2 is around 20 t d-1. Before the 2010 eruption, Toutain et al. (2009) estimated a higher value of the total diffuse degassing from the summit area (about 200-230 t d-1). This drop in the diffuse degassing from the summit area can be related to the decrease in the magmatic activity, to the change of the summit morphology, to the approximations used by Toutain et al. (2009), or, more likely, to a combination of these factors. On the south flank of Merapi, the resistivity model shows spectacular stratification. While surficial recent andesite lava flows are characterized by resistivity exceeding 100,000 Ω m, resistivity as low as 10 Ω m has been encountered at a depth of 200 m at the base of the south flank and was interpreted as a presence of the hydrothermal system. No evidence of the hydrothermal system is found on the basis of the north flank at the same depth. This asymmetry might be caused by the asymmetry of the heat supply source of Merapi whose activity is moving south or/and to the asymmetry in

Facile template-free hydrothermal synthesis and microstrain ...

Indian Academy of Sciences (India)

Administrator

2009), solar cells (Yuan et al 2011), transparent elec- trodes (Kim et al ... increasing the peak width, intensity and shifting the 2θ peak position. ... Facile template-free hydrothermal synthesis and microstrain measurement of ZnO nanorods. 399.

Hydrothermal Synthesis of Hydroxyapatite Nanorods for Rapid Formation of Bone-Like Mineralization

Science.gov (United States)

Hoai, Tran Thanh; Nga, Nguyen Kim; Giang, Luu Truong; Huy, Tran Quang; Tuan, Phan Nguyen Minh; Binh, Bui Thi Thanh

2017-08-01

Hydroxyapatite (HAp) is an excellent biomaterial for bone repair and regeneration. The biological functions of HAp particles, such as biomineralization, cell adhesion, and cell proliferation, can be enhanced when their size is reduced to the nanoscale. In this work, HAp nanoparticles were synthesized by the hydrothermal technique with addition of cetyltrimethylammonium bromide (CTAB). These particles were also characterized, and their size controlled by modifying the CTAB concentration and hydrothermal duration. The results show that most HAp nanoparticles were rod-like in shape, exhibiting the most uniform and smallest size (mean diameter and length of 39 nm and 125 nm, respectively) at optimal conditions of 0.64 g CTAB and hydrothermal duration of 12 h. Moreover, good biomineralization capability of the HAp nanorods was confirmed through in vitro tests in simulated body fluid. A bone-like mineral layer of synthesized HAp nanorods formed rapidly after 7 days. This study shows that highly bioactive HAp nanorods can be easily prepared by the hydrothermal method, being a potential nanomaterial for bone regeneration.

Hydrothermal behaviors and long-term stability of bentonitic buffer material

International Nuclear Information System (INIS)

Lee, Jae Owan; Cho, Won Jin

2007-01-01

In hydrothermal reaction tests, smectite-to-illite conversion was identified using a domestic bentonite which is favorably considered as a buffer material, and its dependency on various hydrothermal conditions was investigated. The analysis results of the XRD and Si concentration indicated that the smectite-to- illite conversion was a major process of bentonite alteration under the hydrothermal conditions. The temperature, potassium concentration in solution, and pH were observed to significantly affect the smectite-to illite conversion. A model of conversion reaction rate was suggested evaluate the long-term stability of smectite composing a major constituent of bentonitic buffer. It was expected from the evaluation results that the smectite would keep its integrity for very long disposal time under a normal condition, while as it might be converted to illite by 50 percent after over 5 x 10 4 year of disposal time under a conservative condition and consequently lose its swelling capacity as a buffer material of a repository

Exploratory benefit-cost analysis of environmental controls on hydrothermal energy

Energy Technology Data Exchange (ETDEWEB)

Scott, M.J.; Wells, K.D.; Currie, J.W.; King, M.J.

1981-02-01

A study of the value of environmental benefits generated by environmental regulation of hydrothermal sites was initiated to compare these benefits with the estimated costs of regulation. Primary objectives were to 1) evaluate the environmental damages caused by unregulated hydrothermal resource development, 2) use existing environmental and economic data to estimate the dollar value of preventing expected environmental damages at two sites, and 3) compare the benefits and costs of preventing the damages. The sites chosen for analyses were in the Imperial Valley at Heber and Niland, California. Reasons for this choice were 1) there is a high level of commercial interest in developing the Heber known geothermal resource area (KGRA) and the Salton Sea KGRA; 2) the potential for environmental damage is high; 3) existing data bases for these two sites are more comprehensive than at other sites. The primary impacts analyzed were those related to hydrogen sulfide (H/sub 2/S) emissions and those related to disposal of spent hydrothermal brine. (MHR)

Rare Earth Oxide Fluoride Nanoparticles And Hydrothermal Method For Forming Nanoparticles

Science.gov (United States)

Fulton, John L.; Hoffmann, Markus M.

2003-12-23

A hydrothermal method for forming nanoparticles of a rare earth element, oxygen and fluorine has been discovered. Nanoparticles comprising a rare earth element, oxygen and fluorine are also described. These nanoparticles can exhibit excellent refractory properties as well as remarkable stability in hydrothermal conditions. The nanoparticles can exhibit excellent properties for numerous applications including fiber reinforcement of ceramic composites, catalyst supports, and corrosion resistant coatings for high-temperature aqueous solutions.

Controllable synthesis of α- and β-MnO2: cationic effect on hydrothermal crystallization

International Nuclear Information System (INIS)

Huang Xingkang; Lv Dongping; Yue Hongjun; Attia, Adel; Yang Yong

2008-01-01

α- and β-MnO 2 were controllably synthesized by hydrothermally treating amorphous MnO 2 obtained via a reaction between Mn 2+ and MnO 4 - , and cationic effects on the hydrothermal crystallization of MnO 2 were investigated systematically. The crystallization is believed to proceed by a dissolution-recrystallization mechanism; i.e. amorphous MnO 2 dissolves first under hydrothermal conditions, then condenses to recrystallize, and the polymorphs formed are significantly affected by added cations such as K + , NH 4 + and H + in the hydrothermal systems. The experimental results showed that K + /NH 4 + were in competition with H + to form polymorphs of α- and β-MnO 2 , i.e., higher relative K + /NH 4 + concentration favoured α-MnO 2 , while higher relative H + concentration favoured β-MnO 2

Thallium isotope variations in seawater and hydrogenetic, diagenetic, and hydrothermal ferromanganese deposits

Science.gov (United States)

Rehkamper, M.; Frank, M.; Hein, J.R.; Porcelli, D.; Halliday, A.; Ingri, J.; Liebetrau, V.

2002-01-01

Results are presented for the first in-depth investigation of TI isotope variations in marine materials. The TI isotopic measurements were conducted by multiple collector-inductively coupled plasma mass spectrometry for a comprehensive suite of hydrogenetic ferromanganese crusts, diagenetic Fe-Mn nodules, hydrothermal manganese deposits and seawater samples. The natural variability of TI isotope compositions in these samples exceeds the analytical reproducibility (?? 0.05???) by more than a factor of 40. Hydrogenetic Fe-Mn crusts have ??205TI of + 10 to + 14, whereas seawater is characterized by values as low as -8 (??205TI represents the deviation of the 205TI/203TI ratio of a sample from the NIST SRM 997 TI isotope standard in parts per 104). This ~ 2??? difference in isotope composition is thought to result from the isotope fractionation that accompanies the adsorption of TI onto ferromanganese particles. An equilibrium fractionation factor of ?? ~ 1.0021 is calculated for this process. Ferromanganese nodules and hydrothermal manganese deposits have variable TI isotope compositions that range between the values obtained for seawater and hydrogenetic Fe-Mn crusts. The variability in ??205TI in diagenetic nodules appears to be caused by the adsorption of TI from pore fluids, which act as a closed-system reservoir with a TI isotope composition that is inferred to be similar to seawater. Nodules with ??205TI values similar to seawater are found if the scavenging of TI is nearly quantitative. Hydrothermal manganese deposits display a positive correlation between ??205TI and Mn/Fe. This trend is thought to be due to the derivation of TI from distinct hydrothermal sources. Deposits with low Mn/Fe ratios and low ??205TI are produced by the adsorption of TI from fluids that are sampled close to hydrothermal sources. Such fluids have low Mn/Fe ratios and relatively high temperatures, such that only minor isotope fractionation occurs during adsorption. Hydrothermal

Submarine Hydrothermal Activity and Gold-Rich Mineralization at Brothers Volcano, Southern Kermadec Arc, New Zealand

Science.gov (United States)

de Ronde, C. E.; Massoth, G. J.; Christenson, B. W.; Butterfield, D. A.; Ishibashi, J.; Hannington, M. D.; Ditchburn, B. G.; Embley, R. W.; Lupton, J. E.; Kamenetsky, D.; Reyes, A. G.; Lahr, J.; Takai, K.

2006-12-01

Brothers volcano is one of several hydrothermally active volcanoes that occur along the Kermadec active arc front, NE of New Zealand. It forms an elongate edifice 13 km long by 8 km across that strikes NW-SE. The volcano has a caldera with a basal diameter of ~3 km and a floor at 1,850 m below sea level, surrounded by 290 to 530 m high walls. A volcanic cone of dacite rises 350 m from the caldera floor and partially coalesces with the southern caldera wall. Three hydrothermal sites have been located; on the NW caldera wall, on the SE caldera wall, and on the dacite cone. The NW caldera vent site is a long-term hydrothermal system that is today dominated by evolved seawater but has had episodic injections of magmatic fluid. The SE caldera site represents the main upflow of a relatively well-established magmatic-hydrothermal system on the seafloor where sulfide-rich chimneys are extant. The cone site is a nascent magmatic-hydrothermal system where crack zones localize upwelling acidic waters. Each of these different vent sites represent diverse parts of an evolving hydrothermal system, any one of which may be typical of submarine volcanic arcs. Hydrothermal venting is today occurring at the NW caldera and cone sites. The former is characterized by high-temperature (up to 302°C) venting with pH down to 2.8, low Mg and SO4 values, Cl between 510 and 760 mM, elevated Si and increasing Fe and Mn values with increasing Cl concentrations, consistent with a mostly Cl-enriched endmember. By contrast, vent fluids from the cone site are gas-rich (up to 220 mM total gas), have temperatures 30 ppm) zones in some chimneys formed over a short period of time, coincident with pulses of magmatic fluid into the hydrothermal system.

EMPLEO DEL PROGRAMA VOLCFLOW PARA SIMULAR FLUJOS PIROCLÁSTICOS DEL VOLCÁN CERRO MACHÍN, TOLIMA, COLOMBIA

Directory of Open Access Journals (Sweden)

Elsa Adriana Cárdenas Quiroga

2013-01-01

Full Text Available Se presentan los resultados de simular futuros flujos piroclásticos que podría producir el Volcán Cerro Machín, ubicado en la Cordillera Central de Colombia. Esta simulación se realizó con el programa VolcFlow desarrollado por el Laboratorio de Magmas y Volcanes de la Universidad Blaise Pascal, Francia, diseñado especialmente para modelar el comportamiento de este tipo de productos volcánicos, ya que está basado en las características reológicas de esos flujos. Se comparan las áreas que serían potencialmente afectadas por una erupción de ese tipo y los espesores del material que se depositaría con resultados obtenidos de simulaciones realizadas con un Model Builder desarrollado en ARC GIS por el Grupo de Investigación Geomática Aplicada de la Universidad Militar Nueva Granada en Colombia, obteniéndose resultados similares.

Evidence for recent hydrothermal activity in the Central Indian Basin

Digital Repository Service at National Institute of Oceanography (India)

Iyer, S.D.; ShyamPrasad, M.; Gupta, S.M.; Charan, S.N.

fracturing provide conditions conducive to hydrothermal discharge and accumulation of the resultant hydrothermal precipitates (Alt et al., 1987). Bonatti and Joensuu (1966) were among the first to report on the occurrence of spongy iron-oxides from a...-S fracture zones, traverse at 73”E, 76”3O’E and 79”E in the basin (Kamesh Raju, 1993). Many seamounts dot the floor of the CIB (Mukhopadhyay and Khadge, 1990; Kamesh Raju et al., 1993), some of them having caldera (Kodagali, 1991; Kodagali, pers. commun...

Hydrothermal pretreatments of macroalgal biomass for biorefineries

DEFF Research Database (Denmark)

Ruiz, Héctor A.; Rodríguez-Jasso, Rosa M.; Aguedo, Mario

2015-01-01

in accordance with the integrated biorefineries. Furthermore, biorefinery concept requires processes that allow efficient utilization of all components of the biomass. The pretreatment step in a biorefinery is often based on hydrothermal principles of high temperatures in aqueous solution. Therefore...

Water-rock interactions in discharge areas of Xiangshan Fossil hydrothermal system

International Nuclear Information System (INIS)

Zhou, Wenbin

1992-01-01

Xiangshan Fossil hydrothermal system is located within a volcanic basin of south-eastern China. The fact that most metal mineralizations were found in the discharge areas of the fossil hydrothermal system shows that the discharge areas were special geochemical fields. This paper discusses some important water-rock interactions in the discharge areas of Xiangshan fossil hydrothermal system. When the fluids circulating in the deep section of the hydrothermal system went upward to the discharge area, the physico-chemical conditions under which the fluids were saturated changed so considerably that the original physico-chemical equilibria were broken. Consequently, the fluids tended to move to new equilibrium by means of regulating their chemical compositions. Temperature and pressures of the fluids could be declined greatly in discharge area; the difference of temperature and pressure are determined to be 100--150 C and 1--2 x 10 7 Pa. As a result, a large amount of CO 2 in solution escaped from the fluids in the discharge area, and UO 2 (CO 3 ) n 2(1-n) , stable in CO 2 -rich solutions, could be decomposed into UUO 2 2+ , which could be easily reduced into pitchblende associated by calcite and hematite. The pH values for the fluids tended to increase with the CO 2 escaping, however, the interactions between the hydrothermal fluids and the wall rocks (dominantly aluminosilicate) served as the buffers for the pH, and regulated the pH value around neutral point. The buffer effect was of great importance to uranium mineralization. In addition, isotope exchangements between the fluids and rocks took place extensively

Hydrothermal alterations as natural analogues of radionuclide migration in granitic rocks

International Nuclear Information System (INIS)

Piantone, P.

1989-01-01

The document is the final report of the project Hydrothermal alteration systems as analogues of nuclear waste repositories in granitic rocks which was the subject of contract n 0 F1 1 W/0072-F (CD) performed at shared cost between the Bureau de Recherches Geologiques et Minieres (BRGM), the Commissariat a l'Energie Atomique and the Commission of the European Communities as part of the MIRAGE programme. This study is the continuation of a preliminary study made by BRGM in 1986 and which concerned the same programme. The data given in this report were obtained from the study of the infilling and hydrothermalized walls of a mineralized vein located at Fombillou, Lot Department, in the French Massif Central. A satisfactory model of the processes generated by hydrothermal alteration then by climatic weathering such as formation of new minerals, flow of elements and variations in volume, was thus built. The mobility of elements displaying physical and chemical properties similar to those of radionuclides present in high-level radioactive waste was studied. A preliminary thermodynamic simulation of mineral transformations and transfers of matter during hydrothermal alteration was performed using the calculation code CEQCSY (Chemical EQuilibrium in Complex SYstem). This simulation is based on the values of the main physical and chemical parameters deduced from the analysis of the natural system. On the basis of the results obtained from Fombillou, an appraisal was made of the response of the granitic environment which has been disturbed by a hydrothermal system produced by heat emitted by the storage of high-level radio-active waste as well as its potential capacities of retention in case of possible leakage

Abiotic synthesis of organic compounds from carbon disulfide under hydrothermal conditions.

Science.gov (United States)

Rushdi, Ahmed I; Simoneit, Bernd R T

2005-12-01

Abiotic formation of organic compounds under hydrothermal conditions is of interest to bio, geo-, and cosmochemists. Oceanic sulfur-rich hydrothermal systems have been proposed as settings for the abiotic synthesis of organic compounds. Carbon disulfide is a common component of magmatic and hot spring gases, and is present in marine and terrestrial hydrothermal systems. Thus, its reactivity should be considered as another carbon source in addition to carbon dioxide in reductive aqueous thermosynthesis. We have examined the formation of organic compounds in aqueous solutions of carbon disulfide and oxalic acid at 175 degrees C for 5 and 72 h. The synthesis products from carbon disulfide in acidic aqueous solutions yielded a series of organic sulfur compounds. The major compounds after 5 h of reaction included dimethyl polysulfides (54.5%), methyl perthioacetate (27.6%), dimethyl trithiocarbonate (6.8%), trithianes (2.7%), hexathiepane (1.4%), trithiolanes (0.8%), and trithiacycloheptanes (0.3%). The main compounds after 72 h of reaction consisted of trithiacycloheptanes (39.4%), pentathiepane (11.6%), tetrathiocyclooctanes (11.5%), trithiolanes (10.6%), tetrathianes (4.4%), trithianes (1.2%), dimethyl trisulfide (1.1%), and numerous minor compounds. It is concluded that the abiotic formation of aliphatic straight-chain and cyclic polysulfides is possible under hydrothermal conditions and warrants further studies.

Synthesis and characterization of nanosized MnZn ferrites via a modified hydrothermal method

Science.gov (United States)

Li, Mingling; Liu, Xiansong; Xu, Taotao; Nie, Yu; Li, Honglin; Zhang, Cong

2017-10-01

Nanosized MnZn ferrite particles, with narrow size distribution, regular morphology and high saturation magnetization have been synthesized via a modified hydrothermal method. This modified hydrothermal method involves a chemical co-precipitation of hydroxides under a vacuum condition using potassium hydroxide as precipitating agent, followed by a separate hydrothermal process. The microstructure and magnetic properties of the synthesized nanoparticles were investigated by X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM) and vibrating sample magnetometer (VSM). The effects of different synthesis conditions (excess ratio of precipitating agent and hydrothermal reaction time) on the microstructure and magnetic properties of the as-synthesized nanoparticles were discussed. The magnetic measurements indicated that the obtained samples were superparamagnetic in nature at room temperature. Moreover, the MnZn ferrite nanoparticles with excellent magnetic performance could be synthesized at 180 °C for a short reaction time (3 h).

Char and coke formation as unwanted side reaction of the hydrothermal biomass gasification

Energy Technology Data Exchange (ETDEWEB)

Karayildirim, T. [Department of Chemistry, Science Faculty, Ege University, Bornova-Izmir (Turkey); Sinag, A. [Department of Chemistry, Science Faculty, Ankara University, Besevler-Ankara (Turkey); Kruse, A. [Institut fuer Technische Chemie CPV, Forschungszentrum Karlsruhe GmbH, Karlsruhe (Germany)

2008-11-15

The hydrothermal biomass gasification is a promising technology to produce hydrogen and/or methane from wet biomass with a water content of {>=}80 % (g/g). In the process, the coke formation usually is very low, but already low amounts may cause problems like, e.g., fouling in the heat exchanger. To learn more about the product formation, the results of the hydrothermal treatment (at 400,500,600 C and 1 h) of different biomass feedstocks (artichoke stalk, pinecone, sawdust, and cellulose as model biomass) in a microreactor are compared. The gas composition and the total organic carbon content of the aqueous phase were determined after reaction. The gas formation rises with increasing temperature. The formation of carbon deposits and their characterization has been investigated by scanning electron microscopy (SEM). The variation of the solid morphology during the hydrothermal conversion is discussed based on chemical pathways occurring during hydrothermal biomass degradation. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

Metal concentration and structural changes in Corallina elongata (Corallinales, Rhodophyta) from hydrothermal vents.

Science.gov (United States)

Couto, Ruben P; Neto, Ana I; Rodrigues, Armindo S

2010-04-01

Shallow-water hydrothermal activity is widely present at Azores archipelago. Organisms in such environments present great potential as sentinels of the effects derived from chronically exposure to increased temperature, metal concentrations and reduced pH. This study aimed to evaluate metal concentration in Corallina elongata collected at locations exposed and not exposed to shallow-water hydrothermal activity and evaluate changes in its calcareous structure. Elemental concentration was determined and morphometric analysis was performed by scanning electron microscopy. Thicker cell walls and a bleached appearance were observed on C. elongata specimens from the hydrothermally active location, as well as increased concentrations of elements associated to volcanic activity. This study reports on metal accumulation and morphometric changes in the calcareous structure of C. elongata from a hydrothermally active location, adding new data for further research on such habitats and communities, providing an insight on how coralline algae might be affected by ocean acidification. (c) 2009 Elsevier Ltd. All rights reserved.

Synthesis of nickel oxide - zirconia composites by coprecipitation route followed by hydrothermal treatment

International Nuclear Information System (INIS)

Yoshito, Walter Kenji; Ussui, Valter; Lazar, Dolores Ribeiro Ricci; Paschoal, Jose Octavio Armani

2009-01-01

Nickel oxide-yttria stabilized zirconia (NiO-YSZ) for use as solid oxide fuel cell anode were synthesized by coprecipitation to obtain amorphous zirconia and crystallized β-nickel gels of the corresponding metal hydroxides. Hydrothermal treatment at 200°C and 220 psi from 2 up to 16 hours, under stirring, was performed to produce nanocrystalline powder. The as-synthesized powders were uniaxially pressed and sintered in air. Powders were characterized by X-ray diffraction, laser scattering, scanning and transmission electron microscopy (SEM/TEM), gas adsorption technique (BET) and TGDTA thermal analysis. Ceramic samples were characterized by dilatometric analysis and density measurements by Archimedes method. The characteristics of hydrothermally synthesized powders and compacts were compared to those produced without temperature and pressure application. Crystalline powders were obtained after hydrothermal process, excluding the calcination step from this route. The specific surface area of powders decreases with increasing time of hydrothermal treatment while the agglomerate mean size is not affected by this parameter. (author)

Multiple sample setup for testing the hydrothermal stability of adsorbents in thermal energy storage applications

International Nuclear Information System (INIS)

Fischer, Fabian; Laevemann, Eberhard

2015-01-01

Thermal energy storage based on adsorption and desorption of water on an adsorbent can achieve high energy storage densities. Many adsorbents lose adsorption capacity when operated under unfavourable hydrothermal conditions during adsorption and desorption. The stability of an adsorbent against stressing hydrothermal conditions is a key issue for its usability in adsorption thermal energy storage. We built an experimental setup that simultaneously controls the hydrothermal conditions of 16 samples arranged in a matrix of four temperatures and four water vapour pressures. This setup allows the testing of potential adsorbents between temperatures of 50 °C and 350 °C and water vapour pressures of up to 32 kPa. A measurement procedure that allows the detection of the hydrothermal stability of an adsorbent after defined time spans has been designed. We verified the functionality of the multiple sample measurements with a microporous adsorbent, a zeolite NaMSX. The hydrothermal stability of this zeolite is tested by water uptake measurements. A standard deviation lower than 1% of the 16 samples for detecting the hydrothermal stability enables setting different conditions in each sample cell. Further, we compared the water uptake measurements by measuring their adsorption isotherms with the volumetric device BELSORP Aqua 3 from Bel Japan. (paper)

Geographic Information System (GIS) Emergency Support for the May 2000 Cerro Grande Wildfire, Los Alamos, New Mexico, USA

Energy Technology Data Exchange (ETDEWEB)

C.R.Mynard; G.N.Keating; P.M.Rich; D.R. Bleakly

2003-05-01

In May 2000 the Cerro Grande wildfire swept through Los Alamos, New Mexico, burning approximately 17,400 ha (43,000 acres) and causing evacuation of Los Alamos National Laboratory (LANL) and the communities of Los Alamos and White Rock. An integral part of emergency response during the fire was the use of geographic information system (GIS) technology, which continues to be used in support of post-fire restoration and environmental monitoring. During the fire Laboratory GIS staff and volunteers from other organizations worked to produce maps and provide support for emergency managers, including at an emergency GIS facility in Santa Fe. Subsequent to the fire, Laboratory GIS teams supported the multiagency Burned Area Emergency Rehabilitation (BAER) team to provide GIS data and maps for planning mitigation efforts. The GIS teams continue to help researchers, operations personnel, and managers deal with the tremendous changes caused by the fire. Much of the work is under the auspices of the Cerro Grande Rehabilitation Project (CGRP) to promote recovery from fire damage, improve information exchange, enhance emergency management, and conduct mitigation activities. GIS efforts during the fire provided important lessons about institutional matters, working relationships, and emergency preparedness. These lessons include the importance of (1) an integrated framework for assessing natural and human hazards in a landscape context; (2) a strong GIS capability for emergency response; (3) coordinated emergency plans for GIS operations; (4) a method for employees to report their whereabouts and receive authoritative information during an evacuation; (5) GIS data that are complete, backed-up, and available during an emergency; (6) adaptation of GIS to the circumstances of the emergency; (7) better coordination in the GIS community; (8) better integration of GIS into LANL operations; and (9) a central data warehouse for data and metadata. These lessons are important for planning

Crystalline hydroxyapatite coatings synthesized under hydrothermal conditions on modified titanium substrates

International Nuclear Information System (INIS)

Suchanek, Katarzyna; Bartkowiak, Amanda; Gdowik, Agnieszka; Perzanowski, Marcin; Kąc, Sławomir; Szaraniec, Barbara; Suchanek, Mateusz; Marszałek, Marta

2015-01-01

Hydroxyapatite coatings were successfully produced on modified titanium substrates via hydrothermal synthesis in a Ca(EDTA) 2− and (NH 4 ) 2 HPO 4 solution. The morphology of modified titanium substrates as well as hydroxyapatite coatings was studied using scanning electron microcopy and phase identification by X-ray diffraction, and Raman and FTIR spectroscopy. The results show that the nucleation and growth of hydroxyapatite needle-like crystals with hexagonal symmetry occurred only on titanium substrates both chemically and thermally treated. No hydroxyapatite phase was detected on only acid etched Ti metal. This finding demonstrates that only a particular titanium surface treatment can effectively induce the apatite nucleation under hydrothermal conditions. - Highlights: • Bioactivation of titanium substrate by chemical and heat treatments • Precipitation of hydroxyapatite on modified titanium plates • Hydrothermal crystallization of hydroxyapatite by chelate decomposition method

Crystalline hydroxyapatite coatings synthesized under hydrothermal conditions on modified titanium substrates

Energy Technology Data Exchange (ETDEWEB)

Suchanek, Katarzyna, E-mail: Katarzyna.Suchanek@ifj.edu.pl [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland); Bartkowiak, Amanda [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland); Gdowik, Agnieszka [Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow (Poland); Perzanowski, Marcin [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland); Kąc, Sławomir [Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, Mickiewica 30, 30-059 Krakow (Poland); Szaraniec, Barbara [Department of Biomaterials, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow (Poland); Suchanek, Mateusz [Department of Chemistry and Physics, University of Agriculture in Krakow, Mickiewicza 21, 31-120 Krakow (Poland); Marszałek, Marta [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland)

2015-06-01

Hydroxyapatite coatings were successfully produced on modified titanium substrates via hydrothermal synthesis in a Ca(EDTA){sup 2−} and (NH{sub 4}){sub 2}HPO{sub 4} solution. The morphology of modified titanium substrates as well as hydroxyapatite coatings was studied using scanning electron microcopy and phase identification by X-ray diffraction, and Raman and FTIR spectroscopy. The results show that the nucleation and growth of hydroxyapatite needle-like crystals with hexagonal symmetry occurred only on titanium substrates both chemically and thermally treated. No hydroxyapatite phase was detected on only acid etched Ti metal. This finding demonstrates that only a particular titanium surface treatment can effectively induce the apatite nucleation under hydrothermal conditions. - Highlights: • Bioactivation of titanium substrate by chemical and heat treatments • Precipitation of hydroxyapatite on modified titanium plates • Hydrothermal crystallization of hydroxyapatite by chelate decomposition method.

Solubility limits in Mn–Mg ferrites system under hydrothermal conditions

Energy Technology Data Exchange (ETDEWEB)

Hemeda, O.M., E-mail: omhemeda@yahoo.co.uk [Physics Department, Faculty of Science, Tanta University, Tanta (Egypt); Mostafa, N.Y. [Chemistry Department, Faculty of Science, Suez Canal University, Ismailia 41522 (Egypt); Faculty of Science, Taif University, PO Box 888, Al-Haweiah, Taif (Saudi Arabia); Abd Elkader, O.H. [Electron Microscope and Thin Films Department, National Research Center, Dokki 12622, Cairo (Egypt); Electron Microscope Unit, Zoology Department, King Saud University, Riyadh 11451 (Saudi Arabia); Ahmed, M.A. [Physics Department, Faculty of Science, Al Azhar University, Nasr City, Cairo (Egypt)

2014-09-01

In the present investigation, we successfully synthesized a pure MnFe{sub 2}O{sub 4} ferrite by the hydrothermal method. Moreover, the effect of Mg ion content on the formation of Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4} particles (with x varying from 0.1 to 1.0) was also investigated using XRD, SEM, TEM and Mossbauer Spectroscopy. Phases formed in the system Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4}; 0.0≤x≤1.0 were investigated under hydrothermal conditions at 453 K.The produced phases were characterized by X-ray diffraction, Scanning, transmission microscopy and Mossbauer spectroscopy. The information of composition, cation distribution in the spinel structure and the particle size of the products were obtained. The spinel ferrites; Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4} were formed in the range 0.0≤x≤0.3. However, sample with x>0.3 showed semi-crystalline magnesium hydroxide (Mg(OH){sub 2}) and hematite (Fe{sub 2}O{sub 3}) beside the ferrite phase. For x=1.0, only magnesium hydroxide and hematite are formed without any ferrites. Particles of uniform size around 10–20 nm were obtained in the spinel structure of Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4} with x=0.0 and 0.1. The corresponding average crystallite size for each sample was 40.3 nm and 39.2 nm respectively. In addition, the Mossbauer spectra were analyzed into two subspectra, one for the tetrahedral A-site and the other for the octahedral B-site. The Mossbauer parameters were determined and discussed for the studied system. The cation distribution was estimated from the analysis of the Mossbauer spectra as well as the X-ray diffraction patterns. The results showed that Mg ions occupy mainly B-site while both Mn and Fe ions are distributed between A- and B-sites. - Highlights: • Mossbauer characterization of Mg–Mn ferrite prepared by hydrothermal route. • X-ray powder diffraction analysis of Mg–Mn ferrite prepared by hydrothermal route. • Solubility limit of MgMn ferrite under

Estudio de la Orientación Cristalográfica Preferente del Cuarzo en el Contacto entre Gneises y Metatexitas - Diatexitas del Macizo Cerro Pelado (Sierra de Comechingones, Argentina)

OpenAIRE

Castellarlni, P.; Fernández Rodríguez, Carlos; Otamendi, Juan E.

2003-01-01

The quartz c-axis fabrics measured in the rocks of the high-grade unit of the Cerro Pelado massif (northern Sierra de Comechingones, Sierras Pampeanas, Argentina) allow to deduce a normal-sinistral sense of movement for the south-dipping shear zone separating the diatexite-metatexite domain to the north, from the gneissic terrane to the south. The crystallographic fabrics also indicate that the activity of this shear zone took place under high-T conditions. The deduced kinematics can account ...

Inactivation of Escherichia coli Endotoxin by Soft Hydrothermal Processing▿

Science.gov (United States)

Miyamoto, Toru; Okano, Shinya; Kasai, Noriyuki

2009-01-01

Bacterial endotoxins, also known as lipopolysaccharides, are a fever-producing by-product of gram-negative bacteria commonly known as pyrogens. It is essential to remove endotoxins from parenteral preparations since they have multiple injurious biological activities. Because of their strong heat resistance (e.g., requiring dry-heat sterilization at 250°C for 30 min) and the formation of various supramolecular aggregates, depyrogenation is more difficult than sterilization. We report here that soft hydrothermal processing, which has many advantages in safety and cost efficiency, is sufficient to assure complete depyrogenation by the inactivation of endotoxins. The endotoxin concentration in a sample was measured by using a chromogenic limulus method with an endotoxin-specific limulus reagent. The endotoxin concentration was calculated from a standard curve obtained using a serial dilution of a standard solution. We show that endotoxins were completely inactivated by soft hydrothermal processing at 130°C for 60 min or at 140°C for 30 min in the presence of a high steam saturation ratio or with a flow system. Moreover, it is easy to remove endotoxins from water by soft hydrothermal processing similarly at 130°C for 60 min or at 140°C for 30 min, without any requirement for ultrafiltration, nonselective adsorption with a hydrophobic adsorbent, or an anion exchanger. These findings indicate that soft hydrothermal processing, applied in the presence of a high steam saturation ratio or with a flow system, can inactivate endotoxins and may be useful for the depyrogenation of parenterals, including end products and medical devices that cannot be exposed to the high temperatures of dry heat treatments. PMID:19502435

Solidification of ion-exchange resins by hydrothermal hot-pressing

International Nuclear Information System (INIS)

Kaneko, M.

1993-01-01

The solidification reaction which easily occurs while continuously keeping the mixture of cation and anion exchange resins compressed under hydrothermal conditions has been demonstrated. Dehydration was considered to occur between sulphonic acid (-SO 3 H) from the cation exchange resin and quaternary ammonium [-CH 2 -N(CH 3 ) 3 OH] from anion-exchange resin-on terminal groups. The cation-and anion-exchange resins were mixed in a 1:1 weight ratio, put in a hot-pressing autoclave and compressed between pistons from the top and bottom at 600 kg cm -2 pressure. The material was continuously compressed during hydrothermal treatment at 200 kg cm -2 by a hydraulic jack and heated to a desired temperature with an induction heater. This system could be used for rapid temperature increasing up to 30 o c min -1 . The pressure and temperature were kept constant for 10 min. The autoclave was cooled to room temperature after the hydrothermal treatment. After the specimen was taken out, the ion-exchange radical reactions were estimated and the product structures were examined. The cation- and anion-exchange resin mixture was solidified. The resultant solidified body at a 300 o C reaction condition for 10 min had a 1.0 g cm -3 density and 700 kg cm -2 compressive strength, and the weight loss did not change in distilled water for 2 weeks. On the other hand, a solidification reaction did not occur at below 250 o C when only the cation or anion was solidified, but they were decomposed. These results suggest that a mixture of cation- and anion-exchange resins causes a solidification reaction under hydrothermal hot-pressing conditions at 300 o C. (author)

Hydrothermal-synthesized NiO nanowall array for lithium ion batteries

International Nuclear Information System (INIS)

Yan, Xiaoyan; Tong, Xili; Wang, Jian; Gong, Changwei; Zhang, Mingang; Liang, Liping

2013-01-01

Graphical abstract: Freestanding NiO nanowall array is prepared via a hydrothermal synthesis method and shows noticeable Li battery performance with good cycle life and high capacity. Highlights: ► NiO nanowall array is prepared by a hydrothermal synthesis method. ► NiO nanowall array with high capacity as anode material for Li ion battery. ► Nanowall array structure is favorable for fast ion/electron transfer. -- Abstract: We report a self-supported NiO nanowall array prepared by a facile hydrothermal synthesis method. The microstructure and morphology of the sample are characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The hydrothermal-synthesized NiO nanowalls with thicknesses of ∼20 nm arrange vertically to the substrate forming a net-like nanowall array structure. As anode material for lithium ion batteries, the NiO nanowall array exhibits better electrochemical performances with higher coulombic efficiency and better cycling performance as compared to the dense NiO film. The NiO nanowall array shows an initial coulombic efficiency of 76%, as well as good cycling stability with a capacity of 567 mAh g −1 at 0.3 A g −1 after 50 cycles, higher than those of the dense polycrystalline NiO film (361 mAh g −1 ). The superior electrochemical performance is mainly due to the unique nanowall array structure with shorter diffusion length for mass and charge transport

Hydrothermal synthesis of magnetite particles with uncommon crystal facets

Directory of Open Access Journals (Sweden)

Junki Sato

2014-09-01

Full Text Available Hydrothermal synthesis of Fe3O4 (magnetite particles was carried out using organic compounds as morphology control agents to obtain magnetite crystals with uncommon facets. It was established that the morphology of Fe3O4 crystals obtained by hydrothermal treatment of an aqueous solution containing Fe2+ and organic compounds depended on the organic compound used. The shape of the Fe3O4 particles obtained when no additives were used was quasi-octahedral. In contrast, the addition of picolinic acid, citric acid or pyridine resulted in the formation of polyhedral crystals, indicating the presence of not only {1 1 1}, {1 0 0} and {1 1 0} facets but also high-index facets including at least {3 1 1} and {3 3 1}. When citric acid was used as an additive, octahedral crystals with {1 1 1} facets also appeared, and their size decreased as the amount of citric acid was increased. Thus, control of Fe3O4 particle morphology was achieved by a simple hydrothermal treatment using additives.

Hydrothermal treatment for inactivating some hygienic microbial indicators from food waste-amended animal feed.

Science.gov (United States)

Jin, Yiying; Chen, Ting; Li, Huan

2012-07-01

To achieve the hygienic safety of food waste used as animal feed, a hydrothermal treatment process of 60-110 degrees C for 10-60 min was applied on the separated food waste from a university canteen. Based on the microbial analysis of raw waste, the inactivation of hygienic indicators of Staphylococcus aureus (SA), total coliform (TC), total aerobic plate counts (TPC), and molds and yeast (MY) were analyzed during the hydrothermal process. Results showed that indicators' concentrations were substantially reduced after hydrothermal treatment, with a greater reduction observed when the waste was treated with a higher temperature and pressure and a longer ramping time. The 110 degrees C hydrothermal treatment for 60 min was sufficient to disinfect food waste as animal feed from the viewpoint of hygienic safety. Results obtained so far indicate that hydrothermal treatment can significantly decrease microbial indicators' concentrations but does not lead to complete sterilization, because MY survived even after 60 min treatment at 110 degrees C. The information from the present study will contribute to the microbial risk control of food waste-amended animal feed, to cope with legislation on food or feed safety.

Protein Adsorption and Antibacterial Behavior for Hydroxyapatite Nanocrystals Prepared by Hydrothermal Method

OpenAIRE

笠原, 英充; 小形, 信男; 荻原, 隆

2005-01-01

Homogeneous hydroxyapatite nanocrystals which have aspect ratio with more than four were synthesized by hydrothermal method. X-ray fluorescence analysis revealed that the Ca/P ratio of hydroxyapatite nanocrystals was maintaining start composition. The protein adsorption properties and bacteria-resistant of hydroxyapatite nanocrystals were investigated. The protein adsorption properties of hydroxyapatite nanocrystals were improvement after the hydrothermal treatment. Bacteria-resistant behavio...

hydrothermal synthesis and characterisation of amine-templated

African Journals Online (AJOL)

PROF EKWUEME

showed that the complexes were insoluble in water, ethanol, DMF and DMSO. KEYWORDS: Hydrothermal synthesis, metal phosphates, p-aminobenzoic acid, ethylacetoacetate, ethylammonium-. 4-aminobenzoate. INTRODUCTION. One of the major areas of materials science is the development of solid state materials with ...

Hydrothermal synthesis, structure and characterization of new ...

Indian Academy of Sciences (India)

Unknown

Keywords. Hydrothermal; crystal structure; solid electrolyte; iron (III) pyrophosphate. 1. Introduction ... tion, structure and electrical conductivity and the higher values of ..... type cavity structure. Acknowledgements. The authors would like to express their thanks to DST,. New Delhi, for financial assistance under the projects.

Hydrothermal effects on montmorillonite

International Nuclear Information System (INIS)

Pusch, R.; Karnland, O.

1988-06-01

Hydrothermal effects on montmorillonite clay are usually taken to have the form of conversion of this clay mineral to other species, such as illite, disregarding microstructural alteration and cementation caused by precipitation of silica and other compounds. The report is focussed on identification of the primary processes that are involved in such alteration, the release of silica and the microstructural changes associated with heating being of major interest. In the first test phase, Na montmorillonite in distilled water was investigated by XRD, rheology tests and electron microscopy after heating to 60-225 0 C for 0.01 to 1 year. The preliminary conclusions are that heating produces contraction of the particle network to form dense 'branches', the effect being most obvious at the highest temperature but of significance even at 60-100 0 C. Release of substantial amounts of silica gas been documented for temperatures exceeding 150 0 and precipitation of silica was observed on cooling after the hydrothermal testing under the closed conditions that prevailed throughout the tests. The precipitates, which appeared to be amorphous and probably consisted of hydrous silica gels, were concluded to have increased the mechanical strength and caused some brittleness, particularly of the dense clays. The nature of the silica release, which is assumed to be associated with beidellitization, may be closely related to an unstable state of a certain fraction of tetrahedral silica at heat-inducted transfer between two different crystal modes of montmorillonite. (orig.)

Abundance and Distribution of Diagnostic Carbon Fixation Genes in a Deep-Sea Hydrothermal Gradient Ecosystem

Science.gov (United States)

Blumenfeld, H. N.; Kelley, D. S.; Girguis, P. R.; Schrenk, M. O.

2010-12-01

The walls of deep-sea hydrothermal vent chimneys sustain steep thermal and chemical gradients resulting from the mixing of hot (350°C+) hydrothermal fluids with cold, oxygenated seawater. The chemical disequilibrium generated from this process has the potential to drive numerous chemolithoautotrophic metabolisms, many of which have been demonstrated to be operative in microbial pure cultures. In addition to the well-known Calvin Cycle, at least five additional pathways have been discovered including the Reverse Tricarboxylic Acid Cycle (rTCA), the Reductive Acetyl-CoA pathway, and the 3-hydroxyproprionate pathway. Most of the newly discovered pathways have been found in thermophilic and hyperthermophilic Bacteria and Archaea, which are the well represented in microbial diversity studies of hydrothermal chimney walls. However, to date, little is known about the environmental controls that impact various carbon fixation pathways. The overlap of limited microbial diversity with distinct habitat conditions in hydrothermal chimney walls provides an ideal setting to explore these relationships. Hydrothermal chimney walls from multiple structures recovered from the Juan de Fuca Ridge in the northeastern Pacific were sub-sampled and analyzed using PCR-based assays. Earlier work showed elevated microbial abundances in the outer portions of mature chimney walls, with varying ratios of Archaea to Bacteria from the outer to inner portions of the chimneys. Common phylotypes identified in these regions included Epsilonproteobacteria, Gammaproteobacteria, and Desulfurococcales. Total genomic DNA was extracted from mineralogically distinct niches within these structures and queried for genes coding key regulatory enzymes for each of the well studied carbon fixation pathways. Preliminary results show the occurrence of genes representing rTCA cycle (aclB) and methyl coenzyme A reductase (mcrA) - a proxy for the Reductive Acetyl-CoA Pathway within interior portion of mature

Learning about hydrothermal volcanic activity by modeling induced geophysical changes

Science.gov (United States)

Currenti, Gilda M.; Napoli, Rosalba

2017-05-01

Motivated by ongoing efforts to understand the nature and the energy potential of geothermal resources, we devise a coupled numerical model (hydrological, thermal, mechanical), which may help in the characterization and monitoring of hydrothermal systems through computational experiments. Hydrothermal areas in volcanic regions arise from a unique combination of geological and hydrological features which regulate the movement of fluids in the vicinity of magmatic sources capable of generating large quantities of steam and hot water. Numerical simulations help in understanding and characterizing rock-fluid interaction processes and the geophysical observations associated with them. Our aim is the quantification of the response of different geophysical observables (i.e. deformation, gravity and magnetic field) to hydrothermal activity on the basis of a sound geological framework (e.g. distribution and pathways of the flows, the presence of fractured zones, caprock). A detailed comprehension and quantification of the evolution and dynamics of the geothermal systems and the definition of their internal state through a geophysical modeling approach are essential to identify the key parameters for which the geothermal system may fulfill the requirements to be exploited as a source of energy. For the sake of illustration only, the numerical computations are focused on a conceptual model of the hydrothermal system of Vulcano Island by simulating a generic 1-year unrest and estimating different geophysical changes. We solved (i) the mass and energy balance equations of flow in porous media for temperature, pressure and density changes, (ii) the elastostatic equation for the deformation field and (iii) the Poisson’s equations for gravity and magnetic potential fields. Under the model assumptions, a generic unrest of 1-year engenders on the ground surface low amplitude changes in the investigated geophysical observables, that are, however, above the accuracies of the modern

Learning about Hydrothermal Volcanic Activity by Modeling Induced Geophysical Changes

Directory of Open Access Journals (Sweden)

Gilda M. Currenti

2017-05-01

Full Text Available Motivated by ongoing efforts to understand the nature and the energy potential of geothermal resources, we devise a coupled numerical model (hydrological, thermal, mechanical, which may help in the characterization and monitoring of hydrothermal systems through computational experiments. Hydrothermal areas in volcanic regions arise from a unique combination of geological and hydrological features which regulate the movement of fluids in the vicinity of magmatic sources capable of generating large quantities of steam and hot water. Numerical simulations help in understanding and characterizing rock-fluid interaction processes and the geophysical observations associated with them. Our aim is the quantification of the response of different geophysical observables (i.e., deformation, gravity, and magnetic fields to hydrothermal activity on the basis of a sound geological framework (e.g., distribution and pathways of the flows, the presence of fractured zones, caprock. A detailed comprehension and quantification of the evolution and dynamics of the geothermal systems and the definition of their internal state through a geophysical modeling approach are essential to identify the key parameters for which the geothermal system may fulfill the requirements to be exploited as a source of energy. For the sake of illustration only, the numerical computations are focused on a conceptual model of the hydrothermal system of Vulcano Island by simulating a generic 1-year unrest and estimating different geophysical changes. We solved (i the mass and energy balance equations of flow in porous media for temperature, pressure and density changes, (ii the elastostatic equation for the deformation field and (iii the Poisson's equations for gravity and magnetic potential fields. Under the model assumptions, a generic unrest of 1-year engenders on the ground surface low amplitude changes in the investigated geophysical observables, that, being above the accuracies of

Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity

Energy Technology Data Exchange (ETDEWEB)

Zuldesmi, Mansjur, E-mail: mzuldesmi@yahoo.com [Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Department of Mechanical Engineering, Manad State University (UNIMA) (Indonesia); Waki, Atsushi [Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Kuroda, Kensuke; Okido, Masazumi [EcoTopia Science Institute, Nagoya University, Nagoya (Japan)

2015-04-01

The surface wettability of implants is a crucial factor in their osteoconductivity because it influences the adsorption of cell-attached proteins onto the surface. In this study, a single-step hydrothermal surface treatment using distilled water at a temperature of 180 °C for 3 h was applied to titanium (Ti) and its alloys (Ti–6Al–4V, Ti–6Al–7Nb, Ti–29Nb–13Ta–4.6Zr, Ti–13Cr–1Fe–3Al; mass%) and compared with as-polished Ti implants and with implants produced by anodizing Ti in 0.1 M of H{sub 3}PO{sub 4} with applied voltages from 0 V to 150 V at a scanning rate of 0.1 V s{sup −1}. The surface-treated samples were stored in a five time phosphate buffered saline (× 5 PBS(−)) solution to prevent increasing the water contact angle (WCA) with time. The surface characteristics were evaluated using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Auger electron spectroscopy, surface roughness, and contact angle measurement using a 2 μL droplet of distilled water. The relationship between WCA and osteoconductivity at various surface modifications was examined using in vivo tests. The results showed that a superhydrophilic surface with a WCA ≤ 10° and a high osteoconductivity (R{sub B–I}) of up to 50% in the cortical bone part, about four times higher than the as-polished Ti and Ti alloys, were provided by the combination of the hydrothermal surface treatment and storage in × 5 of PBS(−). - Highlights: • Hydrothermal treatment in distilled water was applied to titanium alloys. • Surface characteristics and osteoconductivity by in vivo test were evaluated. • Water contact angles of titanium alloys were decreased by hydrothermal treatment. • Osteoconductivity of titanium alloys improved notably by hydrothermal treatment after stored in × 5 of PBS (−)

The transport of oxygen isotopes in hydrothermal systems

International Nuclear Information System (INIS)

McKibbin, R.; Absar, A.; Blattner, P.

1986-01-01

As groundwater passes through porous rocks, exchange of oxygen between the fluid and the solid matrix causes a change in the oxygen isotope concentrations in both water and rock. If the rate at which the exchange takes place can be estimated (as a function of the isotope concentrations and temperature) then the time taken for a rock/water system to come to equilibrium with respect to isotope concentration might be calculated. In this paper, the equation for isotope transport is derived using conservation laws, and a simple equation to describe the rate of isotope exchange is proposed. These are combined with the equations for fluid flow in a porous medium, to produce a general set of equations describing isotope transport in a hydrothermal system. These equations are solved numerically, using typical parameters, for the one-dimensional case. Oxygen isotope data from the basement rocks underlying Kawerau geothermal field are modelled. The results indicate that the time taken for exchange of 18 O to present-day values is less than the postulated age of hydrothermal alteration in that field. This suggests that, although controlled by similar parameters, oxygen isotope exchange, in felsic rocks at least, is much faster than hydrothermal alteration. This conclusion is consistent with the petrographic observations from the Kawerau system as well as other geothermal fields

Improving the circular economy via hydrothermal processing of high-density waste plastics.

Science.gov (United States)

Helmer Pedersen, Thomas; Conti, Federica

2017-10-01

Rising environmental concerns on climate changes are causing an increasing attention on circular economies. The plastic economy, in particular, is in focus due to the accelerating consumption of plastics, mainly derived from virgin feedstock, combined with the lack of plastic recycling strategies. This work presents a novel outlook on the potential of using supercritical hydrothermal processing of waste plastic fractions for tertiary recycling. The study investigates hydrothermal processing of nine different, high-density types of plastics into original resin monomers and other value-added chemical compounds. The outlook presents conversion yields, carbon balances, and chemical details on the products obtained. It is found that all the investigated resins are prone to hydrothermal treatment, and that high yields of monomers and high value compounds (up to nearly 100%), suitable for chemicals and fuels applications, can be obtained. For instance, for polycarbonate, styrene-butadiene, poly(lactic acid), poly(ethylene terephthalate), and poly(butylene terephthalate), original monomeric compounds can be reclaimed for manufacturing new resins. The promising results presented demonstrate that hydrothermal processing of high-density plastics is a prospective technology for increasing the circularity of the plastic economy. Copyright © 2017 Elsevier Ltd. All rights reserved.

Production of Valuables Organic Acids from Organic Wastes with Hydrothermal Treatment Process

Directory of Open Access Journals (Sweden)

Muhammad Faisal

2009-06-01

Full Text Available This article reports production of valuables organic acids from the hydrothermal treatment of representative organic wastes and compounds (i. e. domestic sludge, proteinaceous, cellulosic and plastic wastes with or without oxidant (H2O2. Organic acids such as acetic, formic, propionic, succinic and lactic acids were obtained in significant amounts. At 623 K (16.5 MPa, acetic acid of about 26 mg/g-dry waste fish entrails was obtained. This increased to 42 mg/g dry waste fish entrails in the presence of H2O2. Experiments on glucose to represent cellulosic wastes were also carried out, getting acetic acid of about 29 mg/g-glucose. The study was extended to terephthalic acid and glyceraldehyde, reaction intermediates of hydrothermal treatment of PET plastic wastes and glucose, respectively. Studies on temperature dependence of formation of organic acids showed thermal stability of acetic acid, whereas, formic acid decomposed readily under hydrothermal conditions. In general, results demonstrated that the presence of oxidants favored formation of organic acids with acetic acid being the major product. Keywords: hydrothermal treatment, organic acids, organic wastes, oxidant, supercritical water oxidation

The distribution and stabilisation of dissolved Fe in deep-sea hydrothermal plumes

Science.gov (United States)

Bennett, Sarah A.; Achterberg, Eric P.; Connelly, Douglas P.; Statham, Peter J.; Fones, Gary R.; German, Christopher R.

2008-06-01

We have conducted a study of hydrothermal plumes overlying the Mid-Atlantic Ridge near 5° S to investigate whether there is a significant export flux of dissolved Fe from hydrothermal venting to the oceans. Our study combined measurements of plume-height Fe concentrations from a series of 6 CTD stations together with studies of dissolved Fe speciation in a subset of those samples. At 2.5 km down plume from the nearest known vent site dissolved Fe concentrations were ˜ 20 nM. This is much higher than would be predicted from a combination of plume dilution and dissolved Fe(II) oxidation rates, but consistent with stabilisation due to the presence of organic Fe complexes and Fe colloids. Using Competitive Ligand Exchange-Cathodic Stripping Voltammetry (CLE-CSV), stabilised dissolved Fe complexes were detected within the dissolved Fe fraction on the edges of one non-buoyant hydrothermal plume with observed ligand concentrations high enough to account for stabilisation of ˜ 4% of the total Fe emitted from the 5° S vent sites. If these results were representative of all hydrothermal systems, submarine venting could provide 12-22% of the global deep-ocean dissolved Fe budget.

Stable isotopic and mineralogical studies of hydrothermal alteration at Arima Spa, Southwest Japan

International Nuclear Information System (INIS)

Masuda, Harue; Osaka City Univ.; Sakai, Hitoshi; Chiba, Hitoshi; Matsuhisa, Yukihiro; Nakamura, Takeshi

1986-01-01

The waters of Arima Spa, Southwest Japan, have high salinity (Cl = 54 g/kg) and high isotopic ratios (deltaD = -32, and delta 18 O = +10 per mille), and issue from shallow wells drilled into altered rhyolitic pyroclastic rocks of Cretaceous age. Alteration of the host rocks occurred in two stages. The earlier regional alteration stage is characterized by the presence of 2M- and 1M-type muscovite, albite, chlorite, calcite and epidote, whereas muscovite and Fe-chlorite formation at the expense of partly albitized plagioclase and altered biotite or hornblende occurred in the following hydrothermal stage. Pyrite, sphalerite, galena and siderite are present in the central part of the hydrothermal alteration zone. Oxygen and hydrogen isotopic ratios of secondary muscovite show that regional alteration proceeded under the meteoric circulation, and that the hydrothermal fluid for the second stage had chemical and stable isotopic characteristics of non-meteoric origin similar to the present-day Arima brine. The oxygen and to a lesser extent the hydrogen isotopic ratios of the muscovite rapidly decrease with increasing distance from the central zone of hydrothermal alteration. The isotopic variation is best interpreted as reflecting rapidly decreasing fluid/rock ratios with increasing distance of fluid penetration from the narrow hydrothermal alteration zone into the surrounding area. The results are discussed. (author)

Phase Transformation of Hydrothermally Synthesized Nanoparticle ...

African Journals Online (AJOL)

Mild hydrothermal hydrolysis of TiCl4 produces nanorods of the rutile phase of titanium dioxide in high yield, while in the presence of organic acids (citric, acetic, D-tartaric and benzoic acids) anatase is the only product. The effect of these organic acids on the products of the hydrolysis reaction as well as the reaction kinetics ...

Development and evaluation of a tracer-injection hydrothermal technique for studies of waste package interactions

International Nuclear Information System (INIS)

Jones, T.E.; Coles, D.G.; Britton, R.C.; Burnell, J.R.

1986-11-01

A tracer-injection system has been developed for use in characterizing reactions of waste package materials under hydrothermal conditions. High-pressure liquid chromatographic instrumentation has been coupled with Dickson-type rocking autoclaves to allow injection of selected components into the hydrothermal fluid while maintaining run temperature and pressure. Hydrothermal experiments conducted using this system included the interactions of depleted uranium oxide and Zircaloy-4 metal alloy discs with trace levels of 99 Tc and non-radioactive Cs and I in a simulated groundwater matrix. After waste-package components and simulated waste forms were pre-conditioned in the autoclave systems (usually 4 to 6 weeks), known quantities of tracer-doped fluids were injected into the autoclaves' gold reaction bag at run conditions. Time-sequenced sampling of the hydrothermal fluid providing kinetic data on the reactions of tracers with waste package materials. The injection system facilitates the design of experiments that will better define ''steady-state'' fluid compositions in hydrothermal reactions. The injection system will also allow for the formation of tracer-bearing solid phases in detectable quantities

Hydrothermal Liquefaction of the Microalgae Phaeodactylum tricornutum

DEFF Research Database (Denmark)

Sigaard Christensen, Per; Peng, Gaël; Vogel, Frédéric

2014-01-01

The microalgae Phaeodactylum tricornutum was processed by hydrothermal liquefaction in order to assess the influence of reaction temperature and reaction time on the product and elemental distribution. The experiments were carried out at different reaction times (5 and 15 min) and over a wide range...

Hydrothermal plumes over spreading-center axes: Global distributions and geological inferences

Science.gov (United States)

Baker, Edward T.; German, Christopher R.; Elderfield, Henry

Seafloor hydrothermal circulation is the principal agent of energy and mass exchange between the ocean and the earth's crust. Discharging fluids cool hot rock, construct mineral deposits, nurture biological communities, alter deep-sea mixing and circulation patterns, and profoundly influence ocean chemistry and biology. Although the active discharge orifices themselves cover only a minuscule percentage of the ridge-axis seafloor, the investigation and quantification of their effects is enhanced as a consequence of the mixing process that forms hydrothermal plumes. Hydrothermal fluids discharged from vents are rapidly diluted with ambient seawater by factors of 104-105 [Lupton et al., 1985]. During dilution, the mixture rises tens to hundreds of meters to a level of neutral buoyancy, eventually spreading laterally as a distinct hydrographic and chemical layer with a spatial scale of tens to thousands of kilometers [e.g., Lupton and Craig, 1981; Baker and Massoth, 1987; Speer and Rona, 1989].

The interplay of evolved seawater and magmatic-hydrothermal fluids in the 3.24 Ga panorama volcanic-hosted massive sulfide hydrothermal system, North Pilbara Craton, Western Australia

Science.gov (United States)

Drieberg, Susan L.; Hagemann, Steffen G.; Huston, David L.; Landis, Gary; Ryan, Chris G.; Van Achterbergh, Esmé; Vennemann, Torsten

2013-01-01

The ~3240 Ma Panorama volcanic-hosted massive sulfide (VHMS) district is unusual for its high degree of exposure and low degree of postdepositional modification. In addition to typical seafloor VHMS deposits, this district contains greisen- and vein-hosted Mo-Cu-Zn-Sn mineral occurrences that are contemporaneous with VHMS orebodies and are hosted by the Strelley granite complex, which also drove VHMS circulation. Hence the Panorama district is a natural laboratory to investigate the role of magmatic-hydrothermal fluids in VHMS hydrothermal systems. Regional and proximal high-temperature alteration zones in volcanic rocks underlying the VHMS deposits are dominated by chlorite-quartz ± albite assemblages, with lesser low-temperature sericite-quartz ± K-feldspar assemblages. These assemblages are typical of VHMS hydrothermal systems. In contrast, the alteration assemblages associated with granite-hosted greisens and veins include quartz-topaz-muscovite-fluorite and quartz-muscovite (sericite)-chlorite-ankerite. These vein systems generally do not extend into the overlying volcanic pile. Fluid inclusion and stable isotope studies suggest that the greisens were produced by high-temperature (~590°C), high-salinity (38–56 wt % NaCl equiv) fluids with high densities (>1.3 g/cm3) and high δ18O (9.3 ± 0.6‰). These fluids are compatible with the measured characteristics of magmatic fluids evolved from the Strelley granite complex. In contrast, fluids in the volcanic pile (including the VHMS ore-forming fluids) were of lower temperature (90°–270°C), lower salinity (5.0–11.2 wt % NaCl equiv), with lower densities (0.88–1.01 g/cm3) and lower δ18O (−0.8 ± 2.6‰). These fluids are compatible with evolved Paleoarchean seawater. Fluids that formed the quartz-chalcopyrite-sphalerite-cassiterite veins, which are present within the granite complex near the contact with the volcanic pile, were intermediate in temperature and isotopic composition between the greisen

Hydrothermal calcification of alkali treated titanium in CaHPO_4 solution

International Nuclear Information System (INIS)

Fu, T.; Fan, J.T.; Shen, Y.G.; Sun, J.M.

2017-01-01

The alkali treated titanium was hydrothermally treated in water and 10 mM CaHPO_4 solution (nominal concentration) at 80–180 °C to crystallize the titanate hydrogel layer and calcify the alkali treated titanium. Surface structure and elemental composition of the samples were analyzed by scanning electron microscopy, energy dispersive x-ray analysis, x-ray photoelectron spectroscopy, x-ray diffraction and Raman spectroscopy. Porous titanate hydrogel layer is formed on titanium after the alkali treatment. For the hydrothermal treatment in water, the hydrogel layer is crystallized as anatase TiO_2 with nanoporous or nanofibrous structure at 100 and 120 °C, and the layer is converted to anatase nanoparticles at 150 and 180 °C. For the hydrothermal treatment in the CaHPO_4 solution, hydroxyapatite nanocrystallites are deposited at the samples surface at 80–120 °C, but only anatase nanoparticles are formed at 150 and 180 °C. The growth of hydroxyapatite nanocrystallites is influenced by pH and temperature variations of the solution. The present alkali-hydrothermal treatment can avoid higher temperatures involved in the traditional alkali-heat treatments, which is applicable for bioactive surface modification of the thermally sensitive titanium alloys. The results also show that Raman spectroscopy is a useful technique to analyze the microstructure of TiO_2 and apatite films. - Highlights: • The alkali treated titanium is hydrothermally calcified in a CaHPO_4 solution. • HA nanocrystallites are formed at 80–120 °C, but TiO_2 nanoparticles at 150–180 °C. • The growth mechanism of HA nanocrystallites is discussed. • This low-temperature method is fit for some special titanium alloys.

Entropy production in a box: Analysis of instabilities in confined hydrothermal systems

Science.gov (United States)

Börsing, N.; Wellmann, J. F.; Niederau, J.; Regenauer-Lieb, K.

2017-09-01

We evaluate if the concept of thermal entropy production can be used as a measure to characterize hydrothermal convection in a confined porous medium as a valuable, thermodynamically motivated addition to the standard Rayleigh number analysis. Entropy production has been used widely in the field of mechanical and chemical engineering as a way to characterize the thermodynamic state and irreversibility of an investigated system. Pioneering studies have since adapted these concepts to natural systems, and we apply this measure here to investigate the specific case of hydrothermal convection in a "box-shaped" confined porous medium, as a simplified analog for, e.g., hydrothermal convection in deep geothermal aquifers. We perform various detailed numerical experiments to assess the response of the convective system to changing boundary conditions or domain aspect ratios, and then determine the resulting entropy production for each experiment. In systems close to the critical Rayleigh number, we derive results that are in accordance to the analytically derived predictions. At higher Rayleigh numbers, however, we observe multiple possible convection modes, and the analysis of the integrated entropy production reveals distinct curves of entropy production that provide an insight into the hydrothermal behavior in the system, both for cases of homogeneous materials, as well as for heterogeneous spatial material distributions. We conclude that the average thermal entropy production characterizes the internal behavior of hydrothermal systems with a meaningful thermodynamic measure, and we expect that it can be useful for the investigation of convection systems in many similar hydrogeological and geophysical settings.

Long-term hydrothermal temperature and pressure monitoring equipped with a Kuroko cultivation apparatus on the deep-sea artificial hydrothermal vent at the middle Okinawa Trough

Science.gov (United States)

Masaki, Y.; Nozaki, T.; Saruhashi, T.; Kyo, M.; Sakurai, N.; Yokoyama, T.; Akiyama, K.; Watanabe, M.; Kumagai, H.; Maeda, L.; Kinoshita, M.

2017-12-01

The middle Okinawa Trough, located along the Ryukyu- arc on the margin of the East China Sea, has several active hydrothermal fields. From February to March 2016, Cruise CK16-01 by D/V Chikyu targeted the Iheya-North Knoll and southern flank of the Iheya Minor Ridge to comprehend sub-seafloor geological structure and polymetallic sulfide mineralization. In this cruise, we installed two Kuroko cultivation apparatuses equipped with P/T sensors, flowmeter and load cell to monitor pressure, temperature and flow rate of hydrothermal fluid discharged from the artificial hydrothermal vent together with weight of hydrothermal precipitate. During Cruise KR16-17 in January 2017, two cultivation cells with sensor loggers were successfully recovered by ROV Kaiko MK-IV and R/V Kairei. We report these physical sensor data obtained by more than 10 months monitoring at two deep-sea artificial hydrothermal vents through many first and challenging operations.Hole C9017B at southern flank of the Iheya Minor Ridge (water depth of 1,500 mbsl), fluid temperature was constant ca. 75 ºC for 5 months from the beginning of monitoring. Then temperature gradually decrease to be 40 ºC. In November 2016, temperature and pressure suddenly dropped and quickly recovered due to the disturbance of subseafloor hydrology, induced by another drilling operation at Hole C9017A which is 10.8 meters northeastward from Hole C9017B during Cruise CK16-05. Temperature data exhibit conspicuous periodic 12.4hour cycles and this is attributable to oceanic tidal response. The amplitude of temperature variations increased along with decline of the temperature variations increased along with decline of the temperature. The average flow rate was 67 L/min for 9 hours from the onset of monitoring.Hole C9024A at the Iheya-North Knoll (water depth of 1,050 msl), the maximum temperature reached 308 ºC, which is similar to the maximum value of 311 ºC obtained from the ROV thermometer. The average flow rate was 289 L

Short run hydrothermal coordination with network constraints using an interior point method

International Nuclear Information System (INIS)

Lopez Lezama, Jesus Maria; Gallego Pareja, Luis Alfonso; Mejia Giraldo, Diego

2008-01-01

This paper presents a lineal optimization model to solve the hydrothermal coordination problem. The main contribution of this work is the inclusion of the network constraints to the hydrothermal coordination problem and its solution using an interior point method. The proposed model allows working with a system that can be completely hydraulic, thermal or mixed. Results are presented on the IEEE 14 bus test system

Possible detrital, diagenetic and hydrothermal sources for Holocene sediments of the Andaman backarc basin

Digital Repository Service at National Institute of Oceanography (India)

Kurian, S.; Nath, B.N.; Ramaswamy, V.; Naman, D.; Rao, T.G.; KameshRaju, K.A.; Selvaraj, K.; Chen, C.T.A.

discriminants such as Eu anomaly and Y/Ho ratio also suggest the role of hydrothermal activity. In addition, the association of Mo with Pb, Zn and Cu in the HCl-insoluble residue suggests the presence of sulfidic material probably of hydrothermal origin....

Hydrothermal manganese oxide deposits from the Izu-Ogasawara (Bonin)-Mariana Arc and adjacent areas

Energy Technology Data Exchange (ETDEWEB)

Usui, A.; Nishimura, A. (Geological Survey of Japan, Tsukuba (Japan))

1992-04-27

Modern and fossil hydrothermal manganese oxide deposits were discovered from a number of locations in the Izu-Ogasawara(Bonin)-Mariana Arc and adjacent areas during the Hakurei-Maru cruises from 1984 to 1989. This paper describes the occurrence and characteristics of these manganese deposits and their geological significance. It was found that the mineralogical and chemical composition and microstructure of the deposits are typically different from manganese nodules and crusts of hydrogenetic or diagenetic origin. Hardpans, veinlets, sheets, and irregular mass of the hydrothermal manganese deposits often cover a large area of sea bed, which suggests possible high-temperature hydrothermal sulfide deposits in their vicinity. On the other hand, the manganese minerals sometimes occur as substrate of younger hydrogenetic crusts and as nucleus of hydrogenetic nodules, which can provide a geological history of low-temperature hydrothermal activity on the past island arcs. 45 refs., 19 figs., 3 tabs.