Triple Charge Division (TCD) centroidfindingmethod that uses modified pattern of Backgammon Shape Cathode (MBSC) is introduced for medium range length position sensitive detectors with optimum numbers of cathode segments. MBSC pattern has three separated areas and uses saw tooth like insulator gaps for separating the areas. Side areas of the MBSC pattern are severed by a central common area. Size of the central area is twice of the size of both sides. Whereas central area is the widest area among three, both sides` areas have the main role in position sensing. With the same resolution and linearity, active region of original Backgammon pattern increases twice by using MBSC pattern, and with the same length, linearity of TCD centroidfinding is much better than Backgammon charge division readout method. Linearity prediction of TCD centroidfinding and experimental results conducted us to find an optimum truncation of the apices of MBCS pattern in the central area. The TCD centroidfinding has an especial readout method since charges must be collected from two segments in both sides and from three segments in the central area of MBSC pattern. The so called Graded Charge Division (GCD) is the especial readout method for TCD. The GCD readout is a combination of the charge division readout and sequence grading of serial segments. Position sensing with TCD centroidfinding and GCD readout were done by two sizes MBSC patterns (200mm and 80mm) and Spatial resolution about 1% of the detector length is achieved.
A novel centroid algorithm is proposed to acquire better centroid performance in a star image. Since photons incident on pixels of stars present a Gaussian point spread function (PSF), so, the centroid locations on the x and y-axis are calculated using the pixel intensity ratio and expand the Gaussian PSF to polynomials with respect to the centroid location. The angular separation error between star pairs is used to verify the proposed algorithm indirectly. The result clearly shows that the centroid accuracy achieves 1/33 of a pixel and is about two times better than the moment method, indicating the new algorithm is effective.
Lifetimes of members of the superdeformed band in {sup 135}Nd have been determined by a Doppler-shift attenuation method. In this case, where side feeding occurs along the entire length of the cascade, centroid analysis does not give a unique answer and line-shape analysis is necessary. We find a transition quadrupole moment of 7.4{plus minus}1.0 b, corresponding to an axis ratio of 1.42. The side feeding is {similar to}4 times slower than the main cascade.
Summary Background. This work quantifies and visualises 3D inconsistencies of the ventrointermediate nucleus (VIM) of the thalamus, including the VIM externum (VIMe) and VIM internum (VIMi), in the Schaltenbrand-Wahren (SW) brain atlas. Method. For each VIM, VIMe, VIMi the 3D models, 3D-A, 3D-C and 3D-S were reconstructed from the SW axial, coronal and sagittal microseries, respectively, by applying a shape-based method. All 3D models, placed in the SW coordinate system, were compared quantitatively in terms of location (centroids), size (volumes), shape (normalised eigen values), orientation (eigen vectors), and mutual spatial relationships (overlaps and inclusions). Findings. The reconstructed 3D models differ significantly in location, size, shape, and inclusion rate. The centroid of 3D...
A new method for spike sorting of tetrode recordings during data acquisition is introduced. For each tetrode channel, putative spikes are detected by means of a threshold, and then convolved with a cascade of wavelet filters. These transformed putative spikes are averaged and this average is used as a matched filter to find portions of signals that are likely to contain a spike. A collection of vectors containing the correlation coefficients between putative spikes and the matched filters is then clustered using K-Means. Centroids of the resulting clusters contain enough information to sort spikes recorded by all tetrode channels simultaneously. On-line sorting is achieved by measuring euclidean distance between putative new spikes and the cluster centroids. PMID:21096737
Centroid-based classification is a machine learning approach used in the text classification domain. The main advantage of centroid-based classifiers is their high performance during both the training stage and the classification stage. However, the success rate can be lower than the other classifiers if good centroid values are not used. In this paper, we apply the centroid-based classification method to the language identification problem, which can be considered as a sub-problem of text classification. We propose a novel method named as inverse class frequency to increase the quality of the centroid values, which involves an update of the classical values. We also use a feature set formed of individual characters rather than words or n-gram sequences to decrease the training and classif...
Rachel Akeson. NASA Exoplanet Science Institute ... Exoplanet Database) to a new service, the “NASA Exoplanet Archive”. – Focus on ... Includes in/out of transit centroiding information. – Kepler light ... Method for users to identify candidates ...
Item 1 - 9 ... CHAIN (to assure the topological integrity of polygon files), DACS (DIME AREA. CENTROID ...... on a USGS quad, and the SPC's identified according to the method described for calculating ...... SEARCH FOWARD UNTIL THERE IS A ...
The equation of motion for the centroid of globally coupled oscillators with natural frequency mismatch is obtained through a series expansion in order parameters, valid for any population size. In the case of strong coupling and narrow-frequency distribution the first-order expansion (corresponding to a system where the centroid is coupled to a second macroscopic variable), predicts transient and asymptotic properties of the dynamics of the centroid. Phase transitions appear as macroscopic bifurcations. Collective properties arising in the transient, and particularly critical perturbations, suggest a method of experimental relevance for identifying the parameters of the population.
This paper proposes a diagnosis system model for identification of transient in a PWR nuclear power plant, optimized by the Quantum Inspired Evolutionary Algorithm - QEA in order to help nuclear power plant operator reduce his cognitive load and increase his available time to maintain the plant operating in a safe condition. This method was developed in order to be able to recognize the normal condition and three accidents of the design basis list of the nuclear power plant Angra 2, postulated in the Final Safety Analysis Report (FSAR). This System compares the similarly distance between the set of variables of the anomalous event, in a given time t, and the centroids of the design-basis transient variables. The lower similarly distance indicates the class of the transient to which the anomalous event belongs. The QEA was then used to find the best position of the centroids of each class of the selected transients. Such positions maximize the number of the correct classifications. Unlike the diagnosis system proposed in the literature, Minkowski distance was employed to calculate the similarity distance. The signatures of four transients were submitted to 1% and 2% of noise, and tested with prototype vector found by QEA. The results showed that the present transient diagnostic system was successfully implemented in the nuclear accident identification problem and was compatible with the techniques presented in the literature. (author)
Recently, we have applied the analytic continuation averaged spectrum method (ASM) to calculate collective density fluctuations in quantum liquid [27]. Unlike the maximum entropy (MaxEnt) method, the ASM approach is capable of revealing resolved modes in the dynamic structure factor in agreement with experiments. In this work we further develop the ASM to study single-particle dynamics in quantum liquids with dynamical susceptibilities that are characterized by a smooth spectrum. Surprisingly, we find that for the power spectrum of the velocity autocorrelation function there are pronounced differences in comparison with the MaxEnt approach, even for this simple case of smooth unimodal dynamic response. We show that for liquid para-hydrogen the ASM is closer to the centroid molecular dynami...
Continuing work initiated in an earlier publication, we study the gravitational microlensing effects of the Ellis wormhole in the weak-field limit. First, we find a suitable coordinate transformation, such that the lens equation and analytic expressions of the lensed image positions can become much simpler. Second, we prove that two images always appear for the weak-field lens by the Ellis wormhole. By using these analytic results, we discuss astrometric image centroid displacements due to gravitational microlensing by the Ellis wormhole. The astrometric image centroid trajectory by the Ellis wormhole is different from the standard one by a spherical lensing object that is expressed by the Schwarzschild metric. The anomalous shift of the image centroid by the Ellis wormhole lens is smaller than that by the Schwarzschild lens, provided that the impact parameter and the Einstein ring radius are the same. Therefore, the lensed image centroid by the Ellis wormhole moves slower. Such a difference, although it is very small, will be, in principle, applicable for detecting or constraining the Ellis wormhole by using future high-precision astrometry observations. In particular, the image centroid position gives us additional information, so that the parameter degeneracy existing in photometric microlensing can be partially broken. The anomalous shift reaches the order of a few micro arcseconds, if our galaxy hosts a wormhole with throat radius larger than 10{sup 5} km. When the source moves tangentially to the Einstein ring, for instance, the maximum position shift of the image centroid by the Ellis wormhole is 0.18 normalized by the Einstein ring radius. For the same source trajectory, the maximum difference between the centroid displacement by the Ellis wormhole lens and that by the Schwarzschild one with the same Einstein ring radius is -0.16 in the units of the Einstein radius, where the negative means that the astrometric displacement by the Ellis wormhole lens is smaller than that by the Schwarzschild one.
Spectral centroid estimation from backscattered ultrasound RF signals is the preliminary step for quantitative ultrasound analysis in many medical applications. The traditional approach of estimating the spectral centroid in the frequency domain takes a long time because discrete Fourier transform (DFT) processing for each RF segment is required. To avoid this, we propose time-domain methods to estimate the spectral centroid in this paper. First, we derive the continuous-time-domain equations for the spectral centroid estimation using Parseval's theorem and Hilbert transform theory. Then, we extend the method to the discrete-time domain to ease the implementation while maintaining the same accuracy as the calculation in the frequency domain. From the result, we observe that it is not practical to apply the discrete-time equations directly, because a high sampling rate is needed to approximate the time derivative in the discrete-time domain. Therefore, we also derive the feasible version of the discrete-time equations using a circular autocorrelation function, which has no constraints on the sampling rate for real RF signals acquired from pulse-echo ultrasound systems. Simulation results using numerical phantoms show that the time-domain calculation is approximately 4.4 times faster on average than the frequency-domain method when the software's built-in functions were used. The average estimation error compared with that of the frequency-domain method using DFT is less than 0.2% for the entire propagation depths. The proposed time-domain approach to estimate the spectral centroid can be easily implemented in real-time ultrasound systems. PMID:22711414
We study large-amplitude one-dimensional solitary waves in photonic crystals featuring competition between linear and nonlinear lattices, with minima of the linear potential coinciding with maxima of the nonlinear pseudopotential, and vice versa (inverted nonlinear photonic crystals, INPhCs), in the case of the saturable self-focusing nonlinearity. Such crystals were recently fabricated using a mixture of SU-8 and Rhodamine-B optical materials. By means of numerical methods and analytical approximations, we find that large-amplitude solitons are broad sharply localized stable pulses (quasi-compactons, QCs). With the increase of the totalpower, P, the QC's centroid performs multiple switchings between minima and maxima of the linear potential. Unlike cubic INPhCs, the large-amplitude solitons are mobile in the medium with the saturable nonlinearity. The threshold value of the kick necessary to set the soliton in motion is found as a function of P. Collisions between moving QCs are considered too.
Text classification/categorization (TC) is to assign new unlabeled natural language documents to the predefined thematic categories. Centroid-based classifier (CC) has been widely used for TC because of its simplicity and efficiency. However, it has also been long criticized for its relatively low classification accuracy compared with state-of-the-art classifiers such as support vector machines (SVMs). In this paper, we find that for CC using only border instances rather than all instances to construct centroid vectors can obtain higher generalization accuracy. Along this line, we propose Border-Instance-based Iteratively Adjusted Centroid Classifier (IACC_BI), which relies on the border instances found by some routines, e.g. 1-Nearest-and-1-Furthest-Neighbors strategy, to construct centro...
This paper demonstrates the importance of disaggregating population data aggregated by census tracts or other units, for more realistic population distribution/location. A newly developed mapping method, the Cadastral-based Expert Dasymetric System (CEDS), calculates population in hyper-heterogeneous urban areas better than traditional mapping techniques. A case study estimating population potentially impacted by flood hazard in New York City compares the impacted population determined by CEDS with that derived by centroid-containment method and filtered areal-weighting interpolation. Compared to CEDS, 37% and 72% fewer people are estimated to be at risk from floods city-wide, using conventional areal weighting of census data, and centroid-containment selection, respectively. Undercounting...
Registration of medical images to each other and to physical space for the purposes of surgical planning and surgical navigation can be accomplished using externally attached fiducial markers. The accuracy of fiducial localization, that is, the accuracy of estimating the position of the marker's centroid, is extremely important because marker- based registration accuracy is proportional to localization accuracy. The traditional method of calculating the marker centroid using intensity weighting contains a serious logic flaw. This paper introduces a novel and efficient method for correcting this flaw. Theoretical analysis, computer simulation, and analysis of clinical images demonstrate the importance of this correction.
that utilizes an integral method similar to the Karman-Pohlhausen method in boundary ...... optimal flight plan with consideration for the meteorological conditions on the path ...... at the centroid of these lines Moreover there is a requirement that the position and ...... (AD-A022051 APL-JHU-TG-1280) Avail NTIS CSCL 01/2 ...
Purpose: To evaluate the use of megavoltage cone-beam computed tomography (MV CBCT) to measure interfractional variation in lung tumor position.Methods and Materials: Eight non–small-cell lung cancer patients participated in the study, 4 with respiratory gating and 4 without. All patients underwent MV CBCT scanning at weekly intervals. Contoured planning CT and MV CBCT images were spatially registered based on vertebral anatomy, and displacements of the tumor centroid determined. Setup error was assessed by comparing weekly portal orthogonal radiographs with digitally reconstructed radiographs generated from planning CT images. Hypothesis testing was performed to test the statistical significance of the volume difference, centroid displacement, and setup uncertainty.Results: The ver...
When compared with single gene functional analysis, gene set analysis (GSA) can extract more information from gene expression profiles. Currently, several gene set methods have been proposed, but most of the methods cannot detect gene sets with a large number of minor-effect genes. Here, we propose a novel distance-based gene set analysis method. The distance between two groups of genes with different phenotypes based on gene expression should be larger if a certain gene set is significantly associated with the given phenotype. We calculated the distance between two groups with different phenotypes, estimated the significant P-values using two permutation methods and performed multiple hypothesis testing adjustments. This method was performed on one simulated data set and three real data sets. After a comparison and literature verification, we determined that the gene resampling-based permutation method is more suitable for GSA, and the centroid statistical and average linkage statistical distance methods are efficient, especially in detecting gene sets containing more minor-effect genes. We believe that this distance-based method will assist us in finding functional gene sets that are significantly related to a complex trait. Additionally, we have prepared a simple and publically available Perl and R package (http://bioinfo.hrbmu.edu.cn/dbgsa or http://cran.r-project.org/web/packages/DBGSA/). PMID:22786580
We present an in-depth statistical survey of flare heights of all X-ray microflares as observed by RHESSI between March 2002 and March 2007, a total of >25,000 events, an order of magnitude larger then previous studies. The microflares were found using a new flare-finding algorithm designed to search the 6-- 12~keV count-rate when RHESSI's full sensitivity was available in order to find the smallest events. The flare centroid position are found at the peak time and as a function of energy (3-6, 6-12, 12-25 keV). Flares are found to occur only in active regions, not in the "quiet" Sun. Flare heights are found using two independent methods including that of Matsushita (1992). The distribution of flares at the limb are fitted with a Monte Carlo simulations and the flare height deduced. We find that the 6-12 keV flare heights are consistent with a flare height of ~3 arcseconds above the photosphere with small separation between the thermal and nonthermal sources. The Matsushita method confirm these values.
We show that mean K-shell binding energies E-bar/sub K/ for highly stripped ions moving in solids at a given velocity can be determined with reasonable accuracy from measured centroid energies for radiative electron capture. The method is used to determine E-bar/sub K/ for 20--80-MeV Cl ions in collisions with carbon targets.
The equations of motion for the rotor are derived using an integral Newtonian method, which ..... (modulus weighted centroid) is on the x axis, at a distance xC aft of the ...... coning degree of freedom., while S,C and S,S are the tip-path-plane tilt ...... the pitch horn and pitch link are given by the angles KPH + 0 75 and APL.
This paper presents a simplistic binocular robotic head architecture and a thorough analysis of its rigid body dynamics and kinematic models. A kinematic mathematical model for online computations of desired joint angle trajectories in object centroid tracking and fixation is presented. The efficacy and the characteristics of the models derived are illustrated using dynamic computer simulations with a controller using computed torque method.
We present a new three-dimensional hybrid level set (LS) and volume of fluid (VOF) method for free surface flow simulations on tetrahedral grids. At each time step, we evolve both the level set function and the volume fraction. The level set function is evolved by solving the level set advection equation using a second-order characteristic based finite volume method. The volume fraction advection is performed using a bounded compressive normalized variable diagram (NVD) based scheme. The interface is reconstructed based on both the level set and the volume fraction information. The novelty of the method lies in that we use an analytic method for finding the intercepts on tetrahedral grids, which makes interface reconstruction efficient and conserves volume of fluid exactly. Furthermore, the advection of volume fraction makes use of the NVD concept and switches between different high resolution differencing schemes to yield a bounded scalar field, and to preserve both smoothness and sharp definition of the interface. The method is coupled to a well validated finite volume based Navier-Stokes incompressible flow solver. The code validation shows that our method can be employed to resolve complex interface changes efficiently and accurately. In addition, the centroid and intercept data available as a by-product of the proposed interface reconstruction scheme can be used directly in near-interface sub-grid models in large eddy simulation.
The Kepler mission finds exoplanets by detecting planetary transit signals using various centroidingmethods that identify false positives due to background eclipsing binaries. One robust, high precision method fits the Kepler PSF to both the out-of-transit target star pixels and the difference between out-of and in-transit pixels. This difference image directly provides the location of the transit signal. The difference between these fits provides a high precision estimate of the offset between the transit signal location and the target star. A large offset implies a BGEB. This method is subject to various biases which complicate its interpretation. These biases change every 3 months because the Kepler spacecraft rolls, placing stars on different pixels. We describe several methods to control these biases through modeling, multi-quarter fitting and robust weighted averaging. These methods achieve uncertainties of less than an arcsec, compared with the prior minimum uncertainty of 2 arcsec (Kepler pixels are 3.98 arcsec on a side). The remaining residual biases are observed to have a nearly Gaussian distribution. These residual biases are combined with modeled observation biases to create observed and expected probability distributions for the transit signal, assuming that the transit is on a particular star. We use these distributions to calculate a relative probability that an observed transit is due to a transit on a specified star. This probability is an important step towards computing an absolute probability that a transit is on the observed target star. Funding for this mission provided by NASA's Discovery Program Office, SMD.
(Modified) The scaling of velocity fluctuation, dv, as a function of spatial scale L in molecular clouds can be measured from size-linewidth relations, principal component analysis, or line centroid variation. Differing values of the power law index of the scaling relation dv = L^(g3D) in 3D are given by these different methods: the first two give g3D=0.5, while line centroid analysis gives g3D=0. This discrepancy has previously not been fully appreciated, as the variation of projected velocity line centroid fluctuations (dv_{lc} = L^(g2D)) is indeed described, in 2D, by g2D=0.5. However, if projection smoothing is accounted for, this implies that g3D=0. We suggest that a resolution of this discrepancy can be achieved by accounting for the effect of density inhomogeneity on the observed g2D obtained from velocity line centroid analysis. Numerical simulations of compressible turbulence are used to show that the effect of density inhomogeneity statistically reverses the effect of projection smoothing in the cas...
NEAT is an astrometric mission proposed to ESA with the objectives of detecting Earth-like exoplanets in the habitable zone of nearby solar-type stars. In NEAT, one fundamental aspect is the capability to measure stellar centroids at the precision of 5 x 10-6 pixel. Current state-of-the-art methods for centroid estimation have reached a precision of about 4 x 10-5 pixel at Nyquist sampling. Simulations showed that a precision of 2 ?-pixels can be reached, if intra and inter pixel quantum efficiency variations are calibrated and corrected for by a metrology system. The European part of the NEAT consortium is designing and building a testbed in vacuum in order to achieve 5 x 10-6 pixel precision for the centroid estimation. The goal is to provide a proof of concept for the precision requirement of the NEAT spacecraft. In this paper we give the basic relations and trade-offs that come into play for the design of a centroid testbed and its metrology system. We detail the different conditions necessary to reach the targeted precision, present the characteristics of our current design and describe the present status of the demonstration.
NEAT is an astrometric mission proposed to ESA with the objectives of detecting Earth-like exoplanets in the habitable zone of nearby solar-type stars. In NEAT, one fundamental aspect is the capability to measure stellar centroids at the precision of 5 {\\times} 10-6 pixel. Current state-of-the-art methods for centroid estimation have reached a precision of about 4 {\\times} 10-5 pixel at Nyquist sampling. Simulations showed that a precision of 2 {\\mu}-pixels can be reached, if intra and inter pixel quantum efficiency variations are calibrated and corrected for by a metrology system. The European part of the NEAT consortium is designing and building a testbed in vacuum in order to achieve 5 {\\times} 10-6 pixel precision for the centroid estimation. The goal is to provide a proof of concept for the precision requirement of the NEAT spacecraft. In this paper we give the basic relations and trade-offs that come into play for the design of a centroid testbed and its metrology system. We detail the different conditi...
We demonstrate that the oxidation state of iron (Fe3+/?Fe) can be determined with a precision of ±0.02 (10% relative) on natural basalt glasses at mantle-relevant fO2 using Fe K-edge X-ray absorption near edge structure (XANES) spectroscopy. This is equivalent to ±0.25 log unit resolution relative to the QFM buffer. Precise determination of the oxidation state over this narrow range (Fe3+/?Fe=0.06-0.30) and at low fO2 (down to QFM-2) relies on appropriate standards, high spectral resolution, and highly reproducible methods for extracting the pre-edge centroid position. We equilibrated natural tholeiite powder in a CO/CO2 gas mixing furnace at 1350°C from QFM-3 to QFM+2 to create six glasses of known Fe3+/?Fe, independently determined by Mössbauer spectroscopy. XANES spectra were collected at station X26A at NSLS, Brookhaven Natl. Lab, in fluorescence mode (9 element Ge array detector) using both Si(111) and Si(311) monochromators. Generally, the energy position of the 1s?3d (pre-edge) transition centroid is the most sensitive monitor of Fe oxidation state using XANES. For the mixture of Fe oxidation states in these glasses and the resulting coordination geometries, the pre-edge spectra are best defined by two multiple 3d crystal field transitions. The Si(311) monochromator, with higher energy resolution, substantially improved spectral resolution for the 1s?3d transition. Dwell times of 5s at 0.1eV intervals across the pre-edge region yielded spectra with the 1s?3d transition peaks clearly resolved. The pre-edge centroid position is highly sensitive to the background subtraction and peak fitting procedures. Differences in fitting models result in small but significant differences in the calculated peak area of each pre-edge multiplet, and the relative contribution of each peak to the calculated centroid. We assessed several schemes and obtained robust centroid positions by simultaneously fitting the background with a damped harmonic oscillator (DHO) function and pre-edge features with two Gaussians over a sub-sample of the pre-edge region (7110-7120 eV). We found that the relation between Fe3+/?Fe and the centroid energy is non-linear over this fO2 range, which is expected if the coordination environment changes with oxidation state. ?QFM is linearly related (R2=0.99) to the centroid position. This new calibration allows the oxidation states of natural mantle melts to be discriminated with high spatial resolution (9?m). We apply the new calibration to determination of Fe3+/?Fe in natural basaltic glasses and olivine-hosted glass inclusions (Cottrell et al. & Kelley et al., this meeting).
This paper proposes a method for recognizing hand-shapes by using multi-viewpoint image sets. The recognition of a hand-shape is a difficult problem, as appearance of the hand changes largely depending on viewpoint, illumination conditions and individual characteristics. To overcome this problem, we apply the Kernel Orthogonal Mutual Subspace Method (KOMSM) to shift-invariance features obtained from multi-viewpoint images of a hand. When applying KOMSM to hand recognition with a lot of learning images from each class, it is necessary to consider how to run the KOMSM with heavy computational cost due to the kernel trick technique. We propose a new method that can drastically reduce the computational cost of KOMSM by adopting centroids and the number of images belonging to the centroids, which are obtained by using k-means clustering. The validity of the proposed method is demonstrated through evaluation experiments using multi-viewpoint image sets of 30 classes of hand-shapes.
Phase synchronization is a crucial problem in Bistatic Synthetic Aperture Radar (BiSAR). As phase synchronization error and Doppler phase have nearly the same form, Doppler Centroid (DC) cannot be estimated with traditional method in BiSAR. A DC estimation method is proposed through phase-interferometry of Dual-channel direct signal. Through phase interferometry, phase synchronization error can be counteracted while Doppler phase is reserved and DC can be estimated from the reserved phase.
Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroidmethod or a band ratio method.
ANACROM is a computer code developed for automatic peak search and evaluation of some chromatograms parameters such as: centroid, height, area, full width at half maximum (FWHM) and resolution for each peak. Estimated parameters are accompanied by their associated asymptotic standard errors. The peak search is based on the concept of sign changes of the first derivative. The method of Savitzky and Golay is used to compute the first derivative. The pseudo-peaks are eliminated by a t test described by Barnes. A constant background is subtracted of the experimental values. The fitting function has a general form y = EPSILON/sup n/i = 1 G/sub 1/ (x) where G(x) is a simple Gaussian function or a modified Gaussian by a left or right exponential term, and n is the number of overlapping peaks. The fitting of the data uses the Marquardt-Bevington method to find the non-linear least-squares estimates of the parameters. Three plots are obtained: a) experimental and predicted values versus observation number, b) residuals versus observation number, and c) probabilistic graph of residuals. They should help the users to confirm the goodness of the model chosen.
Electromagnetic (EM) tracking has been recognized as a valuable tool for locating the interventional devices in procedures such as lung and liver biopsy or ablation. The advantage of this technology is its real-time connection to the 3D volumetric roadmap, i.e. CT, of a patient's anatomy while the intervention is performed. EM-based guidance requires tracking of the tip of the interventional device, transforming the location of the device onto pre-operative CT images, and superimposing the device in the 3D images to assist physicians to complete the procedure more effectively. A key requirement of this data integration is to find automatically the mapping between EM and CT coordinate systems. Thus, skin fiducial sensors are attached to patients before acquiring the pre-operative CTs. Then, those sensors can be recognized in both CT and EM coordinate systems and used calculate the transformation matrix. In this paper, to enable the EM-based navigation workflow and reduce procedural preparation time, an automatic fiducial detection method is proposed to obtain the centroids of the sensors from the pre-operative CT. The approach has been applied to 13 rabbit datasets derived from an animal study and eight human images from an observation study. The numerical results show that it is a reliable and efficient method for use in EM-guided application.
This paper demonstrates the importance of disaggregating population data aggregated by census tracts or other units, for more realistic population distribution/location. A newly-developed mapping method, the Cadastral-based Expert Dasymetric System (CEDS), calculates population in hyper-heterogeneous urban areas better than traditional mapping techniques. A case study estimating population potentially impacted by flood hazard in New York City compares the impacted population determined by CEDS with that derived by centroid-containment method and filtered areal weighting interpolation. Compared to CEDS, 37 percent and 72 percent fewer people are estimated to be at risk from floods city-wide, using conventional areal weighting of census data, and centroid-containment selection, respectively. Undercounting of impacted population could have serious implications for emergency management and disaster planning. Ethnic/racial populations are also spatially disaggregated to determine any environmental justice impacts with flood risk. Minorities are disproportionately undercounted using traditional methods. Underestimating more vulnerable sub-populations impairs preparedness and relief efforts. PMID:20047020
In the conventional centroid position estimation method, the effective field of view (FOV) of a scintillation bar-detector cannot be extended beyond the centers of the two outside PMTs. To extend the FOV, the authors have implemented statistical position estimation on a bar-detector with blackened end surfaces. Maximum Likelihood (ML) and Minimum Square Error (MSE) position estimation look up tables (LUTs) were calculated from experimentally measured histogram data. Both statistical estimators provide a 14 cm FOV on a 16 cm bar, with 4 to 6 mm FWHM within the FOV. In contrast, the centroidmethod provides a 10cm FOV on a conventional bar detector. In order to reduce the size of LUTs and memory requirements, they have demonstrated the feasibility of using local, 2-D LUTs for position estimation. Using statistical position estimation methods and scatter-free sources they were able to extend the FOV beyond the conventional limit to utilize 90% of the bar-detector area.
Reference period collation, a method recently proposed for analysing the stochastic nature of a nominally periodic textile reinforcement, is extended to allow application to a laminate of stacked, nested plies. The method decomposes the characteristics of the fibre reinforcement into non-stochastic periodic (or systematic) trends and non-periodic stochastic fluctuations. The stochastic character of every tow is analysed in terms of the centroid position, aspect ratio, area, and orientation of its cross-section. The collation method is tested using X-ray micro-computed tomography data for a seven-ply 2/2 twill woven carbon-epoxy composite produced by resin transfer moulding. All tow characteristics, with exception of the in-plane centroid position, exhibit systematic trends that show only m...
BACKGROUND: Femoroacetabular impingement (FAI) can lead to labral injury, osseous changes, and even osteoarthritis. The literature contains inconsistent definitions of the alpha angle and other nonthree-dimensional (3-D) radiographic measures. We present a novel approach to quantifying cam lesions in 3-D terms. Our method also can be used to develop a classification system that describes the exact location and size of cam lesions. QUESTIONS/HYPOTHESES: We asked whether automated quantification of CAM lesions based on CT data is a reasonable way to detect CAM lesions and whether they may be classified based on location. METHOD OF STUDY: We developed a method to quantify femoral head cam lesions using 3-D modeling of CT scans. By segmenting raw DICOM data, we can determine the distance from the cam lesion's surface points to the centroid of the femoral head to quantify the mean bump height, volume, and location. The resulting 3-D femoral and acetabular models will be analyzed with custom software. We then will quantify the cam lesion with 3-D parameters using a modified zoning method. The mean bump height, volume, and location on the clock face, and relative zoning will be calculated. Zonal differences will be statistically analyzed. To assess the ability of this method to predict arthroscopic findings, we will obtain preoperative CT scans for 25 patients who undergo hip arthroscopy for FAI. We will compare measurements with the method with our measurements from arthroscopy. The clinical implications of our method's measurements then will be reviewed and refined for future prospective studies. SIGNIFICANCE: We present a novel approach that can quantify a cam lesion's location and size. This method will be used to provide guidelines for the exact amount of bony resection needed from a specific location of the proximal femur. There is also potential to develop software for ease of use so this method can be more widely applied. PMID:23129477
The electronic ?-? fast timing technique allows for direct nuclear lifetime determination down to the few picoseconds region by measuring the time difference between two coincident ?-ray transitions. Using high resolution ultra-fast LaBr3(Ce) scintillator detectors in combination with the recently developed mirror symmetric centroid difference method, nuclear lifetimes are measured with a time resolving power of around 5 ps. The essence of the method is to calibrate the energy dependent position (centroid) of the prompt response function of the setup which is obtained for simultaneously occurring events. This time-walk of the prompt response function induced by the analog constant fraction discriminator has been determined by systematic measurements using different photomultiplier tubes and timing adjustments of the constant fraction discriminator. We propose a universal calibration function which describes the time-walk or the combined ?-? time-walk characteristics, respectively, for either a linear or a non-linear amplitude versus energy dependency of the scintillator detector output pulses.
A novel method of using hard X-rays as a diagnostic for chromospheric density and magnetic structures is developed to infer sub-arcsecond vertical variation of magnetic flux tube size and neutral gas density.Using Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) X-ray data and the newly developed X-ray visibilities forward fitting technique we find the FWHM and centroid positions of hard X-ray sources with sub-arcsecond resolution ($\\sim 0.2"$) for a solar limb flare. We show that the height variations of the chromospheric density and the magnetic flux densities can be found with unprecedented vertical resolution of $\\sim$ 150 km by mapping 18-250 keV X-ray emission of energetic electrons propagating in the loop at chromospheric heights of 400-1500 km. Our observations suggest that the density of the neutral gas is in good agreement with hydrostatic models with a scale height of around $140\\pm 30$ km. FWHM sizes of the X-ray sources decrease with energy suggesting the expansion (fanning out) of m...
We propose a method for halftoning grayscale images by drawing weighted centroidal Voronoi tessellations (WCVTs) with black lines on white image planes. Based on the fact that CVT approaches a uniform hexagonal lattice asymptotically, we derive a relationship of darkness between input grayscale images and the corresponding halftone images. Then the derived relationship is used for adjusting the contrast of the halftone images. Experimental results show that the generated halftone images can reproduce the original tone in the input images faithfully.
The joint hypocentral determination method is used to relocate deep seismicity reported in the International Seismological Center catalog for earthquakes deeper than 400 km in the Honshu, Bonin, Mariannas, Java, Banda, and South America subduction zones. Each deep seismic zone is found to display planar features of seismicity parallel to the Harvard centroid-moment tensor nodal planes, which are identified as planes of shear failure. The sense of displacement on these planes is one of resistance to deeper penetration.
Nanosecond lifetime measurements were performed in 196Au by means of the pulsed-beam technique. Using the centroid-shift method, one new lifetime has been determined and three known have been re-measured. The data for the transition probabilities are compared to the predictions of the extended supersymmetry for 196Au. The comparison reveals a partial agreement, which can be considered as a success for the theory describing the complicated structure of the odd odd nucleus.
This paper investigates the problem of designing a codebook with non-uniform power allocation for multimode precoded MIMO schemes(e.g., spatial multiplexing and STBC) with limited feedback in fading channels. The generalized Lloyd algorithm is employed for the design, and two methods with different complexities are addressed for the computation of the centroid which is formulated as an optimization problem. Numerical results show that the proposed design outperforms comparable algorithms which equally allocate the total transmit power to each data stream.
The effect of approximating a continuous Gaussian distribution with histogrammed data are studied. The expressions for theoretical uncertainties in centroid and full-width at half maximum (FWHM), as determined by calculation of moments, are derived using the error propagation method for a histogrammed Gaussian distribution. The results are compared with the corresponding pseudo-experimental uncertainties for computer-generated histogrammed Gaussian peaks to demonstrate the effect of binning the data. It is shown that increasing the number of bins in the histogram improves the continuous distribution approximation. For example, a FWHM {ge} 9 and FWHM {ge} 12 bins are needed to reduce the pseudo-experimental standard deviation of FWHM to within {ge}5% and {ge}1%, respectively, of the theoretical value for a peak containing 10,000 counts. In addition, the uncertainties in the centroid and FWHM as a function of peak area are studied. Finally, Sheppard`s correction is applied to partially correct for the binning effect.
Purpose To determine the position of rectus muscle pulleys in Japanese eyes and to evaluate the effect of oblique muscle surgery on rectus muscle pulleys. Methods Quasi-coronal plane MRI was used to determine area centroids of the 4 rectus muscles. The area centroids of the rectus muscles were transformed to 2-dimensional coordinates to represent pulley positions. The effects of oblique muscle surgery on the rectus muscle pulley positions in the coronal plane were evaluated in 10 subjects with cyclovertical strabismus and, as a control, pulley locations in 7 normal Japanese subjects were calculated. Results The mean positions of the rectus muscle pulleys in the coronal plane did not significantly differ from previous reports on normal populations, including Caucasians. There were significa...
This paper evaluates a speaker-intrinsic vowel formant frequency normalization algorithm initially proposed in Watt & Fabricius (2002). We compare how well this routine, known as the S-centroid procedure, performs as a sociophonetic research tool in three ways: reducing variance in area ratios of vowel spaces (thus attempting to equalize vowel space areas); improving overlap/co-extensiveness of vowel polygons; and reproducing two-dimensional vowel configurational relationships within the vowel space, compared to formant data in raw Hertz. The study uses existing datasets of vowel formant data from RP and Aberdeen English (northeast Scotland). We conclude that, for the data examined here, the S-centroid W&F procedures performs at least as well as the two most recognized speaker-intrinsic, vowel-extrinsic, formant-intrinsic normalization methods, Lobanov's (1971) z-score procedure and Nearey's (1977/8) individual log-mean procedure (CLIHi4 in Adank 2003, CLIHi2 as tested here), and in some test cases better than Nearey1.
Abstract Despite the general increase in digital techniques for dental morphometric analyses, only a few methods are available to study worn teeth. Moreover, permanent dentitions are studied much more frequently than deciduous teeth. In this study, we address both issues by providing a taxonomic classification of Neanderthal and modern human (MH) lower second deciduous molars (dm2s) through the analysis of crown and cervical outlines. Crown and cervical outlines were obtained from a three-dimensional (3D) digital sample of uniformly oriented dm2s. Both outlines were centered on the centroid of their area and represented by 16 pseudolandmarks obtained by equiangularly spaced radial vectors out of the centroid. We removed size information from the oriented and centered outlines with a unifor...
Agricultural and construction equipment are commonly implemented with rectangular tubing in their structural frame designs. A typical joining method to fabricate these frames is by welding and the use of ancillary structural plating at the connections. This aids two continuous members to pass through an intersection point of the frame with some degree of connectivity, but the connections are highly unbalanced as the tubing centroids exhibit asymmetry. Due to the practice of welded continuous member frame intersections in current agricultural equipment designs, a conviction may exist that welded continuous member frames are superior in structural strength over that of structural frame intersections implementing welded non-continuous members where the tubing centroids lie within two planes o...
Purpose: To evaluate the use of megavoltage cone-beam computed tomography (MV CBCT) to measure interfractional variation in lung tumor position. Methods and Materials: Eight non-small-cell lung cancer patients participated in the study, 4 with respiratory gating and 4 without. All patients underwent MV CBCT scanning at weekly intervals. Contoured planning CT and MV CBCT images were spatially registered based on vertebral anatomy, and displacements of the tumor centroid determined. Setup error was assessed by comparing weekly portal orthogonal radiographs with digitally reconstructed radiographs generated from planning CT images. Hypothesis testing was performed to test the statistical significance of the volume difference, centroid displacement, and setup uncertainty. Results: The vertebral bodies and soft tissue portions of tumor within lung were visible on the MV CBCT scans. Statistically significant systematic volume decrease over the course of treatment was observed for 1 patient. The average centroid displacement between simulation CT and MV CBCT scans were 2.5 mm, -2.0 mm, and -1.5 mm with standard deviations of 2.7 mm, 2.7 mm, and 2.6 mm in the right-left, anterior-posterior and superior-inferior directions. The mean setup errors were smaller than the centroid shifts, while the standard deviations were comparable. In most cases, the gross tumor volume (GTV) defined on the MV CBCT was located on average at least 5 mm inside a 10 mm expansion of the GTV defined on the planning CT scan. Conclusions: The MV CBCT technique can be used to image lung tumors and may prove valuable for image-guided radiotherapy. Our conclusions must be verified in view of the small patient number.
Quantification of SPECT(Single Photon Emission Computed Tomography) images can be more accurate if correct segmentation of region of interest (ROI) is achieved. Segmenting ROI from SPECT images is challenging due to poor image resolution. SPECT is utilized to study the kidney function, though the challenge involved is to accurately locate the kidneys and bladder for analysis. This paper presents an automated method for generating seed point location of both kidneys using anatomical location of kidneys and bladder. The motivation for this work is based on the premise that the anatomical location of the bladder relative to the kidneys will not differ much. A model is generated based on manual segmentation of the bladder and both the kidneys on 10 patient datasets (including sum and max images). Centroid is estimated for manually segmented bladder and kidneys. Relatively easier bladder segmentation is followed by feeding bladder centroid coordinates into the model to generate seed point for kidneys. Percentage error observed in centroid coordinates of organs from ground truth to estimated values from our approach are acceptable. Percentage error of approximately 1%, 6% and 2% is observed in X coordinates and approximately 2%, 5% and 8% is observed in Y coordinates of bladder, left kidney and right kidney respectively. Using a regression model and the location of the bladder, the ROI generation for kidneys is facilitated. The model based seed point estimation will enhance the robustness of kidney ROI estimation for noisy cases.
Purpose: To characterize the interfractional variability in lung tumor volume, position, and tumor boundaries.Methods: Cone-beam computed tomography (CBCT) scans were acquired weekly during the course of treatment for 34 lung cancer patients (1-20 scans) with large tumors. Spatial registration based on bones was performed between contoured planning CT and CBCT. Gross tumor volume (GTV) on each CBCT was then contoured. Tumor volume, centroid, and boundaries variability were quantified. A commercial deformable registration software was tested and results were compared to manual contours.Results: Mean volume reduction was 41 ± 32% (p < 0.001) after an average time of 51 days. Tumor centroid drifts were 0.03, 0.14, and -0.13 cm in right-left (RL), anterior-posterior (AP), and superior-inferior (SI) directions with standard deviations of 0.55, 0.50, and 0.51 cm. GTV boundaries displacements were -0.27, -0.14, and -0.16 cm with standard deviations of 0.64, 0.57, and 0.59 cm in RL, AP, and SI directions. Relative error between deformed and manual contours with the commercial deformable registration software rose up exponentially with the GTV decrease.Conclusions: GTV size changes for large lung tumors are similar to those for standard tumors. Magnitude absolute values of displacement vector for centroid and boundaries shifts show that there is not a preferred direction for the drifts but shrinkage. PMID:23127097
We present results from a recent beam test of a prototype sensor for the LHCb Vertex Locator detector, read out with the Beetle 1.3 front-end chip. We have studied the effect of the sensor bias voltage on the reconstructed cluster positions in a sensor placed in a 120GeV pion beam at a 10° incidence angle. We find an unexplained sysematic shift in the reconstructed cluster centroid when increasing the bias voltage on an already overdepleted sensor. The shift is independent of strip pitch and sensor thickness.
Anisotropic triangle meshes are used for efficient approximation of surfaces and flow data in finite element analysis, and in these applications it is desirable to have as few obtuse triangles as possible to reduce the discretization error. We present a variational approach to suppressing obtuse triangles in anisotropic meshes. Specifically, we introduce a hexagonal Minkowski metric, which is sensitive to triangle orientation, to give a new formulation of the centroidal Voronoi tessellation (CVT) method. Furthermore, we prove several relevant properties of the CVT method with the newly introduced metric. Experiments show that our algorithm produces anisotropic meshes with much fewer obtuse triangles than using existing methods while maintaining mesh anisotropy.
A simple and successful design of initial codebook of vector quantization (VQ) is presented. For existing initial codebook algorithms, such as random method, the initial codebook is strongly influenced by selection of initial codewords and difficult to match with the features of the training vectors. In the proposed method, training vectors are sorted according to the norm of training vectors. Then, the ordered vectors are partitioned into N groups where N is the size of codebook. The initial codewords are obtained from calculating the centroid of each group. This initializtion method has a robust performance and can be combined with the VQ algorithm to further improve the quality of codebook.
Node generation plays an important role in meshless methods for seepage analysis with a free surface. A probabilistic algorithm based on a combination of simulated annealing and the generalized probabilistic Lloyd's method, which is related to centroidal Voronoi tessellations (CVTs), is used in seepage analyses with the element-free Galerkin method (EFG). The applications in this paper involve analyzing steady seepage in a rectangular dam, a dam with an inclined slope surface, and a dam with a horizontal drain. The results show that the algorithm can easily fit and update the changeable free surface, and obtains higher-quality node sets, particularly when simulating physical domains with complex geometrical boundaries.
In its crystal structure, the title compound, C9H7NO3, forms ?-stacked dimers, with a centroid–centroid distance of 3.475?(5)?Å between the benzenoid and the 2,4 dicarbonyl oxazine rings. These dimers then form staircase-like linear chains through further ?-stacking between the benzenoid rings [centroid–centroid distance of 3.761?(2)?Å]. The methyl-H atoms are disordered due to rotation about the C—N bond and were modeled with equal occupancy.
This paper analyses the occipital remains recovered from the El Sidrón (Asturias, Spain) Neandertal site between the years of 2000-2008. The sample is represented by three specimens, SD-1219, SD-1149, and SD-370a. Descriptive morphology, linear measurements, 3D geometric morphometrics, and virtual anthropological methods were employed to address the morphological, morphometric, and phylogenetic affinities of these fossils. The fossils display Neandertal autapomorphies (e.g., bilaterally protruding transverse occipital torus, suprainiac fossa). SD-1219 also preserves a strongly projecting juxtamastoid eminence and shows occipital bunning. In linear distances, the El Sidrón occipitals are similar to each other and close to the Neandertal mean. The centroid size of SD-1219 is slightly larger than the Neandertal average. All of the evidence taken together points to the hypothesis that SD-1219 belongs to a smaller Neandertal male. Linear measurements and the vault thickness of SD-1149 also suggest a robust male individual. The gracility of SD-370a points towards an immature individual. Virtual anthropological methods were used to reconstruct a 3D model of the SD-1219 occipital for geometric morphometrics, which reveals that SD-1219 shows relatively broad and low occipital plane proportions. Within the European Pleistocene lineage sample, this fossil falls geometrically closer to primitive rather than to derived morphologies because of its increased width, and a lower, anterior position of inion relative to the biasterionic axis. These results may imply that cranial sphericity could be an important feature of intraspecific Neandertal variability. Our findings open the way for further studies of intraspecific variation in Neandertal populations, in which the El Sidrón sample may play a significant role. PMID:19836056
The random-centroid optimization (RCO) method using computer was applied to determine the optimum conditions of the emulsifying activity of soy protein isolate. Levels of factors including the temperature during emulsification, pH of the protein solution and the concentration of NaCl were optimized. After the second cycle of measurement of the emulsifying activity in 22 samples, we were able to determine the optimum conditions for practical use, namely, a temperature of 30°C, pH 8.2, and concentration of NaCl of 0.35 mol/l. We concluded that this RCO method is suitable for the optimization of food processing conditions with a minimum number of measurements.
A simple method for the rapid identification of inorganic salts used as raw materials during food production has been established using energy dispersive X-ray fluorescence (EDXRF). Intensities of Na, Mg, P, S, Cl, K, Ca, Mn, Fe, Cu, Zn K? peaks have been measured. The treatment and comparison of the respective intensities allowed a rapid identification of inorganic salts. Two different methods of data treatment have been tested: K nearest neighbours (KNN) and centroids. Using cross validation on a database containing 140 samples representing 31 classes, a total of 98% of samples were well identified.
Abstract in portuguese O objetivo deste trabalho foi alterar o método centroide de avaliação da adaptabilidade e estabilidade fenotípica de genótipos, para deixá-lo com maior sentido biológico e melhorar aspectos quantitativos e qualitativos de sua análise. A alteração se deu pela adição de mais três ideótipos, definidos de acordo com valores médios dos genótipos nos ambientes. Foram utilizados dados provenientes de um experimento sobre produção de matéria seca de 92 genótip (more) os de alfafa (Medicago sativa) realizado em blocos ao acaso, com duas repetições. Os genótipos foram submetidos a 20 cortes, no período de novembro de 2004 a junho de 2006. Cada corte foi considerado um ambiente. A inclusão dos ideótipos de maior sentido biológico (valores médios nos ambientes) resultou em uma dispersão gráfica em forma de uma seta voltada para a direita, na qual os genótipos mais produtivos ficaram próximos à ponta da seta. Com a alteração, apenas cinco genótipos foram classificados nas mesmas classes do método centroide original. A figura em forma de seta proporciona uma comparação direta dos genótipos, por meio da formação de um gradiente de produtividade. A alteração no método mantém a facilidade de interpretação dos resultados para a recomendação dos genótipos presente no método original e não permite duplicidade de interpretação dos resultados. Abstract in english ABSTRACT The objective of this work was to modify the centroidmethod of evaluation of phenotypic adaptability and the phenotype stability of genotypes in order for the method to make greater biological sense and improve its quantitative and qualitative performance. The method was modified by means of the inclusion of three additional ideotypes defined in accordance with the genotypes' average yield in the environments tested. The alfalfa (Medicago sativa L.) forage yield (more) of 92 genotypes was used. The trial had a randomized block design, with two replicates, and the data were used to test the method. The genotypes underwent 20 cuts, from November 2004 to June 2006. Each cut was considered an environment. The inclusion of ideotypes of greater biological average production in the environments produced an arrow-shaped graphical dispersion directed to the right in which the most productive genotypes were placed near the tip of the arrow. With the alteration only five genotypes were classified into the former classes of the original centroidmethod. The arrow-shaped figure allowed a direct comparison of genotypes throughout the productivity gradient. The alteration performed in the method preserved the easy interpretation of results for genotype recommendations of the original method, and does leaves no room for ambiguity in interpretation of the results.
We mainly employ centroid-moment tensor solutions (CMTs) for the March 11, 2011 Tohoku Earthquake and its aftershocks reported by Harvard University in studying deformation and stress state around Japan Sea area. After confirming the validity of CMTs by P-wave first motion polarity data from IRIS, we do cluster analysis and find that the solutions can be divided into three groups. The first group events are the kind of the main shock which is a low-angle thrust event, mainly occurred on the interface between the Pacific Plate and the North American Plate. The second group events are normal-fault earthquakes with principal extensional directions roughly pointing East-West direction. Most of these earthquakes located in the forearc uplift region of the Pacific plate. Some others occurred in the forearc accretionary wedge. The third group events are also normal-fault earthquakes though their principal extensional directions are roughly along the direction of the trench. These events located to the west of the Japan trench. We employ finite element method to simulate the stress state and deformation revealed by the focal mechanism solutions as well as GPS observations. Results show that the March 11, 2011 Tohoku Earthquake and some of its aftershocks released much of the East-West directional compressional stress accumulated in hundreds of years and resulted in at least a temporary East-West tensile state in the Japan Sea region which extends to China mainland. The normal-fault aftershocks located to the west of the Japan trench with East-West principal extensional direction were produced by this stress condition, while the existence of the normal-fault aftershocks with North-South principal extensional direction expressed the values of the tension along North-South direction and along East-West direction are roughly equal.
Abstract in portuguese O objetivo deste estudo foi avaliar, por meio de ensaios de rendimento grãos, o desempenho de 15 híbridos de milho em sete locais no Estado de Paraná e em duas safras, pelos métodos centróide (multivariado) e regressão bissegmentada (univariado), e avaliar possíveis divergências entre resultados obtidos por meio das duas metodologias. Os genótipos foram avaliados em delineamento de blocos completos casualizados com três repetiçõess. O método centróide foi ef (more) etivo na indicação de genótipos quanto o seu potencial produtivo, permitindo classificar genótipos não só quanto a adaptabilidade mas também quanto a estabilidade. Valores de probabilidade acima de 0,40 permitem classificar com maior confiabilidade os genótipos não só quanto à adaptabilidade, como também quanto à estabilidade. O genótipo STRIKE apresentou ampla adaptabilidade e estabilidade pelos métodos centróide e regressão bissegmentada. O genótipo SHS 4040 e CD 306 não devem ser indicados para cultivo, tomando-se como referência os ambientes testados. Abstract in english The objective of this study was to evaluate the performance of 15 maize cultivars in seven locations in Paraná State, Brazil. Towards this aim, grain yield trials were conducted during two crop seasons, and centroid (multivariate) and bissegmented regression (univariate) methods were used to evaluate possible divergences among results obtained. The genotypes were evaluated in randomized complete blocks with three replications. The centroidmethod was effective for indica (more) ting productive potential of genotypes, allowing for classification of genotype adaptability and stability. Values of probability above 0.40 allowed more reliable genotype classification for both adaptability and stability. The STRIKE genotype presented wide adaptability and stability by both the centroid and bissegmented regression methods. The SHS 4040 and CD 306 genotypes were not indicated for planting, considering the tested environments.
The spectral centroid of a signal is the curve whose value at any given time is the centroid of the corresponding constant-time cross section of the signal???s spectrogram. A spectral centroid provides a noise-robust estimate of how the dominant frequency of a signal changes over time. As such, spectral centroids are an increasingly popular tool in several signal processing applications, such as speech processing. We provide a new, fast and accurate algorithm for the real-time computation of the spectral centroid of a discrete-time signal. In particular, by exploiting discrete Fourier transforms, we show how one can compute the spectral centroid of a signal without ever needing to explicitly compute the signal???s spectrogram. We then apply spectral centroids to an emerging biometrics prob...
Lifetime measurements for superdeformed bands in {sup 151,152}Dy and {sup 192,194}Hg have been performed at GAMMASPHERE using the Doppler shift attenuation method. The transition quadrupole moments for several bands in these nuclei have been extracted from an analysis of centroid shift data. Of particular interest are the quadrupole moments associated with the so-called `identical` superdeformed bands in these nuclei. A preliminary analysis indicates that the values of the quadrupole moments in the identical bands are equal within experimental errors. This results suggests that the deformations associated with the identical bands are very similar.
Mormon prophet Joseph Smith (1805–44) claimed that more than two-dozen ancient individuals (Nephi, Mormon, Alma, etc.) living from around 2200 BC to 421 AD authored the Book of Mormon (1830), and that he translated their inscriptions into English. Later researchers who analyzed selections from the Book of Mormon concluded that differences between selections supported Smith's claim of multiple authorship and ancient origins. We offer a new approach that employs two classification techniques: ‘delta’ commonly used to determine probable authorship and ‘nearest shrunken centroid’ (NSC), a more generally applicable classifier. We use both methods to determine, on a chapter-by-chapter basis, the probability that each of seven potential authors wrot...
This work contains a clinical validation using biological landmarks of a Geometry Constrained Diffusion registration of mandibular surfaces. Canonical Correlations Analysis is extended to analyse 3D landmarks and the correlations are used as similarity measures for landmark clustering. A novel Active Shape Model is proposed targeting growth modelling by applying Partial Least Squares regression in decomposing the Procrustes tangent space. Shape centroid size is applied as dependent variable but the method generalizes to handle other, both uni- and multivariate, effects probing for high covariation wrt. shape variation.
Environmental pollution is a worldwide problem, and metals are the largest group of contaminants in soil. Microarray toxicogenomic studies with ecologically relevant organisms, such as springtails, supplement traditional ecotoxicological research but are presently rather descriptive. Classifier analysis, a more analytical application of the microarray technique, is able to predict biological classes of unknown samples. We used the uncorrelated shrunken centroidmethod to classify gene expression profiles of the springtail Folsomia candida exposed to soil spiked with six different metals (barium, cadmium, cobalt, chromium, lead, and zinc). We identified a gene set (classifier) of 188 genes that can discriminate between six different metals present in soil, which allowed us to predict the co...
The centroid-moment-tensor (CMT) algorithm provides a straightforward, rapid method for the determination of seismic source parameters from waveform data. As such, it has found widespread application, and catalogues of CMT solutions - particularly the catalogue maintained by the Global CMT Project - are routinely used by geoscientists. However, there have been few attempts to quantify the uncertainties associated with any given CMT determination: whilst catalogues typically quote a `standard error' for each source parameter, these are generally accepted to significantly underestimate the true scale of uncertainty, as all systematic effects are ignored. This prevents users of source parameters from properly assessing possible impacts of this uncertainty upon their own analysis. The CMT algo...
In this manuscript we present an automated algorithm for the alignment of thoracic scans using descriptors of bone structures. Bone structures were utilized because they are expected to be less susceptible to sources of errors such as patient positioning and breath hold. The algorithm employed the positioning of ribs relative to the spinal cord along with a description of the scapula. The spinal cord centroid was detected by extracting local maxima of the distance transform followed by point tracing along consecutive slices. Ribs were segmented using adaptive thresholding followed by the watershed algorithm to detach ribs from the vertebra, and by imposing requirements of rib proximity to the lung border. The angles formed between the spinal cord centroid and segmented rib centroids were used to describe rib positioning. Additionally, the length of the scapula was extracted in each slice. A cost function incorporating the difference of features from rib positioning and scapula length between two slices was derived and used to match slices. The method was evaluated on a set of 12 pairs of full and partial CT scans acquired on the same day. Evaluation was based on whether the slices showing a nodule at its maximum diameter in each scan were matched. Full-to-partial and partial-to-full alignment were performed. Results showed that the proposed metric matched nodule slices within an average distance of 1.08 and 1.17 slices from the target for full-to-partial and partial-to-full alignment respectively. These preliminary results are encouraging for using this method as a first step in an overall process of temporally analyzing CT lung nodules.
The main objective of this study was to determine whether motivational and volitional variables identified in the health action process approach (HAPA) model can be used to successfully differentiate people with multiple sclerosis (MS) in different stages of change for exercise and physical activity. Ex-post-facto design using multiple discriminant analysis was used. Participants were 215 individuals with MS. The outcome variable was measured by the Physical Activity Stages of Change Instrument, along with motivational and volitional measures (severity, action self-efficacy, outcome expectancy, risk perception, perceived barriers, intention, maintenance self-efficacy, action and coping planning, and recovery self-efficacy). Participants in the precontemplation, contemplation, and action groups can be maximally separated by two significant canonical discriminant functions, volition and motivation. The action group can be differentiated from other groups based on high group mean (centroid) score on the volition function, and the precontemplation group can be differentiated based on low group means on both the motivation and volition functions. The contemplation group can be differentiated based on high centroid score on the motivation function. Research findings of this study support the concept of stage-matching exercise and physical activity intervention. The HAPA framework can be used to design health promotion behavioral interventions for people with MS in vocational rehabilitation. (Contains 2 tables.)
We model the motility of Dictyostelium cells in a systematic data-driven manner. We deduce a minimal dynamical model that reproduces the statistical features of experimental trajectories. These are trajectories of the centroid of the cell perimeter, which is more sensitive to pseudopod activity than the usual tracking by centroid or nucleus. Our data account for cell individuality and dictate a model that extends the cell-type specific models recently derived for mammalian cells. Two generalized Langevin equations model stochastic periodic pseudopod motion parallel and orthogonal to the amoeba's direction of motion. This motion propels the amoeba with a random periodic left–right waddle in a direction that has a long persistence time. The model fully accounts for the statistics of the experimental trajectories, including velocity power spectra and auto-correlations, non-Gaussian velocity distributions, and multiplicative noise. Thus, we find neither need nor place in our data for an interpretation in terms ofanomalous diffusion. The model faithfully captures cell individuality as different parameter values in the model, and serves as a basis for integrating the local mechanics of cell motion with our observed long-term behavior.
We extend the study of the core of the Fe K$\\alpha$ emission line at \\sim 6.4 keV in Seyfert galaxies reported in Yaqoob & Padmanabhan (2004) using a larger sample observed by the Chandra High Energy Grating (HEG). Whilst heavily obscured active galactic nuclei (AGNs) are excluded from the sample, these data offer some of the highest precision measurements of the peak energy of the Fe K$\\alpha$ line, and the highest spectral resolution measurements of the width of the core of the line in unobscured and moderately obscured ($N_{H}<10^{23} \\ \\rm cm^{-2}$) Seyfert galaxies to date. The Fe K$\\alpha$ line is detected in 33 sources, and its centroid energy is constrained in 32 sources. In 27 sources the statistical quality of the data is good enough to yield measurements of the FWHM. We find that the distribution in the line centroid energy is strongly peaked around the value for neutral Fe, with over 80% of the observations giving values in the range 6.38--6.43 keV. Including statistical errors, 30 out of 3...
We study the nuclear isoscalar monopole and dipole compression modes in nuclei within the fluid dynamic approach (FDA) with and without the effect of relaxation. For a wide region of the medium and heavy nuclei, the FDA predicts that the isoscalar giant monopole resonance (ISGMR) and the isoscalar giant dipole resonance (ISGDR) exhaust about 90% of the corresponding model-independent sum rules. In the case of neglecting the effect of relaxation, the FDA, when adjusted to reproduce the centroid energy E0 of the ISGMR, results with centroid energy E1 of the ISGDR which is in agreement with the predictions of the self-consistent Hartree-Fock random-phase approximation calculations and the scaling model but significantly larger than the experimental value. We also show that the FDA leads to the correct hydrodynamic limit for the ratio (E1/E0){sub FDA}. We find that the ratio (E1/E0){sub FDA} depends on the relaxation time and approaches the preliminary experimental value (E1/E0){sub exp}=1.5{+-}0.1 in a short relaxation time limit. (c) 2000 The American Physical Society.
Numerous socio-environmental studies, including those in public health, utilize population data as one of the essential elements of modeling and analysis. Typically population data are reported by administrative or accounting units. For example, in the US the Census Bureau reports population counts by census blocks, block groups, and tracts. At any resolution, a uniform population distribution is assumed and the population figures and demographic characteristics are typically associated with block (polygon) centroids. In geographic analyses these points are considered representative of the population for census polygons. Traditional spatial modeling approaches commonly include intersection of census data with buffers of influence to quantify target population, using either inclusion-exclusion (of the centroids) or the area weighted population estimation methods. However, it is well understood that uniform population distribution is the weakest assumption and by considering census polygon centroids as representative of population all analytical approaches are very likely to overestimate or underestimate the analytical results. Given that population is spatially restricted by Census accounting units (such as blocks), there often is great uncertainty about spatial distribution of residents within those accounting units. This is particularly appropriate in suburban and rural areas, where the population is dispersed to a greater degree than urban areas. Because of this uncertainty, there is significant potential to misclassify people with respect to their location from pollution sources, and consequently it becomes challenging to determine if certain sub-populations are actually more likely than others to get differential environmental exposure. In this paper, we describe development and utilization of a high resolution demographic data driven approach for modeling and simulation at Oak Ridge National Laboratory.
Characterization and modeling of subsurface flow and transport properties is critical for modeling, performance prediction and design of a number of important environmental and energy applications, including groundwater flow and contaminant transport, energy recovery from geothermal and hydrocarbon reservoirs, and geologic storage of CO2. Inverse modeling is typically applied to infer hydraulic rock properties from available static and dynamic measurements. Data sparsity and nonlinearity with respect to model parameters often result in significant uncertainty and solution non-uniqueness in solving the resulting inverse problems. Stochastic methods have become increasingly popular for dealing with inverse modeling solution non-uniqueness and uncertainty quantification. In particular, the ensemble Kalman filter (EnKF) has been widely applied for stochastic characterization of aquifer hydraulic properties from dynamic field measurements. For practical applications, where large-scale models are used, the computational cost of the forward simulation severely constrains the number of model realizations that can be included in ensemble predictions. Consequently, the statistics computed from a limited-size ensemble becomes spurious, making the resulting EnKF model updates unreliable. Localization and local analysis methods have been introduced to mitigate the effect of spurious correlations by reducing or removing the unphysical numerical correlations between model parameters (and/or states) and observations at distant locations. While these methods have proven useful, they require prior tuning of localization parameters and do not address the impact of small ensemble size approximation on the existing physical correlations between parameters and close-by observations. An alternative approach to localization is to approximate the correct statistics from computationally efficient surrogate models. Here, we present an efficient streamline-based pseudo forecast method for approximation of the first and second order statistics needed for EnKF-based model calibration. We accomplish this by first performing fast streamline simulation for a large ensemble of models and cluster them into a small number of groups based on their flow responses. We then perform full simulations with the representative models in each cluster (cluster centroids) and use them to find correlations between the forecasts obtained from streamline and full simulation. These correlations are then used to adjust streamline-based forecasts for all realizations, which are in turn used to compute the second order sample statistics needed for the EnKF updates. We examine the performance of the proposed approach using several three dimensional three-phase subsurface flow models and compare the results with those obtained from the full simulation. We demonstrate the effectiveness and practicality of the proposed method for large-scale model calibration with EnKF.
We present a morphological study of 35 X-ray luminous galaxy clusters at 0.15centroid shift, and thus rank the clusters by the degree of substructure. These complementary probes give a consistent description of the cluster morphologies with some well understood exceptions. We find a remarkably tight correlation of regular morphology with the occurrence of cool cores in clusters. We also compare our measurements of X-ray morphology with measurements of the luminosity gap statistics and ellipticity of the brightest cluster galaxy (BCG). We check how our new X-ray morphological analysis maps onto cluster scaling relations, finding that (i) clusters with relatively undisturbed X-ray morphologies are on average more luminous at fixed X-ray...
Digital particle image velocimetry and fluorescent dye visualization are used to characterize the performance of fish-like swimming robots. During nominal swimming, these robots produce a ‘V’-shaped double wake, with two reverse-Kármán streets in the far wake. The Reynolds number based on swimming speed and body length is approximately 7500, and the Strouhal number based on flapping frequency, flapping amplitude, and swimming speed is 0.86. It is found that swimming speed scales with the strength and geometry of a composite wake, which is constructed by freezing each vortex at the location of its centroid at the time of shedding. Specifically, we find that swimming speed scales linearly with vortex circulation. Also, swimming speed scales linearly with flapping frequency and the width of the composite wake. The thrust produced by the swimming robot is estimated using a simple vortex dynamics model, and we find satisfactory agreement between this estimate and measurements made during static load tests.
This is the third paper on the improvements of systematic errors in our weak lensing analysis using an elliptical weight function, called E-HOLICs. In the previous papers we have succeeded in avoiding error which depends on ellipticity of background image. In this paper, we investigate the systematic error which depends on signal to noise ratio of background image. We find that the origin of the error is the random count noise which comes from Poisson noise of sky counts. Random count noise makes additional moments and centroid shift error, and those 1st orders are canceled in averaging, but 2nd orders are not canceled. We derived the equations which corrects these effects in measuring moments and ellipticity of the image and test their validity using simulation image. We find that the systematic error becomes less than 1% in the measured ellipticity for objects with $S/N>3$.
Displacement time-series recorded by Global Positioning System (GPS) receivers are a new type of near-field waveform observation of the seismic source. We have developed an inversion method which enables the recovery of an earthquake's mechanism and centroid coordinates from such data. Our approach is identical to that of the 'classical' Centroid-Moment Tensor (CMT) algorithm, except that we forward model the seismic wavefield using a method that is amenable to the efficient computation of synthetic GPS seismograms and their partial derivatives. We demonstrate the validity of our approach by calculating CMT solutions using 1 Hz GPS data for two recent earthquakes in Japan. These results are in good agreement with independently determined source models of these events. With wider availability of data, we envisage the CMT algorithm providing a tool for the systematic inversion of GPS waveforms, as is already the case for teleseismic data. Furthermore, this general inversion method could equally be applied to other near-field earthquake observations such as those made using accelerometers.
A method has been developed to calculate and represent the geometry of alpha-helices of membrane proteins. Geometrical parameters are computed from coordinate files in the protein data bank. The axis of the helix is determined from the local centroids of tetrapeptide units of the helix. The method provides lower and upper cutoff values of the distance between backbone atoms C(i)(carbonyl carbon) and N(i+4) for allocation of a hinge in a helix. The method calculates other geometrical parameters like the length of helix, twist per residue, height per residue, kink and swivel angles. Packing of bundles of alpha-helices is represented by relative angles of inclination and distance vectors. The parameters are useful in quantitative descriptions of structural features of membrane proteins. [figure]. Representation of the organization of the helix bundle in 1rwt by helix axis Theta1( i)- Theta(n)( i), helix center Theta0( i) of i(th) helix and centroid (C) of centers the three helices. Arrow-head indicates C-terminal end of a helix. PMID:15597208
We have constructed a photoelectron imaging spectrometer with super-resolution image processing and have applied it to the photoionization of nitric oxide and benzene in molecular beams. A field programmable gate array is employed for real-time subpixel centroiding calculations on hardware, providing 64 megapixel resolution (8192 × 8192 pixels). We examined eight different centroiding algorithms based on the center-of-gravity (COG) and Gaussian fitting (Gauss) methods and have found that the two-dimensional COG (2D-COG) and weighted mean of Gaussian center (w-Gauss) methods have the best performance. The excellent performance of the instrument is demonstrated by visualizing a 25 ?m diameter pore structure of an MCP, indicating a spatial resolution of 0.03%. The photoelectron image in one-color (1 + 1) resonance-enhanced multiphoton ionization of nitric oxide using a nanosecond laser provided a photoelectron kinetic energy resolution of 0.2%. This resolution is currently restricted by charged-particle optics. The photoelectron energy and angular distributions in the one-color (1 + 1) resonance-enhanced multiphoton ionization of benzene via 61 and 6111 vibronic levels in the S1 state are also presented. The results demonstrate that photoelectron angular anisotropy varies with the photoelectron kinetic energy and the vibronic state of the cation.
We present a novel method for correlating and classifying ion-specific time-of-flight secondary ion mass spectrometry (ToF-SIMS) images within a multispectral dataset by grouping images with similar pixel intensity distributions. Binary centroid images are created by employing a k-means-based custom algorithm. Centroid images are compared to grayscale SIMS images using a newly developed correlation method that assigns the SIMS images to classes that have similar spatial (rather than spectral) patterns. Image features of both large and small spatial extent are identified without the need for image pre-processing, such as normalization or fixed-range mass-binning. A subsequent classification step tracks the class assignment of SIMS images over multiple iterations of increasing n classes per iteration, providing information about groups of images that have similar chemistry. Details are discussed while presenting data acquired with ToF-SIMS on a model sample of laser-printed inks. This approach can lead to the identification of distinct ion-specific chemistries for mass spectral imaging by ToF-SIMS, as well as matrix-assisted laser desorption ionization (MALDI), and desorption electrospray ionization (DESI). PMID:22567660
Rainfall is regarded as the most important input for the hydrology and nonpoint source (H/NPS) models and uncertainty related to rainfall is generally recognized as a major challenge in watershed modeling. In this paper, we focus on the impact of spatial rainfall variability on H/NPS modeling of a large watershed. The uncertainty introduced by spatial rainfall variability was determined using a number of commonly-used interpolation methods: (1) the Centroidmethod; (2) the Thiessen Polygon method; (3) the Inverse Distance Weighted (IDW) method; (4) the Dis-Kriging method; and (5) the Co-Kriging method. The Soil and Water Assessment tool (SWAT) was used to quantify the effect of rainfall spatial variability on watershed H/NPS modeling of the Daning watershed in China. Results indicated that...
We present an analysis of the Feynman path centroid density that provides new insight into the correspondence between the path integral and the Schrödinger formulations of statistical mechanics. The path centroid density is a central concept for several approximations (centroid molecular dynamics, quantum transition state theory, and pure quantum self-consistent harmonic approximation) that are used in path integral studies of thermodynamic and dynamical properties of quantum particles. The centroid density is related to the quasi-static response of the equilibrium system to an external force. The path centroid dispersion is the canonical correlation of the position operator, that measures the linear change in the mean position of a quantum particle upon the application of a constant external force. At low temperatures, this quantity provides an approximation to the excitation energy of the quantum system. In the zero temperature limit, the particle's probability density obtained by fixed centroid path integ...
A recently developed Centroidal Voronoi Tessellation (CVT) unstructured sampling method is investigated here to assess its suitability for use in statistical sampling and function integration. CVT efficiently generates a highly uniform distribution of sample points over arbitrarily shaped M-Dimensional parameter spaces. It has recently been shown on several 2-D test problems to provide superior point distributions for generating locally conforming response surfaces. In this paper, its performance as a statistical sampling and function integration method is compared to that of Latin-Hypercube Sampling (LHS) and Simple Random Sampling (SRS) Monte Carlo methods, and Halton and Hammersley quasi-Monte-Carlo sequence methods. Specifically, sampling efficiencies are compared for function integration and for resolving various statistics of response in a 2-D test problem. It is found that on balance CVT performs best of all these sampling methods on our test problems.
A novel Doppler beam sharpening (DBS) algorithm based on chirp z-transform (CZT) is proposed in this letter to correct range cell migration (RCM) without prior knowledge of Doppler centroid. Iterations of conventional Doppler centroid estimation algorithms are avoided, and the impact of Doppler centroid estimation error is further circumvented. The processing steps combining DBS and CZT are given based on FFT, which are suitable for real-time projects. Simulation results prove the effectiveness of the proposed algorithm.
An Interactive Cluster Analysis Procedure (ICAP) was developed to derive classifier training statistics from remotely sensed data. The algorithm interfaces the rapid numerical processing capacity of a computer with the human ability to integrate qualitative information. Control of the clustering process alternates between the algorithm, which creates new centroids and forms clusters and the analyst, who evaluate and elect to modify the cluster structure. Clusters can be deleted or lumped pairwise, or new centroids can be added. A summary of the cluster statistics can be requested to facilitate cluster manipulation. The ICAP was implemented in APL (A Programming Language), an interactive computer language. The flexibility of the algorithm was evaluated using data from different LANDSAT scenes to simulate two situations: one in which the analyst is assumed to have no prior knowledge about the data and wishes to have the clusters formed more or less automatically; and the other in which the analyst is assumed to have some knowledge about the data structure and wishes to use that information to closely supervise the clustering process. For comparison, an existing clustering method was also applied to the two data sets.
Background To analyze interfraction motion of seminal vesicles (SV), and its motion relative to rectal and bladder filling. Methods and Materials SV and prostate were contoured on 771 daily computed tomography “on rails” scans from 24 prostate cancer patients undergoing radiotherapy. Random and systematic errors for SV centroid displacement were measured relative to the prostate centroid. Margins required for complete geometric coverage of SV were determined using isotropic expansion of reference contours. SV motion relative to rectum and bladder was determined. Results Systematic error for the SV was 1.9?mm left-right (LR), 2.9?mm anterior-posterior (AP) and 3.6?mm superior-inferior (SI). Random error was 1.4?mm (LR), 2.7?mm (AP) and 2.1?mm (SI). 10?mm margins covered the entire left SV and right SV on at least 90% of fractions in 50% and 33% of patients and 15?mm margins covered 88% and 79% respectively. SV AP movement correlated with movement of the most posterior point of the bladder (mean R2?=?0.46, SD?=?0.24) and rectal area (mean R2?=?0.38, SD?=?0.21). Conclusions Considerable interfraction displacement of SV was observed in this cohort of patients. Bladder and rectal parameters correlated with SV movement. PMID:19524987
The 3-D luminosity distribution at the IP of the SLAC B-Factory is monitored using e{sup +}e{sup -} {yields} e{sup +}e{sup -}, {mu}{sup +}{mu}{sup -} events reconstructed online in the BABAR detector. The transverse centroid and spatial orientation of the luminosity ellipsoid reliably monitor IP orbit drifts. The longitudinal centroid is sensitive to small variations in the average relative RF phase of the beams and provides a detailed measurement of the phase transient along the bunch train. The longitudinal luminosity distribution depends on the e{sup +,-} overlap bunch length and the vertical IP {beta}-functions. Relative variations in horizontal luminous size are detectable at the micron level. In addition to continuous on-line monitoring of all the parameters above, we performed detailed studies of their variation along the bunch train to investigate a temporary luminosity degradation. We also compare {beta}*{sub y} measurements, collected over a year of high-luminosity operation, with HER and LER lattice functions measured by resonant transverse excitation. Our bunch-length measurements are consistent with those obtained by other methods and provide direct evidence for bunch-length modulation.
The electron-proton instability of a long, intense, and partially neutralized proton bunch is studied by numerically solving the equations of motion for the line centroid of the proton beam and the line centroid of the trapped electrons. The formalism takes into account the effects of variable line densities and alternating-gradient focusing. Good qualitative agreement between the computational results and experimental observations was obtained when applying the theory to the Los Alamos Proton Storage Ring (PSR). Both the case of a clean extraction gap and the case with a few percent of protons in the extraction gap were studied. It is found that with only a few percent neutralization, the PSR beam can become unstable in both cases. The same equations and method were used to study the stability of the proton beam in the accumulator ring of the proposed LANSCE II spallation-neutron source. The results indicate that the e-p instability can also occur in the LANSCE II accumulator ring for only a few percent neutralization.
A new detector module has been developed for a prototype system, McSPECT 2, which is being constructed for high-resolution clinical brain imaging. The detector module is the building block of the cylindrical detector system of the McSPECT 2. Each detector module contains 5 NaI(Tl) bars and is backed by a glass window in an aluminum housing. Each detector module is associated with 6 PMTs to form a functional unit for position estimation. Bench-top tests performed on a sample unit demonstrated an average of 10.5% local energy resolution (ER) at 140 keV. Centroid calculations were applied in both orthogonal directions of the module for position estimation. In the longitudinal direction, a two-step centroidmethod yields a 13 cm UFOV (useful field-of-view) along the bar and an 11 cm CFOV (center FOV), with intrinsic spatial resolution of < 5.5 and 3.8 [+-] 0.3 mm FWHM, respectively. In the transverse direction, the task of identifying the bar detector involved in an event is simplified, with an accuracy better than 99% when photons are incident normally.
We propose an anchorless distributed technique for estimating the centroid of a network of agents from noisy relative measurements. The positions of the agents are then obtained relative to the estimated centroid. The usual approach to multi-agent localization assumes instead that one anchor agent exists in the network, and the other agents' positions are estimated with respect to the anchor. We show that our centroid-based algorithm converges to the optimal solution, and such a centroid-based representation produces results that are more accurate than anchor-based ones, irrespective of the selected anchor.
A two-dimensional finite element method for an incompressible two-fluid model is developed in order to enhance the applicability of the two-fluid model to the analyses in arbitrarily shaped channels. The solution algorithm is based on the SMAC method for incompressible single-phase flows. Quadrilateral element with four nodes is employed. The velocities and volumetric fractions of both phases are defined on the nodes. The pressure is defined at a centroid of each element and assumed to be constant within the element. The Galerkin method is applied to the finite element formulations. Air-water two-phase flow around a circular cylinder is analyzed by the finite element method. The calculated distributions of the volumetric fraction of the gas-phase show good agreement with measurements. (author).
A rapid and sensitive flow-injection spectrophotometric method is proposed for the determination of sulfadiazine and sulfamethoxazole. This method is based on the diazotization of sulfonamide with sodium nitrite, and a coupling reaction of the diazo-compound with ?-naphthylamine. The optimum experimental conditions are obtained by using the controlled and weighted centroid simplex method. The linear ranges for the determination of sulfadiazine and sulfamethoxazole are 0.2 - 20 ?g ml-1 and 0.1 - 20 ?g ml-1 and their detection limits are 0.06 ?g ml-1 and 0.05 ?g ml-1, respectively, and the sampling frequency is 130 samples per hour. The method has been used to determine sulfadiazine and sulfamethoxazole in pharmaceuticals and urine without separation. The results are in agreement with those obtained by a high-performance liquid chromatograph technique at the 95% confidence level.
This paper considers selection of urban freeway ramps and routes based on user equilibrium in a single nucleus city of dispersive and continuous structure, and attempts an estimation of the ramp catchment area. The proposed method is a simultaneous estimation model that explains from trips taking place continuously in an urban area to distributed traffic amount in one model. The model features that it considers traffic congestions and demand variation and that the user equilibrium condition is satisfied by the ramp catchment area and utilized traffic amount, and determined endogenously by the model. This method expresses the freeways in the ordinarynetworks, as well as uses a continuum expression on surface roads that are distributed densely. Such a continuum expression method hypothesizes that an urban area has a continuous trip generation density, and differs from the conventional analytical methods, which divide the object area into zones, and hypothesize centroids with each zone as the center. 15 refs., 8 figs., 3 tabs.
A new method of determining the depth of interaction of {gamma}-rays in thick inorganic scintillation crystals was tested experimentally. The method uses the strong correlation between the width of the scintillation light distribution within large continuous crystals and the {gamma}-ray's interaction depth. This behavior was successfully reproduced by a theoretical model distribution based on the inverse square law. For the determination of the distribution's width, its standard deviation {sigma} is computed using an enhanced position-sensitive proportional resistor network which is often used in {gamma}-ray-imaging devices. Minor changes of this known resistor network allow the analog and real-time determination of the light distribution's 2nd moment without impairing the measurement of the energy and centroid. First experimental results are presented that confirm that the described method works correctly. Since only some cheap electronic components, but no additional detectors or crystals are required, the main advantage of this method is its low cost.
We have developed a technique for automatically identifying the script used to generate a document that is stored electronically in bit image form. Our approach differs from previous work in that the distinctions among scripts are discovered by an automatic learning procedure, without any handson analysis. We first develop a set of representative symbols (templates) for each script in our database (Cyrillic, Roman, etc.). We do this by identifying all textual symbols in a set of training documents, scaling each symbol to a fixed size, clustering similar symbols, pruning minor clusters, and finding each cluster`s centroid. To identify a new document`s script, we identify and scale a subset of symbols from the document and compare them to the templates for each script. We choose the script whose templates provide the best match. Our current system distinguishes among the Armenian, Burmese, Chinese, Cyrillic, Ethiopic, Greek, Hebrew, Japanese, Korean, Roman, and Thai scripts with over 90% accuracy.
In this paper, the uncertainties of gamma-ray small peak analysis have been examined. As the intensity of a gamma-ray peak approaches its detection decision limit, derived parameters such as centroid channel energy, peak area, peak area uncertainty, baseline determination, and peak significance are statistically sensitive. The intercomparison exercise organized by the CTBTO provided an excellent opportunity for this to be studied. Near background levels, the false-positive and false-negative peak identification frequencies in artificial test spectra have been compared to statistically predictable limiting values. In addition, naturally occurring radon progeny were used to compare observed variance against nominal uncertainties. The results infer that the applied fit algorithms do not always represent the best estimator. Understanding the statistically predicted peak-finding limit is important for data evaluation and analysis assessment. Furthermore, these results are useful to optimize analytical procedures to achieve the best results.
In this paper, the uncertainties of gamma-ray small peak analysis have been examined. As the intensity of a gamma-ray peak approaches its detection decision limit, derived parameters such as centroid channel energy, peak area, peak area uncertainty, baseline determination, and peak significance are statistically sensitive. The intercomparison exercise organized by the CTBTO provided an excellent opportunity for this to be studied. Near background levels, the false-positive and false-negative peak identification frequencies in artificial test spectra have been compared to statistically predictable limiting values. In addition, naturally occurring radon progeny were used to compare observed variance against nominal uncertainties. The results infer that the applied fit algorithms do not always represent the best estimator. Understanding the statistically predicted peak-finding limit is important for data evaluation and analysis assessment. Furthermore, these results are useful to optimize analytical procedures to achieve the best results. PMID:18515125
We obtained 960,200 22-by-22-pixel windowed images of a pinhole spot using the Teledyne H2RG CMOS detector with un-cooled SIDECAR readout. We performed an analysis to determine the precision we might expect in the position error signals to a telescope's guider system. We find that, under non-optimized operating conditions, the error in the computed centroid is strongly dependent on the total counts in the point image only below a certain threshold, approximately 50,000 photo-electrons. The LSST guider camera specification currently requires a 0.04 arcsecond error at 10 Hertz. Given the performance measured here, this specification can be delivered with a single star at 14th to 18th magnitude, depending on the passband.
Summary Here, we present the results of a genetic analysis of 463 Pottoka ponies corresponding to four generations, using 17 microsatellite markers. Ten years after the beginning of the Pottoka conservation programme, the values for the genetic diversity of the breed are still high and stable, indicating the success of the programme. We found null alleles in Pottoka for the ASB23, HMS3 and HTG10 microsatellites. Together with information obtained from other pony breeds from the Iberian Peninsula, this finding indicates that these microsatellites should not be used for phylogenetic analyses or parentage tests, at least for these breeds. The high heterozygosity exhibited by this breed in comparison to other ponies, together with its genetic proximity to the centroid of the allele frequencies...
A beam detector system, CATS (Chambre A Trajectoires de Saclay), was designed to provide event-by-event particle tracking in experiments with radioactive beams at GANIL. It consists of two low pressure multiwire proportional chambers with one plane of anode wires placed between two cathode planes (active area: 70x70 mm{sup 2}), respectively segmented into 28 vertical or horizontal strips (2.54 mm wide). The anode wires deliver a time signal allowing a time of flight measurement with an accuracy between 440 ps and 1.2 ns, depending on the energy loss of incident particles in the detector. The cathode strips are individually read out and the position of incoming particles is reconstructed using a charge centroidfinding algorithm. A spatial resolution of 400 {mu}m (700 {mu}m) was achieved during in beam experiment, with a counting rate of 1.5x10{sup 5} (10{sup 6}) particles per second. (author)
We establish a general propagation model to describe the spin Hall effect of light beam in left-handed materials (LHMs). A spin-dependent shift of the beam centroid perpendicular to the refractive index gradient for the light beam through an air-LHM interface is demonstrated. For a certain circularly polarized component, whether the transverse shift is positive or negative depends on the magnitude of the refractive index gradient. Very surprisingly, the spin Hall effect in the LHM is unreversed, although the sign of refractive index gradient is reversed. The physics underlying this counterintuitive effect is that the spin angular momentum of photons is unreversed. Further, we reveal that the angular shift in the LHM is reversed due to the negative diffraction. These findings provide alternative evidence for that the linear momentum of photons is reversed, while the spin angular momentum is unreversed in the LHM.
In case of a foot-and-mouth disease (FMD) or other exotic disease outbreak, surveillance zones and infected areas are conventionally created as circles with their centroids at the known infected premises. Given the availability of geographic information systems (GIS), it is no longer difficult to identify relevant zonal or area boundaries. However, it is not clear if from a disease control standpoint this is the optimal strategy. An alternative approach is to define regions using ZIP codes, counties, states, major roads, or natural barriers. We used an updated version of an epidemic simulation model originally applied to a 3-county area in California and the available information about the state’s livestock demographics to compare these two control strategies. The comparisons included the simulated duration of outbreaks, number of herds and animals affected, and manpower issues. These findings will be useful for state, national and international regulatory veterinarians in designing optimal disease control programs.
A multiwire proportional chamber system has been built as an area detector for use in X-ray crystallography with Cu K/sub alpha / radiation (1.54AA). The chamber, constructed by Charpak and collaborators at CERN, consists of a 10cm thick spherical interaction region with a radial electric field, a transition from spherical to plane geometry and a 50cm*50cm multiwire proportional chamber and subtends a 90 degrees opening angle. Two dimensional position information is obtained from orthogonal cathode planes using a high speed analog centroidfinding technique. Data on spatial and energy resolution as a function of angle and depth of interaction in the spherical drift region using a collimated, pulsed, X-ray source are presented. Ionization loss as a function of drift distance and field and loss due to field shaping grids has also been measured. (6 refs).
Summary On 2010 November 14, an intense swarm of earthquakes began in the western Gulf of Aden. Within a 48-hr period, 82 earthquakes with magnitudes between 4.5 and 5.5 were reported along an -80-km-long segment of the east-west trending Aden Ridge, making this swarm one of the largest ever observed in an extensional oceanic setting. In this study, we calculate centroid-moment-tensor solutions for 110 earthquakes that occurred between 2010 November and 2011 April. Over 80-per cent of the cumulative seismic moment results from earthquakes that occurred within 1 week of the onset of the swarm. We find that this sequence has a b-value of -1.6 and is dominated by normal-faulting earthquakes that, early in the swarm, migrate westwards with time. These earthquakes are located in rhombic basins ...
In this paper, we describe an automated integration-free path-integral (AIF-PI) method, based on Kleinert's variational perturbation (KP) theory, to treat internuclear quantum-statistical effects in molecular systems. We have developed an analytical method to obtain the centroid potential as a function of the variational parameter in the KP theory, which avoids numerical difficulties in path-integral Monte Carlo or molecular dynamics simulations, especially at the limit of zero-temperature. Consequently, the variational calculations using the KP theory can be efficiently carried out beyond the first order, i.e., the Giachetti-Tognetti-Feynman-Kleinert variational approach, for realistic chemical applications. By making use of the approximation of independent instantaneous normal modes (INM), the AIF-PI method can readily be applied to many-body systems. Previously, we have shown that in the INM approximation, the AIF-PI method is accurate for computing the quantum partition function of a water molecule (3 degrees of freedom) and the quantum correction factor for the collinear H(3) reaction rate (2 degrees of freedom). In this work, the accuracy and properties of the KP theory are further investigated by using the first three order perturbations on an asymmetric double-well potential, the bond vibrations of H(2), HF, and HCl represented by the Morse potential, and a proton-transfer barrier modeled by the Eckart potential. The zero-point energy, quantum partition function, and tunneling factor for these systems have been determined and are found to be in excellent agreement with the exact quantum results. Using our new analytical results at the zero-temperature limit, we show that the minimum value of the computed centroid potential in the KP theory is in excellent agreement with the ground state energy (zero-point energy) and the position of the centroid potential minimum is the expectation value of particle position in wave mechanics. The fast convergent property of the KP theory is further examined in comparison with results from the traditional Rayleigh-Ritz variational approach and Rayleigh-Schrödinger perturbation theory in wave mechanics. The present method can be used for thermodynamic and quantum dynamic calculations, including to systematically determine the exact value of zero-point energy and to study kinetic isotope effects for chemical reactions in solution and in enzymes. PMID:19749977
We describe a computational approach, incorporating quantum mechanics into enzyme kinetics modeling with a special emphasis on computation of kinetic isotope effects. Two aspects are highlighted: (1) the potential energy surface is represented by a combined quantum mechanical and molecular mechanical (QM/MM) potential in which the bond forming and breaking processes are modeled by electronic structure theory, and (2) a free energy perturbation method in path integral simulation is used to determine both kinetic isotope effects (KIEs). In this approach, which is called the PI-FEP/UM method, a light (heavy) isotope is mutated into a heavy (light) counterpart in centroid path integral simulations. The method is illustrated in the study of primary and secondary KIEs in two enzyme systems. In t...
A new stable unstructured finite volume method is presented for parallel large-scale simulation of viscoelastic fluid flows. The numerical method is based on the side-centered finite volume method where the velocity vector components are defined at the mid-point of each cell face, while the pressure term and the extra stress tensor are defined at element centroids. The present arrangement of the primitive variables leads to a stable numerical scheme and it does not require any ad-hoc modifications in order to enhance the pressure-velocity-stress coupling. The log-conformation representation proposed in [R. Fattal, R. Kupferman, Constitutive laws for the matrix-logarithm of the conformation tensor, J. Non-Newtonian Fluid Mech. 123 (2004) 281-285] has been implemented in order improve the li...
The centroid molecular dynamics (CMD) method is applied to the study of liquid water in the context of the rigid-body approximation. This rigid-body CMD technique, which is significantly more efficient than the standard CMD method, is implemented on the TIP4P model for water and used to examine isotopic effects in the equilibrium and dynamical properties of liquid H2O and D2O. The results obtained with this approach compare remarkably well with those determined previously with path integrals simulations as well as those obtained from the standard CMD method employing flexible models. In addition, an examination of the impact of quantization on the rotational and librational motion of the water molecule is also reported.
This paper presents the evaluation of the effect of the method of ECG signal encoding, based on nonlinear characteristics such as information entropy and Lempel-Ziv complexity, on the distribution of cardiac arrhythmias. Initially proposed a procedure electrocardiographic gating to compensate for errors inherent in the process of filtering segments. For the evaluation of distributions and determine which of the different encoding methods produces greater separation between different kinds of arrhythmias studied (AFIB, AFL, SVTA, VT, Normal's), use a function based on the dispersion of the elements on the centroid of its class, the result being that the best encoding for the entire system is through the method of threshold value for a ternary code with E = 1 / 12.
Quantum lithography (QL) has been suggested as a means of achieving enhanced spatial resolution for optical imaging, but its realization has been held back by the low multi-photon detection rates of recording materials. Recently, an optical centroid measurement (OCM) procedure was proposed as a way to obtain spatial resolution enhancement identical to that of QL but with higher detection efficiency (M. Tsang, Phys. Rev. Lett. 102, 253601, 2009). Here we describe a variation of the OCM method with still higher detection efficiency based on the use of photon-number-resolving detection. We also report laboratory results for two-photon interference. We compare these results with those of the standard QL method based on multi-photon detection and show that the new method leads to superresolution but with higher detection efficiency.
Abstact This paper proposes a hybrid vertex-centered finite volume/finite element method for solution of the two dimensional (2D) incompressible Navier-Stokes equations on unstructured grids. An incremental pressure fractional step method is adopted to handle the velocity-pressure coupling. The velocity and the pressure are collocated at the node of the vertex-centered control volume which is formed by joining the centroid of cells sharing the common vertex. For the temporal integration of the momentum equations, an implicit second-order scheme is utilized to enhance the computational stability and eliminate the time step limit due to the diffusion term. The momentum equations are discretized by the vertex-centered finite volume method (FVM) and the pressure Poisson equation is solved by t...
Context. The mechanisms giving rise to diffuse radio emission in galaxy clusters and, in particular, their connection with cluster mergers are still being debated. Aims: We explore the internal dynamics of Abell 2254, which has been shown to host a very clumpy and irregular radio halo. Methods: Our analysis is mainly based on redshift data for 128 galaxies acquired at the Telescopio Nazionale Galileo. We combined galaxy velocities and positions to select 110 cluster galaxies and analyze its internal dynamics. We also used new (g', r', i') photometric data acquired at the Isaac Newton Telescope, and (V, i') photometric data available in the Subaru Archive. X-ray data from the XMM-Newton Science Archive were analyzed to study the hot gas component. Results: We estimate the cluster redshift ?z? = 0.177, a high line-of-sight (LOS) velocity dispersion, ?V 1350 km s-1, and the X-ray temperature kT 6.4 keV. Both our optical and X-ray analyses reveal complex dynamical activity. The analysis of the 2D galaxy distribution reveals the presence of two density peaks, one to the east and the other to the west (E and W peaks). Using the full 3D information we detect a high-velocity (?Vrf,LOS 3000 km s-1), low-mass (?V 200-500 km s-1) group at the position of the 2D E peak. For the main system we compute a velocity dispersion ?V 1000-1200 km s-1. In the assumption of a bimodal system we estimate a mass Msys = 1.5-2.9 × 1015 h70-1 M_{&sun;}. The X-ray morphological analysis, which is based on power ratios, centroid shifts, and concentration parameter, confirms that Abell 2254 is a dynamically disturbed cluster. The X-ray isophotes are elongated in the east direction, in agreement with a merger in the post core-crossing phase. A simple bimodal model finds that data are consistent with a bound, outgoing subcluster observed a few fractions of Gyr after the core crossing. However, both optical and X-ray analyses suggest that the main system is, in turn, a nonrelaxed structure, indicating north-south as a possible direction for a past accretion. Conclusions: We conclude that Abell 2254, for its mass and merging structure, fits well among the typical clusters with radio halos. We briefly discuss how the particular irregularity of the radio halo might be linked to the complexity of the Abell 2254 structure.
The purpose of this study is to present a framework for quantitative analysis of spinal curvature in 3D. In order to study the properties of such complex 3D structures, we propose two descriptors that capture the characteristics of spinal curvature in 3D. The descriptors are the geometric curvature (GC) and curvature angle (CA), which are independent of the orientation and size of spine anatomy. We demonstrate the two descriptors that characterize the spinal curvature in 3D on 30 computed tomography (CT) images of normal spine and on a scoliotic spine. The descriptors are determined from 3D vertebral body lines, which are obtained by two different methods. The first method is based on the least-squares technique that approximates the manually identified vertebra centroids, while the second method searches for vertebra centroids in an automated optimization scheme, based on computer-assisted image analysis. Polynomial functions of the fourth and fifth degree were used for the description of normal and scoliotic spinal curvature in 3D, respectively. The mean distance to vertebra centroids was 1.1 mm ({+-}0.6 mm) for the first and 2.1 mm ({+-}1.4 mm) for the second method. The distributions of GC and CA values were obtained along the 30 images of normal spine at each vertebral level and show that maximal thoracic kyphosis (TK), thoracolumbar junction (TJ) and maximal lumbar lordosis (LL) on average occur at T3/T4, T12/L1 and L4/L5, respectively. The main advantage of GC and CA is that the measurements are independent of the orientation and size of the spine, thus allowing objective intra- and inter-subject comparisons. The positions of maximal TK, TJ and maximal LL can be easily identified by observing the GC and CA distributions at different vertebral levels. The obtained courses of the GC and CA for the scoliotic spine were compared to the distributions of GC and CA for the normal spines. The significant difference in values indicates that the descriptors of GC and CA may be used to detect and quantify scoliotic spinal curvatures. The proposed framework may therefore improve the understanding of spine anatomy and aid in the clinical quantitative evaluation of spinal deformities.
The method based on Bag-of-visual-Words (BoW) deriving from local keypoints has recently appeared promising for video annotation. Spatial partition scheme has critical impact to the performance of BoW method. In this paper, we propose a new adaptive annular spatial partition scheme. The proposed scheme firstly determines the centroid of partition according to the distribution of keypoints. And then the image is partitioned into several annular regions. In the end, BoW histograms are computed according to the annular regions, which are utilized to train SVM classifiers. A systematic performance study on TRECVID 2006 corpus containing 20 semantic concepts shows that the proposed scheme is more effective than other popular spatial layout partition schemes such as 2 × 2 grid scheme.
Algorithms were developed for the extraction of two components of mean velocity, standard deviation, and the associated correlation coefficient from laser transit anemometry (LTA) data ensembles. The solution method is based on an assumed two-dimensional Gaussian probability density function (PDF) model of the flow field under investigation. The procedure consists of transforming the data ensembles from the data acquisition domain (consisting of time and angle information) to the velocity space domain (consisting of velocity component information). The mean velocity results are obtained from the data ensemble centroid. Through a least squares fitting of the transformed data to an ellipse representing the intersection of a plane with the PDF, the standard deviations and correlation coefficient are obtained. A data set simulation method is presented to test the data reduction process. Results of using the simulation system with a limited test matrix of input values is also given.
Purpose A multiple inputs and multiple outputs (MIMO) fuzzy-logic-based model was proposed to estimate color and chemical oxygen demand (COD) removal efficiencies in the post-treatment of anaerobically pretreated poultry manure wastewater effluent using Fenton's oxidation process. Three main input variables including initial pH, Fe+2, and H2O2 dosages were fuzzified in a new numerical modeling scheme by the use of an artificial intelligence-based approach. Materials and methods Trapezoidal membership functions with eight levels were conducted for the fuzzy subsets, and a Mamdani-type fuzzy inference system was used to implement a total of 70 rules in the IF?THEN format. The product (prod) and the center of gravity (centroid) methods were applied as the inference operator and defuzzificatio...
Abstract The structure of the Arctic stratospheric polar vortex in three chemistry-climate models (CCMs) taken from the CCMVal-2 intercomparison is examined using zonal mean and geometric-based methods. The geometric methods are employed by taking 2D moments of potential vorticity fields that are representative of the polar vortices in each of the models. This allows the vortex area, centroid location and ellipticity to be determined, as well as a measure of vortex filamentation. The first part of the study uses these diagnostics to examine how well the mean state, variability and extreme variability of the polar vortices are represented in CCMs compared to ERA-40 reanalysis data, and in particular for the UMUKCA-METO, NIWA-SOCOL and CCSR/NIES models. The second part of the study assesses ...
We present a detailed study of the Baryscan technique, a new efficient alternative to the widespread Z-scan technique which has been demonstrated [Opt. Lett. 36:8, 2011] to reach among the highest sensitivity levels. This method is based upon the measurement of optical nonlinearities by means of beam centroid displacements with a position sensitive detector and is able to deal with any kind of lensing effect. This technique is applied here to measure pump-induced electronic refractive index changes (population lens), which can be discriminated from parasitic thermal effects by using a time-resolved Baryscan experiment. This method is validated by evaluating the polarizability variation at the origin of the population lens observed in the reference Cr3+:GSGG laser material.
The charge division technique is a simple concept used in photon-counting imaging detectors to determine one or two-dimensional event coordinates by location of the centroid of the charge cloud generated in the detector. Traditional devices, such as the resistive anode and wedge-and-strip anode, utilize resistive and geometric methods respectively to implement this technique, enabling them to achieve reasonably good spatial resolution at moderate event rates using a low electronic channel count. We describe the Capacitive Division Image Readout (C-DIR), a simple method of implementing charge division readout with major performance advantages and which is simple and economical to construct. C-DIR utilizes three elements; (i) a resistive layer providing event charge localization and DC signa...
A generalization of the Gibbs-Bogoliubov-Feynman inequality for spinless particles is proven and then illustrated for the simple model of a symmetric double-well quartic potential. The method gives a pointwise lower bound for the finite-temperature density matrix and it can be systematically improved by the Trotter composition rule. It is also shown to produce groundstate energies better than the ones given by the Rayleigh-Ritz principle as applied to the groundstate eigenfunctions of the reference potentials. Based on this observation, it is argued that the Local Variational Principle performs better than the equivalent methods based on the centroid path idea and on the Gibbs-Bogoliubov-Feynman variational principle, especially in the range of low temperatures.
Centroid of a graph is a structure composed of nodes closest from all others. This suggests the idea of center of mass average of all edges, weighted by the local density or specific weight. Computing this centroid in a classic way needs a global view of the graph environment. In this paper, an algo...
In the crystal structure of the title compound, C23H20NO4 +·CF3SO3 ?, the cations are linked through C—H?O, C—H?? and ?–? interactions [centroid-centroid distances = 3.641?(2) and 3.885?(2)?Å]. The cation and the anion are held together by C—H?O and S—O?? interactions...
In the title compound, [FeCl2(C18H12N2)], the FeII atom is four-coordinated in a distorted tetrahedral arrangement by an N,N?-bidentate 2,2?-biquinoline ligand and two chloride ions. In the crystal, there are extensive ?–? contacts between the pyridine rings [centroid–centroid distances = 3.7611?(3...
In the title compound, C9H6ClNO, the Cl atom deviates by 0.142?(1)?Å from the quinoline ring mean plane (r.m.s. deviation = 0.013?Å). In the crystal, N—H?O hydrogen bonds link the molecules into [010] C(4) chains. Aromatic ?–? stacking interactions [shortest centroid?centroid distance = 3.685?(3)?...
In its crystal structure, the title compound, C9H7NO3, forms ?-stacked dimers, with a centroid–centroid distance of 3.475?(5)?Å between the benzenoid and the 2,4 dicarbonyl oxazine rings. These dimers then form staircase-like linear chains through further ?-stacking between the benzenoid rings [cent...
In the title compound, C(14)H(9)FN(2), the dihedral angle between the benzene ring and the quinoxaline ring system is 22.2?(3)°. Any aromatic ?-? stacking in the crystal must be very weak, with a minimum centroid-centroid separation of 3.995?(2)?Å. PMID:22719556
In the title compound, C12H14N2O2, the quinoxaline ring system and the C atoms of the methylene and methyl substituents lie on a mirror plane. The crystal packing is stabilized by weak ?–? interactions [centroid–centroid distance = 3.680?(7)?Å].
In the title compound, C14H9FN2, the dihedral angle between the benzene ring and the quinoxaline ring system is 22.2?(3)°. Any aromatic ?–? stacking in the crystal must be very weak, with a minimum centroid–centroid separation of 3.995?(2)?Å.
In the title compound, C14H9FN2, the dihedral angle between the benzene ring and the quinoxaline ring system is 22.2?(3)°. Any aromatic ?–? stacking in the crystal must be very weak, with a minimum centroid–centroid separation of 3.995?(2)?Å.
In the title compound, C15H14N2O2, the aromatic rings are oriented at a dihedral angle of 24.52?(5)°. The dihedral angle between the nitro group and its parent benzene ring is 9.22?(16)°. In the crystal, molecules interact through aromatic ?—? stacking interactions [centroid–centroid separations ...
The title complex, [CuBr(C6H4NO3)(H2O)]n, exhibits a layered structure which is stabilized by intermolecular O—H?O and O—H?Br? hydrogen bonds, van der Waals forces and ?–? interactions [centroid–centroid distance = 3.747(4)?Å] between the parallel pyridine rings from two neighboring layers.
path length, air traffic and weather conditions had to be taken into account. [5]. Originally, three ..... APL. Johns. Hopkins. Univ. Laurel,. MD. CRL. Ministry of. P&T. Kashima,. Japan ...... holds for integral years of observations. The rain ...... centroid location, maximum and minimum lengths from the centroid to each respective ...
The title molecule, C18H19N3O3, lies on a mirror plane that bisects the adamantyl group. In the crystal, C—H?O and C—H?N interactions lead to supramolecular chains along [100]. These assemble into layers in the ab plane via ?–? interactions [centroid–centroid distance = 3.6548?(7)?Å] between th...
In the title compound, [Pt(CH3)2(C18H15As)2], the PtII atom adopts a distorted cis-PtAs2C2 square-planar coordination geometry. In the crystal, molecules interact via aromatic ?–? stacking interactions [centroid–centroid separation = 3.6741?(18)?Å].
In the title compound, [Pt(CH(3))(2)(C(18)H(15)As)(2)], the Pt(II) atom adopts a distorted cis-PtAs(2)C(2) square-planar coordination geometry. In the crystal, mol-ecules inter-act via aromatic ?-? stacking inter-actions [centroid-centroid separation = 3.6741?(18)?Å]. PMID:21579645
In the title compound, [Pt(CH3)2(C18H15As)2], the PtII atom adopts a distorted cis-PtAs2C2 square-planar coordination geometry. In the crystal, molecules interact via aromatic ?–? stacking interactions [centroid–centroid separation = 3.6741?(18)?Å].
It is shown that the centroid of the heliospheric equator undergoes quasi-periodic oscillations. During the minimum of the 11-year cycle, the centroid shifts southwards (the so-called bashful-ballerina effect). The direction of the shift reverses during the solar maximum. The solar quadrupole is responsible for this effect. The shift is compared with the tilt of the heliospheric current sheet.
In the title salt, C18H19N4O+·PF6 ?, the dihedral angle between the benzimidazolium and benzimidazole ring systems is 16.24?(2)°. In the cation, a ?–? interaction is observed between the imidazolium ring and the benzene ring of the benzimidazole ring system [centroid–centroid distanc...
A new benzimidazole compound, C12H14N2O2, has been synthesized by the reaction of 2-methyl-1H-benzimidazole and ethyl 2-bromoacetate. In the crystal structure, weak intermolecular C—H?N hydrogen bonds link the molecules into chains. ??? Contacts (centroid?centroid distance = 3.713?Å) are observed...
If the propagation of a light field can be satisfactorily described by a diffraction integral with an ABCD kernel, the propagation of its irradiance centroid is completely determined by the corresponding ABCD ray-transfer matrix in exactly the same way as if the centroid path were a conventional geo...
Fully automated prostate segmentation helps to address several problems in prostate cancer diagnosis and treatment: it can assist in objective evaluation of multiparametric MR imagery, provides a prostate contour for MR-ultrasound (or CT) image fusion for computer-assisted image-guided biopsy or therapy planning, may facilitate reporting and enables direct prostate volume calculation. Among the challenges in automated analysis of MR images of the prostate are the variations of overall image intensities across scanners, the presence of nonuniform multiplicative bias field within scans and differences in acquisition setup. Furthermore, images acquired with the presence of an endorectal coil suffer from localized high-intensity artifacts at the posterior part of the prostate. In this work, a three-dimensional method for fast automated prostate detection based on normalized gradient fields cross-correlation, insensitive to intensity variations and coil-induced artifacts, is presented and evaluated. The components of the method, offline template learning and the localization algorithm, are described in detail. The method was validated on a dataset of 522 T2-weighted MR images acquired at the National Cancer Institute, USA that was split in two halves for development and testing. In addition, second dataset of 29 MR exams from Centre d'Imagerie Médicale Tourville, France were used to test the algorithm. The 95% confidence intervals for the mean Euclidean distance between automatically and manually identified prostate centroids were 4.06 +/- 0.33 mm and 3.10 +/- 0.43 mm for the first and second test datasets respectively. Moreover, the algorithm provided the centroid within the true prostate volume in 100% of images from both datasets. Obtained results demonstrate high utility of the detection method for a fully automated prostate segmentation.
Autonomous navigation systems for mobile robots have been successfully deployed for a wide range of planar ground-based tasks. However, very few counterparts of the previous planar navigation systems were developed for three-dimensional (3-D) motion, which is needed for unmanned aerial vehicles (UAVs). Safe maneuvering in complex environments is a major challenge for UAVs. Future urban reconnaissance and search missions will require UAVs to autonomously navigate through cluttered urban spaces. This research proposes two approaches for unmanned helicopter navigation in cluttered urban environments: a 3-D fuzzy behavioral approach and a 3-D vector field histogram (VFH) approach. Behavior-based control has been very successful for planar mobile robots navigation in unknown environments. A novel fuzzy behavioral scheme for navigating an unmanned helicopter in cluttered 3-D spaces is developed. The 3-D navigation problem is decomposed into several identical two-dimensional (2-D) navigation sub-problems, each of which is solved by using preference-based fuzzy behaviors. Due to the shortcomings of vector summation during the fusion of the 2-D sub-problems, instead of directly outputting steering subdirections by their own defuzzification processes, the undefuzzified intermediate results of the sub-problems are fused to a 3-D solution region, representing degrees of preference for the robot movement. A new defuzzification algorithm that steers the robot by finding the centroid of a 3-D convex region of maximum volume in the 3-D solution region is developed. A fuzzy speed control system is also developed to ensure the efficiency and safety of the navigation. The VFH approach is very popular for planar mobile robots. A 3-D VFH approach to UAV navigation in cluttered urban environments is developed. A 3-D laser measurement system is used to obtain the obstacle distribution in this method. Instead of a 2-D Cartesian histogram grid as a world model, a 3-D spherical histogram mesh is applied. This 3-D histogram mesh is updated continuously with range data. The 3-D VFH method subsequently employs a two-stage data-reduction process in order to compute the desired control commands for the robot. In the first stage the 3-D histogram mesh is reduced to a 2-D polar histogram corresponding to all possible steering directions for the robot. In the second stage, a novel convex finding algorithm is applied to efficiently find candidate directions from the 2-D polar histogram. The most suitable sector within the candidates with the lowest value of a particular cost function is selected, and the steering of the robot is aligned with that direction. Substantial simulations have been carried out to demonstrate that the two algorithms proposed in this dissertation can smoothly and effectively guide an unmanned helicopter through unknown and cluttered urban environments. Comparison simulation results show that the 3-D VFH has the ability to travel shorter and smoother pathes at most of scenarios. However, the feature doesn't apply to the 2-D counterparts. The 2-D fuzzy behavioral method usually has a smoother path, but the 2-D VFH travels a shorter path in most of scenarios.
We investigate 35 pre-stellar cores and 36 proto-stellar cores in the Perseus molecular cloud. We find a very tight correlation between the physical parameters describing the N2H+ and NH3 gas. Both the velocity centroids and the line widths of N2H+ and NH3 correlate much better than either species correlates with CO, as expected if the nitrogen-bearing species are probing primarily the dense core gas where the CO has been depleted. We also find a tight correlation in the inferred abundance ratio between N2H+ and para-NH3 across all cores, with N(p-NH3)/N(N2H+)= 22 +/- 10. We find a mild correlation between NH3 (and N2H+) column density and the (sub)millimeter dust continuum derived H2 column density for pre-stellar cores, N(p-NH3)/N(H2) ~ 10e-8, but do not find a fixed ratio for proto-stellar cores. The observations suggest that in the Perseus molecular cloud the formation and destruction mechanisms for the two nitrogen-bearing species are similar, regardless of the physical conditions in the dense core gas. ...
In this work a rigorous method for the calibration of a liquid scintillation counter for sup 2 sup 1 sup 0 Pb activity determination is proposed. The variation of the PSA threshold level for alpha/beta discrimination with the colour quenching is analysed for different beta energies. Also the changes in some parameters of the detector response, as the muon-peak, the channel ratio and the centroid of the spectrum, due to colour quenching are studied. The relationship between such parameters and the counting efficiency is described in such a way that the effects of colour in the efficiency are established. sup 9 sup 9 Tc is proposed as a good standard to calibrate the counter for sup 2 sup 1 sup 0 Pb determination in real samples.
In the present study, the optimized mixture proportions of low cholesterol-low fat mayonnaise contained soy milk as an egg yolk substitute (10%) with different composition of xanthan gum (XG), guar gum (GG) and mono- & diglycerides emulsifier (MDG) (0-0.36% of each component) were determined by applying the simplex-centroid mixture design method to achieve the desired stability, textural and rheological properties and sensory characteristics for effective formulation process. Results revealed that the best mixture was the formulation contained 6.7% mono- & diglycerides, 36.7% guar gum and 56.7% xanthan gum. The xanthan gum was the component showing the highest effect on all the properties of mayonnaise samples. In addition, an increase of xanthan gum followed by guar gum caused greater val...
Summary A central problem of seismology is the inversion of regional waveform data for models of earthquake sources. In regions such as Southern California, preliminary 3-D earth structure models are already available, and efficient numerical methods have been developed for 3-D anelastic wave-propagation simulations. We describe an automated procedure that utilizes these capabilities to derive centroid moment tensors (CMTs). The procedure relies on the use of receiver-side Green's tensors (RGTs), which comprise the spatial-temporal displacements produced by the three orthogonal unit impulsive point forces acting at the receivers. We have constructed a RGT database for 219 broad-band stations in Southern California using a tomographically improved version of the 3-D SCEC Community Velocity ...
A new technique of two dimensional mold filling simulation based on the Direct Finite Difference Method has been developed. Non-orthogonal elements can be employed in this technique so that the original complicated and thin shape of a casting, including the gating system, can be retained in its simulation model. Pressure points are located at each centroid of the rectangular element while fluid velocity vectors are at vertexes which are the representative points of nodal regions formed around the vertexes. The momentum equation is discretized in each nodal region while the mass conservation equation is discretized in element. Two dimensionless parameters ??, ?s are defined to predict the free surface movement more accurately and mass conservation in the free surface regions is solved explicitly by using these parameters. Some numerical mold filling examples, namely die casting of a disk-like cavity and gravity casting of a curved gating system, showed promising results of the proposed technique.
A rigorous analytical method is presented for calculating the interaction factor between two identical piles subjected to vertical loads. Following the technique proposed by Muki and Sternberg, the problem is decomposed into an extended soil mass and two fictitious piles characterized respectively by Young?s modulus of the soil and that of the difference between the pile and soil. The unknown axial forces along fictitious piles are determined by solving a Fredholm integral equation of the second kind, which imposes the compatibility condition that the axial strains of the fictitious piles are equal to those corresponding to the centroidal axes of the extended soil. The real pile forces and displacements can subequally be calculated based on the determined fictitious pile forces, and finall...
PurposeTo evaluate implanted markers as a surrogate for tumor-based setup during image-guided lung cancer radiotherapy with audiovisual biofeedback. Methods and MaterialsSeven patients with locally advanced non-small-cell lung cancer were implanted bronchoscopically with gold coils. Markers, tumor, and a reference bony structure (vertebra) were contoured for all 10 phases of the four-dimensional respiration-correlated fan-beam computed tomography and weekly four-dimensional cone-beam computed tomography. ResultsThe systematic/random interfractional marker-to-tumor centroid displacements were 2/3, 2/2, and 3/3 mm in the x (lateral), y (anterior-posterior), and z (superior-inferior) directions, respectively. The systematic/random interfractional marker-to-bone displacements were 2/3, 2/3, an...
We investigate the theoretical and practical rate-distortion (R-D) performance of resolution-constrained quantization (RCQ) combined with lossless coding (RCQ+). Based on the high-rate theory, the required rate difference between RCQ and RCQ+, at a given mean distortion, is found to be the Kullback-Leibler distance (KLD) between the source probability density function (PDF) and its rateless centroid density function. Thus, the rate reduction in RCQ+ is diminished as vector dimensionality increases or as the source PDF approaches uniform density. In the experiments with Gaussian data, the R-D performance of high-rate derivation is verified. Huffman coding is implemented on top of the conventional RCQ methods such as ITU-T G.711 and G.722.2 speech coders, and the rate reduction with RCQ+ is found to be decreased for lower values of the KLD.
According to the FLIR image of complex ground fixed target have disordered gray difference between target and background, and no base image available, we propose a target detection algorithm in FLIR imagery using scale space theory. First the reference image been created depending on the satellite dates, 2D Forward-looking image sequences of target regions created by using VRMap software according to the flying route. After performing LoG filtering on these reference images, we obtain a series of characteristic scale, where each scale is related to the size of target. Using these scales, several blob-like candidate regions can be found with the same size with reference image. Then the result is obtained between candidate regions and the reference image using Hausdorff measure and centroid distance. A simulation experiment is developed for the proposed algorithm and results show that our method has high accuracy and quickly performance and it has strong practicability.
During vapor explosion process, multiphase materials coexist. However, our understanding of multiphase flow is still limited. More efforts are needed to improve our understanding of this flow phenomenon and to provide information to validate theoretical models and numerical simulations. Therefore, there is a strong need to develop a quantitative measurement technique to obtain velocity distribution of each phase in multiphase flows. In this research, experimental apparatus was set up to simulate the vapor explosion phenomena, and PTV combined with the image processing method was used to quantify the vapor size and velocity. Dilation and erosion operation was utilized to detect the vapor edge from the original image. And then the centroid and velocity of each vapor were computed for the two-dimensional multiphase flow. Based on these results, it was concluded that an accurate measurement of each phase velocity is possible, and further work is recommended for the measurement of the three-dimensional motion of the vapor. 19 refs., 37 figs. (Author)
The motion of single- and two-cavitation bubbles generated by laser beams directly beneath a free surface is studied experimentally, using high-speed photography, and theoretically using the highly accurate boundary integral method. Favorable comparisons of bubble shape history and centroid motion are observed while the numerical calculations provide information on the pressure field surrounding the bubbles. A range of responses, including the null impulse state, is obtained for the two bubbles depending on the bubble size ratio and the interbubble and bubble-free surface distances, although in all cases reported in this article, the bubble nearest the free surface yields a high-speed liquid jet directed away from the free surface. It is also found that when the free-surface{endash}bubble interaction is strong, a fast free-surface spike is formed for both the single- and two-bubble cases. {copyright} 2001 American Institute of Physics.
The present study is concerned with the out-of-plane vibrations of a rotating, internally damped (Kelvin-Voigt model) Bernoulli-Euler beam carrying a tip mass. The centroid of the tip mass, possessing also a mass moment of inertia is offset from the free end of the beam and is located along its extended axis. This system can be thought of as an extremely simplified model of a helicopter rotor blade or a blade of an auto-cooling fan. The differential eigenvalue problem is solved by using Frobenius method of solution in power series. The characteristic equation is then solved numerically. The simulation results are tabulated for a variety of the nondimensional rotational speeds, tip mass, tip mass offset, mass moment of inertia and internal damping parameters. These are compared with the res...
Microarrays are made it possible to simultaneously monitor the expression profiles of thousands of genes under various experimental conditions. It is used to identify the co-expressed genes in specific cells or tissues that are actively used to make proteins. This method is used to analysis the gene expression, an important task in bioinformatics research. Cluster analysis of gene expression data has proved to be a useful tool for identifying co-expressed genes, biologically relevant groupings of genes and samples. In this paper we applied K-Means with Automatic Generations of Merge Factor for ISODATA- AGMFI. Though AGMFI has been applied for clustering of Gene Expression Data, this proposed Enhanced Automatic Generations of Merge Factor for ISODATA- EAGMFI Algorithms overcome the drawbacks of AGMFI in terms of specifying the optimal number of clusters and initialization of good cluster centroids. Experimental results on Gene Expression Data show that the proposed EAGMFI algorithms could identify compact clus...
A system design and automation of a microbiological instrument that locates bacterial colonies and captures the forward-scattering signatures are presented. The proposed instrument integrates three major components: a colony locator, a forward scatterometer and a motion controller. The colony locator utilizes an off-axis light source to illuminate a Petri dish and an IEEE1394 camera to capture the diffusively scattered light to provide the number of bacterial colonies and two-dimensional coordinate information of the bacterial colonies with the help of a segmentation algorithm with region-growing. Then the Petri dish is automatically aligned with the respective centroid coordinate with a trajectory optimization method, such as the Traveling Salesman Algorithm. The forward scatterometer automatically computes the scattered laser beam from a monochromatic image sensor via quadrant intensity balancing and quantitatively determines the centeredness of the forward-scattering pattern. The final scattering signatures are stored to be analyzed to provide rapid identification and classification of the bacterial samples.
The geothermal structure beneath of the Barramiya?Red Sea coast area of the Central Eastern Desert of Egypt has been determined using Curie point depth (CPD), which is temperature-dependent. The CPD and the surface heat flow (q) maps of such area are estimated by analyzing aeromagnetic data. Such data are low-pass-filtered and analyzed to estimate the magnetic bottom using the centroidmethod. The heat flow map reflects the geothermic nature of the region. However, it is suggested that the shallow Curie point temperature depth pattern depends on the tectonic regime and morphology, which continues eastwards through the Red Sea. Particularly, the coastal regions are characterized by high heat flow (83.6?mW/m2) and shallow Curie depth (22.5?km), whereas the western portion of the studied area...
This paper analyses the occipital remains recovered from the El Sidron (Asturias, Spain) Neandertal site between the years of 2000-2008. The sample is represented by three specimens, SD-1219, SD-1149, and SD-370a. Descriptive morphology, linear measurements, 3D geometric morphometrics, and virtual anthropological methods were employed to address the morphological, morphometric, and phylogenetic affinities of these fossils. The fossils display Neandertal autapomorphies (e.g., bilaterally protruding transverse occipital torus, suprainiac fossa). SD-1219 also preserves a strongly projecting juxtamastoid eminence and shows occipital bunning. In linear distances, the El Sidron occipitals are similar to each other and close to the Neandertal mean. The centroid size of SD-1219 is slightly larger ...
This is part two of a series on the optical modeling activities for JWST. Starting with the linear optical model discussed in part one, we develop centroid and wavefront error sensitivities for the special case of a segmented optical system such as JWST, where the primary mirror consists of 18 individual segments. Our approach extends standard sensitivity matrix methods used for systems consisting of monolithic optics, where the image motion is approximated by averaging ray coordinates at the image and residual wavefront error is determined with global tip/tilt removed. We develop an exact formulation using the linear optical model, and extend it to cover multiple field points for performance prediction at each instrument aboard JWST. This optical model is then driven by thermal and dynamic structural perturbations in an integrated modeling environment. Results are presented.
Abstract Relatively unexplored in recent years, turbulence in the ionized interstellar medium could allow us to explain peculiar gas motions observed in H-ii regions. We present an improved method that allows the extraction of quasi-homogeneous turbulent motions from bidimensional radial velocity maps. This paper is an application to the NGC-595 nebula, a giant H-ii region in M33. The use of the Zurflueh filter is re-instated in order to separate ordered motions from turbulent fluctuations in astronomical observations. A statistical approach, based on the application of the autocorrelation and second-order structure functions, is used on the filtered centroid measurements in H, [O-iii] and [S-ii]. Following the work of Brunt & Mac Low, an investigation of the density inhomogeneities in NGC...
We have operated a Medipix2 CMOS readout chip, with amplifying, shaping and charge discriminating front-end electronics integrated on the pixel level, as a highly segmented direct charge collecting anode in a Three-Stage Gas Electron Multiplier (Triple-GEM) to detect the ionization from {sup 55}Fe X-rays and electrons from {sup 106}Ru. The device allows to perform moderate energy spectroscopy measurements (20% FWHM at 5.9keV X-rays) using only digital readout and two discriminator thresholds. Being a truly 2D detector, it allows to observe individual clusters of minimum ionizing charged particles in Ar/CO{sub 2} (70:30) and He/CO{sub 2} (70:30) mixtures and to achieve excellent spatial resolution for position reconstruction of primary clusters down to {approx}50{mu}m, based on the binary centroid determination method.
This paper presents a laboratory study of multi-class classification problem for multiple indoor air contaminants which belongs to a completely linear-inseparable case. Six kinds of indoor air contaminations (formaldehyde, benzene, toluene, carbon monoxide, ammonia and nitrogen dioxide) were recognized as indicators of air quality in this project. The effectiveness of the proposed HSVM model has been rigorously evaluated on the experimental E-nose data sets. In addition, we have also compared it with existing five methods including Euclidean distance to centroids (EDC), simplified fuzzy ARTMAP network (SFAM), multilayer perceptron neural network (MLP) based on back-propagation learning rule, individual FLDA and single SVM. Experimental results have demonstrated that the HSVM model outperfo...
A localization algorithm for ultrasonic robot described is based on range readings from wide beam ultrasonic transducers to built a model of the empty regions in the room. The method is incorporated into a move-to-station behavior which was demonstrated on the Georgia Tech mobile robot. A belief model of the range of readings that was based on Dempster-Shafer theory was used to compute the belief of points in the environment being empty, occupied, or unknown. The current belief in the empty space was used to construct a weighted centroid of the empty space after each move of the robot. By moving toward this center of mass and continually adding to the beliefs of the point in the environment the robot iteratively moved to the center of the open space.
An integrated Feynman path integral-free energy perturbation and umbrella sampling (PI-FEP/UM) method has been used to investigate the kinetic isotope effects (KIEs) in the proton transfer reaction between nitroethane and acetate ion in water. In the present study, both nuclear and electronic quantum effects are explicitly treated for the reacting system. The nuclear quantum effects are represented by bisection sampling centroid path integral simulations, while the potential energy surface is described by a combined quantum mechanical and molecular mechanical (QM/MM) potential. The accuracy essential for computing KIEs is achieved by a FEP technique that transforms the mass of a light isotope into a heavy one, which is equivalent to the perturbation of the coordinates for the path integral...
Clustering XML documents is extensively used to organize large collections of XML documents in groups that are coherent according to structure and/or content features. The growing availability of distributed XML sources and the variety of high-demand environments raise the need for clustering approaches that can exploit distributed processing techniques. Nevertheless, existing methods for clustering XML documents are designed to work in a centralized way. In this paper, we address the problem of clustering XML documents in a collaborative distributed framework. XML documents are first decomposed based on semantically cohesive subtrees, then modeled as transactional data that embed both XML structure and content information. The proposed clustering framework employs a centroid-based partiti...
This study designs and characterizes a novel precise optics-based autofocusing microscope with both the large linear autofocusing range and the rapid response. In contrast to conventional optics-based autofocusing microscopes with centroidmethod, the proposed microscope comprises two optical paths, namely one optical path which provides a short linear autofocusing range but an extremely high focusing accuracy and a second optical path which achieves a long linear autofocusing range but a reduced focusing accuracy. The two optical paths are combined using a self-written autofocus-processing algorithm to realize an autofocusing microscope with a large linear autofocusing range, a rapid response, and a high focusing accuracy. The microscope is characterized numerically using commercial softw...
We demonstrate subcentimeter depth profiling at a stand off distance of 330 m using a time-of-flight approach based on time-correlated single-photon counting. For the first time to our knowledge, the photon-counting time-of-flight technique was demonstrated at a wavelength of 1550 nm using a superconducting nanowire single-photon detector. The performance achieved suggests that a system using superconducting detectors has the potential for low-light-level and eye-safe operation. The system's instrumental response was 70 ps full width at half-maximum, which meant that 1 cm surface-to-surface resolution could be achieved by locating the centroids of each return signal. A depth resolution of 4 mm was achieved by employing an optimized signal-processing algorithm based on a reversible jump Markov chain Monte Carlo method.
Context. Isolated starless cores within molecular clouds can be used as a testbed to investigate the conditions prior to the onset of fragmentation and gravitational proto-stellar collapse. Aims: We aim to determine the distribution of the dust temperature and the density of the starless core B68. Methods: In the framework of the Herschel guaranteed-time key programme "The Earliest Phases of Star formation" (EPoS), we have imaged B68 between 100 and 500 ?m. Ancillary data at (sub)millimetre wavelengths, spectral line maps of the 12CO (2-1), and 13CO (2-1) transitions, as well as an NIR extinction map were added to the analysis. We employed a ray-tracing algorithm to derive the 2D mid-plane dust temperature and volume density distribution without suffering from the line-of-sight averaging effects of simple SED fitting procedures. Additional 3D radiative transfer calculations were employed to investigate the connection between the external irradiation and the peculiar crescent-shaped morphology found in the FIR maps. Results: For the first time, we spatially resolve the dust temperature and density distribution of B68, convolved to a beam size of 36.?4. We find a temperature gradient dropping from (16.7-1.0+1.3) K at the edge to (8.2-0.7+2.1) K in the centre, which is about 4 K lower than the result of the simple SED fitting approach. The column density peaks at NH = (4.3-2.8+1.4) × 1022 cm-2, and the central volume density was determined to nH = (3.4-2.5+0.9) × 105 cm-3. B68 has a mass of 3.1 M&sun; of material with AK > 0.2 mag for an assumed distance of 150 pc. We detect a compact source in the southeastern trunk, which is also seen in extinction and CO. At 100 and 160 ?m, we observe a crescent of enhanced emission to the south. Conclusions: The dust temperature profile of B68 agrees well with previous estimates. We find the radial density distribution from the edge of the inner plateau outward to be nH ? r-3.5. Such a steep profile can arise from either or both of the following: external irradiation with a significant UV contribution or the fragmentation of filamentary structures. Our 3D radiative transfer model of an externally irradiated core by an anisotropic ISRF reproduces the crescent morphology seen at 100 and 160 ?m. Our CO observations show that B68 is part of a chain of globules in both space and velocity, which may indicate that it was once part of a filament that dispersed. We also resolve a new compact source in the southeastern trunk and find that it is slightly shifted in centroid velocity from B68, lending qualitative support to core collision scenarios. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.Partially based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile, as part of the observing programme 78.F-9012.Appendices are available in electronic form at http://www.aanda.org
A method and apparatus for determining centroid channel locations is disclosed for use in a system activated by one or more multichannel plates (16,18) and including a linear diode array (24) providing channels of information 1, 2, . . . , n, . . . , N containing signal amplitudes A.sub.n. A source of analog A.sub.n signals (40), and a source of digital clock signals n (48), are provided. Non-zero A.sub.n values are detected in a discriminator (42). A digital signal representing p, the value of n immediately preceding that whereat A.sub.n takes its first non-zero value, is generated in a scaler (50). The analog A.sub.n signals are converted to digital in an analog to digital converter (44). The digital A.sub.n signals are added to produce a digital .SIGMA.A.sub.n signal in a full adder (46). Digital 1, 2, . . . , m signals representing the number of non-zero A.sub.n are produced by a discriminator pulse counter (52). Digital signals representing 1 A.sub.p+ 1, 2 A.sub.p+2, . . . , m A.sub.p+m are produced by pairwise multiplication in multiplier (54). These signals are added in multiplier summer (56) to produce a digital .SIGMA.nA.sub.n -p.SIGMA.A.sub.n signal. This signal is divided by the digital .SIGMA.A.sub.n signal in divider (58) to provide a digital (.SIGMA.nA.sub.n /.SIGMA.A.sub.n) -p signal. Finally, this last signal is added to the digital p signal in an offset summer (60) to provide .SIGMA.nA.sub.n /.SIGMA.A.sub.n, the centroid channel locations.
The potential of the laser-induced argon spark atomizer (LINA-Spark atomizer) coupled with ICP-AES as a convenient device for direct analysis of WC/Co powdered precursors of sintered hardmetals was studied. The samples were presented for the ablation as pressed pellets prepared by mixing with powdered silver binder containing GeO2 as internal standard. The pellets were ablated with the aid of a Q-switched Nd:YAG laser (1064 nm) focused 16 mm behind the target surface with a resulting estimated power density of 5 GW cm(-2). Laser ablation ICP-AES signals were studied as a function of ablation time, and the duration of time prior to measurement (pre-ablation time) which was necessary to obtain reliable results was about 40 s. Linear calibration plots were obtained up to 10% (m/m) Ti, 9% Ta and 3.5% Nb both without internal standardization and by using germanium as an added internal standard or tungsten as a contained internal standard. The relative uncertainty at the centroid of the calibration line was in the range from +/- 6% to +/- 11% for Nb, Ta and Ti both with and without internal standardisation by Ge. A higher spread of points about the regression was observed for cobalt for which the relative uncertainty at the centroid was in the range from +/- 9% to +/- 14%. Repeatability of results was improved by the use of both Ge and W internal standards. The lowest determinable quantities calculated for calibration plots were 0.060% Co, 0.010% Nb, 0.16% Ta and 0.030% Ti with internal standardization by Ge. The LA-ICP-AES analyses of real samples led to good agreement with the results obtained by solution-based ICP determination with a relative bias not exceeding 10%. The elimination of the dissolution procedure of powdered tungsten (Nb, Ta, Ti) carbide is the principal advantage of the developed LA-ICP-AES method. PMID:14564441
One of the precise widely used global Zenith Hydrostatic Delay (ZHD) model is based on the gravity value at the centroid of the atmospheric column at the station of observation and gravity value at the centroid is constant in this model for a specific location throughout the year. However, as the content and extent of atmosphere varies temporally, its centroid and consequently gravity value at the centroid also varies. Apart from this, the actual atmospheric condition of different region is not alike. Therefore, there is a need to develop a regional mean gravity model and development of such model has been discussed in this paper. To obtain the mean gravity model, first a regional model of centroid height of atmospheric column was developed as a function of the surface pressure and temperature. It was developed by multiple regressions between estimated centroid of the atmosphere and surface pressure, surface temperature using radiosonde data of five radiosonde stations spread over the Indian subcontinent. Three years radiosonde data from 2006 to 2008 was used for each station. The root mean square error in estimating centroid of the atmospheric column is about ±326 m, which is negligible considering the variability of the atmosphere and its content. The centroid height model has been used to formulate the mean gravity model, considering uniform lapse rate in gravity with height. It is found that proposed mean gravity model provides temporal variation of mean gravity values at the centroid and thus matches with the reality. The interesting advantage of the developed model is that the model shows diurnal variation of mean gravity. The accuracy of ZHD has shown of the order of about 0.3 mm using the developed regional mean gravity model. However, already developed ZHD model has shown a slight inferior result compared to the developed model. These models have shown accuracy of about 0.8 mm and 0.6 mm.
When the low-energy octupole state and low-energy octupole resonance are considered as a single composite mode in {ital A}=24--54 even-even nuclei, a regular pattern for the energy centroids is found. The location of the energy centroid as a function of nuclear mass can be explained in terms of the effects of shell structure on collective octupole excitations. It is predicted that the energy of the centroid of the composite mode in the stable isotope {sup 50}Cr, where it has not yet been measured, is 5.7{plus minus}0.4 MeV.
In the title compound, C17H12O4, the six-membered heterocyclic ring adopts a distorted screw-boat conformation. The molecular structure exhibits an S(6) ring motif, owing to an intramolecular O—H?O hydrogen bond. In the crystal, weak C—H?O contacts generate an infinite chain along the c axis. There are also ?–? stacking interactions between neighbouring isochromanedione benzene rings, with a centroid–centroid distance of 3.755?(1)?Å, and C—O?? interactions with an O?centroid distance of 3.964?(2)?Å. PMID:1708086
The cross-strip imaging readout employs charge division, and centroiding, of microchannel plate charge signals detected on two orthogonal layers of sense strips to encode event X-Y positions and times. We have developed cross-strip detectors and fully parallel channel position encoding electronics. The front-end amplifiers utilize two 32-channel pre-amplifier ASICs that send signals to a full 64-channel 60 MHz ADC circuit followed by a FPGA event-processing board. Tests with a software Finite Impulse Response filter and centroiding algorithm demonstrate 1 MHz in combination with firmware-based FPGA centroiding algorithms.
Cell motility and migration are central to the development and maintenance of multicellular organisms, and errors during this process can lead to major diseases. Consequently, the mechanisms and phenomenology of cell motility are currently under intense study. In recent years, a new interdisciplinary field focusing on the study of biological processes at the nanoscale level, with a range of technological applications in medicine and biological research, has emerged. The work presented in this thesis is at the interface of cell biology, image processing, and stochastic modeling. The stochastic models introduced here are based on persistent random motion, which I apply to real-life studies of cell motility on flat and nanostructured surfaces. These models aim to predict the time-dependent position of cell centroids in a stochastic manner, and conversely determine directly from experimental recordings of cell motility the various motility parameters. This can aid the experimentalist to draw biologically relevant conclusions about cell-substrate interactions. The need to track cells in a large number of movies has raised the question of automation of cell tracking and that of reproducibility and robustness of cell centroid measurement. To address this, I wrote the PACT cell tracking program, which is optimized for uniform as well as non-uniform backgrounds such as nanostructured surfaces. Rapid progress in the field of the automation of cell tracking steered us into a comparative study of PACT’s performance against other cell tracking programs. We find that different programs yield somewhat different results when applied to the same movie of migrating cells but that the differences are not statistically significant. To introduce persistent random motion, I first present a study of idealized random motion in two dimensions. This finds direct application to experimental studies of cell membrane fluidity and membrane protein dynamics, and I improve on the methodology currently used in that field by showing how to assess the randomness of the motility and how to optimally determine the diffusion coefficient. By adding a persistence component to simple random motion I introduce the standard Ornstein-Uhlenbeck process. I build on this commonly used cell motility model to address the challenges of working with real-life data: positional (centroid coordinate measuring) error and time discretization (due to finite frame rate in a movie of motile cells). This includes optimally measuring the motility parameters and balancing precision of measurement against the mathematical complexity of real-life models of cell motility. Finally, I expanded our understanding of cell response to surface topography by generalizing the Orstein-Uhlenbeck process to study cell motility on anisotropic substrates. I apply the general model to analyze cell motility on a series of anisotropic substrates and discuss the implications of our observations. This work is potentially useful to cell biologists by addressing theirneed for precise yet simple tools for studies of cell motility. The advances in the theoretical understanding of motility presented here bear the experimentalists’ needs in mind, and can find direct technological applications such as cell guidance and growth using nanotopography.
Rainfall is regarded as the most important input for the hydrology and nonpoint source (H/NPS) models and uncertainty related to rainfall is generally recognized as a major challenge in watershed modeling. In this paper, we focus on the impact of spatial rainfall variability on H/NPS modeling of a large watershed. The uncertainty introduced by spatial rainfall variability was determined using a number of commonly-used interpolation methods: (1) the Centroidmethod; (2) the Thiessen Polygon method; (3) the Inverse Distance Weighted (IDW) method; (4) the Dis-Kriging method; and (5) the Co-Kriging method. The Soil and Water Assessment tool (SWAT) was used to quantify the effect of rainfall spatial variability on watershed H/NPS modeling of the Daning watershed in China. Results indicated that these interpolation methods could contribute significant uncertainty in spatial rainfall variability and the carry-magnify effect caused even larger uncertainty in the H/NPS modeling. This uncertainty was magnified from hydrology modeling (stream flow) into NPS modeling (sediment, TP, organic nitrogen (N) and dissolved N). This study further suggested that H/NPS prediction uncertainty relating to spatial rainfall variability was scale-dependent due to the averaging effect of spatial heterogeneity. From a practical point of view, a global interpolation method, such as IDW and Kriging, as well as elevation data derived from a digital elevation model (DEM), should be included into the H/NPS models for reliable predictions in larger watersheds.
The Draco dwarf spheroidal galaxy (dSph), with its apparent immense mass to light ratio and compact size, holds many clues to the nature of the enigmatic dark matter. Here we present deep photometric studies of this dwarf galaxy, undertaken with the MegaCam Camera at the Canada-France-hawaii Telescope, the Wide Field Camera at the Isaac Newton Telescope and the Wide-Field and Planetary Camera on board the Hubble Space Telescope. The new photometric data cover the entirety of the galaxy, and reach i=24.5 at 50% completeness, significantly deeper than previous panoramic studies, allowing searches for tidal disturbances of much lower surface brightness than has been possible before. With these improved statistics, we find no evidence for asymmetric disturbances or tidal tails that possess more than 3% of the stars found within the centre of the galaxy. We find that the central stellar density, as probed by the HST data, rises into the central 0.5'. Uncertainties in the position of the centroid of the galaxy do n...
Glacial earthquakes are anomalous earthquakes associated with large ice-loss events occurring at marine-terminating glaciers, primarily in Greenland. They are detectable teleseismically, and a proper understanding of the source mechanism may provide a remote-sensing tool to complement glaciological observations of these large outlet glaciers. We model teleseismic surface-wave waveforms to obtain locations and centroid–single-force source parameters for 121 glacial earthquakes occurring in Greenland during the period 2006–2010. We combine these results with those obtained by previous workers to analyze spatial and temporal trends in glacial-earthquake occurrence over the 18-year period from 1993–2010. We also examine earthquake occurrence at six individual glaciers, comparing the earthquake record to independently obtained observations of glacier change. Our findings confirm the inference that glacial-earthquake seismogenesis occurs through the capsize of large, newly calved icebergs. We find a close correspondence between episodes of glacier retreat, thinning, and acceleration and the timing of glacial earthquakes, and document the northward progression of glacial earthquakes on Greenland's west coast over the 18-year observing period. Our results also show that glacial earthquakes occur when the termini of the source glaciers are very close to the glacier grounding line, i.e., when the glaciers are grounded or nearly grounded.
We have developed a new fast simulator that takes as inputs cloud fields from a general circulation model (GCM) or profiles of optical extinction from CloudSat/MODIS on NASA's A-train satellites and produces an estimate of the cloud optical centroid pressure (OCP). The OCP is a parameter commonly used in trace-gas retrieval algorithms to account for photon-pathlength variations produced by clouds and aerosol. It also provides information about cloud vertical structure that is different from the cloud-top pressure; it is more sensitive to the mean solar photon-penetration depth. There are two algorithms that estimate cloud optical centroid cloud pressure from the Ozone Monitoring Instrument (OMI) on the NASA Aura satellite. One approach makes use of the filling-in of solar Fraunhofer lines due to rotational-Raman scattering at ultraviolet wavelengths and the other uses oxygen dimer absorption near 477 nm. We have compared our fast simulator results with those from a more exact radiative transfer simulation of the OMI rotational-Raman cloud OCP based on CloudSat optical extinction profiles. The results show that the fast simulator performs well for OMI cloud OCP retrievals. We then use the fast simulator with CloudSat/MODIS data to do a detailed comparison with collocated OMI cloud OCP retrievals from both OMI cloud OCP algorithms in order to assess the performance of these retrievals under a wide range of conditions. We find generally good agreement between OMI cloud OCPs and those predicted by CloudSat at moderate to high effective cloud fractions. However, some differences are apparent. These differences may be attributed to several factors including undetected snow and ice, cloud 3D effects, representativeness (collocation) error, and systematic differences between the OMI visible and UV retrievals and the extinction profiles derived from the CloudSat millimeter cloud radar in conjunction with MODIS radiances. We find that both OMI cloud algorithms produce very similar results. Because the two OMI algorithms are completely independent (based on different physical principles and measurements made with 2 separate detectors), differences are not likely due to OMI measurement or retrieval errors.
A modified three point Gaussian (MTPG) method for analyzing histogrammed peaks which are assumed to have an underlying Gaussian distribution has been developed. The original three point Gaussian method introduces systematic biases in estimating area A and full-width at half maximum (FWHM) of Gaussian peaks in histogrammed spectra, in addition to resulting in relatively large uncertainties in these estimates. This bias is caused by choosing the midpoint of each bin as the x-coordinate when calculating the three parameters of a Gaussian distribution (A, centroid {mu}, and FWHM). The MTPG method applied an iterative procedure to more accurately determine the x-coordinate for each bin used in three point Gaussian method. In the FWHM range of about 0.5-2 bins, the MTPG method converged after several iterations (typically 5 to 6), in the process eliminating the bias introduced by the original method. Additionally, the uncertainties of A and FWHM estimates in this same FWHM range were minimized and approached the statistical limits. A detailed description of the MTPG method and results over a range of peak areas and FWHMs are presented.
We characterize certain maps by their action on a fixed polynomial in noncommuting variables on algebras satisfying certain d -freeness condition. Consequently, a characterization of the centroid of a prime ring is obtained.
1, 1989. Jin, M. Yo,. A Doppler. Centroid ...... Thermosense. XI,. SPIE. Vol. 1094, pp. 123 and 138-147,. 1989. Glazman,. R. E., and P. B. Weichman. (California ...... ping, New. South. Wales,. Australia),. P. A. Hamil- ton (University of Tasmania , ...
The title compound, C(4)H(8)N(5) (+)·C(2)HO(4) (-), was obtained from the reaction of oxalic acid and 2,4-diamino-6-methyl-1,3,5-triazine. The protonated triazine ring is essentially planar with a maximum deviation of 0.035?(1)?Å, but the hydrogen oxalate anion is less planar, with a maximum deviation of 0.131?(1)?Å for both carbonyl O atoms. In the crystal, the ions are linked by inter-molecular N-H?O, N-H?N, O-H?O and C-H?O hydrogen bonds, forming a three-dimensional network. Weak ?-? [centroid-centroid distance = 3.763?Å] and C-O?? inter-actions [O?centroid = 3.5300?(16)?Å, C-O?centroid = 132.19?(10)°] are also present. PMID:22590348
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A new Constellation-X Centroid Detector Assembly (CDA) was completed and delivered by .... Work had been preceding at GSFC along a parallel path using a concept involving ..... Integral Workshop {The Extreme ... ApL \\&C 39, 465 (1 999) ...
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calibration requirement specifies the alignment of certain instrument pointing frames to an ... The IRS instrument includes peak-up arrays to provide real-time centroids of .... and R.V.F. Lopes, “Parameter interference in distortion and alignment ...
The title mol-ecule, C(16)H(12)Cl(4)N(2)O(2), lies about an inversion center. The symmetry-unique part of the mol-ecule contains an intra-molecular O-H?N hydrogen bond. In the crystal, mol-ecules are arranged in corrugated layers parallel to (-101). Weak ?-? stacking inter-actions, with a centroid-centroid diatance of 3.7923?(13)?Å, are present. PMID:22719492
This patent describes an optical beam position controller in which a video camera captures an image of the beam in its video frames, and conveys those images to a processing board which calculates the centroid coordinates for the image. The image coordinates are used by motor controllers and stepper motors to position the beam in a predetermined alignment. In one embodiment, system noise, used in conjunction with Bernoulli trials, yields higher resolution centroid coordinates.
In the title compound, [Ti(C8H13Si)(C11H21Si2)Cl2], the TiIV atom is bonded to two Cl atoms, one 1,3-bis(trimethylsilyl)cyclopentadienyl (Si2Cp) and one (trimethylsilyl)cyclopentadienyl ring (SiCp). The Si2Cp centroid–titanium distance is 2.0763?(10)?Å and the SiCp centroid–titanium distanc...
In the title compound, C13H10OS, the phenyl rings are inclined to one another by 51.12?(8)°. There is a short C—H?S contact in the molecule.In the crystal, molecules are linked via C—H?O hydrogen bonds forming chains along the a axis. Molecules are also linked by C—H?? and weak ?–? interactions [centroid–centroid distance = 3.9543?(10)?Å].
In the title compound, C(13)H(10)OS, the phenyl rings are inclined to one another by 51.12?(8)°. There is a short C-H?S contact in the molecule.In the crystal, molecules are linked via C-H?O hydrogen bonds forming chains along the a axis. Molecules are also linked by C-H?? and weak ?-? interactions [centroid-centroid distance = 3.9543?(10)?Å]. PMID:23125631
Using metal-oxide-semiconductor (MOS) structures, the shift of centroid (peak) of {gamma}-ray energy distributions emitted from positron annihilation has been measured as a function of incident positron energy. The Doppler centroid shift was found to be consistent with the positron motion in the MOS depletion region. The results are described by a one-dimensional positron diffusion model, and provide information on effective'' positron diffusion length under applied field.
In the title mol-ecule, C(12)H(12)N(4)O(3)S, there is an intra-molecular O-H?N hydrogen bond. The dihedral angle between the benzene and triazine rings is 65.9?(3)°. In the crystal, N-H?S and O-H?N hydrogen bonds link the mol-ecules into chains along [010]. In addition, there are weak ?-? stacking inter-actions between symmetry-related triazine rings with a centroid-centroid distance of 3.560?(3)°. PMID:22969685
In the title molecule, C12H12N4O3S, there is an intramolecular O—H?N hydrogen bond. The dihedral angle between the benzene and triazine rings is 65.9?(3)°. In the crystal, N—H?S and O—H?N hydrogen bonds link the molecules into chains along [010]. In addition, there are weak ?–? stacking interactions between symmetry-related triazine rings with a centroid–centroid distance of 3.560?(3)°.
In the crystal of the title compound, C15H8N4O6, the molecules are organized in layers due to their linkage by weak C—H?N hydrogen bonds. The layers are themselves interconnected by weak C—H?O hydrogen bonds and ?–? interactions [centroid–centroid distances = 3.8690?(15) and 3.9017?(16)?Å]. The dihedral angle between the rings is 31.9?(1)°.
In the crystal of the title compound, C(15)H(8)N(4)O(6), the mol-ecules are organized in layers due to their linkage by weak C-H?N hydrogen bonds. The layers are themselves inter-connected by weak C-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distances = 3.8690?(15) and 3.9017?(16)?Å]. The dihedral angle between the rings is 31.9?(1)°. PMID:21587662
In the title compound, C13H15N2S+I-, the organic cation is almost planar and the N atoms have nearly trigonal-planar geometry. The crystal packing involves N-H...I hydrogen bonds, aromatic p-p stacking [centroid-to-centroid separation 3.631 (2) A; symmetry code: Formula Not Shown ], a C-H...p interaction and a weak S...I interaction [3.7645 (11) A; symmetry code: Formula Not Shown ].
In the title compound, C11H11N3O4, the 3,5-dioxopiperazine ring adopts an envelope conformation, with the N atom connecting to the –CH2COOH group on the flap. In the crystal, molecules are linked by O—H?N hydrogen bonds to produce a linear chain running along the c axis. ?–? stacking is observed between parallel pyridine rings of adjacent molecules, the centroid–centroid distance being 3.834?(2)?Å.
In the title compound, C9H8N2O2S, the sulfamoyl NH2 group is involved in intramolecular N—H?N and intermolecular N—H?O hydrogen bonding. In the crystal, molecules are linked via pairs of N—H?O hydrogen bonds, forming inversion dimers, which are further associated through ?–? stacking interactions between the quinoline benzene rings [centroid–centroid distance = 3.649?(1)?Å] into a one-dimensional polymeric structure extending along the a axis.
In the title compound, C(19)H(17)NO(2), the piperidine ring adopts a chair conformation. The mean planes of the piperidine ring and the anthracene ring system are inclined at a dihedral angle of 38.7?(1)°. In the crystal, adjacent mol-ecules are linked through C-H?? and ?-? [centroid-centroid distance = 3.782?(1)?Å] inter-actions, forming a layer parallel to the bc plane. PMID:23125677
In the title compound, C(19)H(12)BrFO(3)S, the 3-fluoro-phenyl ring makes a dihedral angle of 80.85?(5)° with the mean plane [r.m.s. deviation = 0.009?(2)Å] of the naphtho-furan fragment. In the crystal, mol-ecules are linked by slipped ?-? inter-actions between the furan and the outer benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.756?(3)?Å and slippage of 1.189?(3)?Å]. PMID:23125809
In the title compound, C19H12BrFO3S, the 3-fluorophenyl ring makes a dihedral angle of 80.85?(5)° with the mean plane [r.m.s. deviation = 0.009?(2)Å] of the naphthofuran fragment. In the crystal, molecules are linked by slipped ?–? interactions between the furan and the outer benzene rings of neighbouring molecules [centroid–centroid distance = 3.756?(3)?Å and slippage of 1.189?(3)?Å].
We have successfully synthesized the complex of C60 fullerene with a three-fold symmetrical donor of 2,3,6,7,10,11-hexamethoxytriphenylene (HMT). All spectroscopic data and analyses support the chemical composition of this complex as C60(HMT)2. Individually, each C60 fullerene sphere was found to be surrounded by four HMT molecules in distinctive tetrahedral arrangement. The closest distance from one C60 centroid to the next C60 centroid in the adjacent chain is 13.099 Å.
In the title compound, [Zr(C5H5)(C13H9)2Cl]·C7H8, the ZrIV atom is coordinated by a Cl atom, a cyclopentadienyl (Cp) ligand [Zr–centroid (Cp) = 2.199?(3)?Å] and two fluorenyl ligands (Fl) [Zr–centroid (Fl) = 2.273?(2)?Å and Zr—CH from fluorenyl = 2.355?(2)?Å] in a distorted tetragonal geometry. T...
In the title compound, C17H15N3OS, the phenothiazine ring system is slightly bent, with a dihedral angle of 13.68?(7)° between the benzene rings. The dihedral angle between the oxadiazole ring and the adjacent benzene ring is 7.72?(7)°. In the crystal, a ?–? interaction with a centroid–centroid distance of 3.752?(2)?Å is observed between the benzene rings of neighbouring molecules. PMID:17924710
The title mol-ecule, C(18)H(19)N(3)O(3), lies on a mirror plane that bis-ects the adamantyl group. In the crystal, C-H?O and C-H?N inter-actions lead to supra-molecular chains along [100]. These assemble into layers in the ab plane via ?-? inter-actions [centroid-centroid distance = 3.6548?(7)?Å] between the oxadiazole and benzene rings. PMID:22412666
In the title compound, C(30)H(21)As·CHCl(3), the dihedral angles between the three naphthalene ring systems [r.m.s. deviations = 0.007, 0.009 and 0.020?Å] are 72.54?(4), 88.05?(4) and 83.36?(4)°. In the crystal, the mol-ecules are stacked down the a axis being consolidated by C-H?? and ?-? inter-actions [centroid to centroid distance = 3.7839?(7)?Å]. PMID:21578366
In the title compound, C15H12N4·H2O, the organic molecule displays approximate non-crystallographic twofold symmetry: the dihedral angle between the benzimidazole ring systems is 81.37?(12)°. In the crystal, the components are linked by O—H?N hydrogen bonds, forming chains propagating in [101]. Aromatic ?–? stacking [centroid–centroid separation = 3.595?(2)?Å] helps to consolidate the structure.
In the title compound, C10H9N3, the benzimidazol-2-amine and CH2—C CH units are not coplanar, with a dihedral angle of 60.36° between their mean planes. The crystal structure is stabilized by intermolecular N—H?N hydrogen bonding and ?–? interactions [centroid–centroid distances 3.677?(1) and 3.580?(1)?Å], assembling the molecules into a supramolecular structure with a three-dimensional network.
In the title compound, [Cd2I4(C24H22N4)2], the 1,3-bis[(2-methyl-1H-benzimidazol-1-yl)methyl]benzene ligand bridges two CdI2 units, forming a centrosymmetric dinuclear complex. The CdII atom adopts a distorted tetrahedral coordination geometry. In the crystal, complex molecules are linked into columns parallel to [101] by ?–? stacking interactions, with centroid–centroid distances of 3.558?(2)?Å.
The title compound, C16H11N3O3, crystallizes with two independent molecules which are almost identical to each other in the asymmetric unit. The dihedral angle between the quinoline ring system and the nitrobenzene ring is 51.04?(9)° in one of the molecules and 48.91?(9)° in the other. The crystal packing is stabilized by C—H?O hydrogen bonds and ?–? interactions, with a centroid–centroid distance of 3.6010?(15)?Å.
The measured distance between two stars on a single Spitzer Space Telescope Infrared Array Camera (IRAC) Channel 1 (Ch1) BCD image can be systematically off by as much as one-fifth of a pixel which is 0.24 arcsec on the sky -- if standard intensity-weighted mean centroids are calculated (Mighell, Glaccum, & Hoffman 2008). The square centroid error distribution is well modeled by using a Point Spread Function (PSF) described by a diffraction-limited Airy pattern at 3.6 microns with a 60 percent circular central obscuration. This simple model describes (1) the separability of the centroid errors in the X and Y direction, (2) the size (amplitude) of the maximum centroid errors in X and Y, and (3) the shape (nearly sinusoidal) and (almost) the phase of the separable centroid errors as a function of X and Y pixel phase. The primary physical cause of the square centroid error distribution is that the space-based nearly-diffraction-limited PSF of the IRAC Ch1 PSF was strongly undersampled at the focal plane of the IRAC Ch1 camera by its detector array. This work has been supported by a grant from the National Aeronautics and Space Administration (NASA), NNX10AD45G, which was awarded by the Astrophysics Data Analysis Program (ADAP) of NASA's Science Mission Directorate.
The CT (Computed tomography) method is very effective for making thinner optical waveguide-type tactile sensors. In a previous paper, the authors established the architecture of a CT tactile sensor and evaluated its principle using a series of computer simulations. As a result, the LU decomposition method showed better noise robustness compared to the ART method. On the basis of the simulations, we develop an experimental CT tactile sensor comprised of infrared diodes, phototransistors, an acrylic plate and a black rubber sheet. In the present study, the LU decomposition method is employed and we determine the validity of the algorithm by examining use of a loading machine produced for the CT tactile sensor. In a series of experiments, it is found that absorption of light intensity increases monotonically with increase of applied force and that the present reconstruction method can be applied to not only simply but also multiply connected contact domains. The estimated position of the pressure centroid possesses a rather large error of 4.9 mm, which is 10.8% of a segment of the sensing area.
The seismic activity that affects the Portuguese territory occurs mainly and more frequently offshore, in the south and southwest of Mainland Portugal. The study of the Portuguese seismicity is conditioned by the poor azimuthal coverage, due to the geographic location of Portugal, and by the large sedimentary basin west of the straight of Gibraltar (Cadiz Basin). In this work we focus on the study of regional seismicity in Portugal (mostly offshore earthquakes) using a recently developed package - the KIWI (Kinematic Waveform Inversion) tools. This new technique performs point and finite source inversions at regional distances. The KIWI routine is a multi-step approach composed of 3 steps, finding different source parameters at different steps. At first, we assume a point source approximation. We initially retrieve the focal mechanism of the earthquake (strike, dip, and rake), the seismic scalar moment M0 and the depth. This inversion step is performed in the spectral domain, by fitting amplitude spectra. In the second step, compressive and dilatation quadrants are retrieved, which is carried out in the time domain. Refined latitude and longitude for the centroid, as well as an earthquake origin time, are also given at this time. The final step of the inversion consists of a simplified finite-fault inversion. We assume the eikonal source model, and determine parameters such as the fault plane orientation (discrimination between fault and auxiliary plane), radius (rupture extension), nucleation point coordinates (indicative of directivity effects) and average rupture velocity of the earthquake. This inversion is performed in the frequency domain by fitting amplitude spectra in a wider frequency band (including higher frequencies). This multi-step approach has the advantage of using different inversion methods, seismic phases and range of frequencies to infer specific parameters. In this work we study 17 regional earthquakes occurred in Southwest Iberia between 2007 and 2009 with moderate magnitude (3.3 to 4.4). The small magnitude of these earthquakes prevents their study with the third step of the algorithm. The solutions obtained are evaluated by a quality criteria and compared with other moment tensor solutions. The quality factor is based on the number of stations and on the misfit between the recorded and the synthetic waveforms. Apart from this study another offshore event was analyzed. The earthquake occurred SW of St Vincent Cape on February 12, 2007 with Mw 5.9. In this study the KIWI tools were employed to infer both the point and finite source parameters of this earthquake. The results of the kinematic source inversion step indicate that the 2007 HAP earthquake ruptured a plane trending WNW-ESE, whereas previous studies suggest that the conjugate fault plane (ENE-WSW) is the true rupture plane. The proposed solution also indicates that the earthquake occurred within the SWIM fault-zone. However, the 46° dip is difficult to reconcile with the sub-vertical nature of the SWIM faults.
In this paper, we introduce an adaptive scheme for reconstructing pipe-shaped human organs from the volume data acquired by 3D ultrasonic devices. No other methods but the contour-based scheme was used in the process of reconstructing the volume data into a 3D polygonal surface. In the first step, the algorithm extracts contours from the sampled slices of the volume data using the modified radial gradient method, in which the points are sampled on the boundary of the region of interest by radiating rays and connected through making use of the chain code algorithm. The contours are represented as the context-free grammar, and their parsing trees are traversed during the reconstruction. The generated polygonal surface is refined as the contours are being refined at the casting of the new rays between the existing rays to sample new points and to modify the contours according to these newly derived points. An adaptive scheme is achieved in casting the rays adaptively on the slices. The proposed algorithm is to be applied in reconstructing the pipe-shaped human organs, such as arteries or blood vessels, to a polygonal surface. In this paper, we present an innovative tiling algorithm that reconstructs pipe-shaped human organ from 3D ultrasonic datasets. A set of contours on slices through the ultrasonic datasets is extracted using a modified radial gradient method, and our algorithm tiles these to make a polygonal surface. The tiling is performed by traversing a set of parsing trees which represent the contours in a context-free grammar. This makes our algorithm more efficient than previous algorithms that reconstruct surfaces from a set of contours. The first step of the algorithm is to determine a contour on each slice of the 3D ultrasonic dataset. After removing unwanted artifacts from the slice by applying several noise-removing operators, the centroid pixel of region of interest on the slice is designated. A radial gradient method casts a set of rays from the centroid pixel to the boundary of the slice and computes the intersection points between the rays and the boundary cells of the object so as to determine the contours. The second step uses context-free grammar that represents the contours. Each edge of a contour can be classified into six categories according to its relation with the rays cast from the centroid pixel, and the contour can then be represented by a string in a context-free grammar whose terminal symbols are the six types of the edges. A polygonal surface between two contours is constructed by traversing the parsing trees of the contours and determining the corresponding edges. The third step is to refine the smooth surface constructed in the second step by casting more rays. Additional rays refine the contour by decomposing the edges on the contour and convert leaf node of the parsing tree to the root of a new sub-tree whose leaf nodes denote the newly created edges. Our algorithm was tested on a phantom object and an artery from the neck. Results show that the performance of the algorithm and the quality of the resulting surface are better than those of existing algorithms. We have implemented a navigation facility that allows users to investigate the pipe-shaped human organs interactively. PMID:16487680
A compact optoelectronic sensor unit measures the apparent motion of the Sun across the sky. The data acquired by this chip are processed in an external processor to estimate the relative orientation of the axis of rotation of the Earth. Hence, the combination of this chip and the external processor finds the direction of true North relative to the chip: in other words, the combination acts as a solar compass. If the compass is further combined with a clock, then the combination can be used to establish a threeaxis inertial coordinate system. If, in addition, an auxiliary sensor measures the local vertical direction, then the resulting system can determine the geographic position. This chip and the software used in the processor are based mostly on the same design and operation as those of the unit described in Micro Sun Sensor for Spacecraft (NPO-30867) elsewhere in this issue of NASA Tech Briefs. Like the unit described in that article, this unit includes a small multiple-pinhole camera comprising a micromachined mask containing a rectangular array of microscopic pinholes mounted a short distance in front of an image detector of the active-pixel sensor (APS) type (see figure). Further as in the other unit, the digitized output of the APS in this chip is processed to compute the centroids of the pinhole Sun images on the APS. Then the direction to the Sun, relative to the compass chip, is computed from the positions of the centroids (just like a sundial). In the operation of this chip, one is interested not only in the instantaneous direction to the Sun but also in the apparent path traced out by the direction to the Sun as a result of rotation of the Earth during an observation interval (during which the Sun sensor must remain stationary with respect to the Earth). The apparent path of the Sun across the sky is projected on a sphere. The axis of rotation of the Earth lies at the center of the projected circle on the sphere surface. Hence, true North (not magnetic North), relative to the chip, can be estimated from paths of the Sun images across the APS. In a test, this solar compass has been found to yield a coarse estimate of the North (within tens of degrees) in an observation time of about ten minutes. As expected, the accuracy was found to increase with observation time: after a few hours, the estimated direction of the rotation axis becomes accurate to within a small fraction of a degree.
As part of its earthquake information service, GFZ Potsdam has started to provide seismic moment tensor solutions for significant earthquakes world-wide. The software used to compute the moment tensors is a GFZ-Potsdam in-house development, which uses the framework of the software SeisComP 3 (Hanka et al., 2010). SeisComP 3 (SC3) is a software package for seismological data acquisition, archival, quality control and analysis. SC3 is developed by GFZ Potsdam with significant contributions from its user community. The moment tensor inversion technique uses a combination of several wave types, time windows and frequency bands depending on magnitude and station distance. Wave types include body, surface and mantle waves as well as the so-called 'W-Phase' (Kanamori and Rivera, 2008). The inversion is currently performed in the time domain only. An iterative centroid search can be performed independently both horizontally and in depth. Moment tensors are currently computed in a semi-automatic fashion. This involves inversions that are performed automatically in near-real time, followed by analyst review prior to publication. The automatic results are quite often good enough to be published without further improvements, sometimes in less than 30 minutes from origin time. In those cases where a manual interaction is still required, the automatic inversion usually does a good job at pre-selecting those traces that are the most relevant for the inversion, keeping the work required for the analyst at a minimum. Our published moment tensors are generally in good agreement with those published by the Global Centroid-Moment-Tensor (GCMT) project for earthquakes above a magnitude of about Mw 5. Additionally we provide solutions for smaller earthquakes above about Mw 4 in Europe, which are normally not analyzed by the GCMT project. We find that for earthquakes above Mw 6, the most robust automatic inversions can usually be obtained using the W-Phase time window. The GFZ earthquake bulletin is located at http://geofon.gfz-potsdam.de/eqinfo For more information on the SeisComP 3 software visit http://www.seiscomp3.org
Abstract in portuguese O presente trabalho faz parte do programa GEOSAFRAS, estimativa e safras no Brasil, coordenado pela Companhia Nacional de Abastecimento e do Programa das Nações Unidas para o Desenvolvimento. Uma aplicação muito comum no gerenciamento de safras é o monitoramento de mudanças nos campos de cultivo usando imagens de satélite adquiridas em diferentes datas. Para isto, a compatibilidade espacial entre essas imagens é um requisito básico, mais ainda quando se trata de (more) imagens de diferentes sensores. Nesse artigo é descrita uma metodologia para a semi-automação do processo de correção geométrica com a finalidade de facilitar o ajuste geométrico entre imagens de diferentes sensores. Inicialmente, uma imagem base é manualmente corrigida a partir de dados extraídos de uma carta topográfica digital. Após essa correção, a imagem corrigida é utilizada como elemento base de referência para corrigir as outras imagens (denominadas neste trabalho de imagens de ajuste), as quais são adquiridas em datas diferentes e/ou de diferentes sensores. Depois de corrigida a imagem base todas as imagens (base e de ajuste) são segmentadas e classificadas. Os segmentos classificados como vegetação florestal são escolhidos para compor a malha relacional. As imagens de ajuste são registradas pelo processo imagem-imagem usando os centróides dos segmentos de vegetação florestal. Os segmentos de vegetação florestal presentes na imagem base são confrontados com os segmentos correspondentes nas imagens de ajuste, para buscar correspondências (matching). O processo de matching é realizado através da aplicação de algoritmos genéticos. Ao obter um resultado satisfatório na busca de correspondência, calcula-se os centróides correspondentes aos segmentos detectados, os quais são utilizados como pontos de controle para o processo de registro das imagens. Os resultados mostram que os algoritmos genéticos encontraram a solução ótima na maior parte dos experimentos realizados. Porém, para a imagem LANDSAT 2002 reamostrada a solução encontrada foi sub-ótima, pois um segmento sofreu grandes variações em relação ao mesmo segmento na imagem base. Abstract in english This work is part of the GEOSAFRAS program - estimates and harvests in Brazil - which is coordinated by the National Company of Supply and the United Nations Development Programme. A regular use in the management of harvests is the monitoring of the cultivation fields changes by using satellite images obtained at different dates. For this purpose, the spatial compatibility between these images is a necessary condition, even more when it comes to images from different sens (more) ors. This article describes a methodology for the semi-automation of the geometric rectification process aimed at facilitating the geometric adjustment between images from different sensors. First, a base image is manually rectified from data extracted from a digital topographic map. After such rectification, the correct image is used as a reference element to rectify other images (in this work, called adjustment images), which are acquired at other dates and/or from other sensors. Once the base image is rectified, all images (base and adjustment ones) are segmented and classified. The segments classified as forest vegetation are selected to compose the relational mesh. The adjustment images are registered by the image-image process by means of the forest vegetation segment centroids. The forest vegetation segments in the base image are compared to the corresponding segments in the adjustment images, to find pattern matching. The matching process involves the application of genetic algorithms. After obtaining a positive result regarding the pattern matching, the centroids corresponding to the detected segments are calculated; These centroids are used as control points for the image registry process. The results show that genetic algorithms have found the optimal solution in most experiments. However, regarding the LANDSAT 2002 resampled image, the solution found was sub-optimal because one of the segments showed large variations in relation to the same segment of the base image.
A recently developed centroidal Voronoi tessellation (CVT) sampling method is investigated here to assess its suitability for use in statistical sampling applications. CVT efficiently generates a highly uniform distribution of sample points over arbitrarily shaped M-dimensional parameter spaces. On several 2-D test problems CVT has recently been found to provide exceedingly effective and efficient point distributions for response surface generation. Additionally, for statistical function integration and estimation of response statistics associated with uniformly distributed random-variable inputs (uncorrelated), CVT has been found in initial investigations to provide superior points sets when compared against latin-hypercube and simple-random Monte Carlo methods and Halton and Hammersley quasi-random sequence methods. In this paper, the performance of all these sampling methods and a new variant ('Latinized' CVT) are further compared for non-uniform input distributions. Specifically, given uncorrelated normal inputs in a 2-D test problem, statistical sampling efficiencies are compared for resolving various statistics of response: mean, variance, and exceedence probabilities.
Statistics of the weak lensing of galaxies can be used to constrain cosmology if the galaxy shear can be estimated accurately. In general this requires accurate modelling of unlensed galaxy shapes and the point spread function (PSF). I discuss suboptimal but potentially robust methods for estimating galaxy shear by stacking images such that the stacked image distribution is closely Gaussian by the central limit theorem. The shear can then be determined by radial fitting, requiring only an accurate model of the PSF rather than also needing to model each galaxy accurately. When noise is significant asymmetric errors in the centroid must be corrected, but the method may ultimately be able to give accurate un-biased results when there is a high galaxy density with constant shear. It provides a useful baseline for more optimal methods, and a test-case for estimating biases. I test stacking methods on the simple toy simulations with constant PSF and shear provided by the GREAT08 project, on which most other existin...
We have developed a method for the detection and correction of translational patient motion in dynamic and static myocardial SPECT studies. The method uses a low activity 99mTc point source and is especially designed for multi-detector cameras. The source's centroid coordinates are measured or derived for all projection images in a temporal frame. The coordinate curves fitted to predicted distributions and the projection images shifted to realign measured to fitted values, with sub-pixel accuracy. In dynamic studies, the frame with the best fits serves as reference for all others. The accuracy of this method, measured with cardiac phantom experiments, was found to be +/- 0.37 mm and +/- 0.44 mm in the axial and transaxial dimension, respectively. By comparison, overall motion in 42 patients undergoing 99mTc-teboroxime dynamic cardiac SPECT studies was +/- 1.6 mm and +/- 1.2 mm, respectively (average on 39,272 projection views). Application of the method to phantom experiments, 99mTc-sestamibi and 99mTc-teboroxime human studies visually eliminated artifactual perfusion defects from simulated phantom motion and actual patient motion. PMID:8326397
This paper proposes a hybrid vertex-centered finite volume/finite element method for solution of the two dimensional (2D) incompressible Navier-Stokes equations on unstructured grids. An incremental pressure fractional step method is adopted to handle the velocity-pressure coupling. The velocity and the pressure are collocated at the node of the vertex-centered control volume which is formed by joining the centroid of cells sharing the common vertex. For the temporal integration of the momentum equations, an implicit second-order scheme is utilized to enhance the computational stability and eliminate the time step limit due to the diffusion term. The momentum equations are discretized by the vertex-centered finite volume method (FVM) and the pressure Poisson equation is solved by the Galerkin finite element method (FEM). The momentum interpolation is used to damp out the spurious pressure wiggles. The test case with analytical solutions demonstrates second-order accuracy of the current hybrid scheme in time and space for both velocity and pressure. The classic test cases, the lid-driven cavity flow, the skew cavity flow and the backward-facing step flow, show that numerical results are in good agreement with the published benchmark solutions.
This paper presents a comparison between several methods dedicated to the interpretation of V K-edge X-ray absorption near-edge structure (XANES) features. V K-edge XANES spectra of several V-bearing standard compounds were measured in an effort to evaluate advantages and limits of each method. The standard compounds include natural minerals and synthetic compounds containing vanadium at various oxidation state (from +3 to +5) and in different symmetry (octahedral, tetrahedral, and square pyramidal). Correlations between normalized pre-edge peak area and its centroid position have been identified as the most reliable method for determining quantitative and accurate redox and symmetry information for vanadium. This methodology has been previously developed for the Fe K edge. It is also well adapted for the V K edge and is less influenced by the standard choice than other methods. This methodology was applied on an "environmental sample," i.e., a well-crystallized leached steel slag containing vanadium as traces. Micro-XANES measurements allowed elucidating the microdistribution of vanadium speciation in leached steel slag. The vanadium exhibits an important evolution from the unaltered to the altered phases. Its oxidation state increases from +3 to +5 together with the decrease of its symmetry (from octahedral to tetrahedral). PMID:17429991
We present VLA H I imaging data for a field in the NW of the galaxy cluster Abell 1367 (z = 0.02) in an attempt to probe the effect environment has on the interstellar medium of late-type spiral galaxies. Several galaxies show pronounced tails and asymmetries, and 7 out of 10 show significant, several kpc offsets between the HI centroid and the optical. We compare our results against a sample of optically bright, late-type galaxies (spirals) across the central 1.5 Mpc of the cluster taken from the Arecibo Galaxy Environment Survey (AGES). We calculate the H I deficiency and find that the expected global trend for the H I deficiency of these spirals to increase with projected proximity to the cluster core, seen in clusters like Coma and Virgo, is not observed. We classified the spirals into four evolutionary states, with the galaxies in each state sharing a similar degree of H I deficiency and optical colour. The common characteristics of the spirals in each evolutionary state suggests they have been subject t...
On February 27th 2010, a MW8.8 earthquake struck the coast of south-central Chile, rupturing ?500 km along the subduction interface. Here we estimate the amount of seismically-released afterslip (SRA) and the mechanisms underlying the distribution of aftershocks of this megathrust earthquake. We employ data from a temporary local network to perform regional moment tensor (RMT) inversions. Additionally, we relocate global centroid-moment-tensor (GCMT) solutions, assembling a unified catalog covering the time period from the mainshock to March 2012. We find that most (70%) of the aftershocks with MW > 4 correspond to thrust events occurring on the megathrust plane, in areas of moderate co-seismic slip between 0.15 and 0.7 fraction of the maximum slip (Smax). In particular, a concentration of aftershocks is observed between the main patches of co-seismic slip, where the highest values of SRA are observed (1.7 m). On the other hand, small events, MW seismic slip (>0.85 Smax), likely related to processes in the damage zone surrounding the megathrust plane. Our study provides insight into the mechanics of the seismic afterslip pattern of this large megathrust earthquake and a quantitative approach to the distribution of aftershocks relative to coseismic slip that can be used for similar studies in other tectonic settings.
We use broadband optical imaging and Chandra X-ray data for a sample of 47 cluster central dominant galaxies (CDGs) to investigate the connection between star formation, the intracluster medium (ICM), and the central active galactic nucleus (AGN). By comparing the near-UV color gradients to the X-ray-derived properties on similar spatial scales, we find that a CDG is likely to experience significant star formation when: 1) the X-ray and galaxy centroids are within ~ 20 kpc of each other, 2) the central cooling time of the hot atmosphere is much less than ~ 8x10^8 yr (or has an entropy of less than ~ 30 keV cm^2), and 3) the ratio of jet (cavity) power to X-ray cooling luminosity is approximately less than unity. These conditions, in addition to the high ratio of cooling time to AGN outburst (cavity) age across our sample, are consistent with the idea that cooling and star formation at the centers of cooling flows are regulated by AGN feedback. Our results provide compelling evidence for a cycle of cooling, st...
We present two seismology research projects that had been ported to web technologies and resulted in KML layers, finding in Google Earth a flexible platform capable of substituting specialized graphical tools in performing qualitative comparisons on the data-sets. The KML layer for the European Regional Centroid Moment Tensor Catalog displays the focal mechanism solutions (beach balls) for moderate-magnitude Earthquake from 1997 to present. Two methodologies for beach balls generation and management were tested: simple import of externally- generated gif files and straight KML implementation. The KML tag was exploited to generate resolution-dependent queries and avoid the informative cluttering often seen in printed focal mechanism plots. The Neries Tomographic Earth Model Repository contains data-sets from over 20 models from literature; a hierarchical structure of folders representing each model's set of depths is easily implemented in KML, and immediately results into an intuitive interface for users to freely navigate and compare the hundreds of tomographic plots corresponding to the Model-Depths 2D matrix. The KML code is based on calls to interface with remote scripts and download the data for a certain sublayer only when needed.
We compare high-resolution ultraviolet spectra of the Sun and thirteen solarmass main sequence stars with different rotational periods that serve as proxies for their different ages and magnetic field structures. In this the second paper in the series, we study the dependence of ultraviolet emission-line centroid velocities on stellar rotation period, as rotation rates decrease from that of the Pleiades star HII314 (Prot = 1.47 days) to Alpha Cen A (Prot = 28 days). Our stellar sample of F9 V to G5 V stars consists of six stars observed with the Cosmic Origins 1Guest Observer, NASA/ESA Hubble Space Telescope and User of the Data Archive at the Space Telescope Science Institute. Spectrograph on HST and eight stars observed with the Space Telescope Imaging Spectrograph on HST. We find a systematic trend of increasing redshift with more rapid rotation (decreasing rotation period) that is similar to the increase in line red shift between quiet and plage regions on the Sun. The fastest-rotating solar-mass star in ...
We present two projects in seismology that have been ported to web technologies, which provide results in Keyhole Markup Language (KML) visualization layers. These use the Google Earth geo-browser as the flexible platform that can substitute specialized graphical tools to perform qualitative visual data analyses and comparisons. The Network of Research Infrastructures for European Seismology (NERIES) Tomographic Earth Model Repository contains data sets from over 20 models from the literature. A hierarchical structure of folders that represent the sets of depths for each model is implemented in KML, and this immediately results into an intuitive interface for users to navigate freely and to compare tomographic plots. The KML layer for the European-Mediterranean Regional Centroid-Moment Tensor Catalog displays the focal mechanism solutions or moderate-magnitude Earthquakes from 1997 to the present. Our aim in both projects was to also propose standard representations of scientific data sets. Here, the general semantic approach of an XML framework has an important impact that must be further explored, although we find the KML syntax to more emphasis on aspects of detailed visualization. We have thus used, and propose the use of, Javascript Object Notation (JSON), another semantic notation that stems from the web-development community that provides a compact, general-purpose, data-exchange format.
We present the preliminary results of our astrometric study of stellar motions along the lines of sight of the Magellanic Clouds and the Galactic bulge. We find that we are able to select stars with proper motions as small as 0.03 inch/yr from five years of PSF photometry due to the characteristic nature of the shapes the light curves of HFM stars. This shape arises from the proper motion of the object relative to the initial fixed centroid location where all photometry of the object is performed. By selecting such light curves and performing astrometry on candidate HPM stars we have discovered 154 new high proper motion (HPM) stars in 50{sup {open_square}}{sup o} from amongst the {approx} 55 million of stars observed by the MACHO project in these fields. These objects have proper motions as high as 0.5 inch/yr, luminosities ranging from V {approx} 13 to V {approx} 19, and V-R colours between 0.3 and 1.45.
Nuclear power plant operation often involves very important human decisions, such as actions to be taken after a nuclear accident/transient, or finding the best core reload pattern, a complex combinatorial optimization problem which requires expert knowledge. Due to the complexity involved in the decisions to be taken, computerized systems have been intensely explored in order to aid the operator. Following hardware advances, soft computing has been improved and, nowadays, intelligent technologies, such as genetic algorithms, neural networks and fuzzy systems, are being used to support operator decisions. In this chapter two main problems are explored: transient diagnosis and nuclear core refueling. Here, solutions to such kind of problems, based on genetic algorithms, are described. A genetic algorithm was designed to optimize the nuclear fuel reload of Angra-1 nuclear power plant. Results compared to those obtained by an expert reveal a gain in the burn-up cycle. Two other genetic algorithm approaches were used to optimize real time diagnosis systems. The first one learns partitions in the time series that represents the transients, generating a set of classification centroids. The other one involves the optimization of an adaptive vector quantization neural network. Results are shown and commented. (orig.)
The FastTracKer (FTK) is a dedicated hardware system able to perform online fast and precise track reconstruction of the full events at the Atlas experiment, within an average latency of few dozens of microseconds. It is made of two pipelined processors: the Associative Memory (AM), finding low precision tracks called "roads", and the Track Fitter (TF), refining the track quality with high precision fits. The FTK design [1] that works well at the Large Hadron Collider (LHC) Phase I luminosity requires the best of the available technology for tracking in high occupancy conditions. While the new processor is designed for the most demanding LHC conditions, we want to use already existing prototypes, part of them developed for the SLIM5 collaboration [2], to exercise the FTK functions in the new Atlas environment. During Laboratory tests, the EDRO board (Event Dispatch and Read-Out) receives on a clustering mezzanine (able to calculate the pixel and SCT cluster centroids) "fake" detector raw data on S-links from ...
We have extended the Sub-Scale Dynamics (SSD) closure model for multi-fluid computational cells. Volume exchange between two materials is based on the interface area and a notional interface translation velocity, which is derived from a linearized Riemann solution. We have extended the model to cells with any number of materials, computing pressure-difference-driven volume and energy exchange as the algebraic sum of pairwise interactions. In multiple dimensions, we rely on interface reconstruction to provide interface areas and orientations, and centroids of material polygons. In order to prevent unphysically large or unmanageably small material volumes, we have used a flux-corrected transport (FCT) approach to limit the pressure-driven part of the volume exchange. We describe the implementation of this model in two dimensions in the FLAG hydrodynamics code. We also report on Lagrangian test calculations, comparing them with others made using a mixed-zone closure model due to Tipton, and with corresponding calculations made with only single-material cells. We find that in some cases, the SSD model more accurately predicts the state of material in mixed cells. By comparing the algebraic forms of both models, we identify similar dependencies on state and dynamical variables, and propose explanations for the apparent higher fidelity of the SSD model.
We study large-scale outflows in a sample of 96 star-forming galaxies at 1centroids and maximum extent of the absorption lines, increase with increasing stellar mass with 2-3sigma significance, in agreement with previous results. We study fine structure emission from FeII*, finding several lines of evidence in support of t...
We present the broad-band 0.6-150 keV Suzaku and Swift BAT spectra of the low luminosity Seyfert galaxy, NGC 7213. The time-averaged continuum emission is well fitted by a single powerlaw of photon index Gamma = 1.75 and from consideration of the Fermi flux limit we constrain the high energy cutoff to be 350 keV < E < 25 MeV. Line emission from both near-neutral iron K_alpha at 6.39 keV and highly ionised iron, from Fe_(xxv) and Fe_(xxvi), is strongly detected in the Suzaku spectrum, further confirming the results of previous observations with Chandra and XMM-Newton. We find the centroid energies for the Fe_(xxv) and Fe_(xxvi) emission to be 6.60 keV and 6.95 keV respectively, with the latter appearing to be resolved in the Suzaku spectrum. We show that the Fe_(xxv) and Fe_(xxvi) emission can result from a highly photo-ionised plasma of column density N_(H) ~ 3 x 10^(23) cm^(-2). A Compton reflection component, e.g., originating from an optically-thick accretion disc or a Compton-thick torus, appears ei...
We study the distribution of projected offsets between the cluster X-ray centroid and the brightest cluster galaxy (BCG) for 65 X-ray selected clusters from the Local Cluster Substructure Survey (LoCuSS), with a median redshift of z=0.23. We find a clear correlation between X-ray/BCG projected offset and the logarithmic slope of the cluster gas density profile at 0.04r500 (alpha), implying that more dynamically disturbed clusters have weaker cool cores. Furthermore, there is a close correspondence between the activity of the BCG, in terms of detected H_alpha and radio emission, and the X-ray/BCG offset, with the line emitting galaxies all residing in clusters with X-ray/BCG offsets of 0.02r500, indicating that the total mass may be systematically underestimated in clusters with larger X-ray/BCG offsets. Our results imply a link between cool core strength and cluster dynamical state consistent with the view that cluster mergers can significantly pertu rb cool cores, and set new constraints on models of the ev...
We report observations of Lyman Alpha Blob 1 (LAB1) in the SSA 22 protocluster region (z=3.09) with the integral-field spectrograph SAURON. We increased the signal-to-noise in the spectra by more than a factor three compared to our previous observations. This allows us to probe the structure of the LAB system in detail, examining its structure in the spatial and wavelength dimensions. We find that the emission from the system comes largely from five distinct blobs. Two of the emission regions are associated with Lyman Break Galaxies, while a third appears to be associated with a heavily obscured submillimeter galaxy. The fourth and fifth components do not appear to be associated with any galaxy despite the deep imaging that is available in this field. If we interpret wavelength shifts in the line centroid as velocity structure in the underlying gas, many of these emission systems show evidence of velocity shear. It remains difficult to distinguish between an underlying rotation of the gas and an outflow drive...
In several migratory cells, the microtubule-organizing center (MTOC) is repositioned between the leading edge and nucleus, creating a polarized morphology. Although our understanding of polarization has progressed as a result of various scratch-wound and cell migration studies, variations in culture conditions required for such assays have prevented a unified understanding of the intricacies of MTOC and nucleus positioning that result in cell polarization. Here, we employ a new SMRT (for sparse, monolayer, round, triangular) analysis that uses a universal coordinate system based on cell centroid to examine the pathways regulating MTOC and nuclear positions in cells plated in a variety of conditions. We find that MTOC and nucleus positioning are crucially and independently affected by cell shape and confluence; MTOC off-centering correlates with the polarization of single cells; acto-myosin contractility and microtubule dynamics are required for single-cell polarization; and end binding protein 1 and light intermediate chain 1, but not Par3 and light intermediate chain 2, are required for single-cell polarization and directional cell motility. Using various cellular geometries and conditions, we implement a systematic and reproducible approach to identify regulators of MTOC and nucleus positioning that depend on extracellular guidance cues. PMID:22193958
We have measured the Ag and Pd M{sub 5}VV Auger spectrum in coincidence with Ag and Pd 4d{sub 5/2} photoelectrons for the Ag/Cu(100) and Pd/Cu(100) systems, respectively, as a function of admetal coverage. These systems form surface alloys (i.e. random substitutional alloys in the first atomic layer) for impurity concentrations in the 0.1 monolayer range. For these systems, the centroid of the impurity 4d levels is expected to shift away from the Fermi level by {approx}1 eV [Ruban et al., Journal of Molecular Catalysis. A 115 (1997) 421], an effect that should be easily seen in coincidence core-valence-valence Auger spectra. We find that the impurity Auger spectra of both systems shift in a manner that is consistent with d-band moving away from EF. However, the shift for Pd is considerably smaller than expected, and a shift almost absent for Ag. The disagreement between theory and experiment is most likely caused by the neglect of lattice relaxations in the calculations.
A regionalization procedure is proposed to define affinity regions in Andalusia (Southern Spain) regarding maximum and minimum temperature, and precipitation in order to validate a regional climate model (WRF). In situ observations are not suitable for model validation unless they are somehow upscaled. Therefore, a regionalization methodology was adopted to overcome the representation error that arises from the spatial scale disagreement between site-specific observations and model outputs. An observational daily dataset that comprises 412 rain gauges and 120 maximum and minimum temperature series all over Andalusia was used. The observations covered a 10-year period ranging from 1990 to 1999 with no more than 10% of missing values. The original dataset composed by 716 series for precipitation and 243 for temperature were employed to fill the gaps using a correlation method. Precipitation and temperature have been processed separately using the multi-step regionalization methodology formed by three main stages. Firstly, a S-Mode Principal Component Analysis (PCA) was applied to the correlation matrix obtained from daily values to retain principal modes of variability and discard possible information redundancy. Secondly, rotated normalized loadings were used to classify the stations via an agglomerative Clustering Analysis (CA) method to set the number of regions and the centroids associated to those regions. Finally, using the centroids calculated in the previous step and once the appropriate number of regions was identified, a non-hierarchical k-means algorithm was applied to obtain the definitive climate division of Andalusia. The combination of methods attempts to take advantage of their benefits and eliminate their shortcomings when used individually. This multi-step methodology achieves a noticeable reduction of subjectivity in the regionalization process. Furthermore, it is a methodology only based on the data analyzed to perform the regionalization with no a priori assumptions that could influence the classification of the stations. Several configurations were acceptable, but the simplest one was chosen so that the regionalization obtained was not fragmented in excess. Five regions were identified for precipitation and six for temperature, leading to a coherent distribution of the division according to the local features of climate and the topography of the region. Since the main purpose of the regionalization technique is to set both observations and WRF outputs to a comparable spatial scale, some results of this comparison are also presented in order to highlight the main differences among the regions. Acknowledgements: The Spanish Ministry of Science and Innovation, with additional support from the European Community Funds (FEDER), project CGL2007-61151/CLI, and the Regional Government of Andalusia project P06-RNM-01622, have financed this study.
Clustering is one of the image-processing methods used in non-destructive testing (NDT). As one of the initializing parameters, most clustering algorithms, like fuzzy C means (FCM), Iterative self-organization data analysis (ISODATA), K-means, and their derivatives, require the number of clusters. This paper proposes an algorithm for clustering the pixels in C-scan images without any initializing parameters. In this state-of-the-art method, an image is sampled based on the rosette pattern and according to the pattern characteristics, and extracted samples are clustered and then the number of clusters is determined. The centroids of the classes are computed by means of a method used to calculate the distribution function. Based on different data sets, the results show that the algorithm improves the clustering capability by 92.93% and 91.93% in comparison with FCM and K-means algorithms, respectively. Moreover, when dealing with high-resolution data sets, the efficiency of the algorithm in terms of cluster detection and run time improves considerably.
Using the Newtonian method, the equations of motion are developed for the coupled bending-torsion steady-state response of beams rotating at constant angular velocity in a fixed plane. The resulting equations are valid to first order strain-displacement relationships for a long beam with all other nonlinear terms retained. In addition, the equations are valid for beams with the mass centroidal axis offset (eccentric) from the elastic axis, nonuniform mass and section properties, and variable twist. The solution of these coupled, nonlinear, nonhomogeneous, differential equations is obtained by modifying a Hunter linear second-order transfer-matrix solution procedure to solve the nonlinear differential equations and programming the solution for a desk-top personal computer. The modified transfer-matrix method was verified by comparing the solution for a rotating beam with a geometric, nonlinear, finite-element computer code solution; and for a simple rotating beam problem, the modified method demonstrated a significant advantage over the finite-element solution in accuracy, ease of solution, and actual computer processing time required to effect a solution.
The Snyder's synthetic unit hydrograph method is selected to apply the concept of the fractal dimension by stream order for the practicable rainfall-runoff generation, and fourth types of the Snyder's relation are derived from topographic and observed unit hydrograph data of twenty nine basins. As a result of the analysis of twenty nine basins and the verification of two basins, the Snyder's relation which considers the fractal dimension of the stream length and uses calculated unit hydrograph data shows the best result. The concept of the fractal dimension by stream order is applied to the Snyder's synthetic unit hydrograph method. The topographic factors, used in the Snyder's synthetic unit hydrograph method, which have a property of the stream length like L{sub ma} (mainstream length) and L{sub ca} (length along the mainstream to a point nearest the watershed centroid) were considered. In order to simplify the fractal property of stream length, it is supposed that L{sub ma} has not the fractal dimension and the stream length between L{sub ma} and L{sub ca} ( L{sub ma} - L{sub ca} ) has the fractal dimension of 1.027. >From the utilization of this supposition, a new Snyder's relation which consider the fractal dimension of the stream length occurred by the map scale used was finally suggested. (author). 9 refs., 7 tabs., 4 figs.
The first part of this paper presents a new method for the classification and screening of diatoms in images taken from water samples. The technique can be split into three main stages: segmentation, object feature extraction and classification. The segmentation part consists of two modified thresholding and contour tracing techniques in order to detect the majority of objects present at the sample. From the segmented objects, several features have been extracted and analyzed. For the classification, a diatom training set was considered and the centroids, means and variances of four different classes were found. For the identification process diatoms were classified according with their Mahalanobis distance. The results show the method ability to select at least 80% of usable diatoms from images contaminated with debris. Secondly, full automation of the diatom classification is achieved when multi-focal microscopy is utilized for water sample acquisition. In this case, a necessary preprocessing step is image fusion. A novel wavelet-based fusion method proposed here returns a sharp image that can be directly used for segmentation. For a better understanding of the diatom shape, a 2.5D reconstruction is given.
Traditionally, P wave arrival times have been used to locate regional earthquakes. In contrast, the travel times of surface waves dependent on source excitation and the source parameters and depth must be determined independently. Thus surface wave path delays need to be known before such data can be used for location. These delays can be estimated from previous earthquakes using the cut-and-paste technique, Ambient Seismic Noise tomography, and from 3D models. Taking the Chino Hills event as an example, we show consistency of path corrections for (>10 s) Love and Rayleigh waves to within about 1 s obtained from these methods. We then use these empirically derived delay maps to determine centroid locations of 138 Southern California moderate-sized (3.5 > Mw > 5.7) earthquakes using surface waves alone. It appears that these methods are capable of locating the main zone of rupture within a few (?3) km accuracy relative to Southern California Seismic Network locations with 5 stations that are well distributed in azimuth. We also address the timing accuracy required to resolve non-double-couple source parameters which trades-off with location with less than a km error required for a 10% Compensated Linear Vector Dipole resolution.
We present a practical approach to generate stochastic anisotropic samples with Poisson-disk characteristic over a two-dimensional domain. In contrast to isotropic samples, we understand anisotropic samples as non-overlapping ellipses whose size and density match a given anisotropic metric. Anisotropic noise samples are useful for many visualization and graphics applications. The spot samples can be used as input for texture generation, e.g., line integral convolution (LIC), but can also be used directly for visualization. The definition of the spot samples using a metric tensor makes them especially suitable for the visualization of tensor fields that can be translated into a metric. Our work combines ideas from sampling theory and mesh generation. To generate these samples with the desired properties we construct a first set of non-overlapping ellipses whose distribution closely matches the underlying metric. This set of samples is used as input for a generalized anisotropic Lloyd relaxation to distribute noise samples more evenly. Instead of computing the Voronoi tessellation explicitly, we introduce a discrete approach which combines the Voronoi cell and centroid computation in one step. Our method supports automatic packing of the elliptical samples, resulting in textures similar to those generated by anisotropic reaction-diffusion methods. We use Fourier analysis tools for quality measurement of uniformly distributed samples. The resulting samples have nice sampling properties, for example, they satisfy a blue noise property where low frequencies in the power spectrum are reduced to a minimum. PMID:18192714
When cream puff paste (CPP) was baked after it was kept at 35°C for 3 h, it did not puff up as much as one baked just after preparation of the CPP. The optimum preparative method for CPP with the least deterioration during storage was found by carrying out random centroid optimization regarding 9 factors, such as the ratio of flour, shortening, yolk, egg white and water as ingredients, and the heating time at the first stage, the temperature of the heated mixture of water, shortening, and flour on the addition of the egg solution, and the time and temperature of the incubation of the yolk as preparative conditions. The optimum values of 18.0%, 14.7%, 13.4%, 25.4%, 28.5%, 106.5s, 53.9°C, 46.7 min, and 63.7°C were obtained, respectively. Each value except the time and temperature for incubating the yolk was similar to that in the standard preparative method of CPP, which brought about deterioration during storage. The incubation of the yolk at 63.7°C for 46.7 min caused a decreased in the specific activity of amylase in the yolk from 1.71±0.43 to 0.20±0.17 ?g of maltose/mg of protein but did not affect proteins in the CPP.
Optical microscopes are widely used in biological and medical researches. By using the microscope, we can observe cellular movements including intracellular ions and molecules tagged with fluorescent dyes at a high magnification. However, a freely motile cell easily escapes from a 3D field of view of the typical microscope. Therefore, we propose a novel auto-focusing algorithm and develop a auto-focusing and tracking microscope. XYZ positions of a microscopic stage are feedback controlled to focus and track the cell automatically. A bright-field image is used to estimate a cellular position. XY centroids are used to estimate XY positions of the tracked cell. To estimate Z position, we use a diffraction pattern around the cell membrane. This estimation method is so-called Depth from Diffraction (DFDi). However, this method is not robust for individual differences between cells because the diffraction pattern depends on each cellular shape. Therefore, in this study, we propose a real-time correction of DFDi by using 2D Laplacian of an intracellular area as a goodness of the focus. To evaluate the performance of our developed algorithm and microscope, we auto-focus and track a freely moving paramecium. In this experimental result, the paramecium is auto-focused and kept inside the scope of the microscope during 45s. The evaluated focal error is within 5µm, while a length and a thickness of the paramecium are about 200µm and 50µm, respectively.
HIFS-VNL is reviewing beam wobbler methods for NDCX upgrades in addition to future heavy ion fusion and high energy physics applications. The wobbler system will smooth the ion beam and deposit its energy uniformly about an annular region on the target, consequently mitigating the Rayleigh-Taylor instability. The wobbler's two pairs of RF-driven electrode plates form this annular structure by accelerating different axial slices of the incident beam in appropriate transverse directions. A lattice of quadrupole magnets will then reduce the focal size of each slice. The coupled, nonlinear ODE system describing the centroid and envelope dynamics through the wobbler and final focusing magnets has been derived for an elliptic beam of uniform density in axial cross-section. Multidimensional Newton methods identified electrode and lattice configurations yielding sufficient deflection and convergence. In the case of a 1 kA, 50 MeV Ar^+ incident beam, an Adams-Bashforth-Moulton integrator was used to analyze the dynamics of an infinitesimal slice and estimate design parameters for deflection and transverse compression both with and without self-field effects. Leading-order results have indicated feasible requirements for the wobbler voltages and quadrupole gradients.
Abstract in spanish Estudiamos la microevolución de las poblaciones arcaicas de la costa norte y sus contribuciones morfológicas al Período Formativo. La muestra comprendió 181 individuos pertenecientes a dos colecciones arcaicas de la costa (Morro-Uhle y Morro 1-1/6) y una al formativo (Alto Ramírez) exhumada en el Valle de Azapa. Un total de 29 variables métricas del cráneo fueron analizadas. La variabilidad biológica fue determinada utilizando análisis discriminante y distancias (more) de Mahalanobis (MDS). La estructura de población se analizó utilizando un método basado en teoría genética cuantitativa que predice una relación lineal entre la varianza promedio intragrupal y su distancia hacia el centroide poblacional. Las cuatro muestras analizadas demostraron ser morfológicamente diferentes. La mayor diferencia fue observada entre Plm-7 (Formativo costero) y Alto Ramírez (Formativo valluno), la menor entre Morro-Uhle y Morro 1-1/6, teniendo las otras distancias valores intermedios. El grupo más divergente fue Alto Ramírez y el menos divergente Morro 1-1/6. Un cambio gradual morfológico se observó entre el arcaico (Morro Uhle y Morro 1-1/6) y el Formativo costero (Plm-7) indicando una contribución morfológica (genética) de los pescadores arcaicos a las poblaciones formativas en la costa del norte de Chile, sin excluir, por cierto, flujo génico de otros grupos de la región centro-sur andina Abstract in english The microevolution of the archaic populations from Chile's northern coast and its morphological contribution to Formative period groups was studied. The sample comprised 181 individuals belonging to two Archaic (Morro-Uhle and Morro 1-1/6) and one Formative (Playa Miller-7 [Plm-7]) series of the coast and one sample from the Formative (Alto Ramírez) exhumed at the Azapa Valley. A total of 29 metric variables of the cranium were analyzed. Biological variability was assess (more) ed using discriminant analysis and Mahalanobis' D² distance stadistic (MDS). Population structure was inferred using a method based on quantitative genetic theory that predicts a lineal relationship between average within-group phenotypic variance and group distance to the population centroid. The four samples studied proved to be different from a morphologic point of view. The greatest distance was observed between Plm-7 (coast Formative) and Alto Ramirez (valley Formative), the least between Morro-Uhle and Morro 1-1/6, the remaining distances presenting intermediate values. Regarding the total population, the most divergent group was Alto Ramírez and the least divergent was Morro1-1/6. A gradual biologic change was observed between Archaic (Morro Uhle and Morro 1-1/6) and coastal Formative populations (Plm-7) pointing to a morphological (genetic) contribution of Archaic fishermen to Formative population of Chile's northern coast, without excluding gene flow from other groups of the South Central Andean Area
The molecular and electronic structures, stabilities, bonding features, magnetotropicity and absorption spectra of benzene-trinuclear Cu(I) and Ag(I) trihalide columnar binary stacks with the general formula [c-M(3)(?(2)-X)(3)](n)(C(6)H(6))(m) (M = Cu, Ag; X = halide; n, m ? 2) have been investigated by means of electronic structure calculation methods. The interaction of c-M(3)(?(2)-X)(3) clusters with one and two benzene molecules yields 1:1 and 1:2 binary stacks, while benzene sandwiched 2:1 stacks are formed upon interaction of two c-M(3)(?(2)-X)(3) clusters with one benzene molecule. In all binary stacks the plane of the alternating c-M(3)(?(2)-X)(3) and benzene components adopts an almost parallel orientation. The separation distance between the centroids of the benzene and the proximal c-M(3)(?(2)-X)(3) metallic cluster found in the range 2.97-3.33 Å at the B97D/Def2-TZVP level is indicative of a ?···? stacking interaction mode, for the centroid separation distance is very close to the sum of the van der Waals radii of Cu···C (3.10 Å) and Ag···C (3.44 Å). Energy decomposition analysis (EDA) at the SSB-D/TZP level revealed that the dominant term in the c-M(3)(?(2)-X)(3)···C(6)H(6) interaction arises from dispersion and electrostatic forces while the covalent interactions are predicted to be negligible. On the other hand, charge decomposition analysis (CDA) illustrated very small charge transfer from C(6)H(6) toward the c-M(3)(?(2)-X)(3) clusters, thus reflecting weak ?-base/?-acid interactions which are further corroborated by the respective electrostatic potentials and the fact that the total dipole moment vector points to the center of the metallic ring of the c-M(3)(?(2)-X)(3) cluster. The absorption spectra of all aromatic columnar binary stacks simulated by means of TD-DFT calculations showed strong absorptions in the UV region. The main features of the simulated absorption spectra are thoroughly analyzed, and assignments of the contributing electronic transitions are given. The magnetotropicity of the binary stacks evaluated by the NICS(zz)-scan curves indicated an enhancement of the diatropicity of the inorganic ring upon interaction with the aromatic benzene molecule. Noteworthy is the slight enhancement of the diatropicity of the benzene ring, particularly in the region between the interacting rings, probably due to the superposition (coupling) of the diamagnetic ring currents of the interacting aromatic ring systems. PMID:22229767
Merging clusters of galaxies are unique in their power to directly probe and place limits on the self-interaction cross-section of dark matter. Detailed observations of several merging clusters have shown the intracluster gas to be displaced from the centroids of dark matter and galaxy density by ram pressure, while the latter components are spatially coincident, consistent with collisionless dark matter. This has been used to place upper limits on the dark matter particle self-interaction cross-section of order 1 cm2 g–1. The cluster A520 has been seen as a possible exception. We revisit A520 presenting new Hubble Space Telescope Advanced Camera for Surveys mosaic images and a Magellan image set. We perform a detailed weak-lensing analysis and show that the weak-lensing mass measurements and morphologies of the core galaxy-filled structures are mostly in good agreement with previous works. There is, however, one significant difference: We do not detect the previously claimed "dark core" that contains excess mass with no significant galaxy overdensity at the location of the X-ray plasma. This peak has been suggested to be indicative of a large self-interaction cross-section for dark matter (at least ~5? larger than the upper limit of 0.7 cm2 g–1 determined by observations of the Bullet Cluster). We find no such indication and instead find that the mass distribution of A520, after subtraction of the X-ray plasma mass, is in good agreement with the luminosity distribution of the cluster galaxies. We conclude that A520 shows no evidence to contradict the collisionless dark matter scenario. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with program 12253. This paper includes data gathered with the 6.5 m Magellan Telescopes located at Las Campanas Observatory, Chile.
Responses to recent great earthquakes and ensuing tsunamis in Sumatra, Chile, and Japan, with the resulting loss of life and damage to infrastructure demonstrate that our ability to ascertain the full extent of slip of catastrophic earthquakes and their tsunamigenic potential in the first minutes after the initiation of rupture is problematic. Regional GPS networks such as those in western North America and Japan are complementary to seismic networks by being able to directly measure displacements close to the source during large earthquakes in real time. We report on rapid modeling of two large earthquakes, the 2003 Mw 8.3 Tokachi-oki earthquake 100 km offshore Hokkaido Island using 356 GEONET stations and the 2010 Mw 7.2 El Mayor-Cucapah earthquake in northern Baja California using 95 CRTN stations in southern California about 75 km northwest of the epicenter. Working in a simulated real-time mode, we invert for finite fault slip in a homogeneous elastic half-space using Green's functions obtained from Okada's formulation. We compare two approaches: the first starts with a catalog of pre-defined faults, while the second uses a rapid centroid moment tensor solution to provide an initial estimate of the ruptured fault plane. In either case, we are able to characterize both earthquakes in less than two minutes, reducing the time necessary to obtain finite fault slip and moment magnitude for medium and greater earthquakes compared to traditional methods by an order of magnitude.
A two-layer air pollution model is developed for the case when inter-layer mixing is continuous, but slower than intra-layer vertical mixing. The model was designed to examine the implications of inter-layer tranport for ground-level impacts. The model equations, consisting of two coupled partial differential equations, are solved numerically by the method of characteristics. In the case of first order chemical reactions, the zero and first order moments are computed in order to determine the locations of the centroids of pollutant mass. The model indicated that a pulse of pollutants emitted at ground level can result in bifurcation of a pollutant plume due to the wind directional shear between the two atmospheric layers. The residual concentrations due to the transport between layers can move upwind, downwind or remain stationary with respect to the ground level winds, depending on the speed and orientation of the winds aloft. Several specific cases are described, and, in each case, the behavior of the residual plume would not be expected from the surface layer winds that are normally used to predict the transport and dispersion of pollutants. In addition, it appears that the characteristic exchange rate between the air aloft and the surface mixing layer is large enough that the winds aloft must be considered when describing long range transport or the multi-day impacts of a pollutant.
ExoplanetSat is a proposed three-unit CubeSat designed to detect down to Earth-sized exoplanets in an orbit out to the habitable zone of Sun-like stars via the transit method. To achieve the required photometric precision to make these measurements, the target star must remain within the same fraction of a pixel, which is equivalent to controlling the pointing of the satellite to the arcsecond level. The satellite will use a two-stage control system: coarse control will be performed by a set of reaction wheels, desaturated by magnetic torque coils, and fine control will be performed by a piezoelectric translation stage. Since no satellite of this size has previously demonstrated this high level of pointing precision, a simulation has been developed to prove the feasibility of realizing such a system. The current baseline simulation has demonstrated the ability to hold the target star to within 0.05 pixels or 1.8 arcseconds (with an 85 mm lens and 15 ?m pixels), in the presence of large reaction wheel disturbances as well as external environmental disturbances. This meets the current requirement of holding the target star to 0.14 pixels or 5.0 arcseconds. Other high-risk aspects of the design have been analyzed such as the effect of changing the guide star centroiding error, changing the CMOS sampling frequency, and reaction wheel selection on the slew performance of the satellite. While these results are promising as an initial feasibility analysis, further model improvements and hardware-in-the-loop tests are currently underway.
Crystal structure of 4-(2-methoxycarbonyl-ethyl)-3,5-dimethyl-1H-pyrrole-2-carboxylic acid benzyl ester has been solved by X-ray diffraction. The crystals are triclinic, space group P1¯, with a=5.4435(18) Å, b=12.248(2) Å, c=13.6769(15) Å, ?=70.274(12)°, ?=81.630(15)°, ?=77.60(2)°, Z=2 and R=0.0519. The molecules are strongly linked in dimers by hydrogen bonds, forming rings with R22(10) as the graph descriptor. The pyrrolic ring, slightly distorted from the C2v symmetry, is almost planar. This plane makes an angle of 75.5(1)° with the L.S. plane containing the methoxy-carbonyl group and an angle of 13.6(1)° with the L.S. plane containing the benzyl group. The internal cohesion of the crystal is supported by three C H…? intermolecular interactions, with H…Cg (ring centroid) distances ranging from 3.060 to 3.377 Å. Several calculations were performed for the dimer such as density functional theory with a hybrid functional B3LYP, semi-empirical self-consistent field (AM1 and PM3) and self-consistent field molecular orbital Hartree Fock (SCF-MO HF) method. The latter calculation was repeated for the isolated molecule. In all cases the minimum of the energy is achieved with the substituents assuming a more perpendicular position to the central aromatic ring than is experimentally observed.
A neutron irradiation facility is being developed at the88-Inch Cyclotron at Lawrence Berkeley National Laboratory for thepurposes of measuring neutron reaction cross sections on radioactivetargets and for radiation effects testing. Applications are of benefit tostockpile stewardship, nuclear astrophysics, next generation advancedfuel reactors, and cosmic radiation biology and electronics in space. Thefacility will supply a tunable, quasi-monoenergetic neutron beam in therange of 10-30 MeV or a white neutron source, produced by deuteronbreakup reactions on thin and thick targets, respectively. Because thedeuteron breakup reaction has not been well studied at intermediateincident deuteron energies, above the target Coulomb barrier and below 56MeV, a detailed characterization was necessary of the neutron spectraproduced by thin targets.Neutron time of flight (TOF) methods have beenused to measure the neutron spectra produced on thin targets of low-Z(titanium) and high-Z (tantalum) materials at incident deuteron energiesof 20 MeV and 29 MeV at 0 deg. Breakup neutrons at both energies fromlow-Z targets appear to peak at roughly half of the available kineticenergy, while neutrons from high-Z interactions peak somewhat lower inenergy, owing to the increased proton energy due to breakup within theCoulomb field. Furthermore, neutron spectra appear narrower for high-Ztargets. These centroids are consistent with recent preliminary protonenergy measurements using silicon telescope detectors conducted at LBNL,though there is a notable discrepancy with spectral widths.
We assessed the potential of white-tailed deer (WTD) (Odocoileus virginianus) to be a sentinel for human cases of Lyme disease (LD) in Indiana using location data from a 3-year survey of approximately 3400 hunted deer with associated tick Ixodes scapularis and Borrelia burgdorferi (Bb) data. Data on human LD cases at the county level were obtained from the Indiana Department of Health. All data were assigned to county centroids to match the resolution of the LD data before creating optimized trend surfaces for LD incidence, hunted deer count, Ixodes scapularis and Bb prevalence. To determine whether LD was spatially associated with the areas of high densities of deer, deer with Ixodes scapularis and deer with ticks infected with Bb, we used spatial analysis with distance indices (SADIE). The SADIE analysis found significant spatial association between LD and the distribution of three organismal predictor variables, that is, WTD, Ixodes ticks and Bb. Lyme disease incident rate varied between 0.08 cases per 10?000 habitants (Johnson county) and 5.9 cases per 10?000 habitants (Warren county). In conclusion, WTD can be used as an accurate and cost-effective sentinel for human LD. This method will permit public health workers to identify potentially endemic areas independently of human case reports. PMID:22776734
Background Utilizing highly precise spatial resolutions within disease outbreak detection, such as the patients’ address, is most desirable as this provides the actual residential location of the infected individual(s). However, this level of precision is not always readily available or only available for purchase, and when utilized, increases the risk of exposing protected health information. Aggregating data to less precise scales (e.g., ZIP code or county centroids) may mitigate this risk but at the expense of potentially masking smaller isolated high risk areas. Methods To experimentally examine the effect of spatial data resolution on space-time cluster detection, we extracted administrative medical claims data for 122500 viral lung episodes occurring during 2007–2010 in Tennessee. We generated 10000 spatial datasets with varying cluster location, size and intensity at the address-level. To represent spatial data aggregation (i.e., reduced resolution), we then created 10000 corresponding datasets both at the ZIP code and county level for a total of 30000 datasets. Using the space-time permutation scan statistic and the SaTScan™ cluster software, we evaluated statistical power, sensitivity and positive predictive values of outbreak detection when using exact address locations compared to ZIP code and county level aggregations. Results The power to detect disease outbreaks did not largely diminish when using spatially aggregated data compared to more precise address information. However, aggregations negatively impacted the ability to more accurately determine the exact spatial location of the outbreak, particularly in smaller clusters (disease cluster increases with aggregated data. PMID:20977545
A method is developed for sensitivity analysis and optimization of nodal point locations in connection with vibration reduction. A straightforward derivation of the expression for the derivative of nodal locations is given, and the role of the derivative in assessing design trends is demonstrated. An optimization process is developed in which added lumped masses on the structure are used as design variables to move the node to a preselected location-for example to where a low response amplitude is required or to a point which makes the mode shape nearly orthogonal to the force distribution, thereby minimizing the generalized force. The optimization formulation leads to values for added masses that adjust a nodal location while minimizing the total amount of added mass required to do so. As an example, the node of the second mode of a cantilever box beam model of a rotor blade is relocated to coincide with the centroid of a prescribed force distribution, thereby reducing the generalized force substantially without adding excessive mass. A comparison with an optimization formulation that directly minimizes the generalized force indicates that nodal placement gives essentially a minimum generalized force when the node is appropriately placed.
We present optical identifications and a multi-band catalogue of a sample of 478 X-ray sources in the XMM and Chandra surveys of the central 0.6 deg^2 of the ELAIS-S1 field. The optical/infrared counterpart of each X-ray source was identified using R and IRAC 3.6 um bands. This method was complemented by the precise positions obtained through Chandra observations. Approximately 94% of the counterparts are detected in the R band, while the remaining are blank fields in the optical down to R~24.5, but have a near-infrared counterpart detected by IRAC within 6 arcsec from the XMM centroid. The multi-band catalogue contains photometry in ten photometric bands (B to the MIPS 24 um). We determined redshift and classification for 237 sources (~50% of the sample) brighter than R=24. We classified 47% of the sources with spectroscopic redshift as broad-line active galactic nuclei (BL AGNs) with z=0.1-3.5, while sources without broad-lines are about 46% of the spectroscopic sample and are found up to z=2.6. We identifi...
The Thermal Diffusion Coefficient (TDC) is an input parameter to subchannel code, and it is required to predict local flow conditions in a PWR fuel bundle. TDC influences on the prediction of thermal interchange or mixing of thermal energy between the hot subchannel and interconnected adjacent subchannels. The thermal mixing term in the energy equation is generally represented in terms of a non-dimensional inverse Peclet number or TDC. The parameters associated with thermal mixing can be defined as Eq.(1): TDC =Pe x De/a (1) where: Pe : Inverse Peclet Number (dimensionless) = {epsilon}/ Va De : Equivalent hydraulic diameter, in. a : Lateral flow area between channels per unit length, in{sup 2}/in {epsilon} : Mixing coefficient, in{sup 2}/sec V : Velocity, in/sec TDC is an important factor to evaluate thermal performance. So, flow temperature maps were obtained from the 5x5 rod bundle test section to assess the thermal performance of corresponding fuels. The flow temperatures were measured by thermocouple at the end of heated length and the centroid of subchannel. There are two typical methods to arrange the hot and cold fuel rods as shown in Fig. 1. Configuration Fig. 1(b) is adopted in this work. This paper presents how to determine the TDC and verifies whether all TDC with the effect of mixing vane shape is valid with respect to current design value
The best estimate method (BEM), which shifts an object event towards the centroid of the events within its location uncertainty, was originally proposed to clarify the pattern of seismicity distribution. It was later widely applied to constrain the location and geometry of seismogenic structures. The goal of this study is to improve the efficiency, robustness and effectiveness of the BEM. We perform a series of synthetic experiments by generating a three-dimensional (3D) event dataset representing complex tectonic features and perturbing the presumed hypocenter locations. The synthetic experiments show that appropriate expression for the location uncertainty of the object event and restrictive thresholds of the event selection can significantly improve the collapsing seismicity image. We also demonstrate that the performance of our revised BEM (RBEM) is better than that of the original BEM. We then apply our RBEM to the seismicity catalog for the Taiwan region, collapsing the diffusive catalog hypocenters into sharp images of seismicity. Our RBEM result delineates a clearer low-seismicity zone in central Taiwan and a wider separation between the Wadati-Benioff double seismic layers in northeastern Taiwan than the corresponding features in either the catalog seismicity or the 3D relocation seismicity. Because of the simplicity and efficiency of the RBEM, it is perfectly suited to delineate the location and geometry of active faults in routine operations.
We use spectral-element and adjoint methods to iteratively improve crustal and upper mantle images of Europe and the Mid-Atlantic Ridge. 159 earthquakes with magnitudes from 5 to 6.5 recorded at 338 stations are used in the iterative preconditioned conjugate-gradient inversion. Crustal model EPcrust1.0 combined with mantle model S362ANI comprise the initial 3D model EU00. Before the iterative structure inversion, earthquake source parameters (i.e, Centroid moment tensor and location), are recalculated based on 3D Green's functions and Fréchet derivatives. Since we concentrate on upper mantle structures which involve significant anisotropy in the Asthenosphere, transversely isotropic (frequency-dependent) traveltime sensitivity kernels are employed in the structure inversion. Long-period surface waves and short-period body waves are combined to constrain shallow and deep structures simultaneously. With each subsequent iteration, higher frequency signals are added to the inversion. Statistical assessments of traveltime anomalies and point-spread functions enable us to assess the inverted source and structure models. Current model EU25 reveals many interesting features. For instance, slabs underneath the Hellenic, Vrancea and Calabria arcs, slab detachment underneath the Central Apennines, mantle upwelling associated with the Eifel hotspot, slow wavespeed structures in several back-arc basins, e.g., the Ponnonian basin and Tyrrhenian sea, the sharp transition of the Teisseyre-Tornquist suture zone between central Europe and the East European platform.
We use spectral-element and adjoint methods to iteratively resolve crustal and upper mantle heterogeneity in Europe, using 159 earthquakes, with magnitudes from 5 to 6.5, and data from 338 stations. Crustal model EPcrust1.0 (Molinari& Morelli, 2010) combined with mantle model S362ANI (Kustowski et al. 2008) comprise the initial 3D model M00. Before the iterative inversion, earthquake source parameters (i.e, centroid moment tensor and location), are recalculated using 3D Green's functions and Fréchet derivatives. Since we concentrate on upper mantle structures, involving significant anisotropy in the asthenosphere, transversely isotropic (frequency-dependent) traveltime sensitivity kernels are employed in the inversion. Long-period surface waves (25 s -- 150 s) and short-period body waves (15 s -- 40 s) are combined to constrain shallow and deep structures simultaneously. With each iteration, higher frequency signals are incorporated in the inversion. Statistical assessments of traveltime anomalies and logarithmic waveform differences enable us to validate the inverted sources and structural parameters. Our current model, M15, shows numerous interesting features, for instance, slabs underneath the Hellenic, Vrancea and Calabria arcs, a slab detachment underneath the Central Apennines, mantle upwelling associated with the Eifel hotspot in Northern German, slow wavespeed structures in several back-arc basins, e.g., the Ponnonian basin and the Tyrrhenian sea, and a sharp transition of the Teisseyre-Tornquist suture zone between central Europe and the East European platform.
The microstructure formed by intercellular lipids in the stratum corneum is important for the barrier function of the skin. However, the correlation between lipid composition and microstructure has not yet been clarified. To elucidate the microstructure of intercellular lipids in the stratum corneum, an intercellular lipid model was prepared from ceramide 5 (CER5), cholesterol (CHOL), and palmitic acid (PA), considering the nonuniformity of the lipid components of the stratum corneum. A response surface method incorporating thin-plate spline interpolation (RSM-S) was employed to prepare the CER5/CHOL/PA lipid bilayers. Fluorescence anisotropy of the CER5/CHOL/PA bilayers showed four distinct clusters based on Kohonen's self-organizing maps (SOM). At the centroid formulation of those clusters, the microstructures of CER5/CHOL/PA bilayers were determined using synchrotron X-ray scattering. Three kinds of lamellar structures and two kinds of lateral packing—namely, hexagonal and orthorhombic—were formed. The microstructure of the CER5/CHOL/PA bilayers was likely to be intrinsic to the intercellular lipids in the stratum corneum. In conclusion, the CER5/CHOL/PA bilayers prepared based on RSM-S and SOM were useful as models of the intercellular lipids in the stratum corneum.
PURPOSE: We report on a novel preclinical pancreatic cancer research model that uses bioluminescence imaging (BLI)-guided irradiation of orthotopic xenograft tumors, sparing of surrounding normal tissues, and quantitative, noninvasive longitudinal assessment of treatment response. MATERIALS AND METHODS: Luciferase-expressing MiaPaCa-2 pancreatic carcinoma cells were orthotopically injected in nude mice. BLI was compared to pathologic tumor volume, and photon emission was assessed over time. BLI was correlated to positron emission tomography (PET)/computed tomography (CT) to estimate tumor dimensions. BLI and cone-beam CT (CBCT) were used to compare tumor centroid location and estimate setup error. BLI and CBCT fusion was performed to guide irradiation of tumors using the small animal radiation research platform (SARRP). DNA damage was assessed by ?-H2Ax staining. BLI was used to longitudinally monitor treatment response. RESULTS: Bioluminescence predicted tumor volume (R = 0.8984) and increased linearly as a function of time up to a 10-fold increase in tumor burden. BLI correlated with PET/CT and necropsy specimen in size (P CBCT. BLI-guided irradiated pancreatic tumors stained positively for ?-H2Ax, whereas surrounding normal tissues were spared. Longitudinal assessment of irradiated tumors with BLI revealed significant tumor growth delay of 20 days relative to controls. CONCLUSIONS: We have successfully applied the SARRP to a bioluminescent, orthotopic preclinical pancreas cancer model to noninvasively: 1) allow the identification of tumor burden before therapy, 2) facilitate image-guided focal radiation therapy, and 3) allow normalization of tumor burden and longitudinal assessment of treatment response. PMID:16952647
Environmental pollution is a worldwide problem, and metals are the largest group of contaminants in soil. Microarray toxicogenomic studies with ecologically relevant organisms, such as springtails, supplement traditional ecotoxicological research but are presently rather descriptive. Classifier analysis, a more analytical application of the microarray technique, is able to predict biological classes of unknown samples. We used the uncorrelated shrunken centroidmethod to classify gene expression profiles of the springtail Folsomia candida exposed to soil spiked with six different metals (barium, cadmium, cobalt, chromium, lead, and zinc). We identified a gene set (classifier) of 188 genes that can discriminate between six different metals present in soil, which allowed us to predict the correct classes for samples of an independent test set with an accuracy of 83% (error rate = 0.17). This study shows further that in order to apply classifier analysis to actual contaminated field soil samples, more insight and information is needed on the transcriptional responses of soil organisms to different soil types (properties) and mixtures of contaminants. PMID:20133373
In this paper, we compare the physical and electrical properties of metal oxide-high- ? oxide-silicon (MOHOS)-type devices using Dy2O3 and Dy2TiO5 films as charge-trapping layers. X-ray diffraction and x-ray photoelectron spectroscopy revealed the structural and compositional features of these films after annealing at various temperatures. MOHOS memory devices incorporating the Dy2TiO5 trapping layer that had been annealed at 800°C exhibited a larger memory window of ~2.91 V (measured at a sweep voltage range of ±9 V), higher flatband voltage shift of 2 V (programming voltage at 9 V for 0.1 s), and smaller charge loss of ~10% (measured at room temperature after 104 s), relative to those of the systems that had been subjected to other annealing conditions. This result suggests that the Dy2TiO5 film featuring a higher dielectric constant as well as a thinner silicate layer provides a higher probability of charge carrier trapping and deeper electron trapping levels. In addition, the centroid of trapped charge in the Dy2TiO5 layer was extracted by the constant current stress method and compared with that of the Dy2O3 layer.
We investigate the distortions due to this shear in the microlensing light curves and in the astrometric microlensing centroid shift trajectories. As expected, the light curve deviation increases as the shear increases and the impact parameter decreases. Although the light curve in the presence of a small shear is similar to the simple Paczynski curve with a slightly smaller impact parameter, the detailed difference between the light curve with and without shear reflects the direction and the magnitude of the shear. The centroid shift trajectory also deviates from a simple ellipse in the presence of shear. The distortion of the centroid shift trajectory increases as the impact parameter decreases, and the shape of the trajectory becomes complicated when the impact parameter becomes small enough. The magnitude of the maximum distortion depends on the magnitude and the direction of the shear. For a source trajectory in a given direction, the time of the maximum distortion depends mostly on the impact parameter ...
We investigate the collective response function and the energy-weighted sums (EWS) $m_k$ for isovector mode in hot nuclei. The approach is based on the collisional kinetic theory and takes into consideration the temperature and the relaxation effects. We have evaluated the temperature dependence of the adiabatic, $E_1=\\sqrt{m_1/m_{-1}}$, and scaling, $E_3=\\sqrt{m_3/m_1}$, energy centroids of the isovector giant dipole resonances (IVGDR). The centroid energy $E_3$ is significantly influenced by the Fermi surface distortion effects and, in contrast to the isoscalar mode, shows much weaker variation with temperature. Taking into account a connection between the isovector sound mode and the corresponding surface vibrations we have established the A-dependence of both the IVGDR centroid energy and the EWS enhancement factor which are in a good agreement with experimental data. We have shown that the enhancement factor for the "model independent" sum $m_1$ is only slightly sensitive to the temperature change.
The latitudinal location of the sunspot zones in each hemisphere is determined by calculating the centroid position of sunspot areas for each solar rotation from May 1874 to June 2011. When these centroid positions are plotted and analyzed as functions of time from each sunspot cycle maximum, there appear to be systematic differences in the positions and equatorward drift rates as a function of sunspot cycle amplitude. If, instead, these centroid positions are plotted and analyzed as functions of time from each sunspot cycle minimum, then most of the differences in the positions and equatorward drift rates disappear. The differences that remain disappear entirely if curve fitting is used to determine the starting times (which vary by as much as eight months from the times of minima). The s...
We present an analytical study of the statistical properties of integrated emission and velocity centroids for a slightly compressible turbulent slab model, to retrieve the underlying statistics of three-dimensional density and velocity fluctuations. Under the assumptions that the density and velocity fields are homogeneous and isotropic, we derive the expressions of the antenna temperature for an optically thin spectral line observation, and of its successive moments with respect to the line of sight velocity component, focusing on the zeroth (intensity or integrated emission I) and first (non-normalized velocity centroid C) moments. The ratio of the latter to the former is the normalized centroid C_0, whose expression can be linearized for small density fluctuations. To describe the statistics of I, C and C_0, we derive expansions of their autocorrelation functions in powers of density fluctuations and perform a lowest-order real-space calculation of their scaling behaviour, assuming that the density and ve...
Results of classical Monte Carlo calculations are presented for the radiation produced by ultra-relativistic positrons incident in a direction parallel to the (110) plane of Si in the energy range 30 to 100 MeV. The results all show the characteristic CR(channeling radiation) peak in the energy range 20 keV to 100 keV. Plots of the centroid energies, widths, and total yields of the CR peaks as a function of energy show the power law dependences of ..gamma../sup 1/ /sup 5/, ..gamma../sup 1/ /sup 7/, and ..gamma../sup 2/ /sup 5/ respectively. Except for the centroid energies and power-law dependence is only approximate. Agreement with experimental data is good for the centroid energies and only rough for the widths. Adequate experimental data for verifying the yield dependence on ..gamma.. does not yet exist.
The cross-strip imaging readout employs charge division, and centroiding, of microchannel plate charge signals detected on two orthogonal layers of sense strips to encode event X-Y positions and times. We have developed cross-strip detectors and fully parallel channel position encoding electronics. The front-end amplifiers utilize two 32-channel pre-amplifier ASICs that send signals to a full 64-channel 60 MHz ADC circuit followed by a FPGA event-processing board. Tests with a software Finite Impulse Response filter and centroiding algorithm demonstrate <10 mm resolution with a 32 mm cross-strip anode detector using low microchannel plate gain ({approx}10{sup 6}). The self-triggered event timing accuracy is 750 ps, and the system is capable of encoding photons at >1 MHz in combination with firmware-based FPGA centroiding algorithms.
Determining the precise location of irradiance centroids is a key step for optical triangulation and wavefront sensing based on wavefront slope measurements (as e.g. in Hartmann-Shack aberrometry). Since most aberrometers include some kind of optical relay system to reimage the irradiance distributions provided by the wavefront sampling element onto the irradiance detector, it is esential to ensure that the centroid position and momentum information is preserved along this operation. In optical systems with ABCD difrraction kernels the centroids propagate according to an effective geometrical optics rule. However, the presence of finite apertures partially blocking the incoming beam or non-uniform transmittances unevenly altering its original irradiance distribution may give rise to potentially significant departures from this simple geometrical picture. The potential magnitude of this bias makes it advisable to take proper steps to counteract it in the design of aberrometric setups.
The crystal structure of the title compound, C16H11F3N4O2S, is stabilized in the form of polymeric chains by N—H?O interactions. In the molecular structure, two S(5) ring motifs are formed by intramolecular N—H?N and N—H?O hydrogen bonding and two S(6) rings are present due to N—H?O and C—H?S interactions. ?–? interactions are present with distances of 3.2735?(17), 3.563?(2) and 3.664?(4)/3.688?(3)?Å between the centroids of the heterocyclic rings, between the centroids of the heterocyclic ring and trifluoromethoxy-substituted phenyl ring, and between the centroids of the trifluoromethoxy-substituted phenyl rings, respectively. The trifluoromethoxyphenyl group is disordered over two sites with an occupancy ratio of 0.642?(10):0.358?(10).
The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N-H?O inter-actions. In the mol-ecular structure, two S(5) ring motifs are formed by intra-molecular N-H?N and N-H?O hydrogen bonding and two S(6) rings are present due to N-H?O and C-H?S inter-actions. ?-? inter-actions are present with distances of 3.2735?(17), 3.563?(2) and 3.664?(4)/3.688?(3)?Å between the centroids of the heterocyclic rings, between the centroids of the heterocyclic ring and trifluoro-meth-oxy-substituted phenyl ring, and between the centroids of the trifluoro-meth-oxy-substituted phenyl rings, respectively. The trifluoro-meth-oxy-phenyl group is disordered over two sites with an occupancy ratio of 0.642?(10):0.358?(10). PMID:21588768
We recover the gross space-time characteristics of high-frequency (HF) radiator of the great Sumatra-Andaman islands earthquake of 2004 December 26 (Mw = 9.1-9.3) using the time histories of the power of radiated HF P waves. To determine these time histories we process teleseismic P waves at 36 BB stations, using, in sequence: (1) bandpass filtering (four bands: 0.4-1.2, 1.2-2, 2-3 and 3-4 Hz); (2) squaring wave amplitudes, making `power signals' for each band and (3) stripping the propagation-related distortion (P coda, etc.) from the power signal and thus recovering source time function for HF power. In step (3) we employ an inverse filter constructed from an empirical Green's function, which is estimated as the power signal from an aftershock. For each ray we thus obtain signals with relatively well-defined end and no coda. From these signals we extract: total duration (joint estimate for all four bands) and temporal centroid of signal power for each band. Through linear inversion, the set of duration values for a set of rays delivers estimates of the rupture stopping point and stopping time. Similarly, the set of temporal centroids can be inverted to obtain the position of the space-time centroid of HF energy radiator. The quality of inversion for centroid is acceptable for lower-frequency bands but deteriorates for higher-frequency bands where only a fraction of stations provide useful data. For the source length and duration the following joint estimates were obtained: 1241 +/- 224 km, 550 +/- 10 s. The estimated stopping point position corresponds to the northern extremity of the aftershock zone. Spatial HF radiation centroids are located at distances 350-700 km from the epicentre, in a systematic way: the higher is the frequency, the farther is the centroid from the epicentre. Average rupture propagation velocity is estimated as 2.25 km s-1.
The asymmetric unit of the title compound, C21H18O3, contains two crystallographically independent molecules. The two molecules are linked into cyclic centrosymmetric dimers R 2 2(8) by O—H?O hydrogen bonds. The dihedral angles between the naphthalene ring system and the benzene ring are 87.0?(8) and 84.4?(2)° in the two molecules. The crystal packing is stabilized by O—H?O, C—H?? and ?–? interactions [centroid–centroid distance = 3.664?(11)?Å]. In one molecule, the mesityl ring is disordered over two positions [occupancy ratio 0.690?(3):0.690?(3)].
During the formation of the title compound, C5H7N2 +·C6H2N3O7 ?, a phenolic proton is transferred to the pyridine N atom. In the crystal structure, the ions are linked by intermolecular N—H?O and N—H?(O,O) hydrogen bonds into layers running parallel to (100). These layers are connected by weak ?–? stacking interactions between symmetry-related pyridine and picric benzene rings with a centroid–centroid distance of 3.758?(2)?Å, forming a three-dimensional network.
During the formation of the title compound, C(5)H(7)N(2) (+)·C(6)H(2)N(3)O(7) (-), a phenolic proton is transferred to the pyridine N atom. In the crystal structure, the ions are linked by inter-molecular N-H?O and N-H?(O,O) hydrogen bonds into layers running parallel to (100). These layers are connected by weak ?-? stacking inter-actions between symmetry-related pyridine and picric benzene rings with a centroid-centroid distance of 3.758?(2)?Å, forming a three-dimensional network. PMID:21587648
The objective of this study was to optimize the extraction of different isoflavone forms (glycosidic, malonyl-glycosidic, aglycone and total) from defatted cotyledon soy flour using the simplex-centroid experimental design with four solvents of varying polarity (water, acetone, ethanol and acetonitrile). The obtained extracts were then analysed by high-performance liquid chromatography. The profile of the different soy isoflavones forms varied with different extractions solvents. Varying the solvent or mixture used, the extraction of different isoflavones was optimized using the centroid-simplex mixture design. The special cubic model best fitted to the four solvents and its combination for soy isoflavones extraction. For glycosidic isoflavones extraction, the polar ternary mixture (water,...
An self-aligning biaxial loading apparatus for use in testing the strength of specimens while maintaining a constant specimen centroid during the loading operation. The self-aligning biaxial loading apparatus consists of a load frame and two load assemblies for imparting two independent perpendicular forces upon a test specimen. The constant test specimen centroid is maintained by providing elements for linear motion of the load frame relative to a fixed crosshead, and by alignment and linear motion elements of one load assembly relative to the load frame.
The title compound, C(15)H(9)Cl(2)NO(3), crystallizes as an inversion twin, the ratio of the twin components being 0.43?(13):0.57?(13). The isoindoline group is planar and inclined by 77.63?(3)° to the aromatic ring substituent. The crystal structure is stabilized by aromatic ?-? stacking inter-actions involving the benzene rings of adjacent isoindoline groups, with a centroid-centroid distance of 3.664?(7)?Å and an inter-planar separation of 3.409?Å. PMID:21202365
Near-infrared maps and multicolor photometry of the interacting galaxies IC 694 and NGC 3690 which form Arp 299 (= Markarian 171) are presented. These data reveal for the first time the distribution of nuclei and old red stars in a cataclysmically interacting system. The nuclei are considerably offset from the visual centroids of the galaxies but not from the mass centroids. The near-infrared colors of the most active regions are strongly affected by extinction, emission form hot dust, and bremsstrahlung. Near-infrared emission is also identified with secondary regions of star formation, probably resulting from the galaxies interaction. 24 references.
In the title compound, C(22)H(21)N(3)O(4), the central pyrrolidine ring adopts an envelope conformation with the N atom in the flap position. The indoline ring systems are almost perpendic-ular to the mean plane of the pyrrolidine ring, making dihedral angles of 86.4?(8) and 83.1?(8)°. The acetate group attached to the pyrrolidine ring assumes an extended conformation. In thecrystal, N-H?O hydrogen bonds result in the formation of a C(7) chain running along [100]. The crystal packing also features ?-? inter-actions [centroid-centroid distance = 3.2032?(11)?Å]. PMID:23125696
In the title compound, C22H21N3O4, the central pyrrolidine ring adopts an envelope conformation with the N atom in the flap position. The indoline ring systems are almost perpendicular to the mean plane of the pyrrolidine ring, making dihedral angles of 86.4?(8) and 83.1?(8)°. The acetate group attached to the pyrrolidine ring assumes an extended conformation. In thecrystal, N—H?O hydrogen bonds result in the formation of a C(7) chain running along [100]. The crystal packing also features ?–? interactions [centroid–centroid distance = 3.2032?(11)?Å].
We present a Life-Long Learning from Mistakes (3LM) algorithm for document classification, which could be used in various scenarios such as spam filtering, blog classification, and web resource categorization. We extend the ideas of online clustering and batch-mode centroid-based classification to online learning with negative feedback. The 3LM is a competitive learning algorithm, which avoids over-smoothing, characteristic of the centroid-based classifiers, by using a different class representative, which we call clusterhead. The clusterheads competing for vector-space dominance are drawn toward misclassified documents, eventually bringing the model to a ''balanced state'' for a fixed distribution of documents. Subsequently, the clusterheads oscillate between the misclassified documents, ...
In the asymmetric unit of the title compound, C(14)H(11)N(5)O(6), there are three crystallographically independent mol-ecules with similar conformations but some differences in bond angles. The mol-ecules are slightly twisted with the dihedral angles between the benzene rings being 10.02?(14), 8.41?(15) and 1.40?(14)°. In each mol-ecule, an intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked by weak C-H?O inter-actions into a three-dimensional network. ?-? inter-actions with centroid-centroid distances of 3.5635?(17)-3.8273?(18)?Å are observed. PMID:22969577
In the asymmetric unit of the title compound, C14H11N5O6, there are three crystallographically independent molecules with similar conformations but some differences in bond angles. The molecules are slightly twisted with the dihedral angles between the benzene rings being 10.02?(14), 8.41?(15) and 1.40?(14)°. In each molecule, an intramolecular N—H?O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by weak C—H?O interactions into a three-dimensional network. ?–? interactions with centroid–centroid distances of 3.5635?(17)–3.8273?(18)?Å are observed.
In the title coordination polymer, [HgCl2(C11H9N3)]n, the HgII ion is coordinated by three N atoms from two N-[(E)-pyridin-2-ylmethylidene]pyridin-3-amine (L) ligands and two chloride anions in a distorted trigonal–bipyramidal geometry. The two pyridine rings in L form a dihedral angle of 50.0?(2)°. L ligands bridge adjacent HgCl2 units into polymeric chains propagating in [010]. The crystal packing is further stabilized by weak intermolecular C—H?Cl hydrogen bonds and ?–? interactions between the pyridine rings, with a centroid–centroid separation of 3.529?(9)?Å. PMID:12829268
In the title compound, C(16)H(16)N(4)O(3)·CH(3)OH, the aromatic rings form a dihedral angle of 0.4?(2)°. The nitro group is twisted from the attached benzene ring by 7.5?(2)°. In the crystal, N-H?O and O-H?O hydrogen bonds link alternating hydrazone and methanol mol-ecules into chains in [100]. The crystal packing exhibits ?-? inter-actions between aromatic rings from neighbouring chains [centroid-centroid distances = 3.734?(3) and 3.903?(3)?Å]. PMID:23125634
In the title compound, C(15)H(8)Cl(4)N(2)O, the quinoxaline ring system is almost planar, with a dihedral angle between the benzene and pyrazine rings of 3.1?(2)°. The 2,4-dichloro-phenyl ring is approximately perpendicular to the pyrazine ring, with a dihedral angle of 86.47?(13)° between them. The crystal packing features inter-molecular N-H?O hydrogen bonds and ?-? stacking inter-actions, with centroid-centroid distances in the range 3.699?(3)-4.054?(3)?Å. PMID:22904923
In the title compound, C(22)H(13)ClN(2), the quinoxaline ring system is close to planar [maximum deviation = 0.061?(2)?Å]. The phenyl ring at the 2-position and the phenyl ring of the phenyl-ethynyl substituent make dihedral angles of 49.32?(7) and 11.99?(7) °, respectively, with the quinoxaline mean plane. The two phenyl rings are inclined to one another by 61.27?(9)°. In the crystal, mol-ecules are linked by C-H?? and ?-? inter-actions [centroid-centroid distances = 3.6210?(12) and 3.8091?(12)?Å]. PMID:22719526
In the title compound, C22H13ClN2, the quinoxaline ring system is close to planar [maximum deviation = 0.061?(2)?Å]. The phenyl ring at the 2-position and the phenyl ring of the phenylethynyl substituent make dihedral angles of 49.32?(7) and 11.99?(7) °, respectively, with the quinoxaline mean plane. The two phenyl rings are inclined to one another by 61.27?(9)°. In the crystal, molecules are linked by C—H?? and ?–? interactions [centroid–centroid distances = 3.6210?(12) and 3.8091?(12)?Å]. PMID:15761078
In the title compound, C15H8Cl4N2O, the quinoxaline ring system is almost planar, with a dihedral angle between the benzene and pyrazine rings of 3.1?(2)°. The 2,4-dichlorophenyl ring is approximately perpendicular to the pyrazine ring, with a dihedral angle of 86.47?(13)° between them. The crystal packing features intermolecular N—H?O hydrogen bonds and ?–? stacking interactions, with centroid–centroid distances in the range 3.699?(3)–4.054?(3)?Å.
Two virtually superimposable molecules comprise the asymmetric unit of the title compound, C27H27N3. The range of dihedral angles between the central 1,3,5-triazine ring and the attached benzene rings is 20.88?(14)–31.36?(14)°, and the shape of each molecule is of a flattened bowl. The crystal packing features weak C—H?? bonds and ?–? interactions between triazine and benzene rings [centroid–centroid separations = 3.7696?(17) and 3.7800?(18)?Å] that result in the formation of supramolecular layers in the ac plane. The crystal studied was a non-merohedral twin with a minor twin component of 20.7?(3)%.
In the crystal structure of the title compound, C12H8Cl2O4, molecules crystallize in planes parallel to (-204) with an interplanar distance of 3.288?(2)?Å [centroid–centroid distance = 3.819?(2) and slippage = 1.932?(2)?Å]. The structure features C—H?O interactions involving methoxy and aromatic H atoms and the carbonyl O atoms as well as a C—H?Cl interaction involving an aromatic H atom. In addition there are short interhalogen contacts between adjoining molecules [Cl?Cl = 3.3709?(5)?Å].
The title compound, C16H11ClO2, is a synthetic flavonoid. The fused-ring system is almost planar, with a mean deviation from the least-squares plane of 0.0204 (2) A. The dihedral angle between the chromene group and the chlorophenyl ring is 50.9 (6)degree, due to unfavourable steric interactions with the Cl atom. Aromatic p-p stacking interactions between the fused benzene (p-rich) and pyran (p-deficient) rings are observed, with a centroid-centroid distance of 3.578 A.
In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl-pyridine (ppy) ligands and two Br(-) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene rings being 49.0?(3) and 47.3?(3)°. In the crystal, the complex mol-ecules are stacked in columns along the a axis. In the columns, there are numerous intra- and inter-molecular ?-? inter-actions between the six-membered rings, the shortest ring centroid-centroid distance being 3.774?(6)?Å. PMID:22969465
The crystal structure of the title compound, [Co(CO(3))(C(12)H(8)N(2))(2)]NO(3)·H(2)O, consists of Co(III) complex cations, nitrate anions and uncoordinated water mol-ecules. The Co(III) cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octa-hedral coordination geometry. A three-dimensional supra-molecular structure is formed by O-H?O and C-H?O hydrogen bonding, C-H?? and aromatic ?-? stacking [centroid-centroid distance = 3.995?(1)Å] inter-actions. PMID:21579944
In the title compound, C(23)H(25)BrN(4)O(3)S(2), the benzene rings bridged by the sulfonamide group are tilted relative to each other by 69.7?(1)° and the dihedral angle between the sulfur-bridged pyrimidine and benzene rings is 70.4?(1)°. The mol-ecular conformation is stabilized by a weak intra-molecular ?-? stacking inter-action between the pyrimidine and the 4-methyl benzene rings [centroid-centroid distance = 3.633?(2)?Å]. The piperidine ring adopts a chair conformation. In the crystal, mol-ecules are linked into inversion dimers by pairs of N-H?O hydrogen bonds. PMID:23125637
In the title compound, C(9)H(8)N(2)O(2)S, the sulfamoyl NH(2) group is involved in intra-molecular N-H?N and inter-molecular N-H?O hydrogen bonding. In the crystal, molecules are linked via pairs of N-H?O hydrogen bonds, forming inversion dimers, which are further associated through ?-? stacking inter-actions between the quinoline benzene rings [centroid-centroid distance = 3.649?(1)?Å] into a one-dimensional polymeric structure extending along the a axis. PMID:23125632
In the title compound, C(22)H(23)NO(4)S(2), the dihedral angles between the dimethyl-phenyl ring and the two methyl-phenyl rings are 41.19?(15) and 20.50?(17)°; the dihedral angle between the methyl-phenyl rings is 48.11?(14)°. The C-N-S-C torsion angles are -87.6?(2) and 77.43?(18)°. The only possible directional inter-actions in the crystal are very weak C-H?? inter-actions and very weak ?-? stacking between parallel methyl-phenyl rings [centroid-to-centroid separation = 4.010?(2)?Å and slippage = 1.987?Å]. PMID:23125784
In the mol-ecule of the title compound, C(14)H(10)ClNO(2)S, the dihedral angle between the almost planar benzothia-zole ring system [maximum deviation = 0.005?(2)?Å] and the benzene ring is 1.23?(9)°. The conformation of the mol-ecule is stabilized by an intra-molecular O-H?N hydrogen bond, forming an S(6) ring motif. In the crystal, mol-ecules are linked into layers parallel to the ac plane by C-H?O hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distance = 3.7365?(12)?Å]. PMID:23125675
In the cation of the title salt, C(6)H(7)N(2)O(2) (+)·C(7)H(7)O(3)S(-), the benzene ring makes a dihedral angle of 10.2?(2)° with the nitro group. In the crystal, the cations and anions are linked by weak N-H?O hydrogen bonds, forming a layer parallel to the ac plane. A weak C-H?O inter-action and ?-? inter-actions [centroid-centroid distances of 3.738?(3) and 3.748?(3)?Å] also observed within the layer. PMID:23125819
In the title compound, C22H23NO4S2, the dihedral angles between the dimethylphenyl ring and the two methylphenyl rings are 41.19?(15) and 20.50?(17)°; the dihedral angle between the methylphenyl rings is 48.11?(14)°. The C—N—S—C torsion angles are ?87.6?(2) and 77.43?(18)°. The only possible directional interactions in the crystal are very weak C—H?? interactions and very weak ?–? stacking between parallel methylphenyl rings [centroid-to-centroid separation = 4.010?(2)?Å and slippage = 1.987?Å].
In the title compound, C(17)H(15)IO(3)S, the 4-methyl-phenyl ring makes a dihedral angle of 76.95?(5)° with the mean plane [r.m.s. deviation = 0.019?(2)?Å] of the benzofuran fragment. In the crystal, mol-ecules are linked via pairs of C-H?O hydrogen bonds, forming inversion dimers. These dimers are connected by slipped ?-? inter-actions between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.671?(3)?Å and slippage = 1.049?(3)?Å]. PMID:23125689
In the title compound, C(16)H(12)FIO(2)S, the 3-fluoro-phenyl ring makes a dihedral angle of 76.47?(6)° with the mean plane [r.m.s. deviation = 0.013?(2)?Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H?O hydrogen bonds,forming chains along the b-axis direction, and an I?O contact [3.204?(2)?Å]. The crystal structure also exhibits slipped ?-? inter-actions between the 3-fluoro-phenyl rings of neighbouring mol-ecules [centroid-centroid distance = 3.683?(3)?Å and slippage = 1.708?(3)?Å]. PMID:23125690
The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitro-phenyl-hydrazine and 2-nitro-acetophenone. The mol-ecule displays an E conformation about the C=N double bond and an intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84?(6)°. In the crystal, mol-ecules are linked by C-H?O hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distance = 3.6447?(8)?Å] into a three-dimensional network. PMID:22220090
The cross-strip imaging readout employs charge division, and centroiding, of microchannel plate charge signals detected on two orthogonal layers of sense strips to encode event X-Y positions and times. We have developed cross-strip detectors and fully parallel channel position encoding electronics. The front-end amplifiers utilize two 32-channel pre-amplifier ASICs that send signals to a full 64-channel 60MHz ADC circuit followed by a FPGA event-processing board. Tests with a software Finite Impulse Response filter and centroiding algorithm demonstrate 1MHz in combination with firmware-based FPG...
In the title compound, C(18)H(22)BrN(3)OS, the piperidine ring adopts a chair conformation. The mean plane of the thia-zole ring forms dihedral angles of 23.97?(10) and 75.82?(10)° with the mean planes of its adjacent benzene and piperidine rings, respectively. An intra-molecular N-H?N hydrogen bond generates an S(7) ring motif in the mol-ecule. In the crystal, no significant inter-moelcular hydrogen bonds are observed, but a weak ?-? inter-action with a centroid-centroid distance of 3.8855?(13)?Å occurs. PMID:22719460
In the title compound, C18H22BrN3OS, the piperidine ring adopts a chair conformation. The mean plane of the thiazole ring forms dihedral angles of 23.97?(10) and 75.82?(10)° with the mean planes of its adjacent benzene and piperidine rings, respectively. An intramolecular N—H?N hydrogen bond generates an S(7) ring motif in the molecule. In the crystal, no significant intermoelcular hydrogen bonds are observed, but a weak ?–? interaction with a centroid–centroid distance of 3.8855?(13)?Å occurs. PMID:19815577
Earthquake moment tensors reflecting seven years of global seismic activity (2004-2010) are presented. The results are the product of the global centroid-moment-tensor (GCMT) project, which maintains and extends a catalog of global seismic moment tensors beginning with earthquakes in 1976. Starting with earthquakes in 2004, the GCMT analysis takes advantage of advances in the mapping of propagation characteristics of intermediate-period surface waves, and includes these waves in the moment-tensor inversions. This modification of the CMT algorithm makes possible the globally uniform determination of moment tensors for earthquakes as small as MW=5.0. For the period 2004-2010, 13,017 new centroid-moment tensors are reported.
Speaker change detection involves the identification of the time indices of an audio stream, where the identity of the speaker changes. This paper proposes novel measures for speaker change detection over the centroid model, which divides the feature space into non-overlapping clusters for effective speaker-change comparison. The centroid model is a computationally-efficient variant of the widely-used mixture-distribution based background models for speaker recognition. Experiments on both synthetic and real-world data were performed; the results show that the proposed approach yields promising results compared with the conventional statistical measures.
In the mol-ecule of the title compound, C(16)H(14)O(2), a substituted benzil, the dicarbonyl unit has an s-trans conformation. This conformation is substanti-ated by the O-C-C-O torsion angle of 108.16?(15)°. The dihedral angle between the two aromatic rings is 72.00?(6)°. In the crystal structure, neighbouring mol-ecules are linked together by weak inter-molecular C-H?O hydrogen bonds and weak inter-molecular C-H?? inter-actions. In addition, the crystal structure is further stabilized by inter-molecular ?-? inter-actions with centroid-centroid distances in the range 3.6000?(8)-3.8341?(8)?Å. PMID:21203307
In the molecule of the title compound, C16H14O2, a substituted benzil, the dicarbonyl unit has an s-trans conformation. This conformation is substantiated by the O—C—C—O torsion angle of 108.16?(15)°. The dihedral angle between the two aromatic rings is 72.00?(6)°. In the crystal structure, neighbouring molecules are linked together by weak intermolecular C—H?O hydrogen bonds and weak intermolecular C—H?? interactions. In addition, the crystal structure is further stabilized by intermolecular ?–? interactions with centroid–centroid distances in the range 3.6000?(8)–3.8341?(8)?Å.
In the title complex, [PtBr2(C11H9N)2], the PtII ion has a distorted cis-Br2N2 square-planar coordination geometry defined by two N atoms from two 2-phenylpyridine (ppy) ligands and two Br? anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene rings being 49.0?(3) and 47.3?(3)°. In the crystal, the complex molecules are stacked in columns along the a axis. In the columns, there are numerous intra- and intermolecular ?–? interactions between the six-membered rings, the shortest ring centroid–centroid distance being 3.774?(6)?Å. PMID:10491073
In the title compound, C20H14N4, the dihedral angles between the central benzene ring and the pendant benzimidazole ring systems are 46.60?(15) and 47.89?(16)°. The dihedral angle between the benzimidazole ring systems is 85.62?(12)° and the N atoms lie to the same side of the molecule. In the crystal, molecules are linked by C—H?N interactions and weak aromatic ?–? stacking [shortest centroid–centroid separation = 3.770?(2)?Å] is observed.
In the title compound, [Co(C13H8N3O2)2]·2H2O, the CoII atom has a distorted octahedral environment defined by four N atoms and two O atoms from two 6-(1H-benzimidazol-2-yl)pyridine-2-carboxylate ligands. In the crystal, the complex molecules and uncoordinated water molecules are linked via N—H?O and O—H?O hydrogen bonds, forming a two-dimensional supramolecular structure parallel to (010). ?–? interactions are present between the imidazole, pyridine and benzene rings [centroid–centroid distances = 3.528?(2), 3.592?(2), 3.680?(2) and 3.732?(3)?Å].
In the title compound, C29H24N4O4S3, the two N-tosylbenzimidazolyl unit are connected through a —S—CH2— fragment, the dihedral angle between the benzimidazole rings being 76.09?(5)°. The methylthio group is disordered with respect to exchange of the S and C atoms in a 0.547?(4):0.453?(4) ratio. In the crystal, C—H?O and C—H?? interactions connect adjacent molecules into infinite layers parallel to the ab plane. The crystal packing is further stabilized by a ?–? interaction [centroid–centroid separation = 3.5187?(4)?Å].
In the title complex, [Zn(C10H8N5)Cl]n, the ZnII ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-?N 3)-1,2,3-triazol-1-ide ligands in a slightly distorted tetrahedral geometry. The ZnII ions are bridged by the ligands, forming a helical chain along [001]. C—H?N and C—H?Cl hydrogen bonds and ?–? interactions between the imidazole rings [centroid–centroid distance = 3.4244?(10)?Å] assemble the chains into a three-dimensional supramolecular network.
In the title compound, C16H14N2O3·4H2O, the dihedral angle between the mean planes of the benzimidazole ring system and benzene ring is 2.9?(1)°. The aldehyde group is disordered over two sets of sites with refined occupancies of 0.559?(4) and 0.441?(4). In the crystal, extensive intermolecular O—H?O, O—H?N and N—H?O hydrogen bonds in concert with weak ?–? stacking interactions [centroid–centroid distances = 3.6104?(9), 3.6288?(9) and 3.9167?(10)?Å] create a three-dimensional network.
In the title benzimidazole mononuclear complex, [ZnCl2(C13H11N3)], the ZnII ion is four-coordinated in a distorted tetrahedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57?(1)°. In the crystal, molecules are linked by weak N—H?Cl hydrogen bonds into layers parallel to the bc plane. ?–? interactions with centroid–centroid distances in the range 3.4452?(8)–3.8074?(8)?Å are also observed.
In the title salt, C13H19N2 +·BF4 ?, an ionic liquid, the butyl and ethyl substituents bonded to the N atoms of the imidazole ring [r.m.s. deviation = 0.019?(1)?Å] adopt equatorial positions. The crystal structure exhibits slipped ?–? interactions between the imidazole and benzene rings of neighbouring molecules [centroid–centroid distance = 3.529?(2)?Å]. In the tetrafluoroborate anion, the B and F atoms are disordered over two sets of sites with site-occupancy factors of 0.813?(7) and 0.187?(7).
Ihe title salt, C8H6F3N2 +·NO3 ?, the F atoms of the triflouromethyl group are disordered over two sets of sites in a 0.58?(2):0.42?(2) ratio. In the crystal, N—H?O hydrogen bonds link the cations and anions into chains running parallel to the b axis. There is ?–? stacking between symmetry-related benzene rings with a centroid-centroid distance of 3.949?(3)?Å. The crystal studied was a non-merohedral twin, with a 19% minor component.
In the title molecular salt, C24H24N5 +·C6H2N3O7 ?, the dihedral angle between the benzimidazole rings of the cation is 5.041?(2)°. In the anion, the three nitro groups make dihedral angles of 2.468?(3), 12.795?(3) and 24.958?(4)° with respect to the central ring. In the crystal, weak aromatic ?–? stacking [centroid–centroid distance = 3.599?(15)?Å] consolidates the packing. In addition, an intramolecular N—H?N hydrogen bond is observed.
In the title compound, C(19)H(13)N(5)·3CH(4)O, the 2,6-bis-(2-benzimidazol-yl)pyridine mol-ecule is essentially planar with an r.m.s. deviation for all non-H atoms of 0.185?Å. The crystal structure is stabilized by inter-molecular O-H?O, O-H?N and N-H?O hydrogen bonds and weak ??? stacking inter-actions with centroid-centroid distances of 3.6675?(16) and 3.6891?(15)?Å. The atoms of one of the methanol solvent molecules are disordered over two sites with refined occupancies of 0.606(8) and 0.394(8). PMID:21583836
We report results from extensive new XMM- Newton observations of the ultraluminous X-ray source (ULX) NGC 5408 X-1, one of the few ULXs to show quasi-periodic X-ray variability. We detect quasi-periodic oscillations (QPOs) in each of four new (approximately equal 100 ks each) pointings, expanding the range of frequencies and rms amplitudes observed from the source to 10-40 mHz and 10-45 %, respectively. However, similarly significant variations in the power-law photon spectral index, Gamma, are not observed. We use the results of timing and energy spectral modeling to compare with the timing and spectral correlations seen in stellar-mass systems. We find that the qualitative nature of the timing and energy spectra of NGC 5408 X-1 are very similar to stellar-mass black holes in the steep power-law state exhibiting Type-C QPOs. However, in order for this analogy to quantitatively hold we must only be seeing the so-called saturated portion of the QPO frequency - photon index (or disk flux) relation. Assuming this to be the case, we place a lower limit on the mass of NGC 5408 X-1 of approx greater than 800 Solar Mass. Alternatively, the QPO centroid frequency is largely independent of the spectral parameters, in which case a close analogy of NGC 5408 X-1's mHz QPOs with Type-C QPOs in stellar systems is problematic. Measurement of the source's timing properties over a greater range of spectral parameters (in particular the spectral index) is needed in order to definitively resolve this ambiguity. We searched all the available data for both a broad Fe emission line as well as high frequency QPO analogs (0.1 - 1 Hz), but detected neither. We place upper limits on the equivalent width of any Fe emission feature in the 6 - 7 keY band, and of the amplitude (rms) of a high frequency QPO analog of approx equal 10 eV and approx equal 4%, respectively.
For 865 earthquakes with focal depths exceeding 90 km this paper presents a concise global summary of the distributions of P, T, and B axes of their focal mechanisms with respect to the downdip, along-strike, and normal axies of Wadati-Benioff zones. The focal mechanisms are best double-couple solutions for the centroid moment tensors reported by the Harvard group, with the P, T, and B axes corresponding to the principal axes of the individual moment tensors. We find, as did previous investigators, that events below 300 km have predominantly downdip P axes, with 50% of all P axes of deep focus events lying within 28/sup 0/ of downdip. For events between 90- and 300-km depth there are regional differences, but most regions possess events with nearly downdip P axes or events with nearly downdip T axes. In almost all regions having downdip P or T axes, Bingham statistics show that the greatest concentration of P or T axes lies somewhat below the plane of the Wadati-Benioff zone. For events of all focal depths in nearly all regions, B axes cluster along the strike direction, with 50% occurring within 38/sup 0/ of the strike. From these regional results we define a ''typical'' focal mechanism as one having the B axis within 30/sup 0/ of the along strike and having either the T or P axis within 30/sup 0/ of the downdip. Such a focal mechanism might occur in response to a stress tensor having its greatest or least principal stresses channeled approximately along the the downdip direction of the subducting slab, with the intermediate principal stress lying horizontally within the slab, controlled possibly by slab bending. However, by this criterion, only 29% of the focal mechanisms for deep and intermediate events are typical.
Sensory experience typically depends on the ensemble activity of hundreds or thousands of neurons, but little is known about how populations of neurons faithfully encode behaviorally important sensory information. We examined how precisely speed of movement is encoded in the population activity of magnocellular-projecting parasol retinal ganglion cells (RGCs) in macaque monkey retina. Multi-electrode recordings were used to measure the activity of approximately 100 parasol RGCs simultaneously in isolated retinas stimulated with moving bars. To examine how faithfully the retina signals motion, stimulus speed was estimated directly from recorded RGC responses using an optimized algorithm that resembles models of motion sensing in the brain. RGC population activity encoded speed with a precision of approximately 1%. The elementary motion signal was conveyed in approximately 10 ms, comparable to the interspike interval. Temporal structure in spike trains provided more precise speed estimates than time-varying firing rates. Correlated activity between RGCs had little effect on speed estimates. The spatial dispersion of RGC receptive fields along the axis of motion influenced speed estimates more strongly than along the orthogonal direction, as predicted by a simple model based on RGC response time variability and optimal pooling. on and off cells encoded speed with similar and statistically independent variability. Simulation of downstream speed estimation using populations of speed-tuned units showed that peak (winner take all) readout provided more precise speed estimates than centroid (vector average) readout. These findings reveal how faithfully the retinal population code conveys information about stimulus speed and the consequences for motion sensing in the brain. PMID:15625091
This study assesses the accuracy of prospective phase-gated PET/CT data binning and presents a retrospective data binning method that improves image quality and consistency. Respiratory signals from 17 patients who underwent 4D PET/CT were analysed to evaluate the reproducibility of temporal triggers used for the standard phase-based gating method. Breathing signals were reprocessed to implement retrospective PET data binning. The mean and standard deviation of time lags between automatic triggers provided by the Real-time Position Management (RPM, Varian) gating device and inhalation peaks derived from respiratory curves were computed for each patient. The total number of respiratory cycles available for 4D PET/CT according to the binning mode (prospective versus retrospective) was compared. The maximum standardized uptake value (SUV(max)), biological tumour volume (BTV) and tumour trajectory measures were determined from the PET/CT images of five patients. Compared to retrospective binning (RB), prospective gating approach led to (i) a significant loss in breathing cycles (15%) and (ii) the inconsistency of data binning due to temporal dispersion of triggers (average 396 ms). Consequently, tumour characterization could be impacted. In retrospective mode, SUV(max) was up to 27% higher, where no significant difference appeared in BTV. In addition, prospective mode gave an inconsistent spatial location of the tumour throughout the bins. Improved consistency with breathing patterns and greater motion amplitude of the tumour centroid were observed with retrospective mode. The detection of the tumour motion and trajectory was improved also for small temporal dispersion of triggers. This study shows that the binning mode could have a significant impact on 4D PET images. The consistency of triggers with breathing signals should be checked before clinical use of gated PET/CT images, and our RB method improves 4D PET/CT image quantification. PMID:23135238
Abstract in spanish La descripción de patrones morfológicos del perfil nasal en la población que orienten la toma de decisiones y evaluación terapéutica, y que aseguren el éxito de técnicas como la reconstrucción facial forense, ha sido el objetivo de numerosos estudios basados en el uso de morfometría tradicional. El objetivo de este trabajo es el estudio del perfil nasal en una muestra de población chilena utilizando herramientas de la morfometría geométrica. Se utilizaron las (more) radiografías de una muestra mixta de 156 individuos adultos y 14 hitos en perfil duro y blando. Se realizó el análisis de Procusto, seguido de análisis de componentesprincipales para el estudio exploratorio de la forma, regresión de los componentes de la forma contra el tamaño de centroide para el estudio del efecto alométrico en la forma del perfil nasal, análisis discriminante para la variable sexo y prueba de validación cruzada. Los resultados muestran que de las variables controladas, el tamaño y luego el sexo serían las que más explican la variabilidad observada, sin embargo el peso general de estas variables es bajo, sugiriendo la presencia de otras variables no controladas, y un gran componente de variación entre los individuos. Morfológicamente, se observa que los perfiles de mayor tamaño, de mayor frecuencia en hombres, presentan un punto nasal más descendido y un dorso nasal más curvo, así como un labio más expandido verticalmente. Desde el punto de vista estético, se sugiere dar importancia a la evaluación individual con fines terapéuticos. En antropología forense, se sugiere la prudencia en las conclusiones basadas en técnicas de reconstrucción debido a la falta de patrones morfológicos que orienten la técnica de manera certera. Abstract in english The search of morphological patterns of nasal profile using traditional morphometrics has been the goal of several studies aiming to orient therapeutical planning and forensic techniques such as facial reconstruction. The present study aims to find and describe such patterns with geometric morphometric tools in a sample of Chilean population with geometric morphometric tools. We used the lateral X-rays of 156 individuals (men and women) and 14 landmarks in bone and soft t (more) issues. Procrustes analysis was performed followed by principal component analysis to assess general shape variation, regression of shape components against centroid size to study to allometric effect and discriminant analysis by sex with cross-validation test. Our results show the lack of shape patterns, and that the size, followed by sex, explains within a limited scope the shape changes which suggests the presence of uncontrolled variables and a high effect of inter-individual variation. In general terms bigger profiles, more frequent in men, show a lower Pronasal point, a more prominent nasal dorsum with a thicker layer of soft tissue, and a vertically expanded upper lip. We suggest the reassessment of the importance of individual aesthetic evaluation for clinical purposes, and recommend caution in concluding results based on forensic reconstruction techniques.
In the plasma-wakefield experiment at SLAC, known as E157, an ultra-relativistic electron beam is used to both excite and witness a plasma wave for advanced accelerator applications. If the beam is tilted, then it will undergo transverse oscillations inside of the plasma. These oscillations can grow exponentially via an instability know as the electron hose instability. The linear theory of electron-hose instability in a uniform ion column predicts that for the parameters of the E157 experiment (beam charge, bunch length, and plasma density) a growth of the centroid offset should occur. Analysis of the E157 data has provided four critical results. The first was that the incoming beam did have a tilt. The tilt was much smaller than the radius and was measured to be 5.3 {micro}m/{delta}{sub z} at the entrance of the plasma (IP1.) The second was the beam centroid oscillates in the ion channel at half the frequency of the beam radius (betatron beam oscillations), and these oscillations can be predicted by the envelope equation. Third, up to the maximum operating plasma density of E157 ({approx}2 x 10{sup 14} cm{sup -3}), no growth of the centroid offset was measured. Finally, time-resolved data of the beam shows that up to this density, no significant growth of the tail of the beam (up to 8ps from the centroid) occurred even though the beam had an initial tilt.
[1] The median Doppler shift of radar echoes is analyzed in measurements by ENVISAT's Advanced Synthetic Aperture Radar (ASAR) over the ocean. This Doppler centroid differs from a predicted signal based on the predicted motion of the satellite and Earth. This anomaly, converted to a surface Doppler ...
A water molecule forms a hydrogen bond with the aromatic ?-electron system within the crystal structure of H–Phe–Leu–NH2 hydrochloride monosolvate. This water molecule located above the phenyl ring plane, 3.119 Å from the centroid of the ring. Ab initio energy calculations revealed the stabilization energy of the phenyl ring–water hydrogen bond to be 3.26 kcal/mol.
In the title compound, C(16)H(13)FO(4), the aromatic rings enclose an angle of 73.68?(6)°. In the crystal, C-H?O and C-H?F contacts connect the mol-ecules into a three-dimensional network. The shortest inter-centroid distance between two aromatic ?-systems is 3.6679?(7)?Å and is apparent between the fluorinated phenyl groups. PMID:22347113
All cockpits have instrumentation measured in feet, statue or nautical miles per ...... If we then fuel the aircraft with 40,000 gal of jet fuel weighing 6.25 lb/gal in fuel tanks that have a centroid (center of the volume or mass) location of 40 ft aft of ...
Field recordings of echolocation signals produced by Heaviside's dolphins (Cephalorhynchus heavisidii) were made off the coast of South Africa using a hydrophone array system. The system consisted of three hydrophones and an A-tag (miniature stereo acoustic data-logger). The mean centroid frequency ...
Aug 23, 2012 ... correcting for spatial offsets as a function of wavelength. • correcting ... change the position of the line centroid on the detector. Since an .... image produces a spectrum from that spatial pixel in the right-hand panel. Initially ..... A sit-and-stare observation with repeated, single exposures at a fixed slit position.
Feb 1, 2011 ... the target star to detect by adaptive optics (AO), speckle imaging, or centroid motion. ..... analysis, 69% are smaller than Neptune (Rp= 3.8 R!). ..... guide to content of the tables, a simple model was developed to provide a ...
In the title compound, C9H11N3O2S, intramolecular O—H?O and N—H?N hydrogen bonds contribute to the planarity of the molecular skeleton. Intermolecular N—H?O hydrogen bonds link the molecules into zigzag chains along the b axis; these molecules are futher paired by ?–? interactions [centroid–ce...
The title compound, C16H13N, is essentially planar [maximum deviation from the least-squares plane = 0.081?(3)?Å], with a dihedral angle of 1.65?(13)° between the planes of the indole and benzene rings. In the crystal, there are no significant intermolecular ?–? interactions [minimum ring centroid...
The asymmetric unit of the title compound, C18H18Cl2N2O2, contains one half of an independent molecule, the other half being generated via a centre of inversion at the molecular centroid. In the crystal structure, molecular chains are formed through non-classical C—H? O hydrogen bonds between an ...
the data is distributed across the processors and a random choice of the k centroids are also ... clustering are as follows: • Compute weighted adjacency matrix W ? Rd×d where Wij. = ..... [2] N. M. Ball and R. J. Brunner. Data Mining and ...
As SIM Interdisciplinary Scientist, we pro- pose to study the formation ..... will lead to the restoration of the nulling mode. 6 ..... dio quasars with the dual goals of anchoring the SIM frame ..... these are diffraction and beam walk due to centroiding ...
In the title compound, C9H5N3, the quinoxaline ring is essentially planar, with a maximum deviation of 0.012?(1)?Å. Short intermolecular distances between the centroids of the 2,3-dihydropyrazine and benzene rings [3.6490?(5)?Å] indicate the existence of ??? interactions. In the crystal packing, ...
In the molecule of the title compound, C12H12N2O, the quinoxaline ring is planar with an r.m.s. deviation of 0.007?(15)?Å. The dihedral angle between the quinoxaline and propenyl planes is 82.1?(2)°. The crystal packing is stabilized by offset ?–? stacking between the quinoxaline rings [centroid–ce...
The asymmetric unit of the title compound, 2C16H14N4·C8H6N2, consits of one molecule of N,N?-bis(pyridin-2-yl)benzene-1,4-diamine (PDAB) and one half-molecule of quinoxaline (QX) that is located around an inversion centre and disordered over two overlapping positions. The PDAB molecule adopts a non-planar conformation with an E configuration at the two partially double exo C N bonds of the 2-pyridylamine units. In the crystal, these self-complementary units are N—H?N hydrogen bonded via a cyclic R 2 2(8) motif, creating tapes of PDAB molecules extending along [010]. Inversion-related tapes are arranged into pairs through ?–? stacking interactions between the benzene rings [centroid–centroid distance = 3.818?(1)?Å] and the two symmetry-independent pyridine groups [centroid–centroid distance = 3.760?(1)?Å]. The QX molecules are enclosed in a cavity formed between six PDAB tapes.
Four-wave mixing and walk-off between two optical beams are! investigated For focusing Kerr media. It is shown that four-wave mixing reinforces the self-focusing of mutually trapped waves by lowering their power threshold for collapse, only when their phase mismatch is small. On the contrary, walk-off inhibits the collapse by detrapping the beams, whose partial centroids experience nonlinear oscillations.
In the crystal structure of the title substituted ferrocene complex, [Fe(C19H18O2P)2], the FeII atom lies on a twofold rotation axis, giving an eclipsed cyclopentadienyl conformation with a ring centroid separation of 3.292?(7)?Å and an Fe—C bond-length range of 2.0239?(15)–2.0521?(15)?Å. In the l...
The 4-chloro- [C(14)H(11)ClN(2)O(2), (I)], 4-bromo- [C(14)H(10)BrN(2)O(2), (II)] and 4-diethylamino- [C(18)H(21)N(3)O(2), (III)] derivatives of benzylidene-4-hydroxybenzohydrazide, all crystallize in the same space group (P2(1)/c), (I) and (II) also being isomorphous. In all three compounds, the conformation about the C=N bond is E. The molecules of (I) and (II) are relatively planar, with dihedral angles between the two benzene rings of 5.75?(12) and 9.81?(17)°, respectively. In (III), however, the same angle is 77.27?(9)°. In the crystal structures of (I) and (II), two-dimensional slab-like networks extending in the a and c directions are formed via N-H...O and O-H...O hydrogen bonds. The molecules stack head-to-tail via ?-? interactions involving the aromatic rings [centroid-centroid distance = 3.7622?(14)?Å in (I) and 3.8021?(19)?Å in (II)]. In (III), undulating two-dimensional networks extending in the b and c directions are formed via N-H...O and O-H...O hydrogen bonds. The molecules stack head-to-head via ?-? interactions involving inversion-related benzene rings [centroid-centroid distances = 3.6977?(12) and 3.8368?(11)?Å]. PMID:23007544
A technique is described in which the centroid of induced charge on cathode strips in a proportional chamber can be determined with reduced differential and integral nonlinearity, without increasing the number of readout channels. It is based on capacitive charge division from intermediate cathode strips to adjacent readout strips, and may be applied to a variety of position readout principles.
ship float on the Sun? Reducing the fuel .... Agreed, there is a point that has zero gravity, but it's not quite at the mass centroid ... My son Bradley asked how far away from the earth would one have to travel to no longer be effected by gravity?
In the crystal structure of the title compound, C12H18S5, no significant intermolecular ?–? interactions are found. Weak intermolecular C—S?? [S?centroid = 3.787?(1)?Å] interactions and van der Waals forces may be effective in the stabilization of the structure.
The optical path length of the l i g h t from S t o P2 to 0 is denoted by L2 and is the distanc ...... denotes the convolution integral 'tuch as) are the p2 and a respectively;. P' aPl p2. L. L and ... intersecting a t the centroid of the free end. Material fcr ...
science community that these data systems are important, integral components ..... must be a distributed system in any event, because that is the only feasible long-term path to ..... AMPTE/CCE Science Data Center at JHU/APL ..... particular, the level referred to as Level 2 (below) represents the centroid of a broad range of ...
integral skin and as a result have little in-plane torsional resistance capability. In 1964,. Dr. .... paths. -. Less structural dt, pth. In use on two n_aior .- t,,,_cc proorams,. 'lilot'-l)clta and ..... centroid of the transformed s e c ti on. Define the following non-dimensional parameters. ...... APl)licatiorlof the measured and. T ( skinned). = ...
and modeling will play an integral role in the Senti- nels mission .... ble, within to 2 scattering mean free paths (i.e., at ...... Laboratory (APL) and the Jet Propulsion Labora- ...... angular rate and position relative to the solar centroid using the ...
could not be used because of the flight path angle requirement, and the available launch .... deposition (e.g., ion chamber) modes, differential or integral energy window modes, or ...... F5-06 Kohl, J.W., "Solar Proton Monitoring," APL Tech. Digest, 8^ 2-9, ..... observer is located east or west with respect to''the centroid of ' the ...
May 17, 1975 ... of the propagation path over the North Pole (i.e., there is little or no possi- ..... centroid and other calibration quantities, but also to measure and store ...... (laser ). APL doppler,. AMS secor raw APL doppler. ANNA 1 doppler .... proposed by Uotila (1960), that sums contributions to the integrals from the whole ...
n ,l(,_mrlcA()ro_apl;_irf,veh1(:lecapab1(_of mls_1(}n_to Mar,_,Saturn, ,tt_(l. Uranu,_. A .,in.(i1_, ex1. ..... _xitveloclt5 (_v()rthe range of entry path ar_lle. ...... 2 (1.32). Multiplyingthisvalueof"CDISTby the integral f dynamicpressuregivesa ...... Surface areas, centroids, enclosed volumes and unit inertiasare given in. Table VI-2 ...
Jan 31, 1999 ... path. Heat pipes are a viable low mass option using a closed two-phase liquid- flow ..... The JSC APL site is also given in Appendix. K. ...... integral cascade curves, i.e. the mean energy deposited .... Fitting these centroids ...
Jan 1, 2012 ... as well as the APL MESSENGER-based AAHFS; port AADS to a ...... on average, the second-level cells have dimensions less than the local mean free path. ...... the integral depends on the reference altitude density and the scale height ..... the flight sequence so that it would be centered on the centroid of ...
Other vehicles are serviced, an integral number of times per commutation cycle. ...... As the radar frequency increases, the path attenuation increases and this ...... Stations at the face-centroids of a tetrahedron can be regarded as located at the ...... 1Newton, R. R., Damping of a Gravitationally Stabilized Satellite, APL Report ...
SPACE and INFORMATION SYSTEMS DIVISION. UA. aPL,. CD. 3. 5. -P. C. O ...... 10~° torr the mean free path of the remaining gases is huge compared to the ...... coordinate envelope occupied by its centroid, and a description of its mass ...... in a sealed enclosure, integral with the outer structure of the engine ...
... in ACTVEH and the integration of model dynamics equations (e.g., actuator motion) in the other. 2-2 ..... velocity contribution due to wind speed and direction, flight path angle,. Mach number, dynamic ...... x-accelerometer: ]L ~ ^apl'ap2' ap3' ...... Defines the vector R from the centroid of the probability ellipse to the intercept ...
mathematical model is capable of evaluating the time dependent integrals ..... Observed photos of some waterspouts indicate spiral paths intercepting ...... gravity is 0.2 ft in front of the centroid of the volume and 0. ..... JPL 6 DOF aPL 6DOF. 30 ...
path runs above the. 74 ° magnetic line for a third of its length, namely from ...... 2( a). The positions marked by a + are the average positions of the centroids of the ...... Six. Ge;ger-Muller detectors cover four integral energy channels for electrons ..... in. 1967-68,. APL. Preprint,. October,. 1970. (Submitted to J. Geophys. Res.) ...
Jan 11, 1982 ... Cloud 4, whose echo centroid traveled at 18.8 m ..... and can be removed from inside the area integral. The updraft ..... APL/JHU CP 056, Johns Hopkins .... path. This procedure was de- signed to concentrate the analysis on ...
Effective Stress at Root Element Centroids. Effective Strain ..... and/or different paths travelled through ..... A3 = Ap3 (cos 4, I - sin 4, K) + As3 J where. 2 sin. _ cos. 0. Ap3. = Apl sin .... integral equation may be applied to extended plane surfaces.
Jan 4, 1970 ... Path of the low voltage cable along the spacecraft and the power conditioning ...... integral to the radiator. Figure. 7-8, layout drawing, and Figure. 7-9, ...... path length between the centroids of the two nodes. The conduction term, ..... so the required area is determined by proportionality; qtp5. ApL. - q(5). ApR ...
position is servoed to center the centroid ...... path or the total energy expended. In some cases, the agent may be unable .... general across apl)lica.tion doma.ins ? .... which TCX built on for a project which did not require TCA's integral support ...
Mar 1, 1981 ... (reference level) from which the integral is begun. By using ...... results in the centroid of the distribution of returned power being shifted away from ...... kins University Report JHUV/APL SIR8OU-018 (NASA CR-156868). Gordon, A.L. .... path length by microwave radiometry, Proceedings IEEE 58, 272-273.
ALSCAT. AM-1. AMC. ANSI. AOCI. AOL. AOP. AOS/LOS. APL. ARGOS. ARI. ASCII. ASI. ASR ...... integral coefficients over the Hermitian pol- ynomials y,j. Matrix elements. (defined in Vol. 26). .... path radiance at flight altitude. The radiance of the atmosphere. Apparent radiance response ..... at a spacecraft, or the centroid ...
May 17, 1975 ... of the propagation path over the North Pole (i.e., there is little or no possi- ..... centroid and other calibration quantities, but also to measure and store ...... (laser ). APL doppler,. AMS secor raw APL doppler. ANNA 1 doppler .... function* S|ijj) is the inverse kernel derived by Molodensky, and the integrals are ...
Nov 2, 1970 ... The AM/FPQ-~ radar is a centroid tracker, and any difference in the pulsewidth used for cal&ratisn and ...... refined ray tracing integral program, The diacrepaneies have been found to be highly aipiflca$iit at ..... electrons along the ray path linlcing the vehicle and tracking station. ...... APL Howard County, Md.
The results of laboratory and telescopic measurements of the position sensitivity of a visible MAMA detector utilizing a 'coarse-fine' array are presented. The photometric accuracy of this detector was determined under point source illumination. It was found that computed centroid positions are accurate across the entire array to within 0.04 pixels.
An extensive set of interlaboratory root bioassay data was unified using centroids of individual tests as scalers. It is shown that the dose response obeys a first order differential equation with the constant of the equation related to the sensitivity of the dose response relati...
New statistical measures of symmetry breaking are used to evaluate the total seniority four admixtures in the low-lying O+ states of even-mass tin and lead nuclei. This approach is based on the centroid energies and partial widths of fixed total seniority and parity spectral distributions. Some seni...
In the title molecular salt, C7H14N5O+·Cl? (the HCl salt of the oxo derivative of the triazine herbicide simazine), the cation and anion are linked by N—H?Cl hydrogen bonds. The chloride ion is also involved in a close electrostatic interaction with an inversion-related triazine ring [Cl?centroid d...
digital representations which in turn can be used to produce a reproduction of the .... into a binary sequence (the encoder) together with a mapping of the binary ..... group. The code word for that group is then replaced by the centroid of all training .... software to ensure synchronization and possibly to meet a fixed rate ...
In the title compound, [Cr(C15H10O2)(CO)3], the Cr(CO)3 unit exhibits a three-legged piano-stool conformation. The chromium metal centre is coordinated by the phenyl ring of the flavone ligand [Cr-(phenyl centroid) distance = 1.709 (1) Å]. The ligand is approximately planar, the dihedral angles betw...
Longitudinal beam compression is essential to produce the requisite peak power for driving ICF targets; it could also produce the proper pulse shapes. Realistic effects of quadrupole focusing and displaced beam centroid in the presence of space charge are being studied with the help of the 3D ARGUS particle-in-cell (PIC) code. We discuss the results and code development for these studies.
We propose, in this letter, a new type of image denoising filter using a data analysis technique. We deal with pixels as data and extract the most dominant cluster from pixels in the filtering window. We output the centroid of the extracted cluster. We demonstrate that this graph-spectral filter can effectively reduce a mixture of Gaussian and random impulsive noise.
The asymmetric unit of the title compound, C8H9N3O2S·0.5H2O, contains two thiosemicarbazide molecules with the short distance of 3.521?(3)?Å between the centroids of the benzene rings, and one water molecule. In the two independent molecules, the benzene rings and the thiosemicarbazone fragments...
Existing errors in the structure and kinematic parameters of multi-legged walking robots, the motion trajectory of robot will diverge from the ideal sports requirements in movement. Since the existing error compensation is usually used for control compensation of manipulator arm, the error compensation of multi-legged robots has seldom been explored. In order to reduce the kinematic error of robots, a motion error compensation method based on the feedforward for multi-legged mobile robots is proposed to improve motion precision of a mobile robot. The locus error of a robot body is measured, when robot moves along a given track. Error of driven joint variables is obtained by error calculation model in terms of the locus error of robot body. Error value is used to compensate driven joint variables and modify control model of robot, which can drive the robots following control model modified. The model of the relation between robot's locus errors and kinematic variables errors is set up to achieve the kinematic error compensation. On the basis of the inverse kinematics of a multi-legged walking robot, the relation between error of the motion trajectory and driven joint variables of robots is discussed. Moreover, the equation set is obtained, which expresses relation among error of driven joint variables, structure parameters and error of robot's locus. Take MiniQuad as an example, when the robot MiniQuad moves following beeline tread, motion error compensation is studied. The actual locus errors of the robot body are measured before and after compensation in the test. According to the test, variations of the actual coordinate value of the robot centroid in x-direction and z-direction are reduced more than one time. The kinematic errors of robot body are reduced effectively by the use of the motion error compensation method based on the feedforward.
Hybrid solutions to time-domain electromagnetic problems offer many advantages when solving open-region scattering or radiation problems. Hybrid formulations use a finite-element or finite-difference discretization for the features of interest, then bound this region with a layer of planar boundary elements. The use of volume discretization allows for intricate features and many changes in material within the structure, while the boundary-elements provide a highly accurate radiating boundary condition. This concept has been implemented previously, using the boundary elements to set the E-field, H-field, or both for an FDTD grid, for example in [1][2][3], or as a mixed boundary condition for the second order wave equation solved by finite elements [4]. Further study has focused on using fast methods, such as the Plane Wave Time Domain method [3][4] to accelerate the BEM calculations. This paper details a hybrid solver using the coupled first-order equations for the E and H fields in the finite-element region. This formulation is explicit, with a restriction on the time step for stability. When this time step is used in conjunction with the boundary elements forming either a inhomogeneous Dirichlet or Neuman boundary condition on the finite-element mesh, late time instabilities occur. To combat this, a Unified Boundary Condition (UBC), similar to the one in [4] for the second-order wave equation, is used. Even when this UBC is used, the late time instabilities are merely delayed if standard testing in time is used. However, the late time instabilities can be removed by replacing centroid based time interpolation with quadrature point based time interpolation for the boundary elements, or by sub-cycling the boundary element portion of the formulation. This sub-cycling, used in [3] for FDTD to reduce complexity, is shown here to improve stability and overall accuracy of the technique.
We investigate galactic-scale outflowing winds in 72 star-forming galaxies at z ~ 1 in the Extended Groth Strip. Galaxies were selected from the DEEP2 survey and follow-up LRIS spectroscopy was obtained covering Si II, C IV, Fe II, Mg II, and Mg I lines in the rest-frame ultraviolet. Using Galaxy Evolution Explorer (GALEX), Hubble Space Telescope (HST), and Spitzer imaging available for the Extended Groth Strip, we examine galaxies on a per-object basis in order to better understand both the prevalence of galactic outflows at z ~ 1 and the star-forming and structural properties of objects experiencing outflows. Gas velocities, measured from the centroids of Fe II interstellar absorption lines, are found to span the interval [–217, +155] km s–1. We find that ~40% (10%) of the sample exhibits blueshifted Fe II lines at the 1? (3?) level. We also measure maximal outflow velocities using the profiles of the Fe II and Mg II lines; we find that Mg II frequently traces higher velocity gas than Fe II. Using quantitative morphological parameters derived from the HST imaging, we find that mergers are not a prerequisite for driving outflows. More face-on galaxies also show stronger winds than highly inclined systems, consistent with the canonical picture of winds emanating perpendicular to galactic disks. In light of clumpy galaxy morphologies, we develop a new physically motivated technique for estimating areas corresponding to star formation. We use these area measurements in tandem with GALEX-derived star formation rates (SFRs) to calculate SFR surface densities. At least 70% of the sample exceeds an SFR surface density of 0.1 M ? yr–1 kpc–2, the threshold necessary for driving an outflow in local starbursts. At the same time, the outflow detection fraction of only 40% in Fe II absorption provides further evidence for an outflow geometry that is not spherically symmetric. We see a ~3? trend between outflow velocity and SFR surface density, but no significant trend between outflow velocity and SFR. Higher resolution data are needed in order to test the scaling relations between outflow velocity and both SFR and SFR surface density predicted by theory. Based, in part, on data obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and NASA, and was made possible by the generous financial support of the W. M. Keck Foundation.
Abstract in spanish Se propone un método que determina la rigidez mínima de arrostramiento requeridos por un sistema elástico de varias columnas para lograr condiciones de pandeo sin deriva entre pisos. Las ecuaciones que evalúan la rigidez mínima requerida de los arrostramientos laterales y de torsión y la carga crítica de pandeo ?arriostrada" correspondiente para cada columna del nivel de piso se obtienen utilizando las funciones de estabilidad modificadas. Se incluyen los siguient (more) es efectos: 1) tipos de conexiones (rígidas, semirrígidas y simples), 2) la distribución en planta de las columnas (es decir, la orientación de la sección transversal y la ubicación del centro de gravedad de cada columna), 3) deformaciones por cortante a lo largo de cada columna mediante el método modificado propuesto por Haringx en 1948, y 4) distribución de la carga axial entre las columnas (es decir, el patrón de carga). Los efectos de las deformaciones axial y de torsión no están incluidos. El método propuesto es aplicable a estructuras 2D y 3D con conexiones rígidas, semirígidas y simple. La formulación se presenta en este documento se basa en un trabajo previo presentado por Aristizábal-Ochoa en 2007. Se demuestra que la rigidez mínima de los arrostramientos laterales y de torsión requeridos por un sistema de varias columnas depende de: 1) la distribución en planta las columnas; 2) la variación en altura y propiedades de la sección transversal de las columnas; 3)las rigideces a flexión y a cortante de cada columna; 4) el patrón de cargas en el sistema de columnas; 5) la falta de simetría (en el patrón de carga, en la disposición de las columnas, tamaños de las columnas, y sus alturas) que hacen que el pandeo combinado de torsión y flexión lateral pueden reducir la capacidad de pandeo critico de la estructura en su conjunto; y 6) las condiciones de apoyo y restricciones en el extremo superior de las columnas. El método propuesto se limita a sistemas multi-columna con columnas elásticas y ortotrópicas con secciones transversales doblemente simétricas (es decir, con centro de corte coincidiendo con el centroide) orientadas en cualquier dirección con respecto a los ejes globales. Se presentan cuatro ejemplos en detalle en una publicación adjunta que muestran la eficacia y la simplicidad del método propuesto. Abstract in english A method that determines the minimum bracing stiffness required by a multi-column elastic system to achieve non-sway buckling conditions is proposed. Equations that evaluate the required minimum stiffness of the lateral and torsional bracings and the corresponding ?braced" critical buckling load for each column of the story level are derived using the modified stability functions. The following effects are included: 1) the types of end connections (rigid, semirigid, and (more) simple); 2) the blueprint layout of the columns (i.e., the cross section orientation and location of the centroid of each column); 3) shear deformations along each column using the modified method initially proposed by Haringx in 1948; and 4) axial load distribution among the columns (i.e., load pattern). The effects of axial deformations and warping torsion are not included. The proposed method is applicable to 2D and 3D framed structures with rigid, semi-rigid, and simple connections. The formulation presented in this paper is based on a previous work presented by Aristizabal-Ochoa in 2007. It is shown that the minimum stiffness of lateral and torsional bracings required by a multi-column system depend on: 1) the blueprint layout of the columns; 2) the variation in heights and cross sectional properties among the columns; 3) the flexural and shear stiffness of each column; 4) the load pattern on the multi-column system; 5) the lack of symmetry (in the loading pattern, column layout, column sizes, and heights) that cause the combined torsion-sway buckling all of which reduce the buckling capacity of the frame as a whole; and 6) the support conditions and restraints at the top end of the columns. The proposed method is limited to multi-column systems with elastic and orthotropic columns with doubly symmetrical cross sections (i.e., with a shear center coinciding with the centroid) oriented in any direction with respect to the global axes. Four comprehensive examples are presented in detail in a companion paper that shows the effectiveness and simplicity of the proposed method.
Abstract in spanish En este trabajo se presentan los resultados de la investigación para la modelación estratégica de transporte de carga en Colombia incluyendo sus costos externos. El modelo utilizado sigue una estructura secuencial de equilibrio entre las fases de distribución y asignación, es de escala nacional interregional, con una perspectiva de decisiones del orden estratégico. La red de transporte utilizada consta de 27.469 km de carreteras, 11.257 km de ríos navegables, 2.192 (more) km de ferrocarril y un conjunto de conectores de centroides para establecer el nexo con el sistema de zonificación, compuesto por 70 zonas internas y 8 zonas externas. Cada arco de la red incluye, entre los costos internos, el del tiempo y el de operación, y entre los costos externos, la congestión, accidentes, polución del aire y emisiones de dióxido de carbono (CO2). El análisis de costos internos no incluyó los de posesión vehicular, y en la evaluación de los costos externos no se tuvieron en cuenta los relacionados con ruido, afectación del paisaje y cambio climático. El cálculo de costos marginales sobre la red se hace aplicando dos métodos. El primero supone que la demanda adicional no afecta el equilibrio de la red y estima el costo marginal sumando los costos marginales sobre los arcos de la ruta más corta. El segundo presume variación del equilibrio existente y estima el costo marginal calculando la diferencia entre las dos situaciones de equilibrio. Los dos métodos son aplicados sobre siete corredores de transporte de carga en Colombia. En los costos externos se encuentra un promedio de 28 $/ton/km en el modo de transporte carretero; 0,21 $/ton/km en el modo de transporte fluvial y 3,25 $/ton/km en el modo de transporte ferroviario, con una preponderancia de los costos ambientales superior al 90%. Abstract in english This report presents the results of research regarding strategic freight transport network modelling in Colombia using external cost. The model uses sequential equilibrium between distribution and traffic assignment phases; it is national and inter-regional, involving strategic decisionmaking. The Colombian transport network consists of 27,469 km of roads, 11,257 km of navigable rivers, 2,192 km of railway lines and a set of centroid connectors for establishing a link wit (more) h the zoning system (consisting of 70 internal areas and 8 external areas). Each link in a network involves internal costs: time, operation and external costs, congestion, accidents, air pollution and CO2 emissions. Vehicle ownership costs were excluded from internal cost analysis; costs such as noise, climate change and effects on the landscape were not studied in external costs. Marginal costs regarding the network were estimated by two methods. First, it was assumed that an additional unit of demand did not affect equilibrium in a transport network and then marginal cost was estimated as being the sum of marginal costs regarding links in the shortest path. The other approach assumed that an additional unit of demand changed network equilibrium; marginal costs were then estimated by calculating the difference between the two equilibrium scenarios. The methods were applied to 7 selected routes covering the most important Colombian freight transport corridors. An average 0.014 US$/ton/km rate was estimated for external costs regarding highway transport, 0.000105 US$/ton/km for water transport and 0.001625 US$/ton/km for railroad transport (preponderance of environmental costs exceeding 90%).
We propose and implement a cluster-based approach for identifying global phenological observatories in which phenologically and climatologically self-similar pixel clusters are monitored. We developed clusters based on a wavelet-filtered subset of the 1982-1999 global Pathfinder Advanced Very High Resolution Radiometer (AVHRR) Land (PAL) Normalized Difference Vegetation Index (NDVI) dataset, a global 10-minute resolution climatology, and the clustering approach developed by the Oak Ridge National Laboratories (ORNL). In the ORNL approach: (1) n cluster centers are defined based on the multi-dimensional NDVI/climate space; (2) pixel distances from the centroids are calculated; (3) pixels are assigned to the minimum distance cluster. While any number of clusters may be specified, we found that a global 500-cluster approach provided a satisfactory global distribution. In traditional rectangular approaches a group of pixels could contain desert, grassland, and tropical forest. Here, longitudinally extensive but latitudinally limited regions such as the Sahel exist as distinct groups. Thus, our approach avoids problems affecting single-pixel approaches (misregistration, cloud contamination) and rectangular approaches (mixed phenological signals). Using the 1982-2003 GIMMS AVHRR dataset, we extracted phenological metrics such as the onset and offset of greenness for each cluster. We then ranked each cluster based on land cover homogeneity, evidence of human impacts, and political diversity. For each biome, we then identified the highest ranked clusters within four climate zones (hot/wet, hot/dry, cold/wet, cold/dry). This strategy provides: (1) selection of regions for which a strong annual is detectable, (2) a method of identifying regions least likely to be impacted by non-climatic factors, and (3) a strategy for ground validation.
The aim of this research is to determine whether geometric morphometric (GM) techniques can provide insights into how the shape of the mandibular corpus differs between bonobos and chimpanzees and to explore the potential implications of those results for our understanding of hominin evolution. We focused on this region of the mandible because of the relative frequency with which it has been recovered in the hominin fossil record. In addition, no previous study had explored in-depth three-dimensional (3D) mandibular corpus shape differences between adults of the two Pan species using geometric morphometrics. GM methods enable researchers to quantitatively analyze and visualize 3D shape changes in skeletal elements and provide an important compliment to traditional two-dimensional analyses. Eighteen mandibular landmarks were collected using a Microscribe 3DX portable digitizer. Specimen configurations were superimposed using Generalized Procrustes analysis and the projections of the fitted coordinates to tangent space were analyzed using multivariate statistics. The size-adjusted corpus shapes of Pan paniscus and Pan troglodytes could be assigned to species with approximately 93% accuracy and the Procrustes distance between the two species was significant. Analyses of the residuals from a multivariate linear regression of the data on centroid size suggested that much of the shape difference between the species is size-related. Chimpanzee subspecies and a small sample of Australopithecus specimens could be correctly identified to taxon, at best, only 75% of the time, although the Procrustes distances between these taxa were significant. The shape of the mandibular symphysis was identified as especially useful in differentiating Pan species from one another. This suggests that this region of the mandible has the potential to be informative for taxonomic analyses of fossil hominoids, including hominins. The results also have implications for phylogenetic hypotheses of hominoid evolution. PMID:22682959
Indicators and indices can be an effective method for tracking environmental conditions over time, and thus for assessing the effectiveness of policy measures or remediation activities. Relative to surface water resources, however, groundwater has received little attention in this regard. This is problematic: about 30% and 44% of the Canadian and American populations depend on groundwater resources, with localized reliance of up to 100%. Aquifers can also serve key functions in watershed hydrology by attenuating peak flows, providing baseflow and associated aquatic habitat, moderating water temperature, and providing transport pathways for contaminants from the land surface to the open freshwater environment. Here, we introduce a prototype groundwater sustainability index. It is holistic in the sense that it incorporates both quantity and quality indicators. The former is based on the signal-to-noise ratio of long-term water level trends as estimated via robust (rank-based) regression, whereas the latter is based on concentration of the chief contaminant of concern. A fuzzy inference system is employed to integrate these unlike metrics, and has the additional advantages of explicitly encoding expert knowledge and directly acknowledging subjectivity in environmental condition "grading" through the use of linguistic rules and fuzzy sets, respectively. The rule base is constructed such that poor environmental conditions captured by one measure would not be hidden by good environmental performance in another. A standard Mamdani (max-min) inference engine is used in conjunction with centroid defuzzification. The outcome is a fuzzy logic-based groundwater sustainability index (FGWSI) ranging from 0 to 100. The index is demonstrated using both synthetic and observational datasets, including examples from the Abbotsford-Sumas aquifer, an important and managerially challenging transboundary (Canada-US) water resource.
Estimates of radiation absorbed doses from radionuclides internally deposited in a pregnant woman and her fetus are very important due to elevated fetal radiosensitivity. This paper reports a set of specific absorbed fractions (SAFs) for use with the dosimetry schema developed by the Society of Nuclear Medicine's Medical Internal Radiation Dose (MIRD) Committee. The calculations were based on three newly constructed pregnant female anatomic models, called RPI-P3, RPI-P6, and RPI-P9, that represent adult females at 3-, 6-, and 9-month gestational periods, respectively. Advanced Boundary REPresentation (BREP) surface-geometry modeling methods were used to create anatomically realistic geometries and organ volumes that were carefully adjusted to agree with the latest ICRP reference values. A Monte Carlo user code, EGS4-VLSI, was used to simulate internal photon emitters ranging from 10 keV to 4 MeV. SAF values were calculated and compared with previous data derived from stylized models of simplified geometries and with a model of a 7.5-month pregnant female developed previously from partial-body CT images. The results show considerable differences between these models for low energy photons, but generally good agreement at higher energies. These differences are caused mainly by different organ shapes and positions. Other factors, such as the organ mass, the source-to-target-organ centroid distance, and the Monte Carlo code used in each study, played lesser roles in the observed differences in these. Since the SAF values reported in this study are based on models that are anatomically more realistic than previous models, these data are recommended for future applications as standard reference values in internal dosimetry involving pregnant females.
Purpose: To measure the three-dimensional motion of liver tumors using cine-magnetic resonance imaging (MRI) and compare it to the liver motion assessed using fluoroscopy. Methods and Materials: Liver and liver tumor motion were investigated in the first 36 patients with primary (n = 20) and metastatic (n = 16) liver cancer accrued to our Phase I stereotactic radiotherapy study. At simulation, all patients underwent anteroposterior fluoroscopy, and the maximal diaphragm excursion in the craniocaudal (CC) direction was observed. Cine-MRI using T{sub 2}-weighted single shot fast spin echo sequences were acquired in three orthogonal planes during free breathing through the centroid of the most dominant liver tumor. ImageJ software was used to measure the maximal motion of the tumor edges in each plane. The intra- and interobserver reproducibility was also quantified. Results: The average CC motion of the liver at fluoroscopy was 15 mm (range, 5-41). On cine-MRI, the average CC tumor motion was 15.5 mm (range, 6.9-35.4), the anteroposterior motion was 10 mm (range, 3.7-21.6), and the mediolateral motion was 7.5 mm (range, 3.8-14.8). The fluoroscopic CC diaphragm motion did not correlate well with the MRI CC tumor motion (r = 0.25). The mean intraobserver error was <2 mm in the CC, anteroposterior, and mediolateral directions, and 90% of measurements between observers were within 3 mm. Conclusions: The results of our study have shown that cine-MRI can be used to directly assess liver tumor motion in three dimensions. Tumor motion did not correlate well with the diaphragm motion measured using kilovoltage fluoroscopy. The tumor motion data from cine-MRI can be used to facilitate individualized planning target volume margins to account for breathing motion.
I present the results from an ongoing large campaign with the Spitzer Space Telescope to gather near-infrared photometric measurements of Kepler Objects of Interest (KOI). Our goals are (1) to validate the planetary status of these Kepler candidates, (2) to estimate observationally the false positive rate, and (3) to study the atmospheres of confirmed planets through measurements of their secondary eclipses. Our target list spans of wide range of candidate sizes and periods orbiting various spectral type stars. The Spitzer observations provide constraints on the possibility of astrophysical false positives resulting from stellar blends, including eclipsing binaries and hierarchical triples. The number of possible blends per star is estimated using stellar population synthesis models and observational probes of the KOI close environments from direct imaging (e.g. Adaptive Optics, Speckle images, Kepler centroids). Combining all the above information with the shape of the transit lightcurves from the Kepler photometry, we compute odd ratios for the 34 candidates we observed in order to determine their false positive probability. Our results suggest that the Kepler false positive rate in this subset of candidates is low. I finally present a new list of Kepler candidates that we were able to validate using this method. This work is based on observations made with the Spitzer, which is operated by JPL/Caltech, under a contract with NASA. Support was provided by NASA through an award issued by JPL/Caltech. Kepler was selected as the 10th mission of the Discovery Program. Funding for this mission is provided by NASA, Science Mission Directorate.
The University of North Dakota Geothermal Laboratory is working on the National Geothermal Data Aggregation project in conjunction with Southern Methodist University (SMU) and other partners, and funded by the Department of Energy to collect data for exploration and utilization of resources for geothermal power production. We have examined 10,951 wells in the Williston Basin to determine accurate methods for estimating power extraction potential in a sedimentary basin. The calculations we used involved defining the area of wells within designated ranges and calculating the geothermal fluid reservoir volume using porosity data from the North Dakota Geological Survey Wilson M. Laird Core Library. We defined the parameters for our calculations as: bottom-hole temperature (BHT), formation thickness data, surface area of the polygon around wells within the temperature range, and porosity data. The wells in each formation with a BHT over 90°C were imported into ArcGIS, buffered to 1.6 kilometers from centroid, and outlined with a polygon feature to define the surface area. We then included average formation thickness to determine an approximate volume for ten water and rock reservoirs. In calculating this available energy the following three assumptions were made; that 1/1000 of the water volume is available to use per year, that the temperature is lowered to 50°C during electrical power production, and that the efficiency of the binary power plant utilized is 14%. The estimated recoverable energy in the volume of rock containing geothermal fluids by temperature range is as follows: 1.32 x 108 MW for 90°-100° C, 1.92 x 108 MW for 100°-110° C, 2.15 x 108 MW for 110°-120° C, 2.4 x 108 MW for 120°-130° C, 1.4 x 108 MW for 130°-140° C, 4.95 x 107 MW for 140°-150° C, and 3.67 x 107 MW for 150° C and up.
The purpose of this study was to assess target repositional accuracy with respect to the bony structures using daily CBCT, and to validate the planning target volume (PTV) margin used in the lung SBRT. All patients underwent 4D CT scanning in preparation for lung SBRT. The internal target volume (ITV) was outlined from the reconstructed 4D data using the maximum-intensity projection (MIP) algorithm. A 6 mm margin was added to the ITV to create the PTV. Conformal treatment planning was performed on the helical images, to which the MIP images were fused. Prior to each treatment, CBCT was taken after a patient was set up in the treatment position. The CBCT images were fused with the simulation CT based on the bony anatomy, in order to derive setup errors and separate them from the tumor repositional errors. The treating physician then checked and modified the alignment based on target relocalization within the PTV. The shifts determined in such a method were recorded and the subtractions of these shifts with respect to the corresponding setup errors were defined as the target relocalization accuracy. Our study of 36 consecutive patients, treating 38 targets for a total of 153 fractions shows that, after setup error correction, the target repositional accuracy followed a normal distribution with the mean values close to 0 in all directions, and standard deviations of 0.25 cm in A-P, 0.24 cm in Lat, and 0.28 cm in S-I directions, respectively. The probability of having the shifts ? 0.6 cm is less than 0.8% in A-P, 0.6% in Lat, and 1.7 % in S-I directions. For the patient population studied, the target centroid position relative to the bony structures changed minimally from day to day. This demonstrated that the PTV margin that is designed on the MIP image-based ITV was adequate for lung SBRT. PMID:22402387
Direct-detection (or incoherent) lidar is now a proven technique for measuring winds in the atmosphere. Over the last few years, several types of direct-detection lidar have evolved. These methods rely on Fabry-Perot interferometers(also termed etalons) or other narrow-passband filters to provide the required spectral resolution. One method, now called the edge (EDG) technique, uses a sharply-sloping filter and measures changes in the filter transmission caused by Doppler shifting of the laser wavelength. A variation of the EDG method, called the double-edge (DEDG) technique, uses two filters. The molecular DEDG method was first demonstrated by Chanin et al. for stratospheric measurements and more recently Korb et al. successfully demonstrated the aerosol DEDG through the troposphere. A second method, here termed the multi-channel (MC) technique, measures Doppler shifts by observing angular displacement of a Fabry-Perot fringe in a spatially resolving detector. The EDG technique thus employs the Fabry-Perot to convert the frequency shift into an amplitude signal, while the MC technique uses the Fabry-Perot to resolve the spectral signature which is then fitted to determine the centroid. The focus of this presentation is on the DEDG and MC methods because these are viewed as the current state of the art in direct-detection lidar. Successful ground-based demonstrations of direct-detection wind measurements have resulted in proposals for spaceborne systems. With this new emphasis on spaceborne systems comes the need for accurate prediction of spaceborne direct-detection Doppler lidar performance. Previously, the EDG and MC methods have been compared although only for aerosol Doppler systems. A recent paper by McGill and Spinhirne compares the DEDG and MC methods in a non-system specific manner for both the aerosol and molecular Doppler systems. The purpose of this presentation is to extend the previous work of McGill and Spinhirne to examine the performance of spaceborne profiling systems. Particular emphasis will be placed on the molecular systems, as these are viewed as the strength of direct-detection Doppler lidar.
On 2010 November 14, an intense swarm of earthquakes began in the western Gulf of Aden. Within a 48-hr period, 82 earthquakes with magnitudes between 4.5 and 5.5 were reported along an ˜80-km-long segment of the east-west trending Aden Ridge, making this swarm one of the largest ever observed in an extensional oceanic setting. In this study, we calculate centroid-moment-tensor solutions for 110 earthquakes that occurred between 2010 November and 2011 April. Over 80 per cent of the cumulative seismic moment results from earthquakes that occurred within 1 week of the onset of the swarm. We find that this sequence has a b-value of ˜1.6 and is dominated by normal-faulting earthquakes that, early in the swarm, migrate westwards with time. These earthquakes are located in rhombic basins along a section of the ridge that was previously characterized by low levels of seismicity and a lack of recent volcanism on the seafloor. Body-wave modelling demonstrates that the events occur in the top 2-3 km of the crust. Nodal planes of the normal-faulting earthquakes are consistent with previously mapped faults in the axial valley. A small number of strike-slip earthquakes observed between two basins near 44°E, where the axial valley changes orientation, depth and width, likely indicate the presence of an incipient transform fault and the early stages of ridge-transform segmentation. The direction of extension accommodated by the earthquakes is intermediate between the rift orthogonal and the direction of relative motion between the Arabian and Somalian plates, consistent with the oblique style of rifting occurring along the slow-spreading Aden Ridge. The 2010 swarm shares many characteristics with dyke-induced rifting episodes from both oceanic and continental settings. We conclude that the 2010 swarm represents the seismic component of an undersea magmatic rifting episode along the nascent Aden Ridge, and attribute the large size of the earthquakes to the combined effects of the slow spreading rate, relatively thick crust and recent quiescence. We estimate that the rifting episode was caused by dyke intrusions that propagated laterally for 12-18 hr, accommodating ˜1-14 m of opening or ˜85-800 yr of spreading along this section of the ridge. Our findings demonstrate the westward propagation of active seafloor spreading into this section of the western Gulf of Aden and illustrate that deformation at the onset of seafloor spreading may be accommodated by discrete episodes of faulting and magmatism. A comparison with similar sequences on land suggests that the 2010 episode may be only the first of several dyke-induced rifting episodes to occur in the western Gulf of Aden.
An inversion method for retrieving seismic anisotropy from non-double-couple components of seismic moment tensors is presented. The method requires a set of highly accurate moment tensors of earthquakes that occurred in a homogeneous anisotropic focal area on differently oriented faults. In contrast to standard methods retrieving anisotropy from travel times or from shear wave splitting, which yield an overall anisotropy averaged along a whole ray path, the presented method yields a local value of anisotropy just in the focal area. The method is robust, being able to retrieve the orientation as well as strength of anisotropy even for low anisotropy symmetries as for orthorhombic symmetry. The method can utilize the moment tensors constrained to have zero trace, but using unconstrained moment tensors is advantageous. The method is applied to retrieving anisotropy in the Tonga subduction zone using moment tensors of deep-focus earthquakes reported in the Harvard centroid moment tensor catalog. The inversion is complemented by tests on synthetic data to assess its stability and the accuracy of the results. The inversion indicates that the subduction zone is anisotropic with orthorhombic symmetry. The orientation of the intra-slab anisotropy is defined by axes (azimuth/dip) a1 = 320°/54°, a2 = 121°/38°, and a3 = 223°/81°. The errors in the azimuth and dip are about 5°. The first and second axes lie along the downdip motion of the slab and along the normal to the slab, respectively. The strength of the P, S1, and S2 anisotropy is of 7.3 +/- 1.5%, 13.4 +/- 2.5%, and 12.6 +/- 3.5%, respectively. The errors of anisotropy strength are only rough estimates, which reflect random but not systematic errors in the moment tensors used in the inversion. The values for anisotropy strength in the slab are remarkably higher than those observed in the surrounding mantle. The symmetry axes of anisotropy coincide with the principal stress directions in the slab. This manifests a primary impact of stress on anisotropy formation. The retrieved anisotropy in the slab can serve as an additional constraint on its structure and mineralogical composition.
The SOM algorithm and numerical taxonomy has been applied to classify the Tajo hydrographic basin (Spain) till Portugal border. A total of 52 stations have collected data. 15 variables of water have been used in this study: flow (m3/sec), pH, electrical conductivity, concentration of several cations and anions (mgr/l) such as Cl-, SO4=, alkalinity (CO3H-, CO3=, OH-), Ca2+, Mg2+, Na+ and K+. The analysis proceeds in two different lines. First, the Kohonen algorithm is trained using as input the corresponding mean each of the variables for each station. This will allow us to establish different clusters characterized in terms of the variables and other auxiliary variables before that referred to us the help we understand and explain the construction of the groups. Second, a new Kohonen network will be trained using as inputs averages of the latent variables or factors obtained after carrying out factor analysis on all available data. Different groups were obtained by applying a Euclidean distance between stations (distance classification) and a Euclidean distance between each station and the estimated centre of gravity between them (centroid classification), varying the number of parameters and with or without standardized variable. The partitions are performed in the entire network. Each group is identified by a number and a colour assigned to the network. The partitions the network evolved to get the best choice. Final partition is associated with a dendrogram. The averages for the variables associated with each cluster and total cluster are shown in a table. To compare the classification of a log-log relationship is established between the number of groups created and distances, to select the best. We found that the centroid is more appropriate classification after a logic way more natural constraints that the minimum distance between stations. Standardized variable does not improve the classification, except when the centre of gravity method is applied. It taking into account the ions and the sum of them as variables, we obtain the best classification. The stations are grouped according to the electrical conductivity (EC), total anions (ta), total cations (ct) and the ratio of the ions (Na / Ca y Mg / Ca). For a given classification and comparison of different groups created some variation in ion concentration and the ratio of the ions are observed. However, the variation in each ion is different between groups as appropriate. For the latter group, regardless of classification, the increase of all ions is general. Comparing the dendrograms, and the groups that originated the Tajo river basin can be sub dived into five distinct sub-basins by the main influence on the water: 1.With a greater influence ombrogenic (rainfed). 2.The ombrogenic and soil influence (rain and groundwater fed). 3.With pedogenic influence. 4.With lithogenic influence (geological foundation). 5.With greater and lithogenic ombrogenic additional influence. Funding provided by Spanish Ministerio de Ciencia e Innovación (MICINN) through project no. AGL2010-21501/AGR is greatly appreciated.
A scheme is proposed for referencing the propagation direction of the transmit laser signal in pointing a free-space optical communications terminal. This recently developed scheme enables the use of low-cost, commercial silicon-based sensors for tracking the direction of the transmit laser, regardless of the transmit wavelength. Compared with previous methods, the scheme offers some advantages of less mechanical and optical complexity and avoids expensive and exotic sensor technologies. In free-space optical communications, the transmit beam must be accurately pointed toward the receiver in order to maintain the communication link. The current approaches to achieve this function call for part of the transmit beam to be split off and projected onto an optical sensor used to infer the pointed direction. This requires that the optical sensor be sensitive to the wavelength of the transmit laser. If a different transmit wavelength is desired, for example to obtain a source capable of higher data rates, this can become quite impractical because of the unavailability or inefficiency of sensors at these wavelengths. The innovation proposed here decouples this requirement by allowing any transmit wavelength to be used with any sensor. We have applied this idea to a particular system that transmits at the standard telecommunication wavelength of 1,550 nm and uses a silicon-based sensor, sensitive from 0.5 to 1.0 micrometers, to determine the pointing direction. The scheme shown in the figure involves integrating a low-power 980-nm reference or boresight laser beam coupled to the 1,550-nm transmit beam via a wavelength-division-multiplexed fiber coupler. Both of these signals propagate through the optical fiber where they achieve an extremely high level of co-alignment before they are launched into the telescope. The telescope uses a dichroic beam splitter to reflect the 980- nm beam onto the silicon image sensor (a quad detector, charge-coupled device, or active-pixel-sensor array) while the 1,550- nm signal beam is transmitted through the optical assembly toward the remotely located receiver. Since the 980-nm reference signal originates from the same single-mode fiber-coupled source as the transmit signal, its position on the sensor is used to accurately determine the propagation direction of the transmit signal. The optics are considerably simpler in the proposed scheme due to the use of a single aperture for transmitting and receiving. Moreover, the issue of mechanical misalignment does not arise because the reference signal and transmitted laser beams are inherently co-aligned. The beam quality of the 980-nm reference signal used for tracking is required to be circularly symmetric and stable at the tracking-plane sensor array in order to minimize error in the centroiding algorithm of the pointing system. However, since the transmit signal is delivered through a fiber that supports a single mode at 1,550 nm, propagation of higher order 980-nm modes is possible. Preliminary analysis shows that the overall mode profile is dominated by the fundamental mode, giving a near symmetric profile. The instability of the mode was also measured and found to be negligible in comparison to the other error contributions in the centroid position on the sensor array.
Eruptive activity at the summit of Kilauea Volcano, Hawaii, beginning in March, 2008 and continuing to the present time is characterized by episodic explosive bursts of gas and ash from a vent within Halemaumau Pit Crater. These bursts are accompanied by seismic signals that are well recorded by a broadband network deployed in the summit caldera. We investigate in detail the dimensions and oscillation modes of the source of a representative burst in the 1-10 s band. An extended source is realized by a set of point sources distributed on a grid surrounding the source centroid, where the centroid position and source geometry are fixed from previous modeling of very-long-period (VLP) data in the 10-50 s band. The source time histories of all point sources are obtained simultaneously through waveform inversion carried out in the frequency domain. Short-scale noisy fluctuations of the source time histories between adjacent sources are suppressed with a smoothing constraint, whose strength is determined through a minimization of the Akaike Bayesian Information Criterion (ABIC). Waveform inversions carried out for homogeneous and heterogeneous velocity structures both image a dominant source component in the form of an east trending dike with dimensions of 2.9 × 2.9 km. The dike extends ˜2 km west and ˜0.9 km east of the VLP centroid and spans the depth range 0.2-3.1 km. The source model for a homogeneous velocity structure suggests the dike is hinged at the source centroid where it bends from a strike E 27°N with northern dip of 85° west of the centroid, to a strike E 7°N with northern dip of 80° east of the centroid. The oscillating behavior of the dike is dominated by simple harmonic modes with frequencies ˜0.2 Hz and ˜0.5 Hz, representing the fundamental mode ?11 and first degenerate mode ?12 = ?21 of the dike. Although not strongly supported by data in the 1-10 s band, a north striking dike segment is required for enhanced compatibility with the model elaborated in the 10-50 s band. This dike provides connectivity between the east trending dike and the new vent within Halemaumau Pit Crater. Waveform inversions with a dual-dike model suggest dimensions of 0.7 × 0.7 km to 2.6 × 2.6 km for this segment. Further elaboration of the complex dike system under Halemaumau does not appear to be feasible with presently available data.
Oct 26, 2012 ... SWG members meet biannually to discuss the latest findings in the Kepler data and to discuss future plans. ... mass determinations using the Doppler method for many of Kepler's most interesting planets. ... Find this article at: ...
and technical findings that are preliminary or of specialized ... technical findings by NASA-sponsored ..... areas and leaf angle assuming that the leaf contact points with .... these concepts and then compared the modeling methods along ...
This quarter, we have focused on several tasks: (1) Building a high-quality catalog of earthquake source parameters for the Middle East and East Asia. In East Asia, we computed source parameters using the CAP method for a set of events studied by Herrman et al., (MRR, 2006) using a complete waveform technique. Results indicated excellent agreement with the moment magnitudes in the range 3.5 -5.5. Below magnitude 3.5 the scatter increases. For events with more than 2-3 observations at different azimuths, we found good agreement of focal mechanisms. Depths were generally consistent, although differences of up to 10 km were found. These results suggest that CAP modeling provides estimates of source parameters at least as reliable as complete waveform modeling techniques. However, East Asia and the Yellow Sea Korean Paraplatform (YSKP) region studied are relatively laterally homogeneous and may not benefit from the CAP method’s flexibility to shift waveform segments to account for path-dependent model errors. A more challenging region to study is the Middle East where strong variations in sedimentary basin, crustal thickness and crustal and mantle seismic velocities greatly impact regional wave propagation. We applied the CAP method to a set of events in and around Iran and found good agreement between estimated focal mechanisms and those reported by the Global Centroid Moment Tensor (CMT) catalog. We found a possible bias in the moment magnitudes that may be due to the thick low-velocity crust in the Iranian Plateau. (2) Testing Methods on a Lifetime Regional Data Set. In particular, the recent 2/21/08 Nevada Event and Aftershock Sequence occurred in the middle of USArray, producing over a thousand records per event. The tectonic setting is quite similar to Central Iran and thus provides an excellent testbed for CAP+ at ranges out to 10°, including extensive observations of crustal thinning and thickening and various Pnl complexities. Broadband modeling in 1D, 2D, and 3D will be presented. (3) Shallow Crustal Structure and Sparse Network Source Inversions for Southern California. We conducted a detailed test of a recently developed technique, CAPloc, in recovering source parameters including location and depth based on tomographic maps. We tested two-station solutions against 160 well determined events which worked well except for paths crossing deep basins and along mountain ridges.
Objective: To analyze radiological findings observed at high-resolution computed tomography in patients with sarcoidosis, and establishing their correlation with pathological findings. Materials and Methods: High-resolution computed tomography findings in ten patients with sarcoidosis were reviewed and correlated with findings in specimens obtained by surgical biopsy or at necropsy of four of such patients. Results: The most frequently observed finding was presence of nodules with perilymphatic distribution, predominating along bronchovascular sheaths and pleural surface, with subpleural nodules and nodular scissurae. Other less frequent findings were ground-glass attenuation and interlobular septa thickening. Conclusion: In general, all the mentioned findings demonstrated anatomopathological correlation with development of granulomas in these regions. (author)
An automated method is being developed in order to identify corresponding nodules in serial thoracic CT scans for interval change analysis. The method uses the rib centerlines as the reference for initial nodule registration. A spatially adaptive rib segmentation method first locates the regions where the ribs join the spine, which define the starting locations for rib tracking. Each rib is tracked and locally segmented by expectation-maximization. The ribs are automatically labeled, and the centerlines are estimated using skeletonization. For a given nodule in the source scan, the closest three ribs are identified. A three-dimensional (3D) rigid affine transformation guided by simplex optimization aligns the centerlines of each of the three rib pairs in the source and target CT volumes. Automatically defined control points along the centerlines of the three ribs in the source scan and the registered ribs in the target scan are used to guide an initial registration using a second 3D rigid affine transformation. A search volume of interest (VOI) is then located in the target scan. Nodule candidate locations within the search VOI are identified as regions with high Hessian responses. The initial registration is refined by searching for the maximum cross-correlation between the nodule template from the source scan and the candidate locations. The method was evaluated on 48 CT scans from 20 patients. Experienced radiologists identified 101 pairs of corresponding nodules. Three metrics were used for performance evaluation. The first metric was the Euclidean distance between the nodule centers identified by the radiologist and the computer registration, the second metric was a volume overlap measure between the nodule VOIs identified by the radiologist and the computer registration, and the third metric was the hit rate, which measures the fraction of nodules whose centroid computed by the computer registration in the target scan falls within the VOI identified by the radiologist. The average Euclidean distance error was 2.7{+-}3.3 mm. Only two pairs had an error larger than 10 mm. The average volume overlap measure was 0.71{+-}0.24. Eighty-three of the 101 pairs had ratios larger than 0.5, and only two pairs had no overlap. The final hit rate was 93/101.
We study large-scale outflows in a sample of 96 star-forming galaxies at 1 UV spectroscopy of Fe II and Mg II absorption and emission. The average blueshift of the Fe II interstellar absorption lines with respect to the systemic velocity is –85 ± 10 km s–1 at z ~ 1.5, with standard deviation 87 km s–1 this is a decrease of a factor of two from the average blueshift measured for far-UV interstellar absorption lines in similarly selected galaxies at z ~ 2. The profiles of the Mg II ??2796, 2803 lines show much more variety than the Fe II profiles, which are always seen in absorption; Mg II ranges from strong emission to pure absorption, with emission more common in galaxies with blue UV slopes and at lower stellar masses. Outflow velocities, as traced by the centroids and maximum extent of the absorption lines, increase with increasing stellar mass with 2?-3? significance, in agreement with previous results. We study fine structure emission from Fe II*, finding several lines of evidence in support of the model in which this emission is generated by the re-emission of continuum photons absorbed in the Fe II resonance transitions in outflowing gas. In contrast, photoionization models indicate that Mg II emission arises from the resonant scattering of photons produced in H II regions, accounting for the differing profiles of the Mg II and Fe II lines. A comparison of the strengths of the Fe II absorption and Fe II* emission lines indicates that massive galaxies have more extended outflows and/or greater extinction, while two-dimensional composite spectra indicate that emission from the outflow is stronger at a radius of ~10 kpc in high-mass galaxies than in low-mass galaxies. Based on data obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and the National Aeronautics and Space Administration, and was made possible by the generous financial support of the W. M. Keck Foundation.
Despite the success of lidar observations at the South Pole and near the Antarctic Circle at Rothera, Davis and Syowa stations, a critical data gap existed in latitude between 90°S and 69°S. To help fill this gap, during the austral summer of 2010-2011, we deployed an Fe Boltzmann temperature lidar to McMurdo Station (77.83°S, 166.66°E), half way between the South Pole and Antarctic Circle. This lidar was originally developed at the University of Illinois by Chu, Gardner and co-workers and deployed to the South Pole (1999-2001) and Rothera (2002-2005). Recently it was refurbished and upgraded at the University of Colorado. With the support and collaboration of the United States Antarctic Program (USAP) and the Antarctic New Zealand (AntNZ), the University of Colorado lidar group installed the Fe lidar into the AntNZ facility at Arrival Heights, McMurdo in late 2010. This lidar has full diurnal coverage and is capable of detecting polar mesospheric clouds (PMCs), meteoric Fe layers, and temperatures under full sunlight. Following installation, it was operated around the clock, weather permitting. In this paper we report the first lidar observations of polar middle and upper atmosphere at McMurdo, Antarctica, and present the newest science discoveries. These include the first-ever observations of neutral Fe layers with gravity wave signatures in the thermosphere from 110-155 km. Frequent occurrence of sporadic Fe layers and extremely active variations of main Fe layers are also unique among other lidar observations of metal species. These results of neutral Fe atoms challenge our understanding of the upper atmosphere composition, chemistry, dynamics and thermal structure. Furthermore, PMC data in the first summer season of 2010-2011 confirm previous reports of the inter-hemispheric difference in PMC mean centroid altitude. By combining the McMurdo observations with those obtained at the South Pole and Rothera, we find that the latitudinal dependence of mean PMC altitude is statistically significant with a slope of 40 ± 3 m/deg. Lidar observations provide direct evidence that the cold phase of wave-induced temperature oscillations facilitates PMC formation and Fe depletion.
An Interactive Cluster Analysis Procedure (ICAP) was developed to derive classifier training statistics from remotely sensed data. ICAP differs from conventional clustering algorithms by allowing the analyst to optimize the cluster configuration by inspection, rather than by manipulating process parameters. Control of the clustering process alternates between the algorithm, which creates new centroids and forms clusters, and the analyst, who can evaluate and elect to modify the cluster structure. Clusters can be deleted, or lumped together pairwise, or new centroids can be added. A summary of the cluster statistics can be requested to facilitate cluster manipulation. The principal advantage of this approach is that it allows prior information (when available) to be used directly in the analysis, since the analyst interacts with ICAP in a straightforward manner, using basic terms with which he is more likely to be familiar. Results from testing ICAP showed that an informed use of ICAP can improve classification, as compared to an existing cluster analysis procedure.
Interferometer observations of Jupiter using short antenna spacings were made in 1968 and 1970 at 21.1 cm wavelength and in 1971 at 18.7 cm. The flux density, centroid position, and complete polarization state of the integrated emission were determined at many different central meridian longitudes. A small displacement of the emission centroid from the center of the planet may have been detected. Of greater importance, perhaps, is that a displacement larger than about 0.15 radii is ruled out. The observations confirm the slow decrease in flux density over a period of years, and extend the time base to eleven years, during which there has been no start of a recovery from the decline. The variation of flux density and polarization with central meridian longitude changed character in several respects from earlier observations. Some, but not all of these changes can be explained by the change in our aspect angle since the earlier observations.
In the tripodinium cation of the title compound {systematic name: 2-[(E)-1-(4-methyl-phen-yl)-3-(pyrrolidin-1-ium-1-yl)prop-1-en-yl]pyridinium bis-(2,4,6-trinitro-phenolate)}, C(19)H(24)N(2) (+)·2C(6)H(2)N(3)O(7) (-), the N atoms on both the pyrrolidine and pyridinium groups are protonated. The pyrrolidine group adopts a slightly distorted envelope configuration. Strong N-H?O cation-anion hydrogen bonds and weak inter-molecular N-H?O inter-actions link the dication and two anions. In both picrate anions, the nitro groups display rotational disorder over two orientations in a 0.605?(6):0.395?(6) ratio. The crystal packing also features weak inter-molecular ?-? [centroid-centroid distance = 3.8036?(14)?Å] and C-H?O inter-actions. PMID:22064274
The title compound, C(30)H(25)NOP(2), is a bulky phosphazene derivative. Its previous crystal structure [Cameron et al. (1979 ?). Acta Cryst. B35, 1373-1377] is confirmed and its H atoms have been located in the present study. The formal P=N double bond is about 0.05?Å shorter than the P-N single bond and the large P=N-P bond angle reflects the steric strain in the mol-ecule. An intra-molecular C-H?O inter-action occurs. In the crystal, short C-H?O contacts connect the mol-ecules into chains propagating in [011], which are cross-linked via C-H?? inter-actions, generating a three-dimensional network. Aromatic ?-? stacking also occurs [shortest centroid-centroid separation = 3.6012?(11)?Å]. PMID:21754359
The title compound, C30H25NOP2, is a bulky phosphazene derivative. Its previous crystal structure [Cameron et al. (1979 ?). Acta Cryst. B35, 1373–1377] is confirmed and its H atoms have been located in the present study. The formal P=N double bond is about 0.05?Å shorter than the P—N single bond and the large P=N—P bond angle reflects the steric strain in the molecule. An intramolecular C—H?O interaction occurs. In the crystal, short C—H?O contacts connect the molecules into chains propagating in [011], which are cross-linked via C—H?? interactions, generating a three-dimensional network. Aromatic ?–? stacking also occurs [shortest centroid–centroid separation = 3.6012?(11)?Å].
In the title compound, C(16)H(15)BrN(2)O(3), there are two independent mol-ecules (A and B) in the asymmetric unit. The major difference between the two mol-ecules is the dihedral angle formed by the aromatic rings [72.6?(2) and 18.8?(2)° for A and B, respectively]. The benzohydrazide groups are not planar and the mol-ecules exist in trans configurations with respect to the methyl-idene units. The mol-ecular packing is stabilized by two inter-molecular N-H?O hydrogen bonds, forming chains parallel to the c axis. Only the A mol-ecules of the asymmetric unit are held together by ?-? inter-actions [centroid-centroid distance = 3.714?(3)?Å]. PMID:21582592
In the title dinuclear complex, [Tb(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)], each Tb(III) ion is eight-coordinated by two N atoms from a 1,10-phenanthroline ligand and six O atoms from the carboxyl-ate groups of five 4-methoxy-benzoate ligands in a distorted square-anti-prismatic geometry. All six 4-methoxy-benzoate ligands act in a bidentate mode, two coordinating to one Tb center each and the other four bridging two Tb centers [Tb?Tb separation = 4.3144?(6)?Å]. In the crystal, inter-molecular ?-? inter-actions between the aromatic rings of 1,10-phenanthroline and 4-methoxy-benzoate ligands [centroid-centroid distance = 3.742?(9)?Å] link two mol-ecules into a centrosymmetric dimer. Weak inter-molecular C-H?O hydrogen bonds help to consolidate the crystal packing. PMID:21577758
In the title compound, C(21)H(14)ClN(3)O(5), an intra-molecular C-H?O hydrogen bond generates an S(7) ring motif and the furan and pyrazole rings are almost coplanar, making a dihedral angle of 1.98?(5)°. The pyrazole ring is inclined at dihedral angles of 47.59?(4) and 7.27?(4)° to the chloro-phenyl and methoxy-phenyl groups, respectively. The nitro group is almost coplanar to its attached furan ring [dihedral angle = 2.03?(12)°]. In the crystal, inter-molecular C-H?O hydrogen bonds link the mol-ecules into a three-dimensional network. The crystal structure also features short inter-molecular O?N [2.8546?(12)?Å] and Cl?O [3.0844?(9)?Å] contacts as well as aromatic ?-? stacking inter-actions [centroid-centroid distance = 3.4367?(6)?Å]. PMID:21579120
We present HST WFPC2 and ground-based images of the low surface brightness dwarf Irr/Sph galaxy KKR~25 in Draco. Its colour-magnitude diagram shows red giant branch stars with the tip at I = 22.32 mag, and the presence of some blue stars. The derived true distance modulus, 26.35 \\+- 0.14 mag, corresponds to linear distances of KKR25 from the Milky Way and from the Local Group centroid of 1.86 and 1.79 Mpc, respectively. The absolute magnitude of the galaxy, M_V = -10.48, its linear diameter (0.54 Kpc) and central surface brightness (24.0 +- 0.2 mag\\arcsec^2) are typical of other dIrr/dSphs in the Local Group. Being situated just beyond the radius of the zero-velocity surface of the Local Group, KKR25 moves away from the LG centroid at a velocity of V_{LG} = + 72 km/s.
There exist several high-order sandwich panel theories, most notably, the first to be introduced high-order sandwich panel theory (HSAPT) assumes a constant shear stress in the core. Recently, the extended high-order sandwich panel theory (EHSAPT) was introduced, its novelty being that it allows for three generalized coordinates in the core (the axial and transverse displacements at the centroid of the core, and the rotation at the centroid of the core) instead of just one (shear stress in the core) of the earlier theory. In this paper, the EHSAPT formulation for predicting the critical wrinkling load is presented for a simply supported sandwich of general asymmetric construction. The cases of (i) applying the loading just on the face sheets with a linear core assumption and (ii) applying ...
We report the energy dependence of normal branch oscillations (NBOs) in Scorpius X-1, a low-mass X-ray binary (LMXB) Z-source. Three characteristic quantities (centroid frequency, quality factor and fractional root-mean-squared (rms) amplitude) of a QPO signal as functions of photon energy are investigated. We found that the NBO centroid frequency decreases with increasing photon energy when it is below 6-8 keV and turns positively correlated with photon energy at the higher-energy side. The rms amplitude increases significantly with the photon energy below 13 keV, and then flats out in the energy band of 13-20 keV. There is no clear dependence on photon energy for the quality factor. Based on these results, we suggest that the NBO originates mainly from the transition layer.
Abstract A three-dimensional geometric morphometric approach was employed to examine shape variation in laser-scan generated models of lower second molars and its relationship to diet in a sample of 9 extant and 16 extinct platyrrhine genera. Principal component analysis of twenty-three x,y,z landmarks describing the occlusal table and sidewalls showed that dental relief was the main contributing factor to variation along the first axis. Discriminant function analysis (DFA) of PC 1 scores and centroid size accurately classified extant platyrrhines according to dietary preference; however, without centroid size, the DFA was less successful. Within this framework, most of the fossil platyrrhines, including specimens from Patagonia, Colombia, Brazil, and the Caribbean, were predicted to have ...
In the title compound, C34H32N2O8, one of the pyrrolidine rings in the pyrrolizidine ring system adopts a twist conformation, whereas the other ring adopts an envelope conformation (C atom as flap). The five-membered ring in the indene ring system and the fused furan ring also adopt envelope conformations (C and O atoms as flaps, respectively). The ?-lactam ring makes dihedral angles of 23.41?(2) and 25.98?(2)°, respectively, with the attached methoxyphenyl and phenoxy rings. The molecular conformation is stabilized by an intramolecular O—H?N hydrogen bond, generating an S(5) motif. In the crystal, molecules are linked into C(12) chains running along the a axis by C—H?O hydrogen bonds. The structure is further consolidated by weak intermolecular C—H?? and ?–? interactions [centroid–centroid distance = 3.7987?(14)?Å].
The authors employ Forward Scattering Particle Image Velocimetry (FSPIV) to measure all three components of the velocity of a buoyant polystyrene particle in oil. Unlike conventional particle image velocimetry (PIV) techniques, FSPIV employs coherent or partially coherent back illumination and collects the forward scattered wavefront; additionally, the field-of-view is microscopic. Using FSPIV, it is possible to easily identify the particle`s centroid and to simultaneously obtain the fluid velocity in different planes perpendicular to the viewing direction without changing the collection or imaging optics. The authors have trained a neural network to identify the scattering pattern as function of displacement along the optical axis (axial defocus) and determine the transverse velocity by tracking the centroid as function of time. They present preliminary results from Mie theory calculations which include the effect of the imaging system. To their knowledge, this is the first work of this kind; preliminary results are encouraging.
In the title compound, [Cd(C(7)H(7)S)(2)(C(13)H(14)N(2))](n), the unique Cd(II) ion, located on a twofold rotation axis, is coordinated by two S atoms and two N atoms in a slightly distorted tetra-hedral environment. Symmetry-related Cd(II) ions are linked via bridging 1,3-di-4-pyridylpropane ligands, forming a zig-zag chain-structure parallel to [001]. In the crystal structure, there are weak intra-chain ?-? stacking inter-actions between benzene rings, with a centroid-centroid distance of 3.825?(7)?Å, and pairs of chains are inter-digitated with respect to the 4-methyl-benzene-thiol-ate groups. PMID:21582384
In the centrosymmetric title compound, [Cu2(C10H8O4)Cl2(C10H8N2)2(H2O)2]·2H2O, the CuII atom is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a chelating 2,2?-bipyridine ligand, one O atom from a 1,4-phenylenediacetate ligand, one Cl atom and one water molecule. The 1,4-phenylenediacetate ligand, lying on an inversion center, bridges two CuII atoms. In the crystal, O—H?O and O—H?Cl hydrogen bonds and ?–? interactions between the pyridine rings [centroid–centroid distance = 3.740?(5)?Å] link the complex molecules and uncoordinated water molecules into a three-dimensional network.
We report the energy dependence of normal branch oscillations (NBOs) in Scorpius X-1, a low-mass X-ray binary Z-source. Three characteristic quantities (centroid frequency, quality factor, and fractional root-mean-squared (rms) amplitude) of a quasi-periodic oscillation signal as functions of photon energy are investigated. We found that, although it is not yet statistically well established, there is a signature indicating that the NBO centroid frequency decreases with increasing photon energy when it is below 6-8 keV, which turns out to be positively correlated with the photon energy at the higher energy side. In addition, the rms amplitude increases significantly with the photon energy below 13 keV and then decreases in the energy band of 13-20 keV. There is no clear dependence on photon energy for the quality factor. Based on these results, we suggest that the NBO originates mainly in the transition layer.
Plume descriptors, constituting the first four moments of the concentration distribution, have been obtained for a Gaussian deposition plume model. Analytical expressions for the plume descriptors (centroid, variance, skewness and kurtosis) for point source ground-level and elevated releases are derived from a solution to the advection-diffusion equation accounting for deposition at the ground surface. A sensitivity analysis has been carried out to investigate the effect of deposition velocity and source height on the plume descriptors. For the particular case of a fully reflected Gaussian plume from a ground-level source, the centroid and the standard deviation have been found to vary as square root of downwind distance whereas skewness and kurtosis are independent of downwind distance, the approximate values being 0.995 for skewness and 3.87 for kurtosis.
The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydro-thermally. The binuclear complex mol-ecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C-C bond. The Pb(II) ion is hepta-coordinated by the O atom of one water mol-ecule, two oxalate O atoms, two nitrate O atoms and two 2,2'-bipyridine N atoms, forming an irregular coordination environemnt. Inter-molecular O-H?O hydrogen bonds between water mol-ecules and oxalate and nitrate ions result in the formation of layers parallel to (010). ?-? inter-actions between pyridine rings in adjacent layers, with centroid-centroid distances of 3.584?(2)?Å, stabilize the structural set-up. PMID:23125622
In the title compound, [Fe(2)(NCS)(4)(H(2)O)(6)]·3C(10)H(8)N(6), the centrosymmetric dinuclear complex contains two Fe(II) ions bridged by two aqua ligand O atoms, forming a four-membered ring. The slightly distorted octa-hedral coordination environment of the two Fe(II) ions is completed by two monodentate aqua ligands and two thio-cyanate ligands. One of the 1,4-bis-(4H-1,2,4-triazol-4-yl)benzene mol-ecules lies across an inversion center. In the crystal, O-H?N hydrogen bonds connect the components, forming a two-dimensional network parallel to (011). In addition, ?-? stacking inter-actions involving the benzene and triazole rings, with centroid-centroid distances in the range 3.502?(5)-3.787?(6)?Å, connect the two-dimensional hydrogen-bonded network into a three-dimensional network. PMID:22904716
In the centrosymmetric title compound, [Cu(2)(C(10)H(8)O(4))Cl(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, the Cu(II) atom is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a chelating 2,2'-bipyridine ligand, one O atom from a 1,4-phenyl-enediacetate ligand, one Cl atom and one water mol-ecule. The 1,4-phenyl-enediacetate ligand, lying on an inversion center, bridges two Cu(II) atoms. In the crystal, O-H?O and O-H?Cl hydrogen bonds and ?-? inter-actions between the pyridine rings [centroid-centroid distance = 3.740?(5)?Å] link the complex mol-ecules and uncoordinated water mol-ecules into a three-dimensional network. PMID:22904766
In the title compound, {[Cd(C(9)H(5)BrO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cd(II) atom has a distorted octa-hedral coordination geometry. Two N atoms from two 4,4'-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxyl-ate O atoms from three 3-bromo-2-(carboxyl-atometh-yl)benzoate (bcb) ligands and one O atom from a water mol-ecule. The bipy and bcb ligands link the Cd(II) atoms into a three-dimensional network. O-H?O hydrogen bonds and ?-? inter-actions between the pyridine and benzene rings [centroid-centroid distance = 3.736?(4)?Å] are present in the crystal. PMID:22904738
In the title mol-ecular salt, (CH(6)N(3))(1.30)[Zn(H(2)O)(6)](0.35)[Zn(C(7)H(4)NO(4))(3)](2), the Zn(II) atom (site symmetry 3) in the anion is coordinated by three N,O-bidentate 3-carb-oxy-pyridine-2-carboxyl-ate monoanions to generate a fac-ZnN(3)O(3) octa-hedral coordination geometry. The guanidinium cation (the C atom has site symmetry 3) and the octa-hedral hexa-aqua-zinc(II) dication (the Zn(2+) cation has site symmetry -3) are occupationally disordered in a 1.30:0.35 ratio. In the crystal, the components are linked by O-H?O and N-H?O hydrogen bonds to generate infinite (001) sheets. Weak aromatic ?-? stacking [centroid-centroid distance = 3.797?(8)?Å] is also observed in the crystal. PMID:22904714
Mol-ecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetra-dentate Schiff base anion in the basal plane and one water mol-ecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intra-molecular C-H?N and inter-molecular C-H?O and O-H?O hydrogen-bonding inter-actions, as well as C-H?? and ?-? stacking inter-actions [shortest centroid-centroid distance = 3.799?(8)?Å and inter-planar distance = 3.469?(2)?Å] are observed. PMID:22904737
The title compound, C(20)H(14)N(4)OS·0.5CH(2)Cl(2)·H(2)O, contains 1,10-phenanthroline and benzoyl fragments that adopt cisoid and transoid conformations respectively, with respect to the S atom. In the crystal, mol-ecules are linked by inter-molecular O-H?O, O-H?N, N-H?O and C-H?O hydrogen bonds, forming chains along [011]. Weak C-H?? and slipped ?-? stacking inter-actions [centroid-centroid distances = 3.715?(3), 3.684?(3) and 3.574?(2)?Å] are also observed. In addition to an ordered water mol-ecule of solvation, there is a disordered dichloro-methane solvent mol-ecule which was difficult to model correctly. The contributions to the electron density for this mol-ecule was removed using the SQUEEZE procedure in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155]. PMID:21754783
In the title compound, [Fe(C(20)H(21)NPS)(C(17)H(14)PS)]·CH(2)Cl(2), both cyclo-penta-dienyl (Cp) rings constituting the ferrocene unit are substituted by a sulfur-protected diphenyl-phosphine. One of the Cp ligands is additionally substituted by a dimethyl-amino-methyl group causing the chirality of the mol-ecule. Surprisingly, although the synthetic procedure yielded the title compound as a racemic mixture, the reported crystal is enanti-omerically pure with the R absolute configuration. The dimethyl-amino group is exo with respect to the Cp ring. Both diphenyl-thio-phosphine groups are trans with respect to the centroid-Fe-centroid direction. Weak intra-molecular C-H?S and C-H?? inter-actions between symmetry-related mol-ecules are observed. The contribution of the disordered solvent was removed from the refinement using SQUEEZE in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155]. PMID:22719348
The asymmetric unit of the title compound, 3C10H8N2·2C7H7NO2, consists of three molecules of 4,4?-bipyridine (bpy) and two molecules of 3-aminobenzoic acid (bza). Two molecules of bza and two molecules of bpy are connected via O—H?N, N—H?N and N—H?O hydrogen bonds, forming forming infinite double-stranded zigzag chains along the c axis. The third molecule of bpy is linked to the chain by weak C—H?O interactions. Adjacent chains are linked via ?–? interactions [centroid–centroid distances = 3.759?(3)–3.928?(3)?Å] involving the pyridine rings of bpy molecules, resulting in a sheet-like structure parallel to (100). These sheets are stacked via C—H?? interactions, resulting finally in the formation of a three-dimensional supramolecular structure.
In the title complex, [Cu(C2HCl2O2)2(C12H8N2)(H2O)], the CuII ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 1.994?(3) and 2.027?(3)?Å] and two O atoms from dichloroacetate ligands and a water molecule [Cu—O = 1.971?(2) and 1.939?(2)?Å]. One O atom from another dichloroacetate ligand occupies the apical positon [Cu—O = 2.152?(3)?Å]. Intermolecular O—H?O hydrogen bonds link the molecules into centrosymmetric dimers. The crystal packing also exhibits weak intermolecular C—H?O hydrogen bonds, ?–? interactions [centroid–centroid distance = 3.734?(2)?Å] and short intermolecular Cl?Cl contacts [3.306?(2) and 3.278?(2)?Å].
In the title complex, [Cu(C(2)HCl(2)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu-N = 1.994?(3) and 2.027?(3)?Å] and two O atoms from dichloro-acetate ligands and a water mol-ecule [Cu-O = 1.971?(2) and 1.939?(2)?Å]. One O atom from another dichloro-acetate ligand occupies the apical positon [Cu-O = 2.152?(3)?Å]. Inter-molecular O-H?O hydrogen bonds link the mol-ecules into centrosymmetric dimers. The crystal packing also exhibits weak inter-molecular C-H?O hydrogen bonds, ?-? inter-actions [centroid-centroid distance = 3.734?(2)?Å] and short inter-molecular Cl?Cl contacts [3.306?(2) and 3.278?(2)?Å]. PMID:21581478
In the cation of the title compound, C18H23N2 +·C7H7O4S?·H2O, one ethyl group of the diethylamino unit is disordered over two sets of sites in a 0.665?(6):0.335?(6) ratio. The styrylpyridinium unit is nearly planar, with a dihedral angle between the pyridinium and benzene rings of 4.27?(8)°. In the crystal, the anion ring is almost perpendicular to the aromatic rings of the cation; the sulfonate-substituted benzene ring forms dihedral angles of 89.60?(8) and 89.37?(8)°, respectively, with the pyridinium and benzene rings of the cation. In the crystal, the three components are linked into a three-dimensional network by O—H?O and C—H?O hydrogen bonds. ?–? interactions with centroid–centroid distances of 3.6999?(9) and 3.7106?(9)?Å are also present. PMID:19589679
In the title compound, C22H23BrN4O4S2, the benzene rings bridged by the sulfonamide group are tilted relative to each other by 68.9?(1)° and the dihedral angle between the sulfur-bridged pyrimidine and benzene rings is 69.7?(1)°. The molecular conformation is stabilized by a weak intramolecular ?–? stacking interaction between the pyrimidine and the 4-methylbenzene rings [centroid–centroid distance = 3.934?(2)?Å]. The morpholine ring adopts a chair conformation and is disordered over two positions with an occupancy ratio of 0.853?(6):0.147?(6). In the crystal, molecules are linked by N—H?O hydrogen bonds into chains extending along the a axis and further, through C—H?N and C—H?O interactions, into a three-dimensional supramolecular structure.
Los Alamos National Laboratory has proposed several CW-proton-beam facilities for production of tritium or transmutation of nuclear waste with beam-current densities greater than 5 mA/mm{sup 2}. The primary beam-diagnostics-instrumentation requirement for these facilities is provision of sufficient beam information to understand and minimize beam-loss. To accomplish this task, the beam-diagnostics instrumentation must measure beam parameters such as the centroids and profiles, total integrated current, and particle loss. Noninterceptive techniques must be used for diagnosis of high-intensity CW beam at low energies due to the large quantity of power deposited in an interceptive diagnostic device by the beam. Transverse and longitudinal centroid measurements have been developed for bunched beams by measuring and processing image currents on the accelerator walls. Transverse beam-profile measurement-techniques have also been developed using the interaction of the particle beam with the background gases near the beam region. This paper will discuss these noninterceptive diagnostic Techniques.
In the title complex, [Co(CO3)(C12H12N2)2]Br·3H2O, the CoIII cation has a distorted octahedral coordination environment. It is chelated by four N atoms of two different 5,5?-dimethyl-2,2?-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water molecules are disordered and their H atoms were not located, there are typical O?O distances between 2.8 and 3.0?Å, indicating O—H?O hydrogen bonding. The crystal packing is consolidated by C—H?O and C—H?Br hydrogen bonds, as well as ?–? stacking interactions between adjacent pyridine rings of the dmbpy ligands, with centroid–centroid distances of 3.694?(3) and 3.7053?(3)?Å.