Energy Technology Data Exchange (ETDEWEB)

The DOE Working Group for an Assessment of Coal-Gasification Research Needs (COGARN - coal gasification advanced research needs) has reviewed and evaluated US programs dealing with coal gasification for a variety of applications. Cost evaluations and environmental-impact assessments formed important components of the deliberations. We have examined in some depth each of the following technologies: coal gasification for electricity generation in combined-cycle systems, coal gasification for the production of synthetic natural gas, coal gasifiers for direct electricity generation in fuel cells, and coal gasification for the production of synthesis gas as a first step in the manufacture of a wide variety of chemicals and fuels. Both ...

Energy Technology Data Exchange (ETDEWEB)

This article puts the case for coal fired combined cycle gas turbine (CCGT) power plants. The need to gasify the coal for the CCGT, use of fluidised bed combustors or gasification systems, the difference in prices of coal and natural gas, and coal and natural gas reserves are discussed. (UK)

Energy Technology Data Exchange (ETDEWEB)

As oil supplies diminish, Britain will have to rely more and more on coal as one of the energy alternatives. To burn coal cleanly and efficiently coal will have to be converted into gas and liquid fuels to replace natural gas and oil. The research and development programme of the National Coal Board is directed towards meeting these new challenges. This paper outlines some of the Coal Board's current projects in the fields of industrial combustion, power generation, domestic combustion, coal gasification and coal liquefaction. 10 figs.

Energy Technology Data Exchange (ETDEWEB)

Environmental studies in slip-stream process development units at SCGP-1, Shell's advanced coal gasification demonstration plant, located near Houston, Texas, have demonstrated that the gas and water effluents from the Shell Coal Gasification Process (SCGP) are environmentally benign on a broad slate of coals. This report presents the results of those environmental studies. It contains two major subjects, which describe, respectively, the experiments on gas treating and the experiments on water treating. Gas treatment focused on the performance of aqueous methyldiethanolamine (MDEA) and sulfinol-M. 8 refs., 24 figs., 13 tabs.

Energy Technology Data Exchange (ETDEWEB)

The paper discusses the status of coal as a raw material and energy source. After referring to coal preparation and the costs it involves the author deals with coal/liquid suspensions and their fueling uses. Access is given to different aspects concerning the use of coal for electric power and heat generation. They include pollution abatement measures, economic analyses and fuel engineering in the case of coal. Further sections are dedicated to upgrading procedures such as the gasification, liquefaction and coking of coal. A bibliography informs the reader about further publications available on the subject. (HAG).

Energy Technology Data Exchange (ETDEWEB)

Short communication

Energy Technology Data Exchange (ETDEWEB)

For high-efficiency coal gasification, investigations were given on effect of coal chars with different conversion rates on coal gasification reactivity. In coal gasification, reactivity of char after pyrolysis governs the efficiency. The reference char conversion in CO2 gasification of coal (weight loss) changes linearly in the initial stage of the reaction, but the reactivity declines as the end point is approached. Char surface area is as large as 400 m{sup 2}/g in the initial stage with the conversion at 20%, but it decreases in the final stage. This phenomenon relates closely with changes in pore size and crystalline structure. Change in the Raman value R which shows incompleteness of char graphite structure and amorphous carbon ratio suggests that an active portion with high reactivity is ...

Energy Technology Data Exchange (ETDEWEB)

The increasing price differential between natural gas and coal will create a demand for technology that can allow the displacement of natural gas with coal in power plants. Coal gasification is the standard approach suggested to allow coal to displace natural gas. However, the relatively high capital investment required for coal gasification will require fuel cost differentials higher than those anticipated in the near term before coal gasification replaces natural gas. One way of achieving shorter term displacement of natural gas by coal would be to develop technology that would allow coal to be used as the heat source for the endothermic reforming of natural gas. In a natural gas-fired combined cycle power plant, the endothermic heat of reforming, which ...

Science.gov (United States)

In addition to an executive summary and glossary, the following sections are included: Clean Boiler Fuel Demonstration Plant; Development of Coal Feeders for Coal Gasification Operations; Development of a Continuous Dry Coal Screw Feeder; Coal Feeder Development Program; Engineering and Technical Support; and Technical Assistance Services. (EJH)

Energy Technology Data Exchange (ETDEWEB)

The Power Systems Development Facility (PSDF) is a joint Department of Energy/Industry sponsored engineering-scale facility for testing advanced coal-based power generation technologies. High temperature, high pressure gas cleaning is critical to many of these advanced technologies. Barrier filter elements that can operate continuously for nearly 9000 hours are required for a successful gas cleaning system for use in commercial power generation. Since late 1999, the Kellogg Brown & Root Transport reactor at the PSDF has been operated in gasification mode. This paper describes the test results for filter elements operating in the Siemens-Westinghouse particle collection device (PCD) with the Transport reactor in gasification mode. Operating conditions in the PCD have varied during gasification operation as described elsewhere in these proceedings (Martin et al, 2002).

Energy Technology Data Exchange (ETDEWEB)

The relationship between coal properties and liquefaction or gasification characteristics was analyzed by using the analysis and test results and liquefaction characteristics in the coal data base. On liquefaction reaction, the close relation between an oil yield and coal constituent composition or a coal rank is well-known. Various multivariable regression analyses were conducted by using 6 factors as variables such as calorific value, volatile component, O/C and H/C atomic ratios, exinite+vitrinite content and vitrinite reflectance, and liquefaction characteristics as variate. On liquefaction characteristics, the oil yield of dehydrated and deashed coals, asphaltene yield, hydrogen consumption, produced water and gas quantities, and oil+asphaltene yield were predicted. The theoretical gasification efficiency of each specimen was calculated ...

Energy Technology Data Exchange (ETDEWEB)

Investigation of co-gasification of biomass-coal blends in oxygen-containing atmosphere was carried out in a pressurized fluidized bed gasifier. Different biomass materials including wood and energy crop were used in the study, whereas the coal used was in bituminous rank from UK, The gasifier used was a Laboratory Development Unit (LDU) with an inner diameter of 144 mm. The operation temperature and pressure were varied in the investigation. The research was part of the European Union's Joule Ill clean coal technology programme. The study was focused on possible synergies in the thermochemical treatment of the fuel blends. The char formed was examined. The tar produced in the process was analyzed. The environmentally concerned nitrogen compounds emitted from the process were detected. Interesting synergies were observed in the experimental study. The blends of the fuels and their char formed ...

Energy Technology Data Exchange (ETDEWEB)

A Lurgi baseline study was requested by the DOE/GRI Operating Committee of the Joint Coal Gasification Program for the purpose of updating the economics of earlier Lurgi coal gasification plant studies for the production of substitute natural gas (SNG) based on commercially advanced technologies. The current study incorporates the recent experience with large size Lurgi plants in an effort to improve capital and operating costs of earlier plant designs. The present coal gasification study is based on a mine mouth plant producing 250 billion Btu (HHV) per day of SNG using the Lurgi dry bottom coal gasification technology. A Western subbituminous coal was designated as the plant food, obtained from the Rosebud seam at Colstrip, Montana. This study presents the detailed description of an integrated ...

British Library Electronic Table of Contents (United Kingdom)

In energy industries, it is always of difficulty to produce high heat value(HHV) gas continuously using pulverized coal. In this paper, a new type furnace for partitioned alternative gasification using pulverized coal is developed, in which the oxidation and reduction reaction occur alternatively with the dropping of pulverized coal and finally HHV gas could be continuously obtained at the reduction zone exit and low heat value(LHV) gas at the oxidation zone exit. Furthermore, the gasification characteristics and their factors in furnace are numerically simulated under two dimensional model with a self-coded program, based on heat, mass and energy transfer as well as reaction principles. It is found that the producing rate of HHV gas is 1.10Nm3/kg with heat value of 11.72MJ/Nm3, however, t...

Energy Technology Data Exchange (ETDEWEB)

With relation to the coals delivered as common samples in the coal fundamental technology development project, an experimental study was conducted on agglomeration characteristics and reaction characteristics in the fluidized-bed coal gasifier. For the experiment, used was a fluidized bed gasifier inserted with a cone-shape dispersion plate with a nozzle in the center. After raising the temperature of the gasifier up to 773K, gasification was conducted sending to the gasifier air from the nozzle and steam from the dispersion plate. The mean particle diameter and gas concentration of chars were measured till the temperature reaches 1373K. As a result of the experiment, it was confirmed that the carbon conversion ratio increases with a decrease in coalification degree of the coal. Moreover, influence of the coal kind was markedly observed at the grid zone of the ...

Energy Technology Data Exchange (ETDEWEB)

The four mines supplying the Sasol-2 plant at Secunda, South Africa are approaching their full production potential of 29 million t/year. Current production is 27.7 million t/year of coal for gasification and steam raising. Three mining methods are employed: bord and pillar, longwall and continuous mining. Details are given of the mining operations and machinery. A 43 km overland conveyor transports the coal to the Sasol plant stockpile.

Energy Technology Data Exchange (ETDEWEB)

Concepts involving combined gas-turbine/steam-turbine power-generation plants, in which the fuel gas for the gas turbine is produced via the gasification of coal, are now extremely advanced. This technology already permits efficiencies of around 50% current development targets view 65% as achievable. In conventional technology, efficiencies are tied to conditions, such as air and cooling-water temperatures, at the particular location. In combined-cycle power plants, the properties of the fuel coal also play an important part. There are, in face, coals which can be more advantageously used in a combined-cycle power plant than in a conventional one. These differences, combined with advantageous concepts for coal-fired combined-cycle power-generating plants, are presented and analyzed. Particular attention is devoted to individual losses occurring at coal ...

Energy Technology Data Exchange (ETDEWEB)

For IGCC, the primary investment is too high due to the demand of high gasification efficiency. For PFBCC, the thermal efficiency is too low due to the relatively low turbine inlet temperature and the hot working medium of the gas turbine is not easy to clean. A new scheme is proposed for coal fired combined cycle to overcome the main drawbacks of IGCC and PFBCC. The research targets are developing a new cycle construction of coal fired combined cycle to raise the efficiency and reduce the primary investment. Actually, the new scheme is a synthesis of some existing proposals. It adopts partial gasification to reduce the primary investment of the gasification equipment. The un-gasified surplus solid is then fed to a pressurized fluidized bed boiler, but adopting Curtiss Wright type external combustion to lower the ash content in the working medium. The gas fuel from the partial ...

Energy Technology Data Exchange (ETDEWEB)

In relation to considerations on composition of gas produced by coal gasification, the HYCOL hydrogen generation process data were analyzed. From the fact that CO concentration (Y) decreases linearly with CO2 concentration (X), element balance of gasification of reacted coal was used to introduce a reaction analysis equation. The equation includes a term of oxygen excess {Delta}(amount of oxygen consumed for combustion of CO and H2 in excess of the theoretical amount), derived by subtracting the stoichiometric oxygen amount used to gasify coal into CO and H2 from the consumed oxygen amount. The {Delta} can be used as a reference to oxygen utilization efficiency. An equation for the {Delta} was introduced. Also introduced was a term for steam decomposition amount derived by subtracting the generated steam from the supplied steam. These terms may be used as a clue to permeate into the ...

Energy Technology Data Exchange (ETDEWEB)

The first part of the conference dealt with environmental effects of using coal. Papers dealt with the use of fly ash in agriculture and its effect on plant growth; the effect of airborne emissions on fish and wildlife resources, on watersheds, and on airsheds; the effects of surface mining on the ecology; blast effects; and health hazards associated with coal. The session on policy studies addressed the issue of cost of synthetic fuels and discussed the state and federal pollution regulations on burning coal and waste disposal. The session on combustion presented papers on atmospheric and pressurized fluidized-bed combustion for industrial and utility boilers. It also included papers on MHD power plants, coal-oil and coal-water mixtures, emission characterization and control, and catalytic combustors. The design of gasification plants, reaction kinetics, ...

Energy Technology Data Exchange (ETDEWEB)

The coal-fired combined cycle with partial gasification and fluidized bed combustion (PGFBC-CC), also referred to as a hybrid cycle, has advantages of staged energy conversion and utilization, which can attain high thermal efficiency with low emissions. Four kinds of PGFBC-CC are studied in this paper, two based on pressurized fluidized bed combustion (PFBC) and two on atmospheric fluidized bed combustion (AFBC). Thermal performance calculations and parametric analyses were performed. On the basis of the results, from the above analyses, the best integration system for China is suggested. In addition, a preliminary exergetic analysis is carried out for three of the PGFBC-CC variants.

Science.gov (United States)

The American Natural Resources System has been attempting to obtain the financing commitments and regulatory approvals necessary to construct the nation's first commercial-scale coal-gasification plant. It would employ the same technology as Sasol plants of South Africa and much of the same hardware as the Sasol II plant now approaching completion. But instead of converting the gas that comes out of the gasifier vessels into liquid hydrocarbons, the proposed plant would upgrade the gas to a Btu-content equivalent to that of natural gas. It could be mixed, transported, and utilized as a constituent part of the natural gas stream. The plant would be located in North Dakota and would utilize coal as the feedstock. North Dakota lignite gasifies very efficiently and, since the plant would be located at the mine mouth, the low-Btu quality of the coal is not a particularly adverse factor. The gas produced by the plant ...

International Nuclear Information System (INIS)

This paper reports that there are four combustion technologies upon which U.S. electric utilities are expected to rely for the majority of their future power generating needs. These technologies are pulverized coal- fired combustion (PC); coal-fired fluidized bed combustion (AFBC); coal gasification, combined cycle systems (CGCC); and natural gas-fired combined cycle systems (NGCC). The engineering and economic parameters which affect the choice of a technology include capital costs, operating and maintenance costs, fuel costs, construction schedule, process risk, environmental and site impacts, fuel efficiency and flexibility, plant availability, capacity factors, timing of startup, and the importance of utility economic and financial factors.

Energy Technology Data Exchange (ETDEWEB)

Coal direct chemical looping (CDCL) substitutes the gasification process in syngas chemical looping (SCL), thus eliminating the need for higher oxygen consumption. In this study, operating conditions are assessed for CDCL and SCL, directed towards hydrogen production from coal. The main objective is to increase the overall H{sub 2}/CO{sub 2} ratio for a given amount of coal, based on the various conditions. The operating variables considered as part of a resource optimization analysis include: (i) inlet conditions to the primary reactors, (ii) minimum resource requirements (air, steam and iron oxide), (iii) hydrogen-to-component ratios, and (iv) effect of coal carrier gas. The results suggest that CDCL has a higher hydrogen-to-CO{sub 2} ratio than SCL along with advantages such as low overall resource requirements (steam and air) and fewer intermediate processes. The ...

International Nuclear Information System (INIS)

A chemical-looping process is proposed for the clean combustion of solid fuels for electric power or heat generation. The process is based on coal gasification with CO_2 to produce CO. The CO then reduces CaSO_4, which is used as an oxygen carrier, in a separate reactor to give CaS and CO_2. A portion of the CO_2 is recycled for the gasification stage and the rest can be sent for sequestration. The CaS is sent to another reactor for oxidation with air and to generate heat or power. The overall thermal effect is the same as direct combustion, but separation of CO_2 and other pollutants, such as sulphur, is achieved. In comparison with conventional chemical-looping combustion of natural gas, much less water is present in the CO_2 product, and hence the loss of heat energy and corrosion of the fuel-reactor system can be reduced.

Energy Technology Data Exchange (ETDEWEB)

Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] ...

Energy Technology Data Exchange (ETDEWEB)

An Fe-19Cr-8Al-0.5Hf alloy has been roll bonded to Alloy 800 to form a protective clad material suitable for use in coal conversion atmospheres. The commercial producibility of both the Fe-19Cr-8Al-0.5Hf alloy and the clad composite has been demonstrated. The clad composite has been shown to exhibit resistance to sulfidation in high sulfur, coal gasification atmospheres low Btu for 2000 hrs at 1800/sup 0/F (1255K). The FeCrAlHf alloy must be preoxidized in the absence of sulfur to form fully protective alumina scales on all surfaces. Useful life of the composite at temperatures of 1400 to 2000/sup 0/F (1033 to 1366K) is governed by reactions at the FeCrAlHf clad alloy 800 interface. The rate of interdiffusion decreases with increasing Ni content and a high Ni alloy such as RA333 appears to be a better substrate than Alloy 800 for a FeCrAlHf composite. The mechanical properties of the clad composite have been evaluated at ...

Energy Technology Data Exchange (ETDEWEB)

Large amounts of US public funds are deviated to energy-related R and D conflicts with the country's simultaneous attempts to control inflation and to limit federal government expansion. Congress must concentrate the funds at its disposal upon a manageable number of energy technologies - those most likely to improve the supply side of the domestic energy equation while maintaining an adequate return on investment. An examination of a wide array to technology alternatives concludes that (1) the development of unconventional gas would yield a large return while requiring only limited federal R and D support, (2) combined-cycle coal gasification and the manufacture of low- and medium-Btu gas need relatively little government aid and produce moderate returns, (3) although requiring limited support, energy from municipal solid waste (MSW) yields a small return, and (4) high-Btu coal gasification ...

Energy Technology Data Exchange (ETDEWEB)

The goal of this project is to develop a bench-scale procedure to produce clean, desulfurized, premium-quality chars from the Illinois basin coals. This goal is achieved by utilizing the effective capabilty of smectites in combination with methane to manipulate the char yields. The major objectives are: to determine the optimum water- ground particle size for the maximum reduction of pyrite and minerals by the selective-bitumen agglomeration process; to evaluate the type of smectite and its interlamellar cation which enhances the premium-quality char yields; to find the mode of dispersion of smectites in clean coal which retards the agglomeration of char during mild gasification; to probe the conditions that maximize the desulfurized clean-char yields under a combination of methane+oxygen or helium+oxygen; to characterize and accomplish a material balance of chars, liquids, and gases produced during mild ...

Science.gov (United States)

The Committee on Interior and Insular Affairs issued the report on a bill to establish a national program for research, development, and demonstration in fuels and energy and for the coordination and financial supplementation of Federal energy research and development; to establish development corporations to demonstrate technologies for shale oil development, advanced power cycle development, geothermal steam development, and coal liquefaction and gasification development; to authorize and direct the Secretary of the Interior to make mineral resources of the public lands available for the development conporations. Comments from governmental agencies on the bill are published. (MCW)

Energy Technology Data Exchange (ETDEWEB)

In relation to coal gasification and combustion under high pressure as highly efficient coal utilization, the effect of total pressure and sintering on the SO2 capture ability of Ca-ion exchanged coal and other desulfurizing agents were studied. In experiment, specimens were filled into a small pressurized reactor to heat them under high-pressure N2 atmosphere. After the completion of combustion reaction of char at 850{degree}C, SO2, CO2 and CO gases were measured at an outlet while flowing SO2/N2. As the experimental result, all of the S content in Ca-ion exchanged coal was not absorbed by Ca content in coal during pyrolysis and combustion, resulting in discharge of 36% of the S content. Since Ca-ion exchanged coal is fast in combustion reaction, most of the S content was desulfurized by coal ash. The ash content ...

Energy Technology Data Exchange (ETDEWEB)

A 8.4 t/d pilot plant was completed in November 1994. Experimental operation for continuous tests have been carried out since December 1994. Two kinds of Indonesian sub-bituminous coals and an Australian lignite were upgraded and slurrified by the end of 1995. Typical pilot test results, such as coal concentration of upgraded sub-bituminous CWM of 65% and 4,700 kcal/kg heating value, were better than the authors expected. And subsequent combustion test in a 200 kg/h furnace was also successfully completed, with results showing very good combustibilities. This R and D is now in its final year, and the authors are conducting combustion tests on a big burner and gasification test, which will be carried out until March 1996. The test results from the pilot plant so far confirm the validity and economic feasibility of the upgrading and CWM production technology to promote the use of low rank coals (LRCs). ...

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion is an indirect combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The feasibility of using NiO as an oxygen carrier during chemical-looping combustion of coal has been investigated experimentally at 800-960{degree}C in the present work. The experiments were carried out in a fluidized bed, where the steam acted as the gasification-fluidization medium. Coal gasification and the reaction of oxygen carrier with the water gas take place simultaneously in the reactor. The oxygen carrier particles exhibit high reactivity above 900{degree}C, and the dry basis concentration of CO{sub 2} in the exit gas of the reactor is nearly 95%. The flue gas composition as a function of the reactor temperature and cyclic reduction number is discussed. At 800-960{degree}C, the dry basis concentration of CO{sub 2} in the flue gas presents a monotonously increasing trend, ...

Energy Technology Data Exchange (ETDEWEB)

Advanced coal-fired combined-cycle power systems under development and demonstration have the potential to increase generating efficiency to approach 50%, reduce the cost of electricity by up to 20%, and meet stringent standards on emissions of SO{sub x}, NO{sub x}, fine particulates, and air toxic metals. Integrated gasification combined cycle, pressurized fluidized-bed combustion, and externally fired combined cycle systems rely on different high-temperature combinations of heat exchange, gas filtration, and sulfur capture to meet these requirements. The success of these systems when operated on low-rank coals depends importantly on the behavior of the ash. This paper focuses on the behavior of ash in an intermediate-scale transport gasifier coupled with a hot-gas cleanup system. The work reported is part of the overall program on hot-gas cleanup and the transport reactor development unit (TRDU) located at the Energy and ...

Energy Technology Data Exchange (ETDEWEB)

One of the five projects selected for funding within the Clean Coal Technology Program is a project proposed by the Pennsylvania Electric Company (Penelec) of Johnstown, Pennsylvania. Penelec proposes to enter into a cooperative agreement with DOE to design, construct and operate a 600 ton-per-day, 66-megawatt (MWe), coal-fueled, externally-fired combined cycle (EFCC) electric power generation facility. The EFCC is an emerging technology with promise for operating highefficiency combined gas- and steam-turbine cycles on coal. The central feature of EFCC is its coupling of the gas turbine to an external, atmospheric-pressure, coal combustor via a hightemperature ceramic heat exchanger (CerHx{reg_sign}) developed by Hague International. The EFCC technology is attractive because, unlike competing combined cycles such as Integrated Gasification (IGCC) and Pressurized Fluidized Bed ...

Energy Technology Data Exchange (ETDEWEB)

The indirect conversion of coal to liquid hydrocarbons via steam gasification followed by synthesis gas (CO/H/sub 2/) chemistry has been the subject of intensive study for a number of decades. A key technological challenge facing researchers in this area is control over the product distribution during the hydrocarbon synthesis step. In the case of iron Fischer-Tropsch catalysts, it has been known that the addition of alkali to the metal catalyst has a significant impact on the product distribution. Iron catalysts treated with alkali produce less methane more alkenes and higher molecular weight products. In spite of numerous investigations, the details of this promotional effect are not understood on a molecular level. To explore the role of alkali in the surface chemistry of iron catalysts, the authors have carried out a combined surface science and catalytic kinetic study of a model iron catalyst with and without surface alkali.

Energy Technology Data Exchange (ETDEWEB)

Both the KRW fluidized-bed gasifier and the transport gasifier case studies were used for this assessment. The transport technology is a high-velocity circulating fluidized-bed reactor currently under development by The M.W. Kellogg Company. In the earlier assessment, seven design concepts or cases were identified; a process design was developed; major equipment items were identified; estimates of capital cost, operation and maintenance cost, and cost of electricity were developed; reliability was predicted; and development issues were identified for six studies. Three of the most probable cases were further evaluated for a Greenfield assessment in this report to adequately determine all costs independent of facilities at Plant Wansley.

Energy Technology Data Exchange (ETDEWEB)

The United States Department of Energy (DOE) at the Morgantown Energy Technology Center (METC) contracted with P.S. Lowell and Co. Inc. (Lowell and Co.) and Jay S. Dweck, Consultant, Inc., (JSD) to enhance the capability of ASPEN in simulating coal gasification and oil shale processing plants. Of particular concern was the capability to predict the distribution of environmentally significant components among the various aqueous and organic liquids and gas streams within or leaving the process. The project was divided into major task areas. The first was to develop and implement the calculational routines necessary for predicting aqueous electrolyte chemical reactions. Part of this effort also was to select a species list and collect and/or regress data for the necessary parameters. The second task was to develop and implement a multi-phase flash capability (including precipitated solids) and unit operations models for a venturi and a ...

Energy Technology Data Exchange (ETDEWEB)

In connection with the ERP project 'Dynamic modelling of staged gasification processes' a gasification simulator has been constructed. The simulator consists of: a mathematical model of the gasification process developed at Technical University of Denmark, a user interface programme, IGSS, and a communication interface between the two programmes. (BA)

International Nuclear Information System (INIS)

Topics related to aerospace power are discussed, taking into account trends and issues of military space power systems technology, space station power system advanced development, the application and use of nuclear power for future spacecraft, the current status of advanced solar array technology development, the application of a parabolic trough concentrator to space station power needs, life test results of the Intelsat-V nickel-cadmium battery, and metal hydride hydrogen storage in nickel hydrogen batteries. Other subjects explored are concerned with alternative fuels, biomass energy, biomedical power, coal gasification, electric power cycles, and electric propulsion. Attention is given to an advanced terrestrial vehicle electric propulsion systems assessment, fuel cells as electric propulsion power plants, a sinewave synthesis for high efficiency dc-ac conversion, steam desulfurization of coal, leadless transfer of ...

Energy Technology Data Exchange (ETDEWEB)

The Institute of Gas Technology (IGT) has conducted a fundamental research program to determine the technical feasibility of a process concept that involves pressurized CO{sub 2}-coal gasification followed by a high-temperature CO{sub 2} removal step, using a MgO-based sorbent. To investigate a hot-CO{sub 2}-removal process, various MgO-containing materials were tested for their reactivity and capacity for removing CO{sub 2} from hot gas streams in a high-pressure thermobalance. No naturally-occurring materials were found to be acceptable, but a KOH-promoted magnesia was found to be sufficiently active for CO{sub 2} removal and to have a good capacity for CO{sub 2} absorption. Tests were conducted at pressures and temperatures in the ranges of 100--300 psig and 850{degree}--1170{degree}F. The CO{sub 2} absorption/desorption cycle was shown to be achievable by a simple pressure-swing operation between 0 and 315 psi CO{sub 2} partial pressure. 4 ...

Energy Technology Data Exchange (ETDEWEB)

In this report is described the work effort performed to provide NETL with VE-Suite based Virtual Engineering software and enhanced equipment models to support NETL's Advanced Process Engineering Co-simulation (APECS) framework for advanced power generation systems. Enhancements to the software framework facilitated an important link between APECS and the virtual engineering capabilities provided by VE-Suite (e.g., equipment and process visualization, information assimilation). Model enhancements focused on improving predictions for the performance of entrained flow coal gasifiers and important auxiliary equipment (e.g., Air Separation Units) used in coal gasification systems. In addition, a Reduced Order Model generation tool and software to provide a coupling between APECS/AspenPlus and the GE GateCycle simulation system were developed. CAPE-Open model interfaces were employed where needed. The improved ...

International Nuclear Information System (INIS)

Alloy 800 was developed in 1949 by The International Nickel Company, Inc. The basic composition, nominally 32wt.%Ni, 20.5wt.%Cr and 46wt.%Fe, was designed to provide a stable, fully austenitic structure and to impart high strength combined with resistance to oxidation, carburization and corrosion in a wide variety of aggressive industrial environments at elevated temperatures. In the short span of twenty-five years, alloy 800 has earned a unique position in the family of heat- and corrosion-resistant materials. Established uses include a wide range of applications in the industrial heating field, in the petro-chemical industry, in domestic appliances and in food processing equipment. The good performance of alloy 800 in these applications has led to its use as boiler tube material both in fossil-fired plants and in HTGR and PWR nuclear power systems. Recently, it was specified for a PHW CANDU reactor and it is now being considered as heat exchanger tube material for the LMFBR and for ...

International Nuclear Information System (INIS)

Small economies such as New Zealand risk significant economic hardship without careful evaluation of alternatives to petroleum-based transportation due to the adverse effects of climate change and depleting international oil reserves. This paper uses an integrated multi-regional multi-fleet system dynamics model of New Zealand's energy economy to assess the primary impacts of alternative vehicle fleet technologies. Results suggest that hydrogen fuelled HICEs and FCVs may offer significantly greater economic savings than BEVs due to a much lower capital cost. Under our Base Case, 65% of the light fleet are HICEs and FCVs and 5% BEVs. Excluding hydrogen vehicles from the vehicle fleet can result in an average annual cost of US$562 per vehicle between 2015 and 2050. Co-production of hydrogen and electricity using coal gasification with carbon capture and storage is the dominant long term hydrogen production technology. (author)

Energy Technology Data Exchange (ETDEWEB)

This paper describes research and development activities at the University of Regina, Saskatchewan, Canada on Optimization of CO{sub 2} Extraction Process Technologies. The ultimate goal of this research is to develop better and more effective CO{sub 2} separation processes which can be used to recover CO{sub 2} from industrial sources such as coal-fired power plants and coal gasification complexes at the lowest possible capital and operating costs. The research program has been supported by Saskatchewan Power Corporation, Saskatchewan Energy and Mines, Prairie Coal Ltd., the Canada Centre for Mineral and Energy Technology (CANMET), Fluor Daniel Inc. (USA), Sulzer Chemtech (Switzerland), Wascana Energy Inc., and Natural Sciences and Engineering Research Council of Canada (NSERC). Currently, six parallel and complementary projects have been carried out at the Process Systems Laboratory. These projects ...

Energy Technology Data Exchange (ETDEWEB)

A discussion is presented of the chemistry and technology of coal liquefaction and the physics and technology of coal desulfurization. 31 refs.

Science.gov (United States)

Global environment problems have become more and more serious in recent years, and reduction of greenhouse gas emission based on Kyoto Protocol adopted at the 3rd conference of the parties of the United nations Framework Convention on Climate Change (COP3); securement of primary energy source and development of clean and renewable energy sources have been pressingly needed in consideration of the predicted depletion of fossil fuel in the future. In this study, we explore the use of a solidified biomass-derived fuel, having the maximum compressive strength of 100MPa and calorific value of 21MJ/kg, in iron-casting or iron-making processes as an alternative fuel to be mixed with coal coke. This study, carried out for internal observation using a quick-freeze technique, observed an actual working cupola furnace under the 20% alternative coal coke operation condition. After quick freeze of the cupola furnace, the solidified biomass fuel was found ...

Energy Technology Data Exchange (ETDEWEB)

Chlorine clearly inhibits the CO{sub 2}-gasification reaction of charcoal at 800{sup o}C. From this and other observations the picture emerges that the reduction in the gasification reactivity of the charcoal is intimately related to the deactivation of the catalytically active alkali metals residing in the wood due to the formation of the chloride salt. It is argued that the heavy metal chlorides will likely transfer the chlorine to the indigenous alkali metals during the pyrolysis stage of the wood. The fate of the thus formed alkali metal chlorides can then be either their removal from the sample (evaporation), or, when present at the gasification stage, re-activation (i.e., de-chlorination) under our gasification conditions. (author) 3 figs., 4 refs.

Energy Technology Data Exchange (ETDEWEB)

This paper discusses geology, coalfields, coal quality, seams and strata, coal reserves, mining methods, production, coal liquefaction, and research on spontaneous combustion and methane explosions.

Energy Technology Data Exchange (ETDEWEB)

The combination of wood gasification and high temperature fuel cells like solid oxide fuel cells (SOFC) is an interesting approach to achieve high electrical efficiencies (40%) in small scale combined heat and power plants. This combination is called 'Biomass - Integrated Gasification Fuel Cell System' (B-IGFC). The main challenge is the adjustment of the three main components gasification, gas cleaning and fuel cell. In this technology, the first proof of principle by combining a gasifier with a SOFC in a laboratory scale for more than 100 hours was achieved. During this period, no deactivation of the system was found. (author)

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The externally fired combined cycle (EFCC) process utilises a high temperature heat exchanger to transfer the heat of a dirty flue gas to a clean working medium. In comparison to other combined cycle concepts, like integrated gasification combined cycle or pressurized pulverized coal combustion, the problems of hot gas cleaning are avoided. The first part of the publication deals with the possible concepts and the efficiency potential of the externally fired combined cycle. The applicability of metallic and ceramic heat exchanger materials are discussed. The second part (BWK 6/02) summarizes the state of the art and presents the basic design of a ceramic heat exchanger. (orig.) [German] Der extern gefeuerte Gasturbinenprozess arbeitet mit einem Waermeuebertrager, um ein Arbeitsmedium auf Gasturbineneintrittstemperatur zu erhitzen. Im Vergleich zu Kombiprozessen mit integrierter Kohlevergasung oder Druckkohlenstaubfeuerung entfaellt damit die ...

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P.S. Lowell and Co., Inc. (Lowell and Co.) and Jay S. Dweck, Consultant, Inc. (JSD) under contract to the US Department of Energy (DOE) Morgantown Energy Technology Center (METC) have developed and implemented an aqueous electrolyte calculation capability into the ASPEN (Advanced System for Process Engineering) process simulator. This report documents the efforts of Task 1 which were to implement the basic calculational capability. Task 2 involves development of several unit operations models and demonstration of the models in simulating environmental control processes in coal gasification and shale oil processing plants. Task 1 of the project involved several subtasks: selection of a chemical equilibrium algorithm; selection of activity coefficient algorithms; selection of species for inclusion in the initial implementation; collection of required data for the selected species; regression of parameters not found in the data collection effort; ...

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Chars prepared from potassium-exchanged carboxy methyl cellulose at several heat treatment temperatures (HTTs) were gasified in air isothermally at selected gasification temperatures (GTs) in the range 633-893 K to investigate the catalytic effectiveness of potassium species. The chars displayed a noticeable jump in gasification rate at a particular gasification temperature (called jump temperature, T{sub j}). The magnitude of jump was much less than that reported for copper and nickel catalysis, but comparable with that for calcium catalysis. Increase in HTT caused a decrease in the jump temperature of chars in contrast with the increase observed in copper, nickel and calcium catalysis; also the magnitude of jump did not decrease, but remained unaltered, on increasing HTT. The different behavior of potassium catalysis is correlated to a change in the chemical state of potassium at higher HTT. The results reveal the ...

KoreaScience (Korea)

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International Nuclear Information System (INIS)

Bio gasification, i. e. anaerobic digestion, is a well known sustainable option for the management of organic solid wastes and sludges. the produced biogas is a valuable bio fuel to replace fossil fuels in different technical applications (like heating, electricity, transport fuel generation) which in turn determine its quality requirements. (Author)

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An investigation of the effect of blending of two different coals in various ratios on the hydrogenation reaction was carried out using a red mud-sulphur catalyst. Three Japanese coals and an Australian brown coal were used in the study. The conversion of the blended coals was compared with that obtained with each of the coals alone. A blend of the Yallourn brown coal and Shin-Yubari coal showed a synergism: it is considered that hydroaromatics from the Japanese coal promote the hydrogenation of the Yallourn coal. (The tables and captions in this paper are in English).

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The use of low rank coal leads to a reduction of the coke strength because of the reduction of the caking property of coking coal. The authors have tried to understand this mechanism by extracting and analyzing the caking component of low rank coal and coking coal. It was found that the caking component is decreased by radical attack from the low rank coal, and thus the caking property is reduced. 11 figs., 3 tabs.

Science.gov (United States)

A process is described for maintaining the proportions of each coal in a coal blend at a desired level. The process involves (1) making a spectral analysis, preferably by infrared spectrometry, of at least one sample of the coal blend, the sample having known desired proportions of each coal, (2) making a spectral analysis of the coal blend sample of unknown proportions of each coal, (3) comparing the spectral analyses of steps (1) and (2), and (4) upon noting a significant difference between the spectral analyses of steps (1) and (2), making adjustments to achieve a final coal blend having proportions of each coal closer to those of the blend of known desired proportions of each coal. The relationship of the aromatic to aliphatic groupings is preferably determined by spectral analysis of each ...

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The global interest in renewable energy is attributed to the decline in fossil fuel sources and the need for technical, economic, social and environmental sustainability. This study focused on the new techniques that have been developed for the use of biomass for energy from wood wastes from the forest-based industry. As an energy source, wood waste contributes positively to the environment by reducing environmental problems related to contamination of soil, air and water through improper disposal of waste. Biomass gasification has the advantage of converting biomass into a combustible gas that can be used for heat generation, electricity and synthesis of chemicals. Syngas produced from gasification of eucalyptus residues has significant potential, with an average High Heating Value of 6.60 MJ/m{sup 3}, and regular composition during the process, with predominance of carbon monoxide, followed by hydrogen, carbon dioxide and methane.

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Biomass gasification provides the potential to efficiently and economically produce a renewable source of a clean gaseous fuel suitable for power generation or synthesis gas (syngas) applications. An important side benefit of the use of biomass is the effective minimization of the primary greenhouse gas, carbon dioxide (CO{sub 2}), by providing a means to close-loop the CO{sub 2} cycle. However, high molecular weight hydrocarbon constituents (tar) in the product gas from gasification can complicate the downstream uses of the gas. This paper discusses both the development of a low cost, disposable catalyst system that can eliminate these heavy hydrocarbons from the gas and the use of the catalyst in conjunction with the Battelle high-throughput gasification process for power generation and synthesis applications. (author)

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This assessment of Queensland's resources of black coal has been prepared by the Coal and Oil Shale Resources Assessment and Development Subprogram, Queensland Department of Mines, in accordance with the 'Code for Reporting of Identified Coal Resources and Reserves'.

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The dispersion mechanism of highly loaded coal-water mixture (CWM) in the presence of a polyelectrolyte additive was investigated. Two important factors have been found: the ability of the additive to apply a sufficient electric repulsive force to the coal particles, and an appropriate affinity of the additive to the coal surface.

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Combustion performance trials were conducted on a commercial sample of Coal Valley coal from the Coalspur coalfield in the foothills region of Alberta. The project included an analytical investigation of the coal and coal ash properties as well as combustion studies in the CCRL pilot-scale, pulverized coal-fired boiler, under conditions representative of those in large steam boilers. This report gives the objectives of the project, the analyses of the coals, and describes the facilities and operational procedures. An evaluation of the experimental results and the conclusions are presented.

Science.gov (United States)

... ENERGY CONSERVATION, ENERGY CONSUMPTION, ELECTRIC POWER DISTRIBUTION, FOSSIL FUELS, COAL, BRAYTON CYCLE. ...

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Orujillo, sometimes called wood matter from pressed oil-stone (WPOS) is a residue from the olive oil mill industry. The generation of this biomass residue is concentrated in small areas allowing its use as fuel for medium size gasification and combustion plants. Rates of gasification of WPOS char were measured in a TGA at various temperatures (800-850-875-900-950{sup o}C), CO{sub 2} partial pressures (0.20-0.35-0.50 bar) and CO partial pressures (0.0-0.20 bar). The experiments were carried out with a monolayer bed of very fine particles well exposed to the gas so as to minimise mass and heat transfer resistances. Two kinetic models, the nth order model and Langmuir-Hinshelwood model, have been used to fit with the reactivity data. For pure CO{sub 2} experiments the kinetic parameters of nth order model were E=133 kJ/mol and n=0.43. The Langmuir-Hinshelwood kinetic model clearly describes the observed CO inhibition effect on the CO{sub 2} ...

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A literature review on gasification of lignocellulosic biomass in various types of fluidized bed gasifiers is presented. The effect of several process parameters such as catalytic bed material, bed temperature and gasifying agent on the performance of the gasifier and quality of the producer gas is discussed. Based on the priorities of researchers, the optimum values of various desired outputs in the gasification process including improved producer gas composition, enhanced LHV, less tar and char content, high gas yield and enhanced carbon conversion and cold gas efficiency have been reported. The characteristics and performance of different fluidized bed gasifiers were assessed and the obtained results from the literature have been extensively reviewed. Survey of literature revealed that several industrial biomass gasification plants using fluidized beds are currently conducting in various countries. However, more research ...

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This paper describes a research and development project to quantify the effects of cleaning the coal feed on the yield patterns and processing rates for the Liquid Solvent Extraction (LSE) direct coal liquefaction process and to obtain information on the effect of the co-refining of coal-derived and petroleum distillates to premium transport fuels. 6 refs., 25 figs., 40 tabs.

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Gasification experiments were performed using urban waste wood (Altholz) with additions of polymers typical for separately collected waste plastics. The resulting tar product distributions are discussed in this paper. The amount of tars is shown to be a function of operation parameters of the gasifier as well as the fuel. Plastics admixture yields higher concentrations of aromatic tar compounds in the gases, even if the plastic used is not aromatic in its structure. Such mixtures can be gasified for the production of synthesis gas, but clearly a larger effort will be required in cleaning the gases. (author)

Science.gov (United States)

Fluidized bed technology was experimentally evaluated for the combustion and gasification of cotton gin waste. The isothermal bed temperatures in the reactors could be maintained below the ash fusion point of the waste. Raw stripper harvested cotton gin trash could be metered directly into the fluidized-bed reactors indicating that little feed preparation is required. H and CO were the primary products of gasification, and approximately 3200-400 Btu of gas were produced per lb of cotton gin waste. These techniques offer the potential of providing small-scale energy conversion systems for use on farms.

Science.gov (United States)

During 1978 the Engineering Board of SRC granted Specially Promoted Program status to the Coal Technology program. This recognized that coal would increase in importance as the cost of liquid and gaseous hydrocarbons rises with the decreasing availability of petroleum related sources. It was, therefore, considered necessary to anticipate and improve, through SRC supported research, the technologies required to win, transport, convert to liquid and gaseous fuels and utilize coal and coal based substances. In view of the interest in the program, and also in the hope of reaching a still wider audience the reports of the two meetings have been combined in this single booklet. The reports indicate specific problems of importance in coal winning and coal conversion but, naturally, do not cover all of the program priorities.

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The objectives of the Upgraded Coal Interest Group (UCIG) are as follows: Review and update the status of various coal upgrading technologies and developments and critically assess the results. Perform engineering screening analyses on various coal upgrading approaches. Perform commercialization analyses that will promote the availability and use of upgraded coal products by quantifying the benefits of using them. Identify market opportunities for introduction of upgraded coals. Perform critical analyses on a variety of coals and technologies in areas important to users but not readily available. Perform critical experiments which will show the differences between technologies.

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Discusses Czechoslovak regulations for determining moisture content in brown coal. Standard formulae for determining total moisture content and residual water content are described. Factors that influence accuracy in determining moisture content under laboratory conditions are analyzed: brown coal type, season of the year, air humidity, method and duration of coal sample drying, number of coal samples simultaneously dried in 1 dryer, ash content of coal. On the basis of analysis recommendations for a modified method of determining moisture content in brown coal are made. 5 refs.

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The overall goal of the Coal Liquefaction Program of the Office of Coal Technology (OCT) is to develop the scientific and engineering knowledge base with which industry can bring economically competitive and environmentally acceptable advanced technology for manufacturing synthetic liquid fuels from coal into the marketplace when needed. The technical goal of the Coal Liquefaction Program is to seek advanced and innovative improvements over the state-of-the-art processes for coal liquefaction that can utilize all major parts of the US coal resource base. A technology description and discussion of program goals and strategy is provided in this report. 2 figs.

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Change in structures of 3 kinds of coals with different coal ranks and their deashed coals was studied by heat treatment below 200{degree}C. In experiment, crushed Adaro, Taiheiyo and Huaibei coals below 200mesh and their deashed coals were used as specimens. The coal and deashed coal specimens dried in vacuum at 110{degree}C for 3 hours were filled into an autoclave, and the heat-treated coal specimens were prepared by holding them under initial nitrogen pressure of 2kg/cm{sup 2} at a fixed temperature for 30min. Extraction using pyridine as solvent, volumetric swelling using methanol or benzene as solvent, and measurement of the amount of carboxyl and phenolic hydroxyl functional groups were conducted for these coal specimens. The experimental results are as follows. Huaibei ...

Energy Technology Data Exchange (ETDEWEB)

The main goal of this research is to delineate the wetting behavior of coal and it subsequent effects on fine coal processing. As both bulk and surface properties of coal are interrelated and have a controlling role on the performance of these processes, a detailed study has been undertaken to correlate their influence on both wetting behavior and the response of coal to flotation and other unit operations encountered in fine coal processing. During the last quarter, the effect of coal rank on water retention capacity was investigated. The effect of pH on the vacuum flotation yield and the effect of desliming on the film flotation response of coal were also studied. 6 refs., 5 figs.

British Library Electronic Table of Contents (United Kingdom)

Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal firms and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in the advanced DEA linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of tot...

Energy Technology Data Exchange (ETDEWEB)

Following the management buy out (MBO) at British Coal`s Hatfield Colliery, a member of the Solicitors involved looks at some of the issues to be considered in coal industry MBO`s. British Coal should be notified, a business plan will be needed for handling venture capital and other issues, and warranties need negotiating.

Energy Technology Data Exchange (ETDEWEB)

The report describes the following: overview of the Russian power industry; electric power equipment of Russia; power industry development forecast for Russia; clean coal technology demonstration program of the US Department of Energy; reduction of coal TPS (thermal power station) environmental impacts in Russia; and base options of advanced coal thermal power plants. Terms of the application of clean coal technology at Russian TPS are discussed in the Conclusions.

Energy Technology Data Exchange (ETDEWEB)

Some applications of magnetic resonance in coal liquefaction research described briefly are: (1) investigation of the nature of carbon deposits on used coal-liquefaction catalysts, (2) determination of the fate of hydrogen during coal liquefaction, and (3) observation of transient free radicals during coal pyrolysis. The first two applications make use of cross-polarization /sup 13/C magnetic resonance combined with magic angle spinning, and the third application is an electron spin resonance study. (BLM)

Science.gov (United States)

Studies in advanced coal research are presented. Included are the following: coal science programs; coal preparation and combustion kinetics; advanced technology in liquefaction, including direct and indirect liquefaction; alternative fuels; advanced combustion technology; flue gas cleanup; environmental coordination, technology transfer, and clean coal demonstration program. (CBS)

Science.gov (United States)

The results of the two most recently completed runs at the Wilsonville Advanced Coal Liquefaction Research and Development Facility are presented. In Run 255, initial screening of operating conditions for the liquefaction of a Texas lignite was completed....

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The conversion of coal to oil can be carried out in two ways. A synthesis route and a degradation route. Each of these routes are described and several degradation processes are explored. The testing of several fuels produced from coal is also given considerations.

British Library Electronic Table of Contents (United Kingdom)

In this work, coals of various ranks were dissolved in an acid melange. With the use of IR spectroscopy, it was found that the mechanism of coal dissolution consists in the grafting of polar groups to the peripheral benzene rings of graphite-like systems.

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A brief discussion is given of the application of control monitoring and automation techniques to coal mining in the United Kingdom, especially of the use of microprocessors, for the purpose of enhancing safety and productivity. Lighting systems for the coal mine is similarly discussed.

Energy Technology Data Exchange (ETDEWEB)

Three areas have been investigated: coal liquefaction with supercritical fluids, liquefaction by extraction with high boiling liquid solvents, and the production of resins from coal-derived hydrocarbons. The processes are described.

Energy Technology Data Exchange (ETDEWEB)

This article outlines research and progress into the liquefaction of coal by solvent treatment, being conducted at the National Research Institute for Pollution and Resources, Japan. (In Japanese)

Energy Technology Data Exchange (ETDEWEB)

A review of the literature was undertaken to determine the potential for development of instrumentation for on-board remote sensing of coal quality. This review report acts as an inventory of commercially available techniques being tested or under development, particularly in the areas of the cutting horizon measurement methods associated with longwall mining equipment and coal/waste monitoring techniques in coal handling systems. While technology is available which can discriminate rocks from coal on a conveyor belt, the literature indicates that this hardware has yet to be adapted to continuous surface mining machines. 23 refs., 18 figs.

Energy Technology Data Exchange (ETDEWEB)

British Columbia is rich in resources of coal but is deficient in resources of liquid petroleum. The overall objective of the B.C. Research Coal Liquefaction Program is to provide sufficient technical data to identify and evaluate coal conversion opportunities in the province. In this first quarterly report, liquefaction test systems are discussed and results from the testing of equipment, procedures and analytical methods using coal samples from Sukunka (N.E. coal) and Hat Creek (central interior) are presented. The proposed program to be undertaken over the next four years is outlined.

Energy Technology Data Exchange (ETDEWEB)

This paper presents the results of a study commissioned by the British Columbia Science Council to identify opportunities for liquefaction of B.C. coals and to recommend effective approaches to the development of a research program on coal conversion. Contains reviews of British Columbia coal resources to identify prospective candidates for conversion to liquid fuels; of the state of the art in the various processes for the conversion of coal to liquid fuels with particular emphasis on those processes most relevant to British Columbia applications; and of research opportunities in British Columbia for the development of coal liquefaction technology. (16 refs.)

Science.gov (United States)

Results of research programs in coal liquefaction are presented. Areas of research include: desulfurization by bioprocessing; characterization of coal liquefaction processes by XAFS spectroscopy; coprocessing of coal with heavy oil and petroleum residuals; liquefaction research in pyrolysis, catalysis and coal dissolution; novel catalysts; data base development; resource evaluation; depolymerization; solvent extraction and chromatography; correlations of liquefaction yields and coal structure. Individual projects are processed separately for the data bases. (CBS)

Energy Technology Data Exchange (ETDEWEB)

Hydrogenolysis reactions of a mixture of coal liquid and coal liquefaction residue were carried out using red mud - sulfur or Co-Mo/Al{sub 2}O{sub 3} catalyst. The effect of deashing treatment of coal liquefaction residue were also investigated. Notable synergistic effects such as the increase of n-hexane soluble and the decrease of dichloromethane insoluble were observed only with the hydrogenolysis of the basic fraction of coal liquid and nondeashed coal liquefaction residue using red mud-sulfur catalyst. 4 refs., 2 figs., 2 tabs.

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The report is the second of three describing the geology of coal quality variations in the foothills and mountains region of Alberta. The Lower Cretaceous Luscar Group, Lower Paleocene Coalspur Formation, and the Upper Paleocene Paskapoo Formation (Obed-Marsh coal zone, which is classified as a foothills deposit) are evaluated. Data on proximate and ultimate analysis variables, calorific analysis, vitrinite reflectance, maceral analyses, and coal quality relationships are presented. The coals range from low volatile bituminous to subbituminous A. Regional and local in seam coal quality variations are examined. 49 refs., 39 figs., 6 tabs.

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This work presents an overview of the characterization physical-chemistry and energy of the aca pit used as input in process of generation of electricity through gasification. Acai pits analyses were accomplished with relationship to the acai pit drying, energy content, proximate and ultimate analyses, size, TGA experiments, bulk density. It was observed that the acai pit can be used as bioenergy but, it presents a low energy content (16,36 MJ/kg) in relationship that of the ' typical' biomass (21 MJ/kg ) and this is not due to the ash content that is very low (1,15%), but yes, the only composition that resembles each other more the Carbohydrates than to the typical composition of the usual biomass. The average diameter of 10 pits chosen at random was 9.5 mm. The acai pits have an angle of repose of {approx}20 degrees, making them ideal for feeding into gasification and combustion processes. (author)

Energy Technology Data Exchange (ETDEWEB)

Traditional methane drainage methods, including conventional ventilation and boreholes drilled in the coal seam, are widely used in modern coal mining operation in China. However, it is often noted that the gas drainage presents low efficiency in most coal mines due to low permeability of the coal seam, which not only affects the safety, but also the productivity of the coal mine. This paper describes the development and application of the waterjet cutting system, which is used to create artificial fractures and increase the permeability of coal seam for the improvement of methane drainage in underground coal mines in China. According to underground monitoring, a significant improvement of methane drainage efficiency of up to 3 to 6 times over the traditional methods has been achieved. (author)

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New York State Electric and Gas Co. (NYSEG) has developed a tool called Coal Quality Engineering Analysis (CQEA) to evaluate the cost impacts of coal quality on its power plants. CQEA allows quantification of the effect of coal quality on plant operating costs and has become an important factor in coal purchasing. The article describes the development of the analysis method, including a logic diagram of CQEA relationships. The results of CQEA calculations on the impact of one coal on overall production costs of different units, the impact of different coals on overall production costs of one unit, and production cost vs. coal quality, are presented and discussed. The use of the CQEA system within NYSEG is described.

British Library Electronic Table of Contents (United Kingdom)

Non-isothermal TG/DTG measurements are widely used to determine kinetic parameters of oxidation and gasification of carbons, e.g. by multi-heating rate methods. Thereby it is important to avoid spurious effects due to diffusion limitations. In this work, TG/DTG experiments with activated carbon were conducted under isothermal and non-isothermal conditions. The agreement of the experimental results with results of simulations based on the intrinsic kinetics, pore diffusion and external diffusion in/to the sample (crucible) is very good. The simulations show that mass transfer has an unwanted influence on TG measurements, if the concentration of the gaseous reactant (O2 and CO2) is too low and/or the heating rate is too high. Based on literature data, the simulation was extended to blast fur...

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This paper describes progress in several projects related to biomass power. These include switchgrass conversion development; switchgrass gasification development; production activities including soil studies, carbon studies, switchgrass production economics, watershed impacts, and prairie lands bio-products; information and education; and geographical information system. Attachments describe switchgrass co-firing test; switchgrass production in Iowa; cooperative agreements with ISU; Rathbun Lake watershed project; newspaper articles and information publications; Secretary of Agriculture Glickman`s visit; integration of technical aspects of switchgrass production in Iowa; and evaluation of an integrated biomass gasification/fuel cell power plant.

Energy Technology Data Exchange (ETDEWEB)

Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal firms and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in the advanced DEA linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of total technical efficiency or ...

Energy Technology Data Exchange (ETDEWEB)

Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal firms and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in the advanced DEA linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of total technical efficiency or ...

Energy Technology Data Exchange (ETDEWEB)

The object of briquetting coal fines is to convert a low grade fuel into one of superior quality coal. Briquetting techniques make coal an attractive substitute fuel by converting it into a compact, stable and inexpensive fuel. The briquetting of coal fines and char fines from coal and lignite, coke breeze, charcoal fines and similar materials is an important process for producing shaped fuel for a number of uses. Formed-coke made from non-caking coal for use in a blast furnace or in a cupola furnace involves the briquetting of treated char fines and further processing of the briquettes by means of carbonizing and curing. Briquettes may be made with or without binders, brown coal is particularly suitable for briquetting without a binder. Heat treatment may enable a higher rank coal to be briquetted without a binder, but ...

Energy Technology Data Exchange (ETDEWEB)

The coal bed methane (CBM) potential of five coal zones (the Kootenay, Gething, Gates, Brazeau, and Coalspur) in the Alberta foothills and mountains is re-evaluated. For evaluation, the coal zones are divided into shallow (200 to 2500 m depth) and deep (over 2500 m depth). The total gas content is estimated. Recommendations on how to obtain more reliable resource data and about producibility are included. 41 refs., 12 figs., 3 tabs., 2 apps.

Energy Technology Data Exchange (ETDEWEB)

This is a collection of photographs of the plant which is now almost completed.

Science.gov (United States)

Not Available

Energy Technology Data Exchange (ETDEWEB)

Results of tests on the 1 kg/h continuous reactor for the hydroliquefaction of coal are described. The reactor was operated at 415-435 C and 21 MPa using a continuous stirred reactor with a retention time of about 2 hours. All product oils were recovered by distillation. Sub-bituminous coal was found to give the best product yield. Tests using 5% red mud and 3% improved red mud showed significant increases in oil yield. (4 refs.)

Energy Technology Data Exchange (ETDEWEB)

Discussion is presented of world crude steel production, the Japanese steel industry and its expectations of the Canadian coal industry. It is concluded that the Canadian coal industry should pay attention to the trend in customer's requirements regarding coal quality, maintain price competitiveness in the international market place, and remain flexible with regard to the market trend.

Energy Technology Data Exchange (ETDEWEB)

This book presents the papers given at a symposium on occupational safety in coal mines. Topics considered at the symposium included human factors, causes and prevention of personal injuries, remote sensing for ground control, respirable dust generation by continuous miners, accident analysis, hazard analysis of mining equipment, coal mine blasting accidents, coal mine respirable dust sampling, and noise in the mining industry.

Energy Technology Data Exchange (ETDEWEB)

Past and current development of coal utilization technology in the Japanese steel industry is reviewed and some projects currently under research and development briefly described. These include DIOS, an iron making process which directly utilizes both iron ore and coal without a sintering plant or a coke oven; and the development of a new generation coke oven. 15 figs.

Energy Technology Data Exchange (ETDEWEB)

This report attempts to bring together available information on the coal deposits of Antarctica and discuss factors that would be involved if these deposits were to be explored and mined. Most of the reported principal coal deposits in Antarctica lie generally within the Transantarctic Mountains: the majority are of Permian age and are present in the Victoria Group of the Beacon Supergroup. Several other deposits have been recorded in East Antarctica and in the Antarctic Peninsula, including minor occurrences of Mesozoic and Tertiary coal and carbonaceous shale.

Energy Technology Data Exchange (ETDEWEB)

Consol R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

Energy Technology Data Exchange (ETDEWEB)

The objective of the current MITRE study is to estimate the cost of the coal derived liquid products that result from processing low rank coals in the Wilsonville and HRI CTSL configurations. The resultant cost of liquids is then compared to liquids produced from bituminous coals. The methodology used to accomplish the above objective was to utilize the MITRE coal liquefaction cost model to assess the overall technical and economic performance of low rank coals in both the Wilsonville and HRI configurations. Actual test data from Wilsonville and HRI was used as the basis for these analyses. This test data is modified to simulate complete resid recycle extinction and to standardize the operating performance of the deashing unit. This corrected yield data is then used in the simulation models to predict the overall performance and economics of a conceptual commercial ...

Energy Technology Data Exchange (ETDEWEB)

Energy consumption of black coal mines in Poland and methods for energy conservation are evaluated. Organizational models of energy management in underground coal mining are discussed. Tasks for dispatcher service for energy consumption control in a coal mine are analyzed: control of energy supplies, control of energy consumption, evaluation of electrical failures and reliability of protection systems, recording accidents and analyzing their causes, optimization of power systems in underground mines. Problems associated with control of energy consumption in a coal mine with mechanized systems for coal mining and use of computerized control systems are discussed. Recommendations for reucing energy consumption in underground coal mining are made. 4 references.

Energy Technology Data Exchange (ETDEWEB)

Electrostatic beneficiation of dry coal has received significant attention in the last decade. In this process the coal is ground and then charged, either by corona charging or by triboelectrification (friction charging). Coal and minerals receive different levels of charge -- often opposite polarities in the case of triboelectrification -- and can then be separated based on differences in electrical mobility. Problems associated with the techniques include rapid deposition of particles on the electrodes, thus, effecting further separation. The goal of this project is to optimize the electrostatic coal cleaning process to remove pyrites and inorganic materials through studies of the electrostatic properties of powdered coal, in-situ measurements of the electrodynamics of coal and mineral particles inside the separator, and development of self-cleaning collector ...

Energy Technology Data Exchange (ETDEWEB)

Brown coal resources of the Latrobe Valley in Australia total 140 billion tons to a depth of 975 feet, while economically recoverable reserves have been calculated to total 57 billion tons. Although the coal provides only a very low heating value, about 3300 Btu/lb with 60% moisture content, the enormous seam thicknesses with little overburden allow large scale, open cut mining operations. The low cost and high reactivity of the coal is attracting extensive coal liquefaction research. Research into dewatering processes for the high moisture content brown coal is being conducted. The dried brown coal could be used both domestically and internationally for electricity generation and as an industrial fuel.

Science.gov (United States)

A steam producing system based on fluidized-bed gasification of biomass materials is discussed. Limited experimental results are discussed and show that steam has been produced at rates of 334.3 kg/hr. (737 lbs/hr.) with 2.8 kg of stream produced for each kilogram of cotton gin trash (2.8 lb/lb.). ref.

Energy Technology Data Exchange (ETDEWEB)

This appendix contains the alphabetically indexed bibliography for the complete group of reports on municipal waste management alternatives. The references are listed for each of the following topics: mass burn technologies, RDF technologies, fluidized-bed combustion, pyrolysis and gasification of MSW, materials recovery- recycling technologies, sanitary landfills, composting, and anaerobic digestion of MSW.

Energy Technology Data Exchange (ETDEWEB)

Biomass contains nitrogen that is converted to NOx on combustion. Conversion of biomass into producer gas by thermal gasification offers an opportunity to reduce NOx-emissions by NH3 removal from the producer gas with water. Waste water will have to be treated before it can be drained. Recovered NH3 may have value as base chemical, but usually will have to be disposed off as waste. Recycling within the gasification process is an option to dispose off NH3 waste, provided NH3 is broken down under gasification conditions. We present experimental data on NH3 destruction in a CFB gasifier at temperatures from 780C to 860C, when NH3 is injected into the gasification air. Within that temperature range, the fraction of NH3 that is broken down increases from less than 50% to nearly 100%. Clearly, the presence of O2 at the injection point leads to a much higher rate of NH3 destruction than observed for purely ...

Energy Technology Data Exchange (ETDEWEB)

By increasing the price of crude oil and natural gas and the decline in their stock a possibility of more intense use of coal reserves as a feedstock not only for energy purposes but also as a feedstock source for other industries, mainly chemical and steel industry, is opening up. At present brown coal exploited in the Czech Republic is explicitly burned in the power sources of various outputs. Coal pyrolysis under the defined conditions may be an outstanding way of non-energetic brown coal processing. The target of our work was to determine the behaviour of various types of brown coal from the North Bohemian Basin under the pyrolysis up to the temperature 750{sup o}C. At the same time, qualitative parameters of the pyrolysis products in dependence on the features of the input brown coal were observed. Various types of brown coal were used ...

Energy Technology Data Exchange (ETDEWEB)

In relation to coal liquefaction, the effect of inorganic minerals on liquefaction reactivity and the effect of hydrofluoric acid (HF) treatment on organic molecular structure of coals were studied by demineralization of low-rank coals in HCl or HF solution. In experiment, Taiheiyo coal specimen was deashed in HCl solution at 25-70{degree}C for 6 hours while agitating, and in addition, deashed in HF solution. Hydrogenolysis of the deashed coal specimen was conducted using tetralin or methylnaphthalene as solvent under initial hydrogen pressure of 1.96MPa at reaction temperature of 693K for 60min. The experimental results are as follows. The ash content of Taiheiyo coal hardly offers catalysis in hydrogenolysis reaction. Carboxyl group increases in demineralization of coal because of breakage of bridged bonds. Organic structure of ...

Energy Technology Data Exchange (ETDEWEB)

In order to develop a high-efficiency coal pyrolysis method, flash pyrolysis was experimented on slurry prepared by using liquid-phase oxidation reformed coal and a methanol-based solvent mixture. Australian Morwell coal was used for the experiment. The oxidized coal, into which carboxyl groups have been introduced, has the condensation structure relaxed largely, and becomes highly fluid slurry by means of the solvent. Char production can be suppressed by making the oxidation-pretreated coal into slurry, resulting in drastically improved pyrolytic conversion. The slurry was divided into dissolved solution, dried substance, extracted residue, and residual slurry, which were pyrolized independently. The dissolved solution showed very high conversion. Improvement in the conversion is contributed by separating the dissolved substances (coal macromolecules) at ...

Science.gov (United States)

The method of producing blast furnace coke by (1) compacting a finely divided coal wherein at least about 60% by weight of the coal has a diameter of less than about 1/8 inch to form a coal compact, which compact immediately after removal from the compacting means comprises at least about 20% by weight of particles having a particle size of less than 1/4 inch in diameter; (2) breaking the thus formed compact such that the bulk density is sufficiently increased to be capable of conversion into coke suitable for use in large blast furnaces upon carbonization thereof; and (3) carbonizing the broken compact to thereby produce blast furnace coke having a minimum hardness of about 68 and a minimum stability of about 55. The compacting is preferably performed at a pressure equivalent to that achieved by passing the finely divided coal between rolls at a pressure applied to the coal of ...

Science.gov (United States)

According to W. H. Wiser and A. G. Oblad, the program at the University of Utah to develop coal conversion techniques, which has received federal grants of $1.35 million since 1969, recently was awarded $425,000 from the U.S. Office of Coal Research for the development of catalysts for coal conversion and low-sulfur fuel oil production. In tests, 100 lb of coal have been converted into 95 lb of products composed of 30 lb liquid fuel like gasoline, 5 lb of diesel or fuel oil, 30 lb of gaseous fuel, and 30 lb of char.

Energy Technology Data Exchange (ETDEWEB)

McLeod River Coal Ltd., a wholly owned subsidiary of Manalta Coal Ltd., has received Alberta Energy Resources Conservation Board approval to establish an open pit coal mine and plant in the northwest portion of the Coalspur field, east of Hinton. McLeod proposes to produce up to 4.2 million tonnes/year of thermal coal for 40 years, starting in 1985. The commercial viability of the project must be assessed before construction starts at the McLeod River site. The Board's ruling is subject to provincial cabinet approval.

Science.gov (United States)

Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

Energy Technology Data Exchange (ETDEWEB)

The presence of water in export coals increases transport and handling costs. Coarse (+0.5 mm) coal constitutes the majority of the product, and small changes in its final moisture content will have a significant effect on overall product moisture. An on-line moisture monitor was installed on a product belt immediately after a coarse coal centrifuge to continuously measure the moisture content of the coal from a single centrifuge. Basic studies were also conducted with a laboratory centrifuge specifically designed to characterize various coarse coal samples in terms of their water retention capacity. The moisture of the coarse coal (typically 6 to 9%) was found to vary by at least 1% at a particular plant, and by a number of percentage points between plants. An empirical model has been developed which can explain about 80% of the moisture variation from the 25 ...

Energy Technology Data Exchange (ETDEWEB)

In 1970, the Federal Power Commission predicted a fall from 46% to 27% in 1990 as a result of predicted increases in the use of nuclear power. Today, the Department of Energy expects coal to supply about 50% of electricity generation in 1990. About one-eighth of the world's annual hard coal production is used to make electricity in the United States. Power stations in the country used more coal in 1979 than was produced in the whole Western Europe that year. These 405,000,000 tons of coal equivalent were burned in 1257 individual utilities with an aggregate capacity of 235,000 megawatts. There are coal-fired power plants in 43 of the 50 states. Four factors will be most important in shaping the future development of coal-based electricity: prices, conservation, environmental regulations, and national security. The price differential between ...

Energy Technology Data Exchange (ETDEWEB)

The DOE Coal Liquefaction Research Needs (COLIRN) Panel reviewed, developed, and assessed R and D needs for the development of coal liquefaction for the production of transportation fuels. Technical, economics, and environmental considerations were important components of the panel's deliberations. The panel examined in some depth each of the following technologies: direct liquefaction of coal, indirect liquefaction via conversion of coal-derived synthesis gas, pyrolysis, coprocessing of combined coal/oil feedstocks, and bioconversion of coal and coal-derived materials. In this assessment particular attention was given to highlighting the fundamental and applied research which has revealed new and improved liquefaction mechanisms, the potentially promising innovative processes currently emerging, and the technological and ...

Energy Technology Data Exchange (ETDEWEB)

This quarterly report for the period April through June 1984 summarizes activities in Sandia National Laboratories' continuing program of coal liquefaction research. The primary goals are to: explore novel catalytic concepts and materials for conversion of coal to liquid fuels; determine the effects of process variables on catalyst deactivation; determine the effects of coal structure and solvent properties on low temperature dissolution; study the kinetics and catalysis of hydrogen transfer reactions; develop an understanding of slurry gelling phenomena; and provide a technical assessment of coal liquefaction processes. During this period, work was performed on: analysis of catalyst samples from Wilsonville Run 246; catalyst presulfiding; catalyst activity testing using pyrene as a chemical probe; catalyst deactivation using a high-pressure model compound test reactor; dissolution chemistry of ...

Energy Technology Data Exchange (ETDEWEB)

For the removal and recycle of CO2, a global warming gas, utilization of photosynthesis by micro algae is investigated. Formed micro algae are decomposed into CO2, H2O and CH4 again, which does not result in the permanent fixation. For the effective utilization of these micro algae, creation of petroleum alternate energy was tried through the co-liquefaction of micro algae with coal. Were investigated influences of the reaction temperature during the co-liquefaction and influences of catalysts, such as Fe(CO)5-S, Ru(CO)12, and Mo(CO)6-S, which are effective for the coal liquefaction. Micro algae, such as chlorella, spirulina, and littorale, and Yallourn brown coal were tested. It was found that co-liquefaction of micro algae with coal can be successfully proceeded under the same conditions as the liquefaction of coal. The oil yield obtained from the co-liquefaction in the presence ...

Energy Technology Data Exchange (ETDEWEB)

Experimental and theoretical investigation on drying of a single coal particle in fluidized bed combustor is presented. Coal particle drying was considered via the moist shrinking core mechanism. The results of the drying test runs of low-rank Serbian coals were used for experimental verification of the model. The temperature of the coal particle center was measured, assuming that drying was completed when the temperature equalled 100{sup o}C. The influence of different parameters (thermal conductivity and specific heat capacity of coal, fluidized bed temperature, moisture content and superheating of steam) on drying time and temperature profile within the coal particle was analyzed by a parametric analysis. The experimentally obtained results confirmed that the moist shrinking core mechanism can be applied for the mathematical description of a ...

Energy Technology Data Exchange (ETDEWEB)

The current status and prospects for Japan`s economy and steel industry, forecast for demand and supply of coking coal, directions in steel making technology, and Japan`s expectations for Canadian coal are discussed. The PCI system, the Coal Moisture Control System (CMC) to increase coke density before it is fed into coke ovens, a feeder that allows use of lower quality coke on the outskirts of blast furnaces, the Direct Iron Ore Smelting (DIOS) Process, and the `Next Generation Coke Oven`, where coke is heated rapidly and coked at 700-800{degree}C are considered. By 2000, semi-soft coking coals are expected to account for over half of total coal consumption by Japanese steel mills.

Energy Technology Data Exchange (ETDEWEB)

This paper presents a numerical study on the formation history of coalbed methane (CBM) reservoir in the southeast edge of Ordos Basin, China. The coal seams studied belong to the Late Palaeozoic coal-bearing series. These coal seams have a burial history and experienced the process of subsidence, rapid subsidence alternated with uplift and then uplift, sequentially, and underwent the geothermal actions at normal, extremely high, and then normal temperatures, respectively. Coal organic matter of the coal seams matured in the Triassic Period and in the Late Jurassic to Early Cretaceous Period. The results from numerical simulation reveal that CBM reservoir evolution history can be classified into five stages, namely primary, initial, stagnant, active and dissipative stages. In the first (primary) stage, coal rank was very low and there was little methane ...

Energy Technology Data Exchange (ETDEWEB)

Catalytic activity of industrial metallic wastes in coal liquefaction was examined in a 100lb/day continuous coal processing development unit. Red mud, a waste material from the aluminium industry, and an electric furnace flue dust containing Ni, Mo, Co and Fe showed a pronounced effect on the conversion of a Kentucky bituminous coal. Coal conversion and oil production increased significantly with the addition of red mud and flue dust. Comparison of the catalytic activity of pyrite, red mud, and flue dust, based on selectivity analysis, showed that red mud was the most desirable disposable catalyst. However, if the primary goal of coal liquefaction is high oil production, irrespective of hydrogen consumption, pyrite is the most active catalyst among those discussed in the paper.

Energy Technology Data Exchange (ETDEWEB)

The coal transportation industry has played an integral role in determining coal markets, particularly in recent years, as the industry has evolved from cost-based pricing to market-based pricing. Aggressive pricing by Western rail carriers has caused extensive changes in coal marketing patterns in the Midwest. Multi-modal barge deliveries of Western and Appalachian coals have also played a significant, though lesser, role in changing coal markets. Eastern rail carriers have generally lagged in their aggressive pursuit of new coal markets and, to date, few changes in coal markets have been realised. The historic dominant role of transportation in shaping markets for coal will continue into the future as the utility industry contends with the effects of CAAA compliance and deregulation and as the coal ...

Energy Technology Data Exchange (ETDEWEB)

This paper discusses spectral change in brown coal and bituminous coal as a result of low-temperature drying. The experiment used a Fourier transform infrared (FT-IR) spectroscopy disposed with an in-situ diffuse reflector as a water content measuring method. The FT-IR spectra of coal showed the existence of two types of adsorbed water. One of the two spectral peaks was thought to have been caused by isolated water molecules which may have been hydrogen bonded to hydrocarbon in the coal molecules and weakly bound. The other peak was thought to have been caused by water which may have been hydrogen bonded to functional groups such as hydroxyl groups in the coal molecules and strongly bound. Drying behavior in brown coal and bituminous coal showed the absorption peak at 3640 cm[sup -1] reducing faster than the absorption peak at 3360cm[sup ...

Energy Technology Data Exchange (ETDEWEB)

The properties of cast basalt and alumina are examined. The ways in which these materials have been used in applications in coal preparation plants, for example in bunker and pipe linings where abrasion and corrosion resistant materials are required, are discussed.

Science.gov (United States)

The extensive reserves of mined coal types, their great variety and the complexity of the composition and properties, as well as their important role as an energy fuel and industrial feedstock, cause one to give special attention to their classification. Of course, one of the principal fields of technological processing of coal is coking. In addition to the production of blast furnace coke, in the future specialized plants will be developed for production of coke and other carbonized materials for non-blast-furnace processes (electrothermal processes, production of calcium carbide, ferroalloys, zinc, yellow phosphorus, copper, etc.). One important area is new nonfuel uses, including a number of processes for processing of coal feedstocks to obtain a wide range of carbonaceous materials (coal-graphite products, carbon black, adsorbents, etc.), liquid fuels, and chemical products. In choosing a given area ...

Energy Technology Data Exchange (ETDEWEB)

A schematic diagram of the decision making process for air pollution control equipment for the conversion of a fossil-fired generating unit from oil to coal is presented and explained.

Energy Technology Data Exchange (ETDEWEB)

In order to replace industrial cobalt and nickel and molybdenum catalysts, more economical catalysts, red muds, are used. Comparative data about the chemical, structural and thermal properties of different samples of red muds, which are important for catalytic hydrogenation, are cited. The different conditions for hydrogenation of coals in a reactor are examined.

Energy Technology Data Exchange (ETDEWEB)

The paper reported on an experiment on measurement of concentration of highly concentrated coal slurry using microwaves carried out at Miike coal preparation works. The purpose of the experiment was to investigate applicability of microwave moisture content measurement of slurry of a mixture of coal and coal particles and to use it to the control of process such as coal preparation and processing. In the experiment, a method for measuring the slurry concentration was adopted in which the container filled with highly concentrated coal slurry was irradiated with microwaves and the damping of strength of the penetrating microwaves was detected. As a result of the experiment, it was found out that there was a big correlation between the capacitive concentration of slurry and the damping ratio of microwaves. When irradiating slurry with microwaves of 1GHz frequency, ...

Energy Technology Data Exchange (ETDEWEB)

Taiheiyo coal deashed using acid treatment and loaded with potassium or calcium was hydro-cracked under gaseous phase to discuss effects of these metals on liquefaction reaction. In addition, the loaded coal was added with red mud catalyst to examine effects of the addition. The loaded potassium has a softening power, and particularly the potassium adsorbed into surface and micropores in the coal decomposes selectively HI-BS and BI-PS and generates gas and HS. On the other hand, potassium deposited on coal surface promotes direct gas production from the coal. Irrespective of its loading modes, calcium has a catalytic nature to produce HI-BS selectively. Calcium also acts to impede decomposition of HI-BS into HS. Adding red mud catalyst to potassium loaded coal increases the inversion rate and the liquefaction yield, and most of the increase is accounted for by ...

Energy Technology Data Exchange (ETDEWEB)

The report details the results of a series of large-scale experiments where small coal fires were used to ignite conveyor belting at air velocities ranging from 0.76 m/s to 6.1 m/s. In the tests, electrical strip heaters imbedded within a pile of coal were used to heat the coal to a point of flaming ignition. The flaming coal subsequently ignited conveyor belting located approximately 5 to 10 cm above the coal pile. During the tests, temperature, CO, and smoke levels were continuously measured in order to determine both alarm time and level as the fire intensity progressed through the stages of smoldering coal, flame coal, and flaming coal plus flaming belt. Analysis of the data leads to certain conditions of air velocity and sensor alarm levels that are required for early detection of conveyor belt entry fires. Two ...

Energy Technology Data Exchange (ETDEWEB)

This progress report presents a detailed description of the background, technology and application, and Statement of Work for the development of a coal-fired pulse combustor for residential space heating.

Energy Technology Data Exchange (ETDEWEB)

Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

Wastenet

... After completing a review into direct coal liquefaction research carried out in Australia and internationally, CSIRO has identified potential new science and technology developments that may improve the cost and viability of CTL in a greenhouse gas-constrained environment. We are conducting research to: determine the optimum ...

Energy Technology Data Exchange (ETDEWEB)

The Coal Quality Engineering Analysis (CQEA) program developed by the New York State Electric and Gas Company (NYSEC) calculates the as-burned cost of burning a specific coal in a specific generation unit. These costs include: maintenance costs for coal and ash handling equipment; ash disposal costs; cost of oil (if required for flame stability and/or derating because of pulverizer capacity limitation); flue gas desulfurization costs; cost of replacement power caused by pulverizer, precipitator fly ash collection and bottom ash capacity limitation; boiler losses due to moisture, hydrogen, dry gas and unburned carbon; power for coal and ash handling equipment; power for coal pulverizers; cost of using excess air to prevent slagging of coal with low ash softening temperatures; and effect of heat rate on coal tonnage required for a desired ...

Science.gov (United States)

The manual describes a combined coal-cleaning and flue gas desulfurization (FGD) computerized design and cost-estimate model and gives detailed procedures for using it. All inputs and outputs are described, as well as the various options available. Design and economic premises ar...

Energy Technology Data Exchange (ETDEWEB)

Many Pacific Basin countries rely on oil for electricity production. Alternative fuel sources such as coal, which is available in the Pacific Basin, can help mitigate adverse impacts of sudden price increases or supply disruptions. Coal combustion produces solid and potentially hazardous wastes of concern to environmental regulators and utility managers. This paper identifies issues associated with managing coal combustion wastes in the Pacific Basin, using the state of Hawaii as a case study. Hawaii is typical of many Pacific Basin locations in that it depends on oil, has limited sites, for waste management operations, and is subject to domestic and international waste management regulations. The paper discusses coal-fired utility wastes, environmental impacts of coal combustion waste disposal, and regulatory requirements that impact coal waste management. From ...

Energy Technology Data Exchange (ETDEWEB)

This report presents the results of Run 260 performed at the Advanced Coal Liquefaction R&D Facility in Wilsonville. The run was started on July 17, 1990 and continued until November 14, 1990, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). Both thermal/catalytic and catalytic/thermal tests were performed to determine the methods for reducing solids buildup in a subbituminous coal operation, and to improve product yields. A new, smaller interstage separator was tested to reduce solids buildup by increasing the slurry space velocity in the separator. In order to obtain improved coal and resid conversions (compared to Run 258) full-volume thermal reactor and 3/4-volume catalytic reactor were used. Shell 324 catalyst, 1/16 in. cylindrical extrudate, at a replacement rate of 3 ...

Energy Technology Data Exchange (ETDEWEB)

It has been discovered that when Taiheiyo coal pulverized to 200 mesh or smaller is dispersed in naphthalene, a non-hydrogen-donor solvent, and reacted under hydrogen pressure in the presence of a red mud/sulfur catalyst, the catalyst exhibits activity in the regeneration of hydrogen donor solvents which have been hydrogen-depleted in the course of coal liquefaction. It is already known that inorganic matter contained in coal acts as a catalyst in liquefaction. This suggests that the reported effect of the red mud/sulfur catalyst is due to the iron oxide reacting with the sulfur and forming pyrrhotite. 22 refs., 6 figs., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

Two nomographs are presented which enable the volumes of a conical pile and an oblong pile of bulk material to be determined.

Science.gov (United States)

A method for analyzing the experimental results of coal liquefaction reactions which is applicable to a number of aspects of coal liquefaction research and process control, including rapid selectivity and performance screening for catalysts; correlation of laboratory results with process parameters; and optimization of product yield with plant process conditions is described here. Ternary diagrams of product/by-product distributions for the coal liquefaction using Co/Mo catalysts combined with a hyperbolic relationship for the conversion of various hydrocarbon fractions can be used for catalyst screening. A hydrogen consumption diagram used to provide a more significant selectivity test than the hyperbolic correlation is also included. (BLM)

Energy Technology Data Exchange (ETDEWEB)

The control of piece size in ruptured rocks in coal sections is important as part of the general problem of increasing efficiency in the technology of open-pit mining operations. An attempt is made in this paper to estimate the rupture capacity of exposed rocks in coal sections based on a set of physicomechanical property indicators, using the methods of multidimensional statistical analysis. It was established that all the parameters for the physiocomechanical properties of the exposed rocks are highly correlated. The method proposed for determining criteria for explosive capacity is of interest in developing criteria for the destruction capacity (drillability, excavation capacity, etc.) in the exposed rocks of coal sections which are characterized by high variation in physical and mechanical properties.

Science.gov (United States)

The economy of Poland depends to a large extent upon the exploitation of its vast rich coal reserves for which new mines will have to be sunk and existing mines modernized. Two avenues of coal conversion are being followed. Both involve hydrogenation but one is based on solvent extraction of coal and the other on its pyrolysis. At present large scale established methods of chemical treatment are those which involve the production of coke, production of town-gas, production of synthesis gas and partial oxydation. Total weight amounts to 21,000,000 tons.

Science.gov (United States)

This bulletin traces development of high-pressure, coal and tar hydrogenation technology, based on an intensive review of pertinent literature. The bulletin written as part of the Bureau of Mines research program on synthetic liquid fuels covers the history and economics of the process; chemical aspects of hydrogenation of coal, tar, and middle oil; engineering aspects of converting coal and tar to liquid fuels, principally gasoline; and equipment for the process. The literature covered includes documents of United States and British governments, journals, and other publications. Bureau results in the hydrogenation field are also incorporated.

Science.gov (United States)

This report--the forty-fifth of a series--is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion process development, materials engineering, alkali metal vapor topping cycles, a coal equipment test program, an AFB coal combustor for cogeneration (CCC), engineering and support studies, process and program assistance, evironmental assessment studies, magnetic beneficiation, and AFBC demonstration plant.

Energy Technology Data Exchange (ETDEWEB)

Denison Mines Limited is completing two final feasibility studies on the Coalspur thermal coal property in northwestern Alberta and the Belcourt property south of Dawson Creek, B.C. Denison is also carrying out a geological field program on a promising metallurgical coal property, Wildhay, west of Hinton, Alberta. Fording Coal Ltd. will close its Fording River mine for at least the second half of December. Site preparation has started at the Obed-Marsh thermal coal project northeast of Hinton.

Energy Technology Data Exchange (ETDEWEB)

The first stage of the continuous coal hydrogenation unit has been used to test a number of coals with different processing strategies. This work has shown that conversion increases with product recycle, however after the second pass the increase is small but operability of the reactor is considerably improved. A kinetic model for the aromatic saturation of the recycle solvent in the second stage has been developed and will be used in the selection of conditions for oil upgrading processes. New insights into the structural composition of coal derived materials have been made due to the refinement of chromatographic or solubility separation analyses into routine operations and the development of a new technique in NMR spectroscopy.

Energy Technology Data Exchange (ETDEWEB)

Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

Energy Technology Data Exchange (ETDEWEB)

This publication, part of the series titled Market Guide for Steam Coal Exports from Appalachia provides information on export markets, contracts, and related matters for producers and others involved in mining, selling, and shipping Appalachian coal to foreign buyers. It also includes information on the financial institutions that provide export finance and how they are used. Senior officers of more than 40 banks ranged from the largest money center bank and a major foreign bank in New York City to small banks in Appalachia.

Energy Technology Data Exchange (ETDEWEB)

Light microscopy was used to analyze the effects of added catalyst at different conditions (temperature and reaction times) in liquefaction testing of a low pyritic sulfur bituminous coal. Quantitative changes in vitrinite/vitroplast reflectance of coal and liquefaction residues were shown to be useful markers in analyzing and understanding the role of catalyst during the initial stage of coal particle hydrogenation. Lower reflectance values corresponded to increased conversions up to about the 60 min and 375{degrees}C experimental conditions. Microscopical observation of liquefaction residues also revealed the presence of `wall scales` of varying width.

Energy Technology Data Exchange (ETDEWEB)

A discussion of the Sasol I, II, and III coal liquefaction plants of the Republic of South Africa was presented. The technology, capacity, and economics of these projects were included in the discussion. These plants utilize the Fischer-Tropsch process of indirect coal liquefaction and produce a barrel of synthetic crude for about $55 (or about $20 above current market prices). Outlines of the differences in indirect coal liquefaction and newer direct methods were presented. It was determined that the South African dedication to coal liquefaction was made more for the political aspects of energy independence than economics.

Energy Technology Data Exchange (ETDEWEB)

The theme of the conference was 'The paradox: today's coal technologies versus tomorrow's promise'. The sessions covered: today's technologies, tomorrow's potential; economic stability; energy security; transition to sustainable energy future; new coal power technologies leading to zero emission coal; existing power plants - improved performance through use of new technology; and carbon capture and storage R & D - challenges and opportunities. Some of the papers only consist of the viewgraphs/overheads.

Energy Technology Data Exchange (ETDEWEB)

This work reports an experimental study on the steam gasification of an anthracite coke in a fluidized bed reactor, with the aim of evaluating the reaction kinetics. Isothermal runs were carried out with samples of 91 to 275 g of coke, at temperatures between 799 and 928{sup 0}C and for steam partial pressures between 0.3 and 0.9 atm. The conversion decreases as the amount of coke is increased and it is very sensitive to the temperature. Neither the volumetric reaction model nor the unreacted shrinking core model can satisfactorily fit the experimental results. That is why empirical models have been used. The first one is derived from the unreacted shrinking core model. An activation energy of 219 kJ. mol{sup -1} and a reaction order with respect of steam of 0.57 have been identified. In the second model, the conversion has been correlated as a function of a dimensionless time. A comparison of the results obtained in the fluidized bed with other ones obtained in a ...

Energy Technology Data Exchange (ETDEWEB)

The composition, rank, coal facies, and coal pore structure characteristics of 15 coal samples were investigated systemically using methods of lithotype analysis, maceral analysis, proximate analysis, mercury porosimetry analysis, and nitrogen adsorption analysis. These samples were directly collected from the working faces of No.4, 8, 9 seams in Liulin district, eastern margin Ordos Basin, China. Four types of paleoenvironment including a wet forest swamp, an intergradation forest swamp, a drained forest swamp, and a fresh-water peat swamp were distinguished by lithotype and merceral analysis. An R-cluster analysis was performed to demonstrate the correlations between the coal facies and the pore structures. The results showed that coal rank is the primary factor affecting the development of micropores and transition pores, whereas coal facies control the ...

Energy Technology Data Exchange (ETDEWEB)

This report provides a regional overview of the hydrologic regimes of the Northeast Coal Study Area in British Columbia; illustrates the range of possible peak discharge values which may be predicted for streams adjacent to the Tumbler Ridge townsite; and, provides recommendations pertaining to future hydrologic analysis within the Northeast Coal Block.

International Nuclear Information System (INIS)

Applications of X-ray fluorescence analysis in coal mining and geology are briefly described based on results published in Czechoslovakia as well as abroad over the past 3 years. Particular attention is paid to the rapid determination of the ash content of coal using portable radionuclide X-ray fluorescence analyzers that are being developed in Czechoslovakia. (author).

Energy Technology Data Exchange (ETDEWEB)

The coalbed methane (CBM) geology, resource and production potential in the Weibei Coalfield, southeastern Ordos Basin are studied based on geological surveys and laboratory measurements. The results showed that coal rank varies both laterally and vertically and changes from volatile bituminous coals in the margin to anthracites towards the basin (1.6-2.5% R{sub o}). Coals are composed of 60-85% vitrinite, 15-40% inertinite and a trace amount of minerals. Methane isothermal adsorption measurements of 20 coal samples revealed that the maximum adsorption capacity (on a dry and ash-free basis) of coals, which are affected by coal rank, coal maceral, coal lithotype and especially to the moisture content, varies from 13.91 to 29.54 m{sup 3}/t. Estimated gas contents range from 0 to 15 m{sup 3}/t. These data yield an estimated ...

Science.gov (United States)

Research is being carried out in this project in two areas which are of interest to ongoing investigations at the Pittsburgh Energy Technology Center (PETC). They are: (1) behavior of slurry reactors used for indirect coal liquefaction, and (2) coal liquefaction under supercritical conditions. The current status of each of these tasks is summarized in this report.

Energy Technology Data Exchange (ETDEWEB)

Reported on here are studies of various methods for liquefying coal. Hydropyrolysis as an alternative method for producing liquid hydrocarbons and a carbon enriched char is discussed. Other methods described involve supercritical gas extraction of coal and use of natural gas as a hydrogenating agent. Relevant waste water treatments are discussed as well. 65 refs., 9 figs.

Energy Technology Data Exchange (ETDEWEB)

Real-time horizon sensing on continuous mining machines is becoming an industry tool. Installation and testing of production-grade Horizon Sensor (HS) systems continued this quarter at Monterey Coal Company (ExxonMobil), Mountain Coal Company West Elk Mine (Arch), and Ohio Valley Coal Company (OVC). Monitoring of system function, user experience, and mining benefits is ongoing. All horizon sensor components have finished MSHA (U.S.) and IEC (International) certification.