calcium phosphate spherical: Topics by WorldWideScience.org

Ethoxylated Bisphenol Dimethacrylate-based Amorphous Calcium Phosphate Composites

Full Text Available

2007-03-01

2

Proceedings of ARO Workshop Biostructures as Composite ...

Improving the anti-demineralizing/remineralizing and mechanical properties of amorphous calcium phosphate (ACP) composites has been the focus of our recent research. In this study, an ethoxylated...Full Text Available

2006-01-01

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Effects of manganese doping on properties of sol-gel derived biphasic calcium phosphate ceramics

... interactive surfaces and interfaces, and 3) the more complex a ... carbonate or calcium phosphate with a thin interface ... diameter) for nerve prosthesis. ...

1990-03-01

4

British Library Electronic Table of Contents (United Kingdom)

We have investigated the effect of manganese (Mn) doping on properties of nanosized biphasic calcium phosphate powders and their dense bodies. Manganese levels of 0.6, 1.3, 1.9, 4.3, 7.0 and 11.9at.% were successfully incorporated into biphasic calcium phosphate via a sol-gel route. The prepared powders were calcined at temperatures of 500-1200^oC. The X-ray diffraction analysis revealed that a mix phase comprising of hydroxyapatite and @b-tricalcium phosphate were present, however the content of each phases in the structure was affected by the Mn content. The studies found that the largest portion of @b-tricalcium phosphate was detected at 4.3at.% Mn doping. The incorporation of Mn has also greatly increased the crystallinity of the biphasic calcium phosphate powder due to progressive den...

2011-01-01

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Modulation of B-cell endoplasmic reticulum calcium homeostasis by Epstein-Barr virus Latent Membrane Protein-1

Physicochemical basis for formation of renal stones of calcium phosphate origin: calculation of the degree of saturation of urine with respect to brushite

BackgroundCalcium signaling plays an important role in B lymphocyte survival and activation, and is critically dependent on the inositol-1,4,5-tris-phosphate-induced...Full Text Available

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Vectors containing a prokaryotic dihydrofolate reductase gene transform Drosophila cells to methotrexate-resistance.

Brushite (CaHPO₄·2H₂O) was considered to govern the formation of renal calculus of calcium phosphate origin. The degree of saturation of urine with respect to this phase...Full Text Available

1969-10-01

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Case series of maxillary sinus augmentation with biphasic calcium phosphate: a clinical and radiographic study

Transformed Drosophila Kc cell lines, resistant to methotrexate, an inhibitor of de novo purine and pyrimidine synthesis, have been obtained by calcium phosphate transfection of plasmids containing...Full Text Available

1983-01-01

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Simultaneous lowering of serum phosphate and LDL-cholesterol by sevelamer hydrochloride (RenaGel) in dialysis patients.

PurposeThe aim of this study was to evaluate 3.5 years-cumulative survival rate of implants placed on augmented sinus using Osteon, a bone graft material, and to assess the height...Full Text Available

2011-04-01

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The influence of amino acids on the biomineralization of hydroxyapatite in gelatin.

The aim of the current investigation was to study the effects of sevelamer hydrochloride (RenaGel) on serum phosphate, intact parathyroid hormone levels (iPTH), and lipid profiles in stable hemodialysis patients. Hemodialysis patients maintained on calcium containing phosphate binders were enrolled in this study. Following two weeks of washout of the phosphate binders, serum phosphate rose from 6.4 +/- 0.6 to 10.5 +/- 0.7 mg/dl (p <0.001). After 8 weeks of titration with sevelamer hydrochloride, serum phosphate fell by 4.5 +/- 0.3 to 6.3 +/- 0.7 mg/dl (p <0.0001). Serum calcium levels fell during washout (9.8 +/- 0.4 to 8.9 +/- 0.3 mg/dl, p <0.004) and were unaffected by sevelamer hydrochloride. Sevelamer hydrochloride administration was associated with a 23.0 +/- 3.1% fall in total cholesterol, a 35.9 +/- 3.0% fall in LDL ...

1998-12-01

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Calcium phosphate glass-ceramics for bioactive coating on a #beta#-titanium alloy

The effects of pH on the calcium phosphate phase, of Tris and of amino acids, such as aspartic acid, glutamic acid, and serine on hydroxyapatite formation and morphology, were studied in double diffusion experiments. In this system, hydroxyapatite was only formed when the pH was around 7.4 or higher for the duration of the reaction. A decrease in pH resulted in the transformation of hydroxyapatite to octacalcium phosphate. Amino acids and Tris or the buffering capacity of Tris have an effect on the morphology of the synthetic hydroxyapatite. The presence of the additive results in spheres consisting of needles, blades or plates depending on the reaction system. PMID:12175941

2002-08-30

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Use of Eu"3"+ as an oxygen environment probe in alkali-alkaline earth-lanthanide phosphates with the #beta#-K_2SO_4 structure

The formation of a porous coating is the decisive feature for the bio-compatibility of silica-free calcium phosphate glass ceramics on alloy surfaces like the #beta#-Ti structured Ti-29Nb-13Ta-4.6Zr used in this work. The ceramic composition is highly important: 50CaO-40P_2O_5-7Na_2O-3TiO_2 glass powder produces a pore-free coating unable to bind hydroxyapatite, whereas 60CaO-30P_2O_5-7Na_2O-3TiO_2 glass incorporates pores from which a crystalline hydroxyapatite phase can grow over the surface from simulated body fluid (see Figure). (Abstract Copyright [2003], Wiley Periodicals, Inc.)

2003-07-01

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Phase change characteristic study of spherical PCMs in solar energy storage

The use of europium as a local structural probe allows the various phases appearing in the NaCaPO_4-Na_3Eu(PO_4)_2 and NaSrPO_4-Na_3Eu(PO_4)_2 systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO_4 groups. (Auth.).

1983-09-01

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Development of non-phosphate detergent with zeolite and. alpha. -olefin sulfonate. Zeolite-AOS ni yoru senzai no murinka

This paper investigates the phase change behavior of 65 mol% capric acid and 35 mol% lauric acid, calcium chloride hexahydrate, n-octadecane, n-hexadecane, and n-eicosane inside spherical enclosures to identify a suitable heat storage material. Analytical models are developed for solidification and melting of sphere with conduction, natural convection, and heat generation. Both the models are validated with previous experimental studies. Good agreement was found between the analytical predictions and experimental study and the deviations were lesser than 20%. Heat flux release at the wall, cumulative energy release to the external fluid, are revealed for the best PCM. The influence of the size of encapsulation, initial temperature of the PCM, the external fluid temperature on solidified and molten mass fraction, and the total phase change time are also investigated. (author)

2009-08-15

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The process for recovery of uranium from dam waste water

Development was explained of non-phosphate detergent with zeolite (Z) and alpha-olefin sulfonate (AOS). 4A type Z was taken notice of as a builder to replace phosphate. In calcium ion trapping power, conventional sodium tripolyphosphate (STP) and Z are 158mgCaO/g and 150mg/g, respectively. However, because Z by the conventional method is large in crystal diameter, coagulates and adheres to matter to be washed, was newly developed fine Z, 0.9 {mu} m in primary grain diameter, which does not give abrasion nor occlusion to the washing machine, nor precipitate in the river. Because linear alkylbenzene sulfonate, combined with Z, is poorer in washing power than that, done with STP, was developed AOS, new non-phoshate use interfacial active detergent, which is excellent in all washing power, biodegradation speed and physical powder property. Improvement was variously made also in powdery detergent production technology. Though ...

1990-07-01

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Human tooth enamel dissolution in citric acid as a function of degree of saturation and pH

For the treatment of dam waste water containing micro quantities of uranium, the so-called chemical precipitation method is conventionally used, that is, acidic sodium phosphate is added to it and so the uranium (UO_2"2"+) is removed in coprecipitation with the then occurring calcium phosphate (solid). The method, however, has several problems, such as the large space required and large quantities of sludge. For the pupose of eliminating such difficulties and removal and recovery of the uranium, development of the new uranium adsorption method was started. Of the many uranium adsorbents available, excellent ones were selected and then the continuous treatment test was made with small apparatus. Subsequently, the dam waste water uranium recovery facility was completed in 1983. (Mori, K.).

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Use of Eu/sup 3 +/ as an oxygen environment probe in alkali-alkaline earth-lanthanide phosphates with the. beta. -K/sub 2/SO/sub 4/ structure

There is increasing concern among the dental community regarding the damage caused to teeth by the acids in soft drinks. Enamel dissolution in acidic solution can be reduced by addition of calcium and/or phosphate salts to increase the degree of saturation with respect to hydroxyapatite (DS sub H sub A), or by an increase in pH. In soft drinks, however, both of these approaches are associated with a reduced taste quality. The separate effects of each parameter are not known. In the work presented here, enamel dissolution was studied in citric acid solutions with compositions typical of soft drinks. Nanoindentation and atomic force microscopy (AFM) were used to investigate very early stages of enamel dissolution, with typical exposure times of 30-600 s. Preliminary investigations of the application of SIMS, ESEM and XPS to enamel dissolution studies are also reported. The individual effects of DS sub H sub A , pH and calcium ...

2002-01-01

17

Selective detection of hexachromium ions by localized surface plasmon resonance measurements using gold nanoparticles/chitosan composite interfaces.

The use of europium as a local structural probe allows the various phases appearing in the NaCaPO/sub 4/-Na/sub 3/Eu(PO/sub 4/)/sub 2/ and NaSrPO/sub 4/-Na/sub 3/Eu(PO/sub 4/)/sub 2/ systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO/sub 4/ groups.

1983-09-15

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Experimental investigation on denting in PWR steam generators: causes and corrective actions

Selective removal of hexavalent chromium ions from aqueous solutions using a chitosan/gold nanoparticles composite film was demonstrated. Localized surface plasmon resonance (LSPR) was used to measure the interface stability and detect the incorporation of chromium ions over time. The effects of pH, ethylenediaminetetraacetic acid (EDTA), and various foreign ions such as trivalent chromium, sodium, calcium, phosphate, sulfate and chloride on the adsorption of hexavalent chromium were investigated. PMID:19381379

2009-03-04

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Experimental investigation on denting in PWR steam generators, causes and corrective actions

Denting studies have been undertaken in order to assess the influence of the most important parameters which could initiate corrosion of the carbon steel occurring in the tube-tube support plate crevices of some PWR steam generators. Tests have been carried out in model boilers where feedwater was polluted with sea or river water. Specific effects of chloride or sulfate and influence of oxygen content, magnetite addition and pH value were investigated. In magnetite prepacked crevices, denting is obtained within 1000 hrs for seawater pollution of 0.3 ppm chloride at the blowdown. In neutral chloride or in river water, denting is observed only with oxygen addition. Denting prevention is effective in the case of an on-line addition of phosphate, boric acid, or calcium hydroxide. For denting stopping, boric acid or calcium hydroxide is efficient even with a high seawater pollution. Soaks cannot stop denting if they are not ...

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Space Radiation Detector with Spherical Geometry

Denting studies have been undertaken in order to assess the influence of the most important parameters which could initiate corrosion of the carbon-steel occurring in the tube-tube support plate crevices of some PWR steam generators. Tests have been carried out in model boilers, feedwater being polluted with sea or river water. Specific effect of chloride or sulfate and influence of oxygen content, magnetite addition and pH value were investigated. In magnetite prepacked crevices, denting is obtained within 1000 hours for sea-water pollution of 0.3 ppm chloride at the blowdown. In neutral chloride or in river water denting is observed only with oxygen addition. Denting prevention is effective in the case of an on-line addition of phosphate, boric acid or calcium hydroxide. For denting stopping, boric acid or calcium hydroxide is efficient even with a high sea-water pollution. Soaks cannot stop denting if they are not ...

1985-03-01

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Semi-empirical simulation of thermoluminescent response under different filter geometries; Simulacao semi-empirica da resposta termoluminescente sob diferentes geometrias de filtro

A particle detector is provided, the particle detector including a spherical Cherenkov detector, and

2011-01-01

22

Difference in the effects produced by non-radioactive and radioactive calcium

Many thermoluminescent materials has been developed and used for photon personal dosimetry but no one has all desired characteristics alone. These characteristics include robustness, high sensitivity, energy photon independence, large range of photon energy detection, good reproducibility, small fading and simple glow curve with peaks above 150 deg C. Calcium Sulfate Dysprosium doped (CaSO{sub 4}:Dy) phosphor Thermoluminescent Dosimeter (TLD) has been used by many laboratories, mainly in Brazil and India. Another interesting phosphor is Calcium Fluoride (CaF{sub 2}). These phosphor advantages begin to be more required and its disadvantages have became more apparent, in a global market more and more competitive. These phosphors are used in environmental and area monitoring, once they present more sensibility than other phosphors, like LiF:Mg. Theirs mainly disadvantage is a strong energetic dependence response, which must be corrected for theirs ...

2006-07-01

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Biphasic calcium sulfate dihydrate/iron-modified alpha-tricalcium phosphate bone cement for spinal applications: in vitro study

... aluminum calcium calcium 45 cations citric acid corrosion inhibition radiation

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Effects of Calcium Supplementations on Mineral Metabolism during Pregnancy with Calcium-Deficient Young Adult Rats

In this study, the cytocompatibility of new 'iron-modified/alpha-tricalcium phosphate (IM/alpha-TCP) and calcium sulfate dihydrate (CSD)' bone cement (IM/alpha-TCP/CSD-BC) intended for spinal applications has been approached. The objective was to investigate by direct-contact osteoblast-like cell cultures (from 1 to 14 days) the in vitro cell adhesion, proliferation, morphology and cytoskeleton organization of MG-63 cells seeded onto the new cements. The results were as follows: (a) quantitative MTT-assay and scanning electron microscopy (SEM) showed that cell adhesion, proliferation and viability were not affected with time by the presence of iron in the cements; (b) double immunofluorescent labeling of F-actin and alpha-tubulin showed a dynamic interaction between the cell and its porous substrates sustaining the locomotion phenomenon on the cements' surface, which favored the colonization, and confirming the ...

2010-04-15

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Effect of nitric oxide on endoplasmic reticulum calcium homeostasis, protein synthesis and energy metabolism

Full Text Available

2003-06-01

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Modeling of Fission Neutrons as a Signature for Detection of Highly Enriched Uranium

ATPase, endoplasmic reticulum, calcium, ischaemia

2000-01-01

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Evaluation of chitosan/beta-tricalcium phosphate microspheres as a constituent to PMMA cement.

We present the results of modeling intended to evaluate the feasibility of using neutrons from induced fission in highly enriched uranium (HEU) as a means of detecting clandestine HEU, even when it is embedded in absorbing surroundings, such as commercial cargo. We characterized radiation from induced fission in HEU, which consisted of delayed neutrons at all energies and prompt neutrons at energies above a threshold. We found that for the candidate detector and for the conditions we considered, a distinctive HEU signature should be detectable, given sufficient detector size, and should be robust over a range of cargo content. In the modeled scenario, an intense neutron source was used to induce fissions in a spherical shell of HEU. To absorb, scatter, and moderate the neutrons, we place one layer of simulated cargo between the source and target and an identical layer between the target and detector. The resulting neutrons and gamma rays are resolved in both time ...

2004-03-09

28

Selectivity of lithium isotopes on semicrystalline titanium (IV) phosphate

Two methods, a traditional emulsion technique and a high voltage electrostatically modified encapsulation system, were used to fabricate degradable chitosan/beta -tricalcium phosphate (beta-TCP) microspheres. The two distinct kinds of microspheres both exhibited good sphericity and the beta-TCP was trapped well inside the chitosan gel. The microspheres prepared by high voltage electrostatic system exhibited a rougher outer surface and narrower size distribution. These microspheres were then used as an added constituent to commercially available PMMA bone cement. Four modified cement composites that were prepared with different composition ratios of the two kinds of chitosan/beta-TCP microspheres that were made from emulsion technique (C1P1 and C2P1) and from a process by a high voltage electrostatic system (EC1P1 and EC2P1) were compared with the PMMA cement (Pure P). The characteristics of these materials indicate that with the addition of ...

2005-06-01

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Regulation and Function of Escherichia coli Sugar Efflux Transporter A (SetA) during Glucose-Phosphate Stress?

No abstract prepared.

2001-01-01

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Health-hazard evaluation report HETA 85-354-1872, Asarco, Denver, Colorado

Accumulation of certain nonmetabolizable sugar-phosphates (including α-methyl glucoside-6-phosphate) in Escherichia coli is growth inhibitory and elicits the glucose-phosphate...Full Text Available

2011-01-01

31

Drying characteristics and nitrogen loss of biogas digestate during drying process

An evaluation was made of possible hazardous working conditions at the ASARCO Globe facility, Denver, Colorado. The facility was involved in the recovery of cadmium from baghouse dust, a waste byproduct of nonferrous smelters. A medical study of kidney function was conducted in 45 current or former cadmium production workers; results were compared to those for 35 hospital workers. Kidney abnormalities were more common and more severe in the cadmium workers than in the hospital workers. Abnormalities of proximal tubular function included reduced reabsorption of beta-2-microglobulin, retinol binding protein, calcium and phosphate. Glomerular dysfunction was evidenced as elevated serum creatinine. As length of exposure to cadmium increased, changes became more apparent in workers. No reversal of the conditions was noted in workers who had ceased to be exposed to cadmium some time before the study. The authors conclude that occupational ...

1988-02-01

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Augmented behavioral response and enhanced synaptosomal calcium transport induced by repeated cocaine administration are decreased by calcium channel blockers

The cost of transporting biogas digestate can be decreased by reducing its water content. However, the digestate emits volatile compounds during drying. This study investigated the drying behaviour and the change of digestate composition. Drying took place in a hybrid solar/waste-heat dryer that used solar energy as well as waste heat from a combined heat and power unit (CHP) and the exhaust air of a microturbine. The experiment involved the use of 60 t of liquid digestate. Climatic conditions were measured inside and outside the drying hall. Dry matter (DM) and organic dry matter (ODM) were also measured on a daily basis. In addition, the energy consumption of waste and solar heat were recorded and related to the quantity of dried feedstock. The total nitrogen, ammonium, phosphate, potassium oxide, magnesium oxide and calcium oxide in the digestate were subjected to chemical analysis before and after the drying process. Losses of nitrogen were ...

2010-07-01

33

Analyses of uranium in some phosphate commercial products

Recent studies suggest that calcium influx via L-type calcium channels is necessary for psychostimulant-induced behavioral sensitization. In addition, chronic amphetamine upregulates subtype...Full Text Available

2007-07-26

34

Spherical harmonic operator method of solving the transport equation in curvilinear coordinates. Application to #gamma#-theta geometry

The raw materials used in manufacturing of phosphate fertilizer products were derived from rocks. Rocks contain a remarkable of natural radioactivity. Uranium and phosphorous were originally initiated at the same time of the initiated rocks. The purpose of this research is to investigate solubility of uranium phosphate species at the phosphate fertilizer samples, samples including; raw phosphate material, single super phosphates (SSP) granules and powdered, triple super phosphates (TSP) and phosphogypsum samples were obtained from Abu-Zabal factory in Egypt. Solubility of uranium phosphate species was estimated. It was found that, less than half of the uranium phosphate species are soluble in water. The soluble uranium may be enter into the food chains by plant. Therefore, restriction should be done in order to limit ...

2004-02-24

35

EXTERNAL GELATION METHOD FOR MANUFACTURING SPHERICAL NUCLEAR FUEL PARTICLE

An explicite PN solution of the multi-dimensional homogeneous neutron transport equation is given by expanding the angular flux into a series of geometry-independent spherical harmonics operators. An algorithm is developed for representing the spherical harmonic operators in orthogonal curvilinear coordinates. The general formulae are applied to two-dimensional spherical geometry; detailed P3 formulae are given. (orig.).

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J-STORE (Japan)

Full Text Available

2006-05-19

37

Discontinuous Galerkin Finite Element Method applied to the 1-D Spherical Neutron Transport Equation

Cold Thermal Energy Storage Characteristics of Spherical PCM Capsule

No abstract prepared.

2005-11-07

38

On the Approach to Spherical Harmonics by Maxwell, Thomson and Tait

Full Text Available

2008-10-01

39

Retardation of Bean Leaf Senescence by Benzyladenine and Its Influence on Phosphate Metabolism ¹

We present a unified self-consistent review of the approach to spherical harmonics developed in the second half of the 19th century by Maxwell and by Thomson and Tait. We remark how this spherical coordinate-free approach straightforwardly leads to physically very important results of the theory of solid and surface harmonics which become rather tedious to work out when using spherical coordinates and associated Legendre functions. These results include, among others, the addition theorem, spherical wave expansions, the construction of the standard set of normalized spherical harmonics, Y_lm - together with their rotational properties-, and recursion relations. We provide new proofs for Maxwell's theorem, the addition theorem and Hobson's theorem, respectively, using in the latter some elementary notions of the symbolic techniques proper of the theory of invariants. Also, we give an ...

2008-01-01

40

Methane conversion process using phosphate-containing catalysts

The levels of glucose, sugar phosphates, and adenosine phosphates were determined in primary leaves of intact bean plants during normal senescence and compared to leaves in which senescence was delayed...Full Text Available

1970-10-01

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Isozymes of the Glycolytic Enzymes in Endosperm from Developing Castor Oil Seeds ¹

A process is described for covering methane to a higher order hydrocarbon comprising contacting a gaseous reactant consisting of methane with a phosphate-containing catalyst for a sufficient period of time and at an effective temperature to provide the phosphate-containing catalyst consisting essentially of the higher order hydrocarbon. The catalyst is represented by a formula.

1987-05-12

42

Disturbance of inorganic phosphate metabolism in diabetes mellitus: temporary therapeutic intervention trials

Ion filtration chromatography on diethylaminoethyl-Sephadex A-25 has been used to separate two isozymes each of triose phosphate isomerase, glyceraldehyde 3-phosphate dehydrogenase, glycerate 3-phosphate...Full Text Available

1982-04-01

43

Carbon tetrachloride-induced release of calcium from isolated hepatocytes

A paradoxical metabolic imbalance in inorganic phosphate occurs from the early onset of diabetes and may lead to a reduction of high energy phosphates and tissue hypoxia. These changes take place in...Full Text Available

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Iodination of glyceraldehyde 3-phosphate dehydrogenase

Studies have shown that CCl_4 administration to rats inhibits endoplasmic reticulum calcium pump activity and reduces the amount of calcium associated with subsequently isolated microsomal subcellular fractions. This report confirms that exposure of isolated hepatocytes to CCl_4 rapidly produces these effects in isolated parenchymal cells and demonstrates that when isolated hepacytes are exposed to CCl_4 calcium is rapidly released from cells. This release can be detected with a calcium ion-selective electrode when cells are incubated in a medium with low extracellular calcium. Calcium released from an intracellular pool(s) may initiate hepatotoxic changes in liver. (author).

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1. A high degree of homology in the positions of tyrosine residues in glyceraldehyde 3-phosphate dehydrogenase from lobster and pig muscle, and from yeast, prompted an examination of the reactivity...Full Text Available

1970-09-01

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Uranium phosphates

The harmful effect of phosphate in yellow cake on the TBP purification process

Methods of preparation, stability in solutions and in the solid phase, composition of orthophosphate crystallohydrates and condensed uranyl- and uranium (4) phosphates, are considered. Structures of these compounds are discussed; it is shown that they are steric polymers with an uranylphosphate framework. The problem of phosphate-anion polymerization in the process of thermal decomposition is discussed. It is established that condensed uranyl polyphosphates are not stable during storage, capable of degradation, its degree increasing with the phosphate chain length and uranium content.

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THE CONTENT OF ADENINE NUCLEOTIDES AND ...

The harmful effect of phosphate in yellow cake on the TBP purification process and its removal methods are dealed with. The reason of more uranium loss in residue was analyzed. The harmful effect of phosphate on TBP extraction efficiency and operaton of extraction column was discussed. The limit value of uranium concentration in digestion solution was presented. For TBP purification process, the presence of phosphate in yellow cake does more harm than good. (authors)

2009-02-01

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Kinetics of chlorination of phosphates of actinides and fission elements in chloride melts. II. Zirconium phosphates

... Accession Number : AD0262144. Title : THE CONTENT OF ADENINE NUCLEOTIDES AND CREATINE PHOSPHATE IN BRAIN. ...

1961-05-01

49

Spatiotemporal intracellular calcium dynamics during cardiac alternans

The kinetics of the reaction of zirconium phosphates with carbon tetrachloride in sodium and potassium chloride melt as well as the effect of temperature, gas flow, solubility and weight of the solid phase of the phosphate, and stirring of the melt on the chlorination rate has been studied. The kinetic parameters of the reaction (rate constants, activation energy, etc.) have been calculated.

1987-07-01

50

Sodium/Calcium Exchangers Selectively Regulate Calcium Signaling in Mouse Taste Receptor Cells

Cellular calcium transient alternans are beat-to-beat alternations in the peak cytosolic calcium concentration exhibited by cardiac cells during rapid electrical stimulation or under pathological conditions....Full Text Available

2009-09-01

51

Role of plasma membrane calcium ATPase 2 in spinal cord pathology

Taste cells use multiple signaling mechanisms to generate appropriate cellular responses to discrete taste stimuli. Some taste stimuli activate G protein coupled receptors (GPCRs) that cause calcium...Full Text Available

2010-07-01

52

Hypertrophy and Heart Failure in Mice Overexpressing the Cardiac Sodium-Calcium Exchanger

A number of studies have indicated that plasma membrane calcium ATPases (PMCAs) are expressed in the brain and spinal cord and could play important roles not only in the maintenance of cellular calcium...Full Text Available

2010-05-26

53

Demographic, Dietary, and Urinary Factors and 24-h Urinary Calcium Excretion

Background:The cardiac sodium–calcium exchanger (NCX1) is a key sarcolemmal protein for the maintenance of calcium homeostasis in the heart. Since heart failure...Full Text Available

2007-05-01

54

Calcium Requirements and Metabolism in Chinese-American Boys and Girls

Background and objectives: Higher urinary calcium is a risk factor for nephrolithiasis. This study delineated associations between demographic, dietary, and urinary factors and 24-h urinary calcium.Design,...Full Text Available

2009-12-01

55

Effect of calcium and phosphorus on the gastrointestinal absorption of /sup 203/Pb in man

Calcium requirements of North American adolescents were set at 1300 mg/day based on data from white girls. Calcium requirements for Asian-American adolescents have not been studied. Using metabolic...Full Text Available

2010-08-01

56

Adsorption of phosphate from aqueous solution using activated red mud

Calcium and phosphorus were mainly responsible for reducing the gastrointestinal absorption of lead in human subjects. The effect of calcium was greater than phosphorus, and their combined effect was more than additive. Increasing weights of calcium and phosphorus progressively reduced lead absorption. The relationship between absorption and increasing weights could be described by two negative exponentials. These effects could be explained if lead competed with calcium and phosphorus for common transport mechanisms in the gut. Milk was also found to reduce lead absorption. Adding milk to the diet of people with low dietary calcium intake could reduce the possibility of increased absorption of ingested lead.

1983-02-01

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Numerical optimization of spherical variable-line-spacing grating X-ray spectrometers

Adsorption of phosphate (PO{sub 4}{sup 3{minus}}) from aqueous solution on activated red mud (ARM) was studied as a function of time, pH, temperature, concentration of adsorbent and adsorbate in acetic acid-sodium acetate buffer medium. The adsorption of phosphate follows Langmuir as well as Freundlich adsorption isotherms. The process efficiency was found to be 80--90% at room temperature. This can be extended to the treatment of industrial effluents containing phosphates like that from phosphatic fertilizer plants.

1998-08-01

58

Refilling Intracellular Calcium Stores

Operation of an X-ray spectrometer based on a spherical variable-line-spacing (VLS) grating is analyzed using dedicated ray-tracing software allowing fast optimization of the grating parameters and...Full Text Available

2011-03-01

59

Calcium-Actin Waves and Oscillations of Cellular Membranes

Within the cardiac cell, the movements of calcium ions are tightly regulated by a number of regulatory proteins including pumps, and channels. The sarcoplasmic reticulum (SR) is in large part...Full Text Available

2010-01-01

60

Assignment of the {sup 1}H, {sup 15}N and{sup 13} C resonances of the calcium-free and calcium-bound forms of the first C{sub 2}-domain of synaptotagmin I

AbstractWe propose a mechanism for the formation of membrane oscillations and traveling waves, which arise due to the coupling between the actin cytoskeleton and the calcium flux through...Full Text Available

2009-09-16

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Rapid determination of "2"3"7Np and Pu isotopes in water by inductively-coupled plasma mass spectrometry and alpha spectrometry

No abstract prepared.

1997-10-15

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RAPID DETERMINATION OF 237 NP AND PU ISOTOPES IN WATER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY

A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of "2"3"7Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry. "2"3"8U can interfere with "2"3"9Pu measurement by ICP-MS as "2"3"8UH"+ mass overlap and "2"3"7Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and ...

2011-01-01

63

Liquid radwaste processing with spiral wound reverse osmosis

A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and ...

2010-06-23

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Investigating the applicability of anions as indicators for verification of consistency of declarations

Two different reverse osmosis systems were investigated. The first was a 50-element plant-scale system that is used to treat 2200 m"3 of AECL liquid radwastes annually.It uses thin-film composite (TFC) membranes and operates at an applied pressure of 2760 kPa, with a fixed crossflow of about 40 L/min. The other system uses the same thin-film composite membranes for waste processing but is a two-element pilot-scale system. It is operated at pressures m ranging between 1500 and 7000 kPa, at a fixed crossflow of 55 L/min. The average lifetime of the thin-film composite membranes in the plant-scale processing application at AECL is about 3000 h. After this service life has expired the rejection efficiency declines rapidly from 99.5% to about 95% as the membranes become impaired from chemical cleaning procedures that are required after each 100 m"3 of waste is treated. The permeation flux for the plant-scale system decreases from about 2.2 L/min/element to below 0.5 L/min/element at the end ...

1996-02-25

65

High extracellular calcium attenuates adipogenesis in 3T3-L1 preadipocytes

Full text: Nuclear material is subjected to chemical processing throughout the entire fuel cycle. Traces of the chemical reagents and solvents are left behind in the nuclear material. So far essentially metallic impurities or light elements have been investigated for their potential in providing clues on the type of process they originate from. In the present investigation, the applicability of anions for attributing nuclear material to a certain chemical process has been investigated. Anions (e.g. nitrate, sulphate, phosphate, chloride) originate from acids or salt solutions that are used for processing of solutions containing uranium or plutonium. The study presented in this paper focuses on yellow cake samples originating from different mines applying different chemical processes for leaching, dissolving and precipitating the uranium. Consequently, the anionic patterns should be different. The concentrations of different anionic species were measured by ion ...

2006-10-16

66

Creation of bony microenvironment with CaP and cell-derived ECM to enhance human bone-marrow MSC behavior and delivery of BMP-2.

We studied the effect of extracellular Ca"2"+ concentration ([Ca"2"+]_e) on adipocyte differentiation. Preadipocytes exposed to continuous [Ca"2"+]_e higher than 2.5 mmol/l accumulated little or no cytoplasmic lipid compared to controls in 1.8 mmol/l [Ca"2"+]_e. Differentiation was monitored by Oil Red O staining of cytoplasmic lipid and triglyceride assay of accumulated lipid, by RT-PCR analysis of adipogenic markers, and by the activity of glycerol-3-phosphate dehydrogenase (GPDH). Elevated [Ca"2"+]_e inhibited expression of peroxisome proliferator-activated receptor #gamma#, CCAAT/enhancer binding protein #alpha#, and steroid regulatory binding element protein. High [Ca"2"+]_e significantly inhibited differentiation marker expression including adipocyte fatty acid binding protein, and GPDH. The decrease in Pref-1 expression that accompanied differentiation also was prevented by high [Ca"2"+]_e. Treatment of 3T3-L1 cells with high [Ca"2"+]_e did not significantly ...

2004-12-10

67

Test particle moving in an interior static spherically symmetric geometry

Extracellular matrix (ECM) comprises a rich meshwork of proteins and proteoglycans, which not only contains biological cues for cell behavior, but is also a reservoir for binding growth factors and controlling their release. Here we aimed to create a suitable bony microenvironment with cell-derived ECM and biodegradable ?-tricalcium phosphate (?-TCP). More specifically, we investigated whether the ECM produced by bone marrow-derived mesenchymal stem cells (hBMSC) on a ?-TCP scaffold can bind bone morphogenetic protein-2 (BMP-2) and control its release in a sustained manner, and further examined the effect of ECM and the BMP-2 released from ECM on cell behaviors. The ECM was obtained through culturing the hBMSC on a ?-TCP porous scaffold and performing decellularization and sterilization. SEM, XPS, FTIR, and immunofluorescent staining results indicated the presence of ECM on the ?-TCP and the amount of ECM increased with the incubation time. BMP-2 was loaded onto ...

2011-05-31

68

Ultraviolet dosimetry characterization from calcium doped borate glass-ceramic

The motion of a test particle moving in an interior static spherically symmetric geometry is investigated. The author concludes that an oscillatory motion with the test particle changing its motion from a free fall towards the center to an outward radial motion can not exist for any static interior spherically symmetric model.

1984-06-01

69

The extracellular calcium sensing receptor is expressed in mouse mesangial cells and modulates cell proliferation.

No abstract prepared.

2006-07-01

70

Structure and Function of NtCDPK1, a Calcium-dependent Protein Kinase in Tobccco

Full Text Available

2005-10-01

71

Phosphorus and calcium homeostasis in chronic subtotally nephrectomized parathyroidectomized rats.

Full Text Available

2000-05-01

72

Method of studying the SIALON wetting with oxides of silicon, aluminium, calcium and titanium

Full Text Available

73

Intracellular Calcium Concentration in the Glutamate-induced Cytotoxicity in PCl2 Cell

Short communication.

1993-10-04

74

Impairing Effects of Acute Glucose Overload on Calcium Homeostasis in Vascular Endothelial Cells

Full Text Available

2002-12-01

75

Effects of Ca Supplementation on Mineral Metabolism during Pregnancy and Lactation of Calcium-Deficient Young Adult Rats

Full Text Available

1998-12-01

76

Cytosolic Calcium Alteration and Cell Injury by Silica in Rat Hepatocytes

Full Text Available

2004-07-01

77

Comment on "Calcium bisulfite oxidation rate in the wet limestone--gypsum flue gas desulfurization process".

Full Text Available

1998-12-01

78

Calcium-influx increases SOD1 aggregates via nitric oxide in cultured motor neurons.

PMID:11506019

2001-08-01

79

Advancing Age Alters the Contribution of Calcium Release From Smooth Endoplasmic Reticulum Stores in Superior Cervical Ganglion Cells

Full Text Available

2007-10-01

80

Characteristics of diethylenetriamine-crosslinked cotton stalk/wheat stalk and their biosorption capacities for phosphate

In superior cervical ganglion (SCG) neurons calcium-induced calcium release (CICR), mediated by ryanodine receptors (RyRs), contributes to stimulation-evoked intracellular calcium ([Ca²⁺]_i)...Full Text Available

2009-01-01

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81

British Library Electronic Table of Contents (United Kingdom)

Two polymeric biosorbents were prepared from cotton stalk (CS) and wheat straw (WS) by the epichlorohydrin-diethylenetriamine-trimethylamine method. Amine-crosslinked cotton stalk (AC-CS) and wheat stalk (AC-WS) were used for the adsorption of phosphate, and their physicochemical properties as well as biosorption properties for phosphate were discussed intensively. Results indicated that the contents of holocellulose in CS and WS corresponded to the distinct phosphate adsorption capacities between AC-CS and AC-WS. Zeta potential and Raman spectra analysis illustrated the electrostatic attraction between phosphate ions and biosorbents. The adsorption of phosphate was not strongly pH dependent when the pH was about 4.0-9.0. The Langmuir isotherm provided the better fit and the maximum adsorp...

2011-01-01

82

Carbon dioxide absorption mechanisms of sodium added to calcium oxide at high temperatures

Two tandemly linked identical genes code for the glycosomal glyceraldehyde-phosphate dehydrogenase in Trypanosoma brucei.

To apply the CO{sub 2} absorber at about 1000{sup o}C for integrated coal gasification combined cycle (IGCC) furnace, the reactions of calcium oxide and CO{sub 2} at high temperatures was examined. Calcium carbonate reacts with sodium hydrogen carbonate below 200{sup o}C and forms sodium-calcium complex carbonate. The sodium-calcium complex carbonate melts at 813{sup o}C, and the carbon dioxide absorption and discharge reversible reactions of calcium-oxide takes place via liquid at around 1000{sup o}C. Sintering of calcium oxide at high temperature has been successfully avoided by the addition of sodium.

2004-07-01

83

Trypanosoma cruzi glycosomal glyceraldehyde-3-phosphate dehydrogenase does not conform to the 'hotspot' topogenic signal model.

Trypanosoma brucei contains two isoenzymes for glyceraldehyde-phosphate dehydrogenase (GAPDH); one enzyme resides in a microbody-like organelle, the glycosome, the other one is found in the cytosol....Full Text Available

1986-05-01

84

Triosephosphates Modulate Leaf Mitochondrial Phosphorylation by Inhibition and Uncoupling of Electron Transport ¹

The genes which encode glycosomal glyceraldehyde-phosphate dehydrogenase (gGAPDH) of Trypanosoma cruzi are arranged as a tandemly repeated pair on a single chromosome and are identical at the level...Full Text Available

1990-09-01

85

The comparative structure of mammalian glyceraldehyde 3-phosphate dehydrogenase

The effect of TP (triosephosphates:glyceraldehyde-3 phosphate, GAP, +dihydroxyacetone phosphate, DHAP) on respiration, phosphorylation and matrix ATP/ADP ratios of isolated oat mesophyll mitochondria...Full Text Available

1985-11-01

86

Phosphate/UO{sub 2} interaction during in vitro dissolution of inhalable particles in a medium simulating the phagolysosomal compartment

1. The amino acid sequences around the thiol groups of glyceraldehyde 3-phosphate dehydrogenase from badger and monkey skeletal muscle were compared with the sequences around the thiol groups in the...Full Text Available

1969-01-01

87

On the water-chemical regime in steam generators at NPP

Qualitative and quantitative methods have been developed to relate phosphate/UO{sub 2} interactions and U dissolution, in vitro, in a medium containing 0 or 10 mM phosphate concentrations at pH 5. This was performed by Energy Dispersive X ray Spectrometry (EDS) at 200 kV on entire particles and by fluorimetric measurement. The U dissolution rate was larger in a medium without phosphate than in a medium containing 10 mM phosphate. During the first day, the initial U dissolution involved 80.55% and 91.13% of the powder in media with and without phosphate respectively. From 5 to 15 d after beginning the assay, the dissolution half-times were longer than 92 d and 22 d for media with and without phosphate. EDS analyses have shown a constant P/U X ray intensity ratio for reference U{sub 2}O(PO{sub 4}){sub 2} for the same range of particle diameter. A gradual increase ...

1998-07-01

88

British Library Electronic Table of Contents (United Kingdom)

The effect of the water-chemical regime (WCR) on damage sustained by heating surfaces of steam generators at NPP is analyzed. It is indicated that phosphate treatment with minimal excesses of phosphates in the steamgenerator water is the most optimal method of managing the WCR regime of horizontal steam generators.

2006-01-01

89

Kinetic Properties of Pyrophosphate:Fructose-6-Phosphate Phosphotransferase from Germinating Castor Bean Endosperm 1

Isoenzymes of Sugar Phosphate Metabolism in Endosperm of Germinating Castor Beans ¹

Pyrophosphate:fructose-6-phosphate phosphotransferase (PFP) was purified over 500-cold from endosperm of germinating castor bean (Ricinus commiunis L. var. Hale). The kinetic properties...Full Text Available

1984-02-01

90

Iodination of glyceraldehyde 3-phosphate dehydrogenase from Bacillus stearothermophilus.

Two isoenzymes each of phosphoglucomutase, hexose phosphate isomerase, aldolase, fructose diphosphatase, phosphofructokinase, and 6-phosphogluconate dehydrogenase have been separated by DEAE-cellulose...Full Text Available

1981-06-01

91

Effects of norepinephrine infusion on myocardial high-energy phosphate content and turnover in the living rat.

The reaction of iodine with glyceraldehyde 3-phosphate dehydrogenase from Bacillus stearothermophilus was investigated. The active-site thiol group of the cysteine residue homologous with cysteine-149...Full Text Available

1976-06-01

92

Complete sequence of the chicken glyceraldehyde-3-phosphate dehydrogenase gene.

Using 31P-nuclear magnetic resonance, we studied the relationship between myocardial high-energy phosphate content and flux values for the creatine kinase reaction in the living rat under inotropic...Full Text Available

1987-06-01

93

Apoferritin Templated Synthesis of Metal Phosphate Nanoparticle Labels for Electrochemical Immunoassay

Glyceraldehyde-3-phosphate dehydrogenase (GAPDH), an evolutionarily conserved glycolytic enzyme, is constitutively expressed in most cell types yet is induced to high levels during the development of...Full Text Available

1985-03-01

94

Study on the use of zirconium phosphate for radioactive waste treatment

W have introduced template-synthesized metal phosphate nanoparticle labels for electrochemical immunoassay. Such use of an apoferritin template offers a simple and convenient route to prepare metallic nanoparticle labels for electrochemical immunoassays and avoid the complicated and time-consuming nanoparticle synthesis process (QD synthesis). Releasing metal ions from metal phosphate in an acetate buffer (pH 4.6) eliminates the harsh condition in the traditional metallic nanoparticle dissolution (e.g., strong acid dissolution of QDs and gold nanoparticles). This method is ultrasensitive and its DL is low to 77fM. The simultaneous detection of multiple protein targets is easily performed by using different metal phosphate nanoparticle labels (cadmium phosphate and lead phosphate). This approach can be extended to prepare multiple metal (such as zinc, lead, cadmium, copper, indium, ...

2006-08-29

95

Differential Effect of Homocysteic Acid and Cysteic Acid on Changes of Inositol Phosphates and $[Ca^{2+}]i$ in Rat Cerebellar Granule Cells

Zirconium phosphate was one of the earliest inorganic ion-exchange suggested for removing strontium and cesium from aqueous nuclear waste. This paper studied ionic exchange to remove Cs-137 and Sr-90 by using different cationic of zirconium phosphate. In this case the parameters studied were the effect of temperature and ion concentration to percent up take and distribution coefficients. It is also conducted the study on column experiments to determine the breakthrough curves for Cs-137 and Sr-90. The result showed the potential of use of zirconium phosphate in radioactive waste treatment. (author)

1998-12-01

96

Ammoxidation of methanol to produce hydrogen cyanide

Full Text Available

1998-02-01

97

The content of natural radioactive materials in phosphate fertilizers and their contribution to the radiation exposure of the human population

Promoted antimony phosphate oxide complexes are excellent catalysts for the ammoxidation of methanol to HCN especially at high methanol throughputs.

1985-04-16

98

Ribose metabolism and nucleic acid synthesis in normal and glucose-6-phosphate dehydrogenase-deficient human erythrocytes infected with Plasmodium falciparum.

The Ra, Th, and K-40 content of the most important phosphate fertilizers used and authorized in the FRG was determined by #gamma#-spectroscopy. The results, together with statistical data on the consumption and use of fertilizers, were used for an estimation of the contribution of #gamma#-radiation from phosphate fertilizers to the external population exposure in the FRG. (orig./AK).

1974-09-23

99

Microtiter plate assay for phosphate using a europium-tetracycline complex as a sensitive luminescent probe

The metabolism of pentose-phosphate was investigated in Plasmodium falciparum-infected normal and glucose-6-phosphate dehydrogenase (G6PD)-deficient human red blood cells in vitro. 5'-Phosphoribosyl-1-pyrophosphate...Full Text Available

1986-04-01

100

Spherical redshift distortions

A new luminescent europium probe is presented for the determination of phosphate (P) in microtiter plate format. The assay is based on the quenching of the luminescence of the europium-tetracycline (EuTc) 1:1 complex by phosphate using a reagent concentration of 20.8 {mu}mol/L. The probe is excited at 400 nm and displays a large Stokes' shift of 210 nm. The emission maximum is located at 616 nm. The system works best at neutral pH 7 and is therefore suitable for phosphate determination in biological and biochemical systems. The linear range of the calibration plot is from 5 x 10{sup -6} mol/L to 7.5 x 10{sup -4} mol/L of phosphate, and the limit of detection is 3 {mu}mol/L.

2006-01-12

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101

SPASE Resource Description - the VHO - NASA

Peculiar velocities induce apparent line of sight displacements of galaxies in redshift space, distorting the pattern of clustering in the radial versus transverse directions. On large scales, the amplitude of the distortion yields a measure of the dimensionless linear growth rate \\ff of fluctuations, which is related to the cosmological density \\Omega and the linear bias factor b in linearly biassed standard cosmology by \\ff \\approx \\Omega^{0.6} /b. To make the maximum statistical use of the data in a wide angle redshift survey, and for the greatest accuracy, the spherical character of the distortion needs to be treated properly, rather than in the simpler plane parallel approximation. In the linear regime, the redshift space correlation function is described by a spherical distortion operator acting on the true correlation function. It is pointed out here that there exists an operator, which is essentially the logarithmic derivative with ...

1995-01-01

102

Preliminary representation of world population by spherical harmonics.

The potentials of the spherical sensor and nearby conductors are controlled by ... Incoming data are continuously monitored by algorithms in the software to ... launched together with FM5 (Rumba) by a Soyuz-Fregat rocket from Baikonur. ...

103

Data - SPASE Resource Description

The geographical arrangement of people on the surface of the earth is approximated by a mathematical equation of 361 terms. This is a convenient form for comparison with other distributions and for...Full Text Available

1992-07-15

104

Removal of phosphate by mesoporous ZrO{sub 2}

Feb 23, 2011 ... The potentials of the spherical sensor and nearby conductors are ... Incoming data are continuously monitored by algorithms in the software to ..... together with FM6 (Salsa) by a Soyuz-Fregat rocket from Baikonur. ...

105

Apoferritin-Templated Yttrium Phosphate Nanoparticle Conjugates for Radioimmunotherapy of Cancers

A type of mesoporous ZrO{sub 2} was synthesized and its phosphate removal potential was investigated in this study. The adsorption isotherm, pH effect, ionic strength effect and desorption were examined in batch experiments. The adsorption data fitted well to the Langmuir model with which the maximum P adsorption capacity was estimated to be 29.71 mg P/g. The amount of phosphate adsorbed increased rapidly in the first 5 h and slowly towards the end of the run, suggesting the possible monolayer coverage of phosphate ions on the surface of the adsorbent. The phosphate adsorption tended to increase with a decrease of pH and an increase of ionic strength. A phosphate desorbability of approximately 60% was observed with 0.5 M NaOH, which indicated a relatively strong bonding between the adsorbed PO{sub 4}{sup 3-} and the sorptive sites on the surface of the adsorbent. The immobilization ...

2008-03-01

106

The role of calcium ions and calcium channel entry blockers in experimental ischemia-reperfusion-induced liver injury.

We report a templated-synthetic approach based on apoferritin to prepare radionuclide nanoparticle (NP) conjugates. Non-radioactive yttrium (89Y) was used as model target and surrogate for radioyttrium (90Y) to prepare the nanoparticle conjugate. The center cavity and multiple channel structure of apoferritin offer a fast and facile method to precipitate yttrium phosphate by diffusing yttrium and phosphate ions into the cavity of apofrritin, resulting a core-shell nanocomposite. The yttrium phosphate/apoferritin nanoparticle was functionalized with biotin for further application. The synthesized nanoparticle was characterized by transmission electron microscopy (TEM) and x-ray photoelectron spectroscopy (XPS). We found that the resulting nanoparticles were uniform in size, with a diameter of around 8 nm. We tested the pre-targeting capability of the biotin-modified yttrium phosphate/apoferritin ...

2008-05-01

107

The Functional Role of Calcineurin in Hypertrophy, Regeneration, and Disorders of Skeletal Muscle

Verapamil administered before treatment, but not after treatment, had a beneficial effect on a 90-minute warm ischemia-reperfusion rat liver injury model. The possible activation of proteases converting...Full Text Available

1991-02-01

108

Strategies for the uses of lanthanide NMR shift probes in the determination of protein structure in solutio. Application to the EF calcium binding site of carp parvalbumin.

Skeletal muscle uses calcium as a second messenger to respond and adapt to environmental stimuli. Elevations in intracellular calcium levels activate calcineurin, a serine/threonine phosphatase, resulting...Full Text Available

2010-01-01

109

Mapping the Spatiotemporal Dynamics of Calcium Signaling in Cellular Neural Networks Using Optical Flow

The homologous sequences observed for many calcium binding proteins such as parvalbumin, troponin C, the myosin light chains, and calmodulin has lead to the hypothesis that these proteins have homologous...Full Text Available

1980-10-01

110

Hair Mercury Negatively Correlates with Calcium Pump Activity in Human Term Newborns and Their Mothers at Delivery

An optical flow gradient algorithm was applied to spontaneously forming networks of neurons and glia in culture imaged by fluorescence optical microscopy in order to map functional calcium signaling...Full Text Available

2010-08-01

111

Effects of calcium supplementation on bone density in healthy children: meta-analysis of randomised controlled trials

BackgroundCalcium homeostasis is a known target of several environmental toxicants including lead and mercury.ObjectiveOur goal was to determine...Full Text Available

2008-02-01

112

Detrusor overactivity is associated with downregulation of large-conductance calcium- and voltage-activated potassium channel protein

Objectives To assess the effectiveness of calcium supplementation for improving bone mineral density in healthy children and to determine if any effect is modified by other factors and...Full Text Available

2006-10-14

113

Calcium, Vitamin D, VDR Genotypes, and Epigenetic and Genetic Changes in Rectal Tumors

Large-conductance voltage- and calcium-activated potassium (BK) channels have been shown to play a role in detrusor overactivity (DO). The goal of this study was to determine whether bladder outlet...Full Text Available

2010-06-01

114

Calcium - blood test: MedlinePlus Medical Encyclopedia

Calcium, vitamin D, exposure to sunshine, and vitamin D receptor (VDR) genotypes have been associated rectal cancer. We used data from 750 rectal tumors and 1,205 population-based...Full Text Available

2010-05-01

115

A Comparison between Quin-2 and Aequorin as Indicators of Cytoplasmic Calcium Levels in Higher Plant Cell Protoplasts ¹

Names Ca+2; Serum calcium; Ca++ References Wysolmerski JJ, Insogna KL. The parathyroid glands, hypercalcemia, and hypocalcemia. In: Goldman L, Ausiello D, eds. Cecil...

2011-08-30

116

17?-estradiol regulation of T-type calcium channels in gonadotropin-releasing hormone neurons

Assessment of the regulation of plant metabolism by the calcium ion requires a knowledge of its intracellular levels and dynamics. Technical problems have prevented direct measurement of the concentration...Full Text Available

1989-06-01

117

The Effect of Combined Estrogen/calcium Therapy on Bone Metabolism in Ovariectomized Rats I. A Study on Biochemical Parameters in Ovariectomized Rats

T-type calcium channels are responsible for generating low-threshold spikes that facilitate burst firing and neurotransmitter release in neurons. GnRH neurons exhibit burst firing, but the underlying...Full Text Available

2009-08-26

118

Smoke Compositions Based on Phosphorus

Full Text Available

1996-12-01

119

Binary systems containing magnesium chloride, calcium chloride and thorium tetrafluoride

... Both magnesium and aluminium phosphides are therefore potentially more efficient than either calcium or sodium phosphide. ...

1958-03-01

120

Russian (1972). USSR Desyatnik, VN Kurbatov, NN Raspopin, SP Trifonov,

1972-01-01

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121

Well preflush fluid

Removal of noxious contaminants from gas

This patent describes a preflush fluid for preventing lost circulation during the cementing of a well, the fluid consisting essentially of: (a) water; (b) about 10 to about 30 percent by weight of water (% BWOW) cement; (c) about 5 to about 30% BWOW calcium sulfate selected from the group consisting of calcium sulfate hemihydrate, calcium sulfate dihydrate, and mixtures thereof; and (d) an alkali metal-containing quick-hardening accelerator.

1992-01-21

122

Calcium fluoride window mounting

Gas contaminated with at least one noxious component, such as SO/sub 2/, HF or NOx, is scrubbed with a clear, calcium-containing, initially-basic washing liquid which also comprises the anion of a strong inorganic acid, that of a polybasic carboxylic acid and, optionally, that of a monobasic carboxylic acid. Apparatus is provided for scrubbing the gas, oxidizing produced calcium bisulfite to calcium sulfate, separating out and removing solids, and recirculating clarified liquid for scrubbing contaminated gas.

1980-09-16

123

Study on carbonization of spherical fuel elements for 10 MW high temperature gas-cooled reactor

A technique has been developed for joining a large calcium fluoride crystal to a stainless-steel flange by means of a silver transition ring. The process involves both vacuum brazing using a copper-silver alloy and air brazing using silver chloride. This paper describes the procedure used in fabricating a high-vacuum leak-tight calcium fluoride window assembly.

124

P3 flux from anisotropic point source

The principle for working out the time-temperature schedule of the carbonization was determined through the investigation on the carbonization process of the green body and the phenol formaldehyde resin. During the carbonization process, the crack at lower temperatures is due to strain inhomogeneity produced in press. But the crack at higher temperatures results from the improper increasing rate of temperature. The application of the autoclave-carbonization process can increase the mechanical properties of the spherical fuel elements.

125

On the nucleon decay of subbarrier single-particle states in soft spherical nuclei

One-velocity angular flux of a neutron field generated by a polarly anisotropic point source in an infinite homogeneous region is calculated in P3 approximation, using the spherical harmonics operator formalism adapted to two-dimensional spherical geometry. The problem is reduced to simple algebraic equations. For weak absorption and linearly anisotropic scattering, the solution is given in closed form. (orig.).

126

On the nucleon decay of subbarrier single-particle states in soft spherical nuclei

The nucleon decay of subbarrier single-particle states with large angular momentum and parity opposite to that of the shell in soft spherical nuclei is considered. It is shown that the reduced probabilities of the nucleon decay into the ground state (0{sup +}) and into the first excited (2{sup +}) state of the daughter nucleus have qualitatively different energy dependences. (orig.).

1991-06-20

127

On peculiarities of nucleon decay of underbarrier one-quasiparticle states in soft spherical nuclei

The nucleon decay of subbarrier single-particle states with large angular momentum and parity opposite to that of the shell in soft spherical nuclei is considered. It is shown that the reduced probabilities of the nucleon decay into the ground state (0"+) and into the first excited (2"+) state of the daughter nucleus have qualitatively different energy dependences. (orig.).

128

Differences of the deformation parameter #beta# for 2"+_1 states of even-even spherical nuclei from electromagnetic excitation and proton scattering

Nucleon decay of underbarrier one-quasiparticle states with large angular momentum in soft spherical nuclei is considered. It is shown that energy dependences of differential probabilities of nucleon decay to the ground (0"+) and first excited (2"+) states of daughter nucleus differ qualitatively from each other due to strong interaction between quasiparticles and low-lying quadrupole states.

129

A simple, high efficiency, negative surface ionization source

Differences of the deformation parameters for the 2"+_1 states of even-even spherical nuclei extracted from electromagnetic excitation #beta#sup(em)_2 and from proton scattering #beta#sup(pp')_2 are discussed. It is found that the ratio #beta#sup(pp')_2/#beta#sup(em)_2 is equal to about unity and that there is a small isotope dependence for several incomplete shell nuclei. (orig.).

130

Spherically bent crystal spectroscopy in laser-produced plasma

A spherical-geometry, self-extraction negative ion source has been designed and fabricated. The source utilizes direct surface ionization to form negative ion beams resulting from interactions between high electron affinity gaseous elemental or molecular materials and a negatively biased, spherical-sector LaB{sub 6} surface ionizer maintained at {similar to}1300 K. The design features of this source and principles upon which the source is based are discussed in this report.

1992-04-01

131

Characterization of the product of the thiosulfate process for desulfurization of flue gases

A curved crystal X-ray spectrographs of reflection type spherical geometry was required based on the Johann scheme. Due to their high efficiency and resolution, X-ray spectrographs of focusing spectrograph spatial resolution are suitable for detecting weak X-ray spectra in spectrometers for laser fusion research. Spherically bent mica crystal with a radius of curvature of 380 mm was used in the spectrometer. The Bragg angle of the crystal analyzer was 51 degree. The image plate was employed to obtain high spatial resolution and a narrow spectral band width, with an effective area of 30 mm x 80 mm. The designed optical path of the X-ray spectrometer beam was 980 mm long from the source to the crystal and the detector. The first experiment was carried out at the 20 J energy laser facility of Research Center of Laser Fusion, China Academy of Engineering Physics. X-ray spectra in an absolute intensity scale were obtained from Al laser-produced ...

2008-02-01

132

Equilibrium, kinetics and thermodynamic studies on phosphate biosorption from aqueous solutions by Fe(III)-treated Staphylococus xylosus biomass: Common ion effect

X-ray diffraction, infrared spectroscopy, thermal analysis, scanning electron microscopy, and particle size analysis were used to characterize the product of the thiosulfate process. It was found to consist of a mixture of a solid solution of calcium sulfate in calcium sulfite hemihydrate, calcium sulfate dihydrate, and calcium carbonate. Reactions taking place on heating the byproduct were identified in oxidizing and reducing atmospheres. Pure calcium sulfite hemihydrate as well as solid solutions of CaSO[sub 4] in CaSO[sub 3] [center dot] (1/2)H[sub 2]O with different sulfate concentrations were synthesized in the laboratory. Thermal analyses of pure solid solutions proved that the higher the sulfate content, the higher is the dehydration temperature. Accordingly, taking SO[sub 4][sup 2[minus

1994-05-01

133

British Library Electronic Table of Contents (United Kingdom)

The biosorption of phosphate from aqueous solutions using Fe(III)-treated Staphylococus xylosus cells was investigated. Langmuir and Freundlich isotherm models were applied to describe the adsorption equilibrium and found that Langmuir isotherm model fitted the equilibrium data better than Freundlich isotherm model. The biosorption capacity of Fe(III)-treated biomass for phosphate was found to be 70.92mg/g at optimum conditions of pH 3.0, biomass concentration 0.5g/L and equilibrium phosphate-biomass time 60min respectively. The sorption efficiency at initial phosphate concentration of 50mg/L was not influenced upon addition of SO4^2^-, Cl^-, CO3^2^-, NO3^-, Mg^2^+ and Ca^2^+ ions from 0 to 800mg/L, whereas under the same conditions, phosphate sorption was increased with increase in concen...

2011-01-01

134

The phosphate complexation of neptunium(V)

Research Activities in the Spokane, Washington, Field Office...

The phosphate complexation of Np(V) is investigated in the pH range from 6.4 to 10.0 in 0.1 M NaClO_4 at 22#+-#2 C by absorption spectroscopy. The formation of two phosphate complexes is confirmed by spectroscopic speciation: NpO_2HPO"-_4 at 988.8 nm and NpO_2PO"2"-_4 at 993.6 nm with molar extinction coefficients of 251#+-#8 and 201#+-#11 1/mol cm, respectively. The complexation constants are determined to be log #beta# = 2.54#+-#0.02 for NpO_2HPO"-_4 and log #beta# = 6.33#+-#0.08 for NpO_2PO"2"-_4. The competition of the phosphate complexation with the carbonate complexation is demonstrated by speciation calculation under different geochemical conditions. (orig.).

1996-01-01

135

New NZP-phosphates B{sub 0.5}FeTa(PO{sub 4}){sub 3} (where B - Ca, Sr, Ba)

other chemical applications include use in water softeners, detergents, and food additives. The development of phosphate resources as a leasable commodity provides income to...

2011-08-20

136

A high-performance liquid chromatography-based radiometric assay for sucrose-phosphate synthase and other UDP-glucose requiring enzymes

New phosphates with NaZr{sub 2}(PO{sub 4}){sub 3} structure of the B{sub 0.5}FeTa(PO{sub 4}){sub 3}-type (where B-Ca, Sr, Ba) are synthesized and characterized by X-ray diffraction analysis and IR-spectroscopy. The heating behavior of the phosphates is studied using high-temperature X-ray crystallography in the range 15-625 deg. C. The unit-cell parameters, the coefficients of thermal expansion {alpha}{sub a}, {alpha}{sub c} and their thermal expansion anisotropy |{alpha}{sub c} - {alpha}{sub a}| of the phosphates under study are determined and the dependences of these characteristics on the nature of cations are established and analyzed.

2009-05-05

137

WASTE TREATMENT AND DISPOSAL PROGRESS REPORT FOR JUNE AND JULY 1962

A method for product analysis that eliminates a problematic step in the radiometric sucrose-phosphate synthase assay is described. The method uses chromatography on a boronate-derivatized high-performance liquid chromatography column to separate the labeled product, (14C)sucrose phosphate, from unreacted uridine 5{prime}-diphosphate-(14C)glucose (UDP-Glc). Direct separation of these compounds eliminates the need for treatment of the reaction mixtures with alkaline phosphatase, thereby avoiding the problem of high background caused by contaminating phosphodiesterase activity in alkaline phosphatase preparations. The method presented in this paper can be applied to many UDP-Glc requiring enzymes; here the authors show its use for determining the activities of sucrose-phosphate synthase, sucrose synthase, and uridine diphosphate-glucose pyrophosphorylase in plant extracts.

1991-05-01

138

LiNO3 molten salt assisted synthesis of spherical nano-sized YSZ powders in a reverse microemulsion system

9 9 simulated Purex waste oxides was investigated as a function of Na/sub 2/O, CaO and P/sub 2/O/sub 5/ content. All compositions lost some sulfate at 50 to 100 deg C above the softening point. In generai the volatility decreased with increase of either Na/ sub 2/O or CaO relative to P/sub 2/O/sub 5/, but no simple correlation Was indicated. Softening temperatures were lowered by inc ease in Na/sub 2/O vs CaO. Ceramic solids were obtained but no true glasses. Attempts to produce glasses by addition of varying combinations of Al/sub 2/O/sub 3/, PbO, BaO, and B/sub 2/O/ sub 3/ to simulated Pure x waste plus phosphite were unsuccessful. The use of 0.005 M Na/sub 2/C/O/sub 3/ to precipitate calcium from wastes containing up to 3 ppm of phosphate was demonstrated in four pilot plant runs and produced a decrease in the hardness of the waste leaving the clarifier. An inadvertent Sr/ sup 90/ and Cs/sup 137/ breakthrough ...

1962-12-19

139

British Library Electronic Table of Contents (United Kingdom)

Spherical nano-sized YSZ (yttria stabilized ZrO2) powders were successfully synthesized via a reverse microemulsion system. The water droplets in the microemulsion system of yclohexane/water/span85/Triton X-100/hexyl alcohol can act as the nano-reactors which solubilize zirconium oxychloride and ammonia water separately. The minute original reactors are favor to the formation of nano-sized spherical YSZ powders and the dispersibility of the powders can be controlled effectually by adjusting the weight ratio of the LiNO3 molten salt to the precursor. The phase transformation from cubic to monoclinic starts at and 500??C and finally monoclinic and cubic phase with increased crytallinity coexist at 800??C. The effect of LiNO3 molten salt in the formation of YSZ powders was also discussed.

2008-01-01

140

Bimetallic Pt-Ag and Pd-Ag nanoparticles

A principle of charged particle trapping by RF electromagnetic field in the spherical cavity

We report studies of bimetallic nanoparticles with 15%-16% atomic crystal parameters size mismatch. The degree of alloying was probed in a 2-nm Pt core (smallest attainable core size) of Pt-Ag nanoparticles (completely immiscible in bulk) and 20-nm-diameter Pd-Ag nanowires (completely miscible in bulk). Particles were synthesized radiolytically, and depending on the initial parameters, they assume spherical or cylindrical (nanowire) morphologies. In all cases, the metals are seen to follow their bulk alloying characteristics. Pt and Ag segregate in both spherical and wire forms, which indicates that strain due to crystallographic mismatch overcomes the excess surface free energy in the small particles. The Pd-Ag nanowires alloy similar to previously reported spherical Pd-Ag particles of similar diameter and composition.

2005-05-01

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141

Theoretical studies of metal-phosphate interactions: interaction of Li+, Na+, K+, Be++, Mg++, and Ca++ with H2PO4- and (CH3O)2PO2-: implications for nucleic acid solvation.

A new principle of particle trapping in the simple spherical cavity using both electric and magnetic components of radiofrequency electromagnetic field is proposed. The electric component of H {sub 12} oscillating mode drives the fast particle oscillations, while the magnetic component synchronously bends the trajectories to the cavity center. A specially developed theory of particle stability predicts dense and energetic electron cluster in the trap. Numerical simulations of particle dynamics in the complete electromagnetic field taking into account both space charge and particle-induced magnetic field are in good agreement with the analytic results, giving a density of 2.6*10{sup 1} electrons/cm{sup 3} and an average kinetic energy of around 30 keV at an operating frequency of 3 GHz. Being used at lower frequency, spherical cavity can trap protons and heavier ions too, but with lower density and kinetic energy.

2005-11-21

142

The complete sequence of a full length cDNA for human liver glyceraldehyde-3-phosphate dehydrogenase: evidence for multiple mRNA species.

Model phosphate-metal solvation complexes have been studied by ab-initio self-consistent-field techniques. The complexes studied include (RO)2PO2-(R = H or CH3) with Li+, Na+, K+, Be++, Mg++, Ca++,...Full Text Available

1975-10-01

143

The Isolation and Characterization of d-Glucose 6-Phosphate Cycloaldolase (NAD-Dependent) from Acer pseudoplatanus L. Cell Cultures

A recombinant M13 clone (O42) containing a 65 b.p. cDNA fragment from human fetal liver mRNA coding for glyceraldehyde-3-phosphate dehydrogenase has been identified and it has been used to isolate from...Full Text Available

1984-12-11

144

Synergistic Activation of Glucose-6-Phosphate Dehydrogenase and NAD(P)H oxidase by Src kinase Elevates Superoxide in Type 2 Diabetic, Zucker fa/fa, Rat Liver

A soluble enzyme system from suspension cultures of Acer pseudoplatanus L. converts d-glucose 6-phosphate to myoinositol. A Mg²⁺-dependent phosphatase, present in...Full Text Available

1971-09-01

145

Silicon effect on corrosion resistance of austenite stainless steels in strongly oxidizing media containing fluoride and phosphate admixtures

Glucose metabolism through glycolysis and hexosamine pathway has been shown to be altered in type 2 diabetes. However, its fate through the pentose phosphate pathway (PPP) is currently unclear....Full Text Available

2009-08-01

146

D-Glyceraldehyde-3-Phosphate Dehydrogenase: Three-Dimensional Structure and Evolutionary Significance

Paper estimates the corrosion resistance and studies the character of dissolving of silicon-bearing austenite stainless steels in strongly oxidizing media containing phosphate and fluoride admixtures. Corrosion behaviour of the studied steels is determined to depend essentially on the content of admixture or alloying silicon, as well as, on their phase composition in many respects determined by the thermal treatment condition. Refs. 22, figs. 1, tabs. 2.

147

Process development for production of coal/sorbent agglomerates. Final technical report, September 1, 1990--August 31, 1991

A 3.0-Å resolution electron density map of lobster glyceraldehyde-3-phosphate dehydrogenase (EC 1.2.1.12) was computed. The essentially single isomorphous replacement map was very substantially...Full Text Available

1973-11-01

148

Method of treating final products from flue gas desulfurization

The goal of this work was to develop a process flow diagram to economically produce a clean-burning fuel from fine Illinois coal. To accomplish this, the process of pelletizing fine coal with calcium hydroxide, a sulfur capturing sorbent, was investigated. Carbonation, which is the reaction of calcium hydroxide with carbon dioxide (in the presence of moisture) to produce a bonding matrix of calcium carbonate, was investigated as a method for improving pellet quality and reducing binder costs. Proper moisture level is critical to allow the reaction to occur. If too much moisture is present in a pellet, the pore spaces are filled and carbon dioxide must diffuse through the water to reach the calcium hydroxide and react. This severely slows or stops the reaction. The ideal situation is when there is just enough moisture to coat the calcium hydroxide allowing for the reaction to ...

1991-12-31

149

Evaluation of influence of fertilizers in radium concentration from tomato culture; Avaliacao da influencia dos fertilizantes nos teores de radio encontrados na cultura do tomate

A method of treating final products from a flue gas desulfurization. The flue gas desulfurization is carried out by the absorption of sulfur oxide in a spray dryer with a suspension which contains lime, or in a reactor with a dry, fine-grained, absorbent which contains lime. Prior to desulfurization, the fly ash carried along by the flue gas which is to be desulfurized is separated entirely, partially, or not at all from the flue gas, and the final products from the flue gas desulfurization, prior to any further treatment thereof, amount to 1-99% by weight, preferably 1-70% by weight, of fly ash, and 1-99% by weight, preferably 30-99% by weight, of the sum of the desulfurization products, preferably calcium sulfite hemihydrate, and/or calcium sulfite, and/or calcium sulfate dyhydrate, and/or calcium sulfate hemihydrate, and/or calcium sulfate, as well as residue of the absorbent. ...

1984-10-23

150

Wet limestone FGD solids analysis by thermogravimetry

The fertilizer contribution to radio uptake by tomato plants was assessed. Tomato and soil samples from four different plantations were analyzed: two using organic fertilizer and two using phosphate fertilizer. The Ra concentrations in eight of the most used tomato fertilizers were determined. The concentration values ranged from 14 to 221 Bq/kg of Ra-226 and from 25 to 176 Bq/kg of Ra-228. Owing to the low Ra concentration and to the used fertilizer quantities, the fertilizers would not increase significantly the Ra soil concentration. However, the highest soil to plant concentration ratios were found in the plantations using phosphate fertilizers. This outcome pointed out the higher Ra availability in the phosphate fertilizer plantations than in the organic fertilizer plantations, showing a possible positive influence of phosphate fertilizers for the tomato Ra uptake. Due to the ...

2001-07-01

151

Simulation of solid molecular hydrogen - a new twist to an old problem

Wet limestone scrubbing is once again becoming a popular technology for removal of sulfur dioxide (SO{sub 2}) from power plant emissions. Critical to the operation of wet limestone flue gas desulfurization (FGD) systems is accurate chemical analysis of scrubber solids. The analytical technique of thermogravimetry is ideal for this application, as the instrument can give precise readings of the principal scrubber solids components, calcium sulfite/sulfate hemihydrate, calcium sulfate dihydrate (gypsum), and unused calcium carbonate. The data provides plant chemists, engineers, and operators with information needed to fine-tune scrubber operation and detect process upsets. (orig.)

2004-07-01

152

British Library Electronic Table of Contents (United Kingdom)

Solid molecular orthohydrogen exhibits orientational order at low temperatures. The orthohydrogen molecules, which are quadrupoles, order in the Pa3 structure. We have simulated this ordering, and explored the behaviour under dilution by spherical parahydrogen molecules.

2010-01-01

153

Observatory: Cluster FM5 (Rumba) - SPASE Resource Description

Internal Functionalization and Surface Modification of Vinylsilsesquioxane Nanoparticles

Feb 7, 2011 ... The potentials of the spherical sensor and nearby conductors are controlled ... Incoming data are continuously monitored by algorithms in the software ... together with FM8 (Tango) by a Soyuz-Fregat rocket from Baikonur. ...

154

Hydrodynamics of primordial black hole formation: dependence on the equation of state

The interior of 237 nm spherical vinylsilsesquioxane nanoparticles has been covalently modified and their surface functionalized under mild conditions to yield a novel type of hybrid silsesquioxane...Full Text Available

2009-01-01

155

Electrochemical synthesis of nanostructured porous materials using liquid crystal and colloidal templates and their magnetic and optical properties

An analysis is made of the manner in which the process of primordial black-hole formation and the subsequent accretion of gas depend on the equation of state. On the assumption that the process is spherically symmetric, the problem is solved numerically.

1980-03-01

156

Cumulative releases of radionuclides from uncontained waste packages

material, and that these magnetic properties vary systematically with the diameter of the spherical pores within the films. A new oscillation effect has been observed for the coercivity of macroporous Ni sub 8 sub 0 Fe sub 2 sub 0 film with different pore layer thickness. sphere templates, the resulting films show well-formed, regular, two- and three-dimensional macroporous networks consisting of spherical pores arranged in a highly ordered face centred cubic (fee) structure. The spherical voids are interconnected by a series of smaller windows that form an open porous structure embedded in the material framework. The diameter of the spherical pores can be precisely changed over the range from 200 to 1000 nm by changing the diameter of the latex spheres used to form the templates. The resulting macroporous material structures are robust, self-supported, dense, polycrystalline, uniform and free from ...

2002-01-01

157

Vitamin D and respiratory health

This report describes mathematical predictions for the migration of radionuclides from an emplaced radioactive waste container. The model assumes a spherical-equivalent waste solid surrounded by backfill but neglects the effect of decay heat. 7 refs., 2 tabs. (TEM)

1986-07-01

158

Two-photon calcium imaging from head-fixed Drosophila during optomotor walking behavior

Vitamin D is now known to be of physiological importance outside of bone health and calcium homeostasis, and there is mounting evidence that it plays a beneficial role in the prevention and/or treatment...Full Text Available

2009-10-01

159

British Library Electronic Table of Contents (United Kingdom)

Drosophila melanogaster is a model organism rich in genetic tools to manipulate and identify neural circuits involved in specific behaviors. Here we present a technique for two-photon calcium imaging in the central brain of head-fixed Drosophila walking on an air-supported ball. The ball's motion is tracked at high resolution and can be treated as a proxy for the fly's own movements. We used the genetically encoded calcium sensor, GCaMP3.0, to record from important elements of the motion-processing pathway, the horizontal-system lobula plate tangential cells (LPTCs) in the fly optic lobe. We presented motion stimuli to the tethered fly and found that calcium transients in horizontal-system neurons correlated with robust optomotor behavior during walking. Our technique allows both behavior ...

2010-01-01

160

Transformation of Verapamil by Cunninghamella blakesleeana

The use of gamma activation to study the behaviour of certain metals, in particular lead, during the dry ashing of bone

A filamentous fungus, Cunninghamella blakesleeana AS 3.153, was used as a microbial model of mammalian metabolism to transform verapamil, a calcium channel antagonist. The metabolites...Full Text Available

2004-05-01

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161

Role of temperature in the spontaneous precipitation of calcium sulfate dihydrate

... calcium 47 combustion dry ashing high temperature labelled compounds lead

1972-04-10

162

Mechanisms of Reproductive Thermotolerance in Gossypium hirsutum: The Effect of Genotype and Exogenous Calcium Application

The spontaneous precipitation of calcium sulfate in supersaturated solutions over the temperature range between 25.0 and 80.0 C was investigated by monitoring the solution specific conductivity during desupersaturation. From measurements of the induction times preceding the onset of precipitation the surface energy of the forming solid, identified as gypsum, was found between ca. 12 and 25 mJ/m{sup 2} for the temperature range between 80.0 and 25.0 C, respectively. Kinetics analysis showed that over 50 C it is possible that anhydrous calcium sulfate is forming as a transient phase converting into the more stable calcium sulfate dihydrate. The linear dependence of the rates of precipitation on the relative solution supersaturation suggested a mechanism according to which the growth units are integrated into the active sites of the supercritical nuclei by surface diffusion. According to the morphological examination of the ...

1999-02-16

163

British Library Electronic Table of Contents (United Kingdom)

Abstract Although photosynthetic thermotolerance has been investigated extensively in cotton leaves, reports on the biochemical influence of the pistil in promoting fertilization thermostability are limited. To evaluate the effect of temperature, genotype, and exogenous calcium application on fertilization and pistil biochemistry in cotton, thermosensitive (cv. ST4554 B2RF) and thermotolerant (cv. VH260) plants were grown under control (30/20-C) or high-temperature (38/20-C) conditions during flowering, and exogenous CaCl2 was applied to flowers 1-day prior to anthesis. Measured pistil parameters included fertilization efficiency; protein concentration; glutathione reductase, superoxide dismutase (SOD) and NADPH oxidase activities; and ATP and calcium levels. Exogenous calcium had no effec...

2011-01-01

164

Loss of Skeletal Calcium by Patients on Maintenance Dialysis

Instrumental-activation analysis of Mo, Al, Ca, Mn, Cl, Na, and K in soil-plant samples

Direct radiological measurements of the mineral content of femoral bone were performed in 13 patients on maintenance dialysis. They were found to be sufficiently sensitive to be used for monitoring,...Full Text Available

1970-08-29

165

Numerical simulation of internal reconnection event in spherical tokamak

... activation analysis aluminium 28 calcium 49 chlorine 38 cotton plants li-drifted

166

Magnetic fluctuation measurement in Sino United Spherical Tokamak plasma

Three-dimensional magnetohydrodynamic simulations are executed in a full toroidal geometry to clarify the physical mechanisms of the Internal Reconnection Event (IRE), which is observed in the spherical tokamak experiments. The simulation results reproduce several main properties of IRE. Comparison between the numerical results and experimental observation indicates fairly good agreements regarding nonlinear behavior, such as appearance of localized helical distortion, appearance of characteristic conical shape in the pressure profile during thermal quench, and subsequent appearance of the m=2/n=1 type helical distortion of the torus. (author)

1999-07-01

167

Galvanic element with suspended electrode. Galvanisches Element mit suspendierter Elektrode

To investigate the magnetic fluctuations and for further transport study, the poloidal and radial magnetic field measurement is conducted on the Sino United Spherical Tokamak (SUNIST). Auto-power spectral density indicates that the magnetic fluctuation energy mainly concentrates in the frequency region lower than 10 kHz. The magnetic field oscillations, which are characterized by harmonic frequencies of 40 kHz, are observed in the scrape-off layer; by contrast, in the plasma core, the magnetic fluctuations are of Gaussian type. The time-frequency profiles show that the poloidal magnetic fluctuations are temporally intermittent. The autocorrelation calculation indicates that the fluctuations in decorrelation time vary between the core and the edge. (authors)

2007-07-01

168

Characteristics of cosmic ray pole-equator anisotropy derived from spherical harmonic analysis of neutron monitor data

A zinc/air battery is claimed whose performance is improved by omitting separating elements such as diaphragms etc. The cathode and anode spaces are separated by a collector with holes big enough to permit the electrons to pass freely while restraining the anode material. Further, the active material consists of a spherical care of inert material with a zinc coating. Under the zinc coating, the spherical particles have another thin coating of an electropositive material, e.g. nickel. The cell also contains means for circulating the anode suspension.

1984-08-09

169

The effects of a calcium deficient diet on the mechanical properties and morphology of goose bone.

The spherical harmonic analysis of cosmic ray neutron data from the worldwide network neutron monitor stations during the years 1966 to 1969 was carried out. The second zonal harmonic component obtained from the analysis corresponds to the Pole-Equator anisotropy of the cosmic ray neutron intensity. Such an anisotropy makes a semiannual variation. In addition to this, it is shown that the Pole-Equator anisotropy makes a variation depending on the interplanetary magnetic field (IMF) sector polarities around the passages of the IMF sector boundary. A mechanism to interpret these results is also discussed.

1985-08-01

170

Effects of compost and phosphate amendments on arsenic mobility in soils and arsenic uptake by the hyperaccumulator, Pteris vittata L

A control group of geese (Anser anser) on a normal calcium diet for egg laying poultry was compared to egg laying geese on a calcium deficient diet. The ultimate compressive strength and modulus of elasticity of femoral cortical bone from each group were determined by compressing right circular cylinders which were 2.4 mm in height and 0.8 mm in diameter. The bending strength and bending modulus of elasticity of tibial cortical bone were determined by three point bend tests on rectangular prisms which were approximately 25 mm by 0.8 mm by 0.8 mm. Bone calcium content and eggshell calcium content were determined by atomic absorption spectrophotometry. Blood samples were analyzed for free calcium ion concentration. Histological observations included studies of cross-sectional microradiographs, examinations of cross sections stained by a modified Masson's technique, and a determination ...

1986-01-01

171

Selective Expression in Carotid Body Type I Cells of a Single Splice Variant of the Large Conductance Calcium- and Voltage-activated Potassium Channel Confers Regulation by AMP-activated Protein Kinase*

Chinese brake fern (Pteris vittata L.), an arsenic (As) hyperaccumulator, has shown the potential to remediate As-contaminated soils. This study investigated the effects of soil amendments on the leachability of As from soils and As uptake by Chinese brake fern. The ferns were grown for 12 weeks in a chromated-copper-arsenate (CCA) contaminated soil or in As spiked contaminated (ASC) soil. Soils were treated with phosphate rock, municipal solid waste, or biosolid compost. Phosphate amendments significantly enhanced plant As uptake from the two tested soils with frond As concentrations increasing up to 265% relative to the control. After 12 weeks, plants grown in phosphate-amended soil removed >8% of soil As. Replacement of As by P from the soil binding sites was responsible for the enhanced mobility of As and subsequent increased plant uptake. Compost additions facilitated As uptake from the CCA soil, but decreased As ...

2003-11-01

172

Effects of xylitol on the absorption of /sup 203/Pb in mice and cockerels

Inhibition of large conductance calcium-activated potassium (BK_Ca) channels mediates, in part, oxygen sensing by carotid body type I cells. However, BK_Ca channels remain active...Full Text Available

2011-04-08

173

Tungsten Effects on Phosphate-Dependent Biochemical Pathways are Species and Liver Cell Line Dependent

Earlier studies have indicated that xylitol may increase the absorption and urinary excretion of dietary oxalate. It has also been indicated that xylitol increases the absorption of calcium. Intestinal absorption of lead, a divalent contaminant in the diet, is in many respects similar to that of calcium. The purpose of this study was to evaluate the effects of xylitol on the intestinal absorption of lead using two different approaches: the in situ ligated intestinal loop technique in cockerels and gastric gavage in mice.

1986-07-01

174

British Library Electronic Table of Contents (United Kingdom)

Tungsten, in the form of tungstate, polymerizes with phosphate, and as extensive polymerization occurs, cellular phosphorylation and dephosphorylation reactions may be disrupted, resulting in negative effects on cellular functions. A series of studies were conducted to evaluate the effect of tungsten on several phosphate-dependent intracellular functions, including energy cycling (ATP), regulation of enzyme activity (cytosolic protein tyrosine kinase [cytPTK] and tyrosine phosphatase), and intracellular secondary messengers (cyclic adenosine monophosphate [cAMP]). Rat noncancerous hepatocyte (Clone-9), rat cancerous hepatocyte (H4IIE), and human cancerous hepatocyte (HepG2) cells were exposed to 1-1000 mg/l tungsten (in the form of sodium tungstate) for 24 h, lysed, and analyzed for the ab...

2010-01-01

175

Physicochemical investigation of the behavior of elements in chloride melts in the presence of solid phases based on phosphates of polyvalent elements. II. Behavior of strontium and barium

Effects of hydrous pyrolysis on biomarker thermal maturity parameters: Monterey Phosphatic and Siliceous members

The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.

1987-07-01

176

Ectopic mineralization of connective tissue in Abcc6-/- mice: effects of dietary modifications and a phosphate binder - a preliminary study

Hydrous pyrolysis of immature Monterey Phosphatic or Siliceous rock at progressively higher temperatures causes systematic changes in biomarker thermal maturity parameters of the generated hydrocarbons. Biomarker ratios based on proposed carbon-carbon cracking or aromatization reactions increase during hydrous pyrolysis along similar pathways for both Siliceous and Phosphatic members. An increase in these biomarker ratios is also observed for oils of increasing thermal maturity from the offshore Santa Maria Basin, although the rates of changes for each parameter differ between the hydrous pyrolysis and natural samples. Changes in some cracking parameters during maturation appear to result from differential thermal stability of the compounds rather than conversion of precursors to products. (author).

1990-01-01

177

British Library Electronic Table of Contents (United Kingdom)

Please cite this paper as: Ectopic mineralization of connective tissue in Abcc6-/- mice: effects of dietary modifications and a phosphate binder - a preliminary study. Experimental Dermatology 2008; 17: 203-207. Abstract: Pseudoxanthoma elasticum (PXE), a heritable multisystem disorder, is caused by mutations in the ABCC6 gene. We have developed a murine model for PXE by targeted inactivation of the corresponding mouse gene. A feature of this mouse model is ectopic mineralization of connective tissue capsule surrounding the bulb of vibrissae. This study was designed to investigate the effect of dietary sevelamer hydrochloride (Renagel), a phosphate binder, and specific mineral modifications on ectopic mineralization of connective tissue in Abcc6-/- mice. Three groups were fed a specific di...

2008-01-01

178

Comparison of sodium zirconium phosphate-structured HLW forms and synroc for high-level nuclear waste immobilization

Chemically bonded phosphate ceramics : part III : reduction mechanism and its application to iron phosphate ceramics.

The incorporation of (a) Cs/Sr as simulated heat-generating isotopes contained in Purex reprocessing waste, (b) simulated actinides, and (c) simulated Purex waste in sodium zirconium phosphate (NZP) has been studied. The samples were prepared by sintering, by hot pressing and by hot isostatic pressing in metal bellows containers. The short-term chemical durability of the phosphate-based material containing Purex waste was within an order of magnitude of that for Synroc-C, as measured by 7-day MCC-1 tests at 90{degrees}C. The dissolution behavior showed evidence of re-precipitation phenomena, even after times as short as 28 days. Potential for improvement of NZP-based ceramics for HLW management is discussed. 19 refs., 4 figs., 3 tabs.

1996-12-31

179

Biosorption of Acid Blue 25 by unmodified and CPC-modified biomass of Penicillium YW01: Kinetic study, equilibrium isotherm and FTIR analysis

In this, the last of a series of three papers, we discuss a method of forming iron phosphate ceramics by a reduction process. We report the formation of iron oxide ceramics by reducing hematite with iron in a phosphoric acid solution. The reaction results in a rapid-setting ceramic (at room temperature) with a compressive strength of 3700 psi and a density of 1.7 g/cm{sup 3}. Although the exact mineral form of the binder is difficult to determine because it is mostly amorphous and hence is not amenable to X-ray diffraction analyses, this material is expected to consist of iron hydrophosphates. The reduction process is very useful in recycling several industrial wastes that are rich in hematite, including iron mine tailings, red mud (a caustic waste from the alumina industry), and machining swarfs. Formation of ceramics with red mud and swarfs is also discussed.

2003-11-01

180

British Library Electronic Table of Contents (United Kingdom)

The main objective of this work was to investigate the biosorption performance of unmodified and Cetylpyridinium chloride (CPC)-modified biomass of Penicillium YW 01 for Acid Blue 25 (AB 25). Maximum biosorption capacity of AB 25 onto CPC-modified biosorbent was 118.48mgg^-^1 under phosphoric-phosphate buffer with initial dye concentration of 200mgL^-^1 at 30^oC. The biosorption pattern of AB 25 onto unmodified biosorbent in aqueous solution and phosphoric-phosphate buffer was well fitted with both Langmuir and Freundlich isotherm models. While the equilibrium data of CPC-modified biosorbent in aqueous solution and phosphoric-phosphate buffer failed to fit the Freundlich isotherm model, indicating the monolayer biosorption formed onto CPC-modified biosorbent. The values of initial biosorpt...

2011-01-01

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181

Solid-gas equilibria in CaSO/sub 3/-H/sub 2/O/sub (g)/ system and Lewis-acid-base alloys

Human complement protein C99 is a calcium binding protein

The role played by calcium sulfite in the flue gas desulfurization of lime/limestone scrubbers makes it desirable to work out its thermodynamic properties. A thermogravimetric apparatus was used to study the equilibria between calcium sulfite hemihydrate and calcium sulfite anhydrite under different conditions. Efforts were made to analyze the difficulties encountered in the dynamic approach to equilibration after calcium sulfate dihydrate failed in calibration of the apparatus. Finally, the kinetics and thermodynamics for the dissociation of calcium sulfite hemihydrate were examined. The confirmation of Engel-Brewer's correlation between the electronic configuration and crystal structure in metallic systems has long been pursued in this group by studying the Lewis-acid-base interactions. Tantalum-iridium alloys of different compositions were brought into equilibrium with ...

1981-10-01

182

skittles, a Drosophila phosphatidylinositol 4-phosphate 5-kinase, is required for cell viability, germline development and bristle morphology, but not for neurotransmitter release.

Human complement protein C9 is shown to be a metalloprotein that binds 1 mol of Ca"2"+/mol of C9 with a dissociation constant of 3 #mu#m as measured by equilibrium dialysis. Incubation with EDTA removes the bound calcium, resulting in a apoprotein with decreased thermal stability. This loss in stability leads to aggregation and, therefore, to loss of hemolytic activity upon heating to a few degrees above the physiological temperature. Heat-induced aggregation of apoC9 can be prevented by salts that stabilize proteins according to the Hofmeister series of lyotropic ions, suggesting that the ion in native C9 may ligand with more than one structural element of domain of the protein. Ligand blotting indicates that the calcium binding site is located in the amino-terminal half of the protein. Removal of calcium by inclusion of EDTA in assay mixtures has no effect on the hemolytic activity of C9, and its capacity to bind to C8 in ...

183

Use of Dimethyl Suberimidate, a Cross-Linking Reagent, in Studying the Subunit Structure of Oligomeric Proteins^*

The phosphatidylinositol pathway is implicated in the regulation of numerous cellular functions and responses to extracellular signals. An important branching point in the pathway is the phosphorylation...Full Text Available

1998-12-01

184

The effect of lecithin on intestinal cholesterol uptake by rat intestine in vitro

Amidination of aldolase, glyceraldehyde-3-phosphate dehydrogenase, tryptophan synthetase B protein, L-arabinose isomerase, and the catalytic subunit of E. coli aspartate transcarbamylase...Full Text Available

1970-07-01

185

The control of sulphate reduction in bacteria

1. Sacs 20 cm long were obtained from the upper half of the small intestine of bile fistula rats (bile duct cannulated 48 hours previously). The sacs were everted, filled with oxygenated phosphate...Full Text Available

1973-03-01

186

The Structure of Sucrose Phosphate Synthase from Halothermothrix orenii Reveals Its Mechanism of Action and Binding Mode

1. An enzyme from Escherichia coli 9723 that reduces adenosine 3′-phosphate 5′-sulphatophosphate to inorganic sulphite is described. Extracts of E. coli...Full Text Available

1965-07-01

187

Targeting the Pentose Phosphate Pathway in Syndrome X-related Cardiovascular Complications

Sucrose phosphate synthase (SPS) catalyzes the transfer of a glycosyl group from an activated donor sugar, such as uridine diphosphate glucose (UDP-Glc), to a saccharide acceptor D-fructose 6-phosphate (F6P), resulting in the formation of UDP and D-sucrose-6'-phosphate (S6P). This is a central regulatory process in the production of sucrose in plants, cyanobacteria, and proteobacteria. Here, we report the crystal structure of SPS from the nonphotosynthetic bacterium Halothermothrix orenii and its complexes with the substrate F6P and the product S6P. SPS has two distinct Rossmann-fold domains with a large substrate binding cleft at the interdomain interface. Structures of two complexes show that both the substrate F6P and the product S6P bind to the A-domain of SPS. Based on comparative analysis of the SPS structure with other related enzymes, the donor substrate, nucleotide diphosphate glucose, binds to the ...

2008-01-01

188

Regulation of lactose catabolism in Streptococcus mutans: purification and regulatory properties of phospho-beta-galactosidase.

Syndrome X is a combination or co-occurrence of several known cardiovascular risk factors (including central obesity, dyslipidemias, fatty liver disease, hyperinsulinemia, insulin resistance,...Full Text Available

2010-05-01

189

PGM2 overexpression improves anaerobic galactose fermentation in Saccharomyces cerevisiae

Phospho-beta-galactosidase (P-beta-gal), the enzyme which catalyzes the first step in the metabolism of intracellular lactose phosphate, occurred at high specific activity in the cytoplasm in 12 of...Full Text Available

1979-01-01

190

Nitrogen metabolite repression of nitrate reductase in Neurospora crassa.

BackgroundIn Saccharomyces cerevisiae galactose is initially metabolized through the Leloir pathway after which glucose 6-phosphate enters glycolysis. Galactose...Full Text Available

191

Method for inhibiting fouling of petrochemical processing equipment

The effect of different nitrogen compounds on the induction of reduced nicotinamide adenine dinucleotide phosphate-nitrate reductase was examined in Neurospora crassa. Whereas in the wild-type strain...Full Text Available

1979-03-01

192

Method for determining the temporal response of microbial phosphate transport affinity.

Method for inhibiting the formation of foulants on petrochemical equipment which involves adding to the petrochemical, during processing, a composition comprising a thiodipropionate and either a dialkyl acid phosphate ester or a dialkyl acid phosphite ester.

1980-10-07

193

Lipid A biosynthesis in Rhizobium leguminosarum: Role of a 2-keto-3-deoxyoctulosonate-activated 4{prime} phosphatase

Nutrient transport affinities of nutrient-starved microbial populations were measured as initial slopes of plots of limiting-nutrient transport rates versus extracellular limiting-nutrient concentrations....Full Text Available

1986-03-01

194

Formate Dehydrogenase of Clostridium thermoaceticum: Incorporation of Selenium-75, and the Effects of Selenite, Molybdate, and Tungstate on the Enzyme

Lipid A from several strains of the N{sub 2}-fixing bacterium Rhizobium leguminosarum displays significant structural differences from Escherichia coli lipid A, one of which is the complete absence of phosphate groups. However, the first seven enzymes of E. coli lipid A biosynthesis, leading from UDP-GlcNAc to the phosphorylated intermediate, 2-keto-3-deoxyoctulosonate (Kdo{sub 2})-lipid IV{sub A}, are present in R. leguminosarum. We now describe a membrane-bound phosphatase in R. leguminosarum extracts that removes the 4{prime} phosphate of Kdo{sub 2}-lipid IV{sub A}. The 4{prime} phosphatase is selective for substrates containing the Kdo domain. It is present in extracts of R. leguminosarum biovars phaseoli, viciae, and trifolii but is not detectable in E. coli and Rhizobium meliloti. A nodulation-defective strain (24AR) of R. leguminosarum bovar trifolii, known to contain a 4{prime} phosphate residue on its lipid A, also ...

1995-08-01

195

Carbon Partitioning in Eelgrass (Regulation by Photosynthesis and the Response to Daily Light-Dark Cycles).

The formation of the nicotinamide adenine dinucleotide phosphate-dependent formate dehydrogenase in Clostridium thermoaceticum is stimulated by the presence of molybdate and selenite...Full Text Available

1973-11-01

196

A proton nuclear magnetic resonance investigation of the anion Bohr effect of human normal adult hemoglobin

Diel variations in rates of C export, sucrose-phosphate synthase (SPS) and sucrose synthase (SS) activity, and C reserves were investigated in Zostera marina L. (eelgrass) to elucidate the environmental...Full Text Available

1995-08-01

197

Process of making particle board from pyrophosphate treated polyisocyanates

High-resolution proton nuclear magnetic resonance spectroscopy has been used to investigate the molecular mechanism of the Bohr effect of human normal adult hemoglobin in the presence of two allosteric effectors, i.e., chloride and inorganic phosphate ions. The individual hydrogen ion equilibria of 22-26 histidyl residues of hemoglobin have been measured in anion-free 0.1 M HEPES buffer and in the presence of 0.18 M chloride or 0.1 M inorganic phosphate ions in both deoxy and carbonmonoxy forms. The results indicate that the #beta#2-histidyl residues are strong binding sites for chloride and inorganic phosphate ions in hemoglobin. The affinity of the #beta#2-histidyl residues for these anions is larger in the deoxy than in the carbonmonoxy form. Nevertheless, the contribution of these histidyl residues to the anion Bohr effect is small due to their low pK value in deoxyhemoglobin in anion-free solvents. The interactions of ...

198

Moessbauer spectroscopy study of iron corrosion underneath painting system

A process is disclosed for the preparation of liquid, storage-stable, polyisocyanate compositions containing a release agent formed in situ which compositions are useful, for example, as binder resins in the formation of particle boards which latter, because of the presence of the release agent, show no tendency to adhere to the face of metal platens used in their formation. The process comprises heating an organic polyisocyanate (polymethylene polyphenyl polyisocyanate preferred) with an acid phosphate (e.g. a mixture of mono-and di-alkyl acid phosphates) under conditions controlled as to time and temperature so as to yield a product which is storage stable and shows no tendency to deposit solid or to separate into two liquid phases.

1984-10-09

199

Long-term monitoring of microleakage of dental cements by radiochemical diffusion

The effect of pigments on the development of corrosion products between the painting system and metal surface when exposed to marine environments has been discussed. The pigments studied were: red mud zinc chromate, zinc chromate, red oxide zinc phosphate, manganese phosphate barium chromate and basic lead silico chromate. Moessbauer spectroscopy revealed that the upper rust layer in all the cases consisted of #gamma#-Fe_2O_3, #gamma#-FeOOH and #alpha#-FeOOH. The lower rust layer immediately in contact with the metal surface consisted of an asymmetrical doublet due to #gamma#-FeOOH. (Auth.).

200

Extraction of magnesium as the iodide by tributyl phosphate

Radioactive "1"4C sucrose was found to be an ideal marker for microleakage because it did not penetrate tooth tissue, dental cement, or mounting resin. The main finding is that the adhesive cements--the glass-ionomer and polycarboxylate--are significantly more effective at preventing microleakage than are the traditional phosphate cements--silicate and zinc phosphate. The differences can be as high as two orders of magnitude. The adhesive cements provide almost perfect and reliable seals. By contrast, the nonadhesive cements are erratic sealants with most of the restorations leaking.

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201

Crystal structure of telluric acid ammonium phosphate (TAAP) in the paraelectric phase

The extraction of magnesium by tributyl phosphate from KI solutions was investigated. With increasing KI and TBP concentrations, the extraction increased. The maximum extraction (82%) was attained at pH 4, and it did not decrease with a further pH increase. With decreasing pH, the extraction decreased because of HI extraction. The magnesium was extracted as the compound MgI/sub 2/ x 4TBP. Complexone III (at pH 3-4) does not affect the extraction of magnesium, which makes it possible to use it to mask other metals.

1987-08-20

202

Numerical ray tracing of electrons in different 3D fringing fields of spherical deflectors

Crystal structure of monoclinic telluric acid ammonium phosphate (TAAP) has been studied by an X-ray diffraction method in the paraelectric phase at 333 K and in the ferroelectric phase at room temperature. It is confirmed that the space group in the paraelectric phase is P2/n. Comparison of the results between the two temperatures suggests that the plane which is made by the PO{sub 4} tetrahedron linked by hydrogen bonds has an important role for the ferroelectric phase transition. This plane is almost parallel to the direction of spontaneous polarization.

2005-01-15

203

Structural definition of the active site and catalytic mechanism of 3,4-dihydroxy-2-butanone 4-phosphate synthase

This paper presents the results of numerical investigations on electron trajectories in different 3D fringing fields of spherical defectors. We start with a chosen set of geometrical values for the electrodes such as radius of curvature, electrode gap, angle between entrance and exit face. We do a first numerical calculation of the spatial potential distribution using a 3D electron optics program based on the finite difference method (FDM). Ray tracing through this potential distribution is then performed using another program, which also gives the potential and the electric field strength along the curved beam path. In the next step we estimate the position and the geometry of the field clamp using Herzog's formulae assuming the entrance of a parallel plate condenser to be a good approximation for the entrance of the spherical deflector in first order. For the consecutive numerical recalculations of the real potential distribution of the ...

1999-11-01

204

Effects of pH and phosphate on metal distribution with emphasis on As speciation and mobilization in soils from a lead smelting site

X-ray crystal structures of L-3,4-dihydroxy-2-butanone-4-phosphate synthase from Magnaporthe grisea are reported for the E-SO{sub 4}{sup 2-}, E-{sub 4}{sup 2-}-Mg{sup 2+}, E-SO{sub 4}{sup 2-}-Mn{sup 2+}, E-SO{sub 4}{sup 2-}-Mn{sup 2+}-glycerol, and E-SO{sub 4}{sup 2-}-Zn{sup 2+} complexes with resolutions that extend to 1.55, 0.98, 1.60, 1.16, and 1.00 {angstrom}, respectively. Active-site residues of the homodimer are fully defined. The structures were used to model the substrate ribulose 5-phosphate in the active site with the phosphate group anchored at the sulfate site and the placement of the ribulose group guided by the glycerol site. The model includes two Mg{sup 2+} cations that bind to the oxygen substituents of the C2, C3, C4, and phosphate groups of the substrate, the side chains of Glu37 and His153, and water molecules. The position of the metal cofactors and the substrate's ...

2010-03-08

205

Small-molecule screen identifies inhibitors of a human intestinal calcium-activated chloride channel.

Arsenic in soils from the Asarco lead smelter in East Helena, Montana was characterized by X-ray absorption spectroscopy (XAS). Arsenic oxidation state and geochemical speciation were analyzed as a function of depth (two sampling sites) and surface distribution. These results were compared with intensive desorption/dissolution experiments performed in a pH stat reactor for samples from the site with the highest degree of As heterogeneity. The objectives of the study were to investigate the solid-phase geochemical As speciation, assess the speciation of As in solutions equilibrated with the solids under controlled pH (pH=4 or 6) and Eh (using hydrogen or air) environments, observe the effects of phosphate on the release of As into solution, and examine the effects of phosphate on metal mobility in the systems. Arsenic was predominantly found in the As(V) valence state, though there was evidence that As(III) and As(0) were present also. The ...

2005-06-01

206

Molecular mechanisms of the epithelial transport of toxic metal ions, particularly mercury, cadmium, lead, arsenic, zinc, and copper. Progress report, January 1, 1979-December 31, 1979

Calcium-activated chloride channels (CaCCs) are widely expressed in mammalian tissues, including intestinal epithelia, where they facilitate fluid secretion. Potent, selective CaCC inhibitors have not been available. We established a high-throughput screen for identification of inhibitors of a human intestinal CaCC based on inhibition of ATP/carbachol-stimulated iodide influx in HT-29 cells after lentiviral infection with the yellow fluorescent halide-sensing protein YFP-H148Q/I152L. Screening of 50,000 diverse, drug-like compounds yielded six classes of putative CaCC inhibitors, two of which, 3-acyl-2-aminothiophenes and 5-aryl-2-aminothiazoles, inhibited by >95% iodide influx in HT-29 cells in response to multiple calcium-elevating agonists, including thapsigargin, without inhibition of calcium elevation, calcium-calmodulin kinase II activation, or cystic fibrosis transmembrane conductance ...

2007-12-14

207

Physical model experiment for wave field measurements by means of laser Doppler vibrometer. Measurement of three components; Laser Doppler shindokei ni yoru butsuri model jikken. Hado sanseibun no kenshutsu

The mechanism of lead transport is presented, and especially the particular similarities or dissimilarities between lead and calcium in this process. The absorption of these metals was determined cockerels, raised on a commercial diet or on a specified diet, using in vivo ligated loop procedure. The dose administered into the loop contained 0.5 #mu#Ci "2"0"3Pb (and/or 0.1 #mu#Ci "4"7Ca), and 0.01 mM lead acetate (and/or mM CaCl_2) in 0.5 ml 0.15 M NaCl,pH 6.5. It was shown that lead is rapidly taken up by the mucosal tissue, and slowly transferred into the body, whereas less calcium is retained by the tissue and the transfer of calcium is many times as effective as that for lead. They appear to respond in a similar manner to a low calcium intake and vitamin D treatment. Increasing luminal stable lead concentration significantly reduced the percentage of radiolead significantly reduced the percentage of ...

208

First plasma experiment on spherical tokamak device UTST

In this experiment, a beam incident from an oblique direction is reflected by a spherical lens toward the direction of incidence. When the surface of a matter is vibrated by elastic waves, the spherical lens comes into a translation motion that accompanies the vibration. It follows accordingly that the vibration on the surface of the matter may be detected by sensing the spherical lens travelling speed. Three components of the vibration may be determined if beams are focused at one spot from three directions. Detection of the S-wave component by LDV (laser Doppler vibrometer) discloses the complicated wave field in a heterogeneous material, and this physical model experiment may be utilized in various fields of study. For instance, information about problems that may surface in the field work may be collected beforehand in a physical model experiment for developing an S-wave-aided probing method. For the study of seismic ...

1997-05-27

209

Thermal stability of mixed-cation #alpha#-sialon ceramics

The UTST (University of Tokyo Spherical Tokamak) device was constructed for the purpose of exploring the formation of ultra-high beta ST (Spherical Tokamak) plasma using the double null plasma merging method. When two plasmas merge together to form a single plasma, magnetic field lines reconnect, and the magnetic field energy is converted to the plasma kinetic energy, increasing the plasma beta. The merging start-up has been demonstrated in the TS-3/4, START and MAST devices using coils inside the vacuum vessel and TS-3 plasma obtained 50% beta. In order to demonstrate the start-up in a more reactor relevant situation, UTST has all poloidal field coils outside the vacuum vessel. The first plasma experiment on the UTST was performed from December, 2007. In the result, the plasma obtained 10 kA by using only outer PF coils and single ST was generated at the lower area (z=-0.3 - -1.0[m]) close to a washer gun. This result suggests that another ...

2009-04-01

210

Spermatozoa of Sharpsnout sea bream (Diplodus puntazzo) and European sea bass (Dicentrarchus labrax) express opioid receptors

A series of #alpha#-sialon (#alpha#') compositions containing mixed stabilising cations were prepared, by introducing additional CaO to a basic Sm #alpha#-sialon compositions. The thermal stability of these Sm-Ca-containing #alpha#-sialon phases was investigated using XRD, SEM and EDXS techniques. It was found that the addition of calcium into the Sm #alpha#-sialon systems greatly improved the stability of the #alpha#-sialon phases. Calcium was found to be incorporated into the #alpha#-sialon structure, coexistent with the samarium, and partitioning of the calcium and samarium was observed between the #alpha#' phase and grain boundary phases. This indicates a technique which may be used to improve the thermal stability of the #alpha#' phase while maintaining good refractory phases at the sialon grain boundaries.

2003-01-02

211

British Library Electronic Table of Contents (United Kingdom)

Endogenous opioid peptides (EOP) are molecules affecting many biological functions influencing productive and reproductive performance. They increase in stress conditions and interact with specific opioidergic receptors (OR): delta, kappa and mu. Several studies in other animal species suggest that they can also affect sperm cell motility. In fish the ionic external environment modulates the increase of intracellular calcium ion that is required to activate sperm motility after spawning. In mammals OR are functionally associated to calcium channels and in fishes calcium is highly required for fish sperm activation. In this study the presence of OR on spermatozoa of two Perciform fish, the sharpsnout seabream (Diplodus puntazzo, family Sparidae) and the European sea bass (Dicentrarchus labr...

2010-01-01

212

Separation of lithium and calcium isotopes during chemical isotopic exchange in extraction systems with phosphoryl-containing podands

Process for producing calcium sulfate dihydrate during desulfurization of stack gases from power station boilers. Verfahren zur Herstellung von Calciumsulfat-Dihydrat im Zuge der Entschwefelung von Rauchgasen aus Kraftwerkskesselfeuerungen

A study was made on extraction of a series of lithium and calcium salts by monopodands L with common formula R-C_6H_4-O-(CH_2CH_2O)_n-C_6H_4-R, where R - CH_2P(O)Ph_2, n 1-3. Extraction-chromatographic separation of lithium and calcium isotopes in systems of metal aquacomplex-solvatocomplex with L in organic phase was conducted. It was established that separation coefficients of "6Li/"7Li isotopes ranged between 1.003 #+-#0.001 and 1.017 #+-#0.002 at the maximal separation degree equal to 1.60. Separation of "4"0Ca/"4"4Ca isotopes was not fixed. 12 refs., 4 figs., 1 tab.

213

Nanoscale calcium bismuth mixed oxide with enhanced photocatalytic performance under visible light

This is a process for producing calcium sulfate dihydrate during desulfurization of stack gases from power station boilers, where the stack gases are introduced into a washing tower and are treated with a washing water suspension containing lime in the washing tower, where oxygen in the form of air or of air enriched in oxygen is also blown into the washing tower, and where the washing water suspension drawn off from the washing tower is fed back to the washing tower at a temperature of 45 to 50/sup 0/C in the circuit and at least part of the flow goes via a thickener and where calcium sulfate dihydrate slurry is drawn off from the thickener.

1986-06-12

214

British Library Electronic Table of Contents (United Kingdom)

The objective of materials research is the development of economical, safe and efficient synthesis routes that lead to the formation of a photocatalyst which is able to overcome performance problems related to particle size, crystallinity, or low surface area. Here, we report high-quality functional nanoparticles of calcium bismuth mixed oxide with 15nm nominal size corresponding to a specific surface area of 41m^2/g which were produced by single-step flame spray synthesis (FSS). The high temperature of the flame afforded creation of oxygen vacancies which were quantified by near edge X-ray absorption fine structure (NEXAFS) spectra. These two parameters, developed active surface area and created in the flame oxygen vacancies, allowed to enhance the photocatalytic activity of calcium bismu...

2010-01-01

215

Mineral carbonation accelerated by dicarboxylic acids as a disposal process of carbon dioxide

British Library Electronic Table of Contents (United Kingdom)

Mineral carbonation is based on the reaction of carbon dioxide with metal-oxide bearing minerals, usually containing magnesium or calcium silicate, to form hardly soluble carbonates and other solid byproducts. The concept is based on acceleration of the naturally occurring rock weathering process. In the present work the calcium silicate is present in the mineral, wollastonite. To accelerate the process and make it potentially useful for practical applications, mineral carbonation is conducted here using an indirect two-step route in which the reactive component (Ca^2^+ ions in considered case) is first extracted from the mineral matrix and afterwards carbonated. Two solid byproducts are formed in this process: silica in the extraction step and calcium carbonate in the carbonation step. In...

2011-01-01

216

Luminescence properties of thallium crystal phosphors and their use in determining microgram quantities of thallium

Depression of calcium pump activity in renal cortex of vitamin D-deficient rats with secondary hyperparathyroidism

The preparation and luminescence properties of crystal phosphors based on alkali metal iodide and calcium oxide substrates were studied. The highest luminescence intensities were achieved with iodide substrates at 200/sup 0/ and with the calcium oxide substrate at 800/sup 0/. The calibration graphs were linear in the thallium concentration ranges 0.03-5.0 and 0.1-2.0 mu g using sodium and potassium oxides, respectively, and in the range 0.05-5 mu g using cesium iodide and calcium oxide. A method is proposed for the determination of down to 3 x 10/sup -4/% thallium in rocks, using a crystal phosphor with sodium iodide substrate.

1986-02-01

217

Depression of calcium pump activity in renal cortex of vitamin D-deficient rats with secondary hyperparathyroidism

To examine the hormonal regulation of the ATP-dependent Ca{sup 2+} pump in the kidneys, the ATP-dependent Ca{sup 2+} uptake by the basolateral membrane vesicles in the renal cortex was measured using radioactive calcium ({sup 45}Ca{sup 2+}) in rats with vitamin D deficiency or rats undergoing thyroparathyroidectomy. The V{sub max} of the Ca{sup 2+} pump activity was increased not only by administering calcitriol, but also by normalizing the serum calcium level in vitamin D-deficient rats. PTH suppressed the Ca{sup 2+} pump activity in normocalcemic vitamin D-deficient rats. Thyroparathyroidectomy did not affect the Ca{sup 2+} pump activity in the kidneys of normal rats. It was concluded that the ATP-dependent Ca{sup 2+} pump activity was depressed by secondary hyperparathyroidism in vitamin D-deficient rats. (author).

1990-01-01

218

To examine the hormonal regulation of the ATP-dependent Ca"2"+ pump in the kidneys, the ATP-dependent Ca"2"+ uptake by the basolateral membrane vesicles in the renal cortex was measured using radioactive calcium ("4"5Ca"2"+) in rats with vitamin D deficiency or rats undergoing thyroparathyroidectomy. The V_m_a_x of the Ca"2"+ pump activity was increased not only by administering calcitriol, but also by normalizing the serum calcium level in vitamin D-deficient rats. PTH suppressed the Ca"2"+ pump activity in normocalcemic vitamin D-deficient rats. Thyroparathyroidectomy did not affect the Ca"2"+ pump activity in the kidneys of normal rats. It was concluded that the ATP-dependent Ca"2"+ pump activity was depressed by secondary hyperparathyroidism in vitamin D-deficient rats. (author).

219

Chemistry of strontium

Thermal diffusion by Brownian motion induced fluid stress

This paper describes stable strontium as composed of four stable isotopes ( Sr 88, Sr 87, Sr 86, and Sr 84), of which Sr 88 contributes more than 82% to its composition. Strontium exists in three crystalline, plymorphic forms; face-centered cubic alpha form, hexagonal beta form and body-centered cubic gamma form. Strontium occupies in many physicochemical aspects an intermediate position between calcium and barium, as does the solubility of strontium salts. As a result of its oxidation potential, strontium readily forms oxides, halides, and sulfide. The author proposes that the slight discrimination against strontium incorporation into bony tissues may be due to the difference in ionic potential (14%) between strontium and calcium. Ionic potential is an indicator of the strength of ionic bonds: strontium has a smaller ratio of ionic charge to ionic radius when compared with calcium.

220

Shock stand-off distance of a solid sphere decelerating in transonic velocity range

The Ludwig-Soret effect, the migration of a species due to a temperature gradient, has been extensively studied without a complete picture of its cause emerging. Here we investigate the dynamics of DNA and spherical particles sub jected to a thermal gradient using a combination of Brownian dynamics and the lattice Boltzmann method. We observe that the DNA molecules will migrate to colder regions of the channel, an observation also made in the experiments of Duhr, et al[1]. In fact, the thermal diffusion coefficient found agrees quantitatively with the experimental value. We also observe that the thermal diffusion coefficient decreases as the radius of the studied spherical particles increases. Furthermore, we observe that the thermal fluctuations-fluid momentum flux coupling induces a gradient in the stress which leads to thermal migration in both systems.

2007-01-01

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221

British Library Electronic Table of Contents (United Kingdom)

The shock stand-off distance of a spherical model flying with transonic speeds is determined through numerical simulations. The model decelerates due to drag forces caused by the pressure and viscous shear stress at the model surface. Two-dimensional axisymmetric numerical codes with numerical grids fixed to the flying spherical model are used in the simulations. Numerically determined shock stand-off distances are compared with experimental data obtained in a previous study as well as with those obtained in our ballistic-range experiments. The numerical results and the experimental data are found to be in good agreement. In addition, the time-dependent shock stand-off distance of a decelerating model is investigated.

2011-01-01

222

Microstructure analysis of nanocrystalline powders by X-ray diffraction

Microstructural aspects of the corrosion of Alloy 800

The use of X-ray diffraction line profile analysis for the study of nanocrystalline powders is described. The fundamentals of the theory are presented in terms of crystallite/domain size, size distribution, lattice distortion, dislocations density and stacking faults. Line profile parameters and the methods of pattern fitting introduced to overcome the diffraction-line overlap problem are discussed. The approaches based of the integral breadth of the measured line profiles and the Fourier method are discussed. In addition, simplified approaches are also commented. Representative examples are selected to illustrate various cases of microstructure, such as nanomaterials with strain-free spherical nano crystallites, strain-free crystallites with anisotropic crystallite shape, anisotropic crystallites with microstrains and spherical crystallites with dislocation densities and crystallite size distributions. (author)

2001-09-23

223

Description of T/sub greater-than/ giant resonances in spherical nuclei

Transmission electron microscopy studies on solution-annealed Alloy 800 revealed small (100-200 nm), spherical-shaped titanium carbide (face centered cubic structure) and large (200 nm-5 #mu#m), faceted titanium nitride (hexagonal structure) particles randomly distributed in the austenite matrix. The volume fraction of former particles was found to be greater than that of the latter. Corrosion studies of the alloy in acidic, chlorides and acidic chloride environments at room temperature indicated that the passivity of Alloy 800 was adversely affected by the addition Cl"- ions. X-ray photoelectron spectroscopy revealed that the surface film formed on the alloy at the onset of passivity consisted of Cr"3"+ (as Cr_2O_3), without any Fe"3"+/Fe"2"+ or Ni"2"+. Scanning electron microscopy studies indicated initiation of pitting at large, faceted particles, not at small, spherical-shaped ones.

2004-12-01

224

Atomic density functions: atomic physics calculations analyzed with methods from quantum chemistry

Formulas are obtained for calculation of the energies and B(Elambda) values of T/sub greater-than/ giant resonances in the quasiparticle-phonon model of the nucleus. Characteristics of giant dipole resonances are calculated in several spherical nuclei and the correct location is obtained for T/sub less-than/ and T/sub greater-than/ collective 1/sup -/ states. The calculated ratios sigma/sub -/1(T/sub greater-than/)/sigma/sub -/1(T/sub less-than/) agree with the experimental data for /sup 88/Sr, /sup 90/Zr, and /sup 92/Mo and are 3 times larger than the experimental values for /sup 116,120,124/Sn. The decrease of the cross sections sigma/sub -/1(T/sub greater-than/) in /sup 124/Sn in comparison with /sup 116/Sn is correctly reproduced.

1982-03-01

225

A novel approach to the dynamics of Szekeres dust models

This contribution reviews a selection of findings on atomic density functions and discusses ways for reading chemical information from them. First an expression for the density function for atoms in the multi-configuration Hartree--Fock scheme is established. The spherical harmonic content of the density function and ways to restore the spherical symmetry in a general open-shell case are treated. The evaluation of the density function is illustrated in a few examples. In the second part of the paper, atomic density functions are analyzed using quantum similarity measures. The comparison of atomic density functions is shown to be useful to obtain physical and chemical information. Finally, concepts from information theory are introduced and adopted for the comparison of density functions. In particular, based on the Kullback--Leibler form, a functional is constructed that reveals the periodicity in Mendeleev's table. Finally a quantum similarity ...

2011-01-01

226

A fast multipole transformation for global climate calculations

We obtain an elegant and useful description of the dynamics of Szekeres dust models (in their full generality) by means of "quasi--local" scalar variables constructed by suitable integral distributions that can be interpreted as weighed proper volume averages of the local covariant scalars. In terms of these variables, the field equations and basic physical and geometric quantities are formally identical to their corresponding expressions in the spherically symmetric LTB dust models. Since we can map every Szekeres model to a unique LTB model, rigorous results valid for the latter models can be readily generalized to a non--spherical Szekeres geometry. The new variables lead naturally to an initial value formulation in which all scalars are expressed as scaling laws in terms of their values at an arbitrary initial space slice. These variables also yield a significant simplification of numerical work, since the fluid flow evolution equations ...

2011-01-01

227

Zinc release from thapsigargin/IP3-sensitive stores in cultured cortical neurons

A fast multipole transformation is adapted to the evaluation of summations that occur in global climate calculations when transforming between spatial and spherical harmonic representations. For each summation, the timing of the fast multipole transformation scales linearly with the number of latitude gridpoints, but the timing for direct evaluations scales quadratically. In spite of a larger computational overhead, this scaling advantage renders the fast multipole method faster than direct evaluation for transformations involving greater than approximately 300 to 500 gridpoints. Convergence of the fast multipole transformation is accurate to machine precision. As the resolution in global climate calculations continues to increase, an increasingly large fraction of the computational work involves the transformation between spatial and spherical harmonic representations. The fast multipole transformation offers a significant reduction in ...

1996-01-01

228

The opening of the two pores of the Hv1 voltage-gated proton channel is tuned by cooperativity

BackgroundChanges in ionic concentration have a fundamental effect on numerous physiological processes. For example, IP₃-gated thapsigargin sensitive intracellular calcium...Full Text Available

229

The nucleation kinetics of calcium sulfate dihydrate in NaCl solutions up to 6 m and 90 C

SUMMARYIn voltage-gated sodium, potassium, and calcium channels the functions of ion conduction and voltage sensing are performed by two distinct structural units: the pore domain...Full Text Available

2010-01-01

230

The L-type calcium channel inhibitor diltiazem prevents cardiomyopathy in a mouse model

The crystallization of calcium sulfate from aqueous solutions with NaCl is both geological and industrial interest because NaCl is the dominant solute in natural brines and many industrial fluids. Induction periods for the nucleation of calcium sulfate dihydrate were experimentally determined as a function of supersaturation in NaCl solutions from 0 to 6 m at 25 C and in 3.0-m NaCl solutions at temperatures from 25 to 90 C. Using classic nucleation theory, the interfacial tension between gypsum and 3.0-m NaCl solution was estimated to be about 39 mJ/m[sup 2] at 25 C and increases with increasing temperature (to 63 mJ/m[sup 2] at 90 C). It was observed that the induction period decreases with increasing NaCl concentrations up to 3 m and then starts to increase slightly at a given temperature and saturation state. The electrolyte effect on nucleation was proportional to the enhanced solubility of calcium sulfate dihydrate in ...

1994-02-01

231

Studies on Inhibition of Intestinal Absorption of Radioactive Strontium

Dominant mutations in sarcomere protein genes cause hypertrophic cardiomyopathy, an inherited human disorder with increased ventricular wall thickness, myocyte hypertrophy, and disarray. To understand...Full Text Available

2002-04-15

232

Strength and fluoride release characteristics of a calcium fluoride based dental nanocomposite

A method is reported which permits selective suppression of absorption of radioactive strontium from ingested food material, permitting the calcium to be available to the body. Studies were carried...Full Text Available

1964-08-08

233

Severe Hypocalcemia due to Vitamin D Deficiency after Extended Roux-en-Y Gastric Bypass

Secondary caries and restoration fracture remain the two most common problems in restorative dentistry. Release of fluoride ions (F) could be a substantial benefit because F could enrich neighboring...Full Text Available

2008-11-01

234

Role of Calcium in Serine Transport into Tobacco Cells

Vitamin D deficiency is a well-known comorbidity of obesity that can be exacerbated after bariatric surgery and can predispose the patient for hypocalcemia. Vitamin D and calcium doses to prevent and...Full Text Available

2011-01-01

235

Resistance of Bacillus subtilis var. niger Spores Occluded in Water-insoluble Crystals to Three Sterilization Agents

The transport of serine into tobacco (Nicotiana tabacum L. var. Xanthi) cells grown in liquid medium was studied. Serine transport was maximal below pH 4.0. A time-dependent stimulation...Full Text Available

1978-12-01

236

Regulation of Vacuolar H⁺-Pyrophosphatase by Free Calcium ¹

The resistance to destruction of spores of Bacillus subtilis var. niger occluded in crystals of calcium carbonate and exposed to ethylene oxide and moist and dry heat...Full Text Available

1967-07-01

237

Regulation of Calcium Influx in Chara¹

The H⁺-translocating inorganic pyrophosphatase (H⁺-PPase) associated with vesicles of the vacuolar membrane (tonoplast) isolated from beet (Beta vulgaris L.) is...Full Text Available

1992-12-01

238

Rapid Action of Estrogens on Intracellular Calcium Oscillations in Primate Luteinizing Hormone-Releasing Hormone-1 Neurons

Measurements were made of ⁴⁵Ca influx into isolated internodal cells of Chara corallina and also into internodal cells of intact plants. ⁴⁵Ca influx was closely...Full Text Available

1992-10-01

239

Radionuclide X-ray fluorescence analysis of waste water from the production of citric acid

Feedback controls of estrogen in LHRH-1 neurons play a pivotal role in reproductive function. However, the mechanism of estrogen action in LHRH-1 neurons is still unclear. In the present study, the...Full Text Available

2008-03-01

240

Radionuclide X-ray fluorescence analysis of waste water from the production of citric acid

Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid.

1982-02-18

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241

Propagation of an alkaline wave with a short contact time through an argilite sample from the Meuse-Haute Marne underground laboratory; Propagation d'une onde alcaline a temps de contact court a travers un echantillon d'argilite de l'est

Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid. (author).

1982-02-01

242

Process for the removal of sulfur oxides from exhaust gases using slurry of red mud containing calcium ion

In the framework of the feasibility study of radioactive waste disposal in deep geologic formations, a clay formation (named 'argilite de l'Est') has been selected in the Meuse-Haute Marne region (France) for the construction of an underground laboratory. The percolation of alkaline solutions through the argilite has been studied using column experiments with short residence times (30 min). These experiments simulate the leaching of a cement which could be used in the building materials of the laboratory. The alkaline solutions used are mono-cationic solutions of calcium, sodium and strontium. The behaviour of calcium is differentiated from the other cations. For all alkaline solutions (NaOH, Ca(OH){sub 2} or Sr(OH){sub 2}) chemical reactions consuming both hydroxide ions and their associated cations have been evidenced. These reactions are heterogenous reactions of surface adsorption by site ionization. The ...

2001-07-01

243

Physiological calcium concentrations regulate calmodulin binding and catalysis of adenylyl cyclase exotoxins

A process is given for the removal of sulfur oxides from exhaust gases by absorbing with a slurry of red mud containing calcium ion which comprises the steps of: (1) contacting an exhaust gas containing sulfur oxides of not higher than about 100/sup 0/ C with a slurry of red mud containing calcium ion led from the next step (2) to take up sulfur oxides in the gas until ph of the slurry becomes in the range of 4.3 to less than 6 while maintaining the molar fraction of SO/sub 4/-- to total SO/sub 2/ in the slurry within the said pH range at 0.05 to 0.7; and then, (2) contacting the treated gas with a fresh slurry of red mud containing calcium ion to further take up sulfur oxides in the gas while maintaining the concentration of NaHSO/sub 3/ in the slurry at not more than about 8 g/l.

1980-09-16

244

Neurobehavioral effects of power-frequency electromagnetic fields.

Edema factor (EF) and CyaA are calmodulin (CaM)-activated adenylyl cyclase exotoxins involved in the pathogenesis of anthrax and whooping cough, respectively. Using spectroscopic, enzyme kinetic and...Full Text Available

2002-12-16

245

Intra- and extracellular calcium modulates stereocilia stiffness on chick cochlear hair cells.

Some laboratory experiments have suggested that power-frequency electric and magnetic fields (EMF) may be capable of influencing calcium efflux from cell membranes, pineal function, and circadian rhythms....Full Text Available

1993-12-01

246

Imaging of calcium transients in skeletal muscle fibers.

Segments of the chick basilar papilla were isolated and maintained in culture medium. The sensory hair bundle of individual hair cells was observed with light microscopy and stimulated with a water...Full Text Available

1994-02-01

247

Hysteretic Behavior of Proprotein Convertase 1/3 (PC1/3)

Epifluorescence images of Ca2+ transients elicited by electrical stimulation of single skeletal muscle fibers were studied with fast imaging techniques that take advantage of the large fluorescence...Full Text Available

1991-01-01

248

Hydrogenolysis reaction of deashed coal loaded K and Ca. K to Ca wo tanjishita dakkai sekitan no suisoka bunkai tokusei

The proprotein convertases (PCs) are calcium-dependent proteases responsible for processing precursor proteins into their active forms in eukariotes. The PC1/3 is a pivotal enzyme of this family that...Full Text Available

249

Gynura procumbens Merr. decreases blood pressure in rats by vasodilatation via inhibition of calcium channels

Taiheiyo coal deashed using acid treatment and loaded with potassium or calcium was hydro-cracked under gaseous phase to discuss effects of these metals on liquefaction reaction. In addition, the loaded coal was added with red mud catalyst to examine effects of the addition. The loaded potassium has a softening power, and particularly the potassium adsorbed into surface and micropores in the coal decomposes selectively HI-BS and BI-PS and generates gas and HS. On the other hand, potassium deposited on coal surface promotes direct gas production from the coal. Irrespective of its loading modes, calcium has a catalytic nature to produce HI-BS selectively. Calcium also acts to impede decomposition of HI-BS into HS. Adding red mud catalyst to potassium loaded coal increases the inversion rate and the liquefaction yield, and most of the increase is accounted for by HI -BS, and BI-PS. When red mud catalyst is added to ...

1992-11-05

250

Effects of Prolonged High Phosphorus Diet on Phosphorus and Calcium Balance in Rats

INTRODUCTION:Gynura procumbens has been shown to decrease blood pressure via inhibition of the angiotensin‐converting enzyme. However, other mechanisms that...Full Text Available

2011-01-01

251

Effect of Anionic Salt and Highly Fermentable Carbohydrate Supplementations on Urine pH and on Experimentally Induced Hypocalcaemia in Cows

The amount of phosphorus contained in food as food additives is currently increasing and a high intake of phosphorus can cause various diseases. To determine the effects of a prolonged high phosphorus...Full Text Available

2007-05-01

252

Disulfide Bonds and the Quaternary Structure of Factor VIII/von Willebrand Factor

The objective of this experiment was to determine the effect of dietary grain on calcium homeostasis. Six rumen-fistulated dairy cows with 3 or more previous lactations and no history of parturient...Full Text Available

2004-01-01

253

Dietary Ammonium Chloride for the Acidification of Mouse Urine

Human Factor VIII/von Willebrand factor, purified by calcium citrate-cellulose chromatography and 4% agarose gel filtration was subjected to sodium dodecyl sulfate gel electrophoresis on gels containing...Full Text Available

1978-09-01

254

Cytoplasmic Calcium Increases in Response to Changes in the Gravity Vector in Hypocotyls and Petioles of Arabidopsis Seedlings1

A novel therapeutic compound was found to induce bladder tumors in male rats. Given the location of the tumors and the increased amounts of calcium- and magnesium-containing solids found in the urine...Full Text Available

2009-03-01

255

Plants respond to a large variety of environmental signals, including changes in the gravity vector (gravistimulation). In Arabidopsis (Arabidopsis thaliana) seedlings, gravistimulation...Full Text Available

2008-02-01

256

Citrat og nyresten

Chemical neutralization to control denting in nuclear steam generators

Citrate is an important naturally occurring inhibitor of calcium stone formation in urine. Urinary citrate excretion was examined in 43 consecutive patients with recurrent idiopathic calcium nephrolithiasis and in 50 normal controls by a specific enzymatic technique. Hypocitraturia (<1.6 mmol/24h) was found in 14 (33%) stone formers compared to 6 (12%) normal controls (p = 0.03). Citrate excretion expressed as citrate-creatinine ratio in 24 hour urine samples was significantly lower in the stone formers than in the healthy controls (p = 0.03), and significantly lower in healthy men, compared to healthy females (p = 0.006). There was a great variability in urinary citrate levels in both groups, and a considerable overlap in the urinary citrate excretion between normal subjects and stone formers. Factors other than urinary citrate excretion must therefore be of importance in the pathophysiology of calcium stone formation. ...

1993-01-01

257

Calcium/Calmodulin-Dependent Protein Kinase II Mediates Hippocampal Glutamatergic Plasticity During Benzodiazepine Withdrawal

Laboratory testing at Combustion Engineering has indicated promise in controlling simulated steam generator tube denting through chemical neutralization. Testing was limited to on-line treatment, and two neutralizers have been evaluated: calcium hydroxide and boric acid. On-line treatment with calcium hydroxide successfully halted active denting whenever the bulk calcium concentration (in ppm) equaled or exceeded the bulk chloride concentration (in ppm). Calcium hydroxide also was effective as an alternative to ammonia as a pH controlling agent in two tests conducted without ingress of chloride. On-line treatment with boric acid consisted of a four-day soak at simulated low (approximately 30 percent) power with 50 ppm B followed by one month full-power operation with 10 ppm B. This treatment also halted denting. Nondestructive and destructive examination of test boilers gave no indication of adverse ...

258

Calcium gradients and buffers in bovine chromaffin cells.

Benzodiazepine withdrawal anxiety is associated with potentiation of α-amino-3-hydroxy-5-methyl-4-isoxazolepropionate receptor (AMPAR) currents in hippocampal CA1 pyramidal...Full Text Available

2010-08-01

259

Calcium Effects on Stomatal Movement in Commelina communis L. ¹

1. Digital imaging and photometry were used in conjunction with the fluorescent Ca2+ indicator, Fura-2, to examine intracellular Ca2+ signals produced by depolarization of single adrenal chromaffin...Full Text Available

1992-05-01

260

Cadherin Mechanics and Complexation: The Importance of Calcium Binding

Stomatal movements depend on both ion influx and efflux; attainment of steady state apertures reflects modulation of either or both processes. The role of Ca²⁺ in those two processes was...Full Text Available

1988-07-01

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261

Amyloid Oligomer Neurotoxicity, Calcium Dysregulation, and Lipid Rafts

E-cadherins belong to a family of membrane-bound, cellular adhesion proteins. Their adhesive properties mainly involve the two N-terminal extracellular domains (EC1 and EC2). The junctions between these...Full Text Available

2005-12-01

262

Age-dependent changes in Ca²⁺ homeostasis in peripheral neurones: implications for changes in function

Amyloid proteins constitute a chemically heterogeneous group of proteins, which share some biophysical and biological characteristics, the principal of which are the high propensity to acquire an incorrect...Full Text Available

263

Acetylsalicylic acid as soluble tablets

Calcium ions represent universal second messengers within neuronal cells integrating multiple cellular functions, such as release of neurotransmitters, gene expression, proliferation, excitability,...Full Text Available

2007-06-01

264

International Science & Technology Center (ISTC)

Realization of Pharmacological Tests, Development of the Specifications and Technical Documentation and Registration in the Russian Federation of Medical Products as Soluble Tablets of Acetylsalicylic Acid/Calcium Carbonate in Two Dosages Intended for use as Medical Products Smoothing, Febrifugal and Antiaggregation Action and Development of Technology of Tableting the Above-Stated Preparations

265

A new method to measure necrotic core and calcium content in coronary plaques using intravascular ultrasound radiofrequency-based analysis

A mathematical/physiological model of parathyroid hormone secretion in response to blood-ionized calcium lowering in vivo.

Although previous intravascular ultrasound (IVUS) radiofrequency-based analysis data showed acceptable reproducibility for plaque composition, measurements are not easily obtained, particularly that...Full Text Available

2010-04-01

266

A Kinetic Model of Dopamine- and Calcium-Dependent Striatal Synaptic Plasticity

The aim of the present study was to test a mathematical model of the biochemical processes in the parathyroid glands responsible for the secretion of parathyroid hormone resulting from extracellular calcium reduction. A double exponential curve described the parathyroid hormone secretion induced by rapid lowering of blood-ionized calcium in humans with normal as well as abnormal parathyroid tissue. Our data show that it was possible to establish a simple mathematical model of the parathyroid hormone response to blood-ionized calcium lowering, sufficient to fit experimental data obtained from patients with abnormal and normal parathyroid tissue. The fitted parameters showed no significant differences between patients with insulin-dependent diabetes mellitus and controls. In primary hyperparathyroidism, the parathyroid hormone production and steady-state transport across the cell membrane were increased, probably due to the ...

1997-01-01

267

* NASA TECHNICAL TRANSLATION NASA TT F-11435 INFLUENCE OF ...

Corticostriatal synapse plasticity of medium spiny neurons is regulated by glutamate input from the cortex and dopamine input from the substantia nigra. While cortical stimulation alone results in long-term...Full Text Available

2010-02-01

268

Yttrium Calcium Oxyborate for high average power frequency doubling and OPCPA

isotherme, dans un courant d'azote ou sous vide entretenu. I t. Comptes Rendus Scientific Academy, Paris, Vol. 265 pyrolyse du carbonate de calcium, ...

269

The early days of parathyroid surgery.

Significant progress has been achieved recently in the growth of Yttrium Calcium Oxyborate (YCOB) crystals. Boules have been grown capable of producing large aperture nonlinear crystal plates suitable for high average power frequency conversion or optical parametric chirped pulse amplification (OPCPA). With a large aperture (5.5 cm x 8.5 cm) YCOB crystal we have demonstrated a record 227 W of 523.5nm light (22.7 J/pulse, 10 Hz, 14 ns). We have also demonstrated the applicability of YCOB for 1053 nm OPCPA.

2006-06-20

270

Stabilisation of #alpha#-Sialons using multiple additives

The parathyroid endocrine glands, usually four in number and about the size of a split pea, lie on either side of the posterior aspect of the thyroid gland. Occasionally one or more of these structures are found in an aberrant position in the neck or even in the superior mediastinum. The parathyroid secretion, parathormone, regulates the level of serum calcium within sharply defined limits. Lack of parathormone, with lowering of the serum calcium, results in hyper-irritability of skeletal muscle, the clinical condition known as tetany. This is encountered following inadvertent removal or bruising of the parathyroid glands at thyroidectomy. PMID:21488463

2011-03-01

271

Physical aspects of FGD by-products

Multi-cation #alpha#-Sialon ceramics were prepared using mixtures of samarium with calcium, magnesium, yttrium and ytterbium, and compared with a pure Sm-Sialon of equivalent total stabilising cation composition. A ratio of 80eq% samarium to 20eq% of the second stabilising additive was used. Samples were fired at 1820 deg C and subsequently heat treated at 1450 deg C. XRD phase analysis showed that all additives resulted in greater #alpha#-Sialon stability, and that calcium was the most effective additive for the stabilisation of the #alpha#-Sialon phase. Copyright (1998) Australasian Ceramic Society

1998-09-28

272

New coumarin-based sensor molecule for magnesium and calcium ions

Air pollution constraints continue to intensify, resulting in solid waste volume increases. An example of this is coal burning power plant flue gas desulfurization by scrubbing. The aqueous suspensions of calcium sulfate hemihydrate or calcium sulfate dihydrate will exceed 200 million tons annually by the year 2000. Disposal of these wastes can have massive environmental effects, due to physical instability and leaching to groundwater. One alternate disposal technique is sulfopozzolanic fixation, converting the FGD waste by addition of fine coal ash and an alkaline earth additive, into a monolithic mass. 6 refs., 17 figs., 3 tabs.

1992-01-01

273

British Library Electronic Table of Contents (United Kingdom)

A new coumarin-based sensor molecule (L1) has been synthesized and this was found to bind calcium and magnesium ions more effectively as compared to other alkali/alkaline earth/lanthanide and certain transition metal ions. A significant enhancement in fluorescence intensity was observed on binding to Ca2+ and Mg2+ ions; while a minor quenching was observed for weakly bound Hg2+, Ni2+, Fe3+, and Co2+ ions. PET process, coupled with the ICT process, is proposed to explain the observed spectral response.

2009-01-01

274

Method of producing calcium sulfate semihydrate in conjunction with the desulfurization of flue gases

Influence of microalloying on the corrosion resistance of steel in saturated calcium hydroxide

Calcium sulfate dihydrate in large crystal form is produced by maintaining the circulation of the lime containing scrubbing solution in the desulfurization scrubbing of flue gases from a power plant boiler so that it has a residence time of 5 to 25 hours, preferably 15 hours. The crystals are moved by passing a portion of the recirculation through a thinner in which a sludge containing crystals with a mean particle size of which 90% is in excess of 100 microns is removed. This product can be dewatered and treated with sulfuric acid and steam to convert it to the alpha semihydrate and is free from sulfite.

1985-03-05

275

The influence of microalloying vanadium or titanium on improving the corrosion resistance of mild steel in saturated calcium hydroxide solution was investigated. Potential-time, potentiodynamic polarization, and impedance measurement techniques were employed. The corrosion products have been examined by infrared and X-ray diffraction analysis and by scanning electron microscopy. It has been shown that the grain refining, due to microalloying, plays an important role in enhancing the corrosion resistance of steel. Scales of calcite and iron oxides on top of a protective oxide are formed on the investigated steels.

276

Heat storage composition

Exact solution to NO/sub 2/ absorption

A heat storage compostion comprises sodium sulfate decahydrate as main component, a supercooling inhibitor, and a solid-liquid separation inhibitor. The composition is characterized in that hydraulic calcium sulfate and/or calcium sulfate dihydrate is contained as the solid-liquid separation inhibitor in an amount of 2-15 wt% base on the whole weight of the composition, whereby the solid-liquid separation, i.e. the sedimentation of the anhydrous sodium sulfate during the phase transition, is effectively prevented and the long-term stability is improved. The long-term stabilty of the composition can be more improved by addition of a silcia series of thickener.

1987-05-05

277

Regulation of the phosphoinositide pathway in cultured Sertoli cells from immature rats: effects of follicle-stimulating hormone and fluoride

This paper describes an exact solution to the problem of absorbing nitrogen dioxide into aqueous solution, in which case the nitrogen dioxide concentration is allowed to vary over a wide range. The authors have worked on the rate of calcium sulfate dihydrate scale formation on the reverse osmosis membrane and find this phenomena can be treated by the crystallization theory. The authors performed long-term experiments using calcium sulfate dihydrate solution with addition of sodium hexametaphosphate (SHMP) and commercially available organophosphates and investigated the mechanism of the inhibitor's action quantitatively.

1984-04-01

278

The triaxial motion in Mo isotopes

Many hormones elicit effects on target cells by stimulating the enzyme phospholipase-C, which catalyzes the hydrolysis of phosphoinositides to the intracellular second messengers diacylglycerol and inositol phosphates. The present study examined the roles of FSH and guanine nucleotide-binding proteins (G-proteins) in regulating the hydrolysis of phosphoinositides in Sertoli cells. Sertoli cell cultures prepared from 16- to 18-day-old rats were incubated for 24 h with myo-[2-3H] inositol to label endogenous phospholipids. Treatment of cells from 0.5-20 min with preparations of ovine FSH ranging in potency from 1-60 times that of NIH FSH S1 did not affect accumulation of inositol phosphates. Levels of total [3H]inositol phosphates [[3H]inositol mono-, di-, and triphosphates (IP, IP2, and IP3)] in FSH-treated cultures was 75-120% the levels in control cultures over the various time intervals studied. Addition of testosterone ...

279

The triaxial motion in Mo isotopes

The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of [sup 87]Mo are studied in detail and explained by the evolution of the [gamma]-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N [>=] 47 for the spherical shape of the Mo isotopes. (orig.)

1993-11-22

280

Representations of the conformal Lie algebra in the space of tensor densities on the sphere

The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of "8"7Mo are studied in detail and explained by the evolution of the #gamma#-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N #>=# 47 for the spherical shape of the Mo isotopes. (orig.).

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281

Performance improvement of pasted nickel electrodes with an addition of ball-milled nickel hydroxide powder

Let ${\\mathcal F}_\\lambda(\\mathbb{S}^n)$ be the space of tensor densities on $\\mathbb{S}^n$ of degree $\\lambda$. We consider this space as an induced module of the nonunitary spherical series of the group $\\mathrm{SO}_0(n+1,1)$ and classify $(\\mathrm{so}(n+1,1),\\mathrm{SO}(n+1))$-sim$unitary submodules of ${\\mathcal F}_\\lambda(\\mathbb{S}^n)$ as a function of $\\lambda$.

2003-01-01

282

On the homology of exotic Springer fibers

Spherical {beta}-Ni(OH){sub 2} was modified by a low-cost method of normal ball milling (NBM), and the physical properties of both ball-milled and un-milled Ni(OH){sub 2} were characterized by transmission electron microscopy, specific surface area, particle size distribution and X-ray diffraction. It was found that NBM could obviously increase the surface area, decrease the particle and crystallite size, and reduce the crystallinity of {beta}-Ni(OH){sub 2}, which were advantageous to the improvement of the electrochemical activity of Ni(OH){sub 2}. NBM also lowered the packing density and flowability of Ni(OH){sub 2}, as revealed by the measurements of tapping density and angle of repose. Electrochemical performances of pasted nickel electrodes with an addition of ball-milled Ni(OH){sub 2} to spherical Ni(OH){sub 2} as the active material were investigated, and were compared with those of the pure spherical Ni(OH){sub 2} ...

2006-09-15

283

Integral testing of the evaluated data files for silicon, zirconium, niobium and iron

We determine the structure of the total homology groups of exotic Springer fibers as affine Weyl group representations. As applications, we provide single top/socle property of standard modules in the exotic Deligne-Langlands correspondence (except for root of unity case), an analogue of Verma's theorem, the coincidence of analytic/geometric gradings in the $C ^{\\infty}$-realization of anti-spherical modules of graded Hecke algebras of type $\\mathsf{BC}$ with unequal parameters, among others.

2011-01-01

284

Influence of defects in compound single crystals on the critical angle of planar channeling

The evaluated data testing for Si, Zr, Nb and Fe materials has been performed through the analyses of the neutron leakage spectrum from spherical assemblies measured in integral benchmark experiments with (d,t) and Cf fission neutron sources. Intercomparisons of the calculated from BROND-2, ENDF/B-6 and JENDL-3 data files with experimental results are presented.

1994-12-31

285

Imaging Three Dimensional Two-Particle Correlations for Heavy-Ion Reaction Studies

The theoretical treatment of the relation between the critical angle of planar channeling and the characteristics of crystal lattice defects is carried out. The predictions are made about some typical forms of the critical angle dependence on the mean-square static displacement produced by defects, and then these predictions are detailed for the cases of homogeneous disordering, spherical clusters of point defects and dislocation loops. Analytical results are supported by the exact computer calculations for the defects in the intermetallic A-15 compounds.

1985-01-01

286

Feynman rules for gauge fields in the presence of a dielectric medium

The authors report an extension of the source imaging method for analyzing three-dimensional sources from three-dimensional correlations. The technique consists of expanding the correlation data and the underlying source function in spherical harmonics and inverting the resulting system of one-dimensional integral equations. With this strategy, they can image the source function quickly, even with the extremely large data sets common in three-dimensional analyses.

2005-06-27

287

Radiolabeling of a wound-inducible pyridoxal phosphate utilizing protein from tomato: evidence for its identification as ACC synthase

T. D. Lee's method for developing the Feynman rules for gauge fields in a cavity is reformulated in terms of path integral. His work is then extended by deriving these rules, in the Feynman gauge, for a spherical cavity. In any gauge only the gauge particle propagator is altered, while all the Feynman rules for gauge field couplings are left unaltered by the presence of a dielectric medium.

1983-10-15

288

Mechanism of biosorption of Heavy metals by mucor rouxii

Aminocyclopropane 1-carboxylic acid (ACC) synthase, a pyridoxal phosphate utilizing enzyme, catalyzes the conversion of S-adenosylmethionine to ACC, the rate limiting step in the biosynthesis of the plant hormone, ethylene. Ethylene, besides being involved in normal plant growth processes, is also produced in response to stress, e.g. wounding, pathogen infection, etc. The authors report the partial purification (400 fold) of ACC synthase from wounded pink tomato pericarp by classical techniques including ammonium sulfate precipitation, ion exchange and phenyl sepharose chromatography. Further purification results in a decrease in specific activity apparently due to the instability of the enzyme and the low levels present in plant tissue. Radiolabeling of a pyridoxal phosphate-utilizing protein in the ACC synthase enriched fraction was achieved. Evidence that this radiolabeled protein is ACC synthase will be presented. Amino acid sequence ...

1986-06-08

289

Identification of the binding domain for NADP"+ of human glucose-6-phosphate dehydrogenase by sequence analysis of mutants

Fungi such as Aspergillus niger and Mucor rouxii are capable of removing heavy metals from aqueous solutions. The role various functional groups play in the cell wall of M. rouxii in metal biosorption of lead, cadmium, nickel and zinc was investigated in this paper. The biomass was chemically treated to modify the functional carboxyl, amino and phosphate groups. These modifications were examined by means of infrared spectroscopy. It was found that an esterification of the carboxyl groups and phosphate and a methylation of the amine groups significantly decreased the biosorption of the heavy metals studied. Thus, the carboxylate, amine and phosphate groups were recognized as important in the biosorption of metal ions by M. rouxii biomass. The role the lipids fraction play was not significant. The study showed that Na, K, Ca and Mg ions were released from the biomass after biosorption of Pb,Cd,Ni and Zn, indicating that ion ...

2008-08-15

290

Development of value-added products from alumina industry mineral wastes using low-temperature-setting phosphate ceramics

Human erythrocyte glucose-6-phosphate is normally quite stable in the presence of 10 #mu#M NADP"+. Certain glucose-6-phosphate dehydrogenase variants lose virtually all their activity at this concentration of NADP"+ but are reactivated by 200 #mu#M NADP"+. Such variants presumably have a defect in their NADP"+-binding site. The authors analyzed the sequence of cDNA or genomic DNA from seven unrelated patients with hemolytic anemia due to the inheritance of variants that are reactivated by NADP"+. Six patients had substitutions of one of three adjacent amino acids, and the seventh patient had another amino acid substitution 23 residues downstream. These amino acids are highly conserved, all being present in rat and all but one being found also in Drosophila. The anomalous electrophoretic behavior of some of the variants can be explained by their loss of ability to bind NADP"+. The conclude that the region in which these mutations occur defines ...

291

Development and application of microbial selective plugging processes

A room-temperature process for stabilizing mineral waste streams has been developed, based on acid-base reaction between MgO and H3PO4 or acid phosphate solution. The resulting waste form sets into a hard ceramic in a few hours. In this way, various alumina industry wastes, such as red mud and treated potliner waste, can be solidified into ceramics which can be used as structural materials in waste management and construction industry. Red mud ceramics made by this process were low-porosity materials ({approx}2 vol%) with a compression strength equal to portland cement concrete (4944 psi). Bonding mechanism appears to be result of reactions of boehmite, goethite, and bayerite with the acid solution, and also encapsulation of red mud particles in Mg phosphate matrix. Possible applications include liners for ponds and thickned tailings disposal, dikes for waste ponds, and grouts. Compatability problems arising at the interface of the liner and ...

1996-01-01

292

Status and progress in sludge washing: A pivotal pretreatment method

Phillips Petroleum Company recently completed a microbial selective plugging (MSP) pilot at the North Burbank Unit (NBU), Shidler, Oklahoma. Nutrients were selected for the pilot that could stimulate indigenous microflora in the reservoir brine to grow and produce exopolymer. It was found that soluble corn starch polymers (e.g., maltodextrins) stimulated the indigenous bacteria to produce exopolymer, whereas simple sugars (e.g., glucose and sucrose), as well as complex media (e.g., molasses and Nutrient Broth), did not. Injection of maltodextrin into rock cores in the presence of indigenous NBU bacteria resulted in stable permeability reductions (> 90%) across the entire length, while injection of glucose resulted only in face plugging. In addition, it was found that organic phosphate esters (OPE) served as a preferable source of phosphorus for the indigenous bacteria, since orthophosphates and condensed phosphates precipitated in NBU brine ...

1995-12-31

293

Precise lithium isotopic analysis by thermal ionization mass spectrometry using lithium phosphate as an ion source material

Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and leaching operations involve batchwise mixing, settling, and ...

1995-01-01

294

Kinetics of inhibition of green crab (Scylla serrata) alkaline phosphatase by sodium (2,2'-bipyridine) oxodiperoxovanadate.

A high-precision Li isotope analysis was developed for determining the Li"+ ion emitted from lithium phosphate as an ion source material by a Re double-filament ionization method in the thermal ionization mass spectrometry. In this method, Li isotopic fractionation is distinctly less sensitive to the filament temperature than those in the previous methods, and stable and high ion beam intensity of more than 8 x 10"-"1"1 A for "7Li is obtained. These advantages in determining the "7Li/"6Li ratio result in the analytical reproducibility of 0.26 per mille (1#sigma#). Furthermore, the sample preparation is simple and the low temperature (850degC) required by this method ensures the analysis of the isotopic composition of small amounts of Li with less influence of Li contamination to the sample, compared with the previous methods. (author).

295

High-temperature investigations of the rare earth NZP phosphates R {sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3} (R = La, Nd, Eu, Lu) by drop calorimetry

Green crab (Scylla serrata) alkaline phosphatase (EC 3.1.3.1) is a metalloenzyme, which catalyzes the nonspecific hydrolysis of phosphate monoesters. The kinetics of inhibition of the enzyme by sodium (2, 2'-bipyridine) oxodiperoxovanadate, pV(bipy), has been studied. The time course of the hydrolysis of p-nitrophenyl-phosphate catalyzed by the enzyme in the presence of different pV(bipy) concentrations showed that at each pV(bipy) concentration, the rate decreased with increasing time until a straight line was approached, the straight line slopes are the same for all concentrations. The results suggest that the inhibition of the enzyme by pV(bipy) is a slow, reversible reaction with fractional remaining activity. The microscopic rate constants are determined for the reaction of inhibitor with the enzyme. PMID:10691182

1999-10-01

296

Fluoride phosphate Li{sub 2}CoPO{sub 4}F as a high-voltage cathode in Li-ion batteries

The high-temperature enthalpy increments of the phosphates La{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3}, Nd{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3}, Eu{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3} and Lu{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3} have been measured by high-temperature drop calorimetry in the temperature range 484.5-1090.7 K. From these results the heat capacity of the studied compounds has been derived.

2007-07-31

297

Distinguishing two groups of flavin reductases by analyzing the protonation state of an active site carboxylic acid

As a new high-voltage cathode candidate for post 4V cathodes, ordered-olivine LiCoPO{sub 4} and fluoride phosphate, Li{sub 2}CoPO{sub 4}F were synthesized by solid-state reaction. Their structures were identified by neutron diffraction. The 5V discharge profiles were demonstrated using coin-type cells. Two important issues for commercial use, metal dissolution and oxygen release at elevated temperatures, were also tested with an atomic absorption spectrophotometer and differential scanning calorimeter, respectively. (author)

2005-08-26

298

British Library Electronic Table of Contents (United Kingdom)

Abstract Flavin-containing reductases are involved in a wide variety of physiological reactions such as photosynthesis, nitric oxide synthesis, and detoxification of foreign compounds, including therapeutic drugs. Ferredoxin-NADP(H)-reductase (FNR) is the prototypical enzyme of this family. The fold of this protein is highly conserved and occurs as one domain of several multidomain enzymes such as the members of the diflavin reductase family. The enzymes of this family have emerged as fusion of a FNR and a flavodoxin. Although the active sites of these enzymes are very similar, different enzymes function in opposite directions, that is, some reduce oxidized nicotinamide adenine dinucleotide phosphate (NADP+) and some oxidize reduced nicotinamide adenine dinucleotide phosphate (NADPH). In t...

2011-01-01

299

Comparison of sodium zirconium phosphate and Synroc matrices for immobilization of high-level waste

A novel structural mechanism for redox regulation of uridine phosphorylase 2 activity

The aims of the present work were to investigate possible compatibility between sodium zirconium phosphate (NZP) and Synroc titanate phases, to prepare NZP-based waste forms by hot-pressing rather than sintering, and to investigate the incorporation in NZP of (a) Cs/Sr as simulated heat-generating nuclides; (b) simulated actinides; and (c) simulated Purex waste. The NZP samples were prepared by methods similar to those used for Synroc. The precursor NZP phase was formed from tetrabutyl zirconate Zr(OC{sub 4}H{sub 9}){sub 4}, sodium nitrate, and 85% orthophosphoric acid. Simulated waste nitrate solutions were then mixed with the liquid precursor. After stir drying of the precursor, calcination was carried out at 700{degree}C to remove nitrates and organics.

1996-12-31

300

British Library Electronic Table of Contents (United Kingdom)

Uridine phosphorylase (UPP) catalyzes the reversible conversion of uridine to uracil and ribose-1-phosphate and plays an important pharmacological role in activating fluoropyrimidine nucleoside chemotherapeutic agents such as 5-fluorouracil and capecitabine. Most vertebrate animals, including humans, possess two homologs of this enzyme (UPP1 & UPP2), of which UPP1 has been more thoroughly studied and is better characterized. Here, we report two crystallographic structures of human UPP2 (hUPP2) in distinctly active and inactive conformations. These structures reveal that a conditional intramolecular disulfide bridge can form within the protein that dislocates a critical phosphate-coordinating arginine residue (R100) away from the active site, disabling the enzyme. In vitro activity measurem...

2011-01-01

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301

Optimizing the specific surface area of fly ash-based sorbents for flue gas desulfurization.

Gastrointestinal absorption of lead (/sup 203/Pb) in chicks: influence of lead, calcium, and age

High performance sorbents for flue gas desulfurization can be synthesized by hydration of coal fly ash, calcium sulfate, and calcium oxide. In general, higher desulfurization activity correlates with higher sorbent surface area. Consequently, a major aim in sorbent synthesis is to maximize the sorbent surface area by optimizing the hydration conditions. This work presents an integrated modeling and optimization approach to sorbent synthesis based on statistical experimental design and two artificial intelligence techniques: neural network and genetic algorithm. In the first step of the approach, the main and interactive effects of three hydration variables on sorbent surface area were evaluated using a full factorial design. The hydration variables of interest to this study were hydration time, amount of coal fly ash, and amount of calcium sulfate and the levels investigated were 4-32 h, 5-15 g, and 0-12 g, respectively. In ...

2005-07-05

302

Contribution of calcium ions and hydrogen ions to the signal transduction chain in phytochrome-mediated spore germination. [Onoclea sensibilis L

The present study was designed to investigate, in more detail, the mechanism of lead transport by the gastrointestinal tract and particularly the similarities or dissimilarities between lead and calcium in this process. The absorption of these metals was determined in 3-week-old white Leghorn cockerels, raised on a commercial diet or special diets, using an in vivo ligated loop procedure. The dose administered into the loop usually contained 0.5 ..mu..Ci /sup 203/Pb (and/or 0.1 ..mu..Ci /sup 47/Ca), 0.01 mM lead acetate (and/or 1 mM CaCl/sub 2/) in 0.5 ml of 0.15 M NaCl, pH 6.5. It was shown that lead is rapidly taken up by the intestinal tissue, and only slowly transferred into the circulation whereas calcium, also accumulated rapidly by the tissue, is rapidly released from the tissue in the serosal direction. The absorption processes of these cations show similar responses to various experimental conditions (low calcium ...

1981-10-01

303

Waste treatment by dialysis. (Latest citations from Pollution abstracts). Published Search

Red light stimulates germination in the spores of Onoclea sensibilis L. Phytochrome is confirmed to be the photoreceptor pigment in the germination response by demonstrating red-far-red photoreversibility. External Ca/sup 2 +/ is required for this response with a threshold at a submicromolar concentration. Red light stimulates an increase in the total concentration of intracellular calcium in the spores as determined by atomic absorption spectroscopy. Subsequent exposure to far-red light inhibits the red light-induced increase in intracellular calcium. The majority of the increase occurs 5 minutes after the onset of irradiation. The calcium-antagonist, La/sup 3 +/ inhibits both germination and the red light-induced increase in intracellular calcium. Using /sup 31/P-nuclear magnetic resonance spectroscopy, the author tested the hypothesis that a sustained increase in intracellular pH contributes to the ...

1985-01-01

304

Three Homologous Genes Encoding sn-Glycerol-3-Phosphate Acyltransferase 4 Exhibit Different Expression Patterns and Functional Divergence in Brassica napus¹^[C]^[W]^[OA]

The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

1996-02-01

305

The direct interaction between ASH2, a Drosophila trithorax group protein, and SKTL, a nuclear phosphatidylinositol 4-phosphate 5-kinase, implies a role for phosphatidylinositol 4,5-bisphosphate in maintaining transcriptionally active chromatin.

Brassica napus is an allotetraploid (AACC) formed from the fusion of two diploid progenitors, Brassica rapa (AA) and Brassica oleracea...Full Text Available

2011-02-01

306

Sustainable phosphorous fertilisation of potatoes (Potato CHIPS)

The products of trithorax group (trxG) genes maintain active transcription of many important developmental regulatory genes, including homeotic genes. Several trxG proteins have been shown to act in...Full Text Available

2004-07-01

307

Superoxide production by NAD(P)H oxidase and mitochondria is increased in genetically obese and hyperglycemic rat heart and aorta before the development of cardiac dysfunction. The role of glucose-6-phosphate dehydrogenase-derived NADPH

DescriptionThis project has two independent aims: (1) to investigate the use of struvite as an alternative to chemical P fertilisers and (2) to develop an oligonucleotide microarray to monitor the P status of the potato crop. The UK horticultural and agricultural industries rely on large inputs of phosphate (P) fertilisers to maintain crop yields and quality. However, the use of non-renewable, chemical P fertilisers is unsustainable, and the alternatives to chemical P-fertilisers must be identified as an [continued...

2008-01-31

308

Safe venting of ``red oil`` runaway reactions

Increased oxidative stress is a known cause of cardiac dysfunction in animals and patients with diabetes, but the sources of reactive oxygen species [e.g., superoxide anion (O₂⁻)]...Full Text Available

2009-07-01

309

Phosphorus-containing catalyst and catalytic cracking process utilizing the same

Calorimetry testing of Tri-n-butyl phosphate (TBP) saturated with strong nitric acid was performed to determine the relationship between vent size and pressure buildup in the event of a runaway reaction. These experiments show that runaway can occur in an open system, but that even when runaway is induced in the TBP/HN0{sub 3} system, dangerous pressure buildup will be prevented with practical vent size.

1994-12-21

310

Phosphorus-containing catalyst and catalytic cracking process utilizing the same

A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with a dihydrogen phosphate anion or a dihydrogen phosphite anion. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.

1985-02-12

311

Nucleotide sequence and genetic analysis of a 13.1-kilobase-pair Pseudomonas denitrificans DNA fragment containing five cob genes and identification of structural genes encoding Cob(I)alamin adenosyltransferase, cobyric acid synthase, and bifunctional cobinamide kinase-cobinamide phosphate guanylyltransferase.

A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with an anion such as a dihydrogen phosphate anion or a dihydrogen phosphite anion and additionally with an ammonium salt other than a salt of an inorganic acid of phosphorus. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.

1985-03-12

312

Method of purifying uranium tetrafluoride hydrate and preparing uranium (VI) peroxide hydrate using a fluoride complexing agent

A 13.1-kb DNA fragment carrying Pseudomonas denitrificans cob genes has been sequenced. The nucleotide sequence and genetic analysis revealed that this fragment contained five different cob genes named...Full Text Available

1991-10-01

313

Hydrothermal synthesis of tobermorite/hydroxyapatite composites

The annual production of phosphate rock, on the order of about 30-40 million tons yearly, represents several million pounds of uranium. The present invention provides a process of purifying uranium tetrafluoride hydrate to produce a uranium (VI) peroxide product meeting 'yellow cake' standards using a double precipitation procedure. A fluoride complexing agent is used in the precipitation.

1978-06-27

314

British Library Electronic Table of Contents (United Kingdom)

A tobermorite/hydroxyapatite composite was prepared by hydrothermal treatment using diatomaceous earth, ?-tricalcium phosphate and slaked lime starting materials. The XRD patterns of the composite confirmed that tobermorite and hydroxyapatite were formed after the hydrothermal process. The bending strength of the composite reached a level higher than 9?MPa after the hydrothermal process. The development of the bending strength was due to the formation of tobermorite and hydroxyapatite during the hydrothermal process. The composite had a high specific surface area due to these newly formed crystals.

2008-01-01

315

Evolution of a bifunctional enzyme: 6-phosphofructo-2-kinase/fructose-2,6-bisphosphatase.

Essential Role for Cellular Phosphoglucomutase in Virulence of Type 3 Streptococcus pneumoniae

The bifunctional rat liver enzyme 6-phosphofructo-2-kinase/fructose-2,6-bisphosphatase (ATP:D-fructose-6-phosphate 2-phosphotransferase/D-fructose-2,6-bisphosphate 2-phosphohydrolase, EC 2.7.1.105/EC...Full Text Available

1989-12-01

316

Elucidating novel pathways and regulation of nitrogen assimilation in alpha proteobacteria exemplified by the soil organism Paracoccus denitrificans

Synthesis of the Streptococcus pneumoniae type 3 capsule requires the pathway glucose-6-phosphate (Glc-6-P) → Glc-1-P → UDP-Glc → UDP-glucuronic acid (UDP-GlcUA)...Full Text Available

2001-04-01

317

Electrophilic addition of astatine

DescriptionThe importance of inorganic nitrate for the nutrition and growth of marine and freshwater autotrophic phytoplankton has long been recognised, in particularly because of the 'blooms' formed in nitrate and phosphate polluted water and their possible roles as carbon dioxide sinks. By contrast, the utilisation of nitrate by heterotrophic bacteria has historically received less attention. Up until now, the primary role of heterotrophic bacteria has classically been considered to be the decomposition [continued...

2010-01-31

318

EFFECTS OF PH AND PHOSPHATE ON METAL DISTRIBUTION WITH EMPHASIS ON AS SPECIATION AND MOBILIZATION IN SOILS FROM A LEAD SMELTING SITE

It has been shown for the first time that astatine is capable of undergoing addition reactions to unsaturated hydrocarbons. A new compound of astatine, viz., ethylene astatohydrin, has been obtained, and its retention numbers of squalane, Apiezon, and tricresyl phosphate have been found. The influence of various factors on the formation of ethylene astatohydrin has been studied. It has been concluded on the basis of the results obtained that the univalent cations of astatine in an acidic medium is protonated hypoastatous acid.

319

Adenine and guanine recognition of stop codon is mediated by different N domain conformations of translation termination factor eRF1

Arsenic in soils from the Asarco Lead Smelter in East Helena, Montana was characterized by X-ray absorption spectroscopy (XAS). As oxidation state and geochemical speciation were analyzed as a function of depth (two sampling sites) and surface distribution. These results were c...

320

The seeded growth of calcium sulfate dihydrate crystals in NaCl solutions up to 6 m and 90 C

Positioning of release factor eRF1 toward adenines and the ribose-phosphate backbone of the UAAA stop signal in the ribosomal decoding site was studied using messenger RNA (mRNA) analogs containing...Full Text Available

2011-09-01

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321

Role of HCl in adsorption of elemental mercury vapor by calcium-based sorbents. Report for September 1998--May 1999

The kinetics of calcium sulfate crystal growth is of importance in various fields, such as geochemistry, desalination technology, petroleum industry, and water and wastewater treatment. The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in NaCl electrolyte solutions from 0 to 6 m at temperatures of 25, 50, 70, and 90 C. The growth followed a second-order parabolic rate law with activation energies greater than 53 kJ/mol which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with NaCl concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from 61 kJ/mol in the pure Ca-SO[sub 4]H[sub 2]O system to 53 kJ/mol in 3.0 m NaCl solutions. The electrolyte effect was similar to the crystal solubility behavior in aqueous ...

1994-03-15

322

Role of HCl in adsorption of elemental mercury vapor by calcium-based sorbents. Report for September 1998--May 1999

The paper gives results of a study to identify active sites and surface functional groups that may contribute to the absorption of elemental mercury (Hg) by relatively inexpensive calcium (Ca)-based sorbents. The study investigated the formation of chlorine (Cl) sites in CA-based sorbents as well as their role and reactivity in the absorption of Hg. HCl-exposed calcium sulfate dihydrate (gypsum) exhibited a superior Hg sorption capability. Crystalline water molecules on the surface of the gypsum were confirmed to contribute indirectly to Hg uptake. These surface molecules may have absorbed HC1 through hydrogen bond formation between an oxygen atom of a crystalline water molecule and a hydrogen atom of an HCl molecule. Two adjacent, physically absorbed HCl molecules could then trap an Hg molecule through formation of a mercuric-chloride-like molecule. Significant correlations between Cl and Hg uptake by gypsum were noted.

1999-11-01

323

Inhibition of calmodulin - regulated calcium pump activity in rat brain by toxaphene

The paper gives results of a study to identify active sites and surface functional groups that may contribute to the absorption of elemental mercury (Hg) by relatively inexpensive calcium (Ca)-based sorbents. The study investigated the formation of chlorine (Cl) sites in CA-based sorbents as well as their role and reactivity in the absorption of Hg. HCl-exposed calcium sulfate dihydrate (gypsum) exhibited a superior Hg sorption capability. Crystalline water molecules on the surface of the gypsum were confirmed to contribute indirectly to Hg uptake. These surface molecules may have absorbed HC1 through hydrogen bond formation between an oxygen atom of a crystalline water molecule and a hydrogen atom of an HCl molecule. Two adjacent, physically absorbed HCl molecules could then trap an Hg molecule through formation of a mercuric-chloride-like molecule. Significant correlations between Cl and Hg uptake by gypsum were noted.

1999-01-01

324

Inhibition of calmodulin - regulated calcium pump activity in rat brain by toxaphene

In vivo effects of toxaphene on calcium pump activity in rat brain synaptosomes was studied. Male Sprague-Dawley rats were dosed with toxaphene at 0,25,50, and 100 mg/kg/day for 3 days and sacrificed 24 h after last dose. Ca/sup 2 +/-ATPase activity and /sup 45/Ca uptake were determined in brain P/sub 2/ fraction. Toxaphene inhibited both Ca/sup 2 +/-ATPase activity and /sup 45/Ca/sup 2 +/ uptake and the inhibition was dose dependent. Both substrate and Ca/sup 2 +/ activation kinetics of Ca/sup 2 +/-ATPase indicated non-competitive type of inhibition as evidenced by decreased catalytic velocity but not enzyme-substrate affinity. The inhibited Ca/sup 2 +/-ATPase activity and Ca/sup 2 +/ uptake were restored to normal level by exogenously added calmodulin which increased both velocity and affinity. The inhibition of Ca/sup 2 +/-ATPase activity and Ca/sup 2 +/ uptake and restoration by calmodulin suggests that toxaphene may impair active calcium ...

1986-03-05

325

Crystallization fouling of calcium sulfate dihydrate on heat-transfer surfaces

In vivo effects of toxaphene on calcium pump activity in rat brain synaptosomes was studied. Male Sprague-Dawley rats were dosed with toxaphene at 0,25,50, and 100 mg/kg/day for 3 days and sacrificed 24 h after last dose. Ca"2"+-ATPase activity and "4"5Ca uptake were determined in brain P_2 fraction. Toxaphene inhibited both Ca"2"+-ATPase activity and "4"5Ca"2"+ uptake and the inhibition was dose dependent. Both substrate and Ca"2"+ activation kinetics of Ca"2"+-ATPase indicated non-competitive type of inhibition as evidenced by decreased catalytic velocity but not enzyme-substrate affinity. The inhibited Ca"2"+-ATPase activity and Ca"2"+ uptake were restored to normal level by exogenously added calmodulin which increased both velocity and affinity. The inhibition of Ca"2"+-ATPase activity and Ca"2"+ uptake and restoration by calmodulin suggests that toxaphene may impair active calcium transport mechanisms by decreasing regulator protein ...

1986-04-13

326

Clear liquor scrubbing with anhydrite production. Fourth quarter 1996 technical progress report

The present paper deals with the fouling process of calcium sulfate dehydrate on heat-transfer surfaces. The crystallization of calcium sulfate showed typical asymptotic fouling curves, the asymptotic value of which was greatly influenced by the surface temperature and fluid velocity. The fouling mechanism was discussed with a generalized fouling model and proved to be surface process controlled, where the activation energy was 6.2 {times} 10{sup 4} J/mol. The availability of mechanical cleaning against the formed scale was quantitatively evaluated by applying the particle abrasion method. The removal test verified that the removing rate per unit particle concentration decreased in an inverse proportion to the overall particle load, to the power of 0.8, and that it was affected by the fluid velocity. The observed final residual fouling resistance decreased asymptotically with an increase in particle concentration. The suitable concentration of ...

1996-02-01

327

Calcium sulfate crystallization along citrus root channels in a Florida soil exhibiting acid sulfate properties

This project is part of PETC`s Advanced Power Systems Program, whose mission is to accelerate the commercialization of affordable, high- efficiency, low emission, coal-fueled electric generating technologies. A process concept - Clear Liquor Scrubbing with Anhydrite Production - was proposed and accepted by PETC as a Phase I project in its Mega-PRDA program. the project integrated three process operations - chloride control upstream of the flue gas desulfurization (FGD) system, a clear liquor process for enhanced SO{sub 2} removal performance, and production of anhydrite (anhydrous calcium sulfate) rather than calcium sulfite or gypsum (calcium sulfate dihydrate). The first step in the project was to perform batch and flow-through experiments in the laboratory to confirm theoretical calculations and preliminary laboratory results concerning anhydrite formation, these laboratory experiments were designed to prove that ...

1997-02-03

328

An indicator, high speed method for determining the water and aqueous phase content in a hydrocarbon fuel

The authors observed euhedral crystals in Manatee soil in a citrus grove in St. Lucie County, Florida. The material was identified as gypsum (CaSO/sub 4/ /times/ 2H/sub 2/O) using x-ray diffraction and infrared spectra. Photomicrography and scanning electron microscopy revealed that gypsum accumulated both in old root channels and within citrus root tissue of the Btg horizon. The subsurface horizons had elevated sulfate levels, a low initial pH, a drop (0.5 unit) in pH upon air-drying. Electrical conductivity paralleled the concentration of water-soluble sulfate. High levels of calcium and sulfate occurred for horizons above the water table. This accumulation is attributed to groundwater bearing these ions and subsequently discharging them to the overlying soil. Dead citrus roots appear to act as wicks to aid water transfer from lower to higher horizons. The roots and their empty channels provide spaces in which the gypsum can precipitate if the concentrations of ...

1988-02-01

329

Alternative calcium-sulfate-bearing materials as cement retarders: Part II. FGD gypsum

A method and an instrument for determining the total water content in a hydrocarbon fuel using an indicator composition, which includes calcium hydride and phenolphthaleyn, are developed. The essence of the method is fixing the presence of water with its interaction with the calcium hydride and subsequent indication of the formed Ca(OH)2 using the phenolphthallen. To make the indicator composition, a hygroscopic cotton, prewashed by rectified alcohol and dried for 30 minutes at 105 degrees, is impregnated by a 1 percent alcohol solution of phenolphthaleyn and is dried in the same conditions. Then the cotton is processed by a powder form calcium hydride (a layer thickness of 0.1 to 0.2 millimeters, and a granule size of less than or equal to 80 micromters). The indicator composition is placed in a glass tube (a diameter of 4 to 7 millimeters and a length of 80 to 100 millimeters), whose ends are sealed or filled with ...

1983-01-01

330

Activation of fat cell adenylate cyclase by protein kinase C

The aim of this paper is to investigate the possible displacement of natural gypsum (CaSO{sub 4}2H{sub 2}O) in cement with an alternative setting retarder, such as the industrial by-product derived from flue gas desulfurization process called FGD gypsum. These calcium-sulfate-bearing materials (CSBM), alone or in mixtures, were ground with clinker both in laboratory and industrial scale to examine their influence on the physical and mechanical properties of cement, as well as on the industrial production line of cement. From the present work, it is extracted that the use of mixtures of sulfate-bearing materials with gypsum seems to be advantageous for the actual control of setting time. The addition of FGD gypsum increases setting time without affecting compressive strength profile. During the industrial trial, the formation of hemihydrate form of calcium sulfate dihydrate has a profound regulatory effect on the setting and strength performance ...

2004-11-01

331

Uranium and thorium based phosphate matrix: synthesis, characterizations and lixiviation; Matrices a base de phosphate d'uranium et de thorium: syntheses, caracterisations et lixiviation

Purified protein kinase C (C-kinase) from guinea pig pancreas and rat brain stimulated adenylate cyclase activity in purified rat adipocyte membranes. Cyclase stimulation occurred over 100 to 1000 mU/ml of C-kinase activity, required greater than 10 ..mu..M calcium, proceeded without a lag, was not readily reversible, and required no exogenous phospholipid. Moreover, C-kinase inhibitors, such as chlorpromazine and palmitoyl carnitine, inhibited selectively adenylate cyclase which was activated by C-kinase and calcium. Depending on assay conditions, 10 nM 12-0-tetradecanoylphorbol-13-acetate (TPA) either enhanced or was required for kinase action on cyclase. Also, TPA plus calcium promoted the quantitative association of C-kinase with membranes. Adenylate cyclase activation by C-kinase was seen both in the presence and absence of exogenous GTP, indicating that the kinase effect does not result from an action on the ...

1986-05-01

332

The Schenberg spherical antenna: status report

In the framework of the search for a ceramic material usable in the radioactive waste storage, uranium and thorium phosphates have been investigated. Their experimental synthesis conditions have been entirely reviewed, they lead to the preparation of four new compounds: U(UO{sub 2})(PO{sub 4}){sub 2}, U{sub 2}O(PO{sub 4}){sub 2}, UCIPO{sub 4}, 4H{sub 2}O, and Th{sub 4}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}. Experimental evidenced are advanced for non existent compounds such as: U{sub 3}(PO{sub 4}){sub 4}, U{sub 2}O{sub 3}P{sub 2}O{sub 7} and Th{sub 3} (PO{sub 4}){sub 4}. Characterization by several techniques (X-rays and neutron powder diffractions, UV-Visible and Infra-red spectroscopies, XPS,...) were performed. The ab initio structure determination of U(UO{sub 2})(PO{sub 4}){sub 2} has been achieved by X-rays and refined by neutron diffractions. Through its physico-chemical analysis, we found that this compound was a new mixed valence uranium ...

1995-03-01

333

The Brazilian spherical detector: progress and plans

Full text. Here we present a status report of the Schenberg antenna, which started commissioning runs in September 2006 under the full support of FAPESP. In its first commissioning runs we tested three preliminary parametric transducer systems, which did not achieve a high enough performance for placing the antenna sensitivity in the range of the calibrator capacitor. Instead of improving the calibrator, making it capable of introducing a larger input force, we decided to go to a radical upgrading operation: replacing the three transducers for a complete set of six transducers, with better sensitivity and arranged according to the truncated icosahedron configuration, plus two extra ones; starting to install the dilution refrigerator; installing wires, cables, and amplifiers for the complete set of transducer circuits; and a new suspension and vibration isolation system for the cabling and microstrip antennas. We also have been developing a new set of transducers, microwave oscillators, ...

2009-09-14

334

Structure of molten alkali halides

We are building the Schenberg gravitational wave detector at the Physics Institute of University of Sao Paulo as programmed by the Brazilian Graviton Project. The antenna and its vibration isolation system are already built, and we have made a first cryogenic run for an overall test, in which we measured the antenna mechanical Q (figure of merit). We also have built a 10.21 GHz oscillator with phase noise performance better than -120 dBc at 3.2 kHz to pump an initial CuAl6% two-mode transducer. We plan to prepare this spherical antenna for a first operational run at 4.2 K with a single transducer and an initial target sensitivity of h #approx# 2 x 10"-"2"1 Hz"-"1"/"2 in a 50 Hz bandwidth around 3.2 kHz soon. Here we present details of this plan and some recent results of the development of this project.

2004-03-07

335

Structure of molten alkali halides

The results of X-ray and neutron diffraction experiments on molten alkali halides in which some data of our experiments by X-ray diffraction such as those of molten LiCl, NaCl, KCl, LiBr and KBr are included were summarized. The first peak positions in the radial distribution function in molten alkali halides by X-ray or neutron diffraction experiments are always longer than those by computer simulations and the differences of 0.1 -- 0.3 A exceed the experimental error. It seems to be due to the deformation of the electron shell. In the computer simulation, the shell model which has the spherical deformation was expected to have a closer value of the first peak position to the experimental one than the rigid ion model by taking the polarization of ions. However, no change in the first peak position was found. Therefore, the non-spherical deformation of electron shell at the point where ions are in contact with each other has to be taken into ...

1982-06-01

336

Spherical nanostructured Si/C composite prepared by spray drying technique for lithium ion batteries anode

The results of X-ray and neutron diffraction experiments on molten alkali halides in which some data of our experiments by X-ray diffraction such as those of molten LiCl, NaCl, KCl, LiBr and KBr are included were summarized. The first peak positions in the radial distribution function in molten alkali halides by X-ray or neutron diffraction experiments are always longer than those by computer simulations and the differences of 0.1 -- 0.3 A exceed the experimental error. It seems to be due to the deformation of the electron shell. In the computer simulation, the shell model which has the spherical deformation was expected to have more closer value of the first peak position to the experimental one than the rigid ion model by taking the polarization of ions. However, no change in the first peak position was found. Therefore, the non-spherical deformation of electron shell at the point where ions are in contact with each other has to be taken into ...

1982-01-01

337

Solution of unidimensional problems from monoenergetics neutrons diffusion through finite differences

Spherical nanostructured Si/C composite was prepared by spray drying technique, followed by heat treatment, in which nanosized silicon and fine graphite particles were homogeneously embedded in carbon matrix pyrolyzed by phenol formaldehyde resin. Cyclic voltammetry tests showed two pairs of redox peaks corresponding to lithiation and delithiation of Si/C composite. The Si/C composite exhibited a reversible capacity of 635 mAh g"-"1 and good cycle performance used in lithium ion batteries. To improve cycle performance of this Si/C composite further, the carbon-coated Si/C composite was synthesized by the second spray drying and heat treatment processing. The cycle performance of carbon-coated Si/C composite was improved significantly, which was attributed to the formation of stable SEI passivation layers on the outer surface of carbon shell which protected the bared silicon from exposing to electrolyte directly.

2006-07-15

338

Microstructural aspects of the corrosion of Alloy 800

A calculation program (URA 6.F4) was elaborated on FORTRAN IV language, that through finite differences solves the unidimensional scalar Helmholtz equation, assuming only one energy group, in spherical cylindrical or plane geometry. The purpose is the determination of the flow distribution in a reactor of spherical cylindrical or plane geometry and the critical dimensions. Feeding as entrance datas to the program the geometry, diffusion coefficients and macroscopic transversals cross sections of absorption and fission for each region. The differential diffusion equation is converted with its boundary conditions, to one system of homogeneous algebraic linear equations using the box integration technique. The investigation on criticality is converted then in a succession of eigenvalue problems for the critical eigenvalue. In general, only is necessary to solve the first eigenvalue and its corresponding eigenvector, employing the power method. The ...

1993-11-18

339

Jacobi stability of the vacuum in the static spherically symmetric brane world models

Transmission electron microscopy studies on solution-annealed Alloy 800 revealed small (100-200 nm), spherical-shaped titanium carbide (face centered cubic structure) and large (200 nm-5 {mu}m), faceted titanium nitride (hexagonal structure) particles randomly distributed in the austenite matrix. The volume fraction of former particles was found to be greater than that of the latter. Corrosion studies of the alloy in acidic, chlorides and acidic chloride environments at room temperature indicated that the passivity of Alloy 800 was adversely affected by the addition Cl{sup -} ions. X-ray photoelectron spectroscopy revealed that the surface film formed on the alloy at the onset of passivity consisted of Cr{sup 3+} (as Cr{sub 2}O{sub 3}), without any Fe{sup 3+}/Fe{sup 2+} or Ni{sup 2+}. Scanning electron microscopy studies indicated initiation of pitting at large, faceted particles, not at small, spherical-shaped ones.

2004-12-01

340

Fuel/propellant mixing in an open-cycle gas core nuclear rocket engine

We analyze the stability of the structure equations of the vacuum in the brane world models, by using both the linear (Lyapunov) stability analysis, and the Jacobi stability analysis, the Kosambi-Cartan-Chern theory. In the brane world models the four-dimensional effective Einstein equations acquire extra terms, called dark radiation and dark pressure, respectively, which arise from the embedding of the three-brane in the bulk. Generally, the spherically symmetric vacuum solutions of the brane gravitational field equations have properties quite distinct as compared to the standard black hole solutions of general relativity. We close the structure equations by assuming a simple linear equation of state for the dark pressure. In this case the vacuum is Jacobi stable only for a small range of values of the proportionality constant relating the dark pressure and the dark radiation. The unstable trajectories on the brane behave chaotically, in the sense that after a ...

2008-05-15

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341

Electrical breakdown at low pressure in the presence of a weak magnetic field

A numerical investigation of the mixing of gaseous uranium and hydrogen inside an open-cycle gas core nuclear rocket engine (spherical geometry) is presented. The gaseous uranium fuel is injected near the centerline of the spherical engine cavity at a constant mass flow rate, and the hydrogen propellant is injected around the periphery of the engine at a five degree angle to the wall, at a constant mass flow rate. The main objective is to seek ways to minimize the mixing of uranium and hydrogen by choosing a suitable injector geometry for the mixing of light and heavy gas streams. Three different uranium inlet areas are presented, and also three different turbulent models (k-var-epsilon model, RNG k-var-epsilon model, and RSM model) are investigated. The commercial CFD code, FLUENT, is used to model the flow field. Uranium mole fraction, axial mass flux, and radial mass flux contours are obtained. copyright 1997 American Institute of Physics.

1997-01-01

342

Determination of size distribution of Guinier-Preston zones in Al-Ag alloys by small-angle x-ray scattering method

Electron trapping in crossed electric and magnetic fields is an important mechanism by which electrical discharges can develop in low pressure gases. The authors report observations of discharges produced by this mechanism around a spherical anode in two space simulation chambers, namely the Space Plasma Interaction Experiment (SPIE) at the University of Maryland, and the NASA-Lewis B-2 chamber. They have identified two types of discharges in these experiments. In the B-2 chamber, the breakdown takes the form of a runaway dischage with spherical topology, limited only by the ability of the power supply to provide the current. In the SPIE chamber this type of discharge also occurs, in addition to a low current toroidal discharge which is observed at higher magnetic fields. They present measurements of both types of discharge and show how the trapping effect of the magnetic field together with secondary electron emission by high energy ion ...

1990-05-01

343

Customized computer models of eyes with intraocular lenses

Small-angle X-ray scattering method recognised to be very useful in the studies of structural problems of materials in homogeneous in nanoscale. Studies by small-angle X-ray scattering on the Al-Ag alloys are presented. The size distributions of spherical Guinier-Person zones were calculated using Vonk's and Glatter's methods. Small-angle X-ray scattering studies were performed on Al-5.0 at.%Ag alloy containing Guinier-Preson zones in the #eta#-state. For this alloy one can assume that scattering particles are of spherical shape, have uniform electron density and scatter independently. Moreover, the size distributions were calculated for Al-1.6 at.%Ag alloy containing Guinier-Preston zones in #epsilon#-state (scattering particles with not uniform electron density). Both, Vonk's and Glatter's, methods gave similar size distributions. Profiles of size distributions for Guinier-Preston zones in #epsilon#-state are more complex in comparison to ...

2001-09-23

344

Compressed-shell integrity measurements in spherical implosion experiments

We compared experimental wave aberrations in pseudophakic eyes with aspheric intraocular lenses (IOLs) to simulate aberrations from numerical ray tracing on customized computer eye models using corneal topography, angle ?, ocular biometry, IOL geometry, and IOL tilt and decentration measured on the same eyes. We found high correlations between real and simulated aberrations even for the eye with only the cornea, and these increased on average when the IOL geometry and position were included. Relevant individual aberrations were well predicted by the complete eye model. Corneal spherical aberration and horizontal coma were compensated by the IOL, and in 58.3% of the cases IOL tilt and decentration contributed to compensation of horizontal coma. We conclude that customized computer eye models are a good representation of real eyes with IOLs and allow understanding of the relative contribution of optical, geometrical and surgically-related factors to image quality. ...

2007-03-01

345

BIMA Array Observations of the Highly Unusual SiO Maser Source with a Bipolar Nebulosity, IRAS 19312+1950

The shell integrity near peak compression of spherical implosions using the 60-beam, 30-kJ UV OMEGA laser system [Opt. Commun. 133, 495 (1997)] has been measured. Hot core emission backlights a shell with a thin titanium-doped layer that is imaged at x-ray photon energies above and below the titanium K edge. The x-ray intensity ratio between the two images is related to perturbations in the cold, or absorbing, part of the shell. The measured cold-shell areal-density modulations, integrated over the time of peak compression, are of the order of 25% to 50% with nonuniformity spectra peaked at spatial wavelengths of 30 to 50 #mu#m and with the smallest detectable nonuniformity features extending down to spatial wavelengths of 12 to 15 #mu#m. Hot-shell areal-density modulations of the emitting part of the shell (inner edge) are of the order of 13% to 20%. The measured shell modulations are in agreement with the results of two-dimensional simulations that include ...

2001-06-01

346

Technical-economic aspects of the utilization of geothermal waters

We report the results of mapping observations of the bipolar nebula with SiO maser emission, IRAS 19312+1950, in the CO (J=1-0 and J=2-1), 13CO (J=1-0 and J=2-1), C18O (J=1-0), CS (J=2-1), SO (J_K=3_2-2_1) and HCO+ (J=3-2) lines with the Berkeley-Illinois-Maryland Association array. Evolutional status of this source has been evoking a controversy since its discovery, though SiO maser sources are usually identified as late-type stars with active mass loss. In line profiles, two kinematical components are found as reported in previous single-dish observations: a broad pedestal component and a narrow component. Spatio-kinetic properties of a broad component region traced by 12CO lines are roughly explained by a simple spherical outflow model with a typical expanding velocity of an AGB star, though some properties of the broad component region still conflict with properties of a typical AGB spherical outflow. A narrow component region apparently ...

2005-01-01

347

Studies on the chemical composition and possible mechanisms underlying the antispasmodic and bronchodilatory activities of the essential oil of Artemisia maritima L.

A brief description is given of the physico-chemical parameters characterized a hot water geothermal reservoir and of its exploitation by means of single or coupled (doublet) wells. The technical aspects of geothermal heat to the users is then discussed, beginning with corrosion of materials caused by seven main agents: oxygen, hydrogen sulphide, carbon dioxide, ammonia, hydrogen, sulphates and chlorides. A brief mention is made of scaling due to calcium carbonate, silica and calcium sulphates. The basic components of a geothermal plant for non-electric uses are then discussed: production pumps, surface pipelines, heat exchangers, heat pumps and reinjection pumps. The advantages and disadvantages of the different equipment and materials used in the geothermal sector are also presented. A list is also given of the criteria used in the energy and economic balance of a geothermal operation. (author). 24 refs, 13 figs, 2 tabs.

348

British Library Electronic Table of Contents (United Kingdom)

This study describes the chemical composition of the essential oil of Artemisia maritima (Am.Oil) and the pharmacological basis for its medicinal use in gut and airways disorders. Twenty five compounds, composing 93.7% of the oil, were identified; among these, chrysanthenyl propionate and elixene were identified for the first time from any Artemisia species. The Am.Oil (0.3?1.0 mg/mL) suppressed spontaneous and high K+ (80 mM)-induced contractions in isolated rabbit jejunum, suggestive of an antispasmodic effect mediated possibly through calcium channel blockade. The calcium channel blockade activity was confirmed when pre-treatment of the tissue with Am.Oil (0.01?0.03 mg/mL) shifted the Ca++ concentration-response curves to the right, similar to verapamil and papaverine. In isolated trach...

2011-01-01

349

Sterilization of male stray dogs with a single intratesticular injection of calcium chloride: a dose-dependent study

British Library Electronic Table of Contents (United Kingdom)

ObjectiveTo study a method of chemical sterilization and its efficacy in adult male stray dogs.MethodsSterilization was performed 45 days after a single bilateral intratesticular injection of calcium chloride (CaCl2) at the doses of 5, 10, 15 or 20 mg per testis per kg body weight.ResultsHistomorphological measures of testes showed total necrosis of testicular tissue at 45 days after an injection of either 10 or 15 or 20 mg CaCl2 along with fibrosis and hyalinization in seminiferous tubules and interstitial spaces. Infiltration of leucocytes was also observed with the 10- or 15-mg dose. Disintegration of germ cell arrangement in seminiferous tubules and washing out of germ cells from the tubules were noted with the 5-mg dose. Relative organ weight, epididymal sperm count, plasma and intrat...

2007-01-01

350

Scale prevention with special reference to threshold treatment

Various chemical, physical, and mechanical methods to prevent unwanted deposition of mineral scale are described. The suitability of the different methods, which largely depends on the specific features and requirements of the system involved, is discussed. Special emphasis is placed upon the threshold treatment, where the growth process is retarded by the addition of trace amounts of growth inhibitors. Growth experiments have been performed on barium sulfate and calcium sulfate dihydrate seed crystals, suspended in a supersaturated solution with and without organic bisphosphonates as inhibitors. Two methods are selected for the analysis of the growth data. A degree of inhibition is defined to obtain a quantitative description of the influence of a growth inhibitor on the growth rate of the crystals. In addition the influence of the molecular structure of various bisphosphonates with different substituents is shown. The effect of a bisphosphonate on the geometry of ...

1983-01-01

351

NEW SLAG-BASED CONCRETES

Jump in the air gasification rate of potassium-doped cellulosic chars

ObjectivesTo determine the reaction rate of slag during curing and factors affecting reactivity.~%~~%~To measure the rates of chloride ingress into concrete and the extent of chloride binding.~%~~%~To determine conditions for pitting corrosion and the nature of corrosion products.~%~~%~To characterise the reactions in slag-calcium alumina cement hydration and the nature of the products.~%~DescriptionBlast-furnace slag has latent hydraulic properties, giving considerable potential for commercial use in addition to its widespread use as a partial replacement for Portland cement, notably in alkali-activated slag (AAS) and slag-calcium alumina cement (CAC) concretes. Use of AAS concretes is already well-established in China and the former USSR, but their further application is hindered by lack of research into setting, hydration and durability, Slag/CAC blends are new materials whose chemistr ...

1999-01-09

352

Intermediate-conductance calcium-activated potassium channels participate in neurovascular coupling

Chars prepared from potassium-exchanged carboxy methyl cellulose at several heat treatment temperatures (HTTs) were gasified in air isothermally at selected gasification temperatures (GTs) in the range 633-893 K to investigate the catalytic effectiveness of potassium species. The chars displayed a noticeable jump in gasification rate at a particular gasification temperature (called jump temperature, T{sub j}). The magnitude of jump was much less than that reported for copper and nickel catalysis, but comparable with that for calcium catalysis. Increase in HTT caused a decrease in the jump temperature of chars in contrast with the increase observed in copper, nickel and calcium catalysis; also the magnitude of jump did not decrease, but remained unaltered, on increasing HTT. The different behavior of potassium catalysis is correlated to a change in the chemical state of potassium at higher HTT. The results reveal the dependence of jump ...

2010-12-15

353

British Library Electronic Table of Contents (United Kingdom)

BACKGROUND AND PURPOSE Controlling vascular tone involves K+ efflux through endothelial cell small- and intermediate-conductance calcium-activated potassium channels (KCa2.3 and KCa3.1, respectively). We investigated the expression of these channels in astrocytes and the possibility that, by a similar mechanism, they might contribute to neurovascular coupling. EXPERIMENTAL APPROACH Transgenic mice expressing enhanced green fluorescent protein (eGFP) in astrocytes were used to assess KCa2.3 and KCa3.1 expression by immunohistochemistry and RT-PCR. KCa currents in eGFP-positive astrocytes were determined in situ using whole-cell patch clamp electrophysiology. The contribution of KCa3.1 to neurovascular coupling was investigated in pharmacological experiments using electrical field stimulatio...

2011-01-01

354

Interaction studies between Crofer-22APU alloy and P2O5 containing barium calcium alumino-borosilicate (BCABS) sealant glass-ceramics

Determination of some minor and trace elements in iron ores by ion exchange chromatography, spectrophotometry and atomic absorption spectrometry

We present the effect of P2O5 addition on barium calcium aluminum borosilicate BCABS glasses of composition (mol %) 35BaO-15CaO-5Al2O3-(37-x)SiO2-8B2O3-xP2O5 (0?x?5). The incorporation of P2O5 increased network polymerization and crystallization tendency. However, addition of P2O5 leads to the formation of Cr2O3 at the interface, saturating it in the ions of the metal. This improves glass-to-metal bonding. (author)

2010-09-01

355

Acid-site distribution on Faujasite-type zeolites determined by n-butylamine titration--1. Comparison of the use of hammett and arylmethanol indicators on zeolites X

A method is described for determination of aluminium, cadmium, cobalt, chromium, copper, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, zinc, titanium and vanadium in iron ore. After dissolution, a 1 gram sample of iron ore is applied to a column of AGI-X8 anion exchange resin (chloride form), in 100 ml of 7M HCl. Aluminium, chromium, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, titanium and vanadium are eluted with 7M HCl; iron, copper and cobalt are eluted with 0.5M HCl; cadmium and zinc are eluted with 2M HNO_3. Iron is subsequently removed from copper and cobalt by a solvent extraction with methyl isobutyl ketone. The elements are determined in the eluates by atomic absorption spectrometry, except for titanium and vanadium, which are determined spectrophotometrically.

356

A prospective randomised open label study to evaluate the potential of a new silver alginate/carboxymethylcellulose antimicrobial wound dressing to promote wound healing

The combined Lewis and Broensted acidities were measured of 13X (sodium) zeolite and of its 84.2% calcium-exchanged, 86.0% lanthanum-exchanged, and 69.2% protonated forms, calcined at 400/sup 0/C. The butylamine titrations were performed to visible color changes of Hammett indicators. The H/sub 0/ acidities were 0 for the sodium X zeolite, and 0.2, 0.98, and 0.75 for the calcium, lanthanum, and hydrogen zeolites, respectively. These acidities compared well with trends reported in literature for zeolites pretreated under different conditions. Titration of Broensted sites with arylmethanol indicators did not give satisfactory visible endpoints.

1980-05-29

357

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to observe both the clinical signs and symptoms of wounds at risk of infection, that is critically colonised (biofilm infected) and antimicrobial-performance of an ionic silver alginate/carboxymethylcellulose (SACMC) dressing, in comparison with a non silver calcium alginate fibre (AF) dressing, on chronic venous leg and pressure ulcers. Thirty-six patients with venous or pressure ulcers, considered clinically to be critically colonised (biofilm infected), were randomly chosen to receive either an SACMC dressing or a non silver calcium AF dressing. The efficacy of each wound dressing was evaluated over a 4-week period. The primary study endpoints were prevention of infection and progression to wound healing. The SACMC group showed a statistically significant (P = ...

2010-01-01

358

The viscoelastic composite with interface debonding

British Library Electronic Table of Contents (United Kingdom)

The effect of particle/matrix interface debonding on composites consisting of elastic particles and viscoelastic matrix is studied. The interface debonding is represented by a nonlinear cohesive law for the high explosive PBX 9501. The Mori-Tanaka method gives the constitutive relation of the composite in terms of the properties of elastic particles, viscoelastic matrix, and nonlinear cohesive law for interfaces. For the example of a composite with spherical particles subject to hydrostatic tension, simple analytical expressions of the composite stress-strain relation are obtained. The strain rate and temperature have strong effects on the composite behavior. High strain rate and low temperature give high strength of the composite. However, the rate and temperature effects decrease as the ...

2008-01-01

359

Study of titanium-niobium alloys manufactured by magnesium thermic reduction of chlorides

Steady-state neutronic investigations to the accident of water ingress in systems with pebble-bed high-temperature gas-cooled reactor fuel

Chemical and phase homogeneity of titanium-niobium sponge, produced by a combined magnesium-thermic reduction of niobium pentachloride and titanium tetrachloride mixtures, is investigated. It is ascertained that a sponge consists of spherical shape particles and has a large number of pores. Particle sizes are reduced with niobium being substituted for titanium from 50-500 #mu#m for titanium sponge to 1-40 #mu#m for niobium one, which testifies to the bormation in a titanium-niobium sponge of an alloy and not a mechanical mixture. A number of solid solutions is detected by X-ray phase analysis. Lattice parameters are determined.

360

Static and dynamic muonic-atom codes-MUON and RURP

For light water reactors, loss of coolant is an important point in safety analysis, whereas for gas-cooled reactors the ingress of water into the core region is an incident of safety relevance. The applicability of the computer code system GAMTEREX to pebble beds of spherical high-temperature gas-cooled reactor fuel elements with simulated water ingress is verified by experiment. The measurements were performed at a Siemens-Argonaut reactor, using its ring core as a driver zone for a pebble-bed core in the center of the reactor.

1987-09-01

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361

Results from the photoemission spectroscopy beamline 2B1 at Pohang Light Source

Muonic-atom energy levels and wave functions are calculated. The results are corrected for nearly all important static effects, including finite nuclear size as produced by a user-specified nuclear charge distribution. Fourth-order Runge-Kutta integration of the radial Dirac equations, with the secant method determining the eigenvalues. Corrections are either included as potentials in the Dirac equations or computed as first-order perturbations. The code assumes spherical symmetry, so that effects of nuclear deformation may be treated only as static first-order perturbations. Dynamic muon-electron and muon-nuclear effects are neglected (the latter are calculated by RURP). (Auth.).

1979-02-01

362

Quantum tunnelling for Hawking radiation from a dynamical Black Hole

The results of photoemission spectroscopy using molybdenum and tantalum samples have been obtained from the new beamline 2B1 at Pohang Light Source. Beamline 2B1 is based on a spherical grating monochromator (SGM) which is equipped with five gratings. The photon energy range from 184 to 1100 eV was covered in this work using two gratings (Gratings 4 and 5). The photon energy resolution has been deduced from Ta Fermi-level spectra and 3d spectra of Mo.

1999-06-01

363

Preparation of silver nanofluid by the submerged arc nanoparticle synthesis system (SANSS)

The paper deals with Hawking radiation related to non-static spherically symmetric black hole. Quantum corrections are incorporated using Hamilton-Jacobi method beyond semi-classical approximation. It is found that different order correction terms satisfy identical differential equation as the semiclassical action and are solved by a typical technique. It has been shown that with proper choice of the proportionality factors, one loop back reaction effect in the space time can be obtained. Finally, using the law of black hole mechanics, a general modified form of the black hole entropy is obtained considering modified Hawking temperature.

2011-01-01

364

Phenomenological studies on structure and elemental composition of nanosecond and femtosecond laser-generated aerosols with implications on laser ablation inductively coupled plasma mass spectrometry

The purpose of this study is fabrication and characterization of silver nanofluid by the submerged arc nanoparticle synthesis system (SANSS). The silver metal electrodes under the electrical discharge will melt and evaporate rapidly and condense to form the nanoparticles in the lower temperature dielectric liquid and produce the suspended nanoparticle. The results showed that the spherical nanosilver particle formed in the ethylene glycol and the mean particle size is about 12.5 nm. The prepared silver nanofluid was irradiated under the 410 nm visible light, electrons could be excited from the valence band to the conduction band. The silver nanofluid more closely resembles Newtonian fluids.

2007-05-31

365

Odontopus brevirostris (Hustache, 1936) (Coleoptera, Curculionidae) associated with new host plants belonging to Annona (Annonaceae)

In laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), the properties of laser-generated aerosols, such as size and composition, are crucial for matrix-independent quantification. In this study, the aerosol particle morphology and elemental composition generated by two state-of-the-art laser systems (ArF excimer nanosecond-UV laser and Ti:sapphire femtosecond-IR laser) were investigated by electron microscopic techniques. Electrostatic sampling of the aerosols directly onto transmission electron microscopy (TEM) grids allowed us to study the morphology and elemental composition of the aerosols using TEM and TEM-EDX (energy dispersive X-ray spectroscopy) analyses, respectively. The results of the electron microscopic studies were finally compared to the LA-ICPMS signals of the main matrix components. The investigations were carried out for non-conducting materials (glass and zircon), metallic samples (steel and brass) and semiconductors (sulfides). The studies ...

366

Scientific Electronic Library Online (English)

Abstract in english Odontopus brevirostris (Hustache, 1936) feeding on Annona squamosa L., A. cherimola Mill., A. glabra L., and A. muricata L. was observed. The last three host plants are recorded for the first time. The endophitic oviposition occurs in the veins of the ventral surface of the young leaves. The larvae, leaf miners, eat the parenchyma and the adults make small holes in the leaves. The pupation occurs in spherical cocoons protected by a sort of nest (pupation chamber) between the two epidermal layers.

2002-01-01

367

Neutron leakage benchmarks for water moderators

Interaction between flavonoid, quercetin and surfactant aggregates with different charges

Fission reaction rates for four nuclides were measured in the leakage spectrum outside spherical water moderators of various radii surrounding a {sup 252}Cf neutron source. Using the MCNP transport code, matching calculations were made with highly detailed modeling of the measurement apparatus. The calculations predicted significantly higher leakage of neutrons in the epicadmium energy range than was found in the measurements. A discrepancy of the same sign but weaker magnitude was found for thermal neutrons. These discrepancies may be relevant to problems with criticality calculations in special cases.

1994-12-31

368

British Library Electronic Table of Contents (United Kingdom)

The interactions of flavonoid, quercetin with sodium dodecyl sulfate (anionic surfactant) and cetyltrimethyl ammonium bromide (cationic surfactant) micelles were investigated. The average location site of quercetin in different micelles was determined by the cyclic voltammetry method with the aid of molecular optimization. The interaction parameters of quercetin with micelles of different charges such as binding constant K and normal binding energy DG were calculated. Furthermore, the morphologic change of the SDS and CTAB spherical micelles and rod-like micelles upon their interaction with quercetin was also observed.

2006-01-01

369

High current implantation of negative copper ions into silica glasses

Generator coordinate method for triaxial quadrupole collective dynamics in strontium isotopes

High-current implantation of Cu{sup {minus}} ions into silica glasses has been demonstrated using mA-class negative ion beams at 60 keV. Negative ion implantation has an advantage to alleviate specimen charging for insulating substrates and has attained high dose rates, up to 260 {micro}A/cm{sup 2}. Spherical Cu colloids form in the silica glasses without additional thermal annealing. Optical absorption and reflection of the implanted specimens vary with the current density, even at a fixed dose level. A beam-induced surface plasma may affect the high current implantation.

1997-12-01

370

Fast Neutral Pressure Measurements in NSTX

We discuss the algebraic structure of the generator coordinate method for triaxial quadrupole collective motion. The collective solutions are classified according to the representations of the permutation group of the intrinsic axes. Our method amounts to an approximate angular-momentum projection. We apply it to a study of the spherical-to-deformed-shape transition in light even strontium isotopes {sup 78-88}Sr. We find that triaxial configurations play a significant role in explaining the structure of the transitional isotopes {sup 80-82}Sr. (orig.).

1991-07-29

371

Estimation of static formation temperatures in geothermal wells

Several fast neutral pressure gauges have been installed on NSTX [National Spherical Torus Experiment] to measure the vessel and divertor pressure during inductive and coaxial helicity injected (CHI) plasma operations. Modified, PDX [Poloidal Divertor Experiment]-type Penning gauges have been installed on the upper and lower divertors. Neutral pressure measurements during plasma operations from these and from two shielded fast Micro ion gauges at different toroidal locations on the vessel mid-plane are described. A new unshielded ion gauge, referred to as the In-vessel Neutral Pressure (INP) gauge is under development.

2002-08-06

372

Emittance characteristics of negative ion beams generated by the sputter technique

Stabilized formation temperatures were estimated at different depths in 40 wells from the Los Humeros geothermal field, Mexico, using the Horner and the spherical radial flow (SRF) methods. The results showed that the Horner method underestimates formation temperatures, while the SRF method gives temperatures that are closer to the true formation temperatures. This was supported by numerical simulation of a combined circulation and shut-in period in several wells, and results for well H-26 are presented. Numerical reproduction of logged temperature is more feasible if an initial temperature profile based on the SRF method is employed instead of using an initial temperature profile based on the Horner method. (Author)

2003-05-01

373

Emittance characteristics of negative ion beams generated by the sputter technique

Average emittance data for ion beams extracted from cesium-sputter negative ion sources equipped with spherical, ellipsoidal, and cylindrical geometry cesium-surface ionizers are presented. The attributes of the respective source geometries are described in terms of their cesium ion optical properties. The results of recent measurement of the emittances of momentum-analyzed beams extracted from the ellipsoidal geometry source are also presented. These measurements indicate the presence of a species-dependent effect. The effect is believed to be attributable to differences in the energy spreads of the respective negative ion beams introduced by the sputter generation process.

1990-01-01

374

Electrical properties of airborne nanoparticles produced by a commercial spark-discharge generator

Average emittance data for ion beams extracted from cesium-sputter negative ion sources equipped with spherical, ellipsoidal, and cylindrical geometry cesium-surface ionizers are presented. The attributes of the respective source geometries are described in terms of their cesium ion optical properties. The results of recent measurement of the emittances of momentum-analyzed beams extracted from the ellipsoidal geometry source are also presented. These measurements indicate the presence of a species-dependent effect. The effect is believed to be attributable to differences in the energy spreads of the respective negative ion beams introduced by the sputter generation process. 11 refs., 8 figs.

1989-01-01

375

Carbon fiber/epoxy matrix composite springs as self-centering supports: manufacture and evaluation

A nanoparticle generator based on the principle of electrical discharge (PALAS GFG-1000) was used to produce nanoparticles of different chemical natures. The fractions of electrically neutral particles were then measured by means of a Spectrometre de Mobilite Electrique Circulaire (SMEC, i.e. radial-flow mobility analyzer) for different operating conditions. The experimental results were compared with the theoretical values calculated from the Fuchs extended charge equilibrium model for spherical particles and agglomerates. For the smallest particles (below 20 nm), the deviations observed remain below 10%, and tend towards 20% for larger particles (over 35 nm).

2010-08-01

376

Are classical tachyons slower-than-light quantum particles

A variety of engineering and experimental applications require primary support structures which are self-centering. High mechanical strength, low-density, carbon fiber/epoxy matrix composite springs are used in unique planar, cylindrical, conical, and spherical configurations to self-center components. The sinusoidal and triangular-shaped composite springs are readily manufactured and assembled into component hardware. Design considerations, flexural strength properties, load bearing and centering data plus procedures for the manufacture of composite springs are presented.

1984-01-01

377

A primer on elliptic functions with applications in classical mechanics

After having studied the shape that a tachyon T (e.g., intrinsically spherical) would take up, we show in an explicit example that the characteristics of classical tachyons are similar to those of the ordinary (slower-than-light) quantum particles. In particular, a realistic tachyon is associated with a ''phase speed'' V(V/sup 2/>c/sup 2/), but with a ''group speed'' upsilon=c/sup 2//V (upsilon/sup 2/

1983-07-02

378

The separation and determination of trace elements in iron ore

The Jacobi and Weierstrass elliptic functions used to be part of the standard mathematical arsenal of physics students. They appear as solutions of many important problems in classical mechanics: the motion of a planar pendulum (Jacobi), the motion of a force-free asymmetric top (Jacobi), the motion of a spherical pendulum (Weierstrass), and the motion of a heavy symmetric top with one fixed point (Weierstrass). The problem of the planar pendulum, in fact, can be used to construct the general connection between the Jacobi and Weierstrass elliptic functions. The easy access to mathematical software by physics students suggests that they might reappear as useful tools in the undergraduate curriculum.

2007-01-01

379

The relation between net calcium, alkali cation and chloride movements in red cells exposed to salicylate.

The separation, concentration, and determination of trace elements in iron ores are described. After the sample has been dissolved, the iron is separated by liquid-liquid extraction with a liquid cation-exchanger, di-(2-ethylhexyl) phosphoric acid. The trace elements aluminium, cadmium, calcium, chromium, cobalt, copper, lead, magnesium, manganese, mercury, potassium, sodium, vanadium, and zinc are determined in the aqueous phase by atomic-absorption spectrophotometry.

2008-05-01

380

Roles of mitochondria and temperature in the control of intracellular calcium in adult rat sensory neurons

1. From a 150 mM-NH4 salicylate medium salicylate enters human red cells with a rate constant of 1.9 min-1 at 0 degrees C. 2. Salicylate increases the red cell permeability for Ca2+ (and Mg2+). There...Full Text Available

1979-02-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

381

Research on the liquefaction of lignite by hydrogenation

SUMMARYWe recorded Ca²⁺ current and intracellular Ca²⁺ ([Ca²⁺]_i) in isolated adult rat dorsal root ganglion (DRG) neurons at 20 and...Full Text Available

2008-04-01

382

Radioactive lead studies in the human

The investigations of lignite hydroliquefaction were aimed at improving reaction control in order to minimize residue and gas portion and hence increase the oil yield. To reach this goal, the process parameters were optimized and various catalysts tested for use in sump phase hydrogenation. Detailed investigations were also carried out on the problem of calcium carbonate agglomeration and the maceral decomposition behaviour of different lignite samples under hydrogenation conditions.

1985-01-01

383

Photolysis of the novel inotropes EMD 57033 and EMD 57439: evidence that Ca2+ sensitization and phosphodiesterase inhibition depend upon the same enantiomeric site.

The differing susceptibility of individuals to the toxic effects of chronic lead exposure has never been fully understood. As the major intake of lead in the human is from food and beverages, any variation between individuals of the quantity of lead absorbed from the gut, and of the distribution and excretion of this lead, may account for the differences in individual susceptibility. The food and beverages themselves may have an influence, and to investigate their effects on absorption, distribution and excretion of lead, experiments were performed on normal subjects using a short lived radionuclide of lead, "2"0"3Pb, and instruments generally available in Nuclear Medicine. Lead absorption between different individuals showed a wide variation when "2"0"3Pb was taken as a single dose between meals. Minerals were found to be mainly responsible for affecting absorption when one subject ingested "2"0"3Pb in control meals from which one dietary constituent at a time was omitted. ...

384

Perlinhibin, a Cysteine-, Histidine-, and Arginine-Rich Miniprotein from Abalone (Haliotis laevigata) Nacre, Inhibits In Vitro Calcium Carbonate Crystallization

1. We studied the effects of flash photolysis on the novel enantiomeric cardiac inotropes EMD 57033 (a calcium sensitizer) and EMD 57439 (a phosphodiesterase III inhibitor) in rat isolated ventricular...Full Text Available

1996-08-01

385

Pathophysiology of incomplete renal tubular acidosis in recurrent renal stone formers: evidence of disturbed calcium, bone and citrate metabolism

We have isolated a 4.785 Da protein from the nacreous layer of the sea snail Haliotis laevigata (greenlip abalone) shell after demineralization with acetic acid. The sequence of 41...Full Text Available

2007-08-15

386

Magnesium Sensitizes Slow Vacuolar Channels to Physiological Cytosolic Calcium and Inhibits Fast Vacuolar Channels in Fava Bean Guard Cell Vacuoles1

Urinary acidification, bone metabolism and urinary excretion of calcium and citrate were evaluated in 10 recurrent stone formers with incomplete renal tubular acidosis (iRTA), 10 recurrent stone formers with normal urinary acidification (NUA) and 10 normal controls (NC). Patients with iRTA had lower plasma standard bicarbonate after fasting (P <0.01) and lower urinary excretion of titratable acid (P <0.05) and citrate (P <0.01) compared with NUA patients and NC, and higher urinary excretion of ammonia (P <0.05) compared with NC (P <0.05). Hypercalciuria was found in 6 of 10 patients with iRTA compared with 3 of 10 with NUA, and 0 of 10 NC. The citrate/calcium ratio in urine was significantly reduced in iRTA compared with the value in NUA (P <0.01), and in NUA compared with NC (P <0.05). Biochemical markers of bone formation (serum osteocalcin) and bone resorption (urinary hydroxyproline) were significantly increased in iRTA ...

1993-01-01

387

Involvement of protein kinase C in the mechanism of action of Escherichia coli heat-stable enterotoxin (STa) in a human colonic carcinoma cell line, COLO-205

Vacuolar ion channels in guard cells play important roles during stomatal movement and are regulated by many factors including Ca²⁺, calmodulin, protein kinases, and phosphatases....Full Text Available

1999-11-01

388

Inactivating calcium-sensing receptor mutations in patients with primary hyperparathyroidism.

The present study was undertaken to determine the involvement of calcium-protein kinase C pathway in the mechanism of action of Escherichia coli heat stable enterotoxin (STa) apart from STa-induced activation of guanylate cyclase in human colonic carcinoma cell line COLO-205, which was used as a model cultured cell line to study the mechanism of action of E. coli STa. In response to E. coli STa, protein kinase C (PKC) activity was increased in a time-dependent manner with its physical translocation from cytosol to membrane. Inhibition of the PKC activity in membrane fraction and inhibition of its physical translocation in response to IP_3-mediated calcium release inhibitor dantrolene suggested the involvement of intracellular store depletion in the regulation of PKC activity. Among different PKC isoforms, predominant involvement of calcium-dependent protein kinase C (PKC#alpha#) was specified using isotype-specific ...

2005-08-01

389

Gastrointestinal absorption of lead in chicks: involvement of the cholecalciferol endocrine system

Objective:? Primary hyperparathyroidism (HPT) is characterised by autonomous secretion of PTH from enlarged parathyroid glands leading, in most patients, to asymptomatic hypercalcaemia. Familial hypocalciuric hypercalcaemia (FHH) is an autosomal dominant disorder caused by inactivating mutations in the calcium sensing receptor (CaSR) gene; it is characterised by lifelong and usually asymptomatic hypercalcaemia. Establishing the correct diagnosis is important because surgery can be curative in HPT, but ineffective in FHH. There is overlap in the diagnostic criteria for the two disorders and some patients carrying inactivating mutations in the CaSR gene, which is suggestive of FHH, also have HPT with hyperplastic parathyroid glands or adenomas. Design and Patients:? CaSR gene mutations were analyzed and clinical and biochemical parameters evaluated in 139 consecutive out-patients presenting with hypercalcaemia and suspected of having HPT. Results:? Six different ...

2011-03-29

390

Gastrointestinal absorption of lead in chicks: involvement of the cholecalciferol endocrine system

The role of dietary calcium and phosphorus in modifying the intestinal absorption of lead and also the effect of lead ingestion on the metabolism of cholecalciferol were studied in chicks. The efficiency of absorption of /sup 203/Pb and /sup 47/Ca was increased when the animals were fed a low calcium diet and treated with cholecalciferol. The synthesis of the vitamin D-induced calcium-binding protein (CaBP) was correspondingly increased. When the chicks were depleted of vitamin D and repleted with 1,25-dihydroxycholecalciferol (1,25(OH)/sub 2/D/sub 3/) as their only source of the vitamin, the absorption of both /sup 47/Ca and /sup 203/Pb was unaffected by dietary calcium levels, and no change in CaBP levels occurred. Low dietary intake of phosphorus resulted in an increase in /sup 47/Ca and /sup 203/Pb absorption and in CaBP synthesis when the animals were treated with cholecalciferol. However, when the ...

1984-04-01

391

Gamma interferon induces rapid and coordinate activation of mitogen-activated protein kinase (extracellular signal-regulated kinase) and calcium-independent protein kinase C in human monocytes.

The role of dietary calcium and phosphorus in modifying the intestinal absorption of lead and also the effect of lead ingestion on the metabolism of cholecalciferol were studied in chicks. The efficiency of absorption of "2"0"3Pb and "4"7Ca was increased when the animals were fed a low calcium diet and treated with cholecalciferol. The synthesis of the vitamin D-induced calcium-binding protein (CaBP) was correspondingly increased. When the chicks were depleted of vitamin D and repleted with 1,25-dihydroxycholecalciferol [1,25(OH)_2D_3] as their only source of the vitamin, the absorption of both "4"7Ca and "2"0"3Pb was unaffected by dietary calcium levels, and no change in CaBP levels occurred. Low dietary intake of phosphorus resulted in an increase in "4"7Ca and "2"0"3Pb absorption and in CaBP synthesis when the animals were treated with cholecalciferol. However, when the birds were repleted with ...

392

Effect of secondary fuels and combustor temperature on mercury speciation in pulverized fuel co-combustion: part 1

Gamma interferon plays an important role in regulating the functional properties of mononuclear phagocytes. In the present study, the role of activated protein kinases in the mechanism of action of...Full Text Available

1994-07-01

393

Differential Roles for STIM1 and STIM2 in Store-Operated Calcium Entry in Rat Neurons

The present work mainly involves bench scale studies to investigate partitioning of mercury in pulverized fuel co-combustion at 1000 and 1300{sup o}C. High volatile bituminous coal is used as a reference case and chicken manure, olive residue, and B quality (demolition) wood are used as secondary fuels with 10 and 20% thermal shares. The combustion experiments are carried out in an entrained flow reactor with a fuel input of 7-8 kWth. Elemental and total gaseous mercury concentrations in the flue gas of the reactor are measured on-line, and ash is analyzed for particulate mercury along with other elemental and surface properties. Animal waste like chicken manure behaves very differently from plant waste. The higher chlorine contents of chicken manure cause higher ionic mercury concentrations whereas even with high unburnt carbon, particulate mercury reduces with increase in the chicken manure share. This might be a problem due to coarse fuel particles, low surface area, and iron ...

2007-08-15

394

Dietary calcium and magnesium intakes and the risk of type 2 diabetes: the Shanghai Women's Health Study¹²³

The interaction between Ca²⁺ sensors STIM1 and STIM2 and Ca²⁺ channel-forming protein ORAI1 is a crucial element of ...Full Text Available

395

Autocrine regulation of T-cell activation by ATP release and P2X₇ receptors

Background: Diet plays a key role in the development of type 2 diabetes (T2D), but little is known about the contributions of specific nutrients in populations in which dietary patterns...Full Text Available

2009-04-01

396

A progress for the health of south countries. The solar refrigerator; Un progres pour la sante dans les pays du Sud. Le refrigerateur solaire

T-cell activation requires the influx of extracellular calcium, although mechanistic details regarding such activation are not fully defined. Here, we show that P2X₇ receptors play a key...Full Text Available

2009-06-01

397

A comparison of nutrient dynamics in forest ecosystems along with the Warmth Index Gradient

In order to conserve vaccines in hot countries a solar refrigerator has been made by a French university. It is a photothermal refrigerator without batteries. It uses two gases: ammonia and calcium chloride. The refrigerator is autonomous and can work eleven days without sun. (N.C.)

1998-05-01

398

A Laser-Pointer-Based Spectrometer for Endpoint Detection of EDTA Titrations

Nutrient elements contained in litter fall flux, that of uptake flux and turnover rate had generally tended to increase with the increase in the Warmth Index, while the amount of nutrient in the A[sub 0] horizon and nutrient use efficiency did not. However, it is suggested that topographic and climatic aridity, and the amount of available and exchangeable phosphorus, calcium and magnesium greatly affect the nutrient dynamics in a each forest ecosystem as the Warmth Index increases. (J.P.N.).

1993-01-01

399

Agonist-directed trafficking of signalling at serotonin 5-HT2A, 5-HT2B and 5-HT2C-VSV receptors mediated Gq/11 activation and calcium mobilisation in CHO cells.

A laser spectrometer for the ethylenediaminetetra-acetic acid (EDTA) titration of magnesium or calcium ions that is designed around a handheld laser pointer as the source and a photoresistor as the detector is developed. Findings show that the use of the spectrometer reduces the degree of uncertainty and error in one part of the EDTA titrations, however overall standard deviations depend on the skill of the student and their willingness to be careful and precise.

2004-12-01

400

Unusual carbon partitioning during phosphate deficiency in celery, a mannitol-synthesizing species

Several examples of agonist-directed trafficking of receptor signalling at 5-HT2A and 5-HT2C receptors have been reported that involve independent downstream transduction pathways. We now report the functional selectivity of a series of chemically diverse agonists at human (h)5-HT2A, h5-HT2B and h5-HT2C-VSV by examining two related responses, the upstream activation of Gq/11 proteins in comparison with its associated cascade of calcium mobilisation. At the h5-HT2A receptor, d-lysergic acid diethylamide (LSD) and the antiparkinsonian agents lisuride, bromocriptine and pergolide exhibit a higher potency for Gq/11 activation than calcium release in contrast with all the other tested ligands such as 5-HT, mCPP and BW723C86, that show an opposite preference of signalling pathway. Comparable observations are made at h5-HT2B and h5-HT2C-VSV receptors, suggesting a similar mechanism of functional selectivity for the three serotonin receptors. ...

2008-07-30

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401

The reduction of actinide ions by hydroxamic acids

Mannitol and sucrose are the main photosynthetic products and translocated carbon compounds in celery (Apium graveolens L.). Carbon partitioning was studied in greenhouse-grown celery plants supplied with a nutrient solution containing or lacking phosphate (P). P-deficient plants developed new leaves at about the same rate as control plants, but showed greatly reduced growth of leaves and petioles; root growth was apparently unaffected. P-deficient leaves contained less mannitol and more sucrose than control leaves. Starch content increased with P-deficiency only in mature (the most photosynthetically-active) leaves, and then amounted to less than 10 mg/g fresh weight. Similarly, when {sup 14}CO{sub 2} was supplied to intact plants, P-deficient leaves contained less label in mannitol and more in sucrose than did control leaves; labeling of starch changed little. The P-status of celery leaves apparently affects the partitioning of carbon between mannitol and sucrose ...

1989-04-01

402

Sucrose phosphate synthase activity in rice grown at elevated CO sub 2 and temperature

Simple hydroxamic acids have been shown to have useful applications in an Advanced Purex process for the reprocessing of irradiated nuclear fuel. They are especially suited to the separation of neptunium (IV) from uranium (VI) by the selective formation of a hydrophilic complex with Np(IV). U(VI) extraction in to 30% tributyl phosphate is unaffected. However, they have also been shown to be very fast reducing agents for Np(VI). The timescales of the reduction have been defined under a range of typical Purex Process conditions although the accurate determination of the reaction kinetics was not possible due to the rapidity of the reaction. U(VI) was shown not to be reduced. Therefore, Np(VI) can be efficiently reductively stripped when solvent phase (30% tributyl phosphate in odourless kerosene) solutions of Np(VI) and U(VI) are contacted with aqueous phase hydroxamic acid solutions. The slow reduction of plutonium (IV) to Pu(III) has also been ...

1999-01-01

403

Research on development of adsorbent for separating and collecting light element isotopes

Rice (Oryza sativa L.) was grown at 330 and 660 {mu}L CO{sub 2} L{sup {minus}1} and at 40/33/37, 34/27/31, and 28/21/25{degree}C day/night/paddy water temperatures respectively. Sucrose phosphate synthase (SPS) activity was measured at saturating substrate concentrations at 59 days after planting. SPS activity increased 2 and 3 fold with increasing CO{sub 2} at 28 and 34{degree}C air temperatures respectively. At 40{degree}C SPS activity decreased by 37% at elevated CO{sub 2} and most plants failed to reach maturity. Similar responses were found in leaf samples taken in the dark. These results indicate that SPS, an enzyme involved in the regulation of C partitioning in leaves, increases in activity at elevated CO{sub 2}. This is in contrast to previous results with soybean. The changes in SPS activity will also be discussed in relation to leaf starch/sucrose ratios.

1990-05-01

404

Rapid toxicity testing based on mitochondrial respiratory activity

Lithium isotopes are used as the raw material of tritium which is the fuel for fusion power generation and the material for fusion reactors, accordingly those are indispensable for future nuclear fusion power generation. As for boron isotopes, the neutron absorption corss section is very large, therefore, they are used for shielding neutrons and controlling fast neutron reactors. In order to further develop the utilization of nuclear power, it is important to develop the technology for separating and refining light element isotopes in large amount. In fiscal year 1995, the relation of the ion sieve characteristics of inorganic ion exchanger and the behavior of lithium isotope separation was examined. The behavior of forming boron complex of polyol amine was examined by B-11 NMR. These experiments and the results are reported. It was shown to be feasible that lithium is adsorbed from seawater, and isotopes are concentrated. Titanium phosphate and its heat treated ...

405

Lithium ion conductive glass?ceramics with Li3Fe2(PO4)3 and YAG laser-induced local crystallization in lithium iron phosphate glasses

The need exists for rapid and inexpensive methods to determine the health effects of environmental contaminants on biological systems. One of the current research approaches for assessing cytotoxicity is to monitor the respiratory activity of the mitochondrion, a sensitive, nonspecific subcellular target site. Detected changes in mitochondrial function after the addition of a test chemical could be correlated to toxic effects. Mitochondrial respiration can be characterized by three indices: state 3 and state 4 respiratory rates, and the respiratory control ratio (RCR). State 4, the idle or resting state, results when coupled mitochondrial respire in a medium containing inorganic phosphate and a Kreb's cycle substrate in the absence of a phosphate acceptor such as adenosine diphosphate (ADP). In the presence of ADP the respiration rate increases to a maximum (state 3), accompanied by phosphorylation of ADP to adenosine triphosphate ...

1990-05-01

406

British Library Electronic Table of Contents (United Kingdom)

The glasses with the composition of 37.5Li2O?(25?x)Fe2O3?xNb2O5?37.5P2O5 (mol%) (x=5,10,15) are prepared, and it is found that the addition of Nb2O5 is effective for the glass formation in the lithium iron phosphate system. The glass?ceramics consisting of Nasicon-type Li3Fe2(PO4)3 crystals with an orthorhombic structure are developed through conventional crystallization in an electric furnace, showing electrical conductivities of 3?10?6?Scm?1 at room temperature and the activation energies of 0.48?eV (x=5) and 0.51?eV (x=10) for Li+ ion conduction in the temperature range of 30?200??C. A continuous wave Nd:YAG laser (wavelength: 1064?nm) with powers of 0.14?0.30?W and a scanning speed of 10??m/s is irradiated onto the surface of the glasses, and the formation of Li3Fe2(PO4)3 crystals is c...

2008-01-01

407

LiPF{sub 6}. Synthesis and stability in EC/DMC and PC/DMC mixtures; LiPF{sub 6}. Synthese et stabilite dans les melanges EC/DMC et PC/DMC

Hybrid porous phosphate heterostructures as adsorbents of Hg(II) and Ni(II) from industrial sewage

Lithium hexa-fluoro-phosphate LiPF{sub 6} is recommended for the replacement of the toxic LiAsF{sub 6} and the explosive perchlorates (like LiClO{sub 4}) in rechargeable lithium electrochemical generators. The aim of this work is to develop a new method of synthesis of this salt and to check its stability with respect to carbonated solvents: ethylene carbonate (EC), propylene carbonate (PC) and dimethyl-carbonate (DMC) in already optimized EC/DMC and PC/DMC binary mixtures. Two methods using HPF{sub 6} are proposed: the first one uses the direct neutralization of this commercial acid by LiOH in aqueous, alcoholic or acetonitrile environment, while in the second one LiPF{sub 6} is obtained from pyridinium hexa-fluoro-phosphate synthesized from HPF{sub 6} using a new and simple protocol. (J.S.) 24 refs.

1996-12-31

408

British Library Electronic Table of Contents (United Kingdom)

Porous phosphate heterostructures (PPH), functionalized with different ratios of aminopropyl and mercaptopropyl groups, labelled as Nx=5,25,50-PPH and Sx=5,25,50-PPH, respectively, were tested as adsorbents for Ni(II) and Hg(II) found in industrial sewage from electroplating processes and button battery recycling. X-ray diffraction was used to study the structures. The specific surface area of the pristine material (PPH) was 620m^2g^-^1, whereas the specific surface areas of the modified mercaptopropyl (S5-PPH) and aminopropyl (N5-PPH) were 472 and 223m^2g^-^1, respectively. The adsorption data were fitted to a Langmuir isotherm model. The S5-PPH material was saturated by 120mmol Hg(II) per 100g of material, whereas for Ni(II) adsorption, N25-PPH material displayed the highest adsorption w...

2011-01-01

409

Genetic engineering of group 2 sigma factor SigE widely activates expressions of sugar catabolic genes in Synechocystis species PCC 6803.

Fluorimetric study of the interaction between nicotinamide adenine dinucleotide phosphate and tetracycline-europium complex and its application

Metabolic engineering of photosynthetic organisms is required for utilization of light energy and for reducing carbon emissions.Control of transcriptional regulators is a powerful approach for changing cellular dynamics, because a set of genes is concomitantly regulated. Here, we show that overexpression of a group 2 ? factor, SigE, enhances the expressions of sugar catabolic genes in the unicellular cyanobacterium, Synechocystis sp. PCC 6803. Transcriptome analysis revealed that genes for the oxidative pentose phosphate pathway and glycogen catabolism are induced by overproduction of SigE. Immunoblotting showed that protein levels of sugar catabolic enzymes, such as glucose-6-phosphate dehydrogenase, 6-phosphogluconate dehydrogenase, glycogen phosphorylase, and isoamylase, are increased. Glycogen levels are reduced in the SigE-overexpressing strain grown under light. Metabolome analysis revealed that metabolite levels of the TCA cycle and ...

2011-07-11

410

Enhancement of glass-forming ability and bio-corrosion resistance of Zr-Co-Al bulk metallic glasses by the addition of Ag

A new spectrofluorimetric method was developed for the determination of trace amount of nicotinamide adenine dinucleotide phosphate (NADP). Using europium (Eu{sup 3+})-tetracycline (TC) complex as a fluorescent probe, in the buffer solution of pH 7.60. NADP can remarkably enhance the fluorescence intensity of the Eu{sup 3+}-TC complex at {lambda} = 612 nm and the enhanced fluorescence intensity of Eu{sup 3+} ion is in proportion to the concentration of NADP. Optimum conditions for the determination of NADP were also investigated. The dynamic range for the determination of NADP is 4.4 x 10{sup -7} to 2.2 x 10{sup -6} mol l{sup -1} with detection limit of 6.9 x 10{sup -8} mol l{sup -1}. This method is simple, practical and relatively free interference from coexisting substances and can be successfully applied to determination of NADP in synthetic water samples and in serum samples. Moreover, the enhancement mechanisms of the fluorescence intensity in the Eu{sup ...

2005-09-06

411

Batch test equilibration studies examining the removal of Cs, Sr, and Tc from supernatants from ORNL underground storage tanks by selected ion exchangers

A novel Ni and Cu-free Zr-based bulk metallic glass (BMG) system with enhancement of glass-forming ability (GFA) and bio-corrosion resistance was prepared by copper mold casting by the addition of Ag. It was found that the addition of Ag can considerably enhance the glass-forming ability, as indicated by the increase of the critical glass dimension from 3 mm diameter of the ternary system to over 10 mm in the alloy of Zr_5_3Co_1_8_._5Al_2_3_._5Ag_5. The bio-corrosion behaviors of the Zr-based BMGs in phosphate buffered solution (PBS) were investigated by electrochemical polarization at 310 K. It was found that the addition of appropriate amount of Ag can enhance the corrosion resistance of the BMGs. The X-ray photoelectron spectroscopy (XPS) indicated that the formation of an Al_2O_3-enriched passive film is mainly responsible for the high corrosion resistance of Ag-bearing alloy in phosphate buffered solution.

2010-08-01

412

A procedure for batch separation of sup 14 C-hexose from sup 14 C-sucrose

Bench-scale batch equilibration tests have been conducted with supernatants from two underground tanks at the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to determine the effectiveness of selected ion exchangers in removing cesium, strontium, and technetium. Seven sorbents were evaluated for cesium removal, nine for strontium removal, and four for technetium removal. The results indicate that granular potassium cobalt hexacyanoferrate was the most effective of the exchangers evaluated for removing cesium from the supernatants. The powdered forms of sodium titanate (NaTiO) and cystalline silicotitanate (CST) were superior in removing the strontium; however, for the sorbents of suitable particle size for column use, titanium monohydrogen phosphate (TiHP {phi}), sodium titanate/polyacrylonitrile (NaTiO-PAN), and titanium monohydrogen phosphate/polyacrylonitrile (TiP-PAN) gave the best results and were about ...

1995-06-01

413

Wastewater treatment of industrial effluent using activated dolomite adsorption

This presentation describes a method for separating {sup 14}C-hexose from {sup 14}C-sucrose in extracts of plant tissue. Portions of ethanol extracts are treated with activated charcoal in microcentrifuge tubes. Aliquots are removed, ethanol evaporated and replaced with reaction mixture that phosphorylates hexose (HEPPS, K{sub 2}HPO{sub 4}, Mg(C{sub 2}H{sub 3}O{sub 2}){sub 2}, ovalbumen, Na{sub 2}ATP, yeast hexokinase). After a time course, the hexokinase reaction is stopped (slowed considerably) to minimize effects of contamination enzyme activities. The stopping agent used is lyxose, a nonphosphorylable analogue of glucose. The strong anionic charge of phosphate introduced through the hexokinase action results in binding (> 95%) of hexose-phosphate to anion-exchange resin. Sucrose remains unbound (> 95%) in solution. This batch ion-exchange is performed in microcentrifuge tubes to allow many samples to be processed simultaneously. ...

1991-05-01

414

Synthesis of high specific activity tritium labelled [2-{sup 3}H]-adenosine-5`-triphosphate

SummaryInitial results from the use of activated dolomite from QUESTOR project L1 have proved extremely encouraging in terms of metallic ion (also phosphate, nitrate and dye) removal from wastewater, with capacities in some instances in excess of commercially available activated carbons.This new project involves investigating actual plant effluent in laboratory scale columns and the design of a pilot scale rig for on site trials. The project also involves investigating disposal options and an economic [continued...

2007-01-01

415

Solubility and rate of dissolution for Miscanthus in hydrophilic ionic liquids

A procedure for high level tritium labelling at the C2-H position of adenosine 5`-triphosphate ([2-{sup 3}H]-ATP, 1), based on the tritiodehalogenation reaction of 2-bromoadenosine 5`-triphosphate (2) has been elaborated. This precursor was prepared in a six-step synthesis from guanosine. The tritiodehalogenation of (2) for three hours over palladium oxide in phosphate buffer yielded tritium labelled ATP with high specific activity, in good chemical yield. (author).

1996-08-01

416

British Library Electronic Table of Contents (United Kingdom)

Miscanthus is a potential feedstock for the production of biofuels. Lignocellulosic biomass is not soluble in conventional solvents, but Miscanthus and other lignocellulosic biomass have reasonable solubilities in some ionic liquids. The solubility of Miscanthus in a variety of hydrophilic ionic liquids was measured as a function of particle size, temperature and time for dissolution. In addition to temperature and time, the ionic liquid anion has a significant effect on solubility and rate of dissolution. The moisture content of Miscanthus lowers its solubility in certain ionic liquids. Chloride, acetate, and phosphate-based ionic liquids favor solubility. A tentative correlation for the solubility of Miscanthus is proposed in terms of Abraham solvation parameters obtained from quantum-ch...

2011-01-01

417

Production of the radioisotope "8"8Y

Preparation of poly (aryl ether ketones) in the presence of an alkali, alkaline earth of lanthanide metal salt

Carrier-free "8"8Y radioisotope, which has the longest half life (T=106.6 d) of yttrium radioisotopes and is a #gamma#-ray emitter, was obtained by proton irradiation of strontium, followed by cooling for one month. Then, "8"8Y was purified by precipitating strontium as strontium nitrate and extracting yttrium with tri-n-butyl phosphate (TBP). The decontamination factor of strontium to yttrium was more than 4x10"3 and chemically pure yttrium radioisotope was obtained. (author) 6 refs.

418

Orthophosphoric acid interactions with ultrastable zeolite Y: Infrared and NMR studies

This patent describes a process for preparing poly(aryl ether ketones) by nucleophilic displacement polymerization in the presence of at least one alkali metal base selected from potassium, rubidium or cesium, and fluoride ions, which comprises adding to the polymerization: (a) an effective amount of at least one metal salt selected from lithium, sodium, alkaline earth or lanthanide chloride, bromide, iodide, sulfate, alkyl or aryl carboxylate, cyanide, borate or phosphate to slow or stop advancement of molecular weight and (b) an end-capping agent.

1988-09-27

419

Electrochemical behavior of Alloy 800 under steam generators temperature and pressure conditions comparison, based on (I,E) polarization curves, with 316L and A533B steels

Zeolite Y is the active component of most commercial cracking catalysts. Interaction of H[sub 3]PO[sub 4] with extraframework aluminum of ultra-stable zeolite (USY) leads to the formation of different types of aluminum phosphates, while there is no indication of the formation of SAPO zeotype structures. The total acidity of USY slightly decreases upon the H[sub 3]PO[sub 4] treatment, while the maximum in the distribution of acid strength is shifted to milder acidities. Dealumination of the zeolite and creation of POH sites associated with AIPO[sub 4] are responsible for the modifications observed. 37 refs., 8 figs., 3 tabs.

1994-01-01

420

Electrochemical behavior of Alloy 800 under steam generators temperature and pressure conditions comparison, based on (I,E) polarization curves, with 316L and A533B steels

We propose a dissolution-passivation model to account for the electrochemical behavior of Alloy 800 and 316L stainless steel under steam generators operating conditions. This model is similar to the one defined for nickel, considering the known importance of this element on the studied alloys. The comparison of the rates of the elementary steps points out the favorable influence of dissolved oxygen and phosphate ions on the dissolution of Alloy 800, even in the presence of chloride ions. The sensitivity of 316L SS is greater, especially because of the lowest stability of oxide-like intermediate.

1992-12-31

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

421

Corrosion and protection of magnesium alloy AZ31D by a new conversion coating

We propose a dissolution-passivation model to account for the electrochemical behavior of Alloy 800 and 316L stainless steel under steam generators operating conditions. This model is similar to the one defined for nickel, considering the known importance of this element on the studied alloys. The comparison of the rates of the elementary steps points out the favorable influence of dissolved oxygen and phosphate ions on the dissolution of Alloy 800, even in the presence of chloride ions. The sensitivity of 316L SS is greater, especially because of the lowest stability of oxide-like intermediate.

1991-08-25

422

Synthesis and crystal structure of a new open-framework iron phosphate (NH4)4Fe3(OH)2F2[H3(PO4)4]: Novel linear trimer of corner-sharing Fe(III) octahedra

A chromium-free conversion coating for magnesium alloys were described. The conversion coating could be obtained when AZ31D magnesium alloy was immersed in a solution containing a manganese salt, phosphate and an inhibitor. Corrosion resistance of the chemical conversion coating was evaluated by anodizing polarization curve and salt immersion. XRD analysis showed that the conversion coating was mainly composed of Mn{sub 3}(PO{sub 4}){sub 2}. The morphology of the coating is observed by using SEM. The effect of electrolyte pH and concentration of inhibitor on coating growth are investigated. (orig.)

2003-07-01

423

Physical basis of the effect of hemoglobin on the "3"1P NMR chemical shifts of various phosphoryl compounds

A new iron phosphate (NH4)4Fe3(OH)2F2[H3(PO4)4] has been synthesized hydrothermally at HF concentrations from 0.5 to 1.2 mL. Single-crystal X-ray diffraction analysis reveals its three-dimensional open-framework structure (monoclinic, space group P21/n (No. 14), a=6.2614(13) A, b=9.844(2) A, c=14.271(3) A, ?=92.11(1)o, V=879.0(3) A3). This structure is built from isolated linear trimers of corner-sharing Fe(III) octahedra, which are linked by (PO4) groups to form ten-membered-ring channels along [1 0 0]. This isolated, linear trimer of corner-sharing Fe(III) octahedra, [(FeO4)3(OH)2F2], is new and adds to the diverse linkages of Fe polyhedra as secondary building units in iron phosphates. The trivalent iron at octahedral sites for the title compound has been confirmed by synchrotron Fe K-edge XANES spectra and magnetic measurements. Magnetic measurements also show that this compound exhibit a strong antiferromagnetic exchange below TN=17 K, ...

2010-12-01

424

Chemical Makeup of Microdamaged Bone Differs from Undamaged Bone

The marked difference between the intra- and extracellular "3"1P NMR chemical shifts of various phosphoryl compounds when added to a red cell suspension may be largely understood in terms of the effects of hemoglobin on the "3"1P NMR chemical shifts. The presence of [oxy- or (carbonmonoxy)-] hemoglobin inside the red cell causes the bulk magnetic susceptibility of the cell cytoplasm to be significantly less than that of the external solution. This difference is sufficient to account for the difference in the intra- and extracellular chemical shifts of the two phosphate esters trimethyl phosphate and triethyl phosphate. However, in the case of the compounds dimethyl methylphosphonate, diethyl methylphosphonate, and trimethylphosphine oxide as well as the hypophosphite, phenylphosphinate, and diphenylphosphinate ions, hemoglobin exerts an additional, much larger, effect, causing the "3"1P NMR resonances to shift to lower ...

425

"1H and "3"1P nuclear magnetic resonance investigation of the interaction between 2,3-diphosphoglycerate and human normal adult hemoglobin

Microdamage naturally occurs in bone tissue as a result of cyclic loading placed on the body from normal daily activities. While it is usually repaired through the bone turnover process, accumulation of microdamage may result in reduced bone quality and increased fracture risk. It is unclear whether certain areas of bone are more susceptible to microdamage than others due to compositional differences. This study examines whether areas of microdamaged bone are chemically different than undamaged areas of bone. Bone samples (L3 vertebrae) were harvested from 15 dogs. Samples were stained with basic fuchsin, embedded in poly-methylmethacrylate, and cut into 5-(micro)m-thick sections. Fuchsin staining was used to identify regions of microdamage, and synchrotron infrared microspectroscopic imaging was used to determine the local bone composition. Results showed that microdamaged areas of bone were chemically different than the surrounding undamaged areas. Specifically, the mineral ...

2006-01-01

426

cap alpha. decay of fission isomers

High-resolution "1H and "3"1P nuclear magnetic resonance spectroscopy has been used to investigate the binding of 2,3-diphosphoglycerate to human normal adult hemoglobin and the molecular interactions involved in the allosteric effect of the 2,3-diphosphoglycerate molecule on hemoglobin. Individual hydrogen ion NMR titration curves have been obtained for 22-26 histidyl residues of hemoglobin and for each phosphate group of 2,3-diphosphoglycerate with hemoglobin in both the deoxy and carbonmonoxy forms. The results indicate that 2,3-diphosphoglycerate binds to deoxyhemoglobin at the central cavity between the two #beta# chains and the binding involves the #beta#2-histidyl residues. Moreover, the results suggest that the binding site of 2,3-diphosphoglycerate to carbonmonoxyhemoglobin contains the same (or at least some of the same) amino acid residues responsible for binding in the deoxy form. As a result of the specific interactions with 2,3-diphosphoglycerate, the ...

427

Two-step template-free route for synthesis of TiO2 hollow spheres

The theory of ..cap alpha.. decay in first-order perturbation theory is presented. The theory is designed for a strongly deformed nucleus in an isomeric state which changes its deformation dynamically through decay from a very deformed to an almost spherical shape. It is shown that other channels are not coupled to the ..cap alpha.. channel in first-order perturbation theory. The collective degrees of freedom of the daughter nucleus are described by shape vibrational states, eigenstates of a Hamiltonian whose potential has two minima. The parent nucleus is described by dynamically coupling the vibrational degrees of freedom to the ..cap alpha..-particle motion and also taking rotations into account. The ..cap alpha.. particle is taken to be a point-like particle. The theory is applied to the ..cap alpha.. decay of the isomeric state of /sub 95//sup 242/Am.

1984-10-01

428

British Library Electronic Table of Contents (United Kingdom)

The TiO2 hollow microspheres were prepared by microwave-assisted solvothermal treatment without template. The morphology and the phase of TiO2 hollow microspheres were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), high resolution transmission electron microscopy (HR-TEM), and BET surface areas. The results show that the particles have hollow structures and the shell was covered by nanocrystals and have higher specific surface area. The possible formation mechanism of hollow TiO2 spherical structures has simply been proposed. The activity was evaluated by the photocatalytic degradation of methyl orange (MO). The results show that the particles having specific surface area show higher photocatalytic activity. It can be attribute to the doped ...

2011-01-01

429

Time-dependent fluid flow and heat transfer around a circular heated cylinder embedded in a horizontal packed bed of spheres

The level schemes of the near "4"8Ca nuclei in the frame of the pure shell model

The present study numerically investigates the enhancement of forced convective heat transfer from a single circular cylinder embedded in a packed bed of spherical particles confined by two impermeable parallel plates. The heat transfer results from the heated cylinder, with and without the presence of a porous medium, are compared. The results show that the presence of the porous particles enhances the heat transfer from the cylinder; however, the significant heat transfer augmentation is produced at high Re due to the effect of thermal dispersion. In addition, the effect of Re on Nut is much greater than that of kr and Bi in the porous channel. It is also found that the %?p is much higher than %HTE producing from packing the empty channel.

2010-05-01

430

Study of the method to improve the corrosion resistance of the matrix materials of spherical fuel elements in HTGR

The energy level schemes of the near "4"8Ca nuclei were investigated in the frame of the spherical shell model with pure configurations. For every nucleus two configurations were considered: the ground state configuration (GS) - calculated making use of empirical two-body interactions extracted from the level energies of the neighbouring nuclei, and the lowest energy configuration with one nucleon in the excited state (ES) - calculated making use of the two-body Kuo-Brown interactions. The results made it possible to explain the greater part of the so-called intruder levels. Comparison of the calculated and experimental level energy values epsilonsub(J)sup(calc)-epsilonsub(J)sup(exp) reveals systematic deviations of the experimental level energies from the shell model predictions. (orig.).

1986-01-01

431

Startup of the experimental physics industrial control system at NSTX

Ceramic fuel element is one of the most important items of HTGR technology, and the corrosion resistance of is matrix materials is vital to the operational performance of HTGR. In the paper, based on the oxidation study of the matrix materials, it has been proposed that the corrosion resistance of the matrix materials might be improved through forming carbon -ceramic composite. The experiment results have shown that the corrosion resistance of matrix materials has been improved by addition of SiC superfine powders, and that the matrix materials containing SiC superfine powders and heat-treated at 1600 deg. C had an oxidation rate lower than the general one containing no SiC superfine powder and heat-treated at 1950 deg. C. (author). 5 refs, 8 figs.

1995-01-01

432

Some features of the atomic radial-distribution functions of metal glasses

The Experimental Physics Industrial Control System (EPICS) is a set of software which is being used as the basis of the National Spherical Torus Experiment's (NSTX) Process Control System, a major element of the NSTX's Central Instrumentation and Control System. EPICS is a result of a co-development effort started by several US Department of Energy National Laboratories. EPICS is actively supported through an international collaboration made up of government and industrial users. EPICS' good points include portability, scalability, and extensibility. A drawback for small experiments is that a wide range of software skills are necessary to get the software tools running for the process engineers. The authors' experience in designing, developing, operating, and maintaining NSTX's EPICS (system) will be reviewed.

1999-12-17

433

Sliding wear of metal-ceramic systems with oscillating load

This paper attempts to explain the peculiarities of the radial-distribution function of metal glasses without involving ideas of the amorphous structure. On a computer, the radial atomic density for a spherical eutectic single crystal of the composition Fe/sub 84/C/sub 16/ of radius 15 A formed by alternating small crystals of e-Fe and Fe/sub 3/C of cubic form with the edge of the cube ca 10 A. For the sake of clarity, the diagram of such a quasisingle crystal is shown and has been given a cubic boundary. The change in the relationship between the heights of the subpeaks of the second maximum of the radial distribution function of atoms in the Fe-B glasses with a change in the concentration of boron can be explained by the change in the space group of the Fe/sub 3/B metastable boride which is formed in this system.

1986-09-01

434

The tribological behavior of SiSiC/100Cr6-, Si/sub 3/N/sub 4//100Cr6- und Al/sub 2/O/sub 3//100Cr6-pairs has been investigated with oscillating load on a spherical disc/disc tribometer. The prevailing wear mechanism of the Si ceramics is tribooxidation, which leads to the formation of a SiO/sub 2/ protective layer with a reduction in friction and wear. With frequencies >1 kHz, this effect increases, resulting in low friction coefficients and wear rates. The prevailing mechanism of the oxid ceramic is surface fatigue. The hard wear particles produce severe abrasive wear. This effect is intensified with higher frequencies.

1989-05-01

435

Shape of tachyons

Self-inhibited rate in gas-solid noncatalytic reactions. The shrinking core model

We study some aspects of the experimental behaviour of tachyons, in particular by finding out their <> shape. A Superluminal particle, which in its own rest frame is spherical or ellipsoidal (and with an infinite lifetime), would <> to a laboratory frame as occupying the whole region of space bound by a double cone and a two sheeted hyperboloid. Such a structure (the tachyon <>) rigidly travels with the speed of the tachyon. However, if the Superluminal particle has a finite lifetime in its rest frame, then in the laboratory frame it gets a finite space extension. As a by-product, we are able to interpret physically the imaginary units entering - as is well known - the transverse co-ordinates in the Superluminal Lorentz transformations. The various particular or limiting cases of the tachyon shape are thoroughly considered. Finally, some brief considerations concerning possible experiments to look for ...

1982-10-21

436

SUCCESSES AND EMERGING ISSUES IN SIMULATING THE MIXING BEHAVIOR OF LIQUID-PARTICLE NUCLEAR WASTE SLURRIES AT THE SAVANNAH RIVER SITE - 211B

The shrinking core model is examined for gas-solid noncatalytic reactions with a self-inhibited rate form and it is shown that multiple reaction pathways are possible for solid particles reacted under identical conditions. The observed reaction rate can have up to two discontinuities (jumps) during reaction for particles of spherical and cylindrical shape. The geometric instability analysis reveals that the reaction interface is stable under a very limited set of conditions only for solid particles of slab geometry. For a sphere or cylinder at large Biot numbers the reaction interface is always potentially unstable. This model provides a plausible explanation for gas-solid reactions which exhibit erratic shrinking core behavior.

1984-02-01

437

Radiochemical investigations of nuclear properties. Progress report, October 1, 1976--September 30, 1977

Aqueous radioactive high-level waste slurries are combined during processing steps that ultimately produce a stable borosilicate glass waste form. Chemically treated waste slurries are combined with each other and with glass frit-water slurries to produce the melter feed. Understanding the evolution of the rheological properties of the slurries is an important aspect of removing and treating the stored waste. To a first approximation, combinations of colloidal waste slurry with {approx}0.1-mm mean diameter glass frit or glass beads act in an analogous matter to slurries of spherical beads in Newtonian liquids. The non-Newtonian rheological properties of the waste slurries without frit, however, add complexity to the hydrodynamic analysis. The use of shear rate dependent apparent viscosities with the modified Einstein equation was used to model the rheological properties of aqueous frit-waste slurries.

2009-09-02

438

Polysomaty analysis in diploid and tetraploid Portulaca grandiflora.

Progress in experimental investigations of high spin excitations in spherical and transitional nuclei in the A = 180 to 204 mass range is described. Most of the experiments were performed by in-beam #gamma#-ray spectroscopy using beams of "3He, "4He, and "1"2C ions from the Michigan State University cyclotron. The main results of studies of the nuclei "1"9"5 "1"9"7 "1"9"9 "2"0"1 "2"0"2 "2"0"3Pb, "1"9"6 "1"9"7 "1"9"9 "2"0"0Hg and "1"8"6 "1"8"7 "1"8"8 "1"8"9Pt are summarized.

439

Perturbations of Schwarzschild Black Holes in Chern-Simons Modified Gravity

Polysomaty analysis of the succulent portulaca (Portulaca grandiflora Hook.) plant was carried out using flow cytometry. For both diploid and tetraploid plants, mature leaf tissue was found to have a higher level of polysomaty than young leaf tissue. Mesophyll (MP), bundle sheath (BSP) and water storage protoplasts (WSP) were isolated from leaf tissues of diploid portulaca plants. WSP had a higher degree of endopolyploidization than MP and BSP. The ploidy distribution was also variable in different floral organs. Tetraploid plants artificially induced by colchicine treatment showed a decline in the degree of polysomaty compared to diploid plants. Tetraploid plants had more spherical leaves, a larger number of petals and lower pollen fertility than diploid plants. PMID:10936528

2000-07-28

440

Perturbation theory including topological degrees of freedom Yang-Mills theory in three Euclidean dimensions

We study perturbations of a Schwarzschild black hole in Chern-Simons modified gravity. We begin by showing that Birkhoff's theorem holds for a wide family of Chern-Simons coupling functions, a scalar field present in the theory that controls the strength of the Chern-Simons correction to the Einstein-Hilbert action. After decomposing the perturbations in spherical harmonics, we study the linearized modified field equations and find that axial and polar modes are coupled, in contrast to general relativity. The divergence of the modified equations leads to the Pontryagin constraint, which forces the vanishing of the Cunningham-Price-Moncrief master function associated with axial modes. We analyze the structure of these equations and find that the appearance of the Pontryagin constraint yields an overconstrained system that does not allow for generic black hole oscillations. We illustrate this situation by studying the case characterized by a canonical choice of the ...

2007-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

441

On 15-component theory of a charged spin-1 particle with polarizability in Coulomb and Dirac monopole fields

A method for systematically including topological degrees of freedom in perturbation theory is developed. This is not bound by the restrictions of semi-classical techniques. The Yang-Mills theory in three Euclidean dimensions is considered here. A well-defined separation of the topological and the ``spin wave'' degrees of freedom is obtained, motivated by a singular gauge. This has ``photons'' distorting the spherically symmetric magnetic fields of Dirac monopoles, and massless charged vector bosons ``W'' scattering off the latter. It is explicitly shown that the Dirac string does not contribute. The mode of the charged vector bosons with total angular momentum J=0 provides precisely the core to give a finite energy to the monopole. The radial equation for W is remarkably simplified and only two polarization states survive exactly for the anomalous magnetic moment required by the Yang-Mills interaction.

2003-01-01

442

New starches: Physicochemical properties of sweetsop (Annona squamosa) and soursop (Anonna muricata) starches

The problem of a spin 1 charged particle with electromagnetic polarizability, obeying a generalized 15-component quantum mechanical equation, is investigated in presence of the external Coulomb potential. With the use of the Wigner's functions techniques, separation of variables in the spherical tetrad basis is done and the 15-component radial system is given. It is shown that there exists a class of quantum states for which the additional characteristics, polarizability, does not manifest itself anyhow; at this the energy spectrum of the system coincides with the known spectrum of the scalar particle. For j=0 states, a 2-order differential equation is derived, it contains an additional potential term 1/r^{4}. In analogous approach wave functions the generalized particle are examined in presence of external Dirac monopole field. It is shown that there exists one special state with minimal conserved quantum number j_{min}. It this solution, first, the polarizability ...

2006-01-01

443

British Library Electronic Table of Contents (United Kingdom)

Starch from the fruits of sweetsop (Anonna squamosa) and soursop (Anonna muricata) were isolated and purified and the fat, ash, phosphorus and protein contents measured. The amount of amylose present was determined spectrophotometrically and found to be very similar (19%) for both starches. Scanning electron microscopy showed very small indented and spherical granules from both with an average granule size of 4.84mm and 4.72mm, respectively. The physicochemical properties, namely the swelling power, solubility, pasting characteristics, paste clarity and freeze-thaw stability were studied to assess the functionality of the starch pastes as hydrocolloids. The sweetsop starch showed higher swelling power and solubility compared to soursop starch and had a lower gelatinization temperature indi...

2009-01-01

444

Neutron physical investigations on the shutdown effect of small boronated absorbing spheres for pebble-bed high-temperature gas-cooled reactors

Nanowires of silicon carbide and 3D SiC/C nanocomposites with inverse opal structure

An emergency shutdown system for high-temperature gas-cooled pebble-bed reactors is proposed in addition to the common absorber rod shutdown system. This system is based on the strongly absorbing effect of small boronated graphite spheres (called KLAK), which trickle in case of emergency by gravity from the top reflector into the reactor core. The inner reflector of the Siemens-Argonaut reactor was substituted by an assembly of spherical Arbeitsgemeinschaft Versuchsreaktor fuel elements, and the shutdown effect was examined by installing well-defined KLAK nests inside this assembly. The purpose was to develop and prove a calculational procedure for determining criticality values for assemblies of large fuel spheres and small absorbing spheres.

1987-09-01

445

Modeling of ablation by photospallation using the computer program PUFF/DFRACT

Synthesis, morphology, structural and optical characteristics of SiC NWs and SiC/C nanocomposites with an inverse opal lattice have been investigated. The samples were prepared by carbothermal reduction of silica (SiC NWs) and by thermo-chemical treatment of opal matrices (SiC/C) filled with carbon compounds which was followed by silicon dioxide dissolution. It was shown that the nucleation of SiC NWs occurs at the surface of carbon fibers felt. It was observed three preferred growth direction of the NWs: [111], [110] and [112]. HRTEM studies revealed the mechanism of the wires growth direction change. SiC/C- HRTEM revealed in the structure of the composites, except for silicon carbide, graphite and amorphous carbon, spherical carbon particles containing concentric graphite shells (onion-like particles).

2011-07-07

446

Microemulsion-mediated synthesis of cobalt (pure fcc and hexagonal phases) and cobalt-nickel alloy nanoparticles

In general, macroscopic material failure is a manifestation of irreversible changes at the microscopic level. Many tissues, which may appear to be macroscopically homogeneous, are, at a fundamental microscopic level, a composite material. For example, cornea is composed of a hyaluronic acid matrix in which layers of collagen fibers are overlaid in a crossing pattern. The points where the collagen fibers intersect are potential nucleation sites for microscopic defects, which under the action of tensile stress, nucleate, grow and coalesce to form macroscopic failure planes, or spall planes. Using a model based on microstructural evolution, this paper examines the failure process during photoablation. Specifically, the paper describes a physically motivated, micromechanical model based on the nucleation and growth of spherical voids. This model is then used to simulate photoablation of cornea. Potential for using this model to predict the stress wave and material ...

1995-03-01

447

British Library Electronic Table of Contents (United Kingdom)

By choosing appropriate microemulsion systems, hexagonal cobalt (Co) and cobalt-nickel (1:1) alloy nanoparticles have been obtained with cetyltrimethylammonium bromide as a cationic surfactant at 500degreeC. This method thus stabilizes the hcp cobalt even at sizes (<10nm) at which normally fcc cobalt is predicted to be stable. On annealing the hcp cobalt nanoparticles in H2 at 700degreeC we could transform them to fcc cobalt nanoparticles. Microscopy studies show the formation of spherical nanoparticles of hexagonal and cubic forms of cobalt and Co-Ni (1:1) alloy nanoparticles with the average size of 4, 8 and 20nm, respectively. Electrochemical studies show that the catalytic property towards oxygen evolution is dependent on the applied voltage. At low voltage (less than 0.65V) the Co (he...

2009-01-01

448

Mechanism of filler action in reducing the wear of PTFE polymer by differential scanning calorimetry

British Library Electronic Table of Contents (United Kingdom)

Two types of representative nanometer materials, i.e., fibroid nanometer attapulgite and approximate spherical ultrafine diamond, were selected as fillers of polytetrafluoroethylene (PTFE) to study the mechanism of the wear-reducing actions of the fillers in PTFE composites. The friction and wear tests were performed on a block-on-ring wear tester under dry sliding conditions. Differential scanning calorimetry (DSC) was used to investigate material microstructure and to examine modes of failure. No significant change in coefficient of friction was found, but the wear rate of PTFE composites was orders of magnitude less than that of pure PTFE. DSC analysis revealed that nanometer attapulgite and ultrafine diamond played a heterogeneous nucleation role in PTFE matrix and consequently resulte...

2007-01-01

449

Measurement of dose distributions of linear energy transfer in matter irradiated by fast neutrons

MODELING AN ION EXCHANGE PROCESS FOR CESIUM REMOVAL FROM ALKALINE RADIOACTIVE WASTE SOLUTIONS

A detector has been developed and used to measure dose distributions versus linear energy transfer to thin gas targets in spherical geometry from fast neutron irradiation of tissue-equivalent plastic and carbon. The detector is a hemispherical proportional counter with a Cs(T1) scintillator at the center of the hemisphere. The coincidence of the proportional counter signals constrain the measurements to charged particles traversing the radius of the hemisphere. The charged particle energy deposition distributions are directly measured for a known pathlength. The A-150 kerma factor was measured at a neutron energy of 14.8 MeV and is in agreement with tabulated values. The carbon kerma factor measurements are less than the tabulated value at 14.8 MeV. The alpha-particle production in carbon was measured for neutron energies from 14.1 to 14.8 MeV and is compared with existing data.

1990-01-01

450

MAGIC Telescope observations of high energy gamma-rays from globular cluster M13

The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.

2008-08-26

451

Liquid crystal films on curved surfaces: An entropic sampling study

Globular clusters are quite compact (size {proportional_to}10 pc) objects distributed spherically around the galaxy. They contain about 10{sup 5}-10{sup 6} mostly old stars. The number of millisecond pulsars in typical globular cluster is expected to be large (of the order of 100). We investigate the possible mechanism of production of high energy gamma-rays in those objects. Part of the wind energy of pulsars (energy conversion factor) is converted into relativistic leptons. Those leptons can upscatter in inverse Compton process low energy starlight and CMB photons and produce gamma-rays. MAGIC is an Imaging Atmospheric Cerenkov Telescopes located at Canary island of La Palma. We present results and discussion of the MAGIC observations of globular cluster M13.

2008-07-01

452

Instabilities in Focused Ion Beam-patterned Au nanowires

The confining effect of a spherical substrate inducing anchoring (normal to the surface) of rod-like liquid crystal molecules contained in a thin film spread over it has been investigated with regard to possible changes in the nature of the isotropic-to-nematic phase transition as the sample is cooled. The focus of these Monte Carlo simulations is to study the competing effects of the homeotropic anchoring due to the surface inducing orientational ordering in the radial direction and the inherent uniaxial order promoted by the intermolecular interactions. By adopting entropic sampling procedure, we could investigate this transition with a high temperature precision, and we studied the effect of the surface anchoring strength on the phase diagram for a specifically chosen geometry. We find that there is a threshold anchoring strength of the surface below which uniaxial nematic phase results, and above which the isotropic fluid cools to a radially ordered nematic ...

2010-01-01

453

British Library Electronic Table of Contents (United Kingdom)

Focused Ion Beam (FIB) technology has become an indispensable enabling tool for micro nano fabrications. One important application is to use FIB for patterning conducting nanowires of metals down to a few tens of nanometre for applications such as interconnects, heaters and temperature nanosensors. A series of experiments on Au nanowires fabricated by FIB on SixNy membrane show that nanowires with width 50nm have structural instabilities. These are liquid like and first show-up as undulations in nanowire width with clearly defined wave lengths. For smaller widths (20nm) the instabilities grow and the wires eventually break-up into spherical balls. Further experiments show that the nanowires can be made stable to smaller widths by the use of a Cr underlayer to enhance surface wetting. The o...

2011-01-01

454

High-energy x-ray microscopy techniques for laser-fusion plasma research at the National Ignition Facility

Generalised rotationally invariant core (RIC) model: a two mass-point approach

Multi-kilo-electron-volt x-ray microscopy will be an important laser-produced plasma diagnostic at future megajoule facilities such as the National Ignition Facility (NIF). However, laser energies and plasma characteristics imply that x-ray microscopy will be more challenging at NIF than at existing facilities. We use analytical estimates and numerical ray tracing to investigate several instrumentation options in detail, and we conclude that near-normal-incidence single spherical or toroidal crystals may offer the best general solution for high-energy x-ray microscopy at NIF and similar large facilities. Apertured Kirkpatrick{endash}Baez microscopes using multilayer mirrors may also be good options, particularly for applications requiring one-dimensional imaging over narrow fields of view. {copyright} 1998 Optical Society of America

1998-04-01

455

Forward on the N=Z line with GASP

A generalised RIC model for the rotational - vibrational spectra of deformed even-even nuclei of ellipsoidal shape in the rare-earth region has been proposed by incorporating many important features of various microscopic models proposed earlier. The two mass-point model and the governor model moments of intertia are obtained on the basis of the proposed model with appropriate limiting values of the radius of the RIC. Also, the model moment of intertia goes to zero for spherical nuclei, thus giving no rotational spectra for such nuclei. A quantum mechanical treatment of the model on the basis of the two mass-point concept, is expected to give results which are in better agreement with experiments. (author).

456

Forward on the N=Z line with GASP

The experimental study of the proton-rich nuclei close to the N=Z line is a constant challenge for nuclear spectroscopy, mainly due to the difficulty to produce them with the currently available beam/target combinations. Significant advances on this direction were obtained from experiments performed with the GASP array during the last two years: the yrast line of {sup 84}Mo was extended up to 10{sup +}, {sup 88}Ru observed for the first time, and the N=Z+1 line was mapped from {sup 81}Zr to {sup 95}Ag. These new results allow us to have a more complete image of the transition from the well-deformed shell closure at N,Z=40 to the spherical-shell closure at N,Z=50, and highlights some particular effects that can be observed only in the vicinity of the N=Z line. (orig.)

2004-04-01

457

Fabrication and characterization of low aberration micrometer-sized electron lenses

The experimental study of the proton-rich nuclei close to the N=Z line is a constant challenge for nuclear spectroscopy, mainly due to the difficulty to produce them with the currently available beam/target combinations. Significant advances on this direction were obtained from experiments performed with the GASP array during the last two years: the yrast line of "8"4Mo was extended up to 10"+, "8"8Ru observed for the first time, and the N=Z+1 line was mapped from "8"1Zr to "9"5Ag. These new results allow us to have a more complete image of the transition from the well-deformed shell closure at N,Z=40 to the spherical-shell closure at N,Z=50, and highlights some particular effects that can be observed only in the vicinity of the N=Z line. (orig.)

2004-04-01

458

British Library Electronic Table of Contents (United Kingdom)

Intrinsic spherical aberrations of electron lenses have been the major resolution limiting factor in electron microscopes for several decades. While effective correctors have recently been implemented, an alternative to correct these aberrations is to circumvent them by scaling down lens dimensions by several orders of magnitude. We have fabricated electrostatic lenses exhibiting one micrometer diameter apertures and evaluated their beam forming properties against predictions from numerical ray tracing simulations. It turns out that it is routinely possible to shape a paraxial low-energy electron beam by such micron-sized lenses. Beam profiles have been measured both at a distant detector as well as in a plane close to the lens. It is shown that the lens can form a parallel beam extending ...

2010-01-01

459

Electrochemical method for the synthesis of silver nanoparticles

Double peak effect in microdosimetric proportional counters and its interpretation

The article deals with a novel electrochemical method of preparing long-lived silver nanoparticles suspended in aqueous solution as well as silver powders. The method does not involve the use of any chemical stabilising agents. The morphology of the silver nanoparticles obtained was studied using transmission electron microscopy, scanning electron microscopy, atomic force microscopy and dynamic light scattering measurements. Silver nanoparticles suspended in water solution that were produced by the present technique are nearly spherical and their size distribution lies in the range of 2 to 20 nm, the average size being about 7 nm. Silver nanoparticles synthesised by the proposed method were sufficiently stable for more than 7 years even under ambient conditions. Silver crystal growth on the surface of the cathode in the electrochemical process used was shown to result in micron-sized structures consisting of agglomerated silver nanoparticles with the sizes below 40 ...

2009-07-15

460

Asymptotic Safety, Asymptotic Darkness, and the hoop conjecture in the extreme UV

In calibration measurements with low energy X-rays, a double peak effect appears in low pressure proportional counters with a helix, when used for simulation of tissue equivalent diameters considerably larger than 2 m. An interpretation of this phenomenon is discussed, based upon electron capture and electric field perturbation at the counter helix. A description of the physical processes is presented showing that the double peak effect is a problem in the case of helix counters (called also Rossi counters) for all simulated diameters. Conclusions are drawn on systematic errors introduced by the counter helix into microdosimetric spectra and anti y/sub D/ of photons and neutrons. The authors recommend to use cylindrical counters with optimized geometrical and electronic parameters rather than the spherical counters with a helix discussed.

1989-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

461

Approximate solutions to the Stefan problem with internal heat generation

Assuming the hoop conjecture in classical general relativity and quantum mechanics, any observer who attempts to perform an experiment in an arbitrarily small region will be stymied by the formation of a black hole within the spatial domain of the experiment. This behavior is often invoked in arguments for a fundamental minimum length. Extending a proof of the hoop conjecture for spherical symmetry to include higher curvature terms we investigate this minimum length argument when the gravitational couplings run with energy in the manner predicted by asymptotically safe gravity. We show that argument for the mandatory formation of a black hole within the domain of an experiment fails. Neither is there a proof that a black hole doesn't form. Instead, whether or not an observer can perform measurements in arbitrarily small regions depends on the specific numerical values of the couplings near the UV fixed point. We further argue that when an experiment is localized on ...

2010-01-01

462

Acoustic resonances in two-dimensional radial sonic crystal shells

Using a quasi-static approach valid for Stefan numbers less than one, we derive approximate equations governing the movement of a phase change front for materials which generate internal heat. These models are applied for both constant surface temperature and constant surface heat flux boundary conditions, in cylindrical, spherical, plane wall and semi-infinite geometries. Exact solutions with the constant surface temperature condition are obtained for the steady-state solidification thickness using the cylinder, sphere, and plane wall geometries which show that the thickness depends on the inverse square root of the internal heat generation. Under constant surface heat flux conditions, closed form equations can be obtained for the three geometries. In the case of the semi-infinite wall, we show that for constant temperature and constant heat flux out of the wall conditions, the solidification layer grows then remelts. (orig.)

2008-05-15

463

A simple model for predicting the flux distribution through the focal plane of a multifaceted concentrator solar furnace

Radial sonic crystals (RSC) are fluidlike structures infinitely periodic along the radial direction that verify the Bloch theorem and are possible only if certain specially designed acoustic metamaterials with mass density anisotropy can be engineered (see Torrent and Sanchez-Dehesa 2009 Phys. Rev. Lett. 103 064301). A comprehensive analysis of two-dimensional (2D) RSC shells is reported here. A given shell is in fact a circular slab with a central cavity. These finite crystal structures contain Fabry-Perot-like resonances and modes strongly localized at the central cavity. Semi-analytical expressions are developed to obtain the quality factors of the different resonances, their symmetry features and their excitation properties. The results reported here are completely general and can be extended to equivalent 3D spherical shells and to their photonic counterparts.

2010-07-15

464

Dynamic {sup 31}P-MR-spectroscopy of the quadriceps muscle. Influence of sex and age on spectroscopic results; Die dynamische 31-Phosphor-Magnetresonanz-Spektroskopie des M. quadriceps. Einfluss von Geschlecht und Alter auf spektroskopische Parameter

The authors describe a small doubly reflecting research furnace. Its optical components, a heliostat and a concentrating array of hexagonal-in-plan-form mirrors, focus sunlight at the aperture of a cavity receiver. A perfect paraboloid of revolution would have given higher concentration ratios. But large paraboloids are difficult to make and manipulate. Small hexagons are convenient and can be close packed. Spherical mirrors centered on a sphere simplified construction and were economical. In this note they use a simple model to describe the radial distribution of the normal flux at the focus of such an array. A schematic representation of a cross section of the concentrator mirror array in a plane which includes its axis is shown.

1984-02-01

465

{sup 3}H-tetracycline as a proxy for {sup 41}Ca for measuring dietary perturbations of bone resorption

Purpose: {sup 31}P-MRS is used to assess the influence of sex and age on quadriceps muscle metabolism before and after exercise. Materials and Methods: 32 healthy volunteers (15 women, 17 men; mean age: 38{+-}17 yrs.) were examined by dynamic phosphorus-31 ({sup 31}P) magnetic resonance spectroscopy (MRS). In the magnet, the quadriceps muscle was stressed by an isometric and an isotonic form of exercise until exhaustion, respectively. Results: Resting conditions: With increasing subjects` age, the ratio {beta}-adenosine triphosphate/total phosphate decreased (r=-0.37; p=0.02). With increasing subjects` age, the ratios inorganic phosphate/phosphocreatine (r=0.79; p=5x10{sup -8}), phosphomonoester/{beta}-adenosine triphosphate (r=0.74; p=10{sup -6}) and phosphodiester/{beta}-adenosine triphosphate (r=0.62; p=10{sup -4}) increased. The pH was the only one of the evaluated spectroscopic parameters which showed a sex-dependence: Female subjects had ...

1999-05-01

466

The use of calcium silicate bricks for retrospective dosimetry

Our group is interested in evaluating early effects of dietary interventions on bone loss. Postmenopausal women lose bone following reduction in estrogen which leads to increased risk of fracture. Traditional means of monitoring bone loss and effectiveness of treatments include changes in bone density, which takes 6 months to years to observe effects, and changes in biochemical markers of bone turnover, which are highly variable and lack specificity. Prelabeling bone with {sup 41}Ca and measuring urinary {sup 41}Ca excretion with accelerator mass spectrometry provides a sensitive, specific, and rapid approach to evaluating effectiveness of treatment. To better understand {sup 41}Ca technology as a tool for measuring effective treatments on reducing bone resorption, we perturbed bone resorption by manipulating dietary calcium in rats. We used {sup 3}H-tetracycline ({sup 3}H-TC) as a proxy for {sup 41}Ca and found that a single dose is feasible to study bone ...

2007-06-15

467

Production of hydrogen by radiolysis

The suitability of calcium silicate bricks (CSBs) for the retrospective measurement of gamma dose using luminescence techniques has been investigated. Bricks of this type are distinguished from fired clay bricks by containing negligible clay and requiring comparatively low temperature treatment during manufacture. They have been used widely in the construction f buildings in the Former Soviet Union since the 1970s but hitherto have not been used for retrospective dosimetry measurements. A procedure based on the se of the 210 deg. C thermoluminescence (TL) peak of quartz was tested with granular quartz extracted from three types of CSB, one of which had been taken from a settlement downwind of Chernobyl. The degree to which the residual geological TL signal within the temperature range of the 210 deg. C L peak had been reduced during manufacture varied with brick type; the levels of residual TL corresponded, in the samples tested, to absorbed doses n the range ...

2004-02-01

468

Macroscopic consequences of calcium signaling in microdomains: A first passage time approach

The possibility of obtaining high yields of hydrogen through the exposure of calcium hydroxide to natural uranium fission fragments is confirmed experimentally. The amounts of hydrogen obtained in some experiments were determined not only from the mass-spectrometry data, but also with the use of standard chemical analysis methods. The radiolytic hydrogen yield averaged over six independent experiments comprises 20.41 hydrogen molecules per 100 eV of absorbed fission fragment energy. The corresponding energy efficiency makes up to 60.62. Since on interaction with water or water vapor calcium hydroxide enters into the exothermal reaction to liberate 15.6 kcal/mole, it can easily be regenerated; this was attested to by one of irradiation experiments. Therefore, in the long run, we are dealing with a radiolytic decomposition of water at low temperatures or at temperatures readily available with modern reactor engineering techniques. Comparison of ...

1998-07-01

469

Lead and calcium distributions in blood, plasma, and milk of the lactating mouse

Calcium (Ca) plays an important role in regulating various cellular processes. In a variety of cell types, Ca signaling occurs within microdomains where channels deliver localized pulses of Ca which activate a nearby collection of Ca-sensitive receptors. The small number of channels involved ensures that the signaling process is stochastic. The aggregate response of several thousand of these microdomains yields a whole-cell response which dictates the cell behavior. Here, we study analytically the statistical properties of a population of these microdomains in response to a trigger signal. We apply these results to understand the relationship between Ca influx and Ca release in cardiac cells. In this context, we use a first passage time approach to show analytically how Ca release in the whole cell depends on the single channel kinetics of Ca channels and the properties of microdomains. Using these results, we explain the underlying mechanism for the graded ...

2007-01-01

470

Development and performance of a miniature, high-voltage thermal battery

Although it has been established that lead is transferred in milk from mother to suckling offspring, the physiological processes and parameters involved are not well understood. Single i.v. doses (0.2 mg/kg) or p.o. doses (2 mg/kg) of radiolabeled lead were administered to lactating and nonlactating female mice, and lead concentrations in blood, plasma, and milk were determined during a 21-day period. Large differences in lead elimination were observed between lactating and nonlactation mice. A significant fraction (25%) of the initial maternal dose (absorbed dose) was transferred to the suckling pups. The ratio of lead concentration in milk to lead concentration in plasma was found to be nearly constant over time. However, the milk-to-blood concentration ratios decreased during the same period. Furthermore, the concentration of lead in milk exceeded the plasma concentration by a factor of approximately 25, indicating that there is a physiological process(es) which establishes a large ...

1980-01-01

471

Comparison of intrinsic and extrinsic tracer methods for estimating calcium bioavailability to rats from dairy foods

A miniature, high-voltage, thermally activated battery has been developed. This battery weighs 41 grams, occupies a volume of 16.4 cu cm, and contains two separate 500-v channels, each designed to charge a 5.25 microfarad capacitor within 300 milli-seconds and remain operational under a 640-kohm load for a minimum of 28 seconds over the temperature range from +16 to +71 C. The electrochemical system utilizes a calcium anode, LiCl-KCl molten salt electrolyte, a CaCrO4-K2CrO4 mixture as the depolarizer or active cathode material, and an iron cathode. The depolarizer and electrolyte, along with a silica binder, are formed into homogeneous pellets, and these pellets are stacked alternately with calcium-iron bimetal disks in beryllium oxide tubes to form cell stacks. The cells are activated by an iron-potassium perchlorate pyrotechnic heat source external to the BeO tubes.

1974-01-01

472

Analysis of lagoon sludge characteristics for choice of treatment process

Dairy products doubly labeled with 45Ca and 47Ca were used to evaluate an extrinsic labeling procedure for calcium bioavailability determination. Nonfat milk, yogurt, and fresh cheese curd were prepared from caprine milk that was intrinsically labeled with 45Ca. The products were then labeled extrinsically with 47Ca and administered to rats by gavage. The 47Ca to 45Ca ratio in bone and teeth averaged about 1.00 with either milk, yogurt, or CaCl2, but the ratio was about 1.04 when dosed with cheese curd. Ca absorption, determined by whole-body counting of 47Ca, was lower (P less than 0.05) in cheese curd (59%) than in either milk (69%), yogurt (72%), or CaCl2 (72%). Expressed as percent of dose, the absorption of 47Ca was highly correlated with bone 47Ca (r = 0.973) and with bone 45Ca (r = 0.946). Correlation between tibia 47Ca and tibia 45Ca was r = 0.923. For the dairy products tested, our results indicated that extrinsic 47Ca was absorbed similarly to intrinsic ...

473

A prospective randomised open label study to evaluate the potential of a new silver alginate/carboxymethylcellulose antimicrobial wound dressing to promote wound healing.

The Korea Atomic Energy Research Institute has launched a decommissioning program of uranium conversion plant. One of the important tasks in the decommissioning program is the treatment of the sludge, which was generated during operation and stored in the two ponds of the lagoon. The treatment requires the volume reduction of lagoon sludges for the low cost of the program and the conversion of the chemical forms, including uranium, for the acceptance at the final disposal site. The physical properties, such as densities, were measured and chemical compositions and radiological properties were analyzed. The denitration was a candidate process which would satisfy the requirements for sludge treatment, and the characteristics of thermal decomposition and dissolution with water were analyzed. The main compounds of the sludge were ammonium and sodium nitrate from conversion plant and calcium nitrate, calcium carbonate from Ca precipitation and ...

2002-04-01

474

Use of X-ray fluorescence analysis in the study of archeological samples

The aim of this study was to observe both the clinical signs and symptoms of wounds at risk of infection, that is critically colonised (biofilm infected) and antimicrobial-performance of an ionic silver alginate/carboxymethylcellulose (SACMC) dressing, in comparison with a non silver calcium alginate fibre (AF) dressing, on chronic venous leg and pressure ulcers. Thirty-six patients with venous or pressure ulcers, considered clinically to be critically colonised (biofilm infected), were randomly chosen to receive either an SACMC dressing or a non silver calcium AF dressing. The efficacy of each wound dressing was evaluated over a 4-week period. The primary study endpoints were prevention of infection and progression to wound healing. The SACMC group showed a statistically significant (P = 0.017) improvement to healing as indicated by a reduction in the surface area of the wound, over the 4-week study period, compared with AF controls. In ...

2010-05-31

475

Radiostrontium in milk and tap water. Appendix D

Radionuclide X-ray fluorescence analysis (XFA) was used in the determination of the contents of metal residues in dosing plates for coin minting. XFA was also used for the determination of the strontium/calcium ratio in bone samples of different animals with the aim to obtain information on the food composition of these animals. It was found that bones of different animals can be distinguished based on the Sr/Ca ratio. No significant differences in the Sr/Ca ratio were observed in human bones of individuals from different social groups. (author). 1 fig., 5 tabs., 4 refs.

1988-09-26

476

Pitting corrosion of steel pipeline in oil-water-gas multiphase flow system

Results of monitoring milk and tap water in New York City are presented. The New York City sample is a monthly composite of pasteurized milk purchased daily at retail stores. The monthly "9"0Sr to calcium ratios for New York City since the inception of the sampling program in 1954 are presented. Samples of New York City tap water are taken daily, so that by the end of the month, approximately 100 liters have been collected. The available cesium-137 data expressed as the "1"3"7Cs to "9"0Sr ratio are also given.

1980-01-01

477

Severe pitting corrosion occurred in a horizontal steel pipeline used to transport multiphase fluid, including water, oil, and natural gas, after 2 months of service. The pitting corrosion rate was up to 42 mm/year. Chemical analysis, X-ray diffractometry, and EDAX showed that the corrosion products mainly consisted of Fe9S8, FeCO3, and NaCl. Calcium containing inclusions were also found in the matrix of the steel, which may accelerate corrosion. The early failure was attributed to the high proportion of water, the slow flow velocity, and the use of unqualified material. (Author)

2000-07-01

478

Phase diagrams

New materials for SRS lasers

The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.

479

Models of cardiac electromechanics based on individual hearts imaging data

The problem of search for new materials for spectrally positioned laser sources, which is central for modern photonics, is discussed. The use of the stimulated Raman scattering effect in crystals offers a highly efficient way to the design of such sources. The recent results of investigations into this effect for a large number of various types of crystalline materials are presented. The most promising compounds, as regards the realisation of different laser operation modes, are considered, including calcium, strontium, barium and lead molybdates and tungstates. Several examples of functioning efficient lasers based on novel materials exhibiting the stimulated Raman light scattering effect are given.

2006-10-31

480

British Library Electronic Table of Contents (United Kingdom)

Current multi-scale computational models of ventricular electromechanics describe the full process of cardiac contraction on both the micro- and macro- scales including: the depolarization of cardiac cells, the release of calcium from intracellular stores, tension generation by cardiac myofilaments, and mechanical contraction of the whole heart. Such models are used to reveal basic mechanisms of cardiac contraction as well as the mechanisms of cardiac dysfunction in disease conditions. In this paper, we present a methodology to construct finite element electromechanical models of ventricular contraction with anatomically accurate ventricular geometry based on magnetic resonance and diffusion tensor magnetic resonance imaging of the heart. The electromechanical model couples detailed repres...

2011-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

481

Mineral analysis in experimental corneal scars. An EDAX study

Mechanical Properties of Carbon Nanotubes / Hydroxyapatite Composites Prepared by Spark Plasma Sintering

Central penetrating excisional wounds were made in the corneas of 12 rabbits and 10 trout. The scar tissue and the surrounding cornea were compared using a new method for assessing inorganic elements in the cornea: the scanning electron microscopy and energy dispersive analysis of x-ray (EDAX). Semiquantitative determination of inorganic elements within the range of atomic numbers 9-93 in the periodic system was performed, comparing the relative concentration of those elements in the scar tissue to the surrounding cornea. Results showed that calcium was the only element higher in the healing wound than in the surrounding cornea.

1988-01-01

482

Fundamental investigation of duct/ESP phenomena. Final report

In this study, Multi-Walled Carbon Nanotubes (MWCNTs) / Hydroxylapatite (HAp) composites were made to improve mechanical properties by using Spark Plasma Sintering (SPS) method. Slurry 6 mol of CaHPO4#centre dot#2H2O (DCPD), 4 mol calcium hydroxide and MWCNTs were mixed and sintered by using SPS at 5-120 MPa pressure, 1200-1250 deg. C and in vacuum or N2 atmosphere. The fracture toughness of sintered MWCNTs/HAp composites was increased.

2006-05-05

483

Fundamental investigation of duct/ESP phenomena

Radian Corporation was contracted to investigate duct injection and ESP phenomena in a 1.7 MW pilot plant constructed for this test program. This study was an attempt to resolve problems found in previous studies and answer remaining questions for the technology using an approach which concentrates on the fundamental mechanisms of the process. The goal of the study was to obtain a better understanding of the basic physical and chemical phenomena that control: (1) the desulfurization of flue gas by calcium-based reagent, and (2) the coupling of an existing ESP particulate collection device to the duct injection process. Process economics are being studied by others. (VC)

1991-10-21

484

Elemental concentration analysis in some plant samples by EDXRF at Trabzon

Radian Corporation was contracted to investigate duct injection and ESP phenomena in a 1.7 MW pilot plant constructed for this test program. This study was an attempt to resolve problems found in previous studies and answer remaining questions for the technology using an approach which concentrates on the fundamental mechanisms of the process. The goal of the study was to obtain a better understanding of the basic physical and chemical phenomena that control: (1) the desulfurization of flue gas by calcium-based reagent, and (2) the coupling of an existing ESP particulate collection device to the duct injection process. Process economics are being studied by others. (VC)

1991-10-21

485

CaSnO3:. a high capacity anode material for Li-ion batteries

The elemental analysis of some plant samples have been carried out in Trabzon region (Turkey) using energy-dispersive X-ray fluorescence (EDXRF) spectrometry. We have analyzed plant samples for nine stations using 1.85 GBq 55Fe radioactive sources. We have found that potassium and calcium within 0.3-1.4% and 0.3-2.8% were present in concentration in plants for every station, respectively. The concentration of Cl and Ti generally changed according to the plant species and the sampling station.

2006-12-01

486

Two Functional S100A4 Monomers Are Necessary for Regulating Nonmuscle Myosin-IIA and HCT116 Cell Invasion.

Calcium stannate (CaSnO3) powders with the distorted perovskite structure have been synthesized by solid state and the sol-gel methods and their electrochemical performance was compared. The sol-gel CaSnO3 shows stable cycling performance with a reversible capacity of 430-440 mAh/g (0.005-1.0 V; 60 mA/g) up to 50 cycles. The role of preparatory conditions, morphology and cycling conditions (current density and potential window) on the anodic performance of the compounds are addressed.

2002-12-01

487

Evaluation of calcification in pulmonary nodules using bone images obtained with single exposure energy subtraction

S100A4, a member of the Ca(2+)-activated S100 protein family, regulates the motility and invasiveness of cancer cells. Moreover, high S100A4 expression levels correlate with poor patient survival in several cancers. Although biochemical, biophysical, and structural data indicate that S100A4 is a noncovalent dimer, it is unknown if two functional S100A4 monomers are required for the productive recognition of protein targets and the promotion of cell invasion. To address this question, we created covalently linked S100A4 dimers using a glycine rich flexible linker. The single-chain S100A4 (sc-S100A4) proteins exhibited wild-type affinities for calcium and nonmuscle myosin-IIA, retained the ability to regulate nonmuscle myosin-IIA assembly, and promoted tumor cell invasion when expressed in S100A4-deficient colon carcinoma cells. Mutation of the two calcium-binding EF-hands in one monomer, while leaving the other monomer intact, caused a ...

2011-07-13

488

Evaluation of calcification in pulmonary nodules using bone images obtained with single exposure energy subtraction

Bone images obtained by single exposure dual energy subtraction with computed radiography, a new image processing method, were evaluated for the detectability of calcification in lung nodules in both phantom and clinical studies. In the phantom study, five simulated nodules containing known and uniformly distributed amounts of calcium hydroxide were placed in a human chest phantom and images were obtained the following five techniques: (1) conventional radiography (CXR), (2) low kV conventional radiography (Low), (3) Fuji computed radiography (FCR), (4) bone images with conventional singles exposure energy subtraction (ES) and (5) bone image with fine single exposure energy subtraction (FES). The detectability of calcification in the simulated nodules was evaluated by six radiologists using ROC analysis and two-way analysis of variance. In the clinical study, images of 42 lung nodules (21 calcified lung nodules and 21 non-calcified nodules), in which calcification ...

1995-08-01

489

Crystallographic data for new phases in the CaSO/sub 3/-H/sub 2/O system

Bone images obtained by single exposure dual energy subtraction with computed radiography, a new image processing method, were evaluated for the detectability of calcification in lung nodules in both phantom and clinical studies. In the phantom study, five simulated nodules containing known and uniformly distributed amounts of calcium hydroxide were placed in a human chest phantom and images were obtained the following five techniques: 1) conventional radiography (CXR), 2) low kV conventional radiography (Low), 3) Fuji computed radiography (FCR), 4) bone images with conventional singles exposure energy subtraction (ES) and 5) bone image with fine single exposure energy subtraction (FES). The detectability of calcification in the simulated nodules was evaluated by six radiologists using ROC analysis and two-way analysis of variance. In the clinical study, images of 42 lung nodules (21 calcified lung nodules and 21 non-calcified nodules), in which calcification was ...

1995-01-01

490

Biological effects of exogenous adenosine 5 prime -triphosphate on cultured mammalian cells: Evidence for a receptor mechanism and its regulation by desensitization

Among the three modifications of calcium sulfite hemihydrate, two of them, hexagonal ..beta..-CaSO/sub 3/.1/2H/sub 2/O with a rhombohedral lattice and ..gamma..-CaSO/sub 3/.1/2H/sub 2/O with a simple triangular hexagonal lattice, were found in the authors' recent work. By heating ..cap alpha..- and/or ..gamma..-hemihydrate at 330-360/sup 0/C in a nitrogen atmosphere, the orthorhombic anhydrate ..cap alpha..-CaSO/sub 3/ was formed, with lattice constants of 6.472, 15.93, and 23.44 angstrom for a, b, and c respectively, while the body-centered tetragonal anhydrate ..beta..-CaSO/sub 3/, with lattice constants of 15.68 and 19.44 angstrom for a and c respectively, was formed by heating the ..beta..-hemihydrate. The dehydration of three hemihydrates and the hydration of two anhydrates were discussed. Calcium sulfite hemihydrate (CaSO/sub 3/.1/2H/sub 2/O) is useful as an architectural material since it has a high thermal stability and a low ...

1982-03-01

491

Benchmarks and models for 1-D radiation transport in stochastic participating media

Exogenous adenosine 5{prime}-triphosphate (ATP) mobilized intracellular calcium in human carcinoma A43l cells and in Swiss 3T3 and 3T6 mouse fibroblasts by increasing inositol trisphosphate similar to well down growth factors (platelet-derived growth factor (PDGF), epidermal growth factor (EGF), bradykinin (BK), serum). Calcium mobilization was examined by video imaging of fura-2 fluorescence is single cells, following the radioactive isotope {sup 45}Ca, and monitoring the decrease in fluorescence of cells loaded with chlortetracycline. Uridine 5{prime}-triphosphate, but not other nucleotides, mimicked ATP. Single-cell analysis revealed synchronous responses in 10 sec to ATP, BK or serum, while PDGF (3T3) and EGF (A431) produced slower signals with significant cell-to-cell variation. PDGF desensitized 3T3 cells to ATP and BK added 100 sec later but ATP or BK did not desensitized to PDGF. Homologous desensitization was seen with all agonists. ...

1989-01-01

492

A novel micro-spherical CoSn{sub 2}/Sn alloy composite as high capacity anode materials for Li-ion rechargeable batteries

Benchmark calculations for radiation transport coupled to a material temperature equation in a 1-D slab and 1-D spherical geometry binary random media are presented. The mixing statistics are taken to be homogeneous Markov statistics in the 1-D slab but only approximately Markov statistics in the 1-D sphere. The material chunk sizes are described by Poisson distribution functions. The material opacities are first taken to be constant and then allowed to vary as a strong function of material temperature. Benchmark values and variances for time evolution of the ensemble average of material temperature energy density and radiation transmission are computed via a Monte Carlo type method. These benchmarks are used as a basis for comparison with three other approximate methods of solution. One of these approximate methods is simple atomic mix. The second approximate model is an adaptation of what is commonly called the Levermore-Pomraning model and which is referred to ...

2000-08-21

493

Surface modification, organometallic and polyaryl polymer coatings, and flame spray technologies for preventing corrosion of metals. Final report

Micro-scaled spherical CoSn{sub 2}/Sn alloy powders synthesized from oxides of Sn and Co via carbothermal reduction at 800 C were examined for use as anode materials in Li-ion battery. The phase composition and particle morphology of the CoSn{sub 2}/Sn alloy composite powders were investigated by XRD, SEM and TEM. The prepared CoSn{sub 2}/Sn alloy composite electrode exhibits a low initial irreversible capacity of ca. 140 mAh g{sup -1}, a high specific capacity of ca. 600 mAh g{sup -1} at constant current density of 50 mA g{sup -1}, and a good rate capability. The stable discharge capacities of 500-515 mAh g{sup -1} and the columbic efficiencies of 95.8-98.1% were obtained at current density of 500 mA g{sup -1}. The relatively large particle size of CoSn{sub 2}/Sn alloy composite powder is apparently favorable for the lowering of initial capacity loss of electrode, while the loose particle structural characteristic and the Co addition in Sn matrix should be ...

2007-04-01

494

Immobilization of tetravalent actinides in three phosphate based ceramics: britholites, TPD and monazites/brabantites

To improve adherent properties of electrogalvanized steel (EGS) to polymeric topcoats, the surfaces of EGS were modified by polyelectrolyte-modified zinc phosphating solution. The electrochemical reaction between phosphating solution and EGS led to the complete coverage with fully grown hopeite crystals after only 5 sec treatment, thereby improving adhesion to topcoating and providing protection of EGS against corrosion. To evaluate the ability of polyphenylene sulfide (PPS) polyaryl thermoplastic coatings to protect zinc phosphate (Zn{center_dot}Ph)treated steels from corrosion in a wet, harsh environment ( 1.0 wt % H{sub 2}SO{sub 4}, 3.0 wt % NaCl and 96.0 wt % water at temperatures from 25{degrees} to 200{degree}C), we exposed them in an autoclave to attempt heating-cooling cyclic fatigue tests (1 cycle = 12 hr at 200{degrees}C + 12 hr at 25{degrees}C) up to 90 times. The major chemical reaction at the interface between ...

1995-07-01

495

Treatment feasibility of the radioactive liquid waste originated from MOX fuel characterization

Three phosphate based ceramics were studied for the immobilization of tri- and tetravalent actinides: britholites Ca{sub 9}Nd{sub 1-x}An{sub x} {sup IV}(PO{sub 4}){sub 5-x}(SiO{sub 4}){sub 1+x}F{sub 2}, monazites/brabantites Ln{sub 1-2x}{sup III}Ca{sub x}An{sub x}{sup IV}PO{sub 4} and Thorium Phosphate Diphosphate (TPD) Th{sub 4-x}An{sub x}{sup IV}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}. For each material, the incorporation of Th, U(IV), or Ce(IV) in the structure was examined. This work was the early beginning of the incorporation of {sup 239}Pu and/or {sup 238}Pu in order to evaluate the effects of {alpha} -decay on these three crystallographic structures. The syntheses were carried out using dry chemistry methods, involving mechanical grinding then heating treatment (1100 deg C {<=} {theta} {<=} 1400 deg C). For britholites, we showed that the incorporation of thorium was complete for weight loading lower than 20 wt.% through the ...

2004-07-01

496

TREATMENT OF RADIOACTIVE EFFLUENTS AT THE MOL LABORATORIES

Different types of radioactive liquid waste are being generated at Advanced Fuel Fabrication Facility (AFFF), Tarapur during the quality control analysis of the mixed oxide (MOX) fuel pellets. A laboratory scale study was performed for treatment of such waste. Some of the waste streams originating from U and Pu analysis contain components like sulphate and phosphate which interfere during chemical precipitation of alpha activity from the waste. Various chemical co-precipitation experiments were conducted based on alkaline precipitation. Reductive precipitation using sodium sulphite and Fe(II) was found to be promising and the same was suggested for plant scale treatment. (author)

2011-02-22

497