Energy Technology Data Exchange (ETDEWEB)

The Korea Atomic Energy Research Institute has launched a decommissioning program of uranium conversion plant. One of the important tasks in the decommissioning program is the treatment of the sludge, which was generated during operation and stored in the two ponds of the lagoon. The treatment requires the volume reduction of lagoon sludges for the low cost of the program and the conversion of the chemical forms, including uranium, for the acceptance at the final disposal site. The physical properties, such as densities, were measured and chemical compositions and radiological properties were analyzed. The denitration was a candidate process which would satisfy the requirements for sludge treatment, and the characteristics of thermal decomposition and dissolution with water were analyzed. The main compounds of the sludge were ammonium and sodium nitrate from conversion plant and calcium nitrate, calcium carbonate from Ca ...

Energy Technology Data Exchange (ETDEWEB)

The spontaneous precipitation of calcium sulfate in supersaturated solutions over the temperature range between 25.0 and 80.0 C was investigated by monitoring the solution specific conductivity during desupersaturation. From measurements of the induction times preceding the onset of precipitation the surface energy of the forming solid, identified as gypsum, was found between ca. 12 and 25 mJ/m{sup 2} for the temperature range between 80.0 and 25.0 C, respectively. Kinetics analysis showed that over 50 C it is possible that anhydrous calcium sulfate is forming as a transient phase converting into the more stable calcium sulfate dihydrate. The linear dependence of the rates of precipitation on the relative solution supersaturation suggested a mechanism according to which the growth units are integrated into the active sites of the supercritical nuclei by surface ...

International Nuclear Information System (INIS)

This study concerns the Souss upstream basin. The objective is to investigate the characteristics of surface water and groundwater, to assess the impact of artificial recharge as reinforcement of the natural replenishment and assess the renewal of groundwater under semi-arid area. Two major water types are observed: (i) surface waters and upstream springs (least mineralized) and (ii) all groundwater samples (prevailing calcium and magnesium bicarbonate water type). Water isotopes show a low evaporation of precipitations during infiltration. Impoverishment in heavy isotopes is the characteristic of mountain rainfalls, or of a climate colder and wetter than present. Carbon-14 activities (34-94 pmc) indicate a long residence time. The artificial recharge is low compared to the reservoir volume, due to which the renewal rate is also low.

Energy Technology Data Exchange (ETDEWEB)

The desorption of uranium from the granular titanium-activated carbon composite adsorbent (concentration of uranium: 25.5 mg/l-Ad), which adsorbed uranium from natural sea water, was examined by the column process with acidic eluent at room temperature. The column operation was able to be carried out without destruction of the granular adsorbent by the generation of the carbon dioxide, and free from disturbance of the eluent flow by precipitate of calcium sulfate dihydrate with sulfuric acid eluent. The amount of acid consumption by the adsorbent was 0.87 eq/l-Ad. The alkaline earth metals were eluted in the range of elution volume below 2l/l-Ad, whereas uranium, iron, and titanium were eluted above 2l/l-Ad. Therefore, uranium was separable from the alkaline earth metals which were adsorbed in the most quantity in the adsorbent. In the range of elution volume 2 to 12l/l-Ad, the percentage of desorbed ...

Energy Technology Data Exchange (ETDEWEB)

The generation of acidic mine drainage is based on the oxidation dissolution of sulfide minerals due to the contact of ores with the natural water and the air. Namely, the sulfuric acid promotes the dissolution of sulfide minerals and gangue minerals, and Fe{sup 2+} is further oxidized to turn into Fe{sup 3+}, which acts as an oxidizer for other sulfide minerals and promotes the dissolution of the same. This paper roughly describes a mine drainage treatment focusing on an Fe{sup 2+} neutralization method and an iron bacteria oxidation method. The iron bacteria oxidation method is a method of oxidizing Fe{sup 2+} into Fe{sup 3+} by using iron bacteria, and then removing Fe{sup 3+} with calcium carbonate. This method has been used for treating the drainage in the Sakuhara Mine and the former Matsuo Mine, with good results. The paper finally introduces, as power-saving low-cost mine drainage treatment methods, a method of treating drainage ...

Energy Technology Data Exchange (ETDEWEB)

X-ray diffraction, infrared spectroscopy, thermal analysis, scanning electron microscopy, and particle size analysis were used to characterize the product of the thiosulfate process. It was found to consist of a mixture of a solid solution of calcium sulfate in calcium sulfite hemihydrate, calcium sulfate dihydrate, and calcium carbonate. Reactions taking place on heating the byproduct were identified in oxidizing and reducing atmospheres. Pure calcium sulfite hemihydrate as well as solid solutions of CaSO[sub 4] in CaSO[sub 3] [center dot] (1/2)H[sub 2]O with different sulfate concentrations were synthesized in the laboratory. Thermal analyses of pure solid solutions proved that the higher the sulfate content, the higher is the dehydration temperature. Accordingly, taking SO[sub 4][sup 2[minus

Energy Technology Data Exchange (ETDEWEB)

Wet limestone scrubbing is once again becoming a popular technology for removal of sulfur dioxide (SO{sub 2}) from power plant emissions. Critical to the operation of wet limestone flue gas desulfurization (FGD) systems is accurate chemical analysis of scrubber solids. The analytical technique of thermogravimetry is ideal for this application, as the instrument can give precise readings of the principal scrubber solids components, calcium sulfite/sulfate hemihydrate, calcium sulfate dihydrate (gypsum), and unused calcium carbonate. The data provides plant chemists, engineers, and operators with information needed to fine-tune scrubber operation and detect process upsets. (orig.)

International Science & Technology Center (ISTC)

Realization of Pharmacological Tests, Development of the Specifications and Technical Documentation and Registration in the Russian Federation of Medical Products as Soluble Tablets of Acetylsalicylic Acid/Calcium Carbonate in Two Dosages Intended for use as Medical Products Smoothing, Febrifugal and Antiaggregation Action and Development of Technology of Tableting the Above-Stated Preparations

Energy Technology Data Exchange (ETDEWEB)

A process for the recovery of nitrilotriacetic acid values from solutions containing polyvalent metal complexes of nitrilotriacetic and the decomposition products thereof is described, the process being characterized by the addition to such solutions of sufficient strong acid to dissociate the complex under conditions to precipitate the nitrilotriacetic acid.

Energy Technology Data Exchange (ETDEWEB)

The authors observed euhedral crystals in Manatee soil in a citrus grove in St. Lucie County, Florida. The material was identified as gypsum (CaSO/sub 4/ /times/ 2H/sub 2/O) using x-ray diffraction and infrared spectra. Photomicrography and scanning electron microscopy revealed that gypsum accumulated both in old root channels and within citrus root tissue of the Btg horizon. The subsurface horizons had elevated sulfate levels, a low initial pH, a drop (0.5 unit) in pH upon air-drying. Electrical conductivity paralleled the concentration of water-soluble sulfate. High levels of calcium and sulfate occurred for horizons above the water table. This accumulation is attributed to groundwater bearing these ions and subsequently discharging them to the overlying soil. Dead citrus roots appear to act as wicks to aid water transfer from lower to higher horizons. The roots and their empty channels provide spaces in which the gypsum can precipitate if ...

International Nuclear Information System (INIS)

A brief description is given of the physico-chemical parameters characterized a hot water geothermal reservoir and of its exploitation by means of single or coupled (doublet) wells. The technical aspects of geothermal heat to the users is then discussed, beginning with corrosion of materials caused by seven main agents: oxygen, hydrogen sulphide, carbon dioxide, ammonia, hydrogen, sulphates and chlorides. A brief mention is made of scaling due to calcium carbonate, silica and calcium sulphates. The basic components of a geothermal plant for non-electric uses are then discussed: production pumps, surface pipelines, heat exchangers, heat pumps and reinjection pumps. The advantages and disadvantages of the different equipment and materials used in the geothermal sector are also presented. A list is also given of the criteria used in the energy and economic balance of a geothermal operation. (author). 24 ...

International Nuclear Information System (INIS)

Denting studies have been undertaken in order to assess the influence of the most important parameters which could initiate corrosion of the carbon-steel occurring in the tube-tube support plate crevices of some PWR steam generators. Tests have been carried out in model boilers, feedwater being polluted with sea or river water. Specific effect of chloride or sulfate and influence of oxygen content, magnetite addition and pH value were investigated. In magnetite prepacked crevices, denting is obtained within 1000 hours for sea-water pollution of 0.3 ppm chloride at the blowdown. In neutral chloride or in river water denting is observed only with oxygen addition. Denting prevention is effective in the case of an on-line addition of phosphate, boric acid or calcium hydroxide. For denting stopping, boric acid or calcium hydroxide is efficient even with a high sea-water pollution. Soaks cannot stop denting if they are not ...

Energy Technology Data Exchange (ETDEWEB)

The investigations of lignite hydroliquefaction were aimed at improving reaction control in order to minimize residue and gas portion and hence increase the oil yield. To reach this goal, the process parameters were optimized and various catalysts tested for use in sump phase hydrogenation. Detailed investigations were also carried out on the problem of calcium carbonate agglomeration and the maceral decomposition behaviour of different lignite samples under hydrogenation conditions.

British Library Electronic Table of Contents (United Kingdom)

Abstract A large remaining source of uncertainty in global model predictions of future climate is how ecosystem carbon (C) cycle feedbacks to climate change. We conducted a field manipulative experiment of warming and nitrogen (N) addition in a temperate steppe in northern China during two contrasting hydrological growing seasons in 2006 [wet with total precipitation 11.2% above the long-term mean (348 mm)] and 2007 (dry with total precipitation 46.7% below the long-term mean). Irrespective of strong intra- and interannual variations in ecosystem C fluxes, responses of ecosystem C fluxes to warming and N addition did not change between the two growing seasons, suggesting independence of warming and N responses of net ecosystem C exchange (NEE) upon hydrological variations in the temperate ...

Energy Technology Data Exchange (ETDEWEB)

Sulfate attack of cement-based materials remains an important problem for the durability assessment of containers and disposal engineering barriers dedicated to the long-term storage of radioactive wastes since underground water which may reach these elements contains small quantities of sulfates (7-31 mmol/1). This work contributes to the study of sulfate-induced damage mechanisms, to their understanding and modelling. The experimental phases of this study aimed at the understanding of the different physico-chemical phenomena involved during an external sulfate attack at following their evolution and their impact on the transport and mechanical properties of the material. Leaching experiments in pure water and in a solution of sodium sulfate (with a sulfate content of 15 mmol/1), have been performed simultaneously on OPC paste (w/c 0,4)in order to allow a comparison of test results. The frequent analysis of the leachant has shown a consumption of sulfate ions by the matrix, ...

Energy Technology Data Exchange (ETDEWEB)

A chemical equilibrium model is used, implemented in a compact FORTRAN package called HITEQ, to investigate possible mineral deposition related to prereinjection treatment of Cerro Prieto brines for silica removal. Large saturation ratios of the treated brines with respect to several minerals are indicated by these computations. As a remedy, an inexpensive CO/sub 2/ removal scheme aimed at inhibiting carbonate mineral precipitation is proposed. This scheme is quantitatively discussed with the aid of HITEQ. It is concluded that the proposed treatment is both technically and economically feasible.

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

In 1991, the air quality monitoring program in Alberta consisted of continuous, intermittent, static, portable, mobile, and acid precipitation monitoring networks. The air quality monitoring networks are described and results from the continuous, intermittent, static, and acid precipitation networks are summarized. Regulations and guidelines for individual pollutants are discussed in detail. Pollutants monitored continuously (1-h average basis) include ammonia, CO, coefficient of haze, H{sub 2}S, nitrogen oxides, ozone, SO{sub 2}, and total hydrocarbons. Good air quality was observed most of the time at all continuous monitoring stations in 1991. The frequency of good air quality ratings ranged from 81% at the Edmonton northwest station to 98% at the Fort McMurray station. Intermittent monitoring (every 6th day) was conducted for total suspended particulates and for vinyl chloride monomers in the Fort Saskatchewan area. Chemical analyses of ...

International Nuclear Information System (INIS)

Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water chemistry and Mn removal rates were monitored over a 3-month period in continuous-flow reactors. For all substrates except quartzite, Mn was removed from the mine water during this period, ...

Energy Technology Data Exchange (ETDEWEB)

Samples of austenitic stainless steel AISI 316 were nitrided using the cathodic cage technique with the addition of methane in the nitriding atmosphere. The aim was to study the influence of this technique in reducing the precipitation of chromium nitrite and in improving the wear resistance. The results show that there was a significant improvement in such properties when compared to the results of ionic plasma nitriding. Formation of a double layer, one more internal composed of carbon and another with high nitrogen content, was confirmed by Scanning Electron Microscopy (SEM). The microhardness profile of the layer showed an increase in hardness values and a larger uniformity, while X-ray analysis showed less chromium nitriding precipitation when compared with results obtained for samples treated using ionic plasma nitriding.

British Library Electronic Table of Contents (United Kingdom)

The competitive adsorption of nitrate, chloride and carbonate in layered double hydroxides (LHD) with the general formula Formula Not Shown was investigated. Both normal ion exchange by exposure to a solution containing different anions, as well as addition of calcined material to solution thereby exploiting the memory effect of LDHs was studied. Changes in the interlayer anion changed the interlayer spacing of the LDH. The order of preference of intercalation was Formula Not Shown . When multiple anions were present in the exchange solution, LDHs with several distinct interlayer spacing were produced indicating that LDHs with different anions in the interlayer existed at the same time. However for extended exchange times (14days) where high concentrations of carbonate anion were present, ...

International Nuclear Information System (INIS)

The microstructures of so called high temperature alloys, which have been developed for service temperatures up to 800"0C, are not necessarily stable at higher temperatures. The mobility of alloying elements is very high in FeCrNi alloys at 950 "0C e.g. iron, chromium or nickel can diffuse up to 0.1 mm distance in one year, which is about a grain diameter. Interstitials like carbon or nitrogen show a four orders of magnitude higher diffusivity than the alloying elements. In addition, the carbon solubility in this type of alloy is reported to be very low. Therefore the alloys are supersaturated with carbon after heat treatment above 1100 "0C and water quenching although the absolute carbon content is very low. At service temperatures around 800"0C the solubility of carbon is still about one order of magnitude lower than at heat treatment temperature. This will lead, together with the ...

British Library Electronic Table of Contents (United Kingdom)

To improve the photocatalytic application performances of TiO2, in this work, firstly CdS modified Degussa P25 TiO2 (CdS/TiO2) composites were prepared by two methods, sol-gel method and precipitation method. Next they, sol-gel-CdS/TiO2 (sg-CdS/TiO2) and precipitation-CdS/TiO2 (pp-CdS/TiO2), were loaded on activated carbon fibers (ACFs) by dip-coating method using the sodium carboxymethyl cellulose as adhesives. The composites were characterized by XRD, UV-vis absorbance spectra, SEM, EDS and BET. The photocatalytic activities under sunlight were investigated by the degradation of methylene blue. The results showed that CdS/TiO2 composites were mainly composed of anatase-TiO2 and little CdS cubic phases. The absorption wavelengths of sg-CdS/TiO2 and pp-CdS/TiO2 composites were extended to ...

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The basic feature in the functional ecology of any mire ecosystem is retardation of the effective decay of organic material resulting in a conspicuous accumulation of plant debris as peat overtime. The carbon accumulation process is slow, and climatic change may have an impact on the carbon cycle of peatlands, therefore, it has been of interest to study the rate of carbon accumulation by geological methods from dated peat strata. The approach is hampered by several facts. First, the mires vary enormously as to their vegetation and hydrology and hence their production and decay properties. It follows that a great number of study sites are needed. Second, the peat in mires expands both vertically and laterally, and this requires a spatial reconstruction of carbon accumulation within a mire basin. Third, simple geological methods cannot account for the actual rate of carbon ...

British Library Electronic Table of Contents (United Kingdom)

Abstract The Jebel Ressas Pb-Zn deposits in North-Eastern Tunisia occur mainly as open-space fillings (lodes, tectonic breccia cements) in bioclastic limestones of the Upper Jurassic Ressas Formation and along the contact of this formation with Triassic rocks. The galena-sphalerite association and their alteration products (cerussite, hemimorphite, hydrozincite) are set within a calcite gangue. The Triassic rocks exhibit enrichments in trace metals, namely Pb, Co and Cd enrichment in clays and Pb, Zn, Cd, Co and Cr enrichment in carbonates, suggesting that the Triassic rocks have interacted with the ore-bearing fluids associated with the Jebel Ressas Pb-Zn deposits. The 18O content of calcite associated with the Pb-Zn mineralization suggests that it is likely to have precipitated from a fl...

Energy Technology Data Exchange (ETDEWEB)

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or ...

Energy Technology Data Exchange (ETDEWEB)

Development was explained of non-phosphate detergent with zeolite (Z) and alpha-olefin sulfonate (AOS). 4A type Z was taken notice of as a builder to replace phosphate. In calcium ion trapping power, conventional sodium tripolyphosphate (STP) and Z are 158mgCaO/g and 150mg/g, respectively. However, because Z by the conventional method is large in crystal diameter, coagulates and adheres to matter to be washed, was newly developed fine Z, 0.9 {mu} m in primary grain diameter, which does not give abrasion nor occlusion to the washing machine, nor precipitate in the river. Because linear alkylbenzene sulfonate, combined with Z, is poorer in washing power than that, done with STP, was developed AOS, new non-phoshate use interfacial active detergent, which is excellent in all washing power, biodegradation speed and physical powder property. Improvement was variously made also in powdery detergent production technology. Though the non-phosphate ...

Energy Technology Data Exchange (ETDEWEB)

The creep characteristics of alloy 800 at temperatures around 600/sup 0/C are greatly affected by the composition and treatments in the final stages of manufacture. Short-term and creep properties of alloy 800 at 600/sup 0/C are described for six melts covering the carbon range 0.054-0.078%, the titanium range 0.23-0.57% and the aluminium range 0.17-0.52%. The properties are related to the alloy chemistry and the microstructure. It is shown that homogeneously nucleated ..gamma..'-precipitates are the main cause of low ductility in alloy 800 but there is also some influence of, for instance, grain boundary M/sub 23/C/sub 6/ films and discontinuous precipitation of Ni/sub 3/Ti or M/sub 23/C/sub 6/ in grain boundaries. The extent of ..gamma..'-precipitation is controlled primarily by the (Ti+Al)-content. To avoid ..gamma..' and ensure a high creep ductility the (Ti+Al)-content ...

British Library Electronic Table of Contents (United Kingdom)

A novel approach using reactive processing is explored that eliminates the labour-intensive separation of post-consumer polyolefin waste from the mixed plastics waste stream. The reactive compatibiliser BMI has been used to form a modified blend of PCPW with 40% improved tensile strength relative to the uncompatibilised control. Addition of 60 wt.-% magnesium hydroxide [Mg(OH)2] during reactive compatibilisation with BMI gave rise to an even more significant enhancement (up to 100%) of the tensile strength. BMI was also able to usefully enhance the properties of a composite based on calcium carbonate and the polyolefin waste.

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for preparing of an ion exchanger, comprising: treating an ionically inert activated charcoal porous support with an aqueous solution of metal oxychloride selected from the group consisting of zirconium and titanium oxychlorides so as to impregnate the pores of the support with the solution; separating the treated support from excess metal oxychloride solution; converting the metal oxychloride to a hydrous metal oxide precipitate in the pores of the support at a pH above 8 and above the pH whereat the hydrous metal oxide and activated charcoal support have opposite zeta potentials and sufficient to hydrolyze the metal oxychloride. It also describes a process for preparing an ion exchanger comprising: treating granulated activated charcoal with a concentrated solution of a metal oxychloride from the group consisting of zirconium and titanium oxychlorides, degassing the mixture; and treating the resultant mixture with a base selected ...

Energy Technology Data Exchange (ETDEWEB)

The previous judgment of eutrophic state, once proposed for the Trasimeno Lake (Umbria region, Italy), has been revised. According to Vollenweider-OECD classification criterion, the lake waters are at present to be classified as mesotrophic waters, with phosphorus limitation. However this level of moderate productivity results to be conditioned by the hydrochemical characteristics of the lake waters, that control phosphorus concentrations independently from the loading coming from the basin, and prevent dangerous and massive algal blooms. Different processes of chemical nature, regulating the phosphorus amount in the lake waters, are then reviewed: adsorption of P/P0(4) onto suspended materials, particularly clay mineral particles, and direct precipitation as hydroxylapatite or co-precipitation with carbonates, are found to be the principal mechanisms that determine chemical removal of phosphorus from the water column. A ...

International Nuclear Information System (INIS)

Beach rocks are observed frequently on the tropical and subtropical sandy beaches where they express thin beds dipping seaward at less than 15 degrees. They consist of beach sediments including fossil shells, fragments of corals, diatoms and other biocarbonates, and are well cemented within the inter-tidal zone with calcium carbonate originated in sea water. Therefore, they are not only good indicators which show the past sea level, but also provide good sample material for radiocarbon dating. The locations of beach rocks give us an optimum condition studying a carbon cycle between land and marine environment by analyzing their isotope fractionations. In order to estimate the origin of calcium carbonate which worked as an adhesive when beach rocks were formed and to estimate the formative ages of beach rocks, a total of 330 fossil corals, fossil shells and calcarenite or calcirdite ...

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion is a promising technology for the combustion of gas or solid fuel with efficient use of energy and inherent separation of CO{sub 2}. Chemical-looping combustion of methane with calcium sulfate as a novel oxygen carrier was conducted in a laboratory scale fixed bed reactor. The effects of reaction temperature, gas flow rate, sample mass, and particle size on reduction reactions were investigated and an optimum operating condition was determined. The results show that this novel oxygen carrier has a high reduction reactivity and stability in a long-time reduction/oxidation test. The conversions of CH{sub 4} increased with a higher temperature, smaller gas flow rate, larger sample mass and smaller particle size. The suitable reaction temperature seems to be around 950 deg. C. Low temperatures lead to a low CH{sub 4} conversion, but a significant SO{sub 2} formation was observed at a higher temperature. The release of SO{sub 2}, CO, H{sub 2} ...

UK PubMed Central (United Kingdom)

Cellular calcium transient alternans are beat-to-beat alternations in the peak cytosolic calcium concentration exhibited by cardiac cells during rapid electrical stimulation or under pathological conditions....Full Text Available

UK PubMed Central (United Kingdom)

A number of studies have indicated that plasma membrane calcium ATPases (PMCAs) are expressed in the brain and spinal cord and could play important roles not only in the maintenance of cellular calcium...Full Text Available

UK PubMed Central (United Kingdom)

Background and objectives: Higher urinary calcium is a risk factor for nephrolithiasis. This study delineated associations between demographic, dietary, and urinary factors and 24-h urinary calcium.Design,...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Field and laboratory work sponsored by the Gas Research Institute (GRI) and the Department of Energy (DOE) have shown that calcium-carbonate scale formation in waters produced with natural gas and oil can be prevented by injection of phosphonate inhibitor into the formation, even if the formation is sandstone without calcite binding material. Inhibitor squeeze jobs have been carried out on DOE's geopressured-geothermal Gladys MaCall brine-gas well and GRI's co-production wells in the Hitchcock field. Following the inhibitor squeeze on Gladys McCall, the well produced over five million barrels of water at a rate of approximately 30,000 BPD without calcium-carbonate scaling. Before the inhibitor squeeze, the well could not be produced above 15,000 BPD without significant scale formation. In the GRI brine-gas co-production field tests, inhibitor squeezes have been used to successfully prevent scaling. Laboratory work has been ...

Energy Technology Data Exchange (ETDEWEB)

The subscale Varestraint test has been used to determine the relative hot cracking susceptibility of the fusion zone in four commercial heats of alloy 800. Although all four heats were susceptible to cracking, one heat exhibited a significant increase in cracking relative to the other three. Optical metallography revealed that nearly all the cracking was localized along fusion zone grain boundaries. Microprobe analysis of the grain boundaries detected high concentrations of titanium, silicon, and niobium resulting from partitioning during solidification. The fusion zone hot cracking mechanism in alloy 800 involves the complex interaction of titanium, silicon, niobium, and carbon along the solidification boundaries. SEM and Auger analyses of the hot crack fracture surfaces revealed the presence of (Ti, Nb)-rich carbides, suggesting that these particles precipitate from the liquid which solidifies last on the fracture surface. 23 references.

Energy Technology Data Exchange (ETDEWEB)

The phase transformations and properties of a precipitation-hardened Ni-Cr-based alloy are investigated as a function of C, B, Nb, and Cr contents. It is found that the primary role of Nb consists in the formation of an independent phase, delta-Ni3Nb, a part of a gamma/gamma-prime-delta eutectoid (for high C and B concentrations) and in stimulating the gamma-sigma reaction consecutively with the gamma double prime-delta reaction (for low C and B concentrations). In both cases, the long-term strength characteristics of the Nb-alloyed system are relatively low. The substitution of boron for carbon contributes to a reduction in the number of nucleation sites for topologically close-packed phases and to the formation of more stable (with respect to excess compounds) M3B2 and MB2 borides. The high-boron material exhibits better properties and phase stability under mechanical and thermal loading. 13 references.

Energy Technology Data Exchange (ETDEWEB)

Calcium and phosphorus were mainly responsible for reducing the gastrointestinal absorption of lead in human subjects. The effect of calcium was greater than phosphorus, and their combined effect was more than additive. Increasing weights of calcium and phosphorus progressively reduced lead absorption. The relationship between absorption and increasing weights could be described by two negative exponentials. These effects could be explained if lead competed with calcium and phosphorus for common transport mechanisms in the gut. Milk was also found to reduce lead absorption. Adding milk to the diet of people with low dietary calcium intake could reduce the possibility of increased absorption of ingested lead.

UK PubMed Central (United Kingdom)

AbstractWe propose a mechanism for the formation of membrane oscillations and traveling waves, which arise due to the coupling between the actin cytoskeleton and the calcium flux through...Full Text Available

Science.gov (United States)

Products of a power plant flue gas desulfurization scrubber are discharged into a pond as sludge consisting of calcite (initial delta13C 3.2-3.8 per thousand), gypsum (initial delta34S 7.6-8.6 per thousand), and aqueous solution. Reducing conditions exist below a boundary that appears to move vertically as a function of changes in pond water level. Under reducing conditions, bacteria partially reduce aqueous sulfate to low-delta34S sulfide, consuming organic carbon and generating low-delta13C bicarbonate. Under oxidizing conditions, sulfide is converted to sulfate, leading to calcite dissolution, gypsum precipitation, and isotopic re-equilibration of remaining calcite with dissolved bicarbonate near the pond surface. The gypsum has delta34S near 6 per thousand, and calcite has delta13C as low as -1.7 per thousand; the changes from initial values correspond to predictions based on isotopic balance and reaction stoichiometry. The pond largely ...

International Nuclear Information System (INIS)

Micronutrient deficiencies in flooded rice have been recognized with increasing frequency in recent years. Zinc deficiency is the most widespread disorder, followed by Fe, Mn, and Cu deficiencies. Boron and Mo deficiencies have not been reported in field culture. The peculiar characteristics of a flooded soil are: 1) a layer of standing water; 2) absence of oxygen; 3) a soil profile largely in a reduced chemical state; 4) the presence of large biological carbon dioxide excesses; 5) the presence of high concentrations of soluble Fe"+"+ and Mn"+"+; 6) alteration of soil pH; 7) the presence of toxic substances; 8) increased soluble Na"+, K"+, Ca"+"+, Mg"+"+, NH_4"+, HCO_3"-, H_2PO_4"-, and Si(OH)_4 in the soil solution. Micronutrient availability in flooded soils is affected by: 1) increased solubility of relatively insoluble minerals due to dilution effects; 2) pH changes in relation to solubility and plant availability; 3) changes in oxidation-reduction equilibria; ...

Energy Technology Data Exchange (ETDEWEB)

In the Ti-Si-C and Ti-Si-C-N systems, metastable layers were precipitated by means of non-reactive magnetron sputtering of hot-pressed two-phase TiC/SiC and TiN/SiC targets with 20 mole% and 50 mole% SiC. The preparation parameters were varied as follows: ion bombardment during precipitation (bias sputtering), substrate temperature, and annealing times when annealing amorphous 50%:50% TiC/SiC and 50%:50% TiN/SiC layers. Sputtering of targets containing 20% SiC was found to result in monophase fcc layers (NaCl structure). This was documented on the basis of X-ray and electron diffraction patterns. Direct precipitation of targets with 50 mole% SiC resulted in amorphous layers. Increasing the ion bombardment during accretion, raising the substrate temperature, and annealing amorphous 50%:50% TiC/SiC and 50%:50% TiN/SiC (layers precipitated directly) resulted in the crystallization of TiC and TiN ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

Short communication.

KoreaScience (Korea)

Full Text Available

KoreaScience (Korea)

Full Text Available

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

OAK B188 The goal of this project is to mimic the energy transduction processes by which photosynthetic organisms harvest sunlight and convert it to forms of energy that are more easily used and stored. The results may lead to new technologies for solar energy harvesting based on the natural photosynthetic process. They may also enrich our understanding and control of photosynthesis in living organisms, and lead to methods for increasing natural biomass production, carbon dioxide removal, and oxygen generation. In our work to date, we have learned how to make synthetic antenna and reaction center molecules that absorb light and undergo photoinduced electron transfer to generate long-lived, energetic charge-separated states. We have assembled a prototype system in which artificial reaction centers are inserted into liposomes (artificial cell-like constructs), where they carry out light-driven transmembrane translocation of hydrogen ions to generate proton motive ...

Energy Technology Data Exchange (ETDEWEB)

A heat resistant nickel base alloy which is excellent in not only hot and cold workability but also high temperature strength properties and which also possesses satisfactory oxidation resistance. The nickel base alloy consists essentially of 0.001-0.15 percent carbon, 0.0005-0.05 percent calcium, 20.0-126.0 percent chromium, 4.7-9.4 percent cobalt, 5.0-16.0 percent molybdenum, 0.5-4.0 percent tungsten, with the total of molybdenum plus tungsten being from 9.0 to 16.5 percent, and the balance nickel and inevitable impurities. The alloy may further contain one selected from the group consisting of (1) 0.3-1.5 percent aluminum and 0.1-1.0 percent titanium, (2) 0.001-0.30 percent at least one of yttrium and rare earth elements, and (3) 0.001-1.0 percent at least one of niobium, vanadium and tantalum, whereby the aforementioned characteristics are further enhanced.

International Nuclear Information System (INIS)

Statements about the dynamic processes of uptake, transport, and deposition of Ca and Mg in norway spruce and Scots pine are made in this paper. Concerning the storage of these elements it is shown that there are great differences in their functional importance in cell metabolism. There is evidence that the role of Mg in enzyme and protein metabolism is of far greater significance for the understanding of Mg-deficiency symptoms than its function as the central atom of the chlorophyll complexes. In regard to the transport and especially to the incorporation of Ca into the needles differences between species were evident, expressing the special status of pine among the gymnosperms. With increasing needle age an accumulation of Ca-oxalate crystals, which are physiologically inert, could be proved for the studied conifers. This was interpreted as a 'detoxication' from surplus Ca to hold constant the level of the physiologically active fraction. Accordingly, the low Ca-contents of yellowed ...

Energy Technology Data Exchange (ETDEWEB)

A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and ...

Energy Technology Data Exchange (ETDEWEB)

The performance of the Magma Power Company's reinjection well No. 46-7 at East Mesa has been examined. Water was cooled to 100/sup 0/F(+-) to simulate total heat extraction and then tested using membrane filter flow procedures. The cooled water contains particles which are in the high colloid size range, and formation impairment by these particles is unlikely. There is evidence that acid soluble corrosion products and calcium compounds constitute about two thirds of the particulates, and that the acid insoluble residue contains precipitated silica, insoluble corrosion products, and possibly formation fines carried in the produced water. Under stabilized conditions, the suspended solids content of the water is less than 2 parts per million. However, during the frequent production well start ups, a higher concentration of suspended solids is carried in the produced water and into the injection well, conceivably augmenting fill in the ...

International Nuclear Information System (INIS)

Full text: Nuclear material is subjected to chemical processing throughout the entire fuel cycle. Traces of the chemical reagents and solvents are left behind in the nuclear material. So far essentially metallic impurities or light elements have been investigated for their potential in providing clues on the type of process they originate from. In the present investigation, the applicability of anions for attributing nuclear material to a certain chemical process has been investigated. Anions (e.g. nitrate, sulphate, phosphate, chloride) originate from acids or salt solutions that are used for processing of solutions containing uranium or plutonium. The study presented in this paper focuses on yellow cake samples originating from different mines applying different chemical processes for leaching, dissolving and precipitating the uranium. Consequently, the anionic patterns should be different. The concentrations of different anionic species were measured by ion ...

Energy Technology Data Exchange (ETDEWEB)

This report summarizes preliminary 2-D reactive-transport simulations on the injection, storage and transport of supercritical CO{sub 2} in dolostone formations in the Ordos Basin in China. The purpose of the simulations was to evaluate the role that basin heterogeneity, permeability, CO{sub 2} flux, and geochemical reactions between the carbonate geology and the CO{sub 2} equilibrated brines have on the evolution of porosity and permeability in the storage reservoir. The 2-D simulation of CO{sub 2} injection at 10{sup 3} ton/year corresponds to CO{sub 2} injection at a rate of 3 x 10{sup 5} ton/year in a 3-D, low permeable rock. An average permeability of 10 md was used in the simulation and reflects the upper range of permeability reported for the Ordos Basin Majiagou Group. Transport and distribution of CO{sub 2} between in the gas, aqueous, and solid phases were followed during a 10-year injection phase and a 10-year post injection phase. Our results show that ...

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

The concentrations of uranium, arsenic, and radium remain well below the maximum permissible values of < 0.1 mg/l (uranium), < 0.1 mg/l (arsenic) and < 100 mBq/l (radium) due to two separation stages with barium sulfate and GoPur 3000 precipitation and due to iron hydroxide/iron arsenate precipitation. The radioactive arsenates can be separated from the toxic ones by separating the sludge which is analyzed. Processing of radioactive sludges leaves reusable GoPur 3000, sulfuric solutions which contain uranium or solutions which contain carbonate, and radioactive barium sulfate whose radiation intensity of 12 mBq/g is due to the presence of radium. The sludge produced contains adsorbed salts in addition to the dosed chemicals (floated sludges: 40 g/m"3, iron sludges < 20 g/m"3). A solids content < 100 g/m"3 can be selected for both sludge portions. Static-mixer chemicals dosing and technical improvements of the ...

International Nuclear Information System (INIS)

The diffusion of ion beam injected self-interstitials (I) and their interaction with impurities in crystalline Si has been investigated and modeled. In particular, the I-substitutional carbon (C) interactions have been studied, using a molecular-beam-epitaxy grown Si_1_-_yC_y layer interposed between the shallow I-source and a deeper B-spike (marker for I-concentration). Substitutional C atoms are shown to trap I's, to be removed from their substitutional sites, and to form stable precipitates into the C-rich region. The I-trapping mechanism was quantitatively studied by a simulation code. The reactions causing trapping and deactivation are described. In addition, the boron markers approach was extended to the two dimensional (2D) diffusion. High resolution scanning capacitance microscopy was used for quantitative measurements of the 2D boron transient enhanced diffusion induced on a boron delta array by the I's ion beam injected through a ...

International Nuclear Information System (INIS)

Using a radioactive tracer method the bulk and grain boundary diffusion of "5"9Fe was determined in industrial alloy 800 and melts of alloy 800 with additional P and S in the temperature range 800 to 1000 C. The use of the approximation of Suzuoka was confirmed by autoradiographs. In alloy 800 H the activation energy of grain boundary diffusion of "5"9Fe is (209 #+-# 17)kJ/mol. Dissolved elements especially P increase the activation energy of the grain boundary diffusion of Fe by their segregation to the grain boundaries. In addition the influence of the grain boundary diffusion on the growth of creep cavities was investigated in the same materials, and the chemical composition of the creep cavities and grain boundaries were analysed by Auger electron spectroscopy (AES). For alloy 800 + 0.088 wt-%P an enrichment of about 14 at-%P was observed at the grain boundaries. The addition of P clearly enhances the creep strength of alloy 800; this can probably be explained by ...

UK PubMed Central (United Kingdom)

Verapamil administered before treatment, but not after treatment, had a beneficial effect on a 90-minute warm ischemia-reperfusion rat liver injury model. The possible activation of proteases converting...Full Text Available

UK PubMed Central (United Kingdom)

The homologous sequences observed for many calcium binding proteins such as parvalbumin, troponin C, the myosin light chains, and calmodulin has lead to the hypothesis that these proteins have homologous...Full Text Available

UK PubMed Central (United Kingdom)

An optical flow gradient algorithm was applied to spontaneously forming networks of neurons and glia in culture imaged by fluorescence optical microscopy in order to map functional calcium signaling...Full Text Available

UK PubMed Central (United Kingdom)

Improving the anti-demineralizing/remineralizing and mechanical properties of amorphous calcium phosphate (ACP) composites has been the focus of our recent research. In this study, an ethoxylated...Full Text Available

UK PubMed Central (United Kingdom)

Large-conductance voltage- and calcium-activated potassium (BK) channels have been shown to play a role in detrusor overactivity (DO). The goal of this study was to determine whether bladder outlet...Full Text Available

Science.gov (United States)

Names Ca+2; Serum calcium; Ca++ References Wysolmerski JJ, Insogna KL. The parathyroid glands, hypercalcemia, and hypocalcemia. In: Goldman L, Ausiello D, eds. Cecil...

UK PubMed Central (United Kingdom)

T-type calcium channels are responsible for generating low-threshold spikes that facilitate burst firing and neurotransmitter release in neurons. GnRH neurons exhibit burst firing, but the underlying...Full Text Available

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

Russian (1972). USSR Desyatnik, VN Kurbatov, NN Raspopin, SP Trifonov,

Science.gov (United States)

Gas contaminated with at least one noxious component, such as SO/sub 2/, HF or NOx, is scrubbed with a clear, calcium-containing, initially-basic washing liquid which also comprises the anion of a strong inorganic acid, that of a polybasic carboxylic acid and, optionally, that of a monobasic carboxylic acid. Apparatus is provided for scrubbing the gas, oxidizing produced calcium bisulfite to calcium sulfate, separating out and removing solids, and recirculating clarified liquid for scrubbing contaminated gas.

Energy Technology Data Exchange (ETDEWEB)

A study has been made of the precipitation and growth processes which occur during cooling from solution treatment and under isothermal hold conditions in a magnesia-partially-stabilized zirconia alloy. Three types of precipitate have been identified which develop during cooling or during isothermal hold treatments just above and below the eutectoid temperature. These precipitate forms are termed (i) primary, (ii) large random, and (iii) secondary. Further precipitation, slow growth of existing precipitates, and subeutectoid decomposition result when an additional 1100/sup 0/C aging treatment is given to the previously cooled material. It is shown that type (iii) secondary precipitates from rapidly within the temperature range of 1300/sup 0/ to 1375/sup 0/C. The secondary precipitates are largely responsible for the improved room-temperature ...

Science.gov (United States)

... say for sure if the signal is coming from hail, lots of graupel, or some other hydrometeor . ... Precipitation forms when cloud droplets or ice particles in clouds grow and .... A landslide is the movement of rock, debris, or earth down a slope. ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

... Oceanographic Institution, Mass. (USA) v. 8 p. 439-442. abundance

Energy Technology Data Exchange (ETDEWEB)

A borohydride, for instance sodium borohydride, is added to the radioactive effluent, with eventually a carrier such as Cu{sup +}, to give a precipitate containing ruthenium. The processing can be combined to Sr and Cs precipitation be know processes giving barium sulfate and nickel ferrocyamide precipitates. Influence of borohydride concentration on decontamination factor is given.

International Nuclear Information System (INIS)

The total interaction cross sections (#sigma#_t) of some sugars and amino acids and five elements: lithium, carbon, oxygen, aluminium and calcium have been measured for 6.4 keV, 13.95 keV, 14.4 keV, 17.74 keV, 24.14 keV, 30.8 keV, 35 keV, 59.54 keV, 81 keV, 122 keV and 136 keV photons in a narrow beam good geometry set up, by using high resolution detectors such as a Si-PIN diode detector and a high purity germanium detector. The #sigma#_t values have been used in a matrix method to evaluate the effective atomic numbers Z_e_f_f of the samples from their effective atomic cross sections #sigma#_a. The effective atomic cross section of a sample #sigma#_a is the total interaction cross section divided by the total number of atoms of all types in it. Further, a quantity called the effective atomic weight A_e_f_f of a sample was defined as the ratio of the molecular weight A to the total number of atoms of all types in it. The variation of Z_e_f_f ...

Energy Technology Data Exchange (ETDEWEB)

In cooling systems, an improved control of scale deposit and corrosion processes is a major challenge and an realistic evaluation tool for water treatments is of the utmost economic importance. In this study, a channel flow cell was used to allow in-situ electrochemical measurements in well defined electrolyte tube flowing conditions. An expression of the mass transfer towards the electrode was established where the diffusion-limited current is a function of Re{sup 1/3} in the laminar regime and was verified experimentally using the redox couples Fe[CN]{sub 6}{sup 4-}/ Fe[CN]{sub 6}{sup 3-} and O{sub 2}/OH{sup -}. This hydrodynamically controlled experimental device was developed to investigate scale deposit processes and to evaluate scale inhibitor efficiency using a electrochemical quartz crystal microbalance. Experiments were performed on three different waters, at various flow rates and temperatures. The efficiency of a well known phosphonate (HEDP) was tested at different ...

Energy Technology Data Exchange (ETDEWEB)

ICP emission analyses are prone to errors due to changes in power level, nebulization rate, plasma temperature, and sample matrix. As a result, accurate analyses of complex samples often require frequent bracketing with matrix matched standards. Information needed to track and correct the matrix errors is contained in the emission spectrum. But most commercial software packages use only the analyte line emission to determine concentrations. Changes in plasma temperature and the nebulization rate are reflected by changes in the hydrogen line widths, the oxygen emission, and neutral ion line ratios. Argon and off-line emissions provide a measure to correct the power level and the background scattering occurring in the polychromator. The authors` studies indicated that changes in the intensity of the Ar 404.4 nm line readily flag most matrix and plasma condition modifications. Carbon lines can be used to monitor the impact of organics on the analyses and ...

International Nuclear Information System (INIS)

Precipitation-hardened single crystals of a beta (bcc) Ti--40 at. percent V--1.0 at. percent Si alloy were deformed in compression at 77 and 298"0K. The dependence of the yield stress upon aging time at 843"0K for solution-treated crystals shows two maxima which are caused by silicide precipitates. The orientation dependence of the yield stress and of the active macroscopic slip plane were determined as a function of aging time. The solution-treated as well as aged crystals exhibit an asymmetry of both the yield stress and the plane of slip, the degree of asymmetry being larger at 77 than at 298"0K. The asymmetry of slip and yielding is not affected by the presence of precipitation hardening. Results indicate that the effect of the dislocation core structure on dislocation motion is independent of the presence of precipitates. (auth).

UK PubMed Central (United Kingdom)

Vitamin D is now known to be of physiological importance outside of bone health and calcium homeostasis, and there is mounting evidence that it plays a beneficial role in the prevention and/or treatment...Full Text Available

UK PubMed Central (United Kingdom)

A filamentous fungus, Cunninghamella blakesleeana AS 3.153, was used as a microbial model of mammalian metabolism to transform verapamil, a calcium channel antagonist. The metabolites...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Abstract Although photosynthetic thermotolerance has been investigated extensively in cotton leaves, reports on the biochemical influence of the pistil in promoting fertilization thermostability are limited. To evaluate the effect of temperature, genotype, and exogenous calcium application on fertilization and pistil biochemistry in cotton, thermosensitive (cv. ST4554 B2RF) and thermotolerant (cv. VH260) plants were grown under control (30/20-C) or high-temperature (38/20-C) conditions during flowering, and exogenous CaCl2 was applied to flowers 1-day prior to anthesis. Measured pistil parameters included fertilization efficiency; protein concentration; glutathione reductase, superoxide dismutase (SOD) and NADPH oxidase activities; and ATP and calcium levels. Exogenous calcium had no effec...

International Nuclear Information System (INIS)

... activation analysis aluminium 28 calcium 49 chlorine 38 cotton plants li-drifted

Science.gov (United States)

... was noted. It was reported that similar fibers also grew on particles of thermal carbon black at a temperature of 10500 and in an atmosphere ...

Science.gov (United States)

Not Available

International Nuclear Information System (INIS)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. This paper describes the roles on corrosion. A corrosion test on precipitate-containing and precipitate-free materials made from pure zirconium and a small quantity of iron and chromium, rest potential measurements on an intermetallic compound of Zr(FeCr)_2 and zirconium matrix, and a galvanic coupling test of those were performed. Results showed that corrosion behavior of zirconium alloys could be attributed to the electrochemical properties of intermetallic compounds precipitated in each alloy. Namely, the cathodic and anodic polarization characteristics were associated with anodic protection provided by the precipitates on the alloys and the ...

International Nuclear Information System (INIS)

The crystallography of #alpha#(hcp) precipitates formed on the #beta#(bcc) matrix grain boundaries has been studied with transmission electron microscopy (TEM) in a Ti-15V-3Cr-3Sn-3Al alloy. The #alpha# precipitates have a near-Burgers orientation relationship with respect to at least one of the adjacent #beta# grains. Among the possible 12 variants in this orientation relationship, the variant that [11 bar 20]_#alpha# is parallel to the _#beta# closest to the grain boundary plane tends to be preferred by the #alpha# precipitates. Additionally, further variant selections are made so as to minimize the deviation of orientation relationship with respect to the ''opposite'' #beta# grain from the Burgers one. Such rules in variant selection often result in the formation of precipitates with a single variant at a planar grain boundary. Prior small deformation of #beta# matrix changes the variant of #alpha# ...

Science.gov (United States)

A control group of geese (Anser anser) on a normal calcium diet for egg laying poultry was compared to egg laying geese on a calcium deficient diet. The ultimate compressive strength and modulus of elasticity of femoral cortical bone from each group were determined by compressing right circular cylinders which were 2.4 mm in height and 0.8 mm in diameter. The bending strength and bending modulus of elasticity of tibial cortical bone were determined by three point bend tests on rectangular prisms which were approximately 25 mm by 0.8 mm by 0.8 mm. Bone calcium content and eggshell calcium content were determined by atomic absorption spectrophotometry. Blood samples were analyzed for free calcium ion concentration. Histological observations included studies of cross-sectional microradiographs, examinations of cross sections stained by a modified Masson's technique, and a determination ...

Energy Technology Data Exchange (ETDEWEB)

The capacity extension of additives was tested in a 200 cm/sup 2/bi-cell and a Zn powder moving-bed slurry. It was found that for the Type A additives in 12 M KOH, 25 g/l of silicate provided higher capacity than stannate, titanate and aluminate additives. The optimum concentration of sorbitol (a Type B additive that stabilizes polymeric chains involving ZnO) was found to be 15 g/l in 12 M KOH. A silicate and sorbitol combination added to Zn powder slurry in 12 M KOH provided a 20% increase in discharge capacity (195 Ah/l at 200 A/cm/sup 2/) compared to the maximum capacity obtained with silicate alone. A much lower capacity (74 Ah/l) was realized with silicate as Type C additive (precipitation of ZnO away from the Zn surface, for low KOH concentrations). The mechanisms of passivation and capacity extension were discussed and a model presented. The cell voltage and power densities were determined for the discharge process as a function of (a) current densities, (b) ...

Energy Technology Data Exchange (ETDEWEB)

The current work continues a project completed in 1999 by ReMaxCo Technologies in which a novel, microwave based, VLS Silicon Carbide Fibrils concept was verified. This project continues the process development of a pilot scale commercial reactor. Success will lead to sufficient quantities of fibrils to expand work by ORNL and others on heat exchanger tube development. A semicontinuous, microwave heated, vacuum reactor was designed, fabricated and tested in these experiments. Cylindrical aluminum oxide reaction boats are coated, on the inner surface, with a catalyst and placed into the reactor under a light vacuum. A series of reaction boats are then moved, one at a time, through the reactor. Each boat is first preheated with resistance heaters to 850 C to 900 C. Each reaction boat is then moved, in turn, to the microwave heated section. The catalyst is heated to the required temperature of 1200 C to 1300 C while a mixture of MTS (methyl trichlorosilane) and hydrogen are introduced ...

Energy Technology Data Exchange (ETDEWEB)

The role played by planetary boundary layer (PBL) in the development and evolution of a severe convective storm is studied by means of meso-scale modeling and surface and upper air observations. The severe convective precipitation event that occurred on 14 September 1999 in the northeast of the Iberian Peninsula was simulated by means of the mesoscale model MM5 (version 3) using three different PBL schemes. The numerical results show a large impact of the PBL schemes on the precipitation fields associated to the convective storm. The schemes are based on different physical assumptions: the nonlocal first order medium-range forecast (MRF) and blackadar (BLA) scheme and the local, one-and-a-half order ETA scheme. Surface and radar observations are used to validate the model results. The comparison focuses on three aspects: the evolution, the spatial distribution and the 24-h accumulated precipitation. The comparison with rain ...

UK PubMed Central (United Kingdom)

Brushite (CaHPO₄·2H₂O) was considered to govern the formation of renal calculus of calcium phosphate origin. The degree of saturation of urine with respect to this phase...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The role played by calcium sulfite in the flue gas desulfurization of lime/limestone scrubbers makes it desirable to work out its thermodynamic properties. A thermogravimetric apparatus was used to study the equilibria between calcium sulfite hemihydrate and calcium sulfite anhydrite under different conditions. Efforts were made to analyze the difficulties encountered in the dynamic approach to equilibration after calcium sulfate dihydrate failed in calibration of the apparatus. Finally, the kinetics and thermodynamics for the dissociation of calcium sulfite hemihydrate were examined. The confirmation of Engel-Brewer's correlation between the electronic configuration and crystal structure in metallic systems has long been pursued in this group by studying the Lewis-acid-base interactions. Tantalum-iridium alloys of different compositions were brought into equilibrium with ...

International Nuclear Information System (INIS)

Concentrations of tritium in environmental waters (precipitation, rivers, lakes, tap water) have been determined using electrolytic enrichment and liquid scintillation counting. In waters of big rivers (the Vistula and the Odra rivers), lakes and tap water the annual average concentrations were similar to each other being from 1.4 to 1.9 Bq x dm"-"3. These concentrations were similar to those in the precipitation in which they ranged from 1.7 to 2.2 Bq x dm"-"3. The lowest tritium concentrations were found in waters of the Seashore Region rivers (average for 1994-1999 was 1.1 Bq x dm"-"3). The tritium concentrations in surface waters and in precipitation are still higher than that of natural level. The data obtained show that tritium concentration in the water of rivers might depend on the size of drainage area. The observed seasonal variations of tritium concentration in the precipitation collected in ...

International Nuclear Information System (INIS)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth ...

Energy Technology Data Exchange (ETDEWEB)

With a pilot electrostatic precipitator having wider plate spacings than usual tests were performed under industrial conditions. In the two-section two-duct pilot precipitator with a precipitation area of 60 m/sup 2/ the plate spacing was increased up to 1,000 mm. As gas velocities values between 0.5 and 2.0 m/s were selected. The precipitator was tested with the flue gases of a coal-fired power station and in the room dedustion of an iron ore sintering plant. Starting with a plate spacing of 250 mm increasing the spacing results initially in a small increase of the precipitation rate. After reaching a maximum the rate decreases and finally with passing a critical spacing it goes below the initial value. Dedusting flue gases the spacing with the maximum and the critical spacing depend on the gas velocity. Cost analyses demonstrate that increasing the up to now used plate spacings ...

International Nuclear Information System (INIS)

This paper presents the results of experimental study carried out to know whether the salicylic acid used as an additive during the precipitation of zirconium using ammonium hydroxide solution goes into the filtrate, remains in the hydrated zirconia or gets distributed between the both under the ambient conditions of precipitation. Keeping its simplicity and amenability to adopt on a routine basis, spectrophotometric method has been chosen for the purpose among the many methods available and the problems associated in determining salicylic acid in the presence of zirconium and the medial measures to circumvent the same have been brought out in detail. (author)

Energy Technology Data Exchange (ETDEWEB)

This paper reports the presence of face centered cubic cobalt precipitates inside tungsten carbide in nanocomposite of WC-Co synthesized by spray conversion processing. EDS was used to identify the presence and micro-diffraction was employed to determine the nature of the precipitates. There is entrapment of cobalt in tungsten carbide during the spray conversion process used to form WC/Co powder. During consolidation, at high temperatures, the cobalt attains enough mobility to precipitate inside WC. A vanadium containing compound was seen at the interfaces in samples which incorporated VC as a grain growth inhibitor. (orig.)

Science.gov (United States)

Homestake Ore from the Ambrosia Lake District of New Mexico was treated in the Alkaline Leach-- Filtration Pilot Plant at Grand Junction, Colorado. Detailed information on grinding, leaching, flltration, and precipitation in connection with the processing of this ore is given. Autoclave leaching and continuous yellow cake precipitation were employed. The circuit liquors contnined organic material that was detrimental to clariflcation and precipitation and the results show that ihe ore was amenable to the Alkaline Leach--Filtration process only if a special additive was used. (auth)

International Nuclear Information System (INIS)

The #beta#-CEZ alloy : Ti-5%Al-2%Sn-4%Zr-4%Mo-2%Cr-1%Fe is a near #beta# titanium alloy. Since its processing routes include heat treatment (consisting of solution treatment and ageing), it has been decided to study the influence of the #beta# phase stability on #alpha# phase precipitation and hardening kinetics. Small sized specimens, coming from industrial heats, have been heat treated above and below the #beta# transus, and then water quenched. Therefore, several degree of #beta# stability are obtained. When it is increased (i.e. the solution treatment temperature is lowered), #alpha# or #omega# phases precipitations are delayed, as well as the hardening phenomena. Moreover, the #omega# stability domain is reduced. The mechanisms of #alpha# or #omega# precipitation are discussed, and related to the hardening kinetics. (orig.).

Science.gov (United States)

... to the north of the Qinling, through mixed deciduous broad-leaved forest at lower mountain elevations, and conifer forest at ... ...

Energy Technology Data Exchange (ETDEWEB)

Alloying elements such as Fe and Cr are generally considered to be effective even in small quantities for corrosion resistance of Zircaloy-4. The maximum total solubility of Fe + Cr in a Zr-Sn matrix has been reported to be very low. Therefore, most of these elements are observed in the form of ternary Zr-Fe-Cr-type precipitates. To clarify the effects of precipitates on corrosion property, Zr-1.3 Sn-(Fe,Cr) alloys containing Fe + Cr from 45 up to 180 ppm (the Fe to Cr ratio is about 2) were melted from pure zirconium (X-bar Zr and EB-Zr) and pure alloying elements. They were subjected to corrosion testing in 633 K water and microstructural analysis. It was found that precipitate-free materials showed much larger weight gains than precipitate-containing materials even at the same alloy compositions. Subsequently, a corrosion test on the precipitate-free material galvanically coupled ...

Science.gov (United States)

Calcium-activated chloride channels (CaCCs) are widely expressed in mammalian tissues, including intestinal epithelia, where they facilitate fluid secretion. Potent, selective CaCC inhibitors have not been available. We established a high-throughput screen for identification of inhibitors of a human intestinal CaCC based on inhibition of ATP/carbachol-stimulated iodide influx in HT-29 cells after lentiviral infection with the yellow fluorescent halide-sensing protein YFP-H148Q/I152L. Screening of 50,000 diverse, drug-like compounds yielded six classes of putative CaCC inhibitors, two of which, 3-acyl-2-aminothiophenes and 5-aryl-2-aminothiazoles, inhibited by >95% iodide influx in HT-29 cells in response to multiple calcium-elevating agonists, including thapsigargin, without inhibition of calcium elevation, calcium-calmodulin kinase II activation, or cystic fibrosis transmembrane conductance ...

Science.gov (United States)

No abstract available.

International Nuclear Information System (INIS)

Short communication.

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

Abstract only.

International Nuclear Information System (INIS)

A series of #alpha#-sialon (#alpha#') compositions containing mixed stabilising cations were prepared, by introducing additional CaO to a basic Sm #alpha#-sialon compositions. The thermal stability of these Sm-Ca-containing #alpha#-sialon phases was investigated using XRD, SEM and EDXS techniques. It was found that the addition of calcium into the Sm #alpha#-sialon systems greatly improved the stability of the #alpha#-sialon phases. Calcium was found to be incorporated into the #alpha#-sialon structure, coexistent with the samarium, and partitioning of the calcium and samarium was observed between the #alpha#' phase and grain boundary phases. This indicates a technique which may be used to improve the thermal stability of the #alpha#' phase while maintaining good refractory phases at the sialon grain boundaries.

International Nuclear Information System (INIS)

A study was made on extraction of a series of lithium and calcium salts by monopodands L with common formula R-C_6H_4-O-(CH_2CH_2O)_n-C_6H_4-R, where R - CH_2P(O)Ph_2, n 1-3. Extraction-chromatographic separation of lithium and calcium isotopes in systems of metal aquacomplex-solvatocomplex with L in organic phase was conducted. It was established that separation coefficients of "6Li/"7Li isotopes ranged between 1.003 #+-#0.001 and 1.017 #+-#0.002 at the maximal separation degree equal to 1.60. Separation of "4"0Ca/"4"4Ca isotopes was not fixed. 12 refs., 4 figs., 1 tab.

British Library Electronic Table of Contents (United Kingdom)

The objective of materials research is the development of economical, safe and efficient synthesis routes that lead to the formation of a photocatalyst which is able to overcome performance problems related to particle size, crystallinity, or low surface area. Here, we report high-quality functional nanoparticles of calcium bismuth mixed oxide with 15nm nominal size corresponding to a specific surface area of 41m^2/g which were produced by single-step flame spray synthesis (FSS). The high temperature of the flame afforded creation of oxygen vacancies which were quantified by near edge X-ray absorption fine structure (NEXAFS) spectra. These two parameters, developed active surface area and created in the flame oxygen vacancies, allowed to enhance the photocatalytic activity of calcium bismu...

Energy Technology Data Exchange (ETDEWEB)

To examine the hormonal regulation of the ATP-dependent Ca{sup 2+} pump in the kidneys, the ATP-dependent Ca{sup 2+} uptake by the basolateral membrane vesicles in the renal cortex was measured using radioactive calcium ({sup 45}Ca{sup 2+}) in rats with vitamin D deficiency or rats undergoing thyroparathyroidectomy. The V{sub max} of the Ca{sup 2+} pump activity was increased not only by administering calcitriol, but also by normalizing the serum calcium level in vitamin D-deficient rats. PTH suppressed the Ca{sup 2+} pump activity in normocalcemic vitamin D-deficient rats. Thyroparathyroidectomy did not affect the Ca{sup 2+} pump activity in the kidneys of normal rats. It was concluded that the ATP-dependent Ca{sup 2+} pump activity was depressed by secondary hyperparathyroidism in vitamin D-deficient rats. (author).

International Nuclear Information System (INIS)

This paper describes stable strontium as composed of four stable isotopes ( Sr 88, Sr 87, Sr 86, and Sr 84), of which Sr 88 contributes more than 82% to its composition. Strontium exists in three crystalline, plymorphic forms; face-centered cubic alpha form, hexagonal beta form and body-centered cubic gamma form. Strontium occupies in many physicochemical aspects an intermediate position between calcium and barium, as does the solubility of strontium salts. As a result of its oxidation potential, strontium readily forms oxides, halides, and sulfide. The author proposes that the slight discrimination against strontium incorporation into bony tissues may be due to the difference in ionic potential (14%) between strontium and calcium. Ionic potential is an indicator of the strength of ionic bonds: strontium has a smaller ratio of ionic charge to ionic radius when compared with calcium.

Energy Technology Data Exchange (ETDEWEB)

The work reported here concerns the evolution of the shape of a coherent, cubic precipitate as it grows by coarsening. The work was motivated by the need to explain recent experimental observations that show that cuboidal ..gamma.. Ni/sub 3/Al precipitates in Ni-Al alloys resist coarsening and decompose into doublets of parallel rectangular plates and octets of small cubes. The theoretical model assumes a precipitate of cubic phase with negative elastic anisotropy, and neglects any difference between the elastic constants of the precipitate and the matrix. The elastic energy of the precipitate is then calculated as a function of its morphology, including the possibility of decomposition into doublets or octets of discrete particles. The results show that a cuboidal precipitate with (100) faces and edge length, 2a, is metastable with respect to transition to a ...

UK PubMed Central (United Kingdom)

Selected sera from cattle naturally infected with Brucella abortus precipitate water soluble antigens extracted by sonication from B. abortus. One of these antigens resembles antigen E (Baughn and Freeman)...Full Text Available

International Nuclear Information System (INIS)

This paper reviews the mill flowsheet applied at the SOMAIR (Societe des Mines de l'Air) uranium mill in Niger. It focuses on the yellow cake quality improvements achieved by molybdenum and zirconium elimination through double yellow cake precipitation in tanks at first stage and through size/density control in a fluidized bed precipitator at second stage. Water saving aspects in the plant are also presented. (author)

Energy Technology Data Exchange (ETDEWEB)

Carbide reactions occurring in a precipitation-hardening gamma/gamma-prime Ni-Cr alloy during prolonged high-temperature aging are investigated experimentally. It is found that the decomposition of primary MC carbides, which is accompanied by the precipitation of M23C6 particles, may lead to void nucleation and growth. The effect of carbide transformations on the residual properties of the material at temperatures above the equicohesion temperature is observed at the late stages of aging only. 6 references.

Energy Technology Data Exchange (ETDEWEB)

YIG precursor powder was obtained by homogeneous precipitation in chloride salt solution by thermal decomposition of urea. It was found that ferric ions precipitated prior to yttrium ions. The precipitate was minute and spherical in shape. The precipitate formed consisted of the mixture of amorphous and ferric oxyhydroxide. Crystallization of YIG was proceeded by solid state reaction of intermediate YFeO{sub 3} and Fe{sub 2}O{sub 3} in the temperature range of 850 deg. C to 1400 deg. C. Single phase of YIG was obtained by heat-treatment of the powder at 1400 deg. C for 6 hrs in air. The powder calcined was molded into pellets and sintered in air. The maximum density of 4.92 g/cm{sup 3} (95.1% of theoretical density) was obtainable for the pellet sintered at 1450 deg. C using the powder calcined at 900 deg. C. (author) 20 refs., 8 figs., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

Anisotropy finite element analysis was performed to study stresses associated with the tetragonal precipitates and the tetragonal to monoclinic transformation in MgO partially stabilized zirconia. Stresses were assumed to be caused by the lattice misfits between the product phase and the parent phase. In the finite element calculations, the tetragonal and monoclinic precipitates were assumed to be lenticular in shape, and the anisotropic elastic constants of the cubic, tetragonal and monoclinic phases were considered. The purpose of this paper is to obtain some knowledge about how stresses respond when the microstructure is changed, and how stress fields affect microstructure development. The finite element results show that increasing a{sub t}/a{sub c} and decreasing c{sub t}/a{sub c} can create a favorable stress field to reduce the growth rate of tetragonal precipitates during the heat treatment. Stresses associated with ...

UK PubMed Central (United Kingdom)

BackgroundChanges in ionic concentration have a fundamental effect on numerous physiological processes. For example, IP₃-gated thapsigargin sensitive intracellular calcium...Full Text Available

UK PubMed Central (United Kingdom)

SUMMARYIn voltage-gated sodium, potassium, and calcium channels the functions of ion conduction and voltage sensing are performed by two distinct structural units: the pore domain...Full Text Available

UK PubMed Central (United Kingdom)

Dominant mutations in sarcomere protein genes cause hypertrophic cardiomyopathy, an inherited human disorder with increased ventricular wall thickness, myocyte hypertrophy, and disarray. To understand...Full Text Available

UK PubMed Central (United Kingdom)

Secondary caries and restoration fracture remain the two most common problems in restorative dentistry. Release of fluoride ions (F) could be a substantial benefit because F could enrich neighboring...Full Text Available

UK PubMed Central (United Kingdom)

The transport of serine into tobacco (Nicotiana tabacum L. var. Xanthi) cells grown in liquid medium was studied. Serine transport was maximal below pH 4.0. A time-dependent stimulation...Full Text Available

UK PubMed Central (United Kingdom)

Measurements were made of ⁴⁵Ca influx into isolated internodal cells of Chara corallina and also into internodal cells of intact plants. ⁴⁵Ca influx was closely...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid.

Energy Technology Data Exchange (ETDEWEB)

In the framework of the feasibility study of radioactive waste disposal in deep geologic formations, a clay formation (named 'argilite de l'Est') has been selected in the Meuse-Haute Marne region (France) for the construction of an underground laboratory. The percolation of alkaline solutions through the argilite has been studied using column experiments with short residence times (30 min). These experiments simulate the leaching of a cement which could be used in the building materials of the laboratory. The alkaline solutions used are mono-cationic solutions of calcium, sodium and strontium. The behaviour of calcium is differentiated from the other cations. For all alkaline solutions (NaOH, Ca(OH){sub 2} or Sr(OH){sub 2}) chemical reactions consuming both hydroxide ions and their associated cations have been evidenced. These reactions are heterogenous reactions of surface adsorption by site ionization. The ...

UK PubMed Central (United Kingdom)

Edema factor (EF) and CyaA are calmodulin (CaM)-activated adenylyl cyclase exotoxins involved in the pathogenesis of anthrax and whooping cough, respectively. Using spectroscopic, enzyme kinetic and...Full Text Available

UK PubMed Central (United Kingdom)

Segments of the chick basilar papilla were isolated and maintained in culture medium. The sensory hair bundle of individual hair cells was observed with light microscopy and stimulated with a water...Full Text Available

UK PubMed Central (United Kingdom)

The proprotein convertases (PCs) are calcium-dependent proteases responsible for processing precursor proteins into their active forms in eukariotes. The PC1/3 is a pivotal enzyme of this family that...Full Text Available

UK PubMed Central (United Kingdom)

INTRODUCTION:Gynura procumbens has been shown to decrease blood pressure via inhibition of the angiotensin‐converting enzyme. However, other mechanisms that...Full Text Available

UK PubMed Central (United Kingdom)

The objective of this experiment was to determine the effect of dietary grain on calcium homeostasis. Six rumen-fistulated dairy cows with 3 or more previous lactations and no history of parturient...Full Text Available

UK PubMed Central (United Kingdom)

A novel therapeutic compound was found to induce bladder tumors in male rats. Given the location of the tumors and the increased amounts of calcium- and magnesium-containing solids found in the urine...Full Text Available

DEFF Research Database (Denmark)

Citrate is an important naturally occurring inhibitor of calcium stone formation in urine. Urinary citrate excretion was examined in 43 consecutive patients with recurrent idiopathic calcium nephrolithiasis and in 50 normal controls by a specific enzymatic technique. Hypocitraturia (<1.6 mmol/24h) was found in 14 (33%) stone formers compared to 6 (12%) normal controls (p = 0.03). Citrate excretion expressed as citrate-creatinine ratio in 24 hour urine samples was significantly lower in the stone formers than in the healthy controls (p = 0.03), and significantly lower in healthy men, compared to healthy females (p = 0.006). There was a great variability in urinary citrate levels in both groups, and a considerable overlap in the urinary citrate excretion between normal subjects and stone formers. Factors other than urinary citrate excretion must therefore be of importance in the pathophysiology of calcium stone formation. ...

UK PubMed Central (United Kingdom)

PurposeThe aim of this study was to evaluate 3.5 years-cumulative survival rate of implants placed on augmented sinus using Osteon, a bone graft material, and to assess the height...Full Text Available

UK PubMed Central (United Kingdom)

1. Digital imaging and photometry were used in conjunction with the fluorescent Ca2+ indicator, Fura-2, to examine intracellular Ca2+ signals produced by depolarization of single adrenal chromaffin...Full Text Available

UK PubMed Central (United Kingdom)

E-cadherins belong to a family of membrane-bound, cellular adhesion proteins. Their adhesive properties mainly involve the two N-terminal extracellular domains (EC1 and EC2). The junctions between these...Full Text Available

UK PubMed Central (United Kingdom)

Calcium ions represent universal second messengers within neuronal cells integrating multiple cellular functions, such as release of neurotransmitters, gene expression, proliferation, excitability,...Full Text Available

DEFF Research Database (Denmark)

The aim of the present study was to test a mathematical model of the biochemical processes in the parathyroid glands responsible for the secretion of parathyroid hormone resulting from extracellular calcium reduction. A double exponential curve described the parathyroid hormone secretion induced by rapid lowering of blood-ionized calcium in humans with normal as well as abnormal parathyroid tissue. Our data show that it was possible to establish a simple mathematical model of the parathyroid hormone response to blood-ionized calcium lowering, sufficient to fit experimental data obtained from patients with abnormal and normal parathyroid tissue. The fitted parameters showed no significant differences between patients with insulin-dependent diabetes mellitus and controls. In primary hyperparathyroidism, the parathyroid hormone production and steady-state transport across the cell membrane were increased, probably due to the ...

Science.gov (United States)

Significant progress has been achieved recently in the growth of Yttrium Calcium Oxyborate (YCOB) crystals. Boules have been grown capable of producing large aperture nonlinear crystal plates suitable for high average power frequency conversion or optical parametric chirped pulse amplification (OPCPA). With a large aperture (5.5 cm x 8.5 cm) YCOB crystal we have demonstrated a record 227 W of 523.5nm light (22.7 J/pulse, 10 Hz, 14 ns). We have also demonstrated the applicability of YCOB for 1053 nm OPCPA.

International Nuclear Information System (INIS)

Multi-cation #alpha#-Sialon ceramics were prepared using mixtures of samarium with calcium, magnesium, yttrium and ytterbium, and compared with a pure Sm-Sialon of equivalent total stabilising cation composition. A ratio of 80eq% samarium to 20eq% of the second stabilising additive was used. Samples were fired at 1820 deg C and subsequently heat treated at 1450 deg C. XRD phase analysis showed that all additives resulted in greater #alpha#-Sialon stability, and that calcium was the most effective additive for the stabilisation of the #alpha#-Sialon phase. Copyright (1998) Australasian Ceramic Society

British Library Electronic Table of Contents (United Kingdom)

A new coumarin-based sensor molecule (L1) has been synthesized and this was found to bind calcium and magnesium ions more effectively as compared to other alkali/alkaline earth/lanthanide and certain transition metal ions. A significant enhancement in fluorescence intensity was observed on binding to Ca2+ and Mg2+ ions; while a minor quenching was observed for weakly bound Hg2+, Ni2+, Fe3+, and Co2+ ions. PET process, coupled with the ICT process, is proposed to explain the observed spectral response.

International Nuclear Information System (INIS)

The influence of microalloying vanadium or titanium on improving the corrosion resistance of mild steel in saturated calcium hydroxide solution was investigated. Potential-time, potentiodynamic polarization, and impedance measurement techniques were employed. The corrosion products have been examined by infrared and X-ray diffraction analysis and by scanning electron microscopy. It has been shown that the grain refining, due to microalloying, plays an important role in enhancing the corrosion resistance of steel. Scales of calcite and iron oxides on top of a protective oxide are formed on the investigated steels.

Energy Technology Data Exchange (ETDEWEB)

This paper describes an exact solution to the problem of absorbing nitrogen dioxide into aqueous solution, in which case the nitrogen dioxide concentration is allowed to vary over a wide range. The authors have worked on the rate of calcium sulfate dihydrate scale formation on the reverse osmosis membrane and find this phenomena can be treated by the crystallization theory. The authors performed long-term experiments using calcium sulfate dihydrate solution with addition of sodium hexametaphosphate (SHMP) and commercially available organophosphates and investigated the mechanism of the inhibitor's action quantitatively.

Energy Technology Data Exchange (ETDEWEB)

The carbon cycle is an important part of major biogeochemical cycles. Many techniques may be used to characterize carbon amounts and sources in the environment. Here we first review the most popular techniques for the determination of organic and inorganic carbon concentrations. Decarbonatation techniques are also reviewed in details since it is often an important part of organic carbon analysis. The second part of this paper addresses the use of carbon stable isotopes to characterize organic carbon sources and processes in the environment. An overview of general stable isotopes background and terminology is given as well as the most popular analytical techniques.

Energy Technology Data Exchange (ETDEWEB)

Carbon supported catalysts can lose their activity over a period of time due to the sintering of the nanometer-sized catalyst particles. The sintering of metal clusters on carbon supports can occur due to the weak interaction between the metal and the support and also due to the corrosion of carbon, especially in fuel cell electrocatalysts. The sintering may be reduced by increasing the interaction between the metal and the support and also by increasing the corrosion resistance of carbon supports. In an effort to mitigate the growth of the nanoparticles, carbon-substituted boron defects were introduced in the carbon lattice. The interaction between the Pt nanoparticles on the pure and boron-doped carbon supports was examined using X-ray photoelectron spectroscopy (XPS). The results indicate that the interaction between the Pt nanoparticles ...

International Nuclear Information System (INIS)

The principle for working out the time-temperature schedule of the carbonization was determined through the investigation on the carbonization process of the green body and the phenol formaldehyde resin. During the carbonization process, the crack at lower temperatures is due to strain inhomogeneity produced in press. But the crack at higher temperatures results from the improper increasing rate of temperature. The application of the autoclave-carbonization process can increase the mechanical properties of the spherical fuel elements.

Energy Technology Data Exchange (ETDEWEB)

This critical review with 28 references examines absorption and emission in the v2 band of the carbon dioxide molecule at around the 15micron wavelength. The argument for additional infrared absorption, the enhanced greenhouse effect due to increased carbon dioxide concentrations, and radiation transport and increased emissions are discussed. Experiments studying the transmission spectra of pure carbon dioxide and carbon dioxide in nitrogen, and comparing them with the results of climate modelling using the HITRAN and GEISA databases, are described.

International Nuclear Information System (INIS)

An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements

International Nuclear Information System (INIS)

Studies on the separation of Ag(I) during the recovery of Pu from analytical waste generated during potentiometric determination of Pu using AgO as oxidant, by precipitation of Pu as ammonium plutonium (III) oxalate have shown that most of the Ag(I) is separated during the reduction of Pu to Pu(III) state by ascorbic acid. A decontamination factor of 54 was obtained. Additional a decontamination factor of 5.8 was obtained during the precipitation of Pu as ammonium plutonium (III) oxalate. The Ag content was determined by gamma spectrometry, using "1"1"1Ag as a tracer (T_1_/_2 7.45 d, #gamma# 342.1 keV) and HPGe as detector. The studies indicate that Ag is preferentially separated almost quantitatively during the recovery of plutonium, when acidity adjustment is done with NaOH instead of NH_3. (author)

Energy Technology Data Exchange (ETDEWEB)

Whilst unwashed preparations of biomass from a local brewery had an apparent maximum biosorption capacity for uranium of 360 mg/g (dry weight biomass) washing reduced this maximum to 150 mg/g. Homogenization of both biomass preparations and recovery of cellular debris had no significant effect on the maximum biosorption capacities although at lower equilibrium concentrations of uranium differences in the biosorption capacities were detected. When unwashed biomass was retained by a semi-permeable membrane 40% of uranium used in the experiments precipitated outside that membrane. Therefore a significant proportion of the uranium removed from solution, and previously attributed to biosorption by the yeast biomass, resulted from precipitation brought about by interaction with low molecular weight components loosely associated with the biomass. (Author).

International Nuclear Information System (INIS)

In this work the calculation of the average precipitation in the Quito River basin, state of Choco, Colombia, is presents through diverse techniques, among which are those suggested by Thiessen and those based on the isohyets analysis, in order to select the one appropriate to quantification of rainwater available to the basin. Also included is an estimation of the error with which the average precipitation in the zone studied is fraught when measured, by means of the methodology proposed by Gandin (1970) and Kagan (WMO, 1966), which at the same time allows to evaluate the representativeness of each one of the stations that make up the rain gauge network in the area. The study concludes with a calculation of the hydrologic balance for the Quito river basin based on the pilot procedure suggested in the UNESCO publication on the study of the South America hydrologic balance, from which the great contribution of rainfall to a greatly enhanced ...

International Nuclear Information System (INIS)

Intergranular corrosion (IGC) resistance of types 304LN and 316LN stainless steels (SS) thermally aged at 823, 873, and 923 K for various durations was assessed by ASTM A262 practice A test (electrolytic etch test) and electrochemical potentiodynamic reactivation (EPR) test. The results indicated that the type 316LN SS has significantly improved IGC resistance compared to 304LN SS. Based on the results of these tests, time-temperature-sensitization (TTS) diagrams were developed for both alloys. The secondary precipitates formed during thermal aging treatments were electrochemically extracted and analyzed by X-ray diffraction (XRD) to determine the types of precipitates formed during the aging treatments. The results indicated that the precipitates were mostly of M_2_3C_6 carbides.

International Nuclear Information System (INIS)

It is essential that alumina used for manufacturing electronic devices should contain an extremely low level of alpha-radiation. The principal source of alpha-radiation in alumina is uranium, a minor source being thorium. Uranium in bauxite dissolves into the liquor in the digestion process and is fixed to the red mud as the desilication reaction progresses. A part of uranium remaining in the liquor precipitates together with aluminum hydroxide in the precipitation process. The uranium content of aluminum hydroxide becomes lower as the precipitation velocity per unit surface area of the seed becomes slower. Organic matters in the Bayer liquor has an extremely significant impact on the uranium content of aluminum hydroxide. Aluminum hydroxide free of uranium is obtainable from the liquor that does not contain organic matters.

UK PubMed Central (United Kingdom)

The carbon-isotope ratio recently obtained for the carbon found in the Murchison meteorite, which has been shown (by the racemic nature of twelve component amino acids) to be free of terrestrial contamination,...Full Text Available

UK PubMed Central (United Kingdom)

Carbon dioxide is a waste product of aerobic cellular respiration in all aerobic life forms. PaCO₂ represents the balance between the carbon dioxide produced and that eliminated. Hypocapnia...Full Text Available

International Nuclear Information System (INIS)

The compressive and torsional buckling behavior of carbon nanotube bundles at room temperature is examined with classical molecular dynamics simulation. The critical compressive load and stiffness of a single carbon nanotube in the bundle are found to be similar to those of individual carbon nanotubes. However, the critical torsional moment and stiffness of a single carbon nanotube in the bundle are found to be higher than those of individual carbon nanotubes. In addition, this study demonstrates that van der Waals interactions between the nanotubes in the bundle significantly affect the critical compressive load of the nanotube bundle.

International Nuclear Information System (INIS)

The effects of alloying elements and precipitated phases on the corrosion rate of high alloy OCTG in the ferric chloride solution have been evaluated. The corrosion rate of Fe-Cr-Ni-Mo alloys without precipitated phases, e.g. carbides and sigma phase, can be estimated from the composition using the following equation: log(C.R.)=-0.144xPRE-7690/(273+T)+28.6 where C.R. is the corrosion rate in g/m/sup 2//hr; PRE is Cr+3Mo+16N in percent and T is the test temperature in "0C. The activation energies of the ferric chloride test are almost the same regardless of PRE or Ni content when no detrimental phase precipitates. When carbides or the sigma phase precipitate, the corrosion rate is higher and the activation energy is lowered. This suggests that secondary phases give preferential sites for initiation of pitting corrosion.

UK PubMed Central (United Kingdom)

Antibodies of the IgM type present in rabbit anti-epiglycanin antiserum were purified by (NH4)2SO4 precipitation and by ion-exchange, affinity and gel-filtration chromatography. After papain treatment...Full Text Available

UK PubMed Central (United Kingdom)

Tendon reconstruction using grafts often results in adhesions that limit joint flexion. These adhesions are precipitated by inflammation, fibrosis, and paucity of tendon differentiation signals...Full Text Available

International Nuclear Information System (INIS)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. In the previous paper, corrosion mechanism was elucidated by the anodic protection-precipitates degradation model. This paper describes the roles on hydrogen pickup. 633 K pure water autoclave test was performed on high purity zirconium, Zr-0.2Fe, Zr-0.2Cr, and Zr-0.1Fe-0.1Cr alloys. Hydrogen analysis after the corrosion test showed that hydrogen pickup ratio of Zr-0.2Fe alloy was about 80%. It was much higher than about 30% of pure Zr and about 10% of both Zr-0.2Cr and Zr-0.1Fe-0.1Cr alloys. Larger hydrogen content was introduced into Zr-0.2Fe alloy than the other ones by the cathodic hydrogen charging under coulombic equivalence. The precipitates at metal-oxide interface could act not only as ...

International Nuclear Information System (INIS)

The applicability of two nuclear analytical methods: radionuclide X-ray fluorescence analysis and radiometric titrations based on precipitate formations was studied in order to determine the heptacaine hydrochloride in solutions. The applied methods were evaluated based on the obtained sensitivity values. (author).

Science.gov (United States)

... 45 SW Staff and NASA on movement, intensity, weather conditions, ...... a) All surfaces of the vehicle susceptible to precipitation particle impact have been ... hydrometeors falling through the 0 deg C level and beginning to melt. ...

Science.gov (United States)

Methods of acidizing a subterranean well formation, acidizing compositions, and sequestering additives for preventing the precipitation of metal compounds in the formation are described. Use of the methods and chemicals described should lead to improved formation permeability as compared to use of previous methods and chemicals. 12 claims.

Science.gov (United States)

Mar 1, 2011 ... The movement of hydrothermal fluids and/or fumarolic vapors through local rocks prior ... The Solar Energetic Particle Event of December 14, 2006 .... for measurement of non-precipitating cloud hydrometeors and aerosols, ...

Energy Technology Data Exchange (ETDEWEB)

We prepared cathodes with various types of activated carbon and measured the cathodes' electrochemical performance according to the kind of activated carbon. Activated carbon supplies airflow channels and reaction sites in the cathode of zinc air batteries. When we use activated carbon with a high specific surface area as the cathode's catalyst substrate, we expect high electrochemical performance because this type of carbon provides more air flow channels and reaction sites. We focused on investigating the relationship between the cathode's pore structure and its electrochemical characterizations. We also studied the effects of the various activated carbon materials on the zinc air batteries' performance. Increasing the macropores or mesopores in the activated carbon resulted in achieving more power from ...

Science.gov (United States)

... rate on the tensile properties of SA-106 carbon steel pipe, in support of analysis and experimental modeling of postulated pipe whip in nuclear ...

Science.gov (United States)

... The fuel proposed was a medium-thermal carbon black-liquid JP-i1 mixture. JP-iO or exo-tetrahydrodi (cyclopentadieue) is a pure hydrocarbon with ...

Energy Technology Data Exchange (ETDEWEB)

Ab initio planewave pseudopotential method is used to study carbon diffusion and pairing in crystalline silicon. The calculation is performed with a 40 Ry planewave cutoff and 2x2x2 special k-point sampling with a supercell of 64 atoms. It is found that substitutional carbon attracts interstitial Si forming a <001> C interstitial with a large binding energy of 1.45 eV. The interstitial carbon is mobile and can migrate with a migration energy of 0.5 eV. The interstitial carbon can bind further to another substitutional carbon forming a substitutional carbon-interstitutional carbon pair with a binding energy of 1.0 eV. This model is used to understand the effect of high C concentration on the transient enhanced diffusion in Si.

Energy Technology Data Exchange (ETDEWEB)

The present study was designed to investigate, in more detail, the mechanism of lead transport by the gastrointestinal tract and particularly the similarities or dissimilarities between lead and calcium in this process. The absorption of these metals was determined in 3-week-old white Leghorn cockerels, raised on a commercial diet or special diets, using an in vivo ligated loop procedure. The dose administered into the loop usually contained 0.5 ..mu..Ci /sup 203/Pb (and/or 0.1 ..mu..Ci /sup 47/Ca), 0.01 mM lead acetate (and/or 1 mM CaCl/sub 2/) in 0.5 ml of 0.15 M NaCl, pH 6.5. It was shown that lead is rapidly taken up by the intestinal tissue, and only slowly transferred into the circulation whereas calcium, also accumulated rapidly by the tissue, is rapidly released from the tissue in the serosal direction. The absorption processes of these cations show similar responses to various experimental conditions (low calcium ...

International Nuclear Information System (INIS)

The chemical separation of carrier-free "2"0"3Pb following deuterium bombardment of a "2"0"3Tl target is described. Coprecipitation from strontium sulphate was used to separate the "2"0"3Pb from a solution of the thallium target in sulphuric acid. The SrSO_4 precipitate was filtered, washed and dissolved in hydrochloric acid, from which "2"0"3Pb was again separated by precipitation on sodium chloride from a strongly acid solution. Advantages of the system are discussed and optimum conditions given. (U.K.).

Energy Technology Data Exchange (ETDEWEB)

The chemical separation of carrier-free /sup 203/Pb following deuterium bombardment of a /sup 203/Tl target is described. Coprecipitation from strontium sulphate was used to separate the /sup 203/Pb from a solution of the thallium target in sulphuric acid. The SrSO/sub 4/ precipitate was filtered, washed and dissolved in hydrochloric acid, from which /sup 203/Pb was again separated by precipitation on sodium chloride from a strongly acid solution. Advantages of the system are discussed and optimum conditions given.

Science.gov (United States)

Metallic contamination was monitored with Surface Photovoltage (SPV) technique in integrated circuit manufacturing facilities. Conventionally, Czochralski silicon bulk materials were used as monitor wafers. However, it has been observed that the diffusion length and the `Iron' concentration measured with SPV were inconsistent from run to run in one facility. The inconsistency is believed to be due to oxygen precipitate in silicon materials during the thermal cycle. By using low oxygen concentration or Float Zone wafers, metallic contaminants can be monitored more accurately and consistently.

Energy Technology Data Exchange (ETDEWEB)

Time-temperature-precipitation diagrams have been established for two steels with 6% Mo, 21% Cr, 25% Ni, 0.14 and 0.19% N (Cronifer 1925 h Mo = 1.4529, UNS N 08925) and for one steel with 6% Mo, 20% Cr, 18% Ni and 0.21% N (UNS S 31 254). The corresponding time-temperature-sensitization diagrams (in accordance to SEP 1877/II) and time-temperature-pitting diagrams (testing in 6% FeCl{sub 3} solution) have been evaluated as well. Precipitation of intermetallics occurs rapidly especially in the range between 700 and 1000{sup 0}C. In case of the 18% Ni steel and the 25% Ni/0.14% N steel grain boundaries are covered to a large extent with precipitates after only 15 min at 850 or 950{sup 0}C. In case of the 25% Ni/0.19% N steel precipitation is considerably slower. Therefore, when welding according to established rules and recommendations, no deterioration of the corrosion resistance in the heat-affected zone ...

Energy Technology Data Exchange (ETDEWEB)

A process is described for removing carbon dioxide from a feed stream of natural gas, having at least methane, ethane and heavier hydrocarbon, comprising: separating the feed stream in a first separator to form a first stream, having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane, and a second stream, having methane, carbon dioxide and ethane; mixing the second stream with a polar compound to form a third stream; separating the vapor and liquid of the third stream in the bottom portion of an absorber; absorbing carbon dioxide and ethane from the separated vapor of Step C in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane forming a fourth stream; separating the ethane from the polar compound and carbon dioxide in a separator; separating the first stream in a third separator to ...

Energy Technology Data Exchange (ETDEWEB)

The paper gives results of a study to identify active sites and surface functional groups that may contribute to the absorption of elemental mercury (Hg) by relatively inexpensive calcium (Ca)-based sorbents. The study investigated the formation of chlorine (Cl) sites in CA-based sorbents as well as their role and reactivity in the absorption of Hg. HCl-exposed calcium sulfate dihydrate (gypsum) exhibited a superior Hg sorption capability. Crystalline water molecules on the surface of the gypsum were confirmed to contribute indirectly to Hg uptake. These surface molecules may have absorbed HC1 through hydrogen bond formation between an oxygen atom of a crystalline water molecule and a hydrogen atom of an HCl molecule. Two adjacent, physically absorbed HCl molecules could then trap an Hg molecule through formation of a mercuric-chloride-like molecule. Significant correlations between Cl and Hg uptake by gypsum were noted.

Energy Technology Data Exchange (ETDEWEB)

In vivo effects of toxaphene on calcium pump activity in rat brain synaptosomes was studied. Male Sprague-Dawley rats were dosed with toxaphene at 0,25,50, and 100 mg/kg/day for 3 days and sacrificed 24 h after last dose. Ca/sup 2 +/-ATPase activity and /sup 45/Ca uptake were determined in brain P/sub 2/ fraction. Toxaphene inhibited both Ca/sup 2 +/-ATPase activity and /sup 45/Ca/sup 2 +/ uptake and the inhibition was dose dependent. Both substrate and Ca/sup 2 +/ activation kinetics of Ca/sup 2 +/-ATPase indicated non-competitive type of inhibition as evidenced by decreased catalytic velocity but not enzyme-substrate affinity. The inhibited Ca/sup 2 +/-ATPase activity and Ca/sup 2 +/ uptake were restored to normal level by exogenously added calmodulin which increased both velocity and affinity. The inhibition of Ca/sup 2 +/-ATPase activity and Ca/sup 2 +/ uptake and restoration by calmodulin suggests that toxaphene may impair active calcium ...

Energy Technology Data Exchange (ETDEWEB)

The present paper deals with the fouling process of calcium sulfate dehydrate on heat-transfer surfaces. The crystallization of calcium sulfate showed typical asymptotic fouling curves, the asymptotic value of which was greatly influenced by the surface temperature and fluid velocity. The fouling mechanism was discussed with a generalized fouling model and proved to be surface process controlled, where the activation energy was 6.2 {times} 10{sup 4} J/mol. The availability of mechanical cleaning against the formed scale was quantitatively evaluated by applying the particle abrasion method. The removal test verified that the removing rate per unit particle concentration decreased in an inverse proportion to the overall particle load, to the power of 0.8, and that it was affected by the fluid velocity. The observed final residual fouling resistance decreased asymptotically with an increase in particle concentration. The suitable concentration of ...

Energy Technology Data Exchange (ETDEWEB)

A method and an instrument for determining the total water content in a hydrocarbon fuel using an indicator composition, which includes calcium hydride and phenolphthaleyn, are developed. The essence of the method is fixing the presence of water with its interaction with the calcium hydride and subsequent indication of the formed Ca(OH)2 using the phenolphthallen. To make the indicator composition, a hygroscopic cotton, prewashed by rectified alcohol and dried for 30 minutes at 105 degrees, is impregnated by a 1 percent alcohol solution of phenolphthaleyn and is dried in the same conditions. Then the cotton is processed by a powder form calcium hydride (a layer thickness of 0.1 to 0.2 millimeters, and a granule size of less than or equal to 80 micromters). The indicator composition is placed in a glass tube (a diameter of 4 to 7 millimeters and a length of 80 to 100 millimeters), whose ends are sealed or filled with ...

Energy Technology Data Exchange (ETDEWEB)

Purified protein kinase C (C-kinase) from guinea pig pancreas and rat brain stimulated adenylate cyclase activity in purified rat adipocyte membranes. Cyclase stimulation occurred over 100 to 1000 mU/ml of C-kinase activity, required greater than 10 ..mu..M calcium, proceeded without a lag, was not readily reversible, and required no exogenous phospholipid. Moreover, C-kinase inhibitors, such as chlorpromazine and palmitoyl carnitine, inhibited selectively adenylate cyclase which was activated by C-kinase and calcium. Depending on assay conditions, 10 nM 12-0-tetradecanoylphorbol-13-acetate (TPA) either enhanced or was required for kinase action on cyclase. Also, TPA plus calcium promoted the quantitative association of C-kinase with membranes. Adenylate cyclase activation by C-kinase was seen both in the presence and absence of exogenous GTP, indicating that the kinase effect does not result from an action on the ...

British Library Electronic Table of Contents (United Kingdom)

This study describes the chemical composition of the essential oil of Artemisia maritima (Am.Oil) and the pharmacological basis for its medicinal use in gut and airways disorders. Twenty five compounds, composing 93.7% of the oil, were identified; among these, chrysanthenyl propionate and elixene were identified for the first time from any Artemisia species. The Am.Oil (0.3?1.0 mg/mL) suppressed spontaneous and high K+ (80 mM)-induced contractions in isolated rabbit jejunum, suggestive of an antispasmodic effect mediated possibly through calcium channel blockade. The calcium channel blockade activity was confirmed when pre-treatment of the tissue with Am.Oil (0.01?0.03 mg/mL) shifted the Ca++ concentration-response curves to the right, similar to verapamil and papaverine. In isolated trach...

Energy Technology Data Exchange (ETDEWEB)

Various chemical, physical, and mechanical methods to prevent unwanted deposition of mineral scale are described. The suitability of the different methods, which largely depends on the specific features and requirements of the system involved, is discussed. Special emphasis is placed upon the threshold treatment, where the growth process is retarded by the addition of trace amounts of growth inhibitors. Growth experiments have been performed on barium sulfate and calcium sulfate dihydrate seed crystals, suspended in a supersaturated solution with and without organic bisphosphonates as inhibitors. Two methods are selected for the analysis of the growth data. A degree of inhibition is defined to obtain a quantitative description of the influence of a growth inhibitor on the growth rate of the crystals. In addition the influence of the molecular structure of various bisphosphonates with different substituents is shown. The effect of a bisphosphonate on the geometry of ...

Energy Technology Data Exchange (ETDEWEB)

Chars prepared from potassium-exchanged carboxy methyl cellulose at several heat treatment temperatures (HTTs) were gasified in air isothermally at selected gasification temperatures (GTs) in the range 633-893 K to investigate the catalytic effectiveness of potassium species. The chars displayed a noticeable jump in gasification rate at a particular gasification temperature (called jump temperature, T{sub j}). The magnitude of jump was much less than that reported for copper and nickel catalysis, but comparable with that for calcium catalysis. Increase in HTT caused a decrease in the jump temperature of chars in contrast with the increase observed in copper, nickel and calcium catalysis; also the magnitude of jump did not decrease, but remained unaltered, on increasing HTT. The different behavior of potassium catalysis is correlated to a change in the chemical state of potassium at higher HTT. The results reveal the dependence of jump ...

International Nuclear Information System (INIS)

We present the effect of P2O5 addition on barium calcium aluminum borosilicate BCABS glasses of composition (mol %) 35BaO-15CaO-5Al2O3-(37-x)SiO2-8B2O3-xP2O5 (0?x?5). The incorporation of P2O5 increased network polymerization and crystallization tendency. However, addition of P2O5 leads to the formation of Cr2O3 at the interface, saturating it in the ions of the metal. This improves glass-to-metal bonding. (author)

International Nuclear Information System (INIS)

The formation of a porous coating is the decisive feature for the bio-compatibility of silica-free calcium phosphate glass ceramics on alloy surfaces like the #beta#-Ti structured Ti-29Nb-13Ta-4.6Zr used in this work. The ceramic composition is highly important: 50CaO-40P_2O_5-7Na_2O-3TiO_2 glass powder produces a pore-free coating unable to bind hydroxyapatite, whereas 60CaO-30P_2O_5-7Na_2O-3TiO_2 glass incorporates pores from which a crystalline hydroxyapatite phase can grow over the surface from simulated body fluid (see Figure). (Abstract Copyright [2003], Wiley Periodicals, Inc.)

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to observe both the clinical signs and symptoms of wounds at risk of infection, that is critically colonised (biofilm infected) and antimicrobial-performance of an ionic silver alginate/carboxymethylcellulose (SACMC) dressing, in comparison with a non silver calcium alginate fibre (AF) dressing, on chronic venous leg and pressure ulcers. Thirty-six patients with venous or pressure ulcers, considered clinically to be critically colonised (biofilm infected), were randomly chosen to receive either an SACMC dressing or a non silver calcium AF dressing. The efficacy of each wound dressing was evaluated over a 4-week period. The primary study endpoints were prevention of infection and progression to wound healing. The SACMC group showed a statistically significant (P = ...

Energy Technology Data Exchange (ETDEWEB)

Carbon Black and activated carbon materials providing high surface areas and a distinct pore distribution are prime materials for supercapacitor applications at frequencies < 0.5 Hz. A number of these materials were tested for their specific capacitance, surface and pore size distribution. High capacitance electrodes were manufactured on the laboratory scale with attention to ease of processability. (author) 1 fig., 1 ref.