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Sample records for caetite ba brazil

  1. Chemical correlations in Caetite (BA) region, Brazil

    International Nuclear Information System (INIS)

    Gennari, R.F.; Almeida, Geangela M.; Souza, S.O.

    2013-01-01

    Brazil's economic situation is responsible for an urgent demand for energy. There are several ways to generate energy, in some localities of our country, energy generation occurs almost exclusively by nuclear route, as in Rio de Janeiro state. Brazil has the sixth largest reserve of the uranium ore in the world. Nowadays there is only one mine under exploration (Uraniferous District of Lagoa Real - Caetite-BA). Unfortunately, nuclear power generation is better known, by common citizen, more for its unwanted effects than for its benefits. This fact is also powered by some Non-Governmental Organizations (NGOs), such as Greenpeace, who claim the uranium mine is dangerous since it causes environmental contamination. However, Industrias Nucleares do Brasil (INB) rejected these accusations. In a previous study, we demonstrated that doses of the Caetite (BA) population are consistent with those usually found in other countries. We stated also the higher concentration of 238 U determined, in only one water sample, is probably due to natural processes, as soil leaching. In order to verify the existing natural processes, macro and micro chemical elements present in water and soil samples collected in the Caetite (BA) region were determined by ICP-MS. The results were transformed into dendrograms where chemical correlations are evidenced and they are consistent with existing natural chemical processes. It was also possible to observe a correlation between samples corroborating with the Geographic Information Systems data to be presented in this same scientific event. (author)

  2. Chemical correlations in Caetite (BA) region, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Gennari, R.F., E-mail: rgennari@usp.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Inst. de Fisica. Dept. de Fisica Nuclear; Campos, S.S., E-mail: simaracampos@gmail.com [Universidade Estadual do Sudoeste da Bahia (UESB), Itapetinga, BA, (Brazil); Almeida, Geangela M.; Souza, S.O., E-mail: susanasouzalalic@gmail.com [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Dept. de Fisica

    2013-07-01

    Brazil's economic situation is responsible for an urgent demand for energy. There are several ways to generate energy, in some localities of our country, energy generation occurs almost exclusively by nuclear route, as in Rio de Janeiro state. Brazil has the sixth largest reserve of the uranium ore in the world. Nowadays there is only one mine under exploration (Uraniferous District of Lagoa Real - Caetite-BA). Unfortunately, nuclear power generation is better known, by common citizen, more for its unwanted effects than for its benefits. This fact is also powered by some Non-Governmental Organizations (NGOs), such as Greenpeace, who claim the uranium mine is dangerous since it causes environmental contamination. However, Industrias Nucleares do Brasil (INB) rejected these accusations. In a previous study, we demonstrated that doses of the Caetite (BA) population are consistent with those usually found in other countries. We stated also the higher concentration of {sup 238}U determined, in only one water sample, is probably due to natural processes, as soil leaching. In order to verify the existing natural processes, macro and micro chemical elements present in water and soil samples collected in the Caetite (BA) region were determined by ICP-MS. The results were transformed into dendrograms where chemical correlations are evidenced and they are consistent with existing natural chemical processes. It was also possible to observe a correlation between samples corroborating with the Geographic Information Systems data to be presented in this same scientific event. (author)

  3. Determination of the concentration of radionuclides in soil and water next the uranium mine of Caetite, Bahia, Brazil

    International Nuclear Information System (INIS)

    Almeida, Geangela M.; Souza, Susana O.; Campos, Simara S.S.; Gennari, Roseli F.

    2011-01-01

    The economic growing in Brazil is responsible for an urgent demand for energy. Uranium is the fuel used to generate nuclear power. Brazil has the sixth largest reserve of the uranium ore in the world and, nowadays there is only one mine under exploration (Uraniferous District of Lagoa Real - Caetite-BA). Some Non-Governmental Organizations (NGOs), such as Greenpeace, state that the explored uranium mine is dangerous and polluting, causing water contamination by uranium. So, the population would be receiving radiation doses above permissible limits. However, Industrias Nucleares do Brasil (INB) the company in charge of the complex extraction and production of yellow cake rejected these accusations. The main purpose of this work is the determination of the composition of natural radionuclides in the Uraniferous District of Lagoa Real in order to determine if the nearest population is exposed to environmental radiation. It was checked if there is water contamination due to the natural transport in the uranium mining surroundings. Soil and water samples from Caetite mine and also from nearby town were collected. Only one water sample collected had concentrations higher than the limits recommended by World Health Organization. The presence of radionuclides in soil samples is considered independent of mineral exploration. The effective dose rates in almost all samples are above the world average which is 2.4 mSv/y. To sum up, the presence of uranium in water and soil of the tested areas is probably due to the nature of the soil and not to the exploration of mine. (author)

  4. Determination of the concentration of radionuclides in soil and water next the uranium mine of Caetite, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Geangela M.; Souza, Susana O. [Federal University of Sergipe (UFS), Sao Cristovao, SE (Brazil). Dept. of Physics; Campos, Simara S.S. [State University of Southwest Bahia (UESB), Itapetinga, BA (Brazil). Dept. of Basic and Instrumental Studies; Gennari, Roseli F., E-mail: rgennari@dfn.if.usp.b [University of Sao Paulo (USP), Sao Paulo, SP (Brazil). Inst. of Physics. Dept. of Nuclear Physics

    2011-07-01

    The economic growing in Brazil is responsible for an urgent demand for energy. Uranium is the fuel used to generate nuclear power. Brazil has the sixth largest reserve of the uranium ore in the world and, nowadays there is only one mine under exploration (Uraniferous District of Lagoa Real - Caetite-BA). Some Non-Governmental Organizations (NGOs), such as Greenpeace, state that the explored uranium mine is dangerous and polluting, causing water contamination by uranium. So, the population would be receiving radiation doses above permissible limits. However, Industrias Nucleares do Brasil (INB) the company in charge of the complex extraction and production of yellow cake rejected these accusations. The main purpose of this work is the determination of the composition of natural radionuclides in the Uraniferous District of Lagoa Real in order to determine if the nearest population is exposed to environmental radiation. It was checked if there is water contamination due to the natural transport in the uranium mining surroundings. Soil and water samples from Caetite mine and also from nearby town were collected. Only one water sample collected had concentrations higher than the limits recommended by World Health Organization. The presence of radionuclides in soil samples is considered independent of mineral exploration. The effective dose rates in almost all samples are above the world average which is 2.4 mSv/y. To sum up, the presence of uranium in water and soil of the tested areas is probably due to the nature of the soil and not to the exploration of mine. (author)

  5. Results of solid state nuclear track detector technique application in radon detection, by alpha particles tracks, for uranium prospecting in Caetite (BA-Brazil)

    International Nuclear Information System (INIS)

    Moraes, M.A.P.V. de; Khouri, M.T.F.C.

    1988-11-01

    The solid state nuclear track detector technique has been used in radon detection, by alpha particles tracks for uranium prospecting on the ground in Caetite city (Bahia-Brazil). The sensitive film to alpha particles used were CA 8015 exposed during 15 days and the results of three anomalies of this region are showed in a form of maps, made with the density of tracks obtained, and were compared with scintillation counter measurements. The technique showed to be simple and an effective auxiliary for the prospection of uranium ore bodies. The initial uranium exploration costs can be reduced by using this technique. (author) [pt

  6. New route for uranium concentrate production from Caetite ore, Bahia State, Brazil; dynamic leaching - direct precipitation

    Energy Technology Data Exchange (ETDEWEB)

    Morais, Carlos A. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)]. E-mail: cmorais@cdtn.br; Gomiero, Luiz A.; Scassiotti Filho, Walter [Industrias Nucleares do Brasil S.A. (INB), Caetite, BA (Brazil)]. E-mails: gomiero@inb.gov.br; scassiotti@inb.gov.br

    2007-07-01

    The common uranium concentrate production consists of ore leaching, uranium purification/concentration by solvent extraction and uranium precipitation as ammonium diuranate steps. In the present work, a new route of uranium concentrate production from Caetite, BA-Brazil ore was investigated. The following steps were investigated: dynamic leaching of the ground ore with sulfuric acid; sulfuric liquor pre-neutralization until pH 3.7; uranium peroxide precipitation. The study was carried out in bath and continuous circuits. In the dynamic leaching of ground ore in agitated tanks the uranium content in the leached ore may be as low as 100 {mu}g/g U{sub 3}O{sub 8}, depending on grinding size. In the pre-neutralization step, the iron content in the liquor is decreased in 99 wt.%, dropping from 3.62 g/L to 0.030 g/L. The sulfate content in the liquor reduces from 46 g/L to 22 g/L. A calcinated final product assaying 99.7 wt.% U{sub 3}O{sub 8} was obtained. The full process recovery was over 94%. (author)

  7. Water management of the uranium production facility in Brazil (Caetite, BA): potential impacts over groundwater quality

    International Nuclear Information System (INIS)

    Lamego, Fernando; Santos, Robson Rodger; Silva, L. Ferreira da; Fernandes, Horst Monken

    2008-01-01

    The uranium unit of Caetite - in charge of all the 'yellow cake' produced in Brazil - is located in the semi-arid Northeast region at Bahia State. The geological uranium content of the ore is 3000 ppm, which is mainly associated with albite (NaAlSi 8 O 8 ), and its extraction is achieved by means of a Heap-Leach process. This process has a low water demand, which is supplied by a network of wells, but can contribute to change the groundwater quality and in some cases the extinguishing of wells was observed. The managing of liquid mining wastes formed by drainage waters from mine pit and solid waste piles is not enough to avoid unwarranted releases in the environment, which turn necessary the waste treatment through passing them into the industrial plant in order to reduce radionuclide concentrations. The groundwater is Na-HCO 3 type water and relative high concentration of Cl are observed in some groundwater. It seems that levels of uranium in groundwaters are mainly a consequence of the complexation of the metal by carbonates (or other anions) and not by any sort of the contamination of these waters by the drainage accumulated in the open pit. The speciation modelling allows identifying some areas where the replenishment of the aquifer is more active, but in general the recharge is a fast process run by direct infiltration. The stable isotope data (δ 2 H and δ 18 O) showed that evaporation plays a role during the infiltration, causing the groundwater salinization. These data discard the possibility that groundwater salinization was caused by discharge of deeper saline groundwater through faults associated to a regional groundwater flow system. The presence of an active shallow groundwater flow system offers better possibility for sustainable use of the groundwater resources in this semi-arid region of Brazil. (author)

  8. Evaluation of natural radioactivity in superficial and underground drinking water, from the Caetite region, BA

    International Nuclear Information System (INIS)

    Silva, Luciana Sousa

    2011-01-01

    Brazil has the seventh greatest geological uranium reserve in the world with approximately 310 thousand tons. The Lagoa Real Uranium Province, in the region of Caetite and Lagoa Real, situated in South Center Bahia, is considered the most important monomineralic province in Brazil. Urban population who lives in the uranium district in the cities of Caetite, Lagoa Real and Livramento de Nossa Senhora uses drinking water originated from public supply. In the rural area, characterized by frequent draughts, residents receive water from digged and drilled wells and from small dams and reservoirs, as well, which are supplied by the rains. This work determined the levels of total alpha and beta radioactivity and the uranium concentrations in several kinds of water consumed by urban and rural population from the Lagoa Real Uranium Province. Total α and β activities were determined with a low-level gas flow proportional detector. The uranium concentrations were determined with an inductive coupled plasma-mass spectrometer (ICP-MS). The results obtained were confronted with the latest World Health Organization's recommendations from 2011, the ordinance number 2914 of December 12 2011 from the Health Ministry and CONAMA's resolutions. Natural radiation levels varied from 0,0041 ± 0,0004 Bq.L -1 to 0,80 ± 0,04 Bq.L -1 for total alpha activity and from 0,045 ± 0,003 to 3,00 ± 0,2 Bq.L -1 for total beta activity. Having the WHO and the HM as parameter, just two underground water samples, one located in the city of Lagoa Real and the other in the city of Caetite presented total alpha concentration above the value of 0,5 Bq.L -1 described in its recommendations, 0,80 ± 0,040 Bq.L -1 and 0,57 ± 0,03 Bq.L -1 respectively. For total beta three samples presented radioactivity levels above the 1 Bq.L -1 limit recommended by the WHO and established by the Health Ministry; 3,00 ± 0,2 Bq.L -1 ; 1,63 ± 0,13 Bq.L -1 and 1,19 ± 0,07 Bq.L -1 ., all of them situated in the Lagoa

  9. Seismic refraction technique aplications in the geotechnical characterization of the Cachoeira deposit massif, Caetite, State of Bahia, Brazil

    International Nuclear Information System (INIS)

    Malagutti Filho, W.; Oliveira Braga, T. de.

    1984-01-01

    Geophysical surveys throught the Cachoeira Uranium deposit massif were carried out with the purpose of assisting in the geotechnical characterization for the implantation of the Mining-Industrial Complex projects on the Lagoa Real uranium deposits, Caetite municipality, state of Bahia, Brazil. This study discusses the methodology utilized in the geophysical surveys and their results as well as their applications to the geotechnical characterization as a whole. (D.J.M.) [pt

  10. Assessment of the total uranium concentration in surface and underground water samples from the Caetite region, Bahia, Brazil

    International Nuclear Information System (INIS)

    Silva, Julia Grasiela Batista; Geraldo, Luiz Paulo; Yamazaki, Ione Makiko

    2011-01-01

    At the region of Caetite, BA, it is located the largest uranium mine in exploration at present days in Brazil. During the uranium extraction process, it may be having an environmental contamination by this heavy metal due to rain water and other natural transport mechanism, with potential exposition risk to the local population. The aim of this work was to investigate the total uranium concentration in surface and underground water samples collected at the Caetite region, using the nuclear track registration technique (SSNTD) in a polycarbonate plastic. A 100 mL volume of water samples were initially treated in 10 mL of HNO 3 (PA) and concentrated by evaporation at a temperature around 80 deg C. The resulting residue was diluted to a total volume of 25 mL without pass it to a filter. About 10 μL of this solution was deposited on the plastic detector surface (around 1.0 cm 2 area) together with 5 μL of a Cyastat detergent solution (5%) and evaporated under an infrared lamp. All the resulting deposits of non volatile constituents were irradiated, together with a uranium standard sample, at the IPEN-IEA-R1 (3.5 MW) nuclear reactor for approximately 3 min. After irradiations, chemical etching of the plastic detectors was carried out at 60 deg C, for 65 min. in a NaOH (6N) solution. The fission tracks were counted scanning all the deposit area of the polycarbonate plastic detector with a system consisting of an optical microscope together with a video camera and TV monitor. The average values of uranium concentrations obtained in this work ranged from (0.95±0.19) μg.L -1 to (25.60±3.3) μg.L -1 . These results were compared to values reported in the literature for water samples from other regions and discussed in terms of safe limits recommended by WHO -World Health Organization and CONAMA - Conselho Nacional do Meio Ambiente. (author)

  11. Assessment of the total uranium concentration in surface and underground water samples from the Caetite region, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Julia Grasiela Batista; Geraldo, Luiz Paulo [Centro Universitario da Fundacao Educacional de Barretos (UNIFEB), (SP) (Brazil); Yamazaki, Ione Makiko [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-07-01

    At the region of Caetite, BA, it is located the largest uranium mine in exploration at present days in Brazil. During the uranium extraction process, it may be having an environmental contamination by this heavy metal due to rain water and other natural transport mechanism, with potential exposition risk to the local population. The aim of this work was to investigate the total uranium concentration in surface and underground water samples collected at the Caetite region, using the nuclear track registration technique (SSNTD) in a polycarbonate plastic. A 100 mL volume of water samples were initially treated in 10 mL of HNO{sub 3} (PA) and concentrated by evaporation at a temperature around 80 deg C. The resulting residue was diluted to a total volume of 25 mL without pass it to a filter. About 10 {mu}L of this solution was deposited on the plastic detector surface (around 1.0 cm{sup 2} area) together with 5 {mu}L of a Cyastat detergent solution (5%) and evaporated under an infrared lamp. All the resulting deposits of non volatile constituents were irradiated, together with a uranium standard sample, at the IPEN-IEA-R1 (3.5 MW) nuclear reactor for approximately 3 min. After irradiations, chemical etching of the plastic detectors was carried out at 60 deg C, for 65 min. in a NaOH (6N) solution. The fission tracks were counted scanning all the deposit area of the polycarbonate plastic detector with a system consisting of an optical microscope together with a video camera and TV monitor. The average values of uranium concentrations obtained in this work ranged from (0.95{+-}0.19) {mu}g.L{sup -1} to (25.60{+-}3.3) {mu}g.L{sup -1}. These results were compared to values reported in the literature for water samples from other regions and discussed in terms of safe limits recommended by WHO -World Health Organization and CONAMA - Conselho Nacional do Meio Ambiente. (author)

  12. Anatomia dos órgãos vegetativos de Hymenaea martiana Hayne (Caesalpinioideae-Fabaceae: espécie de uso medicinal em Caetité-BA Anatomy of vegetative organs of Hymenaea martiana Hayne (Fabaceae-Caesalpinioideae: a species of medicinal use in Caetité-Bahia State, Brazil

    Directory of Open Access Journals (Sweden)

    M.S. Silva

    2012-01-01

    Full Text Available Hymenaea martiana Hayne (Fabaceae-Caesalpinioideae apresenta grande valor na medicina popular em Caetité. A casca, entrecasca do caule e a resina, são utilizadas no tratamento de diversos males. Neste estudo são apresentadas a caracterização anatômica e histoquímica dos órgãos vegetativos. Amostras foram coletadas e processadas segundo técnicas usuais em anatomia vegetal e histoquímica. Todos os órgãos apresentam, em visão transversal, epiderme unisseriada e cavidades secretoras. Cutícula espessa ocorre em todos os órgãos aéreos. A raiz é tetrarca. Colênquima lacunar foi encontrado no caule. Bainha de fibras esclerenquimáticas envolve os feixes vasculares dos órgãos aéreos. Células pétreas ocorrem no pecíolo. Tricomas tectores ocorrem em ambas as faces da folha. A folha é hipoestomática com estômatos paracíticos e o mesofilo é dorsiventral. Cristais de oxalato de cálcio ocorrem no caule, pecíolo e lâmina foliar. Compostos fenólicos ocorrem na raiz, pecíolo e nervura central da folha. Grãos de amido ocorrem na raiz, caule e pecíolo. Lipídios ocorrem em todos os órgãos. Acredita-se que compostos fenólicos e cavidades secretoras de resina podem justificar a utilidade medicinal da espécie pela população de Caetité.Hymenaea martiana Hayne (Fabaceae-Caesalpinioideae shows a great value in folk medicine in Caetité. Its bark, stem-bark and resin are used to treat various ailments. In this study, the anatomical and histochemical characterization of vegetative organs is reported. Samples were collected and processed according to usual techniques of plant anatomy and histochemistry. All organs have, by cross-sectional view, uniseriate epidermis and secretory cavities. Thick cuticle occurs in all aerial organs. The root is tetrarch. Lacunar collenchyma was found in the stem. Sclerenchymatic sheath of fibers surrounds the vascular bundles of the aerial organs. Stone cells occur in the petiole. Trichomes occur

  13. Concentrations of Se, Ba, Zn and Mn in Brazil nuts

    Energy Technology Data Exchange (ETDEWEB)

    Armelin, Maria José A.; Maihara, Vera A.; Cardoso, Paulo S.; Saiki, Mitiko [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Cozollino, Silvia M.F., E-mail: marmelin@ipen.br, E-mail: vmaihara@ipen.br, E-mail: msaiki@ipen.br, E-mail: pscsilva@ipen.br, E-mail: smfcozzo@usp.br [Universidade de São Paulo (USP), SP (Brazil). Faculdade de Ciências Farmacêuticas

    2017-07-01

    The concentrations of Se, Ba, Zn and Mn were determined in samples of Brazil nuts collected in two ways: a) in a production farm predominantly for export and, b) in various points of sale from different regions of Brazil. Instrumental neutron activation analysis was the analytical technique used in this study. Results indicate that the concentrations of Se and Ba varied greatly among the Brazil nut samples analyzed. This large variability may be related to the soil characteristics from which the nuts were produced. An inverse correlation was observed between the concentrations of Se and Ba. On the other hand, the concentrations of Zn and Mn did not show significant differences among these samples. (author)

  14. Concentrations of Se, Ba, Zn and Mn in Brazil nuts

    International Nuclear Information System (INIS)

    Armelin, Maria José A.; Maihara, Vera A.; Cardoso, Paulo S.; Saiki, Mitiko; Cozollino, Silvia M.F.

    2017-01-01

    The concentrations of Se, Ba, Zn and Mn were determined in samples of Brazil nuts collected in two ways: a) in a production farm predominantly for export and, b) in various points of sale from different regions of Brazil. Instrumental neutron activation analysis was the analytical technique used in this study. Results indicate that the concentrations of Se and Ba varied greatly among the Brazil nut samples analyzed. This large variability may be related to the soil characteristics from which the nuts were produced. An inverse correlation was observed between the concentrations of Se and Ba. On the other hand, the concentrations of Zn and Mn did not show significant differences among these samples. (author)

  15. Hydrogeologic characterization of the Cachoeira Deposit Massif, Caetite, state of Bahia, Brazil

    International Nuclear Information System (INIS)

    Bottura, J.A.; Albuquerque Filho, J.L.; Ojima, L.M.

    1984-01-01

    The hydrogeologic applications for the characterization of rock massifs in future mining activity areas are presented. The study was performed in the Cachoeira uranium deposit (Anomaly no.13 - Lagoa Real Project) located in the south-central portion of the state of Bahia, Caetite municipality, belonging to the Brazilian Nuclear Enterprise - NUCLEBRAS. The massif occuring in the area is composed of a group or series of rocks classified generically as gneisses, displaying different geotechnical classes. In order to consubstantiate the hydrogeologic/ hydrogeotechnical characterization, pumping and infiltration tests were performed, as well as periodic water level measurements in piezometers and drill-holes. In this manner, a hydrogeotechnical classification was made possible and a quantitative evaluation of the volume of water that will be drained was elaborated, orviding necessary contributions for research diggings and exploration. (D.J.M.) [pt

  16. Hydrological Monitoring and Environmental Modeling to Assess the Quality and Sustainability of the Water Resources in an Uranium Mine Area, Caetité - Brazil

    Science.gov (United States)

    Franklin, M. R.; van Slobbe, E.; Fernandes, N. F.; Palma, J.; van Dalen, D.; Santos, A. C.; Melo, V.; Reis, R. G.; Carmo, R.; Fernandes, H. M.

    2009-12-01

    Uranium mining and processing constitute the front-end of the nuclear fuel-cycle and respond for most of its radiological impacts. For many years it has been accepted that the key driving force associated with these radiological impacts was related with radon exhalation from mill tailings. However, evidences coming from other mining sites showed that impacts in superficial and ground waters could also play a significant role. In Brazil, the newest uranium production unit presents a unique opportunity to integrate all the above concepts in a logical framework that will lead to sound and environmental balanced operations. The production center (Caetité plant) consists of open pit mine and sulfuric acid Heap Leach operations and is located at a semi-arid region in northeastern Brazil. Because groundwater is the sole perennial source of water for human consumption and industrial use, this resource has to be managed wisely and efficiently. Therefore, this paper intends to summarize the components of an ongoing project of groundwater management in uranium mining areas. The results will guide the adequate management of groundwater use and provide the basis for the appropriate impact assessment of the potential releases of pollutants. The methodology starts with the mathematical simulation of the long-term behavior of the hydrogeological system based on an experimental basin approach. The occurrence and pattern of groundwater flow in the Caetité experimental basin (CEB) are mainly conditioned by the degree of faulting/fracturing of rocks (predominantly gneisses and granites). Two faulting systems are observed in the area, the principal one, parallel to the foliation (with NW direction) and the secondary one with NE direction. The main water reservoirs in the CEB are related to the intrusion of a diabase dike, which increased the density of fractures in the rocks. This dike serves as natural barrier to the water flow and constrains the potential contamination of

  17. Radionuclides incorporated by inhabitants of surrounding Brazilian uranium mines

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Viviane S.; Brasil, Icaro M.; Attie, Marcia R.P.; Souza, Susana O. [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Dept. de Fisica; Campos, Simara S. [Universidade Estadual do Sudoeste da Bahia (UESB), Itapetinga, BA (Brazil). Dept. de Estudos Basico e Instrumental; Gennari, Roseli F. [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica. Dept. de Fisica Nuclear

    2012-07-01

    Full text: Brazil has the 6th largest global geological reserve of uranium, with the main reserve in Santa Quiteria - CE still not under exploration. Currently, uranium mining and processing in Brazil only occur near to the city of Caetite - BA. Several Non-Governmental Organizations claim that uranium mining in this region is polluting and may jeopardize the human health and safety and the environment. However, those in charge of the complex extraction and production of 'yellow cake' for generating fuel to the nuclear power plants reject these allegations. U-238 may be deposited in the skeleton by replacing the calcium, thus it is possible to estimate its incorporation by determining its concentration in the teeth. This study aimed to identify potential problems caused by mining to the population of Caetite, analyzing U-238 contained in samples of teeth extracted for orthodontic reasons from Caetite residents. The concentration of thorium and potassium incorporated were also determined by ICP-MS, as well the cumulative dose of radiation received by this population was estimated. For comparison sake, the same analysis was performed in samples from Santa Quiteria and Aracaju - SE (used as a control area). The doses estimated were compared to doses obtained with EPR spectra of the same samples. The accumulated amount of radioisotopes in the teeth of the population of Caetite is probably due to natural origin, thus it is not possible to state that the mining process in Caetite increases pollution or radiation exposure in a meaningful way. (author)

  18. Absorbed Dose Rate Due to Intake of Natural Radionuclides by Tilapia Fish (Tilapia nilotica,Linnaeus, 1758) Estimated Near Uranium Mining at Caetite, Bahia, Brazil

    International Nuclear Information System (INIS)

    Pereira, Wagner de S; Kelecom, Alphonse; Azevedo Py Junior, Delcy de

    2008-01-01

    The uranium mining at Caetite (Uranium Concentrate Unit--URA) is in its operational phase. Aiming to estimate the radiological environmental impact of the URA, a monitoring program is underway. In order to preserve the biota of the deleterious effects from radiation and to act in a pro-active way as expected from a licensing body, the present work aims to use an environmental protection methodology based on the calculation of absorbed dose rate in biota. Thus, selected target organism was the Tilapia fish (Tilapia nilotica, Linnaeus, 1758) and the radionuclides were: uranium (U-238), thorium (Th-232), radium (Ra-226 and Ra-228) and lead (Pb-210). As, in Brazil there are no radiation exposure limits adopted for biota the value proposed by the Department of Energy (DOE) of the United States of 3.5x10 3 μGy y -1 has been used. The derived absorbed dose rate calculated for Tilapia was 2.51x10 0 μGy y -1 , that is less than 0.1% of the dose limit established by DOE. The critical radionuclide was Ra-226, with 56% of the absorbed dose rate, followed by U-238 with 34% and Th-232 with 9%. This value of 0.1% of the limit allows to state that, in the operational conditions analyzed, natural radionuclides do not represent a radiological problem to biota

  19. Flora of the State of Paraíba, Brazil: Loranthaceae Juss.

    Directory of Open Access Journals (Sweden)

    Gabriella Carla Leite de Vasconcelos

    2015-08-01

    Full Text Available The family Loranthaceae Juss., characterized by its parasitic habit, is rarely studied in Brazil. Current research provides a taxonomic survey of Loranthaceae in the State of Paraiba, northeastern Brazil, in which ten species belonging to four genera have been recorded: Passovia (one species, Psittacanthus (two species, Pusillanthus (one species and Struthanthus (six species. Struthanthus concinnus Mart. was found for the first time in the state of Paraíba. A key to the species identification and taxonomic descriptions is presented, with images, geographic distribution and host data.

  20. Absorbed Dose Rate Due to Intake of Natural Radionuclides by Tilapia Fish (Tilapia nilotica,Linnaeus, 1758) Estimated Near Uranium Mining at Caetité, Bahia, Brazil

    Science.gov (United States)

    Pereira, Wagner de S.; Kelecom, Alphonse; Py Júnior, Delcy de Azevedo

    2008-08-01

    The uranium mining at Caetité (Uranium Concentrate Unit—URA) is in its operational phase. Aiming to estimate the radiological environmental impact of the URA, a monitoring program is underway. In order to preserve the biota of the deleterious effects from radiation and to act in a pro-active way as expected from a licensing body, the present work aims to use an environmental protection methodology based on the calculation of absorbed dose rate in biota. Thus, selected target organism was the Tilapia fish (Tilapia nilotica, Linnaeus, 1758) and the radionuclides were: uranium (U-238), thorium (Th-232), radium (Ra-226 and Ra-228) and lead (Pb-210). As, in Brazil there are no radiation exposure limits adopted for biota the value proposed by the Department of Energy (DOE) of the United States of 3.5×103 μGy y-1 has been used. The derived absorbed dose rate calculated for Tilapia was 2.51×100 μGy y-1, that is less than 0.1% of the dose limit established by DOE. The critical radionuclide was Ra-226, with 56% of the absorbed dose rate, followed by U-238 with 34% and Th-232 with 9%. This value of 0.1% of the limit allows to state that, in the operational conditions analyzed, natural radionuclides do not represent a radiological problem to biota.

  1. Influence of habitat heterogeneity on anuran diversity in Restinga landscapes of the Parnaíba River delta, northeastern Brazil.

    Science.gov (United States)

    Araújo, Kássio C; Guzzi, Anderson; Ávila, Robson W

    2018-01-01

    Anurans have close associations with environmental conditions and therefore represent an interesting vertebrate group for examining how resource availability and environmental variables influence species diversity. Associations between habitat heterogeneity and anuran species diversity were tested in the Restinga landscapes of the Parnaíba River delta in northeastern Brazil. Twenty-one anuran species were sampled in the rainy season during monthly excursions (December 2015 to June 2016) into areas of Restinga on two islands in the Parnaíba River delta. The fourth highest anuran diversity was found in this type of environment in Brazil and is the third in northeastern Brazil. Microenvironments, characterized by a combination of vernal pools with different vegetational and physical structures, better explained anuran species composition in the Parnaíba River delta.

  2. Sediment pollution in margins of the Lake Guaíba, Southern Brazil.

    Science.gov (United States)

    de Andrade, Leonardo Capeleto; Tiecher, Tales; de Oliveira, Jessica Souza; Andreazza, Robson; Inda, Alberto Vasconcellos; de Oliveira Camargo, Flávio Anastácio

    2017-12-02

    Sediments are formed by deposition of organic and inorganic particles on depth of water bodies, being an important role in aquatic ecosystems, including destination and potential source of essential nutrients and heavy metals, which may be toxic for living organisms. The Lake Guaíba supplies water for approximately two million people and it is located in the metropolitan region of Porto Alegre, Rio Grande do Sul State, Brazil. Thus, the aim of this study was to evaluate the sediment pollution in the margins of Lake Guaíba in the vicinity of Porto Alegre city. Surface sediment was sampled in 12 sites to assess the concentration of several elements (C, N, P, Fe, Al, Ca, Mg, Na, K, Mn, Ba, Zn, V, Pb, Cu, Cr, Ni, Cd, Mo, and Se) and the mineralogical composition. Sediment in margins of Lake Guaíba presented predominantly (> 95%) sandy fraction in all samples, but with significant differences between evaluated sites. Sediments in the margins of Lake Guaíba showed indications of punctual water pollution with Pb, Cu, Cr, Ni, TOC, TKN, and P, mainly derived from urban streams that flow into the lake. In order to solve these environmental liabilities, public actions should not focus only on Guaíba, but also in the streams that flow into the lake.

  3. Radiation protection optimization in the CAETITE industrial complex

    International Nuclear Information System (INIS)

    Azevedo Py Junior, D.; Figueiredo, N.; Dos Santos Dias, P.L.; Mantovani Lima, H.

    2002-01-01

    This paper presents, briefly, the radiation protection aspects of process, project and operation of the Caetite Industrial Complex, CIC. Planing priorities were to minimize Environmental Radiological Impact and Occupational Radiological Risk - Based on previous experiences, the process and the project were optimized, in order to minimize environmental impact and allow simultaneous natural environment restoration and operation. Technical, practical and economical advantages became evident during all project fazes, from the initial project development to the conclusion of all decommissioning steps. Planing, conducts. adequate working methods and workers training, together, turned out to be the most efficient way for occupational radiological risk reduction. This efficiency was proved during operational tests and initial operation of the Complex. Radiation Protection optimization is achieved by worker's responsibility, turning safety corrections interference less frequents, rising consequently, minimizing environmental impact. (author)

  4. Comparative assessment of licensing processes of uranium mines in Brazil

    International Nuclear Information System (INIS)

    Silva, K.M.; Menezes, R.M.; Mezrahi, A.

    2002-01-01

    Commercial operation of uranium mining and milling started in Brazil, at the Pocos de Caldas Unit, State of Minas Gerais, in 1982. The Pocos de Caldas Unit was licensed by the Brazilian Regulatory Body (CNEN) and its is now in the decommissioning process. In 2000, a new mining and milling installation, the Caetite Unit, located in State of Bahia, started operation. This paper will discuss how Brazilian Nuclear Energy Commission is licensing the Caetite Unit based on the lessons learned from the Pocos de Caldas Unit. The objective is to draw attention to the importance of the safety assessment for a new unit, specially considering that some wrong decisions were taken for the Pocos de Caldas unit. These decisions lead to less effective long term solutions to protect the environment. Notwithstanding the differences between the two units, it is of great value to use the acquired experience to avoid or minimize the short, medium and long term impacts to the environment and population in the new operation. (author)

  5. Cretaceous-Paleogene ostracods from the Paraíba Basin, northeastern Brazil

    Science.gov (United States)

    de Lima Barros, Cecília; Piovesan, Enelise Katia; Oliveira Agostinho, Sonia Maria

    2018-04-01

    This work presents a detailed taxonomic study on the marine ostracods from the Paraíba Basin, northeastern Brazil, in wells from the wells Itamaracá-1IT-03-PE and Poty-1PO-01-PE, which record the Maastrichtian-Danian boundary. Besides the taxonomic data, this paper contributes to the paleoenvironmental knowledge of Cretaceous-Paleogene ostracods from the Paraíba Basin. The analysis of 98 samples of the well Itamaracá-1IT-03-PE and 59 samples of the Poty-1PO-01-PE resulted in the record of 34 ostracode species, all representative of a marine environment with normal salinity. Seven new species are proposed: Cytherella centrocompressa sp. nov.; Cytherella paraibensis sp. nov.; Neonesidea potyensis sp. nov.; Bythoceratina spinosa sp. nov.; Eucytherura ventrotuberculata sp. nov.; Langiella fauthi sp. nov. and Protobuntonia punctatum sp. nov.

  6. The Paleozoic ichthyofauna of the Amazonas and Parnaíba basins, Brazil

    Science.gov (United States)

    Figueroa, Rodrigo Tinoco; Machado, Deusana Maria da Costa

    2018-03-01

    The Brazilian Paleozoic ichthyofauna from the Parnaíba and Amazonas basins regard a sparsely known diversity, including chondrichthyans and acanthodians, besides some osteichthyan remains. This work proposes a revision of the fossil material from these two sedimentary basins and synthesizes the morphological aspect of such material trying to understand the influences of those fossils to the paleontology of the region, comparing the Brazilian fossils with other gondwanan faunas. The Brazilian Paleozoic fish fauna shows great resemblance to those of Bolivia, especially during the Devonian. Many of the Acanthodian spines from the Manacapuru Formation (Amazonas Basin), and the Pimenteira Formation (Parnaíba Basin), are comparable to the taxa found in Bolivia. The lack of more Placoderm remains in the Brazilian outcrops is similar to the low diversity of this group in Bolivia, when compared to other South American and Euramerican localities. The most diverse Brazilian ichthyofauna is encountered in the Permian Pedra de Fogo Formation where numerous chondrichthyans and 'paleopterygians' remains are found, together with dipnoans and actinistians. Despite the apparent lack of more representative Paleozoic ichthyofaunas in Brazil, the available material that ranges from Lower Devonian to early Permian from Brazil bears important taxa that could address valuable taxonomic and biogeographic informations.

  7. Zooplankton community of Parnaíba River, Northeastern Brazil

    Directory of Open Access Journals (Sweden)

    Ludmilla Cavalcanti Antunes Lucena

    2015-03-01

    Full Text Available Aim:The objective of the present work is to present a list of species of zooplankton (Rotifera, Cladocera and Copepoda from the Parnaíba River. Additionally, we provide comments on their distribution along the river, and between dry and wet seasons.MethodsZooplankton was collected with a plankton net (60 µm mesh and concentrated into a volume of 80 mL for further analysis, during the dry (October 2010 and wet (April 2011 seasons. Sampling was restricted to the marginal areas at depths between 80 and 150 cm.ResultsA total of 132 species was recorded among the three zooplankton groups studied. During the dry season a total of 82 species was registered and 102 species was registered for the wet season. Rotifera contributed with 66.7% of the species, followed by Cladocera (26.5% and Copepoda (6.8%.ConclusionsThe richness of species observed was high compared to other large rivers in Brazil. In the context of current policies for water management and river diversions in northeastern Brazil, the present study highlights the importance of this river system for biodiversity conservation.

  8. Plastic ingestion by sea turtles in Paraíba State, Northeast Brazil

    OpenAIRE

    Camila Poli; Daniel Oliveira Mesquita; Cinthia Saska; Rita Mascarenhas

    2015-01-01

    ABSTRACT Currently, plastics are recognized as a major pollutant of the marine environment, representing a serious threat to ocean wildlife. Here, we examined the occurrence and effects of plastic ingestion by sea turtles found stranded along the coast of Paraíba State, Brazil from August 2009 to July 2010. Ninety-eight digestive tracts were examined, with plastic found in 20 (20.4%). Sixty five percent (n = 13) of turtles with plastic in the digestive tract were green turtles (Chelonia mydas...

  9. Uranium mining impacts on water resources in Brazil

    International Nuclear Information System (INIS)

    Simoes Filho, Francisco Fernando Lamego; Lauria, Dejanira C.; Vasconcellos, Luisa M.H.; Fernandes, Horst M.; Clain, Almir F.; Silva, Liliane F.

    2009-01-01

    Uranium mining and milling activities started operations in Brazil during the 80's. The first production Center was deployed in Pocos de Caldas (CIPC) State of Minas Gerais. The mine was exhausted in 1997, after has produced only 1200 t of U 3 O 8 . The second uranium plant began the operations in Caetite (URA), Bahia State, since 1999 and keeps operations until now with an annual U 3 O 8 production of up to 400 t. The company plans to double this mark in Caetite production center with the exploration of another uranium deposits and initiate underground operations of current open-pit mine. Simultaneously, they are seeking a license for a third plant in the State of Ceara that could produce the double of foreseen capacity in URA. This scenery drives to some issues related to the impact of uranium production on water resources of the respective watersheds. The CIPC plant is a closing mine site, which requires permanent treatment of the company due to the fact their sources of pollutants are subject to the occurrence of Acid Mine Drainage. The URA plant is located in a semi-arid region of Brazil. The extraction of uranium from the ore is achieved by means of a Heap-Leach process, which has low water demand supplied by a network of wells and from a dam, but can contribute to change the groundwater quality and in some cases the extinguishing of wells was observed. An overall assessment of these impacts in national level could produce some lessons that we must take advantage for the ongoing project of Santa Quiteria or even in future sites. (author)

  10. Environmental performance evaluation of waste management system of Uranium Concentrated Unit in Caetite city, Bahia State - Brazil

    International Nuclear Information System (INIS)

    Araujo, Valeska P.; Fernandes, Horst M.; Gomiero, Luis Alberto

    2005-01-01

    The mining/milling activities have the potential to cause risks to the human health and to the environment. In uranium mining, besides inherent damages due to any mining activities there are radiological risks, that may be incurred even in short as in long terms. The large volumes of low activity mining/milling residues produced, are the great challenge in the waste management. Nowadays, the whole Brazilian uranium production come from Uranium Concentrated Unit (URA), a facility operated by Brazilian Nuclear Industry and located at a semi-arid region, in the Caetite city, Bahia state. This Unit is composed by a open pit mine and a milling facility. The present work assess the URA waste management system, the procedures adopted, focused on its environmental performance. It was observed that the waste management system is efficient in the control of the environmental impacts, however improvement chances are detected and a better performance may be reached. Concerning the liquids wastes, it was observed that the storage systems were not projected adequately. The storage capacity was not enough to support a intense rainfall period causing a overflow to the environment. In URA activities there is no radiological risk to the public, but its necessary to improve long term actions, constraints for the post-closure phase, e.g., appropriate institutional controls, restrictions on land use. Finally, it is advisable to introduce a Environmental Management System (EMS) for the whole facility. (author)

  11. First report of the protozoan parasite Perkinsus marinus in South America, infecting mangrove oysters Crassostrea rhizophorae from the Paraíba River (NE, Brazil).

    Science.gov (United States)

    da Silva, Patricia Mirella; Vianna, Rogério Tubino; Guertler, Cristhiane; Ferreira, Liana Pinho; Santana, Lucas Nunes; Fernández-Boo, Sergio; Ramilo, Andrea; Cao, Asunción; Villalba, Antonio

    2013-05-01

    The present work aimed to study the infection by Perkinsus sp. in the mangrove oysters Crassostrea rhizophorae from the estuary of the Paraíba River (Paraíba State, Brazil). Perkinsosis was detected by incubation of oyster gill pieces in Ray's fluid thioglycollate medium. The monthly prevalence values were all above 70%, thus infection was not likely to be a transient event. Perkinsus sp. parasites isolated from eight oysters were propagated in vitro. PCR-RFLP analysis of in vitro cultured cells as well as the sequences of the rDNA ITS region allowed the identification of the in vitro propagated parasites as Perkinsus marinus. Phylogenetic analyses using rDNA ITS region sequences strongly supported the Perkinsus sp. from Paraíba in a monophyletic group with P. marinus. Thus, the results confirmed the species affiliation of Paraíba Perkinsus sp. as P. marinus. This is the first report of P. marinus in Brazil and South America and the first report of P. marinus naturally infecting C. rhizophorae. Copyright © 2013 Elsevier Inc. All rights reserved.

  12. A Miocene wave-dominated estuarine system in the Paraíba Basin, northeastern Brazil

    Science.gov (United States)

    Gandini, Rosana; Rossetti, Dilce de Fátima; Netto, Renata Guimarães; Góes, Ana Maria

    2017-11-01

    A number of publications have documented the effect of the Miocene transgression on several coasts of the world. However, this event is incompletely documented along the Brazilian margin, despite the existence of an impressive record of Miocene deposits exposed mostly as several coastal cliffs along more than 5000 km of distance. The transgressive nature of Miocene deposits, so far recognized only in a few localities of northeastern Brazil, needs to be amplified in order to better characterize the impact of the Miocene transgression in eastern South America. In this work, we provide facies analysis of early/middle Miocene strata exposed in the Paraíba Basin, northeastern Brazil, aiming reconstruct the depositional paleoenvironments and analyze their evolution within the context of relative sea-level fluctuations data. The results revealed deposits characterized by several features that were related to the action of tidal currents, such as alternating thicker/thinner forest packages, abundant reactivation surfaces, mud drapes and oppositely-dipping (herringbone) cross sets. These sedimentary structures were associated with an ichnological assemblage indicative of marine-influenced and brackish water, best represented by Ophiomorpha, Planolites-Palaeophycus-Thalassinoides and Thallassinoides-Planolites-Palaeophycus ichnofabrics. Sedimentation occurred in environments consisting of estuarine channel, estuarine central basin, tidal inlet/tidal channel, tidal delta/washover, tidal flat/shoal and foreshore, which were related to an estuarine setting, at least in part of a wave-dominated type. Analysis of facies stratal patterns led to suggest that the estuarine deposits of the Paraíba Basin reflect a rise in relative sea level probably during the transgressive and/or highstand stage of a depositional sequence formed directly overlying Cretaceous rocks. This rise can be correlated with the worldwide early/mid Miocene marine transgression. However, while the eustatic sea

  13. Prevalence of canine hepatozoonosis in Areia, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Maria das Graças da Silva Bernardino

    2016-02-01

    Full Text Available Canine hepatozoonosis is a parasitic disease of debilitating nature. Also, it is immunosuppressive and difficult to diagnose clinically. The prevalence of the disease in dogs has been described in several Brazilian states, but studies are still scarce in the Northeast region. Accordingly, this study aimed to determine the prevalence of canine hepatozoonosis in Areia, Paraíba, Brazil. The dogs were clinically examined, and peripheral blood samples were obtained from the tip of the ear. Of the 151 dogs analyzed, 9.3% were positive for Hepatozoon canis by the demonstration of gamonts parasitizing neutrophils. The degree of parasitemia ranged from mild to intense. The observed hematological changes were different between animals and showed no pattern of response to infection. The subclinical form was observed in 50% of dogs and the others had nonspecific clinical signs. We conclude that hepatozoonosis occurs in dogs in the urban area of the city studied and that dogs infected with H. canis show hematological changes and nonspecific clinical signs.

  14. Geophysical evidence of pre-sag rifting and post-rifting fault reactivation in the Parnaíba basin, Brazil

    OpenAIRE

    de Castro, David Lopes; Bezerra, Francisco Hilário; Fuck, Reinhardt Adolfo; Vidotti, Roberta Mary

    2016-01-01

    This study investigated the rifting mechanism that preceded the prolonged subsidence of the Paleozoic Parnaíba basin in Brazil and shed light on the tectonic evolution of this large cratonic basin in the South American platform. From the analysis of aeromagnetic, aerogravity, seismic reflection and borehole data, we concluded the following: (1) large pseudo-gravity and gravity lows mimic graben structures but are associated with linear supracrustal strips in the basement. (2...

  15. Environmental monitoring of the Uranium Concentrate Unity (URA) at Caetite - Bahia State - Brazil; Monitoracao ambiental da Unidade de Concentrado de Uranio (URA) em Caetite - BA - Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Wagner de Souza; Py Junior, Delcy de Azevedo [Industrias Nucleares do Brasil SA, Resende, RJ (Brazil). Gerencia de Licenciamento em Meio Ambiente]. E-mail: glima@inb.gov.br

    2002-07-01

    The pre operational monitoring program has been executed in order to set a baseline, on which comparisons with the same points and the same radionuclides will be made after beginning of operation, having the objective of environmental impact evaluation, in the vicinity of the installation. The program was held in the period of 1982 to 1999, collecting non biological environmental samples (aerosol, rain water, surface water, underground water soil and sediment) and samples that are related to the human food chain (manioc, manioc flour, milk, browse, fish, been, corn, cactus and silage). The analyzed radionuclides are natural uranium, natural thorium, Ra-226, Ra-228, Rn-222 and Pb-210. This work intends to analyze data from the last ten years, program (1989 - 1999), analyzing approximately 350 biological samples and 3500 non biological samples, in order to establishing the baseline to be used in future studies of environmental impact. (author)

  16. ISO 9000: The challenge of Camacari petrochemical complex, Bahia State - Northeast Brazil; ISO 9000: o desafio do polo petroquimico de Camacari, BA, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Marcos Antonio Lima de; Carvalho Neto, Jose

    1993-12-31

    The petrochemical complex of Camacari, BA, Brazil, involves 40 companies, responsible for 55% of brazilian production. The companies were installed using the most modern techniques related to quality available at that time, strongly centered in quality control. The new industrial policy towards reducing import taxes and allowing the entrance of foreign products at competitive prices, besides the quality exigencies of international market, induced the companies to develop new techniques for quality management based in the ISO 9000 standards. The paper shows the stage of implementation of these standards in 30 companies, corresponding to 90% of global sales of all the complex. (author)

  17. ISO 9000: The challenge of Camacari petrochemical complex, Bahia State - Northeast Brazil; ISO 9000: o desafio do polo petroquimico de Camacari, BA, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Marcos Antonio Lima de; Carvalho Neto, Jose

    1992-12-31

    The petrochemical complex of Camacari, BA, Brazil, involves 40 companies, responsible for 55% of brazilian production. The companies were installed using the most modern techniques related to quality available at that time, strongly centered in quality control. The new industrial policy towards reducing import taxes and allowing the entrance of foreign products at competitive prices, besides the quality exigencies of international market, induced the companies to develop new techniques for quality management based in the ISO 9000 standards. The paper shows the stage of implementation of these standards in 30 companies, corresponding to 90% of global sales of all the complex. (author)

  18. Diet, reproduction and population structure of the introduced Amazonian fish Cichla piquiti (Perciformes: Cichlidae) in the Cachoeira Dourada reservoir (Paranaíba River, central Brazil)

    OpenAIRE

    Ferraz Luiz, Tatiane; Roquetti Velludo, Marcela; Carvalho Peret, Alberto; Rodrigues Filho, Jorge Luiz; Moldenhauer Peret, André

    2011-01-01

    The Blue Peacock Bass (Cichla piquiti), native to the Tocantins-Araguaia river basin of the Amazon system, was introduced into the basin of the Paranaíba River, Paraná River system. Cachoeira Dourada reservoir is one of a series of dams on the Paranaíba River in central Brazil, where this fish has become established. A study of its feeding spectrum, combined with information about its reproductive characteristics and population structure, would enable the current state of this species in the ...

  19. An application of sample entropy to precipitation in Paraíba State, Brazil

    Science.gov (United States)

    Xavier, Sílvio Fernando Alves; da Silva Jale, Jader; Stosic, Tatijana; dos Santos, Carlos Antonio Costa; Singh, Vijay P.

    2018-05-01

    A climate system is characterized to be a complex non-linear system. In order to describe the complex characteristics of precipitation series in Paraíba State, Brazil, we aim the use of sample entropy, a kind of entropy-based algorithm, to evaluate the complexity of precipitation series. Sixty-nine meteorological stations are distributed over four macroregions: Zona da Mata, Agreste, Borborema, and Sertão. The results of the analysis show that intricacies of monthly average precipitation have differences in the macroregions. Sample entropy is able to reflect the dynamic change of precipitation series providing a new way to investigate complexity of hydrological series. The complexity exhibits areal variation of local water resource systems which can influence the basis for utilizing and developing resources in dry areas.

  20. Genetic characterization of Trypanosoma cruzi natural clones from the state of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Christian Barnabé

    2005-05-01

    Full Text Available Eighteen Trypanosoma cruzi stocks from the state of Paraíba, Brazil, isolated from man, wild mammals, and triatomine bugs were studied by multilocus enzyme electrophoresis and random primed amplified polymorphic DNA. Despite the low number of stocks, a notable genetic, genotypic, and phylogenetic diversity was recorded. The presence of the two main phylogenetic subdivisions, T. cruzi I and II, was recorded. The strong linkage disequilibrium observed in the population under survey suggests that T. cruzi undergoes predominant clonal evolution in this area too, although this result should be confirmed by a broader sample. The pattern of clonal variation does not suggests a recent origin by founder effect with a limited number of different genotypes.

  1. The zooplankton biodiversity of some freshwater environments in Parnaíba basin (Piauí, Northeastern Brazil

    Directory of Open Access Journals (Sweden)

    JDN. Paranhos

    Full Text Available The plankton fauna of the state of Piauí, Northeastern Brazil, especially in the Parnaíba basin, is still poorly known; the results of most studies of the subject have not been published and can only be found in grey literature (unpublished scientific works, such as course completion work and consulting reports. Thus, this paper presents data from samples taken recently from different water bodies in Piauí and represents the second study to be published on the region's zooplankton since the pioneering work of Spandl (1926. A total of 38 species were recorded, including 23 new occurrences of rotifers, 10 of cladocerans and 2 of copepods for the state of Piauí. The greatest richness was observed for the rotifers, of which the genus Brachionus must be highlighted, especially at the Joana reservoir. Among the crustaceans, the greatest richness was observed at the Bezerra reservoir, where cladocerans of the genus Bosmina were prominent. The rotifers Brachionus havanaensis Rousselet, 1911 and Filinia longiseta (Ehrenberg, 1834; the cladocerans Diaphanosoma spinulosum Herbst, 1967 and Moina micrura Kurz, 1874; and the copepods Notodiaptomus cearensis Wright, 1936 and Thermocyclops decipiens Kiefer, 1927 occurred in all or in most environments in which the respective groups were studied. The results presented here expand the taxonomic list of zooplankton for the state of Piauí, including a total fauna of 30 species of rotifers, 15 of cladocerans and 3 of copepods. The zooplankton richness was considered low in the studied reservoirs compared to other freshwater ecosystems from Northeastern Brazil; however, the few studies developed in the Parnaíba basin suggest that the diversity for these organisms should be higher.

  2. Application of the Geographic Information Systems (GIS) in the spatialization of U, Th and K concentrations on the proximity of brazilian uranium mines

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Simara S.; Veiga, Artur J.P., E-mail: simaracampos@gmail.com [Universidade Estadual do Sudoeste da Bahia (UESB), Itapetinga, BA (Brazil); Souza, Susana O. [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Dept. de Fisica; Gennari, Roseli F. [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Dept. de Fisica Nuclear

    2013-07-01

    GIS is a computational tool for improving the obtained data with spatial geographic information. An understanding of complex analysis by overlaying and integrating several types of information is possible. With GIS one can question, analyze, interpret and understand the data to reveal relationships, patterns and trends. In environmental monitoring, GIS have become indispensable to do the contextualization of the problem. The cartographic products generated by the application of these techniques allow the visualization of the environmental current situation, which may also contribute to the prediction of future problems. After accidents with Fukushima and Chernobyl nuclear power plants there is a crescent public fear intensified every time there are nuclear fuel cycle activities occurring. The absence of reliable information leads to unfounded rumors about the daily life and this can impact negatively on activity performed, mainly in situations related to power generation by nuclear route, notably known more by its harm effects than by the benefits. Faced with such controversial subjects, two main Brazilian uranium reserves (Caetite-BA and Santa Quiteria-CE) were studied. We performed ICP-MS analyzes for the U, Th and K determination in water and soil samples. The obtained data GIS tools were applied to survey topography and watershed where URA - Uranium Concentrate Unit of Nuclear Industries of Brazil - INB is inserted. Our aim was to identify the affluent hydrography found in the region and overlaps the radiological data, checking possible routes of contamination. The radionuclides concentration found in soil and water, in both regions, are within the limit set by the World Health Organization. In Santa Quiteria, once this URA is in pre-operational phase, no hydraulic connections were established. In the URA - Caetite, we observe that there is no hydraulic connection between the URA and the City of Caetite, so the Greenpeace affirmation about the radionuclide

  3. Application of the Geographic Information Systems (GIS) in the spatialization of U, Th and K concentrations on the proximity of brazilian uranium mines

    International Nuclear Information System (INIS)

    Campos, Simara S.; Veiga, Artur J.P.; Souza, Susana O.; Gennari, Roseli F.

    2013-01-01

    GIS is a computational tool for improving the obtained data with spatial geographic information. An understanding of complex analysis by overlaying and integrating several types of information is possible. With GIS one can question, analyze, interpret and understand the data to reveal relationships, patterns and trends. In environmental monitoring, GIS have become indispensable to do the contextualization of the problem. The cartographic products generated by the application of these techniques allow the visualization of the environmental current situation, which may also contribute to the prediction of future problems. After accidents with Fukushima and Chernobyl nuclear power plants there is a crescent public fear intensified every time there are nuclear fuel cycle activities occurring. The absence of reliable information leads to unfounded rumors about the daily life and this can impact negatively on activity performed, mainly in situations related to power generation by nuclear route, notably known more by its harm effects than by the benefits. Faced with such controversial subjects, two main Brazilian uranium reserves (Caetite-BA and Santa Quiteria-CE) were studied. We performed ICP-MS analyzes for the U, Th and K determination in water and soil samples. The obtained data GIS tools were applied to survey topography and watershed where URA - Uranium Concentrate Unit of Nuclear Industries of Brazil - INB is inserted. Our aim was to identify the affluent hydrography found in the region and overlaps the radiological data, checking possible routes of contamination. The radionuclides concentration found in soil and water, in both regions, are within the limit set by the World Health Organization. In Santa Quiteria, once this URA is in pre-operational phase, no hydraulic connections were established. In the URA - Caetite, we observe that there is no hydraulic connection between the URA and the City of Caetite, so the Greenpeace affirmation about the radionuclide

  4. First case report of vesicular stomatitis in the State of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Inácio José Clementino

    2014-10-01

    Full Text Available The present report describes the first case of vesicular stomatitis in the State of Paraíba, Brazil. Records from the Official Veterinary Services of the State of Paraíba were analyzed while responding to a suspected case of vesicular disease at a property (property I in the municipality of Pombal in which the cattle showed clinical signs and lesions of vesicular disease. Surveillance in the surrounding area revealed similar lesions in cattle at two other properties (II and III. Based on these events, the suspicion was considered well founded, and samples were collected for evaluation at the National Agricultural Laboratory of the State of Pará. The property was interdicted, and those located within a 3 km radius (perifocal from the focus were inspected. At property I, 42.86% (6/14 of the cattle showed vesicular disease lesions characterized by intense sialorrhea, ruptured oral vesicles, epithelial detachment of the tongue and muzzle, and vesicular lesions in the udder and interdigital space. Similar lesions were detected in cattle at properties II and III, affecting 80.95% (34/42 and 11.54% (3/26 of the animals, respectively. Tissue samples collected from the three properties were positive for the vesicular stomatitis virus (Indiana 3 subtype. The properties were monitored for 21 days after the last infected animal was cured, and afterwards, the three properties were released.

  5. Preliminary studies on fluid inclusions in metasomatic albite grains from Lagoa Real, Caetite, Ba, Brazil

    International Nuclear Information System (INIS)

    Fuzikawa, K.

    1980-01-01

    Preliminary fluid inclusion studies in metasomatic albite grains from the Lagoa Real uranium deposit pointed out to mixing of strong brines (23 wt% NaCl equivalent) with low salinity fluids (2.3 wt% NaCl equivalent). Microthermometry and crushing tests indicated elevated pressures and the presence of hidrocarbons in larger amount than CO 2 . The remobilization of uranium as uranyl carbonate complexes and its precipitation, reducing U 6 + to U 4 + by CH 4 , is considered as a possibility. (Author) [pt

  6. Crustal structure beneath the Paleozoic Parnaíba Basin revealed by airborne gravity and magnetic data, Brazil

    Science.gov (United States)

    de Castroa, David L.; Fuck, Reinhardt A.; Phillips, Jeffrey D.; Vidotti, Roberta M.; Bezerra, Francisco H. R.; Dantas, Elton L.

    2014-01-01

    The Parnaíba Basin is a large Paleozoic syneclise in northeastern Brazil underlain by Precambrian crystalline basement, which comprises a complex lithostructural and tectonic framework formed during the Neoproterozoic–Eopaleozoic Brasiliano–Pan African orogenic collage. A sag basin up to 3.5 km thick and 1000 km long formed after the collage. The lithologic composition, structure, and role in the basin evolution of the underlying basement are the focus of this study. Airborne gravity and magnetic data were modeled to reveal the general crustal structure underneath the Parnaíba Basin. Results indicate that gravity and magnetic signatures delineate the main boundaries and structural trends of three cratonic areas and surrounding Neoproterozoic fold belts in the basement. Triangular-shaped basement inliers are geophysically defined in the central region of this continental-scale Neoproterozoic convergence zone. A 3-D gravity inversion constrained by seismological data reveals that basement inliers exhibit a 36–40.5 km deep crustal root, with borders defined by a high-density and thinner crust. Forward modeling of gravity and magnetic data indicates that lateral boundaries between crustal units are limited by Brasiliano shear zones, representing lithospheric sutures of the Amazonian and São Francisco Cratons, Tocantins Province and Parnaíba Block. In addition, coincident residual gravity, residual magnetic, and pseudo-gravity lows indicate two complex systems of Eopaleozoic rifts related to the initial phase of the sag deposition, which follow basement trends in several directions.

  7. Vascular flora of an inselberg in the state of Paraíba, in Northeast Brazil

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    Elisabeth Emília Augusta Dantas Tölke

    2011-12-01

    Full Text Available This study characterized the floristic composition of an inselberg in the Puxinanã municipality, of Paraíba, in Northeast Brazil. Ninety-seven species were recorded that belong to 35 families: Asteraceae (12 spp., Euphorbiaceae and Fabaceae (nine spp. each, Rubiaceae and Convolvulaceae (eight spp. each were the richest families, comprising 47.42% of the total species registered. The herbaceous habit was predominant, occurring in 39% of the species, followed by species of shrubs (22%, vines (20%, rupicolous plants (6%, subshrubs (5%, trees (4% and epiphytes (1%. Passiflora luetzelburgii Harms (Passifloraceae is a new record for the flora of the state. The data from this study provides information that could be used in the conservation and rational use of the study area, and contributes to what is known about the flora and vegetation of the Caatinga.

  8. Flora da Paraíba, Brasil: Loganiaceae Flora of Paraíba, Brazil: Loganiaceae

    Directory of Open Access Journals (Sweden)

    Kiriaki Nurit

    2005-06-01

    Full Text Available Neste trabalho apresenta-se o tratamento taxonômico da família Loganiaceae, como parte do projeto "Flora da Paraíba", que vem sendo realizado com o objetivo de identificar e catalogar as espécies da flora local. Realizouse coletas e observações de campo para as identificações, descrições e ilustrações botânicas que foram efetuadas após estudos morfológicos, com o auxílio da bibliografia especializada, complementados pela análise de fotos de tipos, espécimes dos herbários EAN, JPB e IPA, e comparação com material identificado por especialistas. Registrou-se para a Paraíba quatro espécies: Spigelia anthelmia L., com ampla distribuição, e três espécies de Strychnos, somente coletadas em remanescentes de Mata Atlântica, S. atlantica Krukoff & Barneby, S. parvifolia A. DC. e S. trinervis (Vell. Mart.This work constitutes a taxonomic treatment of the Loganiaceae family as part of the project "Flora da Paraíba", which have been carried out with the objective to identify and catalogue the species of the local flora. The botanical identifications and illustrations were made by morphological studies supported by bibliography, analysis of the types, specimens from herbaria EAN, JPB and IPA, and comparison with samples previously identified by specialists, complemented by field observations. Four species of Loganiaceae belonging two genera were found in State of Paraíba: Spigelia anthelmia L. that has wide distribution and three species of Strychnos, found on remains of Atlantic forest, which are S. atlantica Krukoff & Barneby, S. parvifolia A. DC. and S. trinervis (Vell. Mart.

  9. Clinical and mycological study of scalp white piedra in the State of Paraíba, Brazil.

    Science.gov (United States)

    Pontes, Zélia Braz Vieira da Silva; Ramos, Adriano Lira; Lima, Edeltrudes de Oliveira; Guerra, Maria de Fátima de Lacerda; Oliveira, Neuza Maria Cavalcante; Santos, Jozemar Pereira dos

    2002-07-01

    White piedra is a superficial mycoses characterized by nodules on the hair shaft, caused by the basidiomycetous yeasts. In the present study, clinical and mycological findings of scalp white piedra caused by Trichosporon spp. are related. Twenty three cases of scalp white piedra were observed with a high incidence in women (87%) and preschool children from 2 to 6 (74%) years old. These groups presented a relationship of dependence with this infection. Despite the low socio-economic status, poor standards of hygiene, (48% of the patients) as well as the fact that 30.4% of the children shared the same nursery, these factors were not significant for the transmission of the mycosis. These were the first reports of scalp white piedra in João Pessoa city, Paraíba, Brazil.

  10. Clinical and mycological study of scalp white piedra in the State of Paraíba, Brazil

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    Zélia Braz Vieira da Silva Pontes

    2002-07-01

    Full Text Available White piedra is a superficial mycoses characterized by nodules on the hair shaft, caused by the basidiomycetous yeasts. In the present study, clinical and mycological findings of scalp white piedra caused by Trichosporon spp. are related. Twenty three cases of scalp white piedra were observed with a high incidence in women (87% and preschool children from 2 to 6 (74% years old. These groups presented a relationship of dependence with this infection. Despite the low socio-economic status, poor standards of hygiene, (48% of the patients as well as the fact that 30.4% of the children shared the same nursery, these factors were not significant for the transmission of the mycosis. These were the first reports of scalp white piedra in João Pessoa city, Paraíba, Brazil.

  11. Experimental study of the uranium mobility due to the weathering action at the uraniferous district of Caetite/Lagoa Real, Bahia, Brazil

    International Nuclear Information System (INIS)

    Scislewski, Alexandro Rocha

    2004-01-01

    In the present research, the proposal was to develop a preliminary study about the geochemical behavior of determined chemical elements, mainly the uranium, during the action of weathering processes in the rocks that bear the uranium mineralizations of the Caetite-Lagoa Real region, State of Bahia, more specifically of the Jazida Cachoeira uranium mine. To reach this purpose were used samples that represent several stages of the milling process of the uranium ore, so selecting representatives of the host rock, the ore and the treated ore (waste from the milling plant) to be used in the laboratory-controlled experiments. The samples were dried, sieved and finally introduced in the reactors, these adapted from the Flow-Through Reactor of Brantley and Chen. In the geochemical point of view, the results of the experiments showed a distinct behavior between the samples. It was observed that the treated ore, in relation to the host rocks of the ore and the own ore, shown a faster and homogeneous interaction with the leaching solution; it was also noted that in the output solution of the treated ore samples existed a significant complexation of the uranium by the sulfate (S0 4 -2 ), ), instead of the non treated samples (host rock and ore) that were complexed mainly by the carbonate (C0 3 -2 ). These different results are attributed to the alterations imposed to the rock during the milling process, and occur mainly, during the acid attack in the leaching process of the milling plant. The results and conclusions of this research, in spite of been preliminary, are essential to understand the behavior of the geochemical speciation of the effluent solutions; to understand the alterations of a rock matrix, and finally, to understand the migration chemical behavior of the related chemical elements. It is expected that these results contribute, in the future, to a deeper knowledge of the processes that control the chemical composition of the natural waters from this region in

  12. Prevalence of anti-pestivirus antibodies and risk factors in dairy goats from the semiarid region of Paraíba State, Northeastern Brazil

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    Maria Luana Cristiny Rodrigues Silva

    2014-06-01

    Full Text Available t The aim of this survey was to determine the prevalence of anti-pestivirus antibodies in dairy goats from the semiarid region of the Paraíba state, Northeastern Brazil, as well as to identify risk factors associated with the flock-level prevalence. A total of 1,092 dairy goats from 110 flocks randomly selected in the county of Monteiro, Paraíba state, during March 2009 to March 2010, were used. In each selected flock a epidemiological questionnaire was applied to verify the occurrence of possible factors that could be associated with the flock-level prevalence. For the serological diagnosis of Pestivirus infection the serum neutralization test, using the BVDV-1 NADL strain, was carried out. Flock-level prevalence was 6.36% (95% CI = 2.60% – 12.67% and animal-level prevalence was 0.82% (95% CI = 0.38% – 1.56%. Not to perform vermifugation (odds ratio = 10.49; p = 0.035 and to perform navel cut and disinfection (odds ratio = 12.73; p = 0.034 were identified as risk factors. These results indicate viral circulation in dairy goats in the semiarid region of the Paraíba state.

  13. An integrative approach to characterize hydrological processes and water quality in a semi-arid watershed in Northeastern Brazil

    Science.gov (United States)

    Franklin, M. R.; Fernandes, N.; Veiga, L. H. S.; Melo, L. R.; Santos, A. C. S.; Araujo, V. P.

    2014-12-01

    Arid and semi-arid regions face serious challenges in the management of scarce water resources. This situation tends to become worse with the increasing population growth rates and consequently increasing water demand. Groundwater is the most important water resource in these areas and, therefore, the sustainability of its use depends on the effectiveness in which it is managed, both in terms of quantity and quality. The Caetité Experimental Basin (CEB), located in a semi-arid region of Northeastern Brazil, faces not only the challenges associated with water scarcity, but also changes in landscape and potential contamination processes due to mining activity. The only active uranium production center in Brazil (URA) is located in this watershed and the sustainability of mining and milling operations as well as the survival of the local community are highly dependent on the availability of groundwater resources. Hydrogeological studies in this area are scarce, and the potential contamination and overexploitation of groundwater can not be ruled out. Therefore, a national project was launched in order to improve the understanding and quantification of the interaction between the hydrogeological system and human health. The methodological approach involved hydrological and geochemical monitoring and characterization of the CEB, use of isotopic techniques, groundwater modeling, water quality diagnosis and human health risk assessment due to water ingestion. The results suggested that the groundwater in the CEB are not totally connected, with evidence of a mixture of recent and old waters. The Na-Ca-HCO3-Cl is the dominant water type (50%) followed by Ca-Na-HCO3-Cl water type (17%). The relevant non-radioactive contaminants are Mn, F, NO3 and Ba, mostly from natural origin, with the exception of NO3 that could be associated with the livestock activities. The estimated effective doses due to groundwater ingestion containing radionuclides are below the recommended

  14. The Mind of the Copaíba Tree: Notes on Extractivism, Animism, and Ontology from Southern Bahia

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    Jonathan DeVore

    2017-12-01

    Full Text Available This article analyzes ritualized prescriptions for harvesting oleoresin or “oil” from the copaíba tree in Brazil. These harvesting prescriptions involve increasingly complex attributions of mind to the copaíba tree itself. The copaíba tree is widespread throughout the Americas, and for centuries has been well-known for the medicinal oil that can be extracted from its trunk. In Brazil, contemporary knowledge of the copaíba tree is bound up with colonial history and what were often destructive extractivist economies. Whereas historical accounts of the copaíba tree are often limited to mechanistic descriptions for extracting oil, this article examines attributions of mind that harvesters make to the copaíba tree. These attributions can be read from procedures for extracting oil. Such procedures are concerned with moon cycles, tree marking, sexual activity, and gaze. The article shows that such prescriptions have a wide transregional and interethnic distribution, from the Amazon Basin in northern Brazil to the Atlantic Forest on Bahia’s southern coast. New evidence from southern Bahia also involves prescriptions concerning speech and naming, which presuppose that the copaíba tree is sensitive to intentionality and human language. These mind attributions are inferred through pragmatic analysis of the (ontological presuppositions that are embedded by harvesting prescriptions. The contribution concludes with reflections on the implications of this presuppositional analytic approach for debates concerned with animism and the “ontological turn.”

  15. The Sr:Ba:Rb ratio and zircon typology in granitoid complexes of Sao Paulo, Parana and Minas Gerais states (Brazil)

    International Nuclear Information System (INIS)

    Wernick, E.; Galembeck, T.M.B.; Artur, A.C.; Rigo Junior, L.; Weber-Diefenbach, K.

    1990-01-01

    Chemical (Sr: Ba: Rb) and zircon typology data from the Nazare Paulista, Mairipora/Cantareira, Cunhaporanga, Tres Corregos, Morungaba, Socorro, Itu, Graciosa and Serra Carambei granitoid complexes from the states of Minas Gerais, Sao Paulo and Parana (SE/S Brazil) are presented and discussed. By the zircon typology method these complexes are reffered, respectively, to the 2nd crustal, 3rd crustal/low temperature C-A, low temperature C-A, medium temperature C-A, medium/high temperature C-A, K-SA/Alkaline and alkaline serie which are considered as generated under increasing temperature associated with a progressive major participation of mantellic material. All these series, with the exception of the medium to high temperature calc-alkaline complexes Socorro and Morungaba whose chemical data come from several laboratories, display different positions and behaviour in the Sr: Ba: Rb diagram which reinforce the use of the zircon typology method in the study of granitoids. From the 2nd crustal serie up to the medium temperature C-A serie the complexes show a regular shift in their chemical composition which became progressively richer in Sr and depleted in Rb. The highly differentiades hypersolvus Serra do Carambei granite is strongly enriched in Rb and impoverish in Ba with respect to the Itu and the Graciosa complex which itself is slighly more depleted in Sr than the Itu granite. (author)

  16. Experimental study of the uranium mobility due to the weathering action at the uraniferous district of Caetite/Lagoa Real, Bahia, Brazil; Estudo experimental da mobilidade do uranio por acao intemperica, distrito uranifero de Caetite/Lagoa Real, Bahia, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Scislewski, Alexandro Rocha

    2004-01-15

    In the present research, the proposal was to develop a preliminary study about the geochemical behavior of determined chemical elements, mainly the uranium, during the action of weathering processes in the rocks that bear the uranium mineralizations of the Caetite-Lagoa Real region, State of Bahia, more specifically of the Jazida Cachoeira uranium mine. To reach this purpose were used samples that represent several stages of the milling process of the uranium ore, so selecting representatives of the host rock, the ore and the treated ore (waste from the milling plant) to be used in the laboratory-controlled experiments. The samples were dried, sieved and finally introduced in the reactors, these adapted from the Flow-Through Reactor of Brantley and Chen. In the geochemical point of view, the results of the experiments showed a distinct behavior between the samples. It was observed that the treated ore, in relation to the host rocks of the ore and the own ore, shown a faster and homogeneous interaction with the leaching solution; it was also noted that in the output solution of the treated ore samples existed a significant complexation of the uranium by the sulfate (S0{sub 4}{sup -2}), ), instead of the non treated samples (host rock and ore) that were complexed mainly by the carbonate (C0{sub 3}{sup -2}). These different results are attributed to the alterations imposed to the rock during the milling process, and occur mainly, during the acid attack in the leaching process of the milling plant. The results and conclusions of this research, in spite of been preliminary, are essential to understand the behavior of the geochemical speciation of the effluent solutions; to understand the alterations of a rock matrix, and finally, to understand the migration chemical behavior of the related chemical elements. It is expected that these results contribute, in the future, to a deeper knowledge of the processes that control the chemical composition of the natural waters from

  17. Plastic ingestion by sea turtles in Paraíba State, Northeast Brazil

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    Camila Poli

    2015-09-01

    Full Text Available ABSTRACT Currently, plastics are recognized as a major pollutant of the marine environment, representing a serious threat to ocean wildlife. Here, we examined the occurrence and effects of plastic ingestion by sea turtles found stranded along the coast of Paraíba State, Brazil from August 2009 to July 2010. Ninety-eight digestive tracts were examined, with plastic found in 20 (20.4%. Sixty five percent (n = 13 of turtles with plastic in the digestive tract were green turtles (Chelonia mydas, 25% (n = 5 were hawksbills (Eretmochelys imbricata, and 10% (n = 2 were olive ridley (Lepidochelys olivacea. More plastic was found in the intestine (85% than in other parts of the gastrointestinal tract. We observed complete blockage of the gastrointestinal tract due to the presence of plastic in 13 of the 20 turtles that had ingested plastic. No correlation was found between the curved carapace length (CCL and the number or mass of the plastic ingested items. Significant differences were found between the intake of hard and soft plastic and the ingestion of white/transparent and colored plastic, with soft and white/transparent plastics being more commonly ingested. This study reveals the serious problem of plastic pollution to sea turtles at the area.

  18. Uranium concentrations in the water consumed by the resident population in the vicinity of the Lagoa Real uranium province, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Luciana S. [State University of Bahia (UNEB), Campus Caetite, BA (Brazil); Pecequilo, Brigitte R.S.; Sarkis, Jorge; Nisti, Marcelo B., E-mail: brigitte@ipen.br, E-mail: jesarkis@ipen.br, E-mail: mbnisti@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-07-01

    The Lagoa Real Uranium Province, situated in South Central Bahia in the region of Caetite and Lagoa Real, is considered the most important monomineralic province of Brazil. The urban population who lives in the proximities of this uranium province in the cities of Caetite, Lagoa Real and Livramento uses public supply water, while the inhabitants of the rural area due to long terms of dry weather use water from wells, cisterns, small dams, reservoirs and dikes which are supplied with the rains. In this work it was determined the concentration of uranium in the water consumed by the rural and urban population living in the proximities of the Lagoa Real Uranium Province. The study comprehends 32 sampling spots spread throughout the region of interest. Samples were collected in January and July 2010, covering superficial, underground and public supply water from the region. The uranium concentrations were determined by an inductively coupled plasma mass spectrometer (ICP-MS). Preliminary results showed that the uranium concentrations in the water from the Lagoa Real Uranium Province varied from 0.064 {+-} 0.005 {mu}g.L{sup -1} to 90 {+-} 1,5 {+-}g.L{sup -1}. It was observed that only two of them obtained values higher than the World Health Organization's recommended limit (2011) of 30 {mu}g.L{sup -1} for maximum uranium concentration in the water for human consumption. For a conclusive evaluation, the uranium concentrations results will be analyzed together with total alpha and beta concentrations determined elsewhere for the same samples. (author)

  19. Uranium concentrations in the water consumed by the resident population in the vicinity of the Lagoa Real uranium province, Bahia, Brazil

    International Nuclear Information System (INIS)

    Silva, Luciana S.; Pecequilo, Brigitte R.S.; Sarkis, Jorge; Nisti, Marcelo B.

    2011-01-01

    The Lagoa Real Uranium Province, situated in South Central Bahia in the region of Caetite and Lagoa Real, is considered the most important monomineralic province of Brazil. The urban population who lives in the proximities of this uranium province in the cities of Caetite, Lagoa Real and Livramento uses public supply water, while the inhabitants of the rural area due to long terms of dry weather use water from wells, cisterns, small dams, reservoirs and dikes which are supplied with the rains. In this work it was determined the concentration of uranium in the water consumed by the rural and urban population living in the proximities of the Lagoa Real Uranium Province. The study comprehends 32 sampling spots spread throughout the region of interest. Samples were collected in January and July 2010, covering superficial, underground and public supply water from the region. The uranium concentrations were determined by an inductively coupled plasma mass spectrometer (ICP-MS). Preliminary results showed that the uranium concentrations in the water from the Lagoa Real Uranium Province varied from 0.064 ± 0.005 μg.L -1 to 90 ± 1,5 ±g.L -1 . It was observed that only two of them obtained values higher than the World Health Organization's recommended limit (2011) of 30 μg.L -1 for maximum uranium concentration in the water for human consumption. For a conclusive evaluation, the uranium concentrations results will be analyzed together with total alpha and beta concentrations determined elsewhere for the same samples. (author)

  20. Nuclear fuel cycle facilities and RP: the case of Brazil

    International Nuclear Information System (INIS)

    Tranjan Filho, Alfredo; Costa, Cesar Gustavo S.

    2008-01-01

    Full text: The renewed nuclear energy scenario, national and worldwide, calls for the strengthening of all activities involving the nuclear fuel production, from uranium extraction at the mines to fuel assemblies delivery at the nuclear power plants, which in Brazil is the mission of the Industrias Nucleares do Brasil (INB). With only a third of its territory prospected, Brazil currently has the sixth largest uranium reserve in the world. Brazil's three main deposits are: the Caldas mine (in the state of Minas Gerais) the first mineral-industrial complex that processed uranium, developed in 1982, and presently being decommissioned; Caetite mine and processing facility (located in the state of Bahia), nowadays operational and with a current production capacity of 400 tonnes per year of uranium concentrates, being in trend of doubling its annual capacity; and the Itataia/Santa Quiteria deposit (in Ceara State), the largest geological uranium reserve in Brazil, although its feasible future production depends on the exploration of the phosphate associated to it. Concerning the nuclear fuel fabrication, INB plant at Resende (in the state of Rio de Janeiro) is responsible for the conversion of Uf 6 to UO 2 the production of fuel pellets and the assembly of the fuel elements, in order to supply the demands of Brazil's two operating PWR (Angra 1 and Angra 2). In addition, in May 2006, INB-Resende inaugurated the uranium enrichment facility, employing the ultra-centrifugation technology. Today still in its first phase of operation, when completed the enrichment facility is intended to provide 100 percent of the domestic requirements, eventually by the year 2015. Detailing present status and future perspectives of INB, in face of the global and national renaissance of nuclear energy, this paper addresses the Radiation Protection (RP) aspects related to INB's achievements and performance, as well as the pressing future challenges to be dealt with, in order to guarantee

  1. The occurence of black spot disease in Astyanax aff. fasciatus(characiformes: characidae in the Guaíba Lake basin, RS, Brazil

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    F Flores-Lopes

    Full Text Available Black spot disease is common in freshwater fish and is usually caused by the metacercaria stage of digenetic trematodes, normally from the Diplostomidae family. The present study evaluated the prevalence and intensity of this disease in Astyanax aff. fasciatus(Teleostei: Characiformes in the Guaíba Lake basin (RS, Brazil, including body parts assessment and the points of sampling with higher occurrence of black spots. Fish samples were taken seasonally from December 2002 until October 2004. The samples were collected with the use of a seine net at eleven points. The specimens were fixed in 10% formalin and stored in 70% ethanol. Black spot disease showed a low frequency in the Guaíba lake basin (2.07% and no specificity to the species Astyanax aff. fasciatus was observed. A high prevalence among the individuals and high intensity of infection levels was found in the ventral and dorsal regions in relation to other body parts (e.g., pectoral, pelvic and anal regions. Among the sampling points studied, we observed a higher prevalence on samples collected at points Gasômetro, Saco da Alemoa and Sinos, located in open areas with less occurrence of mollusks.

  2. Mercury contents in aquatic macrophytes from two reservoirs in the Paraíba do Sul: Guandú river system, SE Brazil

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    M. M. Molisani

    Full Text Available This paper reports on a study to determine the Hg content in the five most abundant aquatic macrophyte species (Elodea densa, Sagittaria montevidensis, Salvinia auriculata, Pistia stratiotes and Eichhornia crassipes in two artificial reservoirs flooded by water diverted from the Paraíba do Sul river, SE Brazil. The potential of these species for Hg accumulation and their role in Hg transport along the river system due to macrophyte management were evaluated. Mercury concentrations were higher in free-floating than in rooted species. Roots were also richer in Hg than were leaves. Dry weight Hg concentrations in leaves and roots from all species varied from 46-246 ng.g-1 to 37-314 ng.g-1, respectively. These values are higher than those reported for uncontaminated lakes in Brazil and in other tropical areas and similar to those reported for moderately contaminated sites. Mercury concentrations can be attributed to fluvial transport from the heavily industrialized Paraíba do Sul river basin. Intensive sampling of Pistia stratiotes from two sites in the Vigário reservoir was performed to evaluate the capacity of Hg incorporation in short periods of time. The results showed a significant negative correlation between Hg content and size class of individual plants, demonstrating the importance of juveniles, fast growing plants in absorbing Hg. The foremost impact related to Hg contents in the studied area concerns the periodic removal of macrophytes for reservoir management, followed by disposal in nearby areas. This results in the mobilization of 0.52 to 1.3 Kg of Hg per year, a significant fraction of the Hg burden present in reservoir waters. Disposal of such material may result in Hg leaching to river systems, affecting the Hg transfer throughout the basin.

  3. Evaluation of the cytotoxic and genotoxic potential of water from the River Paraíba do Sul, in Brazil, with the Allium cepa L. test

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    A. Barbério

    Full Text Available This work investigated the cytotoxic and genotoxic potential of water from the River Paraíba do Sul (Brazil using Allium cepa roots. An anatomo-morphological parameter (root length, mitotic indices, and frequency of micronuclei were analysed. Eight bulbs were chosen at random for treatment for 24 to 120 hours with the River water collected in the years of 2005 and 2006 from sites in the cities of Tremembé and Aparecida (São Paulo state, Brazil. Daily measurements of the length of the roots grown from each bulb were carried out throughout the experiment. Mitotic index (MI and frequency of micronuclei (MN were determined for 2000 cells per root, using 3-5 root tips from other bulbs (7-10. Only in the roots treated with samples of the River water collected in 2005 in Tremembé city was there a decrease in the root length growth compared to the respective control. However, a reduction in MI values was verified for both sites analysed for that year. Considering the data involving root length growth and especially MI values, a cytotoxic potential is suggested for the water of the River Paraíba do Sul at Tremembé and Aparecida, in the year of 2005. On the other hand, since in this year the MN frequency was not affected with the river water treatments, genotoxicity is not assumed for the river water sampled at the aforementioned places.

  4. Sheep gastrointestinal helminthiasis in the Sertão region of Paraíba State, Northeastern Brazil: prevalence and risk factors.

    Science.gov (United States)

    Vieira, Vanessa Diniz; Vilela, Vinícius Longo Ribeiro; Feitosa, Thais Ferreira; Athayde, Ana Célia Rodrigues; Azevedo, Sérgio Santos; Souto, Diego Vagner de Oliveira; Silveira, Gian Libânio da; Melo, Lídio Ricardo Bezerra de

    2014-01-01

    In this study, we aimed to establish the prevalence and risk factors relating to gastrointestinal helminthiasis, and to characterize the sanitary management practiced among sheep herds in the Sertão region of the state of Paraíba, northeastern Brazil, based on factors that condition the ways of controlling these parasites in these herds. The research was carried out between April and July 2012. We visited 54 farms, where fecal and blood samples were individually collected from 465 animals. On each farm, a questionnaire was applied to gather information on variables relating to potential risk factors. The prevalence of sheep gastrointestinal helminthiasis in the region was 75.9%. At least one animal tested positive for this helminthiasis on 53 (98.1%) of the 54 farms evaluated. The eggs per gram of feces (EPG) analysis showed the following infection burdens: 51.8% with mild infection, 27.1% moderate infection, 9.9% heavy infection and 11.2% fatal infection. Among the sheep farms visited, anthelmintics were used on 81.5% (p helminthiasis, because the animals are more prone to reinfection. The Sertão region of Paraíba presents high prevalence of gastrointestinal helminthiasis among sheep, and the farm area is the most relevant risk factor for the development of these parasites.

  5. Systemic acanthamoebiasis associated with canine distemper in dogs in the semiarid region of Paraíba, Brazil

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    Maria T.S. Frade

    2015-02-01

    Full Text Available Infections by free-living amoebae can cause systemic disease in animals and humans. We describe the epidemiological, clinical and pathological aspects of disseminated acanthamoebiasis associated with canine distemper in three dogs of the semiarid region of Paraíba, Northeastern Brazil. Affected dogs developed progressive neurological and respiratory signs that progressed to death within in two to 20 days. Gross lesions were irregular and with yellow-reddish nodules randomly distributed in the lungs, heart, kidneys, spleen, lymph nodes, adrenals, and intestine. One dog had foci of malacia in the parietal cortex and another one in nucleus of brain basis. Histologically, pyogranulomas with areas of necrosis and hemorrhage in all organs affected were observed, associated with myriads of intralesional amoebic trophozoites. All three cases were concomitant canine distemper, that possibly triggered immunosuppression in the dogs. The diagnosis was performed through microscopic findings of infection by free-living amoebae and confirmed Acanthamoeba sp. by immunohistochemistry

  6. A prática de amamentar entre mulheres que exercem trabalho remunerado na Paraíba, Brasil: um estudo transversal Breastfeeding practices among paid working mothers in Paraíba State, Brazil: a cross-sectional study

    Directory of Open Access Journals (Sweden)

    Rodrigo Pinheiro de Toledo Vianna

    2007-10-01

    Full Text Available Estar no mercado de trabalho não deve impedir a mulher de amamentar. A Organização Mundial de Saúde preconiza o aleitamento materno exclusivo até seis meses de vida. No Brasil as leis propiciam à mulher trabalhadora quatro meses de licença maternidade, mas nem sempre ela recebe este benefício. Assim, como praticar amamentação exclusiva? Este artigo objetiva descrever as taxas de aleitamento materno e se o trabalho remunerado interfere na amamentação de mães da Paraíba. Trata-se de estudo transversal em 70 de 223 municípios que aceitaram participar da pesquisa na campanha de vacinação em 2002. Em 11.076 crianças menores de um ano, a prevalência de amamentação exclusiva foi de 22,4% de 0-4 meses e foi significativamente maior entre as mães que trabalhavam fora e que tiveram licença maternidade. Entre estas, foi também menor a prevalência de amamentação total e predominante. Na zona rural o trabalho fora de casa esteve associado com a redução do aleitamento materno exclusivo. A prática do amamentar na Paraíba está muito aquém das recomendações e o retorno precoce da mãe ao trabalho agrava esta situação.Paid work should not be an obstacle to women's breastfeeding. The World Health Organization (WHO recommends exclusive breastfeeding for 6 months. In Brazil, women are legally entitled to 4 months of maternity leave, but in practice few women enjoy such benefits. How is it possible to practice exclusive breastfeeding for 6 months? We analyzed both the breastfeeding rates and whether paid jobs interfere with breastfeeding in Paraíba State, Northeast Brazil. We conducted a cross-sectional study in 70 of 223 municipalities (counties during the annual immunization campaign in 2002. Among 11,076 infants (< 12 months of age, the exclusive breastfeeding rate at 0-4 months was 22.4% and was significantly higher among working women receiving maternity leave as compared to those who did not. The prevalence of total and

  7. REPTILE SPECIES COMPOSITION IN THE MIDDLE GURGUÉIA AND COMPARISON WITH INVENTORIES IN THE EASTERN PARNAÍBA RIVER BASIN, STATE OF PIAUÍ, BRAZIL

    Directory of Open Access Journals (Sweden)

    CLÁUDIA RENATA MADELLA-AURICCHIO

    Full Text Available ABSTRACT The reptile diversity of the Middle Gurguéia River Basin in southern Piauí, Brazil, is little known. The rapid expansion of agriculture in the region is converting the Cerrado and Caatinga into large farming areas, which threatens biodiversity and hastens its loss. In this study, 68 specimens of reptiles from a university collection were examined, comprising 29 species: ten lizards, one amphisbaenian, 15 snakes, two turtles and one crocodilian. They were collected from five locations in the Middle Gurguéia Basin, a region not previously evaluated for reptiles. The most abundant species is a member of Tropidurus. Comparison with eight other areas in the eastern Parnaíba Basin indicated that the diversity of reptiles in the Middle Gurguéia is similar to that in other Caatinga-Cerrado ecotone areas. The reptile assemblage in the eastern Parnaíba Basin comprises 100 species of reptiles: 39 lizards, five amphisbaenians, 50 snakes, four chelonians and two crocodilians. This study expanded the known distributions of some reptiles and recorded the first occurrence of Helicops leopardinus (Schlegel, 1837 for Piauí. A cluster analysis showed that the reptile composition concords with the habitat where species were found, i.e. Cerrado, Caatinga or ecotone. Studies that associate habitat structure with each species are essential to propose efficient strategies for reptile management and conservation for the entire Parnaíba River Basin, mostly in areas that are not yet protected.

  8. Leaching of uranium from the Osamu Utsumi mine wastes, INB Caldas, Minas Gerais, Brazil

    International Nuclear Information System (INIS)

    Santos, Elizangela A.; Ladeira, Ana Claudia Q.

    2009-01-01

    Mining is one of the leading sectors of the Brazilian economy and as any other anthropogenic activity it generates residues that impact the environment directly. The Osamu Utsumi Mine, which belongs to the Nuclear Industries of Brazil (INB), operated from 1982 to 1995 with the activities of mining and metallurgical treatment of the uranium ore. Since then the INB has as a main environmental problem, the generation of acid mine drainage from wastes having its pH around 3. The chemical treatment of this acid water incurs an extremely high cost and generates a precipitate that is rich in some metals, including uranium. This precipitate has been disposed of in the mine opening and has caused an overload of chemical pollutants and radioactive elements in a place that was not planned to receive this volume of residues and does not meet the necessary condition for the construction of a repository. The content of uranium in the precipitate is approximately 0.25% - similar to the content of the metal found in the ore in the Caetite Mine (BA) - around 0.29%. The recovery of this uranium from the precipitate would generate a total of 150 tons of U 3 O 8 . In the present study an alkaline leaching process was carried out aiming at recovering the uranium from sludge samples disposed of for over 20 years. Sodium carbonate and bicarbonate were used as the leaching agents. The experiments were carried out by varying the concentrations of the leaching agents, extraction time and the solid percentage. The other parameters such as temperature, particle size and agitation were kept constant. The results showed that the recovery of the uranium can reach 100% in 24 hours. The uranium concentration in the solutions is around 250 mg.L -1 when using 10% of solids. Preliminary results showed that the recovery of uranium from the sludge would be a feasible practice. The conversion of an environmental liability into a valuable product is one of the most important objectives of this work

  9. Prevalência de defeitos de fechamento de tubo neural no Vale do Paraíba, São Paulo Prevalence of neural tube defects in Vale do Paraíba, São Paulo, Brazil

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    Luiz Fernando C. Nascimento

    2008-12-01

    Full Text Available OBJETIVO: Estimar a prevalência de defeitos de fechamento do tubo neural no Vale do Paraíba paulista e identificar possíveis fatores maternos e neonatais associados a tais defeitos. MÉTODOS: Realizou-se um estudo transversal com dados secundários obtidos na Secretaria Estadual da Saúde referentes aos nascimentos ocorridos em 2004 no Vale do Paraíba paulista, que compreende 35 municípios e conta com população de 2 milhões de habitantes. Anencefalia, encefalocele e espina bífida (mielocele e mielomeningocele foram considerados defeitos de fechamento do tubo neural. As variáveis maternas foram: idade, escolaridade, cor da pele, número de consultas no pré-natal, número de filhos vivos e relato de óbito fetal prévio. As variáveis relativas ao recém-nascido foram: peso, idade gestacional e escore de Apgar. Realizou-se comparação das médias por meio do teste t de Student e obtiveram-se os valores das razões de chance com intervalos de confiança de 95%. RESULTADOS: Foram analisados 33.653 nascidos vivos. Trinta e oito recém-nascidos com o defeito foram encontrados (1,13/1.000 nascidos vivos, sendo 23 casos de espina bífida. Houve associação com baixo peso ao nascimento, prematuridade e menores escores de Apgar de cinco minutos. CONCLUSÕES: A prevalência desta anomalia foi inferior à de outros estudos nacionais e sua presença esteve associada ao baixo peso, à prematuridade e à baixa vitalidade ao nascer.OBJECTIVE: To estimate the prevalence of neural tube defects in Vale do Paraíba, São Paulo, Brazil, and to identify possible maternal and neonatal variables associated with these defects. METHODS: This cross-sectional study used secondary records of the Health Department of São Paulo State related live births during 2004 in Vale do Paraíba, São Paulo, Brazil. This region has 35 cities and 2 million inhabitants. Anencephaly, encephalocele and spina bifida (myelocele and myelomeningocele were considered as neural tube

  10. CHARCOAL-PRODUCING INDUSTRIES IN NORTHEASTERN BRAZIL

    Science.gov (United States)

    Charcoal workers in northeastern Brazil: Occupational risks and effects of exposure to wood smokeABSTRACTBrazil has the largest production of charcoal in the world, which is used mostly in the iron and steel industries. In most of the production sites, the process is ba...

  11. 65Zn and 133Ba standardizing by photon-photon coincidence counting

    International Nuclear Information System (INIS)

    Loureiro, Jamir S.; Cruz, Paulo A.L. da; Iwahara, Akira; Delgado, José U.; Lopes, Ricardo T.

    2017-01-01

    The LNMRI/Brazil has deployed a system using X-gamma coincidence technique for the standardizing radionuclide, which present simple and complex decay scheme with X-rays of energy below 100 keV. The work was carried on radionuclide metrology laboratory using a sodium iodide detector, for gamma photons, in combination with a high purity germanium detector for X-rays. Samples of 65 Zn and 133 Ba were standardized and the results for both radionuclides showed good precision and accuracy when compared with reference values. The standardization differences were 0.72 % for 65 Zn and 0.48 % for 133 Ba samples. (author)

  12. 65Zn and 133Ba standardizing by photon-photon coincidence counting

    Science.gov (United States)

    Loureiro, Jamir S.; da Cruz, Paulo A. L.; Iwahara, Akira; Delgado, José U.; Lopes, Ricardo T.

    2018-03-01

    The LNMRI/Brazil has deployed a system using X-gamma coincidence technique for the standardizing radionuclide, which present simple and complex decay scheme with X-rays of energy below 100 keV. The work was carried on radionuclide metrology laboratory using a sodium iodide detector, for gamma photons, in combination with a high purity germanium detector for X-rays. Samples of 65Zn and 133Ba were standardized and the results for both radionuclides showed good precision and accuracy when compared with reference values. The standardization differences were 0.72 % for 65Zn and 0.48 % for 133Ba samples.

  13. Ethnobotanical survey of plants with toxic active constituents, grown in the municipality of Cuité, Paraíba, Brazil

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    Diégina Araújo FERNANDES

    2017-12-01

    Full Text Available Incidents involving plants have been a major problem for public health over the years and represent the fourth leading cause of poisoning in Brazil, leading to death many people, especially children. This study aimed to carry out an ethnobotanical survey of plants with toxic active constituents, grown in the municipality of Cuité, Paraíba, correlating the popular and scientific knowledge. This study conducted an exploratory and descriptive field research by applying semi-structured questionnaires to city dwellers who maintained frequent contact with plants. The identification of 19 toxic species and 18 potentially poisonous species was possible. Prevalent plants in homes were ornamental. Most respondents were senior women who carried out this practice over ten years, and this interest in cultivation had come through relatives. The survey showed that most interviewees unaware the toxic potential of cited plants, which indicates the need to carry out educational and preventive work among the population.

  14. Explosive pollination mechanism in Periandra mediterranea (Vell. Taub. (Fabaceae in the Guaribas Biological Reserve, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Andressa Cavalcante Meireles

    2015-12-01

    Full Text Available Periandra mediterranea (Vell. Taub. has papilionaceous flowers with a complex pollination mechanism. This study examined pollination and reproduction in P. mediterranea from November 2009 to October 2011 at the Guaribas Biological Reserve, Paraíba, Brazil. The petals are modified in a keel that protects the stamens and stigma; two wings surround the keel, and a standard that serves as landing platform for floral visitors. Periandra mediterranea exhibits an explosive type pollination mechanism in which the bee species Xylocopa frontalis, Acanthopus excellens and Epicharis sp., land on the standard and, due to body weight, expose the reproductive organs in the wing-keel complex. As a result, the reproductive organs of the flower come into contact with the dorsal region of the bee body, depositing pollen (i.e., nototríbic pollination. Reproductive assays showed 20% fruiting in spontaneous auto-pollination, 33% in manual auto-pollination, 33% in manual cross-pollination, and 100% in the control group, with no reproductive success while in apomixis. These results demonstrate self-compatibility in this species, however it depends on pollinators to ensure reproductive success.

  15. Migratory flows and foraging habitat selection by shorebirds along the northeastern coast of Brazil: The case of Baía de Todos os Santos

    Science.gov (United States)

    Lunardi, Vitor O.; Macedo, Regina H.; Granadeiro, José P.; Palmeirim, Jorge M.

    2012-01-01

    Large numbers of Nearctic shorebirds migrate and winter along the coast of northeastern Brazil, but there is little information on their migratory flows, foraging ecology, and on the structure of the species assemblages that they form with resident shorebirds. We studied these issues on intertidal flats of Baía de Todos os Santos (Bahia), the second largest bay in Brazil. During a full year cycle we carried out weekly bird counts in an intertidal area of 280 ha divided in sectors, where we also measured environmental parameters. The analyses of weekly counts resulted in a detailed phenology of use of the area by shorebirds. Five species were resident and ten were Nearctic migrants. Several of the latter had clear peaks in numbers in March and October, revealing the use of the bay as a stopover during both the north-bound and south-bound migration flows. A canonical correspondence analysis of the relationship between environmental parameters and bird numbers indicated that the foraging bird assemblage could be divided into five main groups, occupying distinct ecological gradients in the study area. The most important factors driving this structure were invertebrate prey abundance, percentage of fine sediments, area of mangrove cover and distance to channels. Our findings imply that maintenance of the diversity of intertidal habitats in this bay is crucial to satisfy the particular habitat requirements of resident and migrant shorebirds using the northeastern coastal regions of Brazil.

  16. Prevalence and risk factors associated with goat gastrointestinal helminthiasis in the Sertão region of Paraíba State, Brazil.

    Science.gov (United States)

    Vieira, Vanessa Diniz; Feitosa, Thais Ferreira; Vilela, Vinícius Longo Ribeiro; Azevedo, Sérgio Santos; de Almeida Neto, João Leite; de Morais, Dayana Firmino; Ribeiro, Ana Raquel Carneiro; Athayde, Ana Célia Rodrigues

    2014-02-01

    Gastrointestinal helminthiasis represents an obstacle to goat raising, causing severe damage to herds such as growth retardation, weight loss, and even death. In this study, we aimed to determine the prevalence and risk factors associated to goat gastrointestinal helminthiasis in the Sertão region of Paraíba State, Brazil. A total of 256 goats from 54 farms were systematically sampled. Blood and fecal samples were collected from each animal for egg per gram (EPG), larval culture, and packed cell volume (PCV) analyses. We found that 79.3% of the goats investigated were parasitized with gastrointestinal helminths. Significant correlation (p = 0.004) was observed between the EPG and PCV of the animals studied, and it was observed that the EPG increases as the PCV decreases. In the larval culture, the most prevalent helminth was Haemonchus sp. (83.2%). Age and sex were significant variables (p ≤ 0.20) for the development of gastrointestinal helminths: 86.8% of animals over 36 months of age and 81.7% of females were infected. The variable type of animal exploitation was also significant, with 90.3% (p ≤ 0.20) of the animals presenting double suitability (milk and meat). The Sertão region of Paraíba State presents high prevalence of gastrointestinal helminthiasis in goats, and age and type of animal exploitation are the most relevant risk factors to the development of these parasites.

  17. Early signals of environmental and health impacts caused by uranium mining in Caetite, Bahia, Brazil

    International Nuclear Information System (INIS)

    Brito, Adelson S. de; Rego, Rita de Cassia Franco; Zucchi, Maria do Rosario; Navarro, Marcus V. Teixeira

    2011-01-01

    Uranium mining and processing at Lagoa Real (Bahia, Brazil) in the southwest of Bahia state started in the year 2000.The processing of uranium ore for obtaining U3O8 (yellowcake) is done today in the processing unit of the Brazilian Nuclear Industries INB located in the area of the same municipality above mentioned. The production capacity is 400 tons / year of U3O8, and the reserves in this region are estimated at 100.000 tons of uranium without any other associated minerals, enough to supply the demand for nuclear power plants Angra I and II for over 100 years. Since the granting of AOP (Permanent Operation Authorization) by CNEN (National Commission on Nuclear Energy) in the year 2009, there were some incidents at the facility, such as: solvents and liquid containing uranium overflow; pipes rupture, causing indiscriminate dispersion of toxic acids and other chemical agents; collapse of parts of the slope of the open pit. CNEN admitted in an official press release on April 1, 2011 that 'INB has no capacity to produce annual reports on environmental monitoring (unable to perform radiometric measurements, etc.). The last time a report was released happened in the year 2008. These reports are vital to the environmental impact assessment of the facility'. Another potential source of environmental and health negative impacts on the local population could be linked to radon emission. What are the levels of this important pollutant in the affected areas? (author)

  18. Early signals of environmental and health impacts caused by uranium mining in Caetite, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Brito, Adelson S. de; Rego, Rita de Cassia Franco [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Dept. de Medicina Preventiva. Programa de Pos-Graduacao em Saude, Ambiente e Trabalho; Zucchi, Maria do Rosario [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Dept. de Fisica da Terra. Lab. de Fisica Nuclear Aplicada; Navarro, Marcus V. Teixeira, E-mail: mvtn@ifba.edu.b [Instituto Federal da Bahia (LAFIR/NTS/IFBA) Salvador, BA (Brazil). Nucleo de Tecnologia em Saude. Lab. de Fisica Radiologica

    2011-07-01

    Uranium mining and processing at Lagoa Real (Bahia, Brazil) in the southwest of Bahia state started in the year 2000.The processing of uranium ore for obtaining U3O8 (yellowcake) is done today in the processing unit of the Brazilian Nuclear Industries INB located in the area of the same municipality above mentioned. The production capacity is 400 tons / year of U3O8, and the reserves in this region are estimated at 100.000 tons of uranium without any other associated minerals, enough to supply the demand for nuclear power plants Angra I and II for over 100 years. Since the granting of AOP (Permanent Operation Authorization) by CNEN (National Commission on Nuclear Energy) in the year 2009, there were some incidents at the facility, such as: solvents and liquid containing uranium overflow; pipes rupture, causing indiscriminate dispersion of toxic acids and other chemical agents; collapse of parts of the slope of the open pit. CNEN admitted in an official press release on April 1, 2011 that 'INB has no capacity to produce annual reports on environmental monitoring (unable to perform radiometric measurements, etc.). The last time a report was released happened in the year 2008. These reports are vital to the environmental impact assessment of the facility'. Another potential source of environmental and health negative impacts on the local population could be linked to radon emission. What are the levels of this important pollutant in the affected areas? (author)

  19. Estudo do comportamento reológico das argilas bentoníticas de Cubati, Paraíba, Brasil Rheological behavior study of bentonite clays from Cubati, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    R. R. Menezes

    2009-12-01

    Full Text Available O estado da Paraíba possui jazidas de bentonitas utilizadas comercialmente para uma vasta gama de setores tecnológicos. No entanto, esses jazimentos estão se exaurindo, após dezenas de anos de exploração. Assim, este trabalho tem por objetivo dar prosseguimento à caracterização de argilas bentoníticas de Cubati, PB, estudando o comportamento reológico das dispersões argila-água de modo avaliar seu desempenho para fluidos de perfuração de poços de petróleo base água. As amostras estudadas foram secas a 60 ºC e determinou-se sua capacidade de troca de cátions. As argilas foram transformadas em sódica por tratamento com Na2CO3 e em seguida realizou-se o estudo do comportamento reológico das dispersões. As viscosidades, aparente e plástica, o volume de filtrado, os parâmetros reológicos do fluido e a sua força gel foram determinados. Os resultados evidenciaram que cada amostra apresenta um teor ótimo de carbonato de sódio e que as dispersões argila-água possuem um comportamento pseudo-plástico e tixotrópico. Duas amostras apresentam potencial para utilização como agentes viscosificantes para fluidos de perfuração.The bentonites of the state of Paraíba, Brazil, are commercially used in numerous technological sectors, particularly in oil drilling muds. However, these bentonite deposits are becoming exhausted due to several years of exploitation. Thus, the aim of this work was continue the characterization of the bentonites from Cubati, Paraíba, studying the rheological behavior of water-clay suspensions, evaluating their viability to be used in oil drilling muds. The samples were dried at 60 ºC and, their cation exchange capacity was determined. The natural bentonite clays were transformed in sodium bentonite by addition of concentrated Na2CO3 solution, then the suspensions rheological study was performed. The apparent and plastic viscosities, water loss, rheological parameters and the gel force were determined

  20. Explosive pollination mechanism in Periandra mediterranea (Vell. Taub. (Fabaceae in the Guaribas Biological Reserve, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Andressa Cavalcante Meireles

    2015-09-01

    Full Text Available http://dx.doi.org/10.5007/2175-7925.2015v28n4p71 Periandra mediterranea (Vell. Taub. has papilionaceous flowers with a complex pollination mechanism. This study examined pollination and reproduction in P. mediterranea from November 2009 to October 2011 at the Guaribas Biological Reserve, Paraíba, Brazil. The petals are modified in a keel that protects the stamens and stigma; two wings surround the keel, and a standard that serves as landing platform for floral visitors. Periandra mediterranea exhibits an explosive type pollination mechanism in which the bee species Xylocopa frontalis, Acanthopus excellens and Epicharis sp., land on the standard and, due to body weight, expose the reproductive organs in the wing-keel complex. As a result, the reproductive organs of the flower come into contact with the dorsal region of the bee body, depositing pollen (i.e., nototríbic pollination. Reproductive assays showed 20% fruiting in spontaneous auto-pollination, 33% in manual auto-pollination, 33% in manual cross-pollination, and 100% in the control group, with no reproductive success while in apomixis. These results demonstrate self-compatibility in this species, however it depends on pollinators to ensure reproductive success.

  1. {sup 65}Zn and {sup 133}Ba standardizing by photon-photon coincidence counting

    Energy Technology Data Exchange (ETDEWEB)

    Loureiro, Jamir S.; Cruz, Paulo A.L. da; Iwahara, Akira; Delgado, José U., E-mail: palcruz@ird.gov.br [Instituto de Radioproteção e Dosimetria (LNMRI/IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil). Lab. Nacional de Metrologia das Radiações Ionizantes; Lopes, Ricardo T. [Coordenacao de Pos-Graduacao e Pesquisa de Engenharia (PEN/COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear

    2017-07-01

    The LNMRI/Brazil has deployed a system using X-gamma coincidence technique for the standardizing radionuclide, which present simple and complex decay scheme with X-rays of energy below 100 keV. The work was carried on radionuclide metrology laboratory using a sodium iodide detector, for gamma photons, in combination with a high purity germanium detector for X-rays. Samples of {sup 65}Zn and {sup 133}Ba were standardized and the results for both radionuclides showed good precision and accuracy when compared with reference values. The standardization differences were 0.72 % for {sup 65}Zn and 0.48 % for {sup 133}Ba samples. (author)

  2. Diet, reproduction and population structure of the introduced Amazonian fish Cichla piquiti (Perciformes: Cichlidae in the Cachoeira Dourada reservoir (Paranaíba River, central Brazil

    Directory of Open Access Journals (Sweden)

    Tatiane Ferraz Luiz

    2011-06-01

    Full Text Available The Blue Peacock Bass (Cichla piquiti, native to the Tocantins-Araguaia river basin of the Amazon system, was introduced into the basin of the Paranaíba River, Paraná River system. Cachoeira Dourada reservoir is one of a series of dams on the Paranaíba River in central Brazil, where this fish has become established. A study of its feeding spectrum, combined with information about its reproductive characteristics and population structure, would enable the current state of this species in the reservoir to be assessed and might provide useful data for the management of other species native to this habitat. This study showed that the peacock bass has no predators or natural competitors in the reservoir and that reproduces continuously, with high reproductive rates, and has a smaller median length at first maturity (L50 than other species of Cichla. Its successful establishment in habitats strongly affected by human activity should cause changes in the whole structure of the local fish communities. Nonetheless, in this reservoir, there appears to be some sharing of the functions of this species with native carnivorous fish, a situation that may be sustained by the presence of a wide variety of foraging fish. Rev. Biol. Trop. 59 (2: 727-741. Epub 2011 June 01.

  3. Diet, reproduction and population structure of the introduced Amazonian fish Cichla piquiti (Perciformes: Cichlidae) in the Cachoeira Dourada reservoir (Paranaíba River, central Brazil).

    Science.gov (United States)

    Luiz, Tatiane Ferraz; Velludo, Marcela Roquetti; Peret, Alberto Carvalho; Rodrigues Filho, Jorge Luiz; Peret, André Moldenhauer

    2011-06-01

    The Blue Peacock Bass (Cichla piquiti), native to the Tocantins-Araguaia river basin of the Amazon system, was introduced into the basin of the Paranaíba River, Paraná River system. Cachoeira Dourada reservoir is one of a series of dams on the Paranaíba River in central Brazil, where this fish has become established. A study of its feeding spectrum, combined with information about its reproductive characteristics and population structure, would enable the current state of this species in the reservoir to be assessed and might provide useful data for the management of other species native to this habitat. This study showed that the peacock bass has no predators or natural competitors in the reservoir and that reproduces continuously, with high reproductive rates, and has a smaller median length at first maturity (L50) than other species of Cichla. Its successful establishment in habitats strongly affected by human activity should cause changes in the whole structure of the local fish communities. Nonetheless, in this reservoir, there appears to be some sharing of the functions of this species with native carnivorous fish, a situation that may be sustained by the presence of a wide variety of foraging fish.

  4. Diversidade da ictiofauna de poças de maré da praia do Cabo Branco, João Pessoa, Paraíba, Brasil Diversity of the tidal pool ichthyofauna of Cabo Branco beach, João Pessoa, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Ricardo S Rosa

    1997-01-01

    Full Text Available A survey of the tidal pool fish community was carried out between february/1987 and january/1988, at Cabo Branco Beach, João Pessoa, Paraíba, Brazil. Specimens were collected monthly at low tide, using rotenone. A total of 3143 specimens was obtained. The most speciose families were Ophichthidae (14% of the total number of species, Mugilidae (11% and Muraenidae (9%, and the most representative ones in number of individuais were Gobiidae (48%, Pomacentridae (13% and Labrisomidae (10%. The main resident species were Bathygobius soporator (Valenciennes, 1837 and Abudefduf saxalilis (Linnaeus, 1758. The presence of a large number of juveniles in the pools indicated the importance of the studied sites as nursery áreas for several fish species.

  5. Structural and elemental analysis of bottom sediments from the Paraíba do Sul River (SE, Brazil) by analytical microscopy

    Science.gov (United States)

    Miguens, Flávio Costa; Oliveira, Martha Lima de; Ferreira, Amanda de Oliveira; Barbosa, Laís Rodrigues; Melo, Edésio José Tenório de; Carvalho, Carlos Eduardo Veiga de

    2016-03-01

    The Paraíba do Sul River (PSR) is a medium-sized river that flows through the Minas Gerais, São Paulo and Rio de Janeiro Brazilian states the three most developed states in Brazil. Industrial parks and cities have historically been established along the river basin. The waters of PSR are used in agriculture, industry and human consumption of over 20 million people, including Rio de Janeiro City. Furthermore, the river receives effluent from these activities: agricultural runoff, industrial waste, and domestic sewage. Therefore, PSR has been considered polluted, particularly by heavy metals. In order to assess heavy metals in bottom sediments grains of the PSR, to infer their elemental composition, and to characterize individual sediment grains morphology, a non-destructive methodology - X-ray microanalyses (Scanning Electron Microscope coupled to Energy Dispersive X-rays Spectrometer/SEM/EDS) - was used. Heavy metals - Cr, Mn, Ni, Cu, Zn, Zr, Ag, Ba, Au, La, Ce, Nd, Th, Y, Sn, Os and Pb - were detected by SEM/EDS in bottom sediment grains from PSR, predominantly in grains with equivalent diameter ≤10 μm. They occurred as silicates, oxides (hydro-oxides), sulfides, carbonates, sulfates, phosphates and chlorides. All detected heavy metals occurred as, at least, one kind of soluble metal compound, mainly due to ionic exchange from silicates, with the exception of Ag, which was chloride, sulfate or metallic as Os, Au and Pb. These results corroborate heavy metal PSR pollution and food chain risk, considering that near-shore continental shelf is free of heavy metals contamination. Our results also give support to the hypothesis that the PSR estuary can act as a trap for these elements.

  6. Argilas bentoníticas de Cubati, Paraíba, Brasil: Caracterização física-mineralógica Bentonite clay from Cubati, Paraíba, Brazil: Physical and mineralogical characterization

    Directory of Open Access Journals (Sweden)

    R. R. Menezes

    2009-06-01

    Full Text Available O Estado da Paraíba possui jazidas de bentonitas utilizadas comercialmente em uma vasta gama de setores tecnológicos. No entanto, esses jazimentos estão se exaurindo após dezenas de anos de exploração. Assim, este trabalho tem por objetivo a caracterização físico-mineralógica de bentonitas recentemente descobertas no município de Cubati, PB. As amostras estudadas foram secas a 60 ºC e caracterizadas por meio de fluorescência de raios X, picnometria de He, determinação da distribuição de tamanho de partículas, difração de raios X, análise térmica diferencial e gravimétrica e microscopia eletrônica de varredura. Os resultados evidenciaram que as amostras são bentonitas policatiônicas, apresentando teores de MgO, CaO e K2O semelhantes aos de outras bentonitas sul-americanas e que são constituídas por argilomineral esmectítico e por quartzo e caulinita. As amostras apresentaram frações de partículas abaixo a 2 μm variando entre 31 e 41%, estando, no entanto, em elevado estado de aglomeração.The bentonites of the State of Paraíba, Brazil, are commercially uses in numerous technological sectors. However, these bentonite deposits are becoming exhausted due to several years of exploitation. Thus, the aim of this work was to characterize bentonite clays recently discovered in the Cubaty town, Paraíba. The samples were dried at 60ºC and characterized through X-ray fluorescence, He picnometry, determination of the particle size distribution, X-ray diffraction, thermal differential and gravimetric analyzes and scanning electronic microscopy. The results showed that the samples are polycationic bentonite clays containing amounts of MgO, CaO and K2O similar to those of other South American bentonites and are composed of smectite, kaolinite and quartz. The samples had particle-accumulated fractions under 2 μm ranging from 31 to 41%, however, the particles were in a very agglomerated state.

  7. The gemstone deposits of Brazil: occurrences, production and economic impact

    OpenAIRE

    de Brito Barreto, Sandra; Bretas Bittar, Sheila Maria

    2010-01-01

    This article gathers together data on the occurrence, production and economic importance of gem deposits in Brazil, including specific information on the major deposits. Of the 100 or so different types of gemstones found in the country, the most important in terms of production and/or originality are tourmalines, topaz, opals, varieties of quartz (agate, amethyst and citrine) and emeralds. Brazil is also one of the only producers in the world of imperial topaz and Paraíba tourmaline. The cou...

  8. Soil loss prediction in Guaraíra river experimental basin, Paraíba, Brazil based on two erosion simulation models

    Directory of Open Access Journals (Sweden)

    Jorge Flávio Cazé B. da Costa Silva

    2007-12-01

    Full Text Available In this study, two hydrological models to estimate soil losses and sediment yield due to sheet and channel erosion, at the basin outlet, are applied to Guaraíra River Experimental Basin, located in Paraíba State, northeastern Brazil. The soil erosion models are (a the classical Universal Soil Loss Equation (USLE, which is used to simulate annual and monthly soil losses; and (b Kineros model, which is used to simulate the sediment yield within the basin. Kineros model is a physically-based distributed model that uses a cascade of planes and channels to represent the basin and to describe the processes of interception, infiltration, surface runoff and erosion within the basin. The USLE is computed using land use, soil erodibility, topographic digital maps, as well as observed rainfall data. It was found that Guaraíra river experimental basin has a low potential for soil losses; however, specific areas which are susceptible to the erosion process in the basin could be detected by the modeling techniques coupled to a GIS (Geographic Information System.

  9. Gastrintestinal helminths Of Cerdocyon thous (Linnaeus, 1766 -Smith, 1839 from the caatinga area of the Paraíba State, Brazil

    Directory of Open Access Journals (Sweden)

    Roberto César Lima

    2013-12-01

    Full Text Available The crab eating fox, Cerdocyon thous (Linnaeus, 1766 – Smith, 1839, is a medium sized canid which is found in almost every region of Brazil. It is the only registered native canid specie to be found in the semi-arid Northeastern region of the country. This study had as its objectives: the identification of the helminth fauna common to Cerdocyon thous found in the Caatinga of the state of Paraíba; and the determination of the ecological indications of helminthic infection, hoping to make a favourable addition to the understanding of this little known biome. In this study, 58 animals that were found as ‘roadkill’ on the highways in the municipality of Patos were used. The gastrointestinal helminths from these animals were colected. All the animals in this study were infected with helminths. 16 species of helminths were identified, two being trematodes, one being a cestode, one being an acanthocephalus, and the remaining twelve being nematodes. In this study a new specie, named Pterygodermatites pluripectinata n. sp. Was discovered and its host and location described.

  10. Mass spectrometric determination of stability of gaseous BaMoO2, Ba2MoO4, Ba2MoO5, Ba2Mo2O8 molecules

    International Nuclear Information System (INIS)

    Kudin, L.S.; Balduchchi, Dzh.; Dzhil'i, G.; Gvido, M.

    1982-01-01

    During the mass spectrometric investigation of BaCrO 4 evaporation Cr + , Ba + , BaO + main ions are recorded as well as BaMoO 4 + , BaMoO 3 + , BaMoO 2 + , BaMoO + , BaMoO 4 + , Ba 2 MoO 5 + , BaMo 2 O 8 + ions - the products of ionization of three-component (Ba, Mo, M) molecules, forming as a result of substance chemical interaction with the material of an effusion cell (Mo). Heats of formation of BaMoO 2 , Ba 2 MoO 4 , Ba 2 MoO 5 and Ba 2 Mo 2 O 8 molecules which constituted - 577+-70, -1343+-115, -1464+-70, -2393+-90 k J/mol respectively are determined on the base of the analysis of curves of ionisation efficiency and of reaction heats Ba 2 MoO 5 =BaO+BaMoO 4 , ΔH 0 0 =322+-60 kJ/mol Ba 2 Mo 2 O 8 =2BaMoO 4 , ΔH 0 0 =351+-80 kJ/mol calculated with the use of third low of thermodynamics [ru

  11. Converting the Caetité Mill Process to Enhance Uranium Recovery and Expand Production

    Energy Technology Data Exchange (ETDEWEB)

    Gomiero, L. A.; Scassiotti Filho, W.; Veras, A., E-mail: gomiero@inb.gov.br [Indústrias Nucleares do Brasil S/A — INB, Caetité, BA (Brazil); Cunha, J. W. [Instituto de Engenharia Nuclear-IEN/CNEN, Rio de Janeiro, RJ (Brazil); Morais, C. A. [Centro do Desenvolvimento da Tec. Nuclear-CDTN/CNEN, Belo Horizonte, MG (Brazil)

    2014-05-15

    The Caetité uranium mill was commissioned in 2000 to produce about 340 t U per year from an uranium ore averaging 0.29% U{sub 3}O{sub 8}. This production is sufficient to supply the two operating nuclear power plants in the country. As the Brazilian government has recently confirmed its plan to start building another ones from 2009, the uranium production will have to expand its capacity in the next two years. This paper describes the changes in the milling process that are being evaluated in order to not only increase the production but also the uranium recovery, to fulfil the increasing local demand. The heap leaching process will be changed to conventional tank agitated leaching of ground ore slurry in sulphuric acid medium. Batch and pilot plant essays have shown that the uranium recovery can increase from the 77% historical average to about 93%. As the use of sodium chloride as the stripping agent has presented detrimental effects in the extraction and stripping process, two alternatives are being evaluated for the uranium recovery from the PLS: (a) uranium peroxide precipitation at controlled pH from a PLS that was firstly neutralized and filtered. Batch essays have shown good results with a final calcined precipitate averaging 99% U{sub 3}O{sub 8}. Conversely the results obtained at the first pilot plant essay has shown that the precipitation conditions of the continuous process calls for further evaluation. The pilot plant is being improved and another essay will be carried out. (b) uranium extraction with a tertiary amine followed by stripping with concentrated sulphuric acid solution. Efforts are being made to recover the excess sulphuric acid from the pregnant stripping solution to enhance the economic viability of the process and to avoid the formation of a large quantity of gypsum in the pre-neutralization step before the uranium peroxide precipitation. (author)

  12. Influence of terrestrial radionuclides on environmental gamma exposure in a uranium deposit in Paraíba, Brazil.

    Science.gov (United States)

    Araújo Dos Santos Júnior, José; Dos Santos Amaral, Romilton; Simões Cezar Menezes, Rômulo; Reinaldo Estevez Álvarez, Juan; Marques do Nascimento Santos, Josineide; Herrero Fernández, Zahily; Dias Bezerra, Jairo; Antônio da Silva, Alberto; Francys Rodrigues Damascena, Kennedy; de Almeida Maciel Neto, José

    2017-07-01

    One of the main natural uranium deposits in Brazil is located in the municipality of Espinharas, in the State of Paraíba. This area may present high levels of natural radioactivity due to the presence of these radionuclides. Since this is a populated area, there is need for a radioecological dosimetry assessment to investigate the possible risks to the population. Based on this problem, the objective of this study was to estimate the environmental effective dose outdoors in inhabited areas influenced by the uranium deposit, using the specific activities of equivalent uranium, equivalent thorium and 40 K and conversion factors. The environmental assessment was carried using gamma spectroscopy in sixty-two points within the municipality, with a high-resolution gamma spectrometer with HPGe semiconductor detector and Be window. The results obtained ranged from 0.01 to 19.11 mSv y -1 , with an average of 2.64 mSv y -1 . These levels are, on average, 23 times higher than UNSCEAR reference levels and up to 273 times the reference value of the earth's crust for primordial radionuclides. Therefore, given the high radioactivity levels found, we conclude that there is need for further investigation to evaluate the levels of radioactivity in indoor environments, which will reflect more closely the risks of the local population. Copyright © 2017 Elsevier Inc. All rights reserved.

  13. Immunological responses of the mangrove oysters Crassostrea gasar naturally infected by Perkinsus sp. in the Mamanguape Estuary, Paraíba state (Northeastern, Brazil).

    Science.gov (United States)

    Queiroga, Fernando Ramos; Marques-Santos, Luis Fernando; Hégaret, Hélène; Soudant, Philippe; Farias, Natanael Dantas; Schlindwein, Aline Daiane; Mirella da Silva, Patricia

    2013-08-01

    Perkinsus genus includes protozoan parasites of marine mollusks, especially bivalves. In the last four years, this parasite has been detected in mangrove oysters Crassostrea rhizophorae and Crassostrea gasar from the Northeastern region of Brazil. Hemocytes are the key cells of the oyster immune system, being responsible for a variety of cellular and humoral reactions, such as phagocytosis, encapsulation and the release of several effector molecules that control the invasion and proliferation of microorganisms. In Brazil, there is little information on perkinsosis and none on the immune responses of native oysters' species against Perkinsus spp. The objective of this study was to determine the effects of natural infection by Perkinsus sp. on the immunological parameters of mangrove oysters C. gasar cultured in the Mamanguape River Estuary (Paraíba, Brazil). Adults oysters (N = 40/month) were sampled in December 2011, March, May, August and October 2012. Gills were removed and used to determine the presence and intensity of the Perkinsus sp. infection, according to a scale of four levels (1-4), using the Ray's fluid thioglycollate medium assay. Immunological parameters were measured in hemolymph samples by flow cytometry, including: total hemocyte count (THC), differential hemocyte count (DHC), cell mortality, phagocytic capacity, and production of Reactive Oxygen Species (ROS). The plasma was used to determine the hemagglutination activity. The results showed the occurrence of Perkinsus sp. with the highest mean prevalence (93.3%) seen so far in oyster populations in Brazil. Despite that, no oyster mortality was associated. In contrast, we observed an increase in hemocyte mortality and a suppression of two of the main defense mechanisms, phagocytosis and ROS production in infected oysters. The increase in the percentage of blast-like cells on the hemolymph, and the increase in THC in oysters heavily infected (at the maximum intensity, 4) suggest an induction of

  14. Physical and catalytic characterization of smectites from Boa-Vista, Paraíba, Brazil Caracterização física e catalítica de esmectitas de Boa Vista, Paraíba, Brasil

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    M. G. F. Rodrigues

    2003-09-01

    Full Text Available The original crystalline structure of clay minerals can be altered in a controlled way, through acid or thermal treatments, resulting then in suitable products to be used as catalysts. This paper aims to characterize the red smectite clays of Boa-Vista, Paraíba (Brazil in their natural form, and after chemical, thermal and acid treatments by X-ray fluorescence, differential thermal analysis, dynamic X-ray diffraction, classic X-ray diffraction analysis, scanning electron microscopy, nitrogen adsorption and model reaction. The results show that acid treatment partially altered the structure of the montimorillonite. An important increase in the surface area of the solid obtained was observed. The obtained reaction for the treated material showed that the clay was more acid than the natural one, yielding a better catalytic activity.A estrutura cristalina original dos argilominerais pode ser alterada de um modo controlado através de tratamentos ácidos ou tratamentos químicos, resultando em produtos satisfatórios para serem usados como catalisadores. O objetivo deste trabalho é caracterizar a argila esmectítica vermelha de Boa-Vista, Paraíba (Brasil na sua forma natural e após tratamentos químicos e térmicos. Os métodos usados foram fluorescência de raios X, análise térmica diferencial, difração de raios X, microscopia eletrônica de varredura, adsorção física de nitrogênio e reação modelo. Os resultados mostram que o tratamento ácido alterou parcialmente a estrutura da montmorilonita. Foi observado um importante aumento na área específica do sólido obtido. A reação obtida para o material tratado mostrou que a argila foi mais ácida que a natural conduzindo a uma melhor atividade catalítica.

  15. Radionuclides in waters and soil near the Lagoa Real uranium mine

    International Nuclear Information System (INIS)

    Souza, Susana Oliveira de; Freire, Fabinara Dantas; Dias, Dario M.; Veiga, Artur Jose Pires

    2015-01-01

    Uranium mining generates fuel for the nuclear power plants and it is the main source of income for the region of Caetite-BA. However, Non-Governmental Organizations claim that mining pollutes the environment and jeopardizes human health and safety. Besides uranium, the ground contains significant concentrations of thorium and of all radionuclides of its family, such as radium isotopes. In this framework, we carried out an independent study analyzing the concentration of the radionuclides activities 226, 228 Ra and 234,238 U in water samples and radionuclides 226 Ra, 232 Th and 40 K in soil samples using different techniques of nuclear spectrometry. The selection criteria for the collection points were their proximity to the uranium processing plant and to affluent rivers. The soil samples presented very low concentration of activity for radionuclides investigated, compared to the limits established of the exclusion, exemption and impartiality for radiation protection requirement given by the Regulator Position established by CNEN. The amount of radioisotopes appears consistent with a natural origin, thus it is not possible to state that the mining process in Caetite increases pollution or radiation exposure in a significant way. (author)

  16. Radionuclides in waters and soil near the Lagoa Real uranium mine

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Susana Oliveira de; Freire, Fabinara Dantas, E-mail: sosouza@ufs.br [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Departamento de Fisica; Kozlowska, Beata; Walencik-Lata, Agata, E-mail: beata.kozlowska@us.edu.pl [University of Silesia, Institute of Physics, Katowice (Poland); Dias, Dario M., E-mail: engenheirodario@gmail.com [Secretaria Municipal de Meio Ambiente e Turismo, Andarai, BA (Brazil); Veiga, Artur Jose Pires, E-mail: tk1@ibest.com [Universidade Estadual do Sudoeste da Bahia (UESB), Itapetinga, BA (Brazil). Departamento de Ciencias Exatas e Tecnologicas

    2015-07-01

    Uranium mining generates fuel for the nuclear power plants and it is the main source of income for the region of Caetite-BA. However, Non-Governmental Organizations claim that mining pollutes the environment and jeopardizes human health and safety. Besides uranium, the ground contains significant concentrations of thorium and of all radionuclides of its family, such as radium isotopes. In this framework, we carried out an independent study analyzing the concentration of the radionuclides activities {sup 226,} {sup 228}Ra and {sup 234,238}U in water samples and radionuclides {sup 226}Ra, {sup 232}Th and {sup 40}K in soil samples using different techniques of nuclear spectrometry. The selection criteria for the collection points were their proximity to the uranium processing plant and to affluent rivers. The soil samples presented very low concentration of activity for radionuclides investigated, compared to the limits established of the exclusion, exemption and impartiality for radiation protection requirement given by the Regulator Position established by CNEN. The amount of radioisotopes appears consistent with a natural origin, thus it is not possible to state that the mining process in Caetite increases pollution or radiation exposure in a significant way. (author)

  17. Radon detection in soils by solid state nuclear track detectors

    International Nuclear Information System (INIS)

    Moraes, M.A.P.V. de; Khouri, M.T.F.C.

    1986-01-01

    The solid state nuclear track detectors technique was developed to be used in radon detection, by alpha particles tracks, and its application in uranium prospecting on the ground. The sensitive films to alpha particles used are the cellulose nitrate films LR 115 and CA 8015. Several simulations experiments and field measurements were carried out to verify the method possibilities. Maps of some anomalies in Caetite City (Bahia, Brazil) were made with the densities of tracks obtained. The results were compared with scintillation counter measurements. (Author) [pt

  18. O papel do folclore na motivação para atividades físicas de idosas The role of folklore in the motivation for physical activity of elderly

    OpenAIRE

    Berta Leni Costa Cardoso; Luis Otávio Teles Assumpção

    2011-01-01

    Existem muitos relatos sobre os benefícios biológicos da atividade física em idosos. Porém, o número de praticantes ainda não é satisfatório. Esse ponto controverso foi usado no presente artigo. Pesquisou-se sobre o uso do folclore local como um mecanismo educacional e motivacional útil no aumento da prática de atividades físicas para idosas. Foram entrevistadas idosas do Clube da Amizade em Caetité - BA, que foram motivadas e estimuladas pela dança. Este artigo também usou as reflexões de Pa...

  19. Paleoenvironmental evolution based on benthic foraminifera biofacies of the Paraíba do Sul Deltaic Complex, eastern Brazil

    Science.gov (United States)

    Gasparini, Sarah Pereira; Vilela, Claudia Gutterres

    2017-12-01

    The paleoecology and distribution of benthic foraminiferal assemblages were analyzed in the core 2-MU-1-RJ well, drilled in the Paraíba do Sul Deltaic Complex, Rio de Janeiro (Brazil). An abundant assemblage was found in the upper portion of the well core, inferred to be pleistocenic deposits. The coastal dynamic was recognized from five biofacies based on clusters, the Planktonic/Benthic (P/B) ratios and indicator species distribution in the core. Several biofacies were identified along the core depending on the species dominance. From the bottom to the top of the core, the biofacies succession represents the environmental changes in the coastal area associated to sea-level oscillations. The biofacies ABP dominated by Ammonia parkinsoniana and Bolivina spp. and Pararotalia cananeiaensis represents an inner shelf environment; biofacies QP dominated by shelf miliolids species; biofacies PGH, dominated by P. cananeiaensis, Gavelinopsis praegeri, and Hanzawaia nitidula, represents the estuary complex with middle or outer shelf influence; biofacies QL represents hypersaline waters dominated by lagoonal miliolids; and biofacies HP characterized by Haynesina germanica and P. cananeiaensis is associated with paralic environments. Marine ingressions are recorded and those biofacies show the pleistocenic coastal hydrodinamic in the deltaic complex. The foraminiferal biofacies contribute with detailed information to sedimentary facies previously characterized in the study area by the reconstruction of paleoenvironment succession.

  20. Spatial distribution of scorpions according to the socioeconomic conditions in Campina Grande,State of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Thassiany Sarmento Oliveira de Almeida

    Full Text Available Abstract: INTRODUCTION: Due to its frequency and morbidity, such as that caused by scorpions have achieved public health importance in certain regions of the world. The present exploratory ecological study aimed to characterize the epidemiological profile and spatial distribution of scorpion stings in Campina Grande, State of Paraíba in Northeastern Brazil. METHODS: Geographical information system techniques were used to record the scorpion stings, and Google Earth software, Track Maker, and ArcGIS 10 Esri were used as geocoding databases. The Moran test was used to evaluate spatial correlation, and the Pearson chi-square test was used to analyze associations between scorpion stings and socioeconomic variables. RESULTS: The study evaluated 1,466 scorpion stings. Envenomations were more frequent among women (n = 908, 61.9%, and most patients were aged 13-28 years (n = 428, 29.2%. The Southern region of the city had the largest number of registered cases (n = 548, 37.4%, followed by the Western region (n = 510, 34.8%. CONCLUSIONS: Spatial analysis of scorpionism revealed an irregular occurrence in Campina Grande. Further, no association was observed between the socioeconomic factors analyzed and the geographic location of the scorpion envenomations. Detection of spatial areas with an increased risk of scorpionism can help prioritize adoption of preventive measures in these regions to reduce the associated incidence and morbidity.

  1. Palynological and sedimentary analysis of the Igarapé Ipiranga and Querru 1 outcrops of the Itapecuru Formation (Lower Cretaceous, Parnaíba Basin), Brazil

    Science.gov (United States)

    Ferreira, Neila N.; Ferreira, Elizabete P.; Ramos, Renato R. C.; Carvalho, Ismar S.

    2016-03-01

    The siliciclastic sediments of the Itapecuru Formation occur in a large area of the Parnaíba Basin and its deposits crop out along the Itapecuru River, in Maranhão State, northern Brazil. The palynological analysis of the Igarapé Ipiranga and Querru 1 outcrops strata yields a rich and diversified data. The presence of index-palynofloras in assemblages allows the identification of the Complicatisaccus cearensis Zone, of Late Aptian-Early Albian age. Terrestrial palynomorphs are abundant in the assemblages, being represented by bryophytes and pteridophytes, especially perisporate trilete spores (Crybelosporites and Perotrilites), and gymnosperms and angiosperms (Afropollis and Elaterosporites). The composition of palynological assemblages suggests the presence of moist soils for both outcrops. Acritarchs were recovered in the Querru 1 outcrop, which suggest a marine setting supporting a tidal flat environment indicated by facies associations. Furthermore, reworked Paleozoic palynomorphs were observed in the Querru 1 outcrop. The microflora from Igarapé Ipiranga outcrop suggests terrestrial environment corroborating with floodplain environment indicated by facies association.

  2. Isolation of rabies virus from the parotid salivary glands of foxes (Pseudalopex vetulus from Paraíba State, Northeastern Brazil Isolamento de vírus rábico de glândulas salivares parótidas de raposas (Pseudalopex vetulus do Estado da Paraíba, Nordeste do Brasil

    Directory of Open Access Journals (Sweden)

    Maria Luana Cristiny Rodrigues Silva

    2009-09-01

    Full Text Available To determine the presence of rabies virus in the parotid salivary glands, 12 road-killed rabies-positive hoary foxes (Pseudoalopex vetulus were tested by using the fluorescent antibody test (FAT and mouse inoculation test (MIT. All 12 parotid salivary glands were positive for both tests, although in some cases several passages were required. The findings of this study support the importance of the hoary fox as rabies reservoir in the semi-arid region of Paraíba State, Northeastern Brazil.Para determinar a presença de vírus rábico em glândulas salivares parótidas, 12 raposas (Pseudalopex vetulus atropeladas em rodovias e positivas para raiva foram testadas pelo teste de imunofluorescência direta (IFD e teste de inoculação em camundongos (IC. Todas as 12 glândulas salivares parótidas foram positivas em ambos os testes, embora, em alguns casos, várias passagens terem sido necessárias. Os achados do presente trabalho reforçam a importância das raposas como reservatórios de raiva no semi-árido do Estado da Paraíba, Nordeste do Brasil.

  3. Refinement of crystal structures of CaHCl, SrHCl, BaHCl, BaHBr, and BaHI

    International Nuclear Information System (INIS)

    Beck, H.P.; Limmer, A.

    1983-01-01

    The structures of CaHCl, SrHCl, BaHBr, BaHCl, and BaHI have been refined using single crystal data. The comparison of the parameters with the corresponding data of isotypic fluorohalide compounds gives a valuable insight into the bonding interactions in this structure type. (author)

  4. Refinement of crystal structures of CaHCl, SrHCl, BaHCl, BaHBr, and BaHI

    Energy Technology Data Exchange (ETDEWEB)

    Beck, H.P.; Limmer, A. (Erlangen-Nuernberg Univ., Erlangen (Germany, F.R.). Inst. fuer Anorganische Chemie)

    1983-07-01

    The structures of CaHCl, SrHCl, BaHBr, BaHCl, and BaHI have been refined using single crystal data. The comparison of the parameters with the corresponding data of isotypic fluorohalide compounds gives a valuable insight into the bonding interactions in this structure type.

  5. Estudos bacteriológicos e sorológicos de um surto de peste no Estado da Paraíba, Brasil Bacteriological and serological studies of a plague outbreak in the Paraíba state, Brazil

    Directory of Open Access Journals (Sweden)

    Alzira Maria Paiva Almeida

    1989-06-01

    Full Text Available Foram realizados estudos bacteriológicos e/ou sorológicos para diagnóstico da infecção pestosa, em material obtido de 452 pacientes (48 positivos, 1.938 roedores e outros pequenos mamíferos (75 positivos, 4.756 cães (141 positivos e 3.047 gatos (57 positivos, oriundos de 41 municípios localizados em toda a extensão da área paraibana do Planalto da Borborema. A infecção foi encontrada em 21 municípios. Foram isoladas 20 cepas de Yersinia pestis de amostras coletadas de três pacientes e 17 roedores. Estas cepas apresentam características bioquímicas, fatores de virulência, sensibilidade aos antibióticos e poder patogênico experimental semelhantes ao de cepas isoladas anteriormente. Pelos estudos realizados não foram observados, no surto de peste que eclodiu em setembro de 1986 na Paraíba, fatores diferentes dos observados nos outros focos do nordeste do Brasil.During a plague outbreak in the Borborema Plateu focus (Paraíba, bacteriological and serological studies were carryed out in material from 452 patients (48 positives, 1,938 rodents and other small mammals (75 positives, 4,756 dogs (141 positives and 2,047 cats (57 positives obtained from 41 counties (out of which, 21 produced positive samples. Twenty Yersinia pestis strains isolated from material from 3 patients ans 17 rodents, displayed biochemical reactions, virulence factors, antibiotic susceptibility and animal experimental pathogenicity similar to those observed in strains previously isolated. According to our findings this recent plague outbreak did not exhibite different factors from those observed during prior outbreaks in other plague foci in the northeast of Brazil.

  6. Inorganic As speciation and bioavailability in estuarine sediments of Todos os Santos Bay, BA, Brazil

    International Nuclear Information System (INIS)

    Hatje, V.; Macedo, S.M.; Jesus, R.M. de; Cotrim, G.; Garcia, K.S.; Queiroz, A.F. de; Ferreira, S.L.C.

    2010-01-01

    Research highlights: → Total concentration of As at several stations along Todos os Santos Bay, was above TEL value. → At Subae and Paraguacu systems, As (V) was the dominant species, which is less toxic and less mobile than As (III). → Arsenic concentrations at Jaguaripe estuary were higher than in other estuaries and As (III) was the dominant species. → Relationship between As, Fe, Mn and sand indicated that As enrichment at Jaguaripe River is natural. → As concentrations in sediments and biota suggest that As is bioavailable and it is accumulating in marine organisms, which may impose human risks. → Slurry sampling showed to be a easy, accurate procedure to be used for As determination in estuarine samples. - Abstract: The spatial distribution of As (total As, As (III) and As (V)) in estuarine sediments from the main tributaries of Todos os Santos Bay, BA, Brazil, was evaluated under high and low flow conditions. The concentrations of As were determined using a slurry sampling procedure with hydride generation atomic absorption spectrometry (HG-AAS). The highest concentrations were observed at estuary mouths, and exceeded conservative lower threshold value (Threshold Effects Level; TEL). Due to the oxic conditions and abundance of Mn and Fe (oxyhydr)oxides in the sediments, most inorganic arsenic in the Subae and Paraguacu estuaries was present as As (V). Nevertheless, the concentration of As (III) at several locations along the Jaguaripe River were also above the TEL value, suggesting that As may be toxic to biota. In the Subae estuary, antropogenic activities are the main source of As. At the Jaguaripe and at Paraguacu estuaries, nevertheless, natural sources of As need to be considered to explain the distribution patterns.

  7. Investigação de Campylobacter fetus e Tritrichomonas foetus na mucosa prepucial de touros da região do Médio Paraíba, RJ Campylobacter fetus and Tritrichomonas foetus investigation in prepucial mucous of bulls from Médio Paraíba/RJ region, Brazil

    Directory of Open Access Journals (Sweden)

    Flávio Soares da Rocha

    2009-08-01

    Full Text Available Trinta e nove touros provenientes de propriedades de pecuária leiteira (n=9 e de pecuária de corte (n=30, situadas na região do Médio Paraíba, Rio de Janeiro (RJ, foram investigados para a presença de Campylobacter fetus e Tritrichomonas foetus. Para a pesquisa de Campylobacter, amostras de esmegma foram coletadas e submetidas à técnica de cultivo e isolamento e amostras de lavado prepucial ao teste de Imunofluorescência Direta (IFD. Para a pesquisa de Tritrichomonas, foi utilizada a técnica de exame direto a partir de lavado prepucial. Foi observada a presença de C. fetus em 14 amostras (35,9 %, por meio da IFD, e o isolamento de C. fetus, subespécie venerealis, foi obtido a partir de quatro amostras (10,3%. T. foetus não foi identificado nas amostras investigadas. A alta freqüência de C. fetus observada nos animais investigados sugere a presença da campilobacteriose na região do Médio Paraíba, em rebanhos com problemas reprodutivos.Thirty nine breeding bulls from dairy farms (n=9 and beef farms (n=30 located in Médio Paraíba region at Rio de Janeiro - Brazil state were investigated for the presence of Campylobacter fetus and Tritrichomonas foetus. For Campylobacter investigation, smegma samples were examined by culture and prepucial washings were examined by direct immunofluorescence technique (DIF. The prepucial washings were also examined for Tritrichomonas foetus presence by direct examination. C. fetus was identified in 14 samples (35.9 % by DIF technique and C. fetus subspecies venerealis was isolated from four samples (10.3%. T. foetus was not detected in bull samples. The high frequency of C. fetus observed in bull samples suggests the occurrence of Campylobacteriosis among herds which have reproductive problems at the Médio Paraíba region.

  8. REPRODUCTIVE CYCLE OF Leporinus copelandii (Pisces: Anostomidae FEMALES FROM THE LOWER PARAÍBA DO SUL RIVER BASIN, RJ – BRAZIL

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    Ana Paula Ribeiro Costa Erthal

    2015-12-01

    Full Text Available The aim of this study were investigate the reproductive biology of the fish Leporinus copelandii, a specie at risk of extinction in the lower Paraíba do Sul River basin. During a period of 14 months, a total of 143 females of red-piau were captured, between Itaocara and Campos dos Goytacazes cities (RJ, Brazil. A histological study shows four stages of the oocyte development (I, II, III and IV and five stages of the reproductive cycle of females: rest (1, initial maturation (2A, intermediary (2B, advanced (2C and spawned (4 were identified. The pattern of L. copelandii oocyte development suggests development type synchronous in two groups, characterizing total spawning. Spawned females were captured in November, two months after the peak of frequency of competent females for reproduction. Histologically, a little occurrence of empty follicles was observed in spawned females. The medium diameter of the type IV oocyte of the spawned females (1475.1 ± 884.3mm was significantly larger (Tukey, P <0.001; VC = 41.73%; n = 259 than advanced maturation females (1202.6 ± 245.3mm, what allows suggesting that the study place probably doesn't represent the reproductive area of L. copelandii.

  9. Capture techniques' use of Caranguejo-uçá crabs (Ucides cordatus) in Paraíba state (northeastern Brazil) and its socio-environmental implications.

    Science.gov (United States)

    Nascimento, Douglas M; Ferreira, Emmanoela N; Bezerra, Dandara M M S Q; Rocha, Pollyana D; Alves, Rômulo R N; Mourão, José S

    2012-12-01

    The present study was undertaken in two traditional communities that are located on the margins of the estuary and mangrove complex of the Mamanguape River, Paraíba state (PB), Brazil. This work describes the crabs capture techniques tapamento and redinha, and identifies the negative socio-environmental impacts of redinha, using qualitative methods (open and semi-structured interviews, guided tours, direct observation and the administration of questionnaires). Results indicate that currently only two principle techniques are used to capture Ucides cordatus: redinha and tapamento. Tapamento has a low impact in relation to redinha. Redinha was pointed out by interviewees as a system that has social impact (social conflicts, breaking of traditions, substitution and extinction of techniques) and environmental impact (less selective captures and high productivity, mangrove pollution, death of crabs caught in traps, cutting of the roots of Rhizophora mangle, micro-habitat loss resulting from galleries destroyed and polluted). Knowledge of crab harvesting carried out using these two techniques and the possible social and environmental impacts caused by redinha, can lead to more effective planning and actions towards the conservation of the species.

  10. Phase equilibria in the BaUO3-BaZrO3-BaMoO3 system

    International Nuclear Information System (INIS)

    Kurosaki, Ken; Yamanaka, Shinsuke; Matsuda, Tetsushi; Uno, Masayoshi; Yamamoto, Kazuya; Namekawa, Takashi

    2002-01-01

    The phase equilibria in the pseudo-ternary BaUO 3 -BaZrO 3 -BaMoO 3 system were studied to understand the thermochemical properties of the perovskite type gray oxide phase in high burnup MOX fuel. Thermodynamic equilibrium calculation for the system was performed by using a Chem Sage program under the various oxygen potentials. Solid solutions existing in the system were treated by an ideal solution model. The present calculation results well agreed with the previous reported post irradiation examination results, showing that BaMoO 3 was scarcely included in the gray oxide phase. (author)

  11. Patterns and inferred processes associated with sea turtle strandings in Paraíba State, Northeast Brazil

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    C. Poli

    Full Text Available This study analysed sea turtle strandings on the coast of Paraíba State, Northeastern Brazil, from August 2009 to July 2010. A total of 124 strandings were recorded in this period: green turtle Chelonia mydas (n = 106, hawksbill Eretmochelys imbricata (n = 15, olive ridley Lepidochelys olivacea (n = 2 and loggerhead Caretta caretta (n = 1. Of all turtles for which the Curved Carapace Length (CCL was measured (n = 122, only 12 individuals (9.7% were adults. Twenty individuals had synthetic anthropogenic debris in the gastrointestinal tract. Other traces of human interactions were observed in 43 individuals, such as injuries caused by entanglement in fishing lines or nets, collisions with vessels, direct contact with oil spills and lesions caused by sharp or spiked objects. Moreover, in 28.5% of the stranded turtles, the presence of external tumors was noticed, suggestive of fibropapillomatosis and in 9.7%, shark bite marks were observed. Of the 107 individuals that were sexed, 76 were females and 31 were males. Most turtles (72.6% became stranded during the spring/summer (between October and March. We found evidence of human interactions (injuries in half of the strandings, but in most cases it was not possible to determine if such interactions were the cause of death. A logistic regression found a significant relationship between CCL, ingestion of debris and lesions caused by sharks or spiked objects. Systematic data collection from stranded sea turtles can provide useful biological information, such as seasonal and spatial patterns in their occurrence and mortality, age structure, sex ratio and diet, as well as possible mortality causes.

  12. Characterization of clay of Vitoria da Conquista - BA - Brazil

    International Nuclear Information System (INIS)

    Oliveira, O.M.; Zandonadi, A.R.; Martins, M.V. Surmani; Carrio, J.A.G.; Munhoz Junior, A.H.

    2011-01-01

    Kaolinitic clays are vastly used in ceramic industry. Kaolinitic clay that are not coloured after firing are very useful in the production of ceramics because of their aesthetic aspect after firing. In this work clay material from Vitoria da Conquista (South- West Bahia, Brazil) was characterized by several techniques. The differential Scanning Calorimetry (DSC) shows a kaolinite characteristic curve with an endothermic peak at 492 deg C, which corresponds to the kaolinite - metakaolinite transformation. The transformation of alpha to beta quartz characterized by a 573 deg C peak was also observed in DSC. The samples were also characterized by water absorption and x rays powder diffraction. The 1100 deg C burned samples were tested by flexural strength. (author)

  13. Syntheses, crystal structure, and electronic properties of the five ABaMQ{sub 4} compounds RbBaPS{sub 4}, CsBaPS{sub 4}, CsBaVS{sub 4}, RbBaVSe{sub 4}, and CsBaVSe{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Mesbah, Adel [Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113 (United States); ICSM, UMR 5257 CEA / CNRS / UM / ENSCM, Site de Marcoule-Bâtiment 426, BP 17171, 30207 Bagnols-sur-Cèze Cedex (France); Prakash, Jai [Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113 (United States); Rocca, Dario; Lebègue, Sébastien [Laboratoire de Cristallographie, Résonance Magnétique, et Modélisations CRM2 (UMR UHP-CNRS 7036), Faculté des Sciences et Techniques, Université de Lorraine, BP 70239, Boulevard des Aiguillettes, 54506 Vandoeuvre-lès-Nancy Cedex (France); Beard, Jessica C.; Lewis, Benjamin A. [Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113 (United States); Ibers, James A., E-mail: ibers@chem.northwestern.edu [Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113 (United States)

    2016-01-15

    Five new compounds belonging to the ABaMQ{sub 4} family were synthesized by solid-state chemistry at 1123 K. The compounds RbBaPS{sub 4}, CsBaPS{sub 4}, CsBaVS{sub 4}, RbBaVSe{sub 4}, and CsBaVSe{sub 4} are isostructural and have the TlEuPS{sub 4} structure type. They crystallize in space group D{sup 16}{sub 2h} – Pnma of the orthorhombic system. Their structure consists isolated MQ{sub 4} tetrahedra separated by A and Ba atoms to form a salt-like structure. Density Functional Theory (DFT) calculations of the electronic structures with the use of the HSE functional suggest that the compounds are semiconductors with calculated band gaps of 3.3 eV (RbBaPS{sub 4}), 3.4 eV (CsBaPS{sub 4}), 2.3 eV (CsBaVS{sub 4}), and 1.6 eV (RbBaVSe{sub 4}). - Graphical abstract: General view of the ABaMQ{sub 4} structure down the a axis. - Highlights: • Five new ABaMQ{sub 4} compounds were synthesized by solid-state chemistry at 1123 K. • RbBaPS{sub 4}, CsBaPS{sub 4}, CsBaVS{sub 4}, RbBaVSe{sub 4}, and CsBaVSe{sub 4} have the TlEuPS{sub 4} structure type. • The compounds are semiconductors with calculated band gaps ranging from 1.6 to 3.4 eV.

  14. Isolation and identification of Mycobacterium bovis in milk from cows in northeastern Brazil

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    Joelson Marcolino Ramos

    Full Text Available ABSTRACT: Milk samples from 16 cows that tested positive on the tuberculin test in the state of Paraíba, northeastern Brazil, were used for mycobacteria isolation and identification. Mycobacteria were isolated from five (31.25% of the 16 milk samples; three samples were classified as M. bovis, and two as belonging to the Mycobacterium genus. This is probably the first study of isolation and identification of M. bovis in milk from cows in Northeastern Brazil, which suggests that humans are at risk of contamination by ingestion.

  15. Geochemistry of the Serra das Melancias Pluton in the Serra da Aldeia Suite: a classic post-collisional high Ba-Sr granite in The Riacho do Pontal Fold Belt, NE Brazil

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    Marcela Paschoal Perpétuo

    Full Text Available ABSTRACT: The Serra da Aldeia Suite is composed by circular or oval-shaped plutons, intrusive in meta-sedimentary and meta-volcanosedimentary rocks in the Riacho do Pontal Fold Belt, NE Brazil. The Serra das Melancias Pluton, belonging to Serra da Aldeia Suite, is located southeastern of Piaui state, near Paulistana city. These plutons represent a major magmatic expression in this area and contain important information about the late magmatic/collisional geologic evolution of the Brasiliano Orogeny. Based on petrographic and geochemical data, three facies were defined in the Serra das Melancias Pluton: granites, syenites and quartz monzonites. The rocks display high-K and alkaline to shoshonitic affinities, are metaluminous and show ferrous character. They are enriched in Light Rare Earth Elements and Large Ion Lithophile Elements, with negative anomalies in Nb, Ta and Ti. Their high Ba, Sr, K/Rb, low Rb, relatively low U, Th, Nb to very low Heavy Rare Earth Elements and Y resemble those of typical high Ba-Sr granitoids. The geochemical data suggest the emplacement of Serra das Melancias Pluton in a transitional, late to post-orogenic setting in the Riacho do Pontal Fold Belt during the late Brasiliano-Pan African Orogeny.

  16. A comparative neutron activation analysis study of common generic manipulated and reference medicines commercialized in Brazil

    International Nuclear Information System (INIS)

    Leal, A.S.; Menezes, M.A.B.C.; Rodrigues, R.R.; Andonie, O.; Vermaercke, P.; Sneyers, L.

    2008-01-01

    In this work, a comparative study of neutron activation analysis (NAA) was performed by the nuclear institutes: CDTN/CNEN-Brazil, CCHEN-Chile and the SCK.CEN-Belgium aiming to investigate some generic, manipulated and reference medicines largely commercialized in Brazil. Some impurities such as: As, Ba, Br, Ce, Co, Cr, Eu, Fe, Hf, Sb, Sc, Sm, Ti and Zn were found, and the heterogeneity of the samples pointed out the lack of an efficient public system of quality control

  17. Magnitude, tendência temporal e fatores associados à anemia em crianças do Estado da Paraíba Magnitud, tendencia temporal y factores asociados a la anemia en niños del Estado de Paraíba Magnitude, time trends and factors associate with anemia in children in the state of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Sheila Sherezaide Rocha Gondim

    2012-08-01

    Full Text Available OBJETIVO: Estimar a prevalência da anemia em crianças, sua tendência temporal e identificar fatores associados. MÉTODOS: Estudo de corte transversal, de base populacional, envolvendo 1.108 crianças, com idade entre seis e 59 meses, de ambos os sexos, do Estado da Paraíba, em 2007. A hemoglobina foi analisada em sangue venoso com contador automático. Foram considerados para anemia valores OBJETIVO: Estimar la prevalencia de la anemia en niños, su tendencia temporal e identificar factores asociados. MÉTODOS: Estudio de corte transversal, de base poblacional, involucrando 1.108 niños, con edad entre 6 a 59 meses, de ambos sexos, del Estado de Paraíba, en 2007. La hemoglobina fue analizada en sangre venosa con contador automático. Se consideraron para anemia valores OBJECTIVE: To estimate the magnitude of the anemia, to analyze the time trends and investigate the factors associated with this disturbance in children in the state of Paraíba, Brazil. METHODS: A cross-sectional survey, of population-based, with 1108 children, aged 6 to 59 months, both sexes in the state of Paraíba. Hemoglobin (Hb in venous blood was analyzed with an automatic counter. The social-economic and demographic characteristics of children were obtained by questionnaire. Proportions were compared by Pearson's chi-squared test, and the association between hemoglobin concentrations and potential risk factors was tested by regression model Poisson. The time trend of anemia was assessed by the increase/decreased in the prevalence of anemia, using as comparison the prevalence observed in the years 1982, 1992 and 2007. RESULTS: The prevalence of anemia (Hb < 11.0 g/dl in the state of Paraíba was 36.5% (CI95% 33.7 to 39.3. It was observed that 1.3% (CI95% 0.7 to 1.8 were in severe form (Hb <7.0 g/dl, 11% (CI95% 9.4 to 13.5 in a moderate form and 87.6% (CI95% 79.1 to 91.2 in the mild form. There was an increase 88.5% in cases of anemia between the years 1982-1992 and

  18. Prevalence ratio of HTLV-1 in nursing mothers from the state of Paraiba, Northeastern Brazil.

    Science.gov (United States)

    Pimenta, Flávia C F; Kashima Haddad, Simone; de Medeiros Filho, João G; Costa, Maria José C; Diniz, Margareth F M; Fernandes, Melina P; de Araújo, Lenisio B; Pombo-de-Oliveira, Maria S

    2008-08-01

    The human T-cell lymphotropic virus type 1 (HTLV-1) was the first human retrovirus known as a direct causal agent of a malignant disease. The vertical route of HTLV transmission is the most frequent pathway of the virus contamination. This study was performed to determine the prevalence ratio of HTLV-1 infection among nursing women. From January 2004 to January 2005, blood samples from 1033 nursing mothers from Paraíba, Brazil were evaluated for HTLV antibodies by ELISA and HTLV-1 viral particles confirmed by polymerase chain reaction (PCR). HTLV antibodies were detected in 7 women. The overall seroprevalence ratio was 0.68% and HTLV-1 viral sequences were confirmed by PCR in 2 women. These preliminary data suggest that HTLV screening should be introduced as a mandatory test before breastfeeding and breast milk donation in Paraíba, Brazil. Additionally, counseling programs would help reduce the prevalence ratio of HTLV-1 infected individuals in this Brazilian region.

  19. A biogeochemical and isotopic view of Nitrogen and Carbon in rivers of the Alto Paraíba do Sul basin, São Paulo State, Brazil

    Science.gov (United States)

    Ravagnani, E. D. C.; Coletta, L. D.; Lins, S. R. M.; Antonio, J.; Mazzi, E. A.; Rossete, A. L. M.; Andrade, T. M. B.; Martinelli, L. A.

    2014-12-01

    The magnitude of potential flows of elements in tropical ecosystems is not well represented in the literature, even being very important. The Paraíba do Sul River drains the three more economically developed states in Brazil: São Paulo, Minas Gerais and Rio de Janeiro and its basin is considered extremely altered. Despite its economic and social importance (~ 5.3 mi inhabitants), we don't know much about carbon and nitrogen transport into its rivers and how these are affected by soil use changes. This work aimed to investigate these nutrients, using an isotopic and a biogeochemical approach, at some third order (Paraibuna, Paraitinga and Paraíba do Sul), second and first order rivers, all inserted at the Alto Paraíba do Sul Basin. In general, the low dissolved organic carbon, dissolved inorganic carbon, total dissolved nitrogen and inorganic N concentrations found in the first order rivers, showed the lower variation, despite changes in the soil use. Forested rivers presented higher DOC (3.3 mg.L-1) and TDN (14.2 mM) concentrations than the pasture rivers (2.6 mg.L-1 and 13.8 mM), while these presented higher DIC concentrations than those ones (90.2 mM and 71.2 mM). In third order rivers, the concentrations were also very low. Both carbon and nitrogen contents at the fine and coarse fractions of the suspended particulate material (SPM) were lower at Paraitinga and Paraiba do Sul Rivers. At the Paraibuna River, the fine fraction of SPM presented 25% of C concentration. The concentrations found at the coarse fraction were also higher at this river. The N concentrations were higher at the fine fraction and, consequently, this fraction presented higher C:N ratio. These observations allow us to say that the coarse fraction might be related to plant material, while the fine fraction is probably related to the soils. The δ13C in the SPM was lower in the Paraibuna River, probably due to the predominance of forest, while in the other ones pasture was the main soil use

  20. Performance of different methods for reference evapotranspiration estimation in Jaíba, Brazil

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    Gustavo H. da Silva

    Full Text Available ABSTRACT FAO Penman-Monteith (FO-PM is considered the standard method for the estimation of reference evapotranspiration (ET0 but requires various meteorological data, which are often not available. The objective of this work was to evaluate the performance of the FAO-PM method with limited meteorological data and other methods as alternatives to estimate ET0 in Jaíba-MG. The study used daily meteorological data from 2007 to 2016 of the National Institute of Meteorology’s station. Daily ET0 values were randomized, and 70% of these were used to determine the calibration parameters of the ET0 for the equations of each method under study. The remaining data were used to test the calibration against the standard method. Performance evaluation was based on Willmott’s index of agreement, confidence coefficient and root-mean-square error. When one meteorological variable was missing, either solar radiation, relative air humidity or wind speed, or in the simultaneous absence of wind speed and relative air humidity, the FAO-PM method showed the best performances and, therefore, was recommended for Jaíba. The FAO-PM method with two missing variables, one of them being solar radiation, showed intermediate performance. Methods that used only air temperature data are not recommended for the region.

  1. Aptidão física relacionada à saúde em escolares de Jequié, BA, Brasil Health-related physical fitness in students from Jequié, BA, Brazil

    Directory of Open Access Journals (Sweden)

    Valfredo Dórea

    2008-12-01

    Full Text Available O objetivo deste estudo foi analisar a aptidão física relacionada à saúde (AFRS em escolares de Jequié, BA, Brasil. Para tanto, a AFRS de 182 meninos e 160 meninas (sete a 12 anos, escolares da rede pública de ensino, foi avaliada mediante a aplicação dos testes motores corrida/caminhada de nove minutos (indicador de resistência cardiorrespiratória, abdominal modificado em um minuto (indicador de força e resistência abdominal, sentar-e-alcançar (indicador de flexibilidade. O somatório das espessuras das dobras cutâneas tricipital e subescapular foi utilizado como indicador de gordura corporal. Os resultados encontrados indicaram maior prevalência de meninos e meninas abaixo (19% e 49%, respectivamente do que acima (3% e 1%, respectivamente dos critérios estabelecidos pela AAHPERD (1988 para indicadores de gordura corporal. Por outro lado, somente 51% dos meninos e 58% das meninas no sentar-e-alcançar; 11% e 7%, respectivamente, no abdominal modificado em um minuto, e 15% e 14%, respectivamente, na corrida/caminhada de nove minutos alcançaram os critérios estabelecidos. Portanto, os resultados sugerem que programas efetivos de intervenção parecem necessários para a promoção de mudanças no estado nutricional e na atividade física habitual de escolares de Jequié.The aim of this study was to analyze the health-related physical fitness (HRPF in students from Jequié, BA, Brazil. Therefore, the HRPF of 182 boys and 160 girls aged 7-12 years, students from public schools, was assessed by the application of 9-minute-run/walk (indicator of cardiorespiratory capacity, modified in one minute abdominal (indicator of abdominal strength and endurance, sit-and-reach (indicator of flexibility motor tests. The sum of the triciptal and subscapular skinfolds thickness was used as indicator of body fat. The results found indicated higher prevalence of boys and girls below (19% and 49%, respectively than above (3% and 1%, respectively the

  2. Evolution of the Parnaíba Delta (NE Brazil) during the late Holocene

    Science.gov (United States)

    Szczygielski, Agata; Stattegger, Karl; Schwarzer, Klaus; da Silva, André Giskard Aquino; Vital, Helenice; Koenig, Juliane

    2015-04-01

    Sedimentary processes and the evolution of the wave- and tide-dominated, asymmetric Parnaíba Delta during the late Holocene were investigated based on geochemical and sedimentological analyses of sediment cores collected in 2010, as well as satellite images and historical maps. This is a rare case of pristine deltas essentially unaffected by human activities worldwide. The lowermost part of the main Parnaíba River distributary exhibits several low-sinuosity bends and several anastomosing bifurcation patterns in the east, whereas three NW-SE-oriented tidal channels drain a large mangrove area in the west. Dating of various materials in sediment cores from the tidal flats, tidal channels and supratidal marshes revealed that the oldest sediment (4,853 to 4,228 cal. years BP) is paleo-mangrove soil from the main river distributary. Present-day mangroves and marshes up to 200 years old exhibit high sedimentation rates reaching 3.4 cm/year. The asymmetry of the delta is explained not only by the wind- and wave-induced westward-directed longshore drift but also by neotectonic processes, as revealed by satellite images. Faulting and eastward tilting may have triggered delta lobe switching from west to east. This would explain the erosional character and unusual updrift orientation of the main river-mouth channel. Consistent with existing knowledge on mangrove ecosystems worldwide, sediment carbon and nitrogen signatures lie in the range of freshwater or marine dissolved organic carbon and C3 terrestrial plants. In the western tidal channels, the low Corg/Ntot ratios (16-21) of young mangrove soil (deposited in the last 16 years) reflect a stronger influence of marine plants compared to older mangroves (1,390-1,525 cal. years BP; ratios of 20-37). Thus, there would have been a greater influence of the Parnaíba River on tidal-channel sedimentology 1,400 to 1,500 years ago, entailing a natural connection between the present-day tidal channels and the river in ancient times

  3. Subnitride chemistry: A first-principles study of the NaBa3N, Na5Ba3N, and Na16Ba6N phases

    International Nuclear Information System (INIS)

    Oliva, Josep M.

    2005-01-01

    An ab initio study on the electronic structure of the subnitrides NaBa 3 N, Na 5 Ba 3 N, and Na 16 Ba 6 N is performed for the first time. The NaBa 3 N and Na 5 Ba 3 N phases consist of infinite 1 ∞ [NBa 6/2 ] strands composed of face-sharing NBa 6 octahedra surrounded by a 'sea' of sodium atoms. The Na 16 Ba 6 N phase consist of discrete [NBa 6 ] octahedra arranged in a body-cubic fashion, surrounded by a 'sea' of sodium atoms. Our calculations suggest that the title subnitrides are metals. Analysis of the electronic structure shows partial interaction of N(2s) with Ba(5p) electrons in the lower energy region for NaBa 3 N and Na 5 Ba 3 N. However, no dispersion is observed for the N(2s) and Ba(5p) bands in the cubic phase Na 16 Ba 6 N. The metallic band below the Fermi level shows a strong mixing of N(2p), Ba(6s), Ba(5d), Ba(6p), Na(3s) and Na(3p) orbitals. The metallic character in these nitrides stems from delocalized electrons corresponding to hybridized 5d l 6s m 6p n barium orbitals which interact with hybridized 3s n 3p m sodium orbitals. Analysis of the electron density and electronic structure in these nitrides shows two different regions: a metallic matrix corresponding to the sodium atoms and the regions around them and heteropolar bonding between nitrogen and barium within the infinite 1 ∞ [NBa 6/2 ] strands of the NaBa 3 N and Na 5 Ba 3 N phases, and within the isolated [NBa 6 ] octahedra of the Na 16 Ba 6 N phase. The nitrogen atoms inside the strands and octahedra are negatively charged, the anionic character of nitrogens being larger in the isolated octahedra of the cubic phase Na 16 Ba 6 N, due to the lack of electron delocalization along one direction as opposed to the other phases. The sodium and barium atoms appear to be slightly negatively and positively charged, the latter to a larger extent. From the computed Ba-N overlap populations as well as the analysis of the contour maps of differences between total density and superposition of

  4. Syntheses and crystal structures of BaAgTbS{sub 3}, BaCuGdTe{sub 3}, BaCuTbTe{sub 3}, BaAgTbTe{sub 3}, and CsAgUTe{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Prakash, Jai; Beard, Jessica C.; Ibers, James A. [Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113 (United States); Mesbah, Adel [Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113 (United States); ICSM-UMR 5257 CNRS/CEA/UM2/ENSCM, Bat 426, BP 17171, 30207 Bagnols/Ceze (France)

    2015-06-15

    Five new quaternary chalcogenides of the 1113 family, namely BaAgTbS{sub 3}, BaCuGdTe{sub 3}, BaCuTbTe{sub 3}, BaAgTbTe{sub 3}, and CsAgUTe{sub 3}, were synthesized by the reactions of the elements at 1173-1273 K. For CsAgUTe{sub 3} CsCl flux was used. Their crystal structures were determined by single-crystal X-ray diffraction studies. The sulfide BaAgTbS{sub 3} crystallizes in the BaAgErS{sub 3} structure type in the monoclinic space group C{sup 3},{sub 2h}-C2/m, whereas the tellurides BaCuGdTe{sub 3}, BaCuTbTe{sub 3}, BaAgTbTe{sub 3}, and CsAgUTe{sub 3} crystallize in the KCuZrS{sub 3} structure type in the orthorhombic space group D{sup 1},{sub 2}{sup 7},{sub h}-Cmcm. The BaAgTbS{sub 3} structure consists of edge-sharing [TbS{sub 6}{sup 9-}] octahedra and [AgS{sub 5}{sup 9-}] trigonal pyramids. The connectivity of these polyhedra creates channels that are occupied by Ba atoms. The telluride structure features {sup 2}{sub ∞}[MLnTe{sub 3}{sup 2-}] layers for BaCuGdTe{sub 3}, BaCuTbTe{sub 3}, BaAgTbTe{sub 3}, and {sup 2}{sub ∞}[AgUTe{sub 3}{sup 1-}] layers for CsAgUTe{sub 3}. These layers comprise [MTe{sub 4}] tetrahedra and [LnTe{sub 6}] or [UTe{sub 6}] octahedra. Ba or Cs atoms separate these layers. As there are no short Q..Q (Q = S or Te) interactions these compounds achieve charge balance as Ba{sup 2+}M{sup +}Ln{sup 3+}(Q{sup 2-}){sub 3} (Q = S and Te) and Cs{sup +}Ag{sup +}U{sup 4+}(Te{sup 2-}){sub 3}. (Copyright copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. Paleoenvironmental implications of early diagenetic siderites of the Paraíba do Sul Deltaic Complex, eastern Brazil

    Science.gov (United States)

    Rodrigues, Amanda Goulart; De Ros, Luiz Fernando; Neumann, Reiner; Borghi, Leonardo

    2015-06-01

    Abundant early diagenetic siderites occur as spherulites and rhombohedral microcrystalline and macrocrystalline crystals in the cores of the 2-MU-1-RJ well, drilled in the Paraíba do Sul Deltaic Complex, Rio de Janeiro (Brazil). The host sediments of the siderites are siliciclastic, hybrid, and carbonate deposits. Intense pedogenetic processes affected the siliciclastic sediments immediately after deposition, comprising clay illuviation, plants bioturbation, feldspar dissolution, and iron oxide/hydroxide precipitation. Siderite and pyrite are the main diagenetic constituents. The other diagenetic products are kaolinite, smectite, argillaceous and carbonate pseudomatrix, quartz overgrowths, diagenetic titanium minerals, jarosite, and iron oxides/hydroxides. Early diagenetic siderites were separated into four groups based on their elemental and stable isotopic composition, as well as on their paragenetic relationships with the other constituents and with the host sediments. Spherulitic to macrocrystalline siderites from group 1 are almost pure (average: 94.7 mol% FeCO3; 1.2 mol% MgCO3; 2.3 mol% CaCO3; 1.8 mol% MnCO3) and precipitated from meteoric porewaters in continental siliciclastic rocks under suboxic conditions (δ18Ovpdb values range in - 10.28 to - 5.57‰ and the δ13Cvpdb values in - 12.68 to - 4.33‰). Microcrystalline rhombohedral siderites from group 2 have zonation due to substantial Ca and Mg substitution (core average: 78.5 mol% FeCO3; 4.2 mol% MgCO3; 15.7 mol% CaCO3; 1.6 mol% MnCO3; edge average: 74.0 mol% FeCO3; 9.2 mol% MgCO3; 15.6 mol% CaCO3; 1.1 mol% MnCO3), and δ13Cvpdb and δ18Ovpdb values of + 0.17‰ and - 1.96‰, precipitated from marine porewaters in packstones/wackestones under methanogenic conditions. The group 3 is represented by irregular spherulitic siderites with moderate Ca and Mg substitutions (average: 80.2 mol% FeCO3; 7.9 mol% MgCO3; 11.3 mol% CaCO3; 0.6 mol% MnCO3), with δ18Ovpdb values ranging from - 5.96 to - 7.61‰ and

  6. Characterization and pedogenesis of mangrove soils from Ilhéus-BA, Brazil

    OpenAIRE

    Gomes,Felipe Haenel; Ker,João Carlos; Ferreira,Tiago Osório; Moreau,Ana Maria Souza dos Santos; Moreau,Maurício Santana

    2016-01-01

    ABSTRACT Despite its importance, studies of mangrove soils are scarce, especially from a pedological perspective. The objective of this work was to study the genesis of soils in a mangrove environment in northeastern Brazil (Ilhéus, Bahia) through a morphological, physical, chemical and mineralogical characterization. All soils presented a sandy texture, which is related to the parent material (Quaternary sand deposits). The tidal flooding and resulting hydromorphic conditions is responsible ...

  7. O papel do folclore na motivação para atividades físicas de idosas The role of folklore in the motivation for physical activity of elderly

    Directory of Open Access Journals (Sweden)

    Berta Leni Costa Cardoso

    2011-03-01

    Full Text Available Existem muitos relatos sobre os benefícios biológicos da atividade física em idosos. Porém, o número de praticantes ainda não é satisfatório. Esse ponto controverso foi usado no presente artigo. Pesquisou-se sobre o uso do folclore local como um mecanismo educacional e motivacional útil no aumento da prática de atividades físicas para idosas. Foram entrevistadas idosas do Clube da Amizade em Caetité - BA, que foram motivadas e estimuladas pela dança. Este artigo também usou as reflexões de Paulo Freire, que admite o uso da cultura e contexto de vida pessoal como o mais importante meio de motivação e de educação. Os resultados provaram que é positivo o uso deste citado processo motivacional em estimular idosas nas suas aulas de educação física. Elas relataram que se sentem muito motivadas durante as aulas de dança enquanto podem escutar músicas que as fazem lembrar de seu passado, cultura e valores morais.There are many reports about the biological benefits of the physical activity in older individuals. However the number of physically active elderly is still not satisfactory. This controversial point was used in the present article. It searches if the use of the local folklore as an educating and motivating mechanism was useful for increasing physical activity practices in older individuals. Individuals from "Clube da Amizade" in Caetité city, Bahia (Brazil were interviewed to assess how folkloric dance was used to motivate them in physical education classes. This article also uses the Paulo Freire reflections that admit the use of regional cultural aspects and the life context as the most import strategy to teach and motivate the participants. The results indicated that is positive to use this referred motivational process to stimulate old ladies in the physical education classes. The interviewed ladies reported that they feel very stimulate during dance classes while they listen to music that makes them to remember

  8. Herd-level prevalence and risk factors for bovine viral diarrhea virus infection in cattle in the State of Paraíba, Northeastern Brazil.

    Science.gov (United States)

    Fernandes, Leise Gomes; Nogueira, Adriana Hellmeister de Campos; De Stefano, Eliana; Pituco, Edviges Maristela; Ribeiro, Cláudia Pestana; Alves, Clebert José; Oliveira, Tainara Sombra; Clementino, Inácio José; de Azevedo, Sérgio Santos

    2016-01-01

    Serological surveys based on a planned sampling on bovine viral diarrhea virus (BVDV) infection in Brazilian cattle herds are scarce. A cross-sectional study was carried out to determine herd- and animal-level seroprevalences and to identify risk factors associated with herd-level seroprevalence for BVDV infection in the State of Paraíba, Northeastern Brazil, from September 2012 to January 2013. The state was divided into three sampling strata, and for each stratum, the prevalence of herds infected with BVDV and the prevalence of seropositive animals was estimated by a two-stage sampling survey. In total, 2443 animals were sampled from 478 herds. A virus-neutralization test was used for BVDV antibody detection. A herd was considered positive when at least one seropositive animal was detected. The herd- and animal-level prevalences in the State of Paraíba were 65.5% (95% confidence interval (CI) = 61.1-69.7%) and 39.1% (95% CI = 33.1-45.6%), respectively. The frequency of seropositive animals per herd ranged from 10 to 100% (median of 50%). The risk factors identified were as follows: more than six calves aged ≤12 months (odds ratio (OR) = 3.72; 95% CI = 2.08-6.66), animal purchasing (OR = 1.66; 95% CI = 1.08-2.55), pasture rental (OR = 2.15; 95% CI = 1.35-3.55), and presence of veterinary assistance (OR = 2.04; 95% CI = 1.10-3.79). Our findings suggest that the implementation of control and prevention measures among farmers, with the aim of preventing dissemination of the agent in the herds, is necessary. Special attention should be given to addressing the identified risk factors, such as sanitary control prior to animal purchasing and to discourage the pasture rental, as well as to encourage the vaccination in the herds.

  9. A família Rubiaceae na Reserva Biológica Guaribas, Paraíba, Brasil: subfamílias Antirheoideae, Cinchonoideae e Ixoroideae The family Rubiaceae in the Guaribas Biological Reserve, Paraíba State, Brazil: subfamilies Antirheoideae, Cinchonoideae and Ixoroideae

    Directory of Open Access Journals (Sweden)

    Maria do Socorro Pereira

    2004-06-01

    Full Text Available Este trabalho consiste no levantamento dos representantes das subfamílias Antirheoideae, Cinchonoideae e Ixoroideae na Reserva Biológica Guaribas, Paraíba, Brasil. Foram realizadas coletas intensivas no período de outubro/2000 a outubro/2001, as quais resultaram no reconhecimento de 12 espécies, 10 gêneros e cinco tribos, distribuídos nas três subfamílias. A subfamília melhor representada foi Antirheoideae, com cinco espécies, quatro gêneros e duas tribos. Os gêneros com maior número de espécies foram Guettarda L. (2 e Tocoyena Aubl. (2. Alibertia A. Rich. ex DC., Alseis Schott, Chiococca P. Browne, Chomelia Jacq., Coutarea Aubl., Posoqueria Aubl., Sabicea Aubl. e Salzmannia DC. apresentaram uma única espécie cada. São apresentadas chaves para identificação, descrições, comentários sobre morfologia e distribuição das espécies, e ilustrações dos táxons verificados.This paper is a survey of Rubiaceae subfamilies Antirheoideae, Cinchonoideae and Ixoroideae in the Guaribas Biological Reserve, Paraíba, Brazil. Intensive collections were made from October/2000 to October/2001. Twelve species, 10 genera and five tribes were recognized. The most diverse subfamily was Antirheoideae, with five species, four genera and two tribes. The genera with the most species were Guettarda L. (2 and Tocoyena Aubl. (2. Alibertia A. Rich. ex DC., Alseis Schott, Chiococca P. Browne, Chomelia Jacq., Coutarea Aubl., Posoqueria Aubl., Sabicea Aubl., and Salzmannia DC. were represented by only one species each. Keys, descriptions, comments on morphology and species distributions, as well as illustrations of the taxa are provided.

  10. Characterization and pedogenesis of mangrove soils from Ilhéus-BA, Brazil

    Directory of Open Access Journals (Sweden)

    Felipe Haenel Gomes

    2016-12-01

    Full Text Available ABSTRACT Despite its importance, studies of mangrove soils are scarce, especially from a pedological perspective. The objective of this work was to study the genesis of soils in a mangrove environment in northeastern Brazil (Ilhéus, Bahia through a morphological, physical, chemical and mineralogical characterization. All soils presented a sandy texture, which is related to the parent material (Quaternary sand deposits. The tidal flooding and resulting hydromorphic conditions is responsible for dominance of dark grey colors, and high organic matter contents (paludization process. As well as the high values of electrical conductivity (EC and dominance of Na+ in the saturation extract (salinization and solodization processes, respectively. Contrastingly, the M3 profile, with aninga (Montrichardia linifera vegetation, a non-exclusive mangrove plant, showed colors with high chromas due to a lesser influence of tidal flooding. The pH values and the SO4=/Cl- ratios indicated the presence of sulfidic material and, thus, the occurrence of the sulfidization process. The soil organic matter fractionation evidenced the humin as the fraction with the highest content, probably because of removal of most soluble fractions due to tidal action. Similar to mangrove soils from southeast Brazil, the XRD analysis identified kaolinite, mica and expandable 2:1 minerals in the clay fraction.

  11. Elevated concentrations of dissolved Ba, Fe and Mn in a mangrove subterranean estuary: Consequence of sea level rise?

    Science.gov (United States)

    Sanders, Christian J.; Santos, Isaac R.; Barcellos, Renato; Silva Filho, Emmanoel V.

    2012-07-01

    Groundwater underlying a mangrove habitat was studied to determine the geochemical nature of Ba, Fe and Mn as related to dissolved organic carbon (DOC), SO4 and salinity (Sepetiba Bay, Brazil). Wells were placed across geobotanic facies and sampled monthly for a year. We observed non-conservative behavior and elevated concentrations of dissolved metals relative to local end-members (i.e., fresh river water and seawater). Average Ba concentrations were near 2000 nM in an area with low salinity (˜5.3). Dissolved Fe (up to 654 μM) was two orders of magnitude greater in fresh groundwater than in the seaward sampling stations. Manganese concentrations were greatest (112 μM) in the high salinity (˜65) zone, being directly influenced by salinity. Groundwater Ba, Fe and Mn showed differing site specific concentrations, likely related to ion exchange processes and redox-controlled cycling along distinct mangrove facies. The results of this work show that metal concentrations are altered relative to conservative mixing between terrestrial and marine endmembers, illustrating the importance of mangrove subterranean estuaries as biogeochemical reactors. Roughly-estimated submarine groundwater discharge-derived dissolved Ba, Fe and Mn fluxes were at least one order of magnitude greater than river-derived fluxes into Sepetiba Bay.

  12. Uranium mineralization at Lagoa Real, BA, Brazil: the role of fluids in its genesis

    International Nuclear Information System (INIS)

    Prates, Sonia Pinto; Neves, Jose Marques Correia; Fuzikawa, Kazuo

    2009-01-01

    The Lagoa Real uranium province is situated in the central-south of Bahia state . Brazil and it is presently by far the most important and best known uranium occurrence in Brazil. Nowadays 34 anomalies are known in a 30 Km long and 5 km wide area. An open pit mine was open in Cachoeira Mine, in the north portion of the area, and it is the only uranium mine in operation in Brazil and even in South America as well. The uranium mineralization in the Lagoa Real uranium province occurs in metamorphic rocks named albitites, due to their albite content (over 70%). Uraninite is the main uranium mineral, followed by pechblende, uranophane, torbernite and other uranyl minerals. Uraninite occurs as tiny round and irregular crystals (20 a 30 μm) included or associated to mafic minerals, mainly pyroxene and garnet, and also to amphibole and biotite and sometimes to albite. Some secondary minerals such as, for instance, uranophane, torbernite and tyuyamunite are also found. The main albitites minerals from the Cachoeira mine (plagioclase, garnet, biotite, pyroxene, amphibole and titanite) were studied by means of Infrared Spectroscopy Techniques. Good results were obtained from small quantities of material (around 2 mg) and allowed the minerals identification, and also to know their composition (from the peak position) and to detect the presence of water molecules, which indicates an aqueous phase during the uranium formation, probably rich in Fluorine. (author)

  13. Parotocinclus seridoensis, a new hypoptopomatine catfish (Siluriformes: Loricariidae from the upper rio Piranhas-Açu basin, northeastern Brazil

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    Telton Pedro A. Ramos

    Full Text Available A new species of Parotocinclus is described from the upper rio Piranhas-Açu basin, northeastern Brazil. The new species differs from all its congeners, except P. bidentatus, P. muriaensis (both from rio Paraíba do Sul basin, southeastern Brazil, and P. spilurus (rio Jaguaribe basin, northeastern Brazil by presenting the adipose fin rudimentary or absent. The new species differs from P. bidentatus, P. muriaensis, and P. spilurus mainly by presenting the abdomen region extensively naked, with few reduced rounded dermal platelets between the pectoral girdle and the anus. Parotocinclus seridoensis is probably an endemic species of the semi-arid Caatinga, region where the genus presents high species richness.

  14. Geologic and Geotechnical contributions to the Lagoa da Rabicha and Cachoeira mines projects, Lagoa Real, State of Bahia, Brazil

    International Nuclear Information System (INIS)

    Tognon, A.A.; Costanzo Junior, J.; Ojima, L.M.; Oliveira Braga, T. de; Mueller, M.

    1984-01-01

    The procedures and systematics involved in obtaining basic geologic-geotechnical, geomechanical and hydrogeotechnical parameters to serve as an aid in the planning of mining activities for the Lagoa da Rabicha and Cachoeira deposists, located in the Lagoa Real uranium District, are presented and discussed. These deposits occur in the Caetite massif, composed mainly of Gneissic lithologies. The studies were performed in order to provide the essential elements for an initial Geologic-Geotechnical characterization of the massifs. (D.J.M.) [pt

  15. Water supply diagnosis in the municipality of Cajazeiras, Paraíba State, Brazil

    Directory of Open Access Journals (Sweden)

    José Adalberto da Silva Filho

    2016-04-01

    Full Text Available The water supply is a key factor for the development of the population in a region. The mapping areas that are not supplied with drinking water is an important mechanism, once the vulnerable locations are identified, which leads to establish policies and programs to mitigate the problem. Thus, this paper aims at examining areas that present vulnerability in access to water in the municipality of Cajazeiras, Paraíba State, Brazil. In order to carry this research out, data from the Brazilian Institute of Geography and Statistics were analyzed. The results indicate a disproportion in access to water between rural and urban areas, with the first being very vulnerable to contamination factors. It is necessary environmental education programs for sustainable water use, the development of technologies to ensure good quality water and the well being of the people, by the high risk of water-related diseases caused by the contamination that may occur in capture, transport and storage of water. Diagnóstico do abastecimento de água no município de Cajazeiras – PB, BrasilResumo: O abastecimento de água é um fator determinante para o desenvolvimento da população em uma região. O mapeamento de zonas que não são abastecidos com água potável é um mecanismo importante, uma vez que são identificadas as localidades que apresentam vulnerabilidade, sendo assim possível estabelecer políticas e programas que amenizem a problemática. Dessa forma, o presente trabalho tem por objetivo analisar as zonas que apresentam vulnerabilidade no acesso à água no município de Cajazeiras - PB, por meio de dados obtidos junto ao Instituto Brasileiro de Geografia e Estatística. Os resultados indicam uma desproporcionalidade no acesso à água entre as zonas rurais e urbanas, sendo a primeira muito vulnerável a fatores de contaminação. Dessa forma, faz-se necessário programas de educação ambiental para o uso sustentável da água, como também o

  16. X-ray photoelectron spectroscopy study of BaWO{sub 4} and Ba{sub 2}CaWO{sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Capece, Angela M., E-mail: acapece@pppl.gov [California Institute of Technology, Pasadena, CA (United States); Polk, James E. [Jet Propulsion Laboratory, Pasadena, CA (United States); Shepherd, Joseph E. [California Institute of Technology, Pasadena, CA (United States)

    2014-12-15

    Highlights: • XPS reference spectra for Ba{sub 2}CaWO{sub 6} and BaWO{sub 4} are presented. • Binding energies of Ba 3d and W 4f lines are 0.7 eV higher for BaWO{sub 4} than Ba{sub 2}CaWO{sub 6}. • Ca 2p spectrum contains two sets of Ca 2p doublets attributed to Ba{sub 2}CaWO{sub 6} and CaCO{sub 3}. - Abstract: XPS reference spectra for Ba{sub 2}CaWO{sub 6} and BaWO{sub 4} are presented, including high resolution spectra of the Ba 3d, W 4f, C 1s, Ca 2p, and O 1s lines. The peak locations and full widths at half maximum are also given. The binding energies of the Ba 3d and W 4f lines are 0.7 eV higher for BaWO{sub 4} than for Ba{sub 2}CaWO{sub 6}. The Ca 2p spectrum contains two sets of Ca 2p doublets that were attributed to Ba{sub 2}CaWO{sub 6} and CaCO{sub 3}.

  17. Dissolved Black Carbon in the Headwaters-To Continuum of PARAÍBA do Sul River, Brazil

    Science.gov (United States)

    Marques, Jomar S. J.; Dittmar, Thorsten; Niggemann, Jutta; Almeida, Marcelo G.; Gomez-Saez, Gonzalo V.; Rezende, Carlos E.

    2017-02-01

    Rivers annually carry 25-28 Tg carbon in the form of pyrogenic dissolved organic matter (dissolved black carbon, DBC) into the ocean, which is equivalent to about 10% of the entire riverine land-ocean flux of dissolved organic carbon (DOC). The objective of this study was to identify the main processes behind the release and turnover of DBC on a riverine catchment scale. As a model system, we chose the headwater-to-ocean continuum of Paraíba do Sul River (Brazil), the only river system with long-term DBC flux data available. The catchment was originally covered by Atlantic rain forest (mainly C3 plants) which was almost completely destroyed over the past centuries by slash-and-burn. As a result, large amounts of wood-derived charcoal reside in the soils. Today, fire-managed pasture and sugar cane (both dominated by C4 plants) cover most of the catchment area. Water samples were collected along the river, at the main tributaries, and also along the salinity gradient in the estuary and up to 35 km offshore during three different seasons. DBC was determined on a molecular level as benzenepolycarboxylic acids (BPCAs). Stable carbon isotopes (δ13C) were determined in solid phase extractable DOC (SPE-DOC) to distinguish C4 and C3 sources. Our results clearly show a relationship between hydrology and DBC concentrations in the river, with highest DBC concentrations and fluxes in the wet season (flux of 770 moles .sec 1 in 2013 and 59 moles .sec 1 in 2014) and lowest in the dry season (flux of 27 moles .sec 1). This relationship indicates that DBC is mainly mobilized from the upper soil horizons during heavy rainfalls. The relationship between DBC concentrations and δ13C-SPE-DOC indicated that most of DBC in the river system originated from C3 plants, i.e. from the historic burning event of the Atlantic rain forest. A conservative mixing model could largely reproduce the observed DBC fluxes within the catchment and the land to ocean continuum. Comparably slight

  18. Polarizabilities of Ba and Ba2: Comparison of molecular beam experiments with relativistic quantum chemistry

    International Nuclear Information System (INIS)

    Schaefer, Sascha; Mehring, Max; Schaefer, Rolf; Schwerdtfeger, Peter

    2007-01-01

    The dielectric response to an inhomogeneous electric field has been investigated for Ba and Ba 2 within a molecular beam experiment. The ratio of the polarizabilities per atom of Ba 2 and Ba is determined to be 1.30±0.13. The experimental result is compared to a high level ab initio quantum chemical coupled cluster calculation with an energy-consistent scalar relativistic small-core pseudopotential for Ba. For the barium atom a polarizability of 40.82 A 3 is obtained and the isotropic value of the polarizability calculated for Ba 2 is 97.88 A 3 , which is in good agreement with the experimental results, demonstrating that a quantitative understanding of the interaction between two closed-shell heavy element metal atoms has been achieved

  19. Estado nutricional relativo ao zinco de crianças que frequentam creches do estado da Paraíba Zinc nutritional status in children attending public daycare centers in the state of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Dixis Figueroa Pedraza

    2011-08-01

    Full Text Available OBJETIVO: Avaliar o estado nutricional relativo ao zinco de crianças assistidas em creches do Estado da Paraíba. MÉTODOS: O estado nutricional relativo ao zinco de 235 crianças pré-escolares foi avaliado através de sua concentração no soro, da ingestão dietética de zinco e da estatura para idade, como recomendado pelo International Zinc Consultative Group. As concentrações séricas de zinco foram determinadas por espectrofotometria de absorção atômica de chama, considerando deficiência de zinco valores OBJECTIVE: This study assessed the zinc levels of children attending public daycare centers in the state of Paraíba. Brazil. METHODS: The zinc levels of 235 preschool children were evaluated through serum zinc concentration, dietary zinc intake and height-for-age, as recommended by the International Zinc Nutrition Consultative Group. Baseline zinc levels in the serum were measured by flame atomic absorption spectrophotometry, considering values <65µmol/L indicative of zinc deficiency. The 24-hour recall method was used to record food consumption, considering the food consumption of the child the day before and in the daycare center. Zinc inadequacy was analyzed according to the estimated average zinc requirement by life stage and diet type recommended by the International Zinc Nutrition Consultative Group. The World Health Organization Growth Reference was used as the reference for the height-for-age indices. Children with indices two z-scores below the median value of the reference population were considered stunted. Statistical analysis was performed by the t-test or analysis of variance by the software Statistical Package for the Social Sciences -16.0. RESULTS: The prevalence of inadequate serum zinc concentration, inadequate zinc intakes and stunting were 16.2%, 16.6% and 7.7%, respectively. Mean serum zinc was lower in children of underweight mothers than in children of normal weight mothers. CONCLUSION: The studied children

  20. Population structure of the lancelet Branchiostoma caribaeum (Cephalochordata: Branchiostomidae in the Baía de Guanabara, Rio de Janeiro, southeastern Brazil Estrutura populacional do anfioxo Branchiostoma caribaeum (Cephalochordata: Branchiostomidae na Baía de Guanabara, sudeste do Brasil

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    Luis F. B. da Silva

    2008-12-01

    Full Text Available Population structure of the lancelet Branchiostoma caribaeum Sandevall, 1853 was studied in four surveys, corresponding to austral seasons, in a tropical bay, southeast of Brazil. Abundance was higher in the spring and was positively correlated to coarse sediments, limiting its occurrence to some sectors of the sampling area. Body length and biomass differed seasonally but not between sexes. Sexually mature individuals occurred in all seasons, suggesting continuous breeding that is typical of tropical species. Variation in the frequency of small specimens indicates temporal differences in the intensity of breeding. The body length of recruits differed from other population of lancelets and the small length which B. caribaeum attained sexual maturity in Guanabara Bay may be related to local environmental stress or the great availability of food.A estrutura populacional do anfioxo Branchiostoma caribaeum Sandevall, 1853 foi analisada em quatro campanhas abrangendo todas as estações do ano, na Baía de Guanabara, sudeste do Brasil. A abundância de indivíduos foi maior na primavera e positivamente correlacionada com sedimentos grossos, tendo sua distribuição limitada a alguns setores da área amostral. O tamanho corpóreo e a biomassa diferiram sazonalmente, mas não entre os sexos. Indivíduos sexualmente maduros ocorreram em todas as estações do ano, sugerindo uma reprodução contínua, típica de espécies tropicais. Variações na freqüência de ocorrência de espécimes pequenos indicaram diferenças temporais na intensidade da reprodução. O tamanho corpóreo dos recrutas diferiu de populações de anfioxos de outros locais. O menor tamanho em que B. caribaeum atinge a maturidade sexual na Baía da Guanabara pode estar relacionada ao estresse ambiental ou à grande disponibilidade de alimento do local.

  1. Actions for the development of local productive arrangement of fish farming in the municipality of Sobradinho/BA | Ações para o desenvolvimento de arranjos produtivos locais de piscicultura no município de Sobradinho / BA

    Directory of Open Access Journals (Sweden)

    Eberson Pessoa Ribeiro

    2016-06-01

    Full Text Available Local productive arrangements (LPAs are important options for the implementation of job-creating public policies and income in a sustainable way. In Brazil, such policies to encourage organizations, although recent, has become consistent and the results of its implementation can already be perceived. This work consisted in analyzing the performance of the Development Company of the São Francisco and Parnaíba (Codevasf in the local productive arrangement of fish farming in the municipality of Sobradinho/BA. Through documentary research in the database of the 6th Regional Superintendency and interviews with engineers Unit of the Regional Revitalization Management - Territorial Development Unit of the institution, arrangement of characteristics and the benefits for the participants and the local population were raised. As results, it was found that after the company's participation in LPAs was a considerable increase in production, marketing and consumption of fish as well as the creation of new job opportunities in the region.

  2. Chemical analysis of dairy cattle feed from Brazil

    International Nuclear Information System (INIS)

    Luis Gustavo Cofani dos Santos; De Nadai Fernandes, E.A.; Marcio Arruda Bacchi; Lucimara Blumer; Gabriel Adrian Sarries; Fernando Barbosa Junior

    2009-01-01

    The bovine dairy cattle demand diets of high nutritional value being essential to know chemical composition of feed supplied to cows to achieve high levels of quality, safety and productivity of milk. Different roughages and concentrates from Minas Gerais and Rio Grande do Sul states, Brazil, were analyzed by instrumental neutron activation analysis (INAA) and inductively coupled plasma mass spectrometry (ICP-MS). Concentrate and roughage samples were differentiated by mass fractions of As, Ba, Mg, P, Rb and Sr. Samples of concentrate from both origins were differentiated by mass fractions of As, Cd, Co, Cr, Cs, Ni and Rb. (author)

  3. Outbreaks of rhinofacial and rhinopharyngeal zygomycosis in sheep in Paraíba, northeastern Brazil Surtos de zigomicose rinofacial e rinofaríngea em ovinos na Paraíba

    Directory of Open Access Journals (Sweden)

    Franklin Riet-Correa

    2008-01-01

    Full Text Available Two outbreaks of zigomycosis with rhinofacial and two other with rhinopharyngeal lesions involving fungi with filamentous coaenocytic hyphae characteristic of entomoph-thoramycetous fungi are reported in the state of Paraíba, northeastern Brazil. One outbreak of rhinofacial zygomycosis occurred during the rainy season affecting 5 sheep. Another outbreak of the clinical form affected one out of 40 sheep during the dry season. Common clinical signs of the rhinofacial infection were bilateral serosanguineous nasal discharge with swelling of nostrils, upper lip, and the skin of the face. At necropsy the nasal mucosa showed dark brownish ulcerated areas which extended from the mucocutaneous region to 10cm inside the nasal vestibule. The mucosa of the hard palate was also ulcerated. The cutting surface of nostrils and palate showed a brownish or red spongeous tissue of friable consistency. One outbreak of rhinopharyngitis took place on an irrigated coconut farm; 7 out of 60 adult sheep were affected. Another outbreak affected a sheep in a flock of 80 during the dry season. Clinical signs as noisy respiration and dyspnoea due to mechanical blockage of the nasal cavities, swelling of the nostrils, and serosanguineous nasal discharge were observed. Six out of 8 sheep in this group showed exophthalmia, keratitis and unilateral corneal ulceration of the eye. The sheep either died of their infection or were euthanized after a clinical course of 7-30 days. At necropsy there was a dense yellow exudate in the nasopharyngeal area affecting the ethmoidal region, turbinate bones, paranasal sinuses, hard and soft palates, orbital cavity, pharynges, regional muscles and lymph nodes. Histopathologically both forms of the disease showed multifocal granulomas with an eosinophilic necrotic reaction (Splendore-Hoeppli phenomenon containing ribbon-type coenocytic hyphae with 7-30mum in diameter similar to hyphae of zygomycetous fungi, possibly Conidiobolus spp

  4. Ba incorporation in benthic foraminifera

    NARCIS (Netherlands)

    de Nooijer, L.J.; Brombacher, Anieke; Mewes, A.; Langer, Gerald; Nehrke, G.; Bijma, Jelle; Reichart, G.J.

    2017-01-01

    Barium (Ba) incorporated in the calcite of many foraminiferal species is proportional to the concentration of Ba in seawater. Since the open ocean concentration of Ba closely follows seawater alkalinity, foraminiferal Ba ∕ Ca can be used to reconstruct the latter. Alternatively, Ba ∕ Ca from

  5. Assessment of stability of ceramics type perovskite, Ba{sub 2}MgWO{sub 6}, submerged in crude oil taken from oil wells of Sergipe - Brazil; Avaliacao da estabilidade de ceramicas tipo perovskita, Ba{sub 2}MgWO{sub 6}, submersas em petroleo cru retirado de pocos do estado de Sergipe - Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Yadava, Y.P.; Sales, D.G.; Lima, M.M.; Ferreira, R.A.S. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil)], e-mail: daniella_guedes@yahoo.com.br

    2008-07-01

    Oil wells are harsh environments, thus, it is necessary to find materials that are able to resist the weather imposed by these sites. Many of the new technology incorporating ceramic components because their chemical properties, electrical, mechanical, thermal and structural. The ceramics exhibit high hardness and therefore resistant to high pressure, have high melting point, resisting the high temperatures, and make inert nature in hostile environments. The ceramics, type Perovskite Ba{sub 2}MgWO{sub 6}, were submerged in crude oil for thirty days and then examined by X-ray diffraction, optical microscopy and Vickers microhardness to see if there were changes in structural characteristics, microstructural and mechanical properties. This work was evaluated and discussed by these results, the stability of these ceramics when subject to attack by crude oil taken from oil wells of land and sea state of Sergipe, Brazil. (author)

  6. Characterization of heavy metals in a uranium ore region of the state of Pernambuco, Brazil.

    Science.gov (United States)

    Bezerra, Jairo Dias; dos Santos Amaral, Romilton; dos Santos Júnior, José Araújo; Genezini, Frederico Antonio; Menezes, Rômulo Simões Cezar; de Oliveira, Iane Andrade

    2014-03-01

    The concentrations of As, Zn, Co, Cr, and Ba were determined in soil samples from an anomalous uranium ore region in the countryside of the state of Pernambuco, Brazil. The main land use system in this region is dairy farming, and there is a need to evaluate the potential risk of milk contamination. Twenty-three soil samples were activated with neutrons and analyzed using a high-resolution gamma-ray spectrometer system. The results, recorded in mg kg(-1), varied from 0.4 to 6.7 for As, from 17.0 to 110.0 for Zn, from 2.8 to 38.4 for Co, from 12.1 to 65.5 for Cr, and from 443.0 to 1,497.0 for Ba. All of the Ba concentrations were higher than the intervention value adopted by the Brazilian National Environmental Board. This finding justifies research in other environmental areas to predict the toxicological risks to the local population.

  7. Anthelmintic efficacy of pumpkin seed (Cucurbita pepo Linnaeus, 1753) on ostrich gastrointestinal nematodes in a semiarid region of Paraíba State, Brazil.

    Science.gov (United States)

    Feitosa, Thais Ferreira; Vilela, Vinícius Longo Ribeiro; Athayde, Ana Célia Rodrigues; Braga, Fábio Ribeiro; Dantas, Elaine Silva; Vieira, Vanessa Diniz; de Melo, Lídio Ricardo Bezerra

    2013-01-01

    The aim of this study was to verify the in vivo effectiveness of pumpkin seed (Curcubita pepo Linnaeus, 1753) in naturally infected ostriches in the Cariri zone, semiarid region of Paraíba State, Brazil. Forty-eight ostriches were used, African Black breed, of 14 to 36 months old, naturally infected by gastrointestinal nematodes. These animals were divided into four groups of 12 ostriches. Group 1 consists of animals treated with 0.5 g/kg live weight (l. w.) of pumpkin seed meal; group 2 received 1 g/kg l. w. of pumpkin seed meal; group 3 was treated with Albendazole 5 %, at the dosage of 1 mL/10 kg l. w.; and Group 4 was the control group and do not received treatment. Groups 1 and 2 received the treatment for three consecutive days, orally, at intervals of 7 days, totaling nine administrations. The Albendazole 5 % was administered one time, at the beginning of the experiment, according to the manufacturer's recommendations. The groups treated with pumpkin seed showed a significant decrease in egg counts per gram of feces (EPG), wherein group 2 (1 g/kg l. w.) was the most effective. The control and drug groups showed no reduction in EPG. The results of the present study demonstrate that the administration of pumpkin seed was effective in controlling gastrointestinal helminths in naturally infected ostriches.

  8. Alpha decay of 114Ba

    International Nuclear Information System (INIS)

    Mazzocchi, C.; Janas, Z.; Batist, L.; Belleguic, V.; Doering, J.; Kapica, M.; Kirchner, R.; Roeckl, E.; Gierlik, M.; Zylicz, J.; Mahmud, H.; Schmidt, K.; Woods, P.J.

    2003-01-01

    The neutron-deficient isotope 114 Ba was produced in a fusion evaporation reaction at the GSI On-Line Mass Separator. We measured the α-particle energy of 114 Ba, the half-life of its daughter nucleus 110 Xe, and the α-decay branching ratios for 114 Ba, 110 Xe and 106 Te. (orig.)

  9. Effect of local environment on crossluminescence kinetics in SrF{sub 2}:Ba and CaF{sub 2}:Ba solid solutions

    Energy Technology Data Exchange (ETDEWEB)

    Terekhin, M.A. [P.N. Lebedev Physical Institute, Leninskij Prospekt 53, 119991 Moscow (Russian Federation); Makhov, V.N., E-mail: makhov@sci.lebedev.ru [P.N. Lebedev Physical Institute, Leninskij Prospekt 53, 119991 Moscow (Russian Federation); Lebedev, A.I.; Sluchinskaya, I.A. [Lomonosov Moscow State University, Moscow 119991 (Russian Federation)

    2015-10-15

    Spectral and kinetic properties of extrinsic crossluminescence (CL) in SrF{sub 2}:Ba (1%) and CaF{sub 2}:Ba (1%) are compared with those of intrinsic CL in BaF{sub 2} and are analyzed taking into account EXAFS data obtained at the Ba L{sub III} edge and results of first-principles calculations. The CL decay time was revealed to be longer in SrF{sub 2}:Ba and CaF{sub 2}:Ba compared to BaF{sub 2}. This fact contradicts the expected acceleration of luminescence decay which could result from an increased overlap of wave functions in solid solutions due to shortening of the Ba-F distance obtained in both EXAFS measurements and first-principles calculations. This discrepancy is explained by the effect of migration and subsequent non-radiative decay of the Ba (5p) core holes in BaF{sub 2} and by decreasing of the probability of optical transitions between Ba (5p) states and the valence band in SrF{sub 2}:Ba and CaF{sub 2}:Ba predicted by first-principles calculations. - Highlights: • The crossluminescence kinetics in SrF{sub 2}:Ba and CaF{sub 2}:Ba is slower than in BaF{sub 2}. • Ba{sup 2+} ions substitute for host Ca{sup 2+}(Sr{sup 2+}) ions in the on-center positions. • The nearest Ba-F distances in SrF{sub 2}:Ba and CaF{sub 2}:Ba are shorter than in BaF{sub 2}. • EXAFS data and first-principles calculations of the local structure agree well. • First-principles calculations explain slower luminescence decay in solid solutions.

  10. Diversidade de Euglossinae (Hymenoptera, Apidae em dois fragmentos de Mata Atlântica localizados na região urbana de João Pessoa, Paraíba, Brasil Diversity of Euglossinac (Hymenoptera, Apidae in two Atlantic Forest fragments located in the urban area of João Pessoa, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Cleomar Porto Bezerra

    2001-09-01

    Full Text Available The use of fragrances to attract males of Euglossinae bees has been an important tool to increase the knowledge of the group. In the Northeastern of Brazil, studies on euglossine bees are still uncommon, mainly in urban areas. The goals of this study are to identify the Euglossinae species composition, to know the diversity and the community structure of Euglossinae species, verify their preferences for different fragrances and evaluate the phenology of these species, in two Atlantic Forest fragments of the city of João Pessoa, Paraíba state, Brazil. Bees were sampled at 15 days intervals, over the course of one year, from 8:00 to 17:00 hours, through the use of traps baited with seven types of fragrances. In both areas, 1082 individuals belonging to nine species were sampled. None significant difference of diversity and relative abundance of bees between fragments were observed. Eucalyptol was the most attractive fragrance. Bees were more abundant between 8:00 and 9:00 AM. Visits to the fragrances were more frequent from the middle of dry season to the beginning of the rainy season and positively correlated with the monthly mean temperature. Most species of bees visited all the baits over the year, but the number of attracted males was highest in April.

  11. Aerial gamma spectrometry of the uranium province of Lagoa Real (Caetite, BA, Brazil): go environmental aspects and distribution of the absorbed dose in the air; Espectrometria gama aerea da provincia uranifera de Lagoa Real (Caetite, BA): aspectos geoambientais e distribuicao da dose absorvida no ar

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Esau Francisco Sena

    2006-07-01

    In the present study, it was analyzed the surface concentrations of the natural radioelements K, U and Th, as well as the absorbed dose rate in air caused by gamma radiation from the Lagoa Real uranium province, which is located at the center southern portion of Bahia State and comprises an area of approximately 4.600 Km{sup 2}. Data from the airborne gamma ray spectrometric survey of the region (Sao Timoeo Project) carried out in 1979, was used in this study. Besides, recent data of U, Th and absorbed dose rates from the Environmental Monitoring Program of the uranium concentration plant (URA), operated in the region by the Brazilian Nuclear Industries (INB), were used with the aim of inter compare the sampling points in the same geo referenced area. Imaging geo processing software's give support to frame maps of surface concentrations and ternary maps, as well as allow the integration of these with other themes (e.g. hydrology, geology, pedology) favouring the interpretation of geo environmental process from the radioactive cartography. Considering the whole study area, it was obtained the following mean values: absorbed dose rate in air (61,08 nGy.h{sup -1}), Potassium (1,65 % K) , Uranium (3,02 ppm eU) and thorium (18,26 ppm eTh). The geological unities bounding the uranium anomalies were placed in the areas characterized by the highest values of radioelements and, as expected, the major dose levels. The use of ternary maps coupled with the geology and hydrology allowed distinguishing the relationship between the surface distribution of natural radioelements and the geo environmental aspects, including the influence of the catchment in their transport and migration. (author)

  12. Aerial gamma spectrometry of the uranium province of Lagoa Real (Caetite, BA, Brazil): go environmental aspects and distribution of the absorbed dose in the air; Espectrometria gama aerea da provincia uranifera de Lagoa Real (Caetite, BA): aspectos geoambientais e distribuicao da dose absorvida no ar

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Esau Francisco Sena

    2006-07-01

    In the present study, it was analyzed the surface concentrations of the natural radioelements K, U and Th, as well as the absorbed dose rate in air caused by gamma radiation from the Lagoa Real uranium province, which is located at the center southern portion of Bahia State and comprises an area of approximately 4.600 Km{sup 2}. Data from the airborne gamma ray spectrometric survey of the region (Sao Timoeo Project) carried out in 1979, was used in this study. Besides, recent data of U, Th and absorbed dose rates from the Environmental Monitoring Program of the uranium concentration plant (URA), operated in the region by the Brazilian Nuclear Industries (INB), were used with the aim of inter compare the sampling points in the same geo referenced area. Imaging geo processing software's give support to frame maps of surface concentrations and ternary maps, as well as allow the integration of these with other themes (e.g. hydrology, geology, pedology) favouring the interpretation of geo environmental process from the radioactive cartography. Considering the whole study area, it was obtained the following mean values: absorbed dose rate in air (61,08 nGy.h{sup -1}), Potassium (1,65 % K) , Uranium (3,02 ppm eU) and thorium (18,26 ppm eTh). The geological unities bounding the uranium anomalies were placed in the areas characterized by the highest values of radioelements and, as expected, the major dose levels. The use of ternary maps coupled with the geology and hydrology allowed distinguishing the relationship between the surface distribution of natural radioelements and the geo environmental aspects, including the influence of the catchment in their transport and migration. (author)

  13. An integrated geological and geophysical study of the Parnaíba cratonic basin, North-East Brazil

    Science.gov (United States)

    Tozer, B.; Watts, A. B.; Daly, M.

    2015-12-01

    Cratonic basins are characterized by their sub-circular shape, long-lived (>100 Myr) subsidence, shallow marine/terrestrial sediments that young towards the center of the basin and exhibit little internal deformation, and thick seismic lithosphere. Despite the recognition of >30 world-wide, the paucity of geological and geophysical data over these basins means their origin remains enigmatic. In order to address this problem, we have used a recently acquired 1400 km long seismic reflection profile recorded to 20 s TWTT, field observations and well logs, gravity and magnetic data acquired at 1 km intervals, and five wide-angle refection/refraction receiver gathers recorded at offsets up to 100 km, to constrain the origin of the Parnaíba basin, North-East Brazil. We find a depth to pre-Paleozoic basement and Moho of ~ 3.5 and ~ 40 - 42 km respectively beneath the basin center. A prominent mid-crustal reflection (MCR) can be tracked laterally for ~ 300 km at depths between 17 - 25 km and a low-fold wide-angle receiver gather stack shows that the crust below the MCR is characterized by a ~ 4 s TWTT package of anastomosing reflections. Gravity modelling suggests that the MCR represents the upper surface of a high density (+0.14 kg m-3) lower crustal body, which is probably of magmatic origin. Backstripping of biostratigraphic data from wells in the center of the basin show an exponentially decreasing subsidence. We show that although cooling of a thick (180 km) lithosphere following prolonged rifting (~ 65 Myr) can provide a good fit to the tectonic subsidence curves, process-oriented gravity and flexure modelling suggest that other processes must be important, as rifting does not account for the observed gravity anomaly and predicts too thin a crust (~ 34 km). The thicker than expected crust suggests warping due, for example, to far-field stresses or basal tractions. Another possibility, which is compatible with existing geophysical data, is a dense magmatic intrusion

  14. Oceanographic characteristics of an impacted coastal bay: Baía de Guanabara, Rio de Janeiro, Brazil

    Science.gov (United States)

    Kjerfve, Björn; Ribeiro, Cesar H. A.; Dias, Gilberto T. M.; Filippo, Alessandro M.; Da Silva Quaresma, Valéria

    1997-11-01

    Baía de Guanabara is a 384 km 2 eutrophic coastal bay in Brazil, impacted by the polluted discharge from the Rio de Janeiro metropolitan area. The structurally controlled bay has a central channel with a depth of 30 m and a sandy bottom near the entrance, reflecting wave and tidal forcing. In contrast, the bay-averaged water depth is 5.7 m and the bottom sediments are mostly muds as a result of the Holocene transgression and rapid fluvial sedimentation, accelerated by channelization of rivers and deforestation. An extensive sand bank is located seaward of the bay entrance and a flood-oriented sand wave system indicates sand transport into the bay. The mean freshwater discharge measures 100±59 m 3 s -1 and is greatest in the rainy austral summer in December and January. Tides are mixed mainly semidiurnal with a range of 0.7 m, and peak spring tidal currents reach 0.5 m s -1 inside the bay and 1.6 m s -1 near the bay entrance. The passage of northward propagating polar fronts results in regular strong southwesterly winds and heavy wave forcing. The bay has mean salinities from 21.0 to 34.5‰ with an average of 29.5±4.8‰. The vertical salinity stratification, Δs/s, varies from 0.06 to 0.21 and is relatively weak and inversely proportional to rms tidal currents. The residual circulation is characterized by both gravitational circulation and transverse residual tidal circulation, measuring 800 and 400 m 3 s -1 respectively. The renewal time of 50% of the bay water volume is 11.4 days. Untreated sewage runoff enters the bay from the west, resulting in locally poor water quality, where the near-bottom mean dissolved oxygen measures only 3.1 mg 1 -1 and results in anoxic bottom muds. The worst water quality is indicated by average fecal coliform of 1140 counts ml -1 and excessive ammonia and phosphate loading. The average chlorophyll concentration in this region responds to the nutrient loading and exceeds 130 μg 1 -1 although 57 μg 1 -1 is the overall mean for

  15. Simulação da precipitação diária para Parnaíba e Teresina, PI, em planilha eletrônica Daily rainfall simulation in Parnaíba and Teresina - Brazil, using a spreadsheet

    Directory of Open Access Journals (Sweden)

    Aderson S. de Andrade Júnior

    2001-05-01

    Full Text Available Os estudos envolvendo precipitação pluviométrica são bastante dificultados devido ao fato das séries históricas disponíveis serem, na maioria dos casos, muito pequenas para efetuá-los. Desta forma, faz-se necessário dispor de uma técnica de simulação estocástica que possibilite a geração de valores diários de precipitação, utilizando-se uma planilha eletrônica. No Estado do Piauí, estudos com esse objetivo são inexistentes, razão por que este trabalho tem o objetivo de simular a precipitação pluviométrica diária para as regiões de Parnaíba e Teresina, PI, através de uma planilha eletrônica. O processo de simulação se baseou no método de Monte Carlo. A ocorrência da precipitação foi determinada através da cadeia de Markov, enquanto a sua magnitude foi estimada pelas funções de distribuição de probabilidades gama e empírica. O modelo utilizado proporcionou estimativas com excelente precisão e exatidão, fato comprovado pelos resultados satisfatórios quanto aos índices de desempenho estatísticos.The studies involving rainfall are quite difficult to conduct due to the fact that the available historical series, in most of the cases, are too small to make them. Thus, it is necessary to adjust a stochastic simulation technique that facilitates the generation of daily rainfall values, using a spreadsheet. In Piauí State, studies with this objective are inexistent for its several regions of agricultural importance. This work was executed with the objective of simulating the daily rainfall for the regions of Parnaíba and Teresina - PI, Brazil, using a spreadsheet. The simulation process was based on Monte Carlo's method. The occurrence of the rainfall was determined through a Markov chain, while its magnitude was estimated by gamma and empirical distribution functions. The model used provided estimates with excellent precision and accuracy, checked by satisfactory results of the statistical performance index.

  16. Improvement of the field-trapping capabilities of bulk Nd Ba Cu O superconductors using Ba Cu O substrates

    Science.gov (United States)

    Matsui, Motohide; Nariki, Shinya; Sakai, Naomichi; Iwafuchi, Kengo; Murakami, Masato

    2006-07-01

    We used Ba-Cu-O substrates to fabricate bulk Nd-Ba-Cu-O superconductors using a top-seeded melt-growth method. There were several advantages for the use of Ba-Cu-O substrate compared to conventional substrate materials such as MgO, ZrO2, Al2O3, RE123 and RE211 (RE = rare earth). The Ba-Cu-O did not react with the precursor and minimized liquid loss. Accordingly, the introduction of large-sized cracks was suppressed. We also found that Tc values were high at the bottom regions, which was ascribed to the beneficial effect of Ba-Cu-O in suppressing Nd/Ba substitution. As a result, we obtained bulk Nd-Ba-Cu-O superconductors that exhibited fairly good field-trapping capabilities, even at the bottom surfaces.

  17. Co2FeAl based magnetic tunnel junctions with BaO and MgO/BaO barriers

    Directory of Open Access Journals (Sweden)

    J. Rogge

    2015-07-01

    Full Text Available We succeed to integrate BaO as a tunneling barrier into Co2FeAl based magnetic tunnel junctions (MTJs. By means of Auger electron spectroscopy it could be proven that the applied annealing temperatures during BaO deposition and afterwards do not cause any diffusion of Ba neither into the lower Heusler compound lead nor into the upper Fe counter electrode. Nevertheless, a negative tunnel magnetoresistance (TMR ratio of -10% is found for Co2FeAl (24 nm / BaO (5 nm / Fe (7 nm MTJs, which can be attributed to the preparation procedure and can be explained by the formation of Co- and Fe-oxides at the interfaces between the Heusler and the crystalline BaO barrier by comparing with theory. Although an amorphous structure of the BaO barrier seems to be confirmed by high-resolution transmission electron microscopy (TEM, it cannot entirely be ruled out that this is an artifact of TEM sample preparation due to the sensitivity of BaO to moisture. By replacing the BaO tunneling barrier with an MgO/BaO double layer barrier, the electric stability could effectively be increased by a factor of five. The resulting TMR effect is found to be about +20% at room temperature, although a fully antiparallel state has not been realized.

  18. Diet, reproduction and population structure of the introduced Amazonian fish Cichla piquiti (Perciformes: Cichlidae in the Cachoeira Dourada reservoir (Paranaíba River, central Brazil

    Directory of Open Access Journals (Sweden)

    Tatiane Ferraz Luiz

    2011-06-01

    Full Text Available The Blue Peacock Bass (Cichla piquiti, native to the Tocantins-Araguaia river basin of the Amazon system, was introduced into the basin of the Paranaíba River, Paraná River system. Cachoeira Dourada reservoir is one of a series of dams on the Paranaíba River in central Brazil, where this fish has become established. A study of its feeding spectrum, combined with information about its reproductive characteristics and population structure, would enable the current state of this species in the reservoir to be assessed and might provide useful data for the management of other species native to this habitat. This study showed that the peacock bass has no predators or natural competitors in the reservoir and that reproduces continuously, with high reproductive rates, and has a smaller median length at first maturity (L50 than other species of Cichla. Its successful establishment in habitats strongly affected by human activity should cause changes in the whole structure of the local fish communities. Nonetheless, in this reservoir, there appears to be some sharing of the functions of this species with native carnivorous fish, a situation that may be sustained by the presence of a wide variety of foraging fish. Rev. Biol. Trop. 59 (2: 727-741. Epub 2011 June 01.El pez tucunaré (Cichla piquiti, nativo del sistema de la cuenca del rio Tocantins-Araguaia, fue introducido en la cuenca del río Paranaíba, parte del sistema del río Paraná. En este ecosistema trófico de planicie aluvial, las relaciones entre comunidades de peces están definidas por diferentes factores que pueden ser modificados debido a la represa del río, y da como resultado grandes cambios en la interacción biológica en éstos hábitats. La represa de Cachoeira Dourada forma parte de una serie de represas en el río Paranaíba en el Brasil central, donde el tucunaré se ha establecido. Una investigación sobre su espectro alimentario, combinado con información sobre sus caracter

  19. Structural and electrical properties of Barium Titanate (BaTiO3 and Neodymium doped BaTiO3 (Ba0.995Nd0.005TiO3

    Directory of Open Access Journals (Sweden)

    Tuan Sulong Tuan Amirah

    2017-01-01

    Full Text Available Barium titanate (BaTiO3 and Neodymium (Nd doped BaTiO3 with composition Ba0.995Nd0.005TiO3 were prepared using conventional solid state reaction method to study the dielectric properties of materials. Pure phase samples were found at final heating temperature of 1400°C for overnight. X-ray diffraction analysis reveals the changes in the lattice parameter and unit cell volume of the pure perovskite tetragonal structure with space group (P4mm. Electrical analysis is carried out to investigate the dielectric properties, conductivity behaviour and dielectric loss of BaTiO3 and Ba0.995Nd0.005TiO3. Ba0.995Nd0.005TiO3 have a broaden dielectric peaks with high permittivity of 8000 and reasonably low loss tan δ which is about 0.004 (1 kHz.

  20. Study of stability of the ceramic Ba{sub 2}NiWO{sub 6} in crude petroleum drew back from state - Brazil oil wells; Microestrutura e propriedades mecanicas da ceramica Ba{sub 2}NiWO{sub 6} apos imersao em petroleo cru retirado de pocos de prtroleo do estado de Sergipe - Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Yadava, Y.P.; Bezerra, L.P.; Diniz, M.J.L.; Ferreira, R.A.S. [Universidade Federal de Pernambuco (DEM/UFPE), Recife, PE (Brazil). Dept. de Engenharia Mecanica], e-mail: yadava@ufpe.br

    2008-07-01

    The necessity of developing technologies which make practical the oil-well exploration is notorious. Knowing that those are hostile places is necessary to find materials which are capable to resist to the inclemency caused by those environments. Pondering that the ceramics show the required characteristics to this purpose the present assignment views the elaboration of complex perovskite ceramic Ba{sub 2}NiWO{sub 6} to produce ceramics components parts of temperature sensors to oil-well. To this purpose we studied the ceramic stability when they are vulnerable to the attack of the crude petroleum drew back from ocean and earth's oil-wells of Sergipe state-Brazil. The ceramics were submersed in the mentioned petroleum during thirty days and then they were analyzed by X-ray diffraction, optics microscopy and microhardness Vickers to verify if changes happened in the structure, microstructure and mechanics proprieties characteristics. These results are showed and discussed in this assignment. (author)

  1. Trace Metals and Lead Isotopes in modern Sediments Near Rio de Janeiro, Brazil

    Science.gov (United States)

    Boyle, E. A.; Lazzari, L.; Wagener, A. L.; Carreira, R.; Godoy, J. M.; Noble, A.; Carrasco, G. G.; Moos, S. B.

    2014-12-01

    This work focuses on the export of trace metals and combustion residues from land to ocean and on the Southeast continental margin of Brazil and its historical variability using stable lead isotopes. Two sediment cores were collected, one in highly impacted Guanabara Bay and the other on the Southeast continental shelf. Continental shelf samples were analyzed for trace element concentrations [Mn (117±50 ppm), Ni (6.5±2.3 ppm), Zn (5.0±1.5), (233±46 ppm), ], Pb (5.4±2.4 ppm), as well as Cu, Ag, Cd, Sr, Ba, Tl, U and Pb isotope ratios & Pb-210. Most of the elements show higher concentrations on the upper part of the core compared to the bottom. Downcore changes of the concentrations of these elements were similar. The sediments of adjacent rivers and bays around the upper section of the southeast continental shelf of Brazil are considered highly enriched with Pb, Zn, Cu and Cr such as Guanabara Bay, Sepetiba Bay and Paraíba do Sul River compared with the natural concentrations and other regions in the world. A [Pb] maximum is seen between samples from 24 to 43 cm (~8 ppm). Utilization of tetraethyl lead (TEL) gasoline in Brazil was phased out beginning in 1983 and was largely completed by 1988. Continental shelf Pb-206/Pb-207 varies between 1.174 near the core top to 1.190 at 100 cm, with a sharp difference between samples at 6 and 8 cm. Higher core top Pb, Zn, and Ni corroborate the recent anthropogenic influence on the southeast continental shelf of Brazil. For Guanabara Bay sediment samples [Pb] varies between 90 ppm near the top to 1 ppm at the bottom. Pb-206/Pb-207 varies between 1.161 near the core top to 1.165 near the bottom. Using triple isotope plots we can discern different sources of lead to the region and how these vary with time.

  2. Chalcogenidosilicates: Ba/sub 2/SiTe/sub 4/ and Ba/sub 2/SiSe/sub 4/

    Energy Technology Data Exchange (ETDEWEB)

    Brinkmann, C; Eisenmann, B; Schaefer, H [Technische Hochschule Darmstadt (Germany, F.R.). Fachbereich Anorganische Chemie und Kernchemie

    1985-05-01

    The new compounds Ba/sub 2/SiSe/sub 4/ and Ba/sub 2/SiTe/sub 4/ crystallize in the monoclinic system, space group: P2/sub 1//m (No. 11) with the lattice constants Ba/sub 2/SiSe/sub 4/: a = 918.4(5) pm, b = 703.3(3) pm, c = 687.2(3) pm, ..beta.. = 109.2(1)/sup 0/, Ba/sub 2/SiTe/sub 4/: a = 965.0(5) pm, b = 762.6(3) pm, c = 746.6(3) pm, ..beta.. = 108.9(1)/sup 0/. Both compounds are isotypic to the Sr/sub 2/GeS/sub 4/ structure. Ba/sub 2/SiTe/sub 4/ is the first o-telluridosilicate with discrete SiTe/sub 4//sup 4 -/ anions.

  3. Stellar Laboratories: 3. New Ba 5, Ba 6, and Ba 7 Oscillator Strengths and the Barium Abundance in the Hot White Dwarfs G191-B2B and RE 0503-289

    Science.gov (United States)

    Rauch, T.; Werner, K.; Quinet, P.; Kruk, Jeffrey Walter

    2014-01-01

    Context. For the spectral analysis of high-resolution and high-signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims. Reliable Ba 5-7 oscillator strengths are used to identify Ba lines in the spectra of the DA-type white dwarf G191-B2B and the DO-type white dwarf RE 0503-289 and to determine their photospheric Ba abundances. Methods. We newly calculated Ba v-vii oscillator strengths to consider their radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Ba lines exhibited in high-resolution and high-S/N UV observations of G191-B2B and RE 0503-289. Results. For the first time, we identified highly ionized Ba in the spectra of hot white dwarfs. We detected Ba vi and Ba vii lines in the Far Ultraviolet Spectroscopic Explorer (FUSE) spectrum of RE 0503-289. The Ba vi/Ba vii ionization equilibrium is well reproduced with the previously determined effective temperature of 70 000 K and surface gravity of log g=7.5. The Ba abundance is 3.5 +/- 0.5 × 10(exp-4) (mass fraction, about 23 000 times the solar value). In the FUSE spectrum of G191-B2B, we identified the strongest Ba vii line (at 993.41 Å) only, and determined a Ba abundance of 4.0 +/- 0.5 × 10(exp-6) (about 265 times solar). Conclusions. Reliable measurements and calculations of atomic data are a pre-requisite for stellar-atmosphere modeling. Observed Ba vi-vii line profiles in two white dwarfs' (G191-B2B and RE 0503-289) far-ultraviolet spectra were well reproduced with our newly calculated oscillator strengths. This allowed to determine the photospheric Ba abundance of these two stars precisely.

  4. The BaBar Mini

    International Nuclear Information System (INIS)

    Brown, David N.

    2003-01-01

    BaBar has recently deployed a new event data format referred to as the Mini. The mini uses efficient packing and aggressive noise suppression to represent the average reconstructed BaBar event in under 7 KBytes. The Mini packs detector information into simple transient data objects, which are then aggregated into roughly 10 composite persistent objects per event. The Mini currently uses Objectivity persistence, and it is being ported to use Root persistence. The Mini contains enough information to support detailed detector studies, while remaining small and fast enough to be used directly in physics analysis. Mini output is customizable, allowing users to both truncate unnecessary content or add content, depending on their needs. The Mini has now replaced three older formats as the primary output of BaBar event reconstruction. A reduced form of the Mini will soon replace the physics analysis format as well, giving BaBar a single, flexible event data format covering all its needs

  5. The BaBar mini

    International Nuclear Information System (INIS)

    Brown, David N.; BaBar Collaboration

    2003-01-01

    BaBar has recently deployed a new event data format referred to as the Mini. The mini uses efficient packing and aggressive noise suppression to represent the average reconstructed BaBar event in under 7 KBytes. The Mini packs detector information into simple transient data objects, which are then aggregated into roughly 10 composite persistent objects per event. The Mini currently uses Objectivity persistence, and it is being ported to use Root persistence. The Mini contains enough information to support detailed detector studies, while remaining small and fast enough to be used directly in physics analysis. Mini output is customizable, allowing users to both truncate unnecessary content or add content, depending on their needs. The Mini has now replaced three older formats as the primary output of BaBar event reconstruction. A reduced form of the Mini will soon replace the physics analysis format as well, giving BaBar a single, flexible event data format covering all its needs

  6. Microhabitats de Aedes albopictus (Skuse na região do Vale do Paraíba, Estado de São Paulo, Brasil Microhabitats of Aedes albopictus (Skuse in the Paraíba Valley region of the State of S. Paulo, Brazil

    Directory of Open Access Journals (Sweden)

    Almério de Castro Gomes

    1992-04-01

    Full Text Available Objetivou-se determinar o nível de disseminação de Ae. albopictus na região do Vale do Paraíba, Estado de São Paulo, Brasil. Foram realizadas coletas de larvas e pupas em seis locais distintos, segundo transecto com 10 km de extensão. O alvo principal foi oco de árvores, tendo sido também incluídos artefatos antrópicos. As espécies Ae. terrens e Ae. albopictus foram as únicas do gênero Aedes presentes e, algumas vezes, coexistiram no mesmo microhabitat natural. A segregação de sete espécies da comunidade de oco variou de acordo com os macro e microhabitats examinados. Assim, a distribuição de Ae. albopictus envolveu as zonas rural, rural-urbana e urbana, porém a segunda área foi a mais preferida. Como fator favorável à infestação de Ae. albopictus na região, destacou-se a vacância de nichos ecológicos naturais resultante da influência antrópica. As chuvas foram relevantes no "input" de larvas e pupas e os ocos, com volumes superiores a 600 ml, foram os mais produtivos. A abundância desses dois estádios ocorreu nas estações verão-outono, sendo o pico máximo alcançado nos meses de março-abril. Essa sazonalidade foi comum em bambu experimental e recipientes artificiais. Os dados de temperatura média sugeriram a faixa de 23 a 17°C como o período mais favorável ao desenvolvimento larvário. Face a isso, a cepa de Ae. albopictus estudada parece ser oriunda da Ásia tropical e, portanto, se reveste de elevada importância epidemiológica pela possibilidade dessa espécie vir a exercer, além do dengue, papel vetorial para a febre amarela no Brasil.The objective of this study was the determination of extent of the spacial distribution of Aedes albopictus in the Paraíba River Valley, State S. Paulo, Brazil. Thus, collections of larvae and pupae mosquitoes were carried out at six sites distributed along a transection with a 10-km extension. The target was the treeholes but artificial containers were also used in

  7. Back-contacted BaSi

    NARCIS (Netherlands)

    Vismara, R.; Isabella, O.; Zeman, M.

    2017-01-01

    We present the optical investigation of a novel back-contacted architecture for solar cells based on a thin barium (di)silicide (BaSi2) absorber. First, through the analysis of absorption limits of different semiconducting materials, we show the potential of BaSi2 for

  8. Analysis of lichen species for atmospheric pollution biomonitoring in the Santo Andre municipality, Sao Paulo, Brazil

    International Nuclear Information System (INIS)

    Saiki, M.; Alves, E.R.; Marcelli, M.P.

    2007-01-01

    Instrumental neutron activation analysis was applied for the determination of trace elements in Canoparmelia texana species collected in nonpolluted areas of Atlantic Forest and in six sites of Santo Andre Municipality, SP, Brazil. Concentrations of As, Ba, Br, Ca, Cd, Cl, Cr, Cs, Co, Fe, K, La, Mn, Na, Rb, Sb, Sc, Se, U, and Zn were determined and comparisons were made between the results obtained in lichens from different sites

  9. Tabanidae (Diptera do estado do Maranhão, Brasil: III. Descrição de Philipotabanus (Mimotabanus henriquesi sp. nov. Tabanidae (Diptera from the state of Maranhão, Brazil: III. Description of Philipotabanus (Mimotabanus henriquesi sp. nov.

    Directory of Open Access Journals (Sweden)

    Francisco Limeira-de-Oliveira

    2009-12-01

    Full Text Available Philipotabanus (Mimotabanus henriquesi sp. nov. é descrita e ilustrada baseada em 30 fêmeas e dois machos coletados em vegetação de Cerrado, nos municípios de Carolina, Alto Parnaíba e Mirador, região sul do estado do Maranhão, Brasil. Este é o primeiro registro de uma espécie do subgênero no Brasil.Philipotabanus (Mimotabanus henriquesi, sp. nov., is described and illustrated based on 30 females and two males specimens collected in open vegetation of "Cerrado", in Carolina, Alto Parnaíba and Mirador municipalities, in southern Maranhão state, Brazil. This is the first record of species of the subgenus in Brazil.

  10. Estudo de prevalência de defeitos congênitos no Vale do Paraíba Paulista Prevalence study of birth defects in Vale do Paraíba, São Paulo, Brazil

    Directory of Open Access Journals (Sweden)

    Cilene Otaviano Pinto

    2007-09-01

    Full Text Available OBJETIVO: Estimar a prevalência de anomalias congênitas no Vale do Paraíba Paulista em 2002 e 2003. MÉTODOS: Estudo transversal com base em dados constantes na Declaração de Nascido Vivo (DNV, cujas informações estavam no portal da Secretaria da Saúde do Estado de São Paulo. As malformações foram descritas de acordo com o capítulo XVII do Código Internacional de Doenças (CID 10, referente a variáveis maternas e do recém-nascido. A variável desfecho (dependente foi a presença de anomalia congênita; as demais informações das mães e do recém-nascido constantes na DNV (variáveis independentes foram analisadas para estimar as associações entre elas e a variável desfecho. Utilizou-se o programa Epi-Info 6.04d para análise estatística e o teste do qui-quadrado, do qui-quadrado de tendência linear e o teste t de Student. RESULTADOS: Foram analisados 41.838 dados com informações constantes nas DNVs, sendo identificados 618 (1,5% sem preenchimento do campo correspondente à anomalia congênita e 317 (0,76% nascidos com anomalia congênita. Houve associação positiva de anomalias congênitas com menor duração da gestação, maior número de filhos mortos, tipo de parto, baixo peso ao nascer e menor escore de Apgar. Os sistemas mais afetados foram o osteomuscular e o nervoso. CONCLUSÕES: A prevalência de malformações foi menor que a encontrada em outros estudos, possivelmente por sub-registro de informação.OBJECTIVE: Estimate the prevalence of birth defects in the Vale do Paraíba Paulista, São Paulo - Brazil, during the years of 2002 and 2003. METHODS: Cross-sectional study based on Birth Certificates available in the São Paulo Health Secretary site. The abnormalities were described according to chapter XVII of the International Classification of Diseases and Related Health Problems (ICD 10 for variables related to mothers and infants born alive at birth. The dependent variable was the presence of abnormalities

  11. First record of Amphisbaena mertensi Strauch, 1881 (Squamata: Amphisbaenidae) in Minas Gerais state, Brazil

    OpenAIRE

    Silveira, Adriano; Brites, Vera; Valinhas e Valinhas, Raquel

    2012-01-01

    We present here the first record of Amphisbaena mertensi in Minas Gerais state, southeastern Brazil. Through analysis of scientific collections, we found specimens of A. mertensi from municipalities of Patos de Minas, Uberaba, Indianópolis, Uberlândia and Araguari, in Triângulo Mineiro and Alto Paranaíba regions. These localities are inserted in the Cerrado biome, with Atlantic Forest enclaves, and represent an expansion of the previously known geographic distribution for the species.

  12. Octupole correlations in neutron-rich {sup 143,145}Ba and a type of superdeformed band in {sup 145}Ba

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, S.J.; Wang, M.G.; Long, G.L.; Zhu, L.Y.; Gan, C.Y.; Yang, L.M.; Sakhaee, M.; Li, M.; Deng, J.K. [Physics Department, Tsinghua University, Beijing 100084, Peoples Republic of (China); Zhu, S.J.; Hamilton, J.H.; Ramayya, A.V.; Jones, E.F.; Hwang, J.K.; Zhang, X.Q.; Gore, P.M.; Peker, L.K.; Drafta, G.; Babu, B.R.; Deng, J.K.; Ginter, T.N.; Beyer, C.J.; Kormicki, J.; Ter-Akopian, G.M.; Daniel, A.V. [Physics Department, Vanderbilt University, Nashville, Tennessee 37235 (United States); Zhu, S.J.; Ter-Akopian, G.M.; Daniel, A.V. [Joint Institute for Heavy Ion Research, Oak Ridge, Tennessee 37831 (United States); Ma, W.C. [Physics Department, Mississippi State University, Mississippi 39762 (United States); Cole, J.D.; Aryaeinejad, R.; Drigert, M.W. [Idaho National Engineering Laboratory, Idaho Falls, Idaho 83415 (United States); Rasmussen, J.O.; Asztalos, S.; Lee, I.Y.; Macchiavelli, A.O.; Chu, S.Y.; Gregorich, K.E.; Mohar, M.F. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Ter-Akopian, G.M.; Daniel, A.V.; Oganessian, Y.T.; Kliman, J. [Flerov Laboratory for Nuclear Reactions, Joint Institute for Nuclear Research, Dubna (Russia); Donangelo, R. [Universidade Federal do Rio de Janeiro, Caixa Postal 68528, RG (Brazil); Stoyer, M.A.; Lougheed, R.W.; Moody, K.J.; Wild, J.F. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Prussin, S.G. [Nuclear Engineering Department, University of California at Berkeley, Berkeley, California 94720 (United States); Kliman, J. [Institute of Physics, SASc, Dubravskacesta 9, 84228 Bratislava (Slovakia); Griffin, H.C. [University of Michigan, Ann Arbor, Michigan 48104 (United States)

    1999-11-01

    High spin states in neutron-rich odd-{ital Z} {sup 143,145}Ba nuclei have been investigated from the study of prompt {gamma} rays in the spontaneous fission of {sup 252}Cf by using {gamma}-{gamma}- and {gamma}-{gamma}-{gamma}- coincidence techniques. Alternating parity bands are identified for the first time in {sup 145}Ba and extended in {sup 143}Ba. A new side band, with equal, constant dynamic, and kinetic moments of inertia equal to the rigid body value, as found in superdeformed bands, is discovered in {sup 145}Ba. Enhanced E1 transitions between the negative- and positive-parity bands in these nuclei give evidence for strong octupole deformation in {sup 143}Ba and in {sup 145}Ba. These collective bands show competition and coexistence between symmetric and asymmetric shapes in {sup 145}Ba. Evidence is found for crossing M1 and E1 transitions between the s=+i and s={minus}i doublets in {sup 143}Ba. {copyright} {ital 1999} {ital The American Physical Society}

  13. Phonon dispersion curves of BCC Ba

    International Nuclear Information System (INIS)

    Mizuki, J.; Stassis, C.; Zarestky, J.

    1985-01-01

    Ba, as well as Sr and Ca, is a divalent alkaline earth metal. At room temperature and ambient pressure, the structure of Ba is bcc, whereas that of Sr and Ca is fcc. Under pressure, the bcc phase of Ba transforms to an hcp structure at 55 kbar. Also, at 37 kbar Ba becomes a superconductor with T/sub c/ = 0.06 K. These properties are highly dependent on the position of the d bands relative to the Fermi level. Experimental investigation of the elastic and lattice dynamical properties of these metals has been hindered by difficulties in growing single crystals. However, recently the authors were able to grow several single crystals of bcc Ba of sufficient volume for inelastic neutron scattering experiments. Some of the results are summarized here

  14. Hyperfine structure and isotope shift of the neutron-rich barium isotopes 139-146Ba and 148Ba

    International Nuclear Information System (INIS)

    Wendt, K.; Ahmad, S.A.; Klempt, W.; Neugart, R.; Otten, E.W.

    1988-01-01

    The hyperfine structure and isotope shift in the 6s 2 S 1/2 -6p 2 P 3/2 line of Ba II (455.4 nm) have been measured by collinear fast-beam laser spectroscopy for the neutron-rich isotopes 139-146 Ba and 148 Ba. Nuclear moments and mean square charge radii of these isotopes have been recalculated. The isotope shift of the isotope 148 Ba (T 1/2 = 0.64 s) could be studied for the first time, yielding δ 2 > 138,148 = 1.245(3) fm 2 . (orig.)

  15. Capture techniques' use of Caranguejo-uçá crabs (Ucides cordatus in Paraíba state (northeastern Brazil and its socio-environmental implications

    Directory of Open Access Journals (Sweden)

    Douglas M. Nascimento

    2012-12-01

    Full Text Available The present study was undertaken in two traditional communities that are located on the margins of the estuary and mangrove complex of the Mamanguape River, Paraíba state (PB, Brazil. This work describes the crabs capture techniques tapamento and redinha, and identifies the negative socio-environmental impacts of redinha, using qualitative methods (open and semi-structured interviews, guided tours, direct observation and the administration of questionnaires. Results indicate that currently only two principle techniques are used to capture Ucides cordatus: redinha and tapamento. Tapamento has a low impact in relation to redinha. Redinha was pointed out by interviewees as a system that has social impact (social conflicts, breaking of traditions, substitution and extinction of techniques and environmental impact (less selective captures and high productivity, mangrove pollution, death of crabs caught in traps, cutting of the roots of Rhizophora mangle, micro-habitat loss resulting from galleries destroyed and polluted. Knowledge of crab harvesting carried out using these two techniques and the possible social and environmental impacts caused by redinha, can lead to more effective planning and actions towards the conservation of the species.O estudo foi realizado em duas comunidades tradicionais localizadas às margens do complexo estuário-manguezal do rio Mamanguape, Paraíba (PB, Brasil. Foram descritas as técnicas de captura (tapamento e redinha, identificando os impactos socioambientais negativos provocados pela redinha na captura de caranguejos, utilizando métodos qualitativos (entrevistas abertas e semiestruturadas, turnês guiadas, observação direta e questionários. Os resultados indicaram que atualmente apenas estas técnicas são usadas na captura de Ucides cordatus. O tapamento apresenta baixo impacto em relação à redinha, que é apontada pelos entrevistados como causadora de impactos sociais (conflitos sociais, rompimento de

  16. Syntheses, crystal structures and characterizations of BaZn(SeO3)2 and BaZn(TeO3)Cl2

    International Nuclear Information System (INIS)

    Jiang Hailong; Feng Meiling; Mao Jianggao

    2006-01-01

    Two new barium zinc selenite and tellurite, namely, BaZn(SeO 3 ) 2 and BaZn(TeO 3 )Cl 2 , have been synthesized by the solid state reaction. The structure of BaZn(SeO 3 ) 2 features double chains of [Zn(SeO 3 ) 2 ] 2- anions composed of four- and eight-member rings which are alternatively along a-axis. The double chains of [Zn 2 (TeO 3 ) 2 Cl 3 ] 3- anions in BaZn(TeO 3 )Cl 2 are formed by Zn 3 Te 3 rings in which each tellurite group connects with three ZnO 3 Cl tetrahedra. BaZn(SeO 3 ) 2 and BaZn(TeO 3 )Cl 2 are wide bandgap semiconductors based on optical diffuse reflectance spectrum measurements. -- Graphical abstract: Two new barium zinc selenite and tellurite, namely, BaZn(SeO 3 ) 2 and BaZn(TeO 3 )Cl 2 , have been synthesized by solid state reaction. The structure of BaZn(SeO 3 ) 2 features 1D double chains of [Zn(SeO 3 ) 2 ] 2- anions composed of four- and eight-member rings which are alternatively along a-axis. The 1D double chains of [Zn 2 (TeO 3 ) 2 Cl 3 ] 3- anions in BaZn(TeO 3 )Cl 2 are formed by Zn 3 Te 3 rings in which each tellurite group connects with one ZnO 3 Cl and two ZnO 2 Cl 2 tetrahedra. BaZn(SeO 3 ) 2 and BaZn(TeO 3 )Cl 2 are wide bandgap semiconductors based on optical diffuse reflectance spectrum measurements

  17. Stellar laboratories. III. New Ba v, Ba vi, and Ba vii oscillator strengths and the barium abundance in the hot white dwarfs G191-B2B and RE 0503-289

    Science.gov (United States)

    Rauch, T.; Werner, K.; Quinet, P.; Kruk, J. W.

    2014-06-01

    Context. For the spectral analysis of high-resolution and high-signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims: Reliable Ba v-vii oscillator strengths are used to identify Ba lines in the spectra of the DA-type white dwarf G191-B2B and the DO-type white dwarf RE 0503-289 and to determine their photospheric Ba abundances. Methods: We newly calculated Ba v-vii oscillator strengths to consider their radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Ba lines exhibited in high-resolution and high-S/N UV observations of G191-B2B and RE 0503-289. Results: For the first time, we identified highly ionized Ba in the spectra of hot white dwarfs. We detected Ba vi and Ba vii lines in the Far Ultraviolet Spectroscopic Explorer (FUSE) spectrum of RE 0503-289. The Ba vi/Ba vii ionization equilibrium is well reproduced with the previously determined effective temperature of 70 000 K and surface gravity of log g = 7.5. The Ba abundance is 3.5 ± 0.5 × 10-4 (mass fraction, about 23 000 times the solar value). In the FUSE spectrum of G191-B2B, we identified the strongest Ba vii line (at 993.41 Å) only, and determined a Ba abundance of 4.0 ± 0.5 × 10-6 (about 265 times solar). Conclusions: Reliable measurements and calculations of atomic data are a pre-requisite for stellar-atmosphere modeling. Observed Ba vi-vii line profiles in two white dwarfs' (G191-B2B and RE 0503-289) far-ultraviolet spectra were well reproduced with our newly calculated oscillator strengths. This allowed to determine the photospheric Ba abundance of these two stars precisely. Based on observations with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for

  18. High spin structure in 130,131Ba

    International Nuclear Information System (INIS)

    Kaur, Navneet; Kumar, A.; Singh, Amandeep; Kumar, S.; Kaur, Rajbir; Singh, Varinderjit; Behera, B.R.; Singh, K.P.; Singh, G.; Mukherjee, G.; Sharma, H.P.; Kumar, Suresh; Kumar Raju, M.; Madhusudhan Rao, P.V.; Muralithar, S.; Singh, R.P.; Kumar, Rakesh; Madhvan, N.; Bhowmik, R.K.

    2014-01-01

    High spin states of 130,131 Ba have been investigated via fusion evaporation reactions 122 Sn( 13 C,4n) 131 Ba and 122 Sn( 13 C, 5n) 130 Ba at E beam =65 MeV. The level schemes of 130,131 Ba have been extended by placing several new γ transitions. A few interband transitions connecting two negative-parity bands, which are the experimental fingerprints of signature partners, have been established in 130 Ba. Spin and parity of a side band have been assigned in 131 Ba and this dipole band is proposed to have a three-quasiparticle configuration, νh 11/2 x πh 11/2 x πg 7/2 . The observed band structures and nuclear shape evolution as a function of the angular momentum have been discussed in the light of Total-Routhian-Surface calculations. (orig.)

  19. Mutagenic potential of pollutans in the water of the Paraíba do Sul river, Tremembé, SP, Brazil, using the Allium cepa test

    Directory of Open Access Journals (Sweden)

    Agnes Barbério

    2011-04-01

    Full Text Available The mutagenicity can be related to chromosomic breaks induced by environmental pollutants. The aim of this research was to characterize the mutagenic potential of the pollutants in the water of the Paraíba do Sul river, in Tremembé city, São Paulo State, Brazil, analyzing chromosomal changes in the meristematic cells of Allium cepa, in the summer (April and winter (August of 2008. The bulbs were exposed for 72 h to the treatments: water from river, Hoagland solution (negative control and 15 µg/L from MMS – methyl methanesulfonate (positive control. In each treatment, three bulbs were exposed and for each bulb, five slides were prepared. For mitotic index (MI and micronucleus (MN frequency rate, a total of 2,000 cells per root/slide were analyzed and 100 cells for the chromosome aberrations (CA. In April, the pollutants induced a high mutagenic potential in the meristematic cells of Allium cepa, the frequency rate of MN, stickiness and CA from non-identified type were greater than the negative control. In August, the only significant change found was the chromosome bridges. There was no significant change for MI. These results indicate that the effluents which have varied sources are inducing harmful effects on the bioindicator, therefore, it is important to keep biomonitoring and adopting effluents control measures. The measures are important because these waters are used primarily for public supply and irrigation.

  20. Thermal analysis of formation of nano-crystalline BaTiO3 using Ba(NO32 and TiO2

    Directory of Open Access Journals (Sweden)

    Md. Jawed Ansaree

    2015-12-01

    Full Text Available The reaction of Ba(NO32 with TiO2 was studied by thermogravimetric (TG and differential scanning calorimetric (DSC techniques up to 1000 °C and in nitrogen atmosphere. It was found that the formation of BaTiO3 takes place above 600 °C and that precursor mixing time and heating rate have no effect on the reaction temperature. BaTiO3 powder was prepared by calcination of Ba(NO32 and TiO2 precursor mixture at 800 °C for 8 h. X-ray diffraction analysis of the synthesized BaTiO3 confirmed the formation of tetragonal phase with lattice parameters a = 3.9950±0.0003 Å and c = 4.0318±0.0004 Å. Thermal analysis of the synthesized BaTiO3 powder showed weight loss within temperature range 40–1000 °C of only 0.40%. This small amount of weight loss was connected with some impurity phase, and identified as BaCO3 using Fourier transform infrared (FTIR technique.

  1. Growth and characterization of acentric BaHf(BO{sub 3}){sub 2} and BaZr(BO{sub 3}){sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Mączka, Mirosław, E-mail: m.maczka@int.pan.wroc.pl [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wrocław 2 (Poland); Szymborska-Małek, Katarzyna; Gągor, Anna [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wrocław 2 (Poland); Majchrowski, Andrzej [Institute of Applied Physics, Military University of Technology, 2 Kaliskiego Str., 00-908 Warszawa (Poland)

    2015-05-15

    Growth, single crystal X-ray diffraction, polarized Raman and infrared (IR) studies of BaHf(BO{sub 3}){sub 2} are presented. Raman and IR spectra of polycrystalline BaZr(BO{sub 3}){sub 2} are also reported to facilitate assignment of modes. BaHf(BO{sub 3}){sub 2} borate crystallizes in trigonal system, space group R3c, with lattice parameters: a=5.1540(4) Å, c=33.901(3) Å. It accommodates dolomite-like structure doubled in the c direction, which is built of alternating layers of HfO{sub 6} octahedra and BaO{sub 6} distorted trigonal prisms that are connected through borate groups. The obtained structural as well as spectroscopic data show that BaHf(BO{sub 3}){sub 2} is isostructural with BaZr(BO{sub 3}){sub 2} and the deviations from centrosymmetry is small. - Graphical abstract: Arrangement of BO{sub 3} groups in BaHf(BO{sub 3}){sub 2} along the c direction in one unit cell. Dark and light blue denote different borate groups. - Highlights: • BaHf(BO{sub 3}){sub 2} single crystals were grown. • X-ray diffraction showed that this borate crystallizes in the acentric R3c structure. • Raman and IR spectra were measured for BaHf(BO{sub 3}){sub 2} and BaZr(BO{sub 3}){sub 2}, respectively. • Assignment of modes is proposed.

  2. Epidemiology of snakebite accidents in the municipalities of the state of Paraíba, Brazil Epidemiologia dos acidentes ofídicos ocorridos nos municípios do Estado da Paraíba, Brasil

    Directory of Open Access Journals (Sweden)

    Rafaella Moreno Barros

    2013-05-01

    Full Text Available Accidents involving venomous animals represent an important, albeit neglected, public health issue worldwide. A descriptive study was made of snakebite cases attended and recorded between 2007 and 2010 in the health units of the municipalities of Cariri, State of Paraíba, northeastern Brazil. Data was collected from the Injury Notification Information System data banks of the Health Ministry and a total of 351 records of snakebite victims were reviewed. Victims were predominantly male farm workers over 50. The highest incidence of snakebites occurred in rural areas, between April and June of 2007 and 2010. Snakes of the genus Bothrops were responsible for most cases, and victims were mostly bitten on the feet. The majority of the victims received medical assistance within 1 to 3 hours after being bitten. The most common clinical manifestations were pain, edema and ecchymosis, which were mainly classified as mild or moderate. Two deaths were reported. It was concluded that there is a significant impact of seasonality in snakebites, the prevalence of attacks caused by Bothrops, affecting the lower limbs of adult male farmers in rural areas. The findings of this study may contribute to identify the conditions that increase the risk of snake attacks in the northeastern region.Acidentes por animais peçonhentos representam um importante, embora negligenciado, problema de saúde pública mundial. Neste sentido, foi realizado um estudo descritivo dos acidentes ofídicos atendidos e registrados, entre 2007 e 2010, nas unidades de saúde dos municípios do Cariri, Estado da Paraíba, Nordeste do Brasil. As informações foram coletadas do banco de dados do Sistema de Informação de Agravos de Notificação do Ministério da Saúde. Um total de 351 registros de vítimas de ataques por serpentes peçonhentas foram analisados. As vítimas foram predominantemente trabalhadores rurais do sexo masculino com mais de 50 anos. As maiores incidências de

  3. Metal concentrations in surface sediments of Paraiba do Sul River (Brazil)

    International Nuclear Information System (INIS)

    Pereira, M.O.; Calza, C.; Lopes, R.T.; Anjos, M.J.; UERJ, Rio de Janeiro; Araujo, F.G.

    2006-01-01

    The Paraiba do Sul River is located in a strategic region between the most important urban and industrial centers of Brazil. In the last years, an increase in the water pollution has been reported, caused by the untreated domestic sewerage of the inhabitants, effluents discharged by various industries, mining activities and sand extraction from the riverbed. This work used total reflection X-ray fluorescence with synchrotron radiation (SRTXRF) to determine metals in the bioavailable and residual fractions from the surface sediments. The metals identified were Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Ba and Pb. (author)

  4. Synthesis of BaTiO3 nanoparticles from TiO2-coated BaCO3 particles derived using a wet-chemical method

    Directory of Open Access Journals (Sweden)

    Yuuki Mochizuki

    2014-03-01

    Full Text Available BaCO3 particles coated with amorphous TiO2 precursor are prepared by a wet chemical method to produce BaTiO3 nanoparticles at low temperatures. Subsequently, we investigate the formation behavior of BaTiO3 particles and the particle growth behavior when the precursor is subjected to heat treatment. The state of the amorphous TiO2 coating on the surface of BaCO3 particles depends on the concentration of NH4HCO3, and the optimum concentration is found to be in the range 0.5–1.0 M. Thermogravimetric curves of the BaCO3 particles coated with the TiO2 precursor, prepared from BaCO3 particles of various sizes, show BaTiO3 formation occurring mainly at 550–650 °C in the case of fine BaCO3 particles. However, as evidenced from the curves, the temperature of formation of BaTiO3 shifts to higher values with an increase in the size of the BaCO3 particles. The average particle size of single phase BaTiO3 at heat-treatment temperature of 650–900 °C is observed to be in the range 60–250 nm.

  5. Spectral analysis of Pr{sup 3+} doped germanate glasses modified by BaO and BaF{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Pisarska, Joanna, E-mail: joanna.pisarska@us.edu.pl [University of Silesia, Institute of Chemistry, Szkolna 9 Street, 40-007 Katowice (Poland); Pisarski, Wojciech A. [University of Silesia, Institute of Chemistry, Szkolna 9 Street, 40-007 Katowice (Poland); Dorosz, Dominik; Dorosz, Jan [Bialystok University of Technology, Faculty of Electrical Engineering, Wiejska 45D Street, 15-351 Bialystok (Poland)

    2016-03-15

    Luminescence properties of Pr{sup 3+} ions in germanate glasses modified by BaF{sub 2} were investigated. Several luminescence bands originating to transitions from the {sup 3}P{sub 0} state to the lower-lying states of Pr{sup 3+} were registered under 450 nm excitation. The spectral analysis suggests that the positions of luminescence bands and their relative intensities are changed significantly with BaF{sub 2} content. The relative integrated luminescence intensities of {sup 3}P{sub 0}→{sup 3}H{sub 4} transition (blue) to the {sup 3}P{sub 0}→{sup 3}F{sub 2} transition (red) of Pr{sup 3+} ions strongly depend on fluoride modifier BaF{sub 2} in glass composition. The luminescence bands of Pr{sup 3+} ions are shifted to shorter wavelengths with increasing BaF{sub 2} content. - Highlights: • Praseodymium doped lead-free germanate glasses modified by BaF{sub 2} were prepared. • Emission spectra correspond to transitions from {sup 3}P{sub 0} state to lower-lying states of Pr{sup 3+}. • The relative emission band intensities of Pr{sup 3+} depend strongly on BaF{sub 2} content. • Emission bands of Pr{sup 3+} are shifted to shorter wavelengths with increasing BaF{sub 2} content.

  6. High field-effect mobility at the (Sr,Ba)SnO{sub 3}/BaSnO{sub 3} interface

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, Kohei, E-mail: kfujiwara@imr.tohoku.ac.jp; Nishihara, Kazuki; Shiogai, Junichi; Tsukazaki, Atsushi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2016-08-15

    A perovskite oxide, BaSnO{sub 3}, has been classified as one of transparent conducting materials with high electron mobility, and its application for field-effect transistors has been the focus of recent research. Here we report transistor operation in BaSnO{sub 3}-based heterostructures with atomically smooth surfaces, fabricated on SrTiO{sub 3} substrates by the (Sr,Ba)SnO{sub 3} buffer technique. Indeed, modulation of band profiles at the channel interfaces with the insertion of wide bandgap (Sr,Ba)SnO{sub 3} as a barrier layer results in a significant improvement of field-effect mobility, implying effective carrier doping at the regulated heterointerface. These results provide an important step towards realization of high-performance BaSnO{sub 3}-based field-effect transistors.

  7. Mortalidade perinatal de cordeiros no semi-árido da Paraíba Perinatal mortality of lambs in the semi-arid region of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Janduí Escarião da Nóbrega Jr

    2005-09-01

    Full Text Available As causas de mortalidade perinatal em ovinos foram estudadas de março de 2002 a outubro 2004 em 27 fazendas da região semi-árida da Paraíba. De 90 cordeiros necropsiados, 41,1% morreram de infecções neonatais, 23,3% por malformações, 10% por inanição/hipotermia, 10% por distocia, 2,2% por predação e 4,4% foram abortos sem causa identificada. Em relação ao momento da morte, 4,4% dos cordeiros morreram antes do parto, 10% durante o parto, 30% no primeiro dia de vida, 20% entre o 2º e 5º dia e 35,6% entre o 4º e 28º dia após o parto. A assistência das ovelhas durante o parto, a desinfecção do umbigo dos cordeiros, a ingestão de colostro 2 a 6 horas após o parto, e a manutenção das ovelhas em locais adequados durante e após o parto contribuiriam para diminuir as mortes perinatais por distocia e infecções neonatais. A alta freqüência de malformações, em diferentes raças, sugere que esses defeitos sejam causados por uma planta tóxica. Os principais defeitos observados foram a flexão permanente dos membros anteriores, braquignatismo, fenda palatina e outras alterações dos ossos da cabeça. Recentemente foi demonstrado o efeito teratogênico de Mimosa tenuiflora ("jurema-preta", uma planta muito comum na região semi-árida, nas áreas de caatinga, que aparentemente é responsável pelas malformações. Os cordeiros mortos por inanição/hipotermia tiveram baixo peso ao nascimento (1,37 ± 0,7kg o que sugere que a principal causa dessas mortes é a deficiente nutrição da mãe durante o último terço da gestação. Considerando-se que na região nordeste, na maioria das fazendas, os carneiros permanecem com as ovelhas durante todo o ano, a adoção de uma estação de monta definida contribuiria para a diminuição da mortalidade perinatal.The causes of perinatal lamb mortality were studied, from March 2002 to October 2004, on 27 farms in the semiarid region of Paraíba, northeastern Brazil. In 90 lambs necropsied

  8. Optical characteristics of BaGa2S4:Ho3+ and BaGa2Se4:Ho3+ single crystals

    International Nuclear Information System (INIS)

    Choe, Sung-Hyu; Jin, Moon-Seog; Kim, Wha-Tek

    2005-01-01

    BaGa 2 S 4 , BaGa 2 S 4 :Ho 3+ , BaGa 2 Se 4 , and BaGa 2 Se 4 :Ho 3+ single crystals were grown by using the chemical transport reaction method. The optical energy gaps of the single crystals were investigated in the temperature region from 11 K to 300 K. The temperature dependence of the optical energy gap was well fitted by the Varshni equation. Two broad emission bands were observed in the photoluminescence spectra of the single crystals. These bands were attributed to donor-acceptor pair recombinations. Sharp emission peaks were observed in the BaGa 2 S 4 :Ho 3+ and the BaGa 2 Se 4 :Ho 3+ single crystals and were assigned to radiation recombination between split Stark levels of Ho 3+ .

  9. Long-term evolution of denudational escarpments in southeastern Brazil

    Science.gov (United States)

    Cherem, Luis Felipe Soares; Varajão, Cesar Augusto C.; Braucher, Regis; Bourlés, Didier; Salgado, André Augusto R.; Varajão, Angélica C.

    2012-11-01

    Topographic relief in southeastern Brazil consists of a sequence of stepped surfaces that formed after the fragmentation of Gondwana during the Cretaceous, Tertiary and Quaternary tectonic pulses. This region is drained by four major rivers within four major river basins, with interfluves that contain denudational escarpments, fault escarpments and mountain ranges. This study presents an analysis of the long-term evolution of two denudational escarpments, the Cristiano Otoni and the São Geraldo steps, which divide the river basins of the São Francisco, Doce and Paraíba do Sul rivers in southeastern Brazil. Denudation rates were obtained through the measurement of mean concentrations of in situ produced cosmogenic 10Be in sand-sized fluvial quartz sediments collected from granitic terrains. The rates were calculated and compared with one another and correlated to the basin-scale mean relief, slope, area, and stream power. The mean denudation rates of the Cristiano Otoni and São Geraldo highlands are 8.77 (± 2.78) m My- 1 and 15.68 (± 4.53) m My- 1, respectively. The mean denudation rates of the Cristiano Otoni and São Geraldo escarpments are 17.50 (± 2.71) m My- 1 and 21.22 (± 4.24) m My- 1, respectively. The denudation rates of the catchments of highlands that drain toward the escarpments are similar to those of their respective highlands. The results demonstrate that relief and slope have similar positive control on the denudation rates for all of the samples despite their different geomorphic context and history of landscape evolution. The São Francisco River Basin is losing area to the Doce River Basin, which, in turn, is losing area to the Paraíba do Sul River Basin.

  10. Rates of pulmonary infection by pentastomids in lizards species from a restinga habitat in northeastern Brazil

    OpenAIRE

    Almeida, WO.; Santana, GG.; Vieira, WLS.; Wanderley, IC.; Ribeiro, SC.

    2009-01-01

    Pulmonary parasitism by pentastomids was examined in two lizard species inhabiting an area of restinga vegetation (coastal sand dunes) situated in the municipality of Mataraca (6° 29' S and 34° 56' W), on the extreme northern coast of Paraíba State, Brazil. A total of 123 lizards were collected, being 75 specimens of Micrablepharus maximiliani (Gymnophtalmidae) and 48 specimens of Cnemidophorus ocellifer (Teiidae). Only a single species of Pentastomida (Raillietiella mottae) was found parasit...

  11. Tabagismo em amostra de adolescentes escolares de Salvador-Bahia Smoking among school adolescents in Salvador (BA

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    Adelmo Souza Machado Neto

    2003-10-01

    Full Text Available INTRODUÇÃO: O hábito de fumar em geral se inicia na adolescência. No Brasil, as estimativas da freqüência deste hábito entre adolescentes variam de 1% até 35%. OBJETIVO: Estimar a prevalência do tabagismo entre os adolescentes da oitava série do ensino fundamental à terceira série do curso médio, em escolas de Salvador - Bahia, Brasil. MÉTODO: Feito um estudo do tipo corte transversal de caráter exploratório. Foram aplicados 3.500 questionários a alunos matriculados entre a 8ª série do ensino fundamental e a 3ª série do ensino médio, em cinco escolas da região metropolitana de Salvador (BA. Análise estatística: medidas descritivas e de associação (razão de prevalência e o teste t de Student e o do qui-quadrado. RESULTADOS: A prevalência do tabagismo entre adolescentes de Salvador (BA foi de 9,6%, considerando-se os 3.180 questionários válidos, sendo maior no sexo masculino (14% que no feminino (6%. À medida que aumentava a idade, elevava-se essa prevalência. A média de idade do início do tabagismo foi de 14 ± 2 anos. Dentre adolescentes, 46% experimentaram o cigarro e 20% destes continuaram fumando. Entre filhos de fumantes a freqüência foi maior. O número médio de cigarros consumidos por dia pelos adolescentes que fumavam diariamente (n = 132 foi de 7 ± 6, sendo maior no sexo masculino. CONCLUSÃO: A prevalência do tabagismo em uma amostra selecionada de adolescentes escolares de Salvador (BA foi de 9,6%, sendo maior entre os indivíduos do sexo masculino. A experimentação e a influência dos pais foram associadas ao tabagismo nos adolescentes.BACKGROUND: Most tobacco users become addicted during adolescence. In Brazil, smoking prevalence among teenagers varies from 1% to 35%. OBJECTIVE: To estimate the prevalence of smoking among teenagers, aged from 13 to 20, in fundamental and high school in Salvador, Bahia, Brazil. METHOD: Cross-sectional exploratory study. Thirty five hundred questionnaires were

  12. The use of zootherapeutics in folk veterinary medicine in the district of Cubati, Paraíba State, Brazil

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    da S Mourão José

    2007-09-01

    Full Text Available Abstract Background The present work addresses the use of zootherapy in folk veterinary medicine (ethnoveterinary by the residents of the municipal district of Cubati, microregion of Seridó, Paraíba State, Brazil. It sought to identify the principal animals used as medicinal sources for zootherapeutics and to contribute to the preservation and sustainability of this traditional knowledge. Methods Field research was undertaken on a weekly or biweekly basis during the period November, 2006, to January, 2007. Free, semi-structured, and open interviews were made with local residents of the municipal district of Cubati (in both urban and rural settings as well as with venders in public markets. A total of 25 individuals of both sexes were interviewed (with ages varying from 26 to 78 years although only 16 were finally chosen as informants as these people demonstrated the greatest degree of knowledge concerning zootherapeutics. Graphs and percentages were generated using Microsoft© Excel 2007 software, and the species were identified by photographic registration and subsequent bibliographical surveys. Results Mammals constitute the main medicinal zootherapeutic source for folk veterinary medicines in the studied area, both in terms of the total number of species used and the frequency of their citation. Sheep (Ovis aries, pigs (Sus scrofa, cattle (Bos taurus, and foxes (Cerdocyon thous were mentioned by 62.5, 43.75, 37.5, and 31.25% of the informants, respectively, as being used in folk veterinary medicine. Additionally, chameleons (Iguana iguana, chickens (Gallus domesticus, and rattlesnakes (Crotalus durissus were mentioned by 75, 43.75, and 31.25% of the informants, respectively. Relatively simple animal illnesses, such as furuncles, or injuries resulting from embedded thorns or skin eruptions are responsible for the largest number of zootherapeutic treatment, while, diseases of greater complexity, such as rabies and brucellosis, were not even

  13. The invasion of five alien species in the Delta do Parnaíba Environmental Protection Area, Northeastern Brazil

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    Daniel Loebmann

    2010-09-01

    Full Text Available Marine biological invasions have been regarded as one of the major causes of native biodiversity loss, with shipping and aquaculture being the leading contributors for the introductions of alien species in aquatic ecosystems. In the present study, five aquatic alien species (one mollusk, three crustaceans and one fish species were detected during dives, shore searches and from the fisheries on the coast of the Delta do Parnaíba Environmental Protection Area, in the States of Piauí and Maranhão, Northeastern Brazil. The species were the bicolor purse-oyster Isognomon bicolor, the whiteleg shrimp Litopenaeus vannamei, the giant river prawn Macrobrachium rosenbergii, the Indo-Pacific swimming crab Charybdis hellerii and, the muzzled blenny Omobranchus punctatus. Ballast water (I. bicolor, C. hellerii, and O. punctatus and aquaculture activities (L. vannamei and M. rosenbergii in adjacent areas are the most likely vectors of introduction. All exotic species found have potential impact risks to the environment because they are able to compete against native species for resources (food and habitat. Isognomon bicolor share the same habitat and food items with the native bivalve species of mussels and barnacles. Litopenaeus vannamei share the same habitat and food items with the native penaeids such as the pinkspot shrimp Farfantepenaeus brasiliensis, the Southern brown shrimp Farfantepenaeus subtilis, and the Southern white shrimp Litopenaeus schmitti, and in the past few years L. vannamei was responsible for a viral epidemics in the cultivation tanks that could be transmitted to native penaeid shrimps. Charybdis hellerii is also able to cause impacts on the local fisheries as the species can decrease the populations of native portunid crabs which are commercialized in the studied region. Macrobrachium rosenbergii may be sharing natural resources with the Amazon River prawn Macrobrachium amazonicum. Omobranchus punctatus shares habit with the native

  14. Incorporation of Ba in Al and Fe pollucite

    Energy Technology Data Exchange (ETDEWEB)

    Vance, Eric R., E-mail: erv@ansto.gov.au [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Locked Bag 2001 Kirrawee DC, NSW 2232 (Australia); Gregg, Daniel J.; Griffiths, Grant J. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Locked Bag 2001 Kirrawee DC, NSW 2232 (Australia); Gaugliardo, Paul R. [Centre for Microscopy, Characterisation and Analysis, The University of Western Australia, Crawley, WA 6009 (Australia); Grant, Charmaine [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Locked Bag 2001 Kirrawee DC, NSW 2232 (Australia)

    2016-09-15

    Ba, the transmutation product of radioactive Cs, can be incorporated at levels of up to ∼0.07 formula units in Cs{sub (1−2x)}Ba{sub x}AlSi{sub 2}O{sub 6} aluminium pollucite formed by sol-gel methods and sintering at 1400 °C, with more Ba forming BaAl{sub 2}Si{sub 2}O{sub 8} phases. The effect of Ba substitution in pollucite-structured CsFeSi{sub 2}O{sub 6} was also studied and no evidence of Ba substitution in the pollucite structure via cation vacancies or Fe{sup 2+} formation was obtained. The Ba entered a Fe-silicate glass structure. Charge compensation was also attempted with a Cs{sup +} + Fe{sup 3+} ↔ Ba{sup 2+} + Ni{sup 2+} scheme but again the Ba formed a glass and NiO was evident. PCT leaching data showed CsFeSi{sub 2}O{sub 6} to be very leach resistant. - Highlights: • Barium can be incorporated into aluminium pollucite. • Positron annihilation lifetime spectroscopy supports a charge vacancy mechanism of incorporation. • Iron pollucite does not appear to incorporate any barium with either vacancy or charge compensation mechanisms. • Leaching data suggest iron pollucite is very leach resistant.

  15. Aerial gamma spectrometry of the uranium province of Lagoa Real (Caetite, BA, Brazil): go environmental aspects and distribution of the absorbed dose in the air

    International Nuclear Information System (INIS)

    Santos, Esau Francisco Sena

    2006-01-01

    In the present study, it was analyzed the surface concentrations of the natural radioelements K, U and Th, as well as the absorbed dose rate in air caused by gamma radiation from the Lagoa Real uranium province, which is located at the center southern portion of Bahia State and comprises an area of approximately 4.600 Km 2 . Data from the airborne gamma ray spectrometric survey of the region (Sao Timoeo Project) carried out in 1979, was used in this study. Besides, recent data of U, Th and absorbed dose rates from the Environmental Monitoring Program of the uranium concentration plant (URA), operated in the region by the Brazilian Nuclear Industries (INB), were used with the aim of inter compare the sampling points in the same geo referenced area. Imaging geo processing software's give support to frame maps of surface concentrations and ternary maps, as well as allow the integration of these with other themes (e.g. hydrology, geology, pedology) favouring the interpretation of geo environmental process from the radioactive cartography. Considering the whole study area, it was obtained the following mean values: absorbed dose rate in air (61,08 nGy.h -1 ), Potassium (1,65 % K) , Uranium (3,02 ppm eU) and thorium (18,26 ppm eTh). The geological unities bounding the uranium anomalies were placed in the areas characterized by the highest values of radioelements and, as expected, the major dose levels. The use of ternary maps coupled with the geology and hydrology allowed distinguishing the relationship between the surface distribution of natural radioelements and the geo environmental aspects, including the influence of the catchment in their transport and migration. (author)

  16. Catálogo de tipos de algas depositados en el Herbario Nacional de Plantas Celulares (BA del Museo Argentino de Ciencias Naturales “Bernardino Rivadavia”, Argentina Catalogue of algae types deposited in the National Cryptogamic Herbarium (BA of the Museo Argentino de Ciencias Naturales “Bernardino Rivadavia”, Argentina

    Directory of Open Access Journals (Sweden)

    Andrea Coradeghini

    2011-12-01

    Full Text Available El Herbario Nacional de Plantas Celulares (BA alberga 50.000 especímenes, de los cuales 9.000 son ejemplares de algas marinas y continentales. El catálogo consta de 11 tipos argentinos y 20 tipos del exterior: Australia y Brasil. Cinco de los tipos argentinos fueron depositados por la Lic. Carmen Pujals quién se desempeñó como investigadora de este Museo. El trabajo incluye la lista de nombres ordenados alfabéticamente, sus autores, fecha y cita original seguido por la categoría del tipo, país, provincia, localidad, fecha y datos del colector. De existir una Exsiccata se señalan nombre y número de la misma, número de BA y las observaciones y notas consideradas relevantes. En el caso que corresponde se anota sinonimia y autores.The National Cryptogamic Herbarium (BA contains 50.000 specimens, of which 9.000 are continental and marine algae. The catalogue consists of 11 argentine types and 20 foreign types from Australia and Brazil. Five of the argentine types were deposited by Lic. Carmen Pujals, a former researcher at the Museum. The paper includes the alphabetically ordered list of names, their authors, date and original citation, followed by the type category, country, province, city, date and collector number and original citation. If there is an Exsiccata the name, number, number of BA, observations and relevant notes are reported. When necessary, synonymy and authors are given.

  17. Submillimeter and microwave residual losses in epitaxial films of Y-Ba-Cu-O and Tl-Ca-Ba-Cu-O

    International Nuclear Information System (INIS)

    Miller, D.; Richards, P.L.; Eom, C.B.; Geballe, T.H.; Etemad, S.; Inam, A.; Venkatesan, T.; Martens, J.S.; Lee, W.Y.

    1992-12-01

    We have used a novel bolometric technique and a resonant technique to obtain accurate submillimeter and microwave residual loss data for epitaxial thin films of YBa 2 Cu 3 O 7 , Tl 2 Ca 2 Ba 2 Cu 3 O 10 and Tl 2 CaBa 2 Cu 2 O 8 . For all films we obtain good agreement between the submillimeter and microwave data, with the residual losses in both the Y-Ba-Cu-O and Tl-Ca-Ba-Cu-O films scaling approximately as frequency squared below ∼ 1 THz. We are able to fit the losses in the Y-Ba-Cu-O films to a two fluid and a weakly coupled grain model for the a-b planeconductivity, in good agreement with results from a Kramers-Kronig analysis of the loss data

  18. Processing of R-Ba-Cu-O superconductors

    International Nuclear Information System (INIS)

    Wu, H.

    1998-01-01

    Precipitation processes were developed to introduce second phases as flux pinning centers in Gd-Ba-Cu-O and Nd-Ba-Cu-O superconductors. In Gd-Ba-Cu-O, precipitation is caused by the decrease of the upper solubility limit of Gd 1+x Ba 2-x Cu 3 O 7 solid solution (Gd123ss) in low oxygen partial pressure. Processing of supersaturated Gd 1.2 Ba 1.8 Cu 3 O 7 in low oxygen partial pressure can produce dispersed second phases. Gd211 is formed as a separate phase while extensive Gd124 type stacking fault is formed instead of a separate CuO phase. As a result of the precipitation reaction, the transition temperature and critical current density are increased. In Nd-Ba-Cu-O, precipitation is caused by the decrease of the lower solubility limit of Nd 1+x Ba 2-x Cu 3 O 7 solid solution (Nd123ss) in oxygen. DTA results reveal the relative stability of Nd123ss in different oxygen partial pressures. In 1 bar oxygen partial pressure, Nd123ss with x = 0.1 is the most stable phase. In lower oxygen partial pressures, the most stable composition shifts towards the stoichiometric composition. The relative stability changes faster with decreasing oxygen partial pressure. Therefore, processing in oxygen and air tends to produce broad superconducting transitions but sharp transitions can be achieved in 0.01 bar and 0.001 bar oxygen partial pressures. While the lower solubility limits in 0.01 bar and 0.001 bar oxygen partial pressures remain at x = 0.00, the solubility limits in oxygen and air show a narrowing with decreasing temperature. Because of the narrowing of the solubility range in oxygen, oxygen annealing of Nd123 initially processed in low oxygen partial pressures will result in precipitation of second phases. The equilibrium second phase is BaCuO 2 for temperature above 608 C, and at lower temperatures the equilibrium second phases are Ba 2 CuO 3.3 and Ba 2 Cu 3 O 5+y . However, annealing at low temperature may produce a fine metastable transition phase. A coherent intermediate

  19. TRANSITIVITY AND THE BA CONSTRUCTION

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    Pei-Jung Kuo

    2010-06-01

    Full Text Available In this paper, I discuss the legitimacy of positing a Transitivity Projection (= TrP cf. Bowers 1993, 1997, 2001 and 2002 in the BA construction in Mandarin Chinese. BA has been proposed to be a semantically-bleached verb, inserted in the v position (Huang 1997 and Lin 2001. Several pieces of evidence such as manner adverbial placement (cf. Huang, Li and Li 2009 and GEI-insertion (cf. Tang 2001 indicate that there must be a functional projection between the vP and VP to host the BA NP. I propose that a TrP is probably the most apt candidate for the XP. I also argue, in contrast to the proposal by Huang, Li and Li (2009, that the present proposal which employs a TrP captures most of the properties of the BA construction. A comparison with the structure of the BEI construction also shows that the TrP proposal fits into the general picture of current linguistic theory on transitive constructions without extra stipulations.

  20. Structural evolution of Ba8Ti3Nb4O24 from BaTiO3 using a series of Ba(Ti1−5xNb4x)O3 solid solutions

    International Nuclear Information System (INIS)

    Barrientos Hernández, F.R.; Lira Hernández, I.A.; Gómez Yáñez, C.; Arenas Flores, A.; Cabrera Sierra, R.; Pérez Labra, M.

    2014-01-01

    Highlights: • The evolution phase Ba 8 Ti 3 Nb 4 O 24 was obtained through the mechanism Ba(Ti 1-5x Nb 4x )O 3 . • Addition of niobium can accelerate grain growth of BaTiO 3 ceramics. • Ba 8 Ti 3 Nb 4 O 24 presents a dielectric loss of 0.0035 and permittivity value of 54.6. • Electrical measurements showed that Nb 5+ content drops Curie temperature. • Samples with x ⩾ 0.0625 shows an insulating behavior. -- Abstract: In this work, the structural evolution of hexagonal phase Ba 8 Ti 3 Nb 4 O 24 by adding Nb 2 O 5 to perovskite structure of BaTiO 3 was investigated. The compositions Ba(Ti 1-5x Nb 4x )O 3 ceramics, with 0.00025 ⩽ x ⩽ 0.125 were prepared by the conventional solid state route in air atmosphere, the powders precursors, BaTiO 3 , BaCO 3 and Nb 2 O 5 , were mixed in stoichiometric proportions and ground in a ball mill using alumina balls and acetone. The mixed powders were calcined at temperatures up to 1500 °C. The phase transformation of Ba 8 Ti 3 Nb 4 O 24 from BaTiO 3 was studied by DRX, Raman spectroscopy, SEM, electrical measurements (relative permittivity and P–E hysteresis loops); Rietveld’s refinement was used to structurally characterize the samples. For the devices obtained capacitance was measured at 1 kHz; with these values we calculated the relative permittivity. The samples show typical P–E hysteresis loops at room temperature accompanied by saturation polarization (Ps) and remnant polarization (Pr). The DRX and Rietveld’s refinement results show x ⩽ 0.01 has a ferroelectric behavior. When the doped level is increased x ⩾ 0.02, a peak displacement is observed, this is due to the phase transformation of tetragonal to cubic into the unit cell. Finally, with x = 0.125 the crystal structure transforms to the characteristic hexagonal phase Ba 8 Ti 3 Nb 4 O 24 which resonates at microwave frequencies

  1. AT THE MARGINS OF ROADS AND JURUÁ’S HISTORY: AN ESSAY ON MBYÁ OCCUPATIONS IN THE GUAÍBA HYDROGRAPHIC AREA (STATE OF RIO GRANDE DO SUL

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    Maria Paula Prates

    2012-12-01

    Full Text Available In this article we seek to systematize historical and ethnographic informations about mbyá presence in the Guaíba hydrographic area (Rio Grande do Sul/Brazil, taking into account the relations between indians and non-indians through the process of territorial configuration of Bacia Platina. This discussion is based on fieldwork, literature and primary sources about three contemporary mbyá occupations -- Petim, Passo Grande and Arroio do Conde.

  2. Host genetic factors in American cutaneous leishmaniasis: a critical appraisal of studies conducted in an endemic area of Brazil

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    Léa Cristina Castellucci

    2014-06-01

    Full Text Available American cutaneous leishmaniasis (ACL is a vector-transmitted infectious disease with an estimated 1.5 million new cases per year. In Brazil, ACL represents a significant public health problem, with approximately 30,000 new reported cases annually, representing an incidence of 18.5 cases per 100,000 inhabitants. Corte de Pedra is in a region endemic for ACL in the state of Bahia (BA, northeastern Brazil, with 500-1,300 patients treated annually. Over the last decade, population and family-based candidate gene studies were conducted in Corte de Pedra, founded on previous knowledge from studies on mice and humans. Notwithstanding limitations related to sample size and power, these studies contribute important genetic biomarkers that identify novel pathways of disease pathogenesis and possible new therapeutic targets. The present paper is a narrative review about ACL immunogenetics in BA, highlighting in particular the interacting roles of the wound healing gene FLI1 with interleukin-6 and genes SMAD2 and SMAD3 of the transforming growth factor beta signalling pathway. This research highlights the need for well-powered genetic and functional studies on Leishmania braziliensis infection as essential to define and validate the role of host genes in determining resistance/susceptibility regarding this disease.

  3. Occurrence and distribution of the Ceratiomyxales (Myxomycetes in northeastern Brazil

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    Laise de Holanda Cavalcanti

    2008-10-01

    Full Text Available Order Ceratiomyxales, which belongs to subclass Ceratiomyxomycetidae, includes the exospore bearing Myxomycetes, solely comprising family Ceratiomyxaceae and genus Ceratiomyxa, with four species. Based on the literature, on herbarium collections, and on recent surveys carried out by the authors in different states and ecosystems, it was possible to determine the occurrence and distribution of C. fruticulosa (cosmopolitan,C. morchella and C. sphaerosperma (predominantly tropical or subtropical in northeastern Brazil. Species descriptions and illustrations are presented, as well as a map of their geographical distribution in eight of the nine states of Northeast Brazil. This order is being recorded for the first time for the state of Sergipe. Ceratiomyxa morchella and C. sphaerosperma are being cited for the first time for the state of Paraíba.A ordem Ceratiomyxales, pertencente à subclasse Ceratiomyxomycetidae, reúne os representantes exosporados dos Myxomycetes, compreendendo apenas a família Ceratiomyxaceae e o gênero Ceratiomyxa, com quatro espécies. Com base na literatura, coleções de herbário e coletas recentes realizadas pelos autores em diferentes estados e ecossistemas, foi possível estabelecer a ocorrência e distribuição na região Nordeste do Brasil de C. fruticulosa, cosmopolita, C. morchella e C. sphaerosperma, predominantemente tropicais ou subtropicais. São apresentadas descrições e ilustrações das espécies, bem como mapa de distribuição geográfica em oito dos nove estados situados no Nordeste do país. A ordem está sendo referida pela primeira vez para o estado de Sergipe. C. morchella e C. sphaerosperma constituem primeira referência para o estado da Paraíba.

  4. Difusão de Inovações Sustentáveis: o caso do biodiesel de mamona no Estado da Paraíba

    Directory of Open Access Journals (Sweden)

    Furlanetto, Egídio Luiz

    2014-05-01

    Full Text Available Comprehension of how an innovation disseminates is a key to understand in which ways companies, as well institutions, may conduct innovative activities. Therefore, this paper aims to evaluate the diffusion process of a technology that applies castor beans to product biodiesel in the State of Paraíba (Brazil, here assumed as a sustainable innovation. For this purpose, and based on a structure of analysis constructed upon theoretical reference, it has been developed a qualitative, explorative and descriptive research, through interviews along with Embrapa Algodão’s researchers and rural producers from the city of Pocinhos, Paraíba. As a result, the research pointed out that the production process of castor beans was strongly supported by the actions of Embrapa’s researchers, by means of technological transference and technical assistance. However, it still requires more incentives from the government and a more comprehensible regulatory policy, a scenario that has hampered greater diffusion of such innovations among the region’s producers.

  5. Separation of Sr from Ca, Ba and Ra by means of Ca(OH)2 and Ba(Ra)Cl2 or Ba(Ra)SO4 for the determination of radiostrontium

    DEFF Research Database (Denmark)

    Chen, Q.J.; Hou, Xiaolin; Yu, Y.X.

    2002-01-01

    be completed. The new separation procedure has been successfully used for the determination of Sr-90 in samples with high Ca content, such as 451 of seawater and 2001 of drinking water. The analytical quality of the results is comparable to that of the traditional method using fuming nitric acid and BaCrO4......A simple procedure is developed to separate Sr from a large amount of Ca, which relies on the insolubility of Ca(OH)(2) in alkaline solution. Calcium is quantitatively separated from Sr and more than 95% of Sr is recovered from a sample with as much as 50 g of Ca and a Ca/Sr mole ratio of 250....... A new procedure for the separation of Sr from Ba and Ra is also investigated, which is based on the difference in solubility of the chlorides of Sr, Ba and Ra in HCl media. In 9.5 mol 1(-1) HCl or 7.5 mol 1(-1) HCl-10% acetone media, >97% of Ba and Ra can be removed by Ba(Ra)Cl-2 precipitation, and >94...

  6. Characterization and dielectric properties of BaTiO3 prepared from Ba(NO3)2-TiO2 mixture

    International Nuclear Information System (INIS)

    Othman, K.I.; Hassan, A.A.; Ali, M.E.; Abdelal, O.A.; Salah El Dien, F.E.; El-Raghy, S.M.; Abdel-Karim, R.

    2012-01-01

    BaTiO 3 powder was prepared through a solid-state reaction between the Ba(NO 3 ) 2 and TiO 2 . The thermal analysis and XRD techniques were used to study its formation. A single phase BaTiO 3 was formed after calcination at 600 degree C for 6 hrs. The dielectric properties of the sintered BaTiO 3 were determined in the temperature range from room temperature to 20 degree C at a frequency ranging from 500 Hz to 100 khz. The relative permittivity and the dielectric loss of the sintered pellets at 1 khz, measured at room temperature,were 1805 and 0.419 respectively.

  7. Synthesis, crystal structure and electrical properties of A-site cation ordered BaErMn2O5 and BaErMn2O6

    International Nuclear Information System (INIS)

    Świerczek, Konrad; Klimkowicz, Alicja; Zheng, Kun; Dabrowski, Bogdan

    2013-01-01

    In this paper, we report on a synthesis procedure, structural and electrical properties of BaErMn 2 O 5 and BaErMn 2 O 6 , A-site double perovskites having layered arrangement of Ba and Er cations. These materials belong to a family of BaLnMn 2 O 5+δ oxides, which up to now were successfully synthesized for Ln=Y and La–Ho lanthanides. Up to our knowledge, this is the first report on the successful synthesis of BaErMn 2 O 5 and BaErMn 2 O 6 , yielding>95 wt% of the considered compounds. Structural characterization of the materials is given at room temperature, together with in situ XRD studies, performed during oxidation of BaErMn 2 O 5 in air, at elevated temperatures up to 500 °C. A complex structural behavior was observed, with oxidation process of BaErMn 2 O 5 occurring at around 300 °C. The oxidized BaErMn 2 O 6 shows a structural phase transition at about 225 °C. Results of structural studies are supported by thermogravimetric measurements of the oxidation process, performed in air, as well as reduction process, preformed in 5 vol% of H 2 in Ar. Additionally, isothermal oxidation/reduction cycles were measured at 500 °C, showing interesting properties of BaErMn 2 O 5+δ , from a point of view of oxygen storage technology. Electrical conductivity of BaErMn 2 O 5 is of the order of 10 −4 S cm −1 at room temperature and shows activated character on temperature with activation energy E a =0.30(1) eV. Positive sign of Seebeck coefficient for this material indicates holes as dominant charge carriers. Oxidized BaErMn 2 O 6 possesses much higher electrical conductivity, almost 0.2 S cm −1 at room temperature. Additional, about 10-fold increase of electrical conductivity, occurring in the vicinity of 225 °C for this material, can be associated with phase transition from charge/orbital-ordered insulator COI(CE) to paramagnetic metal PM phase. The highest conductivity for BaErMn 2 O 6 was measured near 500 °C and is almost equal to 40 S cm −1 , while

  8. Revisiting the BaO2/BaO redox cycle for solar thermochemical energy storage.

    Science.gov (United States)

    Carrillo, A J; Sastre, D; Serrano, D P; Pizarro, P; Coronado, J M

    2016-03-21

    The barium peroxide-based redox cycle was proposed in the late 1970s as a thermochemical energy storage system. Since then, very little attention has been paid to such redox couples. In this paper, we have revisited the use of reduction-oxidation reactions of the BaO2/BaO system for thermochemical heat storage at high temperatures. Using thermogravimetric analysis, reduction and oxidation reactions were studied in order to find the main limitations associated with each process. Furthermore, the system was evaluated through several charge-discharge stages in order to analyse its possible degradation after repeated cycling. Through differential scanning calorimetry the heat stored and released were also determined. Oxidation reaction, which was found to be slower than reduction, was studied in more detail using isothermal tests. It was observed that the rate-controlling step of BaO oxidation follows zero-order kinetics, although at high temperatures a deviation from Arrhenius behaviour was observed probably due to hindrances to anionic oxygen diffusion caused by the formation of an external layer of BaO2. This redox couple was able to withstand several redox cycles without deactivation, showing reaction conversions close to 100% provided that impurities are previously eliminated through thermal pre-treatment, demonstrating the feasibility of this system for solar thermochemical heat storage.

  9. Synthesis and characterization of BaTiO3 ferroelectric material

    International Nuclear Information System (INIS)

    Osman, K.I.

    2011-01-01

    BaTiO 3 powder was prepared at low temperatures using the solid-state reaction, starting with two different precursors; the BaCO 3 /TiO 2 and the Ba(NO 3 ) 2 /TiO 2 powder mixtures. It was found that, a single phase BaTiO 3 was formed after calcination at 750 degree C for 10 h and at 600 degree C for 6 h for the first and second mixtures, respectively. Thermal and XRD analyses were used to study the formation kinetics of BaTiO 3 . Contracting volume reaction model was found to control both reactions. The SEM of the as milled powder, TMA, TG and thermodynamics analysis have been used to propose a realistic approach describing the reaction mechanism of BaTiO 3 . Characterization and the dielectric properties of the sintered BaTiO 3 were investigated. The relative permittivity and the dielectric loss measured at room temperature and at 1 khz were 2028.5 and 0.043 for BaTiO 3 prepared from BaCO 3 /TiO 2 , while they were 1805.33 and 0.41 for BaTiO 3 prepared from Ba(NO 3 ) 2 /TiO 2 .

  10. Experimental investigation of decay properties of neutron deficient $^{116-118}$Ba isotopes and test of $^{112-115}$Ba beam counts

    CERN Multimedia

    We propose to study decay of neutron deficient isotopes $^{116-118}$Ba using Double Sided Silicon Strip Detector (DSSSD). To study delayed-proton and $\\alpha$-decay branching ratios of $^{116-118}$Ba are of special interest because of their vicinity to the proton drip line. The nuclear life-times and properties of the proton unstable states of Cs isotopes, populated through decay of $^{116-118}$Ba isotopes will be measured. In addition to that we propose beam development of $^{112-115}$Ba to study exotic decay properties of these neutron deficient nuclei and to search for super-allowed $\\alpha$-decay in future.

  11. Enhanced 77 K vortex-pinning in Y Ba2Cu3O7−x films with Ba2Y TaO6 and mixed Ba2Y TaO6 + Ba2Y NbO6 nano-columnar inclusions with irreversibility field to 11 T

    Directory of Open Access Journals (Sweden)

    F. Rizzo

    2016-06-01

    Full Text Available Pulsed laser deposited thin Y Ba2Cu3O7−x (YBCO films with pinning additions of 5 at. % Ba2Y TaO6 (BYTO were compared to films with 2.5 at. % Ba2Y TaO6 + 2.5 at. % Ba2Y NbO6 (BYNTO additions. Excellent magnetic flux-pinning at 77 K was obtained with remarkably high irreversibility fields greater than 10 T (YBCO-BYTO and 11 T (YBCO-BYNTO, representing the highest ever achieved values in YBCO films.

  12. (Ba+Sr)/Ti ratio dependence of the dielectric properties for (Ba0.5Sr0.5)TiO3 thin films prepared by ion beam sputtering

    Science.gov (United States)

    Yamamichi, Shintaro; Yabuta, Hisato; Sakuma, Toshiyuki; Miyasaka, Yoichi

    1994-03-01

    (Ba0.5Sr0.5)TiO3 thin films were prepared by ion beam sputtering from powder targets with (Ba+Sr)/Ti ratios ranging from 0.80 to 1.50. All of the perovskite (Ba,Sr)TiO3 films were single phase except for the film with a (Ba+Sr)/Ti ratio of 1.41. The dielectric constant values notably depended on the (Ba+Sr)/Ti ratio for films thicker than 70 nm. The highest dielectric constant of 580 was achieved for the 5% (Ba+Sr) rich film. This (Ba+Sr)/Ti ratio dependence was diminished by the thickness dependence for thinner films. The grain sizes for the 9% (Ba+Sr) rich film and for the 6% (Ba+Sr) poor film ranged from 70 to 100 nm and from 30 to 60 nm, respectively. This grain size difference could explain why slightly A-site rich (Ba,Sr)TiO3 films have a larger dielectric constant than A-site poor films.

  13. Structural and thermodynamic characterization of the perovskite-related BA{sub 1+y}UO{sub 3+x} and (BA,SR){sub 1+y}UO{sub 3+x} phases

    Energy Technology Data Exchange (ETDEWEB)

    Cordfunke, E.H.P. [Netherlands Energy Research Foundation (ECN), Petten (Netherlands); Booij, A.S. [Netherlands Energy Research Foundation (ECN), Petten (Netherlands); Smit-Groen, V. [Netherlands Energy Research Foundation (ECN), Petten (Netherlands); Vlaanderen, P. van [Netherlands Energy Research Foundation (ECN), Petten (Netherlands); IJdo, D.J.W. [Rijksuniversiteit Leiden (Netherlands). Gorlaeus Labs.

    1996-11-01

    The perovskite-type BaUO{sub 3} structure has been investigated by X-ray and neutron diffraction. The Ba/U ratio, the (Ba, Sr)/U ratio, and the oxygen stoichiometry in Ba{sub 1+y}UO{sub 3+x} were varied, and the integral enthalpies of formation determined by solution calorimetry. In addition, equilibrium oxygen partial pressures were measured using a reversible EMF cell. The chemical defect mechanism is discussed, and it is shown that a continuous series BaUO{sub 3}-Ba{sub 1+y}UO{sub 3+x}-Ba{sub 3}UO{sub 6} exist in which uranium vacancies are gradually filled up with barium ions, whereas uranium is oxidized via the pentavalent to the hexavalent state in Ba{sub 3}UO{sub 6}(=Ba{sub 2}(Ba, U)O{sub 6}). (orig.).

  14. Dynamics of photoexcited Ba+ cations in 4He nanodroplets

    International Nuclear Information System (INIS)

    2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain))" data-affiliation=" (Departament ECM, Facultat de Física, and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain))" >Leal, Antonio; 2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain))" data-affiliation=" (Departament ECM, Facultat de Física, and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain))" >Pi, Martí; Zhang, Xiaohang; Drabbels, Marcel; 2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain); Laboratoire des Collisions, Agrégats, Réactivité, IRSAMC, UMR 5589, CNRS et Université Paul Sabatier-Toulouse 3, 118 route de Narbonne, F-31062 Toulouse Cedex 09 (France))" data-affiliation=" (Departament ECM, Facultat de Física, and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain); Laboratoire des Collisions, Agrégats, Réactivité, IRSAMC, UMR 5589, CNRS et Université Paul Sabatier-Toulouse 3, 118 route de Narbonne, F-31062 Toulouse Cedex 09 (France))" >Barranco, Manuel; Cargnoni, Fausto; Hernando, Alberto; Mateo, David; Mella, Massimo

    2016-01-01

    We present a joint experimental and theoretical study on the desolvation of Ba + cations in 4 He nanodroplets excited via the 6p ← 6s transition. The experiments reveal an efficient desolvation process yielding mainly bare Ba + cations and Ba + He n exciplexes with n = 1 and 2. The speed distributions of the ions are well described by Maxwell-Boltzmann distributions with temperatures ranging from 60 to 178 K depending on the excitation frequency and Ba + He n exciplex size. These results have been analyzed by calculations based on a time-dependent density functional description for the helium droplet combined with classical dynamics for the Ba + . In agreement with experiment, the calculations reveal the dynamical formation of exciplexes following excitation of the Ba + cation. In contrast to experimental observation, the calculations do not reveal desolvation of excited Ba + cations or exciplexes, even when relaxation pathways to lower lying states are included.

  15. Comunidade microbiana e mesofauna edáficas em solo sob caatinga no semi-árido da Paraíba Soil microbial community and mesofauna under dry forest vegetation in the semi-arid region of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Patrícia Carneiro Souto

    2008-02-01

    Full Text Available A atividade biológica do solo é responsável por inúmeras transformações físicas e químicas dos resíduos orgânicos que são depositados, mantendo, assim, a sustentabilidade do ambiente. O presente estudo objetivou avaliar a distribuição da comunidade microbiana e da mesofauna edáfica no semi-árido da Paraíba. Para determinação da população de microrganismos, foram coletadas amostras de solo na profundidade de 0-15 cm. A contagem total de fungos e de bactérias foi realizada em meios de cultura específicos. A extração da mesofauna foi feita pelo método de Berlese-Tullgren modificado. Oscilações no conteúdo de água do solo e na temperatura promoveram variações na população microbiana. A população de fungos foi superior à de bactérias nos dois anos de observação, provavelmente devido ao pH do solo da área de estudo, que é ligeiramente ácido. O índice de diversidade de Shannon (H e o de Pielou (e variaram de acordo com a época de coleta. Os grupos mais freqüentes da mesofauna do solo foram Diptera (42,5 %, Acarinae (40,3 % e Collembola (8,8 %, indicando que esses organismos possuem papel importante na ciclagem de nutrientes em área de Caatinga.The biological soil activity is responsible for several physical and chemical transformations of deposited organic residues, therefore maintaining the environmental sustainability. The aim of this study was to evaluate the distribution of the soil microbial community and mesofauna in a dry forest (Caatinga in the semi-arid region of Paraíba, northeastern Brazil. To determine the microorganism population soil samples from the 0-15 cm soil layer were evaluated. Total counts of fungi and bacteria were evaluated in specific culture media. The Berleusse-Tüllgren modified method was used to extract the soil mesofauna. Oscillations in the soil water content and high temperatures promoted variations in the microbial population. The fungi population was larger than that of

  16. The interaction of NO2 with BaO: from cooperative adsorption to Ba(NO3)2 formation

    International Nuclear Information System (INIS)

    Yi, Cheol-Woo W.; Kwak, Ja Hun H.; Szanyi, Janos

    2007-01-01

    The effect of water on the morphology of BaO/Al2O3-based NOx storage materials was investigated using Fourier transform infrared spectroscopy, temperature programmed desorption, and time-resolved synchrotron X-ray diffraction techniques. The results of this multi-spectroscopy study reveal that, in the presence of water, surface Ba-nitrates convert to bulk nitrates, and water facilitates the formation of large Ba(NO3)2 particles. The conversion of surface to bulk Ba-nitrates is completely reversible, i.e. after the removal of water from the storage material a significant fraction of the bulk nitrates re-convert to surface nitrates. NO2 exposure of a H2O-containing (wet) BaO/Al2O3 sample results in the formation of nitrites and bulk nitrates exclusively, i.e. no surface nitrates form. After further exposure to NO2, the nitrites completely convert to bulk nitrates. The amount of NOx taken up by the storage material is, however, essentially unaffected by the presence of water, regardless of whether the water was dosed prior to or after NO2 exposure. Based on the results of this study we are now able to explain most of the observations reported in the literature on the effect of water on NOx uptake on similar storage materials

  17. Fabrication and studies of microstructure and mechanical properties of Ba2MgNbO5,5 ceramics for application in the petroleum industry

    International Nuclear Information System (INIS)

    Oliveira, J.C. da S.; Ferreira, R.A.S.; Yadava, Y.P.

    2011-01-01

    The present work aims at the elaboration of a ceramic complex perovskite ceramic components for temperature sensors for oil wells, as well as the study of microstructural characteristics and mechanical properties of ceramics Ba 2 MgNbO 5,5 . The manufacture of pottery Ba 2 MgNbO 5,5 was performed using a thermo-mechanical and solid-state sintering. The pellets of compressed green were calcined for 24 hours at a temperature of 1200°C and then crushed with the help of a set pistil / agate mortar. The resulting powder was compacted and new pellets were sintered at a temperature of 1250°C. Basic studies of stability of ceramics sintered in the environment of crude oil, from onshore wells and the sea, the state of Sergipe in northeastern Brazil. The test results showed that the ceramic is inert to crude oil and can be used to produce ceramic components for the oil industry. (author)

  18. Growth of BaSi2 continuous films on Ge(111) by molecular beam epitaxy and fabrication of p-BaSi2/n-Ge heterojunction solar cells

    Science.gov (United States)

    Takabe, Ryota; Yachi, Suguru; Tsukahara, Daichi; Toko, Kaoru; Suemasu, Takashi

    2017-05-01

    We grew BaSi2 films on Ge(111) substrates by various growth methods based on molecular beam epitaxy (MBE). First, we attempted to form BaSi2 films directly on Ge(111) by MBE without templates. We next formed BaSi2 films using BaGe2 templates as commonly used for MBE growth of BaSi2 on Si substrates. Contrary to our prediction, the lateral growth of BaSi2 was not promoted by these two methods; BaSi2 formed not into a continuous film but into islands. Although streaky patterns of reflection high-energy electron diffraction were observed inside the growth chamber, no X-ray diffraction lines of BaSi2 were observed in samples taken out from the growth chamber. Such BaSi2 islands were easily to get oxidized. We finally attempted to form a continuous BaSi2 template layer on Ge(111) by solid phase epitaxy, that is, the deposition of amorphous Ba-Si layers onto MBE-grown BaSi2 epitaxial islands, followed by post annealing. We achieved the formation of an approximately 5-nm-thick BaSi2 continuous layer by this method. Using this BaSi2 layer as a template, we succeeded in forming a-axis-oriented 520-nm-thick BaSi2 epitaxial films on Ge substrates, although (111)-oriented Si grains were included in the grown layer. We next formed a B-doped p-BaSi2(20 nm)/n-Ge(111) heterojunction solar cell. A wide-spectrum response from 400 to 2000 nm was achieved. At an external bias voltage of 1 V, the external quantum efficiency reached as high as 60%, demonstrating the great potential of BaSi2/Ge combination. However, the efficiency of a solar cell under AM1.5 illumination was quite low (0.1%). The origin of such a low efficiency was examined.

  19. Metals in soils adjacent to avenues of highly dense traffic of Sao Paulo city, Brazil

    International Nuclear Information System (INIS)

    Ticianelli, Regina B.; Ribeiro, Andreza P.; Figueiredo, Ana M.G.; Nammoura-Neto, Georges M.; Silva, Nathalia C.

    2009-01-01

    Sao Paulo is the largest city in Brazil with about 19 millions of inhabitants in the metropolitan area, more than 8 million motor vehicles and strong industrial activity at the metropolitan region, which are responsible for increasing pollution in the region. Nevertheless, there is little information on metal contents in the metropolitan region soils, which would be very useful as a fingerprint of the environmental pollution. The present study aimed to determine As, Ba, Co, Cr, Sb and Zn concentrations in soils adjacent to avenues of highly dense traffic downtown Sao Paulo city: Consolacao/Reboucas Avenues; 23 de Maio Avenue and Tiradentes Avenue, to assess their possible sources and potential environmental impact. The analytical technique employed was Instrumental Neutron Activation Analysis (INAA). The results show metal concentration levels higher than the values reference values for soils of Sao Paulo, according to the Environmental Protection Agency of the State Sao Paulo (CETESB) guidelines. As, Ba and Zn showed concentration levels above the Intervention Values in some points, indicating direct or indirect potential risks to human health. The traffic related element Ba, Sb and Zn presented concentrations above the Prevention Values in points with high density traffic and may be associated to vehicular emissions. (author)

  20. Building a Uranium Heap Leach Project

    International Nuclear Information System (INIS)

    Schnell, Henry

    2014-01-01

    Despite all these we have seen many HL successes and many interesting projects coming down the pipe. • Previous experience in Uranium with previous ROM projects in France (Bessines, Langone), Niger (Somair), Canada (Agnew Lake) and other locations had provided some basic background. • Heap leach based on copper experience with crushed ore has operated for many years in Brazil (Caetite). • Many gold operations for many decades in all climates and continents. • Copper at +20% of production, many in Chile, but also now in many other countries. • Uranium with agglomerated crushed ores is now becoming more prominent – Somair, Imouraren, Trekkopje. • Work also ongoing for Ranger, Rossing, and in consideration for other projects. • Other notable work in Nickel, and multi-metal such as Talvivaara

  1. Laserspectroscopic studies of collective properties of neutron deficient Ba nuclei

    International Nuclear Information System (INIS)

    Bekk, K.; Andl, A.; Goering, S.; Hanser, A.; Nowicki, G.; Rebel, H.; Schatz, G.

    1979-01-01

    Isotope shifts and hyperfine structure of the BaI resonance-line (lambda=553.6 nm) have been measured by dye laser induced resonance fluorescence on an atomic beam for sup(135m,129g,129m,126) Ba thus extending previous high resolution measurements of neutron deficient Ba nuclides (N - isomers sup(135m) Ba and sup(135m) Ba show a decreased staggering. Conspicuously the isomer shift of the g 7/2 + isomer sup(129m) Ba proves to be negative. The nuclear structure information is discussed in the context of gamma-spectroscopic studies of transitional nuclei with 50 [de

  2. [Ill-defined causes of death and unattended deaths, Brazil, 2003].

    Science.gov (United States)

    Santo, Augusto Hasiak

    2008-01-01

    We studied the distribution of deaths from ill-defined causes that occurred in Brazil during 2003, from which was identified the proportion of unattended deaths. Data were obtained from the Mortality Information System, coordinated by the Ministry of Health. Causes of death included in "Chapter XVIII - Symptoms, signs and abnormal clinical and laboratory findings, not classified elsewhere" of the International Statistical Classification of Diseases and Related Health Problems, tenth revision, were considered ill-defined, among which the category R98 identified "unattended deaths". In Brazil during 2003 the underlying causes of 13.3% of deaths were included in the Chapter of ill-defined causes, and the highest proportions of these deaths occurred in the Northeast and North Regions. Considering the total deaths from ill-defined causes, 53 % correspond to unattended deaths. This proportion increased to over 70% in the states of Maranhão, Piauí, Rio Grande do Norte, Pernambuco, Bahia, Paraíba and Alagoas. Due to the decentralized structure of data collection in the country, we believe that the municipalities bear the major responsibility, followed by the states, for upgrading the quality of mortality statistics.

  3. Decrease in electrical contact resistance of Sb-doped n+-BaSi2 layers and spectral response of an Sb-doped n+-BaSi2/undoped BaSi2 structure for solar cells

    Science.gov (United States)

    Kodama, Komomo; Takabe, Ryota; Yachi, Suguru; Toko, Kaoru; Suemasu, Takashi

    2018-03-01

    We investigated how the electron concentration n in a 300-nm-thick Sb-doped n+-BaSi2 layer grown by molecular beam epitaxy affected the contact resistance R C to surface electrodes (Al, indium-tin-oxide). As the n of n-BaSi2 increased, R C decreased and reached a minimum of 0.019 Ω cm2 at n = 2.4 × 1018 cm-3 for the Al electrodes. This value was more than 1 order of magnitude smaller than that obtained for Al/B-doped p-BaSi2. We believe that this significant decrease in R C came from Sb segregation. Furthermore, the internal quantum efficiency (IQE) spectrum was evaluated for an Sb-doped n+-BaSi2 (20 nm)/undoped BaSi2 (500 nm)/n+-Si(111) structure. Its IQE reached as high as ˜50% over a wide wavelength range under a small bias voltage of 0.1 V applied between the top and bottom electrodes.

  4. [Occurrence of Achatina fulica in the Vale do Paraíba, Rio de Janeiro state, Brazil].

    Science.gov (United States)

    Vasconcellos, M C; Pile, E

    2001-12-01

    The first occurrence of the Achatina fulica, an intermediate host of Angiostrongylus cantonensis, the etiological agent of meningoencephalic angiostrongiliasis, is reported in Resende municipality, Brazil. In the five visited localities, snails were found living freely, and the larvae of this parasite was not seen in any of them. The finding of A. fulica in the area may be related to its commercialization as a food item and embodies the possibility of new focus.

  5. Phase relationships in the BaO-Ga2O3-Ta2O5 system and the structure of Ba6Ga21TaO40.

    Science.gov (United States)

    Cao, Jiang; Yu, Xiaodi; Kuang, Xiaojun; Su, Qiang

    2012-07-16

    Phase relationships in the BaO-Ga(2)O(3)-Ta(2)O(5) ternary system at 1200 °C were determined. The A(6)B(10)O(30) tetragonal tungsten bronze (TTB) related solution in the BaO-Ta(2)O(5) subsystem dissolved up to ~11 mol % Ga(2)O(3), forming a ternary trapezoid-shaped TTB-related solid solution region defined by the BaTa(2)O(6), Ba(1.1)Ta(5)O(13.6), Ba(1.58)Ga(0.92)Ta(4.08)O(13.16), and Ba(6)GaTa(9)O(30) compositions in the BaO-Ga(2)O(3)-Ta(2)O(5) system. Two ternary phases Ba(6)Ga(21)TaO(40) and eight-layer twinned hexagonal perovskite solid solution Ba(8)Ga(4-x)Ta(4+0.6x)O(24) were confirmed in the BaO-Ga(2)O(3)-Ta(2)O(5) system. Ba(6)Ga(21)TaO(40) crystallized in a monoclinic cell of a = 15.9130(2) Å, b = 11.7309(1) Å, c = 5.13593(6) Å, β = 107.7893(9)°, and Z = 1 in space group C2/m. The structure of Ba(6)Ga(21)TaO(40) was solved by the charge flipping method, and it represents a three-dimensional (3D) mixed GaO(4) tetrahedral and GaO(6)/TaO(6) octahedral framework, forming mixed 1D 5/6-fold tunnels that accommodate the Ba cations along the c axis. The electrical property of Ba(6)Ga(21)TaO(40) was characterized by using ac impedance spectroscopy.

  6. First occurrence of the crab Calappa nitida Holthuis, 1958 (Brachyura, Calappidae, Calappinae on the coast of the state of Piauí, Brazil

    Directory of Open Access Journals (Sweden)

    Lissandra Corrêa Fernandes-Góes

    2007-03-01

    Full Text Available The present study reports a female of Calappa nitida found at a water-pump station on a shrimp farm, in a mangrove located in Cajueiro da Praia, state of Piauí, within the Parnaíba River Delta Environmental Preservation Area. Although C. nitida occurs in northern and northeastern Brazil, this first record from Piauí fills one of the gaps in its known range.

  7. Ruthenium perovskites of type Ba/sub 2/BRuO/sub 6/ and Ba/sub 3/BRu/sub 2/O/sub 9/ with B = indium, rhodium

    Energy Technology Data Exchange (ETDEWEB)

    Schaller, H U; Kemmler-Sack, S [Tuebingen Univ. (Germany, F.R.). Lehrstuhl fuer Anorganische Chemie 2

    1981-02-01

    The black perovskites Ba/sub 2/InRu/sup 5 +/O/sub 6/ and Ba/sub 3/InRu/sub 2/O/sub 9/ (mean oxydation state of ruthenium: +4.5) adopt the hexagonal BaTiO/sub 3/ structure and form a continuous series of mixed crystals. According to the intensity calculations and analysis of the vibrational spectroscopic data an ordered distribution between indium and ruthenium is present: 1:1 order in Ba/sub 2/RuO/sub 6/ (space group P-3m1 respective Dsub(3d)/sup 3/; R' = 5.3%); 1:2 order in Ba/sub 3/InRu/sub 2/O/sub 9/ (space group P6/sub 3//mmc respective Dsub(6h)/sup 4/; R' = 4.6%). The corresponding black Rh compounds, Ba/sub 2/RhRuO/sub 6/ and Ba/sub 3/RhRu/sub 2/O/sub 9/, crystallize in the rhombohedral 9 L type of BaRuO/sub 3/ (author).

  8. Scintillation and radiation damage of doped BaF2 crystals

    International Nuclear Information System (INIS)

    Gong Zufang; Xu Zizong; Chang Jin

    1992-01-01

    The emission spectra and the radiation damage of BaF 2 crystals doped Ce and Dy have been studied. The results indicate that the doped BaF 2 crystals have the intrinsic spectra of impurity besides the intrinsic spectra of BaF 2 crystals. The crystals colored and the transmissions decrease with the concentration of impurity in BaF 2 crystals after radiation by γ-ray of 60 Co. The doped Ce BaF 2 irradiated by ultraviolet has faster recover of transmissions but for doped Dy the effect is not obvious. The radiation resistance is not good as pure BaF 2 crystals

  9. Fishers' knowledge and seahorse conservation in Brazil.

    Science.gov (United States)

    Rosa, Ierecê Ml; Alves, Rômulo Rn; Bonifácio, Kallyne M; Mourão, José S; Osório, Frederico M; Oliveira, Tacyana Pr; Nottingham, Mara C

    2005-12-08

    From a conservationist perspective, seahorses are threatened fishes. Concomitantly, from a socioeconomic perspective, they represent a source of income to many fishing communities in developing countries. An integration between these two views requires, among other things, the recognition that seahorse fishers have knowledge and abilities that can assist the implementation of conservation strategies and of management plans for seahorses and their habitats. This paper documents the knowledge held by Brazilian fishers on the biology and ecology of the longsnout seahorse Hippocampus reidi. Its aims were to explore collaborative approaches to seahorse conservation and management in Brazil; to assess fishers' perception of seahorse biology and ecology, in the context evaluating potential management options; to increase fishers' involvement with seahorse conservation in Brazil. Data were obtained through questionnaires and interviews made during field surveys conducted in fishing villages located in the States of Piauí, Ceará, Paraíba, Maranhão, Pernambuco and Pará. We consider the following aspects as positive for the conservation of seahorses and their habitats in Brazil: fishers were willing to dialogue with researchers; although captures and/or trade of brooding seahorses occurred, most interviewees recognized the importance of reproduction to the maintenance of seahorses in the wild (and therefore of their source of income), and expressed concern over population declines; fishers associated the presence of a ventral pouch with reproduction in seahorses (regardless of them knowing which sex bears the pouch), and this may facilitate the construction of collaborative management options designed to eliminate captures of brooding specimens; fishers recognized microhabitats of importance to the maintenance of seahorse wild populations; fishers who kept seahorses in captivity tended to recognize the condtions as poor, and as being a cause of seahorse mortality.

  10. Fishers' knowledge and seahorse conservation in Brazil

    Directory of Open Access Journals (Sweden)

    Oliveira Tacyana PR

    2005-12-01

    Full Text Available Abstract From a conservationist perspective, seahorses are threatened fishes. Concomitantly, from a socioeconomic perspective, they represent a source of income to many fishing communities in developing countries. An integration between these two views requires, among other things, the recognition that seahorse fishers have knowledge and abilities that can assist the implementation of conservation strategies and of management plans for seahorses and their habitats. This paper documents the knowledge held by Brazilian fishers on the biology and ecology of the longsnout seahorse Hippocampus reidi. Its aims were to explore collaborative approaches to seahorse conservation and management in Brazil; to assess fishers' perception of seahorse biology and ecology, in the context evaluating potential management options; to increase fishers' involvement with seahorse conservation in Brazil. Data were obtained through questionnaires and interviews made during field surveys conducted in fishing villages located in the States of Piauí, Ceará, Paraíba, Maranhão, Pernambuco and Pará. We consider the following aspects as positive for the conservation of seahorses and their habitats in Brazil: fishers were willing to dialogue with researchers; although captures and/or trade of brooding seahorses occurred, most interviewees recognized the importance of reproduction to the maintenance of seahorses in the wild (and therefore of their source of income, and expressed concern over population declines; fishers associated the presence of a ventral pouch with reproduction in seahorses (regardless of them knowing which sex bears the pouch, and this may facilitate the construction of collaborative management options designed to eliminate captures of brooding specimens; fishers recognized microhabitats of importance to the maintenance of seahorse wild populations; fishers who kept seahorses in captivity tended to recognize the condtions as poor, and as being a cause of

  11. Chemiluminescence from the reaction of Ba 3D with nitric oxide

    International Nuclear Information System (INIS)

    Johnson, S.A.; Solarz, R.W.; Dubrin, J.W.; Brotzmann, R.

    1977-01-01

    The reaction of laser excited Ba*( 3 D) states with nitric oxide is presented. BaO product is not detected, although the channel is thermodynamically open, and instead chemiluminescence is observed. Experiments which suggest that radiative recombination, Ba + NO → BaNO* → BaNO, is the observed reaction channel will also be presented

  12. Rates of pulmonary infection by pentastomids in lizards species from a restinga habitat in northeastern Brazil.

    Science.gov (United States)

    Almeida, W O; Santana, G G; Vieira, W L S; Wanderley, I C; Ribeiro, S C

    2009-02-01

    Pulmonary parasitism by pentastomids was examined in two lizard species inhabiting an area of restinga vegetation (coastal sand dunes) situated in the municipality of Mataraca (6 degrees 29' S and 34 degrees 56' W), on the extreme northern coast of Paraíba State, Brazil. A total of 123 lizards were collected, being 75 specimens of Micrablepharus maximiliani (Gymnophtalmidae) and 48 specimens of Cnemidophorus ocellifer (Teiidae). Only a single species of Pentastomida (Raillietiella mottae) was found parasitizing three females M. maximiliani, with a prevalence of 4% and an average infection intensity of 2.3 +/- 1.3 (range 1-5). The infection rate by pentastomids encountered in the present study was similar to that seen with other species of restinga lizards. Raillietiella mottae is a generalist parasite species that is probably transmitted by common and widely distributed insects making up part of the diet of many insectivorous lizard species from northeastern Brazil.

  13. Thermoelectric properties of doped BaHfO_3

    International Nuclear Information System (INIS)

    Dixit, Chandra Kr.; Bhamu, K. C.; Sharma, Ramesh

    2016-01-01

    We have studied the structural stability, electronic structure, optical properties and thermoelectric properties of doped BaHfO_3 by full potential linearized augmented plane wave (FP-LAPW) method. The electronic structure of BaHfO_3 doped with Sr shows enhances the indirect band gaps of 3.53 eV, 3.58 eV. The charge density plots show strong ionic bonding in Ba-Hf, and ionic and covalent bonding between Hf and O. Calculations of the optical spectra, viz., the dielectric function, refractive index and extinction coefficient are performed for the energy range are calculated and analyzed. Thermoelectric properties of semi conducting are also reported first time. The doped BaHfO_3 is approximately wide band gap semiconductor with the large p-type Seebeck coefficient. The power factor of BaHfO_3 is increased with Sr doping, decreases because of low electrical resistivity and thermal conductivity.

  14. Crystal structure of a new natural (Ba, Nb) silicate

    International Nuclear Information System (INIS)

    Yamnova, N.A.; Pushcharovskii, D.Yu.; Voloshin, A.V.

    1990-01-01

    The structure of a new mineral Ba 3 (Ti 1.2 Nb 4.8 ) Si 4 O 25.4 is determined (166 reflections, method of least squares in anisotropic approximation, R = 0.040). The crystallographic parameters are: a = 9.03(1), c = 7.868(6) angstrom, Z = 1, space group P anti 62m. Like the previously investigated synthetic analogs Ba 3 Si 4 Nb 6 O 26 , Ba 3 Si 4 Ti 6 O 23 , and Ba 3 Si 4 Ta 6 O 26 , the structure contains a mixed framework of octahedral columns of triangular section, bound to the diortho groups [Si 2 O 7 ], of which the cavities contain the Ba atoms

  15. AHP 45: REVIEW: PHYUR BA

    Directory of Open Access Journals (Sweden)

    'Brug mo skyid འབྲུག་མོ་སྐྱིད། (Zhoumaoji 周毛吉

    2017-03-01

    Full Text Available Mkha' mo rgyal was born in Dgon gong ma Village, 'Ba' (Tongde County, Mtsho lho (Hainan Tibetan Autonomous Prefecture, Mtsho sngon (Qinghai Province. While attending the Tibetan Studies College of Mtsho sngon Nationalities University she began writing. In addition to editing and translating teaching materials for primary and secondary schools, she has also published short stories and poetry (Mkha' mo rgyal, 2015. Phyur ba is the first Tibetan women's novel (Robin 2016:86 and was recognized as an Outstanding Work by the Qinghai Writers Guild in 2014 (Duojiecairang and Limaoyou 2014. 1 The name, which translates as 'dried cheese' is a food eaten daily by many Tibetans. Made from fermented milk without cream, it is dried in the sun by women in pastoral areas. Both sweet and sour, phyur ba brings to mind the happiness and sadness, ups and downs, laughter and tears that life brings. ...

  16. Fluid inclusion study of the Cachoeira uranium deposit, Caetite, state of Bahia, Brazil

    International Nuclear Information System (INIS)

    Alves, J.V.; Fuzikawa, K.

    1984-01-01

    The Cachoeira uranium deposit is presently the richest deposit among those in the Lagoa Real Uranium Province. The mineralization is associated to the albitites formed during the onset of strong sodium metasomatism on the granite-gnaissic rocks of the area. Fluid inclusion study of several uraniferous albitites indicated the presence of strong brines (approx. 20 weight percent NaCl equivalent) and the dominance of hydrocarbons over CO 2 in the gas phase. In country rocks, which host the albitites, as well as in unmineralized albities the salinity of aqueous solution is variable and light hydrocarbons are the predominant gas phase. These data were obtained by microthermometry and crushing tests from a larger set of samples than that used in previous studies. However, the results do not differ significantly from the data of these earlier works and reinforce the hypothesis of the importance of CH 4 in Uo 2 precipitation. (Author) [pt

  17. Environmental monitoring of the Uranium Concentrate Unity (URA) at Caetite - Bahia State - Brazil

    International Nuclear Information System (INIS)

    Pereira, Wagner de Souza; Py Junior, Delcy de Azevedo

    2002-01-01

    The pre operational monitoring program has been executed in order to set a baseline, on which comparisons with the same points and the same radionuclides will be made after beginning of operation, having the objective of environmental impact evaluation, in the vicinity of the installation. The program was held in the period of 1982 to 1999, collecting non biological environmental samples (aerosol, rain water, surface water, underground water soil and sediment) and samples that are related to the human food chain (manioc, manioc flour, milk, browse, fish, been, corn, cactus and silage). The analyzed radionuclides are natural uranium, natural thorium, Ra-226, Ra-228, Rn-222 and Pb-210. This work intends to analyze data from the last ten years, program (1989 - 1999), analyzing approximately 350 biological samples and 3500 non biological samples, in order to establishing the baseline to be used in future studies of environmental impact. (author)

  18. High-pressure BaCrO_3 polytypes and the 5H–BaCrO_2_._8 phase

    International Nuclear Information System (INIS)

    Arévalo-López, Angel M.; Paul Attfield, J.

    2015-01-01

    Polytypism of BaCrO_3 perovskites has been investigated at 900–1100 °C and pressures up to 22 GPa. Hexagonal 5H, 4H, and 6H perovskites are observed with increasing pressure, and the cubic 3C perovskite (a=3.99503(1) Å) is observed in bulk form for the first time at 19–22 GPa. An oxygen-deficient material with limiting composition 5H–BaCrO_2_._8 is synthesised at 1200 °C under ambient pressure. This contains double tetrahedral Cr"4"+ layers and orders antiferromagnetically below 260 K with a (0 0 1/2) magnetic structure. - Graphical abstract: Hexagonal 5H, 4H, and 6H perovskites polytypes of BaCrO_3 are observed with increasing pressure and the cubic 3C perovskite is stabilised in bulk form for the first time at 19–22 GPa. Oxygen-deficient 5H–BaCrO_2_._8 synthesised at ambient pressure contains double tetrahedral Cr"4"+ layers and orders antiferromagnetically below 260 K with a (0 0 1/2) magnetic structure.

  19. Occurrence of anti-Brucella abortus and anti-Leptospira spp. antibodies in buffaloes from Paraíba state, Northeastern Brazil

    Directory of Open Access Journals (Sweden)

    Arthur Willian de Lima Brasil

    2015-07-01

    Full Text Available The objective of this study was to determine the frequency of animals that tested positive for brucellosis and leptospirosis and the risk factors for these diseases in the State of Paraíba. A total of 136 buffaloes from 14 herds were examined. For brucellosis, we used the buffered acidified plate antigen (BAPA test as screening method and 2-mercaptoethanol as confirmatory test. For leptospirosis, we conducted a microscopic agglutination test (MAT, with a cut-off point of 1:100. Of the animals examined, two [1.5%; 95% CI = 0.4%–5.2%] were positive for brucellosis, and 38 (27.9%; 95% CI = 21.1%–36.0% were positive for leptospirosis. The brucellosis-positive animals were from two (14.3% herds, while nine (64.3% herds had leptospirosis-seropositive animals. The more frequent Leptospira spp. serotypes were Bratislava, Pomona, and Canicola. We concluded that leptospirosis was widespread in buffaloes in the state of Paraíba and suggested that breeding alongside horses and pigs might be na important factor in the spread of leptospirosis-positive animals. The presence of brucellosispositive animals indicated the possibility of negative-impacting measures on disease control in bovines, and it is therefore recommended that greater attention be given to these animals for brucellosis control.

  20. Biodistribution and Radiation Dosimetry of the Integrin Marker 64Cu-BaBaSar-RGD2 Determined from Whole-Body PET/CT in a Non-Human Primate

    Science.gov (United States)

    Liu, Shuanglong; Vorobyova, Ivetta; Park, Ryan; Conti, Peter S.

    2017-10-01

    Introduction: 64Cu-BaBaSar-RGD2 is a positron emission radiotracer taken up by integrin αvβ3, which is overexpressed in many malignancies. The aim of this study was to evaluate the biodistribution of 64Cu-BaBaSar-RGD2 in a non-human primate with positron emission tomography and to estimate the absorbed doses in major organs for human. Materials and methods: Whole-body PET imaging was done in a Siemens Biograph scanner in a male macaque monkey. After an i.v. injection of 13.1–19.7 MBq/kg of 64Cu-BaBaSar-RGD2, whole body scan was collected for a total duration of 180 min. Attenuation and scatter corrections were applied to reconstruction of the whole-body emission scan. After image reconstruction, three-dimensional volumes of interest (VOI) were hand-drawn on the PET transaxial or coronal slices of the frame where the organ was most conspicuous. Time-activity curves for each VOI were obtained, and residence time of each organ was calculated by integration of the time-activity curves. Human absorbed doses were estimated using the standard human model in OLINDA/EXM software. Results: Injection of 64Cu-BaBaSar-RGD2 was well tolerated in the macaque monkey, with no serious tracer-related adverse events observed. 64Cu-BaBaSar-RGD2 was cleared rapidly from the blood pool, with a 12.1-min biological half-time. Increased 64Cu-BaBaSar-RGD2 uptake was observed in the kidneys, and bladder, with mean percentage injected dose (ID%) values at 1 h after injection approximately 35.50 ± 6.47 and 36.89 ± 5.48, respectively. The calculated effective dose was 15.30 ± 2.21 µSv/MBq, and the kidneys had the highest absorbed dose at 108.43 ± 16.41 µGy/MBq using the non-voiding model. For an injected activity of 925 MBq 64Cu for human, the effective dose would be 14.2 ± 2.1 mSv. Discussion: Due to the limitation of the monkey number, we evaluated 64Cu-BaBaSar-RGD2 in the same monkey of three imaging sessions. Measured absorbed doses and effective doses of 64Cu-BaBaSar-RGD2 are

  1. An approach to WWER fuels with BaCo

    International Nuclear Information System (INIS)

    Marino, A.; Demarco, G.

    2008-01-01

    BaCo is a code for the simulation of the behaviour of a nuclear fuel rod under operation conditions. BaCo, a quasi 2D code based on a finite differences scheme, has been used for simulating PHWR, CANDU, PWR, BWR, MOX, WWER, and experimental fuel rods. We improve the performance of BaCo with a set of tools based on the method of finite elements for 3D analysis of the stress-strain state. We can simulate any UO 2 pellet geometry. Standard WWER-440 fuel assemblies irradiated in the Kola-3 reactor of the CRP FUMEX II of the IAEA were the first WWER simulations with BaCo. We find a very good agreement among our calculations, the experimental results and other qualified fuel codes. We present the BaCo code and our results for PWR and WWER fuels of the CRP FUMEX II, the 3D analysis of WWER fuel pellet and the projections of these results with the Argentinean nuclear fuels development. (authors)

  2. Isolation of Bacillus thuringiensis from the state of Amazonas, in Brazil, and screening against Aedes aegypti (Diptera, Culicidae

    Directory of Open Access Journals (Sweden)

    Joelma Soares-da-Silva

    2015-03-01

    Full Text Available We investigated the use of Bacillus thuringiensis isolated in the state of Amazonas, in Brazil, for the biological control of the dengue vector Aedes aegypti. From 25 soil samples collected in nine municipalities, 484 bacterial colonies were obtained, 57 (11.78% of which were identified as B. thuringiensis. Six isolates, IBt-03, IBt-06, IBt-07, IBt-28, IBt-30, and BtAM-27 showed insecticidal activity, and only BtAM-27 presents the five genes investigated cry4Aa, cry4Ba, cry10Aa, cry11Aa, and cry11Ba. The IBt-07 and IBt- 28, with lower LC50 values, showed equal toxicity compared to the standards. The isolates of B. thuringiensis from Amazonas constitute potential new means of biological control for A. aegypti, because of their larvicidal activity and the possibility that they may also contain new combinations of toxins.

  3. Three new chalcohalides, Ba4Ge2PbS8Br2, Ba4Ge2PbSe8Br2 and Ba4Ge2SnS8Br2: Syntheses, crystal structures, band gaps, and electronic structures

    International Nuclear Information System (INIS)

    Lin, Zuohong; Feng, Kai; Tu, Heng; Kang, Lei; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng

    2014-01-01

    Highlights: • Three new chalcohalides: Ba 4 Ge 2 PbS 8 Br 2 , Ba 4 Ge 2 PbSe 8 Br 2 and Ba 4 Ge 2 SnS 8 Br 2 have been synthesized. • The MQ 5 Br octahedra and GeQ 4 tetrahedra form a three-dimensional framework with Ba 2+ in the channels. • Band Gaps and electronic structures of the three compounds were studied. - Abstract: Single crystals of three new chalcohalides: Ba 4 Ge 2 PbS 8 Br 2 , Ba 4 Ge 2 PbSe 8 Br 2 and Ba 4 Ge 2 SnS 8 Br 2 have been synthesized for the first time. These isostructural compounds crystallize in the orthorhombic space group Pnma. In the structure, the tetra-valent Ge atom is tetrahedrally coordinated with four Q (Q = S, Se) atoms, while the bi-valent M atom (M = Pb, Sn) is coordinated with an obviously distorted octahedron of five Q (Q = S, Se) atoms and one Br atom, showing the stereochemical activity of the ns 2 lone pair electron. The MQ 5 Br (M = Sn, Pb; Q = S, Se) distorted octahedra and the GeQ 4 (Q = S, Se) tetrahedra are connected to each other to form a three-dimensional framework with channels occupied by Ba 2+ cations. Based on UV–vis–NIR spectroscopy measurements and the electronic structure calculations, Ba 4 Ge 2 PbS 8 Br 2 , Ba 4 Ge 2 PbSe 8 Br 2 and Ba 4 Ge 2 SnS 8 Br 2 have indirect band gaps of 2.054, 1.952, and 2.066 eV respectively, which are mainly determined by the orbitals from the Ge, M and Q atoms (M = Pb, Sn; Q = S, Se)

  4. Intermetallic and metal-rich phases in the system Li-Ba-In-N

    International Nuclear Information System (INIS)

    Smetana, Volodymyr; Vajenine, Grigori V.; Kienle, Lorenz; Duppel, Viola; Simon, Arndt

    2010-01-01

    Three new intermetallic phases, BaLi 2.1 In 1.9 , BaLi 1.12 In 0.98 , and BaLi 1.06 In 1.16 and two subnitrides Li 35 In 45 Ba 39 N 9 and LiIn 2 Ba 3 N 0.83 have been synthesized and their crystal structures have been determined. According to single crystal X-ray diffraction data BaLi 2.1 In 1.9 and BaLi 1.12 In 0.98 crystallize with hexagonal symmetry (BaLi 2.1 In 1.9 : P6 3 /mmc, a=10.410(2), c=8.364(2) A, Z=6, V=785.0(2) A 3 ) and BaLi 1.12 In 0.98 : P6/mmm, a=17.469(1), c=10.6409(7) A, Z=30, V=2813.5(8) A 3 ), while BaLi 1.06 In 1.16 has a rhombohedral structure (R-3c, a=18.894(3), c=85.289(17) A, Z=276, V=26368(8) A 3 ). BaLi 2.1 In 1.9 is isostructural with the known phase BaLi 4 . The phase BaLi 1.12 In 0.98 is structurally related to Na 8 K 23 Cd 12 In 48 , while BaLi 1.06 In 1.16 is isostructural with Li 33.3 Ba 13.1 Ca 3 . A sample containing structurally similar BaLi 1.12 In 0.98 and BaLi 1.02 In 1.16 was also investigated by transmission electron microscopy. Li 35 In 45 Ba 39 N 9 and LiIn 2 Ba 3 N 0.83 crystallize with tetragonal (I-42m, a=15.299(2), c=30.682(6) A, Z=2, V=7182(2) A 3 ) and cubic (Fd-3m, a=14.913(2) A, Z=8, V=3316.7(7) A 3 ) symmetry, respectively. While the first-mentioned subnitride belongs to the Li 80 Ba 39 N 9 structure type, the second extends the structural family of Ba 6 In 4.78 N 2.72 . The structural features of the new compounds are discussed in comparison to the known phases and the results of total energy calculations. - Graphical abstract: One-dimensional chain of face-sharing centered icosahedra in BaLi 2.1 In 1.9

  5. Wet routes of high purity BaTiO3 nanopowders

    International Nuclear Information System (INIS)

    Wang Liqiu; Liu Liang; Xue Dongfeng; Kang Hongmin; Liu Changhou

    2007-01-01

    High purity BaTiO 3 nanopowders were prepared in wet routes through stearic acid gel (SAG) and acetic acid gel (AAG) techniques, respectively. BaTiO 3 samples were characterized by X-ray diffraction, transmission electron microscope, Fourier transform infrared spectrometry, X-ray fluorescence spectrometry, and thermal gravimetric analysis. The present results indicate that both methods have a similar reaction process during calcination, while BaTiO 3 crystallites were initially formed at 550 deg. C by SAG and 800 deg. C by AAG. Both methods could produce BaTiO 3 powders with a cubic perovskite structure, while they had different grain size distributions within 25-50 nm for SAG and 50-80 nm for AAG. BaTiO 3 samples prepared by SAG had a lower agglomeration than those by AAG. SAG has shown many distinctive advantages in the preparation of high purity BaTiO 3 nanopowders, without Ba and Ti losses and hazardous wastes

  6. Ferroelectric relaxor Ba(TiCe)O3

    International Nuclear Information System (INIS)

    Chen Ang; Zhi Jing; Yu Zhi

    2002-01-01

    The dielectric behaviour of Ba(Ti 1-y Ce y )O 3 solid solutions (y=0-0.3) has been studied. A small amount of Ce doping (y=0.02) has weak influence on the dielectric behaviour of Ba(Ti 1-y Ce y )O 3 . With increasing Ce concentration, three phase transitions of pure BaTiO 3 are pinched into one rounded dielectric peak with frequency dispersion, and the relaxation time follows the Vogel-Fulcher relation. The evolution from a normal ferroelectric to a ferroelectric relaxor is emphasized. High strains (S=∼0.1-0.19%) with a small hysteresis under ac fields are obtained in ferroelectric relaxors Ba(Ti 1-y Ce y )O 3 . The physical mechanism of the relaxation process, the pinching effect of the phase transitions and their influence on the ferroelectric and electrostrictive behaviour are discussed. (author)

  7. Metaplasia mieloide do baço na Ancilostomose

    Directory of Open Access Journals (Sweden)

    W. O. Cruz

    1934-06-01

    Full Text Available Pesquizamos, no figado e baço de dez casos puros de ancilostomose, elementos hemocitopoieticos; verificamos o peso do baço em 23 casos de individuos com idades compreendidas entre 3 e 60 anos; não encontramos, em nenhum caso, celulas hemoformadoras no figado. Em sete casos, encontramos, no baço, elementos da série vermelha em adiantado estado de evolução (eritroblastos ortocromaticos de nucleo picnotico. Em alguns destes casos observamos megacariocitos e numerosos mielocitos eosinofilos. Os tres casos que não apresentavam metaplasia mieloide no baço, eram os de individuos acima de 50 anos de idade. Entretanto, em outro caso de um individuo com 59 anos esta metaplasia foi verificada. Em individuos acima de 20 anos, o peso médio do baço, em nove casos, mostrou-se igual ao peso normal. Em 14 casos, compreendidos entre 3 e 14 anos, o peso deste orgão foi sempre sensivelmente mais elevado que nos normais de idade correspondente. Estes resultados sugerem a possibilidade de ser a metaplasia mieloide responsavel pelos aumentos de pezo nos baços de individuos jovens, vitimados pela anemia ancilostomica. A notavel proliferação dos eritroblastos ortocromaticos mostra que o grão e a rapidez da regeneração sanguinea, após a administração de ferro, são devidos, essencialmente, á grande quantidade de hemoglobina já preformada no baço e na medula ossea dos organismos ancilostomados.

  8. Hydrogeologic monitoring of the Paraíba do Sul river floodplain area subject to sand mining in the Tremembé municipality, SP, Brazil

    Directory of Open Access Journals (Sweden)

    Getulio Teixeira Batista

    2011-12-01

    Full Text Available To characterize the geological, hydrogeological, hydrochemical, and hydrobacterial aspects of the surface and groundwater in the floodplain of the Paraíba do Sul river in Tremembé municipality, the water levels of the Quaternary sedimentary aquifer experimental site was monitored based on four wells and eight associated piezometers with daily measures of water levels in continuous operation since December 3, 2009. In addition, data from a modular weather station in operation since March 2010 and data from the quality of surface water and groundwater have been analyzed in the period between March 2010 and March 2011. The water balance between April 2010 and March 2011 was estimated to verify the periods of water deficiency and excess. Data loggers installed in the piezometers enabled daily groundwater levels monitoring to establish the influence of the Paraíba do Sul river in the water levels of the Quaternary sedimentary aquifer and also they allowed the determination of the water loss to the atmosphere. A hydrogeological model with simplified equations, based on hydraulics parameters obtained in the wells pump tests, was implemented to calculate the amount of daily evapotranspiration and the average distance of the water loss from the wells to the atmosphere. An evaporation rate of 83.4 m3/h from the open-pit sand mine located at 212.2 m and of 89.2 m3/h for the one at 885.0 m average distance from the monitoring wells were observed. Chemical and bacteriological analysis involving multiple parameters were performed in the period from March 2010 to March 2011 in groundwater collected in wells, in the open-pit mines and in the waters of the Paraíba do Sul river. The results allowed to observe the influences of the Paraíba do Sul river as well as the contamination from fertilizers and pesticides from the agriculture practiced in the floodplain area on the quality of the groundwater.

  9. Compounds of the type Ba/sub 3/Bsup(II)M/sub 2/sup(V)O/sub 9/ with Bsup(II) = Mg, Ca, Sr, Ba, and Msup(V) = Nb, Ta

    Energy Technology Data Exchange (ETDEWEB)

    Kemmler-Sack, S; Thumm, I; Herrmann, M [Tuebingen Univ. (Germany, F.R.). Lehrstuhl fuer Anorganische Chemie 2

    1981-08-01

    The hexagonal perovskites Ba/sub 3/Bsup(II)M/sub 2/sup(V)O/sub 9/ (Msup(V) = Nb, Ta) crystallize with Bsup(II) = Mg, Ca in a 3 L structure (sequence (c)/sub 3/) and Bsup(II) = Sr in the hexagonal BaTiO/sub 3/ type (6 L; sequence (hcc)/sub 2/) with an 1:2 order for the B and M ions. Intensity calculations for Ba/sub 3/SrNb/sub 2/O/sub 9/ and Ba/sub 3/SrTa/sub 2/O/sub 9/ gave in the space group P6/sub 3//mmc a refined, intensity related R' value of 8.4% (Nb) and 9.0% (Ta) respectively. For Bsup(II) = Ba the perovskite Ba/sub 3/BaTa/sub 2/O/sub 9/ has an orthorhombic distorted 6 L structure and forms with Ba/sub 3/SrTa/sub 2/O/sub 9/ a continuous series of mixed crystals (Ba/sub 3/Srsub(1-x)Basub(x)Ta/sub 2/O/sub 9/). In the system Ba/sub 3/Srsub(1-x)Basub(x)Nb/sub 2/O/sub 9/ the range of existence of the hexagonal BaTiO/sub 3/ type is confined to the Sr richer end. The pure Ba compound posesses a proper structure type (5 L: Ba/sub 5/BaNb/sub 3/vacantOsub(13.5)vacantsub(1.5)).

  10. First-principles study of (Ba ,Ca ) TiO3 and Ba (Ti ,Zr ) O3 solid solutions

    Science.gov (United States)

    Amoroso, Danila; Cano, Andrés; Ghosez, Philippe

    2018-05-01

    (Ba ,Ca ) TiO3 and Ba (Ti ,Zr ) O3 solid solutions are the building blocks of lead-free piezoelectric materials that attract a renewed interest. We investigate the properties of these systems by means of first-principles calculations, with a focus on the lattice dynamics and the competition between different ferroelectric phases. We first analyze the four parent compounds in order to compare their properties and their different tendency towards ferroelectricity. The core of our study is systematic characterization of the binary systems (Ba ,Ca ) TiO3 and Ba (Ti ,Zr ) O3 within both the virtual crystal approximation and direct supercell calculations. In the case of Ca doping, we find a gradual transformation from B -site to A -site ferroelectricity due to steric effects that largely determines the behavior of the system. In the case of Zr doping, in contrast, the behavior is eventually dominated by cooperative Zr-Ti motions and the local electrostatics. In addition, our comparative study reveals that the specific microscopic physics of these solids sets severe limits to the applicability of the virtual crystal approximation for these systems.

  11. Electronic structure of Ca, Sr, and Ba under pressure.

    Science.gov (United States)

    Animalu, A. O. E.; Heine, V.; Vasvari, B.

    1967-01-01

    Electronic band structure calculations phase of Ca, Sr and Ba over wide range of atomic volumes under pressure electronic band structure calculations for fcc phase of Ca, Sr and Ba over wide range of atomic volumes under pressure electronic band structure calculations for fcc phase of Ca, Sr and Ba over wide range of atomic volumes under pressure

  12. Effect of Barium-Precursors on Reaction Kinetics in Y-Ba-Cu-O System

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The reactions of stoichiometric Y2O3, CuO, and different Ba salts or oxides (BaCO3, Ba(NO3)2, BaO2, BaCuO2) for forming various compounds in the Y-Ba-Cu-O system (i.e., YBa2Cu3O7-δ, BaCuO2, Y2BaCuO5 and Y2Cu2O5) were systematically investigated by thermal analysis and X-ray diffractometry. The relevant activation energies were calculated from thermogravimetric data. It is found that the reaction pathway significantly depends on the thermal stability of the Ba precursors. Binary BaO-CuO phases form at low temperature (650~700 ℃) when in presence of easy-to-decompose Ba precursors, and then slowly transform to ternary compounds. On the contrary, when Ba ions are released at temperature higher than 900 ℃, ternary phases form directly from the components.

  13. Strain induced optical properties of BaReO3

    Science.gov (United States)

    Kumavat, Sandip R.; Kansara, Shivam; Gupta, Sanjeev K.; Sonvane, Yogesh

    2018-05-01

    Here, we have performed strain induce optical properties of BaReO3 by using density functional theory (DFT). We noticed that after applying intrinsic and extrinsic strain to the BaReO3, it shows the metallic behavior. We also studied optical properties, which show good activity in the ultraviolet region. The results show that after applying intrinsic and extrinsic strain to BaReO3 the absorption peaks are shifted towards the high UV region of the spectrum. Thus, we concluded that, BaReO3 material with extrinsic strain can be useful for high frequency UV device and optoelectronic devices.

  14. Insecticide susceptibility of Aedes albopictus and Ae. aegypti from Brazil and the Swiss-Italian border region.

    Science.gov (United States)

    Suter, Tobias; Crespo, Mônica Maria; de Oliveira, Mariana Francelino; de Oliveira, Thaynan Sama Alves; de Melo-Santos, Maria Alice Varjal; de Oliveira, Cláudia Maria Fontes; Ayres, Constância Flávia Junqueira; Barbosa, Rosângela Maria Rodrigues; Araújo, Ana Paula; Regis, Lêda Narcisa; Flacio, Eleonora; Engeler, Lukas; Müller, Pie; Silva-Filha, Maria Helena Neves Lobo

    2017-09-19

    Aedes aegypti and Ae. albopictus are two highly invasive mosquito species, both vectors of several viruses, including dengue, chikungunya and Zika. While Ae. aegypti is the primary vector in the tropics and sub-tropics, Ae. albopictus is increasingly under the public health watch as it has been implicated in arbovirus-transmission in more temperate regions, including continental Europe. Vector control using insecticides is the pillar of most control programmes; hence development of insecticide resistance is of great concern. As part of a Brazilian-Swiss Joint Research Programme we set out to assess whether there are any signs of existing or incipient insecticide resistance primarily against the larvicide Bacillus thuringiensis svar. israelensis (Bti), but also against currently applied and potentially alternative insecticides in our areas, Recife (Brazil) and the Swiss-Italian border region. Following World Health Organization guidelines, dose-response curves for a range of insecticides were established for both colonized and field caught Ae. aegypti and Ae. albopictus. The larvicides included Bti, two of its toxins, Cry11Aa and Cry4Ba, Lysinibacillus sphaericus, Vectomax CG®, a formulated combination of Bti and L. sphaericus, and diflubenzuron. In addition to the larvicides, the Swiss-Italian Ae. albopictus populations were also tested against five adulticides (bendiocarb, dichlorodiphenyltrichloroethane, malathion, permethrin and λ-cyhalothrin). Showing a similar dose-response, all mosquito populations were fully susceptible to the larvicides tested and, in particular, to Bti which is currently used both in Brazil and Switzerland. In addition, there were no signs of incipient resistance against Bti as larvae were equally susceptible to the individual toxins, Cry11Aa and Cry4Ba. The field-caught Swiss-Italian populations were susceptible to the adulticides tested but DDT mortality rates showed signs of reduced susceptibility. The insecticides currently used for

  15. IR-spectroscopic study and electrical properties of glasses in the Ba(PO3)2-Ba(Hal)2 systems

    International Nuclear Information System (INIS)

    Sokolov, I.A.; Tarlakov, Yu.P.; Murin, I.V.; Pronkin, A.A.

    2000-01-01

    Temperature-concentration dependence of electric conductivity of glasses in the systems Ba(PO 3 ) 2 -Ba(Hal) 2 , where Hal = Cl, Br, I, is studied by the method of conductometry, the numbers of iodide-ions transfer are determined and their concentration dependence is found. Data of IR spectroscopy permitted ascertained participation of halide ions in formation of anionic constituent of the glass structure at the expense of bridge bonds formation, as well as formation of structural-chemical units of [(Hal) - Ba 2+ O - POO 2/2 ] type, their dissociation giving rise to formation of halide ions their dissociation giving rise to formation of halide ions taking part in electric current transfer [ru

  16. High-Temperature Superconductivity in Doped BaFe2As2

    International Nuclear Information System (INIS)

    Martin, Marianne

    2011-01-01

    This thesis provides a detailed look on the synthesis, structural features and physical properties of iron arsenides. Especially the properties of BaFe 2 As 2 and the solid solutions (Ba 1-x K x )Fe 2 As 2 , (Ba 1-x Sr x )Fe 2 As 2 and BaFe 2 (As 1-x P x ) 2 which were all synthesized by solid state reactions by heating mixtures of the elements, were intensively investigated.

  17. Molecular recognition at methyl methacrylate/n-butyl acrylate (MMA/nBA) monomer unit boundaries of phospholipids at p-MMA/nBA copolymer surfaces.

    Science.gov (United States)

    Yu, Min; Urban, Marek W; Sheng, Yinghong; Leszczynski, Jerzy

    2008-09-16

    Lipid structural features and their interactions with proteins provide a useful vehicle for further advances in membrane proteins research. To mimic one of potential lipid-protein interactions we synthesized poly(methyl methacrylate/ n-butyl acrylate) (p-MMA/nBA) colloidal particles that were stabilized by phospholipid (PLs). Upon the particle coalescence, PL stratification resulted in the formation of surface localized ionic clusters (SLICs). These entities are capable of recognizing MMA/nBA monomer interfaces along the p-MMA/nBA copolymer backbone and form crystalline SLICs at the monomer interface. By utilizing attenuated total reflectance Fourier transform infrared (ATR FT-IR) spectroscopy and selected area electron diffraction (SAD) combined with ab initio calculations, studies were conducted that identified the origin of SLICs as well as their structural features formed on the surface of p-MMA/nBA copolymer films stabilized by 1,2-dilauroyl-sn-glycero-3-phosphocholine (DLPC) PL. Specific entities responsible for SLIC formation are selective noncovalent bonds of anionic phosphate and cationic quaternary ammonium segments of DLPC that interact with two neighboring carbonyl groups of nBA and MMA monomers of the p-MMA/nBA polymer backbone. To the best of our knowledge this is the first example of molecular recognition facilitated by coalescence of copolymer colloidal particles and the ability of PLs to form SLICs at the boundaries of the neighboring MMA and nBA monomer units of the p-MMA/nBA chain. The dominating noncovalent bonds responsible for the molecular recognition is a combination of H-bonding and electrostatic interactions.

  18. Epitaxial thin-film growth of Ruddlesden-Popper-type Ba3Zr2O7 from a BaZrO3 target by pulsed laser deposition

    International Nuclear Information System (INIS)

    Butt, Shariqa Hassan; Rafique, M.S.; Siraj, K.; Latif, A.; Afzal, Amina; Awan, M.S.; Bashir, Shazia; Iqbal, Nida

    2016-01-01

    Ruddlesden-Popper Ba 3 Zr 2 O 7 thin films have been synthesized via pulsed laser deposition (PLD) technique. The optimization of deposition parameters in PLD enables the formation of thin film of metastable Ba 3 Zr 2 O 7 phase from BaZrO 3 target. In order to see the post-annealing effects on the structural and optical properties, the deposited Ba 3 Zr 2 O 7 thin films were annealed at 500, 600 and 800 C. X-ray diffraction (XRD) reveals the formation of Ba 3 Zr 2 O 7 phase with tetragonal structure. The changes in the surface of the deposited films were analysed by FE-SEM and AFM. The thin film post-annealed at 500 C exhibited the best structural, optical and surface properties. Furthermore, the chemical states and chemical composition of the films were determined by X-ray photoelectron spectroscopy (XPS) near the surface. The XPS results show that Ba, Zr and O exist mainly in the form of Ba 3 Zr 2 O 7 Ruddlesden-Popper-type perovskite structure. (orig.)

  19. Floristic composition of the riparian forest in the lower Gramame river, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Hermes de Oliveira Machado Filho

    2015-09-01

    Full Text Available Riparian forest has a key ecological and economic significance to productive chains associated with it. This study aimed to conduct a floristic survey of riparian forest stretches in the Gramame river, state of Paraíba, Brazilian Northeast region, and analyze the floristic similarity with Brazilian riparian vegetation fragments. We found 136 species belonging to 106 genera and 43 families. The most representative families were: Fabaceae (19 spp., Cyperaceae (16 spp., and Rubiaceae (11 spp.. The predominant habit was herbaceous and the best represented biological spectrum was camephyte. Regarding the geographic distribution, there was a predominance of widely distributed species associated with the Neotropical province. The distribution patterns have shown a low similarity between areas, and largely distributed species stand out. Similarity analysis pointed out that the area was floristically related to other two coastal areas in the Brazilian Northeast and Southeast regions. Only species typically related to estuarine environments might explain the floristic connections detected.

  20. Behaviour of zirconium in the weathering of granulites from Salvador-BA/Brazil

    International Nuclear Information System (INIS)

    Garcia, I.J.C.

    1979-01-01

    The weathering related to mineralogy with chemical analysis of Zr in granulites and their weathered equivalents in Salvador - Brazil, is studied. The mineralogical and petrographical characteristics were correlated with analyses for K,Al and Zr. The fresh rocks are quartz-rich pyroxene granulites, the weathered samples were submitted to bromoform and electromagnetic separations to recovery nearly pure zircon from the fraction coarser than 50 micros. These zircons were classified by color, size and shape. Proportions between different colors of zircon were correlated with petrography of fresh granulites. Studies of zircons resistent to acid attack indicated, that the darker colors were due to iron oxide staining. Chemical analyses for Zr in fresh rocks presented values higher than the values corresponding to zircon observed in thin sections, sugesting the presence of Zr as a trace element in ferromagnesian silicates. In the weathered rocks, Zr values are much higher than those corresponding to recovered zircon. Comparisons of K 2 O, Al 2 O 3 and Zr values in fresh and weathered rocks indicated a loss of K 2 O, and a gain of Zr by weathering. However, maximum losses of K 2 O do not coincide with maximum gains of Zr. (author) [pt

  1. Hydroids (Cnidaria, Hydrozoa of the intertidal zone of Governador and Paquetá islands, Guanabara Bay, Rio de Janeiro, Brazil Hidróides (Cnidaria, Hydrozoa da zona entremarés das ilhas do Governador e Paquetá, Baía de Guanabara, Rio de Janeiro, Brasil

    Directory of Open Access Journals (Sweden)

    Priscila A. Grohmann

    2009-09-01

    Full Text Available During six consecutive months, sampling were made at three points located on Governador Island and three on Paquetá Island in Guanabara Bay, Rio de Janeiro, Brazil. Material was collected from dock pilings and rocks in the intertidal zone. In these samples, five species belonging to three families, Corynidae, Kirchenpaueriidae and Campanulariidae, were identified. The campanulariid species Obelia dichotoma Linnaeus, 1758, dominated at nearly all points sampled. The small number of species obtained in this survey is attributed to the intense pollution in the bay, which borders the second-largest industrial complex and the second-largest demographic center of Brazil.Durante seis meses consecutivos foram feitas coletas em três pontos localizados na ilha do Governador e três em Paquetá, sendo colhido material em pilares de cais e rochas na zona entremarés. Foram identificadas cinco espécies pertencentes a três famílias: Corynidae, Kirchenpaueriidae e Campanulariidae. A espécie Obelia dichotoma Linnaeus, 1758 dominou em praticamente todos os pontos. O pequeno número de espécies encontradas neste levantamento deve-se, provavelmente, ao alto grau de poluição atualmente existente na baía, uma vez que ela abriga o segundo maior polo industrial e o segundo maior centro demográfico do Brasil.

  2. Study of uranium leaching from industrial residues of Industrias Nucleares do Brazil S.A. (INB), Caetite, Bahia, Brazil

    International Nuclear Information System (INIS)

    Formiga, Thiago S.; Morais, Carlos A.; Gomiero, Luiz A.

    2011-01-01

    The uraniferous district of Lagoa Real, located in the south-central region of the state of Bahia, has reserves estimated at 100,000 tons of uranium, which is enough to supply Angra I, II and III for 100 more years. The process adopted for the beneficiation of the uranium ore from Lagoa Real is heap leaching, a static process in which the ore is crushed, disposed in heaps and irrigated with a sulfuric acid solution to remove the uranium. This technique has a relatively low cost of implementation, although the yield of uranium recovery is low, with an uranium content in the leached residue of 700 μg/g U 3 O 8 for ores with an initial content of 2,700 μg/g U 3 O 8 . With the deepening of the mine pit, an increase in the carbonate content in the ore was noted, which required a higher acid consumption in the leaching. In order to reduce the concentration of carbonates, a study of the ore concentration by flotation column was accomplished. The flotation reject had high carbonate content, with a uranium content of about 2,300 μg/g U 3 O 8 for flotation in one column and 1,100 μg/g U 3 O 8 for flotation in two columns. This paper presents the study of the leaching process for the recovery of the uranium present in the residue of the heap leaching and in the carbonated residue from the flotation of the anomaly 13 ore. The results indicate the feasibility of treating the waste of the heap leaching through dynamic leaching. The study of the uranium leaching from the flotation residue through acid leaching technique indicated a recovery of 96% of uranium, however with a high consumption of acid, around 450 kg/t, showing that for this case, the most suitable technique for the process is alkaline leaching. (author)

  3. Study of uranium leaching from industrial residues of Industrias Nucleares do Brazil S.A. (INB), Caetite, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Formiga, Thiago S.; Morais, Carlos A., E-mail: cmorais@cdtn.b [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil); Gomiero, Luiz A., E-mail: gomiero@inb.gov.b [Industrias Nucleares do Brasil S/A (INB), Caetite, BA (Brazil)

    2011-07-01

    The uraniferous district of Lagoa Real, located in the south-central region of the state of Bahia, has reserves estimated at 100,000 tons of uranium, which is enough to supply Angra I, II and III for 100 more years. The process adopted for the beneficiation of the uranium ore from Lagoa Real is heap leaching, a static process in which the ore is crushed, disposed in heaps and irrigated with a sulfuric acid solution to remove the uranium. This technique has a relatively low cost of implementation, although the yield of uranium recovery is low, with an uranium content in the leached residue of 700 {mu}g/g U{sub 3}O{sub 8} for ores with an initial content of 2,700 {mu}g/g U{sub 3}O{sub 8}. With the deepening of the mine pit, an increase in the carbonate content in the ore was noted, which required a higher acid consumption in the leaching. In order to reduce the concentration of carbonates, a study of the ore concentration by flotation column was accomplished. The flotation reject had high carbonate content, with a uranium content of about 2,300 {mu}g/g U{sub 3}O{sub 8} for flotation in one column and 1,100 {mu}g/g U{sub 3}O{sub 8} for flotation in two columns. This paper presents the study of the leaching process for the recovery of the uranium present in the residue of the heap leaching and in the carbonated residue from the flotation of the anomaly 13 ore. The results indicate the feasibility of treating the waste of the heap leaching through dynamic leaching. The study of the uranium leaching from the flotation residue through acid leaching technique indicated a recovery of 96% of uranium, however with a high consumption of acid, around 450 kg/t, showing that for this case, the most suitable technique for the process is alkaline leaching. (author)

  4. Experimental study on Ra2+ uptake by barite (BaSO{sub 4}). Kinetics of solid solution formation via BaSO{sub 4} dissolution and Ra{sub x}Ba{sub 1-x}SO{sub 4} (re) precipitation

    Energy Technology Data Exchange (ETDEWEB)

    Bosbach, Dirk; Boettle, Melanie; Metz, Volker (Karlsruher Inst. fuer Technologie, Inst fuer Nukleare Entsorgung (INE), Karlsruhe (Germany))

    2010-03-15

    226Ra2+ and 133Ba2+ uptake by barite in aqueous solution is studied on the basis of batch type experiments with two different barite powders with different specific surface area (0.5 m2/g and 3.2 m2/g, respectively). The uptake of 226Ra2+ and 133Ba2+ is not only limited to adsorption reactions but proceeds significantly into the bulk of the barite crystals. 133Ba2+ uptake kinetics is affected by various parameters, such as amount of sample, specific surface area, sample type and solution composition. In the case of 133Ba2+, complete isotopic equilibration of the 133Ba2+ spiked solution with the barite powder occurs within 50 to 600 days. This information is derived by monitoring the aqueous 133Ba2+ concentration combined with simple mass balance calculations. In the case of 226Ra2+ a Ra{sub x}Ba{sub 1-x}SO{sub 4} solid solution forms and the uptake rate drops significantly within 400 days. The observed 226Ra2+ concentration in solution is controlled by the solubility of a Ra{sub x}Ba{sub 1-x}SO{sub 4} solid solution and several orders of magnitude below the Ra2+ solubility with respect to a pure RaSO{sub 4}(s) end member. It cannot be demonstrated unambiguously that a zero exchange rate and therefore thermodynamic equilibrium has been established within the observation period. The observed concentrations may be interpreted either as (1) a partial equilibration of 20 to 50% of the barite crystals with 226Ra2+ or (2) as complete equilibration of a Ra{sub 0.000128}Ba{sub 0.999872}SO{sub 4} solid solution with 226Ra2+ with no pure barite left. In both cases it is concluded that equilibration between aqueous Ra2+ and barite involves the replacement of a substantial fraction of the initial barite and proceeds significantly beyond pure surface adsorption processes

  5. Enhancement of polarization property of silane-modified BaTiO3 nanoparticles and its effect in increasing dielectric property of epoxy/BaTiO3 nanocomposites

    Directory of Open Access Journals (Sweden)

    Thi Tuyet Mai Phan

    2016-03-01

    Full Text Available The surface modification of synthesized nano-BaTiO3 particles was carried out using γ-aminopropyl trimethoxy silane (γ-APS in an ethanol/water solution. The modified particles were characterized by FTIR, TGA, surface charge analysis, and by dielectric constant measurement. The silane molecules were attached to the surface of BaTiO3 particles through SiOBaTiO3 bonds. The γ-APS grafted on BaTiO3 made the dielectric constant of the particles increase at frequencies ≥0.3 kHz in a wide range of temperature (25 °C–140 °C, due to the presence of NH2 groups. The dependence of the polarization vs. electrical field was measured in order to elucidate the dielectric behavior of the silane treated BaTiO3 in comparison to untreated BaTiO3. The nanocomposite based on epoxy resin containing BaTiO3 nanoparticles untreated and treated with γ-APS was also prepared and characterized. The results indicated that the γ-APS-modified BaTiO3 surfaces significantly enhanced the dielectric property of the nanocomposite.

  6. Caloric density of aquatic macrophytes in different environments of the Baía river subsystem, upper Paraná river floodplain, Brazil

    Directory of Open Access Journals (Sweden)

    Célia de Almeida Lopes

    2006-09-01

    Full Text Available The aim of this work was to determine the caloric density of leaves, stems and roots of aquatic macrophytes in different environments of the Baía subsystem (Baía river and Fechada and Guaraná lagoons on the Upper Paraná river floodplain, in addition to identify the variability between ecological groups. Samplings of Eichhornia crassipes, Salvinia spp, Pistia stratiotes, Eichhornia azurea, Polygonum sp, Cyperaceae and Poaceae were carried out in February 2003. Spatial differences in the caloric densities were not observed for these plants. Caloric density values varied from 1906.9 cal/g dry weight (root to 4675.0 cal/g dry weight (leaf. However, significant differences between the caloric content averages of the vegetative structures were observed only for Polygonum sp and Salvinia spp. In relation to the ecological groups, the highest average value was verified for the emergent macrophytes (3529.7 ± 722.5, which were significantly different from the floating ones (3056.5 ± 571.0. There was no difference between the sites included in the subsystem when the caloric densities were compared.O presente trabalho teve por objetivo determinar a densidade calórica de folhas, caules e raízes de macrófitas aquáticas, em diferentes ambientes do subsistema Baía (Rio Baía e lagoas Fechada e do Guaraná na planície de inundação do alto rio Paraná, além de identificar a variabilidade entre grupos ecológicos. As amostragens foram realizadas em fevereiro de 2003, sendo coletadas amostras de diferentes macrófitas, Eichhornia crassipes, Salvinia spp, Pistia stratiotes, Eichhornia azurea, Polygonum sp, Cyperaceae e Poaceae. Diferenças espaciais nas densidades calóricas não foram observadas para as plantas estudadas. Os valores de densidade calórica variaram de 1906,9 cal/g de peso seco (raiz a 4675,0 cal/g de peso seco (folha. Entretanto, diferenças significativas entre as médias dos conteúdos calóricos das estruturas vegetativas foram

  7. Soil organic matter and soil acidity in Mangrove areas in the river Paraiba Estuary, Cabedelo, Paraiba, Brazil

    Directory of Open Access Journals (Sweden)

    Renata Wilma Vasconcelos

    2014-08-01

    Full Text Available Mangrove ecosystems are of great environmental significance, because of their fragility and role in feeding and breeding various animal species. In northeastern Brazil, the disorderly occupation of estuarine areas and the urban sprawl have led to a considerable loss of the original area occupied by mangroves. In the municipality of Cabedelo, State of Paraíba, there are about 4,900 ha of remnant mangrove areas in the estuarine complex of the Paraíba River. However, information about the attributes of mangrove soils at this location is quite scarce. The aim of this study was to quantify the soil organic matter and soil acidity in mangroves located in the estuary of the Paraíba River, State of Paraíba, Brazil, in order to increase the database of soil attributes in this region. The study area is in local influence of the Restinga de Cabedelo National Forest (Flona, an environmental conservation unit of the Chico Mendes Institute for Biodiversity Conservation. For the choice of sampling points, we considered an area that receives direct influence of the eviction of domestic and industrial effluents. The soil of the study area is an “Organossolo Háplico” in Brazilian Soil Classification (Histosol, and was sampled at four point sites: one upstream of the effluent discharge (P1, one in the watercourse receiving effluent water (P2, one downstream of the effluent discharge (P3 and another near Flona (P4, at 0-20 and 20-40 cm, in four replications in time (28/08/2012 in the morning and afternoon, and 21/01/2013 in the morning and afternoon. Potential acidity, pH and soil organic matter (SOM were determined. No significant differences were detected in the potential acidity of the four collection sites, which ranged from 0.38 to 0.45 cmolc dm-3. Soil pH was greatest at point P4 (7.0 and lowest at point P1 (5.8. The SOM was highest at point P1 (86.4 % and lowest at P2 (77.9 %. The attributes related to soil acidity were not sensitive to indicate

  8. Controlled Confinement of Half-metallic 2D Electron Gas in BaTiO3/Ba2FeReO6/BaTiO3 Heterostructures: A First-principles Study

    Science.gov (United States)

    Saha-Dasgupta, Tanusri; Baidya, Santu; Waghmare, Umesh; Paramekanti, Arun

    Using density functional theory calculations, we establish that the half-metallicity of bulk Ba2FeReO6 survives down i to 1 nm thickness in BaTiO3/Ba2FeReO6/BaTiO3 heterostructures grown along the (001) and (111) directions. The confinement of the two-dimensional (2D) electron gas in this quantum well structure arises from the suppressed hybridization between Re/Fe d states and unoccupied Ti d states, and it is further strengthened by polar fields for the (111) direction. This mechanism, distinct from the polar catastrophe, leads to an order of magnitude stronger confinement of the 2D electron gas than that at the LaAlO3/SrTiO3 interface. We further show low-energy bands of (111) heterostructure display nontrivial topological character. Our work opens up the possibility of realizing ultra-thin spintronic devices. Journal Ref: Phys. Rev. B 92, 161106(R) (2015) S.B. and T.S.D thank Department of Science and Technology, India for the support through Thematic Unit of Excellence. AP was supported by NSERC (Canada).

  9. Prática alimentar entre crianças menores de dois anos de idade residentes em municípios do semiárido do Estado da Paraíba, Brasil Feeding practice among children under 24 months in the semi-arid area of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Poliana de Araújo Palmeira

    2011-08-01

    Full Text Available OBJETIVO: Analisar a prática alimentar de crianças menores de dois anos de idade residentes em municípios do interior do Estado da Paraíba. MÉTODOS: Estudo secional realizado nos 14 municípios mais carentes do Estado da Paraíba. Foram pesquisados 539 domicílios com pelo menos uma criança com idade entre 0 e 23,9 meses. Aplicou-se às mães recordatório 24 horas sobre alimentação das crianças. O modelo de análise considerou três momentos do crescimento e desenvolvimento da criança, identificando as recomendações de consumo alimentar pertinentes. RESULTADOS: Crianças de 0-5,9 meses: destacou-se um importante percentual de desmame (20,7% e a reduzida prevalência do aleitamento materno exclusivo (30,5%. Crianças de 6-11,9 meses: 45,2% ainda mamavam, porém apenas 21,7% das crianças entre 6 e 9,9 meses apresentaram uma alimentação complementar oportuna. Crianças entre 12-23,9 meses: a prática alimentar das crianças caracterizou-se essencialmente pelo consumo de leite não materno e pelo consumo insuficiente de alimentos fontes de ferro. CONCLUSÃO: O hábito alimentar distancia-se de uma prática alimentar segura, especialmente pela interrupção precoce do aleitamento materno exclusivo e sua consequente substituição por refeições à base de leite não materno, expondo esse grupo a situações de insegurança alimentar e nutricional.OBJECTIVE: Examine the feeding practices among children under 24 months in the State of Paraíba, Brazil. METHODS: A cross-sectional study conducted in 14 municipalities identified as the poorest of the state; 539 households composed of at least one child between the ages of 0 and 23.9 months were investigated. A 24-hour recall was conducted with the mothers regarding food consumed by their children. The analytic model took into account established recommendations for appropriate child feeding practices for three age groups: 0-5.9 months; 6-12 months; 12-24 months. RESULTS: Children between

  10. The new barium zinc mercurides Ba3ZnHg10 and BaZn0.6Hg3.4 – Synthesis, crystal and electronic structure

    International Nuclear Information System (INIS)

    Schwarz, Michael; Wendorff, Marco; Röhr, Caroline

    2012-01-01

    The title compounds Ba 3 ZnHg 10 and BaZn 0.6 Hg 3.4 were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures, which both represent new structure types, have been determined using single crystal X-ray data. The structure of Ba 3 ZnHg 10 (orthorhombic, oP28, space group Pmmn, a=701.2(3), b=1706.9(8), c=627.3(3)pm, Z=2, R1=0.0657) contains folded 4 4 Hg nets, where the meshes form the bases of flat rectangular pyramids resembling the structure of BaAl 4 . The flat pyramids are connected via Hg–Zn/Hg bonds, leaving large channels at the folds, in which Ba(1) and Hg(2) atoms alternate. Whereas the remaining Hg/Zn atoms form a covalent 3D network of three- to five-bonded atoms with short M–M distances (273–301 pm; CN 9–11), the Hg(2) atoms in the channels adopt a comparatively large coordination number of 12 and increased distances (317–348 pm) to their Zn/Hg neighbours. In the structure of BaZn 0.6 Hg 3.4 (cubic, cI320, space group I4 ¯ 3d, a=2025.50(7) pm, Z=64, R1=0.0440), with a chemical composition not much different from that of Ba 3 ZnHg 10 , the Zn/Hg atoms of the mixed positions M(1/2) are arranged in an slightly distorted primitive cubic lattice with a 4×4×4 subcell relation to the unit cell. The 24 of the originating 64 cubes contain planar cis tetramers Hg(5,6) 4 with Hg in a nearly trigonal planar or tetrahedral coordination. In another 24 of the small cubes, two opposing faces are decorated by Hg(3,4) 2 dumbbells, two by Ba(2) atoms respectively. The third type of small cubes are centered by Ba(1) atoms only. The complex 3D polyanionic Hg/Zn network thus formed is compared with the Hg partial structure in Rb 3 Hg 20 applying a group-subgroup relation. Despite their different overall structures, the connectivity of the negatively charged Hg atoms, the rather metallic Zn bonding characteristic (as obtained from FP-LAPW band structure calculations) and the coordination number of 16 for all Ba cations

  11. Dynamics of photoexcited Ba{sup +} cations in {sup 4}He nanodroplets

    Energy Technology Data Exchange (ETDEWEB)

    Leal, Antonio; Pi, Martí [Departament ECM, Facultat de Física, and IN" 2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain); Zhang, Xiaohang; Drabbels, Marcel [Laboratoire de Chimie Physique Moléculaire, Swiss Federal Institute of Technology Lausanne (EPFL), CH-1015 Lausanne (Switzerland); Barranco, Manuel [Departament ECM, Facultat de Física, and IN" 2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain); Laboratoire des Collisions, Agrégats, Réactivité, IRSAMC, UMR 5589, CNRS et Université Paul Sabatier-Toulouse 3, 118 route de Narbonne, F-31062 Toulouse Cedex 09 (France); Cargnoni, Fausto [Istituto di Scienze e Tecnologie Molecolari (ISTM), Consiglio Nazionale delle Ricerche, via Golgi 19, 20133 Milano (Italy); Hernando, Alberto [Social Thermodynamics Applied Research (SThAR), EPFL Innovation Park, Bâtiment C, CH-1015 Lausanne (Switzerland); Mateo, David [Department of Chemistry and Biochemistry, California State University at Northridge, Northridge, California 91330 (United States); Mella, Massimo [Dipartimento di Scienza ed Alta Tecnologia, Università degli Studi dell’Insubria, via Valleggio 11, 22100 Como (Italy)

    2016-03-07

    We present a joint experimental and theoretical study on the desolvation of Ba{sup +} cations in {sup 4}He nanodroplets excited via the 6p ← 6s transition. The experiments reveal an efficient desolvation process yielding mainly bare Ba{sup +} cations and Ba{sup +}He{sub n} exciplexes with n = 1 and 2. The speed distributions of the ions are well described by Maxwell-Boltzmann distributions with temperatures ranging from 60 to 178 K depending on the excitation frequency and Ba{sup +} He{sub n} exciplex size. These results have been analyzed by calculations based on a time-dependent density functional description for the helium droplet combined with classical dynamics for the Ba{sup +}. In agreement with experiment, the calculations reveal the dynamical formation of exciplexes following excitation of the Ba{sup +} cation. In contrast to experimental observation, the calculations do not reveal desolvation of excited Ba{sup +} cations or exciplexes, even when relaxation pathways to lower lying states are included.

  12. Thermoelectric properties of doped BaHfO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Dixit, Chandra Kr., E-mail: ckparadise@gmail.com, E-mail: sharmarameshfgiet@gmail.com [Dept. of Physics, Dr. Shakuntala Misra National Rehabilitation University, Lucknow-229001, U.P India (India); Bhamu, K. C. [Department of Physics, Goa University, Goa-403 206 (India); Sharma, Ramesh, E-mail: ckparadise@gmail.com, E-mail: sharmarameshfgiet@gmail.com [Dept. of Physics, Feroze Gandhi Institute of Engineering & Technology, Raebareli-229001, U.P India (India)

    2016-05-06

    We have studied the structural stability, electronic structure, optical properties and thermoelectric properties of doped BaHfO{sub 3} by full potential linearized augmented plane wave (FP-LAPW) method. The electronic structure of BaHfO{sub 3} doped with Sr shows enhances the indirect band gaps of 3.53 eV, 3.58 eV. The charge density plots show strong ionic bonding in Ba-Hf, and ionic and covalent bonding between Hf and O. Calculations of the optical spectra, viz., the dielectric function, refractive index and extinction coefficient are performed for the energy range are calculated and analyzed. Thermoelectric properties of semi conducting are also reported first time. The doped BaHfO{sub 3} is approximately wide band gap semiconductor with the large p-type Seebeck coefficient. The power factor of BaHfO{sub 3} is increased with Sr doping, decreases because of low electrical resistivity and thermal conductivity.

  13. Operability test procedure for 211BA flow proportional sampler

    International Nuclear Information System (INIS)

    Weissenfels, R.D.

    1994-01-01

    The purpose of this operability test procedure (OTP) is to verify the 211-BA flow proportional sampler system and components function correctly as intended by design. System test will include the sampling system, all associated instrumentation, and Facility Process Monitor and Control System (FPMCS). The combined chemical sewer stream from B Plant flows through sump 211BA-SMP-01 located in 211-BA and is continuously monitored for gamma and beta radiation and pH. 211-BA has been upgraded to include a flow proportional sampler. A specified sample volume will be withdrawn at programmed intervals from the 211BA sump and deposited in a 19 liter plastic carboy. The sampler will be programmed per the vendor installation and operations manual by B Plant instrument maintenance personnel. Samples will be taken during five consecutive sample cycles with the sample volumes and sample frequencies recorded for comparison purposes. Additional tests related to the sampler include the alarm circuitry for loss of power and failure to obtain sample

  14. Ba-bah on tulnud / Liina Jänes

    Index Scriptorium Estoniae

    Jänes, Liina, 1977-

    2005-01-01

    Eesti noori disainereid-sisearhitekte ühendavast disainiagentuurist Ba-bah, selle eesmärgist. Agentuuri juhib Veiko Jääger. Mais 2005 Disaini- ja Arhitektuurigaleriis toimunud Ba-bahi avanäitusest, kus oli väljas töid EKA sisearhitektuuri, klaasi-, ehte- ja sepakunsti eriala üliõpilastelt ning metallmööbli valmistajalt Kalle Pruudenilt

  15. The microscopic twins and their crystal phase in the high Tc Y-Ba-Cu-O and Dy-Ba-Cu-O superconductive ceramics

    International Nuclear Information System (INIS)

    Zu, Z.J.; Chen, Y.L.

    1988-01-01

    Most consider that the structure of Y-Ba- Cu-O and Dy-Ba-Cu-O stable superconductive crystals with high Tc is associated with the right-angled phase. The superconductivity is closely connected with the right-angled character of the crystalline texture; the better the right- angled character, the better the superconductivity. From statistical investigations of examples the authors have discovered that most of the Y-Ba-Cu-O and Dy-Ba-Cu-O superconductivity with high Tc ceramic crystals is in the monoclinic phase, which, consists of microscopic, lamellar, single twins. The long-columnar grains consisting of lamellar twin slabs show the optical characteristics of right-angled phase. The microscopic twinning and grain morphologies are summarized in this paper

  16. Mineral composition of pastures and mineral deficiencies in cattle of some properties in Middle Paraiba, RJ, Brazil

    Directory of Open Access Journals (Sweden)

    Ana Paula Lopes Marques

    2014-01-01

    Full Text Available ABSTRACT. Marques A.P.L., Botteon R.C.C.M., Amorim E.B., Botteon P.T.L &Zonta E. [Mineral composition of pastures and mineral deficiencies in cattle of some properties in Middle Paraiba, RJ, Brazil.] Composição mineral das pastagens e deficiências minerais dos bovinos em algumas propriedades da região do Médio Paraíba, RJ, Brasil. Revista Brasileira de Medicina Veterinária, 36(1:71-78, 2014. Departamento de Medicina e Cirurgia Veterinária, Universidade Federal Rural do Rio de Janeiro, BR 465 Km 7, Seropédica, RJ 23851-900, Brasil. E-mail: marquesapl@ufrrj.br We studied levels and nutrient availability in the soil and grazing of cattle in Middle Paraíba, RJ, Brazil in the early dry season (May-June and rainy (November-December in seven cattle herds with a history of clinical deficiencies of Na, Cu, Co and P, identified through visits to farmers. The mineral contents in the samples were determined by atomic absorption spectrophotometry and values obtained were compared with clinical signs found. Low values of P and Na were confirmed and although the lack of Ca and Mg is uncommon, some samples showed low rates. We found high values of Fe with possible interference in the absorption of Cu, the main clinical deficiency identified in the region, and high values of Al, Zn and Mn. The results indicate that most mineral deficiencies diagnosed in those herds is due to antagonistic effects of minerals that are not deficient.

  17. Petrology of Terra Nova pluton, Brazil, and associated ultrapotassic dykes

    International Nuclear Information System (INIS)

    Silva Filho, A.F. da; Thompson, R.N.; Leat, P.T.

    1987-01-01

    The Upper Precambrian Terra Nova Pluton, situated 550 Km inland from Recife, Brazil, is 220 Km 2 in area and intrudes deformed metasedimentary rocks of the Pianco-Alto Brigida Mobile Belt. The Pluton shows complex petrological relationships. It consists of subalkaline quartz-monzonites and quartz-syenites, and the major minerals are K-feldspars, albite, hornblende, and quartz. The pluton is intermediate in composition (SiO 2 = 58.9-65.6 wt%, MgO=0.9-3.7 wt%) and is dominantly potassic (K 2 O=3.3-5.6 wt %; K 2 O/Na 2 O=0.9-1.8). Ba (up to 2.300 ppm) and Sr (up to 1,100 ppm) are abundant in the rocks, and LREE are enriched relative to HREE (La N /Lu N = 25.6-43.2). There is no significant Eu Anomaly. Rounded autoliths within the pluton are similar, but more mafic in composition (SiO 2 =54.6-57.5 wt %; MgO=4.9-6.4 wt %). A suite of dykes cut pluton and the surrounding country rocks. These dykes are varied in composition, encompassing most of the chemical range shown by the pluton and associated autoliths. The dykes are holocrystalline, peralkaline, and strongly enriched in both K 2 O(K 2 O=5.3-11.4 wt %) and Ba (Ba=2,400 ppm-10,500 ppm), which are considered to be magmatic abundances. The dykes have similar REE and other trace elements and ratios to the autoliths and plutonic rocks, and the dykes and the pluton are thought to be chemically related. The Terra Nova Pluton records the fractionation of mantle-derived ultrapotassic magma from mafic to intermediate compositions. (author) [pt

  18. Local manifestations of a static magnetoelectric effect in nanostructured BaTiO3-BaFe12O9 composite multiferroics

    Science.gov (United States)

    Trivedi, Harsh; Shvartsman, Vladimir V.; Lupascu, Doru C.; Medeiros, Marco S. A.; Pullar, Robert C.; Kholkin, Andrei L.; Zelenovskiy, Pavel; Sosnovskikh, Andrey; Shur, Vladimir Ya.

    2015-02-01

    A study on magnetoelectric phenomena in the barium titanate-barium hexaferrite (BaTiO3-BaFe12O19) composite system, using high resolution techniques including switching spectroscopy piezoresponse force microscopy (SSPFM) and spatially resolved confocal Raman microscopy (CRM), is presented. It is found that both the local piezoelectric coefficient and polarization switching parameters change on the application of an external magnetic field. The latter effect is rationalized by the influence of magnetostrictive stress on the domain dynamics. Processing of the Raman spectral data using principal component analysis (PCA) and self-modelling curve resolution (SMCR) allowed us to achieve high resolution phase distribution maps along with separation of average and localized spectral components. A significant effect of the magnetic field on the Raman spectra of the BaTiO3 phase has been revealed. The observed changes are comparable with the classical pressure dependent studies on BaTiO3, confirming the strain mediated character of the magnetoelectric coupling in the studied composites.

  19. The BaBar silicon vertex tracker

    International Nuclear Information System (INIS)

    Bozzi, C.; Carassiti, V.; Ramusino, A. Cotta; Dittongo, S.; Folegani, M.; Piemontese, L.; Abbott, B.K.; Breon, A.B.; Clark, A.R.; Dow, S.; Fan, Q.; Goozen, F.; Hernikl, C.; Karcher, A.; Kerth, L.T.; Kipnis, I.; Kluth, S.; Lynch, G.; Levi, M.; Luft, P.; Luo, L.; Nyman, M.; Pedrali-Noy, M.; Roe, N.A.; Zizka, G.; Roberts, D.; Barni, D.; Brenna, E.; Defendi, I.; Forti, A.; Giugni, D.; Lanni, F.; Palombo, F.; Vaniev, V.; Leona, A.; Mandelli, E.; Manfredi, P.F.; Perazzo, A.; Re, V.; Angelini, C.; Batignani, G.; Bettarini, S.; Bondioli, M.; Bosi, F.; Calderini, G.; Carpinelli, M.; Dutra, F.; Forti, F.; Gagliardi, D.; Giorgi, M.A.; Lusiani, A.; Mammini, P.; Morganti, M.; Morsani, F.; Paoloni, E.; Profeti, A.; Rama, M.; Rampino, G.; Rizzo, G.; Sandrelli, F.; Simi, G.; Triggiani, G.; Tritto, S.; Vitale, R.; Burchat, P.; Cheng, C.; Kirkby, D.; Meyer, T.; Roat, C.; Bona, M.; Bianchi, F.; Daudo, F.; Girolamo, B. Di; Gamba, D.; Giraudo, G.; Grosso, P.; Romero, A.; Smol, A.; Trapani, P.; Zanin, D.; Bosisio, L.; Ricca, G. Della; Lanceri, L.; Pompili, A.; Poropat, P.; Prest, M.; Rastelli, C.; Vallazza, E.; Vuagnin, G.; Hast, C.; Potter, E.P.; Sharma, V.; Burke, S.; Callahan, D.; Campagnari, C.; Dahmes, B.; Eppich, A.; Hale, D.; Hall, K.; Hart, P.; Kuznetsova, N.; Kyre, S.; Levy, S.; Long, O.; May, J.; Richman, J.; Verkerke, W.; Witherell, M.; Beringer, J.; Eisner, A.M.; Frey, A.; Grillo, A.; Grothe, M.; Johnson, R.; Kroeger, W.; Lockman, W.; Pulliam, T.; Rowe, W.; Schmitz, R.; Seiden, A.; Spencer, E.; Turri, M.; Wilder, M.; Charles, E.; Elmer, P.; Nielsen, J.; Orejudos, W.; Scott, I.; Walsh, J.; Zobernig, H.

    2000-01-01

    The BaBar Silicon Vertex Tracker (SVT) is designed to provide the high-precision vertexing necessary for making measurements of CP violation at the SLAC B-Factory PEP-II. The instrument consists of five layers of double-sided silicon strip detectors and has been installed in the BaBar experiment and taking colliding beam data since May 1999. An overview of the design as well as performance and experience from the initial running will be presented

  20. Lower Permian stems as fluvial paleocurrent indicators of the Parnaíba Basin, northern Brazil

    Science.gov (United States)

    Capretz, Robson Louiz; Rohn, Rosemarie

    2013-08-01

    A comprehensive biostratinomic study was carried out with abundant stems from the Lower Permian Motuca Formation of the intracratonic Parnaíba Basin, central-north Brazil. The fossils represent a rare tropical to subtropical paleofloristic record in north Gondwana. Tree ferns dominate the assemblages (mainly Tietea, secondarily Psaronius), followed by gymnosperms, sphenophytes, other ferns and rare lycophytes. They are silica-permineralized, commonly reach 4 m length (exceptionally more than 10 m), lie loosely on the ground or are embedded in the original sandstone or siltstone matrix, and attract particular attention because of their frequent parallel attitudes. Many tree fern stems present the original straight cylindrical to slightly conical forms, other are somewhat flattened, and the gymnosperm stems are usually more irregular. Measurements of stem orientations and dimensions were made in three sites approximately aligned in a W-E direction in a distance of 27.3 km at the conservation unit "Tocantins Fossil Trees Natural Monument". In the eastern site, rose diagrams for 54 stems indicate a relatively narrow azimuthal range to SE. These stems commonly present attached basal bulbous root mantles and thin cylindrical sandstone envelopes, which sometimes hold, almost adjacent to the lateral stem surface, permineralized fern pinnae and other small plant fragments. In the more central site, 82 measured stems are preferentially oriented in the SW-NE direction, the proportion of gymnosperms is higher and cross-stratification sets of sandstones indicate paleocurrents mainly to NE and secondarily to SE. In the western site, most of the 42 measured stems lie in E-W positions. The predominantly sandy succession, where the fossil stems are best represented, evidences a braided fluvial system under semiarid conditions. The low plant diversity, some xeromorphic features and the supposedly almost syndepositional silica impregnation of the plants are coherent with marked dry

  1. Genome Sequence of African Swine Fever Virus BA71, the Virulent Parental Strain of the Nonpathogenic and Tissue-Culture Adapted BA71V.

    Science.gov (United States)

    Rodríguez, Javier M; Moreno, Leticia Tais; Alejo, Alí; Lacasta, Anna; Rodríguez, Fernando; Salas, María L

    2015-01-01

    The strain BA71V has played a key role in African swine fever virus (ASFV) research. It was the first genome sequenced, and remains the only genome completely determined. A large part of the studies on the function of ASFV genes, viral transcription, replication, DNA repair and morphogenesis, has been performed using this model. This avirulent strain was obtained by adaptation to grow in Vero cells of the highly virulent BA71 strain. We report here the analysis of the genome sequence of BA71 in comparison with that of BA71V. They possess the smallest genomes for a virulent or an attenuated ASFV, and are essentially identical except for a relatively small number of changes. We discuss the possible contribution of these changes to virulence. Analysis of the BA71 sequence allowed us to identify new similarities among ASFV proteins, and with database proteins including two ASFV proteins that could function as a two-component signaling network.

  2. Praseodymium valency from crystal structure in Pr-Ba-Cu-O and (Y-Pr)-Ba-Cu-O single crystals

    International Nuclear Information System (INIS)

    Collin, G.; Albouy, P.A.; Monod, P.; Ribault, M.

    1990-01-01

    The substitution of Pr to Y leads to materials with a general formula (Y 1-v Pr v ) (Ba 2-x Pr x ) (Cu 3-y vac y ) O 6+x/2-y+z and with a structural transition around v + x' ∼ 0.5. For v + x 0.5 the crystals are tetragonal, La 1.5 Ba 1.5 Cu 3 O 7±z type, with the characteristic tri-twinning of this phase. The Pr valency, in the range 3-3.2 + depending on preparation conditions, is determined from interatomic distances. Orthorhombic crystals of Pr Ba Cu O prepared at high temperatures exhibit a high amount of defects, y ∼ 0.25 on the Cu(1) site and are semiconductors with a T -1/4 activation law attributed to the praseodymium valence fluctuation

  3. Structural evolution of Ba{sub 8}Ti{sub 3}Nb{sub 4}O{sub 24} from BaTiO{sub 3} using a series of Ba(Ti{sub 1−5x}Nb{sub 4x})O{sub 3} solid solutions

    Energy Technology Data Exchange (ETDEWEB)

    Barrientos Hernández, F.R., E-mail: frbh68@hotmail.com [Academic Area of Earth Sciences and Materials, Autonomous University of Hidalgo State, Road Pachuca-Tulancingo km 4.5, Mineral de la Reforma zip code 42184, Hidalgo (Mexico); Department of Metallurgical and Materials Engineering, ESIQIE, National Polytechnic Institute, UPALM, Zacatenco, Mexico City, zip code 07738 (Mexico); Lira Hernández, I.A. [Department of Metallurgical and Materials Engineering, ESIQIE, National Polytechnic Institute, UPALM, Zacatenco, Mexico City, zip code 07738 (Mexico); Industrial Engineering Department, Technological Institute of Pachuca, Road México-Pachuca km. 87.5, Pachuca de Soto zip code 42080, Hidalgo (Mexico); Gómez Yáñez, C. [Department of Metallurgical and Materials Engineering, ESIQIE, National Polytechnic Institute, UPALM, Zacatenco, Mexico City, zip code 07738 (Mexico); Arenas Flores, A. [Academic Area of Earth Sciences and Materials, Autonomous University of Hidalgo State, Road Pachuca-Tulancingo km 4.5, Mineral de la Reforma zip code 42184, Hidalgo (Mexico); Cabrera Sierra, R. [Department of Metallurgical and Materials Engineering, ESIQIE, National Polytechnic Institute, UPALM, Zacatenco, Mexico City, zip code 07738 (Mexico); Pérez Labra, M. [Academic Area of Earth Sciences and Materials, Autonomous University of Hidalgo State, Road Pachuca-Tulancingo km 4.5, Mineral de la Reforma zip code 42184, Hidalgo (Mexico)

    2014-01-15

    Highlights: • The evolution phase Ba{sub 8}Ti{sub 3}Nb{sub 4}O{sub 24} was obtained through the mechanism Ba(Ti{sub 1-5x}Nb{sub 4x})O{sub 3}. • Addition of niobium can accelerate grain growth of BaTiO{sub 3} ceramics. • Ba{sub 8}Ti{sub 3}Nb{sub 4}O{sub 24} presents a dielectric loss of 0.0035 and permittivity value of 54.6. • Electrical measurements showed that Nb{sup 5+} content drops Curie temperature. • Samples with x ⩾ 0.0625 shows an insulating behavior. -- Abstract: In this work, the structural evolution of hexagonal phase Ba{sub 8}Ti{sub 3}Nb{sub 4}O{sub 24} by adding Nb{sub 2}O{sub 5} to perovskite structure of BaTiO{sub 3} was investigated. The compositions Ba(Ti{sub 1-5x}Nb{sub 4x})O{sub 3} ceramics, with 0.00025 ⩽ x ⩽ 0.125 were prepared by the conventional solid state route in air atmosphere, the powders precursors, BaTiO{sub 3}, BaCO{sub 3} and Nb{sub 2}O{sub 5}, were mixed in stoichiometric proportions and ground in a ball mill using alumina balls and acetone. The mixed powders were calcined at temperatures up to 1500 °C. The phase transformation of Ba{sub 8}Ti{sub 3}Nb{sub 4}O{sub 24} from BaTiO{sub 3} was studied by DRX, Raman spectroscopy, SEM, electrical measurements (relative permittivity and P–E hysteresis loops); Rietveld’s refinement was used to structurally characterize the samples. For the devices obtained capacitance was measured at 1 kHz; with these values we calculated the relative permittivity. The samples show typical P–E hysteresis loops at room temperature accompanied by saturation polarization (Ps) and remnant polarization (Pr). The DRX and Rietveld’s refinement results show x ⩽ 0.01 has a ferroelectric behavior. When the doped level is increased x ⩾ 0.02, a peak displacement is observed, this is due to the phase transformation of tetragonal to cubic into the unit cell. Finally, with x = 0.125 the crystal structure transforms to the characteristic hexagonal phase Ba{sub 8}Ti{sub 3}Nb{sub 4}O{sub 24} which

  4. Assessment of inorganic contaminants in golden mussel (Limnoperna fortunei) in Southern Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Ederson R.; Soares, Bruno M.; Duarte, Fabio A., E-mail: fabioand@gmail.com [Escola de Quimica e Alimentos, Universidade Federal do Rio Grande, Rio Grande-RS (Brazil); Vieira, Joao P.; Mai, Ana C.G. [Instituto de Oceanografia, Universidade Federal do Rio Grande, Rio Grande-RS (Brazil); Picoloto, Rochele S.; Muller, Edson I.; Flores, Erico M.M. [Departamento de Quimica, Universidade Federal de Santa Maria, Santa Maria-RS (Brazil)

    2012-05-15

    Major and trace element content was determined in golden mussel (Limnoperna fortunei) collected in the Sao Goncalo Channel (Rio Grande City, Brazil). A microwave-assisted digestion procedure in closed vessels was applied to mussel decomposition and subsequent determination of elements by spectrometric techniques. Results showed that the mussel tissue contains Ag, Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, Li, Mg, Mn, Mo, P, Pb, S, Sn, Sr, Ti, V and Zn, while the same elements (except Ag and Hg) were quantified in its shell, demonstrating its potential as a biomarker. In this sense, these results can be used to establish an initial view and to contribute to further studies related to element contamination in the area under study (author)

  5. From Ba3Ta5O14N to LaBa2Ta5O13N2: Decreasing the optical band gap of a photocatalyst

    International Nuclear Information System (INIS)

    Anke, B.; Bredow, T.; Pilarski, M.; Wark, M.; Lerch, M.

    2017-01-01

    Yellow LaBa 2 Ta 5 O 13 N 2 was successfully synthesized as phase-pure material crystallizing isostructurally to previously reported Ba 3 Ta 5 O 14 N and mixed-valence Ba 3 Ta V 4 Ta IV O 15 . The electronic structure of LaBa 2 Ta 5 O 13 N 2 was studied theoretically with the range-separated hybrid method HSE06. The most stable structure was obtained when lanthanum was placed on 2a and nitrogen on 4h sites confirming Pauling's second rule. By incorporating nitrogen, the measured band gap decreases from ∼3.8 eV for the oxide via 2.74 eV for Ba 3 Ta 5 O 14 N to 2.63 eV for the new oxide nitride, giving rise to an absorption band well in the visible-light region. Calculated fundamental band gaps confirm the experimental trend. The atom-projected density of states has large contributions from N2p orbitals close to the valence band edge. These are responsible for the observed band gap reduction. Photocatalytic hydrogen formation was investigated and compared with that of Ba 3 Ta 5 O 14 N revealing significantly higher activity for LaBa 2 Ta 5 O 13 N 2 under UV-light. - Graphical abstract: X-ray powder diffraction pattern of LaBa 2 Ta 5 O 13 N 2 with the results of the Rietveld refinements. Inset: Unit cell of LaBa 2 Ta 5 O 13 N 2 and polyhedral representation of the crystal structure. - Highlights: • Synthesis of a new oxide nitride LaBa 2 Ta 5 O 13 N 2 . • Refinement of the crystal structure. • Quantum chemical calculations provided band gap close to the measured value. • New phase shows a higher photocatalytic H 2 evolution rate compared to prior tested Ba 3 Ta 5 O 14 N.

  6. Optical characteristics of BaGa{sub 2}S{sub 4}:Ho{sup 3+} and BaGa{sub 2}Se{sub 4}:Ho{sup 3+} single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Choe, Sung-Hyu [Chosun University, Kwangju (Korea, Republic of); Jin, Moon-Seog [Dongshin University, Naju (Korea, Republic of); Kim, Wha-Tek [Chonnam National University, Kwangju (Korea, Republic of)

    2005-11-15

    BaGa{sub 2}S{sub 4}, BaGa{sub 2}S{sub 4}:Ho{sup 3+}, BaGa{sub 2}Se{sub 4}, and BaGa{sub 2}Se{sub 4}:Ho{sup 3+} single crystals were grown by using the chemical transport reaction method. The optical energy gaps of the single crystals were investigated in the temperature region from 11 K to 300 K. The temperature dependence of the optical energy gap was well fitted by the Varshni equation. Two broad emission bands were observed in the photoluminescence spectra of the single crystals. These bands were attributed to donor-acceptor pair recombinations. Sharp emission peaks were observed in the BaGa{sub 2}S{sub 4}:Ho{sup 3+} and the BaGa{sub 2}Se{sub 4}:Ho{sup 3+} single crystals and were assigned to radiation recombination between split Stark levels of Ho{sup 3+}.

  7. Non-observation of 12C cluster decay of 114Ba

    International Nuclear Information System (INIS)

    Guglielmetti, A.; Bonetti, R.; Poli, G.; Collatz, R.; Hu, Z.; Kirchner, R.; Roeckl, E.; Gunn, N.; Price, P.B.; Weaver, B.A.; Westphal, A.; California Univ., Berkeley, CA; Szerypo, J.

    1997-10-01

    By means of the on-line mass separator at Gesellschaft fuer Schwerionenforschung, Darmstadt, we produced 114 Ba through the 58 Ni( 58 Ni,2n) reaction, separated it as a 114 Ba 19 F + beam, and implanted it into a stopper foil positioned in the center of an array of track detectors, which were used to search for 12 C radioactivity of 114 Ba. A total number of (5.4±1.7).10 4 114 Ba atoms were implanted. No 12 C event was found after a total exposure time of 116 hours, corresponding to a 58 Ni beam dose of 1.3.10 17 . The resulting upper limit of 3.4.10 -5 (84% c. 1.) for the branching ratio for 12 C decay of 114 Ba is considerably lower than the limits obtained in previous experiments, which represents an inconsistency at levels of more than 90%. A semiempirical estimate of 19.3 MeV for the upper limit of the Q-value for 12 C decay of 114 Ba is derived. (orig.)

  8. Analysis of oxygen binding-energy variations for BaO on W

    Science.gov (United States)

    Haas, G. A.; Shih, A.; Mueller, D.; Thomas, R. E.

    Interatomic Auger analyses have been made of different forms of BaO layers on W substrates. Variations in Auger spectroscopy energies of the Ba4dBa5pO2p interatomic Auger transition were found to be largely governed by the O2p binding energy of the BaO adsorbate. This was illustrated by comparing results of the Auger data values with values derived from O2p binding energies using ultraviolet photoelectron spectroscopy. Very good agreement was observed not only for the W substrate but also for the W substrate which showed two oxygen-induced electronics state. Variations in binding energy were noted for different states of BaO lattice formation and for different amounts of oxidation, ranging from the transition of Ba to BaO and continuing to the BaO 2 stoichiometry and beyond. Effects were also reported for adsorbate alignment and thermal activation (i.e., reduction) of the oxidized state. An empirical relationship was found suggesting that the more tightly bound the O2p states of the BaO adsorbate were, the lower its work function would be. This link between binding energy and work function was observed to be valid not only for cases of poisoning by oxidation, but held as well during reactivation by the subsequent reduction of the oxide. In addition, this relationship also appeared to predict the low work function obtained through the introduction of substances such as Sc to the BaO-W system. Possible qualitative reasons which might contribute to this are discussed in terms of enhanced dipole effects and shifts in band structure.

  9. Optical energy gaps and photoluminescence peaks of BaGa2S4:Er3+ and BaGa2Se4:Er3+ single crystals

    International Nuclear Information System (INIS)

    Choe, Sung-Hyu; Jin, Moon-Seog; Kim, Wha-Tek

    2005-01-01

    BaGa 2 S 4 :Er 3+ and BaGa 2 Se 4 :Er 3+ single crystals were grown by using the chemical transport reaction method. The optical energy gaps of the BaGa 2 S 4 :Er 3+ and the BaGa 2 Se 4 :Er 3+ single crystals were found to be 4.045 eV and 3.073 eV, respectively, at 11 K. The temperature dependence of the optical energy gap was well fitted by the Varshni equation. Sharp emission peaks were observed in the photoluminescence spectra of the single crystals and assigned to radiation recombination between split Stark levels of the Er 3+ ion.

  10. Floristic composition of the riparian forest in the lower Gramame river, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Thiago da Silva Farias

    2015-04-01

    Full Text Available http://dx.doi.org/10.5007/2175-7925.2015v28n3p23 Riparian forest has a key ecological and economic significance to productive chains associated with it. This study aimed to conduct a floristic survey of riparian forest stretches in the Gramame river, state of Paraíba, Brazilian Northeast region, and analyze the floristic similarity with Brazilian riparian vegetation fragments. We found 136 species belonging to 106 genera and 43 families. The most representative families were: Fabaceae (19 spp., Cyperaceae (16 spp., and Rubiaceae (11 spp.. The predominant habit was herbaceous and the best represented biological spectrum was camephyte. Regarding the geographic distribution, there was a predominance of widely distributed species associated with the Neotropical province. The distribution patterns have shown a low similarity between areas, and largely distributed species stand out. Similarity analysis pointed out that the area was floristically related to other two coastal areas in the Brazilian Northeast and Southeast regions. Only species typically related to estuarine environments might explain the floristic connections detected.

  11. Preparation of Ba1-xSrxWO4 and Ba1-xCaxWO4 films on tungsten plate by mechanically assisted solution reaction at room temperature

    International Nuclear Information System (INIS)

    Rangappa, Dinesh; Fujiwara, Takeshi; Watanabe, Tomoaki; Yoshimura, Masahiro

    2008-01-01

    Preparation of the alkaline earth tungstate films such as Ba 1-x Sr x WO 4 and Ba 1-x Ca x WO 4 on the tungsten substrate was studied with a simple solution process assisted with the ball rotation at room temperature. The solid solution formation and limitations, the effect of oxidizing agent H 2 O 2 and alkaline earth ions concentration on the dissolution of W substrate and the growth of Ba 1-x Sr x WO 4 and Ba 1-x Ca x WO 4 films were studied in detail. The ball rotation assistance plays a very important role to enhance the dissolution of the W substrate and mass transport of the reactant species such as alkaline earth ions and WO 4 2- ions onto the solid/solution interface region, where precipitation occurs. Therefore, the rate of film formation was accelerated by the ball rotation assistance to the reaction system. Ba-rich Ba 1-x Sr x WO 4 and Ba 1-x Ca x WO 4 films were formed without high energy or high temperature treatment

  12. Thermochemical investigations into the system Y-Ba-Cu-O

    International Nuclear Information System (INIS)

    Neuschuetz, D.; Zimmermann, E.; Hack, K.; Boudene, A.; Mohammad, A.

    1992-01-01

    For a consistent thermodynamic description of the quaternary system Y-Ba-Cu-O, the binary and ternary subsystems must be known. The metallic binaries and the ternary system Y-Ba-Cu have been evaluated by the authors. Discrepancies within the Cu-O system made a thorough experimental re-investigation necessary, leading to a new consistent thermodynamic data set for copper-oxygen which can now serve as a basis for the description of phase equilibria of all high temperature superconductors. Extensive experimental work on the ternaries Y-Cu-O and Ba-Cu-O, which are oxygen partial pressure dependent, revealed liquid phases down to 790degC. The ternary Y-Ba-O could be described more easily on the basis of literature values and present experimental results, because it does not contain any liquid phases at relevant temperatures. The representation of the quaternary Y-Ba-Cu-O is complicated both by its dependence on the oxygen potential and the existence of liquid oxide phases. In contrast to common practice, the present investigations had to start from Cu-free Ba-Y-O in order to avoid unknown liquid phases in the experiments. The present results being insufficient for a complete description of the quaternary system, the work is being continued within an EC joint research project. (orig.) With 84 refs., 8 tabs., 47 figs [de

  13. Studi On Oxidation State Of U In Ba2NdUO6

    International Nuclear Information System (INIS)

    Firman Windarto, Hendri

    1996-01-01

    Ba 2 NdUO 6 is not of the important compounds that is formed from a solidification process for high level liquid waste using super high temperature method Ba 2 NdUO 6 has ordered perovskite structure. The objective of this study is to investigate oxidation state of U in Ba 2 NdUO 6 . The properties of Ba 2 NdUO 6 were observed by using Faraday-type torsion magnetometer and X-ray Photoelectron Spectrometer (XPS). The magnetic susceptibility measured in the temperature range of 4K to room temperature showed that the Ba 2 NdUO 6 is paramagnetism that obeys the Curie-Weiss law. The effective moment of Ba 2 NdUO 6 is 3.04 μB. The results of xPs spectrum showed that the peaks of U4f for Ba 2 NdUO 6 appeared exactly between binding energy of UO 2 and UO 3 . It can be concluded that Ba 2 NdUO 6 has binding energy peaks corresponding to pentavalent uranium

  14. Thermoelectric transport properties of BaBiTe{sub 3}-based materials

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Yiming; Zhao, Li-Dong, E-mail: zhaolidong@buaa.edu.cn

    2017-05-15

    BaBiTe{sub 3}, a material with low thermal conductivity, is an inferior thermoelectric material due to the poor electrical properties originated from its narrow band gap. We choose two types of dopants, K and La, trying to optimize its electrical transport properties. The minority carriers, which harm the Seebeck coefficient in this system, are suppressed by La doping. With the increase of both electrical conductivity and Seebeck coefficient, the power factor of 3% La doped BaBiTe{sub 3} reaches 3.7 μW cm{sup −1} K{sup −2} which increased by 40% from undoped BaBiTe{sub 3}. Besides high power factor, the thermal conductivity is also reduced in it. Eventually, a high ZT value, 0.25 at 473 K, for n-type BaBiTe{sub 3} is achieved in 3% La doped BaBiTe{sub 3}. - Graphical abstract: BaBiTe{sub 3} possesses a low thermal conductivity. However, it is an inferior thermoelectric material due to the poor electrical properties originated from its narrow band gap. A high ZT value of 0.25 at 473 K for n-type BaBiTe{sub 3} can be achieved through optimizing electrical transport properties via La doping. - Highlights: • BaBiTe{sub 3} is an analogue of these promising thermoelectric materials: such as CsBi{sub 4}Te{sub 6} and K{sub 2}Bi{sub 8}Se{sub 13}, etc. • BaBiTe{sub 3} possesses a low thermal conductivity. • La is an effective dopant to enhance electrical transport properties. • A high ZT value of 0.25 at 473 K can be achieved in n-type La-doped BaBiTe{sub 3}.

  15. Uranium producer region of Lagoa Real, Brazil. Guarantee of supply of uranium concentrated (DUA) for the brazilian needs

    International Nuclear Information System (INIS)

    Matos, Evandro Carele de; Franco, Jamyle Praxedes

    2008-01-01

    This work focus at the Uranium Province of Lagoa Real, notably considering the geological reserves of uranium already defined (100,000 tones of U 3 O 8 ) and the respective autonomy in providing raw material needed for making fuel elements. The province, based on geo economical parameters, supported by three main vectors (geological model/grade, mining/process route, investment/finance) has been elected to supply the required brazilian demand. Supplying of uranium for the brazilian power plants is in charge of Industrias Nucleares do Brasil - INB and is based on national production. Thus the Industrial Complex of Caetite has been implemented in the state of Bahia, aiming primarily to supply the needs of Angra 1 and Angra 2 power plants. This new production center has the capacity of producing up to 400 tones/yr. of U 3 O 8 . (author)

  16. Bound-bound transitions in the emission spectra of Ba+-He excimer

    Science.gov (United States)

    Moroshkin, P.; Kono, K.

    2016-05-01

    We present an experimental and theoretical study of the emission and absorption spectra of the Ba+ ions and Ba+*He excimer quasimolecules in the cryogenic Ba-He plasma. We observe several spectral features in the emission spectrum, which we assign to the electronic transitions between bound states of the excimer correlating to the 6 2P3 /2 and 5 2D3 /2 ,5 /2 states of Ba+. The resulting Ba+(5 2DJ) He is a metastable electronically excited complex with orbital angular momentum L =2 , thus expanding the family of known metal-helium quasimolecules. It might be suitable for high-resolution spectroscopic studies and for the search for new polyatomic exciplex structures.

  17. Er3+ infrared fluorescence affected by spatial distribution synchronicity of Ba2+ and Er3+ in Er3+-doped BaO–SiO2 glasses

    Directory of Open Access Journals (Sweden)

    Atsunobu Masuno

    2016-02-01

    Full Text Available Glasses with the composition xBaO–(99.9 − xSiO2–0.1ErO3/2 (0 ≤x ≤ 34.9 were fabricated by a levitation technique. The glasses in the immiscibility region were opaque due to chemical inhomogeneity, while the other glasses were colorless and transparent. The scanning electron microscope observations and electron probe microanalysis scan profiles revealed that more Er3+ ions were preferentially distributed in the regions where more Ba2+ ions existed in the chemically inhomogeneous glasses. The synchronicity of the spatial distributions of the two ions initially increased with increasing x and then decreased when the Ba2+ concentration exceeded a certain value. The peak shape and lifetime of the fluorescence at 1.55 μm depended on x as well as the spatial distribution of both ions. These results indicate that although ErOn polyhedra are preferentially coordinated with Ba2+ ions and their local structure is affected by the coordination of Ba2+, there is a maximum in the amount of Ba2+ ions that can coordinate ErOn polyhedra since the available space for Ba2+ ions is limited. These findings provide us with efficient ways to design the chemical composition of glasses with superior Er3+ fluorescence properties for optical communication network systems.

  18. Nuclear spectroscopy of doubly-even130,132Ba

    Science.gov (United States)

    Gupta, Anuradha; Gupta, Surbhi; Singh, Suram; Bharti, Arun

    2018-05-01

    A comparative study of some high-spin characteristic nuclear structure properties of doubly-even 130,132Ba nuclei has been made using two microscopic frameworks - CHFB and PSM. The yrast spectra, intrinsic quadrupole moment and deformation systematics of these nuclei have been successfully calculated. Further, the calculated data from both the frameworks is also compared with the available experimental data and a good agreement has been obtained. The present CHFB calculations describes very well the low spin structure of even-even 130,132Ba nuclei whereas PSM calculations provide a qualitative description of the high-spin band structure of doubly-even 130,132Ba nuclei.

  19. Superconductivity in the U(Th)-Y-Ba-Cu-O systems

    International Nuclear Information System (INIS)

    Qin Qizong; He Adi; Jia Weijie; Ma Lidun; Cheng Huansheng; Hua Zhongyi

    1989-01-01

    High T c superconductivity has been observed both resistively and magnetically in the new U(Th)-Y-Ba-Cu-O systems. The zero resistance temperature of the three samples with nominal composition of U 0.1 Y 1.1 Ba 0.8 Cu O 4-z , U 0.15 Y 1.05 Ba 0.8 Cu 4-z and Th 0.3 Y 0.8 Ba 0.8 Cu 4-z is 87K, 79K and 74K, respectively. The result of ac magnetic susceptibility measurement implies that the superconducting state is realized in the U-doped samples below 90K. The stoichimetry of the U-Y-Ba-Cu O superconductors has the aid of Rutherford backscattering and nuclear reaction 16 O(d, p) 17 O. The analytical results show that the 'real composition' of somples may be different from that of the nomial composition. The X ray diffraction analysis of the U-Y-Ba-Cu-O system shows that none of the peaks can be fitted to the uranium oxides and the other raw materiale structure, and its pattern may be attributed to new multiple phases with structure different from the known singlephase superconducting oxides

  20. Characterization of fluids associated to mineral paragenesis of uraniferous albitites and their gnessic embedding rocks from Lagoa da Rabicha Uranium Deposit, Lagoa Real, BA, Brazil

    International Nuclear Information System (INIS)

    Oliveira, Lucilia Aparecida Ramos de

    2010-01-01

    Brazil has now the seventh largest uranium reserve in the world. The Lagoa Real Uranium Province (PULR) is located in central-south region of Bahia State. Along a helical structure, north-south oriented, with approximately 33 km long, there are 34 known uranium mineralized areas. In its central-south portion is located anomaly 03 (AN03), named Lagoa da Rabicha, discovered and mapped by NUCLEBRAS (Brazilian Nuclear Enterprises), in the 80s. The Cachoeira Mine (AN13), located in northern PULR, is currently the only uranium mine in production in Brazil and even in South America. Nowadays it is observed a growth in energy demand in Brazil and also worldwide and studies and research applied to the petrogenetic uranium deposits are relevant both to be able to increase their potential for exploration and to assist in the possible future occurrences discovery. In recent years, fluid inclusions analysis (FI) have been widely used to study the genesis of uranium deposits in PULR and even thought there are still doubts about the uranium mineralization metallogenesis at Lagoa Real. Therefore, this work aimed to study the minerals and fluids associated with Lagoa da Rabicha albitites uraniferous and gneissic host rocks. In this way it was prepared an overview of the fluids found in this sector, establishing a comparison with several authors' studies in this and others Lagoa Real anomalies, trying to show the solutions evolution, at the same time that happened the uraninite precipitation. Petrography, electronic microprobe, laser ablation (LA-ICP-MS) and fluid inclusion studies were the applied methodologies. The fluids inclusions assemblages present in pyroxene, garnet and plagioclase, the main mineralogical constituents, were studied. The older fluid was found in aegirine-augite pyroxene and had aquo-saline composition (without carbonic phases) with Ca, Fe and Mg, 9-13 wt% NaCl salinities and homogenization temperatures between 220 and 290 deg C. Concomitantly, occurred a

  1. Punta Pitt, Galapagos Ba/Ca Data for 1963-1982

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — File contains Ba/Ca data (in mmol/mol) presented by Lea et al. (1989). Samples were measured at the Massachusetts Institute of Technology by D. Lea. Ba...

  2. Determination of the UO2-ZrO2-BaO equilibrium diagram

    International Nuclear Information System (INIS)

    Paschoal, J.O.A.; Kleykanp, H.; Thuemmler, F.

    1984-01-01

    It is determined the equilibrium diagram of UO 2 - ZrO 2 - BaO to interpret and predict changes in the chemical properties of ceramic (oxide) nuclear fuels during irradiation. The isothermal section of the system at 1700 0 C was determined experimentally, utilizing the techniques of ceramography, X-ray diffraction analysis, microprobe analysis and differential thermal analysis. The solid solubility limits at 1700 0 C between UO 2 and ZrO 2 , UO 2 and BaO, ZrO 2 and BaO, ZrO 2 and BaO and BaUO 3 and BaZrO 3 is presented. The influence of oxygen potential in relation to the different phases is discussed and the phase diagram of the system presented. (M.C.K.) [pt

  3. Left posterior BA37 is involved in object recognition: a TMS study

    DEFF Research Database (Denmark)

    Stewart, Lauren; Meyer, Bernd-Ulrich; Frith, Uta

    2001-01-01

    Functional imaging studies have proposed a role for left BA37 in phonological retrieval, semantic processing, face processing and object recognition. The present study targeted the posterior aspect of BA37 to see whether a deficit, specific to one of the above types of processing could be induced...... to name pictures when TMS was given over lBA37 compared to vertex or rBA37. rTMS over lBA37 had no significant effect on word reading, nonword reading or colour naming. The picture naming deficit is suggested to result from a disruption to object recognition processes. This study corroborates the finding...... from a recent imaging study, that the most posterior part of left hemispheric BA37 has a necessary role in object recognition....

  4. Particle-hole states in 138Ba

    International Nuclear Information System (INIS)

    Bondarenko, V.A.; Khitrov, V.A.; Popov, Yu.P.; Brant, S.; Paar, V.; Simicic, L.

    1995-01-01

    The thermal-neutron-capture gamma rays and γγ-coincidences were measured by means of Ge detectors. Using primary and secondary (n, γ) data, the level scheme of 138 Ba was established with 63 levels up to an excitation energy of 5 MeV. The level energies and (d, p) transfer data were compared with model predictions of the interacting boson-fermion-fermion model. As shown, this model provides a basic understanding of the neutron particle-hole states of 138 Ba in the energy range of 3.5-5.0 MeV. ((orig.))

  5. Continuing education in radiation protection in the nuclear fuel cycle: The case of Nuclear Industries of Brazil

    International Nuclear Information System (INIS)

    Souza Pereira, W. de; Kelecom, A.

    2014-01-01

    This paper describes the pedagogical and technical concept that guided training in radiation protection implemented by the Indústrias Nucleares do Brasil (INB; Nuclear Industries of Brazil) to maintain the competence of its technical staff to perform activities with exposure to radiation, the staff responsible for the supervision of this work and as a form of dissemination of knowledge to the staff not involved in the use of ionizing radiation. The groups of workers to be trained are here described, as well as the level of training, the frequency and types of training, the profile of trainers, the training programs, the forms of assessment and recording of training. It also describes the first general training performed in 2004. After this initial training no other general training was realized, and the option was to train small groups of workers, to avoid stopping the production as it occurred when general training was executed. The overall training was conducted in three units: the Uranium Concentration Unit (URA) under production in the city of Caetité, state of Bahia, the Ore Treatment Unit (UTM) undergoing decommissioning at Poços de Caldas, state of Minas Gerais and the Unit of Heavy Minerals (UMP), at Buena, state of Rio de Janeiro. In the initial training at URA 79 workers were trained, distributed in 6 classes (average of 13 students per class); each class had nine hours training and the grades obtained ranged from 7.5 to 10. At UTM, 200 employees were trained distributed in 9 classes (average of 22 students per class); their notes ranged from 8.8 to 10. Finally, at UMP 151 employees were trained, in 5 classes (average of 31 students per class); their grades ranged from 8.6 to 9.0. That year, a total of 180 hours were spent for training 430 employees, with no effective rebuke. Currently employees are trained when they arrive at their Units, and all along the year in small classes, as the general training has been definitely abolished. (author)

  6. The BaBar Data Acquisition System

    CERN Document Server

    Scott, I; Grosso, P; Huffer, M E; O'Grady, C; Russell, J J

    1999-01-01

    The BaBar experiment at the Stanford Linear Accelerator Center is designed to perform a search for CP violation by ana-lyzing the decays of a very large sample of B and B(Bar) mesons produced at the high luminosity PEP-II accelerator. The data acquisition system must cope with a sustained high event rate, while supporting real time feature extraction and data compression with minimal dead time. The BaBar data acquisition system is based around a common VME interface to the electronics read-out of the separate detec-tor subsystems. Data from the front end electronics is read into commercial VME processors via a custom "Personality Card" and PCI interface. The commercial CPUs run the Tornado operating system to provide a platform for detector subsystem code to perform the necessary data processing. The data is read out via a non-blocking network switch to a farm of commercial UNIX processors. The current implementation of the BaBar data acquisition sys-tem has been shown to sustain a Level 1 trigger rate of 1.3...

  7. Proton microbeam irradiation effects on PtBA polymer

    Indian Academy of Sciences (India)

    Microbeam irradiation effects on poly-tert-butyl-acrylate (PtBA) polymer using 2.0 MeV proton microbeam are reported. Preliminary results on pattern formation on PtBA are carried out as a function of fluence. After writing the pattern, a thin layer of Ge is deposited. Distribution of Ge in pristine and ion beam patterned surface ...

  8. Parasites infecting the cultured oyster Crassostrea gasar (Adanson, 1757) in Northeast Brazil.

    Science.gov (United States)

    Queiroga, Fernando Ramos; Vianna, Rogério Tubino; Vieira, Cairé Barreto; Farias, Natanael Dantas; Da Silva, Patricia Mirella

    2015-05-01

    The oyster Crassostrea gasar is a species widely used as food and a source of income for the local population of the estuaries of Northeast Brazil. Perkinsus marinus and Perkinsus olseni are deleterious parasites for oyster farming and were recently detected in Brazil. In this study, a histopathologic survey of the oyster C. gasar cultured in the estuary of the River Mamanguape (Paraíba State) was performed. Adult oysters were collected in December 2011 and March, May, August and October 2012 and processed for histology and Perkinsus sp. identification by molecular analyses. Histopathological analysis revealed the presence of parasitic organisms including viral gametocytic hypertrophy, prokaryote-like colonies, protozoans (Perkinsus sp. and Nematopsis sp.) and metazoans (Tylocephalum sp. and cestodes). Other commensal organisms were also detected (the protozoan Ancistrocoma sp. and the turbellarian Urastoma sp.). The protozoan parasite Perkinsus sp. had the highest overall prevalence among the symbiotic organisms studied (48.9%), followed by Nematopsis sp. (36.3%). The other organisms were only sporadically observed. Only the protozoan Perkinsus sp. caused alterations in the oysters' infected organs. Molecular analyses confirmed the presence of P. marinus, P. olseni and Perkinsus beihaiensis infecting the oyster C. gasar. This is the first report of P. beihaiensis in this oyster species.

  9. The 226Ra-Ba relationship in the North Atlantic during GEOTRACES-GA01

    Science.gov (United States)

    Le Roy, Emilie; Sanial, Virginie; Charette, Matthew A.; van Beek, Pieter; Lacan, François; Jacquet, Stéphanie H. M.; Henderson, Paul B.; Souhaut, Marc; García-Ibáñez, Maribel I.; Jeandel, Catherine; Pérez, Fiz F.; Sarthou, Géraldine

    2018-05-01

    We report detailed sections of radium-226 (226Ra, T1/2 = 1602 years) activities and barium (Ba) concentrations determined in the North Atlantic (Portugal-Greenland-Canada) in the framework of the international GEOTRACES program (GA01 section - GEOVIDE project, May-July 2014). Dissolved 226Ra and Ba are strongly correlated along the section, a pattern that may reflect their similar chemical behavior. Because 226Ra and Ba have been widely used as tracers of water masses and ocean mixing, we investigated their behavior more thoroughly in this crucial region for thermohaline circulation, taking advantage of the contrasting biogeochemical patterns existing along the GA01 section. We used an optimum multiparameter (OMP) analysis to distinguish the relative importance of physical transport (water mass mixing) from nonconservative processes (sedimentary, river or hydrothermal inputs, uptake by particles and dissolved-particulate dynamics) on the 226Ra and Ba distributions in the North Atlantic. Results show that the measured 226Ra and Ba concentrations can be explained by conservative mixing for 58 and 65 % of the samples, respectively, notably at intermediate depth, away from the ocean interfaces. 226Ra and Ba can thus be considered conservative tracers of water mass transport in the ocean interior on the space scales considered here, namely, on the order of a few thousand kilometers. However, regions in which 226Ra and Ba displayed nonconservative behavior and in some cases decoupled behaviors were also identified, mostly at the ocean boundaries (seafloor, continental margins and surface waters). Elevated 226Ra and Ba concentrations found in deepwater in the West European Basin suggest that lower Northeast Atlantic Deep Water (NEADWl) accumulates 226Ra and Ba from sediment diffusion and/or particle dissolution during transport. In the upper 1500 m of the West European Basin, deficiencies in 226Ra and Ba are likely explained by their incorporation in planktonic calcareous

  10. Perceptions of termites in urban areas of semiarid Brazil

    Directory of Open Access Journals (Sweden)

    Maria Avany Bezerra Gusmão

    2014-07-01

    Full Text Available http://dx.doi.org/10.5007/2175-7925.2014v27n4p117 Perception of termites in urban areas of semiarid Brazil. Termites are present in the daily life of most people, although they usually evoke a sense of strong dislike, especially in populations of urban areas. This study sought to analyze the perception of these insects in human populations in urban areas in the towns of Fagundes (A1 and Pocinhos (A2, in Paraíba state, Brazil. Semi-structured questionnaires were answered by 100 residents in these two areas, following both synchronic and diachronic situations. In spite of the fact that most of the interviewees (64% in A1 and 72% in A2 were able to identify termites by morphology and had knowledge of use for treating eight types of human diseases, very few understood their ecological roles in nature. Attempts to eliminate termites from human environments were linked to the popular belief that these animals are sources of bad luck. Twenty-two percent of the interviewees in A1 and 8% in A2 believe that termites are capable of doing damage or harm, of having a foul smell, and/or of containing pus.In this sense, academic studies are important because they can inform people of the ecological roles of termites in natural and urban environments, while demystifying the termite as an agent of fear and destruction.

  11. Tritellurides of comples cations: Synthesis and crystal structure of (Ba(en)/sub 3/)Te/sub 3/ and (Ba(en)/sub 4,5/)Te/sub 3/

    Energy Technology Data Exchange (ETDEWEB)

    Zagler, R; Eisenmann, B; Schaefer, H

    1987-02-01

    The two title compounds have been prepared by reaction of appropriate mixtures of the elements in ethylenediamine. The structures have been determined on the basis of single crystal data. (Ba(en)/sub 3/Te/sub 3/ crystallizes in the monoclinic system, space group P2/sub 1/c with a = 918.0(4), b = 1203.7(6), c = 1639,9(6) pm, ..beta.. = 93.4(1)/sup 0/. In the structure there are bent tritelluride anions Te/sub 3//sup 2 -/ (bond lengths 273,9-278,5 pm, bond angle (105.7/sup 0/). The Ba/sup 2 +/ cations are six coordinate by the bidentate ligand ethylenediamine. (Ba(en)/sub 4,5/)Te/sub 3/ crystallizes in the monoclinic system, space group Cc with a = 1752.8(6), b = 938.9(4), c = 3041.7(8) pm, ..beta.. = 91.3(1)/sup 0/. In this structure the bond lengths in the TE/sub 3//sup 2 -/ anions are shorter (272.1-273.1 pm, bond angles 110.9-112.2/sup 0/). The cations are coordinated by four bidentate ligands, and are connected into pairs by a further ethylenediamine molecule. The resulting dinuclear (Ba(en)/sub 4/)en(Ba(en)/sub 4/)/sup 4 +/ units have the Ba/sup 2 +/ cations in CN 9.

  12. Natural and experimental poisoning by Cestrum laevigatum (Solanaceae among cattle in the Agreste region of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Temístocles Soares de Oliveira Neto

    2017-10-01

    Full Text Available An outbreak of natural poisoning by Cestrum laevigatum was reported among cattle in the Agreste region of Paraíba, which affected six out of 20 animals. Four animals were found dead and two presented clinical signs, including, dyspnea, drooling, jugular vein engorgement, muscle tremors and ataxia, which subsequently progressed to recumbence and death. An experimental poisoning was performed in two bovines who were administered single doses of 35 g kg-1 and 50 g kg-1 body weight (BW, respectively, of fresh leaves and fruits. The animal that received 35 g kg-1 BW had mild clinical signs, consisting of apathy, salivation and reduced ruminal movements with recovery 30 hours after the onset of initial signs. The animal that received 50 g kg-1 BW showed apathy, dry stool, drooling, hyperexcitability, head pressing, opisthotonos, nystagmus, miosis, jugular and episcleral vessel engorgement, ruminal atony, muscle tremors, ataxia, falling, seizures, and sternal recumbence, followed by lateral recumbence, with death occurring 21 hours and 37 minutes after ingestion. The enzyme activities of aspartate aminotransferase and gamma-glutamyltransferase in the serum increased significantly 18 hours after the administration of the plant. The primary gross lesions in the natural and experimental cases were enlarged livers, with rounded edges and accentuation of the lobular pattern on the capsular and cut surfaces. Histopathology revealed diffuse centrilobular coagulative necrosis with hemorrhages and congestion, and the presence of degenerated hepatocytes in the midzonal regions. Based on the epidemiological and clinicopathological data, we concluded that C. laevigatum was responsible for an acute hepatotoxic disease among cattle in the Agreste region of Paraíba.

  13. Earth Observation for Biodiversity Assessment (EO-BA)

    CSIR Research Space (South Africa)

    Cho, Moses A

    2012-10-01

    Full Text Available in the Dukuduku coastal forest Earth Observation for Biodiversity Assessment (EO-BA) MA CHO, P DEBBA, R MATHIEU, A RAMOELO, L NAIDOO, H VAN DEVENTER, O MALAHLELA AND R MAIN CSIR Natural Resources and the Environment, Pretoria, South Africa PO Box 395... Observation for Biodiversity Assessment (EO-BA) programme is designed to enhance biodiversity assessment and conservation through the application of earth observation data, with particular focus on the African continent. MISSION To initiate and develop...

  14. Food and nutrition security in families with children under five years old in the city of Campina Grande, Paraíba.

    Science.gov (United States)

    Pedraza, Dixis Figueroa; Gama, Jacqueline Santos da Fonsêca Almeida

    2015-01-01

    To estimate the prevalence and identify the socioeconomic risk factors for food insecurity in households with children under five years in the city of Campina Grande, Paraíba. This cross-sectional study involved 793 families with children assisted in municipal day care centers in Campina Grande, Paraíba, Brazil. Household socioeconomic variables were analyzed as the possible predictors of mild food insecurity and moderate/severe food insecurity. For the evaluation of food and nutrition security of households, the Brazilian Food Insecurity Scale was used. Mild food insecurity was characterized in 37.6% of families, and moderate/severe food insecurity affected 31.6% of households. Regarding the household socioeconomic variables, none was associated with mild food insecurity. Meanwhile, the highest prevalence of moderate/severe food insecurity, when compared with reference categories, was present in households without water treatment for drinking purposes, with toilets that are not flushable and individual, with larger families, and without a refrigerator. Being a beneficiary, or not, of the social welfare program "Bolsa Familia" did not represent a factor associated with food insecurity. The results show high rates of food insecurity with the most severe degrees being related to factors dependent on the family purchasing power, indicating a major challenge for them.

  15. 40 CFR 721.10010 - Barium manganese oxide (BaMnO3).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Barium manganese oxide (BaMnO3). 721... Substances § 721.10010 Barium manganese oxide (BaMnO3). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as barium manganese oxide (BaMnO3) (PMN P-00...

  16. Training in radioprotection in INB - Brazilian Nuclear Industries

    International Nuclear Information System (INIS)

    Pereira, Wagner de S.; Py Junior, Delcy de A.; Taddei, Jose F.C.; Dias, Pedro L. dos S.; Iatesta, Antonio

    2005-01-01

    This work describes the ideas that guided the training in radiation protection and the first results obtained in the first half of 2004. The training took place in the Uranium Concentrate Unit URA, in Caetite, BA, in the Ore Treatment Unit - UTM, in Caldas, MG, and in the Heavy Mineral Unit - UMP, in San Francisco de Itabapuana, RJ, Brazil. In URA it was spent 9 days. 79 students were trained in 6 classes (average 13 pupils per class). Each group spent 9 hour of training, for a total of 54 hours of training given. There was no disapproval, and the grade average of the students was 9.2, with the lowest grade 7.5 and the highest 10.0. In UTM, it was spent 9 days. 200 students were trained in 9 classes (an average of 22 students per class). Each class spent 9h of training, totaling 81 hours. There were 18 deprecations, due to the the lack of education of the students. The overall average of the grades was 8.8, with lower note zero and higher 10.0. In UTM 158 people were trained in 5 classes, with an average of 31 students per class.It is concluded that in classes with few students (7 to 12) there were few parallel discussions. In classes with many students (over thirty) there was a scattering of ideas, which interfered in the progress of training. As proposal for upcoming classes can be suggested an average 20 people per class. The division of classes in groups working together was beneficial, giving a unit, which allowed greater freedom in questions, increasing parallel content taught. The classes have evaluated positively the initiative of the work done, which will be extended to other units of DRM, and subsequently all of the INB - Brazilian Nuclear Industries

  17. Socioeconomic factors, nutritional risk, and enamel defects in children from João Pessoa, Paraíba State, Brazil

    OpenAIRE

    Massoni, Andreza Cristina de Lima Targino; Oliveira, Andressa Feitosa Bezerra de; Chaves, Ana Maria Barros; Sampaio, Fábio Correia; Rosenblatt, Aronita

    2007-01-01

    O objetivo deste estudo foi verificar fatores associados ao risco nutricional ao longo do primeiro ano de vida em crianças de baixo nível sócio-econômico de João Pessoa, Paraíba, Região Nordeste do Brasil. E determinar a freqüência de defeitos do esmalte, associando-a ao risco nutricional. O estudo foi realizado com 117 crianças, 56 com risco nutricional e 61 eutróficas. Em domicílio, realizaram-se avaliação nutricional, exame clínico dos elementos dentais e entrevistas com as mães. Na matern...

  18. Characterization of the insulator barrier and the superconducting transition temperature in GdBa2Cu3O7−δ/BaTiO3 bilayers for application in tunnel junctions

    International Nuclear Information System (INIS)

    Navarro, H.; Sirena, M.; Haberkorn, N.; Yang, Ilkyu; Kim, Jeehoon

    2015-01-01

    The optimization of the superconducting properties in a bottom electrode and the quality of an insulator barrier are the first steps in the development of superconductor/insulator/superconductor tunnel junctions. Here, we study the quality of a BaTiO 3 tunnel barrier deposited on a 16 nm thick GdBa 2 Cu 3 O 7−δ thin film by using conductive atomic force microscopy. We find that the tunnel current is systematically reduced (for equal applied voltage) by increasing the BaTiO 3 barrier thickness between 1.6 and 4 nm. The BaTiO 3 layers present an energy barrier of ≈1.2 eV and an attenuation length of 0.35–0.5 nm (depending on the applied voltage). The GdBa 2 Cu 3 O 7−δ electrode is totally covered by a BaTiO 3 thickness above 3 nm. The presence of ferroelectricity was verified by piezoresponse force microscopy for a 4 nm thick BaTiO 3 top layer. The superconducting transition temperature of the bilayers is systematically suppressed by increasing the BaTiO 3 thickness. This fact can be associated with stress at the interface and a reduction of the orthorhombicity of the GdBa 2 Cu 3 O 7−δ . The reduction in the orthorhombicity is expected by considering the interface mismatch and it can also be affected by reduced oxygen stoichiometry (poor oxygen diffusion across the BaTiO 3 barrier)

  19. Left cytoarchitectonic BA 44 processes syntactic gender violations in determiner phrases.

    Science.gov (United States)

    Heim, Stefan; van Ermingen, Muna; Huber, Walter; Amunts, Katrin

    2010-10-01

    Recent neuroimaging studies make contradictory predictions about the involvement of left Brodmann's area (BA) 44 in processing local syntactic violations in determiner phrases (DPs). Some studies suggest a role for BA 44 in detecting local syntactic violations, whereas others attribute this function to the left premotor cortex. Therefore, the present event-related functional magnetic resonance imaging (fMRI) study investigated whether left-cytoarchitectonic BA 44 was activated when German DPs involving syntactic gender violations were compared with correct DPs (correct: 'der Baum'-the[masculine] tree[masculine]; violated: 'das Baum'--the[neuter] tree[masculine]). Grammaticality judgements were made for both visual and auditory DPs to be able to generalize the results across modalities. Grammaticality judgements involved, among others, left BA 44 and left BA 6 in the premotor cortex for visual and auditory stimuli. Most importantly, activation in left BA 44 was consistently higher for violated than for correct DPs. This finding was behaviourally corroborated by longer reaction times for violated versus correct DPs. Additional brain regions, showing the same effect, included left premotor cortex, supplementary motor area, right middle and superior frontal cortex, and left cerebellum. Based on earlier findings from the literature, the results indicate the involvement of left BA 44 in processing local syntactic violations when these include morphological features, whereas left premotor cortex seems crucial for the detection of local word category violations. © 2010 Wiley-Liss, Inc.

  20. Luminescent properties of BaCl2-Eu microcrystals embedded in a CsI matrix

    International Nuclear Information System (INIS)

    Pushak, A.; Vistovskyy, V.; Voloshinovskii, A.; Savchyn, P.; Antonyak, O.; Demkiv, T.; Dacyuk, Yu.; Myagkota, S.; Gektin, A.

    2013-01-01

    The spectral-luminescent properties of CsI-BaCl 2 (1 mol%)-Eu(0.02 mol%) crystalline system are studied. Europium ion doped BaCl 2 microcrystals embedded in a CsI matrix are revealed on CsI-BaCl 2 (1 mol%)-Eu(0.02 mol%) freshly cleaved surface by the scanning electron microscopy. The size of microcrystals is shown to be within 0.5–5 microns. The luminescent parameters of the BaCl 2 -Eu 2+ microcrystals are shown to be similar to ones of a single crystal analogue. The 4f → 5d absorption transitions in europium ions and the reabsorption of the intrinsic emission of the CsI host are the main excitation mechanisms of europium luminescence in the BaCl 2 microcrystals. -- Highlights: ► The formation of chloride BaCl 2 :Eu microcrystals in the case of BaCl 2 doped CsI crystal has been revealed. ► The observed size of microcrystals at BaCl 2 concentration of 1% is about 0.5–5 μm. ► Majority of Eu 2+ ions in CsI-BaCl 2 -EuCl 3 crystalline system enters into BaCl 2 microcrystals. ► The luminescent parameters of the BaCl 2 :Eu 2+ microcrystals and its bulk analogue are similar

  1. Quo Vadis the B.A. degree: Perceptions and visions1

    Directory of Open Access Journals (Sweden)

    Annette L. Combrink

    1993-03-01

    Full Text Available Today is a very special day for all the graduates assembled to have a B.A. degree conferred on them. It is a day on which to celebrate the reward for hard work and for realized dreams. This is a very homogeneous group of people - in the sense that they will be receiving B.A. degrees, and for that reason it would be highly apposite to share some cherished thought and ideas about the B.A. degree.

  2. Anti-Leptospira spp. antibodies in captive animals in Paraíba State

    Directory of Open Access Journals (Sweden)

    Arthur Brasil

    2013-12-01

    Full Text Available The aim of this survey was to verify the occurrence of anti-Leptospira spp. antibodies in captive animals in the Parque Zoobotânico Arruda Câmara, João Pessoa, Paraíba State, Northeastern Brazil. Blood samples were collected from 49 animals: 26 mammals of the species Sapajus libidinosus, Cebus flavius, Saimiri sciureu, Coendu sp., Pseudalopex vetulus, Leopardus pardalis, Leopardus tigrinus, Galactitis vitata, Eira barbara, Nasua nasua, Tayassu tajacu and Ratus norvegicus; 10 birds of the species Penelope jacucaca, Pavo cristatus, Anodorhynchus hyacinthinus, Ara chlorothpterus, Pionites leucogaster, Polyborus plancus, Geranoaetus melanoleucus and Urubitinga urubitinga; and 13 reptiles of the species Caiman latirostris, Paleosuchus trigonatus, Caiman crocodilus, Tupinabis merinae, Tupinambis teguixin, Boa constrictor, Corallus hortulanus, Python molurus, Bufocephala vanderhaegei, Geochelone denticulata and Geochelone carboraria. Sera were examined by the microscopic agglutination teste (MAT using 24 serovars as antigens and cut-off point of 1:100. One ocelot (Leopardo pardalis presented positive reaction for the Icterohaemorrhagiae serovar with titer of 100, however, it did not show any clinical sign of the infection. Sinantropic rodents are the main reservoirs of this serovar, which suggests the need of maintenance and continuous evaluation of rodent control programs.

  3. Estudo ecológico e zoogeográfico sobre a fauna de lagartos (Sauria das dunas de Natal, Rio Grande do Norte e da Restinga de Ponta de Campina, Cabedelo, Paraíba, Brasil Ecologic and zoogeographic study on a fauna of lizards (Sauria from Dunas of Natal, Rio Grande do Norte and from Restinga de Ponta de Campina, Cabedelo, Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Eliza Maria Xavier Freire

    1996-01-01

    Full Text Available An inventory of the fauna of lizards was made in the dunes of Natal (Rio Grande do Norte, Brazil and in the "restingas" (sandbanks with its associated vegetation of Ponta de Campina (Cabedelo, Paraíba, Brazil from October/84 to March/86. The objective was to know the composition and structure of these communities as well as to evaluate the zoogeographical importance of the spots. The samples were collected and the observations were made along of transects which were established to enable the sampling of the habitats under study in both areas. Each transect was crossed one day per month, during 14 months. The collect of lizards was made manually or through the use of a small gun, calibre 22, with ammunition of the type mustard lead. Observations were made on the habitats utilized by the species (open areas or forests and on the species distribution by microhabitat. The fauna of lizards in the area under study is formed by species ecologically connected with open formations and also by species of the Atlantic Rain Forest. The majority of the species collected in the open areas is part of the fauna of the great diagonal of open formations which come from the Northeast of Argentina and go up to the state of Maranhão. There is, however, a great influence of the caatinga fauna, specially in the dunes of Natal. The species found in the forest of the dunes, in spite of being part of the Atlantic Forest, are morphologically differentiated. Gymnodactylus darwinii (Gray, 1845 and G. geckoides Spix, 1825 are sympatrics, but not syntopics, in the dunes of Natal.

  4. THINNING OF ‘GALA’ AND 'GOLDEN DELICIOUS' APPLES WITH BA, NAA AND THEIR COMBINATIONS

    Directory of Open Access Journals (Sweden)

    M STOPAR

    2002-07-01

    Full Text Available Apple trees, eight-year-old ‘Gala’/M.9 and four-year-old ‘Golden Delicious’/M.9 have been thinned with 6- benzyladenine (BA 50 ppm, 100 ppm and 200 ppm, with 1-naphthaleneacetic acid (NAA 5 ppm, 10 ppm and 20 ppm, and with the tank mix combinations of BA 50 ppm + NAA 5 ppm or BA 20 ppm + NAA 5 ppm, all at 9-10 mm fruitlet diameter. All applied concentrations of BA and NAA thinned both cultivars significantly and no significant difference was found between BA or NAA thinning action. No concentration response on thinning was observed with neither BA nor NAA application. All BA or NAA separate treatments caused yield of fruit to shift to bigger size class. The only concentration response effect was found on evaluation of mean fruit weight data on ‘Golden Delicious’. The higher concentration of BA was used, the higher was the weight of ‘Golden Delicious’ fruit. On the opposite, the higher concentration of NAA was used, the lower was the weight of ‘Golden Delicious’ fruit (not significantly. When BA and NAA were sprayed on ‘Gala’ or ‘Golden Delicious’ as a tank mix combination, similar effect on thinning or fruit growth occurred comparing to BA or NAA when sprayed alone. Return bloom was enhanced on all thinned ‘Gala’ trees while flower formation of ‘Golden Delicious’ was better in the case of BA 200 ppm, NAA 5 ppm, NAA 20 ppm or tank mix spraying of BA 20 ppm + NAA 5 ppm.

  5. Prevalence of Candida tropicalis and Candida krusei in onychomycosis in João Pessoa, Paraiba, Brazil from 1999 to 2010

    Directory of Open Access Journals (Sweden)

    JULIANA M.M. ARRUA

    2015-09-01

    Full Text Available ABSTRACTOver time, as the etiology of onychomycosis has developed, yeasts from the genus Candida have emerged as important etiological agents. This study aimed to determine the frequency of yeast caused onychomycosis in Joao Pessoa, Paraíba, Brazil from 1999 to 2010. A retrospective study from January 1999 to December 2010 evaluated the results of onychomycosis positive direct mycological exams (DME - for yeast and realized in the Hemato(r Clinical Laboratory. Women were the most affected by onychomycosis which occur preferentially in adults, and the toenails are the favorite yeast targets. The prevalent yeasts were Candida tropicalis and C. krusei.

  6. Application of NAA and BA in chemical thinning of some commercial apple cultivars

    Directory of Open Access Journals (Sweden)

    Šebek Gordana

    2015-01-01

    Full Text Available This paper presents the fruit thinning response of some commercial apple cultivars to NAA and BA plant regulators. The experiment was designed to evaluate NAA applied separately at three concentrations - 13.2 ppm, 17.82 ppm and 26.73 ppm, and BA + NAA combinations (BA - 60 ppm, 100 ppm, 120 ppm or 140 ppm + NAA 4.29 ppm for thinning the assessed apple cultivars. All treatments with NAA and BA + NAA adequately thinned 'McIntosh' and 'Jonathan', whereas the application of NAA 17.82 ppm and 26.73 ppm and the combined treatment BA 140 ppm+ NAA 4.29 ppm were effective fruit thinners for 'Prima'. In terms of the average fruit weight, number of fruits categorized as large (> 75 mm or > 65 mm, and number of fruit per trunk cross-sectional area, the treatment BA 140 ppm + NAA 4.29 ppm was most effective on 'McIntosh' and 'Prima', whereas BA 100 ppm + NAA 4.29 ppm had the best effect on 'Jonathan'.

  7. Epitaxial thin-film growth of Ruddlesden-Popper-type Ba{sub 3}Zr{sub 2}O{sub 7} from a BaZrO{sub 3} target by pulsed laser deposition

    Energy Technology Data Exchange (ETDEWEB)

    Butt, Shariqa Hassan; Rafique, M.S.; Siraj, K.; Latif, A.; Afzal, Amina [University of Engineering and Technology, Laser and Optronics Centre, Department of Physics, Lahore (Pakistan); Awan, M.S. [Ibn-e-Sina Institute of Science and Technology (ISIT), Islamabad (Pakistan); Bashir, Shazia [Government College University, Centre for Advanced Studies in Physics, Lahore (Pakistan); Iqbal, Nida [Universiti Teknologi Malaysia, Medical Devices and Technology Group (MEDITEG), Faculty of Biosciences and Medical Engineering, Johor Bahru, Johor (Malaysia)

    2016-07-15

    Ruddlesden-Popper Ba{sub 3}Zr{sub 2}O{sub 7} thin films have been synthesized via pulsed laser deposition (PLD) technique. The optimization of deposition parameters in PLD enables the formation of thin film of metastable Ba{sub 3}Zr{sub 2}O{sub 7} phase from BaZrO{sub 3} target. In order to see the post-annealing effects on the structural and optical properties, the deposited Ba{sub 3}Zr{sub 2}O{sub 7} thin films were annealed at 500, 600 and 800 C. X-ray diffraction (XRD) reveals the formation of Ba{sub 3}Zr{sub 2}O{sub 7} phase with tetragonal structure. The changes in the surface of the deposited films were analysed by FE-SEM and AFM. The thin film post-annealed at 500 C exhibited the best structural, optical and surface properties. Furthermore, the chemical states and chemical composition of the films were determined by X-ray photoelectron spectroscopy (XPS) near the surface. The XPS results show that Ba, Zr and O exist mainly in the form of Ba{sub 3}Zr{sub 2}O{sub 7} Ruddlesden-Popper-type perovskite structure. (orig.)

  8. Baština Starog grada Zrinskih

    OpenAIRE

    Kovač, Ivana

    2017-01-01

    Stari grad Zrinskih priča bogate, zanimljive i velike priče u svakom svojem kutku. Dvorac je prepun kulturne baštine koja će svakog ostaviti bez daha i dat će nam nove poglede na hrvatsku povijest, a još više na međimursku povijest. U ovom završnom radu pisat ću o ljepotama kraja, povijesnim zbivanjima i kulturnoj baštini grada, od samog početka pa do danas. Posebno ću se posvetiti predmetima koji su nam ostavili naši preci, a najviše umjetnosti grada i okolice. Čakovečki stari grad ima djelo...

  9. Magnetic and electrical properties in BaNiS2-type solid solutions

    International Nuclear Information System (INIS)

    Irizawa, Akinori; Yoshimura, Kazuyoshi; Kosuge, Koji

    2000-01-01

    The magnetic and electrical properties are reported in the new solid solutions BaCo 1-x Cu x S 2 and BaNi 1-x Fe x S 2 . Both compounds show spin-glass-like behavior, although the type of spin frustrations is different with each other. BaCo 1-x Cu x S 2 shows a competition type spin-glass behavior with reentrant phenomenon from antiferromagnetic to spin-glass at low temperatures. BaNi 1-x Fe x S 2 shows a dilute type spin-glass behavior together with super-paramagnetic properties. The temperature variation of 57 Fe Moessbauer spectra in BaNi 0.8 Fe 0.2 S 2 is explicable in a framework of cluster-glass. (author)

  10. A new spiny species of Hypostomus Lacépède (Loricariidae: Hypostominae from thermal waters, upper rio Paraná basin, central Brazil

    Directory of Open Access Journals (Sweden)

    Fernanda O. Martins

    Full Text Available A new species of Hypostomus is described from the rio Quente, rio Paranaíba drainage, in the upper rio Paraná basin in central Brazil. The rio Quente is a peculiar small and shallow fast water stream with water temperatures around 34ºC. The new species is distinguished from all congeners by having the five lateral series of plates with hypertrophied odontodes not aligned in rows and more conspicuous on flanks of caudal peduncle of the larger specimens. The new species is only known from the rio Quente.

  11. Opening up Brazil's hydrocarbon sector - the Bolivia-Brazil pipeline

    International Nuclear Information System (INIS)

    Law, P.

    2000-01-01

    The Bolivia-Brazil natural gas pipeline, which transports natural gas more than 3000 km from Bolivia to Brazil, cost US$2.1 billion to construct. Despite the substantial benefits for both Bolivia and Brazil and the involvement of reputable private partners, the perceived risks and complexities of this large project made financing it major challenge. neither of these countries has had a tradition of independent regulation or economic fuel pricing, and the pipeline was the first major gas infrastructure project involving the private sector in Brazil. The presentation explains the historical features of the project and how the project was used to open up Brazilian oil and gas sector to private investment and competition. (author)

  12. Dynamic and resuspension by waves and sedimentation pattern definition in low energy environments: guaíba lake (Brazil

    Directory of Open Access Journals (Sweden)

    João Luiz Nicolodi

    2013-03-01

    Full Text Available Little research has been undertaken into sediment dynamics in lakes, and most of it only analyses particular aspects such as the texture of the sediments. In this study, the characteristics of the wave field in Guaíba Lake are investigated. The parameters significant wave height (Hs, period (T and direction of wave propagation are examined together with their relation to the resuspension of sediments at the bottom. For this purpose, the mathematical model SWAN (Simulating Waves Nearshore has been validated and employed. The results pointed out that the highest waves modeled reached 0.55 m at a few points in the lake, particularly when winds were blowing from the S and SE quadrants with an intensity over 7 m.s-1. Generally speaking, waves follow wind intensity and direction patterns, and reach maximum height in about 1 to 2 hours after wind speed peaks. Whenever winds were stronger, waves took some 2 hours to reach 0.10 m. However, with weak to moderate winds, the waves took around 3 hours to achieve this value in significant wave height. In addition to speed and direction, wind regularity proved relevant in generating and propagating waves on Lake Guaíba. In conclusion the lake's sediment environments were mapped and classified as follows: 1 Depositional Environments (51% of the lake; 2 Transitional Environments (41%; and 3 Erosional or Non-Depositional Environments (8%. As a contribution to the region's environmental management, elements have been created relating to the concentration of suspended particulate matter.Pesquisas referentes à dinâmica sedimentar em lagos são escassas e a maioria trata da distribuição e textura dos sedimentos, sendo raras aquelas que fazem menção ao padrão de ondas e suas relações com a ressuspensão destes sedimentos e suas consequências. Este trabalho analisa as características das ondas incidentes no Lago Guaíba (Brasil por meio da utilização do SWAN (Simulating Waves Nearshore e suas rela

  13. A reevaluation of the late quaternary sedimentation in todos os Santos Bay (BA, Brazil

    Directory of Open Access Journals (Sweden)

    GUILHERME C. LESSA

    2000-12-01

    Full Text Available Todos os Santos Bay is a large ( 1000 km², structurally controlled tidal bay in northeast Brazil. Three main drainage basins debouch into the bay, providing a mean freshwater discharge of 200 m³/s (prior to 1985, or less than 1% of the spring tidal discharge through the bay mouth. Based on the result of several sedimentological studies performed in the 1970's, five surface sedimentary facies were identified inside the bay, namely i transgressive siliciclastic marine sand facies; ii transgressive bay sand-mud facies; iii a transgressive carbonate marine sand facies; iv regressive bay-mud facies, and v regressive fluvial sand facies. The spatial distribution of these facies would follow, somewhat closely, the hydrodynamic-energy distribution inside the bay. Seismic profiles along the bay bottom indicate the existence of several paleochannels, 5-10 m deep, blanketed at least by three different sedimentary units. The topmost sedimentary unit, 5-20 m thick, appears to be associated with the regressive bay-mud facies, and assuming that it was laid down within the last 5000 years, sedimentation rates for the central and northeastern part of the bay would average at 2,4 mm/y.

  14. Photoluminescence properties of BaMoO4 amorphous thin films

    International Nuclear Information System (INIS)

    Marques, Ana Paula Azevedo; Melo, Dulce M.A. de; Longo, Elson; Paskocimas, Carlos A.; Pizani, Paulo S.; Leite, Edson R.

    2005-01-01

    BaMoO 4 amorphous and crystalline thin films were prepared from polymeric precursors. The BaMoO 4 was deposited onto Si wafers by means of the spinning technique. The structure and optical properties of the resulting films were characterized by FTIR reflectance spectra, X-ray diffraction (XRD), atomic force microscopy (AFM) and optical reflectance. The bond Mo-O present in BaMoO 4 was confirmed by FTIR reflectance spectra. XRD characterization showed that thin films heat-treated at 600 and 200 deg. C presented the scheelite-type crystalline phase and amorphous, respectively. AFM analyses showed a considerable variation in surface morphology by comparing samples heat-treated at 200 and 600 deg. C. The reflectivity spectra showed two bands, positioned at 3.38 and 4.37 eV that were attributed to the excitonic state of Ba 2+ and electronic transitions within MoO 2- 4 , respectively. The optical band gaps of BaMoO 4 were 3.38 and 2.19 eV, for crystalline (600 deg. C/2 h) and amorphous (200 deg. C/8 h) films, respectively. The room-temperature luminescence spectra revealed an intense single-emission band in the visible region. The PL intensity of these materials was increased upon heat-treatment. The excellent optical properties observed for BaMoO 4 amorphous thin films suggested that this material is a highly promising candidate for photoluminescent applications

  15. Stability of Tl-Ba-Ca-Cu-O superconducting thin films

    International Nuclear Information System (INIS)

    Siegal, M. P.; Overmyer, D. L.; Venturini, E. L.; Padilla, R. R.; Provencio, P. N.

    1999-01-01

    We report the stability of TlBa 2 CaCu 2 O 7 and Tl 2 Ba 2 CaCu 2 O 8 on LaAlO 3 (100) epitaxial thin films, under a variety of conditions. All films are stable in acetone and methanol and with repeated thermal cycling to cryogenic temperatures. Moisture, especially vapor, degrades film quality rapidly. These materials are stable to high temperatures in either N 2 or O 2 ambients. While total degradation, resulting from Tl depletion, occurs at the same temperatures for both phases, 600 degree sign C in N 2 and 700 degree sign C in O 2 , the onset of degradation occurs at somewhat lower temperatures for TlBa 2 CaCu 2 O 7 than for Tl 2 Ba 2 CaCu 2 O 8 . (c) 1999 Materials Research Society

  16. Performance simulation of BaBar DIRC bar boxes in TORCH

    Science.gov (United States)

    Föhl, K.; Brook, N.; Castillo García, L.; Cussans, D.; Forty, R.; Frei, C.; Gao, R.; Gys, T.; Harnew, N.; Piedigrossi, D.; Rademacker, J.; Ros García, A.; van Dijk, M.

    2017-12-01

    TORCH is a large-area precision time-of-flight detector based on the DIRC principle. The DIRC bar boxes of the BaBar experiment at SLAC could possibly be reused to form a part of the TORCH detector time-of-flight wall area, proposed to provide positive particle identification of low momentum kaons in the LHCb experiment at CERN. For a potential integration of BaBar bar boxes into TORCH, new imaging readout optics are required. From the several designs of readout optics that have been considered, two are used in this paper to study the effect of BaBar bar optical imperfections on the detector reconstruction performance. The kaon-pion separation powers obtained from analysing simulated photon hit patterns show the performance reduction for a BaBar bar of non-square geometry compared to a perfectly rectangular cross section.

  17. Synthesis, Crystal Structure, and Chemical-Bonding Analysis of BaZn(NCN2

    Directory of Open Access Journals (Sweden)

    Alex J. Corkett

    2017-12-01

    Full Text Available The ternary carbodiimide BaZn(NCN2 was prepared by a solid-state metathesis reaction between BaF2, ZnF2, and Li2NCN in a 1:1:2 molar ratio, and its crystal structure was determined from Rietveld refinement of X-ray data. BaZn(NCN2 represents the aristotype of the LiBa2Al(NCN4 structure which is unique to carbodiimide/cyanamide chemistry and is well regarded as being constructed from ZnN4 tetrahedra, sharing edges and vertices through NCN2− units to form corrugated layers with Ba2+ in the interlayer voids. Structural anomalies in the shape of the cyanamide units are addressed via IR spectrometry and DFT calculations, which suggest the presence of slightly bent N=C=N2− carbodiimide units with C2v symmetry. Moreover, chemical-bonding analysis within the framework of crystal orbital Hamilton population (COHP reveals striking similarities between the bonding interactions in BaZn(NCN2 and SrZn(NCN2 despite their contrasting crystal structures. BaZn(NCN2 is only the second example of a ternary post-transition metal carbodiimide, and its realization paves the way for the preparation of analogues featuring divalent transition metals at the tetrahedral Zn2+ site.

  18. Design, synthesis and luminescence properties of Ba2 YB2 O6 Cl- and Ba2 YB2 O6 F-based phosphors.

    Science.gov (United States)

    Chen, Wanping; Yang, Xin; Liu, Yan; Dai, Xiaoyan

    2015-05-01

    Using a high-temperature solid-state reaction, the chlorine in Ba2 YB2 O6 Cl is gradually replaced by F, and a new compound with the nominal chemical formula Ba2 YB2 O6 F and two phosphors doped with Ce(3+) and Eu(3+) , respectively, are obtained. X-Ray diffraction and photoluminescence spectroscopy are used to characterize the as-synthesized samples. The as-synthesized Ba2 YB2 O6 Cl exhibits bright blue emission in the spectral range ~ 330-410 nm with a maximum around 363 nm under X-ray or UV excitation. Ba2 YB2 O6 F:0.01Ce(3+) exhibits blue emission in the range ~ 340-570 nm with a maximum around 383 nm. Ba2 YB2 O6 F:0.01Eu(3+) exhibits a predominantly (5) D0 -(7)  F2 emission (~610 nm) and the relative intensities of the (5) D0 -(7)  F0,1,2 emissions are tunable under different wavelength UV excitation. The luminescence behaviors of the two phosphors are explained simply in terms of the host composition and site occupancy probability of Ce(3+) and Eu(3+) , respectively. The results indicate that these phosphors have potential application as a blue phosphor or as a red phosphor. Copyright © 2014 John Wiley & Sons, Ltd.

  19. How Extended Is Wernicke’s Area? Meta-Analytic Connectivity Study of BA20 and Integrative Proposal

    Directory of Open Access Journals (Sweden)

    Alfredo Ardila

    2016-01-01

    Full Text Available Understanding the functions of different brain areas has represented a major endeavor of contemporary neurosciences. The purpose of this paper was to pinpoint the connectivity of Brodmann area 20 (BA20 (inferior temporal gyrus, fusiform gyrus in language tasks. A meta-analysis was conducted to assess the language network in which BA20 is involved. The DataBase of Brainmap was used; 11 papers corresponding to 12 experimental conditions with a total of 207 subjects were included in this analysis. Our results demonstrated seven clusters of activation including other temporal lobe areas (BA3, BA21, the insula, and the prefrontal cortex; minor clusters in the cingulate gyrus and the occipital lobe were observed; however, the volumes of all the activation clusters were small. Our results suggest that regardless of BA20 having certain participation in language processes it cannot be considered as a core language processing area (Wernicke’s area; nonetheless, it could be regarded as kind of language processing marginal area, participating in “extended Wernicke’s area” or simply “Wernicke’s system.” It is suggested that “core Wernicke’s area” roughly corresponds to BA21, BA22, BA41, and BA42, while a “language associations area” roughly corresponds to BA20, BA37, BA38, BA39, and BA40 (“extended Wernicke’s area” or “Wernicke’s system”.

  20. 2. Marketing Communication Tools and Cultural Tourism in the Northeast of Brazil: the ‘forró pé de serra’ of Salvador/BA

    Directory of Open Access Journals (Sweden)

    Rodrigo Ladeira

    2017-12-01

    Full Text Available The aim of this study is to discover how forró artists/bands in Salvador-BA, who work with forró pé de serra - considered the original rhythm and form in which execution of the music is based on the accordion, zabumba and triangle - use marketing communication tools to disseminate their work, reach their target audience and exert an influence on the cultural tourism market. The article presents the cultural tourism market in the northeast, forró, concepts of cultural production and marketing (communication and advertising to set against the participants’ insights. This research, an exploratory and qualitative multiple case study, interviewed three artists/bands for this purpose. As a result, the range of marketing communication used by the actors of this research and their influence on the cultural tourism market was observed. Different uses were identified on account of their management styles. Bands which have greater knowledge and use of marketing and communication tools had a wider audience and higher profits in the groups studied. Furthermore, this research helps to reveal how forró production in Salvador-BA operates.

  1. Strain induced enhancement of magnetization in Ba{sub 2}FeMoO{sub 6} based heterostructure with (Ba{sub x}Sr{sub 1-x})TiO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyeong-Won; Norton, David P. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Ghosh, Siddhartha, E-mail: ghoshsid@gmail.com; Buvaev, Sanal; Hebard, Arthur F. [Department of Physics, University of Florida, Gainesville, Florida 32611 (United States)

    2016-05-14

    High quality epitaxial Ba{sub 2}FeMoO{sub 6} thin films and Ba{sub 2}FeMoO{sub 6}–(Ba{sub x}Sr{sub 1−x})TiO{sub 3} bi-layer (BL) and superlattice (SL) structures were grown via pulsed laser deposition under low oxygen pressure, and their structural, magnetic, and magneto-transport properties were examined. Superlattice and bi-layer structures were confirmed by X-ray diffraction patterns. Low temperature magnetic measurement shows that the saturation magnetization (M{sub S}) is significantly higher for SLs and almost similar or lower for BLs, when compared to phase pure Ba{sub 2}FeMoO{sub 6} thin films. The variation of the coercive field (H{sub C}) follows exact opposite trend, where BL samples have higher H{sub C} and SL samples have lower H{sub C} than pure Ba{sub 2}FeMoO{sub 6} thin films. Also, a significant decrease of the Curie temperature is found in both BL and SL structures compared to pure Ba{sub 2}FeMoO{sub 6} thin films. Negative magneto-resistance is seen in all the BL and SL structures as well as in pure Ba{sub 2}FeMoO{sub 6} thin films. In contrast to the magnetic properties, the magneto-transport properties do not show much variation with induced strain.

  2. Phase controlled synthesis of (Mg, Ca, Ba)-ferrite magnetic nanoparticles with high uniformity

    International Nuclear Information System (INIS)

    Wang, S.F.; Li, Q.; Zu, X.T.; Xiang, X.; Liu, W.; Li, S.

    2016-01-01

    (Mg, Ca, Ba)-ferrite magnetic nanoparticles were successfully synthesized through modifying the atomic ratio of polysaccharide and chelating agent at an optimal sintering temperature. In the process, the polysaccharide plays an important role in drastically shrinking the precursor during the gel drying process. In the metal-complex structure, M"2"+ ion active sites were coordinated by −OH of the water molecules except for EDTA anions. The MFe_2O_4 magnetic nanoparticles exhibited enhanced magnetic properties when compared with nano-MFe_2O_4 of similar particle size synthesized by other synthesis route reported in the literature. In particular, the sintering temperature improves the crystallinity and increases the hysteresis loop squareness ratio of (Mg, Ca, Ba)-ferrite nanoparticles significantly. - Graphical abstract: Schematic representation of the proposed model for MFe_2O_4 nanoparticle synthesis, starting from EDTA-chelated M"2"+ (M=Mg, Ca, or Ba) cations (left). High dispersion (Mg, Ca, Ba)-ferrite magnetic nanoparticles were prepared by a modified polyacrylamide gel route. Optimized utilization of polysaccharide, chelating agent, and sintering temperature allowed the formation of (Mg, Ca, Ba)-ferrite nanoparticles with a narrow diameter distribution. - Highlights: • We report a modified polyacrylamide gel route to synthesize (Mg, Ca, Ba)-ferrite magnetic nanoparticles. • Chelate mechanism of metal ions (Mg, Ca, Ba) and EDTA has been discussed. • Phase transformation process of (Mg, Ca, Ba)-ferrites has been discussed. • The preparation method increases the hysteresis loop squareness ratio of (Mg, Ca, Ba)-ferrite nanoparticles.

  3. The relationship of structure to superconductivity in the Pr-Ba-Cu-O system

    Science.gov (United States)

    Minseo, P.

    1994-05-01

    The relation of structure to lack of superconductivity in Pr-Ba-Cu-O was systematically investigated. First, the phase equilibria of this system was studied to find the processing parameters which maximize the cation-site ordering between Pr and Ba ions. Second, a comparative study between superconducting Nd-Ba-Cu-O and nonsuperconducting Pr-Ba-Cu-O was performed by forming solid-solution Nd-Pr-Ba-Cu-O. The relation between structure and superconductivity in Nd(1-x)Pr(x)Ba2Cu3O(7-delta) is investigated. T sub c decreases monotonically with increasing x and superconductivity disappears at around x = 0.3 to 0.4. T sub c is enhanced by 10 K when the sample is processed at an oxygen partial pressure (PO2) of 0.01 atm, followed by oxygenation at 450 C. Depression of T sub c as a function of x and PO2 is explained in terms of a charge-transfer model. It is suggested that destruction of superconductivity in the RE(1-x)Pr(x)Ba2Cu3O(7-delta) (RE=rare-earth) system can be viewed as disruption of four-fold planar coordinated Cu ions in the chain-site due to permanent occupation of extra Pr ions on Ba sites.

  4. CONTRAST STUDY ON CT AND BA IN DIAGNOSIS OF PATIENTS WITH ATHEROTHROMBOTIC BRAIN INFARCTION

    Institute of Scientific and Technical Information of China (English)

    Mingshun Liu; Haixiang Gao; Xiaomei Fu; Po Ma

    2007-01-01

    Objectives: To explore applied value on CT and BA in diagnosis of patients with atherothrombotic brain infarction. Methods:CT and BA were examined in 246 patients with atherothrombotic brain infarction. Results:The different change of CT and BA were showed in 246 patients with atherothrombotic brain infarction. Conclusions: There were separately different advantage and shortcoming in CT and BA in diagnosis of atherothrombotic brain infarction. The value of clinical application of BA was important in diagnosis of atherothrombotic brain infarction.

  5. Effect of lithium doping in BaTiO3 ceramics for vibration sensor application

    Science.gov (United States)

    Praveen, E.; Murugan, S.; Jayakumar, K.

    2018-04-01

    Phase pure undoped and Lithium doped BaTiO3 particles have been synthesized by high temperature solid-state reaction method. Substitution of Lithium at the Ba2+ site in BaTiO3 lattice has been investigated. The structural, vibrational, electrical and mechanical characterization have been carried out. The poled samples were used as a sensing element for the detection of mechanical oscillations and the presence of 80 Hz pulse in the output spectrum manifest the response of the sensor element to the applied mechanical stress. In comparison with pure BaTiO3 the sensitivity of Li doped BaTiO3 is 14 times greater than the pure BaTiO3. This confirms that Li doped BaTiO3 could be an efficient candidate for the functionalization of vibration sensors in space application.

  6. Growth of BaTiO3-PVDF composite thick films by using aerosol deposition

    Science.gov (United States)

    Cho, Sung Hwan; Yoon, Young Joon

    2016-01-01

    Barium titanate (BaTiO3)-polyvinylidene fluoride (PVDF) composite thick films were grown by using aerosol deposition at room temperature with BaTiO3 and PVDF powders. To produce a uniform composition in ceramic and polymer composite films, which show a substantial difference in specific gravity, we used PVDF-coated BaTiO3 powders as the starting materials. An examination of the microstructure confirmed that the BaTiO3 were well distributed in the PVDF matrix in the form of a 0 - 3 compound. The crystallite size in the BaTiO3-PVDF composite thick films was 5 ˜ 50 times higher than that in pure BaTiO3 thick films. PVDF plays a role in suppressing the fragmentation of BaTiO3 powder during the aerosol deposition process and in controlling the relative permittivity.

  7. Glass formation and physicochemical properties of glasses of Ba(PO3)2-LiRAlF6 (R=Mg, Ca, Sr, Ba) system

    International Nuclear Information System (INIS)

    Khalilev, V.D.; Chkhenkeli, G.D.; Vakhrameev, V.I.

    1987-01-01

    Glass formation regions, crystallizability, optical constants, thermal linear expansion coefficient and IR absorption spectra of glass are studied in Ba(PO) 3 ) 2 - LiRAlF 6 system where R=Mg, Ca, Sr, Ba. The carried out investigation confirms participation of introduced fluorides (as modified cryolites) in structural transformations manifested in increase of glass formation regions and nonlinear variations of properties

  8. Crystallization of the HigBA2 toxin-antitoxin complex from Vibrio cholerae

    DEFF Research Database (Denmark)

    Hadǽi, San; Garcia-Pino, Abel; Martinez-Rodriguez, Sergio

    2013-01-01

    The genome of Vibrio cholerae encodes two higBA toxin-antitoxin (TA) modules that are activated by amino-acid starvation. Here, the TA complex of the second module, higBA2, as well as the C-terminal domain of the corresponding HigA2 antitoxin, have been purified and crystallized. The HigBA2 compl...

  9. Superconductivity of Ba8Si46-xGax clathrates

    Science.gov (United States)

    Li, Yang; Zhang, Ruihong; Chen, Ning; Ma, Xingqiao; Cao, Guohui; Luo, Z. P.; Hu, C. R.; Ross, Joseph H., Jr.

    2007-03-01

    We have presented a combined experimental and theoretical study of the effect of Gallium substitution on the superconductivity of the type I clathrate Ba8Si46-xGax. In Ga-doped clathrates, the Ga state is found to be strongly hybridized with the cage conduction-band state. Ga substitution results in a shift toward to a lower energy, a decrease of density of states at Fermi level, a lowering of the carrier concentration and a breakage of integrity of the sp3 hybridized networks. These play key roles in the suppression of superconductivity. For Ba8Si40Ga6, the onset of the superconducting transition occurs at Tc=3.3 K. The investigation of the magnetic superconducting state shows that Ba8Si40Ga6 is a type II superconductor. The critical magnetic fields were measured to be Hc1=35 Oe and Hc2=8.5 kOe. Our estimate of the lectron-phonon coupling reveals that Ba8Si40Ga6 is a moderate phonon-mediated BCS superconductor.

  10. Tuberculose bovina no Estado da Paraíba: estudo retrospectivo Bovine tuberculosis in the state of Paraíba: retrospective survey

    Directory of Open Access Journals (Sweden)

    Salomão M. Figueiredo

    2010-09-01

    Full Text Available O objetivo do presente trabalho foi determinar a frequência de propriedades positivas (focos e de animais positivos para a tuberculose bovina no Estado da Paraíba. Foram utilizados dados da Agência de Defesa Agropecuária do Estado, coletados de suas 23 microrregiões, durante o período de janeiro de 2008 a julho de 2009. Durante esse período, foram examinadas 10.963 propriedades e 54.472 bovinos foram submetidos ao teste de tuberculinização. Para o diagnóstico foi utilizada, como prova de triagem, a tuberculinização cervical simples para gado de leite e a tuberculinização na prega caudal para gado de corte; como prova confirmatória foi utilizada a tuberculinização cervical comparativa. Uma propriedade foi considerada foco quando apresentou pelo menos um animal soropositivo. Das propriedades investigadas, 62 (0,57% apresentaram pelo menos um animal positivo e dos animais analisados, 136 (0,25% foram positivos. Houve diferença significativa (pThe aim of this study was to determine the frequency of positive herds (foci and positive animals for bovine tuberculosis in the state of Paraíba, Northeast region of Brazil. Data from the Agency of Agricultural Protection in the state, collected from its 23 microregions, during the January 2008 to July 2009 period, were used. During this period, 10,963 herds were examined and 54,472 cattle were submitted to the tuberculin test. For diagnosis the cervical and caudal-fold tuberculin tests were used as screening tests in dairy and beef cattle, respectively; as confirmatory test, comparative cervical test was used. A herd was considered focus when presented at least one positive animal. Of the herds investigated, 62 (0.57% had at least one positive animal, and of the animals examined, 136 (0.25% were positive. There was significant difference (p<0.001 in the proportion of positivity for females (0.32% and males (0.04%. Despite low frequency of foci of brucellosis and seropositive animals, it is

  11. Growth and scintillation properties of BaMgF4

    International Nuclear Information System (INIS)

    Yanagida, Takayuki; Kawaguchi, Noriaki; Fujimoto, Yutaka; Sugiyama, Makoto; Furuya, Yuki; Kamada, Kei; Yokota, Yuui; Yoshikawa, Akira; Chani, Valery

    2010-01-01

    By using the micro-pulling down (μ-PD) method, the barium magnesium fluoride (BaMgF 4 ) single crystalline scintillator was produced. The crystal was cut and mirror polished to the physical dimensions of 1x2x10 mm 3 for examination of scintillation properties. BaMgF 4 demonstrated ∼70% transmittance in wavelength range above 170 nm, and strong emission peaking around 205 nm was observed under X-ray excitation. The absolute light yield of BaMgF 4 was 1300±100 ph/MeV, and the decay time profile showed two components as 0.57±0.01 (70%) and 2.2±0.31 (30%) ns at room temperature.

  12. The use of Tillandsia usneoides L. as bioindicator of air pollution in Sao Paulo, Brazil

    International Nuclear Information System (INIS)

    Figueiredo, A.M.G.; Alcala, A.L.; Ticianelli, R.B.; Saiki, M.; Domingos, M.

    2004-01-01

    Epiphytic bromeliad Tillandsia usneoides was used as a biomonitor of metal atmospheric pollution in the city of Sao Paulo, Brazil. The samples were collected from an unpolluted area and were exposed for 8 weeks in 10 sites of the city and in a control site. The data obtained showed that the control site presented lower concentration for most elements analyzed and the highest concentrations of Na, Cl, Br, K. The highest concentrations of Zn, Cu and V were observed in stations submitted to industrial and vehicular sources. The results obtained for rare earth elements, Al, Fe, Mg, Mn, Rb and Sc indicate mineral dust origin. The elements Ba, As and Sb presented higher values in stations near streets with heavy traffic. (author)

  13. Improvement of β-phase crystal formation in a BaTiO3-modified PVDF membrane

    Science.gov (United States)

    Lin, SHEN; Lei, GONG; Shuhua, CHEN; Shiping, ZHAN; Cheng, ZHANG; Tao, SHAO

    2018-04-01

    In this paper, low temperature plasma is used to modify the surface of barium titanate (BaTiO3) nanoparticles in order to enhance the interfacial compatibility between ferroelectric poly(vinylidene fluoride) (PVDF) and BaTiO3 nanoparticles. The results demonstrate that oxygenic groups are successfully attached to the BaTiO3 surface, and the quantity of the functional groups increases with the treatment voltage. Furthermore, the effect of modified BaTiO3 nanoparticles on the morphology and crystal structure of the PVDF/BaTiO3 membrane is investigated. The results reveal that the dispersion of BaTiO3 nanoparticles in the PVDF matrix was greatly improved due to the modification of the BaTiO3 nanoparticles by air plasma. It is worth noting that the formation of a β-phase in a PVDF/modified BaTiO3 membrane is observably promoted, which results from the strong interaction between PVDF chains and oxygenic groups fixed on the BaTiO3 surface and the better dispersion of BaTiO3 nanoparticles in the PVDF matrix. Besides, the PVDF/modified BaTiO3 membrane at the treatment voltage of 24 kV exhibits a lower water contact angle (≈68.4°) compared with the unmodified one (≈86.7°). Meanwhile, the dielectric constant of PVDF/BaTiO3 nanocomposites increases with the increase of working voltage.

  14. BaBar Data Aquisition

    CERN Document Server

    Scott, I; Grosso, P; Hamilton, R T; Huffer, M E; O'Grady, C; Russell, J J

    1998-01-01

    The BaBar experiment at the Stanford Linear Accelerator Center is designed to perform a search for CP violation by analysing the decays of a very large sample of B and Bbar mesons produced at the high luminosity PEP-11 accelerator. The data acquisition system must cope with a sustained high event rate, while supporting real time feature extraction and data compression with minimal dead time. The BaBar data acquisition system is based around a common VME interface to the electronics read-out of the separate detector subsystems. Data from the front end electronics is read into commercial VME processors via a custom "personality card" and PCI interface. The commercial CPUs run the Tornado operating system to provide a platform for detector subsystem code to perform the necessary data processing. The data are read out via a non-blocking network switch to a farm of commercial UNIX processors. Careful design of the core data acquisition code has enabled us to sustain events rates in excess of 20 kHz while maintaini...

  15. Effect of Ba in the glass characteristics of cesium loaded iron phosphate glasses

    International Nuclear Information System (INIS)

    Joseph, Kitheri; Asuvathraman, R.; Vasudeva Rao, P.R.

    2015-01-01

    Radioactive 137 Cs extracted from high level nuclear waste, when immobilized in a suitable matrix can be used as a γsource in medical industry. Iron phosphate glass (IPG) is one of a suitable matrix for the immobilization of 137 Cs prior to the immobilization of 137 Cs in IPG, it is essential to optimize the immobilization conditions using natural (inactive) cesium. Glass characteristics of inactive Cs loaded iron phosphate glasses were already explored in our earlier studies. However, the change in glass characteristics of 137 Cs loaded iron phosphate glass to 137 Ba loaded iron phosphate glass need to be studied before the immobilization of 137 Cs in iron phosphate glass as 137 Cs transforms to 137 Ba due to nuclear transmutation ( 137 Cs(β,γ) 137 Ba). This paper reports the studies on such a behaviour by incorporating inactive Ba in cesium loaded iron phosphate glasses. Cs and Ba loaded iron phosphate glasses were prepared by melt quench technique in air using appropriate amounts of Fe 2 O 3 , NH 4 H 2 PO 4 , Ba(OH) 2.8 H 2 O and Cs 2 CO 3 . The chemicals were added such that the glass formed possesses the batch composition of (a) 21.4 wt. % Fe 2 O 3 -45 wt. % Cs 2 O-5 wt % BaO-P 2 O 5 (henceforth referred as IP50Cs45Ba5); (b) 21.4 wt. % Fe 2 O 3 -25 wt. % Cs 2 O-25 wt % BaO-P 2 O5 (henceforth referred as IP50Cs25Ba25). The thermal expansion measurements were also carried out using a home-built quartz push-rod dilatometer. The data related to change in thermal expansion behaviour, glass forming ability, glass stability and structural changes in phosphate network due to the partial replacement of Cs with Ba will also be discussed. (author)

  16. The BaBar Software Architecture and Infrastructure

    International Nuclear Information System (INIS)

    Cosmo, Gabriele

    2003-01-01

    The BaBar experiment has in place since 1995 a software release system (SRT Software Release Tools) based on CVS (Concurrent Version System) which is in common for all the software developed for the experiment, online or offline, simulation or reconstruction. A software release is a snapshot of all BaBar code (online, offline, utilities, scripts, makefiles, etc.). This set of code is tested to work together, and is indexed by a release number (e.g., 6.8.2) so a user can refer to a particular release and get reproducible results. A release will involve particular versions of packages. A package generally consists of a set of code for a particular task, together with a GNU makefile, scripts and documentation. All BaBar software is maintained in AFS (Andrew File System) directories, so the code is accessible worldwide within the Collaboration. The combination SRT, CVS, AFS, has demonstrated to be a valid, powerful and efficient way of organizing the software infrastructure of a modern HEP experiment with collaborating Institutes distributed worldwide, both in a development and production phase

  17. Structural phase transition of BaZrO3 under high pressure

    International Nuclear Information System (INIS)

    Yang, Xue; Li, Quanjun; Liu, Ran; Liu, Bo; Zhang, Huafang; Jiang, Shuqing; Zou, Bo; Cui, Tian; Liu, Bingbing; Liu, Jing

    2014-01-01

    We studied the phase transition behavior of cubic BaZrO 3 perovskite by in situ high pressure synchrotron X-ray diffraction experiments up to 46.4 GPa at room temperature. The phase transition from cubic phase to tetragonal phase was observed in BaZrO 3 for the first time, which takes place at 17.2 GPa. A bulk modulus 189 (26) GPa for cubic BaZrO 3 is derived from the pressure–volume data. Upon decompression, the high pressure phase transforms into the initial cubic phase. It is suggested that the unstable phonon mode caused by the rotation of oxygen octahedra plays a crucial role in the high pressure phase transition behavior of BaZrO 3

  18. [Anthropometric indices and nutritional status of low income school children in a municipality of the State of Rio de Janeiro (Brazil): a pilot study].

    Science.gov (United States)

    dos Anjos, L A

    1989-06-01

    The growth and nutritional status of 185 school-aged children (97 boys and 88 girls) of low socio-economic level in Nova Iguaçú, State of Rio de Janeiro, Brazil, were studied. Nutritional anthropometry identified 3.52 and 6.25% of the children as suffering from wasting and stunting, respectively. These prevalences of malnutrition were comparable to those described in pre-school children living in a "favela" (shanty town) of Rio de Janeiro. In general, the median height fell below the 25th centile of the international standard of growth. The value of 10 year-old boys fell below the 10th centile. The mean values of weight and height of these children were comparable to those of children from the Northeastern region of Brazil ("Nordeste"), higher than those found for children in the State of Paraíba, Brazil, and lower than those for middle-class children of the State of S. Paulo. Skinfold thickness, arm circumference, and arm fat area data were higher in girls than boys. However, arm muscle are values in boys were superior in comparison to those of girls.

  19. Analytical strategies for uranium determination in natural water and industrial effluents samples

    International Nuclear Information System (INIS)

    Santos, Juracir Silva

    2011-01-01

    The work was developed under the project 993/2007 - 'Development of analytical strategies for uranium determination in environmental and industrial samples - Environmental monitoring in the Caetite city, Bahia, Brazil' and made possible through a partnership established between Universidade Federal da Bahia and the Comissao Nacional de Energia Nuclear. Strategies were developed to uranium determination in natural water and effluents of uranium mine. The first one was a critical evaluation of the determination of uranium by inductively coupled plasma optical emission spectrometry (ICP OES) performed using factorial and Doehlert designs involving the factors: acid concentration, radio frequency power and nebuliser gas flow rate. Five emission lines were simultaneously studied (namely: 367.007, 385.464, 385.957, 386.592 and 409.013 nm), in the presence of HN0 3 , H 3 C 2 00H or HCI. The determinations in HN0 3 medium were the most sensitive. Among the factors studied, the gas flow rate was the most significant for the five emission lines. Calcium caused interference in the emission intensity for some lines and iron did not interfere (at least up to 10 mg L -1 ) in the five lines studied. The presence of 13 other elements did not affect the emission intensity of uranium for the lines chosen. The optimized method, using the line at 385.957 nm, allows the determination of uranium with limit of quantification of 30 μg L -1 and precision expressed as RSD lower than 2.2% for uranium concentrations of either 500 and 1000 μg L -1 . In second one, a highly sensitive flow-based procedure for uranium determination in natural waters is described. A 100-cm optical path flow cell based on a liquid-core waveguide (LCW) was exploited to increase sensitivity of the arsenazo 111 method, aiming to achieve the limits established by environmental regulations. The flow system was designed with solenoid micro-pumps in order to improve mixing and minimize reagent consumption, as well as

  20. Analytical strategies for uranium determination in natural water and industrial effluents samples; Estrategias analiticas para determinacao de uranio em amostras de aguas e efluentes industriais

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Juracir Silva

    2011-07-01

    The work was developed under the project 993/2007 - 'Development of analytical strategies for uranium determination in environmental and industrial samples - Environmental monitoring in the Caetite city, Bahia, Brazil' and made possible through a partnership established between Universidade Federal da Bahia and the Comissao Nacional de Energia Nuclear. Strategies were developed to uranium determination in natural water and effluents of uranium mine. The first one was a critical evaluation of the determination of uranium by inductively coupled plasma optical emission spectrometry (ICP OES) performed using factorial and Doehlert designs involving the factors: acid concentration, radio frequency power and nebuliser gas flow rate. Five emission lines were simultaneously studied (namely: 367.007, 385.464, 385.957, 386.592 and 409.013 nm), in the presence of HN0{sub 3}, H{sub 3}C{sub 2}00H or HCI. The determinations in HN0{sub 3} medium were the most sensitive. Among the factors studied, the gas flow rate was the most significant for the five emission lines. Calcium caused interference in the emission intensity for some lines and iron did not interfere (at least up to 10 mg L{sup -1}) in the five lines studied. The presence of 13 other elements did not affect the emission intensity of uranium for the lines chosen. The optimized method, using the line at 385.957 nm, allows the determination of uranium with limit of quantification of 30 {mu}g L{sup -1} and precision expressed as RSD lower than 2.2% for uranium concentrations of either 500 and 1000 {mu}g L{sup -1}. In second one, a highly sensitive flow-based procedure for uranium determination in natural waters is described. A 100-cm optical path flow cell based on a liquid-core waveguide (LCW) was exploited to increase sensitivity of the arsenazo 111 method, aiming to achieve the limits established by environmental regulations. The flow system was designed with solenoid micro-pumps in order to improve mixing and

  1. Phase controlled synthesis of (Mg, Ca, Ba)-ferrite magnetic nanoparticles with high uniformity

    Energy Technology Data Exchange (ETDEWEB)

    Wang, S.F., E-mail: wangshifa2006@yeah.net [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan (China); Science and technology on vacuum technology and physics laboratory, Lanzhou Institute of Physics, Lanzhou 730000, Gansu (China); Li, Q. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan (China); Zu, X.T., E-mail: xtzu@uestc.edu.cn [Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan (China); Xiang, X.; Liu, W. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan (China); Li, S., E-mail: sean.li@unsw.edu.au [School of Material Science and Engineering, University of New South Wales, Sydney 2052 (Australia)

    2016-12-01

    (Mg, Ca, Ba)-ferrite magnetic nanoparticles were successfully synthesized through modifying the atomic ratio of polysaccharide and chelating agent at an optimal sintering temperature. In the process, the polysaccharide plays an important role in drastically shrinking the precursor during the gel drying process. In the metal-complex structure, M{sup 2+} ion active sites were coordinated by −OH of the water molecules except for EDTA anions. The MFe{sub 2}O{sub 4} magnetic nanoparticles exhibited enhanced magnetic properties when compared with nano-MFe{sub 2}O{sub 4} of similar particle size synthesized by other synthesis route reported in the literature. In particular, the sintering temperature improves the crystallinity and increases the hysteresis loop squareness ratio of (Mg, Ca, Ba)-ferrite nanoparticles significantly. - Graphical abstract: Schematic representation of the proposed model for MFe{sub 2}O{sub 4} nanoparticle synthesis, starting from EDTA-chelated M{sup 2+} (M=Mg, Ca, or Ba) cations (left). High dispersion (Mg, Ca, Ba)-ferrite magnetic nanoparticles were prepared by a modified polyacrylamide gel route. Optimized utilization of polysaccharide, chelating agent, and sintering temperature allowed the formation of (Mg, Ca, Ba)-ferrite nanoparticles with a narrow diameter distribution. - Highlights: • We report a modified polyacrylamide gel route to synthesize (Mg, Ca, Ba)-ferrite magnetic nanoparticles. • Chelate mechanism of metal ions (Mg, Ca, Ba) and EDTA has been discussed. • Phase transformation process of (Mg, Ca, Ba)-ferrites has been discussed. • The preparation method increases the hysteresis loop squareness ratio of (Mg, Ca, Ba)-ferrite nanoparticles.

  2. Microstructural properties of BaTiO3 ceramics and thin films

    International Nuclear Information System (INIS)

    Fundora C, A.; Portelles, J.J.; Siqueiros, J.M.

    2000-01-01

    A microstructural study of BaTiO 3 ceramics obtained by the conventional ceramic method is presented. Targets were produced to grow BaTiO 3 thin films by pulsed laser deposition on Pt/Ti/Si (100) substrates. X-ray diffraction, Auger Electron Spectroscopy, X-ray Photon Spectroscopy and Scanning Electron Microscopy were used to study the properties of the BaTiO 3 ceramic samples and thin films, as deposited and after an annealing process. (Author)

  3. The Preparation and Characterization of Tourmaline-Containing Functional Copolymer p (VST/MMA/BA

    Directory of Open Access Journals (Sweden)

    Yingmo Hu

    2018-01-01

    Full Text Available Tourmaline was modified with vinyl triethoxysilane containing double bond to prepare the polymerizable organic vinylsiliconoxyl tourmaline (VST and then copolymerized with methyl methacrylate (MMA and butyl acrylate (BA to produce the tourmaline-containing functional copolymer p (VST/MMA/BA. The structures and morphologies of VST and p (VST/MMA/BA copolymer were characterized by IR, SEM, and EDX. The experimental results indicated that tourmaline was introduced into the copolymer via surface modification and the tourmaline-containing functional copolymer was obtained by a copolymerization process with MMA and BA. The prepared p (VST/MMA/BA copolymer displayed excellent storage stabilities, high far-infrared radiation and negative ion releasing performances, and good mechanical properties.

  4. Abelhas (Hymenoptera: Apoidea visitantes das flores de urucum em Vitória da Conquista, BA Bees (Hymenoptera: Apoidea visitors of the annatto flowers in Vitória da Conquista, Bahia State, Brazil

    Directory of Open Access Journals (Sweden)

    Augusto Jorge Cavalcante Costa

    2008-04-01

    Full Text Available O urucum é um arbusto da família Bixaceae, utilizado na fabricação de corantes naturais para a indústria alimentícia e cosmética. No Brasil, somente nos últimos 15 anos, houve maior interesse pelo cultivo, pois se tornou uma alternativa agrícola promissora. O presente trabalho teve por objetivo identificar as abelhas visitantes das flores do urucuzeiro em Vitória da Conquista, BA. O trabalho foi conduzido no campo experimental da UESB, em uma lavoura do tipo cultivado Peruana Paulista. A coleta das abelhas visitantes foi feita na época principal de floração do urucueiro: março/abril, das 6h às 18h. Foram coletadas 3019 abelhas de 22 espécies, com predominância na visitação das 8h às 14h em relação ao número de indivíduos e número de espécies capturadas. As espécies mais freqüentes foram: Trigona spinipes (Fabricius, Apis mellifera L., Schwarziana quadripunctata (Lepeletier e Tetragonisca angustula (Latreille. Espécies de maior porte, como Xylocopa frontalis (Olivier, Bombus morio (Swederus e Eulaema nigrita Lepeletier, consideradas como eficientes na polinização da cultura do urucum, não foram abundantes neste estudo.Annatto is a shrub from Bixaceae family, which natural pigment (annatto is widely used in food and cosmetic industries. In Brazil, the interest for this crop started in the last fifteen years, once it became a promising agricultural alternative. This study was aimed at identifing visitor bees of annatto flowers at the agriculture region of Vitória da Conquista (BA. The research was carried out in the experimental field of UESB, in an experimental plot planted with the cv. Peruana Paulista. The visitor bees were collected during the main blooming period: March/April, between 6:00h and 18:00h. A total of 3,019 bees from 22 species was collected, with higher visitation during the period from 8:00 to 14:00h, regarding the number of individuals and species. The species most frequent were Trigona spinipes

  5. Perovskite phases in the systems AO-SE/sub 2/O/sub 3/-UO/sub 2,x/ with A=alkaline earth metal and SE=rare earths, La, and Y. VII. The systems Ba/sub 2/CaUO/sub 6/-Ba/sub 2/Gd/sub 0. 67/UO/sub 6/ and Ba/sub 2/CaUO/sub 6/-Ba/sub 2/Y/sub 0. 67/UO/sub 6/

    Energy Technology Data Exchange (ETDEWEB)

    Kemmler-Sack, S; Seemann, I; Schittenhelm, H J [Tuebingen Univ. (F.R. Germany). Institut fuer Anorganische Chemie

    1976-05-01

    The ordered perovskite Ba/sub 2/CaUO/sub 6/ forms a solid solution series with Ba/sub 2/Gdsub(0.67)UO/sub 6/ and Ba/sub 2/Ysub(0.67)UO/sub 6/, respectively. The deviations from the ideal behaviour are studied by X-ray, diffuse reflectance and vibrational methods.

  6. Perovskite phases in the systems AO-SE/sub 2/O/sub 3/-UO/sub 2,x/ with A=alkaline earth metal and SE=rare earths, La, and Y. IX. The systems Ba/sub 2/SrUO/sub 6/-Ba/sub 2/Gd/sub 0. 67/UO/sub 6/ and Ba/sub 2/SrUO/sub 6/-Ba/sub 2/Y/sub 0. 67/UO/sub 6/

    Energy Technology Data Exchange (ETDEWEB)

    Kemmler-Sack, S; Seemann, I [Tuebingen Univ. (F.R. Germany). Inst. fuer Anorganische Chemie I

    1976-07-01

    The ordered perovskite Ba/sub 2/SrUO/sub 6/ forms a solid solution series with Ba/sub 2/Gdsub(0.67)UO/sub 6/ and Ba/sub 2/Ysub(0.67)UO/sub 6/ respectively. The deviations from the ideal behaviour are studied by X-ray, diffuse reflectance and vibrational methods.

  7. Environmental influences on distribution of four Sciaenidae species (Actinopterygii, Perciformes in a tropical bay at Southeastern Brazil Influências ambientais na distribuição de quatro espécies de Sciaenidae (Actinopterygii, Perciformes numa baía tropical do sudeste do Brasil

    Directory of Open Access Journals (Sweden)

    Francisco G. Araújo

    2006-06-01

    Full Text Available We sampled fish and measured environmental variables in the Sepetiba Bay, a tropical embayment at Southeastern Brazil. The aim was to assess environmental influences on distribution of four abundant species of Sciaenidae Micropogonias furnieri (Desmarest, 1823, Ctenosciaena gracilicirrhus (Metzelaar, 1919, Cynoscion leiarchus (Cuvier, 1830 and Menticirrhus americanus (Linnaeus, 1758 to test the habitat partition hypothesis. Samples were taken between June 1993 and July 1996, at three bay zones (outer, central and inner. Depth was the most important environmental variable to influence fish distribution, followed by transparency. M. furnieri showed significant negative correlation to depth, transparency and salinity, while C. gracilicirrhus showed the opposite situation. The highest densities of C. leiarchus occurred in the lowest temperature, while M. americanus did not showed preferences for any of the examined environmental variables. Spatial separation, mainly between M. furnieri and C. gracilicirrhus, seems to be the strategy developed to coexist in the Sepetiba Bay, with M. furnieri being more adapted to copy with harsh environmental conditions of the inner bay. The other three species, which use mostly the outer bay zone, seem to be restricted to more stable conditions, where influences from oceanic waters are more intense.Foram coletados peixes e medidas as variáveis ambientais na Baía de Sepetiba, uma baía tropical do Sudeste do Brasil. O objetivo foi determinar influências ambientais na distribuição de quatro espécies abundantes de Sciaenidae Micropogonias furnieri (Desmarest, 1823, Ctenosciaena gracilicirrhus (Metzelaar,1919, Cynoscion leiarchus (Cuvier,1830 and Menticirrhus americanus (Linnaeus, 1758 para testar a hipótese de partição do hábitat. Amostragens foram feitas entre Junho de 1993 e Julho de 1996 em três zonas da baía (externa, central e interna. A profundidade foi a mais importante variável ambiental que

  8. Benzo(A)pyrene (BaP) treatment results in complete infertility in female pigeons

    Energy Technology Data Exchange (ETDEWEB)

    Hough, J.L.; Darrow, D.; Eaton, J.; Baird, M.B. (Masonic Medical Research Lab., Utica, NY (United States))

    1991-03-11

    BaP is a carcinogenic polycyclic aromatic hydrocarbon (PAH) and a common environmental pollutant. Show Racer and White Carneau female pigeons injected weekly with BaP for 3 for 5 months were completely infertile, with ovaries appearing necrotic or oxidized. Fertility in benzo(e)pyrene (BeP, a noncarcinogenic PAH) treated birds was the same as for corn oil treated controls, as was embryo development. Thus, infertility in BaP treated birds appears to be related to its structure-carcinogenic potential. There was no readily apparent affect of BaP treatment on testes from male birds. In order to determine whether BaP metabolites covalently bind to DNA in the ovaries of these birds, pigeons were injected with BaP or BeP, controls were injected with corn oil. Animals were sacrificed 24h later, the ovaries or testes removed, and the DNA isolated and analyzed for PAH-DNA adducts by {sup 32}P-post labeling assay. One major and one minor PAH-DNA adduct was found in ovaries and testes from BaP treated birds. However, no PAH adducts were found in BeP treated or control animals. Thus, problems with fertility may arise because of the alteration in DNA by BaP metabolite binding in ovaries where rapid cell growth occurs during egg production.

  9. Isothermal cross-sections of Sr-Al-Ge and Ba-Al-Ge systems at 673 K

    International Nuclear Information System (INIS)

    Kutsenok, N.L.; Yanson, T.I.

    1987-01-01

    X-ray and microstructural analyses are used to study phase equilibria in Sr-Al-Ge and Ba-Al-Ge systems. Existence of SrAl 2 Ge 2 , Sr(Al, Ge) 2 Ba(Al, Ge) 2 , Sr 3 Al 2 Ge 2 , Ba 3 Al 2 Ge 2 ternary compounds is confirmed, a new BaGe 4 binary compound and also new ternary compounds of approximate composition Sr 57 Al 30 Ge 13 and Ba 20 Al 40 Ge 40 , which crystal structure is unknown, are detected. Aluminium solubility in SrAl 4 and BaAl 4 binary compounds (0.05 atomic fraction) is determined. Ba(Al, Ge) 2 compound homogeneity region is defined more exactly (aluminium content varies from 0.27 to 0.51 at. fractions)

  10. Water adsorption induced in-plane domain switching on BaTiO{sub 3} surface

    Energy Technology Data Exchange (ETDEWEB)

    Li, X.; Bai, Y.; Su, Y. J., E-mail: yjsu@ustb.edu.cn [Corrosion and Protection Center, Key Laboratory for Environmental Fracture (MOE), University of Science and Technology Beijing, Beijing 100083 (China); Wang, B. C. [Corrosion and Protection Center, Key Laboratory for Environmental Fracture (MOE), University of Science and Technology Beijing, Beijing 100083 (China); Multiscale Materials Modelling group, Department of Materials and Engineering, Royal Institute of Technology, SE-10044 Stockholm (Sweden)

    2015-09-07

    In this study, the influences of the adsorption of water molecules on the changes in the atomic and electric structures of BaTiO{sub 3} surface were investigated using ab initio calculation. Water molecules are molecularly and dissociatively adsorbed on the BaTiO{sub 3} surface, which makes electrons transfer from water molecules to the BaTiO{sub 3} surface. The redistribution of electrons in the BaTiO{sub 3} surface layers weakens the Ba-O interactions and strengthens the Ti-O interactions, so that the Ti atom shifts in TiO{sub 2} plane, i.e., an in-plane domain switching. The adsorption of water molecules on BaTiO{sub 3} surfaces also results in a reduction in the surface rumpling.

  11. Advances in enlargement of melt-textured Gd-Ba-Cu-O superconductors

    International Nuclear Information System (INIS)

    Nariki, S; Sakai, N; Kita, M; Fujikura, M; Murakami, M; Hirabayashi, I

    2006-01-01

    We investigated the fabrication of melt-textured Gd-Ba-Cu-O bulk superconductors with the employment of a Gd 2 BaO 4 (Gd210)-BaCuO 2 -CuO precursor. This enabled us to synthesize a very large Gd-Ba-Cu-O bulk superconductor, 140 mm in diameter. The trapped field distribution measured at 77 K revealed that the sample had no serious cracks, and the maximum field was 2.3 T. The formation behaviour and depressing mechanism of cracking were studied using sintered Gd210-containing precursors. The Ba-Cu-O component in the precursor melted at around 900 deg. C. The formation of such a liquid phase enhanced the densification of the precursor by liquid phase sintering. The mechanical strength of the sintered precursor was increased compared to the conventional Gd123-Gd211 precursor. This will be effective in preventing crack formation in the texturing process of large single-grain samples. The superconducting properties of the bulk sample fabricated from Gd210-containing precursor have been discussed

  12. Rattling of Ba-atoms in Ba8ZnxGe43-5x/8([]3-3x/8)

    International Nuclear Information System (INIS)

    Melnychenko, N.; Grytsiv, A.; Rotter, M.; Rogl, P.; Devishvili, A.

    2006-01-01

    Full text: In order to improve the figure of merit of thermoelectric materials, one of the key parameters to be minimized is the lattice thermal conductivity. It is thus essential for the design of new thermoelectric materials to understand the lattice dynamics, especially the scattering mechanism of low energy phonons. The present paper describes formation, phase relations at subsolidus temperatures as well as at 800 o C, crystal chemistry and physical properties of a series of ternary clathrates as part of the solid solution, Ba 8 Zn x (Ge 43-5x/8[]3-3x/8 ), deriving from binary Ba 8 Ge 43 []3 with a solubility limit of 8 Zn per formula unit at 800 o C. Structural investigations in all cases confirm cubic primitive symmetry with a lattice parameter a ∼ 1.1 nm consistent with the space group type Pm-3n. Studies of transport coefficients evidence electrons as the majority charge carriers in the systems. Thermal conductivity exhibits a pronounced low temperature maximum, dominated by the lattice contribution, while at higher temperatures the electronic part gains weight. Inelastic neutron scattering experiments are used to study the phonon spectrum for Ba 8 Zn 8 Ge 38 . (author)

  13. Assessment of atmospheric metallic pollution in the metropolitan region of Sao Paulo, Brazil, employing Tillandsia usneoides L. as biomonitor

    International Nuclear Information System (INIS)

    Figueiredo, A.M.G.; Nogueira, C.A.; Saiki, M.; Milian, F.M.; Domingos, M.

    2007-01-01

    Tillandsia usneoides L. is an epiphytic bromeliad plant able to absorb water and nutrients directly from the air. For this reason this species was selected to carry out a monitoring study of air pollution in the metropolitan region of Sao Paulo, Brazil. Five consecutive transplantation experiments (8 weeks each) were performed in 10 sites of the city, submitted to different sources of air pollution (industrial, vehicular), using plants collected from an unpolluted area. After exposure, trace metals were analyzed in the plant by instrumental neutron activation analysis. Traffic-related elements such as Zn and Ba presented high concentrations in exposure sites near to heavy traffic avenues (cars, buses and trucks) and may be associated to vehicular sources. For Zn and Co the highest contents were related to industrial zones and can be associated to the presence of anthropogenic emission sources. The rare earth elements, Fe and Rb, probably have soil particles as main source. - This paper is the first work on the use of biomonitors to assess metal pollution in Sao Paulo, Brazil, the biggest city in Latin America

  14. Assessment of atmospheric metallic pollution in the metropolitan region of Sao Paulo, Brazil, employing Tillandsia usneoides L. as biomonitor

    Energy Technology Data Exchange (ETDEWEB)

    Figueiredo, A.M.G. [Instituto de Pesquisas Energeticas e Nucleares, IPEN-CNEN/SP, Av. Prof. Lineu Prestes 2242, CEP 05508-000, Sao Paulo, SP (Brazil)]. E-mail: anamaria@ipen.br; Nogueira, C.A. [Instituto de Pesquisas Energeticas e Nucleares, IPEN-CNEN/SP, Av. Prof. Lineu Prestes 2242, CEP 05508-000, Sao Paulo, SP (Brazil); Saiki, M. [Instituto de Pesquisas Energeticas e Nucleares, IPEN-CNEN/SP, Av. Prof. Lineu Prestes 2242, CEP 05508-000, Sao Paulo, SP (Brazil); Milian, F.M. [Instituto de Fisica, Universidade de Sao Paulo, Rua do Matao, Travessa R, 187, Cidade Universitaria, CEP 05508-090, Sao Paulo, SP (Brazil); Domingos, M. [Instituto de Botanica, Av. Miguel Stefano No. 3687, CEP 04301-012, Sao Paulo, SP (Brazil)

    2007-01-15

    Tillandsia usneoides L. is an epiphytic bromeliad plant able to absorb water and nutrients directly from the air. For this reason this species was selected to carry out a monitoring study of air pollution in the metropolitan region of Sao Paulo, Brazil. Five consecutive transplantation experiments (8 weeks each) were performed in 10 sites of the city, submitted to different sources of air pollution (industrial, vehicular), using plants collected from an unpolluted area. After exposure, trace metals were analyzed in the plant by instrumental neutron activation analysis. Traffic-related elements such as Zn and Ba presented high concentrations in exposure sites near to heavy traffic avenues (cars, buses and trucks) and may be associated to vehicular sources. For Zn and Co the highest contents were related to industrial zones and can be associated to the presence of anthropogenic emission sources. The rare earth elements, Fe and Rb, probably have soil particles as main source. - This paper is the first work on the use of biomonitors to assess metal pollution in Sao Paulo, Brazil, the biggest city in Latin America.

  15. Carbon-14 immobilization via the CO2-Ba(OH)2 hydrate gas-solid reaction

    International Nuclear Information System (INIS)

    Haag, G.L.

    1981-08-01

    For the treatment of an air-based off-gas stream, the use of packed beds of Ba(OH) 2 .8H 2 O flakes to remove CO 2 has been demonstrated. However, the operating conditions must be maintained between certain upper and lower limits with respect to the partial pressure of water. If the water vapor pressure in the gas is less than the dissociation vapor pressure of Ba(OH) 2 .8H 2 O, the bed will deactivate. If the vapor pressure is considerably greater, pressure drop problems will increase with increaseing humidity as the particles curl and degrade. Results have indicted that when operated in the proper regime, the bulk of the increase in pressure drop results from the conversion of Ba(OH) 2 .8H 2 O to BaCO 3 and not from the hydration of the commercial Ba(OH) 2 .8H 2 O (i.e., Ba(OH) 2 .7.50H 2 O) to Ba(OH) 2 .8H 2 O

  16. The BaBar electromagnetic calorimeter

    CERN Document Server

    Lewandowski, B

    2002-01-01

    The BaBar electromagnetic calorimeter is a hermetic, total-absorption array of CsI(Tl)-crystals, operated at the asymmetric e sup - e sup + -collider PEP-II at SLAC. The design and the status of the performance as of February 2002 is presented.

  17. Phase formation, structural and microstructural characterization of novel oxynitride-perovskites synthesized by thermal ammonolysis of (Ca,Ba)MoO4 and (Ca,Ba)MoO3

    International Nuclear Information System (INIS)

    Logvinovich, D.; Aguirre, M.H.; Hejtmanek, J.; Aguiar, R.; Ebbinghaus, S.G.; Reller, A.; Weidenkaff, A.

    2008-01-01

    Reactions of AMoO 4 and AMoO 3 (A=Ca 2+ , Ba 2+ ) with ammonia were investigated at 873 K 3 and to study their crystal structure. CaMo(O,N) 3 and BaMo(O,N) 3 were prepared by thermal ammonolysis of the corresponding CaMoO 3 and BaMoO 3 precursors at T=898 and 998 K, respectively. The structural parameters of the oxynitrides were obtained from Rietveld refinements of X-ray and neutron powder diffraction data. CaMo(O,N) 3 crystallizes in the GdFeO 3 distorted perovskite structure with orthorhombic space group Pbnm and a=5.5029(1) A, b=5.5546(1) A, c=7.8248(1) A as determined by X-ray powder diffraction. Its O/N content refined from the neutron diffraction data corresponds to the composition CaMoO 1.7(1) N 1.3(1) . BaMo(O,N) 3 crystallizes in the cubic perovskite structure with space group Pm3-bar m and a=4.0657(1) A as determined by X-ray powder diffraction. Transmission electron microscopy reveals a complex microstructure for both CaMoO 3 and CaMoO 1.7(1) N 1.3(1) represented by twin domains of different orientation. - Graphical abstract: Reactions of AMoO 4 and AMoO 3 (A=Ca 2+ , Ba 2+ ) oxides with ammonia have been studied at T=873-1123 K. Orthorhombic CaMoO 1.7(1) N 1.3(1) (Pbnm) and cubic BaMo(O,N) 3 (Pm3-bar m) were prepared by thermal ammonolysis of the corresponding CaMoO 3 and BaMoO 3 precursors at T=898 and 998 K, respectively. Display Omitted

  18. Evolution of deformation in neutron-rich Ba isotopes up to A =150

    Science.gov (United States)

    Licǎ, R.; Benzoni, G.; Rodríguez, T. R.; Borge, M. J. G.; Fraile, L. M.; Mach, H.; Morales, A. I.; Madurga, M.; Sotty, C. O.; Vedia, V.; De Witte, H.; Benito, J.; Bernard, R. N.; Berry, T.; Bracco, A.; Camera, F.; Ceruti, S.; Charviakova, V.; Cieplicka-Oryńczak, N.; Costache, C.; Crespi, F. C. L.; Creswell, J.; Fernandez-Martínez, G.; Fynbo, H.; Greenlees, P. T.; Homm, I.; Huyse, M.; Jolie, J.; Karayonchev, V.; Köster, U.; Konki, J.; Kröll, T.; Kurcewicz, J.; Kurtukian-Nieto, T.; Lazarus, I.; Lund, M. V.; Mǎrginean, N.; Mǎrginean, R.; Mihai, C.; Mihai, R. E.; Negret, A.; Orduz, A.; Patyk, Z.; Pascu, S.; Pucknell, V.; Rahkila, P.; Rapisarda, E.; Regis, J. M.; Robledo, L. M.; Rotaru, F.; Saed-Samii, N.; Sánchez-Tembleque, V.; Stanoiu, M.; Tengblad, O.; Thuerauf, M.; Turturica, A.; Van Duppen, P.; Warr, N.; IDS Collaboration

    2018-02-01

    The occurrence of octupolar shapes in the Ba isotopic chain was recently established experimentally up to N =90 . To further extend the systematics, the evolution of shapes in the most neutron-rich members of the Z =56 isotopic chain accessible at present, Ba,150148, has been studied via β decay at the ISOLDE Decay Station. This paper reports on the first measurement of the positive- and negative-parity low-spin excited states of 150Ba and presents an extension of the β -decay scheme of 148Cs. Employing the fast timing technique, half-lives for the 21+ level in both nuclei have been determined, resulting in T1 /2=1.51 (1 ) ns for 148Ba and T1 /2=3.4 (2 ) ns for 150Ba. The systematics of low-spin states, together with the experimental determination of the B (E 2 :2+→0+) transition probabilities, indicate an increasing collectivity in Ba-150148, towards prolate deformed shapes. The experimental data are compared to symmetry conserving configuration mixing (SCCM) calculations, confirming an evolution of increasingly quadrupole deformed shapes with a definite octupolar character.

  19. Stability of Tl-Ba-Ca-Cu-O superconducting thin films

    Energy Technology Data Exchange (ETDEWEB)

    Siegal, M. P. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Overmyer, D. L. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Venturini, E. L. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Padilla, R. R. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States); Provencio, P. N. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1421 (United States)

    1999-12-01

    We report the stability of TlBa{sub 2}CaCu{sub 2}O{sub 7} and Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8} on LaAlO{sub 3}(100) epitaxial thin films, under a variety of conditions. All films are stable in acetone and methanol and with repeated thermal cycling to cryogenic temperatures. Moisture, especially vapor, degrades film quality rapidly. These materials are stable to high temperatures in either N{sub 2} or O{sub 2} ambients. While total degradation, resulting from Tl depletion, occurs at the same temperatures for both phases, 600 degree sign C in N{sub 2} and 700 degree sign C in O{sub 2}, the onset of degradation occurs at somewhat lower temperatures for TlBa{sub 2}CaCu{sub 2}O{sub 7} than for Tl{sub 2}Ba{sub 2}CaCu{sub 2}O{sub 8}. (c) 1999 Materials Research Society.

  20. Surface structures and dielectric response of ultrafine BaTiO3 particles

    International Nuclear Information System (INIS)

    Jiang, B.; Peng, J.L.; Bursill, L.A.

    1998-01-01

    Characteristic differences are observed for the dielectric response and microstructures of BaTiO 3 nanoscale fine powders prepared using sol gel (SG) and steric acid gel (SAG) methods. The former exhibit a critical size below which there is no paraelectric/ferroelectric phase transition whereas BaTiO 3 prepared via the SAG route remained cubic for all conditions. Atomic resolution images of both varieties showed a high density of interesting surface steps and facets. Computer simulated images of surface structure models showed that the outer (100) surface was typically a BaO layer and that at corners and ledges the steps are typically finished with Ba+2 ions; i.e. the surfaces and steps are Ba-rich. Otherwise the surfaces were typically clean and free of amorphous layers. The relationship between the observed surfaces structures and theoretical models for size effects on the dielectric properties is discussed. (authors)

  1. Identification of the neutron-rich nuclides /sup 147; 148/Ba and half- life determination of the heavy isotopes of Rb, Sr, Y, Cs, Ba and La

    CERN Document Server

    Amiel, S; Nir-El, Y; Shmid, M

    1976-01-01

    The neutron nuclides /sup 147; 148/Ba were produced in the thermal neutron induced fission of /sup 235/U. A new surface ionization integrated target ion source operating at temperatures in the region of 1800 degrees C permits the measurement of half-lives of isotopes down to about 0.1 sec due to the very fast release of atoms from the target. Isotopes of Rb, Sr, Cs, and Ba were separated by positive surface ionization and their half-lives measured using beta activity detected by a silicon surface barrier detector with a depletion depth of 300 mu . The isotopes /sup 147/Ba and /sup 148/Ba were identified for the first time and their half-lives were found to be 0.72+or-0.07 sec and 0.47+or-0.20 sec, respectively. (0 refs).

  2. Ocorrência de Mollicutes e Ureaplasma spp. em surto de doença reprodutiva em rebanho bovino no Estado da Paraíba Occurrence of Mollicutes and Ureaplasma spp. in outbreak of reproductive disease in cattle herds, State of Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Sandra B. dos Santos

    2013-03-01

    Full Text Available Em março de 2012 foi diagnosticado um surto de doença reprodutiva em rebanho bovino no Estado da Paraíba, Brasil. Foram examinadas 32 vacas e dois touros da raça Girolando. As vacas apresentaram sinais de doença reprodutiva como repetição de cio, vulvovaginite granular, infertilidade e abortos. As amostras de suabes vaginais e prepuciais foram colhidas e submetidas a isolamento bacteriano e PCR. As reações da PCR para Mollicutes e Ureaplasma spp. foram realizadas com os iniciadores MGSO-GPO3 e UGP'F-UGP'R, respectivamente. Na Nested PCR para Ureaplasma diversum, os iniciadores usados foram UD1, UD2, UD3 e UD4. Para isolamento bacteriano, as amostras foram diluídas de 10-1 até 10-5, semeadas em meio "UB", líquido e placa, sendo incubadas por até 21 dias a 37ºC em jarra de microaerofilia. A frequência de Mollicutes detectada na PCR foi de 65,6% e para Ureaplasma spp. foi de 50,0%, enquanto que para U. diversum foi de 15,6%. No isolamento a frequência de Mollicutes foi de 57,1% e para Ureaplasma spp. foi de 28,6%. No ágar "UB" foi visualizado o crescimento misto de Mycoplasma spp. e Ureaplasma spp. em seis amostras. Foi confirmado o envolvimento de micro-organismos da Classe Mollicutes em surto de doença reprodutiva em vacas no sertão paraibano.In March of 2012 was investigated a reproductive disease outbreak in cattle herds from Paraíba State, Brazil. Were examined 32 cows and two bulls Giroland breed. The cows showed signs and symptoms of reproductive failure such as repeat breeding, granular vulvovaginitis, infertility and abortions. Vaginal and preputial mucous samples were collected for analysis by PCR and isolation. The PCR reactions for Mollicutes and Ureaplasma spp. were realized with primers MGSO and GPO3, and UGP'F and UGP'R respectively. The nested PCR assay for Ureaplasma diversum was realized with primers UD1, UD2, UD3 and UD4. For bacteriologic isolation, obtained samples were diluted up to 10-1 at 10-5, inoculated

  3. Bifunctional properties of hydrothermal synthesized BaMF4 (M = Co, Ni and Zn

    Directory of Open Access Journals (Sweden)

    Farheen N. Sayed

    2013-07-01

    Full Text Available BaMF4 (M = Co, Ni and Zn samples having orthorhombic structure have been synthesized by a mild hydrothermal method and characterized by x-ray diffraction (XRD, magnetic and electrical measurements. Single phase formation of these compounds has been found to be dependent on various factors like reaction time, pH, temperature etc. All the samples showed ferroelectricity, which decreases with increase in temperature. BaMF4 (M = Co, Ni samples show 10-15 times more leakage current compared to that of BaZnF4 at higher applied field. Absence of multivalent ions in BaZnF4 can be the reason for its minimum leakage current. All the samples except, BaZnF4, exhibit weak room temperature ferromagnetism also.

  4. Estimation of the specific mass effect in the isotope shifts of energy levels in the optical spectrum of Ba I and Ba II

    International Nuclear Information System (INIS)

    Pendrill, L.R.

    1984-01-01

    A graphical method for separating mass and volume effects from purely optical isotope shift data is presented and compared with King's ''bunching'' method. Recent experimental data on isotope shifts for a wide range of spectral lines in the naturally abundant isotopes of Ba I and Ba II are analysed. Some agreement is found with muonic X-ray data concerning the nuclear size for the isotopes 136, 137 and 138, but there is disagreement (over 20%) for the other isotopes. The level isotope shifts are further parameterised in terms of a linear model, and the specific mass effect is decomposed into sums of one-electron and two-electron shift parameters with respect to the inert-gas like ground state of Ba III. (orig.)

  5. Intertextuality in Ba's So Long a Letter and Umunnakwe's Dear ...

    African Journals Online (AJOL)

    Intertextuality takes for granted the interdependence of literary texts because every artistic creation is a re-echoing of past knowledge. Mariama Ba's So Long A Letter and Ndubisi Umunnakwe's Dear Ramatoulaye are African examples. This work examines how Ba's So Long A Letter intertextualises with Umunnakwe's Dear ...

  6. A Dubious Distinction? The BA versus the BS in Psychology

    Science.gov (United States)

    Pfund, Rory A.; Norcross, John C.; Hailstorks, Robin; Aiken, Leona S.; Stamm, Karen E.; Christidis, Peggy

    2016-01-01

    Previous studies have documented small differences between the bachelor of arts (BA) and the bachelor of science (BS) psychology degrees in their general education core requirements, particularly mathematics and science courses. But are there differences between the BA and BS degrees within the psychology curriculum? Using data from the…

  7. modified BiFeO3–BaTiO3

    Indian Academy of Sciences (India)

    based perovskite structures lead- free BiFeO3–BaTiO3 solid solutions are popularly studied due to the high Curie temperature (TC). It was reported that the BiFeO3–BaTiO3 system possessed high piezoelectric. ∗. Author for correspondence ...

  8. CeF3(Ba) radiation hard scintillator for electromagnetic calorimeters

    International Nuclear Information System (INIS)

    Aseev, A.A.; Devitsin, E.G.; Kozlov, V.A.; Hovepyan, Yu.I.; Potashov, S.Yu.; Sokolovsky, K.A.; Uvarova, T.V.; Vasilchenko, V.G.

    1992-01-01

    The influence of divalent fluoride dopants BaF 2 , CaF 2 , SrF 2 on radiation and luminescent properties of CeF 3 crystal is studied. A high radiation hardness (>10 8 rad) has been obtained for CeF 3 crystals doped with BaF 2 . (orig.)

  9. Electrodeposition of BaCO3 coatings on stainless steel substrates ...

    Indian Academy of Sciences (India)

    Administrator

    Dedicated to the memory of the late Professor S K Rangarajan. *For correspondence. Electrodeposition of BaCO3 coatings on stainless steel substrates: Oriented growth ... orientation by an interfacial molecular recognition mechanism. BaCO3 has important applications in paint, ceramic, and paper industries. Also it is used ...

  10. Description of a newly discovered Triatoma infestans (Hemiptera: Reduviidae Foci in Ibipeba, State of Bahia, Brazil

    Directory of Open Access Journals (Sweden)

    Renato Freitas Araújo

    2014-07-01

    Full Text Available Introduction Chagas disease transmitted by the Triatoma infestans was eradicated from Brazil in 2006. However, reports of triatomine foci threaten the control of Chagas disease. The goal of this study was to determine T. infestans foci in the City of Ibipeba, State of Bahia. Methods Triatominae specimens were collected in Ibipeba and entomologic indicators were calculated using indices of domiciliary infestation, density, and colonization. Results T. infestans foci was discovery in Ibipeba, State of Bahia. Approximately 95% of the specimens were discovered inside dwellings, of which 34% were T. infestans. This species was also discovered forming a colony in tree bark in the peridomicile. Conclusions Triatoma infestans foci in peridomestic ecotopes in Ibipeba, BA, indicate increased the risk of transmission Chagas disease.

  11. Beyond survival: fostering growth and innovation in doctoral study--a concept analysis of the Ba space.

    Science.gov (United States)

    Krahe, J A E; Lalley, Cathy; Solomons, Nan M

    2014-01-25

    This concept analysis examines the Ba space in the context of interdisciplinary doctoral study in nursing and healthcare innovation in a minimal residency program. The authors identified Ba in their small, highly diverse, self-selected doctoral study group and believe Ba is an educational innovation that will prove useful to nursing and healthcare educators. Ba originates from Japanese philosophy and is foundational to the birth and sustainment of environments fostering knowledge creation. Ba manifests in complex environments where participants are emotionally invested and relies on the tacit knowledge of each participant, allowing for synthesis of rationality and intuition. Walker and Avant's concept analysis methodology will explore Ba's centrality to interdisciplinary education. Ba's utility and application in fostering innovation in doctoral study will be illustrated. Ba is a true educational innovation, enriching learning environments promoting interdisciplinary collaboration. Ba permits each member a voice and fosters a safe environment where relationships are created and sustained.

  12. Analysis of the Unified Health System funding and expenditure in the municipalities of the "Rota dos Bandeirantes" health region, State of São Paulo, Brazil.

    Science.gov (United States)

    Santos, João Alves Dos; Mendes, Áquilas Nogueira; Pereira, Antônio Carlos; Paranhos, Luiz Renato

    2017-04-01

    The national scenario of lack of resources in the Brazilian Unified Health System (SUS) has led to major differences in the municipalities funding models. Thus, this study aims to analyze SUS funding and expenditure in seven cities of the Rota dos Bandeirantes health region, State of São Paulo, SP, Brazil, from 2009 to 2012. Settled expenditure indicators were collected from the Public Health Budgets Information System (SIOPS) for analysis, showing descriptive data with absolute and relative frequency calculations. We identified that the per capita income available for the city of Barueri is almost tenfold that of the city of Carapicuíba, and that Barueri's health expenditure per capita is more than double that of the regional average and almost fivefold that of Carapicuíba. The Federal Government is responsible for 95.4% of all funding to municipalities. Most of the available income of the municipalities in the region include their own taxes and state transfers. All the municipalities showed a significant positive trend, both for available income and health expenditure. The regional average of own revenue spent on health is 27.3%. Carapicuíba achieved a level of 37.5%, which is much higher than the minimum of 15% required by the Federal Constitution.

  13. Superconductivity in gallium-substituted Ba8Si46 clathrates

    Science.gov (United States)

    Li, Yang; Zhang, Ruihong; Liu, Yang; Chen, Ning; Luo, Z. P.; Ma, Xingqiao; Cao, Guohui; Feng, Z. S.; Hu, Chia-Ren; Ross, Joseph H., Jr.

    2007-02-01

    We report a joint experimental and theoretical investigation of superconductivity in Ga-substituted type-I silicon clathrates. We prepared samples of the general formula Ba8Si46-xGax , with different values of x . We show that Ba8Si40Ga6 is a bulk superconductor, with an onset at TC≈3.3K . For x=10 and higher, no superconductivity was observed down to T=1.8K . This represents a strong suppression of superconductivity with increasing Ga content, compared to Ba8Si46 with TC≈8K . Suppression of superconductivity can be attributed primarily to a decrease in the density of states at the Fermi level, caused by a reduced integrity of the sp3 -hybridized networks as well as the lowering of carrier concentration. These results are corroborated by first-principles calculations, which show that Ga substitution results in a large decrease of the electronic density of states at the Fermi level, which explains the decreased superconducting critical temperature within the BCS framework. To further characterize the superconducting state, we carried out magnetic measurements showing Ba8Si40Ga6 to be a type-II superconductor. The critical magnetic fields were measured to be HC1≈35Oe and HC2≈8.5kOe . We deduce the London penetration depth λ≈3700Å and the coherence length ξc≈200Å . Our estimate of the electron-phonon coupling reveals that Ba8Si40Ga6 is a moderate phonon-mediated BCS superconductor.

  14. BaMa / Raivo Juurak

    Index Scriptorium Estoniae

    Juurak, Raivo, 1949-

    2002-01-01

    Eesti ülikoolide üleminekust 3+2 süsteemile. Lühend BaMa on tulnud kasutusele seoses Euroopa ülikoolide õppekavade reformimisega ning tähistab õppekava, kus esimese astme läbimise järel omandatakse bakalaureuse- ja teise järel magistrikraad. Õppekavade tüüpidest Eesti ja Euroopa Liidu kõrgkoolides ning Bologna deklaratsioonist

  15. Hexagonal perovskites with cationic vacancies. 21. Structure of Ba/sub 4/Nb/sub 2/WvacantO/sub 12/ and Ba/sub 3/LaNb/sub 3/vacantO/sub 12/

    Energy Technology Data Exchange (ETDEWEB)

    Rother, H J; Kemmler-Sack, S; Treiber, U; Cyris, W R [Tuebingen Univ. (Germany, F.R.). Lehrstuhl fuer Anorganische Chemie 2

    1980-07-01

    Compounds of type Ba/sub 4/M/sub 2/sup(V)WvacantO/sub 12/ and Ba/sub 3/LaM/sub 3/sup(V)vacantO/sub 12/ with Msup(V) = Nb, Ta belong to the group of rhombohedral 12 L stacking polytypes (space group R-3m, sequence (hhcc)/sub 3/). The structure determinations on powder patterns for the Nb compounds gave a refined, intensity related R' value of 6.3% (Ba/sub 4/Nb/sub 2/WvacantO/sub 12/) and 6.6% (Ba/sub 3/LaNb/sub 3/vacantO/sub 12/). The octahedral net consists of blocks of three face connected octahedra with a central void (M/sub 2/vacantO/sub 12/ unit), which are linked to each other through single corner sharing octahedra. In both compounds the M atoms in the M/sub 2/vacantO/sub 12/ groups are displaced in the direction of the central void. The A atoms move in the same direction but the dislocation for A in the hexagonal packed sheets (neighbouring the vacancies) is stronger than in the cubic packed AO/sub 3/ sheets. The results of the vibrational spectroscopic investigations are reported for Ba/sub 4/Nb/sub 2/WvacantO/sub 12/, Ba/sub 4/Ta/sub 2/WvacantO/sub 12/, Ba/sub 3/LaNb/sub 3/vacantO/sub 12/ and Ba/sub 4/CeW/sub 2/vacantO/sub 12/; they are discussed in connection with the factor group analysis.

  16. Adsorption removal of Sr by Barium impregnated 4A Zeolite(BaA) from high radioactive seawater waste

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Eil Hee; Lee, Keun Young; Kim, Kwang Wook; Kim, Ik Soo; Chung, Dong Yong; Moon, Jei Kwon; Choi, Jong Won [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-06-15

    This study investigated the removal of Sr, which was one of the high radioactive nuclides, by adsorption with Barium (Ba) impregnated 4A zeolite (BaA) from high-radioactive seawater waste (HSW). Adsorption of Sr by BaA (BaA-Sr), in the impregnated Ba concentration of above 20.2wt%, was decreased by increasing the impregnated Ba concentration, and the impregnated Ba concentration was suitable at 20.2wt%. The BaA-Sr adsorption was added to the co-precipitation of Sr with BaSO4 precipitation in the adsorption of Sr by 4A (4A-Sr) within BaA. Thus, it was possible to remove Sr more than 99% at m/V (adsorbent weight/solution volume)=5 g/L for BaA and m/V >20 g/L for 4A, respectively, in the Sr concentration of less than 0.2 mg/L (actual concentration level of Sr in HSW). It shows that BaA-Sr adsorption is better than 4A-Sr adsorption in for the removal capacity of Sr per unit gram of adsorbent, and the reduction of the secondary solid waste generation (spent adsorbent etc.). Also, BaA-Sr adsorption was more excellent removal capacity of Sr in the seawater waste than distilled water. Therefore, it seems to be effective for the direct removal of Sr from HSW. On the other hand, the adsorption of Cs by BaA (BaA-Cs) was mainly performed by 4A within BaA. Accordingly, it seems to be little effect of impregnated Ba into BaA. Meanwhile, BaA-Sr adsorption kinetics could be expressed the pseudosecond order rate equation. By increasing the initial Sr concentrations and the ratios of V/m, the adsorption rate constants (k2) were decreased, but the equilibrium adsorption capacities (qe) were increasing. However, with increasing the temperature of solution, k2 was conversely increased, and qe was decreased. The activation energy of BaA-Sr adsorption was 38 kJ/mol. Thus, the chemical adsorption seems to be dominant rather than physical adsorption, although it is not a chemisorption with strong bonding form.

  17. Stellar neutron capture cross sections of the Ba isotopes

    International Nuclear Information System (INIS)

    Voss, F.; Wisshak, K.; Guber, K.; Kaeppeler, F.; Reffo, G.

    1994-03-01

    The neutron capture cross sections of 134 Ba, 135 Ba, 136 Ba, and 137 Ba were measured in the energy range from 5 to 225 keV at the Karlsruhe 3.75 MV Van de Graaff accelerator. Neutrons were produced via the 7 Li(p,n) 7 Be reaction by bombarding metallic Li targets with a pulsed proton beam. Capture events were registered with the Karlsruhe 4π Barium Fluoride Detector. Several runs have been performed under different experimental conditions to study the systematic uncertainties, which resulted mainly from the large ratios of total to capture cross sections of up to 400. The cross section ratios were determined with an overall uncertainty of ∼3%, an improvement by factors of five to eight compared to existing data. Severe discrepancies were found with respect to previous results. Maxwellian averaged neutron capture cross sections were calculated for thermal energies between kT=10 keV and 100 keV. These stellar cross sections were used in an s-process analysis. For the s-only isotopes 134 Ba and 136 Ba the N s ratio was determined to 0.875±0.025. Hence, a significant branching of the s-process path at 134 Cs can be claimed for the first time, in contrast to predictions from the classical approach. This branching yields information on the s-process temperature, indicating values around T 8 =2. The new cross sections are also important for the interpretation of barium isotopic anomalies, which were recently discovered in SiC grains of carbonaceous chondrite meteorites. Together with the results from previous experiments on tellurium and samarium, a general improvement of the N s systematics in the mass range A=120 to 150 is achieved. This allows for a more reliable separation of s- and r-process yields, resulting in an improved assignment of the respective contributions to elemental barium that is required for comparison with stellar observations. (orig.) [de

  18. BaFCl:Eu2+, a new phosphor for X-ray-intensifying screens

    International Nuclear Information System (INIS)

    Stevels, A.L.N.; Pingault, F.

    1975-01-01

    A number of phosphors for X-ray-intensifying screens have been evaluated by calculating figures of merit. On use in combination with standard (''blue''-sensitive) X-ray film, BaFCl:Eu 2+ and BaFBr:Eu 2+ give better performance than the traditional CaWO 4 and more recently developed UV or blue-emitting materials (e.g., sulphates and y-oxysulphides). The calculated figures of merit of BaFCl:Eu 2+ or BaFBr:Eu 2+ /standard-film combinations are comparable to those of Gd 2 O 2 S:Tb/green-sensitive X-ray film systems. The preparation of optimal fluorohalide:Eu 2+ phosphors involves proper formation of the host lattice, complete reduction of Eu 3+ ions as well as elimination of afterglow. Measurements on powders and experimental screens indicate that by using BaFCl:Eu 2+ screens in radiography, important dose reductions can be achieved without the necessity of using other than standard (''blue''-sensitive) X-ray films

  19. Population structure and juvenile habitat use of dusky grouper (Epinephelus marginatus in southern Brazil

    Directory of Open Access Journals (Sweden)

    Mario Vinicius Condini

    2015-11-01

    Full Text Available A better understanding of population dynamics including the identification of reproductive areas and their contribution to the maintenance of fish stocks is essential for population conservation. Dusky grouper, Epinephelus marginatus, is a broadly distributed fish species, usually found in marine rocky bottoms. It is currently listed as “endangered” by the IUCN Red List. The available information on its population in southern Brazil suggests that the neritic habitat of Carpinteiro Bank - CB is the main growth and spawning ground in the region. We investigated if the dusky groupers caught in the rocky-jetties of Rio Grande city (a littoral artificial habitat with no spawning activity originated from the CB. We sampled 28 individuals from the littoral rocky-jetties aged between 2 and 12 years, and 44 individuals from the neritic CB aged between 2 and 40 years. Individuals from both areas had their otolith sections analyzed with LA-ICPMS (core-to-edge profiles for 86Sr:43Ca, 138Ba:43Ca ratios. The otolith core (natal origin and edge (time shortly before capture from individuals of the same age class showed no difference between the two sites. Individual profiles of 138Ba:43Ca ratios of fish from the littoral zone indicated, for the first time, that some juveniles of dusky grouper enter the Patos lagoon and remain within the estuarine environment between the first and second years of life. This interpretation of otolith chemical data is supported by the marked differences in salinity between the littoral and estuarine sites in these studies areas, and by the marked differences in otolith 138Ba:43Ca of other fish species analyzed along the salinity gradient in the Patos Lagoon estuary. The identification of differential juvenile habitat use patterns is crucial for the establishment and implementation of management and conservation strategies to safeguard this endangered species.

  20. Rapid preparation of ultrafine BaSO{sub 3} by SO{sub 2} storage material

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fei; Sha, Feng; Qiao, Xian Shu; Zhao, Tian Xiang; Guo, Bo; Zhang, Jian Bin [College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot (Korea, Republic of)

    2017-01-15

    In this work, a green and efficient process was developed for the preparation of ultrafine BaSO{sub 3} with layered nanostructure surface via the reaction of BaCl{sub 2} with a SO{sub 2} storage material (SO{sub 2}SM) at room temperature. The absorption of SO{sub 2} with equimolar ethylenediamine (EDA) and ethylene glycol (EG) afforded SO{sub 2}SM, which not only offered alkyl sulfite but also released EDA and EG that served as efficient surfactants to promote the formation of BaSO{sub 3} with spherical morphology and porous structure in the process of synthesis of ultrafine BaSO{sub 3}. The factors affecting the morphology and size of BaSO{sub 3} particle were assessed by investigating the effects of SO{sub 2}SM concentration, BaCl{sub 2} concentration, stirring time and speed. It was found that a higher SO{sub 2}SM concentration led to a higher degree of supersaturation, and the particle size of BaSO{sub 3} could be reduced by increasing SO{sub 2}SM concentration. Moreover, under the identified optimal reaction conditions, ultrafine BaSO{sub 3} was obtained with an average diameter of 450 nm. In addition, a plausible formation process of BaSO{sub 3} was proposed to explain the observed reaction results. Overall, the developed process in this work provides an efficient method for the capture, utilization, and conversion of SO{sub 2} into a valuable chemical.

  1. Synthesis of BaTiO3 powder from barium titanyl oxalate (BTO ...

    Indian Academy of Sciences (India)

    Unknown

    the synthesis of BaTiO3 from the mixture of barium car- bonate and titanium dioxide employing microwave heat- ing. They observed that hypostoichiometric TiO2 (TiO2–x) reacted with BaCO3 in the presence of microwave field at temperature as low as 350°C to give the mixture of hexa- gonal and tetragonal forms of BaTiO3 ...

  2. Self-Organized Ni Nanocrystal Embedded in BaTiO3 Epitaxial Film

    Directory of Open Access Journals (Sweden)

    Ge FF

    2010-01-01

    Full Text Available Abstract Ni nanocrystals (NCs were embedded in BaTiO3 epitaxial films using the laser molecular beam epitaxy. The processes involving the self-organization of Ni NCs and the epitaxial growth of BaTiO3 were discussed. With the in situ monitoring of reflection high-energy electron diffraction, the nanocomposite films were engineered controllably by the fine alternation of the self-organization of Ni NCs and the epitaxial growth of BaTiO3. The transmission electron microscopy and the X-ray diffraction characterization confirmed that the composite film consists of the Ni NCs layers alternating with the (001/(100-oriented epitaxial BaTiO3 separation layers.

  3. submitter Performance simulation of BaBar DIRC bar boxes in TORCH

    CERN Document Server

    Föhl, K; Castillo García, L; Cussans, D; Forty, R; Frei, C; Gao, R; Gys, T; Harnew, N; Piedigrossi, D; Rademacker, J; Ros García, A; van Dijk, M

    2017-01-01

    TORCH is a large-area precision time-of-flight detector based on the DIRC principle. The DIRC bar boxes of the BaBar experiment at SLAC could possibly be reused to form a part of the TORCH detector time-of-flight wall area, proposed to provide positive particle identification of low momentum kaons in the LHCb experiment at CERN. For a potential integration of BaBar bar boxes into TORCH, new imaging readout optics are required. From the several designs of readout optics that have been considered, two are used in this paper to study the effect of BaBar bar optical imperfections on the detector reconstruction performance. The kaon-pion separation powers obtained from analysing simulated photon hit patterns show the performance reduction for a BaBar bar of non-square geometry compared to a perfectly rectangular cross section.

  4. INAA and ICP-MSHS. Metal pollutants in fish tissues Nile tilapia (Oreochromic niloticus) in Pampulha Lake, Belo Horizonte city, Minas Gerais State, Brazil

    International Nuclear Information System (INIS)

    Veado, M.A.R.V.; Heeren, A.O.; Arantes, I.A.; Grenier-Loustalot, M.F.; Cabaleiro, H.L.; Almeida, M.R.M.G.

    2007-01-01

    Pampulha Lake, Minas Gerais, Brazil, is being polluted via its tributaries, Sarandi and Ressaca. Instrumental neutron activation analysis and inductively coupled plasma mass spectrometry high resolution were applied to determine Al, As, B, Ba, Co, Cr, Cs, Cu, Fe, K, Mg, Mn, Mo, Na, P, Pb, Rb, Zn and Ti in Nile tilapia fish, Oreochromis niloticus. The organs analyzed were: intestine, spleen, heart, testicle, kidney, liver, gills and muscle. The results demonstrated relatively high concentrations of Al, Co, Cu, Fe, P and Ti in gills, Al and Cu in liver, Al in intestine and Fe in muscle and spleen. (author)

  5. Melatonin ve Bağışıklık Sistemi

    OpenAIRE

    ÇETİN, E.

    2005-01-01

    Melatonin, pineal bezin beta adrenerjik reseptörlerinin aktivasyonu ile triptofandan sentezlenen bir hormondur.Üretim ve salınımı karanlık ile başlar ve aydınlıkla sona erer. Melatonin, birçok biyolojik fonksiyonun düzenlenmesinderol oynar. Bu derlemede melatonin hakkında genel bilgiler verilerek, melatoninin lenfoid dokular, humoral bağışıklık,hücresel bağışıklık ve kanser üzerine etkileri tartışılmıştır

  6. Phase equilibria, crystal chemistry, electronic structure and physical properties of Ag-Ba-Ge clathrates

    Energy Technology Data Exchange (ETDEWEB)

    Zeiringer, I.; Chen Mingxing [Institute of Physical Chemistry, University of Vienna, Waehringerstr. 42, 1090 Wien (Austria); Bednar, I.; Royanian, E.; Bauer, E. [Institute of Solid State Physics, Vienna University of Technology, Wiedner Hauptstr. 8-10, 1040 Wien (Austria); Podloucky, R.; Grytsiv, A. [Institute of Physical Chemistry, University of Vienna, Waehringerstr. 42, 1090 Wien (Austria); Rogl, P., E-mail: peter.franz.rogl@univie.ac.at [Institute of Physical Chemistry, University of Vienna, Waehringerstr. 42, 1090 Wien (Austria); Effenberger, H. [Institute of Mineralogy and Crystallography, University of Vienna, A-1090 Wien (Austria)

    2011-04-15

    In the Ag-Ba-Ge system the clathrate type-{Iota} solid solution, Ba{sub 8}Ag{sub x}Ge{sub 46-x-y{open_square}y}, extends at 800 deg. C from binary Ba{sub 8}Ge{sub 43{open_square}3} ({open_square} is a vacancy) to Ba{sub 8}Ag{sub 5.3}Ge{sub 40.7}. For the clathrate phase (1 {<=} x {<=} 5.3) the cubic space group Pm3-bar n was established by X-ray powder diffraction and confirmed by X-ray single-crystal analyses of the samples Ba{sub 8}Ag{sub 2.3}Ge{sub 41.9{open_square}1.8} and Ba{sub 8}Ag{sub 4.4}Ge{sub 41.3{open_square}0.3}. Increasing the concentration of Ag causes the lattice parameters of the solid solution to increase linearly from a value of a = 1.0656 (x = 0, y = 3) to a = 1.0842 (x = 4.8, y = 0) nm. Site preference determination using X-ray refinement reveals that Ag atoms preferentially occupy the 6d site randomly mixed with Ge and vacancies, which become filled in the compound Ba{sub 8}Ag{sub 4.8}Ge{sub 41.2} when the Ag content increases. At 600 {sup o}C the phase region of the clathrate solution Ba{sub 8}Ag{sub x}Ge{sub 46-x-y{open_square}y} becomes separated from the Ba-Ge boundary and extends from 6.6 to 9.8 at.% Ag. The compound Ba{sub 6}Ge{sub 25} (clathrate type-{Iota}X) dissolves at 800 {sup o}C a maximum of 1.5 at.% Ag. The homogeneity regions of the two ternary compounds BaAg{sub 2-x}Ge{sub 2+x} (ThCr{sub 2}Si{sub 2}-type, 0.2 {<=} x {<=} 0.7) and Ba(Ag{sub 1-x}Ge{sub x}){sub 2} (AlB{sub 2}-type, 0.65 {<=} x {<=} 0.75) were established at 800 deg. C. Studies of transport properties for the series of Ba{sub 8}Ag{sub x}Ge{sub 46-x-y{open_square}y} compounds evidenced that electrons are the predominant charge carriers with the Fermi energy close to a gap. Its position can be fine-tuned by the substitution of Ge by Ag atoms and by mechanical processing of the starting material, Ba{sub 8}Ge{sub 43}. The proximity of the electronic structure at Fermi energy of Ba{sub 8}Ag{sub x}Ge{sub 46-x-y{open_square}y} to a gap is also corroborated by density

  7. BaCO3 mediated modifications in structural and magnetic properties of natural nanoferrites

    Science.gov (United States)

    Widanarto, W.; Jandra, M.; Ghoshal, S. K.; Effendi, M.; Cahyanto, W. T.

    2015-04-01

    Preparing M-type barium hexaferrite and improving the magnetic response of natural ferrites by incorporating barium carbonate (BaCO3) is ever-demanding. Series of barium carbonate doped ferrites with composition (100-x)Fe3O4·xBaCO3 (x=0, 10, 20, 30 wt%) are prepared through solid state reaction method and sintered gradually at temperatures of 800 and 1000 °C. Nanoparticles of natural ferrite and commercial BaCO3 are used as raw materials. Impacts of BaCO3 on structural and magnetic properties of these synthesized ferrites are inspected. The obtained ferrites are characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and vibrating sample magnetometer (VSM) at room temperature. Uniform barium hexaferrite particles in terms of both morphology and size are not achieved. The average crystallite size of BaFe12O19 is observed to be within 30-600 nm. The sintering process results phase transformation from Fe3O4 (magnetite) to α-Fe2O3 (hematite) and the formation of hexagonal barium ferrite crystals. The occurrence of barium crystal is found to enhance with the increase of BaCO3 concentrations up to 20 wt% and suddenly drop at 30 wt%. Saturation and remanent magnetization of the doped ferrites are significantly augmented up to 16.37 and 8.92 emu g-1, respectively compared to their pure counterpart. Furthermore, the coercivity field is slightly decreased as BaCO3 concentrations are increased. BaCO3 mediated improvements in the magnetic response of natural ferrites are demonstrated.

  8. Topological phases in Ba-Borate glasses

    Science.gov (United States)

    Holbrook, Chad; Czaja, Andrew; Boolchand, Punit

    2015-03-01

    Twelve compositions in the (BaO)x(B2O3)100-x pseudo binary, in the 15% Modulated- DSC and Raman scattering experiments were undertaken systematically as function of BaO content (x). Calorimetric measurements reveal Tg(x) to show a broad maximum and the non-reversing enthalpy to show a Gaussian-like reversibility window2, both centered near x = 28%. Raman scattering displays rich lineshapes with modes similar to those observed in Na-Borates2. Modes near 808 cm-1, 770 cm-1, 740 cm-1 and 705 cm-1 are observed, and identified with breathing modes of pure and mixed rings from characteristic structural groupings2. These preliminary results suggest that glasses at x 30% in the flexible phase. Supported by NSF Grant DMR 08-53957.

  9. Aspectos clínicos, epidemiológicos e patológicos da infecção natural em bovinos por Trypanosoma vivax na Paraíba Clinical, epidemiological and pathological signs of natural infection in cattle by Trypanosoma vivax in Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Jael S. Batista

    2008-01-01

    located in the state of Paraíba, northeastern Brazil. The epidemiology, clinical signs and pathology of the disease were studied from May 2005 to November 2006. T. vivax was identified morphologically and by polymerase chain reaction test (PCR. The affected cattle presented anorexia, depression, fever, anemia, weight loss, reduction in milk production, transitory blindness, abortion and some nervous signs as nystagmus, tetany and bruxism. All cattle that presented nervous signs died. Necropsy findings were enlarged lymph and spleen, serous atrophy of the fat depots, proeminence of the splenic white pulp, hydropericardium and pericardial petechiae and ecchymoses on the epicardium. Histologically there was meningoencephalitis. The treatment of the clinical cases with diminazena aceturate was efficient with clearance of the parasite from the blood or disappearance of clinical signs in up to 2 months after the beginning of the outbreak on the two farms studied. The epidemiologic factors favoring the occurrence of the outbreak were the abundance of mechanical vectors, as tabanids and Stomoxys sp., and the introduction into the herd of cattle from farms where the disease occurred. It is suggested that the semiarid of the Brazilian Northeast is an enzootic instability region for trypanosomiasis due to its prolonged periods of drought and high temperatures, constituting during most part of the year an unfavorable environment for the development of vectors.

  10. BaSi2 formation mechanism in thermally evaporated films and its application to reducing oxygen impurity concentration

    Science.gov (United States)

    Hara, Kosuke O.; Yamamoto, Chiaya; Yamanaka, Junji; Arimoto, Keisuke; Nakagawa, Kiyokazu; Usami, Noritaka

    2018-04-01

    Thermal evaporation is a simple and rapid method to fabricate semiconducting BaSi2 films. In this study, to elucidate the BaSi2 formation mechanism, the microstructure of a BaSi2 epitaxial film fabricated by thermal evaporation has been investigated by transmission electron microscopy. The BaSi2 film is found to consist of three layers with different microstructural characteristics, which is well explained by assuming two stages of film deposition. In the first stage, BaSi2 forms through the diffusion of Ba atoms from the deposited Ba-rich film to the Si substrate while in the second stage, the mutual diffusion of Ba and Si atoms in the film leads to BaSi2 formation. On the basis of the BaSi2 formation mechanism, two issues are addressed. One is the as-yet unclarified reason for epitaxial growth. It is found important to quickly form BaSi2 in the first stage for the epitaxial growth of upper layers. The other issue is the high oxygen concentration in BaSi2 films around the BaSi2-Si interface. Two routes of oxygen incorporation, i.e., oxidation of the Si substrate surface and initially deposited Ba-rich layer by the residual gas, are identified. On the basis of this knowledge, oxygen concentration is decreased by reducing the holding time of the substrate at high temperatures and by premelting of the source. In addition, X-ray diffraction results show that the decrease in oxygen concentration can lead to an increased proportion of a-axis-oriented grains.

  11. Conhecimento ecológico local de pescadores da Baía Babitonga, Santa Catarina, Brasil: peixes da família Serranidae e alterações no ambiente marinho = Local ecological knowledge of fishermen from Babitonga Bay, Santa Catarina, Brazil: fishes from the Serranidae family and marine environmental changes

    Directory of Open Access Journals (Sweden)

    Leopoldo Cavaleri Gerhardinger

    2006-07-01

    Full Text Available Investigamos aspectos gerais do Conhecimento Ecológico Local (CEL depescadores de espinhel e pesca subaquática sobre sete espécies de peixes marinhos da família Serranidae (habitat de ocorrência, tamanho máximo e denominação popular e as principais alterações percebidas no ambiente marinho na Baía Babitonga, Estado de Santa Catarina,Brasil. Em termos gerais, o CEL sobre os peixes corrobora a literatura em ictiologia, trazendo informações originais em escala local. Pescadores de comunidades vizinhas e/ou praticantes de diferentes artes de pesca podem desenvolver denominações e um corpo deCEL diferenciado sobre os recursos pesqueiros de uma mesma área. Verificamos que a legislação que institui a moratória da pesca de Epinephelus itajara desconsidera as denominações locais da espécie, impossibilitando a sua interpretação pelos pescadores locais e gerando conflitos na aplicação da lei. As principais alterações ambientais registradas foram: diminuição da abundância dos recursos pesqueiros em geral (especialmente do Parambijú Rachycentron canadum, e os efeitos da interrupção antrópica do “Canal do Linguado” na hidrologia e sedimentologia da Baía Babitonga (assoreamento e aumento da turbidez da água.General aspects of the Local Ecological Knowledge (LEK of long-line and spear fishermen on seven fish species of the Serranidae family (habitat use, maximum size and popular names and on the main marine environmental changes were investigated in Babitonga Bay, Santa Catarina State, Brazil. In general, LEK on fishes corroborates theichthyology literature, bringing original information in a local scale. Neighbor fishermen communities can develop different local species nomenclature and different LEK for fishery resources at the same area. We have verified that the fishing ban legislation on Epinephelus itajara in Brazil does not consider local species denominations, turning impossible its interpretation by local

  12. Growth and scintillation properties of BaMgF{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Yanagida, Takayuki, E-mail: t_yanagi@tagen.tohoku.ac.j [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Kawaguchi, Noriaki [Tokuyama Corporation, Shibuya 3-chome, Shibuya-ku, Tokyo 150-8383 (Japan); Fujimoto, Yutaka; Sugiyama, Makoto; Furuya, Yuki; Kamada, Kei; Yokota, Yuui [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yoshikawa, Akira [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); New Industry Creation Hatchery Center (NICHe), Tohoku University, 6-6-10 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Chani, Valery [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2010-09-21

    By using the micro-pulling down ({mu}-PD) method, the barium magnesium fluoride (BaMgF{sub 4}) single crystalline scintillator was produced. The crystal was cut and mirror polished to the physical dimensions of 1x2x10 mm{sup 3} for examination of scintillation properties. BaMgF{sub 4} demonstrated {approx}70% transmittance in wavelength range above 170 nm, and strong emission peaking around 205 nm was observed under X-ray excitation. The absolute light yield of BaMgF{sub 4} was 1300{+-}100 ph/MeV, and the decay time profile showed two components as 0.57{+-}0.01 (70%) and 2.2{+-}0.31 (30%) ns at room temperature.

  13. Effect of Ba ions on the growth and mitochondrial metabolism of Mung bean seedlings

    Energy Technology Data Exchange (ETDEWEB)

    Minton, G A; Wilson, R H

    1973-01-01

    The presence of high concentrations of BaCl/sub 2/ in vermiculite grown Mung bean (Phaseolus aureus) resulted in a reduction in shoot growth compared with plants grown in equivalent concentrations of CaCl/sub 2/. A high level of Ba ion was found in the mitochondria from plants grown at high Ba ion concentrations. Respiration rates of isolated mitochondria from plants grown at high levels of Ba were more rapid with all substrates tested, while the coupling parameters, including respiratory control with all substrates tested and ADP/O ratios with pyruvate-malate were partially reduced. These results are discussed as a possible mechanism of inhibition of plants grown in high-Ba soils. 12 references, 1 figure, 3 tables.

  14. Effect of BaSi2 template growth duration on the generation of defects and performance of p-BaSi2/n-Si heterojunction solar cells

    Science.gov (United States)

    Yachi, Suguru; Takabe, Ryota; Deng, Tianguo; Toko, Kaoru; Suemasu, Takashi

    2018-04-01

    We investigated the effect of BaSi2 template growth duration (t RDE = 0-20 min) on the defect generation and performance of p-BaSi2/n-Si heterojunction solar cells. The p-BaSi2 layer grown by molecular beam epitaxy (MBE) was 15 nm thick with a hole concentration of 2 × 1018 cm-3. The conversion efficiency η increased for films grown at long t RDE, owing to improvements of the open-circuit voltage (V OC) and fill factor (FF), reaching a maximum of η = 8.9% at t RDE = 7.5 min. However, η decreased at longer and shorter t RDE owing to lower V OC and FF. Using deep-level transient spectroscopy, we detected a hole trap level 190 meV above the valence band maximum for the sample grown without the template (t RDE = 0 min). An electron trap level 106 meV below the conduction band minimum was detected for a sample grown with t RDE = 20 min. The trap densities for both films were (1-2) × 1013 cm-3. The former originated from the diffusion of Ba into the n-Si region; the latter originated from defects in the template layer. The crystalline qualities of the template and MBE-grown layers were discussed. The root-mean-square surface roughness of the template reached a minimum of 0.51 nm at t RDE = 7.5 min. The a-axis orientation of p-BaSi2 thin films degraded as t RDE exceeded 10 min. In terms of p-BaSi2 crystalline quality and solar cell performance, the optimum t RDE was determined to be 7.5 min, corresponding to approximately 4 nm in thickness.

  15. The BaBar instrumented flux return performance: lessons learned

    CERN Document Server

    Anulli, F; Baldini, R; Band, H R; Bionta, R; Brau, J E; Brigljevic, V; Buzzo, A; Calcaterra, A; Carpinelli, M; Cartaro, C; Cavallo, N; Crosetti, G; De Nardo, Gallieno; De Sangro, R; Eichenbaum, A; Fabozzi, F; Falciai, D; Ferrarotto, F; Ferroni, F; Finocchiaro, G; Forti, F; Frey, R; Gatto, C; Graug; Iakovlev, N I; Iwasaki, M; Johnson, J R; Lange, D J; Lista, L; Lo Vetere, M; Lü, C; Macri, M; Messner, R; Moore, T B; Morganti, S; Neal, H; Neri, N; Palano, A; Paoloni, E; Paolucci, P; Passaggio, S; Pastore, F C; Patteri, P; Peruzzi, I; Piccolo, D; Piccolo, M; Piredda, G; Robutti, E; Roodman, A; Santroni, A; Sciacca, C; Sinev, N B; Soha, A; Strom, D; Tosi, S; Vavra, J; Wisniewski, W J; Wright, D M; Xie, Y; Zallo, A

    2002-01-01

    The BaBar Collaboration has operated an instrumented flux return (IFR) system covering over 2000 m sup 2 with resistive plate chambers (RPCs) for nearly 3 years. The chambers are constructed of bakelite sheets separated by 2 mm. The inner surfaces are coated with linseed oil. This system provides muon and neutral hadron detection for BaBar. Installation and commissioning were completed in 1998, and operation began mid-year 1999. While initial performance of the system reached design, over time, a significant fraction of the RPCs demonstrated significant degradation, marked by increased currents and reduced efficiency. A coordinated effort of investigations have identified many of the elements responsible for the degradation. This article presents our current understanding of the aging process of the BaBar RPCs along with the action plan to combat performance degradation of the IFR system.

  16. The new barium mercuride BaHg6 and ternary indium and gallium derivatives

    International Nuclear Information System (INIS)

    Wendorff, Marco; Röhr, Caroline

    2013-01-01

    Highlights: ► The new binary Hg-rich mercuride BaHg 6 crystallizes with a singular structure type. ► Ternary In substituted compounds are isotypic, whereas Ga substituted compounds are only structurally related. ► Structure relation to other Hg-rich alkali and alkaline earth mercurides. ► Discussion of covalent and metallic bonding aspects, as found by structure features and band structure calculations. - Abstract: The new binary barium mercuride BaHg 6 and the derived ternary indium and gallium containing compounds BaIn 1.2 Hg 4.8 and BaGa 0.8 Hg 5.2 were synthesized from melts of the elements, which were slowly cooled from 500 to 200 °C. Their crystal structures have been determined by means of single crystal X-ray diffraction. The binary mercuride BaHg 6 (Pnma, a = 1338.9(3), b = 519.39(13), c = 1042.6(4) pm, Z = 4, R1 = 0.0885) and the isotypic indium substituted compound BaIn 1.2 Hg 4.8 as well as the structurally related gallium mercuride BaGa 0.8 Hg 5.2 (Cmcm, a = 729.77(7), b = 1910.1(2), c = 507.48(5) pm, Z = 4, R1 = 0.0606) crystallize with new structure types. Common features of both structures are planar nets of five- and eight-membered Hg rings, stacked perpendicular to the shortest axes. According to their lengths, the Hg–Hg bonds can be classified into three groups: strong, short ones (I, 285–292 pm), which are only found inside the nets, and longer distances (II), still carrying bond critical points, around 300 pm. Further contacts (III) serve to complete the coordination spheres of Hg/M (320–358 pm). The overall coordination numbers of Hg/M range from 10 to 13. The Ba cations are positioned in the centers of the octagons of the Hg/M nets, thus exhibiting a 5:8:5, i.e. 18, coordination by Hg/M atoms. DFT calculations of the electronic band structure of pure BaHg 6 and ordered models of the indium ( ′ BaInHg 5 ′ ) and the gallium ( ′ BaGaHg 5 ′ ) mercurides were performed using the FP-LAPW method. The calculated Bader charges

  17. Thermodynamic model for the solubility of BaSeO4(cr) in the aqueous Ba2+-SeO42--Na+-H+-OH--H2O system. Extending to high selenate concentrations

    International Nuclear Information System (INIS)

    Rai, Dhanpat; Felmy, Andrew R.; Kitamura, Akira; Yoshikawa, Hideki; Doi, Reisuke; Yoshida, Yasushi; Moore, Dean A.

    2014-01-01

    The aqueous solubility of BaSeO 4 (cr) was studied at 23 ± 2 C as a function of Na 2 SeO 4 concentrations (0.0001 to 4.1 mol kg -1 ) and equilibration periods (3 to 596 d). The equilibrium, approached from both the under- and over-saturation directions, in this system was reached rather rapidly (≤ 3d). The SIT and Pitzer's ion-interaction models were used to interpret these data and the predictions based on both of these models agreed closely with the experimental data. Thermodynamic analyses of the data show that BaSeO 4 (cr) is the solubility-controlling phase for Na 2 SeO 4 concentrations -1 . The log 10 K 0 value for the BaSeO 4 (cr) solubility product (BaSeO 4 (cr) ↔ Ba 2+ + SeO 4 2- ) calculated by the SIT and Pitzer models were very similar (-7.32 ± 0.07 with Pitzer and -7.25 ± 0.11 with SIT). Although the BaSeO 4 (cr) solubility product and Ba concentrations as a function of Na 2 SeO 4 concentrations predicted by both the SIT and Pitzer models are similar, the models required different sets of fitting parameters. For examples, (1) interpretations using the SIT model required the inclusion of Ba(SeO 4 ) 2 2- species with log 10 K 0 = 3.44 ± 0.12 for the reaction (Ba 2+ + 2SeO 4 2- ↔ Ba(SeO 4 ) 2 2- ), whereas these species are not needed for Pitzer model, and (2) at Na 2 SeO 4 concentrations > 0.59 mol kg -1 it was also possible to calculate the value for log 10 K 0 for the solubility product of a proposed double salt (Na 2 Ba(SeO 4 ) 2 (s) ↔ 2Na + + Ba 2+ + 2SeO 4 2- ) which for the SIT model is -(8.70 ± 0.29) whereas for the Pitzer model it is -(9.19 ± 0.19). The ion-interaction/ion-association parameters hitherto unavailable for both the SIT and Pitzer models required to fit these extensive data extending to as high ionic strengths as 12.3 mol kg -1 were determined. The model developed in this study is consistent with all of the reliable literature data, which was also used to extend the model to barium concentrations as high as 0.22 mol kg

  18. Preparation and self-assembly of nanostructured BaCrO4 from CTAB reverse microemulsions

    International Nuclear Information System (INIS)

    Li Zhonghao; Zhang Jianling; Du Jimin; Han Buxing; Mu Tiancheng; Gao Yanan; Liu Zhimin

    2005-01-01

    Well-defined superstructures of rectangular-shaped BaCrO 4 and extensive network of BaCrO 4 nanoparticles constructed by self-assembly were prepared in cetyltrimethylammonium bromide (CTAB) reverse microemulsions. The effects of aging time and reactant concentrations on the morphology and the self-assemble pattern of the nanostructured BaCrO 4 were investigated. TEM combined with the electron diffraction was used to characterize the morphology and the crystal structure of the prepared nanostructured BaCrO 4 at different conditions

  19. Muon spin depolarization in Gd- and EuBa2Cu3Ox

    International Nuclear Information System (INIS)

    Cooke, D.W.; Hutson, R.L.; Kwok, R.S.; Maez, M.; Rempp, H.; Schillaci, M.E.; Smith, J.L.; Willis, J.O.; Lichti, R.L.; Chan, K.C.; Boekema, C.; Weathersby, S.; Oostens, J.

    1989-01-01

    Positive muon spin rotation (μSR) measurements on Gd- and EuBa 2 Cu 3 O x (x ∼ 7) have been conducted in the temperature interval 4 - 300 K. For each sample, muons stop both at grain boundaries and within the superconducting grains. Measured magnetic field penetration depths are 1550 and 1900 Angstrom for two specimens of GdBa 2 Cu 3 O x , and 1350 Angstrom for EuBa 2 Cu 3 O x

  20. The influence of overload on the orientation of hydraulic fractures in Fazenda Alvorada - state of Bahia - Brazil

    International Nuclear Information System (INIS)

    Araujo, Paulo Fernando de

    2000-01-01

    Based on density logs, the overload of Fazenda Alvorada field located in the state of Bahia (Brazil) presents an anomalous behavior in relation to the same sedimentary package of the Reconcavo Basin. This anomaly is in function of a relative uplift accompanied of a concomitant bearing or not, with the uplift doing with that the gradients of fracture propagation usually present high values. Comparisons among the gradients of fracture propagation, obtained step-rate-tests accomplished in reservoirs different from 7-FAV-83-BA well, and the overload of this field allowed to identify occurrences of vertical and horizontal fractures. The objective of this work is to present as these results were obtained, as well as its importance in the stimulation projects and of secondary recovery. (author)

  1. Dependence of transfer number of fluorine on cation type in glasses of Ba(PO3)2-MeF2 systems (Me=Ba,Sr,Ca,Mg)

    International Nuclear Information System (INIS)

    Pronkin, A.A.

    1978-01-01

    The influence of Ba, Sr, Ca, Mg cations on transfer numbers of fluorine in glasses of Ba(PO 3 ) 2 - MeF 2 pseudobinary systems is studied. Transfer numbers are essentially different in one and the same fluorine ion concentration in glasses, containing various alkali-earth cations: increase of the cation field force brings about decrease of the transfer numbers of fluorine, and the glass-formation region in the Ba-Sr-Ca-Mg series rises. The dependence of transfer numbers of fluorine on the fluorine concentration logarithm is presented. It is established, that alkali-earth metals influence the transfer numbers of fluorine on account of selective interaction with the phosphate constituent of glass structure

  2. Characterization of the insulator barrier and the superconducting transition temperature in GdBa{sub 2}Cu{sub 3}O{sub 7−δ}/BaTiO{sub 3} bilayers for application in tunnel junctions

    Energy Technology Data Exchange (ETDEWEB)

    Navarro, H., E-mail: henrynavarro@cab.cnea.gov.ar; Sirena, M.; Haberkorn, N. [Instituto Balseiro, Universidad Nacional de Cuyo and CNEA, 8400 Bariloche (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica. Av. Bustillo 9500, 8400 San Carlos de Bariloche (Argentina); Yang, Ilkyu [Department of Physics, Pohang University of Science and Technology, Pohang (Korea, Republic of); Kim, Jeehoon [Department of Physics, Pohang University of Science and Technology, Pohang (Korea, Republic of); CALDES, Institute for Basic Science, Pohang (Korea, Republic of)

    2015-07-28

    The optimization of the superconducting properties in a bottom electrode and the quality of an insulator barrier are the first steps in the development of superconductor/insulator/superconductor tunnel junctions. Here, we study the quality of a BaTiO{sub 3} tunnel barrier deposited on a 16 nm thick GdBa{sub 2}Cu{sub 3}O{sub 7−δ} thin film by using conductive atomic force microscopy. We find that the tunnel current is systematically reduced (for equal applied voltage) by increasing the BaTiO{sub 3} barrier thickness between 1.6 and 4 nm. The BaTiO{sub 3} layers present an energy barrier of ≈1.2 eV and an attenuation length of 0.35–0.5 nm (depending on the applied voltage). The GdBa{sub 2}Cu{sub 3}O{sub 7−δ} electrode is totally covered by a BaTiO{sub 3} thickness above 3 nm. The presence of ferroelectricity was verified by piezoresponse force microscopy for a 4 nm thick BaTiO{sub 3} top layer. The superconducting transition temperature of the bilayers is systematically suppressed by increasing the BaTiO{sub 3} thickness. This fact can be associated with stress at the interface and a reduction of the orthorhombicity of the GdBa{sub 2}Cu{sub 3}O{sub 7−δ}. The reduction in the orthorhombicity is expected by considering the interface mismatch and it can also be affected by reduced oxygen stoichiometry (poor oxygen diffusion across the BaTiO{sub 3} barrier)

  3. The Synthesis of BaAl2O4 Powder with High Surface Area%高比表面积BaAl2O4粉体合成研究

    Institute of Scientific and Technical Information of China (English)

    乔彦辉; 顾士甲; 王明辉; 田元; 李欢; 江莞

    2017-01-01

    BaAl2O4是优良的NOx存储催化剂材料,同时也是一种理想的荧光基体材料,受到了研究人员的广泛关注.但是一般的BaAl2O4粉体由于比表面积相对较小,使用受到了限制.虽然纳米颗粒有大的比表面积,但其团聚的缺陷严重限制了其应用.本文采用了一种简单的软模板法合成了BaAl2O4粉体.该粉体经过XRD表征表明为BaAl2O4,经BET表征具有较大比表面积.BaAl2O4粉体不仅化学稳定性好,而且具有相对较大的比表面积.其合成方法节省能源、生产效率高,在特定场合极有可能替代普通粉体做实际应用.%BaAl2O4 is an excellent NOx storage catalyst material. At the same time, it is also an ideal fluorescent matrix material and draws extensive attention. However, the general BaAl2O4 powder is limited by the relatively small surface area. Although the nanoparticles have larger surface area, the defect of their aggregation severely limits their applications. In this study, BaAl2O4 powder was synthesized by a simple soft template method, which not only had a good chemical stability, but also had a relatively large surface area. After characterizing by XRD, BET and TEM, the powder proved exactly the BaAl2O4 with a larger surface area. The synthesis method in this paper has high production efficiency and energy efficiency, and the powder is likely to replace the commonly-used powder on particular occasions.

  4. Electrical properties and structure of glasses in the Ba(PO3)2-MF2 systems, where M = Mg, Ca, Sr, Ba

    International Nuclear Information System (INIS)

    Sokolov, I.A.; Tarlakov, Yu.P.; Murin, I.V.; Pronkin, A.A.

    2000-01-01

    Using the methods of conductometry and IR spectroscopy the concentrational dependences of electric conductivity are studied, the nature of current carriers is determined, the concentrational dependence of transfer numbers is ascertained and structural changes in glasses of the system Ba(PO 3 ) 2 -MF 2 (M = Mg, Ca, Sr, Ba), depending on MF 2 content, are considered. It is shown that F - ions take part in electric current transfer. Influence of crystallochemical nature of alkaline-earth cations on physicochemical properties and structure of the glasses studied is analyzed [ru

  5. The Impact of Different Permissible Exposure Limits on Hearing Threshold Levels Beyond 25 dBA.

    Science.gov (United States)

    Sayapathi, Balachandar S; Su, Anselm Ting; Koh, David

    2014-10-01

    Development of noise-induced hearing loss is reliant on a few factors such as frequency, intensity, and duration of noise exposure. The occurrence of this occupational malady has doubled from 120 million to 250 million in a decade. Countries such as Malaysia, India, and the US have adopted 90 dBA as the permissible exposure limit. According to the US Occupational Safety and Health Administration (OSHA), the exposure limit for noise is 90 dBA, while that of the US National Institute of Occupational Safety and Health (NIOSH) is 85 dBA for 8 hours of noise exposure. This study aimed to assess the development of hearing threshold levels beyond 25 dBA on adoption of 85 dBA as the permissible exposure limit compared to 90 dBA. This is an intervention study done on two automobile factories. There were 203 employees exposed to noise levels beyond the action level. Hearing protection devices were distributed to reduce noise levels to a level between the permissible exposure limit and action level. The permissible exposure limits were 90 and 85 dBA in factories 1 and 2, respectively, while the action levels were 85 and 80 dBA, respectively. The hearing threshold levels of participants were measured at baseline and at first month of postshift exposure of noise. The outcome was measured by a manual audiometer. McNemar and chi-square tests were used in the statistical analysis. We found that hearing threshold levels of more than 25 dBA has changed significantly from pre-intervention to post-intervention among participants from both factories (3000 Hz for the right ear and 2000 Hz for the left ear). There was a statistically significant association between participants at 3000 Hz on the right ear at 'deteriorated' level ( χ² (1) = 4.08, φ = - 0.142, P = 0.043), whereas there was worsening of hearing threshold beyond 25 dBA among those embraced 90 dBA. The adoption of 85 dBA as the permissible exposure limit has preserved hearing threshold level among participants at 3000 Hz

  6. Nuclear charge radii and nuclear moments of neutron deficient Ba isotopes from high resolution laser spectroscopy

    International Nuclear Information System (INIS)

    Nowicki, G.; Bekk, K.; Goering, S.; Hanser, A.; Rebel, H.; Schatz, G.

    1978-07-01

    Isotope shifts and hyperfine structure of the BaI 6s 2 1 S 0 -6s6p 1 P 1 transitions (lambda = 553.6 nm) in neutron deficient Ba nuclides (N 131 Ba, 128 Ba, in addition to remeasurements of all stable Ba nuclides. The extracted values of delta 2 >, the observed odd-even staggering and the nuclear moments are discussed in the light of other theoretical and experimental nuclear structure studies of the region 50 [de

  7. Variations of force constants, M-O distances and bond order in solid solutions between Ba/sub 2/MgUO/sub 6/ and Ba/sub 2/MgWO/sub 6/

    Energy Technology Data Exchange (ETDEWEB)

    Kemmler-Sack, S; Fadini, A [Tuebingen Univ. (Germany, F.R.). Inst. fuer Chemie

    1977-12-01

    In solid solutions between the 1:1 ordered perovskites Ba/sub 2/MgUO/sub 6/ and Ba/sub 2/MgWO/sub 6/ (system Ba/sub 2/MgUsub(1-x)Wsub(x)O/sub 6/) the force constants of the UO/sub 6/ and WO/sub 6/ octahedras are variied. The valence force constants fsub(MO) tend to adjust for each x. The bond order and the M-O distances are reported as well.

  8. Photoluminescent BaMoO4 nanopowders prepared by complex polymerization method (CPM)

    International Nuclear Information System (INIS)

    Azevedo Marques, Ana Paula de; Melo, Dulce M.A. de; Paskocimas, Carlos A.; Pizani, Paulo S.; Joya, Miryam R.; Leite, Edson R.; Longo, Elson

    2006-01-01

    The BaMoO 4 nanopowders were prepared by the Complex Polymerization Method (CPM). The structure properties of the BaMoO 4 powders were characterized by FTIR transmittance spectra, X-ray diffraction (XRD), Raman spectra, photoluminescence spectra (PL) and high-resolution scanning electron microscopy (HR-SEM). The XRD, FTIR and Raman data showed that BaMoO 4 at 300 deg. C was disordered. At 400 deg. C and higher temperature, BaMoO 4 crystalline scheelite-type phases could be identified, without the presence of additional phases, according to the XRD, FTIR and Raman data. The calculated average crystallite sizes, calculated by XRD, around 40 nm, showed the tendency to increase with the temperature. The crystallite sizes, obtained by HR-SEM, were around of 40-50 nm. The sample that presented the highest intensity of the red emission band was the one heat treated at 400 deg. C for 2 h, and the sample that displayed the highest intensity of the green emission band was the one heat treated at 700 deg. C for 2 h. The CPM was shown to be a low cost route for the production of BaMoO 4 nanopowders, with the advantages of lower temperature, smaller time and reduced cost. The optical properties observed for BaMoO 4 nanopowders suggested that this material is a highly promising candidate for photoluminescent applications

  9. Positron annihilation lifetime study of positive temperature coefficient BaTiO3 samples

    International Nuclear Information System (INIS)

    Ling Chen; Mingkang Teng; Guanghou Wang; Xiaoyun Li; Tianchang Lu

    1989-01-01

    In order to investigate the doped vacancies in BaTiO 3 samples as well as their influence on the positive temperature coefficient (PTC) the positron annihilation lifetime spectroscopy was applied. Two groups of BaTiO 3 samples with BaO excess were prepared by doping different concentrations of La 2 O 3 and Nb 2 O 5 , respectively in the range from 0.1 to 3 at%. A third group of samples of two Sb-doped PTC BaTiO 3 semiconductors with excess BaO or TiO 2 were studied by the aid of positron technique before and after being reduced. It is shown that the positron lifetime parameters are sensitive to changes in the vacancy concentration in BaTiO 3 ceramics near the 0.1 mol% region. But they are almost unchanged during reduction processing; the resistivity of samples changed by one to two orders of magnitude through the reduction. It can be concluded that the PTC effect is due to oxygen on the grain boundary rather than vacancies, and that the Heywang-Jonker model is more reasonable

  10. Thermoelectric properties of Cu/Ag doped type-III Ba24Ge100 clathrates

    Science.gov (United States)

    Fu, Jiefei; Su, Xianli; Yan, Yonggao; Liu, Wei; Zhang, Zhengkai; She, Xiaoyu; Uher, Ctirad; Tang, Xinfeng

    2017-09-01

    Type-III Ba24Ge100 clathrates possess low thermal conductivity and high electrical conductivity at room temperature and, as such, have a great potential as thermoelectric materials for power generation. However, the Seebeck coefficient is very low due to the intrinsically high carrier concentration. In this paper, a series of Ba24CuxGe100-x and Ba24AgyGe100-y specimens were prepared by vacuum melting combined with the subsequent spark plasma sintering (SPS) process. Doping Cu or Ag on the Ge site not only suppresses the concentration of electrons but it also decreases the thermal conductivity. In addition, the carrier mobility and the Seebeck coefficient increase due to the decrease in the carrier concentration. Thus, the power factor is greatly improved, leading to an improvement in the dimensionless figure of merit ZT. Cu-doped Ba24Cu6Ge94 reaches the maximum ZT value of about 0.17 at 873 K, while Ag-doped Ba24Ag6Ge94 attains the dimensionless figure of merit ZT of 0.31 at 873 K, more than 2 times higher value compared to un-doped Ba24Ge100.

  11. Compounds of type Ba/sub 2/Bsup(III)Ossup(V)O/sub 6/

    Energy Technology Data Exchange (ETDEWEB)

    Treiber, U; Kemmler-Sack, S [Tuebingen Univ. (Germany, F.R.). Lehrstuhl fuer Anorganische Chemie 2

    1981-07-01

    The black perovskites of type Ba/sub 2/Bsup(III)Ossup(V)O/sub 6/ crystallize cubic (Bsup(III) = Pr, Nd, Sm-Lu, Y) and rhombohedral (Bsup(III) = La) respectively; the cell volumina decrease linearily with (rsub(B)sup(III))/sup 3/. Intensity calculations on powder data for Ba/sub 2/YOsO/sub 6/ (space group Fm3m-Osub(h)/sup 5/) and Ba/sub 2/LaOsO/sub 6/ (space group R-3m-Dsub(3d)/sup 5/) gave the intensity related R'values of 4.6% and 5.0% respectively. The results of the vibrational spectroscopic investigations are reported in common with the bond orders, M-O distances and mean amplitudes and compared with the corresponding values of the series Ba/sub 2/Bsup(III)Irsup(V)O/sub 6/ and Ba/sub 2/Bsup(III)Rusup(V)O/sub 6/.

  12. Influence of Ba/Fe mole ratios on magnetic properties, crystallite size and shifting of X-ray diffraction peaks of nanocrystalline BaFe12O19 powder, prepared by sol gel auto combu

    Science.gov (United States)

    Suastiyanti, Dwita; Sudarmaji, Arif; Soegijono, Bambang

    2012-06-01

    Barium hexaferrite BaFe12O19 (BFO) is of great importance as permanent magnets, particularly for magnetic recording as well as in microwave devices. Nano-crystalline BFO powders were prepared by sol gel auto combustion method in citric acid - metal nitrates system. Hence the mole ratios of Ba/Fe were variated at 1:12; 1:11.5 and 1:11. Ratio of cation to fuel was fixed at 1:1. An appropriate amount of amonia solution was added dropwise to this solution with constant stirring until the PH reached 7 in all cases. Heating at 850oC for 10 hours for each sample to get final formation of BFO nanocrystalline. The data from XRD showing the lattice parameters a,c and the unit-cell volume V, confirm that BFO with ratio 1:12 has same crystall parameters with ratio 1:11. Ratio of Ba/Fe 1:12 and 1:11 have diffraction pattern similarly at almost each 2 θ for each samples. Ratio of Ba/Fe 1: 11.5 has the finest crystallite size 22 nm. Almost diffraction pattern peaks of Ba/Fe 1:11.5 move to the left from of Ba/Fe 1:12 then return to diffraction pattern of Ba/Fe 1:12 for Ba/Fe 1:11. SEM observations show the particle size less than 100 nm and the same shape for each sample. Ratio of Ba/Fe 1: 12 gives the highest intrinsic coercive Hc = 427.3 kA/m. The highest remanent magnetization is at ratio 1:11 with Mr = 0.170 T. BFO with mole ratio 1:11.5 has the finest grain 22 nm, good magnetic properties and the highest value of best FoM 89%.

  13. Configuration Database for BaBar On-line

    International Nuclear Information System (INIS)

    Salnikov, Andrei

    2003-01-01

    The configuration database is one of the vital systems in the BaBar on-line system. It provides services for the different parts of the data acquisition system and control system, which require run-time parameters. The original design and implementation of the configuration database played a significant role in the successful BaBar operations since the beginning of experiment. Recent additions to the design of the configuration database provide better means for the management of data and add new tools to simplify main configuration tasks. We describe the design of the configuration database, its implementation with the Objectivity/DB object-oriented database, and our experience collected during the years of operation

  14. Occurrence of new species of mealybug on cotton fields in the states of Bahia and Paraíba, Brazil

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Domingues da Silva

    2012-01-01

    Full Text Available The cotton mealybug, Phenacoccus solenopsis Tinsley (Hemiptera: Pseudococcidae has been reported occurring in several countries causing severe losses in economically important crops, including cotton. Based on information reported by farmers in the regions of the Southwest and Middle São Francisco, Bahia and also in the regions of the Agreste and Semi-arid of the Paraiba State, high infestations of cotton mealybugs have occurred in these regions during the cotton season of 2007 and 2008. The cotton mealybug was identified as P. solenopsis and this represents the first record of this insect attacking cotton in Brazil.

  15. Microstructural properties of BaTiO{sub 3} ceramics and thin films

    Energy Technology Data Exchange (ETDEWEB)

    Fundora C, A.; Portelles, J.J.; Siqueiros, J.M. [Posgrado en Fisica de Materiales, Centro de Investigacion Cientifica y de Educacion Superior de Ensenada. Apartado Postal 2861, 22800 Ensenada, Baja California (Mexico)

    2000-07-01

    A microstructural study of BaTiO{sub 3} ceramics obtained by the conventional ceramic method is presented. Targets were produced to grow BaTiO{sub 3} thin films by pulsed laser deposition on Pt/Ti/Si (100) substrates. X-ray diffraction, Auger Electron Spectroscopy, X-ray Photon Spectroscopy and Scanning Electron Microscopy were used to study the properties of the BaTiO{sub 3} ceramic samples and thin films, as deposited and after an annealing process. (Author)

  16. Structural, optical and electronic properties of K2Ba(NO3)4 crystal

    Science.gov (United States)

    Isaenko, L. I.; Korzhneva, K. E.; Goryainov, S. V.; Goloshumova, A. A.; Sheludyakova, L. A.; Bekenev, V. L.; Khyzhun, O. Y.

    2018-02-01

    Nitrate crystals reveal nonlinear optical properties and could be considered as converters of laser radiation in the short-wave region. The conditions for obtaining and basic properties of K2Ba(NO3)4 double nitrate crystals were investigated. Crystal growth was implemented by slow cooling in the temperature range of 72-49 °C and low rate evaporation. The structural analysis of K2Ba(NO3)4 formation on the basis of two mixed simple nitrate structures is discussed. The main groups of oscillations in K2Ba(NO3)4 crystal were revealed using Raman and IR spectroscopy, and the table of vibrations for this compound was compiled. The electronic structure of K2Ba(NO3)4 was elucidated in the present work from both experimental and theoretical viewpoints. In particular, X-ray photoelectron spectroscopy (XPS) was employed in the present work to measure binding energies of the atoms constituting the titled compound and its XPS valence-band spectrum for both pristine and Ar+ ion-bombarded surfaces. Further, total and partial densities of states of constituent atoms of K2Ba(NO3)4 have been calculated. The calculations reveal that the O 2p states dominate in the total valence-band region of K2Ba(NO3)4 except of its bottom, where K 3p and Ba 5p states are the principal contributors, while the bottom of the conduction band is composed mainly of the unoccupied O 2p states, with somewhat smaller contributions of the N 2p∗ states as well. With respect to the occupation of the valence band by the O 2p states, the present band-structure calculations are confirmed by comparison on a common energy scale of the XPS valence-band spectrum and the X-ray emission O Kα band for the K2Ba(NO3)4 crystal under study. Furthermore, the present calculations indicate that the K2Ba(NO3)4 compound is a direct-gap material.

  17. High Pressure Properties of a Ba-Cu-Zn-P Clathrate-I

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    Juli-Anna Dolyniuk

    2016-08-01

    Full Text Available The high pressure properties of the novel tetrel-free clathrate, Ba8Cu13.1Zn3.3P29.6, were investigated using synchrotron powder X-ray diffraction. The pressure was applied using a diamond anvil cell. No structural transitions or decomposition were detected in the studied pressure range of 0.1–7 GPa. The calculated bulk modulus for Ba8Cu13.1Zn3.3P29.6 using a third-order Birch-Murnaghan equation of state is 65(6 GPa at 300 K. This bulk modulus is comparable to the bulk moduli of Ge- and Sn-based clathrates, like A8Ga16Ge30 (A = Sr, Ba and Sn19.3Cu4.7P22I8, but lower than those for the transition metal-containing silicon-based clathrates, Ba8TxSi46−x, T = Ni, Cu; 3 ≤ x ≤ 5.

  18. Molecular glues for manipulating enzymes: trypsin inhibition by benzamidine-conjugated molecular glues† †Electronic supplementary information (ESI) available: Synthesis of TEG–BA, Gluen–BA, mGluen–BA and Gluen–Ph; 1H NMR, 13C NMR, MALDI-TOF MS, electronic absorption, and CD spectra; zeta potential distributions; SLS plots; DLS histograms; and related experimental procedures. See DOI: 10.1039/c5sc00524h Click here for additional data file.

    Science.gov (United States)

    Mogaki, Rina

    2015-01-01

    Water-soluble bioadhesive polymers bearing multiple guanidinium ion (Gu+) pendants at their side-chain termini (Gluen–BA, n = 10 and 29) that were conjugated with benzamidine (BA) as a trypsin inhibitor were developed. The Gluen–BA molecules are supposed to adhere to oxyanionic regions of the trypsin surface, even in buffer, via a multivalent Gu+/oxyanion salt-bridge interaction, such that their BA group properly blocks the substrate-binding site. In fact, Glue10–BA and Glue29–BA exhibited 35- and 200-fold higher affinities for trypsin, respectively, than a BA derivative without the glue moiety (TEG–BA). Most importantly, Glue10–BA inhibited the protease activity of trypsin 13-fold more than TEG–BA. In sharp contrast, mGlue27–BA, which bears 27 Gu+ units along the main chain and has a 5-fold higher affinity than TEG–BA for trypsin, was inferior even to TEG–BA for trypsin inhibition. PMID:28706668

  19. Kinematics and geometry of structures in the southern limb of the Paraíba do Sul divergent structural fan, SE Brazil: a true transtensional shear

    Directory of Open Access Journals (Sweden)

    Nolan M. Dehler

    2006-06-01

    Full Text Available Shear zones geometry in the Paraíba do Sul belt, southeastern Brazil, delineates a NE-trending fan-like structure. Shear zones dip towards SE in the northern limb, and towards NW in the southern one. This geometry has been interpreted either due to transpression or to late folding of flat-lying thrust surfaces. Stretching lineation plunges to ENE-ESE in the northern limb and towards NNE-NE in the southern one. Structural data in the southern limb of the divergent fan suggest a two stage kinematic evolution in high-temperature conditions: an earlier stage with top-to-SSW/SW sinistral thrusting and orogenic-parallel tangential motion, and a later stage with top-down to NNE/NE transtensional deformation. We propose a heterogeneous deformation model to explain the observed shear reversal, and suggest that the imposed transpressional displacement gradient may change during progressive deformation due to transient rheological inhomogeneities in bulk pure shear strain. In the earlier stage, the partially molten material could easily accommodate the imposed strain rates, giving rise firstly to the SW-directed shearing. As the thermal disturbance tended to vanish and the convergence increased, the NNE-directed transtensional shearing developed. We propose that the transtensional deformation characterized in this paper could be related to extrusion processes during regional transpressional strain.A geometria das zonas de cisalhamento no CinturãoParaíba do Sul no Rio de Janeiro, sudeste do Brasil, delineia uma estrutura-em-leque com direção NE. Estaszonas de cisalhamento mergulham para SE no flanco norte, e para NW no flanco sul da estrutura. Esta geometria tem sido interpretada de duas formas: (a implantação de um regime transpressivo ou (b dobramento tardio de superfícies de empurrão originalmente sub-horizontais. A lineação de estiramento mineral mostra caimento para ENE-ESE, no flanco norte, e para NNE-NE, no flanco sul, onde ocorre a Zona

  20. In vitro anticancer potential of BaCO3 nanoparticles synthesized via green route.

    Science.gov (United States)

    Nagajyothi, P C; Pandurangan, Muthuraman; Sreekanth, T V M; Shim, Jaesool

    2016-03-01

    Green synthesis of nanoparticles is a growing research area because of their potential applications in nanomedicine. Barium carbonate nanoparticles (BaCO3 NPs) were synthesized using an aqueous extract of Mangifera indica seed as a reducing agent. These particles were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Transmission electron microscopy (TEM), selected area electron diffraction (SAED), Energy-dispersive-X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) analysis. HR-TEM images are confirmed that green synthesized BaCO3 NPs have spherical, triangular and uneven shapes. EDX analysis confirmed the presence of Ba, C and O. The peaks at 2θ of 19.45, 23.90, 24.29, 27.72, 33.71, 34.08, 34.60, 41.98, 42.95, 44.18, 44.85, and 46.78 corresponding to (110), (111), (021), (002), (200), (112), (130), (221), (041), (202), (132) and (113) showed that BaCO3 NPs average size was ~18.3 nm. SAED pattern confirmed that BaCO3 NPs are crystalline nature. BaCO3 NPs significantly inhibited cervical carcinoma cells, as evidenced by cytotoxicity assay. Immunofluorescence and fluorescence assays showed that BaCO3 NPs increased the expression and activity of caspase-3, an autocatalytic enzyme that promotes apoptosis. According to the results, green synthesis route has great potential for easy, rapid, inexpensive, eco-friendly and efficient development of novel multifunctional nanoparticles for the treatment of cancer. Copyright © 2016 Elsevier B.V. All rights reserved.

  1. Growth of single crystals of BaFe12O19 by solid state crystal growth

    International Nuclear Information System (INIS)

    Fisher, John G.; Sun, Hengyang; Kook, Young-Geun; Kim, Joon-Seong; Le, Phan Gia

    2016-01-01

    Single crystals of BaFe 12 O 19 are grown for the first time by solid state crystal growth. Seed crystals of BaFe 12 O 19 are buried in BaFe 12 O 19 +1 wt% BaCO 3 powder, which are then pressed into pellets containing the seed crystals. During sintering, single crystals of BaFe 12 O 19 up to ∼130 μm thick in the c-axis direction grow on the seed crystals by consuming grains from the surrounding polycrystalline matrix. Scanning electron microscopy-energy dispersive spectroscopy analysis shows that the single crystal and the surrounding polycrystalline matrix have the same chemical composition. Micro-Raman scattering shows the single crystal to have the BaFe 12 O 19 structure. The optimum growth temperature is found to be 1200 °C. The single crystal growth behavior is explained using the mixed control theory of grain growth. - Highlights: • Single crystals of BaFe 12 O 19 are grown by solid state crystal growth. • A single crystal up to ∼130 μm thick (c-axis direction) grows on the seed crystal. • The single crystal and surrounding ceramic matrix have similar composition. • Micro-Raman scattering shows the single crystal has the BaFe 12 O 19 structure.

  2. High-pressure densified solid solutions of alkaline earth hexaborides (Ca/Sr, Ca/Ba, Sr/Ba) and their high-temperature thermoelectric properties

    International Nuclear Information System (INIS)

    Gürsoy, M.; Takeda, M.; Albert, B.

    2015-01-01

    Solid solutions of alkaline earth hexaborides were synthesized and densified by spark plasma sintering at 100 MPa. The high-temperature thermoelectric properties (Seebeck coefficients, electrical and thermal diffusivities, heat capacities) were measured between room temperature and 1073 K. CaB 6 , SrB 6 , BaB 6 and the ternary hexaborides Ca x Sr 1−x B 6 , Ca x Ba 1−x B 6 , Sr x Ba 1−x B 6 (x = 0.25, 0.5, 0.75) are n-type conducting compounds over the whole compositional and thermal ranges. The values of the figure of merit ZT for CaB 6 (ca. 0.3 at 1073 K) were found to be significantly increased compared to earlier investigations which is attributed to the densification process. - Highlights: • Solid solutions of alkaline earth hexaborides were synthesized. • High-temperature thermoelectric properties of mixed calcium borides are excellent. • Spark plasma source densification results in high ZT values. • Borides are rare-earth free and refractory materials

  3. Influence of Impurities on the Luminescence of Er3+ Doped BaTiO3 Nanophosphors

    Directory of Open Access Journals (Sweden)

    G. D. Webler

    2014-01-01

    Full Text Available The influence of the presence of barium carbonate (BaCO3 phase on the luminescence properties of barium titanate nanocrystals (BaTiO3 powders was investigated. Structural and optical characterizations of erbium (Er3+ doped BaTiO3 synthesized by the sol-emulsion-gel were performed. Using Fourier transform infrared spectroscopy and X-ray powder diffraction, we identified the presence of impurities related to BaCO3 and quantified its fraction. It was observed that the presence of BaCO3 phase, even at low levels, depletes significantly the infrared-to-visible upconverted luminescence efficiency of the produced nanopowders.

  4. Análise espacial da violência doméstica contra a mulher entre os anos de 2002 e 2005 em João Pessoa, Paraíba, Brasil Spatial analysis of domestic violence against women from 2002 to 2005 in João Pessoa, Paraíba State, Brazil

    Directory of Open Access Journals (Sweden)

    Kerle Dayana Tavares de Lucena

    2012-06-01

    Full Text Available Trata-se de um estudo quantitativo, ecológico, exploratório com utilização de técnicas de análise espacial e do Sistema de Informações Geográficas. A população foi composta por todas as denúncias de mulheres vítimas de violência doméstica, residentes no Município de João Pessoa, Paraíba, Brasil, no período de 2002 a 2005, na Delegacia Especializada de Atendimento da Mulher. Objetivou-se investigar a distribuição espacial da violência doméstica para subsidiar os gestores no processo de tomada de decisão. A análise dos resultados permitiu identificar as áreas de alta e baixa incidências de violência, como também o risco de cada bairro comparado à cidade de João Pessoa. A partir do índice de Getis e Ord produziu-se a decisão das áreas prioritárias para intervenção sobre a violência doméstica. Ressaltamos a necessidade de mudanças no que se refere à atenção às mulheres vítimas de violência e a articulação entre as instituições com promoção da educação permanente nos serviços, contemplando discussões sobre gênero e violência contra a mulher.This was a quantitative, ecological, exploratory study using spatial analysis and a geographic information system. The population consisted of all the women that had filed complaints against domestic violence in the city of João Pessoa, Paraíba State, Brazil, from 2002 to 2005, at the Specialized Police Precinct for Women. The aim was to investigate the spatial distribution of domestic violence in order to assist policymakers in the decision-making process. Analysis of the results allowed identifying areas of low and high incidence of domestic violence, besides comparing the risk in each neighborhood to the overall rate for the city of João Pessoa. Based on the Getis and Ord index, the study produced a decision on priority areas for intervening in domestic violence. The authors highlight the need for changes in care for female victims of violence and the

  5. From Ba{sub 3}Ta{sub 5}O{sub 14}N to LaBa{sub 2}Ta{sub 5}O{sub 13}N{sub 2}: Decreasing the optical band gap of a photocatalyst

    Energy Technology Data Exchange (ETDEWEB)

    Anke, B. [Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin (Germany); Bredow, T. [Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Beringstr. 4, 53115 Bonn (Germany); Pilarski, M.; Wark, M. [Institut für Chemie, Carl von Ossietzky Universität Oldenburg, Carl-von-Ossietzky-Str. 9-11, 26129 Oldenburg (Germany); Lerch, M., E-mail: martin.lerch@tu-berlin.de [Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin (Germany)

    2017-02-15

    Yellow LaBa{sub 2}Ta{sub 5}O{sub 13}N{sub 2} was successfully synthesized as phase-pure material crystallizing isostructurally to previously reported Ba{sub 3}Ta{sub 5}O{sub 14}N and mixed-valence Ba{sub 3}Ta{sup V}{sub 4}Ta{sup IV}O{sub 15}. The electronic structure of LaBa{sub 2}Ta{sub 5}O{sub 13}N{sub 2} was studied theoretically with the range-separated hybrid method HSE06. The most stable structure was obtained when lanthanum was placed on 2a and nitrogen on 4h sites confirming Pauling's second rule. By incorporating nitrogen, the measured band gap decreases from ∼3.8 eV for the oxide via 2.74 eV for Ba{sub 3}Ta{sub 5}O{sub 14}N to 2.63 eV for the new oxide nitride, giving rise to an absorption band well in the visible-light region. Calculated fundamental band gaps confirm the experimental trend. The atom-projected density of states has large contributions from N2p orbitals close to the valence band edge. These are responsible for the observed band gap reduction. Photocatalytic hydrogen formation was investigated and compared with that of Ba{sub 3}Ta{sub 5}O{sub 14}N revealing significantly higher activity for LaBa{sub 2}Ta{sub 5}O{sub 13}N{sub 2} under UV-light. - Graphical abstract: X-ray powder diffraction pattern of LaBa{sub 2}Ta{sub 5}O{sub 13}N{sub 2} with the results of the Rietveld refinements. Inset: Unit cell of LaBa{sub 2}Ta{sub 5}O{sub 13}N{sub 2} and polyhedral representation of the crystal structure. - Highlights: • Synthesis of a new oxide nitride LaBa{sub 2}Ta{sub 5}O{sub 13}N{sub 2}. • Refinement of the crystal structure. • Quantum chemical calculations provided band gap close to the measured value. • New phase shows a higher photocatalytic H{sub 2} evolution rate compared to prior tested Ba{sub 3}Ta{sub 5}O{sub 14}N.

  6. Wet chemical synthesis of LiBaF{sub 3} phosphor

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Vartika S., E-mail: svmoharil@yahoo.com [Physics Department, Shri Ramdeobaba K.N. Engineering College, Katol Road, Nagpur 440 013 (India); Joshi, C.P. [Physics Department, Shri Ramdeobaba K.N. Engineering College, Katol Road, Nagpur 440 013 (India); Moharil, S.V. [Department of Physics, R.T.M. Nagpur University, Nagpur 440 010 (India)

    2013-12-05

    Highlights: •LiBaF{sub 3}:RE{sup 3+} phosphors synthesized by a simple wet chemical method. •Ce{sup 3+} and Tb{sup 3+} emissions observed in as-prepared powders without any thermal treatment. •Intense Eu{sup 2+} emission observed after annealing in reductive atmosphere. -- Abstract: LiBaF{sub 3} has great potential applications as X-ray storage phosphor, slow neutron imaging, scintillator, vacuum ultraviolet (VUV) optical lithography, etc. Conventionally, LiBaF{sub 3} is prepared by solid state reaction between the constituent fluorides. However, the preparation of phase pure material and especially single crystals is rather tricky due to incongruent melting. For the first time, a wet chemical preparation of rare earth activated LiBaF{sub 3} is described here. As precipitated powders containing Ce{sup 3+} or Tb{sup 3+} exhibited characteristic luminescence. For observing Eu{sup 2+} emission, it was necessary to heat the powders in a reductive atmosphere. It is suggested that phosphors prepared by this method may prove useful in applications like OSL, X-ray imaging, etc. which do not require large single crystals.

  7. Development of BaSO4:Eu thermoluminescence phosphor

    International Nuclear Information System (INIS)

    Madhusoodanan, U.; Jose, M.T.; Lakshmanan, A.R.

    1999-01-01

    A highly sensitive thermoluminescence (TL) phosphor based on BaSO 4 :Eu was developed following the coprecipitation technique and firing in argon atmosphere at 1123 K. Photoluminescence studies confirm that firing in argon atmosphere instead of air increased the incorporation of Eu ions in 2+ valence state. At low γ-ray doses, its TL sensitivity is nearly 2 to 3 times higher than that of CaSO 4 :Dy phosphor. The other salient features of this BaSO 4 :Eu TL phosphor are a constant glow curve shape and a nearly linear γ-ray dose response

  8. History of the Balkan Stomatological Society (BaSS

    Directory of Open Access Journals (Sweden)

    Todorović Ljubomir

    2014-11-01

    Full Text Available Some of the main activities of the Balkan Stomatological Society (BaSS over a rich 19-year history are presented. These activities have been aimed at improving oral health care provided by the dentists throughout the Balkans, and to establish ties of friendship and collaboration between researchers and clinicians in this region, creating a foundation for mutual understanding and peace. To accomplish these goals, the BaSS annually organizes congresses and publishes a scientific journal, beside many other activities, such as public oral health promotion, bringing into accordance study programmes and curricula, supporting student exchange programmes, etc.

  9. The study of the effect of Ba coverage through the accelerations lifetime of activated BaO/SrO cathodes

    International Nuclear Information System (INIS)

    Hashim, A.A.; Ray, A.K.; Hassan, A.K.; Barratt, D.S.

    2005-01-01

    A novel type of BaO/SrO oxide cathode with 5% addition of Ni powder by weight on a Ni cap containing an activating impurity was studied. The conductivity and the electron activation energy were studied as a function of temperature in the range of 300-1200 K after conversion and activation of the cathode at 1200 K for 1 h. The experimental results yield three values for the activation energy of 1.49, 2.23 and 3.3 eV, which are close to BaO band structure parameters with a small shift due to the effect of other oxide components and metallic fraction additions. The experiments furthermore confirm that the current density of the cathode was enhanced at high temperature range with the long operation. The conduction mechanisms observed a metallic conduction at low temperature after operation for several 100 h due to improvements in the Ba coverage layer on the grains of oxide layer. Additionally, there appears a qualified conduction stability of the current density J = 10-45 mA cm -2 at the acceleration temperature range of 1100-1150 K under the duty of low voltage. The low voltage duty V = 30 mV is focused on the conduction electrons faraway from the emission electrons

  10. Oxygen excess in the '114' cobaltite hexagonal structure: The ferrimagnet CaBaCo4O7.50

    International Nuclear Information System (INIS)

    Pralong, V.; Caignaert, V.; Sarkar, T.; Lebedev, O.I.; Duffort, V.; Raveau, B.

    2011-01-01

    The study of the oxidation of the '114' orthorhombic cobaltite CaBaCo 4 O 7 , using first electrochemistry and then soft chemistry based on oxidation by NaClO, has allowed a new phase, CaBaCo 4 O 7.50 , to be prepared topotactically. The structural study of this phase shows that its hexagonal structure, closely related to that of orthorhombic CaBaCo 4 O 7 , is curiously similar to that of the members of the LnBaCo 4 O 7 series, in spite of its excess oxygen. Its magnetic study shows that this phase, like CaBaCo 4 O 7 , is ferrimagnetic with the same T C (60 K), but differently exhibits an unusual magnetic hysteresis. This exceptional behavior of CaBaCo 4 O 7 with respect to oxidation as well as the magnetic properties of CaBaCo 4 O 7.50 is interpreted in terms of the presence of defects due to oxidation. - Graphical Abstract: The study of the oxidation of the '114' orthorhombic cobaltite CaBaCo 4 O 7 , using first electrochemistry and then soft chemistry based on oxidation by NaClO, has allowed a new phase, CaBaCo 4 O 7.50 , to be prepared topotactically. The structural study of this phase shows that its hexagonal structure, closely related to that of orthorhombic CaBaCo 4 O 7 , is curiously similar to that of the members of the LnBaCo 4 O 7 series, in spite of its oxygen excess. Its magnetic study shows that this phase, like CaBaCo 4 O 7 , is ferrimagnetic. Highlights: → Topotactic oxidation by means of electrochemistry and soft chemistry of the '114' orthorhombic cobaltite CaBaCo 4 O 7 . → This new phase, CaBaCo 4 O 7.5 shows an hexagonal structure, is closely related to that of orthorhombic mother phase CaBaCo 4 O 7 . → CaBaCo 4 O 7.5 is ferrimagnetic and exhibits an unusual magnetic hysteresis, due to defect pinning centers.

  11. Carbon-14 immobilization via the CO2-Ba(OH)2 hydrate gas-solid reaction

    International Nuclear Information System (INIS)

    Haag, G.L.

    1980-01-01

    Although no restrictions have been placed on the release of carbon-14, it has been identified as a potential health hazard due to the ease in which it may be assimilated into the biosphere. The intent of the Carbon-14 Immobilization Program, funded through the Airborne Waste Program Management Office, is to develop and demonstrate a novel process for restricting off-gas releases of carbon-14 from various nuclear facilities. The process utilizes the CO 2 -Ba(OH) 2 hydrate gas-solid reaction to directly remove and immobilize carbon-14. The reaction product, BaCO 3 , possesses both the thermal and chemical stability desired for long-term waste disposal. The process is capable of providing decontamination factors in excess of 1000 and reactant utilization of greater than 99% in the treatment of high volumetric, airlike (330 ppM CO 2 ) gas streams. For the treatment of an air-based off-gas stream, the use of packed beds of Ba(OH) 2 .8H 2 O flakes to remove CO 2 has been demonstrated. However, the operating conditions must be maintained between certain upper and lower limits with respect to the partial pressure of water. If the water vapor pressure in the gas is less than the dissociation vapor pressure of Ba(OH) 2 .8H 2 O, the bed will deactivate. If the vapor pressure is considerably greater, pressure drop problems will increase with increasing humidity as the particles curl and degrade. Results have indicated that when operated in the proper regime, the bulk of the increase in pressure drop results from the conversion of Ba(OH) 2 .8H 2 O to BaCO 3 and not from the hydration of the commercial Ba(OH) 2 .8H 2 O (i.e. Ba(OH) 2 .7.50H 2 O) to Ba(OH) 2 .8H 2 O

  12. Determinação de fatores da equação universal de perda de solo em Sumé, PB Determination of the factors of the universal soil loss equation in Sumé (Paraíba State, Brazil

    Directory of Open Access Journals (Sweden)

    Abel W. de Albuquerque

    2005-06-01

    Full Text Available Para se alcançar os objetivos previstos neste trabalho, determinaram-se os fatores da Equação Universal de Perda de Solo (EUPS em condições de chuva natural, num Luvissolo de Sumé, PB, em que os dados relativos aos anos de 1983-1990 foram obtidos na Estação Experimental de Sumé, PB, pertencente à Universidade Federal da Paraíba - UFPB, cujos tratamentos foram os seguintes: parcela descoberta e em alqueive contínuo, parcela com caatinga nativa, parcela com caatinga nova, parcelas em pousio, parcela com palma cultivada morro abaixo e parcela com palma cultivada em nível. Os valores médios anuais do fator erosividade da chuva expressos em EI30 e PI30 foram de 4.928 MJ mm ha-1 h-1 e 19.734 mm-2 h-1, respectivamente. Os valores do fator erodibilidade do solo (K foram calculados em 0,013 t h MJ-1 mm-1 e 0,003 t ha-1 mm-2, enquanto os valores determinados para o fator uso e manejo do solo foram os seguintes: 0,0015 (caatinga nativa, 0,0174 (caatinga nova, 0,0133 (cobertura morta, 0,0056 (cobertura morta, 0,5103 (palma cultivada morro abaixo e 0,2355 (palma cultivada em nível. O valor do fator práticas conservacionistas para palma cultivada em nível foi de 0,46The Universal Soil Loss Equation (USLE factors were determined in a Haplargs under natural rainfall conditions. Data concerning to the years of 1983 -1990 were obtained at the Sumé Experimental Station (Paraíba State - Brazil of the Federal University of Paraíba (UFPB. The treatments consisted of runoff plots with bare soil, native semiarid vegetation runoff plot, mulch runoff plot, palm leaf under downhill runoff plot and under contour palm leaf runoff plot. The annual average of the rainfall erosivity factors EI30 and PI30 were 4,928 MJ mm ha-1 h-1 and 19,734 mm-2 h-1, respectively. The calculated annual mean values of the erodibility parameters were calculated in 0.013 t h MJ-1 mm-1 and 0.003 t h ha-1 mm-2. The calculated values for the support practice factor cropping

  13. Optical energy gaps and photoluminescence peaks of BaGa{sub 2}S{sub 4}:Er{sup 3+} and BaGa{sub 2}Se{sub 4}:Er{sup 3+} single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Choe, Sung-Hyu [Chosun University, Kwangju (Korea, Republic of); Jin, Moon-Seog [Dongshin University, Naju (Korea, Republic of); Kim, Wha-Tek [Chonnam National University, Kwangju (Korea, Republic of)

    2005-12-15

    BaGa{sub 2}S{sub 4}:Er{sup 3+} and BaGa{sub 2}Se{sub 4}:Er{sup 3+} single crystals were grown by using the chemical transport reaction method. The optical energy gaps of the BaGa{sub 2}S{sub 4}:Er{sup 3+} and the BaGa{sub 2}Se{sub 4}:Er{sup 3+} single crystals were found to be 4.045 eV and 3.073 eV, respectively, at 11 K. The temperature dependence of the optical energy gap was well fitted by the Varshni equation. Sharp emission peaks were observed in the photoluminescence spectra of the single crystals and assigned to radiation recombination between split Stark levels of the Er{sup 3+} ion.

  14. The synthesis and characterization of p(nBA-DEAEMA) polymer

    Science.gov (United States)

    Jiang, X. M.; Zhu, J.; Duan, Y. Y.

    2018-01-01

    In this paper, the polymer of p (nBA-DEAEMA) was polymerized and characterized. The structure of copolymer was characterized by FT-IR and 1HNMR, and the analysis of particle size, appearance and rheology was determined too. The results showed that, the p (nBA-DEAEMA) was synthesised successful, and it could become a surface modification for the inner face of artificial trachea, after further optimization.

  15. Structural characterization of a new vacancy ordered perovskite modification found for Ba3Fe3O7F (BaFeO2.333F0.333): Towards understanding of vacancy ordering for different perovskite-type ferrites

    International Nuclear Information System (INIS)

    Clemens, Oliver

    2015-01-01

    The new vacancy ordered perovskite-type compound Ba 3 Fe 3 O 7 F (BaFeO 2.33 F 0.33 ) was prepared by topochemical low-temperature fluorination of Ba 2 Fe 2 O 5 (BaFeO 2.5 ) using stoichiometric amounts of polyvinylidene difluoride (PVDF). The vacancy order was found to be unique so far for perovskite compounds, and the connectivity pattern can be explained by the formula Ba 3 (FeX 6/2 ) (FeX 5/2 ) (FeX 3/2 X 1/1 ), with X=O/F. Mössbauer measurements were used to confirm the structural analysis and agree with the presence of Fe 3+ in the above mentioned coordination environments. Group–subgroup relationships were used to build a starting model for the structure solution and to understand the relationship to the cubic perovskite structure. Furthermore, a comparison of a variety of vacancy-ordered iron-containing perovskite-type structures is given, highlighting the factors which favour one structure type over the other depending on the composition. - Graphical abstract: The crystal structure of Ba 3 Fe 3 O 7 F in comparison to other perovskite type ferrites. - Highlights: • The crystal structure of Ba 3 Fe 3 O 7 F in comparison to other perovskite type ferrites. • Ba 3 Fe 3 O 7 F was synthesized by low temperature fluorination of Ba 2 Fe 2 O 5 . • Ba 3 Fe 3 O 7 F shows a unique vacancy order not found for other perovskite type compounds. • The structure of Ba 3 Fe 3 O 7 F was solved using group–subgroup relationships. • A systematic comparison to other ferrite type compounds reveals structural similarities and differences. • The A-site coordination of the cation is shown to play an important role for the type of vacancy order found

  16. Dielectric enhancement of BaTiO3/SrTiO3 superlattices with embedded Ni nanocrystals

    International Nuclear Information System (INIS)

    Xiong Zhengwei; Sun Weiguo; Wang Xuemin; Jiang Fan; Wu Weidong

    2012-01-01

    Highlights: ► The BaTiO 3 /SrTiO 3 superlattices with embedded Ni NCs were successfully fabricated by L-MBE. ► The influence with the various concentrations of Ni nanocrystals embedded in BaTiO 3 /SrTiO 3 superlattices was also discussed. ► The BaTiO 3 /SrTiO 3 superlattices with lower concentration of embedded Ni NCs had higher permittivity and dielectric loss compared with the pure BaTiO 3 /SrTiO 3 superlattices. ► The dielectric enhancement of BaTiO 3 /SrTiO 3 superlattices with embedded Ni NCs was proposed to explained by Drude quasi-free-electron theory. - Abstract: The self-organized Ni nanocrystals (NCs) were embedded in BaTiO 3 /SrTiO 3 superlattices using laser molecular beam epitaxy (L-MBE). The stress of the composite films was increased with the increasing concentration of embedded Ni NCs, as investigation in stress calculation. The influence with the various concentrations of Ni NCs embedded in BaTiO 3 /SrTiO 3 superlattices was also discussed. The internal stress of the films was too strong to epitaxial growth of BaTiO 3 /SrTiO 3 superlattices. Compared with the pure BaTiO 3 /SrTiO 3 superlattices, the BaTiO 3 /SrTiO 3 superlattices with lower concentration of embedded Ni NCs had higher permittivity and dielectric loss. Furthermore, the dielectric enhancement of BaTiO 3 /SrTiO 3 superlattices with embedded Ni NCs was proposed to explained by Drude quasi-free-electron theory.

  17. Impacts of Mining and Urbanization on the Qin-Ba Mountainous Environment, China

    Directory of Open Access Journals (Sweden)

    Xinliang Xu

    2016-05-01

    Full Text Available The Qin-Ba Ecological Functional Zone is a component of China’s ecological security pattern designed to protect the regional ecosystem and maintain biodiversity. However, due to the impact of mining and urban encroachment, the plight of a sustainable ecosystem in the Qin-Ba mountainous area is deteriorating. This paper has used a remote sensing and geographic information system (GIS to examine the impacts of mining and urban encroachment on the environment in the Qin-Ba mountainous area. The results indicate that the total mined area in 2013 was 22 km2 and is predicted to escalate. Results also show that the ecosystems in Fengxian County, Shaanxi Province and Baokang County, Hubei Province were most severely affected by mining. Urbanization in the Qin-Ba mountainous area has seen an increase of 85.58 km2 in urban land use from 2010 to 2013. In addition, infrastructure development including airport construction, tourism resorts and real estate development in the Qin-Ba mountainous area has intensified environmental and biodiversity disturbances since large areas of forest have been cleared. Our results should provide insight and assistance to city planners and government officials in making informed decisions.

  18. Recent progress in material technology on RE-Ba-Cu-O bulk superconductors

    International Nuclear Information System (INIS)

    Teshima, Hidekazu; Morita, Mitsuru

    2011-01-01

    The current status of large-grained RE-Ba-Cu-O (RE: Y or rare earth elements) bulk superconductors with excellent superconducting properties is described. Gd-Ba-Cu-O bulk superconductors can trap a very high magnetic field even if they are melt-processed in air. Although the electromagnetic force caused by the trapped field is larger for a larger sample and may break the sample, a large sample of Gd-Ba-Cu-O 46 mm in diameter has the potential of trapped magnetic fields greater than 10 T at around 40 K. In addition, single-grained bulk superconductors as large as 150 mm can be obtained using the RE compositional gradient method. Dy-Ba-Cu-O is an ideal material for current leads because it has low thermal conductivity and high critical current density at 77 K in high magnetic fields. Eu-Ba-Cu-O has low magnetic permeability, and is therefore suitable for bulk NMR applications. Progress in machining technology has made possible various bulk superconductors with complicated shapes such as coils, leading to small and strong electromagnets by stacking several coil-shaped bulk superconductors together. (author)

  19. Large linear magnetoresistance in a new Dirac material BaMnBi2

    International Nuclear Information System (INIS)

    Wang Yi-Yan; Yu Qiao-He; Xia Tian-Long

    2016-01-01

    Dirac semimetal is a class of materials that host Dirac fermions as emergent quasi-particles. Dirac cone-type band structure can bring interesting properties such as quantum linear magnetoresistance and large mobility in the materials. In this paper, we report the synthesis of high quality single crystals of BaMnBi 2 and investigate the transport properties of the samples. BaMnBi 2 is a metal with an antiferromagnetic transition at T N = 288 K. The temperature dependence of magnetization displays different behavior from CaMnBi 2 and SrMnBi 2 , which suggests the possible different magnetic structure of BaMnBi 2 . The Hall data reveals electron-type carriers and a mobility μ (5 K) = 1500 cm 2 /V·s. Angle-dependent magnetoresistance reveals the quasi-two-dimensional (2D) Fermi surface in BaMnBi 2 . A crossover from semiclassical MR ∼ H 2 dependence in low field to MR ∼ H dependence in high field, which is attributed to the quantum limit of Dirac fermions, has been observed in magnetoresistance. Our results indicate the existence of Dirac fermions in BaMnBi 2 . (rapid communication)

  20. Ion conductivities of ZrF4-BaF2-CsF glasses

    International Nuclear Information System (INIS)

    Kawamoto, Yoji; Nohara, Ichiro

    1987-01-01

    The glass-forming region in the ZrF 4 -BaF 2 -CsF glass system has been determined and the ac conductivity and the transport number of fluoride ions have been measured. The conductivities of compounds β-Cs 2 ZrF 6 , α-SrZrF 6 , α-BaZrF 6 , β-BaZrF 6 and α-PbZrF 6 have also been measured. These results and a previous study of ZrF 4 -BaF 2 -MF n (M: the groups I-IV metals) glasses revealed the following: (1) the ZrF 4 -BaF 2 -CsF glasses are exclusively fluoride-ion conductors; (2) the ionic conductivities of ZrF 4 -based glasses are predominantly determined by the activation energies for conduction; (3) the activation energy for conduction decreases with an increase in the average polarizability of glass-constituting cations; (4) a decrease in average Zr-F bond length and a lowering of the average F coordination number of Zr are presumed to increase the activation energy for conduction. Principles of developing ZrF 4 -based glasses with higher conductivities have also been proposed. (Auth.)

  1. Receptor models for source apportionment of remote aerosols in Brazil

    International Nuclear Information System (INIS)

    Artaxo Netto, P.E.

    1985-11-01

    The PIXE (particle induced X-ray emission), and PESA (proton elastic scattering analysis) method were used in conjunction with receptor models for source apportionment of remote aerosols in Brazil. The PIXE used in the determination of concentration for elements with Z >- 11, has a detection limit of about 1 ng/m 3 . The concentrations of carbon, nitrogen and oxygen in the fine fraction of Amazon Basin aerosols was measured by PESA. We sampled in Jureia (SP), Fernando de Noronha, Arembepe (BA), Firminopolis (GO), Itaberai (GO) and Amazon Basin. For collecting the airbone particles we used cascade impactors, stacked filter units, and streaker samplers. Three receptor models were used: chemical mass balance, stepwise multiple regression analysis and principal factor analysis. The elemental and gravimetric concentrations were explained by the models within the experimental errors. Three sources of aerosol were quantitatively distinguished: marine aerosol, soil dust and aerosols related to forests. The emission of aerosols by vegetation is very clear for all the sampling sites. In Amazon Basin and Jureia it is the major source, responsible for 60 to 80% of airborne concentrations. (Author) [pt

  2. Uraniferous albitites from the Lagoa Real Uranium Province, state of Bahia, Brazil

    International Nuclear Information System (INIS)

    Brito, W. de; Raposo, C.; Matos, E.C. de

    1984-01-01

    The Uranium Province of Lagoa Real is located in the region of Caetite, throughout the south-central portion of the state of Bahia. The basic chronostratigraphic units are the metamorphic rocks - granitic rocks and gneisses of the Archean basement - and cataclastic metasomatic rocks - albitites and quartzo-feldspathic lithologies of the lower Proterozoic. The albitites, host rocks for the uranium mineralization, occur regionally as numerous lenticular and discontinuos bodies arranged submeridionally according to two main alignments forming an arc, and are therefore called linear albities in allusion to similar features in Kasachstan, Russia, where they were first given this designation. The name albitite was employed to designate the metasomatites in which albitite dominates over the other minerals. The uranium mineralization consists of uraninite and pitchblende and is confined to the ore zones of those albitites containing aegirine, alkali-amphiboles, andradite, biotite and carbonates Furthermore, it displays lithologic-structural control, the morphology being controlled by the location of shear zones. This mineralization usually takes the shape of ore shoots which pitch in the direction and dip of the lineation. The authors describe the various types of albitites (mineralized or unmineralized) and their structural and petrographic characteristics, mode of occurence, geometry, metasomatic alterations, chemistry, uranium mineralization, as well as their genetic aspects. (Author) [pt

  3. Growth of single crystals of BaFe12O19 by solid state crystal growth

    Science.gov (United States)

    Fisher, John G.; Sun, Hengyang; Kook, Young-Geun; Kim, Joon-Seong; Le, Phan Gia

    2016-10-01

    Single crystals of BaFe12O19 are grown for the first time by solid state crystal growth. Seed crystals of BaFe12O19 are buried in BaFe12O19+1 wt% BaCO3 powder, which are then pressed into pellets containing the seed crystals. During sintering, single crystals of BaFe12O19 up to ∼130 μm thick in the c-axis direction grow on the seed crystals by consuming grains from the surrounding polycrystalline matrix. Scanning electron microscopy-energy dispersive spectroscopy analysis shows that the single crystal and the surrounding polycrystalline matrix have the same chemical composition. Micro-Raman scattering shows the single crystal to have the BaFe12O19 structure. The optimum growth temperature is found to be 1200 °C. The single crystal growth behavior is explained using the mixed control theory of grain growth.

  4. Simulation of iron impurity in BaTiO3 crystals

    International Nuclear Information System (INIS)

    Stashans, Arvids; Castillo, Darwin

    2009-01-01

    Iron-doped barium titanate (BaTiO 3 ) has been simulated taking into account cubic and tetragonal crystallographic lattices of the crystal. A quantum-chemical method based on the Hartree-Fock formalism has been used throughout the study. The calculated equilibrium structures of Fe-doped crystals reveal the defect-inward displacements of the Ti and O atoms whereas the shifts for the Ba atoms are encountered to be away with respect to the Fe impurity. According to the analysis of electron density population and electron band structure it is found that some unusual chemical bonding might take place between the Fe atom and its six adjacent O atoms. The role of Fe impurity in the ferroelectric polarization of the tetragonal BaTiO 3 crystal has been discussed too.

  5. Synthesis and characterization of (Ba,Yb doped ceria nanopowders

    Directory of Open Access Journals (Sweden)

    Branko Matović

    2011-06-01

    Full Text Available Nanometric size (Ba, Yb doped ceria powders with fluorite-type structure were obtained by applying selfpropagating room temperature methods. Tailored composition was: Ce0.95−xBa0.05YbxO2−δ with fixed amount of Ba − 0.05 and varying Yb content “x” from 0.05 to 0.2. Powder properties such as crystallite and particle size and lattice parameters have been studied. Röntgen diffraction analyses (XRD were used to characterize the samples at room temperature. Also, high temperature treatment (up to 1550°C was used to follow stability of solid solutions. The mean diameters of the nanocrystals are determined from the full width at half maxima (FWHM of the XRD peaks. It was found that average diameter of crystallites is less than 3 nm. WilliamsonHall plots were used to separate the effect of the size and strain in the nanocrystals.

  6. Synthesis and electrical properties of BaBiO3 and high resistivity BaTiO3–BaBiO3 ceramics

    Directory of Open Access Journals (Sweden)

    Nitish Kumar

    2016-12-01

    Full Text Available Ceramics of the composition BaBiO3 (BB were sintered in oxygen to obtain a single phase with monoclinic I2/m symmetry as suggested by high-resolution X-ray diffraction. X-ray photoelectron spectroscopy confirmed the presence of bismuth in two valence states — 3+ and 5+. Optical spectroscopy showed presence of a direct bandgap at ∼ 2.2eV and a possible indirect bandgap at ∼ 0.9eV. This combined with determination of the activation energy for conduction of 0.25eV, as obtained from ac impedance spectroscopy, suggested that a polaron-mediated conduction mechanism was prevalent in BB. The BB ceramics were crushed, mixed with BaTiO3 (BT, and sintered to obtain BT–BB solid solutions. All the ceramics had tetragonal symmetry and exhibited a normal ferroelectric-like dielectric response. Using ac impedance and optical spectroscopy, it was shown that resistivity values of BT–BB were orders of magnitude higher than BT or BB alone, indicating a change in the fundamental defect equilibrium conditions. A shift in the site occupancy of Bi to the A-site is proposed to be the mechanism for the increased electrical resistivity.

  7. Solution based approaches for the morphology control of BaTiO3 particulates

    Directory of Open Access Journals (Sweden)

    Florentina Maxim

    2010-09-01

    Full Text Available Within the action COST 539 - ELENA our contribution was aimed at studying solution based approaches for the morphology control of BaTiO3 particulates. Initially, our kinetic analysis and systematic structural and morphological studies, demonstrated that during hydrothermal synthesis from layered titanate nanotubes (TiNTS, BaTiO3 forms via two mechanisms depending on the temperature and time. At low temperatures (90°C, “wild” type BaTiO3 dendritic particles with cubic structure were formed through a phase boundary topotactic reaction. At higher temperatures and/or for longer times time, the reaction is controlled by a dissolution precipitation mechanism and “seaweed” type BaTiO3 dendrites are formed. Our results unambiguously elucidated why TiNTs do not routinely act as templates for the formation of 1D BaTiO3.In our subsequent investigations, the effect of additives on the aqueous and hydrothermal synthesis of BaTiO3 was assessed. We reported that although the tested additives influenced the growth of BaTiO3, their behaviour varied; poly(acrylic acid (PAA adsorbed on specific crystallographic faces changing the growth kinetics and inducing the oriented attachment of the particles; poly(vinyl pyrrolidone (PVP, sodium dodecylsulfate (SDS and hydroxypropylmethylcellulose (HPMC act as growth inhibitors rather than crystal habit modifiers; and DFructose appeared to increase the activation energy for nucleation, resulting in small crystals (26 nm. Our work clearly indicates that the synthesis of 1D nanostructures of complex oxides by chemical methods is non trivial.

  8. Growth of BaSi2 film on Ge(100) by vacuum evaporation and its photoresponse properties

    Science.gov (United States)

    Trinh, Cham Thi; Nakagawa, Yoshihiko; Hara, Kosuke O.; Kurokawa, Yasuyoshi; Takabe, Ryota; Suemasu, Takashi; Usami, Noritaka

    2017-05-01

    We have successfully grown a polycrystalline orthorhombic BaSi2 film on a Ge(100) substrate by an evaporation method. Deposition of an amorphous Si (a-Si) film on the Ge substrate prior to BaSi2 evaporation plays a critical role in obtaining a high-quality BaSi2 film. By controlling substrate temperature and the thickness of the a-Si film, a crack-free and single-phase polycrystalline orthorhombic BaSi2 film with a long carrier lifetime of 1.5 µs was obtained on Ge substrates. The photoresponse property of the ITO/BaSi2/Ge/Al structure was clearly observed, and photoresponsivity was found to increase with increasing substrate temperature during deposition of a-Si. Furthermore, the BaSi2 film grown on Ge showed a higher photoresponsivity than that grown on Si, indicating the potential application of evaporated BaSi2 on Ge to thin-film solar cells.

  9. Preparation and characterization of BaFe12O19/Y3Fe5O12 composites

    International Nuclear Information System (INIS)

    Lin, Ying; Kang, Pan; Yang, Haibo; Liu, Miao

    2015-01-01

    Highlights: • BaM/YIG composites were fabricated by microwave sintering method. • A simple sol–gel method was used to synthesize BaM/YIG composite powders. • The BaM phase and YIG phase are well exchange coupled in the composites. • The (BH) max can be much enhanced by the introduction of YIG. - Abstract: BaFe 12 O 19 /Y 3 Fe 5 O 12 (BaM/YIG) composites with giant enhancement of magnetic energy product ((BH) max ) were fabricated by microwave sintering the BaM/YIG composite powders, which were firstly prepared using a simple sol–gel method. The phase composition and surface morphology of the as-synthesized composites were characterized by an X-ray diffractometer and a scanning electron microscopy equipped with energy dispersive X-ray spectroscopy, respectively. The magnetic properties of the composites were investigated by a vibrating sample magnetometer. All the composites show single-phase-like magnetic hysteresis loops. The results reveal the hard phase (BaM) and soft phase (YIG) are well exchange coupled and the introduction of YIG could significantly enhance the remnant magnetization (M r ), coercivity (H c ) and (BH) max of BaM

  10. Ocorrência de infecção natural de Fasciola hepatica Linnaeus, 1758 em Lymnaea columella Say, 1817 no Vale do Paraíba, SP, Brasil Natural infection by Fasciola hepatica in Lymnaea columella in the Paraíba river valley, S. Paulo, Brazil

    Directory of Open Access Journals (Sweden)

    Marlene Tiduko Ueta

    1980-06-01

    Full Text Available Foram registradas em Piquete, no vale do rio Paraíba do Sul (SP, Brasil, taxas de 1,22% e 0,14% de infecção natural em Lymnaea columella, por Fasciola hepatica. Em um único exemplar de Lymnaea columella dentre os 1.052 examinados, foram observadas rédias com xifidiocercárias, rédias com cercárias de Fasciola hepatica e metacercárias de Echinostomatidae.Infection rates of 1.22% and 0.14% were obtained in Lymnaea columella snails naturally infected by Fasciola hepatica. Samples of the snails were collected in Piquete, a municipality of Paraíba do Sul, a river valley area in the State of S. Paulo. Also observed was one of the 1052 specimen of the Lymnaea columella rediae which had xiphidiocercariae and rediae with Fasciola hepatica cercariae and metacercariae of Echinostomatidae.

  11. Barium isotope fractionation during experimental formation of the double carbonate BaMn[CO3](2) at ambient temperature.

    Science.gov (United States)

    Böttcher, Michael E; Geprägs, Patrizia; Neubert, Nadja; von Allmen, Katja; Pretet, Chloé; Samankassou, Elias; Nägler, Thomas F

    2012-09-01

    In this study, we present the first experimental results for stable barium (Ba) isotope ((137)Ba/(134)Ba) fractionation during low-temperature formation of the anhydrous double carbonate BaMn[CO(3)](2). This investigation is part of an ongoing work on Ba fractionation in the natural barium cycle. Precipitation at a temperature of 21±1°C leads to an enrichment of the lighter Ba isotope described by an enrichment factor of-0.11±0.06‰ in the double carbonate than in an aqueous barium-manganese(II) chloride/sodium bicarbonate solution, which is within the range of previous reports for synthetic pure BaCO (3) (witherite) formation.

  12. Dosimetry of ultraviolet radiation with BaHfO{sub 3} powders; Dosimetria de radiacion ultravioleta con polvos de BaHfO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Barrera A, A. A.; Aguilar D, G. A.; Guzman M, J.; Rivera M, T. [IPN, Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, Av. Legaria 694, Col. Irrigacion, 11500 Ciudad de Mexico (Mexico); Ceron R, V., E-mail: abalba1@hotmail.com [Universidad de Guanajuato, 37670 Leon, Guanajuato (Mexico)

    2016-10-15

    Ceramic materials based on pure barium hafnate (BaHfO{sub 3}) have been obtained as a powder by the co-precipitation method. The powders obtained have a cubic structure that favors the thermoluminescent and optical properties, through which a better detection of the non-ionizing radiation is allowed. With these powders various tests were performed in the ultraviolet range at different exposure times. These thermoluminescent (Tl) studies were carried out using a Tl 3500 hand held reader which yielded a brightness curve that ranged from room temperature to the 350 degrees Celsius. This BaHfO{sub 3} response exhibits a broad brightness curve with a single peak centered around 225 degrees Celsius. Finally, is reported that there are materials of barium hafnate (BaHfO{sub 3}) doped with some rare earths (Eu, Tb) which, instead of improving the performance of the powders, decrease it, so that the use of intrinsic barium hafnate is the most appropriate. (Author)

  13. Improvement of the performance of microwave X band absorbers based on pure and doped Ba-hexaferrite

    Energy Technology Data Exchange (ETDEWEB)

    Seyyed Afghahi, Seyyed Salman [Department of Materials Science and Engineering, Imam Hossein University, Tehran (Iran, Islamic Republic of); Jafarian, Mojtaba, E-mail: m.jafarian@srbiau.ac.ir [Young Researchers and Elite Club, Science and Research Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of); Salehi, Mohsen [Young Researchers and Elite Club, Science and Research Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of); Atassi, Yomen [Department of Applied Physics, Higher Institute for Applied Sciences and Technology, Damascus (Syrian Arab Republic)

    2017-01-01

    Optimum Fe/Ba mole ratio is determined in doped Ba-hexaferrite prepared via mechanical activation. X-ray diffractometer (XRD), scanning electron microscope (SEM), vibrating sample magnetometer (VSM) and vector network analyzer are used to analyze phases, structures, electromagnetic and microwave absorption properties. The mole ratio of Fe/Ba=10 is detected to be optimum for doping and synthesizing the Ba-hexaferrite. In order to achieve high absorption in X band the ions of Zr{sup 4+}–Sn{sup 4+}–Ti{sup 4+}–M{sup 2+} (M=Mg{sup 2+}, Zn{sup 2+}, Cu{sup 2+}, Co{sup 2+}) are used as dopants. The results indicate the formation of single phase Ba-hexaferrite in either pure or doped compounds without any non-magnetic intermediate phases and with spherical and hexagonal morphologies respectively for the pure and doped ferrite. It is found out that BaCo{sub 2}Zr(SnTi){sub 0.5}Fe{sub 8}O{sub 19} compound has the maximum saturation magnetization (49.80 emu/g). Also the composite of BaCo{sub 2}Zr(SnTi){sub 0.5}Fe{sub 8}O{sub 19} 50 wt% in epoxy resin exhibits a minimum reflection loss of −29 dB at 12.2 GHz with 2.6 GHz bandwidth. - Highlights: • Optimum Fe/Ba mole ratio is determined in doped Ba-hexaferrite. • Formation of a single phase M-hexaferrite, pure or doped when Fe/Ba=10. • Preparation of microwave absorber of BaCo{sub 2}Zr(SnTi){sub 0.5}Fe{sub 8}O{sub 19}/epoxy resin, 50 wt%. • The absorber exhibits a minimum RL of −29 dB at 12.2 GHz with 2.6 GHz bandwidth.

  14. Conduction Mechanisms in Multiferroic Multilayer BaTiO3/NiFe2O4/BaTiO3 Memristors

    Science.gov (United States)

    Samardzic, N.; Bajac, B.; Srdic, V. V.; Stojanovic, G. M.

    2017-10-01

    Memristive devices and materials are extensively studied as they offer diverse properties and applications in digital, analog and bio-inspired circuits. In this paper, we present an important class of memristors, multiferroic memristors, which are composed of multiferroic multilayer BaTiO3/NiFe2O4/BaTiO3 thin films, fabricated by a spin-coating deposition technique on platinized Si wafers. This cost-effective device shows symmetric and reproducible current-voltage characteristics for the actuating voltage amplitude of ±10 V. The origin of the conduction mechanism was investigated by measuring the electrical response in different voltage and temperature conditions. The results indicate the existence of two mechanisms: thermionic emission and Fowler-Nordheim tunnelling, which alternate with actuating voltage amplitude and operating temperature.

  15. BACTERICIDAL COATINGS ON TEXTILES FOR REMEDIATION OF INTERMICROBE ACTIVITY (BaCTeRIA) SUMMARY REPORT

    Science.gov (United States)

    2017-07-07

    TEXTILES FOR REMEDIATION OF INTERMICROBE ACTIVITY (BaCTeRIA) SUMMARY REPORT by Tobyn A. Branck Courtney M. Cowell Jennifer M. Rego and...October 2011 – September 2015 4. TITLE AND SUBTITLE BACTERICIDAL COATINGS ON TEXTILES FOR REMEDIATION OF INTERMICROBE ACTIVITY (BaCTeRIA) SUMMARY REPORT... REMEDIATION OF INTERMICROBE ACTIVITY (BaCTeRIA) SUMMARY REPORT Introduction The Biological Sciences and Technology Team (BSTT), Warfighter

  16. Two steps hydrothermal growth and characterisations of BaTiO3 films composed of nanowires

    Science.gov (United States)

    Zawawi, Che Zaheerah Najeehah Che Mohd; Salleh, Shahril; Oon Jew, Lee; Tufail Chaudhary, Kashif; Helmi, Mohamad; Safwan Aziz, Muhammad; Haider, Zuhaib; Ali, Jalil

    2018-05-01

    Barium titanate (BaTiO3) films composed of nanowires have gained considerable research interest due to their lead-free composition and strong energy conversion efficiency. BaTiO3 films can be developed with a simple two steps hydrothermal reactions, which are low cost effective. In this research, BaTiO3 films were fabricated on titanium foil through two steps hydrothermal method namely, the growth of TiO2 and followed by BaTiO3 films. The structural evolutions and the dielectric properties of the films were investigated as well. The structural evolutions of titanium dioxide (TiO2) and BaTiO3 nanowires were characterized using X-ray diffraction and scanning electron microscopy. First step of hydrothermal reaction, TiO2 nanowires were prepared in varied temperatures of 160 °C, 200 °C and 250 °C respectively. Second step of hydrothermal reaction was performed to produce a layer of BaTiO3 films.

  17. Growth and self-assembly of BaTiO3 nanocubes for resistive switching memory cells

    International Nuclear Information System (INIS)

    Chu, Dewei; Lin, Xi; Younis, Adnan; Li, Chang Ming; Dang, Feng; Li, Sean

    2014-01-01

    In this work, the self-assembled BaTiO 3 nanocubes based resistive switching memory capacitors are fabricated with hydrothermal and drop-coating approaches. The device exhibits excellent bipolar resistance switching characteristics with ON/OFF ratio of 58–70, better reliability and stability over various polycrystalline BaTiO 3 nanostructures. It is believed that the inter cube junctions is responsible for such a switching behaviour and it can be described by the filament model. The effect of film thickness on switching ratio (ON/OFF) was also investigated in details. - Graphical abstract: This work describes a novel resistive switching memory cell based on self-assembled BaTiO 3 nanocubes. - Highlights: • BaTiO 3 nanocubes were prepared by one step facile hydrothermal method. • Self-assembled BaTiO 3 nanocubes thin films were obtained by drop-coating approach. • The BaTiO 3 nanocubes show excellent resistive switching properties for memory applications

  18. Spatial distribution of trace elements in topsoils adjacent to main avenues of Sao Paulo city, Brazil

    International Nuclear Information System (INIS)

    Ribeiro, Andreza P.; Figueiredo, Ana Maria G.; Nammoura-Neto, Georges M.; Silva, Natalia C.; Ticianelli, Regina B.; Camargo, Sonia P.; Enzweiler, Jacinta

    2009-01-01

    In the present study, the concentration and distribution of Ba, Cu, Mo, Pb, S, Zn and Zr in soils collected along two main avenues (Pinheiros River Highway and Tiete River Highway) with high traffic density in the metropolitan region of Sao Paulo, Brazil, are presented, and their possible sources are discussed. These elements are strongly considered as contaminants originated from vehicular emissions. The analytical technique employed was XRF. The data set was evaluated by a t test for independent samples (group: avenues) at a 0.05 significance level. According to t test, the average contents obtained from Pinheiros River Highways are significantly different than the Tiete River, except for Mo. Multivariate statistic approaches (Pearson Correlation, Cluster and Factorial Analysis - FA) were adopted for data treatment. FA identified two main factors which accounted for about 86% of the total variance. The behavior of Ba, Cu, Pb, S and Zn were explained by the Factor 1. This indicates that the elements may have similar sources, probably related to gas emissions escaping from the vehicle fuel system. Factor 2 included Mo and Zr, suggesting their origin in the sample soils may be associated with the deterioration process of some device in the vehicular engine system or may be associated with the chemical composition of the urban soil analyzed. (author)

  19. Investigation on microstructure and dielectric behaviour of (Ba0· 999 ...

    Indian Academy of Sciences (India)

    Ceramics of BaTiO3 co-doped with Gd and Cr at Ba-site was synthesized via solid-state reaction route. Surface morphology shows the increase in grain size with the increase of Cr-content below 3 mol%. The high value of in the synthesized samples is associated with space charge polarization and inhomogeneous ...

  20. Searches for low-mass Higgs and dark bosons at BaBar

    Energy Technology Data Exchange (ETDEWEB)

    Oberhof, Benjamin, E-mail: benjamin.oberhof@pi.infn.it [INFN sezione di Pisa and Universitá di Pisa, Polo Fibonacci - Edificio C, Largo B. Pontecorvo 3, 56125 - Pisa (Italy)

    2013-01-15

    We present BaBar latest results for the direct search of a light CP-odd Higgs boson using radiative decays of the ϒ(nS) (n=1,2,3) resonances in different final states. We also present the results for the search of a hidden sector gauge and Higgs bosons using the full BaBar datasample.

  1. Particle morphology as a control of permeation in polymer films obtained from MMA/nBA colloidal dispersions.

    Science.gov (United States)

    Lestage, David J; Urban, Marek W

    2004-07-20

    The combination of precision-controlled weight loss measurements and spectroscopic surface FT-IR analysis allowed us to identify unique behaviors of poly(methyl methacrylate) (p-MMA). When MMA and n-butyl acrylate (nBA) are polymerized into p-MMA and p-nBA homopolymer blends, MMA/nBA random copolymers, and p-MMA/p-nBA core-shell morphologies, a controlled mobility and stratification of low molecular weight components occurs in films formed from coalesced colloidal dispersions. Due to different affinities toward water, p-MMA and p-nBA are capable of releasing water at different rates, depending upon particle morphological features of initial dispersions. As coalescence progresses, water molecules are released from the high free volume p-nBA particles, whereas p-MMA retains water molecules for the longest time due to its hydrophilic nature. As a result, water losses at extended coalescence times are relatively small for p-MMA. MMA/nBA copolymer and p-MMA/p-nBA blends follow the same trends, although the magnitudes of changes are not as pronounced. The p-MMA/p-nBA core-shell behavior resembles that of p-nBA homopolymer, which is attributed to significantly lower content of the p-MMA component in particles. Annealing of coalesced colloidal films at elevated temperatures causes migration of SDOSS to the F-A interface, but for films containing primarily p-nBA, reverse diffusion back into the bulk is observed. These studies illustrate that the combination of different particle morphologies and temperatures leads to controllable permeation processes through polymeric films. Copyright 2004 American Chemical Society

  2. Brazils Role in environmental governance: Analysis of possibilities for increased Brazil-Norway cooperation

    Energy Technology Data Exchange (ETDEWEB)

    Valberg, Anna Helene

    2011-07-01

    This report examines the role played by Brazil in connection with certain international negotiations, such as the climate negotiations and the CBD. It identifies the driving factors that have influenced environmental politics and standards in Brazil, and take note of conflicts that must be discussed when Norway is seeking expanded cooperation with Brazil. In line with the mandate, FNI identifies areas of particular interest for further collaboration between the two countries, and recommend directions for supplementary Norwegian policy-making in light of a broadened scope for Norway-Brazil interaction. In recent years, the Norwegian government has initiated an extensive process aimed at reducing emissions from deforestation and forest degradation (REDD). This is the most obvious shared environmental scope between Norway and Brazil. However, given the large body of literature that already exists on this field, this report will concentrate instead on issues more on the outskirts of the REDD discourse, such as biodiversity conservation, biofuel efficiency and challenges concerning hydropower, all of which threaten to impact negatively on the Amazonian areas. In our recommendations, we cite tangible examples to illustrate issues where we believe lessons learnt in Norway may have applicability to Brazil.(auth)

  3. Fabrication of Ba-K-Bi-O thick film artefacts with improved critical currents

    International Nuclear Information System (INIS)

    Moore, J.C.; Salter, C.J.; Jenkins, R.J.; Grovenor, C.R.M.; Jones, H.

    1993-01-01

    The Ba-K-Bi-O system has a maximum T c of around 30K for a composition of Ba 0.6 K 0.4 BiO 3 . Fabrication of good quality single phase samples is extremely difficult and requires careful control of the fabrication conditions. Successful synthesis procedures for Ba-K-Bi-O powder and melt cast material which allow some control of the potassium content of the product were established by Hinks et al. The process is based on a melt and sinter step in an inert atmosphere which creates oxygen vacancies and allows potassium to enter the lattice. The oxygen vacancies are then filled by a subsequent oxygen anneal to obtain superconductivity. Ba-K-Bi-O is, therefore, metastable and consequently difficult to synthesise. There have been few reports of transport measurements and even fewer reports of transport critical currents for bulk material. It is often accepted that Ba-K-Bi-O has an intrinsically low critical current, and extremely poor critical current densities of 0.05 Acm -2 have been quoted for melt cast material. It has been suggested that the presence of weak links is the cause. However, there has been little research into the relationship between process conditions and superconducting properties for melt processed Ba-K-Bi-O to confirm this. (orig.)

  4. Mapping the involvement of BA 4a and 4p during Motor Imagery.

    Science.gov (United States)

    Sharma, Nikhil; Jones, P S; Carpenter, T A; Baron, Jean-Claude

    2008-05-15

    Motor Imagery (MI) is an attractive but intriguing means to access the motor network. There are marked inconsistencies in the functional imaging literature regarding the degree, extent and distribution of the primary motor cortex (BA 4) involvement during MI as compared to Executed Movement (EM), which may in part be related to the diverse role of BA 4 and its two subdivisions (i.e., 4a and 4p) in motor processes as well as to methodological issues. Here we used fMRI with monitoring of compliance to show that in healthy volunteers optimally screened for their ability to perform MI the contralateral BA 4 is involved during MI of a finger opposition sequence (2, 3, 4, 5; paced at 1 Hz), albeit less than during EM of the same sequence, and in a location sparing the hand area. Furthermore, both 4a and 4p subdivisions were found to be involved in MI, but the relative involvement of BA 4p appeared more robust and closer to that seen with EM. We suggest that during MI the role of BA 4 and its subdivisions may be non-executive, perhaps related to spatial encoding, though clearly further studies are needed. Finally, we report a similar hemispheric activation balance within BA 4 with both tasks, which extends the commonalities between EM and MI.

  5. Nucleation control and inhibition of BaTiO3 films using hydrothermal-electrochemical method

    International Nuclear Information System (INIS)

    Escobar, Ivan; Silva, Carmen; Silva, Eric; Vargas, Tomas; Fuenzalida, Victor

    1999-01-01

    The microstructure of BaTiO 3 films on titanium by the hydrothermal-electrochemical method was investigated using a three electrode high pressure electrochemical cell in a 0.2 M Ba(OH) 2 electrolyte at 150 0 C. The spontaneous initial linked to pure hydrothermal BaTiO 3 formation can be inhibited by cathodically protecting titanium electrode since its immersion in the electrolyte. The application of initial nucleation pulses of varying the cathodic potentials affected the grain size of the deposit. It is suggested that the formation of a titanium oxide layers is a necessary step previous to the nucleation of BaTiO 3

  6. Pulsed laser deposition of Tl-Ca-Ba-Cu-O films

    International Nuclear Information System (INIS)

    Ianno, N.J.; Liou, S.H.; Woollam, J.A.; Thompson, D.; Johs, B.

    1990-01-01

    Pulsed laser deposition is a technique commonly used to deposit high quality thin films of high temperature superconductors. This paper discusses the results obtained when this technique is applied to the deposition of Tl-Ca-Ba-Cu-O thin films using a frequency doubled Nd:YAG laser operating at 532 nm and an excimer laser operating at 248 nm. Films with onset temperatures of 125 K and zero resistance temperatures of 110 K deposited on (100) oriented MgO from a composite Tl2Ca2Ba2Cu3Ox target were obtained at both wavelengths upon appropriate post deposition annealing. Films deposited at 532 nm exhibit a rough surface, while those deposited at 248 nm are smooth and homogeneous. Upon annealing, films deposited at both wavelengths are single phase Tl2Ca2Ba2Cu3Ox. 12 refs

  7. Cogeneration for Brazil

    International Nuclear Information System (INIS)

    Anon.

    2000-01-01

    Almost all the electric power in Brazil comes from large-scale hydroelectric plants: only about 3% comes from cogeneration. But, now that the barriers which discouraged cogeneration are being removed, there will be more and more investment in cogeneration and distributed generation. The circumstances which have brought about these changes are described. It is expected that cogeneration will be responsible for producing 10-15% of Brazil's electricity by 2010 and the demand for cogeneration will reach 11-17 GW. It is concluded that Brazil represents one of the world's most attractive market for cogeneration and distributed generation

  8. Accurate projected augmented wave datasets for BaFe2As2

    International Nuclear Information System (INIS)

    Cao Chao; Wu Yuing; Hamdan, Rashid; Wang, Yunpeng; Cheng Haiping

    2010-01-01

    By carefully choosing parameters and including more semi-core orbitals as valence electrons, we have constructed a high-quality projected augmented wave dataset that yields results comparable to existing full-potential linearized augmented plane-wave calculations. The dataset was then applied to BaFe 2 As 2 to study the effects of different levels of structure optimization, as well as different choices of exchange-correlation functionals. It was found that the local density approximation exchange-correlation functional fails to find the correct spin-density-wave anti-ferromagnetic (SDW-AFM) ground state under full optimization, while the Perdew-Burke-Ernzerhof (PBE) exchange-correlation functional obtains the correct state but significantly overestimates the magnetism. The electronic structure of the SDW-AFM state is not very sensitive to structure optimizations with the PBE exchange-correlation functional because the positions of the As atoms are preserved under optimizations. We further investigated the Ba atom diffusion process on the BaFe 2 As 2 surface using the nudged elastic bands method. The Ba atom was found to be stable above the center of the squares formed by the surface As atoms, and a diffusion barrier of 1.2 eV was found. Our simulated scanning tunneling microscopy image suggests an ordered surface Ba atom structure, in agreement with Massee et al (2009 Phys. Rev. B 80 140507; van Heumen E et al 2010 arXiv:1009.3493v1).

  9. The Danish Microbiology Database (MiBa) 2010 to 2013.

    Science.gov (United States)

    Voldstedlund, M; Haarh, M; Mølbak, K

    2014-01-09

    The Danish Microbiology Database (MiBa) is a national database that receives copies of reports from all Danish departments of clinical microbiology. The database was launched in order to provide healthcare personnel with nationwide access to microbiology reports and to enable real-time surveillance of communicable diseases and microorganisms. The establishment and management of MiBa has been a collaborative process among stakeholders, and the present paper summarises lessons learned from this nationwide endeavour which may be relevant to similar projects in the rapidly changing landscape of health informatics.

  10. Preparation, photoluminescent properties and luminescent dynamics of BaAlF5:Eu2+ nanophosphors

    International Nuclear Information System (INIS)

    Zhang, Wei; Hua, Ruinian; Liu, Tianqing; Zhao, Jun; Na, Liyan; Chen, Baojiu

    2014-01-01

    Graphical abstract: Rice-shaped BaAlF 5 :Eu 2+ nanophosphors were synthesized via one-pot hydrothermal process. The as-prepared BaAlF 5 :Eu 2+ are composed of many particles with an average diameter of 40 nm. When excited at 260 nm, the sharp line emission located at 361 nm of Eu 2+ was observed. The optimum doping concentration of Eu 2+ was confirmed to be 5 mol%. The strong ultraviolet emission of Eu 2+ ions in BaAlF 5 :Eu 2+ nanoparticles suggests that these nanoparticles may have potential applications for sensing, solid-state lasers and spectrometer calibration. - Highlights: • BaAlF 5 :Eu 2+ nanophosphors were synthesized via a mild hydrothermal process. • The Van and Huang models were used to research the mechanism of concentration quenching. • The optimum doping concentration of Eu2+ was confirmed to be 5 mol%. - Abstract: Eu 2+ -doped BaAlF 5 nanophosphors were synthesized via a facile one-pot hydrothermal method. The final products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. XRD results showed that the prepared samples are single-phase. The FE-SEM and TEM images indicated that the prepared BaAlF 5 :Eu 2+ nanophosphors are composed of many rice-shaped particles with an average diameter of 40 nm. When excited at 260 nm, BaAlF 5 :Eu 2+ nanophosphors exhibit the sharp line emissions of Eu 2+ at room temperature. The optimum doping concentration of Eu 2+ was confirmed to be 5 mol%. The Van and Huang models were used to study the mechanism of concentration quenching and the electric dipole–dipole interaction between Eu 2+ can be deduced to be a dominant for quenching fluorescence in BaAlF 5 :Eu 2+ nanophosphors. The strong ultraviolet emission of Eu 2+ in BaAlF 5 :Eu 2+ nanophosphors suggests that these nanoparticles may have potential applications for sensing, spectrometer calibration and solid-state lasers

  11. Sequential structural and antiferromagnetic transitions in BaFe2Se3 under pressure

    Science.gov (United States)

    Zhang, Yang; Lin, Ling-Fang; Zhang, Jun-Jie; Dagotto, Elbio; Dong, Shuai

    2018-01-01

    The discovery of superconductivity in the two-leg ladder compound BaFe2S3 has established the 123-type iron chalcogenides as a novel and interesting subgroup of the iron-based superconductor family. However, in this 123 series, BaFe2Se3 is an exceptional member, with a magnetic order and crystalline structure different from all others. Recently, an exciting experiment reported the emergence of superconductivity in BaFe2Se3 at high pressure [J. Ying et al., Phys. Rev. B 95, 241109(R) (2017), 10.1103/PhysRevB.95.241109]. In this paper, we report a first-principles study of BaFe2Se3 . Our analysis unveils a variety of qualitative differences between BaFe2S3 and BaFe2Se3 , including in the latter an unexpected chain of transitions with increasing pressure. First, by gradually reducing the tilting angle of iron ladders, the crystalline structure smoothly transforms from P n m a to C m c m at ˜6 GPa. Second, the system becomes metallic at 10.4 GPa. Third, its unique ambient-pressure Block antiferromagnetic ground state is replaced by the more common stripe (so-called CX-type) antiferromagnetic order at ˜12 GPa, the same magnetic state as the 123-S ladder. This transition is found at a pressure very similar to the experimental superconducting transition. Finally, all magnetic moments vanish at 30 GPa. This reported theoretical diagram of the complete phase evolution is important because of the technical challenges to capture many physical properties in high-pressure experiments. The information obtained in our calculations suggests different characteristics for superconductivity in BaFe2Se3 and BaFe2S3 : in 123-S pairing occurs when magnetic moments vanish, while in 123-Se the transition region from Block- to CX-type magnetism appears to catalyze superconductivity. Finally, an additional superconducting dome above ˜30 GPa is expected to occur.

  12. New species of the treehopper tribe Amastrini (Hemiptera, Membracidae, Smiliinae Novas espécies de membracídeos da tribo Amastrini (Hemiptera, Membracidae, Smiliinae

    Directory of Open Access Journals (Sweden)

    Olívia Evangelista

    2007-03-01

    Full Text Available Three new species of Amastris Stål and one of Erosne Stål are described and illustrated. Amastris rotheai sp. nov. (Paraiba, Brazil, A. gibberula sp. nov. (Mato Grosso, Brazil, A. comarapa sp. nov. (Santa Cruz, Bolivia, and Erosne parvula sp. nov. (Paraiba, Brazil.Três novas espécies de Amastris Stål e uma de Erosne Stål são descritas e ilustradas. Amastris rotheai sp. nov. (Paraíba, Brasil, A. gibberula sp. nov. (Mato Grosso, Brasil, A. comarapa sp. nov. (Santa Cruz, Bolívia e Erosne parvula sp. nov. (Paraíba, Brasil.

  13. Assessment of air quality in Mangabeiras' Park, Belo Horizonte, Brazil, using epiphytic lichens as biomonitor

    International Nuclear Information System (INIS)

    Viana, Camila de O.; Menezes, Maria Angela de B.C.; Maia, Elene C.P.

    2009-01-01

    Biomonitoring has been used as an alternative method to study the air pollution in several countries. The lichen, or lichenized fungi, is one of the most efficient on air pollution biomonitoring among the biomonitors. However, in Brazil, systematic use of lichens as biomonitors of environmental pollution is quite rare. In order to make an assessment of the air quality of the Mangabeiras' Park, this study was conducted by measuring the concentration of elements accumulated in the lichen thallus. This park, located in Belo Horizonte (Minas Gerais, Brazil), is the greatest green area in the city, and an apparent region of non polluted air. During the development of the study, epiphytic lichens of several species were collected using a steel stainless knife, taking samples of similar sizes from 1.5 m from the soil. The lichens selection was based on morphological similarities, such as color and type of the thallus. The elemental concentration determination was carried out applying the neutron activation technique, k 0 -standardization method, using the TRIGA Mark I IPR-R1 research reactor located at CDTN/CNEN. The lichen samples presented expressive concentrations of Ba, Fe, K, Na and Zn. However, the presence of other characteristic soil elements from the region, such as As, Th and U, suggests the influence of the mining activity area, located in the surroundings. (author)

  14. Structures, phase transitions and microwave dielectric properties of the 6H perovskites Ba3BSb2O9, B=Mg, Ca, Sr, Ba

    International Nuclear Information System (INIS)

    Ling, Chris D.; Rowda, Budwy; Avdeev, Maxim; Pullar, Robert

    2009-01-01

    We present a complete temperature-composition phase diagram for Ba 3 BSb 2 O 9 , B=Mg, Ca, Sr, Ba, along with their electrical behavior as a function of B. These compounds have long been recognized as 6H-type perovskites, but (with the exception of B=Mg) their exact structures and properties were unknown due to their low symmetries, temperature-dependent phase transitions, and difficulties in synthesizing pure samples. The full range of possible space group symmetries is observed, from ideal hexagonal P6 3 /mmc to monoclinic C2/c to triclinic P1-bar. Direct second-order transitions between these phases are plausible according to group theory, and no evidence was seen for any further intermediate phases. The phase diagram with respect to temperature and the effective ionic radius of B is remarkably symmetrical for B=Mg, Ca, and Sr. For B=Ba, a first-order phase transition to a locally distorted phase allows a metastable hexagonal phase to persist to lower temperatures than expected before decomposing around 600 K. Electrical measurements revealed that dielectric permittivity corrected for porosity does not change significantly as a function of B and is in a good agreement with the values predicted by the Clausius-Mossotti equation. - Graphical abstract: Thermodynamic phase diagram for Ba 3 BSb 2 O 9 , B=Mg, Ca, and Sr, as a function of temperature T and effective ionic radius (IR) of the B 2+ cation

  15. Effects of Ce, La and Ba addition on the electrochemical behavior of super duplex stainless steels

    International Nuclear Information System (INIS)

    Yoo, Yun-Ha; Choi, Yoon-Seok; Kim, Jung-Gu; Park, Yong-Soo

    2010-01-01

    The effects of rare earth metal (REM: Ce, La) and Ba addition on aqueous corrosion properties of super duplex stainless steels (SDSS) were investigated by electrochemical tests and surface analyses. The results of potentiodynamic test indicated that the passive range increased by the addition of Ce, La, and Ba, indicating increased relative resistance to localized corrosion. The EIS measurements showed that the Ce-La-Ba-bearing alloys exhibited higher R ct and R p values than the Ce-La-Ba-free alloy at the passive and breakdown states. Furthermore, the additions of REMs and Ba together promoted the formation of dense chromium-enriched passive film.

  16. Analysis in crab tissues and in sediment of estuary from Iguape (Sao Paulo, Brazil) by total reflection X-ray fluorescence

    International Nuclear Information System (INIS)

    Salvador, Marcos J.; Sawazaki, David T.A.; Zucchi, Orgheda L.A. Domingues; Vives, Ana Elisa S. de; Hattori, Gustavo Y.

    2007-01-01

    We report the use of Synchrotron Radiation Total Reflection X-Ray Fluorescence analysis (SR-TXRF) as a technique for macro, micro and trace elements determination in the tissues of the crab Ulcides cordatus and in the sediments from the Iguape estuary (Sao Paulo, Brazil) for environmental pollution control and toxicological evaluation. The analyses were performed on the U. cordatus (muscles and hepatopancreas) and on sediments from 24 sites of the Iguape estuary (Sao Paulo, Brazil). Tissues and sediments samples were analyzed by SRTXRF after digestion in an open system, using Ga as internal standard. Potassium (K), Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Sr, and Ba were the elements detected in crab hepatopancreas at concentration ranging from 0.516 (Mn) to 2061 (K) mug/g. Muscles samples presented the elements K, Ca, Ti, V, Cr, Fe, Ni, Cu, Zn, Br and Sr at concentrations ranging from 0.043 (Ni) to 1917 (K) mug/g. Potassium (K), Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Sn, Ce, and Pb were the elements detected in the sediment samples with concentration between 3.8 (Cu) and 14628 (Fe)mug/g. (author)

  17. Analysis in crab tissues and in sediment of estuary from Iguape (Sao Paulo, Brazil) by total reflection X-ray fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Salvador, Marcos J. [Universidade do Vale do Paraiba (UNIVAP), Sao Jose dos Campos, SP (Brazil)], E-mail: mjsalvador1531@yahoo.com.br; Sawazaki, David T.A.; Zucchi, Orgheda L.A. Domingues [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Faculdade de Ciencias Farmaceuticas], E-mail: david_tatsuo@hotmail.com, E-mail: olzucchi@fcfrp.usp.br; Vives, Ana Elisa S. de [Universidade Metodista de Piracicaba (UNIMEP), Santa Barbara D' Oeste, SP (Brazil). Faculdade de Engenharia Civil, Arquitetura e Urbanismo], E-mail: aesvives@unimep.br; Hattori, Gustavo Y. [Universidade Federal do Amazonas, Benjamin Constant (Brazil). Faculdade de Ciencias Agrarias], E-mail: hattori@ufam.edu.br

    2007-07-01

    We report the use of Synchrotron Radiation Total Reflection X-Ray Fluorescence analysis (SR-TXRF) as a technique for macro, micro and trace elements determination in the tissues of the crab Ulcides cordatus and in the sediments from the Iguape estuary (Sao Paulo, Brazil) for environmental pollution control and toxicological evaluation. The analyses were performed on the U. cordatus (muscles and hepatopancreas) and on sediments from 24 sites of the Iguape estuary (Sao Paulo, Brazil). Tissues and sediments samples were analyzed by SRTXRF after digestion in an open system, using Ga as internal standard. Potassium (K), Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Sr, and Ba were the elements detected in crab hepatopancreas at concentration ranging from 0.516 (Mn) to 2061 (K) mug/g. Muscles samples presented the elements K, Ca, Ti, V, Cr, Fe, Ni, Cu, Zn, Br and Sr at concentrations ranging from 0.043 (Ni) to 1917 (K) mug/g. Potassium (K), Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Sn, Ce, and Pb were the elements detected in the sediment samples with concentration between 3.8 (Cu) and 14628 (Fe)mug/g. (author)

  18. Nuclear sub-structure in 112–122Ba nuclei within relativistic mean field theory

    International Nuclear Information System (INIS)

    Bhuyan, M.; Patra, S.K.; Arumugam, P.; Gupta, Raj K.

    2011-01-01

    Working within the framework of relativistic mean field theory, we study for the first time the clustering structure (nuclear sub-structure) of 112–122 Ba nuclei in an axially deformed cylindrical coordinate. We calculate the individual neutrons and protons density distributions for Ba-isotopes. From the analysis of the clustering configurations in total (neutrons-plus-protons) density distributions for various shapes of both the ground and excited states, we find different sub-structures inside the Ba nuclei considered here. The important step, carried out here for the first time, is the counting of number of protons and neutrons present in the clustering region(s). 12 C is shown to constitute the cluster configuration in prolate-deformed ground-states of 112–116 Ba and oblate-deformed first excited states of 118–122 Ba nuclei. Presence of other lighter clusters such as 2 H, 3 H and nuclei in the neighborhood of N = Z, 14 N, 34–36 Cl, 36 Ar and 42 Ca are also indicated in the ground and excited states of these nuclei. Cases with no cluster configuration are shown for 112–116 Ba in their first and second excited states. All these results are of interest for the observed intermediate-mass-fragments and fusion–fission processes, and the so far unobserved evaporation residues from the decaying Ba* compound nuclei formed in heavy ion reactions. (author)

  19. Microwave-Hydrothermal Synthesis and Characterization of High-Purity Nb Doped BaTiO3 Nanocrystals

    Directory of Open Access Journals (Sweden)

    A. Khanfekr

    2014-01-01

    Full Text Available The synthesis of Nb doped BaTiO3 has been investigated under Microwave-Hydrothermal (MH conditions in the temperature of 150°C for only 2 h using C16H36O4Ti, BaH2O2.8H2O and NbCl5 as Ba, Ti and  Nb sources, respectively.  Typical experiments performed on MH processing have not yet reported for Nb doped BaTiO3.  In the MH process, the formation of high purity nano tetragonal Nb-BaTiO3 was strongly enhanced. New hydrothermal method was used instead of the previous solid state reaction for the BaTiO3±Nb2O3 system. The new method uses high pressure to create nano dimension particles in a lower time and temperature. In case of the phase evolution studies, the XRD pattern measurements and Raman spectroscopy were performed. TEM and FE-SEM images were taken for the detailed analysis of the particle size, surface and morphology.  Synthesis of Nb doped BaTiO3 with the Microwave-hydrothermal provides an advantage of fast crystallization and reduced crystal size when compared to existing methods.

  20. Apresentação Workshop Baía de Guanabara

    Directory of Open Access Journals (Sweden)

    Claudia Gutteres Vilela

    2003-01-01

    Full Text Available Ano 2003 Volume 26 - Workshop Baía de Guanabara Editor: Ismar de Souza Carvalho Coordenadora: Claudia Gutteres Vilela: Apresentação ISSN: 0101-9759 É com grande prazer que participo da edição do Anuário de 2003 do Instituto de Geociências, que inclui os trabalhos apresentados no Workshop Baía, realizado nos dias 12 e 13 de novembro de 2002, nesta instituição. O sucesso desse evento deve-se em grande parte aos trabalhos, apresentados sob a forma de palestras em mesas redondas ou painéis, por pesquisadores consagrados no Brasil e no exterior. O conteúdo dos trabalhos possui uma abrangência que se estende desde a Geologia até a Biologia, passando pela Oceanografia e Geografia, sempre com o objetivo comum de reunir dados sobre a Baía de Guanabara visando o diagnóstico ambiental. O Workshop Baía congregou diversas linhas de pesquisa desenvolvidas na Baía de Guanabara e regiões adjacentes, procurando uma integração das mesmas. Deste modo alguns trabalhos caracterizaram, em um contexto mais geral, a evolução do nível do mar na região sudeste durante o Holoceno, bem como apresentaram a neotectônica da região. Geoquímica orgânica de hidrocarbonetos e de metais pesados, sedimentologia e hidrogeologia integraram-se à distribuição de microorganismos nos sedimentos e na água, analisando diversas respostas a diferentes graus de poluição em regiões distintas. Um zoneamento ambiental ofereceu uma visão dinâmica das condições naturais e sociais do conjunto da Baía de Guanabara. A importância do workshop deve-se à busca de uma integração maior dos trabalhos acadêmicos para aplicação à gestão do desenvolvimento sustentável da Baía de Guanabara e seu entorno, que abriga a cidade do Rio de Janeiro e se constitui em uma das regiões com maior índice demográfico do Brasil. Seu impacto pode se avaliado pela presença de representantes de órgãos públicos como a SERLA, a Prefeitura de Niterói e ONGs ligadas a