WorldWideScience
1

The method for iron removal from cadmium in the course of refining process; Sposob usuwania zelaza z kadmu w procesie jego rafinacji  

Energy Technology Data Exchange (ETDEWEB)

The pyrometallurgic method consisting in introduction of refining agent into the liquid cadmium has been presented. The refining agent consisting of silicon nitride, carbon dust and sodium hydroxide has been added in several portion into the liquid cadmium. Iron has been removed from the cadmium surface in the form of floating slag.

1992-10-30

2

Real-time neutron radiography system performance - Measurements and methods  

Energy Technology Data Exchange (ETDEWEB)

The University of Virginia's real-time neutron radiography facility was characterized by measurement of the total neutron flux, gold/cadmium ratio, neutron/gamma ratio, and the effective collimar length-to-aperture diameter (L/D) ratio. The real-time neutron imaging system and collimator were further characterized by measuring the modulation transfer function (MTF) of the system. The collimator effectiveness was measured by using the MTF to determine the ''unparallelism'' of the neutron beam. The computer-based image processing system allowed rapid calculation of the MTF and the collimator effectiveness. The results of these measurements, using no collimator and a simple tube collimator, demonstrated the method's ability to determine the effective L/D ratio. The MTF measurement scheme provided a fast, ...

1988-09-01

3

Real-time neutron radiography system performance - Measurements and methods  

International Nuclear Information System (INIS)

The University of Virginia's real-time neutron radiography facility was characterized by measurement of the total neutron flux, gold/cadmium ratio, neutron/gamma ratio, and the effective collimar length-to-aperture diameter (L/D) ratio. The real-time neutron imaging system and collimator were further characterized by measuring the modulation transfer function (MTF) of the system. The collimator effectiveness was measured by using the MTF to determine the ''unparallelism'' of the neutron beam. The computer-based image processing system allowed rapid calculation of the MTF and the collimator effectiveness. The results of these measurements, using no collimator and a simple tube collimator, demonstrated the method's ability to determine the effective L/D ratio. The MTF measurement scheme provided a fast, reliable, and reproducible means of monitoring any changes in ...

1988-01-01

4

Extraction of copper-, nickel-, zinc- and cadmium complexes with 4-(2-pyridilazo)-resorcin and 2-aminopyridine  

International Nuclear Information System (INIS)

Extraction of copper-, nickel-, zinc- and cadmium complexes with 4-(2 pyridilazo)-resorcin (PAR) is studied in the presence of 2-aminopyridine (Am). Maximum optical densities of the extracts are attained at pH=7.5-8.0; 6.0-7.0; 6.5-7.0 and 7.0-8.0, respectively. The ratio of components in the complexes extractable by chloroform was defined by the method of isomolar series and equilibrium shift. It is established that nickel and copper are extracted to the organic phase as the NiAm(PAR)_2 and CuAmPAR complexes, and, in the case of zinc and cadmium, complexes of different composition are extracted, for example Zn(Am)_2PAR and ZnAm(PAR)_2. The light absorption spectra are studied and molar extinction coefficients of complex extracts are determined at lambdasub(max). It is shown that the general low of light absorption is observed within a sufficiently wide range of concentrations for all the elements.

1984-01-01

5

The recovery of zinc and cadmium following 6.1 MeV alpha particle irradiation at 4.2 K  

International Nuclear Information System (INIS)

The paper reports the recovery of zinc and cadmium following 6.1 MeV alpha particle irradiation at 4.2 K as studied by means of electrical reistivity measurements. Specimens of 10 #mu#m thick have been used in order to obtain a homogeneous defect distribution over the whole thickness of the specimen. The pre-irradiation resistivity ratios were 700 and 750 for cadmium and zinc, respectively. (Auth.).

6

Physical and electrochemical characterization of CdS hollow microspheres prepared by a novel template free solution phase method  

International Nuclear Information System (INIS)

Novel CdS hollow microspheres have been successfully synthesized via a facile template-free solution-phase reaction from cadmium nitrate and thioacetamide precursors. The morphology of CdS hollow microspheres depends strongly on the ratio between the precursors, cadmium nitrate to thioacetamide ratio. The physical properties of the hollow microspheres have systematically been studied by different characterization methods. The stoichiometry of the hollow microspheres studied by the energy dispersive X-ray diffraction spectroscopy confirmed that the synthesized CdS hollow microspheres are nearly stoichiometric bulk like CdS. The morphology of the hollow microspheres studied by high resolution scanning electron microscopy and transmission electron microscopy observations showed that the CdS hollow microspheres of the size of 2.5 ?m have hollow structure and are constructed by several ...

2010-12-15

7

Assessment of cadmium in aquatic sediment using dialysis samplers with ion-exchange-resin collection  

Energy Technology Data Exchange (ETDEWEB)

Simultaneously extracted metals (SEM) and acid volatile sulfide (AVS) show the potential for toxicity on the basis of their ratio. Accordingly, the authors spiked cadmium in a range for which Cd/AVS ratios were from 0.2 to 10 in the sediment with its weight about 8 kg in each batch. Dialysis samplers with a cation ion-exchange resin (Dowex 50W-X4) collection were used in a laboratory for the determination of free cadmium concentrations in pore water of the collected sediment. When equilibrium was reached among cadmium in pore water, sediment, and ion-exchange resin, cadmium exchanged onto resin phase was regenerated with 1 N hydrochloric acid (OPTIMA grade) and determined using an atomic absorption spectrophotometer (Zeeman 5000) with a graphite furnace accessory. Cadmium determined using the dialysis sampler is considered as free ...

1998-05-01

8

Analysis of control methods: mercury and cadmium pollution.  

UK PubMed Central (United Kingdom)

Physical system conceptual models are developed to illustrate the various interconnecting pathways of metal flow. Economic use of mercury and cadmium, as representative toxic heavy metals, is inventoried,...Full Text Available

1975-12-01

9

Method of forming solar cells by grid contact isolation  

Energy Technology Data Exchange (ETDEWEB)

A solar cell structure is produced by a method comprising baking the solar cell, containing a gridded top layer of cuprous sulfide formed on a base of cadmium sulfide, for 20 minutes to 10 hours, to produce a copper doped cds electrically insulating region in the cadmium sulfide base near the interface of the cuprous sulfide and the cadmium sulfide; removing the cuprous sulfide, and the copper doped cds insulating region not covered by the grid, to provide a bare cadmium sulfide areas; and then forming a cuprous sulfide layer on the exposed areas not covered by the grid.

1982-03-16

10

Apoferritin Templated Synthesis of Metal Phosphate Nanoparticle Labels for Electrochemical Immunoassay  

Energy Technology Data Exchange (ETDEWEB)

W have introduced template-synthesized metal phosphate nanoparticle labels for electrochemical immunoassay. Such use of an apoferritin template offers a simple and convenient route to prepare metallic nanoparticle labels for electrochemical immunoassays and avoid the complicated and time-consuming nanoparticle synthesis process (QD synthesis). Releasing metal ions from metal phosphate in an acetate buffer (pH 4.6) eliminates the harsh condition in the traditional metallic nanoparticle dissolution (e.g., strong acid dissolution of QDs and gold nanoparticles). This method is ultrasensitive and its DL is low to 77fM. The simultaneous detection of multiple protein targets is easily performed by using different metal phosphate nanoparticle labels (cadmium phosphate and lead phosphate). This approach can be extended to prepare multiple metal (such as zinc, lead, cadmium, copper, indium, gold, silver) phosphate nanoparticle labels ...

2006-08-29

11

Thermal-neutron capture cross section and resonance integral of americium-241  

International Nuclear Information System (INIS)

The thermal-neutron capture cross section (#sigma#_0_,_g) and the resonance integral (I_0_,_g) leading to the ground state of "2"4"2Am were measured by an activation method for neutron capture by "2"4"1Am. A method with gadolinium, which was similar to the cadmium difference method, was used to measure the cross section #sigma#_0_,_g with attention to resonances of "2"4"1Am. Americium chloride samples containing "2"4"1Am radioisotope were irradiated for 68 h in the long-irradiation plug of the Kyoto University Research Reactor, KUR. Wires of Co/Al and Au/Al alloys were used as monitors to determine thermal-neutron fluxes and epithermal Westcott's indexes at the irradiation positions. An #alpha#-ray spectrometer was used to measure the activity ratios of "2"4"2Cm to "2"4"1Am. On the basis of Westcott's convention, the #sigma#_0_,_g and I_0_,_g values were determined as 628#+-#22 b ...

2007-12-01

12

Separation and determination of cadmium and zinc as their thenoyltrifluoroacetone complexes with dibenzo-18-crown-6 by means of synergistic extraction and atomic absorption spectrometry  

Energy Technology Data Exchange (ETDEWEB)

A new method for the separation and determination of trace amounts of cadmium and zinc in water as their thenoyltrifluoroacetone (TTA) complexes with dibenzo-18-crown-6 (DB18C6) in o-dichlorobenzene has been established by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry. The effect of various factors (synergism with TTA and DB18C6, shaking time, composition of the extracted species, and mutual separation etc.) on the extraction and back-extraction of cadmium and zinc has been in- vestigated. When the mixtures were extracted for 4 min at pH 4.9, only zinc was extracted quantitatively, whereas cadmium remained in the aqueous phase. After the phases were separated, cadmium was again extracted quantitatively at pH 7.5. Then, the two phases were each shaken with 0.05-0.1 mol/l HCl in order to back-extract cadmium and ...

1997-01-01

13

Enrichment of trace cadmium by soybean protein for the analysis by atomic absorption method  

International Nuclear Information System (INIS)

A method for enrichment of the ppb level of cadmium in water by using the coagulation of soybean protein by adding acids or its complex-forming character with heavy metal ions was investigated. After adding fixed amounts of soybean milk and 2% sodium diethyldithiocarbamate(DDTC) aqueous solution and a suitable amount of delta-gluconic lactone (delta-GL) to a sample solution, the mixture was heated to boiling in order to coagulate the protein. The coagulum(soybean curd) was separated from the suspension by centrifugation and burned to ashes with a low temperature plasma asher. Then the cadmium enriched in it was determined by atomic absorption spectrometry. Various factors such as the pH of the sample solution, the amounts of soybean milk and the collection additives, and the concentration of NaCl in the sample solution on the recovery of cadmium were examined systematically. The best recovery was ...

1975-01-01

14

Neutron-computer tomography using real-time neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

A real-time neutron radiography facility was constructed including the capability of neutron tomography. The neutron beam was measured for total neutron flux ((1.0 +/- 0.2) x 10/sup 11/ m/(m/sup 2/-sec)), gold cadmium ratio (52 +/- 3) and effective neutron temperature (83/sup 0/C +/- 8/sup 0/C). The angular divergence or nonparallelism of the neutron beam was measured to be 2.3/sup 0/ +/- 0.1/sup 0/ thereby providing a means of quantifying the collimator effectiveness. The resolution capabilities of both static film and real-time neutron radiographs were quantified using a Fourier transform algorithm to calculate the modulation transfer function of both types of radiographs. The contrast sensitivity of both types of radiographs. The contrast sensitivity of both types of radiographs was measured as 3.1% for film and 4.0% for real-time radiographs. Two tomography algorithms, the simultaneous iterative reconstruction technique (SIRT) and the ...

1986-01-01

15

Neutron-computer tomography using real-time neutron radiography  

International Nuclear Information System (INIS)

A real-time neutron radiography facility was constructed including the capability of neutron tomography. The neutron beam was measured for total neutron flux ((1.0 +/- 0.2) x 10"1"1 m/(m"2-sec)), gold cadmium ratio (52 +/- 3) and effective neutron temperature (83"0C +/- 8"0C). The angular divergence or nonparallelism of the neutron beam was measured to be 2.3"0 +/- 0.1"0 thereby providing a means of quantifying the collimator effectiveness. The resolution capabilities of both static film and real-time neutron radiographs were quantified using a Fourier transform algorithm to calculate the modulation transfer function of both types of radiographs. The contrast sensitivity of both types of radiographs. The contrast sensitivity of both types of radiographs was measured as 3.1% for film and 4.0% for real-time radiographs. Two tomography algorithms, the simultaneous iterative reconstruction technique (SIRT) and the convolution ...

1986-01-01

18

Assessment of trace element contents of chicken products from turkey  

Energy Technology Data Exchange (ETDEWEB)

Due to the consumption of chicken and chicken products in Turkey at high ratio, trace metal content of chicken and chicken products from Turkey were determined by atomic absorption spectrometry after microwave digestion. The accuracy of the method was confirmed by analysis of standard reference material (NIST SRM 1577b Bovine liver). Trace element content in various parts of chicken samples and chicken products were to be in the range of 0.10-114 {mu}g/g for copper, 0.25-6.09 {mu}g/kg for cadmium, 0.01-0.40 {mu}g/g for lead, 0.10-0.91 {mu}g/g for selenium, 0.05-3.91 {mu}g/g for manganese, 0.06-0.10 {mu}g/g for arsenic, 0.01-0.72 {mu}g/g for chromium, 0.01-2.08 {mu}g/g for nickel, 0.01-0.02 {mu}g/g for cobalt, 0.10-1.90 {mu}g/g for aluminium, 1.21-24.3 {mu}g/g for zinc, 2.91-155 {mu}g/g for iron. The levels of lead in some analyzed chicken products were higher than the recommended legal limits for human consumption.

2009-04-30

19

The Effect of Contacts on the Counting Characteristics of Heavily Doped Normal-Type Cadmium-Telluride  

Science.gov (United States)

Cadmium telluride single crystals were grown heavily doped with chloride by the THM method. The resulting crystals were n-type with free carrier concentrations of the order of 10('12)/cm at room temperature. Hall effect studies revealed room temperature mobilities between 30 and 350 cm('2)/v-sec and resistivites between 2 x 10('3) and 10('4) ohm-cm. Studies were made of the gamma and alpha counting characteristics of these crystals with metal, metal-semiconductor, and metal-insulator electrodes. It was found that the MIS and MSS structures resulted in significant improvement over the MS structures in counting, signal-to-noise and energy resolution.

1985-01-01

20

Studies of crystalline CdZnTe radiation detectors and polycrystalline thin film CdTe for X-ray imaging applications  

CERN Document Server

The development of a replacement to the conventional film based X-ray imaging technique is required for many reasons. One possible route for this is the use of a large area film of a suitable semiconductor overlaid on an amorphous silicon readout array. A suitable semiconductor exists in cadmium telluride and its tertiary alloy cadmium zinc telluride. In this thesis the spectroscopic characteristics of commercially available CZT X- and gamma-radiation detectors are established. The electronic, optical, electro-optic, structural and compositional properties of these detectors are then investigated. The attained data is used to infer a greater understanding for the carrier transport in a CZT radiation detector following the interaction of a high energy photon. Following this a method used to fabricate large area films of CdTe on a commercial scale is described. This is cathodic electrodeposition from an aqueous electrolyte. ...

2001-01-01

21

Fertilizer amendment for improving the phytoextraction of cadmium by a hyperaccumulator Rorippa globosa (Turcz.) Thell  

British Library Electronic Table of Contents (United Kingdom)

Purpose Two main pathways of phytoremediation of heavy metal-contaminated soils are phytostabilization and phytoextraction. Some soil amendments can strengthen phytostabilization or phytoextraction through either reducing heavy metal bioavailability in soil or increasing the heavy metal accumulation capacity of the hyperaccumulator (enhancing heavy metal concentration or shoot biomass of the hyperaccumulator). Urea and chicken manure are often used as fertilizers. This research will explore their effects on a newly found hyperaccumulator, Rorippa globosa (Turcz.) Thell., phytoremediating cadmium (Cd). Materials and methods Pot culture experiment was conducted to study the accumulation characteristics of R. globosa at different Cd contamination concentrations under one fertilizer level (1?g...

2011-01-01

22

Determination of some minor and trace elements in iron ores by ion exchange chromatography, spectrophotometry and atomic absorption spectrometry  

International Nuclear Information System (INIS)

A method is described for determination of aluminium, cadmium, cobalt, chromium, copper, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, zinc, titanium and vanadium in iron ore. After dissolution, a 1 gram sample of iron ore is applied to a column of AGI-X8 anion exchange resin (chloride form), in 100 ml of 7M HCl. Aluminium, chromium, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, titanium and vanadium are eluted with 7M HCl; iron, copper and cobalt are eluted with 0.5M HCl; cadmium and zinc are eluted with 2M HNO_3. Iron is subsequently removed from copper and cobalt by a solvent extraction with methyl isobutyl ketone. The elements are determined in the eluates by atomic absorption spectrometry, except for titanium and vanadium, which are determined spectrophotometrically.

23

Biosorption of heavy metals on fungal biomass  

Energy Technology Data Exchange (ETDEWEB)

A method of using fungi in removing heavy metal from wastewater was discussed. Fungi for this purpose can be obtained inexpensively, and on a constant basis from industrial fermentation processes. The biosorption of lead, cadmium and nickel on fungal stock cultures, was investigated. In these experiments, the fungal stock used was Aspergillus niger and Rhizopus stolonfier. Alkali pre-treatment of the fungal biomass improved the metal biosorptive capacity in comparison to live cells. The effect of alkali treatment, however, varied,showing highest biosorptive capacity for lead and least for nickel. Results showed that metal biosorption of metallic ions increased with an increase in pH from 3.2 to 4.0. Equilibrium times of five hours were observed for the biosorption of lead and cadmium, while the equilibrium time for nickel was three hours. 10 refs., 3 tabs., 7 figs.

1996-09-01

24

Analytical methods for heavy metals in herbal medicines  

British Library Electronic Table of Contents (United Kingdom)

Abstract Introduction - It is estimated that about 70-80% of the world's population relies on non-conventional medicine, mainly of herbal origin. However, owing to the nature and sources of herbal medicines, they are sometimes contaminated with toxic heavy metals such as lead, arsenic, mercury and cadmium, which impose serious health risks to consumers. It is critical to analyse source materials for heavy metals in order to ensure that their concentrations meet the related standards or regulations limiting their concentrations in herbal medicines. In this review, different analytical methods for analysis of heavy metals in herbal medicines are discussed. Objective - To provide a comprehensive review of the current state of the art in analytical methods used to detect heavy metals in herbal...

2011-01-01

25

X-ray diffraction evaluation of the structural perfection of cadmium telluride single crystals  

Science.gov (United States)

A high degree of structural perfection is an essential requirement for CdTe crystals used as substrates for the epitaxial growth of CdHgTe alloys. Here, a method for the evaluation of the structural perfection of CdTe crystals is proposed which is based on X-ray diffraction measurements using both two-crystal and three-crystal diffractometers (differential version). The method makes it possible to obtain more information on structural perfection both at the crystal surface and within the crystal body.

1988-08-01

26

Apparatus for in situ determination of burnup cooling time and fissile content of an irradiated nuclear fuel assembly in a fuel storage pond  

Energy Technology Data Exchange (ETDEWEB)

A detector head for in situ inspection of irradiated nuclear fuel assemblies submerged in a water-filled nuclear fuel storage pond. The detector head includes two parallel arms which extend from a housing and which are spaced apart so as to be positionable on opposite sides of a submerged fuel assembly. Each arm includes an ionization chamber and two fission chambers. One fission chamber in each arm is enclosed in a cadmium shield and the other fission chamber is unshielded. The ratio of the outputs of the shielded and unshielded fission chambers is used to determine the boron content of the pond water. Correcting for the boron content, the neutron flux and gamma ray intensity are then used to verify the declared exposure, cooling time and fissile material content of the irradiated fuel assembly.

1985-04-09

28

Reduction of cadmium toxicity to green microalga Stichococcus bacillaris by manganese  

Energy Technology Data Exchange (ETDEWEB)

Investigations of cadmium toxicity to microorganisms are now more concerned with the interactions of cadmium with different environmental factors and other metals. The interactions are complex and have not been thoroughly studied yet. Metal interactions may assume the form of synergism characterized by increase in toxicity, but also of antagonism in which one metal reduces the toxicity of another. Apart from cadmium interactions with such toxic metals as mercury and lead, interactions of cadmium with the essential trace elements seem to be very interesting because it has been assumed that algal cells take up cadmium by the system transporting these elements. A previous study showed that cadmium transport into Stichococcus bacillaris cells was inhibited by Mn/sup 2 +/ ions. Thus, it can be supported that there exist some possibilities of using those ions ...

1988-12-01

29

Testing of solar cells for communication satellites  

International Nuclear Information System (INIS)

... cadmium sulfides communications electrons performance testing physical

30

Pyrolysis of dichlorodithiourea cadmium(II)  

Energy Technology Data Exchange (ETDEWEB)

By means of infrared spectroscopy, x-ray diffraction, and differential thermal analysis, the authors investigate the pyrolysis of dichlorodithiourea cadmium, the vapor phase epitaxy of the cadmium sulfide film, and the composition of the solid and gaseous pyrolysis products. Those products are found to include the thiocyanates of guanidine, ammonium, and hydrogen along with cadmium oxides and sulfates and hydrochloric acid.

1987-02-20

31

Electrochemical Solar Energy Converter  

International Science & Technology Center (ISTC)

Elaboration of Electrochemical Solar Energy Converter Incorporating Cadmium Selenide Semiconductor Developed Electrochemically

33

Liquid metal flow measurement by neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd{sub 3}) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).

1996-07-21

34

Liquid metal flow measurement by neutron radiography  

International Nuclear Information System (INIS)

Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd_3) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).

1996-07-01

35

Failure location analysis for tagged reactor assemblies  

Science.gov (United States)

The location of defective LMFBR fuel pins by the determination of gas tag isotopic ratios is discussed. The application of this method to the FFTF Reactor briefly described.

1979-03-01

36

Theory of isomer ratios of shape isomers in heavy ion induced reactions  

Science.gov (United States)

A method for the calculation of excitation functions and isomer ratios, for shape isomers, in heavy ion induced reactions is proposed. The calculated values of excitation functions and isomer ratios agree very well with the experimental values for the reaction /sup 238/U(/sup 11/B, alpha 3n)/sup 242/Am. (auth)

1973-11-12

37

Some lessons learned from the DOE site operator program  

Energy Technology Data Exchange (ETDEWEB)

Performance of electric vehicles (EVs) is being studied in an ongoing Site Operator Program, as part of the Electric and Hybrid Vehicle Program supported by the U.S. Department of Energy (DOE). More than 200 EVs are being operated by Site Operators in various geographical and climatic regions of the United States. Cold-weather operation of EVs is of particular interest. As expected, low temperatures affect a battery`s ability to accept a charge, which decreases EV range and increases operating costs. Battery types other than lead-acid are being evaluated such as nickel-iron, gelled electrolyte lead-acid, nickel-cadmium, and sodium-sulfur. Also, improved methods of collecting EV performance data are being implemented, thermal management systems are being tested, and a prototype ultracapacitor is being tested as a possible alternative to conventional batteries.

1995-01-01

38

Pilot project ''measurement of efficacy'' - biological monitoring of antimony pollution in the Munich test area using a standardized grass culture  

International Nuclear Information System (INIS)

This pilot project was carried out for the purpose of testing methods for active biological monitoring. It covered a period of three years (until September 1994), including two years of exposure. The measurements served to determine pollutant levels in plants used as animal fodder and dust-borne heavy metal concentrations in different sites and, on this basis, to obtain indirect information on human exposure. Among others, the pilot project investigated the suitability of Italian rye-grass as a biological indicator for aluminium, arsenic, cadmium, cobalt, chromium, copper, iron, mercury, magnesium, manganese, nickel, lead, platinum, antimony, titanium, and zinc. (orig./GL).

39

Hydrogen transport and embrittlement in 300 M and AerMet100 ultra high strength steels  

Energy Technology Data Exchange (ETDEWEB)

This paper describes how hydrogen transport affects the severity of hydrogen embrittlement in 300 M and AerMet100 ultra high strength steels. Slow strain rate tests were carried out on specimens coated with electrodeposited cadmium and aluminium-based SermeTel 1140/962. Hydrogen diffusivities were measured using two-cell permeation and galvanostatic charging methods and values of 8.0 x 10{sup -8} and 1.0 x 10{sup -9} cm{sup 2} s{sup -1} were obtained for 300 M and AerMet100, respectively. A two-dimensional diffusion model was used to predict the hydrogen distributions in the SSR specimens at the time of failure. The superior embrittlement resistance of AerMet100 was attributed to reverted austenite forming around martensite laths during tempering.

2010-05-15

40

Heavy metals in Semarang`s urban streams: Spatial distribution and bioindication using the guppy (Lepistes reticulatus)  

Energy Technology Data Exchange (ETDEWEB)

A field survey on cadmium, lead, copper, and zinc was performed in Semarang, the fifth largest city in Indonesia. Water, sediment, and fish samples were collected from 101 grids of 2 x 2 km. The objectives of the study were (1) to identify the spatial distribution of metals in the sediments of the greater Semarang area, (2) to estimate the background concentrations of the metals present in Semarang, (3) to provide a simple tool for deriving standards for metals in the sediment, and (4) to explore the potential use of the guppy (Lebistes reticulatus) as a bioindicator of urban metal pollution. To map the spatial distribution of the metals, concentrations of each metal in sediment were plotted against the corresponding city coordinate. On the basis of these plots, background concentrations of the metals were estimated. A combined pollution index can be derived thereafter by calculating the difference between metals concentrations from a particular grid and their ...

1996-12-31

41

Photocatalytic hydrogen production from solutions of sulfite using platinized cadmium sulfide powder  

Energy Technology Data Exchange (ETDEWEB)

Platinized cadmium sulfide powder suspended in a solution of sodium sulfite produces hydrogen efficiently by visible light. Sulfite ions are oxidized to sulfate and dithionate ions. 4 figures.

1983-09-29

42

Nitrogen nutrient status induces sexual differences in responses to cadmium in Populus yunnanensis  

UK PubMed Central (United Kingdom)

Populus yunnanensis was employed as a model species to detect sexual differences in growth, physiological, biochemical, and ultrastructural responses to cadmium (Cd) stress, nitrogen...Full Text Available

2011-10-01

43

Localization and Toxic Effects of Cadmium, Copper, and Uranium in Azolla1  

UK PubMed Central (United Kingdom)

The storage and distribution of copper, cadmium, and uranium and their effects on ionic contents in roots and shoots of Azolla filiculoides has been studied by x-ray microanalysis....Full Text Available

1988-09-01

44

Cadmium, Lead, and Other Metals in Relation to Semen Quality: Human Evidence for Molybdenum as a Male Reproductive Toxicant  

UK PubMed Central (United Kingdom)

BackgroundEvidence on human semen quality as it relates to exposure to various metals, both essential (e.g., zinc, copper) and nonessential (e.g., cadmium, lead), is inconsistent....Full Text Available

2008-11-01

45

Diffusion Zink Planting of Steels  

International Science & Technology Center (ISTC)

Research on Diffusion Zinc Cladding of Structural Steels, as Well as Their Mechanical and Corrosion Properties to Replace Their Cyanic Cadmium Plating

47

Determination methods of alpha activity ratio  

International Nuclear Information System (INIS)

The three determination methods of alpha activity ration are described, namely geometric progression method, extrapolation method and curve fitting method. The validity of the geometric progression method is demonstrated in the present work. The "2"3"8Pu/("2"3"9Pu + "2"4"0Pu) evaluated by extrapolation method is compared with that by geometric progression method. Also, the "2"3"8Pu/("2"3"9Pu + "2"4"0Pu)evaluated by curve fitting method is compared with that by geometric progression.

48

Tracing Cadmium from Culture to Spikelet: Noninvasive Imaging and Quantitative Characterization of Absorption, Transport, and Accumulation of Cadmium in an Intact Rice Plant1[W][OA]  

UK PubMed Central (United Kingdom)

We characterized the absorption and short-term translocation of cadmium (Cd) in rice (Oryza sativa ‘Nipponbare’) quantitatively using serial images observed with a positron-emitting...Full Text Available

2010-04-01

49

Single-crystalline cadmium telluride anodic oxidation kinetics  

Science.gov (United States)

The authors have determined quantitative characteristics for oxide films forming on (111) surfaces of cadmium telluride single crystals on anodic oxidation in 0.1 M KOH: the constants in the Guenterschulze-Betz equation and the film growth constant, which is 2.4 nm/V, from which the activation energy for cadmium telluride electrooxidation has been calculated.

1988-10-10

50

Cadmium down-regulation of kidney Sp1 binding to mouse SGLT1 and SGLT2 gene promoters: Possible reaction of cadmium with the zinc finger domain of Sp1  

UK PubMed Central (United Kingdom)

Cadmium (Cd) exposure causes glucosuria (glucose in the urine). Previously, it was shown that Cd exposure of primary cultures of mouse kidney cells (PMKC) decreased mRNA levels of the glucose...Full Text Available

2010-05-01

51

Absolute dimensions of unevolved O type close binaries  

Energy Technology Data Exchange (ETDEWEB)

A method is presented to derive the absolute dimensions of early-type detached binaries by combining the observed parameters with results of evolutionary computations. The method is used to obtain the absolute dimensions of nine close binaries. We find that most systems have an initial masss ratio near 1.

1984-03-15

52

Cold fusion method  

International Nuclear Information System (INIS)

In a cold fusion method by electrolysis, a hydrogen occluding material mainly comprising vanadium is used as a material for a negative electrode, and lithium isotopes are incorporated in the material by more than 93%. That is, the ratio of lithium 7 ("7Li) isotope is increased to higher than the natural existent ratio, so that tritium ("3H) concentration in the hydrogen occluding material can be increased, to attain energy at high efficiency. (T.M.).

1993-03-02

53

Blood cadmium concentrations in the general population of Umbria, Central Italy  

Energy Technology Data Exchange (ETDEWEB)

The aims of this study were (a) to assess blood cadmium (B-Cd) concentrations and to establish a tentative reference interval; (b) to identify significant determinants of B-Cd, in a population from Umbria, Central Italy, which was not occupationally exposed to cadmium (Cd). Four hundred and thirty-four healthy blood-donors volunteered to answer a questionnaire and provide a blood sample for B-Cd analysis, which was performed by graphite furnace atomic absorption spectrophotometry. Blood Cd concentrations ranged from non-detectable values, i.e. below 0.1 {mu}g/l up to 3.4 {mu}g/l and were not normally distributed. The median values and the 95th percentiles were 0.7 and 2.0 {mu}g/l, respectively. Concentrations of B-Cd were more than double in smokers than in non-smokers, median values being 1.1 {mu}g/l and 0.5 {mu}g/l, respectively. In current smokers, B-Cd values correlated with the number of cigarettes smoked daily (r{sub s}=0.40, P=0.0001) ...

1999-02-02

54

A method for determining the origin of bitumoids  

Energy Technology Data Exchange (ETDEWEB)

The invention is associated with organic geochemistry and may be used in conducting geological exploration operations for oil and gas. The purpose of the invention is to increase the precision of the method for determining the genesis of bitumoids. This is achieved through determining the isotopic composition of nickel or vanadium and from the anomalously high values of the isotopic ratio of Ni-58 to Ni-62 or from the anomalously low values of the isotopic ratio of vanadium, a conclusion is drawn about the epigenetic nature of the bitumoids. The proposed method is characterized by greater resolution due to the fact that the values of the isotopic ratios for oil bearing and water bearing structures are essentially not superimposed. The proposed method exceeds the resolution of metal metering studies in conducting geological exploration for oil and gas by 2 to 3 ...

1983-01-01

55

In vivo effects of cadmium chloride on certain aspects of protein metabolism in tissues of a freshwater field crab Barytelphusa guerini  

Energy Technology Data Exchange (ETDEWEB)

Heavy metals discharged from industries are a major source of pollution which has become a threat to all forms of life. Among the various heavy metals, cadmium is known to be highly toxic even in low concentrations. The harmful effects of cadmium is attributed to its effects on sulfhydryl groups of enzymes, especially dehydrogenases. Various aspects of cadmium pollution on fishes have been extensively reviewed. A survey of the literature reveals that few attempts have been made to study the various aspects of cadmium toxicity in crustaceans and these studies were mainly devoted to marine forms. The freshwater crustaceans, particularly the freshwater field crab, Barytelphusa guerini, has received little attention. The present study reports the influence of cadmium on certain aspects of protein metabolism in the tissues of a freshwater field crab, Barytelphusa guerini, and important ...

1991-04-01

56

Measurement of inorganic chemical characteristics of biomass ash; Bestimmung anorganisch-chemischer Eigenschaften von Biomasseaschen  

Energy Technology Data Exchange (ETDEWEB)

The ash of biomass fuels was analysed in order to identify its inorganic chemical characteristics. The experiments were carried out using different methods of extraction. The accuracy of the measurements was verified by comparative analyses using certified samples. The composition was shown to vary with the fuel type and ash fraction. In the case of arsenic and the toxic heavy metals cadmium, mercury and lead, accumulation factors of 1.4 to 43 were measured in the tissue filter ash. [German] Fuer die Bestimmung der stofflichen Eigenschaften von Biobrennstoffaschen werden neben der fuer die Ermittlung von Stoffbilanzen notwendigen Analyse der Gesamtgehalte, in Abhaengigkeit von der Zielsetzung und den gesetzlichen Vorgaben, unterschiedliche Extraktionsverfahren eingesetzt. Fuer die Gesamtgehaltsbestimmung wurden aus laborinternen Wiederholungsuntersuchungen sowie einem laborexternen Analysenvergleich Kenngroessen fuer die Praezision und ...

2001-07-01

57

Heavy metals in earthworms of Baden-Wuerttemberg. Part 1. Metal contents in earthworms from long-term forest observation plots; Schwermetalle in Regenwuermern Baden-Wuerttembergs. Teil 1. Metallgehalte in Regenwuermern von Wald-Dauerbeobachtungsflaechen  

Energy Technology Data Exchange (ETDEWEB)

Since 1984 the Environmental Protection Agency (LfU) of the State of Baden-Wuerttemberg has been investigating the heavy metal burden of earthworms from representative long-term forest observation plots. These investigations are aimed at elucidating and assessing adverse effects of pollutants on the soil biocenosis. Methods: At first only lead and cadmium were measured in the worms; in repetitive measurements over the years further metals or metalloid elements such as aluminum, arsenic, chromium, cobalt, copper, manganese, mercury, nickel, thallium, vanadium, and zinc were added to the agenda. Results and conclusion: The frequency distribution of the metals in the earthworms was characterized statistically. For the first time state-wide background values, normal values and threshold values were established for all the elements measured. A comparable study with a similar range of parameters is known neither nationally nor internationally. Time ...

2006-08-15

58

Trace metal characterization of the U-Al matrix by atomic spectroscopy  

International Nuclear Information System (INIS)

Uranium-aluminum alloys with a significant enrichment of uranium with "2"3"3U or "2"3"5U serve as nuclear fuels in research reactors. The quality assurance of this fuel requires, among other things, precise knowledge that all trace metal constituents that affect neutron economy, fuel integrity, and fuel fabrication process parameters are well within the specification limits. Trace metal characterization of "2"3"5U-Al alloy has been carried out by atomic spectrometry. The trace metal constituents of interest are grouped into common metals (silver, boron, calcium, cadmium, cobalt, chromium, copper, iron, magnesium, manganese, molybdenum, sodium, nickel, lead, silicon, tin, titanium, vanadium, tungsten, and zinc) and lanthanides (cerium, dysprosium, europium, gadolinium, holminium, lutetium, samarium, and terbium). The elements yttrium and zirconium are grouped with the latter in view of the chemical separation procedure used. The alloy samples are dissolved in 6 M ...

59

An engineering approach to solid waste collection system: Ibadan North as case study  

International Nuclear Information System (INIS)

This research centered on finding and perfecting methods of collection and disposal of refuse in Ibadan North Local Government Areas. The methodology used included questionnaire administration, personal interviews, field reconnaissance, and biochemical tests of water samples, all aimed at providing useful data for the design of effective methods of collecting and disposing refuse. The local government area was divided into three classes based on resident income: a high-income area (Bodija Avenue, etc.), a medium-income area (Sanngo, Oluyole, etc.), and a low-income area (Beere, Adeoyo, etc.). The research outcomes revealed that the waste generation rate for the local government ranged from 0.2 to 0.33 kg/cap/day and waste density ranged from 172.41 to 217.61 kg/m"3. Water analyses showed that the chloride, manganese, lead, and cadmium levels in water from low-income areas were above the WHO standard. The refuse generated in ...

60

The peak to background method in quantitative ion microprobe analysis of thick biological specimens  

Energy Technology Data Exchange (ETDEWEB)

The use of the ratio of the characteristic intensity to the continuum background intensity (P/B ratio) of the X-ray spectrum for a quantitative ion microprobe (IMP) or PIXE (particle induced X-ray emission) analysis of thin biological specimens was proposed previously. The IMP analysis of thick biological specimens is also of considerable practical use. In this paper, the possibility of using the P/B ratio to quantify minor elements in thick biological specimens is investigated. The epoxy resin based standards with gradual concentrations of KCNS up to 0.6 mol/kg and NBS bovine liver were analyzed by a 27 MeV {alpha} particle microprobe. The measured peak to background ratios (between 4.4 to 5.7 keV) agreed well with the theoretical calculations. The calculations showed that the concentration dependence of the P/B ratios was determined mainly by the absorption of X-rays in specimens. ...

1991-05-01

61

Protective role of selenium against renal toxicity induced by cadmium in rats  

International Nuclear Information System (INIS)

Cadmium is an environmental toxic metal implicated in human diseases. The mechanism of its toxicity is not fully understood. Therefore, the role of cadmium in renal toxicity, and the protective role of selenium against this toxicity were investigated. Forty-five male rats were used through out the study and divided into three groups of 15. The first group received saline solution daily for 10 days. The second group, received cadmium chloride (CdCl_2) (2 mg/kg body weight) intraperitoneally daily for a period of 10 days. The third group, received sodium selenite (1 mg/kg body weight, twice a day) and CdCl_2 (once a day) for a period of 10 days. The results showed that cadmium treatment increased renal lipid peroxidation (measured as malondialdehyde, MDA) which was associated with a significant decrease in the antioxidant systems such as reduced glutathione levels and the activities of glutathione ...

2007-06-25

62

Calculated valence electronic structure of 3d metals for use in the X-ray intensity ratio studies  

Energy Technology Data Exchange (ETDEWEB)

3d occupation numbers of the transition elements corresponding to various types of atomic configurations are calculated by means of the linear muffin-tin orbital (LMTO) method. This data is used with the multiconfiguration Dirac-Fock (MCDF) X-ray intensity ratios to estimate the electron populations of the 3d metals in alloys.

2010-09-15

63

Calculated valence electronic structure of 3d metals for use in the X-ray intensity ratio studies  

International Nuclear Information System (INIS)

3d occupation numbers of the transition elements corresponding to various types of atomic configurations are calculated by means of the linear muffin-tin orbital (LMTO) method. This data is used with the multiconfiguration Dirac-Fock (MCDF) X-ray intensity ratios to estimate the electron populations of the 3d metals in alloys.

2010-09-01

64

Simultaneous determination of dorzolamide HCL and timolol maleate in eye drops by two different spectroscopic methods.  

Science.gov (United States)

Two-component mixtures of dorzolamide hydrochloride and timolol maleate were assayed by first derivative and ratio derivative spectrophotometric methods. The first method, derivative spectrophotometry, by the zero-crossing measurements, was used due to the drugs closely overlapping absorption spectra. Linear calibration graphs of first derivative values at 250.3 nm for dorzolamide hydrochloride and 315.8 nm for timolol maleate. The second method, is based on ratio first derivative spectrophotometry, the amplitudes in the first derivative of the ratio spectra at 242.9 and at 223.5 nm were selected to determine dorzolamide and timolol maleate in the binary mixture. Calibration graphs were established for 8.0-30.0 microg ml(-1) for dorzolamide hydrochloride and 3.0-24.6 microg ml(-1) for timolol maleate in binary mixture. Good linearity, precision and selectivity ...

2002-04-15

65

In vivo effects of cadmium chloride on certain aspects of carbohydrate metabolism in the tissues of a freshwater field crab Barytelphusa guerini  

Energy Technology Data Exchange (ETDEWEB)

Cadmium is a toxic, non-essential heavy metal inhibiting numerous enzymes with functional sulfhydryl groups. Among the animals, aquatic organisms are most sensitive to heavy metals. Various aspects of toxic effects of cadmium pollution on fishes have been extensively reviewed. Survey of literature reveals that relatively few attempts have been made on the various aspects of cadmium toxicity in crustaceans and these studies were mainly devoted to marine forms. The freshwater crustaceans, particularly the freshwater field crab, Barytelphusa guerini, received less attention. This crab forms one of the major components of the paddy field ecosystem and has an edible importance among local populations. Apart from this, these crabs are easily available, maintainable in the laboratory and data obtained in this study can be extrapolated to other crustaceans. The present study reports the influence of cadmium on ...

1989-06-01

66

Health-hazard evaluation report HETA 85-354-1872, Asarco, Denver, Colorado  

Science.gov (United States)

An evaluation was made of possible hazardous working conditions at the ASARCO Globe facility, Denver, Colorado. The facility was involved in the recovery of cadmium from baghouse dust, a waste byproduct of nonferrous smelters. A medical study of kidney function was conducted in 45 current or former cadmium production workers; results were compared to those for 35 hospital workers. Kidney abnormalities were more common and more severe in the cadmium workers than in the hospital workers. Abnormalities of proximal tubular function included reduced reabsorption of beta-2-microglobulin, retinol binding protein, calcium and phosphate. Glomerular dysfunction was evidenced as elevated serum creatinine. As length of exposure to cadmium increased, changes became more apparent in workers. No reversal of the conditions was noted in workers who had ceased to be exposed to cadmium some time ...

1988-02-01

67

Measurement of K x-ray intensity ratio of tin, gadolinium and dysprosium  

International Nuclear Information System (INIS)

Full text: Measurement of K_#beta# to K_#alpha# x-ray intensity ratios are important not only in the field of atomic physics, radiation physics and medical physics, but also to test the validity of assumptions made in the theoretical prediction. The intensity ratios can also give information on the effect of physical and chemical environment of the element in the compound. Many investigators have adopted a single and double reflection geometries to measure the K_#beta# to K_#alpha# x ray intensity ratios to understand the effect of physical and chemical environment on x-ray fluorescence. The targets are excited by a radioactive source of having activity of the order 100 MBq. in order to carry out accurate measurement K_#beta# to K_#alpha# x-ray intensity ratios, we have develop 2#pi# geometrical configuration method : placing a target right on the surface of the detector facing the ...

2003-11-01

68

Plasmid-conferred tetracycline resistance confers collateral cadmium sensitivity to E. coli cells  

Energy Technology Data Exchange (ETDEWEB)

E. coli HB101 cells transformed to tetracycline resistance with the plasmids pMB9 or pBR322 display a 10/sup 5/-10/sup 6/-fold lower plating efficiency on agar containing 440 ..mu..M CdCl/sub 2/ than nontransformed cells. When DNA is inserted into the BamH1 site of the plasmid tet gene, or when DNA spanning the BamH1 site is deleted, tetracycline resistance and cadmium hypersensitivity are both lost. In contrast, insertion of DNA into the ampicillin resistance gene does not affect cadmium hypersensitivity.

1982-01-01

69

Cadmium and endrin toxicity to fish in waters containing mineral fibers  

Energy Technology Data Exchange (ETDEWEB)

Taconite tailings and their component asbestiform minerals in Lake Superior water had no demonstrable effect on the chronic toxicity of cadmium to the flagfish, Jordanella floridae. Maximum acceptable toxicant concentrations determined in life cycle tests, where effects on survival, growth, reproduction, and bioconcentration were used as endpoints, were between 3.3 to 7.4, 3.0 to 6.5, and 3.4 to 7.3 micrograms cadmium/liter at 0.004, 0.08, and 0.95 mg/liter taconite tailings concentrations, respectively.

1982-05-01

70

Experimental and theoretical analysis of compression ratio on Otto-cycle engines. Pt. 1  

Energy Technology Data Exchange (ETDEWEB)

The increase of the compression ratio of Otto carburator engines up to epsilon = 14 was investigated by Audi in its research department at Neckarsulm. The results are presented in three partial reports. Part one describes the Audi fuel method and demonstrates the effects of the main parameters. Part two shows the influence of the current on the combustion by the help of a new measuring method developed by the Institut fuer Physikalische Elektronik at Stuttgart University. Part three provides a theoretical analysis of the data gained in the investigations.

1982-01-01

71

A radiant temperature numerical method for laser-plasma diagnostic using SXRSC with absorption method  

International Nuclear Information System (INIS)

An numerical method was developed for measuring radiant temperature using a set of absorption-foils coupled to soft x ray streak camera, SXRSC, in laser plasma experiments. An numerical code, SCC, was given. An x-ray intensity ratio vs temperature was calculated for Parylene, C_3H_6, Mylar and Aluminium. A suitable range of the measuring temperature was discussed to some absorber.

1990-01-01

73

Optical and Structural Characteristics of Heavily Boron ...  

Science.gov (United States)

... Abstract : Cadmium telluride single crystals were subjected to multiple-energy boron ion implants with total doses up to 1.5 x 10 sq cm. ...

1988-05-24

75

Cadmium inhibits neurogenesis in zebrafish embryonic brain development  

International Nuclear Information System (INIS)

Cadmium is a non-essential heavy metal found abundantly in the environment. Children of women exposed to cadmium during pregnancy display lower motor and perceptual abilities. High cadmium body burden in children is also related to impaired intelligence and lowered school achievement. However, little is known about the molecular and cellular basis of developmental neurotoxicity in the sensitive early life stages of animals. In this study, we explore neurological deficits caused by cadmium during early embryonic stages in zebrafish by examining regionalization of the neural tube, pattern formation and cell fate determination, commitment of proneural genes and induction of neurogenesis. We show that cadmium-treated embryos developed a smaller head with unclear boundaries between the brain subdivisions, particularly in the mid-hindbrain region. Embryos display normal anterior to ...

2008-05-01

76

Pulse Rise Time Characterization of a High Pressure Xenon Gamma Detector for use in Resolution Enhancement  

CERN Document Server

High pressure xenon ionization chamber detectors are possible alternatives to traditional thallium doped sodium iodide (NaI(Tl)) and hyperpure germanium as gamma spectrometers in certain applications. Xenon detectors incorporating a Frisch grid exhibit energy resolutions comparable to cadmium/zinc/telluride (CZT) (e.g. 2% (at) 662keV) but with far greater sensitive volumes. The Frisch grid reduces the position dependence of the anode pulse risetimes, but it also increases the detector vibration sensitivity, anode capacitance, voltage requirements and mechanical complexity. We have been investigating the possibility of eliminating the grid electrode in high-pressure xenon detectors and preserving the high energy resolution using electronic risetime compensation methods. A two-electrode cylindrical high pressure xenon gamma detector coupled to time-to-amplitude conversion electronics was used to characterize the pulse rise time of deposited gamma ...

2000-01-01

77

Metal cation inhibitors for controlling denting corrosion in steam generators. Final report. [PWR  

Science.gov (United States)

Metal cations of arsenic, antimony, tin, manganese, zinc, cadmium, indium, and thallium have been evaluated in a preliminary way as possible3 inhibitors for controlling denting corrision observed in steam generators used with pressurized water reactors (PWR). The rationale for this approach was based upon the well-known inhibition effects of metal cations on corrosion rates in electrolyte/metal systems. A review of corrosion inhibition by metal cations (H. Leidheiser, Jr., Corrosion 36, 339 (1982)) has identified eleven inhibition mechanisms. The major test methods used for this evaluation were: (1) Isothermal capsule tests of carbon/steel/Inconel 600 tube bulging rates at temperatures up to 288/sup 0/C in seawater/copper-nickel chloride bulge-accelerating solutions. (2) Immersion weight-loss tests of steel coupled to Inconel 600 in boiling (102/sup 0/C) 3% sodium chloride solutions. In addition, electrochemical measuremens and surface analyses ...

1982-12-01

78

Measuring instrument for radiometric monitoring of solids and heavy metals in water  

International Nuclear Information System (INIS)

A combination of measuring instruments, consisting of a Beta-Sedimeter and a radionuclide X-ray fluorescence instrument, is described. With the Beta-Sedimeter the C-14-radiation is measured. Through direct irradiation with photons of a Pu238-source in an ancillary irradiation chamber and energy dispersing measurement of the K- and L-radiation resp. of the excited heavy metals with the aid of a Si(Li)-semiconductor detector and a 4-channel analyzer the heavy metal concentrations of the heavy metals Zn, Cr, Ni and Pb are determined. For the determination of cadmium the indirect excitation with Am-241 and Dy-targets is described. The system produces records and operates fully automatically in a step-by-step mode with a testing cycle of 45 minutes. In connection with the process monitoring of the wastewater from a zinc plating plant during a period of 8 months the concentration of the solid material and of the metals Cr and Zn, which were considered to be ...

1979-01-01

79

Assessment of interference in biosorption of a heavy metal  

Energy Technology Data Exchange (ETDEWEB)

Biosorption of heavy metals by various biological materials has been studied extensively in the last decade due to its potential particularly in wastewater treatment. The presence of a large number of metals in industrial metal-bearing solutions makes it necessary to investigate their effect on the final metal uptake by individual biosorbent materials. Nonliving biomass of Sargassum, a brown marine alga, is capable of binding more than 10% of its dry weight in toxic cadmium ions. Although ubiquitous iron interferes with Cd uptake, only approximately 4.5% of it is sequestered (biomass dry weight). Biosorption of both metals at pH 4.5 could be described by Langmuir-type isotherms with b, the affinity-related coefficient (Cd: b = 0.015; Fe: b = 0.027). The interference of Fe with Cd uptake, and vice versa, was assessed by deriving three-dimensional equilibrium two-metal sorption isotherm surfaces, smoothed and cut to reveal the inhibition effect of Fe on biosorption ...

1997-05-20

80

Root-to-shoot Cd translocation via the xylem is the major process determining shoot and grain cadmium accumulation in rice  

UK PubMed Central (United Kingdom)

Physiological properties involved in divergent cadmium (Cd) accumulation among rice genotypes were characterized using the indica cultivar ‘Habataki’ (high Cd in grains)...Full Text Available

2009-07-01

81

Peculiarity of counterion - polyion interactions in aqueous solutions of copolymers of acrylamide with cadmium acrylate  

Energy Technology Data Exchange (ETDEWEB)

Binding of Cd/sup 2 +/ ions in aqueous solutions of statistical copolymers of acrylamide with cadmium acrylate with different content of ionogenic groups in copolymers was investigated by polarography, conductometry, viscometry and dialysis. It is shown that the degree of binding of Cd/sup 2 +/ ions increases with increasing of the content of ionogenic groups in the copolymer and with decreasing of ionic strength of the solution. The values of the degree of binding of Cd/sup 2 +/ ions obtained by polarography and dialysis show satisfactory agreement.

1984-02-01

82

A System-Based Comparison of Gene Expression Reveals Alterations in Oxidative Stress, Disruption of Ubiquitin-Proteasome System and Altered Cell Cycle Regulation after Exposure to Cadmium and Methylmercury in Mouse Embryonic Fibroblast  

UK PubMed Central (United Kingdom)

Environmental and occupational exposures to heavy metals such as methylmercury (MeHg) and cadmium (Cd) pose significant health risks to humans, including neurotoxicity. The underlying mechanisms of...Full Text Available

2010-04-01

83

Reliable dates for the last 50.000 years; Des dates fiables pour les 50 000 dernieres annees  

Energy Technology Data Exchange (ETDEWEB)

The accuracy of the carbon 14 dating method is dependent on the fluctuations of carbon 14 in the atmosphere over long periods of time. Fossil corals that are dated by both carbon 14 and uranium-thorium methods allows the setting of calibration curves for the carbon 14 method for the last 50.000 years. The uranium-thorium method is based on the measurement of the ratio of 2 isotopes: thorium 230 and uranium 234 that are both present in the decay chain of uranium 238. (A.C.)

2004-03-01

84

Results of Am isotopic ratio analysis in irradiated MOX fuels  

Energy Technology Data Exchange (ETDEWEB)

For analysis of a small quantity of americium, it is necessary to separate from curium which has similar chemical property. As a chemical separation method for americium and curium, the oxidation of americium with pentavalent bismuth and subsequent co-precipitation of trivalent curium with BIP O{sub 4} were applied to analyze americium in irradiated MOX fuels which contained about 30wt% plutonium and 0.9wt% {sup 241}Am before irradiation and were irradiated up to 26.2GWd/t in the experimental fast reactor Joyo. The purpose of this study is to measure isotopic ratio of americium and to evaluate the change of isotopic ratio with irradiation. Following results are obtained in this study. (1) The isotopic ratio of americium ({sup 241}Am, {sup 242m}Am and {sup 243}Am) can be analyzed in the MOX fuels by isolating americium. The isotopic ratio of {sup 242m}Am and {sup 243}Am increases up ...

1997-04-01

85

Catalytic activity of hydrophobic Pt/C/PTFE catalysts of different PTFE content for hydrogen-water liquid exchange reaction  

International Nuclear Information System (INIS)

10%Pt/C catalysts were prepared by liquid reduction method. PTFE and Pt/ C catalysts were adhered to porous metal and hydrophobic Pt/C/PTFE catalysts were prepared. The structure and size of Pt crystal particles of Pt/C catalysts were analyzed by XRD, and their mean size was 3.1 nm. The dispersion state of Pt/C and PTFE was analyzed by SEM, and they had good dispersion mostly, but PTFE membrane could be observed on local parts of Pt/C/PTFE surface. Because of low hydrophobicity, Pt/C/ PTFE catalysts have low activity when the mass ratio of PTFE and Pt/C is 0.5: 1, and their catalytic activity increases markedly when the ratio is 1:1. When the ratio increases again, more Pt active sites would be covered by PTFE and interior diffusion effect would increase, which result in the decrease of catalytic activity of Pt/C/PTFE. By PTFE pretreatment of porous metal carrier, the activity of Pt/C/PTFE catalysts ...

2007-09-01

86

Passive solar design handbooks: Vol III: passive solar design analysis and supplement  

Energy Technology Data Exchange (ETDEWEB)

This book applies the Los Alamos Solar Load Ratio (SLR) method to the design of passive solar heating systems, with an emphasis on the average annual heating energy consumption. Recommendations are given on minimizing heating energy consumption by appropriate choices of conservation level and solar system parameters. Analytical methods and supporting tables are presented which enable simple, fast estimates of the heating energy consumption as part of the design process. Topics considered include SLR correlations, the load collector ratio (LCR) method, sensitivity data, cooling considerations, conservation formulas, design procedure, life-cycle costs, high-mass direct gain buildings, low-mass sun-tempered buildings, sunspaces, off-reference night insulation, correlation equations, and mixed systems.

1983-01-01

87

Use of carbon stable isotope to investigate chloromethane formation in the electrolytic dechlorination of trichloroethylene  

International Nuclear Information System (INIS)

Carbon stable isotope trichloroethylene ("1"3C TCE) was used to investigate the formation of chloromethane (CM) during the electrolytic dechlorination of trichloroethylene (TCE) at a granular-graphite packed cathode. A method was developed to use a conventional GC/MS to analyze and quantify regular and "1"3C TCE and their dechlorination products. The concentration of a "1"3C compound can be calculated, based on the concentration of its regular counterpart, from the response ratio of two fragments of different mass per charge values from the compounds in a sample and two characteristic MS spectrum ratios: one is the response ratio of the two fragments of the regular compound, and the other is the response ratio of the corresponding fragments of the regular and "1"3C compounds at the same concentrations. The method was used to analyze the regular and "1"3C ...

2007-03-22

88

Evaluation of femoral head perfusion by dynamic MRI  

International Nuclear Information System (INIS)

The purpose of this study was to evaluate the usefulness of dynamic MRI for femoral head perfusion. Objects were 64 femoral heads of 44 normal cases (20-95 years old), 10 cases (33-90 y) of femoral neck fracture and 8 cases (61-86 y) using steroid due to articular rheumatism, nephrosis and other diseases. Siemens 1.0 T Magneton Impact with body array coil was used for dynamic MRI by the fast low-angle shot 2D method for every 17 sec interval. Gd-DTPA was injected intravenously. ROI was defined in the center of femur head and of trochanter to monitor their values for the dynamic curve. Evaluation was done on the ratio of enhancement ratio (ER) in the head/trochanter and on the curve in both heads. In normal cases, the head ER was significantly lower in >60 years old cases. There was neither significant correlation between their head/trochanter ER ratios nor significant difference between their dynamic ...

1998-05-01

89

Calcination of Fluorinel-sodium waste blends using sugar as a feed additive (formerly WINCO-11879)  

Energy Technology Data Exchange (ETDEWEB)

Methods were studied for using sugar as a feed additive for converting the sodium-bearing wastes stored at the Idaho Chemical Processing Plant into granular, free flowing solids by fluidized-bed calcination at 500{degrees}C. All methods studied blended sodium-bearing wastes with Fluorinel wastes but differed in the types of sugar (sucrose or dextrose) that were added to the blend. The most promising sugar additive was determined to be sucrose, since it is converted more completely to inorganic carbon than is dextrose. The effect of the feed aluminum-to-alkali metal mole ratio on calcination of these blends with sugar was also investigated. Increasing the aluminum-to-alkali metal ratio from 0.6 to 1.0 decreased the calcine product-to-fines ratio from 3.0 to 1.0 and the attrition index from 80 to 15%. Further increasing the ratio to 1.25 had no effect.

1992-06-01

90

A method of producing a stabilizer of wash drilling muds  

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for producing a stabilizer of wash drilling muds; by hydrolysis of polyacrylonitrile in an aqueous solution of alkaline agent with heating. To raise the heat resistance of the stabilizer, as the alkaline agent is used monosilicate of sodium, while the hydrolysis is done at a molar ratio of polyacrylonitrile, sodium monosilicate and water equal to 1.0:0.7-2.5:100, to a degree of hydrolysis of 25-40.

1981-01-01

91

Radioanalytical study of the chromate conversion coating formed on aluminium  

Energy Technology Data Exchange (ETDEWEB)

Phosphate/chromate and accelerated chromate coatings were produced on commercially available aluminium. The Cr, P and Fe components of the conversion coatings were determined by radioactive tracer technique. The tracer technique was combined with ion-exchange and film-sectioning methods to determine the chromium(III)/total chromium ratio in the accelerated chromate coating. It was found that during the acidic dissolution of the conversion coating the chromium(III)/total chromium ratio may suffer changes. The film-forming components in the metal/bath interface are supersaturated and deposited onto the aluminium. The identified components of the accelerated chromate coatings are Cr(OH)sub(3), Cr(OH)CrOsub(4) and Crsub(4)(Fe(CN)sub(6))sub(3) and the chromium(III)/total chromium ratio was found to be cca. 2/3. (author). 11 refs.; 5 figs.

1985-09-16

92

Method of constraint loss correction of CTOD fracture toughness for fracture assessment of steel components  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a procedure for transferring the CTOD fracture toughness obtained from laboratory specimens to an equivalent CTOD for structural components, taking constraint loss into account. The Weibull stress criterion is applied to correct the CTOD for constraint loss, which leads to an equivalent CTOD ratio, b, defined as b=d/dWP, where d and dWP are CTODs of the standard fracture toughness specimen and the structural component, respectively, at the same level of the Weibull stress. The CTOD ratio b is intended to apply to the fracture assessment of ferritic steel components to stress levels beyond small-scale yielding. Nomographs are given to determine the b-value as a function of the crack type and size in the component, the yield-to-tensile ratio of the material and the Weibul...

2006-01-01

93

Characterization of humic acids extracted from mined lignite and from their oxidation products  

Energy Technology Data Exchange (ETDEWEB)

An oxidative method for enriching the content of humic acids in a mined lignite from Umbria (central Italy) is described. A mild oxidation using H{sub 2}O{sub 2} in an alkaline medium was successful in increasing the percentage of lignite-derived humidifed carbon from 5.77% to 33.67%. The newly formed humic acids showed a higher number of oxygen-bearing functional groups, a lower carbon/oxygen ratio and a higher absorbance ratio at 465 and 665 nm (E{sub 4}/E{sub 6}) in diluted solution compared to the native lignite-derived humic acids. A high E{sub 4}/E{sub 6} ratio indicated less condensation of the aromatic nucleus and a lower molecular weight in comparison to the lignite-derived native humic acids.

1999-05-01

94

A study of the isomeric ratio for the (n,2n) and (#betta#,n) reactions in Mo92, Zr90, Sr86 and Se74  

International Nuclear Information System (INIS)

Measurements are made of the isomeric ratio for the (n,2n) and (#betta#,n) reactions on the neutron-deficient nuclei _9_2Mo, _9_0Zr, _8_6Sr and _7_4Se. A method is developed for calculating the isomeric ratio for a low excitation energy of the residual nucleus. The good agreement found between experimental results and calculations for the (#betta#,n) reaction confirms the choices of residual nucleus characteristics, transmission coefficients of neutrons emitted etc. used in the calculations. The results of a study of the (n,2n) reaction were used to find the spin dependences of nuclear level density in the excitation energy region approx. 14 MeV. (author).

1998-10-01

95

Method and apparatus for operation of a dual fuel compression ignition combustion engine  

Energy Technology Data Exchange (ETDEWEB)

A dual fuel engine control system for controlling the power output of a dual fuel compression ignition engine. The engine includes mixing means for combining an oxidizer and a primary fuel at a substantially constant ratio of oxidizer to primary fuel. The power output of the engine is controlled through the use of a throttle valve controlling the quantity of combustible mixture delivered to the combustion chamber. The fuel control system minimizes the quantity of ignition fuel required by controlling the quantity of combustible mixture rather than the fuel of air ratio. (author) figs.

1994-03-03

96

Continuum background suppression using various selectors  

International Nuclear Information System (INIS)

Continuum events represent an eminent source of background in any e+e- experiment. As these have a higher branching ratio than BB-bar events (at BaBar this ratio is estimated to about 3.5) or ?+?- events, efficient continuum background suppression is essential in many analyses. Using Artificial Neural Networks and the Nearest Neighbor Method we developed several selectors which, based only on the global event shape variables, efficiently tag BB-bar events and ?+?- events against the continuum background. These selectors could then be combined with the channel specific information in various types of analyses. The study was done using a parametric Monte Carlo.

1999-10-04

97

Recursive distribution method for probabilistic fracture mechanics and its application to evaluation of LWR piping  

Energy Technology Data Exchange (ETDEWEB)

The present authors have previously developed a new method for Probabilistic Fracture Mechanics (PFM), which they call Recursive Distribution (RD) method. The method is based on the construction of the Lebesgue-Stieltjes measure through a deterministic mapping defining a crack growth process. In the present paper, its theoretical background is first discussed, and the Lebesgue decomposition of the measure is given. Then a numerical example of a Light Water Reactor (LWR)`s piping problem is solved by the present method, and the results are compared with those of the Monte Carlo (MC) method. In addition to leakage probability, a variation in stress cycles of the marginal distribution of an aspect ratio of a semi-elliptical surface crack is calculated, which will be used in a study on LBB evaluation.

1996-12-01

98

Detection and classification of bearing flaking using kullback discrimination information; Kullback shikibetsu johoryo (KDI) wo mochiita jikuuke no tendomen hakuri no kenchi to shikibetsu  

Energy Technology Data Exchange (ETDEWEB)

Since bearing is in wide use as basic parts for rotary machines, detection and diagnosis of its defects are important in practical use. To discriminate defect portions by early detection of roller bearing flaking, the conventional parameter method using peakedness is poor. Thus to directly obtain difference in waveform, the new method was applied to such detection which uses KDI as the scale of a difference in waveform, and a most neighborhood classification rule based on KDI. The detection and discrimination abilities of this method was studied mainly in experiment. The experiment used a bench scale rotor and a supporting bearing, and attempted detection and discrimination of no flaking, outer ring flaking and inner ring flaking. As a result, this method could detect and discriminate fine flaking which was never detected by conventional method. Since selection of standard data is ...

1998-06-15

99

Outage Probability of Diversity Combining Receivers in Arbitrarily Fading Channels  

CERN Document Server

We propose a simple and accurate method to evaluate the outage probability at the output of arbitrarily fading L-branch diversity combining receiver. The method is based on the saddlepoint approximation, which only requires the knowledge of the moment generating functions of the signal-to-noise ratio at the output of each diversity branch. In addition, we show that the obtained results reduce to closed-form expressions in many particular cases of practical interest. Numerical results illustrate a very high accuracy of the proposed method for practical outage values and for a large mixture of fading and system parameters.

2011-01-01

100

Application of wavelet analysis to signal processing methods for eddy-current test; ueburetto kaiseki no kadenryushinshoho heno tekiyo  

Energy Technology Data Exchange (ETDEWEB)

This study deals with the application of wavelet analysis to detection and characterization of defects from eddy-current and ultrasonic testing signals of a low signal-to-noise ratio. Presented in this paper are the methods for processing eddy-current testing signals of heat exchanger tubes of a steam generator in a nuclear power plant. The results of processing eddy-current testing signals of tube test pieces with artificial flaws show that the flaw signals corrupted by noise and/or non-defect signals can be effectively detected and characterized by using the wavelet methods. (author)

1998-12-15

101

Long-distance transport, vacuolar sequestration, tolerance, and transcriptional responses induced by cadmium and arsenic  

British Library Electronic Table of Contents (United Kingdom)

Iron, zinc, copper and manganese are essential metals for cellular enzyme functions while cadmium, mercury and the metalloid arsenic lack any biological function. Both, essential metals, at high concentrations, and non-essential metals and metalloids are extremely reactive and toxic. Therefore, plants have acquired specialized mechanisms to sense, transport and maintain essential metals within physiological concentrations and to detoxify non-essential metals and metalloids. This review focuses on the recent identification of transporters that sequester cadmium and arsenic in vacuoles and the mechanisms mediating the partitioning of these metal(loid)s between roots and shoots. We further discuss recent models of phloem-mediated long-distance transport, seed accumulation of Cd and As and rec...

2011-01-01

102

Lead, cadmium, chromium, cobalt, and copper in chicken feathers from Tuskegee, Alabama  

Energy Technology Data Exchange (ETDEWEB)

The feather has been widely used as a indicator tissue of metal exposure in birds. The feathers were collected from Tuskegee University poultry farm (TUPF) and Harrison Poultry farm (HPF) chicken and analyzed by Inductively Coupled Plasma Atomic Emission Spectroscopy for lead, cadmium, cobalt, chromium, and copper contaminations. The mean levels of lead, cadmium, cobalt, chromium, and copper in TUPF chicken were 3.67, 0.13, 12.23, 0.22, and 7.71 ppm, respectively, and in HPF chicken were 5.32, 0.096, 11.03, 0.15, and 8.06 ppm, respectively. The mean levels of these metals did not show any significant difference between TUPF and HPF chicken.

1994-12-31

103

Canadian soil quality criteria for lead, copper, arsenic, cadmium and mercury  

Energy Technology Data Exchange (ETDEWEB)

National soil quality criteria for the protection of ecological receptors, including livestock and wildlife, are currently under development in Canada. Based on an evaluation of direct soil contact and soil and food ingestion pathways for sensitive species, soil quality criteria for lead, copper, arsenic, cadmium and mercury for three land use categories have been derived. The draft values, in mg/kg soil, for agricultural, residential/parkland, commercial/industrial land uses are: mercury, 4, 4, 30; copper, 62, 62, 100; cadmium, 10, 10, 27; lead, 70, 250, 400; arsenic, 17, 17, 26. Critical data requirements in developing soil quality criteria are also reviewed.

1995-12-31

104

A clinical assessment of the relationship between bone scintigraphy and serum biochemical markers in hemodialysis patients  

International Nuclear Information System (INIS)

Renal osteodystrophy is a metabolic bone disease and a common complication of end-stage chronic renal failure and maintenance dialysis treatment. In this study, we examined the correlation between quantifying bone scintigraphy and serum biochemical markers in hemodialysis patients. Bone scintigraphy with technetium-99m-hydroxy-methylene-diphosphonate ("9"9"mTc-HMDP) was performed on 28 patients on maintenance hemodialysis. Bone scintigraphy was performed using a standard protocol and was quantified by setting regions of interest (ROIs) over selected regions. The bone-to-soft-tissue ratio (B/ST ratio) at each region was calculated in all patients. The B/ST ratios were then compared with serum biochemical markers. The B/ST ratio for the skull correlated well with serum bone-specific alkaline phosphatase (BAP) (r=0.735, p<0.001), serum deoxypyridinoline (DPD) (r=0.806, p<0.001) and intact parathyroid ...

2004-09-01

105

Micromachining of CVD diamond films using a focused ion beam  

Energy Technology Data Exchange (ETDEWEB)

Grooving CVD diamond films using a focused ion beam (FIB) to quarry micro parts is described. The substrate-side surface of a polycrystalline diamond film which is prepared by means of microwave plasma CVD, is able to be grooved by a focused Ga ion beam scanned straight repeatedly. The groove has cross section whose shape is like an inverted Gaussian distribution curve. And the surface roughness of the films before grooved influences that of grooves. Under the same irradiation conditions, deeper, narrower, in short, high aspect ratio grooves are obtained on B-doped semiconducting microwave plasma CVD diamond films. Coating electrical conductive material is also effective method to obtain high aspect ratio grooves. It is supposed that these results are due to the degree of electrification on the surface and that FIB irradiation is a suitable method for micromachining semiconducting diamond films.

1995-12-31

106

Method of manufacture of blast furnace cokes containing substantial amounts of low grade coals  

Science.gov (United States)

Blast furnace coke containing low grade coal in a high blending ratio is manufactured by a method which comprises blending not less than 60% of a blended coal having an adjusted total moisture content of not more than 4% with not more than 40% of briquettes and carbonizing the resultant mixture. The blended coal consists essentially of not less than 80% of coking coal and not more than 20% of low grade coal. When coking coal of a kind which has its coking property segregated according to its grain size distribution is pulverized and classified by sifting and the portion of fine particles is used as mixed with the coking coal, the blending ratio of the low grade coal in the blended coal can be increased to up to 35%. The briquettes consist essentially of not less than 10% of coking coal and not more than 90% of low grade coal.

1982-03-09

107

Measurement of the ratio of liquid to solid phases in a continuous ingot  

International Nuclear Information System (INIS)

A radiometric method of measuring the ratio of liquid and solid phases (crust thickness) in a continuous ingot for automation of the continuous steel casting process, has been proposed. The essence of the method is, that radiation flux, bearing information on the object tested, is transformed in a succession of electric pulses, which is processed afterwords for obtaining necessary information. In this case either the flux of non-scattered radiation, passed through the object, or the flux of single-scattered radiation reflected from the object is registered. Block-diagram and specifications of a radiometric device with the Co source of 50 gxequiv. Ra activity developed for this purpose are presented. The technique for calibration ob the device and the results of its tests, are described. It is shown, that introduction of such devices for the control crust thickness at the installations of continuous steel casting of ...

108

Cloud-point measurement for (sulphate salts + polyethylene glycol 15000 + water) systems by the particle counting method  

International Nuclear Information System (INIS)

The phase separation of (water + salt + polyethylene glycol 15000) systems was studied by cloud-point measurements using the particle counting method. The effect of three kinds of sulphate salt (Na2SO4, K2SO4, (NH4)2SO4) concentration, polyethylene glycol 15000 concentration, mass ratio of polymer to salt on the cloud-point temperature of these systems have been investigated. The results obtained indicate that the cloud-point temperatures decrease linearly with increase in polyethylene glycol concentrations for different salts. Also, the cloud points decrease with an increase in mass ratio of salt to polymer.

2009-07-01

109

Valence electronic structure of Ni in Ni-Si alloys from relative K X-ray intensity studies  

Energy Technology Data Exchange (ETDEWEB)

The K{beta}-to-K{alpha} X-ray intensity ratio of Ni in Ni{sub 3}Si, Ni{sub 2}Si and NiSi has been determined by energy dispersive X-ray fluorescence technique. It is found that the intensity ratio of Ni decreases from pure Ni to Ni{sub 2}Si and then increases from Ni{sub 2}Si to NiSi, in good agreement with the electronic structure calculations cited in the literature. We have also performed band structure calculations for pure Ni in various atomic configurations by means of linear muffin-tin orbital method and used this data with the normalized theoretical intensity ratios cited in the literature to estimate the 3d-occupation numbers of Ni in Ni-Si alloys. It is emphasized that investigation of alloying effect in terms of X-ray intensity ratios should be carried out for the stoichiometric alloys in order to make reliable and quantitative comparisons between theory and experiment in ...

2007-02-15

110

Determination of trace amounts of cadmium, cobalt, chromium, iron, molybdenum, nickel, selenium, titanium, vanadium and zinc in blood and milk by neutron activation analysis  

International Nuclear Information System (INIS)

The concentrations of Cd, Co, Cr, Fe, Mo, Ni, Se, Ti, V and Zn in biological fluids, human blood serum and market milk were determined by neutron activation analysis, with enrichment by coprecipitation. The pre-concentration of these trace elements was accomplished by converting the dissolved trace metal ions into their pyrrolidinedithiocarbamate (1-pyrrolidinecarbodithioate) chelates, followed by coprecipitation with a metal carrier such as Ni, Pb or Bi. The coprecipitation was carried out prior to irradiation for the short-lived nuclides (V, Ti and Se) and after irradiation for the other elements. The validity of the method was checked using certified biological reference materials; the concentrations of trace elements found by the proposed method agreed well with the published certified data. The limits of detection for Cd, Co, Cr, Fe, Mo, Ni, Se (obtained through the long-lived isotope "7"5Se) and Zn under the present experimental ...

111

Use of surface affinity enrichment and cryo-embedding to prepare in vitro reconstituted mitotic chromosomes for EM tomography  

Energy Technology Data Exchange (ETDEWEB)

We present a novel preparation method for studies of in vitro reconstituted mitotic chromosomes from Xenopus laevis egg extracts. This method involves a gentle adsorption of chromosomes from the extracts using surface affinity enrichment, followed by plunge freezing, freeze-substitution and cryo-embedding before examination by EM tomography. For comparison, chromosomes were also prepared by a conventional method, which included immobilization of chromosomes in agarose and a room-temperature dehydration (embedding) protocol. Three-dimensional reconstructions showed that samples prepared with the new method have a greater interconnectivity of sub-structural features and a higher compaction ratio together with an apparently less perturbed chromatin structure than those prepared using the conventional approach. The implications of the new method for the preparation ...

2005-07-15

112

Precise lithium isotopic analysis by thermal ionization mass spectrometry using lithium phosphate as an ion source material  

International Nuclear Information System (INIS)

A high-precision Li isotope analysis was developed for determining the Li"+ ion emitted from lithium phosphate as an ion source material by a Re double-filament ionization method in the thermal ionization mass spectrometry. In this method, Li isotopic fractionation is distinctly less sensitive to the filament temperature than those in the previous methods, and stable and high ion beam intensity of more than 8 x 10"-"1"1 A for "7Li is obtained. These advantages in determining the "7Li/"6Li ratio result in the analytical reproducibility of 0.26 per mille (1#sigma#). Furthermore, the sample preparation is simple and the low temperature (850degC) required by this method ensures the analysis of the isotopic composition of small amounts of Li with less influence of Li contamination to the sample, compared with the previous methods. (author).

113

Empirical Evaluation of a New Method for Calculating Signal to Noise Ratio (SNR) for Microarray Data Analysis  

Energy Technology Data Exchange (ETDEWEB)

Signal-to-noise-ratio (SNR) thresholds for microarray data analysis were experimentally determined with an oligonucleotide array that contained perfect match (PM) and mismatch (MM) probes based upon four genes from Shewanella oneidensis MR-1. A new SNR calculation, called signal to both standard deviations ratio (SSDR) was developed, and evaluated along with other two methods, signal to standard deviation ratio (SSR), and signal to background ratio (SBR). At a low stringency, the thresholds of SSR, SBR, and SSDR were 2.5, 1.60 and 0.80 with oligonucleotide and PCR amplicon as target templates, and 2.0, 1.60 and 0.70 with genomic DNA as target templates. Slightly higher thresholds were obtained at the high stringency condition. The thresholds of SSR and SSDR decreased with an increase in the complexity of targets (e.g., target types), and the presence of background DNA, and a ...

2008-03-06

114

Thin Film Solar Cells and Solar Cell Testing, Volume II Proceedings of the Fourth Photovoltaic Specialists Conference  

Science.gov (United States)

Thin film solar cells and solar cell testing - photovoltaic cells, radiation damage to cadmium sulfide solar cells, and airplane testing of solar cells

1964-01-01

115

The role of metallothionein IIa in defending lens epithelial cells against cadmium and TBHP induced oxidative stress  

UK PubMed Central (United Kingdom)

PurposeHeavy metals and other forms of oxidative stress have been implicated as key factors in the formation of age-related cataract in humans. Metallothioneins are...Full Text Available

116

Phytochelatin Synthesis and Glutathione Levels in Response to Heavy Metals in Tomato Cells 1  

UK PubMed Central (United Kingdom)

Cell suspension cultures of tomato, Lycopersicon esculentum Mill. cv VFNT-Cherry, produce phytochelatins (poly[γ-glutamylcysteinyl]glycines) when exposed to cadmium. The synthesis...Full Text Available

1987-12-01

117

Partial Characterization of Cadmium-Binding Protein from Roots of Tomato 1  

UK PubMed Central (United Kingdom)

Cd-binding protein was extracted from tomato roots and purified on QAE-Sephadex A-25 and on Sephadex G-75 in 1 molar KCl buffer. The protein preparation was light brown and contained predominantly Cd...Full Text Available

1986-07-01

118

Optical and Structural Characteristics of Heavily Boron-Implanted CdTe.  

Science.gov (United States)

Cadmium telluride single crystals were subjected to multiple-energy boron ion implants with total doses up to 1.5 x 10 sq cm. Various diagnostic techniques were used to assess the structural and electronic properties of these crystals in their as-implante...

1988-01-01

119

NREL preprints for the 23rd IEEE Photovoltaic Specialists Conference  

Energy Technology Data Exchange (ETDEWEB)

Topics covered include various aspects of solar cell fabrication and performance. Aluminium-gallium arsenides, cadmium telluride, amorphous silicon, and copper-indium-gallium selenides are all characterized in their applicability in solar cells.

1993-05-01

120

Cadmium biosorption rate in protonated Sargassum biomass  

Energy Technology Data Exchange (ETDEWEB)

Biosorption of the heavy metal ion Cd{sup 2+} by protonated nonliving brown alga Sargassum fluitans biomass was accompanied by the release of hydrogen protons from the biomass. The uptake of cadmium and the release of proton matched each other throughout the biosorption process. The end-point titration methodology was used to maintain the constant pH 4.0 for developing the dynamic sorption rate. The sorption isotherm could be well represented by the Langmuir sorption model. A mass transfer model assuming the intraparticle diffusion in a one-dimensional thin plate as a controlling step was developed to describe the overall biosorption rate of cadmium ions in flat seaweed biomass particles. The overall biosorption mathematical model equations were solved numerically yielding the effective diffusion coefficient D{sub e} about 3.5 {times} 10{sup {minus}6} cm{sup 2}/s. This value matches that obtained for the desorption process and is approximately ...

1999-03-01

121

Assessment of battery technologies for electric vehicles  

Energy Technology Data Exchange (ETDEWEB)

This document, Part 2 of Volume 2, provides appendices to this report and includes the following technologies, zinc/air battery; lithium/molybdenum disulfide battery; sodium/sulfur battery; nickel/cadmium battery; nickel/iron battery; iron/oxygen battery and iron/air battery. (FI)

1990-02-01

122

Visualization by PIV of dynamic stall on a vertical axis wind turbine  

Energy Technology Data Exchange (ETDEWEB)

The aerodynamic behavior of a vertical axis wind turbine (VAWT) is analyzed by means of 2D particle image velocimetry (PIV), focusing on the development of dynamic stall at different tip speed ratios. The VAWT has an unsteady aerodynamic behavior due to the variation with the azimuth angle {theta} of the blade's sections' angle of attack, perceived velocity and Reynolds number. The phenomenon of dynamic stall is then an inherent effect of the operation of a VAWT at low tip speed ratios, impacting both loads and power. The present work is driven by the need to understand this phenomenon, by visualizing and quantifying it, and to create a database for model validation. The experimental method uses PIV to visualize the development of the flow over the suction side of the airfoil for two different reference Reynolds numbers and three tip speed ratios in the operational regime of a small ...

2009-01-15

123

Synthesis of histidine-stabilized cadmium sulfide quantum dots: Study of their fluorescence behaviour in the presence of adenine and guanine  

British Library Electronic Table of Contents (United Kingdom)

Cadmium sulfide particles have been synthesized in the aqueous medium using the amino acid histidine as a stabilizing agent. These particles demonstrate the phenomenon of size quantization effect. The fluorescence of histidine-stabilized CdS was found to be enhanced and quenched by the addition of DNA bases adenine and guanine, respectively. The fluorescence enhancement of CdS in the presence of adenine has been explained on the basis of interaction between the quantum dot stabilizer and the amino group of adenine. Quenching of CdS fluorescence by guanine occurs due to interaction of the substrate with the quantum dot surface.

2010-01-01

124

Biosorption process for removing heavy metal ions using water milfoil (Myriophyllum Spicatum) in contaminated water  

Energy Technology Data Exchange (ETDEWEB)

A small scale biomass metal contacting experiment was performed to screen the optimal plant species for biosorption and bioaccumulation of cadmium, zinc, nickel, lead, and copper. Experiments were also conducted to test the ability of the biomass to lower the metal concentrations below the US Environmental Protection Agency surface water discharge criteria. The minimum residual concentration was 0.1 mg/L for zinc, 0.004 mg/L for lead, and about 0.01 mg/L for cadmium, nickel, and lead. Results indicate that water milfoil can be used for bioremoval of metals.

1995-12-31

125

ASARCO to pay over $59 million for damages and cleanup costs at Denver smelting facility  

Science.gov (United States)

Since 1901, ASARCO, Inc. has owned and operated an 89-acre cadmium-refining smelter in the Globeville neighborhood of north Denver, Colorado. According to complaints filed by EPA and local residents, operations at the smelter have allegedly contaminated the air, ground water, surface water, and soil; contamination from arsenic, cadmium, lead, and zinc has occurred both onsite and offsite. EPA proposed to add the site to the National Priorities List (NPL) in May 1993.

1993-11-01

126

Distribution of blood lead, blood cadmium, urinary cadmium, and urinary arsenic levels in employees of a copper smelter  

Energy Technology Data Exchange (ETDEWEB)

A cross-sectional medical examination of a copper smelter work force included determination of blood lead (Pb-B), zinc protoporphyrin (ZPP), blood cadmium (Cd-B), urinary cadmium (Cd-U), and urinary arsenic (As-U), since it was known that such metal impurities were present in the copper concentrate. A total of 776 copper smelter employees (680 active and 96 retirees and ex-employees) were examined. Another 144 men, never employed in the smelter, but who had worked in copper mines (and sometimes in gold mines) were also examined. Mean Pb-B, ZPP, Cd-B, and As-U were significantly higher in active copper smelter employees than in retirees or miners, indicating exposure and absorption in the copper smelter. Significant correlations between Pb-B and Cd-B, and Cd-U and As-U were present, confirming the common source of absorption. Although there was evidence for an increased lead absorption, this was very moderate, with practically no Pb-B levels in ...

1984-02-01

127

Calculating ac/dc resistance ratios for high-pressure oil-filled cable Designs. Volume 1. Designer's guide. Final report  

Energy Technology Data Exchange (ETDEWEB)

Using electromatic field theory, a new method is developed for calculating alternating current in power cables installed in pipes of carbon steel (magnetic pipes). The technique for evaluating these losses is based on the method of images which replaces complicated distribution of currents in the system with a sequence of thin conductors. The method not only gives a mathematical framework for the solution of alternating current losses, but it also gives the underlying physical picture of effects contributing to these losses. Skin effect, proximity effect and losses due to the pipe are calculated separately. For the first time, the increase of losses in the conductors, when the cables are placed in a magetic pipe, are analyzed mathematically. Good agreement is obtained between the result of calculations and the experimentally determined ac-dc resistance ratios for pipe-type cables with concentric ...

1985-04-01

128

Transient burnout in flow reduction condition  

International Nuclear Information System (INIS)

A transient flow reduction burnout experiment was conducted with water in a uniformly heated, vertically oriented tube. Test pressures ranged from 0.5 to 3.9 MPa. An analytical method was developed to obtain transient burnout conditions at the exit. A simple correlation to predict the deviation of the transient burnout mass velocity at the tube exit from the steady state mass velocity obtained as a function of steam-water density ratio and flow reduction rate. The correlation was also compared with the other data. (author).

129

Supernova Neutrinos Detection On Earth  

CERN Document Server

In this paper, we first discuss the detection of supernova neutrino on Earth. Then we propose a possible method to acquire information about $\\theta_{13}$ smaller than $1.5^\\circ$ by detecting the ratio of the event numbers of different flavor supernova neutrinos. Such an sensitivity cannot yet be achieved by the Daya Bay reactor neutrino experiment.

2009-01-01

130

Spectrophotometric technique quantitatively determines NaMBT inhibitor in ethylene glycol-water solutions  

Science.gov (United States)

Spectrophotometric method, using a ratio-recording ultraviolet-absorption spectrophotometer, permits analysis of NaMBT in ethylene glycol-water solutions with high accuracy. It reduces analysis time, requires smaller samples, and is able to detect extremely small concentrations of mercaptobenzothiazole.

1967-01-01

131

Diagnosis of early human myocardial ischemic damage with electron probe microanalysis  

Energy Technology Data Exchange (ETDEWEB)

We determined the Na/K x-ray intensity ratio in frozen sections of myocardial tissues obtained at autopsy from patients who died from various causes, using electron probe analysis. We have been able to distinguish between the ischemically injured and normal cells. The method is simple, fast, and dependable even when the duration of ischemia is only 30 minutes.

1983-03-01

132

Calculating ac/dc resistance ratios for high-pressure oil-filled cable designs. Volume 2. Details of mathematical derivations. Final report  

Energy Technology Data Exchange (ETDEWEB)

Conventional methods for calculating electricity losses in pipe-type cable systems rely heavily on data measured in lower-voltage systems in the 1950s. With the new technique developed in this study, engineers can compute power losses more precisely for cables of various configurations and voltage ratings.

1985-04-01

133

[F-18]FDG PET metabolic indices for the evluation of glioma  

International Nuclear Information System (INIS)

[F-18]FDG PET brain imaging is an accurate predictor of primary brain tumor grading and prognosis. The purpose of this study was to evaluate simplified [F-18]FDG PET metabolic indices as indicators of proliferative activity of brain tumor cells. Twenty-five patients with glioma were studied with [F-18]FDG PET. From the tissue radioactivity ratios, following tumor metabolic indices were calculated: 1) the tumor-to-whole brain ratio (T/WB), 2) the ratio of tumor-to-contralateral gray matter at the level of centrum semiovale (T/GM), 3) the ratio of tumor-to-contralateral white matter at the level of centrum semiovale (T/WM), 4) the tumor-to-ipsilateral cerebella ratio (T/iCB) and 5) the tumor-to-contralateral cerebellar ratio (T/cCB). A standardized threshold method was used to define ROIs in the tumor areas having representative metabolic ...

1997-05-16

134

Breached fuel location in FFTF by delayed neutron monitor triangulation  

International Nuclear Information System (INIS)

The purpose of this work was to develop and evaluate a method of locating breached fuel within the Fast Flux Test Facility (FFTF) reactor based on the relative response of the delayed neutron monitors (DNM) located on each of the three primary sodium cooling loops. The primary method of location is the use of tag gas containing unique ratios of the noble gases xenon and krypton. Although the tag gas system works quite well, it is relatively expensive because of the costs of preparing and loading the gas into each fuel pin. Triangulation of DNM signals could potentially decrease tag gas costs while maintaining overall location reliability.

1985-11-10

135

Combined inverse modeling approach and load duration curve method for variable nitrogen total maximum daily load development in an agricultural watershed  

British Library Electronic Table of Contents (United Kingdom)

Purpose Nonpoint sources (NPS) pollution has been an important cause for water quality impairment worldwide. To take the temporal variations of both NPS pollution and in-stream attenuation into consideration, an inverse modeling approach and the load duration curve (LDC) method were combined for variable nutrient total maximum daily load (TMDL) development. Methods Water quality and hydrological parameters were monitored monthly along the ChangLe River system in 2004?2008. The catchment NPS export load (EL) and TMDL for total nitrogen (TN) were estimated by the inverse format of an existing stream nutrient transport equation. The LDC method was used to describe the variability of EL, TMDL, requiring load (RLR) and percent (the ratio between the RLR and the EL, RPR) reduction, and then to s...

2011-01-01

136

Characterization of Y2BaCuO5 nanoparticles synthesized by nano-emulsion method  

British Library Electronic Table of Contents (United Kingdom)

Nanoscale yttrium?barium?copper oxide (Y2BaCuO5, Y211) particles were synthesized using the emulsion method and the solution method. The basic water-in-oil (w/o) emulsion system consisted of n-octane (continuous oil phase), cetyltrimethylammonium bromide (cationic surfactant), butanol (cosurfactant) and water. The composition of the emulsion system was varied and characterized by measuring the conductivity of the solutions and droplet size. The droplet size of emulsion was determined by using the dynamic light scattering method. The water content, cosurfactant content, and surfactant/n-octane ratio affected the droplet size which was in the range of 3?8?nm, and hence the w/o emulsion system was referred to as a nano-emulsion system. A model was used to verify the droplet size. The influenc...

2007-01-01

137

Assessment of the sensitivity and prediction uncertainty of evaporation models applied to Nasser Lake, Egypt  

British Library Electronic Table of Contents (United Kingdom)

SummaryThis paper examines the sensitivity and uncertainty of evaporation estimates from Nasser Lake, south of Egypt using data collected at the floating station Raft, 2km upstream of the Aswan High Dam, and 12 evaporation models. Based on their approach the evaporation models were ranked in five classes, respectively the Bowen ratio energy budget (BREB) approach, three energy-aerodynamic based methods, a mass transfer method, two temperature and five solar radiation-temperature approaches. State dependent parameter models were used to estimate the sensitivity indices of the different evaporation estimation methods at daily and monthly frequencies. A drastic reduction in the cost of the sensitivity analysis was obtained when coupled with efficient sampling methods, producing quasi-Monte Ca...

2010-01-01

138

Recent developments and applications for the University of Texas thermal neutron imaging facility  

Energy Technology Data Exchange (ETDEWEB)

The full text follows. A thermal neutron imaging facility (TNIF) capable of real time neutron radiography and computed tomography was developed for the University of Texas TRIGA Mark II (UT-TRIGA) reactor from 1994-1998. The facility was developed with a through reactor beam port capable of producing a 5.2 x 10{sup 6} n/cm{sup 2}/s thermal neutron flux with a gamma dose rate of less than 1 mR/s after collimation. The original TNIF included the UT-TRIGA reactor, neutron collimation array, sample positioning system, neutron image intensifier tube, video camera, computerized image acquisition system, and a radiation shield. A 0.7 mm slit in cadmium was easily detectable using neutron radiography, and 1.4 mm diameter holes bored in an aluminum block were easily resolved using computed neutron tomography. Precise lower limits of the system resolution have hot been determined. The TNIF is currently being revamped to begin work with the non-destructive evaluation (NDE) of ...

2001-07-01

139

Particokinetics In Vitro: Dosimetry Considerations for In Vitro Nanoparticle Toxicity Assessments  

Energy Technology Data Exchange (ETDEWEB)

The rapid growth in the use of in vitro methods for nanoparticle toxicity assessment has proceeded with limited consideration of the unique kinetics of these materials in solution. Particles in general and nanoparticles specifically, diffuse, settle and agglomerate in cell culture media as a function of several systemic and particle factors: media density and viscosity, particle size, shape and density. Cellular dose then is also a function of these factors as they determine the rate of transport of nanoparticles to cells in culture. Here we develop and apply the principles of particokinetics and dosimetry in vitro and outline an approach for simulation of nanoparticle particokinetics in cell culture systems. We illustrate that where equal mass concentrations (?g/ml) imply equal doses for dissimilar materials, the corresponding particle number or surface area concentration doses differ by orders of magnitude. When rates of diffusional and gravitational particle ...

2007-02-01

140

Lead and cadmium in food. How do heavy metals find their way into our food and, how can the general public protect itself; Blei und Cadmium in Lebensmitteln; Wie kommen die Schwermetalle in unsere Nahrung? Und: Wie koennen sich Verbraucherinnen und Verbraucher schuetzen?  

Energy Technology Data Exchange (ETDEWEB)

The amounts of lead and cadmium produced and processed in these days are considerable. As a result, our environment is increasingly polluted by heavy metals and industrial installations, motor vehicles or incinerating plants appear to be among the main culprits here. Air and water are the media permitting the entry of heavy metals into our natural environment where they accumulate in the soil and then gradually migrate into the plants. Their further transport in the food constitutes the third step in the environmental spread of heavy metals. The consumption of muscle and organ meats, of vegetables, fruits, canned food and drinking water is unavoidably associated with some ingestion of lead and cadmium. The degree to which they are taken up and stored in different tissues is determined by absorption properties and the nutritional state of the organism. Cadmium tends to accumulate in the kidneys, lead is mainly stored in the ...

1992-08-01

141

ETE-EVAL: a methodology for D and D cost estimation  

International Nuclear Information System (INIS)

In compliance with Article 20 of the sustainable radioactive materials and waste management act dated 28 June 2006, the CEA and AREVA are required every three years to revise the cost of decommissioning their facilities and to provide the necessary assets by constituting a dedicated fund. For the 2007 revision the CEA used ETE-EVAL V5. Similarly, AREVA reevaluated the cost of decontaminating and dismantling its facilities at La Hague, as the previous estimate in 2004 did not take into account the complete cleanup of all the structural work. ETE-EVAL V5 is a computer application designed to estimate the cost of decontamination and dismantling of basic nuclear installations (INB). It has been qualified by Bureau Veritas and audited. ETE-EVAL V5 has become the official software for cost assessment of CEA civilian and AREVA decommissioning projects. It has been used by the DPAD (Decontamination and Dismantling Projects Department) cost assessment group to estimate the cost of ...

142

Steady particulate flows in a horizontal rotating cylinder  

Energy Technology Data Exchange (ETDEWEB)

Results of discrete element method (DEM) simulation and magnetic resonance imaging (MRI) experiments are compared for monodisperse granular materials flowing in a half-filled horizontal rotating cylinder. Because opacity is not a problem for MRI, a long cylinder with an aspect ratio {approximately}7 was used and the flow in a thin transverse slice near the center was studied. The particles were mustard seeds and the ratio of cylinder diameter to particle diameter was approximately 50. The parameters compared were dynamic angle of repose, velocity field in a plane perpendicular to the cylinder axis, and velocity fluctuations at rotation rates up to 30 rpm. The agreement between DEM and MRI was good when the friction coefficient and nonsphericity were adjusted in the simulation for the best fit. {copyright} {ital 1998 American Institute of Physics.}

1998-06-01

143

Learning Undirected Graphical Models with Structure Penalty  

CERN Document Server

In undirected graphical models, learning the graph structure and learning the functions that relate the predictive variables (features) to the responses given the structure are two topics that have been widely investigated in machine learning and statistics. Learning graphical models in two stages will have problems because graph structure may change after considering the features. The main contribution of this paper is the proposed method that learns the graph structure and functions on the graph at the same time. General graphical models with binary outcomes conditioned on predictive variables are proved to be equivalent to multivariate Bernoulli model. The reparameterization of the potential functions in graphical model by conditional log odds ratios in multivariate Bernoulli model offers advantage in the representation of the conditional independence structure in the model. Additionally, we impose a structure penalty on groups of ...

2011-01-01

144

Full potential linear augmented plane wave study of the elastic properties of XPt_3 (X=V, Cr, Mn, Fe, Co, Ni)  

International Nuclear Information System (INIS)

From the first principles total energy calculations based on full-potential linear augmented plane wave method (FPLAPW), the elastic properties of XPt_3 (X=V, Cr, Mn, Fe, Co, Ni) are reported here. Theoretical values of Young's modulus, shear modulus, Poisson's ratio and Debye temperature are estimated from the computed elastic constants. From the analysis of the ratio of shear to bulk modulus, it is found that these intermetallic compounds are ductile in nature except CrPt_3, which is brittle. The calculated results are compared with other reported values.

2010-06-01

145

Evaluation of the Soft and Hard Tissue Changes After Anterior Segmental Osteotomy on the Maxilla and Mandible  

British Library Electronic Table of Contents (United Kingdom)

PurposeThe purpose of this study was to determine the relationship between the changes of soft and hard tissues after modified anterior segmental osteotomy on the maxilla and mandible and to evaluate unintended facial changes using cephalometric and photometric analyses.Materials and MethodsThe subjects included 29 women and 1 man (22 to 50 years of age) who were diagnosed as bialveolar or bimaxillary protrusion and underwent modified anterior segmental osteotomy on the maxilla and mandible. Lateral cephalograms and lateral and frontal photographs taken preoperatively and postoperatively were analyzed.ResultsThere was a significant change in all soft and hard tissue parameters except the labiomental angle. The ratio of upper lip to maxillary incisor retraction was 0.67:1 and the ratio of l...

2008-01-01

146

Oxygen O18 method and the search for the ionization mechanism in sputtering of oxygenated surfaces  

International Nuclear Information System (INIS)

Recently developed oxygen O18 method [K. Franzreb, J. Lorincik, P. Williams, Surf. Sci. 573 (2004) 291; R.C. Sobers, K. Franzreb, P. Williams, Appl. Surf. Sci. 231-232 (2004) 729; P. Williams, R.C. Sobers Jr., K. Franzreb, J. Lorincik, Appl. Surf. Sci. 252 (2006) 6429] is able to quantitatively determine the flux ratio of oxygen to matrix species at dynamical SIMS sputtering. This flux ratio can be directly related to the surface oxygen concentration at dynamical sputtering - an important parameter controlling the ionization yield of emitted species. It is argued that the oxygen O18 method is a worthy step forward in gathering relevant experimental data that might eventually lead to the understanding of oxygen enhancement mechanism in SIMS. A current status of understanding of the ionization processes in SIMS is briefly discussed in terms of non-adiabatic strongly velocity dependent processes ...

2008-12-15

147

Chaos and bifurcation of a flexible rotor supported by porous squeeze couple stress fluid film journal bearings with non-linear suspension  

Energy Technology Data Exchange (ETDEWEB)

This study presents a dynamic analysis of a flexible rotor supported by two porous squeeze couple stress fluid film journal bearings with non-linear suspension. The dynamics of the rotor center and bearing center are studied. The analysis of the rotor-bearing system is investigated under the assumptions of non-Newtonian fluid and a short bearing approximation. The spatial displacements in the horizontal and vertical directions are considered for various non-dimensional speed ratios. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The numerical results show that the stability of the system varies with the non-dimensional speed ...

2008-01-15

148

Chaos and bifurcation of a flexible rotor supported by porous squeeze couple stress fluid film journal bearings with non-linear suspension  

International Nuclear Information System (INIS)

This study presents a dynamic analysis of a flexible rotor supported by two porous squeeze couple stress fluid film journal bearings with non-linear suspension. The dynamics of the rotor center and bearing center are studied. The analysis of the rotor-bearing system is investigated under the assumptions of non-Newtonian fluid and a short bearing approximation. The spatial displacements in the horizontal and vertical directions are considered for various non-dimensional speed ratios. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The numerical results show that the stability of the system varies with the non-dimensional speed ...

2008-01-01

149

The measurement of the fission product ratios, {sup 134}Cs/{sup 137}Cs and {sup 154}Eu/{sup 137}Cs in spent PWR fuel by gamma scanning method  

Energy Technology Data Exchange (ETDEWEB)

We obtained the ratios of {sup 134}Cs/{sup 137}Cs and {sup 154}Eu/{sup 137}Cs in spent PWR fuels with gamma scanning equipment of irradiated material examination facility. The fuel segments, of which the burn-up is about 40 GWD/MTU and its cooling time is 8.4 years, are prepared in Post Irradiated Examination Facility and transported to IMEF. By considering of multi-peaks of {sup 134}Cs and {sup 154}Eu, we obtained the relative efficiency of the gamma scanning system as a function of energy. And finally we obtained the number ratios of radioactive nuclides in 72 fuel pellets, radioactive {sup 134}Cs/{sup 137}Cs and {sup 154}Eu/{sup 137}Cs. (author). 4 refs., 27 tabs., 28 figs.

1997-10-01

150

The measurement of the fission product ratios, "1"3"4Cs/"1"3"7Cs and "1"5"4Eu/"1"3"7Cs in spent PWR fuel by gamma scanning method  

International Nuclear Information System (INIS)

We obtained the ratios of "1"3"4Cs/"1"3"7Cs and "1"5"4Eu/"1"3"7Cs in spent PWR fuels with gamma scanning equipment of irradiated material examination facility. The fuel segments, of which the burn-up is about 40 GWD/MTU and its cooling time is 8.4 years, are prepared in Post Irradiated Examination Facility and transported to IMEF. By considering of multi-peaks of "1"3"4Cs and "1"5"4Eu, we obtained the relative efficiency of the gamma scanning system as a function of energy. And finally we obtained the number ratios of radioactive nuclides in 72 fuel pellets, radioactive "1"3"4Cs/"1"3"7Cs and "1"5"4Eu/"1"3"7Cs. (author). 4 refs., 27 tabs., 28 figs.

1988-09-18

151

Study of praseodymium complexing with ethylenediaminetetraacetic acid by proton magnetic resonance  

Energy Technology Data Exchange (ETDEWEB)

The method of proton magnetic resonance (PMR) has been used to study the mechanism of reaction of complexing of paramagnetic Pr/sup 3 +/ ion with ethylenediaminetetra acetic acid (EDTA). The influence of medium acidity (pH5-12), EDTA/Pr ratio varying from 1 to 50, Pr/sup 3 +/ ion concentration (from 5x10/sup -3/ to 3x10/sup -1/ g-ion/l) and temperature (8-98 deg C) on chemical shifts and broadening of signals of EDTA molecule protons is investigated. Data on ratio of components, coordination and stability of forming complexes are obtained. The existence of two types of complexes with the Pr/EDTA ratio equal to 1:1 and 1:2 has been found. Equimolecular complex (1:1) is stable all over the studied temperature interval in contrast to the complex 1:2 for which at 50 deg C fast extrasphere exchange (Pr EDTA)EDTA * + EDTA/sup 0/ reversible (PrEDTA)EDTA/sup 0/ + EDTA * is observed, while at t=98 deg C ...

1983-05-01

152

Stable isotopes of authigenic minerals in variably-saturated fractured tuff  

Energy Technology Data Exchange (ETDEWEB)

Identifying stable isotope variation and mineralogical changes in fractured rock may help establish the history of climatic and geomorphological processes that might affect the isolation properties of a waste repository site. This study examines the use of the stable isotope ratios of oxygen ({sup 18}O/{sup 16}O) and carbon ({sup 13}C/{sup 12}C) in authigenic minerals as hydrogeochemical tools tracing low-temperature rock-water interaction in variably-saturated fractured stuff. Isotopic compositions of fracture-filling and rock matrix minerals in the Apache Leap tuff, near Superior, Arizona were concordant with geothermal temperatures and in equilibrium with water isotopically similar to present-day meteoric water and groundwater. Oxygen and carbon isotope ratios of fracture-filling, in unsaturated fractured tuff, displayed an isotopic gradient believed to result from near-surface isotopic enrichment due to evaporation rather than the effects ...

1988-11-01

153

Measurement of the concentration of coal slurry using microwave techniques; Maikuroha wo oyoshita konodo sekitan slurry no nodo sokutei ni tsuite  

Energy Technology Data Exchange (ETDEWEB)

The paper reported on an experiment on measurement of concentration of highly concentrated coal slurry using microwaves carried out at Miike coal preparation works. The purpose of the experiment was to investigate applicability of microwave moisture content measurement of slurry of a mixture of coal and coal particles and to use it to the control of process such as coal preparation and processing. In the experiment, a method for measuring the slurry concentration was adopted in which the container filled with highly concentrated coal slurry was irradiated with microwaves and the damping of strength of the penetrating microwaves was detected. As a result of the experiment, it was found out that there was a big correlation between the capacitive concentration of slurry and the damping ratio of microwaves. When irradiating slurry with microwaves of 1GHz frequency, a big correlation between the concentration and the damping ...

1996-09-30

154

Lead recycling; Namari no recycle  

Energy Technology Data Exchange (ETDEWEB)

In Japan, lead has been widely used for gasoline additives, inorganic chemicals such as pigment, lead pipes/plates, and coating materials of cable. Because of the steady increase in car population and the mounting of environmental concern, lead consumption ratio for lead-acid batteries is tending to increase gradually up to 70% with decreasing the consumption for gasoline additives. This paper describes the recycling of lead-acid batteries in Japan. Since the latter half of FY 1994, the battery manufacturing industry started the new lead recycling system. The recycling ratio of the used lead-acid batteries became 90% in 1996 from 84% in 1994. In near future, it can reach to 95%, the recycling ratio in some European countries. The primary smelting occupies 53%, and the secondary smelting occupies 47%. For the conventional method by secondary smelting makers, reduction smelting and copper removing of lead ...

1997-12-25

155

VSP reverse-time migration  

Energy Technology Data Exchange (ETDEWEB)

VSP reverse-time migration is a well adaptable wave equation migration method. Its control equation not only describes all-direction propagation of seismic wave but also removes interbed multiples. Clearbout's image principle is generalized to determine image conditions, real VSP data are used to determine boundary condition, and two way reflection-free wave equation is solved by making reverse-time extrapolation. In each step of extrapolation, the migration value at relevant image point is obtained by using the image condition. The complete migration of a seismic section is achieved when reverse-time extrapolation reaches the minimum image time. In this paper it is proved theoretically and practically that this method is applicable to any velocity variation and makes the migrated section have both good resolution and high S/N ratio. Besides, this method results in high processing efficiency.

1991-01-01

156

Estimating hip fracture risk from digital x-ray image data  

International Nuclear Information System (INIS)

The authors propose a method for determining the risk of femoral neck fracture in osteoporotic patients that is not based on densitometric techniques. The method is based on a structural analysis performed by a computer on data taken from a single digital anteroposterior projection of the hip. From the image, the effective cross-sectional area and cross-sectional moment of inertia are computed from attenuation principles. Together with other geometric measurements, these data are used in an engineering analysis to compute the yield strength of the proximal femur, under stress applied through the acetabulum in a one-legged stance. An index of fracture risk based on the ratio of estimated yield strength to body weight is proposed. Ultimately it is expected that this work will allow the clinician to estimate hip fracture risk in osteoporotic patient using widely available existing technology, a goal which has eluded bone ...

157

Absolute subcriticality measurement without calibration and detection efficiency dependence by the /sup 252/Cf source-driven noise method  

Energy Technology Data Exchange (ETDEWEB)

The /sup 252/Cf-source-driven noise analysis method determines the subcriticality of a system containing fissionable material from the ratio of cross power spectral densities between the detectors that detect particles from the fission process and between these detectors and an ionization chamber containing a spontaneously fissioning neutron source which provides neutrons to induce fission in the system. This method has two advantages: (1) a calibration is not required and thus subcriticality can be determined from measurements only on the subcritical system of interest, and (2) the subcriticality is independent of the type of detector or its efficiency. These properties of this technique are illustrated by measurements.

1984-01-01

158

A calculation method of running range of electric vehicle with battery hybrid system  

Energy Technology Data Exchange (ETDEWEB)

Much attention is being paid to electric vehicles from environmental standpoints. One disadvantage of the electric vehicle is that its operative range is short. A means to overcome this difficulty is to use a hybrid battery which consist of a energy battery and a power battery. A method to make it possible to calculate the discharge characteristics of the battery hybrid system taking into account the charging behavior from the energy battery to the power battery is presented. In the proposed method, first the output voltage and the output current of an equivalent battery, which is required for realizing the given operating pattern are calculated. Next, the conduction ratio of the main chopper and the equivalent discharge of electric charge of each battery are calculated. These calculated data are used to calculate the operating range.

1980-05-01

159

K/sub. beta. //K/sub. cap alpha. / transition probability ratios from the measurement of fluorescent X-ray intensities of some lanthanide compounds  

Energy Technology Data Exchange (ETDEWEB)

The effect that different chemical and physical atomic environments can have on the relative intensities of radiative electron transitions from the filling of K shell vacancies was investigated. The method used involved the detection of photoionization induced X-ray fluorescence. An experimental system based on a hyper pure germanium detector (HPGE) was used to measure the relative K-L and K-M X-ray yields from the photofluorescence of a series of lanthanide elements and compounds. A background subtraction and peak integration strategy was employed which accounted for scattering in the samples and scattering of the flux from the radioisotope photoionization sources. Analysis of the data resulted in a tabulation of relative K/sub ..beta..//K/sub ..cap alpha../ X-ray intensity ratios. The measured relative K/sub ..beta..//K/sub ..cap alpha../ X-ray intensity ratios were compared to the calculated values predicted by the ...

1987-01-01

160

K/sub #beta#//K/sub #alpha#/ transition probability ratios from the measurement of fluorescent X-ray intensities of some lanthanide compounds  

International Nuclear Information System (INIS)

The effect that different chemical and physical atomic environments can have on the relative intensities of radiative electron transitions from the filling of K shell vacancies was investigated. The method used involved the detection of photoionization induced X-ray fluorescence. An experimental system based on a hyper pure germanium detector (HPGE) was used to measure the relative K-L and K-M X-ray yields from the photofluorescence of a series of lanthanide elements and compounds. A background subtraction and peak integration strategy was employed which accounted for scattering in the samples and scattering of the flux from the radioisotope photoionization sources. Analysis of the data resulted in a tabulation of relative K/sub #beta#//K/sub #alpha#/ X-ray intensity ratios. The measured relative K/sub #beta#//K/sub #alpha#/ X-ray intensity ratios were compared to the calculated values predicted by the theoretical ...

1987-01-01

161

Characteristics of oxidation reaction of rare-earth chlorides for precipitation in LiCl-KCl molten salt by oxygen sparging  

International Nuclear Information System (INIS)

The precipitation reaction of some rare earth chlorides (La/Ce/Nd/GdCl3) in a LiCl-KCl molten salt has been carried out by using the oxygen sparging method. In this study, regardless of the oxygen sparging time and the molten salt temperature, oxychlorides (REOCl) for LaCl3, NdCl3 and GdCl3, and an oxide (REO2) for CeCl3 are formed as a precipitate. The conversion of rare-earth chlorides into insoluble precipitates was described by using a conversion ratio. The conversion ratio increased exponentially with the oxygen sparging time and finally showed asymptotic value at 1,023K of the molten salt temperature condition. The conversion ratios of LaCl3, NdCl3 and GdCl3 were increased with the molten salt temperature, however, even though the conversion ratio was increased from 0.660 to 0.995 with increasing molten salt temperature from 823 to 923 K at 60 min of a sparging time, the ...

2006-10-01

162

Determination of As, Cd, Pb, and Hg in urine using inductively coupled plasma mass spectrometry with the direct injection high efficiency nebulizer  

Energy Technology Data Exchange (ETDEWEB)

The application of the large-bore direct injection high efficiency nebulizer (LB-DIHEN) for the determination of arsenic (As), cadmium (Cd), lead (Pb), and mercury (Hg) in urine by inductively coupled plasma mass spectrometry (ICP-MS) is described. The LB-DIHEN is compared with the standard method using a concentric pneumatic nebulizer and cyclonic spray chamber. In addition to the toxicological significance of As, Cd, Pb, and Hg, these elements represent a cross-section of analytical issues including spectral interferences (e.g., {sup 40}Ar{sup 35}Cl{sup +} on {sup 75}As{sup +} and {sup 98}Mo{sup 16}O{sup +} on {sup 114}Cd{sup +}) and memory effects (Hg). In this study, the low sample consumption of the LB-DIHEN is used to reduce the volume of urine needed for analysis, and to reduce the volume of final diluted sample required for analysis. Eliminating the spray chamber and reducing the dead volume of the nebulizer reduces memory effects, ...

2008-03-15

163

Application of variational methods to fusion reactor blanket studies  

International Nuclear Information System (INIS)

The general development of variational methods for fusion reactor blanket studies is given. Important quantities such as tritium breeding ratio and total nuclear heating are linear functionals of the solutions to the Boltzmann transport equation. To estimate a neutronic quantity by variational methods is, in general, to carry out the scalar product formulation of the Roussopoulos variational principle, or the Schwinger variational principle, with the help of the associated adjoint transport equation where the appropriate response function for the estimate is taken as the source. A multipoint interpolation method based on the above variational principles has been developed and compared to other variational approaches. The method of variational interpolation removes the need to compute both forward and adjoint solutions while the error has the characteristic of cancellation of errors ...

164

Analysis of impurities in beryllium, affecting evaluation of the tritium breeding ratio  

International Nuclear Information System (INIS)

In most conceptual fusion power reactor designs, it is proposed to use beryllium as a neutron multiplier in the blanket. Detailed chemical composition of beryllium is necessary for evaluation of the tritium breeding ratio, and estimating the activation and transmutation of beryllium in the fusion reactor. In the present report, special attention was paid to a detailed analysis of impurities in beryllium, relevant to the tritium breeding ratio evaluation. Two different methods were used for the study of impurities: an analysis of the local sample by the ICP-MS method, and an integral analysis of the beryllium assembly, using the pulsed neutron method. The latter method was proposed as the most effective way of analyzing the integral effect to impurities in beryllium on production of the tritium on the lithium-6. The evaluation of the integral effect was based on ...

165

Influence of sedation and data acquisition method on tracer uptake in animal models: ["1"2"3I]-2-iodo-L-phenylalanine in pentobarbital-sedated tumor-bearing athymic mice  

International Nuclear Information System (INIS)

Objectives: To minimize movement artifacts during tracer imaging studies, the animals are generally sedated. Although many reports describe the effect of barbiturates on brain function, less is published about the general impact on the extracerebral metabolism and tracer biodistribution. This report describes the influence of pentobarbital on tumor uptake of ["1"2"3I]-2-iodo-L-phenylalanine (["1"2"3I]-2I-L-PA) using dissection and nuclear imaging. Methods: R1M tumor-bearing athymic mice were divided into two populations: untreated and pentobarbital-treated. Each group was subjected to dynamic and static planar imaging and organ dissection after ["1"2"3I]-2I-L-PA injection. Two-compartment blood modeling was performed. Analysis of variance (ANOVA), t test and clustered boxplot analyses were used to compare the results between the treatment groups and between the data acquisition methods. Results: Two-compartment blood modeling demonstrated that ...

2006-01-01

166

Enhanced cadmium cytotoxicity in A549 cells with reduced glutathione levels is due to neither enhanced cadmium accumulation nor reduced metallothionein synthesis  

International Nuclear Information System (INIS)

Glutathione (GSH) depletion sensitizes human lung carcinoma (A549-T27) cells to the cytotoxic effects of Cd++. The effects of GSH depletion on Cd++ accumulation and Cd++-induced metallothionein (MT) content were investigated to determine the possible role of these Cd++ responses in the sensitization process. Cellular GSH was depleted to 20% to 25% of control levels with buthionine sulfoximine (BSO), or diethyl maleate (DEM), respectively. Neither treatment significantly affected Cd++-induced accumulation of exogenous 35s-cysteine into intracellular MT in a dose-dependent fashion. The results indicate that neither enhanced Cd++ accumulation nor reduced MT synthesis plays a primary role in affecting enhanced Cd++ cytotoxicity in A549 cells with reduced GSH levels. Although BSO inhibition of GSH synthesis enhanced MT synthesis, it sensitized the cells to Cd++, which suggests an additive effect of GSH and MT in cadmium cytoprotection. This observation also raises the ...

167

Enhanced biosorptive removal of cadmium from aqueous solutions by silicon dioxide nano-powder, heat inactivated and immobilized Aspergillus ustus  

British Library Electronic Table of Contents (United Kingdom)

Heat inactivated Aspergillus ustus (Asp), silicon dioxide-nano-powder (N Si), and silicon dioxide nano-powder-combined-heat inactivated Aspergillus ustus (N Si Asp) were used to study the biosorption of Cd(II) from aqueous solutions via batch equilibrium technique. Surface characterization and immobilization of the fungal cells on silicon dioxide-nano-powder were examined and confirmed by using FT-IR and ESM analysis. Cadmium biosorption processes were investigated under the effect of pH, contact time, sorbent dosage and initial metal concentration. The three examined sorbents were found to exhibit maximum mmolg^-^1 capacity values in pH 7.0. The maximum determined cadmium capacity by silicon dioxide-nano-powder (N Si) (600mmolg^-^1) was found higher than that exhibited by the heat inactiv...

2011-01-01

168

SLFP: A stochastic linear fractional programming approach for sustainable waste management.  

Science.gov (United States)

A stochastic linear fractional programming (SLFP) approach is developed for supporting sustainable municipal solid waste management under uncertainty. The SLFP method can solve ratio optimization problems associated with random information, where chance-constrained programming is integrated into a linear fractional programming framework. It has advantages in: (1) comparing objectives of two aspects, (2) reflecting system efficiency, (3) dealing with uncertainty expressed as probability distributions, and (4) providing optimal-ratio solutions under different system-reliability conditions. The method is applied to a case study of waste flow allocation within a municipal solid waste (MSW) management system. The obtained solutions are useful for identifying sustainable MSW management schemes with maximized system efficiency under various constraint-violation risks. The results indicate that SLFP can support ...

2011-09-01

169

Method for controlling the liquid level of a steam generator for a sodium-cooled fast breeder reactor  

International Nuclear Information System (INIS)

Object: To control the average liquid level of each steam generator at a constant level irrespective of the flow rate of sodium thereby to decrease change in the retained amount of sodium and at the same time to improve the load response characteristic. Construction: A method for decreasing to as large an extent as possible a change in the amount of sodium retained in a steam generator due to change in the flow rate, which comprises the steps of detecting the main recirculating flow rate of liquid sodium by the use of a sodium flow rate detector, amplifying the detected flow rate signal depending upon the ratio between the flow rates respectively in a super-heater and a re-heater (distribution ratio), delivering the amplified signal to a function generator which generates a liquid level setting signal for maintaining the respective average liquid levels of the super-heater and the re-heater at constant levels irrespective ...

170

Heat transfer in parallel plate duct with a sinusoidal wave plate uniaxially inserted (1st). Effect of wave length on heat transfer augmentation  

Energy Technology Data Exchange (ETDEWEB)

High-performance heat transfer augmentation methods applicable in the forced convection field of heat exchangers include a method which requires no external drive means, such as the insertion of a turbulence augmentation object into the flow passage and the use of a wave-shaped flow passage, but disturbs the main stream of flow to raise the heat transportation effect thereby to augment heat transfer in the flow passage. The heat transfer characteristics and thermal performance ratio achieved when sinusoidal-shape plates are inserted instead of augmentation objects, such as cylinders, with a high shape-induced resistance were studied. As a result, the relationship between the resistance coefficient, average Nusselt number, heat transfer coefficient, and pitch was clarified. It has been revealed that the use of eddies with a large gap flow and recirculation area should be considered in order to get a higher heat transfer ...

1988-09-01

171

Augmentation of radiative heat transfer in an infinite cylindrical pipe enclosing a participating gas  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray gas, the augmentation observed are negligible. For the ...

1992-10-01

172

THE DISAPPEARING NUTRITIONAL BIAS AGAINST CHINESE GIRLS  

British Library Electronic Table of Contents (United Kingdom)

This paper investigates whether China has reached postnatal nutrient intake equality between boys and girls, despite an exceptionally high ratio of boys to girls at birth, after dramatic technological advances in prenatal sex determination, rapid increases in income, and improved educational opportunities for females. Dominance methods applied to data from the Chinese Health and Nutrition Surveys (selected years 1991-2004) reveal no bias in calorie consumption between girls and boys. We find some weak evidence of protein bias toward boys in 1991, but it disappeared by 2004. (JEL I32, O15, N35)

2011-01-01

173

Sensitivity to alpha-variation in ultracold atomic-scattering experiments  

CERN Document Server

We present numerical calculations for cesium and mercury to estimate the sensitivity of the scattering length to the variation of the fine structure constant alpha. The method used follows ideas Chin and Flambaum [Phys. Rev. Lett. 96, 230801 (2006)], where the sensitivity to the variation of the electron to proton mass ratio, beta, was considered. We demonstrate that for heavy systems, the sensitivity to variation of alpha is of the same order of magnitude as to variation of beta. Near narrow Feshbach resonances the enhancement of the sensitivity may exceed nine orders of magnitude.

2011-01-01

174

Oxidation of Propylene with Oxygen and Air in a Barrier Discharge in the Presence of Octane  

British Library Electronic Table of Contents (United Kingdom)

Oxidation of propylene with oxygen, air and a mixture of nitrogen?oxygen in a barrier discharge is investigated. The selectivity towards formation of propylene oxide in pure oxygen is shown to be as high as 45 wt% and the propylene conversion ratio is found to be 12.9 wt%. In the oxidation with air, the propylene oxide selectivity is 23 wt%, while the conversion is 7.5 wt%. The values of propylene conversion and selectivity towards formation of propylene oxide in a barrier discharge are consistent with those obtained by the thermocatalytic methods for production of propylene oxide.

2011-01-01

175

NMR at earth's magnetic field using para-hydrogen induced polarization  

British Library Electronic Table of Contents (United Kingdom)

A method to achieve NMR of dilute samples in the earth's magnetic field by applying para-hydrogen induced polarization is presented. Maximum achievable polarization enhancements were calculated by numerically simulating the experiment and compared to the experimental results and to the thermal equilibrium in the earth's magnetic field. Simultaneous 19F and 1H NMR detection on a sub-milliliter sample of a fluorinated alkyne at millimolar concentration (1018 nuclear spins) was realized with just one single scan. A highly resolved spectrum with a signal/noise ratio higher than 50:1 was obtained without using an auxiliary magnet or any form of radio frequency shielding.

2011-01-01

176

Method for treating red mud  

Energy Technology Data Exchange (ETDEWEB)

In order to improve the handling capability of red mud, it is mixed with fine-grain coal material such as brown coal or lignite in dust form, in a ratio by weight of between 0.5-10:1. The liquid present in the red mud is bound by the very fine coal admixed therewith so that the resulting mixture can be stored in a silo and even pneumatically conveyed, and the oily properties of the red mud are removed by the treatment. The mixture is particularly suitable for use in connection with the hydrogenating liquefaction of coal in which the red mud is used as a catalyst.

1984-08-07

177

Measurement error modeling and nutritional epidemiology association analyses  

British Library Electronic Table of Contents (United Kingdom)

Abstract This article summarizes the results of a Nutrient Biomarker Study in the Women's Health Initiative, and its application to studies of the association between energy and protein consumption and the risk of major cancers and cardiovascular diseases. The presentation emphasizes measurement error modeling and related data analysis methods, since addressing measurement issues appears to be central to these topics and to progress in nutritional epidemiology more generally. The manner in which body mass index is modeled in disease association analysis is particularly challenging, since it could serve as a mediator or as a confounder of the association, and at the same time contributes valuably to energy and protein consumption assessment. A hazard ratio parameter estimation procedure tha...

2011-01-01

178

Investigation of formation of Sn-PM tetracycline and Sn-PM-tetracycline-_9_9Tc complexes  

International Nuclear Information System (INIS)

The formation and stability constants of the [sup(99m)Tc]PM tetracycline have been investigated by the potentiometric method. The pK value of the complex formed was measured as pK = 5.49 +- 0.19. The spectrophotometric study has been performed on the formation of a complex of Sn(II) and TcO"4"- in the presence of PM Tetracycline. This study shows that Sn(II) forms with PMT a complex at a mole ratio of 1:1. The molar extinction coefficients of the Sn-PMT and [_9_9Tc]PMT complexes have been measured. (author).

1983-01-01

179

High rate sputter deposition of wear resistant tantalum coatings  

Energy Technology Data Exchange (ETDEWEB)

The refractory nature and high ductility of body centered cubic (bcc) phase tantalum makes it a suitable material for corrosion- and wear-resistant coatings on surfaces that are subjected to high stresses and harsh chemical and erosive environments. Sputter deposition can produce thick tantalum films but is prone to forming the brittle tetragonal beta phase of this material. Efforts aimed at forming thick bcc phase tantalum coatings in both flat plate and cylindrical geometries by high-rate triode sputtering methods are discussed. In addition to substrate temperature, the bcc-to-beta phase ratio in sputtered tantalum coatings is shown to be sensitive to other substrate surface effects.

1992-07-01

180

Gases in insulating oil - analysis of dissolved gases using a portable chromatograph  

Energy Technology Data Exchange (ETDEWEB)

New technological advances make it possible to perform on site gas-in-oil analysis quickly and efficiently. Gas-in-oil analysis is crucial in assessing the status of oil-filled electrical equipment. The new technique is used for extracting and measuring gases dissolved in electrical insulating oil. On-site sampling requires the use of a specially designed 100 ml capacity syringe. Extraction of the dissolved gases is made with a precise ratio of oil to air. A comparison was made between the analysis of the on-site and the laboratory techniques. Results showed that the detection limits of the on-site technique were comparable to those obtained by laboratory methods.

1996-07-01

181

Electron temperature diagnostics in the RFX reversed field pinch experiment  

Energy Technology Data Exchange (ETDEWEB)

The paper presents an integrated approach to the problem of electron temperature diagnostics of the plasma in a reversed field pinch. Three different methods, sampling different portions of the electron distribution function, are adopted, namely Thomson scattering, soft X-ray spectroscopy by pulse-height analysis and filtered soft X-ray intensity ratio. A careful analysis of the different sources of systematic errors is performed and a novel statistical approach is adopted to mutually validate the three independent measurements. A satisfactory agreement is obtained over a large range of experimental conditions, indicating that in the plasma core the energy distribution function is well represented by a maxwellian. (author)

2000-08-01

182

Determination of fast neutron flux distribution in irradiation sites of the Malaysian Nuclear Agency research reactor  

British Library Electronic Table of Contents (United Kingdom)

Determination of thermal to fast neutron flux ratio (ffast) and fast neutron flux (phi-fast) is required for fast neutron reactions, fast neutron activation analysis, and for correcting interference reactions. The ffast and subsequently phi-fast were determined using the absolute method. The ffast ranged from 48 to 155, and the phi-fast was found in the range 1.03x1010-4.89x1010 n cm-2 s-1. These values indicate an acceptable conformity and applicable for installation of the fast neutron facility at the MNA research reactor.

2011-01-01

183

Coating of metallic membranes by pulsed laser deposition; Beschichtung von metallischen Membranen mittels Pulsed Laser Deposition  

Energy Technology Data Exchange (ETDEWEB)

There is increasing demand to functionalize meso- and nano-porous materials by coating and make the porous substrate biocompatible or environment friendly. However, coating on a meso-porous substrate poses great challenges, especially if the pore aspect ratio is high. In the current work the pulsed laser deposition (PLD) method is used for coating Ni{sub 3}Al-based meso-porous membranes with diamond-like carbon (DLC) layers of high thickness homogeneity and adhesion. (orig.)

2008-08-15

184

An estimation method for basemat uplift behavior of nuclear power plant buildings  

Energy Technology Data Exchange (ETDEWEB)

It is important to accurately estimate the effects of strong earthquake motions on the basemat uplift behavior and structural responses for the seismic design of nuclear power plant buildings. In this paper, an analysis model which describes the soil part using the 3 dimensional FEM was proposed to be used when the ground contact ratio is low, and the validity of this model was confirmed. Furthermore, investigations using the model were carried out where the attaching force under the basemat was taken into account, in order to more realistically estimate the basemat uplift behavior. The effects in the case of the building being embedded were also investigated.

2007-07-15

185

An estimation method for basemat uplift behavior of nuclear power plant buildings  

International Nuclear Information System (INIS)

It is important to accurately estimate the effects of strong earthquake motions on the basemat uplift behavior and structural responses for the seismic design of nuclear power plant buildings. In this paper, an analysis model which describes the soil part using the 3 dimensional FEM was proposed to be used when the ground contact ratio is low, and the validity of this model was confirmed. Furthermore, investigations using the model were carried out where the attaching force under the basemat was taken into account, in order to more realistically estimate the basemat uplift behavior. The effects in the case of the building being embedded were also investigated.

2007-07-01

186

Henry`s law gas-solid chromatography and correlations of virial coefficients for hydrocarbons, chlorofluorocarbons, ethers, and sulfur hexafluoride adsorbed onto carbon  

Energy Technology Data Exchange (ETDEWEB)

Gas-solid chromatography was used to determine the Henry`s law second gas-solid virial coefficients within the temperature range of 314--615 K for ethane, propane, butane, isobutane, pentane, hexane, heptane, chloromethane, dichloromethane, trichloromethane, tetrachloromethane, trichlorofluoromethane (Freon 11), chlorodifluoromethane (Freon 22), dichlorodifluoromethane (Freon 12), methyl ether, ethyl ether, and sulfur hexafluoride with Carbopack B, a microporous carbon adsorbent. The temperature dependence of the second gas-solid virial coefficients of these adsorbates was used in conjunction with analyses based on a graphical method, a single-surface numeric integration method, a single-surface analytic expression method, and a two-surface analytic expression method to determine the gas-solid interaction energies and other parameters. The interaction energies were correlated with a ...

1995-07-01

187

A novel method for solving lithium carbonate pellet by binary-acid for tritium production rate measurement by liquid scintillation counting technique  

International Nuclear Information System (INIS)

Lithium carbonate pellets are frequently used for estimation of tritium production rate in irradiated samples in fusion blanket neutronics experiment and the activity is measured by liquid scintillation counting technique. In this measurement, it is essential to solve the lithium carbonate pellet as much as possible and to mix the pellet solution into scintillation cocktail homogeneously at stable condition. For this purpose, a novel binary-acid method has been developed to solve lithium carbonate and to mix the pellet solution into scintillation cocktail. High solubility is attained by adopting two acids, HNO_3 and CH_3COOH, and a good compatibility of the pellet solution with scintillator is obtained by emulsion cocktail resulting in high counting efficiency. Defining a product of dissolved mass and counting efficiency as a Figure of Merit (FOM), the present method has higher FOM value than the conventional method and is ...

188

/sup 252/Cf-source-driven neutron noise analysis measurements for coupled uranium metal cylinders  

Energy Technology Data Exchange (ETDEWEB)

The /sup 252/Cf-source-driven neutron noise analysis method for obtaining the subcriticality of an assembly of fissile material from cross-power spectral densities (CPSDs) was developed to avoid some difficulties inherent in other measurement methods. This method requires measurement of frequency-dependent CPSD between a pair of detectors in or near the fissile assembly and CPSDs between these detectors and a source of correlated neutron noise from an ionization chamber containing /sup 252/Cf, also in or near the fissile assembly. Also, the auto-power spectral density of the source is required. The ratio of spectral densities is then formed and is related to the subcriticality. To date various measurements have been performed which demonstrate the usefulness of the method including measurements with single uranium metal cylinders. The experiments described here, which used coupled ...

1985-01-01

189

Trace analysis in cadmium telluride by heavy ion induced X-ray emission and by SIMS  

International Nuclear Information System (INIS)

The possibilities of using both selective heavy ion induced X-ray emission and secondary ion mass spectroscopy (SIMS), for the identification of impurities present at low concentrations in cadmium telluride are examined. The relative concentrations of the impurities along CdTe crystals have been determined by exciting the X-ray emission of the elements in several slices with Ar and Kr ions and by comparing the relative characteristic X-ray emission yields. As a consequence of the quasimolecular inner shell ionization mechanism in heavy ion-atom collisions, Ar and Kr ions allow a strong excitation of the main impurities seen by SIMS namely Si, Cl and Ge, As, with only a minor contribution of Cd and Te. From the changes of the concentrations of the various impurities along the crystal, informations about segregation coefficients and compensation can be obtained.

2007-02-01

190

Studies on biosorption and toxicity of heavy metals in bacteria; Untersuchungen zur Biosorption und zur Toxizitaet von Schwermetallen auf Bakterien  

Energy Technology Data Exchange (ETDEWEB)

Biosorption behaviour of and toxic effects of heavy metals in submersed and immobilised microorganisms was studied in batches and in continuous processes in an airlift-recycle reactor. Nickel, cadmium, and zinc were used as heavy metals. (orig./VHE) [Deutsch] Am Beispiel einer Naphthalin-2-sulfonsaeure-abbauenden Kultur wurde das Biosorptionsverhalten und die toxische Wirkung von Schwermetallen auf submerse und immobilisierte Mikroorganismen im Batch-Ansatz und im kontinuierlichen Betrieb in einem Airlift-Schlaufenreaktor untersucht. Als Schwermetalle wurden Nickel, Cadmium und Zink eingesetzt. (orig./VHE)

1993-09-01

191

Roles of biomarkers in evaluating interactions among mixtures of lead, cadmium and arsenic  

British Library Electronic Table of Contents (United Kingdom)

Human exposure to environmental chemicals is most correctly characterized as exposure to mixtures of these agents. The metals/metalloids, lead (Pb), cadmium (Cd), and arsenic (As), are among the leading toxic agents detected in the environment. Exposure to these elements, particularly at chronic low dose levels, is still a major public health concern. Concurrent exposure to Pb, Cd, or As may produce additive or synergistic interactions or even new effects that are not seen in single component exposures. Evaluating these interactions on a mechanistic basis is essential for risk assessment and management of metal/metalloid mixtures. This paper will review a number of individual studies that addressed interactions of these metals/metalloids in both experimental and human exposure studies with...

2008-01-01

192

Development of engineering technology basis for pyrometallurgical reprocessing: development of transport technology and pyro-process equipments  

International Nuclear Information System (INIS)

Development of the engineering technology basis of pyrometallurgical reprocessing is a key issue for industrialization. For development of the transport technologies of molten salt and liquid cadmium at around 773 K, a salt transport test rig and a metal transport test rig were newly installed in an Ar glove box. Function of the salt transport test rig was confirmed with LiCl-KCl molten salt, and the transport behaviour of molten salt was found to follow that of water. The molten salt/liquid metal contactor for Ln/An separation was newly designed and installed. The test with a single-stage contactor was successful with simulated elements, and a three-stage contactor is now under development. A large-scale electro-refiner with a function to transport molten salt and liquid cadmium were newly designed, and to be installed for demonstration test with simulated materials. (authors)

2006-09-25

193

A 1500-year record of lead, copper, arsenic, cadmium, zinc level in Antarctic seal hairs and sediments  

British Library Electronic Table of Contents (United Kingdom)

To reconstruct the profiles of heavy metal levels in the South Ocean ecosystem of Antarctica, the concentrations of lead (Pb), copper (Cu), arsenic (As), cadmium (Cd), and zinc (Zn) in seal hairs and lake sediments spanning the past 1500?years from Fildes Peninsula of King George Island and in weathering lake sediments from Nelson Island of West Antarctica were determined. The lead contents in the seal hairs and the weathering sediments show a sharp increase since the late 1800s, very likely due to anthropogenic contamination from modern industries. After the 1980s, the Pb content in seal hairs dropped by one-third, apparently due to the reduced usage of leaded gasoline in the Southern Hemisphere. Copper arises mainly from the weathering process, and its level may be substantially affected...

2006-01-01

194

Symbiotic N2 fixation by legumes growing in pots. 2. Uptake of VN-labelled NO3 , C2H2 reduction and H2 evolution by Trifolium subterraneum L. , Medicago truncatula Gaertn. and Acacia dealbata Link  

Energy Technology Data Exchange (ETDEWEB)

The objectives of this study were to estimate symbiotic nitrogen fixation by two common pasture legumes, Trifolium subterraneum L. and Medicago truncatula Gaertn., and an Australian native legume, Acacia dealbata Link, growing in pots using an indirect isotopic method. This method was also used to calibrate the C2H2 reduction assay of the intact plants. In addition, hydrogen evolution was measured in an attempt to explain the variations in C2H2:N2 ratios between the species. 25 refs.; 1 figure; 4 tabs.

1983-01-01

195

Subcritical measurements with a cylindrical tank of Pu-U nitrate  

Energy Technology Data Exchange (ETDEWEB)

This series of measurements with a mixed Pu-U nitrate solution (280 g Pu/liter, 180 g U/liter) in a 35.54-cm-diam cylindrical tank provides a wide variety of experimental data for subcritical configurations that can be used to verify calculational methods and nuclear data. The Pu contained 7.85 wt% {sup 240}Pu and the uranium was natural uranium. The measurements performed were: inverse count rate, prompt neutron decay constants, inverse kinetics, and frequency analysis by the {sup 252}Cf source driven method. These data are presented in sufficient detail that the results of the experiments can be calculated directly. For purposes of extrapolating to the delayed critical height the ratio of spectral densities was linear with height and thus provided the best estimate of critical height.

1997-04-01

196

Statistical estimation of the lifetimes of charmed particles  

Energy Technology Data Exchange (ETDEWEB)

Various statistical methods for the estimation of the mean lifetimes of charmed particles have been considered. It is shown that the usual estimates of the maximum likelihood in some cases do not exist or may have rather great positive bias, if the statistics are low. Alternative estimates of the mean lifetime tau are discussed. Among them the 'jackknife' estimate of tau is considered. The minimum variance unbiased estimates of the average rate of decay 1/tau have been derived for some particular cases. It is also shown that the usual estimate of the ratio of the mean lifetimes of different kinds of particles may also have a bias when the statistics are poor. Two methods of reducing this bias have been proposed.

1984-12-15

197

Silver nanoparticles prepared by chemical reduction-protection method, and their application in electrically conductive silver nanopaste  

Energy Technology Data Exchange (ETDEWEB)

Ag nanoparticles were prepared in a water-phase system with a mixture of silver-ammonia complex, sodium borohydride, and lauric acid according to molar feed ratio of approximately 6:3:1. The mechanism of preparation and separation by chemical reduction-protection method was explored. The as-synthesized Ag nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and UV-vis spectroscopy, respectively. It was found that the size of high purity Ag particles was ranging from 30 to 50 nm with slight agglomeration. In addition, the as-synthesized wet Ag nanoparticles were dispersed stably in organic vehicle to formulate electrically conductive nanopaste. Upon direct-written and sintered, the array pattern of the nanopaste with the resolution of about 30 {mu}m was achieved with the electrical resistivity in the order of magnitude of 10{sup -5} {Omega} cm.

2010-04-02

198

On the statistical estimation of the lifetimes of charmed particles  

Energy Technology Data Exchange (ETDEWEB)

Various statistical methods for the estimation of the mean lifetimes of charmed particles have been considered. It is shown that the usual estimates of the maximum likelihood in some cases do not exist or may have rather great positive bias, if the statistics are low. Alternative estimates of the mean lifetime tau are discussed. Among them the 'jackknife' estimate of tau is considered. The minimum variance unbiased estimates of the average rate of decay 1/tau have been derived for some particular cases. It is also shown that the usual estimate of the ratio of the mean lifetimes of different kinds of particles may alos have a bias when the statistics are poor. Two methods of reducing this bias have been proposed. (orig.).

1984-12-15

199

No evidence of over-reporting of SARS in mainland China  

British Library Electronic Table of Contents (United Kingdom)

Summary Objective To find out whether there was over-reporting of SARS patients in mainland China in view of the relatively low case fatality ratio in mainland China, in comparison with other affected countries and areas. Methods We searched PubMed for all SARS antibody detection papers (in English or Chinese language) using the keywords `SARS' and `antibody'. Then the resulting articles were further read through to select the SARS detection results using ELISA methods of serum samples collected at least 1 month after disease onset. A multi-level logistic regression was applied to test for possible differences in the proportions positive between locations of the study. Results A total of 48 studies were identified, including 39 from mainland China and nine from elsewhere (Hong Kong, Taiwan...

2009-01-01

200

Mode shape and natural frequency identification for seismic analysis from background vibration  

International Nuclear Information System (INIS)

Background vibration in a CANDU plant can be used to determine the dynamic characteristics of major items of equipment, such as calandria, the fuelling machines and the primary heat transport pumps. These dynamic characteristics can then be used to verify the seismic response of the equipment which, at present, is based on theoretical models only. The feasibility and basic theory of this new approach (which uses accelerations measured at several points on a structure and does not require knowledge of the source of excitation) was established in Phase I of the study. This report is based on Phase II in which the methods of analysis developed in Phase I were improved and verified experimentally. A Fast Fourier Transform (FFT) algorithm was incorporated and an interactive curve fitting technique was developed to obtain the dynamic characteristics in the form of natural frequencies, mode shapes and damping ratios. The method is ...

1984-02-06

201

Method of reducing volume of radioactive liquid waste  

International Nuclear Information System (INIS)

Purpose: To enable the solidification of liquid waste containing radioactive substance in a free shape with large volume reduction ratio without a pulverizing step by producing solute in the liquid waste as a slurry in a predetermined organic solvent and forming it into a cake by mechanical exfoliation. Method: Liquid waste containing suitably concentrated radioactive substances is supplied to a centrifugal thin film evaporator together with an organic agent having a higher boiling point than water and a non aqueous solution to evaporate the water content, the solute in the waste is produced as a slurry in the organic solvent, and removed as cake-state solute slightly residued with the organic solvent by the mechanical exfoliation such as centrifugal exfoliation or settling exfoliation from the slurry-state liquid. Accordingly, it can be increased in size as compared with the powder reduced in volume of the radioactive liquid waste, and can be ...

1981-08-01

202

Mechanism of nanocapsules of Matricaria recutita L. extract formation by the emulsion-diffusion process  

British Library Electronic Table of Contents (United Kingdom)

Nanocapsules coated by medicinal plants have many applications in drug manufacturing. Medicinal plants can be loaded on nanocapsules with polyesteric triblock copolymer poly ethylene glycol-poly butylene adipate-poly ethylene glycol (PEG-PBA-PEG) as shell and olive oil can be introduced as a core of nanocapsules by a method known as polymer deposition solvent evaporation method. In this research, first, certain amount of polymer, Matricaria recutita extract and olive oil were mixed with acetone and then, water was added to the solution using magnetic stirrer. After which the acetone was removed by vacuuming and finally nanocapsules were found by freezing-drier. The study showed the size of nanocapsules depends on variety of factors such as the ratio of polymer to oil and concentration of p...

2011-01-01

203

Elastic properties, hardness and indentation fracture toughness of #beta#-sialons  

International Nuclear Information System (INIS)

Dense samples of #beta#-sialons (with z from 1 to 4) were pressuressly sintered for different time (15-240 minutes) and at relatively low temperature of 1600 C using single-phase #beta#-sialon powders synthesized by combustion nitridation. The samples were characterized using ultrasonic method for determination of elastic properties (E,G,#mu#). Also, hardness by Knoop and fracture toughness by Vickers indentation microfracture method was estimated. With increasing z number Young's modulus decreases from 293 to 179 GPa. Simultaneously Poisson ratio increases by about 30%. The highest values of hardness and fracture toughness were obtained for sialon with z equal to 1. (orig.).

1993-10-04

204

Effects of multiwall carbon nanotubes on the thermal and mechanical properties of medium density polyethylene matrix nanocomposites produced by a mechanical milling method  

British Library Electronic Table of Contents (United Kingdom)

Medium-density polyethylene/multiwall carbon nanotube (MDPE/MWCNT) nanocomposites were produced by a mechanical milling method using a high-energy ball mill. The MDPE and MWCNTs were added to the ball mill at a constant 20:1 weight ratio of ball/powders and milled for 10 h to obtain polyethylene matrix nanocomposites reinforced with 0.5, 1, 2.5, and 5 weight percent of MWCNTs. To clarify the role of both MWCNT content and milling time on the morphology of MDPE, some nanocomposite samples were investigated by using a scanning electron microscope. To evaluate the role of milling on the microstructure of the nanocomposites, very thin films of MDPE/MWCNTs were prepared and studied by transmission electron microscopy. Thermal behavior of these nanocomposites was investigated by using differenti...

2010-01-01

205

Combined effect of magnetic field and heat absorption on unsteady free convection and heat transfer flow in a micropolar fluid past a semi-infinite moving plate with viscous dissipation using element free Galerkin method  

British Library Electronic Table of Contents (United Kingdom)

The fully developed electrically conducting micropolar fluid flow and heat transfer along a semi-infinite vertical porous moving plate is studied including the effect of viscous heating and in the presence of a magnetic field applied transversely to the direction of the flow. The Darcy-Brinkman-Forchheimer model which includes the effects of boundary and inertia forces is employed. The differential equations governing the problem have been transformed by a similarity transformation into a system of non-dimensional differential equations which are solved numerically by element free Galerkin method. Profiles for velocity, microrotation and temperature are presented for a wide range of plate velocity, viscosity ratio, Darcy number, Forchhimer number, magnetic field parameter, heat absorption ...

2010-01-01

206

Barium carbonate sediment sampling for inorganic dissolved carbon using isotope mass ratio spectrometer  

International Nuclear Information System (INIS)

This paperwork explain the method of water sampling to obtain the precipitate of BaCO3 solutions that will be used to analyze 13C from field work in Kelana Jaya, Selangor, Langkawi, Kedah and Taiping, Perak. The sampling involves collecting of water samples for groundwater from boreholes and surface water from canal, river, pond and ex-mining pond from several locations at the study sites. This study also elaborates the instruments and chemicals used. The main purpose of this sampling is to obtain the precipitate of BaCO3 for 13C analysis of dissolved inorganic carbon (DIC). A correct sampling method according to standard is very important to ensure an accurate and precise result. With this, the data from the laboratory analysis result can be fully utilized to make the interpretation of the pollutants movement. (Author)

2009-10-06

207

A novel method of single step hydrophobic interaction chromatography for the purification of phycocyanin from Phormidium fragile and its characterization for antioxidant property  

British Library Electronic Table of Contents (United Kingdom)

Phycocyanin - a major phycobiliprotein constitutively produced by many cyanobacteria hold several promising applications in diagnostics, biomedical research, and therapeutics. This paper discusses a novel rapid method for the purification of cyanobacterial phycocyanin (C-PC) from Phormidium fragile using hydrophobic interaction chromatography. The protein was extracted and concentrated by grinding under liquid nitrogen and ammonium sulfate fractionation. C-PC was purified by single step hydrophobic interaction chromatography. Purified phycocyanin showed absorbance maximum (lmax) at 624nm. The criterion of purity (R) achieved was 4.52. Phycocyanin to phycoerythrin and phycocyanin to allophycocyanin purity ratio were 3.85 and 7.49, respectively. The purified protein showed a pI of 5.2 and ha...

2008-01-01

208

"9"9"mTechnetium-heat damaged erythrocyte spleen scan  

International Nuclear Information System (INIS)

"9"9"mTechnetium -heat damaged erythrocyte were used as spleen scanning agents in 12 patients from July, 1985 to April, 1986. We used this scan to evaluate situs inversus, asplenia, accessory spleen, hypersplenism, splenic infarction, tumor staging and evaluation of therapy, especially when the "9"9"mTc-tin colloid scans were not definite for diagnosis. The techniques applied to these scans were in vivo/in vitro-labeling method and heating-method to damage the erythrocytes. Liver-to-spleen uptake ratios were increased upto 100:1 and interference from the left lobe of the liver was eliminated. These scans were helpful to evaluate the spleen. (Author).

209

An empirical and computational method for performance evaluation of vertical axis wind energy capture system  

Science.gov (United States)

This Dissertation presents the author's investigation and development of a systematic method for evaluating the aerodynamic performance of Vertical Axis Wind Energy Capture Systems (WECS) apart from their electrical generation capability. The current standard method for specifying a wind energy machine is to discuss its rated power in kilowatts (or megawatts when capacity exceeds 100 kW). While this holistic method is effective for comparing machines it does not reveal the essential characteristics necessary for optimization of individual machine components. The method developed herein separates the performance characteristics of the WECS from the generation characteristics and isolates them for benchmarking and optimization. In order to develop an evaluation criterion, it was essential to evaluate and benchmark the current state of the art for wind energy capture. A thorough history of Vertical Axis ...

2010-01-01

210

Emplacement ages of Jurassic-Cretaceous South African kimberlites by the Rb-Sr method on phlogopite and whole-rock samples  

International Nuclear Information System (INIS)

Rb-Sr phlogopite age determinations, interpreted as emplacement ages, are reported for 15 southern African kimberlites. Jagersfontein and Rietfontein (85 and 95 Ma) have ages typical of the majority of well-known Cretaceous kimberlites, whereas somewhat older ages of about 118 to 125 Ma have been obtained for localities in the Postmasburg, Barkly West and Boshoff districts. Previous zircon ages of 90Ma for Finsch and Roberts Victor are believed to be incorrect. Two other localities in the Barkly West area have significantly younger emplacement ages of about 114 Ma relative to most Barkly West occurrences. Two off-craton kimberlites, Uintjiesberg and Mzongwana, are 100 and 150 Ma in age respectively. Swartruggens and Elandskloof have ages of 150-160 and 165 Ma respectively. A Barkly West occurrence, Klipfontein, also has an apparent age of 160 Ma, but this result cannot be considered reliable. The emplacement ages and initial "8"7Sr/"8"6Sr ratios of southern African ...

211

Characteristics of meningioma scintigraphy with multiple brain imaging agents  

International Nuclear Information System (INIS)

Purpose: To clarify the characteristics of meningioma scintigraphy with multiple brain imaging agents and to evaluate their roles in diagnosis of meningiomas. Methods: Blood flow, "9"9"mTc-ECD, "9"9"mTc-DTPA, and/or "9"9"mTc-MIBI brain imagings were performed in 21 patients with meningiomas (3 malignant, 18 benign) proved by surgery and pathology. CT/MRI examinations were also made within one month. Characteristics of meningioma images were analyzed and uptake ratios were calculated. Results: In 16 of 20 patients, increased radioactivity during the arterial phase in the blood flow image was seen. Concave round or oval defects with smooth contour in the cerebral cortex were observed in 17 of 19 patients with "9"9"mTc-ECD, depression of frontoparietal cortex was found in one case and no abnormality in the other. A homogeneous accumulation of radioactivity in area corresponding to the defect in "9"9"mTc-ECD image was found in 17/17 patients with ...

1998-08-01

212

Comparative studies on titanium and tantalum oxides thin film structures for laser mirrors, deposited by ion assisted gun  

International Nuclear Information System (INIS)

For obtaining radiation less damagable laser mirrors, a preliminary optimization of film fabrication suitable for the analysis of laser damage mechanism has been done as the first step. Here, the optimization requires not only the stable fabrication process but also the ideal film structure i.e., the amorphous and smooth film structure simultaneously, eliminating latently unwanted secondary effects such as light scattering during laser damage test. For this purpose, we adopted the ion assisted deposition (IAD) method and modified the deposition conditions for titanium and tantalum oxide films, both of which compose typical high index layers, and where SiO_2 layers are also chosen as low index layers because of their amorphous and smooth nature, in alternative multilayer laser mirrors. Surface and cross sectional film structures and film crystallinity are compared and characterized, using a high resolution SEM and a x-ray diffractometer, respectively. The ...

1996-10-07

213

Physics of the {sup 252}Cf-source-driven noise analysis measurement  

Energy Technology Data Exchange (ETDEWEB)

The {sup 252}Cf-source-driven noise analysis method is a versatile measurements tool that has been applied to measurements for initial loading of reactors, quality assurance of reactor fuel elements, fuel processing facilities, fuel reprocessing facilities, fuel storage facilities, zero-power testing of reactors, verification of calculational methods, process monitoring, characterization of storage vaults, and nuclear weapons identification. This method`s broad range of application is due to the wide variety of time- and frequency domain signatures, each with unique properties, obtained from the measurement. The following parameters are obtained from this measurement: average detector count rates, detector multiplicities, detector autocorrelations, cross-correlation between detectors, detector autopower spectral densities, cross-power spectral densities between detectors, coherences, and ratios of ...

1997-02-01

214

Mode-locked YAG-Nd ring laser with unidirectional stimulated emission  

Energy Technology Data Exchange (ETDEWEB)

The traveling-wave mode in ring lasers is achieved by two methods: by a reversing mirror, and by using an intracavity nonreciprocal device. This paper is devoted to realization of the traveling-wave mode in a mode-locked YAG-Nd ring laser by a method proposed by Tomov et al. This method uses two intracavity Q-switches. In mode-locked operation, pulses are generated that can be considered short compared with the period of modulation T = L/C (where L is the length of the perimeter of the cavity). Analysis shows that if the shift of the switching signals corresponds to the time of travel of a light pulse between Q-switches, the pulse in one direction will pass the Q-switches at instants of zero losses, while losses in the other direction will be maximized for a distance between Q-switches of L/4, and will be zero for a distance L/2. Experimental verification of the proposed method gave unidirectional ...

1981-05-01

215

Measurement of "1"0"1Tc Half-Life  

International Nuclear Information System (INIS)

75 mg (NH_4)_6Mo_7O_24 #centre dot# 4H_2O solution was irradiated for 20 min in miniature neutron source reactor (MNSR) and cooled for 12 min. In the conditions of 0.8 mol/L HNO_3, phase ratio 1:1, the solution of "1"0"1Tc sample was extracted twice with #alpha#-benzoin oxime/ethyl acetate phase to remove "1"0"1Mo and a radiochemically pure and carrier-free "1"0"1Tc product was obtained. The half-life of "1"0"1Tc was accurately measured with a HPGe #gamma#-detector by following 306.8 keV #gamma#-ray about 150 min, and processed the data by three methods, R-value method, iterative method and translation method. Five parallel measurments gave a half-life (14.02 #+-# 0.01) min (n=5) for "1"0"1Tc. (authors)

2009-11-01

216

Determination of binary mixtures of analgesic and spasmolytic drugs in pure and dosage forms by derivative spectrophotometry.  

Science.gov (United States)

Binary mixtures of dipyrone and pitophenone hydrochloride are assayed by zero-crossing second- and third-derivative spectrophotometry and by ratio-spectra first- and second-derivative spectrophotometry. In the first method, calibration plots are linear at 266.5 and 302.5 nm (dipyrone, second derivative), and 257 and 286 nm (pitophenone second derivative) and 242 and 278.3 nm (dipyrone third derivative), and 228.5 and 300 nm (pitophenone, third-derivative). By the second method, lines of regression are linear at 235 and 262 nm (dipyrone, first derivative), and 229.5 and 288.5 nm (pitophenone, first-derivative), and 249.7 and 268 nm (dipyrone, second derivative), and 280.5 and 300 nm (pitophenone, second-derivative). In all methods calibration curves follow the Beer's law up to 40 microg/ml of each drug. LOD and LOQ values were calculated. The developed derivative spectrophotometric ...

2003-10-15

217

A technique for the fast calculation of three-dimensional photon dose distributions using the superposition model  

International Nuclear Information System (INIS)

Techniques for reducing computation time in 3D photon dose calculations are addressed with specific emphasis given to the convolution/superposition approach. A single polyenergetic superposition model calculating absorbed dose per incident photon fluence (Gy cm"2) was developed in terms of TERMA and a total energy deposition kernel (a total point spread function). A novel approach was devised for reducing calculation time. The method, named the CF method, was based on the use of a conventional, fast model (here a modified power-law method was used) for the generation of 3D dose distributions on a fine dose matrix. Superposition calculations were carried out on a coarse matrix and calculation speed was increased simply by reducing the number of calculations. A set of correction factors was derived on the coarse grid from the ratio of the dose values from superposition to those from the conventional ...

1997-08-01

218

A convolution/superposition method using primary and scatter dose kernels formed for energy bins of X-ray spectra reconstructed as a function of off-axis distance: comparison of calculated and measured 10-MV X-ray doses in thorax-like phantoms  

British Library Electronic Table of Contents (United Kingdom)

We performed experimental studies on the convolution/superposition method reported in the former companion paper (Iwasaki in Radiol Phys Technol 4, 2011) using 10-MV X-ray beams from open-jaw-collimated fields. The method uses primary and scatter dose kernels formed for energy bins of X-ray spectra reconstructed as a function of off-axis distance. We made a comparison of calculations and measurements in water phantoms and thorax-like phantoms with respect to percentage depth dose curves, tissue???phantom ratio curves, and dose profiles. We made the dose calculation by taking into account the beam-hardening effect with depth and the off-axis radiation-softening effect. We found that the method could be used, in general, for performing accurate dose calculations.

2011-01-01

219

The separation and determination of trace elements in iron ore  

International Nuclear Information System (INIS)

The separation, concentration, and determination of trace elements in iron ores are described. After the sample has been dissolved, the iron is separated by liquid-liquid extraction with a liquid cation-exchanger, di-(2-ethylhexyl) phosphoric acid. The trace elements aluminium, cadmium, calcium, chromium, cobalt, copper, lead, magnesium, manganese, mercury, potassium, sodium, vanadium, and zinc are determined in the aqueous phase by atomic-absorption spectrophotometry.

2008-05-01

220

Indium-cadmium-oxide films having exceptional electrical conductivity and optical transparency: Clues for optimizing transparent conductors  

UK PubMed Central (United Kingdom)

Materials with high electrical conductivity and optical transparency are needed for future flat panel display, solar energy, and other opto-electronic technologies. InxCd1-xO...Full Text Available

2001-06-19

221

Identification of Thlaspi caerulescens Genes That May Be Involved in Heavy Metal Hyperaccumulation and Tolerance. Characterization of a Novel Heavy Metal Transporting ATPase1  

UK PubMed Central (United Kingdom)

Thlaspi caerulescens is a heavy metal hyperaccumulator plant species that is able to accumulate extremely high levels of zinc (Zn) and cadmium (Cd) in its shoots (30,000 μg...Full Text Available

2004-11-01

222

Heavy Metals in selected Edible Vegetables and their daily intake in Sanandaj, Iran  

Energy Technology Data Exchange (ETDEWEB)

The levels of four different heavy metals [cadmium (Cd), lead (Pb), chromium (Cr) and copper (Cu)] were determined in various vegetables [leek (Allium ampeloprasum), sweet basil (Ocimum basilicum), parsley (Petroselium cripsum), gardem cress (lepidium sativum) and tarragon (Artemisia dracuncullus)] cultivated around the Sanandaj city. (Author)

2009-07-01

223

Heavy Metals in selected Edible Vegetables and their daily intake in Sanandaj, Iran  

International Nuclear Information System (INIS)

The levels of four different heavy metals [cadmium (Cd), lead (Pb), chromium (Cr) and copper (Cu)] were determined in various vegetables [leek (Allium ampeloprasum), sweet basil (Ocimum basilicum), parsley (Petroselium cripsum), gardem cress (lepidium sativum) and tarragon (Artemisia dracuncullus)] cultivated around the Sanandaj city. (Author)

224

Final Report: Planetary Instrument Definition and Design Program (PIDDP) Support Project  

Energy Technology Data Exchange (ETDEWEB)

The results of Sandia National Laboratories' participation in the NASA Planetary Definition and Design Program are summarized. Areas reported include the characterization of large area cadmium zinc telluride spectrometers and the application of simulation techniques to the prediction of device performance. Also investigated was the response of mercuric iodide devices in the region from 1 to 100 KeV. A literature study to determine the status or radiation damage measurements in room temperature semiconductor devices is also reported.

1999-03-01

225

Preparation and characteristics of rice-straw-based porous carbons with high adsorption capacity  

Energy Technology Data Exchange (ETDEWEB)

To prepare porous carbons with high adsorption capacity from rice straws, two different kinds of precursors, i.e. one as the raw rice straws (one-stage process) and the other as pre-carbonized rice straws (two-stage process), were active with KOH of various impregnation ratios. The two-stage process was found very effective for manufacturing porous carbons with high surface area and adsorption capacities for MB and I{sub 2}. For example, the porous carbon that was carbonized at 700{sup o}C and subsequently activated at 900{sup o}C exhibited the surface area of 2410 m{sup 2}/g, the adsorption capacities of 800 and 1720 mg/g for MB and I{sub 2}, respectively, and the total pore volume of 1.4 ml/g. In the two-stage method, there was a preferential optimum impregnation ratio of KOH to a precursor carbon, i.e. 4:1, with which high surface area of porous carbons could be achieved. The formation of uni- and bidentate carboxylic ...

2002-02-01

226

Evaluation of aseptic loosening of knee prostheses by quantitative bone scintigraphy  

Energy Technology Data Exchange (ETDEWEB)

In not infected knee prostheses bone scintigraphy is a possible method to diagnose mechanical loosening, and therefore, to affect treatment regimes in symptomatic patients. However, hitherto studies showed controversial results for the reliability of bone scintigraphy in diagnosing loosened knee prostheses by using asymptomatic control groups. Therefore, the aim of our study was to optimize the interpretation procedure and to evaluate the accuracy using results from revision surgery as standard. Methods: Retrospectively, we were able to examine the tibial component in 31 cemented prostheses. In this prostheses infection was excluded by histological or bacteriological examination during revision surgery. To quantify bone scintigraphy, we used medial and lateral tibial regions with a reference region from the contralateral femur. Results: to differentiate between loosened and intact prostheses we found a threshold of 5.0 for the maximum tibia to ...

2008-07-01

227

Evaluation of aseptic loosening of knee prostheses by quantitative bone scintigraphy  

International Nuclear Information System (INIS)

In not infected knee prostheses bone scintigraphy is a possible method to diagnose mechanical loosening, and therefore, to affect treatment regimes in symptomatic patients. However, hitherto studies showed controversial results for the reliability of bone scintigraphy in diagnosing loosened knee prostheses by using asymptomatic control groups. Therefore, the aim of our study was to optimize the interpretation procedure and to evaluate the accuracy using results from revision surgery as standard. Methods: Retrospectively, we were able to examine the tibial component in 31 cemented prostheses. In this prostheses infection was excluded by histological or bacteriological examination during revision surgery. To quantify bone scintigraphy, we used medial and lateral tibial regions with a reference region from the contralateral femur. Results: to differentiate between loosened and intact prostheses we found a threshold of 5.0 for the maximum tibia to ...

228

Superconducting A-15 Nb_3Ge films produced by reactive evaporation  

International Nuclear Information System (INIS)

The reactive evaporation process was successfully used to deposit films of the A-15 Nb_3Ge phase. This is the first report, to the best of our knowledge, illustrating the use of such processes for the deposition of A-15 compounds. In this process, niobium vapors from an electron-beam-heated evaporation source react with germane gas introduced into the vacuum chamber at low partial pressures (approximately 10"-"4 Torr) to produce Nb_3Ge deposits. The process variables studied were the deposition temperature, the niobium-to-germanium impingement ratio on the substrate and the plasma-enhanced deposition, in this case the activated reactive evaporation process. At low deposition temperatures (below 450"0C) the deposit is amorphous (or microcrystalline) and can be crystallized to the Nb_3Ge phase by heat treatment, e.g. at 850"0C for 1 h in vacuum. The ratio of niobium to germanium in the deposit can be varied by changing the process parameters. The ...

229

Resonance ionization spectroscopy at {sup 240f,242f}Am fission isomers  

Energy Technology Data Exchange (ETDEWEB)

Optical Isotope shift measurements have been performed for the {sup 240f,242f}Am fission isomers to test the stability of nuclear deformation as function of the neutron number. The method is based on resonance ionization spectroscopy (RIS) in a buffer gas cell with fission detection of the ionization process. The {sup 240f,242f}Am fission isomers have been produced by {sup 242}Pu(p, 3n), {sup 242}Pu(d, 2n) reactions, respectively. Relative isotope shift ratios X{sub exp}{sup 242f}(500 nm)=IS{sup 242f,241}/IS{sup 243,241}=41.4(8) and X{sub exp}{sup 240f}(500 nm)=IS{sup 240f,241}/IS{sup 243,241}=39.2(8) were measured. From these ratios a small difference {delta}{beta}{sub 2}{sup 242f,240f}=0.0076(14) of the deformation parameter {beta}{sub 2} can be deduced assuming that the isotope shift between the reference isotopes {sup 241,243}Am is caused by a pure volume change. (orig.)

1997-10-01

230

Rationale for chemical control of feedwater and boiler water. Volume 1. Concentration models. Final report  

Science.gov (United States)

Operating PWR units in the USA have experienced very severe corrosion of the tube support plate at the crevice between the tube and the support. This results in distortion of the plate and crushing of the tube (denting). The first task of this project required that currently available computational methods to estimate the pH attained by concentrating boiler water under various fault conditions such as condenser leakage of river waters and faulty operation of condensate polishing plant. Particular attention has been paid to systems in which sulfate predominates. In the second task, the mechanisms are discussed by which solutions become concentrated in porous deposits on a boiling heat transfer surface. It is concluded that more experimental data are needed to test the validity of existing models. High solution concentrations in the deposit may occur at a heat flux close to the critical value for drying out the base of the deposit. The pore to bulk concentration ...

1984-01-01

231

Rapid toxicity testing based on mitochondrial respiratory activity  

Energy Technology Data Exchange (ETDEWEB)

The need exists for rapid and inexpensive methods to determine the health effects of environmental contaminants on biological systems. One of the current research approaches for assessing cytotoxicity is to monitor the respiratory activity of the mitochondrion, a sensitive, nonspecific subcellular target site. Detected changes in mitochondrial function after the addition of a test chemical could be correlated to toxic effects. Mitochondrial respiration can be characterized by three indices: state 3 and state 4 respiratory rates, and the respiratory control ratio (RCR). State 4, the idle or resting state, results when coupled mitochondrial respire in a medium containing inorganic phosphate and a Kreb's cycle substrate in the absence of a phosphate acceptor such as adenosine diphosphate (ADP). In the presence of ADP the respiration rate increases to a maximum (state 3), accompanied by phosphorylation of ADP to adenosine triphosphate ...

1990-05-01

232

Phosphate/UO{sub 2} interaction during in vitro dissolution of inhalable particles in a medium simulating the phagolysosomal compartment  

Energy Technology Data Exchange (ETDEWEB)

Qualitative and quantitative methods have been developed to relate phosphate/UO{sub 2} interactions and U dissolution, in vitro, in a medium containing 0 or 10 mM phosphate concentrations at pH 5. This was performed by Energy Dispersive X ray Spectrometry (EDS) at 200 kV on entire particles and by fluorimetric measurement. The U dissolution rate was larger in a medium without phosphate than in a medium containing 10 mM phosphate. During the first day, the initial U dissolution involved 80.55% and 91.13% of the powder in media with and without phosphate respectively. From 5 to 15 d after beginning the assay, the dissolution half-times were longer than 92 d and 22 d for media with and without phosphate. EDS analyses have shown a constant P/U X ray intensity ratio for reference U{sub 2}O(PO{sub 4}){sub 2} for the same range of particle diameter. A gradual increase of this ratio was measured for UO{sub 2} incubated in a 10 mM ...

1998-07-01

233

Performance of bentonite/crushed rock borehole plugs  

International Nuclear Information System (INIS)

A mixture of crushed rock and bentonite is being considered as backfill and sealant for high-level nuclear waste repositories. Many variables affect the hydraulic conductivity of such a mixture, including the size and shape of the rock particles, method of mixing, water content and density of the clay, and the weight ratio of rock to clay. Mixtures of crushed basalt and bentonite have been tested to determine the relative effects of these variables. Two types of permeameters are used, 20 cm diameter stainless steel permeameters and 10 cm diameter clear PVC permeameters. Plugs are installed as a single lift or in many lifts; the water content of the clay ranged from air-dry (in most cases) to as high as 200%. Preliminary results show that a mixture of 75% crushed basalt and 25% bentonite has a hydraulic conductivity between 1 x 10/sup -9/ cm/s and 2.5 x 10/sup -8/ cm/s. In some cases, preferential flow paths have developed (possibly as a result ...

234

PC/PBT alloy. PC/PBT alloy  

Energy Technology Data Exchange (ETDEWEB)

Polycarbonate (PC), a non-crystalline resin, and polybutylene terephthalate (PBT), a crystalline resin, can be achieved by means of alloying of improving such various properties as chemical resistance, heat and impact resistance, and formability. This paper describes its manufacturing methods, properties, and market trends. A PC/PBT alloy improves the chemical resistance if the PBT composition ratio is high, but reduces thermal deformation temperature and impact strength. It is regarded adequate, therefore, that the PBT component ratio is set to 20% to 30%. The impact strength is improved by adding elastomer as a third component. The national production amount in 1992 was 4,800 tons a year; price per kilogram is 700 to 800 yen; and the main application is interior and exterior parts for automobiles. While PP and urethane are often used for interior and exterior automotive parts, there is a high possibility of transferring ...

1994-04-05

235

Line intensity enhancements in stellar coronal X-ray spectra due to opacity effects  

CERN Document Server

Context. The I(15.01 A)/I(16.78 A) emission line intensity ratio in Fe XVII has been reported to deviate from its theoretical value in solar and stellar X-ray spectra. This is attributed to opacity in the 15.01 A line, leading to a reduction in its intensity, and was interpreted in terms of a geometry in which the emitters and absorbers are spatially distinct. Aims. We study the I(15.01 A)/I(16.78 A) intensity ratio for the active cool dwarf EV Lac, in both flare and quiescent spectra. Methods. The observations were obtained with the Reflection Grating Spectrometer on the XMM-Newton satellite. The emission measure distribution versus temperature reconstruction technique is used for our analysis. Results. We find that the 15.01 A line exhibits a significant enhancement in intensity over the optically thin value. To our knowledge, this is the first time that such an enhancement has been detected on such a sound statistical ...

2008-01-01

236

High precision, in situ oxygen isotope ratio measurements obtained from geological and extra-terrestrial materials using an Isolab 54 ion microprobe  

Energy Technology Data Exchange (ETDEWEB)

We have developed an ion probe technique for the in situ measurement of oxygen isotope ratios, {sup 18}O/{sup 16}O and {sup 17}O/{sup 16}O, with high spatial resolution in polished thin sections of silicate minerals. This technique allows the isotopic analysis of samples as small as picomoles of material which represents only 10{sup -7} of the sample size required by conventional fluorination oxygen isotope measurement methods and thus has wide application to the study of many terrestrial and extra-terrestrial samples that have heterogeneous oxygen isotope compositions on a scale of tens of micrometres. To illustrate the breadth of studies that are made possible by the ion probe, we report here oxygen isotope measurements from an authigenic quartz overgrowth obtained from the Penrith sandstone, UK, and measurements of magnetite grains from the Orgueil and Yamato 82162 carbonaceous chondrites which may be used to constrain possible formation ...

1995-05-01

237

Comparison of intrinsic and extrinsic tracer methods for estimating calcium bioavailability to rats from dairy foods  

International Nuclear Information System (INIS)

Dairy products doubly labeled with 45Ca and 47Ca were used to evaluate an extrinsic labeling procedure for calcium bioavailability determination. Nonfat milk, yogurt, and fresh cheese curd were prepared from caprine milk that was intrinsically labeled with 45Ca. The products were then labeled extrinsically with 47Ca and administered to rats by gavage. The 47Ca to 45Ca ratio in bone and teeth averaged about 1.00 with either milk, yogurt, or CaCl2, but the ratio was about 1.04 when dosed with cheese curd. Ca absorption, determined by whole-body counting of 47Ca, was lower (P less than 0.05) in cheese curd (59%) than in either milk (69%), yogurt (72%), or CaCl2 (72%). Expressed as percent of dose, the absorption of 47Ca was highly correlated with bone 47Ca (r = 0.973) and with bone 45Ca (r = 0.946). Correlation between tibia 47Ca and tibia 45Ca was r = 0.923. For the dairy products tested, our results indicated that extrinsic 47Ca was absorbed ...

238

A characteristic ventricular shape in myelomeningocele-associated hydrocephalus? A CT stereology study  

International Nuclear Information System (INIS)

We measured the volume of the supratentorial ventricles in 39 consecutive children with myelomeningocele (MMC) and associated hydrocephalus, using a stereological method based on the Cavalieri theorem of systematic sampling. We distinguished the following groups: newborns before and after cerebrospinal fluid shunting (14), a somewhat larger group of newborns with an untreated MMC-associated hydrocephalus (25) and a group of shunted children at a mean age of 1.5 years (28). We paid special attention to the shape of the lateral ventricles, looking separately at the anterior and posterior halves. The measurements were compared with a healthy control group (10) and with children with hydrocephalus unrelated to MMC (15). The average volume ratio of the posterior to the anterior half of the lateral ventricles was 1.05 #+-# 0.39 in non-hydrocephalic children, 1.11 #+-# 0.55 in untreated hydrocephalic children without MMC, and 2.15 #+-# 0.65 in ...

239

Safe detection of Co-60. New perspectives in contamination and clearance measurements  

International Nuclear Information System (INIS)

Consistent application of a newly developed coincidence technique to determine activation products in the operation and demolition of nuclear facilities results in very new perspectives in contamination monitoring and clearance measurement of plant components. In particular, it is possible to avoid the critical spread of point-source Co-60 contamination, the so-called hot particles. The CCM (Cobalt Coincidence Measurement) technique includes the coincident detection of prompt-prompt gamma cascades with "6"0Co and other activation products ("1"1"0"mAg, "1"2"4Sb, "2"2Na) with low mass-specific limits for unrestricted clearance. Special features of the technique are the short measurement times, excellent signal-to-noise ratio, and focusing in space achieved. Compared to conventional integral gamma-measurements, the signal-to-background ratio can be improved by 1-2 orders of magnitude. The method can be employed especially ...

240

Validation of reactor core protection system  

International Nuclear Information System (INIS)

Reactor COre Protection System (RCOPS), an advanced core protection calculator system, is a digitized one which provides core protection function based on two reactor core operation parameters, Departure from Nucleate Boiling Ratio (DNBR) and Local Power Density (LPD). It generates a reactor trip signal when the core condition exceeds the DNBR or LPD design limit. It consists of four independent channels adapted a two-out-of-four trip logic. System configuration, hardware platform and an improved algorithm of the newly designed core protection calculator system are described in this paper. One channel of RCOPS was implemented as a single channel facility for this R and D project where we performed final integration software testing. To implement custom function blocks, pSET is used. Software test is performed by two methods. The first method is a 'Software Module Test' and the second method is a ...

2008-10-13

241

Unbiased cut selection for optimal upper limits in neutrino detectors the model rejection potential technique  

CERN Document Server

We present a method for optimising experimental cuts in order to place the strongest constraints (upper limits) on theoretical signal models. The method relies only on signal and background expectations derived from Monte-Carlo simulations, so no bias is introduced by looking at actual data, for instance by setting a limit based on expected signal above the ``last remaining data event.'' After discussing the concept of the ``average upper limit,'' based on the expectation from an ensemble of repeated experiments with no true signal, we show how the best model rejection potential is achieved by optimising the cuts to minimise the ratio of this ``average upper limit'' to the expected signal from the model. As an example, we use this technique to determine the limit sensitivity of kilometre scale neutrino detectors to extra-terrestrial neutrino fluxes from a variety of models, e.g. active galaxies and gamma-ray bursts. We ...

2003-01-01

242

Synthesis and characterization of MoO_3 nanostructures by solution combustion method employing morphology and size control  

International Nuclear Information System (INIS)

Molybdenum oxide nanostructures were synthesized utilizing the solution combustion method where the ammonium molybdate powder and an organic additive were used as precursors. Different organic additives including ethylene diamine tetra-acetic acid (EDTA), polyethylene glycol 200 (PEG 200), sorbitol and urea were used as surfactants in order to investigate the effect of additive structure on morphology and particle size of products. Also various reaction parameters such as the additive/Mo molar ratio, concentration of metal ion in solution, pH of the reaction, and temperature of the synthesis media were changed to study effects on product morphology and size. Outcomes were characterized by Scanning Electron Microscopy (SEM), X-ray diffraction, and Transmission Electron Microscopy (TEM) techniques. Results show a variety of MoO_3 nanoparticles and nanorods produced within the size range of 10-80 nm. Furthermore, microrods and microsheets were ...

2010-05-01

243

Oxidation resistance of C/C composites coated by SiC in premixed methane-air combustion; SiC hifuku sareta C/C konpojietto no metan-kuki yokongo nenshojochu ni okeru taisanka tokusei  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the effects of SiC coating on the oxidation resistance of C/C composites in combusting fields, which are expected to be applied to high temperature structural materials at over 1770K. The coating methods employed were CVD and pack cementation. The time changes in weight loss of the specimens were measured at temperatures of 1770K and 1900K under the equivalence ratio of 0.9 generated by methane-air combustion, and the surface of the specimens before and after the experiment was observed by SEM. Although the weight loss of the specimens coated by the CVD method was minimal, the coating layer was easily peeled off from the substrate. On the other hand, the layer of the specimens coated by the pack cementation method was stable and adhered to the substrate, but the substrate was degraded because of penetration of oxygen through the pores in the layer. To cover the pores, the specimens ...

1997-11-01

244

Nonlinear dynamics of a flexible rotor supported by turbulent journal bearings with couple stress fluid  

Energy Technology Data Exchange (ETDEWEB)

This study presents a dynamic analysis of a rotor supported by two turbulent flow model journal bearings and lubricated with couple stress fluid under nonlinear suspension. The dynamics of the rotor center and bearing center is studied. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The results show that the values of dimensionless parameters l* strongly influence dynamic motions of bearing and rotor centre. It is found that couple stress fluid improve the stability of the system when l* > 0.4 even if the flow of this system is turbulent. We also demonstrated that the dimensionless rotational speed ratios s and the dimensionless ...

2008-08-15

245

Nonlinear dynamics of a flexible rotor supported by turbulent journal bearings with couple stress fluid  

International Nuclear Information System (INIS)

This study presents a dynamic analysis of a rotor supported by two turbulent flow model journal bearings and lubricated with couple stress fluid under nonlinear suspension. The dynamics of the rotor center and bearing center is studied. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The results show that the values of dimensionless parameters l* strongly influence dynamic motions of bearing and rotor centre. It is found that couple stress fluid improve the stability of the system when l* > 0.4 even if the flow of this system is turbulent. We also demonstrated that the dimensionless rotational speed ratios s and the dimensionless ...

2008-08-01

246

Luminescence characteristics for the detection of radiation treatment of shellfish by using isolated minerals  

International Nuclear Information System (INIS)

Seven types of shellfish were irradiated by gamma ray at doses of 0, 3 and 6 kGy. Pulse photo-stimulated luminescence (PPSL) and thermoluminescence (TL) methods were employed to detect the radiation treatment. The screening of irradiation was carried out by the PPSL method followed by identification using the TL technique. Most of the irradiated shellfish were screened out correctly and only a few showed photon counts a bit higher than the lower threshold value by much lower than the upper threshold value. The TL method was employed using minerals isolated from all the control and irradiated shellfish samples by density gradient treatment. Three parameters, integrated intensities of first glow curves (TL1), ratios of first to that of second glow curves (TL1/TL2), and the shapes of maxima of first glow curves, were utilized for the identification of gamma ray treatment of shellfish. (author)

247

Difference Antenna Selection and Power Allocation for Wireless Cognitive Systems  

CERN Document Server

In this paper, we propose an antenna selection method in a wireless cognitive radio (CR) system, namely difference selection, whereby a single transmit antenna is selected at the secondary transmitter out of $M$ possible antennas such that the weighted difference between the channel gains of the data link and the interference link is maximized. We analyze mutual information and outage probability of the secondary transmission in a CR system with difference antenna selection, and propose a method of optimizing these performance metrics of the secondary data link subject to practical constraints on the peak secondary transmit power and the average interference power as seen by the primary receiver. The optimization is performed over two parameters: the peak secondary transmit power and the difference selection weight $\\delta\\in [0, 1]$. We show that, difference selection using the optimized parameters determined by the proposed ...

2010-01-01

248

Assessment of liver circulation by quantitative scintiangiography: Evaluation of the relative contribution of the hepatic arterial and portal venous blood flows to liver perfusion  

Energy Technology Data Exchange (ETDEWEB)

Quantitative hepatic scintiangiography was previously used for evaluating the relative contribution of hepatic arterial and portal venous blood flows to the hepatic circulation. The present study compares 3 different procedures (automatic and manual integration, and slope fitting methods) for analyzing the hepatic time activity curves obtained after bolus i.v. injection of 370 MBq /sup 99m/Tc-diethylentriaminopentacetic acid. Twenty five subjects were studied: Five controls, ten cirrhotics, and ten portal hypertensive patients previously submitted to side to side portacaval anastomosis. The correspondence between results given by the different methods was satisfactory only in shunted patients, and the reproducibility of computed parameters was quite poor for all procedures. Accordingly, none of the methods can be considered as supporting reliable quantitative pathophysiological evaluations. However, the hepatic ...

1989-04-01

249

Determination of the Sr/Ca ratio in bones by XRFA  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis was used for the determination of Sr/Ca ratio in bones to test the influence of a diet on this ratio. Significant differences were observed for Sr/Ca ratio in bones of various animals. Only small differences in the Ca/Sr ratio were observed for the samples of various prehistoric human bones. (author) 4 refs.; 4 tabs.

1989-11-01

250

The use of short-echo-time {sup 1}H MRS for childhood cerebellar tumours prior to histopathological diagnosis  

Energy Technology Data Exchange (ETDEWEB)

Proton magnetic resonance spectroscopy (MRS) measures concentrations of metabolites in vivo and provides a powerful method for identifying tumours. MRS has not entered routine clinical use partly due to the difficulty of analysing the spectra. To create a straightforward method for interpreting short-echo-time MRS of childhood cerebellar tumours. Single-voxel MRS (1.5-T Siemens Symphony NUM4, TR/TE 1,500/30 ms) was performed at presentation in 30 children with cerebellar tumours. The MRS results were analysed for comparison with histological diagnosis. Peak heights for N-acetyl aspartate (NAA), creatine (Cr), choline (Cho) and myo-inositol (mIns) were determined and receiver operator characteristic curves used to select ratios that best discriminated between the tumour types. The method was implemented by a group of clinicians and scientists, blinded to the results. A total of 27 MRS studies met the ...

2007-11-15

251

Quantitative bone and 67Ga scintigraphy in the differentiation of necrotizing external otitis from severe external otitis  

Energy Technology Data Exchange (ETDEWEB)

Qualitative technetium Tc 99m bone scintigraphy using phosphate compounds and gallium 67 scintigraphy were described as a helpful means in diagnosing necrotizing external otitis (NEO). They were, however, claimed to be nonspecific. Quantitative Tc 99m methylene diphosphonate bone scintigraphy and gallium 67 scintigraphy were performed in eight patients with NEO and in 20 patients with severe external otitis, in order to prove usefulness of scintigraphy in the diagnosis of NEO. Ratios of lesion to nonlesion for bone scintigraphy were 1.67 {plus minus} 0.16 in patients with NEO and 1.08 {plus minus} 0.09 in patients with severe external otitis, and for gallium 67 scintigraphy they were 1.35 {plus minus} 0.24 in NEO patients and 1.05 {plus minus} 0.03 in patients with severe external otitis. There was no difference in uptake between diabetic patients with severe external otitis and nondiabetic patients. The scintigraphic studies were also evaluated using a qualitative ...

1991-06-01

252

Quantitative bone and 67Ga scintigraphy in the differentiation of necrotizing external otitis from severe external otitis  

International Nuclear Information System (INIS)

Qualitative technetium Tc 99m bone scintigraphy using phosphate compounds and gallium 67 scintigraphy were described as a helpful means in diagnosing necrotizing external otitis (NEO). They were, however, claimed to be nonspecific. Quantitative Tc 99m methylene diphosphonate bone scintigraphy and gallium 67 scintigraphy were performed in eight patients with NEO and in 20 patients with severe external otitis, in order to prove usefulness of scintigraphy in the diagnosis of NEO. Ratios of lesion to nonlesion for bone scintigraphy were 1.67 #+-# 0.16 in patients with NEO and 1.08 #+-# 0.09 in patients with severe external otitis, and for gallium 67 scintigraphy they were 1.35 #+-# 0.24 in NEO patients and 1.05 #+-# 0.03 in patients with severe external otitis. There was no difference in uptake between diabetic patients with severe external otitis and nondiabetic patients. The scintigraphic studies were also evaluated using a qualitative scoring ...

253

Magnetic properties of FePt nanodots formed by a self-assembled nanodot deposition method  

International Nuclear Information System (INIS)

Fe_5_0Pt_5_0 nanodots dispersed in a SiO_2 film (Fe_5_0Pt_5_0 nanodot film) were formed by a self-assembled nanodot deposition (SAND) method in which Fe_5_0Pt_5_0 and SiO_2 are cosputtered in a high vacuum rf magnetron sputtering equipment. Fe_5_0Pt_5_0 pellets are laid on a SiO_2 target in a sputtering chamber to form the Fe_5_0Pt_5_0 nanodot film in the SAND method. The size and density of Fe_5_0Pt_5_0 nanodot were controlled by changing the ratio of the total area of Fe_5_0Pt_5_0 pellets to that of SiO_2 target. The Fe_5_0Pt_5_0 nanodot size decreases and its density increases when the ratio decreases. As-deposited Fe_5_0Pt_5_0 nanodots self-assembled to a face-centered-cubic phase of single-crystal structure. The Fe_5_0Pt_5_0 nanodot films were annealed to evaluate the nanodot size controllability, the magnetic anisotropy, and the thermal stability. Fully ordered L1_0 face-centered-tetragonal ...

2006-08-07

254

Wetting failure and contact line dynamics in a Couette flow  

CERN Document Server

Liquid-liquid wetting failure is investigated in a two-dimensional Couette system with two immiscible fluids of arbitrary viscosity. The problem is solved exactly using a sharp interface treatment of hydrodynamics (lubrication theory) as a function of the capillary number, viscous ratio and separation of scale, i.e. slip length versus macroscopic scale of the system. The existence of critical velocities, above which no stationary solutions are found, is analyzed in detail in terms of the relevant parameters of the system. Comparisons with existing analysis for other geometries are also carried out. A numerical method of analysis is also presented, based on diffuse interface models obtained from multiphase extensions of the lattice Boltzmann equation (LBE). Sharp interface and diffuse interface models are quantitatively compared face to face indicating the correct limit of applicability of the diffuse interface models.

2008-01-01

255

Thermal conductivity of sintered lithium orthosilicate compacts  

British Library Electronic Table of Contents (United Kingdom)

The design of solid breeder blankets is strongly affected by the low values of thermal conductivity and density of ceramic breeder pebble beds. A significant rise of both quantities would enhance the thermal performance and lead to an increased tritium breeding ratio. In order to improve these quantities pretreated lithium orthosilicate pebble material was dry pressed and subsequently sintered. The thermal conductivity of cylindrical pellets was determined by the heat pulse method using a laser flash device. A pebble bed characteristic sample was also investigated in order to check the measurement accuracy in comparison with previous results. Furthermore, two samples of low density cellular ceramics were also prepared by infiltration of polymer foams with a ceramic slurry. The thermal cond...

2009-01-01

256

Temperature profiles from rotational Raman lidar: parameter for the interpretation of PSC composition  

Energy Technology Data Exchange (ETDEWEB)

The depletion of stratospheric ozone is caused by chlorine species formed in heterogeneous processes on the surfaces of polar stratospheric cloud (PSC) particles. For studying local PSC formation processes in the Arctic a temperature lidar receiver was developed that makes use of the rotational Raman method, the only lidar technique for measuring atmospheric temperature profiles not perturbed by the presence of aerosols or cloud particles. The receiver was implemented in the mobile GKSS Raman lidar and transferred to Esrange (67.9 N, 21.1 E) near Kiruna in northern Sweden in winter 1997/98. Temperature data measured between January 22 and February 6, 1998, are presented and compared to model data analyzed by the European centre for medium-range weather forecast. Local temperature profiles are studied in three cases of type-Ib PSCs. This type is characterized by a low depolarization ratio. (orig.)

1999-07-01

257

TUNABLE FIBER FABRY-PEROT FILTER FOR OPTICAL CARRIER-SUPPRESSION AND SINGLE-SIDEBAND MODULATION IN RADIO OVER FIBER LINKS  

British Library Electronic Table of Contents (United Kingdom)

A novel method of simultaneous realization of optical carrier-suppression and single-sideband modulation using fiber Fabry-Perot tunable filter is presented. In order to enhance transmission performance of radio over fiber links, we use a fiber Fabry-Perot tunable filter to filter out one sideband as well as suppress the optical carrier power. The results demonstrate 20.5dB and 14.2dB improvement in the signal noise ratios when 18GHz and 10GHz microwave signals carrying 5Mbit/s quadrature-phase-shift-keyed (QPSK) format data is transmitted over 35 km single mode fiber, respectively.

2006-01-01

258

Synergistic effect of different phase on the photocatalytic activity of visible light sensitive silver antimonates  

British Library Electronic Table of Contents (United Kingdom)

We investigated phase transition of ilmenite-type AgSbO3 to pyrochlore by post-heat treatment and the synergy effect of the mixed phases of AgSbO3 on the photocatalytic activities to enhance the activities. The AgSbO3 with an ilmenite structure was prepared by a cation-exchange method. Phase transition from the ilmenite to pyrochlore occurred by proper control of post-heat treatment. The sample that was obtained by post-heat treatment of ilmenite-type AgSbO3 at 660^oC for 3h consisted of both of the ilmenite and pyrochlore phases, and the sample at 685^oC for 4h mainly consisted of the pyrochlore phase. Together with an increase in the ratio of the pyrochlore phase, the optical absorption spectra blue-shifted. The band gaps of single phases of the ilmenite and the pyrochlore were 2.4 and 2...

2010-01-01

259

Sulfonaphtholazoresorcinol as reagent for tungsten  

International Nuclear Information System (INIS)

Interaction of W(6) with sulphonaphtholazoresorcinol (SNAR) in aqueous solution has been studied. Tungsten is determined in the form of sulphonaphtholazoresorcinate by extraction with higher alcohols. The optimum conditions for the formation of a complex of W with SNAR in aqueous solution are as follows: a 10-fold excess of SNAR, concentration of HCl 1-1.5N, ethanol content 5-10 vol.%, time of formation of the complex 30 min. A component ratio for the complex has been established in the case of aqueous solution and extract; molar extinction coefficients are 0.9x10"4 and 1.7x10"4, respectively. The formation constant for the complex being extracted is 2.2x10"2"3. A method has been developed for determination of microgram quantities of W in a vanadium specimen.

1977-01-01

260

Study on the low-lying collective states of A=54-124 nuclei in 50 MeV #alpha#-particle scattering and in the "6"4Ni("3He, "3He') reaction by DWBA and coupled channel method  

International Nuclear Information System (INIS)

The analysis of elastic and inelastic scattering of #alpha# particles with energy of 50 MeV by nuclei with mass numbers A=54-124 and of "3He particles by the nucleus "6"4Ni is given in the framework of the optical model. The parameters of multipole deformations for lower states are determined. The parameters for quadrupole and octupole deformations of the potential for the nucleus "1"1"2Sn are extracted, the values of the hexadecupole deformation #beta#_4 of the potential for nuclei "9"4Zr, "1"2"0","1"2"4Sn are found. Information is extracted on the ratio of deformation parameters for the neutron and proton components in lower collective states (2_1"+, 3_1"-) of nuclei with A=90-124.

261

Somatic radiation risk in different mammography techniques  

International Nuclear Information System (INIS)

By measuring organ doses with TLD at an Alderson-Rando-phantom it was tested to evaluate the somatic risk for mammographies. Similarly as the genetic risk can be expressed by the genetic significant dose, the somatic risk can be expressed by the somatic significant dose index. The measurement results of the mammography show a large deviation of almost one power of ten with dependence of the chosen technique. In conventional xeroradiography and recording technique with foilless film the somatic radiation risk is the highest. By using amplifying foils in combination with high-sensitive films it is relatively small. Unfortunately the magnitude of the somatic risk in the different mammography techniques is in the ratio reciprocal to the corresponding image quality. At the time being the most favourable technique is mammography with a soft rastering method, although the xeromammography with additional high aluminium-filtering is a further ...

1981-01-01

262

Semiclassical calculation of photon-stimulated Schwinger pair creation  

International Nuclear Information System (INIS)

We consider the electron-positron pair creation by a photon in an external constant electric field. The presented treatment is based on a purely quasiclassical calculation of the imaginary part of the on-shell photon polarization operator. By using this approach we find the pair production rate for photons with polarization parallel as well as orthogonal to the external electric field in the leading order in the parameter eE/m"2, which has been recently found by other methods. For the orthogonal polarization we also find a new contribution to the rate, which is leading in the ratio of the photon energy to the electron mass #omega#/m. We also reproduce by a purely geometrical calculation the exponential factor in the probability of the stimulated pair creation at arbitrary energy of the photon.

2010-04-15

263

Rb-Sr isotopic studies on granodioritic rocks from the Mecsek mountains, Hungary  

Energy Technology Data Exchange (ETDEWEB)

New isotopic age determinations carried out with the rubidium-strontium method on granodioritic basement rocks from the Mecsek Mountains in Southeastern Transdanubia give further support to assumptions on a polyphase development of the Mecsek crystalline. As shown by initial Sr isotopic ratios, the protolith of the granodioritic assemblage of polymetamorphic-anatectic origin must have been strongly basic in its composition. The scatter of individual model ages obtained on total rock samples reflects the polymetamorphic-polytectonized character of the basement, and suggests that following a primary granitization process secondary events might have led to the total or partial recrystallization of the rocks in question. The tectonic development of the basement crystalline as reflected in the isotopic age data closed at about 270+-20 million years ago, with processes causing retrograde changes in the crystalline as a whole but leading to the ...

1981-01-01

264

Radioiodinated 1-substituted-4-phenylpiperazines as potential brain imaging agents  

Energy Technology Data Exchange (ETDEWEB)

A series of four 125I-labeled 1-substituted-4-phenylpiperazines were prepared and evaluated in rats as potential brain imaging agents. The compounds were labeled using (125I)iodide/chloramine-T or iodine monochloride and isolated in 48-60% radiochemical yields. The tissue distribution studies indicated that a butyrophenone derivative demonstrated the best overall brain-imaging properties. Compared with the compounds having other 1-substituents this agent had a more prolonged retention of activity in the brain and higher brain-to-blood ratios over the 4-h period studied. The in vivo behavior of this agent is comparable to that of radioiodinated N-isopropyl-p-iodoamphetamine, and, because it can be labeled directly via electrophilic methods, it has substantial potential for use in brain imaging with single photon emission computed tomography.

1985-01-01

265

Psychological distress and investment in one-s appearance in patients with pemphigus  

British Library Electronic Table of Contents (United Kingdom)

Abstract Background- Pemphigus vulgaris is a chronic disease not currently curable. Physical involvement and the impact of chronic therapies can lead patients to changes in psychological and relational areas. Objectives- To provide a measure of psychological distress, dysfunctional investment in one's appearance, and their relationship. Methods- Self-administered questionnaires (ASI, HADS) were given to 74 pemphigus inpatients. Results- Strong associations between psychological distress and dysfunctional investment in one's appearance were observed [adjusted odds ratio (OR) = 7.36, 95% confidence intervals (CI) 1.20-45.11; OR 5.38, 95% CI 0.81-35.87, respectively, for appearance stereotyping and body-image vulnerability], together with a perceived high disease severity (OR 6.03, 95% CI 1.9...

2011-01-01

266

Preparation, characterization, pharmacokinetics, and bioactivity of honokiol-in-hydroxypropyl--cyclodextrin-in-liposome  

British Library Electronic Table of Contents (United Kingdom)

Abstract Entrapping inclusion complexes in liposomes has been proposed to increase the entrapment efficiency (EE) and stability of liposomes compared with conventional liposomes. In the present study, a stable honokiol-in-hydroxypropyl--cyclodextrin-in-liposome (honokiol-in-HP--CD-in-liposome) was developed as honokiol delivery system by a novel method. The final molar ratio of honokiol/HP--CD/lipid was selected as 1:2:2. The mean particle size was 123.5 nm, the zeta potential was -25.6 mV, and the EE was 91.09 2.76%. The release profile in vitro demonstrated that honokiol is released from honokiol-in-HP--CD-in-liposome with a sustained and slow speed. Crystallographic study indicated that honokiol was first bound within HP--CD and then the inclusion complex was encapsulated within liposom...

2011-01-01

267

Precise radiometry: Some recent aspects of fruitful interaction with atomic physics  

International Nuclear Information System (INIS)

Modern radiometric analytics demands a complex consideration of nuclear and electron shell processes, if more pretentious aims are envisaged. As an example the small variation of decay rates of radionuclides presents possibilities for information on chemical situations of decaying atoms. In principle this phenomenon is well known since many years, but now the situation is such that, e.g. in /sup 99m/Tc internal conversion, a full agreement of the difficult experiments and the respective theory was established. The secondary emission of X-rays as a consequence of high excitation of electron shells in combination with nuclear transitions supplies another example for a methodical progress of radiometry. Investigations on "5"1Cr as an electron capture nuclide have shown that chemically induced variations of the K/sub #alpha#/ to K/sub #beta#/ X-ray intensity ratio is at least qualitatively understood. (author).

1986-01-01

268

Parallel MRI reconstruction using variance partitioning regularization  

British Library Electronic Table of Contents (United Kingdom)

Multiple receivers can be utilized to enhance the spatiotemporal resolution of MRI by employing the parallel imaging technique. Previously, we have reported the L-curve Tikhonov regularization technique to mitigate noise amplification resulting from the geometrical correlations between channels in a coil array. Nevertheless, one major disadvantage of regularized image reconstruction is lengthy computational time in regularization parameter estimation. At a fixed noise level, L-curve regularization parameter estimation was also found not to be robust across repetitive measurements, particularly for low signal-to-noise ratio (SNR) acquisitions. Here we report a computationally efficient and robust method to estimate the regularization parameter by partitioning the variance of the noise-white...

2007-01-01

269

Ozonation kinetics of phenolic acids present in wastewaters from olive oil mills  

Energy Technology Data Exchange (ETDEWEB)

A kinetic study of the degradation by ozone of eight phenolic acids present in wastewaters from olive oil mills has been performed by using a competition kinetic method. The selected phenolic acids are: caffeic, p-coumaric, syringic, vanillic, 3,4,5-trimethoxybenzoic, veratric, p-hydroxy-benzoic, and protocatechuic. The influence of the operating variables (temperature, pH, and ozone partial pressure in the gas stream) is established, and the stoichiometric ratios for the individual direct reactions between ozone and each acid are determined. Once the reaction rate constants are evaluated, they are correlated as a function of temperature and pH into kinetic expressions which are provided for every phenolic acid. The global process occurs in the fast and pseudo-first-order kinetic regime of absorption, a condition required by the competition model to be used.

1997-03-01

270

Outcome for Gram-negative bacteraemia when following restrictive empirical antibiotic guidelines  

British Library Electronic Table of Contents (United Kingdom)

Introduction: Restrictions in prescribing broad spectrum antimicrobials have been part of a strategy to reduce Clostridium difficile cases in the UK in recent years. However, there has been little work on assessing the safety of alternative antimicrobial agents. Methods: We performed an uncontrolled prospective observational survey over a 1-year period to determine the effectiveness and safety of a new antimicrobial stewardship programme in a district hospital in the UK. Results: In total, 227 Gram-negative bacteraemias (203 episodes) occurred in the study period. Guidelines were adequate in 194 of 203 (95%) episodes and 163 episodes (80.2%) received adequate therapy. Patients in the inadequate therapy group had >2-fold increased likelihood of death [odds ratio (OR) = 2.63, 95% confidence ...

2011-01-01

271

Nuclear forensics and nuclear analytical chemistry - iridium determination in a referred forensic sample  

International Nuclear Information System (INIS)

Nuclear approaches for compositional characterization has bright application prospect in forensic perspective towards assessment of nature and origin of seized material. The macro and micro physical properties of nuclear materials can be specifically associated with a process or type of nuclear activity. Under the jurisdiction of nuclear analytical chemistry as well as nuclear forensics, thrust areas of scientific endeavor like determination of radioisotopes, isotopic and mass ratios, analysis for impurity contents, arriving at chemical forms/species and physical parameters play supporting evidence in forensic investigations. The analytical methods developed for this purposes can be used in international safeguards as well for nuclear forensics. Nuclear material seized in nuclear trafficking can be identified and a profile of the nuclear material can be created

2010-11-15

272

New pulse sequence for simultaneous T1, T2, and RHO determination in whole-body proton MR imaging  

International Nuclear Information System (INIS)

A newly developed method to support tissue characterization in routine MR imaging is presented. It represents a compromise between the practical requirements of clinical routine (short measurement time, multisection imaging) and the necessary accuracy of the relaxation parameter evaluation. The sequence employed is a modification of the PHAPS technique and works with two excitation pulses. It allows the simultaneous acquisition of all measurement data for the subsequent T1, T2, and rho evaluations. T1 is determined with a specially designed computation formula based on four signal ratios. A multiexponential T2 analysis is performed with use of 28 echoes. From these parameters, relative proton density can be computed.

273

Mapping burned areas and burn severity patterns in SW Australian eucalypt forest using remotely-sensed changes in leaf area index  

British Library Electronic Table of Contents (United Kingdom)

Remote sensing is the most practical method available to managers of fire-prone forests for quantifying and mapping fire impacts. Differenced Normalised Burn Ratio (?NBR) is among the most widely used spectral indices for the mapping of burn severity but is difficult to interpret in terms of fire-related changes in key biophysical attributes and processes. We propose to quantify burn severity as a change in the leaf area index (?LAI) of a stand. LAI is a key biophysical attribute of forests, and is central to understanding their water and carbon cycles. Previous studies have suggested that changes in canopy LAI may be a major contributor to ?NBR and to the composite burn index (CBI) that is frequently used in combination with the NBR to assess burn severity on the ground. We applied remote...

2008-01-01

274

Investigation on the effect of cellulosic nanoparticles' morphology on the properties of natural rubber based nanocomposites  

British Library Electronic Table of Contents (United Kingdom)

Cellulose whiskers and microfibrillated cellulose (MFC) were extracted from the rachis of date palm tree and characterized. These cellulosic nanoparticles were used as reinforcing phase to prepare nanocomposite films using latex of natural rubber as matrix. These films were obtained by the casting/evaporation method. The properties of the ensuing nanocomposite films were investigated using differential scanning calorimetry, toluene and water uptake experiments, dynamic mechanical analysis and tensile tests. The stiffness of the natural rubber was significantly increased above its glass-rubber transition temperature upon nanoparticles addition. The reinforcing effect was shown to be higher for nanocomposites with MFC compared to whiskers. It was ascribed to the higher aspect ratio and possi...

2010-01-01

275

Interconnected project 'Development and testing of a biological monitoring for effects of polycyclic aromatic hydrocarbons on man'  

International Nuclear Information System (INIS)

The research project had the aim to develop a standard for measuring individual, inner stresses from polycyclic aromatic hydrocarbons (PAHs) at work. The employed method was by characterizing PAHs and metabolites of PAHs to be identified in urine with a view to developing a biological monitoring of professionally exposured persons. Using a number of PAHs relevant to work, the following questions were studied in cell culture systems and different animal-experimental models: Which metabolites are formed from the PAHs used in cell culture systems and the different animal-experimental models, and what are their ratios in percent? What percentage of a PAH is excreted by experimental animals in their urine and faeces on the first, second, and third day following different forms of application? What is the scale of the individual range of variation of PAH mass excretion? Are these results transferable to man? (orig.).

1992-01-01

276

In vivo chicken model for peripheral intravascular human fibrin clot detection  

Energy Technology Data Exchange (ETDEWEB)

A chicken model was prepared that provides a simple and economical method of evaluating the use of fibrin-specific monoclonal antibody 64C5 in the detection of peripheral vascular thrombi. Human fibrin was clotted in segments of a chicken's femoral artery and vein prior to intravenous injection of radioiodinated antibody 64C5. After a 3-hr perfusion time, the thrombosed and contralateral control segments of the vessels were excised and counted for radioactivity. The radiolabeled 64C5 uptake ratio of the thrombosed segment to the control segment was 5.4 +/- 1.2 (p less than 0.007) in the femoral artery, and 3.8 +/- 1.1 (p less than 0.02) in the femoral vein. This in vivo chicken model may also find application in studies of targeting agents for human fibrin.

1988-08-01

277

In vitro susceptibility of enterococci strains isolated from urine samples to fosfomycin and other antibiotics  

British Library Electronic Table of Contents (United Kingdom)

Enterococci are mostly isolated from urinary tract infections (UTIs). Increasing antibiotic resistance affects the success rate in empirical treatment, thus makes antibiotic susceptibility tests important. The aim of this study was to determine the species distribution and resistance patterns of Enterococcus strains isolated from urine samples to antibacterial agents including fosfomycin in a teaching hospital, Istanbul. The identification of 100 Enterococcus strains were determined by using conventional methods and API 20 Strep (bioMerieux France). The susceptibility testing was performed by disk diffusion and Etest. The majority of isolates were E. faecalis (67%), followed by E. faecium (33%). The ratio of E. faecalis to E. faecium was 2.03/1. E. faecalis and E. faecium strains were resi...

2011-01-01

278

In vitro and in vivo evaluation of [{sup 123}I]-VEGF{sub 165} as a potential tumor marker  

Energy Technology Data Exchange (ETDEWEB)

One of the research challenges in oncology is to develop new biochemical methods for noninvasive tumor therapy evaluation to determine whether the chemotherapeutics is effective. Vascular endothelial growth factor (VEGF) was labeled with radioiodine and evaluated in vitro as well as in vivo, using A2058, a melanoma cell line overexpressing VEGFR-1 and -2. Saturation binding analysis with [{sup 125}I]-VEGF resulted in a K {sub d} of 0.1 nM. Internalization assays indicate the preserved ligand induced internalization and metabolization of the tracer. Biodistribution studies with [{sup 123}I]-VEGF in wild type and A2058 tumor-bearing athymic mice showed low background activity and a tumor to reference tissue ratio of maximum 6.12. These results suggest that [{sup 123}I]-VEGF is a potentially suitable tracer for tumor therapy evaluation.

2005-07-01

279

High rate sputter deposition of wear resistant tantalum coatings  

Energy Technology Data Exchange (ETDEWEB)

The refractory nature and high ductility of body centered cubic (bcc) phase tantalum makes it a suitable material for corrosion- and wear-resistant coatings on surfaces which are subjected to high stresses and harsh chemical and erosive environments. Sputter deposition can produce thick tantalum films but is prone to forming the brittle tetragonal beta phase of this material. Efforts aimed at forming thick bcc phase tantalum coatings in both flat plate and cylindrical geometries by high-rate triode sputtering methods are discussed. In addition to substrate temperature, the bcc-to-beta phase ratio in sputtered tantalum coatings is shown to be sensitive to other substrate surface effects.

1991-11-01

280

Fish intake and acute coronary syndrome  

British Library Electronic Table of Contents (United Kingdom)

Aims To study the effect of fish consumption on the risk of acute coronary syndrome (ACS) in healthy subjects. Methods and results This Danish follow-up study included 57 053 men and women between 50 and 64 years. Intake of lean and fatty fish was estimated from a detailed and validated food frequency questionnaire. Potential cases of ACS were identified through nationwide medical databases. A total of 1122 cases of ACS were verified during a mean follow-up period of 7.6 years. Among men, intake of fatty fish was associated with a lower risk of ACS. For men in the highest quintile of fish intake compared with the lowest quintile, the hazard ratio was 0.67 (95% confidence interval: 0.53-0.85). The inverse association was observed for intakes >6 g of fatty fish per day with no obvious additi...

2010-01-01

281

Familiar and environmental factors influencing atopic dermatitis in the childhood  

British Library Electronic Table of Contents (United Kingdom)

Abstract Background The increase in the incidence of atopic dermatitis (AD) in developed countries has been related to familiar and environmental factors. This survey was undertaken to investigate the family background, birthweight and the home environment of children suffering from AD in order to point out the possible factors that provoke the development of the disease. Methods The study uses data collected by means of self-administered questionnaires and discusses 461 cases of children (age 0-12) with active skin signs of AD. The control group comprised of 343 children (age 0-12) with no skin signs or positive lifetime history of AD. Associations between familiar and various home environmental factors and the risk of AD were calculated by means of odds ratios. Results There were statist...

2006-01-01

282

Experimental compliance calibration for the mixed-mode bending (MMB) specimen  

Energy Technology Data Exchange (ETDEWEB)

A novel method to control the mixed-mode bending (MMB) specimen is presented. By maintaining a constant opening, or Mode 1, displacement rate, stable delamination growth is achieved for all mixed-mode ratios. A constant-opening displacement rate is achieved by attaching a second displacement transducer to the hinges of the specimen. The test machine is then controlled externally by the second displacement transducer. By achieving stable delamination growth and monitoring the opening displacement, an experimental compliance calibration may be derived for the Modes 1 and 2 parts. This new approach to control the test and determine the experimental compliance calibration, overcomes the potential inaccuracies of the previously used beam theory expressions to determine compliance and to separate the modal values of G.

1997-12-31

283

Efficacy and safety of a fixed-dose oral combination of pyronaridine-artesunate compared with artemether-lumefantrine in children and adults with uncomplicated Plasmodium falciparum malaria: a randomised non-inferiority trial  

British Library Electronic Table of Contents (United Kingdom)

Summary Background There is a need for new artemisinin-based combination therapies that are convenient, effective, and safe. We compared the efficacy and safety of pyronaridine-artesunate with that of artemether-lumefantrine for treatment of uncomplicated P falciparum malaria. Methods This phase 3, parallel-group, double-blind, randomised, non-inferiority trial was undertaken in seven sites in Africa and three sites in southeast Asia. In a double-dummy design, patients aged 3-60 years with uncomplicated P falciparum malaria were randomly assigned in a 2:1 ratio to receive pyronaridine-artesunate once a day or artemether-lumefantrine twice a day, orally for 3 days, plus respective placebo. Randomisation was done by computer-generated randomisation sequence in blocks of nine by study centre....

2010-01-01

284

Effect of Coating of Ammonium Perchlorate with Fluorocarbon on Ballistic and Sensitivity Properties of AP/Al/HTPB Propellant  

British Library Electronic Table of Contents (United Kingdom)

Fluorocarbon polymers are used to enhance thermal stability and electrostatic protection of composite propellant compositions. A precipitation technique has been developed to coat ammonium perchlorate (AP) using a copolymer of hexafluoropropylene and vinylidene fluoride (HFP-VF) with the help of solvent-counter solvent method. The coated AP has been used to prepare propellant compositions in different ratio based on hydroxyl terminated polybutadiene (HTPB), aluminium powder along with uncoated AP and studied for viscosity build-up and visco-elastic behaviour as well as mechanical, ballistic, thermal and sensitivity properties keeping 86% solid loading. The data on viscosity build-up indicate that as the percentage of viton coated AP increases end of mix viscosity and viscosity build-up inc...

2009-01-01

285

Dosimetric evaluation of multi-pattern spatially fractionated radiation therapy using a multi-leaf collimator and collapsed cone convolution superposition dose calculation algorithm  

British Library Electronic Table of Contents (United Kingdom)

Purpose: In this paper, we present an alternative to the originally proposed technique for the delivery of spatially fractionated radiation therapy (GRID) using multi-leaf collimator (MLC) shaped fields. We employ the MLC to deliver various pattern GRID treatments to large solid tumors and dosimetrically characterize the GRID fields. Methods and materials: The GRID fields were created with different open to blocked area ratios and with variable separation between the openings using a MLC. GRID designs were introduced into the Pinnacle3 treatment planning system, and the dose was calculated in a water phantom. Ionization chamber and film measurements using both Kodak EDR2 and Gafchromic EBT film were performed in a SolidWater phantom to determine the relative output of each GRID design as w...

2009-01-01

286

Development of titanium diboride coatings deposited by PACVD  

Energy Technology Data Exchange (ETDEWEB)

TiB{sub 2} appears to be a promising material for the wear protection in various tribological systems, e.g. the diecasting of Al. This study focuses on the development of titanium boride coatings deposited by PACVD, a deposition method which is most suitable for the coating of substrates with complex shapes. All layers analysed are very smooth and exhibit a quasi-amorphous fracture surface. XRD and TEM analysis indicate a nanocrystalline structure with grain sizes in the order of 2 nm. The diffraction patterns can well be correlated to titanium diboride. WDS reveals an over stoichiometric B/Ti ratio. The layer hardness reaches the value of 33 GPa and the critical load in scratch tests rises to 35 N. Neither 100Cr6 nor Al as a counterpart in pin-on-disk tests leads to wear of the coating. (orig.)

2000-09-01

287

Detection of previous neutron irradiation and reprocessing of uranium materials for nuclear forensic purposes  

International Nuclear Information System (INIS)

The paper describes novel analytical methods developed for the detection of previous neutron irradiation and reprocessing of illicit nuclear materials, which is an important characteristic of nuclear materials of unknown origin in nuclear forensics. Alpha spectrometry and inductively coupled plasma sector-field mass spectrometry (ICP-SFMS) using solution nebulization and direct, quasi-non-destructive laser ablation as sample introduction were applied for the measurement of trace-level "2"3"2U, "2"3"6U and plutonium isotopes deriving from previous neutron irradiation of uranium-containing nuclear materials. The measured radionuclides and isotope ratios give important information on the raw material used for fuel production and enable confirm the supposed provenance of illicit nuclear material.

2009-04-01

288

Consumption of filtered and boiled coffee and the risk of incident cancer: a prospective cohort study  

British Library Electronic Table of Contents (United Kingdom)

Background Despite potentially relevant chemical differences between filtered and boiled coffee, this study is the first to investigate consumption in relation to the risk of incident cancer. Methods Subjects were from the V?sterbotten Intervention Project (64,603 participants, including 3,034 cases), with up to 15?years of follow-up. Hazard ratios (HR) were calculated by multivariate Cox regression. Results No associations were found for all cancer sites combined, or for prostate or colorectal cancer. For breast cancer, boiled coffee ?4 versus <1 occasions/day was associated with a reduced risk (HR?=?0.52, CI?=?0.30?0.88, p trend?=?0.247). An increased risk of premenopausal and a reduced risk of postmenopausal breast cancer were found for both total (HRpremenopausal?=?1.69, CI?=?0.96?2.98...

2010-01-01

289

Comparison of skeletal and bone marrow radionuclide scintimetry of femoral neck fracture  

Energy Technology Data Exchange (ETDEWEB)

Twenty-six patients with late complications following femoral neck fracture were examined with both skeletal and bone marrow radionuclide scintimetry. There was no correlation between the methods with respect to the quantitative assessment of femoral head vascularity based on different uptake ratios comparing the fractured and the intact side. Skeletal scintimetry always had good image quality and permitted reliable differentation between nonunion of the fracture and late segmental collapse, in contrast to bone marrow scintimetry which gave poor image quality. Skeletal scintimetry thus seems superior to bone marrow scintimetry for assessment and differential diagnosis of late complications following femoral neck fracture. It is emphasized that the physiological mechanisms for radionuclide uptake must be taken into account when comparing scintimetric studies using different tracers.

1984-01-01

290

Comparison of skeletal and bone marrow radionuclide scintimetry of femoral neck fracture  

International Nuclear Information System (INIS)

Twenty-six patients with late complications following femoral neck fracture were examined with both skeletal and bone marrow radionuclide scintimetry. There was no correlation between the methods with respect to the quantitative assessment of femoral head vascularity based on different uptake ratios comparing the fractured and the intact side. Skeletal scintimetry always had good image quality and permitted reliable differentation between nonunion of the fracture and late segmental collapse, in contrast to bone marrow scintimetry which gave poor image quality. Skeletal scintimetry thus seems superior to bone marrow scintimetry for assessment and differential diagnosis of late complications following femoral neck fracture. It is emphasized that the physiological mechanisms for radionuclide uptake must be taken into account when comparing scintimetric studies using different tracers. (author).

291

Combined radiation and convection in absorbing, emitting, nongray gas-particulate tube flow  

Energy Technology Data Exchange (ETDEWEB)

The interaction of thermal radiation with conduction and convection in thermally developing absorbing, emitting, nongray gas-particulate turbulent suspension flow through a circular tube is investigated. The contribution of thermal radiation is obtained through evaluation of the total hemispherical emittance of the particulate cloud and through evaluation of single band absorptances for molecular gases, modified to account for the interaction with the particles. The governing differential equation is derived as a (nonlinear) energy equation, coupled with integral equations to find the thermal radiation contributions. The energy equation is solved numerically by an implicit finite difference method with an iterative procedure. Qualitative results for Nusselt numbers are shown for a variety and range of parameters, such as optical thickness of particulates and single molecular gas bands, relative gas band position and band width, and temperature ...

1987-05-01

292

Change of charging characteristics for polyethylene powder using plasma treatment in Ar gas; Ar plasma shori i yoru polyethylene funtai no taiden tokusei no henka  

Energy Technology Data Exchange (ETDEWEB)

A new method of plasma treatment for powder particles was investigated. A glass bottle horizontally held on a rotating system was used for the treatment. The outside of the bottle was covered by the grounded metal net, and the rod electrode was provided at the center of the bottle, which was connected to an ac high voltage source. Powder particles were placed in the bottle with stainless steel beads of large diameter and the plasma was generated between two electrodes and while the bottle was rotating. Using this system, powder particles were uniformly plasma-treated without coagulation. After 40 seconds treatment with plasma of 0.55 W in Ar gas, the charge to mass ratio for polyethylene powder particles having 160 {mu}m mean diameter generated by stainless before treatment. (author)

2000-03-31

293

Bayesian estimation of mixed Weibull distributions  

Energy Technology Data Exchange (ETDEWEB)

Estimation of mixed Weibull distribution by maximum likelihood estimation and other methods is frequently difficult due to unstable estimates arising from limited data. Bayesian techniques can stabilize these estimates through the priors, but there is no closed-form conjugate family for the Weibull distribution. This paper reduces the number of numeric integrations required for using Bayesian estimation on mixed Weibull situations from five to two, thus making it a more feasible approach to the typical user. It also examines the robustness of the Bayesian estimates under a variety of different prior distributions. It is found that Bayesian estimation can improve accuracy over the MLE for situations with low mixture ratios so long as the prior on the weak subpopulation's characteristic life has an expected value less than or equal to the true characteristic life.

2009-02-15

294

Association of area sociodemographic characteristics and capacity for treatment with disparities in colorectal cancer care and mortality  

British Library Electronic Table of Contents (United Kingdom)

AbstractBACKGROUND: Disparities in treatment and mortality for colorectal cancer (CRC) may reflect differences in access to specialized care or other characteristics of the area where an individual lives. METHODS: Surveillance, Epidemiology and End Results Program-Medicare data for seniors diagnosed with CRC were linked to area measures of the sociodemographic characteristics and the capacity of surgeons, medical oncologists, and radiation oncologists. Outcomes included receipt of stage-appropriate CRC care and mortality. RESULTS: After adjustment, blacks and Hispanics were less likely than whites to undergo surgery (odds ratio [OR] 0.57, 95% confidence interval (CI) 0.52-0.63 and OR 0.82, 95% CI 0.70-0.95, respectively). Individuals who lived in areas with the highest tertile of surgeon c...

2011-01-01

295

Are there bubbles in the REITs market? New evidence using regime-switching approach  

British Library Electronic Table of Contents (United Kingdom)

This study looks for the presence of rational speculative bubbles in Real Estate Investment Trusts (REITs) using unit-root, variance ratio, duration dependence and regime switching regression tests. The regime switching method provides weak evidence of speculative bubble behaviour in both the mortgage and hybrid REITs sectors even though traditional econometric bubble tests do not provide evidence of rational speculative bubbles in all REIT markets. Findings suggest that price movement in mortgage and hybrid REITs may be induced by bubble-like behaviour of investors. This behaviour may be traced to the real estate market bubble. Our results provide evidence that the real estate bubble that started in early 2000 was transmitted into securitized real estate markets. A regime switching model ...

2011-01-01

296

Application of a new water-soluble polyethylenimine polymer sorbent for simultaneous separation and preconcentration of trace amounts of copper and manganese and their determination by atomic absorption spectrophotometry  

International Nuclear Information System (INIS)

In this work, a water-soluble polymer, polyethylenimine (PEI) was used for the simultaneous separation and preconcentration of trace Cu and Mn prior to their determination by flame atomic absorption spectrometry. For this purpose, the sample and the PEI solution were mixed and the metal-bound polymer was precipitated by adding acetone. The precipitate was separated and dissolved in a minimum amounts of water and aspirated into a flame AAS. By increasing the ratio of the volumes of sample to water used in dissolving the precipitate, the analyte elements were concentrated as needed. The sorption is quantitative in the pH ?6. Detection limits were 5.2 ?g/L for Cu and 5.4 ?g/L for Mn. This method is simple, fast and precise.

2006-04-21

297

A parametric study on the exergoeconomic assessment of a vertical ground-coupled (geothermal) heat pump system  

Energy Technology Data Exchange (ETDEWEB)

An exergoeconomic model of a vertical ground-source heat pump residential heating system presented in this study uses exergy and cost energy mass (EXCEM) methods. The data obtained from a ground-source heat pump (GSHP) residential heating system installed at the Solar Energy Institute, Ege University, Turkey, are utilized for calculations at different reference temperature values in the range 0-25{sup o}C. The performance of the geothermal heat pump residential heating system is evaluated to indicate how exergoeconomic parameter values change with system. We also undertake a parametric study to investigate how varying reference temperatures will affect the exergoeconomic analysis of the GSHP system. A correlation between the ratio of thermodynamic loss rate to capital cost and reference state temperature is developed. (author)

2007-03-15

298

A new method for adiabatic flame temperature estimations of hydrocarbon fuels  

Energy Technology Data Exchange (ETDEWEB)

This paper presents the application of artificial neural networks to adiabatic flame temperature prediction of hydrocarbon fuels. The investigation was conducted over a wide range of operating conditions in terms of fuel composition, pressure and temperature of reactants, fuel-air equivalence ratio and fuel vapour fraction. Several neural network models for predicting the flame temperature for different applicable fuel ranges were built and examined. The proper preparation of network training data and the appropriate choice of network parameters for achieving better prediction accuracy are discussed. The neural network prediction results were compared with those calculated by a thermodynamic and chemical equilibrium-based computer code - the NASA program CET89. It was shown that trained neural network models can provide the adiabatic flame temperature prediction with a good level of accuracy over a wide range of operating conditions. 16 refs., 5 figs., 1 tab.

1999-03-01

299

A comparison of flue gas desulfurization processes  

Science.gov (United States)

As coal becomes more and more important as a power plant fuel in this time of energy shortage and the combustion of high-sulfur coals that would impair air quality, efforts have been made to devise efficient processes to control sulfur dioxide emission. Besides desulfurization before combustion, flue gas desulfurization is considered the most promising method that could also be applicable to all other fossil fuels. In this article, the flue gas desulfurization processes are briefly reviewed, and processes with highest use and with high potential for future use are compared from technical and economical points of view. In the selection of a desulfurization process, it is very important to consider the capacity of the plant, fuel type and fuel-to-sulfur ratio, availability and price of the reagent to be used, type, price, and market of side products, disposal problems of wastes, and environmental factors.

2000-04-01

300

The influence of stent design on neointimal hyperplasia of an aortic stent covering the visceral arterial ostia: an experimental study in dogs using a self-expandable nitinol stent  

Energy Technology Data Exchange (ETDEWEB)

To assess the influence of stent design [interlacing (type A) vs. crossing method (type B)] on neointimal hyperplasia using a self-expandable nitinol stent, which crosses the side branches of the abdominal aorta. In seven mongrel dogs, nitinol stents with type A and B intersections were placed in the abdominal aorta across the main branches: 4 Niti-Ms and 3 Niti-Ds. Two months after the stent placement, a DSA was performed for a stent patency evaluation, followed by the extraction of the aortas. The degree of neointimal formation along the wire was evaluated by calculating the area ratio of intimal hyperplasia (type A vs. B). A Student's t-test was employed to investigate the differences in the neointimal hyperplasia between blood types A and B. The total number of wire intersections overlain at the ostia branch ostia was 23 for type A and 36 for type B. The area ratio of the neointimal hyperplasia, for a given ...

2008-05-15

301

Synthesis and tissue distribution of substituted [{sup 125}I]iodophenylamine derivatives: Possible brain imaging agents  

Energy Technology Data Exchange (ETDEWEB)

The synthesis and brain uptake in mice of the radioidinated derivatives of N,N-dimethyl-N'-(idodimethoxyphenyl)-1,3-propanediamine, as well as the N-substituted derivatives of (iodoalkylphenyl)isopropyl, iodoalkylphenylethylamine and 3,4-(methylenedioxy)phenyl-amphetamine (MDA) are described. These compounds contain structural features of both IMP and HIPDM, the cerebral perfusion agents currently in clinical use. The radiolabeled analogs were obtained via the [{sup 125}I]I exchange method, or by [{sup 125}I]NaI treatment of the iodo-free precursor in the presence of an oxidant. Following intravenous injection in mice, all compounds showed important radioactivity concentrations in the lungs and kidneys. The N-substituted (iodoalkylphenyl)isopropyl and iodoalkylphenyl-ethylamine derivatives displayed a high initial brain uptake (>10%IDg{sup -1}) followed by a rapid clearance phase, resulting in lower brain-to-blood ratios as ...

1997-02-01

302

Synthesis and tissue distribution of substituted ["1"2"5I]iodophenylamine derivatives: Possible brain imaging agents  

International Nuclear Information System (INIS)

The synthesis and brain uptake in mice of the radioidinated derivatives of N,N-dimethyl-N'-(idodimethoxyphenyl)-1,3-propanediamine, as well as the N-substituted derivatives of (iodoalkylphenyl)isopropyl, iodoalkylphenylethylamine and 3,4-(methylenedioxy)phenyl-amphetamine (MDA) are described. These compounds contain structural features of both IMP and HIPDM, the cerebral perfusion agents currently in clinical use. The radiolabeled analogs were obtained via the ["1"2"5I]I exchange method, or by ["1"2"5I]NaI treatment of the iodo-free precursor in the presence of an oxidant. Following intravenous injection in mice, all compounds showed important radioactivity concentrations in the lungs and kidneys. The N-substituted (iodoalkylphenyl)isopropyl and iodoalkylphenyl-ethylamine derivatives displayed a high initial brain uptake (>10%IDg"-"1) followed by a rapid clearance phase, resulting in lower brain-to-blood ratios as those reported for IMP and ...

1997-02-01

303

MRI in the diagnosis of non-compacted ventricular Myocardium (NCVM) compared to echocardiography  

International Nuclear Information System (INIS)

Purpose: To report the detection of con-compacted ventricular myocardium (NVCM) with MRI compared to echocardiography in 8 patients. Material and methods: Non-compaction of the ventricular myocardium is a congenital disorder characterized by an altered structure of the myocardial wall resulting from an intrauterine arrest in endomyocardial embryogenesis. The morphological findings consist of a prominent meshwork of multiple myocardial trabeculations and deep intertrabecular recesses, communicating with the left ventricular cavity. 8 consecutive patients (mean age 7.3 years) with clinical and echocardiographic signs of NCVM were examined by MRI (1.5 T, Vision, Siemens) in short axis and 2- and 4-chamber views, using T_1-weighted TSE and Cine-GRE in 6 patients and true FISP sequences in 2 patients. MRI and echocardiography were evaluated for visibility, signs of NCVM and involvement of myocardial wall segments. Thickness was measured for non-compacted and compacted ...

2003-09-01

304

High volume fly ash RCC for dams - I : mixture optimization and mechanical properties  

Energy Technology Data Exchange (ETDEWEB)

Roller compacted concretes (RCC) were developed for the Norwegian Skjerka hydropower project. RCCs were developed to have a high-volume fly ash content to address environmental issues, including the reduction of carbon dioxide emissions associated with dam construction. They also makes good use of waste product and conserve natural resources. This study examined a series of mixtures to determine the appropriateness of using RCC as a competing alternative to the traditional rock fill dam proposed for the Skjerka hydropower project. The main advantage of RCC is speed, allowing a relatively large dam to be constructed in just one summer season, saving financial costs and providing early return on the investment. In addition, fly ash can be used in the structure, using clean and renewable energy. Several procedures to proportion RCC mixtures were proposed, including the optimal paste volume method which is based on the assumption that an optimal RCC should have just ...

2001-07-01

305

Error ratio of daily clearness indexes estimated from phrase of general weather condition in various parts of Japan; Nippon kakuchi ni oite tenki gaikyo kara suiteishita seiten shisu no gosaritsu  

Energy Technology Data Exchange (ETDEWEB)

To utilize solar energy effectively, a method has been developed by which daily clearness indexes can be estimated from phrase of general weather condition, and it has been examined at four places located at different typical climatic divisions in Japan. Successive results of extra-terrestrial solar insulation and measured solar insulation were illustrated at each place. It was found that the envelope of maximal value among measured values is in proportion to the extra-terrestrial solar insulation. Based on the basic clearness index and the meaning of term expressing general weather condition defined by the Meteorological Agency, the general weather condition was quantitated using the clearness index. This value was defined as weather index. Relationship between the measured clearness index at each place and the weather index was analyzed regressively. Correlation between the both was highly close, proportionally. Accordingly, the clearness index can be estimated ...

1997-07-31

306

Combined release of radiation sterilized adults of spotted bollworm, Earias vittella (Fabricius)  

International Nuclear Information System (INIS)

Feasibility of using combined release of sterile males and sterile females for population suppression of Earias vittella (Fabricius) was evaluated on okra in two ways. In one study, a combined release of sterile males and sterile females was evaluated under simulated conditions in laboratory, a 10: 10: 1: 1 (sterile male: sterile female: normal female: normal male) ratio effected > 99% sterility. In the second study, in a field cage experiment, a combined release of sterile males and sterile females was evaluated using normal males and tethered normal females. In this experiment, the release of sterile males and sterile females in 10: 10: 1: 1 ratio caused complete 'shut off' of mating of normal females for first 2 days and indicated>93% reduction in the larval progeny in the next generation. The tethered females were allowed to mate only once. E. vittella females mate multiply and so with overwhelming numbers of sterile males present, ...

2005-06-01

307

Chemical effects on K x-ray intensity ratios in chromium compounds  

International Nuclear Information System (INIS)

K_#beta#/ K_#alpha# x-ray intensity ratio of chromium were measured in different chromium compounds. The results show the variation of the intensity ratio as a function of the chemical environment around the metal ion. (author)

2003-02-10

308

Phytoremediation of Ionic and Methyl Mercury P  

Science.gov (United States)

Our long-term goal is to enable highly productive plant species to extract, resist, detoxify, and/or sequester toxic heavy metal pollutants as an environmentally friendly alternative to physical remediation methods. We have focused this phytoremediation research on soil and water-borne ionic and methylmercury. Mercury pollution is a serious world-wide problem affecting the health of human and wild-life populations. Methylmercury, produced by native bacteria at mercury-contaminated wetland sites, is a particularly serious problem due to its extreme toxicity and efficient biomagnification in the food chain. We engineered several plant species (e.g., Arabidopsis, tobacco, canola, yellow poplar, rice) to express the bacterial genes, merB and/or merA, under the control of plant regulatory sequences. These transgenic plants acquired remarkable properties for mercury remediation. (1) Transgenic plants expressing merB (organomercury lyase) extract methylmercury from their ...

1999-06-01

309

Suppressive effects of cadmium on neurons and affected proteins in cultured developing cortical cells  

International Nuclear Information System (INIS)

The purpose of the present study was to examine the in vitro effects of low-dose cadmium (Cd) on developing cortical cells. The cortical cells removed from fetuses (embryonic day 15) were treated with 10 nM of Cd for 24 h. The effects of Cd on dendritic and synaptic development were immunocytochemically observed with anti-microtubule associated protein-2 (MAP2) and anti-synapsin I antibodies, respectively. Administration of Cd suppressed dendritic as well as synaptic development at 10 nM. By two-dimensional gel electrophoresis and liquid chromatography-tandem mass spectrometric (LC/MS/MS) analysis, we identified three proteins with different expression after Cd-treatment; dihydropyrimidinase-related protein 2 (DRP-2/CRMP-2), 14-3-3-epsillon and calmodulin (CaM). Though the number of identified proteins was small, these proteins are known to be involved in neuronal development. The present study demonstrated the morphological effects as well as affected proteins in ...

2008-11-20

310

Spectroscopic properties of Er"3"+ ions in cadmium and alkali cadmium borosulphate glasses  

International Nuclear Information System (INIS)

Spectroscopic properties of Er"3"+ : CBS (CdSO_4 + B_2O_3 and R_2SO_4 + CdSO_4 + B_2O_3, R_2SO_4 = Li_2SO_4.H_2O, Na_2SO_4, K_2SO_4 and Gd_2(SO_4)_3.8H_2O) glasses are reported. The assigned energy level data of Er"3"+(4f"1"1) in these glasses are analysed in terms of a parametrized model Hamiltonian. The standard deviations of the data fits are between 39 and 47 cm"-"1 so that the energy level schemes of the Er"3"+(4f"1"1) ions in borosulphate (CBS) glasses are reasonably well reproduced. Radiative properties for the fluorescent levels of Er"3"+ : CBS glasses are determined by using the Judd-Ofelt theory. The potential laser transitions are identified with the help of predicted radiative properties which are compared and discussed with similar results. (author).

1997-01-01

311

Recent Progress in CdTe and CdZnTe Detectors  

CERN Document Server

Cadmium telluride (CdTe) and cadmium zinc telluride (CdZnTe) have been regarded as promising semiconductor materials for hard X-ray and Gamma-ray detection. The high atomic number of the materials (Z_{Cd} =48, Z_{Te} =52) gives a high quantum efficiency in comparison with Si. The large band-gap energy (Eg ~ 1.5 eV) allows us to operate the detector at room temperature. However, a considerable amount of charge loss in these detectors produces a reduced energy resolution. This problem arises due to the low mobility and short lifetime of holes. Recently, significant improvements have been achieved to improve the spectral properties based on the advances in the production of crystals and in the design of electrodes. In this overview talk, we summarize (1) advantages and disadvantages of CdTe and CdZnTe semiconductor detectors and (2) technique for improving energy resolution and photopeak efficiencies. Applications of these imaging detectors in ...

2001-01-01

312

Preparation of immission dust samples for the analysis of toxic substances in dust by atomic emission spectroscopy with inductively coupled plasma  

International Nuclear Information System (INIS)

Samples of air-dust-concentration- and air-dust-deposit measurements were digested by a standardized wet digestion procedure and the amounts of substances in the dust according to class I TA Luft by Atomic Emission Spectroscopy with Inductively Coupled Plasma (AES-ICP). The characteristic values for procedures according to VDI 2449, sheet 1, were determined for lead, vanadium, cadmium, chromium, copper, nickel and zinc. By partial automatic control of the digestion procedure the personel expenditure of work could be reduced by a factor 13. Dust filter samples were analysed without sample preparation by evaporating the material with a solid state laser. The absolute detection limit was between 1 and 100 ng/cm"2 for the elements arsenic, cadmium, cobalt, chromium, mercury, antimony, selen and thallium. For sampling by means of the Beta-Staubmeter the relative detection limits for the laser-ICP were 10-fold lower than by use of a nebulizer. ...

313

Microprocessor-controlled anodic stripping voltammeter for trace metal analysis in tap water  

Energy Technology Data Exchange (ETDEWEB)

The construction and use of a portable, microprocessor controlled anodic stripping voltameter for on-site simultaneous metal analysis of copper, lead and cadmium in tap water is discussed. The instrumental system is comprised of a programmable controller which permits keying in analytical parameters such as sparge time and plating time: a rotating cell for efficient oxygen removal and amalgam formation; and, data handling via a minicomputer or analog pen recorder. Plating and stripping potentials are controlled by a digital potentiostat; stripping is done using a staircase waveform with measurement of the current after a one msec delay. In this way charging current effects are minimized. Results of tap water analysis showed 3 +- 1 ..mu..g/L lead, 22 +- 0.3 ..mu..g/L copper, and less than 0.2 ..mu..g/L cadmium for a Berkeley, California tap water, and 1-1000 ..mu..g/L Cu, 1 -2 ..mu..g/L Pb for ten samples of Seattle, Washington tap water. ...

1984-06-01

314

High power nickel - cadmium cells with fiber electrodes (FNC)  

International Nuclear Information System (INIS)

Nickel cadmium batteries differ greatly in their mechanical design and construction of the electrodes. Using available electrode constructions, batteries are designed which meet the requirements of specific applications and offer optimum performance. Pocket- and tubular cells are basically developed with the technology of the year 1895. Since then some improvements with todays technology have been made. The sintered cells use the technology of the 1930's and they are still limited to high power application. With this knowledge and the technology of today the fiber-structured nickel electrode (FNC) was developed at DAUG laboratory, a subsidiary company of Mercedes-Benz and Volkswagen. After ten years of experience in light weight prototype batteries for electric vehicles (1-2), the system was brought into production by a new company, DAUG-HOPPECKE. Characteristics of fiber electrodes: thickness and size can be easily changed; pure active materials are used; high ...

315

Experimental Evaluation And Simulation Of Multi-pixel Cadmium-zinc-telluride Hard-x-ray Detectors  

CERN Document Server

This dissertation describes the evaluation of many-pixel Cadmium-Zinc-Telluride (CdZnTe) hard-X-ray detectors for future use with the High Energy Replicated Optics (HERO) telescope being developed at Marshall Space Flight Center. The detector requirements for the HERO application are good energy resolution (sufficient to resolve cyclotron features and nuclear lines), spatial resolution of ∼200 μm, minimal charge loss of absorbed X rays, and minimal sensitivity to the background environment. This research concentrates on assessing the suitability of these detectors for the focus of HERO, and includes the development of a simulation of the physics involved in an X-ray-detector interaction, a study of the intrinsic material properties, measurements with prototype detectors such as the energy and spatial resolution, charge loss, and X-ray background reduction through 3-dimensional depth sensing. Two types of detectors were available for evaluation. The ...

2004-01-01

316

A 1500-year record of lead, copper, arsenic, cadmium, zinc level in Antarctic seal hairs and sediments  

Energy Technology Data Exchange (ETDEWEB)

To reconstruct the profiles of heavy metal levels in the South Ocean ecosystem of Antarctica, the concentrations of lead (Pb), copper (Cu), arsenic (As), cadmium (Cd), and zinc (Zn) in seal hairs and lake sediments spanning the past 1500 years from Fildes Peninsula of King George Island and in weathering lake sediments from Nelson Island of West Antarctica were determined. The lead contents in the seal hairs and the weathering sediments show a sharp increase since the late 1800s, very likely due to anthropogenic contamination from modern industries. After the 1980s, the Pb content in seal hairs dropped by one-third, apparently due to the reduced usage of leaded gasoline in the Southern Hemisphere. Copper arises mainly from the weathering process, and its level may be substantially affected by climatic conditions. The concentrations of Cd, As, and Zn do not show any clear temporal trends.

2006-12-01

318

DUCTILITY RATIO OF AGED BETA TITANIUM ALLOY  

Science.gov (United States)

... Title : DUCTILITY RATIO OF AGED BETA TITANIUM ALLOY. Corporate Author : NEW YORK UNIV NY SCHOOL OF ENGINEERING AND SCIENCE. ...

1962-01-02

319

Trace metals in tap water from Tehran, Iran  

Energy Technology Data Exchange (ETDEWEB)

A total of 272 tap water samples were collected from 68 homes throughout the city of Tehran. Analysis for cadmium, zinc, lead, copper, arsenic, iron and manganese showed some accumulation of these metals in household piping overnight. However, the concentration of all metals was in the parts per billion (ug/l) range and well below international standards. Heavy metals in Tehran's drinking water therefore, do not pose a significant acute health hazard. 19 references, 2 tables.

1986-01-01

320

Synthesis of CdSe nanoparticles and their effect on the antioxidant activity of Spirulina platensis and Porphyridium cruentum cells  

International Nuclear Information System (INIS)

Single-crystalline cadmium selenide nanoparticles were obtained using high-temperature solution phase synthesis (HTSPS) synthesis. X-Ray powder diffraction and transmission electron microscopy were used to confirm the crystallinity and morphology of the resulting nanoparticles. To study the action of CdSe on antioxidant activity, we selected two biotechnological important strains of microalgae: cyanobacteria Spirulina platensis and red microalgae Porphyridium cruentum. In the case of Porphyridium cruentum, the obtained results demonstrated an increase in the productivity. For Spirulina platensis, the presence of the compound in the cultivating medium decreased the productivity of cyanobacteria.

2011-07-07

321

Synthesis and characterization of nickel(II), chromium(III), cobalt(II), copper(II), zinc(II), and cadmium(II) complexes with isatin- isonicotinoylhydrazone  

International Nuclear Information System (INIS)

A few metal complexes of isatin-isonicotinoylhydrazone with Ni(II), Cr(III), Co(II), Cu(II), Zn(II) and Cd(II) have been prepared and characterized on the basis of elemental analyses, infrared and electronic spectra as well as "1H NMR spectra, conductivity and magnetic measurements. In view of the results obtained, it has been found that two molecules of isatin-isonicotinoylhydrazone are chelated to the central metal ion as bis-uninegative ONO tridentate ligand forming non-electrolytic octahedral metal complexes. (author)

1997-03-01

322

Probable role of trace elements of some medicinal plants in cardio-vascular diseases  

International Nuclear Information System (INIS)

A number of herbal drugs are used in the Unani (Greco-Arab) System of Medicine for cardiovascular diseases. The herbs were analyzed by flame AAS and ICP-AES to determine if their therapeutic actions can be associated with the elements present in them. Cadmium, cobalt, chromium, copper, iron, potassium, magnesium, manganese, sodium, nickel, phosphorus, lead and zinc were some of the elements which play various roles in cardiovascular affections. An effort was made to correlate the role of these elements in cardiac diseases. (Auth.). 2 tabs., 32 refs.

323

Phase diagrams  

International Nuclear Information System (INIS)

The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.

324

Determination of uranium and thorium concentrations in integrated circuit packaging materials  

International Nuclear Information System (INIS)

The purpose of the present research is to find a suitable technique to measure trace amounts of uranium and thorium and to determine the surface #alpha#-flux in silicon compound (SiO) used for fabrication of integrated circuit packaging materials. Among several commonly-used detecting techniques, it was found that neutron activation analysis (NAA) was most promising. The results from NAA show a large difference in uranium and thorium concentrations when cadmium and boron carbide shields are used, whereas #alpha#-flux measurements show a low #alpha#-activity, which corresponds to the trace amounts of uranium and thorium expected to be present in these materials. (author) 13 refs.; 6 figs.

325

Anodic oxide coatings on metals and anodic protection /2nd revised and enlarged edition/. Anodnye oksidnye pokrytiia na metallakh i anodnaia zashchita /2nd revised and enlarged edition/  

Energy Technology Data Exchange (ETDEWEB)

The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.

1985-01-01

326

An application of the analysis of variance of measures repeated in an experiment with heavy metals  

International Nuclear Information System (INIS)

A revision of some basic concepts related to the analysis of variance of repeated measures is presented within an ecological context topics such as the types of experiments in which the technique is applicable, the hypotheses of interest, and its preference over other traditional techniques such as regression and conventional analysis of variance, are discussed. As an example, the technique was successfully applied to an experiment carried out at Cienaga Grande de Santa Marta, Colombia, in which the concentration of cadmium #mu#g/g in leaves of the black mangrove Avicennia germinans was measured in several monitoring stations and throughout several sampling intervals representing seasons.

1997-11-01

327

Simulating physiological conditions to evaluate nanoparticles for magnetic fluid hyperthermia (MFH) therapy applications  

Energy Technology Data Exchange (ETDEWEB)

Magnetite nanoparticles with high self-heating capacity and low toxicity characteristics are a promising candidate for cancer hyperthermia treatment. In order to achieve minimum dosage to a patient, magnetic nanoparticles with high heating capacity are needed. In addition, the influence of physiological factors on the heat capacity of a material should be investigated in order to determine the feasibility. In this study, magnetite nanoparticles coated with lauric acid were prepared by co-precipitation of Fe{sup 3+}:Fe{sup 2+} in a ratio of 2:1, 5:3, 3:2, and 4:3, and the pH was controlled using NaOH. Structural and magnetization characterization by means of X-ray diffractometry (XRD) and a superconducting quantum interference device (SQUID) revealed that the main species was Fe{sub 3}O{sub 4} and further showed that most of the nanoparticles exhibited superparamagnetic properties. All of the magnetic nanoparticles showed a specific absorption rate (SAR) increase ...

2010-01-15

328

Probing dark energy with the shear-ratio geometric test  

Science.gov (United States)

We adapt the Jain-Taylor (2003) shear-ratio geometric lensing method to measure the dark energy equation of state, w = pv/?v and its time derivative from dark matter haloes in cosmologies with arbitrary spatial curvature. The full shear-ratio covariance matrix is calculated for lensed sources, including the intervening large-scale structure and photometric redshift errors as additional sources of noise, and a maximum likelihood method for applying the test is presented. Decomposing the lensing matter distribution into dark matter haloes we calculate the parameter covariance matrix for an arbitrary experiment. Combining with the expected results from the cosmic microwave background (CMB) we design an optimal survey for probing dark energy. This shows that a targeted survey imaging 60 of the largest clusters in a hemisphere with five-band optical photometric redshifts to a median galaxy depth of zm = 0.9 ...

2007-02-01

329

Present status of biological effects of toxic metals in the environment: lead, cadmium, and manganese  

Energy Technology Data Exchange (ETDEWEB)

The number of reports concerning the chemical toxicology of metals which are released in the environment by natural as well as anthropogenic sources, have been increasing constantly. Lead, cadmium, and manganese have found a variety of uses in industry, craft, and agriculture owing to their physical and chemical properties. The environmental burden of heavy metals has been rising substantially by smelter emission in air and waste sewage in water. Further, organic compounds of lead and manganese used as antiknock substances in gasoline are emitted into the atmosphere by automobile exhaustion. Such environmental contamination of air, water, soil, and food is a serious threat to all living kinds. Although these metals are known to produce their toxic effects on a variety of body systems, much emphasis has been placed on their effects on the nervous system owing to apparent association of relatively low or ''subclinical'' levels of ...

1984-08-01

330

The End of Amnesia: A New Method for Measuring the Metallicity of Type Ia Supernova Progenitors Using Manganese Lines in Supernova Remnants  

CERN Document Server

We propose a new method to measure the metallicity of Type Ia supernova progenitors using Mn and Cr lines in the X-ray spectra of young supernova remnants. We show that the Mn to Cr mass ratio in Type Ia supernova ejecta is tightly correlated with the initial metallicity of the progenitor, as determined by the neutron excess of the white dwarf material before thermonuclear runaway. We use this correlation, together with the flux of the Cr and Mn Kalpha X-ray lines in the Tycho supernova remnant recently detected by Suzaku (Tamagawa et al. 2008) to derive a metallicity of log(Z) = -1.32 (+0.67,-0.33) for the progenitor of this supernova, which corresponds to log(Z/Zsun)= 0.60 (+0.31,-0.60) according to the latest determination of the solar metallicity by Asplund et al. (2005). The uncertainty in the measurement is large, but metallicities much smaller than the solar value can be confidently discarded. We discuss the implications of this result ...

2008-01-01

331

Signal Processing in Large Systems: a New Paradigm  

CERN Document Server

For a long time, signal processing applications, and most particularly detection and parameter estimation methods, have relied on the limiting behaviour of test statistics and estimators, as the number n of observations of a population grows large comparatively to the population size N, i.e. n>>N. Modern technological and societal advances now demand the study of sometimes extremely large populations, while simultaneously requiring fast signal processing due to accelerated system dynamics; this results in not-so-large practical ratios n/N, sometimes even smaller than one. A disruptive change in classical signal processing methods has therefore been initiated in the past ten years, mostly spurred by the field of large dimensional random matrix theory. The early literature in random matrix theory for signal processing applications is however scarce and highly technical. This tutorial proposes an accessible ...

2011-01-01

332

Quantification of the local glucose utilization and local blood flow in the heart of the awake rat using the /sup 14/C-2-deoxyglucose and /sup 14/C-iodoantipyrine methods  

Science.gov (United States)

Local cardiac glucose utilization (LCarGU) was quantified in the rat heart according to the Sokoloff model and local cardiac blood flow (LCarBF) according to the /sup 14/C-iodoantipyrine method. For quantitative autoradiography calibration curves for heart slices were performed. They differed from the brain calibration curves by 8%. The lumped constant was 0.377 in isolated working hearts. LCarGU and LCarBF could then be quantified in awake rats. At different locations mean LCarGU of different hearts varied from 85 to 200 ..mu..moles/100g/min and mean LCarBF from 390 to 831 ml/100g/min. The ratio subendocardial/subepicardial glucose utilization or blood flow was not systematically different from 1. The results indicate that glucose can be an important fuel in the heart of the awake rat, although its contribution to overall metabolism varies from animal to animal.

1986-03-05

333

Physical properties of shape-controlled TiO_2 nanoparticles  

International Nuclear Information System (INIS)

The synthesis of narrowly dispersed nanocrystalline TiO_2 was investigated with a surfactant aided solvothermal synthetic method in toluene solutions. When a sufficient amount of titanium isopropoxide, Ti[OCH(CH_3)_2]_4 (TIP), was added to the solution, the shapes of TiO_2 nanoparticles changed from spheres to rods. The aggregated microstructures of the nano-sized TiO_2 in systems of spheres, rods, and mixtures of spheres and rods was studied using TEM. The morphological shape of the aggregation was described in terms of the fractal dimensions. We used a box-counting method to get the fractal dimension of these systems. The fitted fractal dimensions for spheres, sphere/rod mixtures, and rods are D = 1.54, D = 1.81, and D = 1.89, respectively. The fractal dimension changed from 1.54 to 1.9 with the TIP/toluene ratio, indicating that the growth mechanism for aggregations showed different behaviors.

2005-11-01

334

Optimizing the acquisition time profile for a planar integral measurement system with a spinning slat collimator  

International Nuclear Information System (INIS)

This article considers a hypothetical imaging device with a spinning slat collimator that measures parallel-planar-integral data from an object. This device rotates around the object 180 deg. and stops at N positions uniformly distributed over this 180 deg. . At each stop, the device spins on its own axis 180 deg. and acquires measurements at M positions uniformly distributed over this 180 deg. . For a fixed total imaging time, an optimal distribution of the scanning time among the data measurement locations is searched by a nonlinear programming method: Nelder-Mead's simplex method. The optimal dwell time is approximately proportional to the weighting factor in the backprojector of the reconstruction algorithm. By using an optimal dwell-time profile, the reconstruction signal-to-noise ratio has a gain of 23%-24% for the filtered backprojection algorithm and a gain of 10%-18% for the iterative algorithms, compared with the ...

2005-09-01

335

Novel InN growth method under In-rich condition on GaN/Al2O3(0001) templates  

International Nuclear Information System (INIS)

A novel technique is proposed for the growth of an InN film on a GaN/Al2O3(0001) template by radio-frequency plasma-excited molecular beam epitaxy (RF-MBE). The method involves 1) InN growth under an In-rich condition and 2) additional nitrogen radical irradiation after the InN growth under an In-rich condition. Excess In that appeared on the InN surface in the InN growth under an In-rich condition is transformed to InN by the additional nitrogen radical irradiation. The effective V/III ratio is easily controlled by monitoring the intensity in a reflection high-energy electron diffraction (RHEED) pattern. The growth of the InN film by repeating the InN growth under an In-rich condition and the additional nitrogen radical irradiation is also demonstrated. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

2009-06-01

336

New facility design and work method for the quantitative fit testing laboratory. Master's thesis  

Energy Technology Data Exchange (ETDEWEB)

The United States Air Force School of Aerospace Medicine (USAFSAM) tests the quantitative fit of masks which are worn by military personnel during nuclear, biological, and chemical warfare. Subjects are placed in a Dynatech-Frontier Fit Testing Chamber, salt air is fed into the chamber, and samples of air are drawn from the mask and the chamber. The ratio of salt air outside the mask to salt air inside the mask is called the quantitative fit factor. A motion-time study was conducted to evaluate the efficiency of the layout and work method presently used in the laboratory. A link analysis was done to determine equipment priorities, and the link data and design guidelines were used to develop three proposed laboratory designs. The proposals were evaluated by projecting the time and motion efficiency, and the energy expended working in each design. Also evaluated were the lengths of the equipment links for each proposal, and each ...

1989-05-01

337

Mesoporous activated carbons with metal-oxide particles prepared from Morwell coal; Morwell tan wo genryo to shita kinzoku sankabutsu tanji kasseitan no saiko kozo  

Energy Technology Data Exchange (ETDEWEB)

The metal dependence of mesoporous activated carbons with various metal acetylacetonate (acac) particles prepared from Morwell coal was studied. In experiment, the mixture of Morwell coal and acac metal complexes were dissipated into tetrahydrofuran, and after agitation in Ar atmosphere, the solvent was removed by vacuum distillation. Coal specimens with Fe(acac)3, Ni(acac)2 and Co(acac)2 as acac complexes were activated by exchanging flow gas with water vapor after heat treatment in N2 gas flow at 900{degree}C. The pore sizes of the specimens were obtained from N2 adsorption isotherms by BET method and BJH method. Conditions of pores and metals in the specimens were examined by XRD measurement and TEM observation. The relation between the above conditions and pore characteristics obtained from adsorption experiment was also examined. As a result, the difference in mesopore ratio between the specimens and blank specimens ...

1996-10-28

338

Joining of boron carbide using nickel interlayer  

International Nuclear Information System (INIS)

Carbide ceramics such as boron carbide due to their unique properties such as low density, high refractoriness, and high strength to weight ratio have many applications in different industries. This study focuses on direct bonding of boron carbide for high temperature applications using nickel interlayer. The process variables such as bonding time, temperature, and pressure have been investigated. The microstructure of the joint area was studied using electron scanning microscope technique. At all the bonding temperatures ranging from 1150 to 1300degC a reaction layer formed across the ceramic/metal interface. The thickness of the reaction layer increased by increasing temperature. The strength of the bonded samples was measured using shear testing method. The highest strength value obtained was about 100 MPa and belonged to the samples bonded at 1250 for 75 min bonding time. The strength of the joints decreased by increasing the bonding ...

339

In-situ synthesis of poly(dimethylsiloxane)-gold nanoparticles composite films and its application in microfluidic systems.  

Science.gov (United States)

We presented a simple approach for in-situ synthesis of poly(dimethylsiloxane) (PDMS)-gold nanoparticles composite film based on the special characteristics of PDMS itself. It is an environmentally safe synthesis method without the requirement of additional reducing/stabilizing agents. The region where the resulting gold nanoparticles distribute (in the matrix or on the surface of the polymer) and the size of the nanoparticles, as well as the colour of the free-standing films, can be simply controlled by adjusting the ratio of curing agent and the PDMS monomer. The chemical and optical properties of these composite films were studied. Using such a method, gold nanoparticle micropatterns on PDMS surfaces can be performed. And based on the gold nanoparticles micropattern, further modification with antibodies, antigens, enzymes and other biomolecules can be achieved. To verify this ability, an immobilized glucose oxidase (GOx) ...

2007-11-14

340

Gamma heating in LMFBR media  

International Nuclear Information System (INIS)

State-of-the-art approaches for the calculation of gamma heating in LMFBR core, blanket and reflector regions have been evaluated, with particular emphasis on coupled neutron-gamma methods/cross section sets. The major source of calculational error was found to be the apparent failure to impose a mass-energy balance on total gamma energy yield from neutron capture and other interactions in the preparation of representative neutron-gamma cross section sets. The applicability of many simplifying assumptions was demonstrated, including: volume-weighted homogenization, insensitivity to the shape of the gamma-source-spectrum, gamma energy deposition equal to gamma energy source more than 10 cm inside large zones of uniform composition, and the negligible effect of bremsstrahlung. A simple one-group method was developed to permit rapid, accurate estimation of the large (factor of 2) changes in the gamma energy deposition-to-source ...

1976-01-01

341

Fracture characteristics obtained from the instrumented impact test of A533B steel for reactor pressure vessel  

Energy Technology Data Exchange (ETDEWEB)

Analyses of the date obtained from the instrumented impact test and of its correlation with static and dynamic J integral values and various tensile properties are made in this study. It is shown that a dynamic bending yield load recorded in the instrumented Charpy V test can be easily converted to a dynamic tensile yield stress using Server's equation. It is also possible to estimate a true fracture strain, COD value, and SZW easily if the load point displacement is recorded. Temperature dependency of Charpy V energy and J integral values is rather well simulated by a curve fitting method. However, a half value transition temperture obtained in that method has no physical meaning. Dynamic J sub(ID) is larger than a static J sub(IC) in the ductile fracture range in this study. This rise is proportional to the yield stress ratio sigmasub(yd)/sigmasub(y)(--1.2-1.3). It is found, therefore, that the following relation ...

1983-07-01

342

Fracture characteristics obtained from the instrumented impact test of A533B steel for reactor pressure vessel  

International Nuclear Information System (INIS)

Analyses of the date obtained from the instrumented impact test and of its correlation with static and dynamic J integral values and various tensile properties are made in this study. It is shown that a dynamic bending yield load recorded in the instrumented Charpy V test can be easily converted to a dynamic tensile yield stress using Server's equation. It is also possible to estimate a true fracture strain, COD value, and SZW easily if the load point displacement is recorded. Temperature dependency of Charpy V energy and J integral values is rather well simulated by a curve fitting method. However, a half value transition temperture obtained in that method has no physical meaning. Dynamic J sub(ID) is larger than a static J sub(IC) in the ductile fracture range in this study. This rise is proportional to the yield stress ratio #sigma#sub(yd)/#sigma#sub(y)(--1.2-1.3). It is found, therefore, that the following relation ...

343

Energy analysis of biochemical conversion processes of biomass to bioethanol  

Energy Technology Data Exchange (ETDEWEB)

Bioethanol is among the most promising of biofuels that can be produced from different biomass such as agricultural products, waste and byproducts. This paper reported on a study that examined the energy conversion of different groups of biomass to bioethanol, including lignocelluloses, starches and sugar. Biochemical conversion generally involves the breakdown of biomass to simple sugars using different pretreatment methods. The energy needed for the conversion steps was calculated in order to obtain mass and energy efficiencies for the conversions. Mass conversion ratios of corn, molasses and rice straw were calculated as 0.3396, 0.2300 and 0.2296 kg of bioethanol per kg of biomass, respectively. The energy efficiency of biochemical conversion of corn, molasses and rice straw was calculated as 28.57, 28.21 and 31.33 per cent, respectively. The results demonstrated that lignocelluloses can be efficiently converted with specific microorganisms ...

2010-07-01

344

Effect of halogens and inhibitors on the external stress corrosion cracking of Type 304 austenitic stainless steel  

Energy Technology Data Exchange (ETDEWEB)

The methodology of the drip procedure of the Standard Test Method for Evaluating the Influence of Thermal Insulation on External Stress Corrosion Cracking Tendency of Austenitic Stainless Steel (ASTM C 692-95a) was used to research the effect of halogens and inhibitors on the external stress corrosion cracking (ESCC) of Type 304 stainless steel as it applies to the insulation industry. Simulated insulation extraction solutions were made with pure chemical reagents for the halogens and inhibitors. The results indicated that sodium silicate compounds that were higher in sodium were more effective for preventing chloride-induced ESCC in Type 304 austenitic stainless steel. Potassium silicate was not as effective as sodium silicate. Fluoride, bromide, and iodide may cause ESCC but they were much less active than chloride and could be effectively inhibited by sodium silicate compound. The addition of fluoride ions to the chloride/sodium silicate systems, at the ...

1997-11-01

345

Different purification methods and quality of sunflower biodiesel  

Energy Technology Data Exchange (ETDEWEB)

Biodiesel is derived from triacylglycerides and is produced primarily through transesterification, a chemical reaction of vegetable oils with alcohol, methanol or ethanol. The cost of raw material should be considered since 85 per cent of production cost is related to vegetable oil. The purpose of this study was to evaluate oil expression of sunflower seed. It also examined the sunflower crude oil as a raw material for biodiesel by transesterification in both laboratory and pilot scale studies. Three different biodiesel purification methods were examined. The best result for oil expelling (68.4 per cent) at the experimental stage was obtained for seeds with a moisture content of 6.9 per cent at 25 degrees C and at a screw speed of 114 rpm. For biodiesel production at the laboratory scale, the best result for oil expelling was 87.5 per cent. It was obtained with an ethanol:oil molar ratio of 4.7:1 and with a 4.42 per cent catalyst concentration ...

2010-07-01

346

Cf-source-driven neutron-noise measurements of subcriticality for a 4. 95 wt% /sup 235/U-enriched uranyl fluoride solution cylinder  

Energy Technology Data Exchange (ETDEWEB)

A method for determining the reactivity of subcritical systems of fissile material, using neutron-noise power spectral density measurements in conjunction with a /sup 252/Cf source, has been tested in experiments with an aqueous solution containing uranium fluoride (4.95 wt% /sup 235/U). The kappasub(eff)-values obtained from the ratio of spectral densities G*/sub 12/G/sub 13//G/sub 11/G/sub 23/ agreed with those from break-frequency noise analysis and with bias-corrected transport theory calculations within the statistical uncertainty of the measurements. Corrections for the effects of spatial modes and source-detector locations appear to be well-understood, since measurements for a variety of source-detector positions resulted in essentially the same kappasub(eff)-values. Modal correction factors were such that ignoring them would result in higher values of kappasub(eff) than actually occur. The measurements have demonstrated the ...

1986-01-01

347

XRF analysis of rock and sediment using standard rock samples  

Energy Technology Data Exchange (ETDEWEB)

A simple and rapid method is described for the determination of major and trace elements in rock and sediment samples by wavelength dispersive XRF. Sample measured were made from cellulose powder pressed into 4 cm diameter aluminium ring 0.4 t cm/sup -2/, and then 1 g of powdered sample (0.08 g cm/sup -2/) was placed on the disk and repressed at 1.6 t cm/sup -2/. X-ray measurements were performed for total XRF intensity (I/sub p/) at the characteristic line of each element and background intensity (I/sub b/) in vicinity of the line. The correction of matrix effect was achieved by X-ray intensity ratio of peak to background for each element. Eight standard rock samples from Geological Survey of Japan were used as standard materials, and linear calibration curves were obtained by the plot of I/sub p/ - I/sub b/ vs. concentration for Ca, Na and Pb and by the plot of I/sub p//I/sub b/ ratio vs. concentration for Si, Fe, Ti, K, ...

1987-03-01

348

XRF analysis of rock and sediment using standard rock samples  

International Nuclear Information System (INIS)

A simple and rapid method is described for the determination of major and trace elements in rock and sediment samples by wavelength dispersive XRF. Sample measured were made from cellulose powder pressed into 4 cm diameter aluminium ring 0.4 t cm"-"2, and then 1 g of powdered sample (0.08 g cm"-"2) was placed on the disk and repressed at 1.6 t cm"-"2. X-ray measurements were performed for total XRF intensity (I_p) at the characteristic line of each element and background intensity (I_b) in vicinity of the line. The correction of matrix effect was achieved by X-ray intensity ratio of peak to background for each element. Eight standard rock samples from Geological Survey of Japan were used as standard materials, and linear calibration curves were obtained by the plot of I_p - I_b vs. concentration for Ca, Na and Pb and by the plot of I_p/I_b ratio vs. concentration for Si, Fe, Ti, K, P, Cl, Cr, Mn, Ni, Cu, Zn, Pb, Sr and Ba, ...

349

Synthesis characterization and biological evaluation of a novel mixed ligand "9"9"mTc complex as potential brain imaging agent  

International Nuclear Information System (INIS)

One approach in the design of neutral oxotechnetium complexes is based on the simultaneous substitution of a tridentate dianionic ligand and a monodentate monoanionic coligand on a [Tc(V)O]"+"3 precursor. Following this ''mixed ligand'' concept, a novel "9"9"mTc complex with N,N-bis(2-mercaptoethyl)-N'N'-diethylethylenediamine as ligand and 1-octanethiol as coligand is prepared and evaluated as potential brain radiopharmaceutical. Preparation of the complex at tracer level was accomplished by using "9"9"mTc-glucoheptonate as precursor. The substitution was optimized and a coligand/ligand ratio of 5 was selected. Under this conditions the labeling yield was over 80% and a major product (with radiochemical purity > 80%) was isolated by HPLC methods and used for biological evaluation. Chemical characterization at carrier level was developed using the corresponding rhenium complex as structural model. The Re complex was also prepared by ...

1998-08-01

350

Preparation and separation of Tc-97 and development and application of a mass spectrometrical isotope dilution analysis for trace analysis of technetium, molybdenum and ruthenium. Herstellung und Isolierung von /sup 97/Tc sowie Entwicklung und Anwendung einer massenspektrometrischen Isotopenverduennungsanalyse zur Technetium-, Molybdaen- und Rutheniumspurenanalyse  

Energy Technology Data Exchange (ETDEWEB)

The thesis explains the development of a mass spectrometerical isotope dilution analysis (MS/DA) for determining trace amounts of Tc. The Tc-97 isotope has been prepared by in-core irradiation of Ru of natural isotopic composition, and used as the indicator isotope. For separation of Tc-97 from the Ru matrix, a method has been developed to quantitatively separate Tc-97 from a high Ru surplus. For determining the isotope ratio for the MS/DA, a mass spectrometrical measuring technique has been found which allows reproducible measurement of the Tc-99/Tc-97 isotope ratio. Positive and, for the first time, also negative thermoionisation has been used as a method of selective ionisation of Tc. The applicability of the MS/DA for Tc trace analysis has been verified using two Al foils doped with Tc-99 or Mo-98, respectively. These have been irradiated in a nuclear reactor, the irradiation of Tc-99 yielding ...

1984-01-01

351

Influence of anchor behaviour on the earthquake response of liquid storage tanks  

International Nuclear Information System (INIS)

The dynamic response of thin liquid storage tanks to earthquakes is a very complicated phenomenon, because it can be highly non linear. Among others, one can meet material and geometric non linearities of the tank shell leading eventually to static or dynamic buckling non linear behavior of anchor bolts, contact non-linearities due to the uplift of the tank base and to the unilateral character of the fluid pressure on the shell and high amplitude fluid oscillations. Moreover, linear or non linear soil structure interaction affects considerably the response of the fluid structure system under consideration. In this paper we focus attention on problems related only to the base uplift and anchors plastification. We study a tank similar to the Hualien project tank, but we neglect the soil structure interaction. The studied tank is representative of medium height to radius ratio ratio tanks with relatively thick bottom plate. The contact is ...

352

Purification of CH{sub 3}Cl from CH{sub 3}I using cold trap with sealed 2,2,4-trimethylpentane for {delta}{sup 37}Cl measurement  

Energy Technology Data Exchange (ETDEWEB)

A cryogenic separation method of chloromethane (CH{sub 3}Cl) from methyl iodide (CH{sub 3}I) for {delta}{sup 37}Cl measurement with isotope ratio mass spectrometer is described. A cold trap with sealed 2,2,4-trimethylpentane (TMP) as the cryogen is used in this method. CH{sub 3}Cl can be separated from CH{sub 3}I at the TMP melting point (-107 deg. C) based on the difference in the vapor pressure between CH{sub 3}Cl (322.6 Pa) and CH{sub 3}I (lower than 1.3 Pa) at -107 deg. C. After two-step separation processes, the yields of CH{sub 3}Cl purified from CH{sub 3}Cl-CH{sub 3}I mixture are 96-101%, and the difference between the {delta}{sup 37}Cl{sub original} and {delta}{sup 37}Cl{sub Afterseparation} is from -0.06 to +0.06 per mille (0.01 {+-} 0.04 per mille ). These results suggest that CH{sub 3}Cl is completely separated from CH{sub 3}I with no change of {delta}{sup 37}Cl value. This method using the ...

2006-01-05

353

Determination of Cinchona alkaloids and Vitamin B_6 by high-performance liquid chromatography with fluorescence detection  

International Nuclear Information System (INIS)

A simple and specific method has been developed for the simultaneous determination of the four major Cinchona alkaloids and their dihydroderivatives and pyridoxine hydrochloride (Vitamin B_6) by high-performance liquid chromatography (HPLC) with fluorescence detection (#lambda#_e_m=420 nm with #lambda#_e_x=330 nm). The chromatographic separation was performed on a Phenomenex Prodigy ODS column (5 #mu#m, 250 mmx3.2 mm i.d.), recommended for basic compounds, under isocratic reversed-phase conditions. The method allowed a good peak shape and an effective resolution of the tested compounds. The extraction of alkaloids from the Cinchona succirubra bark was carried out in mild and fast conditions (ambient temperature, 20 min) by ultrasonication. The procedure showed to be advantageous respect to a reference method, which involved Soxhlet extraction. The results were compared statistically by means of the Student's t-test and the ...

2004-06-04

354

A sample preparation for quantitative determination of magnesium in individual lymphocytes by electron probe X-ray microanalysis.  

Science.gov (United States)

We present a sample preparation method for measuring magnesium in individual whole lymphocytes by electron probe X-ray microanalysis. We use Burkitt's lymphoma cells in culture as the test sample and compare X-ray microanalysis of individual cells with atomic absorption analysis of pooled cell populations. We determine the magnesium peak-to-local continuum X-ray intensity ratio by electron probe X-ray microanalysis and calculate a mean cell magnesium concentration of 39 +/- 19 mmol/kg dry weight from analysis of 100 cells. We determine a mean cell magnesium concentration of 34 +/- 4 mmol/kg dry weight by atomic absorption analysis of pooled cells in three cell cultures. The mean cell magnesium concentrations determined by the two methods are not significantly different. We find a 10% coefficient of variation for both methods of analysis and a 30% coefficient of variation in magnesium concentration among ...

1986-01-01

355

A sample preparation for quantitative determination of magnesium in individual lymphocytes by electron probe X-ray microanalysis  

International Nuclear Information System (INIS)

We present a sample preparation method for measuring magnesium in individual whole lymphocytes by electron probe X-ray microanalysis. We use Burkitt's lymphoma cells in culture as the test sample and compare X-ray microanalysis of individual cells with atomic absorption analysis of pooled cell populations. We determine the magnesium peak-to-local continuum X-ray intensity ratio by electron probe X-ray microanalysis and calculate a mean cell magnesium concentration of 39 +- 19 mmol/kg dry weight from analysis of 100 cells. We determine a mean cell magnesium concentration of 34 +- 4 mmol/kg dry weight by atomic absorption analysis of pooled cells in three cell cultures. The mean cell magnesium concentrations determined by the two methods are not significantly different. We find a 10% coefficient of variation for both methods of analysis and a 30% coefficient of variation in magnesium concentration among ...

1986-01-01

360

MICROMECHANICS - COMPRESSIVE PROPERTIES OF ...  

Science.gov (United States)

... slenderness ratio. Equations which determine the ultimate compressive strength of a composite were established. Several ...

1965-05-01

365

Coalfire related CO2 emissions and remote sensing  

Energy Technology Data Exchange (ETDEWEB)

Subsurface and surface coalfires are a serious problem in many coal-producing countries. Combustion can occur within the coal seams (underground or surface), in piles of stored coal, or in spoil dumps at the surface. While consuming a non renewable energy source, coalfires promote several environmental problems. Among all GHGs that are emitted from coalfires, CO2 is the most significant because of its high quantity. In connection to this environmental problem, the core aim of the present research is to develop a hyperspectral remote sensing and radiative transfer based model that is able to estimate CO2 concentration (ppmv) from coalfires. Since 1960s remote sensing is being used as a tool to detect and monitoring coalfires. With time, remote sensing has proven a reliable tool to identify and monitor coalfires. In the present study multi-temporal, multi-sensor and multi-spectral thermal remote sensing data are being used to detect and monitor coalfires. Unlike the earlier studies, the ...

2008-06-11

366

Influence of surface heat flux ratio on heat transfer augmentation in square channels with parallel, crossed, and V-shaped angled ribs  

Science.gov (United States)

The paper investigates the effect of the wall heat flux ratio on the local heat transfer augmentation in a square channel with two opposite in-line ribbed walls for Reynolds numbers from 15,000 to 80,000. The square channel composed of 10 isolated copper sections has a length-to-hydraulic diameter ratio of 20. The rib height-to-hydraulic diameter ratio is 0.0625 and the rib pitch-to-height ratio equals 10. Six ribbed side to smooth side wall heat flux ratios are studied for four rib orientations. The results show that the ribbed side wall heat transfer augmentation increases with increasing ribbed side to smooth side wall heat flux ratios, but the reverse is true for the smooth side wall heat transfer augmentation. The average heat transfer augmentation of the ribbed side and smooth side wall decreases slightly with increasing wall heat flux ...

1992-10-01

367

U.S. Department Of Energy's nuclear engineering education research: highlights of recent and current research-II. 4. Studies of Forced-Convection Heat Transfer Augmentation in Large Containment Enclosures  

International Nuclear Information System (INIS)

This paper provides information on heat transfer enhancement due to jet mixing inside a cylindrical enclosure. The work addresses conservative heat transfer assumptions regarding mixing and condensation that have typically been incorporated into passive containment design analyses. The current research presents an interesting possibility for increasing decay heat removal of passive containment systems under combined natural and forced convection. Eliminating these conservative assumptions could provide the basis for a change of containment design and reduce the construction cost. It is found that the ratio of forced- and free convection Nusselt numbers can be predicted as a function of the Archimedes number and a correlated factor accounting for jet orientation and enclosure geometry. To use the small-scale tests for large containment design, scale-up methods and criteria are important for matching the key governing parameters and fluid ...

2001-06-17

368

Optimal parameters for energy spectral calculations of mega voltage photon beam using Monte Carlo simulations  

International Nuclear Information System (INIS)

For the Convolution, Superposition and Monte Carlo methods, energy spectrum data is an essential parameter. Especially, by using Monte Carlo method, if the adequate properties of electrons are set, complex energy spectrum data can be calculated by simple input. However, adjustment of the property of electrons incident on the target of linear accelerator is time-consuming procedure. To cover the difference of many accelerators, it is important how we obtain accurate energy spectrum by simple methods. Especially, the total accuracy of dose calculation depends on the agreement of measured and calculated percentage depth dose (PDD) and off-axis ratio (OAR). Thus, a simple method for the determination of the simulation parameters was considered. To reduce the adjustment procedure, we selected values of important three parameters, which were the mean energy of the input electron beam, the ...

2005-06-01

369

Fifty years of jet in cross flow research  

Science.gov (United States)

The jet in cross flow (JICF) is a basic flowfield which is relevant to a wide variety of applications which are described to provide context for JICF investigations. Material consistent with the scope of topics presented at the 72nd AGARD Fluid Dynamics Panel Meeting and Symposium on Computational and Experimental Assessment of Jets in Cross Flow on 19-22 April 1993 in Winchester, U.K. is summarized. The JICF research was divided into three time periods: (1) early research - up to 1970, (2) research during the 1970's, and (3) research since 1980. The following areas of experimental activity are discussed; the definition of an effective correlation parameter; the jet flowfield including the jet trajectories, cross-section shape, and jet induced pressures; the effects of jet deflection angle, nozzle shape, pressure ratio, velocity decay, and temperature; and the effect of confined flowfield, ground effects, multiple jets, and adjacent surface geometry. In addition, ...

1993-11-01

370

Electromagnetic interactions in the {Delta}-resonance region  

Energy Technology Data Exchange (ETDEWEB)

Cross sections for some electro- and photoinduced spallation reactions on {sup 27}Al and {sup 51}V are measured in the energy region 130 MeV to 580 MeV with the activation method. Comparisons are made with calculations based on the Dalitz formalism for virtual photon spectra, and Monte Carlo calculations based on a cascade evaporation model, respectively. By use of Bremsstrahlung with end-point energies from threshold to 750 MeV, the yields for photo- production of{pi}{sup -}leading to ground and isomeric states in {sup 197}Hg are measured with the activation method. The activity from the Hg-isotopes were measured after a chemical separation of Hg from the target material. The yields and isomeric ratios are compared with impulse approximation calculations. For the photoproduction of {sup 195m}Hg and {sup 192}Hg from {sup 197}Au, the yields were measured. The experimental mean cross sections are compared with data from other ...

1995-03-01

371

Dynamic-stiffness matrix of embedded and pile foundations by indirect boundary-element method  

Energy Technology Data Exchange (ETDEWEB)

The boundary-integral equation method is well suited for the calculation of the dynamic-stiffness matrix of foundations embedded in a layered visco-elastic halfspace (or a transmitting boundary of arbitrary shape), which represents an unbounded domain. It also allows pile groups to be analyzed, taking pile-soil-pile interaction into account. The discretization of this boundary-element method is restricted to the structure-soil interface. All trial functions satisfy exactly the field equations and the radiation condition at infinity. In the indirect boundary-element method distributed source loads of initially unknown intensities act on a source line located in the excavated part of the soil and are determined such that the prescribed boundary conditions on the structure-soil interface are satisfied in an average sense. In the two-dimensional case the variables are expanded in a Fourier integral in the wave number domain, ...

1984-08-01

372

Analysis of load-penetration depth data using Oliver-Pharr and Cheng-Cheng methods of SiAlON-ZrO_2 ceramics  

International Nuclear Information System (INIS)

Depth sensing indentation tests were carried out to obtain load-penetration depth curves of SiAlON-ZrO_2 ceramics under different peak loads ranging from 200 to 1800 mN. The values of indentation hardness (H_O_P, H_C_C) and reduced elastic modulus (E_O_P, E_C_C) were calculated by using Oliver-Pharr (OP) and Cheng-Cheng (CC) methods. The experimental results revealed that the indentation hardness and reduced elastic modulus exhibit peak-load dependence, i.e. indentation size effect. Both indentation hardness and reduced elastic modulus values were obtained by considering indenter tip roundness and machine compliance. These values obtained from the OP method are higher than from the CC method. On the other hand, h_f/h_m ratios were used to clarify the indentation deformation behaviour of the SiAlON-ZrO_2 ceramic. The experimental h_f/h_m values were lower than the reported critical value (0.7) for all ...

2008-02-07

373

In vitro and in vivo analysis of pegulated Avidin  

Energy Technology Data Exchange (ETDEWEB)

Full text: In 1995, we demonstrated the use of pretargetting three steps method and biotinylated tetracycline using radiolabelled {sup 99m}Tc-DTPA-biocytinamide for the detection of tumour cells in (C57B1/6 x BALB/C) F1 mice with E-3 thymoma. The three steps were (1) IP injection of biotinylated-tetracycline conjugate (1:1) ratio, (2) 96 hours later Avidin/Streptavidin was injected, and (3) 24 hours after (2), {sup 99m}Tc-biocytinamide -cDTPA was injected. Mice were sacrificed 16/24 h after (3) by cervical dislocation. Biodistribution of radioactivity tumour to blood, liver, bone were T:B1= 15.0, T:Li= 5.08, T:Bo=15.0. The percentage of injected dose per g was T= 3.15% and B1= 0.21%. To prolong circulation of Avidin and therefore its uptake into tumour, Avidin was covalently bound to polyethylene-glycol (PEG20 KD) at the molar ratio of PEG:Avidin 100:1 and 400:1. The pegulated Avidin was then cleared from the circulation ...

1997-09-01

374

Implementation of an algorithm for absorbed dose calculation in high energy photon beams at off axis points  

International Nuclear Information System (INIS)

Full text: A semiempirical algorithm for absorbed dose calculation at off-axis points in irregular beams was implemented. It is well known that semiempirical methods are very useful because of their easy implementation and its helpfulness in dose calculation in the clinic. These methods can be used as independent tools for dosimetric calculation in many applications of quality assurance. However, the applicability of such methods has some limitations, even in homogeneous media, specially at off axis points, near beam fringes or outside the beam. Only methods derived from tissue-air-ratio (TAR) or scatter-maximum-ratio (SMR) have been devised for those situations, many years ago. Despite there have been improvements for these manual methods, like the Sc-Sp ones, no attempt has been made to extend their usage at off axis points. In this work, ...

2008-10-19

375

Thermodynamic and thermoeconomic analyses of a trigeneration (TRIGEN) system with a gas-diesel engine: Part II - An application  

Energy Technology Data Exchange (ETDEWEB)

The paper is Part 2 of the study on the thermodynamic and thermoeconomic analyses of trigeneration system with a gas-diesel engine. In Part 1, thermodynamic and thermoeconomic methodologies for such a comprehensive analysis were provided, while this paper applies the developed methodology to an actual TRIGEN system with a rated output of 6.5 MW gas-diesel engine installed in the Eskisehir Industry Estate Zone, Turkey. Energy and exergy efficiencies, equivalent electrical efficiency, the Public Utility Regulatory Policies Act (PURPA) efficiency, fuel energy saving ratio, fuel exergy saving ratio and other thermodynamic performance parameters are determined for the TRIGEN system. The efficiencies of energy, exergy, PURPA and equivalent electrical efficiency of the entire system are found to be 58.97%, 36.13%, 45.7% and 48.53%, respectively. For the whole system and its components, exergetic cost allocations and various exergoeconomic performance ...

2010-11-15

376

Thermodynamic and thermoeconomic analyses of a trigeneration (TRIGEN) system with a gas-diesel engine: Part II - An application  

International Nuclear Information System (INIS)

The paper is Part 2 of the study on the thermodynamic and thermoeconomic analyses of trigeneration system with a gas-diesel engine. In Part 1, thermodynamic and thermoeconomic methodologies for such a comprehensive analysis were provided, while this paper applies the developed methodology to an actual TRIGEN system with a rated output of 6.5 MW gas-diesel engine installed in the Eskisehir Industry Estate Zone, Turkey. Energy and exergy efficiencies, equivalent electrical efficiency, the Public Utility Regulatory Policies Act (PURPA) efficiency, fuel energy saving ratio, fuel exergy saving ratio and other thermodynamic performance parameters are determined for the TRIGEN system. The efficiencies of energy, exergy, PURPA and equivalent electrical efficiency of the entire system are found to be 58.97%, 36.13%, 45.7% and 48.53%, respectively. For the whole system and its components, exergetic cost allocations and various exergoeconomic performance ...

2010-11-01

377

The effect of hydrogen peroxide solution on SO2 removal in the semidry flue gas desulfurization process.  

Science.gov (United States)

The present study attempts to use hydrogen peroxide solution to humidify Ca(OH)(2) particles to enhance the absorption of SO(2) to achieve higher removal efficiency and to solve the valuable reuse of the reaction product in the semidry flue gas desulfurization (FGD) process. Experiments were carried out to examine the effect of various operating parameters including hydrogen peroxide solution concentration, Ca/S molar ratio and approach to adiabatic saturation temperature on SO(2) removal efficiency in a laboratory scale spray reactor. The product samples were analyzed to obtain semi-quantitative measures of mineralogical composition by X-ray diffraction (XRD) with reference intensity ratio (RIR) method and the morphology of the samples was examined by scanning electron microscope (SEM). Compared with spraying water to humidify Ca(OH)(2), SO(2) removal efficiency was improved significantly by spraying hydrogen peroxide ...

2009-04-24

378

Stoichiometry of photorespiration during C3-photosynthesis is not fixed: evidence from combined physical and stereochemical methods  

Energy Technology Data Exchange (ETDEWEB)

The stoichiometry of photorespiration, S, is defined as the fraction of glycolate carbon photorespired. It is postulated that under steady-state conditions there are two determinants of the ratio of photorespiration to net photosynthesis: the partitioning of ribulose bisphosphate between oxidation and carboxylation, and the partitioning of glycolate between reactions leading to complete oxidation to CO/sub 2/ (S . 100%) and those yielding CO/sub 2/ plus serine (S . 25%). S may be calculated using two independent probes of the system. The physical probe, using an infrared gas analyzer, measured photorespiration and net photosynthesis, and hence their ratio PR/NPS . pn(phys). The metabolic probe employed tracer (3R)-D-(3-/sup 3/H1,3-/sup 14/C)glyceric acid to determine r, the fraction of /sup 3/H retained in the triose phosphates leaving the chloroplasts. It is deduced from the postulated model that S . pn(phys) . r/(1 - r). Experiments have been ...

1985-03-01

379

Processing of LiBH{sub 4} from its elements by ball milling method  

Energy Technology Data Exchange (ETDEWEB)

Investigations of alternative renewable energy resources continue, with many studies concentrating on hydrogen storage. However, there are a few problems such as storage, transportation, delivery to the user and usage safely, to be addressed to facilitate commercialization and wide usage of the hydrogen. The absorbed form within the metal hydrides seems to be the best solution of this problem. Since Li is the lightest metal, it has the advantage as the stored amount of hydrogen mass ratio. LiBH{sub 4} production process was investigated using elemental Li, B and H{sub 2}. Spex type ball milling with tungsten carbide, stainless steel and zirconia type vessels, was used to mix the different amount of Li and B under argon atmosphere. X-ray diffraction pattern demonstrated that the LiB was obtained. A system was designed to provide a hydrogen atmosphere of 60 bars to force hydrogen into the LiB structure. FTIR analysis strongly indicated the LiBH{sub 4} compound when ...

2008-11-15

380

Measurement of the L sub 2 - L sub 3 Coster-Kronig transition probability in Tm( Z =69)  

Energy Technology Data Exchange (ETDEWEB)

The {ital L}{sub 2}-{ital L}{sub 3} Coster-Kronig transition probability ({ital f}{sub 23}) in Tm was measured by multiparameter {ital K} versus {ital L} x-ray coincidence techniques. The Tm x rays were obtained from a radioactive source of {sup 169}Yb and were detected with cooled germanium and silicon detectors of high-energy resolution. Corrections were applied for the contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak and for the contribution of unresolved {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak. The contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak was determined solely from the results of the coincidence measurements using a method of data analysis which was previously described elsewhere. The contribution of {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak was determined from the coincidence measurements and published values of the {ital L}{eta} to ...

1989-11-01

381

Measurement of the L sub 2 - L sub 3 Coster-Kronig transition probability in Tm( Z =69)  

Science.gov (United States)

The {ital L}{sub 2}-{ital L}{sub 3} Coster-Kronig transition probability ({ital f}{sub 23}) in Tm was measured by multiparameter {ital K} versus {ital L} x-ray coincidence techniques. The Tm x rays were obtained from a radioactive source of {sup 169}Yb and were detected with cooled germanium and silicon detectors of high-energy resolution. Corrections were applied for the contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak and for the contribution of unresolved {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak. The contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak was determined solely from the results of the coincidence measurements using a method of data analysis which was previously described elsewhere. The contribution of {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak was determined from the coincidence measurements and published values of the {ital L}{eta} to ...

1989-11-01

382

Increased Prevalence of Albuminuria in HIV-Infected Adults with Diabetes  

Science.gov (United States)

ObjectiveHIV and type 2 diabetes are known risk factors for albuminuria, but no previous reports have characterized albuminuria in HIV-infected patients with diabetes.Research Design and MethodsWe performed a cross-sectional study including 73 HIV-infected adults with type 2 diabetes, 82 HIV-infected non-diabetics, and 61 diabetic control subjects without HIV. Serum creatinine >1.5 mg/dL was exclusionary. Albuminuria was defined as urinary albumin/creatinine ratio >30 mg/g.ResultsThe prevalence of albuminuria was significantly increased among HIV-infected diabetics (34% vs. 13% of HIV non-diabetic vs. 16% diabetic control, p?=?0.005). HIV status and diabetes remained significant predictors of albuminuria after adjusting for age, race, BMI, and blood pressure. Albumin/creatinine ratio correlated significantly with HIV viral load (r?=?0.28, p?=?0.0005) and HIV-infected subjects with albuminuria had significantly greater ...

2011-09-13

383

Heat transfer augmentation for high heat flux removal in rib-roughened narrow channels  

International Nuclear Information System (INIS)

Heat transfer augmentation in narrow rectangular channels in a target system is a very important method to remove high heat flux up to 12 MW/m"2 generated at target plates of a high-intensity proton accelerator of 1.5 GeV and 1 mA with a proton beam power of 1.5 MW. In this report, heat transfer coefficients and friction factors in narrow rectangular channels with one-sided rib-roughened surface were evaluated for fully developed flows in the range of the Reynolds number from 6,000 to 1,00,000; the rib pitch-to-height ratios (p/k) were 10,20 and 30; the rib height-to-equivalent diameter ratios (k/De) were 0.025, 0.03 and 0.1 by means of previous existing experimental correlations. The rib-roughened surface augmented heat transfer coefficients approximately 4 times higher than the smooth surface at Re=10,000, p/k=10 and k/De=0.1; friction factors increase around 22 times higher. In this case, higher heat flux up to 12 MW/m"2 ...

2001-04-08

384

Heat transfer augmentation for high heat flux removal in rib-roughened narrow channels  

Energy Technology Data Exchange (ETDEWEB)

Heat transfer augmentation in narrow rectangular channels in a target system is a very important method to remove high heat flux up to 12 MW/m{sup 2} generated at target plates of a high-intensity proton accelerator of 1.5 GeV and 1 mA with a proton beam power of 1.5 MW. In this report, heat transfer coefficients and friction factors in narrow rectangular channels with one-sided rib-roughened surface were evaluated for fully developed flows in the range of the Reynolds number from 6,000 to 1,00,000; the rib pitch-to-height ratios (p/k) were 10,20 and 30; the rib height-to-equivalent diameter ratios (k/De) were 0.025, 0.03 and 0.1 by means of previous existing experimental correlations. The rib-roughened surface augmented heat transfer coefficients approximately 4 times higher than the smooth surface at Re=10,000, p/k=10 and k/De=0.1; friction factors increase around 22 times higher. In this case, higher heat flux up to 12 ...

1997-03-01

385

Feasibility of delivering grid therapy using a multileaf collimator  

International Nuclear Information System (INIS)

The feasibility of using a multileaf collimator (MLC) for grid therapy is demonstrated in this study. Grids with the projected field openings of 10 mmx10 mm and 5 mmx5 mm were created using multiple MLC-shaped fields. The deposited doses were measured with films at different depths in a solid water phantom and compared to those of Cerrobend grid collimators of similar hole sizes and hole separations. At the depth of maximum dose (d_m_a_x), the valley-to-peak dose ratios of the MLC grids were found to be about 11% and 19% for the respective 10 mmx10 mm and 5 mmx5 mm grid openings, and those of the corresponding grid blocks were about 15% and 20%. To quantify the dose contributed by transmission in the blocked areas due to the limited leaf thickness, Monte Carlo simulations (based on convolution/superposition method) were performed to calculate the doses in the solid water phantom using an ideal MLC with no leakage and perfect divergence in both ...

2006-01-01

386

Extraction-spectrophotometric determination of terbium in its mixture with lanthanum  

International Nuclear Information System (INIS)

A spectrophotometric study of the extraction with isobutanol of rare-earth elements in the form of complexes with quinoilizarin and N-benzene-N-phenylhydroxylamine has been made. The purpose of the study is to find out whether this reaction can be used in determining the concentration of elements in the presence of other rare-earth elements. In determining the relationship between the pH and light absorption the pH of the solution is measured after the extraction. The extraction of complexes begins at pH approximately 4 and reaches a maximum at pH7-8 (for La) and pH6-9 (for Er). The complexes underge decomposition when pH of the solution increased. The composition of complex compounds is determined by spectrophotometric methods for isomolar series, molar ratios and from the slope of logarithmic plots. Under optimal conditions (pH7.5) aAd at the measured ratio of the component for each ion of rare-earth elements, the molar ...

1975-01-01

387

Evaluation of indexes for tumor growth and effect of radiation therapy using MRS; Experimental studies on SCCVII tumor bearing mice  

Energy Technology Data Exchange (ETDEWEB)

Changes in the phosphate metabolism of the transplanted SCCVII (squamous cell carcinoma VII) tumor were studied before and after irradiation using in vivo [sup 31]P-magnetic resonance spectroscopy (MRS). Phosphocreatine (PCr), [gamma]-, [alpha]-, [beta]-ATP, inorganic phosphate (Pi), phosphomonoester (PME), and phosphodiester (PDE) were detected in [sup 31]P-MR spectra of tumor tissues. The curve fitting method was employed for calculating each peak of [sup 31]P-MR spectra (PCr, [beta]-ATP, Pi, PME, PDE). The values of PCr, PCr/Pi, [beta]-ATP/Pi and pH decreased in proportion to the growth of tumor, whereas that of Pi, PME and PDE increased. But the changes of [beta]-ATP were minimal in degree. Based on the fact that the ratio of PCr/Pi highly correlated with tumor volume and showed the most remarkable change among various parameters, it might be the useful index for the tumor growth. Because the phospholipid metabolite PME was detected in the ...

1992-03-01

388

Effect of pitting corrosion on local strength of hold frames of bulk carriers (1st report)  

Energy Technology Data Exchange (ETDEWEB)

Firstly, pitting corrosion observed on hold frames in cargo holds of bulk carriers which exclusively carry coal and iron ore has been investigated in detail. It was shown that the shape of the corrosion pits observed on them is a circular cone and the ratio of the diameter to the depth is in the range between 8 to 1 and 10 to 1, which is different from the trend observed for the bottom shell of the oil tanker where the ratio is in the range between 4 to 1 and 6 to 1. Secondly, a series of tensile tests has been conducted to investigate the effect of pitting corrosion on tensile strength of members. It was pointed out that the tensile strength decreases gradually and the total elongation decreases drastically with the increase of the thickness loss due to pitting corrosion. The reduction of the tensile strength of the members with pitting corrosion is larger than that of members with uniform thickness loss in terms of average thickness loss. ...

2004-09-01

389

Dosimetric evaluation of multi-pattern spatially fractionated radiation therapy using a multi-leaf collimator and collapsed cone convolution superposition dose calculation algorithm  

International Nuclear Information System (INIS)

Purpose: In this paper, we present an alternative to the originally proposed technique for the delivery of spatially fractionated radiation therapy (GRID) using multi-leaf collimator (MLC) shaped fields. We employ the MLC to deliver various pattern GRID treatments to large solid tumors and dosimetrically characterize the GRID fields. Methods and materials: The GRID fields were created with different open to blocked area ratios and with variable separation between the openings using a MLC. GRID designs were introduced into the Pinnacle"3 treatment planning system, and the dose was calculated in a water phantom. Ionization chamber and film measurements using both Kodak EDR2 and Gafchromic EBT film were performed in a SolidWater phantom to determine the relative output of each GRID design as well as its spatial dosimetric characteristics. Results: Agreement within 5.0% was observed between the Pinnacle"3 predicted dose distributions and the ...

2009-10-01

390

Determinants of warfarin use and international normalized ratio levels in atrial fibrillation patients in Japan.  

Science.gov (United States)

Background: Determinants of warfarin use and anticoagulation levels in atrial fibrillation (AF) patients have not been clarified thoroughly. Methods and Results: A total of 6,324 patients with non-valvular AF and congestive heart failure, hypertension, age, diabetes, prior stroke (CHADS(2)) score ?1 were used to investigate determinants of warfarin use, and 6,932 patients with AF receiving warfarin were used to investigate determinants of international normalized ratio (INR) of prothrombin time. Target INR levels for non-valvular AF patients were 1.6-2.6 for patients aged ?70 years and 2-3 for patients aged transient ischemic attack (TIA), and had higher CHADS(2) scores than those not receiving warfarin. Determinants of warfarin use were age (?60 years), AF type (persistent and permanent), and comorbidities (congestive heart failure, diabetes mellitus, and prior stroke or TIA). Use of antiplatelet drugs was a negative determinant of warfarin ...

2011-07-27

391

Comparison of turbo inversion recovery magnitude (TIRM) with T2-weighted turbo spin-echo and T1-weighted spin-echo MR imaging in the early diagnosis of acute osteomyelitis in children  

Energy Technology Data Exchange (ETDEWEB)

Objective. To compare turbo inversion recovery magnitude (TIRM) with standard T1-weighted (T1-W) and T2-weighted (T2-W) MR sequences in the very early detection of acute osteomyelitis in children. Materials and methods. In 15 children with osteomyelitis, 15 sets of T1-W spin-echo (SE) (TR/TE, 400-640/12-17), T2-W turbo spin-echo (TSE) (TR/TE/ETL, 3290-4465/112-120/11), and TIRM (TR/TE/TI, 4000-6120/60/160) images were acquired with a 1.0-T magnet. Contrast-to-noise (C/N) ratios and percentage of signal between lesion and normal bone marrow were analysed with a computer-assisted image analysing system in a region of interest (ROI). Results. In 13 of 15 patients, the absolute signal enhancement in a ROI on the TIRM images was better than on the T1-W SE and T2-W TSE images and in 14 of 15 cases, C/N ratios were also better on the TIRM images than on the other sequences. In the other cases, the TIRM signal was diagnostically ...

1998-11-01

392

Analysis of advanced direct-injection diesel engine development strategies. Final report, 1 July 1995--9 July 1998  

Energy Technology Data Exchange (ETDEWEB)

The methodology of achieving a high power density (HPD, or brake mean effective pressure) direct-injection Diesel engine has been studied, which is directed to using high fuel/air ratio, high-speed and ceramic engine components. Among the main thrust to achieve these engine changes for an advanced Diesel engine is the design of a high injection pressure (HIP) fuel system. During the course of the present study, two Cummins 903 engines mated with a Rutger-built HIP were employed to investigate the engine response to HIP and in-cylinder processes by using the Rutgers high-speed infrared (IR) spectral digital imaging system. Five separate technical publications were prepared to report results obtained from the study. The main findings include: The HIP system permits engine operation at an air/fuel ratio of as rich as 18 to 1 with smoke emission not worse than with the conventional mechanical (low pressure) injection system; A high injection ...

1998-08-01

393

A PIXE/PIGE study of gold mineralisation in lateritic terrain, Tanami Desert, Australia  

Energy Technology Data Exchange (ETDEWEB)

Proton induced X-ray and {gamma}-ray emission (PIXE/PIGE) have been used to analyze major and trace elements in a suite of 140 core samples from around of the Jim`s Find South gold anomaly in the Tanami desert, located in heavily weathered terrain. Simultaneous analyses were obtained for 30 elements, ranging in atomic number from {sup 3}Li to {sup 90}Th. The method was chosen because of its speed and the wide range of determination, its flexibility, precision and low detection limits. The regolith powder samples were treated by hot aqua regia before making them into pills. The PIXE/PIGE data of the acid insoluble residue give three factor analysis clusters. The first cluster comprises the elements F, Al, K, V, Mn, Fe, Ga, Rb, W and Au and is essentially related to sericitic wallrock alteration. The second cluster consists of Ti, As, Y, Zr, and Nb and is largely related to resistant minerals. The third cluster consists of Na, Ca and Sr and is interpreted to comprise ...

1997-12-31

394

Optimum aspect ratio for heat transfer enhancement in curved rectangular channels  

Science.gov (United States)

Enhanced heat transfer in curved rectangular channels depends on at least two geometric factors, the radius of curvature of the duct and the aspect ratio, which is the width/depth ratio of the duct. In this work, an expression for optimum aspect ratio is derived mathematically from a correlation that includes both aspect ratio and bend curvature parameters. Enhancement factors are developed that show optimal, near-optimal, and nonoptimal aspect ratios for curved rectangular ducts. Predicted enhancements are within 25% of published literature results for individual designs, two of which show heat transfer enhancement of 200% over that of a straight duct with turbulent flow. The theoretical maximum enhancement is shown to be about 480% over a straight-duct, turbulent-flow situation. This is not achievable in practice, but near-optimal solutions are achievable, yielding enhancements on ...

395

Tree data structures for N-body simulation  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we study data structures for use in N-body simulation. We concentrate on the spatial decomposition tree used in particle-cluster force evaluation algorithms such as the Barnes-Hut algorithm. We prove that a k-d tree is asymptotically inferior to a spatially balanced tree. We show that the worst case complexity of the force evaluation algorithm using a k-d tree is {Theta}(n log{sup 3} n log L) compared with {Theta}(n log L) for an oct-tree. (L is the separation ratio of the set of points.) We also investigate improving the constant factor of the algorithm, and present several methods which improve over the standard oct-tree decomposition. Finally, we consider whether or not the bounding box of a point set should be {open_quotes}tight{close_quotes}, and show that it is only safe to use tight bounding boxes for binary decompositions. The results are all directly applicable to practical implementations of N-body algorithms.

1996-12-31

396

Treatment of radioactive liquid waste by reverse osmosis; Influence of co-existing ions on the change of decontamination factor  

Energy Technology Data Exchange (ETDEWEB)

The report addresses the application of reverse osmosis to the treatment of radioactive liquid waste, focusing on the effects of non-radioactive cations and anions, existing in radioactive waste, on the removal of radioactive nuclides. The bivalent cations are generally about ten times as high in decontamination factor as monovalent ones. In the case of anions, the factor of SO{sub 4}{sup 2-} is about ten times that of Cl{sup -} while that of NO{sub 3}{sup -} is somewhat smaller than that of Cl{sup -}. During permeation through membrane, anions tend to accompany cations, and the decontamination factor of accompanying ions is found to increase with that of the paring ions. These results indicate that if one can select components that will remain in the liquid waste, one should consider their effects on the efficiency of its treatment. Furthermore, the interaction between two anions or between two cations can be approximated by a linear equation consisting of the logarithm of the ...

1991-01-01

397

Treatment of radioactive liquid waste by reverse osmosis  

International Nuclear Information System (INIS)

The report addresses the application of reverse osmosis to the treatment of radioactive liquid waste, focusing on the effects of non-radioactive cations and anions, existing in radioactive waste, on the removal of radioactive nuclides. The bivalent cations are generally about ten times as high in decontamination factor as monovalent ones. In the case of anions, the factor of SO_4"2"- is about ten times that of Cl"- while that of NO_3"- is somewhat smaller than that of Cl"-. During permeation through membrane, anions tend to accompany cations, and the decontamination factor of accompanying ions is found to increase with that of the paring ions. These results indicate that if one can select components that will remain in the liquid waste, one should consider their effects on the efficiency of its treatment. Furthermore, the interaction between two anions or between two cations can be approximated by a linear equation consisting of the logarithm of the decontamination factor of each ion ...

398

Thermal conductivity of sintered lithium orthosilicate compacts  

International Nuclear Information System (INIS)

The design of solid breeder blankets is strongly affected by the low values of thermal conductivity and density of ceramic breeder pebble beds. A significant rise of both quantities would enhance the thermal performance and lead to an increased tritium breeding ratio. In order to improve these quantities pretreated lithium orthosilicate pebble material was dry pressed and subsequently sintered. The thermal conductivity of cylindrical pellets was determined by the heat pulse method using a laser flash device. A pebble bed characteristic sample was also investigated in order to check the measurement accuracy in comparison with previous results. Furthermore, two samples of low density cellular ceramics were also prepared by infiltration of polymer foams with a ceramic slurry. The thermal conductivity results show that the values are affected both by the particle size and the sample density. Thermal conductivity values of higher than 2 W/m K were ...

2009-04-30

399

The effects of the design of the cap of a natural gas-fired cooktop burner on flame stability  

Energy Technology Data Exchange (ETDEWEB)

Results of an investigation aiming to study the effects of the burner cap design factors on flame stability are presented in this paper. Flame stability is an essential part of the operation of all domestic burners, including natural gas-fired cooktops. At high thermal inputs flame lifts are encountered above certain levels of primary aeration, whereas flashback only takes place at low thermal inputs, due to natural gas low flame speed, above certain levels of primary aeration. In this work, flame lift limits were measured at 3.3 kW thermal input and the highest primary aeration above which flame lifts started to become visible was the stability limit at this thermal input. Around 60% primary aeration was desired to minimize pollutant emissions. Turndown tests were done at 40% primary aeration. The `Factorial Experimental Design` method with statistical analysis was used. This enabled detection of interactions between factors as well as the effects of each single ...

1998-02-01

400

The crystal structure of the novel ternary silicide Sm_4Pd_4Si_3  

International Nuclear Information System (INIS)

The crystal structure of the compound Sm_4Pd_4Si_3 was determined by the single-crystal method (KM-4 automatic diffractometer, Mo K#alpha# radiation). Sm_4Pd_4Si_3 has the monoclinic Nd_4Rh_4Ge_3 type structure: space group C2/c, mC44 (No. 15), a=20.693(6), b=5.584(1), c=7.699(2) A, #beta#=109.48(3) , V=838 A"3, Z=4, #mu#=36.23 mm"-"1, R_F=0.0537, R_W=0.0435 for 1652 unique reflections. The coordination numbers of samarium atoms are 17 and 18. For palladium and silicon atoms icosahedra and trigonal prisms with additional atoms are typical as coordination polyhedra. The structure of Sm_4Pd_4Si_3 is composed of fragments of the YPd_2Si and Y_3Rh_2Si_2 structure in a ratio 1:1. (orig.).

401

Tau Boo b: Hunting for reflected starlight  

CERN Document Server

Aims. We attempt to detect starlight reflected from the hot Jupiter orbiting the main-sequence star Tau Boo, in order to determine the albedo of the planetary atmosphere, the orbital inclination of the planetary system and the exact mass of the planetary companion. Methods. We analyze high-precision, high-resolution spectra, collected over two half nights using UVES at the VLT/UT2, by way of data synthesis. We interpret our data using two different atmospheric models for hot Jupiters. Results. Although a weak candidate signal appears near the most probable radial velocity amplitude, its statistical significance is insufficient for us to claim a detection. However, this feature agrees very well with a completely independently obtained result by another research group, which searched for reflected light from Tau Boo b. As a consequence of the non-detection of reflected light, we place upper limits to the planet-to-star flux ratio at the 99.9% ...

2010-01-01

402

Study on the correlation between chemical and mineral composition of coal ashes; Sekitanbaibun no kobutsu soseigakuteki kento kagakubutsu sosei to kobutsugakuteki sosei no sokan  

Energy Technology Data Exchange (ETDEWEB)

Coal ash is a substance that has been mixed into minerals in the earth`s crust during their coalification process. Estimation was made on what kinds of mineral composition have been mixed into coals. Noted first was the kinds of compounds contained in the ash, wherein the ratios of mass in the compounds and minerals were correlated, and selection was made on minerals which are thought correlated. The selection criterion was based on minerals containing silica, alumina, iron oxide, lime and magnesium as compounds. Then, a phase equilibrium line diagram was used to estimate compositions and melting points of minerals which are thought to have been produced from these compounds. By comparing the estimation with the measured melting points of the ashes, mineral compositions thought reasonable were all selected. Assumption was possible on minerals that are thought to have been transferred into coal ash. Compound indications of ashes from 29 kinds of the world`s typical ...

1996-10-28

403

Study of chest portable radiography using computed radiography. Removal effect of X-ray scatter by a copper plate  

Energy Technology Data Exchange (ETDEWEB)

When chest radiographs are obtained using an anti-scatter grid in a mobile x-ray unit by Fuji Computed Radiography (FCR), right lung densities may differ from left lung densities owing to misalignment caused by an oblique x-ray beam. Such misalignment is considered to be caused by factors such as the shape of the bed and angle of the x-ray tube. Misalignment is especially frequent when exposure is carried out in the sitting position. Although a low-ratio grid has been reported to offer improvement, the misalignment is not completely eliminated. Therefore, we used a copper plate without a lattice feature instead of grid, and examined the results. The copper plate was found to have the ability of a grid to eliminate radiation scatter, and, furthermore, to offer the physical capabilities of a grid as determined by Carlin's new grid assessment method. Image quality was demonstrated through contrast manipulation to be equal to that obtained ...

2001-04-01

404

Study of chest portable radiography using computed radiography. Removal effect of X-ray scatter by a copper plate  

International Nuclear Information System (INIS)

When chest radiographs are obtained using an anti-scatter grid in a mobile x-ray unit by Fuji Computed Radiography (FCR), right lung densities may differ from left lung densities owing to misalignment caused by an oblique x-ray beam. Such misalignment is considered to be caused by factors such as the shape of the bed and angle of the x-ray tube. Misalignment is especially frequent when exposure is carried out in the sitting position. Although a low-ratio grid has been reported to offer improvement, the misalignment is not completely eliminated. Therefore, we used a copper plate without a lattice feature instead of grid, and examined the results. The copper plate was found to have the ability of a grid to eliminate radiation scatter, and, furthermore, to offer the physical capabilities of a grid as determined by Carlin's new grid assessment method. Image quality was demonstrated through contrast manipulation to be equal to that obtained by grid ...

2001-04-01

405

Structure and surface and catalytic properties of Mg-Al basic oxides  

Science.gov (United States)

Mg-Al mixed oxides with Mg/Al molar ratios of 0.5--9.0 were obtained by thermal decomposition of precipitated hydrotalcite precursors. The effect of composition on structure and surface and catalytic properties was studied by combining several characterization methods with ethanol conversion reactions. The nature, density, and strength of surface basic sites depended on the Al content. The catalyst activity and selectivity of Mg-Al mixed oxides in ethanol conversion reactions depended on composition. The dehydrogenation of ethanol to acetaldehyde and the aldol condensation to n-butanol both involved the initial surface ethoxide formation on a Lewis acid-strong base pair. The dehydration of ethanol to ethylene, and the coupling and dehydration to diethyl ether increased with Al content, probably reflecting the density increase of both Al{sup 3+}-O{sup 2{minus}} pairs and low- and medium-strength basic sites. Pure Al{sub 2}O{sub 3} displayed the ...

1998-09-10

406

Statistical measure of association between smoking and lung cancer in Abakaliki, Ebonyi State Nigeria.  

Science.gov (United States)

The hazards of smoking in relation to lung cancer can never be over emphasized. In recent times shortly after Ebonyi State was created in 1996, the capital territory has increasingly been polluted by either quarry operators, motorcycle (Okada) riders or reckless cigarette smokers and bush burning. To investigate the havoc caused by all these on people, questionnaire was distributed among smokers and non smokers in various areas of specialization and habitations. In measuring the significance of association and the degree of association, a chi2 test and odds ratio method of analysis was employed. The result of the analysis showed that non-smokers do suffer lung cancer. It also revealed that the chances of a smoker to have lung cancer is 1.765 times higher than that of a non-smoker. Analysis also showed that lung cancer depends on age of smokers. It was later discovered that middle aged population are mostly affected, by the reason of chi2 ...

2009-04-01

407

Solar-powered unmanned aerial vehicles  

Energy Technology Data Exchange (ETDEWEB)

An analysis was performed to determine the impact of various power system components and mission requirements on the size of solar-powered high altitude long endurance (HALE)-type aircraft. The HALE unmanned aerial vehicle (UAV) has good potential for use in many military and civil applications. The primary power system components considered in this study were photovoltaic (PV) modules for power generation and regenerative fuel cells for energy storage. The impact of relevant component performance on UAV size and capability were considered; including PV module efficiency and mass, power electronics efficiency, and fuel cell specific energy. Mission parameters such as time of year, flight altitude, flight latitude, and payload mass and power were also varied to determine impact on UAV size. The aircraft analysis method used determines the required aircraft wing aspect ratio, wing area, and total mass based on maximum endurance or minimum ...

1996-12-31

408

Selective patterned growth of single-crystal organic nanowires of Ag-TCNQ with chemical raction method  

Energy Technology Data Exchange (ETDEWEB)

Abstract: We report for the selective-area chemical synthesis of semiconductor single-crystal organic nanowires of silver-tetracyanoquinodimethane (Ag-TCNQ). Straight and smooth Ag-TCNQ nanowires can be produced and patterned on micrometer and nanometer scale on silicon substrates covered with a thin layer of Ag film through the reaction of TCNQ and Ag in a simple gas-solid chemical reaction process. Ag-TCNQ nanowires are characterized by UV-vis, IR and Raman spectroscopy, respectively. The Ag-TCNQ nanowires grows preferentially along the [100] direction of strong - stacking of Ag-TCNQ molecules. Nanodevices based on these nanowires are fabricated using focus ion beam (FIB) technique. Electrical properties are characterized and I-V hysteresis is observed, which shows memory effect with electrical switching of three orders on-off ratio. These nanowires could be potential for use in optical storage, ultrahigh-density nanoscale memory and logic devices.

2008-09-01

409

Recovery of lanthanides and yttrium from red mud by selective leaching  

Energy Technology Data Exchange (ETDEWEB)

This study presents a rapid and selective method for the recovery of lanthanides and yttrium, existing in economically interesting concentrations, from red mud, the byproduct of the alumina production. The leaching process is based on the extraction of these elements with diluted nitric acid from red mud under moderate conditions and without using any preliminary treatment. Several parameters such as leaching agents, contact time, temperature, pressure and solid to liquid ratio were investigated in order to achieve an optimum recovery. The process followed here was selected taking into account its efficiency for the selective recovery of yttrium and lanthanides, but also its suitability for the subsequent liquid-liquid extraction of the leaching solution for the separation of the individual lanthanides. The achieved recovery percentages were for Y about 90%, for the investigated heavy lanthanides (Dy, Er, Yb) up to 70%, for the middle ones (Nd, ...

1996-01-30

410

Recovery of lanthanides and yttrium from red mud by selective leaching  

International Nuclear Information System (INIS)

This study presents a rapid and selective method for the recovery of lanthanides and yttrium, existing in economically interesting concentrations, from red mud, the byproduct of the alumina production. The leaching process is based on the extraction of these elements with diluted nitric acid from red mud under moderate conditions and without using any preliminary treatment. Several parameters such as leaching agents, contact time, temperature, pressure and solid to liquid ratio were investigated in order to achieve an optimum recovery. The process followed here was selected taking into account its efficiency for the selective recovery of yttrium and lanthanides, but also its suitability for the subsequent liquid-liquid extraction of the leaching solution for the separation of the individual lanthanides. The achieved recovery percentages were for Y about 90%, for the investigated heavy lanthanides (Dy, Er, Yb) up to 70%, for the middle ones (Nd, ...

411

Radon-mitigation in buildings  

International Nuclear Information System (INIS)

From the indoor radon problem arises a great challenge for the radiation protection of the population. The soil can be considered as the only source for high radon concentrations in buildings. The contribution of common building materials to high indoor concentrations with a range of 30 Bq/m"3 is negligible low. Therefore building materials for radon mitigation should be judged by their tightness against diffusive radon and not by their radon exhalation rate. Also isolation materials for mitigation should be radon tight. The radon diffusion coefficient describes the physical processes in relatively homogeneous samples. The diffusion coefficient D and the diffusion length R are very exactly determined by a self engineered measuring method. The range of D reaches from D = (0.0005 to 2.35) . 10"-"6 m"2/s for building materials and from D = (0.07 to < 10"-"6) . 10"-"6 m"2/s for isolation materials. Applicable mitigation measures like increased ventilation rates, ...

412

Radionuclide scintimetry for diagnosis of complications following femoral neck fracture  

Energy Technology Data Exchange (ETDEWEB)

A scintimetric study using Tc-99m MDP was made of 54 patients with delayed union, nonunion, or late segmental collapse of the femoral head, 4-92 months after femoral neck fracture. In radiographically verified collapse, the radionuclide uptake ratio between the femoral head on the fractured and on the intact side (HHR) was significantly higher than in fractures resulting in delayed union or nonunion. On the basis of scintimetric and radiographic findings, the patients with healing disturbances could be divided into three groups, characterized by the following features: (1) Satisfactory post-reduction position of the fracture without subsequent redisplacement and a high HHR, which as a rule turned out to be delayed union; (2) The same radiographic pattern but with a lower HHR, which in most cases resulted in nonunion; (3) Inadequate reduction or early redisplacement of the fracture with a high HHR, which resulted in nonunion. The fractional precision in ...

1984-01-01

413

Parity-projected shell model Monte Carlo level densities for medium-mass nuclei  

International Nuclear Information System (INIS)

We investigate the effects of single-particle structure and pairing on the equilibration of positive and negative-parity level densities for the even-even nuclei "5"8","6"2","6"6Fe and "5"8Ni and the odd-A nuclei "5"9Ni and "6"5Fe. Calculations are performed using the shell model Monte Carlo method in the complete fp-gds shell-model space using a pairing+quadrupole type residual interaction. We find for the even-even nuclei that the positive-parity states dominate at low excitation energies due to strong pairing correlations. At excitation energies at which pairs are broken, single-particle structure of these nuclei is seen to play the decisive role for the energy dependence of the ratio of negative-to-positive parity level densities. We also find that equilibration energies are noticeably lower for the odd-A nuclei "5"9Ni and "6"5Fe than for the neighboring even-even nuclei "5"8Ni and "6"6Fe.

2008-11-11

414

Parity-projected shell model Monte Carlo level densities for fp-shell nuclei  

International Nuclear Information System (INIS)

We calculate parity-dependent level densities for the even-even isotopes "5"8","6"2","6"6Fe and "5"8Ni and the odd-A nuclei "5"9Ni and "6"5Fe using the shell model Monte Carlo method. We perform these calculations in the complete fp-gds shell-model space using a pairing+quadrupole residual interaction. We find that, due to pairing of identical nucleons, the low-energy spectrum is dominated by positive parity states. Although these pairs break at around the same excitation energy in all nuclei, the energy dependence of the ratio of negative-to-positive parity level densities depends strongly on the particular nucleus of interest. We find equilibration of both parities at noticeably lower excitation energies for the odd-A nuclei "5"9Ni and "6"5Fe than for the neighboring even-even nuclei "5"8Ni and "6"6Fe.

2007-06-01

415

PROPERTIES OF DISKS AND BULGES OF SPIRAL AND LENTICULAR GALAXIES IN THE SLOAN DIGITAL SKY SURVEY  

International Nuclear Information System (INIS)

A bulge-disk decomposition is made for 737 spiral and lenticular galaxies drawn from a Sloan Digital Sky Survey galaxy sample for which morphological types are estimated. We carry out the bulge-disk decomposition using the growth curve fitting method. It is found that bulge properties, effective radius, effective surface brightness, and also absolute magnitude, change systematically with the morphological sequence; from early to late types, the size becomes somewhat larger, and surface brightness and luminosity fainter. In contrast, disks are nearly universal, their properties remaining similar among disk galaxies irrespective of detailed morphologies from S0 to Sc. While these tendencies were often discussed in previous studies, the present study confirms them based on a large homogeneous magnitude-limited field galaxy sample with morphological types estimated. The systematic change of bulge-to-total luminosity ratio, B/T, along the ...

2009-11-01

416

Numerical Models of Sgr A*  

CERN Document Server

We review results from general relativistic axisymmetric magnetohydrodynamic simulations of accretion in Sgr A*. We use general relativistic radiative transfer methods and to produce a broad band (from millimeter to gamma-rays) spectrum. Using a ray tracing scheme we also model images of Sgr A* and compare the size of image to the VLBI observations at 230 GHz. We perform a parameter survey and study radiative properties of the flow models for various black hole spins, ion to electron temperature ratios, and inclinations. We scale our models to reconstruct the flux and the spectral slope around 230 GHz. The combination of Monte Carlo spectral energy distribution calculations and 230 GHz image modeling constrains the parameter space of the numerical models. Our models suggest rather high black hole spin ($a_*\\approx 0.9$), electron temperatures close to the ion temperature ($T_i/T_e \\sim 3$) and high inclination angles ($i \\approx 90 \\deg$).

2010-01-01

417

Measurement of reactor tube cladding thickness by x-ray fluorescence spectrometry  

International Nuclear Information System (INIS)

An x-ray fluorescence spectrometer was designed and fabricated which nondestructively determines the thickness of aluminum cladding at small suspected thin spots in the inner or outer surface of actinide reactor tubes. The analysis method is based on the difference in absorption of actinide L/sub #alpha#/ and L/sub #beta#/ fluorescent x-rays in passing through the cladding. Calibration plots of the logarithm of the L/sub #beta#//L/sub #alpha#/ x-ray intensity ratio versus cladding thickness are linear to at least 40 mils for U-Al, U_3O_8-Al, and PuO_2-Al substrates. Accuracy and precision of the experimentally determined cladding thickness and evaluated for both uranium and plutonium substrates. Experimental thickness data are reported for 618 quality assurance analyses on six Mark 41 PuO_2-Al target tubes. An x-ray fluorescence cladding thickness monitor operated with a computer-controlled fluoroscope holds considerable promise for quality ...

1978-01-01

418

Lifetimes of superdeformed nuclei in the mass region A {approx}150 with the Eurogam multidetector array; Durees de vie de noyaux superdeformes de la region de masse A {approx}150 mesurees avec le multicompteur Eurogam  

Energy Technology Data Exchange (ETDEWEB)

This work concerns the study of the nuclear superdeformation phenomenon in the rare earth region (A {approx} 150). The superdeformed (SD) states in Gadolinium and Dysprosium isotopes were produced via heavy-ion induced reactions and studied with the (EUROGAM EUROpean GAmma-ray Microscope) gamma multidetector array. Precise level attenuation method (DSAM). From the derived quadrupole moments, we find large differences in deformation between the yrast bands in neighbour nuclei explained in terms of the case of nuclei corresponding to an axis ratio of 2:1, the shell gaps are not fixed at a specific particle number and deformation. Furthermore the present results indicate that the deformations associated with identical bands are different supporting the picture that mass and deformation changes tend to compensate in SB bands with the same moments of inertia. (author). 114 refs.

1996-05-13

419

L'exercice physique d'endurance est plus efficace que l'exercice aerobie pour le controle par la pression arterielle sur 24heures chez des diabetiques de type 2  

British Library Electronic Table of Contents (United Kingdom)

Aim: The study aimed to analyze blood pressure (BP) responses in individuals with type 2 diabetes (T2D) over a 24h period following resistance (RES) and aerobic (AER) exercise. Methods: Ten adults with T2D (age: 55.8+/-7.7 years; weight: 79.4+/-14.0kg; fasting glucose: 133.0+/-36.7mg.dL^-^1) underwent: (1) AER: 20min of cycling at 90% lactate threshold (90% LT); (2) RES: three laps of a circuit of six exercises with eight repetitions at 70% 1-RM and 40s of recovery; and (3) a control session of no exercise. Heart rate (HR), and systolic (SBP), diastolic (DBP), mean arterial (MAP) and pulse (PP) BP, as well as lactataemia (Lac), VO2, respiratory exchange ratio (RER) and rate of perceived exertion (RPE) were measured at rest, during exercise and control (CON) periods, and 60min after interve...

2011-01-01

420

Isotope shift measurements at the {sup 242{ital f}}Am fission isomer  

Energy Technology Data Exchange (ETDEWEB)

Isotope shift measurements have been performed for the {sup 242{ital f}}Am fission isomer with target production rates of only a few per second. The method is based on resonance ionization spectroscopy (RIS) in a buffer gas cell with radioactive decay detection of the ionization process (RADRIS). A relative isotope shift ratio X{sub {ital exp}}=IS{sup 242{ital f},241}/IS{sup 243,241}=41.7{plus_minus}0.9 has been measured for the 500.02 nm transition corresponding to a nuclear parameter A{sup 242{ital f},241}=(5.4{plus_minus}0.3) fm{sup 2}. A preliminary analysis of the quadrupole moment based on the deformed Fermi model of the nuclear charge distribution results in Q{sub 20}=35.9{plus_minus}1.1({sup +0.3}{sub {minus}0.7}) {sub model} eb. {copyright} 1995 {ital American} {ital Institute} {ital of} {ital Physics}

1995-04-01

421

Intracellular monitoring of superoxide dismutase expression in an Escherichia coli fed-batch cultivation using on-line disruption with at-line surface plasmon resonance detection.  

Science.gov (United States)

An on-line cell disruption system for at-line monitoring of the intracellular concentration of recombinant human superoxide dismutase (rhSOD) in a genetically modified Escherichia coli strain, HMS174(DE3) (pET11a/rhSOD), in bioreactor cultivations is described. The sampled bacteria were disrupted on-line by rapid mixing with a nonionic detergent. The recombinant protein content of the lysed bacterial sample was quantitated by a subsequent surface plasmon resonance biosensor with a specific monoclonal antibody. Extraction efficiency of the monitoring system was optimized with respect to the flow rate ratio of the cell suspension and the detergent at relevant cell densities with the aim to attain rapid monitoring. Monitoring was demonstrated for a shake flask culture and a glucose-limited fed-batch cultivation. The results are compared with a traditional enzyme-linked immunosorbent assay method showing a correlation coefficient of R2 = 0.97. ...

2005-07-01

422

Interconnected project 'Development and testing of a biological monitoring for effects of polycyclic aromatic hydrocarbons on man'. Final report. Verbundprojekt Entwicklung und Erprobung biologischer Ueberwachungsmethoden (Biological Monitoring) bei der Einwirkung von polycyklischen aromatischen Kohlenwasserstoffen auf den Menschen. Abschlussbericht  

Energy Technology Data Exchange (ETDEWEB)

The research project had the aim to develop a standard for measuring individual, inner stresses from polycyclic aromatic hydrocarbons (PAHs) at work. The employed method was by characterizing PAHs and metabolites of PAHs to be identified in urine with a view to developing a biological monitoring of professionally exposured persons. Using a number of PAHs relevant to work, the following questions were studied in cell culture systems and different animal-experimental models: Which metabolites are formed from the PAHs used in cell culture systems and the different animal-experimental models, and what are their ratios in percent What percentage of a PAH is excreted by experimental animals in their urine and faeces on the first, second, and third day following different forms of application What is the scale of the individual range of variation of PAH mass excretion Are these results transferable to man (orig.).

1992-01-01

423

Initial stage of localized corrosion in artificial pits formed with photon rupture on Zn-5 mass% Al alloy-coated steel  

International Nuclear Information System (INIS)

The photon rupture method, by which oxide film and metal are removed by focused pulsed Nd-YAG laser beam irradiation, was applied to form artificial micro-pits in Zn-5 mass% Al alloy-coated steel. The zinc alloy-coated layer was removed by pulsed laser irradiation treatment for about one second in a neutral buffer solution with NaCl. The rest potential transient with the laser treatment was measured. In the early stage of the laser treatment the rest potential of zinc alloy-coated steel changed to the negative direction immediately after every irradiation of a laser pulse and then returned to the previous value. However, after the steel substrate was exposed to the solution, the rest potential moved to the positive direction immediately after every irradiation of a laser pulse and then returned to the previous value. The amplitude and duration of the potential change after the laser irradiation increased with repetition of laser irradiation, related to the pit ...

2007-05-01

424

Influence of microstructural characteristics on the mechanical properties of silicon nitride with Al{sub 2}O{sub 3}, Y{sub 2}O{sub 3} and Nd{sub 2}O{sub 3} as sintering aids  

Energy Technology Data Exchange (ETDEWEB)

Silicon nitride based ceramics have attracted considerable attention as good candidates for structural applications due to their excellent mechanical properties including strength, hardness, fracture toughness, and high temperature strength. These properties are strongly influenced by grain size and morphology, and by the degree of crystallinity and chemistry of grain boundary phases. In this work, the microstructure of Si{sub 3}N{sub 4} densified with Nd{sub 2}O{sub 3}, Y{sub 2}O{sub 3} and Al{sub 2}O{sub 3} sintering additives was studied. Sintered samples were polished and plasma etched for microstructural analysis using scanning electron microscope. Quantitative evaluation of materials microstructure was accomplished using Quantikov software. Fracture toughness was measured by Vickers indentation method. The observed microstructure is typical of silicon nitride based materials and is characterized by high aspect ratio.-Si{sub 3}N{sub 4} ...

2003-07-01

425

Influence of composite LiCl-KCl molten salt on microstructure and electrochemical performance of spinel Li4Ti5O12  

International Nuclear Information System (INIS)

A series of spinel Li4Ti5O12 samples were synthesized via a composite molten-salt method (CMSM) using the mixtures of LiCl and KCl with different L values (L is defined as the molar ratio of LiCl:KCl) as the reaction media. It is found that the melting point of the composite molten salt can effectively influence the formation of particles, and leads to different electrochemical performances of the as-prepare Li4Ti5O12. The investigations of X-ray diffraction (XRD), particle size distribution (PSD), Brunauer-Emmet-Teller (BET) surface area, and scanning electron microscopy (SEM) indicate that the as-prepared Li4Ti5O12 with L = 1.5 is a pure phase, and has uniform homogeneous octahedral shape particles, rather narrow PSD, and high BET surface area. Electrochemical tests show that the optimized Li4Ti5O12 with L = 1.5 has an initial discharge capacity of 169 mAh g-1 and an initial charge-discharge efficiency of 94% at 0.2 C rate, and achieves good ...

2008-12-30

426

Influence of composite LiCl-KCl molten salt on microstructure and electrochemical performance of spinel Li4Ti5O12  

British Library Electronic Table of Contents (United Kingdom)

A series of spinel Li4Ti5O12 samples were synthesized via a composite molten-salt method (CMSM) using the mixtures of LiCl and KCl with different L values (L is defined as the molar ratio of LiCl:KCl) as the reaction media. It is found that the melting point of the composite molten salt can effectively influence the formation of particles, and leads to different electrochemical performances of the as-prepare Li4Ti5O12. The investigations of X-ray diffraction (XRD), particle size distribution (PSD), Brunauer-Emmet-Teller (BET) surface area, and scanning electron microscopy (SEM) indicate that the as-prepared Li4Ti5O12 with L=1.5 is a pure phase, and has uniform homogeneous octahedral shape particles, rather narrow PSD, and high BET surface area. Electrochemical tests show that the optimized...

2008-01-01

427

In situ isotopic analyses of U and Pb in zircon by remotely operated SHRIMP II, and Hf by LA-ICP-MS: an example of dating and genetic evolution of zircon by 176Hf/177Hf from the Ita Quarry in the Atuba Complex, SE, Brazil  

International Nuclear Information System (INIS)

Remotely-operated SHRIMP dating of zircon is an interesting alternative for dating of zircon crystals. Although it does not represent any technical progress of the geochronological method using the U-Pb system in zircon it is a very useful and cheap facility. The procedure was first used for mass spectrometric analyses involving two international laboratories in Sao Paulo, Brazil and Beijing, China. It was applied to samples of three gneiss-migmatitic rocks from the Ita quarry in the Atuba Complex (located between the Luis Alves and the Apiai Domain) to test previous controversial hypotheses about its evolution. The presence of important archaean and paleo proterozoic components in the complex is confirmed by analyses of zircon found in probably neo proterozoic leucosomes. Diorite intrusion also occurred during the neo proterozoic, associated with the 0.6Ga continental collisions involved in the assembly of Gondwana. The determination of Hf isotope ...

2009-10-01

428

Hydrothermal synthesis of semiconductive PZT solid solutions and electromechancal properties of sintered bodies. Suinetsuho ni yoru handosei PZT koyotai no gosei to shoketsutai no denki kikaiteki seishitsu  

Energy Technology Data Exchange (ETDEWEB)

Semiconductive crystalline PZT powders doped with Bi and K were synthesized by hydrothermal reaction at 200{degree}C for 48 hours. The synthesis of the crystalline powders became difficult with an increase in doped amount of Bi and K, and in Zr/(Ti+Zr) ratio. Since substantial amounts of Pb remained in solution after hydrothermal reaction, the addition of Pb in excess of 25% was necessary to obtain the stoichiometric composition of the PZT solid solution. Bi contents in the powders were identical to those in starting materials, while K contents were less than expected ones. The electromechanical properties of the sintered bodies could be precisely measured by an admittance-curve-fitting method. The electromechanical coupling factor and piezoelectric coefficient of the sintered bodies varied with the Bi content like those of specimens prepared by solid state reaction, and showed the maximum values at a given Bi content. However, the change in ...

1989-10-01

429

HD 75289Ab revisited - Searching for starlight reflected from a hot Jupiter  

CERN Document Server

Aims. We attempt to detect starlight reflected from a hot Jupiter, orbiting the main-sequence star HD 75289Ab. We report a revised analysis of observations of this planetary system presented previously by another research group. Methods. We analyse high-precision, high-resolution spectra, collected over four nights using UVES at the VLT/UT2, by way of data synthesis. We try to interpret our data using different atmospheric models for hot Jupiters. Results. We do not find any evidence for reflected light, and, therefore, establish revised upper limits to the planet-to-star flux ratio at the 99.9% significance level. At high orbital inclinations, where the best sensitivity is attained, we can limit the relative reflected radiation to be less than e = 6.7 x 10-5 assuming a grey albedo, and e = 8.3 x 10-5 assuming an Class IV function, respectively. This implies a geometric albedo smaller than p = 0.46 and p = 0.57, for the grey albedo and the ...

2008-01-01

430

Frequency and risk factors of gout flares in a large population-based cohort of incident gout  

British Library Electronic Table of Contents (United Kingdom)

Objective. So far, few data are available to characterize the flare history of patients with gout. The objective of this study was to describe the frequency and risk factors of gout flares with special consideration of the comorbidity. Methods. A cohort study was conducted in a UK general practice database (The Health Improvement Network) including all patients aged 20-89 years diagnosed with incident gout between the years 2000 and 2007. Results. In this study, 23 857 incident gout patients (mean age 61.9 years) were included, overall incidence rate was 2.68 (95% CI 2.65, 2.72) per 1000 person-years. The proportion of patients with at least one flare during the follow-up period (mean 3.8 years) was 36.9% (n = 8806). A history of ischaemic heart disease [hazard ratio (HR) 1.12 (95% CI 1.06...

2011-01-01

431

Experiments on the formation of the A 15-compounds Nb-Sn and Nb-Ge by ion implantation  

International Nuclear Information System (INIS)

Nb_3Sn films (Tsub(c)=17.8 K) were obtained by implantation of Sn"+ ions into Nb films (1500 A thick) after subsequent annealing. The annealing temperature required for the formation of the A15 phase in the implanted films was about 100 K higher than for Nb-Sn sandwich films evaporated at 300 K. The influence of the Sn concentration and of the annealing temperature was studied by measuring the sample resistance. The Nb-Sn compounds formed during the annealing process were analysed by measurements of the Moessbauer-effect of "1"1"9Sn. The implantation method was also used to produce Nb-Ge films with a ratio Ge/Nb approximately 1/3. The Ge-concentration and the temperature of the Nb-target (300-1070 K) were varied. These variations as well as subsequent annealing at 600-850"0C did not lead to superconducting transition temperatures above 8 K. (Auth.).

432

Estimation of vapour pressure over MOX fuel  

International Nuclear Information System (INIS)

Use of high plutonia MOX as fuel is contemplated from the point of view of rapid disposition of plutonium and economic power generation. The fuel pellets are subjected to steep thermal gradients #approx# 1700 K drop across a radius of #approx# 2.5mm. This leads to evaporation-condensation of the fuel constituents to cooler regions. Vaporization depends on fuel compositions such as Pu fraction, Oxygen-to-Metal (O/M) ratio and local temperature. Knowledge of vapour chemistry is essential in understanding the fuel behavior. The vaporization behaviour of MOX was analyzed in this work using thermochemical methods. The vapour phase consisted of nine species; O, O_2, Pu, PuO, PuO_2, U, UO, UO_2 and UO_3. Oxygen formed part of the vapour phase along with other species and oxygen potential was not controlled independently. The vapour pressures were estimated at 2000 K as a function of (O/M) for several Pu-fraction. Results for MOX-28%PuO_2 is shown in ...

2010-12-01

433

Dutch urban bus driving cycle  

Energy Technology Data Exchange (ETDEWEB)

Deteriorating air quality in urban areas is leading bus manufacturers to look for cleaner drives of urban buses. Various new systems are now available, but it is difficult to compare them and verify their effects without having a driving cycle accurately representing contemporary average urban bus use. The idealized form (engine cycle, passenger car cycle or different kW/tonnes ratio and traffic conditions) of existing driving cycles disqualifies them for the purpose. For this reason, it was decided to attempt the development of a new driving cycle for urban buses. To this end, measurements were carried out on buses in service in four major Dutch towns. The resulting data were combined to produce a reference cycle comprising all data relating to urban bus use. Statistical methods were then used to compare a large number of 15-20 minute cycles with this reference cycle, until one was found that corresponded closely to the reference cycle. 5 ...

1994-12-31

434

Direct chemical information from special radiotracers as well as from outer X-ray excitation  

Energy Technology Data Exchange (ETDEWEB)

Radionuclides exhibiting in decaying a strong interaction between nucleus and electron shell (especially electron capture and internal conversion) are, in principle, sensitive to their chemical surroundings. Consequently, they can be used to yield chemical information after an appropriate labelling procedure. The information can be extracted from the decay rate variation as well as from their X-ray emission as a response to an inner-shell vacancy creation during nuclear deexcitation. As an example of the former method the relationship between the decay rate of /sup 99m/Tc and the chemical structures of pertechnetate and bis(meso-dimercapto-succinate)oxotechnetate(V) is considered. Lower expectations with respect to measuring techniques are associated with the observation of X-ray emission. For a number of elements (especially 3d transition elements) the K/sub ..cap alpha..//K/sub ..beta../ X-ray intensity ratio was found to be an indicator of ...

1983-09-01

435

Direct chemical information from special radiotracers as well as from outer X-ray excitation  

International Nuclear Information System (INIS)

Radionuclides exhibiting in decaying a strong interaction between nucleus and electron shell (especially electron capture and internal conversion) are, in principle, sensitive to their chemical surroundings. Consequently, they can be used to yield chemical information after an appropriate labelling procedure. The information can be extracted from the decay rate variation as well as from their X-ray emission as a response to an inner-shell vacancy creation during nuclear deexcitation. As an example of the former method the relationship between the decay rate of /sup 99m/Tc and the chemical structures of pertechnetate and bis(meso-dimercapto-succinate)oxotechnetate(V) is considered. Lower expectations with respect to measuring techniques are associated with the observation of X-ray emission. For a number of elements (especially 3d transition elements) the K/sub #alpha#//K/sub #betta#/ X-ray intensity ratio was found to be an indicator of the ...

1982-10-01

436

Dipole response of {sup 88}Sr up to the neutron-separation energy  

Energy Technology Data Exchange (ETDEWEB)

Dipole and quadrupole excitations in the semimagic N{sup .} = 50 nucleus {sup 88}Sr were investigated at the superconducting electron linear accelerator ELBE with bremsstrahlung produced at electron energies of 9.0, 13.2, and 16.0 MeV. About 160 {gamma} transitions were identified up to 12 MeV. By using polarized photons linear polarizations of about 50 {gamma} transitions were measured. In the energy range of 6 - 12 MeV there is only one M1 transition while all other transitions have E1 character. Statistical methods were applied in order to filter out inelastic transitions and to correct the intensities of the ground-state transitions for their branching ratios. The photoabsorption cross section obtained in this way provides information about the extension of the Giant Dipole Resonance towards energies below the neutron-separation energy. The experimental results are compared with existing data beyond the neutron-separation energy and with ...

2007-07-01

437

Cross-section measurements for (n, 2a) (n, p) and (n, #alpha#) reactions on strontium isotopes at the neutron energy about 14 MeV  

International Nuclear Information System (INIS)

Cross-sections for "8"4Sr(n, 2n)"8"3Sr, "8"6Sr(n, 2n)"8"5"mSr, "8"6Sr(n, 2n)"8"5Sr, "8"8Sr(n, 2n)"8"7"mSr, "8"4Sr(n, p)"8"4Rb, "8"6Sr(n, p)"8"6Rb, "8"8Sr(n, p)"8"8Rb and "8"8Sr(n, #alpha#)"8"5"mKr reactions have been measured at neutron energies from 13.5 to 14.6 MeV using activation technique and by means of #gamma#-ray spectrometry. The neutron flux was determined using the monitor reaction "9"3Nb(n, 2n)"9"2"mNb and the neutron energies were measured by the method of cross-section ratios for "9Zr(n, 2n)"8"9Zr to "9"3Nb (n, 2n)"9"2"mNb reactions. The results of present work are compared with data published previously.

2006-01-01

438

Cross section measurement for "2"0"4Pb(n,2n)"2"0"3Pb and "2"0"6Pb(n, #alpha#)"2"0"3Hg reactions  

International Nuclear Information System (INIS)

The cross sections of "2"0"4Pb(n,2n)"2"0"3Pb and "2"0"6Pb(n, #alpha#)"2"0"3Hg reactions have been measured by using the activation method in the neutron energy range of 13.50-14.81 MeV. Neutron fluence dose was calibrated with the cross sections of "2"7Al(n, #alpha#)"2"4Na reaction and neutron energies were determined by using the cross section ratios of "9"0Zr(n,2n)"8"9"m"+"gZr to "9"3Nb(n,2n)"9"2"mNb reactions. The results obtained are compared with the published data.

439

Corrosion in drilling and well stimulation  

Energy Technology Data Exchange (ETDEWEB)

Corrosion in drilling and well stimulation is described in relation to acid corrosion inhibition, acid inhibitors, acetylenic inhibitors, synergistic blends, metallurgy, wellbore tubulars, coiled tubing, and high alloy tubular materials. Acidizing is a procedure for stimulating oil and gas wells. Factors that have an important influence on the reaction rate and the way in which acid reacts with rock include temperature, acid concentration, acid volume, injection velocity, acid viscosity, and fluid loss properties of the formation. The cost of drill pipe failures are $1 per fot of hole drilled, which is a significant fraction of the drilling cost. Steps in a test procedure are listed, as well as factors which determine the extent of acid corrosion in a given situation including acid type and strength, metal type, temperature, contact time; pressure, and volume/surface area ratio. Underbalanced drilling is a method for completing oil and gas ...

1999-07-01

440

Characteristics of sugar uptake by immature maize embryos  

Energy Technology Data Exchange (ETDEWEB)

Characteristics of sugar uptake by immature maize embryos were determined in vitro utilizing a /sup 14/C-sugar solution incubation method. Hexose uptake rates were greater than those for sucrose, however, all showed biphasic kinetics. Glucose and fructose saturable components were evidence at <50 mM and sucrose at <5 mM. Chemical inhibitors (CCCP, DNP, NaCN, and PCMBS) and low temperature reduced sugar uptake. Sucrose influx was pH dependent while glucose was not. Embryos maintained a high sucrose to hexose ratio throughout development. At 25 days after pollination sucrose levels exceeded 200 mM while hexose levels remained below 5 mM. Glucose was rapidly converted to sucrose upon transport into the embryo. These circumstantial data indicate that sugar uptake by immature maize embryos is metabolically dependent and carrier mediated. Furthermore, sucrose transport appears to occur against its concentration gradient involving a H+/sucrose ...

1986-04-01

441

Burnup determination of spent nuclear fuel in the pool  

Energy Technology Data Exchange (ETDEWEB)

A algorithm was developed to determine the characteristic parameters of PWR spent fuel, such as burnup, cooling time and initial enrichment of {sup 235}U by use of gamma-ray activity ratios of {sup 134}Cs/{sup 137}Cs, {sup 154}Eu/{sup 137}Cs and {sup 106}Ru/{sup 137}Cs from the high resolution gamma-ray spectroscopy and ORIGEN-S calculations. For the verification of the method developed, gamma-ray measurements of Kori-1 and Kori-2 nuclear fuel rods were carried out using HPGe gamma ray scanning system. As a results, it is revealed that the measured values are in a good agreement with the operator declared values within the about {+-} 5% errors. Besides, the under-water burnup measuring device has been designed to measure the gamma-ray from the PWR spent fuel assembly. This device will be set up in the pool of Post-Irradiation Examination Facility(PIEF), and used in determination of the average burnup, cooling time and initial enrichment of the ...

1998-06-01

442

Biocatalytic desulfurization of petroleum and middle distillates  

Energy Technology Data Exchange (ETDEWEB)

Biocatalytic Desulfurization (BDS) represents an alternative approach to the reduction of sulfur in fossil fuels. The objective is to use bacteria to selectively remove sulfur from petroleum and middle distillate fractions, without the concomitant release of carbon. Recently, bacteria have been developed which have the ability to desulfurize dibenzothiophene (DBT) and other organosulfur molecules. These bacteria are being developed for use in a biocatalyst-based desulfurization process. Analysis of preliminary conceptual engineering designs has shown that this process has the potential to complement conventional technology as a method to temper the sulfur levels in crude oil, or remove the recalcitrant sulfur in middle distillates to achieve the deep desulfurization mandated by State and Federal regulations. This paper describes the results of initial feasibility studies, sensitivity analyses and conceptual design work. Feasibility studies with various crude oils ...

1993-02-01

443

Binary Pseudo-random Grating Standard for Calibration of Surface Profilometers  

Energy Technology Data Exchange (ETDEWEB)

We suggest and describe the use of a binary pseudo-random (BPR) grating as a standard test surface for measurement of the modulation transfer function (MTF) of interferometric microscopes. Knowledge of the MTF of a microscope is absolutely necessary to convert the measured height distribution of a surface undergoing metrology into an accurate power spectral density (PSD) distribution. For an'ideal' microscope with an MTF function independent of spatial frequency out to the Nyquist frequency of the detector array with zero response at higher spatial frequencies, a BPR grating would produce a flat 1D PSD spectrum, independent of spatial frequency. For a'real' instrument, the MTF is found as the square root of the ratio of the PSD spectrum measured with the BPR grating to the'ideal,' spatial frequency independent, PSD spectrum. We present the results from a measurement of the MTF of MicromapTM-570 interferometric ...

2008-01-16

444

Analysis of non-Gaussian CMB maps based on the N-pdf. Application to WMAP data  

CERN Document Server

We present a new method based on the N-point probability distribution (pdf) to study non-Gaussianity in cosmic microwave background (CMB) maps. Likelihood and Bayesian estimation are applied to a local non-linear perturbed model up to third order, characterized by a linear term which is described by a Gaussian N-pdf, and a second and third order terms which are proportional to the square and the cube of the linear one. We also explore a set of model selection techniques (the Akaike and the Bayesian Information Criteria, the minimum description length, the Bayesian Evidence and the Generalized Likelihood Ratio Test) and their application to decide whether a given data set is better described by the proposed local non-Gaussian model, rather than by the standard Gaussian temperature distribution. As an application, we consider the analysis of the WMAP 5-year data at a resolution of around 2 degrees. At this angular scale (the Sachs-Wolfe regime), ...

2008-01-01

445

An adjuvant autologous therapeutic vaccine (HSPPC-96; vitespen) versus observation alone for patients at high risk of recurrence after nephrectomy for renal cell carcinoma: a multicentre, open-label, randomised phase III trial  

British Library Electronic Table of Contents (United Kingdom)

Summary Background Treatment of localised renal cell carcinoma consists of partial or radical nephrectomy. A substantial proportion of patients are at risk for recurrence because no effective adjuvant therapy exists. We investigated the use of an autologous, tumour-derived heat-shock protein (glycoprotein 96)-peptide complex (HSPPC-96; vitespen) as adjuvant treatment in patients at high risk of recurrence after resection of locally advanced renal cell carcinoma. Methods In this open-label trial, patients were randomly assigned to receive either vitespen (n=409) or observation alone (n=409) after nephrectomy. Randomisation was done in a one to one ratio by a computer-generated pseudo-random number generator, with a block size of four, and was stratified by performance score, lymph node stat...

2008-01-01

446

Acidity of H-Y zeolites: Role of extralattice aluminum  

Science.gov (United States)

The nature of extralattice aluminum and its effect on acidity in zeolites was studied. A series of zeolites (some commercial), dealuminated by various methods, were obtained having Si/Al ratios between 1.5 and 20. These were characterized using volumetric sorption, XRD, AA, NMR, and reaction studies. Samples dealuminated using ammonium hexafluorosilicate were found to contain little or no extralattice aluminum. In contrast, steam-dealuminated zeolites had large amounts of extralattice aluminum. In some cases a significant portion of the extralattice aluminum was unobservable by [sup 27]Al NMR, suggesting the existence of an aluminum species of low symmetry. Proton NMR indicated that all the protons were associated with the lattice aluminum atoms. Depending on the preparation history, different groups of H-Y zeolites exhibited different maxima in catalytic activity as a function of aluminum content. The maxima in catalytic activity for n-pentane ...

1993-02-01

447

A one-pot synthetic approach to prepare palladium nanoparticles embedded hierarchically porous TiO2 hollow spheres for hydrogen peroxide sensing  

Science.gov (United States)

A simple one-step method to fabricate hierarchically porous TiO2/Pd composite hollow spheres without any template was developed by using solvothermal treatment. Pd nanoparticles (2-5 nm) were well dispersed in the mesopores of the TiO2 hollow spheres via in-situ reduction. In our experiment, polyvinylpyrrolidone played an important role in the synthetic process as the reducing agent and the connective material between TiO2 and Pd nanoparticles. HF species generated from solvothermal reaction leaded to the formation of TiO2 hollow spheres and Ostwald ripening was another main factor that affected the size and structure of the hollow spheres. The as-prepared TiO2/Pd composite hollow spheres exhibited high electrocatalytic activity towards the reduction of H2O2. The sensitivity was about 226.72 ?A mM-1 cm-2 with a detection limit of 3.81 ?M at a signal-to-noise ratio of 3. These results made the hierarchically porous TiO2/Pd composite a promising ...

2010-10-01

448

A numerical investigation of the aerodynamics of a furnace with a movable block burner  

Scientific Electronic Library Online (English)

Abstract in english In this work the air flow in a furnace was computationally investigated. The furnace, for which experimental test data are available, is composed of a movable block burner connected to a cylindrical combustion chamber by a conical quarl. The apertures between the movable and the fixed blocks of the burner determine the ratio of the tangential to the radial air streams supplied to the furnace. Three different positions of the movable blocks were studied at this time. A thr (more) ee-dimensional investigation was performed by means of the finite volume method. The numerical grid was developed by the multiblock technique. The turbulence phenomenon was addressed by the RNG k-epsilon model. Profiles of the axial, tangential and radial velocities in the combustion chamber were outlined. The map of the predicted axial velocity in the combustion chamber was compared with a map of the experimental axial velocity. The internal space ...

2007-06-01

449

A Wide-Band Electromagnetic Impedance Profiling System forNon-Invasive Subsurface Characterization  

Energy Technology Data Exchange (ETDEWEB)

A non-invasive, wide-band electromagnetic (EM) impedance difference system for shallow subsurface electrical structure characterization in environmental and engineering problems has been developed at the Lawrence Berkeley National Laboratory (LBNL). Electrical parameters of interest are electrical conductivity and dielectric permittivity that are deduced from the impedance difference data. The prototype system includes a magnetic loop transmitter, which operates between 0.1 MHz and 100 MHz, an electrical dipole antenna for observing the electric field, and a loop antenna for measuring the magnetic field.All antennas are mounted on a cart made of non-metallic material for easy movement of the whole array for profiling. Surface EM impedance difference is obtained by taking the difference of the ratios of the electric fields to the magnetic fields at selected frequencies at two different levels. Numerical simulations will be presented to verify this new approach. A ...

2004-12-17

450

MRI in the diagnosis of non-compacted ventricular Myocardium (NCVM) compared to echocardiography; MR-Tomographie in der morphologischen Darstellung der isolierten non-compaction des linksventrikulaeren Myokards (NCVM)  

Energy Technology Data Exchange (ETDEWEB)

Purpose: To report the detection of con-compacted ventricular myocardium (NVCM) with MRI compared to echocardiography in 8 patients. Material and methods: Non-compaction of the ventricular myocardium is a congenital disorder characterized by an altered structure of the myocardial wall resulting from an intrauterine arrest in endomyocardial embryogenesis. The morphological findings consist of a prominent meshwork of multiple myocardial trabeculations and deep intertrabecular recesses, communicating with the left ventricular cavity. 8 consecutive patients (mean age 7.3 years) with clinical and echocardiographic signs of NCVM were examined by MRI (1.5 T, Vision, Siemens) in short axis and 2- and 4-chamber views, using T{sub 1}-weighted TSE and Cine-GRE in 6 patients and true FISP sequences in 2 patients. MRI and echocardiography were evaluated for visibility, signs of NCVM and involvement of myocardial wall segments. Thickness was measured for non-compacted and ...

2003-09-01

451

Subcriticality measurements for two coupled uranyl nitrate solution tanks using /sup 252/Cf-source-driven neutron noise analysis methods  

Energy Technology Data Exchange (ETDEWEB)

The subcriticality of two interacting solution tanks was determined using /sup 252/Cf-source-driven neutron noise analysis methods. These experiments were the first test of this method for an interacting system with materials (in this case, uranyl nitrate) typical of nuclear materials in processing plants. The experiments were performed to test the conclusions from previous interaction experiments with uranium metal discs for a fissile system with moderation, and to provide data to test theoretical models for coupled systems. The uranium metal experiments showed that the subcritical neutron multiplication factor, k/sub eff/, could be determined using point kinetics without any correction for spatial effects from measurements with the source and detectors located adjacent to the same cylinder, whereas for source-detector configurations with either the source and/or detectors adjacent to different cylinders, a model which incorporates the ...

1986-01-01

452

Preliminary investigation of /sup 252/Cf-driven neutron noise analysis for subcritical fuel solution systems  

Energy Technology Data Exchange (ETDEWEB)

A method for determining the reactivity of highly subcritical systems of fissile material, using neutron-noise power spectral densities in conjunction with a /sup 252/Cf source, had previousy been tested in two fast reactor critical assemblies (a mockup of the Fast Flux Test Facility reactor and unreflected enriched uranium metal assemblies) and one thermal reactor (a light-water moderated and reflected lattice of Oak Ridge Research Reactor fuel elements). The last-mentioned test demonstrated the effectiveness of the method in water-moderated systems and thereby prompted the present study of its application to facilities for fuel preparation, reprocessing, and storage. To investigate the applicability of this method to facilities for fuel preparation, reprocessing, and storage, limited experiments were performed with a uranyl fluoride solution. The Los Alamos National Laboratory SHEBA facility, an unreflected cylindrical ...

1981-01-01

453

New microwave assisted radiolabelling method and rat brain biodistribution study of two new "9"9"mTc-tricarbonyl complexes as potential brain imaging agents  

International Nuclear Information System (INIS)

Two new cyclopentadienyl piperidine derivatives, namely ferrocene carboxylic acid 1-ethyl-3-hydroxypiperidinyl ester and ferrocene carboxylic acid 4-hydroxypiperidinyl ester, were synthesized. The ligands were then radiolabelled with "9"9"mTc using two different approaches. The first method consisted of reacting the ligand precursor with Mn(CO)_5Br in pertechnetate "9"9"mTcO_4 - in normal saline and dimethyl formamide (DMF) at 150 "oC for 1 h. The yields were 70% and 90%, respectively. For the second method, the reactions mixtures were placed in a microwave oven for 2 min at 650 watt. The yields were higher than 90% for both "9"9"mTc complexes. Biodistribution studies showed that tricarbonyl[#eta#"5-[carboxy-3-hydroxy(N-ethyl)piperidine]cyclopentadienyl] technetium(I) had the highest brain uptake. The regional distribution in the brain also demonstrated relatively higher uptake of tricarbonyl [#eta#"5-[carboxy-3-hydroxy(N-ethyl) ...

454

Gas-liquid flows in a microscale fractal-like branching flow network  

Energy Technology Data Exchange (ETDEWEB)

Two-phase air-water flows in a microscale fractal-like flow network were experimentally studied and results were compared to predictions from existing macroscale void fraction correlations and flow regime maps. Void fraction was assessed using (1) two-dimensional analysis of high-speed images (direct method) and (2) experimentally determined using gas velocities (indirect method). Fixed downstream-to-upstream length and width ratios of 1.4 and 0.71, respectively, characterize the five-level flow network. Channels were fabricated in a 38 mm diameter silicon disk, 250 {mu}m deep disk with a terminal channel width of 100 {mu}m. A Pyrex top allowed for flow visualization. Superficial air and water velocities through the various branch levels were varied from 0.007 m/s to 1.8 m/s and from 0.05 m/s to 0.42 m/s, respectively. Two-phase flow regime maps were generated for each level of the flow network and are well predicted by the ...

2009-10-15

455

Gas-liquid flows in a microscale fractal-like branching flow network  

International Nuclear Information System (INIS)

Two-phase air-water flows in a microscale fractal-like flow network were experimentally studied and results were compared to predictions from existing macroscale void fraction correlations and flow regime maps. Void fraction was assessed using (1) two-dimensional analysis of high-speed images (direct method) and (2) experimentally determined using gas velocities (indirect method). Fixed downstream-to-upstream length and width ratios of 1.4 and 0.71, respectively, characterize the five-level flow network. Channels were fabricated in a 38 mm diameter silicon disk, 250 ?m deep disk with a terminal channel width of 100 ?m. A Pyrex top allowed for flow visualization. Superficial air and water velocities through the various branch levels were varied from 0.007 m/s to 1.8 m/s and from 0.05 m/s to 0.42 m/s, respectively. Two-phase flow regime maps were generated for each level of the flow network and are well predicted by the ...

2009-10-01

456

Evaluation of Aution Max AX-4030 and 9UB Uriflet, 10PA Aution Sticks urine dipsticks in the automated urine test strip analysis.  

Science.gov (United States)

Abstract Background: Aution Max AX-4030, a test strip analyzer recently introduced to the market, represents an upgrade of the Aution Max AX-4280 widely employed for urinalysis. This new instrument model can allocate two different test strips at the same time. In the present study the two instruments have been compared together with the usage of Uriflet 9UB and the recently produced Aution Sticks 10PA urine strips, the latter presenting an additional test area for the measurement of urinary creatinine. Methods: Imprecision and correlation between instruments and strips have been evaluated for chemical-physical parameters. Accuracy was evaluated for protein, glucose and creatinine by comparing the semi-quantitative results to those obtained by quantitative methods. The well-known interference effect of high ascorbic acid levels on urine glucose test strip determination was evaluated, ascorbic acid influence was also evaluated on protein and ...

2011-09-26

457

Technical evaluation of Solar Cells, Inc., CdTe module and array at NREL  

Energy Technology Data Exchange (ETDEWEB)

The Engineering and Technology Validation Team at the National Renewable Energy Laboratory (NREL) conducts in-situ technical evaluations of polycrystalline thin-film photovoltaic (PV) modules and arrays. This paper focuses on the technical evaluation of Solar Cells, Inc., (SCI) cadmium telluride (CdTe) module and array performance by attempting to correlate individual module and array performance. This is done by examining the performance and stability of the modules and array over a period of more than one year. Temperature coefficients for module and array parameters (P{sub max}, V{sub oc}, V{sub max}, I{sub sc}, I{sub max}) are also calculated.

1996-05-01

458

Specific features and mechanisms of photoluminescence of nanostructured silicon carbide films grown on silicon in vacuum  

British Library Electronic Table of Contents (United Kingdom)

The light-emitting properties of cubic silicon carbide films grown by vacuum vapor phase epitaxy on Si(100) and Si(111) substrates under conditions of decreased growth temperatures (T gr ? 900?700?C) have been discussed. Structural investigations have revealed a nanocrystalline structure and, simultaneously, a homogeneity of the phase composition of the grown 3C-SiC films. Photoluminescence spectra of these structures under excitation of the electronic subsystem by a helium-cadmium laser (?excit = 325 nm) are characterized by a rather intense luminescence band with the maximum shifted toward the ultraviolet (?3 eV) region of the spectral range. It has been found that the integral curve of photoluminescence at low temperatures of measurements is split into a set of Lorentzian components. Th...

2011-01-01

459

Report on breast milk examinations carried out in Lower Saxony from 1987 until 1990  

International Nuclear Information System (INIS)

In the group of persistent aromatic hydrocarbons, the highest values were determined for polychlorinated biphenyls (PCB), total DDT and hexachlorobenzene (HBC). Comparisons of the relevant median values for the past six years led to the conclusion that the steep initial decline in the breast milk concentrations of DDT and HBC was followed by reductions at a much lower pace in the years after 1987. The time course of the concentration of the total PCB did not appear to follow any particular pattern. The mean contents of lead and cadmium remained by a wide margin below the threshold values for these heavy metals and thus were of no relevance from the toxicological point of view. It was found that the 134 and 137 cesium isotopes constituted no particular health hazard for breast-fed infants, as the relevant concentrations in breast milk were low. (VHE).

460

Relationships between hepatic trace element concentrations, reproductive status, and body condition of female greater scaup  

British Library Electronic Table of Contents (United Kingdom)

We collected female greater scaup (Aythya marila) on the Yukon-Kuskokwim Delta, Alaska during two breeding seasons to determine if concentrations of 18 trace elements in livers and eggs were elevated and if hepatic concentrations correlated with body condition or affected reproductive status. Fifty-six percent, 5%, and 42% of females, respectively, had elevated hepatic cadmium (Cd: >3mgg-1 dry weight [dw]), mercury (Hg: >3mgg-1dw), and selenium (Se: >10mgg-1dw). Somatic protein and lipid reserves were not correlated with hepatic Cd or Hg, but there was a weak negative correlation between protein and Se. Hepatic Cd, Hg, and Se were similar in females that had and had not initiated egg production. In a sample of six eggs, 33% and 100%, respectively, contained Se and Hg, but concentrations we...

2009-01-01

461

Private power in the country -- a chronology  

Energy Technology Data Exchange (ETDEWEB)

The chronology of installing solar power in a rural area of Ontario is described. The installation took all of seven years, and was characterized by a lot of joy, but also a lot of heartache and hardship, all of which are chronicled in this article. The project started with four solar modules generating 300 watts, nickel cadmium batteries of 225 Ah, an inverter of 600 watt, and a three-cylinder 6.5 Kw water-cooled propane generator. Today, nearly seven years later, the installation consists of 18 solar modules supplying 1350 watts of power, lead-acid batteries of 2770 Ah, a 2500 watt inverter, a one cylinder, 5.5 kw propane-gasoline generator, a heated, underground generator house, complete with an amp-hour meter and MPPT charge controller.

2003-06-30

462

Influence of Dopants on Characteristics of X-Ray Detectors Fabricated from Indium-, Gallium-, and Chlorine-Doped Cadmium Telluride Single Crystals  

Science.gov (United States)

Counting characteristics of X-ray detectors fabricated from indium-doped, gallium-doped, and chlorine-doped CdTe have been investigated. The detectors fabricated from indium-doped and gallium-doped crystals showed radiation-induced polarization, namely, a progressive decrease of count rate with an increase of photon fluence in the high-photon-fluence region, while the detectors fabricated from chlorine-doped crystals did not. Results from current-voltage characteristics of the detectors indicated that the different counting characteristics of these detectors originated from the difference in internal electric fields in each detector.

1995-08-01

463

Effects of Copper, Cadmium, and Zinc on the Hatching Success of Brine Shrimp (Artemia franciscana)  

British Library Electronic Table of Contents (United Kingdom)

Previous studies indicate that the hatching success of brine shrimp (Artemia franciscana) cysts is surprisingly sensitive to ambient metal concentrations. These studies estimated median effective concentrations (EC50s) of 7, 5, and 28??g l?1 for Cd, Cu, and Zn, suggesting that the hatching end point for A. franciscana is the most sensitive tested to date for Cd and Zn in saline environments and comparable in sensitivity with the most sensitive tested to date for Cu. Furthermore, these data suggest that brine shrimp are at significant risk from Cu and Zn in Great Salt Lake (GSL), UT, where ambient concentrations as high as 10 and 14??g l?1, respectively, have been measured. Given that brine shrimp appear to be successfully reproducing in GSL, we hypothesized that these toxicity values were ...

2006-01-01

464

Determination of selected microelements in polish herbs and their infusions  

Energy Technology Data Exchange (ETDEWEB)

Ba, Cd, Cr, Cu, Fe, Ni, Pb and Zn were determined in birch leaves (Folium Betulae), dandelion roots (Radix Taraxacae), hawthorn blossom (Inflorescentia Crataegi) and their infusions by graphite furnace atomic absorption spectrometry (GFAAS) after microwave digestion of plant samples. Infusions were made from herbs according to prescription for patients, provided by the producer of medicine on the package. The results obtained were compared with daily requirements for each element. Results show high content of cadmium in the medicinal plants analyzed. The highest level in infusions was observed for Ni and Zn (over 90% of the total element concentration for Ni and in most cases over 50% for Zn), and the lowest for Cd and Pb. The calculated daily intake of majority of the analyzed elements was very low (under 1% of daily requirements)

2007-08-01

465

Characteristics and development report for the T1576 power supply and the MC3935 battery  

Energy Technology Data Exchange (ETDEWEB)

This report describes the requirements, designs, performance, and development histories for the T1576 power supply and the MC3935 rechargeable battery. These devices are used to power Permissive Action Link (PAL) ground controllers. The T1576 consists of a stainless steel container, one SA3553 connector, and one MC3935 battery. The MC3935 is a vented nickel/cadmium battery with 24 cells connected in series. It was designed to deliver 5.5 Amp-hours at 25{number_sign}C and the one-hour rate, with a nominal voltage of 28 V. The battery was designed to operate for 5 years or 500 full charge/discharge cycles. The power supply is expected to last indefinitely with replacement batteries and hardware.

1993-10-01

466

Catalytic desulfurization of organic sulfur compounds over zeolite catalysts  

Energy Technology Data Exchange (ETDEWEB)

In the dehydrodesulfurization of ethanethiol at 400/sup 0/C, the activities of sodium X, Y, and A zeolites decreased in the order given as did the activities of nickel, cobalt, zinc, cadmium, copper, silver, lead, manganese, barium, calcium, sodium, and iron Y zeolite catalysts. A volcano-shape order was observed between the catalytic activity and the electronegativity of the metal ions. The changes in the activity of hydrogen Y zeolite catalyst in ethanethiol dehydrodesulfurization and cumene dealkylation by calcination agreed with the decrease in the Broensted acidity but were independent of Lewis acidity. For hydrodesulfurization of thiophene, the activities of nickel, cobalt, copper, and silver Y zeolite catalysts decreased in the order given and were greater than for a commercial hydrodesulfurization catalyst; reduced and presulfided catalysts showed selective hydrodesulfurization activity. Addition of 5% of nickel or molybdenum oxides to cobalt or nickel Y ...

1980-01-01

467

Biosorption of heavy metal ions on Rhodobacter sphaeroides and Alcaligenes eutrophus H16  

Energy Technology Data Exchange (ETDEWEB)

A fundamental study of the application of bacteria to the recovery of toxic heavy metals from aqueous environments was carried out. The biosorption characteristics of cadmium and lead ions were determined with purple nonsulfur bacteria, Rhodobacter sphaeroides and hydrogen bacteria, Alcaligenes eutrophus H16 that were inactivated by steam sterilization. A simplified version of the metal binding model proposed by Plette et al. was used for the description of meal binding data. The results showed that the biosorption of bivalent metal ions to whole cell bodies of the bacteria was due to monodentate binding to two different types of acidic sites: carboxilic and phosphatic-type sites. The number of metal binding sites of A. eutrophus was 2.4-fold larger than that of R. sphaeroides.

1998-01-15

468

A facile and green preparation of high-quality CdTe semiconductor nanocrystals at room temperature  

Energy Technology Data Exchange (ETDEWEB)

One chemical reagent, hydrazine hydrate, was discovered to accelerate the growth of semiconductor nanocrystals (cadmium telluride) instead of additional energy, which was applied to the synthesis of high-quality CdTe nanocrystals at room temperature and ambient conditions within several hours. Under this mild condition the mercapto stabilizers were not destroyed, and they guaranteed CdTe nanocrystal particle sizes with narrow and uniform distribution over the largest possible range. The CdTe nanocrystals (photoluminescence emission range of 530-660 nm) synthesized in this way had very good spectral properties; for instance, they showed high photoluminescence quantum yield of up to 60%. Furthermore, we have succeeded in detecting the living Borrelia burgdorferi of Lyme disease by its photoluminescence image using CdTe nanocrystals.

2008-06-18

469

Standardization of clinical decision making for the conduct of credible clinical research in complicated medical environments.  

UK PubMed Central (United Kingdom)

The likelihood that past experience will produce correct guides to current practice depends on the signal-to-noise ratio for the clinical problem of interest. If the signal-to-noise ratio is high, the...Full Text Available

1996-01-01

472

Cold startability and blue and white smoke in a small direct injection diesel engine. (4th report) Effects of cetane number and compression ratio  

Energy Technology Data Exchange (ETDEWEB)

The improvement of startability achieved by chemical ignition promotion at low temperature was studied theoretically and experimentally in terms of compression ratio and cetane number using a small direct injection diesel engine. The findings are as follows: The compression ratio and cetane number vary almost linearly. When the compression ratio increases by 1, the cetane number decreases by about 9. Since almost the same ignition condition at starting can be achieved by adjusting the number of cranking cycles, there is almost no influence of compression ratio and cetane number on ignition delay. When the soak temperature is -10{sup 0}C and the compression ratio is 18, the influence of the cetane number is almost negligible. Given the same starting time, the influence produced by an increase in compression ratio by 1 is equivalent to the influence produced by a ...

1988-11-25

473

Changes of magnetization transfer ratio according to rat brain development  

International Nuclear Information System (INIS)

We assessed the age-related changes in magnetization transfer ratio (MTR) value and the ratio of water content in rat brain (frontal lobe and pons) during normal development. All studies were done on 42 normal Wistar rats. MTR was calculated by using the equation (M_o_f_f-M_o_n)/M_o_f_f, where M_o_f_f and M_o_n were the measured signal intensities on the conventional and MT-prepared SPGR images, respectively. The ratios of water content were measured by comparing the wet weight with the dry weight of the frontal lobe and the pons, which were extracted from a rat brain soon after MTR measurements. The ratio of water content was calculated by using the equation 100 x (wet weight-dry weight)/wet weight (%). The ratio of water content decreased markedly during the first 30 days, but the decrease was very slight there after both in the frontal lobe and the pons. The change in MTR was ...

474

Calculation of cosmic ray antiproton-proton ratio  

Energy Technology Data Exchange (ETDEWEB)

Cross section parameterizations for antiproton production in pp collisions are used to predict the antiproton/proton ratio resulting from a flux of cosmic protons with energy spectral index of 2.6 interacting with a 5 gm/cm/sup 2/ column density of H. (GHT)

1980-01-01

475

Applications of BMI or BSI: Differences and Revisions According to Age and Height  

UK PubMed Central (United Kingdom)

Validation of body-mass relationships requires a careful statistical analysis of data of normal weight individuals. BMI (ratio between body mass and square of body height) and BSI values (ratio between...Full Text Available

2010-01-01

476

Coalfires related CO2 emissions and remote sensing  

Energy Technology Data Exchange (ETDEWEB)

Subsurface and surface coalfires are a serious problem in many coal-producing countries. Combustion can occur within the coal seams (underground or surface), in piles of stored coal, or in spoil dumps at the surface. While consuming a non renewable energy source, coalfires promote several environmental problems. Among all GHGs that are emitted from coalfires, CO2 is the most significant because of its high quantity. In connection to this environmental problem, the core aim of the present research is to develop a hyperspectral remote sensing and radiative transfer based model that is able to estimate CO2 concentration (ppmv) from coalfires. Since 1960s remote sensing is being used as a tool to detect and monitoring coalfires. With time, remote sensing has proven a reliable tool to identify and monitor coalfires. In the present study multi-temporal, multi-sensor and multi-spectral thermal remote sensing data are being used to detect and monitor coalfires. Unlike the earlier studies, the ...

2008-06-11

477

The distribution of mass-to-light ratio with radius in M31 and M33  

International Nuclear Information System (INIS)

1974. Netherlands Baldwin, JE Cambridge Univ. (UK). Cavendish Lab. Reidel.;

479

Surface Crystallization and Composition of Spinel and Acmite in High-Level Waste Glass  

Science.gov (United States)

Surface crystallization and surface-to-bulk ratio in high-level waste glasses.

2000-07-10

481

Quantitative bone scintigraphy in the evaluation of angular deformity of the lower extremity  

International Nuclear Information System (INIS)

A technique for quantitative analysis of growth plates in varus or valgus deformity about the knee has been developed. Computer-generated regions of interest are placed on magnification scintigraphs to divide distal femoral and proximal tibial physes into four equal segments. The ratio of counts in the medial half to counts in the lateral half was studied in 31 children (22 normal, 9 with angular deformity). Normal ratios were 0.74 to 0.98 for femora and 0.98 to 1.20 for tibias. In eight of nine patients with deformity, the ratio was abnormal; in two patients the ratio returned to normal when the deformity ceased to progress.

482

Hollow Glass Filament Reinforced Plastics for Deep ...  

Science.gov (United States)

... Problems investigated in various basic hollowness ratios include ultimate compressive strength, fatigue properties, buckling characteristics, and ...

1966-02-08

483

[Dependence of scattered Mn K alpha / K beta X-ray intensity ratio on the scatterer materials].  

Science.gov (United States)

The K alpha / K beta ratio of Mn KX-rays scattered by metallic samples changed remarkably with the geometry between the sample and the (55)Fe source-Si(Li) detector system. On the contrary, this intensity ratio changed little in the cases of non-metallic scatterer samples such as lucite or mylar. This difference is interpreted as due to the occurrence of strong or weak interference in the coherent scattering photons. PMID:7280291

1980-10-01

484

Is the Ksub(#beta#)/Ksub(#alpha#) X-ray intensity ratio dependent upon the energy of an inducing proton  

International Nuclear Information System (INIS)

Ksub(#beta#)/Ksub(#alpha#) X-ray intensity ratios have been measured for various elements between Z = 29 and Z = 79 for incident proton energies of 23.6, 32.1 and 43.6 MeV. The results yield no evidence for a variation in ratio with particle energy. (orig.).

1980-01-01

485

Hydrogen, Oxygen, and Carbon Isotope Ratios of Cellulose from Submerged Aquatic Crassulacean Acid Metabolism and Non-Crassulacean Acid Metabolism Plants  

UK PubMed Central (United Kingdom)

Isotope ratios of cellulose and cellulose nitrate from aquatic Crassulacean acid metabolism (CAM) and non-CAM plants were determined. Cellulose oxygen istope ratios for all plants that grew together...Full Text Available

1984-09-01

486

Energy dependence of Ksub(#beta#)/Ksub(#alpha#) intensity ratio of Si0_2 from proton induced ionisation  

International Nuclear Information System (INIS)

The Ksub(#beta#)/Ksub(#alpha# 12) x-ray intensity ratio of the Si K spectrum was measured for proton impact on Si0_2 in the energy range 300-800 keV. An energy dependence of the intensity ratio was found and an explanation is given in terms of multiple ionisation. (author).

1980-04-01

487

Chemical effects on L_#gamma#_1/L_#beta#_1 x-ray intensity ratio of molybdenum compounds  

International Nuclear Information System (INIS)

Chemical effects on the intensity ratio of LX-ray of molybdenum compounds irradiated by 11-keV electrons and by 3-MeV protons were studied using an x-ray crystal spectrometer. It was found that the intensity ratios of L_#gamma#_1/L_#beta#_1 markedly decrease with the increase of ionicity of molybdenum compounds, except for the case of metallic molybdenum. (author).

1987-06-01

488

The development of emissions of heavy metals in the Federal Republic of Germany from 1985 to 1995; Die Entwicklung der Schwermetallemissionen in der Bundesrepublik Deutschland von 1985 bis 1995  

Energy Technology Data Exchange (ETDEWEB)

Emission inventories were estimated for the airborne emissions of: Arsenic, Beryllium, Cadmium, Chromium, Cobalt, Copper, Mercury, Manganese, Molybdenum, Nickel, Lead, Antimony, Selenium, Tellur, Thallium, Zinc, Platinum, Palladium, Rhodium, Tin. The inventories were made for the status of 1985 and 1990. A prognosis was given for 1995. The investigations were made for the whole area of the Federal Republic of Germany including the former German Democratic Republic. Working point was an overview about the plant-specific emissions for the various industrial branches and the production statistics. The results are given as total emissions from the existing plants and industrial branches. (orig.) [Deutsch] Es erfolgte eine Abschaetzung der luftseitigen Emissionen fuer die Elemente: Arsen, Beryllium, Cadmium, Chrom, Kobalt, Kupfer, Quecksilber, Mangan, Molybdaen, Nickel, Blei, Antimon, Selen, Tellur, Thallium, Zink, Platin, Palladium, Rhodium und ...

1995-03-01

489

Report on breast milk examinations carried out in Lower Saxony from 1987 until 1990; Bericht ueber die in Niedersachsen von 1987-1990 durchgefuehrten Muttermilchuntersuchungen  

Energy Technology Data Exchange (ETDEWEB)

In the group of persistent aromatic hydrocarbons, the highest values were determined for polychlorinated biphenyls (PCB), total DDT and hexachlorobenzene (HBC). Comparisons of the relevant median values for the past six years led to the conclusion that the steep initial decline in the breast milk concentrations of DDT and HBC was followed by reductions at a much lower pace in the years after 1987. The time course of the concentration of the total PCB did not appear to follow any particular pattern. The mean contents of lead and cadmium remained by a wide margin below the threshold values for these heavy metals and thus were of no relevance from the toxicological point of view. It was found that the 134 and 137 cesium isotopes constituted no particular health hazard for breast-fed infants, as the relevant concentrations in breast milk were low. (VHE) [Deutsch] In der Gruppe der persistenten Chlorkohlenwasserstoffe werden die hoechsten Konzentrationen bei den ...

1992-02-01

490

Land Disposal Restrictions Treatment Standards: Compliance Strategies for Four Types of Mixed Wastes  

International Nuclear Information System (INIS)

This paper describes the unique challenges involved in achieving compliance with the Resource Conservation and Recovery Act (Public Law 94-580) Land Disposal Restrictions (LDR) treatment standards for four types of mixed wastes generated throughout the U.S. Department of Energy (DOE) complex: (1) radioactively contaminated lead acid batteries; (2) radioactively contaminated cadmium-, mercury-, and silver-containing batteries; (3) mercury-bearing mixed wastes; and (4) radioactive lead solids. For each of these mixed waste types, the paper identifies the strategy pursued by DOE's Office of Pollution Prevention and Resource Conservation Policy and Guidance (EH-43) in coordination with other DOE elements and the U.S. Environmental Protection Agency (EPA) to meet the compliance challenge. Specifically, a regulatory interpretation was obtained from EPA agreeing that the LDR treatment standard for wastes in the D008 'Radioactive Lead Solids' sub-category applies to ...

6000-01-01

491

Experimental studies of compact real-time neutron dosimeters  

International Nuclear Information System (INIS)

Full text: Semiconductor detectors coated with boron or lithium compounds have been studied for neutron detection for decades but, until recently, have been limited to thermal neutron detection efficiencies of less than 5%. We reported previously on development and simulation studies of perforated detectors whose perforations are filled with neutron-reactive material in order to produce higher detection efficiencies. Incorporation of bare and cadmium-backed detectors into battery-powered devices with low-power electronics enables us to produce compact personal neutron dosimeters that provide LED readout of counts, which can be related approximately to neutron dose. We report here on experimental studies with such compact devices; devices capable of direct readout in dose units are anticipated. The thermal and epithermal neutron flux densities from the tangential beam tube of the TRIGA Mark II reactor at Kansas State University were measured. Then, thermoluminescent ...

2008-06-01

492

Effects of perinatal exposure to low doses of cadmium or methylmercury on thyroid hormone metabolism in metallothionein-deficient mouse neonates  

International Nuclear Information System (INIS)

Perinatal exposure to cadmium (Cd) or methylmercury (MeHg) results in impaired neurodevelopment. Thyroid hormone is essential for normal brain development. However, the issue whether Cd or MeHg, especially at low doses, interrupts thyroid hormone action remains to be investigated. In the present study, effects of perinatal exposure to low levels of Cd or MeHg on thyroid hormone metabolism were examined using metallothionein I and II (MT-I/II) null or wild-type neonatal mice. Dams were exposed to 10 mg/L water of Cd or 5 mg/kg chow of MeHg from gestational day 0 to post-natal day 10 (PND 10). Sera, livers and brains were collected from neonates on PND 10. Iodothyronine deiodinase activities and serum thyroxine (T4) concentrations were measured. MeHg exposure failed to induce changes in serum T4 levels and liver type 1 deiodinase (D1) and brain type 2 deiodinase (D2) activities regardless of the MT genotype. However, exposure to MeHg resulted in a decrease in brain ...

2006-11-10

493

Coordinated responses of phytochelatin synthase and metallothionein genes in black mangrove, Avicennia germinans, exposed to cadmium and copper  

Energy Technology Data Exchange (ETDEWEB)

To evaluate the role of phytochelatins and metallothioneins in heavy metal tolerance of black mangrove Avicennia germinans, 3-month-old seedlings were exposed to cadmium or copper for 30 h, under hydroponic conditions. Degenerate Mt2 and PCS primers were synthesized based on amino acid and nucleotide alignment sequences reported for Mt2 and PCS in other plant species found in GenBank. Total RNA was isolated from A. germinans leaves and two partial fragments of metallothionein and phytochelatin synthase genes were isolated. Gene expression was evaluated with reverse transcripatase-polymerase chain reaction (RT-PCR) amplification technique. Temporal analysis showed that low Cd{sup 2+} and Cu{sup 2+} concentrations caused a slight (but not significant) increase in AvMt2 expression after a 16 h exposure time, while AvPCS expression showed a significant increase under the same conditions but only after 4 h. Results strongly suggest that the rapid increase in AvPCS ...

2007-08-01

494

Coordinated responses of phytochelatin synthase and metallothionein genes in black mangrove, Avicennia germinans, exposed to cadmium and copper  

International Nuclear Information System (INIS)

To evaluate the role of phytochelatins and metallothioneins in heavy metal tolerance of black mangrove Avicennia germinans, 3-month-old seedlings were exposed to cadmium or copper for 30 h, under hydroponic conditions. Degenerate Mt2 and PCS primers were synthesized based on amino acid and nucleotide alignment sequences reported for Mt2 and PCS in other plant species found in GenBank. Total RNA was isolated from A. germinans leaves and two partial fragments of metallothionein and phytochelatin synthase genes were isolated. Gene expression was evaluated with reverse transcripatase-polymerase chain reaction (RT-PCR) amplification technique. Temporal analysis showed that low Cd"2"+ and Cu"2"+ concentrations caused a slight (but not significant) increase in AvMt2 expression after a 16 h exposure time, while AvPCS expression showed a significant increase under the same conditions but only after 4 h. Results strongly suggest that the rapid increase in AvPCS expression ...

2007-08-01

495

Biosorption of lead, copper, and cadmium with continuous hollow-fiber microfiltration processes  

Energy Technology Data Exchange (ETDEWEB)

A hollow-fiber crossflow microfiltration membrane was utilized to retain a biomass of Pseudomonas aeruginosa PU21 for continuous biosorption of lead (Pb), copper (Cu), and cadmium (Cd) ions in single or ternary metal systems. The results obtained from the microfiltration systems showed that in both single and ternary biosorption, the metal removal efficiency based on a molar basis was clearly Pb > Cu > Cd. For a single-membrane process with an influent metal concentration of 200 {micro}M and a flow rate of 350 mL/h, the effluent concentration of Pb and Cu satisfied the national regulations for an influent volume of 6.3 L. With a three-metal influent, the adsorption capacity of the biomass for Pb, Cu, and Cd was reduced 4, 50, and 74% compared to that for single-metal adsorption. Selective biosorption with a three-column sequential microfiltration operation exhibited an enhancement of 40 and 57% of total metal removal for Cu and Cd, respectively, over the ...

1999-06-01

496

Biosorption of heavy metals  

Energy Technology Data Exchange (ETDEWEB)

Only within the past decade has the potential of metal biosorption by biomass materials been well established. For economic reasons, of particular interest are abundant biomass types generated as a waste byproduct of large-scale industrial fermentations or certain metal-binding algae found in large quantities in the sea. These biomass types serve as a basis for newly developed metal biosorption processes foreseen particularly as a very competitive means for the detoxification of metal-bearing industrial effluents. The assessment of the metal-building capacity of some new biosorbents is discussed. Lead and cadmium, for instance, have been effectively removed from very dilute solutions by the dried biomass of some ubiquitous species of brown marine algae such as Ascophyllum and Sargassum, which accumulate more than 30% of biomass dry weight in the metal. Mycelia of the industrial steroid-transforming fungi Rhizopus and Absidia are excellent biosorbents for lead, ...

1995-05-01

497

Hydrogen lines in the high-luminosity quasar B2 1225+31  

International Nuclear Information System (INIS)

The emission lines H#alpha#, H#beta#+[OIII], and L#alpha# have been observed in the high-redshift quasar 1225+31. The ratios of line intensities in 1225+31 are found to be L#alpha#/H#alpha#approx.0.8, H#alpha#/(H#beta#+[OIII]) approx.4, and 4ratio derived by Baldwin on the basis of a composite quasar spectrum, and with direct determination of this ratio in 3C 273 and PKS 0237--23. The ratio H#alpha#/H#beta# is in the range of values found for a sample of low-redshift quasars by Baldwin. The low value for the L#alpha#/H#alpha# ratio cannot be reasonably explained by foreground extinction between the Sun and 1225+31.

498

Constraining SN Ia Models Using X-ray Spectra of Clusters of Galaxies  

CERN Document Server

We present constraints on theoretical models of Type Ia SNe using spatially resolved ASCA X-ray spectroscopy of four galaxy clusters: Abell 496, Abell 2199, Abell 3571 & Perseus. All four clusters have central Fe abundance enhancements and an ensemble of abundance ratios are used to show that most of the Fe in the central regions of the clusters comes from SN Ia. At the center of each cluster, simultaneous analysis of spectra from all ASCA instruments shows that the Ni to Fe abundance ratio (normalized by the solar ratio) is ~ 4. We use the Ni/Fe ratio as a discriminator between SN Ia explosion models: the Ni/Fe ratio of ejecta from the "Convective Deflagration" model W7 is consistent with the observations, while those of "delayed detonation" models are not consistent at the 90% confidence level.

2000-01-01

499

Feasibility of /sup 252/Cf source driven neutron noise measurements in water moderated reactors  

Energy Technology Data Exchange (ETDEWEB)

Previous experiments in fast critical assemblies demonstrated a method of determining reactivity from power spectral density measurements with /sup 252/Cf. This method determines reactivity from properties of the reactor only at the subcritical state of interest, thus it does not require a calibration near delayed criticality. The interpretation of the measured data to obtain reactivity does not require knowledge of the relative or absolute values of the source intensity, knowledge of the detection efficiencies, or knowledge of the detection instrumentation frequency responses. An experiment was performed at the Pool Critical Assembly to evaluate the possibility of /sup 252/Cf source driven neutron noise spectral density measurements in light water moderated reactors. This experiment showed that using commercially available detectors, such measurements can be performed in a reasonable time, that is, the measurement of the quantity of interest ...

1980-01-01