Molar extinction coefficients of some carbohydrates viz. L-arabinose (C5H10O5), D-glucose (C6H12O6), D-mannose (C6H12O6), D-galactose (C6H12O6), D(-) fructose (C6H12O6) and maltose (C12H24O12) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by gamma ray transmission method in a narrow beam good geometry set-up. These coefficients have been found to depend upon the photon energy following a 4-parameter polynomial. These extinction coefficients for different sugars having the same molecular formula have same values varying within experimental uncertainty. Within concentration ranges studied, Beer--Lambert law is obeyed very well.
Knighton et al. used a pulsed high pressure mass spectrometer to examine thermal electron detachment from C_6F_6"-. This technique had been used earlier for the measurement or detachment rate coefficients for azulene anions as a function of temperature. C_6F_6"- and c-C_4F_6"- have been studied by Datskos et al. using a pulsed drift tube. In our laboratory, we have used a flowing afterglow Langmuir probe (FALP) apparatus to measure the thermal electron detachment rate coefficient for c-C_4F_8"- ions at 375 K. We have also measured the electron attachment rate coefficient for c-C_4F_8 at 303 K and 375 K. (author).
This paper is devoted to investigate the influences of thermal dispersion and magnetic field on a hot semi-infinite vertical porous plate embedded in a saturated Darcy-Forchheimer-Brinkman porous medium. The coefficient of thermal diffusivity has been assumed to be the sum of the molecular diffusivity and the dynamic diffusivity due to mechanical dispersion. The effects of transverse magnetic field parameter (Hartmann number Ha), Reynolds number Re (different velocities), Prandtl number Pr (different types of fluids) and dispersion parameter on the wall shear stress and the heat transfer rate are discussed.
A ferritic steel with finely dispersed precipitates was investigated to reveal the fundamental strengthening mechanisms. The steel has a yield strength of 760MPa, approximately three times higher than that of conventional Ti-bearing high strength hot-rolled sheet steels, and its ultimate tensile strength reaches 850MPa with an elongation-to-failure value of 18%. Using energy dispersive X-ray spectroscopy (EDXS) and transmission electron microscope (TEM), fine carbides TiC with an average diameter of 10nm were observed in the ferrite matrix of the 0.08%Ti steel, and some cubic M23C6 precipitates were also observed at the grain boundaries and the interior of the grains. The finely dispersed TiC precipitates in the matrix provide matrix strengthening. The estimated magnitude of precipitation ...
A study was made on extraction of a series of lithium and calcium salts by monopodands L with common formula R-C_6H_4-O-(CH_2CH_2O)_n-C_6H_4-R, where R - CH_2P(O)Ph_2, n 1-3. Extraction-chromatographic separation of lithium and calcium isotopes in systems of metal aquacomplex-solvatocomplex with L in organic phase was conducted. It was established that separation coefficients of "6Li/"7Li isotopes ranged between 1.003 #+-#0.001 and 1.017 #+-#0.002 at the maximal separation degree equal to 1.60. Separation of "4"0Ca/"4"4Ca isotopes was not fixed. 12 refs., 4 figs., 1 tab.
The propagation of acoustic pressure perturbations in an adiabatic low-quality air/water flow were investigated both theoretically and experimentally. A linearized dispersion model is correlated with data to extract information on the behavior of interfacial momentum transfer controlled by the virtual volume coefficient. The dispersion model is examined in limiting cases of low and high frequency and related to current models for critical flow velocity. Fourier decomposition techniques are employed to predict the dispersion of measured pressure pulses and to relate data for standing waves and propagating pulses. The dispersion model is based on a two-fluid model and is the most complete model available in the literature at this time. The dispersion data presented herein is also the best available to date for low frequency (i.e., frequencies less than bubble ...
Molar extinction coefficients of some commonly used solvents (ethanol (C_2H_5OH), methanol (CH_3OH), propanol (C_3H_7OH), butanol (C_4H_9OH), water (H_2O), toluene (C_7H_8), benzene (C_6H_6), carbontetrachloride (CCl_4), acetonitrile (C_4H_3N), chlorobenzene (C_6H_5Cl), diethylether (C_4H_1O) and dioxane (C_4H_8O_2)) have been determined by a well-collimated narrow beam transmission geometry at 279, 356, 662, 1173, 1252 and 1332 keV #gamma# rays. The total #gamma# ray interaction cross sections of these solvents have also been determined. A good agreement has been obtained between the experimental results with the theoretical values evaluated through XCOM calculations.
A study for Cs-137 radionuclide dispersion in the marine environment through of compartmental model (Box Model) is presented. The model simulates the surface water contamination caused by direct atmospheric deposition, surface wash off, desorption from sediments and transfer with the ground water of accidentally released radionuclides. For this study the model was applied to the North Sea, near to Sellafield, based on the transfer coefficients obtain at the literature. The results obtained are in good agreement with the literature, being that the model developed can be applied in to the brazilian coastal regions. (author). 7 refs, 7 figs.
The attenuation of gamma rays in some fatty acids, viz. formic acid (CH_2O_2), acetic acid (C_2H_4O_2), propionic acid (C_3H_6O_2), butyric acid (C_4H_8O_2), n-hexanoic acid (C_6H_1_2O_2), n-caprylic acid (C_8H_1_6O_2), lauric acid (C_1_2H_2_4O_2), myristic acid (C_1_4H_2_8O_2), palmitic acid (C_1_6H_3_2O_2), oleic acid (C_1_8H_3_4O_2) and stearic acid (C_1_8H_3_6O_2), has been measured at the photon energies 81, 356, 511, 662, 1173 and 1332 keV. Experimental values for the molar extinction coefficient, the effective atomic number and the electron density have been derived and compared with theoretical calculations. There is good agreement between experiment and theory.
Abstract A series of polypropylene carbonate (PPC)/ZnO nanocomposite films with different ZnO contents were prepared via a solution blending method. The morphological structures, thermal properties, oxygen permeability, water sorption, and antibacterial properties of the films were investigated as a function of ZnO concentration. While all of the composite films with less than 5 wt % ZnO exhibited good dispersion of ZnO in the PPC matrix, FTIR and SEM results revealed that solution blending did not lead to a strong interaction between PPC and unmodified ZnO. As such, poor dispersion was induced in the composite films with a high ZnO content. By incorporating inorganic ZnO filler nanoparticles, the diffusion coefficient, water uptake in equilibrium, and oxygen permeability decreased as the ...
The characteristics of the temperature dependence of the upper critical magnetic field, Hc2(T), of structurally inhomogeneous superconductors (e.g., ternary molybdenum chalcogenides, A-15 compounds, transition metal alloys, and amorphous films) are investigated analytically. The MWGH equation for Hc2(T) is generalized to the case of weakly inhomogeneous systems with a characteristic inhomogeneity scale much smaller than the effective coherence length. It is shown that an increase in the dispersion of the diffusion coefficient leads to an increase in the slope and width of the linear section of the Hc2(T) curve. 11 references.
Out of the R and D of mesoscopic metal group composite materials, the paper described the fiscal 1997 results. In the in-situ method as a composite material making method, elucidated to some degree were chemical composition of Fe-C-Cr-V-Nb-Mo-W-Ni base multi-dimensional alloys, and wear resistance and oxidation resistance of MC type carbide dispersion multi-phase texture crystallizing as primary crystal and eutectic. In the composite material making with ceramic fiber and alloy by the pressure infiltration method, the paper clarified the texture formation mechanism in solidification/heat treatment by a combination of Al alloys and alumina long fiber, and the relation between fiber configuration and wear resistance. By MA and MG methods as the powder metallurgy composite material making method, a composed body of {alpha}-stainless steel of Fe-12%Cr composition and M23C6 of 40-90vol% are designed for alloy composition, and ...
A reliability approach for probabilistic modeling of one-dimensional non-reactive and reactive transport in porous media provides two important quantitative results: (1) an estimate of the probability that dimensionless concentration equals or exceeds some specified level and, (2) the sensitivity of the probabilistic outcome to likely changes in each uncertain variable. The reliability approach is particularly attractive because it can incorporate various marginal probability density functions (PDF) for any of the uncertain variables. In this work uncertain variables include: groundwater flow velocity, diffusion coefficient, dispersivity, distribution coefficient, porosity and bulk density. The primary objective is to examine how the probabilistic outcome is influenced by choice of marginal PDF, correlation and magnitude of uncertainty for the variables. Because little information exists concerning the statistical ...
The primary concern of this work is to study the emission characteristics of a series of chiral nematic liquid crystal lasers doped with different laser dyes (DCM, pyrromethene 580, and pyrromethene 597) at varying concentrations by weight (0.5-2 wt %) when optically pumped at 532 nm. Long-wavelength photonic band-edge laser emission is characterized in terms of threshold energy and slope efficiency. At every dye concentration investigated, the pyrromethene 597-doped lasers exhibit the highest slope efficiency (ranging from 15% to 32%) and the DCM-doped lasers the lowest (ranging from 5% to 13%). Similarly, the threshold was found to be, in general, higher for the DCM-doped laser samples in comparison to the pyrromethene-doped laser samples. These results are then compared with the spectral properties, quantum efficiencies and, where possible, fluorescence lifetimes of the dyes dispersed in a common nematic host. In accordance with the low thresholds and high slope ...
New York City data indicate that seasonal and annual variations in dispersion-normalized air pollutant concentrations appear to accurately reflect changes in source emission patterns. The normalized concentrations make it possible to observe the impact of regulatory changes on ambient air quality without these impacts being obscured by meteorological fluctuations. It is found that numerical modeling techniques and regression analysis can be powerful tools for extracting information from large sets of air quality data. The use of differential, as opposed to absolute, pollutant concentration values will reduce artifact correlations caused by seasonal, weekly, or daily meteorological fluctuations and will permit more accurate estimation of the regression coefficients. This technique was successfully applied to a set of daily pollution measurements whose absolute concentrations were found not to yield a statistically significant fit by multiple ...
New York City data indicate that seasonal and annual variations in dispersion-normalized air pollutant concentrations appear to accurately reflect changes in source emission patterns. The normalized concentrations make it possible to observe the impact of regulatory changes on ambient air quality without these impacts being obscured by meteorological fluctuations. It is found that numerical modeling techniques and regression analysis can be powerful tools for extracting information from large sets of air quality data. The use of differential, as opposed to absolute, pollutant concentration values will reduce artifact correlations caused by seasonal, weekly, or daily meteorological fluctuations and will permit more accurate estimation of the regression coefficients. This technique was successfully applied to a set of daily pollution measurements whose absolute concentrations were found not to yield a statistically significant fit by multiple ...
The temperature dependences of the Grueneisen parameter, heat capacity, bulk modulus and linear thermal expansion coefficient of sixteen III-V zincblende compounds are studied by first-principles response-function calculations. The fundamental relationships among these physical parameters are explored. Negative thermal expansions at lower temperature are found in most of these III-V phases except for the nitrides and boron compounds. By analyzing the cell-volume dependences of the phonon spectrum, it is found that the phases with a negative thermal expansion show a significant acoustic phonon weakening at the X-point in their phonon dispersion, while slight weakening is only seen around the L-point for those boron phases. There is no sign of phonon weakening in the nitrides. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Fine-grained BaTiO3-based X7R ceramic materials were prepared and the effects of milling process on the core-shell structures and dielectric properties were investigated using scanning electron microscope, transmission electron microscope, and energy dispersive spectroscopy (EDS). As the milling time extends, the dielectric constant of the ceramics increases, whereas the temperature coefficient of capacitance at 125degreeC drops quickly. The changes in dielectric properties are considered relevant to the microstructure evolution caused by the milling process. Defects on the surface of BaTiO3 particles increase because of the effects of milling process, which will make it easier for additives to diffuse into the interior grains. As the milling time increases, the shell region gets thicker a...
In the present study the optical properties of co-evaporated indium sulfide thin films are investigated. Before being optically characterized, the composition as well as the crystalline properties of the film have been checked with the help of energy dispersive spectroscopy (EDX) and X-Ray diffraction (XRD) analyses. The optical absorption coefficient ? of this indium sulfide film has been deduced from reflectivity R(?) and transmission T(?) measurements. The fit of the curve representing ?(h?) suggests that the ?-In2S3 has an indirect bandgap of 2.01?eV. Density functional theory (DFT) calculations are performed on this indium sulfide compound, using TB-LMTO code. Through these band structure investigations, an indirect bandgap is predicted as observed experimentally. The top of the valen...
High resolution Monte-Carlo simulations show that the neutron spectrum, fuel burnup and fuel temperature feedback effect of a PWR core loaded with Thoria-based fuel (Th/Pu-O_2) do not significantly differ from the MOX fuelled one due to the similar neutronic characteristics of both fertile materials (Th-232, U-238). The core physics of this fuel variant is characterized by an enhanced moderator/void temperature coefficient (by factor 2.4) and high incineration rate for Pu (approx. 60 %). A PWR core loaded with the Molybdenum-based inert matrix fuel (IMF) - in contrast to MOX-, shows a harder spectrum, resulting in small temperature coefficients of reactivity and particularly in a higher fuel depletion rate as well as an enhanced TRU reduction performance. The incineration of Pu amounts to 46 % resulting, in turn, in generation of minor actinides of about 10 % of the total Pu consumption. The higher excess reactivity resulting from the initial ...
Abstract Lyme neuroborreliosis (LNB) is a serious but treatable disease. The diagnosis of LNB poses a challenge to clinicians, and improved tests are needed. The C6-peptide ELISA is frequently used on serum but not on cerebrospinal fluid (CSF). Data on the sensitivity of the C6-peptide ELISA in CSF in patients suffering from LNB have been conflicting. Serum-CSF pairs from 59 LNB patients, 36 Lyme non-neuroborreliosis cases, 69 infectious meningitis/encephalitis controls and 74 neurological controls were tested in a C6-peptide ELISA. With the optimal cut-off of 1.1, the sensitivity of the C6-peptide ELISA for LNB patients in CSF was 95%, and the specificity was 83% in the Lyme non-neuroborreliosis patients, 96% in the infectious controls, and 97% in the neurological controls. These results ...
In this paper, a phenomenological model of the thermal hydraulics of convective boiling in the post-critical-heat-flux (post-CHF) regime is developed and discussed. The model was implemented in the TRAC-PF1/MOD2 computer code (an advanced best-estimate computer program written for the analysis of pressurized water reactor systems). The model was built around the determination of flow regimes downstream of the quench front. The regimes were determined from the flow-regime map suggested by Ishii and his coworkers. Heat transfer in the transition boiling region was formulated as a position-dependent model. The propagation of the CHF point was strongly dependent on the length of the transition boiling region. Wall-to-fluid film boiling heat transfer was considered to consist of two components: first, a wall-to-vapor convective heat-transfer portion and, second, a wall-to-liquid heat transfer representing near-wall effects. Each contribution was considered separately in each of the inverted ...
In this paper we discuss the effect on the emittance of the residual dispersion in the insertion devices. The dispersion in the straights could be generated by the lattice error, trim dipole, and insertion device. The effect on the emittance is examined, and the dispersion tolerances are given for the NSLS-11.
Radical cations of various 3-methylalkanes (C_6-C_1_4) have been produced and stabilized by #gamma#-irradiation of the corresponding neutral compounds in saturated chlorofluorocarbon and perfluorocarbon matrices at 77 K. The perfluorocarbon matrices appeared more suitable for studies of the lighter radical cations, whereas the chlorofluorocarbon matrices were more suited for studies of the heavier radical cations; intermediary cations could be studied in both types of matrices. After irradiation, electronic absorptions associated with both the matrix and the alkane additive were observed. Pure spectra of the 3-methylalkane radical cations were obtained by difference spectrometry, after selective elimination of these cations by illumination. The electronic absorption spectra of the 3-methylalkane radical cations consist in all cases of a single broad absorption band. The spectral position of this band shifts to longer wavelengths with increasing ...
Here I provide a brief overview of recent experimental gas-phase measurements using the Selected-Ion Flow Tube or SIFT technique at 294#+-#2 K with helium buffer gas at 0.35 Torr for reactions which remove electrons from the C_6_0 molecule or donate electrons to singly and multiply-charged C_6_0 cations. The results of these measurements have provided new insight into physicochemical aspects of electron transfer and have revealed the occurrence of unprecedented electron transfer reactions at thermal energies. (author).
The authors used radioligand binding and studies of cell contraction to characterize muscarinic receptors on dispersed smooth muscle cells from rabbit proximal and distal colon. Cells obtained after serial incubations in collagenase were used to measure binding of tritiated quinuclidinyl benzilate (["3H]QNB). At 37 degree C, specific ["3H]QNB binding was saturable and linearly related to cell number. Nonlinear regression analysis was used to determine the affinity of ["3H]QNB for its receptor. The IC_5_0 for the muscarinic agonists bethanechol and oxotremorine were 80 and 0.57 #mu#M, respectively. Hill coefficients were 0.67 for both, suggesting more complex interaction involving receptors of different affinities. In studies of cell contraction, bethanechol stimulated a dose-dependent decrease in cell length with half the maximal contraction occurring at 100 pM. These results suggest that (1) contraction is mediated by binding of bethanechol to ...
In addition to ceramics, alloys such as tool steel and nickel- and iron-based superalloys are being considered for high temperature applications such as missile bearings and low heat rejection engines. Studies were made to lubricate a nickel-based superalloy at 500{degrees}C, by using a vaporized aryl phosphate ester, at a concentration of 0.1% in air. From deposition and wear studies it was found that it was impossible to form a good polymeric coating on the superalloy surface. Energy dispersive X-ray analyzer (EDXA) analysis showed that this was due to minute quantities of aluminum in the alloy segregating to the surface, upon being heated to 500{degrees}C, forming a passive oxide coating. It was necessary to activate the surface, in order to lubricate the material successfully. A method of activation by electrodepositing the surface with a layer of iron oxide was developed. Once activated, a good lubricous polymer was formed on the superalloy surface. Tests ...
In the present paper the tribological behavior of the coatings are discussed. Duplex coatings were applied on cold working steel 100Cr6. Samples were plasma nitrided at different thickness of plasma surface layers. TiN was deposited with a classic BALZERS PVD equipment and subsequent ion implantation. Ion implantation was provided with N{sup 5+} ions. The other samples were produced with IBAD technology in DANFYSIK chamber. Wear resistance and exchanges of friction coefficient were measured with on-line test using special designed tribology equipment. Following the tests, the wear zone morphology and characteristics of surface layer structure as well as important properties were investigated by scanning electron microscopy (SEM) and X-ray diffraction analysis (XRD). Scratch adhesion testing was performed using commercially available equipment. Energy dispersive X-ray analysis (EDAX) of the wear-scars on pins provided essential information on ...
A series of 22 steady-state, rod bundle, dispersed flow film boiling experiments has been performed in the Thermal-Hydraulic Test Facility (THTF), a pressurized-water loop containing 64 full-length electrically heated rods. Test parameters in the upflow experiments cover a wide range of conditions typical of those which might be encountered during a nuclear reactor loss-of-coolant accident. Local equilibrium fluid conditions were calculated using mass and energy conservation considerations. Experimentally determined heat transfer coefficients were compared to several available film boiling heat transfer correlations: Dougall-Rohsenow, Groeneveld 5.7, Groeneveld-Delorme, Chen, Jones-Zuber, and Yoder-Rohsenow. The Groeneveld 5.7 correlation tended to predict the data better than any other correlation tested. The Dougall-Rohsenow correlation tends to overpredict the data while the Yoder-Rohsenow correlation predicted the data better than the other ...
Microstructural evolution due to thermal effects was studied in micro solder joints (55 {+-} 5 {micro}m). The composition of the Sn/Pb solder studied was found to be hypereutectic with a tin content of 65--70 wt%.This was determined by Energy Dispersive X-ray analysis and confirmed with quantitative stereology. The quantitative stereological value of the surface-to-volume ratio was used to characterize and compare the coarsening during thermal cycling from 0--160 C to the coarsening during annealing at 160 C. The initial coarsening of the annealed samples was more rapid than the cycled samples, but tapered off as time to the one-half as expected. Because the substrates to which the solder was bonded have different thermal expansion coefficients, the cycled samples experienced a mechanical strain with thermal cycling. The low-strain cycled samples had a 2.8% strain imposed on the solder and failed by 1,000 cycles, despite undergoing less ...
An objective methodology is presented for determining the number and disposition of ambient air-quality stations in a monitoring network for the primary purpose of compliance with air-quality standards. The methodology utilizes a data base with real or simulated data from an air quality dispersion model for application with a two-step process for ascertaining the optimal monitoring network. In the first step, the air-quality patterns in the data base are collapsed into a single composite pattern through a figure-of-merit (FOM) concept. The most-desirable locations are ranked and identified using the resultant FOM fields. In the second step the network configuration is determined on the basis of the concept of spheres of influence (SOI) developed from cutoff values of spatial-correlation coefficients between potential monitoring sites and adjacent locations. The minimum number of required stations is then determined by deletion of lower-ranked ...
Hydrolysis kinetics of the lead silicate glass (LSG) with 40 mol% PbO in 0.5 N HNO_3 aqueous acid solution was investigated. The surface morphology and the gel layer thickness were studied by scanning electron microscopy (SEM) micrographs. Energy dispersive X-ray spectroscopy (EDS) and inductively coupled plasma spectroscopy (ICP) were used to determine the composition of the gel layer and the aqueous solution, respectively. The silicon content of the dissolution products was determined by using weight-loss data and compositions of the gel layer and the solution. The kinetic parameters were determined using the shrinking-core-model (SCM) for rate controlling step. The activation energy obtained for hydrolysis reaction was Q_c_h_e = 56.07 kJ/mole. The diffusion coefficient of the Pb ions from the gel layer was determined by using its concentration in solution and in LSG. The shrinkage of the sample and the gel layer thickness during dissolution ...
Dispersal can be regarded as a process operating both between and within patches of suitable habitat. For uncontrolled dispersal processes, the risk of crossing the borders of the habitat patch and arriving in the unsuitable landscape matrix will increase with decreasing patch area, in particular when the distance between isolated habitat patches is larger than the species' average dispersal capacity. Ballooning dispersal in spiders can be considered as a passive dispersal process, in which dispersed distances depend on the prevalent wind velocity. We executed a reaction norm analysis to analyze how dispersal propensity of the salt marsh wolf spider Pardosa purbeckensis depended on population characteristics (patch size) and the environment (wind velocity). Dispersal propensity was affecte...
This interim technical report presented a summary of results obtained from Pit Lake models developed from different simulation models. The models were used to predict stratification in a hypothetical Pit Lake. Predictions were used to assess the hydrodynamic similarities and differences between the 2 models and to determine if the models would produce similar stratification profiles for the Pit Lakes to previous models. Results showed that the models produced similar results for both temperatures and salinities. The main difference between the RMA10 and CE-QUAL-W2 model used in a previous study was found to be run time. A sensitivity analysis of the RMA10 and CE-QUAL-W2 model predictions was completed to assess the effects of segmentation; time step; lake surface area; lake orientation; and model coefficients or parameters. Results showed that the selected time step and model segmentation were appropriate, as both led to modelling results that were stable. However, ...
We consider the case of a test sphere (ball) of radius a{sub 1} rotating at constant angular velocity {omega} in an otherwise quiescent unbounded suspension of uniformly sized spheres of radii a{sub 2} dispersed in a Newtonian fluid of viscosity {mu}. To the first order in the volume fraction c of suspended spheres it is shown that when the ball is small compared with the suspended spheres the suspension does not behave as regards the hydrodynamic torque L exerted on the ball like a homogeneous Newtonian fluid characterized by the usual Einstein viscosity coefficient {mu}{sub s}={mu}(1+5/2c). Explicitly, the torque on the rotating sphere does not obey Kirchoff{close_quote}s law, L=8{pi}{mu}{sub s}a{sub 1}{sup 3}{omega} for no slip. Rather, a modified form of Kirchoff{close_quote}s law is obtained in which the Einstein coefficient of 5/2 is multiplied by a coefficient which is less than unity in ...
The purpose of the present study was to prepare a novel domperidone hydrogel. The domperidone dispersion was prepared by the solvent evaporation method. The characteristics of domperidone dispersion...Full Text Available
Surface layers on lithium electrodes formed in several solvents including dimethyl carbonate (DMC), diethyl carbonate (DEC), polyethylene glycol 400 dimethyl ether (PEG400DME), and propylene carbonate (PC) have been studied by Raman spectroscopy. Both DMC and DEC were used singly, and also mixed with either methyl acetate or methyl formate. The Raman spectra showed that passive films formed on the Li surface in different solvents may have different chemical structures, which changed during the charging and discharging processes. A solid film of fullerene C6O, which could be used as a cathode in Li rechargeable batteries, was examined in the PEG400DME solution by both electrochemical and Raman spectroscopy. Cyclic voltammograms (CVs) showed five redox peaks which suggested the formation of C6O(-), C6O(2-), C6O(3-), ...
The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ? ?p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ? ?p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.
The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ??p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ??p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.
Pathogenic strains of Vibrio cholerae are lysogens of the filamentous phage CTXc6;, which carries the genes for cholera toxin (ctxAB). We found that the titers...Full Text Available
We previously reported that acetaminophen (APAP) caused apoptosis of C6 glioma cells. Therefore, we hypothesized that the level of p53, which usually stimulates apoptosis, might be increased...Full Text Available
Green leaf C6-volatiles are among the most important herbivore-induced plant volatiles (HIPVs). They play important roles in mediating the behavior of herbivores and their natural enemies, and in triggering...Full Text Available
A new method for the preconcentration and determination of trace amounts of lead at the {mu}g/L level in natural waters has been established based on the formation of the thenoyltrifluoroacetone (TTA) complex with dibenzo-18-crown-6 (DB18C6) by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry (AAS). The effect of various factors (synergism with TTA and DB18C6, shaking time, preconcentration factor, composition of the extracted species, and foreign ions etc.) on the extraction and back-extraction of lead has been investigated in detail. The lead-TTA chelate in o-dichlorobenzene forms a stable adduct with DB18C6 as Pb(TTA){sub 2} DB18C6. The stability constant ({beta}) of the adduct determined by curve fitting method was log {beta} = 4.2. The amount of lead in natural waters ...
Twenty-two cases of indigestion occurred in a 650-cow herd. Five cows had severe sand abomasal impaction, diagnosed by laparotomy. The pH of prepartum cows’ urine was c; 6.0 and of sand...Full Text Available
...of Mixing Sections 9 Interacting Rotor/Stator Mixers 10 Floating Ring Mixing Devices 11 Static (or Motionless) Mixers 12 Incorporation of Liquid Additives and Dispersions by Direct Addition 13 Dispersive Mixing of Fillers and Pigments 14 Dispersive Mixing Applied to Polymer Blending 15 Compounding with Single Screw Extruders Appendix - Preparation of Microtome Sections for Assessment of Dispersive In order to get a feel for this book, you can view Chapter 1 now, simply follow the link ...
The reaction of RbC_2_4 with C_6D_6 vapour was studied by neutron diffraction on a time scale of 5 min/spectrum. As for the reaction of KC_2_4, a second stage phase RbC_2_4(C_6D_6)sub(y) is initially formed and subsequently transformed into a first stage phase. Model calculations indicate that the benzene rings are canted against the graphite planes both in the first and in the second stage phase. (Auth.).
Analysis of steady-state and transient photoconductivity measurements at room temperature performed on c-axis oriented GaN nanowires yielded estimates of free carrier concentration, drift mobility, surface band bending, and surface capture coefficient for electrons. Samples grown (unintentionally n-type) by nitrogen-plasma-assisted molecular beam epitaxy primarily from two separate growth runs were examined. The results revealed carrier concentration in the range of (3-6)x10"1"6 cm"-"3 for one growth run, roughly 5x10"1"4-1x10"1"5 cm"-"3 for the second, and drift mobility in the range of 500-700 cm"2/(V s) for both. Nanowires were dispersed onto insulating substrates and contacted forming single-wire, two-terminal structures with typical electrode gaps of #approx =#3-5 #mu#m. When biased at 1 V bias and illuminated at 360 nm (3.6 mW/cm"2) the thinner (#approx =#100 nm diameter) nanowires with the higher background doping showed an abrupt ...
The radiation dose and the atmospheric dispersion for Pressurized Heavy Water Reactors (PHWR) are based on the CAN/CSA N288.2-M91 standards: for Pressurized Water Reactor (PWR) on the NRC Regulatory Guide 1.145. There are some differences between in the methodologies used in the standards, including the atmospheric dispersion model, the release height, the temperature lapse rate, the cutoff condition. This paper reports on a comparison of standards for atmospheric dispersion models of PHWRs and PWRs in order to determine which one is the more conservative. The comparison between PHWR and PWR for atmospheric dispersion factors and radiation doses confirms that there are no big differences
The U.S. Department of Energy (DOE) has been developing a nuclear waste disposal facility, the Waste Isolation Pilot Plant (WIPP), located approximately 42 km east of Carlsbad, New Mexico. The WIPP is designed to demonstrate the safe disposal of transuranic wastes produced by the defense nuclear-weapons program. Pefiormance assessment analyses (U.S. DOE, 1996) indicate that human intrusion by inadvertent and intermittent drilling for resources provide the only credible mechanisms for significant releases of radionuclides horn the disposal system. These releases may occur by five mechanisms: (1) cuttings, (2) cavings, (3) spallings, (4) direct brine releases, and (5) long- term brine releases. The first four mechanisms could result in immediate release of contaminant to the accessible environment. For the last mechanisq migration pathways through the permeable layers of rock above the Salado are important, and major emphasis is placed on the Culebra Member of the Rustler Formation ...
To heighten durability and safety of materials/parts for undersea oil drilling, the development of ceramic base materials was made by developing function harmony type process technology which harmonizes on a high grade contrary characteristics and various functions. The paper summed up the fiscal 1997 results. In the design of system formation, computational simulation technology was developed to the composite process and the diploid system. The development of multifunction simultaneous manifestation materials was trially made by the higher nano structure process. A study was made of control of microstructures of porous materials and matrix filling by the gas phase precipitation control. Proposed were selective control of grain growth from species crystals and the columnar particle orientation laminated structure of simultaneous manifestation of strength and toughness. By composite precipitation reaction control, studied were simultaneous dispersion of whisker and ...
The use of aqueous methyldiethanolamine (MDEA) for selective removal of hydrogen sulfide from acid gas streams has been studied in a 2 inch column packed with 1/4 inch ceramic Intalox saddles. The column was operated in a counter-current, steady state fashion. The feed gas composition varied between 1 and 5 mole % hydrogen sulfide and between 0 and 50 mole % carbon dioxide. In order to assist the development of packed column absorption models, the rate at which pure carbon dioxide absorbs into 2 M MDEA was measured as a function of pressure, liquid flow rate and packed bed length. The importance of end effects was carefully evaluated. In addition, draining and tracer methods were used to estimate the amount of static holdup present in the column. Using classical draining methods, as much as 50 % of the total holdup was found to be static. However, according to the step decrease in tracer method, less than 5 % of the total holdup was static. Since the step decrease in tracer method ...
Germination inhibition of the marine macrophyte Phyllospora comosa was utilized as a sub-lethal end-point to assess and compare the effects of four oil dispersants and dispersed diesel fuel and crude oil combinations. Inhibition of germination by the water-soluble fraction of diesel fuel increased following the addition of each of the dispersants; the nominal 48-h EC{sub 50} concentration of diesel fuel declined from 6800 to approximately 400 {mu}l 1{sup -1} nominal for each dispersed combination. This contrasted with crude oil, where the addition of two dispersants resulted in an enhanced germination rate and an increase in nominal EC{sub 50} concentrations from 130 {mu}l 1{sup -1} for the undispersed crude to 4000 and 2500 {mu}l 1{sup -1}. The results indicate that, while germination inhibition of P. comosa may be enhanced by the chemical dispersal of oil ...
... Title : Wear Rate and Friction Coefficient in Liquid Nitrogen and Hydrogen of Steel Sliding on Polymer Laminates (Various Fabrics and Polymers. ...
... Values of absorption maxima, X.nax, and associated molar extinction coefficients, c, as well as values of the n-octanol/water partition coefficient( ...
The diffusion coefficients (De) in bentonite were measured to understand and quantify the influence of groundwater chemistry such as ionic strength and to quantify the alteration of smectite mineralogical transformations. (author)
The first cohomology of the Virasoro algebra with coefficients in string fields are investigated. The relation between them and the Nambu-Goto action for a closed string is established. (orig.).
A new method for the separation and determination of trace amounts of cadmium and zinc in water as their thenoyltrifluoroacetone (TTA) complexes with dibenzo-18-crown-6 (DB18C6) in o-dichlorobenzene has been established by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry. The effect of various factors (synergism with TTA and DB18C6, shaking time, composition of the extracted species, and mutual separation etc.) on the extraction and back-extraction of cadmium and zinc has been in- vestigated. When the mixtures were extracted for 4 min at pH 4.9, only zinc was extracted quantitatively, whereas cadmium remained in the aqueous phase. After the phases were separated, cadmium was again extracted quantitatively at pH 7.5. Then, the two phases were each shaken with 0.05-0.1 mol/l HCl in order to back-extract cadmium and zinc from the organic phases; the ions were ...
The safety, pharmacokinetics, and distribution in tissue of an amphotericin B (AmB)-cholesteryl sulfate colloidal dispersion (ABCD) were compared with those of micellar amphotericin B-deoxycholate (m-AmB)....Full Text Available
Background and AimsSeed quality may be compromised if seeds are harvested before natural dispersal (shedding). It has been shown previously that slow or delayed drying can increase...Full Text Available
Species that depend on ephemeral habitat often evolve distinct dispersal strategies in which the propensity to disperse is closely integrated with a suite of morphological, behavioural and physiological...Full Text Available
The dispersion mechanism of highly loaded coal-water mixture (CWM) in the presence of a polyelectrolyte additive was investigated. Two important factors have been found: the ability of the additive to apply a sufficient electric repulsive force to the coal particles, and an appropriate affinity of the additive to the coal surface.
Pigment-dispersing factor (PDF) is a neuropeptide that plays a prominent role in the circadian clock of several insects. The cockroach Leucophaea maderae...Full Text Available
A pigment-dispersing hormone (PDH) from eyestalks of the fiddler crab Uca pugilator has been purified by gel filtration, ion-exchange chromatography, partition chromatography, and reversed-phase...Full Text Available
Gun barrel vibrations lead to dispersion in the shot patterns. Thus, reducing these vibrations should lead to increased accuracy. Since the muzzle is the anti-node for all vibration modes and its vibrations have the greatest effect on shot dispersion, it ...
A highly dispersed limonite catalyst was shown to have advantageous properties in a commercial liquefaction plant: it has high catalytic activity, low cost for catalyst production and abundant resources. 3 refs., 3 figs., 2 tabs.
The radial distribution function and the second virial coefficient of interacting bosons have been studied. The second virial coefficient has been deduced theoretically and is in good agreement with experimental values. The third virial coefficient has been calculated from the experimental values of the pressure. (Auth.).
A linear diffusion model serves as the basis for determination of an effective radon diffusion coefficient in concrete. The coefficient was needed to later allow quantitative prediction of radon accumulation within and behind concrete walls after application of an impervious radon barrier. A resolution of certain discrepancies noted in the literature in the use of an effective diffusion coefficient to model diffusion of a radioactive gas through a porous medium is suggested. An outline of factors expected to affect the concrete physical structure and the effective diffusion coefficient of radon through it is also presented. Finally, a field method for evaluating effective radon diffusion coefficients in concrete is proposed and results of measurements performed on a concrete foundation wall are compared with similar published values of gas diffusion coefficients ...
A Lagrangian atmospheric dispersion model(K-LADM) combining a three dimensional sea-land breeze model has been developed and applied to the estimation of the quaterly and the annual averaged air tritium concentration around Wolsung NPP site. The estimated concentrations were compared with the observed concentration data. The results showed that the present Lagrangian Atmospheric dispersion model(K-LADM) provided very good agreement with the observations.
Dispersants have been widely used as a primary response measure for marine oil spills around the world. Recently, the U.S. Environmental Protection Agency (EPA) developed an improved laboratory dispersant testing protocol, called the Baffled Flask Test (BFT). The BFT protocol w...
The diffusion coefficient of particles in radioactive gases has been calculated with account of random wandering of aerosols (occurrence of local fields affecting the particles; recoils accompanying radiation emitted by particles, etc.). To determine the diffusion coefficient, the method of Fokker-Planck equation derivation was used. A formula is presented for calculating the radiation-stimulated diffusion coefficient. A linear growth of the diffusion coefficient with radioactivity is noted according to the formula, the diffusion coefficient is mainly determined by the field in the radiation damage region. The aerosol radioactivity may result in a more rapid deposition of aerosols in the pipelines and aerosol purification systems. The diffusion rate grows not only in the presence of intrinsic radioactivity but in case of external radiation exposure as well.
Inorganic nanoparticles are indispensable for science and technology as materials, pigments and cosmetics products. Improving the dispersion stability of nanoparticles in various liquids is essential for those applications. In this review, we discuss why it is difficult to control the stability of nanoparticles in liquids. We also overview the role of surface interaction between nanoparticles in their dispersion and characterization, e.g. by colloid probe atomic force microscopy (CP-AFM). Two types of surface modification concepts, post-synthesis and in situ modification, were investigated in many previous studies. Here, we focus on post-synthesis modification using adsorption of various kinds of polymer dispersants and surfactants on the particle surface, as well as surface chemical reactions of silane coupling agents. We discuss CP-AFM as a technique to analyze the surface interaction between nanoparticles and the effect ...
Lateral plume dispersion in deep river valleys during neutral and stable lapse rate conditions can be exceptionally high due to the intense horizontal turbulence generated by prominent variations in the width, orientation and surface roughness of the valley walls. Use of the standard Gaussian dispersion equation to represent this enhanced lateral plume spread in a narrow valley may be inappropriate since consideration should also be given to the restriction of the horizontal plume spread due to impingement against the valley walls. The basic concept employed in the modification of the Gaussian dispersion equation was to assume that multiple eddy reflections occur between the valley walls in a manner similar to the vertical eddy reflections between the ground plane and an inversion layer aloft. The expressions are developed, but no attempt has been made to validate them with actual measured field data. 4 references, 3 ...
Seed dispersal involves several complex stages that can be affected by multiple peripheral processes. Thus, a major dispersal event can be followed by secondary dispersal, which can reduce density-dependent mortality and consolidate the dispersal phase. But predation events can also follow, and predation of seeds in feces is particularly interesting because it can heavily alter the fate of seeds dispersed through vertebrate guts. Our review of 20 cases involving this kind of interaction found that research has chiefly been in tropical and subtropical areas (85% of cases), suggesting that it is a minor phenomenon at higher latitudes. However, the small size of both the seeds and predators involved may have caused this process to go unnoticed outside the tropics. We tested the presence of pr...
A three dimensional sea-land breeze model and lagrangian particle dispersion model have been employed for the study on the mesoscale atmospheric dispersion of radioactive materials released from Wolsung NPPs. In this study, atmospheric dispersion simulations are carried out under two synoptic weather conditions: the geostrophic flow is a weak northerly wind (CASE 1) and a strong northerly wind (CASE 2) on a clear day in spring. The results show that atmospheric dispersion is affected by sea-land breeze and the recirculation of particles by the change of wind direction between sea breeze and land breeze plays an important role in atmospheric concentration distribution of radioactive materials.
Production of cermet nuclear fuel having fine uranium dioxide (UO{sub 2}) particles dispersed in matrix metal requires basic property data on the compatibility of matrix metal with fission product compounds. It is thermodynamically suggested that, as burnup increases, cesium in oxide fuel reacts with the fuel, other fission products or cladding pipe and produces cesium uranates, cesium molybdate, or cesium chromate in stainless steel cladding pipe. Attempt was made to measure the thermal expansion coefficient and thermal conductivity of cesium uranates (Cs{sub 2}UO{sub 4} and Cs{sub 2}U{sub 2}O{sub 7}), cesium molybdate (Cs{sub 2}MoO{sub 4}) and cesium chromate (Cs{sub 2}CrO{sub 4}). Thermal expansion was measured by X-ray diffraction and determined by Cohen`s method. Thermal conductivity was obtained by measuring thermal diffusion by laser flash method. The thermal expansion of Cs{sub 2}UO{sub 4} and Cs{sub 2}U{sub 2}O{sub 7} is as low as 1.2% ...
The release of {sup 222}Radon to the atmosphere is controlled by the rate of its gas transport through earthen materials. Of the many soil-related parameters, radon diffusion coefficient is the key parameter that characterizes this transport. We compared the radon diffusion coefficients measured at the laboratories for the UMTRA Project with simple empirical correlations developed by others. The empirical correlations predict the radon diffusion coefficient based on the fraction of moisture saturation and porosity. One of the more recent correlations agrees reasonably well with the measurements. In addition, by using a series of correlation curves, we studied the empirical relationships of the. radon diffusion coefficient with the saturated hydraulic conductivity, the fines content, and the moisture saturation in soil. The results reveal that a reliable determination of the long-term moisture and ...
Radon migration in porous, earthen materials is characterized by diffusion in both the air and water components of the system as well as by the interaction of the radon between the air and water. The size distribution and configuration of the pore spaces and their moisture distributions are key parameters in determining the radon diffusion coefficient for the bulk material. A mathematical model is developed and presented for calculating radon diffusion coefficients solely from the moisture content and pore size distribution of a soil, reducing the need for resorting to radon diffusion measurements. The resulting diffusion coefficients increase with the median pore diameter of the soil and decrease with increasing widths of the pore size distribution. The calculated diffusion coefficients are suitable for use in simple homogeneous-medium diffusion expressions for predicting radon transport and compare ...
By the example of CH2Cl2, CF2Cl2, CHF2Cl, C2F6, C2H6, SF6 and C6H12 we have investigated the isobaric thermal conductivity jump at crystal-liquid phase transition. It is shown that the reduction in the thermal conductivity at melting derives from the degree of orientational ordering of the crystals at pre-melting point.
Carbide reactions occurring in a precipitation-hardening gamma/gamma-prime Ni-Cr alloy during prolonged high-temperature aging are investigated experimentally. It is found that the decomposition of primary MC carbides, which is accompanied by the precipitation of M23C6 particles, may lead to void nucleation and growth. The effect of carbide transformations on the residual properties of the material at temperatures above the equicohesion temperature is observed at the late stages of aging only. 6 references.
The doping of deuterated polyparaphenylene [C_6D_4]sub(n) with AsF_5 has been investigated by real time neutron diffractometry at 100, 400 and 820 mbar AsF_5 pressure. The reaction appears to be diffusion controlled. Evidence for one doped phase with partial crystalline order was obtained. Structural considerations suggest two polymer chains plus one dopant ''string'' as the repetitive unit. (Auth.).
The factors determining temperature and current coefficients of lasing wavelength are investigated and discussed under monitoring CO2-gas absorption spectra. The diffusion rate of...Full Text Available
Available data are presented which support the supposition that metals and alloys with a negative low-temperature Hall coefficient are apparently not superconducting. (author).
Reliable values of x-ray and gamma-ray attenuation coefficients of elements and compounds are required in spectrometry as well as in many other scientific, engineering and medical disciplines involving photon radiation
An elliptic equation in a rectangle with coefficients depending on a fast variable and with its period being a small parameter is considered. An asymptotic expansion of the solution up to an arbitrary degree of the small parameter is constructed and substantiated by applying the two-scale expansion method.
The problem of optimizing a horn radiator of electromagnetic waves for the reflection coefficient and the coefficient of transformation of the fundamental mode into higher order modes is solved. Optimization is performed by means of selecting a combined shape of the radiator generatrices.
The temperature coefficient has been investigated on the Wolsung nuclear power reactor, in which fuel is natural uranium dioxide and moderator heavy water. The numerical computations are carried out in terms of changes of the effective neutron multiplication factor with respect to fuel, moderator, and coolant temperatures. Those results are compared with the computed values of temperature coefficient based on the LATREP computer code. (author).
Solid state effects are taken into account in an internal conversion coefficients computation by using Wigner-Seitz boundary conditions. Both the bound and free electron wave functions are calculated from an atomic Dirac-Hartree-Fock-Slater self consistent potential. These internal conversion coefficients are compared with those obtained from the usual free atom boundary conditions.
Solid state effects are taken into account in an internal conversion coefficients computation by using Wigner-Seitz boundary conditions. Both the bound and free electron wave functions are calculated from an atomic Dirac-Hartree-Fock-Slater self consistent potential. These internal conversion coefficients are compared with those obtained from the usual free atom boundary conditions. (orig.).
The algebra of the coefficients in the minimal representation of the A_n_-_1 quantum group, discussed by Felder and Varchenko, is given. Those coefficients are associated with the Boltzmann weights of A_n_-_1"("1") interaction-round-a-face model. The authors show that the algebra satisfies the Yang-Baxter equation. The PBW base for this algebra is also given
The thermal accommodation coefficients of helium, neon, argon, hydrogen and deuterium have been measured in the temperature range of 77-340 K on the surface of a graphitized carbon filament. The dependence of the accommodation coefficient upon the molecular weight as well as the temperature of measurement, and the conversion from orthohydrogen to parahydrogen, have been discussed.
A variable-dispersion electron spectrometer is being installed for use by the Stanford Superconducting Accelerator in conjunction with its Free Electron Laser program. The system has been designed to operate with electron beam energies from 20 MeV to 200 MeV, with a maximum energy resolution of 0.01% FWHM. The maximum energy acceptance is approximately #+-# 5%, as determined by the bending magnet aperture. Resolution is controlled by adjusting the focal conditions at the entrance to a 90 degree bending magnet, while the dispersion is controlled by changing the magnitude and polarity of the field in a quadrupole magnet which immediately follows the bending magnet. 4 refs., 5 figs.
Sixty-seven unresolved objects with flat blue spectra that had no apparent features on the plates of the Case Low-Dispersion Northern Sky Survey have been observed at higher dispersion and to shorter wavelengths in order to determine their nature. The following classifications are proposed: 20 low-redshift QSOs (z greater than 1.7), two Seyfert 2 galaxies, 23 stars, and two variable objects. The spectra obtained for the remaining 20 objects were flat with no obvious features, but noisy, and these will need further observation. 5 references.
This paper presents the results of a series of experiments performed to study the effect of initial pressure vessel conditions on the extent of melt dispersal from scaled reactor cavities and describes progress in development of a mathematical model which is designed to predict the melt mass dispersed from reactor cavities as a function of reactor vessel initial conditions and on the vessel breach area. The model, which is being developed to also characterize the heat transfer and chemical reaction phenomena which would take place within the reactor cavity, is designed to be incorporated into a lumped-parameter containment analysis computer code.
It is demonstrated that highly dispersed molybdenum sulfide catalysts are prepared by using Mo(CO){sub 6} adsorbed on the support. The structure of ultradispersed molybdenum sulfide is suggested by EXAFS techniques to be different from that of MoS{sub 2}. The TOF of the thiophene HDS is almost invariant with the dispersion of molybdenum sulfide at a high molybdenum dispersion, whereas the TOF of the hydrogenation greatly increases with increasing dispersion. On the basis of the HDS activity and optimum Co/Mo ratio of Co-Mo/Al{sub 2}O{sub 3} catalysts having a variety of molybdenum dispersion fabricated by using carbonyl complexes, it is demonstrated that highly active HDS catalysts are prepared by highly dispersing molybdenum sulfide phases. Edge decorations of molybdenum sulfides by cobalt are suggested for the synergy generation between cobalt and molybdenum ...
Two quantities play a central role in that part of nonlinear optics which deals with the effects of a finite momentum spread in a particle beam: the orbit position whose derivative with respect to momentum is called 'orbit dispersion' and the betatron wave number whose derivative WRT momentum is the 'chromaticity'. The orbit dispersion varies with the azimuth and is essentially horizontal in a machine with a horizontal symmetry plane; parasitic radial fields induce a vertical component. The chromaticity is a scalar quantity related to the integral of the focusing strength, over one turn of the machine; it is defined for the horizontal and vertical planes. After recalling the general motion equation in the horizontal plane, the orbit dispersion and the chromaticity will be treated. Closed formulae are given for lumped elements and special emphasis is put on dipoles with a high deflection angle. (8 refs).
Abstract A one step method was used to prepare stable aqueous nanocomposite dispersions based on cellulose whiskers extracted from the rachis of the date palm tree and a poly(styrene co 2 ethyl hexylacrylate) copolymer via miniemulsion polymerization. A reactive silane, i.e., methacryloxypropyl triethoxysilane was added to stabilize the dispersion and favor the anchoring of the whiskers on polymer particles. Dynamic light scattering was used to study the effect of the silane and whiskers contents on the average particle size of the polymer. Nanocomposites materials were prepared from these dispersions using a casting/evaporation method. The effect of the silane and whiskers contents on the thermal and mechanical properties were studied using differential scanning calorimetry and dynamic me...
Behavioral responses to wind are thought to play a critical role in controlling the dispersal and population genetics of wild Drosophila species1,Full Text Available
The purpose of this study is to search for a new method of dispersing spilled heavy oil, which has a detrimental effect on the natural environment and marine ecosystem. A method ejecting a waterjet vertically downward to heavy oil on the water surface was studied, particularly focusing on the effect of the guide nozzle shape. The waterjet comprised heavy oil and minute air bubbles, and passed through the hole of the guide nozzle. Thirteen guide nozzle shapes were tested and compared. The dispersion efficiency of a tapered hole was the best among the 13 nozzles. The flow in the hole of the guide nozzles was recorded by a high-speed video camera. The occurrence of two flows, regular and counter flows, was observed in the taper guide nozzle. It seemed that the counter flows generated the shearing force between the waterjet and the heavy oil layer. It is considered that the shearing force determines the surplus efficiency of ...
Studies of collisions between Rydberg atoms with values of principal quantum number n in the range 100 approx-lt n approx-lt 400 and H_2S and C_6H_5NO_2 are reported. These targets were selected because they have very different dipole moments: 0.97 and 4.22 D, respectively. Analysis of the data using the essentially-free-electron model shows that at micro-electron-volt energies the cross sections for rotationally inelastic electron scattering by these targets have very different energy dependences. This difference suggests that, in the case of C_6H_5NO_2, dipole-supported states might be important in the scattering. To examine this further, the data are compared with the results of calculations using a free-electron cross section that assumes the presence of dipole-supported states, and it is demonstrated that, with a reasonable choice of parameters, it is possible to reproduce the experimental ...
It is shown that it is necessary to take into account locality of the analysis and to introduce additional corrections for partial capture of matrix and fluorescent subexcitation by matrix during quantitative X-ray spectral microanalysis of finely dispersed materials. Cast two-phase (#alpha#+#beta#) titanium alloy VT3-1 is chosen as an investigation object.
A mathematical model describing the behavior of a gas of any density released into a turbulent atmosphere was developed. A numerical treatment was established for two dimensional flow. An understanding of the effects of accidental or continuous release wa...
Results are reported from dye tests of the dispersion of the vapor plume from the natural draft cooling tower of a fossil-fuel power plant located in the coastal region of Maryland.
The biodegradation of one of the most commonly used commercially available dispersants in the treatment of hydrocarbon out-flow was studied. The culture mediums employed were sea water, sterile sea water, and medium M19 (Merck). The latter two were inoculated with two kinds of microorganisms of the Pseudomona genus isolated from sludge from a waste treatment plant. The dispersants used is a commercial product made of anionic sulphated dispersants (1.710% by weight); anionic sulphonated dispersants (0.144%) and non-ionic dispersants (8.146%), both accompained by hidrocarbonated solvent (90%). The degradation processes occurred at differents temperatures (20, 30 and 37). The greatest degradation was obtained at 30 degree centigree. The degradation percentages obtained with the miscroorganisms were 40% of the anionic total and 70% of the non-ionic total after 56 hours for the 5:2 ...
An energy dispersive x-ray fluorescence technique was used for the determination of Titanium (Ti) and Zirconium (Zr) in red mud by using a standard addition method. An annular {sup 241}Am source is employed for excitation of K shells of elements. 13 refs., 2 figs., 1 tab.
Extended conformal algebras with supersymmetry (super-W/sub n/ algebra) is constructed and the algebras are shown to exist for special values of the central charge c. The super-W/sub n/ algebra containing currents of spin (5/2, 3) has a unitary representation (c=10/7) and a non-unitary one (c=-5/2), and the super-W/sub n/ algebra containing currents of spins (2, 5/2) has a non-unitary representation (c=-6/5).
Mass spectrometry was instrumental in the discovery of the fullerenes and the characterization of their special structure (truncated icosahedron). High resolution and high sensitivity mass spectrometry in combination with a crossed molecular beam/electron beam ion source is used here to study a further, very unique property of singly and multiply charged fullerene ions (up to Z=7), i.e. their strong resilience towards decomposition via sequential C_2 evaporation and via Coulomb explosion, respectively. (author).
The interaction of free electrons in the energy range from 0 to 10 eV with molecules at different stages of aggregation is investigated. The mechanism in the gas phase under single collision conditions is described. Fullerenes C_6_0 and C_7_0 are used as targets. Electron impact on condensed molecules can lead to temporary negative ions. The formation of Cl"- from gas phase CCl_4 and the desorption of Cl"- from 6 monolayer CCl_4 film on an Au substrate is determined experimentally. (Suda).
Three dispersants (stearic acid, oleic acid, and poly-(12-hydroxystearic acid)) are compared for their ability to produce low-viscosity suspensions of zirconia in kerosene. Rheological measurements and sediment packing density measurements show that poly(12-hydroxystearic acid) is a better dispersant than stearic acid or oleic acid; this is explained in terms of the longer tail of the poly-(12-hydroxystearic acid) surfactant molecule. The amount of dispersant can be optimized to reduce viscosity and yield point of the suspension, and to eliminate thixotropic hysteresis. The use of a dispersion medium of lower viscosity than the dispersant makes it easy to detect when complete monolayer coverage has been achieved. The loss of pseudoplasticity, brought about by a higher degree of deflocculation, can be recovered by increasing the volume fraction of solids of a suspension and this is ...
We discuss the prospects for bounding and perhaps even measuring quantum gravity effects on the dispersion of light using the highest-energy photons produced in gamma-ray bursts (GRBs) measured by the Fermi telescope. These prospects are brighter than might have been expected, as in the first ten months of operation, Fermi has so far reported eight events with photons over 100 MeV seen by its Large Area Telescope. We review features of these events which may bear on Planck-scale phenomenology, and we discuss the possible implications for alternative scenarios for in-vacua dispersion coming from breaking or deforming of Poincare invariance. Among these are semiconservative bounds (which rely on some relatively weak assumptions about the sources) on subluminal and superluminal in-vacuo dispersion. We also propose that it may be possible to look for the arrival of still higher-energy photons and neutrinos from GRBs with ...
Finite-difference acoustic-wave modeling and reverse-time depth migration based on the full wave equation are general approaches that can take into account arbitrary variations in velocity and density and can handle turning waves as well. However, conventional finite-difference methods for solving the acoustic- or elastic-wave equation suffer from numerical dispersion when too few samples per wavelength are used. The flux-corrected transport (FCT) algorithm, adapted from hydrodynamics, reduces the numerical dispersion in finite-difference wavefield continuation. The flux-correction procedure endeavors to incorporate diffusion into the wavefield continuation process only where needed to suppress the numerical dispersion. Incorporating the flux-correction procedure in conventional finite-difference modeling or reverse-time migration can provide finite-difference solutions with no numerical dispersion even ...
We used the tissue distribution of ({sup 14}C)butanol to quantitate regional blood flow in the spinal cord (RSCBF) of pentobarbital-anesthetized, normothermic rats in which segmental local cooling pentobarbital-anesthetized, normothermic rats in which segmental local cooling of the spinal cord (to 25-28{degrees}C) at vertebral levels C4-C6 (n = 6) or T13-L1 (n = 6) was induced. Thirty minutes later, blood flow measurements were made at seven levels of the spinal cord and in the sciatic nerve trunks and biceps femoris muscles. Sham-cooled rats served as controls (n = 12). In control rats, RSCBF varied between 41.5 +/- 2.4 and 65.1 +/- 3.2 ml.min-1.100 g-1. Local cooling of the C4-C6 cord segment reduced RSCBF by 32%, from 65.1 +/- 3.2 to 44.4 +/- 3.5 ml.min-1.100 g-1 (P less than 0.01). Tissue vascular resistance (R) in the cooled C4-C6 segment was elevated ...
A new generation of transmit-receive single-pass probes, denoted as C6 or X probe, was field tested during the Gentilly II, 2000 steam generator tube inspection. This probe has a performance equivalent to rotating probes and can be used for tubesheet and full-length inspection at an inspection speed equivalent to that of bobbin probes. Existing C3 transmit-receive probes have been demonstrated to be effective in detecting circumferential cracks. The C5 probe can detect both circumferential and axial cracks and volumetric defects but cannot discriminate between them. The C6 probe expands on the capabilities of both probes in a single probe head. It can simultaneously detect and discriminate between circumferential and axial cracks to satisfy different plugging criteria. It has excellent coverage, good defect detectability, and improved sizing and characterization. Probe data is displayed in C-scan format ...
Fully fluorinated compounds (perfluoro compounds) represent a class of chemicals which include many extremely inert species-inert to both chemical reaction and photodissociation. Well known examples include SF6 and the perfluorocarbons (PFCs) CF_4 and Teflon. SF_6 is used industrially in electrical switch gear and as an atmospheric tracer. CF_4 and C_2F_6 are released into the atmosphere as a by-product of aluminum manufacture. Several perfluoro compounds have been proposed as substitutes for the ozone-destroying Freons and halons; proposed substitutes include SF_6, c-C_4F_8, C_5F_1_2, and C_6F_1_4. These chemicals were chosen in part because they do not harm the stratospheric ozone layer and were therefore considered environmentally friendly. Recently, Ravishankara et al. reported that perfluoro compounds have significant global warming potential (GWP), contributing to the greenhouse effect due to strong infrared absorption. The perfluoro ...
The following paper is focused on the numerical modelling of the transient radon diffusion through radon-proof membranes during the measurement of their radon diffusion coefficient. The major aim of such numerical modelling is to increase the accuracy of radon diffusion coefficients derived from the measured data sets. The developed complex ''transient'' numerical model is able to calculate the radon diffusion coefficient with sufficient accuracy from almost any data set - even from a short-time measurement with a non-linear course of results. This numerical model can also be used for various analyses of transient radon transfer processes (e.g. for the calculation of radon distribution curves within the membrane). The following paper presents governing equations for the simulation model, together with a brief description of algorithms incorporated in the newly developed software package, ...
A thermodynamic model for predicting the distribution coefficients has been developed by taking into account the extraction mechanism and the chloride complexation when Sm, Eu, Gd, Tb, Dy and Ho for single component systems are extracted from acidic chloride solutions by di-2-ethylhexyl ester in kerosene, respectively. The model equation includes two constants, of which one corresponds to the apparent extraction equilibrium constant and the other is due to the variation of the activity coefficients of organic species. These values are determined from a few experimental data by the curve fitting method. Then, the distribution coefficients under untried calculations, Bromley's formulation is used to estimate the activity coefficients of aqueous species and the interaction parameters for some rare earth chlorides are reported in terms of morality and molarity using data from Spedding et al. According to ...
Most wind farms consist of horizontal axis wind turbines (HAWTs) due to the high power coefficient (mechanical power output divided by the power of the free-stream air through the turbine cross-sectional area) of an isolated turbine. However when in close proximity to neighboring turbines, HAWTs suffer from a reduced power coefficient. In contrast, previous research on vertical axis wind turbines (VAWTs) suggests that closely spaced VAWTs may experience only small decreases (or even increases) in an individual turbine's power coefficient when placed in close proximity to neighbors, thus yielding much higher power outputs for a given area of land. A potential flow model of inter-VAWT interactions is developed to investigate the effect of changes in VAWT spatial arrangement on the array performance coefficient, which compares the expected average power coefficient of turbines in an ...
Radon emanation coefficients of 0.02 to 0.55 were measured at moisture contents ranging from dry to saturation in 18 different ores. The emanation coefficients rose from a minimum when dry to a plateau usually starting at 5 to 20 percent of saturation. A model, using measured pore-size distributions, suggested that the radium mineralization may be confined to annular layers about 0.02 micrometers thick around pores. Radon's diffusion coefficient was determined as a function of moisture. The techniques involved comparing a disk's exhalation as a function of time whether or not the disk had a distributed source. The model was free of approximations and included the effects of porosity and adsorption. An increase of diffusion coefficient with moisture for one or two ores was explained in terms of a model's equation for the diffusion coefficient in terms of ...
Transverse glow discharges in supersonic air and methane flows are studied both experimentally and theoretically. The experiments show that a diffuse volume discharge filling the whole cross section of the flow can easily be initiated in air, whereas a diffuse discharge in a methane flow shows a tendency to transition into a constricted mode. The electron transport coefficients (mobility and drift velocity) and the kinetic coefficients (such as collisional excitation rates of the vibrational levels of a methane molecule, as well as dissociation and ionization rates) are calculated by numerically solving the Boltzmann equation for the electron energy distribution function. The calculated coefficients are used to estimate the parameters of the plasma and the electric field in the positive co...
In order to increase the sensitivity of photometric determination of tungsten and to find forms with high molar extinction coefficients, mixed-ligand complexes of tungsten with antipyrine and trihydroxyfluorone have been studied. The molar extinction coefficients have been determined for chloride associates of mixed-ligand complexes containing different trioxyfluorones: phenylfluorone, salicylflourone, p-bromphenylfluorone, anthrafluorone, dioxyfluorescein, and dioxyfluoroscein ethylate (DOFE). An associate formed by DOFE has the maximum molar extinction coefficient. It has been used for photometric determination of microgram amounts of tungsten impurity in vanadyl sulphate.
This paper focuses on the design and modeling of the humidification dehumidification desalination (HDH) process. The process is only found on experimental or very small pilot scale. Literature studies are rather limited and it includes a number of experimental investigations, performance evaluation, and measurements of the heat and mass transfer coefficients. This study includes useful and new data on the evaluation of the heat transfer coefficient of the humid air stream in the condenser unit. The analysis develops a correlation for the heat transfer coefficient for the humid air stream as a function of the Reynolds and Prandtl numbers. Also, detailed evaluation of the system performance is presented as a function of the system temperatures and the inlet relative humidity of the air strea...
The present paper dealt with the extension of tendon friction coefficient correlation as a function of loading end load and circumferential angle, proposed in the former paper. The extended correlation further included the effects of the number of strands contacted with sheath, tendon diameter, politicization of tendon and tendon local curvature. The validity of the correlation was confirmed by several published measured data. The structural analysis of middle cylinder part of 1/4 PCCV (Prestressed Concrete Containment Vessel) model was conducted using the present friction coefficient correlation. The results were compared with the analysis using constant friction coefficient, focused on the tendon tension force distribution. (author)
Hitherto in this laboratory, ionization coefficients alpha and attachment coefficients #eta# have been determined from Townsend's discharge experiments by a curve-fitting method. However, the method proved to be laborious, Formulae have been derived in this paper to give value of alpha and #eta# as a function of Isubo, Isub1 and Isub2 where Isubo is the photoelectric current at a gap setting d and Isub2 the current at another gap setting 2 d. The values of alpha and #eta# obtained give currents in agreement to within 3% in the best cases with the observed currents.
Precious metal (PM) dispersions on CeO{sub 2}-containing supports were examined. When dispersions were evaluated by the H{sub 2}-O{sub 2} titration method, the CeO{sub 2}-containing supports hide the true redox of PM because of the large oxygen storage-reduction capacity of the oxide, resulting in higher apparent dispersions than the exact values. When Pt dispersions on the CeO{sub 2} support were evaluated by the ordinary CO pulse method, CO was adsorbed on the CeO{sub 2} support as carbonate species accompanying the oxidation with lattice oxygen. Therefore, the dispersions estimated from the CO uptake were also higher than the exact value. Infrared spectra also clearly evidenced the presence of carbonate species after CO adsorption. To prevent the CO adsorption on CeO{sub 2} as the carbonate species, we treated Pt/CeO{sub 2} with CO{sub 2} before CO adsorption. The strong bands ...
The most important commercialized methods of attenuation correction in SPECT are based on attenuation coefficient map from a transmission imaging method. The transmission imaging system can be the linear source of radioelement or a X-ray CT system. The image of transmission imaging system is not useful unless to replacement of the attenuation coefficient or CT number with the attenuation coefficient in SPECT energy. In this paper we essay to evaluate the validity and estimate the error of the most used method of this transformation. The final result shows that the methods which use a linear or multi-linear curve accept a error in their estimation. The value of mA is not important but the patient thickness is very important and it can introduce a error more than 10 percent in the final result.
This paper first introduces the calculating method of radium specific activity to determine the radon emanation rate of tailing of uranium mine No. 794, the method needs two parameters: radon emanation coefficient and radon diffusion coefficient. According to the measured results of parameters and the contrast between radium specific activity of indoor chemical analysis of field sample and field gamma-ray spectra, the authors discuss the variation rules and characteristics of radon emanation coefficient and radon diffusion coefficient, and the best climate and seasons for measuring these parameters in northern China, and finally summarize the characteristics of this method through analyzing measured results. (authors)
Reactive Magnetron Sputtering is a complex process and huge efforts are made addressing the understanding of its fundamental phenomena and the simulation of the deposition process by e.g. Particle in Cell/Monte Carlo (PIC/MC). One of the most uncertain parameters in this reactive sputtering process is the incorporation coefficient of the reactive gas in the growing layer, i.e. the real-time sticking coefficient during deposition. In this work, mass spectrometry is used to deliver more insights on this complex matter. Earlier, a method was developed to determine the incorporation coefficient of the reactive gas molecules in the growing metal film, using mass spectrometry combined with thin film analysis techniques (electron probe microanalysis and x-ray photoelectron spectroscopy). This method delivers a global, realistic incorporation coefficient which can be used in models for the reactive sputtering ...
The hydraulic characteristics of flow control multiorifice plate assemblies designed for the FFTF reactor were investigated. The pressure drop flowrate characteristics determined in the test are presented. (JWR)
In terms of the reduced potential energy barrier ? = ?uTS/kT, the rate coefficients for chemical reactions are usually expressed as proportional to e-?. The coupling between vibrational modes of the medium to the reaction coordinate leads to a proportionality of the regularized gamma function of Euler Q(a,?) = ?(a,?)/?(a), with a being the number of modes coupled to the reaction coordinate. In this work, the experimental rate coefficients at various temperatures for several chemical reactions were fitted to the theoretical expression in terms of Q(a,?) to determine the extent of its validity and generality. The new expression affords lower deviations from the experimental points in 29 cases out of 38 and it accounts for the curvature in the logarithmic plots of rate coefficients versus inverse temperature. In the absence of tunneling, conventional theories predict the curvature of these plots to be identically zero.
coupled heat/mass transfer Stefan problem. Taking the diffusion coefficient of Bi as a free parameter, the best fit was observed for the published value, ...
This paper proposes an adaptive morphological dilation image coding with context weights prediction. The new dilation method is not to use fixed models, but to decide whether a coefficient needs to be dilated or not according to the coefficient's predicted significance degree. It includes two key dilation technologies: 1) controlling dilation process with context weights to reduce the output of insignificant coefficients, and 2) using variable-length group test coding with context weights to adjust the coding order and cost as few bits as possible to present the events with large probability. Moreover, we also propose a novel context weight strategy to predict coefficient's significance degree more accurately, which serves for two dilation technologies. Experimental results show that our proposed method outperforms the state of the art image coding algorithms available today.
We prove a generalization of the Verlinde formula to fermionic rational conformal field theories. The fusion coefficients of the fermionic theory are equal to sums of fusion coefficients of its bosonic projection. In particular, fusion coefficients of the fermionic theory connecting two conjugate Ramond fields with the identity are either one or two. Therefore, one is forced to weaken the axioms of fusion algebras for fermionic theories. We show that in the special case of fermionic W(2, #delta#)-algebras these coefficients are given by the dimensions of the irreducible representations of the horizontal subalgebra on the highest weight. As concrete examples we discuss fusion algebras of rational models of fermionic W(2, #delta#)-algebras including minimal models of the N = 1 super Virasoro algebra as well as N = 1 super W-algebras SW(3/2, #delta#). (orig.).
Even when a healthy individual is studied, his/her erythrocytes in capillaries continually change their shape in a synchronized erratic fashion. In this work, the problem of characterizing the cell...Full Text Available
Summary Analyses of event runoff coefficients provide essential insight on catchment response, particularly if a range of catchments and a range of events are compared by a single indicator. In this study we examine the effect of climate, geology, land use, flood types and initial soil moisture conditions on the distribution functions of the event runoff coefficients for a set of 14 mountainous catchments located in the eastern Italian Alps, ranging in size from 7.3 to 608.4km2. Runoff coefficients were computed from hourly precipitation, runoff data and estimates of snowmelt. A total of 535 events were analysed over the period 1989-2004. We classified each basin using a "permeability index" which was inferred from a geologic map and ranged from "low" to "high permeability". A continuous s...
... 5.9-585/T; thermal stability; solubility in liquid nitrogen, oxygen and Freons; molar extinction coefficients in the visible range and EPR spectrum. ...
Radon proof barriers are used for lowering of radon transport from the soil into the house and the determination of the radon diffusion coefficient is an important parameter to be determined in order to design the minimal thickness of the radon proof insulation. A method has been developed in our laboratory by using modified Lucas cells connected to a radon source and tightly closed onto the top by the tested membranes whose radon diffusion coefficients are being measured. Solving the time-dependent differential equation for radon diffusion in the membrane for well-defined experimental conditions the effective radon diffusion coefficient of the insulating material can be evaluated by comparing the radon concentration decrease in the cell for the first hours with the well-known radioactive decay. First results obtained in several preliminary tests carried out with a parafilm M barrier and two polyethylene membranes are shown ...
Mar 1, 2011 ... Molar extinction coefficients of hydrogen iodide in the Schumann region. Author: De More, W. B.; Raper, O. F.. Abstract: Molar extinction ...
A highly sensitive and stable tris(2,2prime-bipyridyl)ruthenium(II) (Ru(bpy)32+) electrogenerated chemiluminescence (ECL) sensor was developed based on carbon nanotube (CNT) dispersed in mesoporous composite films of sol-gel titania and perfluorosulfonated ionomer (Nafion). Single-wall (SWCNT) and multi-wall carbon nanotubes (MWCNT) can be easily dispersed in the titania-Nafion composite solution. The hydrophobic CNT in the titania-Nafion composite films coated on a glassy carbon electrode certainly increased the amount of Ru(bpy)32+ immobilized in the ECL sensor by adsorption of Ru(bpy)32+ onto CNT surface, the electrocatalytic activity towards the oxidation of hydrophobic analytes, and the electronic conductivity of the composite films. Therefore, the present ECL sensor based on the CNT-...
Abstract Incomplete dispersion of aggregates is a well known difficulty when analyzing soil texture of Andosols, particularly if no fresh soil material is available. To facilitate such investigations, several dispersion procedures were carried out on air dried samples rich in short range order minerals, originating from selected Andosol profiles (S Mexico). As a result, we propose an improved method based on a sequential chemical treatment with K oxalate, NH4 oxalate, and oxalic acid that reliably removes cementing agents and allows for a stable dispersion of soil particles after addition of Na pyrophosphate. This method was proved to be well reproducible and highly reliable for routine grain size determinations. The potential error caused by the inherent risk of dissolving primary mineral...
This process for the preparation of nonaqueous dispersions of water-soluble polymerisates concerns compounds obtained by polymerization of water-soluble unsaturated ethylenic monomers in an emulsion of water in oil. The product is then dewatered to a maximum residual water content of 5% by means of microwaves. The process is azeotropic. The polymer has a molecular weight between 100,000 and 50,000,000, preferably between one and 10 million. Before treating with microwaves, the mixture is concentrated by conventional means until it has a polymer concentration between 20 and 65%, preferably between 40 and 60%. The microwaves have a wavelength between 0.1 and 30 cm. These polymer dispersions can be used in drilling fluids and as additives in tertiary oil recovery. 4 claims.
Abstract Smoke is a mixture of toxic gases and suspended particulate matter of solids and liquids that evolves from a fire of flammable materials. This article presents real-time consequence modeling to track the concentration of individual species in smoke as well as its soot deposition. In the modeling process presented, the burning rate or vapor mass is fed into a combustion model in which the combustion of products has been identified and quantified along with the temperature of the fire. The output of the combustion model is the smoke that will be dispersed into the ambient. The fire geometry, which depends on the type of fire (e.g., pool or flare), is identified. A dispersion model with the capability of determining particulate deposition is then used for tracking the smoke plume. Th...
The versatile electrospinning technique was used to successfully align and disperse multiwalled carbon nanotubes (MWCNT) in nylon 6,6 matrix to obtain composite fibers. The morphology of the composite fibers and the dispersion of the CNTs within the fibers were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM), respectively. TEM analysis revealed that the CNTs were well-dispersed, separated and aligned along the fiber axis. The thermal and mechanical properties of the composite fibers were characterized as a function of weight fraction of the CNTs. Incorporation of the CNTs in the fibers resulted in an increase in glass-transition temperature (Tg) by 7degreeC, indicating that the addition of CNTs has restricted the mobility of the polymer chains a...
A wavelength division multiplexer/demultiplexer having optical path lengths between a fiber array and a Fourier transform lens, and between a dispersion grating and the lens equal to the focal length of the lens. The optical path lengths reduce losses due to angular acceptance mismatch in the multiplexer. Close orientation of the fiber array about the optical axis and the use of a holographic dispersion grating reduces other losses in the system. Multi-exposure holographic dispersion gratings enable the multiplexer/demultiplexer for extremely broad-band simultaneous transmission and reflection operation. Individual Bragg plane sets recorded in the grating are dedicated to and operate efficiently on discrete wavelength ranges.
The Bureau of Mines has investigated the hazards of military explosives dispersed as dust clouds in a 20-L test chamber. For purposes of personnel safety, the spark ignitability of the explosives in the form of unconfined dust layers was also studied. The 20-L data show that most of the explosives dusts were capable of sustaining explosions as dust clouds dispersed in air and some dusts were even capable of sustaining explosions when dispersed in nitrogen. The finest sizes of explosives dusts were less reactive than the larger sizes; this is opposite to the particle size effect observed previously for the pure fuel dusts. The data for the explosives dusts were compared to those for pure fuel dusts. 27 refs., 47 figs.
A stable chlorobenzene dispersion of conducting polyaniline (PANI) has been obtained by doping emeraldine base with dodecylbenzene sulfonic acid (DBSA) and studied by spectrophotometric measurements in the UV-vis-IR range. The electrical properties of PANI: DBSA films obtained from the above dispersion have been investigated under different temperature and relative humidity conditions. All-organic chemoresistive devices have been developed by spin-coating the PANI: DBSA dispersion on flexible substrates, and then by depositing electrodes on the top, from a carbon nanotube conducting ink. Sensing tests performed under exposition to calibrated amounts of ammonia reveal that these simple and inexpensive sensors are able to detect ammonia at room temperature in a reliable way, with a sensitivity linearly related to concentration in the range between 5 ppm and 70 ppm.
Abstract Dispersions of single-walled carbon nanotubes (SWNTs) in various surfactant solutions have been systematically evaluated as additives in MEEKC. The compounds examined were catechins, phenolic acids, and flavonoids. Compared with zwitterionic and neutral surfactants, the addition of anionic dispersion seemed to be better at separating the three types of analytes in microemulsion system. In order to achieve low operating currents, an in situ-synthesized surfactant system based on the combination of a long-chain alkyl acid with an organic base was used in MEEKC. The optimized buffer contained 0.5% (57-mM) ethyl acetate, 0.6% (30-mM) lauric acid, 4.0% (666-mM) propanol, 50-mM Tris solution, and 4.5-mg/L the dispersion of SWNTs. Under optimized conditions, the established method was ap...
Dispersed flow film boiling is the heat transfer regime that occurs at high void fractions in a heated channel. The way this transfer mode is modelled in the NRC computer codes (RELAP5 and TRAC) and the validity of the assumption and empirical correlations used is discussed. An extensive review of the theoretical and experimental work related with heat transfer to highly dispersed mixtures reveals the basic deficiencies of these models: the investigation refers mostly to the typical conditions of low rate bottom reflooding, since the simulation of this physical situation by the computer codes has often showed poor results. The alternative models that are available in the literature are reviewed, and their merits and limits are highlighted. The modification that could improve the physics of the models implemented in the codes are identified. (author) 13 figs., 123 refs.
The energy dispersive beamline X6A at the National Synchrotron Light Source employs a curved crystal monochromator (polychromator) which focuses a range ([similar to]1 keV) of x-ray energies into a narrow (100--120 [mu]m) line image. Although this beamline was constructed primarily for time-dependent EXAFS experiments, we have begun to explore the use of this instrument for energy dispersive diffraction experiments with different types of sample including macromolecular crystals. The tunability ([ital E]=6.5 to 21 keV) and flexibility ([Delta][ital E]=100--1000 eV) of the instrument makes the beamline ideal as a test bed for the application of polychromatic single-crystal diffraction techniques to different chemical or biological materials.
We investigate the chemical and observational implications of repetitive transient dense core formation in molecular clouds. We allow a transient density fluctuation to form and disperse over a period of 1 Myr, tracing its chemical evolution. We then allow the same gas immediately to undergo further such formation and dispersion cycles. The chemistry of the dense gas in subsequent cycles is similar to that of the first, and a limit cycle is reached quickly (2 - 3 cycles). Enhancement of hydrocarbon abundances during a specific period of evolution is the strongest indicator of previous dynamical history. The molecular content of the diffuse background gas in the molecular cloud is expected to be strongly enhanced by the core formation and dispersion process. Such enhancement may remain for as long as 0.5 Myr. The frequency of repetitive core formation should strongly determine the level of background molecular enhancement. ...
The concept of the 'white-light cavity' has recently generated considerable research interest in the context of gravitational wave detection. Cavity designs are proposed using negative (or anomalous) dispersion in an intracavity medium to make the cavity resonate over a large range of frequencies and still maintain a high cavity build-up. This paper presents the first experimental attempt and demonstration of white-light effect in a meter long ring cavity using an intracavity atomic medium. The medium's negative dispersion is caused by bi-frequency Raman gain in an atomic vapor cell. Although the white light condition was not perfectly achieved and improvements in experimental control are still desirable, significantly broad cavity response over bandwidth greater than 20 MHz has been observed. These devices will have potential applications in new generation laser interferometer gravitational wave detectors.
Industrial effects have long been significant factors in wage inequality. Previous research indicates that wage differentials across industries were increasing through the mid 1980s. Using more recent data, however, we find that the level of inter-industry wage dispersion declined by 36% from 1986 to 2002 despite the continued trend towards increasing inequality in the labor force. This decline in inter-industry wage dispersion is evident across gender and educational groups. Using multilevel growth curve models, our multivariate results indicate that the decline is only weakly related to industrial changes in education, occupation or even productivity despite the fact that the latter variable had been a critical factor in the prior period. Indicators of globalization and downsizing also d...
This paper describes the study of particles' dispersion in an isotropic turbulent flow. The particle's motion and the turbulent flow characteristics are calculated independently. While the particles' displacement is computed by the author's code, the flow is simulated with a commercial code : PowerFLOW. The particles and the flow are coupled through the relative velocity component of the aerodynamic force. When the simulated flow is turbulent, a turbulence regeneration model is used in order to get the flow instantaneous velocity. Validation of the method is done by comparing the particles' dispersion obtained with experimental results from literature and with the results calculated by FLUENT. Good accordance is found between numerical studies and experimental results. However, comparison between results of PowerFLOW coupled to the author's code and results from FLUENT shows differences when the particle's path goes through the turbulent ...
Deep level effects in GaAs MOSFET have been characterised in the ohmic channel using DLTS, low frequency excess noise and dispersion technique. An isothermal multi exponential curve fitting method has been devised and implanted into the DLTS system. Multi exponential curve fitting method used to decompose a multi exponential transient into its constituents so that the peak signature can be better characterised for the case whereas several peaks are closely spaced. Low frequency excess noise and dispersion techniques also confirm the trap in signature of the same traps observed in the DLTS measurements. (author)
In the previous paper, we have derived a dispersion relation for the free electron laser (FEL) gain in the exponential regime taking account the diffraction and electron`s betatron oscillation. Here, we compare the growth rates obtained by solving the dispersion relation with those obtained by simulation calculation for the waterbag and the Gaussian models for the electron`s transverse phase space distribution. The agreement is found to be good except for the limiting case where the Rayleigh length is much longer than the gain length (1-D limit). We also generalize the analysis to the case where the electron beam cross section is elliptical as is usually the case in storage rings, and derive the first-order dispersion relation.
Papers are presented on the modeling, dispersion, formation, transformation, monitoring and biological effects of atmospheric pollution. Specific topics include a prognostic mesoscale model for pollutant transport and diffusion, commuter exposure modeling, a Gaussian plume model for an urban area, carbon monoxide dispersion in an urbanized area, wind-tunnel modeling of flue gas dispersion, the regional-scale transport of fine aerosol components in eastern North America, and a Markov process for the generation of hourly average wind vectors. Attention is also given to photochemical aerosol formation in multicomponent systems, heterogeneous nitrogen oxide-particulate reactions, the generation and measurement of primary soot aerosols of size between 50 and 400 A, inertial particle size classification techniques, the design of air quality monitoring networks, visibilities in polluted and unpolluted areas, and monitoring air ...
Villarrica (Chile) is one of the most active volcanoes in South America having erupted about 60 times in the last 460years. Although its historical eruptive activity has been mainly effusive and weakly explosive, it had strong explosive behaviour in postglacial times. Chaimilla (<3.1ka) is one of the best exposed and widely dispersed pyroclastic deposits, related to both fall and flow activity. The deposit is dispersed over an area of 250km^2 and consists of 8 units (A-H) which were grouped into four sequences. Stratigraphic data suggest that the eruption had a relatively short duration and evolved from i) an Opening phase, dispersing ash, lapilli clasts, accretionary lapilli, blocks and bombs, to ii) a Pulsatory phase, originating a series of magmatic explosions, to iii) a Collapsing phas...
Abstract in english We present a detailed derivation of the effective dielectric constant to be used in the dispersion relation for electrostatic waves in the case of a plasma immersed in a inhomogeneous magnetic field, with inhomogeneity perpendicular to the direction of the magnetic field.
Since membrane structures such as domes have been constructed in snowy regions, how to dispose snow on the roof has become a big problem. In the case of disposing snow on the roof by sliding off, it is required to know the distance and range of snow dispersion after the fall from the roof from the aspect of disaster prevention. This paper describes the experimental study on the effects of snow depth, sliding distance and angle on the distance and range of snow dispersion using an outdoor apparatus to slide the snow off which can adjust the conditions for sliding. As a result, the distance of snow dispersion was influenced not only by the sliding distance and angle but also the depth (as well as the weight) of the snow. When the snow was sliding on the membrane structure, it was neccesary to consider viscostic resisting force of water between the snow and the membrane in addition to kinetic friction force. After the fall ...
A stochastic-convective reactive (SCR) transport method is developed for one-dimensional steady transport in physically heterogeneous media with nonlinear degradation. The method is free of perturbation amplitude limitations and circumvents the difficulty of scale dependence of phenomenological parameters by avoiding volume-averaged specifications of diffusive/dispersive fluxes. The transport system is conceptualized as an ensemble of independent convective-reactive streamlines, each characterized by a randomized convective velocity (or travel time). Dispersive effects are treated as a component of the randomness in the streamline velocity ensemble, so no explicit expression for hydrodynamic dispersive flux is written in the streamline transport equation. The expected value of the transport over the stream tube ensemble is obtained as an average of solutions to the reactive convection equation according to the stream tube ...
... Zeitschrift fur SaugetierkundeOnline publication date: 16-Sep-2010.DANIEL J. THOMPSON, DOROTHY M. FECSKE, JONATHAN A. JENKS, and ANGELA ... Hillscougarlong-distance dispersalmountain lionOklahomaPuma conc...
The analysis of individual molecules is evolving into an important tool for biological research, and presents conceptually new ways of approaching experimental design strategies. However, more...Full Text Available
Elemental composition and distribution of the mineral reserves in the endosperm and embryo tissues of Ricinus communis cultivars Hale and Zanzibarensis were investigated. Energy dispersive...Full Text Available
ObjectivesIn old age, there are marked changes in both the structure of the liver sinusoidal endothelial cell and liver perfusion. The objective of this study was...Full Text Available
The SCILS program investigates and demonstrates concepts of operation for dispersed theater forces C3. The dispersal concept would increase the number of potential targets for nuclear strike, make these targets smaller, more highly mobile and harder to find, and introduce functional redundancy. The SCILS system is a microcomputer-based approach to preserving and enhancing the effectiveness of C3 operation in a dispersed configuration. In this program, the system was implemented for testing for the 9th Infantry Division in coordination with the Army's Distributed Command and Control System. Technical highlights of the system include a distributed, replicated data base, a video map/graphics-oriented Commander's Decision Display System, a packet switched Multi-Media Network that operates with deployed field communication systems, and a Voice/Data Conferencing System that supports remote coordination/briefing ...
The Sunshine Project of Japan was inaugurated in 1974. Since 1980 it has been promoting priority projects such as coal liquefaction. Japan is now promoting the basic and applied research that underpins this development and is increasing the efficiency of technical development. With regard to risk dispersion, the expansion of international cooperation such as the IEA is being promoted.
The thermal conductivity of steam has been measured as a function of temperature from 100 deg C to 515 deg C and pressure up to 500 bar using the coaxial cylinder method. Corrections to the apparent thermal conductivity data are detailed. Correlations of the thermal conductivity coefficients are given in terms of temperature and density.
The method and results are presented of measurements of the coefficients of "2"2"2Rn emanation from samples of fly- ashes and slag and other commonly used building materials. A chamber was used for electrostatic collection of "2"2"2Rn decay products. The coefficients of emanation ranged from 0.2% (fly- ashes) to 21.3% (phosphogipsum from phosphorit). (author).
In this work, the thermal performance of a conventional collector is improved by inserting porous substrates at the inner walls of the collector tubes. The porous substrates improve the convective heat transfer coefficient between the tube wall and the fluid. This improvement is investigated numerically and its effects on the efficiency and the useful gain of the collector are evaluated. It is found that inserting the porous substrate may raise the collector efficiency considerably, especially at high values of the overall heat loss coefficient.
This report contains a set of nomographs which can be used to estimate the average annual solar fraction for solar space and water heating at a large number of DOD facilities. The solar fraction estimated from the nomograph is in close agreement with F-Chart 3.0 and allows for variation of the following parameters: annual load, collector area, collector transmittance-absorptance coefficient, and collector overall loss coefficient.
A set of nomographs is presented which can be used to estimate the average annual solar fraction for solar space and water heating at a large number of DOD facilities. The solar fraction estimated from the nomograph is in close agreement with F-Chart 3.0 and allows for variation of the following parameters: annual load, collector area, collector transmittance-absorptance coefficient, and collector overall loss coefficient.
A set of nomographs is provided which can be used to estimate the average annual solar fraction for solar space and water heating at a large number of DOD facilities. The solar fraction estimated from the nomograph is in close agreement with F-Chart 3.0 and allows for variation of the following parameters: annual load, collector area, collector transmittance-absorption coefficient, and collector overall loss coefficient.
The change of the transport coefficient due to the fusion energy source is studied. The scale invariance property of the reduced set of equations is investigated in the presence of the self-heating term due to the fusion reaction. The pressure gradient as well as the fusion power are the free energy sources that dictate the turbulent transport. It is shown that the burning transport coefficient can have a form with much wider variety, and that the transport property could be different owing to the self-heating by the fusion reactions. (author)
Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)
General conclusions, principles and order of substantiating the extractable reserves and coefficients of oil extraction from oil and oil and gas fields are presented. Recommendations are made for solving questions of constructing calculation models for heterogeneous beds, schematization of the working conditions, selection of mathematical models for oil extraction for different geological-field conditions and different stages of ''life'' of the field.
Design constraints require that as Earth terminal attempting communications with a FLTSATCOM EHF Package (FEP) located onboard a FLTSATCOM satellite be provided with an accurate FEP package. To be precise, the terminal is provided with a coefficient element set from which the ephemeris of a satellite may be computed. This report describes the operation of a user friendly computer program that produces the above mentioned coefficient set so as to provide reference benchmarks from which the ephemeris related operations of the terminal can be judged.
Results of americium-242m and americium-242 preparation by irradiating initial americium-241 at a reactor in the form of a diphtalocyanine complex are presented. The enrichment coefficient, equalling 10, has been obtained using the extraction method of recoil atom separation from the parent isotope. Application of the chromatographic column with Dowex-50 permits to increase the enrichment coefficient of isotopes upto 24.6.
Annealing of magnetostrictive Metglas foils, subsequently incorporated into laminated Metglas/Pb(Zr, Ti)O3 magnetoelectric (ME) composites, is shown to result in improved magnetic properties, as well as ME coefficients. Annealing of the foils at 350 ?C resulted in partial crystallization, without oxidation or magnetic cluster formation that would reduce the magnetization. Laminate composites made with these annealed Metglas foils had improved ME coefficients.
The magnon dispersion curve of Gd metal has been determined from first principles by use of augmented-plane-wave energy bands and wave functions. The exchange matrix elements I (k,k') between the 4f electrons and the conduction electrons from the first six energy bands were calculated under the assumption of an unscreened Coulomb interaction. The results are in good overall agreement with experiment provided the I (k,k') are diminished by a constant scale factor of about 2 which may be caused by screening.
Methods of X-ray diffraction and transmission electron microscopy were used to study the microstructure of dispersion-strengthened Cu-Al2O3 nanocomposites obtained by the method of simultaneous deposition of Cu and Al2O3 from the vapor phase. The effect of the size of particles of the oxide (Al2O3) and of their content on the electrical resistance of the composite has been considered. The results obtained make it possible to suppose that the main structural factor that determines the electrical resistance of the composite are nanodispersed particles of Al2O3 with a size of less than 20 nm.
In symmetrical nuclear matter the solutions of pion dispersion equation are investigated in the complex plane of the pion frequency $\\omega$. There are three well-known branches of solutions on the physical sheet : sound, pion and isobar, at the matter density less than the critical one $\\rho <\\rho_c$. At the condition $\\omega^2_c\\leq0$ (in general case Re$ \\omega^2_c\\leq0$) takes place. This points out the instability of the ground state which is possibly related to the pion condensation.
The purpose of SEADEX was to acquire a comprehensive, high-quality data base for evaluating models of dispersion within coastal zones, it secondary objective was to provide data to help determine which meteorological measurements are most appropriate for emergency preparedness at nuclear power plant sites. The study was conducted in the vicinity of Kewannee, Wisconsin, on the western shore of Lake Michigan. This report describes the design of the study and the data base resulting from it. Both a gas tracer (SF/sub 6/) and a particulate tracer (oil fog) were used. (ACR)
A dispersion interferometer based on CO2 laser for measurements of plasma line density in the gas dynamic trap (GDT) experiment has been developed with sensitivity el>min ? 1.1013 cm-2, temporal resolution ?50 ns. The main advantages of the interferometer are compactness and low sensitivity to vibrations. The interferometer does not require specific vibration isolation structure and can be mounted directly on the working chamber of the plasma device. The above mentioned advantages have been successfully demonstrated in the Gas Dynamic Trap experiments.
This paper introduces the summary of design guideline (draft) for the limit state design method for foundation structures, and examples of calculations on pile foundations. The limit states were set using the load to transformation curves, and the limit state No. 3 in particular assumed a large earthquake, a state that a foundation is fatally damaged because of rarely acting loads that lead to generation of displacement and loss of stability and functions. Ground survey coefficient, ground resistance coefficient, and ground property coefficient were defined especially as the safety coefficients. With respect to the displacement in the limit state No. 3, a restriction value was set for the plasticity of the foundation. Loads were given considerations of combination of permanent load, variation load, and accidental load, each having been set with a load coefficient. It was decided ...
Conductivity and Hall effect measurements were made in dark and IR-photoexcited p-type ZnTe samples between 77 and 300 K. Acceptor vacancy complexes of activation energies 0.09-0.1 eV were found to be present in the photoexcited samples. Different possible scattering mobilities were considered for both samples to explain the observed hole mobility. In the photoexcited sample a scattering mobility due to vacancy complexes was suggested for the first time to explain the results. The scattering centres were associated with native vacancy complexes segregated at the dislocations sites. The expression for the complex scattering mobility has been deduced using the curve fitting method to be {mu}{sub C}=(6.6x10{sup -11})T{sup 5} e{sup 725/T}. (orig.).
We obtain conformal invariant topological field theories with N = 2 supersymmetry by twisting Sevrin, Troost and Van Proeyen's SU(2) x SU(2) x U(1) extended N = 4 superconformal field theories. We expect that the number of physical states is finite although the original N = 4 theories have continuous spectra. It is shown that the number of physical states is actually finite when the central charge c < 6 in the corresponding N = 4 theories. The physical states inherit the structure of the chiral ring in N = 2 superconformal minimal series which is obtained by the reduction from N = 4 theories. We also show that the algebra contains the topological N = 4 superconformal algebra as subalgebra. Therefore a closed set of a finite number of physical states in the topological N = 1 superconformal algebra can also be obtained. (orig.).
The effect of W and V on the high temperature strength properties of 12%Cr-15%Mn austenitic steels was studied from the view point of precipitation hardening and internal stress. The contribution of W addition to the tensile and creep-rupture strength was not so large. By contrast the combined addition of W and V increased the strength considerably. These are resulted from the precipitation of fine vanadium nitride (VN) within grains and the enhancement of M_2_3C_6 type carbide precipitation at grain boundaries. The V added material had large internal stress value which is considered to be due to dislocation movement disturbed by fine vanadium nitrides. (author).
An enantiocontrolled route to aziridinomitosenes had been developed from l-serine methyl ester hydrochloride. The tetracyclic target ring system was assembled by an internal azomethine ylide cycloaddition reaction based on silver ion-assisted intramolecular oxazole alkylation and cyanide-induced ylide generation via a labile oxazoline intermediate (62 to 66). Other key steps include reductive detritylation of 26, methylation of the N-H aziridine 56, oxidation of the sensitive cyclohexenedione 68 to quinone 70, and carbamoylation using Fmoc-NCO. Although the aziridinomitosene tetracycle is sensitive, a range of protecting group manipulations and redox chemistry can be performed if suitable precautions are taken. A study of DNA alkylation by the first C-6,C-7-unsubstituted aziridinomitosene 11a has been carried out, and evidence for DNA cross-link formation involving nucleophilic addition to the quinone subunit is described. PMID:14677970
The ORR operated at an average power level of 29.7 MW for 85.3% of the time during this period. The reactor was shut down on fifteen occasions, nine of which were unscheduled. Reactor downtime needed for refueling and checks was normal. The reactor remained available for operation 88.3% of the time. Special tests completed during the quarter included: (1) transfer of LEU fuel elements CLE-202 and NLE-201 from core positions B-9 and B-2 to core positions C-5 and C-6 for continued operation; and (2) calculation of maximum heat flux in LEU elements CLE-201 and NLE-202 in core positions A-2 and A-8. In-service inspections included inspections of ORR decay tank, primary heat exchanger No. 4, and the 24-in. strainer.
Intergranular corrosion (IGC) resistance of types 304LN and 316LN stainless steels (SS) thermally aged at 823, 873, and 923 K for various durations was assessed by ASTM A262 practice A test (electrolytic etch test) and electrochemical potentiodynamic reactivation (EPR) test. The results indicated that the type 316LN SS has significantly improved IGC resistance compared to 304LN SS. Based on the results of these tests, time-temperature-sensitization (TTS) diagrams were developed for both alloys. The secondary precipitates formed during thermal aging treatments were electrochemically extracted and analyzed by X-ray diffraction (XRD) to determine the types of precipitates formed during the aging treatments. The results indicated that the precipitates were mostly of M_2_3C_6 carbides.
Intergranular corrosion (IGC) resistance of types 304LN and 316LN stainless steels (SS) thermally aged at 823, 873, and 923 K for various durations was assessed by ASTM A262 practice A test (electrolytic etch test) and electrochemical potentiodynamic reactivation (EPR) test. The results indicated that the type 316LN SS has significantly improved IGC resistance compared to 304LN SS. Based on the results of these tests, time-temperature-sensitization (TTS) diagrams were developed for both alloys. The secondary precipitates formed during thermal aging treatments were electrochemically extracted and analyzed by X-ray diffraction (XRD) to determine the types of precipitates formed during the aging treatments. The results indicated that the precipitates were mostly of M_2_3C_6 carbides.
The published literature is reviewed and supplemented by current information from the author's laboratory, to show the influence of various compositional, heat treatment and thermomechanical factors on the structural characteristics of Alloy 800. The features discussed include carbon, aluminium, titanium and boron, solution treatment, ageing treatments with and without applied strain, and cold working. Examples of the aspects reviewed include the effect of heat treatment and service or testing temperature on the austenite grain size, and the relative importance of M_2_3C_6 and TiC, the influence of carbon level on gamma prime, the effect of residual or steady stress combined with time at temperature on changes in carbide or gamma prime morphology, and on the appearance of sigma or other intermetallic phases. The questions posed by these features are discussed generally, in terms of their effect on the mechanical properties at ambient and ...
SKB is currently performing site investigations at two potential sites for a final repository for spent nuclear fuel. This report presents results of water flow and solute transport modelling of the Forsmark site. The modelling reported in this document focused on the near-surface groundwater, i.e. groundwater in Quaternary deposits and shallow rock, and surface water systems, and was performed using the MIKE SHE tool. The most recent site data used in the modelling were delivered in the Forsmark 2.3 dataset, which had its 'data freeze' on March 31, 2007. The present modelling is performed in support of the final version of the Forsmark site description that is produced during the site investigation phase. In this work, the hydrological modelling system MIKE SHE has been used to describe near-surface groundwater flow and the contact between groundwater and surface water at the Forsmark site. The surface water system at Forsmark is described with the one-dimensional ...
A microcosm laboratory experiment was conducted to determine the impact of biological reworking by the ragworm Nereis diversicolor on the redistribution of particle-bound radionuclides deposited at the sediment-water interface. Over the course of the 40-day experiment, as much as 35% of a {sup 137}Cs-labelled particulate tracer deposited on the sediment surface was redistributed to depths of up to 11 cm by the polychaete. Three different reworking models were employed to model the profiles and quantify the biodiffusion and biotransport coefficients: a gallery-diffuser model, a continuous sub-surface egestion model and a biodiffusion model. Although the biodiffusion coefficients obtained for each model were quite similar, the continuous sub-surface egestion model provided the best fit to the data. The average biodiffusion coefficient, at 1.8 {+-} 0.9 cm{sup 2} y{sup -1}, is in good agreement with the values quoted by other ...
A microcosm laboratory experiment was conducted to determine the impact of biological reworking by the ragworm Nereis diversicolor on the redistribution of particle-bound radionuclides deposited at the sediment-water interface. Over the course of the 40-day experiment, as much as 35% of a "1"3"7Cs-labelled particulate tracer deposited on the sediment surface was redistributed to depths of up to 11 cm by the polychaete. Three different reworking models were employed to model the profiles and quantify the biodiffusion and biotransport coefficients: a gallery-diffuser model, a continuous sub-surface egestion model and a biodiffusion model. Although the biodiffusion coefficients obtained for each model were quite similar, the continuous sub-surface egestion model provided the best fit to the data. The average biodiffusion coefficient, at 1.8 #+-# 0.9 cm"2 y"-"1, is in good agreement with the values quoted by other workers on ...
The half-value thicknesses, linear and mass attenuation coefficients of biological samples such as bone, muscle, fat and water have been measured at 140, 364 and 662keV ?-ray energies by using the ATOMLABTM-930 medical spectrometer. The ?-rays were obtained from 99mTc, 131I and 137Cs ?-ray point sources. Also theoretical calculations have been performed in order to obtain the half-value thicknesses and, mass and linear attenuation coefficients at photon energies 0.001keV-20MeV for bone, muscle and water samples. The calculated value and the experimental results of this work and the other results in literature are found to be in good agreement.
A noninvasive method is described for estimating local cerebral blood flow (LCBF) and local partition coefficients by means of computed tomographic scanning during inhalation of 30% stable xenon gas in oxygen. Time-dependent xenon concentrations in arterial blood and brain tissue during the wash-in and washout phases are used to calculate partition coefficients and LCBF values by means of a least-squares curve-fitting analysis. Control values for partition coefficient and LCBF obtained from control subjects with minor head trauma in the chronic stage were compatible with those in several past reports, and reproducibility was satisfactory. The theoretic grounds underlying this new method of curve-fitting analysis are discussed.
A noninvasive method is described for estimating local cerebral blood flow (LCBF) and local partition coefficients by means of computed tomographic scanning during inhalation of 30% stable xenon gas in oxygen. Time-dependent xenon concentrations in arterial blood and brain tissue during the wash-in and washout phases are used to calculate partition coefficients and LCBF values by means of a least-squares curve-fitting analysis. Control values for partition coefficient and LCBF obtained from control subjects with minor head trauma in the chronic stage were compatible with those in several past reports, and reproducibility was satisfactory. The theoretic grounds underlying this new method of curve-fitting analysis are discussed.
Internal friction of amorphous Pd/sub 80/Si/sub 20/ metal doped with hydrogen or deuterium was measured with a specially designed apparatus using amorphous metal sheet as a part of the electric oscillating circuit. Two peaks in Q/sup -1/ curve are observed. Applying the peak shift method to the first Snoek-like peak, we can determine the relaxation time from which the microdiffusion coefficient can be calculated. The obtained microdiffusion coefficient is about 10/sup -14/ m/sup 2//s at 200 K, being comparable with the macrodiffusion coefficient obtained from the releasing method. It can, however, not elucidate the hydrogen isotopic effect on the peak temperature of Q/sup -1/ curve, the activation energy for relaxation and the relaxation time from the present work because of the broadness of obtained Q/sup -1/ curve.
An experimental and theoretical study of heat and mass transfer analogy and a comparison of that to a binary liquid mixture evaporation is presented. Common organic solvents, ethanol and n-heptane, were used to form an alcohol - hydrocarbon mixture. Studies were carried out in a horizontal rectangular channel having air flow velocities of 0.2 - 0.9 m/s. Heat transfer coefficients were measured with a copper plate resistor and mass transfer coefficients with a square pool. The heat and mass transfer analogy is presented for a system having two evaporating compounds with a fixed value of air flow and verified by measuring and comparing mass transfer coefficients for distilled water with air flow velocities of 0.2 - 0.9 m/s. An illustrative example of the use of the theory for industrial ventilation is presented. (author)
X-ray diffraction offers a unique combination of advantages for kinetic study which include the non-destructive nature of the measurement, the use of bulk crystals, and the convenience of the experimental arrangements. These attributes and the availability of position-sensitive detectors and high-flux synchrotron radiation sources make this technique most useful for in situ, dynamical investigations. When using diffraction techniques to determine a diffusion coefficient, the principle of analysis entails a scattering theory and a kinetic model. The former allows the kinetic parameter(s) to be extracted from measured intensity, while the latter relates the kinetic parameter(s) to the diffusion coefficient(s). Three examples are demonstrated: (1) Palladium Silicide (Pd{sub 2}Si) Layer Growth on Silicon, (2) Decomposition of an Ni-12.5at%Si Superalloy, and (3) Short-range Ordering in Cu-Au Solid Solutions.
The energy levels, wavelengths, oscillator strengths, Auger rates and level-to-level dielectronic recombination rate coefficients describing dielectronic recombination into excited levels of Ne-like titanium from F-like low-lying states are calculated. Our calculations are based on Dr. R.D. Cowan's semi-relativistic mass-velocity and Darwin corrections are included in the Hamiltonian, and the distorted-wave model is used for the calculation of free electron wavefunctions. In order to set the recombination rate coefficients on a level by level basis, in a manner compatible with detailed level population kinetics modelling of highly-stripped ions in plasma, the dielectronic recombination rate coefficients as a function of free electron temperatures are given in an analytical form, which is not only very convenient in practice, but also hopefully accurate compared with the exactly calculated numerical results. (orig.).
Dimensioning of actinides waste packages for long duration storage has to take into account helium production from natural decay and release rates from the material. For the latter, we propose here an improved method for the determination of the helium diffusion coefficient in britholite, to be used for minor actinides storage. This work is based on results we previously published using the classical three steps method: "3He implantation on a Van de Graaff facility, "3He profile determination analysing the protons resulting from the "3He(d,p)"4He reaction in a nuclear microprobe, evolution of the helium profile during annealings. Taking explicitly into account the incident deuterons energy stragglings allows us to show that the implanted helium profiles are bimodal, each component leading to a different helium diffusion coefficient.
#epsilon#_m(Ce"4"+) values of the ceric-cereus system have been measured and the experimental procedure is described. Both routine titration method and electrochemical measurement were used. Some interference factors, such as ultraviolet, acidity and temperature, were studied as well. The temperature coefficient of #epsilon#_m(Ce"4"+) value in this experiment is about -0.1% degree C"-"1. A statistic analysis was made for 24 experimental values of #epsilon#_m(Ce"4"+) and a Gaussian distribution was found. Ultimately, an average molar extinction coefficient of 553.2 +- 1.3 m"2#centre dot#mol"-"1 was obtained at #approx#320 nm in 0.4 mol/L H_2SO_4 system, with a relative standard deviation of 0.24% (95% confidence level) and a total uncertainty of 1.5%.
Fundamental phenomena of condensation heat transfer at a steam-water interface have been studied related to the thermo-hydrodynamics of the emergency core cooling system for light water reactors. In this study temperature fluctuations near the interface and in the liquid phase were measured using fine thermocouples for a saturated steam-subcooled water co-current stratified two-phase flow in a nearly horizontal rectangular channel, and heat transfer coefficients were determined experimentally. The values of the condensation heat transfer coefficients in this experiment are from 6 to 40 kW/m{sup 2}K. In the regions of high Reynolds numbers, as the steam Reynolds numbers become larger, the average interfacial heat transfer coefficients tend to increase. The corelations of Nusselt numbers were obtained from the heat transfer data. (author)
Fundamental phenomena of condensation heat transfer at a steam-water interface have been studied related to the thermo-hydrodynamics of the emergency core cooling system for light water reactors. In this study temperature fluctuations near the interface and in the liquid phase were measured using fine thermocouples for a saturated steam-subcooled water co-current stratified two-phase flow in a nearly horizontal rectangular channel, and heat transfer coefficients were determined experimentally. The values of the condensation heat transfer coefficients in this experiment are from 6 to 40 kW/m"2K. In the regions of high Reynolds numbers, as the steam Reynolds numbers become larger, the average interfacial heat transfer coefficients tend to increase. The corelations of Nusselt numbers were obtained from the heat transfer data. (author)
(Boiling site densities and heat-transfer coefficients have been measured for ethanol-water and ethanol-benzene mixtures at 1.01 bar for a heated vertical brass disk. A strong effect of composition on the boiling site density was observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The boiling heat-transfer coefficient was found to decrease with increasin subcooling, but for the mixtures at a given level of subcooling the decrease was less than that for the single components and azeotropic mixtures.) The heat-transfer coefficient at a given heat flux was seen to be quite insensitive to the very large increase in boiling site density in comparing the pure water and the ethanol-water azeotrope results, leading one to question pool boiling models that predict heat-transfer rates on the basis of boiling site density.
We report the synthesis of four diorganotin(IV) compounds of Schiff base pyruvic acid hydrazone derivatives formulated as [R2SnLY]2, where L1 is 2-SC4H3CON2C(CH3)CO2 with Y = CH3CH2CH2CH2OH, R = n-Bu (1); L2 is C6H5CON2C(CH3)CO2 with Y = CH3CH2OH, R = p-F-Bz (2); L3 is 2-HOC6H4CON2C(CH3)CO2 with YH2O, R = p-CN-Bz (3); and L4 is 4-NO2-C6H4CON2C(CH3)CO2 with YCH3CH2OH, R = Bz (4). The structures of all compounds have been established by a combination of single-crystal X-ray diffraction analysis, 1H and 119Sn NMR spectroscopy, IR spectroscopy, and elemental analysis. Studies reveal that four ligands present the same coordination mode with tin center, which all present tridentate ONO donor Schiff bases and coordinate to the tin center in an enolic form. In compounds 1-4, each tin atom is seven...
Half-Heusler phases XYZ (Pearson symbol cF12) are chemically versatile and rich in physical properties. The half-Heusler phase in the Fe-Zn-Sb ternary system was reported in the year 2000. In this work, two new ternary phases are identified in the vicinity of the equiatomic composition FeZnSb in the same system: Fe1-xZnSb (tetragonal, space group P4/nmm, Pearson symbol tP6-?, Z=2: a=4.1113(6) A, c=6.0127(12) A for x=0.08 (1), and a=4.1274(6) A, c=6.0068(12) A for x=0.12 (2)); and Fe7.87Zn6.72Sb8 (Fe0.98Zn0.84Sb) (3) (cubic, space group Fm-3m, Pearson symbol cF96-?, Z=4, a=11.690(13) A). 1 and 2 crystallize in the PbFCl-type structure, and 3 adopts a unique 2x2x2 supercell of a normal half-Heusler structure. The structures of both the tetragonal and cubic phases can be described as assemblies of half-Heusler structure related subunits. Electrical resistivity measurement on the pure sample of 2 shows it ...
"1"4C measurement uses a number of standards and reference materials with different properties. Historically the absolute calibration of "1"4C measurement was tied to 1890 wood, through the 'primary' standard of NBS-OxI (produced by the National Bureau of Standards, now NIST - National Institute of Standards and technology) subsequently replaced by NBS-OxII. These are both internationally calibrated and certified materials, whose "1"4C activities are known absolutely. A second tier of materials, often called secondary standards or reference materials, and including internationally recognised materials such as ANU-sucrose (now also IAEA-C6), Chinese - sucrose and the IAEA C1-C6 series, augmented by additional oxalic acid samples are also used routinely. The activity of these materials has been estimated from large numbers of measurements made by many laboratories. Recently, further natural materials from ...
The creep characteristics of alloy 800 at temperatures around 600"0C are greatly affected by the composition and treatments in the final stages of manufacture. Short-term and creep properties of alloy 800 at 600"0C are described for six melts covering the carbon range 0.054-0.078%, the titanium range 0.23-0.57% and the aluminium range 0.17-0.52%. The properties are related to the alloy chemistry and the microstructure. It is shown that homogeneously nucleated #gamma#'-precipitates are the main cause of low ductility in alloy 800 but there is also some influence of, for instance, grain boundary M_2_3C_6 films and discontinuous precipitation of Ni_3Ti or M_2_3C_6 in grain boundaries. The extent of #gamma#'-precipitation is controlled primarily by the (Ti+Al)-content. To avoid #gamma#' and ensure a high creep ductility the (Ti+Al)-content should be limited to 0.70-0.75% for alloy 800 with a carbon content ...
Thin films (1-10 ?m thickness) of nanocomposites (NC) based on organic coordinated compound (OCC) Eu(TTA)2(Ph3PO)2NO3 (where TTA is thenoyl trifluoroacetonate (C8H5F3O2S), Ph3PO - triphenylphosphine (C6H5PO) and polymer-polyvinylpyrrolidone ((C6H9NO)n) (PVP)) were obtained by chemical methods and with different molar ratios into organic polymer matrix. NC have been characterized by measurements of optical transmission, excitation spectra of photoluminescence (PL) and photoluminescence of NC at different concentrations of Eu(TTA)2(Ph3PO)2NO3 in NC. In the optical transmission of NC, the characteristic parameters of NC such as threshold absorbance, dependence on the concentration of the organic coordinated compound in NC, etc., have been determined The displacement of threshold absorption to infrared is observed with increasing of the concentration of the coordination material in NC. The excitation ...
A 3-D hydrodynamic dispersion model for tracer transport is developed and implemented into the TOUGH2 EOS3 (T2R3D) module. The model formulation incorporates a full dispersion tensor, based on a 3-D velocity field with a 3-D, irregular grid in a heterogeneous geological system. Two different weighting schemes are proposed for spatial average of 3-D velocity fields and concentration gradients to evaluate the mass flux by dispersion and diffusion of a tracer or a radionuclide. This new module of the TOUGH2 code is designed to simulate processes of tracer/radionuclide transport using an irregular, 3-D integral finite difference grid in non-isothermal, three-dimensional, multiphase, porous/fractured subsurface systems. The numerical method for this transport module is based on the integral finite difference scheme, as in the TOUGH2 code. The major assumptions of the tracer transport module are: (a) a tracer or a radionuclide is ...
The angular ..gamma gamma..-correlations for nuclei of Sr even-even isotopes with A=82, 84, 86, 88 were measured. Multipole structurs of ..gamma..-transtion series and th coefficients multipole mixing were determined.
The angular #gamma##gamma#-correlations for nuclei of Sr even-even isotopes with a=8 82, 84, 86, 88 were measured. Multipole structurs of #gamma#-transtion series and th coefficients multipole mixing were determined.
1. Rates and rate coefficients of glucose utilization and replacement were determined with [5-3H]- and [U-14C]-glucose in rats starved for 24h, either conscious or under halothane anaesthesia, in a...Full Text Available
We calculate the Bogolubov coefficients for a metric which describes the snapping of a cosmic string. If we insist on a matching condition for all times {\\it and} a particle interpretation, we find no particle creation.
Mass attenuation coefficients of amino acids viz. glycerine (C_2H_5NO_2), 1-Serine (C_3H_7NO_3), 1-Theronine (C_4H_9NO_3), 1-Proline (C_5H_9NO_2), 1-Valine (C_5H_1_1NO_2) and 1-Phenylalanine (C_9H_1_1NO_2) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by the gamma-ray transmission method in a narrow beam good geometry setup. Precisely measured densities of these solutions were used for the determination of these coefficients which varied systematically with the corresponding changes in the concentrations (g/cm"3) of the solutions. Molar extinction coefficients of amino acids were then obtained at these energies and were found to be in good agreement with the theoretical results. In addition, total interaction cross sections of amino acids in aqueous solutions were also calculated. (author)
The estimation of numerical values of the mean distance of closest approach of ions, a, of alkaline-earth metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.
Describes investigations into flow density, angle of repose, coefficients of friction and adhesion using poor quality anthracite culm (from the 50-letie Ukrainy mine) and anthracite slurry with a high ash content (from the Tsentral'naya and Partizanskaya mines) on samples of varying moisture content (2-22%). The results show that flow properties are impaired when anthracite has a moisture content of 8.5 to 9.5%; when these anthracites are used in electric power plants they should be stored in bunkers with walls with a slope of greater than 70 degrees (or dried) to prevent sticking. Results of investigations into internal and external friction, adhesion and cohesion varied for the different samples, but the highest coefficient of internal friction was found with concrete where it increases continuously with moisture content. With rubber, PVC, St. 3 steel and stainless steel, the friction coefficient increases with ...
The iron(III) molar extinction coefficient in H/sub 2/O-0.4 M H/sub 2/SO/ sub 4/ solution at maximum absorption and 25 deg C, epsilon /sub s/, was determined to be 2220 plus or minus 20 liters mole/sup -1/ cm/sup -1/. The ratio of the iron(III) molar extinction coefficient in D/sub 2/O-0.4 M H/sub 2/SO/ sub 4/ solution at maximum absorption and 25 deg C to epsilon /sub s/ was found to be 1.068 P 0.004. The acidity effect is presented graphically, since the effect is nonlinear. The temperature coefficients were determined to be +(0.63 plus or minus 0.02)% per de gree centigrade for light water solutions and +(0.36 plus or minus 0.02)% per degree centigrade for heavy water solutions. (auth)
... the hydroxyl group with the benzene ring. The molar extinction coefficients for the various species at their respective absorption ... Glya Recorded by 1H-NMR Spectroscopy TABLE 2 Molar Extinction Coeff...
An important application of metal hydrides is as a moderator material in nuclear reactors. The fundamental properties of hydrides are illustrated and an impression given of the current research into hydrogen in transition metals. Phase diagrams, magnetic properties, temperature dependence of the diffusion coefficient, energy level schemes and superconductivity are considered. (C.F.).
Gas-solid chromatography was used to determine the Henry`s law second gas-solid virial coefficients within the temperature range of 314--615 K for ethane, propane, butane, isobutane, pentane, hexane, heptane, chloromethane, dichloromethane, trichloromethane, tetrachloromethane, trichlorofluoromethane (Freon 11), chlorodifluoromethane (Freon 22), dichlorodifluoromethane (Freon 12), methyl ether, ethyl ether, and sulfur hexafluoride with Carbopack B, a microporous carbon adsorbent. The temperature dependence of the second gas-solid virial coefficients of these adsorbates was used in conjunction with analyses based on a graphical method, a single-surface numeric integration method, a single-surface analytic expression method, and a two-surface analytic expression method to determine the gas-solid interaction energies and other parameters. The interaction energies were correlated with a ratio of the critical temperature divided by the square root ...
1. Rates and rate coefficients of glucose utilization and replacement in post-absorptive rats, either conscious or under halothane anaesthesia, were determined in a thermoneutral environment by using...Full Text Available
Scraped-surface heat transfer augmentation is proposed as a possible technique for use in improved air-cooling designs. Although it has been in common use with liquids, the technique has apparently never been used with gases. An experimental investigation...
Measurements have been made of radon ("2"2"2Rn), release from diverse quaternary samples collected from different sediment deposits in the Errachidia and Beni-Mellal areas (Morocco). The radon diffusion coefficient as one of some important parameters of radon transport in the soil has been measured using solid state nuclear track detectors (SSNTD). Radon #alpha#-activity, uranium content and radon exhalation rate have been determined in the studied samples. Uranium concentrations were found to vary from 0.14 to 9.52 ppm whereas the radon exhalation rate varied from 0.003 to 0.145 Bq x m"-"2 x h"-"1. A positive correlation has been found between radon exhalation rate and uranium content in the studied samples. The average radon diffusion coefficients were found to vary from (1.26 #+-# 0.09) x 10"-"6 m"2 x s"-"1 to (4.3 #+-# 0.36) x 10"-"6 m"2 x s"-"1. Furthermore, the correlation between "2"2"2Rn diffusion coefficient and ...
Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 or MOX) were not clearly observed. In addition, it is likely that the restructuring effect of fuel pellet on the diffusion ...
A heat transfer (condenser) of a domestic freezer was tested in a vertical channel in order to study the influence of the chimney effect in the optimization of the heat transfer coefficient. The variation of the opening of the channel, position and the heating power of the heat exchanger in the heat transfer coefficient was considered. The influence of the surface emissivity on the heat transfer by thermal radiation was studied with the heat exchanger testes without paint and with black paint. The air velocity entering the channel was measured with a hot wire anemometer. In order to evaluate the chimney effect, the heat exchanger was testes in a open ambient. This situation simulates its operational conditions when installed on the freezer system. The variables collected in the experimental procedures was gathered in the form of dimensionless parameters as Nusselt, Rayleigh, Grashof and Prandtl numbers, and dimensional parameters of the ...
The authors extend the Fermilab formalism for heavy quarks to develop an {Omicron}(a{sup 2}) improved relativistic action. They discuss their construction of the action, including the identification of redundant operators and the calculation of the improvement coefficients.
Problems of classification and regression estimation in which objects are represented by multidimensional arrays of features are considered. Many practical statements can be reduced to such problems, for example, the popular approach to the description of images as a set of patches and a set of descriptors in each patch or the description of an object in the form of a set of distances from it to certain support objects selected based on a set of features. For solving problems concerning the objects thus described, a generalization of the relevance vector model is proposed. In this generalization, specific regularization coefficients are defined for each dimension of the multidimensional array of the object description; the resultant regularization coefficient for a given element in the mul...
Passage of neon gas through activated charcoal is planned to be the primary method of removing impurities from the liquid neon scintillator in the CLEAN experiment. In order to quantify this technique, the breakout curves for hydrogen, nitrogen, argon and krypton impurities in neon-saturated activated charcoal were measured. Adsorption coefficients and the number of theoretical stages were measured for hydrogen in the temperature range between 300 and 80 K, nitrogen between 300 and 200 K, and argon between 300 and 190 K. The adsorption coefficient for krypton was measured at 300 K.
A thermodynamic analysis of a hybrid geothermal heat pump system is carried out. Mass, energy, and exergy balances are applied to the system, which has a cooling tower as a heat rejection unit, and system performance is evaluated in terms of coefficient of performance and exergy efficiency. The heating coefficient of performance for the overall system is found to be 5.34, while the corresponding exergy efficiency is 63.4%. The effect of ambient temperature on the exergy destruction and exergy efficiency is investigated for the system components. The results indicate that the performance of hybrid geothermal heat pump systems is superior to air-source heat pumps.
Densities were measured with a vibrating-tube densimeter for binary mixtures of dimethyl sulfoxide + thiophene at temperatures from 293.15 to 313.15 K as a function of composition. Molar excess volumes V[sup E] for the mixtures, determined from the density data, are negative and become more negative with an increase in temperature. The coefficients of thermal expansion were also evaluated from the temperature dependence of the density.
Reflection coefficients of electromagnetic waves in a nonuniform plasma layer with electrons, positive ions and negative ions, covering a metal surface are investigated by using the finite-difference-time-domain method. It is shown that the reflection coefficients are influenced greatly by the density gradient on the layer edge, layer thickness and electron proportion, i.e., the effect of the negative ions. It is also found that low reflection or high attenuation can be reached by properly choosing high electron proportion, thick plasma layer, and smooth density gradient in the low frequency regime, but sharp density gradient in the high frequency regime. (authors)
Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition-rate measurements using molecular beam scattering and a very low-pressure cold-wall reactor. The RSCs have nonlinear Arrhenius temperature dependencies and decrease with increasing flux at low (710 /sup 0/C) temperatures. Several simple models are proposed to explain these observations. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction and low-pressure chemical vapor deposition-rate measurements.
A practical method to determine the ionic diffusion coefficient and activation energy by using quasielastic light scattering (QELS) is presented. It is shown that a temperature dependence curve of the QELS intensity at a fixed frequency can be well fitted by Jonscher's formula and that the diffusion parameters can be obtained from this curve fitting. This method is successfully applied not only to crystals with high optical quality, as reported earlier, but also to opaque ceramics, which are more important than the crystals from a practical point of view. The composition dependence of the ionic diffusion coefficient is studied in sintered YbSZ to show the usefulness of this method.
Experimental data on the gas holdup and the mean bubble size in a bubble column with a single nozzle was obtained for gas-molten salt systems of a eutectic mixture of LiCl (58 mol %)-KCl (42 mol %) and molten NaNO/sub 3/. The liquid-phase mass transfer coefficient K /SUB L/ was evaluated from the specific surface area a and the volumetric coefficient K /SUB L/ a data for oxygen and carbon dioxide absorption into molten NaNO/sub 3/. The dimensionless correlations of the performance of bubble columns for aqueous solutions can be extended to the gas-molten salt systems.
Developed is a simple method alloing one to determine the k-loop coefficient of #beta# function in gauge theories provided the operator expansion is constructed in (k-1) loop for certain two-point functions. The calculation of the two-loop coefficient of the Gell-Mann-Low function becomes trival - it reduces to a few algebraic operations with expressions which are already known. As an example spinor, scalar and supersymmetric electrodynamics are considered. Although the corresponding results for #beta#"("2") are known in the literature, both the method of the calculations and some points referring to the construction of the operator expansion are novel.
The mine dumps that arise from the gold mining operations in South Africa are a potential source of high concentrations of radon (222"Rn). Studying the diffusion of radon and the emanation from the soil will help to deduce the radon flux from these dumps to identify the problem areas for rehabilitation. This study describes measurements of the emanation coefficient and the modelling of the depth profile of the radon activity concentration, which is compared to a depth profile that was measured on such a mine dump. Emanation coefficients ranging from 0.13 to 0.39 have been obtained.
The entrainment flow rate distribution, the gas velocity profile, and the concentration profile of droplets across the channel cross section in fully developed region of a horizontal rectangular channel of 150mm width and 50mm height were measured. The concentration profile of droplets was expressed by a simple equation based on a constant diffusion coefficient model. From this equation the effects of gravity and turbulent diffusion of droplets on the concentration profile were evaluated. The characteristic mean settling velocity of a group of droplets with various diameters was derived, and using this value the mean diffusion coefficient of the group of droplets was obtained
The entrainment flow rate distribution, the gas velocity profile, and the concentration profile of droplets across the channel cross section in fully developed region of a horizontal rectangular channel of 150 mm width and 50 mm height were measured. The concentration profile of droplets was expressed by a simple equation based on a constant diffusion coefficient model. From this equation the effects of gravity and turbulent diffusion of droplets on the concentration profile were evaluated. The characteristic mean settling velocity of a group of droplets with various diameters was derived, and using this value the mean diffusion coefficient of the group of droplets was obtained. (author).
Microporous membranes are suitable for the CO{sub 2}-MEA (monoethanolamine) system because the overall mass transfer coefficient K of the membrane is approximately 10 times larger than that of composite membranes consisting of microporous membranes and homogeneous membranes. The overall volumetric mass transfer coefficient K{center_dot} of the hollow-fiber contact is more than 5 times larger than that of a conventional packed bed, which suggests that adorption using the present method has the advantage of making the absorption more compact. 8 refs., 7 figs., 4 tabs.
Experiments were conducted to study the condensation heat transfer characteristics of horizontal enhanced tubes. In the current experiment, six different enhanced tubes, including 26, 40 fpi low fin tubes and four three-dimensional-fin tubes, were tested. The working fluid used in the experiment was HCFC-22. Data were presented in the form of overall heat transfer coefficient at three working pressures, namely 1.32, 1.47 and 1.62 Mpa. In addition, the condensing heat transfer coefficients for the test tubes were obtained from the Wilson plot technique.
Retention kinetics and tissue partition coefficients for "8"5Kr were determined in rats exposed to known concentrations of "8"5Kr gas. The tissue partition coefficients were used to calculate the relative tissue radiation dose, assuming exposure conditions equivalent to the maximum permissible concentration in air (MPC)a. The estimated radiation dose was highest in adrenals and body fat, about twice the dose estimated for the next highest tissue, ovaries. Saturation and desaturation curves show that the contents of the large intestines have a prolonged desaturation time compared to other samples analyzed.
The dispersion of more than 20 vol pct submicrometer ceramic particles within a metallic matrix and the deposition of such a cermet to form a thick and tough coating presents problems. Most of the coating techniques have failed in attempting to homogeneously disperse very fine and hard particles in large amounts while avoiding their decomposition or reaction with the metal matrix during the deposition process. A simple and efficient method has been developed for producing ceramic-containing composite coatings. It consists in synthesizing cermet-based materials and in depositing them by a rapid solidification process, such as thermal spraying. Boride- and carbide-based materials have been successfully obtained by plasma spraying reactive powders comprising the basic reagents. These materials, with a microstructure of submicrometer ceramic particles dispersed in a metallic matrix, exhibit good wear-resistant properties ...
Emulsions now find a wide range of applications in industry and daily life. In the pharmaceutical industry lipophilic active ingredients as well as many nutritional products such as vitamins are often formulated in the dispersed phase of oil-in-water emulsions. Emulsions can be produced with different mechanical emulsification techniques. In the following review, the process of rotor-stator systems and disc systems are compared to other popular mechanical emulsification systems. On the basis of experimental results from the authors' laboratory, a discontinuous gear-rim dispersing system, discontinuous disc system, and a continuous high pressure system are compared with regard to their attainable mean droplet diameter and drop size distribution in an oil-in-water emulsion. It can be shown that dissolver discs with a very simple geometry attain very small mean droplet diameters and a very narrow droplet size distribution, comparable to ...
Central velocity dispersions and rotation curves to radii of approx.5 kpc have been measured for 32 galaxies, mostly field S0's. Our rotation curves confirm the result of Kormendy and Illingworth that the bulges of S0 galaxies are in rapid rotation, with enough rotational kinetic energy to account for their flattenings. The V/sigma-ellipticity relation we find for S0 bulges is compared with similar data for elliptical galaxies from Davies et al. We conclude that (1) faint SO bluges and elliptical galaxies (M/sub B/ fainter than -20.5) are both consistent with oblate rotators with isotropic velocity dispersions (although in our sample, S0 bluges are flatter, on the average, than ellipticals) and (2) bright S0 bulges, -22.0
Limited field trial results of a heating oil additive package developed to minimize unscheduled maintenance indicate that it achieves its goal of keeping heating oil systems cleaner. The multifunctional additive package was developed to provide improved fuel oxidation stability, improved corrosion protection, and dispersency. This combination of performance benefits was chosen because we believed it would retard the formation of sludge, as well as allow sludge already present to be carried through the system without fouling the fuel system components (dispersency should keep sludge particles small so they pass through the filtering system). Since many unscheduled maintenance calls are linked to fouling of the fuel filtering system, the overall goal of this technology is to reduce these maintenance calls. Photographic evidence shows that the additive package not only reduces the amount of sludge formed, but even removes existing sludge from ...
Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executive summary of the whole program followed by the dissertation of Ghosal and Ebert. Volume 2 contains the dissertation of Ebert which covers the measurements of the optical constants of slags, and calculations of the radiant properties of fly ash dispersions. A list of publications and conference presentations ...
Gravitational lensing by the dual cusp catastrophes of the cold dark matter (CDM) caustic rings at cosmological distances may provide the tantalizing opportunity to detect CDM indirectly, and discriminate between axions and weakly interacting massive particles (WIMPs). Caustics are places where the CDM particles are naturally focussed. Our focus is upon the caustic rings which are closed tubes whose cross-section is an elliptic umbilic catastrophe with three dual cusps. A caustic ring has a specific density profile, a specific geometry and, therefore, precisely calculable gravitational lensing signatures. The magnification monotonically increases as the line of sight approaches to the cusps where it diverges in the limit of zero velocity dispersion. In this limit, we find 37% magnification at a sample point near the outer cusps of the CDM caustic rings at cosmological distances. In the presence of finite velocity dispersion, the lower and upper ...
This study effort was required as a preliminary step prior to initiation of field measurements of atmospheric dispersion in coastal regions. The Nuclear Regulatory Commission (NRC) is in the process of planning an extensive field measurement program to generate data which will serve as improved data bases for licensing decisions, confirmation of regulations, standards, and guides, and for site characterizations. The study being reported here is an effort directed to obtaining as much information as is possible from existing studies that is relevant toward NRC's objectives. For this study, reports covering research and meteorological measurements conducted for industrial purposes, utility needs, military objectives, and academic studies were obtained and critically reviewed in light of NRC's current data needs. This report provides an interpretation of the extent of existing usable information, an indication of the potential for tailoring existing ...
This thesis is in the field of gas emission control from automobile and stationary sources. Out of the possible approaches to the elimination of pollutant gases, such as nitrogen oxides (NO{sub x}), one consists in the selective catalytic reduction (SCR) of these NO{sub x} on a suitable heterogeneous catalyst. Ammonia or hydrocarbons are employed as reducing agents. The most important catalysts active in the SCR of NO{sub x} are based on ions of transition metal either supported on several oxides or dispersed in zeolites. The catalysts have been characterized by electron magnetic resonance techniques (EPR, ENDOR, ESEEM) and the interaction of catalysts with nitrogen oxides, with reducing and poisoned agents have been followed with the same techniques. Copper dispersed on alumina and its interaction with both NO and ammonia has been investigated. Also the interaction between both water and ammonia with copper dispersed in ...
Capacitance dispersion on the fractal carbon electrode with edge and basal orientations was investigated using atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and a.c.-impedance spectroscopy. For this purpose, four types of as-received pyrolytic graphite electrode, as-received, mechanically polished, and as-activated glassy carbon electrodes were prepared with different surface irregularities and amounts of edge orientations. The apparent self-similar fractal dimensions of the carbon electrodes were determined from the analyses of AFM images based upon triangulation method. The amounts of edge orientations on the surface of the carbon electrodes were qualitatively estimated from the XPS analysis of surface acidic functional groups that were preferably formed on the edge planes by the heat treatment of the carbon electrodes. The values of the constant phase element exponent {alpha} determined from the apparent self-similar fractal dimensions ...
Performance assessments for the Area 5 Radioactive Waste Management Site on the Nevada Test Site have used three different mathematical models to estimate Rn-222 flux density. This study describes the performance, uncertainty, and sensitivity of the three models which include the U.S. Nuclear Regulatory Commission Regulatory Guide 3.64 analytical method and two numerical methods. The uncertainty of each model was determined by Monte Carlo simulation using Latin hypercube sampling. The global sensitivity was investigated using Morris one-at-time screening method, sample-based correlation and regression methods, the variance-based extended Fourier amplitude sensitivity test, and Sobol's sensitivity indices. The models were found to produce similar estimates of the mean and median flux density, but to have different uncertainties and sensitivities. When the Rn-222 effective diffusion coefficient was estimated using five different published predictive models, ...
Spectral absorption properties of total suspended matter (TSM) and colored dissolved organic matter (CDOM) are important for the use of the bio-optical model to estimate water quality parameters. This study aims to investigate the variation in the absorption coefficients of TSM and CDOM of inland waters. A total of 92 water samples were collected from Shitoukoumen Reservoir and Songhua Lake in Northeast China, analyzed for TSM and Chl-a, and measured for the absorption coefficient of TSM, CDOM and total pigments using a laboratory spectrophotometer. The absorption coefficient of TSM has been decomposed for phytoplankton and inorganic sediments. The results show that for Shitoukoumen Reservoir, CDOM has strong absorptions with shallow absorption slopes (i.e., the coefficient S in a(?)=a(?0)exp[-S(?- ?0)]) and large absorption at 355 nm; and for Songhua Lake, CDOM follows similar spectral absorption ...
The diffusion coefficient of radioactive radon (Rn) through buffer materials from low-level radwaste disposal site was determined in this present study by measuring the time-dependent diffusion of radon through a thin slab of the material. The diffusion process was required to reach a steady state so as to obtain a good estimate of the diffusion coefficient. A numerical method using the nonlinear least-squares and Marquardt`s method (NLSM method) was proposed for characterizing the diffusion coefficient of Rn so as to determine whether the process has reached steady-state or not. Natural mordenite, a potential buffer material of LLW disposal facility, was selected as testing porous material. The NLSM method was shown by the results to be able to estimate the diffusion coefficient even if the process was in transient period. Additionally, this method was also demonstrated to agree well with the results ...
This paper presents the characteristics of selected parameters of organic matter of the Tertiary coal samples and organic matter of Carboniferous rock samples from the Spitsbergen. The coal samples were taken from Central Coal Basin (the Longyearbyen region) and from the Forlandsundet Basin (Oscar II Land, the Kaffioyra region). Samples of dispersed organic matter were collected from Suffolk Pynten and Sergeijevfjellet area in Sorkapp Land. The optical properties of coal samples are different from properties of dispersed organic matter. Macerals of vitrinite group dominate in all of the samples. The average content of vitrinite group macerals is much lower in dipersed organic matter samples than it is in coals. The average content of liptinite group macerals is a little lower, and inertinite group macerals is much higher. The average content of mineral matter is higher in organic matter samples than in coal samples. The average value of ...
The Kadomtsev-Petviashvili equation describes nonlinear dispersive waves which travel mainly in one direction, generalizing the Korteweg-de Vries equation for purely uni-directional waves. In this Letter we derive an improved KP-equation that has exact dispersion in the main propagation direction and that is accurate in second order of the wave height. Moreover, different from the KP-equation, this new equation is also valid for waves on deep water. These properties are inherited from the AB-equation (E. van Groesen, Andonowati, 2007 ) which is the unidirectional improvement of the KdV equation. The derivation of the equation uses the variational formulation of surface water waves, and inherits the basic Hamiltonian structure.
With the increased usage of dispersion models that require stack top wind information, such as the Complex Terrain Dispersion Model (CTDM), the need for a reliable method to collect elevated wind data has also increased. Doppler Sound Detection and Ranging (SODAR) instruments have gained recognition as a viable means of collecting such data. SODAR technology has improved greatly over the last decade and is now a cost effective alternative to tall meteorological towers. SODARs are remote sensing devices that sample the atmosphere and calculate wind speed and wind direction data at different altitudes. This is accomplished by measuring the doppler shift of an acoustic pulse emitted by a ground level antenna.
We report Sr, Pd and Ag abundances for a sample of metal-poor field giants and analyze a larger sample of Y, Zr, and Ba abundances. The [Y/Zr] and [Pd/Ag] abundance ratios are similar to those measured for the r-process-rich stars CS 22892-052 and CS 31082-001. The [Pd/Ag] ratio is larger than predicted from the solar-system r-process abundances. The constant[Y/Zr] and [Sr/Y] values in the field stars places strong limits on the contributions of the weak s-process and the main s-process to the light neutron-capture elements. Stars in the globular cluster M 15 possess lower [Y/Zr] values than the field stars. There is a large dispersion in [Y/Ba]. Because the r-process is responsible for the production of the heavy elements in the early Galaxy, these dispersions require varying light-to-heavy ratios in r-process yields.
Published density profiles and central velocity dispersions place important constraints on the stellar velocity ellipsoid and on the distribution of dark matter (DM) in the dwarf spheroidal galaxies Draco and Ursa Minor. Central velocity dispersions of 9 km/s are adopted for Draco and 11 km/s for Ursa Minor. Then, for an isotropic stellar velocity distribution, the central DM densities are 0.8 and 1.0 solar mass/cu pc, respectively, if visible and dark matter have the same core radius. If DM has a much larger core radius than visible matter but nevertheless dominates the potential, these densities are reduced by a factor of 2. Central DM densities can be lower than this only if the stellar velocity distribution is anisotropic. Simple two-component King models are used to investigate this and to look for the smallest DM densities that are consistent with the observations. 36 refs.
Consideration is given to the stability of negative ion beams which are neutralized through ionization of a background gas. Two types of instabilities are examined. First, beam-plasma instabilities are analyzed with the dispersion relation showing that they are unimportant if the beam velocity is less than the electron thermal velocity. Second, results of a computer simulation on the flow of a cylindrical beam and the resulting background plasma show that when the background neutral gas density is less than or approximately equal to a critical density as instability occurs. This critical density is the density that would be needed to space-charge neutralize the beam if the positive ions were not retarded by the beam. An approximate dispersion relation indicates that the nature of the instability is a transverse positive-ion acoustic wave which couples to the beam.
In this paper, a time-domain equivalent circuit method is applied to solve dispersion of coupled-cavity travelling-wave tube (CCTWT). First, the time-domain circuit equations of CCTWT coupled-cavity chain are deduced from the equivalent circuit model. Then, the equations are solved numerically by fourth-order Runge-Kutta method and a program CTTDCP is developed using MATLAB. Last, a L-band CCTWT is calculated using CTTDCP and the cavity pass-band of this tube is computed to be 1.08-1.48 GHz, which is consistent with the experimental results and the simulation results of electromagnetic code and demonstrates the validity of the time-domain equivalent circuit method. In addition, a new design method which uses the equivalent circuit method and electromagnetic simulation together to optimize the cold cavity characteristics of CCTWT is proposed. (authors)
Novel fluoroalkyl end-capped vinyltrimethoxysilane oligomeric nanoparticles were prepared by the hydrolysis of the corresponding oligomer under alkaline conditions. The size of fluorinated nanoparticles thus obtained is of submicrometer levels and is not sensitive to the refractive indices of a variety of solvents; however, the turbidity of the dispersed fluorinated nanoparticles is extremely sensitive to the refractive indices of these solvents. In particular, the solvents of which the refractive indices are from 1.378 to 1.408 were found to afford the transparent colorless dispersed particle solutions. More interestingly, the modified glass surface treated with fluorinated nanoparticles exhibited a completely superhydrophobic characteristic (a water contact angle: 180?) with a nonwetting...
We investigate two routes to obtain negative group velocity bands in two-dimensional phononic crystal structures. The negative dispersion originates from the resonances of sub-wavelength building blocks and as such, the system should be regarded as acoustic metamaterials. The first kind of acoustic metamaterial exhibits effectively negative bulk modulus and negative mass density simultaneously. Monopolar and dipolar Mie resonances are combined to achieve an effective medium with negative refractive index. In particular, we present a double negative metamaterial for airborne sonic waves. We then show that we can obtain negative group velocity from quadrupole resonances, and the result is explained using the quasi-static approximation. The negative dispersion in quadrupole bands cannot be de...
TRANSVERSE EMITTANCE PRESERVATION IS A MAJOR CONCERN OF THE LHC INJECTOR CHAIN. MINIMISATION OF THE BLOW-UP DUE TO MISMATCH AT INJECTION INTO THE SPS IS THEREFORE MANDATORY. WHILE THE TRANSVERSE POSITIONN OF THE BEAM IN THE SPS INJECTION LINE IS MONITORED BUNCH BY BUNCH BY AN OTR (OPTICAL TRANSITION RADIATION) SCREEN AND A FAST CCD (CHARGED COUPLED DEVICE) CAMERA, THE PHASE SPACE MATCHING AT INJECTION IS MONITORED BY AN OTR BASED MISMATCH MONITOR IN THE SPS RING. ORTHOGONAL TUNING KNOBS WERE DEVELOPED TO TUNE INDEPENDENTLY TWISS PARAMETERS, DISPERSION AND DISPERSION DERIVATIVE. IN THIS PAPER WE DESCRIBE THE MISMATCH CORRECTION MECHANISM AS WELL AS THE TWO MONITORING SYSTEMS. WE REPORT ON FIRST MEASUREMENTS WHICH WERE CARRIED OUT DURING THE 1998 SPS RUN.
Mechanical alloying is an important pre-requisite for the manufacturing of heat resistant oxide-dispersion-strengthened superalloys. Though the microstructure of these materials after hot extrusion and recrystallization treatment is well documented, little is known about the microstructural evolution during ball-milling. A method was tested to prepare electron transparent foils and extraction replica from powder particles for TEM investigations. The microstructure was found to consist of a Ni-Cr-Al solid solution in which submicron particles of refractory metals were embedded. The extremely fine grainize of about 50 nm is the consequence of severe plastic deformation. Yttria particles could not be detected in the powder after ball milling, but after a heat treatment at 1000 C the well-known fine dispersion of oxide particles was evident. (orig.)
Abstract Four methods were used to extract length scales from mixing data: the maximum striation thickness, point-to-nearest-neighbour (PNN) distributions, the correlogram and the variogram. Four test data sets were analysed: blending in a micromixer; particle dispersion in a stirred tank; dispersion of a smoke plume and a pulse tracer test in a reactor. The maximum striation thickness captures the largest length scale. The PNN method quantifies differences between clustered, random and regular spatial distributions. The correlogram calculation cannot be consistently used for all types of mixing data and has therefore been rejected. The variogram reveals both large-scale segregation and periodicity. Sub-sampling is needed to isolate smaller structures. The variogram, PNN and transect metho...
Regularities of deformation-induced dissolution of a surface layer of iron oxides in matrixes of iron-based alloys with bcc and fcc lattices have been studied by the methods of M?ssbauer spectroscopy, transmission electron microscopy, and X-ray diffraction. A method of producing iron alloys strengthened by dispersed oxide nanoparticles and alloyed with elements possessing a high affinity to oxygen (titanium and yttrium) has been proposed, which implies a dynamic dissolution of a surface layer of iron oxides upon strong cold deformation and a precipitation of secondary yttrium and titanium nanooxides upon a subsequent high-temperature sintering of mechanically alloyed powders. There has been demonstrated a possibility of oxide strengthening of pure iron upon its interaction with air without...
Microreserves may be useful in protecting native arthropod diversity in urbanized landscapes. However, species that do not disperse through the urban matrix may eventually be lost from these fragments. Population extinctions may be precipitated by an increase in genetic differentiation among fragments and loss of genetic diversity within fragments, and these effects should become stronger with time. We analyzed population genetic structure in the dispersal limited Jerusalem cricket Stenopelmatus n. sp. ?santa monica?? in the Santa Monica Mountains and Simi Hills north of Los Angeles, California (CA), to determine the impacts of fragmentation over the past 70 years. MtDNA divergence was greater among urban fragments than within contiguous habitat and was positively correlated with fragment ...
Abstract The Brazilian Atlantic Forest is one of the richest biodiversity hotspots of the world. Paleoclimatic models have predicted two large stability regions in its northern and central parts, whereas southern regions might have suffered strong instability during Pleistocene glaciations. Molecular phylogeographic and endemism studies show, nevertheless, contradictory results: although some results validate these predictions, other data suggest that paleoclimatic models fail to predict stable rainforest areas in the south. Most studies, however, have surveyed species with relatively high dispersal rates whereas taxa with lower dispersion capabilities should be better predictors of habitat stability. Here, we have used two land planarian species as model organisms to analyse the patterns ...
Laboratory {open_quotes}jar{close_quotes} tests compared eleven different fuel oil and diesel fuel sludge-control additives. Factors studied included (1) ability to disperse and prevent buildup of sludge deposits on surfaces, (2) ability to protect steel from corrosion, (3) ability to inhibit growth and proliferation of bacteria, and (4) ability to disperse water. Results varied greatly, and it was found that many commercial products do not do what they claim. It is concluded that fuel retailers should not believe manufacturers` claims for their additive products, but rather should test such products themselves to be sure that the benefits of treatment are real. A simplified form of the procedure used here is proposed as one way for dealers to do such testing.
Using the method of statistic planning of an experiment, the SrSO_4 desulfurization process has been studied in the case of reductive roasting of celestine with the use blast-furnace coke. The main factors that determine the rate of the SrSO_4 desulfurization are the roasting temperature and charge components dispersity. The desulfurization rate increases proportionally to the increase in the roasting temperature and dispersity of the reaction mixture components. To decrease the SrSO_4 desulfurization and the concentration of sulfur-containing components in gases released at rather a high celestine reduction rate, the roasting is recommended to proceed at the temperature of 1100 to 1150 deg, in this case it is necessary to limit the content of small (less than 3.2 mm) fractions of reagents.
Heat-transfer augmentation by straight grid spacers in rod bundles is studied for single-phase flow and for post-critical heat flux dispersed flow. The heat transfer effect of swirling grid spacers in single-phase flow is also examined. Governing heat-transfer mechanisms are analyzed, and predictive formulations are established. For single-phase flow, the local heat transfer at a straight spacer and at its upstream or downstream locations are treated separately. The effect of local velocity increasing near swirling spacer is considered. For post critical heat flux (CHF) dispersed flow, the heat transfer by thermal radiation, fin cooling, and vapor convection near the spacer are calculated. The predictions are compared with experimental data with satisfactory agreement.
The so-called spectral dimension is a scale-dependent number associated with both geometries and field theories that has recently attracted much attention, driven largely though not exclusively by investigations of causal dynamical triangulations (CDT) and Horava gravity as possible candidates for quantum gravity. We advocate the use of the spectral dimension as a probe for the kinematics of these (and other) systems in the region where spacetime curvature is small, and the manifold is flat to a good approximation. In particular, we show how to assign a spectral dimension (as a function of so-called diffusion time) to any arbitrarily specified dispersion relation. We also analyze the fundamental properties of spectral dimension using extensions of the usual Seeley-DeWitt and Feynman expansions, and by saddle point techniques. The spectral dimension turns out to be a useful, robust and powerful probe, not only of geometry, but also of kinematics.
A new fuel-cell electrocatalyst based on highly porous carbonized polyacrylonitrile (PAN) microcellular foam with platinum particles was prepared recently in this laboratory. Its surface morphology, one of the most important aspects of a practical electrocatalyst, has been examined in terms of fractal theory and methods. The fractal dimension of the platinum particles dispersed in porous carbonized PAN foam was determined by using chronometric and rotating-disk-electrode methods in oxygen-saturated solutions. A fractal dimension smaller than 2 was obtained, which was attributed to the partially active nature of the surface of this electrocatalytic material. This value of fractal dimension is also proposed to be considered as a reaction dimension. A reaction dimension smaller than 2 may indicate that not all of the platinum particle surface is accessible to the incoming oxygen molecules.
Stellar rotation velocities and velocity dispersions along three slit positions in M31 have been measured, and three-dimensional velocity and velocity dispersion fields are obtained in order to search for a central black hole. Synthetic apparent spectra are constructed to eliminate problems with the reaction of the Fourier quotient program to stellar population mixes. Models are constructed to explore parameter space. The large velocities and velocity gradients that are found imply that the total mass-to-light ratio rises sharply at r of 0.5 arcsec or less to values greater than 100. This is much larger than normal for old stellar populations. Velocity anisotropies are not a major uncertainty because of the rapid rotation. There is thus strong evidence for a dark central mass, probably a supermassive black hole. 48 references.
Stellar rotation velocities and velocity dispersions have been measured along the major and minor axes of NGC 4594 with the Canada-France-Hawaii Telescope. The observations show the kinematic signature of a nuclear disk of stars superposed on the bulge (Fig. 1). Apart from its larger size, this is similar to the nucleus of M31. It rotates rapidly: the apparent rotation curve reaches an inner maximum of V 231 #+-# 7 km s"-"1 at r = 5.''0. The apparent velocity dispersion falls from #sigma# = 250 #+-# 7 km s"-"1 at the center to 181 #+-# 6 km s"-"1 at r = 3.''7. (author).
We have obtained radial velocities for 69 stars in the globular cluster M2 (NGC 7089). M2's rotation axis is, within sizeable uncertainties, perpendicular to the major axis determined by the flattening. The ratio of rotational to random kinetic energy agrees with that predicted from the ellipticity assuming an oblate figure and an isotropic velocity-dispersion tensor. We have fitted King-Michie models to determine M2's mass, the exponent of an assumed power-law mass function, and the anisotropy radius. The most significant sources of uncertainty in the modeling are the velocity dispersion, the distance, and the mass-luminosity relation for the cluster stars. The models favor mass functions similar to or shallower than the Salpeter initial-mass function and a moderate amount of velocity anisotropy.
Rapid administration of stable iodine is essential for the saturation and subsequent protection of the thyroid gland against the potential harm caused by radioiodines. This paper proposes the Dutch risk analysis that uses an atmospheric dispersion model to calculate the size of the zones around nuclear power plants where radiological thyroid doses for children might be sufficiently high to warrant iodine administration. Dose calculations for possible releases from the nuclear power plants of Borssele (The Netherlands), Doel (Belgium) and Emsland (Germany) are based on two scenarios in combination with a 1-y set of authentic, high-resolution meteorological data. The dimensions of the circular zones were defined for each nuclear power plant. In these zones, with a radius up to 50 km, distribution of stable iodine tablets is advised. PMID:20332130
Rapid administration of stable iodine is essential for the saturation and subsequent protection of the thyroid gland against the potential harm caused by radioiodines. This paper proposes the Dutch risk analysis that uses an atmospheric dispersion model to calculate the size of the zones around nuclear power plants where radiological thyroid doses for children might be sufficiently high to warrant iodine administration. Dose calculations for possible releases from the nuclear power plants of Borssele (The Netherlands), Doel (Belgium) and Emsland (Germany) are based on two scenarios in combination with a 1-y set of authentic, high-resolution meteorological data. The dimensions of the circular zones were defined for each nuclear power plant. In these zones, with a radius up to 50 km, distrib...
In this project, graphite is used as a substitute for lead in order to maintain the machinability of plumbing components at the level of leaded brass. Graphite dispersed in Cu alloy was observed to impart good machinability and reduce the sizes of chips during machining of plumbing components in a manner similar to lead. Copper alloys containing dispersed graphite particles could be successfully cast in several plumbing fixtures which exhibited acceptable corrosion rate, solderability, platability, and pressure tightness. The power consumption for machining of composites was also lower than that of the matrix alloy. In addition, centrifugally cast copper alloy cylinders containing graphite particles were successfully made. These cylinders can therefore be used for bearing applications, as substitutes for lead-containing copper alloys. The results indicate that copper graphite alloys developed under this DOE project have a great potential to ...
The Atmospheric Release Advisory Capability (ARAC) at the Lawrence Livermore National Laboratory uses the U.S. Navy's Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS) to supply high-resolution wind data for use in its real-time dispersion modeling system. ARAC has used COAMPS products to support several events and exercises, and COAMPS forecasts appear accurate, based on qualitative examination. Recently ARAC has developed a quantitative verification system which calculates COAMPS error and bias statistics, comparing COAMPS forecasts of various lengths with observational data. This paper shows how this system has been used to guide ARAC operators, who need an estimate of the likely behavior of COAMPS forecasts of various lengths in different regions, seasons, and weather patterns.
A prism spectrometer has been developed to operate in the VUV wavelength range from 120 to 200 nm. It can be used as a pre- disperser in conjunction with a Fabry-Perot based gas refractometer. This instrument has also been used to measure the refractive index of the liquid radiator C/sub 6/F/sub 14/ in various spectral lines. This radiator is used in the RICH detectors of the DELPHI experiment and has been proposed for ALICE, and LHCb experiments. The spectral resolution of the system is improved as the wavelength decreases and the data are consistent with a wavelength accuracy about 0.4 nm at 140 nm. The results for the dispersion curve of the above liquid are presented. (17 refs).
Bis(imido) uranium(VI) trans- and cis-dichalcogenate complexes with the general formula U(NtBu)2(EAr)2(OPPh3)2 (EAr = O-2-tBuC6H4, SPh, SePh, TePh) and U(NtBu)2(EAr)2(R2bpy) (EAr = SPh, SePh, TePh) (R2bpy = 4,4'-disubstituted-2,2'-bipyridyl, R = Me, tBu) have been prepared. This family of complexes includes the first reported monodentate selenolate and tellurolate complexes of uranium(VI). Density functional theory calculations show that covalent interactions in the U-E bond increase in the trans-dichalcogenate series U(NtBu)2(EAr)2(OPPh3)2 as the size of the chalcogenate donor increases and that both 5f and 6d orbital participation is important in the M-E bonds of U-S, U-Se, and U-Te complexes.
Potassium atoms in selected high-lying np Rydberg states (80 #<=# n #<=# 400) are being used as a tool to examine electron-polar molecule collisions at ultra-low energies (#approx#80 #mu#eV - 1 meV). This energy regime has not been investigated previously and is of interest because the corresponding electron de Broglie wavelength is large, #approx#1300 - 330 Angstrom, and because the collision time is comparable to the period of molecular rotation. A variety of target molecules has been studied, including simple rotors such as HF, and more complex species such as NH_3, CH_3I, CH_2Br_2 and C_6H_5NO_2. These targets encompass a range of dipole moments and rotational behavior, but analysis of the data shows that in each case the cross section #sigma#(#epsilon#) for rotationally-inelastic electron-polar molecule scattering varies approximately as 1/#epsilon# where #epsilon# is the electron energy. Such threshold behavior is not predicted by ...
Heavy ion irradiation on tantalum metal target with 57 MeV "1"1B"4"+ leads to the production of no-carrier-added radioisotopes of platinum, "1"8"7","1"8"8Pt and iridium, "1"8"7","1"8"8Ir in the matrix, which have been effectively separated from the bulk target and from each other with suitable anion exchangers employing liquid-liquid extraction (LLX). Also "1"8"8","1"8"9Pt and "1"8"8","1"8"9Ir radionuclides have been produced, from their short-lived precursors "1"8"8","1"8"9Au, in "1"2C"6"+ irradiated tantalum matrix. Gamma-spectroscopy has been utilised to determine the production, extent of separation and purity of the radiotracers at different stages of the experiment. (orig.)
In this study, dissimilar welds between HP heat-resistant steel and Incoloy 800 were made with four different filler materials including: 309 stainless steel and nickel-based Inconel 82, 182 and 617. The microstructure of the base metals, weld metals and their interfaces were characterized by utilizing optical and scanning electron microscopy. Grain boundaries migration in the weld metals was studied. It was found that the migration of grain boundaries in the Inconel 82 weld metal was very extensive. Precipitates of TiC and M_2_3C_6 (M = Cr and Mo) in the Inconel 617 weld metal are identified. The necessary conditions for the formation of cracks close to the fusion line of the 309-HP joints are described. Furthermore unmixed zone near the fusion line between HP steel base metal and Inconel 82 weld metal is discussed. An epitaxial growth is characterized at the fusion line of the 309-Alloy 800 and Inconel 617-Alloy 800 joints.
Because of their austenitic-ferritic microstructures, duplex stainless steels offer a good combination of mechanical and corrosion resistance properties. However, heat treatments can lower the mechanical strength of these stainless steels as well as render them susceptible to intergranular corrosion (IGC) and pitting corrosion. In this study, a low-carbon (0.02%) duplex stainless steel is subjected to various heat treatments at 450 to 950 C for 30 min to 10 h. The heat-treated samples than undergo ASTM IGC and pitting corrosion tests, and the results are correlated with the microstructures obtained after each heat treatment. In the absence of Cr_2_3C_6 precipitation, #sigma#-phase precipitates render this duplex stainless steel susceptible to IGC and pitting corrosion. Even submicroscopic #sigma#-phase precipitates are deleterious for IGC resistance. Longer-duration heat treatments (at 750 to 850 C) induce chromium diffusion to replenish the ...
Using a radioactive tracer method the bulk and grain boundary diffusion of "5"9Fe was determined in industrial alloy 800 and melts of alloy 800 with additional P and S in the temperature range 800 to 1000 C. The use of the approximation of Suzuoka was confirmed by autoradiographs. In alloy 800 H the activation energy of grain boundary diffusion of "5"9Fe is (209 #+-# 17)kJ/mol. Dissolved elements especially P increase the activation energy of the grain boundary diffusion of Fe by their segregation to the grain boundaries. In addition the influence of the grain boundary diffusion on the growth of creep cavities was investigated in the same materials, and the chemical composition of the creep cavities and grain boundaries were analysed by Auger electron spectroscopy (AES). For alloy 800 + 0.088 wt-%P an enrichment of about 14 at-%P was observed at the grain boundaries. The addition of P clearly enhances the creep strength of alloy 800; this can probably be explained by precipitation of ...
Application of Alloy 800 in steam generator tubing of fast reactors, where continuous service temperature of the order of 550"0C is experienced, has been analyzed with respect to small variations in its chemical composition. Several laboratory melts of Alloy 800 have been prepared and their microstructural and mechanical property changes during simple aging and creep tests at 500 to 600"0C have been studied. It has been found that in the above temperature range precipitation of M_2_3C_6 on the grain boundaries is independent of the Ti : C ratio generally specified for Alloy 800. Gamma prime precipitation occurred in alloys containing as low as 0.5 percent Ti + Al after 1000 h of aging and was accompanied with a creep ductility decline. Upon #gamma# precipitation creep rate was retarded and its reacceleration for test times up to 8500 h at 550"0C was not observed. Based on the findings, increased Ti concentration at the expense of Al within the ...
Stereoselective methods for synthesising iminoalditols are still needed, as this class of compounds is known to contain strong glycosidase inhibitors. We have for some time investigated (1) the possibilities for using 2-amino-6-bromo-2,6-dideoxy-aldonolactones as starting materials for such compounds, since a substitution at C-6 by the 2-amino group should lead to the target molecules. We have found that treatment of mentioned 2-aminolacones with aqueous base gave 5- or 6-membered iminoalditols depending of the stereochemistry of the lactone, while under non aqueous conditions only formation of 6-membered iminoalditols were observed. The use of triethylamine in methanol thus gave methylesters of 6-membered iminouronic acids. Reduction of the ester group with sodium borohydride gave the target compounds. The mechanisms of the reactions will be discussed as well as specific results obtained. (1) Lundt, I. Top. Curr. Chem. 1997, 187, 117-156
Early effects of boron neutron capture therapy (BNCT) on malignant glioma are characterized by reduction of the enhancement area and regression of the peritumoral edema radiologically. The aim of this study was to investigate the early histological changes of tumors and inflammatory cells after BNCT in the rat brain. Rats were treated with BNCT using boronophenylalanine (BPA) 7 days after implantation of C6 glioma cells. The tumors were assessed with magnetic resonance imaging and histopathological examination at 4 days after BNCT. The mean tumor volumes were 39#+-#2 mm"3 in the BNCT group and 134#+-#18 mm"3 in the control group. In the BNCT group, tumor cells showed a less pleomorphic appearance with atypical nuclei and mitotic figures. The Ki-67 labeling index was 6.5%#+-#4.7% in the BNCT and 35%#+-#3.8% in the control group. The reactions of the inflammatory cells were examined with ED-1 as macrophage marker and OX42 as microglia marker. ...
The paper presents the preparation, X-ray powder diffraction data as well as some magnetic and spectroscopic properties of a new uranium(III) complex bromide of the formula NH{sub 4}UBr{sub 4}.1.5CH{sub 3}CN.6H{sub 2}O. The compound crystallizes in the monoclinic system with a=11.877 A, b=6.385 A, c=6.815 A, {beta}=101.29deg and Z=2. In the 60-240 K range it follows the Curie-Weiss law with {theta}=-37.24 K and {mu}{sub eff}=3.20 B.M. The IR and UV-VIS absorption spectra were recorded in the 80-4000 cm{sup -1} and 4000-26000 cm{sup -1} spectral ranges respectively. Thermal decomposition at a non-static high vacuum enabled the conversion of the compound into pure and anhydrous UBr{sub 3}. (orig.).
At 650"0C, the low-cycle fatigue life was essentially the same for the two alloys on the basis of strain amplitude, but Alloy 800H had a longer life on the basis of stress amplitude. A 500"0C, Alloy 800 and 800H exhibited longer fatigue lifetime than at 650"0C, with Alloy 800 exhibiting a 2-3 times longer life than Alloy 800H when compared on the basis of plastic strain range, whereas the difference was less pronounced when compared on the basis of stress amplitude. When a creep effect was introduced either by way of a hold time or a reduced frequency, Alloy 800 exhibited a greater reduction in life than did Alloy 800H. The dislocation structure changed from planar to cellular with increase in strain range, and extensive precipitation of M_2_3C_6 was noted within the grains for Alloy 800H and along grain boundaries for both alloys. (Auth.).
Penicillic acid-negative mutants were obtained from a color mutant derived from Penicillium cyclopium NRRL 1888 through N-methyl-N'-nitro-N-nitrosoguanidine treatment. One mutant (SK2N6) accumulated 6-methyl-1,2,4-benzenetriol, which was not previously known to be a metabolite of P. cyclopium, in addition to orsellinic acid and orcinol. The radioactivity of [1-"1"4C]acetic acid was rapidly incorporated into 6-methyl-1,2,4-benzenetriol in a culture of P. cyclopium SK2N6. Moreover, the radioactivity of ["1"4C]6-methyl-1,2,4-benzenetriol was efficiently incorporated into penicillic acid in a culture of P. cyclopium NRRL 1888. These data indicate that 6-methyl-1,2,4-benzenetriol is a precursor for penicillic acid biosynthesis. The results on the addition of 1,4-dihydroxy-6-methoxy-2-methylbenzene, 6-methoxy-2-methylbenzoquinone (1,4), and 1-O-methylorcinol to a culture of P. cyclopium SK2N6 indicated that only the former two compounds are converted ...
It is shown that the extended softening in k space of the [111] transverse acoustic phonon in Nb_3Sn seen recently by neutron measurements is in agreement with the predictions of a phenomenological Landau description of the structural phase transition in the A-15 compounds. This indicates the feasibility of a calculation of the partial phonon density of states of modes directly coupled to the order parameter driving the structural transition, as a function of temperature.
It is shown that the extended softening in k space of the [111] transverse acoustic phonon in Nb3Sn seen recently by neutron measurements is in agreement with the predictions of a phenomenological Landau description of the structural phase transition in the A-15 compounds. This indicates the feasibility of a calculation of the partial phonon density of states of modes directly coupled to the order parameter driving the structural transition, as a function of temperature.
Zinc tetraaminophthalocyanine-Fe3O4 nanoparticle composites were prepared by organic-inorganic complex technology and characterized. It has been proved that the ZnTAPc dispersed...Full Text Available
Retention or dispersion of larvae from the spawning grounds has been identified as one of the key processes influencing recruitment success in fish stocks. To examine the potential effects of transport on recruitment. numerical simulations were performed utilizing a three-dimensional physical oceanographic model of the Baltic Sea. Cod larvae were represented as Lagrangian drifters released in the deepwater region of the Bornholm Basin, the main spawning ground for Baltic cod. Simulations were performed for the major spawning seasons of 1993 and 1994. when annual and interannual variability of meteorological forcing was large. The principal goals of the modelling exercise were first to identify the physical processes influencing the demersal distribution of the early life stages and second to describe the transport of the pelagic stages in response to variations in windstress, thereby identifying the meteorological and hydrodynamic mechanisms influencing retention ...
A new optics providing an emittance close to the minimum theoretical value has been proposed for the Super-ACO storage ring with a reduced value of the momentum compaction factor and non-zero dispersive function in the Free-Electron Laser (FEL) section. It has been adapted to the FEL operation mode, with two RF cavities at 100 and 500 MHz. The obtained results concerning this new optics and the FEL oscillation are presented.
In a slurry explosive, the fine droplets of the aqueous phase are dispersed in a continuous oily phase which comprises a thin film surrounding each droplet, the latter being less than one micron in size. The authors present these commercial explosives in three different forms, indicate their explosive properties and discuss their advantages from the safety viewpoint. They also report on tests undertaken with slurry explosives in quarries possessing different types of rock and using deep vertical shotholes.
We discuss optimal detection of fast radio transients from astrophysical objects while taking into account the effects of propagation through intervening ionized media, including dispersion, scattering and scintillation.Our analysis applies to the giant-pulse phenomenon exhibited by some pulsars, for which we show examples, and to radio pulses from other astrophysical sources, such as prompt radio emission from gamma-ray burst sources and modulated signals from extra-terrestrial civilizations.
Three dimensional rotatory modes of oscillations in a one-dimensional chain of rodlike charged particles or dust grains in a plasma are investigated. The dispersion characteristics of the modes are analyzed. The stability of different equilibrium orientations of the rods, phase transitions between the different equilibria, and a critical dependence on the relative strength of the confining potential are analyzed. The relations of these processes with liquid crystals, nanotubing, and plasma coating are discussed.
A brief review and assessment of field measurement programs that provide data for mixed layer diffusion research is presented. The majority of programs emphasize either the meteorological aspects of the mixed layer or plume characterization. Few programs are available that provide the complimentary blend of plume and appropriate meteorological measurements needed to adequately validate mixed layer diffusion theory. Three major U.S. EPA (Environmental Protection Agency) field programs that provide data bases for model development and validation of mixed layer diffusion processes are described and discussed in more detail. The Regional Air Pollution Study (RAPS) focused on measurements of surface and mixed layer turbulent transport processes in the urban environment. The Tennessee Plume Study (TPS) obtained a database with coincident measurement of boundary layer turbulent structure and plume dispersion for a large coal-fired power plant in nonuniform terrain over ...
Amoco Trinidad Oil Company produces 60,000 bbl/d of oil from the Trinidadian offshore. The oil is pipelined ashore where it is processed and returned offshore to a buoy mooring for transport up Trinidad's east coast. Amoco Trinidad has developed comprehensive oil spill contingency plans, starting from computer models of spill scenarios. The models used initially assumed that the oils would emulsify quickly and the spills would become highly viscous and persistent, reaching the shoreline in 15-24 h. Such behavior would render ineffective the use of dispersants as a spill countermeasure. Studies showed a poor potential capability of physical recovery systems for spills off the Trinidad east coast due to high sea states, strong winds, and other factors. These results led to questioning of the spill model's assumptions, and laboratory tests were conducted to study the actual behavior of the crude oils. It was found that the oil was difficult to emulsify and highly ...
The horizontal spread of a plume in atmospheric dispersion can be described by the standard deviation of horizontal direction. The widely used Pasquill-Gifford classes of atmospheric stability have assigned typical values of the standard deviation of horizontal wind direction and of the lapse rate. A measured lapse rate can thus be used to estimate the standard deviation of wind direction. It is examined by means of a large dataset of fast wind measurements how good these estimates are. (author) 1 fig., 2 refs.
The Formerly Utilized Sites Remedial Action Program (FUSRAP) is to evaluate the radiological conditions at former MED-US AEC sites. Purpose of the Ocean FUSRAP program is to assess the feasibility of ocean disposal of FUSRAP waste which contains trace natural radioactive materials. This paper presents soil characterization information on the Middlesex, NJ, Sampling Plant site, and reports preliminary ocean dispersion calculations. (DLC)
This chapter discusses the types of natural radioactive materials in the environment that include primordial natural radioactive materials such as K-40, U and Th, and daughters of their decay series. The discussion also includes secondary natural radioactive material generated through cosmic radiation interaction with nucleus of materials in the atmosphere. The dispersion of these radioactive materials to environment will also be part of the discussion. (Author)
Based on the nonlinear dispersion relation of electromagnetic wave in relativistic plasma, the nonlinear controlling equation for linearly polarized mode is obtained using Karpman's method. The modulation instability of intense laser pulse propagating through relativistic plasma is analyzed and the modulation instability growth rate as a function of perturbation wave number for laser beam propagating through relativistic plasma is given. (authors)
The surface properties of copper-refractory metal (CU-RF) alloy bodies are modified by heat treatments which cause the refractory metal to form a coating on the exterior surfaces of the alloy body. The alloys have a copper matrix with particles or dendrites of the refractory metal dispersed therein, which may be niobium, vanadium, tantalum, chromium, molybdenum, or tungsten. The surface properties of the bodies are changed from those of copper to that of the refractory metal.
Microwaves improve the rate of many chemical reactions either interacting with the solvent, when the reaction is carried out in solution, or with the surface of a solid substrate where a suitable reagent is dispersed (dry chemistry). A few examples of chemical reactions positively affected by microwaves are described: particularly interesting are those concerning polymers and radio-pharmaceuticals.
The production of water from a subterranean formation is reduced by contacting the formation with a water dispersible hydrophilic organic polymer having a molecular weight greater than 100,000 and containing carboxyl functionality and a crosslinking composition comprising water, a zirconium compound having a value of 4+, an alpha-hydroxy acid and an amine compound.
A method is proposed for deriving hydrolized polyacrylonitrile from a water-based alkali solution. This process is meant to improve the thermal stability of clay drilling solutions by employing the hydrolized product to treat aliphatic non-water-soluble C/sub 8/-C/sub 16/ spirits in an organic dispersant during the presence of acidity and while the solution is being heated.
The magnetic excitations of the Kondo compound CePd_2Si_2 below its Neel temperature (T_N = 10 K) have been studied by inelastic neutron scattering. At T = 1.6 K the data are best represented by two dispersive inelastic modes. Their linewidth (#propor to# 0.5 meV) indicates substantial broadening, which is ascribed to Kondo-type local fluctuations. (orig.).
Methods of solving Navier-Stokes equations for turbulent channel flow are given. These numerical solutions utilize either Neumann or Dirichlet boundary conditions. Computer codes were written and tested and are discussed. Digital image processing of flow visualization video sequences, taken simultaneously with vorticity probe measurements in a turbulent boundary layer, were carried out. 4 figs. (GHH)
An advanced ceramic dome cavity receiver is discussed which heats pressurized gas to temperatures above 1800/sup 0/F (1000/sup 0/C) for use in solar Brayton power systems of the dispersed receiver/dish or central receiver type. Optical, heat transfer, structural, and ceramic material design aspects of the receiver are reported and the development and experimental demonstration of a high-temperature seal between the pressurized gas and the high-temperature silicon carbide dome material is described.
Heat transfer augmentation by straight grid spacers in rod bundles is studied for single phase flow and for post critical heat flux dispersed flow. The heat transfer effect of swirling grid spacers in single phase flow is also examined. Governing heat transfer mechanisms are analyzed, and predictive formulations are established. For single phase flow, the local heat transfer at a straight spacer and at its upstream or downstream locations are treated separately. 18 refs.
The Euler-Maxwell system describes the evolution of a plasma when the collisions are important enough that each species is in a hydrodynamic equilibrium. In this paper we prove global existence of small solutions to this system set in the whole three-dimensional space, by combining the space-time resonance method, dispersive estimates, localization estimates and energy estimates. An important novelty is that we can prove a very slow growth of high derivatives even with a nonintegrable decay by reiterating the energy estimate.
Distribution of scattered elements in basic minerals of salt-rocks is studied. It is shown that rubidium and cesium are accumulated mainly in carnallites and are contained in small quantities halites. These elements are accumulated primarily in the carnallite production products, wherein their content in a number of cases exceeds by dozens and hundred times their content in source rocks. It is noted that only carnallites may be considered in the list of actual sources for rubidium and cesium separation
Mn-modified Pb0.92La0.08(Zr0.65Ti0.35)O3 (PLZT) was prepared chemically by a coprecipitate method using their respective nitrate salts and isopropoxides. Differential thermal analysis (DTA) and X-ray analysis clearly show the formation of PLZT single rhombohedral phase for samples calcined beyond 750 C. Uniform grain distribution was observed from scanning electron microscopic (SEM) studies and grain size was found to increase with Mn doping up to x=0.08 and then decreased. Dielectric measurement shows the decrease in peak transition temperature (TC) with Mn doping up to x=0.12 and then increase along with a sharp rise in dielectric maxima. A diffuse dielectric dispersion is observed in all the compositions. A detailed dispersion study was carried out using the Vogel-Fulcher empirical relation, a universal relaxation law and the Havriliak-Negami function. The Vogel-Fulcher relation fitting parameters of activation energy and freezing ...
The effect of the moisture content in amorphous polymers (PS, PVC, PMMA) on their electro-physical properties is considered. Analytical relationships describing the inflence of the external-field frequency and environmental relative humidity on the conductivity of the polymers are given. For the use of these polymers as active elements of moisture sensors, the moisture-resistive effect is estimated.
We test the evolution of the correlation between black hole mass and bulge velocity dispersion (M{sub BH} - {sigma}), using a carefully selected sample of 14 Seyfert 1 galaxies at z = 0.36 {+-} 0.01. We measure velocity dispersion from stellar absorption lines around Mgb (5175 {angstrom}) and Fe (5270 {angstrom}) using high S/N Keck spectra, and estimate black hole mass from the H{beta} line width and the optical luminosity at 5100 {angstrom}, based on the empirically calibrated photo-ionization method. We find a significant offset from the local relation, in the sense that velocity dispersions were smaller for given black hole masses at z = 0.36 than locally. We investigate various sources of systematic uncertainties and find that those cannot account for the observed offset. The measured offset is {Delta} log M{sub BH} = 0.62 {+-} 0.10 {+-} 0.25, i.e. {Delta} log {sigma} = 0.15 {+-} 0.03 {+-} 0.06, where the error bars ...
The presynaptic Ca2+ signal, which triggers vesicle release, disperses to a broadly distributed residual [Ca2+] ([Ca2+]res) that plays an important...Full Text Available
Testing of barrier properties of insulating materials against radon is usually based on the measurement of the radon diffusion coefficient. Presented report summarizes results of radon diffusion coefficients measurements in more than 120 insulating materials obtained throughout Europe. All measurements were performed by the Czech Technical University, Faculty of Civil Engineering in cooperation with the Radiation Protection Institute. We have found out that great differences exist in diffusion properties, because the diffusion coefficients vary within eight orders from 10"-"1"5 m"2/s to 10"-"8 m"2/s. For each material category of different chemical composition statistical evaluation of results is presented. Possibilities of usage of the radon diffusion coefficient for the design of radon resisting membranes are discussed. Based on the experience from the Czech Republic the paper is trying to show that ...
This work reports an alternative methodology for the linear attenuation coefficient determination ({mu} {rho}) of irregular form samples, in such a way that is not necessary to consider the sample thickness. With this methodology, indigenous archaeological ceramics fragments from the region of Londrina, north of Parana, were studied. These ceramics fragments belong to the Kaingaing and Tupiguarani traditions. The equation for the {mu} {rho} determination employing the two mean method was obtained and it was used for {mu} {rho} determination by the gamma ray beam attenuation if immersed ceramics, by turns, in two different means with known linear attenuation coefficient. By the other side, {mu} theoretical value was determined with the XCOM computer code. This code uses as input the ceramics chemistry composition and provides an energy versus mass attenuation coefficient table. In order to validate the two mean method ...
The aim of this study is to clarify the radon behavior in the soil at the waste rock yards of uranium mine. We have developed an apparatus for measuring radon diffusion coefficient in soil under the control of soil temperature. The radon diffusion coefficients changed suddenly around the soil temperature of 0degC. The radon diffusion coefficients in dry soil have little temperature dependency, and were comparable coefficients obtained by empirical formula of Rogers and Nielson. To study the restraint effect of radon exhalation by covering with bentonite on soil, we carried out the measurements and the calculations by using one-dimensional transport model of atmosphere and soil. The decrease of radon exhalation rate was 2.9 Bq m"-"2s"-"1 when soil covered with the bentonite of 5 cm thick. The radon concentrations in snow cover and the radon flux from the snow surface were measured at the waste rock yard ...
Cylindrical test pieces of concrete are used for measurements of "2"2"2Rn exhalation rates. Except one flat end surface of a test piece, other parts of its exteriority are covered with sealant. Radon atoms can escape only through its end surface from the interior into the outside air. This treatment makes the radon transport in the concrete one dimensional phenomena. The piece is put in an airtight container. Time variations of radon concentrations in the air of the container are measured with a plane multiwire-electrode ionization chamber. From this result, the radon areal exhalation rate is deduced for the piece. Exhalation rates are measured for four pieces with different length. Then, the diffusion coefficient is obtained for radon in the concrete as (5.0 #+-# 1.0) x 10"-"8m"2s"-"1 (a one-block method). A two-block method has been invented to obtain simultaneously values of three parameters: diffusion coefficient, porosity of concrete, and ...
Some of the results of property measurements of CeO{sub 2} and its solid solutions were reviewed. The deviation from stoichiometry of undoped and doped CeO{sub 2} was presented in several figures, which suggested that CeO{sub 2} fired at high temperatures in air might be nonstoichiometric in some degree. At low temperatures, the deviation from stoichiometry in doped CeO{sub 2} is higher than undoped CeO{sub 2}. As another interesting property, CeO{sub 2} shows high solubility to trivalent cations such as rare earth elements. A possible reason behind this high solubility was presented. The nonstoichiometric defect in undoped CeO{sub 2} and the trivalent cation in solid solution with CeO{sub 2} have to be compensated by other defects. The possible defect structures in this solid solution were reviewed and the most probable structure was chosen based on density measurement and impurity dependence of oxygen diffusion coefficient. Finally the oxygen diffusion ...
A laser resonance absorption spectrometer is used to investigate the characteristics of both self and nitrogen collision broadened carbon dioxide in resonance with He--Ne laser radiation at 4.2 ..mu..m. The absorption coefficient in these broadening conditions has contributions from the R(28) to R(34) absorption lines of the ..nu../sub 3/ CO/sub 2/ spectrum. The Fletcher-Powell optimization method is used to reduce the raw absorption data and to find the best value average collision broadening coefficient and laser emission frequency for a Lorentzian line shape model of the contributing lines. Pure carbon dioxide absorption in a pressure range of from 0.0016 atm (1.25 Torr) to 0.33 atm (250 Torr) is described well by the model with an average self broadening coefficient of 0.084 +- 0.008 cm/sup -1/ atm/sup -1/ for laser frequencies located at either 2370.591 +- 0.020 cm/sup -1/ or 2371.135 +- 0.019 cm/sup -1/. Nitrogen ...
The mathematical calculation to obtain a radon diffusion coefficient from measured radon transient-diffusion data is usually done by fitting a difference equation to the data. The difference equation is obtained through transformation of the time-dependent diffusion equation based on Fick's law. But, actual measured transient-diffusion data often have much scatter. Therefore just fitting over the whole range of the measured data through the method of least squares may not always be valid, because the method offers mathematical interpretation rather than a physical one. Instead, the actual radon diffusion coefficients must be otherwise obtainable from measured radon transient data. Taking this viewpoint, the present paper claims that about a 90% leveling-off time is often easily discernible regardless of the shape of the radon transient curve obtained from the measured data and it can be a decisive factor for determining the radon diffusion ...
Six illitized samples from drillhole OL-KR12 in Olkiluoto were analyzed by helium gas methods for their diffusion coefficient, permeability and porosity. The diffusion coefficients measured varied in the range 2.1 x 10-10 - 3.5 x 10-8 m2/s, permeabilities in the range 6 x 10-21 - 5.8 x 10-16 m2, and porosities in the range 0.2 6.2%. Variations observed in these quantities were concluded to arise from the heterogeneous structure of the sample rock. A 4 mm x 4 mm x 4 mm subsample was sawed from each of the six samples for structural analysis by x-ray microtomography. The three-dimensional structure of tomographic reconstructions, and thereby that of the samples themselves, was analyzed visually, which confirmed their heterogeneity. Samples represent altered rock whose structure and thereby transport properties vary significantly depending on the local alteration history of the rock. (orig.)
The sensitivity analysis summarized in this paper was made to determine the parameters of greatest influence in the prediction of radon barrier cover thickness for the stabilization of uranium mill tailings piles. Such information provides the basis for setting priorities and levels of effort for data collection, and improves knowledge of the sources of uncertainty in the calculation of cover thickness. In the context of this paper, the influence of a parameter on cover thickness incorporates two effects: (1) the sensitivity of the mathematical formulation to changes in a parameter's value, and (2) the range of values that a parameter may take on under site-specific conditions. Of the several parameters that are used in the calculations, the most influential are cover moisture content, cover radon diffusion coefficient, tailings radium concentration and tailings radon emanating fraction, in order of decreasing relative influence. Less influential parameters for ...
Purpose: calculation of conversion coefficients for the reconstruction of organ doses from entrance doses for abdomen radiographs of 0, 1, 5, 10, 15, and 30-year-old patients in conventional pediatric radiology for the radiographic settings recommended by the German and European guidelines for quality management in diagnostic radiology. Materials und method: using the commercially available personal computer program PCXMC developed by the Finnish Center for Radiation and Nuclear Safety (Saeteilyturvakeskus STUK), conversion coefficients for conventional abdomen radiographs were calculated performing Monte Carlo simulations in mathematical hermaphrodite phantom models describing patients of different ages. The possible clinical variation of beam collimation was taken into consideration by defining optimal and suboptimal radiation fields on the phantoms' surfaces. Results: conversion coefficients for the ...
One of the main goals in the determination of three-dimensional macromolecular structures from electron microscope images of individual molecules and complexes (single particles) is a sufficiently high spatial resolution, about 4 A, at which the interpretation with an atomic model becomes possible. To reach high resolution, an iterative refinement procedure using an expectation maximization algorithm is often used that leads to a more accurate alignment of the positional and orientational parameters for each particle. We show here the results of refinement algorithms that use a phase residual, a linear correlation coefficient, or a weighted correlation coefficient to align individual particles. The algorithms were applied to computer-generated data sets that contained projections from model structures, as well as noise. The algorithms show different degrees of over-fitting, especially at high resolution where the signal is weak. We demonstrate ...
The adverse effect of moisture diffusion on the properties of wood has been one of the main weaknesses of wood. Using a gamma irradiation method, wood-polymer composites have been produced which exhibit significant improvement in mechanical properties like compression, creep deformation and creep rupture particularly at high humidity. It has been thought that the impregnation of polymer into the wood has affected the moisture diffusion in the wood, so that its adverse effects on the mechanical properties has been reduced. In this report the apparent diffusion coefficients of a Ramin wood impregnated with varying amounts of polymethyl methacrylate (PMMA) were determined using a Fick's law approach. An initial linear relationship was found for impregnation of up to 70% PMMA, after which the diffusion coefficient levels off to a maximum value, for the three environmental relative humidity levels of 40, 60 and 90({plus minus}5)%. The ...
The adverse effect of moisture diffusion on the properties of wood has been one of the main weaknesses of wood. Using a gamma irradiation method, wood-polymer composites have been produced which exhibit significant improvement in mechanical properties like compression, creep deformation and creep rupture particularly at high humidity. It has been thought that the impregnation of polymer into the wood has affected the moisture diffusion in the wood, so that its adverse effects on the mechanical properties has been reduced. In this report the apparent diffusion coefficients of a Ramin wood impregnated with varying amounts of polymethyl methacrylate (PMMA) were determined using a Fick's law approach. An initial linear relationship was found for impregnation of up to 70% PMMA, after which the diffusion coefficient levels off to a maximum value, for the three environmental relative humidity levels of 40, 60 and 90(#+-#5)%. The phenomenon could be ...
Minority-carrier lifetime damage coefficients for 1 MeV electron, 3 MeV proton, and 6 MeV alpha particle irradiation of n-type (4.5{times}10{sup 15} and 1.3{times}10{sup 17}cm{sup {minus}3}) and p-type (2.5{times}10{sup 17}cm{sup {minus}3}) InP have been measured using time-resolved photoluminescence. These values are relatively insensitive to carrier type and show a slight increase with increasing carrier concentration. Evidence of comparable electron and hole capture lifetimes is found for the dominant recombination defect. The effect of 3 MeV proton and 6 MeV alpha particles relative to 1 MeV electrons is an increase in the lifetime damage coefficient by factors of about 10{sup 4} and 10{sup 5}, respectively. {copyright} {ital 1997 American Institute of Physics.}
Engineering materials for use in low heat rejection engines are required to function under stringent tribological conditions. Severe wear damage and high friction between the components of the tribosystem limit the number of potential materials suitable for such application conditions. The superalloys X-750 and 188 are composed of alloying elements that not only promote a high mechanical and chemical stability but may also result in a reduced wear rate and friction coefficient at elevated temperatures. As a part of the DOE-ECUT Tribology program at Argonne, the present study was undertaken to evaluate the tribological characteristics of these alloys that will also be utilized as the substrates for ion beam deposited lubricous coatings. A wear test rig that crudely simulated the sliding conditions between a piston ring and a cylinder liner in an operating engine was utilized for friction and wear studies. The test results indicated that the wear and friction ...
High-performance heat transfer augmentation methods applicable in the forced convection field of heat exchangers include a method which requires no external drive means, such as the insertion of a turbulence augmentation object into the flow passage and the use of a wave-shaped flow passage, but disturbs the main stream of flow to raise the heat transportation effect thereby to augment heat transfer in the flow passage. The heat transfer characteristics and thermal performance ratio achieved when sinusoidal-shape plates are inserted instead of augmentation objects, such as cylinders, with a high shape-induced resistance were studied. As a result, the relationship between the resistance coefficient, average Nusselt number, heat transfer coefficient, and pitch was clarified. It has been revealed that the use of eddies with a large gap flow and recirculation area should be considered in order to get a higher heat transfer ...
The calculation of nominal choke valve size determines the effective capacity for an oil and gas production system. The degree of restriction for the controlling area in the valve is a function of the surrounding geometry. In an orifice plate this is known as the 'velocity of approach' and can be used to determine the meter coefficient (C_m). This paper presents a technique for choke valves, based on the meter velocity of approach parameter, which can be used to predict the Valve Coefficient (C_v) for new trim designs. The prediction method uses a data trend based on a number of flow tests conducted on various trim characteristics. The resultant parametric equation is used to predict the C_v of a new trim geometry. The method relies on experimental data determined per IEC 60534-2-3, with calculations per IEC 60534-2-1. This paper further investigates the effect of varying upstream geometry on C_v for a 4'' nominal valve.
The diffusion of linalool and methylchavicol from thin (45-50 mm) antimicrobial low-density polyethylene-based films was evaluated after immersion in isooctane and the effect of temperature (4, 10, or 25 degreeC) on the diffusion rate was evaluated. The kinetics of linalool and methylchavicol release showed a non-Fickian behavior at the lowest temperature. An increase in temperature from 4 degreeC to 25 degreeC resulted in an increase in the diffusion coefficient from 4.2 x 10-13 m2 s-1 to 2.5 x 10-12 m2 s-1 for linalool and from 3.5 x 10-13 m2 s-1 to 1.1 x 10-12 m2 s-1 for methylchavicol. The effect of temperature on the diffusion coefficient followed an Arrhenius-type model (r2 = 0.972) in relation to a time-response function with a Hill coefficient. Activation energies of 57.8 kJ mol-1 ...
This paper presents direct measurements of the aerodynamic forces on the wing of a free-flying, insect-like ornithopter that was modeled on a hawk moth (Manduca sexta). A micro differential pressure sensor was fabricated with micro electro mechanical systems (MEMS) technology and attached to the wing of the ornithopter. The sensor chip was less than 0.1% of the wing area. The mass of the sensor chip was 2.0 mg, which was less than 1% of the wing mass. Thus, the sensor was both small and light in comparison with the wing, resulting in a measurement system that had a minimal impact on the aerodynamics of the wing. With this sensor, the 'pressure coefficient' of the ornithopter wing was measured during both steady airflow and actual free flight. The maximum pressure coefficient observed for steady airflow conditions was 1.4 at an angle of attack of 30"0. In flapping flight, the coefficient was around 2.0 for angles of attack ...
The objective was to study the interaction of a side jet with the incoming supersonic flow and hypersonic flow. Qualitatively same Cp trends have been obtained as found experimentally. Also in aerodynamic coefficients side jet interaction results in additional pitching moment which is because of the high pressure region in upstream of the jet and a low pressure region in the downstream of the jet. Also jet interaction results in the rise in the lift coefficient. Whereas in the incidence case, simulation has been performed for the hypersonic flows over a biconic body with supersonic lateral jet at Mach 9.7 and incidence of 0"o to incidence of -12"o and 12"o. The results obtained were compared with the experimental and CFD code CFL3D results. PAK-3D over predicts the surface pressure as compared to the CFL3D and experimental results, whereas the qualitative trends are the same. Finally the integrated aerodynamic force ...
The authors discuss a two-phase two-component experimental system developed to study enhancement of heat transfer from a vertical chip size heater to surrounding liquid (Freon 113 or Ethanol) due to air jet impingement. Heat transfer coefficient was measured as function of jet velocity, heat flux and the distance between exit of jet tube and heated surface. The injector was placed very close to the hot surface. It was found that the heat transfer was notably enhanced with foreign gas impingement, especially in the cases of small temperature differences between wall and coolant. In fact for higher jet velocities the heat transfer coefficients tended to infinite while the temperature differences between wall and coolant were zero. The heat transfer coefficients decreased with the increasing of heat flux. High-speed camera was used to study the behaviour of the gas bubbles which play very important role in the heat transfer ...
Transition joints in power plants between ferritic steels and austenitic stainless steels suffer from a mismatch in coefficients of thermal expansion (CTE) and the migration of carbon during service from the ferritic to the austenitic steel. To overcome these, nickel-based consumables are commonly used. The use of a trimetallic combination with an insert piece of intermediate CTE provides for a more effective lowering of thermal stresses. The current work envisages a trimetallic joint involving modified 9Cr-1Mo steel and 316LN austenitic stainless steel as the base materials and Alloy 800 as the intermediate piece. Of the two joints involved, this paper describes the choice of welding consumables for the joint between Alloy 800 and 316LN. Four consumables were examined: 316, 16-8-2, Inconel 82 and Inconel 182. The comparative evaluation was based on hot cracking tests and estimation of mechanical properties and coefficient of thermal expansion. ...
The unsteady aerodynamic forces of a model fruit fly wing in flapping motion were investigated by numerically solving the Navier-Stokes equations. The flapping motion consisted of translation and rotation [the translation velocity (u(t)) varied according to the simple harmonic function (SHF), and the rotation was confined to a short period around stroke reversal]. First, it was shown that for a wing of given geometry with u(t) varying as the SHF, the aerodynamic force coefficients depended only on five non-dimensional parameters, i.e. Reynolds number (Re), stroke amplitude (Phi), mid-stroke angle of attack (alpha(m)), non-dimensional duration of wing rotation (Delta tau(r)) and rotation timing [the mean translation velocity at radius of the second moment of wing area (U), the mean chord length (c) and c/U were used as reference velocity, length and time, respectively]. Next, the force coefficients were investigated for a case in which typical ...
Quark Gluon Plasma transport coefficients for heavy quarks and quark-antiquark pairs are computed through an extension of the results obtained for a hot QED plasma by describing the heavy-quark propagation in the eikonal approximation and by weighting the gauge field configurations with the Hard Thermal Loop effective action. It is shown that such a model allows to correctly reproduce, at leading logarithmic accuracy, the results obtained by other independent approaches. The results are then inserted into a relativistic Langevin equation allowing to follow the evolution of the heavy-quark momentum spectra. Our numerical findings are also compared with the ones obtained in a strongly-coupled scenario, namely with the transport coefficients predicted (though with some limitations and ambiguities) by the AdS/CFT correspondence.
The Ludwig-Soret effect, the migration of a species due to a temperature gradient, has been extensively studied without a complete picture of its cause emerging. Here we investigate the dynamics of DNA and spherical particles sub jected to a thermal gradient using a combination of Brownian dynamics and the lattice Boltzmann method. We observe that the DNA molecules will migrate to colder regions of the channel, an observation also made in the experiments of Duhr, et al[1]. In fact, the thermal diffusion coefficient found agrees quantitatively with the experimental value. We also observe that the thermal diffusion coefficient decreases as the radius of the studied spherical particles increases. Furthermore, we observe that the thermal fluctuations-fluid momentum flux coupling induces a gradient in the stress which leads to thermal migration in both systems.
The experimental survey about the heat transfer between the working fluid and the combustion chamber wall with a direct injection diesel engine has shown the production of a soot layer with increasing loads on the combustion chamber wall. Because the combustion process of methanol occurs without the formation of wall deposits, the same engine spark ignitioned with methanol at the same conditions has shown a higher heat transfer coefficient. Because the heat losses do not only depend on the heat transfer coefficient but also on the driving temperature difference between the working fluid and the combustion chamber wall, the methanol engine with corresponding process management showed lower heat losses than the diesel engine at nearly the same load. (orig./HW)
The structural, electronic and optical properties of ZnX and CdX (X = Se, Te and S) are studied using density functional theory by the Wien2k package. The energy band gap, real and imaginary parts of the dielectric function, energy loss function, optical absorption coefficient and reflectivity spectra of these compounds are calculated. The Engel-Vosko approach improves the energy band gaps of ZnX and CdX compounds. The calculated optical parameters are in good agreement with available experimental results, particularly in the Engel-Vosko approach. Furthermore the effect of hydrostatic pressure on the energy band gap, the real and imaginary parts of the dielectric function of these compounds is studied. The first and second order pressure coefficient for the energy band gaps, the static dielectric function and the static reflectivity spectra are calculated.
Reliability analysis is now being used to a large extent for several civil engineering structures. Such analysis has not been used for rockfill dams, the most common dams in Norway. Following work on reliability analysis for breakwaters, reliability analysis was then used to investigate the ability of the stone material on the upstream face of a rockfill dam to withstand wind generated waves. An attempt is made to follow up this work by including discharge overtopping on a rockfill dam in a reliability analysis. This report primarily goes through previous work on the required weight of protective stones on the downstream face of the dam for specified discharges over the dam and also deals with the probability formulation of extreme floods. A failure function with partial coefficients is formulated. But for reasons of economy the calibration of the partial coefficients remains for a next phase of the project. 14 refs., 17 figs.
This study is an attempt to measure the quantities of elements in a composite by irradiating that composite with #gamma#-rays of various energies and detecting the transmitted radiation through the composite. A previous knowledge of the number of the elements and their attenuation coefficients is required. The quantities are calculated by solving the matrix of a linear system of equations. A computer program was developed to select the best combinations of the available energies. Five criteria were established to determine these energy combinations: (i) the determinant of the attenuation coefficient matrix; (ii) the condition number, (iii) the number of times the solution of the matrix leads to acceptable results; (iv) the indicator, (a new concept); (v) the standard deviations of the results. The intended application of this technique in medicine is to measure the bone mineral content of the skeleton. An examination of the error propagation, ...
Abstract In this paper, a new predictive model that can forecast the performance of a vertical axis wind turbine (VAWT) is presented. The new model includes four primary variables (rotor velocity, wind velocity, air density, and turbine power output) as well as five geometrical variables (rotor radius, turbine height, turbine width, stator spacing, and stator angle). These variables are reduced to include the power coefficient (Cp) and tip speed ratio (TSR). A power coefficient correlation for a novel VAWT (called a Zephyr Vertical axis Wind Turbine (ZVWT)) is developed. The turbine is an adaptation of the Savonius design. The new correlation can predict the turbine's performance for altered stator geometry and varying operating conditions. Numerical simulations with a rotating reference f...
The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.
In this paper, numerical simulation of a concentric tube heat exchanger is presented to determine the convective heat transfer coefficient and friction factor in a smooth tube. Increasing the convective heat transfer coefficient can increase heat transfer rate in a concentric tube heat exchanger from a given tubular surface area. This can be achieved by using heat transfer augmentation devices. This work constitutes the initial phase of the numerical simulation of heat transfer from tubes employing augmentation devices, such as twisted tapes, wire-coil inserts, for heat transfer enhancement. A computational fluid dynamics (CFD) simulation tool was developed with CFX software and the results obtained from the simulations are validated with the empirical correlations for a smooth tube heat exchanger. The difficulties associated with the simulation of a heat exchanger augmented with wire-coil inserts are discussed. (author)
A microcosm laboratory experiment was conducted to determine the impact of biological reworking by the ragworm Nereis diversicolor on the redistribution of particle-bound radionuclides deposited at the sediment-water interface. Over the course of the 40-day experiment, as much as 35% of a 137Cs-labelled particulate tracer deposited on the sediment surface was redistributed to depths of up to 11 cm by the polychaete. Three different reworking models were employed to model the profiles and quantify the biodiffusion and biotransport coefficients: a gallery-diffuser model, a continuous sub-surface egestion model and a biodiffusion model. Although the biodiffusion coefficients obtained for each model were quite similar, the continuous sub-surface egestion model provided the best fit to the data...
The Sputter coefficient of accelerated CO{sub 2} cluster ions hitting surfaces of various materials is investigated. For copper it varies proportional to the 2nd power of the energy between 155 and 260 keV. The rate of erosion for different target materials varies by two orders of magnitude from tungsten to PMMA. Diamond is eroded fairly quickly, while aluminum is eroded less than corundum (Al{sub 2}O{sub 3}). No simple correlation of the sputter coefficient on the bulk material properties is found. For copper the angular distribution of sputtered material is measured and found to be following roughly a cosine distribution. By using masks different microstructures have been produced in cobalt-samarium magnets, diamond and glass. (orig.)
Measurements of {gamma}-ray, {gamma}{gamma}-coincidence and internal conversion electron spectra from the {sup 106}Cd({alpha},n{gamma}){sup 109}Sn reaction were carried out at 15-20 MeV {alpha}-particle bombarding energies with Ge(HP) {gamma}-ray and superconducting magnetic lens plus Si(Li) electron spectrometers. The energies, relative intensities, internal conversion coefficients and coincidence relations of the {sup 109}Sn transitions were determined, and a more complete, consistent level scheme has been deduced. Spin and parity values have been determined from the internal conversion coefficients, the bombarding-energy dependence of the side-feeding intensities of the states and the available {gamma}-ray angular distribution data. The level scheme was interpreted in the framework of the quasi-particle shell model.
The local heat transfer coefficient distribution of a square channel with two opposite ribbed walls was determined. The square channel was connected to a sudden contraction entrance in order to simulate the inlet condition of the turbine blade cooling passages. The test channel was heated by thin stainless steel foils with a thickness of 0.000025 m, and instrumented with 180 thermocouples. The brass ribs of a square cross-section were glued periodically, in line, onto the top and bottom walls of the foil-heated channel in patterns to achieve the desired spacing and angle-of-attack. The local heat transfer coefficients on the smooth side and the ribbed side walls, at the channel entrance and the downstream regions, were measured for eight rib configurations and three Reynolds numbers (Re = 10,000, 30,000, and 60,000).
This paper discusses the link between R&D and productivity across the European industrial and service sectors. The empirical analysis is based on both the European sectoral OECD data and on a unique micro-longitudinal database consisting of 532 top European R&D investors. The main conclusions are as follows. First, the R&D stock has a significant positive impact on labor productivity; this general result is largely consistent with previous literature in terms of the sign, the significance, and the magnitude of the estimated coefficients. More interestingly, both at sectoral and firm levels the R&D coefficient increases monotonically (both in significance and magnitude) when we move from the low-tech to the medium- and high-tech sectors. This outcome means that corporate R&D investment is m...
The US NRC, in its Generic Environmental Impact Statement on uranium milling has specified that the radon flux escaping a uranium mill tailings pile will be reduced to pCi/m/sup 2/ s by application of covering layers of soils and clays. These covers present a radon diffusion barrier, which sufficiently increases the time required for radon passage from the tailings to the atmosphere to allow for decay of /sup 222/Rn within the cover. The depth of cover necessary to reduce the escaping radon flux to the prescribed level is to be determined by calculation, and requires precise knowledge of the radon diffusion coefficient in the covering media. A Radon Attenuation Test Facility was developed to determine rates of radon diffusion through candidate cover materials. This paper describes this facility and its application for determining the influence of physical properties of the soil column on the radon diffusion coefficient.
Absorption spectra of the visible I_2 band of I_2 complexes with Et_2O, Et_2S, and Et_2Se in heptane have been measured up to 3300 bar at 25"0C. The equilibrium constants and volume changes accompanying complex formation, the molar extinction coefficients and the absorption maxima have been estimated. The volume changes were found comparable with those estimated from the X-ray data of the I_2 complexes in the crystalline state. The enhancement of the molar extinction coefficient and the blue shift of the visible I_2 band with increasing pressure have been established. The results suggest a decrease in the bond distance between an n-donor and I_2, compared with the spectroscopic properties of the I_2 complex at 1 bar. The decrease has been estimated as 0.008 nm with increasing pressure up to 3300 bar. (author).
In this paper, the moisture buffering capacity of spruce plywood is measured by recording the change in mass of a test specimen when the air relative humidity (RH) is changed between 33% RH and 75% RH. The aim is to represent diurnal cycles in indoor humidity with 33% RH maintained for 16 h and 75% RH maintained for 8 h. Measurements are taken using two different apparatuses, which provide different convective transfer coefficients between the air and the plywood, and the results are compared to a numerical model for validation. The validated numerical model is then used to investigate the effect of initial conditions, boundary conditions and thickness on the moisture buffering capacity of plywood. The results show that the buffering capacity of plywood depends on the initial conditions and thickness of the plywood as well as the surface film coefficient and humidity cycle. (author)
Experiments have been performed to study the usefulness of several types of plastic foils as filter to separate radon and thoron. Time-integrated alpha-activity measurements have been carried out by using the so-called ''can-technique'' equipped with both LR-115 and CR-39 track detectors. The track density observed on the detectors, taken as a measure of radon activity concentration, has been determined as a function of the thickness of filter foils. The radon permeability and the thoron separation factors have been determined. It is shown that various plastic foils exhibit considerable differences in radon diffusion coefficient owing to their different chemical structures. Among the plastic foils investigated the polyethylene proved to have the highest gas diffusion coefficient.
Unitarity cuts are widely used in analytic computation of loop amplitudes in gauge theories such as QCD. We expand upon the technique introduced in hep-ph/0503132 to carry out any finite unitarity cut integral. This technique naturally separates the contributions of bubble, triangle and box integrals in one-loop amplitudes and is not constrained to any particular helicity configurations. Loop momentum integration is reduced to a sequence of algebraic operations. We discuss the extraction of the residues at higher-order poles. Additionally, we offer concise algebraic formulas for expressing coefficients of three-mass triangle integrals. As an application, we compute all remaining coefficients of bubble and triangle integrals for nonsupersymmetric six-gluon amplitudes.
A nonlinear free boundary-value problem of supercavitating flow past n + 1 hydrofoils is analyzed. To describe the cavities' closure mechanism, the Tulin-Terentev single-spiral-vortex model is employed. The flow domain is considered as the image of an (n + 1)-connected circular domain. The conformal map is constructed in terms of the solutions to two Riemann-Hilbert problems of the theory of symmetric automorphic functions. One of the problems is homogeneous and its coefficients are continuous functions while the second problem is inhomogeneous and has discontinuous coefficients. The exact solutions to the problems are found by using quasiautomorphic and quasimultiplicative analogs of the Cauchy kernel. The case of a single plate is considered in detail and the numerical results are report...
Mitsubishi is developing a new type of accumulator incorporating the technology of fluidics as one of the seeds for the improved safety of the newly constructed pressurized water reactor plants. This accumulator employs a vortex flow control device, called a vortex damper, as a fluidic device to simplify the safety systems. A fundamental experimental study with a one-fifth scale model and confirmation tests with a one-third scale model to develop the vortex damper have been carried out, and satisfactory results have been achieved. The results of the confirmation tests under the prototype pressure conditions agree well with the basic tests. The flow rate ratio can be 5 to 6. The pressure loss coefficient in the large flow rate period is 8. A cavitation factor is the main parameter of the flow rate coefficient.
Real-time object detection is one of the core problems in computer vision. The cascade boosting framework proposed by Viola and Jones has become the standard for this problem. In this framework, the learning goal for each node is asymmetric, which is required to achieve a high detection rate and a moderate false positive rate. We develop new boosting algorithms to address this asymmetric learning problem. We show that our methods explicitly optimize asymmetric loss objectives in a totally corrective fashion. The methods are totally corrective in the sense that the coefficients of all selected weak classifiers are updated at each iteration. In contract, conventional boosting like AdaBoost is stage-wise in that only the current weak classifier's coefficient is updated. At the heart of the totally corrective boosting is the column generation technique. Experiments on face detection show that our methods outperform the state-of-the-art asymmetric ...
We present an empirical model for periodic variations of diurnal and sub-diurnal Earth rotation parameters (ERPs) that was derived based on the transformation of normal equation (NEQ) systems of Very Long Baseline Interferometry (VLBI) observing sessions. NEQ systems that contain highly resolved polar motion and UT1-TAI with a temporal resolution of 15?min were generated and then transformed to the coefficients of the tidal ERP model to be solved for. To investigate the quality of this model, comparisons with empirical models from the Global Positioning System (GPS), another VLBI model and the model adopted by the conventions of the International Earth Rotation and Reference Systems Service (IERS) were performed. The absolute coefficients of these models agree almost completely within 7.5?...
Individual photophysical parameters of the chromophore of a fluorescent protein mRFP1 and its two mutants (amino-acid substitution at position 66 - mRFP1/ Q66C and mRFP1/Q66S proteins) are determined. For this purpose, apart from conventional methods of fluorimetry and spectrophotometry, nonlinear laser fluorimetry is used. It is shown that the individual extinction coefficients of the chromophore of proteins correlate (correlation coefficient above 0.9) with the volume of the substituted amino-acid residue at position 66 (similar to the positions of the absorption, fluorescence excitation and emission maxima). (laser biology and medicine)
Arsenic and hydrogen ions produced from a mixture of arsine and hydrogen gas were implanted with a dose of 3 x 10{sup 15} As{sup +} ions/cm{sup 2} into silicon using an ion-shower implanter. The dominant ionic species implanted into the silicon were As{sub 2}H{sup +}, AsH{sup +}, H{sub 5}{sup +}, and H{sub 3}{sup +} ions. Arsenic atoms diffused into the silicon with large diffusion coefficients during annealing at 700 and 800 C. However, when the implanted silicon was annealed at 900 C, the arsenic atoms diffused into a deeper region in the silicon with a very small diffusion coefficient that was independent of concentration. (Abstract Copyright [2003], Wiley Periodicals, Inc.)
A thermal analysis of the Omnium-G receiver is presented and the technique is shown to be generally applicable to solar thermal receivers utilizing a directly heated thermal mass. The thermal loss coefficient, including reradiation losses, is calculated and shown to agree quite well with the experimentally measured thermal loss coefficient. The rate of heat transfer to the working fluid is also analyzed and the analysis is used to show that the Omnium-G receiver is well matched to the water/steam working fluid because the steam outlet temperature is almost the same as the receiver temperature. A general procedure for calculating receiver performance is presented. With this procedure, the energy delivery to any working fluid, the delivered temperature of the working fluid, and the pressure drop through the receiver can be determined. An example of the calculation is also presented.
The widespread use of building materials with relatively high radium concentrations may increase population exposure. A method is presented for measuring effective diffusion coefficients and exhalation rates of radon from such materials. Equations for use in the experimental determination of these values are obtained theoretically. The experimental set-up consists of a container which is hermetically sealed to a slab of the building material. Nitrogen is blown through the container and then through an ionization chamber which is connected to an electrometer and X-Y plotter, and the radon concentration is measured continuously. Exhalation rates of radon from some major building materials measured by this method will be used as reference levels. The method can also be used to determine other properties such as porosity. (author).
In this study, the degrees of destruction of hemoglobin irradiated in atmospheres of air and argon were compared. Hemoglobin preparations were irradiated in the forms: oxyhemoglobin (HbO_2) deoxyhemoglobin (Hb"2"+) and methemoglobin (MetHb) applying doses of 0.5 to 5 Mrad. The degree of hemoglobin destruction was estimate on the basis of changes in the values of the absorption coefficient at the Soret band, the absorption ratio A_5_0_5/A_5_6_3 determined after conversion of irradiated preparations into MetHb, absorption coefficinets for pyridine hemochromogen obtained from irradiated preparations, and changes in parameters characterizing the hemoglobin oxygenation reaction (log p/sub 1/2/O_2 and the Hill n coefficient). The calculated oxygen enhancement ratios S were generally higher than 1 for the parameters estimated. This indicates that the presence of oxygen during irradiation enhances hemoglobin destruction.
For the first time, rheological phase method, a simple and effective route, is applied to synthesize novel cathode material LiCoPO{sub 4}. X-ray diffraction spectrometer (XRD), X-ray photoelectron spectrometer (XPS), transmission electron microscope (TEM) and electrochemical impedance spectroscopy (EIS) are taken to investigate this material, respectively. XRD figure shows that the rheological sample is better crystallized than the solid-state one. XPS result of the rheological sample exhibits that the valence of Co is 2+. TEM images show that better dispersed particles with smaller size can be formed by rheological method comparing to the solid-state route. Charge-discharge test is carried out in the range of 3.0-5.0 V at 0.2 mA cm{sup -2}. The initial discharge capacity for rheological phase and solid-state powder is 71.5 and 30.9 mAh g{sup -1}, respectively. The better electrochemical property should be ascribed to the better crystallized rheological phase ...
For the first time, rheological phase method, a simple and effective route, is applied to synthesize novel cathode material LiCoPO4. X-ray diffraction spectrometer (XRD), X-ray photoelectron spectrometer (XPS), transmission electron microscope (TEM) and electrochemical impedance spectroscopy (EIS) are taken to investigate this material, respectively. XRD figure shows that the rheological sample is better crystallized than the solid-state one. XPS result of the rheological sample exhibits that the valence of Co is 2+. TEM images show that better dispersed particles with smaller size can be formed by rheological method comparing to the solid-state route. Charge-discharge test is carried out in the range of 3.0-5.0 V at 0.2 mA cm-2. The initial discharge capacity for rheological phase and solid-state powder is 71.5 and 30.9 mAh g-1, respectively. The better electrochemical property should be ascribed to the better crystallized rheological phase production with better ...
The stellar disc kinematics in a sample of fifteen intermediate- to late-type edge-on spiral galaxies are studied using a dynamical modeling technique. The sample covers a substantial range in maximum rotation velocity and deprojected face-on surface brightness and contains seven spirals with either a boxy- or peanut-shaped bulge. Dynamical models of the stellar discs are constructed using the disc structure from $I$-band surface photometry and rotation curves observed in the gas. The differences in the line-of-sight stellar kinematics between the models and absorption line spectroscopy are minimized using a least-squares approach. The modeling constrains the disc surface density and stellar radial velocity dispersion at a fiducial radius through the free parameter $\\sqrt{M/L}$ $(\\sigma_{\\rm z}/\\sigma_{\\rm R})^{-1}$, where $\\sigma_{\\rm z}/\\sigma_{\\rm R}$ is the ratio of vertical and radial velocity dispersion and $M/L$ the disc ...
TaC-4wt.% CNT composites were synthesized using spark plasma sintering. Two kinds of CNTs, having long (10-20mm) and short (1-3mm) length, were dispersed by wet chemistry and spray drying techniques respectively. Spark plasma sintering was carried out at 1850^oC at pressures of 100, 255 and 363MPa. Addition of CNTs leads to an increase in the density of 100MPa sample from 89% to 95%. Short CNTs are more effective in increasing the density of the composites whereas long CNTs are more effective grain growth inhibitors. The longer CNTs are more effective in increasing the fracture toughness and an increase up to 60% was observed for 363MPa sample. Hardness and elastic modulus are found to increase by 22% and 18% respectively for 100MPa samples by addition of long CNTs. Raman spectroscopy, SEM...
Petrographic research for the Nevada Nuclear Waste Storage Investigations focused on xenolithic variability in the Topopah Spring Member and on variations of clinoptilolite composition at Yucca Mountain. Zeolite and smectite occurrences were considered in terms of their relation to a disturbed zone beneath the potential repository, and mineral stability experiments have produced a new clinoptilolite structure as a result of prolonged heating at low temperature. Limitations were defined on the abundance of erionite and of sulfur. X-ray diffraction studies lead to improved analytical methods. Progress was made in the comparative study of mineralogy in sand ramps and in faults. Geological modeling considered the differences of the diffusion of nonsorbing tracers in vertically and in horizontally fractured rock. Modeling also treated the diffusion of a nonsorbing tracer in devitrified and in zeolitized rock. The results of these experiments in all cases show relatively symmetrical ...
Ceramics with composition Ba{sub 1-x}Na{sub x}Ti{sub 1-x}Nb{sub x}O{sub 3} are of either classical ferroelectric (for 0{<=}x<0.075) and ferro- or antiferroelectric (for 0.55<x{<=}1) or relaxor ferroelectric type (for 0.075{<=}x{<=}0.55), the transition at T{sub c} being only diffuse without any frequency dispersion for this last region. All the corresponding dielectric characteristics, i.e. diffusivity of the ferroelectric-paraelectric transition, frequency dispersion of {epsilon}{sub r}', shift of T{sub m} with frequency deviation from the Curie-Weiss law, are determined. The relaxor behaviour is more relaxor the more the composition deviates from BaTiO{sub 3} and NaNbO{sub 3}. This study is in the field of preparation of relaxor ceramics free from lead in the interest of the environment, which present a transition temperature close to room temperature. (author)
This work analyzes the unoptimized prototype triode-sputtered, 150 microns thick tantalum coatings deposited with a 2.5 microns niobium underlayer on the bore of a large-diameter A723 steel cylinder. The coating was deposited for wear and erosion protection by Pacific Northwest National Laboratory. The phase determination was based on X ray diffraction analysis, wavelength dispersive X ray fluorescence analysis, energy dispersive X ray analysis, and hardness and electrical resistivity measurements. Both X ray diffraction and radius-of- curvature methods were used to determine residual stresses. A locally developed high-resolution pole figure technique was used to perform texture analysis. The post-firing, debonded coating showed alpha-tantalum, preferred 110 orientation, high surface stresses, tantalum oxides, entrapped krypton sputtering gas, interstitial oxygen, and other impurities. The surface and subsurface pole figures revealed broadened ...
The reactions between (100) GaAs and the near-noble metals Ni, Pd, and Pt have been investigated by application of high-resolution transmission electron microscopy (TEM), energy-dispersive analysis of x rays in the scanning TEM and Rutherford backscattering spectrometry. Emphasis is placed on the evolution of the phase distributions, film compositions, and interface morphologies during annealing at temperatures up to 480 /sup 0/C. The first phase in the Ni/GaAs reaction is shown to have the nominal composition Ni/sub 3/GaAs. Ternary phases of the type Pd/sub x/GaAs are also found to be the dominant products of the Pd/GaAs reaction. Conversely, only binary phases result from the Pt/GaAs reaction. These observations are used to construct isothermal sections of the M--Ga--As thin-film phase diagrams. The behavior of a thin (1--2 nm) native oxide--hydrocarbon layer during the Ni/GaAs, Pd/GaAs, and Pt/GaAs reactions is also investigated. Only the Ni/GaAs reaction is ...
The Green-Chasman lattice, which is the basis for both NSLS storage rings, was conceived with insertion devices in mind. Long, field-free straight sections were provided in the design. The electron optics were chosen so that these sections had zero dispersion and the effects of new magnetic structures placed in these regions would have minimal effect on the emittance of the electron beam. This design concept has been followed by all high-brightness rings which were built subsequent to the NSLS. The X-Ray Ring straight sections also have a very small vertical {beta} function, in addition to the zero dispersion. This was done to optimize the brightness of wiggler sources. There is a further benefit however. The {beta} function determines the beam size and divergence at a particular point in the storage ring lattice. The size is proportional to {radical}{beta} and the divergence is proportional to 1/{radical}{beta}. Thus the electron beam is very ...
Functionalizing nanoparticle surfaces is essential for achieving homogeneous dispersions of monodisperse particles in polymer nanocomposites for successful utilization in engineering applications. Functionalization reduces the surface energy of the nanoparticles, thereby limiting the tendency to agglomerate. Moreover, reactive groups on the surface can also participate in the polymerization, creating covalent bonds between the inorganic and organic phases. In this paper, a fluidized bed inductively coupled plasma (FB-ICP) reactor is used to break apart the agglomerates and functionalize commercial TiO2 nanoparticle powders in a batch of several grams. The fluidized bed could be implemented into a continuous flow reactor, potentially making this a viable method to treat larger quantities of commercial powders. The particles are treated with acrylic acid (AA) and tetraethylorthosilicate (TEOS) plasma and the functionalized particles were collected separately from ...
Some models for quantum gravity (QG) violate Lorentz invariance and predict an energy dependence of the speed of light, leading to a dispersion of high-energy gamma-ray signals that travel over cosmological distances. Limits on the dispersion from short-duration substructures observed in gamma-rays emitted by gamma-ray bursts (GRBs) at cosmological distances have provided interesting bounds on Lorentz invariance violation (LIV). Recent observations of unprecedentedly fast flares in the very-high energy gamma-ray emission of the active galactic nuclei (AGNs) Mkn 501 in 2005 and PKS 2155-304 in 2006 resulted in the most constraining limits on LIV from light-travel observations, approaching the Planck mass scale, at which QG effects are assumed to become important. I review the current status of LIV searches using GRBs and AGN flare events, and discuss limitations of light-travel time analyses and prospects for future instruments in the gamma-ray ...
The symmetric noncoplanar (e,2e) cross sections (momentum profiles) of H_2 and D_2 for the transitions to the 2p#sigma#_u and 2s#sigma#_g excited ion states have been measured, relative to the ground-state ion transition, using a high-sensitivity multichannel momentum-dispersive electron momentum spectrometer (EMS) at an impact energy of 1200 eV. Newly calculated plane-wave impulse approximation (PWIA) cross sections, based on a full-configuration-interaction H_2 wave function, are compared to the experimental results. These calculations are in better agreement with the experimental results for the transition to the 2s#sigma#_g ion state than the earlier theoretical work of Liu and Smith, Jr. [Phys. Rev. A 31, 3003 (1985)] which has been found to be in error. Nevertheless, significant discrepancies between the relative experimental and theoretical cross sections are observed for the transitions to excited ion states, suggesting a failure of the PWIA description of ...
It has been clarified by the present authors, based on the plasma nitriding of Fe-Cr alloys and Fe-Ti alloys carried out at the temperature under 550{degree}C hitherto, that an internal nitriding layer is formed due to the fine dispersion of the particles of Cr nitride and Ti nitride in {gamma}{prime} Fe4N layer on the specimen surface. In this study, the plasma nitriding of Fe-Cr alloys are carried out at 650{degree}C, and the effects of the solute (Cr) content on the structures, nitride and the thickness distribution are examined. The main results obtained therefrom are indicated hereafter. In accordance with the observation on the cross-sectional structure of the alloys, only the nitriding layer deduced as the dispersion and precipitation of the particles of Cr nitride from {alpha}-Fe of the mother phase is formed, while {gamma}{prime}-Fe4N layer, which is found at the temperature under 550{degree}C, is not formed. The nitride of Cr ...
Volume sources is used for standard sources by radioactive measurement using Ge semiconductor detector of environmental sample, e.g. water, soil and etc. that require large volume. The commercial volume source used in measurement of the water sample is made of agar-agar, and that used in measurement of the soil sample is made of alumina powder. When the plastic receptacles of this two kinds of volume sources were damaged, the leakage contents cause contamination. Moreover, if hermetically sealing performance of volume source made of agar-agar fell, volume decrease due to an evaporation off moisture gives an error to radioactive measurement. Therefore, we developed the two type methods using unsaturated polyester resin, vinilester resin, their hardening agent and acrylicresin. The first type is due to dispersing the hydrochloric acid solution included the radioisotopes uniformly in each resin and hardening the resin. The second is due to ...
A dense silica glass was prepared by consolidating a highly dispersed silicic acid powder (particle size 1H magic-angle spinning (MAS) NMR confirmed an increase in hydroxyl groups in the sample prepared by SPS relative to that of the conventional SiO2 reference glass. Aside from the comparably high water content, we conclude from the similarity of the IR-reflectance and the 29Si MAS NMR spectra of the SPS sample and the corresponding spectra of the conventionally prepared silica glass, that the short- and medium-range order is virtually the same in both materials. Raman spectroscopy, however, suggests that the number of three- and four-membered rings is significantly smaller in the SPS sample compared to the conventionally prepared sample. Based on these results we conclude that it is possible to prepare glasses by compacting amorphous powders by the SPS process. The SPS process may therefore enable the preparation of glasses with compositions inaccessible by ...
10%Pt/C catalysts were prepared by liquid reduction method. PTFE and Pt/ C catalysts were adhered to porous metal and hydrophobic Pt/C/PTFE catalysts were prepared. The structure and size of Pt crystal particles of Pt/C catalysts were analyzed by XRD, and their mean size was 3.1 nm. The dispersion state of Pt/C and PTFE was analyzed by SEM, and they had good dispersion mostly, but PTFE membrane could be observed on local parts of Pt/C/PTFE surface. Because of low hydrophobicity, Pt/C/ PTFE catalysts have low activity when the mass ratio of PTFE and Pt/C is 0.5: 1, and their catalytic activity increases markedly when the ratio is 1:1. When the ratio increases again, more Pt active sites would be covered by PTFE and interior diffusion effect would increase, which result in the decrease of catalytic activity of Pt/C/PTFE. By PTFE pretreatment of porous metal carrier, the activity of Pt/C/PTFE catalysts decreases when the mass ratio of PTFE and ...
A beta microprobe was successfully applied to monitor arterial input function for quantification of regional cerebral blood flow (rCBF) in the monkey brain with {sup 15}O-water and positron emission tomography (PET). The sensitivity of the probe was approximately 0.83 to 1.67 cps/kBq/ml depending on the studies. A preliminary study was performed to find a suitable use and to evaluate the performance of the system and data analysis procedure. The results showed that dispersion correction of measured input function was unnecessary if microprobes were connected directly to the arterial catheter. Then multiple CBF measurements were done in three monkeys under anesthesia. Identical regions of interest were placed with the aid of magnetic resonance imaging (MRI) of each monkey and rCBF values were estimated. Estimated rCBFs were reproducible for several measurements. The mean CBF value for a pentobarbital anesthetized monkey was 46.0 ml/min/100 g (PaCO{sub 2}=46.3 mmHg). ...
With relation to the coals delivered as common samples in the coal fundamental technology development project, an experimental study was conducted on agglomeration characteristics and reaction characteristics in the fluidized-bed coal gasifier. For the experiment, used was a fluidized bed gasifier inserted with a cone-shape dispersion plate with a nozzle in the center. After raising the temperature of the gasifier up to 773K, gasification was conducted sending to the gasifier air from the nozzle and steam from the dispersion plate. The mean particle diameter and gas concentration of chars were measured till the temperature reaches 1373K. As a result of the experiment, it was confirmed that the carbon conversion ratio increases with a decrease in coalification degree of the coal. Moreover, influence of the coal kind was markedly observed at the grid zone of the lower part of the bed, and it was clarified that the lower carbon content ratio the ...
The surface layer optimized in resistance of corrosion and wear has been obtained by W + C dual implantation on H13 steel. The electrochemical polarization measurements show that the peak current density I_D is increased and then saturated with increasing of voltage scanning loops. The I_D is 100 times smaller than that of H13 steel, and 2-3 times smaller than that of tungsten. Then influence of dual implantation order on corrosion resistance is also studied. The I_D for W_5C_8 implanted first with W is half of that for C_5W_5 implanted first with C. The corrosion resistance structure of the samples after corrosion is observed by SEM. The X-ray analysis indicates that the structure consists of disperse phases of WC, W_2C, FeW, Fe_2W, FeW_2C and iron carbides. It is shown from Auger analysis that the optimum complex layer for corrosion resistance consists of thin carbon film on surface, disperse phases of these metal compounds in middle and then ...
Warm-intermediate inflationary universe models in the context of braneworld cosmologies, are studied. This study is done in the weak and strong dissipative regimes. We find that, the scalar potentials and dissipation coefficients in terms of the scalar field, evolves as type-power-law and powers of logarithms, respectively. General conditions required for these models to be realizable are derived and discussed. We also study the scalar and tensor perturbations for each regime. We use recent astronomical observations to constraint the parameters appearing in the braneworld models.
The reactor core of TAPP-3 and 4 is divided into 14 power zones for spatial power control. Corresponding to each zone is a light water zonal compartment. The 14 ZCCs are located in two radial planes, each containing 7 ZCCs. For each zone, power measurement is carried out using three cobalt Self Powered Neutron Detectors (SPNDs) at appropriate locations close to the respective ZCC. Since the zone power as obtained by the true average of the healthy zone control detector (ZCD) readings belonging to a particular zone may not correspond to its actual power because these 3 detectors per zone, measure only point fluxes but the zone extends over a large core region. Therefore accurate estimation of zone power calibration factors is required to estimate the zone powers and also to provide effective spatial power control to avoid the xenon induced spatial power oscillations in large PHWRs like 540 MWe Reactor. This accurate calculation of zone power is carried out by FMS which uses ? modes in ...
This invention relates to an automatically-operating wedge block for maintaining intimate structural contact over wide temperature ranges, including cryogenic use. The wedging action depends on the relative thermal expansion of two materials having very different coefficients of thermal expansion. The wedge block expands in thickness when cooled to cryogenic temperatures and contracts in thickness when returned to room temperature.
The behaviour of an elastomeric seal for vehicle brake Tandem master cylinder is measured and analyzed in temperature and brake fluids changed. Working conditions are simulated for different piston rod velocity and cylinder supply pressure, in temperature rising, brakefluid boundary and Nanoaluminum oxide brakefluid oxide brakefluid lubrication. The result shows that Nanoaluminum oxide brakefluid with its ball shape can highly reduce friction coefficient to avoid seal excessive wear and reduce slick slip in brake applications.
The experimental superconducting magnetic system of 0.5 MJ energy storage is described. The step variation of the winding inductance provides a control by the discharge current at the energy output on a high-ohmic load. The voltage on a load is 45 kV at the current 1100 A under the controllable discharge conditions. The energy transfer coefficient constitutes 0,76 under the maximum-to-minimal current ratio equal to 1.3. 7 refs., 3 figs., 2 tabs.
We consider a particle that is subject to a constant force and scatters inelastically on a vibrating periodically corrugated floor. At small friction and for small scatterers the dynamics is dominated by resonances forming spiral structures in phase space. These spiral modes lead to pronounced maxima and minima in the diffusion coefficient as a function of the vibration frequency, as is shown in computer simulations. Our theoretical predictions may be verified experimentally by studying transport of single granular particles on vibratory conveyors.
We describe a global closed orbit feedback experiment, based upon a real time harmonic analysis of both the orbit movement and the correction magnetic fields. The feedback forces the coefficients of a few harmonics near the betatron tune to vanish, and significantly improves the global orbit stability. We present the results of the experiment in the UV ring using 4 detectors and 4 trims, in which maximum observed displacement was reduced by a factor of between 3 and 4. 4 refs., 3 figs.
Pyrheliometric methods are described (particularly methods for measuring the solar constant), and theoretical and experimental studies in this field are surveyed and systematized. Particular attention is given to the analysis of instruments intended for pyrheliometers used as standards, reference instruments, and solar-constant meters is examined, and consideration is given to methods for determining the thermal-radiation properties of absorbing coatings and methods for calculating the absorption coefficients of cavity receivers.
An original evaluating method of gain degradation has been found for neutron irradiated transistors. It establishes a correlation between degradation and the product of two coefficients: spectra factor and an electrical parameter which is measured or directly deduced from manufacturer's data. Equivalence for several type of spectra (fission, 14MeV and degradation sensitivity to electrical parameters values of individual components of a batch are obtained.
The polarization characteristics of spontaneous radiation from relativistic electrons moving through helical and planar wiggler fields are evaluated for imperfect beam injection. Maximum coherent gain in free-electron laser systems are seen to occur in optical fields having these polarization characteristics rather than those of the wiggler magnets. Coupling coefficients for an electron beam skewed at an angle to the optical mode are presented.
An apparatus allowing the photoexcitation of barium atomic beam over its whole surface is described. This photoexcitation is achieved by another barium spectrum emitted up steam of the beam by a cathodic out-flow produced at the exit oven. The fluorescence spectrum is studied in detail as well as the influence of different parameters, such as oven temperature, current intensity of the outflow, and excitation depth. A calculation shows how to determine Einstein coefficient, oscillator strengths and atomic lifetimes from our experimental measurements.
A study of the 150-300 keV proton beam transmission through glass (borosilicate) tapered capillaries with different diameters of the input and output of the capillary was performed. The focusing effect was observed. The areal density of the transmitted beam is enhanced by approximately 20 times. It was shown that changing a taper angle from 0.5 deg to 1.7 deg evidences the increase of the transmission coefficient more than by 300 times keeping the initial energy spectrum of ions. (author)
Transient enhanced diffusion in boron-implanted silicon is interpreted as being due to the fact that during rapid thermal annealing a relaxation process takes place, associated with quasi-chemical reactions including defects. A simple analytical model makes it possible to describe the annealing mechanism on a microscopic scale in terms of reaction-diffusion processes. The measured dependences of the boron diffusion coefficient of the enhanced diffusion on time, temperature and implantation energy are satisfactorily explained. (author).
Transient enhanced diffusion in boron-implanted silicon is interpreted as being due to the fact that during rapid thermal annealing a relaxation process takes place, associated with quasi-chemical reactions including defects. A simple analytical model makes it possible to describe the annealing mechanism on a microscopic scale in terms of reaction-diffusion processes. The measured dependences of the boron diffusion coefficient of the enhanced diffusion on time, temperature and implantation energy are satisfactorily explained. (author).
The basic design of a system installed in the Columbus, Ohio Zoo is described. The distribution system is described in detail. The control system is microprocessor controlled, with about 50 monitoring points. Preliminary evaluations have indicated that the system can operate with an overall coefficient of performance in excess of 3.5. 1 figure.
We developed a model for radar scattering from the lunar reoglith layer using vector radiative transfer theory. From this model, both the radar backscattering coefficient and the circular polarization ratio can be predicted analytically as a function of regolith parameters.
A pulsed field gradient spin echo sequence has been incorporated in a nuclear magnetic resonance (NMR) imaging experiment to provide an image contrast dependent on local molecular self-diffusion. The...Full Text Available
Frequency response measurements are used to determine the carrier lifetime of 1.3-..mu..m InGaAsP buried heterostructure lasers between 1 mA and threshold. The data confirm previous results on the radiative and Auger recombination coefficients and reveal the presence of a nonradiative current which dominates at low currents and contributes 4 mA at threshold.
A mathematical model is proposed for three-phase filtering which is a particular case of a more general model of filtering multiple component mixtures and makes it possible to describe three-phase filtering flows under conditions where the pressure of saturation is variable in time and in space. In the proposed model, the system of unknown functions is selected so that it makes it possible to trace fairly simply the pressure of saturation and to compute the corresponding equation coefficients.
This paper is concerned with the development and application of an analytical method for the performance prediction of air cooled condensers. A local analysis is employed in which the condenser is considered as a matrix of small basic heat transfer modules. For each element, local film coefficients for both the air and the condensing fluid are determined according to the existing local conditions, including the two-phase flow regime. The paper considers an application of the method to heat pump condensing.
Dianionic tridentate, O, N, S, Schiff bases derived from salicylaldehyde and 2-mercapto-amines react with Tc(V) gluconate to form radiochemically pure neutral Tc chelates. The existence of lipophilic Tc complexes could be proved by high voltage electrophoresis, thin layer chromatography and octanol/water partition coefficients. 11 refs.
Dianionic tridentate, O, N, S Schiff bases derived from salicylaldehyde and 2-mercapto-amines react with Tc(V) gluconate to form radiochemically pure neutral Tc chelates. The existence of lipophilic Tc complexes could be proved by high voltage electrophoresis, thin layer chromatography and octanol/water partition coefficients. (author).
X-ray results on the lattice parameters, molar volume and thermal expansion coefficients of solid ortho-deuterium for the region from 2 K to the melting point are reported. It is found that the thermal expansion of ortho-deuterium crystals, similarly to parahydrogen is essentially anisotropic near the melting temperature. The vacancy density at the triple point is estimated. Some thermodynamic characteristics of ortho-deuterium are calculated and temperature dependences of heat capacity at constant volume, isothermal compressibility and Gruneisen constant are analyzed.
Radionuclide (R) sorption from a solution (vapor) by freshly formed crystals with production of substitution solid solutions under different types of self-disordering is studied. Changes of self-defectiveness and macrodefectiveness with time and effect of radiation defects in the presence of P macroquantities are taken into account. An analysis for monodispersed sorbents is performed. It is shown that the achievement of equilibrium within a reasonable time in impurity-solid phase system depends on defectiveness which ensures a required level of the coefficient of impurity diffusion in sorbent crystals.
In studying the absorption of carbon dioxide by absorbents impregnated with alkanol amines, researchers used a laboratory-scale packed column to determine the overall gas-phase mass-transfer coefficients and enhancement factors. A model derived for the mechanism of the chemical reaction taking place in the interfacial layer accounts for the effect of the reaction upon the absorption rate better than other models.
It is well known that the zeros of orthogonal polynomials interlace. In this paper we study the case of multiple orthogonal polynomials. We recall known results and some recursion relations for multiple orthogonal polynomials. Our main result gives a sufficient condition, based on the coefficients in the recurrence relations, for the interlacing of the zeros of neighboring multiple orthogonal polynomials. We give several examples illustrating our result.
The droplet concentration profile in a liquid film-mist two-phase flow in a developing flow region of a horizontal rectangular channel was analyzed theoretically and experimentally. The effects of the mean settling velocity of droplets v sub(f) and the turbulent diffusion coefficient epsilon sub(p) on the droplet concentration profile were investigated by the theoretical analysis. The calculated results of the droplet concentration profile using the proper values of v sub(f) and epsilon sub(p) agreed with the experimental results.
The droplet concentration profile in a liquid film-mist two-phase flow in a developing flow region of a horizontal rectangular channel was analyzed theoretically and experimentally. The effects of the mean settling velocity of droplets v sub(f) and the turbulent diffusion coefficient epsilon sub(p) on the droplet concentration profile were investigated by the theoretical analysis. The calculated results of the droplet concentration profile using the proper values of v sub(f) and epsilon sub(p) agreed with the experimental results. (author).
We construct a chaotic inflation model in which the Higgs fields play the role of the inflaton in the singlet extension of the supersymmetric standard model. The key idea is to impose a shift symmetry on the D-flat direction Hu Hd in the Kahler potential. The model is a realization of the recently proposed running kinetic inflation, in which the coefficient of the kinetic term grows as the inflaton field. The inflaton potential depends on the structure of the Higgs sector. For instance, the inflaton potential is proportional to phi^{2/3} during inflation in the NMSSM.
A correlation was developed for laminar film condensation on vertical fluted surfaces. The theoretical analysis of Panchal and Bell was used for defining important physical property groups. The experimental data of Combs et al. were used to validate the proposed correlation. The experimental database used in the present study included four flute geometries that could be approximated to cosine-type flutes and seven fluids. The resulting correlation can predict the average condensate heat transfer coefficient within {+-}20%.
Natural radioactive materials were used for detector calibration. We found that KCl is a very suitable material for this purpose. The efficiency curve shape was derived by using {gamma} ray lines of {sup 214}Bi normalised using a known quantity of KCl in the same geometry. The best fit was found by the least squares method. The summing correction coefficients for {sup 214}Bi are determined. (orig.).
Natural radioactive materials were used for detector calibration. We found that KCl is a very suitable material for this purpose. The efficiency curve shape was derived by using #gamma# ray lines of "2"1"4Bi normalised using a known quantity of KCl in the same geometry. The best fit was found by the least squares method. The summing correction coefficients for "2"1"4Bi are determined. (orig.).
Friction opposes tooth motion whenever sliding mechanics is employed. Understanding what friction is and how to manage it is of paramount importance to the successful practitioner. In this article, the coefficients of friction are summarized between different arch wire-bracket couples as a function of material, geometric, and external parameters. From this vantage point, friction can then be evaluated within the context of other factors that affect sliding-binding and notching. PMID:9573878
A simple arrangement of standard horizontal coaxial Ge(Li) detectors with the aim of constructing a Compton linear-polarimeter was tested. High polarization sensitivity and detection efficiency were achieved. The characteristics of the polarimeter and analysis of the observed quantities in terms of the linear-polarization mixing coefficient Hsub(l)(LL') are described.
Experimental investigation was carried out for friction factor and heat transfer coefficient in the case of a rotating tube with a twisted-tape insert for heat transfer augmentation. The data obtained were compared with existing data for a stationary tube with a twisted-tape insert. It has been observed that the enhancement in heat transfer offsets the rise in friction factor due to rotation, with respect to a plain tube under stationary conditions. A correlation has been proposed for the data obtained.
The estimation of numerical values of the mean distance of closest approach of ions, a, of heavy metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.
Based on results from recent studies of elemental dietary intake and organ or tissue content for adult Chinese men, quoted nationwide elemental concentrations in Chinese soil and newly published national average consumption of dietary foods, values of both transfer coefficients and discrimination factor (DF) for transfer from soil via the diet to both critical organs and the whole body have been calculated for important elements in radiation protection, including alkaline earths, alkali metals, rare earths and other related elements. These calculations have used both the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) model and the DF method. In the UNSCEAR model, the basic parameters used to describe the transport of radionuclides are the transfer coefficients P_i_j, which describe the relationship of concentrations or other amounts between compartment i and the following compartment j, whereas the DF is the ...
During electrolysis of a "2"4"8Cm(III) solution in 2M K_2CO_3 at pH=13, partial oxidation of curium to a higher oxidation state, probably Cm(IV), was observed. The absorption spectra of Cm(III) and Cm(IV) in K_2CO_3 solution were recorded and the molar extinction coefficients of main absorption bands of curium were evaluated. (author).
Donnan dialysis with ion-exchange membranes was studied under various kinds of experimental conditions using ions of different valences. The diffusion coefficients (D{sub d}) of various kinds of ions in the ion-exchange membrane were obtained by curve fitting an equation derived from the mass balance to three kinds of Donnan dialytic experiments. It was found that the value of D{sub d}/D{sub s} using D{sub d} of monovalent ions in Donnan dialysis with a set of monovalent feed ions and bivalent driving ions was 1/175, where D{sub s} represents a diffusion coefficient in solution. D{sub s} was calculated from the Nernst-Einstein equation substituted by the ionic conductance of ions at infinite dilution in water. Using D{sub d} of bivalent ions in Donnan dialysis with the same set led to a D{sub d}/D{sub s} value of 1/438. Moreover, using D{sub d} in Donnan dialysis with the same set, the value of D{sub d}/D{sub e} was kept constant at 0.4 (D{sub ...
The carbon content of silicon single crystals and polycrystals has been measured by charged particle activation analysis (CPAA) and infrared absorption. The authors obtained a linear relationship between the absorption coefficient at 605 cm/sup -1/ and the carbon content obtained by CPAA. They obtained a conversion factor of (1.00 +- 0.03) 10/sup 17//cm/sup 2/ for a 100% substitutional carbon.
The kinetic parameters, ..cap alpha.. the coupling coefficient and tau-bar the mean neutron transit time have been determined using a reactor oscillator on the coupled-core of the Queen Mary College research reactor. By using correlation techniques it has proved possible to use detectors small enough to be inserted in the fuel tanks. It is shown that the simplified Baldwin model with one-group diffusion theory is inadequate to describe the kinetic behaviour and the experimentally-determined parameters are dependent upon the positioning of the detectors.
An equation is described to estimate the value of the liquid-phase mass-transfer coefficient of aqueous solutions of surfactants from its value for pure water. The form of the equation is obtained from Levich's theory, and it is adjusted to experiments of absorption of CO/sub 2/ in aqueous solutions of five pure surfactants. The reduction of the absorption rate is correlated with the interfacial pressure of the solution.
The paper presents a sequential procedure for coordinated stabilization of a multimachine power system with arbitrary complexity of the system model. The most effective machine to be equipped with a power system stabilizer is identified using eigenvalue analysis. The selection is based on the sensitivity of critical eigenvalues to increases in the coefficient of a damping term which is inserted in each equation of motion, in succession. The method is applied to a three-machine system and simulation studies show appreciable improvements in the small disturbance stability of the system.
Collisional-Radiative numerical models are commonly used to design or interpret experiments in atomic physics of laser-created plasmas, including X-ray laser studies. We describe our new code containing several options: average ion, more or less detailed configurations. It consists of an atomic data base coupled to subroutines evaluating ionic populations and emission and absorption coefficients. Numerical results are given to illustrate the capabilities of the code and to compare different models and types of approximation.
Results on defect structure study and degree of molybdenum radiation hardening irradiated by fission neutrons and medium energy alpha-particles are presented. It is shown that molybdenum irradiation by alpha-particles and neutrons leads to different degree of material hardening for the same damage level. It is established that molybdenum radiation hardening is mainly defined by radiation defect clusters visible in electron microscope whose coefficient of rigidity depends on their size. 5 refs.; 6 figs.; 2 tabs. (author).
Calculation method for pyramidal horn radiators (PHR) with curvilinear generatrix has been developed on the basis of the theory of waveguide tapers. This method makes it possible to reduce the value of spurious reflection coefficients and transformation of the principal wave into waves of higher order modes by forming generatrixes of walls with specific curvilinearity.
The authors investigate the breakdown luminescence spectra in reverse-biased p-n heterojunctions based on gallium and aluminum phosphides and arsenides for the purpose of determining their behavior as lasing and photodetection materials. Data are given on temperature coefficients, band gap structure, bremsstrahlung, hot carrier mobility and photon emission, and transition and recombination parameters.
Proceeding from analysis of the influence of parameters of the target-filter system on radiation-physical characteristics of braking radiation, some recommendations were issued for assessment of the forming systems of medical accelerators of electrons. A new criterion - a coefficient of the forming system efficacy - was introduced, characterizing a beam formation tract with relation to a whole set of radiotherapeutic problems.
The effect of finite gyroradius on the current diffusive ballooning mode is examined. Starting from the reduced MHD equations including turbulent transports, coupling with drift motion and finite gyroradius effect of ions, we derive a ballooning mode equation with complex transport coefficients. The eigenfrequency, saturation level and thermal diffusivity are evaluated numerically from the marginal stability condition. Preliminary results of their parameter dependence is presented. (author)
A simple arrangement of standard horizontal coaxial Ge(Li) detectors with the aim of constructing a Compton linear-polarimeter was tested. High polarization sensitivity and detection efficiency were achieved. The characteristics of the polarimeter and analysis of the observed quantities in terms of the linear-polarization mixing coefficient Hsub(l)(LL') are described. (orig.).
The instability of the phonon spectrum in liquid Helium for T < 1 K is a well established experimental fact. We discuss the role of q-deformation as a possible mechanism to supply the energy deficit that forbidden one-phonon decay into two phonons when the constant {gamma} in the phonon anomalous dispersion relation ({omega}{sup ph} = c{sub 0} p(1 - {gamma}p{sup 2})) is positive, through the analysis of three-phonon processes in a q-phonons gas. (author). 19 refs.
An account is given of the existence of kinematic subsystems in elliptical galaxies, in conjunction with discussions of the application of statistical tests to determine whether ellipticals are triaxial, and of the modified Faber-Jackson relation for elliptical galaxies. Recent data obtained by Kormendy (1988) and Dressler and Richstone (1988) on the kinematics of the M31, M32, and NGC 4594 central regions indicate both very steep rotation curves and peaked velocity dispersion profiles. If elliptical galaxies are triaxial, and if it is common for them to have accreted other galaxies during their evolution, then both a source of fuel for an active nucleus and a mechanism for getting that fuel from outside the galaxy into its center is available. 61 refs.
The penetration depth and concentration distribution for vanadium ions with low energy implanted into the dry peanut seeds is determined by scanning electron microscope and X-ray energy dispersion spectrometer. The results show that the depth-concentration distribution is a Gaussian distribution with a long tail and the maximum penetration depth is about 13.6 #mu#m for V"+ with 200 keV in cotyledon of the peanut. The experimental result of the implanted V"+ range in the peanut seeds is compared with the calculating value of the TRIM95
Spontaneous emission in photonic crystals with anisotropic three-dimensional dispersion relation is studied. If the upper level is below a characteristic frequency omega(1), or above omega(2), or between omega(1) and omega(2), the radiation is a localized field with a frequency in the band gap, or a propagating field with a frquency in the band, or a diffusion field, respectively. An analytical expression for the Lamb shift is obtained. The Lamb shift for the current case is small compared to that in an ordinary vacuum or in one- or two-dimensional photonic crystals due to lower density of states. PMID:11017227
The methodology for studying the behaviour of the toxic pollutant metals (Hg, Pb, Cd, Cr) in the South Shetland region is presented here, toxic pollutants are caused by the urban and industrial activity at the Southern hemisphere and they are pressured to be incorporated to the region though atmospheric transport processes the Cs 137 (refI) was used as a tracing element, which was freed and dispersed in the atmosphere as a result of nuclear bombs testing. During the austral summer samples from ground, sediments, atmospheric and glacier were extracted.
Purpose - This paper aims to describe the technology and applications of nanocomposite materials. Design/methodology/approach - This paper discusses products, applications and technological developments in polymer, ceramic and metal nanocomposites. It concludes with a brief consideration of electronic component applications. Findings - It is shown that polymer nanocomposites and the materials used in their production are commercially available and finding applications in several industries, including automotive, military, food, electronics and leisure, due to their enhanced mechanical, electrical and thermal properties. Ceramic and metallic nanocomposites are at an earlier stage of development and a critical issue to resolve is optimising the dispersion of nanomaterials in the matrices. Pa...
Using the [sup 57]Fe Moessbauer spectroscopy, the microscopic behavior of Fe powders has been investigated during and after the mechanical alloying (MA) process for Al-Fe and Ag-Fe systems. A repeated rolling method as well as a conventional ball-milling method are employed in order to understand the microscopic process of the kneading of Al and Fe powders during their MA and the resultant powders show quite similar Moessbauer spectra suggesting that the kneading by an impact between colliding balls is the same process as that of the thickness reduction by cold rolling. Moessbauer spectra show clearly the occurrence of the mutual atomic dispersion for the thermodynamically immiscible Ag-Fe system. (orig.).
The Meteorological Information System (MIS) comprising the meteorological instruments, the computers, and the software for data processing and recording, is part of the KfK safety and control system. In 1982 is was equipped with an independent data processing system. The report explains the arrangement and the operation of the sensors and thw two process computers. For selected meteorological situations the ability of the system is demonstrated, i.e., the presentation of the vertical profiles of wind, temperature and turbulence in the lower atmospheric boundary layer as well as the calculation and graphical representation of the transport and dispersion into the KfK environment of radioactive pollutants being released by the nuclear installations of the KfK into the atmosphere.
A method and apparatus for operating a compression ignition engine having a cylinder wall, a piston, and a head defining a combustion chamber. The method and apparatus includes delivering fuel substantially uniformly into the combustion chamber, the fuel being dispersed throughout the combustion chamber and spaced from the cylinder wall, delivering an oxidant into the combustion chamber sufficient to support combustion at a first predetermined combustion duration, and delivering a diluent into the combustion chamber sufficient to change the first predetermined combustion duration to a second predetermined combustion duration different from the first predetermined combustion duration.
Fractal dimensional analysis was employed to obtain a quantitative measure of the morphology of polymer networks formed by UV irradiation induced polymerization of photo-reactive mesogenic monomers dissolved in a liquid crystal host medium. The fractal dimensions obtained, may be interpreted by polymer network growth following a percolation-like model for monomer concentrations well below the solubility limit. On passing the solubility limit, the polymerization process changes from a (radical chain) solution polymerization to a dispersion polymerization, with fractal dimensions decreasing and suggesting a cluster-cluster aggregation process for monomer concentrations above the solubility limit, similar to the aggregation of colloidal particles.
Progress reports on the European Research Centre for Air Pollution Control Measures project are presented. Topics covered were: assessment and analysis of the impacts of airborne pollutants on forest trees, and distinction from other potential causes of recent forest dieback; research into atmospheric dispersion, conversion and deposition of airborne pollutants; development and optimization of industrial technical processes to reduce or avoid emissions; and providing instruments and making recommendations to the industrial and political sectors.
Elastic electromagnetic form factors of nucleons are investigated for both the time-like and the space-like momenta by using the unsubtracted dispersion relation with QCD constraints. It is shown that the calculated form factors reproduce the experimental data reasonably well; they agree with recent experimental data for the neutron magnetic form factors for the space-like data obtained by the CLAS Collaboration and are compatible with the ratio of the electric and magnetic form factors for the time-like momentum obtained by the BABAR Collaboration.
Studies dialysis kinetics of zinc dialkyldithiophosphates, detergent-dispersing agents, alkyl-phenols and base oils. It was established that diffusion kinetics of oil hydrocarbons through membrane of individual compounds and narrow fractions is described by Brinzinger's formula, which is identical to the kinetic reaction formula of the 1st order. It was shown that dialysis can be utilized to determine the content of the ''active substance'' only in sulphonate and alkylsalycilate additives. Increasing temperature from 20 to 40/sup 0/ results in an increased dialysis constant for all studied products by 1.4-1.9 times.
An alkaline-side solvent extraction process was developed for cesium removal from Savannah River Site (SRS) tank waste. The process was invented at Oak Ridge National Laboratory and developed and tested at Argonne National Laboratory using singlestage and multistage tests in a laboratory-scale centrifugal contactor. The dispersion number, hydraulic performance, stage efficiency, and general operability of the process flowsheet were determined. Based on these tests, further solvent development work was done. The final solvent formulation appears to be an excellent candidate for removing cesium from SRS tank waste.
A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.
The dual-media approach to contaminant transport modeling has emerged over the years as a clear improvement over the conventional Fickian advection-dispersion, or single-medium model, in an increasing number of settings. Recent application to the MADE-2 tracer test at Columbus Air Force Base has extended interest to field-scale plume migration in unconsolidated sediments. Subsequent application to tritium migration from the SRS F- and H-area seepage basins within this study also demonstrated improved transport predictions.
We fabricated a double negative acoustic metamaterial which consisted of Helmholtz resonators and membranes. Experimental data on the transmission and dispersion relation are presented. The system exhibits three frequencies where the acoustic state makes sharp transitions from density negative ({\\rho} -NG) to double negative (DNG), modulus negative (B-NG), and double positive (DPS) in sequence with the frequency. We observed a wide range of negative refractive index from -0.06 to -3.7 relative to air, which will allow for new acoustic transformation techniques.
A new potential function based on spectroscopic results for diatomic molecules is presented and applied to the hydrogen bonding systems. The potential energy of interaction is supposed to have electrostatic, polarization, dispersion, repulsion and effective charge-transfer contributions. Estimates of the effective charge-transfer quantity have been made based on the average charge of the proton donor and the acceptor atoms. For dimers such as water, methanol, acetic acid and formic acid, the vibrational stretching frequencies and dimerization energies are calculated and discussed in connection with Badger-Bauer rule. (author).