WorldWideScience

Sample records for brass

  1. Micro Structure and Hardness Analysis of Brass Metal Welded

    Science.gov (United States)

    Lukman Faris, N.; Muljadi; Djuhana

    2018-01-01

    Brass metals are widely used for plumbing fittings. High tensile brasses are more highly alloyed and find uses in marine engineering. The welding of brass metal has been done by using electrical weld machine (SMAW). The microstructure of brass metal welded was observed by optical microscope. The result can see that the microstructure has been changed due to heat from welding. The microstructure of original brass metal is seen a fine laminar stucture, but the microstructure at HAZ appears bigger grains and some area at HAZ is seen coarser microstructure. The microstructure at weld zone can be seen that it was found some of agglomeration of materials from reaction between brass metal and electrode coating wire. According the hardness measurement, it is found highest hardness value about 301.92 HV at weld zone, and hardness value at base metal is 177.84 HV

  2. Optical properties and electronic structure of the Cu–Zn brasses

    International Nuclear Information System (INIS)

    Keast, V.J.; Ewald, J.; De Silva, K.S.B.; Cortie, M.B.; Monnier, B.; Cuskelly, D.; Kisi, E.H.

    2015-01-01

    The color of Cu–Zn brasses range from the red of copper through bright yellow to grey-silver as the Zn content increases. Here we examine the mechanism by which these color changes occur. The optical properties of this set of alloys has been calculated using density functional theory (DFT) and compared to experimental spectroscopy measurements. The optical response of the low Zn content α-brasses is shown to have a distinctly different origin to that in the higher content β′, γ and ε-brasses. The response of β′-brass is unique in that it is strongly influenced by an overdamped plasmon excitation and this alloy will also have a strong surface plasmon response. - Highlights: • Study of the electronic structure and optical response of the Cu–Zn brasses. • Agreement between experiment and calculation of the dielectric functions. • α-brasses optical response is dominated by transitions from the top of the d-band. • In the other brasses it is transitions around the Fermi level. • β′-brass response is dominateed by an overdamped bulk plasmonic response

  3. Optical properties and electronic structure of the Cu–Zn brasses

    Energy Technology Data Exchange (ETDEWEB)

    Keast, V.J., E-mail: vicki.keast@newcastle.edu.au [School of Mathematical and Physical Sciences, The University of Newcastle, Callaghan, NSW 2308 (Australia); Ewald, J. [School of Mathematical and Physical Sciences, The University of Newcastle, Callaghan, NSW 2308 (Australia); De Silva, K.S.B.; Cortie, M.B. [Institute for Nanoscale Technology, University of Technology Sydney, PO Box 123, Broadway, NSW 2007 (Australia); Monnier, B. [School of Engineering, The University of Newcastle, Callaghan, NSW 2308 (Australia); Universite de Technologie de Troyes, 12 Rue Marie Curie, BP 2060, 10010 Troyes Cedex (France); Cuskelly, D.; Kisi, E.H. [School of Engineering, The University of Newcastle, Callaghan, NSW 2308 (Australia)

    2015-10-25

    The color of Cu–Zn brasses range from the red of copper through bright yellow to grey-silver as the Zn content increases. Here we examine the mechanism by which these color changes occur. The optical properties of this set of alloys has been calculated using density functional theory (DFT) and compared to experimental spectroscopy measurements. The optical response of the low Zn content α-brasses is shown to have a distinctly different origin to that in the higher content β′, γ and ε-brasses. The response of β′-brass is unique in that it is strongly influenced by an overdamped plasmon excitation and this alloy will also have a strong surface plasmon response. - Highlights: • Study of the electronic structure and optical response of the Cu–Zn brasses. • Agreement between experiment and calculation of the dielectric functions. • α-brasses optical response is dominated by transitions from the top of the d-band. • In the other brasses it is transitions around the Fermi level. • β′-brass response is dominateed by an overdamped bulk plasmonic response.

  4. High-resolution photoelectron spectroscopy analysis of sulfidation of brass at the rubber/brass interface

    International Nuclear Information System (INIS)

    Ozawa, Kenichi; Kakubo, Takashi; Shimizu, Katsunori; Amino, Naoya; Mase, Kazuhiko; Komatsu, Takayuki

    2013-01-01

    Highlights: ► Chemical composition at the rubber/brass interface is investigated. ► The 2-min vulcanization reaction is enough to convert the interface composition. ► Five S-containing species are identified at the interface. ► Strong rubber–brass adhesion is related to the Cu 2 S/CuS ratio. ► Degradation of adhesion proceeds along with desulfidation of the interface. - Abstract: High resolution photoelectron spectroscopy is utilized to investigate the chemical composition at the rubber/brass interface to elucidate the origin of strong adhesion as well as the degradation between rubber and brass. Special attention has been given to copper sulfides formed at the interface during the vulcanization reaction at 170 °C. At least five sulfur-containing species are identified in the adhesive interlayer including crystalline CuS and amorphous Cu x S (x ≃ 2). These copper sulfide species are not uniformly distributed within the layer, but there exits the concentration gradation; the concentration of Cu x S is high in the region on the rubber side and is diminished in the deeper region, while vice versa for that of CuS. Degradation of the interface adhesive strength by prolonged vulcanization arises from the decrease in the Cu x S/CuS ratio accompanying desulfurization of the adhesive layer.

  5. Phase diagrams of laser-processed nanoparticles of brass

    Energy Technology Data Exchange (ETDEWEB)

    Kazakevich, P.V. [Wave Research Center of A.M. Prokhorov General Physics Institute of the Russian Academy of Sciences 38, Vavilov Street, 119991 Moscow (Russian Federation); Simakin, A.V. [Wave Research Center of A.M. Prokhorov General Physics Institute of the Russian Academy of Sciences 38, Vavilov Street, 119991 Moscow (Russian Federation); Shafeev, G.A. [Wave Research Center of A.M. Prokhorov General Physics Institute of the Russian Academy of Sciences 38, Vavilov Street, 119991 Moscow (Russian Federation); Monteverde, F. [Electron Microscopy Unit, Materia Nova, Avenue Copernic 1, B-7000 Mons (Belgium); Wautelet, M. [Condensed Matter Physics, University of Mons-Hainaut, 23, Avenue Maistriau, B-7000 Mons (Belgium)]. E-mail: michel.wautelet@umh.ac.be

    2007-07-31

    Nanoparticles of brass are prepared by ablation of a brass target in ethanol using radiation of a copper-vapor laser at various laser fluences. The nanoparticles are characterized by TEM and optical spectroscopy. The multipulse laser irradiation leads to formation both the nanoparticles in liquid and well-ordered micro-structures on a surface of a target. It is revealed that both the morphology and absorption spectra of brass nanoparticles depend on presence of the micro-structures. Nanoparticles with the various phase diagrams are formed from a flat brass surface and from the same surface with micro-structures. The results are compared with a model of phase diagrams, in which size and composition effects are taken into account.

  6. Standing wave brass-PZT square tubular ultrasonic motor.

    Science.gov (United States)

    Park, Soonho; He, Siyuan

    2012-09-01

    This paper reports a standing wave brass-PZT tubular ultrasonic motor. The motor is composed of a brass square tube with two teeth on each tube end. Four PZT plates are attached to the outside walls of the brass tube. The motor requires only one driving signal to excite vibration in a single bending mode to generate reciprocating diagonal trajectories of teeth on the brass tube ends, which drive the motor to rotate. Bi-directional rotation is achieved by exciting different pairs of PZT plates to switch the bending vibration direction. Through using the brass-PZT tube structure, the motor can take high magnitude vibration to achieve a high output power in comparison to PZT tube based ultrasonic motors. Prototypes are fabricated and tested. The dimension of the brass-PZT tube is 3.975mm×3.975mm×16mm. Measured performance is a no-load speed of >1000RPM, a stall torque of 370μNm and a maximum output power of 16 mW when a sinusoidal driving voltage of 50V is applied. The working frequencies of the motor are 46,050Hz (clockwise) and 46,200Hz (counter-clockwise). Copyright © 2012. Published by Elsevier B.V.

  7. High-resolution photoelectron spectroscopy analysis of sulfidation of brass at the rubber/brass interface

    Energy Technology Data Exchange (ETDEWEB)

    Ozawa, Kenichi, E-mail: ozawa.k.ab@m.titech.ac.jp [Department of Chemistry and Materials Science, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8551 (Japan); Kakubo, Takashi; Shimizu, Katsunori; Amino, Naoya [Yokohama Rubber Co., Ltd., Oiwake, Hiratsuka 254-8601 (Japan); Mase, Kazuhiko [Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba 305-0801 (Japan); Komatsu, Takayuki [Department of Chemistry and Materials Science, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8551 (Japan)

    2013-01-01

    Highlights: Black-Right-Pointing-Pointer Chemical composition at the rubber/brass interface is investigated. Black-Right-Pointing-Pointer The 2-min vulcanization reaction is enough to convert the interface composition. Black-Right-Pointing-Pointer Five S-containing species are identified at the interface. Black-Right-Pointing-Pointer Strong rubber-brass adhesion is related to the Cu{sub 2}S/CuS ratio. Black-Right-Pointing-Pointer Degradation of adhesion proceeds along with desulfidation of the interface. - Abstract: High resolution photoelectron spectroscopy is utilized to investigate the chemical composition at the rubber/brass interface to elucidate the origin of strong adhesion as well as the degradation between rubber and brass. Special attention has been given to copper sulfides formed at the interface during the vulcanization reaction at 170 Degree-Sign C. At least five sulfur-containing species are identified in the adhesive interlayer including crystalline CuS and amorphous Cu{sub x}S (x Asymptotically-Equal-To 2). These copper sulfide species are not uniformly distributed within the layer, but there exits the concentration gradation; the concentration of Cu{sub x}S is high in the region on the rubber side and is diminished in the deeper region, while vice versa for that of CuS. Degradation of the interface adhesive strength by prolonged vulcanization arises from the decrease in the Cu{sub x}S/CuS ratio accompanying desulfurization of the adhesive layer.

  8. A novel approach to improving resistance to dezincification of diphasic brass

    Energy Technology Data Exchange (ETDEWEB)

    Hung, Chang-Yu; Lin, Chi-Ming; Hsieh, Chih-Chun; Li, Chia-Chun; Wu, Paxon Ti-Yuan; Chen, Kuan-Ting; Wu, Weite, E-mail: wwu@dragon.nchu.edu.tw

    2016-06-25

    Dezincification-resistant brasses have been developed and refined for nearly 100 years, and lead (Pb) doped brass fittings have played a large role in the transport of potable water. However, due to Pb toxicity, restrictions have been placed on the amount of Pb that can be added to brass, and in general there is no safe level of Pb. In this study, 0.02 wt.% addition of Niobium (Nb) to diphasic brass (also know as duplex brass) was found to significantly improve resistance to dezincification when compared with a 0.20 wt.% doping level of Pb. Nb prevents dezincification in two ways: by alloying with β-phase to suppress the preferential dissolution of Zn and by forming a passivation layer incorporated with Nb that serves as a barrier against chloride ions in CuCl{sub 2} solution. As a result, it is expected that a Nb-doped diphasic brass will not negatively impact industrial application of duplex brass. - Highlights: • Nb doped diphasic brass improves resistance to dezincification. • Nb-doped diphasic prevents dezincification by alloying with β-phase. • Forming a passivation layer incorporated with Nb.

  9. Metallurgical characterization of brass objects from the Akko 1 shipwreck, Israel

    International Nuclear Information System (INIS)

    Ashkenazi, D.; Cvikel, D.; Stern, A.; Klein, S.; Kahanov, Y.

    2014-01-01

    The Akko 1 shipwreck was a small Egyptian armed vessel or auxiliary naval brig built in the eastern Mediterranean at the beginning of the 19th century. During the underwater excavations, about 230 brass hook-and-eye closures were found, mainly in the bow area. In addition, 158 brass cases were found, mainly between midships and the aft extremity of the shipwreck. Metallurgical non-destructive and destructive characterizations of selected items were performed, including radiographic testing, XRF, lead isotope analysis, optical microscopy, SEM–EDS and microhardness tests. The hook-and-eye closures and the cases were both found to be made of binary copper–zinc alloy (about 30 wt.% zinc). While the brass cases were made from rolled sheets, hand-made using simple tools, and joined by tin–lead soldering material, the brass hook-and-eye closures were hand-made from drawn brass wire, and manufactured from commercial drawn brass bars by a cold-working process. The lead isotope analyses suggest different provenances of the raw materials used for making the brass objects, thus the different origins of the ores may hint that the brass wire and sheet were imported to the workshops in which the objects were manufactured. - Highlights: • Brass cases and hook-and-eye closures were retrieved from the Akko 1 shipwreck. • Both types of objects were made of binary copper–zinc alloy (about 30 wt.% zinc). • The cases were hand-made from rolled sheets and joined by tin–lead soldering. • Hook-and-eye closures were made from drawn brass wire manufactured by cold-working. • Lead isotope analyses suggest that the origins of the raw material were diverse

  10. Wettability transition of laser textured brass surfaces inside different mediums

    Science.gov (United States)

    Yan, Huangping; Abdul Rashid, Mohamed Raiz B.; Khew, Si Ying; Li, Fengping; Hong, Minghui

    2018-01-01

    Hydrophobic surface on brass has attracted intensive attention owing to its importance in scientific research and practical applications. Laser texturing provides a simple and promising method to achieve it. Reducing wettability transition time from hydrophilicity to hydrophobicity or superhydrophobicity remains a challenge. Herein, wettability transition of brass surfaces with hybrid micro/nano-structures fabricated by laser texturing was investigated by immersing the samples inside different mediums. Scanning electron microscopy, energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy and surface contact angle measurement were employed to characterize surface morphology, chemical composition and wettability of the fabricated surfaces of brass samples. Wettability transition time from hydrophilicity to hydrophobicity was shortened by immersion into isopropyl alcohol for a period of 3 h as a result of the absorption and accumulation of organic substances on the textured brass surface. When the textured brass sample was immersed into sodium bicarbonate solution, flower-like structures on the sample surface played a key role in slowing down wettability transition. Moreover, it had the smallest steady state contact angle as compared to the others. This study provides a facile method to construct textured surfaces with tunable wetting behaviors and effectively extend the industrial applications of brass.

  11. Study unique artistic lopburi province for design brass tea set of bantahkrayang community

    Science.gov (United States)

    Pliansiri, V.; Seviset, S.

    2017-07-01

    The objectives of this study were as follows: 1) to study the production process of handcrafted Brass Tea Set; and 2) to design and develop the handcrafted of Brass Tea Set. The process of design was started by mutual analytical processes and conceptual framework for product design, Quality Function Deployment, Theory of Inventive Problem Solving, Principles of Craft Design, and Principle of Reverse Engineering. The experts in field of both Industrial Product Design and Brass Handicraft Product, have evaluated the Brass Tea Set design and created prototype of Brass tea set by the sample of consumers who have ever bought the Brass Tea Set of Bantahkrayang Community on this research. The statistics methods used were percentage, mean ({{{\\overline X}} = }) and standard deviation (S.D.) 3. To assess consumer satisfaction toward of handcrafted Brass tea set was at the high level.

  12. Mechanistic study of the rubber-brass adhesion interphase

    Science.gov (United States)

    Ashirgade, Akshay

    Brass-plated steel tire cords form an essential strengthening component of a radial automobile tire. Adhesion between rubber compound and brass-plated steel tire cord is crucial in governing the overall performance of tires. The rubber-brass interfacial adhesion is influenced by the chemical composition and thickness of the interfacial layer. It has been shown that the interfacial layer consists mainly of sulfides and oxides of copper and zinc. This thesis discusses the effect of changes in the chemical composition and the structure of the interfacial layers due to addition of adhesion promoter resins. Grazing incidence X-Ray Diffraction (GIXRD) experiments were run on sulfidized polished brass coupons previously bonded to six experimental rubber compounds. It was confirmed that heat and humidity conditions lead to physical and chemical changes of the rubber-steel tire cord interfacial layer, closely related to the degree of rubber-brass adhesion. Morphological transformation of the interfacial layer led to loss of adhesion after aging. The adhesion promoter resins inhibit unfavorable morphological changes in the interfacial layer thus stabilizing it during aging and prolonging failure. Tire cord adhesion tests illustrated that the one-component resins improved adhesion after aging using a rubber compound with lower cobalt loading. Based on the acquired diffraction profiles, these resins were also found to impede crystallization of the sulfide layer after aging leading to improved adhesion. Secondary Ion Mass Spectrometry (SIMS) depth profiles, SEM micrographs and AFM images strongly corroborated the findings from GIXRD. FTIR was utilized in a novel way to understand the degradation mechanism due to aging. A model for rubber and interfacial layer degradation is proposed to illustrate the effect of aging and the one-component resins. This interfacial analysis adds valuable new information to our understanding of the complex nature of the rubber-brass bonding

  13. Physiology and prospects of bimanual tracheoesophageal brass instrument play

    NARCIS (Netherlands)

    Hilgers, F. J. M.; Dirven, R.; Jacobi, I.; van den Brekel, M. W. M.

    2015-01-01

    This study investigated whether trachea pressures during brass instrument play of laryngectomised patients are within the range of those measured during tracheoesophageal voicing, and whether application of an automatic speaking valve can 'free' both hands to play a brass instrument. Objective

  14. Physiology and prospects of bimanual tracheoesophageal brass instrument play

    NARCIS (Netherlands)

    Hilgers, F.J.M.; Dirven, R.; Jacobi, I.; van den Brekel, M.W.M.

    2015-01-01

    This study investigated whether trachea pressures during brass instrument play of laryngectomised patients are within the range of those measured during tracheoesophageal voicing, and whether application of an automatic speaking valve can ‘free’ both hands to play a brass instrument. Objective

  15. X-ray fluorescence analysis of ancient and medieval brass artifacts from south Moravia

    International Nuclear Information System (INIS)

    Hložek, M.; Komoróczy, B.; Trojek, T.

    2012-01-01

    This paper deals with an investigation of archeological finds using X-ray fluorescence analysis and microanalysis. The main aim of the investigation was to prove the production of brass in the South Moravian Region (part of the Czech Republic) in former times. The probable brass production technology is described. Various objects dating back to Antiquity and to the Middle Ages were investigated using two X-ray fluorescence systems, and the results of the analyses are discussed. The measurements showed, e.g., that fragments of Roman scale armor and a belt fitting dating back to Antiquity were made of brass. Brass was also identified on the surfaces of various ancient and medieval molds and melting pots. - Highlights: ► Semiquantitative X-ray fluorescence analysis of archeological finds. ► Two different gilding techniques of a brass belt terminal found in Brno. ► Use of brass before the Great Moravian period. ► Evidence of brass casting in the 12th century in Brno.

  16. STAGNATION TIME, COMPOSITION, PH, AND ORTHOPHOSPHATE EFFECTS ON METAL LEACHING FROM BRASS

    Science.gov (United States)

    Plumbing products made of brass and similar alloys are the only lead containing materials still installed in drinking water systems and, by law, may contain up to 8% lead. Brass ranges in metal composition depending on its application. Brass is composed of approximately 60 to 80%...

  17. A comparison of fingerprint sweat corrosion of different alloys of brass.

    Science.gov (United States)

    Sykes, Stephanie; Bond, John W

    2013-01-01

    Fingerprint sweat from 40 donors was deposited onto samples of five α and α + β phase brasses, comprising five alloys with different copper and zinc concentrations, two of which also had the addition of small concentrations of lead. Visual grading of the visibility of the corrosion revealed that brasses with the least amount of zinc produced the most visible and fully formed fingerprints from the most donors. Consideration of previously reported mechanisms for the corrosion of brass suggests red copper (I) oxide as a likely corrosion product for low zinc brasses, and a consideration of the color, composition, and solubility of fingerprint sweat corrosion products suggests that copper (I) oxide produces good contrast and visibility with the brass substrate. Scanning electron microscope images of the corrosion of all five alloys confirmed the enhanced contrast between corroded and uncorroded areas for low zinc alloys. © 2012 American Academy of Forensic Sciences.

  18. X-ray fluorescence analysis of ancient and medieval brass artifacts from south Moravia

    Energy Technology Data Exchange (ETDEWEB)

    Hlozek, M. [Methodical Centre of Conservation-Technical Museum in Brno, Purkynova 105, 612 00 Brno (Czech Republic); Komoroczy, B. [Institute of Archeology of the Academy of Science of the Czech Republic, Kralovopolska 147, 612 00 Brno (Czech Republic); Trojek, T., E-mail: tomas.trojek@fjfi.cvut.cz [Department of Dosimetry and Application of Ionizing Radiation, Czech Technical University in Prague, Brehova 7, 115 19 Praha 1 (Czech Republic)

    2012-07-15

    This paper deals with an investigation of archeological finds using X-ray fluorescence analysis and microanalysis. The main aim of the investigation was to prove the production of brass in the South Moravian Region (part of the Czech Republic) in former times. The probable brass production technology is described. Various objects dating back to Antiquity and to the Middle Ages were investigated using two X-ray fluorescence systems, and the results of the analyses are discussed. The measurements showed, e.g., that fragments of Roman scale armor and a belt fitting dating back to Antiquity were made of brass. Brass was also identified on the surfaces of various ancient and medieval molds and melting pots. - Highlights: Black-Right-Pointing-Pointer Semiquantitative X-ray fluorescence analysis of archeological finds. Black-Right-Pointing-Pointer Two different gilding techniques of a brass belt terminal found in Brno. Black-Right-Pointing-Pointer Use of brass before the Great Moravian period. Black-Right-Pointing-Pointer Evidence of brass casting in the 12th century in Brno.

  19. Structural Transformations Versus Hard Particles Motion in the Brass Ingots

    Directory of Open Access Journals (Sweden)

    Wołczyński W.

    2017-12-01

    Full Text Available A mathematical method for the forecast of the type of structure in the steel static ingot has been recently developed. Currently, the method has been applied to structural zones prediction in the brass ingots obtained by the continuous casting. Both the temperature field and thermal gradient field have been calculated in order to predict mathematically the existence of some structural zones in the solidifying brass ingot. Particularly, the velocity of the liquidus isotherm movement and thermal gradient behavior versus solidification time have been considered. The analysis of the mentioned velocity allows the conclusion that the brass ingots can evince: chilled columnar grains-, (CC, fine columnar grains-, (FC, columnar grains-, (C, equiaxed grains zone, (E, and even the single crystal, (SC, situated axially. The role of the mentioned morphologies is analyzed to decide whether the hard particles existing in the brass ingots can be swallowed or rejected by the solid / liquid (s/l interface of a given type of the growing grains. It is suggested that the columnar grains push the hard particles to the end of a brass ingot during its continuous casting.

  20. Structural evolution and mechanisms of fatigue in polycrystalline brass

    International Nuclear Information System (INIS)

    Vejloe Carstensen, J.

    1998-03-01

    The plastic strain controlled fatigue behaviour of polycrystalline Cu-15%Zn and Cu-30%Zn has been investigated with the aim of studying the effect of slip mode modification by the addition of zinc to copper. It has been clearly demonstrated, that true cyclic saturation does not occur in the plastic strain controlled fatigue of brass. This complicates the contstruction of a cyclic stress-strain (CSS) curve and thus the comparison with copper. A method to overcome this complication has been suggested. Surface observations on fatigued brass specimens show that individual grains tend to deform by Sachs type single slip. This behaviour has been described by the self-consistent Sachs-Eshelby model, which provides estimates of the CSS curve for brass polycrystals. Successive stages of primary hardening, softening and secondary hardening has been observed in the plastic strain controlled fatigue of brass. It has been found that the primary hardening is attributed to an increase of intergranular stresses whereas the secondary hardening apparently is attributed to an increase of friction stresses. Investigations of the structural evolution show that the softening behaviour can be explained by the presence of short-range order (SRO). SRO promote the formation of extended dipole arrays which hardens the material. The formation of intense shear bands destroy the dipole arrays, which explains the cyclic softening. The present results reveal that Cu-30%Zn in a pure planar slip alloy, while Cu-15%Zn displays both planar and wavy slip. The mechanical and structural behaviour observed in brass resembles recent observations in 316L austenitic stainless steels, and the present results reveal that Cu-30%Zn and 316L have approximately the same fatigue life curve. This emphasizes brass as being a convenient model system for the industrially important austenitic steels. (au)

  1. Corrosion inhibition of brass by aliphatic amines

    International Nuclear Information System (INIS)

    Taha, K. K.; Sheshadri, B. S; Ahmed, M. F.

    2005-01-01

    Aliphatic amines hexylamine (HCA), octylamine (OCA) and decylamine (DCA) have been used as corrosion inhibitors for (70/30) brass in 0.I M HCIO 4 . The inhibitor efficiency (%P) calculated using weight loss, Tafel extrapolation, linear polarization and impedance methods was found to be in the order DCA> OCA> HCA. These adsorb on brass surface following bockris-swinkels' isotherm. DCA, OCA and HCA displaced 4, 3 and 2 molecules of water from interface respectively. Displacement of water molecules brought a great reorganization of double layer at the interface. These amines during corrosion form complexes with dissolved zinc and copper ions.(Author)

  2. The Paramagnetism of Dissolved Mn in {alpha} and {beta} Brasses

    Energy Technology Data Exchange (ETDEWEB)

    Myers, H P; Westin, R

    1962-12-15

    Paramagnetic susceptibility measurements have been made on {alpha} and {beta} brasses containing {approx} 1 w/o Mn. The susceptibility varied with temperature according to the Curie Weiss law and the Curie constant and thereby the Bohr magneton number per Mn atom were determined. Interpreted in terms of valency, Mn monovalent in copper has a valency in {alpha} brass which decreases progressively with zinc content attaining the value 0.58 at the limiting of composition. Mn in {beta} brass exhibits a valency 0.8. These results are not in keeping with previous values for the valency of manganese as determined from phase boundary relationships and electron to atom ratios.

  3. Experimental investigation on carbon nano tubes coated brass rectangular extended surfaces

    International Nuclear Information System (INIS)

    Senthilkumar, Rajendran; Prabhu, Sethuramalingam; Cheralathan, Marimuthu

    2013-01-01

    Finned surface has been extensively used for free convection cooling of internal combustion engines and several electronic kits etc. Here rectangular brass fin was preferred for analysis. Thermocouples were attached all over the surface of the fin in equal distances. The measurement of surface temperature and calculated convective heat transfer rate were reported for several heat input values. The overall system performance can be improved by enhancing heat transfer rate of extended surfaces. Based on the above requirement, brass surface was coated by carbon nano tubes. The temperature and heat transfer characteristics were investigated using Taguchi method for experimental design. Finally the performances of coated and non-coated rectangular brass fins were compared. The average percentage of increase in heat transfer rate was proved around 12% for carbon nanocoated rectangular brass fins. - Graphical abstract: The designed Natural and Forced convection Heat Transfer Test Rig measures the enhanced rate of heat transfer for nano coated rectangular fins than in non-coated fins. Highlights: ► Rectangular brass fins were preferred for convective heat transfer process. ► The rectangular brass fins are coated with multi wall carbon nano tubes in EBPVD process with nanometer thickness. ► Temperature and heat transfer rate were investigated for nanocoated and non-coated fins by using Taguchi method. ► Multi wall carbon nanotubes act as a pin fin to enhance surface area for effective convective heat transfer rate.

  4. Laser Brazing Characteristics of Al to Brass with Zn-Based Filler

    Science.gov (United States)

    Tan, Caiwang; Liu, Fuyun; Sun, Yiming; Chen, Bo; Song, Xiaoguo; Li, Liqun; Zhao, Hongyun; Feng, Jicai

    2018-05-01

    Laser brazing of Al to brass in lap configuration with Zn-based filler was performed in this work. The process parameters including laser power, defocused distance were found to have a significant influence on appearance, microstructure and mechanical properties. The process parameters were optimized to be laser power of 2700 W and defocusing distance of + 40 mm from brass surface. In addition, preheating exerted great influence on wetting and spreading ability of Zn filler on brass surface. The microstructure observation showed the thickness of reaction layer (CuZn phase) at the interface of the brass side would grow with the increase in laser power and the decrease in the laser defocusing distance. Moreover, preheating could increase the spreading area of the filler metal and induced the growth of the reaction layer. The highest tensile-shear load of the joint could reach 2100 N, which was 80% of that of Al alloy base metal. All the joints fractured along the CuZn reaction layer and brass interface. The fracture morphology displayed the characteristics of the cleavage fracture when without preheating before welding, while it displayed the characteristics of the quasi-cleavage fracture with preheating before welding.

  5. Structural evolution and mechanisms of fatigue in polycrystalline brass

    Energy Technology Data Exchange (ETDEWEB)

    Vejloe Carstensen, J

    1998-03-01

    The plastic strain controlled fatigue behaviour of polycrystalline Cu-15%Zn and Cu-30%Zn has been investigated with the aim of studying the effect of slip mode modification by the addition of zinc to copper. It has been clearly demonstrated, that true cyclic saturation does not occur in the plastic strain controlled fatigue of brass. This complicates the contstruction of a cyclic stress-strain (CSS) curve and thus the comparison with copper. A method to overcome this complication has been suggested. Surface observations on fatigued brass specimens show that individual grains tend to deform by Sachs type single slip. This behaviour has been described by the self-consistent Sachs-Eshelby model, which provides estimates of the CSS curve for brass polycrystals. Successive stages of primary hardening, softening and secondary hardening has been observed in the plastic strain controlled fatigue of brass. It has been found that the primary hardening is attributed to an increase of intergranular stresses whereas the secondary hardening apparently is attributed to an increase of friction stresses. Investigations of the structural evolution show that the softening behaviour can be explained by the presence of short-range order (SRO). SRO promote the formation of extended dipole arrays which hardens the material. The formation of intense shear bands destroy the dipole arrays, which explains the cyclic softening. The present results reveal that Cu-30%Zn in a pure planar slip alloy, while Cu-15%Zn displays both planar and wavy slip. The mechanical and structural behaviour observed in brass resembles recent observations in 316L austenitic stainless steels, and the present results reveal that Cu-30%Zn and 316L have approximately the same fatigue life curve. This emphasizes brass as being a convenient model system for the industrially important austenitic steels. (au) 9 tabs., 94 ills., 177 refs.; The thesis is also available as DCAMM-R-S80 and as an electronic document on http://www.risoe.dk/rispubl

  6. Identification of force constants in β-brass

    DEFF Research Database (Denmark)

    Norvell, J. C.; Als-Nielsen, Jens Aage

    1969-01-01

    The phonon dispersion curves of β-brass have previously been measured by Gilat and Dolling and a fit was obtained to a Born-von Kármán model with forces extending to the fourth nearest neighbours. Although a factor of 10 was found between the second-nearest-neighbour Cu-Cu and Zn-Zn force constants......, the data did not allow an identification of these constants. By comparisons of neutron group intensities from two β-brass crystals, one with normal Cu and the other isotopically enriched with 65Cu, we are able to identify conclusively these force constants: αZn-Zn2nd similar, equals 10αCu-Cu2nd....

  7. Methods to improve the PVD coatability of brass by using diffusion barriers

    Science.gov (United States)

    Langer, Bernd

    Previous work involving PVD coatings on brass has used a combination of multilayers consisting of electroplated films like nickel or chromium and deposited decorative PVD coatings like TiN, TiAIN or ZrN systems. The disadvantages of these systems are the combination of wet electrochemistry and high tech vacuum processes. Furthermore the allergic reaction to nickel and the toxic nature of Cr(VI) must be considered.There is a need for intermediate layers to 'seal-off the brass in order to avoid the evaporation of zinc in vacuum using a diffusion barrier. Furthermore the intermediate layers are required to act as a corrosion barrier.This thesis reports on the development of PVD coatings on heat sensitive brass substrate materials utilising ABS technology with Al, CuAl8 and Nb targets as vapour sources.The brass pretreatment includes careful grinding, polishing and cleaning steps as well as steered arc metal ion etching using the above target materials. The coatings are produced at temperatures between 100 and 250°C in the unbalanced magnetron mode, including layers made from Al, Al-Nb, CuA18, CuAl8-Nb and Nb.Scratch adhesion and Rockwell indentation tests are found not to be directly applicable to the system of soft brass and ductile coating(s). Therefore a new classification for both scratch and indentation tests was defined. The best adhesion was shown by the CuA18 coatings on brass. Corrosion tests showed good results for the Al coatings and poor results for the pure Nb coatings directly applied on brass. The best corrosion result was obtained with a CuAl8-Nb layer system. This layer system also offers very good barrier behaviour concerning Zn diffusion.Other investigations like Glow Discharge Optical Emission Spectroscopy (GDOES), Scanning Electron Microscopy (SEM) imaging, Transmission Electron Microscopy (TEM) and X-ray Diffraction (XRD) were undertaken to characterise the new coating systems for brass.

  8. Potential of Brass to Remove Inorganic Hg(II) from Aqueous Solution through Amalgamation.

    Science.gov (United States)

    Wenke, Axel; Bollen, Anne; Richard, Jan-Helge; Biester, Harald

    2016-06-01

    Brass shavings (CuZn45) were tested for their efficiency to remove Hg(II) from contaminated groundwater through amalgamation. The study was focused on long-term retention efficiency, the understanding of the amalgamation process and kinetics, and influences of filter surface alteration. Column tests were performed with brass filters (thickness 3 to 9 cm) flushed with 1000 μg/L Hg solution for 8 hours under different flow rates (300 to 600 mL/h). Brass filters consistently removed >98% of Hg from solution independent of filter thickness and flow rate. In a long-term experiment (filter thickness 2 cm), Hg retention decreased from 96 to 92% within 2000 hours. Batch and column experiments for studying kinetics of Hg removal indicate ~100% Hg removal from solution within only 2 hours. Solid-phase mercury thermo-desorption analysis revealed that Hg(0) diffusion into the brass surface controls kinetics of mercury retention. Brass surface alteration could be observed, but did not influence Hg retention.

  9. Experimenting with Brass Musical Instruments.

    Science.gov (United States)

    LoPresto, Michael C.

    2003-01-01

    Describes experiments to address the properties of brass musical instruments that can be used to demonstrate sound in any level physics course. The experiments demonstrate in a quantitative fashion the effects of the mouthpiece and bell on the frequencies of sound waves and thus the musical pitches produced. (Author/NB)

  10. Structure Analysis and Properties of Unleaded Brasses

    Directory of Open Access Journals (Sweden)

    Rzadkosz S.

    2015-04-01

    Full Text Available The analysis of brasses regarding their microstructure, mechanical properties and ecological characteristics has been presented. The influence of characteristic alloying elements contained in the brasses and the possibilities of replacing them with other elements have been assessed. The paper contains the results of studies on the influence of chosen additional elements shaping the structure and properties of unleaded alloys based on Cu-Zn system as the matrix. The research aimed at determining the mechanism and the intensity of influence of such additives as tellurium and bismuth. The microstructures were investigated with the help of light microscopy and scanning electron microscopy with X-ray microanalysis (SEM-EDS for determining significant changes of the properties.

  11. Copper and brass aged at open circuit potential in slightly alkaline solutions

    International Nuclear Information System (INIS)

    Procaccini, R.; Vazquez, M.; Cere, S.

    2009-01-01

    Surface oxide films were grown on 99.99% copper and brass (copper-zinc alloy, Cu77Zn21Al2) in 0.1 mol L -1 borax solution at open circuit potential and were characterized using various experimental techniques. The composition of the passive films formed in situ on the different materials was studied using differential reflectance spectroscopy. The thickness of the oxide layers on copper and brass was compared by chronopotentiometric curves and potentiodynamic reductions. The electrical properties of each oxide were analyzed by means of electrochemical impedance spectroscopy. Their influence on the oxygen reduction reaction was also investigated using voltammetry hydrodynamic tools such as the rotating disk electrode. The results show that the incorporation of Zn to Cu in brass changes the composition and the thickness of the surface film. The films grown on brass tend to be thicker but less resistive and Zn compounds incorporate to the film. This is supported by results from reflectance and impedance spectroscopy. The kinetics of oxygen reduction is strongly inhibited on oxidized electrodes, particularly in the case of brass. The global number of exchanged electrons remains close to four and seems to be independent of the presence of surface oxides.

  12. Diffusion phenomenon at the interface of Cu-brass under a strong gravitational field

    Energy Technology Data Exchange (ETDEWEB)

    Ogata, Yudai; Tokuda, Makoto; Januszko, Kamila; Khandaker, Jahirul Islam; Mashimo, Tsutomu, E-mail: mashimo@gpo.kumamoto-u.ac.jp [Institute of Pulsed Power Science, Kumamoto University, Kumamoto 860-8555 (Japan); Iguchi, Yusuke [Department of Solid State Physics, Debrecen University, 4032 Debrecen (Hungary); Ono, Masao [Advanced Science Research Center, Japan Atomic Energy Agency (JAEA), Ibaraki 319-1195 (Japan)

    2015-03-28

    To investigate diffusion phenomenon at the interface between Cu and brass under a strong gravitational field generated by ultracentrifuge apparatus, we performed gravity experiments on samples prepared by electroplating with interfaces normal and parallel to the direction of gravity. For the parallel-mode sample, for which sedimentation cannot occur thorough the interface, the concentration change was significant within the lower gravity region; many pores were observed in this region. Many vacancies arising from crystal strain due to the strong gravitational field moved into the lower gravity region, and enhanced the atoms mobilities. For the two normal-mode samples, which have interface normal to the direction of gravity, the composition gradient of the brass-on-Cu sample was steeper than that for Cu-on-brass. This showed that the atoms of denser Cu diffuse in the direction of gravity, whereas Zn atoms diffuse in the opposite direction by sedimentation. The interdiffusion coefficients became higher in the Cu-on-brass sample, and became lower in the brass-on-Cu sample. This rise may be related to the behavior of the vacancies.

  13. Role of the Structural and Thermal Peclet Numbers in the Brass Continuous Casting

    Directory of Open Access Journals (Sweden)

    Kwapisiński P.

    2017-06-01

    Full Text Available The Structural Peclet Number has been estimated experimentally by analyzing the morphology of the continuously cast brass ingots. It allowed to adapt a proper development of the Ivantsov’s series in order to formulate the Growth Law for the columnar structure formation in the brass ingots solidified in stationary condition. Simultaneously, the Thermal Peclet Number together with the Biot, Stefan, and Fourier Numbers is used in the model describing the heat transfer connected with the so-called contact layer (air gap between an ingot and crystallizer. It lead to define the shape and position of the s/l interface in the brass ingot subjected to the vertical continuous displacement within the crystallizer (in gravity. Particularly, a comparison of the shape of the simulated s/l interface at the axis of the continuously cast brass ingot with the real shape revealed at the ingot axis is delivered. Structural zones in the continuously cast brass ingot are revealed: FC - fine columnar grains, C - columnar grains, E - equiaxed grains, SC - single crystal situated axially.

  14. Temperature Dependence of Short-Range Order in β-Brass

    DEFF Research Database (Denmark)

    Dietrich, O.W.; Als-Nielsen, Jens Aage

    1967-01-01

    Critical scattering of neutrons around the superlattice reflections (1, 0, 0) and (1, 1, 1) from a single crystal of beta-brass has been measured at temperatures from 2 to 25deg C above the transition temperature. The temperature dependence of the critical peak intensity, proportional to the susc......Critical scattering of neutrons around the superlattice reflections (1, 0, 0) and (1, 1, 1) from a single crystal of beta-brass has been measured at temperatures from 2 to 25deg C above the transition temperature. The temperature dependence of the critical peak intensity, proportional...

  15. Electrochemical behaviour of brass in chloride solution concentrations found in eccrine fingerprint sweat

    Energy Technology Data Exchange (ETDEWEB)

    Bond, John W., E-mail: jwb13@le.ac.uk [Department of Chemistry, George Porter Building, University of Leicester, University Road, Leicester LE1 7RH (United Kingdom); Lieu, Elaine [Department of Physics and Astronomy, University of Leicester, University Road, Leicester LE1 7RH (United Kingdom)

    2014-09-15

    Highlights: • Corrosion of brass in NaCl concentrations found in eccrine sweat was investigated. • Concentrations < 0.2 M produce a layer of mainly zinc oxide after 24 h. • A concentration of 0.2 M enables active corrosion of brass at room temperature. • 0.2 M NaCl gives both zinc and copper dissolution. • 24-h immersion of brass in 0.2 M NaCl gives an oxide film thickness of 1.3 nm. - Abstract: In this work, the corrosion properties of α phase brass immersed in concentrations of aqueous NaCl solutions that are typically found in eccrine fingerprint sweat and range between 0.01 M and 0.2 M have been analysed. Analysis methods employed were electrochemical techniques, X-ray photoelectron spectroscopy and optical profiling. For NaCl concentrations <0.2 M, active corrosion did not occur although, after a period of 24 h, a passivating layer of mainly zinc oxide formed. At a concentration of 0.2 M active corrosion did occur, with measured corrosion potentials consistent with both brass and copper dissolution. A 1 h contact time at this concentration (0.2 M) resulted in the formation of a zinc oxide passivating layer with the surface ratio of zinc oxide to copper oxide increasing with time. Film thickness was calculated to be of the order of 1.3 nm after 24 h contact. Formation of oxide layers on brass by fingerprint sweat as observed here may well have implications for the successful investigation of crime by the visualisation of corrosion fingerprint ridge patterns or the reduction of hospital environmental contamination by hand contact with brass objects such as door handles or taps.

  16. Effect of ion irradiation on the surface, structural and mechanical properties of brass

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, Shahbaz; Bashir, Shazia, E-mail: shaziabashir@gcu.edu.pk; Ali, Nisar; Umm-i-Kalsoom,; Yousaf, Daniel; Faizan-ul-Haq,; Naeem, Athar; Ahmad, Riaz; Khlaeeq-ur-Rahman, M.

    2014-04-01

    Highlights: • Brass targets were exposed to carbon ions of energy 2 MeV. • The effect of ion dose has been investigated. • The surface morphology is investigated by SEM analysis. • XRD analysis is performed to reveal structural modification. • Mechanical properties were investigated by tensile testing and microhardness testing. - Abstract: Modifications to the surface, structural and mechanical properties of brass after ion irradiation have been investigated. Brass targets were bombarded by carbon ions of 2 MeV energy from a Pelletron linear accelerator for various fluences ranging from 56 × 10{sup 12} to 26 × 10{sup 13} ions/cm{sup 2}. A scanning electron microscope and X-ray diffractometer were utilized to analyze the surface morphology and crystallographic structure respectively. To explore the mechanical properties e.g., yield stress, ultimate tensile strength and microhardness of irradiated brass, an universal tensile testing machine and Vickers microhardness tester were used. Scanning electron microscopy results revealed an irregular and randomly distributed sputter morphology for a lower ion fluence. With increasing ion fluence, the incoherently shaped structures were transformed into dendritic structures. Nano/micro sized craters and voids, along with the appearance of pits, were observed at the maximum ion fluence. From X-ray diffraction results, no new phases were observed to be formed in the brass upon irradiation. However, a change in the peak intensity and higher and lower angle shifting were observed, which represents the generation of ion-induced defects and stresses. Analyses confirmed modifications in the mechanical properties of irradiated brass. The yield stress, ultimate tensile strength and hardness initially decreased and then increased with increasing ion fluence. The changes in the mechanical properties of irradiated brass are well correlated with surface and crystallographic modifications and are attributed to the generation

  17. Effect of ion irradiation on the surface, structural and mechanical properties of brass

    Science.gov (United States)

    Ahmad, Shahbaz; Bashir, Shazia; Ali, Nisar; Umm-i-Kalsoom; Yousaf, Daniel; Faizan-ul-Haq; Naeem, Athar; Ahmad, Riaz; Khlaeeq-ur-Rahman, M.

    2014-04-01

    Modifications to the surface, structural and mechanical properties of brass after ion irradiation have been investigated. Brass targets were bombarded by carbon ions of 2 MeV energy from a Pelletron linear accelerator for various fluences ranging from 56 × 1012 to 26 × 1013 ions/cm2. A scanning electron microscope and X-ray diffractometer were utilized to analyze the surface morphology and crystallographic structure respectively. To explore the mechanical properties e.g., yield stress, ultimate tensile strength and microhardness of irradiated brass, an universal tensile testing machine and Vickers microhardness tester were used. Scanning electron microscopy results revealed an irregular and randomly distributed sputter morphology for a lower ion fluence. With increasing ion fluence, the incoherently shaped structures were transformed into dendritic structures. Nano/micro sized craters and voids, along with the appearance of pits, were observed at the maximum ion fluence. From X-ray diffraction results, no new phases were observed to be formed in the brass upon irradiation. However, a change in the peak intensity and higher and lower angle shifting were observed, which represents the generation of ion-induced defects and stresses. Analyses confirmed modifications in the mechanical properties of irradiated brass. The yield stress, ultimate tensile strength and hardness initially decreased and then increased with increasing ion fluence. The changes in the mechanical properties of irradiated brass are well correlated with surface and crystallographic modifications and are attributed to the generation, augmentation, recombination and annihilation of the ion-induced defects.

  18. Antimicrobial brass coatings prepared on poly(ethylene terephthalate) textile by high power impulse magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Ying-Hung, E-mail: tieamo2002@gmail.com; Wu, Guo-Wei; He, Ju-Liang

    2015-03-01

    The goal of this work is to prepare antimicrobial, corrosion-resistant and low-cost Cu65Zn35 brass film on poly(ethylene terephthalate) (PET) fabric by high-power impulse magnetron sputtering (HIPIMS), which is known to provide high-density plasma, so as to generate a strongly adherent film at a reduced substrate temperature. The results reveal that the brass film grows in a layer-plus-island mode. Independent of their deposition time, the obtained films retain a Cu/Zn elemental composition ratio of 1.86 and exhibit primarily an α copper phase structure. Oxygen plasma pre-treatment for 1 min before coating can significantly increase film adhesion such that the brass-coated fabric of Grade 5 or Grade 4–5 can ultimately be obtained under dry and wet rubbing tests, respectively. However, a deposition time of 1 min suffices to provide effective antimicrobial properties for both Staphylococcus aureus and Escherichia coli. As a whole, the feasibility of using such advanced HIPIMS coating technique to develop durable antimicrobial textile was demonstrated. - Highlights: • Prepare antimicrobial, corrosion-resistant and low-cost Cu65Zn35 brass film on PET fabric by HIPIMS • Brass-coated fabric with excellent durability, even undergone rubbing and washing tests • Brass-coated fabric provides effective antimicrobial properties for E. coli and S. aureus. • After brass coating, PET fabric still retained its mechanical property.

  19. Antimicrobial brass coatings prepared on poly(ethylene terephthalate) textile by high power impulse magnetron sputtering

    International Nuclear Information System (INIS)

    Chen, Ying-Hung; Wu, Guo-Wei; He, Ju-Liang

    2015-01-01

    The goal of this work is to prepare antimicrobial, corrosion-resistant and low-cost Cu65Zn35 brass film on poly(ethylene terephthalate) (PET) fabric by high-power impulse magnetron sputtering (HIPIMS), which is known to provide high-density plasma, so as to generate a strongly adherent film at a reduced substrate temperature. The results reveal that the brass film grows in a layer-plus-island mode. Independent of their deposition time, the obtained films retain a Cu/Zn elemental composition ratio of 1.86 and exhibit primarily an α copper phase structure. Oxygen plasma pre-treatment for 1 min before coating can significantly increase film adhesion such that the brass-coated fabric of Grade 5 or Grade 4–5 can ultimately be obtained under dry and wet rubbing tests, respectively. However, a deposition time of 1 min suffices to provide effective antimicrobial properties for both Staphylococcus aureus and Escherichia coli. As a whole, the feasibility of using such advanced HIPIMS coating technique to develop durable antimicrobial textile was demonstrated. - Highlights: • Prepare antimicrobial, corrosion-resistant and low-cost Cu65Zn35 brass film on PET fabric by HIPIMS • Brass-coated fabric with excellent durability, even undergone rubbing and washing tests • Brass-coated fabric provides effective antimicrobial properties for E. coli and S. aureus. • After brass coating, PET fabric still retained its mechanical property

  20. Generation of nanoparticles of bronze and brass by laser ablation in liquid

    Energy Technology Data Exchange (ETDEWEB)

    Sukhov, I.A. [Wave Research Center of A.M. Prokhorov General Physics Institute of the Russian Academy of Sciences, 38, Vavilov Street, 119991 Moscow (Russian Federation); Shafeev, G.A., E-mail: Shafeev@kapella.gpi.ru [Wave Research Center of A.M. Prokhorov General Physics Institute of the Russian Academy of Sciences, 38, Vavilov Street, 119991 Moscow (Russian Federation); Voronov, V.V. [Wave Research Center of A.M. Prokhorov General Physics Institute of the Russian Academy of Sciences, 38, Vavilov Street, 119991 Moscow (Russian Federation); Sygletou, M. [Institute of Electronic Structure and Laser, Foundation for Research and Technology—Hellas (IESL-FORTH), P.O. Box 1527, Heraklion 711 10 (Greece); Department of Physics, University of Crete, Vassilika Vouton, GR-711 10, Heraklion (Greece); Stratakis, E.; Fotakis, C. [Institute of Electronic Structure and Laser, Foundation for Research and Technology—Hellas (IESL-FORTH), P.O. Box 1527, Heraklion 711 10 (Greece)

    2014-05-01

    Nanoparticles of brass and bronze are generated by ablation of corresponding bulk targets in liquid ethanol. The experiments were performed using three pulsed lasers with different pulse duration: ytterbium fiber laser (80 ns), a Neodymium:YAG laser (10 ps), and femtosecond Ti:sapphire laser (200 fs). The generated nanoparticles (NPs) are characterized by UV–vis absorption spectroscopy, X-ray diffractometry, Raman scattering, and Transmission Electron Microscopy. The size of generated NPs lies in the range 10–25 nm depending on the laser source. The X-ray diffractometry reveals the change of phase composition of brass NPs compared to the initial target in case of ablation with 80 ns laser source, while with 10 ps laser pulses this effect is less pronounced. Brass NPs generated with pico- and femtosecond laser radiation show the plasmon resonance in the vicinity of 560 nm and no plasmon peak for NPs generated with longer laser pulses. Raman analysis shows the presence of Cu{sub 2}O in generated NPs. The stability of generated NPs of both brass and bronze to oxidation is compared to that of Cu NPs generated in similar experimental conditions.

  1. 77 FR 23508 - Brass Sheet and Strip From France, Germany, Italy, and Japan

    Science.gov (United States)

    2012-04-19

    ...)] Brass Sheet and Strip From France, Germany, Italy, and Japan Determination On the basis of the record \\1... antidumping duty orders on brass sheet and strip from France, Germany, Italy, and Japan would be likely to... from France, Germany, Italy, and Japan: Investigation Nos. 731-TA-313, 314, 317, and 379 (Third Review...

  2. The brass-type texture and its deviation from the copper-type texture

    DEFF Research Database (Denmark)

    Leffers, Torben; Ray, R.K.

    2009-01-01

    Our basic aim with the present review is to address the classical problem of the “fcc rolling texture transition” – the fact that fcc materials may, depending on material parameters and rolling conditions, develop two different types of rolling textures, the copper-type texture and the brass...... the subject and sketch our approach for dealing with it. We then recapitulate the decisive progress made during the nineteen sixties in the empirical description of the fcc rolling texture transition and in lining up a number of possible explanations. Then follows a section about experimental investigations...... of the brass-type texture after the nineteen sixties covering texture measurements and microstructural investigations. The main observations are: (1) The brass-type texture deviates from the copper-type texture from an early stage of texture development. (2) Deformation twinning has a decisive effect...

  3. Determination of a brass alloy concentration composition using calibration-free laser-induced breakdown spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Achouri, M.; Baba-Hamed, T.; Beldjilali, S. A., E-mail: sidahmed.beldjilali@univ-usto.dz; Belasri, A. [Université des Sciences et de la Technologie d’Oran Mohamed Boudiaf USTO-MB, LPPMCA (Algeria)

    2015-09-15

    Laser-induced breakdown spectroscopy (LIBS) is a technique that can provide qualitative and quantitative measurements of the characteristics of irradiated metals. In the present work, we have calculated the parameters of the plasma produced from a brass alloy sample under the action of a pulsed Nd: YAG laser operating at 1064 nm. The emission lines of copper atoms (Cu I), zinc atoms (Zn I), and lead atoms (Pb I), which are elements of a brass alloy composition, were used to investigate the parameters of the brass plasma. The spectral profiles of Cu, Zn, and Pb lines have been used to extract the electron temperature and density of the brass alloy plasma. The characteristics of Cu, Zn, and Pb were determined quantatively by the calibration-free LIBS (CF-LIBS) method considering for accurate analysis that the laser-induced ablated plasma is optically thin in local thermodynamic equilibrium conditions and the plasma ablation is stoichiometric. The Boltzmann plot method was used to evaluate the plasma temperature, and the Stark broadened profiles were used to determine the electron density. An algorithm based on the experimentally measured values of the intensity of spectral lines and the basic laws of plasma physics was developed for the determination of Cu, Zn, and Pb concentrations in the brass sample. The concentrations C{sub CF-LIBS} calculated by CF-LIBS and the certified concentrations C{sub certified} were very close.

  4. Predicting the need for institutional care shortly after admission to rehabilitation: Rasch analysis and predictive validity of the BRASS Index.

    Science.gov (United States)

    Panella, L; La Porta, F; Caselli, S; Marchisio, S; Tennant, A

    2012-09-01

    Effective discharge planning is increasingly recognised as a critical component of hospital-based Rehabilitation. The BRASS index is a risk screening tool for identification, shortly after hospital admission, of patients who are at risk of post-discharge problems. To evaluate the internal construct validity and reliability of the Blaylock Risk Assessment Screening Score (BRASS) within the rehabilitation setting. Observational prospective study. Rehabilitation ward of an Italian district hospital. One hundred and four consecutively admitted patients. Using classical psychometric methods and Rasch analysis (RA), the internal construct validity and reliability of the BRASS were examined. Also, external and predictive validity of the Rasch-modified BRASS (RMB) score were determined. Reliability of the original BRASS was low (Cronbach's alpha=0.595) and factor analyses showed that it was clearly multidimensional. A RA, based on a reduced 7-BRASS item set (RMB), satisfied model's expectations. Reliability was 0.777. The RMB scores strongly correlated with the original BRASS (rho=0.952; P28 days (RR=7.6, 95%CI=1.8-31.9). This study demonstrated that the original BRASS was multidimensional and unreliable. However, the RMB holds adequate internal construct validity and is sufficiently reliable as a predictor of discharge problems for group, but not individual use. The application of tools and methods (such as the BRASS Index) developed under the biomedical paradigm in a Physical and Rehabilitation Medicine setting may have limitations. Further research is needed to develop, within the rehabilitation setting, a valid measuring tool of risk of post-discharge problems at the individual level.

  5. Photoelectron studies of machined brass surfaces

    Science.gov (United States)

    Potts, A. W.; Merrison, J. P.; Tournas, A. D.; Yacoot, A.

    UV photoelectron spectroscopy has been used to determine the surface composition of machined brass. The results show a considerable change between the photoelectron surface composition and the bulk composition of the same sample determined by energy-dispersive X-ray fluorescence. On the surface the lead composition is increased by ˜900 G. This is consistent with the important part that lead is believed to play in improving the machinability of this alloy.

  6. A computational study of adhesion between rubber and metal sulfides at rubber–brass interface

    Energy Technology Data Exchange (ETDEWEB)

    Ling, Chian Ye; Hirvi, Janne T.; Suvanto, Mika; Bazhenov, Andrey S. [Department of Chemistry, University of Eastern Finland, P.O. Box 111, FI80101 Joensuu (Finland); Ajoviita, Tommi; Markkula, Katriina [R & D, Car Tyres, Nokian Tyres plc., P.O. Box 20, FI37101 Nokia (Finland); Pakkanen, Tapani A., E-mail: tapani.pakkanen@uef.fi [Department of Chemistry, University of Eastern Finland, P.O. Box 111, FI80101 Joensuu (Finland)

    2015-05-12

    Highlights: • An atomic level model for brass–rubber interactions has been presented. • The main adhesion force has been tracked to the rubber sulfur–brass zinc or brass copper interaction. • The model gives new understanding of the adhesion and can be used for further developments of the system. - Abstract: Computational study at level of density functional theory has been carried out in order to investigate the adhesion between rubber and brass plated steel cord, which has high importance in tire manufacturing. Adsorption of natural rubber based adsorbate models has been studied on zinc sulfide, ZnS(1 1 0), and copper sulfide, Cu{sub 2}S(1 1 1) and CuS(0 0 1), surfaces as the corresponding phases are formed in adhesive interlayer during rubber vulcanization. Saturated hydrocarbons exhibited weak interactions, whereas unsaturated hydrocarbons and sulfur-containing adsorbates interacted with the metal atoms of sulfide surfaces more strongly. Sulfur-containing adsorbates interacted with ZnS(1 1 0) surface stronger than unsaturated hydrocarbons, whereras both Cu{sub 2}S(1 1 1) and CuS(0 0 1) surfaces showed opposite adsorption preference as unsaturated hydrocarbons adsorbed stronger than sulfur-containing adsorbates. The different interaction strength order can play role in rubber–brass adhesion with different relative sulfide concentrations. Moreover, Cu{sub 2}S(1 1 1) surface exhibits higher adsorption energies than CuS(0 0 1) surface, possibly indicating dominant role of Cu{sub 2}S in the adhesion between rubber and brass.

  7. Structural Evolution and Mechanisms of Fatigue in Polycrystalline Brass

    DEFF Research Database (Denmark)

    Carstensen, Jesper Vejlø

    The plastic strain controlled fatigue behaviour of polycrystalline Cu-15%Zn and Cu-30%Zn has been investigated with the aim of studying the effect of slip mode modification by the addition of zinc to copper. It has been clearly demonstrated, that true cyclic saturation does not occur in the plastic...... type single slip. This behaviour has been described by the self-consistent Sachs-Eshelby model, which provides estimates of the CSS curve for brass polycrystals. Successive stages of primary hardening, softening and secondary hardening has been observed in the plastic strain controlled fatigue of brass....... It has been found that the primary hardening is attributed to an increase of intergranular stresses whereas the sec-ondary hardening apparently is attributed to an increase of friction stresses. Investigations of the structural evolution show that the softening behaviour can be explained by the presence...

  8. SU-F-T-517: Determining the Tissue Equivalence of a Brass Mesh Bolus in a Reconstructed Chest Wall Irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Shekel, E; Epstein, D; Levin, D [Dept of radiotherapy, Assuta Medical Centers, Tel Aviv (Israel)

    2016-06-15

    Purpose: To determine the tissue equivalence of a brass mesh bolus (RPD) in the setting of a reconstructed chest wall irradiation Methods: We measured breast skin dose delivered by a tangential field plan on an anthropomorphic phantom using Mosfet and nanoDot (Landauer) dosimeters in five different locations on the breast. We also measured skin dose using no bolus, 5mm and 10 mm superflab bolus. In the Eclipse treatment planning system (Varian, Palo Alto, CA) we calculated skin dose for different bolus thicknesses, ranging from 0 to 10 mm, in order to evaluate which calculation best matches the brass mesh measurements, as the brass mesh cannot be simulated due to artefacts.Finally, we measured depth dose behavior with the brass mesh bolus to verify that the bolus does not affect the dose to the breast itself beyond the build-up region. Results: Mosfet and nanoDot measurements were consistent with each other.As expected, skin dose measurements with no bolus had the least agreement with Eclipse calculation, while measurements for 5 and 10 mm agreed well with the calculation despite the difficulty in conforming superflab bolus to the breast contour. For the brass mesh the best agreement was for 3 mm bolus Eclipse calculation. For Mosfets, the average measurement was 90.8% of the expected dose, and for nanoDots 88.33% compared to 83.34%, 88.64% and 93.94% (2,3 and 5 mm bolus calculation respectively).The brass mesh bolus increased skin dose by approximately 25% but there was no dose increase beyond the build-up region. Conclusion: Brass mesh bolus is most equivalent to a 3 mm bolus, and does not affect the dose beyond the build-up region. The brass mesh cannot be directly calculated in Eclipse, hence a 3mm bolus calculation is a good reflection of the dose response to the brass mesh bolus.

  9. Effects of differently hardened brass foil laminate on the electromechanical property of externally laminated CC tapes

    Energy Technology Data Exchange (ETDEWEB)

    Bautista, Zhierwinjay; Shin, Hyung Seop [Dept. of Mechanical Design Engineering, Andong National University, Andong (Korea, Republic of); Mean, Byoung Jean; Lee, Jae Hun [SuNAM Co Ltd., Anseong (Korea, Republic of)

    2016-12-15

    The mechanical properties of REBCO coated conductor (CC) wires under uniaxial tension are largely determined by the thick component layers in the architecture, namely, the substrate and the stabilizer or even the reinforcement layer. Depending on device applications of the CC tapes, it is necessary to reinforce thin metallic foils externally to one-side or both sides of the CC tapes. Due to the external reinforcement of brass foils, it was found that this could increase the reversible strain limit from the Cu-stabilized CC tapes. In this study, the effects of differently hardened brass foil laminate on the electromechanical property of CC tapes were investigated under uniaxial tension loading. The tensile strain dependence of the critical current (I{sub c}) was measured at 77 K and self-field. Depending on whether the I{sub c} of CC tapes were measured during loading or after unloading, a reversible strain (or stress) limit could be determined, respectively. The both-sides of the Cu-stabilized CC tapes were laminated with brass foils with different hardness, namely 1/4H, 1H and EH. From the obtained results, it showed that the yield strength of the brass laminated CC tapes with EH brass foil laminate was comparable to the one of the Cu-stabilized CC tape due to its large yield strength even though its large volume fraction. It was found that the brass foil with different hardness was mainly sensitive on the stress dependence of I{sub c}, but not on the strain sensitivity due to the residual strain induced in the laminated CC tapes during unloading.

  10. A technical study of alloy compositions of "brass" wind musical instruments (1651-1867) utilizing non-destructive X-ray fluorescence

    Science.gov (United States)

    Bacon, Alice Louise

    This thesis represents a new interdisciplinary approach to the conservation, care and curatorial study of 'brass' wind musical instruments. It attempts to combine metallurgical, chronological and historical aspects for a selection of instruments. The research consists of the systematic study of seventy-seven musical instruments, by known makers, using standardised non-destructive energy dispersive x-ray fluorescence (XRF). Such compositional data are virtually non-existent for historical 'brass' instruments in Britain and what few technical data that do exist are sporadic in quantity and quality. The development of brass instruments is interwoven with the history of brass making, but because there are a limited number of appropriate examples such links can be difficult to identify. This thesis describes the development of brass production from the cementation process to the commercial production of zinc and modern brass. Its relationship to the musical instrument industry in Britain is linked with historical evidence. It will be shown that innovation and known historical metallurgical achievements are reflected in the compositional changes of the alloys used for musical instruments. This thesis focuses on specific named brass wind musical instrument makers. This thesis sets out to investigate the extent to which a single analytical technique such as non-destructive analysis utilising XRF could be useful in the curatorial and conservation care of musical instruments. The results of the analyses revealed new aspects to the use of metals for making musical instruments. They give new information on approximate alloy compositions and, in particular, the results have shown that in the seventeenth-century in England, a ternary alloy of copper/tin/zinc was used, and that it was, perhaps, only superseded by brass (copper/zinc alloy) in the eighteenth century. It has been possible to arrange the results into a chronology of alloys particularly reflecting the change from the

  11. Synchronous visualization of multimodal measurements on lips and glottis: comparison between brass instruments and the human voice production system.

    OpenAIRE

    Hézard , Thomas; FREOUR , Vincent; Causse , René; Hélie , Thomas; Scavone , Gary P.

    2013-01-01

    cote interne IRCAM: Hezard13a; None / None; National audience; Brass instruments and the human voice production system are both composed of a vibrating "human valve" (constriction in a pipe) coupled to an acoustic resonator: lips coupled to the brass instrument or vocal folds coupled to the vocal tract. In both cases, the aeroacoustic coupling is responsible for the self-oscillations and a large variety of regimes. Additionally, brass instruments and voice share difficulties for the...

  12. 48 CFR 252.216-7000 - Economic price adjustment-basic steel, aluminum, brass, bronze, or copper mill products.

    Science.gov (United States)

    2010-10-01

    ...-basic steel, aluminum, brass, bronze, or copper mill products. 252.216-7000 Section 252.216-7000 Federal... adjustment—basic steel, aluminum, brass, bronze, or copper mill products. As prescribed in 216.203-4-70(a... Mill Products (JUL 1997) (a) Definitions. As used in this clause— Established price means a price which...

  13. Synthesis and atomic structure determination of Al8V5 gamma-brass

    International Nuclear Information System (INIS)

    Mizutani, Uichiro

    2006-01-01

    Many structurally complex compounds like quasicrystals and their approximants are known to be stabilized at a particular electron per atom ratio e/a, regardless of constituent elements involved. This has been often referred to as the Hume-Rothery electron concentration rule. We consider the understanding of the Hume-Rothery stabilization mechanism to be best deepened by performing both ab initio LMTO-ASA and FLAPW band calculations for the complex compound whose atomic structure is experimentally determined. Admittedly, however, a computing time increases rapidly beyond practical level with increasing the number of atoms in a unit cell. Among various candidates, we chose a series of gamma-brasses containing 52 atoms in a unit cell by taking a full advantage of the facts that it exists in as many as 24 binary alloy systems and that its unit cell is just in size to be handled even in more time-consuming FLAPW method. We have so far studied the stability mechanism of Cu 5 Zn 8 and Cu 9 Al 4 , both being regarded as its prototype, and TM 2 Zn 11 gamma-brasses containing late transition elements TM=Fe, Co, Ni and Pd. In the present work, we chose the gamma-brass consisting of early transition metal element V and trivalent element Al. An almost single phase Al 8 V 5 gamma-brass was ultimately synthesized by overcoming metallurgical difficulties encountered. Its atomic structure was determined by using the Brandon model as a starting structure in the Rietveld structure analysis for powdered diffraction spectra taken at the beam line BL02B2 of 8 GeV synchrotron radiation facility, SPring-8, Japan. The atomic structure suitable for band calculations was then proposed by eliminating quenched-in chemical disorder, i.e., partial mixing of Al and V atoms at given sites with minimum sacrifice. (author)

  14. Comparative Investigations on the Stress Corrosion Behavior of α -Al Bronze and α Brass in Sodium Nitrite

    International Nuclear Information System (INIS)

    Ashour, E.A.

    1995-01-01

    The stress corrosion behavior of α- Aluminum bronze (copper [Cu] -7% Al) (UNS C 61400) has been investigated as compared to α- brass under slow strain in sodium nitrite solutions under open - circuit and different anodic potentials. While α- brass was quite susceptible to SCC, α- Al bronze was found to be resistant to SCC. The ratios of time to failure in solution to that in air and of maximum stress in solution to that in air decreased sharply with increase of anodic potential for α-brass but remained virtually constant for α- Al bronze. The mode of failure was predominantly ductile for α- Al bronze under various conditions. The stress corrosion cracking of α - brass has been shown to be promoted by relatively concentrated Na N O 2 and high anodic potentials. Previous explanations for the change of the mode of failure from intergranular at open circuit potential (OCP) to transgranular cracking under anodic potential were confirmed. The bronzes resistance to SCC was attributed to the presence of Al 2 O 3 on the alloy surface. 10 Figs

  15. The Influence of Temperature on the Frictional Behavior of Duplex-Coated Die Steel Rubbing Against Forging Brass

    Science.gov (United States)

    Ebrahimzadeh, I.; Ashrafizadeh, F.

    2015-01-01

    Improvement of die life under hot forging of brass alloys is considered vital from both economical and technical points of view. One of the best methods for improving die life is duplex coatings. In this research, the influence of temperature on the tribological behavior of duplex-coated die steel rubbing against forging brass was investigated. The wear tests were performed on a pin-on-disk machine from room temperature to 700 °C; the pins were made in H13 hot work tool steel treated by plasma nitriding and by PVD coatings of TiN-TiAlN-CrAlN. The disks were machined from a two-phase brass alloy too. The results revealed that the friction coefficient of this tribosystem went through a maximum at 550 °C and decreased largely at 700 °C. Furthermore, the formation of Cr2O3 caused the reduction of friction coefficient at 700 °C. PVD coatings proved their wear resistance up to 550 °C, well above the working temperature of the brass forging dies.

  16. Morphology Controlled Fabrication of InN Nanowires on Brass Substrates

    Directory of Open Access Journals (Sweden)

    Huijie Li

    2016-10-01

    Full Text Available Growth of semiconductor nanowires on cheap metal substrates could pave the way to the large-scale manufacture of low-cost nanowire-based devices. In this work, we demonstrated that high density InN nanowires can be directly grown on brass substrates by metal-organic chemical vapor deposition. It was found that Zn from the brass substrates is the key factor in the formation of nanowires by restricting the lateral growth of InN. The nanowire morphology is highly dependent on the growth temperature. While at a lower growth temperature, the nanowires and the In droplets have large diameters. At the elevated growth temperature, the lateral sizes of the nanowires and the In droplets are much smaller. Moreover, the nanowire diameter can be controlled in situ by varying the temperature in the growth process. This method is very instructive to the diameter-controlled growth of nanowires of other materials.

  17. On the effect of β phase on the microstructure and mechanical properties of friction stir welded commercial brass alloys.

    Science.gov (United States)

    Heidarzadeh, Akbar; Saeid, Tohid

    2015-12-01

    Conventional fusion welding of brass (Cu-Zn) alloys has some difficulties such as evaporation of Zn, toxic behavior of Zn vapor, solidification cracking, distortion, and oxidation [1], [2], [3]. Fortunately, friction stir welding (FSW) has been proved to be a good candidate for joining the brass alloys, which can overcome the fusion welding short comes [4], [5], [6], [7]. The data presented here relates to FSW of the single and double phase brass alloys. The data is the microstructure and mechanical properties of the base metals and joints.

  18. Inhibition of the Cu65/Zn35 brass corrosion by natural extract of Camellia sinensis

    International Nuclear Information System (INIS)

    Ramde, Tambi; Rossi, Stefano; Zanella, Caterina

    2014-01-01

    In this work, the corrosion inhibition of brass was studied using natural plant extract, Camellia sinensis, in 0.1 M Na2SO4 solutions with pH 7 and pH 4. Electrochemical techniques (potentiodynamic polarization, electrochemical impedance spectroscopy) and scanning electron microscopy (SEM) were applied to study the brass corrosion behavior in presence and absence of the extract. The results indicated that the extract is a very effective corrosion inhibitor for brass corrosion process in both the acidic and neutral media by virtue of adsorption. The inhibition effect increases by time as demonstrated by the EIS monitoring for 120 h. In the blank solution the corrosion process leads to the formation of a dark oxide patina at pH 7 and induces localized corrosion morphology at pH 4. The extract presence can avoid both the dark patina and the pits formation.

  19. Inhibition of the Cu65/Zn35 brass corrosion by natural extract of Camellia sinensis

    Energy Technology Data Exchange (ETDEWEB)

    Ramde, Tambi, E-mail: t_ramde@univ-ouaga.bf [Equipe Chimie Physique et Electrochimie, Laboratoire de Chimie Moléculaire et des Matériaux, Université de Ouagadougou, 03 BP 7021 Ouagadougou 03 (Burkina Faso); Department of Industrial Engineering, University of Trento, via Sommarive 9, 38123 Trento (Italy); Rossi, Stefano; Zanella, Caterina [Department of Industrial Engineering, University of Trento, via Sommarive 9, 38123 Trento (Italy)

    2014-07-01

    In this work, the corrosion inhibition of brass was studied using natural plant extract, Camellia sinensis, in 0.1 M Na2SO4 solutions with pH 7 and pH 4. Electrochemical techniques (potentiodynamic polarization, electrochemical impedance spectroscopy) and scanning electron microscopy (SEM) were applied to study the brass corrosion behavior in presence and absence of the extract. The results indicated that the extract is a very effective corrosion inhibitor for brass corrosion process in both the acidic and neutral media by virtue of adsorption. The inhibition effect increases by time as demonstrated by the EIS monitoring for 120 h. In the blank solution the corrosion process leads to the formation of a dark oxide patina at pH 7 and induces localized corrosion morphology at pH 4. The extract presence can avoid both the dark patina and the pits formation.

  20. Powder metallurgy ferrous synchronizer ring with brass-based friction layer; Tetsu-do niso shoketsu synchronize ring no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Okajima, H; Yoshikawa, K; Miyajima, K; Sugiyama, M [Toyota Motor Corp., Aichi (Japan); Nakamura, M; Ito, M [Japan Powder Metallurgy Co. Ltd., Tokyo (Japan)

    1997-10-01

    Synchronizer rings for manual transmissions are generally made of brass or molybdenum coated brass. Powder metallurgy (PM) synchronizer ring was developed for the purpose of high performance and cost reduction. This synchronizer ring consists of the high strength PM ferrous ring that needs neither special densification nor heat treatment, and it has the brass-based friction layer. New joining technique was required because of that shape and two different materials. Powder of copper-phosphorus alloy are admixed with the friction material. While sintering, that melt and migrate to the interface. Then the friction layer and the ferrous ring are joined tightly. 7 refs., 9 figs., 6 tabs.

  1. Evaluation Characterization of Mechanisms Controlling Fate and Effects of Army Smokes. (Transport, Transformations, Fate and Terrestrial Ecological Effects of Brass Obscurants).

    Science.gov (United States)

    1990-08-29

    Ecological Dose of Brass Flake Causing 50% Inhibition (EcDso) of Microbial Activity ................... 3.70 FIGURE 3.10 Ecological Dose of Brass Flake...diversity was determined by the procedure of Atlas (1 984a) and Atlas and Bartha (1987). Total heterotrophic bacteria were counted on Dlfcoo nutrient...0.99) 2515 (0.99) 1451 (0.97) 1335 (0.97) (a) EcDs 0 , the ecological concentration of brass flake causing 50% Inhibition of microbial parameter, was

  2. Growth of surface structures correlated with structural and mechanical modifications of brass by laser-induced Si plasma ions implantation

    Science.gov (United States)

    Ahmad, Shahbaz; Bashir, Shazia; Rafique, M. Shahid; Yousaf, Daniel

    2017-04-01

    Laser-produced Si plasma is employed as an ion source for implantation on the brass substrate for its surface, structural, and mechanical modifications. Thomson parabola technique is employed for the measurement of energy and flux of Si ions using CR-39. In response to stepwise increase in number of laser pulses from 3000 to 12000, four brass substrates were implanted by laser-induced Si plasma ions of energy 290 keV at different fluxes ranging from 45 × 1012 to 75 × 1015 ions/cm2. SEM analysis reveals the formation of nano/micro-sized irregular shaped cavities and pores for the various ion fluxes for varying numbers of laser pulses from 3000 to 9000. At the maximum ion flux for 12,000 pulses, distinct and organized grains with hexagonal and irregular shaped morphology are revealed. X-ray diffractometer (XRD) analysis exhibits that a new phase of CuSi (311) is identified which confirms the implantation of Si ions in brass substrate. A significant decrease in mechanical properties of implanted brass, such as Yield Stress (YS), Ultimate Tensile Strength (UTS), and hardness, with increasing laser pulses from 3000 to 6000 is observed. However, with increasing laser pulses from 9000 to a maximum value of 12,000, an increase in mechanical properties like hardness, YS, and UTS is observed. The generation as well as annihilation of defects, recrystallization, and intermixing of Si precipitates with brass matrix is considered to be responsible for variations in surface, structural, and mechanical modifications of brass.

  3. Lots of Brass, Lots of Colors

    DEFF Research Database (Denmark)

    Steijn, Arthur

    2014-01-01

    Those entering the foyer ahead of the brass concert find several installations on the ground floor of the Copenhagen Opera House. Each installation explores the relationship between music and color, and there are musical instruments (trombones) available for people to play. On a large TV screen......, streams of colored particles represent the musical sounds that are picked up by a microphone when playing the trombone. People are also invited to take their own ‘particle LED light’ into the concert hall and use them to accompany the music. When seated, the link becomes obvious: Music and colors become...

  4. Corrosion fatigue behavior of high strength brass in aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Hamada, A.S.; Kassem, M.A.; Ramadan, R.M.; El-Zeky, M.A. [Suez Canal Univ., Dept. of Metallurgy and Materials Engineering (Egypt)

    2000-07-01

    Corrosion fatigue behavior of British Standard high strength brass, CZ 127 has been studied in various environments, 3.5%NaC1 solution and 3.5%NaC1 containing 1000ppm ammonia by applying the reverse bending technique, strain-controlled cyclic, at 67 cycles/min. Characteristics of the produced alloy were studied using differential thermal analysis with applying its results in heat treating of the alloy; metallographic examinations; hardness measurements; X-ray; and electrochemical behavior of the unstressed alloy. CZ 127 was fatigued at three different conditions, solution treated, peak aged, and over aged at a fixed strain amplitude, 0.03 5. Solution treated alloy gave the best fatigue properties in all environments tested among the other materials. Results of the alloy studied were compared with that obtained of 70/30 {alpha}-brass. Fracture surface of the fatigued alloy was examined using optical microscope and scanning electron microscope equipped with EDX. (author)

  5. Corrosion fatigue behavior of high strength brass in aqueous solutions

    International Nuclear Information System (INIS)

    Hamada, A.S.; Kassem, M.A.; Ramadan, R.M.; El-Zeky, M.A.

    2000-01-01

    Corrosion fatigue behavior of British Standard high strength brass, CZ 127 has been studied in various environments, 3.5%NaC1 solution and 3.5%NaC1 containing 1000ppm ammonia by applying the reverse bending technique, strain-controlled cyclic, at 67 cycles/min. Characteristics of the produced alloy were studied using differential thermal analysis with applying its results in heat treating of the alloy; metallographic examinations; hardness measurements; X-ray; and electrochemical behavior of the unstressed alloy. CZ 127 was fatigued at three different conditions, solution treated, peak aged, and over aged at a fixed strain amplitude, 0.03 5. Solution treated alloy gave the best fatigue properties in all environments tested among the other materials. Results of the alloy studied were compared with that obtained of 70/30 α-brass. Fracture surface of the fatigued alloy was examined using optical microscope and scanning electron microscope equipped with EDX. (author)

  6. Comparison of brass alloys composition by laser-induced breakdown spectroscopy and self-organizing maps

    Energy Technology Data Exchange (ETDEWEB)

    Pagnotta, Stefano; Grifoni, Emanuela; Legnaioli, Stefano [Applied and Laser Spectroscopy Laboratory, ICCOM-CNR, Research Area of Pisa, Via G. Moruzzi 1, 56124 Pisa (Italy); Lezzerini, Marco [Department of Earth Sciences, University of Pisa, Via S. Maria 53, 56126 Pisa (Italy); Lorenzetti, Giulia [Applied and Laser Spectroscopy Laboratory, ICCOM-CNR, Research Area of Pisa, Via G. Moruzzi 1, 56124 Pisa (Italy); Palleschi, Vincenzo, E-mail: vincenzo.palleschi@cnr.it [Applied and Laser Spectroscopy Laboratory, ICCOM-CNR, Research Area of Pisa, Via G. Moruzzi 1, 56124 Pisa (Italy); Department of Civilizations and Forms of Knowledge, University of Pisa, Via L. Galvani 1, 56126 Pisa (Italy)

    2015-01-01

    In this paper we face the problem of assessing similarities in the composition of different metallic alloys, using the laser-induced breakdown spectroscopy technique. The possibility of determining the degree of similarity through the use of artificial neural networks and self-organizing maps is discussed. As an example, we present a case study involving the comparison of two historical brass samples, very similar in their composition. The results of the paper can be extended to many other situations, not necessarily associated with cultural heritage and archeological studies, where objects with similar composition have to be compared. - Highlights: • A method for assessing the similarity of materials analyzed by LIBS is proposed. • Two very similar fragments of historical brass were analyzed. • Using a simple artificial neural network the composition of the two alloys was determined. • The composition of the two brass alloys was the same within the experimental error. • Using self-organizing maps, the probability of the alloys to have the same composition was assessed.

  7. Comparison of brass alloys composition by laser-induced breakdown spectroscopy and self-organizing maps

    International Nuclear Information System (INIS)

    Pagnotta, Stefano; Grifoni, Emanuela; Legnaioli, Stefano; Lezzerini, Marco; Lorenzetti, Giulia; Palleschi, Vincenzo

    2015-01-01

    In this paper we face the problem of assessing similarities in the composition of different metallic alloys, using the laser-induced breakdown spectroscopy technique. The possibility of determining the degree of similarity through the use of artificial neural networks and self-organizing maps is discussed. As an example, we present a case study involving the comparison of two historical brass samples, very similar in their composition. The results of the paper can be extended to many other situations, not necessarily associated with cultural heritage and archeological studies, where objects with similar composition have to be compared. - Highlights: • A method for assessing the similarity of materials analyzed by LIBS is proposed. • Two very similar fragments of historical brass were analyzed. • Using a simple artificial neural network the composition of the two alloys was determined. • The composition of the two brass alloys was the same within the experimental error. • Using self-organizing maps, the probability of the alloys to have the same composition was assessed

  8. The effects of Ti and Sn alloying elements on precipitation strengthened Cu40Zn brass using powder metallurgy and hot extrusion

    International Nuclear Information System (INIS)

    Li Shufeng; Imai, Hisashi; Atsumi, Haruhiko; Kondoh, Katsuyoshi; Kojima, Akimichi; Kosaka, Yoshiharu; Yamamoto, Koji; Takahashi, Motoi

    2012-01-01

    Highlights: ► Alloying elements Ti and Sn are proposed as additives in 60/40 brass. ► Super-saturated Ti in powder creates high chemical potential for precipitation. ► Ti is readily segregated in primary particle boundaries in BS40–1.0Ti. ► Sn was proposed as an additive to inhibit segregation of Ti in BS40–1.0Ti. ► The introduction of Sn to BS40–1.0Ti brass effectively impedes Ti segregation. - Abstract: The effects of Ti and Sn alloying elements on the microstructural and mechanical properties of 60/40 brass were studied by powder metallurgy processing. The super-saturated solid solution of Ti creates a high precipitation reaction chemical potential in water-atomized BS40-1.0Ti brass powder. Consequently, BS40–1.0Ti brass was remarkably strengthened by the addition of Ti. However, Ti readily segregated in the primary particle boundaries at elevated temperatures, which detrimentally affected the mechanical properties of BS40–1.0Ti brass. Accordingly, Sn was proposed as an additive to BS40–0.6Sn1.0Ti to inhibit the segregation of Ti. Consequently, the Ti precipitate was retained in the form of CuSn 3 Ti 5 in the interior of grains and grain boundaries rather than in the primary particle boundaries. This result demonstrates that the addition of Sn can effectively hinder Ti segregation in the primary particle boundaries. Sn addition produced significant grain refinement and mechanical strengthening effects in BS40–0.6Sn1.0Ti brass. As a result, outstanding strengthening effects were observed for BS40–0.6Sn1.0Ti sintered at 600 °C, which exhibited a yield strength of 315 MPa, an ultimate tensile strength of 598 MPa, and a Vickers micro-hardness of 216 Hv. These values represent increases of 27.5%, 20.1% and 45.6%, over those of extruded BS40–1.0Ti brass.

  9. The effects of Ti and Sn alloying elements on precipitation strengthened Cu40Zn brass using powder metallurgy and hot extrusion

    Energy Technology Data Exchange (ETDEWEB)

    Li Shufeng, E-mail: shufenglimail@gmail.com [Joining and Welding Research Institute, Osaka University (Japan); Imai, Hisashi; Atsumi, Haruhiko; Kondoh, Katsuyoshi [Joining and Welding Research Institute, Osaka University (Japan); Kojima, Akimichi; Kosaka, Yoshiharu [San-Etsu metals Co. Ltd., 1892, OHTA, Tonami, Toyama (Japan); Yamamoto, Koji; Takahashi, Motoi [Nippon Atomized Metal Powders Corporation, 87-16, Nishi-Sangao, Noda, Chiba (Japan)

    2012-02-15

    Highlights: Black-Right-Pointing-Pointer Alloying elements Ti and Sn are proposed as additives in 60/40 brass. Black-Right-Pointing-Pointer Super-saturated Ti in powder creates high chemical potential for precipitation. Black-Right-Pointing-Pointer Ti is readily segregated in primary particle boundaries in BS40-1.0Ti. Black-Right-Pointing-Pointer Sn was proposed as an additive to inhibit segregation of Ti in BS40-1.0Ti. Black-Right-Pointing-Pointer The introduction of Sn to BS40-1.0Ti brass effectively impedes Ti segregation. - Abstract: The effects of Ti and Sn alloying elements on the microstructural and mechanical properties of 60/40 brass were studied by powder metallurgy processing. The super-saturated solid solution of Ti creates a high precipitation reaction chemical potential in water-atomized BS40-1.0Ti brass powder. Consequently, BS40-1.0Ti brass was remarkably strengthened by the addition of Ti. However, Ti readily segregated in the primary particle boundaries at elevated temperatures, which detrimentally affected the mechanical properties of BS40-1.0Ti brass. Accordingly, Sn was proposed as an additive to BS40-0.6Sn1.0Ti to inhibit the segregation of Ti. Consequently, the Ti precipitate was retained in the form of CuSn{sub 3}Ti{sub 5} in the interior of grains and grain boundaries rather than in the primary particle boundaries. This result demonstrates that the addition of Sn can effectively hinder Ti segregation in the primary particle boundaries. Sn addition produced significant grain refinement and mechanical strengthening effects in BS40-0.6Sn1.0Ti brass. As a result, outstanding strengthening effects were observed for BS40-0.6Sn1.0Ti sintered at 600 Degree-Sign C, which exhibited a yield strength of 315 MPa, an ultimate tensile strength of 598 MPa, and a Vickers micro-hardness of 216 Hv. These values represent increases of 27.5%, 20.1% and 45.6%, over those of extruded BS40-1.0Ti brass.

  10. Synchrotron applications in archaeometallurgy: analysis of high zinc brass astrolabes

    International Nuclear Information System (INIS)

    Newbury, B.; Stephenson, B.; Almer, J.; Notis, M.; Cargill, G. S. III; Stephenson, G. B.; Haeffner, D.

    2003-01-01

    Astrolabes represent the ingenious application of mathematics and astronomy in creating a single instrument that was used for both mapping the heavens and solving everyday problems in medieval Europe and Islamic lands. Constructed as a sort of analog computer to map the heavens, astrolabes were widely used for 700 years in Europe and 1000 years in Islamic lands. In this study, 14 astrolabes (5 European and 9 Islamic) have been analyzed non-destructively utilizing a high-energy collimated x-ray beam produced at the Advanced Photon Source synchrotron at Argonne National Laboratories. By impinging a high energy (71 KeV) beam of x-rays capable of transmitting through the brass astrolabes (up to 1 cm thick), metallurgical data can be produced from the bulk of the samples without any harm to them. Diffraction, fluorescence, and radiography experiments were performed on the astrolabes. Diffraction experiments allowed composition of the bulk samples as well as mechanical deformation and forming histories to be determined. X-ray fluorescence experiments allowed the near surface (∼ 20 μm) compositions to be determined, while radiography allowed mapping of the relative thickness. From these experiments and the forming history, it is possible to obtain information about microstructural characteristics and compositions fo the astrolabes that no other non-destructive technique could furnish. These data were used to learn more about technical and metalworking techniques used by the astrolabe manufacturers, as well as to determine if any astrolabe parts wee later (or modern) replacements. Of the Islamic astrolabes studied, a group of four from the Lahore region in current day Pakistan were found to have abnormally high (> 35%) zinc compositions. These astrolabes, signed by Diya al-Din Muhammad and dating from 1637-1662 AD, provide evidence for direct alloying of metallic zinc and copper to form brass. While metallic zinc is believed to have been produced in the region for many

  11. Failure of the Hume-Rothery stabilization mechanism in the Ag5Li8 gamma-brass studied by first-principles FLAPW electronic structure calculations

    International Nuclear Information System (INIS)

    Mizutani, U; Asahi, R; Noritake, T; Sato, H; Takeuchi, T

    2008-01-01

    The first-principles FLAPW (full potential linearized augmented plane wave) electronic structure calculations were performed for the Ag 5 Li 8 gamma-brass, which contains 52 atoms in a unit cell and has been known for many years as one of the most structurally complex alloy phases. The calculations were also made for its neighboring phase AgLi B2 compound. The main objective in the present work is to examine if the Ag 5 Li 8 gamma-brass is stabilized at the particular electrons per atom ratio e/a = 21/13 in the same way as some other gamma-brasses like Cu 5 Zn 8 and Cu 9 Al 4 , obeying the Hume-Rothery electron concentration rule. For this purpose, the e/a value for the Ag 5 Li 8 gamma-brass as well as the AgLi B2 compound was first determined by means of the FLAPW-Fourier method we have developed. It proved that both the gamma-brass and the B2 compound possess an e/a value equal to unity instead of 21/13. Moreover, we could demonstrate why the Hume-Rothery stabilization mechanism fails for the Ag 5 Li 8 gamma-brass and proposed a new stability mechanism, in which the unique gamma-brass structure can effectively lower the band-structure energy by forming heavily populated bonding states near the bottom of the Ag-4d band

  12. Microstructure and Mechanical Characterization of Friction-Stir-Welded Dual-Phase Brass

    Science.gov (United States)

    Ramesh, R.; Dinaharan, I.; Akinlabi, E. T.; Murugan, N.

    2018-03-01

    Friction stir welding (FSW) is an ideal process to join brass to avoid the evaporation of zinc. In the present investigation, 6-mm-thick dual-phase brass plates were joined efficiently using FSW at various tool rotational speeds. The microstructures were studied using optical microscopy, electron backscattered diffraction and transmission electron microscopy. The optical micrographs revealed the evolution of various zones across the joint line. The microstructure of the heat-affected zone was similar to that of base metal. The weld zone exhibited finer grains due to dynamic recrystallization. The recrystallization was inhomogeneous and the inhomogeneity reduced with increased tool rotational speed. The dual phase was preserved in the weld zone due to the retention of zinc. The severe plastic deformation created a lot of dislocations in the weld zone. The weld zone was strengthened after welding. The role of tool rotational speed on the joint strength is further reported.

  13. Solid Obtained by Electrocoagulation of Vinasse, new Inhibitor for Acid Corrosion of Brass

    Directory of Open Access Journals (Sweden)

    Elaine Ojeda-Armaignac

    2016-07-01

    Full Text Available This work is part of research related to obtaining a corrosion inhibitor from vinasse, whose basic advantages is the possibility of using an industrial waste from distilleries ethyl alcohol as raw material in the production of a solid corrosion inhibitor of national production by electrocoagulation, which implies import substitution and cost reductions. The inhibitory action of the solids obtained by electrocoagulation of vinasse was investigated by potentiodynamic polarization techniques and electrochemical impedance spectroscopy. It was found that the efficiencies of inhibition against the brass into the electrolyte solution were very good, behaving as an efficient inhibitor in acid medium. Inhibition efficiency increases with increasing concentration. The maximum inhibition efficiency was of 93,43 % for the concentration of 2 mg / L of vinasse. Thermodynamic parameters were obtained at the study temperature. It was found that the adsorption of inhibitor molecules on the surface of brass obey the Langmuir isotherm, and the values of adsorción free energy of - 23.06 kJ mol-1 show the spontaneity of adsorption and indicate that the inhibitor is strongly adsorbed on the surface of brass, study of potentiodynamic polarization curves confirmed that it is a mixed type inhibitor, with an anode predominance and there is a predominant mechanism of physical adsorption combined with a chemisorption.

  14. Determination of Copper and Zinc in Brass: Two Basic Methods

    Science.gov (United States)

    Fabre, Paul-Louis; Reynes, Olivier

    2010-01-01

    In this experiment, the concentrations of copper and zinc in brass are obtained by two methods. This experiment does not require advanced instrumentation, uses inexpensive chemicals, and can be easily carried out during a 3-h upper-level undergraduate laboratory. Pedagogically, the basic concepts of analytical chemistry in solutions, such as pH,…

  15. Electrochemical and DFT studies of {beta}-amino-alcohols as corrosion inhibitors for brass

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Guo [State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China)]. E-mail: gaogaoguoguo@yahoo.com.cn; Liang, Chenghao [State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China); Electromechanics and Materials Engineering College, Dalian Maritime University, Dalian 116026 (China)

    2007-03-20

    The electrochemical performance of 1-diethylamino-propan-2-ol (EAP) and 1,3-bis-diethylamino-propan-2-ol (DEAP) for brass in simulated atmospheric water is evaluated by potentiodynamic curves and electrochemical impedance spectroscopy (EIS). The experimental results show that the investigated compounds, which can effectively retard the anodic dissolution of brass, are anodic inhibitors. Furthermore, the inhibition efficiency of DEAP is higher than that of EAP at the same concentration. This observation is supported by density functional theoretical (DFT) parameters such as the highest occupied molecule energy level (E {sub HOMO}), the lowest unoccupied molecule energy level (E {sub LUMO}), the energy difference ({delta}E) between E {sub HOMO} and E {sub LUMO}, Mulliken charges and the HOMO orbital.

  16. Corrosion of mild steel, copper and brass in crude oil / seawater mixture

    Digital Repository Service at National Institute of Oceanography (India)

    PrabhaDevi, S.; Sawant, S.S.; Wagh, A.B.

    Mild steel, copper and brass coupons were introduced in natural seawater containing varying amount of crude oil. Mild steel showed higher rate of corrosion in seawater containing oil and lower corrosion rate in natural as well as artificial seawater...

  17. Moessbauer study of the composition and corrosion behaviour of electrodeposited and cast brass containing 1-4 m% tin

    International Nuclear Information System (INIS)

    Vertes, A.; Suba, M.; Varsanyi-Lakatos, M.; Czako-Nagy, I.; Pchelnikov, A.P.; Losev, V.V.

    1982-01-01

    Moessbauer measurements on electrodeposited and cast brass containing 1-4 m% tin were carried out using conversion electron detector. It was found that the tin formed phases with copper but not with zinc. The identified phases were β, γ, epsilon and eta and their ratio depended on the tin concentration and on the preparation process of the brass. The corrosion behaviour of the samples was also studied. (author)

  18. Determination of Cu-Zn Fraction of an Ancient Brass Pipe by Prompt Gamma-ray Activation Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Sun, G. M.; Lee, Y. N.; Moon, J. H.; Lee, K. H. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2009-05-15

    Prompt Gamma Activation Analysis (PGAA) has an advantage over most other methods in the investigation of archeological and cultural objects which must be dealt with a non-destructive method. In this study, we study about how to determine the copper-zinc fraction in archeological objects such as a smoking pipe made from brass, where the proportions of copper and zinc can be varied to create a range of brasses with varying properties. In this study, a Japanese smoking pipe was analyzed to determine the copper-zinc fraction at the KAERI-SNU PGAA facility.

  19. Combat Service Support Model Development: BRASS - TRANSLOG - Army 21

    Science.gov (United States)

    1984-07-01

    throughout’the system. Transitional problems may address specific hardware and related software , such as the Standard Army Ammunition System ( SAAS ...FILE. 00 Cabat Service Support Model Development .,PASS TRANSLOG -- ARMY 21 0 Contract Number DAAK11-84-D-0004 Task Order #1 DRAFT REPOkT July 1984 D...Armament Systems, Inc. 211 West Bel Air Avenue P.O. Box 158 Aberdeen, MD 21001 8 8 8 2 1 S CORMIT SERVICE SUPPORT MODEL DEVELOPMENT BRASS -- TRANSLOG

  20. SAFETY ALERT - Failure of brass non-return valves in gas point installations

    CERN Multimedia

    HSE Unit

    2016-01-01

    There have been three recent failures in brass non-return valves in separate high pressure gas point installations across CERN. Whilst each was in a different gas service, the visual nature of the failure has been similar.   In all three cases, these components were connected to stainless steel flexible connections and stainless steel pipework. From the metallurgical investigation of the failed component, it appears that the failure is linked to uncontrolled tightening, leading to a localised weakening resulting in premature failure when subjected to pressure. Lead levels in the examined components appear to be a contributing factor to the reduction in ductility but are not identified as the root cause. It has also not been possible to attribute failure to a particular batch of material. The Occupational Health & Safety and Environmental Protection Unit prescribes the following actions to be taken, aligned with the CERN Safety Rules: Verification of all brass non-return valves (prioritising...

  1. Development of precipitation strengthened brass with Ti and Sn alloying elements additives by using water atomized powder via powder metallurgy route

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shufeng, E-mail: shufengli@hotmail.com [Joining and Welding Research Institute, Osaka University, Osaka (Japan); Imai, Hisashi; Kondoh, Katsuyoshi [Joining and Welding Research Institute, Osaka University, Osaka (Japan); Kojima, Akimichi; Kosaka, Yoshiharu [San-Etsu Metals Co. LTD., 1892 OHTA, Tonami, Toyama (Japan); Yamamoto, Koji; Takahashi, Motoi [Nippon Atomized Metal Powders Corporation, 87-16, Nishi-Sangao, Noda, Chiba (Japan)

    2012-08-15

    Effect of Ti and Sn alloying elements on microstructure and mechanical properties of 60/40 brass has been studied via the powder metallurgy (P/M) route. The water-atomized BS40-0.6Sn1.0Ti (Cu40wt%Zn-0.6wt%Sn1.0wt%Ti) pre-alloyed powder was consolidated at various temperatures within range of 400-600 Degree-Sign C using spark plasma sintering (SPS) and hot extrusion was carried out at 500 Degree-Sign C. Effects of extrusion temperature on microstructure and tensile strength were investigated by employing SEM-EDS/EBSD, TEM, XRD and tensile test. Results indicated that super-saturated solid solution Ti and Sn elements created high chemical potential for a precipitate reaction in rapidly solidified brass powder, which showed significant strengthening effects on the extruded sample consolidated at lower temperature. Solid solubility of Ti in brass matrix decreased with increasing of sintering temperature, thus resulted in degradation of mechanical properties. Consequently, lower hot processing temperature is necessary to obtain excellent mechanical properties for BS40-0.6Sn1.0Ti during sintering and extrusion. An yield strength of 398 MPa and ultimate tensile strength of 615 MPa were achieved, they respectively showed 31.3% and 22.9% higher values than those of extruded Cu40Zn brass. -- Graphical abstract: The Ti and Sn alloying elements additions showed significant grain refinement on Cu40Zn-0.6Sn1.0Ti brass (b) as comparing with that of the conventional Cu40Zn brass (a), detected by electron backscatter diffraction (EBSD) technique. The grain boundaries maps of (a) BS40 (b) BS40-0.6Sn1.0Ti SPS compact sintered at 400 Degree-Sign C reveals by electron backscatter diffraction (EBSD) technique. Highlights: Black-Right-Pointing-Pointer Alloying elements Ti and Sn are proposed as additives in 60/40 brass. Black-Right-Pointing-Pointer Super-saturated Ti in powder creates high chemical potential for precipitation. Black-Right-Pointing-Pointer CuSn{sub 3}Ti{sub 5

  2. X-ray fluorescence analysis of ancient and medieval brass artifacts from south Moravia

    Czech Academy of Sciences Publication Activity Database

    Hložek, M.; Komoróczy, Balázs; Trojek, T.

    2012-01-01

    Roč. 7, č. 70 (2012), s. 1250-1253 ISSN 0969-8043 Institutional research plan: CEZ:AV0Z80010507 Institutional support: RVO:68081758 Keywords : x-ray fluorescence analysis * brass * Moravia Subject RIV: AC - Archeology, Anthropology, Ethnology Impact factor: 1.179, year: 2012

  3. Leaching and recovery of zinc and copper from brass slag by sulfuric acid

    Directory of Open Access Journals (Sweden)

    I.M. Ahmed

    2016-09-01

    Full Text Available Leaching and recovery processes for zinc and copper from brass slag by sulfuric acid were carried out and iron and aluminum were also precipitated as hydroxides in addition to silica gel. The factors affecting the performance and efficiency of the leaching processsuch as agitation rate, leaching time, acid concentration and temperature were separately investigated. The results obtained revealed that zinc and copper are successfully recovered from these secondary resources, where the percent recovery amounts to 95% and 99% for zinc and copper, respectively. The experimental data of this leaching process were well interpreted with the shrinking core model under chemically controlled processes. The apparent activation energy for the leaching of zinc has been evaluated using the Arrhenius expression. Based on the experimental results, a separation method and a flow sheet were developed and tested to separate zinc, copper, iron, aluminum and silica gel from the brass slag.

  4. Phase stability of random brasses: pseudopotential theory revisited

    International Nuclear Information System (INIS)

    Rahman, S.M.M.

    1987-06-01

    We review the theoretical development concerning the phase stability of random brasses. The introductory discussion of the subject embraces the rules of metallurgy in general, but we emphasize on the roles of electron-per-atom ratio in the major bulk of our discussion. Starting from the so-called rigid-band model the discussion goes up to the recent higher-order pseudopotential theory. The theoretical refinements within the pseudopotential framework are discussed briefly. The stability criteria of the random phases are analysed both in the static lattice and dynamic lattice approximations. (author). 71 refs, figs and tabs

  5. Do wind and brass players snore less? A cross-sectional study of snoring and daytime fatigue in professional orchestral musicians.

    Science.gov (United States)

    Wardrop, P J C; Ravichandran, S; Hair, M; Robertson, S M; Sword, D

    2011-04-01

    To determine whether playing a wind or brass musical instrument is associated with reduced snoring or daytime fatigue. Cross-sectional, controlled, anonymous, questionnaire-based observational study. Rehearsal and performance halls. Three hundred and forty musicians from Scotland's five professional orchestras. Snore Outcomes Survey questionnaire and the Epworth Sleepiness Score. Hierarchical linear regression analysis. No significant difference was found between the snoring severity (Snore Outcomes Survey score) or daytime sleepiness (Epworth score) of wind/brass and other professional musicians. A regression model with snoring severity (Snore Outcomes Survey score) as the dependent variable and the three covariates of gender, age and body mass index as independent variables was significant [F(3, 206) = 28.77, P study demonstrated no significant difference between the snoring severity or daytime sleepiness of brass/wind players and other professional orchestral musicians. This result may have been attributed to comparatively low levels of snoring/daytime sleepiness in the population studied. The findings contrast with previous studies examining the effects of singing and didgeridoo playing but concur with a recent similar study of orchestral musicians. A prospective interventional study would be required to determine whether playing a wind or brass instrument improves these variables in patients complaining of disruptive snoring. © 2011 Blackwell Publishing Ltd.

  6. Compatibility studies of copper, brass and cupronickel with Hytherm-500 thermofluid

    International Nuclear Information System (INIS)

    Pujar, M.G.; Dayal, R.K.; Gnanamoorthy, J.B.

    1989-01-01

    Carbon steel used as a structural material in thermofluid/water heat exchangers in the Fast Breeder Test Reactor (FBTR) got perforated resulting in leakage. To suggest an alternative better corrosion resistant material for these exchangers, corrosion resistance studies of copper based alloy systems in both a s received and pickled conditions were carried out in the thermofluid medium (Hytherm-500) at room temperature (∼298 K), 373 K and 423 K upto 500 h duration. The tested materials, copper, admiralty brass and 70/30 cupronickel were found to have excellent corrosion resistance in both as-received and pickled conditions. In all the cases corrosion rates decreased with increased duration of exposure. All the above materials showed better corrosion resistance in pickled condition compared to that in as-received condition. The relative corrosion resistance of these three alloys was as follows: admiralty brass > cop per > cupronickel. This trend in the corrosion resistance was observed in both as-received and pickled conditions. In general, the corrosion resistance in pickled condition was found to be better than that in as-received condition. (author). 3 refs., 3 figs., 2 tabs

  7. 76 FR 11509 - Brass Sheet and Strip From France, Germany, Italy, and Japan

    Science.gov (United States)

    2011-03-02

    ...)] Brass Sheet and Strip From France, Germany, Italy, and Japan AGENCY: United States International Trade... and strip from France, Germany, Italy, and Japan. SUMMARY: The Commission hereby gives notice that it... France, Germany, Italy, and Japan would be likely to lead to continuation or recurrence of material...

  8. The void nucleation mechanism within lead phase during spallation of leaded brass

    Science.gov (United States)

    Yang, Yang; Wang, Can; Chen, Xingzhi; Chen, Kaiguo; Hu, Haibo; Fu, Yanan

    2018-07-01

    The incipient spall behaviours of Cu-34%Zn-3%Pb leaded brass samples with annealed and cryogenic-treated conditions were loaded using one-stage light gas gun experiments. The effect of Pb-phase on dynamic damage nucleation in leaded brass specimens was investigated by means of optical microscopy, scanning electron microscopy and x-ray computer tomography. It was found that the voids of incipient spall were mainly nucleated in the interior of the lead (no tensile stress would be produced within lead according to the impact theory) instead of nucleated at the phase interface as expected by quasi-static damage fracture theory. A nucleation model is proposed in the present work that is the asymmetry high compression zones in the centre of the lead-phase were formed by the rarefaction wave convergence effects of matrix/quasi-spherical lead interface, which caused adiabatic temperature rise that exceeded melting point of lead due to severe plastic deformation, finally led to local melting and void nucleation. In addition, the spall strength and damage rate increased with the increase in the Pb-phase number.

  9. The vibrational and configurational entropy of α-brass

    International Nuclear Information System (INIS)

    Benisek, Artur; Dachs, Edgar; Salihović, Miralem; Paunovic, Aleksandar; Maier, Maria E.

    2014-01-01

    Highlights: • The heat capacity of two α-brass samples was measured from T = 5 K to 300 K. • Above T = 300 K, the ordering/disordering processes were investigated calorimetrically. • The vibrational and configurational entropies of α-brass were calculated. • A volume vs. bulk modulus approach describing the excess entropy was tested. -- Abstract: The heat capacities of two samples of a fcc Cu–Zn alloy with the composition CuZn15 and CuZn34 were measured from T = 5 K to 573 K using relaxation and differential scanning calorimetry. Below ∼90 K, they are characterised by negative excess heat capacities deviating from ideal mixing by up to −0.20 and −0.44 J · mol −1 · K −1 for CuZn15 and CuZn34, respectively. The excess heat capacities produce excess vibrational entropies, which are less negative compared to the excess entropy available from the literature. Since the literature entropy data contain both, the configurational and the vibrational part of the entropy, the difference is attributed to the excess configurational entropy. The thermodynamics of different short-range ordered samples was also investigated. The extent of the short-range order had no influence on the heat capacity below T = 300 K. Above T = 300 K, where the ordering changed during the measurement, the heat capacity depended strongly on the thermal history of the samples. From these data, the heat and entropy of ordering was calculated. The results on the vibrational entropy of this study were also used to test a relationship for estimating the excess vibrational entropy of mixing

  10. Analysis of metals with luster: Roman brass and silver

    Energy Technology Data Exchange (ETDEWEB)

    Fajfar, H., E-mail: helena.fajfar@ijs.si [Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Jožef Stefan International Postgraduate School, Jamova 39, SI-1000 Ljubljana (Slovenia); Rupnik, Z. [Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Šmit, Ž. [Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Faculty of Mathematics and Physics, University of Ljubljana, Jadranska 19, SI-1000 Ljubljana (Slovenia)

    2015-11-01

    Non-destructive PIXE analysis using in-air proton beam was used for the studies of earliest brass coins issued during the 1st century BC by Greek cities in Asia Minor, Romans and Celts, and for the studies of plated low grade silver coins of the 3rd century AD. The analysis determined the levels of zinc and important trace elements, notably selenium, which confirms spread of selenium-marked copper from the east. For plating, combined tinning and silvering was identified by the mapping technique for the mid 3rd century AD, which evolved into mere plating by 270 AD.

  11. Analysis of metals with luster: Roman brass and silver

    International Nuclear Information System (INIS)

    Fajfar, H.; Rupnik, Z.; Šmit, Ž.

    2015-01-01

    Non-destructive PIXE analysis using in-air proton beam was used for the studies of earliest brass coins issued during the 1st century BC by Greek cities in Asia Minor, Romans and Celts, and for the studies of plated low grade silver coins of the 3rd century AD. The analysis determined the levels of zinc and important trace elements, notably selenium, which confirms spread of selenium-marked copper from the east. For plating, combined tinning and silvering was identified by the mapping technique for the mid 3rd century AD, which evolved into mere plating by 270 AD.

  12. Oxygen Compatibility of Brass-Filled PTFE Compared to Commonly Used Fluorinated Polymers for Oxygen Systems

    Science.gov (United States)

    Herald, Stephen D.; Frisby, Paul M.; Davis, Samuel Eddie

    2009-01-01

    Safe and reliable seal materials for high-pressure oxygen systems sometimes appear to be extinct species when sought out by oxygen systems designers. Materials that seal well are easy to find, but these materials are typically incompatible with oxygen, especially in cryogenic liquid form. This incompatibility can result in seals that leak, or much worse, seals that easily ignite and burn during use. Materials that are compatible with oxygen are easy to find, such as the long list of compatible metals, but these metallic materials are limiting as seal materials. A material that seals well and is oxygen compatible has been the big game in the designer's safari. Scientists at the Materials Combustion Research Facility (MCRF), part of NASA/Marshall Space Flight Center (MSFC), are constantly searching for better materials and processes to improve the safety of oxygen systems. One focus of this effort is improving the characteristics of polymers used in the presence of an oxygen enriched environment. Very few systems can be built which contain no polymeric materials; therefore, materials which have good impact resistance, low heat of combustion, high auto-ignition temperature and that maintain good mechanical properties are essential. The scientists and engineers at the Materials Combustion Research Facility, in cooperation with seal suppliers, are currently testing a new formulation of polytetrafluoroethylene (PTFE) with Brass filler. This Brass-filled PTFE is showing great promise as a seal and seat material for high pressure oxygen systems. Early research has demonstrated very encouraging results, which could rank this material as one of the best fluorinated polymers ever tested. This paper will compare the data obtained for Brass-filled PTFE with other fluorinated polymers, such as TFE-Teflon (PTFE) , Kel-F 81, Viton A, Viton A-500, Fluorel , and Algoflon . A similar metal filled fluorinated polymer, Salox-M , was tested in comparison to Brass-filled PTFE to

  13. A metallurgical and mechanical study on dissimilar Friction Stir welding of aluminum 1050 to brass (CuZn30)

    International Nuclear Information System (INIS)

    Esmaeili, A.; Givi, M.K. Besharati; Rajani, H.R. Zareie

    2011-01-01

    Highlights: → Brass and aluminum 1050 are joined for the first time through Friction Stir welding. → Welding parameters are optimized to obtain a sound joint. → The ultimate tensile strength of the sound joint reaches 80% of aluminum base metal. → The effect of interfacial intermetallic compounds on mechanical properties is probed. → CuZn, Cu9Al4 and CuAl2 form the majority of observed intermetallic compounds. - Abstract: In this research, the effect of Friction Stir welding parameters on mechanical and metallurgical properties of aluminum 1050/brass (70%Cu-30%Zn) joints was investigated. Optical microscopy, SEM, X-ray diffraction analysis and EDS analysis were used to probe microstructures and chemical compositions. In order to examine mechanical properties, besides hardness test, tensile strength of the welds was measured. The main parameters in this study were the tool rotational speed, offset, welding speed, and depth of the sinking pin. The maximum ultimate tensile strength of the joint reached in this research was 80% of the base metal (aluminum). Results show that the optimum parameters will yield a defect free joint arisen from a suitable material flow and a narrow multilayer intermetallic compound at interface in addition to a composite structure in the stir zone which all result in a strong joint. Also, by leaving the optimized condition, occurrence of large brass fragments and weld defects lower weld strength besides shifting fracture path from interface to the stir zone. Also, according to the results, using low rotation speed is accompanied by disappearance of interfacial intermetallic layer, whereas fast rotation will thicken this layer. Moreover, severe mechanical twining is observed in TMAZ of brass which leads to high values of hardness in this region.

  14. Laser cleaning of varnishes and contaminants on brass

    Energy Technology Data Exchange (ETDEWEB)

    Mateo, M.P.; Ctvrtnickova, T. [Universidad de A Coruna, Dpto. Ingenieria Industrial II, C/ Mendizabal s/n, 15403 Ferrol (Spain); Fernandez, E.; Ramos, J.A. [Instituto Tecnologico de Optica Color e Imagen, AIDO, Dpto. Laser, Valencia (Spain); Yanez, A. [Universidad de A Coruna, Dpto. Ingenieria Industrial II, C/ Mendizabal s/n, 15403 Ferrol (Spain); Nicolas, G. [Universidad de A Coruna, Dpto. Ingenieria Industrial II, C/ Mendizabal s/n, 15403 Ferrol (Spain)], E-mail: gines@cdf.udc.es

    2009-03-01

    The capability of laser ablation to perform controlled cleaning of varnishes containing contaminants and paints used by restorers in artistic objects from brass samples while keeping unaltered the finish structure is demonstrated in this work. Adequate laser energy per pulse and number of laser shots required to perform a suitable cleaning by laser ablation have been optimized. The inspection of the samples before and after the cleaning process by optical microscopy and by Fourier transform infrared spectroscopy (FTIR) technique demonstrated that the finish structure of the surface was intact while the coatings were completely eliminated. Furthermore, a laser-induced plasma spectroscopy (LIBS)-based detection system was applied during the irradiation process for the analysis of the material removal and also for its monitoring.

  15. Laser cleaning of varnishes and contaminants on brass

    International Nuclear Information System (INIS)

    Mateo, M.P.; Ctvrtnickova, T.; Fernandez, E.; Ramos, J.A.; Yanez, A.; Nicolas, G.

    2009-01-01

    The capability of laser ablation to perform controlled cleaning of varnishes containing contaminants and paints used by restorers in artistic objects from brass samples while keeping unaltered the finish structure is demonstrated in this work. Adequate laser energy per pulse and number of laser shots required to perform a suitable cleaning by laser ablation have been optimized. The inspection of the samples before and after the cleaning process by optical microscopy and by Fourier transform infrared spectroscopy (FTIR) technique demonstrated that the finish structure of the surface was intact while the coatings were completely eliminated. Furthermore, a laser-induced plasma spectroscopy (LIBS)-based detection system was applied during the irradiation process for the analysis of the material removal and also for its monitoring

  16. Fabrication and properties of high-strength extruded brass using elemental mixture of Cu-40% Zn alloy powder and Mg particle

    Energy Technology Data Exchange (ETDEWEB)

    Atsumi, Haruhiko, E-mail: atsumi-h@jwri.osaka-u.ac.jp [Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan); Imai, Hisashi; Li, Shufeng; Kondoh, Katsuyoshi [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan); Kousaka, Yoshiharu; Kojima, Akimichi [San-etsu Metals Co. Ltd., 1892 Ohta, Tonami, Toyama 939-1315 (Japan)

    2012-08-15

    In this paper, high-strength brass (Cu-40% Zn) alloy with magnesium (Mg) element was fabricated via powder technology process, and the effect of the additive Mg element on microstructural and mechanical properties of extruded brass alloys with {alpha}-{beta} duplex phases was investigated. Pre-mixed Cu-40% Zn alloy powder with 0.5-1.5 mass% pure Mg powder (Cu-40% Zn + Mg) was consolidated using a spark plasma sintering (SPS) equipment. SPSed Cu-40% Zn + Mg specimens consisted of {alpha}-{beta} duplex phases containing Mg(Cu{sub 1-x}Zn{sub x}){sub 2} intermetallic compounds (IMCs) with a mean particle size of 10-30 {mu}m in diameter. The IMCs were completely dissolved in the {alpha}-{beta} duplex phases by a heat-treatment at 973 K for 15 min; thus, in order to disperse fine IMCs on {alpha}-{beta} duplex phase matrix, the SPSed Cu-40% Zn + Mg specimens were pre-heated at the solid solutionizing condition, and immediately extruded. The extruded specimen exhibited fine {alpha}-{beta} duplex phases, containing very fine precipitates of the above Mg(Cu{sub 1-x}Zn{sub x}){sub 2} IMCs with 0.5-3.0 {mu}m in diameter. In particular, a mean grain size of the extruded Cu-40% Zn + 1.0% Mg specimen was 3.32 {mu}m analyzed using an electron back-scattered diffraction. Tensile properties of the extruded Cu-40% Zn + 1.0% Mg specimen were an average value of yield strength (YS): 328 MPa, ultimate tensile strength (UTS): 553 MPa, and 25% elongation. This indicated that the extruded Cu-40% Zn + 1.0% Mg specimen revealed the significantly high-strength properties compared to a conventional binary brass alloy with 229 MPa YS and 464 MPa UTS. A high strengthening mechanism of this wrought brass alloy was mainly due to the grain refinement because of a pinning effect by the fine Mg(Cu{sub 1-x}Zn{sub x}){sub 2} precipitates at the boundaries of each phase. -- Highlights: Black-Right-Pointing-Pointer New high-strength extruded brass alloy with Mg was fabricated via powder metallurgy. Black

  17. Structural and phase transformations in zinc and brass wires under heating with high-density current pulse

    Energy Technology Data Exchange (ETDEWEB)

    Pervikov, A. V. [Laboratory of Physical Chemistry of Ultrafine Materials, Institute of Strength Physics and Materials Science, 2/4, pr. Akademicheskii, 634021 Tomsk, Russia and Department of High Voltage Electrophysics and High Current Electronics, Tomsk Polytechnic University, 30 Lenin Avenue, 634050 Tomsk (Russian Federation)

    2016-06-15

    The work is focused on revealing the mechanism of structure and phase transformations in the metal wires under heating with a high-density current pulse (the electric explosion of wires, EEWs). It has been demonstrated on the example of brass and zinc wires that the transition of a current pulse with the density of j ≈ 3.3 × 10{sup 7} A/cm{sup 2} results in homogeneous heating of the crystalline structure of the metal/alloy. It has been determined that under heating with a pulse of high-density current pulse, the electric resistance of the liquid phases of zinc and brass decreases as the temperature increases. The results obtained allow for a conclusion that the presence of the particles of the condensed phase in the expanding products of EEW is the result of overheating instabilities in the liquid metal.

  18. Surface integrity evaluation of brass CW614N after impact of acoustically\

    Czech Academy of Sciences Publication Activity Database

    Lehocká, D.; Klich, Jiří; Foldyna, Josef; Hloch, Sergej; Hvizdoš, P.; Fides, M.; Botko, F.; Cárach, J.

    2016-01-01

    Roč. 149, č. 149 (2016), s. 236-244 E-ISSN 1877-7058. [International Conference on Manufacturing Engineering and Materials, ICMEM 2016. Nový Smokovec, 06.06.2016-10.06.2016] R&D Projects: GA MŠk(CZ) LO1406; GA MŠk ED2.1.00/03.0082 Institutional support: RVO:68145535 Keywords : pulsating water jet * surface integrity * mass material removal * brass * nanoindentation Subject RIV: JQ - Machines ; Tools http://www.sciencedirect.com/science/article/pii/S1877705816311705

  19. 78 FR 56656 - Brass Sheet and Strip From France: Rescission of Antidumping Duty Administrative Review; 2012-2013

    Science.gov (United States)

    2013-09-13

    ... DEPARTMENT OF COMMERCE International Trade Administration [A-427-602] Brass Sheet and Strip From..., International Trade Administration, Department of Commerce. DATES: Effective Date: September 13, 2013. FOR... Administration, International Trade Administration, U.S. Department of Commerce, 14th Street and Constitution...

  20. Axial vibrations of brass wind instrument bells and their acoustical influence: Theory and simulations.

    Science.gov (United States)

    Kausel, Wilfried; Chatziioannou, Vasileios; Moore, Thomas R; Gorman, Britta R; Rokni, Michelle

    2015-06-01

    Previous work has demonstrated that structural vibrations of brass wind instruments can audibly affect the radiated sound. Furthermore, these broadband effects are not explainable by assuming perfect coincidence of the frequency of elliptical structural modes with air column resonances. In this work a mechanism is proposed that has the potential to explain the broadband influences of structural vibrations on acoustical characteristics such as input impedance, transfer function, and radiated sound. The proposed mechanism involves the coupling of axial bell vibrations to the internal air column. The acoustical effects of such axial bell vibrations have been studied by extending an existing transmission line model to include the effects of a parasitic flow into vibrating walls, as well as distributed sound pressure sources due to periodic volume fluctuations in a duct with oscillating boundaries. The magnitude of these influences in typical trumpet bells, as well as in a complete instrument with an unbraced loop, has been studied theoretically. The model results in predictions of input impedance and acoustical transfer function differences that are approximately 1 dB for straight instruments and significantly higher when coiled tubes are involved or when very thin brass is used.

  1. Leaching and recovery of zinc and copper from brass slag by sulfuric acid

    OpenAIRE

    Ahmed, I.M.; Nayl, A.A.; Daoud, J.A.

    2016-01-01

    Leaching and recovery processes for zinc and copper from brass slag by sulfuric acid were carried out and iron and aluminum were also precipitated as hydroxides in addition to silica gel. The factors affecting the performance and efficiency of the leaching processsuch as agitation rate, leaching time, acid concentration and temperature were separately investigated. The results obtained revealed that zinc and copper are successfully recovered from these secondary resources, where the percent r...

  2. APPLICATION OF SCANNING ELECTRON MICROSCOPE EQUIPPED WITH THE MICROANALYSIS SYSTEM FOR INVESTIGATION OF BRASS COVERING

    Directory of Open Access Journals (Sweden)

    T. P. Kurenkova

    2010-01-01

    Full Text Available The possibilities of application of scanning electronic microscope equipped with microanalysis system for investigation of the brass covering quality by slug for production of wire and metal cord particularly of change of copper concentration by covering thickness and slug perimeter, revealing of ?-phase allocation presence and character, determination of defect reasons, are shown.

  3. 3 MeV proton irradiation effects on surface, structural, field emission and electrical properties of brass

    Science.gov (United States)

    Ali, Mian Ahsan; Bashir, Shazia; Akram, Mahreen; Mahmood, Khaliq; Faizan-ul-Haq; Hayat, Asma; Mutaza, G.; Chishti, Naveed Ahmed; Khan, M. Asad; Ahmad, Shahbaz

    2018-05-01

    Ion-induced modifications of brass in terms of surface morphology, elemental composition, phase changes, field emission properties and electrical conductivity have been investigated. Brass targets were irradiated by proton beam at constant energy of 3 MeV for various doses ranges from 1 × 1012 ions/cm2 to 1.5 × 1014 ions/cm2 using Pelletron Linear Accelerator. Field Emission Scanning Electron Microscope (FESEM) analysis reveals the formation of randomly distributed clusters, particulates, droplets and agglomers for lower ion doses which are explainable on the basis of cascade collisional process and thermal spike model. Whereas, at moderate ion doses, fiber like structures are formed due to incomplete melting. The formation of cellular like structure is observed at the maximum ion dose and is attributed to intense heating, melting and re-solidification. SRIM software analysis reveals that the penetration depth of 3 MeV protons in brass comes out to be 38 μm, whereas electronic and nuclear energy losses come out to be 5 × 10-1 and 3.1 × 10-4 eV/Å respectively. The evaluated values of energy deposited per atom vary from 0.01 to 1.5 eV with the variation of ion doses from 1 × 1012 ions/cm2 to 1.5 × 1014 ions/cm2. Both elemental analysis i.e. Energy Dispersive X-ray spectroscopy (EDX) and X-ray Diffraction (XRD) supports each other and no new element or phase is identified. However, slight change in peak intensity and angle shifting is observed. Field emission properties of ion-structured brass are explored by measuring I-V characteristics of targets under UHV condition in diode-configuration using self designed and fabricated setup. Improvement in field enhancement factor (β) is estimated from the slope of Fowler-Nordheim (F-N) plots and it shows significant increase from 5 to 1911, whereas a reduction in turn on field (Eo) from 65 V/μm to 30 V/μm and increment in maximum current density (Jmax) from 12 μA/cm2 to 3821 μA/cm2 is observed. These enhancements

  4. Ordering and structural vacancies in non-stoichiometric Cu-Al γ brasses

    International Nuclear Information System (INIS)

    Kisi, E.H.; Browne, J.D.

    1991-01-01

    γ-Brass structures are based on the cubic packing of 26-atom clusters which have, as concentric subunits, an inner and an outer tetrahedron (IT, OT), an octahedron (OH) and a cuboctahedron (CO). Cu 9 Al 4 [M r = 679.37, P43m, a = 8.7046(1) A, V = 659.5 A 3 , Z = 4, D x = 6.846 Mg m -3 , R wp = 0.051, R B = 0sun017 for 238 powder reflections] is the stoichiometric γ brass of the Cu-Al system and contains two clusters (A, B) per unit cell. Al atoms occupy a 4(e) (IT) site in cluster A and a 12(i) (CO) site in cluster B. Cu atoms occupy the remaining 4(e) (OT), 6(f) (OH) and 12(i) (CO) sites of cluster A and the two 4(e) (IT, OT) and a 6(g) (OH) site of cluster B. The structure has considerable solubility for Al and this paper contains a systematic neutron powder diffraction study of the changes in the Cu 9 Al 4 structure at 295 K (λ = 1.376 A) and 77 K(λ = 1.500 A) as Al is added. The structure was found to remain cubic for compositions Cu 8.93 Al 4.08 , Cu 8.83 , Al 4.17 , Cu 8.75 Al 4.25 and Cu 8.58 Al 4.42 . At Cu 8.30 Al 4.58 the structure was slightly distorted to an undetermined symmetry. For Cu 8.03 Al 4.68 and Cu 7.55 Al 4.80 the structure was found to be rhombohedral [M r = 636.57, R3m, a = 8.7066(1) A, α = 89.74(1) deg, V = 660.0(1) A 3 , Z = , D x = 6.406, D m = 6.41 Mg m -3 , R wp = 0.064, R B = 0.025 for 702 reflections; and M r = 609.31, R3m, a = 8.6884(1) A, α = 89.78(1) deg, V = 655.9(1) A 3 , Z = 4, D x = 6.170, D m = 6.18 Mg m -3 , R wp = 0.064, R B = 0.027 for 789 reflections, respectively]. The non-cubic structures contain sufficient structural vacancies to maintain a classical valence content of 88 electrons per unit cell. Refined structures are presented for all of the above compositions, except Cu 8.30 Al 4.58 , and the results discussed in terms of current γ-brass stability theories. (orig.)

  5. Effect of Brass Interlayer Sheet on Microstructure and Joint Performance of Ultrasonic Spot-Welded Copper-Steel Joints

    Science.gov (United States)

    Satpathy, Mantra Prasad; Kumar, Abhishek; Sahoo, Susanta Kumar

    2017-07-01

    Solid-state ultrasonic spot welding (USW) inevitably offers a potential solution for joining dissimilar metal combination like copper (Cu) and steel (SS). In this study, the USW has been performed on Cu (UNS C10100) and SS (AISI 304) with brass interlayer by varying various welding parameters, aiming to identify the interfacial reaction, changes in microstructure and weld strength. The highest tensile shear and T-peel failure loads of 1277 and 174 N are achieved at the optimum conditions like 68 µm of vibration amplitude, 0.42 MPa of weld pressure and 1 s of weld time. The fractured surface analysis of brass interlayer and AISI 304 stainless steel samples reveals the features like swirls, voids and intermetallic compounds (IMCs). These IMCs are composed of CuZn and FeZn composite-like structures with 1.0 μm thickness. This confirms that the weld quality is specifically sensitive to the levels of input parameter combinations as well as the type of material present on the sonotrode side.

  6. Microbiologically influenced corrosion evaluation on brass (UNS C68700, UNS C443) and AISI 316 stainless steel

    International Nuclear Information System (INIS)

    Ohanian, M.; Diaz, V.; Corengia, M.; Russi, P.; Pianzzola, M. J.; Menes, R. J.

    2014-01-01

    Microorganisms may play an important role in the corrosion process and generate conditions which affect the rate and/or the mechanism of deterioration. They become visible by the formation of bio films: clusters of microorganisms and extracellular polymers. These bio films affect not only the durability of the material, but also reduce the heat transfer. The present work studied the growth of aerobic and anaerobic heterotrophic microorganisms and sulfate reducing bacteria on aluminum brass (Uns C.a.), admiralty brass (Uns C.a.) and stainless steel Asi 316 in exposure experiments held in the Bay of Montevideo (Uruguay). The influence of the biofilm growth on the corrosion behavior was studied by electrochemical techniques: polarization curves and Electrochemical Impedance Spectroscopy (Ei). The selection of the most suitable material for the exposure conditions is discussed and hypotheses of the corrosion mechanism are presented. Although stainless steel Asi 316 presented the lowest corrosion rate it showed localized deterioration. (Author)

  7. Antiphase boundaries, inversion, and ferroelastic domains in the striped-type superstructure of γ-brass Cu-Al alloys

    Science.gov (United States)

    Koyama, Y.; Hatano, M.; Tanimura, M.

    1996-05-01

    Features of the striped-type superstructure in γ-brass Cu-Al alloys have been investigated mainly by transmission electron microscopy in order to understand the role of a rhombohedral distortion in its stability. From dark field images taken from alloys exhibiting the superstructure, it was found that there exist two types of ferroelastic rhombohedral domains, which are in a twin relation. In other words, the superstructure is characterized by a periodic array of the ferroelastic domains as well as inversion antiphase boundaries. Because charge density waves should be responsible for the formation of the superstructure, as suggested in our previous paper [Phys. Rev. B 40, 5378 (1989)], the rhombohedral distortion must play a crucial role in their appearance. Presumably the distortion enlarges parallel portions of the Fermi surface. On the basis of the present experimental data, the interplay between the striped-type superstructure and the rhombohedral γ-brass structure is also discussed.

  8. Anti frictional materials iron-pig iron-brass manufacture using shaving waste products of pig-iron

    International Nuclear Information System (INIS)

    Nasamov, S. N.; Krivij, N.; Gudenau, H. W.; Babich, A. I.; Garcia, L. L.; Formoso, A.; Cores, A.

    2003-01-01

    Parts based on iron and steel powders are widely used in the manufacture of automobile and domestic equipment. This work was done to study the anti-friction properties of iron-pig iron-brass compositions of materials which were obtained by pressing and sintering from a mix of iron powders and industrial by products of cast-iron turnings, brass, talc and technical sulphur. Experiments were performed using cold pressure technology in the flowing matrix of the powder composite without solid lubricants. The subsequent sintering was carried out at 1200 degree centigree under isothermal conditions in a nitrogen atmosphere in the sintering zone during 1 h. The physical-mechanical and anti-friction properties were almost double by the active drainage of the gases from the compression mould. The study of the microstructure of the sintered materials showed that free cementite existed between the particle limits and around the pores. large agglomerations of dark inclusions could be observed, consisting of graphite, zinc and iron oxides, which were points of tension in the materials that reduce its durability and, therefore, its wear resistance to dry friction. (Author) 34 refs

  9. AN INVESTIGATION OF THE IMPACT OF ALLOY COMPOSITION AND PH ON THE CORROSION OF BRASS IN DRINKING WATER

    Science.gov (United States)

    A better understanding of brass corrosion may provide information and guidance on the use of the safest materials for the production of plumbing fixtures, and optimization of corrosion control treatments. The effect of alloy composition and pH on the metal leached from six differ...

  10. Hume-Rothery electron concentration rule across a whole solid solution range in a series of gamma-brasses in Cu-Zn, Cu-Cd, Cu-Al, Cu-Ga, Ni-Zn and Co-Zn alloy systems

    Science.gov (United States)

    Mizutani, U.; Noritake, T.; Ohsuna, T.; Takeuchi, T.

    2010-05-01

    The aim of the present work is to examine if the Hume-Rothery stabilisation mechanism holds across whole solid solution ranges in a series of gamma-brasses with especial attention to the role of vacancies introduced into the large unit cell. The concentration dependence of the number of atoms in the unit cell, N, for gamma-brasses in the Cu-Zn, Cu-Cd, Cu-Al, Cu-Ga, Ni-Zn and Co-Zn alloy systems was determined by measuring the density and lattice constants at room temperature. The number of itinerant electrons in the unit cell, e/uc, is evaluated by taking a product of N and the number of itinerant electrons per atom, e/a, for the transition metal element deduced earlier from the full-potential linearised augmented plane wave (FLAPW)-Fourier analysis. The results are discussed within the rigid-band model using as a host the density of states (DOS) derived earlier from the FLAPW band calculations for the stoichiometric gamma-brasses Cu5Zn8, Cu9Al4 and TM2Zn11 (TM = Co and Ni). A solid solution range of gamma-brasses in Cu-Zn, Cu-Cd, Cu-Al, Cu-Ga and Ni-Zn alloy systems is found to fall inside the existing pseudogap at the Fermi level. This is taken as confirmation of the validity of the Hume-Rothery stability mechanism for a whole solute concentration range of these gamma-brasses. An exception to this behaviour was found in the Co-Zn gamma-brasses, where orbital hybridisation effects are claimed to play a crucial role in stabilisation.

  11. Strain path and work-hardening behavior of brass

    International Nuclear Information System (INIS)

    Sakharova, N.A.; Fernandes, J.V.; Vieira, M.F.

    2009-01-01

    Plastic straining in metal forming usually includes changes of strain path, which are frequently not taken into account in the analysis of forming processes. Moreover, strain path change can significantly affect the mechanical behavior and microstructural evolution of the material. For this reason, a combination of several simple loading test sequences is an effective way to investigate the dislocation microstructure of sheet metals under such forming conditions. Pure tension and rolling strain paths and rolling-tension strain path sequences were performed on brass sheets. A study of mechanical behavior and microstructural evolution during the simple and the complex strain paths was carried out, within a wide range of strain values. The appearance and development of deformation twinning was evident. It was shown that strain path change promotes the onset of premature twinning. The work-hardening behavior is discussed in terms of the twinning and dislocation microstructure evolution, as revealed by transmission electron microscopy

  12. New Co–Pd–Zn γ-Brasses with Dilute Ferrimagnetism and Co2Zn11 Revisited: Establishing the Synergism between Theory and Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Weiwei; Miller, Gordon J

    2014-04-22

    A synergism between electronic structure theory and the targeted synthesis of new ternary γ-brass compounds is demonstrated in the Co–Zn system. Co2Zn11, which adopts a cubic γ-brass structure, is shown to be at the Zn-rich end of a homogeneity range that varies from 15.4 to 22.1 atom % Co. Four samples were examined by single-crystal diffraction, all of which crystallize in space group I43¯m with the lattice parameter ranging from 8.9851(1) to 8.8809(1) Å as the Co content increases. In the 26-atom γ-brass clusters, Co atoms preferentially occupy the outer tetrahedron (OT) sites and then replace Zn atoms at the octahedron (OH) sites at higher Co concentrations. In addition, a small fraction of vacancies occurs on the inner tetrahedron (IT) sites. The electronic structure of Co2Zn11 shows two distinct pseudogaps near the Fermi level: one at 292 valence electrons per primitive unit cell and the other at 302–304 valence electrons per primitive unit cell. Using molecular orbital arguments applied to the body-centered cubic packing of the 26-atom Co4Zn22 γ-brass cluster, these pseudogaps arise from (i) splitting among the valence s and p orbitals, which gives rise to the Hume–Rothery electron counting rule, and (ii) splitting within the manifold of Co 3d orbitals via Co–Zn orbital interactions. Co2Zn11 is Pauli paramagnetic, although the density of states at the Fermi level is large, whereas Curie–Weiss behavior emerges for higher Co concentrations. Because Pd has a size and an electronegativity similar to those of Zn, and inspired by the pseudogaps in the electronic density of states curve of Co2Zn11, Pd-doped γ-brass compounds were designed and two new γ-brass compounds were obtained: Co0.92(2)Pd1.08Zn11 and Co2.50(1)Pd2.50Zn8. In these, the site preferences for Co and Pd can

  13. Dislocation Line Tensions in the Noble Metals, the Alkali Metals and beta-Brass

    Energy Technology Data Exchange (ETDEWEB)

    Pettersson, B; Malen, K

    1971-06-15

    The line tension for a straight partial dislocation which can produce the necessary slip for a martensitic phase transformation of the bcc-fcc or bcc-hcp type has been calculated in ordered 6-brass and in Li, Na and K. Also the line tension for a Shockley partial dislocation in Cu, Ag and Au has been calculated. Negative line tension is found for certain dislocation directions, and the possible influence of this on the stability of a stacking fault bounded by these partials is discussed

  14. Inhibition of Brass (80/20 by 5-Mercaptopentyl-3-Amino-1,2,4-Triazole in Neutral Solutions

    Directory of Open Access Journals (Sweden)

    Ivan А. Arkhipushkin

    2017-11-01

    Full Text Available The effect of the adsorption of 5-mercaptopentyl-3-amino-1,2,4-triazole (MPATA on the corrosive behavior of brass (Cu80/Zn20 in neutral (pH 7.4 borate buffer solutions with and without 0.01 M NaCl was studied. Electrochemical methods show significant decrease of the anodic and cathodic currents on the polarization curves in the presence of MPATA. X-ray photoelectron spectroscopy (XPS reveals MPATA adsorption on the brass surface from an inhibitor solution. After 17 h of exposure, a mixed complex [CuxZnyMPATAz] with a thickness of about 3–3.5 nm is formed on the surface. This nanolayer has sufficient protective ability to withstand corrosion tests in a salt fog chamber: after 5 days of testing, the samples remain glossy and less than 1% of the surface has been damaged. After corrosion tests in a salt fog chamber, the surface of unprotected samples is enriched with zinc, while at the surface of inhibitor-treated samples, the copper and zinc are present in practically equal contents.

  15. To Determine the Percentage of Copper in a Brass Screw Using a Computer Interface with a Colorimeter.

    Science.gov (United States)

    Horgan, Joan; Hedge, Robyn

    1997-01-01

    Year 11 students investigated the real-world problem of whether screws are really brass. It allowed them to use the colorimeter and computer interface in a way that was easily understood and models normal practice in testing laboratories. Screws were dissolved in nitric acid and their absorbance of red light was compared with a standard curve.…

  16. Investigation of scaling laws by critical neutron scattering from beta-brass

    DEFF Research Database (Denmark)

    Als-Nielsen, Jens Aage

    1969-01-01

    Using a Cu65-Zn β-brass crystal, the critical scattering of neutrons has been studied, both above and below T c. The staggered susceptibilities χ vary as C+(T/Tc-1)-γ and C-(1-T/Tc)-γ ', respectively. It is found that γ=γ' within an accuracy of 3%, in agreement with the scaling hypothesis of static...... critical phenomena; and that C+/C-=5.46±0.05, in excellent agreement with the recent parametric representation theory of Schofield and in fair agreement with the results of series expansions by Essam and Hunter. For fixed q, a flat maximum is observed in the wave-vector-dependent susceptibility χ(q, T...

  17. On the possible importance of mechanical twinning for the development of the brass-type rolling texture and final comment on the above remarks by T. Leffers

    DEFF Research Database (Denmark)

    Leffers, Torben

    1970-01-01

    The author presents his final comments on the discussion between himself and Heye and Wasserman (see abstrs. A11834 and A11835 of 1970) which arose from the latter authors' paper on mechanical twinning (see abstr. A19815 of 1969). The validity of the twinning theory for the brass-type rolling...... texture is questioned for two reasons: There is no convincing crystallographic model explaining how the formation of the brass-type texture by combined twinning and slip should work in theory, and there are experimental results indicating that it should not work in practice...

  18. Anatomical studies of timber and EPMA analysis of brass artefacts collected from steam engine shipwreck of Minicoy Island, Lakshadweep, India

    Digital Repository Service at National Institute of Oceanography (India)

    Tripati, S.; Shukla, S.R.; Som, V.; Sundaresh; Khedekar, V.; Shashikala, S.; Sharma, S.K.

    construction but also for anchors. During exploration of shipwreck off Minicoy doorframe hinge, latch, porthole, flanges, J hook were found and all these artefacts are made of brass. Moreover timber remains noticed on doorframe hinge and latch. In order...

  19. Nanosecond pulsed laser ablation of brass in a dry and liquid-confined environment

    Science.gov (United States)

    Bashir, Shazia; Vaheed, Hamza; Mahmood, Khaliq

    2013-02-01

    The effect of ambient environment (dry or wet) and overlapping laser pulses on the laser ablation performance of brass has been investigated. For this purpose, a Q-switched, frequency doubled Nd:YAG laser with a wavelength of 532 nm, pulse energy of 150 mJ, pulse width of 6 ns and repetition rate of 10 Hz is employed. In order to explore the effect of ambient environments, brass targets have been exposed in deionized water, methanol and air. The targets are exposed for 1000, 2000, 3000 and 4000 succeeding pulses in each atmosphere. The surface morphology and chemical composition of ablated targets have been characterized by using Scanning Electron Microscope (SEM), Atomic Force Microscope (AFM) and Attenuated Total Reflection (ATR) techniques. In case of liquid environment, various features like nano- and micro-scale laser-induced periodic surface structures with periodicity 500 nm-1 μm, cavities of size few micrometers with multiple ablative layers and phenomenon of thermal stress cracking are observed. These features are originated by various chemical and thermal phenomena induced by laser heating at the liquid-solid interfaces. The convective bubble motion, explosive boiling, pressure gradients, cluster and colloid formation due to confinement effects of liquids are possible cause for such kind of features. The metal oxides and alcohol formed on irradiated surface are also playing the significant role for the formation of these kinds of structure. In case of air one huge crater is formed along with the redeposition of sputtered material and is ascribed to laser-induced evaporation and oxide formation.

  20. Automated Image Acquisition System for the Verification of Copper-Brass Seal Images

    International Nuclear Information System (INIS)

    Stringa, E.; Bergonzi, C.; Littmann, F.; ); Marszalek, Y.; Tempesta, S.; )

    2015-01-01

    This paper describes a system for the verification of copper-brass seals realized by JRC according to DG ENER requirements. DG ENER processes about 20,000 metal seals per year. The verification of metal seals consists in visually checking the identity of a removed seal. The identity of a copper-brass seal is defined by a random stain pattern realized by the seal producer together with random scratches engraved when the seals are initialized ('seal production'). In order to verify that the seal returned from the field is the expected one its pattern is compared with an image taken during seal production. Formerly, seal initialization and verification were very heavy tasks as seal pictures were acquired with a camera one by one both in the initialization and verification stages. During the initialization the Nuclear Safeguards technicians had to place one by one new seals under a camera and acquire the related reference images. During the verification, the technician had to take used seals and place them one by one under a camera to take new pictures. The new images were presented to the technicians without any preprocessing and the technicians had to recognize the seal. The new station described in this paper has an automated image acquisition system allowing to easily process seals in batches of 100 seals. To simplify the verification, a software automatically centres and rotates the newly acquired seal image in order to perfectly overlap with the reference image acquired during the production phase. The new system significantly speeds up seal production and helps particularly with the demanding task of seal verification. As a large part of the seals is dealt with by a joint Euratom-IAEA team, the IAEA directly profits from this development. The new tool has been in routine use since mid 2013. (author)

  1. Structure of ordered and disordered α-brass

    International Nuclear Information System (INIS)

    Mu''ller, S.; Zunger, Alex

    2001-01-01

    Alloys of copper and zinc (brass) have been widely used since Neolithic times due to the discovery that unlike regular copper this alloy can be worked ''cold'' around a 3:1 copper-to-zinc ratio. While it is now known that the as-grown system is a disordered fcc solid solution, no 3:1 ordered phase has yet been directly observed even though the negative mixing enthalpy of the disordered alloy suggests ordering tendencies. Moreover, neutron scattering experiments have been deduced that this disordered alloy contains peculiar chains of Zn atoms. We have expressed the first-principles calculated total energy of general Cu-Zn fcc-lattice configurations using a mixed-space cluster expansion. Application of Monte Carlo--simulated annealing to this generalized Ising-like Hamiltonian produces the predicted low-temperature ground state as well as finite-temperature phase diagram and short-range order. We find (i) that at low temperature the disordered fcc alloy will order into the DO 23 structure, (ii) the high-temperature short-range order in close agreement with experiment, and (iii) chains of Zn atoms in the [001] direction, as seen experimentally. Furthermore, our model allows a detailed study of the influence and importance of strain on the phase stability

  2. Quantitative analysis of a brass alloy using CF-LIBS and a laser ablation time-of-flight mass spectrometer

    Science.gov (United States)

    Ahmed, Nasar; Abdullah, M.; Ahmed, Rizwan; Piracha, N. K.; Aslam Baig, M.

    2018-01-01

    We present a quantitative analysis of a brass alloy using laser induced breakdown spectroscopy, energy dispersive x-ray spectroscopy (EDX) and laser ablation time-of-flight mass spectrometry (LA-TOF-MS). The emission lines of copper (Cu I) and zinc (Zn I), and the constituent elements of the brass alloy were used to calculate the plasma parameters. The plasma temperature was calculated from the Boltzmann plot as (10 000  ±  1000) K and the electron number density was determined as (2.0  ±  0.5)  ×  1017 cm-3 from the Stark-broadened Cu I line as well as using the Saha-Boltzmann equation. The elemental composition was deduced using these techniques: the Boltzmann plot method (70% Cu and 30% Zn), internal reference self-absorption correction (63.36% Cu and 36.64% Zn), EDX (61.75% Cu and 38.25% Zn), and LA-TOF (62% Cu and 38% Zn), whereas, the certified composition is (62% Cu and 38% Zn). It was observed that the internal reference self-absorption correction method yields analytical results comparable to that of EDX and LA-TOF-MS.

  3. Injection Pharyngoplasty With Autologous Fat as Treatment for Stress Velopharyngeal Insufficiency in Brass and Woodwind Musicians.

    Science.gov (United States)

    Syamal, Mausumi N; Bryson, Paul C

    2017-02-01

    Stress velopharyngeal insufficiency (SVPI) is an uncommon but often career-threatening condition affecting professional brass and woodwind musicians. To review the evaluation of and treatment for SVPI in professional musicians with lipoinjection to the posterior pharyngeal wall. A retrospective medical record and literature review. Two professional musicians with SVPI treated with autologous lipoinjection to the posterior pharyngeal wall were included. Nasopharyngoscopy was performed while patients played their instrument both before and after injection. To assess the effectiveness of autologous fat injection to the posterior pharyngeal wall to treat stress velopharyngeal insufficiency in 2 professional instrumentalists. Successful treatment was the absence of VPI during playing as visualized by flexible nasopharyngoscopy. After autologous lipoinjection of the posterior pharyngeal wall, 1 patient resumed full play with complete resolution, now 3 years after lipoinjection pharyngoplasty. The other patient received temporary resolution. Both had no surgical complications. Stress VPI is often a career-threatening condition for professional brass and woodwind musicians, with a cited incidence of 34%. Various treatment options in the literature include observation, speech and language pathology referral for pharyngeal strengthening, lipoinjection of the soft palate, and more invasive options, such as sphincter pharyngoplasty, pharyngeal flaps and V-Y pushback. Autologous fat injection pharyngoplasty of the posterior pharyngeal wall may be a less invasive treatment option for musicians with SVPI.

  4. Monte Carlo simulation of spectrum changes in a photon beam due to a brass compensator

    International Nuclear Information System (INIS)

    Custidiano, E.R.; Valenzuela, M.R.; Dumont, J.L.; McDonnell, J.; Rene, L; Rodriguez Aguirre, J.M.

    2011-01-01

    Monte Carlo simulations were used to study the changes in the incident spectrum when a poly-energetic photon beam passes through a static brass compensator. The simulated photon beam spectrum was evaluated by comparing it against the incident spectra. We also discriminated the changes in the transmitted spectrum produced by each of the microscopic processes. (i.e. Rayleigh scattering, photoelectric effect, Compton scattering, and pair production). The results show that the relevant process in the energy range considered is the Compton Effect, as expected for composite materials of intermediate atomic number and energy range considered.

  5. Monte Carlo simulation of spectrum changes in a photon beam due to a brass compensator

    Energy Technology Data Exchange (ETDEWEB)

    Custidiano, E.R., E-mail: ernesto7661@gmail.com [Department of Physics, FaCENA, UNNE, Av., Libertad 5470, C.P.3400, Corrientes (Argentina); Valenzuela, M.R., E-mail: meraqval@gmail.com [Department of Physics, FaCENA, UNNE, Av., Libertad 5470, C.P.3400, Corrientes (Argentina); Dumont, J.L., E-mail: Joseluis.Dumont@elekta.com [Elekta CMS Software, St.Louis, MO (United States); McDonnell, J., E-mail: josemc@express.com.ar [Cumbres Institute, Riobamba 1745, C.P.2000, Rosario, Santa Fe (Argentina); Rene, L, E-mail: luismrene@gmail.com [Radiotherapy Center, Crespo 953, C.P.2000, Rosario, Santa Fe (Argentina); Rodriguez Aguirre, J.M., E-mail: juakcho@gmail.com [Department of Physics, FaCENA, UNNE, Av., Libertad 5470, C.P.3400, Corrientes (Argentina)

    2011-06-15

    Monte Carlo simulations were used to study the changes in the incident spectrum when a poly-energetic photon beam passes through a static brass compensator. The simulated photon beam spectrum was evaluated by comparing it against the incident spectra. We also discriminated the changes in the transmitted spectrum produced by each of the microscopic processes. (i.e. Rayleigh scattering, photoelectric effect, Compton scattering, and pair production). The results show that the relevant process in the energy range considered is the Compton Effect, as expected for composite materials of intermediate atomic number and energy range considered.

  6. The Observation of TGSCC Nucleation in α-Brass/NH3 System

    International Nuclear Information System (INIS)

    Kim, Joung Soo

    1991-01-01

    Transgranular stress corrosion cracking (TGSCC) of α-brass in cuprous ammoniacal solution was investigated to illustrate the nucleation (initiation) mechanism of TGSCC. The cuprous ammoniacal solution used tin this study is at equilibrium with Cu, which means no formation of oxide film on the specimen surface and no general corrosion occurring. TGSCC nucleation was observed to occur by localized preferential anodic corrosion along slip traces formed on the specimen surface during straining in solution. The orientation of crack surfaces formed by the nucleation and the propagation of TGSCC were different from each other: the former is {111} and the latter {110}. This represents that both events do not occur by the same mechanism. The observation of TGSCC nucleation in this investigation also shows that the thin film technique using TEM is not appropriate for a study on the propagation mechanism of TGSCC

  7. Characterization of Schottky barrier diodes fabricated from electrochemical oxidation of {alpha} phase brass

    Energy Technology Data Exchange (ETDEWEB)

    Bond, John W., E-mail: jwb13@le.ac.u [Forensic Research Centre, University of Leicester, Leicester LE1 7 EA (United Kingdom)

    2011-04-01

    By careful selection of chloride ion concentration in aqueous sodium chloride, electrochemical oxidation of {alpha} phase brass is shown to permit fabrication of either p-type copper (I) oxide/metal or n-type zinc oxide/metal Schottky barrier diodes. X-ray photoelectron and Auger electron spectroscopies provide evidence that barrier formation and rectifying qualities depend on the relative surface abundance of copper (I) oxide and zinc oxide. X-ray diffraction of the resulting diodes shows polycrystalline oxides embedded in amorphous oxidation products that have a lower relative abundance than the diode forming oxide. Conventional I/V characteristics of these diodes show good rectifying qualities. When neither of the oxides dominate, the semiconductor/metal junction displays an absence of rectification.

  8. Slow strain rate stress corrosion cracking under multiaxial deformation conditions: technique and application to admiralty brass

    International Nuclear Information System (INIS)

    Blanchard, W.K.; Heldt, L.A.; Koss, D.

    1984-01-01

    A set of straightforward experimental techniques are described for the examination of slow strain rate stress corrosion cracking (SCC) of sheet deforming under nearly all multiaxial deformation conditions which result in sheet thinning. Based on local fracture strain as a failure criterion, the results contrast stress corrosion susceptibility in uniaxial tension with those in both plane strain and balanced biaxial tension. These results indicate that the loss of ductility of the brass increases as the stress state changes from uniaxial toward balanced biaxial tension

  9. The Belgian repository of fundamental atomic data and stellar spectra (BRASS). I. Cross-matching atomic databases of astrophysical interest

    Science.gov (United States)

    Laverick, M.; Lobel, A.; Merle, T.; Royer, P.; Martayan, C.; David, M.; Hensberge, H.; Thienpont, E.

    2018-04-01

    Context. Fundamental atomic parameters, such as oscillator strengths, play a key role in modelling and understanding the chemical composition of stars in the Universe. Despite the significant work underway to produce these parameters for many astrophysically important ions, uncertainties in these parameters remain large and can propagate throughout the entire field of astronomy. Aims: The Belgian repository of fundamental atomic data and stellar spectra (BRASS) aims to provide the largest systematic and homogeneous quality assessment of atomic data to date in terms of wavelength, atomic and stellar parameter coverage. To prepare for it, we first compiled multiple literature occurrences of many individual atomic transitions, from several atomic databases of astrophysical interest, and assessed their agreement. In a second step synthetic spectra will be compared against extremely high-quality observed spectra, for a large number of BAFGK spectral type stars, in order to critically evaluate the atomic data of a large number of important stellar lines. Methods: Several atomic repositories were searched and their data retrieved and formatted in a consistent manner. Data entries from all repositories were cross-matched against our initial BRASS atomic line list to find multiple occurrences of the same transition. Where possible we used a new non-parametric cross-match depending only on electronic configurations and total angular momentum values. We also checked for duplicate entries of the same physical transition, within each retrieved repository, using the non-parametric cross-match. Results: We report on the number of cross-matched transitions for each repository and compare their fundamental atomic parameters. We find differences in log(gf) values of up to 2 dex or more. We also find and report that 2% of our line list and Vienna atomic line database retrievals are composed of duplicate transitions. Finally we provide a number of examples of atomic spectral lines

  10. A STUDY TO EXPLORE THE POSSIBLE USES OF X-RAY MOTION PICTURE PHOTOGRAPHY FOR THE IMPROVEMENT OF BRASS INSTRUMENT TEACHING. SUMMARY REPORT.

    Science.gov (United States)

    MERRIMAN, LYLE C.

    THE OBJECTIVE OF THIS STUDY WAS TO COLLECT INFORMATION WHICH WOULD LEAD TO MORE EFFICIENT TEACHING OF SUCH FUNDAMENTALS OF BRASS INSTRUMENT PERFORMANCE AS PITCH, DYNAMICS, AND ARTICULATION. FIVE FRENCH HORN AND FIVE TRUMPET PLAYERS WERE PHOTOGRAPHED BY MEANS OF CINEFLUOROGRAPHY DURING THE PERFORMANCE OF CERTAIN MUSICAL EXERCISES. REPRESENTATIVE…

  11. Electrochemical and Corrosion Properties of Aluminum Brass in Seawater Desalination Environments

    Directory of Open Access Journals (Sweden)

    Hong JU

    2017-11-01

    Full Text Available The corrosion behavior and mechanism of aluminum brass (HAl77-2 in seawater desalination plant were investigated using electrochemical measurement, Scanning Electronic Microscope (SEM and Energy Dispersive X-ray spectroscopy (EDX analysis. The electrochemical results revealed that the corrosion of HAl77-2 in the desalination artificial seawater depended on chloride ion concentrations, displaying a maximum with a chloride ion concentration of 2.3 wt.%. Corrosion rate of HAl77-2 initial increased and subsequently decreased with the increasing of chloride ion concentration. Moreover, corrosion of HAl77-2 becomes more severe when temperature rises. The above results obtained by electrochemical impedance spectroscopy and potentiodynamic polarization tests were in a good agreement. The results of SEM and EDX methods showed selective localized corrosion appeared remarkably on the surface of HAl77-2.DOI: http://dx.doi.org/10.5755/j01.ms.23.4.17170

  12. Study on the Formation and Precipitation Mechanism of Mn5Si3 Phase in the MBA-2 Brass Alloy

    Science.gov (United States)

    Li, Hang; Jie, Jinchuan; Zhang, Pengchao; Jia, Chunxu; Wang, Tongmin; Li, Tingju

    2016-06-01

    Mn5Si3 is an attractive dispersion in the special brass, owing to its high hardness and high wear resistance. In the present study, synchrotron X-ray radiography and rapid cooling were applied to investigate the formation mechanism of Mn5Si3 phase in the MBA-2 brass alloy. The primary Mn5Si3 phase is proved to exist stably in the alloy melt and nucleate from the melt at temperatures above 1373 K (1100 °C). In addition, the precipitation mechanism of Mn5Si3 phase is addressed systematically by the isothermal heat treatment. The Mn5Si3 particles are observed to precipitate from the matrix at temperatures above 1023 K (750 °C), and a crystallographic orientation relationship is found between the precipitated Mn5Si3 particle and β phase: (110)_{β } //(1overline{1} 00)_{{{{Mn}}5 {{Si}}3 }} and [overline{1} 11]_{β } //[11overline{2} overline{2} ]_{{{{Mn}}5 {{Si}}3 }} . However, the precipitation of Mn5Si3 phase is thermodynamically inhibited at lower temperatures, which can be ascribed to the increase in the Gibbs free energy of formation of Mn5Si3 with decreasing the temperature.

  13. Analysis and Solution to the Crucial Problems during Brass Instrument Playing%铜管演奏把握性问题的分析与处理

    Institute of Scientific and Technical Information of China (English)

    张良; 史育松

    2015-01-01

    The paper lists and analyzes the crucial problems during brass instruments playing. And it also sums up three factors during brass instruments which can cause the problems:playing skill ,playing psychology and physical capacity as well, and offers specific solutions to the problems.%本文列举了以往铜管演奏者在演奏中出现的把握性问题,并对其进行了分析研究,认为至少有3个方面的原因:演奏技术的问题,演奏心理的问题,体力与体能的原因。针对这3个方面的原因文章提出了具体的解决办法。

  14. Conversion of Carbon Dioxide to Ethanol by Electrochemical Synthesis Method Using Brass as A Cathode

    Directory of Open Access Journals (Sweden)

    Septian Ramadan

    2017-09-01

    Full Text Available The effect of potential and gas flow rate were investigated to determine the optimum conditions of the electrochemical synthesis process to convert carbon dioxide to ethanol. The conversion process is carried out using a NaHCO3 electrolyte solution in an electrochemical reactor equipped with a cathode and anode. As cathode is used brass, while as anode is used carbon. The result of the electrochemical synthesis process was analyzed by gas chromatography to determine the content of the compounds produced qualitatively and quantitatively. The optimum electrochemical synthesis conditions to convert carbon dioxide to ethanol are potential and gas flow rate are 3 volts and 0.5 L/minutes with ethanol concentration yielded 1.32%.

  15. Standard specification for leak detector solutions intended for use on brasses and other copper alloys

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2005-01-01

    1.1 This specification covers the requirements for leak detector solutions suitable for use in checking the leakage of valves, pipes, fittings, joints, and so forth of a pressurized gas system fabricated from brasses and other copper alloys. 1.2 This specification deals with the stress corrosion cracking aspect of leak detector solutions. The effectiveness, chemical, physical and mechanical properties of leak detector solutions are not within the scope of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.

  16. Propagation of stress corrosion cracks in alpha-brasses

    Energy Technology Data Exchange (ETDEWEB)

    Beggs, Dennis Vinton [Univ. of Illinois, Urbana-Champaign, IL (United States)

    1981-01-01

    Transgranular and intergranular stress corrosion cracks were investigated in alpha-brasses in a tarnishing ammoniacal solution. Surface observation indicated that the transgranular cracks propagated discontinuously by the sudden appearance of a fine crack extending several microns ahead of the previous crack tip, often associated with the detection of a discrete acoustic emission (AE). By periodically increasing the deflection, crack front markings were produced on the resulting fracture surfaces, showing that the discontinuous propagation of the crack trace was representative of the subsurface cracking. The intergranular crack trace appeared to propagate continuously at a relatively blunt crack tip and was not associated with discrete AE. Under load pulsing tests with a time between pulses, Δt greater than or equal to 3 s, the transgranular fracture surfaces always exhibited crack front markings which corresponded with the applied pulses. The spacing between crack front markings, Δx, decreased linearly with Δt. With Δt less than or equal to 1.5 s, the crack front markings were in a one-to-one correspondence with applied pulses only at relatively long crack lengths. In this case, Δx = Δx* which approached a limiting value of 1 μm. No crack front markings were observed on intergranular fracture surfaces produced during these tests. It is concluded that transgranular cracking occurs by discontinuous mechanical fracture of an embrittled region around the crack tip, while intergranular cracking results from a different mechanism with cracking occurring via the film-rupture mechanism.

  17. The influence of positron trapping at vacancies on a pattern of the Fermi surface of #betta#-brass studied by positron annihilation

    International Nuclear Information System (INIS)

    Rozenfeld, B.; Chabik, S.; Pajak, J.

    1982-01-01

    Angular correlations of positron annihilation quanta (ACPAQ) have been measured for differently oriented monocrystalline samples of the ordered #betta#-brass under conditions permitting the neglecting of the trapping of positrons at vacancies as well as in the case when almost all the positrons annihilate being trapped at vacancies. It has been shown that trapping of positrons at vacancies can make the observation of the directional anisotropy in electron momentum distribution impossible. (Auth.)

  18. Electrochemical evaluation of the influence of pseudomonas sp on aluminium brass in seawater

    International Nuclear Information System (INIS)

    Frontini, Maria Alejandra; Rosso de Sanchez, Susana

    2004-01-01

    The development of a biofilm on metallic surfaces generates serious problems for the acceleration of corrosive processes. The control of the development of the biological film is important because its formation, among other effects, causes fouling of the surface where it has developed, producing differential aeration cells and aggressive metabolites. The influence of surface films was studied by applying electrochemical techniques in artificial seawater with and without bacteria, under different immersion times. Since the pitting potential (Epic) defines the metals' ability to resist pitting corrosion, a measure of susceptibility to pitting in aggressive solutions is considered. The pitting potential was studied in the systems being studied as well as the influence of seawater + ClO - ion biocides on the systems, since the biocides used was sodium hypochlorite (NaCIO). The material used was aluminum brass and a wild bacterial strain was used, which was isolated from the tubes by a heat exchanger from a thermoelectric plant (CW)

  19. Experimental determination of the effects of annealing on the micro-structures and mechanical properties of cold-worked alpha-brass

    Science.gov (United States)

    Edward, Aghogho Bright; Izelu, Christopher

    2013-12-01

    Experimental determination of the effect of annealing on the microstructure and mechanical properties of a cold work 70 - 30 brass, was carried out by subjecting specimens of the material to various degrees of cold-work (20%, 40% and 60%), by straining using a tensile machine. The specimens for each degree of cold work were then annealed at 250°C, 350°C, 450°C and 600°C, for 30 minutes. The approach involves the use of metallographic techniques: grinding, polishing and etching to reveal the microstructure while tensile test was carried out on the specimen using a Monsanto tensometer so as to obtain the load/extension graph from which the tensile strength and hardness values were obtained. From the results obtained, it was conclusive that annealing produced finer grains and eliminates prior cold work whereby the material becomes ductile. However, there should be an appreciable deformation for this effect to be noticed. One important aspect of re-crystallization in structural materials is that there is a loss of strength which accompanies disappearance of the cold-worked grains when subjected to high temperature applications. Yet, it is often difficult to establish the exact range of permissible temperature. This work establishes a range for the re-crystallization of alpha brass as 350°C < TC < 450°C, where TC is the re-crystallization temperature. Thus, it will be safe to apply this material at temperatures below 350°C, without fear of structural changes with accompanying lost in strength.

  20. Effect of mode of rolling on development of texture and microstructure in two-phase (α + β) brass

    International Nuclear Information System (INIS)

    Garg, Rohini; Ranganathan, S.; Suwas, Satyam

    2010-01-01

    The evolution of microstructure and texture during deformation of two-phase (α + β) brass was studied for different initial microstructure and texture. The deformation processing involved unidirectional and multi-step cross-rolling. The bulk textures were determined by measuring the pole figures and calculating the orientation distribution function ODF for both α (fcc) and β (bcc) phases, while the microstructure and other microstructural parameters were measured through optical microscopy and scanning electron microscopy with electron back scatter diffraction (SEM-EBSD). Results indicate that textures developed after unidirectional rolling and multi-step cross-rolling are significantly different. The variation in initial texture had a pronounced effect on the development of texture in the α phase during subsequent deformation.

  1. Effect of mode of rolling on development of texture and microstructure in two-phase ({alpha} + {beta}) brass

    Energy Technology Data Exchange (ETDEWEB)

    Garg, Rohini; Ranganathan, S. [Department of Materials Engineering, Indian Institute of Science, Bangalore 560012 (India); Suwas, Satyam, E-mail: satyamsuwas@met.iisc.ernet.in [Department of Materials Engineering, Indian Institute of Science, Bangalore 560012 (India)

    2010-07-15

    The evolution of microstructure and texture during deformation of two-phase ({alpha} + {beta}) brass was studied for different initial microstructure and texture. The deformation processing involved unidirectional and multi-step cross-rolling. The bulk textures were determined by measuring the pole figures and calculating the orientation distribution function ODF for both {alpha} (fcc) and {beta} (bcc) phases, while the microstructure and other microstructural parameters were measured through optical microscopy and scanning electron microscopy with electron back scatter diffraction (SEM-EBSD). Results indicate that textures developed after unidirectional rolling and multi-step cross-rolling are significantly different. The variation in initial texture had a pronounced effect on the development of texture in the {alpha} phase during subsequent deformation.

  2. Ultrasound-Assisted Transient Liquid Phase Bonding of Magnesium Alloy Using Brass Interlayer in Air

    Institute of Scientific and Technical Information of China (English)

    Zhiwei Lai; Ruishan Xie; Chuan Pan; Xiaoguang Chen; Lei Liu; Wenxian Wang; Guisheng Zou

    2017-01-01

    The microstructure evolution and oxide film behavior in ultrasound-assisted transient liquid phase (U-TLP) bonding of Mg alloy were investigated by applying different ultrasonic time at 460℃ withbrass interlayer in air.The results indicated that with increasing ultrasonic time,brass interlayer disappeared gradually and the Mg-Cu-Zn eutectic compounds were formed.The eutectic compounds in the joint decreased as the ultrasonic time increased further.The oxide removal process was divided into four steps.Continuous oxide film at the interface was partially fractured by ultrasonic vibration,and then suspended into liquid by undermining eutectic reaction.After that,the suspended oxide film was broken into small oxide fragments by ultrasonic cavitation effect,which was finally squeezed out of the joint by ultrasonic squeeze action.In addition,the mechanical properties of the joints were investigated.The maximum shear strength of the joint reached 105 MPa,which was 100% of base metal.

  3. Performance capabilities of EDM of high carbon high chromium steel with copper and brass electrodes

    Science.gov (United States)

    Surekha, B.; Swain, Sudiptha; Suleman, Abu Jafar; Choudhury, Suvan Dev

    2017-07-01

    The paper address the statistical modeling of input-output relationships of electric discharge machining. In the present work, peak current (I) pulse on time (T) and gap voltage of electric discharge machining (EDM) process are chosen as control parameters to analyze the performance of the process. The output characteristics, namely radial overcut, electrode wear rate (EWR) and metal removal rate (MRR) are treated as the responses. A full factorial design (FFD) of experiments has been used to conduct the experiments and linear regression models are developed for different process characteristics. While conducting the experiments, high carbon and high chromium steel is considered as work piece material and brass and copper are used as electrode material. It is important to note that the experimental conditions are kept similar while machining with the help of different electrode materials. The data obtained from the experiments has been used to develop the regression models for three process parameters for two electrode materials.

  4. Tribological studies of composite material based on CuZn38Al2Mn1Fe brass strengthened with δ-alumina fibres

    Directory of Open Access Journals (Sweden)

    J. W. Kaczmar

    2010-10-01

    Full Text Available The results of tribological studies (friction coefficient, wear resistance of the frictional couple of composite material based on CuZn38Al2Mn1Fe brass strengthened with δ-alumina fibres (Saffil and cast iron are shown in this paper. The wear investigations were conducted applying the tribological pin-on-disc tester and the friction forces between composite materials containing 10 and 20 vol. % of δ-alumina fibres (Saffil and cast iron were registered. Wear was determined on the base of the specimen mass loss after 1, 3,5 and 8.5 km of friction distance.

  5. Standard test method for determining whether gas-leak-detector fluid solutions can cause stress corrosion cracking of brass alloys

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2005-01-01

    1.1 This test method covers an accelerated test method for evaluating the tendency of gas leak detection fluids (LDFs) to cause stress corrosion cracking (SCC) of brass components in compressed gas service. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.

  6. Determination of the speed of corrosion of aluminum brass in drinking water

    International Nuclear Information System (INIS)

    Valcarce, M.B; Vasquez, M; Sanchez, S.R de

    2004-01-01

    Copper alloys are widely used for water conduits. This work defines the speed of corrosion of aluminum brass (Cu76Zn22Al2) in potable water by comparing the results from electrochemical tests and from weight loss tests. The chosen medium is synthetic drinking water (pH 7.6) whose composition is the average for the drinking water in Mar del Plata city. Coupons were prepared for the weight loss test, which were kept in artificial potable water for 90 days. The flow of corrosion was determined based on the resulting weight loss. After the period of immersion, the coupons showed pitting. The resistance to polarization (Rp) was also determined at different immersion times with potential jumps, potentiodynamic sweeps and electrochemical impedance spectroscopy (EIS). The Rp values obtained with the different electrochemical methods are in agreement, and they increase over time. This increase can be attributed to the growth of a layer of oxide over the metallic surface. Based on the record of polarization curves the Tafel slopes were obtained and the corrosion current was estimated after 2 hrs and 192 hrs of immersion. The corrosion current values obtained for the different electrochemical methods match the results obtained from the weight loss test (CW)

  7. Contribution to the knowledge of the Cu-Sn-Zn system for compositions close to brass alloys

    International Nuclear Information System (INIS)

    Vilarinho, C.; Soares, D.; Castro, F.

    2004-01-01

    The effect of tin content in the equilibrium phases of the Cu-Zn-based alloys, within the range of chemical compositions with interest to brass producers is described. For this purpose, ternary alloys with copper contents between 55.4 and 67.5 wt.% and tin contents up to 5.30 wt.% have been studied. The chemical composition of each alloy has been determined by X-ray fluorescence spectrometry (XRF). Isothermal homogenization, followed by rapid cooling, has been employed to determine the equilibrium phases at different temperatures. The homogenized alloys have been observed by scanning electron microscopy and the respective chemical analysis of the phases determined by electron probe microanalysis (EPMA). The statistical analysis of the obtained results enable to correlate the chemical composition of equilibrium phases with temperature. The chemical composition of the three-phase field, for the studied temperatures, has also been determined

  8. Electrochemical performances of diamond-like carbon coatings on carbon steel, stainless steel, and brass

    International Nuclear Information System (INIS)

    Hadinata, Samuel-Sudibyo; Lee, Ming-Tsung; Pan, Szu-Jung; Tsai, Wen-Ta; Tai, Chen-Yi; Shih, Chuan-Feng

    2013-01-01

    Diamond-like carbon (DLC) coatings have been deposited onto stainless steel, carbon steel and brass by plasma-enhanced chemical vapor deposition, respectively. Atomic arrangement, chemical structure, surface morphology and cross-section microstructure of the DLC coatings were examined by X-ray diffraction, Raman scattering spectroscopy and scanning electron microscopy. The electrochemical behaviors of the DLC coatings in 3.5 wt.% NaCl solution were investigated by performing an open circuit potential (OCP) measurement and a potentiodynamic polarization test. The experimental results showed that properly deposited DLC coatings could cause an increase of OCP by hundreds of millivolts and a reduction of anodic current density by several orders of magnitude as compared to that of the substrate. The results also demonstrated that electrochemical techniques could be used as tools to detect the soundness of the DLC coating by examining OCP and polarization curve, which varied with the form of defect and depended on the type of substrate. - Highlights: ► The substrate could affect the quality of diamond-like carbon (DLC) coating. ► Defect-free DLC coating exhibited extremely low anodic current density. ► The quality of DLC coating on metal could be evaluated by electrochemical test

  9. Electrochemical performances of diamond-like carbon coatings on carbon steel, stainless steel, and brass

    Energy Technology Data Exchange (ETDEWEB)

    Hadinata, Samuel-Sudibyo; Lee, Ming-Tsung [Department of Materials Science and Engineering, National Cheng Kung University, 1, Ta-Hsueh Road, Tainan 701, Taiwan (China); Pan, Szu-Jung [Ocean Energy Research Center, Tainan Hydraulics Laboratory, National Cheng Kung University, 1, Ta-Hsueh Road, Tainan 701, Taiwan (China); Tsai, Wen-Ta, E-mail: wttsai@mail.ncku.edu.tw [Department of Materials Science and Engineering, National Cheng Kung University, 1, Ta-Hsueh Road, Tainan 701, Taiwan (China); Ocean Energy Research Center, Tainan Hydraulics Laboratory, National Cheng Kung University, 1, Ta-Hsueh Road, Tainan 701, Taiwan (China); Tai, Chen-Yi [Ocean Energy Research Center, Tainan Hydraulics Laboratory, National Cheng Kung University, 1, Ta-Hsueh Road, Tainan 701, Taiwan (China); Shih, Chuan-Feng [Ocean Energy Research Center, Tainan Hydraulics Laboratory, National Cheng Kung University, 1, Ta-Hsueh Road, Tainan 701, Taiwan (China); Department of Electrical Engineering, National Cheng Kung University, 1, Ta-Hsueh Road, Tainan 701, Taiwan (China)

    2013-02-01

    Diamond-like carbon (DLC) coatings have been deposited onto stainless steel, carbon steel and brass by plasma-enhanced chemical vapor deposition, respectively. Atomic arrangement, chemical structure, surface morphology and cross-section microstructure of the DLC coatings were examined by X-ray diffraction, Raman scattering spectroscopy and scanning electron microscopy. The electrochemical behaviors of the DLC coatings in 3.5 wt.% NaCl solution were investigated by performing an open circuit potential (OCP) measurement and a potentiodynamic polarization test. The experimental results showed that properly deposited DLC coatings could cause an increase of OCP by hundreds of millivolts and a reduction of anodic current density by several orders of magnitude as compared to that of the substrate. The results also demonstrated that electrochemical techniques could be used as tools to detect the soundness of the DLC coating by examining OCP and polarization curve, which varied with the form of defect and depended on the type of substrate. - Highlights: ► The substrate could affect the quality of diamond-like carbon (DLC) coating. ► Defect-free DLC coating exhibited extremely low anodic current density. ► The quality of DLC coating on metal could be evaluated by electrochemical test.

  10. Process Parameters Optimization for Friction Stir Welding of Pure Aluminium to Brass (CuZn30 using Taguchi Technique

    Directory of Open Access Journals (Sweden)

    Elfar O. M. R.

    2016-01-01

    Full Text Available In this research, the friction stir welding of dissimilar commercial pure aluminium and brass (CuZn30 plates was investigated and the process parameters were optimized using Taguchi L9 orthogonal array. The considered process parameters were the rotational speed, traverse speed and pin offset. The optimum setting was determined with reference to ultimate tensile strength of the joint. The predicted optimum value of ultimate tensile strength was confirmed by experimental run using optimum parameters. Analysis of variance revealed that traverse speed is the most significant factor in controlling the joint tensile strength and pin offset also plays a significant role. In this investigation, the optimum tensile strength is 50% of aluminium base metal. Metallographic examination revealed that intermetallic compounds were formed in the interface of the optimum joint where the tensile failure was observed to take place.

  11. Investigation about the influence of the mechanical properties of lead core and brass jacket of a NATO 7.62 mm ball bullet in numerical simulations of ballistic impacts

    Directory of Open Access Journals (Sweden)

    Scapin M.

    2012-08-01

    Full Text Available In the present work a validated numerical approach has been used in order to build a robust and reliable FE model of the impact of a NATO 7.62 mm ball bullet, against an aluminium transmission shaft. The bullet is a full metal jacket type, with a lead alloy core and a brass jacket. Target shaft is made by an Al6061-T6 aluminium alloy. According to the soft core (lead alloy of the bullet, most effort has been spent in order to evaluate the effect of bullet materials mechanical properties on the numerical results. Numerical analyses, carried out using the non-linear dynamic finite element solver Abaqus∖Explicit 6.10, have been performed focusing on core and jacket material behaviour (target material, Al6061-T6, has been previously calibrated by the authors. Thus numerical analyses have been performed considering for the mechanical behaviour of the bullet both a simplified approach (as reported in literature and new material data (with strain rate effect obtained by means of experimental tests on the two materials (lead and brass with specimens cut directly from the bullet. Finally the results of the analyses have been compared with real experimental ballistic tests.

  12. The Effects of Voltage and Concentration of Sodium Bicarbonate on Electrochemical Synthesis of Ethanol from Carbon Dioxide Using Brass as Cathode

    Science.gov (United States)

    Ramadan, Septian; Fariduddin, Sholah; Rizki Aminudin, Afianti; Kurnia Hayatri, Antisa; Riyanto

    2017-11-01

    The effects of voltage and concentration of sodium bicarbonate were investigated to determine the optimum conditions of the electrochemical synthesis process to convert carbon dioxide into ethanol. The conversion process is carried out using a sodium bicarbonate electrolyte solution in an electrochemical synthesis reactor equipped with a cathode and anode. As the cathode was used brass, while as the anode carbon was utilized. Sample of the electrochemical synthesis process was analyzed by gas chromatography to determine the content of the compounds produced. The optimum electrochemical synthesis conditions to convert carbon dioxide into ethanol are voltage and concentration of sodium bicarbonate are 3 volts and 0.4 M with ethanol concentration of 1.33%.

  13. Identification of Control Parameters for Brass Player’s Embouchure by Measuring Contact Pressure on the Teeth Buccal Surface

    Science.gov (United States)

    Kourakata, Itaru; Moriyama, Kozo; Hara, Toshiaki

    For the technical improvement for brass instrument players it is important to obtain the detailed control parameters for embouchure building. While many investigators have reported the preliminary data on the muscle behavior, the precise aspects are unrevealed so far. The purpose of the present paper is to study dynamic perioral muscle behavior of French horn players and to investigate their lip valve function by measuring the contact pressure on teeth buccal surface during playing. It was shown from the experimental results that the advanced players contracted depressor angulioris and levator angulioris especially for high tone playing. It is considered that the combined contraction by these muscles contributes to forming smaller lip aperture being suitable to produce higher tones. Inversely a strong contraction of m. buccinator, which is widely believed to work to give hard tension to player’s lip, was observed insignificantly in the advanced players.

  14. Evaluation of dislocation density in copper and brass α deformed by XRD peak width analysis

    International Nuclear Information System (INIS)

    Sousa, Talita Gama de

    2014-01-01

    The determination of dislocation density in metallic materials has been available for many years in scientific environment. This is due to the fact that the dislocations are the main responsible for plastic deformation, which, thereafter, markedly influences the mechanical properties. In this work, the dislocation density was analyzed through peak broadening of Xray diffraction (XRD) using Convolutional Multiple Whole Profile (CMWP) program. The measurements obtained by XRD were compared with those obtained from images observed by transmission electronic microscopy (TEM). The materials used in this study were pure copper and brass α as alloy 268 (6 % Cu and 34 % Zn), deformed by rolling and ECA (equal channel angular extrusion) processes. The results indicate that the XRD is a powerful tool for the characterization of the microstructure in relation to the dislocation density, as they were consistent to the TEM measurements, and also showed good relationship with measurements of hardness. Furthermore, through the dislocation density it was possible to verify the influence of stacking fault energy (SFE) in the evolution of the copper samples deformation process and its alloy, and that the presence of texture in rolled samples did not impair the measurements obtained by XRD technique. (author)

  15. Extending the magnetoelectric efficiency of an MFC/brass/NdFeB energy harvester by coupling a pair of movable magnets

    Science.gov (United States)

    Leung, Chung Ming; Wang, Ya

    2017-10-01

    In this letter, an MFC/brass/NdFeB tip magnet three-phase cantilever beam was coupled with a pair of movable magnets to harness energy from alternating magnetic fields. By coupling with a pair of moveable magnets, both bandwidth and magnetoelectric (ME) voltage coefficient (α\\text{V}) were largely increased by 25% and 87.5%, respectively, in comparison with the same harvester coupled with stationary magnets. Such improvements were attributed to magnetic energy introduced by the moving magnets. Experiments also revealed the boundary positions of external magnets (movable and stationary) where the repulsive magnetic forces jumped to the attractive ones, and the stiffness hardening switched to the softening process. These results provided a wide-band nonlinear approach to efficiently harvest/detect the low-frequency alternating magnetic field energies.

  16. Microbiologically influenced corrosion evaluation on brass (UNS C68700, UNS C443) and AISI 316 stainless steel; Estudio de la influencia microbiologica en la corrosion de latones (UNS C68700, UNS C443) y acero inoxidable AISI 316

    Energy Technology Data Exchange (ETDEWEB)

    Ohanian, M.; Diaz, V.; Corengia, M.; Russi, P.; Pianzzola, M. J.; Menes, R. J.

    2014-10-01

    Microorganisms may play an important role in the corrosion process and generate conditions which affect the rate and/or the mechanism of deterioration. They become visible by the formation of bio films: clusters of microorganisms and extracellular polymers. These bio films affect not only the durability of the material, but also reduce the heat transfer. The present work studied the growth of aerobic and anaerobic heterotrophic microorganisms and sulfate reducing bacteria on aluminum brass (Uns C.a.), admiralty brass (Uns C.a.) and stainless steel Asi 316 in exposure experiments held in the Bay of Montevideo (Uruguay). The influence of the biofilm growth on the corrosion behavior was studied by electrochemical techniques: polarization curves and Electrochemical Impedance Spectroscopy (Ei). The selection of the most suitable material for the exposure conditions is discussed and hypotheses of the corrosion mechanism are presented. Although stainless steel Asi 316 presented the lowest corrosion rate it showed localized deterioration. (Author)

  17. Densification and volumetric change during supersolidus liquid phase sintering of prealloyed brass Cu28Zn powder: Modeling and optimization

    Directory of Open Access Journals (Sweden)

    Mohammadzadeh A.

    2014-01-01

    Full Text Available An investigation has been made to use response surface methodology and central composite rotatable design for modeling and optimizing the effect of sintering variables on densification of prealloyed Cu28Zn brass powder during supersolidus liquid phase sintering. The mathematical equations were derived to predict sintered density, densification parameter, porosity percentage and volumetric change of samples using second order regression analysis. As well as the adequacy of models was evaluated by analysis of variance technique at 95% confidence level. Finally, the influence and interaction of sintering variables, on achieving any desired properties was demonstrated graphically in contour and three dimensional plots. In order to better analyze the samples, microstructure evaluation was carried out. It was concluded that response surface methodology based on central composite rotatable design, is an economical way to obtain arbitrary information with performing the fewest number of experiments in a short period of time.

  18. RhCd{sub 9+δ} (-1.18 ≤δ≤0.29) a γ-brass related cubic giant cell structure

    Energy Technology Data Exchange (ETDEWEB)

    Jana, Partha Pratim [Indian Institute of Technology, Kharagpur (India). Dept. of Chemistry

    2017-09-01

    The compound RhCd{sub 9+δ} (-1.18 ≤δ≤0.29) has been synthesized and the average structure has been analyzed by single crystal X-ray diffraction. The average structure crystallizes in the face centered cubic space group F43m (216) and contains ∝405 atoms/unit cell. It represents a (2a{sub γ}){sup 3}-superstructure of cubic γ-brass and is isostructural to Rh{sub 7-x}Mg{sub 44+x}. The comparison between the structures of RhCd{sub 9+δ} and Rh{sub 7-x}Mg{sub 44+x} has been presented using a layer description. The structure of the title phase has also been described by a ''cluster'' concept. The electronic structure of RhCd{sub 9+δ} (-1.18 ≤δ≤0.29) shows that the phase is stabilized by a Hume-Rothery mechanism.

  19. A comparative study of microstructure and mechanical properties between friction stir welded single and double phase brass alloys

    International Nuclear Information System (INIS)

    Heidarzadeh, A.; Saeid, T.

    2016-01-01

    This study was done in order to compare the microstructure and mechanical properties of friction stir welded single and double phase brass alloys. The microstructure of the joints were examined using optical microscope, scanning electron microscope (SEM), scanning transmission electron microscope (STEM), and X-ray diffraction. Furthermore, tensile test and fractography were applied to evaluate the mechanical properties of the joints. The results showed that the grain size of the stir zone in the double phase joint was smaller than that of the single phase alloy. In comparison with base metals, both of the joints contained high density of dislocations with a qualitatively similar texture. However, the dislocation density of the double phase joint was somewhat lower than that of the single phase one. Moreover, the joints had higher tensile strength, lower elongation and less ductile fracture compared to their base metals due to their finer grain size and higher dislocation density. The double phase joint had higher strength and lower elongation than single phase joint due to the effect of the second phase.

  20. A comparison of the free vacancy production in α brass by fission reactor neutrons and 14.8-MeV neutrons

    International Nuclear Information System (INIS)

    Damask, A.C.; Van Konynenburg, R.; Borg, R.J.; Dienes, G.J.

    1976-01-01

    Enhancement of substitutional diffusion is observed in α brass (30 wt% Zn) by following the decrease in electrical resistivity with neutron irradiation of a thermally equilibrated alloy; the decrease arises from the increase in short-range order. It was determined by previous research that this diffusion enhancement is largely caused by the annealling of radiation-produced vacancies in excess of the thermal equilibrium concentration. Therefore, the results reported here are based upon a well-established technique. The rate of resistivity change per neutron of different energies will give the relative number of free vacancies produced per neutron. This experiment compares the effect of 14.8 MeV neutrons with neutrons from a fission reactor. The results indicate that 14.8 MeV neutrons produce 10 +- 2 times as many free vacancies as reactor neutrons when the latter are expressed in terms of those neutrons with energies greater than 0.1 MeV. (author)

  1. Synthesis of novel ionic liquids and evaluation of their leaching performance in the recovery of copper and zinc from industrial brass slag

    International Nuclear Information System (INIS)

    Sahina, A.K.; Atalaya, T.S.; Atbakarb, M.; Ocalb, N.; Saridede, M.N.

    2016-01-01

    Imidazolium-based ionic liquids, 1,3-dibenzylimidazolium trifluoroacetate, 1-benzyl-3-ethylimidazolium trifluoroacetate and 1-benzyl-3-propylimidazolium trifluoroacetate were prepared by simple methods, when compared with those in literature sources, and characterized by IR, NMR and GC-MS and LC-MS. These ILs (Ionic Liquids) were employed as leaching agents in the treatment of industrial copper and zinc bearing slag for the recovery of metals. Results showed that synthesized all novel ionic liquids meet the standard specifications of an ionic liquid. Metal recovery rates decrease with time except for zinc dissolution in 1,3-dibenzylimidazolium trifluoroacetate. 1,3-dibenzylimidazolium trifluoroacetate, when compared with others, is a more effective leaching agent for the treatment of copper and zinc bearing brass slag. Metal recovery rates achieved with this IL are 62.58% for zinc and 24.95% for copper. (Author)

  2. Synthesis of novel ionic liquids and evaluation of their leaching performance in the recovery of copper and zinc from industrial brass slag

    Directory of Open Access Journals (Sweden)

    Ayfer Kilicarslan Sahin

    2016-12-01

    Full Text Available Imidazolium-based ionic liquids, 1,3-dibenzylimidazolium trifluoroacetate, 1-benzyl-3-ethylimidazolium trifluoroacetate and 1-benzyl-3-propylimidazolium trifluoroacetate were prepared by simple methods, when compared with those in literature sources, and characterized by IR, NMR and GC-MS and LC-MS. These ILs (Ionic Liquids were employed as leaching agents in the treatment of industrial copper and zinc bearing slag for the recovery of metals. Results showed that synthesized all novel ionic liquids meet the standard specifications of an ionic liquid. Metal recovery rates decrease with time except for zinc dissolution in 1,3-dibenzylimidazolium trifluoroacetate. 1,3-dibenzylimidazolium trifluoroacetate, when compared with others, is a more effective leaching agent for the treatment of copper and zinc bearing brass slag. Metal recovery rates achieved with this IL are 62.58% for zinc and 24.95% for copper.

  3. Synthesis of novel ionic liquids and evaluation of their leaching performance in the recovery of copper and zinc from industrial brass slag

    Energy Technology Data Exchange (ETDEWEB)

    Sahina, A.K.; Atalaya, T.S.; Atbakarb, M.; Ocalb, N.; Saridede, M.N.

    2016-07-01

    Imidazolium-based ionic liquids, 1,3-dibenzylimidazolium trifluoroacetate, 1-benzyl-3-ethylimidazolium trifluoroacetate and 1-benzyl-3-propylimidazolium trifluoroacetate were prepared by simple methods, when compared with those in literature sources, and characterized by IR, NMR and GC-MS and LC-MS. These ILs (Ionic Liquids) were employed as leaching agents in the treatment of industrial copper and zinc bearing slag for the recovery of metals. Results showed that synthesized all novel ionic liquids meet the standard specifications of an ionic liquid. Metal recovery rates decrease with time except for zinc dissolution in 1,3-dibenzylimidazolium trifluoroacetate. 1,3-dibenzylimidazolium trifluoroacetate, when compared with others, is a more effective leaching agent for the treatment of copper and zinc bearing brass slag. Metal recovery rates achieved with this IL are 62.58% for zinc and 24.95% for copper. (Author)

  4. Microstructure and Mechanical Properties of Stainless Steel/Brass Joints Brazed by Sn-Electroplated Ag Brazing Filler Metals

    Science.gov (United States)

    Wang, Xingxing; Peng, Jin; Cui, Datian

    2018-05-01

    To develop a high-Sn-content AgCuZnSn brazing filler metal, the BAg50CuZn was used as the base filler metal and a Sn layer was electroplated upon it. Then, the 304 stainless steel and the H62 brass were induction-brazed with the Sn-plated brazing filler metals. The microstructures of the joints were examined with an optical microscope, a scanning electron microscope and an x-ray diffractometer. The corresponding mechanical properties were obtained with a universal tensile testing machine. The results indicated that the induction brazed joints consisted of the Ag phase, the Cu phase and the CuZn phase. When the content of Sn in the Sn-plated Ag brazing filler metal was 6.0 or 7.2 wt.%, the Cu5Zn8, the Cu41Sn11 and the Ag3Sn phases appeared in the brazed joint. The tensile strength of the joints brazed with the Sn-plated filler metal was higher compared to the joints with the base filler metal. When the content of Sn was 6.0 wt.%, the highest tensile strength of the joint reached to 395 MPa. The joint fractures presented a brittle mode, mixed with a low amount of ductile fracture, when the content of Sn exceeded 6.0 wt.%.

  5. Results of the independent radiological verification survey at the former Bridgeport Brass Company Facility, Seymour, Connecticut (SSC001)

    International Nuclear Information System (INIS)

    Foley, R.D.; Rice, D.E.; Allred, J.F.; Brown, K.S.

    1995-03-01

    At the request of the USDOE, a team from ORNL conducted an independent radiological verification survey at the former Bridgeport Brass Company Facility, Seymour, Connecticut, from September 1992 to March 1993. Purpose of the survey was to determine whether residual levels of radioactivity inside the Ruffert Building and selected adjacent areas were rmediated to levels below DOE guidelines for FUSRAP sites. The property was contaminated with radioactive residues of 238 U from uranium processing experiments conducted by Reactive Metals, Inc., from 1962 to 1964 for the Atomic Energy Commission. A previous radiological survey did not characterize the entire floor space because equipment which could not be moved at the time made it inaccessible for radiological surveys. During the remediation process, additional areas of elevated radioactivity were discovered under stationary equipment, which required additional remediation and further verification. Results of the independent radiological verification survey confirm that, with the exception of the drain system inside the building, residual uranium contamination has been remediated to levels below DOE guidelines for unrestricted release of property at FUSRAP sites inside and outside the Ruffert Building. However, certain sections of the drain system retain uranium contamination above DOE surface guideline levels. These sections of pipe are addressed in separate, referenced documentation

  6. Determination of the characteristics of a Schottky barrier formed by latent finger mark corrosion of brass

    International Nuclear Information System (INIS)

    Bond, J W

    2009-01-01

    The ideality factor (η) and barrier height (φ B ) for a metal-copper(I) oxide rectifying contact formed by the latent finger mark corrosion of α phase brass have been determined from forward bias I/V characteristics in the range 0.4 V ≤ V ≤ 0.55 V. Rectifying contacts formed from the finger mark deposits of different people gave η = 1.5-1.6 ± 0.1 and φ B = 0.49-0.52 ± 0.04 V. A Mott-Schottky plot of capacitance-voltage measurements in reverse bias gave the built in potential ψ bi = 0.4 ± 0.1 V, the gradient of the plot confirming the conductivity of the finger mark corrosion as p type. X-ray photoelectron spectroscopy spectra of the corrosion showed that Cu(I), Cu(II) and Zn(II) can co-exist on the surface, the Cu(I) : Cu(II) and Zn : Cu ratios determining whether a rectifying contact is formed. Initial findings suggest that when the concentration of Cu(I) dominates the Cu(I) : Cu(II) ratio (approximately 6 : 1), or when Cu(II) is absent, a rectifying contact can be formed subject to the Zn : Cu ratio being approximately 1 : 3. As the surface concentration of zinc increases, the rectifying contact is degraded until the concentration of zinc approaches that of copper when no evidence of a Schottky barrier is observed and the contact appears ohmic.

  7. The effect of sequential dual-gas testing on laser-induced breakdown spectroscopy-based discrimination: Application to brass samples and bacterial strains

    International Nuclear Information System (INIS)

    Rehse, Steven J.; Mohaidat, Qassem I.

    2009-01-01

    Four Cu-Zn brass alloys with different stoichiometries and compositions have been analyzed by laser-induced breakdown spectroscopy (LIBS) using nanosecond laser pulses. The intensities of 15 emission lines of copper, zinc, lead, carbon, and aluminum (as well as the environmental contaminants sodium and calcium) were normalized and analyzed with a discriminant function analysis (DFA) to rapidly categorize the samples by alloy. The alloys were tested sequentially in two different noble gases (argon and helium) to enhance discrimination between them. When emission intensities from samples tested sequentially in both gases were combined to form a single 30-spectral line 'fingerprint' of the alloy, an overall 100% correct identification was achieved. This was a modest improvement over using emission intensities acquired in argon gas alone. A similar study was performed to demonstrate an enhanced discrimination between two strains of Escherichia coli (a Gram-negative bacterium) and a Gram-positive bacterium. When emission intensities from bacteria sequentially ablated in two different gas environments were combined, the DFA achieved a 100% categorization accuracy. This result showed the benefit of sequentially testing highly similar samples in two different ambient gases to enhance discrimination between the samples.

  8. Study of the diffusion in the {alpha} brasses, using the evaporation or condensation of zinc - influence of the diffusion sense and of impurities (first and second thesis); Etude de la diffusion dans les laitons {alpha} au moyen des methodes d'evaporation ou de condensation du zinc influence du sens de diffusion et de la presence d'impurete (premiere et deuxieme these)

    Energy Technology Data Exchange (ETDEWEB)

    Accary, A. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-12-15

    The author develops a zero concentration extrapolation method for the exact determination of the diffusion coefficient. He applies it to the comparison of the inward and outward diffusion coefficient in {alpha} brasses. In a second part he shows the large influence of traces of some elements such as P, As, Sb, on the diffusion velocity in {alpha} brasses. (author) [French] L'auteur montre comment, au moyen d'une extrapolation a variation de concentration nulle, ces methodes permettent d'atteindre rigoureusement la valeur du coefficient de diffusion. Il les utilise pour comparer la valeur du coefficient de diffusion avec enrichissement en zinc a la valeur du coefficient de diffusion avec appauvrissement en zinc. Dans une seconde partie, il met en evidence la grande influence de traces d'elements tels que le phosphore, l'arsenic, l'antimoine sur la vitesse de diffusion dans les laitons {alpha}. (auteur)

  9. Study of the diffusion in the {alpha} brasses, using the evaporation or condensation of zinc - influence of the diffusion sense and of impurities (first and second thesis); Etude de la diffusion dans les laitons {alpha} au moyen des methodes d'evaporation ou de condensation du zinc influence du sens de diffusion et de la presence d'impurete (premiere et deuxieme these)

    Energy Technology Data Exchange (ETDEWEB)

    Accary, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-12-15

    The author develops a zero concentration extrapolation method for the exact determination of the diffusion coefficient. He applies it to the comparison of the inward and outward diffusion coefficient in {alpha} brasses. In a second part he shows the large influence of traces of some elements such as P, As, Sb, on the diffusion velocity in {alpha} brasses. (author) [French] L'auteur montre comment, au moyen d'une extrapolation a variation de concentration nulle, ces methodes permettent d'atteindre rigoureusement la valeur du coefficient de diffusion. Il les utilise pour comparer la valeur du coefficient de diffusion avec enrichissement en zinc a la valeur du coefficient de diffusion avec appauvrissement en zinc. Dans une seconde partie, il met en evidence la grande influence de traces d'elements tels que le phosphore, l'arsenic, l'antimoine sur la vitesse de diffusion dans les laitons {alpha}. (auteur)

  10. The ultrasonic copper and brass decontamination study; Etude de la decontamination du cuivre et des laitons en presence d'ultra-sons

    Energy Technology Data Exchange (ETDEWEB)

    Courtault, J; Kerdelleau, J de; Mestre, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The use of ultra-sounds as a decontamination technic does not bring an absolute solution. As a function of the materials it seemed necessary to find what was the optimum conditions for using the ultra-sounds and to define not only the ultra-sonic factors but also the chemical solutions which bring some appreciable decontamination factors without bringing any too important corrosion processus. This report gives the results of this study applied to copper and brass. This study allowed to select some effective treatment baths on the two types of contamination: plutonium and fission products. (authors) [French] L'emploi des ultra-sons comme technique de decontamination n'amene pas une solution absolue. Il est apparu necessaire de rechercher en fonction de la nature du materiau a decontaminer quelles etaient les conditions optimales d'utilisation des ultra-sons et de definir alors non seulement les facteurs ultrasoniques mais encore les solutions chimiques qui apportent des facteurs de decontamination appreciables sans amener des phenomenes de corrosion trop importants. Ce rapport donne les resultats de cette etude appliquee au cuivre et aux laitons. Cette etude a permis de selectionner des bains de traitement efficaces dans les deux cas de contamination: plutonium et produits de fission. (auteurs)

  11. Defense Scrap Yard Handbook

    Science.gov (United States)

    1985-06-01

    Shall consist of brass castings, rolled brass, rod brass, tubing and 26 Honey . miscellaneous yellow brasses, including plated brass. Must be free of...surveillance. (See torns include: dry cough , irritation of throat and OSHA 1910.1025) tightness of chest leading to difficulty in breath- (1) Lead...selected conditions, e.g., styrene- up the cure of a compound when added in minor acrylonitrile copolymer resins blended with butadi- quantity as compared

  12. Effects of Brass (Cu3Zn2) as High Thermal Expansion Material on Shrink Disc Performance During High Thermal Loading

    Science.gov (United States)

    Mazlan, MIS; Mohd, SA; Bahar, ND; Aziz, SAA

    2018-03-01

    This research work is focused on shrink disc operation at high temperature. Geometrical and material design selections have been done by taking into consideration the existing shrink disc operating at high temperature condition. The existing shrink disc confronted slip between shaft and shaft sleeve during thermal loading condition. The assessment has been obtained through virtual experiment by using Finite Element Analysis (FEA) -Thermal Transient Stress for 900 seconds with 300 °C of thermal loading. This investigation consists of the current and improved version of shrink disc, where identical geometries and material properties were utilized. High Thermal Expansion (HTE) material has been introduced to overcome the current design of the shrink disc. Brass (Cu3Zn2) has been selected as the HTE material in the improved shrink disc design due to its high thermal expansion properties. The HTE has shown a significant improvement on the total contact area and contact pressure on the shaft and the shaft sleeve. The improved shrink disc embedded with HTE during thermal loading exhibit a minimum of 1244.1 mm2 of the total area on shaft and shaft sleeve which uninfluenced the total contact area at normal condition which is 1254.3 mm2. Meanwhile, the total pressure of improved shrink disc had an increment of 108.1 MPa while existing shrink disc total pressure has lost 17.2 MPa during thermal loading.

  13. Enhanced photoluminescence and Raman properties of Al-Doped ZnO nanostructures prepared using thermal chemical vapor deposition of methanol assisted with heated brass.

    Directory of Open Access Journals (Sweden)

    Tamil Many K Thandavan

    Full Text Available Vapor phase transport (VPT assisted by mixture of methanol and acetone via thermal evaporation of brass (CuZn was used to prepare un-doped and Al-doped zinc oxide (ZnO nanostructures (NSs. The structure and morphology were characterized by field emission scanning electron microscopy (FESEM and x-ray diffraction (XRD. Photoluminescence (PL properties of un-doped and Al-doped ZnO showed significant changes in the optical properties providing evidence for several types of defects such as zinc interstitials (Zni, oxygen interstitials (Oi, zinc vacancy (Vzn, singly charged zinc vacancy (VZn-, oxygen vacancy (Vo, singly charged oxygen vacancy (Vo+ and oxygen anti-site defects (OZn in the grown NSs. The Al-doped ZnO NSs have exhibited shifted PL peaks at near band edge (NBE and red luminescence compared to the un-doped ZnO. The Raman scattering results provided evidence of Al doping into the ZnO NSs due to peak shift from 145 cm-1 to an anomalous peak at 138 cm-1. Presence of enhanced Raman signal at around 274 and 743 cm-1 further confirmed Al in ZnO NSs. The enhanced D and G band in all Al-doped ZnO NSs shows possible functionalization and doping process in ZnO NSs.

  14. Enhanced photoluminescence and Raman properties of Al-Doped ZnO nanostructures prepared using thermal chemical vapor deposition of methanol assisted with heated brass.

    Science.gov (United States)

    Thandavan, Tamil Many K; Gani, Siti Meriam Abdul; San Wong, Chiow; Md Nor, Roslan

    2015-01-01

    Vapor phase transport (VPT) assisted by mixture of methanol and acetone via thermal evaporation of brass (CuZn) was used to prepare un-doped and Al-doped zinc oxide (ZnO) nanostructures (NSs). The structure and morphology were characterized by field emission scanning electron microscopy (FESEM) and x-ray diffraction (XRD). Photoluminescence (PL) properties of un-doped and Al-doped ZnO showed significant changes in the optical properties providing evidence for several types of defects such as zinc interstitials (Zni), oxygen interstitials (Oi), zinc vacancy (Vzn), singly charged zinc vacancy (VZn-), oxygen vacancy (Vo), singly charged oxygen vacancy (Vo+) and oxygen anti-site defects (OZn) in the grown NSs. The Al-doped ZnO NSs have exhibited shifted PL peaks at near band edge (NBE) and red luminescence compared to the un-doped ZnO. The Raman scattering results provided evidence of Al doping into the ZnO NSs due to peak shift from 145 cm-1 to an anomalous peak at 138 cm-1. Presence of enhanced Raman signal at around 274 and 743 cm-1 further confirmed Al in ZnO NSs. The enhanced D and G band in all Al-doped ZnO NSs shows possible functionalization and doping process in ZnO NSs.

  15. Evaluation and characterization of mechanisms controlling fate and effects of Army smokes

    Energy Technology Data Exchange (ETDEWEB)

    Cataldo, D.A.; Ligotke, M.W.; Bolton, H. Jr.; Fellows, R.J.; Van Voris, P.; McKinley, J.P.; Mi, Shu-mei W.; McFadden, K.M.

    1990-08-01

    The primary objective of this study was to characterize the fate and response of soil and biotic components of the terrestrial environment to aerosols, deposited brass, and brass in combination with fog oil. Important physical, chemical, and biotic aspects were investigated using an environmental wind tunnel. Air/surface deposition rates were determined for foliar and soil surfaces, both in the absence and presence of fog oil. Deposition velocities for foliage ranged from 0.1 to 1.0 cm/s at wind speeds of 2 to 10 mph, respectively. Foliar contact toxicity was assessed using five different types of terrestrial vegetation representative of Army training sites and surrounding environments. No significant foliar contact toxicity was observed for brass. The weathering and chemistry of brass aerosols deposited and amended to soils was assessed, along with the impacts of acid precipitation and moisture regimes on weathering rates. Rates of brass weathering and the fate of solubilized Cu and Zn are discussed. The influence of soil weathering processes and brass solubilization on seed germination indicated no detectable effects of brass. However, moderate toxicity effects were noted after seed germination indicated no detectable effects of brass. However, moderate toxicity effects were noted after 160 days of soil incubation. The effects were proportional to soil-loading levels. Influence of soil weathering processes and contaminant solubilization on soil microbiological activities indicated that soil dehydrogenase activity was more susceptible to impacts than was phosphatase activity or microbial biomass. Nitrifying bacteria and heterotrophic bacteria were not significantly affected by brass. Invertebrates (earthworms) associated with soil contaminated with brass were only slightly impacted, and only at loading rates >445 {mu}g/cm{sup 2}.

  16. Condition monitoring and life assessment of lake water cooled admiralty brass condenser tubes of a nuclear power plant

    International Nuclear Information System (INIS)

    De, P.K.; Ghosal, S.K.; Kutty, K.K.; Bhat, H.R.

    2000-01-01

    The present paper deals with the failure of condenser tubes in a nuclear power plant. The tubes were made of arsenical admiralty brass and were cooled using lake water. They were in service for over 25 years. So far about 1000 tubes have been plugged as they failed due to several reasons. In order to assess the remaining life of the existing tubes as well as to investigate the cause of recent tube failures, some of the tubes from the condenser were removed and examined in detail following several procedure. It was observed that in general, wall thickness of the tubes was reduced by 10- 15%. Maximum reduction in wall thickness took place near the water inlet ends. No denting type phenomenon was observed at the tube to tube-support plate crevice locations. At certain locations on ID surfaces of some tubes, small steps, 0.2 mm high, were noticed along the longitudinal direction of the tubes. ID surfaces of the tubes were covered with light gray coloured thin and adherent corrosion products decorated with red spots at places. EDAX analysis showed that these red spots were enriched with copper. While some pits were present on the ID surfaces, the OD surfaces were covered with shining black oxide film. Fracture surfaces of the tubes, which had lost much strength and broke while taking them out of the condenser, showed presence of cleavages with fatigue striations near the OD edges. Mechanical properties of the tubes as such had deteriorated significantly. The tubes were observed to have been degraded to a large extent due to localised corrosion on the ID surfaces and corrosion fatigue damage caused by flow induced vibration. Under the present operational conditions, the tubes are expected to perform satisfactorily for a limited period. (author)

  17. The role of local strains from prior cold work on stress corrosion cracking of α-brass in Mattsson's solution

    International Nuclear Information System (INIS)

    Ulaganathan, Jaganathan; Newman, Roger C.

    2014-01-01

    The dynamic strain rate ahead of a crack tip formed during stress corrosion cracking (SCC) under a static load is assumed to arise from the crack propagation. The strain surrounding the crack tip would be redistributed as the crack grows, thereby having the effect of dynamic strain. Recently, several studies have shown cold work to cause accelerated crack growth rates during SCC, and the slip-dissolution mechanism has been widely applied to account for this via a supposedly increased crack-tip strain rate in cold worked material. While these interpretations consider cold work as a homogeneous effect, dislocations are generated inhomogeneously within the microstructure during cold work. The presence of grain boundaries results in dislocation pile-ups that cause local strain concentrations. The local strains generated from cold working α-brass by tensile elongation were characterized using electron backscatter diffraction (EBSD). The role of these local strains in SCC was studied by measuring the strain distributions from the same regions of the sample before cold work, after cold work, and after SCC. Though, the cracks did not always initiate or propagate along boundaries with pre-existing local strains from the applied cold work, the local strains surrounding the cracked boundaries had contributions from both the crack propagation and the prior cold work. - Highlights: • Plastic strain localization has a complex relationship with SCC susceptibility. • Surface relief created by cold work creates its own granular strain localization. • Cold work promotes crack growth but several other factors are involved

  18. A facile approach for the fabrication of 3D flower-like Cu2S nanostructures on brass mesh with temperature-induced wetting transition for efficient oil-water separation

    Science.gov (United States)

    Niu, Lei; Kang, Zhixin

    2017-11-01

    3D flower-like Cu2S nanostructures on brass meshes have been fabricated for the first time, with a reversible wetting transition and excellent durability. In the present work, we demonstrated a simple and environmentally-benign method to fabricate the nanostructures utilizing an electrolyte containing CuSO4·5H2O, EDTA-2Na and CH3CSNH2. The superhydrophobicity was achieved by drying thoroughly at 200 °C, instead of using low surface energy materials. After annealing at 300 °C for 6 min, the superhydrophobic surface was oxidized and became superhydrophilic. However, the superhydrophobicity can be restored by heating at 200 °C for several hours. In simpler terms, the reversible wetting transition is responded to the temperature. Scanning electron microscopy, X-ray diffractometer, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy were employed to characterize the surfaces and analyze the wetting transition mechanism. Furthermore, different kinds of oily sewages were separated by as-prepared mesh with high separation efficiency. It is believed that this method should have a promising future in expanding the applications of copper alloys.

  19. Experimental set-up for high-power pulsed X-rays on the basis of a high-current electron accelerator diode with a pointed brass cathode and an aluminum anode target

    International Nuclear Information System (INIS)

    Goncharov, V.K.; Krekoten', O.V.; Makarov, V.V.

    2015-01-01

    The main aim of this article is to assess experimentally the possibility for the development and manufacturing of a high-power pulse X-ray source on the basis of a high-current electron accelerator of the diode type. This task was realized using a vacuum diode with the explosive plasma cathode from brass and an anode of aluminum foil 850 microns thick. As a result of the experiments performed, it is shown that, for this metal of the anode, the component of X-rays, propagating along electron beam motion, has bigger energy weight than the reflected one. The photographic paper placed in a black dense paper holder was used as a sensor. It is necessary to mark that at present the current investigations have a purely qualitative character. At the same time, the authors have succeeded to define an angle of divergence (~90°) of the generated radiation after an aluminum target. The possibility of generating bremsstrahlung and also the energy estimates indicate applicability of this installation in pure research, and application-oriented purposes, for example, for monitoring of the radiation stability of different electronic products. (authors)

  20. Standard Practice for Use of Mattsson's Solution of pH 7.2 to Evaluate the Stress- Corrosion Cracking Susceptibility of Copper-Zinc Alloys

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2011-01-01

    1.1 This practice covers the preparation and use of Mattsson's solution of pH 7.2 as an accelerated stress-corrosion cracking test environment for brasses (copper-zinc base alloys). The variables (to the extent that these are known at present) that require control are described together with possible means for controlling and standardizing these variables. 1.2 This practice is recommended only for brasses (copper-zinc base alloys). The use of this test environment is not recommended for other copper alloys since the results may be erroneous, providing completely misleading rankings. This is particularly true of alloys containing aluminum or nickel as deliberate alloying additions. 1.3 This practice is intended primarily where the test objective is to determine the relative stress-corrosion cracking susceptibility of different brasses under the same or different stress conditions or to determine the absolute degree of stress corrosion cracking susceptibility, if any, of a particular brass or brass component ...

  1. Comparison of characteristics parameters in the evaluation of wall thickness diminishing in admiralty brass tubes of the steam condenser, tested by eddy currents

    International Nuclear Information System (INIS)

    Obrutsky, Alba E.; Mendez, Jorge A.; Acosta, Cesar D.; Scopelliti, Jose D.

    1999-01-01

    This work is aimed to appraise the measure of the wall thickness diminishing in the signals evaluation obtained in the inspection of steam condenser by eddy currents. In the analysis of the obtained signals were observed in the brass tubes a great quantity of internal defects whose signal indicates that there were diminishing of the wall thickness between 80% and 100%. With all this information and analyzing the data acquired, the tubes with more important indications were selected to make a more exhaustive study of the found defectology. As first test, it was measured the thickness of the worn tubes, comparing them with the original ones that are in stock. It was verified that the tubes separated for this study presented a 30% less thickness in comparison with the new tubes. A semiquantitative chemical test (EDAX) was made to verify if it was the same material. One of the extracted tubes (066 Y1) was reinspected in order to isolate the area with indications. Once this was performed, it was decided to cut the tube to make a visual inspection and to evaluate to what type of defect corresponds to the signals obtained. In the metallography it was confirm that it was a horseshoe type defect. When performing a dimensional control test of the found real defect, it was checked that the information obtained by eddy currents regarding the diminishing of the wall thickness diminishing was valid. At a last stage of the test, it was proceed to make an study and verification of the used parameters, probes, standards and finally determine which shall be the convenient modifications to minimize errors. (author)

  2. PELATIHAN TEKNIK ELEKTROPLATING NIKEL BAGI INDUSTRI KERAJINAN KUNINGAN DI DESA KAMASAN KABUPATEN KLUNGKUNG

    Directory of Open Access Journals (Sweden)

    T. G. Tirta Nindhia

    2013-12-01

    Full Text Available The Village of Kamasan at Klungkung in the Province of Bali is recognized as a centre of metal handicrafts,especially the handicraft made from brass. Many home industries for the brass handicraft are established in thisvillage. Recently due to Rapid progress of Tourism in Bali, The brass handicraft in Kamasan are growing wellbecause the demand for the souvenir. However some problem arise such as limited of variation, and surface qualityof the brass handicraft that tend to become blurred or dull due to the process of oxidation. This condition makethe brass handicrafts become not so interest as silver handicrafts that can shine for quite long time. To overcomethis problem it is needed to coating the surface of the brass handicrafts so that there will be no contact withoxygen. The coating will be more benefit if able to exhibit more interesting appearance, as what nickel coatingcan affect the appearance of the surface to become like silver but more clear. Equipment for nickel elektroplatingwas designed for this purpose and donated for this purpose. The unique of the equipment that was donated weresmall in size therefore only low electric power is needed, only 1 liter electrolyte was used and can be use manytime. The positive result is obtained for this activity where all participants able to operate the elektroplatingprocess with excellent result.

  3. Influence of bress laminate volume fraction on electromechanical properties of externally laminated coated conductor tapes

    Energy Technology Data Exchange (ETDEWEB)

    Bautista, Zhierwinjay M.; Shin, Hyung Seop [Dept. of Mechanical Design Engineering, Andong National University, Andong (Korea, Republic of); Lee, Jae Hun; Lee, Hun Ju; Moon, Seung Hyun [SuNAM Co Ltd., Anseong (Korea, Republic of)

    2016-09-15

    The enhancement of mechanical properties of coated conductor (CC) tapes in practical application are usually achieved by reinforcing through lamination or electroplating metal layers on either sides of the CC tape. Mechanical or electromechanical properties of the CC tapes have been largely affected by the lamination structure under various loading modes such as tension, bending or even cyclic. In this study, the influence of brass laminate volume fraction on electromechanical properties of RCE-DR processed Gadolinium-barium-copper-oxide (GdBCO) CC tapes was investigated. The samples used were composed of single-side and both-side laminate of brass layer to the Cu-stabilized CC tape and their Ic behaviors were compared to those of the Cu-stabilized CC tape without external lamination. The stress/strain dependences of Ic in laminated CC tapes under uniaxial tension were analyzed and the irreversible stress/strain limits were determined. As a result, the increase of brass laminate volume fraction initially increased the irreversible strain limit and became gradual. The corresponding irreversible stress limit, however, showed no difference even though the brass laminate volume fraction increased to 3.4. But the irreversible load limit linearly increased with the brass laminate volume fraction.

  4. Model tests for corrosion influence of electrode surface on electroosmosis in marine sludge

    Science.gov (United States)

    Zheng, Lingwei; Li, Jinzhu; Shi, Hanru

    2017-11-01

    The corrosion of metal electrodes is inevitable on electroosmosis in soil. Surface corrosion of electrodes is also one of the reasons for increasing energy consumption in electroosmosis treatment. A series of laboratory tests were conducted employing three kinds of materials, aluminium, steel, and brass. To explore the impact of surface corrosion degree on electroosmosis, metal electrodes were pretreated with durations 0 h, 12 h, 24 h, and 36 h. After the pretreatment, corroded electrodes are used as anodes on electroosmosis. Water discharge, current, voltage potential were measured during the tests; water content was also tested at three points after the electroosmosis. The results showed that aluminium was better than steel in electroosmotic drainage while brass provided the worst dewatering performance. Surface corrosion did not influence the aluminium and steel on electroosmosis in marine sludge, but brass did. In the pretreatment of brass electrodes, corrosion rate had started to slow down at later periods, with the deterioration rate of dewatering reduced afterwards. As the results showed, it is not recommended to employ those easily deteriorated electrode materials from surface corrosion in practical engineering, such as brass; electrode material with higher electroosmosis exchange rate is recommended, such as aluminium.

  5. Tortoiseshell or Polymer? Spectroscopic Analysis to Redefine a Purported Tortoiseshell Box with Gold Decorations as a Plastic Box with Brass.

    Science.gov (United States)

    Pereira, António; Caldeira, Ana Teresa; Maduro, Belmira; Vandenabeele, Peter; Candeias, António

    2016-01-01

    possible biofilm composition and understand the role of microorganisms in the biodeterioration process. Using these methodologies, the box was correctly identified as being made of cellulose acetate plastic with brass decorations and the white film was identified as being composed mainly of polymer exudates, namely sulphonamides and triphenyl phosphate. © The Author(s) 2015.

  6. Dynamic measurement of mercury adsorption and oxidation on activated carbon in simulated cement kiln flue gas

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Jensen, Anker Degn; Windelin, Christian

    2012-01-01

    of the sulfite converter is short and typically within 2min. Dynamic mercury adsorption and oxidation tests on commercial activated carbons Darco Hg and HOK standard were performed at 150°C using simulated cement kiln gas and a fixed bed reactor system. It is shown that the converter and analyzer system...... are still under development and are investigated in this work. A commercial red brass converter was tested at 180°C and it was found that the red brass chips work in nitrogen atmosphere only, but do not work properly under simulated cement kiln flue gas conditions. Test of the red brass converter using only...... elemental mercury shows that when HCl is present with either SO2 or NOx the mercury measurement after the converter is unstable and lower than the elemental mercury inlet level. The conclusion is that red brass chips cannot fully reduce oxidized mercury to elemental mercury when simulated cement kiln gas...

  7. The Corrosion Inhibition Characteristics of Sodium Nitrite Using an On-line Corrosion Rate Measurement System

    International Nuclear Information System (INIS)

    Park, Mal-Yong; Kang, Dae-Jin; Moon, Jeon-Soo

    2015-01-01

    An on-line corrosion rate measurement system was developed using a personal computer, a data acquisition board and program, and a 2-electrode corrosion probe. Reliability of the developed system was confirmed with through comparison test. With this system, the effect of sodium nitrite (NaNO 2 ) as a corrosion inhibitor were studied on iron and aluminum brass that were immersed in sodium chloride (NaCl) solution. Corrosion rate was measured based on the linear polarization resistance method. The corrosion rates of aluminum brass and iron in 1% NaCl solutions were measured to be 0.290 mm per year (mmpy) and 0.2134 mmpy, respectively. With the addition of 200 ppm of NO 2 - , the corrosion rates decreased to 0.0470 mmpy and 0.0254 mmpy. The addition of NO 2 - caused a decrease in corrosion rates of both aluminum brass and iron, yet the NO 2 - acted as a more effective corrosion inhibitor for iron. than aluminum brass

  8. APPLICATION OF THE X-RAY STRUCTURE ANALYSIS FOR IMPROVEMENT OF TECHNOLOGICAL PROCES- SES OF WIRE PRODUCTION AT BMZ

    Directory of Open Access Journals (Sweden)

    D. V. Kuznetsov

    2012-01-01

    Full Text Available The X-ray diffraction methods of qualitative and quantative analysis of phase composition of the brass coating, scale on the surface of brass wire, rod, patented wire, methods of determining the characteristics of the microstrains the lattice ferritic matrix pearlitic high-carbon steel, are explored.

  9. 29 CFR 1910.111 - Storage and handling of anhydrous ammonia.

    Science.gov (United States)

    2010-07-01

    ... threaded. Threaded connections shall not be back-welded. Brass, copper, or galvanized steel pipe shall not be used. (v) Tubing made of brass, copper, or other material subject to attack by ammonia shall not... shall be provided against container flotation wherever sufficiently high flood water might occur. (vii...

  10. Tribological characterization of TiN coatings prepared by magnetron sputtering

    Science.gov (United States)

    Makwana, Nishant S.; Chauhan, Kamlesh V.; Sonera, Akshay L.; Chauhan, Dharmesh B.; Dave, Divyeshkumar P.; Rawal, Sushant K.

    2018-05-01

    Titanium nitride (TiN) coating deposited on aluminium and brass pin substrates using RF reactive magnetron sputtering. The structural properties and surface morphology were characterized by X-ray diffraction (XRD), atomic force microscope (AFM) and field emission scanning electron microscope (FE-SEM). There was formation of (101) Ti2N, (110) TiN2 and (102) TiN0.30 peaks at 3.5Pa, 2Pa and 1.25Pa sputtering pressure respectively. The tribological properties of coating were inspected using pin on disc tribometer equipment. It was observed that TiN coated aluminium and brass pins demonstrated improved wear resistance than uncoated aluminium and brass pins.

  11. The difference between standing and sitting in 3 different seat inclinations on abdominal muscle activity and chest and abdominal expansion in woodwind and brass musicians

    Directory of Open Access Journals (Sweden)

    Bronwen Jane Ackermann

    2014-08-01

    Full Text Available Wind instrumentalists require a sophisticated functioning of their respiratory system to control their air stream, which provides the power for optimal musical performance. The air supply must be delivered into the instrument in a steady and controlled manner and with enough power by the action of the expiratory musculature to produce the desired level of sound at the correct pitch. It is suggested that playing posture may have an impact on the abdominal muscle activity controlling this expired air, but there is no research on musicians to support this theory. This study evaluated chest and abdominal expansion, via respiratory inductive plethysmography, as well as activation patterns of lower and upper abdominal musculature, using surface electromyography, during performance of a range of typical orchestral repertoire by 113 woodwind and brass players. Each of the five orchestral excerpts was played in one of four randomly allocated postures: standing; sitting flat; sitting inclined forwards; and sitting inclined backwards.Musicians showed a clear preference for playing in standing rather than sitting. In standing, the chest expansion range and maximum values were greater (p<0.01, while the abdominal expansion was less than in all sitting postures (p<0.01. Chest expansion patterns did not vary between the three sitting postures, while abdominal expansion was reduced in the forward inclined posture compared to the other sitting postures (p<0.05. There was no significant variation in abdominal muscle activation between the sitting postures, but the level of activation in sitting was only 2/3 of the significantly higher level observed in standing (p<0.01.This study has demonstrated significant differences in respiratory mechanics between sitting and standing postures in wind musicians during playing of typical orchestral repertoire. Further research is needed to clarify the complex respiratory mechanisms supporting musical performance.

  12. 77 FR 40897 - Notice of Intent to Repatriate Cultural Items: Gregg County Historical Museum, Longview, TX

    Science.gov (United States)

    2012-07-11

    ... and thereafter, six unassociated funerary objects were removed from burials at the C.D. Marsh site... piece of sheet brass, and 1 brass musket butt plate. The Millsey Williamson site dates to A.D. 1650-1800..., the Late-Historic Caddo period. Sometime between the mid-1950s and the mid-1960s, six unassociated...

  13. Passivation of Cu-Zn alloy on low carbon steel electrodeposited from a pyrophosphate medium

    Science.gov (United States)

    Yavuz, Abdulcabbar; Yakup Hacıibrahimoğlu, M.; Bedir, Metin

    2018-01-01

    The motivation of this study is to understand whether zinc-based alloy also has a passivation behaviour similar to zinc itself. Cu-Zn alloys were electrodeposited potentiostatically from a pyrophosphate medium on a carbon steel electrode and their corrosion behaviours were studied. Pt and carbon steel electrodes were used in order to examine the corrosion/passivation behaviour of bare Cu, bare Zn and Cu-Zn alloy coatings. The passivation behaviour of all brass-modified electrodes having Zn content between 10% and 100% was investigated. The growth potential affects the morphology and structure of crystals. The brass coatings are more porous than their pure components. The crystalline structure of Cu-Zn alloys can be obtained by changing the deposition potential. The zinc content in brass increases when the deposition voltage applied decreases. However, the growth potential and the ratio of zinc in brass do not affect the passivation behaviour of the resulting alloys. The coatings obtained by applying different growth potentials were immersed in tap water for 24 h to compare their corrosion behaviours with carbon steel having pitting formation.

  14. Contact area measurements on structured surfaces

    DEFF Research Database (Denmark)

    Kücükyildiz, Ömer Can; Jensen, Sebastian Hoppe Nesgaard; De Chiffre, Leonardo

    In connection with the use of brass specimens featuring structured surfaces in a tribology test, an algorithm was developed for automatic measurement of the contact area by optical means.......In connection with the use of brass specimens featuring structured surfaces in a tribology test, an algorithm was developed for automatic measurement of the contact area by optical means....

  15. Botanical Collections of Brass

    NARCIS (Netherlands)

    Brass, L.J.

    1966-01-01

    Earliest collections, made in southeastern parts of Queensland, were not numbered in sequence, and probably no duplicates were kept. Serious collecting began in 1919, when a start was made in sending specimens to C.T. White at the Queensland Herbarium.

  16. Induction brazing of complex joints

    DEFF Research Database (Denmark)

    Henningsen, Poul; Zhang, Wenqi; Bay, Niels

    2003-01-01

    , or if the hottest area is located outside the joint interface, a number of defects may appear: the braze metal may flow away from the joint, the flux may burn off, poor binding of the braze metal may appear or the braze metal may be overheated. Joint geometry as well as electro-magnetic properties of the work piece...... presents a combined numerical and experimental method for fast determination of appropriate coil geometry and position in induction brazing tube-to-plate joints of different ratios between tube and plate thickness and different combinations of the materials stainless steel, brass and copper. The method has...... proven to give successful results in brazing tube-plate joints of copper-brass, copper-stainless steel, stainless steel-brass, and stainless steel-stainless steel....

  17. In situ chemical state analysis of buried polymer/metal adhesive interface by hard X-ray photoelectron spectroscopy

    International Nuclear Information System (INIS)

    Ozawa, Kenichi; Kakubo, Takashi; Shimizu, Katsunori; Amino, Naoya; Mase, Kazuhiko; Ikenaga, Eiji; Nakamura, Tetsuya; Kinoshita, Toyohiko; Oji, Hiroshi

    2014-01-01

    Highlights: • Chemical state analysis of the buried rubber/brass interface is conducted by HAXPES. • Ultrathin rubber films are prepared on the brass surface by two methods. • A high density of Cu 2 S is found on the rubber side of the buried adhesive layer. • The chemical states of the buried and exposed interfaces are compared. - Abstract: Chemical state analysis of adhesive interfaces is important to understand an adhesion mechanism between two different materials. Although photoelectron spectroscopy (PES) is an ideal tool for such an analysis, the adhesive interfaces must be exposed to the surface because PES is essentially a surface sensitive technique. However, an in situ observation is possible by hard X-ray PES (HAXPES) owing to its large probing depth. In the present study, HAXPES is applied to investigate the adhesive interface between rubber and brass without exposing the interface. It is demonstrated that copper sulfides formed at the buried rubber/brass interface are distinguished from S-containing species in the rubber overlayer. The chemical state of the buried interface is compared with that of the “exposed” interface prepared by so-called a filter-paper method

  18. Deposition of corrosion products from dowels on human dental root surfaces measured with proton microprobe technique

    International Nuclear Information System (INIS)

    Brune, D.; Brunell, G.; Lindh, U.

    1982-01-01

    Distribution of copper, mercury and zinc on human teeth root surfaces adjacent to dowels of gold alloy or brass as well as dowels of brass in conjunction with an amalgam crown has been measured with a proton microprobe using PIXE techniques. Upper limits of the contents of gold and silver on the root surfaces were established. Pronounced concentration profiles of copper and zinc were observed on the root surfaces of teeth prepared with dowels of brass. The dowel of gold alloy revealed only zinc deposition. The major part of copper on the root surfaces is assumed to arise from corrosion of the dowels, and has been transported to the surface by diffusion through the dential tubuli. Zinc in the volume analysed is a constituent of dentin tissue as well as a corrosion product of the brass dowel. Part of the zinc level could also be ascribed to erosion of the zinc phosphate cement matrix. The volumes analysed were (25 x 25 x 25)μm 3 . The levels of copper, mercury and zinc on the tooth root surfaces attained values up to about 200, 20 and 600 ppm, respectively. (orig.)

  19. Deposition of corrosion products from dowels on human dental root surfaces measured with proton microprobe technique

    Science.gov (United States)

    Brune, D.; Brunell, G.; Lindh, U.

    1982-06-01

    Distribution of copper, mercury and zinc on human teeth root surfaces adjacent to dowels of gold alloy or brass as well as dowels of brass in conjunction with an amalgam crown has been measured with a proton microprobe using PIXE techniques. Upper limits of the contents of gold and silver on the root surfaces were established. Pronounced concentration profiles of copper and zinc were observed on the root surfaces of teeth prepared with dowels of brass. The dowel of gold alloy revealed only zinc deposition. The major part of copper on the root surfaces is assumed to arise from corrosion of the dowels, and has been transported to the surface by diffusion through the dential tubuli. Zinc in the volume analysed is a constituent of dentin tissue as well as a corrosion product of the brass dowel. Part of the zinc level could also be ascribed to erosion of the zinc phosphate cement matrix. The volumes analysed were (25×25×25)μm 3. The levels of copper, mercury and zinc on the tooth root surfaces attained values up to about 200, 20 and 600 ppm, respectively.

  20. Aplikasi Cetakan Permanen untuk Meningkatkan Produksi dan Kualitas Produk IKM Pengecoran Logam Kuningan di Ngawen, Sidokarto, Godean, Yogyakarta

    Directory of Open Access Journals (Sweden)

    Suyitno Suyitno

    2016-12-01

    Full Text Available Small and Medium Enterprises (SME brass foundry in Ngawen Sidokarto, District of Godean, Sleman, Yogyakarta mostly produced cow necklace accessories (klonthong and jathilan accessories (klinthing. Te industry and business management are arranged within the scope of family. Te products are relatively low in quality and its market share is limited and tend to be traditional. Tis condition is caused by the weak knowledge of the management and the method of casting metals and metal science. Brass casting methode, that was used at IKM partner, is casting with mold of sand or soil. Tis process requires the making process of sand molds, that is removed afer the brass solidify. For large quantities products, this process is inefcient and takes a long time. It would require a more efcient and faster method in the production process. Method of sand casting and ceramics have been used by SMEs cast brass in Yogyakarta, however it  has many disadvantages in terms of increased productivity and quality as well as the expansion of product applications. Te permanent mold casting of iron is a casting method which has many advantages over other methods, but the use for SMEs has not been applied in the SME of cast brass. Te permanen mold casting methods was introduced to SME partners. Tis replaces the sand mold materials and molding sand. It is expected the casting process is faster because the mold can be used for a large number of products. Te results show that the application of the technology results in products with precision and consistent in shape and size. Community Service of UGM with Appropriate Technology has also collaborated with  Industry and Trade service of Yogyakarta donation of production machinery for making permanent mold. It can be concluded that the application of permanen mold in the brass foundry industry improve the product precision and the speed of produsction.

  1. Experiences with electrochemical analysis of copper at the PPB-level in saline cooling water and in the water/steam cycle

    Energy Technology Data Exchange (ETDEWEB)

    Thomsen, K [I/S Nordjyllandsvaerket, Vodskov (Denmark)

    1996-12-01

    Determination of trace amounts of copper in saline cooling water and in process water by differential pulse anodic stripping voltammetry combined with an UV-photolysis pretreatment is described. Copper concentrations well below 1 {mu}g/L may be analysed with a precision in the order of 10% and a high degree of accuracy. The basic principles of the method are described together with three applications covering analysis of cooling and process water samples. The analysis method has been applied to document the adherence of environmental limits for the copper uptake of cooling water passing brass condensers, to monitor the formation of protective layers of iron oxides on the cooling water side of brass condensers, and to study the transport of copper in water/steam cycles with heat exchangers and condensers of brass materials. (au)

  2. Evaluation of the contact switch materials in high voltage power supply for generate of underwater shockwave by electrical discharge

    Directory of Open Access Journals (Sweden)

    K Higa

    2016-10-01

    Full Text Available We have developed the high voltage power-supply unit by Cockcroft-Walton circuit for ingenerate high pressure due to underwater shockwave by electrical discharge. This high voltage power supply has the problem of the metal contact switch operation that contact switch stop by melting and bonding due to electrical spark. We have studied the evaluation of materials of contact switch for the reducing electrical energy loss and the problem of contact switch operation. In this research, measurement of discharge voltage and high pressure due to underwater shockwave was carried out using the contact switch made of different materials as brass plate, brass-carbon plate-brass and carbon block. The contact switch made of carbon is effective to reduce energy loss and problem of contactor switch operation.

  3. Effect of the Heat Flux Density on the Evaporation Rate of a Distilled Water Drop

    Directory of Open Access Journals (Sweden)

    Ponomarev Konstantin

    2016-01-01

    Full Text Available This paper presents the experimental dependence of the evaporation rate of a nondeaerated distilled water drop from the heat flux density on the surfaces of non-ferrous metals (copper and brass. A drop was placed on a heated substrate by electronic dosing device. To obtain drop profile we use a shadow optical system; drop symmetry was controlled by a high-speed video camera. It was found that the evaporation rate of a drop on a copper substrate is greater than on a brass. The evaporation rate increases intensively with raising volume of a drop. Calculated values of the heat flux density and the corresponding evaporation rates are presented in this work. The evaporation rate is found to increase intensively on the brass substrate with raising the heat flux density.

  4. Effects of Si on the microstructure, ordering transformation and properties of the Cu60Zn40 alloy

    International Nuclear Information System (INIS)

    Doostmohammadi, Hamid; Moridshahi, Hamid

    2015-01-01

    Highlights: • A duplex brass (Cu 60 Zn 40 ) was developed by additions of Si. • Phase fractions in the microstructure were changed and β phase was increased. • Microstructural changes were discussed by electron to atom ratio. • Dilatometric showed that Si increased the ordering temperature of β to β′. • The developed lead-free brass alloy can find application in machining. - Abstract: Effects of small additions of Si to Cu 60 Zn 40 on the properties, microstructure and phase transformation were investigated. It was found that Si promotes the formation of β′ phase and the microstructure of the alloys was changed from duplex α + β′ to single phase β′ brass. Electron to atom ratio was calculated and it was concluded that increment in this ratio led to a decrease in stacking fault energy which had an important role in reduction of the grain size as well microstructural variations in this study. The dilatomeric analysis showed that Si increased the ordering temperature of Cu 60 Zn 40 alloy. Finally, based on the properties, the Cu–Zn 40 –Si alloys are predicted to have the potential of being an alternative for free cutting leaded brass

  5. Grain refinement of permanent mold cast copper base alloys. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sadayappan, M.; Thomson, J. P.; Elboujdaini, M.; Gu, G. Ping; Sahoo, M.

    2004-04-29

    Grain refinement behavior of copper alloys cast in permanent molds was investigated. This is one of the least studied subjects in copper alloy castings. Grain refinement is not widely practiced for leaded copper alloys cast in sand molds. Aluminum bronzes and high strength yellow brasses, cast in sand and permanent molds, were usually fine grained due to the presence of more than 2% iron. Grain refinement of the most common permanent mold casting alloys, leaded yellow brass and its lead-free replacement EnviroBrass III, is not universally accepted due to the perceived problem of hard spots in finished castings and for the same reason these alloys contain very low amounts of iron. The yellow brasses and Cu-Si alloys are gaining popularity in North America due to their low lead content and amenability for permanent mold casting. These alloys are prone to hot tearing in permanent mold casting. Grain refinement is one of the solutions for reducing this problem. However, to use this technique it is necessary to understand the mechanism of grain refinement and other issues involved in the process. The following issues were studied during this three year project funded by the US Department of Energy and the copper casting industry: (1) Effect of alloying additions on the grain size of Cu-Zn alloys and their interaction with grain refiners; (2) Effect of two grain refining elements, boron and zirconium, on the grain size of four copper alloys, yellow brass, EnviroBrass II, silicon brass and silicon bronze and the duration of their effect (fading); (3) Prediction of grain refinement using cooling curve analysis and use of this method as an on-line quality control tool; (4) Hard spot formation in yellow brass and EnviroBrass due to grain refinement; (5) Corrosion resistance of the grain refined alloys; (6) Transfer the technology to permanent mold casting foundries; It was found that alloying elements such as tin and zinc do not change the grain size of Cu-Zn alloys

  6. Induction Brazing

    DEFF Research Database (Denmark)

    Henningsen, Poul

    , or if the hottest area is located outside the joint interface, a number of defects may appear: the braze metal may flow away from the joint, the flux may burn off, poor binding of the braze metal may appear or the braze metal may be overheated. Joint geometry as well as electro-magnetic properties of the work piece...... presents a combined numerical and experimental method for determination of appropriate/optimiged coil geometry and position in induction brazing tube-to-plate joints of different ratios between tube and plate thickness and different combinations of the materials stainless steel, brass and copper....... The method has proven to give successful results in brazing tube-plate joints of copper-brass, copper-stainless steel, stainless steel-brass, and stainless steel-stainless steel. A new design of an adjustable flux concentrator for induction heating tube-to-plate joints is proposed and tested on a variety...

  7. Effect of sponge ball cleaning on removing vernacles in condenser tubes

    International Nuclear Information System (INIS)

    Mimura, Keisuke; Minamoto, Kenju; Kyohara, Shigeru

    1977-01-01

    Usually aluminum brass material is adopted for the condenser tubes in thermal and nuclear power stations today, and sea water is treated with chlorine for the purpose of smooth operation and maintenance, but recently, this treatment tends to be avoided in view of environment preservation. When the chlorine treatment is not carried out, vernacles and other marine living things adhere to the internal surfaces of condenser tubes, and the corrosion of the tubes and the lowering of heat transfer rate occur. In this study, sponge ball cleaning was selected as the method of mechanically removing the adhering living things in tubes. When the balls are used too frequently, the formation of protective film is hindered, and the corrosion of tubes is accelerated, therefore it is important to determine the optimal frequency. The model condenser test and the immersion test of aluminum brass and titanium tubes were carried out. The testing method, the operation record and the test results are reported. Vernacles are apt to adhere to titanium tubes rather than aluminum brass tubes, and in case of aluminum brass tubes, they adhere to those with iron hydroxide film rather than those as manufactured. Vernacles adhere more as the flow speed in tubes is lower and the number of larvae in water is more. It was confirmed that the sponge ball cleaning was extremely effective for removing vernacles. (Kako, I.)

  8. Effect of sponge ball cleaning on removing vernacles in condenser tubes

    Energy Technology Data Exchange (ETDEWEB)

    Mimura, K; Minamoto, K; Kyohara, S [Kobe Steel Ltd. (Japan)

    1977-01-01

    Usually aluminum brass material is adopted for the condenser tubes in thermal and nuclear power stations today, and sea water is treated with chlorine for the purpose of smooth operation and maintenance, but recently, this treatment tends to be avoided in view of environment preservation. When the chlorine treatment is not carried out, vernacles and other marine living things adhere to the internal surfaces of condenser tubes, and the corrosion of the tubes and the lowering of heat transfer rate occur. In this study, sponge ball cleaning was selected as the method of mechanically removing the adhering living things in tubes. When the balls are used too frequently, the formation of protective film is hindered, and the corrosion of tubes is accelerated, therefore it is important to determine the optimal frequency. The model condenser test and the immersion test of aluminum brass and titanium tubes were carried out. The testing method, the operation record and the test results are reported. Vernacles are apt to adhere to titanium tubes rather than aluminum brass tubes, and in case of aluminum brass tubes, they adhere to those with iron hydroxide film rather than those as manufactured. Vernacles adhere more as the flow speed in tubes is lower and the number of larvae in water is more. It was confirmed that the sponge ball cleaning was extremely effective for removing vernacles.

  9. Synthesis, characterization and corrosion inhibition efficiency of N-(4-(Morpholinomethyl Carbamoyl Phenyl Furan-2-Carboxamide

    Directory of Open Access Journals (Sweden)

    N. Zulfareen

    2016-01-01

    Full Text Available A mannich base namely N-(4-(Morpholinomethyl Carbamoyl Phenyl Furan-2-Carboxamide (MFC was synthesized and characterized by FT-IR, 1H NMR, and 13C NMR. The molecular weight of MFC was confirmed by LC-MS. The inhibition effect of MFC on brass in 1 M HCl medium has been investigated by weight loss measurement, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS and cyclic voltametry (CV. Thermodynamic parameters such as free energy, entropy and enthalpy were calculated to describe the mechanism of corrosion inhibitor. The inhibition efficiency of MFC increases with increase in concentration and temperature ranges from 30 °C to 60 °C. Polarization measurements indicated that MFC acts as a mixed type corrosion inhibitor. AC impedance indicates that Rct value increases with increase in the concentration of inhibitor. CV reveals that the oxidation of the copper is controlled by the addition of inhibitor on the brass metal. Surface analysis using scanning electron microscope (SEM shows a significant morphological improvement on the brass surface with the addition of the inhibitor. The adsorption of MFC on brass obeys Langmuir adsorption isotherm. The molecular structure of MFC was distorted to quantum chemical indices using density functional theory (DFT which indicates that the inhibition efficiency of MFC is closely related to quantum parameters.

  10. Eletrodissolução de ligas de latão empregando sistemas de análise em fluxo para a determinação de cobre, zinco e chumbo por ICP-AES Electrodissolution of brasses alloys employing flow systems for determination of copper, zinc and lead by ICP-AES

    Directory of Open Access Journals (Sweden)

    Ana Paula G. Gervasio

    1999-09-01

    Full Text Available An on-line electrodissolution procedure implemented in a flow injection system for determination of copper, zinc and lead in brasses alloys by ICP-AES is described. Sample dissolution procedure was carried out by using a PTFE chamber and a DC power supply with constant current. Solid sample was attached to chamber as anode and a gold tubing coupled in the chamber was used as cathode. An electrolytic solution flowing through the gold tubing closed the electric circuit with sample, in order to provide condition for electric dissolution when the DC power supply was switched on. The best results were achieved by using a 1.5 mol l-1 nitric acid solution as electrolyte and a 2.5 A current intensity. The procedure presented a good performance characterized by a relative standard deviation better than < 5% (n=5 and a sample throughput of 180 determinations per hour for Cu, Zn and Pb. Results were in agreement with those obtained by conventional acid dissolution (99% confidence level.

  11. Pitfalls of tungsten multileaf collimator in proton beam therapy

    Energy Technology Data Exchange (ETDEWEB)

    Moskvin, Vadim; Cheng, Chee-Wai; Das, Indra J. [Department of Radiation Oncology, Indiana University School of Medicine, Indianapolis, Indiana 46202 (United States) and Indiana University Health Proton Therapy Center (Formerly Midwest Proton Radiotherapy Institute), Bloomington, Indiana 47408 (United States)

    2011-12-15

    Purpose: Particle beam therapy is associated with significant startup and operational cost. Multileaf collimator (MLC) provides an attractive option to improve the efficiency and reduce the treatment cost. A direct transfer of the MLC technology from external beam radiation therapy is intuitively straightforward to proton therapy. However, activation, neutron production, and the associated secondary cancer risk in proton beam should be an important consideration which is evaluated. Methods: Monte Carlo simulation with FLUKA particle transport code was applied in this study for a number of treatment models. The authors have performed a detailed study of the neutron generation, ambient dose equivalent [H*(10)], and activation of a typical tungsten MLC and compared with those obtained from a brass aperture used in a typical proton therapy system. Brass aperture and tungsten MLC were modeled by absorber blocks in this study, representing worst-case scenario of a fully closed collimator. Results: With a tungsten MLC, the secondary neutron dose to the patient is at least 1.5 times higher than that from a brass aperture. The H*(10) from a tungsten MLC at 10 cm downstream is about 22.3 mSv/Gy delivered to water phantom by noncollimated 200 MeV beam of 20 cm diameter compared to 14 mSv/Gy for the brass aperture. For a 30-fraction treatment course, the activity per unit volume in brass aperture reaches 5.3 x 10{sup 4} Bq cm{sup -3} at the end of the last treatment. The activity in brass decreases by a factor of 380 after 24 h, additional 6.2 times after 40 days of cooling, and is reduced to background level after 1 yr. Initial activity in tungsten after 30 days of treating 30 patients per day is about 3.4 times higher than in brass that decreases only by a factor of 2 after 40 days and accumulates to 1.2 x 10{sup 6} Bq cm{sup -3} after a full year of operation. The daily utilization of the MLC leads to buildup of activity with time. The overall activity continues to increase

  12. Investigation of effective forensic cleaning methods for bullet and cartridge case samples

    Science.gov (United States)

    Shuherk, Cassie Marie

    Bullet and cartridge case evidence may potentially link weapons and crimes through the comparison of toolmark patterns. This analysis relies on the clarity of the toolmarks and the ability of the examiner to identify patterns on the evidence. These patterns may be distorted by debris such as soil, blood, cyanoacrylate, and construction materials. Despite the potential importance of bullet and cartridge case evidence, few investigations of proper cleaning methods have been conducted. The present study was designed to examine the effects of various cleaning solutions and application methods on copper and brass bullets and cartridge cases. Additionally, this research investigated the efficacy of these cleaning protocols on the common evidence contaminants blood and cyanoacrylate. No cleaning method was found to be universally effective on both contaminant types and nondestructive to the metal surface. Ultrasonication was the most efficient application method employed when used in conjunction with an appropriate cleaning solution. Acetone proved to be safe and successful at removing heavy cyanoacrylate deposits from brass cartridge cases without damaging the metal. Although sulfuric acid removed most of the cyanoacrylate from the brass cartridge case, ultrasonication of the fumed cartridge cases in sulfuric acid caused the nickel-plated primer caps to turn black. Additionally, etching occurred when sulfuric acid was allowed to dry on the cartridge case surface. Citric acid, salt-flour-vinegar paste, TergazymeRTM, and water did not effectively remove the cyanoacrylate from the cartridge cases, but the solutions were safe to use on the brass and sometimes resulted in a shinier surface. Regardless of the cleaning method employed, the bloodstained bullets retained most or all of the underlying brown tarnish. Ultrasonication with sulfuric acid was successful at removing some blood-initiated tarnishing; however, the removal of residues was not complete, making it difficult

  13. Search for prompt neutrinos and new penetrating particles from 28-GeV proton-nucleus collisions

    International Nuclear Information System (INIS)

    Soukas, A.; Wanderer, P.; Weng, W.; Bregman, M.; Claudson, M.; LoSecco, J.; Rivkin, L.; Roeder, J.; Russek, S.; Sulak, L.; Timbie, P.; Yudis, M.; Gabriel, T.A.; Galik, R.S.; Horstkotte, J.; Knauer, J.; Levine, M.; Williams, H.H.

    1980-01-01

    This paper describes a search for weakly or semistrongly interacting particles produced in the collision of 4.9 x 10 18 28-GeV protons with a thick copper and brass beam stop. 104 events have been observed; their characteristics are similar to those produced by neutrinos arising from proton interactions in a 15-cm-thick brass target. However, compared to the number expected, an excess of 48 events is found with uncertainties of +- 10 (statistical) and +- 12 (systematic). At most ten events (68% confidence level) are attributable to beam losses

  14. Process Optimization of EDM Cutting Process on Tool Steel using Zinc Coated Electrode

    Directory of Open Access Journals (Sweden)

    Hanizam H.

    2017-01-01

    Full Text Available In WEDM machining process, surface finish quality depends on intensity and duration of spark plasma. Electrode wire diameter has significant effect on the spark intensity and yet the studies on this matter still less. Therefore, the main objectives of this studies are to compare the different diameters of zinc coated and uncoated brass electrode on H13 tool steel surface roughness. The experiments were conducted on Sodick VZ300L WEDM and work piece material of tool steel AISI H13 block. Electrode of zinc coated brass with diameters of 0.1 mm, 0.2 mm, 0.25 mm and uncoated brass 0.2 mm were used. The surface roughness of cutting was measured using the SUR-FTEST SJ-410 Mitutoyo, surface roughness tester. The results suggest that better surface roughness quality can be achieved through smaller electrode wire diameter. The zinc coated improves flushing ability and sparks intensity resulting in better surface finish of H13 tool steel. New alloys and coating materials shall be experimented to optimized the process further.

  15. Effect of water temperature on the fit of provisional crown margins during polymerization: An in vitro study

    Directory of Open Access Journals (Sweden)

    Vivekanandan Ramkumar

    2012-01-01

    Full Text Available Aim: To evaluate the effect of water temperature on the marginal fit of bis-acrylic composite provisional crown during resin polymerization. Materials and Methods: Precisely machined 10 brass master dies were designed to simulate molar teeth. Five brass dies were selected and precisely machined to simulate all ceramic crown preparation. An acrylic jaw replica was made in which brass dies were arranged equidistant from each other. A custom-made metallic tray was fabricated on the acrylic jaw replica to make polyvinyl siloxane impression matrix. Bis-acrylic composite resin provisional crowns were made using polyvinyl siloxane impression matrix. Provisional crowns were polymerized at room temperature (Group I direct technique, on dental stone cast; Group I indirect technique crowns and at different water temperatures (Group II direct technique crowns. The vertical marginal gap between all the provisional crown margins and the finish line of brass dies was measured using a Research Stereomicroscope System. Results: The results were statistically analyzed using one-way analysis of variance (ANOVA test and Newman-Keul′s test. The results showed that crowns polymerized in 20°C and 30°C water had marginal gap approximately three times smaller than those polymerized in 30°C air, due to the reduced polymerization shrinkage. Conclusion: This study shows that crowns polymerized in 20°C and 30°C water had mean vertical marginal gap approximately three times smaller than those polymerized in 30°C air. It was approximately closer to that of crowns fabricated by indirect technique. Warmer water also supposedly hastens polymerization.

  16. Effect of water temperature on the fit of provisional crown margins during polymerization: An in vitro study.

    Science.gov (United States)

    Ramkumar, Vivekanandan; Sangeetha, Arunachalam; Kumar, Vinaya

    2012-08-01

    To evaluate the effect of water temperature on the marginal fit of bis-acrylic composite provisional crown during resin polymerization. Precisely machined 10 brass master dies were designed to simulate molar teeth. Five brass dies were selected and precisely machined to simulate all ceramic crown preparation. An acrylic jaw replica was made in which brass dies were arranged equidistant from each other. A custom-made metallic tray was fabricated on the acrylic jaw replica to make polyvinyl siloxane impression matrix. Bis-acrylic composite resin provisional crowns were made using polyvinyl siloxane impression matrix. Provisional crowns were polymerized at room temperature (Group I direct technique, on dental stone cast; Group I indirect technique crowns) and at different water temperatures (Group II direct technique crowns). The vertical marginal gap between all the provisional crown margins and the finish line of brass dies was measured using a Research Stereomicroscope System. The results were statistically analyzed using one-way analysis of variance (ANOVA) test and Newman-Keul's test. The results showed that crowns polymerized in 20°C and 30°C water had marginal gap approximately three times smaller than those polymerized in 30°C air, due to the reduced polymerization shrinkage. This study shows that crowns polymerized in 20°C and 30°C water had mean vertical marginal gap approximately three times smaller than those polymerized in 30°C air. It was approximately closer to that of crowns fabricated by indirect technique. Warmer water also supposedly hastens polymerization.

  17. Asymmetric acoustic transmission in multiple frequency bands

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Hong-xiang, E-mail: jsdxshx@ujs.edu.cn [Research Center of Fluid Machinery Engineering and Technology, Jiangsu University, Zhenjiang 212013 (China); Laboratory of Modern Acoustics, Institute of Acoustics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093 (China); State Key Laboratory of Acoustics, Institute of Acoustics, Chinese Academy of Sciences, Beijing 100190 (China); Yuan, Shou-qi, E-mail: Shouqiy@ujs.edu.cn [Research Center of Fluid Machinery Engineering and Technology, Jiangsu University, Zhenjiang 212013 (China); Zhang, Shu-yi [Laboratory of Modern Acoustics, Institute of Acoustics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093 (China)

    2015-11-23

    We report both experimentally and numerically that the multi-band device of the asymmetric acoustic transmission is realized by placing two periodic gratings with different periods on both sides of two brass plates immersed in water. The asymmetric acoustic transmission can exist in four frequency bands below 1500 kHz, which arises from the interaction between various diffractions from the two gratings and Lamb modes in the brass plates immersed in water. The results indicate that the device has the advantages of multiple band, broader bandwidth, and simpler structure. Our finding should have great potential applications in ultrasonic devices.

  18. Asymmetric acoustic transmission in multiple frequency bands

    International Nuclear Information System (INIS)

    Sun, Hong-xiang; Yuan, Shou-qi; Zhang, Shu-yi

    2015-01-01

    We report both experimentally and numerically that the multi-band device of the asymmetric acoustic transmission is realized by placing two periodic gratings with different periods on both sides of two brass plates immersed in water. The asymmetric acoustic transmission can exist in four frequency bands below 1500 kHz, which arises from the interaction between various diffractions from the two gratings and Lamb modes in the brass plates immersed in water. The results indicate that the device has the advantages of multiple band, broader bandwidth, and simpler structure. Our finding should have great potential applications in ultrasonic devices

  19. Pro Forma Registration of Companies

    DEFF Research Database (Denmark)

    Werlauff, Erik

    2010-01-01

    The article analyses the view taken by Community law on companies' pro forma registration in another EU or EEA country. Community law recognises pro forma registration under company law, i.e. a brass plate is sufficient, whereas it does not recognise pro forma registration under tax law, i.......e. a brass plate is not sufficient. The article provides reasons for the differential treatment of the two contexts and clarifies the difference on the basis of the Hubbard criterion, in which it was ruled that the effectiveness of Community law cannot vary according to the various branches of national law....

  20. Evolution of the feedback from experience on degradations of French nuclear power plants condensers and foreseen solutions

    Energy Technology Data Exchange (ETDEWEB)

    Mayos, M.; Chanel, F.; Copin, E.; Carlier, L. [EDF/DIN/CEIDRE, Saint-Denis (France); Coquio, N.; Garbay, E. [EDF/DIN/CEIDRE, Avoine (France); Bastian, C. [EDF/DPN/UNIE, Saint-Denis (France)

    2011-07-01

    The materials constituting the condenser tubes of French nuclear power plants display a great diversity and are subject to different degradations, known from the operational feedback from experience. Copper alloys (mainly brass), which were bound to disappear in renovated condensers, are still significantly present, due to their unique bacteriostatic ability. Brass tubes lifetime is still governed in general by steady abrasion, as evaluated by eddy current nondestructive testing. However, an atypical NDE (non-destructive evaluation) behavior has led to spot a new damage: localized under-deposit pitting corrosion on the raw water side, caused by the particular quality of water chemistry and heavy scaling of the tube surface. This damage is likely to overcome steady abrasion for tube life prediction. Prevention includes a tighter look at NDE indications and improved descaling solutions (chemical or mechanical). Other specific damages have been reported from operation feedback: the main one was accidental stress corrosion cracking, which has occurred on some recently renovated brass condenser tube bundles. Thanks to a metallurgical and mechanical study, its cause was found in the manufacturing process. This experience has resulted in tightened specifications for brass tubes manufacturing. Stainless steel and titanium still appear more damage-resistant and represent a safe solution when no microorganism issue is present. The degradation feedback, confirmed by NDE inspections, is very low in French power plants. However, titanium hydriding still represents an issue when cathodic protection is present. Furthermore, some other damages have been reported on titanium, like isolated steam erosion. Vibration fatigue damage has been observed on stainless steel tubes, but it is more in relationship with the condenser design than with the material itself. (authors)

  1. Improvement of reliability of heater and condenser

    International Nuclear Information System (INIS)

    Yamagishi, Hiroki

    1988-01-01

    Recently, the diversification of the operation modes of power plants has advanced as well as daily start and stop and weekly start and stop operations, as the result, the needs for the reliability improvement of various heat exchangers around steam turbines heighten. In newly constructed plants, the design to meet this demand is carried out, but also in existing platns, the application of the latest technology is investigated. As for the reliability of condensers, aluminum brass cooling tubes have been used by doing the optimal maintenance and taking the measures against deposit attack. In the case of requiring high reliability, the examples of adopting titanium cooling tubes increased. The technology of titanium tube condensers, completely assembled condensers, the replacement of existing brass tubes with titanium tubes and so on are discussed. In the case of feed heaters, the deterioration phenomena due to the lapse of long years, such as the attack of steel tube inlet, the drain attack on the external surfaces of steel tubes, the ammonia attack of aluminum brass tubes and the adhesion of scale to heaters, are explained, and the countermeasures are shown. (Kako, I.)

  2. SIMS depth profiling of rubber-tyre cord bonding layers prepared using 64Zn depleted ZnO

    International Nuclear Information System (INIS)

    Fulton, W.S.; Sykes, D.E.; Smith, G.C.

    2006-01-01

    Zinc oxide and copper/zinc sulphide layers are formed during vulcanisation and moulding of rubber to brass-coated steel tyre reinforcing cords. Previous studies have described how zinc diffuses through the rubber-brass interface to form zinc sulphide, and combines with oxygen to create zinc oxide during dezincification. The zinc is usually assumed to originate in the brass of the tyre cord, however, zinc oxide is also present in the rubber formulation. We reveal how zinc from these sources is distributed within the interfacial bonding layers, before and after heat and humidity ageing. Zinc oxide produced using 64 Zn-isotope depleted zinc was mixed in the rubber formulation in place of the natural ZnO and the zinc isotope ratios within the interfacial layers were followed by secondary ion mass spectroscopy (SIMS) depth profiling. Variations in the relative ratios of the zinc isotopes during depth profiling were measured for unaged, heat-aged and humidity-aged wire samples and in each case a relatively large proportion of the zinc incorporated into the interfacial layer as zinc sulphide was shown to have originated from ZnO in the rubber compound

  3. Study the effect of nitrogen flow rate on tribological properties of tantalum nitride based coatings

    Science.gov (United States)

    Chauhan, Dharmesh B.; Chauhan, Kamlesh V.; Sonera, Akshay L.; Makwana, Nishant S.; Dave, Divyeshkumar P.; Rawal, Sushant K.

    2018-05-01

    Tantalum Nitride (TaN) based coatings are well-known for their high temperature stability and chemical inertness. We have studied the effect of nitrogen flow rate variation on the structural and tribological properties of TaN based coating deposited by RF magnetron sputtering process. The nitrogen flow rate was varied from 5 to 30 sccm. X-ray diffractometer (XRD) and Atomic Force Microscopy (AFM) were used to determine structure and surface topography of coating. Pin on disc tribometer was used to determine tribological properties of coating. TaN coated brass and mild steel substrates shows higher wear resistance compared to uncoated substrates of brass and mild steel.

  4. A non-destructive synchrotron X-ray study of the metallurgy and manufacturing processes of Eastern and Western astrolabes in the Adler Planetarium collection

    Science.gov (United States)

    Newbury, Brian Dale

    The astrolabe collection of the Adler Planetarium and History of Astronomy Museum, Chicago, IL, was examined using non-destructive synchrotron based high-energy X-ray techniques including diffraction, fluorescence, and radiography to determine the metallurgy, microstructure, and metal forming processes used in astrolabe construction. All high-energy X-ray measurements were performed at the Advanced Photon Source (APS) synchrotron of Argonne National Laboratory, Argonne, IL. Astrolabes from the collection were selected to represent all major astrolabe production centers possible and time periods. It was found that all European astrolabes were manufactured of traditional cementation brass by hand worked metal forming processes consistent with technology in the literature. Of the Islamic astrolabes examined, all seven from Lahore in current-day Pakistan exhibited advanced brass alloys not typical of alloys discussed in the literature. It was found that these alloys were selected for their specific hot working properties, allowing the Lahore metalworkers to more efficiently make brass sheet from which to make astrolabe components. In addition, the alloy required a fundamental change in the brass foundry process, indicating advanced Zn metal production techniques. It was found that analysis by high energy X-rays from the APS was essential to produce data on the chemistry and microstructure from the interior of the astrolabe components in a non-destructive manner. Many astrolabe components had undergone surface dezincification due to heavy annealing during manufacturing, causing the Zn composition measured by the surface sensitive fluorescence technique to be lower than the true bulk alloy Zn composition. This would have been impossible to quantify non-destructively without the high-energy diffraction capability of the APS. The results of this study have proven the effectiveness of the synchrotron as a viable non-destructive analysis technique for examining cultural

  5. Distribution of Cr atoms in the surface zone of Fe-rich Fe–Cr alloys quenched into various media: Mössbauer spectroscopic study

    International Nuclear Information System (INIS)

    Dubiel, Stanisław M.; Cieślak, Jakub; Żukrowski, Jan

    2015-01-01

    Graphical abstract: Chromium depletion, Δx = x_k − x, in Fe_1_0_0_−_xCr_x (x = 2.2, 3.9, 6.4, 8.5, 10.25, 10.75, 14.9, 15.15) alloys quenched into LN (left panel) and those quenched onto brass (right panel) as found from CEMS (pre surface zone) and TRANS (bulk) Mössbauer spectra (x_k – Cr content in the pre surface or bulk as estimated from the average hyperfine field found for the quenched samples). - Highlights: • Effect of quenching media on Cr atom distribution in Fe–Cr alloys was determined. • Significant differences between bulk and pre surface zone were revealed. • Quenching into water and LH resulted in surface oxidation of samples. • Samples quenched onto a block of brass were not oxidized. - Abstract: Effect of a quenching medium (water, liquid nitrogen and block of brass) on a distribution of Cr atoms in the surface zone of Fe_1_0_0_−_xCr_x (x ≤ 19) alloys was studied with the Mössbauer spectroscopy. The distribution of Cr atoms was expressed in terms of the Cowley–Warren short-range order (SRO) parameters: 〈α_1〉 for the first neighbor-shell, 〈α_2〉 for the second neighbor-shell and 〈α_1_2〉 for both neighbor-shells. It was revealed that none of the quenching media resulted in a random distribution of atoms, yet the degree of randomness was the highest for the samples quenched onto the block of brass. The quenching into water and liquid nitrogen caused a partial oxidation of samples’ surface accompanied by a chromium depletion of the bulk. Quantitative analysis of various phases in the studied samples both in their bulk as well as in pre surface zones was carried out.

  6. Behavior of Fatigue Crack Tip Opening in Air and Corrosive Atmosphere

    Science.gov (United States)

    Hayashi, Morihito; Toeda, Kazunori

    In the study, a formula for predicting fatigue crack tip opening displacement is deduced firstly. And then, due to comparing actual crack growth rate with the deduced formula, the crack tip configuration factor is defined to figure out the crack tip opening configuration that is useful to clarify the behavior of fatigue crack tip formation apparently. Applying the concept, the crack growth of 7/3 brass and 6/4 brass is predicted from the formula, by replacing material properties such as plastic flow resistance, Young modulus, the Poisson ratio, and fatigue toughness, and fatigue test conditions such as the stress intensity factor range, the load ratio, and cycle frequency. Furthermore, the theoretically expected results are verified with the fatigue tests which were carried out on CT specimens under different load conditions of load ratio, cycle frequency, and cyclic peak load, in different environments of air or corrosive ammonia atmosphere, for various brasses. And by comparing and discussing the calculated crack growth rate with attained experimental results, the apparent configuration factor at the crack tip is determined. And through the attained factor which changes along with crack growth, the behaviors of fatigue crack tip formation under different test conditions have been found out.

  7. Estudio de corrosión galvánica en pares latón/acero inoxidable y latón/fundición de hierro

    Directory of Open Access Journals (Sweden)

    Ohanian, M.

    2011-08-01

    Full Text Available Corrosion attack in heat exchanger systems is a topic of main interest for the maintenance in each industrial plant. These are multigalvanic systems with particular geometric and fluidodynamic complexity. Corrosive damages include zinc selective dealeation in copper alloys. In order to explain zinc dealeation attack, this paper deals with laboratory scale testing, characterization and interactions between two copper and zinc alloys (Yellow brass –UNS C268– and Admiralty brass –UNS C443– compared to AISI 316 stainless steel and cast iron. The tests were performed at 20 °C in 1.5 % NaCl and 1.5 % Na2SO4 solutions, pH 8 and each material was characterized by potentiodynamic sweeps. The couples are analyzed by studying transient galvanic currents. We conclude about the cause of the analyzed pathology, brass protection potential ranges and its coupling compatibility with other metals.

    El ataque por corrosión en los sistemas intercambiadores de calor constituye un problema para el mantenimiento de cualquier planta industrial. Se trata de sistemas multigalvánicos con particular complejidad geométrica y fluidodinámica. Las patologías corrosivas incluyen el fenómeno de dealeación selectiva de cinc en las aleaciones de cobre. A fin de explicar un caso particular de ataque por decinficación (deterioro en placa de intercambiador de calor de tubos de inoxidable, el presente trabajo aborda en ensayos a escala de laboratorio, la caracterización e interacciones entre dos aleaciones de cobre y cinc, (Yellow brass –UNS C268– y Admiralty brass –UNS C443–, respecto a acero inoxidable AISI 316 y fundición gris de hierro. Los ensayos se realizan a 20 °C en disoluciones de NaCl 1,5 % y Na2SO4 1,5 % y pH 8. Se caracterizan electroquímicamente las aleaciones y materiales involucrados mediante barridos potenciodinámicos. Los pares galvánicos formados se analizan mediante el

  8. [(123)I]FP-CIT ENC-DAT normal database

    DEFF Research Database (Denmark)

    Tossici-Bolt, Livia; Dickson, John C; Sera, Terez

    2017-01-01

    quantifications methods, BRASS and Southampton, and explores the performance of the striatal phantom calibration in their harmonisation. RESULTS: BRASS and Southampton databases comprising 123 ENC-DAT subjects, from gamma cameras with parallel collimators, were reconstructed using filtered back projection (FBP......) and iterative reconstruction OSEM without corrections (IRNC) and compared against the recommended OSEM with corrections for attenuation and scatter and septal penetration (ACSC), before and after applying phantom calibration. Differences between databases were quantified using the percentage difference......-camera variability (-0.2%, p = 0.44). CONCLUSIONS: The ENC-DAT reference values are significantly dependent on the reconstruction and quantification methods and phantom calibration, while reducing the major part of their differences, is unable to fully harmonize them. Clinical use of any normal database, therefore...

  9. [(123)I]FP-CIT ENC-DAT normal database

    DEFF Research Database (Denmark)

    Tossici-Bolt, Livia; Dickson, John C; Sera, Terez

    2017-01-01

    BACKGROUND: [(123)I]FP-CIT is a well-established radiotracer for the diagnosis of dopaminergic degenerative disorders. The European Normal Control Database of DaTSCAN (ENC-DAT) of healthy controls has provided age and gender-specific reference values for the [(123)I]FP-CIT specific binding ratio...... quantifications methods, BRASS and Southampton, and explores the performance of the striatal phantom calibration in their harmonisation. RESULTS: BRASS and Southampton databases comprising 123 ENC-DAT subjects, from gamma cameras with parallel collimators, were reconstructed using filtered back projection (FBP......) and iterative reconstruction OSEM without corrections (IRNC) and compared against the recommended OSEM with corrections for attenuation and scatter and septal penetration (ACSC), before and after applying phantom calibration. Differences between databases were quantified using the percentage difference...

  10. Propagation speed of gamma radiation in brass

    International Nuclear Information System (INIS)

    Cavalcante, Jose T.P.D.; Silva, Paulo R.J.; Saitovich, Henrique

    2009-01-01

    The propagation speed (PS) of visible light -represented by a short frequency range in the large frame of electromagnetic radiations (ER) frequencies- in air was measured during the last century, using a great deal of different methods, with high precision results being achieved. Presently, a well accepted value, with very small uncertainty, is c= 299,792.458 Km/s) (c reporting to the Latin word celeritas: 'speed swiftness'). When propagating in denser material media (MM), such value is always lower when compared to the air value, with the propagating MM density playing an important role. Until present, such studies focusing propagation speeds, refractive indexes, dispersions were specially related to visible light, or to ER in wavelengths ranges dose to it, and with a transparent MM. A first incursion in this subject dealing with γ-rays was performed using an electronic coincidence counting system, when the value of it's PS was measured in air, C γ(air) 298,300.15 Km/s; a method that went on with later electronic improvements. always in air. To perform such measurements the availability of a γ-radiation source in which two γ-rays are emitted simultaneously in opposite directions -as already used as well as applied in the present case- turns out to be essential to the feasibility of the experiment, as far as no reflection techniques could be used. Such a suitable source was the positron emitter 22 Na placed in a thin wall metal container in which the positrons are stopped and annihilated when reacting with the medium electrons, in such way originating -as it is very well established from momentum/energy conservation laws - two gamma-rays, energy 511 KeV each, both emitted simultaneously in opposite directions. In all the previous experiments were used photomultiplier detectors coupled to NaI(Tl) crystal scintillators, which have a good energy resolution but a deficient time resolution for such purposes. Presently, as an innovative improvement, were used BaF 2 and Cs F crystal scintillators which display a much better time resolution. Incidentally, the use of γ-rays would a 110 W a determination of ER propagation values in non-transparent MM, non transparent for visible light; and in such a way better sketching their structural -or of other nature- properties that may interfere with this propagation. (author)

  11. Eesti viib Rostrumile kolm teost

    Index Scriptorium Estoniae

    2001-01-01

    11. juunil algab Pariisis rahvusvaheline heliloojate Rostrum, millel osalevad ka kolme noore eesti helilooja teosed: Mirjam Tally :Swinburne" Hasso Krulli luulele, Tõnis Kaumanni "Long Play" brass ansamblile ja Helena Tulve "Traces"

  12. 78 FR 14183 - Import Restrictions Imposed on Certain Archaeological Material From Belize

    Science.gov (United States)

    2013-03-05

    ... considerably, and may include lids, tripod feet, or other supplementary decoration. A. Common Vessels 1. Vases.... III. Metal--Objects in copper, gold, silver, brass, or other. Beaten or cast into shape, often...

  13. Mapping the Galvanic Corrosion of Three Coupled Metal Alloys Using Coupled Multielectrode Array: Influence of Chloride Ion Concentration

    Directory of Open Access Journals (Sweden)

    Hong Ju

    2018-04-01

    Full Text Available The galvanic corrosion behavior of three metal alloys commonly used in water desalination plants was investigated using coupled multielectrode arrays consisting of aluminum-brass (HAl77-2, titanium alloy (TA2, and 316L stainless steel (316L SS. The three electrode types were coupled galvanically and arranged in different geometric configurations. Their corrosion behavior was characterized as a function of the chloride concentration. The potential and current distributions of the three-electrode coupling systems display electrochemical inhomogeneity. Generally, the aluminum-brass wires are anodic versus the titanium alloy and stainless steel. The titanium alloy acts as a primary cathode, and the 316L SS acts as a secondary cathode. The corrosion rate of aluminum-brass depends on the concentration of chloride ion, with a maximum corrosion rate at a chloride concentration of 2.3 wt %. In terms of geometrical arrangements, when the anodic HAl77-2 wires are located on the edge and are connected to the 316L SS wires in the coupling system, the main anodic area enlarges, especially in the area adjacent to the 316L SS wires. When the HAl77-2 wires are located between (in the middle of the two other types of wires, the corrosion rates are higher than the corrosion rates observed from the other two geometrical arrangements.

  14. Degradation of automotive materials in palm biodiesel

    International Nuclear Information System (INIS)

    Fazal, M.A.; Haseeb, A.S.M.A.; Masjuki, H.H.

    2012-01-01

    As compared to petroleum diesel, biodiesel is more corrosive for automotive materials. Studies on the characterization of corrosion products of fuel exposed automotive materials are scarce. Automotive fuel system and engine components are made from different ferrous and non-ferrous materials. The present study aims to investigate the corrosion products of different types of automotive materials such as copper, brass, aluminum and cast iron upon exposure to diesel and palm biodiesel. Changes in fuel properties due to exposure of different materials were also examined. Degradation of metal surface was characterized by digital camera, SEM/EDS and X-ray diffraction (XRD). Fuel properties were examined by measuring TAN (total acid number), density and viscosity. Among the metal investigated, copper is found to be least resistant in biodiesel and formed comparatively more corrosion products than other metals. Upon exposure of metals in biodiesel, TAN number crosses the limit given by standard while density and viscosity remain within the acceptable range of limit. -- Highlights: ► Order of incompatible metals in palm biodiesel: copper > brass > aluminum > cast iron. ► The possible reactions for the degradation of copper and cast iron have been discussed. ► For metal exposed biodiesel, only TAN number crosses the limit while density and viscosity remain within the limit. ► Copper and copper based alloy (brass) increase TAN number comparatively more than other metals.

  15. Generation of DNA profiles from fingerprints developed with columnar thin film technique.

    Science.gov (United States)

    Plazibat, Stephanie L; Roy, Reena; Swiontek, Stephen E; Lakhtakia, Akhlesh

    2015-12-01

    Partial-bloody fingerprints and partial fingerprints with saliva are often encountered at crime scenes, potentially enabling the combination of fingerprint and DNA analyses for absolute identification, provided that the development technique for fingerprint analysis does not inhibit DNA analysis. 36 partial-bloody fingerprints and 30 fingerprints wetted with saliva, all deposited on brass, were first developed using the columnar-thin-film (CTF) technique and then subjected to short tandem repeat (STR) DNA analysis. Equal numbers of samples were subjected to the same DNA analysis without development. Tris (8-hydroxyquinolinato) aluminum, or Alq3, was evaporated to deposit CTFs for development of the prints. DNA was extracted from all 132 samples, quantified, and amplified with AmpFlSTR(®) Identifiler Plus Amplification Kit. Additionally, DNA analyses were conducted on four blood smears on un-fingerprinted brass that had been subjected to CTF deposition and four blood smears on un-fingerprinted brass that had not been subjected to CTF deposition. Complete and concordant autosomal STR profiles of the same quality were obtained from both undeveloped and CTF-developed fingerprints, indicating that CTF development of fingerprints preserves DNA and does not inhibit subsequent DNA analysis. Even when there were no fingerprints, CTF deposition did not lead to inhibition of DNA analysis. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

  16. All welded titanium condenser adopted in atomic power plants

    International Nuclear Information System (INIS)

    Iwai, Nagao; Itabashi, Yukihiko

    1980-01-01

    Condensers in power plants are shell-and-tube type heat exchangers. Most condensers use seawater as a coolant. Their tube and tube Sheets have usually been made of brass, which resists corrosion but cannot completely prevent it; as a result, tubes sometimes corrode or erode, allowing seawater to leak into the turbine cycle. As is well known, titanium has almost complete corrosion resistance against seawater; for this reason titanium tubes have replaced brass ones in some condensers operating in Europe and the USA. Even in such condensers, though, the tube plates have still been made of brass, tightly fitted to the titanium tubes, and it has proved impossible to eliminate seawater leakage at the junctions between tubes and tube Sheets. In order to eliminate such leakage completely, the tube Sheets must be made of titanium too, and the tubes and plates must be welded together. However, the welding of titanium requires an extremely celan atmosphere, a condition very difficult to fulfill at power plant construction sites, and the use of whole welded titanium tube condensers has long been considered a practical impossibility. Such all-titanium welded condensers have now been successfully constructed and installed in two 600 MW fossil power plants and one 1100 MW nuclear power plant. This paper describes the techniques used, add in addition reviews the various materials that have been used in condenser tubes. (author)

  17. Mapping the Galvanic Corrosion of Three Coupled Metal Alloys Using Coupled Multielectrode Array: Influence of Chloride Ion Concentration.

    Science.gov (United States)

    Ju, Hong; Duan, JinZhuo; Yang, Yuanfeng; Cao, Ning; Li, Yan

    2018-04-20

    The galvanic corrosion behavior of three metal alloys commonly used in water desalination plants was investigated using coupled multielectrode arrays consisting of aluminum-brass (HAl77-2), titanium alloy (TA2), and 316L stainless steel (316L SS). The three electrode types were coupled galvanically and arranged in different geometric configurations. Their corrosion behavior was characterized as a function of the chloride concentration. The potential and current distributions of the three-electrode coupling systems display electrochemical inhomogeneity. Generally, the aluminum-brass wires are anodic versus the titanium alloy and stainless steel. The titanium alloy acts as a primary cathode, and the 316L SS acts as a secondary cathode. The corrosion rate of aluminum-brass depends on the concentration of chloride ion, with a maximum corrosion rate at a chloride concentration of 2.3 wt %. In terms of geometrical arrangements, when the anodic HAl77-2 wires are located on the edge and are connected to the 316L SS wires in the coupling system, the main anodic area enlarges, especially in the area adjacent to the 316L SS wires. When the HAl77-2 wires are located between (in the middle of) the two other types of wires, the corrosion rates are higher than the corrosion rates observed from the other two geometrical arrangements.

  18. RATIONALIZATION OF THE SCHEMA OF SACRIFICIAL ANODES USING FROM THE STANDPOINT OF MATERIAL AND POWER RESOURCES ECONOMY

    Directory of Open Access Journals (Sweden)

    S. E. Chikilev

    2008-01-01

    Full Text Available The calculations, allowing to optimize using of sacrificial copper anodes in the process of wire brassing, and also the results of experimental matching of material for insoluble anodes are given.

  19. incidence of heavy metals in kano metropolis drinking water sources

    African Journals Online (AJOL)

    userpc

    corrosion of brass fittings of certain submersible pumps and pipes used in borehole and taps specifically. The contamination of well with heavy metals might be due to seepage of sewage ... Chloride determination (Agumetric method):.

  20. Machinability evaluation of titanium alloys (Part 2)--Analyses of cutting force and spindle motor current.

    Science.gov (United States)

    Kikuchi, Masafumi; Okuno, Osamu

    2004-12-01

    To establish a method of determining the machinability of dental materials for CAD/CAM systems, the machinability of titanium, two titanium alloys (Ti-6Al-4V and Ti-6Al-7Nb), and free-cutting brass was evaluated through cutting force and spindle motor current. The metals were slotted using a milling machine and square end mills at four cutting conditions. Both the static and dynamic components of the cutting force represented well the machinability of the metals tested: the machinability of Ti-6Al-4V and Ti-6Al-7Nb was worse than that of titanium, while that of free-cutting brass was better. On the other hand, the results indicated that the spindle motor current was not sensitive enough to detect the material difference among the titanium and its alloys.

  1. Fouling communities and degradation of archeological metals in the coastal sea of the Southwestern Gulf of Mexico.

    Science.gov (United States)

    López Garrido, Pedro H; González-Sánchez, J; Escobar Briones, Elva

    2015-01-01

    Corrosion and biofouling phenomena of cast iron and brass were evaluated under natural conditions to determine the degradation process of archeological artifacts. Field exposure studies of experimental materials were conducted over 15 months at an offshore position in the sea of Campeche in the Gulf of Mexico. Corrosion was determined by gravimetric measurements. The community structure of the benthic assemblage inhabiting the surfaces of both materials was evaluated. A total of 53 species was identified. The community in both cases was composed of a small number of species. Encrusting, attached and erect life forms were dominant on iron. Attached life forms were dominant on brass. Biofouling produced a decrease in the weight loss measurements of cast iron samples. Biofouling provided a beneficial factor for in situ preservation of iron archeological artifacts in wreck sites.

  2. Simultaneous determination of trace-levels of alloying zinc and copper by semi-mercury-free potentiometric stripping analysis with chemometric data treatment

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov; Hansen, Elo Harald

    1998-01-01

    Assays of copper and zinc in brass samples were performed by Semi-Mercury Free Potentiometric Stripping Analysis (S-MF PSA) using a thin-film mercury covered glassy-carbon working electrode and dissolved oxygen as oxidizing agent during the stripping step. The stripping peak transients were...... resolved by chemometrics which enabled simultaneous determination of both the copper and the zinc concentrations, thereby eliminating the conventional necessary pretreatment of the sample solution, such as initial addition of Ga(III) or solvent extraction of copper. The brass samples were diluted...... by factors in the range 2.104 - 5.105 which resulted in quantification of the copper and of zinc contents comparable to the specified values within 10%. On the basis of the chemometric treatment, an empirical expression is deduced relating the stripping time to the recorded potential....

  3. 6 Home Cleaning Recipes

    Science.gov (United States)

    ... aluminum, brass, ceramics, chrome, copper, fiberglass, glass/quartz, plastic, and steel. GLASS CLEANER 1 cup vinegar 1 ... originally filled with commercial cleaning products. Instead, reuse plastic water bottles.  Always place a label on the ...

  4. Body Piercing

    Science.gov (United States)

    ... site and jewelry carefully. Avoid jewelry made of nickel or brass. These metals can cause allergic reactions. ... KnowRead Article >>Genetic Testing: What You Should KnowOccupational Exposure to LeadRead Article >>Occupational Exposure to Lead Visit ...

  5. Validation of the Turkish version of the Breast Reduction Assessed Severity Scale.

    Science.gov (United States)

    Kececi, Yavuz; Sir, Emin; Zengel, Baha

    2013-01-01

    Measuring patient-reported outcomes has become increasingly important in cosmetic and reconstructive breast surgery. There is no validated questionnaire in Turkish to evaluate quality-of-life issues for patients with mammary hypertrophy. The authors describe the reliability and validity of a translated Breast Reduction Assessed Severity Scale (BRASS) in evaluating Turkish patients. The BRASS, developed by Sigurdson et al, was translated into Turkish adhering strictly to the guidelines of questionnaire translations. Statistical analysis was carried out with Cronbach's α to test the internal consistency and intraclass correlation coefficient for test-retest reliability. Exploratory factor analysis was carried out using principal component analysis with oblimin rotation to test its construct validity. Correlations between subscales identified in the factor analysis and corresponding domains in the Short Form-36 and Rosenberg Self-Esteem Scale were analyzed. The total instrument was found to have an α coefficient of 0.92 and subscale α coefficients ranging from 0.76 to 0.87. Intraclass correlation coefficient was 0.93 for the total scale and ranged from 0.81 to 0.91 for the subscales. Exploratory factor analysis resulted in a 5-factor structure: physical implications, body pain, physical appearance, poor self-concept, and negative social interactions. With this study, the reliability and validity of the Turkish version of the BRASS were revealed. This translated version can be used to evaluate the effect of mammary hypertrophy on quality of life in Turkish patients.

  6. Strengthening mechanisms in a high-strength bulk nanostructured Cu–Zn–Al alloy processed via cryomilling and spark plasma sintering

    International Nuclear Information System (INIS)

    Wen, Haiming; Topping, Troy D.; Isheim, Dieter; Seidman, David N.; Lavernia, Enrique J.

    2013-01-01

    A bulk nanostructured alloy with the nominal composition Cu–30Zn–0.8Al wt.% (commercial designation brass 260) was fabricated by cryomilling of brass powders and subsequent spark plasma sintering (SPS) of the cryomilled powders, yielding a compressive yield strength of 950 MPa, which is significantly higher than the yield strength of commercial brass 260 alloys (∼200–400 MPa). Transmission electron microscopy investigations revealed that cryomilling results in an average grain diameter of 26 nm and a high density of deformation twins. Nearly fully dense bulk samples were obtained after SPS of cryomilled powders, with average grain diameter 110 nm. After SPS, 10 vol.% of twins is retained with average twin thickness 30 nm. Three-dimensional atom-probe tomography studies demonstrate that the distribution of Al is highly inhomogeneous in the sintered bulk samples, and Al-containing precipitates including Al(Cu,Zn)–O–N, Al–O–N and Al–N are distributed in the matrix. The precipitates have an average diameter of 1.7 nm and a volume fraction of 0.39%. Quantitative calculations were performed for different strengthening contributions in the sintered bulk samples, including grain boundary, twin boundary, precipitate, dislocation and solid-solution strengthening. Results from the analyses demonstrate that precipitate and grain boundary strengthening are the dominant strengthening mechanisms, and the calculated overall yield strength is in reasonable agreement with the experimentally determined compressive yield strength

  7. BWR fuel experience with zinc injection

    International Nuclear Information System (INIS)

    Levin, H.A.; Garcia, S.E.

    1995-01-01

    In 1982 a correlation between low primary recirculation system dose rates in BWR's and the presence of ionic zinc in reactor water was identified. The source of the zinc was primarily from Admiralty brass condensers. Plants with brass condensers are called ''natural zinc'' plants. Brass condensers were also a source of copper that was implicated in crude induced localized corrosion (CILC) fuel failures. In 1986 the first BWR intentionally injected zinc for the benefits of dose rate control. Although zinc alone was never implicated in fuel degradation of failures, a comprehensive fuel surveillance program was initiated to monitor fuel performance. Currently there are 14 plants that are injecting zinc. Six of these plants are also on hydrogen water chemistry. This paper describes the effect on both Zircaloy corrosion and the cruding characteristics as a result of these changes in water chemistry. Fuel rod corrosion was found to be independent of the specific water chemistry of the plants. The corrosion behavior was the same with the additions of zinc alone or zinc plus hydrogen and well within the operating experience for fuel without either of these additions. No change was observed in the amounts of crude deposited on the fuel rods, both for the adherent and loosely held deposits. One of the effects of the zinc addition was the trend to form more of the zinc rich iron spinel in the fuel deposits rather than the hematite deposits that are predominantly formed with non additive water chemistry

  8. Preparation and characterization of magnesium–aluminium–silicate ...

    Indian Academy of Sciences (India)

    Unknown

    and the melt was poured into graphite/brass moulds. Glass disc/cylinder of ... of the sample was measured by indentation technique using Vickers diamond pyramid .... Machinability of samples was tested by changing vari- ous parameters i.e. ...

  9. 9 CFR 96.9 - Casings admitted on disinfection; sealing; transfer and disinfection.

    Science.gov (United States)

    2010-01-01

    ... container in the space where the ends of the container enter the staves, by means of red sealing wax imprinted with the No. 3 Veterinary Services brass brand from which “insp'd & p's'd” and the establishment...

  10. Energy harvesting from vibration using a piezoelectric membrane

    Energy Technology Data Exchange (ETDEWEB)

    Ericka, M.; Vasic, D.; Costa, F.; Tliba, S. [Ecole Normale Superieure de Cachan, Systemes et Applications des Technologies de l' Information et de l' Energie (SATIE, UMR 8029), 94 - Cachan (France); Poulin, G. [Ecole Nationale Superieure d' Ingenieurs Electriciens de Grenoble, Laboratoire d' Automatique de Grenoble, 38 (France)

    2005-09-01

    In this paper we investigate the capability of harvesting the electric energy from mechanical vibrations in a dynamic environment through a piezoelectric membrane transducer. This transducer consists of 2 layers lead zirconate titanate (PZT)/brass, the brass layer is embedded over the whole circumference by epoxy adhesive. A very small vibration gives a consequent deformation of the membrane which generates electric energy. Due to the impedance matrices connecting the efforts and flows of the membrane, we have established the dynamic electric equivalent circuit of the transducer. In a first study and in order to validate theoretical results, we performed experiments with a vibrating machine moving a macroscopic 25 mm diameter piezoelectric membrane. A power of 1.8 mW was generated at the resonance frequency (2.58 kHz) across a 56 k{omega} optimal resistor and for a 2 g acceleration. (authors)

  11. Investigation of the susceptibility to solidification cracking in copper alloys

    Energy Technology Data Exchange (ETDEWEB)

    Warren, Richard [Avesta Sheffield R and D, Avesta (Sweden)

    2000-04-01

    A test procedure has been developed at LuTH for investigating the susceptibility to cracking at high temperatures in weldments. It has been proposed to adapt this testing procedure to investigate the cracking susceptibility at high temperatures during strip casting of certain copper alloys. Six different materials were selected for investigation - OFHC copper, tellurium containing copper, 4% tin bronze, 6% tin bronze, 30% zinc brass and 35% zinc brass. The aim of the investigation was to characterize the cracking susceptibility of the candidate materials so as to be able to rank and compare them in a quantitative manner. A further aim of the work was to study the suitability of using the data on the cracking indices generated in the present work in thermomechanical models of the casting process to optimize the casting parameters for each of the materials.

  12. The Compact Muon Solenoid (CMS) hadron calorimeter

    International Nuclear Information System (INIS)

    Hagopian, Vasken

    1999-01-01

    The Hadron Calorimeter of the CMS detector for the CERN LHC accelerator is designed to measure hadron jets as well as single hadrons. It has six segments. The central barrel made of brass and scintillators covers the vertical bar η vertical bar range of about 0 to 1.3. Two End Caps, also made of brass and scintillators extends the vertical bar η vertical bar range to 3.0. Two Forward calorimeters made of iron and quartz fibers cover the range 3.0 to 5.0. Since the barrel portion of the calorimeter is only 6.5 interaction lengths, the outer barrel will sample, by scintillators, outside the magnet coil and cryostat. Progress has been made on all subsystems and prototypes have been built. We now have a better understanding of magnetic field effects on calorimeters

  13. The effects of microstructure on crack initiation in liquid-metal environments

    CSIR Research Space (South Africa)

    Fernandes, PJL

    1997-09-01

    Full Text Available Liquid-metal-induced embrittlement under tensile test conditions is identified by the existence of a characteristic ductility trough. In this study, the effect of molten gallium on the behaviour of two brass alloys with different microstructures...

  14. 76 FR 70706 - Frontseating Service Valves From the People's Republic of China: Final Results of the 2008-2010...

    Science.gov (United States)

    2011-11-15

    ... also accessible on the Web at http://ia.ita.doc.gov/frn . The paper copy and electronic version of the... Include French Import Data to Value Brass Bar Comment 4: Whether To Use the Average of HTS 7407.21.10 and...

  15. Vol. 4(1), S/No 13, January, 2015:1-17 ISSN: 2225-8590 (Print ...

    African Journals Online (AJOL)

    DR Nneka

    2015-01-13

    Jan 13, 2015 ... headed by the oldest man (odionwere pl. edionwere) who was assisted by a village ... the emergence of Ogiso Ere, iron smith had existed in Benin. ..... brass mask given his predecessor by the Oba Esigie of Benin symbolized ...

  16. Comparative corrosion resistance of selected metals and nonmetals

    International Nuclear Information System (INIS)

    Anon.

    1977-01-01

    The relative corrosion resistance to 140 corrosive media is tabulated for the following substances: stainless steels 302, 303, 304, 305, 316, 410, 416, and 430, brass, silicon bronze, copper alloy 110, monel alloy 400, aluminum, and nylon (type 6/6)

  17. Basic Guidelines for Performance Monitoring of Shipboard Machinery

    Science.gov (United States)

    1975-11-01

    failure. The sensors will electrically indicate the buildup of particles ( aluminum , steel, magnesium, brass, etc.) as well as strain these particles...manual is a "consolidated sourcebook covering all aspects relating to accuracy, application, and usefulness of thermometric methods," specifically

  18. Investigations on a brass armour: Authentic or forgery?

    International Nuclear Information System (INIS)

    Martini, C.; Chiavari, C.; Ospitali, F.; Grazzi, F.; Scherillo, A.; Soffritti, C.; Garagnani, G.L.

    2013-01-01

    A copper-based armour, supposedly excavated in Eastern Georgia and tentatively dated to the I–II century AD, was investigated with the aim of checking its authenticity. The finding consisted of several pieces, mostly in a good state of conservation: helmet, lorica musculata (i.e. muscled cuirass), forearm guards, pterygies (covering the lower body and thighs), shin greaves and a spear tip. The combination of conventional metallography with in situ and non-destructive investigations (including Time of Flight Neutron Diffraction (ToF-ND)) on the front of the lorica, on one of the pterygies and on the spear tip showed that the composition and microstructure of the armour was not fully homogeneous. However, the results from the muscled cuirass are fairly coherent and raise suspicion about the authenticity of the piece, namely because of the (i) presence of metallic Al in the alloy, in solid solution with Cu, (ii) prevalence of an as-cast microstructure, which lead to a heavy weight as well to the need for a high amount of metal by comparison to hammered sheet and (iii) presence of an artificial patina, combined with earthy deposits which are not explainable if the original patina was removed before artificial patination for aesthetical reasons. - Highlights: • Cu-based armour from Eastern Georgia (I–II century AD?): check authenticity. • Conventional metallography combined with in situ and non-destructive investigations (ToF-ND). • Suspicious points: Al in the alloy, as-cast microstructure, artificial patina

  19. Investigations on a brass armour: Authentic or forgery?

    Energy Technology Data Exchange (ETDEWEB)

    Martini, C., E-mail: carla.martini@unibo.it [Department of Industrial Engineering (DIN), University of Bologna, Via Risorgimento 4, 40136 Bologna (Italy); Chiavari, C., E-mail: cristina.chiavari@unibo.it [C.I.R.I. M.A.M (Advanced Applications in Mechanical Engineering and Materials Technology Interdepartmental Centre for Industrial Research), University of Bologna, Via Risorgimento 2, 40136 Bologna (Italy); Ospitali, F., E-mail: francesca.ospitali@unibo.it [Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Viale Risorgimento 4, 40136 Bologna (Italy); Grazzi, F., E-mail: francesco.grazzi@fi.isc.cnr.it [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Via Madonna del Piano 10, 50019 Sesto Fiorentino, FI (Italy); Scherillo, A., E-mail: antonella.scherillo@stfc.ac.uk [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Via Madonna del Piano 10, 50019 Sesto Fiorentino, FI (Italy); Science and Technology Facility Council, ISIS Neutron Source, OX0QJ Didcot (United Kingdom); Soffritti, C., E-mail: chiara.soffritti@unife.it [TekneHub, Department of Architecture, University of Ferrara, Via Quartieri 8, 44122 Ferrara (Italy); Department of Engineering, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy); Garagnani, G.L., E-mail: gian.luca.garagnani@unife.it [Department of Engineering, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy)

    2013-10-01

    A copper-based armour, supposedly excavated in Eastern Georgia and tentatively dated to the I–II century AD, was investigated with the aim of checking its authenticity. The finding consisted of several pieces, mostly in a good state of conservation: helmet, lorica musculata (i.e. muscled cuirass), forearm guards, pterygies (covering the lower body and thighs), shin greaves and a spear tip. The combination of conventional metallography with in situ and non-destructive investigations (including Time of Flight Neutron Diffraction (ToF-ND)) on the front of the lorica, on one of the pterygies and on the spear tip showed that the composition and microstructure of the armour was not fully homogeneous. However, the results from the muscled cuirass are fairly coherent and raise suspicion about the authenticity of the piece, namely because of the (i) presence of metallic Al in the alloy, in solid solution with Cu, (ii) prevalence of an as-cast microstructure, which lead to a heavy weight as well to the need for a high amount of metal by comparison to hammered sheet and (iii) presence of an artificial patina, combined with earthy deposits which are not explainable if the original patina was removed before artificial patination for aesthetical reasons. - Highlights: • Cu-based armour from Eastern Georgia (I–II century AD?): check authenticity. • Conventional metallography combined with in situ and non-destructive investigations (ToF-ND). • Suspicious points: Al in the alloy, as-cast microstructure, artificial patina.

  20. Elemental fractionation in 785 nm picosecond and femtosecond laser ablation inductively coupled plasma mass spectrometry

    International Nuclear Information System (INIS)

    Shaheen, M.E.; Gagnon, J.E.; Fryer, B.J.

    2015-01-01

    Elemental fractionation and ICP-MS signal response were investigated for two different pulse width laser beams originating from the same laser system. Femtosecond and picosecond laser beams at pulse widths of 130 fs and 110 ps, respectively, and wavelength of 785 nm were used to ablate NIST 610 synthetic glass and SRM 1107 Naval Brass B at the same spot for 800 to 1000 laser pulses at different repetition rates (5 to 50 Hz). Elemental fractionation was found to depend on repetition rate and showed a trend with femtosecond laser ablation that is opposite to that observed in picosecond laser ablation for most measured isotopes. ICP-MS signal intensity was higher in femtosecond than picosecond LA-ICP-MS in both NIST 610 and naval brass when ablation was conducted under the same fluence and repetition rate. The differences in signal intensity were partly related to differences in particle size distribution between particles generated by femtosecond and picosecond laser pulses and the consequent differences in transport and ionization efficiencies. The main reason for the higher signal intensity resulting from femtosecond laser pulses was related to the larger crater sizes compared to those created during picosecond laser ablation. Elemental ratios measured using 66 Zn/ 63 Cu, 208 Pb/ 238 U, 232 Th/ 238 U, 66 Zn/ 232 Th and 66 Zn/ 208 Pb were found to change with the number of laser pulses with data points being more scattered in picosecond than femtosecond laser pulses. Reproducibility of replicate measurements of signal intensities, fractionation and elemental ratios was better for fs-LA-ICP-MS (RSD ~ 3 to 6%) than ps-LA-ICP-MS (RSD ~ 7 to 11%). - Highlights: • Fractionation and ICP-MS signal response were investigated for two different pulse widths using NIST 610 and Naval Brass. • Dependence of fractionation indices on repetition rate and pulse width. • Higher ablation rate was observed in picosecond compared to femtosecond laser ablation of NIST 610 and Brass

  1. Efficient low static-volume water heater

    Science.gov (United States)

    Brown, R. L.

    1976-01-01

    Calrod heating element is surrounded by matrix of fused sintered copper or brass balls, and assembly is then installed in piping of water system. As water flows through matrix, sintered balls cause turbulent flow and heating. Applications include laundromats, laboratories, and photographic labs.

  2. Effects of carbon fibres on the life cycle assessment of additively manufactured injection moulding inserts for rapid prototyping

    DEFF Research Database (Denmark)

    Hofstätter, Thomas; Bey, Niki; Mischkot, Michael

    2017-01-01

    properties and lifetime. The additively manufactured inserts are compared to the standard materials steel, aluminium and brass. The investigated part of the production and prototyping phase considers the insert itself, the moulded part, and resulting waste material of the injection moulding process....

  3. Corrosion of metals and alloys in the coastal and deep waters of the Arabian Sea and the Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)

    Sawant, S.S.; Venkat, K.; Wagh, A.B.

    Corrosion rate of mild steel (MS), stainless steel (SS), copper, brass and cupro-nickel has been determinEd. by exposing metallic coupons in coastal and oceanic waters of the Arabian Sea and Bay of Bengal. Amongst the metals and alloys under study...

  4. 76 FR 27005 - Polyethylene Terephthalate Film, Sheet, and Strip From the Republic of Korea: Initiation and...

    Science.gov (United States)

    2011-05-10

    ... typically examines several factors including, but not limited to: (1) Management; (2) production facilities; (3) supplier relationships; and (4) customer base. See Brass Sheet and Strip from Canada: Final... Saehan to TAMK resulted in little or no change in management, production facilities, supplier...

  5. Effects of loading variables on fatigue-crack growth in liquid-metal environments

    CSIR Research Space (South Africa)

    Fernandes, PJL

    1995-10-01

    Full Text Available Liquid-metal-induced embrittlement (LMIE) refers to the loss of ductility in normally ductile metals and alloys when stressed while in contact with a liquid metal. In this study, the fatigue crack growth behaviour of brass in molten gallium...

  6. Russian orchestral works. Torgny Sporsen / Ivan March

    Index Scriptorium Estoniae

    March, Ivan

    1991-01-01

    Uuest heliplaadist "Russian orchestral works. Torgny Sporsen (bass). Gothenburg Symphony Brass Band. Gothenburg Symphony Chorus and Orchestra / Neeme Järvi" D6 MC 429 984 - 4 GH; CD 429 984 - 26H (76 minutes). Borodin: In Central Asia. Prince Igor - Polovtsian Dances

  7. Download this PDF file

    African Journals Online (AJOL)

    User

    Mathematics and Statistics, Federal Polytechnic, Idah, Kogi State, Nigeria. ce Laboratory Technology, College of Education Technical Brass, Bayelsa State rtment of Microbiology, Kaduna State University, Kaduna State. Corresponding author. E-mail: ocholiahmed@yahoo.com primary school children between the ages of ...

  8. 76 FR 45511 - Stainless Steel Plate in Coils From Belgium: Notice of Initiation of Antidumping Duty Changed...

    Science.gov (United States)

    2011-07-29

    ..., but not limited to: (1) Management; (2) production facilities; (3) supplier relationships; and (4) customer base. See Brass Sheet and Strip from Canada: Final Results of Antidumping Duty Administrative... example, Aperam provided statements regarding its material and service providers and its customer base...

  9. Psychic Warfare: Exploring the Mind Frontier

    Science.gov (United States)

    1988-05-01

    month later Anderson was bacrk reinforcing psychic skepticism. This time he began, "The brass hats are, indeed, dabbling in the dark arts." Other...Emotion Radiator Ray; (10) Antisubmarine Systems; (11) Teleporters (Prototype); (12) Force Generators: (13) Orthoframe Generators; (14) Quark /Antiquark

  10. Determination of heat transfer parameters by use of finite integral transform and experimental data for regular geometric shapes

    Science.gov (United States)

    Talaghat, Mohammad Reza; Jokar, Seyyed Mohammad

    2017-12-01

    This article offers a study on estimation of heat transfer parameters (coefficient and thermal diffusivity) using analytical solutions and experimental data for regular geometric shapes (such as infinite slab, infinite cylinder, and sphere). Analytical solutions have a broad use in experimentally determining these parameters. Here, the method of Finite Integral Transform (FIT) was used for solutions of governing differential equations. The temperature change at centerline location of regular shapes was recorded to determine both the thermal diffusivity and heat transfer coefficient. Aluminum and brass were used for testing. Experiments were performed for different conditions such as in a highly agitated water medium ( T = 52 °C) and in air medium ( T = 25 °C). Then, with the known slope of the temperature ratio vs. time curve and thickness of slab or radius of the cylindrical or spherical materials, thermal diffusivity value and heat transfer coefficient may be determined. According to the method presented in this study, the estimated of thermal diffusivity of aluminum and brass is 8.395 × 10-5 and 3.42 × 10-5 for a slab, 8.367 × 10-5 and 3.41 × 10-5 for a cylindrical rod and 8.385 × 10-5 and 3.40 × 10-5 m2/s for a spherical shape, respectively. The results showed there is close agreement between the values estimated here and those already published in the literature. The TAAD% is 0.42 and 0.39 for thermal diffusivity of aluminum and brass, respectively.

  11. Effect of flexure beam geometry and material on the displacement of piezo actuated diaphragm for micropump

    Science.gov (United States)

    Roopa, R.; Navin Karanth, P.; Kulkarni, S. M.

    2018-02-01

    In this paper, we present a COMSOL analysis of flexure diaphragm for piezo actuated valveless micropump. Diaphragms play an important role in micropumps, till now plane diaphragms are commonly used in micropumps. Use of compliant flexure hinges in diaphragm and other MEMS application is one of the new approach to achieving high deflection in diaphragm at low operating voltage. Flexures hinges in diaphragm acts as simply supported beam. Out-off plane compliance value and stiffness is considered for the selection of proper flexure for diaphragm. Diaphragm material also plays an important role in the diaphragm central deflection. Factor considered for diaphragm material selection is resilience; it is the ratio of yield stress to static modulus. Higher is the resilience will leads to higher deflection generated, it also imparts good compliance. Based on the resilience beryllium copper, stainless steel and brass materials are selected for diaphragm analysis. Simulations have been performed using COMSOL multiphysics. This study reports the effect of flexure hinge geometry and diaphragm material on the central deflection of diaphragms and compared with existing plane diaphragm. Simulation results illustrates that the deflection of three flexure diaphragm with 2mm width and 2mm length flexure is 6.75µm for stainless steel, 10.89 for beryllium copper and 12.10µm for brass, at 140V which is approximately twice that of plane diaphragm deflection. The maximum in both plane and three flexure diaphragm deflection is obtained for brass diaphragm compared to stainless steel and beryllium copper.

  12. 75 FR 71072 - Initiation and Preliminary Results of Antidumping Duty Changed Circumstances Review: Certain...

    Science.gov (United States)

    2010-11-22

    ... factors including, but not limited to: (1) Management; (2) production facilities; (3) supplier relationships; and (4) customer base. See Brass Sheet and Strip from Canada: Final Results of Antidumping Duty... y Placa resulted in little or no change in management, production facilities, supplier relationships...

  13. THE MINERALOGY OF PB SCALES IN DRINKING WATER DISTRIBUTION SYSTEMS AS REVEALED BY COMBINED XRD AND MICRO-RAMAN SPECTROSCOPY

    Science.gov (United States)

    Dissolving Pb from lead service lines and Pb-containing brasses and solders has become a major health issue for many water distribution systems. Knowledge of the mineralogy of scales in these pipes is key to modeling this dissolution. The traditional method of determining their ...

  14. Home Plumbing Simulator for the Study of Copper and Lead Corrosion and Release, Disinfectant Demand, and Biofilm Activity - abstract

    Science.gov (United States)

    The corrosion of household or premise plumbing materials (such as copper, brass, and solder) and the metal release that results from that corrosion can cause numerous problems, ranging from “blue” water to copper pinhole leaks. If left untreated, these problems can lead to health...

  15. Modelling the survivorship of Nigeria children in their first 10 years of ...

    African Journals Online (AJOL)

    Fagbamigbe

    Conflict of Interest: Authors declared no conflict of interest ... Keywords: Survivorship, Nigeria, children mortality, Kaplan Meier, Brass Indirect method, Prediction ... variables or sex of older siblings, post- neonatal mortality is 12% higher and 2nd ... Relationship between maternal education and child survival in developing ...

  16. Performances of cutting fluids in turning. Mineral oil - RM

    DEFF Research Database (Denmark)

    Axinte, Dragos Aurelian; Belluco, Walter

    1999-01-01

    Scope of the present measurement campaign is the evaluation of the cutting fluid performance. The report presents the standard routine and the results obtained when turning stainless steel and brass with a commercial vegetable based oil called RM. The methods were developed to be applicable...

  17. Performances of cutting fluids in turning. Vegetable based oil - RV

    DEFF Research Database (Denmark)

    Axinte, Dragos Aurelian; Belluco, Walter

    1999-01-01

    Scope of the present measurement campaign is the evaluation of the cutting fluid performance. The report presents the standard routine and the results obtained when turning stainless steel and brass with a commercial vegetable based oil called RV. The methods were developed to be applicable...

  18. 46 CFR 181.320 - Fire hoses and nozzles.

    Science.gov (United States)

    2010-10-01

    ... fittings of brass or other suitable corrosion-resistant material that comply with NFPA 1963 (incorporated..., and an outer cover of rubber or equivalent material, and of sufficient strength to withstand the... corrosion-resistant material. (d) Each nozzle must be of corrosion-resistant material and be capable of...

  19. Sadhana | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Home; Journals; Sadhana. SIBA SANKAR MAHAPATRA. Articles written in Sadhana. Volume 35 Issue 5 October 2010 pp 619-629. Optimization in CNC end milling of UNS C34000 medium leaded brass with multiple surface roughnesses characteristics · Bharat Chandra Routara Saumya Darsan Mohanty Saurav Datta ...

  20. Nitrogen uptake by size-fractionated plankton in permanently well-mixed temperate coastal waters

    Digital Repository Service at National Institute of Oceanography (India)

    Wafar, M.V.M.; L'Helguen, S.; Raikar, V.; Maguernd, J.-F.; Le Corre, P.

    ’absorption de l’azote dans un syste`me brasse´ peu profound (Manche occidentale). Oceanol. Acta., 19, 529–537. Malone, T. C. (1980) Algal size. In Morris, I. (ed.), The Physiological Ecology of Phytoplankton. Blackwell, Oxford, UK, 433–463. Platt, T. and Li, W...

  1. 75 FR 82375 - North American Free Trade Agreement, Article 1904 NAFTA Panel Reviews; Request for Panel Review

    Science.gov (United States)

    2010-12-30

    .... (``Nacobre''), and their U.S. affiliates Cambridge-Lee Industries LLC and Copper and Brass International... conforms with the antidumping or countervailing duty law of the country that made the determination. Under... the allegations of error of fact or law, including the jurisdiction of the investigating authority...

  2. CHALLENGES IN MAINTAINING DRINKING WATER QUALITY AT THE TAP: CONTAMINATION WITH TOXIC LEAD

    Science.gov (United States)

    Aging drinking water infrastructure in the US was given a grade of D (poor) by the American Society of Civil Engineers, and was voted as the most urgent of all societal infrastructure challenges. Legacy lead pipe, leaded solder and/or leaded brass are a particularly notorious old...

  3. Catalogue of Wind and Percussion Solos and Ensembles and Recordings. American School Band Directors' Association, Research Committee Reports for the 26th Annual Convention, Oklahoma City, Oklahoma, 1978.

    Science.gov (United States)

    Berndt, William; Berndt, Arnold

    This catalogue lists over 350 phonograph records which feature solo and ensemble music by wind and percussion instruments. Instruments heard on the records include oboe/English horn, flute, clarinet, bassoon, trumpet/cornet, French horn, trombone, baritone, tuba, saxophone, percussion, woodwind ensembles, and brass ensembles. The catalogue is…

  4. Kontserdipeegel / Igor Garshnek

    Index Scriptorium Estoniae

    Garšnek, Igor, 1958-

    2000-01-01

    Kontsertidest Estonia kontserdisaalis ئ 17. veebr. ERSO A. Tshistjakovi juhatusel, solist S. Kuulmann; 28. veebr. Eesti-Soome SO A. Tali juhatusel kontserdiga "Armastus"; 2. märtsil ERSO A. Manzano juhatusel, solistid M. Mikalai, M. Männi ja P. Tarvas; 3. märtsil The Brass Brothers

  5. Basic science right, not basic science lite: medical education at a crossroad.

    Science.gov (United States)

    Fincher, Ruth-Marie E; Wallach, Paul M; Richardson, W Scott

    2009-11-01

    This perspective is a counterpoint to Dr. Brass' article, Basic biomedical sciences and the future of medical education: implications for internal medicine. The authors review development of the US medical education system as an introduction to a discussion of Dr. Brass' perspectives. The authors agree that sound scientific foundations and skill in critical thinking are important and that effective educational strategies to improve foundational science education should be implemented. Unfortunately, many students do not perceive the relevance of basic science education to clinical practice.The authors cite areas of disagreement. They believe it is unlikely that the importance of basic sciences will be diminished by contemporary directions in medical education and planned modifications of USMLE. Graduates' diminished interest in internal medicine is unlikely from changes in basic science education.Thoughtful changes in education provide the opportunity to improve understanding of fundamental sciences, the process of scientific inquiry, and translation of that knowledge to clinical practice.

  6. Evolution of Additively Manufactured Injection Molding Inserts Investigated by Thermal Simulations

    DEFF Research Database (Denmark)

    Hofstätter, Thomas; Pedersen, David B.; Tosello, Guido

    .7) mm3 and (60 x 80 x 10) mm3 produced with vat photo polymerization. This contribution discusses the heat transportation within the inserts made from a thermoset material, brass, steel, and ceramic material. It therefore elaborates on the possibilities of injection molding as well as the thermal...

  7. Determining two-step control in heterogeneous catalytic reactions

    Energy Technology Data Exchange (ETDEWEB)

    Chakrabarty, T; Silveston, P L; Hudgins, R R

    1979-10-01

    The data by Thaller and Thodos on the sec.-butanol dehydrogenation to methyl ethyl ketone on brass catalyst indicated that a dual site surface reaction was rate-controlling below 575/sup 0/K and hydrogen desorption was rate-controlling above 616/sup 0/K (Vertical BarAIChE J.

  8. Influence of environmental health services on students' academic ...

    African Journals Online (AJOL)

    The study investigated the effect of environmental health services on students' academic performance in secondary schools in Brass Local Government Area of Bayelsa State. The study adopted the descriptive survey design. The sample for the study comprised a total of 245 students and 59 teachers, amounting to 304 ...

  9. 24 CFR 3280.609 - Water distribution systems.

    Science.gov (United States)

    2010-04-01

    ... copper tubing, approved or listed plastic or other approved or listed material. (i) Plastic piping. All plastic water piping and fittings in manufactured homes must be listed for use with hot water. (ii... brass piping. They shall be installed where required for change in direction, reduction of size, or...

  10. ADHESION OF PSEUDOMONAS-FLUORESCENS TO METALLIC SURFACES

    NARCIS (Netherlands)

    VIEIRA, MJ; OLIVEIRA, R; MELO, L; PINHEIRO, M; VANDERMEI, HC

    1992-01-01

    Deposition of Pseudomonas fluorescens on aluminium, brass and copper plates was studied in a flow system. The number of bacteria deposited on aluminium was greater than on the other two types of metals. The results are discussed in terms of the mechanisms (transport and/or adhesion) that may control

  11. 77 FR 70738 - Procurement List Additions

    Science.gov (United States)

    2012-11-27

    ... Fire Fighters, Metal NSN: CBFF0053--Nameplate, Navy Fire Fighters, 2 Line, Metal NSN: CBFF0054--Collar, Brass, Navy Fire Fighters, Metal NSN: CBFF0055--Shorts, Navy Fire Fighters, Physical Training, Small... following products are added to the Procurement List: PRODUCTS: NSN: CBFF0001--Shirt, Navy Fire Fighters...

  12. The Golden Age of Technical Communication

    Science.gov (United States)

    Kimball, Miles A.

    2017-01-01

    This article uses a historical perspective to describe the development of the profession of technical communication through three ages: Brass, Beige, and Glass. I compare this development to the growth of the academic discipline and both to the explosion of noninstitutional technical communication--the growing body of tactical technical…

  13. 76 FR 73658 - Notice of Intent to Repatriate Cultural Items: Tennessee Valley Authority and the University of...

    Science.gov (United States)

    2011-11-29

    ...; six shell pendants; three pieces of glass; three samples of red ochre; three mink skull fragments; one... made from iron, brass, pewter, silver and lead; three glass mirrors or mirror fragments; six glass... piece of smelted lead; four steatite pipes; one catlinite pipe; two clay siltstone pipes; three...

  14. Sexual slander and the 1965/66 mass killings in Indonesia: political and methodological considerations

    NARCIS (Netherlands)

    Wieringa, S.E.

    2011-01-01

    Indonesia has been haunted by the "spectre of communism" since the putsch by military officers on 1 October 1965. That event saw the country's top brass murdered and the military attributing this putsch to the Communist Party. The genocide that followed was triggered by a campaign of sexual slander.

  15. Investigation Of The Microbial-Induced Corrosion Potential Of Soils ...

    African Journals Online (AJOL)

    Investigation of sulphate-reducing bacteria induced corrosion potential of soils along 18-inch 45km Tebidaba/Brass underground oil pipeline in Southern Ijaw LGA of Bayelsa State, Nigeria, is carried out experimentally. The analysis involves determination of some physico-chemical parameters of soils in the pipeline route, ...

  16. AcEST: DK953371 [AcEST

    Lifescience Database Archive (English)

    Full Text Available ragment) OS=Brass... 36 1.7 tr|Q590K5|Q590K5_9ROSI Maturase K OS=Phragmotheca ecuador... 464 S+F + HGD Sbjct: 67 SLFVYLHGD 75 >tr|Q590K5|Q590K5_9ROSI Maturase K OS=Phragmotheca ecuador

  17. Extractants to assess zinc phytoavailability in mineral fertilizer and industrial by-products

    Directory of Open Access Journals (Sweden)

    Camila Prado Cenciani de Souza

    2013-08-01

    Full Text Available Efficient analytical methods for the quantification of plant-available Zn contained in mineral fertilizers and industrial by-products are fundamental for the control and marketing of these inputs. In this sense, there are some doubts on the part of the scientific community as well as of the fertilizer production sector, whether the extractor requested by the government (Normative Instruction No. 28, called 2nd extractor, which is citric acid 2 % (2 % CA (Brasil, 2007b, is effective in predicting the plant availability of Zn via mineral fertilizers and about the agronomic significance of the required minimal solubility of 60 % compared to the total content (HCl (Brasil, 2007a. The purpose of this study was to evaluate the alternative extractors DTPA, EDTA, neutral ammonium citrate (NAC, buffer solution pH 6.0, 10 % HCl, 10 % sulfuric acid, 1 % acetic acid, water, and hot water to quantify the contents of Zn available for maize and compare them with indices of agronomic efficiency of fertilizers and industrial by-products when applied to dystrophic Clayey Red Latosol and Dystrophic Alic Red Yellow Latosol with medium texture. The rate of Zn applied to the soil was 5 mg kg-1, using the sources zinc sulfate, commercial granular zinc, ash and galvanic sludge, ash and two brass slags. Most Zn was extracted from the sources by DTPA, 10 % HCl, NAC, 1% acetic acid, and 10 % sulfuric acid. Recovery by the extractors 2 % CA, EDTA, water, and hot water was low. The agronomic efficiency index was found to be high when using galvanic sludge (238 % and commercial granular zinc (142 % and lower with brass slag I and II (67 and 27 %, respectively. The sources galvanizing ash and brass ash showed solubility lower than 60 % in 2 % CA, despite agronomic efficiency indices of 78 and 125 %, respectively. The low agronomic efficiency index of industrial by-products such as brass slag I and galvanizing ash can be compensated by higher doses, provided there is no

  18. Elemental fractionation in 785 nm picosecond and femtosecond laser ablation inductively coupled plasma mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Shaheen, M.E., E-mail: mshaheen73@science.tanta.edu.eg [Department of Physics, Faculty of Sciences, Tanta University, Tanta (Egypt); Gagnon, J.E.; Fryer, B.J. [Great Lakes Institute for Environmental Research (GLIER), University of Windsor, Windsor, Ontario N9B 3P4 (Canada); Department of Earth and Environmental Sciences, University of Windsor, Windsor, Ontario N9B 3P4 (Canada)

    2015-05-01

    Elemental fractionation and ICP-MS signal response were investigated for two different pulse width laser beams originating from the same laser system. Femtosecond and picosecond laser beams at pulse widths of 130 fs and 110 ps, respectively, and wavelength of 785 nm were used to ablate NIST 610 synthetic glass and SRM 1107 Naval Brass B at the same spot for 800 to 1000 laser pulses at different repetition rates (5 to 50 Hz). Elemental fractionation was found to depend on repetition rate and showed a trend with femtosecond laser ablation that is opposite to that observed in picosecond laser ablation for most measured isotopes. ICP-MS signal intensity was higher in femtosecond than picosecond LA-ICP-MS in both NIST 610 and naval brass when ablation was conducted under the same fluence and repetition rate. The differences in signal intensity were partly related to differences in particle size distribution between particles generated by femtosecond and picosecond laser pulses and the consequent differences in transport and ionization efficiencies. The main reason for the higher signal intensity resulting from femtosecond laser pulses was related to the larger crater sizes compared to those created during picosecond laser ablation. Elemental ratios measured using {sup 66}Zn/{sup 63}Cu, {sup 208}Pb/{sup 238}U, {sup 232}Th/{sup 238}U, {sup 66}Zn/{sup 232}Th and {sup 66}Zn/{sup 208}Pb were found to change with the number of laser pulses with data points being more scattered in picosecond than femtosecond laser pulses. Reproducibility of replicate measurements of signal intensities, fractionation and elemental ratios was better for fs-LA-ICP-MS (RSD ~ 3 to 6%) than ps-LA-ICP-MS (RSD ~ 7 to 11%). - Highlights: • Fractionation and ICP-MS signal response were investigated for two different pulse widths using NIST 610 and Naval Brass. • Dependence of fractionation indices on repetition rate and pulse width. • Higher ablation rate was observed in picosecond compared to

  19. The muon filter of the L3 detector

    International Nuclear Information System (INIS)

    Adriani, O.; Bocciolini, M.; Cartacci, A.M.; Civinini, C.; D'Alessandro, R.; Gallo, E.; Landi, G.; Marchionni, A.; Meschini, M.; Monteleoni, B.; Pieri, M.; Spillantini, P.; Wang, Y.F.; Florence Univ.

    1991-01-01

    In this article we describe the outer part (Muon Filter) of the Hadron Calorimeter of the L3 detector. Construction and performance of the brass chambers, which form the sensitive part of the detector, are reviewed. We also report the results from data taken on two beam tests, at CERN. (orig.)

  20. EDM Electrode for Internal Grooves

    Science.gov (United States)

    Ramani, V.; Werner, A.

    1985-01-01

    Electroerosive process inexpensive alternative to broaching. Hollow brass electrodes, soldered at one end to stainless-steel holding ring, held in grooves in mandrel. These electrodes used to machine grooves electrically in stainless-steel tube three-eights inch (9.5 millimeters) in diameter. Tool used on tubes already in place in equipment.

  1. 77 FR 59596 - Procurement List; Proposed Additions

    Science.gov (United States)

    2012-09-28

    ... NSN: CBFF0051--Tie Clip, Navy Fire Fighters, Metal NSN: CBFF0053--Nameplate, Navy Fire Fighters, 2 Line, Metal NSN: CBFF0054--Collar, Brass, Navy Fire Fighters, Metal NSN: CBFF0055--Shorts, Navy Fire..., Navy Fire Fighters, Unisex, Short Sleeve Polo, Small thru XXX-Large NSN: CBFF0002--Shirt, Navy Fire...

  2. Morphologic variations of periwinkle and profiles of periwinkle ...

    African Journals Online (AJOL)

    Periwinkles are invertebrates rich in protein and omega-3 fatty acids. These make them relished delicacies. Three hundred and fifteen (315) individual periwinkles were hand-picked from mangrove swamp river banks and intertidal zones of Twon-Brass in Bayelsa State and Abonnema town of Rivers State. Shell length and ...

  3. The Communications of Influence through Technology-Enabled Media

    Science.gov (United States)

    2006-12-01

    meaning, communication, action, and contextual structures, resources, or frameworks-such as those discussed in Blumer’s (1969) symbolic interactionism or...Blumer, H. (1969). Symbolic interactionism : Perspective and method. Englewood Cliffs, NJ: Prentice-Hall. Brass, D. J., & Burkhardt, M. E. (1993...and Interaction ................................................................ 42 3. Symbolic Exchange of Influence Messages

  4. 24 CFR 3280.610 - Drainage systems.

    Science.gov (United States)

    2010-04-01

    ... iron, brass, copper tube DWV, listed plastic, cast iron, or other listed or approved materials. (2... be used to join copper tubing to threaded pipe. (c) Drain outlets. (1) Each manufactured home shall have only one drain outlet. (2) Clearance from drain outlet. The drain outlet shall be provided with a...

  5. ISSN 2073 ISSN 2073-9990 East Cent. Afr. J. surg. (Online) 90 East ...

    African Journals Online (AJOL)

    DELL

    Teunissen LL, Rinkel GJE, Algra A, van Gijn J. Risk factors for subarachnoid hemorrhage. A systemic review. Stroke 1996; 27: 544-549. 22. Levine SR, Brust JC, Futrell N, Brass LM, Blake D, Fayad P, et al. A comparative study of cerebro- vascular complications of cocaine: alkaloidal versus hydrochloride. Neurology 1991 ...

  6. Fatigue damage assessment of recycled metals and alloys | Ayensu ...

    African Journals Online (AJOL)

    Cyclic fatigue tests were conducted on recycled polycrystalline metals and alloys at room and elevated tempera-ures to determine the fatigue strength, endurance limit and endurance ratio. Annealed and polished stainless steel (Fe-18Cr-8Ni), mild steel (Fe-0.25Cr), aluminium (Al), alpha-brass (Cu-30 % Zn) and copper ...

  7. Terrorism, Violence, and the Collision of Masculinities in "Four Lions"

    Science.gov (United States)

    Labidi, Imed

    2011-01-01

    Many critics hailed the new film, "Four Lions," by director Chris Morris as "provocative, incendiary, audacious, and shocking" and "one of the funniest and boldest comedies of the year." As a satirist, Morris already established his wit signature with the production of the mockumentary series, "Brass Eye." Using the same absurdist approach, he…

  8. 46 CFR 160.043-3 - Materials.

    Science.gov (United States)

    2010-10-01

    ... Type 420 stainless steel, heat treated to show a Rockwell hardness of C44 to C48. (b) Linings and center. The linings and center shall be hard brass. (c) Bolsters and shackle. The bolsters and shackle shall be 18 percent nickel-silver. (d) Handles. The handles shall be good quality, thermosetting, high...

  9. The New Star, the New Nose: Tycho Brahe's Nasal Prosthesis

    DEFF Research Database (Denmark)

    Østermark-Johansen, Lene

    2017-01-01

    Tycho Brahe’s loss of part of his nose in a duel has become an important part of his afterlife. The exact nature of his nasal prosthesis–of brass, gold, or silver–remains an enigma, not even solved at his exhumation in 2010. This essay discusses the materiality of Brahe’s new nose...

  10. Influence of surface condition on the corrosion resistance of copper alloy condenser tubes in sea water

    Energy Technology Data Exchange (ETDEWEB)

    Sato, S; Nagata, K; Yamauchi, S

    1979-07-01

    Investigation was made on the influence of various surface conditions of aluminum brass tube. The corrosion behavior of aluminum brass tube, with nine kinds of surface conditions, was studied in stagnant 0.1N NaHCo/sub 3/ solution and flowing sea water (natural, Fe/sup + +/ containing and S/sup - -/ containing water). Surface treatments investigated contained bright annealing, special annealing to form carbon film, hot oxidizing and pickling. Anodic polarization measurements in 0.1N NaHCO/sub 3/ solution showed that the oxidized surface was superior and that the pickled surface was inferior. However, relation between these characteristics and corrosion resistance in sea water has not been established. Electrochemical characteristics in flowing sea water were dependent on the surface conditions in the very beginning of immersion time; nobler corrosion potential for the surface with carbon film, higher polarization resistance for the bright annealed and the oxidized surface, and faster decrease of polarization resistance in S/sup - -/ containing sea water for the pickled surface. However, these differences disappeared in the immersion time of only 2 to 7 days. It was revealed, by the statistical analysis on the corrosion depth in corrosion test in flowing sea water and in jet impingement test, that the corrosion behavior was not influenced by surface conditions, but was significantly influenced by quality of sea water and sponge ball cleaning. Sulfide ion of 0.05 ppm caused severe pitting corrosion, and sponge ball cleaning of 5 chances a week caused erosion corrosion. From above results, it was concluded that surface conditions of aluminum brass were not important to sea water corrosion, and that quality of sea water and operating condition such as sponge ball cleaning were more significant.

  11. Aplikasi Multichart Diagram Dalam Desain Dan Manufaktur Tungku Pengecoran Kuningan (CuZn5 Menggunakan Bahan Bakar Briket Batubara Kalori Rendah

    Directory of Open Access Journals (Sweden)

    Diah Kusuma Pratiwi

    2015-07-01

    Full Text Available Abstrak : Sejak semakin mahalnya harga miyak bumi, sebagian besar industri kecil pengecoran logam tidakdapat bertahan karena biaya produksi yang semakin tinggi. Oleh karena itu dicari bahan bakaralternatif yang dapat menggantikan minyak dan gas dengan aman dan murah. Indonesia kayaakan batubara yang dalam pasar domestik dijual dalam bentuk briket batubara kalori rendah,oleh karena itu dilakukan desain untuk membuat tungku dengan bahan bakar ini. Proses desaindilakukan dengan mulai menghitung kalor yang dibutuhkan untuk melebur lagam, dalam hal inilogam yang akan dilebur adalah kuningan (CuZn5. Selanjutnya dilakukan pemilihan materialrefraktori untuk tungku yang dapat meminimalisir heat loss. Desain tungku pengecoran inidilakukan dengan menggunakan Multichart Diagram untuk effisiensi 40 % dan kapasitas 150 kgkuningan. Hasil Uji coba pengecoran dilapangan ternyata effisiensi tungku adalah 42%, lamapeleburan 3,5 jam.Kata kunci: Tungku pengecoran kuningan, briket batubara kalori rendah, mulichart diagram Abstract : Since the increasingly price of oil fuel, mostly small foundry industry can not survive due to thehigher production costs. Therefore searching for alternative fuels that can replace oil and gas safelyand inexpensively is promoted. Indonesia is rich in coal. In domestic market is sold in the form oflow-grade coal briquettes, therefore, is carried out the design to make furnace from this fuel. Thedesign process is done by beginning to calculate the heat needed to melt this alloy, in this case themetal to be melted is brass (CuZn5. Furthermore, the material selection for refractory furnace tominimize heat loss. This casting is done by using Multichart Diagram for 40% efficiency andcapacity of 150 kg brass. The test results during experiment obtained that efficiency is 42% in 3.5hours.Keywords: Furnace casting brass, low grade coal briquettes, multichart diagram

  12. In Situ Monitoring of Pb2+ Leaching from the Galvanic Joint Surface in a Prepared Chlorinated Drinking Water.

    Science.gov (United States)

    Ma, Xiangmeng; Armas, Stephanie M; Soliman, Mikhael; Lytle, Darren A; Chumbimuni-Torres, Karin; Tetard, Laurene; Lee, Woo Hyoung

    2018-02-20

    A novel method using a micro-ion-selective electrode (micro-ISE) technique was developed for in situ lead monitoring at the water-metal interface of a brass-leaded solder galvanic joint in a prepared chlorinated drinking water environment. The developed lead micro-ISE (100 μm tip diameter) showed excellent performance toward soluble lead (Pb 2+ ) with sensitivity of 22.2 ± 0.5 mV decade -1 and limit of detection (LOD) of 1.22 × 10 -6 M (0.25 mg L -1 ). The response time was less than 10 s with a working pH range of 2.0-7.0. Using the lead micro-ISE, lead concentration microprofiles were measured from the bulk to the metal surface (within 50 μm) over time. Combined with two-dimensional (2D) pH mapping, this work clearly demonstrated that Pb 2+ ions build-up across the lead anode surface was substantial, nonuniform, and dependent on local surface pH. A large pH gradient (ΔpH = 6.0) developed across the brass and leaded-tin solder joint coupon. Local pH decreases were observed above the leaded solder to a pH as low as 4.0, indicating it was anodic relative to the brass. The low pH above the leaded solder supported elevated lead levels where even small local pH differences of 0.6 units (ΔpH = 0.6) resulted in about four times higher surface lead concentrations (42.9 vs 11.6 mg L -1 ) and 5 times higher fluxes (18.5 × 10 -6 vs 3.5 × 10 -6 mg cm -2 s -1 ). Continuous surface lead leaching monitoring was also conducted for 16 h.

  13. Field size dependence of wedge factor: miniphantom vs full phantom measurements

    International Nuclear Information System (INIS)

    Allen Li, X.; Szanto, J.; Soubra, M.; Gerig, L. H.

    1995-01-01

    It is empirically known that the transmission factor for wedge in a high-energy photon beam is dependent upon field size and depth of measurement. The field-size dependence of wedge factors may be attributed to changes in (i) head scatter, (ii) phantom scatter, and (iii) backscatter from the wedge into the linac monitor chamber. In this work we present the results of studies designed to examine each of these factors in isolation. The wedge factors for wedges with nominal wedge angles of 15 deg. , 30 deg. , 45 deg. and 60 deg. were measured with a 3-g/cm 2 -diameter narrow cylindrical phantom (miniphantom), a brass cap with 1.5-g/cm 2 side-wall thickness and a full water phantom for 6-, 10- and 18-MV photon beams. The measurements were performed with and without flattening filter in place. The wedge factors measured with the miniphantom and the brass cap exclude the phantom scatter contribution. It has been found that the field-size behaviour of wedge factor measured with full water phantom is similar to that measured with the miniphantom and cap. This indicates that the head scatter radiation is the major contributor to the field size dependence of wedge factors. Wedge factors measured with water phantom are up to 5.0% smaller than those measured with miniphantom. This difference increases with wedge angle. When Measured with the flattening filter removed, the field size dependence of the wedge factor is reduced. This justify that the flattening filter is one of the major contributors to head scatters. The measurement results made with the brass cap agree well with those made by using the miniphantom. By measuring the monitor chamber output, it is found that the backscatters from the wedge into the linac ion chamber have little effect on the field size dependence of the wedge factor

  14. PORTABLE SOURCE OF RADIOACTIVITY

    Science.gov (United States)

    Goertz, R.C.; Ferguson, K.R.; Rylander, E.W.; Safranski, L.M.

    1959-06-16

    A portable source for radiogiaphy or radiotherapy is described. It consists of a Tl/sup 170/ or Co/sup 60/ source mounted in a rotatable tungsten alloy plug. The plug rotates within a brass body to positions of safety or exposure. Provision is made for reloading and carrying the device safely. (T.R.H.)

  15. Acute Toxicological Effects of Crude Oil On Haematological And ...

    African Journals Online (AJOL)

    The acute toxicological effects of Brass blend of crude oil on the haemoglobin concentration, and Liver functions in the Guinea pig were studied. 25 Guinea pigs divided into five animals per group were used for the study. They were divided into 5 groups. One group served as a control group, while the others received ...

  16. An overview of CMS central hadron calorimeter

    CERN Document Server

    Katta, S

    2002-01-01

    The central hadron calorimeter for CMS detector is a sampling calorimeter with active medium as scintillator plates interleaved with brass absorber plates. It covers the central pseudorapidity region (¿ eta ¿<3.0). The design and construction aspects are reported. The status of construction and assembly of various subdetectors of HCAL are presented. (5 refs).

  17. Mosses of d’Entrecasteaux group & Louisiade Archipelago, Papua, New Guinea

    NARCIS (Netherlands)

    Bartram, Edwin B.

    1960-01-01

    The moss collections made by L. J. Brass in connection with the 5th, Archbold Expedition to New Guinea to New Guinea in 1956 to the islands off the eastern tip of Papua comprise 166 numbers representing 87 species as outlined in the following list. Three species are described as new and 22 preceeded

  18. Translations on Eastern Europe Political, Sociological, and Military Affairs No. 1564

    Science.gov (United States)

    1978-07-18

    to all this, he has enough knowledge from his high school studies and passes the written exams in mathematics and the Russian language, and does well...activities or technical hobbies. You can find in the’ school a brass band, a cymbal band, a violin quintet, 60-member choir and a jazz ballet--and

  19. 75 FR 7936 - Airworthiness Directives; SCHEIBE-Flugzeugbau GmbH Model SF 25C Gliders

    Science.gov (United States)

    2010-02-23

    ... the lower side of the wing), disconnect the aileron from the wings, disconnect the elevator from the... connected to the ribs and the spar with steel tube rivets, no further action is required. (3) If the aileron hinges or the stabilizer to fuselage fittings are connected to the ribs and the spar with brass tube...

  20. Hispanics and the Military: A Selected Annotated Bibliography.

    Science.gov (United States)

    1985-08-01

    assigned to Puerto Rico as the com- mander of the 65th, which, he says, was what "the Pentagon brass referred to as a ’rum and Coca Cola ’ outfit." Hayes...over- represenation of blacks, Hispanics, and economically disad- vantaged whites. Under sponsorship of the Department of Defense, an additional sample

  1. Fulltext PDF

    Indian Academy of Sciences (India)

    393. Coomar N see Kadoli R. 1. Daneshmand S. The effect of chromium coating in RP tech- nology for airfoil Manufacturing. 569. Dash S see Kumar N. 493. Dash S see Kumar N. 609. Datta S. Optimization in CNC end milling of UNS. C34000 medium leaded brass with multiple surface roughnesses characteristics. 619.

  2. Leadership in Two Worlds: Operating in Disparate Realms, One that Pushes Ego and Ambition, the Other that Promotes Personal Values and Principled Acts

    Science.gov (United States)

    Goens, George A.

    2011-01-01

    People live in two worlds. The first is the external world of competition, ego, ambition and power. Here they chase the brass ring of success through control and standardized procedures designed to stave off failure. In this context, leaders face politics, conflicting expectations and bottom-line metrics. But in quiet moments of solitude, these…

  3. An experimental investigation of triggered film boiling destabilisation

    International Nuclear Information System (INIS)

    Naylor, P.

    1985-03-01

    Film boiling was established on a polished brass rod in water, collapse being initiated by either a pressure pulse or a transient bulk water flow. This work is relevant to the triggering stage of a molten fuel-coolant interaction, and a criterion is proposed for triggered film boiling collapse with pressure pulse. (U.K.)

  4. Things Korean.

    Science.gov (United States)

    Chang, Roberta

    Presented in this booklet are brief descriptions of items and activities that are symbolic of Korean culture. Some of the items and activities described include traditional Korean clothing and accessories, dolls, fans, a Korean game called "yut," tape recordings of Korean music, a "buhk" (drum), and brass eating utensils. A map of Korea, some…

  5. Investigation on power discharge in micro-EDM stainless steel drilling using different electrodes

    Energy Technology Data Exchange (ETDEWEB)

    D' Urso, G.; Maccarini, G.; Quarto, M.; Ravasio, C. [University of Bergamo, Bergamo (Italy)

    2015-10-15

    The present work deals with the execution of through micro-holes on stainless steel plates using a micro-EDM (Electrical discharge machining) machine. The investigation focuses on the influence of different electrodes' materials and power discharge on both the process performance and the dimensional characteristics of the holes. The experimental campaign was carried out by varying peak current and voltage in order to achieve both high and low power discharge conditions. Tubular electrodes made of three different materials (tungsten carbide, brass and copper) were used. The indexes taken into account were Material removal rate (MRR), Tool wear ratio (TWR), Diametral overcut (DOC) and Taper rate (TR). Brass and copper electrodes always resulted to be the best solution in terms of drilling speed even though the wear of these electrode types is remarkable higher than the tungsten one. On the opposite, tungsten carbide electrodes resulted to be the best solution when high dimensional and geometrical precision is required. Concerning the finishing of the hole inner surface, the best results were achieved using tungsten carbide electrode.

  6. Investigation on power discharge in micro-EDM stainless steel drilling using different electrodes

    International Nuclear Information System (INIS)

    D'Urso, G.; Maccarini, G.; Quarto, M.; Ravasio, C.

    2015-01-01

    The present work deals with the execution of through micro-holes on stainless steel plates using a micro-EDM (Electrical discharge machining) machine. The investigation focuses on the influence of different electrodes' materials and power discharge on both the process performance and the dimensional characteristics of the holes. The experimental campaign was carried out by varying peak current and voltage in order to achieve both high and low power discharge conditions. Tubular electrodes made of three different materials (tungsten carbide, brass and copper) were used. The indexes taken into account were Material removal rate (MRR), Tool wear ratio (TWR), Diametral overcut (DOC) and Taper rate (TR). Brass and copper electrodes always resulted to be the best solution in terms of drilling speed even though the wear of these electrode types is remarkable higher than the tungsten one. On the opposite, tungsten carbide electrodes resulted to be the best solution when high dimensional and geometrical precision is required. Concerning the finishing of the hole inner surface, the best results were achieved using tungsten carbide electrode.

  7. Music and its Impact on Musicians in Broadcasting Company

    Directory of Open Access Journals (Sweden)

    Mina Milani

    1999-03-01

    Full Text Available Sound is an inseparable part of human life and provides us with lovely experiences such as listening to music. Musicians from classical orchestras to rock groups are exposed to high decibel of sounds. Musicians playing percussion musical instruments are exposed to high level of impact noise and players of Brass musical instruments are highly exposed to noise peaks higher than 100dB. Woodwind players are enduring the risk of posing directly in front of Brass players. Based on the above-mentioned risks for hearing loss clinical consideration of noise induced hearing loss in musicians is highly required. In the current study we were aimed at examining hearing stratus of classic and traditional musicians by means of pure tone audiometry in Islamic Republic of Iran Broadcasting. 33 subjects were evaluated aged between 22 to 59 years old. Their musical experience was variable between 6 to 45 years. The study demonstrated that most of the musicians in this study suffered bilateral high frequency hearing loss with a notch in the frequency range of 4-8 KHz.

  8. Machinability evaluation of titanium alloys.

    Science.gov (United States)

    Kikuchi, Masafumi; Okuno, Osamu

    2004-03-01

    In the present study, the machinability of titanium, Ti-6Al-4V, Ti-6A1-7Nb, and free-cutting brass was evaluated using a milling machine. The metals were slotted with square end mills under four cutting conditions. The cutting force and the rotational speed of the spindle were measured. The cutting forces for Ti-6Al-4V and Ti-6Al-7Nb were higher and that for brass was lower than that for titanium. The rotational speed of the spindle was barely affected by cutting. The cross sections of the Ti-6Al-4V and Ti-6Al-7Nb chips were more clearly serrated than those of titanium, which is an indication of difficult-to-cut metals. There was no marked difference in the surface roughness of the cut surfaces among the metals. Cutting force and the appearance of the metal chips were found to be useful as indices of machinability and will aid in the development of new alloys for dental CAD/CAM and the selection of suitable machining conditions.

  9. Effect of Projectile Materials on Foreign Object Damage of a Gas-Turbine Grade Silicon Nitride

    Science.gov (United States)

    Choi, Sung R.; Racz, Zsolt; Bhatt, Ramakrishna T.; Brewer, David N.; Gyekenyesi, John P.

    2005-01-01

    Foreign object damage (FOD) behavior of AS800 silicon nitride was determined using four different projectile materials at ambient temperature. The target test specimens rigidly supported were impacted at their centers by spherical projectiles with a diameter of 1.59 mm. Four different types of projectiles were used including hardened steel balls, annealed steel balls, silicon nitride balls, and brass balls. Post-impact strength of each target specimen impacted was determined as a function of impact velocity to better understand the severity of local impact damage. The critical impact velocity where target specimens fail upon impact was highest with brass balls, lowest with ceramic ball, and intermediate with annealed and hardened steel balls. Degree of strength degradation upon impact followed the same order as in the critical impact velocity with respect to projectile materials. For steel balls, hardened projectiles yielded more significant impact damage than annealed counterparts. The most important material parameter affecting FOD was identified as hardness of projectiles and was correlated in terms of critical impact velocity, impact deformation, and impact load.

  10. Functional Performances of CuZnAl Shape Memory Alloy Open-Cell Foams

    Science.gov (United States)

    Biffi, C. A.; Casati, R.; Bassani, P.; Tuissi, A.

    2018-01-01

    Shape memory alloys (SMAs) with cellular structure offer a unique mixture of thermo-physical-mechanical properties. These characteristics can be tuned by changing the pore size and make the shape memory metallic foams very attractive for developing new devices for structural and functional applications. In this work, CuZnAl SMA foams were produced through the liquid infiltration of space holder method. In comparison, a conventional CuZn brass alloy was foamed trough the same method. Functional performances were studied on both bulk and foamed SMA specimens. Calorimetric response shows similar martensitic transformation (MT) below 0 °C. Compressive response of CuZnAl revealed that mechanical behavior is strongly affected by sample morphology and that damping capacity of metallic foam is increased above the MT temperatures. The shape memory effect was detected in the CuZnAl foams. The conventional brass shows a compressive response similar to that of the martensitic CuZnAl, in which plastic deformation accumulation occurs up to the cellular structure densification after few thermal cycles.

  11. The effect of Cu-rich sub-layer on the increased corrosion resistance of Cu-xZn alloys in chloride containing borate buffer

    International Nuclear Information System (INIS)

    Milosev, Ingrid; Mikic, Tadeja Kosec; Gaberscek, Miran

    2006-01-01

    The electrochemical behaviour of Cu-xZn alloys, as well as their constituent metals, in a borate buffer containing chloride ions in the molar range from 0.01 to 1 M are studied. Characteristics of these materials under anodic polarization are compared and the composition and morphology of the corrosion products formed in the course of polarization experiment are analysed by SEM and EDS. X-ray photoelectron spectroscopy and electrochemical impedance measurements are used for characterization of the surface layers formed on Cu, Zn and Cu-40Zn alloy during 2-h immersion at E oc in a borate buffer containing two different concentrations of chloride ions. New aspects of the behaviour of brass under E oc condition are revealed. The improved corrosion resistance of brass in chloride media, if compared to zinc metal, is attributed to a Cu-rich layer formed by the selective dissolution of zinc. Based on the results, a structural model describing the improved corrosion resistance of Cu-40Zn alloy with respect to Zn metal is proposed

  12. Comparative assessment of microstructure and texture in the Fe-30.5Mn-8.0Al-1.2C and Fe-30.5Mn-2.1Al-1.2C steels under cold rolling

    Directory of Open Access Journals (Sweden)

    Fabrício Mendes Souza

    Full Text Available Abstract Investigation of microstructure and texture has been done for cold rolled Fe-30.5Mn-8.0Al-1.2C (8Al and Fe-30.5Mn-2.1Al-1.2C (2Al (wt.% steels. They were rolled to a strain of ~0.70. Refinement of a crystallographic slip band substructure in low to medium rolling strain and nucleation of twins on the mature slip bands at a higher strain were suggested as deformation mechanisms in the 8Al steel. Mainly shear banding contributed to the formation of a Copper texture in such steel. Brass-texture development in the 2Al steel is mainly due to deformation twinning and shear banding formation. Detailed images of KAM maps showed that the stored deformation energy was mainly localized in the twinned areas and shear bands, which generated the inhomogeneous deformation microstructures in both steels at a higher strain. Goss and Brass texture intensity decreases and Cu-texture intensity increases as the Al wt.% increases in different cold rolled High-Mn (Mn ~30 wt.% steels.

  13. Thermal Analysis of Fluidized Bed and Fixed Bed Latent Heat Thermal Storage System

    Science.gov (United States)

    Beemkumar, N.; Karthikeyan, A.; Shiva Keshava Reddy, Kota; Rajesh, Kona; Anderson, A.

    2017-05-01

    Thermal energy storage technology is essential because its stores available energy at low cost. Objective of the work is to store the thermal energy in a most efficient method. This work is deal with thermal analysis of fluidized bed and fixed bed latent heat thermal storage (LHTS) system with different encapsulation materials (aluminium, brass and copper). D-Mannitol has been used as phase change material (PCM). Encapsulation material which is in orbicular shape with 4 inch diameter and 2 mm thickness orbicular shaped product is used. Therminol-66 is used as a heat transfer fluid (HTF). Arrangement of encapsulation material is done in two ways namely fluidized bed and fixed bed thermal storage system. Comparison was made between the performance of fixed bed and fluidized bed with different encapsulation material. It is observed that from the economical point of view aluminium in fluidized bed LHTS System has highest efficiency than copper and brass. The thermal energy storage system can be analyzed with fixed bed by varying mass flow rate of oil paves a way to find effective heat energy transfer.

  14. The σ phase formation in annealed UNS S31803 duplex stainless steel: Texture aspects

    International Nuclear Information System (INIS)

    Souza, C.M.; Abreu, H.F.G.; Tavares, S.S.M.; Rebello, J.M.A.

    2008-01-01

    The influence of sigma phase precipitation on the texture of austenite in a duplex stainless steel UNS S31803 was investigated. Sigma phase quantification was precisely performed by electron backscattered scanning diffraction (EBSD) for some conditions. It was found that the increase of the sigma phase precipitation enhances the amount of Brass texture in the austenite phase

  15. Commentary on "Research in Secondary English, 1912-2011: Historical Continuities and Discontinuities in the NCTE Imprint"

    Science.gov (United States)

    Hillocks, George, Jr.

    2011-01-01

    Jory Brass and Leslie David Burns provide a useful and informative review of research appearing in the "English Journal" ("EJ") and "Research in the Teaching of English" ("RTE") over the past 100 years. It is a bit unfortunate, if understandable, to exclude books and articles in other journals, because such a restriction excludes many pieces of…

  16. Low-Cost Timer to Measure the Terminal Velocity of a Magnet Falling through a Conducting Pipe

    Science.gov (United States)

    Pathare, Shirish R.; Huli, Saurabhee; Lahane, Rohan; Sawant, Sumedh

    2014-01-01

    Dropping a magnet into a conductive pipe (made up of copper or brass or aluminum) is a very popular demonstration in many physics classrooms and laboratories. In this paper we present an inexpensive timer that can be used to measure the terminal velocity of the magnet falling through a conducting pipe. The timer assembly consists of Hall effect…

  17. 46 CFR 105.35-15 - Fire hose.

    Science.gov (United States)

    2010-10-01

    ... bronze or equivalent metal. (e) All fittings on fire hose shall be of brass, copper, or other suitable corrosion resistant metal. (f) A length of fire hose shall be attached to each fire hydrant at all times... 46 Shipping 4 2010-10-01 2010-10-01 false Fire hose. 105.35-15 Section 105.35-15 Shipping COAST...

  18. Plaadid / Priit Hõbemägi

    Index Scriptorium Estoniae

    Hõbemägi, Priit, 1957-

    2006-01-01

    Uutest heliplaatidest Neil Siamond "12 Songs", The Bamboos "Step It Up", Van Morrison "Pay The Devil", Mystery Jets "Making Dens", In Extremo "Raue Spree 2005", "Bossa n' Marley", Liv Kristine "Enter My Religion", Ugly Ducling "Bang The Buck", "Big Boi Presents", Youngblood Brass Band "Is That A Riott", Tosca "Souvenirs", Azymuth "Pure", Eels "With Strings", "Metal For The Masses"

  19. 77 FR 32986 - Notice of Inventory Completion: The University of Alabama Museums, Tuscaloosa, AL

    Science.gov (United States)

    2012-06-04

    ... notice are the sole responsibility of the museum, institution, or Federal agency that has control of the... than 2,032 glass beads, 1 lot of more than 17 shell beads, 1 unidentified bead, 1 gun lock, 1 gun butt plate, 1 gun stock, 2 gun barrels, 1 brass ramrod support, 8 musket balls, 2 iron buckles, 1 iron handle...

  20. fireforce - one man's war in the rhodesian light infantry

    African Journals Online (AJOL)

    "They have the faces of boys but they fight like lions". The history of the Rhodesian Light Infantry is an illustrious one. The. RLI produced many of the senior brass who led the Rhodesian Army including Gen Peter Walls. It was arguably Rhodesia's premier fighting unit (if one excludes Rhodesia's two special forces outfits, the ...

  1. 24 CFR 3280.611 - Vents and venting.

    Science.gov (United States)

    2010-04-01

    ...) Materials—(1) Pipe. Vent piping shall be standard weight steel, wrought iron, brass, copper tube DWV, listed...) Size of vent piping—(1) Main vent. The drain piping for each toilet shall be vented by a 11/2 inch... venting cross section of a 11/2 inch diameter vent, connected to the toilet drain by one of the following...

  2. Design and construction of superconductor resonators

    International Nuclear Information System (INIS)

    Ben-Zvi, I.; Goliak, T.; Holmgren, D.W.; Storm, D.W.

    1984-01-01

    A low beta resonator was fabricated at the Nuclear Physics Laboratory, then plated and successfully tested at Stony Brook. The basic design is a quarter wave, cylindrical cavity excited by a magnetic coupling loop. Before the copper prototype was made the exact design parameters were measured by the construction and RF testing of a brass model

  3. Achieving uniform dose with the use of a custom tissue compensator and a leveled beam for tangential breast fields

    International Nuclear Information System (INIS)

    Asbury, L.; Luttrell, L.; Lake, D.

    1989-01-01

    In order to achieve uniform dose distribution in intact breast treatments, wedges can be employed. This paper will describe a custom compensator made from brass chips used in conjunction with a leveled beam and a custom cast to treat breast shapes that are less suited to a standard wedge set up. Materials and design, dosimetry, criteria, efficacy and results will be described

  4. 76 FR 73660 - Notice of Intent To Repatriate Cultural Items: U.S. Department of Defense, Army Corps of...

    Science.gov (United States)

    2011-11-29

    ... point, 1 preform, 3 stone cores, 5 brass tubes, 1 cap box, 1 ceramic pipe, 1 ceramic doll, 1 powder horn cap, 1 locket, 1 crucifix, 1 lamp wick holder, 2 marbles, 1 book, 1 lamp wick, 2 bottles, 3 spoons, 1... pendants, 3 lots of animal remains, 36 lots of stone flakes, 17 lots of metal fragments, 1 lot of wooden...

  5. CLASSICS UNITED STATES PATENT OFFICE

    Indian Academy of Sciences (India)

    IAS Admin

    From the profits, he became a very rich man and was able ... The Schedule referred to in these Letters Patent and making part of the same. TO ALL ... This is the real character and purpose of my invention; and in order to enable others ... kneading, it is rubbed through a hair, silk, or brass-wire sieve, (iron corrodes) and any.

  6. An experimental investigation of untriggered film boiling collapse

    International Nuclear Information System (INIS)

    Naylor, P.

    1985-03-01

    Film boiling has been investigated in a stagnant pool, using polished brass or anodised aluminium alloy rods in water. Experimental boiling curves were obtained, and pronounced ripples on the vapour/liquid interface were photographed. A criterion for untriggered film boiling collapse is proposed, consistent with experimental results. Application of the results to molten fuel coolant interaction studies is discussed. (U.K.)

  7. On the repetitive operation of a self-switched transversely excited ...

    Indian Academy of Sciences (India)

    tive 2 m concave gold-coated mirror and ~60% reflective ZnSe output coupler (6 m. ROC) forming an optical cavity of ~42 cm length. The pre-ionization chamber con- sisting of 13 pairs of brass pins interspaced at ~2 cm and placed on one side along the length of the electrodes at a distance of ~4.5 cm from the discharge ...

  8. An EBSD Investigation of Cryogenically-Rolled Cu-30%Zn Brass

    Science.gov (United States)

    2015-02-07

    a severely deformed dilute aluminium alloy , Acta Mater. 56 (2008) 1619–1632. http://dx.doi.org/10.1016/j.actamat.2007.12.017. [2] T. Konkova, S... alloys has given rise to considerable commercial interest in techniques for grain refinement. Of particular importance are cost effective methods that can...cryogenic working has focused on aluminum alloys and pure copper [e.g., 1 7]. In both materials, cryogenic rolling has been found to provide no

  9. Catching the Brass Ring: Oil Market Diversification Potential for Canada

    Directory of Open Access Journals (Sweden)

    Michal C. Moore

    2011-12-01

    Full Text Available This paper examines the nature and structure of the Canadian oil export market in the context of world prices for heavy crude oil and the potential price differential available to Canadian producers gaining access to new overseas markets. Success in this arena will allow Canada to reap incredible economic benefits. For example, the near term benefits for increased access to Gulf Coast markets after mid-continent bottlenecks are removed, are significant, representing nearly 10$ US per barrel for Canadian producers. On the Pacific Coast, the world market is represented by growing capacity for heavy crude products in emerging Asian markets including Japan, Korea and China and existing heavy crude facilities in California and the west coast. Here, in the reference scenario for California and Asia the benefits are assumed to begin in 2020. The differential value range in California in 2020 is estimated at $7.20US per barrel and escalates to $8.77US by 2030. In Asia, the benefit range is estimated to grow from $11.15US per barrel in 2020 to $13.60US in 2030. Those higher prices for Canadian heavy oil would translate into significant increases in profits, jobs and government revenues. With better access and new pipeline capacity, oil producers will see more efficient access to international markets which can add up to $131 billion to Canada’s GDP between 2016 and 2030 in the reference scenario. This amounts to over $27 billion in federal, provincial and municipal tax receipts, along with an estimated 649,000 person-years of employment. Alberta will be the principal but not sole beneficiary from increased access to world market pricing. Most provinces and territories will realize fiscal and economic gains from the distribution and sale of products reflecting reduced costs and increased access to refineries for heavy oil. The key to this change is the elimination of current bottlenecks in transport and the expansion of a network of pipelines that can move Canadian crude oil to locations reflecting minimal discounts from world market prices. As this paper demonstrates with hard facts and figures, the rewards are too great to ignore.

  10. Benzotriazole as an inhibitor of brass corrosion in chloride solution

    International Nuclear Information System (INIS)

    Kosec, Tadeja; Milosev, Ingrid; Pihlar, Boris

    2007-01-01

    The current research explores the formation of protective layers on copper, zinc and copper-zinc (Cu-10Zn and Cu-40Zn) alloys in chloride solution containing benzotriazole (BTAH), by use of electrochemical techniques, atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). Electrochemical reactions and surface products formed at the open circuit potential and as a function of the potential range are discussed. The addition of benzotriazole to aerated, near neutral 0.5 M NaCl solution affects the dissolution of copper, zinc, Cu-10Zn and Cu-40Zn alloys. The research also compares the inhibition efficiency and Gibbs adsorption energies of the investigated process. Benzotriazole, generally known as an inhibitor of copper corrosion is also shown to be an efficient inhibitor for copper-zinc alloys and zinc metal. The surface layer formed on alloys in BTAH-inhibited solution comprised both oxide and polymer components, namely Cu 2 O and ZnO oxides, and Cu(I)-BTA and Zn(II)-BTA polymers. The formation of this mixed copper-zinc oxide polymer surface film provides an effective barrier against corrosion of both metal components in chloride solution

  11. Band Structure and Fermi-Surface Properties of Ordered beta-Brass

    DEFF Research Database (Denmark)

    Skriver, Hans Lomholt; Christensen, N. E.

    1973-01-01

    , but that their position relative to the Fermi level is correct. The derived Fermi-surface model allows a detailed interpretation of the de Hass-van Alphen (dHvA) data. The present model has no open orbit along for B→∥ 〈110〉. This agrees with dHvA as well as magnetoresistance measurements. Four new extremal cross sections...

  12. New Numerical Solution of von Karman Equation of Lengthwise Rolling

    Directory of Open Access Journals (Sweden)

    Rudolf Pernis

    2015-01-01

    Full Text Available The calculation of average material contact pressure to rolls base on mathematical theory of rolling process given by Karman equation was solved by many authors. The solutions reported by authors are used simplifications for solution of Karman equation. The simplifications are based on two cases for approximation of the circular arch: (a by polygonal curve and (b by parabola. The contribution of the present paper for solution of two-dimensional differential equation of rolling is based on description of the circular arch by equation of a circle. The new term relative stress as nondimensional variable was defined. The result from derived mathematical models can be calculated following variables: normal contact stress distribution, front and back tensions, angle of neutral point, coefficient of the arm of rolling force, rolling force, and rolling torque during rolling process. Laboratory cold rolled experiment of CuZn30 brass material was performed. Work hardening during brass processing was calculated. Comparison of theoretical values of normal contact stress with values of normal contact stress obtained from cold rolling experiment was performed. The calculations were not concluded with roll flattening.

  13. New mechanical chemical equilibrium in the copper-zinc alloys obtained by mechanical alloying

    International Nuclear Information System (INIS)

    Dianez, M.J; Criado, J.M; Donoso, E; Diaz, G

    2006-01-01

    A series of copper zinc alloys have been synthesized in the entire composition range Cu10Zn to Cu70Zn respectively, by mechanical alloying at room temperature in a planetary high-energy mill. A mechanism is proposed for the mechanical alloying reaction of the copper and zinc. It is made clear that the mechanical treatment considerably extends the range of composition of the α phase up to a content of 41% zinc, instead of the 36% accepted by the conventional phase diagrams. Exact determinations of the phase α reticular parameter were carried out as a function of its composition which can be used to determine the zinc content of the brass α. The results show that a brass phase α may be obtained containing 49% zinc in samples that include a mixture of phases α and β' after reaching stationary state as a function of the milling time. The stability field of phases β' and γ also displace noticeably higher values than those expected from the conventional binary Cu-Zn diagram. This behavior has been explained as a function of the nanometric texture generated by the milling (CW)

  14. Microstructure and texture evolution in cryorolled Al 7075 alloy

    International Nuclear Information System (INIS)

    Jayaganthan, R.; Brokmeier, H.-G.; Schwebke, Bernd; Panigrahi, S.K.

    2010-01-01

    The present work investigates the microstructure and texture evolution of cryorolled Al 7075 alloy using FE-SEM, TEM, and neutron diffraction, respectively. The solution treated bulk Al 7075 alloy is subjected to rolling at liquid nitrogen temperature to produce sheets with different thickness reductions such as 35%, 50%, 70%, and 90%, respectively. It is evident from the microstructural characterisations of cryorolled samples that with the increasing deformation strain induced in the materials, the grains are fragmented and produce high amount of dislocation density due the suppression of dynamic recovery. The texture analysis of the cryorolled Al 7075 alloy has shown that the ideal fibres observed in the starting solution treated alloy has been destroyed during rolling. The Goss/Brass orientation of the cryorolled Al alloy is shifting towards the Brass components with increasing deformation strain induced in the samples. The orientation distribution functions of the cryorolled Al 7075 alloy clearly indicate the progressive weakening of the texture components, during cryorolling, with increasing strain, therefore, fragmentation and reorientation of micron sized grains occurs easily for the formation of subgrains and ultrafine-grained microstructures as evident from EBSD and TEM micrographs.

  15. Correlation between the thermal performance and the microstructure of the material used in medium and high voltage transformer terminals

    Science.gov (United States)

    Salas, Y. J.; Vera-Monroy, S. P.; Mejia-Camacho, A.; Rivera, W.

    2017-12-01

    In Colombia, energy companies neglect the distribution that represents the main and most valuable process, presenting shortcomings in prevention and forecasting programs, using contractors who perform corrective maintenance of the components without guaranteeing the quality and performance of the materials. Within the process, the terminals determine the effective connection between the voltage line and the transformer, which have faults that are evidenced by the thermal deterioration of the material. In this work, a diagnosis of the thermal performance of these components was carried out and it was correlated with the microstructure, observing variations of the working temperature, with a thermography camera, for three types of terminals, which were classified by X-ray fluorescence in brass Z20, Z40 and Z60, and for two types of connection, copper and aluminium. The microstructure results showed that copper is the conductor that degrades the terminals faster, evidencing cracking of the material; on the other hand, the Z40 brass was the most stable with the lowest temperature variation regardless of the conductor diameter; however, in all cases the behaviour of higher temperature to lower calibre is satisfied.

  16. Convenient telemetry system for precise and continuous measurement of groundwater level and temperature

    Energy Technology Data Exchange (ETDEWEB)

    Tsunakawa, Hideo; Asada, Toshi

    1988-03-25

    A telemeter system has been developed, a device easy to manufacture and install and which facilitates data collection and achieves a relative precision to at least 1 cm in underground water level and 5 m deg C in underground water temperature, thus contributing to earthquake prediction. Its underground water level sensor feeds as voltage the differential pressure of a membrane to which a semiconductor sensor chip is attached. The sensor uses a 12V DC power supply and achieves a sensitivity of 8 mV/cm to sense a 0-5 m water level change as a 1-5 V voltage fluctuation. This sensor is put into a 40 mm-diameter, 100 mm-long brass container and dipped in water at a depth of about 2.5 m. To detect underground water temperature sensor, a semiconductor sensor LM35 is placed in a 25 mm-diameter, 50 mm-long brass container and submerged at a desired depth. The system uses a 12-bit data logger. Telemetry takes place at 1,200 bps via modems and NTT's(Nippon Telegraph and Telecommunications) public telephone line. An example of measurement is shown and mentioned. (2 figs, 5 refs)

  17. Characterisation of an enamelled metallic object found in Guerrero Negro (Baja California) by PIXE and RBS techniques

    International Nuclear Information System (INIS)

    Calvo del Castillo, H.; Ruvalcaba, J.L.; Calderon, T.; Salinas Nolasco, M.F.; Mejia, L.M.; Perdigon, K.

    2008-01-01

    The coast of Guerrero Negro (Baja California) has been known for a long time by archaeologists for its shipwrecks. Archaeologists are recovering objects that come from sunken Spanish galleons in the colonial period, and reach the American coast in the frontier of the USA with Mexico. An enamelled metallic object was found next to the beach in Guerrero Negro. We have analysed the piece with proton induced X-ray emission (PIXE) and Rutherford backscattering (RBS) in an attempt to establish whether the object could come from one of the colonial shipwrecks and to valuate its cleaning process. Scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS) have been also performed in three samples taken from the object in order to observe the heterogeneity of the material. The materials found revealed the presence of typical lead-glass enamels from with pigments such as cuprite (red), or lead-tin yellow used in colonial times. The metallic part consisted of brass. As for the cleaning process, the average efficiency considered as the weight% of chlorine removed, was of 83.4% for brass and 100% for enamels

  18. Fouling research and cleaning effect by sponge ball on condencer tubes

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, S; Sano, A [Kansai Electric Power Co., Inc., Osaka (Japan); Minamoto, K; Mimura, K; Kyohara, S

    1978-07-01

    Systematic research has been performed to investigate the cleaning effect on condensers cooled by sea water. The test has been done for a year using the test condenser at the Kainan Power Station, Kansai Electric Power Company. The main purpose of this research was to see the effect of cleaning inner walls of condenser tubes with sponge balls on the prevention of adhesion of marine creatures such as barnacles and other shellfishes. As the test tubes, the aluminum-brass and titanium tubes with 25.4 mm diameter, 1.245 mm thickness and 170 mm length were used. Frequency of cleaning and flow rate were chosen as the variable parameters. The effect of seasons was also investigated. Major conclusions drawn from this research were as follows. (1) More adhesion of barnacles was observed at slower flow speed and in titanium tubes rather than aluminum brass tubes. (2) At the flow speed of 1 m/sec. cleaning frequency of more than twice a week was necessary to perfectly avoid the adhesion. (3) In summer, the adhesion was most intensive, whereas in winter, it was the least. (4) Barnacles were the most predominant organism. (5) Cleaning with sponge balls was effective.

  19. Characterisation of an enamelled metallic object found in Guerrero Negro (Baja California) by PIXE and RBS techniques

    Energy Technology Data Exchange (ETDEWEB)

    Calvo del Castillo, H. [Departamento de Geologia y Geoquimica, Universidad Autonoma de Madrid (Spain); Instituto de Fisica, Universidad Nacional Autonoma de Mexico (Mexico); Centre Europeen d' Archeometrie - I.P.N.A.S., Universite de Liege, Allee du 6 Aout, 10 Bat-15, Sart Tilman, 4000-Liege 1 (Belgium)], E-mail: hcalvo@ulg.ac.be; Ruvalcaba, J.L. [Instituto de Fisica, Universidad Nacional Autonoma de Mexico (Mexico); Calderon, T. [Departamento de Geologia y Geoquimica, Universidad Autonoma de Madrid (Spain); Salinas Nolasco, M.F. [Coordinacion de Conservacion del Patrimonio Cultural, Instituto Nacional de Antropologia e Historia (Mexico); Mejia, L.M. [Direccion de Arqueologia Subacuatica, Instituto Nacional de Antropologia e Historia (Mexico); Perdigon, K. [Coordinacion de Conservacion del Patrimonio Cultural, Instituto Nacional de Antropologia e Historia (Mexico)

    2008-05-15

    The coast of Guerrero Negro (Baja California) has been known for a long time by archaeologists for its shipwrecks. Archaeologists are recovering objects that come from sunken Spanish galleons in the colonial period, and reach the American coast in the frontier of the USA with Mexico. An enamelled metallic object was found next to the beach in Guerrero Negro. We have analysed the piece with proton induced X-ray emission (PIXE) and Rutherford backscattering (RBS) in an attempt to establish whether the object could come from one of the colonial shipwrecks and to valuate its cleaning process. Scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS) have been also performed in three samples taken from the object in order to observe the heterogeneity of the material. The materials found revealed the presence of typical lead-glass enamels from with pigments such as cuprite (red), or lead-tin yellow used in colonial times. The metallic part consisted of brass. As for the cleaning process, the average efficiency considered as the weight% of chlorine removed, was of 83.4% for brass and 100% for ename0008.

  20. Der slawische Anteil am Bestand des Blasmusikarchives der Universität für Musik und darstellende Kunst in Graz

    Directory of Open Access Journals (Sweden)

    Engelbert Logar

    2015-06-01

    Full Text Available The article examines the Slavic share of sheet music for brass instruments in the archive of the University of Music and Performing Arts Graz, located in the research station in Oberschützen in the Austrain state of Burgenland. The archive material is comprised of 4805 numbered maps with works and compositions of 2072 different composers – 10,632  formaly  defined works. It is intended for symphonic brass music, salon orchestra, string instruments and chambers ensembles and was collected during the 200 years of the performance practice of the institution. The focal point of the article is the south-Slavic region, although its share is relatively small compared to the Czech, Vienna or Hungarian region.  Discussed are over 200 composers that were mainly working in the time between 1850 and 1940. Over 1500 compositions are in the form of manuscripts. The  analysis  of  the temporal, spatial and formal layering of the material is followed by statistical data of the share of composers form Slovenia, Croatia, Bosnia and Herzegovina, Serbia and Bulgaria; incorporated in the overview is also the share of eastern and western Slavic countries.

  1. The Electrodeposition of Rhenium and Its Alloys

    Science.gov (United States)

    2015-09-18

    did not have benefit. A combination of vanillin, sodium lauryl sulfate, and gelatin , and equal concentrations of Ni2+ and ReO4 - yielded a coating...substrate, thus facilitating good bonding between the coating and substrate. Similar phenomenon would occur between a silver substrate and...electrodeposited metal coating. Historically, this is why most successful electroplating process used copper, brass (copper-zinc alloy), and silver as substrates

  2. Sound / Ülo Külm

    Index Scriptorium Estoniae

    Külm, Ülo

    1998-01-01

    Uutest plaatidest Uriah Heep "Sonic Origami", Amanda Lear "Follow Me Back In My Arms", No Mercy "More", Dr.Bombay "Rice & Curry", Vanilla Ice"Hard To Swallow", Orgy "Cancỳass", Bee Gees "One Night Only", PJ Harvey "Is This Desire", Mudhoney "Tomorrow Hit Today", Frank Sinatra "Sinatra And Swingin Brass", Kurupt "Kuruption!", Mike Scott & The Waterboys "The Whole Of The Moon", Dodgy "Ace As & Killer Bs"

  3. On-Line Monitoring and Diagnostics of the Integrity of Nuclear Plant Steam Generators and Heat Exchangers

    Energy Technology Data Exchange (ETDEWEB)

    Belle R. Upadhyaya; J. Wesley Hines

    2004-09-27

    Integrity monitoring and flaw diagnostics of flat beams and tubular structures was investigated in this research task using guided acoustic signals. A piezo-sensor suite was deployed to activate and collect Lamb wave signals that propagate along metallic specimens. The dispersion curves of Lamb waves along plate and tubular structures are generated through numerical analysis. Several advanced techniques were explored to extract representative features from acoustic time series. Among them, the Hilbert-Huang transform (HHT) is a recently developed technique for the analysis of non-linear and transient signals. A moving window method was introduced to generate the local peak characters from acoustic time series, and a zooming window technique was developed to localize the structural flaws. The time-frequency analysis and pattern recognition techniques were combined for classifying structural defects in brass tubes. Several types of flaws in brass tubes were tested, both in the air and in water. The techniques also proved to be effective under background/process noise. A detailed theoretical analysis of Lamb wave propagation was performed and simulations were carried out using the finite element software system ABAQUS. This analytical study confirmed the behavior of the acoustic signals acquired from the experimental studies. The report presents the background the analysis of acoustic signals acquired from piezo-electric transducers for structural defect monitoring. A comparison of the use of time-frequency techniques, including the Hilbert-Huang transform, is presented. The report presents the theoretical study of Lamb wave propagation in flat beams and tubular structures, and the need for mode separation in order to effectively perform defect diagnosis. The results of an extensive experimental study of detection, location, and isolation of structural defects in flat aluminum beams and brass tubes are presented. The results of this research show the feasibility of on

  4. On-Line Monitoring and Diagnostics of the Integrity of Nuclear Plant Steam Generators and Heat Exchangers

    International Nuclear Information System (INIS)

    Upadhyaya, Belle R.; Hines, J. Wesley

    2004-01-01

    Integrity monitoring and flaw diagnostics of flat beams and tubular structures was investigated in this research task using guided acoustic signals. A piezo-sensor suite was deployed to activate and collect Lamb wave signals that propagate along metallic specimens. The dispersion curves of Lamb waves along plate and tubular structures are generated through numerical analysis. Several advanced techniques were explored to extract representative features from acoustic time series. Among them, the Hilbert-Huang transform (HHT) is a recently developed technique for the analysis of non-linear and transient signals. A moving window method was introduced to generate the local peak characters from acoustic time series, and a zooming window technique was developed to localize the structural flaws. The time-frequency analysis and pattern recognition techniques were combined for classifying structural defects in brass tubes. Several types of flaws in brass tubes were tested, both in the air and in water. The techniques also proved to be effective under background/process noise. A detailed theoretical analysis of Lamb wave propagation was performed and simulations were carried out using the finite element software system ABAQUS. This analytical study confirmed the behavior of the acoustic signals acquired from the experimental studies. The report presents the background the analysis of acoustic signals acquired from piezo-electric transducers for structural defect monitoring. A comparison of the use of time-frequency techniques, including the Hilbert-Huang transform, is presented. The report presents the theoretical study of Lamb wave propagation in flat beams and tubular structures, and the need for mode separation in order to effectively perform defect diagnosis. The results of an extensive experimental study of detection, location, and isolation of structural defects in flat aluminum beams and brass tubes are presented. The results of this research show the feasibility of on

  5. Liquid sampling-atmospheric pressure glow discharge optical emission spectroscopy detection of laser ablation produced particles: A feasibility study

    International Nuclear Information System (INIS)

    Quarles, C. Derrick; Gonzalez, Jhanis; Choi, Inhee; Ruiz, Javier; Mao, Xianglei; Marcus, R. Kenneth; Russo, Richard E.

    2012-01-01

    The use of a liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma source as an alternative to conventional inductively coupled plasma (ICP) detection of laser ablation (LA) produced particles using a Nd:YAG laser at 1064 nm is demonstrated. This configuration utilizes a 180° geometry, which is different from the 40° geometry that was used to ionize ablated particles followed by mass spectrometric detection. The use of a hollow counter electrode (nickel, 0.3 cm o.d., 0.1 cm i.d.) was implemented to introduce ablated particles directly into the APGD plasma with helium as a carrier gas. The LS-APGD source was optimized using ablated copper as the test sample (helium carrier gas flow rate (0.30 L min −1 He), discharge current (60 mA), laser power (44 mJ), and solution electrode sheath gas (0.2 L min −1 He) and solution flow rates (10 μL min −1 5% HNO 3 )). Standard brass samples having known Zn/Cu percentages were ablated and analyzed using the LS-APGD source. As a comparison, the established technique of laser-induced breakdown spectroscopy (LIBS) was used to analyze the same set of brass standards under similar ablation conditions to the LS-AGPD measurements, yielding comparable results. The Zn/Cu ratio results for the LS-APGD and LIBS measurements showed good similarity to previous measurements using ICP-MS detection. The performance of the LS-APGD–OES microplasma, comparable to well established methods, with lower capital and operational overhead expenses, suggests a great deal of promise as an analytical excitation source. - Highlights: ► Particles formed by laser ablation are readily introduced to the LS-APGD microplasma. ► The low power microplasma has sufficient energy to vaporize laser produced particles. ► Qualitative analysis of brass alloys is performed using a simple OES ratio method. ► The qualitative performance of the LS-APGD microplasma is on-par with LIBS analysis.

  6. Development of a compact HTS lead unit for the SC correction coils of the SuperKEKB final focusing magnet system

    Energy Technology Data Exchange (ETDEWEB)

    Zong, Zhanguo, E-mail: zhanguo.zong@kek.jp; Ohuchi, Norihito; Tsuchiya, Kiyosumi; Arimoto, Yasushi

    2016-09-11

    Forty-three superconducting (SC) correction coils with maximum currents of about 60 A are installed in the SuperKEKB final focusing magnet system. Current leads to energize the SC correction coils should have an affordable heat load and fit the spatial constraints in the service cryostat where the current leads are installed. To address the requirements, design optimization of individual lead was performed with vapor cooled current lead made of a brass material, and a compact unit was designed to accommodate eight current leads together in order to be installed with one port in the service cryostat. The 2nd generation high temperature SC (HTS) tape was adopted and soldered at the cold end of the brass current lead to form a hybrid HTS lead structure. A prototype of the compact lead unit with HTS tape was constructed and tested with liquid helium (LHe) environment. This paper presents a cryogenic measurement system to simulate the real operation conditions in the service cryostat, and analysis of the experimental results. The measured results showed excellent agreement with the theoretical analysis and numerical simulation. In total, 11 sets of the compact HTS lead units were constructed for the 43 SC correction coils at KEK. One set from the mass production was tested in cryogenic conditions, and exhibited the same performance as the prototype. The compact HTS lead unit can feed currents to four SC correction coils simultaneously with the simple requirement of controlling and monitoring helium vapor flow, and has a heat load of about 0.762 L/h in terms of LHe consumption. - Highlights: • The requirements of the SC correction coils on current leads are introduced. • The optimum design of the brass vapor cooled current lead is described. • The compact structure of eight leads with HTS tape is presented. • The theoretical, numerical, and experimental results are compared. • The current lead heat load is evaluated for cryogenic system.

  7. Implementation of the European multicentre database of healthy controls for [{sup 123}I]FP-CIT SPECT increases diagnostic accuracy in patients with clinically uncertain parkinsonian syndromes

    Energy Technology Data Exchange (ETDEWEB)

    Albert, Nathalie L.; Unterrainer, Marcus; Xiong, Guoming; Bartenstein, Peter; Koch, Walter [University of Munich, Department of Nuclear Medicine, Munich (Germany); Diemling, Markus [Hermes Medical Solutions, Stockholm (Sweden); Varrone, Andrea [Karolinska University Hospital, Karolinska Institutet, Department of Clinical Neuroscience, Centre for Psychiatry Research, Stockholm (Sweden); Dickson, John C. [UCLH NHS Foundation Trust and University College, Institute of Nuclear Medicine, London (United Kingdom); Tossici-Bolt, Livia [University Hospitals Southampton NHS Trust, Department of Medical Physics, Southampton (United Kingdom); Sera, Terez [University of Szeged, Department of Nuclear Medicine and Euromedic Szeged, Szeged (Hungary); Asenbaum, Susanne [Medical University of Vienna, Department of Neurology, Vienna (Austria); Booij, Jan [University of Amsterdam, Department of Nuclear Medicine, Academic Medical Centre, Amsterdam (Netherlands); Kapucu, L. Oezlem A. [Gazi University, Department of Nuclear Medicine, Faculty of Medicine, Ankara (Turkey); Kluge, Andreas [ABX-CRO, Dresden (Germany); Ziebell, Morten [Rigshospitalet and University of Copenhagen, Neurobiology Research Unit, Copenhagen (Denmark); Darcourt, Jacques [University of Nice-Sophia Antipolis, Nuclear Medicine Department, Centre Antoine Lacassagne, Nice (France); Nobili, Flavio [University of Genoa, Clinical Neurology Unit, Department of Neuroscience (DINOGMI), Genoa (Italy); Pagani, Marco [Institute of Cognitive Sciences and Technologies, CNR, Rome (Italy); Karolinska Hospital, Department of Nuclear medicine, Stockholm (Sweden); Sabri, Osama [University of Leipzig, Department of Nuclear Medicine, Leipzig (Germany); Hesse, Swen [University of Leipzig, Department of Nuclear Medicine, Leipzig (Germany); Leipzig University Medical Centre, Molecular Neuroimaging IFB Adiposity Diseases, Leipzig (Germany); Borght, Thierry vander [Universite Catholique de Louvain, Nuclear Medicine Division, Mont-Godinne Medical Center, Yvoir (Belgium); Laere, Koen van [University Hospital and K.U. Leuven, Nuclear Medicine, Leuven (Belgium); Tatsch, Klaus [Staedtisches Klinikum Karlsruhe, Department of Nuclear Medicine, Karlsruhe (Germany); La Fougere, Christian [University of Tuebingen, Division of Nuclear Medicine, Department of Radiology, Tuebingen (Germany)

    2016-07-15

    Even though [{sup 123}I]FP-CIT SPECT provides high accuracy in detecting nigrostriatal cell loss in neurodegenerative parkinsonian syndromes (PS), some patients with an inconclusive diagnosis remain. We investigated whether the diagnostic accuracy in patients with clinically uncertain PS with previously inconclusive findings can be improved by the use of iterative reconstruction algorithms and an improved semiquantitative evaluation which additionally implemented a correction algorithm for patient age and gamma camera dependency (EARL-BRASS; Hermes Medical Solutions, Sweden). We identified 101 patients with inconclusive findings who underwent an [{sup 123}I]FP-CIT SPECT between 2003 and 2010 as part of the diagnostic process of suspected PS at the University of Munich, and re-evaluated these scans using iterative reconstruction algorithms and the new corrected EARL-BRASS. Clinical follow-up was obtained in 62 out of the 101 patients and constituted the gold standard for the re-evaluation to assess the possible improvement in diagnostic accuracy. Clinical follow-up confirmed the diagnosis of PS in 11 of the 62 patients. In patients in whom both visual and semiquantitative analysis showed concordant findings (48 patients), a high negative predictive value (93 %), positive predictive value (100 %) and accuracy (94 %) were found, and thus a correct diagnosis was obtained in 45 of the 48 patients. Among the 14 patients with discordant findings, the additional semiquantitative analysis correctly identified all five of nine patients patients without PS by nonpathological semiquantitative findings in visually pathological or inconclusive scans. In contrast, four of the remaining five patients with decreased semiquantitative values but visually normal scans did not show a PS during follow-up. The age-corrected and camera-corrected mode of evaluation using EARL-BRASS provided a notable improvement in the diagnostic accuracy of [{sup 123}I]FP-CIT SPECT in PS patients with

  8. Electron backscatter diffraction study of deformation and recrystallization textures of individual phases in a cross-rolled duplex steel

    Energy Technology Data Exchange (ETDEWEB)

    Zaid, Md; Bhattacharjee, P.P., E-mail: pinakib@iith.ac.in

    2014-10-15

    The evolution of microstructure and texture during cross-rolling and annealing was investigated by electron backscatter diffraction in a ferritic–austenitic duplex stainless steel. For this purpose an alloy with nearly equal volume fraction of the two phases was deformed by multi-pass cross-rolling process up to 90% reduction in thickness. The rolling and transverse directions were mutually interchanged in each pass by rotating the sample by 90° around the normal direction. In order to avoid deformation induced phase transformation and dynamic strain aging, the rolling was carried out at an optimized temperature of 898 K (625 °C) at the warm-deformation range. The microstructure after cross warm-rolling revealed a lamellar structure with alternate arrangement of the bands of two phases. Strong brass and rotated brass components were observed in austenite in the steel after processing by cross warm-rolling. The ferrite in the cross warm-rolling processed steel showed remarkably strong RD-fiber (RD//< 011 >) component (001)< 011 >. The development of texture in the two phases after processing by cross warm-rolling could be explained by the stability of the texture components. During isothermal annealing of the 90% cross warm-rolling processed material the lamellar morphology was retained before collapse of the lamellar structure to the mutual interpenetration of the phase bands. Ferrite showed recovery resulting in annealing texture similar to the deformation texture. In contrast, the austenite showed primary recrystallization without preferential orientation selection leading to the retention of deformation texture. The evolution of deformation and annealing texture in the two phases of the steel was independent of one another. - Highlights: • Effect of cross warm-rolling on texture formation is studied in duplex steel. • Brass texture in austenite and (001)<110 > in ferrite are developed. • Ferrite shows recovery during annealing retaining the (001

  9. Implementation of the European multicentre database of healthy controls for [123I]FP-CIT SPECT increases diagnostic accuracy in patients with clinically uncertain parkinsonian syndromes

    International Nuclear Information System (INIS)

    Albert, Nathalie L.; Unterrainer, Marcus; Xiong, Guoming; Bartenstein, Peter; Koch, Walter; Diemling, Markus; Varrone, Andrea; Dickson, John C.; Tossici-Bolt, Livia; Sera, Terez; Asenbaum, Susanne; Booij, Jan; Kapucu, L. Oezlem A.; Kluge, Andreas; Ziebell, Morten; Darcourt, Jacques; Nobili, Flavio; Pagani, Marco; Sabri, Osama; Hesse, Swen; Borght, Thierry vander; Laere, Koen van; Tatsch, Klaus; La Fougere, Christian

    2016-01-01

    Even though [ 123 I]FP-CIT SPECT provides high accuracy in detecting nigrostriatal cell loss in neurodegenerative parkinsonian syndromes (PS), some patients with an inconclusive diagnosis remain. We investigated whether the diagnostic accuracy in patients with clinically uncertain PS with previously inconclusive findings can be improved by the use of iterative reconstruction algorithms and an improved semiquantitative evaluation which additionally implemented a correction algorithm for patient age and gamma camera dependency (EARL-BRASS; Hermes Medical Solutions, Sweden). We identified 101 patients with inconclusive findings who underwent an [ 123 I]FP-CIT SPECT between 2003 and 2010 as part of the diagnostic process of suspected PS at the University of Munich, and re-evaluated these scans using iterative reconstruction algorithms and the new corrected EARL-BRASS. Clinical follow-up was obtained in 62 out of the 101 patients and constituted the gold standard for the re-evaluation to assess the possible improvement in diagnostic accuracy. Clinical follow-up confirmed the diagnosis of PS in 11 of the 62 patients. In patients in whom both visual and semiquantitative analysis showed concordant findings (48 patients), a high negative predictive value (93 %), positive predictive value (100 %) and accuracy (94 %) were found, and thus a correct diagnosis was obtained in 45 of the 48 patients. Among the 14 patients with discordant findings, the additional semiquantitative analysis correctly identified all five of nine patients patients without PS by nonpathological semiquantitative findings in visually pathological or inconclusive scans. In contrast, four of the remaining five patients with decreased semiquantitative values but visually normal scans did not show a PS during follow-up. The age-corrected and camera-corrected mode of evaluation using EARL-BRASS provided a notable improvement in the diagnostic accuracy of [ 123 I]FP-CIT SPECT in PS patients with previously

  10. Simultaneous delivery of electron beam therapy and ultrasound hyperthermia using scanning reflectors: a feasibility study

    International Nuclear Information System (INIS)

    Moros, Eduardo G.; Straube, William L.; Klein, Eric E.; Yousaf, Muhammed; Myerson, Robert J.

    1995-01-01

    Purpose: The feasibility of simultaneously delivering external electron beam radiation and superficial hyperthermia using a scanning ultrasound reflector-array system (SURAS) was experimentally investigated and demonstrated. Methods and Materials: A new system uses a scanning reflector to distribute the acoustic energy from a planar ultrasound array over the surface of the target volume. External photon/electron beams can be concurrently delivered with hyperthermia by irradiating through the scanning reflectors. That is, this system enables the acoustic waves and the radiation beams to enter the target volume from the same direction. Reflectors were constructed of air-equivalent materials for maximum acoustic reflection and minimum radiation attenuation. Acoustically, the air reflectors were compared to brass reflectors (assumed ideal) for reflectivity and specular quality using several single transducers ranging in frequency from 0.68 to 4.8 MHz. The relative reflectivity was determined from acoustic power measurements using a force-balance technique. The specular quality was assessed by comparing the acoustic pressure fields reflected by air reflectors with those reflected by brass reflectors. Also, acoustic pressure fields generated by a SURAS prototype for two different arrays (2.24 and 4.5 MHz) were measured to investigate field distribution variations as a function of the distance separating the array and the scanning reflector. All pressure fields were measured with a hydrophone in a degassed water tank. Finally, to determine the effect of the air reflectors on electron dose distributions, these were measured using film in a water-equivalent solid phantom after passage of a 20 MeV electron beam through the SURAS. These measurements were performed with the reflector scanning continuously across the electron beam and at rest within the electron beam. Results: The measurements performed using single ultrasound transducers showed that the air reflectors had

  11. Treatment of Partial Thickness Burns with a Novel Extracellular Matrix in Rats (Rattus norvegicus)

    Science.gov (United States)

    2016-12-20

    partial thickness burn was produced using a brass scale weight. Groups of 10 rats were randomly assigned to the various treatments . Jackets made from...Objectives: The objective this study was to examine the cellular and immune responses to various extracellular matrices (ECM) in a rat burn model...significant difference between treatments in terms of mean wound area (p = 0.77). Histologic examination revealed that all of the grafts were infected, with

  12. ADVANCEMENTS IN NEUTRON RADIOGRAPHY WITHIN THE DEPARTMENT OF THE ARMY

    Science.gov (United States)

    2016-11-01

    visual testing, acoustic emission, NR, and other specialized methods such as infrared or thermography. These inspection processes are used to...include: polyethylene, steel, rubber , brass, aluminum, and ceramic (from left to right). Figures 5a and 5b show visual images of both sides of the...Boroflex is a proprietary product of specialized flexible rubber sheets containing high amounts of boron-10. Most of this exterior material was put in

  13. Preliminary results from film boiling destabilisation experiments

    International Nuclear Information System (INIS)

    Naylor, P.

    1984-05-01

    A series of experiments to investigate the triggered destabilisation of film boiling has been undertaken. Film boiling was established on a polished brass rod immersed in water and the effects of various triggers were investigated. Preliminary results are presented and two thresholds have been observed: an impulse threshold below which triggered destabilisation will not occur and a thermal threshold above which film boiling will re-establish following triggered destabilisation. (author)

  14. The Integration of Minorities into Special Operations: How Cultural Diversity Enhances Operations

    Science.gov (United States)

    2014-03-01

    Darlene Marie Iskra. Breaking through the Brass Ceiling : Elite Military Women’s Strategies for Success ProQuest, 2007. Ethnic Majority. The Glass ...United States dates back to the American Revolution. Native Americans, African American slaves, immigrants and women made up a diverse group that...The 1 commission focused almost solely on a statistical comparison of service by white males and minorities, which included women , as opposed to

  15. Use of a Fabry-Perot resonator at millimeter wave frequencies in the determination of thin-film resistivities

    Energy Technology Data Exchange (ETDEWEB)

    Hogan, S. J.

    1979-08-01

    A novel contact-free method of measuring resistivity of thin semiconducting films on highly conductive substrates is described. The material structure studied is commonly encountered in thin-film solar cell development. The microwave technique that involves using a semiconfocal Fabry-Perot cavity at a wavelength of 3 mm is discussed in detail. The sample consists o a thin film of CdS on a brass substrate and is mounted on the flat reflector of the cavity. Using field perturbation methods, an expression is derived that relates the film resistivity to the cavity quality factor Q. The cavity quality factor is an easily measured parameter and, by comparing measurements of Q with and without the sample mounted, an accurate measure of the resistivity is obtained. Accuracy of measurements and necessary sample constraints are discussed in detail. Three samples of CdS were measured on brass substrates spanning an order of magnitude in resistivity difference. The results of the method described agree with those of another method that involves current voltage measurement after application of a metallic contact. Unlike the latter method, however, the new technique provides a nondestructive way of measuring the resistivity of semiconductor films on conducting substrates and is amenable to automation.

  16. Nanosecond laser textured superhydrophobic metallic surfaces and their chemical sensing applications

    Science.gov (United States)

    Ta, Duong V.; Dunn, Andrew; Wasley, Thomas J.; Kay, Robert W.; Stringer, Jonathan; Smith, Patrick J.; Connaughton, Colm; Shephard, Jonathan D.

    2015-12-01

    This work demonstrates superhydrophobic behavior on nanosecond laser patterned copper and brass surfaces. Compared with ultrafast laser systems previously used for such texturing, infrared nanosecond fiber lasers offer a lower cost and more robust system combined with potentially much higher processing rates. The wettability of the textured surfaces develops from hydrophilicity to superhydrophobicity over time when exposed to ambient conditions. The change in the wetting property is attributed to the partial deoxidation of oxides on the surface induced during laser texturing. Textures exhibiting steady state contact angles of up to ∼152° with contact angle hysteresis of around 3-4° have been achieved. Interestingly, the superhydrobobic surfaces have the self-cleaning ability and have potential for chemical sensing applications. The principle of these novel chemical sensors is based on the change in contact angle with the concentration of methanol in a solution. To demonstrate the principle of operation of such a sensor, it is found that the contact angle of methanol solution on the superhydrophobic surfaces exponentially decays with increasing concentration. A significant reduction, of 128°, in contact angle on superhydrophobic brass is observed, which is one order of magnitude greater than that for the untreated surface (12°), when percent composition of methanol reaches to 28%.

  17. Fouling research and cleaning effect by sponge ball on condencer tubes

    International Nuclear Information System (INIS)

    Matsumoto, Seizo; Sano, Akira; Minamoto, Kenju; Mimura, Keisuke; Kyohara, Shigeru.

    1978-01-01

    Systematic research has been performed to investigate the cleaning effect on condensers cooled by sea water. The test has been done for a year using the test condenser at the Kainan Power Station, Kansai Electric Power Company. The main purpose of this research was to see the effect of cleaning inner walls of condenser tubes with sponge balls on the prevention of adhesion of marine creatures such as barnacles and other shellfishes. As the test tubes, the aluminum-brass and titanium tubes with 25.4 mm diameter, 1.245 mm thickness and 170 mm length were used. Frequency of cleaning and flow rate were chosen as the variable parameters. The effect of seasons was also investigated. Major conclusions drawn from this research were as follows. (1) More adhesion of barnacles was observed at slower flow speed and in titanium tubes rather than aluminum brass tubes. (2) At the flow speed of 1 m/sec. cleaning frequency of more than twice a week was necessary to perfectly avoid the adhesion. (3) In summer, the adhesion was most intensive, whereas in winter, it was the least. (4) Barnacles were the most predominant organism. (5) Cleaning with sponge balls was effective. (Aoki, K.)

  18. The use of cutting temperature to evaluate the machinability of titanium alloys.

    Science.gov (United States)

    Kikuchi, Masafumi

    2009-02-01

    This study investigated the machinability of titanium, two commercial titanium alloys (Ti-6Al-4V and Ti-6Al-7Nb) and free-cutting brass using the cutting temperature. The cutting temperature was estimated by measuring the thermal electromotive force of the tool-workpiece thermocouple during cutting. The thermoelectric power of each metal relative to the tool had previously been determined. The metals were slotted using a milling machine and carbide square end mills under four cutting conditions. The cutting temperatures of Ti-6Al-4V and Ti-6Al-7Nb were significantly higher than that of the titanium, while that of the free-cutting brass was lower. This result coincided with the relationship of the magnitude of the cutting forces measured in a previous study. For each metal, the cutting temperature became higher when the depth of cut or the cutting speed and feed increased. The increase in the cutting speed and feed was more influential on the value than the increase in the depth of cut when two cutting conditions with the same removal rates were compared. The results demonstrated that cutting temperature measurement can be utilized to develop a new material for dental CAD/CAM applications and to optimize the cutting conditions.

  19. Corrosion tests in Baltic sea water on heat exchanger tubes of various metallic materials

    International Nuclear Information System (INIS)

    Henrikson, S.; Knutsson, L.

    1975-05-01

    Seventeen different tube materials have been exposed to continuous and intermittent flow in Baltic Sea water (0.4 % Cl - ) at 50 deg C for a maximum of 15 000 hours. During testing the specimens have been examined at certain intervals. After testing the specimens have been examined visually and metallographically. The following materials were completely resistant: titanium, CuNi30Mn1Fe, Alloy 825 and the austenitic steels Cr18Ni24Mo4.5, Cr20Ni25Mo4.5Cu and Cr24Ni24Mo2Ti. The ferritic-austenitic steels Cr18Ni5Mo2Si and Cr25Ni5Mo1.5 on the other hand, seem to be attacked by local intercrystalline corrosion in the vicinity of the welds. The same type of attack occurs, against expectations, even in the entirely ferritic steels, especially in Cr21Mo3Ti; this attack was however shown to be caused by surface carburization. Admiralty brass (2.5 m/s), aluminium brass (3.0 m/s) and CuNi10Fe1Mn (3.5 m/s) have been attacked by erosion corrosion. The same type of attack, although to a considerably smaller extent, has also been observed for the three aluminium materials (2.5 m/s). (author)

  20. Semi-quantitative evaluation of texture components and anisotropy of the yield strength in 2524 T3 alloy sheets

    International Nuclear Information System (INIS)

    Shen, Fanghua; Yi, Danqing; Wang, Bin; Liu, Huiqun; Jiang, Yong; Tang, Cong; Jiang, Bo

    2016-01-01

    Decreasing the anisotropy of 2524 alloys is a key factor for their use in applications such as high-performance inertial components or space robots. Studying the interaction between sheet textures and anisotropy is a key factor to overcome this problem. In this study, the semi-quantitative approach to estimate the relation between texture and in-plane anisotropy (IPA) of yield strength has been developed. The intensity ratio between Cube and Brass texture components (F CGB ) was used as an effective variable for this purpose. This approach has been tested in 2524 T3 aluminum alloy sheets, which were investigated using X-Ray diffraction, scanning electron microscopy, optical microscopy and tensile tests. The results show that F CGB decreased with an increase in cold reduction. The 2524 T3 sheet, dominated by Cube texture grains, possesses the lowest in-plane anisotropy for the yield strength of all texture components investigated. The alloy sheet dominated by Brass texture exhibits the highest anisotropy, while the Goss texture-led sheets fall in between them. These results agree with the trends seen in the factor F CGB , suggesting that is suited to evaluate the anisotropy of yield strength in 2524 T3 alloy sheets semi-quantitatively.

  1. Semi-quantitative evaluation of texture components and anisotropy of the yield strength in 2524 T3 alloy sheets

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Fanghua [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Yi, Danqing, E-mail: yioffice@csu.edu.cn [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Light Alloy Research Institute, Central South University, Changsha, Hunan 410083 (China); National Collaborative Innovation Center of Advanced Nonferrous Structural Materials and Manufacturing, Central South University, Changsha 410083 (China); Wang, Bin; Liu, Huiqun; Jiang, Yong; Tang, Cong; Jiang, Bo [School of Materials Science and Engineering, Central South University, Changsha 410083 (China)

    2016-10-15

    Decreasing the anisotropy of 2524 alloys is a key factor for their use in applications such as high-performance inertial components or space robots. Studying the interaction between sheet textures and anisotropy is a key factor to overcome this problem. In this study, the semi-quantitative approach to estimate the relation between texture and in-plane anisotropy (IPA) of yield strength has been developed. The intensity ratio between Cube and Brass texture components (F{sub CGB}) was used as an effective variable for this purpose. This approach has been tested in 2524 T3 aluminum alloy sheets, which were investigated using X-Ray diffraction, scanning electron microscopy, optical microscopy and tensile tests. The results show that F{sub CGB} decreased with an increase in cold reduction. The 2524 T3 sheet, dominated by Cube texture grains, possesses the lowest in-plane anisotropy for the yield strength of all texture components investigated. The alloy sheet dominated by Brass texture exhibits the highest anisotropy, while the Goss texture-led sheets fall in between them. These results agree with the trends seen in the factor F{sub CGB}, suggesting that is suited to evaluate the anisotropy of yield strength in 2524 T3 alloy sheets semi-quantitatively.

  2. EXAMINATION OF THE OXIDATION PROTECTION OF ZINC COATINGS FORMED ON COPPER ALLOYS AND STEEL SUBSTRATES

    International Nuclear Information System (INIS)

    Papazoglou, M.; Chaliampalias, D.; Vourlias, G.; Pavlidou, E.; Stergioudis, G.; Skolianos, S.

    2010-01-01

    The exposure of metallic components at aggressive high temperature environments, usually limit their usage at similar application because they suffer from severe oxidation attack. Copper alloys are used in a wide range of high-quality indoor and outdoor applications, statue parts, art hardware, high strength and high thermal conductivity applications. On the other hand, steel is commonly used as mechanical part of industrial set outs or in the construction sector due to its high mechanical properties. The aim of the present work is the examination of the oxidation resistance of pack cementation zinc coatings deposited on copper, leaded brass and steel substrates at elevated temperature conditions. Furthermore, an effort made to make a long-term evaluation of the coated samples durability. The oxidation results showed that bare substrates appear to have undergone severe damage comparing with the coated ones. Furthermore, the mass gain of the uncoated samples was higher than this of the zinc covered ones. Particularly zinc coated brass was found to be more resistant to oxidation conditions in which it was exposed as it has the lower mass gain as compared to the bare substrates and zinc coated copper. Zinc coated steel was also proved to be more resistive than the uncoated steel.

  3. Sessile Drop Evaporation and Leidenfrost Phenomenon

    OpenAIRE

    A. K. Mozumder; M. R. Ullah; A. Hossain; M. A. Islam

    2010-01-01

    Problem statement: Quenching and cooling are important process in manufacturing industry for controlling the mechanical properties of materials, where evaporation is a vital mode of heat transfer. Approach: This study experimentally investigated the evaporation of sessile drop for four different heated surfaces of Aluminum, Brass, Copper and Mild steel with a combination of four different liquids as Methanol, Ethanol, Water and NaCl solution. The time of evaporation for the droplet on the hot...

  4. Demonstration of Lightweight Engineering Solutions for a Low-Cost Safe Explosive Ordnance Destruct Tool

    Science.gov (United States)

    2007-12-01

    Staff) and Mr. Doug Learned ( Intercity Manufacturing), whose efficiency and expertise was vital in manufacturing the parts required for our tests...detonation products caused by the hollow cavity. Upon initiation of a hollow lined charge, the resulting high pressure shock wave travels outward...5.6 km/s for the brass encased charge at 2 and 3 CD. This indicates that the jet must be traveling at velocities greater than the estimates, which

  5. Heavy metal pollution and soil enzymatic activity

    Energy Technology Data Exchange (ETDEWEB)

    Tyler, G

    1974-01-01

    The activity of hydrolytic soil enzymes was studied on spruce mor, polluted with Cu and Zn from a brass foundry in Sweden. Approximately straight regression lines were obtained between enzymatic activity or respiration rate and log Cu + Zn concentration, with highly significant negative regression coefficients for urease and acid phosphatase activity as well as respiration rate, whereas US -glucosidase activity was not measurably lower at high concentrations of Cu + Zn. 17 references, 5 figures.

  6. The Fate of Malathion on Copper and Iron Piping Within a Water Distribution System

    Science.gov (United States)

    2015-03-26

    application in biological, polymers and plastics , explosive, inorganic compounds as well as metal and alloy research (Dodd & Tonge, 1987). There are...submerged in a dielectric fluid [i.e. water] prior to the EDM sending an electrically charged brass wire over the sample. The wire disintegrated the...period, the coupon samples were removed from the glass vial, placed on a plastic sample holder, and allowed to dry in the desiccator for a four-hour

  7. CRREL (Cold Regions Research and Engineering Laboratory) Technical Publications. Supplement

    Science.gov (United States)

    1986-09-01

    Utilization for Fresh Water Production, ROAD. CHIMCAL COMPOSITION OF DUST nical memorandum~ Mar. 1976, No. 116, Muske Re- Weather Modilicationt, and...it appeared in a J-9 core Commes a i elon teo kEvromna 516 on an unusual boundary layer showing in th core andaa PV.e sEvromns assessment of the...AN ELON - TRA, REFLECOTIVTY, TEMPERATURE PF- NIP 1855 GATED, UNIAXIAL BRASS ICE STRESS SEN* FECTS, MATHEMATICAL MODELS. DETERMINING THE CHARACTERISTIC

  8. Iron, brass and burial, the Kapsiki blacksmith and his many crafts

    NARCIS (Netherlands)

    Beek, van W.E.A.; Moñino, Y.

    1991-01-01

    Sommaire: Avant-propos (D. Barreteau, H. Tourneux) - Discours d'ouverture (A. Marliac) - Introduction (Y. Moñino) - Observations sur le nom du fer et de la forge dans le bassin du lac Tchad (H. Tourneux) - Les migrations des forgerons djorok chez les Massa du Cameroun (J. Pahai) - Les Murgur, ou

  9. Toxicity and Fate Comparison between Several Brass and Titanium Dioxide Powders

    Science.gov (United States)

    1993-07-01

    the entire gut without showing any apparent effects . 14. UBJET TEMS1I. NUMBER OF PAGES 27 Daphnia Algae EC50 Aquatic toxicity 11T.PRICE CODE 9...levels of soluble copper and zinc in solution. 3. RESULTS The titanium dioxide ( TiO2 ) materials did not show any apparent toxic effects to daphnia up to...The extended exposure did not show any apparent toxic effects . Long term effects on aquatic org.rnisms exposed to TiO2 are not known. It is apparent

  10. A Practice Indexes for Improving Facial Movements of Brass Instrument Players

    Science.gov (United States)

    Ito, Kyoko; Hirano, Takeshi; Noto, Kazufumi; Nishida, Shogo; Ohtsuki, Tatsuyuki

    Two experimental studies have been conducted in order to propose practice indexes for the improvement of the embouchure of French horn players, two experimental studies have been conducted. In both studies, the same task was performed by advanced and amateur French horn players. The first study investigated the activity, while performing the above-mentioned task, of the 5 facial muscles (levator labii superioris, zygomaticus major, depressor anguli oris, depressor labii inferioris, and risorius muscles) on the right side of the face by surface electromyography, and the facial movement on the left side of the face by attaching two markers above each muscle and using two high-speed cameras simultaneously. The results of the study showed that it is possible for the four markers around the lower lip to practice indexes. The second study evaluated whether the above-mentioned markers are appropriate as practice indexes using a 3-D tracking system and questionnaires. The results showed that both the advanced and the amateur players assessed that the markers were suitable as practice indexes for improving the embouchure. This set of approaches could be useful for selecting practice indexes and developing scientific practice methods not only for the French horn but also for other instruments and other fields.

  11. Cold rolled texture and microstructure in types 304 and 316L austenitic stainless steels

    International Nuclear Information System (INIS)

    Wasnik, D.N.; Samajdar, I.; Gopalakrishnan, I.K.; Yakhmi, J.V.; Kain, V.

    2003-01-01

    Two grades of austenitic stainless steel (ASS), types 304 (UNS S 30400) and 316L (UNS S 31603), were cold rolled to different reductions by unidirectional and by cross-rolling. The steels had reasonable difference in stacking fault energy (estimated respectively as 15 and 61 mJ/m 2 in types 304 and 316L) and also in starting (or pre-deformation) crystallographic texture-being relatively weak and reasonably strong in types 304 and 316L respectively. The cold rolling increased texturing in type 304, but not in type 316L ASS. The more significant effect of cold rolled texture development was in the relative increase of Brass ({011} ) against Copper ({112} ) and S ({231} ) orientations. In type 304 the increase in Brass was significant, while in type 316L the increase in Copper and S was stronger. This effect could be captured by Taylor type deformation texture simulations considering stronger twinning contributions in type 304 - for example the respective 'best-fits' (in terms of matching the changes in the volume fractions of Brass against Copper and S) were obtained by full constraint Taylor model with 1:100 and 1:10 slip:twin activities in types 304 and 316L ASS respectively. Microstructural developments during cold rolling were generalized as strain induced martensite formation and developments of dislocation substructure. The former, as estimated by vibrating sample magnetometer (VSM), increased with cold reduction, being significantly more in type 304 and was also noticeably stronger in both grades under cross-rolling. The most significant aspect of substructural developments was the formation of strain localizations. These were observed as dense dislocation walls (DDWs), micro-bands (MBs) and twin lamellar structures (TLS). The TLS contribution gained significance at higher reductions and during cross-rolling, especially in type 304. Large misorientation development and the accompanying grain splittings were always associated with such strain localizations

  12. Growth of Legionella anisa in a model drinking water system to evaluate different shower outlets and the impact of cast iron rust.

    Science.gov (United States)

    van der Lugt, Wilco; Euser, Sjoerd M; Bruin, Jacob P; Den Boer, Jeroen W; Walker, Jimmy T; Crespi, Sebastian

    2017-11-01

    Legionella continues to be a problem in water systems. This study investigated the influence of different shower mixer faucets, and the influence of the presence of cast iron rust from a drinking water system on the growth of Legionella. The research is conducted using a model of a household containing four drinking water systems. All four systems, which contained standard plumbing components including copper pipes and a water heater, were filled with unchlorinated drinking water. Furthermore, all systems had three different shower faucets: (A) a stainless-steel faucet, (B) a brass-ceramic faucet, and (C) a brass thermostatic faucet. System 1 was solely filled with drinking water. System 2 was filled with drinking water, and cast iron rust. System 3 was contaminated with Legionella, and system 4 was contaminated with a Legionella, and cast iron rust. During a period of 34 months, 450 cold water samples were taken from 15 sample points of the four drinking water systems, and tested for Legionella according to the Dutch Standard (NEN 6265). In system 4, with added cast iron rust, the stainless-steel mixer faucet (A) had the highest concentration of Legionella at >4.3log10CFU/l (>20,000CFU/l) and was positive in 46.4% of samples. In contrast, the stainless-steel mixer faucet (A) of system 3 without cast iron rust showed 14.3% positive samples with a maximum concentration of 3.9log10CFU/l (7600CFU/l) Legionella. Additionally, both contaminated systems (3 and 4), with the brass thermostatic faucet (C), tested positive for Legionella. System 3 in 85.7% of the samples, with a maximum concentration of 4.38log10CFU/l (24,200CFU/l), and system 4 in 64.3% of the samples with a maximum concentration of 4.13log10CFU/l (13.400CFU/l). These results suggest that both the type of faucet used in a drinking water system and the presence or absence of cast iron rust influence the growth of Legionella. Copyright © 2017 Elsevier GmbH. All rights reserved.

  13. Development of Goss texture in Al–0.3%Cu annealed after heavy rolling

    DEFF Research Database (Denmark)

    Shuai, L. F.; Huang, T. L.; Wu, G. L.

    2018-01-01

    The evolution of the microstructure and texture during annealing has been studied in the center layer of 95% cold rolled Al–0.3%Cu with a large initial grain size. The cold-rolled condition is characterized by a strong Brass texture component and a deformed microstructure comprising lamellar stru...... grain size of Goss-oriented grains and strengthening of the Goss texture. As a result, new low angle boundaries are formed between Goss-oriented grains in this strongly textured material....

  14. Defense Standardization Program Journal. April/June 2011

    Science.gov (United States)

    2011-06-01

    years, the seven winners have played an integral part in keeping our men and women in uniform sate and in providing them the tools they need to get...supporting our men and women in uniform, helping to multiply capability through interoperability, and saving money tor the taxpayer. 1 hope that reading...committee chair of ASTM B687, "Standard Specifi- cation for Brass, Copper, and Chromium-Plated Pipe Nipples " (FSC 4730), to incor- porate eight additional

  15. Description of the manufacture of a Geiger-Muller counter with window

    International Nuclear Information System (INIS)

    Granados, C. E.

    1959-01-01

    Total details about the manufacture elements in counter fabrication and the way of obtention are described as well as total indications useful in the installation process and filling of the counter. The appropriate materials and precautions that might be adopted in order to obtain counters with uniform operation and good characteristics, are described. Counters are of brass, with thin mica or aluminium windows and operate at 1100 V approximately with a slope lower than 5 % 1100 V. (Author)

  16. Osmanlı Mühür Sanatı Ve Klasik Türk Şiirinde Mühür
    The Ottoman Art Of Seals And Seals In The Classical Turkish Poetry

    OpenAIRE

    Semra TUNÇ; Emine YENİTERZİ

    2013-01-01

    Seals are inscriptions, coats of arms or stamps and theirtypography engraved on hard substances in place of signatures. Havingbeen used in Mesopotamia, Egypt, Iran and Anatolia throughouthistory, seals have been engraved on minerals such as silver, brass,iron, bronze and notably gold, or gems such as emerald, amethyst,onyx, turquoise, pebble, garnet, cornelian, and pearl. The inscriptionson seals were engraved in reverse order so that they could be correctlyread when they were put on paper an...

  17. The Disorderly, Undisciplined State of the Good Order and Discipline Term

    Science.gov (United States)

    2016-02-16

    Command and Staff College. He holds a juris doctorate from Case Western Reserve University School of Law. iv Abstract Good order and... segregation was essential to “harmony and efficiency aboard ship.” The brass took the same view of admitting women to the service academies. In 1974, Lt...in the same document as “racial,” “ gender ,” “homosexual” or “military justice” revealed 1,705 responsive documents out of the original 2,883

  18. Top-down modulation of motor priming by belief about animacy

    OpenAIRE

    Liepelt, R.; Brass, M.

    2010-01-01

    There is recent evidence that we directly map observed actions of other agents onto our own motor repertoire, referred to as direct matching (Iacoboni et al., 1999). This was shown when we are actively engaged in joint action with others' (Sebanz et al. 2003) and also when observing irrelevant movements while executing congruent or incongruent movements ( Brass et al., 2000). However, an open question is whether direct matching in human beings is limited to the perception of intentional agent...

  19. Climate Change, State Stability, and Political Risk in Africa

    Science.gov (United States)

    2016-09-30

    www.acq.osd.mil/dsb/reports/ADA552760.pdf. iii P.P. Hearn Jr. et al., “Global GIS Database; Digital Atlas of Africa,” USGS Numbered Series, Data...Series, (2001), http://pubs.er.usgs.gov/publication/ds62B. iv U.S. Geological Survey World Conventional Resources Assessment Team, “USGS Digital ...Retrenchment and the Exercise of Citizenship in Africa,” Comparative Political Studies 44, 9 (2011): 1238-1266; Jennifer N. Brass, “Blurring Boundaries

  20. Flotation atomic absorption determination of bismuth in nonferrous metal alloys

    International Nuclear Information System (INIS)

    Ososkov, V.K.; Plintus, A.M.; Kornelli, M.Eh.; Zakhariya, A.N.; Lozanova, E.V.

    1986-01-01

    Technique of flotation concentration and atomic absorption determination of bismuth microquantities in alloys on the basis of copper and zinc has been developed. Fine-dispersed EhDEh-10P anionite was used as a carrier in flotation concentration. State standard samples (SSS) of brasses and German silver were used as analysed objects. Effect of macrocomponents on the results of bismuth content determination has been studied. Satisfactory coincidence of the results obtained and SSS certificates is shown

  1. Description of the manufacture of a Geiger-Muller counter with window; Descripcion de la fabricacion de un contador Geiger-Muller con ventana

    Energy Technology Data Exchange (ETDEWEB)

    Granados, C E

    1959-07-01

    Total details about the manufacture elements in counter fabrication and the way of obtention are described as well as total indications useful in the installation process and filling of the counter. The appropriate materials and precautions that might be adopted in order to obtain counters with uniform operation and good characteristics, are described. Counters are of brass, with thin mica or aluminium windows and operate at 1100 V approximately with a slope lower than 5 % 1100 V. (Author)

  2. Identification of temperature-dependent thermal conductivity and experimental verification

    International Nuclear Information System (INIS)

    Pan, Weizhen; Yi, Fajun; Zhu, Yanwei; Meng, Songhe

    2016-01-01

    A modified Levenberg–Marquardt method (LMM) for the identification of temperature-dependent thermal conductivity is proposed; the experiment and structure of the specimen for identification are also designed. The temperature-dependent thermal conductivities of copper C10200 and brass C28000 are identified to verify the effectiveness of the proposed identification method. The comparison between identified results and the measured data of laser flash diffusivity apparatus indicates the fine consistency and potential usage of the proposed method. (paper)

  3. Methods for tube attachment in a heat exchange equipment

    International Nuclear Information System (INIS)

    Shilin, O.V.; Vasil'ev, V.B.

    1984-01-01

    Two main ways of attaching tubes to tube panels in heat exchange equipment are analyzed: expanding and pulse method (by explosion, for instance). Labour-consumption and cost price for the fastening of brass, perlitic and corrosion-resistant tubes for both of the methods are presented. The extent of fitting out with equipment for tube fixing and ways of testing the joints for attachment are evaluated. Measures for improving the joint quality and introduction of the advanced technology are suggested

  4. The Center is Everywhere

    OpenAIRE

    Weinberg, David H.

    2012-01-01

    "The Center is Everywhere" is a sculpture by Josiah McElheny, currently (through October 14, 2012) on exhibit at the Institute of Contemporary Art, Boston. The sculpture is based on data from the Sloan Digital Sky Survey (SDSS), using hundreds of glass crystals and lamps suspended from brass rods to represent the three-dimensional structure mapped by the SDSS through one of its 2000+ spectroscopic plugplates. This article describes the scientific ideas behind this sculpture, emphasizing the p...

  5. K.S. Micro-Implant Placement Guide

    OpenAIRE

    Sharma, K; Sangwan, A

    2014-01-01

    A one of the greatest concerns with orthodontic mini-implants is risk of injury to dental roots during placement is, especially when they are inserted between teeth. Many techniques have been used to facilitate safe placement of interradicular miniscrews. Brass Wires or metallic markers are easy to place in the interproximal spaces, but because their relative positions may be inconsistent in different radio -graphic views, they are not always accurate. K.S. micro implant placement guide sugge...

  6. Innovations in microspore embryogenesis in Indonesian hot pepper (Capsicum annuum L.) and Brassica napus L.

    OpenAIRE

    Supena, E.D.J.

    2004-01-01

    Hot pepper (Capsicum annuumL.) is the most important vegetable inIndonesia, but the yield is low, and the breeding programs are confined to the conventional methods and not efficient. To improve the efficiency of the breeding programs by speeding up the production of homozygous lines, studies were aimed at the introduction of haploid technology, which includes the regeneration and the production of doubled haploid plants from gametes. This technique is well developed in the model speciesBrass...

  7. TEORIA DE BILL MUNDY Y EL ANGULO EFECTIVO DE ATAQUE DE HERRAMIENTAS DE CORTE EN ALEACIONES DE COBRE

    OpenAIRE

    Godoy R, Juan Miguel; Vergara D, Jorge; Oviedo O, Percy; Quispe Y, Martín; Gallardo M, Edward; Ramírez H, Leandro

    2007-01-01

    Magazines like American Machinist and Manufacturing Engineering, have explained the Bill Mundy theory about the effective rake angle of cutting tools. These articles show the effective rake angle of cutting tools for carbon steel, steel , alloys, cast iron, aluminium and stainless steel. In the present work the theory is applied to cutting tools used in brass and bronze. The effective rake angle for these materials was obtained with the tensile stress test. The rake angles in the cutting tool...

  8. Effect of strain path on microstructure, deformation texture and mechanical properties of nano/ultrafine grained AA1050 processed by accumulative roll bonding (ARB)

    Energy Technology Data Exchange (ETDEWEB)

    Naseri, M.; Reihanian, M. [Department of Materials Science and Engineering, Faculty of Engineering, Shahid Chamran University of Ahvaz, Ahvaz (Iran, Islamic Republic of); Borhani, E., E-mail: e.borhani@semnan.ac.ir [Department of Nano Technology, Nano Materials Group, Semnan University, Semnan (Iran, Islamic Republic of)

    2016-09-15

    Commercial pure Al sheets were severe plastically deformed at room temperature by accumulative roll bonding (ARB) and cross accumulative roll bonding (CARB). Change in strain path was imposed during CARB by rotating the sheets with 90° around the normal direction axis between each cycle. Microstructural evolution of processed sheets was studied by electron back scattered diffraction (EBSD) analysis and revealed that nano/ultrafine grains (NG/UFG) with the average grain size of 380 nm and 155 nm were formed by both processing routes after eight cycles, respectively. The fraction of high angle grain boundaries and mean misorientation angle of the boundaries in the CARB were 49% and 40.20°, respectively, in comparison to that of ARB sample (41% and 37.37°). Deformation texture evolution demonstrated that the change in strain path leads to the formation of strong orientation along the β-fiber. The major texture components for ARB specimens were Brass {011}<211> and S {123}<634> while those for CARB were Brass {011}<211> and Goss {011}<100>. The CARB processed specimen exhibited the tensile strength, microhardness and elongation of about 230 MPa, 92 HV and 13% compared with ARB sample (180 MPa, 80 HV and 10.5%) after eight cycles. Scanning electron microscopy (SEM) observations of tensile fracture surface of specimens revealed ductile type fracture.

  9. The effect of pouring time on the dimensional accuracy of casts made from different irreversible hydrocolloid impression materials

    Directory of Open Access Journals (Sweden)

    Supneet Singh Wadhwa

    2013-01-01

    Full Text Available Aims and Objectives: To determine the time dependent accuracy of casts made from three different irreversible hydrocolloids. Materials and Methods: The effect of delayed pouring on the accuracy of three different irreversible hydrocolloid impression materials - Regular set CA 37(Cavex, The Netherlands, regular set chromatic (Jeltrate, Dentsply, and fast set (Hydrogum soft, Zhermack Clinical was investigated. A brass master die that contained two identical posts simulating two complete crown-tapered abutment preparations with reference grooves served as a standardized master model. A total of 120 impressions were made using specially prepared stock-perforated brass tray with 40 impressions of each material. The impressions were further sub-grouped according to four different storage time intervals: 0 min (immediately, 12 min, 30 min, and 1 h. The impressions were stored at room temperature in a zip-lock plastic bag. Interabutment and intraabutment distances were measured in the recovered stone dies (Type IV, Kalrock using a profile projector with an accuracy of 0.001 mm. The data so obtained was analyzed statistically. Results: Results of this study showed no statistically significant differences in the accuracy of casts obtained at different time intervals. Conclusion: Because it is not always possible to pour the impression immediately in routine clinical practice, all irreversible hydrocolloid materials studied could be stored in a zip-lock plastic bag for upto 1 h without any significant distortion.

  10. PHYTOAVAILABILITY OF COPPER IN INDUSTRIAL BY-PRODUCTS AND MINERAL FERTILIZERS

    Directory of Open Access Journals (Sweden)

    Camila Prado Cenciani de Souza

    2015-04-01

    Full Text Available Alternative copper (Cu sources could be used in fertilizer production, although the bioavailability of copper in these materials is unknown. The objective of this study was to evaluate the extractants neutral ammonium citrate (NAC, 2 % citric acid, 1 % acetic acid, 10 % HCl, 10 % H2SO4, buffer solution pH 6.0, DTPA, EDTA, water, and hot water in the quantification of available Cu content in several sources, relating them to the relative agronomic efficiency (RAE of wheat grown in a clayey Latossolo Vermelho eutrófico (Oxisol and Neossolo Quartzarênico (Typic Quartzipsamment. Copper was applied at the rate of 1.5 mg kg-1 as scrap slag, brass slag, Cu ore, granulated copper, and copper sulfate. The extractants 10 % HCl, 10 % H2SO4, and NAC extracted higher Cu concentrations. The RAE values of brass slag and Cu ore were similar to or higher than those of Cu sulfate and granulated Cu. Solubility in the 2nd NAC extractant, officially required for mineral fertilizers with Cu, was lower than 60 % for the scrap slag, Cu ore, and granulated copper sources. This fact indicates that adoption of the NAC extractant may be ineffective for industrial by-products, although no extractant was more efficient in predicting Cu availability for wheat fertilized with the Cu sources tested.

  11. Experimental study of the thermal stability of hydrocarbon fuels

    Science.gov (United States)

    Marteney, P. J.; Colket, M. B.; Vranos, A.

    1982-01-01

    The thermal stability of two hydrocarbon fuels (premium diesel and regular diesel) was determined in a flow reactor under conditions representing operation of an aircraft gas turbine engine. Temperature was varied from 300 to 750 F (422 to 672 K) for fuel flows of 2.84 to 56.8 liters/hr (corresponding to 6.84 x 0.00010 to 1.63 x 0.010 kg/sec for regular diesel fuel and 6.55 x 0.00010 to 1.37 x 0.010 kg/sec for premium diesel fuel); test times varied between 1 and 8 hr. The rate of deposition was obtained through measurement of weight gained by metal discs fixed along the channel wall. The rate of deposit formation is best correlated by an Arrhenius expression. The sample discs in the flow reactor were varied among stainless steel, aluminum and brass; fuels were doped with quinoline, indole, and benzoyl perioxide to yield nitrogen or oxygen concentrations of approximately 1000 ppm. The most substantial change in rate was an increase in deposits for brass discs; other disc materials or the additives caused only small perturbations. Tests were also conducted in a static reactor at temperatures of 300 to 800 F for times of 30 min to 2 1/2 hr. Much smaller deposition was found, indicating the importance of fluid transport in the mechanism.

  12. Water chemistry in PWR

    International Nuclear Information System (INIS)

    Abe, Kenji

    1987-01-01

    This article outlines major features and basic concept of the secondary system of PWR's and water properties control measures adopted in recent PWR plants. The secondary system of a PWR consists of a condenser cooling pipe (aluminum-brass, titanium, or stainless steel), low-pressure make-up water heating pipe (aluminum-brass or stainless steel), high-ressure make-up water heating pipe (cupro-nickel or stainless steel), steam generator heat-transfer pipe (Inconel 600 or 690), and bleed/drain pipe (carbon steel, low alloy steel or stainless steel). Other major pipes and equipment are made of carbon steel or stainless steel. Major troubles likely to be caused by water in the secondary system include reduction in wall thickness of the heat-transfer pipe, stress corrosion cracking in the heat-transfer pipe, and denting. All of these are caused by local corrosion due to concentration of purities contained in water. For controlling the water properties in the secondary system, it is necessary to prevent impurities from entering the system, to remove impurities and corrosion products from the system, and to prevent corrosion of apparatus making up the system. Measures widely adopted for controlling the formation of IGA include the addition of boric acid for decreasing the concentration of free alkali and high hydrazine operation for providing a highly reducing atmospere. (Nogami, K.)

  13. Mental Health Risk Factors for Suicides in the US Army, 2007-8

    Science.gov (United States)

    2012-03-07

    Levin A. Military brass address suicide crisis and strategies to cure it. Psychiatr News 2009;44:10. 6. Black SA, ed. Brief to the U.S. Army Suicide... schizophrenia . Br J Psychiatry 2000;177:212e17. 19. Conner KR, Cox C, Duberstein PR, et al. Violence, alcohol, and completed suicide: a caseecontrol...study. Am J Psychiatry 2001;158:1701e5. 20. de Hert M, Peuskens J. Psychiatric aspects of suicidal behaviour: schizophrenia . In: Hawton K, Van Heerigen K

  14. Israel: Background and U.S. Relations

    Science.gov (United States)

    2012-02-29

    Israel would eventually be “wiped off the map,” and he has described the Holocaust as a “myth” used as a pretext to create an “ artificial Zionist...smuggling into Gaza and continue to limit passenger traffic at the Rafah crossing. Even after 2011-2012 elections, the power structure and...rls/rm/176684.htm. 102 Barbara Opall -Rome, “Israeli Brass Decry U.S. Arms Sales to Arab States,” Defense News, January 23, 2012. According to this

  15. An in-line clean system for the solid-phase extraction of emerging contaminants in natural waters

    OpenAIRE

    Sodré, Fernando F.; Locatelli, Marco Antonio F.; Jardim, Wilson F.

    2010-01-01

    A solid-phase in-line extraction system for water samples containing low levels of emerging contaminants is described. The system was specially developed for large volume samples (up to 4 L) using commercial solid-phase extraction (SPE) cartridges. Four sets containing PTFE-made connectors, brass adapters and ball valves were used to fit SPE cartridges and sample bottles to a 4-port manifold attached to a 20 L carboy. A lab-made vacuum device was connected to the manifold cap. The apparatus i...

  16. Strength of Screw Propellers

    Science.gov (United States)

    1975-07-07

    ship because of increese of propeller efficiency and saving on the high cost of difficult to obtain materials (bronze, brass, stainless steel). The...indAjate that. x :axmuin stresses in the blade cross section are the cor-,prc-.,; ivFe norm-al strcs3es at point G. The maximom tensile stres-ses cis a...and stern part of the ship. Because of purely technical difficulties and also because of the relatively high cost of preparations for such tests, only

  17. Sistema limpo em linha para extração em fase sólida de contaminantes emergentes em águas naturais

    OpenAIRE

    Sodré,Fernando F.; Locatelli,Marco Antonio F.; Jardim,Wilson F.

    2010-01-01

    A solid-phase in-line extraction system for water samples containing low levels of emerging contaminants is described. The system was specially developed for large volume samples (up to 4 L) using commercial solid-phase extraction (SPE) cartridges. Four sets containing PTFE-made connectors, brass adapters and ball valves were used to fit SPE cartridges and sample bottles to a 4-port manifold attached to a 20 L carboy. A lab-made vacuum device was connected to the manifold cap. The apparatus i...

  18. Crack Initiation and Growth Behavior at Corrosion Pit in 7075-T6 High Strength Aluminum Alloy

    Science.gov (United States)

    2013-06-01

    brass, etc.) have a very small impact in the aerospace industry. In other words, their usage is limited in aerospace systems, which at present are...rolling direction of the material has a profound impact on the growth of the pits. The pits have anisotropy and the largest dimension occurs along the...referred to as H13 . This is a specimen that was previously prepared by Sabelkin. Table 3.3: Specifications for the uni-axial test specimens. ∆K values are

  19. Determination of mercury in sectioned hair samples of Tycho Brahe by RNAA and μ-PIXE methods, and assay of Apertura piriformis bones by INAA method

    International Nuclear Information System (INIS)

    Kucera, Jan; Kamenik, Jan; Havranek, Vladimir

    2014-01-01

    Theories exist saying that the world-renowned Renaissance astronomer Tycho Brahe died of mercury intoxication. Brahe's grave was reopened in 2010 and new samples of his hair, beard-hair, and bones were taken and analysed. Evidence obtained by us suggests that Brahe was not administered lethal doses of mercury and that neither acute nor chronic mercury poisoning was the cause of his death. The INAA results of A piriformis suggest that his nasal prosthesis was most likely made of brass

  20. America Makes: National Additive Manufacturing Innovation Institute (NAMII) Project 1: Nondestructive Evaluation (NDE) of Complex Metallic Additive Manufactured (AM) Structures

    Science.gov (United States)

    2014-06-01

    advanced algorithms is:  Two 6-core CPUs (Intel Xeon X5650, 2.67 GHz)  72 GB RAM  Two 448-core GPUs ( NVIDIA Tesla M2070, 6 GB RAM)  2...Produktionstechnik und Automatisierung, Nobelstraße 12, 70569 Stuttgart, Germany, pp 1-11 , 2013 [40] General Electric Company , “Jet Engine Bracket from...GPU Using Nvidia CUDA”, Damien Vintache, Bernard Humbert, David Brasse, TSINGHUA SCIENCE AND TECHNOLOGY, ISSNl l1007-0214l l02/20l lpp11-16,Volume

  1. Do green manures as winter cover crops impact the weediness and crop yield in an organic crop rotation?

    OpenAIRE

    Madsen, Helena; Talgre, Liina; Eremeev, Viacheslav; Alaru, Maarika; Kauer, Karin; Luik, Anne

    2016-01-01

    The effects of different winter cover crops and their combination with composted cattle manure on weeds and crop yields were investigated within a five-field crop rotation (barley undersown with red clover, red clover, winter wheat, pea, potato) in three organic cropping systems. The control system (Org 0) followed the rotation. In organic systems Org I and Org II the winter cover crops were used as follows: ryegrass (Lolium perenne L. in 2011/2012) and a mixture of winter oilseed-rape (Brass...

  2. Radioactive contamination of natural and artificial materials

    International Nuclear Information System (INIS)

    Kovalchuk, E.L.; Pomansky, A.A.; Smolnikov, A.A.; Temmoev, A.H.

    1980-01-01

    The gamma radiation of different materials was measured in an underground low-background chamber with extraordinary background characteristics. The excellent background conditions of the measurements enabled investigators to see the alpha-particle peaks of the internal radioactive contamination of NaI(Tl) detectors, which were especially made for these measurements. The sensitivity limit of the installation was determined by the internal contamination of the NaI(Tl) detectors alone. Any radiation background, except for three substances, tungsten, copper, and brass, could be registered

  3. Methodology for fabrication of hydraulics mini turbines with composite materials; Metodologia para a fabricacao de mini turbinas hidraulicas com materiais compostos

    Energy Technology Data Exchange (ETDEWEB)

    Faria, M.T.C. [Universidade Federal de Minas Gerais (DEMEC/UFMG), Belo Horizonte, MG (Brazil). Dept. de Engenharia Mecanica], Email: mtcdf@uol.com.br; Martinez, C.B.; Viana, E.M.F. [Universidade Federal de Minas Gerais (EHR-UFMG), Belo Horizonte, MG (Brazil). Escola de Engenharia. Dept. de Engenharia Hidraulica e Recursos Hidricos], Emails: martinez@cce.ufmg.br, ednamariafaria@bol.com.br

    2009-07-01

    This paper presents the description of methodological procedure specially developed for manufacturing mini turbines. This procedure is used in the design of a Francis type mini turbine with 12.5 kW. The housing volute and the suction tube of this equipment are manufactured with using composed material based on glass fiber and its distributor system is manufactured with stainless steel and brass. At the end it is presented an estimate cost of design / manufacturing of such equipment and a comparison with other equipment in the market.

  4. Structure and chemical composition changes of Pd-rod and reaction product collector irradiated by 10 MeV braking gamma quanta inside high pressure chamber filled with 2.5 kbar molecular hydrogen

    International Nuclear Information System (INIS)

    Didyk, A.Yu.; Wisniewski, R.

    2013-01-01

    A research of the elemental composition and surface structure of a Pd rod saturated with hydrogen and a brass collector of nuclear and chemical reaction products irradiated by 10 MeV braking gamma quanta in dense molecular hydrogen gas at 2.5 kbar pressure is carried out. The changes of the elemental composition and surface structure of the Pd rod and collector similar to analogous changes in the experiment carried out in dense gas deuterium are observed. Possible explanations of the firstly observed phenomenon are offered

  5. Design and construction of two phases flow meter

    International Nuclear Information System (INIS)

    Nor Paiza Mohamad Hasan

    2002-01-01

    This paper deals with design of the gamma ray correlometer and flow loop system for measuring the velocity between two parallel cross-sections of a pipeline. In the laboratory, the radioisotope source and detector were collimated by brass with small beam slit respectively. The flow loop system consists of transparent pipeline, adjustable frequency pump and water container. As a result, when the construction of the flow loop and correlometer is completed, the velocity of two phases flow can be measured by the cross-correlation techniques. (Author)

  6. Study of electron beam effects on surfaces using x-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS)

    International Nuclear Information System (INIS)

    Gettings, M.; Coad, J.P.

    1976-02-01

    Discrepancies in the surface analyses of oxidised or heavily contaminated materials have been observed between X-ray Photoelectron Spectroscopy (XPS) and techniques using electron beams (primarily Auger Electron Spectroscopy (AES)). These discrepancies can be ascribed to the influence of the primary electron beam and to illustrate the various types of electron effects different materials were analysed using XPS and Secondary Ion Mass Spectroscopy (SIMS) before and after large area electron bombardment. The materials used included chrome and stainless steels, nickel, platinum, glass and brass. (author)

  7. Testing and Measurement Techniques in Heat Transfer and Combustion.

    Science.gov (United States)

    1980-09-01

    fine brass gauze, which have initially been heated or cooled by passing air through copper spiral coils immersed in a bath of heated oil or alcohol and...par l’analyseur peut Ctre interpr~t~e soit cornie 6tant celle r~ellement presente dans la flamme, sojt canine r~sultant d’une oxydation de NO syant...pr~l ,vement et analyse provient d’one oxydation de NO en proportion variltle suivant le type de sonde utilis6. De plus ii apparalt que cette

  8. Production of a large, quiescent, magnetized plasma

    Science.gov (United States)

    Landt, D. L.; Ajmera, R. C.

    1976-01-01

    An experimental device is described which produces a large homogeneous quiescent magnetized plasma. In this device, the plasma is created in an evacuated brass cylinder by ionizing collisions between electrons emitted from a large-diameter electron gun and argon atoms in the chamber. Typical experimentally measured values of the electron temperature and density are presented which were obtained with a glass-insulated planar Langmuir probe. It is noted that the present device facilitates the study of phenomena such as waves and diffusion in magnetized plasmas.

  9. Investigation of the diffusion {proportional_to} brasses using methods depending on the evaporation or condensation of zinc; Etude de la diffusion dans les laitons {proportional_to} au moyen des methodes d'evaporation ou de condensation du zinc

    Energy Technology Data Exchange (ETDEWEB)

    Accary, A [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Centre d' Etudes de Chimie Metallurgique du CNRS (France)

    1959-07-01

    Diffusion in {alpha} brasses has been investigated using methods involving the evaporation and the condensation of zinc. Having shown that at sufficiently high temperatures intergranular diffusion has no effect, it was then proved that the rate of evaporation or of condensation can only be defined if the mechanical treatment of the test piece before diffusion, the direction of the diffusion and the nature of the impurities present are also defined. The coefficient of diffusion D is then given by the equation D ({pi}/4t){rho}{sup 2}{sub 0} where t is the duration of the diffusion; {rho}{sub 0} is the extrapolated value of {rho} = ({delta}m)/({delta}C) for a zero value of the variation of concentration ({delta}m in is the change in weight of the test piece per unit surface; {delta}C is the difference between the concentration at the surface and the initial concentration of the test piece). This method has been used to study the effect of the direction of the diffusion on the coefficient of diffusion. The coefficient for diffusion which decreases the concentration of zinc is 5 times greater than that for diffusion which increases the quantity of zinc in the metal; an interpretation of this phenomena based on the mechanism of diffusion vacancies in the structure has been proposed. By means of micrographic investigation and by weighing it has been shown that the presence of certain impurities, such as phosphorous, arsenic, antimony, silicon, and aluminium can result in a marked increase of the rate of diffusion: the effect of these impurities on the coefficient of diffusion has been related to their valency and atomic weight. (author) [French] La diffusion dans les laitons {alpha} a ete etudiee au moyen des methodes d'evaporation et de condensafion du zinc. Apres avoir montre qu'aux temperatures suffisamment elevees, la diffusion intergranulaire ne jouait aucun role, l'auteur a prouve que la vitesse d'evaporation ou de condensation n'est definie que dans la mesure ou

  10. Texture Analysis using The Neutron Diffraction Method on The Non Standardized Austenitic Steel Process by Machining,Annealing, and Rolling

    Directory of Open Access Journals (Sweden)

    Tri Hardi Priyanto

    2016-04-01

    Full Text Available Austenitic steel is one type of stainless steel which is widely used in the industry. Many studies on  austenitic stainless steel have been performed to determine the physicalproperties using various types of equipment and methods. In this study, the neutron diffraction method is used to characterize the materials which have been made from  minerals extracted from the mines in Indonesia. The materials consist of a granular ferro-scrap, nickel, ferro-chrome, ferro-manganese, and ferro-silicon added with a little titanium. Characterization of the materials was carried out in threeprocesses, namely: machining, annealing, and rolling. Experimental results obtained from the machining process generally produces a texture in the 〈100〉direction. From the machining to annealing process, the texture index decreases from 3.0164 to 2.434.Texture strength in the machining process (BA2N sample is  8.13 mrd and it then decreases to 6.99 in the annealing process (A2DO sample. In the annealing process the three-component texture appears, cube-on-edge type texture{110}〈001〉, cube-type texture {001}〈100〉, and brass-type {110}〈112〉. The texture is very strong leading to the direction of orientation {100}〈001〉, while the {011}〈100〉is weaker than that of the {001}, and texture withorientation {110}〈112〉is weak. In the annealing process stress release occurred, and this was shown by more randomly pole compared to stress release by the machining process. In the rolling process a brass-type texture{110}〈112〉with a spread towards the goss-type texture {110}〈001〉 appeared,  and  the  brass  component  is markedly  reinforced  compared  to  the undeformed state (before rolling. Moreover, the presence of an additional {110} component was observed at the center of the (110 pole figure. The pole density of three components increases withthe increasing degree of thickness reduction. By increasing degrees

  11. Peach Bottom Atomic Power Station recirc pipe dose rates with zinc injection and condenser replacement

    International Nuclear Information System (INIS)

    DiCello, D.C.; Odell, A.D.; Jackson, T.J.

    1995-01-01

    Peach Bottom Atomic Power Station (PBAPS) is located near the town of Delta, Pennsylvania, on the west bank of the Susquehanna River. It is situated approximately 20 miles south of Lancaster, Pennsylvania. The site contains two boiling water reactors of General Electric design and each rated at 3,293 megawatts thermal. The units are BWR 4s and went commercial in 1977. There is also a decommissioned high temperature gas-cooled reactor on site, Unit 1. PBAPS Unit 2 recirc pipe was replaced in 1985 and Unit 3 recirc pipes replaced in 1988 with 326 NGSS. The Unit 2 replacement pipe was electropolished, and the Unit 3 pipe was electropolished and passivated. The Unit 2 brass condenser was replaced with a Titanium condenser in the first quarter of 1991, and the Unit 3 condenser was replaced in the fourth quarter of 1991. The admiralty brass condensers were the source of natural zinc in both units. Zinc injection was initiated in Unit 2 in May 1991, and in Unit 3 in May 1992. Contact dose rate measurements were made in standard locations on the 28-inch recirc suction and discharge lines to determine the effectiveness of zinc injection and to monitor radiation build-up in the pipe. Additionally, HPGe gamma scans were performed to determine the isotopic composition of the oxide layer inside the pipe. In particular, the specific (μCi/cm 2 ) of Co-60 and Zn-65 were analyzed

  12. A comparative evaluation of linear dimensional accuracy of the dies obtained using three conceptually different die systems in the fabrication of implant prosthesis: An in vitro study

    Directory of Open Access Journals (Sweden)

    Manawar Ahmad

    2014-01-01

    Purpose: The purpose of the study was to evaluate the linear dimensional accuracy between the implant master die and three conceptually different die systems such as Pindex system, Accu-trac precision die system, and Conventional brass dowel pin system. Materials and Methods: Thirty impressions of implant master die were made with polyether impression material. Ten experimental implant casts were fabricated for each of the three different die systems tested: Accu-trac precision die tray system, Pindex system, and conventional brass dowel pin system. The solid experimental casts were sectioned and then removed from the die system 30 times. Linear distances between all six possible distances were measured from one centre of the transfer coping to the other, using a co-ordinate measuring machine in millimeters up to accuracy of 0.5 microns. Data were tabulated and statistically analyzed by Binomial non parametric test using SPSS version 15. Results: Significant differences were found for distance A-B (P = 0.002, A-C ( P = 0.002, A-D (P value = 0.002, and B-D ( P = 0.021 in Conventional Dowel pin system however for Accu-trac precision die tray system, it was significant only for distance A-D (P = 0.002 but for Pindex system it was non-significant for all the distances measured. Conclusion: Within the limitations of this study, use of Pindex system is recommended when sectioned dies are needed for a multi implant retained prosthesis.

  13. Electron backscatter and X-ray diffraction studies on the deformation and annealing textures of austenitic stainless steel 310S

    Energy Technology Data Exchange (ETDEWEB)

    Nezakat, Majid, E-mail: majid.nezakat@usask.ca [Canadian Light Source Inc., 44 Innovation Boulevard, Saskatoon, SK, S7N 2V3 (Canada); Akhiani, Hamed [Westpower Equipment Ltd., 4451 54 Avenue South East, Calgary, AB T2C 2A2 (Canada); Sabet, Seyed Morteza [Department of Ocean and Mechanical Engineering, Florida Atlantic University, Boca Raton, FL 33431 (United States); Szpunar, Jerzy [Department of Mechanical Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, SK, S7N 5A9 (Canada)

    2017-01-15

    We studied the texture evolution of thermo-mechanically processed austenitic stainless steel 310S. This alloy was cold rolled up to 90% reduction in thickness and subsequently annealed at 1050 °C. At the early stages of deformation, strain-induced martensite was formed from deformed austenite. By increasing the deformation level, slip mechanism was found to be insufficient to accommodate higher deformation strains. Our results demonstrated that twinning is the dominant deformation mechanism at higher deformation levels. Results also showed that cold rolling in unidirectional and cross rolling modes results in Goss/Brass and Brass dominant textures in deformed samples, respectively. Similar texture components are observed after annealing. Thus, the annealing texture was greatly affected by texture of the deformed parent phase and martensite did not contribute as it showed an athermal reversion during annealing. Results also showed that when the fraction of martensite exceeds a critical point, its grain boundaries impeded the movement of austenite grain boundaries during annealing. As a result, recrystallization incubation time would increase. This caused an incomplete recrystallization of highly deformed samples, which led to a rational drop in the intensity of the texture components. - Highlights: •Thermo-mechanical processing through different cold rolling modes can induce different textures. •Martensite reversion is athermal during annealing. •Higher fraction of deformation-induced martensite can increase the annealing time required for complete recrystallization. •Annealing texture is mainly influenced by the deformation texture of austenite.

  14. Design and assembly technology for the thermal insulation of the W7-X cryostat

    Energy Technology Data Exchange (ETDEWEB)

    Risse, K., E-mail: konrad.risse@ipp.mpg.de [Max-Planck-Institut fuer Plasmaphysik (IPP), Euratom Association, Wendelsteinstrasse 1, D-17491 Greifswald (Germany); Nagel, M.; Pietsch, M.; Braatz, A. [Max-Planck-Institut fuer Plasmaphysik (IPP), Euratom Association, Wendelsteinstrasse 1, D-17491 Greifswald (Germany); Binni, A. [MAN Diesel and Turbo SE, Dpt. OSA, Werftstrasse 17, D-94469 Deggendorf (Germany); Posselt, H. [Linde AG Engineering Div., Dr.-Carl-von-Linde-Strasse 6-14, D-82049 Hoellriegelskreuth (Germany)

    2011-10-15

    The Max-Planck-Institut fuer Plasmaphysik in Greifswald is building up the stellarator fusion experiment Wendelstein 7-X (W7-X). To operate the superconducting magnet system the vacuum and the cold structures are protected by a thermal insulated cryostat. The plasma vessel forms the inner cryostat wall, the outer wall is realised by a thermal insulated outer vessel. In addition 254 thermal insulated ports are fed through the cryogenic vacuum to allow the access to the plasma vessel for heating systems, supply lines or plasma diagnostics. The thermal insulation is being manufactured and assembled by MAN Diesel and Turbo SE (Germany). It consists of a multi-layer insulation (MLI) made of aluminized Kapton with a silk like fibreglass spacer and a thermal shield covering the inner cryostat surfaces. The shield on the plasma vessel is made of fibreglass reinforced epoxy resin with integrated copper meshes. The outer vessel insulation is made of brass panels with an average size of 3.3 x 2.0 m{sup 2}. Cooling loops made of stainless steel are connected via copper strips to the brass panels. Especially the complex 3 D shape of the plasma vessel, the restricted space inside the cryostat and the consideration of the operational component movements influenced the design work heavily. The manufacturing and the assembly has to fulfil stringent geometrical tolerances e.g. for the outer vessel panels +3/-2 mm.

  15. Design and assembly technology for the thermal insulation of the W7-X cryostat

    International Nuclear Information System (INIS)

    Risse, K.; Nagel, M.; Pietsch, M.; Braatz, A.; Binni, A.; Posselt, H.

    2011-01-01

    The Max-Planck-Institut fuer Plasmaphysik in Greifswald is building up the stellarator fusion experiment Wendelstein 7-X (W7-X). To operate the superconducting magnet system the vacuum and the cold structures are protected by a thermal insulated cryostat. The plasma vessel forms the inner cryostat wall, the outer wall is realised by a thermal insulated outer vessel. In addition 254 thermal insulated ports are fed through the cryogenic vacuum to allow the access to the plasma vessel for heating systems, supply lines or plasma diagnostics. The thermal insulation is being manufactured and assembled by MAN Diesel and Turbo SE (Germany). It consists of a multi-layer insulation (MLI) made of aluminized Kapton with a silk like fibreglass spacer and a thermal shield covering the inner cryostat surfaces. The shield on the plasma vessel is made of fibreglass reinforced epoxy resin with integrated copper meshes. The outer vessel insulation is made of brass panels with an average size of 3.3 x 2.0 m 2 . Cooling loops made of stainless steel are connected via copper strips to the brass panels. Especially the complex 3 D shape of the plasma vessel, the restricted space inside the cryostat and the consideration of the operational component movements influenced the design work heavily. The manufacturing and the assembly has to fulfil stringent geometrical tolerances e.g. for the outer vessel panels +3/-2 mm.

  16. Strategies to Reduce Tin and Other Metals in Electronic Cigarette Aerosol.

    Directory of Open Access Journals (Sweden)

    Monique Williams

    Full Text Available Metals are present in electronic cigarette (EC fluid and aerosol and may present health risks to users.The objective of this study was to measure the amounts of tin, copper, zinc, silver, nickel and chromium in the aerosol from four brands of EC and to identify the sources of these metals by examining the elemental composition of the atomizer components.Four brands of popular EC were dissected and the cartomizers were examined microscopically. Elemental composition of cartomizer components was determined using integrated energy dispersive X-ray microanalysis, and the concentrations of the tin, copper, zinc silver, nickel, and chromium in the aerosol were determined for each brand using inductively coupled plasma optical emission spectroscopy.All filaments were made of nickel and chromium. Thick wires were copper coated with either tin or silver. Wires were joined to each other by tin solder, brazing, or by brass clamps. High concentrations of tin were detected in the aerosol when tin solder joints were friable. Tin coating on copper wires also contributed to tin in the aerosol.Tin concentrations in EC aerosols varied both within and between brands. Tin in aerosol was reduced by coating the thick wire with silver rather than tin, placing stable tin solder joints outside the atomizing chamber, joining wires with brass clamps or by brazing rather than soldering wires. These data demonstrate the feasibility of removing tin and other unwanted metals from EC aerosol by altering designs and using materials of suitable quality.

  17. Peach Bottom Atomic Power Station recirc pipe dose rates with zinc injection and condenser replacement

    Energy Technology Data Exchange (ETDEWEB)

    DiCello, D.C.; Odell, A.D.; Jackson, T.J. [PECO Energy Co., Delta, PA (United States)

    1995-03-01

    Peach Bottom Atomic Power Station (PBAPS) is located near the town of Delta, Pennsylvania, on the west bank of the Susquehanna River. It is situated approximately 20 miles south of Lancaster, Pennsylvania. The site contains two boiling water reactors of General Electric design and each rated at 3,293 megawatts thermal. The units are BWR 4s and went commercial in 1977. There is also a decommissioned high temperature gas-cooled reactor on site, Unit 1. PBAPS Unit 2 recirc pipe was replaced in 1985 and Unit 3 recirc pipes replaced in 1988 with 326 NGSS. The Unit 2 replacement pipe was electropolished, and the Unit 3 pipe was electropolished and passivated. The Unit 2 brass condenser was replaced with a Titanium condenser in the first quarter of 1991, and the Unit 3 condenser was replaced in the fourth quarter of 1991. The admiralty brass condensers were the source of natural zinc in both units. Zinc injection was initiated in Unit 2 in May 1991, and in Unit 3 in May 1992. Contact dose rate measurements were made in standard locations on the 28-inch recirc suction and discharge lines to determine the effectiveness of zinc injection and to monitor radiation build-up in the pipe. Additionally, HPGe gamma scans were performed to determine the isotopic composition of the oxide layer inside the pipe. In particular, the specific ({mu}Ci/cm{sup 2}) of Co-60 and Zn-65 were analyzed.

  18. Formation of recrystallization textures after hot working of AA2014 and AA6063

    Energy Technology Data Exchange (ETDEWEB)

    Geertruyden, W.H. van; Misiolek, W.Z. [Inst. for Metal Forming, Lehigh Univ., Bethlehem, PA (United States); Goncalves, M.; Szilagyi, G. [IPT-Dimet, Cidade Universitara, Sao Paulo-SP (Brazil); Nowell, M. [TSL/EDAX, Draper, UT (United States)

    2002-07-01

    This paper involves the investigation of the material response of two commercial aluminum alloys, 2014 and 6063, to thermo-mechanical processing parameters and the subsequent effects on the recrystallization behavior. Samples of the 2014 and 6063 alloys were hot rolled at 350, 400, 480, and 500 C to reductions of 50% and 75%. The samples were subsequently solutionized at 500 C (2014) and 525 C (6063) for 1 hour. Light optical microscopy (LOM) was performed which showed increased recrystallization kinetics in the 6063 alloy relative to the 2014 alloy. The solutionized samples of the 2014 alloy showed a banded microstructure indicating recrystallization was inhibited in the normal direction. The microtexture of the samples was characterized using electron backscatter diffraction (EBSD). Orientation distribution functions (ODF) and pole figures showed that the 6063 alloy displayed a copper rolling texture {l_brace}112{r_brace} left angle 111 right angle and an increasing cube recrystallization texture {l_brace}001{r_brace} left angle 100 right angle as the deformation temperature was increased. At low deformation temperatures, the 2014 alloy had a mixed Goss {l_brace}110{r_brace} left angle 001 right angle and Brass {l_brace}011{r_brace} left angle 211 right angle texture, while at higher temperatures and reductions the Brass component was very strong. The 2014 recrystallized texture was predominantly a cube texture rotated 45 degrees about the normal direction. (orig.)

  19. Ultrasonic backward radiation on painted rough interface

    International Nuclear Information System (INIS)

    Kwon, Yong Gyu; Yoon, Seok Soo; Kwon, Sung Duck

    2002-01-01

    The angular dependence(profile) of backscattered ultrasound was measured for steel and brass specimens with periodical surface roughness (1-71μm). Backward radiations showed more linear dependency than normal profile. Direct amplitude increased and averaging amplitude decreased with surface roughness. Painting treatment improved the linearity in direct backward radiation below roughness of 0.03. Scholte and Rayleigh-like waves were observed in the spectrum of averaging backward radiation on periodically rough surface. Painting on periodically rough surface could be used in removing the interface mode effect by periodic roughness.

  20. Stochastic cooling equipment at the ISR

    CERN Multimedia

    1983-01-01

    The photo shows (centre) an experimental set-up for stochastic cooling of vertical betatron oscillations, used at the ISR in the years before the ICE ring was built. Cooling times of about 30 min were obtained in the low intensity range (~0.3 A). To be noted the four 50 Ohm brass input/output connections with cooling fins, and the baking-out sheet around the cylinder. On the left one sees a clearing electrode box allowing the electrode current to be measured, and the pressure seen by the beam to be evaluated.

  1. RECYCLING OF SCRAP AND WASTE OF COPPER AND COPPER ALLOYS IN BELARUS

    Directory of Open Access Journals (Sweden)

    S. L. Rovin

    2017-01-01

    Full Text Available The construction of a new casting and mechanical shop of unitary enterprise «Tsvetmet» in December 2015 has allowed to solve the complex problem of processing and utilization of scrap and wastes of copper and copper alloys in the Republic of Belarus. The technological processes of fire refinement of copper and manufacturing of copper rod from scrap and production of brass rod by hot pressing (extrusion of the continuously casted round billet have been mastered for the first time in the Republic of Belarus.

  2. Non-invasive chemical and phase analysis of Roman bronze artefacts from Thamusida (Morocco)

    Energy Technology Data Exchange (ETDEWEB)

    Gliozzo, Elisabetta, E-mail: gliozzo@unisi.i [Dipartimento di Scienze della Terra, Universita di Siena, via Laterina 8, 53100 Siena (Italy); Arletti, Rossella, E-mail: rarletti@unimore.i [Dipartimento di Scienze della Terra, Universita di Modena e Reggio Emilia, Largo S. Eufemia 19, 41100 Modena (Italy); Cartechini, Laura, E-mail: laura@thch.unipg.i [Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), c/o Dipartimento di Chimica, Universita di Perugia, via Elce di Sotto 8, 06123 Perugia (Italy); Dipartimento di Chimica, Universita di Perugia, via Elce di Sotto 8, 06123 Perugia (Italy); Imberti, Silvia, E-mail: Silvia.Imberti@stfc.ac.u [Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, OX11 0QX (United Kingdom); Kockelmann, Winfried A., E-mail: Winfried.Kockelmann@stfc.ac.u [Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, OX11 0QX (United Kingdom); Memmi, Isabella, E-mail: memmi@unisi.i [Dipartimento di Scienze della Terra, Universita di Siena, via Laterina 8, 53100 Siena (Italy); Rinaldi, Romano, E-mail: rrinaldi@unipg.i [Dipartimento di Chimica, Universita di Perugia, via Elce di Sotto 8, 06123 Perugia (Italy); Tykot, Robert H., E-mail: rtykot@cas.usf.ed [Department of Anthropology, University of South Florida, Tampa, FL 33620 (United States)

    2010-12-15

    A repertory of Roman military bronze equipment (1st- 3rd century AD) found at the archaeological site of Thamusida (Rabat, Morocco) was analysed by non-destructive X-ray fluorescence and time of flight neutron diffraction (TOF-ND). Most objects are made of leaded alloys, where copper is combined with tin and/or zinc and, in six cases, to arsenic as well. A mixed technology was employed, making a limited use of 'pure' semi-finished materials if compared with the large utilization of recycled materials (brass and bronze).

  3. Relationship between structure and the stress pattern in the human mandible.

    Science.gov (United States)

    Mongini, F; Calderale, P M; Barberi, G

    1979-12-01

    The internal bony structure of ten dentate human mandibles was examined on lateral radiograms, and the condylar shape measured with a digital electronic machine. The external surface was coated with photoelastic material. Each mandible was then placed in centric occlusion with brass replicas of the upper arch and the glenoid fossae and set in a supporting frame. Occlusal loads were simulated and the isoclinics recorded in plane-polarized light. The isostatic flow lines were constructed for each mandible. A relation was found between the mandibular structure and the distribution pattern of these lines.

  4. Manpower and Personnel Requirements Determination Methodologies (MANPERS).

    Science.gov (United States)

    1984-12-01

    appropriate. The raters agreed most: of the time, and discussed reasons for discre- pancies; however, there was no formal scoring because the ratings...97-7 Piano Player 02N 3-97-11 Guitar Player 02T 3-97-13 Baritone or Euphonium Player 02C 3-97-7 .. TRasson Player 02K 3-97-7 Brass Group Leader 02P 3...These scales permit the rater to select a score ranging from 0 to 17, with sample task descrip- tions (i.e., anchor points) provided to assist the

  5. A Fiber-Coupled Self-Mixing Laser Diode for the Measurement of Young’s Modulus

    Directory of Open Access Journals (Sweden)

    Ke Lin

    2016-06-01

    Full Text Available This paper presents the design of a fiber-coupled self-mixing laser diode (SMLD for non-contact and non-destructive measurement of Young’s modulus. By the presented measuring system, the Young’s modulus of aluminum 6061 and brass are measured as 70.0 GPa and 116.7 GPa, respectively, showing a good agreement within the standards in the literature and yielding a much smaller deviation and a higher repeatability compared with traditional tensile testing. Its fiber-coupled characteristics make the system quite easy to be installed in many application cases.

  6. [Estimation of infant and child mortality in the eastern provinces of Cuba].

    Science.gov (United States)

    Gonzalez, G; Herrera, L

    1986-01-01

    An estimate of infant and child mortality in the eastern provinces of Cuba is presented using the Brass method as adapted by Trussell. "Estimations by urban and rural zones are also performed within the provinces studied, and results are compared with those possible to obtain by continuous statistics. Results obtained show that in the eastern [part] of the country Holguin and Guantanamo are the provinces with highest infantile mortality rates, and the lowest rates correspond to Granma, followed by Santiago de Cuba." (SUMMARY IN ENG AND FRE) excerpt

  7. High torque DC motor fabrication and test program

    Science.gov (United States)

    Makus, P.

    1976-01-01

    The testing of a standard iron and standard alnico permanent magnet two-phase, brushless dc spin motor for potential application to the space telescope has been concluded. The purpose of this study was to determine spin motor power losses, magnetic drag, efficiency and torque speed characteristics of a high torque dc motor. The motor was designed and built to fit an existing reaction wheel as a test vehicle and to use existing brass-board commutation and torque command electronics. The results of the tests are included in this report.

  8. A Bacon Tone Ring on an Open-Back Banjo

    OpenAIRE

    Politzer, David

    2016-01-01

    Head taps on a new Goodtime banjo rim fitted with a reproduction Bacon Professional ff tone ring are contrasted with a new Goodtime, a 2002 Goodtime, and a 1999 Goodtime fitted with a 1/4′′ diameter brass ring. Conclusions: The 1/4" ring does what’s commonly imagined, the upgrades to the Goodtime over the years are not merely cosmetic, and the Bacon ring’s biggest effect is to damp head ringing and suppress high harmonics. Detailed comparisons of the new Goodtimes with and without the Bacon r...

  9. Failure analysis of a helicopter's main rotor bearing

    International Nuclear Information System (INIS)

    Shahzad, M.; Qureshi, A.H.; Waqas, H.; Hussain, N.; Ali, N.

    2011-01-01

    Presented results report some of the findings of a detailed failure analysis carried out on a main rotor hub assembly, which had symptoms of burning and mechanical damage. The analysis suggests environmental degradation of the grease which causes pitting on bearing-balls. The consequent inefficient lubrication raises the temperature which leads to the smearing of cage material (brass) on the bearing-balls and ultimately causes the failure. The analysis has been supported by the microstructural studies, thermal analysis and micro-hardness testing performed on the affected main rotor bearing parts. (author)

  10. Strategies to Reduce Tin and Other Metals in Electronic Cigarette Aerosol

    Science.gov (United States)

    Williams, Monique; To, An; Bozhilov, Krassimir; Talbot, Prue

    2015-01-01

    Background Metals are present in electronic cigarette (EC) fluid and aerosol and may present health risks to users. Objective The objective of this study was to measure the amounts of tin, copper, zinc, silver, nickel and chromium in the aerosol from four brands of EC and to identify the sources of these metals by examining the elemental composition of the atomizer components. Methods Four brands of popular EC were dissected and the cartomizers were examined microscopically. Elemental composition of cartomizer components was determined using integrated energy dispersive X-ray microanalysis, and the concentrations of the tin, copper, zinc silver, nickel, and chromium in the aerosol were determined for each brand using inductively coupled plasma optical emission spectroscopy. Results All filaments were made of nickel and chromium. Thick wires were copper coated with either tin or silver. Wires were joined to each other by tin solder, brazing, or by brass clamps. High concentrations of tin were detected in the aerosol when tin solder joints were friable. Tin coating on copper wires also contributed to tin in the aerosol. Conclusions Tin concentrations in EC aerosols varied both within and between brands. Tin in aerosol was reduced by coating the thick wire with silver rather than tin, placing stable tin solder joints outside the atomizing chamber, joining wires with brass clamps or by brazing rather than soldering wires. These data demonstrate the feasibility of removing tin and other unwanted metals from EC aerosol by altering designs and using materials of suitable quality. PMID:26406602

  11. Comparative Evaluation of Marginal Discrepancy in Tooth Colored Self Cure Acrylic Provisional Restorations With and Without Reinforcement of Glass Beads: An In-Vitro Study.

    Science.gov (United States)

    Yasangi, Manoj Kumar; Mannem, Dhanalakshmi; Bommireddy, Vikram Simha; Neturi, Sirisha; Ravoori, Srinivas; Jyothi

    2015-05-01

    This invitro study was conducted to compare and evaluate marginal discrepancy in two types of tooth colored self cure provisional restorative materials {DPI&UNIFAST TRAD} before and after reinforcement of glass beads. The aim of the present study was to evaluate and compare marginal discrepancy in two types of provisional restorative materials (DPI and UNI FAST TRAD) before and after reinforcement with Glass beads. Tooth shaped resin copings were fabricated on custom made brass metal die. A total of 60 resin copings were fabricated in which 30 samples were prepared with DPI and 30 samples with UNIFAST material. Each group of 30 samples were divided in to two sub groups in which 15 samples were prepared with glass bead reinforcement and 15 samples without reinforcement. The marginal discrepancy was evaluated with photomicroscope {Reichet Polyvar 2 met} by placing the resin copings on custom made brass resin coping holder. Measurements obtained were statistically analysed by unpaired t-test to know any significance between two variables. Unreinforced DPI specimens had shown lower marginal discrepancy (442.82) than reinforced specimens (585.77). Unreinforced UNIFAST specimens have shown high values of marginal discrepancy (592.83) than reinforced specimens (436.35). p-value between reinforced and unreinforced specimens of DPI (p=0.0013) and UNIFAST (p= 0.0038) has shown statistical significance. This in-vitro study revealed that unreinforced DPI specimens have shown lower marginal discrepancy than reinforced specimens and unreinforced UNIFAST specimens have shown higher values of marginal discrepancy than reinforced specimens.

  12. Efficient prion disease transmission through common environmental materials.

    Science.gov (United States)

    Pritzkow, Sandra; Morales, Rodrigo; Lyon, Adam; Concha-Marambio, Luis; Urayama, Akihiko; Soto, Claudio

    2018-03-02

    Prion diseases are a group of fatal neurodegenerative diseases associated with a protein-based infectious agent, termed prion. Compelling evidence suggests that natural transmission of prion diseases is mediated by environmental contamination with infectious prions. We hypothesized that several natural and man-made materials, commonly found in the environments of wild and captive animals, can bind prions and may act as vectors for disease transmission. To test our hypothesis, we exposed surfaces composed of various common environmental materials ( i.e. wood, rocks, plastic, glass, cement, stainless steel, aluminum, and brass) to hamster-adapted 263K scrapie prions and studied their attachment and retention of infectivity in vitro and in vivo Our results indicated that these surfaces, with the sole exception of brass, efficiently bind, retain, and release prions. Prion replication was studied in vitro using the protein misfolding cyclic amplification technology, and infectivity of surface-bound prions was analyzed by intracerebrally challenging hamsters with contaminated implants. Our results revealed that virtually all prion-contaminated materials transmitted the disease at high rates. To investigate a more natural form of exposure to environmental contamination, we simply housed animals with large contaminated spheres made of the different materials under study. Strikingly, most of the hamsters developed classical clinical signs of prion disease and typical disease-associated brain changes. Our findings suggest that prion contamination of surfaces commonly present in the environment can be a source of disease transmission, thus expanding our understanding of the mechanisms for prion spreading in nature. © 2018 by The American Society for Biochemistry and Molecular Biology, Inc.

  13. A Statistical Review of Alternative Zinc and Copper Extraction from Mineral Fertilizers and Industrial By-Products.

    Science.gov (United States)

    Cenciani de Souza, Camila Prado; Aparecida de Abreu, Cleide; Coscione, Aline Renée; Alberto de Andrade, Cristiano; Teixeira, Luiz Antonio Junqueira; Consolini, Flavia

    2018-01-01

    Rapid, accurate, and low-cost alternative analytical methods for micronutrient quantification in fertilizers are fundamental in QC. The purpose of this study was to evaluate whether zinc (Zn) and copper (Cu) content in mineral fertilizers and industrial by-products determined by the alternative methods USEPA 3051a, 10% HCl, and 10% H2SO4 are statistically equivalent to the standard method, consisting of hot-plate digestion using concentrated HCl. The commercially marketed Zn and Cu sources in Brazil consisted of oxides, carbonate, and sulfate fertilizers and by-products consisting of galvanizing ash, galvanizing sludge, brass ash, and brass or scrap slag. The contents of sources ranged from 15 to 82% and 10 to 45%, respectively, for Zn and Cu. The Zn and Cu contents refer to the variation of the elements found in the different sources evaluated with the concentrated HCl method as shown in Table 1. A protocol based on the following criteria was used for the statistical analysis assessment of the methods: F-test modified by Graybill, t-test for the mean error, and linear correlation coefficient analysis. In terms of equivalents, 10% HCl extraction was equivalent to the standard method for Zn, and the results of the USEPA 3051a and 10% HCl methods indicated that these methods were equivalents for Cu. Therefore, these methods can be considered viable alternatives to the standard method of determination for Cu and Zn in mineral fertilizers and industrial by-products in future research for their complete validation.

  14. Investigations on vanadium doped glasses

    International Nuclear Information System (INIS)

    Madhusudana Rao, P.

    2013-01-01

    The glass samples studied in the present work have been prepared by melt quenching technique. They were prepared by mixing and grinding together by appropriate amounts of Li 2 O - Na 2 O - B 2 O 3 doped with V 2 O 5 in an agate motor before transferring into crucible. The mixtures were heated in an electric furnace at 1225K for 20 mm. The melt was then quenched to room temperature by pouring it on plane brass plate and pressing it with another brass plate. White and yellow coloured glasses have been obtained with good optical quality and high transparency. Finally the vitreous sample were annealed for 3 hrs at 423K to relieve residual internal stress and slowly cooled to room temperature. The polished glasses have been used for XRD, FTIR analysis and for DSC report. The DSC thermo grams for all the glasses were recorded on in the temperature range 50-550℃ with a heating rate of 10℃/min. Electron spin resonance and optical absorption of 20Li 2 O - 10 Na 2 O - (70-X)B 2 O 3 doped with XV 2 O 5 glass system are studied. ESR spectra of V 4+ ions doped in the glass exhibit peak at g =1.98. Spin Hamiltonian parameters are calculated. It was found that these parameters are dependent upon alkali ion concentration in the glass and the VO +2 ion in an octahedral coordination with a tetragonal compression. The physical parameters of all glasses were also evaluated with respect to the composition

  15. Modeling and experimental study of oil/water contact angle on biomimetic micro-parallel-patterned self-cleaning surfaces of selected alloys used in water industry

    Energy Technology Data Exchange (ETDEWEB)

    Nickelsen, Simin; Moghadam, Afsaneh Dorri, E-mail: afsaneh@uwm.edu; Ferguson, J.B.; Rohatgi, Pradeep

    2015-10-30

    Graphical abstract: - Highlights: • Wetting behavior of four metallic materials as a function of surface roughness has been studied. • A model to predict the abrasive particle size and water/oil contact angles relationship is proposed. • Active wetting regime is determined in different materials using the proposed model. - Abstract: In the present study, the wetting behavior of surfaces of various common metallic materials used in the water industry including C84400 brass, commercially pure aluminum (99.0% pure), Nickle–Molybdenum alloy (Hastelloy C22), and 316 Stainless Steel prepared by mechanical abrasion and contact angles of several materials after mechanical abrasion were measured. A model to estimate roughness factor, R{sub f}, and fraction of solid/oil interface, ƒ{sub so}, for surfaces prepared by mechanical abrasion is proposed based on the assumption that abrasive particles acting on a metallic surface would result in scratches parallel to each other and each scratch would have a semi-round cross-section. The model geometrically describes the relation between sandpaper particle size and water/oil contact angle predicted by both the Wenzel and Cassie–Baxter contact type, which can then be used for comparison with experimental data to find which regime is active. Results show that brass and Hastelloy followed Cassie–Baxter behavior, aluminum followed Wenzel behavior and stainless steel exhibited a transition from Wenzel to Cassie–Baxter. Microstructural studies have also been done to rule out effects beyond the Wenzel and Cassie–Baxter theories such as size of structural details.

  16. Comparative Evaluation of Marginal Discrepancy in Tooth Colored Self Cure Acrylic Provisional Restorations With and Without Reinforcement of Glass Beads: An In-Vitro Study

    Science.gov (United States)

    Yasangi, Manoj Kumar; Mannem, Dhanalakshmi; Neturi, Sirisha; Ravoori, Srinivas; Jyothi

    2015-01-01

    Context This invitro study was conducted to compare and evaluate marginal discrepancy in two types of tooth colored self cure provisional restorative materials {DPI&UNIFAST TRAD} before and after reinforcement of glass beads. Aim The aim of the present study was to evaluate and compare marginal discrepancy in two types of provisional restorative materials (DPI and UNI FAST TRAD) before and after reinforcement with Glass beads. Materials and Methods Tooth shaped resin copings were fabricated on custom made brass metal die. A total of 60 resin copings were fabricated in which 30 samples were prepared with DPI and 30 samples with UNIFAST material. Each group of 30 samples were divided in to two sub groups in which 15 samples were prepared with glass bead reinforcement and 15 samples without reinforcement. The marginal discrepancy was evaluated with photomicroscope {Reichet Polyvar 2 met} by placing the resin copings on custom made brass resin coping holder. Results Measurements obtained were statistically analysed by unpaired t-test to know any significance between two variables. Unreinforced DPI specimens had shown lower marginal discrepancy (442.82) than reinforced specimens (585.77). Unreinforced UNIFAST specimens have shown high values of marginal discrepancy (592.83) than reinforced specimens (436.35). p-value between reinforced and unreinforced specimens of DPI (p=0.0013) and UNIFAST (p= 0.0038) has shown statistical significance. Conclusion This in-vitro study revealed that unreinforced DPI specimens have shown lower marginal discrepancy than reinforced specimens and unreinforced UNIFAST specimens have shown higher values of marginal discrepancy than reinforced specimens. PMID:26155574

  17. Dispersion of breakdown voltage of liquid helium

    International Nuclear Information System (INIS)

    Ishii, Itaru; Noguchi, Takuya

    1978-01-01

    As for the electrical insulation characteristics of liquid helium, the discrepancy among the measured values by each person is very large even in the fundamental DC breakdown voltage in uniform electric field. The dispersion of experimental values obtained in the experiments by the same person is also large. Hereafter, the difference among the mean values obtained by each experimenter will be referred to as ''deviation of mean values'', and the dispersion of measured values around the mean value obtained by the same person as ''deviation around the man value''. The authors have mainly investigated on the latter experimentally. The cryostat was made of stainless steel, and the innermost helium chamber was of 500 mm I.D. and approximately 1200 mm deep. The high voltage electrode was of brass sphere of 25 mm diameter, and the low voltage electrode was of brass plate. The experiment was conducted for liquid helium boiling at 4.2 K and 1 atm, and the breakdown voltage and time lag were measured by applying the approximately square wave impulses of fast rise and long tail, ramp and DC voltages. The cause of the deviation of mean values may be the presence of impurity particles or the effect of electrode shape. As for the deviation around the mean value, the dispersion is large, and its standard deviation may amount to 10 to 20% of the man value. The dispersion is not due to the statistical time lag, but is due to parameters that vary with breakdown. (Wakatsuki, Y.)

  18. Bragg Fibers with Soliton-like Grating Profiles

    Directory of Open Access Journals (Sweden)

    Bugaychuk S.

    2016-01-01

    Full Text Available Nonlinear dynamical system corresponding to the optical holography in a nonlocal nonlinear medium with dissipation contains stable localized spatio-temporal states, namely the grid dissipative solitons. These solitons display a non-uniform profile of the grating amplitude, which has the form of the dark soliton in the reflection geometry. The transformation of the grating amplitude gives rise many new atypical effects for the beams diffracted on such grating, and they are very suitable for the fiber Brass gratings. The damped nonlinear Schrodinger equation is derived that describes the properties of the grid dissipative soliton.

  19. BATING A REFERENCE INSTALLATION BASED ON CONTROLLED-POTENTIAL COULOMETRY METOD IN THE FRAME OF IMPROVING THE STATE PRIMARY STANDARD GET 176 AND ITS MEASUREMENT CAPABILITIES

    Directory of Open Access Journals (Sweden)

    V. M. Zyskin

    2016-01-01

    Full Text Available The results of developing of reference installation, based on a controlled-potential coulometry, in the frame of improving the State primary standard of the units of mass (molar fraction and mass (molar concentration of a component in the liquid and solid substances and materials GET 176 are presented. The physical principles of controlled-potential coulometry, content and metrological characteristics of the developed installation are considered. Measurement results of copper, iron and lead contents in the certified reference materials of metals' solutions and CRM of brass produced by BAM, Germany, obtained using reference installation are given.

  20. Young's moduli of cables for high field superconductive dipole magnet

    International Nuclear Information System (INIS)

    Yamada, Shunji; Shintomi, Takakazu.

    1983-01-01

    Superconductive dipole magnets for big accelerators are subjected to enormous electro-magnetic force, when they are operated with high field such as 10 Tesla. They should be constructed by means of superconductive cables, which have high Young's modulus, to obtain good performance. To develop such cables we measured the Young's moduli of cables for practical use of accelerator magnets. They are monolithic and compacted strand cables. We measured also Young's moduli of monolithic copper and brass cables for comparison. The obtained data showed the Young's moduli of 35 and 15 GPa for the monolithic and compacted strand cables, respectively. (author)

  1. MicroCT parameters for multimaterial elements assessment

    Science.gov (United States)

    de Araújo, Olga M. O.; Silva Bastos, Jaqueline; Machado, Alessandra S.; dos Santos, Thaís M. P.; Ferreira, Cintia G.; Rosifini Alves Claro, Ana Paula; Lopes, Ricardo T.

    2018-03-01

    Microtomography is a non-destructive testing technique for quantitative and qualitative analysis. The investigation of multimaterial elements with great difference of density can result in artifacts that degrade image quality depending on combination of additional filter. The aim of this study is the selection of parameters most appropriate for analysis of bone tissue with metallic implant. The results show the simulation with MCNPX code for the distribution of energy without additional filter, with use of aluminum, copper and brass filters and their respective reconstructed images showing the importance of the choice of these parameters in image acquisition process on computed microtomography.

  2. X-ray fluorescence - a non-destructive tool in investigation of Czech fine and applied art objects

    Science.gov (United States)

    Trojek, T.; Musílek, L.

    2017-08-01

    A brief review of application of X-ray fluorescence analysis (XRFA) to fine and applied arts related to Czech cultural heritage is presented. The Department of Dosimetry and Application of Ionising Radiation of CTU-FNSPE has used XRFA in collaboration with various Czech institutions dealing with cultural history for many kinds of artefacts, (e.g., Roman and medieval brass, gemstones and noble metals from the sceptre of one of the faculties of the Charles University in Prague, millefiori beads, etc.). In some cases, a combination of various other techniques alongside XRFA was used for enhancing our knowledge of a measured object.

  3. MicroCT parameters for multi material elements assessment

    Energy Technology Data Exchange (ETDEWEB)

    Araújo, Olga M.O. de; Machado, Alessandra S.; Santos, Thaís M.P. dos; Ferreira, Cintia G.; Lopes, Ricardo T., E-mail: olgaufrjlin@gmail.com [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear; Bastos, Jaqueline Silva [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), São Paulo, SP (Brazil)

    2017-07-01

    Microtomography is a non-destructive testing technique for quantitative and qualitative analysis. The investigation of multi material elements with great difference of density can result in artifacts that degrade image quality depending on combination of additional filter. The aim of this study is the selection of parameters most appropriate for analysis of bone tissue with metallic implant. The results show the simulation with MCNPX code for the distribution of energy without additional filter, with use of aluminum, copper and brass filters and their respective reconstructed images showing the importance of the choice of these parameters in image acquisition process on computed microtomography. (author)

  4. Time-resolved studies of particle effects in laser ablation inductively coupled plasma-mass spectrometry. Part 2: Investigation of MO+ ions, effect of sample morphology, transport gas, and binding agents

    International Nuclear Information System (INIS)

    Perdian, D.; Bajic, S.; Baldwin, D.; Houk, R.

    2007-01-01

    Time resolved signals in laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) are studied to determine the influence of experimental parameters on ICP-induced fractionation effects. Differences in sample composition and morphology, i.e., ablating brass, glass, or dust pellets, have a profound effect on the time resolved signal. Helium transport gas significantly decreases large positive signal spikes arising from large particles in the ICP. A binder for pellets also reduces the abundance and amplitude of spikes in the signal. MO + ions also yield signal spikes, but these MO + spikes generally occur at different times from their atomic ion counterparts.

  5. Electrochemical corrosion of carbon-fiber-reinforced plastic-metal electrode couples in corrosion media

    International Nuclear Information System (INIS)

    Chukalovskaya, T.V.; Shcherbakov, A.I.; Chigirinskaya, L.A.; Bandurkin, V.V.; Medova, I.L.; Chukalovskij, P.A.

    1995-01-01

    Polarization diagrams, obtained for carbon-fiber-reinforced plastic(cathode)-metallic material(anode) contact couples are analyzed to predict the corrosion behaviour of some technical metals and alloys (carbon steel, stainless steels, brass, aluminium, titanium) in contact with carbon-fiber-reinforced plastic in differen agressive media (H 2 SO 4 , HCl, H 3 PO 4 , NaOH solutions in wide temperature and concentration range, synthetic seawater at 30 and 50 deg C). The predicted behaviour was supported by direct investigation into carbon-fiber-reinforced plastic-titanium and carbon-fiber-reinforced plastic-aluminium contact couples at different square ratios. 6 refs.; 4 figs

  6. Bagatellid : maailm / Nele-Eva Steinfeld, Ivo Heinloo

    Index Scriptorium Estoniae

    Steinfeld, Nele-Eva

    2011-01-01

    Muusikasõnumeid maailmast: 14. Tšaikovski nimelisest konkursist. Daniel Barenboim tõstetakse rüütliseisusesse. Orkestrist I, Culture Orchestra. Charles Dutoit plaanib luua Lõuna- ja Põhja-Koread ühendava orkestri. Lahkus Josef Suk. Seiji Ozawa pälvis Praemium Imperiale auhinna. Cardiffi lauljate konkursi võitis Valentina Nafornita. Lahkus Nikolai Petrov. Venetsueelas lööb laineid noor dirigent Jose Omar Davila. "Jazzkaare" täht Brass Jaw sai Suurbritannias suure tunnustuse osaliseks. Põhjamaade Nõukogu muusikaauhinna teenis Mats Gustafsson. Black Eyed Peas paneb pillid kotti. Kuuba kitarrist Manuel Galban surnud. Eesti on Tšehhi jazziraadio fookuses

  7. Development of high-performance sintered friction material for synchronizer ring; Koseino shoketsu synchronizer ring masatsu zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Miyajima, K; Fuwa, Y; Okajima, H; Yoshikawa, K [Toyota Motor Corp., Aichi (Japan); Nakamura, M [Japan Powder Metallurgy Co. Ltd., Tokyo (Japan)

    1997-10-01

    Increasing vehicle speed and power, high-performance synchronizer ring of manual transmission is required. We develop double layer sintered synchronizer ring for high performance and cost reduction. The main structure is consisted of ferrous sinter for high strength. In this paper, friction materials of sintered synchronizer ring are studied. We can get the good friction and anti-wear property by means of hard particles (FeTi, ZrO2), solid lubricant (Graphite) and suitable porosity in brass sinter matrix. And we also achieve high joining strength between double layers adding Cu-P material. 6 refs., 13 figs., 2 tabs.

  8. Implementation of the FASTBUS data-acquisition system in the readout of the SAPHIR detector

    International Nuclear Information System (INIS)

    Empt, J.

    1993-12-01

    The magnetic detector SAPHIR is layed out to detect multiparticle final states with good acuracy, especially a good photon detection capability is designed. Therefore a large electromagnetic calorimeter was built, consisting of 98 modules covering a detection area of about 16 m 2 in forward direction. For this calorimeter a brass-gas-sandwich detector was developed with signal wires perpendicular to the converter planes. For data acquisition of a major part of this calorimeter a modular FASTBUS system is used. In this report the FASTBUS system and its installation in the SAPHIR Online Program are described. (orig.)

  9. Development of Zn50 Brazing Alloy for Joining Mild Steel to Mild Steel (SAE1018

    Directory of Open Access Journals (Sweden)

    S.C. Nwigbo

    2014-09-01

    Full Text Available This work has developed new brazing alloys for joining mild steel to mild steel (SAE1018 at a lower temperature. The alloys blends and error analysis were done by experimental design software (Design Expert 8.0.7.1. Design of experiments was done by Scheffe quadratic mixture method. The liquidus temperatures were predicted by calculation of phase diagrams of the alloying metals. The brazing alloys were produced by gravity technique and melted using silicon carbide graphite crucible. The quality of the brazing alloys was analyzed by optical microscopy (OM, atomic absorption spectroscopy (AAS and fourier transform infrared spectroscopy (FT-IR. Brazed joints were produced by torch method with a commercial flux. Brazing temperatures (liquidus were tracked by a digital infrared/laser pyrometer. Some mechanical properties studied were tensile strength and hardness. Finally, brazed joints produced from the developed brazing alloys were compared to that produced from muntz brass. Six (6 brazing alloys were successfully developed. Zinc and manganese were the main components, to which were added; 3 to 4 %wt silver and 11 to15 %wt modifying element. The microstructure showed a typical eutectic structure with zinc-rich phase distributed uniformly in the matrix with a combination of different sizes of dendrite, rounded blocks of compounds and hypoeutectic structures. AAS results indicated minimal out-gassing of zinc and FT-IR results indicated very low presence of atmospheric gas. The range of brazing temperature for best results was recorded from 690.90 to 735.10 0C. The joints produced from the developed brazing alloys had acceptable strengths with improved stress-strain behaviour compared to muntz brass.

  10. An intelligent approach to optimize the EDM process parameters using utility concept and QPSO algorithm

    Directory of Open Access Journals (Sweden)

    Chinmaya P. Mohanty

    2017-04-01

    Full Text Available Although significant research has gone into the field of electrical discharge machining (EDM, analysis related to the machining efficiency of the process with different electrodes has not been adequately made. Copper and brass are frequently used as electrode materials but graphite can be used as a potential electrode material due to its high melting point temperature and good electrical conductivity. In view of this, the present work attempts to compare the machinability of copper, graphite and brass electrodes while machining Inconel 718 super alloy. Taguchi’s L27 orthogonal array has been employed to collect data for the study and analyze effect of machining parameters on performance measures. The important performance measures selected for this study are material removal rate, tool wear rate, surface roughness and radial overcut. Machining parameters considered for analysis are open circuit voltage, discharge current, pulse-on-time, duty factor, flushing pressure and electrode material. From the experimental analysis, it is observed that electrode material, discharge current and pulse-on-time are the important parameters for all the performance measures. Utility concept has been implemented to transform a multiple performance characteristics into an equivalent performance characteristic. Non-linear regression analysis is carried out to develop a model relating process parameters and overall utility index. Finally, the quantum behaved particle swarm optimization (QPSO and particle swarm optimization (PSO algorithms have been used to compare the optimal level of cutting parameters. Results demonstrate the elegance of QPSO in terms of convergence and computational effort. The optimal parametric setting obtained through both the approaches is validated by conducting confirmation experiments.

  11. Effective atomic number, energy loss and radiation damage studies in some materials commonly used in nuclear applications for heavy charged particles such as H, C, Mg, Fe, Te, Pb and U

    Science.gov (United States)

    Kurudirek, Murat

    2016-05-01

    Commonly used nuclear physics materials such as water, concrete, Pb-glass, paraffin, freon and P 10 gases, some alloys such as brass, bronze, stainless-steel and some scintillators such as anthracene, stilbene and toluene have been investigated with respect to the heavy charged particle interaction as means of projected range and effective atomic number (Zeff) in the energy region 10 keV to 10 MeV. Calculations were performed for heavy ions such as H, C, Mg, Fe, Te, Pb and U. Also, the energy loss and radiation damage were studied using SRIM Monte Carlo code for anthracene for different heavy ions of 100 keV kinetic energy. It has been observed that the variation in Zeff becomes less when the atomic number of the ions increase. Glass-Pb, bronze, brass, stainless-steel and Freon gas were found to vary less than 10% in the energy region 10 keV to 10 MeV. For total proton interaction, discrepancies up to 10% and 18% between two databases namely PSTAR and SRIM were noted in mass stopping power and Zeff of water, respectively. The range calculations resulted with a conclusion that the metal alloys and glass-Pb have lowest values of ranges confirming best shielding against energetic heavy ions whereas freon and P 10 gases have the highest values of ranges in the entire energy region. The simulation results showed that the energy loss (%) to target electrons decreases as the Z of the incident ion increases. Also, it was observed that the radiation damage first increases with Z of the ion and then keeps almost constant for ions with Z≥52.

  12. The Al-rich region of the Al–Fe–Mn alloy system

    International Nuclear Information System (INIS)

    Balanetskyy, S.; Pavlyuchkov, D.; Velikanova, T.; Grushko, B.

    2015-01-01

    Highlights: • Constitution of Al–Fe–Mn was studied above 50 at.% Al at 650–1070 °C. • AlMn (A2) and AlFe (B2) phases form a continuous compositional region. • Al 8 Mn 5 and Al 8 Fe 5 γ-brass type phases form a continuous compositional region. • Al 13 Fe 4 , Al 5 Fe 2 , Al 2 Fe, Al 6 Mn, Al 11 Mn 4 , γ 2 exhibit wide ternary extensions. • Four ternary intermetallics were revealed. - Abstract: Phase equilibria in the Al-rich region of the Al–Fe–Mn alloy system were studied at 1070, 1020, 950, 875, 800, 740, 695 and 650 °C. The continuous region of the bcc solid solution was estimated between the Al–Mn and Al–Fe terminals. Also the isostructural high-temperature Al–Mn and Al–Fe γ 1 -phases (γ-brass type structure) form continuous regions. The Al 6 Mn, high-temperature T-Al 11 Mn 4 and low-temperature γ 2 phases dissolve up to 9.0, 14.5 and 31.0 at.% Fe, respectively, while the M-Al 13 Fe 4 , Al 5 Fe 2 and Al 2 Fe phases dissolve up to 15.5, 11.5 and 10.0 at.% Mn, respectively. The thermodynamically stable decagonal D 3 -phase with periodicity of 1.25 nm in the specific direction and two periodic intermetallics designated φ (P6 3 /mmc; a = 0.7554, c = 0.7872 nm) and κ (P6 3 /m; a = 1.7630, c = 1.2506 nm) were identified. An additional ternary phase of unknown structure was also revealed

  13. Studies of some alloys using x-ray fluorescence

    International Nuclear Information System (INIS)

    Elmahi, Elamin Musaid

    1997-01-01

    In this project an attempt has been made for the study of alloys commonly used using x-ray fluorescence ( XRF ) technique. The alloys selected for the study included gold jewellery, steels, brasses and coins. The XRF method proved to be simple, fast, non-destructive and reliable as compared to chemical methods. The results showed that most of the gold jewellery used in this country have carat value of 18 and 21. Also most coins used in different countries are alloys of Cu and Ni. A simple spark method was used for the determination of C in steels, since C is not possible to analyze by XRF. ( Author )

  14. Condenser performance monitoring and cleaning

    International Nuclear Information System (INIS)

    Walden, J.V.

    1998-01-01

    The main condenser at Ginna Station was retubed from admiralty brass to 316 stainless steel. A condenser performance monitoring spreadsheet was developed using EPRI guidelines after fouling was discovered. PEPSE computer models were used to determine the power loss and confirm the spreadsheet results. Cleaning of the condenser was performed using plastic scrubbers. Condenser performance improved dramatically following the cleaning. PEPSE, condenser spreadsheet performance, and actual observed plant data correlated well together. The fouling mechanism was determined to be a common lake bacteria and fungus growth which was combined with silt. Chlorination of the circulating water system at the allowable limits is keeping the biofouling under control

  15. The electrodeposition of 149Sm targets for (n,α) studies

    International Nuclear Information System (INIS)

    Ingelbrecht, C.; Ambeck-Madsen, J.; Teipel, K.; Robouch, P.; Arana, G.; Pomme, S.

    1999-01-01

    A method of electrodeposition from ethanol was developed for the production of 149 Sm targets of area 50x60 mm 2 to be used for (n,α) experiments. Targets of 60 μg cm -2 Sm were obtained with a Sm yield of 50% and a Sm mass fraction of 35% after calcination of the layers at 450 deg. C. Target substrates were 20 μm aluminium foils mounted on brass frames. A water cooling jig was constructed to protect the glue used for mounting during the calcination process. The layers were characterized by inductively coupled plasma source mass spectrometry (ICP-MS) and by neutron activation analysis (NAA)

  16. Design and modelling of a 5 MeV radio frequency electron gun

    International Nuclear Information System (INIS)

    Batchelor, K.; Sheehan, J.; Woodle, M.

    1988-01-01

    The Accelerator Test Facility (ATF) at Brookhaven National Laboratory is a linac-laser complex for research into laser acceleration and for the generation of coherent radiation from electron beams. In order to achieve the design 50 MeV output emittance (γσ/sub x/σ/sub x/') of less than 3 /times/ 10/sup /minus/5/ m rad a high brightness electron gun is required. This paper describes computations and measurements made on a full scale brass model of a 1-1/2 cell, π-mode, resonant, disc loaded, radiofrequency gun structure which has been designed for this purpose. 7 refs., 9 figs., 6 tabs

  17. Stepped-Frequency Ground-Penetrating Radar for Detection of Small Non-metallic Buried Objects

    DEFF Research Database (Denmark)

    Jakobsen, Kaj Bjarne; Sørensen, Helge Bjarup Dissing; Nymann, Ole

    1997-01-01

    -shaped objects. Two-dimensional probe-correction and addition signal processing are applied to the raw probe-data. The probe used in this experiment was an open-ended waveguide operating at S-band. The movements of the probe are controlled by two stepmotors via an RS-232 interface. The probe is connected...... at each measurement point using a mesh-grid with a resolution down to 1 mm by 1 mm. The size of the scan area is 1410 mm by 210 mm. Measurements have been performed on loamy soil containing a buried M-56, a non-metallic AP-mine, and various other mine-like objects made of solid plastic, brass, aluminum...

  18. Design, Performance, and Calibration of the CMS Hadron-Outer Calorimeter

    CERN Document Server

    Abdullin, Salavat; Acharya, Bannaje Sripathi; Adam, Nadia; Adams, Mark Raymond; Akchurin, Nural; Akgun, Ugur; Albayrak, Elif Asli; Anderson, E Walter; Antchev, Georgy; Arcidy, M; Ayan, S; Aydin, Sezgin; Aziz, Tariq; Baarmand, Marc M; Babich, Kanstantsin; Baden, Drew; Bakirci, Mustafa Numan; Banerjee, Sunanda; Banerjee, Sudeshna; Bard, Robert; Barnes, Virgil E; Bawa, Harinder Singh; Baiatian, G; Bencze, Gyorgy; Beri, Suman Bala; Berntzon, Lisa; Bhatnagar, Vipin; Bhatti, Anwar; Bodek, Arie; Bose, Suvadeep; Bose, Tulika; Budd, Howard; Burchesky, Kyle; Camporesi, Tiziano; Cankocak, Kerem; Carrell, Kenneth Wayne; Cerci, Salim; Chendvankar, Sanjay; Chung, Yeon Sei; Clarida, Warren; Cremaldi, Lucien Marcus; Cushman, Priscilla; Damgov, Jordan; De Barbaro, Pawel; Debbins, Paul; Deliomeroglu, Mehmet; Demianov, A; de Visser, Theo; Deshpande, Pandurang Vishnu; Díaz, Jonathan; Dimitrov, Lubomir; Dugad, Shashikant; Dumanoglu, Isa; Duru, Firdevs; Efthymiopoulos, I; Elias, John E; Elvira, D; Emeliantchik, Igor; Eno, Sarah Catherine; Ershov, Alexander; Erturk, Sefa; Esen, Selda; Eskut, Eda; Fenyvesi, Andras; Fisher, Wade Cameron; Freeman, Jim; Ganguli, Som N; Gaultney, Vanessa; Gamsizkan, Halil; Gavrilov, Vladimir; Genchev, Vladimir; Gleyzer, Sergei V; Golutvin, Igor; Goncharov, Petr; Grassi, Tullio; Green, Dan; Gribushin, Andrey; Grinev, B; Gurtu, Atul; Murat Güler, A; Gülmez, Erhan; Gümüs, K; Haelen, T; Hagopian, Sharon; Hagopian, Vasken; Halyo, Valerie; Hashemi, Majid; Hauptman, John M; Hazen, Eric; Heering, Arjan Hendrix; Heister, Arno; Hunt, Adam; Ilyina, N; Ingram, D; Isiksal, Engin; Jarvis, Chad; Jeong, Chiyoung; Johnson, Kurtis F; Jones, John; Kaftanov, Vitali; Kalagin, Vladimir; Kalinin, Alexey; Kalmani, Suresh Devendrappa; Karmgard, Daniel John; Kaur, Manjit; Kaya, Mithat; Kaya, Ozlem; Kayis-Topaksu, A; Kellogg, Richard G; Khmelnikov, Alexander; Kim, Heejong; Kisselevich, I; Kodolova, Olga; Kohli, Jatinder Mohan; Kolossov, V; Korablev, Andrey; Korneev, Yury; Kosarev, Ivan; Kramer, Laird; Krinitsyn, Alexander; Krishnaswamy, Marthi Ramaswamy; Krokhotin, Andrey; Kryshkin, V; Kuleshov, Sergey; Kumar, Arun; Kunori, Shuichi; Laasanen, Alvin T; Ladygin, Vladimir; Laird, Edward; Landsberg, Greg; Laszlo, Andras; Lawlor, C; Lazic, Dragoslav; Lee, Sang Joon; Levchuk, Leonid; Linn, Stephan; Litvintsev, Dmitri; Lobolo, L; Los, Serguei; Lubinsky, V; Lukanin, Vladimir; Ma, Yousi; Machado, Emanuel; Maity, Manas; Majumder, Gobinda; Mans, Jeremy; Marlow, Daniel; Markowitz, Pete; Martínez, German; Mazumdar, Kajari; Merlo, Jean-Pierre; Mermerkaya, Hamit; Mescheryakov, G; Mestvirishvili, Alexi; Miller, Michael; Möller, A; Mohammadi-Najafabadi, M; Moissenz, P; Mondal, Naba Kumar; Mossolov, Vladimir; Nagaraj, P; Narasimham, Vemuri Syamala; Norbeck, Edwin; Olson, Jonathan; Onel, Yasar; Onengüt, G; Ozkan, Cigdem; Ozkurt, Halil; Ozkorucuklu, Suat; Ozok, Ferhat; Paktinat, S; Pal, Andras; Patil, Mandakini Ravindra; Penzo, Aldo; Petrushanko, Sergey; Petrosian, A; Pikalov, Vladimir; Piperov, Stefan; Podrasky, V; Polatoz, A; Pompos, Arnold; Popescu, Sorina; Posch, C; Pozdnyakov, Andrey; Qian, Weiming; Ralich, Robert; Reddy, L; Reidy, Jim; Rogalev, Evgueni; Roh, Youn; Rohlf, James; Ronzhin, Anatoly; Ruchti, Randy; Ryazanov, Anton; Safronov, Grigory; Sanders, David A; Sanzeni, Christopher; Sarycheva, Ludmila; Satyanarayana, B; Schmidt, Ianos; Sekmen, Sezen; Semenov, Sergey; Senchishin, V; Sergeyev, S; Serin, Meltem; Sever, Ramazan; Singh, B; Singh, Jas Bir; Sirunyan, Albert M; Skuja, Andris; Sharma, Seema; Sherwood, Brian; Shumeiko, Nikolai; Smirnov, Vitaly; Sogut, Kenan; Sonmez, Nasuf; Sorokin, Pavel; Spezziga, Mario; Stefanovich, R; Stolin, Viatcheslav; Sudhakar, Katta; Sulak, Lawrence; Suzuki, Ichiro; Talov, Vladimir; Teplov, Konstantin; Thomas, Ray; Tonwar, Suresh C; Topakli, Huseyin; Tully, Christopher; Turchanovich, L; Ulyanov, A; Vanini, A; Vankov, Ivan; Vardanyan, Irina; Varela, F; Vergili, Mehmet; Verma, Piyush; Vesztergombi, Gyorgy; Vidal, Richard; Vishnevskiy, Alexander; Vlassov, E; Vodopiyanov, Igor; Volobouev, Igor; Volkov, Alexey; Volodko, Anton; Wang, Lei; Werner, Jeremy Scott; Wetstein, Matthew; Winn, Dave; Wigmans, Richard; Whitmore, Juliana; Wu, Shouxiang; Yazgan, Efe; Yetkin, Taylan; Zálán, Peter; Zarubin, Anatoli; Zeyrek, Mehmet

    2008-01-01

    The CMS hadron calorimeter is a sampling calorimeter with brass absorber and plastic scintillator tiles with wavelength shifting fibres for carrying the light to the readout device. The barrel hadron calorimeter is complemented with an outer calorimeter to ensure high energy shower containment in the calorimeter. Fabrication, testing and calibration of the outer hadron calorimeter are carried out keeping in mind its importance in the energy measurement of jets in view of linearity and resolution. It will provide a net improvement in missing $\\et$ measurements at LHC energies. The outer hadron calorimeter will also be used for the muon trigger in coincidence with other muon chambers in CMS.

  19. Sistema limpo em linha para extração em fase sólida de contaminantes emergentes em águas naturais An in-line clean system for the solid-phase extraction of emerging contaminants in natural waters

    Directory of Open Access Journals (Sweden)

    Fernando F. Sodré

    2010-01-01

    Full Text Available A solid-phase in-line extraction system for water samples containing low levels of emerging contaminants is described. The system was specially developed for large volume samples (up to 4 L using commercial solid-phase extraction (SPE cartridges. Four sets containing PTFE-made connectors, brass adapters and ball valves were used to fit SPE cartridges and sample bottles to a 4-port manifold attached to a 20 L carboy. A lab-made vacuum device was connected to the manifold cap. The apparatus is robust and less expensive than the typical available system. Its also provides less experimental handling, avoiding cross contamination and sample losses.

  20. Condensers

    International Nuclear Information System (INIS)

    Andrieux, M.B.

    1984-01-01

    Characteristics of the condenser cooling waters of various French 900 MW nuclear power plants. Design and description of various types of condensers: condensers feeded directly with river water, condensers feeded by cooling towers, condensers feeded with sea water of brackish water. Presentation of the main problems encountered with the brass bundles (ammoniacal corrosion, erosion of the peripheral tubes, vibrations of the tubes), with the titanium bundles, with the tubular plates, the tubes-tubular plates assemblies, the coatings of the condenser water chamber (sea water), the vapor by-pass and with the air inlet. Analysis of the in service performances such as condensation pressure, oxygen content and availability [fr

  1. Effect of gas ratio on tribological properties of sputter deposited TiN coatings

    Energy Technology Data Exchange (ETDEWEB)

    Chavda, Mahesh R., E-mail: maheshchavda1990@gmail.com [Department of Mechanical Engineering, Dr. Jivraj Mehta Institute of Technology, Mogar-388340 (India); Chauhan, Kamlesh V.; Rawal, Sushant K., E-mail: sushantrawal.me@charusat.ac.in [CHAMOS Matrusanstha Department of Mechanical Engineering, Chandubhai S. Patel Institute of Technology, Charotar University of Science and Technology (CHARUSAT), Changa-388421 (India)

    2016-05-06

    Titanium nitride (TiN) coatings were deposited on Si, corning glass, pins of mild steel (MS, ϕ3mm), aluminium (Al, ϕ4mm) and brass (ϕ6mm) substratesby DC magnetron sputtering. The argon and nitrogen (Ar:N{sub 2})gas ratio was precisely controlled by Mass Flow Controller (MFC) and was varied systematically at diffract values of 10:10,12:08, 16:04 and 18:02sccm. The structural properties of TiN coatings were characterized by X-ray diffraction (XRD) and its surface topography was studied using field emission scanning electron microscopy (FE-SEM). The tribological properties of TiN coatings were investigated using pin-on-disc tribometer.

  2. Queering gender in contemporary female Bildung narrative

    Directory of Open Access Journals (Sweden)

    Šnircová Soňa

    2015-09-01

    Full Text Available The paper explores, in the context of feminist discussions about the Bildungsroman, a contemporary British novel that offers shocking images of female coming of age at the turn of the millennium. Queering gender and introducing male elements into the heroine’s process of maturation, the analysed novel appears to raise questions about the continuous relevance of the feminist distinction between male and female version of the genre. The paper however argues that although significantly rewriting both female Bildung and pornographic narratives, Helen Walsh’s Brass can still be read as a variation of the female Bildungsroman and an example of its contemporary developments.

  3. Copper and nickel alloys and titanium for seawater applications

    International Nuclear Information System (INIS)

    Richter, H.

    1977-01-01

    Copper and nickel alloys and titanium have been successfully used for heat exchangers on ships, in power plants and for chemical apparatus and piping systems because of their resistance against corrosion in sea water. Aluminium brass and copper nickel alloys, the standard materials for condensers and coolers, however, may be attacked, the corrosion depending on water quality, water velocity, and structural conditions. The mechanisms of corrosion are discussed. Under severe conditions the use of titanium may be indicated. The use of nickel base alloys is advantageous at elevated temperatures, e.g. for chemical reactions and for evaporation processes. Examples are given for application and for prevention of corrosion. (orig.) [de

  4. Physical and chemical factors affecting sludge consolidation

    Energy Technology Data Exchange (ETDEWEB)

    Turner, C.W.; Blimkie, M.E.; Lavoie, P.A

    1997-09-01

    Chemical reactions between sludge components and precipitation reactions within the pores of the existing sludge are shown to contribute to the consolidation of sludge under steam generator operating conditions. Simulations of sludge representative of plants with a mixed iron/copper feedtrain suggest that as the conditions in the feedtrain become more oxidizing the sludge will become harder with a higher nickel ferrite content. The precipitation of feedwater impurities introduced by condenser leaks and of zinc silicate, which is produced in plants with brass condenser tubes and silica in the makeup water, contribute significantly to sludge consolidation. Sodium phosphate is also shown to be an agent of sludge consolidation. (author)

  5. Corrosion behaviour of metals and alloys in the waters of the Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Sawant, S.S.; Wagh, A.B.

    1987 to November 1988. Experimental method Panels sized lOx6cm were cut from sheets of commercial-grade mild steel (C 0.20%. Si 0.05%, Mn 0.26%, P 0.052%, S 0.04%, Fe the rest), brass (Zn 32.55%, Cu the rest), aluminium (Si 0.15%, Mn 0.8%, Ai the rest... with the help of pvc nuts, bolts and washers. These cages were maintained at two different depths with the help of a deep-sea mooring system used for sediment traps. The depths under study were lOOOm and 2400m at a station in the Western Arabian Sea (WAST, 16...

  6. The 'Stolpersteine' and the Commemoration of Life, Death, and Government

    DEFF Research Database (Denmark)

    Östman, Lars

    of the victims. The Stolpersteine are made out of cement and with a ‘HIER WOHNTE’ engraved on the brass plate on top of the stone they indicate where the individual victim lived; name, day of birth and death as well as the victim’s fate is also engraved on the stone. The Stolpersteine are installed not only...... the integrity of the homes of current residents. The Stolpersteine wish to restore the victims’s dignity via the use of legal, ethical, and religious categories; hence, through the Stolpersteine the factual past seems to be normalized using the same principles from the state of law which the Third Reich...

  7. Dry decontamination for tritiated wastes

    International Nuclear Information System (INIS)

    Shi Zhengkun; Wu Tao; Dan Guiping; Xie Yun

    2009-01-01

    To aim at decontamination of tritiated wastes, we have developed and fabricated a dry tritium decontamination system, which is designed to reduce tritium surface contamination of various alloy by UV, ozone and heating. The result indicates that the elevation of temperature can obviously improve decontamination effect. With 3 h irradiation by 365 nm UV at 220 degree C, it has a decontamination rate of 99% to stainless steel surface. Ozone can more obviously improve decontamination effect when metal was heated. Ozone has a decontamination effect beyond 95% to stainless steel, aluminum and brass at 220 degree C. Tritium surface concentration of metal has a little increase after decontamination. (authors)

  8. Air-Leak Effects on Ear-Canal Acoustic Absorbance

    Science.gov (United States)

    Rasetshwane, Daniel M.; Kopun, Judy G.; Gorga, Michael P.; Neely, Stephen T.

    2015-01-01

    Objective: Accurate ear-canal acoustic measurements, such as wideband acoustic admittance, absorbance, and otoacoustic emissions, require that the measurement probe be tightly sealed in the ear canal. Air leaks can compromise the validity of the measurements, interfere with calibrations, and increase variability. There are no established procedures for determining the presence of air leaks or criteria for what size leak would affect the accuracy of ear-canal acoustic measurements. The purpose of this study was to determine ways to quantify the effects of air leaks and to develop objective criteria to detect their presence. Design: Air leaks were simulated by modifying the foam tips that are used with the measurement probe through insertion of thin plastic tubing. To analyze the effect of air leaks, acoustic measurements were taken with both modified and unmodified foam tips in brass-tube cavities and human ear canals. Measurements were initially made in cavities to determine the range of critical leaks. Subsequently, data were collected in ears of 21 adults with normal hearing and normal middle-ear function. Four acoustic metrics were used for predicting the presence of air leaks and for quantifying these leaks: (1) low-frequency admittance phase (averaged over 0.1–0.2 kHz), (2) low-frequency absorbance, (3) the ratio of compliance volume to physical volume (CV/PV), and (4) the air-leak resonance frequency. The outcome variable in this analysis was the absorbance change (Δabsorbance), which was calculated in eight frequency bands. Results: The trends were similar for both the brass cavities and the ear canals. ΔAbsorbance generally increased with air-leak size and was largest for the lower frequency bands (0.1–0.2 and 0.2–0.5 kHz). Air-leak effects were observed in frequencies up to 10 kHz, but their effects above 1 kHz were unpredictable. These high-frequency air leaks were larger in brass cavities than in ear canals. Each of the four predictor variables

  9. Spalling fracture of metals and alloys under intense x-radiation

    International Nuclear Information System (INIS)

    Molitvin, A.M.

    2001-01-01

    Creation of different power and irradiating installations assisted in studying mechanical properties of structural materials under the effect of high-power radiation fluxes: laser, electron, X-ray, ion beam etc. There are being widely investigated such phenomena as surface and deep hardening of metals and alloys under irradiation, generation of elastic and shock waves, materials failure under thermal shock etc.In the paper there are discussed the results of long researches of spalling fracture of materials and alloys under intense X-radiation. Model assemblies with consequently arranged samples (foils) of metals and alloys under investigation underwent pulse X-radiation. The energy flux of X-radiation was weakened to the needed value by dose filters intensively absorbing soft spectrum of X-radiation. At carrying out the researches the foils of copper, nickel, titanium, brass, bronze, molybdenum, tungsten, tantalum, cadmium, lead, zinc, silver and steels 0.005-1 mm thick were used as objects under investigation. The samples diameter (10-16 mm) was chosen to be quite large as compared to their thickness so that the side load does not affect the central part of the samples and the front (looking the source of X-radiation) and back (shadow) surfaces of the samples are free what makes it possible to consider the processes of spalling fracture in one-dimensional approximation. Within the frames of kinetic approach to the problem of solid states spalling fracture under pulse loading that considers fracture as progressing in time process there were found spalling fracture time dependencies of lead, cadmium, zinc, silver, copper, brass, bronze, nickel, titanium, molybdenum, tungsten, tantalum and steels under thermal shock initiated by X-radiation. It was demonstrated that longevity of metals and alloys under thermal shock exponentially decreases with the growth of rupture stresses amplitude and can be described in terms of kinetic concept of strength.Within the frames of

  10. Evaluation of biocidal efficacy of copper alloy coatings in comparison with solid metal surfaces: generation of organic copper phosphate nanoflowers.

    Science.gov (United States)

    Gutierrez, H; Portman, T; Pershin, V; Ringuette, M

    2013-03-01

    To analyse the biocidal efficacy of thermal sprayed copper surfaces. Copper alloy sheet metals containing >60% copper have been shown to exhibit potent biocidal activity. Surface biocidal activity was assessed by epifluorescence microscopy. After 2-h exposure at 20 °C in phosphate-buffered saline (PBS), contact killing of Gram-negative Escherichia coli and Gram-positive Staphylococcus epidermidis by brass sheet metal and phosphor bronze was 3-4-times higher than that by stainless steel. SEM observations revealed that the surface membranes of both bacterial strains were slightly more irregular when exposed to brass sheet metal than stainless steel. However, when exposed to phosphor bronze coating, E. coli were 3-4 times larger with irregular membrane morphology. In addition, the majority of the cells were associated with spherical carbon-copper-phosphate crystalline nanostructures characteristic of nanoflowers. The membranes of many of the S. epidermidis exhibited blebbing, and a small subset was also associated with nanoflowers. Our data indicate that increasing the surface roughness of copper alloys had a pronounced impact on the membrane integrity of Gram-positive and, to a lesser degree, Gram-negative bacteria. In the presence of PBS, carbon-copper-phosphate-containing nanoflowers were formed, likely nucleated by components derived from killed bacteria. The intimate association of the bacteria with the nanoflowers and phosphor bronze coating likely contributed to their nonreversible adhesion. Thermal spraying of copper alloys provides a strategy for the rapid coating of three-dimensional organic and inorganic surfaces with biocidal copper alloys. Our study demonstrates that the macroscale surface roughness generated by the thermal spray process enhances the biocidal activity of copper alloys compared with the nanoscale surface roughness of copper sheet metals. Moreover, the coating surface topography provides conditions for the rapid formation of organic copper

  11. Grain structure, texture and mechanical property evolution of automotive aluminium sheet during high power ultrasonic welding

    International Nuclear Information System (INIS)

    Haddadi, Farid; Tsivoulas, Dimitrios

    2016-01-01

    High power ultrasonic spot welding (HPUSW) is a joining technique which is performed within less than a second and provides a more energy-efficient alternative to friction stir spot welding (FSSW), which is considered a longer cycle manufacturing process for joining automotive alloys. To date, only a few reports exist on the deformation mechanisms that take place during high power ultrasonic spot welding. In this work, dynamic recrystallization and grain growth were examined using electron backscatter diffraction (EBSD). HPUSW causes extensive deformation within the weld zone where the temperature increases to 440 °C. An ultra-fine grain structure was observed in a thin band of flat weld interface within a short welding time of 0.10 s. With increasing welding time the interface was displaced and ‘folds’ or ‘crests’ appeared together with shear bands. The weld interface progressively changed from flat to sinusoidal and eventually to a convoluted wave-like pattern when the tool fully penetrated the workpiece, having a wavelength of ~ 1 mm after 0.40 s. Finally, the microstructure and texture varied significantly depending on the location within the weld. Although the texture near the weld interface was relatively weak, a shift was observed with increasing welding time from an initially Cube-dominated texture to one where the typical β-fibre Brass component prevailed. - Highlights: •Lap shear strength of ~2.9 kN was achieved in 0.30 sec welding time. •Temperature approached 440 °C along the weld centreline for the highest welding time. •The texture near the teeth was dominated by Brass, P and S components at optimum condition. •The weld interface showed typical β-fibre deformation texture at optimum condition.

  12. Mechanical and thermal behavior of a prototype support structure for a large silicon vertex detector (BCD)

    International Nuclear Information System (INIS)

    Mulderink, H.; Michels, N.; Joestlein, H.

    1989-01-01

    The Bottom Collider Detector (BCD) has been proposed as a device to study large numbers of events containing B mesons. To identify secondary vertices in hadronic events it will employ the most ambitious silicon strip tracking detector proposed to-date. This report will discuss results from measurements on a first mechanical/thermal model of the vertex detector support structure. The model that was built and used for the studies described here is made of brass. Brass was used because it is readily available and easily assembled by soft soldering, and, for appropriate thicknesses, it will behave similarly to the beryllium that will be used in the actual detector. The trough was built to full scale with the reinforcement webbing and the cooling channels in place. There were no detector modules in place. We plan, however, to install modules in the trough in the future. The purpose of the model was to address two concerns that have arisen about the proposed structure of the detector. The first is whether or not the trough will be stable enough. The trough must be very light in weight yet have a high degree of rigidity. Because of the 3m length of the detector there is question as to the stiffness of the proposed trough. The main concern is that there will sagging or movement of the trough in the middle region. The second problem is the heat load. There will be a great deal of heat generated by the electronics attached to the detector modules. So the question arises as to whether or not the silicon detectors can be kept cool enough so that when the actual experiment is run the readings will be valid. The heat may also induce motion by differential expansion of support components. 26 figs

  13. Magnetic resonance visualization of conductive structures by sequence-triggered direct currents and spin-echo phase imaging

    Energy Technology Data Exchange (ETDEWEB)

    Eibofner, Frank; Wojtczyk, Hanne; Graf, Hansjörg, E-mail: hansjoerg.graf@med.uni-tuebingen.de, E-mail: drGraf@t-online.de [Section on Experimental Radiology, University Hospital Tübingen, Tübingen D-72076 (Germany); Clasen, Stephan [Department of Diagnostic and Interventional Radiology, University Hospital Tübingen, Tübingen D-72076 (Germany)

    2014-06-15

    Purpose: Instrument visualization in interventional magnetic resonance imaging (MRI) is commonly performed via susceptibility artifacts. Unfortunately, this approach suffers from limited conspicuity in inhomogeneous tissue and disturbed spatial encoding. Also, susceptibility artifacts are controllable only by sequence parameters. This work presents the basics of a new visualization method overcoming such problems by applying sequence-triggered direct current (DC) pulses in spin-echo (SE) imaging. SE phase images allow for background free current path localization. Methods: Application of a sequence-triggered DC pulse in SE imaging, e.g., during a time period between radiofrequency excitation and refocusing, results in transient field inhomogeneities. Dependent on the additional z-magnetic field from the DC, a phase offset results despite the refocusing pulse. False spatial encoding is avoided by DC application during periods when read-out or slice-encoding gradients are inactive. A water phantom containing a brass conductor (water equivalent susceptibility) and a titanium needle (serving as susceptibility source) was used to demonstrate the feasibility. Artifact dependence on current strength and orientation was examined. Results: Without DC, the brass conductor was only visible due to its water displacement. The titanium needle showed typical susceptibility artifacts. Applying triggered DC pulses, the phase offset of spins near the conductor appeared. Because SE phase images are homogenous also in regions of persistent field inhomogeneities, the position of the conductor could be determined with high reliability. Artifact characteristic could be easily controlled by amperage leaving sequence parameters unchanged. For an angle of 30° between current and static field visualization was still possible. Conclusions: SE phase images display the position of a conductor carrying pulsed DC free from artifacts caused by persistent field inhomogeneities. Magnitude and phase

  14. Grain structure, texture and mechanical property evolution of automotive aluminium sheet during high power ultrasonic welding

    Energy Technology Data Exchange (ETDEWEB)

    Haddadi, Farid, E-mail: farid.haddadi@gmail.com [Clemson University–International Center for Automotive Research (CU-ICAR), #347, 4 Research Drive, Greenville, SC 29607 (United States); School of Materials, The University of Manchester, Oxford Road, Manchester M13 9PL (United Kingdom); Tsivoulas, Dimitrios, E-mail: dim.tsivoulas@gmail.com [School of Materials, The University of Manchester, Oxford Road, Manchester M13 9PL (United Kingdom); Clean Energy/Nuclear Services, Amec Foster Wheeler, 601 Faraday Street, Birchwood Park, Warrington WA3 6GN (United Kingdom)

    2016-08-15

    High power ultrasonic spot welding (HPUSW) is a joining technique which is performed within less than a second and provides a more energy-efficient alternative to friction stir spot welding (FSSW), which is considered a longer cycle manufacturing process for joining automotive alloys. To date, only a few reports exist on the deformation mechanisms that take place during high power ultrasonic spot welding. In this work, dynamic recrystallization and grain growth were examined using electron backscatter diffraction (EBSD). HPUSW causes extensive deformation within the weld zone where the temperature increases to 440 °C. An ultra-fine grain structure was observed in a thin band of flat weld interface within a short welding time of 0.10 s. With increasing welding time the interface was displaced and ‘folds’ or ‘crests’ appeared together with shear bands. The weld interface progressively changed from flat to sinusoidal and eventually to a convoluted wave-like pattern when the tool fully penetrated the workpiece, having a wavelength of ~ 1 mm after 0.40 s. Finally, the microstructure and texture varied significantly depending on the location within the weld. Although the texture near the weld interface was relatively weak, a shift was observed with increasing welding time from an initially Cube-dominated texture to one where the typical β-fibre Brass component prevailed. - Highlights: •Lap shear strength of ~2.9 kN was achieved in 0.30 sec welding time. •Temperature approached 440 °C along the weld centreline for the highest welding time. •The texture near the teeth was dominated by Brass, P and S components at optimum condition. •The weld interface showed typical β-fibre deformation texture at optimum condition.

  15. Selective Leaching of Gray Cast Iron: Electrochemical Aspects

    International Nuclear Information System (INIS)

    Na, Kyung Hwan; Yun, Eun Sub; Park, Young Sheop

    2010-01-01

    Currently, to keep step with increases in energy consumption, much attention has been paid to the construction of new nuclear power plants (NPPs) and to the continued operation of NPPs. For continued operation, the selective leaching of materials should be evaluated by visual inspections and hardness measurements as a part of One-Time Inspection Program according to the requirements of the guidelines for continued operation of pressured water reactors (PWRs) in Korea and license renewals in the United States, entitled the 'Generic Aging Lessons Learned (GALL) report.' However, the acceptance criteria for hardness have yet to be provided. Recently, USNRC released a new draft of the GALL report for comment and plans to publish its formal version by the end of 2010. In the new draft, the quantitative acceptance criteria for hardness are given at last: no more than a 20 percent decrease in hardness for gray cast iron and brass containing more than 15 percent zinc. Selective leaching is the preferential removal of one of the alloying elements from a solid alloy by corrosion processes, leaving behind a weakened spongy or porous residual structure. The materials susceptible to selective leaching include gray cast iron and brass, which are mainly used as pump casings and valve bodies in the fire protection systems of NPPs. Since selective leaching proceeds slowly during a long period of time and causes a decrease in strength without changing the overall dimensions of original material, it is difficult to identify. In the present work, the selective leaching of gray cast iron is investigated in terms of its electrochemical aspects as part of an ongoing research project to study the changes in metal properties by selective leaching

  16. Comparison of conventional Injection Mould Inserts to Additively Manufactured Inserts using Life Cycle Assessment

    DEFF Research Database (Denmark)

    Hofstätter, Thomas; Bey, Niki; Mischkot, Michael

    2016-01-01

    Polymer Additive Manufacturing can be used to produce soft tooling inserts for injection moulding. Compared to conventional tooling, the energy and time consumption during production are significantly lower. As the life time of such inserts is significantly shorter than the life time of traditional...... of their potential environmental impact and yield throughout the development and pilot phase. Insert geometry is particularly advantageous for pilot production and small production sizes. In this research, Life Cycle Assessment is used to compare the environmental impact of soft tooling by Additive Manufacturing...... (using Digital Light Processing) and three traditional methods for the manufacture of inserts (milling of brass, steel, and aluminium) for injection moulds during the pre-production phase....

  17. Radiation of Sawtooth Waves from the End of an Open Pipe

    Science.gov (United States)

    Bakaitis, Rachael; Bodon, Josh; Gee, Kent; Thomas, Derek

    2012-10-01

    It is known, that because of nonlinear propagation distortion, a sinusoidal wave is transformed into a sawtooth-like wave as it travels through a pipe. It has been observed that the sawtooth wave, when measured immediately after it exits a pipe, has a form similar to a delta function. Currently this behavior is not understood, but has potential application to radiation of sound from brass instruments and rocket motors. Building on previous work in the 1970s by Blackstock and Wright, the purpose of the current research is to better understand the radiation of sawtooth waves from the open end of a circular pipe. Nonlinear propagation theory, the experimental apparatus and considerations, and some preliminary results are described.

  18. Anticorrosive Performance of Zinc Phosphate Coatings on Mild Steel Developed Using Galvanic Coupling

    Directory of Open Access Journals (Sweden)

    M. Arthanareeswari

    2013-01-01

    Full Text Available The anticorrosive performance of zinc phosphate coatings developed by galvanic coupling technique on mild steel substrates using the cathode materials such as titanium (Ti, copper (Cu, brass (BR, nickel (Ni, and stainless steel (SS is elucidated in this study. Thermal and chemical stability tests, immersion test in 3.5% NaCl, ARE salt droplet test, and salt spray test were carried out. The study reveals that the mild steel substrates phosphated under galvanically coupled condition showed better corrosion resistance than the one coated without coupling. The open circuit potential (OCP of phosphated mild steel panels in 3.5% NaCl was found to be a function of phosphate coating weight and porosity of the coating.

  19. Application of risk analysis and quality control methods for improvement of lead molding process

    Directory of Open Access Journals (Sweden)

    H. Gołaś

    2016-10-01

    Full Text Available The aim of the paper is to highlight the significance of implication of risk analysis and quality control methods for the improvement of parameters of lead molding process. For this reason, Fault Mode and Effect Analysis (FMEA was developed in the conceptual stage of a new product TC-G100-NR. However, the final product was faulty (a complete lack of adhesion of brass insert to leak regardless of the previously defined potential problem and its preventive action. It contributed to the recognition of root causes, corrective actions and change of production parameters. It showed how these methods, level of their organization, systematic and rigorous study affect molding process parameters.

  20. Spectrum diagnoses of laser plasma in 'ablation mode' laser propulsion

    International Nuclear Information System (INIS)

    Zhang Ling; Tang Zhiping; Tong Huifeng; Su Maogen; Xue Simin

    2007-01-01

    The propellant materials (LY12 aluminium, No.45 steel, H62 brass, graphite, polyvinyl chloride, polyoxymethylene) in laser propulsion are ablated by a Nd: YAG laser (1.06 μm, 10 ns). The space-resolved and the power density-depended emission spectrums of aluminum and copper plasma are recorded and analyzed. Under the local thermo equilibrium assumption, the electronic temperature and density as well as the average intensity of ionization from the relative intensity of characteristic spectrum for aluminum are obtained. Their dependence on laser power-density and spatial variation are also investigated. The ablation imagines (the ejected plumes) of the six materials in vacuum are obtained and discussed by using a B shutter camera. (authors)