The results of studies performed for the development of a new process of the thermal cracking of tar as a suspension with ground Baltic oil shale in order to obtain motor fuel components are reported. The experimental results suggest undoubted advantages of the process over industrial thermal cracking because the deep degradation of tar (the yields of a gasoline fraction with bp to 180?C, middle distillates with bp of 180?360?C, and feedstock for catalytic cracking with bp of 360?520?C were ~12, 43?44, and ~15?16 wt % on an initial tar basis) was achieved upon the single-stage processing of the raw material under relatively mild conditions (5 MPa, 425?C, and a feed space velocity of 1.0 h?1). The resulting coke-like products and V and Ni contained in the raw material were deposited on the ...
Last year, 1991, was a difficult one for Finland's oil and chemicals company, Neste Corporation. The sharp fall in the international price of chemicals products had a significant impact on the corporation's overall result. Neste was, however, able to improve its competitive position, move ahead with numerous investments, and develop new businesses. This was particularly evident in two areas that have received significant emphasis within Neste in recent years: oil exploration and the Baltic region where a network of modern service stations in Neste livery and stretching from Vyborg on the Finnish-Russian border, through St. Petersburg, Tallinn, and the Balticcountries to Warsaw, is currently taking shape. The majority of the western-style stations in this network will be located along the route of the M12 highway, which has been dubbed the Via Baltica.
The investigations carried out on Alloy 800 in aqueous high-temperature environments in France as well as in other countries are reviewed. These studies are mainly concerned with nuclear industry where Alloy 800 can be used as structural material for steam generators of PWR, breeders or HTR. As results referred to in the literature on cracking in caustic environmens do not always agree, a discussion is presented on the matter. The behaviour of Alloy 800 in superheated steam is examined. (Auth.).
Sprat Sprat in the Southwestern Baltic Sea (including Sound and Belt Sea) ...episodic salt water inflows which occur during autumn to spring.The last major inflow to the Baltic Proper ...The small inflows in spring 1986 and fall 1988 have had only effects on salinity and temperature
By August 2007, there were 438 nuclear power plants (NPPs) in operation worldwide, with a total capacity of 371.7 GW(e). Further, 31 units, totaling 24.1 GW(e), were under construction. During 2006 nuclear power produced 2659.7 billion kWh of electricity, which was 15.2% of the world's total. The vast majority of these plants use water-cooled reactors. Based on information provided by its Member States, the IAEA projects that nuclear power will grow significantly, producing between 2760 and 2810 billion kWh annually by 2010, between 3120 and 3840 billion kWh annually by 2020, and between 3325 and 5040 billion kWh annually by 2030. There are several reasons for these rising expectations for nuclear power: - Nuclear power's lengthening experience and good performance: The industry now has more than 12 000 reactor years of experience, and the global average nuclear plant availability during 2006 reached 83%; - Growing energy needs: All forecasts project increases in world energy demand, ...
By August 2007, there were 438 nuclear power plants (NPPs) in operation worldwide, with a total capacity of 371.7 GW(e). Further, 31 units, totaling 24.1 GW(e), were under construction. During 2006 nuclear power produced 2659.7 billion kWh of electricity, which was 15.2% of the world's total. The vast majority of these plants use water-cooled reactors. Based on information provided by its Member States, the IAEA projects that nuclear power will grow significantly, producing between 2760 and 2810 billion kWh annually by 2010, between 3120 and 3840 billion kWh annually by 2020, and between 3325 and 5040 billion kWh annually by 2030. There are several reasons for these rising expectations for nuclear power: - Nuclear power's lengthening experience and good performance: The industry now has more than 12 000 reactor years of experience, and the global average nuclear plant availability during 2006 reached 83%; - Growing energy needs: All forecasts project increases in world energy demand, ...
By August 2007, there were 438 nuclear power plants (NPPs) in operation worldwide, with a total capacity of 371.7 GW(e). Further, 31 units, totaling 24.1 GW(e), were under construction. During 2006 nuclear power produced 2659.7 billion kWh of electricity, which was 15.2% of the world's total. The vast majority of these plants use water-cooled reactors. Based on information provided by its Member States, the IAEA projects that nuclear power will grow significantly, producing between 2760 and 2810 billion kWh annually by 2010, between 3120 and 3840 billion kWh annually by 2020, and between 3325 and 5040 billion kWh annually by 2030. There are several reasons for these rising expectations for nuclear power: - Nuclear power's lengthening experience and good performance: The industry now has more than 12 000 reactor years of experience, and the global average nuclear plant availability during 2006 reached 83%; - Growing energy needs: All forecasts project increases in world energy demand, ...
We carried out a feeding study in rats aimed at extending our aboservations of contaminant-induced immunosuppression in harbour seals. Two herring batches were freeze-dried, supplemented and fed to female adult PVG rats for a period of 4 1/2 months. Daily contaminant intakes of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) toxic equivalents (TEQ) were estimated to be 0.3 ng/kg body weight and 1.6 ng/kg in the Atlantic and Baltic groups, respectively. At the end of the feeding experiment, no contaminant-related changes in spleen CD{sub 4}{sup +}/CD{sub 8}{sup +} cellularity, natural killer cell activity, or mitogen-induced proliferative responses of thymus or spleen cells could be detected. However, total thymocyte numbers and thymus CD{sub 4}{sup +}/CD{sub 8}{sup +} ratios were reduced in the Baltic group. A novel model was established to assess the specific T-cell response to rat cytomegalovirus (RCMV). When applied to the feeding study, no ...
We have done analysis of elements in the Baltic sea sediment by using gamma spectrometry in neutron activation analysis Goal of the analysis is to determine the rate of morsel elements which is contained in the Baltic sea sediment. Sample of the Baltic sea Sediment (IAEA-SED-1), Standard of Reference Material (SRM) 1646 Estuarine Sediment and Standard Ce, Fe, Sc, and Co are put into vial of capsule rabbit, then irradiated together for 30 minutes in rabbit facility Multi Purpose Reactor at power of 25 MW and then cooled for one week. Next sample, standard, and SRM which have irradiated, each is cut for 30 minutes using gamma spectrometer. Result of analysis of rate of elements Ce, Fe, Sc and Co in the baltic sea sediment successively equal to 141.20 ppm, 5.91 %, 14.88 ppm, and 19.59 ppm. Result of analysis in SRM Estuarine sediment successively equal to 96.60 ppm, 3.21 %, 10.25 ppm, and 9.63 ppm. Result ...
After a brief review of the degradations occurring on tubes of Inconel 600 in steam generators of PWR power stations emphasis is put on the conditioning of the secondary water and more particularly on the condensate treatment in the units of Doel which work on heavily polluted brackish water. The important role of non-destructive testing and eddy-current testing is also pointed out, method developed by Laborelec. The operational experience shows that Belgian stations are nearly not concerned by the degradations mostly found in power stations in other countries which shows the efficiency of the conditioning of the secondary water. On the other hand, other problems have occurred, resulting from: damage caused by foreign objects; fouling of tube before commissioning, cracking of bends and at the limit of the dudgeoning and leaking plugs. (AF).
Work at Institutt for energiteknikk (IFE) comprises both nuclear and non-nuclear activities. The main nuclear program is centered on the Halden Reactor Project. In 1958, the first Halden Reactor Project Agreement was signed by organisations representing 12 European countries. During 1994 France became a full member and associate membership was established with Russia. Accordingly, 16 countries were participating in the Project by the end of the year. The objectives have evolved from being simply a demonstration of the operation of a boiling heavy-water reactor to becoming a substantial research and development programme covering the domains of human-machine interaction, fuel behaviour, materials testing, water chemistry, and instrumentation. In 1994, significant progress was achieved in all of the areas addressed by the project, including the re-instrumentation of irradiated fuel rods, fission gas release, irradiation-assisted stress corrosion ...
This paper reports the results of in situ observation of fatigue crack growth in a ferrite?pearlite steel. Stress intensity factor range (?K) decreasing/increasing and constant-?K fatigue tests have been carried out. In banded pearlite orientation, intense crack branching was observed which leads to fatigue crack retardation. Crack closure during the test was monitored to understand the fatigue crack growth behaviour.
The new Code Case to substitute the allowable crack angle for a circumferential surface crack in 'Rules on Fitness-for-Service (FFS)' published from The Japan Society of Mechanical Engineers (JSME). Until now, the angle of a circumferential surface crack was limited below 60deg. This is the limitation with consideration to the stability of the crack if the deep crack penetrates wall of the pipe. Therefore, a long crack (such like an SCC) was obliged to repair or replace even if it was shallow enough. Weld Overlay (WOL) repair in which strength of the original piping is ignored is also inapplicable for the same reason. In order to solve this irrationality, the new Code Case applying to the crack stability assessment when the crack angle exceeds 60deg was established, and allowable crack depth ...
Fatigue crack growth tests of three ferrite-pearlite steels with different size and spacing of pearlite particles, which were uniformly distributed in the ferrite matrix, were carried out to investigate the effect of microstructure on fatigue crack growth behavior in the Paris regime. The fatigue crack growth rates for the three materials did not coincide with each other, even when the crack growth curves were arranged by the effective stress intensity factor range. From in situ observations, crack tip stress shielding phenomena, such as interlocking and branching, were found on the crack wake, which enhanced fatigue crack growth resistance. A small size and spacing of pearlite particle seemed to induce small but frequent crack deflections, which resulted in crack closure phenomena. On the...
LP steam turbine retrofits are generally undertaken as a result of mechanical problems, for example due to stress corrosion cracking, torsional vibration or erosion. They present plant operators with an opportunity to introduce advanced aerodynamic technology, and at the same time improve efficiency and availability. Standard components, the majority proven in long-term service, can be used to obtain a permanent solution to the problems. In several European countries, retrofits have been carried out on intact LP steam turbines owned by utilities whose primary motivation is efficiency improvement. (orig.) [Deutsch] Niederdruck-Dampfturbinen werden in der Regel nur dann nachgeruestet, wenn waehrend des Betriebes Probleme durch Spannungsrisskorrosion, Torsionsschwingungen oder Erosion auftreten. In solchen Faellen bietet sich die Gelegenheit, eine moderne aerodynamische Loesung zu waehlen, die gleichzeitig Wirkungsgrad und Verfuegbarkeit ...
Leak-before-break (LBB) analyses for circumferentially cracked pipes are currently being conducted in the nuclear industry to justify elimination of pipe whip restraints and jet impingement shields which are present because of the expected dynamic effects from pipe rupture. The application of the LBB methodology frequently requires calculation of leak rates. These leak rates depend on the crack-opening area of a through-wall crack in the pipe. In addition to LBB analyses, which assume a hypothetical flaw size, there is also interest in the integrity of actual leaking cracks corresponding to current leakage detection requirements in NRC Regulatory Guide 1.45, or for assessing temporary repair of Class 2 and 3 pipes that have leaks as are being evaluated in ASME Section 11. This study was requested by the NRC to review, evaluate, and refine current analytical models for ...
Retention or dispersion of larvae from the spawning grounds has been identified as one of the key processes influencing recruitment success in fish stocks. To examine the potential effects of transport on recruitment. numerical simulations were performed utilizing a three-dimensional physical oceanographic model of the Baltic Sea. Cod larvae were represented as Lagrangian drifters released in the deepwater region of the Bornholm Basin, the main spawning ground for Baltic cod. Simulations were performed for the major spawning seasons of 1993 and 1994. when annual and interannual variability of meteorological forcing was large. The principal goals of the modelling exercise were first to identify the physical processes influencing the demersal distribution of the early life stages and second to describe the transport of the pelagic stages in response to variations in windstress, thereby identifying the meteorological and hydrodynamic mechanisms ...
Results of hot cracking on welds with compositions between alloy 800 and AWS ER NiCr 3. Investigation of the influence of Si, Mn, Ti and Al on the hot cracking suscpetibility of the alloy 800. (orig.).
With regard to a fracture system in the Hijiori hot dry rock artificial reservoir, an attempt was made on an interpretation which integrates different data. Major factors that characterize development and performance of an artificial reservoir are composed of a fracture system in rocks, which acts as circulating water paths, a heat exchange face and a reservoir space. The system relates not only with crack density distribution, but also with cracks activated by water pressure fracturing, cracks generating acoustic emission (AE), and cracks working as major flow paths, all of which are characterized by having respective behaviors and roles. Characteristics are shown on AE cluster distribution, crack distribution, production zone and estimated stress fields. Mutual relationship among these elements was discussed based on the Coulomb`s theory. The most important paths are characterized ...
Cracking resistance and metal damage are considered in relation to structural state for steam-pipe fittings during use. An approximate scheme is given for estimating the maximum permissible operating time in the plastic state in relation to the depth of an observed crack-type defect.
The shrinkage of the cement paste with low water-cement ratio at different relative humidity was observed and analyzed with ESEM and deformation map technique. The crack morphology was observed with different magnification with SEM and FESEM, and the formation of the crack was observed with AFM between two C-S-H nano particles. The observation by multi technique at multi scale indicated that the shrinkage was increase with the decrease of the humidity due to the increase of the pressure of the capillary pressure, the morphology of the crack in smaller scale was similar to that in the bigger scale, the smaller crack distributed in the latticework of the bigger ones, and the crack propagated along the gap between two nano particles of C-S-H with weaker bonding.
Barsebaeck 1 was closed on 30 November 1999. Barsebaeck's output of approximately 4 TWh per year will primarily be replaced by imports from coal-fired plants in Denmark and Germany. During the year, the closure of Swedish fossil-fired condensing power stations continued. With that, over 3,000 MW of peak-load power has been shut down during recent years. Consequently, situations entailing shortages of power can arise. On the deregulated electricity market, it is only the system operators that have a satisfactory overview of the overall electricity balance. The Swedish Power Association has thus lobbied the government as regards the need to elucidate Svenska Kraftnaet's responsibility. In a governmental decision from December, Svenska Kraftnaet was given the task of, among other things, monitoring the available capacity during peak loads and developing market instruments that can contribute to safeguarding the availability of power during peak loads. Svenska Kraftnaet ...
A focused ion beam (FIB) system has been applied to prepare a thin foil specimen of Si, MgO and alumina which contained cracks in the plan of foil. It was possible to observe a much larger area at and near a crack tip than has been hitherto possible. FIB was also applied to observation of microstructure near a crack tip evolved during severe rolling contact fatigue in a steel.
In view of the widespread cracks discovered in the reinforced-concrete circulating water culvert of Daya Bay Nuclear Power Station, cause analysis for the cracks is made in terms of construction and design. It is concluded that the cracks mainly resulted from shrinkage and temperature. Corresponding countermeasures are put forward thereafter for reference of similar projects
The subscale Varestraint test has been used to determine the relative hot cracking susceptibility of the fusion zone in four commercial heats of alloy 800. Although all four heats were susceptible to cracking, one heat exhibited a significant increase in cracking relative to the other three. Optical metallography revealed that nearly all the cracking was localized along fusion zone grain boundaries. Microprobe analysis of the grain boundaries detected high concentrations of titanium, silicon, and niobium resulting from partitioning during solidification. The fusion zone hot cracking mechanism in alloy 800 involves the complex interaction of titanium, silicon, niobium, and carbon along the solidification boundaries. SEM and Auger analyses of the hot crack fracture surfaces revealed the presence of (Ti, Nb)-rich carbides, suggesting that these particles ...
A crack fault is one of the damage modes most frequently occurring in gears. Identifying different crack levels, especially for early cracks is a challenge in gear fault diagnosis. This paper aims to propose a method to classify the different levels of gear cracks automatically and reliably. In this method, feature parameters in time domain, specially designed for gear damage detection and in frequency domain are extracted to characterize the gear conditions. A two-stage feature selection and weighting technique (TFSWT) via Euclidean distance evaluation technique (EDET) is presented and adopted to select sensitive features and remove fault-unrelated features. A weighted K nearest neighbor (WKNN) classification algorithm is utilized to identify the gear crack levels. The gear crack experime...
The varestraint cracking test was carried out to assess the hot cracking tendency of alloy 800 at different welding conditions and augmented strain levels. The test results revealed that the hot cracking susceptibility of alloy 800 increases with increasing the heat input and augmented strain levels. This emphasizes the role of constraint either internally induced or externally applied to the welded structure. A cracking threshold or the minimum augmented strain ([epsilon][sub min]) below which no hot cracking takes place has been found to be 0.25 for alloy 800. Also, the Critical Strain Rate to Time (CSS) required to cause cracking was found to be 6.42x10[sup -3] sec[sup -1] at welding condition of 100 Amp, 13 Volt and 140 mm/min. (author).
The varestraint cracking test was carried out to assess the hot cracking tendency of alloy 800 at different welding conditions and augmented strain levels. The test results revealed that the hot cracking susceptibility of alloy 800 increases with increasing the heat input and augmented strain levels. This emphasizes the role of constraint either internally induced or externally applied to the welded structure. A cracking threshold or the minimum augmented strain (#epsilon#_m_i_n) below which no hot cracking takes place has been found to be 0.25 for alloy 800. Also, the Critical Strain Rate to Time (CSS) required to cause cracking was found to be 6.42x10"-"3 sec"-"1 at welding condition of 100 Amp, 13 Volt and 140 mm/min. (author).
Nuclear grade production tubing of Alloy 600 was evaluated for stress corrosion cracking (SCC) susceptibility in high purity water at 365, 345, 325, and 290 C. Reverse tube U-bend specimens provided crack initiation data and constant extension rate tests were employed to determine the crack velocities experienced in th crack propagation stage. Initial results indicate that a linear extrapolation of data received from high temperature tests can be used to predict the service life of steam generator tubing that has been plastically deformed or is continually deforming by ''denting.''.
Simplified strain-based fracture mechanics equations, established for external surface cracked pipelines subjected to an external bending load, are presented and used in probabilistic assessment of a pipeline girth weld. The model takes into account several parameters, such as variation in crack depth, crack length, internal pressure and material hardening. The critical strain from ductile tearing in the cracked pipeline is found by using the tangency criterion. The reliability problem is solved using first and second order reliability methods for different pipe dimensions and load levels.
The crack growth behavior and fracture toughness of two laminated metal composites (6090/SiC/25p laminated with 5182 and ultrahigh-carbon steel laminated with brass) have been studied in both ``crack arrester`` and ``crack divider`` orientations. The mechanisms of crack growth were analyzed and extrinsic toughening mechanisms were found to contribute significantly to the toughness. The influence of laminate architecture (layer thickness and component volume function), component material properties and residual stress on these mechanisms and the resulting crack growth resistance are discussed.
The known metazoa parasite fauna of the invasive round goby Apollonia melanostoma (formerly Neogobius melanostomus) consists of 12 species. The core of the parasite fauna comprises two species: Cryptocotyle concavum and Diplostomum spathaceum; secondary species are absent; satellite species include Cercariae gen. sp. and Ergasilus sieboldi; rare species are Acanthocephalus lucii, Anguillicola crassus, Bothriocephalus sp., Dichelyne minutus, Hysterothylacium aduncum, Pomphorhynchus laevis, Piscicola geometra, and Tylodelphys clavata. Fifty percent of metazoa parasites that occurred in the invasive round goby in the Gulf of Gda?sk (an invasion that was first detected in 1990) are also typically found in the native Gulf of Gda?sk gobiids. The round goby hosts common fish parasite species: C. ...
This work describes how a general, process-based mass-balance model (CoastMab) for phosphorus for coastal areas may be used as a tool to estimate realistic values of "natural" or preindustrial reference levels of key bioindicators in coastal science, including the Secchi depth, a standard measure of water clarity, the chlorophyll-a concentration, an operational measure of phytoplankton biomass and the concentration of cyanobacteria, a measure of the concentration of harmful algae. The CoastMab-model is an ecosystem model giving monthly predictions to achieve seasonal variations of basin-wide properties. The selected case-study area, the Gulf of Riga, is sensitive to nutrient loading because of its shallowness and low openness towards the Baltic Proper. The morphometry of any coastal area, ...
Given sufficient time, the extraction of heat from geothermal reservoirs formed by the hydraulic fracturing of competent rock will eventually result in the formation of thermal stress cracks in the reservoir. These cracks penetrate the rock in a manner such that the penetration-to-spacing ratio is approximately one. The penetration depends upon the extent of cooling and the square root of time. Initially then, the cracks are closely spaced and penetrate but little, so that a crazing pattern is apparent; but with increasing time some of these cracks, now more widely spaced, grow deeper. Eventually these larger cracks attain a critical aperture such that significant rates of water flow can be established within them and thus the newly created heat transfer area becomes useful for heat extraction. At the same time that cracks are forming within the main reservoir, ...
In recent years intergranular stress corrosion cracking has occurred world-wide in the shrink-fitted discs of low pressure turbine rotors made of low alloy steels. Only in a few cases steam impurities such as NaOH, Na_2CO_3, Na_2SO_4, H_2S or NaCl, which initiate SCC, could be found. To clarify the SCC-behaviour experiments on turbine disc steels with different chemical compositions and yield strength were performed in high purity water. The results show, that chemical composition has no effect on the crack initiation. Under high purity water conditions no crack initiation due to stress corrosion cracking is observed on the steel with a yield strength of 850 N/mm"2. On the steel with a yield strength of 1250 N/mm"2 which is not used in service, crack initiation occurs in pure water. But if sharp cracks already exist, crack propagation occurs ...
In this study, growth measurements of fatigue cracks in air and various simulated media for steam turbines were made by means of rupture-mechanical methods. In this connection, it was detected that even pure water leads to a clear increase in the fatigue crack rates of low-pressure rotor steels. In this connection, it was striking to observe that the crack propagation velocities at 100"0C were higher than at 160"0C. It is probable that the kinetics of the film formation at the crack tip was of importance. The inhibiting effect of the alkaline solutions is explained by the increasing stability of a film of Fe(OH)_2 at an increased pH value. Neither the frequency response nor the fractographic result indicate an influence of the stress crack corrosion. This can be explained by the fact that the incubation period (= the period to initiate an intercrystalline crack ...
A nonlinear partial differential equation modeling the propagation of a vertical hydraulic fracture first derived by Nordgren is studied. When properly posed, Nordgren's derivation constitutes a Stefan problem and requires another boundary condition-namely, that the velocity of the fluid at the crack tip equals the velocity of crack propagation. With this addition, Nordgren's similarity solution in the no-leakoff case is perfected by a power-series solution. New shut-in solutions are derived in the large-and-no-leakoff cases where the crack of the large-leakoff shut-in solution retracts and the crack of the no-leakoff shut-in solution extends forever. This study ignores the effect of crack-tip rock strength on crack propagation.
The purpose of this experimental study is to investigate the micromechanical fatigue behavior, in terms of slip nature and preferential cracking sites, of a commercial #alpha#/#beta#-forged Ti-6Al-4V alloy. Electron backscattering diffraction is extensively used to identify the deformation (prismatic, basal, pyramidal slip) and crack formation modes activated by fatigue at the surface of several hundred primary #alpha# nodules. Some fatal crack formation sites are also characterized. Cracking in basal planes is identified as the most critical damage mode leading to fracture. An explanation is proposed which involves the resolved shear stress, taking into account the Schmid factor and the normal stress in relation to the elastic anisotropy of the #alpha#-phase. Finally, the spatial distribution of the secondary cracks is analyzed according to the crystallographic textures ...
Up to 90% of the life time of cyclically loaded components is determined by short crack initiation and propagation. This stage of the fatigue damage process is strongly influenced by microstructural features, e.g. grain boundaries and crystallographic grain orientation. Therefore LEFM can not be applied in a reasonable manner explaining the demand for a mechanism-related modelling method. The present study deals with mechanical testing and microstructural examinations applied to the relatively new #beta#-titanium alloy LCB. The results are used as data base to develop a new short crack model that is based on the model of Navarro and de los Rios. By using various techniques such as electron back-scattered diffraction and finite-element calculations the origin of crack initiation is revealed and the characteristics of crack propagation is determined. (orig.)
ABSTRACT Crack tip opening angle (CTOA) is becoming one of the most accepted methods for characterizing fully plastic fracture. It provides a measure of the resistance to fracture for a material in cases where there is a large degree of stable-tearing crack extension during the fracture process. Our current pipeline research uses the CTOA test as an alternative, or addition, to the CTOD (crack tip opening displacement) and the fracture energy characterization provided by the J-integral approach. A test technique was developed for measurement of CTOA that uses a modified double cantilever beam (MDCB) specimen. A digital camera and image analysis software were used to record the progression of the crack tip and to estimate the CTOA. In this article, CTOA data on crack growth orientations per...
Countries and Regions A-Z List of Countries and Other Areas Africa (Sub-Sahara) East Asia and the Pacific Europe and Eurasia Near East (northern Africa, Middle East) South and...
Effect of water injection/draining on elastic waves penetrating through cracks is examined by measuring elastic waves before, during, and after the injection/draining of water into/from cracks in presence in granite. Two blocks of rock, with their crack-containing surfaces in contact with each other, are placed in a vessel, and water injection/draining is done through a hole on a vessel bottom side so that water will penetrate into the cracks. When the blocks are dry, there is almost no contact between the cracks, and so no crack penetrating waves are observed. Crack penetrating waves are produced when water is injected, and the position of the receiver sensing the penetrating waves changes as the water level rises. When the water level is lowered from the high water level, the waveform changes again as the level changes. The change in ...
Bench Scale methane cracking tests have been completed using a stack of ten whole SAES(R) St909 pellets - a 6 gram sample size. Methane was found to be the most difficult impurity to process and can impact diffuser operation.
Bench Scale methane cracking tests have been completed using a stack of ten whole SAES(R) St909 pellets - a 6 gram sample size. Methane was found to be the most difficult impurity to process and can impact diffuser operation.
This report describes the results of EPRI Program S404-28, titled Experimental Modeling of Eddy Current Response'', conducted by the Westinghouse Science and Technology Center (STC). The Westinghouse STC demonstrates that its mercury modeling technique provides an unique bridge between steam generator eddy current field inspection conditions and predictions obtained using recently developed analytical models. The mercury modeling technique was used systematically to explore factors which contribute to primary water stress corrosion cracking (PWSCC) sizing inaccuracy, including probe design, coil excitation frequency, crack length, and crack morphology. Two new proposed techniques for inverting crack lengths from eddy current data are compared with the technique commonly used in field data analysis for PWSCC. The performance of uniform field eddy current probes is compared with the ...
This report describes the results of EPRI Program S404-28, titled Experimental Modeling of Eddy Current Response'', conducted by the Westinghouse Science and Technology Center (STC). The Westinghouse STC demonstrates that its mercury modeling technique provides an unique bridge between steam generator eddy current field inspection conditions and predictions obtained using recently developed analytical models. The mercury modeling technique was used systematically to explore factors which contribute to primary water stress corrosion cracking (PWSCC) sizing inaccuracy, including probe design, coil excitation frequency, crack length, and crack morphology. Two new proposed techniques for inverting crack lengths from eddy current data are compared with the technique commonly used in field data analysis for PWSCC. The performance of uniform field eddy current probes is compared with the ...
A crack fault is one of the damage modes most frequently occurring in gears. Identifying different crack levels, especially for early cracks is a challenge in gear fault diagnosis. This paper aims to propose a method to classify the different levels of gear cracks automatically and reliably. In this method, feature parameters in time domain, specially designed for gear damage detection and in frequency domain are extracted to characterize the gear conditions. A two-stage feature selection and weighting technique (TFSWT) via Euclidean distance evaluation technique (EDET) is presented and adopted to select sensitive features and remove fault-unrelated features. A weighted K nearest neighbor (WKNN) classification algorithm is utilized to identify the gear crack levels. The gear crack experiments were conducted and the vibration signals were captured from the gears ...
In support of a project on lifetime calculation experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K{sup Iscc}, and the crack growth rate were made to predict evolution of damage in tube walls. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that the material of SG tubes is sensitive to transgranular environmentally assisted cracking in the three basic concentrated environments used, ...
In support of a project on lifetime calculation experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K"I"s"c"c, and the crack growth rate were made to predict evolution of damage in tube walls. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that the material of SG tubes is sensitive to transgranular environmentally assisted cracking in the three basic concentrated environments used, ...
The threshold stress intensities for stress corrosion crack propagation in beta titanium alloy 38-6-44, Ti3Al-8V-6Cr-4Mo-4Zr, has been determined in salt water and methanolic solutions. The alloy was immune to stress corrosion cracking (SCC) in aqueous sodium chloride solutions (marine atmosphere). However, in methanolic solutions, the alloy was very susceptible to SCC. This marked susceptibility in methanolic solutions can be mitigated by the addition of an inhibitor: sodium nitrate. Crack extension in the alloy was transgranular and failure occurred by brittle quasi-cleavage in methanolic solutions.
In the power station West Block 2 at Voerde (Federal Republic of Germany), cracks in the final stage of the shaft were determined at the ND1 rotor of the 350 MW condensation tube was determined. A purely mechanical preparation of the crack was not possible due to the depth of the crack. A substitute rotor was not available. A repair solution was developed covering a welding of a new shaft section to the existing rotor. The authors of the contribution under consideration report on the damage, cause of the damage, repair solution and the process of repair.
Long crack fatigue threshold ({delta} K{sub th}) and crack closure behaviour of two thermomechanically processed microalloyed (MA) ferrite-pearlite steels are reported. {delta} K{sub th} and crack closure were measured using a dynamic compliance measurement technique. Crack closure was observed at low load ratios (R < 0.5) and the fatigue thresholds decreased with increasing load ratio. In both steels, the closure-free intrinsic threshold ({delta} K{sub eff} {sub th}) was found to be independent of the load ratio. (orig.)
Results of investigation of stress corrosion cracking of steam turbine materials in nuclear, fossil and geothermal power plants have been analysed. The role of factors that cause damage to rotor discs, mono block and welding rotors of steam turbines has been shown. These are yield stress and steel composition, stress intensity coefficient and crack growth rate, composition and temperature of the condensed steam and water, electrochemical conditions. The conclusion has been made about the state of stress corrosion cracking of the rotors materials, and main investigation trends which are necessary to solve this problem have been listed.
The threshold stress itensities for stress corrosion crack propagation in beta titanium alloy 38-6-44, Ti-3Al-8V-6Cr-4Mo-4Zr, has been determined in salt water and methanolic solutions. The alloy was immune to stress corrosion cracking in aqueous sodium c...
Crack arrest of fast running cracks is an important issue for the safety of steel structures. Crack arrest design can prevent fatal damage of large structures by restricting the influence of the incidents. Therefore crack arrest design is important especially for very large structure, where accidents may cause huge economical and social losses. Propagating shear fracture, long running ductile crack propagation in pipelines and brittle crack propagation in heavy thick shipbuilding steels have been investigated. For the propagating shear fracture issue, a new HLP simulation model, applicable to various backfill conditions, including underwater backfill, was developed. The proposed backfill model can be applied to the prediction of the crack arrest of propagating shear fracture under various backfill conditions. The new HLP simulation was ...
This paper discusses the storage of spent nuclear fuel by countries around the world. At the present time, all countries are storing it. A small number of countries are reprocessing it for recycling. Essentially all countries are preparing for eventual disposal of end waste form. There is much uncertainty and controversy over what should and will happen.
Desiccation cracking is a common phenomenon in clay materials, which may considerably increase the hydraulic conductivity of soil. This issue is one of the main concerns in the design and construction of landfill covers, especially, in arid regions. For some highly plastic soils, permeability increases during cyclic drying and wetting are not significant, even though cracking may clearly be noticed in the soil. These cracks may self-heal during subsequent wetting and saturation processes. In the present study, large scale experimental models of various natural clayey soils with various plasticity indices were subjected to cyclic drying and wetting and hydraulic conductivity testing to better understand cracking behaviour and self-healing in fine-grained soils. The soils are candidate clay ...
The potential material class for use at 600"0C and more, e.g. for steam turbines with improved thermal efficiency, are austenitic steels. Using these steels with welded joints, it is to be considered that, by superposition of weld residual stresses and service stresses, extensive creep strains - and in the worst case crack formation - can occur locally. To assess the influence of these effects on service behaviour, different material states of CrNi-steels and Incoloy 800 were investigated with respect to strength, ductility and, especially, to crack and creep crack growth in the temperature range around 600"0C. It is shown that creep embrittlement, not microstructural changes as effected by weld heat input, causes heat affected zone (HAZ)-reheat cracking. Creep embrittlement can be avoided by special design and fabrication rules. (orig.).
Damage and cyclic fatigue failure under alternating loading in transformation-toughened zirconia ceramics is reviewed and compared to corresponding behavior under quasi-static loading (static fatigue). Current understanding of the role of transformation toughening in influencing cyclic fatigue-crack propagation behavior is examined based on studies which altered the extent of the tetragonal-to-monoclinic phase transformation in MG-PSZ through subeutectoid aging. These studies suggest that near-tip computations of the crack-driving force (in terms of the local stress intensity) can be used to predict crack-growth behavior under constant amplitude and variable-amplitude (spectrum) loading, using spatially resolved Raman spectroscopy to measure the extent of the transformation zones. In addition, results are reviewed which rationalize distinctions between the crack-growth behavior of preexisting, ...
There are a total of nine operational nuclear plants in Spain totalling 7.350 MWe. These units produced 54.265 x 106 KWh in 1990, 36% of the total generation in Spain. Seven of these plants are of the PWR type. The first plant in operation was Jose Cabrera (ZORITA) in 1968, one loop Westinghouse plant with a model 24 Steam Generator. Due to the design margin and careful operation of the Steam Generator of this plant its performance have been very good, with only 5% tubes plugged after 23 years of operation. This is one of the few units in the world that remains in phosphate chemistry. During the period 1981-1985 a total of four units, two in Almaraz and two in Asco entered in operation. These three loop s Westinghouse units use model D-3 preheater Steam Generators. The poor design and manufacture of the Steam Generators of these units have caused a large number of problems: mechanical (Preheater and AVB's vibration), denting, and primary and secondary stress corrosion ...
Welding problems occurred while resistance welding Inconel 625 to Inconel 600 pins in the MC3462A header at Unidynamics/Phoenix (UPI). The bridgewire showed transverse and longitudinal cracks, a condition called hot cracking, at the weld area. Welding studies at Mound confirmed a best effort could not produce welds without hot cracking. Two new bridgewire materials, Tophet C and Alloy 800, were then introduced to replace Inconel 625. Samples of both bridgewired headers welded at Unidynamics were studied at Mound to determine which was the better material. Results showed that Alloy 800 was subject to the same hot cracking phenomenon as Inconel 625, whereas all samples of Tophet C except one showed no cracks. The only Tophet C sample showing cracks showed only minor cracks. Langley tests performed with Tophet C as the bridgewire showed that ...
Detection of fatigue damage cracks in aircraft skin structures is an ongoing NDT challenge. Cracks growing rate is difficult to predict, and for this reason, it is important to detect them as soon as possible to avoid a catastrophic break. Eddy current methods are known and well-accepted techniques which are relatively simple to carry out. However, with conventional inspection of airframe structures using standard driver-pickup eddy current probes, it is difficult to detect small fatigue cracks initiated in the second layer of the skin and in the shadow region at fastener holes. Such difficulty is related to fasteners length and their spacing which reduces test sensitivity. This report explains the development of improved eddy current probe/technique to detect and visualize fatigue cracks in fasteners. In this study, an eddy current array probe was evaluated and new coil design was suggested. Several ...
The combined effects of environment, yield strength and stress state on the cracking susceptibility of beta-extruded Ti-6Al-6V-2Sn have been examined. At a constant yield strength and under plane strain conditions, the stress intensity required for slow crack propagation decreased as the severity of the environment increased, i.e., from laboratory air to 3.5% NaCl. Furthermore, the crack propagation rates were a function of both stress intensity, and environmental severity. Although the fracture toughness and threshold stress intensities for slow crack growth generally decreased with increasing yield strength, aging, which resulted in the precipitation of ordered Ti3Al particles in the primary alpha phase, tended to accentuate the susceptibility of this alloy to sustained load/stress corrosion cracking. Finally, at constant yield strength, the sustained load ...
Age-related deterioration of the fracture properties of bone, coupled with increased life expectancy, are responsible for increasing incidence of bone fracture in the elderly, and hence, an understanding of how its fracture properties degrade with age is essential. The present study describes ex vivo fracture experiments to quantitatively assess the effect of aging on the fracture toughness properties of human cortical bone in the longitudinal direction. Because cortical bone exhibits rising crack-growth resistance with crack extension, unlike most previous studies the toughness is evaluated in terms of resistance-curve (R-curve) behavior, measured for bone taken from wide range of age groups (34-99 years). Using this approach, both the ex vivo crack-initiation and crack-growth toughness are determined and are found to deteriorate with age; the initiation toughness decreases some 40% over six decades ...
More than 660 synthetic aperture radar (SAR) images acquired over the southern Baltic Sea, the North Sea, and the Gulf of Lyon in the Mediterranean Sea by the Second European Remote Sensing Satellite (ERS-2) have been analyzed since December 1996 with respect to radar signatures of marine pollution and other phenomena causing similar signatures. First results of our analysis reveal that the seas are most polluted along the main shipping routes. SAR images acquired during descending (morning) and ascending (evening) satellite passes show different percentages of oil pollution, because most of this pollution occurs during night time and is still visible on the SAR images acquired in the morning time. Moreover, we found a higher amount of oil spills on SAR images acquired during summer (April-September) than on SAR images acquired during winter (October-March). We attribute this finding to the higher mean wind speed encountered in all three test areas during winter. ...
Concentrations of tritium in environmental waters (precipitation, rivers, lakes, tap water) have been determined using electrolytic enrichment and liquid scintillation counting. In waters of big rivers (the Vistula and the Odra rivers), lakes and tap water the annual average concentrations were similar to each other being from 1.4 to 1.9 Bq x dm"-"3. These concentrations were similar to those in the precipitation in which they ranged from 1.7 to 2.2 Bq x dm"-"3. The lowest tritium concentrations were found in waters of the Seashore Region rivers (average for 1994-1999 was 1.1 Bq x dm"-"3). The tritium concentrations in surface waters and in precipitation are still higher than that of natural level. The data obtained show that tritium concentration in the water of rivers might depend on the size of drainage area. The observed seasonal variations of tritium concentration in the precipitation collected in Warsaw and at the Mount Sniezka indicate the stratospheric source of tritium. It was ...
Sequence stratigraphic interpretation of paralic successions is complicated by the complex interfingering of marine and continental strata. The successions may also include terrestrial extensions of marine parasequences and completely independent lacustrine parasequence analogues. Failure in recognizing the possible interbedding of these two independent parasequence types may lead to construction of sequence stratigraphic schemes based on incompatible data sets. We have studied a Lower Jurassic paralic section from the Baltic island of Bornholm. The Hettangian-Sinemurian Sose Bugt Member (Ronne Formation) of Bornholm includes lacustrine, fluvial and restricted marine, estuarine deposits reflecting the basin-margin position. Biostatigraphic resolution is poor and a sequence stratigraphic interpretation of the paralic succession is far from straightforward. A multidisciplinary approach including facies analysis, recognition and lateral tracting of key surface, ...
The costs of greenhouse gas emission-reductions vary among countries depending on emission levels, technologies used, past emission-reduction achievements, path of economic development, fuel mix, and initial endowment of hydrocarbon resources. The criterion of cost-effectiveness therefore suggests that the ways should be found to encourage emission reductions in the countries where the required costs of reduction of additional unit of emissions are the lowest. These countries usually face crucial capital constraints and have other development priorities than investing in reduction of greenhouse gas emissions. Developed countries could invest their resources in the former Soviet Union and the east European countries to achieve the same level of reduction of greenhouse gases with lower costs than they could in their own countries.
Microstructural analyses by several advanced metallographic techniques were conducted on austenitic stainless steel mockup and core shroud welds that had cracked in boiling water reactors. Contrary to previous beliefs, heat-affected zones of the cracked Type 304L, as well as 304 SS core shroud welds and mockup shielded-metal-arc welds, were free of grain-boundary carbides, which shows that core shroud failure cannot be explained by classical intergranular stress corrosion cracking. Neither martensite nor delta-ferrite films were present on the grain boundaries. However, as a result of exposure to welding fumes, the heat-affected zones of the core shroud welds were significantly contaminated by oxygen and fluorine, which migrate to grain boundaries. Significant oxygen contamination seems to promote fluorine contamination and suppress thermal sensitization. Results of slow-strain-rate tensile tests also indicate that fluorine ...
The papers contained in this volume provide an overview of recent theoretical and experimental research related to the fracture toughness and fatigue crack growth characteristics of titanium alloys. Topics discussed include room temperature fatigue crack propagation in beta-titanium alloys, fatigue crack growth rate acceleration in alpha+beta Ti alloys, influence of transformed beta microstructures on fatigue crack growth rates in Ti-6Al-4V, and the role of inclusion and pore content on the fracture toughness of powder processed blended elemental Ti-10V-2Fe-3Al. Papers are also presented on fatigue crack growth measurements in an alpha-beta titanium alloy, the effects of thermal processing variation on the properties of Ti-6Al-4V, and the effect of microstructure on ductility and fracture toughness of alpha+beta titanium alloys.
High temperature fatigue crack growth (FCG) and creep crack growth (CCG) experiments have been conducted in air on weld metal, heat affected zone (HAZ) and base metal of the austenitic Alloy 800 and the nickel base Alloy 617. Tests were performed on specimens machined from pipes, in the temperature range 550-900 deg. C. The crack propagation mode was examined. At all temperatures and for both materials, FCG of base metal was found to be the highest, whereas the weld metal exhibited the lowest FCG rate. The FCG rate in the HAZ was found to lie in between of those observed for base and weld metal. The crack propagation mode remained transgranular in base metal and transdendritic in weld metal at all temperatures. CCG behaviour could be described using the energy rate integral C*. Base metal and weld metal exhibited similar CCG rate at same C*. The crack propagation mode under CCG ...
Effect of the coverage of shot peening, the surface roughness and shot shape, etc. on the stress corrosion cracking (SCC) of Alloy 800 in alkaline solutions was studied. Alloy 800 specimens were cracked in boiling alkaline solutions at the potntial range of {minus} 100 to 0mV in the boiling 50%NaOH+0.3%SiO {sub 2} solution. U bend specimens were tested under the polarized condition at the controlled potential to 0mV, showing that shot peened specimens cracked more easily. Tests of specimens with the same hardness showed that specimens hardened by cold working showed the higher susceptivity than that of surface hardened specimens. In these connections, U bend specimens of higher shot peened coverage were cracked at conditions of 593K and 10%NaOH solution. O-ring specimens of smaller stress level did not show any cracks independent of surface treatments. 8 refs., 9 figs., 5 tabs.
The effect of mean stress, or the stress ratio (R), on the fatigue-crack growth (FCG) behavior of #alpha#-aged and #omega#-aged microstructures of the beta titanium alloy Ti-10V-2Fe-3Al was investigated. While the mean stress had a negligible effect on the FCG behavior of the #alpha#-aged microstructure, a strong effect was observed in the #omega#-aged microstructure. In particular, the values of the threshold stress-intensity range (#DELTA#K_t_h) exhibited a strong dependence on R in the #omega#-aged microstructure, while this dependence was weak in the #alpha#-aged microstructure. These effects seem to arise primarily from fracture-surface roughness-induced crack closure. The crack closure levels for the #alpha#-aged microstructure were found to be very low compared to those for the #omega#-aged microstructure. Transmission electron microscopy and scanning electron microscopy studies of microstructures and fracture ...
The solar central receiver at the Barstow Pilot Plant is a once-through steam boiler consisting of vertical arrays of Alloy 800 tubes. Water/steam leaks associated with tube bends near the receiver outlet were observed after 16 service months. The leaks resulted from through-wall cracks localized in the crown of tube bends operating in the temperature range from 550 to 650/sup 0/C. Initiation occurred on the ID (steam side) of the tube and propagated transgranular through the tube wall. Cracking was axial and circumferential; in general, the circumferential cracks were more severe than the axial cracks. Thick oxide layers showed on the ID of the receiver tubes; a 25-..mu..m thick oxide layer had formed on tubing which operated at 650/sup 0/C. In addition, an enhanced oxidation layer was observed along a narrow band in the crown of the tube. This band was up to five times thicker than the oxide elsewhere ...
A study of stress corrosion cracking susceptibility of Zircaloy-4 in chloride-containing aqueous methanolic media is presented. The influence of water content is investigated in the 5-100 vol. % water range. The dependence of stress corrosion cracking on potential is evidenced. A close correlation is established with pitting susceptibility determined by a statistical analysis of induction times. A correlation with the repassivation potential is observed in the water-rich solutions. In the low water content solutions, two repassivation curves are determined according to the experimental technique. Pit morphology and fractography show a transition from aqueous to organic media. (author).
At the importance increase of UT (ultrasonic testing) with the application of rules on fitness-for-service for nuclear power plants, JAPEIC (Japan power engineering and inspection corporation) started education training for defect detection and sizing technique. Weld joints specimen with EDM (Electro-Discharged Machining) notches, fatigue cracks and intergranular stress corrosion cracks were tested and practiced repeatedly based on a modified ultrasonic method and the defect size measuring accuracy of the trainees was surely improved. Results of the blind test confirmed effectiveness of education training. (T. Tanaka)
It has been found out that 30HGSNA steel undergo cracking under action of stresses in aqueous solutions containing oxygen, while it show high resistance in deoxidated solutions. The purpose of such phenomena is the existence of sulfur inclusions in steel which are a centers of denting corrosion. That points acting as a stresses concentrators where pH factor decreases including hydrogen formation and its absorption in the metal. That mechanism is the main purpose of brittle steel cracking observed in oxygen rich solutions. (author).
This Workpackage Report describes the introduction of fatigue cracks in bolts with ISO-metric threads M5x0.8, M8x1.0, M12x1.25 made from the materials Ti 6Al 4V, A-286 and INCONEL 718. Introdued cracks are verified by destructive testing. Results of the NDI of these bolts performed with special eddy current probes are reported. The detectability of cracks with a {>=} 0.65 and a/2c {approx equal} 0.3 located in the thread ground perpendicular to the load axis is demonstrated. (orig.).
The importance that must be attached to the phenomenon of stress corrosion cracking of austenitic alloys is emphasized. The relation between chemical composition of various alloys and their sensitivity to cracking is shown with particular reference to the behaviour of Alloy 800. The different effects of alkaline anc chloride environments are discussed. Studies are reported of the general corrosion of Alloy 800 and other alloys in an environment representative of the primary coolant of PWR reactors; and of the behaviour of various alloys (including Alloy 800) in the conditions envisaged for their use for steam generators with superheat up to about 550 deg.C. (U.K.).
The aim was to assess options and cost of reducing emissions of greenhouse gases (with emphasis on carbon dioxide) from human activity in Zimbabwe. A brief description of the country's economy and energy sector, policy and pricing and regulations is given...
Countries and Regions A-Z List of Countries and Other Areas Africa (Sub-Sahara) East Asia and the Pacific Europe and Eurasia Near East (northern Africa, Middle East) South and...
Second Regional Meeting for Nuclear Energy in Central Europe is an annual meeting of the Nuclear Society of Slovenia. The proceedings contains 75 articles from Slovenia, surrounding countries and countries of the Central and Eastern European Region
BackgroundMost maternal deaths in developing countries can be prevented. China is among the 13 countries with the most maternal deaths; however, there has been a marked decrease...Full Text Available
ObjectiveTo assess the perceived effectiveness of cigarette health warnings in China, compared with picture and text-only warnings from other countries.Method1169...Full Text Available
Four points are made about globalization and health. First, economic integration is a powerful force for raising the incomes of poor countries. In the past 20 years several large developing countries...Full Text Available
Provides standardized energy balance sheets expressed in a common unit of tons of oil equivalent for all OECD countries as well as the regions: OECD total, IEA, North America, Pacific, OECD Europe, EEC and Yugoslavia.
BackgroundDengue fever is a mosquito-borne illness that places significant burden on tropical developing countries with unplanned urbanization. A surveillance system using Google...Full Text Available
BackgroundWe were commissioned to carry out three health assessments in urban areas of Dublin in Ireland. We required an epidemiologically robust method that could collect data rapidly...Full Text Available
The cracking of 2-methylpentane on USHY at 300, 400, 450, and 500[degrees]C is interpreted in detail in terms of a chain mechanism. The kinetic equation developed from this mechanism fits the experimental data very well. The contribution of chain processes to the overall rate of conversion depends on the kinetic chain length, which in turn depends on the surface coverage by carbenium ions and their reactivities. Kinetic parameters were obtained at all four temperatures. A detailed examination of the kinetics shows that chain processes are more important at low reaction temperatures, whereas protolytic cracking dominates at higher temperatures. The parameters also show that both competitive inhibition by products and the rate of catalyst decay increase with increasing reaction temperature. Furthermore, they show that carbenium ions formed on Broensted sites are more stable than carbonium ions. 39 refs., 12 figs., 5 tabs.
Advances in the theory and practice of stress corrosion cracking (SCC) are reviewed for the period 1965-1990. The proceedings of two landmark conferences are used as a basis for discussion: Ohio State University (1967) and Kohler, WI (1988). The discussion is developed around the following topics: metal-environment combinations, testing, fractography, metallurgical aspects, electrochemical aspects and crack chemistry, mechanisms, and prediction and mitigation. It is concluded that the main developments since 1967 are the recognition of the lack of specificity of SCC environments, the use of slow strain rate and fracture mechanics testing, quantitative SEM fractography, studies of grain boundary structure and compositions, transient electrochemistry of bare metal surfaces, measurement and modelling of crack chemistry, elaboration of several SCC models, including slip-dissolution and film induced cleavage, and mitigation by ...
In the present paper an attempt is made to describe transverse cracking of cross-ply ([0{sup o}{sub n}/90{sup o}{sub m}]{sub s}) laminates subjected to an external applied load and a temperature change. For this purpose a new method is suggested which was developed on the basis of the energy balance based finite fracture criterion suggested by Hashin (1996) [Hashin, Z., 1996. J. Mech. Phys. Solids 44, 1129]. In this approach the value of the specific surface energy (the critical energy release rate) is assumed to be dependent on a random microdamage distribution in the material. Hence, it is assumed to be a random function of location. A new probabilistic technique is developed to take this randomness into consideration. It is shown that only one unknown probabilistic function is required, namely the probability density function of the specific surface energy. This is determined by fitting the external stress and the corresponding crack density ...
The effect of alloying low carbon 18Cr-30Ni steel with silicon (up to 5.1%), copper (up to 5.4%), cobalt (up to 15.3%) on the resistance to corrosion cracking and pitting corrosion, is studied. Tests on uniaxial tension are carried out in 42% MgCl_2 solution and gravimetric studies in 10% FeCl_3x6H_2O. It is established that alloying steel of the Kh18N30 type with silicon increases strength and resistance to corrosion cracking. Copper and cobalt decrease a resistance to pitting corrosion but somewhat increase a resistance to corrosion cracking.
We conduct the static and dynamic loading fracture experiments on magnesium alloy (AZ31B) under the equitable and inequitable biaxial stress. We process specimens as cross type with cracks. There are different kinds of cracks defined by their crack angles. By using a hydraulic high-speed biaxial experiment machine, we put the equitable and inequitable stresses on the specimen. We analyze results using the caustic method. The experiments reveal a few important results. There is negative correlation between the fracture toughness value and the plate thickness in the magnesium alloy sheet specimen. The fracture toughness value decrease in the case the crack has the angle different from the loading direction. The fracture toughness value decreases significantly under the inequitable biaxial stress. (orig.)
The objective of this paper is to present a theoretical evaluation of soil and house related factors that may affect the transport of radon from the soil into houses. A two-dimensional mathematical model was used to simulate the diffusive and convective transport of radon into the house through idealized openings in the understructure. With the help of model predictions we tried to find out whether diffusion or convection predominates and under which circumstances. Radon transport through cracks in the house understructure is influenced mainly by the soil permeability, radon concentration at the soil-crack interface, the total area of cracks and the pressure difference across cracks. Because of its large range of variability, the soil permeability appears to have the greatest effect on the radon transport through cracks. At permeabilities below 1x10"-"1"2 m"2 diffusive transport ...
Discussions were given on mullite/SiC composite ceramics as to crack size dependence of their crack healing behavior, and high-temperature strength properties. Test specimens used in the experiment are sinters of mullite powder added with SiC powder at 20% by volume, and hot-pressed under conditions of a sintering temperature of 1650 degC, time of four hours, and a pressure of 35 MPa. In the experiment, a pre-crack was introduced at the center of a test specimen by using a Vickers hardness meter, and a heat treatment was performed in atmosphere at 1300 degC for one hour. A four-point bending test was conducted in atmosphere as a strength test. Conditions in test specimens were investigated by using SEM observation, a laser microscope and X-ray diffraction. The following findings were obtained as a result of the experiment: the bending strength for the pre-cracked material is about 140 MPa against that ...
The number of spent fuel storage facilities in the world continues to increase because of "Wait and See" policies and delay of a permanent disposal plan. The temporary spent fuel storage concept is changing to a pre-disposal storage concept. Strengthened safety concepts are required for expanded spent fuel storage facilities and sites. The Korea Hydro and Nuclear Power Company is planning to construct a reinforced concrete MACSTOR-400 facility at Wolsung. In concrete dry spent fuel storage structures, cracks can occur due to radiant heat and environmental chloride. The likelihood of cracking increases over time. Research on changes in shielding performance from one collinear crack in the surface of a concrete facility has been carried out. However there is no research about public radiolog...
Different semi precious alloys (Pd-Ag, Pd-Au) have been studied after thermal oxidation treatments to analyze the mechanical improvement of the interface between the metal and the ceramic. Using the four point bending test, the authors have analyzed the different steps corresponding to the mechanical evolution of the bi-material : cracking energy on the surface, relaxation energy after first cracking, propagation energy of cracks at the interface zone. It has been shown that some alloys only have a high resistance to the interface cracking and the role played by the interface reactions to improve this property. (orig.).
Food irradiation is the process of exposing food to an ionizing energy to kill harmful bacteria and other organisms and extend shelf-life. It is a safe process and has been approved by some 50 countries worldwide and applied commercially in the USA, Japan, China and several European countries for many years. Trends law regulations and new applications in Europe and another countries has been described. (author)
The quality assurance requirements in various countries and according to various international codes and standards are presented, compared and critically discussed. Cases of developing countries are also discussed, and the use of IAEA code of practice and other codes for quality assurance in these countries is reviewed. Recommendations are made regarding the quality assurance system to be applied for Egypt's nuclear power plants.
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As part of a coordinated program, AECL is developing a set of tools to aid with the prediction and management of steam generator performance. Although stress corrosion cracking (of Alloy 800) has not been detected in any operating steam generator, for life management it is necessary to develop mechanistic models to predict the conditions under which stress corrosion cracking is plausible. Therefore, constant extension rate tests were carried out for Alloy 800 under various steam generator crevice chemistry conditions at applied potentials. These tests were designed to evaluate the stress corrosion cracking susceptibility of Alloy 800 under CANDU( steam generator operating conditions. Based on the experimental results, the recommended electrochemical corrosion potential/pH zone for Alloy 800 determined by electrochemical polarization measurements was verified with the respect of stress corrosion cracking ...
As part of a coordinated program, AECL is developing a set of tools to aid with the prediction and management of steam generator performance. Although stress corrosion cracking (of Alloy 800) has not been detected in any operating steam generator, for life management it is necessary to develop mechanistic models to predict the conditions under which stress corrosion cracking is plausible. Therefore, constant extension rate tests were carried out for Alloy 800 under various steam generator crevice chemistry conditions at applied potentials. These tests were designed to evaluate the stress corrosion cracking susceptibility of Alloy 800 under CANDU( steam generator operating conditions. Based on the experimental results, the recommended electrochemical corrosion potential/pH zone for Alloy 800 determined by electrochemical polarization measurements was verified with the respect of stress corrosion cracking ...
As part of a coordinated program, AECL is developing a set of tools to aid with the prediction and management of steam generator performance. Although stress corrosion cracking (of Alloy 800) has not been detected in any operating steam generator, for life management it is necessary to develop mechanistic models to predict the conditions under which stress corrosion cracking is plausible. Therefore, constant extension rate tests were carried out for Alloy 800 under various steam generator crevice chemistry conditions at applied potentials. These tests were designed to evaluate the stress corrosion cracking susceptibility of Alloy 800 under CANDU( steam generator operating conditions. Based on the experimental results, the recommended electrochemical corrosion potential/pH zone for Alloy 800 determined by electrochemical polarization measurements was verified with the respect of stress corrosion cracking ...
The CASTOC project addresses environmentally assisted cracking (EAC) phenomena in low alloy steels used for pressure boundary components in both Western type boiling water reactors (BWR) and Russian type pressurised water reactors (VVER). It comprises the four work packages (WP): inter-laboratory comparison test (WP1); EAC behaviour under static load (WP2), EAC behaviour under cyclic load and load transients (WP3); evaluation of the results with regard to their relevance for components in practice (WP4). The use of sophisticated test facilities and measurement techniques for the on-line detection of crack advances have provided a more detailed understanding of the mechanisms of environmentally assisted cracking and provided quantitative data of crack growth rates as a function of loading events and time, respectively. The effect of several major parameters controlling EAC was investigated with ...
Mechanical testing of controlled-purity Ni-xCr-9Fe-yC alloys at 360 C revealed an environmental enhancement in IG cracking and time-dependent deformation in high purity and primary water over that exhibited in argon. Dimples on the IG facets indicate a creep void nucleation and growth failure mode. IG cracking was primarily located at the interior of the specimen and not necessarily linked to direct contact with the environment. Controlled potential CERT experiments showed increases in IG cracking as the applied potential decreased, suggesting that hydrogen is detrimental to the mechanical properties. It is proposed that the environment, through the presence of hydrogen, enhances IG cracking by enhancing the matrix dislocation mobility. This is based on observations that dislocation-controlled creep controls the IG cracking of controlled-purity Ni-xCr-9Fe-yC in argon at 360 C and ...
The principle for working out the time-temperature schedule of the carbonization was determined through the investigation on the carbonization process of the green body and the phenol formaldehyde resin. During the carbonization process, the crack at lower temperatures is due to strain inhomogeneity produced in press. But the crack at higher temperatures results from the improper increasing rate of temperature. The application of the autoclave-carbonization process can increase the mechanical properties of the spherical fuel elements.
This paper dealt with the identification of possible damaging mechanism of the collector of the WWER 440 steam generator, cracking of primary collectors, corrosion damage of the protective coat of the primary collector circumferential weld, cracking of breathing space in the region of blinding effect by corrosion and strain, leaking of disassembling joint of the primary collector lid and with the integrity of heat exchanging tubes.
A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with a dihydrogen phosphate anion or a dihydrogen phosphite anion. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.
A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with an anion such as a dihydrogen phosphate anion or a dihydrogen phosphite anion and additionally with an ammonium salt other than a salt of an inorganic acid of phosphorus. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.
Nature of tube degradation was studied in support of horizontal steam generator lifetime calculations. Experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K(ISCC), and the crack growth rate were made to predict evolution of damage in tube walls. Experimental results were compared with in-service inspections experience. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that material of SG (steam generator) tubes ...
Nature of tube degradation was studied in support of horizontal steam generator lifetime calculations. Experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K(ISCC), and the crack growth rate were made to predict evolution of damage in tube walls. Experimental results were compared with in-service inspections experience. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that material of SG (steam generator) tubes ...
Explicit analytical formulas are derived for the stress intensity factors at the tips of a main crack and of a microcrack for the two-dimensional case of a collinear microcrack. This configuration is used to derive an estimate of the toughness degradation due to microcracks linking up with an advancing main crack. The implications of this estimate for theoretical predictions of the toughening due to stress-induced microcracking are discussed.
As characterization of artificial cracks formed underground by using the water pressure fracturing method, experiments have been carried out to detect relationship of pressurization and S-wave propagation time with the polarizing direction dependence. Openings are created when pressure in the vicinity of the artificial cracks increases greater than reopening pressure of micro cracks. Elastic wave velocity decreases in this region because of water in the opened micro cracks. Anisotropy is created in the S-wave propagation velocity due to influence from anisotropic reopening region when the artificial cracks are pressurized, and is separated into two components which polarize orthogonally with each other (micro splitting). Field experiments conducted at the Higashi-hachimantai field were analyzed by using wavelet transform. It was possible to detect the S-wave arrival time at high ...
Two kinds of Si3N4/SiC composite ceramics having different sintering auxiliaries were fabricated to investigate reproduction of crack healing phenomenon, effects of sintering auxiliaries on crack healing behavior, optimal crack healing conditions, and high-temperature strength characteristics of crack healed portions. The experiment used sinters added with SiC powder at 20% by volume, and hot-pressed under conditions of a sintering temperature of 1850 degC, time for two hours, and a pressure of 35 MPa. The sintering auxiliaries used are Y2O3 and Al2O3. In the experiment, pre-cracks were introduced into test specimens, and heat treatments were given in atmosphere and in argon gas atmosphere at 1300 degC for one hour. A four-point bending test was conducted in atmosphere as a strength test. The result of the experiment revealed that the materials which were heat-treated in atmosphere ...
Stress corrosion cracking tests in constant extension rate tensile (CERT) and constant load tensile (CLT) tests were conducted on Ni-xCr- 9Fe-yC in Ar, water, and a LiOH-boric acid solution. Cr and C improve the resistance of Ni-base alloys to IG cracking in both Ar and water at 360C. Since creep plays a role in IG cracking, one possible explanation for the role of the environment involves its effect on the creep. Experiments were conducted on the role of C in the deformation behavior and failure mode of Ni-16Cr-9Fe. Constant load experiments were conducted on Ni-16Cr-9Fe to determine if the CLT test is more aggressive than CERT. The electron backscattering technique in a SEM is being developed in order to extend the IG cracking studies to grain sizes typical of commercial alloys, 20-30 microns.
Stress corrosion cracking tests in constant extension rate tensile (CERT) and constant load tensile (CLT) tests were conducted on Ni-xCr- 9Fe-yC in Ar, water, and a LiOH-boric acid solution. Cr and C improve the resistance of Ni-base alloys to IG cracking in both Ar and water at 360C. Since creep plays a role in IG cracking, one possible explanation for the role of the environment involves its effect on the creep. Experiments were conducted on the role of C in the deformation behavior and failure mode of Ni-16Cr-9Fe. Constant load experiments were conducted on Ni-16Cr-9Fe to determine if the CLT test is more aggressive than CERT. The electron backscattering technique in a SEM is being developed in order to extend the IG cracking studies to grain sizes typical of commercial alloys, 20-30 microns.
Steam Generator (SG) tubes in PWR plant are periodically inspected using eddy current testing (ECT) method. In Japan, bobbin coil type dual function probe is used for full length inspection, but the detectability for circumferential crack is very poor, and to improve detectability for circumferential crack and supplement regular ECT, various kinds of multi segment eddy current probes and multi transducer ultrasonic testing (UT) method have been developed. ECT probes are constructed of multiple surfaceriding special winding differential type coils and UT probe consists of 16 transducers which are spaced equally around the probe circumference for 360deg wall coverage. Both of those EC and UT probes are designed effective to detect circumferential crack. On the other hand, various kinds of laboratory induced circumferential cracks have been made and destroyed to prove the detectability of these probes. ...
Abstract in english Higher olefins are produced as a by product in a number of refinery processes and are one of the potential raw materials to produce propylene. In the present study, FCC model feed compound was considered to explore the olefin cracking features and options to enhance propylene using 30% SAPO-34 zeolite as catalyst in a micro-reactor. The superior selectivity of propylene (73 wt%) and higher total olefin selectivity was obtained over 30% SAPO-34 catalyst than over Y or ZSM- (more) 5 zeolite catalysts. The thermodynamical constraints were found to be relatively less serious in the case of 1-hexene conversion. Most of the 1-hexene follows a direct cracking pathway to give two propylene molecules, due to weak acid sites and better diffusion opportunities. The higher temperature and short residence time could also suppress the hydrogen transfer reactions. From OPE (olefins performance envelop) the products were classified as ...
A common evaluation is given for creep crack growth and fatigue crack growth experiments which have been performed at the companies ABB, Siemens-KWU and KFA. The materials under investigation were X10NiCrAlTi32 20 (Alloy 800) and NiCr22Col2Mo (Alloy 617). Several production lots and semi-finished materials as well as welded materials have been tested. Testing techniques differed at the different labs. In order to eliminate the influence of individual testing techniques, material from some production lots was investigated at different labs. The given data cover fatigue crack growth (the materials were tested between room temperature and 1050[sup o]C; the influence of temperature, R-ratio, and frequency was investigated) and creep crack growth (Alloy 800 was tested between 550sup(o)C and 900sup(o)C, Inconel 617 between 800sup(o)C and 1000sup(o)C; the evaluation was done on the basis of the fracture ...
A common evaluation is given for creep crack growth and fatigue crack growth experiments which have been performed at the companies ABB, Siemens-KWU and KFA. The materials under investigation were X10NiCrAlTi32 20 (Alloy 800) and NiCr22Col2Mo (Alloy 617). Several production lots and semi-finished materials as well as welded materials have been tested. Testing techniques differed at the different labs. In order to eliminate the influence of individual testing techniques, material from some production lots was investigated at different labs. The given data cover fatigue crack growth (the materials were tested between room temperature and 1050"oC; the influence of temperature, R-ratio, and frequency was investigated) and creep crack growth (Alloy 800 was tested between 550sup(o)C and 900sup(o)C, Inconel 617 between 800sup(o)C and 1000sup(o)C; the evaluation was done on the basis of the fracture mechanics ...
Alloy 800 has been proposed for use in the receiver tube panel arrays of advanced solar central receiver (SCR) designs. In this application the alloy will be exposed to a molten mixture of sodium and potassium nitrate salts at temperatures ranging up to approximately 600/sup 0/C While these salts are routinely used in a variety of applications including metal heat treating and process heat transfer, common industrial experience has been limited to maximum temperatures of 400/sup 0/C - 450/sup 0/C. There is, therefore, considerable interest in the compatibility of these salts with containment alloys at the higher temperatures associated with SCR designs. Additionally, the containment alloy may be subject to thermally induced fatigue damage resulting from intermittent cloud cover and diurnal cycling. Previous work has found that slower near-threshold fatigue crack growth rates (FCGR) in Alloy 800 result when it is tested in molten nitrate salt at 600/sup 0/C ...
Tar sand bitumen is petroleum-based ultra-heavy oil, and has a great amount of reserve like coal. However, there are still a lot of problems for its highly effective utilization. This paper discusses whether the light components in bitumen show independent behavior during the thermal cracking of heavy components, or not. Solvent effect and reaction mechanism during the thermal cracking are also derived from the change of their chemical structures. Athabasca tar sand bitumen was separated into light and heavy fractions by vacuum distillation based on D-1660 of ASTM. Mixtures of the both fractions at various ratios were used as samples. Negative effect of the light fraction on cracking of the heavy fraction was observed with dealkylation and paraffin formation Polymerization of the dealkylated light fraction to the heavy fraction was suggested due to lack of hydrogen in the thermal cracking under nitrogen ...
Country Analysis Briefs: 1994 is a compilation of country profiles prepared by the Energy Markets and Contingency Information Division (EMCID) of the Office of Energy Markets and End Use. EMCID maintains Country Analysis Briefs (CABs) for specific countries or geographical areas that are important to world energy markets. As a general rule, CABs are prepared for all members of the Organization of Petroleum Exporting Countries (OPEC), major non-OPEC oil producers (i.e., the North Sea, Russia), major energy transit areas (i.e., Ukraine), and other areas of current interest to energy analysts and policy makers. As of January 1995, EMCID maintained over 40 CABs, updated on an annual schedule and subject to revision as events warrant. This report includes 25 CABs updated during 1994. All CABs contain a profile section, a map showing the country`s location, and a ...
Radiation hardening and radiation-induced chromium (Cr) depletion were related to intergranular stress corrosion cracking (IGSCC) response among various stainless steels (SS). Available data on neutron-irradiated materials were analyzed and correlations developed between fluence, yield strength, grain-boundary Cr concentration, and cracking susceptibility in high-temperature water environments. Large heat-to-heat differences in the critical fluence (0.2 neutrons/cm"2 to 2.5 x 10"2"1 neutrons/cm"2) for IGSCC were documented. Variability often was consistent with yield strength differences among irradiated materials. IGSCC correlated better to yield strength than to fluence for most heats, suggesting a possible role for radiation-induced hardening (and microstructure) on cracking. However, isolated heats revealed a wide range of yield strengths (450 MPa to 800 MPa) necessary to promote IGSCC which could not be explained by ...
As a partner in this project, Siemens Power Generation investigated the crack propagation characteristics of short cracks in CMSX4. This involved crack propagation tests under dynamic and static load, creep tests on samples of different geometries, and life calculations, with the following results: No typical short cracking behaviour was observed under dynamic loads. Short crack propagation at 950 C under static load is well described by the fracture mechanical parameter C* integral. Notched bar creep tests showed longer times to cracking for notched bars. [German] In dem Verbundprojekt hat Siemens Power Generation u.a. die Untersuchungen von Rissausbreitungsverhalten von Kurzenrissen in CMSX4 als Hauptaufgabe bekommen. Dabei wurden Rissausbreitungsversuche unter dynamischer und statischer Belastung, Kriechversuche an Proben verschiedener Geometrie und ...
Due to thermal gradients and load changes steam-turbine casings suffer combined creep-fatigue loading. Creep and fatigue portions depend on service conditions. Special interest is focused on the behaviour of creep-fatigue cracks, originated from potential defects due to construction and manufacturing weldments, on residual lifetime assessment. The project deals with the crack-growth behaviour at 530deg C and r.t. of welded and unwelded heat-resistant cast steels: 1% CrMoV-cast (GS-17 CrMoV 5 11, two melts: low and high V-content) and 12% CrMoV-cast (G-X 22 CrMoV 12 1). The crack planes of CT-specimens investigated, taken from manual arc-welded plates, were situated in the heat-affected zone (HAZ). The fatigue, creep and combined creep-fatigue crack-growth behaviour was investigated by means of low-frequency (0.5 and 0.05 Hz) tests, holding-time (20 min) tests and constant load tests up to about 5 000 h. ...
This paper highlights some of the conceptual and methodological problems involved in the compilation of statistics on economic aid to developing countries. Figures from the OECD Development Assistance Committee (DAC) and the Organization of Petroleum Exporting Countries (OPEC) member states are compared to point up problems in the interpretation of the statistics. One area of concern is the listing of funds provided by financial institutions located in the DAC countries. OPEC capital often forms a majority of such institutions; yet the figures do not measure the OPEC share of the capital nor its share of the risk borne in its provision of the loans. Another area of concern is bond purchases and subscriptions to syndicated loans by OPEC financial institutions in the financial markets of DAC countries. The flows in these instances, originating from OPEC sources, are merely channeled through the DAC ...
In the 150 kV power system of the Dutch energy utility MEGA Limburg cross-country faults have caused problems in the protection of high voltage transmission lines. A cross-country fault is the simultaneous presence of two single-phase earth connections in different phases and places within the grid. These cross-country faults can lead to the incorrect operation of a number of distance relays, which could result in the faulty disconnection of high voltage transmission lines. To gain an insight into these problems, the transient phenomenon in the power system during cross-country faults were studied. For this purpose, the simulation program EMTP (ElectroMagnetic Transients Program) has been used. Simulation models of the 150 kV power system and the measuring system of a distance relay were developed within EMTP. 7 figs., 1 ill.
Private transfers of capital from the Organization of Petroleum Exporting Countries (OPEC) to developing countries are intended to complement private transfers from the Organization of Economic Cooperation and Development (OECD) by tapping the emerging capital markets in the Middle East. Developing countries will be able to diversify their borrowing and gain additional financing. The long-term investment of oil-producing countries will benefit and the pressures on the banking institutions to recycle funds will lessen. Middle East capital markets include international loans and international bonds. The history of the Kuwaiti dinar (KD) bond market, with its advantages for both investors and borrowers, illustrates the successful development of a capital market. Financial intermediation needs to be improved, however, if the Middle East is to become efficient enough to compete with the Euromarkets. ...
The fatigue life variability of the #alpha#+#beta# titanium alloy, Ti-6Al-2Sn-4Zr-6Mo increased with decreasing stress level. The variability in life was found to be due to segregation of lives due to two failure mechanisms. A bimodal cumulative distribution model was shown to accurately describe the combined failure modes. The nominal failure processes for the two regimes were similar, with crack nucleation occurring in equiaxed #alpha#p particles, irrespective of life or stress level. However the variability in life was not controlled by the size of the crack-nucleating #alpha#p, but rather by the ability of the material to distribute deformation and avoid early crack nucleation.
ABSTRACT Traditional risk-based design process involves designing the structure based on risk estimates obtained during several iterations of an optimization routine. This approach is computationally expensive for large-scale aircraft structural systems. Therefore, this paper introduces the concept of risk-based design plots that can be used for both structural sizing and risk assessment for fracture strength when maximum allowable crack length is available. In situations when crack length is defined as a probability distribution the presented approach can only be applied for various percentiles of crack lengths. These plots are obtained using normalized probability density models of load and material properties and are applicable for any arbitrary load and strength values. Risk-based desi...
The patent describes a method for repairing leakage-causing cracks and fissures in a cryogenic heat exchanger. It comprises: reducing the interior pressure of the heat exchanger to a level which does not exceed the external pressure upon the hear exchanger while maintaining the temperature of the heat exchanger at a low level relative to the ambient external temperature; applying a curable liquid filler composition to the surface of the heat exchanger proximal the leakage site for seepage into the cracks and fissures located at the leakage. The composition upon a relatively short period of cure at low temperature forming a solid material which fills the cracks and fissures; curing the filler composition; and, applying a sealant composition to the surface of the heat exchanger at the filled leakage site. The sealant composition having long-term sealing performance under cyrogenic conditions.
An effect of load conditions on Corrosion Fatigue Crack Propagation (CFCP) behavior of High Performance Steel (HPS) under seawater environment was investigated. Fatigue crack propagation tests under several load conditions including stress ratio and load frequency were conducted in air and 3.5% NaCl solution environments. Corrosion/fatigue ratio factor, C/F, particularly was defined to analyze the effect of such conditions. As shown in the results, a decrease of load ratio and frequency leads to an increase of C/F factor. Consequently, under lower loading frequency and stress ratio, the seawater condition causes much more significant effect on CFCP behavior of HPS.
Clayey soils containing smectites are widely used for construction of liner and cover systems to reduce the hydraulic conductivity in geotechnical applications because of their low permeability and high cation exchange capacity. However, the compacted clayey soils crack on drying because of their high swelling potential, and their hydraulic conductivities increase. To solve this problem, it is essential to stabilize the clayey soils using additive materials. The aim of this study is to examine the suitability of silica fume as a stabilization material to reduce the development of desiccation cracks in compacted clayey liner and cover systems. Natural clayey soil and clayey soil?silica fume mixtures were compacted at the optimum moisture content and subjected to laboratory tests. The result...
The electrochemical behaviour and fracture morphology of homogenized and sensitized type SAE 304 stainless steel U bent specimens, in 3% NaCl solution, at pH=2.0 and pH=7.0 both at room temperature and 100"0C was studied. Polarization curves, galvanostatic and potentiostatic experiments were run. It could be observed that high temperature and low pH favour transgranular cracking and longer sensitization times lower fracture time and tend to give rise to intergranular fracture. Light sensitization can produce transgranular cracking even at room temperature, when the homogenized alloy does not present stress-corrosion cracking for the same condition. (Author).
Commercial rolled magnesium sheets of alloys AZ31 (Mg-3 mass%Al-1 mass%Zn) and ZE10 (Mg-1 mass% Zn-<1 mass% Rare Earths) in O-temper condition were used for blanking experiments near room temperature. A serrated fracture surface can be observed in case of AZ31 but not in case of ZE10. During the shearing process of the AZ31 sheet, many micro cracks parallel to the sheet plane are generated in the shearing zone. These micro cracks lead to the formation of loose particles during the shearing operation, which interfere with further processing of the part and incur additional costs by increasing the scrap rate. It is found that the strong basal texture of this alloy is an important reason for the generation of such serrated cracks. In this paper a new method of selective texture modification i...
Giant magnetoresistance (GMR) has been used with Eddy current testing to detect small defects not only in thin film structures but also in multilayered metallic structures. This work detected small scratches in the thin film under the surface where these defects were unable to be inspected or monitored by regular testing. In addition, rotational GMR magnetic sensor based Eddy current probes were used for detecting buried corner cracks at the edge of holes in metallic structures. The results of this study proved that giant magnetoresistance is very powerful and effective to sense the magnetic field, which is the result from the perturbation of the Eddy currents caused by a defect. This method can be used for quality control of metallization layers on silicon wafer and to detect cracks in thick structures such as cracks in aging aircraft.
During a regular inspection of the Boiler Auxiliaries at one of the Dutch Electricity Production Companies serious cracks were found in the cover and casings of the feed water circulation pumps in two units after 108.000 and 122.000 hours of boiler operation. Kema Laboratories carried out Failure analyses on boat samples at the cracked areas. Corrosion fatigue cracking was found on the inner side of the GS-24CrNiMo325 casing. Shop Weld repairs were carried out using a newly developed mechanized Plasma Welding Technique. The repaired feed water circulation pumps showed no problems alter several years of operation. The costs of repair were substantially lower than the costs of replacement. (orig.) 3 refs.
The nucleation of microdamage under dynamic loading was investigated through planar impact experiments accomplished with a light gas gun. The microscopic observation of recovered and sectioned specimens showed that microcracks were nucleated only by cracking of brittle particles inside material. However, for comparison the in situ static tensile tests on the same material conducted with a scanning electron microscope showed that the microcracks were nucleated by many forms those were fracture of ductile matrix, debonding particles from matrix and cracking of brittle particles. The quantitative metallographic observations of the specimens subjected to impact loading showed that most of the cracked particles were situated on grain boundaries of the aluminum matrix. These facts suggested the concept of critical size and incubation time of submicroscopic cavities in the dynamic case and the mechanism of embryo-damage induced ...
Briefly described is knowledge of crevice corrosion, corrosion cracking and denting. In evaluating the corrosion resistance of steam generator materials it is necessary to distinguish corrosion problems caused by the primary coolant side and by the secondary circuit side. At present tubes are manufactured of 7 austenitic alloys of a different chemical composition, and available information shows that views on their corrosion resistance differ. Greatest attention has been devoted to corrosion cracking in the presence of NaOH. Findings related to I-600, I-800, I-690 and AISI 316 are given. Corrodibility by sulfur-containing products is now being studied, namely the intercrystalline corrosion cracking caused by the presence of H/sub 2/S/sub 4/O/sub 6/. Knowledge gained in this respect is summed up.
Briefly described is knowledge of crevice corrosion, corrosion cracking and denting. In evaluating the corrosion resistance of steam generator materials it is necessary to distinguish corrosion problems caused by the primary coolant eide and by the secondary circuit side. At present tubes are manufactured of 7 austenitic alloys of a different chemical composition, and available information shows that views on their corrosion resistance differ. Greatest attention has been devoted to corrosion cracking in the presence of HaOH. Findings related to I-600, I-800, I-690 and AISI 316 are given. Corrodibility by sulfur-containing products is now being studied, namely the intercrystalline corrosion cracking caused by the presence of H_2S_4O_6. Knowledge gained in this respect is summed up. (J.P.).
Gelatine is a reliable tissue simulant in wound ballistic experiments. The projectile penetrating the gelatine transfers energy and causes radial cracks according to the temporary cavity. Thus the crack length is a function of the energy spent in the medium. In practice the fissures are poorly contrasted for which reason an enhancement of contrast was searched. A series of six shoots with expanding bullets (9mmx19 Action-5, 9mmx19 Quick Defense 1, 5.56mmx45 Styx Action) was realized on 10% gelatine blocks at 4^oC temperature. Three blocks were marked with acryl paint on the front, three blocks were shot native. The blocks were cut in slices of 1cm thickness and optically scanned. The evaluation was performed according to Fackler's wound profile, the total crack length method and the polygo...
This paper explores how an aid-funded Ph.D.-programme in mathematics education instituted in some Southern African Development Community countries measures up to issues related to research capacity development projects. The research capacity development programme is described and reflected against mutual benefit, relevance, sustainability and prioritization of the location of project funding expenditure--some of the constructs in the discourse on research capacity development initiatives. It is found that the benefits of the programme are indeed mutual; the outcomes regarding relevance and sustainability are more uncertain and the location of expenditure of the funding is not overtly in favour of the donor country.
A database has been compiled on human dietary intakes of trace elements by populations groups living in various countries. The main sources of information used were (1) publications in the open scientific literature, and (2) data submitted to the IAEA in response to a questionnaire. The database contains 1,758 intake values covering 35 elements and 47 countries. In this report the data are listed in various ways to facilitate identification of intake values for any specified country, element and population group. 4 refs, 5 tabs.
The present volume provides standardized energy balance sheets expressed in a common unit of tons of oil equivalent for all OECD Countries. It covers the years 1970 to 1982 year by year and includes many revisions and additions to data previously published. The balances in the present volume are based on data published in OECD Energy Statistics 1971-1981 and OECD Energy Statistics 1981-1982. Tables for each OECD Country include production, import, export, consumption by the different industries, transportation, agriculture, residential sector of the different energies: solid fuels, petroleum, gas, nuclear power and hydroelectricity.
This file is devoted to the Chernobyl accident. It is divided in four parts. The first part concerns the accident itself and its technical management. The second part is relative to the radiation doses and the different contaminations. The third part reports the sanitary effects, the determinists ones and the stochastic ones. The fourth and last part relates the consequences for the other European countries with the case of France. Through the different parts a point is tackled with the measures taken after the accident by the other countries to manage an accident, the cooperation between the different countries and the groups of research and studies about the reactors safety, and also with the international medical cooperation, specially for the children, everything in relation with the Chernobyl accident. (N.C.)
This article identifies the key role of the sugar industry in the rural development of developing countries. The Indian sugar industry, already second largest among the country`s processing industries, shows even greater potential, according to the Plan Documents (shown in a table). The potential of waste heat in sugar processing plants, which produce white crystal sugar using the double sulphitation clarification process, is estimated at 5757.9 KJ/kg of sugar. Efficient waste heat recovery (WHR) systems could help arrest the trend of increasing production costs. This would help the sugar industry not only in India, but in many other countries as well. The innovative methods suggested and discussed briefly in this article include dehydration of prepared cane, bagasse drying, and juice heating using waste heat. These methods can reduce the cost of energy in sugar production by at least 10% and improve efficiency and ...
According to the environmental Kuznets curve hypothesis, environmental degradation increases in the early stages of growth, but it eventually decreases as income exceeds a threshold level. It is thus often argued that if international trade increases incomes then it can also have a positive impact on environmental quality. So far, these hypotheses have been widely empirically tested for the developed countries. However, it is still uncertain whether positive effects of international trade on growth and on the environment may also hold in developing countries. One of the major difficulties in testing these relations in developing countries is the poor quality of environment related data. In this analysis this problem is reduced by constructing a structural equation model (SEM) with three la...
BackgroundUse of Traditional Chinese medicine (TCM), an important category of complementary and alternative medicine (CAM), has increased substantially in Western countries during...Full Text Available
This paper overviews the curricula of nuclear medicine (NM) undergraduate training in 34 Central and Eastern European (CEE) and 37 European Union (EU) medical faculties. The data show enormous variation in the number of hours devoted to nuclear medicine, varying between 1-2 to 40 hours and highly differentiated concepts/ideas of nuclear medicine training in particular countries. In most EU countries this teaching is integrated with that of radiology or clinical modules, also with training in clinical physiology. In many CEE countries teaching and testing of NM are independent, although integration with other teaching modules is frequent. The paper discusses the differences in particular approaches to nuclear medicine teaching. (author)
Careers Business / Policy USAID: From The American People - Link to USAID Home Page Health USAID's 50th Anniversary Health Overview » Overview Technical Areas Countries...
Snakebites are common among the rural population of developing countries. The severity of venomous snakebites depends on several factors, including the location of the bite, the amount of venom injected,...Full Text Available
Objectives:Myocardial infarction (MI) is a leading cause of death in both the industrialized and developing countries globally. The economic evaluation of MI is undertaken...Full Text Available
This paper summarizes the main features of four current REDD proposals: Compensated Reduction, Papua New Guinea et al; Joint Research Center; and Brazil. ... ...
BackgroundBrucellosis is a zoonosis of veterinary, public health and economic significance in most developing countries. Human brucellosis is a severely debilitating disease that...Full Text Available
About a third of the population in the cities of developing countries live in slums and shanty towns. By the year 2000 it is estimated that this number will grow to 2200 million, and by 2025 about 57%...Full Text Available
Fava beans (Vicia fava) are cultivated rather widely in most countries of the Eastern Mediterranean area and provide a cheap but protein-rich food that can be eaten alone, in various...Full Text Available
"Physics in the United States is in a crisis that the country may lose the leadership in basic particle research in coming years, a report of the National Research Council warned." (1 page)
The supernatural fears associated with the experience of isolated sleep paralysis in the culture of developing countries is sometimes associated with the evolution of somatic symptoms of psychological...Full Text Available
With the increased costs of maintaining boilers and chillers entrepreneurs around the country have offered magnetic and similar devices to facilities as viable alternatives to their maintenance program. This report gives a brief history of some of the pre...
Current decisions on greenhouse gas emissions may have effects on human well being for centuries. This project has aimed to extend the economic models designed for analyzing this particular issue. A closely related topic follows from the fact that emitting CO{sub 2} can be interpreted as a utilization of a free access resource, i.e., when countries gain from utilizing cheap fossil fuels (relative to noncarbon energy sources), the possible loss any country suffers from climate change is only a negligible fraction of the total loss of all countries. Thus, from a global point of view, the incentives for an individual country to abate emissions is low. Economic understanding of these problems calls for dynamic game-theoretical models
A letter of inquiry was sent to 21 countries in Europe to ascertain their experience of diphtheria during the last 20 years. An analysis of the 15 replies showed that all relied on childhood vaccination...Full Text Available
BackgroundHypertension is a common non communicable condition worldwide. In developing countries (including Nigeria), the use of complementary and alternative medicine (CAM) is common....Full Text Available
Chemical leucoderma is an industrial disorder in developed countries and the common causative chemicals are phenols and catechols. Due to stringent controls and preventive measures the incidence has...Full Text Available
SummaryBackgroundMalaria, a non-fatal disease if detected promptly and treated properly, still causes many deaths in malaria-endemic countries with...Full Text Available
The role of the environment is an important issue in policy making and the accurate assessment of the environmental conditions is vital. In this paper, using nonparametric techniques, an environmental efficiency index is developed for each of the OECD countries. These indexes allow one both to do cross section comparisons on the state of each country's production process in its treatment of undesirable outputs and also to trace each country's modification of their production processes overtime. Furthermore in this study we investigate the factors underlying societies' environmental concerns that eventually lead to changes in the environmental efficiency. The results provide further empirical evidence for the environmental Kuznets curve hypothesis. 16 refs.
Two austenitic steels, 316 Stainless Steel and Alloy 800, have been examined under conditions of both isothermal low cycle fatigue (LCF) and thermomechanical fatigue (TMF). The TMF tests were conducted between 649 and 360/sup 0/C with a carefully controlled triangular waveform. The LCF tests were performed at 649/sup 0/C and both kinds of tests were subjected to a strain range of 0.5%. TMF shortened life to 40% for 316 Stainless Steel and to 5% for Alloy 800. The microstructural evolution occurring in both alloys has been examined and we conclude these do not play a role in the life shortening caused by TMF. The TMF does produce asymmetric hysteresis loops with large tensile peak stresses in tests where the maximum temperature corresponded with the peak compressive stress. The influence of TMF on fatigue crack growth rates has been measured and it was found that TMF accelerated crack growth in Alloy 800 and slowed it down slightly in 316 ...
As a basic research to consider aging deterioration of the operating nuclear power plant to seismic fragility analysis, aging deteriorations occurring safety related equipment of both Kori unit 1 and Wolsung unit 1, are investigated in this study. First of all, 378 and 152 safety related equipment are selected at Kori unit 1 and Wolsung unit 1 respectively. Seismic review team including seismic capability engineer, is organized and seismic walkdown is carried out using the nondestructive tests. As a results of seismic walkdown, crack is a typical aging deterioration which can reduce the seismic safety of safety related equipment and the other aging deteriorations such as concrete compressive strength, corrosion, and tightness of anchor bolt, have a much smaller influence than crack. In order to manage the aging deterioration data collected through the seismic walkdown in effective and systematic, EDS(Evaluation of Deteriorated System) DB is ...
As a basic research to consider aging deterioration of the operating nuclear power plant to seismic fragility analysis, aging deteriorations occurring safety related equipment of both Kori unit 1 and Wolsung unit 1, are investigated in this study. First of all, 378 and 152 safety related equipment are selected at Kori unit 1 and Wolsung unit 1 respectively. Seismic review team including seismic capability engineer, is organized and seismic walkdown is carried out using the nondestructive tests. As a results of seismic walkdown, crack is a typical aging deterioration which can reduce the seismic safety of safety related equipment and the other aging deteriorations such as concrete compressive strength, corrosion, and tightness of anchor bolt, have a much smaller influence than crack. In order to manage the aging deterioration data collected through the seismic walkdown in effective and systematic, EDS(Evaluation of Deteriorated System) DB is ...
Microstructural analyses by advanced metallographic techniques were conducted on mockup welds and a cracked BWR core shroud weld fabricated from Type 304L stainless steel. heat-affected zones of the shroud weld and mockup shielded-metal-arc welds were free of grain-boundary carbide, martensite, delta ferrite, or Cr depletion near grain boundaries. However, as a result of exposure to welding fumes, the heat-affected zones of the welds were significantly contaminated by fluorine and oxygen which migrate to grain boundaries. Significant oxygen contamination promotes fluorine contamination and suppresses classical thermal sensitization, even in Type 304 steels. Results of slow-strain-rate tensile tests indicate that fluorine exacerbates the susceptibility of irradiated steels to intergranular stress corrosion cracking. These observations, combined with previous reports on the strong influence of weld flux, indicate that oxygen and fluorine ...
... in Ti-6Al-4V has been studied quite thoroughly [5-7], much of the work resulting from the Air Force-sponsored High Cycle Fatigue initiative [8]. In ...
From this literature study it was found that ferrocement is a composite material of superior mechanical properties when compared to reinforced concrete. This superiority is reflected in greater flexural crack strength, tensile strength, ductility, and imp...
A scientific breakthrough at Queen's University's Sudbury Neutrino Observatory has received major international recognition. The journal Science ranked the discovery that cracked the "neutrino problem" second, in the journal's top 10 scientific achievements of 2002 (1/2 page).
Probabilistic sensitivities using the score function method are developed for a lifing analysis of an alpha + beta titanium alloy in a round bar under axial fatigue load. Sensitivities with respect to the statistical inputs of the crack initiation size (a...
Methodology based on probabilistic fracture mechanics (PFM) is finding increasing acceptability in demonstrating safety of Nuclear Power Plant (NPP) piping. In PFM, the methods of fracture mechanics and reliability theory are combined for assessing the reliability of components, which contain cracks. In this work, reliability assessment of Tarapur Atomic Power Plant (TAPP) 3-4 Primary Heat Transport (PHT) piping is done using PFM. Monte Carlo simulation with stratified sampling is used as a variance reduction technique. PFM model assumes a pre-existing circumferential surface crack before the start of plant operation. The crack grows in size during the lifetime of the plant due to the fatigue loading. This part-through wall crack having escaped hydro-test and pre-service inspection, may result in either a through wall flaw (leak) or may lead to the rupture of the piping. R6 method is used as failure ...
EPRI has sponsored an experimental program in the pipe whip impact and pipe rupture and depressurization areas. Sixteen pipe whip tests were performed with 3 in Schedule 80 (or 10) carbon steel pipes impacting on rigid target or concrete slab. The major testing parameters include distance, impact location, pipe rupture location, and concrete slab thickness and strength. The piping crushing at impact correlates with impact force and target response behavior. Conservatism was established by comparing measured and calculated impact forces. The pipe rupture and depressurization tests were carried out using 6 in stainless steel and carbon steel pipes under either PWR or BWR fluid conditions. These tests are of axial crack with initial machined-in surface flaw. It was found that pipe rupture would occur only if a long unstable through-wall crack was embedded in a sufficiently long unstable part-through crack (in the pipe wall). ...
An experiment was conducted on the structure of mesoscopic calculating method for cement-based composite materials. The purpose was utilization for the simulation of mesoscale failure processes and the development of new composite materials. Mesh split based on Voronoi polygons was applied as the discrete limit analysis of the cement-based composite materials containing aggregate particles taking the arrangement of random particles into consideration, and a two-dimensional rigid-body/spring model was employed as the model. The nonhomogeneity of concrete was represented by three kinds of different spring parameters which were aggregate, mortar matrix and their interfaces. The simulation results were summarized as follows: The stress-strain curve went into a non-linear state from the 30% of the maximum stress. The generation of interfacial crack started on the side of the aggregate, but the propagation of the crack was stable. Deformation became ...
This report is a continuation of the former efforts to elucidate the behavior of ferrocement concrete in static and dynamic stress fields. The influence of various reinforcements on pre and post cracking of thin sections forms the main topic of this repor...
A micro-mechanistic understanding of bone fracture that encompasses how cracks interact with the underlying microstructure and defines their local failure mode is lacking, despite extensive research on the response of bone to a variety of factors like aging, loading, and/or disease. Micro-mechanical models for fracture incorporating such local failure criteria have been widely developed for metallic and ceramic materials systems; however, few such deliberations have been undertaken for the fracture of bone. In fact, although the fracture event in mineralized tissues such as bone is commonly believed to be locally strain controlled, until recently there has been little experimental evidence to support this widely held belief. In the present study, a series of in vitro experiments involving a double-notch bend test geometry are performed in order to shed further light on the nature of the local cracking events that precede catastrophic fracture ...
This report summarizes work performed by Argonne National Laboratory on fatigue and environmentally assisted cracking (EAC) in light water reactors from January 1997 to June 1997. Topics that have been investigated include (a) fatigue of carbon, low-alloy, and austenitic stainless steels (SSs) used in reactor piping and pressure vessels, (b) irradiation-assisted stress corrosion cracking of Types 304 and 304L SS, and (c) EAC of Alloys 600 and 690. Fatigue tests were conducted on ferritic and austenitic SSs in water that contained various concentrations of dissolved oxygen (DO) to determine whether a slow strain rate applied during various portions of a tensile-loading cycle is equally effective in decreasing fatigue life. Slow-strain-rate-tensile tests were conducted in simulated boiling water reactor (BWR) water at 288 C on SS specimens irradiated to a low fluence in the Halden reactor and the results were compared with similar data from a ...
A micro-mechanistic understanding of bone fracture thatencompasses how cracks interact with the underlying microstructure anddefines their local failure mode is lacking, despite extensive research nthe response of bone to a variety of factors like aging, loading, and/ordisease.
The goal of this study was to evaluate topics used to troubleshoot circuit boards with known or suspected thermally intermittent components. Failure modes for thermally intermittent components are typically mechanical defects, such as cracks in solder paths or joints, or broken b...
In order to develop competitive and reliable nuclear power generation systems, development of innovative structural design methods is indispensable and risk-based design approach based on the assessment of failure probability is being developed. Fatigue is commonly considered as an important contributor to failure probability in many components of reactor systems and its assessment gives a large influence on total reliability of the plants. In order to assess its effect on the reliability, propagation of cracks needs to be evaluated as well as their initiation and pre-existence probability. As a part of new design approach, efforts are being taken to develop a simplified estimation method for fatigue crack growth under cyclic application of thermal and thermo-mechanical loading. A simplified estimation method of J-integral based on reference stress method and elastic follow-up factor was developed based on many finite element analyses and ...
S>Hydrogen-induced delayed failure in an alpha-beta titanium alloy (4Al-- 4Mn) was sensitive to microstructure. A quenched structure was less susceptible to delayed failure than aged or annealed structures. The tendency for delayed failure was magnified in all structures by an increase in hydrogen content or an increase in strength level. Hydrogen-induced delayed failure occurred by a process of crack initiation and controlled crack growth. Delayed failures resulting from creep were also encountered. Plastic strain resulting from creep tended to retard crack initiation. Changes occurring in material under static load prior to formation of cracks were reversible, as long as no appreciable plastic strain occurred, indicating stress-induced diffusion of hydrogen. Hydrogen-induced delayed failure disappeared at both high and low temperatares. The time required for failure as ...
An ampoule corrosion tests technique is presented for making a comparative corrosion-proof estimation of austenitic steels and alloys which are candidate materials for the ITER first wall and shield blanket. Influence of Cl"- on the rate and character of corrosion cracking has been determined. The dependence of time before destruction on Cl"- contents was obtained by experiments in twice-distilled water at a Cl"- content value of less than 0.05 mg/l. Kinetics of a corrosion crack growth has been determined by way of acoustic emission and measurement of electrical resistance. It has been revealed, that corrosion cracking of 316L and 316Ti steels in water with 100 mg/l of Cl"- takes place at temperatures over 50 C. For 316L (Russian analogue), 316Ti, 08Cr18Ni10Ti (type 304), 00Cr16Ni15Mo3Nb (type 316) steels and CrNiMo-1 (42-47%Cr, 1%Mo, Ni-base) alloy corrosion long-term strength and crack-resistance ...
An experimental study was conducted to determine the effects of ply thickness in composite laminates on thermally induced cracking and changes in the coefficient of thermal expansion (CTE). After a few thermal cycles, laminates with thick-plies cracked, resulting in large changes in CTE. CTE`s of the thin-ply laminates were unaffected by microcracking during the first 500 thermal cycles, whereas, the CTE`s of the thick-ply laminates changed significantly. After about 1500 cycles, microdamage had also reduced the CTE of the thin-ply laminates to a value of about half of their initial value.
This paper describes two research programs which are currently underway in the author's laboratory to investigate the effect of fluid flow on the degradation of power plant materials in high temperature/high pressure aqueous environments. These programs include the design and operation of a controlled hydrodynamic corrosion testing apparatus that can be used to study the general and localized corrosion characteristics of alloys in simulated nuclear reactor environments, and a study of the effect of flow velocity on the stress corrosion cracking of ASTM A508 C1.2 steel and Type 304SS in simulated BWR heat transport fluids.
A review of the performance of steam generator tubes in 116 water-cooled nuclear power reactors showed that tubes were plugged at 54 (46 percent) of the reactors. The number of tubes removed from service decreased from 4 692 (0.30 percent) in 1981 to 3 222 (0.20 percent) in 1982. The leading causes of tube failures were stress corrosion cracking from the primary side, stress corrosion cracking (or intergranular attack) from the secondary side and pitting corrosion. The lowest incidence of corrosion-induced defects from the secondary side occurred in reactors that have used only volatile treatment, with or without condensate demineralization.
Some examples are given of design adaptations, e.g. U-bend support, tube spacer grid, flow distribution baffle, triangular tube pitch, tube-tubeplate sheet connection, which reduce the tendency to various types of corrosion (stress corrosion cracking, tube denting, tube wastage, intergranular cracking). A basic diagram of the secondary circuit is shown. Oxygen, corrosion product and impurity control in the secondary circuit is described. (E.J.). 19 figs., 6 refs.
The shot peening of the outer surface of Alloy 800 is proposed by the steam generator supplier in order to increase the stress corrosion cracking resistance of the tubes. The benefits and drawbacks of such a treatment are evaluated, focusing on the main concern i.e. a possible enhanced tendency of stress corrosion cracking at the transition of the expanded tube-to-tubesheet joint. Stress corrosion tests as well as residual stresses measurements demonstrate no significant difference between peened and unpeened tubes at that location. The other concerns such as stability of the compressive stresses, increased risk of pitting or intergranular attack and pollution of the secondary circuit by fragmented beads appear the as minor concerns.
A gelcasting composition has improved drying behavior, machinability and shelf life in the dried and unfired state. The composition includes an inorganic powder, solvent, monomer system soluble in the solvent, an initiator system for polymerizing the monomer system, and a plasticizer soluble in the solvent. Dispersants and other processing aides to control slurry properties can be added. The plasticizer imparts an ability to dry thick section parts, to store samples in the dried state without cracking under conditions of varying relative humidity, and to machine dry gelcast parts without cracking or chipping. A method of making gelcast parts is also disclosed.
The failure took place on a welded elbow pipe which exhibited a catastrophic transverse rupture. The failure was located on the welding HAZ region, parallel to the welding path. Branching cracks were detected at the edge of the rupture area. Deposits of corrosion products were also spotted. The optical microscope analysis showed the presence of transgranular failures which were related to the stress corrosion cracking (SCC) and were predominantly caused by the welding residual stress. The significant difference in hardness between the welded area and the pipe confirmed the findings. Moreover, the failure was also caused by the low Mo content in the stainless steel pipe which was detected by means of spark emission spectrometer. (orig.)
The report summarizes ten years of experience in the analysis and evaluation of ultrasonic testing data measured in turbine and generator rotors. Apart from the information on type, position, size and distribution of flaws, the expert knowledge achieved in an interpretation of ultrasonic signals yields further insight, as e.g.: - Confirmation of assumptions taken as a basis for fracture-mechanical analysis of these flaws with regard to crack initiation and crack growth under low-cycle fatigue conditions (O=0.7-1 Rp 0.2, N<25.000 growth in length); - enhanced information on a correlation of ultrasonic testing data with the real flaw size. (orig.).
A computer code ICRKFLO was used to simulate the multiphase reacting flow of fluidized catalytic cracking (FCC) riser reactors. The simulation provided a fundamental understanding of the hydrodynamics and heat transfer processes in an FCC riser reactor, critical to the development of a new high performance unit. The code was able to make predictions that are in good agreement with available pilot-scale test data. Computational results indicate that the heat transfer and droplet evaporation processes have a significant impact on the performance of a pilot-scale FCC unit. The impact could become even greater on scale-up units.
An Al-5%Mg-0.18%Mn-0.2%Sc-0.08%Zr-0.002%Be was subjected to equal-channel angular extrusion up to true strains of #approx#3 and #approx#8, that resulted in the formation of partially recrystallized and fully recrystallized structure, respectively. It was shown that the alloy with partially recrystallized structure exhibits highest strength and ductility. The material with fully recrystallized structure showed lowest fatigue crack growth rate and highest value of fracture toughness. Reasons of this unusual effect of microstructure on crack propagation resistance under fatigue are discussed.
In this project the influence of residual compression stresses on the stress corrosion cracking behaviour of the turbine disc steel 26 NiCrMoV 14 5 (Rp(sub 0.2) = 850 N/mm(sup 2)) was investigated. The residual compression stresses were produced by shot p...
This work contains 27 chapters which cover recent advances in fracture mechanics applied to cement-based composites: concrete, reinforced concrete, and fiber reinforced concrete. The book, based on a NATO Advanced Study Institute, is a comprehensive survey of treating nonlinearity associated with crack growth in brittle materials such as cement composites, rocks and ice. The book is divided into 8 major themes: advances in nonlinear fracture mechanics; fracture processes; numerical modelling of fracture; experimental methods of determining fracture parameters; damage and continuum modelling; strain-rate and dynamic effects of crack propagation; stress-corrosion, time and temperature effects on fracture; and implications for concrete structures.
The susceptibility of CHN35VT-VD and 08CH18N10T stainless steels to stress corrosion cracking in water environment, simulating water solution found in threaded holes, was investigated using rising load line displacement tests of precracked C(T) specimens. To judge the role of oxidant on stress corrosion cracking of both stainless steels, the effect of dissolved oxygen content (fully deaerated water, water aerated at the beginning of the test) was studied. 7 refs.
This paper obtains the acidity spectra of modernites and SVK-zeolites from the heats of adsorption of NH/sub 3/ at 300 C and compares the catalytic activity of these zeolites with the cracking of n-octane and the isomerization of o-xylene. It is shown that the calculation of the specific catalytic activity of centers of different strengths by the method of regional rates allows one to predict the activity of the zeolites from the acidity spectra. It follows from the calculation that only the centers of Bronsted acidity are active towards cracking but that the centers of Lewis acidity are also active towards isomerization.
The properties of the passive films formed on Alloy 600 at different applied potentials in 10% NaOH solution at 315 .deg. C was studied using in situ AC impedance and polarization measurements. The results were correlated with the stress corrosion cracking (SCC) behavior obtained from the C-ring tests in the same conditions. The change of the semiconductive property and the peak of relaxation time were observed at 0.2 V where the SCC rate showed a maximum. These results were also consistent with the prediction parameter for SCC obtained from fast and slow polarization scans.
During the Bruce A Nuclear Generating Station (BNGS-A) Unit 1 1997 planned outage, a dew point search method identified a leak in one steam generator(SG) tube. Subsequently, the tube was inspected with all available eddy current probes and removed for examination. The initial inspection results and metallurgical examination of the removed tube confirmed that the leak was due to intergranular attack/stress corrosion cracking (IGA/SCC) emanating from the secondary side of the tube at the top of the tubesheet location. Subsequently, eddy current and ultrasonic indications were found at the top of the tubesheet of other Alloy 600 SG tubes. To investigate the source of the indications and to validate the inspection probes, sections of 40 tubes with various levels of damage were removed. The metallurgical examination of the removed sections showed that both secondary side and primary side initiated, circumferential, stress corrosion cracking and ...
The primary coolant oxidises the surfaces of construction materials in nuclear power plants. The properties of the oxide films influence significantly the extent of incorporation of actuated corrosion products into the primary circuit surfaces, which may cause additional occupational doses for the maintenance personnel. The physical and chemical properties of the oxide films play also an important role in different forms of corrosion observed in power plants. This report gives a short overview of the factors influencing activity build-up and corrosion phenomena in nuclear power plants. Furthermore, the most recent modifications in the water chemistry to decrease these risks are discussed. A special focus is put on zinc water chemistry, and a preliminary discussion on the mechanism via which zinc influences activity build-up is presented. Even though the exact mechanisms by which zinc acts are not yet known, it is assumed that Zn may block the diffusion paths within the oxide film. This ...
The creep crack growth properties of two versions of Alloy 800 have been compared at 500 and 600"0C in the Grade II condition in tests up to 10"4 hours duration. The two alloys were a low carbon alloy containing (wt.%) 0.024 C, 0.5 Ti, 0.3 Al (Alloy B) and a higher carbon alloy containing (wt.%) 0.038 C, 0.2-0.3 Ti, 0.2-3.0 Al (Alloy J). At 600"0C, Alloy B attained maximum age hardening in 10"2 hours, whereas J did not harden significantly in time up to 10"4 hours. Both alloys age hardened at 550"0C with Alloy J hardening more rapidly than B. The creep displacements and displacement rates in small compact tension specimens at 600"0C were smaller than Alloy B than in Alloy J. However, failure times were shorter in Alloy B because of lower displacements for crack initiation and propagation and higher crack growth rates. At 550"0C the displacements for initiation and propagation in Alloy J were smaller than at 600"0C. A ...
A theoretical model was developed to simulate this phenomenon, under some specific assumptions. The model simulates: the generation and decay of radon within the soil; its transport throughout the soil due to diffusion and convection induced by the pressure disturbance applied at a crack in the basement; its entrance into the house through the crack; and the resultant indoor radon concentration. The most important assumptions adopted in the model were: a steady-state condition; a house with a basement; a geometrically well-defined crack at the wall-floor joint in the basement; and a constant negative pressure applied at the crack in relation to the outside atmospheric pressure. Two three-dimensional finite-difference computer programs were written to solve the mathematical equations of the model. The first program, called PRESSU, was used to calculate: the pressure distribution within the soil as a ...
This report summarizes work performed by Argonne National Laboratory (ANL) on fatigue and environmentally assisted cracking (EAC) in light water reactors (LWRs) during the six months from October 1993 to March 1994. EAC and fatigue of piping, pressure vessels, and core components in LWRs are important concerns in operating plants and as extended reactor lifetimes are envisaged. Topics that have been investigated include (a) fatigue of low-alloy steel used in piping, steam generators, and reactor pressure vessels, (b) EAC of wrought and cast austenitic stainless steels (SSs), and (c) radiation-induced segregation and irradiation-assisted stress corrosion cracking (IASCC) of Type 304 SS after accumulation of relatively high fluence. Fatigue tests have been conducted on A302-Gr B low-alloy steel to verify whether the current predictions of modest decreases of fatigue life in simulated pressurized water reactor water are valid for high-sulfur heats ...
A new eddy current array probe has been implemented as a straightforward and promising technique for detection of outer diameter (OD) surface-breaking cracks on the extrados of feeder bends. The design is based on previous work performed at AECL, which had demonstrated that eddy current probes with laterally displaced transmit-receive coils can overcome some of the limitations of inspecting ferritic steel components for surface-breaking cracks. The Feeder Integrity Joint Program-CANDU Owners Group Inc. (FIJP-COG) Non-Destructive Evaluation (NDE) Team members commissioned AECL to work in collaboration with the probe manufacturer ZETEC, to develop a field usable eddy current array probe. The objective was to acquire a technique with the following capabilities: fast scanning non-contact inspection technique for surface breaking discontinuities; full inspection of the bend extrados OD surface in a single scan; ability to inspect first and second ...
A new eddy current array probe has been implemented as a straightforward and promising technique for detection of outer diameter (OD) surface-breaking cracks on the extrados of feeder bends. The design is based on previous work performed at AECL, which had demonstrated that eddy current probes with laterally displaced transmit-receive coils can overcome some of the limitations of inspecting ferritic steel components for surface-breaking cracks. The Feeder Integrity Joint Program-CANDU Owners Group Inc. (FIJP-COG) Non-Destructive Evaluation (NDE) Team members commissioned AECL to work in collaboration with the probe manufacturer ZETEC, to develop a field usable eddy current array probe. The objective was to acquire a technique with the following capabilities: fast scanning non-contact inspection technique for surface breaking discontinuities; full inspection of the bend extrados OD surface in a single scan; ability to inspect first and second ...
Experiments for lifetime prediction of the first wall are being carried out within the framework of the European fusion reactor programme. Defects such as notches and cavities may develop in the first wall and may initiate under cyclic thermal stress cracking processes which may reduce the service life of the material. For examination of crack growth, specimens with defined initial notches were prepared and subjected to cyclic thermal loads. The paper shows that the eddy current method is suitable for detecting and revealing the crack growth processes even under conditions of complex geometry, as e.g. cracks in inner bores. The experiments indicated particularly susceptible, critical spots in the first wall and yielded crack growth rates of use for lifetime calculations. (orig./CB) [Deutsch] Im Rahmen des europaeischen Fusionsreaktorprogramms werden Untersuchungen zur ...
Constant pull rate tests were conducted on tensile specimens of Inconel Alloy 600, Incoloy Alloy 800, and Type 304 stainless steel in deaerated 10% NaOH solution at 288 C (550 F) with a cover gas of 5% H_2 in N_2. The pull rate used for most experiments was 3.3 x 10"-"6 cm/s, which corresponds to an initial strain rate of 3 x 10"-"6 s"-"1. The electrical potential of the specimens was controlled by a potentiostat using a nickel wire as a hydrogen reference electrode. Under open circuit conditions, Type 304 stainless steel specimens cracked rapidly, but Alloys 600 and 800 specimens exhibited only ductile fracture. However, cracks readily formed in Alloy 800 specimens at potentials in the +50 to +300 mV range and in Alloy 600 specimens at potentials in the +150 to +250 mV range. Scanning electron microscope (SEM) photographs of some of the cracked specimen surfaces showed the transition from ductile to brittle fracture as a ...
BackgroundComplaints of arm, neck and/or shoulders (CANS) affects millions of computer office workers. However its prevalence and associated risk factors in developing countries...Full Text Available
One approach to improving the competitiveness of photovoltaic systems is the development of designs specifically for export applications. In other words, where is it appropriate in a system design to incorporate components manufactured and/or assembled in the receiving country in order to improve the photovoltaic exports from the US? What appears to be needed is a systematic method of evaluating the potential for export from the US of PV systems for various application in different countries. Development of such a method was the goal of this project.
... The structure comprises piled foundations supporting a steel frame, and is clad in both masonry and rainscreen cladding systems. The hotel is adjacent to the recently redeveloped bus station in the centre of Norwich. Related Services Structural Design Go View all Services Find Projects Sector All Sectors Buildings & Infrastructure Environment Natural Resources Transportation Sub Sector All Sub-Sectors Country All Countries Angola Antigua and Barbuda Argentina ...
... Further complications resulted from the requirement to use existing piled foundations and columns which had originally been designed to accommodate a six-storey office block. The hotel bedroom configurations and planning constraints were different from thos Related Services Structural Design Go View all Services Find Projects Sector All Sectors Buildings & Infrastructure Environment Natural Resources Transportation Sub Sector All Sub-Sectors Country All Countries Angola Antigua and Barbuda Argentina Australia Azerbaijan ...
Government facilities and services are often the largest energy users and major purchasers of energy-using equipment within a country. In developing as well as industrial countries, government ''leadership by example'' can be a powerful force to shift the market toward energy efficiency, complementing other elements of a national energy efficiency strategy. Benefits from more efficient energy management in government facilities and operations include lower government energy bills, reduced greenhouse gas emissions, less demand on electric utility systems, and in many cases reduced dependence on imported oil. Even more significantly, the government sector's buying power and example to others can generate broader demand for energy-efficient products and services, creating entry markets for domestic suppliers and stimulating competition in providing high-efficiency products and services. Despite these ...
... (restricted)] 98-118 Oil prices and competitiveness: time series evidence from six oil-producing countries by Mohammad R. Jahan-Parvar & Hassan Mohammadi [Downloadable! (restricted)] 2008, Volume 35, Issue 6 444-485 The S-shaped labor supply schedule: evidence from industrialized countries by Maryke ...
... Operational aspects of fiscal policy making in oil-producing countries , in J. Davis, R. Ossowski and A. Fedelino (...), Fiscal Policy Formulation and Implementation in Oil-Producing Countries , International Monetary Fund, Washington, D.C. Barro, R. (...
One of the challenges facing Clean Development Mechanism (CDM) projects today is their limited ability to secure financing for the underlying greenhouse gas emission reduction activities, particularly in the least developed countries. Among the key reasons for this is the fact that most financial intermediaries in the CDM host countries have limited or no knowledge of the CDM Modalities and Procedures. Moreover, approaches, tools and skills for CDM project appraisal are lacking or are asymmetrical to the skills in comparable institutions in developed countries. Consequently, developing country financial institutions are unable to properly evaluate the risks and rewards associated with investing or lending to developers undertaking CDM projects, and therefore have, by-and-large, refrained from financing these projects. In addition, some potential project proponents lack experience in structuring ...
Solar cookers offer a viable alternative to conventional cooking methods in many areas, and can be an effective tool in the fight against the deforestation and desertification that plague many developing countries. However, there have been numerous obstacles to the successful dissemination of solar cookers in the past. The purpose of this paper is to identify opportunities, review constraints and develop a marketing strategy to disseminate the Sundyne Solar Cooker (SSC) in developing countries.
The present report is final report from a study on characterisation of radioactive waters in the Nordic countries. The study has mainly been focused on long-lived low and intermediate level radioactive waste. Methods to measure or estimate the activity content and the general composition are discussed. Recommendations are given regarding characterisation of waste under treatment and characterisation of already produced waste packages. (au).
In order to conserve vaccines in hot countries a solar refrigerator has been made by a French university. It is a photothermal refrigerator without batteries. It uses two gases: ammonia and calcium chloride. The refrigerator is autonomous and can work eleven days without sun. (N.C.)
The European Commission recently has adopted a new European Strategy for Environment and Health focusing on the growing concern over the adverse health effects caused by environmental pollution. Based on the results of various studies carried out in recent years polychlorinated dioxins and furans (PCDD/Fs) and PCBs are playing an important role in this strategy. In view of the enlargement of the European Union (EU) to include Candidate Countries (CCs) the Commission stressed the need to involve the Candidate Countries from an early stage on in the development of such a strategy. Thus two studies have been commissioned which are particularly directed to provide a) an overview on environmental levels and human exposure of dioxins and PCBs and b) an harmonised PCDD/F emission inventory for the target matrices air, water and land The latter study, entitled ''Dioxin Emissions in Candidate ...
Renewable energy systems have been suggested as appropriate technologies for developing countries for many years. But they are less attractive to low-income rural and urban populations for reasons of risk and initial capital outlay, and market penetration is usually small as a result. Technology transfer by outside intervention appears unlikely to deliver to enough people in Africa; only self propagating technologies have managed that to date. Unfortunately target populations in developing countries have little capital and are understandably reluctant to take risks. Outside interests see little likelihood of profit and have already demonstrated reluctance to invest in many developing countries. Benefit from technology relies on continued use after purchase and is rightly associated with reliability and availability. Mean time to repair may be a better measure of appropriateness than mean time between failures. Technology ...
The severe health and environmental hazards posed by inadequate waste-collection systems in the rapidly growing cities of the Third World have stimulated interest in the waste-to-energy options developed in industrialized countries over the past 20 years. This economic study, the first of its kind, provides: (1) a comparative analysis of the characteristics of urban solid wastes in the United States, Europe, and developing countries; (2) basic information on the characteristics and operation of the two main types of waste-to-energy systems used in the developed world - landfill gas (LFG) systems and waste combustion systems; and (3) a preliminary assessment of the feasibility of using these systems in developing countries. The main conclusion is that present technology for the recovery and utilization of LFG appears to be suitable for developing country use, although the design of LFG projects would ...
Geothermal energy is one of the more promising renewable energy technologies because it is environmentally benign and, unlike most renewable energy sources, can provide base power. This report provides an assessment of the research and development (R&D) work underway in geothermal energy in the following countries: Denmark, France, Germany, Italy, Japan, Russia, and the United Kingdom. While the R&D work underway in the US exceeds the R&D efforts of the other countries, the lead is eroding. This erosion is due to reductions in federal government funding for geothermal energy R&D and the decline of the US petroleum industry. This erosion of R&D leadership is hindering commercialization of US geothermal energy products and services. In comparison, the study countries are promoting the commercialization of their geothermal energy products and services. As a result, some of these ...
The most relevant aspects of research and service experience with environmentally-assisted cracking (EAC) of carbon (C) and low-alloy steels (LAS) in high-temperature (HT) water are reviewed, with special emphasis on the primary pressure boundary components of boiling water reactors (BWRs). The main factors controlling the susceptibility to EAC under light water reactor (LWR) conditions are discussed with respect to crack initiation and crack growth. The adequacy and conservatism of the current BWRVIP-60 stress corrosion cracking (SCC) disposition lines (DLs), ASME III fatigue design curves, and ASME XI reference fatigue crack growth curves, as well as of the GE EAC crack growth model are evaluated in the context of recent research results. The operating experience is summarized and compared to the experimental/mechanistic background knowledge. Finally, open ...
The influence of high C martensite on the strength and impact behavior of C-Mn-Nb-Al steels has been determined for two distributions: films surrounding the ferrite grains and distinct colonies. In the former case, the impact behavior markedly deteriorated, this deterioration increasing with martensite level. The changes in impact behavior could be explained by regarding the films of martensite as being similar to the brittle grain boundary carbides that are present in ferrite-pearlite steels. These films readily crack, yet are always thick enough to produce a sufficient wide crack to render crack propagation easy. The critical event in fracture then becomes the ability to propagate the cracks through the grain boundaries. The greater the grain boundary coverage by these films, the easier this becomes and the worse is the impact behavior. When the martensite is present as colonies, again the impact ...
There are currently no accepted industry standards for the tensile strain limits of girth welds. This paper investigated the behavior of girth welds with buried defects subjected to high longitudinal strains caused by soil movement. A strain design methodology based on a crack driving method was used to examine the factors influencing stain limits along with a constraint-sensitive fracture mechanics approach. No strength undermatching was used in the welds, and the defect location had no influence on crack driving force. The weld joint was assumed to have uniform tensile properties. A 3D finite element (FE) model was used to simulate pipe behavior. Symmetric boundary conditions were imposed on the symmetry planes, and uniform remote axial displacement was applied as the primary loading. Automated data processing routines were developed to extract and analyze the data. The crack driving force was computed directly from a ...
This paper describes estimation of a stress field in the earth`s crust in the Kakkonda geothermal field. Formation micro imager (FMI) logging known as a crack detecting logging was performed in the well WD-1. This FMI logging has made observation possible on cracks along well axis thought to indicate size and direction of the crust stress, and drilling-induced tensile fractures (DTF). It was verified that these DTFs are generated initially in an azimuth determined by in-situ stress (an angle up to the DTF as measured counterclockwise with due north as a starting point, expressed in {theta}) in the well`s circumferential direction. It was also confirmed that a large number of cracks incline at a certain angle to the well axis (an angle made by the well axis and the DTF, expressed in {gamma}). The DTF is a crack initially generated on well walls as a result of such tensile stresses as mud pressure and ...
In association with periodic inspection of CANDU nuclear power plant components, Canadian Standards Association issued CSA N285.8 in 2005 as technical requirements for in-service evaluation of zirconium alloy pressure tubes in CANDU reactors. This first version, CSA N285.8 involves procedures for, firstly, the evaluation of pressure tube flaws, secondly, the evaluation of pressure tube to calandria tube contact and, thirdly, the assessment of a reactor core, and material properties and derived quantities. The evaluation of pressure tube flaws includes delayed hydride cracking evaluation the procedures of which are stipulated based on the existing delayed hydride cracking models. For example, the evaluation of flaw-tip hydride precipitation during reactor cooldown involves a procedure to calculate the equilibrium hydrogen equivalent concentration in solution at the flaw tip, Htipas follows: Htip=Hfexp[- (VH delta no.)/RT], where Hf is the total ...
Investigation of an HP-blade damage in 1996 and an MP-blade damage in 1007 at the mounting showed that fretting and creep fatigue had caused the damage. Break-down occurred when creep-related cracks developed between radial bridge to the upper blade tooth and weight relief boreholes. After disassembly of the HP-blades the lower blade tooth was found to be cracked after fretting (some cracks along the whole length of the tooth). The lower teeth of MP-bladedes showed merely superficial cracks (depth about 0.4mm). The massive cracks of the lower blade tooth were caused by instationary clearance changes combined with hard blade underground.(orig.) [German] Das Ergebnis der Untersuchung nach einem HD-Schaufelschaden 1996 sowie einem MD-Schaufelschaden 1997 an der Vierzackenfussbefestigung ergab Zeitstanderschoepfung und Fretting als auszuloesende Schadensmechanismen. Die Havarien wurden ...
Proposals for use of Alloy 800 as a H.T.R. boiler material have prompted studies of its creep and high temperature fatigue properties in impure helium with comparative tests in air. In impure helium, as expected in a H.T.R., reactions of potential importance are selective oxidation (of chromium, aluminium and titanium) and possibly carburisation from carbon monoxide or methane. In air, general oxidation will occur, possibly accompanied by nitridation. The effects of these reactions will depend on specimen geometry and the nature of the deformation. Two important possibilities are: (i) that environment affects the structure and properties of a surface zone of material undegoing uniform deformation (this may modify creep rate and crack nucleation); and (ii) that environment affects behaviour of a small region (e.g. at the root of a notch or ahead of a crack) in a specimen undergoing non-uniform deformation (this will modify ...
The fibre reinforcement of ceramic materials is used above all to improve the toughness and tolerance of damage, compared to unreinforced monolithic ceramics. This improvement is made possibly by the bridging effect of the cracks by the fibres in crack propagation in the matrix. In this work, the crack bridging effect of the fibres is included in a bridge stress equation, in which a clear relationship between bridge stress and crack opening is determined. The most important step for deriving the bridge stress law was determining the probability of failure of a fibre for a given axial stress curve. One relied on the micromechanical analysis of Hutchinson and Jensen here, by which the boundary conditions in multi-fibre materials can be included and realistic assumptions can be made for the load transfer mechanisms in the fibre/matrix boundary surface. (orig./MM) [Deutsch] Die Faserverstaerkung keramischer ...
Progress reports are presented for the following two areas: catalytic cracking studies with water-wet silica-alumina catalysts; and Fischer-Tropsch reactor studies where similarities and differences between fixed bed and slurry type reactors are investigated and further experiments conducted to measure mass transfer coefficients and reaction kinetics which are to be used in a model slurry reactor. The following are some of the conclusions. (1) The premise that the presence of liquid water might increase catalytic cracking activity was found to be invalid. It was demonstrated that cracking can occur at previously unobserved low temperatures (though at low conversions) and that an anomaly exists in that one of the catalysts tested shows an entirely different cracking behavior and probably follows a different cracking mechanism. (2) the diameter of a fixed-bed Fischer-Tropsch reactor ...
To study the biogeochemical behaviour, mobility and transport of trace metals in seawater (Se, Mo, Cd, Pb, Hg, Cu, Co, Fe, Ni, Zn), in suspended particulate matter (Mo, Cd, Pb, Cu, Co, Fe, Ni, Zn, Al, Mn) and in sediments of the inner and outer coastal regions, samples were collected on 3 separate cruises during a one year period (Mai 1993 - April 1994) at 20 stations in the coastal area of Mecklenburg-Vorpommern. Standard hydrographic parameters, nutrients and dissolved oxygen were also measured. Priority was taken to establish the methods for the determination of molybdenum and selenium. To study the behaviour of these two elements in detail, longterm measurements were carried out weekly between January 1993 and June 1994 at the `Messsteg/Warnemuende`. Because of parallel measurements correlations to biological, chemical and hydrographic parameters have been tested. The total database is summarized in the Appendix. The results are presented in 30 figures and 13 tables and are ...
Southeastern Finland belongs to the area covered by the Weichselian ice sheet, where the release of the ice load caused a rapid isostatic rebound during the postglacial time. While the mean overall apparent uplift is of the order of 2 mm/yr today, in the early Holocene time it was several times higher. A marked decrease in the rebound rate occurred around 8500 BP, however, since then the uplift rate has remained high until today, with a slightly decreasing trend towards the present time. According to current understanding there have neither been temporary increases nor decreases in the rate of uplift during the postglacial time. Even so, it is not known for sure whether there are regional irregularities on the rebound in Finland. Concurrently with land uplift, relative sea-level changes in the Baltic basin were also strongly affected by the global eustatic rise of sea-level. During the early Litorina Sea stage on the southern coast of Finland around 7000 BP, the ...
This paper tests the Environmental Kuznets Curve hypothesis for four local (SOx, NOx, CO, VOC) and two global (CO2, GHG) air pollutants. Using a new panel data set of thirty OECD countries, the paper finds that the postulated inverted U-shaped relationship between income and pollution does not hold for all gases. A meaningful Environmental Kuznets Curve exists only for CO, VOC and NOx, where for CO2 the curve is monotonically increasing. For GHG there is indication of an inverted U-shaped relationship between income and pollution, but still most countries are on the increasing path of the curve and hence the future development of the curve is uncertain. For SOx it was found that emissions follow an U-shaped curve. Based on the empirical results, the paper concludes that the Environmental Kuznets Curve does not hold for all gases, it is rather an empirical artefact than a regularity.
This paper tests the Environmental Kuznets Curve hypothesis for four local (SOx, NOx, CO, VOC) and two global (CO2, GHG) air pollutants. Using a new panel data set of thirty OECD countries, the paper finds that the postulated inverted U-shaped relationship between income and pollution does not hold for all gases. A meaningful Environmental Kuznets Curve exists only for CO, VOC and NOx, where for CO2 the curve is monotonically increasing. For GHG there is indication of an inverted U-shaped relationship between income and pollution, but still most countries are on the increasing path of the curve and hence the future development of the curve is uncertain. For SOx it was found that emissions follow an U-shaped curve. Based on the empirical results, the paper concludes that the Environmental Kuznets Curve does not hold for all gases, it is rather an empirical artefact than a regularity.
The environmental Kuznets curve hypothesis (EKC) predicts an inverse U-shaped relationship between environmental pollution and per capita income. The literature with respect to the EKC is vast but far from conclusive. This paper adds firm size to the standard EKC reduced form regression and analyses whether firm size matters once income and composition are controlled for. Results suggest that large firm countries are initially associated with higher levels of environmental damage. However, as economies develop, large firm countries find it easier to adopt more stringent environmental legislation. Once environmental damage starts to decrease, the decrease is much larger in large firm countries.
Many nations and international agencies are working to develop improved technology and industrial capability for neuclear fuel cycle and waste management operations. The effort in some countries is limited to research in university laboratories on treating low-level waste from reactor plant operations. In other countries, national nuclear research institutes are engaged in major programs in all phases of the fuel cycle and waste management, and there is a national effort to commercialize fuel cycle operations. Since late 1976, staff members of Pacific Northwest Laboratory have been working under US Department of Energy sponsorship to assemble and consolidate openly available information on foreign and international nuclear waste management programs and technology. This report summarizes the information collected on the status of fuel cycle and waste management programs in selected countries making major efforts in these ...
The steam generator is a very important component of a nuclear power plant. Historically, vertical steam generators came to be used abroad and horizontal steam generators in our country. Both types of steam generators operate successfully in nuclear power plants and satisfactorily fulfill their functions, enabling the production of electricity. Repeated attempts to re-examine the existing concepts in one or another country have been unsuccessful because there are no convincing arguments for this. Nonetheless, the question of using a different type of steam generator is raised periodically in our country and abroad. This article briefly reviews different concepts of steam generators. Their parameters, characteristics, and thermal efficiency are compared and ways to increase the latter are a...
Fission energy systems that significantly reduce the need for the user country to be involved in the nuclear operations and technology could simplify implementation and reduce the proliferation potential. Conceptual system designs with improved (relative to the once-through LWR fuel cycle) proliferation resistance for application in developing countries are being evaluated. The fission energy systems being studied include all activities and equipment necessary to produce energy, recycle selected materials, and dispose of the waste. The systems currently being studied are required to function with no refueling of the reactors on the user site. These requirements are being used to initiate the study, on the assumption that removal of these operations from within the developing countries will improve the proliferation resistance. Preliminary evaluations of a small fast reactor core cooled either by sodium or lead-bismuth are ...
The confluence of technology development and market readiness is opening up major business opportunities for photovoltaic (PV) systems throughout the developing world. The National Renewable Energy Laboratory (NREL) and Sandia National Laboratories in Abuquerque (Sandia), working on behalf of the U.S. Department of Energy, have launched pilot projects in several countries throughout the world over the past 3 years. The focus of these pilot projects has been the development of in-country institutional capabilities necessary to deliver the promise of PV electricity to the rural populations. In addition to country-specific activities, NREL is conducting several technology, information, and partnership projects focused on further accelerating the education, training, business, and technology developments necessary to bridge the gap between promise and reality. This paper summarizes these efforts.
The report presents an overview of A.I.D. efforts, which encompass a wide range of environmental issues and support environmental training, research, and institutional development. The report's opening section details A.I.D.'s efforts to enlist host-country support for environmental programs, with specific emphasis on improving natural resource management (especially in Africa), encouraging policy change, strengthening the private sector's environmental role, and preparing environmental profiles of host countries and helping them develop conservation strategies. The ensuing sections recount A.I.D. efforts in particular topics of environmental concern (biological diversity and environmental health and safety), critical ecological areas (coastal areas and forests and fragile lands), and specific country programs (reforestation in Haiti). A brief history of the evolution of the Agency's ...
Human breast milk samples collected in 2007?2008 from four countries, Vietnam (Hanoi), China (Beijing), Korea (Seoul) and Japan (Sendai, Kyoto and Takayama), were analyzed for persistent organic pollutants (POPs) such as dichlorodiphenyltrichloroethane and its metabolites (DDTs), chlordane-related compounds (CHLs), hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs). Comparing with previous surveys, the present study indicates that the DDTs in breast milk from China and Vietnam had gradually decreased during the last decade, but were still 5?10 times higher than those in other nations. The ratios of p,p?-DDE/p,p?-DDT and o,p?-DDT/p,p?-DDT were higher in Beijing than in the other countries, suggesting that there...
This article investigates the missing link in the literature - whether informal institutions, or what is known as culture, can affect the level of financial development for a country? Our hypothesis stresses that the cultural dimensions of a country can have an impact on its financial set-up. We consider multiple dimensions of culture, identified in the literature by Tabellini (2008), to test our hypothesis. As culture evolves in the form of greater trust, control and other traits, individuals' attitudes towards financial market change, and they engage in greater financial transactions. This, in turn, leads to better financial development. Using quantile estimation technique for a cross section of 90 countries, we find that culture significantly influences the level of financial developmen...
Abstract The World Bank is the largest international funder of biodiversity conservation. It invests in protected areas to conserve species and spaces, protect ecosystems, and provide food, shelter, and other ecosystem services to local communities. It spends on average, $275 million annually supporting parks in developing countries. We examined their protected areas investment portfolio from 1988 to 2008 to understand how they allocate these funds. We found that more money is allocated to countries with progressively larger GDPs. Many, but not all, of these investments correlate with consensus opinions of high biodiversity priorities. But the World Bank's investments are not proportional; poorer countries receive relatively more funds than richer ones, regardless of biodiversity importanc...
Abstract In response to growing consumer concerns, developed-country governments have reduced permissible pesticide residue levels in food. Many food retailers have developed even more stringent private food safety protocols relating to pesticide use, storage and disposal and passed them on to their suppliers. Exporters in developing countries enforce these developed-country pesticide standards (DC-PS) by subjecting farmers to close monitoring. This study explores the effects of enforcing compliance with DC-PS on smallholder farmers' pesticide-related health costs. Results suggest that enforcing DC-PS encourages farmers to use protection that lowers pesticide-induced morbidity, hence reducing farmers' health costs from pesticide exposure. The study concludes that there are health benefits ...
The Sultanate of Oman has a relatively young national health care system that could demonstrate its high performance at an international level. Emergency medicine as a specialty has developed rapidly in the country over the last decade. This has involved the parallel development of local emergency residency training, prehospital emergency care, and emergency nursing programs. This article reviews the progress of emergency care practice in this country from a general primary care system toward becoming an established specialty in hospital, prehospital, and private emergency care settings. It also describes aspects of undergraduate, postgraduate, and continuous emergency medicine education in the country. Further, a glimpse into academic emergency medicine and emergency nursing is provided. ...
The aim of this paper is to analyze the influence of the legal and institutional environment on bidder firm returns around the announcement date of cross-border Mergers and Acquisitions (M&As). The database includes 469 M&As of European (221 cross-border and 248 domestic) listed firms, with target firms being worldwide public or private firms (40 countries), over the 2002-2006 period. Shareholders of acquiring firms place greater value on cross-border M&A announcements than on domestic ones. The stronger (weaker) the legal and institutional environment of the acquirer firm country in comparison with that of the target firm country, the more positive (negative) the effect on acquiring-firm shareholders' valuation of M&As.
The presence of inefficient distribution networks and supply chains of medicines creates problems in that even if African countries can secure steep, sustainable cost-containing procurements, access to needed medicines may still be impaired. The expected health benefits from affordable pricing or subsidies on prices of medicines may not be realized. This article evaluates drug supply chains in African countries and advocates for consolidated private wholesale markets and multiplicity of retail pharmacies. Public supply chains should be shortened and supported by contracting out with private distributors, including wholesalers and retail pharmacies. Additionally, drug regulatory authorities should be allowed to charge registration fees that are proportionate to the costs of technical regula...
We investigate how corruption influences the income level at the turning point of the relationship between sulfur emissions and income, using a wide cross-national panel of countries, at different levels of development and with different degrees of corruption. Our results support the Environmental Kuznets Curve hypothesis for sulfur. We find evidence that the higher the country's degree of corruption, the higher the per capita income at the turning point, suggesting different income-pollution paths across countries due to corruption. We build upon a new specification for the EKC developed by Bradford et al. (2005) that avoids using nonlinear transformations of potentially nonstationary regressors in panel estimation. Also, we account for the indirect impact of corruption on emissions throu...
With the rapid growth of Information and Communication Technology, Electronic commerce is now acting as a new means of carrying out business transactions through electronic means such as Internet environment. To avoid the complexities associated with the digital cash and electronic cash, consumers and vendors are looking for credit card payments on the Internet as one possible time-tested alternative. This gave rise of the on-line payment processing using a third-party verification; which is not suitable for the developing countries in most of the cases because of the excessive costs associated with it for maintenance and establishment of an online third-party processor. As a remedy of this problem, in this paper, we have proposed a framework for easy security incorporation in credit card based electronic payment system without the use of an on-line third- party processor; which tends to be low cost and effective for the developing countries.
The fundamental differences in the type of products sold in both Japan and the US, and some of the reasons for these differences, are outlined. Japan is the largest single country market for residential heat pumps, while the US represents the largest single country market for residential heating equipment. Quite different types and associated features of heat pumps are demanded in the USA and Japan. The term `convenience features`, used to describe the physical characteristics of the user interface device, is explained, as well as the fundamental reasons leading to the particular styles of product sold in each country: (1) product strategy and sales channels, (2) design of housing, (3) climatic factors, and (4) energy costs and distribution. It is stressed that there is no big cooling load in Japan. It is rather the comfort issue that drives the market for heat pumps
The interpretation of data from the nuclear forensic analysis of illicit nuclear material of unknown origin requires comparative data from samples of known origin. One way to provide such comparative data is to create a system of national nuclear forensics libraries, in which each participating country stores information about nuclear or other radioactive material that either resides in or was manufactured by that country. Such national libraries could provide an authoritative record of the material located in or produced by a particular country, and thus forms an essential prerequisite for a government to investigate illicit uses of nuclear or other radioactive material within its borders. We describe the concept of the national nuclear forensic library, recommendations for content and structure, and suggested querying methods for utilizing the information for addressing nuclear smuggling.
A CANDU nuclear reactor was shut down for over one year because steam generator (SG) tubes had failed with outer diameter stress-corrosion cracking (ODSCC) in the U-bend section. Novel, single-pass eddy current transmit-receive probes, denoted as C3, were successful in detecting all significant cracks so that the cracked tubes could be plugged and the unit restarted. Significant numbers of tubes with SCC were removed from a SG in order to validate the results of the new probe. Results from metallurgical examinations were used to obtain probability-of-detection (POD) and sizing accuracy plots to quantify the performance of this new inspection technique. Though effective, the above approach of relying on tubes removed from a reactor is expensive, in terms of both economic and radiation-exposure costs. This led to a search for more affordable methods to validate inspection techniques and procedures. Methods are presented for ...
A CANDU nuclear reactor was shut down for over one year because steam generator (SG) tubes had failed with outer diameter stress-corrosion cracking (ODSCC) in the U-bend section. Novel, single-pass eddy current transmit-receive probes, denoted as C3, were successful in detecting all significant cracks so that the cracked tubes could be plugged and the unit restarted. Significant numbers of tubes with SCC were removed from a SG in order to validate the results of the new probe. Results from metallurgical examinations were used to obtain probability-of-detection (POD) and sizing accuracy plots to quantify the performance of this new inspection technique. Though effective, the above approach of relying on tubes removed from a reactor is expensive, in terms of both economic and radiation-exposure costs. This led to a search for more affordable methods to validate inspection techniques and procedures. Methods are presented for ...
This paper reviews the technical literature published on the welding of alloy 800. Much of this work has been carried out using the Varestraint and Gleeble tests to investigate the susceptibility of the alloy and of high nickel consumables to hot-cracking. Inspite of much reported work, it is pointed out that many years of experience in the use of alloy 800 shows it to be readily weldable without any major problems occurring due to hot-cracking. The elements investigated include titanium, aluminium, sulphur, phosphorus and carbon, and the effects of these elements are discuused in terms of their effects on the hot-ductility curves obtained by Gleeble testing. Conclusions reached by various researchers state that the individual effects of the above five elements may be masked by other unknown factors. It is concluded that with correct welding procedures alloy 800 can be welded without cracking problems even with high heat ...
In situ fracture studies on thin-film NiTi intermetallic compounds have been carried out in the high-voltage electron microscope at Argonne National Laboratory. Local stress-induced amorphization of regions directly in front of moving crack tips has been observed under tensile loading conditions. The stress-induced amorphization at crack tips exhibits a temperature dependence similar to that of ion-induced amorphization of NiTi. The upper limiting temperature for stress-induced amorphization is the same as that for ion-induced amorphization of crystalline NiTi and for amorphous phase formation during ion-beam mixing of Ni and Ti multilayer specimens. This upper limiting temperature of 600K is also the lowest temperature at which stress-induced amorphous phase crystallizes during isothermal annealing. This isothermal crystallization temperature is nearly 200K less than the kinetic crystallization temperature during heating of unrelaxed NiTi ...
Samples from a burning bituminous coal seam from Coalspur, Alberta, were studied by reflected light microscopy. Two zones - namely oxidation- combustion and distillation - were detected in the seam. Near the surface, the oxidation zone contained chars showing cracks and oxidation rims. The cracks were filled with fluorescing hydrocarbon material formed by thermal cracking of coal macerals. The chars in the deeper part of the oxidation zone had a carbonized matrix and burnt rims. The distillation zone covered most of the coal seam. Chars were mostly in the precarbonization stage, except those immediately below the combustion zone or near the base of the seam. Precarbonized chars contained pyrolytic carbon in some horizons. The distilled chars were formed by heat generated by combustion at the top of the seam and also by heat transfer from an underlying burning seam through an intermediate clastic layer. The minimum ...
Catalytic reactions of 3-methylpentane and 2,3-dimethylbutane on HY, amorphous silica-alumina, and HZSM-5 have been studied at 500{degree}C. Both kinetic phenomena and product selectivities have been reported. Cracking reactions an HZSM-5 can be attributed to initiation through protonation occurring at Bronsted sites. Bimolecular processes leading to chain reaction via hydride transfer are restricted within the narrow pore pentasil zeolite. On HY and amorphous silica-alumina, initiation of cracking also occurs at Bronsted sited. No direct evidence was found for participation of Lewis acid sites on the catalyst framework itself. Following initiation, reactions on these catalysts are accelerated through a chain process occurring at Lewis sites generated by adsorption of product olefins at Bronsted sites. The resulting change in the dominant cracking mechanism is reflected in the product selectivity, illustrated here by a ...
A model has been developed in the recent past to predict fatigue crack growth (FCG) behaviour in the Paris-regime of various steels by employing low cycle fatigue (LCF) properties. The model forms its basis on the assumption that the cyclic damage process immediately ahead of a crack-tip, restricted in a small zone termed as process zone, is identical to those experienced in the LCF loading of a smooth specimen. Within the process zone, fatigue damage has been assumed in terms of product of stress and plastic strain which is analogous to the plastic strain energy density of the smooth specimen under fatigue loading. In this paper the model developed by Kujawski and Ellyin has been used to predict the FCG behaviour of an #alpha#-#beta# titanium alloy in the Paris-regime by employing the experimentally obtained LCF properties. The FCG behaviour thus theoretically predicted was compared with the experimentally determined FCG behaviour.
The corrosion behaviour of friction stir welded (FSW) joints of AA 5083 has been compared to that of MIG welded joints. Pitting and stress corrosion cracking (SCC) resistance in 3.5% NaCl + 0.3 g/l H{sub 2}O{sub 2} and in EXCO (4 M KCl + 0.5 M KNO{sub 3} + 0.1 M HNO{sub 3}) solutions has been determined at 25 C. SCC susceptibility was evaluated by slow strain rate tests (SSRT), at a strain rate of 1 x 10{sup -6}s{sup -1}. Welds obtained by FSW technique showed a higher corrosion resistance in EXCO solution and a lower pitting tendency than the base alloy. Electrochemical measurements (corrosion potential measurements, polarization curves recording) evidenced that FSW weld was cathodic to base alloy. FSW joints were not susceptible to SCC in both test solutions, whereas MIG joints cracked in both solutions. (orig.)
Slurry aluminizing is one method of protecting titanium alloys and intermetallics at temperatures at which oxidation would otherwise significantly degrade mechanical properties. The technique produces a continuous layer of alumina-forming TiAl_3 on exposed surfaces. The influence of composition, film thickness, and diffusion temperature upon the oxidation resistance of these slurry aluminides was studied in cyclic tests to 816degC (1500deg F). Degradation of slurry aluminized #beta#-titanium alloy and #alpha#-Z titanium aluminide intermetallic occurs by localized oxidation at cracks in the coating layer. These cracks are probably due to mismatch of coefficients of thermal expansion between the coatings and substrates. Addition of silicon to the slurry modifies the oxidation behaviour around a crack by introducing a continuous layer of titanium silicide at the boundary of the aluminide coating and substrate, thereby ...
The inspection of PFR evaporator tubing, superheater and reheater tubing, and tube plate examinations, are described. Ferritic steel U tubes in the evaporator have been examined by an eddy current system operating at 400 kHz using flexible rotating probes. Surface defects as shallow as 0.1 mm can be detected and sized in the range 0.1 to 0.5 mm deep. An ultrasonic method is under development for wall thickness. Special test coil probes have been developed for examination of the type 316 stainless steel superheater and reheater tubing. Crack-life defects in the bore are detectable at approximately 10% wall thickness and 20% on the outside diameter. Tube plate examinations from the tube holes, have been conducted using eddy current probes which identify surface breaking cracks in the holes. For detecting curtain cracks between tube plate holes, ultrasonic compression wave probes have been used. (U.K.).
The influence of some processing factors such as cold work and heat treatment on the susceptibility to caustic stress corrosion cracking (SCC) of modified alloy 800, referred to alloy 800 M, in a boiling solution of 50%NaOH + 0.3%SiO_2+0.3%Na_2S_2O_3 was investigated by means of microstructure examination, tensile test, stress analysis, SCC test of C-rings, Auger electron spectroscopy (AES) and corrosion mode. Cold work led to lengthening of grains, decrease in ductility, increase in strength, residential stress and susceptibility to SCC. With increasing temperature of heat treatment on alloy 800 M after cold work, grains became bigger, ductility increased but strength, residential stress and susceptibility to SCC decreased. SCC cracks on C-ring specimens initiated from pitting and propagated along grain boundaries. AES analysis indicates that the surface films on alloy 800M are enriched in nickel and depleted in iron and chromium. (authors)
Ten different alloys of zirconium have been tested with regard to the effect of irradiation on their mechanical properties and their sensitivity to environmentally induced failure. Two different environments were used: iodine vapour and liquid cesium with an addition of 2% cadmium. The neutron dose was 10"2"1n/cm"2 (E>1MeV) and the irradiation temperature was about 300 degrees C. All alloy additions increased the irradiation hardening. Especially notable was the large effect of titanium and tin on irradiation hardening. A limited amount of transmission electron microscopy was carried out in order to find an explanation to the effects. The testing in different environments showed that there is no clear correlation between environmental sensitivity and yield stress. For materials of similar yield stress an alloyed material tends to be more sensitive to environmental cracking than a material which only contains oxygen as an impurity. There also seems to be an ...
The methodology of the drip procedure of the Standard Test Method for Evaluating the Influence of Thermal Insulation on External Stress Corrosion Cracking Tendency of Austenitic Stainless Steel (ASTM C 692-95a) was used to research the effect of halogens and inhibitors on the external stress corrosion cracking (ESCC) of Type 304 stainless steel as it applies to the insulation industry. Simulated insulation extraction solutions were made with pure chemical reagents for the halogens and inhibitors. The results indicated that sodium silicate compounds that were higher in sodium were more effective for preventing chloride-induced ESCC in Type 304 austenitic stainless steel. Potassium silicate was not as effective as sodium silicate. Fluoride, bromide, and iodide may cause ESCC but they were much less active than chloride and could be effectively inhibited by sodium silicate compound. The addition of fluoride ions to the chloride/sodium silicate ...
Modelization of crack propagation and theoretical prediction of rupture are the two main objectives of researchers in stress corrosion cracking. Nevertheless, to reach this aim, the behavior of the passive film which appears spontaneously on the substrate in contact with an environment has to be known. This structural and mechanical characterization is all the more difficult because the number of parameters is important: crystallinity rate, defects concentration, thickness (about a few nanometers), electric field, chemical composition (a lot of oxides are present), peeling layers (atomic structure for example) and some hypothesis can be made about their multi-layer structure, their chemical composition or their epitaxial character... Passive films formed on 316L or 304L stainless steels in different aqueous solutions (in ambient air, in MgCl{sub 2} at 117 deg. C...) have been studied and some important remarks about their mechanical properties ...
Modelization of crack propagation and theoretical prediction of rupture are the two main objectives of researchers in stress corrosion cracking. Nevertheless, to reach this aim, the behavior of the passive film which appears spontaneously on the substrate in contact with an environment has to be known. This structural and mechanical characterization is all the more difficult because the number of parameters is important: crystallinity rate, defects concentration, thickness (about a few nanometers), electric field, chemical composition (a lot of oxides are present), peeling layers (atomic structure for example) and some hypothesis can be made about their multi-layer structure, their chemical composition or their epitaxial character... Passive films formed on 316L or 304L stainless steels in different aqueous solutions (in ambient air, in MgCl_2 at 117 deg. C...) have been studied and some important remarks about their mechanical properties are ...
A personal computer based single specimen unloading technique has been demonstrated using a nuclear grade pressure vessel material, A533B Class I steel, and an #alpha#-#beta# titanium alloy, CORONA-5. Experimental parameters investigated in the case of steel include the effect of test temperature, loading rate and neutron irradiation. Results revealed the effect of dynamic strain aging (DSA) as a drop in the critical crack initiation fracture toughness (Jsub(q)); the minimum in Jsub(q) shifts to higher temperatures at higher test speeds as predicted from DSA models. In CORONA-5, the effects of microstructure and heat treatment for two different sizes of equiaxed #alpha# morphology in a #beta#-matrix heat treated to different yield strengths were investigated. It is found that the observed higher values of Jsub(q) and tearing modulus result from a greater tortuosity of the crack path and ease of crack blunting. The largest ...
A singular stress field can occur at the edge of the joint plane in a thermally or mechanically loaded material compound. This stress field was calculated analytically and was compared with the results from the finite element method. If one of the two partners consists of ceramic material, unstable crack spread starting from faults in this strongly stressed area can lead to failure. In linear elastic material, the behaviour of a crack is clearly described by the stress intensity factors. These can be calculated for a known stress distribution in the uncracked structure by the method of the weight function. The corresponding weight functions for surface cracks parallel to the boundary surface were determined with the aid of suitable reference load cases. The effect of the position of the crack in the compound and the elastic constants of the compound are discussed. For examples, the stress intensity ...
The aim of the presented investigation was to gain information about the behaviour of the initiation and growth of intercrystalline creep cracks during creep deformation from the evaluation of metallographic micrographs. The austenitic steel X10 NiCrAlTi 32 20 HT (Alloy 800 HT) was investigated by carrying out creep tests at 800 and 900 C with different nominal stresses until fracture. Additional tests are carried out on certain creep strains in the late tertiary creep stage. The creep tests are followed by a metallographic investigation of the crept specimens. The statistical distribution of the microcrack lengths was used to estimate the rate of crack initiation and crack growth. It is found that the rate of growth of the intercrystalline creep cracks in Alloy 800 HT is dependent on the applied stress and the creep strain reached. The rate of growth of long cracks was only ...
...qualified and who were under consideration at the time, USDA Secretary Tom Vilsack chose an animal husbandry specialist employed by one of the largest organic livestock product marketers in the country. While this appointee had grown up on a conventional farm, her immediate occupation is not that of ...
Old world cutaneous leishmaniasis (CL) is caused by Leishmania major and Leishmania tropica, and is endemic to several Asian and Middle-Eastern countries where the...Full Text Available
The objective of this study was to analyze the industrial demand for energy in seven Organization for Economic Cooperation and Development (OECD) countries with particular emphasis on fuel substitution between oil, natural gas, coal, and electricity. Changing fuel demand also results from economic growth, changes in industrial structure, and changes in the energy intensity of industrial output. A historical analysis of these factors and fuel substitution is undertaken for industry as an aggregate, and for 12 specific industries. The major results of the historical analysis are: (1) fuel use changes are a result of fuel switching, changing energy intensity, changing industrial structure, and economic growth; (2) fuel substitutability depends upon fuel use. The three fossil fuels are substitutes in the industrial heat market, but there are numerous special industrial processes where a particular fuel is required; (3) large substitutions have occurred between fuels; ...
BACKGROUND AND OBJECTIVE:Streptococcus pneumoniae is a major cause of mortality and morbidity in both developing and industrialized countries, especially...Full Text Available
BackgroundPublic information about prevention of zoonoses should be based on the perceived problem by the public and should be adapted to regional circumstances. Growing fox populations...Full Text Available
Most Danish windmill manufacturers have experienced a grave economic crisis during the last three years. In 1987, the total windmill industry in this country ran at a loss of 40 million Danish crowns where the turnover was 550 million crowns. Danish firms...
Twelve Salmonella typhimurium strains resistant to broad-spectrum cephalosporins were isolated from cases of gastroenteritis during 1996 to 1998 in Russia, Hungary, and Greece. Resistance...Full Text Available
BackgroundCholera has claimed many lives throughout history and it continues to be a global threat, especially in countries in Africa. The disease is listed as one of three internationally...Full Text Available
BackgroundIn many of the European countries affected by Bovine Spongiform Encephalopathy (BSE), case clustering patterns have been observed. Most of these patterns have been interpreted...Full Text Available
BackgroundThere is a lack of studies considering social disparity in oral health emanating from adolescents in low-income countries. This study aimed to assess socio-demographic...Full Text Available
Biomass fuel burning leads to high levels of suspended particulate matter and hazardous chemicals in the indoor environment in countries where it is in common use, contributing significantly to indoor...Full Text Available
Sexually transmitted diseases (STDs) represent a major public health problem in the country, cause patients enormous suffering, and cost the nation billions of dollars annually. Demographic, sociological,...Full Text Available
Zaprionus indianus was first recorded in Brazil in 1999 and rapidly spread throughout the country. We have obtained data on esterase loci polymorphisms (Est2 and Est3), and analyzed...Full Text Available
Although major inroads into making antiretroviral therapy available in resource-poor countries have been made, there is an urgent need for an effective vaccine administered shortly after birth, which...Full Text Available
Objectives To provide direct estimates of risk of cancer after protracted low doses of ionising radiation and to strengthen the scientific basis of radiation protection standards for environmental,...Full Text Available
IntroductionResearch is an essential tool in facing the challenges of scaling up interventions and improving access to services. As in many other countries, the translation of research...Full Text Available
The energy strategy of the UK Overseas Development Administration is outlined with specific emphasis on energy efficiency and renewable energies. Based on 29 case studies concerning projects and programmes in both developed and developing countries, critical success factors for renewable energy projects are identified. UK)
Multidrug-resistant tuberculosis is an increasing public health concern in many parts of the world, especially in low-income countries, where most cases occur. Traditional drug susceptibility testing...Full Text Available
We have evaluated the performance of two rapid, low-cost methods for the detection of ofloxacin (OFX) resistance with 95 Mycobacterium tuberculosis isolates from countries with high...Full Text Available
Skiing—either downhill or cross-country—is one of the most popular winter sports. Because the skiing season is short, a pre-ski conditioning program is particularly important to enhance...Full Text Available
OBJECTIVE: To determine the common types of injuries among children (0-14 years) in Al-Ain, United Arab Emirates (UAE). DESIGN: A retrospective descriptive hospital based study. SETTING: Al-Ain Medical...Full Text Available
BackgroundLittle is known about the role European patient organisations play in the process of deciding on reimbursement for medicines. Therefore we explore the...Full Text Available
The evolution of drug resistant bacteria is a severe public health problem, both in hospitals and in the community. Currently, some countries aim at concentrating highly specialized services in large...Full Text Available
... Austrian Environment Minister Nikolaus Berlakovich called for such stress tests on Sunday (13 March) to make sure that nuclear power stations were quake-proof following Japan's massive earthquake and tsunami. Austria, a mountainous country rich in geothermal energy, has no NPPs and no plans to develop ...
Profile of aid statistics to Pakistan. Shows the amount of aid received, the major donors and the form in which the majority of the aid is given. Especially useful when compared to the aid profile of similar countries. Shows that ODA accounts for about 1.5% of Pakistani GDP and that it is distributed over various sectors.
This report describes how Nigeria, a country that at one time had the highest number of cases of dracunculiasis (Guinea worm disease) in the world, reduced the number of cases from more than 653,000...Full Text Available
BackgroundArtemisinin-based combination therapy, currently considered the therapy of choice for uncomplicated Plasmodium falciparum malaria in endemic countries,...Full Text Available
Background and ObjectiveCervical cancer is one of the leading causes of morbidity and mortality amongst the gynecological cancers worldwide, especially in developing countries. It...Full Text Available
Intensity modulated radiotherapy (IMRT) is widely used in clinical applications in developed countries, for the treatment of malignant and non-malignant diseases. This technique uses multiple radiation...Full Text Available
Background The scale-up of treatment for HIV and multidrug-resistant tuberculosis (MDR-TB) in developing countries requires a long-term relationship with the...Full Text Available
The extent of our reliance on animal pollination for world crop production for human food has not previously been evaluated and the previous estimates for countries or continents have seldom used primary...Full Text Available
Using a sample of 88 less developed countries, hypotheses were tested over time in panel regression models to determine what type of impact military and arms expenditures have on national economic growth and development. Hypotheses were drawn from three theoretical perspectives. The first set of tested hypotheses came from the modernization literature, which assumes that expenditures have positive ripple effects in national economies that are good for growth and development. The second set is based on the economic dependency and world systems theories. These theories assume that the relationships between countries affect a nation's economic structure and that arms expenditures are a mechanism used by core industrialized nations to increase economic penetration and dependency of periphery unindustrialized countries. Finally, the third set of hypotheses is grounded in literature on the role of the state in ...
... (restricted)] 24-53 Cyclicality of Fiscal Policy in Oil-Producing Countries by E. Gurvich & E. Vakulenko & P. Krivenko [Downloadable! (restricted)] 54-75 Russian Energy Efficiency Potential by I. Bashmakov [Downloadable! (restricted)] 76-94 Outlook and ...
Main results of the 40-year experience gained from operation of horizontal steam generators in VVER-type reactor installations used in Russia and many foreign countries are described. Existing unresolved problems are pointed out.
efforts to work with other countries to solve shared problems. U.S. Condemns Alleged WikiLeaks Disclosures November 29, 2010: President Obama and Secretary of State Hillary Rodham...
BackgroundHepatitis B virus (HBV) infection is a serious health problem in the developing countries including Pakistan. Various risk factors are responsible for the spread of this...Full Text Available
BackgroundThe burden of non-communicable diseases, including type 2 diabetes, is growing in South Africa. This country has a complex mix of over- and under-nutrition, especially...Full Text Available
In most countries, residential electricity consumption typically ranges from 20% to 40% of total electricity consumption. This energy is used for heating, cooling, refrigeration and other end-uses. Significant energy savings are possible if new appliance purchases are for models with higher efficiency than that of existing models. There are several ways to ensure or encourage such an outcome, for example, appliance rebates, innovative procurement, and minimum efficiency standards. This paper focuses on the latter approach. At the present time, the US is the only country with comprehensive appliance energy efficiency standards. However, many other countries, such as Australia, Canada, the European Community (EC), Japan and Korea, are considering enacting standards. The greatest potential impact of minimum efficiency standards for appliances is in the developing countries (e.g., China and India), where ...
Emissions of sulphur and nitrogen oxides are continuing to fall in Europe but rise in Asia, according to calculations based on individual countries' predictions of economic development. The upward trend is slower than in previous predictions. 2 refs., 2 figs., 2 tabs.
Oil and gas companies operate in many countries around the world. Their exploration and production (E&P) operations generate many kinds of waste that must be carefully and appropriately managed. Some of these wastes are inherently part of the E&P process; examples are drilling wastes and produced water. Other wastes are generic industrial wastes that are not unique to E&P activities, such as painting wastes and scrap metal. Still other wastes are associated with the presence of workers at the site; these include trash, food waste, and laundry wash water. In some host countries, mature environmental regulatory programs are in place that provide for various waste management options on the basis of the characteristics of the wastes and the environmental settings of the sites. In other countries, the waste management requirements and authorized options are stringent, even though the infrastructure to ...
Enteropathogenic Escherichia coli (EPEC) is a common cause of watery diarrhea in children in developing countries. After adhering intimately to small intestinal cells, EPEC...Full Text Available
BackgroundInvasive Staphylococcus aureus infection is increasingly recognised as an important cause of serious sepsis across the developing world, with mortality...Full Text Available
BackgroundNon-small cell lung cancer (NSCLC) is the foremost cause of cancer-related death in Western countries, which is due partly to the propensity of NSCLC cells to metastasize....Full Text Available
The authors studied noncancer mortality among phenoxyacid herbicide and chlorophenol production workers and sprayers included in an international study comprising 36 cohorts from 12 countries followed...Full Text Available
The Global Road Safety Partnership (GRSP) is a global partnership of business, civil society and government working for sustained reduction of road accidents in developing and transition countries. GRSP, which started operations in 1999, has a global secr...
In recent years, Salmonella enteritidis has become an increasingly important public health problem in Italy. In some parts of the country, the fraction of total human salmonella isolates...Full Text Available
1 The long term safety and efficacy of vigabatrin has been studied in 254 patients with refractory epilepsy (82% with partial seizures) in 23 different clinics in eight European countries....Full Text Available
BackgroundStudies from various countries have observed worse population health in geographical areas with more income inequality. The psychosocial interpretation of this association...Full Text Available
A rapid expansion of urban systems, particularly in less-developed countries, pose considerable challenges. Urbanization also provides opportunities for socio-economic progress. Relative contribution...Full Text Available
Background"Doing the month", or "sitting month", is a traditional practice for postpartum women in China and other Asian countries, which includes some taboos against well-accepted...Full Text Available
BackgroundStudies conducted in developed countries using economic models show that individual- and household- level variables are important determinants of health insurance ownership....Full Text Available
BackgroundTrypanosomosis is a major impediment to livestock farming in sub-Saharan Africa and limits the full potential of agricultural development in the 36 countries where it is...Full Text Available
There has been a major interest in the drug treatment of osteoporosis and an increase in the number of drugs available in most countries. The ideal drug (one which increases or restores bone density...Full Text Available
Reactions of consumers to the appearance and taste of pork with and without information concerning outdoor production of pigs were tested in France, Denmark, Sweden and UK. Consumers in all four countries focussed on colour and fatness rather than marbling and drip to make their choice. Almost half of the British and Danish preferred the paler and the French the darker pork. Most people preferred the leaner pork. When information was provided in the form of labels, the vast majority of consumers preferred the pork labelled as originating from their own country as opposed to 'imported' and that labelled as pork from pigs 'raised outside' as opposed to 'inside'. There was no difference in the taste of grilled pork from indoor and outdoor production systems but pork labelled 'home produced' or 'outdoor' were more appreciated. Consumers' willingness to pay varied widely and was higher for those consumers who found more of the characteristics they ...
Enterotoxigenic Escherichia coli (ETEC) is a leading cause of diarrhea in travelers to countries where the disease is endemic and causes a major disease burden in the indigenous population,...Full Text Available
Although the use of amphibole asbestos (crocidolite and amosite) has been banned in most European countries because of its known effects on the lung and pleura, chrysotile asbestos remains in use in...Full Text Available
Endometrial carcinoma is the most commonly diagnosed gynaecological cancer in developed countries. Although the molecular genetics of this disease has been in the focus of many research laboratories...Full Text Available
Colorectal cancer (CRC) is the third-ranked neoplasm in order of incidence and mortality, worldwide, and the second cause of cancer death in industrialized countries. One of the most important environmental...Full Text Available
Hookworms, bloodfeeding intestinal nematodes, infect nearly one billion people in resource limited countries and are a leading cause of anemia and malnutrition. Like other nematodes, hookworms...Full Text Available
BackgroundThe occurrence of diabetes has greatly increased in low- and middle-income countries, particularly in Asia, as has the prevalence of overweight and obesity; in European-derived...Full Text Available
Global meat and milk consumption is exponentially increasing due to population growth, urbanization and changes in lifestyle in the developing world. This is an excellent opportunity for developing countries to improve the livestock sector by using technological advances. Biotechnology is one of the avenues for improved production in the "Livestock revolution". Biotechnology developments applied to livestock health, nutrition, breeding and reproduction are improving with a reasonable pace in developing countries. Simple bio-techniques such as artificial insemination have been well implemented in many parts of the developing world. However, advanced technologies including transgenic plant vaccines, marker assisted selection, solid state fermentation for the production of fibrolytic enzymes, transgenic fodders, embryo transfer and animal cloning are confined largely to research organizations. Some developing countries such as ...
Inadequate measures of water quality have been used in many studies of the health effects associated with water supplies in developing countries. The present 1-year epidemiological-microbiological study...Full Text Available
Simplification of cell enumeration technologies is necessary, especially for resource-poor countries, where reliable and affordable enumeration systems are greatly needed. In this paper, an immunomagnetic...Full Text Available
The relationships between basic and applied agricultural R&D, developed and developing country R&D and between R&D, extension, technology and productivity growth are outlined....Full Text Available
Recent research at the laboratory scale by a number of organizations in different countries has shown that with the use of particular types of solvents it is possible to achieve almost complete conversion of coal to liquid products under relatively mild process conditions. This work is reviewed and the conclusions to be drawn from it are summarized.
BackgroundTuberculosis (TB) is the most common opportunistic infection in HIV-infected adults in developing countries. Isoniazid (INH) is recommended for treatment of latent TB infection,...Full Text Available
BackgroundErrors have been the concern of providers and consumers of health care services. However, consumers' perception of medical errors in developing countries is rarely explored....Full Text Available
It is often argued that Nursing Minimal Data Sets (NMDSs) have advantages for the nursing profession. The NMDSs that have been developed and applied in some countries have many features in common,...Full Text Available
In this study, the influence of Beryllium (Be) content on the fracture behaviour of Al?15%Mg2Si composite was investigated. The results showed an increase in mechanical properties with increasing of Be content. The stress?strain curves of samples showed a same category of serrations reflecting non-uniform deformation. Scanning electron microscopy was employed to examine the crack nucleation and fracture model. The results indicate that Al?15%Mg2Si composite shows different behaviours of crack initiation and fracture for samples with and without Be. Differences observed in the fracture behaviour were attributed to microstructural changes as well as morphological aspects of primary Mg2Si particles.
By tests about pipe failure under extreme bending, moment at cross sections affected by circumferential cracks, admissible strains for securing the integrity in the area of a flow link are indicated. These are 7% for austenic and ferritic materials in the undisturbed cross section. From d/t-ratios of 20 onwards the strains are limited by pipe bulging on the pressure-load side. In this connection, circumferential flaws do not have any influence on the behaviour on the strained side, when their expansion does not exceed the investigated limitis of <60 circumferential expansion and crack depth of 0,3 t. (orig.)
Appraisals of the isothermal general corrosion of Incoloy 800 in steam at 595 and 650 deg.C indicated good long-term resistance (<7 mg/cm"2 weight gained in 20 years) whether surfaces were ground or electropolished. Electropolished surfaces corroded much faster than ground surfaces in earlier stages, (39 and 15 times as fast in 3000 hr at 595 and 650 deg.C, respectively), but the corrosion rate decreased with time and gave comparable estimates over the long term for both surface preparations. Both nonwelded and welded Incoloy 800 were definately susceptible in chloride stress-corrosion cracking tests of U-bend specimens in a cyclic, wet-dry steam environment. However, C-configuration specimens of Incoloy 800, which were less severly strained, did not crack in this environment. (author).
The present authors have previously developed a new method for Probabilistic Fracture Mechanics (PFM), which they call Recursive Distribution (RD) method. The method is based on the construction of the Lebesgue-Stieltjes measure through a deterministic mapping defining a crack growth process. In the present paper, its theoretical background is first discussed, and the Lebesgue decomposition of the measure is given. Then a numerical example of a Light Water Reactor (LWR)`s piping problem is solved by the present method, and the results are compared with those of the Monte Carlo (MC) method. In addition to leakage probability, a variation in stress cycles of the marginal distribution of an aspect ratio of a semi-elliptical surface crack is calculated, which will be used in a study on LBB evaluation.
This paper is concerned with the real time automatic discriminating of flaws from two categories; i. cracks (planar defect) and ii. Non-cracks (volumetric defect such as cluster porosity and slag) using pulse-echo ultrasound. The raw ultrasonic flaws signal were collected from a computerized robotic plane scanning system over the whole of each reflector as the primary source of data. The signal is then filtered and the analysis in both time and frequency domain were executed to obtain the selected feature. The real time feature analysis techniques measured the number of peaks, maximum index, pulse duration, rise time and fall time. The obtained features could be used to distinguish between quantitatively classified flaws by using various tools in artificial intelligence such as neural networks. The proposed algorithm and complete system were implemented in a computer software developed using Microsoft Visual BASIC 6.0 (author)
Passive films, formed on annealed and cold worked AISI 304 stainless steel in hot chloride media, were examined using polarization resistance and impedance measurements. The obtained results show the influence of cold work on film conductivity, which can be correlated to conditions of susceptibility to stress corrosion cracking. Capacitance measurements, using the Mott-Schottky approach, revealed that a change from n to p type semi-conductivity is associated to susceptible conditions with an increase in the doping density estimated for cold worked samples in the presence of chloride. It is assumed that p-type semi-conductivity of the passive film together with the position of the flat band potential has a strong influence on the dissolution processes at the corrosion potential. Based on this analysis the influence of plastic deformation, at the dislocation scale, is discussed. (authors)
A concentric reducer tube, which was a part of the top exit roughing hydraulic descaler in a hot strip mill failed prematurely under working pressure. A detailed metallurgical investigation comprising physical examination, optical microscopy, scanning electron microscopy, and electron probe microanalysis was carried out to find out the genesis of the failure. Physical examination revealed cracks located symmetrically around the circumference of the tube that ran along its full length, up to the weld beads at both ends. Optical microscopy of etched samples revealed a banded ferrite-pearlite structure and the existence of forging folds near the change-in-section(160? fillets). Cracks were found to initiate from these forging folds. No structural abnormalities were found in the weld beads and...
The mechanical stability of diamond-like carbon (DLC) films coated on nitinol vascular stents was investigated under cyclic loading condition by employing a stent crimping system. DLC films were coated on the vascular stent of a three dimensional structure by using a hybrid ion beam system with rotating jig. The cracking or delamination of the DLC coating occurred dominantly near the hinge connecting the V-shaped segments of the stent where the maximum strain was induced by a cyclic loading of contraction and extension. However the failures were significantly suppressed as the amorphous Si (a-Si) buffer layer thickness increased. Interfacial adhesion strength was estimated from the spalled crack size in the DLC coating for various values of the a-Si buffer layer thickness.
In this work, a pre-cracked semi-circular shaped explosive simulant was loaded using a split Hopkinson pressure bar (SHPB). A high-speed camera was used to capture the deformation and fracture process of the specimen in situ. The digital images were processed using the digital image correlation (DIC) method. Next, full displacement and strain fields were obtained. The displacement vector field shows that the specimen fractured under tensile stress action. The strain field can be used to predict the crack propagation. Results show that the method of combined DIC and SHPB is effective to study the dynamic deformation and fracture behavior of explosive simulants. In addition, the specimen was loaded using a drop weight. The fracture toughness of the specimen was preliminary measured.
The influence of common welding defects such as internal under-cut, incomplete penetration of the root bead, internal concavity and hollow bead have been evaluated in a sour environment. Tests were performed on samples cut from actual pipeline welds. The individual defects were subjected to slow strain rate testing. The samples were then examined by metallography, scanning electron microscopy, and hardness testing. It was established that a threshold stress intensity exists for sulphide stress cracking. The test results were compared to those obtained from samples of the weld and pipe which did not contain any defects. This comparison indicated that the metallurgical variations associated with the presence of a weld are the main factor for sulphide stress cracking rather than any specific defects or geometry. 5 tabs., 9 figs.
The kinetic rate constants for the cracking, isomerization, and disproportionation of n-heptane over a CrHNaY (32% chromium exchanged) zeolite catalyst at 400, 450, and 470/sup 0/C have been calculated. The interaction of n-heptane with a model Lewis acid such as BF/sub 3/ and progress along the reaction coordinate have been studied by means of molecular orbital calculations. From the kinetic results, i.e., activation energies and frequency factors, and the theoretical calculations, it can be concluded that the controlling step in these reactions is not the formation of the carbonium ion, but the subsequent transformation of this carbonium ion. In addition, the theoretical calculations show that the attack of a Lewis acid is more likely to occur on a carbon atom than on a C-H bond.
Consideration is given to the data, demonstrating the effect of ion radiation on strength characteristics of ionic crystals, presented by magnesium oxide. Crystals, prepared in the form of plates, were irradiated by Si"+, Fe"+, C"+ ions by the dose of 10"1"6-10"1"7 ion/cm"2 at room temperature in vacuum. The following characteristics were investigated: dislocation density, microhardness, crack resistance. Investigation of dislocation structure showed, that dislocation density in irradiated sample was 2-3 times higher, as compared to nonirradiated one. Sufficient increase of fracture viscosity of MgO crystals was revealed. It can be conditioned by occurrence of compression stresses in the surface layer, decelerating crack formation and propagation.
In order to develop the filler metal for Hastelloy alloy XR structure with thick wall, the weldability and high temperature strength properties of Hastelloy alloy XR weldment were investigated using the filler metals, which were alloy-designed on the basis of multiple regression analysis. The former was examined through the chemical analysis in the deposited metal, bend test, FISCO cracking test, optical microscopy and hardness measurement. The latter was investigated by means of tensile and creep test. It was found from these results that the crack susceptibility in the weldment was apparent to be lowered without degrading the high temperature strength properties. Therefore, it is concluded that these filler metals possess excellent performance as the filler metal for Hastelloy alloy XR structure with thick wall. (author).
Smooth and notched specimens of the bearing steel 100Cr6 (SAE 52100) in a bainitic condition were used to determine the S-N curves under tensile, torsional and combined in- and out-of-phase loading. In the area of high-cycle fatigue, crack initiation was most likely caused by inclusions like Titanium Carbon nitrides or Aluminium Oxides. A micro mechanical model for the crack initiation by inclusions was developed. Another model was developed to describe the influence of these inclusions on the lifetime. A weakest-link model, using the statistical distribution of inclusions and surface flaws, was used to describe the endurance limit. (orig.)
Hydrous pyrolysis of immature Monterey Phosphatic or Siliceous rock at progressively higher temperatures causes systematic changes in biomarker thermal maturity parameters of the generated hydrocarbons. Biomarker ratios based on proposed carbon-carbon cracking or aromatization reactions increase during hydrous pyrolysis along similar pathways for both Siliceous and Phosphatic members. An increase in these biomarker ratios is also observed for oils of increasing thermal maturity from the offshore Santa Maria Basin, although the rates of changes for each parameter differ between the hydrous pyrolysis and natural samples. Changes in some cracking parameters during maturation appear to result from differential thermal stability of the compounds rather than conversion of precursors to products. (author).
The detection and characterization of deeply buried fatigue damage in thick, multi-layer airframe components pose significant technical challenges to the aviation safety community. Currently, no nondestructive evaluation technique is available to reliably detect such potential damage from the exterior of the airframe, which is highly desirable in light of inspection cost as well as avoidance of structure damage. Recent technological advances in high-sensitivity magnetic sensors, i.e., spin-dependent tunneling (SDT) sensors, make it feasible to employ electromagnetic inspection techniques for deep fatigue crack inspection. In this work, we report on the development and fabrication of a low frequency eddy current probe based on a magnetically shielded SDT pickup sensor concentrically located...
Microstructural observations of damage around indentations in Ti{sub 3}SiC{sub 2} are presented. The Vickers hardness decreased with increasing load and asymptotically approached 4 GPa at the highest loads. No indentation cracks were observed even at loads as high as 300 N. Preliminary strength versus indentation plots indicate that, at least for the large-grained material ({approx}100 {micro}m) studied here, Ti{sub 3}SiC{sub 2} is a damage-tolerant material able to contain the extent of microdamage to a small area around the indent. The following multiple energy-absorbing mechanisms have been identified from scanning electron micrographs of areas in the vicinity of the indentation: diffuse microcracking, delamination, crack deflection, grain push-out, grain pull-out, and the buckling of individual grains.
A validated computational fluid dynamics (CFD) computer code, ICRKFLO, was used to investigate the scale-up effects on the coke yields of thermal cracking riser factors. Comparisons were made for calculated coke yields of pilot- and commercial-scales riser units. Computational results show that the riser aspect ratio, reaction temperature, particle residence time, and particle/oil ratio have major impacts on the coke yield. A computational experiment was conducted to determine optimal operating conditions for a conceptual design of a commercial-scale riser unit. This experiment showed that the performance loss in scale-up from pilot to commercial scale may be almost completely recovered through optimizing the operating conditions after scale-up using the CFD simulations as a guide.
The following subjects were discussed at the conference: Stability of welded joints, creep stress in CrMo steels, life prediction, developments in modern power plant steels, testing, calculation of deformation, crack propagation and crack analysis under complex loads. [German] Die Autoren der Tagung referieren ueber folgende Themen: Stabilitaet von Schweissverbindungen, Kriechbeanspruchung von Chrom-Molybdaen Staehlen, Lebensdauervorhersage, Entwicklungen fuer die Anwendung in modernen Kraftwerken, Prueftechnik, Berechnung von Verformung, Rissentwicklung und -bewertung bei komplexer Beanspruchung. (uke)
Possible use of stable radioisotopes in studies on nutrition and medicine problems that may be used in investigations of babies, children, pregnant women is shown. Attention is paid to behaviour of limited number of elements: hydrogen, carbon, nitrogen, oxygen. The IAEA plans implementation of a new coordinated research program on use of stable isotopes for studying nutrition problems and related diseases. The program emphasis will be placed on protein metabolism measurements and estimation of energy consumption in control population groups in developing countries.
Although not Pakistan`s first independent power project, the 586 MW Uch plant is certainly one of the country`s most important. It is the first gas-fired combined cycle plant to be developed under Pakistan`s Private Power Policy, and uses low heating value natural gas previously thought worthless. The project also features some innovative financing arrangements, and with construction now at an advanced stage, it promises to kick-start the development of private power in Pakistan. (Author)
The paper presents a comprehensive analysis of the energy conservation policy conducted in the Central and Eastern European countries - its development from the start of reforms and up to the present. The problems of rational energy consumption are shown to be closely connected with the concrete conditions of the transition from the economy based on the command principles to the market economy. The author indicates the main areas of application for energy conservation activities. He also describes the models for determination of energy intensity in different branches of energy economy, and organisational structure of the measures to be taken foe energy conservation. (author)
High-voltage transmission lines can pose an environmental problem, especially in countries where the electricity production is at a distance from the demand location. Planning, construction, and operation of high voltage transmission lines should be conducted within a comprehensive environmental policy, which may include assessment of visual impact, landscape and wildlife protection, and reduction of health risks. This paper reviews the environmental policies and action in planning, construction, and operation as developed by the utilities members of the Union Internationale des Producteurs et Distributeurs d`Energie Electrique (UNIPEDE). The paper also presents a brief outline of the health issues associated with the effects of electromagnetic fields to humans.
High-voltage transmission lines can pose an environmental problem, especially in countries where the electricity production is at a distance from the demand location. Planning, construction, and operation of high voltage transmission lines should be conducted within a comprehensive environmental policy, which may include assessment of visual impact, landscape and wildlife protection, and reduction of health risks. This paper reviews the environmental policies and action in planning, construction, and operation as developed by the utilities members of the Union Internationale des Producteurs et Distributeurs d'Energie Electrique (UNIPEDE). The paper also presents a brief outline of the health issues associated with the effects of electromagnetic fields to humans.
Microcomputers are beginning to be used for energy analysis in many developing countries, and have the potential for making a significant contribution to the resolution of difficult analytical and data problems, and to improving communications between analyst and decision maker. Successful introduction of a microcomputer based on analytical capability, however, requires attention to several important factors in order to avoid the mistakes of the earlier mainframe computer era. This paper reviews the key issues of matching models to staff capabilities, of training, and of the operating environment, based on the author's first-hand experience with microcomputer projects in Uruguay, Haiti and Sri Lanka. 3 figures, 3 tables.
Environmental regulations can have a significant impact on product use, disposal, and recycling. This report summarizes the basic aspects of current federal, state and international regulations which apply to end-of-life photovoltaic (PV) modules and PV manufacturing scrap destined for disposal or recycling. It also discusses proposed regulations for electronics that may set the ground of what is to be expected in this area in the near future. In the US, several states have started programs to support the recycling of electronic equipment, and materials destined for recycling often are excepted from solid waste regulations during the collection, transfer, storage and processing stages. California regulations are described separately because they are different from those of most other states. International agreements on the movement of waste between different countries may pose barriers to cross-border shipments. Currently waste moves freely among ...
In developing countries with rapidly growing economies, energy consumption will more than triple by 2030. This will require more than 8 trillion euros in investments in energy in these countries. The way these investments are made will be crucial in determining whether greenhouse gas emissions will rise proportionately. By creating a worldwide, lucrative market for clean technologies, countries can use the money they set aside for fighting climate change to stimulate large-scale private investment in clean energy production and efficient energy consumption. A well-functioning market ensures that money is invested where it will be the most cost-effective and will have the greatest impact in helping to solve a generally recognised problem. This also means making sure that innovations get to the market, so as to take advantage of economies of scale. The conference on 16 and 17 October 2006 in Amsterdam was the official start ...
The Asian countries are expected to generate 45% of the world energy consumption and Japan is the absolutely greatest consumer in Asia, but China is the country that will be most important as a new consumer on the world energy markets. China, like India and later possibly even Japan try to change to natural gas as a source of energy as much as possible. This is causing a competition about the resources that can be reached by pipelines for gas, which in practice means those in Russia and Central Asia. Russia is trying to control the gas in Central Asia. The competition is also increasing about oil. China is becoming heavily dependent on Muslim countries in the Middle East and Central Asia. This also leads to an effort to increase the safety along the sea lanes, which may collide with the interests of other countries. Territorial conflicts with gas and oil as underlying elements exist in Asia. USA is a ...
A large number of proven technical solutions exists for the use of renewable energies (RE). However, their dissemination is still too slow to meet the political goal of substituting 12 % of the primary energy demand in the European Union by the year 2010. Even renewable energy systems (RES) with economic potential are only partly exploited. There is a long literature concerning the barriers to RE use. In particular it has become clear that the availability of finance and the forms and conditions upon which it is lent have a major impact on RE deployment. An area of importance is the deficiency of appropriate ownership forms and properly adapted financing instruments in certain countries. Moreover, different regulations and institutional barriers in the European countries hinder the free flow of capital for RES within the European common market. On the other hand, solutions have been developed very successfully in individual ...
The water and steam circuits of steam generators in pressurized-water nuclear power plants are described together with the mechanism of denting, and the corrosion of spacer plates that leads to cracks in tubes by constriction. The different chemical specifications applicable to the water of the secondary circuit of the generators in normal operation and on first commissioning are listed. The results obtained and the measurements of chemical values taken in operation on the water in the secondary circuits of steam generators at Fessenheim and Bugey are presented.
The water and steam circuits of steam generators in pressurized-water nuclear power plants are described together with the mechanism of denting, and the corrosion of spacer plates that leads to cracks in tubes by constriction. The different chemical specifications applicable to the water of the secondary circuit of the generators in normal operation and on first commissioning are listed. The results obtained and the measurements of chemical values taken in operation on the water in the secondary circuits of steam generators at Fessenheim and Bugey are presented.
Damage survey of protective coats of modern gas turbine blade shows that most damages are not due to classic wear mechanisms such as oxydation or high-temperature corrosion but caused by foreign bodies, poor coating during manufacturing, or operation-caused cracks. Mere visual inspection of cracks is often not sufficient to tell whether cracks are superficial or whether they have already progressed into the base material. Non-destructive methods such as ultrasonic inspection or eddy-current testing are helpful tools but there is not yet a fully matured testing concept at hand. Metallographical tests can give important information about crack mechanisms and thermal, chemical and mechanical stresses.(orig.) [German] Die Schadenerfahrung mit Schutzschichten moderner Gasturbinenschaufeln zeigt, dass die meisten Schaeden nicht auf die klassischen Verbrauchsmechanismen wie Oxydation und ...
The IPIRG-2 program was an international group program managed by the US NRC and funded by organizations from 15 nations. The emphasis of the IPIRG-2 program was the development of data to verify fracture analyses for cracked pipes and fittings subjected to dynamic/cyclic load histories typical of seismic events. The scope included: (1) the study of more complex dynamic/cyclic load histories, i.e., multi-frequency, variable amplitude, simulated seismic excitations, than those considered in the IPIRG-1 program, (2) crack sizes more typical of those considered in Leak-Before-Break (LBB) and in-service flaw evaluations, (3) through-wall-cracked pipe experiments which can be used to validate LBB-type fracture analyses, (4) cracks in and around pipe fittings, such as elbows, and (5) laboratory specimen and separate effect pipe experiments to provide better insight into the effects of dynamic and cyclic load ...
Steam generators (SGs) in PWRs and CANDUs are designed for at least a 30-year operating life. However, in the 15-25 years that SGs tubed with Alloy 600 have operated commercially, they have experienced reduced reliability, mainly due to SG tubing degradation. One of the degradation mechanisms that Alloy 600 SG tubing has suffered from is lead-induced stress corrosion cracking (PbSCC) in AVT and near-neutral SG environments. In contrast to Alloy 600 tubing, test data obtained in high temperature water indicate that Alloy 800 is resistant to cracking by lead and lead compounds. For Alloy 800 (cold worked, shot peened), the most aggressive environment is reported to be alkaline with minor concentration of PbO (80 ppm). Work by Max Helie et al. also concluded that Alloy 800 is not sensitive to lead assisted SCC for pH values close to neutrality, whereas it could be affected in high alkaline conditions. The work reported here investigated the ...
Steam generators (SGs) in PWRs and CANDUs are designed for at least a 30-year operating life. However, in the 15-25 years that SGs tubed with Alloy 600 have operated commercially, they have experienced reduced reliability, mainly due to SG tubing degradation. One of the degradation mechanisms that Alloy 600 SG tubing has suffered from is lead-induced stress corrosion cracking (PbSCC) in AVT and near-neutral SG environments. In contrast to Alloy 600 tubing, test data obtained in high temperature water indicate that Alloy 800 is resistant to cracking by lead and lead compounds. For Alloy 800 (cold worked, shot peened), the most aggressive environment is reported to be alkaline with minor concentration of PbO (80 ppm). Work by Max Helie et al. also concluded that Alloy 800 is not sensitive to lead assisted SCC for pH values close to neutrality, whereas it could be affected in high alkaline conditions. The work reported here investigated the ...
The influence of heat treatment on the structure, mechanical properties and fracture peculiarities of high-strength (#alpha#+#beta#)-titanium alloy VT22 has been studied. It is ascertained that thermal cycling and subsequent high-temperature aging permit to reduce considerably crack growth rate. Thermal cycling is realized in the following mode: heating in #beta#-region, cooling and allowance in (#alpha#+#beta#)-region, heating in #beta#-region.
Radiation hardening in austenitic stainless steels is shown to modify deformation characteristics and correlate well with an increased susceptibility to intergranular stress corrosion cracking (IGSCC). Available data on neutron-irradiated materials have been analyzed and correlations developed between fluence, yield strength and cracking susceptibility in high-temperature water environments. Large heat-to-heat differences in the critical fluence (0.2 to 2.5 x10"2"1 n/cm"2) for IGSCC are documented. In many cases, this variability is consistent with yield strength differences among irradiated materials. IGSCC correlates better to yield strength than to fluence for most heats suggesting a possible role of radiation-induced hardening and microstructure on cracking. Microstructural evolution during proton and heavy-ion irradiation has been characterized in low-carbon 304SSs. Hardening results from a dispersion of dislocation ...
Beta C trademark, a metastable beta titanium alloy developed by RMI Titanium Company, continues to be used in new applications due to its excellent mechanical properties and resistance to corrosion. New data in this paper include mechanical properties in large sections, cold drawn bar and welds. Fatigue crack growth and corrosion data are added to supplement previously published data.
Technology of plasma sputtering, structure and properties of zirconium dioxide coatings were studied. Necessity of void number increase to enhance coating heat-resistance is shown. Optimal powder particle size (20-60 #mu#m) providing optimal coating porosity was determined. Weight part of stabilizating oxide (Y_2O_3) in ZrO_2 for formation in coating of microcracks serving as barriers for macro-cracks propagation was determined.
This book presents the papers given at a conference on offshore platforms. Topics considered in this book include risk assessment, crack propagation, fracture control, stress corrosion, the reliability of pile foundations, the thermal conductivity of offshore pipeline coating material, economic analysis, hydrodynamics, simulation, Arctic structure design, composite materials, buoys, deep water drilling, corrosion protection, pollution control equipment, and subsea exhaust gas compressors.
Post-irradiation annealing was used to help identify the role of radiation-induced segregation (RIS) in irradiation-assisted stress corrosion cracking (IASCC) by preferentially removing dislocation loop damage from proton-irradiated austenitic stainless steels while leaving the RIS of major and minor alloying elements largely unchanged. The goal of this study is to better understand the underlying mechanisms of IASCC. Simulations of post-irradiation annealing of RIS and dislocation loop microstructure predicted that dislocation loops would be removed preferentially over RIS due to both thermodynamic and kinetic considerations. To verify the simulation predictions, a series of post-irradiation annealing experiments were performed. Both a high purity 304L (HP-304L) and a commercial purity 304 (CP-304) stainless steel alloy were irradiated with 3.2 MeV protons at 360 deg. C to doses of 1.0 and 2.5 dpa. Following irradiation, post-irradiation anneals were performed at ...
In this work, energy-based features for gear fault diagnosis and prediction are proposed. The instantaneous energy density is shown to obtain high values when defected teeth are engaged. Three methods are compared in terms of sensitivity, reliability and computation effectiveness. The Wigner Ville distribution is contrasted to the wavelet transform and the newly proposed empirical mode decomposition scheme. It is shown that all three methods are capable of a reliable prediction. An empirical law, which relates the energy content to the crack magnitude is established.
The goal of the present work has been to clarify the influence of sulphate ions on the oxide films formed on stainless steel and Ni-based alloys in simulated crack chemistry conditions using different ex situ analytical techniques. The main observations of this work can be summarised as follows: The thickness of the films formed in simulated oxygen-free crack chemistry conditions during an exposure of circa 4 days varies roughly in the range 200..500 nm, which corresponds to observations reported in the literature [2]. The presence of 10000 ppb sulphate ions in simulated crack tip conditions seems to lead to a considerably lower thickness of the oxide films when compared to sulphate-free conditions. The presence of 10000 ppb sulphate ions leads also to considerable changes in the morphology of the oxide crystals on the material samples. In the absence of sulphate the outer oxide layer contains elongated round-edged ...
This patent describes a catalyst comprising: (a) a non-zeolitic inorganic oxide matrix, and (b) an ultrastable Y-type crystalline zeolite, the ziolite having been pretreated by contacting the zeolite with a phosphorus compound selected from the group consisting of phosphoric acid, phosphorous acid, a salt of phosphoric acid, a salt of phosphorous acid, and mixtures thereof for a time sufficient to composite an effective amount of phosphorus with the zeolite.
A borehole televiewer (BHTV) logging was conducted to investigate cracks in bored wells. The logging process shoots ultrasonic waves onto bore walls and utilizes reflection waves from the bore walls. If the bores are filled with muddy water, or the ultrasonic waves can pass through even if vinyl chloride tubes have been inserted after excavation, the state of the bore walls can be investigated in principle. Conventional optical scanners are, however, incapable of making this investigation. The BHTV logging can be used for identifying lithofacies from reflection intensities from bore walls (it depends on sound impedance of rocks), not to speak of finding cracks. As a result of making logging upon setting time windows from 105 to 145 {mu} sec in a bored well inserted with a vinyl chloride tube, cracks in the bore wall were identified clearly through the vinyl chloride tube. If the distance between the bore wall and the vinyl ...
A new generation of transmit-receive single-pass probes, denoted as C6 or X probe, was field tested during the Gentilly II, 2000 steam generator tube inspection. This probe has a performance equivalent to rotating probes and can be used for tubesheet and full-length inspection at an inspection speed equivalent to that of bobbin probes. Existing C3 transmit-receive probes have been demonstrated to be effective in detecting circumferential cracks. The C5 probe can detect both circumferential and axial cracks and volumetric defects but cannot discriminate between them. The C6 probe expands on the capabilities of both probes in a single probe head. It can simultaneously detect and discriminate between circumferential and axial cracks to satisfy different plugging criteria. It has excellent coverage, good defect detectability, and improved sizing and characterization. Probe data is displayed in C-scan format so that the amount ...
A case study is presented about the failure of a stainless steel blade reinforcing band in a steam turbine. The inspection results and analysis of samples of material are discussed. Being pitting corrosion and cracks the main defects found, a study of chemical composition and heat treatment state of the steel is made and findings are related to type of failure. (orig.)
The purpose of the present work is to investigate the effects of matrix resin and fiber content on the behavior of fatigue crack propagation in continuous-glass-fiber-mat reinforced CP-resin composites. For this purpose, ductile matrix resin and brittle one are used. These two kinds of resins have the characteristic that the elastic modulus and tensile strength are nearly the same with each other while the elongation is different. The composite specimens are made of these resins and continuous grass fiber mat of 20 wt.% and 60 wt% fiber contents. The fatigue crack propagation test was conducted by using the tapered DCB specimens to control the stress intensity factor range, {delta}K, during the test. The results obtained are as follows; (1) The relation between the crack propagation rate, da/dN, and {delta}K for all the present materials is shown by a straight line in logarithmic representation. (2) For the composites of 20 ...
The effect of treatment with hydrogen, hydrogen sulfide, and steam on the catalytic properties of NaY zeolites has been studied. A mechanism has been proposed for activation of the zeolites, which explains the appearance of Broensted acid centers on modified samples. The influence of modification temperature and the degree of decationization of the zeolites on the promoting capacity of the latter in the cumene cracking reaction has been studied.
Coal liquefaction technology aims to obtain a liquid fuel from coal by cracking the coal under elevated temperature and pressure and simultaneously adding hydrogen, either directly as a gas or by way of a suitable solvent. The author describes the work being done on coal liquefaction in Japan, where this technology is being developed as part of a large-scale national project.
Effect of hydroxide nature, concentration and temperature on corrosion resistance of domestic steels and alloys to hot NaOH, KOH, LiOH solutions is considered. It is ascertained that by corrosion growth in relation to stainless steels and nickel alloys, the hydroxides are placed in the following sequence: LiOHcracking is manifested, are determined. 12 refs., 12 figs.
A historical overview of corrosion problems found in power plant condensers and mitigation procedures is presented. The paper is organized according to alloy type and failure mode. Alloys considered are copper-base alloys, stainless steels and titanium. Failure modes discussed include erosion-corrosion, sulfide attack, environmentally assisted cracking, galvanic corrosion, steam condensate corrosion, pitting corrosion, and dealloying. Mitigation procedures discussed include cathodic protection, ferrous ion injection, as well as tube cleaning and layup practices.
The 1977 version of the Simpson-Puls-Dutton model appears to be the most amenable with respect to utilizing known or readily estimated quantities. The Pardee-Paton model requires extensive calculations involving estimated quantities. Recent observations by Koike and Suzuki on vanadium support the general assumption that crack growth in hydride forming metals is determined by the rate of hydride formation, and their hydrogen atmosphere-displacive transformation model is of potential interest in explaining hydrogen embrittlement in ferrous alloys as well as hydride formers. The discontinuous nature of cracking due to hydrogen embrittlement appears to depend very strongly on localized stress intensities, thereby pointing to the role of microstructure in influencing crack initiation, fracture mode and crack path. The initiation of hydrogen induced failures over relatively short periods of time can be ...
As the 20th century draws to a close, both individual countries and the world community face challenging problems related to the supply and use energy. These include local and regional environmental impacts, the prospect of global climate and sea level change associated with the greenhouse effect, and threats to international relations in connection with oil supply or nuclear proliferation. For developing countries, the financial cost of providing energy to provide basic needs and fuel economic development pose an additional burden. To assess the magnitude of future problems and the potential effectiveness of response strategies, it is important to understand how and why energy use has changed in the post and where it is heading. This requires study of the activities for which energy is used, and of how people and technology interact to provide the energy services that are desired. The authors and their colleagues have analyzed trends in energy ...
As the 20th century draws to a close, both individual countries and the world community face challenging problems related to the supply and use energy. These include local and regional environmental impacts, the prospect of global climate and sea level change associated with the greenhouse effect, and threats to international relations in connection with oil supply or nuclear proliferation. For developing countries, the financial cost of providing energy to provide basic needs and fuel economic development pose an additional burden. To assess the magnitude of future problems and the potential effectiveness of response strategies, it is important to understand how and why energy use has changed in the post and where it is heading. This requires study of the activities for which energy is used, and of how people and technology interact to provide the energy services that are desired. The authors and their colleagues have analyzed trends in energy ...
An initial draft of an environmental and natural resource strategy for the Asia Near/East region in the 1990's is presented. The report contains five chapters. Chapter I provides an analytic framework that links natural resources, their extent, quality, and management with economic growth in the region. Chapter II contains a more detailed description and analysis of key resource problems that are restricting economic growth and have a severe negative impact on standard of living and quality of life. The most serious of these are soil and water degradation; destruction of natural forests, wetlands, and coastal zones; inefficient energy use and industrial pollution; and lack of environmental services. Chapters III and IV describe 20 specific opportunities for working toward sustainable economic growth through protection and enhancement of the natural resource base. Opportunities for action were chosen on the basis of the urgency and importance of the problems, the availability ...
The technology for performance testing and improvement of materials which are durable at space environment is a military related technology and veiled and securely regulated in advanced countries such as US and Russia. This core technology cannot be easily transferred to other country too. Therefore, this technology is the most fundamental and necessary research area for the successful establishment of space environment system. Since the task for evaluating the effects of space materials and components by space radiation plays important role in satellite lifetime extension and running failure percentage decrease, it is necessary to establish simulated space radiation facility and systematic testing procedure. This report has dealt with the status of the technology to enable the simulation of space environment effects, including the effect of space radiation on space materials. This information such as the fundamental knowledge of space ...
Many Asian countries have experienced rapid economic growth during recent years and this trend is expected to continue. The economic growth is accompanied by increasing energy demand, with coal as the dominant energy source. For the first time a model has been specifically developed and applied for integrated assessment of future SO{sub 2} emissions in Asia. The report deals with the RAINS-ASIA model developed in Norway offering an opportunity to assess sulphur deposition and ecosystem protection levels resulting from different energy pathways and different emission control strategies. The cost of various control strategies are also provided. During the project an impressive database has been collected for the region (23 countries, 94 subregions and 355 large point sources). This was made possible through dedicated work by the project team, in close collaboration with scientific and technical institutions in several Asian ...
This paper examines the dynamic international political economic environment in which petroleum exploration and production companies must operate when considering investments in the economically transitional nations of the former Soviet Union or developing nations In this period of critical global changes low oil prices is only one factor with which petroleum companies Must be. concerned in their investment decisions Other factors include the transition from a bipolar world to a multipolar world of free trade zones. the general malaise of the international economy public and political recognition that nations and industries can no longer practice environmental {open_quotes}beggar-thy-neighbor{close_quotes} policies, and the rejection of aggregate national economic growth policies for sustainable economic development policies in both the Developed and developing world This paper focuses on actions which investing petroleum exploration and production companies can take in order to gain a ...
The first section of this Handbook describes hydro-electric projects currently under construction or recently commissioned in a number of countries. The major part of the Handbook is devoted to lists of data relating to hydro-electric plants and hydromachinery. These include: data for 1990 submitted by national power authorities on hydro-electric and pumped-storage plants in operation, under construction or planned; more detailed data for pumped-storage plants; country by country data on the dimensions, and reservoir and electrical capacity of major dams and hydro plant; a listing of roller compacted concrete dams; a listing of the world's largest turbines giving data on the largest unit at each scheme in rank order ranging from a unit capacity of 838 MV down to 147 MV; a similar list of the largest hydrogenerators ranging from a unit capacity of 825 MVA down to 150 MVA; details of turbine and generator contracts. ...
The French nuclear power program was pushed through in order to reduce the country's dependence on imported fossil sources of energy. Nuclear power and hydro power have achieved a level of self-sufficiency in the energy sector of more than 50%. It should be emphasized that the French nuclear power program was largely self-financed. Electricite de France (EdF) considers itself well prepared for the European market, provided the creation of the single market implies that electricity rates are taken as a yardstick of competitiveness. Negotiations about a European directive on deregulating the electricity market were for the government to hold. EdF pleaded in favor of preserving for each country a certain leeway for shaping its own policy. The road to deregulation was to be opened, but the specific situation of each country was to be taken electricity to be passed through imposes narrow constraints upon an expansion of ...
The possibilities to design and prepare better and more organ-specific radiopharmaceuticals for diagnostic nuclear medicine has increased dramatically in the recent past with a deeper understanding of the relationships between chemical structure and biological activity. Whereas most of the research is performed in well-funded laboratories of industrialized countries, there are several developing countries with adequate resources and expertise as to undertake fruitful research in the field of radiopharmacy. With the aim of promoting advanced research in radiopharmacy by developing new radiodiagnostics agents, in particular, hepatobiliary imaging agents labelled with "9"9"mTc, and to facilitate exchange of information, the IAEA has established in 1983 the present Research Co-ordination Programme (CRP) with a duration of five years. The report includes detailed results obtained by all participants as well as novel preparation procedures for some ...
Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal firms and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in the advanced DEA linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of total technical efficiency or decomposed pure technical and scale efficiency, is much lower than in American coal firms. The study also highlights the input ...
Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in the energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal companies and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in advanced data envelopment analysis (DEA) linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of total technical efficiency or decomposed pure technical and scale efficiency, is much lower than in American coal firms. The ...
Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal firms and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in the advanced DEA linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of total technical efficiency or decomposed pure technical and scale efficiency, is much lower than in American coal firms. The study also highlights the input ...
Light duty vehicles, i.e. passenger cars and light trucks, account for approximately half of global transportation energy demand and, thus, a major share of carbon dioxide and other emissions from the transport sector. Energy consumption in the transport sector is expected to grow in the future, especially in developing countries. Cars with alternative powertrains to internal combustion engines (notably battery, hybrid and fuel-cell powertrains), in combination with potentially low carbon electricity or alternative fuels (notably hydrogen and methanol), can reduce energy demand by at least 50%, and carbon dioxide and regulated emissions much further. This article presents a comparative technical and economic assessment of promising future fuel/vehicle combinations. There are several promising technologies but no obvious winners. However, the electric drivetrain is a common denominator in the alternative powertrains and continued cost reductions are important for ...
All African Nations belong to the category of third world underdeveloped countries of the world. UNDP Human Development Index uses factors like per capita income, health of the people, and educational attainment to classify countries. Adult literacy and gross enrolment ratios are indicators of education status. This paper uses Nigeria, a typical African country, to illustrate the problems posed by adult illiteracy to national development. Statistical data are used to show the low levels of adult literacy with disparities between males and females; urban and rural areas, and between different zones of Nigeria and the continent. Enrolments and completion rate in adult literacy programmes are presented. Nigeria's policy on adult and non formal education as reflected in the Nigerian constitution (1999), National Policy on Education (2004 edition), Decree 17 on the National Commission for Mass Literacy, Adult and Non formal ...
Gross electricity production in 1993 in the OECD (including generation from pumped storage plants) was 7 466 TWh, a rise of 1.2 per cent from the level of gross production in 1992 (Tables 1 and 3). Nuclear plants accounted for 24.2 per cent of total gross electricity production in 1993, hydroelectric plants 16.7 per cent, total thermal plants 58.7 per cent and geothermal and other renewables 0.4 per cent. In 1992 total OECD heat production that is sold to third parties by public producers was 25 Mtoe (Table 6). About 86 per cent of this heat (21.6 Mtoe) was produced in CHP plants, about 12 per cent (3.1 Mtoe) in heat plants, and the remainder (0.3 Mtoe) in nuclear power plants (in Canada and Switzerland only). Based on preliminary data, apparent consumption of electricity (gross production plus imports less exports) in 1993 in OECD was 7 474 TWh. The corresponding figure for 1992 was 7 379 TWh, indicating a rise of 1.3 per cent in apparent electricity consumption in OECD ...
A technique has been developed to estimate the percent population having electric power access based on the presence of satellite detected nighttime lighting. A global survey was conducted for the year 2006 using nighttime lights collected by the U.S. Air Force Defense Meteorological Satellite Program (DMSP) in combination with the U.S. Department of Energy Landscan population dataset. The survey includes results for 229 countries and more than 2000 subnational units. The results are compared to reported electrification rates for 87 countries compiled from a variety of sources by the International Energy Agency. The DMSP derived estimate of number of people worldwide who lack access to electricity is 1.62 billion, only slightly larger than the 1.58 billion estimated by the International Energy Agency.
Although destruction of United States wetlands has slowed, their continued conversion, especially in certain inland regions of the country, may pose adverse ecological effects over the next few decades. The Army Corps of Engineers' regulatory program (Section 404 of the Clean Water Act) protects most coastal wetlands, but provides no protection for 95% of the country's wetlands which remain inland. These inland, freshwater wetlands, converted for agricultural purposes, comprise 80% of the wetland losses over the past 30 years. This report outlines options for more effective federal management, such as the mapping and categorizing of wetlands to determine relative values. In effect, agencies can focus protection programs on higher-value wetlands, especially those threatened by agricultural conversion. The report also discusses the contradictory federal policies aimed at wetlands; for example, the tax code encourages the ...
Full text: The nuclear renaissance, anticipated by AREVA in the beginning of the century is now happening in several countries around the world. The fundamentals being the increasing demand of energy, the volatility of fossil fuel prices, the awareness of climate change threat connected with the extensive use of fossil fuels. The EPRTM reactor present significant improvements compared to previous generation reactors enabling to reach an outstanding safety level (redundancy of safety systems, airplane crash resistance), to improve the economics (extended plant lifetime, flexibility and availability during operation and, increased efficiency and fuel utilization) while limiting the impact on workers and the environment. Several countries have been implementing the transition to third generation reactors. The presentation will analyze different examples in order to draw the lessons learned from this first wave and to set-up the criteria for a ...
World oil prices are responsible for new concerns about the health of the international banking system, particularly the $60 billion in annual deficits of the developing countries. If the banks continue lending money to these countries in hopes of repayment in better times, they could jeopardize their financial position; but if they stop the loans, they will jeopardize repayment of the present debts. High US interest rates, heavy goods and technology, economic sanctions imposed by the US in response to Russia's invasion of Afghanistan, and the unregulated Eurocurrency market have contributed to the problem. No one knows how great a loss the capital markets can sustain and still survive. New banking arrangements by the World Bank and other institutions are still unproven. 19 references. (DCK)
Background:- Discrepancies exist in optometric education, practice and regulation across the Asia-Pacific region and the competence of optometric practitioners in adopting new lens technologies may vary widely. Over the past 10-years, a continuing professional development program, Varilux Academy Asia-Pacific (VAAP), was implemented and conducted in countries across the Asia-Pacific region to improve practitioners' understanding of optometric fitting principles, with special emphasis on progressive addition lenses (PAL). The aim was to demonstrate the effectiveness of VAAP and to compare the competence of practitioners across the Asia-Pacific region in new lens fitting technologies. Methods:- From 2002 to 2008, all VAAP participants from 12 countries across Asia-Pacific were invited to com...
This study revisits the environmental Kuznets curve (EKC) hypothesis for water pollution by using a recent dynamic technique, which is the generalized method of moments (GMM) approach, for a board sample of 97 countries during the period 1980-2001. On a global scale, as we cannot obtain the EKC relationship between real income and biological oxygen demand (BOD) emissions, this paper further classifies these countries into four regional groups - Africa, Asia and Oceania, America, and Europe - to explore whether the different regions have different ECK relationships. The empirical results show evidence of the inverted U-shaped EKC relationships' existence in America and Europe, but not in Africa and Asia and Oceania. Thus, the regional difference of EKC for water pollution is supported. Furthermore, the estimated turning points are, approximately, US$13,956 and US$38,221 for America and Europe, respectively.
This study revisits the environmental Kuznets curve (EKC) hypothesis for water pollution by using a recent dynamic technique, which is the generalized method of moments (GMM) approach, for a board sample of 97 countries during the period 1980-2001. On a global scale, as we cannot obtain the EKC relationship between real income and biological oxygen demand (BOD) emissions, this paper further classifies these countries into four regional groups - Africa, Asia and Oceania, America, and Europe - to explore whether the different regions have different ECK relationships. The empirical results show evidence of the inverted U-shaped EKC relationships' existence in America and Europe, but not in Africa and Asia and Oceania. Thus, the regional difference of EKC for water pollution is supported. Furthermore, the estimated turning points are, approximately, US$13,956 and US$38,221 for America and Europe, respectively.
This study revisits the environmental Kuznets curve (EKC) hypothesis for water pollution by using a recent dynamic technique, which is the generalized method of moments (GMM) approach, for a board sample of 97 countries during the period 1980-2001. On a global scale, as we cannot obtain the EKC relationship between real income and biological oxygen demand (BOD) emissions, this paper further classifies these countries into four regional groups - Africa, Asia and Oceania, America, and Europe - to explore whether the different regions have different ECK relationships. The empirical results show evidence of the inverted U-shaped EKC relationships' existence in America and Europe, but not in Africa and Asia and Oceania. Thus, the regional difference of EKC for water pollution is supported. Furthermore, the estimated turning points are, approximately, US$13,956 and US$38,221 for America and Europe, respectively. (author)
Some aspects of the PSO scheme for natural gas are examined critically. Two central arguments used for justifying the PSO subsidy scheme of natural gas and its distribution are reviewed; these include the 'smallholder argument' and the 'environmental argument'. The 'smallholder argument' claims that since Norway has the natural gas resources, it should also make use of the natural gas in the country, and not simply send the raw material to other countries. The 'environmental argument' states that natural gas compared to other fossil fuels such as coal and fuel oil, is a far cleaner alternative, thus an environmental-friendly alternative entitled to financial support. The arguments are critically examined by the author (ml)
Thailand's demand for gas will outstrip supplies in the late 1990s as rapid economic growth continues. Gas will be a cornerstone for Thai energy policy throughout the growth, although sources in neighboring countries need development. Thai gas production will rise 25% from 1992 to average 1 bcfd by 1995. Including production from new discoveries, production could rise to 1.5 bcfd by 2000, up almost 90% from the 1992 level. Increased gas flow output in the mid-1990s will be due largely to development of Gulf of Thailand fields. By 1998, production from Gulf of Thailand fields will not be enough to offset the decline in today's fields. Thailand will need to import more than 1 bcfd by 2005 in the absence of future discoveries in the country. The paper discusses new pipelines and imports.
Abstract An important aspect of Chinese academic health science libraries is their involvement in teaching medical information retrieval courses as part of the medical curriculum. Health science librarians in China have a more formal teaching role than is generally found in Western countries, including many full time teaching positions. This article provides a case study of Kunming Medical University Library, where courses are provided as credit units at both undergraduate and postgraduate levels. The teaching practices of Chinese health science libraries are compared with teaching experiences reported in Western countries. It is noted that Chinese government s educational policy is similar to that of the United States in promoting the role of the library in teaching subjects as part of th...
In recent years, cobia has become an emerging farmed species in Asia due to its quick growth and high economic value. This study collects biological and economic data affecting the economic performance of cobia farming in three countries, namely Taiwan, China, and Vietnam. The data are collected by questionnaire sampling and analyzed by multivariate statistical analysis in order to compare the key factors affecting the production and economy of cobia farming in these three countries. The results show that Taiwan, China, and Vietnam have significant differences in input intensities and profitability. China has the highest input intensity (3372.42?TWD/m3), as its high stocking density increases feed input. Taiwan has the highest unit input cost (103.44?TWD/kg), as the high quality of the pro...
The Spratly Islands are developing into a flashpoint in the South China Sea region. Geological surveys conducted underneath the seabed of these islands following the oil crisis in the 1970s shows an enormous potential of oil and gas reserves. Moreover, with the adoption of the new International Law of the Sea concept there are overlapping claims by contending countries. Unless these claimant countries reconcile their differences and come to terms, the conflict is bound to escalate. This thesis is an in depth study of the disputes over the Spratlys and examines four cases of islands based territorial disputes that could be used as a model in resolving these tensions. This thesis argues that a military option will only create division and in-flame longstanding animosities. Instead, a peaceful solution is recommended as quickly as possible so that regional nations will realize the full potential of these islands. Spratly Islands in the South China ...
The national research and development (R&D) base has in the post-cold war era gained increased importance in order to fill new security demands. There is a broadening of the search for security relevant science and technology involving more organizations and interests, scientific disciplines and nations. The question discussed in this article is if the premises of international, free and open R&D will be(come) compromised? Will we see more scientists, in their normal scientific activities, being accused of spying? The article suggests that such risks are not unrealistic to expect. Spy cases in less democratic countries could have consequences for scientists also in other countries. Outcomes depend on, among other things, the relative strengths of academic freedom and a political ...
Increase in power utility loads in industrialized countries, as well as developing countries, demands a higher level of transmission line voltage. Radio interference (RI) problems have been determined to be a limiting factor in selecting the size of transmission line conductors. Transmission line noise is primarily caused by corona discharges in the immediate vicinity of the conductor. It has been observed that discharges occur during both half-cycles of the applied voltage, but positive corona is usually predominant at AM radio frequencies range with practical high-voltage and extra high-voltage transmission lines. The corona radio noise effect is highly dependent upon the presence of particles on the surface of the conductor and the increase of the electrical gradient beyond the breakdown value of the air. Therefore, corona radio noise varies significantly with the weather and atmospheric conditions and generally increases by 10 to 30 dB in ...
Increase in power utility loads in industrialized countries, as well as developing countries, demands a higher level of transmission line voltage. Radio interference (RI) problems have been determined to be a limiting factor in selecting the size of transmission line conductors. Transmission line noise is primarily caused by corona discharges in the immediate vicinity of the conductor. It has been observed that discharges occur during both half-cycles of the applied voltage, but positive corona is usually predominant at AM radio frequencies range with practical high-voltage and extra high-voltage transmission lines. The corona radio noise effect is highly dependent upon the presence of particles on the surface of the conductor and the increase of the electrical gradient beyond the breakdown value of the air. Therefore, corona radio noise varies significantly with the weather and atmospheric conditions and generally increases by 10 to 30 dB in ...
Increase in power utility loads in industrialized countries, as well as developing countries, demands a higher level of transmission line voltage. Radio interference (RI) problems have been determined to be a limiting factor in selecting the size of transmission line conductors. Transmission line noise is primarily caused by corona discharges in the immediate vicinity of the conductor. It has been observed that discharges occur during both half-cycles of the applied voltage, but positive corona is usually predominant at AM radio frequencies range with practical high-voltage and extra high-voltage transmission lines. The corona radio noise effect is highly dependent upon the presence of particles on the surface of the conductor and the increase of the electrical gradient beyond the breakdown value of the air. Therefore, corona radio noise varies significantly with the weather and atmospheric conditions and generally increases by 10 to 30 dB in ...
The Riskaudit 7 report has been made by a group of independent experts from Western European countries representing technical organizations specialized in the support of regulatory bodies of those countries. It represents a preliminary estimation of the Ukrainian WWER B 213 and B 320 reactors, based on the example of Rovno NPP, analysed with a Western practice. The first part of the document covers the following aspects of the report: core design and fuel management; pressurized components; electrical supply; instrumentation and control; containment; internal events; site conditions and external events.
Pathway analyses are regarded by National Plant Protection Organizations as a very efficient way to address the risks posed by invasive alien species. Data on import of aquatic plants was obtained from 10 EPPO countries (Austria, Czech Republic, Estonia, France, Germany, Hungary, the Netherlands, Latvia, Switzerland and Turkey) and aggregated in order to consider whether invasive or potentially invasive alien plants could be introduced in the EPPO region through this pathway. This study highlights that this pathway mainly consists of the import of tropical plants for use in aquaria, and which do not represent a risk due to their climatic requirements. However, a few species require thorough attention owing to the threats they cause. Of the 247 species recorded as imported, only 10 are curr...
Over 170 participants from 60 countries met for three days in Copenhagen from 7 to 9 June 1994 to discuss howe the aims of the United Nations Framework convention on Climate Change can be translated into practical action. The Conference was organised by the UNEP collaborating Centre on Energy and Environment (UCCEE), with financial support from the Danish International Development Agency (Danida), the Global Environment Facility (GEF), the United Nations Environment Programme (UNEP) and Risoe National Laboratory, Denmark. The main objective of the conference was to identify common approaches to national mitigation analysis for countries to use in meeting their commitments under the FCCC, and in setting priorities for national actions. Although addressing a broader theme, the conference marked the completion and publication of the second phase on UNEP Greenhouse Gas Abatement Costing Study. (au)
This paper summarizes the IHY and BSS activities in West Asia and their importance in many Arab countries, such as Algeria, Egypt, Iraq, Jordan, Kuwait, Qatar, Saudi Arabia, UAE, etc. BSS future plans for some of these countries are as follows: It is proposed by the astronomers from the Arabian Gulf Region to build the Gulf Observatory on top of Jabal Shams (2980 msl) which will have a 2-3 m optical telescope. Libya signed a contract with a French company for building an observatory which will have a 2-m optical robotic telescope. It is also proposed to rebuild the Iraqi National Astronomical Observatory (INAO) which was destroyed during the two wars. It is planned to build a 5-6 m optical telescope and a small solar telescope on the top of Korek mountain, which has excellent observing conditions.
An international conference on forestry research presented papers on topics including forest mensuration, growth and yield; growth/yield relationships; design, performance, and evaluation of experiments; forest resource inventory and monitoring techniques; forest management, planning, and managerial economics; forestry and rural development in developing countries; forestry in sustainable economic development; conceptual advances in multiple-use forestry evaluations; economic evaluation of forest damages; supply and demand of roundwood and forest industry products; forestry and rural development in industrialized countries; analysis and evaluation of forest policies; forest institutions and organizations; biological and economic considerations when harvesting young thinning stands; applied sector modelling; and structural changes of the forest sector in a global perspective. Separate abstracts have been prepared for 3 papers from this ...
Renewable Energy Technologies (RETS) have over the years become an integral part of the energy supply chain in most developed countries. Recent projections show that 13.5% of the world's primary energy supply comes from renewable and this figure has an aggregated annual growth rate of 16%. Wind has the highest annual growth rate of 22% while the least annual growth rate of 2% is for hydropower. The main push for renewable like wind in the OECD countries are environmental concerns and the business aspect in power generation. The situation is however completely different in Africa, where the thrust for RETs is developmental based. Although the continent has abundant renewable energy resources like solar, biomass, wind and hydro potential, they have remained largely unexploited. Several efforts have been made to help African countries like Zimbabwe to exploit such resources. The main objectives of this ...
Nuclear energy generates 30% of the electricity in the EU. Still, different countries of EU27 have very different attitudes towards the future use of nuclear energy for electricity generation or other uses. However, independently of the political decision of continuation or phase out of the nuclear energy, all countries using nuclear energy to generate electricity are facing the question of the final management of its spent nuclear fuel and other high level radioactive wastes. Partition and Transmutation are emerging technologies that when integrated in advanced fuel cycles can strongly influence on the final wastes from the nuclear industry and its management. A review of the progress on the understanding of their real potentialities and main conclusions from a large number of internation...
The number of immigrants to Western Europe has been increasing, with immigration the subject of much controversy in contemporary Europe. In this article, we investigate the relationship between the size of the immigrant population, how natives perceive this size, and their anti-immigrant attitudes. We use data from the 2002/2003 European Social Survey covering 17 Western European countries, and we find that as a rule Western Europeans think that the immigrant population in their country is much larger than it actually is. The perceived size of an immigrant population has an impact on anti-immigrant prejudices, but the real size does not. Like many authors before us, we find that education reduces prejudice. However, we also find that around 10 percent of the total effect of education is a ...
Abstract Hepatitis B (HBV) and C (HCV) viruses are the most important infections transmitted by the parenteral route in patients receiving maintenance dialysis. The prevalence varies markedly from country to country. The aim of this study is to review the efficacy of the strategies to reduce the incidence of these infections and the trend of results in Iran. As a routine, all hemodialysis patients in Iran have biannual blood samples for assessment of serum HBSAg, HBS Abs, and HCV Abs. The data are collected in the Ministry of Health. For statistical analysis, prevalence, and incidence were calculated. There is an increasing prevalence/incidence of end-stage renal disease (ESRD) in Iran, from 238/49.9 pmp in 2000 to 357/63.8 pmp in 2006. The prevalence of positive HBSAg and HCV Abs decrease...
This paper has two key objectives. Firstly, using the findings from case study research undertaken in Colombo (Sri Lanka), Faisalabad (Pakistan) and Dar es Salaam (Tanzania), the paper seeks to demonstrate the importance of an appropriate regulatory framework and effective mechanisms of enforcement for sustainable urban transport systems in developing countries. Secondly, the paper highlights the critical importance of communication and co-ordination between stakeholders (defined here as transport users, providers and regulators) if regulation is to be effective. The views of poor and disadvantaged passenger groups-women, children, the elderly and disabled-are used in the paper to illustrate the importance of transport systems to their livelihoods, such as work, education, health and socia...
In recent years, the concept of sustainable consumption (SC) has received increased attention. Overconsumption in industrialized countries still presents major challenges to achieving sustainable development goals despite the global economic crisis. This paper offers an in-depth analysis of national influences on consumption patterns in the Republic of Ireland, focusing in particular on the role of governance in the design of policy instruments for sustainable consumption. It is argued that country-specific political conditions and policy frameworks fundamentally shape everyday household consumption. After an initial discussion of the effectiveness of three key types of policy instruments?legislative, economic, communicative?the paper compares SC policy making and implementation in Ireland...
Whether or not a current account deficit sustainable has important implications for policy. If the current account deficits of a nation is sustainable, then it implies that the government should have no incentive to default on its international debt. In this article we examine whether or not the current account deficits for the OECD countries can be characterized by a unit root process with regime switching. The econometric methodology allows us to distinguish periods that are associated with unsustainable outcomes from those in which the intertemporal national long-run budget constraint (LRBC) holds. Among the main results, it is found that it is very likely that the LRBC will not hold for the Australia, the Czech Republic, Finland, Hungary, New Zealand, Portugal or Spain, thus signifying...
Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal firms and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in the advanced DEA linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of tot...
ALLEYNE G., HANCOCK C. & HUGHES P. (2011) Chronic and non-communicable diseases: a critical challenge for nurses globally. International Nursing Review58, 328-331 Background:- Chronic and non-communicable diseases (NCDs) are a growing and enormous challenge that faces countries across the world. Low- and middle-income countries are disproportionately affected. Contributory factors:- Three risk factors - tobacco use, poor diet (including excessive alcohol intake) and lack of physical activity - contribute to four major chronic diseases - cardiovascular, chronic obstructive pulmonary disease, diabetes and some cancers, which are responsible for over 50% of deaths worldwide. Potential solutions:- International governmental and non-governmental agencies are becoming increasingly concerned and ...
Nuclear and other radioactive materials may get smuggled into the country aimed at malicious acts. Radioactive material detected accidentally or during inspection at the entry points/national borders may indicate illicit trafficking for the purpose of nuclear/radiological terrorism. As country requires prevention and preparedness for response to these malicious acts, nuclear forensic techniques are to be developed incorporating radiological safety aspects. Nuclear forensics helps in determining the origin, intended use, legal owner and the smuggled route etc. by using fingerprinting as well as comparison with reference data. The suggested sequence of methods for analysis of radioactive material/samples will be radiological assessment, physical characterization, traditional forensic analysis, isotope analysis along with elemental/chemical analysis
The marketing strategy developed for use in international markets by the S. M. Group International of Longueuil, Quebec, a company with interest and well-developed expertise in the environmental and energy sector, was described. The strategy is designed to aid in the selection of countries or regions of interest, in determining the sector of activity to be emphasized, in selecting a local partner or local business representatives, and in making contact locally with the people responsible for the development banks in the target countries in an effort to create awareness of the company. The company also tries, wherever possible, to promote its services to local governmental agencies through the industrial cooperation program of CIDA. Since development banks have a very conservative behaviour, past performances and constant provision of high quality services are of prime importance.
The aim of this economic study is the wording of a synthetic document for the public information in the framework of the 98/30/CE european directive transposition to the gas internal market. It is writing in four main chapters, one for each country concerned: the Germany, the Spain, the Netherlands and the United Kingdom. Each one presents the historical context, the actors of the natural gas industry and the main provisions. (A.L.B.)
Abstract Large areas of the southern European countries possess a Mediterranean climate, which influences soil properties, land use, fertilizer application practices and pathways of phosphorus (P) loss from agricultural soils. On average, inputs of fertilizer P exceed P exports from the agricultural areas in these countries; however, large differences in P surplus/deficit and soil P test values exist among regions. Losses of P in drainage water are modest except in some irrigated areas and in those regions where intensive animal production is concentrated. Losses of P in runoff water, whether as dissolved reactive or particulate P, can be substantial as a result of the significance of erosive processes under the land uses typical of the Mediterranean region, where extreme rainfall events c...
Abstract: We used socioeconomic models that included economic inequality to predict biodiversity loss, measured as the proportion of threatened plant and vertebrate species, across 50 countries. Our main goal was to evaluate whether economic inequality, measured as the Gini index of income distribution, improved the explanatory power of our statistical models. We compared four models that included the following: only population density, economic footprint (i.e., the size of the economy relative to the country area), economic footprint and income inequality (Gini index), and an index of environmental governance. We also tested the environmental Kuznets curve hypothesis, but it was not supported by the data. Statistical comparisons of the models revealed that the model including both economi...
The influence of high temperature thermal ageing treatments on the development of intercrystalline creep damage in two variants of Alloy 800 has been investigated. Ageing up to 3000 h and creep testing were carried out at 800 and 900 C. The high temperature behaviour of the 800HT variant is discussed with reference to the effect of heat treatments on the microstructure. The metallographic methods by which the creep damage was quantitatively determined are described. The growth rate of intercrystalline microcracks was described using a statistical model and the dependence of crack growth rate on the thermal history for both 800HT and 800H was determined. The carbide precipitation and growth processes were determined as functions of the exposure temperature and duration. The results showed the three characteristic stages, precipitation, growth and coarsening (Ostwald ripening). The largest increase in the intergranular creep damage was found in Alloy 800HT within the ...
There is currently considerable interest in identifying and quantifying the effects of welding procedure parameters and steel composition factors on the risk of cracking in pipeline girth welds that may be experienced during winter construction. Although low ambient temperatures, that may be experienced during winter construction, are generally assumed to increase the risk of cracking there has been little work to quantify the effects and to suggest how welding procedures should be modified for winter conditions. The present work was undertaken to calculate the effects of changes in welding parameters on the thermal cycle and the diffusion of hydrogen for a typical pipeline girth weld. A simple analytical method and the finite element method (FEM) were used. Both methods gave similar results but the simple method was very sensitive to the value of heat transfer coefficient. The results showed that the relation between the hydrogen diffusion ...
Essential to today's modern refineries and the gasoline production process are fluidized catalytic cracking units. By using a computational fluid dynamics (CFD) code developed at Argonne National Laboratory to simulate the riser, parametric and sensitivity studies were performed to determine the effect of catalyst inlet conditions on the riser hydrodynamics and on the product yields. Simulations were created on the basis of a general riser configuration and operating conditions. The results of this work are indications of riser operating conditions that will maximize specific product yields. The CFD code is a three-dimensional, multiphase, turbulent, reacting flow code with phenomenological models for particle-solid interactions, droplet evaporation, and chemical kinetics. The code has been validated against pressure, particle loading, and product yield measurements. After validation of the code, parametric studies were performed on various parameters such ...
Passive films, formed on annealed and cold worked AISI 304 stainless steel in hot chloride media, were examined using polarization resistance and impedance measurements. The obtained results show the influence of cold work on film conductivity, which can be correlated to conditions of susceptibility to stress corrosion cracking. Capacitance measurements, using the Mott-Schottky approach, revealed that a change from n to p type semi-conductivity is associated to susceptible conditions with an increase in the doping density estimated for cold worked samples in the presence of chloride. It is assumed that p-type semi-conductivity of the passive film together with the position of the flat band potential has a strong influence on the dissolution processes at the corrosion potential. Based on this analysis the influence of plastic deformation, at the dislocation scale, is discussed. (authors)
Upon request by the Science and Technology Agency of Japanese Government, the Japan Atomic Energy Research Institute has conducted Piping Reliability Test Program to demonstrate the safety and reliability of light water reactor primary pipings. In this report, the results of the program are summarized. In the test program, pipe fatigue tests, Leak-Before-Break (LBB) verification tests and pipe rupture tests were carried out to examine the integrity of pipings, to verify the LBB concept and to demonstrate the effectiveness of the protective measures against jet impingement and pipe whip under pipe rupture event, respectively. In the pipe fatigue tests, a procedure to predict the fatigue crack growth was developed and the integrity of piping during plant service life was demonstrated. In the LBB verification tests, pipe fracture tests and leak rate tests were performed using cracked pipes. Based on the test results, LBB in the primary pipings was ...
In principle four different methods (ultrasound, microwaves, {gamma}-radiation and x-rays) are available for the non-destructive testing of refractories. Three of these methods, i.e. ultrasound, microwaves and {gamma}-radiation, are in use by different producers of AZS materials to carry out the quality control of their products. This paper will compare the three methods on the basis of the physical properties, present the existing devices, and show the advantages as well as the limits of the different methods. {gamma}-radiography, the oldest method in use, has one main disadvantage, which is the requirement of protection against radioactive radiation. Furthermore, while cracks and cavities can be detected with this method, structural changes can not be monitored. Therefore, the ultrasonic method was developed that allows to detect variations of porosity and grain size as well as cracks and voids when the ultrasonic parameters are tuned as well ...
Fatigue-crack growth in air and in aqueous 3.5-percent NaCl as well as fracture toughness are evaluated for the metastable beta-titanium alloy Ti-3Al-8V-6Cr-4Mo-4Zr in various microstructural conditions. Two solution heat treatments (SHT), 800 C and 927 C, were chosen to produce two different grain sizes. Approximately 20 vol pct unrecrystallized beta grains remained after SHT at the lower temperature. Yield stresses were 895 and 850 MPa, respectively. Both simplex and duplex aging treatments were performed for both grain sizes to vary the distribution of alpha precipitates while keeping the yield stress in the range of 1075-1220 MPa for all aged conditions. Unaged material exhibits significantly higher fracture toughness levels than aged material. The unrecrystallized regions were associated with a loss in ductility and toughness. 21 refs.
Localized deformation may play a key role in the underlying mechanism of irradiation assisted stress corrosion cracking (IASCC) in light water reactor core components. In this study, four austenitic alloys, 18Cr8Ni, 15Cr12Ni, 13Cr15Ni and 21Cr32Ni, with different stacking fault energies were irradiated to 1 and 5 dpa at 360 deg. C using 3.2 MeV protons. Interrupted constant extension rate tensile (CERT) tests were conducted in a simulated BWR environment to determine IASCC susceptibility. In order to characterize the localized deformation in slip channels and grain boundaries, parallel CERT experiments were also performed in an argon atmosphere. Results show that the IASCC susceptibility of the tested alloys increases with increasing irradiation dose and decreasing stacking fault energy. IASCC tends to initiate at locations where slip channels intersect grain boundaries. Localized deformation in the form of grain boundary sliding due to the interaction of slip ...
In-reactor testing of bolt-loaded compact tension specimens was performed in 360 C water. New data confirms previous results that high irradiation levels reduce SCC resistance in Alloy X-750. Low boron heats show improved IASCC (irradiation-assisted stress corrosion cracking). Alloy 625 is resistant to IASCC. Microstructural, microchemical, and deformation studies were carried out. Irradiation of X-750 caused significant strengthening and ductility loss associated with formation of cavities and dislocation loops. High irradiation did not cause segregation in X-750. Irradiation of 625 resulted in formation of small dislocation loops and a fine body-centered-orthorhombic phase. The strengthening due to loops and precipitates was apparently offset in 625 by partial dissolution of #gamma# precipitates. Transmutation of boron to helium at grain boundaries, coupled with matrix strengthening, is believed to be responsible for IASCC in X-750, and the absence of these two ...
Dependence of C, N and Nb contents on intergranular corrosion (IGC), strews corrosion cracking (SCC) and mechanical strength of alloy 600 were examined. To evaluate the corrosion resistance of heat affected zone (HAZ), post weld heat treated specimens were used. To evaluate I G C and S C C susceptibility, Ferric Sulfate-Sulfuric Acid Test and High Temperature Water Test were used. Nb is effective as a stabilizer of C. Consequently to prevent corrosion attack on H A Z in high temperature water Nb should be added more than 100 ( % C - 0.005)% and to maintain mechanical strength, Nb should be added more than 3 + 75( %C + %N)%. Modified alloy 600 satisfying above condition was manufactured commercially and its various properties including weldability were confirmed to be excellent.
Machines and structures, such as automobiles are usually subjected to biaxial or three-axial stresses instead of uniaxial stress. However, research on a fatigue failure under multi-axial stress has not been fully presented because such experiments are difficult. To solve this problem, we developed the servo biaxial fatigue-testing machine. In this research, we performed the biaxial fatigue tests of a magnesium alloy in order to clarify the effects from different heat treatments. Magnesium alloy is the lightest in weight among metal materials for structural use. The fatigue characteristics of a magnesium alloy are indispensable in order to create the design which ensures the reliability and the safety of the vehicles especially in long-distance run. The main conclusions are summarized as follows; (1) The mechanical property of magnesium alloy AZ31B falls by heat treatment at low temperature. (2) The crack progress speed becomes quick by the fall of the mechanical ...
Increasingly stringent safety requirements governing the nuclear industry have made it essential to gain in-depth knowledge of the injuriousness of cracking phenomena in auxiliary and secondary nuclear power plant systems, and to devise methods of rapidly evaluating potentially injurious flaws. The Defect Injuriousness Diagnosis and Treatment Package (DIDTP) discussed in this paper was developed by Framatome, a French-based PWR builder, with this goal in mind. A general description is given of the DIDTP, which is made up of tables and nomographs illustrating the injuriousness of flaws liable to be encountered in the most severely loaded regions of plant systems. The basic principles underlying the DIDTP, together with computational methods and application procedure, are detailed. Two practical examples illustrating the use of the diagnostic system are presented, one applied to the main steam line, the other to gate valve wedges. The types of results obtained and ...
A press formability of magnesium alloy sheet cannot be evaluated by only general characteristics in tensile test; tensile strength, elongation n-value and r-value. For example, AZ31-alloy elongates about 20% in room temperature but breaks easily at shallow stage in deep drawing, which is caused by little local elongation (local necking). Crystallographic restriction of slip deformation in this alloy produces high strength, which almost equal to macroscopic fracture strength. In press forming, the bending under high tension requires a large deformability. A great difference in the deformability between AZ31 magnesium alloy and a strain hardened A1100 Aluminum (only 5% in elongation) is shown by static bending test with V-notch. In a rolled plate of AZ31, a crack is produced by stress concentration and propagates with reduced load at all testing temperature up to 453 K. In contrast, the point of notch in A1100 is dulled by local plastic deformation with held load in ...
Stress corrosion cracks have been discovered in Group Distribution Headers (GDH) at the Ignalina and Chernobyl Nuclear Power Plants. This increases the probability that a guillotine pipe break can occur that creates a whipping pipe (GDH) with the potential to damage surrounding structures-i.e. adjacent GDH and its attached piping or adjacent reinforced concrete compartment wall. The GDH is the most important component for reactor safety in case of an accident. Emergency Core Cooling System (ECCS) piping is connected to the GDH piping such that, during an accident, coolant passes from the ECSS into the GDH. Presented in this paper is the transient analysis of a Group Distribution Header following a guillotine break at the blind end of the header. Using a very conservative force loading function, the transient response of a whipping RBMK-1500 GDH along with neighboring concrete walls and pipelines is obtained using finite element methodology. The results of the ...
The newly developed techniques by the Hot Laboratory (JMTR HL) have provided for us the key information on behavior of specimens due to mechanical / physical / chemical / synergistic effects of radiation, stress and water for fission and fusion reactor environment. These techniques are focused on several topics as follows; (1) miniaturized specimen test for the development of fusion reactor materials, (2) slow strain rate tensile testing (SSRT) and crack propagation measuring tests for the study of Irradiation Assisted Stress Corrosion Cracking (IASCC) of core internals of LWR, (3) handling technique on specimens including tritium for the research and development of tritium breeders and neutron multiplier as fusion blanket materials, (4) joining method using the Tungsten Inert Gas (TIG) welding technique for re-assembling of capsule and re-fabrication of specimen and (5) nondestructive evaluation using ultrasonic wave and infrared thermography ...
It was to be investigated why inexplicable cracking occurred in plain stainless austenitic steel pipes of heat exchangers in discrete sites of the inner surface exposed to acid even with anodic corrosion protection, and what countermeasures must be taken. The following materials were investigated: X 6 CrNiTi 18 10 and X 6 CrNiMoTi 17 12 2. The influence of mechanical vibrations on passive film formation and destruction was investigated in unconstrained pipes and pipes constrained at one end in conditions of anodic protection at frequencies of 0 to 160 Hz and temperatures of 98 to 130 degrees Centigrade in 98% sulphuric acid. The authors were unable to reconstruct the cracks observed in practical operation in anodically protected heat exchanger pipes of stainless austenitic steel. (orig./MM). 5 refs., 2 tabs., 71 figs.
The application of the LBB technology to the newly constructed PWRs has been approved in Korea for several high energy systems that can meet rigorous acceptance criteria. The LBB evaluation had been initiated for Yong-Gwang 3 and 4 units (YGN 3 and 4) which are in service, and subsequently performed for Ul-Chin 3 and 4 units (UCN 3 and 4) which are in construction. The LBB application in Korea is based on the USNRC requirements. The LBB evaluation for YGN 3 and 4 is to eliminate the dynamic effects associated with the postulated DEGB from design basis loads as well as to eliminate pipe whip restraints and jet impingement barriers. There were several issues on the application of LBB to the primary coolant loop and the pressurizer surge line. Of concern were material properties of carbon steel for the primary coolant loop, estimation of crack opening area at the pipe-to-nozzle interface considering the asymmetry, and the leakage crack size which ...
Electrochemical noise generated during stress corrosion cracking (SCC) of type 304 stainless steel (UNS S30400) and {alpha}-brass were studied. Noise patterns showed common characteristics (i.e., a quick drop and slow recovery of the potential). The quick drop corresponded to the initiation of localized events where fresh metal was exposed. The slow recovery corresponded to the repassivation process of the exposed bare metal. The potential drop rate and recovery rate were almost constant during the SCC process for a given SCC system. For random noise, rates of potential rise and drop were similar. Frequency of the noise generated during SCC increased with an increase in applied stress. SCC initiation could be monitored and determined according to noise characteristics and distribution. Since the shift of background potentials had an obvious influence on characteristics of power spectrum density (PSD), the direct current (DC) component should be removed before ...
Recently there has been considerable interest in the Cu-ZSM-5 catalysts for the selective reduction of NO by light hydrocarbons for the purpose of atmospheric pollution abatement. Isobutane and n-pentane cracking were studied over Cu zeolite catalysts and these results were compared with their HY analogues at low conversions and at temperatures of 673 K and below. Three forms of the catalysts were used: those reduced in CO at 773 K; those reduced with H[sub 2] at 473 K; and those in the oxidic form (following flushing with He at 773 K). In contrast with an earlier publication, very little difference in activity was found between the two reduced forms of the catalysts did not differ significantly from each other nor from the H-form of the zeolite. They are typical of a Bronsted acid catalysis. The oxidic form of the catalyst produced excess H[sub 2] in increasing amounts with time on stream. This could be quantitatively accounted for by the coking of the catalyst. ...
Transition joints in power plants between ferritic steels and austenitic stainless steels suffer from a mismatch in coefficients of thermal expansion (CTE) and the migration of carbon during service from the ferritic to the austenitic steel. To overcome these, nickel-based consumables are commonly used. The use of a trimetallic combination with an insert piece of intermediate CTE provides for a more effective lowering of thermal stresses. The current work envisages a trimetallic joint involving modified 9Cr-1Mo steel and 316LN austenitic stainless steel as the base materials and Alloy 800 as the intermediate piece. Of the two joints involved, this paper describes the choice of welding consumables for the joint between Alloy 800 and 316LN. Four consumables were examined: 316, 16-8-2, Inconel 82 and Inconel 182. The comparative evaluation was based on hot cracking tests and estimation of mechanical properties and coefficient of thermal expansion. While 16-8-2 ...
Various remedial measures have been tried to lower radon levels in buildings in Uranium City. The methods used are source material removal, passive ventilation of crawl spaces, sub-floor ventilation, complete epoxy coating of the entire basement, sealants for floor-wall joints and cracks in basements, electrostatic precipitators, mechanical ventilation, and sealing and grouting concrete block plenums in basement walls. The type and condition of structures encountered in Uranium City as well as the relative isolation of the town indicate that mechanical ventilation is the most long-term cost-effective method.
In order to investigate the influence of grain boundary cavities on the life time of Alloy 800 H various fatigue tests have been performed at 800/sup 0/C. Cavity formation has been observed only in asymmetrical tests. Compared to the corresponding symmetrical tests, the cyclic life time is shorter. As the cavitation damage increases, the ratio of life times in vacuum and in air steadily decreases from an initial value of 5. In extreme cases it can reach a value close to 1. In this case, cavitation damage dominates over the usual damage mechanism, which is cracks from the surface.