Energy Technology Data Exchange (ETDEWEB)

The liquefaction reaction system of an NEDOL process coal liquefaction 1t/d PSU was opened and checked to investigate the cause of the rise of differential pressure between liquefaction reactors of the PSU. The liquefaction test at a coal concentration of 50 wt% using Tanito Harum coal was conducted, and it was found that the differential pressure between reactors was on the increase. By the two-phase flow pressure loss method, deposition thickness of deposit in pipelines was estimated at 4.4mm at the time of end operation, which agreed with a measuring value obtained from a {gamma} ray. The rise of differential pressure was caused by deposit formation in pipelines connecting reactors. The main component of the deposit is calcite (CaCO3 60-70%) and is the same as the usual one. It is also the same type as the deposit on the reactor wall. Ca in coal ash is concerned with this. To withdraw solid matters deposited in the reactor, there are installed pipelines for the withdrawal at the ...

Energy Technology Data Exchange (ETDEWEB)

In order to realize simultaneous reduction of NO{sub x} and Particulate emissions, effects of combustion chamber geometry were investigated in a high speed direct-injection diesel engine. The reentrant combustion chambers with different throat diameter were compared in terms of engine performance, combustion characteristics and emissions such as NO{sub x}, particulate and THC. The phenomena of combustion process were also observed with endoscopic high speed photography. The results showed that when the throat diameter of a reentrant combustion chamber was reduced to an extent, NO{sub x} and particulate decreased simultaneously due to retarded injection timing and the intensified squish. (author)

Energy Technology Data Exchange (ETDEWEB)

Several proposals have been made on the method of calculating generation of formaldehyde released from plywood. In calculating generation per hour of a volatile organic compound of adhesives or coatings using a chamber method, such models are frequently used that the generation is largest when the specimen is exposed in the chamber and that the generation attenuates with lapse of time. In the meantime, a number of studies for calculating formaldehyde generation from construction materials are often those determining a specific quantity of generation in a stationary state, while few studies are the observation of time series variation from immediately after the exposure into the chamber. Accordingly, the subject studies used lauan plywood as the samples and examined the method of calculating the change with lapse of time of the formaldehyde generation. (translated by NEDO)

Energy Technology Data Exchange (ETDEWEB)

In relation to coal liquefaction reaction, the effect of the coexistence of transferable hydrogen (TH) from process solvent on reduction of radical concentration and the effect of pre-heat treatment on average structure of coals were studied. In experiment, change in radical concentration with temperature rise was measured using the system composed of Yallourn coal and process solvent. The results are as follows. Process solvent with a wide boiling point range of 180-420{degree}C is effective in suppressing an increase in radical concentration even at higher temperature. The effect of hydrogen-donating solvent increases with TH. It was also suggested that high-boiling point constituents in solvent stabilize radicals even over 400{degree}C by vapor phase hydrogenation. The experimental results of pre-heat treatment are as follows. Although the conversion improvement effect of TH is equivalent to that of the model solvent, TH tends to produce soluble products with smaller ring numbers. ...

Energy Technology Data Exchange (ETDEWEB)

Industrial utilization of reaction mechanisms of microorganisms under anaerobic condition permits structuring energy saving type production processes. The present survey has investigated features of new microorganisms under anaerobic condition and the status of researches thereon inside and outside the country, and discussed their future applications. Chapter 1 compares anaerobic microorganisms and functions of microorganism under anaerobic condition with those aerobic to describe their general features, and describes the purpose of this survey and the summary of the investigations. Chapter 2 surveys the current status of technologies to utilize microorganisms under anaerobic condition. Chapter 3 outlines metabolic characteristics of the anaerobic microorganisms, and extracts functions effective for material production by different anaerobic microorganisms to describe their applicability. Chapter 4 evaluates the system classification for the anaerobic microorganisms utilizing the basic ...

Energy Technology Data Exchange (ETDEWEB)

A new characteristics temperature, an adiabatic limit flame temperature, was proposed as the basis to evaluate an effective energy emission and to examine a self combustion limit. Its characteristics were discussed using the reaction system between diatomic molecules as an example, and the low calorific limit of flammability was also discussed. Since the adiabatic limit flame temperature was the inherent temperature of a combustible mixture based on the thermochemical properties of constituents, it was, in particular, very important as considering a combustion system with energy recirculation between products and reactants. The available energy and efficiency of the combustion system should have been estimated on the basis of this temperature, instead of on an adiabatic flame temperature. It was also considerably high even in an extremely lean mixing ratio, however, the flame temperature in a lean region was strongly affected by heat loss in a high temperature region. 13 refs., 8 ...

Energy Technology Data Exchange (ETDEWEB)

Experimental and numerical investigations were performed for the laminar burning velocity and the flame structure of laminar premixed CH{sub 4}/O{sub 2}/CO{sub 2} flames. Measurements of the laminar burning velocity were conducted by using a flame cone angle method for a circular nozzle burner. Numerical simulation was performed using one-dimensional plane flame code including radiation heat loss with an optically thin model. It was shown that the laminar burning velocity decrease with CO{sub 2} addition even though the adiabatic flame temperature is the same as that for CH{sub 4}/Air flames. The radiation heat loss is significant for the CH{sub 4}/O{sub 2}/CO{sub 2}, flames, and the flame temperature and laminar burning velocity decreases when the radiation heat loss is considered. Effects of thermal properties, radiation, and chemical reaction on the determination of the laminar burning velocity of CH{sub 4}/O{sub 2}/CO{sub 2} flames were discussed. (author)

Energy Technology Data Exchange (ETDEWEB)

Experimental investigations are being conducted on a single-cylinder direct-injection diesel engine to examine the effects of combustion chamber specifications and swirl ratios on the heat release and transient heat transfer characteristics. Heat rejection was examined on the basis of heat release calculations using cylinder pressure time histories. Transient surface temperature data obtained from stationary locations in the piston and cylinder head were used as the basis for determining the transient heat flux rates. The results showed good agreement with the heat rejection calculated from cylinder pressure data and that transient heat flux in a piston cavity was reduced with the larger cavity diameter and a higher swirl ratio. On the other hand, a transient heat flux in a piston head was not changed by the cavity diameter and swirl ratio. 5 refs., 19 figs.

Energy Technology Data Exchange (ETDEWEB)

Process solvent was hydrogenated in the brown coal liquefaction, to investigate the influence of it on the prethermal treatment and liquefaction. Consequently, it was found that the n-hexane soluble (HS) yield was improved. In this study, capacity of hydrogen transfer from solvent during prethermal treatment and effects of catalyst were investigated. Since prethermal treatment in oil was effective for improving the oil yield in the presence of hydrogen/catalyst or high hydrogen-donor solvent, influence of hydrogen-donor performance of solvent or addition of catalyst on the hydrogenation behavior of coal and the characteristics of products during prethermal treatment were investigated in relation to successive liquefaction results. As a result, it was found that the increase of HS yield was due to the acceleration of conversion of THF-insoluble using high hydrogen-donor solvent and/or by adding catalyst. It was also found that the use of high hydrogen-donor solvent and highly active ...

Energy Technology Data Exchange (ETDEWEB)

Study was made on the city bus driven by the series hybrid system composed of a small ceramic gas turbine (100kW), generator and lead storage battery. Two driving modes were adopted, 10-driving mode and real driving mode assuming a certain bus route in Tokyo. The motor is driven mainly by generated power and additionally by battery power, however, the engine/generator system is controlled at an optimum operation point (driving mode and regenerating mode) with a maximum thermal efficiency considering depth of discharge. Design voltage of the battery had nearly no effect on fuel consumption, while its capacity as large as possible was desirable unless its weight has an adverse effect on the system. The real driving mode was lower in fuel consumption by 39% than the 10-driving mode. Since real fuel consumption is largely affected by recovery rate of regenerable energy, the operation point of the motor should be optimized according to driving mode. Fuel consumption at the real bus driving ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to acquire fundamental knowledge about the factors for production and the physical properties of boards when wood powder is used as the main material and powder adhesive is used as the binder in the formation of wood boards under heat and pressure. The effects of temperature for pressing, specific gravity of board, and the ratio of adhesive on bending strength, internal binding force, and size and stability against moisture are investigated. The temperature behavior at the central area of boards under heat and pressure shows similar tendency of stagnation near 140degC which increases thereafter irrespective of the temperature of the hot plate in this experiment. The bending property increases linearly when the resin content is low, and shows the tendency of leveling off gradually when the resin content is larger than 20%. Linear relation with specific gravity if obtained in the 0.6 to 1.0 specific gravity range. Wood powder boards have high internal size ...

Energy Technology Data Exchange (ETDEWEB)

With respect to concept of resolution in seismic exploration using the reflection method, detailed considerations were given on processes of forming the resolution as a result of arranging observation points at vibration transmitting and receiving points. In the discussion, numerical experiments were carried out, in which the scattering stacking process is applied in a model having one scatterer existing in homogeneous media. The experiments investigated an imaging formation process of the scatterer when arrangement of the vibration transmitting and receiving points were changed from a coarse condition to a dense condition while the number of transmitting and receiving points is being increased. Resolution is created if waveforms having finite frequencies are used as input, and the imaging is performed by utilizing the limited number of vibration receiving and transmitting points. If the concept of equi-travel plane is used under these conditions, the equi-travel planes perform ...

Energy Technology Data Exchange (ETDEWEB)

In order to clarify the alkali-resistance of fibers to be utilized as reinforcing materials for concrete, such as glass fiber, Aramid fiber, and carbon fiber, accelerated aging tests in alkaline solution were conducted. In detail, the degree of degradation of the fracture strength and Young's modulus were investigated through static tensile strength tests after soaking in alkaline solution of these fibers and then the mechanism of degradation was examined by observation using a scanning electron microscope. The conclusion obtained was as follows. Glass fiber was easily degraded in the alkaline solution and the progress of degradation was simulated quantitatively by the method proposed in this paper, which was based on a diffusion theory. Both Aramid fiber and carbon fiber showed a significant alkali-resistance without degrading. The reaction of glass fiber with alkaline solution proceeded uniformly from the surface of glass fiber into the inner direction with passage of time. ...

Energy Technology Data Exchange (ETDEWEB)

The thermal contact resistance between balls and inner and outer rings of thermally steady space-use deep groove ball bearings was studied experimentally to verify the validity of the previously proposed calculation method for the resistance. The 440C stainless steel single row bearing was used for measuring its steady state temperature distributions in a vacuum environment under axial, radial and combined load conditions. As a result, the experimental results of the resistance well agreed with calculated ones under each load condition resulting in the sufficient validity at nearly the same surface roughness. It was necessary to apply a static equivalent radial load to calculation under the combined load that a contact angle is larger than the angle of resultant force dependent on both load components. In experiments under only radial load, measurement of outer ring temperatures was necessary at some points with no contact with balls to avoid the under estimation of the resistance. 8 ...

Energy Technology Data Exchange (ETDEWEB)

Authors already reported the integrated system so called SODAS (System Of Design and Assembling for Shipbuilding) which was based on product model concept. And products in shipbuilding industry today are not limited to ship structures alone. Therefore, it is desirable that a more global product model which can describe another products such as offshore structures should be considered. In this paper, a product model of offshore structures is discussed. Compared with the case of ship structures, the distinctive feature in the design stage of offshore structures lies in the initial design stage. Thus in this paper, some of the new model in initial design stage are introduced. Some of them are `Function Element Model` which expresses functional concept by designers. In the other design stage, product information such as `Room` and `Part` which were already introduced in SODAS are used effectively for a product model of offshore structures. By the use of product information such as ...

Energy Technology Data Exchange (ETDEWEB)

Investigations and studies are conducted seeking for a CO2 fixation method improved by utilizing the photosynthesizing function of higher vegetation. Details of higher vegetation genes are being disclosed thanks to the rapid progress of studies making use of molecular biological techniques, and the application of the genetic mechanism to scientific and technological fields is becoming increasingly feasible. In particular, the role of the CO2 fixation enzyme RuBisCO has been elucidated almost completely. It has been learned that, in terms of photosynthesizing capability, the C{sub 4} plants (corn etc.) are 2-3 times higher than the C{sub 3} plants (rice, wheat, etc.), and 5-10 times higher than the CAM plants (cactuses etc.). Studies are also under way about the rice genome so that a photosynthesizing capability so high as that of the C{sub 4} plants may be endowed the rice plant. The metabolism and control of useful substances produced in the CO2 fixation process etc. in the higher ...

Energy Technology Data Exchange (ETDEWEB)

Effect of water injection/draining on elastic waves penetrating through cracks is examined by measuring elastic waves before, during, and after the injection/draining of water into/from cracks in presence in granite. Two blocks of rock, with their crack-containing surfaces in contact with each other, are placed in a vessel, and water injection/draining is done through a hole on a vessel bottom side so that water will penetrate into the cracks. When the blocks are dry, there is almost no contact between the cracks, and so no crack penetrating waves are observed. Crack penetrating waves are produced when water is injected, and the position of the receiver sensing the penetrating waves changes as the water level rises. When the water level is lowered from the high water level, the waveform changes again as the level changes. The change in waveform is not so remarkable, however, as that observed during water injection thanks to the water residual in the cracks. It is now inferred that ...

Energy Technology Data Exchange (ETDEWEB)

A geothermal heat pump-assisted heating system is introduced into Changchun City and a survey is conducted to determine if the system may be popularized in this extremely cold region located in the northeastern part of China. In concrete terms, the hot water that circulates through the office building of Changchun Ground Heat Development Co., Ltd., is switched to hot water prepared by a geothermal heat pump. The test continued from December 2000 to March 2001. It is then concluded that heating by geothermal heat pumps will be fully serviceable to Changchun City. Implemented are (1) the shift from the coal fired boiler system to a geothermal heat pump system comprising 16 subterranean heat exchangers for the heating of the office building which is approximately 1000 m{sup 2} large, (2) long-term monitoring of the operating conditions, (3) measurement of subterranean heat exchanger thermal conductivity and subterranean temperature, and (4) the study of pipe shapes for improved thermal ...

British Library Electronic Table of Contents (United Kingdom)

The percolated or active triple phase boundary (TPB) length per unit volume of Ni-YSZ anode hollow fibers (HFs) containing 60wt.% initial NiO and a spatially varying microstructure were measured using a focused ion beam (FIB)-SEM technique. The measured values of contiguous TPB density were interfaced with a 2-D distributed finite element model of a hollow fiber solid oxide fuel cell. The model was applied to simultaneously solve the ionic and electronic charge balances in the electrodes, which were modelled as overlying continuum materials with effective electronic and ionic conductivities. The model was used to predict the effects of anode microstructure on the distribution of current density, and anode activation polarization. Active TPB lengths of 2.63-8.63 m^-^2 were measured for the ...

Energy Technology Data Exchange (ETDEWEB)

Described herein are the results of the FY1994 research program for structural defects of silicon-based amorphous materials for solar cells. The study on light generation defects of the a-Si:H system and rejuvenation process by annealing establishes the effects of light irradiation time on changed neutral dangling bond density as a result of light irradiation at varying temperature of 77K, room temperature and 393K. The study on annealing to rejuvenate light generation defects of various types of a-Si-H systems establishes the activation energy distribution with respect to annealing to remove light-induced defects, showing that hydrogen affects the distribution of light-induced defects. The study on decaying process of light-induced ESR for undoped and N-doped a-Si:H systems observes the decaying process of light-induced ESR, after light is cut off, extending for a period of several seconds to several hours at 77K for the a-Si-H systems containing N in a range from 0 to 12at%. The ...

Energy Technology Data Exchange (ETDEWEB)

The influence of (%MgO) and (%T.Fe) in slug on the corrosion resistance of Al{sub 2}O{sub 3}-C brick was studied at 1,550-1,800{degree}C to apply it to the post combustion zone of an in-bath smelting reduction furnace. The wear rate of the brick was affected strongly by temperature decreasing to 1 2-2 3 for every temperature reduction of 100{degree}C, and it was also more affected by (%T.Fe) than (%MgO) in slug at every temperature. The observation of brick microstructures by reflecting microscopy revealed the preceding wear of a carbon matrix. Based on the consideration that the growth of degraded structures by decarburization also contributes to movement of Al{sub 2}O{sub 3} clinkers, the wear rate equation of the Al{sub 2}O{sub 3}-C brick was derived taking into account not only elution of Al{sub 2}O{sub 3} clinkers into slug but oxidation and decarburization of the carbon matrix in oxidation atmosphere at high temperature, resulting in the good agreement between calculated and ...

Energy Technology Data Exchange (ETDEWEB)

What utilizes the effect of electrohydrodynamical technique (EHD), as one of heat transfer augmentation methods, is methodically frequented and partially prepared to be put to practical use. Then, the heat transfer augmentation effect on nucleate boiling, utilizing the EHD effect, was both experimentally and theoretically studied from both the applicative and basic viewpoints. By adding fleon with 2wt% ethyl alcohol, higher in electric conductivity, in order to have the mitigation time of electric charge correspond to the bubbling frequency of bubble, the heat transfer augmentation was enabled to be about 8.5 times as high as that without impressing the electric field. As a result of observing the behavior of bubble in the electric field, was observed a phenomenon of bubble, moving from place to place, without ascending, on the plane electrode plate, by which could be found one of causes of the heat transfer augmentation. From analyzing the electric field around the bubble, it was ...

International Nuclear Information System (INIS)

A zirconium alloy comprising from 0.8 to 1.6wt% of Sn, from 0.17 to 0.25wt% of Fe, from 0.15 to 0.25wt% of Cr and from 0.01 to 0.08wt% of Ni and Si at a concentration of 120ppm or lower as an impurity and the balance of Zr is melted into cast pieces and then subjected to an #beta# annealing. It is controlled so as to satisfy Fe + Cr + Ni #<=# 0.52wt%. Then, rolling and annealing are applied so that the total heat injection amount #SIGMA#A_i to the materials is within a range of from 1 x 10"-"1"9 to 1 x 10"-"1"7. #SIGMA#A_i = #SIGMA#t_i #centre dot# exp(-Q/RT_i), in which t_i represents processing time (hour) at an ith heat treatment step after the #beta# annealing, T_i represents a processing temperature (K) in the step i. Q represents an activating energy, R represents a gas constant, and Q/R 40,000. (I.N.).

Energy Technology Data Exchange (ETDEWEB)

The overall objective of this research work was to prepare hydrocracking catalysts using amorphous silica-alumina (ASA) supports in combination with USY and {beta}-zeolites. Three supports: namely silica-alumina, USY and {beta}-zeolites were selected to prepare the extrudates using AP-1 as a binder, while two metal pairs: namely Ni-W and Ni-Mo were loaded on the extrudates through co-impregnation using incipient wetness technique. The catalysts were then calcined at 550C for 2h. The catalysts were tested in a fixed-bed flow reaction system for their activity, using desulfurized vacuum gas oil (DS-VGO) as a feedstock. The catalytic evaluation results of the catalysts showed that {beta}-zeolite alone and in combination with the ASA used in this study, has a potential as a support for developing heavy oil hydrocracking catalysts. A balance of weak and strong acidities of {beta}-zeolite provides control cracking, while high ...

Energy Technology Data Exchange (ETDEWEB)

In this work a comprehensive metallophysical study was carried out for two aluminosilicide slip coatings of the systems Al-Si and Al-Nb-Si and an electron-beam Co-Cr-Al-Y coating on alloy EP-539 (17...19% Cr, 4...6% Co, 2.5...4% W, 4.5...6.5% Mo, 2...3% Ti, 3...4% Al, 1.4...2% Nb, balance Ni) after high-temperature testing. The protective properties of the coatings were evaluated from the results of laboratory tests for heat resistance at 1000/sup 0/C in the combustion products of diesel fuel with added sulfur at 970, 1000, and 1060/sup 0/C for 100 h and after full-scale tests for 150, 250, 400, and 700 h. Metallographic, hardness, x-ray, and micro x-ray studies of the coating were carried out. Layer-by-layer phase composition and the lattice spacing of the main phases were determined. X-ray analysis was carried out in an a DRON-1 diffractometer in copper K/sub ..-->../-radiation, and x-ray microanalysis was carried out in a MS-46 Cameca ...

International Nuclear Information System (INIS)

The corrosion resistance of zircaloy is affected by conditions of heat treatment in the manufacturing steps to be formed into a final product as a structural material. In the manufacturing method of the present invention, a Zr alloy controlled to contain Sn: 0.8 to 1.2wt%, Fe: 0.17 to 0.28wt%, Cr: 0.05 to 0.15wt%, Ni: 0.04 to 0.10wt%, Nb: 0.01 to 0.09wt%, oxygen: 1,000 to 1,500ppm and Si, an Si impurity at a concentration of 120ppm or less and balance of Zr is melted into a cast piece, to which #beta# hardening is applied. Then, rolling and annealing treatment are applied so that the total heat input amount to the material: #SIGMA#Ai ranges from 1 x 10"-"1"9 to 1 x 10"-"1"7. With such procedures, a Zr alloy structural material for a reactor core having excellent homogeneous corrosion resistance and hydrogen absorption resistance for a long period of time while having a sufficient strength can be obtained even in a case where Sn content is ...

UK PubMed Central (United Kingdom)

Ten subjects balanced their own body or a mechanically equivalent unstable inverted pendulum by hand, through a compliant spring linkage. Their balancing process was always characterized by repeated...Full Text Available

KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

A virtual balancing axis arrangement is described for multi-cylinder reciprocating piston machines for effectively balancing out imbalanced forces and minimizing residual imbalance moments acting on the crankshaft of such machines without requiring the use of additional parallel-arrayed balancing shafts or complex and expensive gear arrangements. The novel virtual balancing axis arrangement is capable of being designed into multi-cylinder reciprocating piston and crankshaft machines for substantially reducing vibrations induced during operation of such machines with only minimal number of additional component parts. Some of the required component parts may be available from parts already required for operation of auxiliary equipment, such as oil and water pumps used in certain types of reciprocating piston and crankshaft machine so that by appropriate location and dimensioning in accordance with the ...

Energy Technology Data Exchange (ETDEWEB)

The exchange charge model of crystal field theory has been used to analyze systematically the ground state absorption spectra of octahedrally coordinated Ni{sup 2+} ion in isostructural nickel halide crystals NiCl{sub 2}, NiBr{sub 2}, and NiI{sub 2}. The parameters of the crystal field acting on the Ni{sup 2+} ion are calculated from the available crystal structure data. The obtained energy level schemes are compared with experimental absorption spectra; a good agreement with experimental data is demonstrated. Dependencies of the crystal field invariants and covalence effects on the type of ligands are considered. It is shown numerically that the overlap effects between Ni{sup 2+} ion and ligands increase with an increase of the ligands' atomic number resulting in the following order of the degree of covalence: NiI{sub ...

UK PubMed Central (United Kingdom)

Disposable nappies (diapers) have been satisfactorily demineralized and used for the collection of excreta from infants and young children during mineral and trace metal balances. It was possible to...Full Text Available

Science.gov (United States)

Ghil, M., B. Shkoller, and V. Yangarber, 1977: A balanced diagnostic system compatible with a barotropic prognostic model. M. Weather. Rev. , 105, 1223- 1238, ...

Energy Technology Data Exchange (ETDEWEB)

Provides standardized energy balance sheets expressed in a common unit of tons of oil equivalent for all OECD countries as well as the regions: OECD total, IEA, North America, Pacific, OECD Europe, EEC and Yugoslavia.

Science.gov (United States)

... 036[0598:DMBRSP]2.0.CO;2 Dendrochronological Mass Balance Reconstruction, Strathcona Provincial Park, Vancouver Island, British ...

Science.gov (United States)

based sensors, and a host of other scientific ... and change the balance between incoming and outgoing energy. ..... have launched on a larger rocket, flown in ...

International Nuclear Information System (INIS)

The hydrogen evolution reaction (HER) was studied on bare brass (B), nickel coated brass (B/Ni), nickel-zinc alloy coated brass (B/NiZn, leached Zn), nickel (under layer)/nickel-zinc alloy coated (top layer) brass electrodes (B/Ni/NiZn, leached Zn) in 1 M NaOH solution using electrolysis, cathodic polarization and electrochemical impedance spectroscopy (EIS) techniques. Long term tests were performed in order to evaluate the electrocatalytic activity and corrosion performance of the prepared electrodes with operation time. The results showed that leached electrodes, especially B/Ni/NiZn electrode, have a smaller overpotential than the others and a good electrocatalytic activity for the HER. Its electrocatalytic activity is also stable over electrolysis time. Contrary to the HER performance, B/NiZn cannot provide an adequate corrosion protection. However, when a thin ...

International Nuclear Information System (INIS)

The size distributions of precipitated Ni clusters on the surface of a LaNi_5-based alloy immersed in alkaline solution (alkaline treatment) at 383 K for 0-110 min were precisely determined by combining superparamagnetic analysis and transmission electron microscopy (TEM) observations. The superparamagnetic analysis indicated that the diameters of the Ni clusters were smaller than #approx#25 nm in all samples, while their average values increased approximately from 5 to 9 nm with increasing alkaline treatment time. The spatial distribution of the Ni clusters was successively observed by TEM, which agreed fairly well with the estimated size distribution by superparamagnetic analysis. Therefore, estimation of the actual size distribution of Ni clusters by superparamagnetic analysis was proved to be feasible. Based on the above results, a precipitation process for ...

Energy Technology Data Exchange (ETDEWEB)

Composite particles represented as TiV{sub 2.1}Ni{sub 0.3}-Raney Ni(R) were prepared by ball-milling a TiV{sub 2.1}Ni{sub 0.3} alloy with Raney Ni in the presence of 0.01 M sodium hypophosphite (NaH{sub 2}PO{sub 2}) aqueous solution as a reducing agent. The composite particles had different morphology from original TiV{sub 2.1}Ni{sub 0.3} alloy particles and TiV{sub 2.1}Ni{sub 0.3}-Raney Ni composite particles prepared by the ball-milling in the absence of the NaH{sub 2}PO{sub 2} aqueous solution. In charge-discharge cycle tests, the TiV{sub 2.1}Ni{sub 0.3}-Raney Ni(R) composite electrode showed the maximum discharge capacity of 620 mAh g{sup -1}, while its cycle durability was similar to the TiV{sub 2.1}Ni{sub 0.3} alloy electrode, which was explained from depth profiles of ...

International Nuclear Information System (INIS)

The rare earth metal rich compounds RE4NiMg (RE=Y, Pr-Nd, Sm, Gd-Tm, Lu) were synthesized from the elements in sealed tantalum tubes in an induction furnace. All compounds were investigated by X-ray diffraction on powders and single crystals: Gd4RhIn type, space group F4-bar 3m, Z=16, a=1367.6(2) pm for Y4NiMg, a=1403.7(3) pm for Pr4NiMg, a=1400.7(1) pm for Nd4NiMg, a=1386.5(2) pm for Sm4NiMg, a=1376.1(2) pm for Gd4NiMg, a=1362.1(1) pm for Tb4NiMg, a=1355.1(2) pm for Dy4NiMg, a=1355.2(1) pm for Ho4NiMg, a=1354.3(2) pm for Er4NiMg, a=1342.9(3) pm for Tm4NiMg, and a=1336.7(3) pm for Lu4NiMg. The nickel atoms have trigonal prismatic rare earth coordination. These NiRE6 prisms are condensed via common edges to a ...

KoreaScience (Korea)

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International Nuclear Information System (INIS)

We present a study of the crystal field in PrNiAl, NdNiAl, ErNiAl and ErCuAl intermetallic compounds based on inelastic neutron spectroscopy. These compounds crystallize in the ZrNiAl-type hexagonal structure with an orthorhombic symmetry on rare-earth sites. The results are compared with the specific-heat data, and the lower parts of the crystal-field energy-level schemes are determined. (orig.)

International Nuclear Information System (INIS)

Rapid self-aggregation of Ni nanodots on Si substrate covered with a thin SiO_2 buffered layer is investigated. The Ni nanodots can hardly self-aggregate on highly heat-dissipated Si substrate with a thermal conductivity of 148 W/m K. Adding a 200-A-thick SiO_2 buffer with an ultralow thermal conductivity of 1.35 W/m K prevents the formation of NiSi_2 compounds, enhances the heat accumulation, and releases the adhesion at Ni/Si interface, which greatly accelerates the self-assembly of Ni nanodots. Dense Ni nanodots with size and density of 30 nm and 7x10"1"0 cm"-"2, respectively, can be formatted after rapid thermal annealing at 850 deg. C for 22 s.

Energy Technology Data Exchange (ETDEWEB)

Spiral orbit tribometry friction tests performed on Ni-rich Ni55Ti45 titanium ball bearings indicate that this alloy is a promising candidate for future aerospace bearing applications. Microstructural characterization of the bearing specimens was performed using transmission electron microscopy and energy dispersive spectroscopy, with NiTi, Ni4Ti3, Ni3Ti, and Ni2Ti4Ox phases identified within the microstructure of the alloy. Density functional theory was applied to predict the electronic structure of the NixTiy phases, including the band structure and site projected density of states. Ultraviolet photoemission spectroscopy was used to verify the density of states results from the density functional theory calculations, with good agreement observed between experiment and theory.

Energy Technology Data Exchange (ETDEWEB)

Calcined and sulfided Ni-Mo catalysts supported on ultrastable Y zeolite (USY), NaY zeolite, mordenite, and ZSM-5 were studied by high-resolution electron transmission microscopy (HRTEM) with selected-area electron diffraction (SAED) and energy-dispersive spectroscopy (EDS). Ni and Mo oxide aggregates were rarely observed in the USY-supported Ni-Mo catalyst, indicating that most of Ni and Mo may be incorporated into USY, e.g., supercavities and possibly sodalite cages. However, there were a large number of {alpha}-NiMoO{sub 4} aggregates of different particle sizes in NaY-, mordenite-, and ZSM-5-supported catalysts, and the mordenite-supported catalyst also contained MoO{sub 3} crystals. The {alpha}-NiMoO{sub 4} may be attached to the surface of substrates as individual particles or needle aggregates, it may be disseminated into mordenite particles, or it may ...

Energy Technology Data Exchange (ETDEWEB)

The present volume provides standardized energy balance sheets expressed in a common unit of tons of oil equivalent for all OECD Countries. It covers the years 1970 to 1982 year by year and includes many revisions and additions to data previously published. The balances in the present volume are based on data published in OECD Energy Statistics 1971-1981 and OECD Energy Statistics 1981-1982. Tables for each OECD Country include production, import, export, consumption by the different industries, transportation, agriculture, residential sector of the different energies: solid fuels, petroleum, gas, nuclear power and hydroelectricity.

UK PubMed Central (United Kingdom)

Patients rely on their primary care physician to manage multiple, often chronic medical conditions that require prescription medications. Balancing the risk to benefit of treatments can be challenging...Full Text Available

Science.gov (United States)

Astron. J., 82, 890-901, doi:10.1086/112143. Ghil, M., B. Shkoller, and V. Yangarber, 1977: A balanced diagnostic system compatible with a barotropic prognostic model....

International Nuclear Information System (INIS)

A new controlled-clearance pressure balance is under development with the aim of improving the hydraulic high-pressure standard up to 1 GPa. This pressure balance consists of three parts: (i) a pressure generation device up to 1 GPa, (ii) a weight-loading unit which can load/unload weights automatically and independently, (iii) a controlled-clearance piston-cylinder which is designed to allow the jacket pressure to be applied independently. Some adjustments were made for loading heavy weights on/off the piston safely, keeping them in balance, then generating the pressure stably. Stability of the generated pressure was checked for several piston-cylinders, and it was found that pressure fluctuation was less than a few parts per million. The jacket pressure coefficient of a 500 MPa controlled-clearance piston-cylinder was precisely evaluated as a function of both the system pressure and the jacket pressure.

KoreaScience (Korea)

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British Library Electronic Table of Contents (United Kingdom)

Aerial deposition of Ni from a refinery in Port Colborne, Ontario, Canada has resulted in the enrichment of 29km2 of land with Ni concentrations exceeding the Canadian Ministry of the Environment's remedial action level of 200mgkg-1. Several studies on these soils have shown that making the soils calcareous was effective at reducing chemically extractable Ni, as well as alleviating Ni phytotoxicity symptoms in vegetable crops grown in the vicinity of the refinery. Conversely, dolomitic limestone additions resulted in increased uptake of Ni in the Ni hyperaccumulator Alyssum murale `Kotodesh', a plant whose use was proposed as a remediation strategy for this area. In this paper we use multiple techniques to directly assess the role soil type and lime treatments play in altering the speciati...

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The intermetallic phase NiAl is a potential material for high-temperature applications; however, its technical application was prevented so far by its high brittleness at room temperature. This problem may be solved by incorporating relatively high-ductility particles into the NiAl matrix. Controlled crack propagation experiments, tensile and pressure tests were carried out in order to analyze the toughness and deformation characteristics of NiAl composite materials containing niobium or molybdenum particles at room temperature and in ambient atmosphere. Both the niobium and the molybdenum particles increase the toughness as compared to the pure NiAl matrix, but no ductilisation was observed in the composite materials investigated. Model experiments in consideration of experimental data suggest, hovewer, that the toughness and ductility of NiAl may be enhanced by optimizing the ...

British Library Electronic Table of Contents (United Kingdom)

Ultrafine grained steels with different carbon contents were produced through warm caliber rolling and evaluated for their stress-strain behavior along with the reduction in area. It was found that the reduction in area-tensile strength balance is far better than the conventional ferrite+pearlite steels and even superior to bainitic steels for all materials tested in the present study.

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The high temperature solid-state reaction between LiNiO{sub 2} and V{sub 2}O{sub 3} (or V{sub 2}O{sub 5}) in air used to prepare LiNiVO{sub 4} has been further studied. This quaternary Li-Ni-V-O reaction is strongly dependent on reaction temperature and lithium stoichiometry in Li{sub x}Ni{sub 2-x}O{sub 2} and has produced a highly crystalline LiNiVO{sub 4} material whose structure has been confirmed to be an inverse spinel by Rietveld analysis with a Bragg R-factor of 1.18 in the absence of crystal orientation preference. The cell performance of LiNiVO{sub 4} prepared at various temperatures or by varying x-values in Li{sub x}Ni{sub 2-x}O{sub 2} has been examined in lithium coin cells and indicated that preparation at low temperatures or when x=0.89 provided an electrode material with higher cell capacity. (orig.)

UK PubMed Central (United Kingdom)

Many patients are currently suffering from nickel (Ni)-induced allergic contact dermatitis (ACD). There have been few Korean studies dealing with the threshold of Ni-induced ACD and quantifying the...Full Text Available

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A new preparation method for LiNiVO{sub 4} has been developed. LiNiVO{sub 4} can be readily obtained from the solid state reaction of LiNiO{sub 2} and V{sub 2}O{sub 3} or V{sub 2}O{sub 5} at 700 C for 2 h in air. The quarternary Li-Ni-V-O reaction is strongly dependent on vanadium starting materials, reaction environment atmosphere, reactant stoichiometry and synthesis temperature. Individual particles of LiNiVO{sub 4} powders are well-formed crystallites shown clearly by scanning electron microscopy results to be in the shape of an octahedron. Powder X-ray diffraction studies of this crystalline material indicate that LiNiVO{sub 4} has an inverse spinel structure different from that of known cathode materials such as LT-LiCoO{sub 2} and LiMn{sub 2}O{sub 4}. The Li/LiNiVO{sub 4} cell can be charged and discharged at about 4.8 V versus ...

International Nuclear Information System (INIS)

... Toshiba Corporation, Isogo Engineering Center, Yokohama, Kanagawa (Japan)

Science.gov (United States)

A calorimeteric method for determining total hemispherical emittance of ... the standard deviation in the total hemispherical emittance value ...

International Nuclear Information System (INIS)

The ZnO nanorods were used as a template to fabricate nickel nanoclusters by electrodeposition. The ZnO nanorod arrays act as a nano-semiconductor electrode for depositing metallic and magnetic nickel nanoclusters. The growth sites of Ni nanoclusters could be controlled by adjusting the applied potential. Under -1.15 V the Ni nanoclusters could be grown on the tips of ZnO nanorods. On increasing the potential to be more negative the ZnO nanorods were covered by Ni nanoclusters. The magnetic properties of the electrodeposited Ni nanoclusters also evolved with the applied potentials.

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Nickel is present in radioactive waste (as activation products {sup 59}Ni and {sup 63}Ni) besides being an element widely distributed in the geosphere and considered for alloys in the engineered barrier systems for underground repositories. For these reasons, within the scope of the OECD Nuclear Energy Agency (NEA) Thermochemical Data Base (TDB) Project a comprehensive review of thermodynamic data has been carried out by the present authors [1]. Over 700 original bibliography sources have been considered, resulting in recommended data for over 50 inorganic species and compounds. Central to the new database are the selections for {delta}{sub f}G{sub m}{sup 0}(Ni{sup 2+}, 298.15 K), established on the basis of re-evaluations of potentiometric data for Ni{sup 2+} | Ni (cr) and S{sub m}{sup 0}(Ni{sup 2+}, 298.15 K) established on the dissolution equilibria for ...

Science.gov (United States)

Resistivity measurements were performed on Fe40 Ni40 B20 and Pd80 Si20 in order to improve the understanding of structural relaxation in amorphous metals. A model describing structural relaxation as a combination of chemical short range ordering (CSRO) an...

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A series of stainless austenitic and ferritic materials was exposed for 100 days to boiling nitric acid which contained no corrosion products; the corrosion rates and depths of the grain boundary attack were observed. - Provided the structure is precipitation-free, the following are suitable for long-term exposure; the austenitic steels X 2 CrNi 19 11, X 1 CrNi 25 21, X 1 CrNiMoN 25 22 2 and X 1 NiCrMoCu 31 27 4, the practically Mo-free and Cu-free development steel X 1 NiCr 31 27, and the highly Mo-alloyed variant X 1 NiCrMoCu 31 27 5. - In the case of alloy NiCr21Mo it is advisable to limit the concentration and/or temperature of the nitric acid. - The 'superferrite' X 1 CrNiMoNb 28 4 2, the Japanese steel X 1 CrNiNb 30 2 and the austenitic steels X 2 CrNiMoN ...

International Nuclear Information System (INIS)

The ErNi_1_- _x Cu _x Al compounds crystallize all in the hexagonal ZrNiAl-type structure. The concentration dependence of lattice constants shows a discontinuity between x=0.5 and 0.6. This structural change has no primary impact on the magnetic order in this series, but influences the crystal field. The lower part of the crystal-field energy-level schemes has been estimated from the specific-heat data.

International Nuclear Information System (INIS)

Heusler films with L2_1 and B2 structure are deposited simultaneously on amorphous carbon films, Si(100) surfaces, and in situ cleaved InAs(110) surfaces by coevaporation of Ni and the alloy MnIn. Morphology, structure, and stoichiometry are investigated with transmission-electron microscopy, electron diffraction, and X-ray spectroscopy. The almost perfect lattice match supports highly oriented growth of Ni_2MnIn on InAs, which is proven by electron diffraction under grazing incidence. The electrical resistivity of thin films on Si show metallic behavior. At temperatures of liquid helium point-contact Andreev reflection spectroscopy is performed on films grown on Si(100) and in situ cleaved InAs(110) surfaces yielding spin polarizations comparable to the ones of Fe, Ni, Co, and permalloy (Ni_8_0Fe_2_0).

British Library Electronic Table of Contents (United Kingdom)

The influence of trace level Ni additions on the eutectic solidification mode of Sn?0.7Cu has been studied using continuous torque experiments during solidification. The solid fraction at which resistance to paddle rotation at the thermal centre of the sample occurs is related to the spatial distribution of solid during solidification. The results indicate that a transition in solidification mode occurs in the range 0?300ppm Ni. Growth occurs antiparallel to heat flow from near the mould walls in the Ni-free alloy, while equiaxed growth from distributed centres dominates in alloys containing at least 300ppm Ni.

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The production of hydrogen from the two-stage pyrolysis-gasification of polypropylene using a Ni/CeO{sub 2}/ZSM-5 catalyst has been investigated. Experiments were conducted on CeO{sub 2} loading, calcination temperature and Ni loading of the Ni/CeO{sub 2}/ZSM-5 catalyst in relation to hydrogen production. The results indicated that with increasing CeO{sub 2} loading from 5 to 30 wt.% for the 10 wt.% Ni/CeO{sub 2}/ZSM-5 catalyst calcined at 750 C, hydrogen concentration in the gas product and the theoretical potential hydrogen production were decreased from 63.0 to 49.8 vol.% and 50.4 to 21.6 wt.%, respectively. In addition, the amount of coke deposited on the catalyst was reduced from 9.5 to 6.2 wt.%. The calcination temperature had little influence on hydrogen production for the catalyst containing 5 wt.% of CeO{sub 2}. However, for the 10 wt.% Ni/CeO{sub 2}/ZSM-5 catalyst with a ...

International Nuclear Information System (INIS)

The occurrence of stable decagonal quasicrystalline phase in Al-Co-Ni and Al-Cu-Co alloys through conventional solidification is well established. Earlier, we have studied the effect of Cu substitution in place of Co in the Al_7_0Co_1_5Ni_1_5 alloy. Here we report the structural/micro-structural changes with substitution of Cu for Ni in rapidly solidified Al-Co-Ni alloys. The melt spun ribbons have been characterized using X-ray diffractometry, scanning and transmission electron microscopy. With an increase in Cu content in the melt spun Al_7_0Co_1_5Cu _xNi_1_5_-_x (x = 0-15 at.%) alloys, the relative amount of the decagonal phase decreased up to 10 at.% of Cu. At this composition, the quaternary alloy showed the co-existence of decagonal quasicrystal and superstructure of #tau#_3 vacancy ordered crystalline phases. The decagonal phase containing Cu showed more disordering than ...

International Nuclear Information System (INIS)

64Cu (T1/2=12.7h, ?- decay: 40%, ?+ decay: 19%, E.C. decay: 41%) is one of the most useful radioisotope in the nuclear medicine due to its multiple decay mode and the intermediate half-life. Several nuclear reaction, i.e., 64Ni(p,n)64Cu, 68Zn(p,?n)64Cu and 64Ni(d,2n)64Cu have been investigated for production. The highest could be obtained with proton irradiation on the enriched 64Ni target. For mass and routine production, the 64Ni target fabrication using electroplating, the reliable chemical separation of 64Cu from the irradiated 64Ni target and the effective recovery process for the recycling of very expensive enriched material ($20,000/g) and so forth are absolutely necessary to be established. In this work, we report our mass production method of 64Cu with 64Ni and Cyclone-30 accelerator

Science.gov (United States)

The purpose of this communication is to determine whether the solubility enhancements for cold-worked Pd-Ni alloys increase or decrease with atom fraction of Ni. Substitutional Ni atoms contract and Pd lattice, in contrast to the lattice expansion resulting from substitutional Ag in Pd. The Pd-Ni alloy system forms a continuous series of fcc solid solution alloys over the whole composition range. The solubility enhancements will also be determined for a series of homogeneous, ternary Pd[sub 1[minus]x]Ni[sub 1/2x]Ag[sub 1/2x] alloys for x in the range from 0 to 0.2. For this series of ternary alloys the fcc lattice parameters do not change significantly from that of pure Pd. The alloys used in this research were purchased from Tanaka Kikinzoku Kogyo K.K. The detailed experimental procedure has been described previously. The alloys were all deformed by cold-rolling ca 90%. Both the ...

British Library Electronic Table of Contents (United Kingdom)

The article examines the limits and challenges small powers face when they adjust to systemic changes. Specifically, this article discusses the Philippines' conduct of a diplomatic strategy of equi balancing between the USA and China. In this strategy, the Philippines enhances and deepens its security relations with its strategic ally, the USA and at the same time, obtains economic assistance and politico diplomatic concessions from East Asia's emergent power, China. The Philippines' diplomatic gambit, however, is restrained by its formal alliance with the USA and its chronic territorial dispute with China over the Spratly Islands. At present, several developments are undermining Manila's efforts in playing this balancing game with Washington and Beijing. These are: the Philippines' passiv...

Energy Technology Data Exchange (ETDEWEB)

Magnetothermal measurements up to 1600 K have been made on alloys in the ternary Ni-Mn-Sb system with a constant ratio Mn/Sb=1/1, to which belong the two ferromagnetic Heusler phases Ni/sub 2/MnSb with L2/sub 1/ structure and NiMnSb with C1/sub b/ structure. The susceptibility-temperature curves show the constitution of the vertical section. At high temperatures the susceptibilities obey a Curie-Weiss law. In the solid state the effective magneton number decreases with increasing Mn concentration from 4.9 (Ni/sub 2/MnSb) to 3.8 (NiMnSb). Simultaneously, on the transition from Ni/sub 2/MnSb to NiMnSb there is a strong increase of the susceptibility and of the Curie temperature from 292 to 686 K. In the heterogeneous range between 10 and 20 at.% Mn another phase part appears which is ferromagnetic at room temperature. By a heat treatment it ...

International Nuclear Information System (INIS)

Minor M (M = Fe, Mn, Cr) additions are widely added to enhance the corrosion resistance of commercial cupronickel alloys. The present paper aims at optimizing the amounts of M in Cu_7_0(Ni,Fe,Mn,Cr)_3_0 (at.%) alloys using a cluster-plus-glue-atom model for stable solid solutions. By this model, it assumed that 1 M atom and 12 Ni atoms formed an M-centered and Ni-surrounded cube-octahedron cluster and the isolated M_1Ni_1_2 clusters are embedded in a Cu matrix, conforming to a cluster formula [M_1Ni_1_2]Cu_3_0_._3 = [M_1_/_1_3Ni_1_2_/_1_3]_3_0Cu_7_0. A structure of this kind satisfies ideally the nearest neighbor requirement, i.e. only M-Ni and Ni-Cu neighbors are allowed and the unfavorable Cu-M pairs are avoided, and hence it describes a stable solid solution structure with good thermal stability. Electrochemical ...

UK PubMed Central (United Kingdom)

During organogenesis, net growth of tissues is determined by a balance between proliferation, hypertrophy, and apoptotic death. Human fetal bladder outflow obstruction is a major cause of end-stage...Full Text Available

UK PubMed Central (United Kingdom)

The ability to enter a hypometabolic state upon restriction of caloric intake is pivotal for animal survival: balancing the energy budget in endotherms can be a real struggle when food is not...Full Text Available

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The authors introduce the above electric car. They deal particularly with the vehicle concept, the energy consumption and the emission balance. (orig.).

Science.gov (United States)

Theoretically, the outcome of World War II in Europe hung in the balance as the Allies poured onto the Normandy beachhead. Following the June 6, 1944 invasion, the Allies continue to come ashore, massively building up men and material inside the beachhead...

UK PubMed Central (United Kingdom)

BackgroundMaintenance of healthy bone requires the balanced activities of osteoclasts (OCs), which resorb bone, and osteoblasts, which build bone. Disproportionate action of OCs...Full Text Available

UK PubMed Central (United Kingdom)

Diamagnetic samples placed in a strong magnetic field and a magnetic field gradient experience a magnetic force. Stable magnetic levitation occurs when the magnetic force exactly counter balances...Full Text Available

UK PubMed Central (United Kingdom)

1. Interactions of pyrazole and ethanol were studied in three laboratory test procedures. They included sleeping time in mice, rotor rod balance in rats and lever pressing behaviour of rats. 2....Full Text Available

UK PubMed Central (United Kingdom)

The importance of a properly functioning and well-balanced immune system for maintaining health has become strikingly evident over the past decades. Roughly since World War II, there has been an apparent...Full Text Available

UK PubMed Central (United Kingdom)

We analyze transport through conical channels due to the difference in particle concentration on the two sides of the membrane. Because of the detailed balance, fluxes of non-interacting particles...Full Text Available

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The report deals with the energy consumption of traffic and its emissions of hazardous substances into the air, and stresses the advantages of the electric car with respect to energy consumption and noise generation. 5 figs., 3 refs.

UK PubMed Central (United Kingdom)

Prophylactic knee braces are designed to prevent and reduce the severity of ligamentous injuries to the knee. Conflicting evidence is reported concerning their efficacy. The purpose of this study was...Full Text Available

UK PubMed Central (United Kingdom)

Modifications of the design and calibration procedure of a diffusion porometer permit determinations of stomatal resistance which agree well with results obtained by leaf energy balance. The energy...Full Text Available

Science.gov (United States)

General balance laws and constitutive relations are developed for convective hydrothermal geothermal reservoirs. A fully interacting rock-fluid system is considered; typical rock-fluid interactions involve momentum and energy transfer, and the dependence ...

UK PubMed Central (United Kingdom)

Carbon dioxide is a waste product of aerobic cellular respiration in all aerobic life forms. PaCO₂ represents the balance between the carbon dioxide produced and that eliminated. Hypocapnia...Full Text Available

UK PubMed Central (United Kingdom)

Adjuvant therapy aims to prevent outgrowth of residual disease but can induce serious side effects. Weighing conflicting treatment effects and communicating this information with patients is not elementary....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

In the 1988 February issue of this magazine the units olf and decipol were introduced. Olf is a measure for the pollution load and decipol for the indoor air quality. This article discusses a new ventilation theory which is quantified by the new indoor air quality thermal comfort balance based on the units olf and decipol. This balance requires more ventilation air than for the present regulations. It takes into account all pollution sources. 2 figs., 9 refs., 3 tabs.

CERN Document Server

We investigate the parametrization issue for discrete-time stable all-pass multivariable systems by means of a Schur algorithm involving a Nudelman interpolation condition. A recursive construction of balanced realizations is associated with it, that possesses a very good numerical behavior. Several atlases of charts or families of local parametrizations are presented and for each atlas a chart selection strategy is proposed. The last one can be viewed as a nice mutual encoding property of lossless functions and turns out to be very efficient. These parametrizations allow for solving optimization problems within the fields of system identification and optimal control.

Science.gov (United States)

Prior to 1978, the Wilsonville Advanced Coal Liquefaction facility material balance surrounded only the thermal liquefaction unit and involved analyses of only the slurry stream and individual gas streams. The distillate solvent yield was determined by difference. Subsequently, several modifications and additional process units were introduced to this single unit system. With the inclusion of the deashing unit in 1978 and the catalytic hydrogenation unit in 1981, the process has evolved into a sophisticated two-stage coal liquefaction process and has the potential for various modes of integration. This report presents an elemental balancing procedure and a simplified presentation format that is sufficiently flexible to meet current and future needs. The development of the elemental balancing technique and the relevant computer programs to handle the calculations have been addressed. This will be useful in modelling ...

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In situ fracture studies on thin-film NiTi intermetallic compounds have been carried out in the high-voltage electron microscope at Argonne National Laboratory. Local stress-induced amorphization of regions directly in front of moving crack tips has been observed under tensile loading conditions. The stress-induced amorphization at crack tips exhibits a temperature dependence similar to that of ion-induced amorphization of NiTi. The upper limiting temperature for stress-induced amorphization is the same as that for ion-induced amorphization of crystalline NiTi and for amorphous phase formation during ion-beam mixing of Ni and Ti multilayer specimens. This upper limiting temperature of 600K is also the lowest temperature at which stress-induced amorphous phase crystallizes during isothermal annealing. This isothermal crystallization temperature is nearly 200K less than the kinetic crystallization ...

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The reactions between (100) GaAs and the near-noble metals Ni, Pd, and Pt have been investigated by application of high-resolution transmission electron microscopy (TEM), energy-dispersive analysis of x rays in the scanning TEM and Rutherford backscattering spectrometry. Emphasis is placed on the evolution of the phase distributions, film compositions, and interface morphologies during annealing at temperatures up to 480 /sup 0/C. The first phase in the Ni/GaAs reaction is shown to have the nominal composition Ni/sub 3/GaAs. Ternary phases of the type Pd/sub x/GaAs are also found to be the dominant products of the Pd/GaAs reaction. Conversely, only binary phases result from the Pt/GaAs reaction. These observations are used to construct isothermal sections of the M--Ga--As thin-film phase diagrams. The behavior of a thin (1--2 nm) native oxide--hydrocarbon layer during the Ni/GaAs, Pd/GaAs, and Pt/GaAs ...

Science.gov (United States)

Hybridization and thermal evolution of the Ni+C{sub 60} composites, deposited on Si(001) at room temperature, were studied using Scanning Electron Microscopy, {mu}-Raman spectroscopy and Rutherford Backscattering. As-deposited, the hybrid films exhibited a granular nano-structure with Ni nano-particles encapsulated in C{sub 60} polymerized rinds. The Ni and C (C{sub 60}) distributions in a top layer were found homogeneous with a stable Ni/C (C{sub 60}) ratio; in the larger depth the distributions were inhomogeneous and their ratio dramatically varied. At elevated temperatures, all structural parameters were changed. In the subsurface layer Ni- and C (C{sub 60})-rich zones were formed (due to the induced phase separation), C{sub 60}-molecules decayed and their fragments were transformed into amorphous carbon (a-C). The free volume distribution of the stressed hybrid matter was ...

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In this work, an attempt was made to develop a novel type of wear-resistant composite employing a TiNi alloy matrix reinforced by hard particles. Titanium carbide was chosen as the reinforcing phase because of its high hardness and TiNi alloy as the matrix due to its pseudoelasticity and good toughness. TiC particles may sustain external load, while the TiNi matrix may accommodate deformation, absorb impact energy and retain the hard particles. Such a combination is expected to lead to an enhanced wear resistance, compared to TiNi alloy. As a matter of fact, some efforts were previously made to develop TiNi-matrix composite reinforced by ceramic particles. However, the emphasis of those studies was put on effects of the reinforcing particles on the phase transformation behavior, shape memory effect and some mechanical properties of the composite; no attempt was made to explore the ...

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A new two-step solid-state process was developed for synthesis of a pure phase 4.7 V LiMn{sub 1.5}Ni{sub 0.5}O{sub 4-{delta}} (LMNO) spinel of good electrochemical properties. This process which was based on formation of stable Ni{sub 1-x}Mn{sub 2}O{sub 4-{delta}} (x {<=} 0.33) spinel followed by subsequent lithiation, demonstrated the emerging of LiMn{sub 1.5}Ni{sub 0.5}O{sub 4-{delta}} frame work at temperatures of as low as 350 C. During this lithiation process, migration of metal ions (Ni/Mn) from partially occupied tetrahedral 8a sites (in Ni{sub 0.67}Mn{sub 2}O{sub 4-{delta}}) toward octahedral 16d site occurred. The resultant spinel material displayed low irreversible loss, a 97% columbic efficiency and 6% loss in discharge capacity after 100 cycles at 60 C. (author)

Energy Technology Data Exchange (ETDEWEB)

Normally, the alloy NiMo28 is used in the solution annealed and quenched condition in which it has a face centred cubic matrix structure. The matrix of the material is supersaturated with molybdenum and, at temperatures above 800 C, has a tendency to form intermetallic precipitates such as the Ni{sub 4}Mo-ordered phase leading to the embrittlement of the NiMo28-ordered phase leading to the embrittlement of the NiMo28 alloy during hot working. For this reason, the aim of these investigations was to optimise the alloy by reducing its tendency to embrittle. The TEM-analyses carried out served to investigate the precipitation of the material as a function of its iron content after ageing at 700 C. The change in hardness and in the lattice constants of the NiMo28-specimens with iron content were also determined. To improve the hot working properties of this material it is recommended ...

International Nuclear Information System (INIS)

The chemical properties of alloys in a given environment are to a large extent governed by the surface composition. Changes of the surface composition during passivation are important features in this respect. Previous studies of single crystal Ni-Mo alloys surfaces have been reported. The aim of this work was to obtain quantitative data, for the natural oxide and the passive films formed on Ni-6% Mo(100) and (110) alloys, using Rutherford backscattering spectroscopy and nuclear reaction analysis. (author).

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Low cycle fatigue (LCF) of a fourth-generation single-crystal (SC) Ni-base superalloy TMS-138 was studied by comparison with a typical third-generation (TMS-75) and a second-generation (CMSX-4) Ni-base SC superalloys. TMS-138 exhibits improved LCF behaviour under a condition of the R ratio of 0 at temperatures of 1073 K and 1173 K. The addition of refractory elements resulted in a remarkable improvement of the LCF properties compared to those of the reference superalloys due to the different microstructure developed in TMS-138. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The half-metallic Heusler alloy Ni{sub 2}MnIn is of high interest for use in spin electronics since at the Ni{sub 2}MnIn/InAs interface a spin polarization of 100% is predicted. We prepare high-quality thin films of 20-60nm thickness by co-evaporation and DC magnetron sputtering. Point-contact Andreev reflection spectroscopy yields a spin polarization of up to 54%. By spectral generalized magneto-optical ellipsometry, the dielectric and magneto-optical properties are determined and ferromagnetic behavior below the Curie temperature T{sub C}=318K is proved.

Energy Technology Data Exchange (ETDEWEB)

Microstructure characterization is important for controlling the quality of laser welding. In the present work, a detailed microstructure characterization by transmission electron microscopy was carried out on the laser welding cast Ni-based superalloy K418 turbo disk and alloy steel 42CrMo shaft and an unambiguous identification of phases in the weldment was accomplished. It was found that there are {gamma}-FeCrNiC austenite solid solution dendrites as the matrix, (Nb, Ti) C type MC carbides, fine and dispersed Ni{sub 3} Al {gamma}' phase as well as Laves particles in the interdendritic region of the seam zone. A brief discussion was given for their existence based on both kinetic and thermodynamic principles.

Energy Technology Data Exchange (ETDEWEB)

Fatigue tests were accomplished with a series of specimens doped with trace elements of a hardened Fe-Ni-Cr alloy, cast and hardened with intermetallic phases for determining the influence of these elements on the high temperature strength properties. The results of extensive fatigue tests show that even small contents of Te, Bi, Se, Pb, Tl and Zn considerably influence the life and creep processes especially after longer running periods, when added individually or combinedly. In contrast to this, the fatigue ductility is reduced by trace element additions even with short running periods. The order in which the metallic trace elements influence the fatigue properties nearly correlates with earlier work concerning Ni- and Co-superalloys. (orig.)

Energy Technology Data Exchange (ETDEWEB)

To study the effect of CuO on the electrochemical properties of MgNi alloy, the MgNi-xCuO (x = 3, 5 and 10 wt%) composites were prepared by ball-milling method. The X-ray diffraction (XRD) analysis showed that the structures of the composites were amorphous. The cycle stability of the composites was improved compared to pure MgNi alloy due to the enhancement of the anti-corrosion property in the alkaline electrolyte, and the composite with 5 wt% CuO ball-milled for 15 h exhibited the best performance. Electrochemical impedance spectroscopy (EIS) and potential-step measurements indicated that the electrochemical kinetics of the composites was improved.

International Nuclear Information System (INIS)

NiMnSb has attracted a great deal of interest as a spin injector/detector in spintronic devices because it has a Curie temperature of 728 K and is predicted to be half-metallic (100% spin polarized). NiMnSb has been reported to have greatly reduced surface polarization, and to lose its half metallicity above 80 K. Here we report the investigation of the surface polarisation and electronic structure of NiMnSb by measurement of the transport spin polarization using point contact Andreev reflection spectroscopy, and anomalous Hall effect in thin films on Si(0 0 1). A comparison to bulk properties is made.

International Nuclear Information System (INIS)

Inert markers (evaporated tungsten and silver) were used in growth studies of silicides formed both by thermal annealing and by ion mixing in the Ni/Si, Pd/Si, and Cr/Si systems. The markers were initially imbedded inside silicides and backscattering spectrometry was used to determine the marker displacement after different processing conditions. The results obtained in thermal annealing are quite consistent with that found in previous investigations. Ni is the dominant diffusing species in Ni_2Si, while Si is the diffusing species in CrSi_2. In Pd_2Si, both Pd and Si are moving species with Pd the faster of the two. In contrast, in growth of silicides by ion irradiation Si is the faster diffusing species in all three systems.

International Nuclear Information System (INIS)

The thickness dependent magnetic properties of artificially prepared ultrathin body-centered cubic Ni films have been explored using the all electron full potential linearized augmented plane wave (FLAPW) method. We have considered two types of BCC Ni(001) films: (i) pure BCC Ni(001) and (ii) Au capped BCC Ni(001) in the range from 1 monolayer (ML) to 4 ML of Au capping coverage. The average magnetic moment of pure BCC Ni(001) is about 0.63 #mu#_B and a typical surface enhancement is found with a magnetic moment of 0.78 #mu#_B. In the presence of an Au capping layer, the magnetic moment of interface Ni is strongly suppressed to approximately 0.5 #mu#_B and this causes a reduction of average magnetic moment. Nevertheless, the Au adlayer has no meaningful induced magnetic moment. The BCC pure Ni(001) films always have in-plane magnetization up ...

International Nuclear Information System (INIS)

Using the full potential linearized augmented plane wave (FLAPW) method, the magnetic properties of two-dimensional Ru and Rh monolayers (MLs) on a NiAl(001) surface have been investigated. It has been found that free standing one monolayer Ru and Rh films have ferromagnetic ground state with magnetic moments of 2.21 and 1.48 #mu#_B, respectively. The ferromagnetism is still observed even on a Ni terminated NiAl(001) surface, while no magnetic state is found on an Al terminated surface. The calculated magnetic moments of Ru and Rh atoms are 1.56 and 0.88 #mu#_B, respectively. In addition, an induced magnetic moment in surface Ni is observed. It has been found that the free standing Ru film has perpendicular magnetization to the film surface with a magnetocrystalline anisotropy (MCA) energy of 0.66 meV/atom, while an in-plane MCA energy of 0.37 meV/atom is achieved in Rh film. Very interestingly, we find ...

International Nuclear Information System (INIS)

A ternary nickel-base alloy Ni-W-B has been developed for surface corrosion and wear resistance to replace chromium plating, which uses environmentally hazardous solutions. The deposition conditions used an alkaline bath and insoluble anodes. The as-deposited alloy typically contains 40 wt% W and 1 wt% B and has an amorphous or partially amorphous structure. These deposits compare favorably with hexavalent chromium deposits in throwing power, color uniformity, and reflectivity. The corrosion resistance of Ni-W-B alloy was compared with hexavalent chromium and electroless nickel deposits in a variety of acids, including hydrochloric, sulfuric, fluoroboric, and phosphoric. In all cases, best results were obtained with the Ni-W-B deposits.

International Nuclear Information System (INIS)

... parameters magnetic fields magnetic properties magnetization monocrystals

International Nuclear Information System (INIS)

The study of passive films formed on a nickel base alloy type Inconel 600 is performed by capacitance measurements (Mott-Schottky approach). This research is supported by the passivation study of the alloying elements Ni, Cr, Fe and high purity alloys Ni-Cr, Ni-Fe, Ni-Cr-Fe. The results obtained show that the capacitive behaviour of the Inconel 600 in the passive state is similar to that on a p-n heterojunction to which a barrier zone of nickel oxide is added. The individual or combined action of alloying elements on the development of this kind of electronic structure is discussed. (authors). 5 refs., 6 figs.

UK PubMed Central (United Kingdom)

Some acylhydrazine derived ONO donor Schiff bases and their Co(II) and Ni(II) complexes have been prepared having the same metal ion (cation) but different anions. These synthesized metal(II)...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The corrosion and passivation behaviour of bulk polycrystalline martensite Ni{sub 50}Mn{sub 30}Ga{sub 20} and austenite Ni{sub 48}Mn{sub 30}Ga{sub 22} alloys was compared in electrolytes with different pH values. Linear anodic and cyclic potentiodynamic polarisation methods and anodic current transient measurements have been conducted for the alloys and their constituents to analyze free corrosion, anodic dissolution and passive layer formation processes. Electrochemically treated alloy surfaces were characterized with scanning electron microscopy (SEM) and angle-resolved x-ray photoelectron spectroscopy (XPS). The electrochemical response of both alloys is in principal similar and is dominated by the Ni oxidation. In acidic solutions (pH 0.5 and 5) a slightly higher reactivity is detectable for the martensitic alloy which is mainly attributed to enhanced dissolution processes at the multiple twin boundaries. In weakly ...

Energy Technology Data Exchange (ETDEWEB)

The lowest excited level in Ni-like ions, 3d{sup 9}4s {sup 3}D{sub 3}, decays only via a magnetic octupole (M3) decay. They present calculated values of transition wavelengths and rates for ions with 30 {le} Z {le} 100. They have observed this line in Xe{sup 26+}, using the Livermore EBIT-I electron beam ion trap and a microcalorimeter, as well as a high-resolution flat-field grating spectrometer.

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In this work a Ni-based superalloy GMR 235 was investigated. We determined convenient metallographic methods for preparation of bulk metallographic specimens, extraction carbon replicas, transparent metallic foils and minor phase extraction. In addition, the alloy microstructure was characterised using different metallographic techniques. (orig.)

International Nuclear Information System (INIS)

The structural changes attendant on intermartensitic transformation in a Ni-Mg-Ga shape memory alloy are considered using magneto-optical visualization with the help of ferrite-garnet monocrystalline films. It is established that on the intermartensitic transformation the complete reorganization of martensite macrostructure fails. Martensite crystals resulted from the basic transformation change somewhat their sizes on intermartensitic transition. The existence of large-scale labyrinth magnetic domain structure is revealed

International Nuclear Information System (INIS)

K#beta#-to-K#alpha# x-ray intensity ratios of Fe and Ni in pure metals and in Fe_xNi_1_-_x alloys (x=0.20, 0.50, 0.58) exhibiting similar crystalline structure have been measured following excitation by 59.54 keV #gamma# rays from a 200 mCi "2"4"1Am point source to understand why the properties of the Fe_xNi_1_-_x (x=0.2) alloy are distinct from other alloy compositions. The valence electronic structure of Fe and Ni in the samples has been evaluated by comparing the measured K#beta#-to-K#alpha# intensity ratios with the results of multiconfiguration Dirac-Fock calculations. Significant changes in the 3d electron population (with respect to the pure metal) are observed for Fe and Ni for certain alloy compositions. These changes can be explained by assuming rearrangement of electrons between 3d and (4s,4p) band states of the individual metal atoms. It has been found that the valence ...

International Nuclear Information System (INIS)

In order to investigate the role of amorphous SiO2 particles in corrosion and wear resistance of Ni-based metal matrix composite alloying layer, the amorphous nano-SiO2 particles reinforced Ni-based composite alloying layer has been prepared by double glow plasma alloying on AISI 316L stainless steel surface, where Ni/amorphous nano-SiO2 was firstly predeposited by brush plating. The composition and microstructure of the nano-SiO2 particles reinforced Ni-based composite alloying layer were analyzed by using SEM, TEM and XRD. The results indicated that the composite alloying layer consisted of ?-phase and amorphous nano-SiO2 particles, and under alloying temperature (1000 deg. C) condition, the nano-SiO2 particles were uniformly distributed in the alloying layer and still kept the amorphous structure. The corrosion resistance of composite alloying layer was investigated by an electrochemical method in ...

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The hydrogen evolution reaction (HER) was studied on Ni-P{sub x} electrodes containing 8 to 16 weight percent P prepared by potentiostatic deposition. The amount of P in the alloy varied with deposition potential. The activity of the electrodes was dependent on the P concentration, and the formation of a passive film. Cyclic voltametry was used to study the removal of this film. 3 refs.

International Nuclear Information System (INIS)

General corrosion behavior of ALLOY 800 in high temperature water was studied in relation to its surface film structure. The surface film formed in water was found to decrease the corrosion rate of ALLOY 800. This film is composed of Ni ferrite, and can be obtained by oxidation in air or steam. Based on these results, air or steam oxidation treatment to inhibit Ni and Co release of ALLOY 800 into high temperature water is proposed. (author).

International Nuclear Information System (INIS)

Surface analytical studies of high nitrogen austenitic stainless steels exposed to deaerated 0.1M HCl have revealed that nitrogen alloying additions influence the composition of salt layers and the passive film/alloy interface. In this study the authors employ electrochemical techniques and variable angle X-ray Photoelectron Spectroscopy (XPS) to examine the passive films formed on a series of austenitic stainless steels, Fe18Cr8Ni, Fe18Cr8Ni0.2N, Fe20Cr20Ni, Fe20Cr20Ni6Mo and Fe20Cr20Ni6Mo0.2N, in acidic chloride aqueous solution. In addition, several other model alloys, Fe19Cr, Fe19Cr9Ni, Fe19Cr2.5Mo, and Fe19Cr9Ni2.5Mo, were examined before and after electrochemical surface nitriding, a technique proven to have an effect analogous to N alloying. It was shown that nitrogen, nickel and molybdenum additions independently and in certain ...

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence method with Si/Li semiconductor detector and "2"3"8Pu exciting source was used for the determination of Cu, Ni, Zn and Pb in plant samples (Taraxacum officinale) from various localities near the highway D-61 Bratislava-Trnava (SR). (author) 2 refs.; 1 fig.; 1 tab.

Energy Technology Data Exchange (ETDEWEB)

The conductance in ferromagnetic Ni nano-wire is quantized in units of 2e{sup 2}/h in the absence of magnetic field, while the units switch to e{sup 2}/h in the magnetic field. The fractional units of 0.7e{sup 2}/h and 1.4e{sup 2}/h with and without magnetic field appear under the application of high bias-voltage. The spin polarization and bias-voltage play an important role in the electric conduction.

International Nuclear Information System (INIS)

The microstructure, microhardness, corrosion, and wear resistance of d.c.-plated Ni electrodeposits prepared from different types of electrolysing Watts-type baths, without or with organic compounds, ceramic powder - SiC and polymer - polytetrafluoroethylene (PTFE), on Cu substrate, which was subsequently removed from the deposits, were investigated. With the change of the type of bath, the deposit grain size was found to decrease markedly, e.g. deposits with an average grain size of about 50 nm could be produced from the bath containing 45 g/dm"3 Ni"2"+ ions, 5 g/dm"3 SiC, and 20 g/dm"3 PTFE. The surface morphology on the bath side of the electrode-posited Ni or Ni-SiC-PTFE foils was characteristic of the type of bath, and its roughness correlated well with the observed grain size. Microhardness and wear resistance increased with decreasing grain size, as expected. On discussing the factors controlling ...

Energy Technology Data Exchange (ETDEWEB)

Magnetic imaging in the transmission electron microscope (TEM) has been used to examine submicron elements with the aim of discovering down to what element size complex domain patterns can form. The elements were squares, circles, triangles, and pentagons in the size range 100{endash}500 nm and were made from 36 nm Co films or 8 nm Ni{sub 80}Fe{sub 20} (NiFe) with in-plane magnetization. The magnetic domain structures in these elements were imaged at high resolution using the differential phase contrast imaging mode in a TEM. Nonuniform magnetization structures were seen in the images. Vortices were present at remanence in all shapes of 36-nm-thick Co elements down to 100 nm size and in circular NiFe elements down to 116 nm diameter. Triangular NiFe elements did not have a vortex state at remanence, instead the magnetization curved round within the element but did not achieve complete flux closure. In ...

Energy Technology Data Exchange (ETDEWEB)

The geometrical and chemical effects of cerium (Ce) addition to Ni-Cr anode electrode in molten carbonate fuel cells (MCFCs) were investigated by measuring the fractal dimensions and wettability of four types of anode electrode with Ce added up to 5 wt.%. In addition, their cell performances were investigated through a single cell operation test and their results were explained based on the wettability of the anode electrodes. The addition of Ce to the anode electrode increased the fractal dimensions and wettabilities of the electrodes. Despite the even larger electrical resistivity of Ce compared to that of Ni and Cr, the electrical resistances of the Ce-added anode electrodes were slightly increased with increasing level of Ce addition. This might be ascribed to the greater wettability of the Ce-added anode electrode that enhanced the cell performance. Therefore, the greater wettability of the Ce-added anode electrode might compensate for its ...

British Library Electronic Table of Contents (United Kingdom)

The main drawback of Ni/YSZ anode supports for solid oxide fuel cell application is their low tolerance to reducing and oxidizing (RedOx) atmosphere changes, owing to the Ni/NiO volume variation. This work describes a structured approach based on design of experiments for optimizing the microstructure for RedOx stability enhancement. A full factorial hypercube design and the response surface methodology are applied with the variables and their variation range defined as: (1) NiO proportion (40-60wt% of the ceramic powders), (2) pore-former proportion (0-30wt% corresponding to 0-64vol.%), (3) NiO particle size (0.5-8mm) and (4) 8YSZ particle size (0.6-9mm). To obtain quadratic response models, 25 different compositions were prepared forming a central composite design. The measured responses...

Energy Technology Data Exchange (ETDEWEB)

The study of passive films formed on a nickel base alloy type Inconel 600 is performed by capacitance measurements (Mott-Schottky approach). This research is supported by the passivation study of the alloying elements Ni, Cr, Fe and high purity alloys Ni-Cr, Ni-Fe, Ni-Cr-Fe. The results obtained show that the capacitive behaviour of the Inconel 600 in the passive state is similar to that on a p-n heterojunction to which a barrier zone of nickel oxide is added. The individual or combined action of alloying elements on the development of this kind of electronic structure is discussed. (authors). 5 refs., 6 figs.

Energy Technology Data Exchange (ETDEWEB)

Commercially available melter technologies were tested during 1994-95 as part of a multiphase program to test candidate technologies for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of Hanford Site tank wastes. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. Various feed material samples, product glass samples, and process offgas streams were characterized to provide data for evaluation of process decontamination factors and material mass balances for each vitrification technology. This report describes the melter mass balance evaluations and results for six of the Phase 1 LLW melter vendor demonstration tests.

International Nuclear Information System (INIS)

The heavy dependence on nuclear power eventually raise the issues of an efficient utilization of uranium resources, which Korea presently imports from abroad, end of a spent fuel storage. From the viewpoint that sodium-cooled fast Reactors (SFRs) have the potential of an enhanced safety by utilizing inherent safety characteristics, trans-uranics (TRU) reduction and resolving the spent fuel storage problems through a proliferation-resistant actinide recycling. SFRs are sure to be most promising nuclear power operation. The Korea Atomic Energy Research Institute (KAERI) has been developing SFR design technologies since 1997. And nowadays, the preliminary heat balance of the demonstration SFR is calculated. However, in order to verify design condition of the NSSS, it is necessary to set the heat balance and the conceptual design for BOP of the SFR as a part of the SFR design technique development business. Moreover, in order to confirm whether the ...

International Nuclear Information System (INIS)

It has been previously stated that the minimum physiological recommendations for the indispensable amino acids in health adults, as proposed by FAO/WHO/UNU in 1985, are far too low, except for the methionine. An amino acid stable isotopic kinetic study was conducted to seek further experimental support to this hypothesis. Twenty healthy young men received an l-amino acid based diet, supplying 140 mg N.kg"-"1.d"-"1, patterned on egg protein for 1 week, then for 3 weeks either i) a pattern based on current international recommendations (FAO diet, n=7), ii) a the tentative Laboratory of Human Nutrition of the Massachusetts Institute of Technology, new amino acid recommendation pattern (MIT diet, n=7) or iii) again the egg hen pattern (EGG diet, n=6). All subjects were again studied for one final, consecutive week of the egg diet. At the end of the initial week, at the first and third week with the three experimental diets,and after three days following the return of the egg diet, an 8 h ...

British Library Electronic Table of Contents (United Kingdom)

This presentation deals with innovation in teaching and understanding of thermodynamic principles. Key features of the approach being advocated are: (a) postulation of the existence of entropy, (b) explicitly associating energy transfers with other transports, (c) stating the 2nd Law in terms of Gibbs' available-energy, (d) systematic use of software such as EES. The paper outlines and elaborates upon an introductory course. Major headings in the course are: basic concepts: properties, additive properties and balances, primitive properties, energy, 1st Law. entropy, elementary academic applications of balances, available-energy, second law, exergy, thermostatic property relations, EES. Applications to processes, fluid flow, Heat transfer, thermochemical. Applications to devices, single-pro...

DEFF Research Database (Denmark)

We study the spike statistics of neurons in a network with dynamically balanced excitation and inhibition. Our model, intended to represent a generic cortical column, comprises randomly connected excitatory and inhibitory leaky integrate-and-fire neurons, driven by excitatory input from an external population. The high connectivity permits a mean field description in which synaptic currents can be treated as gaussian noise, the mean and autocorrelation function of which are calculated self-consistently from the firing statistics of single model neurons. Within this description, a wide range of Fano factors is possible. We find that the irregularity of spike trains is controlled mainly by the strength of the synapses relative to the difference between the firing threshold and the postfiring reset level of the membrane potential. For moderately strong synapses, we find spike statistics very similar to those observed in primary visual cortex.

British Library Electronic Table of Contents (United Kingdom)

When withdrawing a fluid sample (for additional chromatographic analyses) from an apparatus operated at a reduced pressure, a typical syringe proves to be ineffective (even if it is equipped with a gas tight plunger). It simply does not create enough pressure differential to remove a fluid sample from a reduced pressure environment. We encountered such a situation as part of efforts to extend the operation of the advanced distillation curve protocol to reduced pressures. The problem was solved by the development of a pressure balance syringe that allows reliable and precise sampling from an apparatus operating at sub-ambient pressures. This new device uses an external vacuum source to evacuate a syringe barrel, allowing a user to withdraw fluid samples from environments with pressures as l...

International Nuclear Information System (INIS)

During the 1990's, natural gas was the energy source with the fastest rate of growth in the world energy balance. Nevertheless, recent evolutions of the energy context, in particular in terms of prices, have had a rather strong impact on the progress of the different energy sources penalizing gas a little. Beyond this competition between energies, which may increase, the medium-term perspectives of natural gas development is in keeping with an environment full of uncertainties. This article presents: the world supply and demand prospects for 2010-2015 (impact of high gas prices on other energy sources, occurrence of production constraints, political decisions of producing countries and world gas industry balance), trends on main markets (North America, Europe, Asia-Oceania), and international trade. (J.S.)

Energy Technology Data Exchange (ETDEWEB)

Many of the vulnerabilities to Energy Access, Energy Security, and Environmental Sustainability result from impediments to reaching a global demand-supply balance, as well as local balances, for various energy sources and carriers. Vulnerabilities result from multiple reasons: regional imbalances of energy production and consumption, the bulky character of the majority of energy fuels, the virtual necessity of electricity consumption following its production, among others. To detect and prioritize respective 'bottlenecks' across energy carriers, they have to be measured. In this report, production, consumption, exports, and imports were measured across all major energy carriers for seven key regions of the world for three time frames-2008, 2020, and 2050. Imbalances between production and consumption form bottlenecks in each region.

Energy Technology Data Exchange (ETDEWEB)

The characteristics of the local magnetic shear, a quantity associated with high-mode-number ballooning mode stability, are considered in heliotron/torsatron devices that have a large Shafranov shift. The local magnetic shear is shown to vanish even in the stellarator-like region in which the global magnetic shear is positive. The reason for this is that the degree of the local compression of the poloidal magnetic field on the outer side of the torus, which maintains the toroidal force balance, is reduced in the stellarator-like region of global magnetic shear because the global rotational transform in heliotron/torsatron systems is a radially increasing function. This vanishing of the local magnetic shear is a universal property in heliotron/torsatron systems with a large Shafranov shift since it results from toroidal force balance in the stellarator-like global shear regime that is inherent to such systems.

British Library Electronic Table of Contents (United Kingdom)

Even if there have been efforts to validate remote-sensing-based energy balance models, which provide evapotranspiration (ET) maps over a large spatial scale, few studies have been conducted to validate their performance in Korea. In this study, surface energy balance fluxes including ET were estimated and inter-compared with two different models using the Landsat-5 Thematic Mapper (TM) image over a watershed scale in Korea. While there were larger spatial discrepancies for net radiation, soil heat and sensible heat fluxes on a pixel-by-pixel basis between the two models, relatively smaller spatial discrepancies for the latent heat flux and daily ET were detected. The spatial discrepancies for the daily ET were larger in low topography and dense vegetation ranges. Despite the different par...

British Library Electronic Table of Contents (United Kingdom)

Abstract The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay-rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two-year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 11...

CERN Document Server

Given a double complex $X$ there are spectral sequences with the $E_2$ terms being either H$_I$ (H$_{II}(X))$ or H$_{II}($H$_I (X))$. But if $H_I(X)=H_{II}(X)=0$ both spectral sequences have all their terms 0. This can happen even though there is nonzero (co)homology of interest associated with $X$. This is frequently the case when dealing with Tate (co)homology. So in this situation the spectral sequences may not give any information about the (co)homology of interest. In this article we give a different way of constructing homology groups of $X$ when H$_I(X)=$H$_{II}(X)=0$. With this result we give a new and elementary proof of balance of Tate homology and cohomology.

British Library Electronic Table of Contents (United Kingdom)

This work describes how a general, process-based mass-balance model (CoastMab) for phosphorus for coastal areas may be used as a tool to estimate realistic values of "natural" or preindustrial reference levels of key bioindicators in coastal science, including the Secchi depth, a standard measure of water clarity, the chlorophyll-a concentration, an operational measure of phytoplankton biomass and the concentration of cyanobacteria, a measure of the concentration of harmful algae. The CoastMab-model is an ecosystem model giving monthly predictions to achieve seasonal variations of basin-wide properties. The selected case-study area, the Gulf of Riga, is sensitive to nutrient loading because of its shallowness and low openness towards the Baltic Proper. The morphometry of any coastal area, ...

Energy Technology Data Exchange (ETDEWEB)

Ni catalysts supported on {gamma}-Al{sub 2}O{sub 3}, CeO{sub 2} and CeO{sub 2}-Al{sub 2}O{sub 3} systems were tested for catalytic CO{sub 2} reforming of methane into synthesis gas. Ni/CeO{sub 2}-Al{sub 2}O{sub 3} catalysts showed much better catalytic performance than either CeO{sub 2}- or {gamma}-Al{sub 2}O{sub 3}-supported Ni catalysts. CeO{sub 2} as a support for Ni catalysts produced a strong metal-support interaction (SMSI), which reduced the catalytic activity and carbon deposition. However, CeO{sub 2} had positive effect on catalytic activity, stability, and carbon suppression when used as a promoter in Ni/{gamma}-Al{sub 2}O{sub 3} catalysts for this reaction. A weight loading of 1-5wt% CeO{sub 2} was found to be the optimum. Ni catalysts with CeO{sub 2} promoters reduced the chemical interaction between nickel and support, resulting in an increase in ...

Energy Technology Data Exchange (ETDEWEB)

The particle surface of Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} was modified by AlF{sub 3} as a new coating material to improve the electrochemical properties in the high cutoff voltage of 4.5 V. The AlF{sub 3}-coated Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} showed no difference in the bulk structure compared with the pristine one and the uniform AlF{sub 3} coating layers whose thickness is of about 10 nm covered Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} particles, as confirmed by a transmission electron microscopy. The AlF{sub 3} coating on Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2} particles improved the overall electrochemical properties such as the cyclability, rate capability and thermal stability compared with those of the pristine Li[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]O{sub 2}. Such enhancements were attributed to the presence of the stable AlF{sub 3} layer ...

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of ...

Energy Technology Data Exchange (ETDEWEB)

LiNi{sub 0.8}Co{sub 0.2}O{sub 2} particles from high-power lithium-ion cells were examined to determine material changes that result from accelerated aging tests. X-ray absorption spectroscopy (XAS) and transmission electron microscope (TEM) data indicated a Li{sub x}Ni{sub 1-x}O-type layer on the particle surfaces. The greater thickness on particles from high-power fade cells indicate that these surface layers are a significant contributor to cathode impedance rise observed during cell tests.

International Nuclear Information System (INIS)

He ions incident at grazing angles on Cu(110) and Ni(110) surfaces are neutralised into triplet and singlet states, of which the 3p, 3d and 4d upper states are accessible to optical spectroscopy. In the energy range from 500 eV to 15 keV no significant energy dependence of the relative intensities of singlet and triplet lines was observed for scattering on Cu(110). The intensities from Ni(110) are higher and the singlet to triplet intensity ratio of the 3d to 2p transition is about 6% smaller than that from Cu(110). The results can be explained well by assuming resonant charge capture into excited He and intermediate formation of negative He"- states. (orig.).

International Nuclear Information System (INIS)

The redistribution of implanted As and Sb following metal-silicide formation of Pt, Pd, and Ni has been studied. The phases of the silicides used were PtSi, Pd_2Si, and NiSi. Investigations with Rutherford backscattering analysis showed that after the formation of the silicides, the Sb was always found in the silicide layer near the surface of the samples, whereas PtSi and Pd_2Si caused a partial rejection of As for implanted doses of 2 x 10"1"5 cm"-"2 and higher. No rejection of As was found after the formation of NiSi. The results are discussed in terms of solid solubilities and impurity-metal compound formation. The data presented has implications in the fabrication of Ohmic contacts and the adjustments of the heights of Schottky barriers on silicon.

International Nuclear Information System (INIS)

The effects of addition of 0.17wt%Zr, 0.1wt%Mg and 0.1wt%Co on the mechanical properties of a Cu-1.2wt%Ni-0.2wt%Be alloy have been investigated. Adding Zr, Co or Mg to the Cu-Ni-Be alloy brings about the improvement in strength and stress relaxation property. The Zr, Co or Mg addition decreases the inter-precipitate spacing of #gamma#'' precipitates, resulting in the increase in strength. The higher resistance to the stress relaxation of the Zr- or Co-added alloy is attributed to the lower density of mobile dislocations. The improvement of stress relaxation property by the Mg addition is explained by the viscous glide motion of dislocations dragging Mg atoms, in addition to the lower density of mobile dislocations.

International Nuclear Information System (INIS)

The ground state masses of thirty-nine neutron-rich nuclei from "5"1Ca to "7"2Ni have been measured using the Time-of-Flight Isochronous (TOFI) spectrometer. Eight of these masses have been measured for the first time and thirty-one are remeasurements of neutron-rich nuclei previously reported. Good agreement between these results and a previous TOFI experiment was observed except for the most neutron-rich isotopes of vanadium through iron with the present results being more bound and in better agreement with theory. The low binding energy of "6"8Ni, as indicated by an unreasonably low two-neutron separation energy, suggests the presence of a high-lying, long-lived isomeric state in this nucleus. (orig.).

Energy Technology Data Exchange (ETDEWEB)

We have succeeded in aligning self-assembled structures by using a lithographically defined stripe. The 140 nm wide by 100 nm high SiO{sub 2} strip is shown to guide the assembly of 500 nm latex spheres so that spheres are aligned along the strip and are in registration on either side of the strip. This method can be used to increase long-range ordering in magnetic storage systems without compromising the density. Inverse sphere Ni arrays were made by electrodeposition through the latex template. We also show that the hexagonal symmetry of the resulting inverse sphere Ni arrays can be simulated using the approach presented below.

British Library Electronic Table of Contents (United Kingdom)

We have succeeded in aligning self-assembled structures by using a lithographically defined stripe. The 140nm wide by 100nm high SiO2 strip is shown to guide the assembly of 500nm latex spheres so that spheres are aligned along the strip and are in registration on either side of the strip. This method can be used to increase long-range ordering in magnetic storage systems without compromising the density. Inverse sphere Ni arrays were made by electrodeposition through the latex template. We also show that the hexagonal symmetry of the resulting inverse sphere Ni arrays can be simulated using the approach presented below.

Energy Technology Data Exchange (ETDEWEB)

Stability and decomposition of PtSi, NiSi, and PdSi in contact with single crystal or amorphous Si is examined. PtSi, PdSi and NiSi are thermally stable both with Si, but are unstable in contact with metal film. It is shown that epitaxial Si layers can be obtained using both Pd and Al as metal film and layers can be electrically doped by the addition of a doping layer to the thin film structure prior to the heat treatment or by inclusion of Al atoms so that n/sup +/ and p/sup +/ conductivity can be achieved in the grown epilayer. The effects of impurities, substrate orientation on the growth kinetics are also discussed. (LEW)

Energy Technology Data Exchange (ETDEWEB)

The effect of the composition of multicomponent Zr-Ti-V-Mn-Cr-Ni alloys on their hydrogen-storage capacity and on the rate of electrosorption/desorption hydrogen was investigated under potentiodynamics as well as single-pulse and long-term galvanostatic conditions. The main characteristics of alloys and alloy electrodes were determined by their structural analysis by means of X-ray diffraction and scanning electron microscope, by specific surface area test and by determination of the hydrogen absorption/desorption isotherms in the gas/solid phase system. It was found that only the alloys with a manganese content below a threshold could be used as electrode materials for Ni-MH batteries, whereas the modification of the electrode material by micro-encapsulation of alloy particles should limit the dissolution of manganese from the electrode material in a strong alkaline solution. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Ba, Cd, Cr, Cu, Fe, Ni, Pb and Zn were determined in birch leaves (Folium Betulae), dandelion roots (Radix Taraxacae), hawthorn blossom (Inflorescentia Crataegi) and their infusions by graphite furnace atomic absorption spectrometry (GFAAS) after microwave digestion of plant samples. Infusions were made from herbs according to prescription for patients, provided by the producer of medicine on the package. The results obtained were compared with daily requirements for each element. Results show high content of cadmium in the medicinal plants analyzed. The highest level in infusions was observed for Ni and Zn (over 90% of the total element concentration for Ni and in most cases over 50% for Zn), and the lowest for Cd and Pb. The calculated daily intake of majority of the analyzed elements was very low (under 1% of daily requirements)

CERN Document Server

We present constraints on theoretical models of Type Ia SNe using spatially resolved ASCA X-ray spectroscopy of four galaxy clusters: Abell 496, Abell 2199, Abell 3571 & Perseus. All four clusters have central Fe abundance enhancements and an ensemble of abundance ratios are used to show that most of the Fe in the central regions of the clusters comes from SN Ia. At the center of each cluster, simultaneous analysis of spectra from all ASCA instruments shows that the Ni to Fe abundance ratio (normalized by the solar ratio) is ~ 4. We use the Ni/Fe ratio as a discriminator between SN Ia explosion models: the Ni/Fe ratio of ejecta from the "Convective Deflagration" model W7 is consistent with the observations, while those of "delayed detonation" models are not consistent at the 90% confidence level.

British Library Electronic Table of Contents (United Kingdom)

The Jaduguda U (?Cu?Fe) deposit in the Singhbhum shear zone has been the most productive uranium deposit in India. Pyrite occurs as disseminated grains or in sulphide stringers and veins in the ore zone. Veins, both concordant and discordant to the pervasive foliation, are mineralogically either simple comprising pyrite ? chalcopyrite or complex comprising pyrite + chalcopyrite + pentlandite + millerite. Nickel-sulphide minerals, though fairly common in concordant veins, are very rare in the discordant veins. Pyrite in Ni-sulphide association is commonly replaced by pentlandite at the grain boundary or along micro-cracks. Based on concentrations of Co and Ni, pyrite is classified as: type-A ? high Co (up to 30800?ppm), no/low Ni; type-B ? moderate Co (up to 16500?ppm) and moderate to high ...

Wastenet

... (I still say no to bags though if I can, even if it means the bus driver looks at me funny when I get on balancing a pie and bread roll on top of 18 better-than-half-price recycled toilet rolls - as happened on Tuesday night.) I know some cloth/nylon bags are designed to fold up tightly - either with poppers or a bag to keep them neat - so ...

Science.gov (United States)

The maximum fissile fuel production capacity of three conceptual fusion breeder systems is examined on the basis of the dominant isotopic-balance processes. Compact relationships involving system power output, plasma and energy multiplication, and parameters which describe the fuel cycle and neutron spectrum in the blanket are established. It is found that the fusion breeder, as characterized herein, possesses a substantial fissile fuel breeding capacity the extent of which is governed primarily by the neutron spectrum in the conversion blanket and the break-even condition of the plasma.

Energy Technology Data Exchange (ETDEWEB)

This paper presents the Asian landscape with its regional balances and imbalances and its changes after September 11 and subsequent events. The nuclear posture and the role of nuclear weapons inside the China-India-Pakistan triangle is analyzed with respect to the US non-proliferation policy and its expanding military presence over the Asian continent. (J.S.)

Energy Technology Data Exchange (ETDEWEB)

The fundamental principles of coal gasification are discussed including the reactions, their course and influencing parameters. Said principles are illustrated considering heat balance as well as process performance. Coal gasification processes are presented which are under development on a pilot plant scale or which are approved on an industrial scale.

Energy Technology Data Exchange (ETDEWEB)

This EPRI sponsored report describes factors that influence the selection of drives in process industry. These factors include economics, safety aspects, speed control and the plant steam balance. Since the economics play a key-role in the decision, this report provides a quick way of estimating the economics of replacing steam turbines with electric motors. The tools to carry out economic analyses have been provided in the form of graphs and nomographs for quick estimation.

Wastenet

... News In Practice UK work Key facts & information Mass Balance Projects Resources & Library Technical Area Contacts Site Map Benchmarking solvent waste in the UK furniture manufacturing industry OrganisationBritish Furniture Manufacturers Ltd Project ReportSolvent Waste in Furniture Manufacturing Website: www.bfmenvironment.co.uk Return to list � RSWT | Website Design Quiet Storm Solutions Ltd Please consider upgrading your browser! If you can see this ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to describe instrumentation and control (I C) system improvements at Experimental Breeder Reactor 11 (EBR-11). The improvements are focused on three objectives; to keep the reactor and balance of plant (BOP) I C systems at a high level of reliability, to provide diagnostic systems that can provide accurate information needed for analysis of fuel performance, and to provide systems that will be prototypic of I C systems of the next generation of liquid metal reactor (LMR) plants.

Energy Technology Data Exchange (ETDEWEB)

Water transport in the ionomeric membrane, typically Nafion{reg_sign}, has profound influence on the performance of the polymer electrolyte fuel cell, in terms of internal resistance and overall water balance. In this work, high resolution neutron imaging of the Nafion{reg_sign} membrane is presented in order to measure water content and through-plane gradients in situ under disparate temperature and humidification conditions.

Science.gov (United States)

In November 1998, President Clinton charged the National Bioethics Advisory Commission with the task of conducting a thorough review of the issues associated with human stem cell research, balancing all ethical and medical considerations. The President's ...

Energy Technology Data Exchange (ETDEWEB)

An austenitic alloy having good thermal stability and resistance to sodium corrosion at 700.degree. C. consists essentially of 35-45% nickel 7.5-14% chromium 0.8-3.2% molybdenum 0.3-1.0% silicon 0.2-1.0% manganese 0-0.1% zirconium 2.0-3.5% titanium 1.0-2.0% aluminum 0.02-0.1% carbon 0-0.01% boron and the balance iron.

Energy Technology Data Exchange (ETDEWEB)

The metabolism of organic matter in the coastal regions of the ocean may significantly affect the oceanic carbon budget. This paper describes the high percentage (30%) of oceanic oxidation that occurs in coastal areas and the impact of this metabolism on the carbon cycle and climate of earth. Organic metabolism in the ocean appears to be a source of carbon dioxide release into the atmosphere. Oxidation in the coastal zone is of special interest, as it is likely influenced by anthropogenic activity. Recommendations for future research on this topic are proposed. 129 refs., 2 figs., 6 tabs.

Energy Technology Data Exchange (ETDEWEB)

''Climates of the Oceans'' deals with the atmosphere over the world oceans and provides a treatment not only of the climatic elements such as temperature, pressure, wind, precipitation etc., but also of the circulation of the atmosphere and its changes throughout the year. The connection between sea and overlying air is examined through studies of the water and heat balance. Numerous maps and tables illustrate the elements and their fluctuations over the water and on islands and coasts.

Energy Technology Data Exchange (ETDEWEB)

This work provides an overview of existing plants in Europe and describes the substrates being used. It focuses on the individual farm-scale and community plants, as these are the two main types now being built. It also describes plants currently under construction, especially in Germany and Denmark, where the major efforts are focused. A description of how the technique has developed over the past few years, its current state of development, the motivation and economic balance, and the substrate characteristics, is presented.

Energy Technology Data Exchange (ETDEWEB)

Recently the increase of steam temperature and pressure of power plant is required to enhance the thermal efficiency and reduce the CO{sub 2} emission. For the application to advanced USC (Ultra Super Critical) boiler with steam temperature around 700 C, the application of Ni-based alloy such as Alloy617 will be necessary. A new Ni-based alloy USC141 (20Cr-10Mo-2Ti-Al-bal.Ni) with excellent creep rupture strength and low thermal expansion has been developed by Hitachi Ltd. and Hitachi Metals Ltd. as the candidate material for 700 C USC turbine components. In present work, to investigate the possibility for boiler tube application of USC141, its weldability and high temperature strength properties were experimentally examined. The tested material as solution-treated condition shows higher creep rupture strength than that of Alloy617. GTAW (Gas Tungsten Arc Welding) trials of tubular specimen using NIMONIC263 filler wire were ...

International Nuclear Information System (INIS)

K?-to-K? X-ray intensity ratios of Ti and Ni have been measured in pure metals and in alloys of TixNi1-x (x=0.7, 0.6, 0.5, 0.4 and 0.3) following excitation by 22.69 keV X-rays from a 10 mCi 109Cd radioactive point source. The valence-electron configurations of these metals were determined by corporation of measured K?-to-K? X-ray intensity ratios with the results of multiconfiguration Dirac-Fock calculation for various valence-electron configurations. Valence-electron configurations of 3d-transition metals in alloys indicate significant differences with respect to the pure metals. Our analysis indicates that these differences arise from delocalization and/or charge transfer phenomena in alloys. Namely, the observed change of the valence-electron configurations of metals in alloys can be explained with the transfer of 3d electrons from one element to the other element and/or the rearrangement of electrons between 3d and 4s, 4p states of ...

Energy Technology Data Exchange (ETDEWEB)

Stress corrosion cracking tests in constant extension rate tensile (CERT) and constant load tensile (CLT) tests were conducted on Ni-xCr- 9Fe-yC in Ar, water, and a LiOH-boric acid solution. Cr and C improve the resistance of Ni-base alloys to IG cracking in both Ar and water at 360C. Since creep plays a role in IG cracking, one possible explanation for the role of the environment involves its effect on the creep. Experiments were conducted on the role of C in the deformation behavior and failure mode of Ni-16Cr-9Fe. Constant load experiments were conducted on Ni-16Cr-9Fe to determine if the CLT test is more aggressive than CERT. The electron backscattering technique in a SEM is being developed in order to extend the IG cracking studies to grain sizes typical of commercial alloys, 20-30 microns.

International Nuclear Information System (INIS)

Results of hot cracking on welds with compositions between alloy 800 and AWS ER NiCr 3. Investigation of the influence of Si, Mn, Ti and Al on the hot cracking suscpetibility of the alloy 800. (orig.).

UK PubMed Central (United Kingdom)

BackgroundIt has been reported that the El Niño–Southern Oscillation (ENSO) influences the interannual variation of endemic cholera in Bangladesh. There is increased...Full Text Available

International Nuclear Information System (INIS)

Three new rare earth metal-rich compounds, Gd_6MTe_2 (M=Co, Ni) and Er_6RuTe_2, were synthesized in direct reactions between the R, R_3M, and R_2Te_3 (R=Gd, Er, M=Co, Ni, Ru). These materials all adopt the same Zr_6CoAl_2 structure type with space group P6-bar 2m (No. 189, Z=1). Single crystal structures of Gd_6CoTe_2 and Er_6RuTe_2 were determined and lattice parameters are a=b=8.3799(5), c=3.9801(4) A, and a=b=8.1473(5) A, c=3.9962(4) A, respectively. Gd_6NiTe_2 was characterized by X-ray powder diffraction; lattice parameters are a=b=8.412(2), c=3.9577(9) A. Metal-metal bonding correlations were analyzed using the empirical Pauling bond order concept.

British Library Electronic Table of Contents (United Kingdom)

New Schiff base derivatives (L1 and L2) were prepared by the condensation of 2-hydroxy-3-methoxybenzaldehyde (o-vanillin) and 3-hydroxy-4-methoxybenzaldehyde (iso-vanillin) with 5-methylfurfurylamine. Two new complexes [Ni(L1)2] and [Cu(L1)2] have been synthesized with bidentate NO donor Schiff base ligand (L1). The Ni(II) and Cu(II) atoms in each complex are four coordinated in a square planar geometry. Schiff bases (L1 and L2) and complexes [Ni(L1)2] and [Cu(L1)2] were characterized by elemental analyses, FT-IR, UV-vis, mass and 1H, 13C NMR spectroscopies. The crystal structures of the ligand (L2) and complexes [Ni(L1)2] and [Cu(L1)2] have also been determined by using X-ray crystallographic technique.

International Nuclear Information System (INIS)

Russian 1986. p. 339. USSR Smirnov, AV Antropov, AE Osorio, VF Zarubin,

International Nuclear Information System (INIS)

The service conditions for high-temperature heat-exchangers with helium coolant of HTGRs and requirements imposed on materials for their production are discussed. The choice of nickel-base alloys with solid-solution hardening for long-term service at high temperatures is grounded. Results of study on properties and structure of types Ni-25Cr-5W-5Mo and Ni-20Cr-20W alloy in the temperature range of 900 deg. - 1,000 deg. C are given. The ageing of Ni-25Cr-5W-5Mo alloy at 900 deg. - 950 deg. C results in decreased corrosion-mechanical properties and is caused by the change of structural metal stability. Alloy with 20% tungsten retains a high stability of both structure and properties after prolonged exposure in helium at above temperatures. The alloy has also increased resistance to delayed fracture and low-cycle fatigue at high temperatures. The developed alloy of type Ni-20Cr-20W with microalloying is ...

UK PubMed Central (United Kingdom)

El Niño/Southern Oscillation related climate anomalies were analyzed by using a combination of satellite measurements of elevated sea-surface temperatures and subsequent elevated rainfall and...Full Text Available

International Nuclear Information System (INIS)

We calculate parity-dependent level densities for the even-even isotopes "5"8","6"2","6"6Fe and "5"8Ni and the odd-A nuclei "5"9Ni and "6"5Fe using the shell model Monte Carlo method. We perform these calculations in the complete fp-gds shell-model space using a pairing+quadrupole residual interaction. We find that, due to pairing of identical nucleons, the low-energy spectrum is dominated by positive parity states. Although these pairs break at around the same excitation energy in all nuclei, the energy dependence of the ratio of negative-to-positive parity level densities depends strongly on the particular nucleus of interest. We find equilibration of both parities at noticeably lower excitation energies for the odd-A nuclei "5"9Ni and "6"5Fe than for the neighboring even-even nuclei "5"8Ni and "6"6Fe.

Science.gov (United States)

This study deals with the torsional response of Ti-8823 and 18Ni (200) maraging steel. The effect of different heat treatments and the subsequent change in microstructure are investigated. In the case of the Ti-8823, a comparison was made between the solu...

International Nuclear Information System (INIS)

Fe-Ni-Mn martensitic steels are one of the major groups of ultra-high strength steels that have good mechanical properties and ductility in as annealed condition but they suffer from severe inter-granular embitterment after aging. In this paper, the effect of heavy shaped cold rolling and wire drawing on the mechanical properties of Fe-Ni-Mn steel was investigated. This process could provide a large strain deformation in this alloy. The total strain was #epsilon# #approx#7. Aging behavior and tensile properties of Fe-10Ni-7Mn were studied after aging at 753 K. The results showed that the ultimate tensile strength and ductility after cold rolling, wire drawing and aging increased up to 2540 MPa and 7.1 %, respectively, while the conventional steels show a premature fracture stress of 830 MPa with about zero ductility after aging.

Energy Technology Data Exchange (ETDEWEB)

The phenomenon of the limit of pitting corrosion in direction to positive potentials is studied by potentiokinetic polarization after a jump in the transpassive range and by potentiostatic tests at technical wrought materials and at model alloys of the systems NiCrMo and NiMo in CaCl{sub 2} solution in the concentration range 1 to 9 mol/l chloride at pH-values of 1 to 9 at temperatures of 30 to 110 C. Surface-analytical investigations gives in connection with knowledges from anodic polarization studies directions to the mechanism of the limit of pitting corrosion. Ranges of the limit of pitting corrosion are obtained at materials with a Mo content above 6.5% and contents of chloride of the media above 2 mol/l chloride. Increasing temperatures, increasing contents of chloride and sulfate shift the potential of the limit of pitting corrosion being always above 0.2 V (SCE) at potentiostatic determination to noble direction. There are indications ...

International Nuclear Information System (INIS)

Xe ion irradiation of NiSi, PdSi, and PtSi on Si was performed at various substrate temperatures. The phase formation and mixing behavior of the three monosilicides with their Si substrates are quite different. For NiSi, NiSi_2 was formed on amorphous Si substrates at 350 "0C, while NiSi remained stable on crystalline Si substrates even at 400 "0C. PtSi reacted with Si to form a metastable Pt_4Si_9 phase, which decomposed back to PtSi and Si by successive irradiation at higher temperatures. The decomposition of the metastable Pt_4Si_9 was easier on crystalline Si substrates than on amorphous substrates. No mixing was observed for PdSi on Si in the temperature range of 35--400 "0C. The ion mixing results were compared with those from thermal annealing. The importance of demixing of a thermally stable system was explored.

International Nuclear Information System (INIS)

Systematic analysis of the energy level schemes, ground state absorption (GSA) and covalency effects for the Ni"2"+ ion in Ca_3Sc_2Ge_3O_1_2 was performed. The recently developed first-principles approach to the analysis of the absorption spectra of impurity ions in crystals based on the discrete variational multi-electron method (DV-ME) [K. Ogasawara et al., Phys. Rev. B 64, 115413 (2001)] was used in the calculations. As a result, complete energy level schemes of Ni"2"+ and its absorption spectra at both possible crystallographic positions (distorted octahedral Sc"3"+ and tetrahedral Ge"4"+ positions) were calculated, assigned and compared with experimental data. Energies of the charge transfer (CT) transitions for both positions are estimated. Numerical contributions of all possible electron configurations into the calculated energy states were determined. By performing analysis of the molecular orbitals (MO) population, it was shown that ...