Sample records for antinucleon reactions

  1. Analysis of sensitivity of the reaction cross section and the forward scattering amplitude to the structure of the nuclear optical potential for intermediate-energy nucleons and antinucleons

    Within the framework of the optical model with phenomenological optical potentials describing elastic scattering we calculate the total cross section, the reaction cross section, and the real part of the forward scattering amplitude for nucleons and antinucleons in the energy range 50--200 MeV for a broad range of nuclei. It is shown that with a significantly different spatial dependence of the real part of the optical potential (the Woods-Saxon form and the ''wine-bottle bottom'' form) the real parts of the proton forward scattering amplitude differ from each other by several times, while the difference in the total cross sections and reaction cross sections is not larger than tens of per cent. The calculations are performed in first-order perturbation theory in deviation of the wave function of the incident particle from the eikonal approximation. Comparison of the results of the approximate and exact calculations shows that the error of the approximate approach in the energy range considered is not larger than 10%. We compare our results with the results of calculations of the reaction cross section for antiprotons in light nuclei in the Glauber theory

  2. Nucleon-antinucleon interaction

    The current status of our understanding of the low energy nucleon-antinucleon (N anti N) interaction is reviewed. We compare several phenomenological models which fit the available N anti N cross section data. The more realistic of these models employ an annihilation potential W(r) which is spin, isospin and energy dependent. The microscopic origins for these dependences are discussed in terms of quark rearrangement and annihilation processes. It is argued that the study of N anti N annihilation offers a powerful means of studying quark dynamics at short distances. We also discuss how one may try to isolate coherent meson exchange contributions to the medium and long range part of the N anti N potential. These pieces of the N anti N interaction are calculable via the G-parity transformation from a model for the NN potential; their effects are predicted to be seen in N anti N spin observables, to be measured at LEAR. The possible existence of quasi-stable bound states or resonances of the anti N plus one or more nucleons is discussed, with emphasis on few-body systems. 42 references

  3. Antinucleon nucleon annihilations into two mesons

    We study two aspects of the antinucleon-nucleon annihilation into two mesons (antiNN → M1M2), starting from simple Born diagrams. On one hand, we discuss the possibility of modelling the antiNN optical potential with the box diagrams related to the M1M2 channels. We include the lightest pseudoscalar, scalar and vector mesons with effective coupling constants. Much more channels appear to be needed in order to achieve sensible results. On the other hand, we show that a simple phenomenological optical potential, successfull in reproducing antiNN elastic scattering and total annihilation data can be further used to make predictions on the antiNN → M1M2 processes, which prove to be in good agreement with experiment. We find a lower bound of 17% on the relative contribution of these reactions to the antiNN annihilation. Also, the model favours a rather small effective radius for the nucleon

  4. Antinucleon-nucleus interactions

    Dover, C.B.


    Recent experimental and theoretical results on anti p-nucleus interactions are reviewed. We focus on determinations of the anti p optical potential from elastic scattering, the use of (anti p, anti p') inelastic scattering to reveal aspects of the spin-isospin dependence of N anti N amplitudes, and some puzzling features of (anti p, anti n) charge exchange reactions on nuclei. 47 refs., 7 figs.

  5. Contribution to the study of the antinucleon-nucleon interactions

    A potential for the antinucleon-nucleon system is constructed. It has an imaginary part of very short range, respecting theoretical constraints. This implies a significant dependence on spin and isospin, and also on the energy. The spectrum of resonances is computed using an original method. One state (I=0 jPC=0++) could be easily detected. A model is proposed for a class of inelastic reactions: NantiN #-> # 2 mesons. Using a distorted-wave-Born approximation, comparisons with experiment are made. Finally, we consider some aspects of the atomic pantip system (protonium)

  6. Nucleon-antinucleon interaction from the modified Skyrme model

    We calculate the static nucleon-antinucleon interaction potential from the modified Skyrme model with an additional BμBμ term using the product ansatz. The static properties of the single baryon are improved in the modified Skyrme model. State mixing is taken into account by perturbation theory, which substantially increases the strength of the central attraction. We obtain a long- and mid-range potential which is in qualitative agreement with some phenomenological potentials

  7. Nucleon-antinucleon interaction from the Skyrme model

    We calculate the nucleon-antinucleon static potential in the Skyrme model using the product ansatz and including some finite NC (number of colors) corrections. The mid- and long-range part of the spin-spin and tensor force are mostly correctly given in both isospin channels while the central interaction has insufficient midrange attraction. This is a well-known problem of the product ansatz that should be repaired with better Skyrme dynamics. copyright 1996 The American Physical Society

  8. Nucleon-antinucleon Interaction from the Modified Skyrme Model

    Ding, G J; Ding, Gui-Jun; Yan, Mu-Lin


    We calculate the static nucleon-antinucleon interaction potential from the modified Skyrme model with additional $B^{\\mu}B_{\\mu}$ term using the product ansatz. The static properties of single baryon are improved in the modified Skyrme model. State mixing is taken into account by perturbation theory, which substantially increases the strength of the central attraction. We obtain a long and mid range potential which is in qualitative agreement with some phenomenological potentials.

  9. Nucleon-antinucleon resonance spectrum in a potential model

    Lacombe, M.; Loiseau, B.; Moussallam, B.; Mau, R. Vinh


    We investigate the spectrum of antinucleon-nucleon resonances, using an optical potential we derived recently. An effective method to compute the S-matrix poles is presented. The corresponding phase shifts do not behave as ordinary resonances in the Argand diagram. We show, however, that the poles can be located by extrapolating the phase shifts with the aid of polynomial fits. The annihilation part of our potential is state and energy dependent and of short range. It yields a richer spectrum than that given by a longer ranged annihilation model.

  10. Contribution at the study of nucleon-antinucleon interaction at low energy and at the proton-antiproton transition in two pions or kaons

    This thesis contains a semi-phenomenological study of the Nucleon-Antinucleon interaction at low energy, and in particular of the annihilation of Proton-Antiproton system into two charged pions or kaons. This annihilation reaction is calculated within the DWBA (Distorted-Wave Born-Approximation) formalism: the transition into two mesons is treated as perturbation around the solution computed out of the whole interaction, including elastic forces and absorption. We first review the optical-potential models which describe the Nucleon-Antinucleon scattering in term of meson exchange supplemented by a complex core to simulate the effects of absorption. Those optical potentials provide the initial state for the annihilation reactions. The transition itself is described by mean of two models, a local one and a separable one. As for the local model, the results are generally in good agreement with experimental data, especially for the analyzing power, but the backward hemisphere for annihilation into two kaons cannot be reproduced. The separable model restricts the transition to S and P waves only, but leads rather naturally to an enhancement of the P wave with respect to the S wave, improving the global description of the angular distribution. This P to S ratio is intimately connected to the relative weight of quark annihilation and quark rearrangement diagrams. The true dynamics of those annihilation reactions presumably mixes our two models, with a transition operator being almost local in the high partial waves and nearly separable for the S and the P waves

  11. The signal of $Z^\\pm(4430)$ in nucleon-antinucleon scattering

    Ke, Hong-Wei; Liu, Xiang(Research Center for Hadron and CSR Physics, Lanzhou University and Institute of Modern Physics of CAS, 730000, Lanzhou , China)


    We study the production of $Z^\\pm(4430)$ at a nucleon-antinucleon scattering experiment. Considering the PANDA experiment to be an ideal platform to explore the production of the charmonium and charmonim-like states, we suggest the forthcoming PANDA experiment to pay attention to the production of $Z^\\pm(4430)$.

  12. Heavy ion collisions, the quark-gluon plasma and antinucleon annihilation

    Studies in high energy physics have indicated that nucleon and mesons are composed of quarks confined in bags by the strong colours mediated by gluons. It is reasonably expected that at suitably high baryon density and temperature of the nucleus, these bags of nucleon and mesons fuse into a big bag of quarks or gluons i.e. hadronic matter undergoes transition to a quark-gluon phase. Two techniques to achieve this transition in a laboratory are: (1) collision of two heavy nuclei, and (2) annihilation of antinucleons and antinuclei in nuclear matter. Theoretical studies as well as experimental studies associated with the transition to quark-gluon phase are reviewed. (author)

  13. KNO scaling in isospin-connected reactions

    The generation of correct KNO scaling is presented. It permits one to describe the multiplicity distributions of both π+ and π- mesons in different nucleon-nucleon and nonannihilation antinucleon-nucleon interactions by the same scaling function Ψ(z) and the same energy dependence of the scale parameters. Multiplicity distributions in different antinucleon-nucleon annihilation reactions are described by another function Ψ(z). In this case the slope of the scale-parameter energy dependence is about 1.5 times greater than for nucleon-nucleon interaction

  14. Analysis of sensitivity of cross section and zero-angle scattering amplitude to structure of nuclear optical potential for intermediate energy nucleons and antinucleons

    Total cross section, reaction cross section and the real of the forward scattering amplitude for nucleons and antinucleons in the energy range from 50 to 200 MeV are calculated for a wide set of nuclei by means of the optical model with phenomenological optical potentials which describe the elastic scattering. It is shown that for substantialy different radial dependences of the part of the optical potential (the Woods-Saxon potential and the ''wine-bottle'' potential) the real parts of the proton forward scattering amplitude are different by a factor of several times, while the differences in the total cross sections and in the reaction cross sections do not exceed a few dozen percent. The calculations have been performed in the first order of the perturbation theory in a deviation of the incident particle wave function from the eikonal approximation. A comparison between the results of the aproximate and exact calculations shows that in the considered energy region an error of the approximation does not exceed 10%. The results have been compared with the Glauber theory for the antiproton reaction cross sections on light nuclei

  15. Something, but not much follows from the quark line rule in nucleon-antinucleon annihilations

    Validity and consequences of the quark line rule (QLR) in nucleon(N)-antinucleon(anti N)annihilations into two or three mesons at LEAR energies are investigated. Recent data on proton-antiproton annihilation into an η or η' together with additional non-strange pseudoscalar or vector meson(s) is used to successfully test the rule. We find that for present data any pseudoscalar meson mixing angle ΦPS restricted to -26deg PS0π0, ηη, π0ρ0, π0ω, ηρ0, ηω, ρ0ρ0, ωω. As a main consequence, dominance of annihilation predicts without any ambiguity equality of the proton-antiproton annihilation cross sections σ(ωω) and σ(ρ0ρ0). Further consequences of dominance of either annihilation or rearrangement diagrams for proton-antiproton annihilation into two or three mesons are also worked out. We compare the predictions of the models we discuss to the sparse present data. It is emphasized that our predictions only exploit the quark flavor flux within the quark line diagrams that are assumed to dominate. They thus are independent of gluon contributions to these diagrams. (orig.)

  16. Coupled-channel analysis of low energy nucleon-antinucleon interactions

    Multichannel M-matrix method is applied to an NN-bar-system with taking into account elastic pp-bar-scattering, charge-exchange pp-bar→nn-bar reaction and pp-bar annihilation. It is shown that contrary to standard assumptions the isotopic invariance due the large influence of the charge exchange channel affects very significantly the parameters of strong interactions. Contrary to previous descriptions, M-matrix elements are treated as real functions. The differential and total cross-sections for pp-bar→pp-bar and pp-bar→nn-bar processes, cross-section δtot(pp-bar) and the real-to-imaginary ratio of the forward amplitude of elastic pp-bar scattering up to beam momenta plab=600 MeV/c are described. The fitting leads to a resonance in the s-wave at about plab=500 MeV/c and to bound states in p-wave near the pp-bar threshold. 33 refs.; 8 figs.; 3 tabs

  17. 有限核真空中的反核子能谱%Spectra of Anti-Nucleons in the Vacuum of Finite Nuclei



    The quantum vacuum in a many-body system of finite nuclei has been investigated within the relativistic Hartree approach which describes the bound states of nucleons and anti-nucleons consistently. The contributions of the Dirac sea to the source terms of the meson-field equations are taken into account up to the one-nucleon loop and one-meson loop. The tensor couplings for the ω- and ρ-meson are included in the model. After adjusting the parameters of the model to the properties of spherical nuclei, a large effective nucleon mass m */MN ≈ 0. 78 is obtained. The overall nucleon spectra of shell-model states are in agreement with the data. The computed anti-nucleon spectra in the vacuum differ about 20-30MeV with and without the tensor-coupling effects.%通过建立能够自洽地描述核子和反核子束缚态的相对论Hartree模型来研究有限核中的量子真空,其中狄拉克海对介子场方程的贡献由单圈图考虑,模型中还引入了ω介子和ρ介子的张量耦合项.在拟合球形核的性质后得到模型的参数,给出核子有效质量为m*/MN≈0.78;计算得到的核子壳模型能级与实验值相一致,在考虑张量耦合项的效应后真空反核子位阱深度增大了20-30 MeV.

  18. The 3rd Nordic meeting on high energy reactions in nuclei

    Abstracts of the 31 lectures given at the meeting are presented. Major emphasis was placed on the nucleon-nucleon and nucleon-antinucleon interaction in bound and unbound systems. Four of the ten sessions were devoted to this subject. Two sessions contained lecture and seminars on 'Isobars in nuclei', two were devoted to hadron-nucleus reactions, one to high-energy heavy-ion reactions and one to new developments of experimental tools. This latter session had two talks, one about channeling with GeV particles and the other about the planned low-energy antiproton facility LEAR at CERN. Talks of more general character were 'The experimental programme at the CERN SC', 'Accelerator produced nuclear fuel' and 'The upsilons, a new family of quark-antiquark bound state'. (JIW)

  19. Exact solution of a model for πd induced reactions and its application to pion-nucleon reactions

    Reduction techniques are applied to πd elastic scattering and π absorption in a theory without anti-nucleons. In the one-pion approximation we derive two sets of exact coupled-channel equations for respectively the amplitudes Tsub(πd,NN), Tsub(NΔ,NN) and Tsub(π,πdsup3) Tsub(πd,NΔ). Alternatively are expressed all amplitudes in terms of the absorption amplitude Tsub(πd,NΔ) and available solutions for a three-body problem restricted to the πd and NΔ channels. It is explicity demonstrated that the model (which comes close to the one of Thomas, Mutzutani and Koltun) strictly respects the Pauli principle and avoids double-counting. Using the same technique amplitudes for the (π,2N) reaction and for π(in) elastic scattering on general nuclei in terms of amplitudes amongst the NN, NNπ channels are determined. Both the elastic amplitude and the πA optical potential are shown to decompose into a multiple scattering part based on an input πN amplitude without the Psub(11) partial wave and calculable absorption corrections. (author)

  20. Nuclear Reactions

    Bertulani, C. A.


    Nuclear reactions generate energy in nuclear reactors, in stars, and are responsible for the existence of all elements heavier than hydrogen in the universe. Nuclear reactions denote reactions between nuclei, and between nuclei and other fundamental particles, such as electrons and photons. A short description of the conservation laws and the definition of basic physical quantities is presented, followed by a more detailed account of specific cases: (a) formation and decay of compound nuclei;...

  1. Quasinuclear resonances and annihilation in nucleon-antinucleon scattering

    The author sketches some of the current problems of the N-anti N system, both in experiment and theory and investigates the general properties like levels, cross sections and amplitudes near the N-anti N threshold given a one boson exchange interaction and using a G-parity transformed non-static potential. A multi-channel N/D formalism is used to calculate the levels and amplitudes and a thorough description of the pole structure near the N-anti N threshold is presented. Based on the results of the model for the N-anti N system, the annihilation of the e+-e- pairs into hadrons is considered and the antipd system is described. (Auth./C.F.)

  2. Nucleon-antinucleon annihilation in chiral soliton model

    We investigate annihilation process of nucleons in chiral soliton model by path integral method. Soliton-antisoliton pair is shown to decay into pions at range of order of about 1 fm, defined by SS-bar potential. Contribution of annihilation channel into elastic scattering is discussed. (author). 14 refs, 1 fig

  3. Low-Energy Antinucleon-Nucleus Interaction Revisited

    Friedman, E


    Annihilation cross sections of antiprotons and antineutrons on the proton between 50 and 400 MeV/c show Coulomb focusing below 200 MeV/c and almost no charge-dependence above 200 MeV/c. Similar comparisons for heavier targets are not possible for lack of overlap between nuclear targets studied with $\\bar p$ and $\\bar n$ beams. Interpolating between $\\bar p$-nucleus annihilation cross sections with the help of an optical potential to compare with $\\bar n$-nucleus annihilation cross sections reveal unexpected features of Coulomb interactions in the latter. Direct comparisons between $\\bar n$-nucleus and $\\bar p$-nucleus annihilations at very low energies could be possible if $\\bar p$ cross sections are measured on the same targets and at the same energies as the available cross sections for $\\bar n$. Such measurements may be feasible in the foreseeable future.

  4. Nucleon-antinucleon annihilation in chiral soliton model

    We investigate annihilation process of nucleons in the chiral soliton model by the path integral method. A soliton-antisoliton pair is shown to decay into mesons at range of about 1fm, defined by the S bar S potential. Contribution of the annihilation channel to the elastic scattering is discussed

  5. The nucleon-antinucleon interaction at low energies

    A theoretical analysis is made of recent low energy data relative to scattering process p sup(-)d → p + pions from 300 to 600 Mev/c laboratory incident momentum, with the purpose of obtaining information about resonances in the pure iso-spin system p sup(-)n (I = 1). The single and double term of the multiple scattering series are evaluated using a formalism based on Glauber theory and Feynman rules. Then, the differential cross section with respect to the invariant mass of the produced pions is obtained. The theoretical results are used to analyse the available data, which are then shown to be consistent with a non resonant behavior of the p sup(-)n system. (Author)

  6. Conference summary: antinucleon- and nucleon-nucleus interactions

    Topics summarized include: the hadronic substructure, the EMC effect, observations on relativity and the Dirac equation, and relativistic Lagrangian field theories for N-N interactions and nuclear matter

  7. Piezonuclear Reactions

    Cardone, Fabio; Petrucci, Andrea


    In this paper, we deal with the subject of piezonuclear reactions, namely nuclear reactions (of new type) triggered by pressure waves. We discuss the experimental evidences obtained in the last two decades, which can be summarized essentially as follows: experiments in cavitation of liquids, where transmutation of elements, creation of elements and emission of neutrons have been observed; emission of neutrons in brittle failure of solids subjected to mechanical pressure; alteration of the lifetime of un unstable element (thorium) subjected to cavitation. A theoretical model to explain these facts is proposed. Future perspectives of these experimental and theoretical investigations are also underlined.

  8. Reaction mechanisms

    The 1988 progress report of the Reaction Mechanisms laboratory (Polytechnic School, France), is presented. The research topics are: the valence bond methods, the radical chemistry, the modelling of the transition states by applying geometric constraints, the long range interactions (ion - molecule) in gaseous phase, the reaction sites in gaseous phase and the mass spectroscopy applications. The points of convergence between the investigations of the mass spectroscopy and the theoretical chemistry teams, as well as the purposes guiding the research programs, are discussed. The published papers, the conferences, the congress communications and the thesis, are also reported

  9. Nuclear reactions

    Nuclear reactions' marks a new development in the study of television as an agency of public policy debate. During the Eighties, nuclear energy became a major international issue. The disasters at Three-mile Island and Chernobyl created a global anxiety about its risks and a new sensitivity to it among politicians and journalists. This book is a case-study into documentary depictions of nuclear energy in television and video programmes and into the interpretations and responses of viewers drawn from many different occupational groupings. How are the complex and specialist arguments about benefit, risk and proof conveyed through the different conventions of commentary, interview and film sequence? What symbolic associations does the visual language of television bring to portrayals of the issue? And how do viewers make sense of various and conflicting accounts, connecting what they see and hear on the screen with their pre-existing knowledge, experience and 'civic' expectations. The authors examine some of the contrasting forms and themes which have been used by programme makers to explain and persuade, and then give a sustained analysis of the nature and sources of viewers' own accounts. 'Nuclear Reactions' inquires into the public meanings surrounding energy and the environment, spelling out in its conclusion some of the implications for future media treatments of this issue. It is also a key contribution to the international literature on 'television knowledge' and the processes of active viewing. (author)

  10. Chain reaction

    Chain Reaction is a work of recent American political history. It seeks to explain how and why America came to depend so heavily on its experts after World War II, how those experts translated that authority into political clout, and why that authority and political discretion declined in the 1970s. The author's research into the internal memoranda of the Atomic Energy Commission substantiates his argument in historical detail. It was not the ravages of American anti-intellectualism, as so many scholars have argued, that brought the experts back down to earth. Rather, their decline can be traced to the very roots of their success after World War II. The need to over-state anticipated results in order to garner public support, incessant professional and bureaucratic specialization, and the sheer proliferation of expertise pushed arcane and insulated debates between experts into public forums at the same time that a broad cross section of political participants found it easier to gain access to their own expertise. These tendencies ultimately undermined the political influence of all experts. (author)

  11. On thermonuclear reaction rates

    Hans J. Haubold; Mathai, Arak Mathai


    Nuclear reactions govern major aspects of the chemical evolution of galaxies and stars. Analytic study of the reaction rates and reaction probability integrals is attempted here. Exact expressions for the reaction rates and reaction probability integrals for nuclear reactions in the cases of nonresonant, modified nonresonant, screened nonresonant and resonant cases are given. These are expressed in terms of H-functions, G-functions and in computable series forms. Computational aspects are als...

  12. The Glyoxal Clock Reaction

    Ealy, Julie B.; Negron, Alexandra Rodriguez; Stephens, Jessica; Stauffer, Rebecca; Furrow, Stanley D.


    Research on the glyoxal clock reaction has led to adaptation of the clock reaction to a general chemistry experiment. This particular reaction is just one of many that used formaldehyde in the past. The kinetics of the glyoxal clock makes the reaction suitable as a general chemistry lab using a Calculator Based Laboratory (CBL) or a LabPro. The…

  13. Practice Gaps: Drug Reactions.

    Wolverton, Stephen E


    The term "drug reactions" is relevant to dermatology in three categories of reactions: cutaneous drug reactions without systemic features, cutaneous drug reactions with systemic features, and systemic drugs prescribed by the dermatologist with systematic adverse effects. This article uses examples from each of these categories to illustrate several important principles central to drug reaction diagnosis and management. The information presented will help clinicians attain the highest possible level of certainty before making clinical decisions. PMID:27363888

  14. Incomplete fusion reactions

    Various aspects of the mechanism of heavy-ion induced reactions in the range of bombarding energies from a few to about 20 MeV/A are reviewed with special emphasis on the reactions for very asymmetric systems. Results of the experimental studies of binary reactions and particularly of the incomplete fusion reactions (selected by means of various coincidence techniques)are discussed. A model of generalized critical angular momentum is formulated. The model explains essential features of the incomplete fusion reactions and predicts that particular reaction channels are localized in well defined regions of angular momenta. An extension of this model (the sum-rule model) is also proposed in attempt to consistently describe the complete fusion reactions, incomplete fusion reactions and multibody reactions in the framework of statistical competition constrained by the angular momentum limitations. (author)

  15. Microfluidic chemical reaction circuits

    Lee, Chung-cheng; Sui, Guodong; Elizarov, Arkadij; Kolb, Hartmuth C.; Huang, Jiang; Heath, James R.; Phelps, Michael E.; Quake, Stephen R.; Tseng, Hsian-rong; Wyatt, Paul; Daridon, Antoine


    New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.

  16. Microscale Thermite Reactions.

    Arnaiz, Francisco J.; Aguado, Rafael; Arnaiz, Susana


    Describes the adaptation of thermite (aluminum with metal oxides) reactions from whole-class demonstrations to student-run micro-reactions. Lists detailed directions and possible variations of the experiment. (WRM)

  17. Anaphylaxis-Like Reactions

    ... be "primed" by previous exposure to cause anaphylaxis, anaphylactoid reactions can occur with no previous exposure at all. ... an X-ray. Although the mechanism of an anaphylactoid reaction is different, the treatment is the same as ...

  18. Common Reactions After Trauma

    ... here Enter ZIP code here Common Reactions After Trauma Public This section is for Veterans, General Public, Family, & Friends Common Reactions After Trauma Available in Spanish: Reacciones Comunes Después de un ...

  19. Preequilibrium Nuclear Reactions

    After a survey on existing experimental data on precompound reactions and a description of preequilibrium reactions, theoretical models and quantum mechanical theories of preequilibrium emission are presented. The 25 papers of this meeting are analyzed separately

  20. Chemical transport reactions

    Schäfer, Harald


    Chemical Transport Reactions focuses on the processes and reactions involved in the transport of solid or liquid substances to form vapor phase reaction products. The publication first offers information on experimental and theoretical principles and the transport of solid substances and its special applications. Discussions focus on calculation of the transport effect of heterogeneous equilibria for a gas motion between equilibrium spaces; transport effect and the thermodynamic quantities of the transport reaction; separation and purification of substances by means of material transport; and

  1. Anaphylactoid reactions to paracetamol

    Ayonrinde, O.; Saker, B.


    The toxic effects of paracetamol in overdose quantities are well recognised but the occurrence of anaphylactoid reactions to paracetamol is infrequently identified by consumers and health care professionals. Nevertheless adverse reactions to this drug, even in therapeutic doses, can have fatal or near fatal consequences. A case of an anaphylactoid reaction to paracetamol is described.

Keywords: paracetamol; anaphylaxis; allergy; hypersensitivity

  2. Sodium concrete reactions

    The data from an extensive series of sodium/concrete reaction tests are presented and mechanisms by which the reactions proceed are analyzed. The results indicate water transport and the resulting sodium/water reaction dominate both the chemical energy release and H2 generation. A mechanism which explains the limited penetration of concrete observed in most of these tests is proposed

  3. Noncanonical Reactions of Flavoenzymes

    Pablo Sobrado


    Full Text Available Enzymes containing flavin cofactors are predominantly involved in redox reactions in numerous cellular processes where the protein environment modulates the chemical reactivity of the flavin to either transfer one or two electrons. Some flavoenzymes catalyze reactions with no net redox change. In these reactions, the protein environment modulates the reactivity of the flavin to perform novel chemistries. Recent mechanistic and structural data supporting novel flavin functionalities in reactions catalyzed by chorismate synthase, type II isopentenyl diphosphate isomerase, UDP-galactopyranose mutase, and alkyl-dihydroxyacetonephosphate synthase are presented in this review. In these enzymes, the flavin plays either a direct role in acid/base reactions or as a nucleophile or electrophile. In addition, the flavin cofactor is proposed to function as a “molecular scaffold” in the formation of UDP-galactofuranose and alkyl-dihydroxyacetonephosphate by forming a covalent adduct with reaction intermediates.

  4. Cosmetic tattoo pigment reaction

    Greywal, Tanya; Cohen, Philip R


    BackgroundCutaneous reactions to tattoos are most commonly granulomatous or lichenoid. PurposeWe describe a woman who developed a lymphocytic reaction following a cosmetic tattoo procedure with black dye. The reaction occurred not only at the site of the tattoos (eyebrows and eyelash lines), but also in non-tattooed skin (bilateral malar cheeks). Methods and MaterialsWe reviewed PubMed for the following terms: cosmetic, dye, granuloma, granulomatous, lichenoid, lymphocytic, ...

  5. Anaphylactic reactions to cinoxacin.

    Stricker, B H; Slagboom, G.; Demaeseneer, R.; Slootmaekers, V.; Thijs, I.; Olsson, S


    During 1981 to mid-1988 three cases of anaphylactic shock after treatment with the quinolone derivative cinoxacin were reviewed by the Netherlands Centre for Monitoring of Adverse Reactions to Drugs and 17 cases of an anaphylactic type of reaction notified to the World Health Organisation Collaborating Centre for International Drug Monitoring. In five out of six patients for whom data were available the reaction began shortly after taking a single capsule of a second or next course of treatme...

  6. Reaction kinetics of polybutylene terephthalate polycondensation reaction

    Darda, P. J.; Hogendoorn, J. A.; Versteeg, G. F.; Souren, F.


    The kinetics of the forward polycondensation reaction of polybutylene terephthalate (PBT) has been investigated using thermogravimetric analysis (TGA). PBT - prepolymer with an initial degree of polymerization of 5.5 was used as starting material. The PBT prepolymer was prepared from dimethyl tereph

  7. Reactions at Solid Surfaces

    Ertl, Gerhard


    Expanding on the ideas first presented in Gerhard Ertl's acclaimed Baker Lectures at Cornell University, Reactions at Solid Surfaces comprises an authoritative, self-contained, book-length introduction to surface reactions for both professional chemists and students alike. Outlining our present understanding of the fundamental processes underlying reactions at solid surfaces, the book provides the reader with a complete view of how chemistry works at surfaces, and how to understand and probe the dynamics of surface reactions. Comparing traditional surface probes with more modern ones, and brin

  8. Desosamine in multicomponent reactions

    Achatz, Sepp; Dömling, Alexander


    Desosamine occurring ubiquitously in natural products is introduced into isocyanide based multicomponent reaction chemistry. Corresponding products are of potential interest for the design of novel antibiotics. © 2006.

  9. Chemical reaction and separation method

    Jansen, J.C.; Kapteijn, F.; Strous, S.A.


    The invention is directed to process for performing a chemical reaction in a reaction mixture, which reaction produces water as by-product, wherein the reaction mixture is in contact with a hydroxy sodalite membrane, through which water produced during the reaction is removed from the reaction mixtu

  10. Clock Reaction: Outreach Attraction

    Carpenter, Yuen-ying; Phillips, Heather A.; Jakubinek, Michael B.


    Chemistry students are often introduced to the concept of reaction rates through demonstrations or laboratory activities involving the well-known iodine clock reaction. For example, a laboratory experiment involving thiosulfate as an iodine scavenger is part of the first-year general chemistry laboratory curriculum at Dalhousie University. With…

  11. Degradations and Rearrangement Reactions

    Zhang, Jianbo

    This section deals with recent reports concerning degradation and rearrangement reactions of free sugars as well as some glycosides. The transformations are classified in chemical and enzymatic ways. In addition, the Maillard reaction will be discussed as an example of degradation and rearrangement transformation and its application in current research in the fields of chemistry and biology.

  12. Hydrogen evolution reaction catalyst

    Subbaraman, Ram; Stamenkovic, Vojislav; Markovic, Nenad; Tripkovic, Dusan


    Systems and methods for a hydrogen evolution reaction catalyst are provided. Electrode material includes a plurality of clusters. The electrode exhibits bifunctionality with respect to the hydrogen evolution reaction. The electrode with clusters exhibits improved performance with respect to the intrinsic material of the electrode absent the clusters.

  13. Reactions of oriented molecules.

    Brooks, P R


    Beams of oriented molecules have been used to directly study geometrical requirements in chemical reactions. These studies have shown that reactivity is much greater in some orientations than others and demonstrated the existence of steric effects. For some reactions portions of the orientation results are in good accord with traditional views of steric hindrance, but for others it is clear that our chemical intuition needs recalibrating. Indeed, the information gained from simultaneously orienting the reactants and observing the scattering angle of the products may lead to new insights about the detailed mechanism of certain reactions. Further work must be done to extend the scope and detail of the studies described here. More detailed information is needed on the CH(3)I reaction and the CF(3)I reaction. The effects of alkyl groups of various sizes and alkali metals of various sizes are of interest. In addition, reactions where a long-lived complex is formed should be studied to see if orientation is important. Finally, it would be of interest to apply the technique to the sort of reactions that led to our interest in the first place: the S(N)2 displacements in alkyl halides where the fascinating Walden inversion occurs. PMID:17793988

  14. Hypersensitivity reactions to corticosteroids.

    Vatti, Rani R; Ali, Fatima; Teuber, Suzanne; Chang, Christopher; Gershwin, M Eric


    Hypersensitivity reactions to corticosteroids (CS) are rare in the general population, but they are not uncommon in high-risk groups such as patients who receive repeated doses of CS. Hypersensitivity reactions to steroids are broadly divided into two categories: immediate reactions, typically occurring within 1 h of drug administration, and non-immediate reactions, which manifest more than an hour after drug administration. The latter group is more common. We reviewed the literature using the search terms "hypersensitivity to steroids, adverse effects of steroids, steroid allergy, allergic contact dermatitis, corticosteroid side effects, and type I hypersensitivity" to identify studies or clinical reports of steroid hypersensitivity. We discuss the prevalence, mechanism, presentation, evaluation, and therapeutic options in corticosteroid hypersensitivity reactions. There is a paucity of literature on corticosteroid allergy, with most reports being case reports. Most reports involve non-systemic application of corticosteroids. Steroid hypersensitivity has been associated with type I IgE-mediated allergy including anaphylaxis. The overall prevalence of type I steroid hypersensitivity is estimated to be 0.3-0.5%. Allergic contact dermatitis (ACD) is the most commonly reported non-immediate hypersensitivity reaction and usually follows topical CS application. Atopic dermatitis and stasis dermatitis of the lower extremities are risk factors for the development of ACD from topical CS. Patients can also develop hypersensitivity reactions to nasal, inhaled, oral, and parenteral CS. A close and detailed evaluation is required for the clinician to confirm the presence of a true hypersensitivity reaction to the suspected drug and choose the safest alternative. Choosing an alternative CS is not only paramount to the patient's safety but also ameliorates the worry of developing an allergic, and potentially fatal, steroid hypersensitivity reaction. This evaluation becomes

  15. The Reaction Wheel Pendulum

    Block, Daniel J; Spong, Mark W


    This monograph describes the Reaction Wheel Pendulum, the newest inverted-pendulum-like device for control education and research. We discuss the history and background of the reaction wheel pendulum and other similar experimental devices. We develop mathematical models of the reaction wheel pendulum in depth, including linear and nonlinear models, and models of the sensors and actuators that are used for feedback control. We treat various aspects of the control problem, from linear control of themotor, to stabilization of the pendulum about an equilibrium configuration using linear control, t

  16. Electron transfer reactions

    Cannon, R D


    Electron Transfer Reactions deals with the mechanisms of electron transfer reactions between metal ions in solution, as well as the electron exchange between atoms or molecules in either the gaseous or solid state. The book is divided into three parts. Part 1 covers the electron transfer between atoms and molecules in the gas state. Part 2 tackles the reaction paths of oxidation states and binuclear intermediates, as well as the mechanisms of electron transfer. Part 3 discusses the theories and models of the electron transfer process; theories and experiments involving bridged electron transfe

  17. Autocatalysis in reaction networks.

    Deshpande, Abhishek; Gopalkrishnan, Manoj


    The persistence conjecture is a long-standing open problem in chemical reaction network theory. It concerns the behavior of solutions to coupled ODE systems that arise from applying mass-action kinetics to a network of chemical reactions. The idea is that if all reactions are reversible in a weak sense, then no species can go extinct. A notion that has been found useful in thinking about persistence is that of "critical siphon." We explore the combinatorics of critical siphons, with a view toward the persistence conjecture. We introduce the notions of "drainable" and "self-replicable" (or autocatalytic) siphons. We show that: Every minimal critical siphon is either drainable or self-replicable; reaction networks without drainable siphons are persistent; and nonautocatalytic weakly reversible networks are persistent. Our results clarify that the difficulties in proving the persistence conjecture are essentially due to competition between drainable and self-replicable siphons. PMID:25245394

  18. Chemisorption And Precipitation Reactions

    The transport and bioavailability of chemical components within soils is, in part, controlled by partitioning between solids and solution. General terms used to describe these partitioning reactions include chemisorption and precipitation. Chemisorption is inclusive of the suit...

  19. Nucleon induced reactions

    The collection contains full texts of 37 contributions; all fall within the INIS Subject Scope. The topics treated include some unsolved problems of nuclear reactions and relevant problems of nuclear structure at low and intermediate energies. (Z.S.)

  20. Allergic reactions in anaesthesia

    Krøigaard, M; Garvey, L H; Menné, T;


    BACKGROUND: The aim of this retrospective survey of possible allergic reactions during anaesthesia was to investigate whether the cause suspected by anaesthetists involved corresponded with the cause found on subsequent investigation in the Danish Anaesthesia Allergy Centre (DAAC). METHODS: Case...... notes and anaesthetic charts from 111 reactions in 107 patients investigated in the DAAC were scrutinized for either suspicions of or warnings against specific substances stated to be the cause of the supposed allergic reaction. RESULTS: In 67 cases, one or more substances were suspected. In 49 of these...... match, the right substance being suspected, but investigations showed an additional allergen or several substances, including the right substance being suspected. CONCLUSIONS: An informed guess is not a reliable way of determining the cause of a supposed allergic reaction during anaesthesia and may put...

  1. Ofloxacin induced hypersensitivity reaction

    Hari Babu Ramineni


    Full Text Available Ofloxacin is a commonly used antimicrobial agent to combat various infections. The adverse profile of quinolones includes gastrointestinal symptoms, which are the most frequent, neuropsychiatric symptoms, hematologic abnormalities are less common. We report a rare case of ofloxacin induced hypersensitivity reaction in a 57 year old female patient with complaints of rashes over the axilla, upper limb and back, abdomen, thorax associated with exfoliation of skin all over the axilla associated with severe itching. Based on history and clinical examination patient was diagnosed as ofloxacin induced hypersensitivity reaction and was successfully treated with antihistamines and corticosteroids. Pharmacovigilance should be a part of patient care in order to reduce occurrence of adverse drug reaction and also encourage practitioners in reporting so as to gather more and more data regarding adverse drug reactions. [Int J Res Med Sci 2015; 3(1.000: 349-351

  2. Adverse reactions to radiopharmaceuticals

    Full text. An adverse reaction can occur following administration of a radio pharmaceutical, but fortunately reactions are uncommon. They are usually mild and do not require intensive treatment. This is probably related to the fact that only small chemical quantities of material are administered to patients and that only one or a small number of doses are administered. Since symptoms are unrelated to any known pharmacology of the agents, they can be described as Type B reactions according to the classification of Rawlings and Thompson. Types of reaction that occur and possible mechanisms will be described. The reactions most commonly observed are skin rashes and vasomotor symptoms. It is important that, as far as possible, a cause - effect relationship can be established between the administration of the radio pharmaceutical and the symptoms caused. Some classification schemes therefore exclude vasomotor reactions such as hypotension and slow pulse, since such events can arise in a variety of clinical situations unrelated to radio pharmaceutical administration. It is important for nuclear medicine departments to be aware of the nature of reactions such that they can be recognized and appropriate re-assurance and/or prompt treatment can be given to their patients. Radio pharmaceuticals most frequently mentioned in reporting schemes are di phosphonates used for bone imaging. This probably reflect the fact that these agents are the most frequently used in current practice rather than that they cause more reactions. Problems in establishing the overall frequency of adverse reactions to radio pharmaceuticals include the fact that events may not be recognized if they occur after the patient has left the Nuclear Medicine Department and that reactions are never reported. Two recent studies have attempted to obtain more definitive information by performing prospective studies in a large number of departments. A study in the USA found that there was a rate of 2.3 events per

  3. Adverse reactions to cosmetics

    Dogra A; Minocha Y; Kaur S


    Adverse reaction to cosmetics constitute a small but significant number of cases of contact dermatitis with varied appearances. These can present as contact allergic dermatitis, photodermatitis, contact irritant dermatitis, contact urticaria, hypopigmentation, hyperpigmentotion or depigmentation, hair and nail breakage. Fifty patients were included for the study to assess the role of commonly used cosmetics in causing adverse reactions. It was found that hair dyes, lipsticks and surprisingly ...

  4. Meson production in + reactions

    H Machner; M Betigeri; J Bojowald; A Budzanowski; A Chatterjee; J Ernst; L Freindl; D Frekers; W Garske; K Grewer; A Hamacher; J Ilieva; L Jarczyk; K Kilian; S Kliczewski; W Klimala; D Kolev; T Kutsarova; J Lieb; H Machner; A Magiera; H Nann; L Pentchev; H S Plendl; D Protić; B Razen; P Von Rossen; B J Roy; R Siudak; J Smyrski; R V Srikantiah; A Strzałkowski; R Tsenov; K Zwoll


    Total and differential cross sections for the reactions $p+d → 3He + 0 with = ; and + → 3H + + were measured with the GEM detector at COSY for beam momenta between threshold and the maximum of the corresponding baryon resonance. For both reactions a strong forward–backward asymmetry was found. The data were compared with model calculations. The aspect of isospin symmetry breaking is studied.

  5. Oxygen evolution reaction catalysis

    Haber, Joel A.; Jin, Jian; Xiang, Chengxiang; Gregoire, John M.; Jones, Ryan J.; Guevarra, Dan W.; Shinde, Aniketa A.


    An Oxygen Evolution Reaction (OER) catalyst includes a metal oxide that includes oxygen, cerium, and one or more second metals. In some instances, the cerium is 10 to 80 molar % of the metals in the metal oxide and/or the catalyst includes two or more second metals. The OER catalyst can be included in or on an electrode. The electrode can be arranged in an oxygen evolution system such that the Oxygen Evolution Reaction occurs at the electrode.


    Varun; Neeraj; Ushadhar; Yogesh; Rinku


    OBJECTIVES: Physical exercise provides multiple benefits to an individual. It is known that exercising regularly can prevent coronary heart disease, hypertension and obesity and improve flexibility. The effect of exercise on visual reaction time needs to be studied, a s the existing data on the benefit of aerobic exercise on psychomotor functions is insufficient. MATERIALS AND METHODS: Online Visual reaction time is measured before and after exercise. Subjects were ...

  7. Antinucleon-nucleus interaction near threshold from the Paris $\\bar NN$ potential

    Friedman, E; Loiseau, B; Wycech, S


    A general algorithm for handling the energy dependence of hadron-nucleon amplitudes in the nuclear medium, consistently with their density dependence, has been recently applied to antikaons, eta mesons and pions interacting with nuclei. Here we apply this approach to antiprotons below threshold, analyzing experimental results for antiprotonic atoms across the periodic table. It is also applied to antiproton and antineutron interaction with nuclei up to 400~MeV/c, comparing with elastic scattering and annihilation cross sections. The underlying $\\bar pN$ scattering amplitudes are derived from the Paris $\\bar NN$ potential, including modifications in the medium. Emphasis is placed on the role of the $P$-wave amplitudes with respect to the repulsive $S$-wave amplitudes.

  8. The power-law reaction rate coefficient for barrierless reactions

    Yin, Cangtao; Du, Jiulin


    The power-law reaction rate coefficient for the barrierless reactions is studied if the reactions take place in systems with power-law distributions, and a generalized rate formula for the barrierless reactions in Gorin model is derived. We show that due to barrierless, different from those for bimolecular and unimolcular reactions, the power-law rate coefficient for the barrierless reactions does not have the factor of power-law distribution function and thus it is not very strongly dependen...

  9. Chemical kinetics of gas reactions

    Kondrat'Ev, V N


    Chemical Kinetics of Gas Reactions explores the advances in gas kinetics and thermal, photochemical, electrical discharge, and radiation chemical reactions. This book is composed of 10 chapters, and begins with the presentation of general kinetic rules for simple and complex chemical reactions. The next chapters deal with the experimental methods for evaluating chemical reaction mechanisms and some theories of elementary chemical processes. These topics are followed by discussions on certain class of chemical reactions, including unimolecular, bimolecular, and termolecular reactions. The rema

  10. Marketing Mix Reactions to Entry

    Robinson, William T.


    Initial product, distribution, marketing expenditure, and price reactions by incumbents are examined for 115 entrants into oligopolistic markets. The most common reaction pattern is either no reaction or only a single reaction. It is very unusual for entrants to face reactions across the entire marketing mix. Reactions in the first two years after entry are explained as a function of the entrant's strategy, incumbent characteristics, and industry characteristics. The explanation provides insi...

  11. Introduction to chemical reaction engineering

    This deals with chemical reaction engineering with thirteen chapters. The contents of this book are introduction on reaction engineering, chemical kinetics, thermodynamics and chemical reaction, abnormal reactor, non-isothermal reactor, nonideal reactor, catalysis in nonuniform system, diffusion and reaction in porosity catalyst, design catalyst heterogeneous reactor in solid bed, a high molecule polymerization, bio reaction engineering, reaction engineering in material process, control multi-variable reactor process using digital computer.

  12. Adverse reactions to cosmetics

    Dogra A


    Full Text Available Adverse reaction to cosmetics constitute a small but significant number of cases of contact dermatitis with varied appearances. These can present as contact allergic dermatitis, photodermatitis, contact irritant dermatitis, contact urticaria, hypopigmentation, hyperpigmentotion or depigmentation, hair and nail breakage. Fifty patients were included for the study to assess the role of commonly used cosmetics in causing adverse reactions. It was found that hair dyes, lipsticks and surprisingly shaving creams caused more reaction as compared to other cosmetics. Overall incidence of contact allergic dermatitis seen was 3.3% with patients own cosmetics. Patch testing was also done with the basic ingredients and showed positive results in few cases where casual link could be established. It is recommended that labeling of the cosmetics should be done to help the dermatologists and the patients to identify the causative allergen in cosmetic preparation.

  13. Reaction Qualifications Revisited

    Lippert-Rasmussen, Kasper


      When, in a competitive sphere, people are selected on the basis of qualifications only, their chances of acquiring positions of advantage may seem to depend entirely upon their abilities, not discriminatory bias. However, if reaction qualifications - i.e. characteristics which contribute...... of merit. Specifically, it preserves symmetry between negative evaluations of antimeritocratic bases of selection and negative evaluations of qualifications rooted in comparable antimeritocratic reactions. So if employers should not select among applicants on the basis of their (the employers') racial...... preferences, recipients should not respond to the applicant actually hired on the basis of their (the recipients') racial preferences. My account decomposes the meritocratic ideal into four separate norms, one of which applies to recipients rather than to selectors. Finally, it defends the view that reaction...

  14. Interfacial Reaction Kinetics

    O'Shaughnessy, Ben; Vavylonis, Dimitrios


    We study irreversible A-B reaction kinetics at a fixed interface separating two immiscible bulk phases, A and B. We consider general dynamical exponent $z$, where $x_t\\sim t^{1/z}$ is the rms diffusion distance after time $t$. At short times the number of reactions per unit area, $R_t$, is {\\em 2nd order} in the far-field reactant densities $n_A^{\\infty},n_B^{\\infty}$. For spatial dimensions $d$ above a critical value $d_c=z-1$, simple mean field (MF) kinetics pertain, $R_t\\sim Q_b t n_A^{\\in...

  15. Nuclear reactions and structure

    A more complete data base for deriving level parameters for specific nuclei is provided by using charged-particle induced reactions. (α,pγ) reactions on 40Ca, 52Cr, 19F, 26Mg, 48Ti and 51V at Eα = 12 MeV have been used to excite levels in 43Sc, 55Mn, 22Ne, 29Al, 51V and 54Cr. Gamma rays were observed in coincidence with associated protons using a multiparameter data acquisition system. 5 figs., 9 refs., 1 tab

  16. Nuclear structure, nuclear reaction

    Etchegoyen, Maria Cristina Berisso de.; Sinclair, D.; Dr. D. Sinclair


    In this thesis, particle- particle angular correlations for reactions in non-zero degree geometry and with non-zero spin nuclei are performed and found to be a valuable tool for spin determination, (d-α) angular correlations in the reaction process 14N(6Li,d)18F* (α)14N are measured for three high excited states in 18F with a 6Li beam of 36MeV. Spins and parities for two of the observed states are determined, and in agreement with theoretical predictions, these states are s...

  17. Multinucleon transfer reactions

    Nuclear reactions induced by complex nuclei are studied. The description of the single neutron transfer is used to show some aspect of the theoretical treatment of transfer reactions and rules concerning the dependence of cross sections on quantum numbers of the initial and final channels are deduced. Strongly excited states of 20Ne, 19F, sup(16,17)0, 15N were studied experimentally by using different projectile-target combinations in the four-particle, eight-particle and ten-particle transfer reactions, leading to the some final nuclei. Obtained results are discussed. In addition, studies of the projectile break-up phenomenon were performed. The dissociation of 6Li and 7Li projectiles was investigated in reactions on Pb, Sn and Ni nuclei. These nuclei were chosen to allow measurements at one incident energy below, above and at the Coulomb barrier. The observed spectra indicate that the process proceeds primarily via the resonance level but the shape deviates from the shape which was calculated assuming isotropic decay of the excited 6Li in its center of mass system. The investigations of the elastic scattering turned out to be more fruitful and allowed to define better the Coulomb barrier for the 6Li-target system. (S.B.)

  18. Managing Your Emotional Reactions

    ... takes a bit more practice for some people. Learning to React Well Managing emotional reactions means choosing how and when to express ... easier to make choices that work out well. Learning to react well takes ... at taking emotional situations in stride and expressing emotions in healthy ...

  19. Azlactone Reaction Developments.

    de Castro, Pedro P; Carpanez, Arthur G; Amarante, Giovanni W


    Azlactones (also known as oxazolones) are heterocycles usually employed in the stereoselective synthesis of α,α-amino acids, heterocycles and natural products. The versatility of the azlactone scaffold arises from the numerous reactive sites, allowing its application in a diversity of transformations. This review aims to cover classical and recent applications of oxazolones, especially those involving stereoselective processes. After a short introduction on their structures and intrinsic reactivities, dynamic kinetic resolution (DKR) processes as well as reactions involving stereoselective formation of a new σ C-C bond, such as alkylation/allylation/arylation, aldol, ene, Michael and Mannich reactions will be exposed. Additionally, cycloadditions, Steglich rearrangement and sulfenylation reactions will also be discussed. Recent developments of the well-known Erlenmeyer azlactones will be described. For the most examples, the proposed mechanism, activation modes and/or key reaction intermediates will be exposed to rationalize both the final product and the observed stereochemistry. Finally, this review gives an overview of the synthetic utility of oxazolones. PMID:27245128

  20. Chain Reaction Polymerization.

    McGrath, James E.


    The salient features and importance of chain-reaction polymerization are discussed, including such topics as the thermodynamics of polymerization, free-radical polymerization kinetics, radical polymerization processes, copolymers, and free-radical chain, anionic, cationic, coordination, and ring-opening polymerizations. (JN)

  1. The Gewald multicomponent reaction

    Huang, Yijun; Doemling, Alexander


    The Gewald reaction of sulfur, cyanoacetic acid derivatives, and oxo-component (G-3CR) yielding highly substituted 2-aminothiophene derivatives has seen diverse applications in combinatorial and medicinal chemistry. Its products are of great use in pharmaceutical industry mainly as small molecular w

  2. Explaining competitive reaction effects

    Leeflang, P.S.H.; Wittink, D.R.


    Changes in promotional expenditure decisions for a brand, as in other marketing decisions, should be based on the expected impact on purchase and consumption behavior as well as on the likely reactions by competitors. Purchase behavior may be predicted from estimated demand functions. Competitive re

  3. Cluster knockout reactions

    Arun K Jain; B N Joshi


    Cluster knockout reactions are expected to reveal the amount of clustering (such as that of , d and even of heavier clusters such as 12C, 16O etc.) in the target nucleus. In simple terms, incident medium high-energy nuclear projectile interacts strongly with the cluster (present in the target nucleus) as if it were existing as a free entity. Theoretically, the relatively softer interactions of the two outgoing particles with the residual nucleus lead to optical distortions and are treated in terms of distorted wave (DW) formalism. The long-range projectile–cluster interaction is accounted for, in terms of the finite range (FR) direct reaction formalism, as against the more commonly adopted zero-range (ZR) distorted wave impulse approximation (DWIA) formalism. Comparison of the DWIA calculations with the observed data provide information about the momentum distribution and the clustering spectroscopic factor of the target nucleus. Interesting results and some recent advancements in the area of (, 2) reactions and heavy cluster knockout reactions are discussed. Importance of the finite-range vertex and the final-state interactions are brought out.

  4. Relativistic heavy ion reactions

    Relativistic heavy ion reactions are reviewed in terms of our present understanding of some selected experimental results from the LBL Bevalac and the CERN ISR. The Lund Model for nucleus-nucleus collisions is presented and its power of predictivity is illustrated. (authors)




    Full Text Available OBJECTIVES: Physical exercise provides multiple benefits to an individual. It is known that exercising regularly can prevent coronary heart disease, hypertension and obesity and improve flexibility. The effect of exercise on visual reaction time needs to be studied, a s the existing data on the benefit of aerobic exercise on psychomotor functions is insufficient. MATERIALS AND METHODS: Online Visual reaction time is measured before and after exercise. Subjects were instructed to run on the spot with a springy step in ex aggerated motion for 50 to 60 counts at 2 counts per second, maintaining a constant rhythm. RESULTS: We observed that reaction time was significantly lower after performance of exercise. Individuals reported improved mental alertness, feel good factor, bet ter mood and increase circulation. CONCLUSION: Improving reaction times in sports can help the athlete to optimize his performance in making decisions and increasing attention span for example getting off the starting blocks sooner or successfully making c ontact with the ball. In addition this study shows that use of physical exercise helps improve cognitive function. Exercise proves to be a cheap non pharmacological alternative to improve cognitive performance.

  6. Reaction Formulation: A Bibliography.

    Pedrini, D. T.; Pedrini, Bonnie C.

    Reaction formation was studied by Sigmund Freud. This defense mechanism may be related to repression, substitution, reversal, and compensation (or over-compensation). Alfred Adler considered compensation a basic process in his individual psychology. Anna Freud discussed some defense mechanisms, and Bibring, Dwyer, Huntington, and Valenstein…

  7. Reaction product imaging

    Chandler, D.W. [Sandia National Laboratories, Livermore, CA (United States)


    Over the past few years the author has investigated the photochemistry of small molecules using the photofragment imaging technique. Bond energies, spectroscopy of radicals, dissociation dynamics and branching ratios are examples of information obtained by this technique. Along with extending the technique to the study of bimolecular reactions, efforts to make the technique as quantitative as possible have been the focus of the research effort. To this end, the author has measured the bond energy of the C-H bond in acetylene, branching ratios in the dissociation of HI, the energetics of CH{sub 3}Br, CD{sub 3}Br, C{sub 2}H{sub 5}Br and C{sub 2}H{sub 5}OBr dissociation, and the alignment of the CD{sub 3} fragment from CD{sub 3}I photolysis. In an effort to extend the technique to bimolecular reactions the author has studied the reaction of H with HI and the isotopic exchange reaction between H and D{sub 2}.

  8. Oral Hypersensitivity Reactions

    ... and ulcers. Affected individuals may complain of a burning sensation and mouth sensitivity to cold, hot, and spicy foods. Lichenoid ... melon, and pineapple, are all associated with this syndrome. You should inform your ... reaction in the mouth, though some are more common than others. If ...

  9. Photoneutron reactions in astrophysics

    Varlamov, V. V., E-mail:; Ishkhanov, B. S.; Orlin, V. N.; Peskov, N. N.; Stopani, K. A. [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)


    Among key problems in nuclear astrophysics, that of obtaining deeper insight into the mechanism of synthesis of chemical elements is of paramount importance. The majority of heavy elements existing in nature are produced in stars via radiative neutron capture in so-called s- and r processes, which are, respectively, slow and fast, in relation to competing β{sup −}-decay processes. At the same time, we know 35 neutron-deficient so-called bypassed p-nuclei that lie between {sup 74}Se and {sup 196}Hg and which cannot originate from the aforementioned s- and r-processes. Their production is possible in (γ, n), (γ, p), or (γ, α) photonuclear reactions. In view of this, data on photoneutron reactions play an important role in predicting and describing processes leading to the production of p-nuclei. Interest in determining cross sections for photoneutron reactions in the threshold energy region, which is of particular importance for astrophysics, has grown substantially in recent years. The use of modern sources of quasimonoenergetic photons obtained in processes of inverse Compton laser-radiation scattering on relativistic electronsmakes it possible to reveal rather interesting special features of respective cross sections, manifestations of pygmy E1 and M1 resonances, or the production of nuclei in isomeric states, on one hand, and to revisit the problem of systematic discrepancies between data on reaction cross sections from experiments of different types, on the other hand. Data obtained on the basis of our new experimental-theoretical approach to evaluating cross sections for partial photoneutron reactions are invoked in considering these problems.

  10. The human acrosome reaction

    H.W.G.Baker; D.Y.Liu; C.Garrett; M.Martic


    We developed tests of sperm-oocyte interaction: sperm-zona binding, zona-induced acrosome reaction, spermzona penetration and sperm-oolemma binding, using oocytes which failed to fertilise in clinical in vitro fertilization (IVF). Although oocyte defects contribute to failure of sperm oocyte interaction, rarely are all oocytes from one woman affected. Low or zero fertilization in standard IVFwas usually caused by sperm abnormalities. Poor sperm-zona pellucida binding was frequently associated with failure of standard IVF and obvious defects of sperm motility or morphology. The size and shape of the acrosome is particularly important for sperm binding to the oocyte. The proportion of acrosome intact sperm in the insemination medium was related to the IVF rate. Inducing the acrosome reaction with a calcium ionophore reduced sperm-zona binding. Blocking acrosome dispersal with an acrosin inhibitor prevented spermzona penetration. Sperm-zona penetration was even more highly related to IVF rates than was sperm-zona binding. Some patients had low or zero fertilization rates with standard IVF but normal sperm by conventional tests and normal sperm-zona binding. Few of their sperm underwent the acrosome reaction on the surface of the zona and none penetrated the zona. In contrast, fertilization and pregnancy rates were high with intracytoplasmic sperm injection. We call thiscondition defective zona pellucida induced acrosome reaction. Discovery of the nature of the abnormalities in the signal transduction and effector pathways of the human zona pellucida induced acrosome reaction should result in simpler tests and treatments for the patients and also provide new leads for contraceptive development.

  11. Parameters influencing the pyrotechnic reaction

    Berger, Beat [Swiss Department of Defence, Civil Protection and Sports, armasuisse, Science and Technology, Feuerwerkerstrasse 39, CH-3602 Thun (Switzerland)


    Phenomena (reaction effects) such as varied light emissions, sound, varied burning rates, varied heats of reaction and reaction products occur during the reaction of inorganic redox systems used for pyrotechnics. The peculiarity of these redox reactions is, that they take place as solid-solid, solid-liquid or solid-gaseous state reactions. In opposite the theoretical redox reaction normally postulated in inorganic chemistry takes place in a solvent. By variation of different parameters as for example the reducing agent, the oxidizer, the oxygen balance and the particle size, it is possible to create the above-mentioned effects in a wide range. (Abstract Copyright [2005], Wiley Periodicals, Inc.)

  12. Pion interactions at medium energies. Progress report, December 1, 1982-January 31, 1984

    Research summaries are given on the following topics: spin dependence of nucleon-nucleon amplitudes, kaon and hypernuclear physics, kaon reactions at higher momentum, anti-nucleon reactions, and double charge exchange with heavy ions. A feasibility study for a 1 to 2 GeV separated kaon beam at the AGS is included. Publications are listed

  13. Reaction chemistry of cerium



    It is truly ironic that a synthetic organic chemist likely has far greater knowledge of the reaction chemistry of cerium(IV) than an inorganic colleague. Cerium(IV) reagents have long since been employed as oxidants in effecting a wide variety of organic transformations. Conversely, prior to the late 1980s, the number of well characterized cerium(IV) complexes did not extend past a handful of known species. Though in many other areas, interest in the molecular chemistry of the 4f-elements has undergone an explosive growth over the last twenty years, the chemistry of cerium(IV) has for the most part been overlooked. This report describes reactions of cerium complexes and structure.

  14. Neutrons from Piezonuclear Reactions

    Cardone, F; Mignani, R; Perconti, W; Petrucci, A; Rosetto, F; Spera, G


    We report the results obtained by cavitating water solutions of iron salts (iron chloride and iron nitrate) with different concentrations at different ultrasound powers. In all cases we detected a neutron radiation well higher than the background level. The neutron production is perfectly reproducible and can at some extent be controlled. These evidences for neutron emission generated by cavitation support some preliminary clues for the possibility of piezonuclear reactions (namely nuclear reactions induced by pressure and shock waves) obtained in the last ten years. We have been able for the first time to state some basic features of such a neutron emission induced by cavitation, namely: 1) a marked threshold behavior in power, energy and time; 2) its occurring without a concomitant production of gamma radiation.

  15. Nuclear reactions in astrophysics

    It is revised the nuclear reactions which present an interest in astrophysics regarding the explanation of some problems such as the relative quantity of the elements, the structure and evolution of the stars. The principal object of the study is the determination of the experimental possibilities in the field of astrophysics, of an accelerator Van de Graaff's 700 KeV type. Two hundred nuclear reactions approximately, were found, and nothing or very little has been done in the intervals of energy which are of interest. Since the bombardment energies and the involved sections are low in some cases, there are real possibilities, for the largest number of stars to obtain important statistical data with the above mentioned accelerator, taking some necessary precautions. (author)

  16. Photooxidative reactions of psoralens

    The mechanism and biological significance of photooxidative reactions of psoralens are reviewed. Skin-photosensitizing activities of bifunctional and monofunctional psoralens are compared. Antioxidants tocopherols and butilated hydroxytoluene inhibit photochemical reactions of psoralens responsible for induction of erythema. The same antioxidants do not inhibit PUVA-therapy of psriasis. Though psoralens can generate singlet oxygen under UVA-irradiation (315 - 400 nm), nevertheless singlet oxygen does not play significant role in 8-methoxypsoralen (8-MOP) sensitized photooxidation of tocopherol or dihydroxyphenylalanine (DOPA). SH-compounds enhance the rate of 8-MOP sensitized photooxidation of DOPA by a factor of four, simultaneously the rate of oxidation of SH-groups is enhanced many fold in the presence of DOPA. Under UVA-irradiation in organic solvents psoralens are photooxidized. Dimeric photooxidized psoralens are easily destructed in water medium, their destruction induce oxidation of unsaturated lipids and DOPA. (author)

  17. On Reaction Coordinate Optimality.

    Krivov, Sergei V


    The following question is addressed: how to establish that a constructed reaction coordinate is optimal, i.e., that it provides an accurate description of dynamics. It is shown that the reaction coordinate is optimal if its cut free energy profile, determined using length-weighted transitions, is constant, i.e., it is position and sampling interval independent. The observation leads to a number of interesting results. In particular, the equilibrium flux between two boundary states can be computed exactly as diffusion on a free energy profile associated with the coordinate. The mean square displacement, for the trajectory projected onto the coordinate, grows linear with time. That for the same trajectory projected onto a suboptimal coordinate grows slower than linear with time. The results are illustrated on a number of model systems, Sierpinski gasket, FIP35 protein, and beta3s peptide. PMID:26589017

  18. Two photon reactions

    Some recent results from the field of photon-photon interaction are presented. After a brief general introduction author discusses resonance production, exclusive processes with the four pion final state (γγ→π+π-π+π-), exclusive reaction γγ→psi psi, γγ - 2 body final state and jet production. Total hadronic cross sections for γγ - interactions and the photon structure function are also considered. (M.F.W.)

  19. Polymerase chain reaction

    Gaurav Solanki


    The polymerase chain reaction (PCR) is a technique in molecular biology to amplify a single or a few copies of a piece of DNA across several orders of magnitude, generating thousands to millions of copies of a particular DNA sequence. PCR is now a common and often indispensable technique used in medical and biological research labs for a variety of applications. There are three major steps involved in the PCR technique: denaturation, annealing and extension. PCR is useful in the investigation...

  20. Photochemical reaction dynamics

    Moore, B.C. [Lawrence Berkeley Laboratory, Livermore, CA (United States)


    The purpose of the program is to develop a fundamental understanding of unimolecular and bimolecular reaction dynamics with application in combustion and energy systems. The energy dependence in ketene isomerization, ketene dissociation dynamics, and carbonyl substitution on organometallic rhodium complexes in liquid xenon have been studied. Future studies concerning unimolecular processes in ketene as well as energy transfer and kinetic studies of methylene radicals are discussed.

  1. Astrophysical Reaction Rates as a Challenge for Nuclear Reaction Theory

    Rauscher, T.


    The relevant energy ranges for stellar nuclear reactions are introduced. Low-energy compound and direct reactions are discussed. Stellar modifications of the cross sections are presented. Implications for experiments are outlined.

  2. Compound-nuclear reaction cross sections via surrogate reactions

    The surrogate reaction method is an indirect technique for determining cross sections for nuclear reactions that proceed through a well-defined compound nucleus. In this method, the same compound nucleus is produced by an alternate ('surrogate') reaction and its decay products measured. The assumptions underlying the method are examined for the special case of 235U(n, f)

  3. Insect bite reactions

    Sanjay Singh


    Full Text Available Insects are a class of living creatures within the arthropods. Insect bite reactions are commonly seen in clinical practice. The present review touches upon the medically important insects and their places in the classification, the sparse literature on the epidemiology of insect bites in India, and different variables influencing the susceptibility of an individual to insect bites. Clinical features of mosquito bites, hypersensitivity to mosquito bites Epstein-Barr virus NK (HMB-EBV-NK disease, eruptive pseudoangiomatosis, Skeeter syndrome, papular pruritic eruption of HIV/AIDS, and clinical features produced by bed bugs, Mexican chicken bugs, assassin bugs, kissing bugs, fleas, black flies, Blandford flies, louse flies, tsetse flies, midges, and thrips are discussed. Brief account is presented of the immunogenic components of mosquito and bed bug saliva. Papular urticaria is discussed including its epidemiology, the 5 stages of skin reaction, the SCRATCH principle as an aid in diagnosis, and the recent evidence supporting participation of types I, III, and IV hypersensitivity reactions in its causation is summarized. Recent developments in the treatment of pediculosis capitis including spinosad 0.9% suspension, benzyl alcohol 5% lotion, dimethicone 4% lotion, isopropyl myristate 50% rinse, and other suffocants are discussed within the context of evidence derived from randomized controlled trials and key findings of a recent systematic review. We also touch upon a non-chemical treatment of head lice and the ineffectiveness of egg-loosening products. Knockdown resistance (kdr as the genetic mechanism making the lice nerves insensitive to permethrin is discussed along with the surprising contrary clinical evidence from Europe about efficacy of permethrin in children with head lice carrying kdr-like gene. The review also presents a brief account of insects as vectors of diseases and ends with discussion of prevention of insect bites and some

  4. Chernobyl - the government reaction

    The Farmers' Union of Wales submitted this memorandum to the Agriculture Committee of the House of Commons giving its interpretation of the Government's reaction to the Chernobyl disaster. The primary aim of the paper is to provide an objective assessment of the impact of the disaster and the Government's handling of it, for future reference. The subject is dealt with under the following headings:- Chernobyl nuclear fallout in Wales, monitoring of milk and fresh vegetables, silage contamination, the North Wales Sheep Sector, soil, herbage and genetic implications, recommendations for the future. (UK)

  5. Nuclear reactions. An introduction

    Modern, self-contained introduction to the subject matter. Emphasizes the interplay between theory and experiment. Course-tested tutorial style, contains many derivations. Nuclei and nuclear reactions offer a unique setting for investigating three (and in some cases even all four) of the fundamental forces in nature. Nuclei have been shown - mainly by performing scattering experiments with electrons, muons, and neutrinos - to be extended objects with complex internal structures: constituent quarks; gluons, whose exchange binds the quarks together; sea-quarks, the ubiquitous virtual quark-antiquark pairs and, last but not least, clouds of virtual mesons, surrounding an inner nuclear region, their exchange being the source of the nucleon-nucleon interaction. The interplay between the (mostly attractive) hadronic nucleon-nucleon interaction and the repulsive Coulomb force is responsible for the existence of nuclei; their degree of stability, expressed in the details and limits of the chart of nuclides; their rich structure and the variety of their interactions. Despite the impressive successes of the classical nuclear models and of ab-initio approaches, there is clearly no end in sight for either theoretical or experimental developments as shown e.g. by the recent need to introduce more sophisticated three-body interactions to account for an improved picture of nuclear structure and reactions. Yet, it turns out that the internal structure of the nucleons has comparatively little influence on the behavior of the nucleons in nuclei, and nuclear physics - especially nuclear structure and reactions - is thus a field of science in its own right, without much recourse to subnuclear degrees of freedom. This book collects essential material that was presented in the form of lectures notes in nuclear physics courses for graduate students at the University of Cologne. It follows the course's approach, conveying the subject matter by combining experimental facts and experimental

  6. (d,pγ) Reactions and the surrogate reaction technique

    Neutron-capture reactions on neutron-rich nuclei are important to understand r-process nucleosynthesis, as well as applied needs such as stewardship science and nuclear energy. Because of the short half-lives of these species, it is not possible to measure these reactions directly with neutron beams on unstable targets. The (d,pγ) reaction with radioactive ion beams has been proposed as a surrogate reaction for (n,γ). Experiments to develop (d,pγ) techniques with radioactive ion beams and to demonstrate the efficacy of the (d,pγ) reaction as a surrogate for (n,γ) are discussed

  7. Zeolite Catalyzed Aldol Condensation Reactions

    Adedayo I. Inegbenebor; Raphael C. Mordi; Oluwakayode M. Ogunwole


    The review is based on the description of zeolite structure, uses, synthesis, and catalytic aldol reaction in aldol condensation. An internal aldolcondensation reaction has been achieved over ZSM-5 zeolite with high silica-alumina ratio at 350oC. It therefore follows that zeolite canfunction as a catalyst in aldol type condensation reactions and that weak acid sites as well as a small number of active sites favor the aldolcondensation reaction of carbonyl compounds. However, the mixed condens...

  8. Reaction spreading on percolating clusters

    Bianco, Federico; Chibbaro, Sergio; Vergni, Davide; Vulpiani, Angelo


    Reaction-diffusion processes in two-dimensional percolating structures are investigated. Two different problems are addressed: reaction spreading on a percolating cluster and front propagation through a percolating channel. For reaction spreading, numerical data and analytical estimates show a power-law behavior of the reaction product as M(t) \\sim t^dl, where dl is the connectivity dimension. In a percolating channel, a statistically stationary traveling wave develops. The speed and the widt...

  9. Hydrogen isotope exchange reactions

    The two most widely used methods for following hydrogen isotope exchange reactions, namely dedeuteriation and detritiation, involve in the first place the synthesis of an appropriately labelled compound. Rates of dedeuteriation are usually followed by measuring changes in the 1H n.m.r. spectrum of the substrate (examples are given); the method not only gives the rate but also the site(s) of exchange. It is limited to rather slow reactions and is not as accurate as some of the other methods. The development of deuterium n.m.r. spectroscopy means that changes in the 2H n.m.r. spectrum can also be used to measure rates of dedeuteriation. The development of liquid scintillation counting greatly eased the problem of how to detect weak β emitters; the attractions of tritium as a tracer were thereby much enhanced. Nowadays the study of rates of detritiation constitutes one of the most versatile and accurate methods of following hydrogen isotope exchange. Examples of the technique are given. (U.K.)

  10. Status of breakup reaction theory

    Recent studies on breakup reactions with the continuum-discretized coupled-channels method are reviewed. The topics covered are: four-body breakup processes for 6He induced reaction, dynamical relativistic effects on Coulomb breakup, microscopic description of projectile breakup processes, description of ternary processes (new triple-α reaction rate) and new approach to inclusive breakup processes.

  11. Medications and Drug Allergic Reactions

    ... breathing. This is most common in adults with asthma and in people with nasal polyps (benign growths). Other reactions to NSAIDs can result in hives or in rare instances, severe reactions can result in shock. A number of factors influence your chances of having an adverse reaction ...

  12. The power-law reaction rate coefficient for barrierless reactions

    We study the power-law reaction rate coefficient for barrierless reactions, when the reactions take place in systems with power-law distributions, and derive a generalized rate formula for the barrierless reactions in the Gorin model. We show that, unlike those for bimolecular and unimolcular reactions, due to the lack of barriers, the power-law rate coefficient for barrierless reactions does not have a power-law function, and thus is not very strongly dependent on the ν-parameter. Four barrierless reactions are taken as application examples to calculate the new rate coefficients, which with larger fitting ν-parameters can be exactly in agreement with measurements in the experimental studies. (paper)

  13. Polymerase Chain Reaction

    Gaurav Solanki


    Full Text Available The polymerase chain reaction (PCR is a technique in molecular biology to amplify a single or a few copies of a piece of DNA across several orders of magnitude, generating thousands to millions of copies of a particular DNA sequence. PCR is now a common and often indispensable technique used in medical and biological research labs for a variety of applications. There are three major steps involved in the PCR technique: denaturation, annealing and extension. PCR is useful in the investigation and diagnosis of a growing number of diseases. PCR is also used in forensics laboratories. PCR can identify genes that have been implicated in the development of cancer. The present paper is an attempt to review basics of PCR in relation to its methods, application and use.

  14. Kinetics of Bio-Reactions

    Villadsen, John


    his chapter predicts the specific rates of reaction by means of a mathematical expression, the kinetics of the reaction. This expression can be derived through a mechanistic interpretation of an enzymatically catalyzed reaction, but it is essentially of empirical nature for cell reactions. The...... models can be used in mass balances for design of processes under process conditions not yet studied experimentally. The value of the predictive kinetic model depends on the quality of the experimental data on which the model is based, and well-founded kinetic models for enzyme reactions have a...... considerable predictive power. This is also true for cell reaction models, when the model is used in its proper context. The chapter first discusses the kinetics for enzymatically catalyzed reactions (“enzyme reactions”). The kinetics can be derived from a mechanistic model. Then, the chapter derives empirical...

  15. Resonance Reaction in Diffusion-Influenced Bimolecular Reactions

    Kolb, Jakob J.; Angioletti-Uberti, Stefano; Dzubiella, Joachim


    We investigate the influence of a stochastically fluctuating step-barrier potential on bimolecular reaction rates by exact analytical theory and stochastic simulations. We demonstrate that the system exhibits a new resonant reaction behavior with rate enhancement if an appropriately defined fluctuation decay length is of the order of the system size. Importantly, we find that in the proximity of resonance the standard reciprocal additivity law for diffusion and surface reaction rates is viola...

  16. Dechlorinating reaction of organic chlorides

    Dechlorination has been examined by the reaction between iron, aluminum powder or CaO and organic chlorides such as C2HCl3 and CH2Cl2. Progress of the reaction was analyzed with mass spectrometer. The reaction between iron and organic chloride was rapidly occurred at the temperature between 350 and 440degC in an atmosphere of argon. Above 380degC, more than 99.5% of C2HCl3 was decomposed within approximately 100 minutes. At 440degC, approximately 60% of C2HCl3 was decomposed by the reaction with aluminium powder within approximately 100 minutes. At 440degC, reaction between C2HCl3 and CaO powder were occurred rapidly in an atmosphere of argon to form CaCl2 and free carbon. Also in an atmosphere of air, nearly the same result was obtained. In this reaction, CaCl2, CO and CO2 were formed. CH2Cl2 was also decomposed by the reaction with iron at the temperature between 380 and 440degC. In the reaction, FeCl2, carbon and hydrogen were formed. CH3+ and CH4 were observed during the dechlorinating reaction of CH2Cl2. Variation in particle size of iron powder such as 100, 150 and 250 mesh did not affect the reaction rate. (author)

  17. Resonance Reaction in Diffusion-Influenced Bimolecular Reactions

    Kolb, Jakob J; Dzubiella, Joachim


    We investigate the influence of a stochastically fluctuating step-barrier potential on bimolecular reaction rates by exact analytical theory and stochastic simulations. We demonstrate that the system exhibits a new resonant reaction behavior with rate enhancement if an appropriately defined fluctuation decay length is of the order of the system size. Importantly, we find that in the proximity of resonance the standard reciprocal additivity law for diffusion and surface reaction rates is violated due to the dynamical coupling of multiple kinetic processes. Together, these findings may have important repercussions on the correct interpretation of various kinetic reaction problems in complex systems, as, e.g., in biomolecular association or catalysis.

  18. Communication: Resonance reaction in diffusion-influenced bimolecular reactions

    Kolb, Jakob J.; Angioletti-Uberti, Stefano; Dzubiella, Joachim


    We investigate the influence of a stochastically fluctuating step-barrier potential on bimolecular reaction rates by exact analytical theory and stochastic simulations. We demonstrate that the system exhibits a new "resonant reaction" behavior with rate enhancement if an appropriately defined fluctuation decay length is of the order of the system size. Importantly, we find that in the proximity of resonance, the standard reciprocal additivity law for diffusion and surface reaction rates is violated due to the dynamical coupling of multiple kinetic processes. Together, these findings may have important repercussions on the correct interpretation of various kinetic reaction problems in complex systems, as, e.g., in biomolecular association or catalysis.

  19. Microwave-Accelerated Organic Reactions

    LU; TaJung


    The use of microwave technology in accelerating organic reactions has received intense attention leading to immense growth recently. Accordingly, we have been interested in improving the efficacy of organic processes by microwave irradiation. Here we report our results on the microwave assisted 1,3-dipolar cycloaddition reaction of nitrile oxides with allylic alcohols, the cleavage reaction of 1,3-diketones under alkaline conditions, and the formation of carbamates from isocyanates with alcohols. The reactions carried out under microwave irradiation, in general, required considerably less reaction time and afforded the desired products in higher yields than those under classical conditions. In all the cases we have studied, the procedures are simplified, the purity of the products are higher, and the cost of reaction is greatly reduced employing microwave.  ……

  20. Limits for Stochastic Reaction Networks

    Cappelletti, Daniele

    Reaction systems have been introduced in the 70s to model biochemical systems. Nowadays their range of applications has increased and they are fruitfully used in dierent elds. The concept is simple: some chemical species react, the set of chemical reactions form a graph and a rate function is...... associated with each reaction. Such functions describe the speed of the dierent reactions, or their propensities. Two modelling regimes are then available: the evolution of the dierent species concentrations can be deterministically modelled through a system of ODE, while the counts of the dierent species at...... a certain time are stochastically modelled by means of a continuous-time Markov chain. Our work concerns primarily stochastic reaction systems, and their asymptotic properties. In Paper I, we consider a reaction system with intermediate species, i.e. species that are produced and fast degraded along...

  1. The Glaser–Hay reaction

    Vilhelmsen, Mie Højer; Jensen, Jonas; Tortzen, Christian;


    The oxidative Glaser–Hay coupling of two terminal alkynes to furnish a butadiyne is a key reaction for acetylenic scaffolding. Although the reaction is performed under rather simple conditions [CuCl/TMEDA/O2 (air)], the mechanism is still under debate. Herein we present detailed studies on the...... scope of this reaction by using both 13C NMR and UV/Vis spectroscopic methods. The former method was used to study the kinetics of the coupling of aryl-substituted alkynes as the aryl carbon resonances of the reactants and products have similar NOEs and relaxation times. The reaction was found to be...... zero-order with respect to the terminal alkyne reactant under standard preparative conditions. Moreover, as the reaction proceeded, a clear change to slower reaction kinetics was observed, but it was still apparently zero-order. The onset of this change was found to depend on the catalyst loading. This...

  2. Microwave-Accelerated Organic Reactions

    LU TaJung


    @@ The use of microwave technology in accelerating organic reactions has received intense attention leading to immense growth recently. Accordingly, we have been interested in improving the efficacy of organic processes by microwave irradiation. Here we report our results on the microwave assisted 1,3-dipolar cycloaddition reaction of nitrile oxides with allylic alcohols, the cleavage reaction of 1,3-diketones under alkaline conditions, and the formation of carbamates from isocyanates with alcohols. The reactions carried out under microwave irradiation, in general, required considerably less reaction time and afforded the desired products in higher yields than those under classical conditions. In all the cases we have studied, the procedures are simplified, the purity of the products are higher, and the cost of reaction is greatly reduced employing microwave.

  3. The Paterno-Buchi reaction

    Brogaard, Rasmus Yding; Schalk, Oliver; Boguslavskiy, Andrey E.;


    The Paternò-Büchi (PB) reaction between an excited carbonyl compound and an alkene has been widely studied, but so far little is known about the excited-state dynamics of the reaction. In this investigation, we used a compound in which a formyl and a vinyl group are attached to a [2.......2]paracyclophane in order to obtain a model system in pre-reactive conformation for the PB reaction. We studied the excited-state dynamics of the isolated molecule in a molecular beam using femtosecond time-resolved photoelectron spectroscopy and ab initio calculations. The results show that inter-system crossing...... within two picoseconds competes efficiently with the reaction in the singlet manifold. Thus, the PB reaction in this model system takes place in the triplet state on a time scale of nanoseconds. This result stresses the importance of triplet states in the excited-state pathway of the PB reaction...

  4. Electrochemical reactions and ionization processes

    Girault, Hubert; Liu, Baohong; Qiao, Liang; Bi, Hongyan; Prudent, Michel; Lion, Niels; Abonnenc, Mélanie


    Electrochemical or photo-electrochemical reactions in both electrospray ionization and laser desorption ionization are discussed stressing the role of the electrode reaction in influencing the ionization process. In particular, upon application of a high voltage during electrospray ionization, the emitter includes a working electrode, where redox reactions are observed, such as electro-generation of benzoquinone and metal ions. In contrast, the target plate in laser-induced desorption ionizat...

  5. Nuclear astrophysics from direct reactions


    Accurate nuclear reaction rates are needed for primordial nucleosynthesis and hydrostatic burning in stars. The relevant reactions are extremely difficult to measure directly in the laboratory at the small astrophysical energies. In recent years direct reactions have been developed and applied to extract low-energy astrophysical S-factors. These methods require a combination of new experimental techniques and theoretical efforts, which are the subject of this presentation.

  6. Influences of Reaction Parameters on the Product of a Geothermite Reaction: A Multi-Component Oxidation-Reduction Reaction Study

    Faierson, Eric J.


    This study investigated an oxidation-reduction reaction involving a mixture of minerals, glass, and aluminum that exhibited thermite-type reaction behavior. Thermite reactions are a class of Self-propagating High-temperature Synthesis (SHS) reactions. Chemical reactions between raw minerals and a reducing agent, which exhibit thermite-type reaction behavior, are termed geothermite reactions by the author. Geothermite reactions have the potential for use in In-Situ Resource Utilization (ISRU...

  7. Speeding chemical reactions by focusing

    Lacasta, A. M.; Ramírez-Piscina, L.; Sancho, J. M.; Lindenberg, K.


    We present numerical results for a chemical reaction of colloidal particles which are transported by a laminar fluid and are focused by periodic obstacles in such a way that the two components are well mixed and consequently the chemical reaction is speeded up. The roles of the various system parameters (diffusion coefficients, reaction rate, and obstacles sizes) are studied. We show that focusing speeds up the reaction from the diffusion limited rate ˜t-1/2 to very close to the perfect mixing rate, ˜t-1.

  8. Speeding chemical reactions by focusing

    Lacasta, A M; Sancho, J M; Lindenberg, K


    We present numerical results for a chemical reaction of colloidal particles which are transported by a laminar fluid and are focused by periodic obstacles in such a way that the two components are well mixed and consequently the chemical reaction is speeded up. The roles of the various system parameters (diffusion coefficients, reaction rate, obstacles sizes) are studied. We show that focusing speeds up the reaction from the diffusion limited rate (t to the power -1/2) to very close to the perfect mixing rate, (t to the power -1).

  9. Dynamic Reaction Figures: An Integrative Vehicle for Understanding Chemical Reactions

    Schultz, Emeric


    A highly flexible learning tool, referred to as a dynamic reaction figure, is described. Application of these figures can (i) yield the correct chemical equation by simply following a set of menu driven directions; (ii) present the underlying "mechanism" in chemical reactions; and (iii) help to solve quantitative problems in a number of different…

  10. [Reaction mechanism studies of heavy ion induced nuclear reactions

    This report contains papers that discuss: Target Dependence of Complex Fragment Emission in 47-MeV/u La-Induced Reactions; Deconvolution of Time-of-Flight Data to Improve Mass Identification; and Study of the Reaction of La + Al at E/A = 50 MeV with Landau-Vlasov Dynamics

  11. Progress in microscopic direct reaction modeling of nucleon induced reactions

    Dupuis, M.; Bauge, E.; Hilaire, S.; Lechaftois, F.; Peru, S.; Pillet, N.; Robin, C. [CEA, DAM, DIF, Arpajon (France)


    A microscopic nuclear reaction model is applied to neutron elastic and direct inelastic scatterings, and pre-equilibrium reaction. The JLM folding model is used with nuclear structure information calculated within the quasi-particle random phase approximation implemented with the Gogny D1S interaction. The folding model for direct inelastic scattering is extended to include rearrangement corrections stemming from both isoscalar and isovector density variations occurring during a transition. The quality of the predicted (n,n), (n,n{sup '}), (n,xn) and (n,n{sup '}γ) cross sections, as well as the generality of the present microscopic approach, shows that it is a powerful tool that can help improving nuclear reactions data quality. Short- and long-term perspectives are drawn to extend the present approach to more systems, to include missing reactions mechanisms, and to consistently treat both structure and reaction problems. (orig.)

  12. Progress in microscopic direct reaction modeling of nucleon induced reactions

    A microscopic nuclear reaction model is applied to neutron elastic and direct inelastic scatterings, and pre-equilibrium reaction. The JLM folding model is used with nuclear structure information calculated within the quasi-particle random phase approximation implemented with the Gogny D1S interaction. The folding model for direct inelastic scattering is extended to include rearrangement corrections stemming from both isoscalar and isovector density variations occurring during a transition. The quality of the predicted (n,n), (n,n'), (n,xn) and (n,n'γ) cross sections, as well as the generality of the present microscopic approach, shows that it is a powerful tool that can help improving nuclear reactions data quality. Short- and long-term perspectives are drawn to extend the present approach to more systems, to include missing reactions mechanisms, and to consistently treat both structure and reaction problems. (orig.)

  13. Microscopic effective reaction theory for deuteron-induced reactions

    Neoh, Yuen Sim; Minomo, Kosho; Ogata, Kazuyuki


    The microscopic effective reaction theory is applied to deuteron-induced reactions. A reaction model-space characterized by a $p+n+{\\rm A}$ three-body model is adopted, where A is the target nucleus, and the nucleon-target potential is described by a microscopic folding model based on an effective nucleon-nucleon interaction in nuclear medium and a one-body nuclear density of A. The three-body scattering wave function in the model space is obtained with the continuum-discretized coupled-channels method (CDCC), and the eikonal reaction theory (ERT), an extension of CDCC, is applied to the calculation of neutron removal cross sections. Elastic scattering cross sections of deuteron on $^{58}$Ni and $^{208}$Pb target nuclei at several energies are compared with experimental data. The total reaction cross sections and the neutron removal cross sections at 56 MeV on 14 target nuclei are calculated and compared with experimental values.

  14. Astronomy with Radioactivities: Chapter 9, Nuclear Reactions

    Wiescher, M.; Rauscher, T.


    Nuclear reaction rates determine the abundances of isotopes in stellar burning processes. A multitude of reactions determine the reaction flow pattern which is described in terms of reaction network simulations. The reaction rates are determined by laboratory experiments supplemented by nuclear reaction and structure theory. We will discuss the experimental approach as well as the theoretical tools for obtaining the stellar reaction rates. A detailed analysis of a reaction is only possible fo...

  15. Chemistry of heavy ion reactions

    The use of heavy ions to induce nuclear reactions was reported as early as 1950. Since that time it has been one of the most active areas of nuclear research. Intense beams of ions as heavy as uranium with energies high enough to overcome the Coulomb barriers of even the heaviest elements are available. The wide variety of possible reactions gives rise to a multitude of products which have been studied by many ingenious chemical and physical techniques. Chemical techniques have been of special value for the separation and unequivocal identification of low yield species from the plethora of other nuclides present. Heavy ion reactions have been essential for the production of the trans-Md elements and a host of new isotopes. The systematics of compound nucleus reactions, transfer reactions, and deeply inelastic reactions have been elucidated using chemical techniques. A review of the variety of chemical procedures and techniques which have been developed for the study of heavy ion reactions and their products is given. Determination of the chemical properties of the trans-Md elements, which are very short-lived and can only be produced an ''atom-at-a-time'' via heavy ion reactions, is discussed. 53 refs., 19 figs

  16. Entropy Effects in Chelation Reactions.

    Chung, Chung-Sun


    The entropy change for a reaction in aqueous solution can be evaluated as a combination of entropy factors. Valuable insight or understanding can be obtained from a detailed examination of these factors. Several entropy effects of inorganic chemical reactions are discussed as examples. (Author/JN)

  17. Symmetry violation in nuclear reactions

    Precision studies of nuclear reactions can be used to search for small violations of the discrete symmetries. Recent and proposed experimental work using nuclear reactions to study the breakdown of three symmetries - isospin (I), parity (P) and time-reversal (T) is reviewed. 44 references

  18. Free Radical Reactions in Food.

    Taub, Irwin A.


    Discusses reactions of free radicals that determine the chemistry of many fresh, processed, and stored foods. Focuses on reactions involving ascorbic acid, myoglobin, and palmitate radicals as representative radicals derived from a vitamin, metallo-protein, and saturated lipid. Basic concepts related to free radical structure, formation, and…

  19. Zeolite Catalyzed Aldol Condensation Reactions

    Adedayo I. Inegbenebor


    Full Text Available The review is based on the description of zeolite structure, uses, synthesis, and catalytic aldol reaction in aldol condensation. An internal aldolcondensation reaction has been achieved over ZSM-5 zeolite with high silica-alumina ratio at 350oC. It therefore follows that zeolite canfunction as a catalyst in aldol type condensation reactions and that weak acid sites as well as a small number of active sites favor the aldolcondensation reaction of carbonyl compounds. However, the mixed condensation product was found to be favored at temperatures above 300oCand the self-condensation of ethanal to crotonaldehyde was favored at temperatures below 300oC. It has also been suggested that both Brønstedand Lewis acids are involved in aldol reactions with Lewis acid sites the most probable catalytic sites. The zeolite group of minerals has founduse in many chemical and allied industries.

  20. Enzymatic reactions in confined environments

    Küchler, Andreas; Yoshimoto, Makoto; Luginbühl, Sandra; Mavelli, Fabio; Walde, Peter


    Within each biological cell, surface- and volume-confined enzymes control a highly complex network of chemical reactions. These reactions are efficient, timely, and spatially defined. Efforts to transfer such appealing features to in vitro systems have led to several successful examples of chemical reactions catalysed by isolated and immobilized enzymes. In most cases, these enzymes are either bound or adsorbed to an insoluble support, physically trapped in a macromolecular network, or encapsulated within compartments. Advanced applications of enzymatic cascade reactions with immobilized enzymes include enzymatic fuel cells and enzymatic nanoreactors, both for in vitro and possible in vivo applications. In this Review, we discuss some of the general principles of enzymatic reactions confined on surfaces, at interfaces, and inside small volumes. We also highlight the similarities and differences between the in vivo and in vitro cases and attempt to critically evaluate some of the necessary future steps to improve our fundamental understanding of these systems.

  1. Sodium concrete reaction: structural considerations

    An overview of the sodium concrete reaction phenomenon, with emphasis on structural considerations, is presented. Available test results for limestone, basalt, and magnetite concrete with various test article configurations are reviewed. Generally, tests indicate reaction is self limiting before all sodium is used. Uncertainties, however, concerning the mechanism for penetration of sodium into concrete have resulted in different theories about a reaction model. Structural behavior may be significant in the progression of the reaction due to thermal-structural-chemical interactions involving tensile cracking, compressive crushing, or general deterioration of concrete and the exposure of fresh concrete surfaces to react with sodium. Structural behavior of test articles and potential factors that could enhance the progression of the reaction are discussed

  2. Integrated Microreactors for Reaction Automation: New Approaches to Reaction Development

    McMullen, Jonathan P.; Jensen, Klavs F.


    Applications of microsystems (microreactors) in continuous-flow chemistry have expanded rapidly over the past two decades, with numerous reports of higher conversions and yields compared to conventional batch benchtop equipment. Synthesis applications are enhanced by chemical information gained from integrating microreactor components with sensors, actuators, and automated fluid handling. Moreover, miniaturized systems allow experiments on well-defined samples at conditions not easily accessed by conventional means, such as reactions at high pressure and temperatures. The wealth of synthesis information that could potentially be acquired through use of microreactors integrated with physical sensors and analytical chemistry techniques for online reaction monitoring has not yet been well explored. The increased efficiency resulting from use of continuous-flow microreactor platforms to automate reaction screening and optimization encourages a shift from current batchwise chemical reaction development to this new approach. We review advances in this new area and provide application examples of online monitoring and automation.

  3. Nuclear Reactions at Intermediate Energies

    Shyam, Radhey


    In the domain of Nuclear reactions at intermediate energies, the QCD coupling constant $\\alpha_s$ is large enough ($\\sim$ 0.3 - 0.5) to render the perturbative calculational techniques inapplicable. In this regime the quarks are confined into colorless hadrons and it is expected that effective field theories of hadron interactions via exchange of hadrons, provide useful tools to describe such reactions. In this contribution we discuss applications of one such theory, the effective Lagrangian model, in describing the hadronic reactions at intermediate energies whose measurements are the focus of a vast international experimental program.

  4. Palladium-catalyzed coupling reactions

    Molnár, Árpád


    This handbook and ready reference brings together all significant issues of practical importance for interested readers in one single volume. While covering homogeneous and heterogeneous catalysis, the text is unique in focusing on such important aspects as using different reaction media, microwave techniques or catalyst recycling. It also provides a comprehensive treatment of modern-day coupling reactions and emphasizes those topics that show potential for future development, such as continuous flow systems, water as a reaction medium, and catalyst immobilization, among others. With i

  5. Hypersensitivity reaction associated with phenytoin.

    Indu, T H; Basutkar, Roopa Satyanarayan


    Hypersensitivity reactions with antiepileptic drugs (AEDs) are generally associated with aromatic AEDs. We present a case of hypersensitivity reactions followed by administration of phenytoin with diazepam and ranitidine in a patient with generalized tonic-clonic seizures. Antigen-antibody reactions or decreased levels of epoxide hydrolase are well known with phenytoin. Increased level of serum phenytoin causing toxicities due to competitive inhibition with diazepam on co-administration was also reported in the literature. Prevention of the adverse effects with AEDs is a multi-stage process, which requires implementation of preventive measures through careful monitoring and prompts interventions. PMID:26692739

  6. Reactions with light exotic nuclei

    Lichtenthäler, R.; Faria, P.N. de; Pires, K.C.C.; Lepine-Szily, A.; Guimaraes, V.; Mendes Junior, D.R.; Assuncao, M.; Barioni, A.; Morcelle, V.; Morais, M.C.; Camargo Junior, O.; Alcantara Nuñez, J. [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto de Fisica; Moro, A.M. [Departamento de FAMN, Universidad de Sevilla, Sevilla (Spain); Arazi, A. [Laboratorio Tandar, Departamento de Fisica, Comision Nacional de Energia Atomica (CNEA), Buenos Aires (Argentina); Rodriguez-Gallardo, M. [Instituto de Estructura de la Materia, CSIC, Madrid (Spain)


    Experimental cross sections for the {sup 6}He+{sup 120}Sn are analysed. Elastic scattering angular distributions and alpha particle production cross sections have been measured and are compared with the total reaction cross sections. (author)

  7. Bulk Nuclear Properties from Reactions

    Danielewicz, P.


    Extraction of bulk nuclear properties by comparing reaction observables to results from semiclassical transport-model simulations is discussed. Specific properties include the nuclear viscosity, incompressibility and constraints on the nuclear pressure at supranormal densities.

  8. Transfer reactions in nuclear astrophysics

    Bardayan, D. W.


    To a high degree many aspects of the large-scale behavior of objects in the Universe are governed by the underlying nuclear physics. In fact the shell structure of nuclear physics is directly imprinted into the chemical abundances of the elements. The tranquility of the night sky is a direct result of the relatively slow rate of nuclear reactions that control and determines a star’s fate. Understanding the nuclear structure and reaction rates between nuclei is vital to understanding our Universe. Nuclear-transfer reactions make accessible a wealth of knowledge from which we can extract much of the required nuclear physics information. A review of transfer reactions for nuclear astrophysics is presented with an emphasis on the experimental challenges and opportunities for future development.

  9. Reaction-bonded silicon nitride

    Reaction-bonded silicon nitride (RBSN) has been characterized. The oxidation behaviour in air up to 15000C and 3000 h and the effects of static and cyclic oxidation on room-temperature strength have been studied. (orig./IHOE)

  10. Statistical emission in nuclear reactions

    Statistical model in nuclear reactions has been extensively developed in the past decades, mainly by V. Weisskopf. However, a clear understanding of the experimental situation regarding low- and medium- energy nuclear reaction is not yet settled. The interpretation is complicated by the fact that often the reactions proceed via other mechanisms, for instance direct effects. The purpose 'of the present paper is to show how a great number of experiments can be put in agreement with the statistical formulas, and particularly the resonance measurements for slow neutrons, the evaporation spectra from medium-energy (n, n'), (p, n) and (n, p) reactions and the (n, p) cross-sections at 14 MeV. From the set of experiments discussed it is possible to obtain a consistent table of a, the parameter of the level density formula. (author)

  11. Fluctuations in catalytic surface reactions

    Imbihl, R


    The internal reaction-induced fluctuations which occur in catalytic CO oxidation on a Pt field emitter tip have been studied using field electron microscopy (FEM) as a spatially resolving method. The structurally heterogeneous Pt tip consists of facets of different orientations with nanoscale dimensions. The FEM resolution of roughly 2 nm corresponds to a few hundred reacting adsorbed particles whose variations in the density are imaged as brightness fluctuations. In the bistable range of the reaction one finds fluctuation-induced transitions between the two stable branches of the reaction kinetics. The fluctuations exhibit a behaviour similar to that of an equilibrium phase transition, i.e. the amplitude diverges upon approaching the bifurcation point terminating the bistable range of the reaction. Simulations with a hybrid Monte Carlo/mean-field model reproduce the experimental observations. Fluctuations on different facets are typically uncorrelated but within a single facet a high degree of spatial cohere...

  12. Microreactors for Studying Enantioselective Reactions

    Pavlorková, Jana

    Prague: Faculty of Chemical Technology, ICT, 2014. [Conference of Post-graduate Students. Prague (CZ), 26.06.2014] Institutional support: RVO:67985858 Keywords : enantioselective reactions * microreactors * molecular chirality Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  13. Solar-thermal reaction processing

    Weimer, Alan W; Dahl, Jaimee K; Lewandowski, Allan A; Bingham, Carl; Raska Buechler, Karen J; Grothe, Willy


    In an embodiment, a method of conducting a high temperature chemical reaction that produces hydrogen or synthesis gas is described. The high temperature chemical reaction is conducted in a reactor having at least two reactor shells, including an inner shell and an outer shell. Heat absorbing particles are included in a gas stream flowing in the inner shell. The reactor is heated at least in part by a source of concentrated sunlight. The inner shell is heated by the concentrated sunlight. The inner shell re-radiates from the inner wall and heats the heat absorbing particles in the gas stream flowing through the inner shell, and heat transfers from the heat absorbing particles to the first gas stream, thereby heating the reactants in the gas stream to a sufficiently high temperature so that the first gas stream undergoes the desired reaction(s), thereby producing hydrogen or synthesis gas in the gas stream.

  14. Engineering reactors for catalytic reactions

    Vivek V Ranade


    Catalytic reactions are ubiquitous in chemical and allied industries. A homogeneous or heterogeneous catalyst which provides an alternative route of reaction with lower activation energy and better control on selectivity can make substantial impact on process viability and economics. Extensive studies have been conducted to establish sound basis for design and engineering of reactors for practising such catalytic reactions and for realizing improvements in reactor performance. In this article, application of recent (and not so recent) developments in engineering reactors for catalytic reactions is discussed. Some examples where performance enhancement was realized by catalyst design, appropriate choice of reactor, better injection and dispersion strategies and recent advances in process intensification/ multifunctional reactors are discussed to illustrate the approach.

  15. Enzymatic reactions in dense gases

    Knez, Željko


    The developments on applications of supercritical fluids as alternative solvents for biocatalytic processes that have taken place over the past two decades have been reviewed. An overview of process parameters influencing enzyme activity and stability, the influence of process parameters on reaction rates and productivity are presented. Applications of various types of reactors for enzymatic reaction in dense fluids, limitations of using enzymes as biocatalyst in supercritical fluids as well ...

  16. Psychosocial reactions to physical illness.

    Lipowski, Z J


    Recently medical educators have emphasized the need for physicians to acquire the skills to deal with psychologic aspects of patient care. To facilitate this task a descriptive schema is presented for use in evaluating patients' psychosocial reactions to physical illness. Three core components of such reactions are: the personal meaning of illness, emotional responses to illness and modes of coping with illness. Clinical application of this schema may help with patient management and prevent ...

  17. Drug Reactions in Oral Mucosa

    Emine Derviş


    Full Text Available Both immunologic and nonimmunologic drug reactions can be seen in oral mucosa. Since considerable number of these reactions heals spontaneously without being noticed by the patients, exact frequency of the lesions is unknown. Most common lesions are xerostomia, taste disorders, mucosal ulcerations and edema. In this article, oral lesions resulting from drug intake similar to those from oral lesions of local and systemic diseases, and diagnostic problems caused by these similarities, have been reviewed.

  18. Spatial model of autocatalytic reactions

    De Anna, Pietro; Di Patti, Francesca; Fanelli, Duccio; McKane, Alan J.; Dauxois, Thierry


    Biological cells with all of their surface structure and complex interior stripped away are essentially vesicles - membranes composed of lipid bilayers which form closed sacs. Vesicles are thought to be relevant as models of primitive protocells, and they could have provided the ideal environment for pre-biotic reactions to occur. In this paper, we investigate the stochastic dynamics of a set of autocatalytic reactions, within a spatially bounded domain, so as to mimic a primordial cell. The ...

  19. Polarization phenomena in collinear reactions

    Moravcsik, Michael J.; Arash, Firooz


    It is shown for a collinear reaction containing four particles with arbitrary spins which amplitudes remain nonzero and how they are related to the observables. In terms of primary observables all submatrices relating products of amplitudes to observables either vanish or turn into one-by-one submatrices, except the 8i types which may turn into three-by-three submatrices, but these latter submatrices are mostly avoidable when determining amplitudes. In terms of the secondary observables the 1M and 2i submatrices are slightly larger. Specifically, it is shown that in collinear reactions all observables in which only one particle is polarized (no matter how) vanish. Since reactions at very high energies are expected to be predominantly very close to being collinear, the smallness of such observables in such reactions can be expected on general grounds but polarization effects involving observables with more than one polarized particle can very well be very large. An iterative approximation method for the polarization analysis of reactions at very high energies is suggested. The results of this paper are also applicable to all models in which helicity conservation holds, since they are, for all t values, formally identical with collinear reactions.

  20. Polarization phenomena in collinear reactions

    It is shown for a collinear reaction containing four particles with arbitrary spins which amplitudes remain nonzero and how they are related to the observables. In terms of primary observables all submatrices relating products of amplitudes to observables either vanish or turn into one-by-one submatrices, except the 8/sub i/ types which may turn into three-by-three submatrices, but these latter submatrices are mostly avoidable when determining amplitudes. In terms of the secondary observables the 1/sub M/ and 2/sub i/ submatrices are slightly larger. Specifically, it is shown that in collinear reactions all observables in which only one particle is polarized (no matter how) vanish. Since reactions at very high energies are expected to be predominantly very close to being collinear, the smallness of such observables in such reactions can be expected on general grounds but polarization effects involving observables with more than one polarized particle can very well be very large. An iterative approximation method for the polarization analysis of reactions at very high energies is suggested. The results of this paper are also applicable to all models in which helicity conservation holds, since they are, for all t values, formally identical with collinear reactions

  1. Kinetics of actinide complexation reactions

    Though the literature records extensive compilations of the thermodynamics of actinide complexation reactions, the kinetics of complex formation and dissociation reactions of actinide ions in aqueous solutions have not been extensively investigated. In light of the central role played by such reactions in actinide process and environmental chemistry, this situation is somewhat surprising. The authors report herein a summary of what is known about actinide complexation kinetics. The systems include actinide ions in the four principal oxidation states (III, IV, V, and VI) and complex formation and dissociation rates with both simple and complex ligands. Most of the work reported was conducted in acidic media, but a few address reactions in neutral and alkaline solutions. Complex formation reactions tend in general to be rapid, accessible only to rapid-scan and equilibrium perturbation techniques. Complex dissociation reactions exhibit a wider range of rates and are generally more accessible using standard analytical methods. Literature results are described and correlated with the known properties of the individual ions

  2. Nuclear Reactions for Astrophysics and Other Applications

    Escher, J E; Burke, J T; Dietrich, F S; Scielzo, N D; Ressler, J J


    Cross sections for compound-nuclear reactions are required for many applications. The surrogate nuclear reactions method provides an indirect approach for determining cross sections for reactions on unstable isotopes, which are difficult or impossible to measure otherwise. Current implementations of the method provide useful cross sections for (n,f) reactions, but need to be improved upon for applications to capture reactions.

  3. Reaction rates for a generalized reaction-diffusion master equation

    Hellander, Stefan; Petzold, Linda


    It has been established that there is an inherent limit to the accuracy of the reaction-diffusion master equation. Specifically, there exists a fundamental lower bound on the mesh size, below which the accuracy deteriorates as the mesh is refined further. In this paper we extend the standard reaction-diffusion master equation to allow molecules occupying neighboring voxels to react, in contrast to the traditional approach, in which molecules react only when occupying the same voxel. We derive reaction rates, in two dimensions as well as three dimensions, to obtain an optimal match to the more fine-grained Smoluchowski model and show in two numerical examples that the extended algorithm is accurate for a wide range of mesh sizes, allowing us to simulate systems that are intractable with the standard reaction-diffusion master equation. In addition, we show that for mesh sizes above the fundamental lower limit of the standard algorithm, the generalized algorithm reduces to the standard algorithm. We derive a lower limit for the generalized algorithm which, in both two dimensions and three dimensions, is of the order of the reaction radius of a reacting pair of molecules.

  4. Reaction pathways of propene pyrolysis.

    Qu, Yena; Su, Kehe; Wang, Xin; Liu, Yan; Zeng, Qingfeng; Cheng, Laifei; Zhang, Litong


    The gas-phase reaction pathways in preparing pyrolytic carbon with propene pyrolysis have been investigated in detail with a total number of 110 transition states and 50 intermediates. The structure of the species was determined with density functional theory at B3PW91/6-311G(d,p) level. The transition states and their linked intermediates were confirmed with frequency and the intrinsic reaction coordinates analyses. The elementary reactions were explored in the pathways of both direct and the radical attacking decompositions. The energy barriers and the reaction energies were determined with accurate model chemistry method at G3(MP2) level after an examination of the nondynamic electronic correlations. The heat capacities and entropies were obtained with statistical thermodynamics. The Gibbs free energies at 298.15 K for all the reaction steps were reported. Those at any temperature can be developed with classical thermodynamics by using the fitted (as a function of temperature) heat capacities. It was found that the most favorable paths are mainly in the radical attacking chain reactions. The chain was proposed with 26 reaction steps including two steps of the initialization of the chain to produce H and CH(3) radicals. For a typical temperature (1200 K) adopted in the experiments, the highest energy barriers were found in the production of C(3) to be 203.4 and 193.7 kJ/mol. The highest energy barriers for the production of C(2) and C were found 174.1 and 181.4 kJ/mol, respectively. These results are comparable with the most recent experimental observation of the apparent activation energy 201.9 +/- 0.6 or 137 +/- 25 kJ/mol. PMID:20082392

  5. Capture reactions at low energies

    Some few body capture reaction studies at low energies are reviewed. The emphasis is on the use of polarized beams. New calculations of n+d and p+d capture had just recently been completed by the Los Alamos group (Friar, Gibson, and Payne). Their results are in good agreement with existing data, and emphasize the importance of meson exchange current effects in these processes at thermal energies. The effects of M1 radiation can be seen in the vector analyzing power of the p+d radiative capture reaction from its interference with E1 radiation. The vector analyzing powers of the rvec p+T → 4He + γ reaction can be used to search for M1 radiation in 4He. Low energy data show a substantial b1 coefficient which can only be accounted for with a substantial M1 contribution. The author is also working on studying the rvec d+T and rvec d+3He capture reactions in the region of the fusion resonance. His (published) rvec d+T capture data indicate that the reaction goes via ∼95% S = 3/2, E1 capture with small S = 1/2, E1 and small M1 admixtures. In the course of obtaining the d+T and d+3He data, he realized that he could use his spectra to obtain the ground state widths of 5He and 5Li. Finally, he will discuss the d+d reaction at very low energies. The simplest picture of this reaction dominated by S wave capture to the D-state below 1 MeV

  6. Exchange Reactions. Proceedings of the Symposium on Exchange Reactions

    The mechanisms and kinetics of chemical reactions are of great interest to chemists. The study of exchange reactions in particular helps to shed light on the dynamics of chemical change, providing an insight into the structures and the reactivities of the chemical species involved. The main theme of this meeting was the subject of oxidation-reduction reactions in which the net result is the transfer of one or more electrons between the different oxidation states of the same element. Other studies reported included the transfer of protons, atoms, complex ligands or organic radicals between molecules. Heterogeneous exchange, which is of importance in many cases of catalytic action, was also considered. For a long time isotopic tracers have formed the most convenient means of studying exchange reactions and today a considerable amount of work continues to be done with their aid. Consequently, several papers presented at this Symposium reported on work carried out by purely radiochemical tracer methods. In recognition, however, of the important role which nuclear magnetic resonance and electron spin resonance play in this field, in particular in the study of fast reactions, a number of reports on investigations in which these techniques had been used was included in the programme. By kind invitation of the United States Government the Symposium on Exchange Reactions was held from 31 May to 4 June at the Brookhaven National Laboratory, Upton, Long Island, N.Y., USA. It was attended by 46 participants from nine countries and one inter-governmental organization. The publication of these Proceedings makes the contents of the papers and the discussion available to a wider audience

  7. Carbonitriding reactions of diatomaceous earth: phase evolution and reaction mechanisms



    Full Text Available The possibility of using diatomaceous earth as Si precursor for low temperature synthesis of non-oxide powders by carbothermal reduction-nitridation was studied. It was found that carbonitriding reactions produce phases of the Si–Al–O–N system. Already at 1300 °C, nanosized, non-oxide powders were obtained. The comparatively low reaction temperatures is attributred to the nano-porous nature of the raw material. The evolution of crystalline phases proceeded via many intermediate stages. The powders were characterized by X-ray and SEM investigations. The results showed that diatomaceous earth can be a very effective source for obtaining non-oxide powders.

  8. A comprehensive survey of nuclear reactions; Panorama des reactions nucleaires

    Cugnon, J. [Liege Univ., IFPA, AGO Dept. (Belgium)


    The various mechanisms of nuclear reactions are surveyed and classified in different regimes, based on the notions of coherent mechanisms and hard versus soft processes. The emphasis is put on the concepts at the basis of the understanding of these regimes and on the elements of nuclear structure which are involved in these different regimes, as well as the on the possibility of extracting this information. Due to lack of space and for pedagogical reasons, the discussion is limited to nucleon-induced and light-ion-induced reactions. However, a few remarks are given concerning some specific probes, such as weakly bound projectiles or neutron-rich nuclei. (author)

  9. Modeling of fluctuating reaction networks

    Full Text:Various dynamical systems are organized as reaction networks, where the population size of one component affects the populations of all its neighbors. Such networks can be found in interstellar surface chemistry, cell biology, thin film growth and other systems. I cases where the populations of reactive species are large, the network can be modeled by rate equations which provide all reaction rates within mean field approximation. However, in small systems that are partitioned into sub-micron size, these populations strongly fluctuate. Under these conditions rate equations fail and the master equation is needed for modeling these reactions. However, the number of equations in the master equation grows exponentially with the number of reactive species, severely limiting its feasibility for complex networks. Here we present a method which dramatically reduces the number of equations, thus enabling the incorporation of the master equation in complex reaction networks. The method is examplified in the context of reaction network on dust grains. Its applicability for genetic networks will be discussed. 1. Efficient simulations of gas-grain chemistry in interstellar clouds. Azi Lipshtat and Ofer Biham, Phys. Rev. Lett. 93 (2004), 170601. 2. Modeling of negative autoregulated genetic networks in single cells. Azi Lipshtat, Hagai B. Perets, Nathalie Q. Balaban and Ofer Biham, Gene: evolutionary genomics (2004), In press

  10. Combustion kinetics and reaction pathways

    Klemm, R.B.; Sutherland, J.W. [Brookhaven National Laboratory, Upton, NY (United States)


    This project is focused on the fundamental chemistry of combustion. The overall objectives are to determine rate constants for elementary reactions and to elucidate the pathways of multichannel reactions. A multitechnique approach that features three independent experiments provides unique capabilities in performing reliable kinetic measurements over an exceptionally wide range in temperature, 300 to 2500 K. Recent kinetic work has focused on experimental studies and theoretical calculations of the methane dissociation system (CH{sub 4} + Ar {yields} CH{sub 3} + H + Ar and H + CH{sub 4} {yields} CH{sub 3} + H{sub 2}). Additionally, a discharge flow-photoionization mass spectrometer (DF-PIMS) experiment is used to determine branching fractions for multichannel reactions and to measure ionization thresholds of free radicals. Thus, these photoionization experiments generate data that are relevant to both reaction pathways studies (reaction dynamics) and fundamental thermochemical research. Two distinct advantages of performing PIMS with high intensity, tunable vacuum ultraviolet light at the National Synchrotron Light Source are high detection sensitivity and exceptional selectivity in monitoring radical species.

  11. Optimization of Reaction Conditions for Preparing Carboxymethylcellulose

    S. Nilus; L.M. Chng; Bono, A; A.C.R. Valintinus; N.M. Ismail


    The cellulose powder was converted to carboxymethylcellulose (CMC) by etherification process using sodium monochloroacetate and sodium hydroxide. There are two reaction occur simultaneously during carboxymethylation that are the primary reaction which produces pure CMC and side reaction that produces undesired sodium glycolate. The carboxymethylation reaction was optimized against the reaction temperature, reaction time, SMCA concentration, NaOH concentration and the ratio solvent of ethanol:...

  12. Adverse Reactions to Radiographic Contrast Material

    Bush, William H.; Mullarkey, Michael F.; Webb, D. Robert


    Major adverse reactions to radiographic contrast media will occur more often as contrast material is now also administered during computerized tomographic (CT) scanning. Differentiation of the two major contrast reactions, the vagus reaction and the anaphylactoid reaction, is essential. Bradycardia is the key finding for identifying the vagus reaction. The vagus reaction involving hypotension and bradycardia requires treatment with large doses of atropine given intravenously. The immediate ge...

  13. The Reaction of Acenaphthene with Nitrobenzene


    The reaction of acenaphthene with nitrobenzene was investigated in the presence of AlCl3 . The results showed that the reaction proceeded via carboncation-electrophilic substitution reaction and free radical substitution reaction pathway. The products of acenaphthenyl phenylamine and biacenaphthyl could be synthesized by this reaction. The influence of the amount of AlCl3 and the temperature on the components of products were also studied in this reaction.

  14. Anaphylactoid reactions to radiocontrast media.

    Canter, Lauren M


    As the role for diagnostic and therapeutic contrast-enhanced imaging increases, review of the epidemiology, mechanisms, risk factors, and pretreatment for radiocontrast-mediated anaphylactoid reactions becomes more and more pertinent. Ongoing research has failed to elucidate the precise mechanisms of both early and late reactions, though the current data point to a multifactorial pathogenesis. The risk of reactions has decreased over time as contrast media have evolved from ionic, high-osmolality to nonionic, low-osmolality formulations; however, the expense of the low-osmolality agents limit their universal use. Today, 1-12% of patients exhibit adverse responses ranging from mild to severe, with individual risk depending on the type of contrast administered and certain baseline patient characteristics. For those high-risk patients who must receive contrast, effective pretreatment guidelines have been established. PMID:16119034

  15. Postcolumn reaction detectors for HPLC

    Frei, R.W.; Jansen, H.; Brinkman, U.A.T.


    Currently, the best and most reliable HPLC (high-performance liquid chromatography) detectors are UV-VIS absorbance, fluorescence, and electrochemical detectors. It is attractive to try to expand their range of application by using suitable chemical derivatization techniques to convert the analytes of interest with their originally poor detection properties into compounds that can be detected with high sensitivity with these detectors. Besides an improvement of the detection properties, the chemical reaction can also enhance the selectivity of the total analytical method. The derivatization can be carried out either prior to the HPLC separation or by doing the reaction in an on-line postcolumn mode. Comparative advantages and disadvantages of these two approaches have been discussed previously. This paper will discuss on-line postcolumn derivatization. A general scheme of an HPLC system equipped with an on-line postcolumn reaction detector is given. 40 references, 6 figures, 2 tables.

  16. Photonuclear reactions on titanium isotopes

    Belyshev, S. S. [Moscow State University (Russian Federation); Dzhilavyan, L. Z. [Russian Academy of Sciences, Institute for Nuclear Research (Russian Federation); Ishkhanov, B. S.; Kapitonov, I. M. [Moscow State University (Russian Federation); Kuznetsov, A. A., E-mail:; Orlin, V. N.; Stopani, K. A. [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)


    The photodisintegration of titanium isotopes in the giant-dipole-resonance energy region is studied by the photon-activation method. Bremsstrahlung photons whose spectrum has the endpoint energy of 55 MeV is used. The yields and integrated cross sections are determined for photoproton reactions on the titanium isotopes {sup 47,48,49,50}Ti. The respective experimental results are compared with their counterparts calculated on the basis of the TALYS code and a combined photonucleon-reaction model. The TALYS code disregards the isospin structure of the giant dipole resonance and is therefore unable to describe the yield of photoproton reactions on the heavy titanium isotopes {sup 49,50}Ti.

  17. Catalytic, enantioselective, vinylogous aldol reactions.

    Denmark, Scott E; Heemstra, John R; Beutner, Gregory L


    In 1935, R. C. Fuson formulated the principle of vinylogy to explain how the influence of a functional group may be felt at a distant point in the molecule when this position is connected by conjugated double-bond linkages to the group. In polar reactions, this concept allows the extension of the electrophilic or nucleophilic character of a functional group through the pi system of a carbon-carbon double bond. This vinylogous extension has been applied to the aldol reaction by employing "extended" dienol ethers derived from gamma-enolizable alpha,beta-unsaturated carbonyl compounds. Since 1994, several methods for the catalytic, enantioselective, vinylogous aldol reaction have appeared, with which varying degrees of regio- (site), enantio-, and diastereoselectivity can be attained. In this Review, the current scope and limitations of this transformation, as well as its application in natural product synthesis, are discussed. PMID:15940727

  18. Spatial model of autocatalytic reactions

    de Anna, Pietro; di Patti, Francesca; Fanelli, Duccio; McKane, Alan J.; Dauxois, Thierry


    Biological cells with all of their surface structure and complex interior stripped away are essentially vesicles—membranes composed of lipid bilayers which form closed sacs. Vesicles are thought to be relevant as models of primitive protocells, and they could have provided the ideal environment for prebiotic reactions to occur. In this paper, we investigate the stochastic dynamics of a set of autocatalytic reactions, within a spatially bounded domain, so as to mimic a primordial cell. The discreteness of the constituents of the autocatalytic reactions gives rise to large sustained oscillations even when the number of constituents is quite large. These oscillations are spatiotemporal in nature, unlike those found in previous studies, which consisted only of temporal oscillations. We speculate that these oscillations may have a role in seeding membrane instabilities which lead to vesicle division. In this way synchronization could be achieved between protocell growth and the reproduction rate of the constituents (the protogenetic material) in simple protocells.

  19. Direct-reaction and isospin symmetries in d + d reactions

    We have measured angular distributions of the analyzing powers A/sub y/, A/sub x/x, A/sub y/y, and A/sub x/z for the 2H(d,p)3H reaction at deuteron lab energies E/sub d/ of 13.39 and 17.00 MeV. These distributions do not show the symmetry or antisymmetry about 900 (c.m.) expected on the basis of a simple direct-neutron-transfer reaction mechanism. In a companion experiment, we have measured the same four analyzing powers for both the 2H(d,p)3H reaction and its charge-symmetric partner 2H(d,n)3He at E/sub d/ = 15.50 and 17.00 MeV in a restricted angular range. These latter data were obtained by simultaneously detecting the tritons and helions. Only small differences were observed in the respective analyzing powers for the two reactions, which suggests a weakening of the mechanism responsible for the larger differences found by others at lower energies

  20. Fundamentals of chemical reaction engineering

    Davis, Mark E


    Appropriate for a one-semester undergraduate or first-year graduate course, this text introduces the quantitative treatment of chemical reaction engineering. It covers both homogeneous and heterogeneous reacting systems and examines chemical reaction engineering as well as chemical reactor engineering. The authors take a chemical approach, helping students develop an intuitive feeling for concepts, rather than an engineering approach, which tends to overlook the inner workings of systems and objects.Each chapter contains numerous worked-out problems and real-world vignettes involving commercia

  1. Interface reactions in film materials

    Fengwu Zhu; Zhonghai Zhai; Guanghua Yu


    Interface reaction (IR) is a frequently observed phenomenon in the study of advanced thin film materials. It is very important to study the reaction conditions at which IR happens and then to suppress or make use of it, the necessary conditions, including both thermodynamical and dynamical conditions of IR were discussed in detail. IRs in various systems, including oxide/silicon,oxide/metal, metal/metal, metal/semiconductor and semiconductor/semiconductor, were reviewed. Methods to suppress and make use of IR were also introduced.

  2. Vision 2020. Reaction Engineering Roadmap

    Klipstein, David H. [Reaction Design, San Diego, CA (United States); Robinson, Sharon [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)


    The Reaction Engineering Roadmap is a part of an industry- wide effort to create a blueprint of the research and technology milestones that are necessary to achieve longterm industry goals. This report documents the results of a workshop focused on the research needs, technology barriers, and priorities of the chemical industry as they relate to reaction engineering viewed first by industrial use (basic chemicals; specialty chemicals; pharmaceuticals; and polymers) and then by technology segment (reactor system selection, design, and scale-up; chemical mechanism development and property estimation; dealing with catalysis; and new, nonstandard reactor types).

  3. Hadronic model for the consistent description of the scattering and annihilation of the antinucleon-nucleon system

    In this work a consistent description of the anti NN scattering and annihilation with a hadronic model is presented. The elastic anti NN interaction is obtained from the Bonn NN potential via a G-parity transformation. For the annihilation part, a consistent, partly microscopic description is constructed treating the most important two meson channels explicitly and accounting for the rest by a phenomenological optical potential of Gaussian form. Transitions from the antibaryon-baryon sector to the meson sector are mediated via the exchange of N, Δ, Λ, Σ and Y* baryons. anti NN scattering observables, branching ratios and cross sections for the annihilation into two mesons and bound states are calculated consistently. Results are compared with former calculations and the experimental data. The agreement with the data is good. The importance of meson-meson interactions in the final state is studied at the example of the particular annihilation channel anti NN → ππ. A full coupled channels calculation with the channels anti NN, ππ, anti KK and ρρ is performed. Interactions and transitions in the meson sector are described by meson-exchange diagrams. Integrated as well as differential cross sections and analyzing powers for the annihilation process anti NN → ππ are described with good quality. Results of the coupled channels model for ππ phase shifts and inelasticities above the anti NN threshold are discussed. Effects of the meson-meson interactions on anti NN scattering observables are small. The importance of two-step processes and meson-meson interactions in the final state for the description of the angle-dependent observables in the annihilation process anti NN → ππ can be demonstrated. (orig.)

  4. Reactions

    Søndergaard, Morten


    ) museum. Augmentation, in this expanding digital field, is part of a production of new public spaces, as well as a new reality that affects and traverses art and institutions immanently and througout. The expanding digital field is transforming art and the art museum in a number of fundamental ways, a few......; It is in this negotiation, I would claim, that the foundation of a possible critique of the role of the (art) museum in the age of post-bourgeois public space and experience-based culture should be located....

  5. Reduction of chemical reaction models

    Frenklach, Michael


    An attempt is made to reconcile the different terminologies pertaining to reduction of chemical reaction models. The approaches considered include global modeling, response modeling, detailed reduction, chemical lumping, and statistical lumping. The advantages and drawbacks of each of these methods are pointed out.

  6. Reactions of ethanol on Ru

    Sturm, J. M.; Lee, C. J.; F. Bijkerk,


    The adsorption and reactions of ethanol on Ru(0001) were studied with temperature-programmed desorption (TPD) and reflection-absorption infrared spectroscopy (RAIRS). Ethanol was found to adsorb intact onto Ru(0001) below 100 K. From 175 K to 200 K, ethanol is converted into ethoxy groups, which und

  7. Exchange effects in direct reactions

    The effect of antisymmetrization in direct reactions is examined by studying the properties of the coupling-normalization kernel function occurring in a resonating-group formulation. From this study, one obtains useful information concerning the general behavior of direct-reactiion processes and some justification for the use of three-body models in phenomenological analyses

  8. Recyclization reactions leading to benzimidazoles

    Mamedov, Vakhid A; Murtazina, Anna M [A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the Russian Academy of Sciences, Kazan (Russian Federation)


    The published data on the recyclization reactions that afford benzimidazoles are generalized and systematized. Both classical and new methods of benzimidazole synthesis are considered. Attention is focused on the publications over the recent 10-15 years; of the earlier publications, only those unknown to the wide circle of chemists are analyzed.

  9. Multispecies reaction-diffusion systems

    Aghamohammadi, A.; Fatollahi, A. H.; Khorrami, M.; Shariati, A.


    Multispecies reaction-diffusion systems, for which the time evolution equation of correlation functions become a closed set, are considered. A formal solution for the average densities is found. Some special interactions and the exact time dependence of the average densities in these cases are also studied. For the general case, the large time behaviour of the average densities has also been obtained.

  10. Apparent tunneling in chemical reactions

    Henriksen, Niels Engholm; Hansen, Flemming Yssing; Billing, G. D.


    A necessary condition for tunneling in a chemical reaction is that the probability of crossing a barrier is non-zero, when the energy of the reactants is below the potential energy of the barrier. Due to the non-classical nature (i.e, momentum uncertainty) of vibrational states this is, however...

  11. Apparent tunneling in chemical reactions

    Henriksen, Niels Engholm; Hansen, Flemming Yssing; Billing, G. D.

    A necessary condition for tunneling in a chemical reaction is that the probability of crossing a barrier is non-zero, when the energy of the reactants is below the potential energy of the barrier. Due to the non-classical nature (i.e, momentum uncertainty) of vibrational states this is, however...

  12. Knoevenagel Reaction of Unprotected Sugars

    Scherrmann, Marie-Christine

    The Knoevenagel reaction of unprotected sugars was investigated in the 1950s using zinc chloride as promoter. The so-called Garcia Gonzalez reaction had been almost forgotten for 50 years, until the emergence of new water tolerant catalysts having Lewis acid behavior. The reaction was thus reinvestigated and optimal conditions have been found to prepare trihydroxylated furan derivatives from pentose or β-tetrahydrofuranylfuran from hexoses with non-cyclic β-keto ester or β-diketones. Other valuable compounds such as β-linked tetrahydrobenzofuranyl glycosides or hydroxyalkyl-3,3,6,6,-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione can be obtained using cyclic β-dicarbonylic derivatives. Apart from one report in the 1950s, the Knoevenagel reaction of unprotected carbohydrate in basic condition has been studied only in the mid-1980s to prepare C-glycosyl barbiturates from barbituric acids and, later on, from non-cyclic β-diketones, β-C-glycosidic ketones. The efficient method exploited to prepare such compounds has found an industrial development in cosmetics.

  13. Reactants encapsulation and Maillard Reaction

    Troise, A.D.; Fogliano, V.


    In the last decades many efforts have been addressed to the control of Maillard Reaction products in different foods with the aim to promote the formation of compounds having the desired color and flavor and to reduce the concentration of several potential toxic molecules. Encapsulation, already app

  14. Quantum Tunneling and Back Reaction

    Banerjee, Rabin; Majhi, Bibhas Ranjan


    We give a correction to the tunneling probability by taking into account the back reaction effect to the metric of the black hole spacetime. We then show how this gives rise to the modifications in the semiclassical black hole entropy and Hawking temperature. Finally, we reproduce the familiar logarithmic correction to the Bekenstein-Hawking area law.

  15. Detecting deception through reaction times

    B. Verschuere; K. Suchotzki; E. Debey


    Reaction times (RTs) are among the oldest measures in psychology, and remain popular in several psychology disciplines. However, they have been largely neglected as a cue for deception, reflecting the sceptic's view that RTs fall under voluntary control and are easily manipulated. From our review of

  16. Strangeness exchange reactions and hypernuclei

    Recent progress in the spectroscopy of Λ and Σ hypernuclei is reviewed. Prospects for the production of doubly strange hypernuclei at a future kaon factory are assessed. It is suggested that the (K-,K+) reaction on a nuclear target may afford an optimal way of producing the H dibaryon, a stable six quark object with J/sup π/ = O+, S = -2

  17. Reaction of alkylcobalamins with thiols

    Carbon-13 NMR spectroscopy and phosphorus-31 NMR spectroscopy have been used to study the reaction of several alkylcobalamins with 2-mercaptoethanol. At alkaline pH, when the thiol is deprotonated, the alkyl-transfer reactions involve a nucleophilic attack of the thiolate anion on the Co-methylene carbon of the cobalamins, yielding alkyl thioethers and cob(II)alamin. In these nucleophilic displacement reactions cob(I)alamin is presumably formed as an intermediate. The higher alkylcobalamins react more slowly than methylcobalamin. The lower reactivity of ethyl- and propylcobalamin is probably the basis of the inhibition of the corrinoid-dependent methyl-transfer systems by propyl iodide. The transfer of the upper nucleoside ligand of adenosylcobalamin to 2-mercaptoethanol is a very slow process; S-adenosylmercaptoethanol and cob(II)alamin are the final products of the reaction. The dealkylation of (carboxymethyl)cobalamin is a much more facile reaction. At alkaline pH S-(carboxymethyl)mercaptoethanol and cob(II)alamin are produced, while at pH values below 8 the carbon-cobalt bond is cleaved reductively to acetate and cob(II)alamin. The reductive cleavage of the carbon-cobalt bond of (carboxymethyl)cobalamin by 2-mercaptoethanol is extremely fast when the cobalamin is in the base-off form. Because the authors have been unable to detect trans coordination of 2-mercaptoethanol, they favor a mechanism that involves a hydride attack on the Co-methylene carbon of (carboxymethyl) rather than a trans attack of the thiol on the cobalt atom

  18. Experimental Demonstrations in Teaching Chemical Reactions.

    Hugerat, Muhamad; Basheer, Sobhi


    Presents demonstrations of chemical reactions by employing different features of various compounds that can be altered after a chemical change occurs. Experimental activities include para- and dia-magnetism in chemical reactions, aluminum reaction with base, reaction of acid with carbonates, use of electrochemical cells for demonstrating chemical…

  19. Exact Results for Kinetics of Catalytic Reactions

    Frachebourg, L.; Krapivsky, P. L.


    The kinetics of an irreversible catalytic reaction on substrate of arbitrary dimension is examined. In the limit of infinitesimal reaction rate (reaction-controlled limit), we solve the dimer-dimer surface reaction model (or voter model) exactly in arbitrary dimension $D$. The density of reactive interfaces is found to exhibit a power law decay for $D


    Hiren M. Marvaniya


    Full Text Available The toxicity and volatile nature of many organic solvents, particularly chlorinated hydrocarbons that are widely used in huge amounts for organic reactions have posed a serious threat to the environment. Thus, design of solventless catalytic reaction has received tremendous attention in recent times in the area of green synthesis. A solvent-free or solid state reaction may be carried out using the reactants alone or incorporating them in clays, zeolites, silica, alumina or other matrices to achieve high degree of stereoselectivity in the products, to reduce byproducts, to maximize rate of reaction. We illustrate the environmentally benign approach to 1,2-Oxazine-2- oxides, Michael addition, Wohl–Ziegler reaction, Acylation, Heck reaction, Tishchenko reaction, Diels– Alder reaction, Reformatsky and Luche Reaction, Oxidative coupling Reaction, Synthesis of chalcones, Synthesis of Dihydropyrimidinones

  1. Thermodynamics of Enzyme-Catalyzed Reactions Database

    SRD 74 Thermodynamics of Enzyme-Catalyzed Reactions Database (Web, free access)   The Thermodynamics of Enzyme-Catalyzed Reactions Database contains thermodynamic data on enzyme-catalyzed reactions that have been recently published in the Journal of Physical and Chemical Reference Data (JPCRD). For each reaction the following information is provided: the reference for the data, the reaction studied, the name of the enzyme used and its Enzyme Commission number, the method of measurement, the data and an evaluation thereof.

  2. Investigating Reaction-Driven Cracking

    Kelemen, P. B.; Hirth, G.; Savage, H. M.


    Many metamorphic reactions lead to large volume changes, and potentially to reaction-driven cracking [1,2]. Large-scale hydration of mantle peridotite to produce serpentine or talc is invoked to explain the rheology of plate boundaries, the nature of earthquakes, and the seismic properties of slow-spread ocean crust and the 'mantle wedge' above subduction zones. Carbonation of peridotite may be an important sink in the global carbon cycle. Zones of 100% magnesite + quartz replacing peridotite, up to 200 m thick, formed where oceanic mantle was thrust over carbonate-bearing metasediments in Oman. Talc + carbonate is an important component of the matrix in subduction mélanges at Santa Catalina Island , California, and the Sanbagawa metamorphic belt, Japan. Engineered systems to emulate natural mineral carbonation could provide relatively inexpensive CO2 capture and storage [3]. More generally, engineered reaction-driven cracking could supplement or replace hydraulic fracture in geothermal systems, solution mining, and extraction of tight oil and gas. The controls on reaction-driven cracking are poorly understood. Hydration and carbonation reactions can be self-limiting, since they potentially reduce permeability and armor reactive surfaces [4]. Also, in some cases, hydration or carbonation may take place at constant volume. Small changes in volume due to precipitation of solid products increases stress, destabilizing solid reactants, until precipitation and dissolution rates become equal at a steady state stress [5]. In a third case, volume change due to precipitation of solid products causes brittle failure. This has been invoked on qualitative grounds to explain, e.g., complete serpentinization of mantle peridotite [6]. Below ~ 300°C, the available potential energy for hydration and carbonation of olivine could produce stresses of 100's of MPa [2], sufficient to fracture rocks to 10 km depth or more, causing brittle failure below the steady state stress required

  3. Relativistic Formulation of Reaction Theory

    Polyzou, W N


    A relativistic formulation of reaction theory for nuclei with a dynamics given by a unitary representations of the Poincar\\'e group is developed. Relativistic dynamics is introduced by starting from a relativistic theory of free particles to which rotationally invariant interactions are added to the invariant mass operator. Poincar\\'e invariance is realized by requiring that simultaneous eigenstates of the mass and spin transform as irreducible representations of the Poincar\\'e group. A relativistic formulation of scattering theory is presented and approximations emphasizing dominant degrees of freedom that preserve unitarity, exact Poincar\\'e invariance and exchange symmetry are discussed. A Poincar\\'e invariant formulation of a (d,p) reaction as a three-body problem is given as an explicit example.

  4. Programmability of Chemical Reaction Networks

    Cook, Matthew; Soloveichik, David; Winfree, Erik; Bruck, Jehoshua

    Motivated by the intriguing complexity of biochemical circuitry within individual cells we study Stochastic Chemical Reaction Networks (SCRNs), a formal model that considers a set of chemical reactions acting on a finite number of molecules in a well-stirred solution according to standard chemical kinetics equations. SCRNs have been widely used for describing naturally occurring (bio)chemical systems, and with the advent of synthetic biology they become a promising language for the design of artificial biochemical circuits. Our interest here is the computational power of SCRNs and how they relate to more conventional models of computation. We survey known connections and give new connections between SCRNs and Boolean Logic Circuits, Vector Addition Systems, Petri nets, Gate Implementability, Primitive Recursive Functions, Register Machines, Fractran, and Turing Machines. A theme to these investigations is the thin line between decidable and undecidable questions about SCRN behavior.

  5. Nuclear Reactions from Lattice QCD

    Briceño, Raúl A; Luu, Thomas C


    One of the overarching goals of nuclear physics is to rigorously compute properties of hadronic systems directly from the fundamental theory of strong interactions, Quantum Chromodynamics (QCD). In particular, the hope is to perform reliable calculations of nuclear reactions which will impact our understanding of environments that occur during big bang nucleosynthesis, the evolution of stars and supernovae, and within nuclear reactors and high energy/density facilities. Such calculations, being truly ab initio, would include all two-nucleon and three- nucleon (and higher) interactions in a consistent manner. Currently, lattice QCD provides the only reliable option for performing calculations of some of the low- energy hadronic observables. With the aim of bridging the gap between lattice QCD and nuclear many-body physics, the Institute for Nuclear Theory held a workshop on Nuclear Reactions from Lattice QCD on March 2013. In this review article, we report on the topics discussed in this workshop and the path ...

  6. Radiation Reaction on Brownian Motions

    Seto, Keita


    Tracking the real trajectory of a quantum particle is one of the interpretation problem and it is expressed by the Brownian (stochastic) motion suggested by E. Nelson. Especially the dynamics of a radiating electron, namely, radiation reaction which requires us to track its trajectory becomes important in the high-intensity physics by PW-class lasers at present. It has been normally treated by the Furry picture in non-linear QED, but it is difficult to draw the real trajectory of a quantum particle. For the improvement of this, I propose the representation of a stochastic particle interacting with fields and show the way to describe radiation reaction on its Brownian motion.

  7. Electrochemical promotion of catalytic reactions

    Imbihl, R.


    The electrochemical promotion of heterogeneously catalyzed reactions (EPOC) became feasible through the use of porous metal electrodes interfaced to a solid electrolyte. With the O 2- conducting yttrium stabilized zirconia (YSZ), the Na + conducting β″-Al 2O 3 (β-alumina), and several other types of solid electrolytes the EPOC effect has been demonstrated for about 100 reaction systems in studies conducted mainly in the mbar range. Surface science investigations showed that the physical basis for the EPOC effect lies in the electrochemically induced spillover of oxygen and alkali metal, respectively, onto the surface of the metal electrodes. For the catalytic promotion effect general concepts and mechanistic schemes were proposed but these concepts and schemes are largely speculative. Applying surface analytical tools to EPOC systems the proposed mechanistic schemes can be verified or invalidated. This report summarizes the progress which has been achieved in the mechanistic understanding of the EPOC effect.

  8. Modelling of biochemical reaction networks

    Gloppen Jørgensen, Arne Gunnar


    This report investigates signalling in reaction kinetic networks. The main topic is signalling between a substance being controlled by another substance and how this can be related to control theory. Different types of so-called natural controllers are compared and certain properties are investigated. Natural controllers are models on how a catalyst enzyme controls, for example the concentration, of a substance. There are sixteen different combinations of signalling between these substanc...

  9. Pion production reaction near threshold

    The differential cross section of the 40Ca(p,π+)41Ca reaction has been measured. The energy dependence of pion production near threshold has been studied at constant transferred momentum. The cross-section decreases by a factor 7, for proton energies varying from 154 to 149MeV (E(π) varies from 17.4 to 12.4MeV). The results are analyzed in the framework of the one nucleon mechanism

  10. Anaphylactic reaction to intravenous diclofenac

    Ranju Singh


    Full Text Available Diclofenac sodium is a non-steroidal anti-inflammatory drug widely used as an opioid sparing agent for postoperative analgesia. Anaphylaxis due to intravenous diclofenac sodium is very rare. We report a case of anaphylactic reaction to IV diclofenac sodium, occurring postoperatively in a 25-year-old primigravida, the clinical features of which mimicked pulmonary embolism. The rarity, clinical importance and the diagnostic dilemma associated prompted us to report this case.

  11. Laser-induced chemical reactions

    A classical model for the interaction of laser radiation with a molecular system is derived. This model is used to study the enhancement of a chemical reaction via a collision induced absorption. It was found that an infrared laser will in general enhance the rate of a chemical reaction, even if the reactants are infrared inactive. Results for an illustrative analytically solvable model are presented, as well as results from classical trajectory studies on a number of systems. The collision induced absorption spectrum in these systems can be written as the Fourier transform of a particular dipole correlation function. This is used to obtain the collision induced absorption spectrum for a state-selected, mono-energetic reactive collision system. Examples treated are a one-dimensional barrier problem, reactive and nonreactive collisions of H + H2, and a modified H + H2 potential energy surface which leads to a collision intermediate. An extension of the classical model to treat laser-induced electronically nonadiabatic collision processes is constructed. The model treats all degrees of freedom, molecular, electronic and radiation, in a dynamically consistent framework within classical mechanics. Application is made to several systems. Several interesting phenomena are discovered including a Franck-Condon-like effect causing maxima in the reaction probability at energies much below the classical threshold, laser de-enhancement of chemical reactions and an isotope effect. In order to assess the validity of the classical model for electronically nonadiabatic process (without a laser field), a model problem involving energy transfer in a collinear atom-diatom system is studied, and the results compared to the available quantum mechanical calculation. The calculations are in qualitative agreement

  12. Adverse Reactions of Ferric Carboxymaltose

    Thanusubramanian, Harish; Patil, Navin; Shenoy, Smita; Bairy, K. L.; Sarma, Yashdeep


    The author reports a 55-year-old female diagnosed of chronic kidney disease grade-5 with associated co-morbidities like type 2 diabetes mellitus, diabetic retinopathy and hypothyroidism was admitted for arteriovenous fistula construction. She was started on ferric carboxymaltose for the treatment of anaemia. She was given a test dose before administering the drug intravenously and she did not develop any reaction. The drug ferric carboxymaltose was then administered over a period of one hour....

  13. Cellular reactions to patterned biointerfaces

    Schulte, Vera Antonie


    The subject of this thesis is to study cellular reactions to topographically, mechanically and biochemically tunable polymeric biomaterials. Different aspects of in vitro cell-biomaterial interactions were systematically studied with the murine fibroblast cell line NIH L929 and primary human dermal fibroblasts (HDFs). Besides a general cytocompatibility assessment of the applied materials and the quantification of cell adhesion per se, cell morphological changes (e.g. cell spreading) and intr...

  14. Statistical theory of breakup reactions

    We propose an alternative for Coupled-Channels calculations with loosely bound exotic nuclei (CDCC), based on the the Random Matrix Model of the statistical theory of nuclear reactions. The coupled channels equations are divided into two sets. The first set, described by the CDCC, and the other set treated with RMT. The resulting theory is a Statistical CDCC (CDCCs), able in principle to take into account many pseudo channels. (author)

  15. Statistical theory of nuclear reactions

    Statistical theory of nuclear reactions is briefly reviewed with the emphasis on the underlying physical basis and, in particular, on the role of the quantum chaos. Hauser-Feshbach formula and its improvements, to account for the widths fluctuation effects are discussed. The Heidelberg solution to the Compound Nucleus problem - the three-fold integral is presented. Finally, a list of selected statistical model codes, along with their short characteristics, is given. (author)

  16. Statistical Theory of Breakup Reactions

    Bertulani, Carlos A; Hussein, Mahir S


    We propose alternatives to coupled-channels calculations with loosely-bound exotic nuclei (CDCC), based on the the random matrix (RMT) and the optical background (OPM) models for the statistical theory of nuclear reactions. The coupled channels equations are divided into two sets. The first set, described by the CDCC, and the other set treated with RMT. The resulting theory is a Statistical CDCC (CDCC$_S$), able in principle to take into account many pseudo channels.




    The concept of nanochemistry and the reactions involved are discussed. The work is focused on nanoparticles obtained from colloidal dispersions. The colloidal particles by transmission electron microscopy of low and high resolution were analyzed. The high resolution electron miscroscopy (HRTEM) allow us to classify the nanostructure of the metal particles in some polyhedral models: cubooctahedron, truncated octahedron, tetracai decahedron and icosahedron. Some HRTEM of Pd-2 propanol and Ge-2-...

  18. Stickland reactions of dental plaque.

    Curtis, M A; Kemp, C W; Robrish, S A; Bowen, W H


    Dental plaque samples from monkeys (Macaca fascicularis) were shown to contain proline reduction activity in coupled Stickland reactions with other amino acids and also with certain end products of bacterial glucose metabolism. The unusually high concentration of bound and free proline in the oral environment may be of importance in both the production of base and in the removal of acid from the tooth surface after dietary carbohydrate ingestion.

  19. Tuberculin reaction and BCG scar

    Timmermann, Clara Amalie Gade; Biering-Sørensen, Sofie; Aaby, Peter;


    rate ratio (MRR) comparing children with a BCG scar with those without was 0.42 (95% CI = 0.19; 0.93). There was a similar tendency for TST positivity: MRR = 0.47 (95% CI = 0.14; 1.54). For LBW children who had both a positive TST reaction and a scar, the MRR was 0.22 (95% CI = 0.05; 0.87). For NBW...

  20. Kinetics of nitroxyl radical reactions

    Absolute rate-constants for the reaction of the nitroxyl free radicals TAN and TMPN with radiation-chemically-formed radicals and ions have been determined. k(TAN + X) (in M-1 sec-1) = 4.0 x 109 (for X =OH), 2.9 x 1010(esub(aq)-), 8.0 x 109 (H), 7.2 x 108 (CH2OH), 4.0 x 108 (CH3CHOH), 4.3 x 108 ((CH3)2COH), 2.8 x 108 (CH2(CH3)2COH), 5.9 x 107 (glucose radical), 4.0 x 108 (c-C5H9), and k(TMPN + X) = 3.4 x 109 (OH), 7.8 x 109 (esub(aq)-), 4.9 x 109 (H), 4.4 x 108 (CH2OH), 4.9 x 108 (CH3CHOH), 3.6 x 108 ((CH3)2COH), 1.5 x 108 (CH2(CH3)2COH), 4.9 x 107 (glucose radical), 4.3 x 108 (c-C5H9). Direct measurements by means of a pulse-radiolysis conductivity technique were based on the formation and destruction of charged species in these reactions within certain pH ranges. It is indicated that the radiosensitizing nitroxyles undergo both redox and addition reactions. (author)

  1. Modelling Chemical Reasoning to Predict Reactions

    Segler, Marwin H S


    The ability to reason beyond established knowledge allows Organic Chemists to solve synthetic problems and to invent novel transformations. Here, we propose a model which mimics chemical reasoning and formalises reaction prediction as finding missing links in a knowledge graph. We have constructed a knowledge graph containing 14.4 million molecules and 8.2 million binary reactions, which represents the bulk of all chemical reactions ever published in the scientific literature. Our model outperforms a rule-based expert system in the reaction prediction task for 180,000 randomly selected binary reactions. We show that our data-driven model generalises even beyond known reaction types, and is thus capable of effectively (re-) discovering novel transformations (even including transition-metal catalysed reactions). Our model enables computers to infer hypotheses about reactivity and reactions by only considering the intrinsic local structure of the graph, and because each single reaction prediction is typically ac...

  2. Non-Markovian polymer reaction kinetics

    Guérin, Thomas; Voituriez, Raphaël; 10.1038/NCHEM.1378


    Describing the kinetics of polymer reactions, such as the formation of loops and hairpins in nucleic acids or polypeptides, is complicated by the structural dynamics of their chains. Although both intramolecular reactions, such as cyclization, and intermolecular reactions have been studied extensively, both experimentally and theoretically, there is to date no exact explicit analytical treatment of transport-limited polymer reaction kinetics, even in the case of the simplest (Rouse) model of monomers connected by linear springs. We introduce a new analytical approach to calculate the mean reaction time of polymer reactions that encompasses the non-Markovian dynamics of monomer motion. This requires that the conformational statistics of the polymer at the very instant of reaction be determined, which provides, as a by-product, new information on the reaction path. We show that the typical reactive conformation of the polymer is more extended than the equilibrium conformation, which leads to reaction times sign...

  3. Reaction path synthesis methodology for waste minimization

    HU Shanying; LI Mingheng; LI Yourun; SHEN Jingzhu; LIU Zheng


    It is a key step for reducing waste generation in chemical processes to design optimal reaction paths. In this paper, methods of waste minimization for reaction path synthesis problems are proposed to realize eco-industrial production mode with minimum waste emission. A new conception of simple stoichiometric reaction is presented for reaction path synthesis problem. All simple stoichiometric reactions can be obtained by mathematical transformation for atom matrix of a reaction system. Based on the conception, a two-tier optimization method for complex reaction path synthesis problems is addressed. The first step is to determine the economic optimal overall reactions, and the second step to decompose each overall reaction into several sub-reactions and find out the best thermodynamic feasible reaction path. Further, a method of reaction path synthesis with waste closed-cycle is proposed based on simple stoichiometric reactions for achieving zero waste emission to poly-generation problem of multi-products. Case studies show that the proposed methods can efficiently solve practical reaction path synthesis problems.

  4. πN TDAs from charmonium production in association with a forward pion at P̅ANDA

    Ma B.


    Full Text Available Charmonium production in association with a forward or backward pion in nucleon-antinucleon annihilation is one of the most promising reaction to access nucleon-to-pion transition distribution amplitudes (TDAs at P̅ANDA. We briefly review the description of this reaction in terms of πN TDAs within the collinear factorization approach and present the first results of dedicated feasibility studies for the P̅ANDA experimental setup.

  5. Metal-catalyzed asymmetric aldol reactions

    Dias, Luiz C.; Lucca Junior, Emilio C. de; Ferreira, Marco A. B.; Polo, Ellen C., E-mail: [Universidade de Campinas (UNICAMP), SP (Brazil). Inst. de Quimica


    The aldol reaction is one of the most powerful and versatile methods for the construction of C-C bonds. Traditionally, this reaction was developed in a stoichiometric version; however, great efforts in the development of chiral catalysts for aldol reactions were performed in recent years. Thus, in this review article, the development of metal-mediated chiral catalysts in Mukaiyama-type aldol reaction, reductive aldol reaction and direct aldol reaction are discussed. Moreover, the application of these catalysts in the total synthesis of complex molecules is discussed. (author)

  6. Chemical reactions in solvents and melts

    Charlot, G


    Chemical Reactions in Solvents and Melts discusses the use of organic and inorganic compounds as well as of melts as solvents. This book examines the applications in organic and inorganic chemistry as well as in electrochemistry. Organized into two parts encompassing 15 chapters, this book begins with an overview of the general properties and the different types of reactions, including acid-base reactions, complex formation reactions, and oxidation-reduction reactions. This text then describes the properties of inert and active solvents. Other chapters consider the proton transfer reactions in

  7. The molecular dynamics of atmospheric reaction

    Polanyi, J. C.


    Detailed information about the chemistry of the upper atmosphere took the form of quantitative data concerning the rate of reaction into specified states of product vibration, rotation and translation for exothermic reaction, as well as concerning the rate of reaction from specified states of reagent vibration, rotation and translation for endothermic reaction. The techniques used were variants on the infrared chemiluminescence method. Emphasis was placed on reactions that formed, and that removed, vibrationally-excited hydroxyl radicals. Fundamental studies were also performed on exothermic reactions involving hydrogen halides.

  8. Effect of Pozzolanic Reaction Products on Alkali-silica Reaction

    WEI Fengyan; LAN Xianghui; LV Yinong; XU Zhongzi


    The effect of fly ash on controlling alkali-silica reaction (ASR) in simulated alkali solution was studied. The expansion of mortar bars and the content of Ca(OH)2 in cement paste cured at 80 ℃ for 91 d were measured. Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) were employed to study the microstructure of C-S-H. TEM/energy dispersive spectroscopy (EDS) was then used to determine the composition of C-S-H. The pore structure of the paste was analyzed by mercury intrusion porosimetry (MIP). The results show that the contents of fly ash of 30% and 45% can well inhibit ASR. And the content of Ca(OH)2 decreases with the increase of fly ash. That fly ash reacted with Ca(OH)2 to produce C-S-H with a low Ca/Si molar ratio could bind more Na+ and K+ ions, and produce a reduction in the amount of soluble alkali available for ASR. At the same time, the C-S-H produced by pozzolanic reaction converted large pores to smaller ones (gel pores smaller than 10 nm) to densify the pore structure. Perhaps that could inhibit alkali transport to aggregate for ASR.

  9. Reaction cross-section predictions for nucleon induced reactions

    Nobre, G P A; Escher, J E; Dietrich, F S


    A microscopic calculation of the optical potential for nucleon-nucleus scattering has been performed by explicitly coupling the elastic channel to all the particle-hole (p-h) excitation states in the target and to all relevant pickup channels. These p-h states may be regarded as doorway states through which the flux flows to more complicated configurations, and to long-lived compound nucleus resonances. We calculated the reaction cross sections for the nucleon induced reactions on the targets $^{40,48}$Ca, $^{58}$Ni, $^{90}$Zr and $^{144}$Sm using the QRPA description of target excitations, coupling to all inelastic open channels, and coupling to all transfer channels corresponding to the formation of a deuteron. The results of such calculations were compared to predictions of a well-established optical potential and with experimental data, reaching very good agreement. The inclusion of couplings to pickup channels were an important contribution to the absorption. For the first time, calculations of excitatio...

  10. Fragmentation processes in nuclear reactions

    Fragmentation processes in nuclear collisions are reviewed. The main emphasis is put on light ion breakup at nonrelativistic energies. The post- and prior-form DWBA theories are discussed. The post-form DWBA, appropriate for the ''spectator breakup'' describes elastic as well as inelastic breakup modes. This theory can also account for the stripping to unbound states. The theoretical models are compared to typical experimental results to illustrate the various possible mechanisms. It is discussed, how breakup reactions can be used to study high-lying single particle strength in the continuum; how it can yield information about momentum distributions of fragments in the nucleus. (orig.)

  11. Kinetics of heterogeneous catalytic reactions

    Boudart, Michel


    This book is a critical account of the principles of the kinetics of heterogeneous catalytic reactions in the light of recent developments in surface science and catalysis science. Originally published in 1984. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These paperback editions preserve the original texts of these important books while presenting them in durable paperback editions. The goal of the Princeton Legacy Library is to vastly increase acc

  12. Photo nuclear reactions by QMD

    Maruyama, Tomoyuki; Niita, Koji; Chiba, Satoshi; Maruyama, Toshiki; Iwamoto, Akira [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment


    QMD (Quantum Molecular Dynamics) was applied to photo nuclear reaction. Advantages of QMD were explained. The cross section of (Cr, pX) at 375 MeV/c was simulated. The results showed three peaks, the peak in the lowest momentum indicated contribution of statistics decay and the middle one, the largest peak, was contribution of quasi-free process (QF) which consisted of two-step process. Then, the total cross section of {pi} photoproduction for three target nuclei (C, Al and Cu) was simulated by QMD. The obtained values were larger than the experimental values, so that the present QMD calculation showed small {pi} adsorption. (S.Y.)

  13. Quantum control in nuclear reaction

    A frontier field beyond atom and molecular control will be concentrated on the controlling of nuclei. Both theoretical design and laboratory experiments extremely need to be developed with the great progress of quantum physics and laser technology. This work is to focus on the computational approach to achieve the quantum control in nuclear reaction with a stable semi-discrete numerical paradigm in high dimensions. A reasonable physical model is established by multi-Klein–Gordon Schroedinger dynamics. Demonstrative experiments would provide the confident guidance to control quantum system at nuclei scale in real laboratory. (author)

  14. Chemical reactions at aqueous interfaces

    Vecitis, Chad David


    Interfaces or phase boundaries are a unique chemical environment relative to individual gas, liquid, or solid phases. Interfacial reaction mechanisms and kinetics are often at variance with homogeneous chemistry due to mass transfer, molecular orientation, and catalytic effects. Aqueous interfaces are a common subject of environmental science and engineering research, and three environmentally relevant aqueous interfaces are investigated in this thesis: 1) fluorochemical sonochemistry (bubble-water), 2) aqueous aerosol ozonation (gas-water droplet), and 3) electrolytic hydrogen production and simultaneous organic oxidation (water-metal/semiconductor). Direct interfacial analysis under environmentally relevant conditions is difficult, since most surface-specific techniques require relatively `extreme' conditions. Thus, the experimental investigations here focus on the development of chemical reactors and analytical techniques for the completion of time/concentration-dependent measurements of reactants and their products. Kinetic modeling, estimations, and/or correlations were used to extract information on interfacially relevant processes. We found that interfacial chemistry was determined to be the rate-limiting step to a subsequent series of relatively fast homogeneous reactions, for example: 1) Pyrolytic cleavage of the ionic headgroup of perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) adsorbed to cavitating bubble-water interfaces during sonolysis was the rate-determining step in transformation to their inorganic constituents carbon monoxide, carbon dioxide, and fluoride; 2) ozone oxidation of aqueous iodide to hypoiodous acid at the aerosol-gas interface is the rate-determining step in the oxidation of bromide and chloride to dihalogens; 3) Electrolytic oxidation of anodic titanol surface groups is rate-limiting for the overall oxidation of organics by the dichloride radical. We also found chemistry unique to the interface, for example: 1

  15. Precautions and Adverse Reactions during Blood Transfusion

    ... fever and need another transfusion may be given acetaminophen before the next transfusion. Allergic reactions Symptoms of an allergic reaction include itching, a widespread rash, swelling, dizziness, and headache. Less common symptoms are breathing difficulties, ...

  16. Reaction Wheel with Embedded MEMS IMU Project

    National Aeronautics and Space Administration — The innovation is to embed a MEMS IMU Sensor Chip into a reaction wheel to measure its spin rate as well as wheel attitude rate. We propose to use a reaction wheel...

  17. Catalytic Hydrogenation Reaction of Naringin-Chalcone. Study of the Electrochemical Reaction

    B. A. López de Mishima; H. T. Mishima; A. N. Giannuzzo; M. A. Nazareno


    The electrocatalytic hydrogenation reaction of naringin derivated chalcone is studied. The reaction is carried out with different catalysts in order to compare with the classic catalytic hydrogenation.

  18. Competing reaction channels in IR-laser-induced unimolecular reactions

    Berman, M.R.


    The competing reaction channels in the unimolecular decomposition of two molecules, formaldehyde and tetralin were studied. A TEA CO/sub 2/ laser was used as the excitation source in all experiments. The dissociation of D/sub 2/CO was studied by infrared multiphoton dissociation (MPD) and the small-molecule nature of formaldehyde with regard to MPD was explored. The effect of collisions in MPD were probed by the pressure dependence of the MPD yield and ir fluorescence from multiphoton excited D/sub 2/CO. MPD yield shows a near cubic dependence in pure D/sub 2/CO which is reduced to a 1.7 power dependence when 15 torr of NO is added. The peak amplitude of 5 ir fluorescence from D/sub 2/CO is proportional to the square of the D/sub 2/CO pressure in pure D/sub 2/CO or in the presence of 50 torr of Ar. Results are explained in terms of bottlenecks to excitation at the v = 1 level which are overcome by a combination of vibrational energy transfer and rotational relaxation. The radical/molecule branching ratio in D/sub 2/CO MPD was 0.10 +- 0.02 at a fluence of 125 J/cm/sup 2/ at 946.0 cm/sup -1/. The barrier height to molecular dissociation was calculated to be 3.6 +- 2.0 kcal/mole below the radical threshold or 85.0 +- 3.0 kcal/mole above the ground state of D/sub 2/CO. In H/sub 2/CO, this corresponds to 2.5 +- 2.0 kcal/mole below the radical threshold or 83.8 +- 3.0 kcal/mole above the ground state. Comparison with uv data indicate that RRKM theory is an acceptable description of formaldehyde dissociation in the 5 to 10 torr pressure range. The unimolecular decomposition of tetralin was studied by MPD and SiF/sub 4/ - sensitized pyrolysis. Both techniques induce decomposition without the interference of catalytic surfaces. Ethylene loss is identified as the lowest energy reaction channel. Dehydrogenation is found to result from step-wise H atom loss. Isomerization via disproportionation is also identified as a primary reaction channel.

  19. Competing reaction channels in IR-laser-induced unimolecular reactions

    The competing reaction channels in the unimolecular decomposition of two molecules, formaldehyde and tetralin were studied. A TEA CO2 laser was used as the excitation source in all experiments. The dissociation of D2CO was studied by infrared multiphoton dissociation (MPD) and the small-molecule nature of formaldehyde with regard to MPD was explored. The effect of collisions in MPD were probed by the pressure dependence of the MPD yield and ir fluorescence from multiphoton excited D2CO. MPD yield shows a near cubic dependence in pure D2CO which is reduced to a 1.7 power dependence when 15 torr of NO is added. The peak amplitude of 5 μm ir fluorescence from D2CO is proportional to the square of the D2CO pressure in pure D2CO or in the presence of 50 torr of Ar. Results are explained in terms of bottlenecks to excitation at the v = 1 level which are overcome by a combination of vibrational energy transfer and rotational relaxation. The radical/molecule branching ratio in D2CO MPD was 0.10 +- 0.02 at a fluence of 125 J/cm2 at 946.0 cm-1. The barrier height to molecular dissociation was calculated to be 3.6 +- 2.0 kcal/mole below the radical threshold or 85.0 +- 3.0 kcal/mole above the ground state of D2CO. In H2CO, this corresponds to 2.5 +- 2.0 kcal/mole below the radical threshold or 83.8 +- 3.0 kcal/mole above the ground state. Comparison with uv data indicate that RRKM theory is an acceptable description of formaldehyde dissociation in the 5 to 10 torr pressure range. The unimolecular decomposition of tetralin was studied by MPD and SiF4 - sensitized pyrolysis. Both techniques induce decomposition without the interference of catalytic surfaces. Ethylene loss is identified as the lowest energy reaction channel. Dehydrogenation is found to result from step-wise H atom loss. Isomerization via disproportionation is also identified as a primary reaction channel

  20. Contact-Allergic Reactions to Cosmetics

    An Goossens


    Contact-allergic reactions to cosmetics may be delayed-type reactions such as allergic and photo-allergic contact dermatitis, and more exceptionally also immediate-type reactions, that is, contact urticaria. Fragrances and preservative agents are the most important contact allergens, but reactions also occur to category-specific products such as hair dyes and other hair-care products, nail cosmetics, sunscreens, as well as to antioxidants, vehicles, emulsifiers, and, in fact, any possible cos...

  1. Indirect techniques for astrophysical reaction rates determinations

    Hammache, F.; Oulebsir, N.; Benamara, S.; De Séréville, N.; Coc, A.; Laird, A.; Stefan, I.; Roussel, P.


    Direct measurements of nuclear reactions of astrophysical interest can be challenging. Alternative experimental techniques such as transfer reactions and inelastic scattering reactions offer the possibility to study these reactions by using stable beams. In this context, I will present recent results that were obtained in Orsay using indirect techniques. The examples will concern various astrophysical sites, from the Big-Bang nucleo synthesis to the production of radioisotopes in massive stars.

  2. Nuclear reaction rates and the primordial nucleosynthesis

    Mishra, Abhishek; Basu, D. N.


    The theoretical predictions of the primordial abundances of elements in the big-bang nucleosynthesis (BBN) are dominated by uncertainties in the input nuclear reaction rates. We investigate the effect of modifying these reaction rates on light element abundance yields in BBN by replacing the thirty-five reaction rates out of the existing eighty-eight. We have studied these yields as functions of evolution time or temperature. We find that using these new reaction rates results in only a littl...

  3. Oxidation-reduction reactions of metal ions.

    Carter, D E


    Several metal or metalloid ions exist in multiple oxidation states and can undergo electron transfer reactions that are important in biological and environmental systems. There are endogenous metal ions such as iron, copper, and cobalt that participate in oxidation-reduction reactions with species of oxygen like molecular dioxygen, superoxide, and hydrogen peroxide. These reactions may be modulated by endogenous reducing agents such as glutathione, ascorbate, and tocopherol. The reactions can...

  4. Efficient path sampling on multiple reaction channels

    van Erp, Titus S.


    Due to the time scale problem, rare events are not accessible by straight forward molecular dynamics. The presence of multiple reaction channels complicates the problem even further. The feasibility of the standard free energy based methods relies strongly on the success in finding a proper reaction coordinate. This can be very difficult task in high-dimensional complex systems and even more if several distinct reaction channels exist. Moreover, even if a proper reaction coordinate can be fou...

  5. Multi-step direct reactions

    In recent years a variety of statistical theories has been developed concerning multistep direct (MSD) nuclear reactions. In addition, dominant in applications is a whole class of semiclassical models that may be subsumed under the heading of 'generalized exciton models'; these are basically MSD-type extensions on top of compound-like concepts. In this report the relation between their underlying statistical MSD-postulates are highlighted. A command framework is sketched that enables to generate the various MSD theories through assigning statistical properties to different parts of the nuclear Hamiltonian. Then it is shown that distinct forms of nuclear randomness are embodied in the mentioned theories. All these theories appear to be very similar at a qualitative level. In order to explain the high energy-tails and forward-peaked angular distribution typical for particles emitted in MSD reactions, it is imagined that the incident continuum particle stepwise looses its energy and direction in a sequence of collisions, thereby creating new particle-hole pairs in the target system. At each step emission may take place. The statistical aspect comes in because many continuum states are involved in the process. These are supposed to display chaotic behavior, the associated randomness assumption giving rise to important simplifications in the expression for MSD emission cross sections. This picture suggests that mentioned MSD models can be interpreted as a variant of essentially one and the same theory. 113 refs.; 25 figs.; 9 tabs

  6. Severe photosensitivity reaction induced by topical diclofenac

    Pramod B Akat


    Full Text Available Albeit uncommon, photosensitivity reaction induced by diclofenac can be an unfortunate adverse reaction complicating its use as a topical analgesic. We here present a case of a patient who suffered such a reaction as a result of exposure to diclofenac, employed as a topical analgesic for low backache. The lesions healed with conservative management without extensive scarring or other complications.

  7. Allergic reactions seen in orthodontic treatment

    Hande Görücü Coşkuner


    Full Text Available Allergy can be defined as inappropriate and harmful response to harmless and ordinary materials. Allergic reactions, like in other fields of dentistry, can also be seen in the field of orthodontics. The reactions that occur against orthodontic materials can be seen as irritant or hypersensitivity reactions. The main reason of the irritant reactions is friction between soft tissues and orthodontic appliances. However, the reason of the hypersensitivity reactions is usually the antigenicity of the materials. Hypersensitivity reactions are usually seen as allergic contact dermatitis on face and neck; the occurrence of mucosal-gingival reactions and dermal and systemic reactions are rare. Latex, metal and acrylic resins are the most common allergens in orthodontics. Apart from these materials, allergic reactions can occur against bonding materials, extraoral appliances, disinfectants and antimicrobial agents. The reactions that occur against extraoral appliances usually result from metallic and elastic parts of the appliances or the appliance parts that are in contact with skin. Orthodontists should be aware of the allergic reactions to protect their patients’ health. The aim of this review was to evaluate the allergic reactions seen in orthodontic patients and discuss the cautions that orthodontists can take.

  8. The Rate Laws for Reversible Reactions.

    King, Edward L.


    Provides background information for teachers on the rate laws for reversible reactions. Indicates that although prediction of the form of the rate law for a reverse reaction given the rate law for the forward reaction is not certain, the number of possibilities is limited because of relationships described. (JN)

  9. Chapter 19 (Part 3): Enolate Reactions

    Christiansen, Mike A


    In this video I'll continue teaching you about various reactions (with mechanisms) that we can do using carbonyl compounds, due to the acidities of their alpha-hydrogens. These reactions include the aldol reaction, the Claisen condensation, the Robinson annulation, acid-catalyzed decarboxylation, and the malonic ester synthesis. --Dr. Mike Christiansen from Utah State University

  10. Reaction-Map of Organic Chemistry

    Murov, Steven


    The Reaction-Map of Organic Chemistry lists all the most commonly studied reactions in organic chemistry on one page. The discussed Reaction-Map will act as another learning aide for the students, making the study of organic chemistry much easier.