A new type of magnetocaloric composite based on conductive polymer and magnetocaloric compound

International Nuclear Information System (INIS)

Imamura, W.; Coelho, A.A.; Kupfer, V.L.; Carvalho, A.M.G.; Zago, J.G.; Rinaldi, A.W.; Favaro, S.L.; Alves, C.S.

2017-01-01

We introduce a processing route of the first magnetocaloric composite with conductive polymer – wherein the magnetocaloric reinforcement is a compound Gd_5_._0_9Ge_2_._0_3Si_1_._8_8 and the ductile matrix is a conductive polymer polyaniline doped by camphorsulfonic acid (PAni-CSA). This new type of composite combines mechanical, electrical and magnetocaloric properties that can be applied in thermomagnetic machines. - Highlights: • We developed a new type of magnetocaloric composite: PAni-CSA/Gd5.09Ge2.03Si1.88. • We presented a processing route which use a conductive polymer instead of epoxy resins or thermoplastic polymers. • We varied the concentration of PAni-CSA (numerical type) and sintering (categorical type). • We analyzed the matrix (PAni-CSA), the magnetocaloric reinforcement (Gd5.09Ge2.03Si1.88) and the composites. • We presented and discussed mechanical, electrical and magnetocaloric properties.

Magnetocaloric effect in Ni{sub 2}MnGa single crystal in the vicinity of the martensitic phase transition

Energy Technology Data Exchange (ETDEWEB)

Radelytskyi, I., E-mail: radel@ifpan.edu.pl [Institute of Physics, PAS, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Pękała, M. [Department of Chemistry, University of Warsaw, Al. Zwirki i Wigury 101, 02-089 Warsaw (Poland); Szymczak, R. [Institute of Physics, PAS, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gawryluk, D.J. [Institute of Physics, PAS, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Laboratory for Scientific Developments and Novel Materials, Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Berkowski, M.; Fink-Finowicki, J. [Institute of Physics, PAS, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Diduszko, R. [Tele and Radio Research Institute, ul Ratuszowa 11, 03-450 Warsaw (Poland); Dyakonov, V.; Szymczak, H. [Institute of Physics, PAS, Al. Lotnikow 32/46, 02-668 Warsaw (Poland)

2017-05-15

The magnetocaloric effect in the vicinity of the martensitic transformation for a single crystalline alloy with a composition close to the stoichiometric Ni{sub 2}MnGa has been determined indirectly by M(T,H) magnetization measurements. It has an inverse character. The magnetocaloric parameters, i.e., the magnetic entropy change, refrigeration capacity and various hysteretic effects have been calculated from the M(T,H) dependences. Besides the martensitic transition a weak entirely separated intermartensitic transition was observed. These two successive magneto-structural transformations give contributions to the observed magnetocaloric effect. Unusual dependence of entropy change as a function of magnetic field has been explained as arising because of two different mechanisms. Additionally, to confirm that studied martensitic transformation is a first order phase transition electrical resistivity and thermoelectric power measurements have been performed. - Highlights: • Inverse magnetocaloric effect in Ni{sub 50.4}Mn{sub 24.9}Ga{sub 24.7} single crystal was measured. • The martensitic and separated intermartensitic transition were investigated. • Anisotropy of measured magnetocaloric effect was discussed.

Magnetocaloric refrigeration concepts: current state of the art

DEFF Research Database (Denmark)

Nielsen, Kaspar Kirstein

2014-01-01

Refrigeration devices based on the magnetocaloric effect have been prototyped in great numbers during the past decade. The search for the optimal combination of magnetic field source, regenerator geometry, magnetocaloric material composition and flow system design has resulted in a variety...

The effect of plastic deformation on magnetic and magnetocaloric properties of Gd-B alloys

Science.gov (United States)

Taskaev, Sergey; Skokov, Konstantin; Karpenkov, Dmitry; Khovaylo, Vladimir; Ulyanov, Maxim; Bataev, Dmitry; Dyakonov, Alexandr; Fazlitdinova, Alfiya; Gutfleisch, Oliver

2017-11-01

We report on the magnetocaloric effect in Gd100-xBx (x = 0, 10, 15) cold rolled ribbons. A moderate entropy change ΔS = 5 J/kg·K and adiabatic change of ΔT = 4.8 K were observed for the as-cast materials in an external magnetic field of 3 T which is less by 20% in comparison with the pure gadolinium metal. It was found that a significant (up to 70%) depression of magnetization and magnetocaloric properties developed in the course of plastic deformation can completely be restored by means of a high temperature heat treatment. It is concluded that cold rolling is one promising technique for producing foil shaped magnetocaloric materials suitable for designing heat exchangers of magnetic cooling devices.

Magnetocaloric effect in “reduced” dimensions: Thin films, ribbons, and microwires of Heusler alloys and related compounds: Magnetocaloric effect in “reduced” dimensions

Energy Technology Data Exchange (ETDEWEB)

Khovaylo, Vladimir V. [National University of Science and Technology MISiS, Moscow 119049 Russia; ITMO University, St. Petersburg 197101 Russia; Rodionova, Valeria V. [National University of Science and Technology MISiS, Moscow 119049 Russia; Innovation Park and Institute of Physics & Technology, Immanuel Kant Baltic Federal University, Kaliningrad 236041 Russia; Shevyrtalov, Sergey N. [Innovation Park and Institute of Physics & Technology, Immanuel Kant Baltic Federal University, Kaliningrad 236041 Russia; Novosad, Val [Materials Science Division, Argonne National Laboratory, Argonne IL 60439 USA

2014-08-19

Room temperature magnetic refrigeration is an energy saving and environmentally-friendly technology which has developed rapidly from a basic idea to prototype devices. The performance of magnetic refrigerators crucially depends on the magnetocaloric properties and the geometry of the employed refrigerants. Here we review the magnetocaloric properties of Heusler alloys and related compounds with a high surface to volume ratio such as films, ribbons and microwires, and compare them with their bulk counterparts.

MnFe(PGe) compounds: Preparation, structural evolution, and magnetocaloric effects

International Nuclear Information System (INIS)

Yue Ming; Zhang Hong-Guo; Zhang Jiu-Xing; Liu Dan-Min

2015-01-01

The interdependences of preparation conditions, magnetic and crystal structures, and magnetocaloric effects (MCE) of the MnFePGe-based compounds are reviewed. Based upon those findings, a new method for the evaluation of the MCE in these compounds, based on differential scanning calorimetry (DSC), is proposed. The MnFePGe-based compounds are a group of magnetic refrigerants with giant magnetocaloric effect (GMCE), and as such, have drawn tremendous attention, especially due to their many advantages for practical applications. Structural evolution and phase transformation in the compounds as functions of temperature, pressure, and magnetic field are reported. Influences of preparation conditions upon the homogeneity of the compounds’ chemical composition and microstructure, both of which play a key role in the MCE and thermal hysteresis of the compounds, are introduced. Lastly, the origin of the “virgin effect” in the MnFePGe-based compounds is discussed. (paper)

Nonuniversal scaling of the magnetocaloric effect as an insight into spin-lattice interactions in manganites

DEFF Research Database (Denmark)

Smith, Anders; Nielsen, Kaspar Kirstein; Neves Bez, Henrique

2016-01-01

is not given uniquely by the critical exponents of the ferromagnetic-paramagnetic phase transition, i.e., the scaling is nonuniversal. A theoretical description based on the Bean-Rodbell model and taking into account compositional inhomogeneities is shown to be able to account for the observed field dependence....... In this way the determination of the nonuniversal field dependence of the magnetocaloric effect close to a phase transition can be used as a method to gain insight into the strength of the spin-lattice interactions of magnetic materials. The approach is shown also to be applicable to first-order transitions.......We measure the magnetocaloric effect of the manganite series La0.67Ca0.33-xSrxMnO3 by determining the isothermal entropy change upon magnetization, using variable-field calorimetry. The results demonstrate that the field dependence of the magnetocaloric effect close to the critical temperature...

Observation of large magnetocaloric effect in equiatomic binary compound ErZn

Directory of Open Access Journals (Sweden)

Lingwei Li

2017-05-01

Full Text Available The magnetism, magnetocaloric effect and universal behaviour in rare earth Zinc binary compound of ErZn have been studied. The ErZn compound undergoes a second order paramagnetic (PM to ferromagnetic (FM transition at Curie temperature of TC ∼ 20 K. The ErZn compound exhibits a large reversible magnetocaloric effect (MCE around its own TC. The rescaled magnetic entropy change curves overlap with each other under various magnetic field changes, further confirming the ErZn with the second order phase transition. For the magnetic field change of 0-7 T, the maximum values of the magnetic entropy change (−ΔSMmax, relative cooling power (RCP and refrigerant capacity (RC for ErZn are 23.3 J/kg K, 581 J/kg and 437 J/kg, respectively.

Magnetocaloric effect in (La1-xAx)2/3Ba1/3Mn1.05O3-δ

DEFF Research Database (Denmark)

Ancona-Torres, Carlos Eugenio; Menon, Mohan; Bahl, Christian Robert Haffenden

Recently, a large magnetocaloric effect has been reported in La2/3Ba1/3MnO3-δ at about 300 K. In this paper, we investigate the effect of the ion size distribution at the A site on the magnetocaloric effect of this perovskite material. This is accomplished by replacing the lanthanum by Ce, Pr......, and Nd, which allows us to study the effect of both the average size, , and the distribution, σrA, on the magnetic properties of the system. Using magnetization and heat capacity measurements, we determine the important magnetocaloric parameters ΔSM and ΔTad of (La1-xAx)2/3Ba1/3Mn1.05O3-δ powders...

Direct and indirect measurement of the magnetocaloric effect in bulk and nanostructured Ni-Mn-In Heusler alloy

Science.gov (United States)

Ghahremani, Mohammadreza; Aslani, Amir; Hosseinnia, Marjan; Bennett, Lawrence H.; Della Torre, Edward

2018-05-01

A systematic study of the magnetocaloric effect of a Ni51Mn33.4In15.6 Heusler alloy converted to nanoparticles via high energy ball-milling technique in the temperature range of 270 to 310 K has been performed. The properties of the particles were characterized by x-ray diffraction, electron microscopy, and magnetometer techniques. Isothermal magnetic field variation of magnetization exhibits field hysteresis in bulk Ni51Mn33.4In15.6 alloy across the martensitic transition which significantly lessened in the nanoparticles. The magnetocaloric effects of the bulk and nanoparticle samples were measured both with direct method, through our state of the art direct test bed apparatus with controllability over the applied fields and temperatures, as well as an indirect method through Maxwell and thermodynamic equations. In direct measurements, nanoparticle sample's critical temperature decreased by 6 K, but its magnetocaloric effect enhanced by 17% over the bulk counterpart. Additionally, when comparing the direct and indirect magnetocaloric curves, the direct method showed 14% less adiabatic temperature change in the bulk and 5% less adiabatic temperature change in the nanostructured sample.

Constraints on the Adiabatic Temperature Change in Magnetocaloric Materials

DEFF Research Database (Denmark)

Nielsen, Kaspar Kirstein; Bahl, Christian Robert Haffenden; Smith, Anders

2010-01-01

The thermodynamics of the magnetocaloric effect implies constraints on the allowed variation in the adiabatic temperature change for a magnetocaloric material. An inequality for the derivative of the adiabatic temperature change with respect to temperature is derived for both first- and second...

Magnetocaloric effect and other low-temperature properties of Pr2Pt2 In

Science.gov (United States)

Mboukam, J. J.; Sondezi, B. M.; Tchokonté, M. B. Tchoula; Bashir, A. K. H.; Strydom, A. M.; Britz, D.; Kaczorowski, D.

2018-05-01

We report on X-ray diffraction, electrical transport, heat capacity and magnetocaloric effect measurements of a polycrystalline sample of Pr2Pt2 In . The compound forms in the tetragonal Mo2FeB2 type structure and orders ferromagnetically at TC=9 K. In the ordered state, its thermodynamic and electrical transport properties are dominated by magnon contributions with an energy gap of about 8 K in the spin-wave spectrum. The magnitude of magnetocaloric effect is similar to the values reported for most rare-earth based intermetallics. Characteristic behavior of the isothermal magnetic entropy change maximum points to a second-order character of the ferromagnetic phase transition in the compound studied.

Heat capacity and magnetocaloric effect in polycrystalline Gd 1-xSm xMn 2Si 2

Science.gov (United States)

Kumar, Pramod; Singh, Niraj K.; Suresh, K. G.; Nigam, A. K.; Malik, S. K.

2007-12-01

We report the magnetocaloric effect in terms of isothermal magnetic entropy change as well as adiabatic temperature change, calculated using the heat capacity data. Using the zero-field heat capacity data, the magnetic contribution to the heat capacity has been estimated. The variations in the magnetocaloric behavior have been explained on the basis of the magnetic structure of these compounds. The refrigerant capacities have also been calculated for these compounds.

Magnetocaloric Effect and Thermoelectric Cooling - A Synergistic Cooling Technology

Science.gov (United States)

2018-01-16

Thermoelectric Cooling - A Synergistic Cooling Technology Sb. GRANT NUMBER N00173-14-1-G016 Sc. PROGRAM ELEMENT NUMBER 82-2020-17 6. AUTHOR(S) 5d...Magnetocaloric Effect and Thermoelectric Cooling - A Synergistic Cooling Technology NRL Grant N00173-14-l-G016 CODE 8200: Spacecraft Engineering Department...82-11-0 1: Space and Space Systems Technology General Engineering & Research, L.L.C. Technical & Administrative point of contact: Dr. Robin

Magnetocaloric effect in magnetothermally-responsive nanocarriers for hyperthermia-triggered drug release

International Nuclear Information System (INIS)

Li Jianbo; Qu Yang; Ren Jie; Yuan Weizhong; Shi Donglu

2012-01-01

The magnetocaloric effects and lower critical solution temperature (LCST) were investigated in a magnetothermally-responsive nanocarrier for magnetothermal drug release under alternating magnetic field (AMF). The Mn 0.2 Zn 0.8 Fe 2 O 4 nanoparticles with low T c were dispersed in a polymeric matrix consisting of N-Isopropyl acrylamide (NIPAAm) and N-hydroxymethyl acrylamide (HMAAm). The magnetocaloric effects and LCST of the nanocarriers were characterized by using high-resolution electron transmission microscopy, thermogravimetric analyses, and vibrating sample magnetometer. The maximum self-heating temperature of 42.9 °C was achieved by optimizing the Mn 0.2 Zn 0.8 Fe 2 O 4 concentration in the polymer matrix. By adjusting the NIPAAm to HMAAm ratio, the LCST was controlled at an ideal level of 40.1 °C for efficient thermosensitive drug delivery. Magnetothermally responsive drug release of Doxorubicin, an anticancer drug, was significantly enhanced by application of an external AMF on the nanocarriers. The cytotoxicity experimental results in vitro show good biocompatibility and efficient therapeutic effects in cancer treatment. (paper)

Order of magnetic transition and large magnetocaloric effect in Er3Co

International Nuclear Information System (INIS)

Jun, Shen; Jian-Feng, Wu; Jin-Liang, Zhao; Feng-Xia, Hu; Ji-Rong, Sun; Bao-Gen, Shen

2010-01-01

We have studied the magnetic and magnetocaloric properties of the Er 3 Co compound, which undergoes ferromagnetic ordering below the Curie temperature T C = 13 K. It is found by fitting the isothermal magnetization curves that the Landau model is appropriate to describe the Er 3 Co compound. The giant magnetocaloric effect (MCE) without hysteresis loss around T C is found to result from the second-order ferromagnetic-to-paramagnetic transition. The maximal value of magnetic entropy change is 24.5 J/kg·K with a refrigerant capacity (RC) value of 476 J/kg for a field change of 0–5 T. Large reversible MEC and RC indicate the potentiality of Er 3 Co as a candidate magnetic refrigerant at low temperatures. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

Phase transitions and magnetocaloric effects in intermetallic compounds MnFeX (X=P, As, Si, Ge)

International Nuclear Information System (INIS)

Tegus, O.; Bao Li-Hong; Song Lin

2013-01-01

Since the discovery of giant magnetocaloric effect in MnFeP 1−x As x compounds, much valuable work has been performed to develop and improve Fe 2 P-type transition-metal-based magnetic refrigerants. In this article, the recent progress of our studies on fundamental aspects of theoretical considerations and experimental techniques, effects of atomic substitution on the magnetism and magnetocalorics of Fe 2 P-type intermetallic compounds MnFeX (X=P, As, Ge, Si) is reviewed. Substituting Si (or Ge) for As leads to an As-free new magnetic material MnFeP 1−x Si(Ge) x . These new materials show large magnetocaloric effects resembling MnFe(P, As) near room temperature. Some new physical phenomena, such as huge thermal hysteresis and ‘virgin’ effect, were found in new materials. On the basis of Landau theory, a theoretical model was developed for studying the mechanism of phase transition in these materials. Our studies reveal that MnFe(P, Si) compound is a very promising material for room-temperature magnetic refrigeration and thermo-magnetic power generation. (topical review - magnetism, magnetic materials, and interdisciplinary research)

Effects of pre-deformation on the martensitic transformation and magnetocaloric property in Ni-Mn-Co-Sn ribbons

International Nuclear Information System (INIS)

Ma Sheng-Can; Xuan Hai-Cheng; Zhang Cheng-Liang; Wang Liao-Yu; Cao Qing-Qi; Wang Dun-Hui; Du You-Wei

2010-01-01

This paper investigates the martensitic transformation and magnetocaloric effect in pre-deformed Ni-Mn-Co-Sn ribbons. The experimental results show that the reverse martensitic transformation temperature T M increases with the increasing pre-pressure, suggesting that pre-deformation is another effective way to adjust T M in ferromagnetic shape memory alloys. Large magnetic entropy changes and refrigerant capacities are obtained in these ribbons as well. It also discusses the origin of the enhanced martensitic transformation temperature and magnetocaloric property in pre-deformed Ni-Mn-Co-Sn ribbons

Large magnetocaloric effect of GdNiAl2 compound

International Nuclear Information System (INIS)

Dembele, S.N.; Ma, Z.; Shang, Y.F.; Fu, H.; Balfour, E.A.; Hadimani, R.L.; Jiles, D.C.; Teng, B.H.; Luo, Y.

2015-01-01

This paper presents the structure, magnetic properties, and magnetocaloric effect of the polycrystalline compound GdNiAl 2 . Powder X-ray diffraction (XRD) measurement and Rietveld refinement revealed that GdNiAl 2 alloy is CuMgAl 2 -type phase structure with about 1 wt% GdNi 2 Al 3 secondary phase. Magnetic measurements suggest that the compound is ferromagnetic and undergoes a second-order phase transition near 28 K. The maximum value of magnetic entropy change reaches 16.0 J/kg K for an applied magnetic field change of 0–50 kOe and the relative cooling power was 6.4×10 2 J/kg. It is a promising candidate as a magnetocaloric material working near liquid hydrogen temperature (~20 K) exhibiting large relative cooling power. - Highlights: • Preferred orientation with axis of [010] was found in the GdNiAl 2 compound. • The ΔS Mmax and the RCP are 16.0 J/kg K and 640 J/kg, respectively, for ΔH=50 kOe. • Relative low rare earth content in GdNiAl 2 comparing with other candidates

Magnetocaloric effect in quantum spin-s chains

Directory of Open Access Journals (Sweden)

A. Honecker

2009-01-01

Full Text Available We compute the entropy of antiferromagnetic quantum spin-s chains in an external magnetic field using exact diagonalization and Quantum Monte Carlo simulations. The magnetocaloric effect, i. e., temperature variations during adiabatic field changes, can be derived from the isentropes. First, we focus on the example of the spin-s=1 chain and show that one can cool by closing the Haldane gap with a magnetic field. We then move to quantum spin-s chains and demonstrate linear scaling with s close to the saturation field. In passing, we propose a new method to compute many low-lying excited states using the Lanczos recursion.

Improvement of magnetocaloric properties of Gd-Ge-Si alloys by alloying with iron

Directory of Open Access Journals (Sweden)

Erenc-Sędziak T.

2013-01-01

Full Text Available The influence of annealing of Gd5Ge2Si2Fex alloys at 1200°C and of alloying with various amount of iron on structure as well as thermal and magnetocaloric properties is investigated. It was found that annealing for 1 to 10 hours improves the entropy change, but reduces the temperature of maximum magnetocaloric effect by up to 50 K. Prolonged annealing of the Gd5Ge2Si2 alloy results in the decrease of entropy change due to the reduction of Gd5Ge2Si2 phase content. Addition of iron to the ternary alloy enhances the magnetocaloric effect, if x = 0.4 – 0.6, especially if alloying is combined with annealing at 1200°C: the peak value of the isothermal entropy change from 0 to 2 T increases from 3.5 to 11 J/kgK. Simultaneously, the temperature of maximum magnetocaloric effect drops to 250 K. The changes in magnetocaloric properties are related to the change in phase transformation from the second order for arc molten ternary alloy to first order in the case of annealed and/or alloyed with iron. The results of this study indicate that the minor addition of iron and heat treatment to Gd-Ge-Si alloys may be useful in improving the materials’ magnetocaloric properties..

Measurement of pressure effects on the magnetic and the magnetocaloric properties of the intermetallic compounds DyCo2 and Er(Co1-xSix)2

International Nuclear Information System (INIS)

Singh, Niraj K; Kumar, Pramod; Suresh, K G; Nigam, A K; Coelho, A A; Gama, S

2007-01-01

The effect of external pressure on the magnetic properties and magnetocaloric effect of polycrystalline compounds DyCo 2 and Er(Co 1-x Si x ) 2 (x = 0,0.025 and 0.05) has been studied. The ordering temperatures of both the parent and the Si-substituted compounds are found to decrease with pressure. In all the compounds, the critical field for metamagnetic transition increases with pressure. It is seen that the magnetocaloric effect in the parent compounds is almost insensitive to pressure, while there is considerable enhancement in the case of Si-substituted compounds. Spin fluctuations arising from the magnetovolume effect play a crucial role in determining the pressure dependence of the magnetocaloric effect in these compounds. The variation of the magnetocaloric effect is explained on the basis of the Landau theory of magnetic phase transitions

Hysteresis in Magnetocaloric Materials

DEFF Research Database (Denmark)

von Moos, Lars

, obtained at the initial low and final high field. However, in first order materials thermal entropy hysteresis loops are obtained through characterization, corresponding to measurements done in an increasing and a decreasing temperature mode. Indirectly determining the MCE through the use of the Maxwell...... order materials, taking the magnetic and thermal history dependence of material properties into account, as well as the heat production due to hysteretic losses. MnFe(P,As) and Gd5Si2Ge2 compounds are modelled and it is found that the Preisach approach is suitable to reproduce material behavior in both......In this thesis the effects of hysteresis on magnetocaloric material properties and their performance in magnetic refrigeration devices are investigated. This is done through an experimental and model study of first order magnetocaloric materials MnFe(P,As) and Gd5Si2Ge2. The experimental...

Integration of a magnetocaloric heat pump in a low-energy residential building

DEFF Research Database (Denmark)

Johra, Hicham

2018-01-01

The EnovHeat project aims at developing an innovative heat pump system based on the magnetocaloric effect and active magnetic regenerator technology to provide for the heating needs of a single family house in Denmark. Unlike vapor-compression devices, magnetocaloric heat pumps use the reversible...... heat pump can deliver 2600 W of heating power with an appreciable average seasonal system COP of 3.93. On variable part-load operation with a simple fluid flow controller, it can heat up an entire house with an average seasonal system COP of 1.84....... magnetocaloric effect of a solid refrigerant to build a cooling/heating cycle. It has the potential for high coefficient of performance, more silent operation and efficient part-load control. After presenting the operation principles of the magnetocaloric device and the different models used in the current...... numerical study, this article demonstrates for the first time the possibility to utilize this novel heat pump in a building. This device can be integrated in a single hydronic loop including a ground source heat exchanger and a radiant under-floor heating system. At maximum capacity, this magnetocaloric...

Magnetocaloric properties of distilled gadolinium: effects of structural inhomogeneity and hydrogen impurity

Czech Academy of Sciences Publication Activity Database

Burkhanov, G.S.; Kolchugina, N.B.; Tereshina, Evgeniya; Tereshina, I. S.; Politova, G.A.; Chzhan, V.B.; Badurski, D.; Chistyakov, O.D.; Paukov, M.; Drulis, H.; Havela, L.

2014-01-01

Roč. 104, č. 24 (2014), "242402-1"-"242402-5" ISSN 0003-6951 R&D Projects: GA ČR GAP204/12/0150 Institutional support: RVO:68378271 Keywords : high-purity rare- earth metals * gadolinium * magnetocaloric effect * hydrogenation * structural studies Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.302, year: 2014

Experimental study of magnetocaloric effect in the two-level quantum system KTm(MoO4)2

Science.gov (United States)

Tarasenko, R.; Tkáč, V.; Orendáčová, A.; Orendáč, M.; Valenta, J.; Sechovský, V.; Feher, A.

2018-05-01

KTm(MoO4)2 belongs to the family of binary alkaline rare-earth molybdates. This compound can be considered to be an almost ideal quantum two-level system at low temperatures. Magnetocaloric properties of KTm(MoO4)2 single crystals were investigated using specific heat and magnetization measurement in the magnetic field applied along the easy axis. Large conventional magnetocaloric effect (-ΔSM ≈ 10.3 J/(kg K)) was observed in the magnetic field of 5 T in a relatively wide temperature interval. The isothermal magnetic entropy change of about 8 J/(kgK) has been achieved already for the magnetic field of 2 T. Temperature dependence of the isothermal entropy change under different magnetic fields is in good agreement with theoretical predictions for a quantum two-level system with Δ ≈ 2.82 cm-1. Investigation of magnetocaloric properties of KTm(MoO4)2 suggests that the studied system can be considered as a good material for magnetic cooling at low temperatures.

Integration of a magnetocaloric heat pump in a low-energy residential building

DEFF Research Database (Denmark)

Johra, Hicham; Filonenko, Konstantin; Heiselberg, Per

2018-01-01

magnetocaloric effect of a solid refrigerant to build a cooling/heating cycle. It has the potential for high coefficient of performance, more silent operation and efficient part-load control. After presenting the operation principles of the magnetocaloric device and the different models used in the current...

A comparative study of critical phenomena and magnetocaloric properties of ferromagnetic ternary alloys

Science.gov (United States)

Yüksel, Yusuf; Akinci, Ümit

2018-01-01

Magnetic and magnetocaloric properties, as well as the phase diagrams of a ferromagnetic ternary alloy system have been studied. A detailed comparison of two different methods, namely the effective field theory (EFT), and Monte Carlo (MC) simulations has been provided. Our numerical data show that the general qualitative picture presented by two methods are in a good agreement with each other. In terms of the magnetocaloric properties, our results yield that it is possible to design magnetic materials with a variety of working temperatures and magnetocaloric properties (such as large ΔSM and q values) by manipulating the magnetic phase transition via tuning the compositional factor (i.e. the mixing ratio of sublattice ions). The observed magnetocaloric effect has been found to be a direct one with ΔSM < 0 associated with a second order phase transition.

Magnetocaloric effect of polycrystalline Sm0.5Ca0.5MnO3 compound: Investigation of low temperature magnetic state

Science.gov (United States)

Das, Kalipada; Banu, Nasrin; Das, I.; Dev, B. N.

2018-06-01

An attempt has been made to probe low temperature magnetic state of the polycrystalline Sm0.5Ca0.5MnO3 compound via magnetization and magnetocaloric studies. In the context of the earlier debatable reports on the above mentioned compound between the existence of glassy magnetic state and small ferromagnetic domains from the 'ac' susceptibility measurements, our experimental observation from magnetocaloric effect study clearly indicates the existence of ferromagnetic droplets along with certain amount of superparamagnetic component at low temperature (magnetization (even at H = 0.01 T) data do not exhibit the spin freezing nature at the low temperature which is almost a generic tendency of glassy magnetic state. Our study also highlights the competence of magnetocaloric effect as a tool to distinguish between different magnetic states of a compound.

FAST TRACK COMMUNICATION: Reproducible room temperature giant magnetocaloric effect in Fe-Rh

Science.gov (United States)

Manekar, Meghmalhar; Roy, S. B.

2008-10-01

We present the results of magnetocaloric effect (MCE) studies in polycrystalline Fe-Rh alloy over a temperature range of 250-345 K across the first order antiferromagnetic to ferromagnetic transition. By measuring the MCE under various thermomagnetic histories, contrary to the long held belief, we show here explicitly that the giant MCE in Fe-Rh near room temperature does not vanish after the first field cycle. In spite of the fact that the virgin magnetization curve is lost after the first field cycle near room temperature, reproducibility in the MCE under multiple field cycles can be achieved by properly choosing a combination of isothermal and adiabatic field variation cycles in the field-temperature phase space. This reproducible MCE leads to a large effective refrigerant capacity of 324.42 J kg-1, which is larger than that of the well-known magnetocaloric material Gd5Si2Ge2. This information could be important as Fe-Rh has the advantage of having a working temperature of around 300 K, which can be used for room temperature magnetic refrigeration.

Magnetocaloric effect in Heusler alloys Ni50Mn34In16 and Ni50Mn34Sn16

Science.gov (United States)

Sharma, V. K.; Chattopadhyay, M. K.; Kumar, Ravi; Ganguli, Tapas; Tiwari, Pragya; Roy, S. B.

2007-12-01

We present results of detailed ac susceptibility, magnetization and specific heat measurements in Heusler alloys Ni50Mn34In16 and Ni50Mn34Sn16. These alloys undergo a paramagnetic to ferromagnetic transition around 305 K, which is followed by a martensitic transition in the temperature regime around 220 K. Inside the martensite phase both the alloys show signatures of field-induced transition from martensite to austenite phase. Both field- and temperature-induced martensite-austenite transitions are relatively sharp in Ni50Mn34In16. We estimate the isothermal magnetic entropy change and adiabatic temperature change across the various phase transitions in these alloys and investigate the possible influence of these transitions on the estimated magnetocaloric effect. The sharp martensitic transition in Ni50Mn34In16 gives rise to a comparatively large inverse magnetocaloric effect across this transition. On the other hand the magnitudes of the conventional magnetocaloric effect associated with the paramagnetic to ferromagnetic transition are quite comparable in these alloys.

Magnetic and magnetocaloric properties of Ni-Mn-Cr-Sn Heusler alloys under the effects of hydrostatic pressure

Science.gov (United States)

Pandey, Sudip; Us Saleheen, Ahmad; Quetz, Abdiel; Chen, Jing-Han; Aryal, Anil; Dubenko, Igor; Stadler, Shane; Ali, Naushad

2018-05-01

The magnetic, thermal, and magnetocaloric properties of Ni45Mn43CrSn11 Heusler alloy have been investigated using differential scanning calorimetry and magnetization with hydrostatic pressure measurements. A shift in the martensitic transition temperature (TM) to higher temperatures was observed with the application of pressure. The application of pressure stabilizes the martensitic state and demonstrated that pressure can be a parameter used to control and tune the martensitic transition temperature (the temperature where the largest magnetocaloric effect is observed). The magnetic entropy change significantly decreases from 33 J/kg K to 16 J/kg K under the application of a hydrostatic pressure of 0.95 GPa. The critical field of the direct metamagnetic transition increases, whereas the initial susceptibility (dM/dH) in the low magnetic field region drastically decreases with increasing pressure. The relevant parameters that affect the magnetocaloric properties are discussed.

Effect of terbium substitution on the magnetocaloric properties of Gd3Ga5O12

International Nuclear Information System (INIS)

Reshmi, C.P.; Savitha Pillai, S.; Varma, Manoj Raama; Suresh, K.G.

2011-01-01

The magnetic refrigeration is an environment friendly cooling technology based on magnetocaloric effect. The most crucial ingredient behind a magnetic refrigerator is a magnetic material which possesses large magnetocaloric effect. Certain materials when placed in a magnetic field suddenly get heats up and suddenly cooled down by the application and the removal of magnetic field due to their change in entropy. This is measured either in terms of isothermal entropy change and adiabatic temperature change observed when the applied magnetic field is varied. The refrigerators which operate below 15K have applications in liquefying helium and for the development of space based cooling system for the space crafts. The material of choice in this temperature range is rare earth gallium garnets. Rare earth garnets are complex ceramic oxides having the chemical formula A 3 B 2 C 3 O 12 have attracted attention due to their interesting magnetic properties. The magnetism in R 3 Ga 5 O 12 is due to the exchange interaction between the rare earth spins. In the proposed work we have chosen Gd 3 Ga 5 O 12 as parent material, substituted Tb systematically in the place of Gd. The structural studies were done by using Rietveld analysis of X-Ray diffraction. There is a systematic variation of volume and lattice parameter upon substitution of Tb. The magnetic characterizations were done by a vibrating sample magnetometer. The experimental magnetic moments of the materials were calculated from the M-T curve by using Curie-Weiss fit and are good agreement with the theoretical values. There is a systematic increase of magnetic moments by Tb substitution. The magnetocaloric effect is calculated by using the integrated Maxwell's relation from the magnetization data. At low magnetic fields the Tb substituted compounds show good MCE values than GGG. Tb substitution enhances the magnetocaloric effect at low magnetic fields and the ΔS M values are higher for x = 1 and 3 at 1T. Hence these

Large magnetocaloric effect of GdNiAl{sub 2} compound

Energy Technology Data Exchange (ETDEWEB)

Dembele, S.N.; Ma, Z.; Shang, Y.F. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Fu, H., E-mail: fuhao@uestc.edu.cn [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Balfour, E.A. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Hadimani, R.L.; Jiles, D.C. [Department of Electrical and Computer Engineering, Iowa State University, Ames, IA 50011 (United States); Ames Laboratory, US Department of Energy, Ames, IA 50011 (United States); Teng, B.H.; Luo, Y. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China)

2015-10-01

This paper presents the structure, magnetic properties, and magnetocaloric effect of the polycrystalline compound GdNiAl{sub 2}. Powder X-ray diffraction (XRD) measurement and Rietveld refinement revealed that GdNiAl{sub 2} alloy is CuMgAl{sub 2}-type phase structure with about 1 wt% GdNi{sub 2}Al{sub 3} secondary phase. Magnetic measurements suggest that the compound is ferromagnetic and undergoes a second-order phase transition near 28 K. The maximum value of magnetic entropy change reaches 16.0 J/kg K for an applied magnetic field change of 0–50 kOe and the relative cooling power was 6.4×10{sup 2} J/kg. It is a promising candidate as a magnetocaloric material working near liquid hydrogen temperature (~20 K) exhibiting large relative cooling power. - Highlights: • Preferred orientation with axis of [010] was found in the GdNiAl{sub 2} compound. • The ΔS{sub Mmax} and the RCP are 16.0 J/kg K and 640 J/kg, respectively, for ΔH=50 kOe. • Relative low rare earth content in GdNiAl{sub 2} comparing with other candidates.

Influence of the materials magnetic state on the accurate determination of the magnetocaloric effect

Directory of Open Access Journals (Sweden)

Forchelet J.

2012-06-01

Full Text Available In this paper, we report a detailed study of the magnetocaloric effect (MCE in different first order magnetic transition (FOMT materials with different situation of the magnetic state (magnetic order. For this purpose, R-Co2, MnAs based compounds were considered in this study. The MCE is discussed in terms of Maxwell relation (MR and Clausius-Clapeyron (C-C equation. The deviation observed between both methods is discussed and analyzed. On the other hand, practically all the reported data of the MCE in the literature are associated to the applied external magnetic field and have not been corrected taking into account the demagnetization effect related to the materials shape. The obtained results demonstrate that this phenomenon can alter drastically the MCE values by cancelling out a large part of the external field, resulting in spurious values of the measured MCE. The effect of the demagnetization field on the magnetocaloric performances is also the subject of this paper.

Anisotropy of the magnetocaloric effect in DyNiAl

Czech Academy of Sciences Publication Activity Database

Kaštil, J.; Javorský, P.; Andreev, Alexander V.

2009-01-01

Roč. 321, č. 15 (2009), s. 2318-2321 ISSN 0304-8853 Institutional research plan: CEZ:AV0Z10100520 Keywords : magnetocaloric effec * DyNiAl * magnetism * anisotropy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.204, year: 2009

Monte Carlo simulation study of magnetocaloric effect in NdMnO{sub 3} perovskite

Energy Technology Data Exchange (ETDEWEB)

Masrour, R., E-mail: rachidmasrour@hotmail.com [Laboratory of Materials, Processes, Environment and Quality, Cady Ayyed University, National School of Applied Sciences, PB 63 46000 Safi (Morocco); Laboratoire de Magnétisme et Physique des Hautes Energies L.M.P.H.E.URAC 12, Université Mohammed V, Faculté des Sciences, B.P. 1014, Rabat (Morocco); Jabar, A. [Laboratoire de Magnétisme et Physique des Hautes Energies L.M.P.H.E.URAC 12, Université Mohammed V, Faculté des Sciences, B.P. 1014, Rabat (Morocco); Benyoussef, A. [Laboratoire de Magnétisme et Physique des Hautes Energies L.M.P.H.E.URAC 12, Université Mohammed V, Faculté des Sciences, B.P. 1014, Rabat (Morocco); Institute of Nanomaterials and Nanotechnologies, MAScIR, Rabat (Morocco); Hassan II Academy of Science and Technology, Rabat (Morocco); Hamedoun, M. [Institute of Nanomaterials and Nanotechnologies, MAScIR, Rabat (Morocco); Hlil, E.K. [Institut Curie, CNRS et Université Joseph Fourier, BP 166, F-38042 Grenoble Cedex 9 (France)

2016-03-01

The magnetocaloric effect in NdMnO{sub 3} perovskite is investigated by using the Monte Carlo simulations. The Curie temperature T{sub C} of NdMnO{sub 3} compound is deduced from the variation of the magnetization vs. the temperature with different values of external magnetic field. The variation of magnetization with the external magnetic field H is given. The specific heat with the temperature is established for different external magnetic field. The thermal magnetic entropy for different external magnetic field and different exchange interactions in NdMnO{sub 3} compound is obtained. The adiabatic temperature change is obtained. The relative cooling power with different external magnetic field is established. The magnetocaloric effect has been investigated from magnetization. - Highlights: • Results obtained show that the PM–FM transition is of second order in NdMnO{sub 3}. • Critical properties of NdSi at the FM–PM transition have been analyzed. • The Curie temperature and magnetic entropy have been obtained.

Pressure effects on the magnetocaloric properties of MnFeP1-x As x

International Nuclear Information System (INIS)

Brueck, E.; Kamarad, J.; Sechovsky, V.; Arnold, Z.; Tegus, O.; Boer, F.R. de

2007-01-01

We studied the effect of hydrostatic pressure on the magnetic and magnetocaloric properties of the potential magnetic-refrigerant materials MnFeP 1- x As x with x=0.35 and 0.55. While applied pressure reduces both the Curie temperature and magnetic moment of the former compound, the Curie temperature of the latter is increased whereas the moment is hardly affected by pressure. The same trends are seen in the magnetocaloric properties. These results indicate a different character of the magnetism in these two materials. While the compound with x=0.35 exhibits a volume instability like a weak itinerant ferromagnet, whereas the one with x=0.55 behaves as a strong itinerant ferromagnet. An alternative scenario may be formulated within the localized-moment picture. One may interpret the effect of pressure on the compound with x=0.35 as an indication of pressure-induced enhancement of antiferromagnetic interactions. This latter interpretation is offered by a pronounced enhancement of the high-field susceptibility under pressure

Indirect measurement of the magnetocaloric effect using a novel differential scanning calorimeter with magnetic field

DEFF Research Database (Denmark)

Jeppesen, Stinus; Linderoth, Søren; Pryds, Nini

2008-01-01

A simple and high-sensitivity differential scanning calorimeter (DSC) unit operating under magnetic field has been built for indirect determination of the magnetocaloric effect. The principle of the measuring unit in the calorimeter is based on Peltier elements as heat flow sensors. The high...

Magnetocaloric properties of the hexagonal HoMnO{sub 3} single crystal revisited

Energy Technology Data Exchange (ETDEWEB)

Balli, M., E-mail: Mohamed.balli@Usherbrooke.ca [Regroupement québécois sur les matériaux de pointe, Département de physique, Université de Sherbrooke, QC, Canada J1K 2R1 (Canada); Roberge, B.; Vermette, J.; Jandl, S. [Regroupement québécois sur les matériaux de pointe, Département de physique, Université de Sherbrooke, QC, Canada J1K 2R1 (Canada); Fournier, P. [Regroupement québécois sur les matériaux de pointe, Département de physique, Université de Sherbrooke, QC, Canada J1K 2R1 (Canada); Canadian Institute for Advanced Research, Toronto, Ontario, Canada M5G 1Z8 (Canada); Gospodinov, M.M. [Institute of Solid State Physics, Bulgarian Academy of Science, Sofia 1184 (Bulgaria)

2015-12-01

Magnetic and magnetocaloric properties of the hexagonal HoMnO{sub 3} single crystal have been revisited. It was found that the magnetocaloric effect shown by HoMnO{sub 3} strongly depends on the crystal orientation in respect to the applied magnetic field. Consequently, a large thermal effect can be induced by spinning the single crystal HoMnO{sub 3} around the a (or b) axis in a constant magnetic field instead of the conventional magnetization–demagnetization process. Under 7 T, the maximum rotating entropy change was evaluated to be about 8 J/kg K. The associated adiabatic temperature change reaches a value of about 5 K. These values are comparable to those of the other oxides exhibiting a large rotating magnetocaloric effect. The presence of both conventional and rotating thermal effects makes the hexagonal HoMnO{sub 3} more interesting from a practical point of view.

Magnetocaloric properties and critical behavior of high relative cooling power FeNiB nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Chaudhary, V. [Interdisciplinary Graduate School, Nanyang Technological University, Singapore 639798 (Singapore); Energy Research Institute @NTU, Nanyang Technological University, Singapore 637553 (Singapore); School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Maheswar Repaka, D. V.; Chaturvedi, A.; Ramanujan, R. V., E-mail: ramanujan@ntu.edu.sg [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Sridhar, I. [School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

2014-10-28

Low cost magnetocaloric nanomaterials have attracted considerable attention for energy efficient applications. We report a very high relative cooling power (RCP) in a study of the magnetocaloric effect in quenched FeNiB nanoparticles. RCP increases from 89.8 to 640 J kg{sup −1} for a field change of 1 and 5 T, respectively, these values are the largest for rare earth free iron based magnetocaloric nanomaterials. To investigate the magnetocaloric behavior around the Curie temperature (T{sub C}), the critical behavior of these quenched nanoparticles was studied. Detailed analysis of the magnetic phase transition using the modified Arrott plot, Kouvel-Fisher method, and critical isotherm plots yields critical exponents of β = 0.364, γ = 1.319, δ = 4.623, and α = −0.055, which are close to the theoretical exponents obtained from the 3D-Heisenberg model. Our results indicate that these FeNiB nanoparticles are potential candidates for magnetocaloric fluid based heat pumps and low grade waste heat recovery.

Materials Challenges for High Performance Magnetocaloric Refrigeration Devices

DEFF Research Database (Denmark)

Smith, Anders; Bahl, Christian; Bjørk, Rasmus

2012-01-01

Magnetocaloric materials with a Curie temperature near room temperature have attracted signifi cant interest for some time due to their possible application for high-effi ciency refrigeration devices. This review focuses on a number of key issues of relevance for the characterization, performance....... The question of how to evaluate the suitability of a given material for use in a magnetocaloric device is covered in some detail, including a critical assessment of a number of common performance metrics. Of particular interest is which non-magnetocaloric properties need to be considered in this connection....... An overview of several important materials classes is given before considering the performance of materials in actual devices. Finally, an outlook on further developments is presented....

Pressure effect on phase transitions and magnetocaloric effect in Gd.sub.5./sub.Ge.sub.4./sub..

Czech Academy of Sciences Publication Activity Database

Arnold, Zdeněk; Skorokhod, Yuriy; Kamarád, Jiří; Magen, C.; Algarabel, P.A.

2009-01-01

Roč. 105, č. 3 (2009), 07A934/1-07A934/3 ISSN 0021-8979 R&D Projects: GA ČR(CZ) GA106/06/0368 Institutional research plan: CEZ:AV0Z10100521 Keywords : Curie temperature * ferromagnetic materials * ferromagnetic-antiferromagnetic transitions * gadolinium compounds * magnetocaloric effect Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.072, year: 2009

Design, fabrication and thermal characterization of a magnetocaloric microcooler

Energy Technology Data Exchange (ETDEWEB)

Kim, S.; Ghirlanda, S.; Adams, C.; Bethala, B.; Sambandam, S.N.; Bhansali, S. [BioMEMS and Microsystems Laboratory, Department of Electrical Engineering, University of South Florida, 4202 E. Fowler Ave., ENB118, Tampa, FL 33620, (United States)

2006-12-11

Magnetocaloric cooling is an alternative, high-efficiency cooling technology. In this paper, we present the design and fabrication of a micromachined magnetocaloric cooler and demonstrate its ability to work in a small magnetic field (<1.2 T) with a cooling test. The cooler was built by fabricating Si microfluidic channels, and it was integrated with a Gd{sub 5}(Si{sub 2}Ge{sub 2}) magnetocaloric refrigeration element. The magnetic properties of the Gd{sub 5}(Si{sub 2}Ge{sub 2}) material were characterized to calculate the magnetic entropy change at different ambient temperatures. Three different methods to integrate the channel layer and the magnetocaloric element were evaluated to test sealing and cooling performance. The cooling tests were performed by providing a magnetic field using an electromagnet. A test jig was constructed between the poles of an electromagnet to maintain a steady temperature during the test. Cooling tests were performed on the magnetocaloric element at ambient temperatures ranging from 258 to 280 K using a magnetic field of 1.2 T. Experimental results showed a maximum temperature change of 7 K on the magnetocaloric element alone at an ambient temperature of 258 K. Cooling tests of the fully integrated coolers were also performed. A solution of anti-freeze fluid (propylene glycol) and water was used as the coolant. The temperature of the working fluid decreased by 4.6 and 9 K for the glass and Si intermediate layers, respectively, confirming that the thermal conductivity of the materials is also an important factor in cooler performance. (Author)

Multifunctional phenomena in rare-earth intermetallic compounds with a laves phase structure: giant magnetostriction and magnetocaloric effect

Czech Academy of Sciences Publication Activity Database

Tereshina, I.; Cwik, J.; Tereshina, Evgeniya; Politova, G.; Burkhanov, G.; Chzhan, V.; Ilyushin, A.; Miller, M.; Zaleski, A.; Nenkov, K.; Schultz, L.

2014-01-01

Roč. 50, č. 11 (2014), s. 2504604 ISSN 0018-9464 Institutional support: RVO:68378271 Keywords : giant magnetostriction * Laves phase structure * magnetic anisotropy * magnetocaloric effect * rare-earth intermetallic Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.386, year: 2014

Magnetocaloric effect of Gd4(BixSb1-x)3 alloy series

International Nuclear Information System (INIS)

Niu, Xuejun

1999-01-01

Alloys from the Gd 4 (Bi x Sb 1-x ) 3 series were prepared by melting a stoichiometric amounts of pure metals in an induction furnace. The crystal structure is of the anti-Th 3 P 4 type (space group Ibar 43d) for all the compounds tested. The linear increase of the lattice parameters with Bi concentration is attributed to the larger atomic radius of Bi than that of Sb. Magnetic measurements show that the alloys order ferromagnetically from 266K to 330K, with the ordering temperature increasing with decreasing Bi concentration. The alloys are soft ferromagnets below their Curie temperatures, and follow the Curie-Weiss law above their ordering temperatures. The paramagnetic effective magnetic moments are low compared to the theoretical value for a free Gd 3+ , while the ordered magnetic moments are close to the theoretical value for Gd. The alloys exhibit a moderate magnetocaloric effect (MCE) whose maxima are located between 270K and 338K and have relatively wide peaks. The peak MCE temperature decreases with decreasing Bi concentration while the peak height increases with decreasing Bi concentration. The Curie temperatures determined from inflection points of heat capacity are in good agreement with those obtained from the magnetocaloric effect. The MCE results obtained from the two different methods (magnetization and heat capacity) agree quite well with each other for all of the alloys in the series

Effective medium theory for anisotropic metamaterials

KAUST Repository

Zhang, Xiujuan

2015-01-20

Materials with anisotropic material parameters can be utilized to fabricate many fascinating devices, such as hyperlenses, metasolids, and one-way waveguides. In this study, we analyze the effects of geometric anisotropy on a two-dimensional metamaterial composed of a rectangular array of elliptic cylinders and derive an effective medium theory for such a metamaterial. We find that it is possible to obtain a closed-form analytical solution for the anisotropic effective medium parameters, provided the aspect ratio of the lattice and the eccentricity of the elliptic cylinder satisfy certain conditions. The derived effective medium theory not only recovers the well-known Maxwell-Garnett results in the quasi-static regime, but is also valid beyond the long-wavelength limit, where the wavelength in the host medium is comparable to the size of the lattice so that previous anisotropic effective medium theories fail. Such an advance greatly broadens the applicable realm of the effective medium theory and introduces many possibilities in the design of structures with desired anisotropic material characteristics. A real sample of a recently theoretically proposed anisotropic medium, with a near-zero index to control the flux, is achieved using the derived effective medium theory, and control of the electromagnetic waves in the sample is clearly demonstrated.

Pressure effects on the magnetocaloric properties of MnFeP.sub.1-x./sub.As.sub.x./sub..

Czech Academy of Sciences Publication Activity Database

Brück, E.; Kamarád, Jiří; Sechovský, V.; Arnold, Zdeněk; Tegus, O.; De Boer, F. R.

2007-01-01

Roč. 310, - (2007), e1008-e1009 ISSN 0304-8853 Institutional research plan: CEZ:AV0Z10100521 Keywords : magnetic refrigeration * magnetocaloric effect * pressure effect * MnFe(P, As) compounds Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.704, year: 2007

Europium substitution effects on structural, magnetic and magnetocaloric properties in La0.5Ca0.5MnO3

Directory of Open Access Journals (Sweden)

Boujelben W.

2012-06-01

Full Text Available We have investigated structural, magnetic and magnetocaloric properties of polycrystalline samples La0.5-xEuxCa0.5MnO3 (x=0 and 0.1. Rietveld refinement of the X-ray diffraction patterns show that our samples are single phase and crystallize in the orthorhombic structure with Pnma space group. Magnetization measurements versus temperature at a magnetic applied field of 500 Oe indicate that La0.4Eu0.1Ca0.5MnO3 sample exhibits a paramagnetic to ferromagnetic transition with decreasing temperature. Magnetic measurements reveal strong magnetocaloric effect in the vicinity of the Curie temperature TC. The parent compound shows a negative magnetic entropy change of ∆SM=−1.13Jkg−1K−1 at 220K and a positive magnetocaloric effects ∆SM=1Jkg−1K−1 at 150K under a magnetic applied field of 2T. La0.4Eu0.1Ca0.5MnO3 exhibits a maximum value of magnetic entropy change ∆SM=−1.15Jkg−1K−1 at 130K under an applied field of 2T and a large relative cooling power RCP with a maximum value of 72 J/kg.

Magnetocaloric materials and first order phase transitions

DEFF Research Database (Denmark)

Neves Bez, Henrique

and magnetocaloric regenerative tests. The magnetic, thermal and structural properties obtained from such measurements are then evaluated through different models, i.e. the Curie-Weiss law, the Bean-Rodbell model, the free electron model and the Debye model.The measured magnetocaloric properties of La0.67Ca0.33MnO3...... heat capacity, magnetization and entropy change measurements. By measuring bulky particles (with a particle size in the range of 5001000 μm) of La(Fe,Mn,Si)13Hz with first order phase transition, it was possible to observe very sharp transitions. This is not the case for finer ground particles which......This thesis studies the first order phase transitions of the magnetocaloric materials La0.67Ca0.33MnO3 and La(Fe,Mn,Si)13Hz trying to overcome challenges that these materials face when applied in active magnetic regenerators. The study is done through experimental characterization and modelling...

Performance-oriented Analysis of a Hybrid magnetic Assembly for a Heat-pump Magnetocaloric Device

DEFF Research Database (Denmark)

Insinga, Andrea Roberto; Smith, Anders; Bahl, Christian R.H.

2014-01-01

Conventional active-regenerator magnetocaloric devices include moving parts, with the purpose of generating an oscillating magnetic field in the magneto-caloric material, placed inside the regenerator. In this work a different design is analyzed, for application in a magnetocaloric heat pump...

Magnetocaloric effect in potassium doped lanthanum manganite perovskites prepared by a pyrophoric method

Science.gov (United States)

Das, Soma; Dey, T. K.

2006-08-01

The magnetocaloric effect (MCE) in fine grained perovskite manganites of the type La1-xKxMnO3 (0value of 3.00 J kg-1 K-1 at 310 K amongst the compounds investigated. Moreover, the maximum magnetic entropy change exhibits a linear dependence with applied magnetic field. The estimated adiabatic temperature change at TC and at 1 T field also increases with K doping, being a maximum of 2.1 K for the La0.85K0.15MnO3 compound. The relative cooling power (RCP) of La1-xKxMnO3 compounds is estimated to be about one-third of that of the prototype magnetic refrigerant material (pure Gd). However, La1-xKxMnO3 compounds possess an MCE around room temperature, which is comparable to that of Gd. Further, tailoring of their TC, higher chemical stability, lower eddy current heating and lower cost of synthesis are some of the attractive features of K doped lanthanum manganites that are advantageous for a magnetic refrigerant. The temperature dependence of the magnetic entropy change (ΔSM) measured under various magnetic fields is explained fairly well using the Landau theory of phase transitions. Contributions of magnetoelastic and electron interaction are found to have a strong influence in the magnetocaloric effect of manganites.

Giant reversible magnetocaloric effect in flower-like β-Co(OH){sub 2} hierarchical superstructures self-assembled by nanosheets

Energy Technology Data Exchange (ETDEWEB)

Liu, Xianguo; Feng, Chao; Xiao, Feng; Jin, Chuangui; Xia, Ailin, E-mail: liuxianguohugh@gmail.com, E-mail: eeswor@polyu.edu.hk [Anhui Key Laboratory of Metal Materials and Processing, School of Materials Science and Engineering, Anhui University of Technology, Ma' anshan, PR (China); Or, Siu Wing [Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Sun, Yuping [Center for Engineering Practice and Innovation Education, Anhui University of Technology, Ma' anshan, PR (China)

2014-01-15

A facile hydrothermal strategy is proposed to synthesize flower-like β- Co(OH){sub 2} hierarchical microspherical superstructures with a diameter of 0.5-1.5 µm, which are self-assembled by β - Co(OH){sub 2} nano sheets with the average thickness ranging between 20 and 40 nm. The magnetocaloric effect associated with magnetic phase transitions in Co(OH){sub 2} superstructures has been investigated. A sign change in the magnetocaloric effect is induced by a magnetic field, which is related to a filed-induced transition from the antiferromagnetic to the ferromagnetic state below the Néel temperature. The large reversible magnetic-entropy change –ΔS{sub m} (13.4 J/kg K at 15 K for a field change of 5 T) indicates that flower-like Co(OH){sub 2} superstructures is a potential candidate for application in magnetic refrigeration in the low-temperature range. (author)

The normal and inverse magnetocaloric effect in RCu2 (R=Tb, Dy, Ho, Er) compounds

International Nuclear Information System (INIS)

Zheng, X.Q.; Xu, Z.Y.; Zhang, B.; Hu, F.X.; Shen, B.G.

2017-01-01

Orthorhombic polycrystalline RCu 2 (R=Tb, Dy, Ho and Er) compounds were synthesized and the magnetic properties and magnetocaloric effect (MCE) were investigated in detail. All of the RCu 2 compounds are antiferromagnetic (AFM) ordered. As temperature increases, RCu 2 compounds undergo an AFM to AFM transition at T t and an AFM to paramagnetic (PM) transition at T N . Besides of the normal MCE around T N , large inverse MCE around T t was found in TbCu 2 compound. Under a field change of 0–7 T, the maximal value of inverse MCE is even larger than the value of normal MCE around T N for TbCu 2 compound. Considering of the normal and inverse MCE, TbCu 2 shows the largest refrigerant capacity among the RCu 2 (R=Tb, Dy, Ho and Er) compounds indicating its potential applications in low temperature multistage refrigeration. - Highlights: • Large inverse magnetocaloric effect is observed in TbCu 2 compound. • The AFM to AFM transition is observed in RCu 2 (R=Tb, Dy, Ho, Er) compounds. • The MCE performance of TbCu 2 compound is evaluated in a more comprehensively way.

Glassy formation ability, magnetic properties and magnetocaloric effect in Al27Cu18Er55 amorphous ribbon

Science.gov (United States)

Li, Lingwei; Xu, Chi; Yuan, Ye; Zhou, Shengqiang

2018-05-01

In this work, we have fabricated the Al27Cu18Er55 amorphous ribbon with good glassy formation ability by melt-spinning technology. A broad paramagnetic (PM) to ferromagnetic (FM) transition (second ordered) together with a large reversible magnetocaloric effect (MCE) in Al27Cu18Er55 amorphous ribbon was observed around the Curie temperature TC ∼ 11 K. Under the magnetic field change (ΔH of 0-7 T, the values of MCE parameter of the maximum magnetic entropy change (-ΔSMmax) and refrigerant capacity (RC) for Al27Cu18Er55 amorphous ribbon reach 21.4 J/kg K and 599 J/kg, respectively. The outstanding glass forming ability as well as the excellent magneto-caloric properties indicate that Al27Cu18Er55 amorphous could be a good candidate for low temperature magnetic refrigeration.

Effect of rapid quenching on the magnetism and magnetocaloric effect of equiatomic rare earth intermetallic compounds RNi (R = Gd, Tb and Ho)

Energy Technology Data Exchange (ETDEWEB)

Rajivgandhi, R. [Department of Physics, Indian Institute of Technology Madras, Chennai 600 036 (India); Arout Chelvane, J. [Defence Metallurgical Research Laboratory, Hyderabad 500 058 (India); Quezado, S.; Malik, S.K. [Departamento de F’ısica Teorica e Experimental, Universidade Federal do Rio Grande do Norte, Natal 59072-970 (Brazil); Nirmala, R., E-mail: nirmala@physics.iitm.ac.in [Department of Physics, Indian Institute of Technology Madras, Chennai 600 036 (India)

2017-07-01

Highlights: • Melt-spinning yields microcrystalline RNi (R = Gd, Tb and Ho) samples with texture. • The texture-induced anisotropy affects magnetic and magnetocaloric properties. • Melt-spinning helps one engineer magnetocaloric effect in rare-earth compounds. - Abstract: Magnetocaloric effect (MCE) in RNi (where R = Gd, Tb and Ho) compounds has been studied in their arc-melted and melt-spun forms. The compound GdNi has the orthorhombic CrB-type structure (Space group Cmcm, No. 63) and the compound HoNi has the orthorhombic FeB-type structure (Space group Pnma, No. 62) at room temperature regardless of their synthesis condition. However, arc-melted TbNi orders in a monoclinic structure (Space group P2{sub 1}/m, No. 11) and when it is rapidly quenched to a melt-spun form, it crystallizes in an orthorhombic structure (Space group Pnma, No. 62). The arc-melted GdNi, TbNi and HoNi compounds order ferromagnetically at ∼69 K, ∼67 K and ∼36 K (T{sub C}) respectively. While the melt-spun GdNi shows about 6 K increase in T{sub C}, the ordering temperature of TbNi remains nearly the same in both arc-melted and melt-spun forms. In contrast, a reduction in T{sub C} by about 8 K is observed in melt-spun HoNi, when compared to its arc-melted counterpart. Isothermal magnetic entropy change, ∆S{sub m}, calculated from the field dependent magnetization data indicates an enhanced relative cooling power (RCP) for melt-spun GdNi for field changes of 20 kOe and 50 kOe. A lowered RCP value is observed in melt-spun TbNi and HoNi. These changes could have resulted from the competing shape anisotropy and the granular microstructure induced by the melt-spinning process. Tailoring the MCE of rare earth intermetallic compounds by suitably controlled synthesis techniques is certainly one of the directions to go forward in the search of giant magnetocaloric materials.

Study of the magnetic phase transitions and magnetocaloric effect in Dy{sub 2}Cu{sub 2}In compound

Energy Technology Data Exchange (ETDEWEB)

Zhang, Yikun, E-mail: ykzhang10@hotmail.com [State Key Laboratory of Advanced Special Steels, Shanghai University, Shanghai, 200072 (China); Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University, Shanghai, 200072 (China); School of Materials Science and Engineering, Shanghai University, 200072 (China); Institute of Materials Physics, University of Münster, Wilhelm-Klemm-Straße 10, D-48149, Münster (Germany); Xu, Xiao; Yang, Yang; Hou, Long; Ren, Zhongming [State Key Laboratory of Advanced Special Steels, Shanghai University, Shanghai, 200072 (China); Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University, Shanghai, 200072 (China); School of Materials Science and Engineering, Shanghai University, 200072 (China); Li, Xi, E-mail: lx_net@sina.com [State Key Laboratory of Advanced Special Steels, Shanghai University, Shanghai, 200072 (China); Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University, Shanghai, 200072 (China); School of Materials Science and Engineering, Shanghai University, 200072 (China); Wilde, Gerhard [Institute of Materials Physics, University of Münster, Wilhelm-Klemm-Straße 10, D-48149, Münster (Germany)

2016-05-15

The magnetic properties and magnetocaloric effect (MCE) in Dy{sub 2}Cu{sub 2}In compound have been investigated. Dy{sub 2}Cu{sub 2}In undergoes two magnetic phase transitions, a paramagnetic to ferromagnetic (FM) at T{sub C} ∼ 49.5 K followed by a spin reorientation (SR) at T{sub SR} ∼ 19.5 K. For a magnetic field change of 0–7 T, the maximum values of the magnetic entropy change (−ΔS{sub M}{sup max}) are estimated to be 16.5 around T{sub C} and 6.7 J/kg K around T{sub SR} with a large relative cooling power (RCP) value of 617 J/kg. The modified Arrott plots and universal curves of the rescaled ΔS{sub M} confirmed that the magnetic phase transitions in Dy{sub 2}Cu{sub 2}In compound belongs the second order phase transitions. The present results may provide some clues to search for new magnetocaloric materials belonging to RE{sub 2}T{sub 2}X system. - Highlights: • Magnetic properties and magnetocaloric effect in Dy{sub 2}Cu{sub 2}In was studied. • The Dy{sub 2}Cu{sub 2}In undergoes 2 s order magnetic phase transitions. • A large reversible MCE was observed in Dy{sub 2}Cu{sub 2}In. • The origin of MCE and its potential application in Dy{sub 2}Cu{sub 2}In were discussed.

Magnetocaloric effect, thermal conductivity, and magnetostriction of epoxy-bonded La(Fe0.88Si0.12)13 hydrides

Science.gov (United States)

Matsumoto, K.; Murayama, D.; Takeshita, M.; Ura, Y.; Abe, S.; Numazawa, T.; Takata, H.; Matsumoto, Y.; Kuriiwa, T.

2017-09-01

Magnetic materials with large magnetocaloric effect are significantly important for magnetic refrigeration. La(Fe0.88Si0.12)13 compounds are one of the promising magnetocaloric materials that have a first order magnetic phase transition. Transition temperature of hydrogenated La(Fe0.88Si0.12)13 increased up to room temperature region while keeping metamagnetic transition properties. From view point of practical usage, bonded composite are very attractive and their properties are important. We made epoxy bonded La(Fe0.88Si0.12)13 hydrides. Magnetocaloric effect was studied by measuring specific heat, magnetization, and temperature change in adiabatic demagnetization. The composite had about 20% smaller entropy change from the hydrogenated La(Fe0.88Si0.12)13 powder in 2 T. Thermal conductivity of the composite was several times smaller than La(Fe,Si)13. The small thermal conductivity was explained due to the small thermal conductivity of epoxy. Thermal conductivity was observed to be insensitive to magnetic field in 2 T. Thermal expansion and magnetostriction of the composite material were measured. The composite expanded about 0.25% when it entered into ferromagnetic phase. Magnetostriction of the composite in ferromagnetic phase was about 0.2% in 5 T and much larger than that in paramagnetic phase. The composite didn’t break after about 100 times magnetic field changes in adiabatic demagnetization experiment even though it has magnetostriction.

Magnetic and magnetocaloric properties of amorphous Y{sub 3}Fe{sub 5}O{sub 12} compound

Energy Technology Data Exchange (ETDEWEB)

Nóbrega, E.P., E-mail: pilad@cbpf.br; Costa, S.S.; Alvarenga, T.S.T.; Alho, B.P.; Caldas, A.; Ribeiro, P.O.; Sousa, V.S.R de; Oliveira, N.A. de; Ranke, P.J. von

2017-01-15

We report a theoretical model formed by two coupled magnetic sublattices of localized spins in the presence of an applied magnetic field to investigate the magnetic characteristics and magnetocaloric properties of amorphous yttrium iron garnet. The magnetic state equation is based on Handrich–Kobe´s theory, where the amorphization is taken into account by introducing fluctuations in the exchange parameters. Experimental results report that Y{sub 3}Fe{sub 5}O{sub 12} presents a structural phase transition from crystalline to amorphous caused by a variation of external pressure. This phase transition on Y{sub 3}Fe{sub 5}O{sub 12} leads to interesting results in the magnetic properties and magnetocaloric quantities. - Highlights: • Study of magnetic and magnetocaloric properties of amorphous Y{sub 3}Fe{sub 5}O{sub 12} compound. • Theoretical model formed by two coupled magnetic sublattices of localized spins in the presence of an applied magnetic field. • The influence of crystalline/amorphous transition on the magnetocaloric effect.

Three isostructural one-dimensional Ln(III) chains with distorted cubane motifs showing dual fluorescence and slow magnetic relaxation/magnetocaloric effect.

Science.gov (United States)

Li, Yan; Yu, Jia-Wen; Liu, Zhong-Yi; Yang, En-Cui; Zhao, Xiao-Jun

2015-01-05

Three new homometallic lanthanide complexes with mixed carboxylate-modified rigid ligands, [Ln(μ3-OH)(na)(pyzc)]n (na(-) = 1-naphtholate, pyzc(-) = 2-pyrazinecarboxylate, Ln = Dy (1), Yb (2), and Gd (3)), were solvothermally synthesized, and their structures and magnetic as well as photophysical properties were completely investigated. Complexes 1-3 are crystallographically isostructural, exhibiting linear chains with four bidentate bridging μ-COO(-) moieties encapsulated cubic {Ln4(μ3-OH)4}(8+) clusters repeatedly extended by 4-fold chelating-bridging-pyzc(-) connectors. Magnetically, the former two complexes with highly anisotropic Dy(III) and weak anisotropic Yb(III) ions in the distorted NO7 triangular dodecahedron coordination environment display field-induced slow relaxation of magnetization. Fitting the dynamic magnetic data to the Arrhenius law gives energy barrier ΔE/kB = 39.6 K and pre-exponential factor τo = 1.52 × 10(-8) s for 1 and ΔE/kB = 14.1 K and τo = 2.13 × 10(-7) s for 2. By contrast, complex 3 with isotropic Gd(III) ion and weak intracluster antiferromagnetic coupling shows a significant cryogenic magnetocaloric effect, with a maximum -ΔSm value of 30.0 J kg(-1) K(-1) at 2.5 K and 70 kOe. Additionally, the chromophoric na(-) and pyzc(-) ligands can serve as antenna groups, selectively sensitizing the Dy(III)- and Yb(III)-based luminescence of 1 and 2 in the UV-visible region by an intramolecular energy transfer process. Thus, complexes 1-3, incorporating field-induced slow magnetic magnetization and interesting luminescence together, can be used as composite magneto-optical materials. More importantly, these interesting results further demonstrate that the mixed-ligand system with rigid carboxylate-functionalized chromophores can be excellent candidates for the preparations of new bifunctional magneto-optical materials.

Pressure enhancement of the giant magnetocaloric effect in LaFe.sub.11.6./sub.Si.sub.1.4./sub..

Czech Academy of Sciences Publication Activity Database

Sun, Y.; Arnold, Zdeněk; Kamarád, Jiří; Wang, G.-J.; Shen, B.G.; Cheng, Z.-H.

2006-01-01

Roč. 89, č. 17 (2006), 172513/1-172513/3 ISSN 0003-6951 R&D Projects: GA ČR GA202/06/0178 Institutional research plan: CEZ:AV0Z10100521 Keywords : intermetallic compounds * magnetocaloric effect * pressure effect Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.977, year: 2006

Colossal magnetocaloric effect in magneto-auxetic systems

Science.gov (United States)

Dudek, M. R.; Wojciechowski, K. W.; Grima, J. N.; Caruana-Gauci, R.; Dudek, K. K.

2015-08-01

We show that a mechanically driven magnetocaloric effect (MCE) in magneto-auxetic systems (MASs) in the vicinity of room temperature is possible and the effect can be colossal. Even at zero external magnetic field, the magnetic entropy change in this reversible process can be a few times larger in magnitude than in the case of the giant MCE discovered by Pecharsky and Gschneidner in Gd5(Si2Ge2). MAS represent a novel class of metamaterials having magnetic insertions embedded within a non-magnetic matrix which exhibits a negative Poisson’s ratio. The auxetic behaviour of the non-magnetic matrix may either enhance the magnetic ordering process or it may result in a transition to the disordered phase. In the MAS under consideration, a spin 1/2 system is chosen for the magnetic component and the well-known Onsager solution for the two-dimensional square lattice Ising model at zero external magnetic field is used to show that the isothermal change in magnetic entropy accompanying the auxetic behaviour can take a large value at room temperature. The practical importance of our findings is that MCE materials used in present engineering applications may be further enhanced by changing their geometry such that they exhibit auxetic behaviour.

Colossal magnetocaloric effect in magneto-auxetic systems

International Nuclear Information System (INIS)

Dudek, M R; Dudek, K K; Wojciechowski, K W; Grima, J N; Caruana-Gauci, R

2015-01-01

We show that a mechanically driven magnetocaloric effect (MCE) in magneto-auxetic systems (MASs) in the vicinity of room temperature is possible and the effect can be colossal. Even at zero external magnetic field, the magnetic entropy change in this reversible process can be a few times larger in magnitude than in the case of the giant MCE discovered by Pecharsky and Gschneidner in Gd 5 (Si 2 Ge 2 ). MAS represent a novel class of metamaterials having magnetic insertions embedded within a non-magnetic matrix which exhibits a negative Poisson’s ratio. The auxetic behaviour of the non-magnetic matrix may either enhance the magnetic ordering process or it may result in a transition to the disordered phase. In the MAS under consideration, a spin 1/2 system is chosen for the magnetic component and the well-known Onsager solution for the two-dimensional square lattice Ising model at zero external magnetic field is used to show that the isothermal change in magnetic entropy accompanying the auxetic behaviour can take a large value at room temperature. The practical importance of our findings is that MCE materials used in present engineering applications may be further enhanced by changing their geometry such that they exhibit auxetic behaviour. (paper)

Second Law Violation By Magneto-Caloric Effect Adiabatic Phase Transition of Type I Superconductive Particles

Directory of Open Access Journals (Sweden)

Peter Keefe

2004-03-01

Full Text Available Abstract: The nature of the thermodynamic behavior of Type I superconductor particles, having a cross section less than the Ginzburg-Landau temperature dependent coherence length is discussed for magnetic field induced adiabatic phase transitions from the superconductive state to the normal state. Argument is advanced supporting the view that when the adiabatic magneto-caloric process is applied to particles, the phase transition is characterized by a decrease in entropy in violation of traditional formulations of the Second Law, evidenced by attainment of a final process temperature below that which would result from an adiabatic magneto-caloric process applied to bulk dimensioned specimens.

Large roomtemperature magnetocaloric effect with negligible magnetic hysteresis losses in Mn1-xVxCoGe alloys

International Nuclear Information System (INIS)

Ma, S.C.; Zheng, Y.X.; Xuan, H.C.; Shen, L.J.; Cao, Q.Q.; Wang, D.H.; Zhong, Z.C.; Du, Y.W.

2012-01-01

The magnetic and magnetocaloric properties have been investigated in a series of Mn 1-x V x CoGe (x=0.01, 0.02, 0.03, and 0.05) alloys. The substitution of V for Mn reduces the structural transformation temperature of MnCoGe alloy effectively and results in a second-order magnetic transition in Mn 0.95 V 0.05 CoGe alloys. Large room temperature magnetocaloric effect and almost zero magnetic hysteresis losses are simultaneously achieved in the alloys with x=0.01, 0.02, and 0.03. The reasons for the negligible magnetic hysteresis losses and the potential application for the roomtemperature magnetic refrigeration are discussed. - Highlights: → V-substitution for Mn reduces the structural transformation temperature of MnCoGe. → FM-PM transition presents the second-order nature in Mn0.95V0.05CoGe. → The first-order FM-PM transitions are observed for alloys with x=0.01, 0.02, and 0.03. → Large room temperature MCEs are achieved in these alloys. → Negligible magnetic HL is achieved for these alloys simultaneously.

Conventional and inverse magnetocaloric effect in Pr2CuSi3 and Gd2CuSi3 compounds

International Nuclear Information System (INIS)

Wang, Fang; Yuan, Feng-ying; Wang, Jin-zhi; Feng, Tang-fu; Hu, Guo-qi

2014-01-01

Highlights: • Two phase transitions in a narrow temperature range were observed and studied. • Both typical and inverse magnetocaloric effect were observed and discussed. • The inverse magnetocaloric effect was attributed to the spin-glass behavior. - Abstract: Magnetic properties and magnetocaloric effect (MCE) in Pr 2 CuSi 3 and Gd 2 CuSi 3 compounds were investigated systematically. Both Pr 2 CuSi 3 and Gd 2 CuSi 3 compounds experienced two phase transitions in a relatively narrow temperature range: first a paramagnet (PM)–ferromagnet (FM) second-order phase transition at 12 and 26 K and then a FM–spin glass (SG) transition at 6 K and 7.5 K, respectively. The magnetic entropy change (ΔS M ) was calculated based on Maxwell relation using the collected magnetization data. The maximum of ΔS M for Pr 2 CuSi 3 and Gd 2 CuSi 3 compounds was 7.6 and 5 J kg −1 K −1 , respectively, at the applied filed change of 0–5 T. The shape of the temperature dependence of ΔS M (ΔS M –T) curve was obviously different from that of the conventional magnetic materials undergoing only one typical phase transition. In the left half part of ΔS M –T curve, ΔS M is not very sensitive to the applied field and they tend to intersect with the decrease of temperature. Both typical conventional and inverse MCE behavior were observed in Gd 2 CuSi 3 , which would be originated from the two transition features at the low temperatures

Simulation of the magnetocaloric effect in Tb nanofilms

Energy Technology Data Exchange (ETDEWEB)

Anselmo, Dory Hélio A. L., E-mail: doryh@dfte.ufrn.br [Departamento de Física Teórica e Experimental (DFTE), Universidade Federal do Rio Grande do Norte (UFRN), Natal-RN (Brazil); Mello, Vamberto D. [Departamento de Física,Universidade do Estado do Rio Grande do Norte (UERN), Mossoró-RN (Brazil); Vasconcelos, Manoel S. [Escola de Ciência e Tecnologia (ECT), Universidade Federal do Rio Grande do Norte (UFRN), Natal-RN (Brazil)

2014-03-31

Rare-earth (RE) metals have different magnetic structures resulting from the competition between the crystal-field and exchange interactions. When a magnetic field is applied it creates a third interaction and the magnetic structures are more complicated. In thin films, it is expected that even the magnetic arrangement itself can be strongly modified. Rare-earth helimagnets such as Terbium (Tb), Holmium (Ho) and Dysprosium (Dy) represent the best candidates to evidence such finite-size effects. This finite-size effect is caused by the reduced number of atoms in the direction perpendicular to the film plane that leads to a decrease of the total magnetic exchange energy. We report this contribution to the investigation of magnetocaloric effect (MCE) of thin Terbium films in the helimagnetic temperature range, from T{sub C} = 219 K to T{sub N} = 231 K, for external fields of the order of 1 kOe. We find that for strong fields, H = 50 kOe, the adiabatic temperature change ΔT near the Néel temperature is around 15 K for any thickness of Tb films. However large thickness effects are found for small values of the magnetic field. For field strength of the order of a few kOe, the thermocaloric efficiency increases significantly for ultrathin (nanomagnetic) films.

Magnetocaloric effect and refrigeration cooling power in amorphous Gd7Ru3 alloys

OpenAIRE

Pramod Kumar; Rachana Kumar

2015-01-01

In this paper, we report the magnetic, heat capacity and magneto-caloric effect (MCE) of amorphous Gd7Ru3 compound. Both, temperature dependent magnetization and heat capacity data reveals that two transitions at 58 K and 34 K. MCE has been calculated in terms of isothermal entropy change (ΔSM) and adiabatic temperature change (ΔTad) using the heat capacity data in different fields. The maximum values of ΔSM and ΔTad are 21 Jmol−1K−1 and 5 K respectively, for field change of 50 kOe whereas re...

The physical mechanism of magnetic field controlled magnetocaloric effect and magnetoresistance in bulk PrGa compound

Science.gov (United States)

Zheng, X. Q.; Wu, H.; Chen, J.; Zhang, B.; Li, Y. Q.; Hu, F. X.; Sun, J. R.; Huang, Q. Z.; Shen, B. G.

2015-01-01

The PrGa compound shows excellent performance on the magnetocaloric effect (MCE) and magnetoresistance (MR). The physical mechanism of MCE and MR in PrGa compound was investigated and elaborated in detail on the basis of magnetic measurement, heat capacity measurement and neutron powder diffraction (NPD) experiment. New types of magnetic structure and magnetic transition are found. The results of the NPD along with the saturation magnetic moment (MS) and magnetic entropy (SM) indicate that the magnetic moments are randomly distributed within the equivalent conical surface in the ferromagnetic (FM) temperature range. PrGa compound undergoes an FM to FM transition and an FM to paramagnetic (PM) transition as temperature increases. The magnetizing process was discussed in detail and the physical mechanism of the magnetic field controlled magnetocaloric effect (MCE) and the magnetoresistance (MR) was studied. The formation of the plateau on MCE curve was explained and MR was calculated in detail on the basis of the magnetic structure and the analysis of the magnetizing process. The experimental results are in excellent agreement with the calculations. Finally, the expression of MR = β(T)X2 and its application conditions were discussed, where X is M(H)/Meff, and Meff is the paramagnetic effective moment. PMID:26455711

The influence of non-magnetocaloric properties on the AMR performance

DEFF Research Database (Denmark)

Nielsen, Kaspar Kirstein; Bahl, Christian; Smith, Anders

2012-01-01

The performance of Active Magnetic Regenerators (AMR) does not depend solely on the magnetocaloric effect of their constituents. Rather, it depends on several additional parameters, including, magnetic field, geometry (hydraulic diameter, cross-sectional area, regenerator length etc.), thermal pr...... a strong dependence on the orientation of the applied field and the regenerator geometry. Finally, the flow maldistribution of non-uniform regenerator geometries is found to degrade the AMR performance even at minor deviations from perfectly homogeneous regenerator matrices.......The performance of Active Magnetic Regenerators (AMR) does not depend solely on the magnetocaloric effect of their constituents. Rather, it depends on several additional parameters, including, magnetic field, geometry (hydraulic diameter, cross-sectional area, regenerator length etc.), thermal...... properties (conductivity, specific heat and mass density) and operating parameters (utilization, frequency, number of transfer units etc.). In this paper we focus on the influence of three parameters on regenerator performance: 1) Solid thermal conductivity, 2) magnetostatic demagnetization and 3) flow...

Investigate the effect of anisotropic order parameter on the specific heat of anisotropic two-band superconductors

International Nuclear Information System (INIS)

Udomsamuthirun, P.; Peamsuwan, R.; Kumvongsa, C.

2009-01-01

The effect of anisotropic order parameter on the specific heat of anisotropic two-band superconductors in BCS weak-coupling limit is investigated. An analytical specific heat jump and the numerical specific heat are shown by using anisotropic order parameters, and the electron-phonon interaction and non-electron-phonon interaction. The two models of anisotropic order parameters are used for numerical calculation that we find little effect on the numerical results. The specific heat jump of MgB 2 , Lu 2 Fe 3 Si 5 and Nb 3 Sn superconductors can fit well with both of them. By comparing the experimental data with overall range of temperature, the best fit is Nb 3 Sn, MgB 2 , and Lu 2 Fe 3 Si 5 superconductors.

Magnetocaloric effect and critical behavior in melt-extracted Gd{sub 60}Co{sub 15}Al{sub 25} microwires

Energy Technology Data Exchange (ETDEWEB)

Xing, Dawei; Jiang, Sida; Chen, Dongming; Liu, Yanfen; Sun, Jianfei [School of Materials Science and Engineering, Harbin Institute of Technology (China); Shen, Hongxian [School of Materials Science and Engineering, Harbin Institute of Technology (China); Institute of Materials and Department of Physics, University of South Florida, Tampa, FL (United States); Liu, Jingshun [School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot (China); Phan, Manh-Huong [Institute of Materials and Department of Physics, University of South Florida, Tampa, FL (United States); Wang, Huan; Qin, Faxiang [Institute for Composites Science and Innovation (InCSI), College of Materials Science and Engineering, Zhejiang University, Hangzhou (China)

2015-09-15

High-quality Gd{sub 60}Co{sub 15}Al{sub 25} microwires with an average diameter of 40 μm were successfully fabricated by the melt-extraction method. The as-cast microwires undergo a second-order paramagnetic to ferromagnetic (PM-FM) transition at ∝100 K. Large values of the magnetic entropy change (-ΔS{sub M} ∝9.73 J kg{sup -1} K{sup -1}) and the refrigerant capacity (RC ∝732 J kg{sup -1}) are achieved for a field change of 5 T. A careful analysis of critical exponents near the PM-FM transition indicates the significant effects of structural disorder on the long-range ferromagnetic interaction and the magnetocaloric response of the microwires. The excellent magnetocaloric properties make the Gd{sub 60}Co{sub 15}Al{sub 25} microwires very promising for use in magnetic refrigerators operating in the liquid nitrogen temperature range. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Ageing effect on the magnetocaloric properties of Gd, Gd5Si1.9Ge2.1 and on the eutectic composition Gd75Cd25

International Nuclear Information System (INIS)

Canepa, F; Cirafici, S; Napoletano, M; Cimberle, M R; Tagliafico, L; Scarpa, F

2008-01-01

The ageing effects due to the interaction with typical working fluids (water and air) of magnetic refrigerant materials have been analysed for up to one year. Among the many compounds reported to exhibit a sufficiently high magnetocaloric effect, we decided to artificially age Gd, which represents the first choice high magnetocaloric element, Gd 5 Si 1.9 Ge 2.1 , belonging to the series Gd 5 (Si x Ge 4-x ) 4 which for x ∼ 0.5 displays a giant magnetocaloric effect, and finally, the eutectic Gd 75 Cd 25 alloy, presenting an almost constant adiabatic temperature rise in an interesting temperature span (260-280 K). Magnetothermal results give evidence that corrosion and corrosion/erosion processes take place with different results on the refrigerant properties of all the materials. The adiabatic temperature rise is strongly reduced due to surface oxidation which lowers thermal conduction while the effect on the refrigerant capacity Q is definitely smaller. The effects of corrosion/erosion processes are confirmed by quantitative chemical analysis performed on the refrigerant fluid before and after the ageing process. Employing working fluids with a reduced corrosive effect but with comparable thermal properties may be a viable way of avoiding corrosion damage; alternatively the use of additives to decrease the corrosive properties of the fluids is strongly suggested

Magnetic refrigeration at room temperature - from magnetocaloric materials to a prototype

DEFF Research Database (Denmark)

Kuhn, Luise Theil; Pryds, Nini; Bahl, Christian Robert Haffenden

2011-01-01

Based on the magnetocaloric effect, magnetic refrigeration at room temperature has for the past decade been a promising, environmentally friendly new energy technology predicted to have a significantly higher efficiency than the present conventional methods. However, so far only a few prototype...... refrigeration machines have been presented worldwide and there are still many scientific and technological challenges to be overcome. We report here on the MagCool project, which spans all the way from basic materials studies to the construction of a prototype. Emphasis has been on ceramic magnetocaloric...... materials, their shaping and graded composition for technological use. Modelling the performance of a permanent magnet with optimum use of the flux and relatively low weight, and designing and constructing a prototype continuous magnetic refrigeration device have also been major tasks in the project...

Magnetic refrigeration at room temperature - from magnetocaloric materials to a prototype

International Nuclear Information System (INIS)

Kuhn, L Theil; Pryds, N; Bahl, C R H; Smith, A

2011-01-01

Based on the magnetocaloric effect, magnetic refrigeration at room temperature has for the past decade been a promising, environmentally friendly new energy technology predicted to have a significantly higher efficiency than the present conventional methods. However, so far only a few prototype refrigeration machines have been presented worldwide and there are still many scientific and technological challenges to be overcome. We report here on the MagCool project, which spans all the way from basic materials studies to the construction of a prototype. Emphasis has been on ceramic magnetocaloric materials, their shaping and graded composition for technological use. Modelling the performance of a permanent magnet with optimum use of the flux and relatively low weight, and designing and constructing a prototype continuous magnetic refrigeration device have also been major tasks in the project.

Numerical analysis of a magnetocaloric heat pump implementation into a residential building

DEFF Research Database (Denmark)

Johra, Hicham

of the magneto-caloric heat pump in a single hydronic loop coupling directly the heat source and the heat sink without additional heat exchangers. Moreover, several parameters can be controlled in order to perform efficient part load power generation. The objective of this work is to understand how to integrate...... a magneto-caloric heat pump into a residential building and establish a control strategy for such device. A numerical model of a single family house with water based under-floor heating and horizontal ground source heat exchanger is created. It is used to demonstrate the feasibility and the advantages...... of the integrated magneto-caloric heat pump system is compared with conventional heat pumps one....

Hydrostatic pressure effect on the magnetocaloric behavior of Ga-doped MnNiGe magnetic equiatomic alloy

International Nuclear Information System (INIS)

Dutta, P; Das, D; Chatterjee, S; Pramanick, S; Majumdar, S

2016-01-01

The magnetocaloric properties of a new class of ferromagnetic shape memory alloys of nominal composition MnNiGe 0.928 Ga 0.072 have been investigated in ambient conditions as well as in the presence of external hydrostatic pressure. Both inverse (6.35 Jkg −1 K −1 for 0  −  50 kOe around 160 K) and conventional (−4.54 Jkg −1 K −1 for 0–50 kOe around 210 K) magnetocaloric effects (MCEs) have been observed around the structural and magnetic transitions respectively. The sample can be thought of as being derived from the parent MnNiGe alloy, where Ga was doped at the expense of the Ge atom. Ga doping at Ge sites brings down the martensitic transition temperature to below room temperature and induces ferromagnetism by affecting the lattice volume of the alloy. However, below the first-order martensitic transition the alloy loses its ferromagnetism. Application of external hydrostatic pressure results in a revival of ferromagnetic interactions in the martensitic phase of the alloy and a considerable increase in the refrigeration capacity around the conventional MCE region. (paper)

Developing a Magnetocaloric Domestic Heat Pump

DEFF Research Database (Denmark)

Bahl, Christian R.H.

2014-01-01

beverage coolers, A/Cs for cars and electronics cooling. Devices for heating have not been extensively demonstrated. Here we consider a promising application of magnetocaloric heat pumps for domestic heating. The task of designing and building such a device is a multidisciplinary one encompassing materials...

A theory for the anisotropic interaction between two substitutional magnetic impurities and the magnetic anisotropic effect in dilute magnetic alloys

International Nuclear Information System (INIS)

Satter, M.A.

1990-08-01

In this paper, a formalism for studying the anisotropic interaction between two substitutional magnetic impurities and the magnetic anisotropic effect in a dilute noble metal- transition metal magnetic alloy has been developed from relativistic scattering theory. The theoretical development and the computational techniques of this formalism are based on relativistic spin-polarized scattering theory and relativistic band structure frameworks. For studying the magnetic anisotropic effect a convenient ''working'' frame of reference with its axes oriented along the fcc crystal axes is set up. This formalism is applied to study the situation for two Fe impurities in paramagnetic Au hosts. For AuFe dilute alloy, the two impurity site interaction as a function of separation is not oscillatory and the anisotropic effect is found to be less than the two site interaction itself only by an order of magnitude. Apart from the anisotropic coupling of the two impurity spins to the separation vector, for the first time, another weak anisotropic coupling to the crystal axes is also contained in the two site interaction. These anisotropic effects are the results of the relativistic spin-orbit interaction which are incorporated into the formalism. (author). 22 refs, 5 figs

A study of the phase transition and magnetocaloric effect in multiferroic La{sub 2}MnNiO{sub 6} single crystals

Energy Technology Data Exchange (ETDEWEB)

Balli, M., E-mail: mohamed.balli@usherbrooke.ca; Jandl, S. [Regroupement québécois sur les matériaux de pointe, Département de physique, Université de Sherbrooke, Quebec J1K 2R1 (Canada); Fournier, P. [Regroupement québécois sur les matériaux de pointe, Département de physique, Université de Sherbrooke, Quebec J1K 2R1 (Canada); Canadian Institute for Advanced Research, Toronto, Ontario M5G 1Z8 (Canada); Gospodinov, M. M. [Institute of Solid State Physics, Bulgarian Academy of Science, Sofia 1184 (Bulgaria)

2014-05-07

Magnetic and magnetocaloric properties of single crystal double perovskite La{sub 2}MnNiO{sub 6} have been investigated in details. Its ordered phase with a high Curie temperature (T{sub C} = 280 K) exhibits a significant refrigerant capacity around room temperature. A model based on the mean field theory approximation has been used in order to quantify the magnetic and magnetocaloric properties in the ordered La{sub 2}MnNiO{sub 6}. The magnetization and entropy changes were satisfactorily simulated as a function of temperature and magnetic field. On the other hand, the presence of cationic disorder in La{sub 2}MnNiO{sub 6} phases allows to shift the Curie point to low temperature without a significant change in the magnetocaloric performance.

Magnetocaloric piezoelectric composites for energy harvesting

International Nuclear Information System (INIS)

Cleveland, Michael; Liang, Hong

2012-01-01

Magnetocaloric alloy, Gd 5 Si 2 Ge 2 , was developed into a composite with the poly(vinylidene fluoride) (PVDF) piezoelectric polymer. This multifunctional material possesses unique properties that are suitable for energy conversion and harvesting. Experimental approaches include using an arc melting technique to synthesize the Gd 5 Si 2 Ge 2 (GSG) alloy and the spinning casting method to fabricate the composite. The materials were characterized using various techniques at different length scales. These include atomic force microscopy (AFM), optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), x-ray diffraction (XRD), and x-ray photoelectron spectroscopy (XPS). The results indicated that the phase transformation of the magnetocaloric material close to its Curie temperature induced a significant increase in power generation in the piezoelectric polymer. The power output of a laminated structure was 1.1 mW, more than 200 thousand times higher than the piezoelectric materials alone (5.1 nW). (technical note)

Near room temperature magnetocaloric properties and the universal curve of MnCoGe1-xCux

Science.gov (United States)

Si, Xiaodong; Liu, Yongsheng; Lu, Xiaofei; Shen, Yulong; Wang, Wenli; Yu, Wenying; Zhou, Tao; Gao, Tian

2017-05-01

Intermetallic compounds based on MnCoGe have drawn attention due to the coupled magnetic and structural transformations and the large magnetocaloric entropy. Here, we provide a systematic comparison of experimental data under different magnetic fields with magnetic and the magnetocaloric properties. The ferromagnetic transition temperature (TC) increases from 353.4(6) K for x = 0.01 to 363.4(4) K for x = 0.04 with increasing nominal copper content. The maximum magnetic entropy change |ΔSM| in a magnetic field change of 5 T is found to be 18.3(2) J/(kg K) with a large relative cooling power (RCP) value of 292.5(4) J/kg for x = 0.01, revealing that the present system can provide an acceptable magnetocaloric effect at a cheaper price for magnetic refrigeration materials. Making attempt to contrast a master curve for the present system, we find the experimental values of magnetic field dependence of the magnetic entropy change are consistent with a phenomenological universal curve.

Direct and indirect measurement of the magnetocaloric effect in a La0.6Ca0.4MnO3 ceramic perovskite

DEFF Research Database (Denmark)

Dinesen, A.R.; Linderoth, Søren; Mørup, Steen

2002-01-01

The adiabatic temperature change DeltaT(ad) due to a change of the external magnetic field (the magnetocaloric effect) for a perovskite-type La0.6Ca0.4MnO3 sample has been measured directly and indirectly (from the entropy change) and the results are compared. From the indirect method, involving...

The correlation of the magnetic properties and the magnetocaloric effect in (Gd1-xErx)NiAl alloys

International Nuclear Information System (INIS)

Korte, B.J.; Pecharsky, V.K.; Gschneidner, K.A. Jr.

1998-01-01

A study of the magnetic properties of several (Gd 1-x Er x )NiAl alloys (where x=0, 0.30, 0.40, 0.46, 0.50, 0.55, 0.60, 0.80, and 1.00) was undertaken using both ac and dc magnetic and heat capacity measurements in an attempt to understand the table-like magnetocaloric effect previously observed in (Gd 0.54 Er 0.46 )NiAl. Results indicate the presence of both antiferromagnetic and ferromagnetic ordering processes in all alloys containing Gd. For ErNiAl, a metamagnetic transition from an antiferromagnetic ground state was observed. Within each alloy, several magnetic transitions occur over a temperature range from 10 K [in (Gd 0.20 Er 0.80 )NiAl] up to 35 K (in GdNiAl), with all but the lowest temperature transition shifting to higher temperatures with increasing Gd content. The change in magnetic entropy (ΔS mag ) induced by a change in field is observed to peak around the Nacute eel temperature for ErNiAl while gradually broadening and shifting toward the Curie temperature as the Gd content is increased. For Gd-rich alloys, a significant contribution to ΔS mag is observed at both the low and high temperature transitions, resulting in a rounded, skewed caret-like temperature profile of the magnetocaloric effect. Factors, which are believed to contribute to this effect, include the presence and temperature spacing of multiple zero-field transitions, which most likely result from competing anisotropy and exchange interactions within a frustrated hexagonal spin lattice. This leads to broad peaks in the magnetic heat capacity that span several transition temperatures, providing for a substantial ΔS mag over an extended temperature range. This characteristic is desired for application to magnetic refrigeration, where certain thermodynamic cycles (e.g., Ericsson cycle) require specific temperature profiles of the magnetocaloric effect in refrigerant materials (e.g., a constant change in magnetic entropy as a function of temperature within the region of cooling). In

The effect of adding aluminum and iron to Tb–Dy–Ho–Co multicomponent alloys on their structure and magnetic and magnetocaloric properties

Czech Academy of Sciences Publication Activity Database

Politova, G.A.; Burkhanov, G.S.; Tereshina, I. S.; Kaminskaya, T.; Chzhan, V.B.; Tereshina, Evgeniya

2017-01-01

Roč. 62, č. 4 (2017), s. 577-582 ISSN 1063-7842 Institutional support: RVO:68378271 Keywords : multicomponent alloys * Laves phase compounds * magnetocaloric effect Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 0.632, year: 2016

Glass formation, magnetic properties and magnetocaloric effect of ternary Ho–Al–Co bulk metallic glass

International Nuclear Information System (INIS)

Zhang, Huiyan; Li, Ran; Ji, Yunfei; Liu, Fanmao; Luo, Qiang; Zhang, Tao

2012-01-01

A ternary Ho–Al–Co system with high glass-forming ability (GFA) was developed and fully glassy rods with diameters up to 1 cm can be produced for the best glass former of Ho 55 Al 27.5 Co 17.5 alloy. The thermal stability and low-temperature magnetic properties of the Ho 55 Al 27.5 Co 17.5 bulk metallic glass (BMG) were studied. The magnetic transition temperature of this alloy is ∼14 K as determined by the thermomagnetic measurement. Two indicators, i.e. isothermal magnetic entropy change (ΔS M ) and the relative cooling power (RCP), were adopted to evaluate the magnetocaloric effect (MCE) of the alloy under a low magnetic field up to 2 T, which can be generated by permanent magnets. The values of |ΔS M | and RCP are 7.98 J kg −1 K −1 and 191.5 J kg −1 , respectively. The Ho 55 Al 27.5 Co 17.5 BMG with good MCE and high GFA provides an attractive candidate for magnetic refrigeration applications, like hydrogen liquefaction and storage. - Highlights: ► A ternary Ho–Al–Co BMG system with high glass-forming ability was developed. ► Fully glassy rods of Ho 55 Al 27.5 Co 17.5 alloy were produced up to 1 cm in diameter. ► The thermal stability and magnetic properties of the BMG were evaluated. ► The BMG exhibits good magnetocaloric effect under a low magnetic field up to 2 T.

Effect of vanadium doping on structural, magnetic and magnetocaloric properties of La{sub 0.5}Ca{sub 0.5}MnO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Mansouri, M., E-mail: mansourimoufida23@yahoo.fr [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Sfax University, B.P. 1171, 3000 Sfax (Tunisia); Omrani, H. [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Sfax University, B.P. 1171, 3000 Sfax (Tunisia); Cheikhrouhou-Koubaa, W. [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Sfax University, B.P. 1171, 3000 Sfax (Tunisia); Centre de Recherche en Informatique, Multimédia et Traitement Numérique des Données, BP 275, Sakiet Ezzit, 3021 Sfax (Tunisia); Koubaa, M. [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Sfax University, B.P. 1171, 3000 Sfax (Tunisia); Madouri, A. [Laboratoire de Photonique et Nanostructure, LPN-CNRS, Route de Nozay, 91460 Marcoussis (France); Cheikhrouhou, A. [Laboratoire de Physique des Matériaux, Faculté des Sciences de Sfax, Sfax University, B.P. 1171, 3000 Sfax (Tunisia)

2016-03-01

We report the effect of vanadium doping on structural, magnetic and magnetocaloric properties of La{sub 0.5}Ca{sub 0.5}Mn{sub 1−x}V{sub x}O{sub 3} (x=0.05; 0.1). Our samples were elaborated using the conventional solid state reaction method at high temperatures. X-Ray powder diffraction at room temperature indicates that our samples crystallize in the orthorhombic structure with Pbnm space group. Magnetic measurements reveal a paramagnetic-ferromagnetic transition with decreasing temperature. Magnetocaloric studies show that the maximum of the magnetic entropy change and the relative cooling power (RCP) are found to be 2.42 J Kg{sup −1} K{sup −1} and 162.75 J Kg{sup −1} for x=0.05 and 3.12 J Kg{sup −1} K{sup −1} and 221.31 J Kg{sup −1} for x=0.1 under a field change of 5 T. - Highlights: • The La{sub 0.5}Ca{sub 0.5}Mn{sub 1−x}V{sub x}O{sub 3}(x=0.05 and x=0.1) compounds were synthesized using conventional solid state reaction method. • T{sub C} increases with V content from 187 K for x=0.05 to 263 K for x=0.1 • Large magnetocaloric effect is reported based on second order phase transition. • Noticeable |∆S{sub M}| at 5 T field makes the system useful for magnetic refrigeration.

Magnetocaloric effects in MnFeP1-x As x -based compounds

International Nuclear Information System (INIS)

Brueck, E.; Ilyn, M.; Tishin, A.M.; Tegus, O.

2005-01-01

Here we present the results of an investigation of some magnetic and thermal properties of the compounds MnFeP 0.45 As 0.55 , MnFeP 0.47 As 0.53 , and Mn 1.1 Fe 0.9 P 0.47 As 0.53 which can be regarded as possible magnetic refrigerants for room temperature applications. Magnetization measurements are performed in the temperature range 250-330 K, in magnetic fields up to 5 T. The coexistence of the magnetic and structural first-order phase transitions is revealed in all three samples, suggesting its key role in the large values observed for the magnetocaloric effect. The adiabatic temperature change measured directly was up to 4.0, 3.4, and 4.2 K for a magnetic field change of 1.45 T

Operational test of bonded magnetocaloric plates

DEFF Research Database (Denmark)

Bahl, Christian; Navickaité, Kristina; Neves Bez, Henrique

2017-01-01

Bonded plates made by hot pressing La0.85Ce0.15Fe11.25Mn0.25Si1.5Hy particles and resin have been tested as active magnetic regenerators in a small scale magnetocaloric device. Firstly the plates were carefully characterised magnetically and thermally. The plates were prepared with 5 wt% resin...

Direct measurement of the magnetocaloric effect in Tb5Si2Ge2

International Nuclear Information System (INIS)

Tocado, L.; Palacios, E.; Burriel, R.

2005-01-01

A method for measuring the adiabatic temperature change ΔT S upon quasi-static application of an external magnetic field H is proposed. ΔT S is directly measured with an accuracy better than 0.01K. Results of experiments on the giant magnetocaloric compound Tb 5 Si 2 Ge 2 are compared with those obtained from magnetization and heat capacity in an applied field

Magnetic structure and phase formation of magnetocaloric Mn-Fe-P-X compounds

NARCIS (Netherlands)

Ou, Z.Q.

2013-01-01

This thesis presents a study of the crystal and magnetic structure, the magnetocaloric effect and related physical properties in Mn-Fe-P-X compounds. The influences of boron addition in (Mn,Fe)2(P,As) compounds have been studied. It is found that boron atoms occupy interstitial sites within the

High performance magnetocaloric perovskites for magnetic refrigeration

DEFF Research Database (Denmark)

Bahl, Christian R. H.; Velazquez, David; Nielsen, Kaspar K.

2012-01-01

We have applied mixed valance manganite perovskites as magnetocaloric materials in a magnetic refrigeration device. Relying on exact control of the composition and a technique to process the materials into single adjoined pieces, we have observed temperature spans above 9 K with two materials...

Effective medium theory for anisotropic metamaterials

KAUST Repository

Zhang, Xiujuan; Wu, Ying

2015-01-01

-dimensional metamaterial composed of a rectangular array of elliptic cylinders and derive an effective medium theory for such a metamaterial. We find that it is possible to obtain a closed-form analytical solution for the anisotropic effective medium parameters, provided

Magnetocaloric effect in La(FexSi1-x)13 doped with hydrogen and under external pressure

International Nuclear Information System (INIS)

Medeiros, L.G. de; Oliveira, N.A. de

2006-01-01

In this paper, we calculate the magnetocaloric effect in the compounds La(Fe x Si 1-x ) 13 doped with hydrogen and subjected to external pressure. We use a microscopical model where the Coulomb interaction between itinerant electrons is treated in the mean field approach. The effect of hydrogen atoms is considered as a chemical pressure. We also include phenomenologically the magnetoelastic coupling via the renormalization of the electron dispersion relation and the Debye temperature. The calculated isothermal entropy changes upon magnetic field variations for the compound La(Fe 0.88 Si 0.12 ) 13 H y are in good agreement with the available experimental data

Magneto-caloric and magneto-resistive properties of La0.67Ca0.33-xSrxMnO3

International Nuclear Information System (INIS)

Reves Dinesen, Anders

2004-08-01

This thesis presents results of an experimental investigation of magneto-caloric and magneto-resistive properties of a series of polycrystalline Ca- and Sr-doped lanthanum manganites, La 0.67 Ca 0.33-x Sr x MnO 3 (0≤ x ≤ 0.33), with the perovskite structure. The samples consisted of sintered oxide powders prepared the glycine-nitrate combustion technique. The compounds were ferromagnetic and showed a Curie transition in the temperature range 267370 K (T C increased with increasing x). An analysis of the structural properties was carried out by means of x-ray diffraction and the Rietveld technique. The variation of the Ca/Sr ratio was found to cause a transition from orthorhombic to rhombohedral symmetry in the composition range 0.110 0.67 Ca 0.33-x Sr x MnO 3 samples was measured directly and indirectly (by means of magnetization measurements). All the samples showed a magnetocaloric effect in the vicinity of T C . A model for the mag-netocaloric effect based on Weiss mean field theory and classical theories for heat capacities was developed. The model provided reasonable predictions of the magneto-caloric properties of the samples. The compounds with low Sr content showed a magnetocaloric effect comparable to that of Gadolinium, the prototypical working material for magnetic refrigeration at room temperature. A less comprehensive part of the investigation regarded the magneto-resistive properties of the La 0.67 Ca 0.33-x Sr x MnO 3 system. It was found that th polycrystalline nature of the compounds played a decisive role for the magnetotransport properties. Characteristic grain boundary effects, such as a low-field magnetoresistance, which is absent in single-crystalline perovskites, were observed. The low-field effect is usually ascribed to spin-dependent scattering in grain boundaries. Qualitatively the results obtained for the La 0.67 Ca 0.33-x Sr x MnO 3 samples were consistent with this model. The resistivity contribution arising from the presence of

Giant magnetocaloric effect, magnetization plateaux and jumps of the regular Ising polyhedra

International Nuclear Information System (INIS)

Strečka, Jozef; Karľová, Katarína; Madaras, Tomáš

2015-01-01

Magnetization process and adiabatic demagnetization of the antiferromagnetic Ising spin clusters with the shape of regular polyhedra (Platonic solids) are exactly examined within the framework of a simple graph-theoretical approach. While the Ising cube as the only unfrustrated (bipartite) spin cluster shows just one trivial plateau at zero magnetization, the other regular Ising polyhedra (tetrahedron, octahedron, icosahedron and dodecahedron) additionally display either one or two intermediate plateaux at fractional values of the saturation magnetization. The nature of highly degenerate ground states emergent at intermediate plateaux owing to a geometric frustration is clarified. It is evidenced that the regular Ising polyhedra exhibit a giant magnetocaloric effect in a vicinity of magnetization jumps, whereas the Ising octahedron and dodecahedron belong to the most prominent geometrically frustrated spin clusters that enable an efficient low-temperature refrigeration by the process of adiabatic demagnetization

Magnetocaloric effect of Er.sub.5./sub.Si.sub.4./sub. under hydrostatic pressure

Czech Academy of Sciences Publication Activity Database

Arnold, Zdeněk; Magen, C.; Morellon, L.; Algarabel, P.A.; Kamarád, Jiří; Ibarra, M. R.; Pecharsky, V. K.; Gschneidner, Jr., K. A.

2009-01-01

Roč. 79, č. 14 (2009), 144430/1-144430/6 ISSN 1098-0121 R&D Projects: GA ČR GA202/09/0030 Institutional research plan: CEZ:AV0Z10100521 Keywords : Curie temperature * entropy * erbium compounds * ferromagnetic materials * high-pressure solid-state phase transformations * magnetisation * magnetocaloric Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.475, year: 2009

Developments in magnetocaloric refrigeration

International Nuclear Information System (INIS)

Brueck, Ekkes

2005-01-01

Modern society relies on readily available refrigeration. Magnetic refrigeration has three prominent advantages compared with compressor-based refrigeration. First, there are no harmful gases involved; second, it may be built more compactly as the working material is a solid; and third, magnetic refrigerators generate much less noise. Recently a new class of magnetic refrigerant-materials for room-temperature applications was discovered. These new materials have important advantages over existing magnetic coolants: they exhibit a large magnetocaloric effect (MCE) in conjunction with a magnetic phase-transition of first order. This MCE is larger than that of Gd metal, which is used in the demonstration refrigerators built to explore the potential of this evolving technology. In the present review we compare the different materials considering both scientific aspects and industrial applicability. Because fundamental aspects of MCE are not so widely discussed, we also give some theoretical considerations. (topical review)

Room temperature magnetocaloric effect in Ni-Mn-In-Cr ferromagnetic shape memory alloy thin films

Energy Technology Data Exchange (ETDEWEB)

Akkera, Harish Sharma [Functionalnanomaterials Research Lab, Department of Physics, Indian Institute of Technology Roorkee, Uttarakhand-247667 (India); Singh, Inderdeep [Mechanical and Industrial Engineering Department, Indian Institute of Technology Roorkee, Uttarakhand-24667 (India); Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functionalnanomaterials Research Lab, Department of Physics, Indian Institute of Technology Roorkee, Uttarakhand-247667 (India)

2017-02-15

The influence of Cr substitution for In on the martensitic phase transformation and magnetocaloric effect (MCE) has been investigated in Ni-Mn-Cr-In ferromagnetic shape memory alloy (FSMA) thin films fabricated by magnetron sputtering. Temperature dependent magnetization (M-T) measurements demonstrated that the martensitic transformation temperatures (T{sub M}) monotonously increase with the increase of Cr content due to change in valence electron concentration (e/a) and cell volume. From the study of isothermal magnetization curves (M-H), magnetocaloric effect around the martensitic transformation has been investigated in these FSMA thin films. The magnetic entropy change ∆S{sub M} of 7.0 mJ/cm{sup 3}-K was observed in Ni{sub 51.1}Mn{sub 34.9}In{sub 9.5}Cr{sub 4.5} film at 302 K in an applied field of 2 T. Further, the refrigerant capacity (RC) was also calculated for all the films in an applied field of 2 T. These findings indicate that the Cr doped Ni-Mn-In FSMA thin films are potential candidates for room temperature micro-length-scale magnetic refrigeration applications. - Highlights: • The Cr content leads to an increase in the martensitic transformation temperature. • The ∆S{sub M} =7 mJ/cm{sup 3}-K at 302 K was observed in the Ni{sub 51.1}Mn{sub 34.9}In{sub 9.5}Cr{sub 4.5}. • The RC =39.2 mJ/K at 2 T was obtained in Ni{sub 51.1}Mn{sub 34.9}In{sub 9.5}Cr{sub 4.5} film.

Table-like magnetocaloric effect in Gd–Ni–Al amorphous/nanocrystalline composites

International Nuclear Information System (INIS)

Zheng, Qiang; Zhang, Linlin; Du, Juan

2017-01-01

In this work, Gd–Ni–Al amorphous/nanocrystalline composites produced by melt-spinning method with double magnetocaloric effect (MCE) plateaus have been developed. Two MCE plateaus, ∼4.7 J kg −1 K −1 (90–120 K) and ∼3.60 J kg −1 K −1 (250–275 K), were discovered in Gd 80 Ni 11.6 Al 8.4 for a magnetic field change of 0 to 5 T. For Gd 90 Ni 5.8 Al 4.2 , the plateau values are ∼3.90 J kg −1 K −1 (85–120 K) and ∼6.70 J kg −1 K −1 (265–280 K) for a magnetic field change of 0–5 T. The reason why MCE plateau formation was investigated and discussed. These composites having two MCE plateaus are competitive candidates for the ideal Ericsson cycle. (paper)

Anisotropic magnetoresistance and piezoelectric effect in GaAs Hall samples

Science.gov (United States)

Ciftja, Orion

2017-02-01

Application of a strong magnetic field perpendicular to a two-dimensional electron system leads to a variety of quantum phases ranging from incompressible quantum Hall liquid to Wigner solid, charge density wave, and exotic non-Abelian states. A few quantum phases seen in past experiments on GaAs Hall samples of electrons show pronounced anisotropic magnetoresistance values at certain weak magnetic fields. We argue that this might be due to the piezoelectric effect that is inherent in a semiconductor host such as GaAs. Such an effect has the potential to create a sufficient in-plane internal strain that will be felt by electrons and will determine the direction of high and low resistance. When Wigner solid, charge density wave, and isotropic liquid phases are very close in energy, the overall stability of the system is very sensitive to local order and, thus, can be strongly influenced even by a weak perturbation such as the piezoelectric-induced effective electron-electron interaction, which is anisotropic. In this work, we argue that an anisotropic interaction potential may stabilize anisotropic liquid phases of electrons even in a strong magnetic field regime where normally one expects to see only isotropic quantum Hall or isotropic Fermi liquid states. We use this approach to support a theoretical framework that envisions the possibility of an anisotropic liquid crystalline state of electrons in the lowest Landau level. In particular, we argue that an anisotropic liquid state of electrons may stabilize in the lowest Landau level close to the liquid-solid transition region at filling factor ν =1 /6 for a given anisotropic Coulomb interaction potential. Quantum Monte Carlo simulations for a liquid crystalline state with broken rotational symmetry indicate stability of liquid crystalline order consistent with the existence of an anisotropic liquid state of electrons stabilized by anisotropy at filling factor ν =1 /6 of the lowest Landau level.

New type of magnetocaloric effect: Implications on low-temperature magnetic refrigeration using an Ericsson cycle

International Nuclear Information System (INIS)

Takeya, H.; Pecharsky, V.K.; Gschneidner, K.A. Jr.; Moorman, J.O.

1994-01-01

The low-temperature, high magnetic field heat capacity (1.5 to 70 K and 0 to 9.85 T), dc and ac magnetic behaviors of the compound (Gd 0.54 Er 0.46 )AlNi show that field-induced magnetic entropy change is significant and almost constant over the temperature region of ∼15 to ∼45 K. The resulting temperature dependence of the magnetocaloric effect, nearly constant over a 30+ K temperature range, is unprecedented (most magnetic materials have a caretlike shape temperature dependence). These data show that (Gd 0.54 Er 0.46 )AlNi can be used as an effective active magnetic regenerator material for an Ericsson-cycle magnetic refrigerator, and could substitute for complex composite layered materials suggested earlier

Effective material parameter retrieval of anisotropic elastic metamaterials with inherent nonlocality

Science.gov (United States)

Lee, Hyung Jin; Lee, Heung Son; Ma, Pyung Sik; Kim, Yoon Young

2016-09-01

In this paper, the scattering (S-) parameter retrieval method is presented specifically for anisotropic elastic metamaterials; so far, no retrieval has been accomplished when elastic metamaterials exhibit fully anisotropic behavior. Complex constitutive property and intrinsic scattering behavior of elastic metamaterials make their characterization far more complicated than that for acoustic and electromagnetic metamaterials. In particular, elastic metamaterials generally exhibit anisotropic scattering behavior due to higher scattering modes associated with shear deformation. They also exhibit nonlocal responses to some degrees, which originate from strong multiple scattering interactions even in the long wavelength limit. Accordingly, the conventional S-parameter retrieval methods cannot be directly used for elastic metamaterials, because they determine only the diagonal components in effective tensor property. Also, the conventional methods simply use the analytic inversion formulae for the material characterization so that inherent nonlocality cannot be taken into account. To establish a retrieval method applicable to anisotropic elastic metamaterials, we propose an alternative S-parameter method to deal with full anisotropy of elastic metamaterials. To retrieve the whole effective anisotropic parameter, we utilize not only normal but also oblique wave incidences. For the retrieval, we first retrieve the ratio of the effective stiffness tensor to effective density and then determine the effective density. The proposed retrieval method is validated by characterizing the effective material parameters of various types of non-resonant anisotropic metamaterials. It is found that the whole effective parameters are retrieved consistently regardless of used retrieval conditions in spite of inherent nonlocality.

Tuning of magnetocaloric effect in a La.sub.0.69./sub.Ca.sub.0.31./sub.MnO.sub.3./sub. single crystal by pressure,

Czech Academy of Sciences Publication Activity Database

Sun, Y.; Kamarád, Jiří; Arnold, Zdeněk; Kou, Z.; Cheng, Z.

2006-01-01

Roč. 88, č. 10 (2006), 102505/1-102505/3 ISSN 0003-6951 R&D Projects: GA ČR(CZ) GA106/06/0368 Institutional research plan: CEZ:AV0Z10100521 Keywords : magnetocaloric effect * pressure effect * manganites * single crystal Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.977, year: 2006

Debonding analyses in anisotropic materials with strain- gradient effects

DEFF Research Database (Denmark)

Legarth, Brian Nyvang

2012-01-01

A unit cell approach is adopted to numerically analyze the effect of plastic anisotropy on damage evolution in a micro-reinforced composite. The matrix material exhibit size effects and a visco-plastic anisotropic strain gradient plasticity model accounting for such size effects is adopted....... A conventional cohesive law is extended such that both the average as well as the jump in plastic strain across the fiber-matrix interface are accounted for. Results are shown for both conventional isotropic and anisotropic materials as well as for higher order isotropic and anisotropic materials...... with and without debonding. Generally, the strain gradient enhanced material exhibits higher load carry capacity compared to the corresponding conventional material. A sudden stress drop occurs in the macroscopic stress-strain response curve due to fiber-matrix debonding and the results show that a change in yield...

Giant magnetocaloric effect in antiferromagnetic DyVO{sub 4} compound

Energy Technology Data Exchange (ETDEWEB)

Midya, A., E-mail: arindam.midya@saha.ac.in; Khan, N.; Bhoi, D.; Mandal, P.

2014-09-01

We have investigated the magnetic and magnetocaloric properties of DyVO{sub 4} by magnetization and heat capacity measurements. χ(T) shows antiferromagnetic to paramagnetic transition at T{sub N}{sup Dy}∼3.5K. The compound undergoes a metamagnetic transition and exhibits a huge entropy change. The maximum values of magnetic entropy change (ΔS{sub M}), adiabatic temperature change (ΔT{sub ad}) and refrigerant capacity (RC) reach 26 J kg{sup −1} K{sup −1}, 17 K, and 526 J kg{sup −1}, respectively for a field change of 0–8 T. Moreover, the material is highly insulating and exhibits no thermal and field hysteresis, satisfying the necessary conditions for a good magnetic refrigerant material.

Influence of Si and Ge on the magnetic phase transition and magnetocaloric properties of MnFe(P, Si, Ge)

International Nuclear Information System (INIS)

Cam Thanh, D.T.; Brueck, E.; Tegus, O.; Klaasse, J.C.P.; Buschow, K.H.J.

2007-01-01

Recently, we found a large magnetocaloric effect (MCE) and favourable magnetic properties in low cost and nontoxic MnFe(P, Si, Ge) compounds [D.T. Cam Thanh, E. Brueck, O. Tegus, J.C.P. Klaasse, T.J. Gortenmulder, K.H.J. Buschow, J. Appl. Phys. 99 (2006) 08Q107]. These compounds are promising for magnetic refrigeration applications. One of the interesting points in these compounds is a nonlinear dependence of the Curie temperature (T C ) on Si concentration. This dependence is associated with the change in the lattice parameters a and c, and their ratio c/a. Compounds with larger a parameter and smaller c/a ratio have higher T C . It is clear that Si and Ge atoms play an important role in the magnetic and magnetocaloric properties in the MnFe(P, Si, Ge) compounds. In this paper, we study the effect of Si and Ge on the magnetic phase transition in these materials. Our study shows that the temperature of the phase transition, from paramagnetic to ferromagnetic, can be tuned in the room temperature range without losing giant magnetocaloric properties

Magnetic refrigeration capabilities of magnetocaloric Ni2Mn:75Cu:25Ga

Science.gov (United States)

Mishra, S. K.; Jenkins, C. A.; Dubenko, I.; Samanta, T.; Ali, N.; Roy, S.

2013-03-01

Doping-driven competition between energetically similar ground states leads to many exciting materials phenomena such as the emergence of high-Tc superconductivity, diluted magnetic semiconductors, and colossal magnetoresistance. Doped Ni2MnGa Heusler alloy, which is a multifunctional ferromagnetic alloy with various exotic physical properties demonstrates this notion of rich phenomenology via modified ground spin states. Adopting this generic concept, here we will present a novel doped Ni2Mn.75Cu.25Ga alloy that offers unprecedented co-existence of the magnetocaloric effect and fully controlled ferromagnetism at room temperature. Application of site engineering enables us to manipulate the ground spin state that leads to the decrease in magnetic transition temperature and also increases the delocalization of the Mn magnetism. SQUID magnetometery suggests that Cu doping enhances the saturation magnetization, coercive field and clarity of magnetic hysteresis loops. By exploiting x-ray absorption techniques and measuring element specific magnetic hysteresis loops, here we will describe the microscopic origin of enhnaced magnetocaloric properties and d-d interaction driven charge transfer effects in Ni2Mn.75Cu.25Ga This work was supported by DOE Grant No. DE-FG02-06ER46291

Magnetocaloric properties of manganese(III) porphyrins bearing 2,6-di-tert-butylphenol groups

Energy Technology Data Exchange (ETDEWEB)

Korolev, V.V., E-mail: vvk@isc-ras.ru [G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo 153045 (Russian Federation); Lomova, T.N.; Maslennikova, A.N.; Korolev, D.V. [G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo 153045 (Russian Federation); Shpakovsky, D.B.; Zhang, Jianwei; Milaeva, E.R. [Lomonosov Moscow State University, Department of Medicinal Chemistry and Fine Organic Synthesis, Moscow 119991 (Russian Federation)

2016-03-01

Magnetocaloric effect (MCE) and heat capacity during the magnetization of (5,10,15,20-tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphynato) manganese (III) chloride (1), (5-(4-hydroxyphenyl)-10,15,20-tris(3,5-di-tert-butyl-4-hydroxyphenyl) porphynato) manganese (III) chloride (2), and (5-(4-palmitoyloxyphenyl)-10,15,20-tris(3,5-di-tert-butyl-4-hydroxyphenyl) porphynato) manganese (III) chloride (3) in their aqueous suspensions were determined by the microcalorimetric method over the temperature range of 278–320 K and in magnetic fields from 0 to 1 T. MCE was positive for all complexes studied, i.e. the magnetic field impression under adiabatic conditions led to an increase in temperature of the complexes suspensions. MCE increased with an increase in the magnetic field induction at all temperatures studied. Dependences of MCE on temperature had weak maxima at 298 K at all magnetic induction values. The disturbance of the intermolecular hydrogen-bonding of hydroxyl groups is one of probable reasons for such dependences type. MCE values increased under the palmitoyl substituent incorporation into one of the phenol groups at all temperatures. The heat capacity of the studied complexes rose slightly with temperature growth. Dependences of the heat capacity on temperature showed that the magnetic component of the heat capacity did not appear due to the presence of the manganese atom acting as a paramagnetic center in complexes 1, 2, and 3. The relation between the complexes structure and their magnetothermal properties was analyzed. It was justified that the changes of magnetothermal properties were caused by electronic substitution effects and, to an even greater degree, by the conditions of intermolecular hydrogen bonds formation in the paramagnetic materials. - Highlights: • The magnetocaloric effect and heat capacity of 3 manganese porphyrin were determined. • Temperature dependences of magnetocaloric effect has been studied. • The relation between the

(Dy0.5Er0.5)Al2: A large magnetocaloric effect material for low-temperature magnetic refrigeration

International Nuclear Information System (INIS)

Gschneidner, K.A. Jr.; Takeya, H.; Moorman, J.O.; Pecharsky, V.K.

1994-01-01

The low-temprature heat capacity and ac and dc magnetic properties of (Dy 0.5 Er 0.5 )Al 2 have been studied as a function of magnetic fields up to ∼10 T. The magnetocaloric effect in (Dy 0.5 Er 0.5 )Al 2 is 30% larger than that of the prototype material, GdPd. Magnetic measurements show that there is no measurable magnetic hysteresis above ∼17 K. These results suggest that (Dy 0.5 Er 0.5 )Al 2 would be a significantly better magnetic refrigerant than GdPd

Bryan's effect and anisotropic nonlinear damping

Science.gov (United States)

Joubert, Stephan V.; Shatalov, Michael Y.; Fay, Temple H.; Manzhirov, Alexander V.

2018-03-01

In 1890, G. H. Bryan discovered the following: "The vibration pattern of a revolving cylinder or bell revolves at a rate proportional to the inertial rotation rate of the cylinder or bell." We call this phenomenon Bryan's law or Bryan's effect. It is well known that any imperfections in a vibratory gyroscope (VG) affect Bryan's law and this affects the accuracy of the VG. Consequently, in this paper, we assume that all such imperfections are either minimised or eliminated by some known control method and that only damping is present within the VG. If the damping is isotropic (linear or nonlinear), then it has been recently demonstrated in this journal, using symbolic analysis, that Bryan's law remains invariant. However, it is known that linear anisotropic damping does affect Bryan's law. In this paper, we generalise Rayleigh's dissipation function so that anisotropic nonlinear damping may be introduced into the equations of motion. Using a mixture of numeric and symbolic analysis on the ODEs of motion of the VG, for anisotropic light nonlinear damping, we demonstrate (up to an approximate average), that Bryan's law is affected by any form of such damping, causing pattern drift, compromising the accuracy of the VG.

Evolution of magnetostructural transition and magnetocaloric effect with Al doping in MnCoGe1-xAlx compounds

KAUST Repository

Bao, Lifu; Hu, Fengxia; Wu, Rongrong; Wang, Jianping; Chen, Liming; Sun, Jirong; Shen, Baogen; Li, Lain-Jong; Zhang, Bei; Zhang, Xixiang

2014-01-01

The effect of Al doping in MnCoGe1-xAlx compounds has been investigated. The substitution of Al for Ge enhances Mn-Mn covalent bonding by shortening the distance of nearest Mn atom layers, and thus stabilizes the hexagonal structure. As a result, first-order magnetostructural transition between ferromagnetic martensite and paramagnetic austenite takes place for the optimized compositions (x = 0.01, 0.02). Accompanied with the magnetostructural transition, large magnetocaloric effect (MCE) is observed. More doping of Al(x = 0.03, 0.04) leads to the separation of magnetic and structural transitions and remarkable reduction of MCE. © 2014 IOP Publishing Ltd.

Evolution of magnetostructural transition and magnetocaloric effect with Al doping in MnCoGe1-xAlx compounds

KAUST Repository

Bao, Lifu

2014-01-03

The effect of Al doping in MnCoGe1-xAlx compounds has been investigated. The substitution of Al for Ge enhances Mn-Mn covalent bonding by shortening the distance of nearest Mn atom layers, and thus stabilizes the hexagonal structure. As a result, first-order magnetostructural transition between ferromagnetic martensite and paramagnetic austenite takes place for the optimized compositions (x = 0.01, 0.02). Accompanied with the magnetostructural transition, large magnetocaloric effect (MCE) is observed. More doping of Al(x = 0.03, 0.04) leads to the separation of magnetic and structural transitions and remarkable reduction of MCE. © 2014 IOP Publishing Ltd.

Magnetocaloric effect in Sr2CrIrO6 double perovskite: Monte Carlo simulation

Science.gov (United States)

El Rhazouani, O.; Slassi, A.; Ziat, Y.; Benyoussef, A.

2017-05-01

Monte Carlo simulation (MCS) combined with the Metropolis algorithm has been performed to study the magnetocaloric effect (MCE) in the promising double perovskite (DP) Sr2CrIrO6 that has not so far been synthetized. This paper presents the global magneto-thermodynamic behavior of Sr2CrIrO6 compound in term of MCE and discusses the behavior in comparison to other DPs. Thermal dependence of the magnetization has been investigated for different values of reduced external magnetic field. Thermal magnetic entropy and its change have been obtained. The adiabatic temperature change and the relative cooling power have been established. Through the obtained results, Sr2CrIrO6 DP could have some potential applications for magnetic refrigeration over a wide temperature range above room temperature and at large magnetic fields.

Magnetic and magnetocaloric properties of martensitic Ni2Mn1.4Sn0.6 Heusler alloy

International Nuclear Information System (INIS)

Chernenko, Volodymyr A.; Barandiarán, Jose M.; Rodriguez Fernández, Jesus; Rojas, Daniel P.; Gutiérrez, Jon; Lázpita, Patricia; Orue, Iñaki

2012-01-01

The evolutions of magnetic properties at low temperatures and the influence of magnetic field on the temperature dependence of specific heat in martensitic Ni 2 Mn 1.4 Sn 0.6 Heusler alloy are studied. The frequency-dependent blocking temperature and considerable exchange bias below it are measured in the martensitic phase. From the analysis of the specific heat curves under magnetic field, a large inverse magnetocaloric effect manifested as the magnetic field induced rise of isothermal magnetic entropy and/or magnetic field induced adiabatic temperature decrease in the vicinity of the reverse magnetostructural transformation and a significant value of the conventional magnetocaloric effect at the Curie temperature are obtained. The Debye temperature and electronic coefficient equal to Θ D =310±2 K and γ= 16.6±0.3 mJ/K 2 mol, respectively, do not depend on the magnetic field.

Pressure effects in the giant magnetocaloric compounds Gd.sub.5./sub.(Si.sub.x./sub.Ge.sub.1 - x./sub.).sub.4./sub..

Czech Academy of Sciences Publication Activity Database

Morellon, L.; Arnold, Zdeněk; Algarabel, P. A.; Magen, C.; Ibarra, M. R.; Skorokhod, Yuriy

2004-01-01

Roč. 16, - (2004), s. 1623-1630 ISSN 0953-8984 R&D Projects: GA ČR GA106/02/0943 Grant - others:CICYT(ES) MAT2000-1756 Institutional research plan: CEZ:AV0Z1010914 Keywords : magnetocaloric effect * high pressure * Gd 5 Si 4-x Ge x * magnetic transitions Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.049, year: 2004

Chiral magnetic effect in the anisotropic quark-gluon plasma

International Nuclear Information System (INIS)

Ali-Akbari, Mohammad; Taghavi, Seyed Farid

2015-01-01

An anisotropic thermal plasma phase of a strongly coupled gauge theory can be holographically modelled by an anisotropic AdS black hole. The temperature and anisotropy parameter of the AdS black hole background of interest http://dx.doi.org/10.1007/JHEP07(2011)054 is specified by the location of the horizon and the value of the Dilaton field at the horizon. Interestingly, for the first time, we obtain two functions for the values of the horizon and Dilaton field in terms of the temperature and anisotropy parameter. Then by introducing a number of spinning probe D7-branes in the anisotropic background, we compute the value of the chiral magnetic effect (CME). We observe that in the isotropic and anisotropic plasma the value of the CME is equal for the massless quarks. However, at fixed temperature, raising the anisotropy in the system will increase the value of the CME for the massive quarks.

A study on the effective hydraulic conductivity of an anisotropic porous medium

International Nuclear Information System (INIS)

Seong, Kwan Jae

2002-01-01

Effective hydraulic conductivity of a statistically anisotropic heterogeneous medium is obtained for steady two-dimensional flows employing stochastic analysis. Flow equations are solved up to second order and the effective conductivity is obtained in a semi-analytic form depending only on the spatial correlation function and the anisotropy ratio of the hydraulic conductivity field, hence becoming a true intrinsic property independent of the flow field. Results are obtained using a statistically anisotropic Gaussian correlation function where the anisotropic is defined as the ratio of integral scales normal and parallel to the mean flow direction. Second order results indicate that the effective conductivity of an anisotropic medium is greater than that of an isotropic one when the anisotropy ratio is less than one and vice versa. It is also found that the effective conductivity has upper and lower bounds of the arithmetic and the harmonic mean conductivities

Study of Magnetocaloric Cooling for Thermal Management

Science.gov (United States)

2012-11-12

The AMR bed, made of stainless steel 304, encloses the magnetocaloric working substance. Each part of the refrigerator is controlled by the...prototype is composed of magnetic field, hydraulic circuit, stainless steel AMR bed and control system. There are various sensors for measuring...DSC and VSM results show that the martensitic transition temperatures of Ni-Co-Mn-Sn decreased with increasing Co content. Co substitution resulted in

Magnetism of a sigma-phase Fe{sub 60}V{sub 40} alloy: Magnetic susceptibilities and magnetocaloric effect studies

Energy Technology Data Exchange (ETDEWEB)

Bałanda, Maria [Institute of Nuclear Physics, Polish Academy of Science, PL-31-342 Kraków (Poland); Dubiel, Stanisław M., E-mail: Stanislaw.Dubiel@fis.agh.edu.pl [AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, PL-30-059 Kraków (Poland); Pełka, Robert [Institute of Nuclear Physics, Polish Academy of Science, PL-31-342 Kraków (Poland)

2017-06-15

Highlights: • Sigma-phase Fe{sub 60}V{sub 40} alloy was studied by means of AC and DC magnetic susceptibilities. • Re-entrant character of the magnetism has been evidenced. • Curie temperature was found as ∼169 K and the spin-freezing temperature as ∼164 K. • Critical exponents β = 0.6, γ = 1.0 and Δ = 1.6 were determined. • Magnetocaloric effect was investigated. - Abstract: Magnetic properties of a sigma-phase Fe{sub 60}V{sub 40} intermetallic compound were studied by means of ac and dc magnetic susceptibility and magnetocaloric effect measurements. The compound is a soft magnet yet it was found to behave like a re-entrant spin-glass system. The magnetic ordering temperature was found to be T{sub C} ≈ 170 K, while the spin-freezing temperature was ∼164 K. Its relative shift per decade of ac frequency was 0.002, a value smaller than that typical of canonical spin-glasses. Magnetic entropy change, ΔS, in the vicinity of T{sub C} was determined for magnetic field, H, ranging between 5 and 50 kOe. Analysis of ΔS in terms of the power law yielded the critical exponent, n, vs. temperature with the minimum value of 0.75 at T{sub C}, while from the analysis of a relative shift of the maximum value of ΔS with the field a critical exponent Δ = 1.7 was obtained. Based on scaling laws relationships values of other two exponents viz. β = 0.6 and γ = 1 were determined.

Thermodynamic behavior and enhanced magnetocaloric effect in a frustrated spin-1/2 Ising-Heisenberg triangular tube

Science.gov (United States)

Alécio, Raphael Cavalcante; Strečka, Jozef; Lyra, Marcelo L.

2018-04-01

The thermodynamic behavior of an Ising-Heisenberg triangular tube with Heisenberg intra-rung and Ising inter-rung interactions is exactly obtained in an external magnetic field within the framework of the transfer-matrix method. We report rigorous results for the temperature dependence of the magnetization, entropy, pair correlations and specific heat, as well as typical iso-entropic curves. The discontinuous field-driven ground-state phase transitions are reflected in some anomalous thermodynamic behavior as for instance a striking low-temperature peak of the specific heat and an enhanced magnetocaloric effect. It is demonstrated that the intermediate magnetization plateaus shrink in and the relevant sharp edges associated with the magnetization jump round off upon increasing temperature.

Magnetic Grüneisen parameter and magnetocaloric properties of a coupled spin–electron double-tetrahedral chain

International Nuclear Information System (INIS)

Gálisová, Lucia; Strečka, Jozef

2015-01-01

Magnetocaloric effect in a double-tetrahedral chain, in which nodal lattice sites occupied by the localized Ising spins regularly alternate with three equivalent lattice sites available for mobile electrons, is exactly investigated by considering the one-third electron filling and the ferromagnetic Ising exchange interaction between the mobile electrons and their nearest Ising neighbours. The entropy and the magnetic Grüneisen parameter, which closely relate to the magnetocaloric effect, are exactly calculated in order to investigate the relation between the ground-state degeneracy and the cooling efficiency of the hybrid spin–electron system during the adiabatic demagnetization. - Highlights: • A double-tetrahedral chain of mobile electrons and localized Ising spins is studied. • Magnetic Grüneisen parameter for the system is exactly derived. • Macroscopically degenerate phases FRU and FM constitute the ground state. • MCE is three times higher nearby FRU–FM transition than in FRU phase at small fields

Spatially resolved measurements of the magnetocaloric effect and the local magnetic field using thermography

DEFF Research Database (Denmark)

Christensen, Dennis; Bjørk, Rasmus; Nielsen, Kaspar Kirstein

2010-01-01

The magnetocaloric effect causes a magnetic material to change temperature upon application of a magnetic field. Here, spatially resolved measurements of the adiabatic temperature change are performed on a plate of gadolinium using thermography. The adiabatic temperature change is used to extract...... the corresponding change in the local magnetic field strength. The measured temperature change and local magnetic field strength are compared to results obtained with a numerical model, which takes demagnetization into account and employs experimental data....

Magneto-caloric and magneto-resistive properties of La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Reves Dinesen, Anders

2004-08-01

This thesis presents results of an experimental investigation of magneto-caloric and magneto-resistive properties of a series of polycrystalline Ca- and Sr-doped lanthanum manganites, La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3} (0{<=} x {<=} 0.33), with the perovskite structure. The samples consisted of sintered oxide powders prepared the glycine-nitrate combustion technique. The compounds were ferromagnetic and showed a Curie transition in the temperature range 267370 K (T{sub C} increased with increasing x). An analysis of the structural properties was carried out by means of x-ray diffraction and the Rietveld technique. The variation of the Ca/Sr ratio was found to cause a transition from orthorhombic to rhombohedral symmetry in the composition range 0.110 < x < 0.165. The analysis suggested a strong correlation between structural properties and magnetism, for instance a relationship between the mean MnOMn bond angle and the Curie temperature. The MnOMn bonds mediate ferromagnetism and electrical transport in these materials via the double-exchange mechanism. The magnetocaloric effect of the La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3} samples was measured directly and indirectly (by means of magnetization measurements). All the samples showed a magnetocaloric effect in the vicinity of T{sub C}. A model for the mag-netocaloric effect based on Weiss mean field theory and classical theories for heat capacities was developed. The model provided reasonable predictions of the magneto-caloric properties of the samples. The compounds with low Sr content showed a magnetocaloric effect comparable to that of Gadolinium, the prototypical working material for magnetic refrigeration at room temperature. A less comprehensive part of the investigation regarded the magneto-resistive properties of the La{sub 0.67}Ca{sub 0.33-x}Sr{sub x}MnO{sub 3} system. It was found that th polycrystalline nature of the compounds played a decisive role for the magnetotransport properties

Scaling and universality in magnetocaloric materials

DEFF Research Database (Denmark)

Smith, Anders; Nielsen, Kaspar Kirstein; Bahl, Christian R. H.

2014-01-01

-order phase transition within the context of the theory of critical phenomena. Sufficiently close to the critical temperature of a second-order material, the scaling of the isothermal entropy change will be determined by the critical exponents and will be the same as that of the singular part of the entropy......The magnetocaloric effect of a magnetic material is characterized by two quantities, the isothermal entropy change and the adiabatic temperature change, both of which are functions of temperature and applied magnetic field. We discuss the scaling properties of these quantities close to a second...... fields are not universal, showing significant variation for models in the same universality class. As regards the adiabatic temperature change, it is not determined exclusively by the singular part of the free energy and its derivatives. We show that the field dependence of the adiabatic temperature...

Second Law Violation By Magneto-Caloric Effect Adiabatic Phase Transition of Type I Superconductive Particles

OpenAIRE

Keefe, Peter

2004-01-01

Abstract: The nature of the thermodynamic behavior of Type I superconductor particles, having a cross section less than the Ginzburg-Landau temperature dependent coherence length is discussed for magnetic field induced adiabatic phase transitions from the superconductive state to the normal state. Argument is advanced supporting the view that when the adiabatic magneto-caloric process is applied to particles, the phase transition is characterized by a decrease in entropy in violation of tradi...

Co and In doped Ni-Mn-Ga magnetic shape memory alloys: a thorough structural, magnetic and magnetocaloric study

Czech Academy of Sciences Publication Activity Database

Fabbrici, S.; Porcari, G.; Cugini, F.; Solzi, M.; Kamarád, Jiří; Arnold, Zdeněk; Cabassi, R.; Albertini, F.

2014-01-01

Roč. 16, č. 4 (2014), s. 2204-2222 ISSN 1099-4300 Institutional support: RVO:68378271 Keywords : magnetic shape memory materials * magnetocaloric effect * multifunctional Heusler alloys Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.502, year: 2014

Phase control studies in Gd5Si2Ge2 giant magnetocaloric compound

International Nuclear Information System (INIS)

Belo, J.H.; Pereira, A.M.; Ventura, J.; Oliveira, G.N.P.; Araújo, J.P.; Tavares, P.B.; Fernandes, L.; Algarabel, P.A.; Magen, C.; Morellon, L.

2012-01-01

Highlights: ► Study of time dependence of O(I) to M phase. ► Determination of the optimal annealing time. ► New method for phase amount estimation (O(I) and M). ► Effect of annealing on the MCE. ► Analysis of the nature of the magnetic transition through the Arrot plot representation. - Abstract: A systematic set of annealings on arc-melted synthesized Gd 5 Si 2 Ge 2 sample was performed. Through powder X-ray diffraction (XRD) and magnetometry measurements we monitored the effect of varying the annealing time with constant temperature (T = 1473 K) on the formation of the monoclinic (M) crystallographic phase fraction, which is the one responsible for the giant magnetocaloric effect (GMCE) in this compound. The conversion of the orthorhombic O(I) crystallographic phase into M was achieved, resulting in a significant increase of the M mass fraction. Such conversion led to a change in the magnetic transition nature, evolving from a second to a first order transition for the as-cast and annealed samples, respectively. An optimal annealing time range for the M phase conversion was identified to be within 80–120 min at T = 1473 K followed by a rapid quenching to liquid N 2 . Furthermore, an increase up to ∼50% of the magnetocaloric effect was obtained for the sample annealed during 120 min.

Giant anisotropy of magnetocaloric effect in TbMnO3 single crystals

Science.gov (United States)

Jin, Jin-Ling; Zhang, Xiang-Qun; Li, Guo-Ke; Cheng, Zhao-Hua; Zheng, Lin; Lu, Yi

2011-05-01

The magnetocaloric effect (MCE) in TbMnO3 single crystals was investigated by isothermal magnetization curves for the ab plane at low temperatures. Large magnetic entropy change, ΔSM = -18.0 J/kg K, and the refrigerant capacity, RC = 390.7 J/kg, are achieved near the ordering temperature of Tb3+ moment (TNTb) under 70 kOe along the a axis. Furthermore, the TbMnO3 single crystal exhibits a giant MCE anisotropy. The difference of ΔSMand RC between the a and b axes is field and temperature dependent, which reaches maximum values of 11.4 J/kg K and 304.1 J/kg, respectively. By taking magnetocrystalline anisotropy into account, the rotating ΔSMwithin the ab plane can be well simulated, indicating that the anisotropy of ΔSMis directly contributed from the magnetocrystalline anisotropy. Our finding for giant MCE anisotropy in TbMnO3 single crystals explores the possibility of using this material for magnetic refrigerators by rotating its magnetization vector rather than moving it in and out of the magnet.

Effect of spin fluctuations in magnetocaloric and magnetoresistance properties of Dy10Co20Si70 alloy

Science.gov (United States)

Rashid, T. P.; Arun, K.; Curlik, Ivan; Ilkovic, Sergej; Reiffers, Marian; Dzubinska, Andrea; Nagalakshmi, R.

2017-09-01

Systematic investigations on the structure, magnetic, thermodynamic, magnetocaloric and magnetoresistance (MR) properties of the arc melted Dy10Co20Si70 alloy are presented. The Dy10Co20Si70 alloy crystallizes in tetragonal BaNiSn3-type DyCoSi3 (space group = I4mm; No. 107) as a major phase and CaF2-type CoSi2 (space group = Fm-3m; No. 225) and C-type Si (space group = Fd-3m; No. 227) as minor phases. The title compound exhibits multiple magnetic transitions having antiferromagnetic ordering at temperatures, viz., T1 = 10.8 K, T2 = 8.8 K and T3 = 3.3 K. The magnetic and thermodynamic studies confirm these magnetic anomalies in the compound. The large value of maximum magnetic entropy change, -ΔSMM a x = 16.4 and 26.6 J/kg K for the field change ΔH of 50 and 90 kOe, respectively, observed in the compound is associated with field induced magnetic transitions. Asymmetric broadening of the magnetic entropy change peaks above the ordering temperatures resulting in significant refrigerant capacities of 361 and 868 J/kg for ΔH = 50 and 90 kOe, respectively, in the compound is due to the spin fluctuation effect. The sign reversal in MR measurements is attributed to the field induced antiferromagnetic to ferromagnetic transition. A large positive MR (42% in 90 kOe) is observed at 2 K. The H2 dependence of both the magnetocaloric effect (MCE) and MR in the paramagnetic regime indicates the role of the applied magnetic field in suppressing the spin fluctuations. The large MCE and MR together with no thermal or magnetic hysteresis establish this new compound as an attractive multifunctional magnetic material.

Pulsed high-magnetic-field experiments: New insights into the magnetocaloric effect in Ni-Mn-In Heusler alloys

International Nuclear Information System (INIS)

Salazar Mejía, C.; Nayak, A. K.; Felser, C.; Nicklas, M.; Ghorbani Zavareh, M.; Wosnitza, J.; Skourski, Y.

2015-01-01

The present pulsed high-magnetic-field study on Ni 50 Mn 35 In 15 gives an extra insight into the thermodynamics of the martensitic transformation in Heusler shape-memory alloys. The transformation-entropy change, ΔS, was estimated from field-dependent magnetization experiments in pulsed high magnetic fields and by heat-capacity measurements in static fields. We found a decrease of ΔS with decreasing temperature. This behavior can be understood by considering the different signs of the lattice and magnetic contributions to the total entropy. Our results further imply that the magnetocaloric effect will decrease with decreasing temperature and, furthermore, the martensitic transition is not induced anymore by changing the temperature in high magnetic fields

The influence of Co substitution on the magnetocaloric effect of Gd(Al,Fe)2

International Nuclear Information System (INIS)

Deng, J Q; Yan, J L; Huang, J L; Zhu, J M; Chen, X; Zhuang, Y H

2007-01-01

The magnetocaloric effect (MCE) in samples GdAl 1.7 (Fe 1-x Co x ) 0.3 with x= 0, 0.1, 0.2, 0.3 and 0.4 were investigated by x-ray diffraction (XRD) and magnetization measurements. It was found that five samples crystallize well in the MgCu 2 -type structure. The lattice parameter and the values of Curie temperature decrease with increasing Co content, whereas the magnetic-entropy change and cooling capacity increase. In the magnetic-field change of 2.0 T the maximum of the magnetic-entropy change and refrigerant capacity in sample GdAl 1.7 Fe 0.7 Co 0.3 reach 4.8 J kg -1 K -1 and 88.3 J kg -1 , respectively. The maximum of the magnetic-entropy change is comparable to that of Gd metal (3.8 J kg -1 K -1 in Δ B=1.5 T)

Magnetocaloric refrigeration near room temperature (invited)

International Nuclear Information System (INIS)

Brueck, E.; Tegus, O.; Thanh, D.T.C.; Buschow, K.H.J.

2007-01-01

Modern society relies on readily available refrigeration. The ideal cooling machine would be a compact, solid state, silent and energy-efficient heat pump that does not require maintenance. Magnetic refrigeration has three prominent advantages compared to compressor-based refrigeration. First, there are no harmful gases involved, second it may be built more compact as the working material is a solid and third magnetic refrigerators generate much less noise. Recently, a new class of magnetic refrigerant materials for room-temperature applications was discovered. These new materials have important advantages over existing magnetic coolants: They exhibit a large magnetocaloric effect (MCE) in conjunction with a magnetic phase transition of first order. This MCE is, larger than that of Gd metal, which is used in the demonstration refrigerators built to explore the potential of this evolving technology. In the present review, we compare the different materials considering both scientific aspects and industrial applicability

Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window

KAUST Repository

Liu, E. K.

2013-03-28

An effective scheme of isostructural alloying was applied to establish a Curie-temperature window in isostructural MnNiGe-CoNiGe system. With the simultaneous accomplishment of decreasing structural-transition temperature and converting antiferromagnetic martensite to ferromagnetic state, a 200 K Curie-temperature window was established between Curie temperatures of austenite and martensite phases. In the window, a first-order magnetostructural transition between paramagnetic austenite and ferromagnetic martensite occurs with a sharp jump in magnetization, showing a magnetic entropy change as large as −40 J kg−1 K−1 in a 50 kOe field change. This giant magnetocaloric effect enables Mn1− x Co x NiGe to become a potential magnetic refrigerant.

Experimental results for a magnetic refrigerator using three different types of magnetocaloric material regenerators

DEFF Research Database (Denmark)

Engelbrecht, Kurt; Bahl, Christian Robert Haffenden; Nielsen, Kaspar Kirstein

2011-01-01

in an experimental device. This paper compares the performance of three magnetocaloric material candidates for AMRs, La(Fe,Co,Si)13, (La,Ca,Sr)MnO3 and Gd, in an experimental active magnetic regenerator with a parallel plate geometry. The performance of single-material regenerators of each magnetocaloric material...... family were compared. In an attempt to improve system performance, graded two-material regenerators were made from two different combinations of La(Fe,Co,Si)13 compounds having different magnetic transition temperatures. One combination of the La(Fe,Co,Si)13 materials yielded a higher performance, while...

Effect of neutron anisotropic scattering in fast reactor analysis

International Nuclear Information System (INIS)

Chiba, Gou

2004-01-01

Numerical tests were performed about an effect of a neutron anisotropic scattering on criticality in the Sn transport calculation. The simplest approximation, the consistent P approximation and the extended transport approximation were compared with each other in one-dimensional slab fast reactor models. JAERI fast set which has been used for fast reactor analyses is inadequate to evaluate the effect because it doesn't include the scattering matrices and the self-shielding factors to calculate the group-averaged cross sections weighted by the higher-order moment of angular flux. In the present study, the sub-group method was used to evaluate the group-averaged cross sections. Results showed that the simplest approximation is inadequate and the transport approximation is effective for evaluating the anisotropic scattering. (author)

A novel magnetic valve using room temperature magnetocaloric materials

DEFF Research Database (Denmark)

Eriksen, Dan; Bahl, Christian; Pryds, Nini

2012-01-01

changes. This is made possible by the strong temperature dependence of the magnetization close to the Curie temperature of the magnetocaloric materials. Different compositions of both La0.67(Ca,Sr)0.33MnO3 and La(Fe,Co,Si)13 have been considered for use in prototype valves. Based on measured magnetization...

Magnetocaloric and magnetoresistive properties of La0.67Ca0.33-xSrxMnO3

DEFF Research Database (Denmark)

Dinesen, Anders Reves

This thesis presents results of an experimental investigation of magneto-caloric and magnetoresistive properties of a series of polycrystalline Ca- and Sr-doped lanthanum manganites, La0.67Ca0.33-xSrxMnO3 (0=x=0.33 ), with the perovskite structure. The samples consisted of sintered oxide powders...... prepared the glycine-nitrate combustion technique. The compounds were ferromagnetic and showed a Curie transition in the temperature range 267–370 K (TC increased with increasing x). An analysis of the structural properties was carried out by means of x-ray diffraction and the Rietveld technique...... and the Curie temperature. The Mn–O–Mn bonds mediate ferromagnetism and electrical transport in these materials via the double-exchange mechanism. The magnetocaloric effect of the La0.67Ca0.33-xSrxMnO3 samples was measured directly and indirectly (by means of magnetization measurements). All the samples showed...

Magnetocaloric Properties of Fe-Ni-Cr Nanoparticles for Active Cooling

Science.gov (United States)

Chaudhary, V.; Ramanujan, R. V.

2016-10-01

Low cost, earth abundant, rare earth free magnetocaloric nanoparticles have attracted an enormous amount of attention for green, energy efficient, active near room temperature thermal management. Hence, we investigated the magnetocaloric properties of transition metal based (Fe70Ni30)100-xCrx (x = 1, 3, 5, 6 and 7) nanoparticles. The influence of Cr additions on the Curie temperature (TC) was studied. Only 5% of Cr can reduce the TC from ~438 K to 258 K. These alloys exhibit broad entropy v/s temperature curves, which is useful to enhance relative cooling power (RCP). For a field change of 5 T, the RCP for (Fe70Ni30)99Cr1 nanoparticles was found to be 548 J-kg-1. Tunable TCin broad range, good RCP, low cost, high corrosion resistance and earth abundance make these nanoparticles suitable for low-grade waste heat recovery as well as near room temperature active cooling applications.

Giant magnetocaloric effect in Gd5(Si2Ge2 alloy with low purity Gd

Directory of Open Access Journals (Sweden)

Cleber Santiago Alves

2004-12-01

Full Text Available Gd5(Ge1-xSi x, x < 4 based alloys are potential candidates for magnetic refrigeration in the range ~20 - ~290 K. However, one of the greatest obstacles for the use of that technology in large scale is the utilization of high pure Gd metal (99.99 wt. (% to produce the GdGeSi alloys, since the impurity elements decrease the intensity of the magnetocaloric effect (EMC¹. In this work, we prove that annealing of the Gd5Ge2Si2 can promote remarkable values for the EMC in comparison to those obtained for the alloy with high pure Gd. Also, the as cast alloy and the annealed alloy are not monophasic, but have at least two crystalline phases in their microstructure. Results for X-ray analysis, optical and electronic microscopy and magnetization measurements are reported.

Effective Medium Theory for Anisotropic Metamaterials

KAUST Repository

Zhang, Xiujuan

2017-11-12

This dissertation includes the study of effective medium theories (EMTs) and their applications in describing wave propagation in anisotropic metamaterials, which can guide the design of metamaterials. An EMT based on field averaging is proposed to describe a peculiar anisotropic dispersion relation that is linear along the symmetry line but quadratic in the perpendicular direction. This dispersion relation is associated with the topological transition of the iso-frequency contours (IFCs), suggesting interesting wave propagation behaviors from beam shaping to beam splitting. In the framework of coherent potential approximation, an analytical EMT is further developed, with the ability to build a direct connection between the microscopic structure and the macroscopic material properties, which overcomes the requirement of prior knowledge of the field distributions. The derived EMT is valid beyond the long-wavelength limit. Using the EMT, an anisotropic zero-index metamaterial is designed. Moreover, the derived EMT imposes a condition that no scattered wave is generated in the ambient medium, which suggests the input signal cannot detect any object that might exist, making it invisible. Such correspondence between the EMT and the invisibilityinspires us to explore the wave cloaking in the same framework of coherent potential approximation. To further broaden the application realm of EMT, an EMT using the parameter retrieval method is studied in the regimes where the previously-developed EMTs are no longer accurate. Based on this study, in conjunction with the EMT mentioned above, a general scheme to realize coherent perfect absorption (CPA) in anisotropic metamaterials is proposed. As an exciting area in metamaterials, the field of metasurfaces has drawn great attention recently. As an easily attainable device, a grating may be the simplest version of metasurfaces. Here, an analytical EMT for gratings made of cylinders is developed by using the multiple scattering

Magnetocaloric effect and multifunctional properties of Ni-Mn-based Heusler alloys

Energy Technology Data Exchange (ETDEWEB)

Dubenko, Igor, E-mail: igor_doubenko@yahoo.com [Department of Physics, Southern Illinois University, Carbondale, IL 62901 (United States); Samanta, Tapas; Kumar Pathak, Arjun [Department of Physics, Southern Illinois University, Carbondale, IL 62901 (United States); Kazakov, Alexandr; Prudnikov, Valerii [Faculty of Physics, Moscow State University, Vorob' evy Gory, 11999I Moscow (Russian Federation); Stadler, Shane [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803 (United States); Granovsky, Alexander [Faculty of Physics, Moscow State University, Vorob' evy Gory, 11999I Moscow (Russian Federation); IKERBASQUE, The Basque Foundation for Science, 48011 Bilbao (Spain); Departamento de Fisica de Materiales, Facultad de Quimica, Universidad del Pais Vasco, Paseo M. de Lardizabal 3, 20018 Donostia - San Sebastian (Spain); Zhukov, Arcady [IKERBASQUE, The Basque Foundation for Science, 48011 Bilbao (Spain); Departamento de Fisica de Materiales, Facultad de Quimica, Universidad del Pais Vasco, Paseo M. de Lardizabal 3, 20018 Donostia - San Sebastian (Spain); Ali, Naushad [Department of Physics, Southern Illinois University, Carbondale, IL 62901 (United States)

2012-10-15

The studies of magnetocaloric properties, phase transitions, and phenomena related to magnetic heterogeneity in the vicinity of the martensitic transition (MT) in Ni-Mn-In and Ni-Mn-Ga off-stoichiometric Heusler alloys are summarized. The crystal structure, magnetocaloric effect (MCE), and magnetotransport properties were studied for the following alloys: Ni{sub 50}Mn{sub 50-x}In{sub x}, Ni{sub 50-x}Co{sub x}Mn{sub 35}In{sub 15}, Ni{sub 50}Mn{sub 35-x}Co{sub x}In{sub 15}, Ni{sub 50}Mn{sub 35}In{sub 14}Z (Z=Al, Ge), Ni{sub 50}Mn{sub 35}In{sub 15-x}Si{sub x}, Ni{sub 50-x}Co{sub x}Mn{sub 25+y}Ga{sub 25-y}, and Ni{sub 50-x}Co{sub x}Mn{sub 32-y}FeyGa{sub 18}. It was found that the magnetic entropy change, {Delta}S, associated with the inverse MCE in the vicinity of the temperature of the magneto-structural transition, TM, persists in a range of (125-5) J/(kg K) for a magnetic field change {Delta}H=5 T. The corresponding temperature varies with composition from 143 to 400 K. The MT in Ni{sub 50}Mn{sub 50-x}In{sub x} (x=13.5) results in a transition between two paramagnetic states. Associated with the paramagnetic austenite-paramagnetic martensite transition {Delta}S=24 J/(kg K) was detected for {Delta}H=5 T at T=350 K. The variation in composition of Ni{sub 2}MnGa can drastically change the magnetic state of the martensitic phase below and in the vicinity of TM. The presence of the martensitic phase with magnetic moment much smaller than that in the austenitic phase above TM leads to the large inverse MCE in the Ni{sub 42}Co{sub 8}Mn{sub 32-y}FeyGa{sub 18} system. The adiabatic change of temperature ({Delta}T{sub ad}) in the vicinity of TC and TM of Ni{sub 50}Mn{sub 35}In{sub 15} and Ni{sub 50}Mn{sub 35}In{sub 14}Z (Z=Al, Ge) was found to be {Delta}T{sub ad}=-2 K and 2 K for {Delta}H=1.8 T, respectively. It was observed that |{Delta}T{sub ad}| Almost-Equal-To 1 K for {Delta}H=1 T for both types of transitions. The results on resistivity, magnetoresistance, Hall

Effective Elliptic Models for Efficient Wavefield Extrapolation in Anisotropic Media

KAUST Repository

Waheed, Umair bin

2014-05-01

Wavefield extrapolation operator for elliptically anisotropic media offers significant cost reduction compared to that of transversely isotropic media (TI), especially when the medium exhibits tilt in the symmetry axis (TTI). However, elliptical anisotropy does not provide accurate focusing for TI media. Therefore, we develop effective elliptically anisotropic models that correctly capture the kinematic behavior of the TTI wavefield. Specifically, we use an iterative elliptically anisotropic eikonal solver that provides the accurate traveltimes for a TI model. The resultant coefficients of the elliptical eikonal provide the effective models. These effective models allow us to use the cheaper wavefield extrapolation operator for elliptic media to obtain approximate wavefield solutions for TTI media. Despite the fact that the effective elliptic models are obtained by kinematic matching using high-frequency asymptotic, the resulting wavefield contains most of the critical wavefield components, including the frequency dependency and caustics, if present, with reasonable accuracy. The methodology developed here offers a much better cost versus accuracy tradeoff for wavefield computations in TTI media, considering the cost prohibitive nature of the problem. We demonstrate the applicability of the proposed approach on the BP TTI model.

Effective Elliptic Models for Efficient Wavefield Extrapolation in Anisotropic Media

KAUST Repository

Waheed, Umair bin; Alkhalifah, Tariq Ali

2014-01-01

Wavefield extrapolation operator for elliptically anisotropic media offers significant cost reduction compared to that of transversely isotropic media (TI), especially when the medium exhibits tilt in the symmetry axis (TTI). However, elliptical anisotropy does not provide accurate focusing for TI media. Therefore, we develop effective elliptically anisotropic models that correctly capture the kinematic behavior of the TTI wavefield. Specifically, we use an iterative elliptically anisotropic eikonal solver that provides the accurate traveltimes for a TI model. The resultant coefficients of the elliptical eikonal provide the effective models. These effective models allow us to use the cheaper wavefield extrapolation operator for elliptic media to obtain approximate wavefield solutions for TTI media. Despite the fact that the effective elliptic models are obtained by kinematic matching using high-frequency asymptotic, the resulting wavefield contains most of the critical wavefield components, including the frequency dependency and caustics, if present, with reasonable accuracy. The methodology developed here offers a much better cost versus accuracy tradeoff for wavefield computations in TTI media, considering the cost prohibitive nature of the problem. We demonstrate the applicability of the proposed approach on the BP TTI model.

Toward a better understanding of the magnetocaloric effect: An experimental and theoretical study of MnFe{sub 4}Si{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Gourdon, Olivier, E-mail: gourdono@lanl.gov [Los Alamos Neutron Scattering Center, National Laboratory, Los Alamos, NM 87545 (United States); Gottschlich, Michael; Persson, Joerg [Jülich Center for Neutron Science JCNS-2 and Peter Grünberg Institut PGI-4, JARA-FIT, Forschungszentrum Jülich 52425 Jülich (Germany); Cruz, Clarina de la [Quantum Condensed Matter Division, Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Petricek, Vaclav [Institute of Physics ASCR v.v.i., Na Slovance 2, 182 21 Prague (Czech Republic); McGuire, Michael A. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Brückel, Thomas [Jülich Center for Neutron Science JCNS-2 and Peter Grünberg Institut PGI-4, JARA-FIT, Forschungszentrum Jülich 52425 Jülich (Germany)

2014-08-15

The intermetallic compound MnFe{sub 4}Si{sub 3} has been studied by high-resolution Time of Flight (TOF) neutron powder diffraction. MnFe{sub 4}Si{sub 3} crystallizes in the hexagonal space group P6{sub 3}/mcm with lattice constants of a=b=6.8043(4) Å and c=4.7254(2) Å at 310 K. Magnetic susceptibility measurements show clearly the magnetic transition from paramagnetism to ferromagnetism at about 302(2) K. Magnetic structure refinements based on neutron powder diffraction data with and without external magnetic field reveal strong evidence on the origin of the large magnetocaloric effect (MCE) in this material as a partial reordering of the spins between ∼270 K and 300 K. In addition, electronic structure calculations using the self-consistent, spin-polarized Tight Binding-Linear MuffinTin Orbital (TB-LMTO) method were also accomplished to address the “coloring problem” (Mn/Fe site preference) as well as the unique ferromagnetic behavior of this intermetallic compound. - Graphical abstract: Theoretical and experimental reinvestigation of the magnetic structure of MnFe{sub 4}Si{sub 3} for a better understanding of its large magnetocaloric effect (MCE). - Highlights: • Strong magnetic transition from paramagnetism to ferromagnetism at about 302(2) K. • MCE associated to a partial reordering of the spins between ∼270 K and 300 K. • DFT calculations show strong relation between MCE and spintronic materials.

Magnetic and magnetocaloric properties of the exactly solvable mixed-spin Ising model on a decorated triangular lattice in a magnetic field

Science.gov (United States)

Gálisová, Lucia; Strečka, Jozef

2018-05-01

The ground state, zero-temperature magnetization process, critical behaviour and isothermal entropy change of the mixed-spin Ising model on a decorated triangular lattice in a magnetic field are exactly studied after performing the generalized decoration-iteration mapping transformation. It is shown that both the inverse and conventional magnetocaloric effect can be found near the absolute zero temperature. The former phenomenon can be found in a vicinity of the discontinuous phase transitions and their crossing points, while the latter one occurs in some paramagnetic phases due to a spin frustration to be present at zero magnetic field. The inverse magnetocaloric effect can also be detected slightly above continuous phase transitions following the power-law dependence | - ΔSisomin | ∝hn, where n depends basically on the ground-state spin ordering.

Anisotropic ray trace

Science.gov (United States)

Lam, Wai Sze Tiffany

anisotropic ray tracing. x. Chapter 4 presents the data reduction of the P matrix of a crystal waveplate. The diattenuation is embedded in the singular values of P. The retardance is divided into two parts: (A) The physical retardance induced by OPLs and surface interactions, and (B) the geometrical transformation induced by geometry of a ray path, which is calculated by the geometrical transform Q matrix. The Q matrix of an anisotropic intercept is derived from the generalization of s- and p-bases at the anisotropic intercept; the p basis is not confined to the plane of incidence due to the anisotropic refraction or reflection. Chapter 5 shows how the multiple P matrices associated with the eigenmodes resulting from propagation through multiple anisotropic surfaces can be combined into one P matrix when the multiple modes interfere in their overlapping regions. The resultant P matrix contains diattenuation induced at each surface interaction as well as the retardance due to ray propagation and total internal reflections. The polarization aberrations of crystal waveplates and crystal polarizers are studied in Chapter 6 and Chapter 7. A wavefront simulated by a grid of rays is traced through the anisotropic system and the resultant grid of rays is analyzed. The analysis is complicated by the ray doubling effects and the partially overlapping eigen-wavefronts propagating in various directions. The wavefront and polarization aberrations of each eigenmode can be evaluated from the electric field distributions. The overall polarization at the plane of interest or the image quality at the image plane are affected by each of these eigen-wavefronts. Isotropic materials become anisotropic due to stress, strain, or applied electric or magnetic fields. In Chapter 8, the P matrix for anisotropic materials is extended to ray tracing in stress birefringent materials which are treated as spatially varying anisotropic materials. Such simulations can predict the spatial retardance variation

Hydrostatic pressure-tuned magnetostructural transition and magnetocaloric effect in Mn-Co-Ge-In compounds

Science.gov (United States)

Liang, F. X.; Shen, F. R.; Liu, Y.; Li, J.; Qiao, K. M.; Wang, J.; Hu, F. X.; Sun, J. R.; Shen, B. G.

2018-05-01

Polycrystalline MnCoGe0.99In0.01 with magnetostructural transition temperature (Tmstr) around 330 K has been prepared by arc-melting technique, and the pressure-tuned magnetostructural transition as well as the magnetocaloric effect (MCE) has been investigated. The experimental results indicate that a pressure (P) smaller than 0.53 GPa can shift Tmstr to lower temperature at a considerable rate of 119 K/GPa with the coupled nature of magnetostructural transition unchanged. However, as P reaches 0.53 GPa, the martensitic structural transition temperature (TM) further shifts to 254 K while the magnetic transition temperature of austenitic phase (TCA) occurs at around 282 K, denoting the decoupling of magnetostructural transition. Further increasing P to 0.87 GPa leads the further shift of TM to a lower temperature while the TCA keeps nearly unchanged. Therefore, the entropy change (ΔS) of the MnCoGe0.99In0.01 under different magnetic fields can be tailored by adjusting the hydrostatic pressure.

Fracture of anisotropic materials with plastic strain-gradient effects

DEFF Research Database (Denmark)

Legarth, Brian Nyvang

2013-01-01

A unit cell is adopted to numerically analyze the effect of plastic anisotropy on frac-ture evolution in a micro-reinforced fiber-composite. The matrix material exhibit size-effects and an anisotropic strain-gradient plasticity model accounting for such size-effects through a mate-rial length scale...

Effective wavefield extrapolation in anisotropic media: Accounting for resolvable anisotropy

KAUST Repository

Alkhalifah, Tariq Ali

2014-04-30

Spectral methods provide artefact-free and generally dispersion-free wavefield extrapolation in anisotropic media. Their apparent weakness is in accessing the medium-inhomogeneity information in an efficient manner. This is usually handled through a velocity-weighted summation (interpolation) of representative constant-velocity extrapolated wavefields, with the number of these extrapolations controlled by the effective rank of the original mixed-domain operator or, more specifically, by the complexity of the velocity model. Conversely, with pseudo-spectral methods, because only the space derivatives are handled in the wavenumber domain, we obtain relatively efficient access to the inhomogeneity in isotropic media, but we often resort to weak approximations to handle the anisotropy efficiently. Utilizing perturbation theory, I isolate the contribution of anisotropy to the wavefield extrapolation process. This allows us to factorize as much of the inhomogeneity in the anisotropic parameters as possible out of the spectral implementation, yielding effectively a pseudo-spectral formulation. This is particularly true if the inhomogeneity of the dimensionless anisotropic parameters are mild compared with the velocity (i.e., factorized anisotropic media). I improve on the accuracy by using the Shanks transformation to incorporate a denominator in the expansion that predicts the higher-order omitted terms; thus, we deal with fewer terms for a high level of accuracy. In fact, when we use this new separation-based implementation, the anisotropy correction to the extrapolation can be applied separately as a residual operation, which provides a tool for anisotropic parameter sensitivity analysis. The accuracy of the approximation is high, as demonstrated in a complex tilted transversely isotropic model. © 2014 European Association of Geoscientists & Engineers.

Effective wavefield extrapolation in anisotropic media: Accounting for resolvable anisotropy

KAUST Repository

Alkhalifah, Tariq Ali

2014-01-01

Spectral methods provide artefact-free and generally dispersion-free wavefield extrapolation in anisotropic media. Their apparent weakness is in accessing the medium-inhomogeneity information in an efficient manner. This is usually handled through a velocity-weighted summation (interpolation) of representative constant-velocity extrapolated wavefields, with the number of these extrapolations controlled by the effective rank of the original mixed-domain operator or, more specifically, by the complexity of the velocity model. Conversely, with pseudo-spectral methods, because only the space derivatives are handled in the wavenumber domain, we obtain relatively efficient access to the inhomogeneity in isotropic media, but we often resort to weak approximations to handle the anisotropy efficiently. Utilizing perturbation theory, I isolate the contribution of anisotropy to the wavefield extrapolation process. This allows us to factorize as much of the inhomogeneity in the anisotropic parameters as possible out of the spectral implementation, yielding effectively a pseudo-spectral formulation. This is particularly true if the inhomogeneity of the dimensionless anisotropic parameters are mild compared with the velocity (i.e., factorized anisotropic media). I improve on the accuracy by using the Shanks transformation to incorporate a denominator in the expansion that predicts the higher-order omitted terms; thus, we deal with fewer terms for a high level of accuracy. In fact, when we use this new separation-based implementation, the anisotropy correction to the extrapolation can be applied separately as a residual operation, which provides a tool for anisotropic parameter sensitivity analysis. The accuracy of the approximation is high, as demonstrated in a complex tilted transversely isotropic model. © 2014 European Association of Geoscientists & Engineers.

Influence of Dy addition on the magnetocaloric effect of La0.67Ca0.33Mn0.9V0.1O3 ceramics

International Nuclear Information System (INIS)

Nisha, P.; Savitha Pillai, S.; Suresh, K.G.; Raama Varma, Manoj

2012-01-01

The influence of partial substitution of La by Dy on the magnetocaloric response of (La 1-x Dy x ) 0.67 Ca 0.33 Mn 0.9 V 0.1 O 3 , where x=0.03, 0.15 and 0.25 is studied. Rietveld refinement of X-ray diffraction pattern using GSAS method shows that the compounds adopt the orthorhombic structure with Pnma space group. The systematic change in lattice parameters and magnetic phase transition indicates the substitution effect of Dy. From the magnetization isotherms at different temperatures, magnetic entropy change close to their respective transition temperatures (T C ) has been evaluated. The maximum value of entropy change near T C is found to be about 4.8 J/kg K at 187.5 K for LCMVDy 0.03 , 2.45 J/kg K at 107.5 K for LCMVDy 0.15 and 2.15 J/kg K at 92.5 K for LCMVDy 0.25 at 4 T. Dy addition produces a reduction in T C and in magnitude of the magnetic entropy change. Even though the entropy change decreases with increasing Dy substitution the refrigerant temperature range, ΔT, is found to be 10 K for LCMVDy 0.03 , 31 K for LCMVDy 0.15 and 35 K for LCMVDy 0.25 compounds [90%] at 4 T. The field dependence of the magnetic entropy change is also analyzed showing the power law dependence, ΔS M ∞H n where n=0.75(2) for LCMVDy 0.03 , n=0.80(4) for LCMVDy 0.15 and n=0.92(8) for LCMVDy 0.25 compounds at their respective transition temperatures. The relative cooling power and its field dependance are also analyzed. - Highlights: → Studied magnetocaloric response of Dy substituted solid state synthesized LCMVO. → Studied the field dependence of the magnetic entropy change (ΔS M ∞H n ). → Studied the field dependence of Relative cooling power (RCP∞H 1+1/δ ). → Considerably large magnetocaloric effect and moderate relative cooling power.

Gd{sub 90}Co{sub 2.5}Fe{sub 7.5} alloy displaying enhanced magnetocaloric properties

Energy Technology Data Exchange (ETDEWEB)

Provenzano, V., E-mail: virgil12@nist.gov [Materials Science and Engineering Division, NIST, Gaithersburg, MD 20899-8552 (United States); Shull, R.D., E-mail: robert.shull@nist.gov [Materials Science and Engineering Division, NIST, Gaithersburg, MD 20899-8552 (United States); Kletetschka, G., E-mail: kletetschka@gmail.com [Faculty of Science, Charles University, Prague 12843 (Czech Republic); Institute of Geology, Academy of Science of the Czech Republic, v.v.i., Prague 16500 (Czech Republic); Stutzman, P.E., E-mail: paul.stutzman@nist.gov [Materials and Structural Systems Division, NIST, Gaithersburg, MD 20899-861 (United States)

2015-02-15

Highlights: • The Gd{sub 90}Co{sub 2.5}Fe{sub 7.5} alloy displays superior magnetocaloric properties than Gd. • Alloy’s superior properties at relatively low field values: 400, 800 kA/m (0.5, 1 T). • We proposed two possible mechanisms for the Gd-based alloy enhanced properties. • We indicated a pathway for further improving the alloy magnetocaloric properties. - Abstract: We report on the discovery of a new Gd{sub 90}Co{sub 2.5}Fe{sub 7.5} alloy exhibiting superior magnetocaloric properties compared to those of gadolinium. We present magnetically-derived entropy change, ΔS{sub M}, computed from magnetic data, and thermally-derived temperature change, ΔT{sub ad}, obtained from direct thermal measurements together with their respective MCE peaks for the alloy and gadolinium. The MCE peaks of the alloy are taller and broader than the corresponding MCE peaks of gadolinium. Correspondingly, the refrigeration capacity (RC) values of the alloy computed from magnetic and thermal MCEs for field changes, ΔH, of 400 kA/m (0.5 T) and 800 kA/m (1 T) are about 20% larger than those of gadolinium. Two possible mechanisms are proposed to account for the improved magnetocaloric properties of gadolinium alloyed with small amounts of Co and Fe, thereby pointing out a different methodology to use in the search for improved low field magnetic refrigerants.

The Effective Coherence Length in Anisotropic Superconductors

International Nuclear Information System (INIS)

Polturak, E.; Koren, G.; Nesher, O

1999-01-01

If electrons are transmitted from a normal conductor(N) into a superconductor(S), common wisdom has it that the electrons are converted into Cooper pairs within a coherence length from the interface. This is true in conventional superconductors with an isotropic order parameter. We have established experimentally that the situation is rather different in high Tc superconductors having an anisotropic order parameter. We used epitaxial thin film S/N bilayers having different interface orientations in order to inject carriers from S into N along different directions. The distance to which these carriers penetrate were determined through their effect on the Tc of the bilayers. We found that the effective coherence length is 20A only along the a or b directions, while in other directions we find a length of 250dr20A out of plane, and an even larger value for in-plane, off high symmetry directions. These observations can be explained using the Blonder-Tinkham-Klapwijk model adapted to anisotropic superconductivity. Several implications of our results on outstanding problems with high Tc junctions will be discussed

Magnetic, transport and magnetocaloric properties in the Laves phase intermetallic Ho (Co1−xAlx)2 compounds

International Nuclear Information System (INIS)

Ivanova, T.I.; Nikitin, S.A.; Tskhadadze, G.A.; Koshkid’ko, Yu.S.; Suski, W.; Iwasieczko, W.; Badurski, D.

2014-01-01

Highlights: • The Al influence on magnetic properties of the Ho (Co 1-x Al x ) 2 compounds is analyzed. • The first-order magnetic transition appears in sample with Al concentrations x ≤ 0.06. • The MCE and Curie temperature TC demonstrate complex Al concentration dependences. • The magnetoresistance for sample with Al concentration x = 0.06 (58%) is maximum. • High magnetic fields changes the Curie temperature T c of the Ho (Co 1−x Al x ) 2 compounds. - Abstract: The magnetization, magnetoresistivity and magnetocaloric effect (MCE) of the Ho (Co 1−x Al x ) 2 Laves phase intermetallic compounds for x ⩽ 0.2 have been investigated. Complex measurements have been carried out in order to determine the influence of substitution in the Co sublattice by Al on the Co moment, type of the magnetic transition and related properties of these compounds. A comparative analysis of the magnetic, transport and magnetocaloric properties of Ho (Co 1−x Al x ) 2 alloys under various Al concentration is represented. Substitutions at the Co site by Al are found to result in the appearance of itinerant electron metamagnetism (IEM) at the small Al concentrations and in positive magnetovolume effect, leading to an initial increase in the ordering temperature; on the other hand the magnetic phase transition temperature as well as ΔT (MCE) do not depend in direct way on the Al concentration. The 16% increase of magnetocaloric effect for the alloy with x = 0.02 is detected in relation to maternal HoCo 2 . A giant value of magnetoresistivity (58%) is observed for the alloy with the same Al concentration

Effect of B-doping on the structural, magnetotransport and magnetocaloric properties of La0.67Ca0.33MnO3 compounds

International Nuclear Information System (INIS)

Kolat, V.S.; Gencer, H.; Gunes, M.; Atalay, S.

2007-01-01

In this study, the effect of Mn site substitution of B on the structural, electrical and magnetocaloric properties of manganites was investigated. Polycrystalline manganites with the chemical composition La 0.67 Ca 0.33 Mn 1-x B x O 3 (x = 0, 0.1, 0.2 and 0.3) were prepared by the standard solid-state process. It was found that the magnetisation, the Curie temperature and the maximum value of the magnetic entropy change |ΔS m | decrease with increasing concentration of B

Efficient Wavefield Extrapolation In Anisotropic Media

KAUST Repository

Alkhalifah, Tariq; Ma, Xuxin; Waheed, Umair bin; Zuberi, Mohammad Akbar Hosain

2014-01-01

Various examples are provided for wavefield extrapolation in anisotropic media. In one example, among others, a method includes determining an effective isotropic velocity model and extrapolating an equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. The effective isotropic velocity model can be based upon a kinematic geometrical representation of an anisotropic, poroelastic or viscoelastic wavefield. Extrapolating the equivalent propagation can use isotopic, acoustic or elastic operators based upon the determined effective isotropic velocity model. In another example, non-transitory computer readable medium stores an application that, when executed by processing circuitry, causes the processing circuitry to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. In another example, a system includes processing circuitry and an application configured to cause the system to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield.

Efficient Wavefield Extrapolation In Anisotropic Media

KAUST Repository

Alkhalifah, Tariq

2014-07-03

Various examples are provided for wavefield extrapolation in anisotropic media. In one example, among others, a method includes determining an effective isotropic velocity model and extrapolating an equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. The effective isotropic velocity model can be based upon a kinematic geometrical representation of an anisotropic, poroelastic or viscoelastic wavefield. Extrapolating the equivalent propagation can use isotopic, acoustic or elastic operators based upon the determined effective isotropic velocity model. In another example, non-transitory computer readable medium stores an application that, when executed by processing circuitry, causes the processing circuitry to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield. In another example, a system includes processing circuitry and an application configured to cause the system to determine the effective isotropic velocity model and extrapolate the equivalent propagation of an anisotropic, poroelastic or viscoelastic wavefield.

Calculations of the magnetic entropy change in amorphous through a microscopic anisotropic model: Applications to Dy{sub 70}Zr{sub 30} and DyCo{sub 3.4} alloys

Energy Technology Data Exchange (ETDEWEB)

Ranke, P. J. von, E-mail: von.ranke@uol.com.br; Nóbrega, E. P.; Ribeiro, P. O.; Alvarenga, T. S. T.; Lopes, P. H. O.; Sousa, V. S. R. de; Oliveira, N. A. de [Instituto de Física, Universidade do Estado do Rio de Janeiro—UERJ, Rua São Francisco Xavier, 524, 20550-013 Rio de Janeiro (Brazil); Caldas, A. [Sociedade Unificada de Ensino Superior e Cultura, SUESC, 20211-351 Rio de Janeiro (Brazil); Alho, B. P. [Instituto de Aplicação Fernando Rodrigues da Silveira, Universidade do Estado do Rio de Janeiro, Rua Santa Alexandrina, 288, 20260-232 Rio de Janeiro (Brazil); Carvalho, G. [Laboratório Nacional de Luz Sincroton—LNLS, 13083-970 Campinas, São Paulo (Brazil); Magnus, A.

2014-10-14

We report theoretical investigations on the magnetocaloric effect, described by the magnetic entropy change in rare earth—transition metal amorphous systems. The model includes the local anisotropy on the rare earth ions in Harris-Plischke-Zuckermann assumptions. The transition metals ions are treated in terms of itinerant electron ferromagnetism and the magnetic moment of rare earth ions is coupled to the polarized d-band by a local exchange interaction. The magnetocaloric effect was calculated in DyCo{sub 3.4} system, which presents amorphous sperimagnetic configuration. The calculations predict higher refrigerant capacity in the amorphous DyCo{sub 3.4} than in DyCo{sub 2} crystal, highlighting the importance of amorphous magnetocaloric materials. Our calculation of the magnetocaloric effect in Dy{sub 70}Zr{sub 30}, which presents amorphous asperomagnetic configuration, is in good agreement with the experimental result. Furthermore, magnetic entropy changes associated with crystal-amorphous configurations change are estimated.

Computational Study of Subdural Cortical Stimulation: Effects of Simulating Anisotropic Conductivity on Activation of Cortical Neurons.

Directory of Open Access Journals (Sweden)

Hyeon Seo

Full Text Available Subdural cortical stimulation (SuCS is an appealing method in the treatment of neurological disorders, and computational modeling studies of SuCS have been applied to determine the optimal design for electrotherapy. To achieve a better understanding of computational modeling on the stimulation effects of SuCS, the influence of anisotropic white matter conductivity on the activation of cortical neurons was investigated in a realistic head model. In this paper, we constructed pyramidal neuronal models (layers 3 and 5 that showed primary excitation of the corticospinal tract, and an anatomically realistic head model reflecting complex brain geometry. The anisotropic information was acquired from diffusion tensor magnetic resonance imaging (DT-MRI and then applied to the white matter at various ratios of anisotropic conductivity. First, we compared the isotropic and anisotropic models; compared to the isotropic model, the anisotropic model showed that neurons were activated in the deeper bank during cathodal stimulation and in the wider crown during anodal stimulation. Second, several popular anisotropic principles were adapted to investigate the effects of variations in anisotropic information. We observed that excitation thresholds varied with anisotropic principles, especially with anodal stimulation. Overall, incorporating anisotropic conductivity into the anatomically realistic head model is critical for accurate estimation of neuronal responses; however, caution should be used in the selection of anisotropic information.

Magnetocaloric effect in textured rare earth intermetallic compound ErNi

Directory of Open Access Journals (Sweden)

Aparna Sankar

2018-05-01

Full Text Available Melt-spun ErNi crystallizes in orthorhombic FeB-type structure (Space group Pnma, no. 62 similar to the arc-melted ErNi compound. Room temperature X-ray diffraction (XRD experiments reveal the presence of texture and preferred crystal orientation in the melt-spun ErNi. The XRD data obtained from the free surface of the melt-spun ErNi show large intensity enhancement for (1 0 2 Bragg reflection. The scanning electron microscopy image of the free surface depicts a granular microstructure with grains of ∼1 μm size. The arc-melted and the melt-spun ErNi compounds order ferromagnetically at 11 K and 10 K (TC respectively. Field dependent magnetization (M-H at 2 K shows saturation behaviour and the saturation magnetization value is 7.2 μB/f.u. for the arc-melted ErNi and 7.4 μB/f.u. for the melt-spun ErNi. The isothermal magnetic entropy change (ΔSm close to TC has been calculated from the M-H data. The maximum isothermal magnetic entropy change, -ΔSmmax, is ∼27 Jkg-1K-1 and ∼24 Jkg-1K-1 for the arc-melted and melt-spun ErNi for 50 kOe field change, near TC. The corresponding relative cooling power values are ∼440 J/kg and ∼432 J/kg respectively. Although a part of ΔSm is lost to crystalline electric field (CEF effects, the magnetocaloric effect is substantially large at 10 K, thus rendering melt-spun ErNi to be useful in low temperature magnetic refrigeration applications such as helium gas liquefaction.

Magnetocaloric effect in textured rare earth intermetallic compound ErNi

Science.gov (United States)

Sankar, Aparna; Chelvane, J. Arout; Morozkin, A. V.; Nigam, A. K.; Quezado, S.; Malik, S. K.; Nirmala, R.

2018-05-01

Melt-spun ErNi crystallizes in orthorhombic FeB-type structure (Space group Pnma, no. 62) similar to the arc-melted ErNi compound. Room temperature X-ray diffraction (XRD) experiments reveal the presence of texture and preferred crystal orientation in the melt-spun ErNi. The XRD data obtained from the free surface of the melt-spun ErNi show large intensity enhancement for (1 0 2) Bragg reflection. The scanning electron microscopy image of the free surface depicts a granular microstructure with grains of ˜1 μm size. The arc-melted and the melt-spun ErNi compounds order ferromagnetically at 11 K and 10 K (TC) respectively. Field dependent magnetization (M-H) at 2 K shows saturation behaviour and the saturation magnetization value is 7.2 μB/f.u. for the arc-melted ErNi and 7.4 μB/f.u. for the melt-spun ErNi. The isothermal magnetic entropy change (ΔSm) close to TC has been calculated from the M-H data. The maximum isothermal magnetic entropy change, -ΔSmmax, is ˜27 Jkg-1K-1 and ˜24 Jkg-1K-1 for the arc-melted and melt-spun ErNi for 50 kOe field change, near TC. The corresponding relative cooling power values are ˜440 J/kg and ˜432 J/kg respectively. Although a part of ΔSm is lost to crystalline electric field (CEF) effects, the magnetocaloric effect is substantially large at 10 K, thus rendering melt-spun ErNi to be useful in low temperature magnetic refrigeration applications such as helium gas liquefaction.

Necking of anisotropic micro-films with strain-gradient effects

DEFF Research Database (Denmark)

Legarth, Brian Nyvang

2008-01-01

Necking of stubby micro-films of aluminum is investigated numerically by considering tension of a specimen with an initial imperfection used to onset localisation. Plastic anisotropy is represented by two different yield criteria and strain-gradient effects are accounted for using the visco......-plastic finite strain model. Furthermore, the model is extended to isotropic anisotropic hardening (evolving anisotropy). For isotropic hardening plastic anisotropy affects the predicted overall nominal stress level, while the peak stress remains at an overall logarithmic strain corresponding to the hardening...... exponent. This holds true for both local and nonlocal materials. Anisotropic hardening delays the point of maximum overall nominal stress....

Efficient Modeling and Migration in Anisotropic Media Based on Prestack Exploding Reflector Model and Effective Anisotropy

KAUST Repository

Wang, Hui

2014-05-01

This thesis addresses the efficiency improvement of seismic wave modeling and migration in anisotropic media. This improvement becomes crucial in practice as the process of imaging complex geological structures of the Earth\\'s subsurface requires modeling and migration as building blocks. The challenge comes from two aspects. First, the underlying governing equations for seismic wave propagation in anisotropic media are far more complicated than that in isotropic media which demand higher computational costs to solve. Second, the usage of whole prestack seismic data still remains a burden considering its storage volume and the existing wave equation solvers. In this thesis, I develop two approaches to tackle the challenges. In the first part, I adopt the concept of prestack exploding reflector model to handle the whole prestack data and bridge the data space directly to image space in a single kernel. I formulate the extrapolation operator in a two-way fashion to remove he restriction on directions that waves propagate. I also develop a generic method for phase velocity evaluation within anisotropic media used in this extrapolation kernel. The proposed method provides a tool for generating prestack images without wavefield cross correlations. In the second part of this thesis, I approximate the anisotropic models using effective isotropic models. The wave phenomena in these effective models match that in anisotropic models both kinematically and dynamically. I obtain the effective models through equating eikonal equations and transport equations of anisotropic and isotropic models, thereby in the high frequency asymptotic approximation sense. The wavefields extrapolation costs are thus reduced using isotropic wave equation solvers while the anisotropic effects are maintained through this approach. I benchmark the two proposed methods using synthetic datasets. Tests on anisotropic Marmousi model and anisotropic BP2007 model demonstrate the applicability of my

Investigations in MnAs{sub 1−x}Sb{sub x}: Experimental validation of a new magnetocaloric composite

Energy Technology Data Exchange (ETDEWEB)

Campos, A. de, E-mail: acampos@icte.uftm.edu.br [Instituto de Ciências Tecnológicas e Exatas, Universidade Federal do Triângulo Mineiro (UFTM), 38066-200 Uberaba (Brazil); Luz, M.S. da; Campos, Adriana de [Instituto de Ciências Tecnológicas e Exatas, Universidade Federal do Triângulo Mineiro (UFTM), 38066-200 Uberaba (Brazil); Coelho, A.A.; Cardoso, L.P. [Instituto deFísica Gleb Wataghin, Universidade Estadual de Campinas (UNICAMP), 13083-970 Campinas (Brazil); Santos, A.O. dos [Centro de Ciências Sociais, Saúde e Tecnologia, Universidade Federal do Maranhão – (UFMA), 65900-000 Imperatriz, MA (Brazil); Gama, S. [Departamento de Ciências Exatas e da Terra, Universidade Federal de São Paulo (UNIFESP), Diadema, 09971-270 SP (Brazil)

2015-01-15

An overview of the magnetocaloric properties of the MnAs{sub 1−x}Sb{sub x} is presented. The temperature dependence of the isothermal magnetic entropy, ΔS{sub mag}, and the refrigerant capacity, RC, have been investigated theoretically and experimentally in a composite based on second order MnAs{sub 1−x}Sb{sub x} phases. This work demonstrates the outstanding agreement between the experimental results and the continuous curves predicted by numerical calculations, indicating that this approach can be used to design magnetic refrigerant materials with enhanced magnetocaloric response in magnetic refrigerator performing an Ericsson cycle near room temperature. - Highlights: • This is the first report showing the magnetocaloric properties of the MnAs{sub 1−x}Sb{sub x} composite. • This work demonstrates a good agreement between experimental and the predicted by numerical calculations. The results indicating that this approach can be used to design magnetic refrigerant materials.

Negative thermal expansion and magnetocaloric effect in Mn-Co-Ge-In thin films

Science.gov (United States)

Liu, Y.; Qiao, K. M.; Zuo, S. L.; Zhang, H. R.; Kuang, H.; Wang, J.; Hu, F. X.; Sun, J. R.; Shen, B. G.

2018-01-01

MnCoGe-based alloys with magnetostructural transition show giant negative thermal expansion (NTE) behavior and magnetocaloric effects (MCEs) and thus have attracted a lot of attention. However, the drawback of bad mechanical behavior in these alloys obstructs their practical applications. Here, we report the growth of Mn-Co-Ge-In films with thickness of about 45 nm on (001)-LaAlO3, (001)-SrTiO3, and (001)-Al2O3 substrates. The films grown completely overcome the breakable nature of the alloy and promote its multifunctional applications. The deposited films have a textured structure and retain first-order magnetostructural transition. NTE and MCE behaviors associated with the magnetostructural transition have been studied. The films exhibit a completely repeatable NTE around room temperature. NTE coefficient α can be continuously tuned from the ultra-low expansion (α ˜ -2.0 × 10-7/K) to α ˜ -6.56 × 10-6/K, depending on the growth and particle size of the films on different substrates. Moreover, the films exhibit magnetic entropy changes comparable to the well-known metamagnetic films. All these demonstrate potential multifunctional applications of the present films.

Finite-size effects for anisotropic bootstrap percolation : Logarithmic corrections

NARCIS (Netherlands)

van Enter, Aernout C. D.; Hulshof, Tim

In this note we analyse an anisotropic, two-dimensional bootstrap percolation model introduced by Gravner and Griffeath. We present upper and lower bounds on the finite-size effects. We discuss the similarities with the semi-oriented model introduced by Duarte.

Finite-size effects for anisotropic bootstrap percolation: logerithmic corrections

NARCIS (Netherlands)

Enter, van A.C.D.; Hulshof, T.

2007-01-01

In this note we analyse an anisotropic, two-dimensional bootstrap percolation model introduced by Gravner and Griffeath. We present upper and lower bounds on the finite-size effects. We discuss the similarities with the semi-oriented model introduced by Duarte.

The influence of quench atomic disorder on the magnetocaloric properties of Ni–Co–Mn–In alloys

International Nuclear Information System (INIS)

Singh, Sandeep; Glavatskyy, Illya; Biswas, C.

2014-01-01

Highlights: • Large magnetic entropy change (ΔS m = 11 J/Kg K) at 1.5 Tesla above 300 K is obtained. • The peak value of ΔS m is higher in disordered system. • Refrigeration capacity (RC) is unaffected by the quenched atomic disorder. - Abstract: The magnetocaloric effect in Ni–Co–Mn–In alloys is studied at low magnetic field, across the first order magnetostructural transition. The Co doping at Ni site induces the large magnetic entropy change (ΔS m ) above room temperature. The large ΔS m of 11 J/Kg K has been observed for disordered Ni 1.81 Co 0.22 Mn 1.46 In 0.51 alloy at 337 K at an applied field of 1.5 Tesla. The influence of quench atomic disorder on the magnetocaloric properties of Ni–Co–Mn–In alloys has been studied. The atomic disorder significantly increases the peak value of ΔS m and decreases the peak width. The refrigeration capacity (RC) is almost unchanged with atomic disorder

Influence of manganite powder grain size and Ag-particle coating on the magnetocaloric effect and the active magnetic regenerator performance

DEFF Research Database (Denmark)

Turcaud, J.A.; Neves Bez, Henrique; Ruiz-Trejo, E.

2015-01-01

The magnetocaloric performance of La0.67Ca0.27Sr0.06Mn1.05O3 is investigated as a function of the powder grain size and also as a function of decoration of grains with highly conductive silver particulates as a coating layer. We demonstrate that the thermal and electrical conductivities can be si...

Magnetism and large magnetocaloric effect in HoFe{sub 2-x}Al{sub x}

Energy Technology Data Exchange (ETDEWEB)

Mican, S., E-mail: sever.mican@ubbcluj.ro [Babes-Bolyai University Cluj-Napoca, RO-400084 Cluj-Napoca (Romania); Benea, D., E-mail: diana.benea@phys.ubbcluj.ro [Babes-Bolyai University Cluj-Napoca, RO-400084 Cluj-Napoca (Romania); Tetean, R., E-mail: romulus.tetean@phys.ubbcluj.ro [Babes-Bolyai University Cluj-Napoca, RO-400084 Cluj-Napoca (Romania)

2013-02-05

Highlights: Black-Right-Pointing-Pointer Structural, magnetic and magnetocaloric properties of HoFe{sub 2-x}Al{sub x} compounds are reported. Black-Right-Pointing-Pointer Electronic structure calculations show a good agreement between theory and experiment. Black-Right-Pointing-Pointer Magnetic transitions close to room temperature for the Fe-rich samples. Black-Right-Pointing-Pointer High values of the relative cooling power for all of the investigated samples. Black-Right-Pointing-Pointer No hysteresis losses in applied fields of up to 4 T. - Abstract: The structural, magnetic and magnetocaloric properties of several HoFe{sub 2-x}Al{sub x} compounds were investigated. The compounds in the Fe-rich region (0.36 Less-Than-Or-Slanted-Equal-To x Less-Than-Or-Slanted-Equal-To 0.4) crystallize in the cubic MgCu{sub 2} (C15) structure, while for the ones in the intermediate region (0.75 Less-Than-Or-Slanted-Equal-To x Less-Than-Or-Slanted-Equal-To 1.125) the hexagonal MgZn{sub 2} (C14) structure was observed. Electronic structure calculations were performed, showing a good agreement between theory and experiment. The Curie temperatures were found to decrease with Al content. For the Fe-rich compounds, these are close to room temperature, while for the compounds in the intermediate region, transition temperatures are well below 300 K. No magnetic hysteresis was found around the Curie temperature for applied magnetic fields of up to 4 T. All of the investigated compounds undergo a second-order magnetic phase transition at the Curie temperature. A maximum magnetic entropy change value of 7.6 J/kg K was obtained for the sample with x = 1.125, all of the samples displaying rather large RCP values. The possibility of incorporating these materials in magnetic refrigeration devices is discussed.

Magnetocaloric properties of Nd.sub.5./sub.Si.sub.1.45./sub.Ge.sub.2.55./sub. compound under high hydrostatic pressure

Czech Academy of Sciences Publication Activity Database

Skorokhod, Yuriy; Arnold, Zdeněk; Kamarád, Jiří; Morellon, L.; Magen, C.

2006-01-01

Roč. 26, č. 4 (2006), s. 495-498 ISSN 0895-7959 R&D Projects: GA ČR(CZ) GA106/06/0368 Institutional research plan: CEZ:AV0Z10100521 Keywords : magnetocaloric effect * magnetic properties * pressure effect Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.228, year: 2006

Very large refrigerant capacity at room temperature with reproducible magnetocaloric effect in Fe0.975Ni0.025Rh

International Nuclear Information System (INIS)

Manekar, Meghmalhar; Roy, S B

2011-01-01

We present the results of magnetocaloric effect (MCE) measurements on Fe 0.975 Ni 0.025 Rh. The MCE is estimated using both the isothermal field-dependent magnetization and the temperature-dependent magnetization in constant magnetic fields. We find a very large effective refrigerant capacity of nearly 492.8 J kg -1 , with the hot end at about 307 K, which is reproducible over many field cycles. We compare this refrigerant capacity with those of two well known systems, namely Gd 5 Ge 1.9 Si 2 Fe 0.1 and MnFeP 0.45 As 0.55 , which show a large MCE near room temperature, and also with our earlier results on the parent Fe-Rh alloy. The large effective refrigerant capacity in our sample is one of the largest achieved yet at room temperature with a significant improvement over the parent Fe-Rh system. (fast track communication)

Magnetic properties and magnetocaloric effects in Mn1.2Fe0.8P1-xGex compounds

International Nuclear Information System (INIS)

Ou, Z Q; Wang, G F; Lin Song; Tegus, O; Brueck, E; Buschow, K H J

2006-01-01

We have studied the magnetic properties and magnetocaloric effects in the Mn 1.2 Fe 0.8 P 1-x Ge x compounds with x = 0.2, 0.22, 0.3, 0.4 and 0.5. X-ray diffraction patterns show that the Mn 1.2 Fe 0.8 P 1-x Ge x compounds crystallize in the hexagonal Fe 2 P-type crystal structure. The magnetic moments of the Mn 1.2 Fe 0.8 P 1-x Ge x compounds measured at 5 K and 5 T increase with increasing Ge content. The Curie temperature increases strongly and the magnetic entropy change has a maximum around 233 K for the compound with x = 0.22, which is about 19 and 31 J kg -1 K -1 for a field change of 2 and 5 T, respectively

Magnetocaloric effects in RTX intermetallic compounds (R = Gd–Tm, T = Fe–Cu and Pd, X = Al and Si)

International Nuclear Information System (INIS)

Zhang Hu; Shen Bao-Gen

2015-01-01

The magnetocaloric effect (MCE) of RTSi and RT Al systems with R = Gd–Tm, T = Fe–Cu and Pd, which have been widely investigated in recent years, is reviewed. It is found that these RTX compounds exhibit various crystal structures and magnetic properties, which then result in different MCE. Large MCE has been observed not only in the typical ferromagnetic materials but also in the antiferromagnetic materials. The magnetic properties have been studied in detail to discuss the physical mechanism of large MCE in RTX compounds. Particularly, some RTX compounds such as ErFeSi, HoCuSi, HoCuAl exhibit large reversible MCE under low magnetic field change, which suggests that these compounds could be promising materials for magnetic refrigeration in a low temperature range. (topical review)

Effect of Fe substitution on magnetocaloric effect in La0.7Sr0.3Mn1-xFexO3 (0.05≤x≤0.20)

International Nuclear Information System (INIS)

Barik, S.K.; Krishnamoorthi, C.; Mahendiran, R.

2011-01-01

We have studied the effect of Fe substitution on magnetic and magnetocaloric properties in La 0.7 Sr 0.3 Mn 1-x Fe x O 3 (x=0.05, 0.07, 0.10, 0.15, and 0.20) over a wide temperature range (T=10-400 K). It is shown that substitution by Fe gradually decreases the ferromagnetic Curie temperature (T C ) and saturation magnetization up to x=0.15 but a dramatic change occurs for x=0.2. The x=0.2 sample can be considered as a phase separated compound in which both short-range ordered ferromagnetic and antiferromagnetic phases coexist. The magnetic entropy change (-ΔS m ) was estimated from isothermal magnetization curves and it decreases with increase of Fe content from 4.4 J kg -1 K -1 at 343 K (x=0.05) to 1.3 J kg -1 K -1 at 105 K (x=0.2), under ΔH=5 T. The La 0.7 Sr 0.3 Mn 0.93 Fe 0.07 O 3 sample shows negligible hysteresis loss, operating temperature range over 60 K around room temperature with refrigerant capacity of 225 J kg -1 , and magnetic entropy of 4 J kg -1 K -1 which will be an interesting compound for application in room temperature refrigeration. - Research highlights: → We report magnetocaloric effect in La 0.7 Sr 0.3 Mn 1-x Fe x O 3 (x=0-0.2). → Magnetic entropy change (ΔS m ) decreases with increasing x. → A large ΔS m and refrigeration capacity are found around 300 K in x=0.07.

Magnetocaloric effect in the La0.8Ce0.2Fe11.4-xCoxSi1.6 compounds

International Nuclear Information System (INIS)

Wang, G.F.; Song, L.; Li, F.A.; Ou, Z.Q.; Tegus, O.; Brueck, E.; Buschow, K.H.J.

2009-01-01

The effects of substitution of Co for Fe on the magnetic and magnetocaloric properties of La 0.8 Ce 0.2 Fe 11.4-x Co x Si 1.6 (0, 0.2, 0.4, 0.6, 0.8 and 1.0) compounds have been investigated. X-ray diffraction shows that all compounds crystallize in the NaZn 13 -type structure. Magnetic measurements show that the Curie temperature (T C ) can be tuned between 184 and 294 K by changing the Co content from 0 to 1. A field-induced methamagnetic transition occurs in samples with x=0, 0.2 and 0.4. The magnetic entropy changes of the compounds have been determined from the isothermal magnetization measurements by using the Maxwell relation.

Simple types of anisotropic inflation

International Nuclear Information System (INIS)

Barrow, John D.; Hervik, Sigbjoern

2010-01-01

We display some simple cosmological solutions of gravity theories with quadratic Ricci curvature terms added to the Einstein-Hilbert Lagrangian which exhibit anisotropic inflation. The Hubble expansion rates are constant and unequal in three orthogonal directions. We describe the evolution of the simplest of these homogeneous and anisotropic cosmological models from its natural initial state and evaluate the deviations they will create from statistical isotropy in the fluctuations produced during a period of anisotropic inflation. The anisotropic inflation is not a late-time attractor in these models but the rate of approach to a final isotropic de Sitter state is slow and is conducive to the creation of observable anisotropic statistical effects in the microwave background. The statistical anisotropy would not be scale invariant and the level of statistical anisotropy will grow with scale.

Pressure-induced three-dimensional ferromagnetic correlations in the giant magnetocaloric compound Gd.sub.5./sub.Ge.sub.4./sub..

Czech Academy of Sciences Publication Activity Database

Magen, C.; Arnold, Zdeněk; Morellon, L.; Skorokhod, Yuriy; Algarabel, P. A.; Ibarra, M. R.; Kamarád, Jiří

2003-01-01

Roč. 91, č. 20 (2003), s. 207202-1 - 207202-4 ISSN 0031-9007 R&D Projects: GA ČR GA106/02/0943 Grant - others:CICYT(ES) MAT2000-1756 Institutional research plan: CEZ:AV0Z1010914 Keywords : magneto-caloric compounds * pressure effect * magnetism Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 7.035, year: 2003

Magnetocaloric effect in In doped YbMnO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Sattibabu, Bhumireddi, E-mail: bsb.satti@gmail.com [School of Engineering Sciences and Technology, University of Hyderabad, Hyderabad 500046 (India); Department of Electronics and Physics, Institute of Science, GITAM University, Visakhapatnam 530045 (India); Bhatnagar, A.K., E-mail: anilb42@gmail.com [School of Physics, University of Hyderabad, Hyderabad 500046 (India); Vinod, K.; Mani, Awadhesh [Condensed Matter Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India)

2017-06-01

Magnetic and magnetocaloric (MCE) properties of Yb{sub 0.9}In{sub 0.1}MnO{sub 3} and Yb{sub 0.8}In{sub 0.2}MnO{sub 3} polycrystalline samples are presented in this paper. Isothermal magnetization measurements reveal a field induced magnetic transition. Magnetic entropy change of 2.34±0.35 J/mole-K for Yb{sub 0.9}In{sub 0.1}MnO{sub 3} and 2.64±0.38 J/mole-K for Yb{sub 0.8}In{sub 0.2}MnO{sub 3} field change ΔH =10 KOe is observed around the ferromagnetic ordering temperature of Yb{sup 3+}. Values of relative cooling power for the same field change are found to be 38.03±9 J /mol, and 40.90±10 J/mol for Yb{sub 0.9}In{sub 0.1}MnO{sub 3} and Yb{sub 0.8}In{sub 0.2}MnO{sub 3}, respectively. These values suggest In doped YbMnO{sub 3} may be a potential candidate for magnetic refrigerant at low temperatures.

Iron particle and anisotropic effects on mechanical properties of magneto-sensitive elastomers

Science.gov (United States)

Kumar, Vineet; Lee, Dong-Joo

2017-11-01

Rubber specimens were prepared by mixing micron-sized iron particles dispersed in room-temperature-vulcanized (RTV) silicone rubber by solution mixing. The possible correlations of the particle volume, size, and distribution with the mechanical properties of the specimens were examined. An isotropic mechanical test shows that at 60 phr, the elastic modulus was 3.29 MPa (electrolyte), 2.92 MPa (carbonyl), and 2.61 MPa (hybrid). The anisotropic effect was examined by curing the specimen under magnetic fields of 0.5-2.0 T at 90° relative to the applied strain. The measurements show anisotropic effects of 11% (carbonyl), 9% (electrolyte), and 6% (hybrid) at 40 phr and 1 T. At 80 phr, the polymer-filler compatibility factor (c-factor) was estimated using the Pythagorean theorem as 0.53 (regular) and 0.73 (anisotropic studies). The improved features could be useful in applications such as controlled damping, vibrational absorption, or automotive bushings.

Analytical theory and method for longitudinal magneto-optical Kerr effect of optically anisotropic magnetic film

Energy Technology Data Exchange (ETDEWEB)

Wang, Xiao, E-mail: sps_wangx@ujn.edu.cn [School of Physics and Technology, University of Jinan, Jinan 250022 (China); School of Material Science and Engineering, University of Jinan, Jinan 250022 (China); Lian, Jie [School of Information Science and Engineering, Shandong University, Jinan 250100 (China); Li, Ping; Xu, XiJin [School of Physics and Technology, University of Jinan, Jinan 250022 (China); Li, MengMeng [School of Information Science and Engineering, Shandong University, Jinan 250100 (China)

2017-01-15

The Fresnel equations are solved to analyze the reflection and propagation properties of the ordinary and extraordinary light of the optically anisotropic magnetic film. Using the boundary and propagation matrix, the longitudinal magneto-optical Kerr rotation expression is derived. After that, simulations are performed on optically anisotropic and isotropic Co/SiO{sub 2} film. Results show that for Co material in the thin-film limit, the anisotropic Co can provide larger max rotations than the isotropic Co in the visible region. This is because that the refractive index discrepancy of optically anisotropic Co film reduces the Fresnel reflective coefficient r{sub pp,} which improves the Kerr rotation. This makes the optically anisotropic Co film more effective in magneto optical sensor design and device fabrication. - Highlights: • In this work, using the boundary matrix and media propagation matrix developed by Zak and S.D.Bader,we get the analytical solution of the magneto-optical Kerr rotation of the optical anisotropic magnetic film. • Results show that for film in the thin-film limit, the anisotropic Co can provide larger maximum rotations than the isotropic Co. • The improvement of Kerr rotation can be attributed to the refractive index discrepancy of optically anisotropic Co film which reduce the Fresnel reflective coefficient rpp.

Inapplicability of the Maxwell relation for the quantification of caloric effects in anisotropic ferroic materials

Czech Academy of Sciences Publication Activity Database

Niemann, R.; Heczko, Oleg; Schultz, L.; Fähler, S.

2014-01-01

Roč. 37, SI (2014), 281-288 ISSN 0140-7007 R&D Projects: GA ČR(CZ) GAP107/11/0391 Institutional support: RVO:68378271 Keywords : magnetocaloric * shape memory alloy s * multiferroic * Ni-Mn-Ga * Maxwell relation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.241, year: 2014

Experimental study of the anisotropic magneto-Seebeck effect in (Ga,Mn)As thin films

Energy Technology Data Exchange (ETDEWEB)

Althammer, Matthias; Krupp, Alexander T.; Brenninger, Thomas; Venkateshvaran, Deepak; Opel, Matthias; Gross, Rudolf; Goennenwein, Sebastian T.B. [Walther-Meissner-Institut, Bayerische Akademie der Wissenschaften, Garching (Germany); Dreher, Lukas [Walter Schottky Institut, Technische Universitaet Muenchen, Garching (Germany); Schoch, Wladimir; Limmer, Wolfgang [Abteilung Halbleiterphysik, Universitaet Ulm, Ulm (Germany)

2011-07-01

In analogy to anisotropic magnetoresistance (AMR), the thermopower of ferromagnetic materials also characteristically depends on the orientation of the magnetization vector. This anisotropic magneto-thermopower - or anisotropic magneto-Seebeck effect (AMS) - has only scarcely been studied to date. Taking the ferromagnetic semiconductor (Ga,Mn)As with its large magneto-resistive effects as a prototype example, we have measured the evolution of both the AMR and the AMS effects at liquid He temperatures as a function of the orientation of a magnetic field applied in the (Ga,Mn)As film plane, for different, fixed magnetic field magnitudes. Our data show that the AMS effect can be adequately modeled only if the symmetry of the (Ga,Mn)As crystal is explicitly taken into account. We quantitatively compare our AMR and AMS measurements with corresponding model calculations, and address the validity of the Mott relations linking the magneto-resistance and the magneto-Seebeck coefficients.

Theoretical investigations on magnetocaloric effect in Er{sub 1−y}Tb{sub y}Al{sub 2} series

Energy Technology Data Exchange (ETDEWEB)

Ribeiro, P.O., E-mail: paula.ribeiro@gmail.com [Instituto de Física, Universidade do Estado do Rio de Janeiro – UERJ, Rua São Francisco Xavier, 524, 20550-013 RJ (Brazil); Alho, B.P.; Alvarenga, T.S.T.; Nóbrega, E.P.; Sousa, V.S.R. de [Instituto de Física, Universidade do Estado do Rio de Janeiro – UERJ, Rua São Francisco Xavier, 524, 20550-013 RJ (Brazil); Carvalho, A. Magnus G. [Laboratório Nacional de Luz Síncrotron, CNPEM, 13083-970 Campinas, SP (Brazil); Caldas, A. [Sociedade Unificada de Ensino Superior e Cultura, SUESC, 20211-351 Rio de Janeiro, RJ (Brazil); Oliveira, N.A. de; Ranke, P.J. von [Instituto de Física, Universidade do Estado do Rio de Janeiro – UERJ, Rua São Francisco Xavier, 524, 20550-013 RJ (Brazil)

2015-04-01

We report on the magnetic and magnetocaloric effect calculations in rare earth Er{sub 1−y}Tb{sub y}Al{sub 2} compounds (y=0.00, 0.25, 0.5, 0.75 and 1.00). Our model Hamiltonian has contributions of the crystalline electrical field anisotropy in both Er and Tb magnetic sublattices, disorder in exchange interactions among Er–Er, Tb–Tb and Er–Tb magnetic ions and the Zeeman effect. The magnetization, the isothermal entropy change (ΔS{sub T}) and the adiabatic temperature change (ΔT{sub ad}) dependence on temperature were simulated and, compared with the experimental data available. - Highlights: • Modeling Er{sub (1−y)}Tb{sub y}Al{sub 2} intermetallic compounds. • Magnetic entropy changes in Er{sub (1−y)}Tb{sub y}Al{sub 2}. • Adiabatic temperature changes in Er{sub 0.75}Tb{sub 0.25}Al{sub 2} and Er{sub 0.65}Tb{sub 0.35}Al{sub 2} compounds.

Electromagnetic effects on cracking of anisotropic polytropes

Energy Technology Data Exchange (ETDEWEB)

Sharif, Muhammad; Sadiq, Sobia [University of the Punjab, Department of Mathematics, Lahore (Pakistan)

2016-10-15

In this paper, we study the electromagnetic effects on the stability of a spherically symmetric anisotropic fluid distribution satisfying two polytropic equations of state and construct the corresponding generalized Tolman-Oppenheimer-Volkoff equations. We apply perturbations on matter variables via the polytropic constant as well as the polytropic index and formulate the force distribution function. It is found that the compact object is stable for a feasible choice of perturbed polytropic index in the presence of charge. (orig.)

Some Aspects of Scaling and Universality in Magnetocaloric Materials

DEFF Research Database (Denmark)

Smith, Anders; Nielsen, Kaspar Kirstein; Bahl, Christian R.H.

2014-01-01

The magnetocaloric effect of a magnetic material is characterized by two quantities, the isothermal entropy change and the adiabatic temperature change, both of which are functions of temperature and applied magnetic field. We discuss the scaling properties of these quantities close to a second...... order phase transition within the context of critical scaling theory. In the critical region the isothermal entropy change will exhibit universal scaling exponents. However, this is only true close to Tc and for small fields; we show that for finite fields the scaling exponents in general become field...... dependent, even at Tc. Furthermore, the scaling exponents at finite fields are not universal: Two models with the same critical exponents can exhibit markedly different scaling behaviour even at relatively low fields. Turning to the adiabatic temperature change, we argue that it is not determined...

Dynamics of anisotropic tissue growth

Energy Technology Data Exchange (ETDEWEB)

Bittig, Thomas; Juelicher, Frank [Max Planck Institute for the Physics of Complex Systems, Noethnitzer Strasse 38, 01187 Dresden (Germany); Wartlick, Ortrud; Kicheva, Anna; Gonzalez-Gaitan, Marcos [Department of Biochemistry and Department of Molecular Biology, Geneva University, Sciences II, Quai Ernest-Ansermet 30, 1211 Geneva 4 (Switzerland)], E-mail: Marcos.Gonzalez@biochem.unige.ch, E-mail: julicher@pks.mpg.de

2008-06-15

We study the mechanics of tissue growth via cell division and cell death (apoptosis). The rearrangements of cells can on large scales and times be captured by a continuum theory which describes the tissue as an effective viscous material with active stresses generated by cell division. We study the effects of anisotropies of cell division on cell rearrangements and show that average cellular trajectories exhibit anisotropic scaling behaviors. If cell division and apoptosis balance, there is no net growth, but for anisotropic cell division the tissue undergoes spontaneous shear deformations. Our description is relevant for the study of developing tissues such as the imaginal disks of the fruit fly Drosophila melanogaster, which grow anisotropically.

Properties of magnetocaloric materials with a distribution of Curie temperatures

DEFF Research Database (Denmark)

Bahl, Christian Robert Haffenden; Bjørk, Rasmus; Smith, Anders

2012-01-01

The magnetocaloric properties of inhomogeneous ferromagnets that contain distributions of Curie temperatures are considered as a function of the width of such a distribution. Assuming a normal distribution of the Curie temperature, the average adiabatic temperature change, ΔTad, the isothermal...... of the distribution, explaining the observed mismatch of peak temperatures reported in experiments. Also, the field dependence of ΔTad and Δs is found to depend on the width of the distribution....

Crack growth resistance for anisotropic plasticity with non-normality effects

DEFF Research Database (Denmark)

Tvergaard, Viggo; Legarth, Brian Nyvang

2006-01-01

For a plastically anisotropic solid a plasticity model using a plastic flow rule with non-normality is applied to predict crack growth. The fracture process is modelled in terms of a traction–separation law specified on the crack plane. A phenomenological elastic–viscoplastic material model...... is applied, using one of two different anisotropic yield criteria to account for the plastic anisotropy, and in each case the effect of the normality flow rule is compared with the effect of non-normality. Conditions of small scale yielding are assumed, with mode I loading conditions far from the crack......-tip, and various directions of the crack plane relative to the principal axes of the anisotropy are considered. It is found that the steady-state fracture toughness is significantly reduced when the non-normality flow rule is used. Furthermore, it is shown that the predictions are quite sensitive to the value...

Thermomagnetic and magnetocaloric properties of metamagnetic Ni-Mn-In-Co Heusler alloy in magnetic fields up to 140 kOe

Directory of Open Access Journals (Sweden)

Kamantsev Alexander

2014-07-01

Full Text Available High cooling power of magnetocaloric refrigeration can be achieved only at large amounts of heat, which can be transferred in one cycle from cold end hot end at quasi-isothermal conditions. The simple and robust experimental method of direct measuring of the transferred heat of materials with magnetocaloric effect (MCE in thermal contact with massive copper block with definite heat capacity in quasi-isothermal regime was proposed. The vacuum calorimeter for the specific transferred heat ΔQ and adiabatic temperature change ΔT measurements of MCE materials in the fields of Bitter coil magnet up to H = 140 kOe was designed and tested on samples of Ni43Mn37.9In12.1Co7 Heusler alloy with inverse MCE in the vicinity of meta-magnetostructural phase transition (PT. It was found, that the magnetic field H = 80 kOe produces complete PT from martensite to austenite with ΔQ = - 1600 J/kg at initial temperature 273 K.

Influence of magnetic field, chemical pressure and hydrostatic pressure on the structural and magnetocaloric properties of the Mn-Ni-Ge system

Science.gov (United States)

Taubel, Andreas; Gottschall, Tino; Fries, Maximilian; Faske, Tom; Skokov, Konstantin P.; Gutfleisch, Oliver

2017-11-01

The magnetic, structural and thermomagnetic properties of the MM’X material system of MnNiGe are evaluated with respect to their utilization in magnetocaloric refrigeration. The effects of separate and simultaneous substitution of Fe for Mn and Si on the Ge site are analysed in detail to highlight the benefits of the isostructural alloying method. A large range of compounds with precisely tunable structural and magnetic properties and the tuning of the phase transition by chemical pressure are compared to the effect of hydrostatic pressure on the martensitic transition. We obtained very large isothermal entropy changes Δ S_iso of up to -37.8 J kg-1 K-1 based on magnetic measurements for (Mn,Fe)NiGe in moderate fields of 2 T. The enhanced magnetocaloric properties for transitions around room temperature are demonstrated for samples with reduced Ge, a resource critical element. An adiabatic temperature change of 1.3 K in a magnetic field change of 1.93 T is observed upon direct measurement for a sample with Fe and Si substitution. However, the high volume change of 2.8% results in an embrittlement of large particles into several smaller fragments and leads to a sensitivity of the magnetocaloric properties towards sample shape and size. On the other hand, this large volume change enables to induce the phase transition with a large shift of the transition temperature by application of hydrostatic pressure (72 K GPa-1 ). Thus, the effect of 1.88 GPa is equivalent to a substitution of 10% Fe for Mn and can act as an additional stimulus to induce the phase transition and support the low magnetic field dependence of the phase transition temperature for multicaloric applications.

Table-like magnetocaloric effect of Fe88−xNdxCr8B4 composite materials

International Nuclear Information System (INIS)

Lai, J.W.; Zheng, Z.G.; Zhong, X.C.; Franco, V.; Montemayor, R.; Liu, Z.W.; Zeng, D.C.

2015-01-01

The narrow working temperature range due to the sharp magnetic entropy change |ΔS M | peak and large thermal or magnetic hysteresis restricts the practical application of magnetocaloric materials. In this work, the table-like magnetocaloric effect (MCE) was obtained in the multilayer composite of Fe 88−x Nd x Cr 8 B 4 alloys with various Nd substitutions for Fe (x=5, 8, 10, 12, and 15), which were prepared by arc-melting followed by melt-spinning. The substation of Nd was found to enhance the glass-forming ability. For the alloys with Nd substitution from 5 at% to 15 at%, the Curie temperature (T C ) ranged from 322 K to 350 K and the peak value of |ΔS M | remained almost constant, 3.4–3.5 J/(kg K) under an applied field of 0–5 T. The composite with various Nd contents was prepared by stocking the ribbons layer by layer. The |ΔS M | of the composite approached a nearly constant value of ∼3.2 J/(kg K) in a field change of 0–5 T in a wide temperature span over 40 K, resulting in large refrigerant capacity value of >408 J/kg. This |ΔS M | value was much larger than the previous reported Fe-based amorphous composite Fe 78−x Ce x Si 4 Nb 5 B 12 Cu 1 . This composite can be used as the working material in the Ericsson-cycle magnetic regenerative refrigerator around room temperature. - Highlights: • The T C ranges from 322 K to 350 K when increasing Nd substitution from 5 to 15 at%. • |ΔS M | remains relatively constant, about 3.4–3.5 J/(kg K) under H=0–5 T. • RC decreases from 93 to 78 J/kg in a field change of 1.5 T when Nd increasing. • Table-like MCE ,|ΔS M | ~3.2J/kg K under 0–5 T, appeared in the composite. • A wide working temperature range (40 K) and enhanced RC (>408J/kg) were obtained in the composite

Effective orthorhombic anisotropic models for wavefield extrapolation

KAUST Repository

Ibanez-Jacome, W.

2014-07-18

Wavefield extrapolation in orthorhombic anisotropic media incorporates complicated but realistic models to reproduce wave propagation phenomena in the Earth\\'s subsurface. Compared with the representations used for simpler symmetries, such as transversely isotropic or isotropic, orthorhombic models require an extended and more elaborated formulation that also involves more expensive computational processes. The acoustic assumption yields more efficient description of the orthorhombic wave equation that also provides a simplified representation for the orthorhombic dispersion relation. However, such representation is hampered by the sixth-order nature of the acoustic wave equation, as it also encompasses the contribution of shear waves. To reduce the computational cost of wavefield extrapolation in such media, we generate effective isotropic inhomogeneous models that are capable of reproducing the firstarrival kinematic aspects of the orthorhombic wavefield. First, in order to compute traveltimes in vertical orthorhombic media, we develop a stable, efficient and accurate algorithm based on the fast marching method. The derived orthorhombic acoustic dispersion relation, unlike the isotropic or transversely isotropic ones, is represented by a sixth order polynomial equation with the fastest solution corresponding to outgoing P waves in acoustic media. The effective velocity models are then computed by evaluating the traveltime gradients of the orthorhombic traveltime solution, and using them to explicitly evaluate the corresponding inhomogeneous isotropic velocity field. The inverted effective velocity fields are source dependent and produce equivalent first-arrival kinematic descriptions of wave propagation in orthorhombic media. We extrapolate wavefields in these isotropic effective velocity models using the more efficient isotropic operator, and the results compare well, especially kinematically, with those obtained from the more expensive anisotropic extrapolator.

Effective orthorhombic anisotropic models for wavefield extrapolation

KAUST Repository

Ibanez-Jacome, W.; Alkhalifah, Tariq Ali; Waheed, Umair bin

2014-01-01

Wavefield extrapolation in orthorhombic anisotropic media incorporates complicated but realistic models to reproduce wave propagation phenomena in the Earth's subsurface. Compared with the representations used for simpler symmetries, such as transversely isotropic or isotropic, orthorhombic models require an extended and more elaborated formulation that also involves more expensive computational processes. The acoustic assumption yields more efficient description of the orthorhombic wave equation that also provides a simplified representation for the orthorhombic dispersion relation. However, such representation is hampered by the sixth-order nature of the acoustic wave equation, as it also encompasses the contribution of shear waves. To reduce the computational cost of wavefield extrapolation in such media, we generate effective isotropic inhomogeneous models that are capable of reproducing the firstarrival kinematic aspects of the orthorhombic wavefield. First, in order to compute traveltimes in vertical orthorhombic media, we develop a stable, efficient and accurate algorithm based on the fast marching method. The derived orthorhombic acoustic dispersion relation, unlike the isotropic or transversely isotropic ones, is represented by a sixth order polynomial equation with the fastest solution corresponding to outgoing P waves in acoustic media. The effective velocity models are then computed by evaluating the traveltime gradients of the orthorhombic traveltime solution, and using them to explicitly evaluate the corresponding inhomogeneous isotropic velocity field. The inverted effective velocity fields are source dependent and produce equivalent first-arrival kinematic descriptions of wave propagation in orthorhombic media. We extrapolate wavefields in these isotropic effective velocity models using the more efficient isotropic operator, and the results compare well, especially kinematically, with those obtained from the more expensive anisotropic extrapolator.

Magnetic and magnetocaloric properties of spin-glass material DyNi{sub 0.67}Si{sub 1.34}

Energy Technology Data Exchange (ETDEWEB)

Chen, X. [The Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, IA 50011-3020 (United States); College of Physics and Electronic Information Engineering, Neijiang Normal University, Neijiang 641100 (China); Mudryk, Y., E-mail: slavkomk@ameslab.gov [The Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, IA 50011-3020 (United States); Pathak, A.K.; Feng, W. [The Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, IA 50011-3020 (United States); Pecharsky, V.K. [The Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, IA 50011-3020 (United States); Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011-2300 (United States)

2017-08-15

Highlights: • Spin-glass state is observed in the DyNi{sub 0.67}Si{sub 1.4} compound. • Random Ni/Si distribution in the AlB{sub 2}-type structure leads to magnetic frustration. • Magnetic frustration affects magnetic field dependence of magnetocaloric effect. - Abstract: Structural, magnetic, and magnetocaloric properties of DyNi{sub 0.67}Si{sub 1.34} were investigated using X-ray powder diffraction, magnetic susceptibility, and magnetization measurements. X-ray powder diffraction pattern shows that DyNi{sub 0.67}Si{sub 1.34} crystallizes in the AlB{sub 2}-type hexagonal structure (space group: P6/mmm, No. 191, a = b = 3.9873(9) Å, and c = 3.9733(1) Å). The compound is a spin-glass with the freezing temperature T{sub G} = 6.2 K. The ac magnetic susceptibility measurements confirm magnetic frustration in DyNi{sub 0.67}Si{sub 1.34}. The maximum value of the magnetic entropy change determined from M(H) data is −16.1 J/kg K at 10.5 K for a field change of 70 kOe.

Anisotropic and excellent magnetocaloric properties of La0.7Ca0.3MnO3 single crystal with anomalous magnetization

International Nuclear Information System (INIS)

Debnath, J.C.; Zeng, R.; Kim, J.H.; Chen, D.P.; Dou, S.X.

2012-01-01

Highlights: ► ΔS M shows a very large reversibility value at low field. ► The single crystal exhibits anisotropy in the MCE. ► La 0.7 Ca 0.3 MnO 3 is weakly itinerant ferromagnetic. ► No hysteresis loss is observed. - Abstract: Magnetic properties and the magnetocaloric effect (MCE) have been investigated in La 0.7 Ca 0.3 MnO 3 single crystal with applied field along both the ab-plane and the c-direction. Due to the magnetocrystalline anisotropy, the crystal exhibits anisotropy in the MCE. Upon application of a 5 T field, the magnetic entropy changes (ΔS M ), reaching values of 7.668 J/(kg K) and 6.412 J/(kg K) for both the ab-plane and the c-direction, respectively. A magnetic entropy change of 3.3 J/(kg K) was achieved for a magnetic field change of 1.5 T at the Curie temperature, T C = 245 K. Due to the absence of grains in the single crystal, the ΔS M distribution here is much more uniform than for gadolinium (Gd) and other polycrystalline manganites, which is desirable for an Ericsson-cycle magnetic refrigerator. For a field change of 5 T, the relative cooling power, RCP, reached 358.17 J/kg, while the maximum adiabatic temperature change of 5.33 K and a magnetoresistance (MR) ratio of 507.88% at T C were observed. We analysed the magnetization of La 0.7 Ca 0.3 MnO 3 single crystal at T C and estimated several parameters of spin fluctuation on the basis of a self-consistent renormalization theory of spin fluctuations, with reciprocal susceptibility above T C . We found that the magnetic property of La 0.7 Ca 0.3 MnO 3 is weakly itinerant ferromagnetic. A large reversible MCE and no hysteresis loss with a considerable value of refrigerant capacity indicate that La 0.7 Ca 0.3 MnO 3 single crystal is a potential candidate as a magnetic refrigerant.

Effects on RCS of a perfect electromagnetic conductor sphere in the presence of anisotropic plasma layer

Science.gov (United States)

Ghaffar, A.; Hussan, M. M.; Illahi, A.; Alkanhal, Majeed A. S.; Ur Rehman, Sajjad; Naz, M. Y.

2018-01-01

Effects on RCS of perfect electromagnetic conductor (PEMC) sphere by coating with anisotropic plasma layer are studied in this paper. The incident, scattered and transmitted electromagnetic fields are expanded in term of spherical vector wave functions using extended classical theory of scattering. Co and cross-polarized scattered field coefficients are obtained at the interface of free space-anisotropic plasma and at anisotropic plasma-PEMC sphere core by scattering matrices method. The presented analytical expressions are general for any perfect conducting sphere (PMC, PEC, or PEMC) with general anisotropic/isotropic material coatings that include plasma and metamaterials. The behavior of the forward and backscattered radar cross section of PEMC sphere with the variation of the magnetic field strength, incident frequency, plasma density, and effective collision frequency for the co-polarized and the cross polarized fields are investigated. It is also observed from the obtained results that anisotropic layer on PEMC sphere shows reciprocal behavior as compared to isotopic plasma layer on PEMC sphere. The comparisons of the numerical results of the presented analytical expressions with available results of some special cases show the correctness of the analysis.

Structure and magnetocaloric properties of La1-xKxMnO3 manganites

International Nuclear Information System (INIS)

Aliev, A.M.; Gamzatov, A.G.; Batdalov, A.B.; Mankevich, A.S.; Korsakov, I.E.

2011-01-01

A technology of obtaining the single-phase ceramic samples of La 1-x K x MnO 3 manganites and the dependence of their structural parameters on the content of potassium has been described. Magnetocaloric effect (MCE) in the obtained samples has been measured by two independent methods: classical direct methodic and a method of magnetic field modulation. The values of MCE obtained by both methods substantially differ. The explanation of the observed divergences is given. The correlation between the level of doping and MCE value has been defined. The value of T C determined by the MCE maximum conforms with the literature data obtained by other methods.

Analysis of electromagnetic scattering by uniaxial anisotropic bispheres.

Science.gov (United States)

Li, Zheng-Jun; Wu, Zhen-Sen; Li, Hai-Ying

2011-02-01

Based on the generalized multiparticle Mie theory and the Fourier transformation approach, electromagnetic (EM) scattering of two interacting homogeneous uniaxial anisotropic spheres with parallel primary optical axes is investigated. By introducing the Fourier transformation, the EM fields in the uniaxial anisotropic spheres are expanded in terms of the spherical vector wave functions. The interactive scattering coefficients and the expansion coefficients of the internal fields are derived through the continuous boundary conditions on which the interaction of the bispheres is considered. Some selected calculations on the effects of the size parameter, the uniaxial anisotropic absorbing dielectric, and the sphere separation distance are described. The backward radar cross section of two uniaxial anisotropic spheres with a complex permittivity tensor changing with the sphere separation distance is numerically studied. The authors are hopeful that the work in this paper will help provide an effective calibration for further research on the scattering characteristic of an aggregate of anisotropic spheres or other shaped anisotropic particles.

Research for magnetocaloric effect of Gd{sub 1-x}Dy{sub x} alloy

Energy Technology Data Exchange (ETDEWEB)

Hou, Xueling; Shitao, Li; An, Zhang; Hui, Xu; Ni, Jiansen; Zhou, Bangxin [Institute of Materials, Shanghai University, Shanghai 20007 (China)

2007-12-15

The magnetocaloric effect (MEC) in Gd{sub 1-x}Dy{sub x} (x=0.13,0.20,0.27,0.34,0.40) alloys is investigated using commercial elements with purity of up to 99.80% for Gd and Dy. These alloys are prepared by arc melting in stoichiometric proportions on a water-cooled copper crucible under high pure argon atmosphere. As a result, when x was changed from 0 to 40at%, the adiabatic temperature change ({delta}T) increases from 1.6 K to 3.1 K, the Curie temperature decreased from 288 K to 245.5 K. Gd{sub 73}Dy{sub 27} exhibits the largest {delta}T{sub max} value of 3.1 K at the T{sub C} value of 260 K among the alloys investigated up to 1.2 T (tesla) applied field, it is almost same as the {delta}T of high pure unitary Gd (99.99%) and is clearly superior to commercial unitary Gd (99.80%). The T{sub C} of Gd{sub 73}Dy{sub 27} alloy is minor to high pure unitary Gd (99.99%) and commercially unitary Gd (99.80%). But this alloy prepared by commercial elements with low cost has better MEC to be a promising candidate for magnetic working substances for room temperature magnetic refrigeration. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Complex magnetic properties and large magnetocaloric effects in RCoGe (R=Tb, Dy compounds

Directory of Open Access Journals (Sweden)

Yan Zhang

2018-05-01

Full Text Available Complicated magnetic phase transitions and Large magnetocaloric effects (MCEs in RCoGe (R=Tb, Dy compounds have been reported in this paper. Results show that the TbCoGe compounds have a magnetic phase transition from antiferromagnetic to paramagnetic (AFM-PM at TN∼16 K, which is close to the value reported by neutron diffraction. The DyCoGe compound undergoes complicated phase changes from 2 K up to 300 K. The peak at 10 K displays a phase transition from antiferromagnetic to ferromagnetic (AFM-FM. In particular, a significant ferromagnetic to paramagnetic (FM-PM phase transition was found at the temperature as high as 175 K and the cusp becomes more abrupt with the magnetic field increasing from 0.01 T to 0.1 T. The maximum value of magnetic entropy change of TbCoGe and DyCoGe compounds achieve 14.5 J/kg K and 11.5 J/kg K respectively for a field change of 0-5 T. Additionally, the correspondingly considerable refrigerant capacity value of 260 J/kg and 242 J/kg are also obtained respectively, suggesting that both TbCoGe and DyCoGe compounds could be considered as good candidates for low temperature magnetic refrigerant.

Band gaps in periodically magnetized homogeneous anisotropic media

Science.gov (United States)

Merzlikin, A. M.; Levy, M.; Vinogradov, A. P.; Wu, Z.; Jalali, A. A.

2010-11-01

In [A. M. Merzlikin, A. P. Vinogradov, A. V. Dorofeenko, M. Inoue, M. Levy, A. B. Granovsky, Physica B 394 (2007) 277] it is shown that in anisotropic magnetophotonic crystal made of anisotropic dielectric layers and isotropic magneto-optical layers the magnetization leads to formation of additional band gaps (BG) inside the Brillouin zones. Due to the weakness of the magneto-optical effects the width of these BG is much smaller than that of usual BG forming on the boundaries of Brillouin zones. In the present communication we show that though the anisotropy suppresses magneto-optical effects. An anisotropic magnetophotonic crystal made of anisotropic dielectric layers and anisotropic magneto-optical; the width of additional BG may be much greater than the width of the usual Brillouin BG. Anisotropy tends to suppress Brillouin zone boundary band gap formation because the anisotropy suppresses magneto-optical properties, while degenerate band gap formation occurs around points of effective isotropy and is not suppressed.

Magnetocaloric properties of Gd in fields up to 14 T

Energy Technology Data Exchange (ETDEWEB)

Koshkid' ko, Yu.S. [International Laboratory of High Magnetic Fields and Low Temperatures, PAS, 53-421 Wroclaw (Poland); Ćwik, J., E-mail: jacek.cwik@ml.pan.wroc.pl [International Laboratory of High Magnetic Fields and Low Temperatures, PAS, 53-421 Wroclaw (Poland); Ivanova, T.I.; Nikitin, S.A. [International Laboratory of High Magnetic Fields and Low Temperatures, PAS, 53-421 Wroclaw (Poland); Lomonosov Moscow State University, Faculty of Physics, 119991 Moscow (Russian Federation); Miller, M. [International Laboratory of High Magnetic Fields and Low Temperatures, PAS, 53-421 Wroclaw (Poland); Rogacki, K. [International Laboratory of High Magnetic Fields and Low Temperatures, PAS, 53-421 Wroclaw (Poland); Institute of Low Temperatures and Structure Research, PAS, 50-950 Wroclaw (Poland)

2017-07-01

Highlights: • MCE of Gd in fields up to 14 T. • Extraction. • MCE described in terms of the Landau theory. - Abstract: The magnetocaloric effect (MCE) of polycrystalline gadolinium was studied in high steady magnetic fields up to 14 T by direct measurements of the adiabatic temperature change (ΔT) using an “extraction method”. Large MCE was observed at the ferromagnetic phase transition resulting in ΔT of 19.5 K at a field change of 14 T. The direct measurements of MCE were performed using the measuring system designed and constructed by the authors. It was shown that near the Curie temperature, the magnetic field dependence of the adiabatic temperature change is far from saturation even in a 14 T field and is adequately described by the thermodynamic Landau theory for magnetic second-order phase transitions.

Magnetic properties and magnetocaloric effect in the HoNi1−xCuxIn (x=0, 0.1, 0.3, 0.4) intermetallic compounds

International Nuclear Information System (INIS)

Mo, Zhao-Jun; Shen, Jun; Yan, Li-Qin; Tang, Cheng-Chun; He, Xiao-Nan; Zheng, Xinqi; Wu, Jian-Feng; Sun, Ji-Rong; Shen, Bao-Gen

2014-01-01

The magnetic properties and magnetocaloric effect (MCE) in HoNi 1−x Cu x In (x=0, 0.1, 0.3, 0.4) compounds have been investigated. With the substitution of Cu for Ni, the Ho magnetic moment will cant from the c-axis, and form a complicated magnetic structure. These compounds exhibit two successive magnetic transitions with the increase in temperature. The large reversible magnetocaloric effects have been observed in HoNi 1−x Cu x In compounds around T ord , with no thermal and magnetic hysteresis loss. The large reversible isothermal magnetic entropy change (−ΔS M ) is 20.2 J/kg K and the refrigeration capacity (RC) reaches 356.7 J/kg for field changes of 5 T for HoNi 0.7 Cu 0.3 In. Especially, the value of −ΔS M (12.5 J/kg K) and the large RC (132 J/kg) are observed for field changes of 2 T for HoNi 0.9 Cu 0.1 In. Additionally, the values of RC are improved to 149 J/K for the field changes of 2 T due to a wide temperature span for the mix of HoNi 0.9 Cu 0.1 In and HoNi 0.7 Cu 0.3 In compounds with the mass ratio of 1:1. These compounds with excellent MCE are expected to have effective applications in magnetic refrigeration around 20 K. - Highlights: • For magnetic-field changes of 2 T, the values of RC are improved to 149 J/K. • MCEs of these compounds show no thermal and magnetic hysteresis. • Compounds show two successive magnetic transitions with the increase in temperature. • With the substitution of Cu for Ni, compounds form a complicated magnetic structure

Anisotropic electro-optic effect on InGaAs quantum dot chain modulators.

Science.gov (United States)

Liu, Wei; Liang, Baolai; Huffaker, Diana; Fetterman, Harold

2013-10-15

We investigated the anisotropic electro-optic (EO) effect on InGaAs quantum dot (QD) chain modulators. The linear EO coefficients were determined as 24.3 pm/V (33.8 pm/V) along the [011] direction and 30.6 pm/V (40.3 pm/V) along the [011¯] direction at 1.55 μm (1.32 μm) operational wavelength. The corresponding half-wave voltages (Vπs) were measured to be 5.35 V (4.35 V) and 4.65 V (3.86 V) at 1.55 μm (1.32 μm) wavelength. This is the first report on the anisotropic EO effect on QD chain structures. These modulators have 3 dB bandwidths larger than 10 GHz.

Elastic properties of spherically anisotropic piezoelectric composites

International Nuclear Information System (INIS)

En-Bo, Wei; Guo-Qing, Gu; Ying-Ming, Poon

2010-01-01

Effective elastic properties of spherically anisotropic piezoelectric composites, whose spherically anisotropic piezoelectric inclusions are embedded in an infinite non-piezoelectric matrix, are theoretically investigated. Analytical solutions for the elastic displacements and the electric potentials under a uniform external strain are derived exactly. Taking into account of the coupling effects of elasticity, permittivity and piezoelectricity, the formula is derived for estimating the effective elastic properties based on the average field theory in the dilute limit. An elastic response mechanism is revealed, in which the effective elastic properties increase as inclusion piezoelectric properties increase and inclusion dielectric properties decrease. Moreover, a piezoelectric response mechanism, of which the effective piezoelectric response vanishes due to the symmetry of spherically anisotropic composite, is also disclosed. (condensed matter: structure, thermal and mechanical properties)

Determination of the magnetocaloric entropy change in the presence of phase separation and metastability: The case of Eu0.58Sr0.42MnO3

International Nuclear Information System (INIS)

Guillou, F.; Hardy, V.; Fruchart, D.; Zawilski, B.

2014-01-01

The magnetocaloric effect (MCE) in the manganite Eu 0.58 Sr 0.42 MnO 3 was derived by different methods, in a field range very sensitive to the phenomenon of phase separation. It turns out that a strong scatter in the MCE features was observed. When the applied field is less than the field required to complete the transition, it is found that the MCE can be strongly overestimated by “standard” indirect measurements. A way to properly estimate the MCE around a first order transition in the presence of phase separation and metastability is proposed. - Highlights: • The entropy change was investigated in an oxide with pronounced metastable effects. • A strong scatter is observed among results derived from several indirect methods. • It is found that even the calorimetric approach can be proned to artefacts. • A method is proposed to evaluate a “real” magnetocaloric entropy change

Quantitative feasibility study of magnetocaloric energy conversion utilizing industrial waste heat

International Nuclear Information System (INIS)

Vuarnoz, D.; Kitanovski, A.; Gonin, C.; Borgeaud, Y.; Delessert, M.; Meinen, M.; Egolf, P.W.

2012-01-01

Highlights: ► We model magnetic energy conversion machine for the use of industrial waste heat. ► Efficiencies and masses of the system are evaluated by a numerical model. ► Excellent potential of profitability is expected with large low-exergy heat sources. -- Abstract: The main objective of this theoretical study was to investigate under which conditions a magnetic energy conversion device (MECD) – utilizing industrial waste heat – is economically feasible. Furthermore, it was evaluated if magnetic energy conversion (MCE) has the potential of being a serious concurrent to already existing conventional energy conversion technologies. Up-today the availability of magnetocaloric materials with a high Curie temperature and a high magnetocaloric effect is rather limited. Therefore, this study was mainly focused on applications with heat sources of low to medium temperature levels. Magnetic energy conversion machines, containing permanent magnets, are numerically investigated for operation conditions with different temperature levels, defined by industrial waste heat sources and environmental heat sinks, different magnetic field intensities and different frequencies of operation (number of thermodynamic cycles per unit of time). Theoretical modeling and numerical simulations were performed in order to determine thermodynamic efficiencies and the exergy efficiencies as function of different operation conditions. From extracted data of our numerical results, approximate values of the total mass and total volume of magnetic energy conversion machines could be determined. These important results are presented dependent on the produced electric power. An economic feasibility study supplements the scientific study. It shows an excellent potential of profitability for certain machines. The most important result of this article is that the magnetic energy conversion technology can be economically and technically competitive to or even beat conventional energy

Aeroelastic modal dynamics of wind turbines including anisotropic effects

Energy Technology Data Exchange (ETDEWEB)

Fisker Skjoldan, P.

2011-03-15

Several methods for aeroelastic modal analysis of a rotating wind turbine are developed and used to analyse the modal dynamics of two simplified models and a complex model in isotropic and anisotropic conditions. The Coleman transformation is used to enable extraction of the modal frequencies, damping, and periodic mode shapes of a rotating wind turbine by describing the rotor degrees of freedom in the inertial frame. This approach is valid only for an isotropic system. Anisotropic systems, e.g., with an unbalanced rotor or operating in wind shear, are treated with the general approaches of Floquet analysis or Hill's method which do not provide a unique reference frame for observing the modal frequency, to which any multiple of the rotor speed can be added. This indeterminacy is resolved by requiring that the periodic mode shape be as constant as possible in the inertial frame. The modal frequency is thus identified as the dominant frequency in the response of a pure excitation of the mode observed in the inertial frame. A modal analysis tool based directly on the complex aeroelastic wind turbine code BHawC is presented. It uses the Coleman approach in isotropic conditions and the computationally efficient implicit Floquet analysis in anisotropic conditions. The tool is validated against system identifications with the partial Floquet method on the nonlinear BHawC model of a 2.3 MW wind turbine. System identification results show that nonlinear effects on the 2.3 MW turbine in most cases are small, but indicate that the controller creates nonlinear damping. In isotropic conditions the periodic mode shape contains up to three harmonic components, but in anisotropic conditions it can contain an infinite number of harmonic components with frequencies that are multiples of the rotor speed. These harmonics appear in calculated frequency responses of the turbine. Extreme wind shear changes the modal damping when the flow is separated due to an interaction between

The effects of small metal additions (Co, Cu, Ga, Mn, Al, Bi, Sn) on the magnetocaloric properties of the Gd5Ge2Si2 alloy

Czech Academy of Sciences Publication Activity Database

Shull, R. D.; Provenzano, V.; Shapiro, A. J.; Fu, A.; Lufaso, M. W.; Karapetrova, J.; Kletetschka, Günther; Mikula, V.

2006-01-01

Roč. 99, č. 8 (2006), s. 8-8 ISSN 0021-8979 Institutional research plan: CEZ:AV0Z30130516 Keywords : magnetocaloric * (Co, Cu, Ga, Mn, Al, Bi, Sn) additions * Cryogenic properties Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.316, year: 2006

The effects of substituting Ag for In on the magnetoresistance and magnetocaloric properties of Ni-Mn-In Heusler alloys

Directory of Open Access Journals (Sweden)

Sudip Pandey

2016-05-01

Full Text Available The effect of substituting Ag for In on the structural, magnetocaloric, and thermomagnetic properties of Ni50Mn35In15−xAgx (x = 0.1, 0.2, 0.5, and 1 Heusler alloys was studied. The magnitude of the magnetization change at the martensitic transition temperature (TM decreased with increasing Ag concentration. Smaller magnetic entropy changes (ΔSM were observed for the alloys with larger Ag concentrations and the martensitic transition shifted to higher temperature. A shift of TM by about 25 K to higher temperature was observed for an applied hydrostatic pressure of P = 6.6 kbar with respect to ambient pressure. A large drop in resistivity was observed for large Ag concentration. The magnetoresistance was dramatically suppressed due to an increase in the disorder of the system with increasing Ag concentration. Possible mechanisms responsible for the observed behavior are discussed.

The persistence of the magnetocaloric effect in (La1-x)A(x)(0.67)Ba0.33Mn1.05O3-δ

DEFF Research Database (Denmark)

Ancona-Torres, Carlos Eugenio; Pryds, Nini; Kuhn, Luise Theil

2010-01-01

Polycrystalline samples of (La1-xAx)0.67Ba0.33Mn1.05O3-δ, with A being a mixture of lanthanides containing 66% La, 22% Nd, 8% Pr and 4% Ce, were prepared by the glycine-nitrate method, with target compositions of x = 0, 0.33, 0.67 and 1. The effect of the mixture of lanthanides on the Curie...... temperature, TC, and the magnetocaloric properties was investigated. The prepared samples are single phase, with space group R-3c. The lattice parameters and average A-site ionic radius, rA decrease linearly with x while the size disorder, as characterized by the variance, σ2, increases from 0.014 to 0...

Correlation theory of crystal field and anisotropic exchange effects

DEFF Research Database (Denmark)

Lindgård, Per-Anker

1985-01-01

A general theory for including correlation effects in static and dynamic properties is presented in terms of Raccah or Stevens operators. It is explicitly developed for general crystal fields and anisotropic interactions and systems with several sublattices, like the rare earth compounds....... The theory gives explicitly a temperature dependent renormalization of both the crystal field and the interactions, and a damping of the excitations and in addition a central park component. The general theory is illustrated by a discussion of the singlet-doublet system. The correlation effects...

Modelling and simulation of regenerators with complex flow arrangements for active magnetocaloric refrigeration

DEFF Research Database (Denmark)

Lei, Tian; Nielsen, Kaspar Kirstein; Engelbrecht, Kurt

2014-01-01

Compared to a conventional vapor compression refrigera-tion system, a magnetocaloric refrigerator has many advantages, such as potentially high efficiency, low vibration and avoidance of refrigerants that deplete the ozone layer and cause the green-house effect. As a main component of the active...... magnetic re-generative refrigerator, the regenerator plays an important role in the cooling performance and efficiency of the whole system. However, the regenerator design is constrained by several exter-nal factors, such as the geometry of the magnetic field source and flow resistance. In this work, novel...... regenerators with complex flow arrange-ments, providing high performance at lower pressure drop, are investigated. Correspondingly a one dimensional model is pre-sented and comparative studies between novel and conventional regenerators are carried out by simulation. The effect of regen-erator geometries...

A Preisach approach to modeling partial phase transitions in the first order magnetocaloric material MnFe(P,As)

DEFF Research Database (Denmark)

von Moos, Lars; Bahl, C.R.H.; Nielsen, Kaspar Kirstein

2014-01-01

of MnFe(P,As) under partial phase transitions, which is similar to what materials experience in actual magnetic refrigeration devices. Partial phase transition curves, in the absence of a magnetic field, are measured using calorimetry and the experimental results are compared to simulations......Magnetic refrigeration is an emerging technology that could provide energy efficient and environmentally friendly cooling. Magnetocaloric materials in which a structural phase transition is found concurrently with the magnetic phase transition are often termed first order magnetocaloric materials....... Such materials are potential candidates for application in magnetic refrigeration devices. However, the first order materials often have adverse properties such as hysteresis, making actual performance troublesome to quantify, a subject not thoroughly studied within this field.Here we investigate the behavior...

Cracking on anisotropic neutron stars

Science.gov (United States)

Setiawan, A. M.; Sulaksono, A.

2017-07-01

We study the effect of cracking of a local anisotropic neutron star (NS) due to small density fluctuations. It is assumed that the neutron star core consists of leptons, nucleons and hyperons. The relativistic mean field model is used to describe the core of equation of state (EOS). For the crust, we use the EOS introduced by Miyatsu et al. [1]. Furthermore, two models are used to describe pressure anisotropic in neutron star matter. One is proposed by Doneva-Yazadjiev (DY) [2] and the other is proposed by Herrera-Barreto (HB) [3]. The anisotropic parameter of DY and HB models are adjusted in order the predicted maximum mass compatible to the mass of PSR J1614-2230 [4] and PSR J0348+0432 [5]. We have found that cracking can potentially present in the region close to the neutron star surface. The instability due cracking is quite sensitive to the NS mass and anisotropic parameter used.

Effective Orthorhombic Anisotropic Models for Wave field Extrapolation

KAUST Repository

Ibanez Jacome, Wilson

2013-05-01

Wavefield extrapolation in orthorhombic anisotropic media incorporates complicated but realistic models, to reproduce wave propagation phenomena in the Earth\\'s subsurface. Compared with the representations used for simpler symmetries, such as transversely isotropic or isotropic, orthorhombic models require an extended and more elaborated formulation that also involves more expensive computational processes. The acoustic assumption yields more efficient description of the orthorhombic wave equation that also provides a simplified representation for the orthorhombic dispersion relation. However, such representation is hampered by the sixth-order nature of the acoustic wave equation, as it also encompasses the contribution of shear waves. To reduce the computational cost of wavefield extrapolation in such media, I generate effective isotropic inhomogeneous models that are capable of reproducing the first-arrival kinematic aspects of the orthorhombic wavefield. First, in order to compute traveltimes in vertical orthorhombic media, I develop a stable, efficient and accurate algorithm based on the fast marching method. The derived orthorhombic acoustic dispersion relation, unlike the isotropic or transversely isotropic one, is represented by a sixth order polynomial equation that includes the fastest solution corresponding to outgoing P-waves in acoustic media. The effective velocity models are then computed by evaluating the traveltime gradients of the orthorhombic traveltime solution, which is done by explicitly solving the isotropic eikonal equation for the corresponding inhomogeneous isotropic velocity field. The inverted effective velocity fields are source dependent and produce equivalent first-arrival kinematic descriptions of wave propagation in orthorhombic media. I extrapolate wavefields in these isotropic effective velocity models using the more efficient isotropic operator, and the results compare well, especially kinematically, with those obtained from the

Magnetocaloric properties of a frustrated Blume-Capel antiferromagnet

Directory of Open Access Journals (Sweden)

Žukovič Milan

2014-07-01

Full Text Available Low-temperature magnetization processes and magnetocaloric properties of a geometrically frustrated spin-1 Blume-Capel model on a triangular lattice are studied by Monte Carlo simulations. The model is found to display qualitatively different behavior depending on the sign of the single-ion anisotropy D. For positive values of D we observe two magnetization plateaus, similar to the spin-1/2 Ising antiferromagnet, and negative isothermal entropy changes for any field intensity. For a range of small negative values of D there are four magnetization plateaus and the entropy changes can be either negative or positive, depending on the field. If D is negative but large in absolute value then the entropy changes are solely positive.

Investigation of magnetocaloric effect in La0.45Pr0.25Ca0.3MnO3 by magnetic, differential scanning calorimetry and thermal analysis

International Nuclear Information System (INIS)

Aparnadevi, M.; Barik, S.K.; Mahendiran, R.

2012-01-01

We investigated magnetocaloric effect in La 0.45 Pr 0.25 Ca 0.3 MnO 3 by direct methods (changes in temperature and latent heat) and indirect method (magnetization isotherms). This compound undergoes a first-order paramagnetic to ferromagnetic transition with T C =200 K upon cooling. The paramagnetic phase becomes unstable and it transforms into a ferromagnetic phase under the application of magnetic field, which results in a field-induced metamagnetic transition (FIMMT). The FIMMT is accompanied by release of latent heat and temperature of the sample as evidenced from differential scanning calorimetry and thermal analysis experiments. A large magnetic entropy change of ΔS m =−7.2 J kg −1 K −1 at T=212.5 K and refrigeration capacity of 228 J kg −1 are found for a field change of ΔH=5 T. It is suggested that destruction of magnetic polarons and growth of ferromagnetic phase accompanied by a lattice volume change with increasing magnetic field is responsible for the large magnetocaloric effect in this compound. - Highlights: ► We report magnetic entropy change measured by indirect and direct methods in La 0.45 Pr 0.25 Ca 0.3 MnO 3. ► Anomalous field-induced induced metamagnetic transition is found in the paramagnetic state. ► A large reversible magnetic entropy change (ΔS m =7.2 J kg −1 K −1 for ΔH=5 T). ► A large refrigeration capacity (RC=228 J kg −1 ). ► Collapse of magnetic polarons is suggested as possible origin of the large MCE.

Effective stress law for anisotropic elastic deformation

International Nuclear Information System (INIS)

Carroll, M.M.

1979-01-01

An effective stress law is derived analytically to describe the effect of pore fluid pressure on the linearly elastic response of saturated porous rocks which exhibit anisotropy. For general anisotropy the difference between the effective stress and the applied stress is not hydrostatic. The effective stress law involves two constants for transversely isotropic response and three constants for orthotropic response; these constants can be expressed in terms of the moduli of the porous material and of the solid material. These expressions simplify considerably when the anisotropy is structural rather than intrinsic, i.e., in the case of an isotropic solid material with an anisotropic pore structure. In this case the effective stress law involves the solid or grain bulk modulus and two or three moduli of the porous material, for transverse isotropy and orthotropy, respectively. The law reduces, in the case of isotropic response, to that suggested by Geertsma (1957) and by Skempton (1961) and derived analytically by Nur and Byerlee

Magnetic Properties and Magnetocaloric Effect in Layered NdMn1.9Ti0.1Si2

Directory of Open Access Journals (Sweden)

M.F. Md Din

2014-04-01

Full Text Available The structural and magnetic properties of the NdMn1.9Ti0.1Si2 compund have been studied by high-intensity x-ray and high-resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range of 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9Ti0.1Si2 are indicated as TC ~ 22 K and TN ~ 374 K respectively. The first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd+Fmc] around TC is found in layered NdMn1.9Ti0.1Si2 and is associated with large magnetocaloric effect. This behavior has been confirmed as a contribution of the magnetostructural coupling by using neutron and x-ray powder diffraction. The magnetic entropy change –ΔSM ~ 15.3 J kg-1 K-1 and adiabatic temperature change ΔTad ~ 4.7 K have been determined using magnetization and specific heat measurement under 0-5 T applied fields. This compound exhibits almost no thermal and magnetic hysteresis, thus potentially applicable in low temperature region for magnetic refrigerator material

Microstructure evolution and large magnetocaloric effect of La0.8Ce0.2(Fe0.95Co0.05)11.8Si1.2 alloy prepared by strip-casting and annealing

Science.gov (United States)

Zhong, X. C.; Feng, X. L.; Huang, J. H.; Zhang, H.; Huang, Y. L.; Liu, Z. W.; Jiao, D. L.

2018-04-01

The microstructure and magnetocaloric effect of the La0.8Ce0.2(Fe0.95Co0.05)11.8Si1.2 strip-cast flakes annealed between 1273K and 1423K for different time have been investigated. For the flakes annealed for 2h from 1273K to 1423K, the shape and distribution of α-Fe, La-rich and NaZn13-type 1:13 phases are quite sensitive to the annealing temperature. Especially, at a high annealing temperature of 1423K, the 1:13 phase began to decompose into macroscopic α-Fe conglomerations and La-rich dendrites. With the increase of annealing time from 0 to 12h at 1323K, the amount of 1:13 phase increased significantly and reached ˜93.50 wt.% at 12h. However, an overlong annealing time also led to 1:13 phase decomposition and influenced the magnetic performance. For the flakes annealed at 1323K for 12h, large magnetic entropy change value of 18.12Jkg-1K-1 at 5T has been obtained. The present results indicate that strip casting method can potentially be used in mass production of high performance magnetocaloric materials.

Indirect measurement of the magnetocaloric effect using a novel differential scanning calorimeter with magnetic field.

Science.gov (United States)

Jeppesen, S; Linderoth, S; Pryds, N; Kuhn, L Theil; Jensen, J Buch

2008-08-01

A simple and high-sensitivity differential scanning calorimeter (DSC) unit operating under magnetic field has been built for indirect determination of the magnetocaloric effect. The principle of the measuring unit in the calorimeter is based on Peltier elements as heat flow sensors. The high sensitivity of the apparatus combined with a suitable calibration procedure allows very fast and accurate heat capacity measurements under magnetic field to be made. The device was validated from heat capacity measurements for the typical DSC reference material gallium (Ga) and a La(0.67)Ca(0.33)MnO(3) manganite system and the results were highly consistent with previous reported data for these materials. The DSC has a working range from 200 to 340 K and has been tested in magnetic fields reaching 1.8 T. The signal-to-noise ratio is in the range of 10(2)-10(3) for the described experiments. Finally the results have been compared to results from a Quantum Design(R) physical properties measuring system. The configuration of the system also has the advantage of being able to operate with other types of magnets, e.g., permanent magnets or superconducting coils, as well as the ability to be expanded to a wider temperature range.

Effect of strain path change on limits to ductility of anisotropic metal sheets

DEFF Research Database (Denmark)

Kuroda, M.; Tvergaard, Viggo

2000-01-01

of the anisotropic plasticity models, and it is shown that elastic straining plays a large role, as the stresses quickly move from one point of the yield surface to another. When the load is removed between steps, the stress point moves in a different manner, which results in quite different flow localization......Localized necking in thin metal sheets is analyzed by using the M-K-model approach, and the effect of a number of different non-proportional strain paths prior to the occurrence flow localization are considered. The analyses account for plastic anisotropy, using four different anisotropic...

Magnetic and magnetocaloric properties of itinerant-electron system Hf.sub.1-x./sub.Ta.sub.x./sub.Fe.sub.2./sub. (x = 0.125 and 0.175)

Czech Academy of Sciences Publication Activity Database

Diop, L.V.B.; Kaštil, Jiří; Isnard, O.; Arnold, Zdeněk; Kamarád, Jiří

2015-01-01

Roč. 627, Apr (2015), s. 446-450 ISSN 0925-8388 R&D Projects: GA ČR GAP204/12/0692 Institutional support: RVO:68378271 Keywords : itinerant-electron compounds * magnetic properties * magnetocaloric effect Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.014, year: 2015

Magnetocaloric effect and corrosion resistance of La(Fe, Si)13 composite plates bonded by different fraction of phenolic resin

Science.gov (United States)

Zhang, K. S.; Xue, J. N.; Wang, Y. X.; Sun, H.; Long, Y.

2018-04-01

La(Fe, Si)13-based composite plates were successfully fabricated using different amount of phenolic resin. The introduction of phenolic resin as binder increased the corrosion resistance and maintained giant magnetocaloric effect for La(Fe, Si)13-based composite plates. It was found that corroded spots were firstly observed on the boundaries between resin and La(Fe, Si)13 particles, rather than in La(Fe, Si)13-based particles, after being immersed in static distilled water. The corrosion rate decreased significantly with the increase of resin content. And the increase of the content of phenolic resin leads to the reduction of corrosion current density. Meanwhile, the volumetric magnetic entropy change ΔSM decreases slightly as the content of phenolic resin increases. The ΔSM of the plates with 3 wt.%, 5 wt.% and 8 wt.% resin are 63.1, 61.2 and 59.8 mJ/cm3 K under a low magnetic field change of 1 T, respectively.

Room temperature inverse magnetocaloric effect in Pd substituted Ni{sub 50}Mn{sub 37}Sn{sub 13} Heusler alloys

Energy Technology Data Exchange (ETDEWEB)

Saha, Ritwik, E-mail: ritwik.saha@tifr.res.in; Nigam, A.K.

2014-09-01

The structural, magnetic and magnetocaloric effects for Ni{sub 50−x}Pd{sub x}Mn{sub 37}Sn{sub 13} Heusler alloys have been investigated around both structural and magnetic transitions. The room temperature X-ray diffraction indicates 10 M modulated martensitic structure with an orthorhombic unit cell for x=0 and 1. However, the superstructure reflections for x=2 alloy imply that the pattern is related to the L2{sub 1} phase. The maximum entropy change occurring at the martensitic transition is found to be 21 J kg{sup −1} K{sup −1} for Ni{sub 50}Mn{sub 37}Sn{sub 13} alloy around room temperature. Despite the smaller change in entropy around room temperature, 3.8 times larger value of refrigerant capacity (184.6 J/kg) is achieved for 2% substitution of Pd, due to occurrence of magnetic entropy change in a broader temperature region.

Structural and magnetocaloric properties of (Mn,Fe){sub 2}(P,Si) materials with added nitrogen

Energy Technology Data Exchange (ETDEWEB)

Thang, N.V., E-mail: v.t.nguyen-1@tudelft.nl; Miao, X.F., E-mail: X.F.Miao@tudelft.nl; Dijk, N.H. van, E-mail: N.H.vanDijk@tudelft.nl; Brück, E., E-mail: E.H.Bruck@tudelft.nl

2016-06-15

Amongst magnetic materials that exhibit a giant magnetocaloric effect near room temperature, the (Mn,Fe){sub 2}(P,Si) system is one of the most promising candidates for magnetic refrigeration. Although the (Mn,Fe){sub 2}(P,Si) materials hold many advantages, controlling the magnetic entropy change ΔS{sub m}, the adiabatic temperature change ΔT{sub ad}, the thermal hysteresis and the mechanical stability across the ferromagnetic transition requires a delicate tuning of the composition. This work investigates the addition of nitrogen, as an interstitial or substitutional element, as a new parameter to tune the properties of (Mn,Fe){sub 2}(P,Si) materials. We found that the nitrogen addition results in a decrease of the Curie temperature, consistent with the observed increase in the c/a ratio. The introduction of nitrogen in (Mn,Fe){sub 2}(P,Si) materials also results in a strong enhancement of the mechanical stability. - Highlights: • N-doped materials were synthesized by high-energy ball milling and solid-state reactions. • Nitrogen atoms enter the structure both as substitutional and as interstitial element in (Mn,Fe){sub 2}(P,Si) materials. • Nitrogen addition leads to a decrease in the Curie temperature, while improving the mechanical stability and preserving the magnetocaloric properties. • The origin of the increase in the thermal hysteresis by increasing the N content has been investigated by analyzing the XRD data.

Magnetic properties and tunable magneto-caloric effect in La0.8Ce0.2Fe11.5-xCoxSi1.5C0.2 (x = 0.3, 0.5, and 0.7) compounds

Science.gov (United States)

Wu, Qiming; Wang, Xiangjie; Ding, Zan; Li, Lingwei

2018-05-01

The magnetic and magneto-caloric properties in the ternary elementals doped La0.8Ce0.2Fe11.5-xCoxSi1.5C0.2 (x = 0.3, 0.5, and 0.7) compounds were studied. With the increases of Co content x, the Curie temperature TC increases and the thermal hysteresis decreases. All the compounds undergo a second-order magnetic phase transition and exhibit a considerable reversible tunable magneto-caloric effect. The values of maximum magnetic entropy change (-ΔSMmax) and the Relative Cooling Power (RCP) are kept at same high level with different Co content. Under a magnetic field change of 0-5 T, the values of -ΔSMmax for La0.8Ce0.2Fe11.5-xCoxSi1.5C0.2 are 10.5, 10.7, and 9.8 J/kg K for x = 0.3, 0.5, and 0.7, respectively. The corresponding values of RCP are 267.1, 289.9, and 290.2 J/kg.

Study of multi-layer active magnetic regenerators using magnetocaloric materials with first and second order phase transition

DEFF Research Database (Denmark)

Lei, Tian; Engelbrecht, Kurt; Nielsen, Kaspar Kirstein

2016-01-01

Magnetocaloric materials (MCM) with a first order phase transition (FOPT) usually exhibit a large, although sharp, isothermal entropy change near their Curie temperature, compared to materials with a second order phase transition (SOPT). Experimental results of applying FOPT materials in recent...

Magnetocaloric effect in multiferroic Y-type hexaferrite Ba0.5Sr1.5Zn2(Fe0.92Al0.0812O22

Directory of Open Access Journals (Sweden)

Wenfei Xu

2014-06-01

Full Text Available Magnetocaloric effect is investigated in multiferroic Ba0.5Sr1.5Zn2(Fe0.92Al0.0812O22 ceramic with Y-type hexagonal system. Three magnetic transitions, from alternating longitudinal conical to mixed conical at ∼240 K, to ferrimagnetic at ∼297 K, further to paramagnetic at ∼702 K, are unambiguously determined. Furthermore, obvious MCE is shown, and the maximum values of the magnetic entropy change and relative cooling power are evaluated to be 1.53 JKg−1K−1 and 280 JKg−1 for a field change of 7 T, respectively. In addition, inverse MCE is also observed, which might be associated with the first-order magnetic phase transition between two incommensurate longitudinal conical phases.

Heat flux measurements of Tb{sub 3}M series (M=Co, Rh and Ru): Specific heat and magnetocaloric properties

Energy Technology Data Exchange (ETDEWEB)

Monteiro, J.C.B., E-mail: jolmiui@gmail.com [Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin, Campinas, SP 13083-859 (Brazil); Lombardi, G.A. [Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin, Campinas, SP 13083-859 (Brazil); Reis, R.D. dos [Max-Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, 01187 Dresden (Germany); Freitas, H.E.; Cardoso, L.P.; Mansanares, A.M.; Gandra, F.G. [Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin, Campinas, SP 13083-859 (Brazil)

2016-12-15

We report on the magnetic properties and magnetocaloric effect (MCE) for the Tb{sub 3}M series, with M=Co, Rh and Ru, obtained using a heat flux technique. The specific heat of Tb{sub 3}Co and Tb{sub 3}Rh are very similar, with a first order type transition occurring around 6 K below the magnetic ordering temperature without any corresponding feature on the magnetization. The slightly enhanced electronic specific heat, the Debye temperature around 150 K and the presence of the magnetic specific heat well above the ordering temperature are also characteristic of many other compounds of the R{sub 3}M family (R=Rare Earth). The specific heat for Tb{sub 3}Ru, however, presents two peaks at 37 K and 74 K. The magnetization shows that below the first peak the system presents an antiferromagnetic behavior and is paramagnetic above 74 K. We obtained a magnetocaloric effect for M=Co and Rh, −∆S=12 J/kg K, but for Tb{sub 3}Ru it is less than 3 J/kg K (μ{sub 0}∆H=5 T). We believe that the experimental results show that the MCE is directly related with the process of hybridization of the (R)5d-(M)d electrons that occurs in the R{sub 3}M materials.

Effects of anisotropic properties on bursting behavior of rectangular cup with a V-notch

Energy Technology Data Exchange (ETDEWEB)

Kim, Jeong Tai [R and D Center, TERA Co. Ltd., Seoul (Korea, Republic of); Kim, Sang Mok [R and D Center, Hyosung Power and Industrial Systems PG, Changwon (Korea, Republic of); Kang, Beom Soo [Dept. of Aerospace Engineering, Pusan National University, Busan (Korea, Republic of); Ku, Tae Wan [Engineering Research Center of Innovative Technology on Advanced Forming, Pusan National University, Busan (Korea, Republic of)

2016-09-15

Effects of mechanical anisotropic properties on bursting failure and its pressure of rectangular deep-drawn cup fabricated by using AA3005-H14 thin sheet are investigated to utilize for electrolyte container of lithium-ion secondary batteries. The V-notch shape with a depth of 0.1 mm and an angle of 20.0 degrees is defined on the rectangular cup, which has a thickness of 0.20 mm on the major surface and that of 0.30 mm on the minor surface. With the measured mechanical properties by uni-axial tensile tests and the defined V-notch geometry, a series of numerical prediction models considering isotropic, planar and normal anisotropic characteristics, are built-up and the bursting simulations are performed. Thereafter, the bursting fracture behavior is investigated by adopting ductile fracture criterion proposed by Cockcroft and Latham. The results predicted for the planar and the normal anisotropic models show that the bursting fracture pressure is well matched to 0.400 MPa, and the isotropic and the planar anisotropic models present a bursting fracture height of about 4.95 mm and 4.92 mm, respectively. A series of experimental investigations are undertaken to verify the bursting deformation that had been predicted. The bursting pressure and its height during experimental verifications are shown to be in good agreement with each variation of about 5.88% and roughly 0.20% with respect to the numerical results obtained using the planar anisotropic model.

Preparing Magnetocaloric LaFeSi Uniform Microstructures by Spark Plasma Sintering

DEFF Research Database (Denmark)

Vicente, N.; Ocanã, J.; Neves Bez, Henrique

2014-01-01

Spark Plasma Sintering (SPS) of LaFeSi alloy powders was conducted to prepare magnetocaloric La-Fe-Si-based uniform microstructures. Two electrically insulating discs made of alumina were interposed between the punches and powder sample inhibiting the flow of electric current across the powder...... from hydrogenated and decrypted casting ingot. The characterizations of sintered samples were performed by Scanning Electron Microscopy (SEM), Archimedes principle, Vicker’s hardness and microhardness. The uniformity of the microstructure was evaluated by checking the evidence of position on the Vicker...

The influence of non-magnetocaloric properties on the performance in parallel-plate AMRs

DEFF Research Database (Denmark)

Nielsen, Kaspar Kirstein; Bahl, Christian R.H.; Smith, Anders

2014-01-01

a strong dependence on the orientation of the applied field and the regenerator geometry. Finally, the flow maldistribution of non-uniform regenerator geometries is found to degrade the AMR performance even at minor deviations from perfectly homogeneous regenerator matrices. This paper reflects a summary......The performance of Active Magnetic Regenerators (AMR) does not depend solely on the magnetocaloric effect of their constituents. Rather, it depends on several additional parameters, including, magnetic field, geometry (hydraulic diameter, cross-sectional area, regenerator length etc.), thermal...... properties (conductivity, specific heat and mass density) and operating parameters (utilization, frequency, number of transfer units etc.). In this paper we focus on the influence of three parameters on regenerator performance: 1) Solid thermal conductivity, 2) magnetostatic demagnetization and 3) flow...

Strain dependent magnetocaloric effect in La0.67Sr0.33MnO3 thin-films

Directory of Open Access Journals (Sweden)

V. Suresh Kumar

2013-05-01

Full Text Available The strain dependent magnetocaloric properties of La0.67Sr0.33MnO3 thin films deposited on three different substrates (001 LaAlO3 (LAO, (001 SrTiO3 (STO, and (001 La0.3Sr0.7Al0.65Ta0.35O9 (LSAT have been investigated under low magnetic fields and around magnetic phase transition temperatures. Compared to bulk samples, we observe a remarkable decrease in the ferromagnetic transition temperature that is close to room temperature, closely matched isothermal magnetic entropy change and relative cooling power values in tensile strained La0.67Sr0.33MnO3 films. The epitaxial strain plays a significant role in tuning the peak position of isothermal magnetic entropy change towards room temperature with improved cooling capacity.

Effects of Anisotropic Thermal Conductivity in Magnetohydrodynamics Simulations of a Reversed-Field Pinch

International Nuclear Information System (INIS)

Onofri, M.; Malara, F.; Veltri, P.

2010-01-01

A compressible magnetohydrodynamics simulation of the reversed-field pinch is performed including anisotropic thermal conductivity. When the thermal conductivity is much larger in the direction parallel to the magnetic field than in the perpendicular direction, magnetic field lines become isothermal. As a consequence, as long as magnetic surfaces exist, a temperature distribution is observed displaying a hotter confined region, while an almost uniform temperature is produced when the magnetic field lines become chaotic. To include this effect in the numerical simulation, we use a multiple-time-scale analysis, which allows us to reproduce the effect of a large parallel thermal conductivity. The resulting temperature distribution is related to the existence of closed magnetic surfaces, as observed in experiments. The magnetic field is also affected by the presence of an anisotropic thermal conductivity.

Anisotropic elliptic optical fibers

Science.gov (United States)

Kang, Soon Ahm

1991-05-01

The exact characteristic equation for an anisotropic elliptic optical fiber is obtained for odd and even hybrid modes in terms of infinite determinants utilizing Mathieu and modified Mathieu functions. A simplified characteristic equation is obtained by applying the weakly guiding approximation such that the difference in the refractive indices of the core and the cladding is small. The simplified characteristic equation is used to compute the normalized guide wavelength for an elliptical fiber. When the anisotropic parameter is equal to unity, the results are compared with the previous research and they are in close agreement. For a fixed value normalized cross-section area or major axis, the normalized guide wavelength lambda/lambda(sub 0) for an anisotropic elliptic fiber is small for the larger value of anisotropy. This condition indicates that more energy is carried inside of the fiber. However, the geometry and anisotropy of the fiber have a smaller effect when the normalized cross-section area is very small or very large.

Modelling and comparison studies of packed screen regenerators for active magnetocaloric refrigeration

DEFF Research Database (Denmark)

Lei, Tian; Engelbrecht, Kurt; Nielsen, K. K.

2011-01-01

In active magnetic regeneration (AMR) systems, not only the magnetocaloric properties of materials, but also the regenerator geometry plays an important role in the system performance. Packed sphere regenerators are often employed in existing prototypes, however, the characteristics such as relat...... is improved and applied to simulate the regenerators. The performance of the new regenerators is studied and compared with that of the packed sphere regenerators. Possible fabrication methods of the packed screen regenerators are also discussed....

Modelling and comparison studies of packed screen regenerators for active magnetocaloric refrigeration

DEFF Research Database (Denmark)

Lei, Tian; Engelbrecht, Kurt; Nielsen, Kaspar Kirstein

2014-01-01

In active magnetic regeneration (AMR) systems, not only the magnetocaloric properties of materials, but also the regenerator geometry plays an important role in the system performance. Packed sphere regenerators are often employed in existing prototypes, however, the characteristics such as relat...... is improved and applied to simulate the regenerators. The performance of the new regenerators is studied and compared with that of the packed sphere regenerators. Possible fabrication methods of the packed screen regenerators are also discussed....

Tuning the magnetocaloric response in half-Heusler/Heusler MnNi1 +xSb solid solutions

Science.gov (United States)

Levin, Emily E.; Bocarsly, Joshua D.; Wyckoff, Kira E.; Pollock, Tresa M.; Seshadri, Ram

2017-12-01

Materials with a large magnetocaloric response are associated with a temperature change upon the application of a magnetic field and are of interest for applications in magnetic refrigeration and thermomagnetic power generation. The usual metric of this response is the gravimetric isothermal entropy change Δ SM . The use of a simple proxy for the Δ SM that is based on density functional theory (DFT) calculations of the magnetic electronic structure suggests that half-Heusler MnNiSb should be a better magnetocaloric than the corresponding Heusler compound MnNi2Sb . Guided by this observation, we present a study of MnNi1 +xSb (x =0 , 0.25, 0.5, 0.75, and 1.0) to evaluate relevant structural and magnetic properties. DFT stability calculations suggest that the addition of Ni takes place at a symmetrically distinct Ni site in the half-Heusler structure and support the observation using synchrotron x-ray diffraction of a homogeneous solid solution between the half-Heusler and Heusler end members. There is a maximum in the saturation magnetization at x =0.5 and the Curie temperature systematically decreases with increasing x . Δ SM for a maximum magnetic field change of Δ H =5 T monotonically decreases in magnitude from -2.93 J kg-1K-1 in the half-Heusler to -1.35 J kg-1K-1 in the Heusler compound. The concurrent broadening of the magnetic transition results in a maximum in the refrigerant capacity at x =0.75 . The Curie temperature of this system is highly tunable between 350 K and 750 K, making it ideal for low grade waste heat recovery via thermomagnetic power generation. The increase in Δ SM with decreasing x may be extendable to other MnNi2Z Heusler systems that are currently under investigation for use in magnetocaloric refrigeration applications.

Phase transitions, magnetotransport and magnetocaloric effects in a new family of quaternary Ni-Mn-In-Z Heusler alloys.

Science.gov (United States)

Kazakov, Alexander; Prudnikov, Valerii; Granovsky, Alexander; Perov, Nikolai; Dubenko, Igor; Pathak, Arjun Kumar; Samanta, Tapas; Stadler, Shane; Ali, Naushad; Zhukov, Arcady; Ilyin, Maxim; Gonzalez, Julian

2012-09-01

The magnetic, magnetotransport, and magnetocaloric properties near compound phase transitions in Ni50Mn35In14Z (Z = In, Ge, Al), and Ni48Co2Mn35In15 Heusler alloys have been studied using VSM and SQUID magnetometers (at magnetic fields (H) up to 5 T), four-probe method (at H = 0.005-1.5 T), and an adiabatic magnetocalorimeter (for H changes up to deltaH = 1.8 T), respectively. The martensitic transformation (MT) is accompanied by large magnetoresistance (up to 70%), a significant change in resistivity (up to 200%), and a sign reversal of the ordinary Hall effect coefficient, all related to a strong change in the electronic spectrum at the MT. The field dependences of the Hall resistance are complex in the vicinity of the MT, indicating a change in the relative concentrations of the austenite and martensite phases at strong fields. Negative and positive changes in adiabatic temperatures of about -2 K and +2 K have been observed in the vicinity of MT and Curie temperatures, respectively, for deltaH = 1.8 T.

Glass formation ability, structure and magnetocaloric effect of a heavy rare-earth bulk metallic glassy Gd{sub 55}Co{sub 20}Fe{sub 5}Al{sub 20} alloy

Energy Technology Data Exchange (ETDEWEB)

Jo, C.-L. [Shanghai University, School of Materials Science and Engineering, Yanchang Road 149, Zhabei District, 200072 Shanghai (China)], E-mail: jochollong@163.com; Xia Lei; Ding Ding; Dong Yuanda; Gracien, Ekoko [Shanghai University, School of Materials Science and Engineering, Yanchang Road 149, Zhabei District, 200072 Shanghai (China)

2008-06-30

The glass formation ability, the structure and the magnetocaloric effect of the bulk metallic glassy Gd{sub 55}Co{sub 20}Fe{sub 5}Al{sub 20} alloy were investigated. Bulk metallic glassy (BMGs) alloys were prepared by a copper-mold casting method. The glass forming ability and their structure were studied by using X-ray diffraction (XRD) and differential scanning calorimeter (DSC). The XRD analysis revealed that the as-cast cylinder of Gd{sub 55}Co{sub 20}Fe{sub 5}Al{sub 20} alloy showed fully amorphous structure in 2 mm diameter. The DSC revealed that the bulk cylinder of the Gd{sub 55}Co{sub 20}Fe{sub 5}Al{sub 20} alloy showed a distinct glass transition temperature and a relatively wide supercooled liquid region before crystallization. SQUID investigated the magnetic properties and the entropy changes. The Curie temperature of Gd{sub 55}Co{sub 20}Fe{sub 5}Al{sub 20} BMGs alloy was about 130 K, but the maximum magnetic entropy changes(-{delta}S{sub M}) showed at about 125 K, a little lower than the Curie temperature 130 K. The reason could probably be due to the presence of a little amount of nanocrystalline particles between amorphous phases. The BMG alloy has the characteristic of second-order transition (SOT) on Arrott plots. The results showed that the amorphous sample had a relatively improved magnetocaloric effect, indicating that the amorphous alloy could be considered as a candidate for magnetic refrigeration applications in the temperature interval range of 100-200 K.

Giant anisotropic magnetoresistance and planar Hall effect in the Dirac semimetal Cd3As2

Science.gov (United States)

Li, Hui; Wang, Huan-Wen; He, Hongtao; Wang, Jiannong; Shen, Shun-Qing

2018-05-01

Anisotropic magnetoresistance is the change tendency of resistance of a material on the mutual orientation of the electric current and the external magnetic field. Here, we report experimental observations in the Dirac semimetal Cd3As2 of giant anisotropic magnetoresistance and its transverse version, called the planar Hall effect. The relative anisotropic magnetoresistance is negative and up to -68% at 2 K and 10 T. The high anisotropy and the minus sign in this isotropic and nonmagnetic material are attributed to a field-dependent current along the magnetic field, which may be induced by the Berry curvature of the band structure. This observation not only reveals unusual physical phenomena in Weyl and Dirac semimetals, but also finds additional transport signatures of Weyl and Dirac fermions other than negative magnetoresistance.

The crystal and magnetic structure of the magnetocaloric compound FeMnP(0.5)Si(0.5)

Czech Academy of Sciences Publication Activity Database

Hoglin, V.; Hudl, M.; Sahlberg, M.; Nordblad, P.; Beran, Přemysl; Anderson, I.

2011-01-01

Roč. 184, č. 9 (2011), s. 2434-2438 ISSN 0022-4596 Institutional research plan: CEZ:AV0Z10480505 Keywords : Magnetocaloric * Neutron powder diffraction * X-ray diffraction (XRD) * Magnetic refrigeration * Magnetic structure Subject RIV: CA - Inorganic Chemistry Impact factor: 2.159, year: 2011

Local fields and effective conductivity tensor of ellipsoidal particle composite with anisotropic constituents

Science.gov (United States)

Kushch, Volodymyr I.; Sevostianov, Igor; Giraud, Albert

2017-11-01

An accurate semi-analytical solution of the conductivity problem for a composite with anisotropic matrix and arbitrarily oriented anisotropic ellipsoidal inhomogeneities has been obtained. The developed approach combines the superposition principle with the multipole expansion of perturbation fields of inhomogeneities in terms of ellipsoidal harmonics and reduces the boundary value problem to an infinite system of linear algebraic equations for the induced multipole moments of inhomogeneities. A complete full-field solution is obtained for the multi-particle models comprising inhomogeneities of diverse shape, size, orientation and properties which enables an adequate account for the microstructure parameters. The solution is valid for the general-type anisotropy of constituents and arbitrary orientation of the orthotropy axes. The effective conductivity tensor of the particulate composite with anisotropic constituents is evaluated in the framework of the generalized Maxwell homogenization scheme. Application of the developed method to composites with imperfect ellipsoidal interfaces is straightforward. Their incorporation yields probably the most general model of a composite that may be considered in the framework of analytical approach.

Effect of Fe substitution on magnetocaloric effect in La{sub 0.7}Sr{sub 0.3}Mn{sub 1-x}Fe{sub x}O{sub 3} (0.05{<=}x{<=}0.20)

Energy Technology Data Exchange (ETDEWEB)

Barik, S K; Krishnamoorthi, C [Department of Physics and NUS Nanoscience and Nanotechnology Initiative, 2 Science Drive 3, National University of Singapore, Singapore 117542, Singapore. (Singapore); Mahendiran, R [Department of Physics and NUS Nanoscience and Nanotechnology Initiative, 2 Science Drive 3, National University of Singapore, Singapore 117542, Singapore. (Singapore)

2011-04-15

We have studied the effect of Fe substitution on magnetic and magnetocaloric properties in La{sub 0.7}Sr{sub 0.3}Mn{sub 1-x}Fe{sub x}O{sub 3} (x=0.05, 0.07, 0.10, 0.15, and 0.20) over a wide temperature range (T=10-400 K). It is shown that substitution by Fe gradually decreases the ferromagnetic Curie temperature (T{sub C}) and saturation magnetization up to x=0.15 but a dramatic change occurs for x=0.2. The x=0.2 sample can be considered as a phase separated compound in which both short-range ordered ferromagnetic and antiferromagnetic phases coexist. The magnetic entropy change (-{Delta}S{sub m}) was estimated from isothermal magnetization curves and it decreases with increase of Fe content from 4.4 J kg{sup -1} K{sup -1} at 343 K (x=0.05) to 1.3 J kg{sup -1} K{sup -1} at 105 K (x=0.2), under {Delta}H=5 T. The La{sub 0.7}Sr{sub 0.3}Mn{sub 0.93}Fe{sub 0.07}O{sub 3} sample shows negligible hysteresis loss, operating temperature range over 60 K around room temperature with refrigerant capacity of 225 J kg{sup -1}, and magnetic entropy of 4 J kg{sup -1} K{sup -1} which will be an interesting compound for application in room temperature refrigeration. - Research highlights: > We report magnetocaloric effect in La{sub 0.7}Sr{sub 0.3}Mn{sub 1-x}Fe{sub x}O{sub 3} (x=0-0.2). > Magnetic entropy change ({Delta}S{sub m}) decreases with increasing x. > A large {Delta}S{sub m} and refrigeration capacity are found around 300 K in x=0.07.

Magnetic hysterysis evolution of Ni-Al alloy with Fe and Mn substitution by vacuum arc melting to produce the room temperature magnetocaloric effect material

Energy Technology Data Exchange (ETDEWEB)

Notonegoro, Hamdan Akbar [PPS Materials Science, FMIPA-Universitas Indonesia, Depok 16424 (Indonesia); Mechanical Engineering Dept., FT-Universitas Sultan Ageng Tirtayasa, Cilegon 42435 (Indonesia); Kurniawan, Budhy; Manaf, Azwar, E-mail: azwar@sci.ui.ac.id [PPS Materials Science, FMIPA-Universitas Indonesia, Depok 16424 (Indonesia); Setiawan, Jan [Center for Nuclear Fuel Tecnology-Badan Tenaga Atom Nasional, Tangerang Selatan 15310 (Indonesia)

2016-06-17

The development of magnetocaloric effect (MCE) material is done in order to reduce the damage of the ozone layer caused by the chlorofluorocarbons (CFCs) emitted into the air. The research dealing with synthesis of magnetocaloric materials based of Ni-Al Heusler Alloy structure and by varying substitution some atoms of Ni with Fe and Al with Mn on Ni-Al Heusler Alloy structure to become Ni{sub 44}Fe{sub 6}Mn{sub 32}Al{sub 18}. Vacuum Arc Melting (VAM) equipment is used to form the alloys on vacuum condition and by flowing argon gas atmosphere and then followed by annealing process for 72 hours. X-Ray Diffraction (XRD) reveals that crystallite structure of material is observed. We define that Ni{sub 44}Fe{sub 6} as X{sub 2}, Mn{sub 25} as Y, and Al{sub 18}Mn{sub 7} as Z. Based on the XRD result, we observed that the general formula X{sub 2}YZ is not changed. The PERMAGRAF measurement revealed that there exists of magnetic hysterysis. The hysterysis show that the magnetic structures of the system undego evolution from diamagnetic to soft ferromagnetic material which all of the compound have the same crystallite structure. This evolution indicated that the change in the composition has led to changes the magnetic composition. Mn is the major element that gives strong magnetic properties to the sample. When Mn partially replaced position of Al, the sample became dominant to be influenced to improve their magnetic properties. In addition, substitution a part of Ni by Fe in the composition reveals a pinning of the domain walls in the sample.

Anisotropic solutions by gravitational decoupling

Science.gov (United States)

Ovalle, J.; Casadio, R.; da Rocha, R.; Sotomayor, A.

2018-02-01

We investigate the extension of isotropic interior solutions for static self-gravitating systems to include the effects of anisotropic spherically symmetric gravitational sources by means of the gravitational decoupling realised via the minimal geometric deformation approach. In particular, the matching conditions at the surface of the star with the outer Schwarzschild space-time are studied in great detail, and we describe how to generate, from a single physically acceptable isotropic solution, new families of anisotropic solutions whose physical acceptability is also inherited from their isotropic parent.

Anisotropic solutions by gravitational decoupling

Energy Technology Data Exchange (ETDEWEB)

Ovalle, J. [Silesian University in Opava, Institute of Physics and Research Centre of Theoretical Physics and Astrophysics, Faculty of Philosophy and Science, Opava (Czech Republic); Universidad Simon Bolivar, Departamento de Fisica, Caracas (Venezuela, Bolivarian Republic of); Casadio, R. [Alma Mater Universita di Bologna, Dipartimento di Fisica e Astronomia, Bologna (Italy); Istituto Nazionale di Fisica Nucleare, Bologna (Italy); Rocha, R. da [Universidade Federal do ABC (UFABC), Centro de Matematica, Computacao e Cognicao, Santo Andre, SP (Brazil); Sotomayor, A. [Universidad de Antofagasta, Departamento de Matematicas, Antofagasta (Chile)

2018-02-15

We investigate the extension of isotropic interior solutions for static self-gravitating systems to include the effects of anisotropic spherically symmetric gravitational sources by means of the gravitational decoupling realised via the minimal geometric deformation approach. In particular, the matching conditions at the surface of the star with the outer Schwarzschild space-time are studied in great detail, and we describe how to generate, from a single physically acceptable isotropic solution, new families of anisotropic solutions whose physical acceptability is also inherited from their isotropic parent. (orig.)

Magnetocaloric effect and transport properties of Gd5Ge2(Si1-x Sn x )2 (x=0.23 and 0.40) compounds

International Nuclear Information System (INIS)

Campoy, J.C.P.; Plaza, E.J.R.; Nascimento, F.C.; Coelho, A.A.; Pereira, M.C.; Fabris, J.D.; Raposo, M.T.; Cardoso, L.P.; Persiano, A.I.C.; Gama, S.

2007-01-01

We report a study about the structural properties of polycrystalline samples of nominal composition Gd 5 Ge 2 (Si 1- x Sn x ) 2 (x=0.23, 0.40) that closely influence their physical behavior particularly related to electric resistivity and magnetocaloric (MCE) effect. The samples were characterized by X-ray diffraction (XRD) using the Rietveld refinement method, metallographic analyses, 119 Sn Moessbauer spectroscopy, DC magnetization and electrical transport measurements. It was identified a Gd 5 Si 2 Ge 2 -monoclinic phase for x=0.23 and a Sm 5 Sn 4 -orthorhombic phase (type II) for x=0.40, both with two non-equivalent crystallographic sites for the Sn ions. We were able to infer on the role of tin on the magnetic and transport properties in these compounds

Anisotropic gravitational instability

International Nuclear Information System (INIS)

Polyachenko, V.L.; Fridman, A.M.

1988-01-01

Exact solutions of stability problems are obtained for two anisotropic gravitational systems of different geometries - a layer of finite thickness at rest and a rotating cylinder of finite radius. It is shown that the anisotropic gravitational instability which develops in both cases is of Jeans type. However, in contrast to the classical aperiodic Jeans instability, this instability is oscillatory. The physics of the anisotropic gravitational instability is investigated. It is shown that in a gravitating layer this instability is due, in particular, to excitation of previously unknown interchange-Jeans modes. In the cylinder, the oscillatory Jeans instability is associated with excitation of a rotational branch, this also being responsible for the beam gravitational instability. This is the reason why this instability and the anisotropic gravitational instability have so much in common

A Preisach approach to modeling partial phase transitions in the first order magnetocaloric material MnFe(P,As)

Energy Technology Data Exchange (ETDEWEB)

Moos, L. von, E-mail: lmoo@dtu.dk [Department of Energy Conversion and Storage, Technical University of Denmark, 4000 Roskilde (Denmark); Bahl, C.R.H.; Nielsen, K.K.; Engelbrecht, K. [Department of Energy Conversion and Storage, Technical University of Denmark, 4000 Roskilde (Denmark); Küpferling, M.; Basso, V. [Istituto Nazionale di Ricerca Metrologica, 10135 Torino (Italy)

2014-02-15

Magnetic refrigeration is an emerging technology that could provide energy efficient and environmentally friendly cooling. Magnetocaloric materials in which a structural phase transition is found concurrently with the magnetic phase transition are often termed first order magnetocaloric materials. Such materials are potential candidates for application in magnetic refrigeration devices. However, the first order materials often have adverse properties such as hysteresis, making actual performance troublesome to quantify, a subject not thoroughly studied within this field. Here we investigate the behavior of MnFe(P,As) under partial phase transitions, which is similar to what materials experience in actual magnetic refrigeration devices. Partial phase transition curves, in the absence of a magnetic field, are measured using calorimetry and the experimental results are compared to simulations of a Preisach-type model. We show that this approach is applicable and discuss what experimental data is required to obtain a satisfactory material model.

Anisotropic constant-roll inflation

Energy Technology Data Exchange (ETDEWEB)

Ito, Asuka; Soda, Jiro [Kobe University, Department of Physics, Kobe (Japan)

2018-01-15

We study constant-roll inflation in the presence of a gauge field coupled to an inflaton. By imposing the constant anisotropy condition, we find new exact anisotropic constant-roll inflationary solutions which include anisotropic power-law inflation as a special case. We also numerically show that the new anisotropic solutions are attractors in the phase space. (orig.)

Anisotropic hydrodynamics, holography and the chiral magnetic effect

International Nuclear Information System (INIS)

Gahramanov, Ilmar; Kalaydzhyan, Tigran; Kirsch, Ingo; Hamburg Univ.

2012-03-01

We discuss a possible dependence of the chiral magnetic effect (CME) on the elliptic flow coefficient υ 2 . We first study this in a hydrodynamic model for a static anisotropic plasma with multiple anomalous U(1) currents. In the case of two charges, one axial and one vector, the CME formally appears as a first-order transport coefficient in the vector current. We compute this transport coefficient and show its dependence on υ 2 . We also determine the CME-coefficient from first-order corrections to the dual AdS background using the fluid-gravity duality. For small anisotropies, we find numerical agreement with the hydrodynamic result. (orig.)

Anisotropic hydrodynamics, holography and the chiral magnetic effect

Energy Technology Data Exchange (ETDEWEB)

Gahramanov, Ilmar; Kalaydzhyan, Tigran; Kirsch, Ingo [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Hamburg Univ. (Germany). Zentrum fuer Mathematische Physik

2012-03-15

We discuss a possible dependence of the chiral magnetic effect (CME) on the elliptic flow coefficient {upsilon}{sub 2}. We first study this in a hydrodynamic model for a static anisotropic plasma with multiple anomalous U(1) currents. In the case of two charges, one axial and one vector, the CME formally appears as a first-order transport coefficient in the vector current. We compute this transport coefficient and show its dependence on {upsilon}{sub 2}. We also determine the CME-coefficient from first-order corrections to the dual AdS background using the fluid-gravity duality. For small anisotropies, we find numerical agreement with the hydrodynamic result. (orig.)

Orientation dependent size effects in single crystalline anisotropic nanoplates with regard to surface energy

International Nuclear Information System (INIS)

Assadi, Abbas; Salehi, Manouchehr; Akhlaghi, Mehdi

2015-01-01

In this work, size dependent behavior of single crystalline normal and auxetic anisotropic nanoplates is discussed with consideration of material surface stresses via a generalized model. Bending of pressurized nanoplates and their fundamental resonant frequency are discussed for different crystallographic directions and anisotropy degrees. It is explained that the orientation effects are considerable when the nanoplates' edges are pinned but for clamped nanoplates, the anisotropy effect may be ignored. The size effects are the highest when the simply supported nanoplates are parallel to [110] direction but as the anisotropy gets higher, the size effects are reduced. The orientation effect is also discussed for possibility of self-instability occurrence in nanoplates. The results in simpler cases are compared with previous experiments for nanowires but with a correction factor. There are still some open questions for future studies. - Highlights: • Size effects in single crystalline anisotropic nanoplates are discussed. • A generalized model is established containing some physical assumptions. • Orientation dependent size effects due to material anisotropy are explained. • Bending, instability and frequencies are studied at normal/auxetic domain

Efficient anisotropic wavefield extrapolation using effective isotropic models

KAUST Repository

Alkhalifah, Tariq Ali; Ma, X.; Waheed, Umair bin; Zuberi, Mohammad

2013-01-01

Isotropic wavefield extrapolation is more efficient than anisotropic extrapolation, and this is especially true when the anisotropy of the medium is tilted (from the vertical). We use the kinematics of the wavefield, appropriately represented

Influence of Fe doped on the magnetocaloric behavior of La_{{2}/{3}} Ca_{{1}/{3}} Mn1-x Fe x O3 compounds: a Monte Carlo simulation

Science.gov (United States)

Alzate-Cardona, J. D.; Barco-Rios, H.; Restrepo-Parra, E.

2018-02-01

The magnetocaloric behavior of La{2/{3}} Ca{1/{3}} Mn1-x Fe x O3 for x  =  0.00, 0.02, 0.03, 0.05, 0.07, 0.08 and 0.10 under the influence of an external magnetic field was simulated and analyzed. Simulations were carried out using the Monte Carlo method and the classical Heisenberg model under the Metropolis algorithm. These mixed valence manganites are characterized by having three types of magnetic ions corresponding to Mn4+≤ft(S=\\frac{3}{2}\\right) , which are bonded with Ca2+ , and Mneg3+ and Mneg\\prime3+ (S=2) , related to La3+ . The Fe ions were randomly included, replacing Mn ions. With this model, the magnetic entropy change, Δ S , in an isothermal process was determined. -Δ Sm showed maximum peaks around the paramagnetic-ferromagnetic transition temperature, which depends on Fe doping. Relative cooling power was computed for different Fe concentrations varying the magnetic applied field. Our model and results show that the Fe doping decreases the magnetocaloric effect in the La{2/{3}} Ca{1/{3}} Mn1-x Fe x O3, making this a bad candidate for magnetic refrigeration. The strong dependence of the magnetocaloric behavior on Fe doping and the external magnetic field in La{2/{3}} Ca{1/{3}} Mn1-x Fe x O3 can boost these materials for the future technological applications.

Highly Sensitive Flexible Magnetic Sensor Based on Anisotropic Magnetoresistance Effect.

Science.gov (United States)

Wang, Zhiguang; Wang, Xinjun; Li, Menghui; Gao, Yuan; Hu, Zhongqiang; Nan, Tianxiang; Liang, Xianfeng; Chen, Huaihao; Yang, Jia; Cash, Syd; Sun, Nian-Xiang

2016-11-01

A highly sensitive flexible magnetic sensor based on the anisotropic magnetoresistance effect is fabricated. A limit of detection of 150 nT is observed and excellent deformation stability is achieved after wrapping of the flexible sensor, with bending radii down to 5 mm. The flexible AMR sensor is used to read a magnetic pattern with a thickness of 10 μm that is formed by ferrite magnetic inks. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Magneto-caloric effect in the pseudo-binary intermetallic YPrFe{sub 17} compound

Energy Technology Data Exchange (ETDEWEB)

Alvarez, Pablo [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain); Gorria, Pedro, E-mail: pgorria@uniovi.es [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain); Sanchez Llamazares, Jose L. [Division de Materiales Avanzados, Instituto Potosino de Investigacion Cientifica y Tecnologica, Camino a la presa San Jose 2055, CP 78216, San Luis Potosi (Mexico); Perez, Maria J. [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain); Franco, Victorino [Departamento de Fisica de la Materia Condensada, ICMSE-CSIC, Universidad de Sevilla, P.O. Box 1065, 41080 Sevilla (Spain); Reiffers, Marian; Kovac, Jozef [Institute of Experimental Physics, Watsonova 47, SK-04001 Kosice (Slovakia); Puente-Orench, Ines [Institute Laue Langevin, 6 rue Jules Horowitz, 38042 Grenoble (France); Blanco, Jesus A. [Departamento de Fisica, Universidad de Oviedo, Calvo Sotelo, s/n, 33007 Oviedo (Spain)

2011-12-15

Highlights: Black-Right-Pointing-Pointer YPrFe{sub 17} exhibits a broad {Delta}S{sub M}(T) associated with the ferro-to-paramagnetic phase transition (T{sub C} Almost-Equal-To 290 K). Black-Right-Pointing-Pointer We obtain |{Delta}S{sub M}| Almost-Equal-To 2.3 J kg{sup -1} K{sup -1} and RCP Almost-Equal-To 100 J kg{sup -1}for a magnetic field change of 1.5 T. Black-Right-Pointing-Pointer A single master curve for {Delta}S{sub M} is found when compared with other isostructural R{sub 2}Fe{sub 17} binary alloys. - Abstract: We have synthesized the intermetallic YPrFe{sub 17} compound by arc-melting. X-ray and neutron powder diffraction show that the crystal structure is rhombohedral with R3{sup Macron }m space group (Th{sub 2}Zn{sub 17}-type). The investigated compound exhibits a broad isothermal magnetic entropy change {Delta}S{sub M}(T) associated with the ferro-to-paramagnetic phase transition (T{sub C} Almost-Equal-To 290 K). The |{Delta}S{sub M}| ( Almost-Equal-To 2.3 J kg{sup -1} K{sup -1}) and the relative cooling power ( Almost-Equal-To 100 J kg{sup -1}) have been calculated for applied magnetic field changes up to 1.5 T. A single master curve for {Delta}S{sub M} under different values of the magnetic field change can be obtained by a rescaling of the temperature axis. The results are compared and discussed in terms of the magneto-caloric effect in the isostructural R{sub 2}Fe{sub 17} (R = Y, Pr and Nd) binary intermetallic alloys.

Anomalous Skin Effect for Anisotropic Electron Velocity Distribution Function

International Nuclear Information System (INIS)

Igor Kaganovich; Edward Startsev; Gennady Shvets

2004-01-01

The anomalous skin effect in a plasma with a highly anisotropic electron velocity distribution function (EVDF) is very different from skin effect in a plasma with the isotropic EVDF. An analytical solution was derived for the electric field penetrated into plasma with the EVDF described as a Maxwellian with two temperatures Tx >> Tz, where x is the direction along the plasma boundary and z is the direction perpendicular to the plasma boundary. The skin layer was found to consist of two distinctive regions of width of order nTx/w and nTz/w, where nTx,z/w = (Tx,z/m)1/2 is the thermal electron velocity and w is the incident wave frequency

Magnetocaloric effect in gadolinium-oxalate framework Gd2(C2O4)3(H2O)6⋅(0⋅6H2O)

International Nuclear Information System (INIS)

Sibille, Romain; Didelot, Emilie; Mazet, Thomas; Malaman, Bernard; François, Michel

2014-01-01

Magnetic refrigerants incorporating Gd 3+ ions and light organic ligands offer a good balance between isolation of the magnetic centers and their density. We synthesized the framework material Gd 2 (C 2 O 4 ) 3 (H 2 O) 6 ⋅0.6H 2 O by a hydrothermal route and characterized its structure. The honeycomb lattice of Gd 3+ ions interlinked by oxalate ligands in the (a,c) plane ensures their decoupling in terms of magnetic exchange interactions. This is corroborated by magnetic measurements indicating negligible interactions between the Gd 3+ ions in this material. The magnetocaloric effect was evaluated from isothermal magnetization measurements. The maximum entropy change −ΔS M max reaches 75.9 mJ cm −3 K −1 (around 2 K) for a moderate field change (2 T)

Adiabatic physics of an exchange-coupled spin-dimer system: Magnetocaloric effect, zero-point fluctuations, and possible two-dimensional universal behavior

International Nuclear Information System (INIS)

Brambleby, J.; Goddard, P. A.; Singleton, John; Jaime, Marcelo; Lancaster, T.

2017-01-01

We present the magnetic and thermal properties of the bosonic-superfluid phase in a spin-dimer network using both quasistatic and rapidly changing pulsed magnetic fields. The entropy derived from a heat-capacity study reveals that the pulsed-field measurements are strongly adiabatic in nature and are responsible for the onset of a significant magnetocaloric effect (MCE). In contrast to previous predictions we show that the MCE is not just confined to the critical regions, but occurs for all fields greater than zero at sufficiently low temperatures. We explain the MCE using a model of the thermal occupation of exchange-coupled dimer spin states and highlight that failure to take this effect into account inevitably leads to incorrect interpretations of experimental results. In addition, the heat capacity in our material is suggestive of an extraordinary contribution from zero-point fluctuations and appears to indicate universal behavior with different critical exponents at the two field-induced critical points. Finally, the data at the upper critical point, combined with the layered structure of the system, are consistent with a two-dimensional nature of spin excitations in the system.

Microstructural effect on radiative scattering coefficient and asymmetry factor of anisotropic thermal barrier coatings

Science.gov (United States)

Chen, X. W.; Zhao, C. Y.; Wang, B. X.

2018-05-01

Thermal barrier coatings are common porous materials coated on the surface of devices operating under high temperatures and designed for heat insulation. This study presents a comprehensive investigation on the microstructural effect on radiative scattering coefficient and asymmetry factor of anisotropic thermal barrier coatings. Based on the quartet structure generation set algorithm, the finite-difference-time-domain method is applied to calculate angular scattering intensity distribution of complicated random microstructure, which takes wave nature into account. Combining Monte Carlo method with Particle Swarm Optimization, asymmetry factor, scattering coefficient and absorption coefficient are retrieved simultaneously. The retrieved radiative properties are identified with the angular scattering intensity distribution under different pore shapes, which takes dependent scattering and anisotropic pore shape into account implicitly. It has been found that microstructure significantly affects the radiative properties in thermal barrier coatings. Compared with spherical shape, irregular anisotropic pore shape reduces the forward scattering peak. The method used in this paper can also be applied to other porous media, which designs a frame work for further quantitative study on porous media.

Gd.sub.90./sub.Co.sub.2.5./sub.Fe.sub.7.5./sub. alloy displaying enhanced magnetocaloric properties.

Czech Academy of Sciences Publication Activity Database

Provenzano, V.; Shull, R. D.; Kletetschka, Günther; Stutzman, P. E.

2015-01-01

Roč. 622, February (2015), s. 1061-1067 ISSN 0925-8388 Institutional support: RVO:67985831 Keywords : magnetocaloric properties * bulk gadolinium * gadolinium-based alloy * magnetic refrigeration * magnetic hysteresis * refrigeration capacity Subject RIV: DE - Earth Magnetism, Geodesy, Geography Impact factor: 3.014, year: 2015

Speckle Suppression by Weighted Euclidean Distance Anisotropic Diffusion

Directory of Open Access Journals (Sweden)

Fengcheng Guo

2018-05-01

Full Text Available To better reduce image speckle noise while also maintaining edge information in synthetic aperture radar (SAR images, we propose a novel anisotropic diffusion algorithm using weighted Euclidean distance (WEDAD. Presented here is a modified speckle reducing anisotropic diffusion (SRAD method, which constructs a new edge detection operator using weighted Euclidean distances. The new edge detection operator can adaptively distinguish between homogenous and heterogeneous image regions, effectively generate anisotropic diffusion coefficients for each image pixel, and filter each pixel at different scales. Additionally, the effects of two different weighting methods (Gaussian weighting and non-linear weighting of de-noising were analyzed. The effect of different adjustment coefficient settings on speckle suppression was also explored. A series of experiments were conducted using an added noise image, GF-3 SAR image, and YG-29 SAR image. The experimental results demonstrate that the proposed method can not only significantly suppress speckle, thus improving the visual effects, but also better preserve the edge information of images.

Study of magnetic, structural and magnetocaloric properties of La{sub 0.6}Pr{sub 0.4}Mn{sub 2}Si{sub 2} under high pressures and magnetic field

Energy Technology Data Exchange (ETDEWEB)

Kaštil, J., E-mail: kastil@fzu.cz [Institute of Physics AS CR v.v.i., Na Slovance 2, 182 21 Prague 8 (Czech Republic); Arnold, Z. [Institute of Physics AS CR v.v.i., Na Slovance 2, 182 21 Prague 8 (Czech Republic); Isnard, O. [Centre national de la recherche scientifique (CNRS), Institut Néel, 25 rus des martyrs, F-38042 Grenoble (France); Université Grenoble Alpes, Institut Néel, F-38042 Grenoble (France); Skourski, Y. [Hochfeld-Magnetlabor Dresden (HLD), HZ Dresden-Rossendorf, D-01314 Dresden (Germany); Kamarád, J. [Institute of Physics AS CR v.v.i., Na Slovance 2, 182 21 Prague 8 (Czech Republic); Itié, J.P. [Synchrotron SOLEIL, L' Orme des Merisiers, Saint-Aubin, 91192 Gif-sur-Yvette (France)

2017-02-15

The structural, magnetic and magnetocaloric properties of La{sub 0.6}Pr{sub 0.4}Mn{sub 2}Si{sub 2} compound were measured in wide range of temperature, magnetic field and hydrostatic pressure. The structural study up to 10 GPa confirmed the existence of critical Mn-Mn distance 0.2883 nm for the ferromagnetic to antiferromagnetic transition at room temperature. The results demonstrated the crucial role of the volume in the suppression of the ferromagnetic phase above the transition temperature T{sub 1}=168 K under pressure. The huge pressure shift of the transition temperature T{sub 1}, dT{sub 1}/dp=230 K/GPa, was observed. Based on our magnetization measurement the low temperature transition at T{sub 2}=30 K is connected with reorientation of Mn moment and the rare-earth sublattice is not ordered in this case. The direct magnetocaloric measurement showed moderate values of the adiabatic temperature change connected with the magnetic transition at T{sub c} and T{sub 1} and confirmed the first order character of the transition at T{sub 1} and second order character of the transition at T{sub c}. - Highlights: • The huge pressure shift of the transition temperature dT{sub 1}/dp=230 K/GPa was observed. • Ferromagnetic order is suppressed by applying pressure of 1 GPa. • The direct magnetocaloric effect showed moderate values of ΔT{sub ad}.

Thermal properties of heavy fermion systems under unaxial and hydrostatic pressure: Anisotropic magnetic ordering in CeCu6-xAux and (B,T,p) phase diagram of UPt3

International Nuclear Information System (INIS)

Sieck, M.

1996-01-01

Single crystal samples of heavy fermion systems UPt 3 and CeCu 6-x Au x have been investigated under hydrostatic and uniaxial pressure, respectively, at low temperatures and in magnetic fields up to 3 T using measurements of the specific heat and the magnetocaloric effect. A light-weigth hydrostatic pressure cell made of CuBe was designed and built up. For CeCu 6-x Au x the interrelation between magnetic order and the non-magnetic ground state was studied as function of Au concentration. For the UPt 3 system the phase diagrams in the superconducting state has been constructed. In the magnetocaloric effect irreversibilities due to flux pinning in the flux line lattice were observed

Two-point anchoring of a lanthanide-binding peptide to a target protein enhances the paramagnetic anisotropic effect

International Nuclear Information System (INIS)

Saio, Tomohide; Ogura, Kenji; Yokochi, Masashi; Kobashigawa, Yoshihiro; Inagaki, Fuyuhiko

2009-01-01

Paramagnetic lanthanide ions fixed in a protein frame induce several paramagnetic effects such as pseudo-contact shifts and residual dipolar couplings. These effects provide long-range distance and angular information for proteins and, therefore, are valuable in protein structural analysis. However, until recently this approach had been restricted to metal-binding proteins, but now it has become applicable to non-metalloproteins through the use of a lanthanide-binding tag. Here we report a lanthanide-binding peptide tag anchored via two points to the target proteins. Compared to conventional single-point attached tags, the two-point linked tag provides two to threefold stronger anisotropic effects. Though there is slight residual mobility of the lanthanide-binding tag, the present tag provides a higher anisotropic paramagnetic effect

New aspects of magnetocaloric effect in NiMn{sub 0.89}Cr{sub 0.11}Ge

Energy Technology Data Exchange (ETDEWEB)

Jaworska-Gołąb, T., E-mail: teresa.jaworska-golab@uj.edu.pl [Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków (Poland); Baran, S. [Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków (Poland); Duraj, R. [Institute of Physics, Cracow University of Technology, Podchorążych 1, 30-084 Kraków (Poland); Marzec, M. [Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków (Poland); Dyakonov, V. [Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warszawa (Poland); A.A. Galkin Donetsk Physico-Technical Institute, 83-114 Donetsk (Ukraine); Sivachenko, A. [A.A. Galkin Donetsk Physico-Technical Institute, 83-114 Donetsk (Ukraine); Tyvanchuk, Yu. [Chemistry Department, Ivan Franko National University of Lviv, 79-005 Lviv (Ukraine); Szymczak, H. [Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warszawa (Poland); Szytuła, A. [Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków (Poland)

2015-07-01

Investigations of structural and magnetic phase transitions in the NiMn{sub 0.89}Cr{sub 0.11}Ge half-Heusler alloy were carried out by DSC, XRD (80–400 K), magnetic susceptibility and magnetization (1.9–400 K, magnetic field up to 9.0 T, pressure up to 5.25 kbar) measurements. At high temperatures the sample is a single phase crystallizing in the hexagonal crystal structure (Ni{sub 2}In-type, space group P6{sub 3}/mmc) while below 260 K, down to 100 K, some amount of the hexagonal phase coexists with the orthorhombic (TiNiSi-type, space group Pnma) one. Strong magnetostructural coupling is observed. Magnetic data indicate that with increasing temperature magnetic properties of the sample change from antiferro- to ferro- and then to paramagnetic ones. The latter magnetic phase transition is associated with the crystal structure change and results in large magnetic entropy change equal to −51 J/kg K at μ{sub 0}H= 9.0 T near 260 K. Application of external pressure shifts T{sub C} towards lower temperatures. - Highlights: • # Pnma below 210 K, # P6{sub 3}/mmc above 260 K, for 210 K magnetocaloric effect observed about 260 K at ambient pressure. • Magnetostructural effect observed at 260 K (ΔV/V= 2.4%) at ambient pressure. • Magnetic measurements under hydrostatic pressure up to 5.25 kbar; (p, T) diagram.

Tunable waveguide bends with graphene-based anisotropic metamaterials

KAUST Repository

Chen, Zhao-xian; Chen, Ze-guo; Ming, Yang; Wu, Ying; Lu, Yan-qing

2016-01-01

We design tunable waveguide bends filled with graphene-based anisotropic metamaterials to achieve a nearly perfect bending effect. The anisotropic properties of the metamaterials can be described by the effective medium theory. The nearly perfect bending effect is demonstrated by finite element simulations of various structures with different bending curvatures and shapes. This effect is attributed to zero effective permittivity along the direction of propagation and matched effective impedance at the interfaces between the bending part and the dielectric waveguides. We envisage that the design will be applicable in the far-infrared and terahertz frequency ranges owing to the tunable dielectric responses of graphene.

Tunable waveguide bends with graphene-based anisotropic metamaterials

KAUST Repository

Chen, Zhao-xian

2016-01-15

We design tunable waveguide bends filled with graphene-based anisotropic metamaterials to achieve a nearly perfect bending effect. The anisotropic properties of the metamaterials can be described by the effective medium theory. The nearly perfect bending effect is demonstrated by finite element simulations of various structures with different bending curvatures and shapes. This effect is attributed to zero effective permittivity along the direction of propagation and matched effective impedance at the interfaces between the bending part and the dielectric waveguides. We envisage that the design will be applicable in the far-infrared and terahertz frequency ranges owing to the tunable dielectric responses of graphene.

Influence of kondo effect on the specific heat jump of anisotropic superconductors

Science.gov (United States)

Yoksan, S.

1986-01-01

A calculation for the specific heat jump of an anisotropic superconductor with Kondo impurities is presented. The impurities are treated within the Matsuura - Ichinose - Nagaoka framework and the anisotropy effect is described by the factorizable model of Markowitz and Kadanoff. We give explicit expressions for the change in specific heat jump due to anisotropy and impurities which can be tested experimentally.

Influence of Kondo effect on the specific heat jump of anisotropic superconductors

International Nuclear Information System (INIS)

Yoksan, S.

1986-01-01

A calculation for the specific heat jump of an anisotropic superconductor with Kondo impurities is presented. The impurities are treated within the Matsuura - Ichinose - Nagaoka framework and the anisotropy effect is described by the factorizable model of Markowitz and Kadanoff. Explicit expressions are given for the change in specific heat jump due to anisotropy and impurities which can be tested experimentally. (author)

Acoustic frequency filter based on anisotropic topological phononic crystals

KAUST Repository

Chen, Zeguo

2017-11-02

We present a design of acoustic frequency filter based on a two-dimensional anisotropic phononic crystal. The anisotropic band structure exhibits either a directional or a combined (global + directional) bandgap at certain frequency regions, depending on the geometry. When the time-reversal symmetry is broken, it may introduce a topologically nontrivial bandgap. The induced nontrivial bandgap and the original directional bandgap result in various interesting wave propagation behaviors, such as frequency filter. We develop a tight-binding model to characterize the effective Hamiltonian of the system, from which the contribution of anisotropy is explicitly shown. Different from the isotropic cases, the Zeeman-type splitting is not linear and the anisotropic bandgap makes it possible to achieve anisotropic propagation characteristics along different directions and at different frequencies.

Acoustic frequency filter based on anisotropic topological phononic crystals

KAUST Repository

Chen, Zeguo; Zhao, Jiajun; Mei, Jun; Wu, Ying

2017-01-01

We present a design of acoustic frequency filter based on a two-dimensional anisotropic phononic crystal. The anisotropic band structure exhibits either a directional or a combined (global + directional) bandgap at certain frequency regions, depending on the geometry. When the time-reversal symmetry is broken, it may introduce a topologically nontrivial bandgap. The induced nontrivial bandgap and the original directional bandgap result in various interesting wave propagation behaviors, such as frequency filter. We develop a tight-binding model to characterize the effective Hamiltonian of the system, from which the contribution of anisotropy is explicitly shown. Different from the isotropic cases, the Zeeman-type splitting is not linear and the anisotropic bandgap makes it possible to achieve anisotropic propagation characteristics along different directions and at different frequencies.

Estimation of magnetocaloric properties by using Monte Carlo method for AMRR cycle

International Nuclear Information System (INIS)

Arai, R; Fukuda, H; Numazawa, T; Tamura, R; Li, J; Saito, A T; Nakagome, H; Kaji, S

2015-01-01

In order to achieve a wide refrigerating temperature range in magnetic refrigeration, it is effective to layer multiple materials with different Curie temperatures. It is crucial to have a detailed understanding of physical properties of materials to optimize the material selection and the layered structure. In the present study, we discuss methods for estimating a change in physical properties, particularly the Curie temperature when some of the Gd atoms are substituted for non-magnetic elements for material design, based on Gd as a ferromagnetic material which is a typical magnetocaloric material. For this purpose, whilst making calculations using the S=7/2 Ising model and the Monte Carlo method, we made a specific heat measurement and a magnetization measurement of Gd-R alloy (R = Y, Zr) to compare experimental values and calculated ones. The results showed that the magnetic entropy change, specific heat, and Curie temperature can be estimated with good accuracy using the Monte Carlo method. (paper)

Anisotropic contrast optical microscope.

Science.gov (United States)

Peev, D; Hofmann, T; Kananizadeh, N; Beeram, S; Rodriguez, E; Wimer, S; Rodenhausen, K B; Herzinger, C M; Kasputis, T; Pfaunmiller, E; Nguyen, A; Korlacki, R; Pannier, A; Li, Y; Schubert, E; Hage, D; Schubert, M

2016-11-01

An optical microscope is described that reveals contrast in the Mueller matrix images of a thin, transparent, or semi-transparent specimen located within an anisotropic object plane (anisotropic filter). The specimen changes the anisotropy of the filter and thereby produces contrast within the Mueller matrix images. Here we use an anisotropic filter composed of a semi-transparent, nanostructured thin film with sub-wavelength thickness placed within the object plane. The sample is illuminated as in common optical microscopy but the light is modulated in its polarization using combinations of linear polarizers and phase plate (compensator) to control and analyze the state of polarization. Direct generalized ellipsometry data analysis approaches permit extraction of fundamental Mueller matrix object plane images dispensing with the need of Fourier expansion methods. Generalized ellipsometry model approaches are used for quantitative image analyses. These images are obtained from sets of multiple images obtained under various polarizer, analyzer, and compensator settings. Up to 16 independent Mueller matrix images can be obtained, while our current setup is limited to 11 images normalized by the unpolarized intensity. We demonstrate the anisotropic contrast optical microscope by measuring lithographically defined micro-patterned anisotropic filters, and we quantify the adsorption of an organic self-assembled monolayer film onto the anisotropic filter. Comparison with an isotropic glass slide demonstrates the image enhancement obtained by our method over microscopy without the use of an anisotropic filter. In our current instrument, we estimate the limit of detection for organic volumetric mass within the object plane of ≈49 fg within ≈7 × 7 μm 2 object surface area. Compared to a quartz crystal microbalance with dissipation instrumentation, where contemporary limits require a total load of ≈500 pg for detection, the instrumentation demonstrated here improves

On Pokrovskii's anisotropic gap equations in superconductivity theory

Science.gov (United States)

Yang, Yisong

2003-11-01

An existence and uniqueness theorem for Pokrovskii's zero-temperature anisotropic gap equation is proved. Furthermore, it is shown that Pokrovskii's finite-temperature equation is inconsistent with the Bardeen-Cooper-Schrieffer (BCS) theory. A reformulation of the anisotropic gap equation is presented along the line of Pokrovskii and it is shown that the new equation is consistent with the BCS theory for the whole temperature range. As an application, the Markowitz-Kadanoff model for anisotropic superconductivity is considered and a rigorous proof of the half-integer-exponent isotope effect is obtained. Furthermore, a sharp estimate of the gap solution near the transition temperature is established.

Table-like magnetocaloric effect of Fe{sub 88−x}Nd{sub x}Cr{sub 8}B{sub 4} composite materials

Energy Technology Data Exchange (ETDEWEB)

Lai, J.W.; Zheng, Z.G.; Zhong, X.C. [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Franco, V. [Departamento Física de la Materia Condensada, ICMSE-CSIC, Universidad de Sevilla, P.O. Box 1065, 41080 Sevilla (Spain); Montemayor, R.; Liu, Z.W. [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Zeng, D.C., E-mail: medczeng@scut.edu.cn [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China)

2015-09-15

The narrow working temperature range due to the sharp magnetic entropy change |ΔS{sub M}| peak and large thermal or magnetic hysteresis restricts the practical application of magnetocaloric materials. In this work, the table-like magnetocaloric effect (MCE) was obtained in the multilayer composite of Fe{sub 88−x}Nd{sub x}Cr{sub 8}B{sub 4} alloys with various Nd substitutions for Fe (x=5, 8, 10, 12, and 15), which were prepared by arc-melting followed by melt-spinning. The substation of Nd was found to enhance the glass-forming ability. For the alloys with Nd substitution from 5 at% to 15 at%, the Curie temperature (T{sub C}) ranged from 322 K to 350 K and the peak value of |ΔS{sub M}| remained almost constant, 3.4–3.5 J/(kg K) under an applied field of 0–5 T. The composite with various Nd contents was prepared by stocking the ribbons layer by layer. The |ΔS{sub M}| of the composite approached a nearly constant value of ∼3.2 J/(kg K) in a field change of 0–5 T in a wide temperature span over 40 K, resulting in large refrigerant capacity value of >408 J/kg. This |ΔS{sub M}| value was much larger than the previous reported Fe-based amorphous composite Fe{sub 78−x}Ce{sub x}Si{sub 4}Nb{sub 5}B{sub 12}Cu{sub 1}. This composite can be used as the working material in the Ericsson-cycle magnetic regenerative refrigerator around room temperature. - Highlights: • The T{sub C} ranges from 322 K to 350 K when increasing Nd substitution from 5 to 15 at%. • |ΔS{sub M}| remains relatively constant, about 3.4–3.5 J/(kg K) under H=0–5 T. • RC decreases from 93 to 78 J/kg in a field change of 1.5 T when Nd increasing. • Table-like MCE ,|ΔS{sub M}| ~3.2J/kg K under 0–5 T, appeared in the composite. • A wide working temperature range (40 K) and enhanced RC (>408J/kg) were obtained in the composite.

Synthetic acceleration methods for linear transport problems with highly anisotropic scattering

International Nuclear Information System (INIS)

Khattab, K.M.; Larsen, E.W.

1992-01-01

The diffusion synthetic acceleration (DSA) algorithm effectively accelerates the iterative solution of transport problems with isotropic or mildly anisotropic scattering. However, DSA loses its effectiveness for transport problems that have strongly anisotropic scattering. Two generalizations of DSA are proposed, which, for highly anisotropic scattering problems, converge at least an order of magnitude (clock time) faster than the DSA method. These two methods are developed, the results of Fourier analysis that theoretically predict their efficiency are described, and numerical results that verify the theoretical predictions are presented. (author). 10 refs., 7 figs., 5 tabs

Synthetic acceleration methods for linear transport problems with highly anisotropic scattering

International Nuclear Information System (INIS)

Khattab, K.M.; Larsen, E.W.

1991-01-01

This paper reports on the diffusion synthetic acceleration (DSA) algorithm that effectively accelerates the iterative solution of transport problems with isotropic or mildly anisotropic scattering. However, DSA loses its effectiveness for transport problems that have strongly anisotropic scattering. Two generalizations of DSA are proposed, which, for highly anisotropic scattering problems, converge at least an order of magnitude (clock time) faster than the DSA method. These two methods are developed, the results of Fourier analyses that theoretically predict their efficiency are described, and numerical results that verify the theoretical predictions are presented

Effective-field treatment of an anisotropic Ising ferromagnet: thermodynamical properties

International Nuclear Information System (INIS)

Sarmento, E.F.; Honmura, R.; Tsallis, C.

1982-01-01

The anisotropic square lattice spin -1/2 Ising ferromagnet is discussed. Through this system it is illustrated how all relevant thermodynamical quantities (phase diagram, magnetization, short range order parameter, specific heat and susceptibility) can be approximatively calculated within an effective-field unified procedure (which substantially improves the Mean Field Approximation). Two slightly different approximations for the susceptibility (whose exact computation is still lacking) are presented. The (square lattice) - (linear chain) crossover is exhibited. The present (mathematically simple) procedures could be useful in the study of complex Ising problems. (Author) [pt

Magneto-thermal conduction and magneto-caloric effect in poly and nano crystalline forms of multiferroic GdCrO3

International Nuclear Information System (INIS)

Uma, S; Philip, J

2014-01-01

Gadolinium chromite, GdCrO 3 , belongs to the family of rare earth chromites, exhibiting multiferroism with coupling between electric polarization and magnetic ordering. It is understood that the interaction between Gd 3+ and Cr 3+ ions is responsible for switchable polarization in this system. Below Néel temperature the spins of Cr 3+ ions interact in anti-parallel through super exchange mechanism, giving rise to antiferromagnetic ordering at around 169 K in poly and nanocrystalline phases of this material. In order to understand the nature of spin–lattice coupling and magnon–phonon interaction in the intermediate temperature range (150–250 K), the magneto-thermal conduction and magneto-caloric effect in poly and nanocrystalline forms of this material are reported. These properties show anomalies around 169 K, which is described as due to spin–phonon coupling. When particle sizes are reduced to nanometer scales, thermal conductivity decreases significantly while specific heat capacity increases. The former is explained as due to reduction in phonon mean free path and phonon scattering from nanoparticle interfaces, while the latter is ascribed to contributions from Einstein oscillators at weakly bound atoms at the interfaces of nanocrystals. (paper)

Microstructure and magnetocaloric effect in cast LaFe11.5Si1.5Bx (x=0.5, 1.0)

International Nuclear Information System (INIS)

Zhang, H.; Long, Y.; Cao, Q.; Mudryk, Ya.; Zou, M.; Gschneidner, K.A.; Pecharsky, V.K.

2010-01-01

Phase formation, structure, and the magnetocaloric effect (MCE) in as-cast LaFe 11.5 Si 1.5 B x (x=0.5, 1.0) compounds have been studied. The Curie temperatures, T C , are ∼211 and 230 K for x=0.5 and 1.0, respectively, which are higher than that of annealed LaFe 11.5 Si 1.5 (T C =183 K), while the maximum magnetic entropy changes at the respective T C under a magnetic field change of 0-5 T are 7.8 and 5.8 J/(kg K). Wavelength dispersive spectrometry (WDS) analysis shows that only a small fraction of boron atoms is dissolved in the NaZn 13 -type structure phase, and that the compositions of the as-cast LaFe 11.5 Si 1.5 B x (x=0.5, 1.0) alloys are much different from the intended nominal compositions. These as-cast alloys exhibit second-order magnetic phase transitions and low MCEs. However, based on the relative cooling power, the as-cast LaFe 11.5 Si 1.5 B x alloys are promising candidates for magnetic refrigerants over a wide temperature range.

Characterization of highly anisotropic three-dimensionally nanostructured surfaces

International Nuclear Information System (INIS)

Schmidt, Daniel

2014-01-01

Generalized ellipsometry, a non-destructive optical characterization technique, is employed to determine geometrical structure parameters and anisotropic dielectric properties of highly spatially coherent three-dimensionally nanostructured thin films grown by glancing angle deposition. The (piecewise) homogeneous biaxial layer model approach is discussed, which can be universally applied to model the optical response of sculptured thin films with different geometries and from diverse materials, and structural parameters as well as effective optical properties of the nanostructured thin films are obtained. Alternative model approaches for slanted columnar thin films, anisotropic effective medium approximations based on the Bruggeman formalism, are presented, which deliver results comparable to the homogeneous biaxial layer approach and in addition provide film constituent volume fraction parameters as well as depolarization or shape factors. Advantages of these ellipsometry models are discussed on the example of metal slanted columnar thin films, which have been conformally coated with a thin passivating oxide layer by atomic layer deposition. Furthermore, the application of an effective medium approximation approach to in-situ growth monitoring of this anisotropic thin film functionalization process is presented. It was found that structural parameters determined with the presented optical model equivalents for slanted columnar thin films agree very well with scanning electron microscope image estimates. - Highlights: • Summary of optical model strategies for sculptured thin films with arbitrary geometries • Application of the rigorous anisotropic Bruggeman effective medium applications • In-situ growth monitoring of atomic layer deposition on biaxial metal slanted columnar thin film

Dynamical anisotropic response of black phosphorus under magnetic field

Science.gov (United States)

Liu, Xuefeng; Lu, Wei; Zhou, Xiaoying; Zhou, Yang; Zhang, Chenglong; Lai, Jiawei; Ge, Shaofeng; Sekhar, M. Chandra; Jia, Shuang; Chang, Kai; Sun, Dong

2018-04-01

Black phosphorus (BP) has emerged as a promising material candidate for next generation electronic and optoelectronic devices due to its high mobility, tunable band gap and highly anisotropic properties. In this work, polarization resolved ultrafast mid-infrared transient reflection spectroscopy measurements are performed to study the dynamical anisotropic optical properties of BP under magnetic fields up to 9 T. The relaxation dynamics of photoexcited carrier is found to be insensitive to the applied magnetic field due to the broadening of the Landau levels and large effective mass of carriers. While the anisotropic optical response of BP decreases with increasing magnetic field, its enhancement due to the excitation of hot carriers is similar to that without magnetic field. These experimental results can be well interpreted by the magneto-optical conductivity of the Landau levels of BP thin film, based on an effective k · p Hamiltonian and linear response theory. These findings suggest attractive possibilities of multi-dimensional control of anisotropic response (AR) of BP with light, electric and magnetic field, which further introduces BP to the fantastic magnetic field sensitive applications.

Anisotropic intrinsic spin Hall effect in quantum wires

International Nuclear Information System (INIS)

Cummings, A W; Akis, R; Ferry, D K

2011-01-01

We use numerical simulations to investigate the spin Hall effect in quantum wires in the presence of both Rashba and Dresselhaus spin-orbit coupling. We find that the intrinsic spin Hall effect is highly anisotropic with respect to the orientation of the wire, and that the nature of this anisotropy depends strongly on the electron density and the relative strengths of the Rashba and Dresselhaus spin-orbit couplings. In particular, at low densities, when only one subband of the quantum wire is occupied, the spin Hall effect is strongest for electron momentum along the [1-bar 10] axis, which is the opposite of what is expected for the purely 2D case. In addition, when more than one subband is occupied, the strength and anisotropy of the spin Hall effect can vary greatly over relatively small changes in electron density, which makes it difficult to predict which wire orientation will maximize the strength of the spin Hall effect. These results help to illuminate the role of quantum confinement in spin-orbit-coupled systems, and can serve as a guide for future experimental work on the use of quantum wires for spin-Hall-based spintronic applications. (paper)

Slope stability of bioreactor landfills during leachate injection: effects of heterogeneous and anisotropic municipal solid waste conditions.

Science.gov (United States)

Giri, Rajiv K; Reddy, Krishna R

2014-03-01

In bioreactor landfills, leachate recirculation can significantly affect the stability of landfill slope due to generation and distribution of excessive pore fluid pressures near side slope. The current design and operation of leachate recirculation systems do not consider the effects of heterogeneous and anisotropic nature of municipal solid waste (MSW) and the increased pore gas pressures in landfilled waste caused due to leachate recirculation on the physical stability of landfill slope. In this study, a numerical two-phase flow model (landfill leachate and gas as immiscible phases) was used to investigate the effects of heterogeneous and anisotropic nature of MSW on moisture distribution and pore-water and capillary pressures and their resulting impacts on the stability of a simplified bioreactor landfill during leachate recirculation using horizontal trench system. The unsaturated hydraulic properties of MSW were considered based on the van Genuchten model. The strength reduction technique was used for slope stability analyses as it takes into account of the transient and spatially varying pore-water and gas pressures. It was concluded that heterogeneous and anisotropic MSW with varied unit weight and saturated hydraulic conductivity significantly influenced the moisture distribution and generation and distribution of pore fluid pressures in landfill and considerably reduced the stability of bioreactor landfill slope. It is recommended that heterogeneous and anisotropic MSW must be considered as it provides a more reliable approach for the design and leachate operations in bioreactor landfills.

Enhancement of magnetocaloric effect by external hydrostatic pressure in MnNi0.75Fe0.25Ge alloy

Science.gov (United States)

Mandal, K.; Dutta, P.; Dasgupta, P.; Pramanick, S.; Chatterjee, S.

2018-06-01

A systematic investigation on the structural and magnetic properties of an Fe-doped MnNiGe alloy with nominal composition MnNi0.75Fe0.25Ge has been performed. Temperature dependent x-ray diffraction studies indicate a clear structural phase transition (martensitic type) from the high temperature hexagonal austenite phase (space group P63/mmc) to the low temperature orthorhombic martensite phase (space group Pnma). Interestingly, about 1.4% of the high temperature hexagonal phase has been observed at 15 K, which is well below the martensitic phase transition (MPT) temperature. The studied alloy is found to be ferromagnetic in nature at the lowest temperature of measurement and the saturation moment increases in the presence of external hydrostatic pressure (P). In addition, it shows a significantly large conventional (negative) magnetocaloric effect with an adiabatic entropy change () of about ‑16.2 J kg‑1 K‑1 around the MPT for a magnetic field changing from 0  →  5 T. The most interesting observation is the  ∼40.1% increase in the peak value of on application of 6 kbar of external P. A considerable increment in the refrigeration capacity has also been noted with the applied P.

Investigation of magnetocaloric effect in La{sub 0.45}Pr{sub 0.25}Ca{sub 0.3}MnO{sub 3} by magnetic, differential scanning calorimetry and thermal analysis

Energy Technology Data Exchange (ETDEWEB)

Aparnadevi, M; Barik, S K [Department of Physics, 2 Science Drive 3, National University of Singapore, Lower Kent Ridge Road, Singapore-117 452 (Singapore); Mahendiran, R [Department of Physics, 2 Science Drive 3, National University of Singapore, Lower Kent Ridge Road, Singapore-117 452 (Singapore)

2012-10-15

We investigated magnetocaloric effect in La{sub 0.45}Pr{sub 0.25}Ca{sub 0.3}MnO{sub 3} by direct methods (changes in temperature and latent heat) and indirect method (magnetization isotherms). This compound undergoes a first-order paramagnetic to ferromagnetic transition with T{sub C}=200 K upon cooling. The paramagnetic phase becomes unstable and it transforms into a ferromagnetic phase under the application of magnetic field, which results in a field-induced metamagnetic transition (FIMMT). The FIMMT is accompanied by release of latent heat and temperature of the sample as evidenced from differential scanning calorimetry and thermal analysis experiments. A large magnetic entropy change of {Delta}S{sub m}=-7.2 J kg{sup -1} K{sup -1} at T=212.5 K and refrigeration capacity of 228 J kg{sup -1} are found for a field change of {Delta}H=5 T. It is suggested that destruction of magnetic polarons and growth of ferromagnetic phase accompanied by a lattice volume change with increasing magnetic field is responsible for the large magnetocaloric effect in this compound. - Highlights: Black-Right-Pointing-Pointer We report magnetic entropy change measured by indirect and direct methods in La{sub 0.45}Pr{sub 0.25}Ca{sub 0.3}MnO{sub 3.} Black-Right-Pointing-Pointer Anomalous field-induced induced metamagnetic transition is found in the paramagnetic state. Black-Right-Pointing-Pointer A large reversible magnetic entropy change ({Delta}S{sub m}=7.2 J kg{sup -1} K{sup -1} for {Delta}H=5 T). Black-Right-Pointing-Pointer A large refrigeration capacity (RC=228 J kg{sup -1}). Black-Right-Pointing-Pointer Collapse of magnetic polarons is suggested as possible origin of the large MCE.

Effect of an anisotropic escape mechanism on elliptic flow in relativistic heavy-ion collisions

Science.gov (United States)

Jaiswal, Amaresh; Bhaduri, Partha Pratim

2018-04-01

We study the effect of an anisotropic escape mechanism on elliptic flow in relativistic heavy-ion collisions. We use the Glauber model to generate initial conditions and ignore hydrodynamic expansion in the transverse direction. We employ the Beer-Lambert law to allow for the transmittance of produced hadrons in the medium and calculate the anisotropy generated due to the suppression of particles traversing through the medium. To separate non-flow contribution due to surface bias effects, we ignore hydrodynamic expansion in the transverse direction and consider purely longitudinal boost-invariant expansion. We calculate the transverse momentum dependence of elliptic flow, generated from an anisotropic escape mechanism due to surface bias effects, for various centralities in √{sN N}=200 GeV Au +Au collisions at the Relativistic Heavy Ion Collider and √{sN N}=2.76 TeV Pb +Pb collisions at the Large Hadron Collider. We find that the surface bias effects make a sizable contribution to the total elliptic flow observed in heavy-ion collisions, indicating that the viscosity of the QCD matter extracted from hydrodynamic simulations may be underestimated.

Martensitic phase transformations and magnetocaloric effect in Al co-sputtered Ni–Mn–Sb alloy thin films

International Nuclear Information System (INIS)

Akkera, Harish Sharma; Choudhary, Nitin; Kaur, Davinder

2015-01-01

Highlights: • The Al content leads to a increase in the martensitic transformation temperature. • A maximum ΔS M = 23 mJ/cm 3 K at 300 K was observed in the N 49.8 Mn 32.97 Al 4.43 Sb 12.8 . • The refrigeration capacity RC = 64.4 mJ/cm 3 at 2 T for N 49.8 Mn 32.97 Al 4.43 Sb 12.8 film. - Abstract: We systematically investigated the influence of aluminium (Al) content on the martensitic transformations and magnetocaloric effect (MCE) in Ni–Mn–Sb ferromagnetic shape memory alloy (FSMA) thin films. The temperature-dependent magnetization (M–T) and resistance (R–T) results displayed a monotonic increase in martensitic transformation temperature (T M ) with increasing Al content. From the isothermal magnetization (M–H) curves, a large magnetic entropy change (ΔS M ) of 23 mJ/cm 3 K was observed in N 49.8 Mn 32.97 Al 4.43 Sb 12.8 . A remarkable enhancement of MCE could be attributed to the significant change in the magnetization of Ni–Mn–Sb films with increasing Al content. Furthermore, a high refrigerant capacity (RC) was observed in Ni–Mn–Sb–Al thin films as compared to pure Ni–Mn–Sb. The substitution of Al for Mn in Ni–Mn–Sb thin films with field induced MCE are potential candidates for micro length scale magnetic refrigeration applications where low magnetic fields are desirable

Magnetic field dependence of Griffith phase and magnetocaloric effect in Ca0.85Dy0.15MnO3

Science.gov (United States)

Nag, Ripan; Sarkar, Bidyut; Pal, Sudipta

2018-03-01

Temperature and Magnetic field dependent magnetization properties of electron doped polycrystalline sample Ca0.85Dy0.15MnO3 (CDMO) prepared by solid state reaction method have been studied. The sample undergoes ferromagnetic to paramagnetic phase transition at about 111k. From the study of magnetic properties in terms of Arrot plots it is observed that the phase transition is of 2nd order. The Griffith phase behavior of the sample is suppressed with the increase of the applied magnetic field strength H. We have estimated the magnetic entropy change from experimental magnetization and temperature data. For a magnetic field change of 8000 Oe, the maximum value of magnetic entropy change arrives at a value of 1.126 J-kg-1 k-1 in this magnetocaloric material.

Strain effects on anisotropic magnetoresistance in a nanowire spin valve

Science.gov (United States)

Hossain, Md I.; Maksud, M.; Subramanian, A.; Atulasimha, J.; Bandyopadhyay, S.

2016-11-01

The longitudinal magnetoresistance of a copper nanowire contacted by two cobalt contacts shows broad spin-valve peaks at room temperature. However, when the contacts are slightly heated, the peaks change into troughs which are signature of anisotropic magnetoresistance (AMR). Under heating, the differential thermal expansion of the contacts and the substrate generates a small strain in the cobalt contacts which enhances the AMR effect sufficiently to change the peak into a trough. This shows the extreme sensitivity of AMR to strain. The change in the AMR resistivity coefficient due to strain is estimated to be a few m Ω -m/microstrain.

Fluid-like elasticity induced by anisotropic effective mass density

DEFF Research Database (Denmark)

Ma, Guancong; Fu, Caixing; Wang, Guanghao

We present a three-dimensional anisotropic elastic metamaterial, which can generate dipolar resonances. Repeating these subwavelength units can lead to one-dimensional arrays, which are essentially elastic rods that can withstand both longitudinal, and flexural vibrations. Band structure analysis...

Minimal Sampling for Effective Acquisition of Anisotropic BRDFs

Czech Academy of Sciences Publication Activity Database

Vávra, Radomír; Filip, Jiří

2016-01-01

Roč. 35, č. 7 (2016), s. 299-309 ISSN 0167-7055 R&D Projects: GA ČR(CZ) GA14-02652S Institutional support: RVO:67985556 Keywords : BRDF * anisotropic * measurement Subject RIV: BD - Theory of Information Impact factor: 1.611, year: 2016 http://library.utia.cas.cz/separaty/2016/RO/vavra-0463872.pdf

Anisotropic Magnus Force in Type-II Superconductors with Planar Defects

Science.gov (United States)

Monroy, Ricardo Vega; Gomez, Eliceo Cortés

2015-02-01

The effect of planar defects on the Magnus force in type-II superconductors is studied. It is shown that the deformation of the vortex due to the presence of a planar defect leads to a local decrease in the mean free path of electrons in the vortex. This effect reduces the effective Magnus coefficient in normal direction to the planar defect, leading to an anisotropic regime of the Hall effect. The presented developments here can qualitatively explain experimental observations of the anisotropic Hall effect in high- T c superconductors in the mixed state.

Thermopower and magnetocaloric properties in NdSrMnO/CrO3 composites

Science.gov (United States)

Ahmed, A. M.; Mohamed, H. F.; Paixão, J. A.; Mohamed, Sara A.

2018-06-01

The thermoelectric power (TEP) and magnetocaloric effect (MCE) for (Nd0.6Sr0.4MnO3)1-x/(CrO3)x composites have been measured. The TEP measurements show a negative sign value of the Seebeck coefficient (S), in microvolts. TEP data construe in the low range of temperature by the magnon and phonon drag model, whereas at high temperature by small polaron conduction mechanism. Magnetic measurements exhibit that all composites show a paramagnetic-ferromagnetic transition with decreasing temperature. The Arrott plots of composites reveal the occurrence of a second order phase transition. The maximum value of magnetic entropy change (ΔS) is 2.37 J kg-1 K-1, achieved fore the composite with x = 0.015. Moreover, the maximum value of relative cooling power (RCP) is 122.1 J kg-1, achieved for the composite with x = 0.020. These composites may be appropriate for magnetic application near room temperature.

Waveguide effect under 'antiguiding' conditions in graded anisotropic media.

Science.gov (United States)

Kozlov, A V; Mozhaev, V G; Zyryanova, A V

2010-02-24

A new wave confinement effect is predicted in graded crystals with a concave slowness surface under conditions of growth of the phase velocity with decreasing distance from the waveguide axis. This finding overturns the common notion about the guiding and 'antiguiding' profiles of wave velocity in inhomogeneous media. The waveguide effect found is elucidated by means of ray analysis and particular exact wave solutions. The exact solution obtained for localized flexural waves in thin plates of graded cubic and tetragonal crystals confirms the predicted effect. Since this solution is substantially different with respect to the existence conditions from all others yet reported, and it cannot be deduced from the previously known results, the predicted waves can be classified as a new type of waveguide mode in graded anisotropic media. Although the concrete calculations are given in the article for acoustic waves, its general predictions are expected to be valid for waves of various natures, including spin, plasma, and optical waves.

Waveguide effect under 'antiguiding' conditions in graded anisotropic media

International Nuclear Information System (INIS)

Kozlov, A V; Mozhaev, V G; Zyryanova, A V

2010-01-01

A new wave confinement effect is predicted in graded crystals with a concave slowness surface under conditions of growth of the phase velocity with decreasing distance from the waveguide axis. This finding overturns the common notion about the guiding and 'antiguiding' profiles of wave velocity in inhomogeneous media. The waveguide effect found is elucidated by means of ray analysis and particular exact wave solutions. The exact solution obtained for localized flexural waves in thin plates of graded cubic and tetragonal crystals confirms the predicted effect. Since this solution is substantially different with respect to the existence conditions from all others yet reported, and it cannot be deduced from the previously known results, the predicted waves can be classified as a new type of waveguide mode in graded anisotropic media. Although the concrete calculations are given in the article for acoustic waves, its general predictions are expected to be valid for waves of various natures, including spin, plasma, and optical waves.

Analytical Solution for the Anisotropic Rabi Model: Effects of Counter-Rotating Terms

OpenAIRE

Zhang, Guofeng; Zhu, Hanjie

2015-01-01

The anisotropic Rabi model, which was proposed recently, differs from the original Rabi model: the rotating and counter-rotating terms are governed by two different coupling constants. This feature allows us to vary the counter-rotating interaction independently and explore the effects of it on some quantum properties. In this paper, we eliminate the counter-rotating terms approximately and obtain the analytical energy spectrums and wavefunctions. These analytical results agree well with the ...

Anisotropic magnetoelectric characteristics in five-layer magnetization-graded multiferroic composites

Directory of Open Access Journals (Sweden)

Lei Chen

2017-05-01

Full Text Available We investigate the anisotropic magnetoelectric(ME characteristics for the five-layer magnetization-graded multiferroic composites(MGMC. The magnetic anisotropy and corresponding anisotropic magnetomechanical effect, demagnetization effect and magneto-mechanical damping’s dependence on magnetic field direction result in an obvious anisotropic ME coupling effect. The experimental results show that ME voltage coefficient in H33 mode is remarkably larger than the other ones (H11, H31 and H13 over the whole Hdc range. Correspondingly, ∂VME/∂Hdc arrives about 420mV/Oe at an optimum bias magnetic field of 46Oe, which is approximately 40 times larger than that of the previous reported composite. Furthermore, it also demonstrates an obvious angular dependence on dc magnetic field. Taking advantage of these specifications, the MGMC can be used to detect weak dc magnetic field and its spatial orientation.

Anisotropic stars obeying Chaplygin equation of state

Indian Academy of Sciences (India)

P Bhar

2017-12-14

Dec 14, 2017 ... Anisotropic effects may also originate from slow rotation of the core ... to include the effects of pressure anisotropy, electric charge, scalar field, dark energy and the cosmological constant in .... Generating solutions. In order to ...

Size-dependent effective properties of anisotropic piezoelectric composites with piezoelectric nano-particles

International Nuclear Information System (INIS)

Huang, Ming-Juan; Fang, Xue-Qian; Liu, Jin-Xi; Feng, Wen-Jie; Zhao, Yong-Mao

2015-01-01

Based on the electro-elastic surface/interface theory, the size-dependent effective piezoelectric and dielectric coefficients of anisotropic piezoelectric composites that consist of spherically piezoelectric inclusions under a uniform electric field are investigated, and the analytical solutions for the elastic displacement and electric potentials are derived. With consideration of the coupling effects of elasticity, permittivity and piezoelectricity, the effective field method is introduced to derive the effective dielectric and piezoelectric responses in the dilute limit. The numerical examples show that the effective dielectric constant exhibits a significant variation due to the surface/interface effect. The dielectric property of the surface/interface displays greater effect than the piezoelectric property, and the elastic property shows little effect. A comparison with the existing results validates the present approach. (paper)

Anisotropic and Hierarchical Porosity in Multifunctional Ceramics

Science.gov (United States)

Lichtner, Aaron Zev

The performance of multifunctional porous ceramics is often hindered by the seemingly contradictory effects of porosity on both mechanical and non-structural properties and yet a sufficient body of knowledge linking microstructure to these properties does not exist. Using a combination of tailored anisotropic and hierarchical materials, these disparate effects may be reconciled. In this project, a systematic investigation of the processing, characterization and properties of anisotropic and isotropic hierarchically porous ceramics was conducted. The system chosen was a composite ceramic intended as the cathode for a solid oxide fuel cell (SOFC). Comprehensive processing investigations led to the development of approaches to make hierarchical, anisotropic porous microstructures using directional freeze-casting of well dispersed slurries. The effect of all the important processing parameters was investigated. This resulted in an ability to tailor and control the important microstructural features including the scale of the microstructure, the macropore size and total porosity. Comparable isotropic porous ceramics were also processed using fugitive pore formers. A suite of characterization techniques including x-ray tomography and 3-D sectional scanning electron micrographs (FIB-SEM) was used to characterize and quantify the green and partially sintered microstructures. The effect of sintering temperature on the microstructure was quantified and discrete element simulations (DEM) were used to explain the experimental observations. Finally, the comprehensive mechanical properties, at room temperature, were investigated, experimentally and using DEM, for the different microstructures.

Study of magnetic, structural and magnetocaloric properties of La.sub.0.6./sub.Pr.sub.0.4./sub.Mn.sub.2./sub.Si.sub.2./sub. under high pressures and magnetic field

Czech Academy of Sciences Publication Activity Database

Kaštil, Jiří; Arnold, Zdeněk; Isnard, O.; Skourski, Y.; Kamarád, Jiří; Itié, J.P.

2017-01-01

Roč. 424, Feb (2017), s. 416-420 ISSN 0304-8853 R&D Projects: GA ČR GA15-03777S Institutional support: RVO:68378271 Keywords : magnetization * compressibility * magnetocaloric effect * high pressure Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 2.630, year: 2016

Anisotropic wetting characteristics versus roughness on machined surfaces of hydrophilic and hydrophobic materials

International Nuclear Information System (INIS)

Liang, Yande; Shu, Liming; Natsu, Wataru; He, Fuben

2015-01-01

Graphical abstract: - Highlights: • The aim is to investigate the influence of roughness on anisotropic wetting on machined surfaces. • The relationship between roughness and anisotropic wetting is modeled by thermodynamical analysis. • The effect of roughness on anisotropic wetting on hydrophilic materials is stronger than that on hydrophobic materials. • The energy barrier existing in the direction perpendicular to the lay is one of the main reasons for the anisotropic wetting. • The contact angle in the parallel direction is larger than that in the perpendicular direction. - Abstract: Anisotropic wetting of machined surfaces is widely applied in industries which can be greatly affected by roughness and solid's chemical properties. However, there has not been much work on it. A free-energy thermodynamic model is presented by analyzing geometry morphology of machined surfaces (2-D model surfaces), which demonstrates the influence of roughness on anisotropic wetting. It can be concluded that the energy barrier is one of the main reasons for the anisotropic wetting existing in the direction perpendicular to the lay. In addition, experiments in investigating anisotropic wetting, which was characterized by the static contact angle and droplet's distortion, were performed on machined surfaces with different roughness on hydrophilic and hydrophobic materials. The droplet's anisotropy found on machined surfaces increased with mean slope of roughness profile Kr. It indicates that roughness on anisotropic wetting on hydrophilic materials has a stronger effect than that on hydrophobic materials. Furthermore, the contact angles predicted by the model are basically consistent with the experimentally ones

Magnetic, transport, and magnetocaloric properties of boron doped Ni-Mn-In alloys

International Nuclear Information System (INIS)

Pandey, S.; Quetz, A.; Aryal, A.; Dubenko, I.; Ali, N.; Rodionov, I. D.; Blinov, M. I.; Titov, I. S.; Prudnikov, V. N.; Granovsky, A. B.; Stadler, S.

2015-01-01

The impact of B substitution in Ni 50 Mn 35 In 15−x B x Heusler alloys on the structural, magnetic, transport, and parameters of the magnetocaloric effect (MCE) has been studied by means of room-temperature X-ray diffraction and thermomagnetic measurements (in magnetic fields (H) up to 5 T, and in the temperature interval 5–400 K). Direct adiabatic temperature change (ΔT AD ) measurements have been carried out for an applied magnetic field change of 1.8 T. The transition temperatures (T-x) phase diagram has been constructed for H = 0.005 T. The MCE parameters were found to be comparable to those observed in other MCE materials such as Ni 50 Mn 34.8 In 14.2 B and Ni 50 Mn 35 In 14 X (X=In, Al, and Ge) Heusler alloys. The maximum absolute value of ΔT AD  = 2.5 K was observed at the magnetostructural transition for Ni 50 Mn 35 In 14.5 B 0.5

Magnetic and magnetocaloric properties of itinerant-electron system Hf{sub 1−x}Ta{sub x}Fe{sub 2} (x = 0.125 and 0.175)

Energy Technology Data Exchange (ETDEWEB)

Diop, L.V.B. [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Kastil, J. [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Institute of Physics AS CR v.v.i., Na Slovance 2, 182 21 Prague 8 (Czech Republic); Isnard, O. [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Arnold, Z.; Kamarad, J. [Institute of Physics AS CR v.v.i., Na Slovance 2, 182 21 Prague 8 (Czech Republic)

2015-04-05

Highlights: • First report of the direct measurement of ΔT{sub ad} in Hf{sub 1−x}Ta{sub x}Fe{sub 2} compounds. • ΔT{sub ad} reach values of 2.5 K under μ{sub 0}ΔH = 3 T for x = 0.175 compound. • A field induced metamagnetic phase transition has been observed. - Abstract: Intrinsic magnetic properties and magnetocaloric effect (MCE) have been investigated for Hf{sub 1−x}Ta{sub x}Fe{sub 2} (x = 0.125 and 0.175) itinerant-electron compounds which exhibit a temperature-induced transition from the ferromagnetic (FM) to the antiferromagnetic (AFM) state. Upon increasing Ta concentration, the ferromagnetic ordering temperature strongly decreases with decreasing the lattice parameters and both the isothermal magnetic entropy change ΔS{sub M} and the adiabatic temperature change ΔT{sub ad} are enhanced. An adiabatic temperature change of ΔT{sub ad} = 2 and 2.5 K was observed in Hf{sub 0.875}Ta{sub 0.125}Fe{sub 2} and Hf{sub 0.825}Ta{sub 0.175}Fe{sub 2}, respectively, for a magnetic field change of 3 T. Therefore, the partial substitution of Ta for Hf is highly effective in the enhancement of the magnetocaloric effect in Hf{sub 1−x}Ta{sub x}Fe{sub 2} systems. In addition substitution can be used to tune both the transition temperature but also the magnetic transition from first toward second order type.

General PFG signal attenuation expressions for anisotropic anomalous diffusion by modified-Bloch equations

Science.gov (United States)

Lin, Guoxing

2018-05-01

Anomalous diffusion exists widely in polymer and biological systems. Pulsed-field gradient (PFG) anomalous diffusion is complicated, especially in the anisotropic case where limited research has been reported. A general PFG signal attenuation expression, including the finite gradient pulse (FGPW) effect for free general anisotropic fractional diffusion { 0 integral modified-Bloch equation, were extended to obtain general PFG signal attenuation expressions for anisotropic anomalous diffusion. Various cases of PFG anisotropic anomalous diffusion were investigated, including coupled and uncoupled anisotropic anomalous diffusion. The continuous-time random walk (CTRW) simulation was also carried out to support the theoretical results. The theory and the CTRW simulation agree with each other. The obtained signal attenuation expressions and the three-dimensional fractional modified-Bloch equations are important for analyzing PFG anisotropic anomalous diffusion in NMR and MRI.

Table-like magnetocaloric effect in Gd56Ni15Al27Zr2 alloy and its field independence feature

International Nuclear Information System (INIS)

Agurgo Balfour, E.; Ma, Z.; Fu, H.; Wang, L.; Luo, Y.; Hadimani, R. L.; Jiles, D. C.; Wang, S. F.

2015-01-01

In order to obtain “table-like” magnetocaloric effect (MCE), multiple-phase Gd 56 Ni 15 Al 27 Zr 2 alloy was prepared by arc-melting followed by suck-casting method. Powder x-ray diffraction and calorimetric measurements reveal that the sample contains both glassy and crystalline phases. The fraction of the glassy phase is about 62%, estimated from the heat enthalpy of the crystallization. The crystalline phases, Gd 2 Al and GdNiAl further broadened the relatively wider magnetic entropy change (−ΔS M ) peak of the amorphous phase, which resulted in the table-like MCE over a maximum temperature range of 52.5 K to 77.5 K. The plateau feature of the MCE was found to be nearly independent of the applied magnetic field from 3 T to 5 T. The maximum −ΔS M value of the MCE platforms is 6.0 J/kg K under applied magnetic field change of 5 T. Below 3 T, the field independence of the table-like feature disappears. The relatively large constant values of −ΔS M for the respective applied magnetic fields have promising applications in magnetic refrigeration using regenerative Ericsson cycle

Anisotropic pressure effects on the Kagome Cu3Bi(SeO3)2O2Cl metamagnet

Science.gov (United States)

Wu, H. C.; Tseng, W. J.; Yang, P. Y.; Chandrasekhar, K. D.; Berger, H.; Yang, H. D.

2017-07-01

The anisotropic spin-flip-induced multiferroic property of the Kagome single-crystal Cu3Bi(SeO3)2O2Cl was recently investigated. The doping effects on the structural and magnetic properties of Cu3Bi(Se1-x Te x O3)2O2Cl (0 ≤slant x≤slant 0.6) polycrystalline samples were studied to further explore and manipulate the metamagnetic spin-flip transition. With higher Te concentration, the lattice constants a and b exhibit a linear increase, whereas the lattice constant c gradually decreases, which indicates that the anisotropic expansion and compression effect is induced by Te substitution in the Se site. Subsequently, the antiferromagnetic transition (T N) shifts to a higher temperature, the critical field ({{H}\\text{c}} ) of the metamagnetic spin-flip transition increases, and the value of the saturation magnetisation ({{M}\\text{s}} ) diminishes. Meanwhile, the effects of isotropic expansion (with Br doping) and compression (with external pressure) do not show a clear influence on the spin-flip phenomena. Our results emphasise the introduction of anisotropic pressure in Cu3Bi(SeO3)2O2Cl, which modulates the magnetic interaction of Cu (I)-O1-Cu (I) and Cu (I)-O1-Cu (II) and, consequently, enhances the {{H}\\text{c}} of the spin-flip transition.

Cascade of Quantum Transitions and Magnetocaloric Anomalies in an Open Nanowire

Science.gov (United States)

Val'kov, V. V.; Mitskan, V. A.; Shustin, M. S.

2017-12-01

A sequence of magnetocaloric anomalies occurring with the change in a magnetic field H is predicted for an open nanowire with the Rashba spin-orbit coupling and the induced superconducting pairing potential. The nature of such anomalies is due to the cascade of quantum transitions related to the successive changes in the fermion parity of the nanowire ground state with the growth of the magnetic field. It is shown that the critical H c values fall within the parameter range corresponding to the nontrivial values of the Z 2 topological invariant of the corresponding 1D band Hamiltonian characteristic of the D symmetry class. It is demonstrated that such features in the behavior of the open nanowire are retained even in the presence of Coulomb interactions.

Quantum effects and elimination of the conformal anomaly in anisotropic space-time

International Nuclear Information System (INIS)

Grib, A.A.; Nesteruk, A.V.

1988-01-01

In homogeneous anisotropic space-time the connection between the problem of the elimination of infrared divergences and the conformal anomaly of the regularized energy-momentum tensor is studied. It is shown that removal of the infrared divergence by means of a cutoff leads to the absence of a conformal anomaly. A physical interpretation of the infrared cutoff as a shift in the particle-energy spectrum by an amount equal to the effective temperature of the gravitational field is proposed

Structural, magnetic and magnetocaloric properties of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}Mn{sub 1−x}Cr{sub x}O{sub 3} compounds with x = 0, 0.05 and 0.1

Energy Technology Data Exchange (ETDEWEB)

Dhahri, Ah., E-mail: dhahri.ahmad@outlook.fr [Laboratoire de Physique Appliquée, Faculté des Sciences de Sfax, BP 1171, Université de Sfax, 3000 (Tunisia); Jemmali, M. [Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences de Sfax, BP 1171, Université de Sfax, 3000 (Tunisia); Taibi, K. [Département SDM, FGMGP/USTHB, 16311 (Algeria); Dhahri, E. [Laboratoire de Physique Appliquée, Faculté des Sciences de Sfax, BP 1171, Université de Sfax, 3000 (Tunisia); Hlil, E.K. [Institut Néel, CNRS et Université J. Fourier, BP 166, 38042 Grenoble (France)

2015-01-05

Highlights: • The samples crystallize in the rhombohedral structure with the R3{sup ¯}c space group. • Enhancement of T{sub C} for the rhombohedral samples. • The relative cooling power increases with Cr-doping. • All samples exhibit a large magnetocaloric effect. • High values of the magnetoresistance in all samples. - Abstract: Structural, magnetic and magnetocaloric properties of La{sub 0.7}Sr{sub 0.1}Ca{sub 0.2}Mn{sub 1−x}Cr{sub x}O{sub 3} compounds with x = 0, 0.05 and 0.1 have been investigated to shed light on Cr-doping influence. X-ray diffraction studies show that all samples crystallize in the rhombohedral symmetry with R3{sup ¯}c space group. Rietveld refinement structure shows that the insertion of Cr in Mn network modifies the structural parameters such as the volume, Mn–O–Mn angles and the Mn–O bond length. The substitution of Mn by Cr decreases the 2p-3d hybridization between O and Mn ions, reduces the bandwidth and increases the electron–phonon coupling. The investigation of magnetic and magnetocaloric properties reveals that the samples exhibit a paramagnetic(PM)–ferromagnetic (FM) transition with decreasing Curie temperature (T{sub C}) from 294 K to 255 K when Cr doping level increases. The magnetic entropy change (ΔS{sub M}{sup max}) also decreases from 6.20 J kg{sup −1} K{sup −1} for x = 0 to3.80 J kg{sup −1} K{sup −1} for x = 0.1, while the relative cooling power (RCP) increases from 234.5 to 240 J kg{sup −1}, respectively, under a magnetic field of 5 T. These outcomes suggest that Mn-site Cr doping inhibits the enhancement of the magnetocaloric effect in some perovskite manganites. This is explained by the weakening of the ferromagnetic double-exchange interaction between Mn{sup 3+} and Mn{sup 4+} ions.

Magnetocaloric response of La 0.70 Ca 0.1 Sr 0.2 Fe 0.1 Mn 0.9 O 3 ...

Indian Academy of Sciences (India)

Home; Journals; Bulletin of Materials Science; Volume 38; Issue 1. Magnetocaloric response of La0.70Ca0.1Sr0.2Fe0.1Mn0.9O3 pervoskite for magnetic refrigeration. M S Anwar Faheem Ahmed Bon Heun Koo. Volume 38 Issue 1 February 2015 pp 101-104 ...

Effect of orbital symmetry on the anisotropic superexchange interaction

International Nuclear Information System (INIS)

Kim, Beom Hyun; Min, B I

2011-01-01

Employing the microscopic superexchange model incorporating the effect of spin-orbit interaction, we have investigated the Dzyaloshinsky-Moriya (DM) interaction in perovskite transition-metal (TM) oxides and explored the interplay between the DM interaction and the TM-3d orbital symmetry. For d 3 and d 5 systems with isotropic orbital symmetry, the DM vectors are well described by a simple symmetry analysis considering only the bond geometry. In contrast, the DM interaction for d 4 systems with anisotropic orbital symmetry shows slightly different behavior, which does not obey simple symmetry analysis. The direction as well as the strength of the DM vector varies depending on the occupied orbital shape. We have understood this behavior based on the orbital symmetry induced by local crystal field variation.

Anisotropic light scattering of individual sickle red blood cells.

Science.gov (United States)

Kim, Youngchan; Higgins, John M; Dasari, Ramachandra R; Suresh, Subra; Park, YongKeun

2012-04-01

We present the anisotropic light scattering of individual red blood cells (RBCs) from a patient with sickle cell disease (SCD). To measure light scattering spectra along two independent axes of elongated-shaped sickle RBCs with arbitrary orientation, we introduce the anisotropic Fourier transform light scattering (aFTLS) technique and measured both the static and dynamic anisotropic light scattering. We observed strong anisotropy in light scattering patterns of elongated-shaped sickle RBCs along its major axes using static aFTLS. Dynamic aFTLS analysis reveals the significantly altered biophysical properties in individual sickle RBCs. These results provide evidence that effective viscosity and elasticity of sickle RBCs are significantly different from those of the healthy RBCs.

Casimir interactions for anisotropic magnetodielectric metamaterials

Energy Technology Data Exchange (ETDEWEB)

Da Rosa, Felipe S [Los Alamos National Laboratory; Dalvit, Diego A [Los Alamos National Laboratory; Milonni, Peter W [Los Alamos National Laboratory

2008-01-01

We extend our previous work on the generalization of the Casimir-Lifshitz theory to treat anisotropic magnetodielectric media, focusing on the forces between metals and magnetodielectric metamaterials and on the possibility of inferring magnetic effects by measurements of these forces.

Effective Floquet Hamiltonian theory of multiple-quantum NMR in anisotropic solids involving quadrupolar spins: Challenges and Perspectives

Science.gov (United States)

Ganapathy, Vinay; Ramachandran, Ramesh

2017-10-01

The response of a quadrupolar nucleus (nuclear spin with I > 1/2) to an oscillating radio-frequency pulse/field is delicately dependent on the ratio of the quadrupolar coupling constant to the amplitude of the pulse in addition to its duration and oscillating frequency. Consequently, analytic description of the excitation process in the density operator formalism has remained less transparent within existing theoretical frameworks. As an alternative, the utility of the "concept of effective Floquet Hamiltonians" is explored in the present study to explicate the nuances of the excitation process in multilevel systems. Employing spin I = 3/2 as a case study, a unified theoretical framework for describing the excitation of multiple-quantum transitions in static isotropic and anisotropic solids is proposed within the framework of perturbation theory. The challenges resulting from the anisotropic nature of the quadrupolar interactions are addressed within the effective Hamiltonian framework. The possible role of the various interaction frames on the convergence of the perturbation corrections is discussed along with a proposal for a "hybrid method" for describing the excitation process in anisotropic solids. Employing suitable model systems, the validity of the proposed hybrid method is substantiated through a rigorous comparison between simulations emerging from exact numerical and analytic methods.

Anisotropic modulation of magnetic properties and the memory effect in a wide-band (011)-Pr0.7Sr0.3MnO3/PMN-PT heterostructure

KAUST Repository

Zhao, Ying-Ying

2015-04-24

Memory effect of electric-field control on magnetic behavior in magnetoelectric composite heterostructures has been a topic of interest for a long time. Although the piezostrain and its transfer across the interface of ferroelectric/ferromagnetic films are known to be important in realizing magnetoelectric coupling, the underlying mechanism for nonvolatile modulation of magnetic behaviors remains a challenge. Here, we report on the electric-field control of magnetic properties in wide-band (011)-Pr0.7Sr0.3MnO3/0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 heterostructures. By introducing an electric-field-induced in-plane anisotropic strain field during the cooling process from room temperature, we observe an in-plane anisotropic, nonvolatile modulation of magnetic properties in a wide-band Pr0.7Sr0.3MnO3 film at low temperatures. We attribute this anisotropic memory effect to the preferential seeding and growth of ferromagnetic (FM) domains under the anisotropic strain field. In addition, we find that the anisotropic, nonvolatile modulation of magnetic properties gradually diminishes as the temperature approaches FM transition, indicating that the nonvolatile memory effect is temperature dependent. By taking into account the competition between thermal energy and the potential barrier of the metastable magnetic state induced by the anisotropic strain field, this distinct memory effect is well explained, which provides a promising approach for designing novel electric-writing magnetic memories.

A unified theoretical and experimental study of anisotropic hardening

International Nuclear Information System (INIS)

Boehler, J.P.; Raclin, J.

1981-01-01

The purpose of this work is to develop a consistent formulation of the constitutive relations regarding anisotropic hardening materials. Attention is focused on the appearance and the evolution of mechanical anisotropies during irreversible processes, such as plastic forming and inelastic deformation of structures. The representation theorems for anisotropic tensor functions constitute a theoretical basis, allowing to reduce arbitrariness and to obtain a unified formulation of anisotropic hardening. In this approach, a general three-dimensional constitutive law is developed for prestrained initially orthotropic materials. Introduction of the plastic behavior results in the general forms of both the flow-law and the yield criterion. The developed theory is then specialized for the case of plane stress and different modes of anisotropic hardening are analyzed. A new generalization of the Von Mises criterion is proposed, in considering a homogeneous form of order two in stress and employing the simplest combinations of the basic invariants entering the general form of the yield condition. The proposed criterion involves specific terms accounting for the initial anisotropy, the deformation induced anisotropy and correlative terms between initial and induced anisotropy. The effects of prestrainings result in both isotropic and anisotropic hardening. An adequate experimental program, consisting of uniaxial tensile tests on oriented specimens of prestrained sheet-metal, was performed, in order to determine the specific form and the evolution of the anisotropic failure criterion for soft-steel subjected to different irreversible prestrainings. (orig.)

An effective one-dimensional anisotropic fingerprint enhancement algorithm

Science.gov (United States)

Ye, Zhendong; Xie, Mei

2012-01-01

Fingerprint identification is one of the most important biometric technologies. The performance of the minutiae extraction and the speed of the fingerprint verification system rely heavily on the quality of the input fingerprint images, so the enhancement of the low fingerprint is a critical and difficult step in a fingerprint verification system. In this paper we proposed an effective algorithm for fingerprint enhancement. Firstly we use normalization algorithm to reduce the variations in gray level values along ridges and valleys. Then we utilize the structure tensor approach to estimate each pixel of the fingerprint orientations. At last we propose a novel algorithm which combines the advantages of onedimensional Gabor filtering method and anisotropic method to enhance the fingerprint in recoverable region. The proposed algorithm has been evaluated on the database of Fingerprint Verification Competition 2004, and the results show that our algorithm performs within less time.

Low-loss single-mode hollow-core fiber with anisotropic anti-resonant elements

DEFF Research Database (Denmark)

Habib, Selim; Bang, Ole; Bache, Morten

2016-01-01

A hollow-core fiber using anisotropic anti-resonant tubes in thecladding is proposed for low loss and effectively single-mode guidance. We show that the loss performance and higher-order mode suppression is significantly improved by using symmetrically distributed anisotropic antiresonant tubes i...

A Magnetocaloric Pump for Lab-On-Chip Technology: Phase I Report

Energy Technology Data Exchange (ETDEWEB)

Love, L.J.

2004-04-05

A magnetocaloric pump provides a simple means of pumping fluid using only external thermal and magnetic fields. The principle, which can be traced back to the early work of Rosensweig, is straightforward. Magnetic materials tend to lose their magnetization as the temperature approaches the material's Curie point. Exposing a column of magnetic fluid to a uniform magnetic field coincident with a temperature gradient produces a pressure gradient in the magnetic fluid. As the fluid heats up, it loses its attraction to the magnetic field and is displaced by cooler fluid. The impact of such a phenomenon is obvious: fluid propulsion with no moving mechanical parts. Until recently, limitations in the magnetic and thermal properties of conventional materials severely limited practical operating pressure gradients. However, recent advancements in the design of metal substituted magnetite enable fine control over both the magnetic and thermal properties of magnetic nanoparticles, a key element in colloidal based magnetic fluids (ferrofluids). This manuscript begins with a basic description of the process and previous limitations due to material properties. This is followed by a review of existing methods of synthesizing magnetic nanoparticles as well as an introduction to a new approach based on thermophilic metal-reducing bacteria. We compare two compounds and show, experimentally, significant variation in specific magnetic and thermal properties. We develop the constitutive thermal, magnetic, and fluid dynamic equations associated with magnetocaloric pump and validate our finite element model with a series of experiments. Preliminary results show a good match between the model and experiment as well as approximately an order of magnitude increase in the fluid flow rate over conventional magnetite based ferrofluids operating below 80 C. Finally, as a practical demonstration, we describe a novel application of this technology: pumping fluids at the &apos

Anisotropic elastic plates

CERN Document Server

Hwu, Chyanbin

2010-01-01

As structural elements, anisotropic elastic plates find wide applications in modern technology. The plates here are considered to be subjected to not only in plane load but also transverse load. In other words, both plane and plate bending problems as well as the stretching-bending coupling problems are all explained in this book. In addition to the introduction of the theory of anisotropic elasticity, several important subjects have are discussed in this book such as interfaces, cracks, holes, inclusions, contact problems, piezoelectric materials, thermoelastic problems and boundary element a

Anisotropic characterization of magnetorheological materials

Energy Technology Data Exchange (ETDEWEB)

Dohmen, E., E-mail: eike.dohmen@tu-dresden.de; Modler, N.; Gude, M.

2017-06-01

For the development of energy efficient lightweight parts novel function integrating materials are needed. Concerning this field of application magnetorheological (MR) fluids, MR elastomers and MR composites are promising materials allowing the adjustment of mechanical properties by an external magnetic field. A key issue for operating such structures in praxis is the magneto-mechanical description. Most rheological properties are gathered at laboratory conditions for high magnetic flux densities and a single field direction, which does not correspond to real praxis conditions. Although anisotropic formation of superstructures can be observed in MR suspensions (Fig. 1) or experimenters intentionally polymerize MR elastomers with anisotropic superstructures these MR materials are usually described in an external magnetic field as uniform, isotropic materials. This is due to missing possibilities for experimentally measuring field angle dependent properties and ways of distinguishing between material properties and frictional effects. Just a few scientific works experimentally investigated the influence of different field angles (Ambacher et al., 1992; Grants et al., 1990; Kuzhir et al., 2003) or the influence of surface roughness on the shear behaviour of magnetic fluids (Tang and Conrad, 1996) . The aim of this work is the introduction of a novel field angle cell allowing the determination of anisotropic mechanical properties for various MR materials depending on the applied magnetic field angle. - Highlights: • Novel magnetic field angle testing device (MFATD) presented. • Determination of magnetic field dependent anisotropic mechanical properties. • Experimental data for different field directions shown for a commercial MR fluid. • Material description of MR fluids as transversal-isotropic solids. • Magnetic field angle dependent variations in shear stresses experimentally measured. • Determination of frictional coefficients between the MR fluid and

Collision-induced absorption with exchange effects and anisotropic interactions: theory and application to H2 - H2.

Science.gov (United States)

Karman, Tijs; van der Avoird, Ad; Groenenboom, Gerrit C

2015-02-28

We discuss three quantum mechanical formalisms for calculating collision-induced absorption spectra. First, we revisit the established theory of collision-induced absorption, assuming distinguishable molecules which interact isotropically. Then, the theory is rederived incorporating exchange effects between indistinguishable molecules. It is shown that the spectrum can no longer be written as an incoherent sum of the contributions of the different spherical components of the dipole moment. Finally, we derive an efficient method to include the effects of anisotropic interactions in the computation of the absorption spectrum. This method calculates the dipole coupling on-the-fly, which allows for the uncoupled treatment of the initial and final states without the explicit reconstruction of the many-component wave functions. The three formalisms are applied to the collision-induced rotation-translation spectra of hydrogen molecules in the far-infrared. Good agreement with experimental data is obtained. Significant effects of anisotropic interactions are observed in the far wing.

Saving Moore’s Law Down To 1 nm Channels With Anisotropic Effective Mass

Science.gov (United States)

Ilatikhameneh, Hesameddin; Ameen, Tarek; Novakovic, Bozidar; Tan, Yaohua; Klimeck, Gerhard; Rahman, Rajib

2016-08-01

Scaling transistors’ dimensions has been the thrust for the semiconductor industry in the last four decades. However, scaling channel lengths beyond 10 nm has become exceptionally challenging due to the direct tunneling between source and drain which degrades gate control, switching functionality, and worsens power dissipation. Fortunately, the emergence of novel classes of materials with exotic properties in recent times has opened up new avenues in device design. Here, we show that by using channel materials with an anisotropic effective mass, the channel can be scaled down to 1 nm and still provide an excellent switching performance in phosphorene nanoribbon MOSFETs. To solve power consumption challenge besides dimension scaling in conventional transistors, a novel tunnel transistor is proposed which takes advantage of anisotropic mass in both ON- and OFF-state of the operation. Full-band atomistic quantum transport simulations of phosphorene nanoribbon MOSFETs and TFETs based on the new design have been performed as a proof.

Anisotropic evaluation of synthetic surgical meshes.

Science.gov (United States)

Saberski, E R; Orenstein, S B; Novitsky, Y W

2011-02-01

The material properties of meshes used in hernia repair contribute to the overall mechanical behavior of the repair. The anisotropic potential of synthetic meshes, representing a difference in material properties (e.g., elasticity) in different material axes, is not well defined to date. Haphazard orientation of anisotropic mesh material can contribute to inconsistent surgical outcomes. We aimed to characterize and compare anisotropic properties of commonly used synthetic meshes. Six different polypropylene (Trelex(®), ProLite™, Ultrapro™), polyester (Parietex™), and PTFE-based (Dualmesh(®), Infinit) synthetic meshes were selected. Longitudinal and transverse axes were defined for each mesh, and samples were cut in each axis orientation. Samples underwent uniaxial tensile testing, from which the elastic modulus (E) in each axis was determined. The degree of anisotropy (λ) was calculated as a logarithmic expression of the ratio between the elastic modulus in each axis. Five of six meshes displayed significant anisotropic behavior. Ultrapro™ and Infinit exhibited approximately 12- and 20-fold differences between perpendicular axes, respectively. Trelex(®), ProLite™, and Parietex™ were 2.3-2.4 times. Dualmesh(®) was the least anisotropic mesh, without marked difference between the axes. Anisotropy of synthetic meshes has been underappreciated. In this study, we found striking differences between elastic properties of perpendicular axes for most commonly used synthetic meshes. Indiscriminate orientation of anisotropic mesh may adversely affect hernia repairs. Proper labeling of all implants by manufacturers should be mandatory. Understanding the specific anisotropic behavior of synthetic meshes should allow surgeons to employ rational implant orientation to maximize outcomes of hernia repair.

Numerical analysis of anisotropic diffusion effect on ICF hydrodynamic instabilities

Directory of Open Access Journals (Sweden)

Olazabal-Loumé M.

2013-11-01

Full Text Available The effect of anisotropic diffusion on hydrodynamic instabilities in the context of Inertial Confinement Fusion (ICF flows is numerically assessed. This anisotropy occurs in indirect-drive when laminated ablators are used to modify the lateral transport [1,2]. In direct-drive, non-local transport mechanisms and magnetic fields may modify the lateral conduction [3]. In this work, numerical simulations obtained with the code PERLE [4], dedicated to linear stability analysis, are compared with previous theoretical results [5]. In these approaches, the diffusion anisotropy can be controlled by a characteristic coefficient which enables a comprehensive study. This work provides new results on the ablative Rayleigh-Taylor (RT, ablative Richtmyer-Meshkov (RM and Darrieus-Landau (DL instabilities.

A new model for spherically symmetric anisotropic compact star

Energy Technology Data Exchange (ETDEWEB)

Maurya, S.K.; Dayanandan, Baiju [University of Nizwa, Department of Mathematical and Physical Sciences, College of Arts and Science, Nizwa (Oman); Gupta, Y.K. [Raj Kumar Goel Institute of Technology, Department of Mathematics, Ghaziabad, UP (India); Ray, Saibal [Government College of Engineering and Ceramic Technology, Department of Physics, Kolkata, West Bengal (India)

2016-05-15

In this article we obtain a new anisotropic solution for Einstein's field equations of embedding class one metric. The solution represents realistic objects such as Her X-1 and RXJ 1856-37. We perform a detailed investigation of both objects by solving numerically the Einstein field equations with anisotropic pressure. The physical features of the parameters depend on the anisotropic factor i.e. if the anisotropy is zero everywhere inside the star then the density and pressures will become zero and the metric turns out to be flat. We report our results and compare with the above mentioned two compact objects as regards a number of key aspects: the central density, the surface density onset and the critical scaling behaviour, the effective mass and radius ratio, the anisotropization with isotropic initial conditions, adiabatic index and red shift. Along with this we have also made a comparison between the classical limit and theoretical model treatment of the compact objects. Finally we discuss the implications of our findings for the stability condition in a relativistic compact star. (orig.)

Magnetocaloric properties in La{sub 1−x}Ca{sub x}MnO{sub 3} thin films: Monte Carlo simulations

Energy Technology Data Exchange (ETDEWEB)

Restrepo-Parra, E., E-mail: erestrepopa@unal.edu.co; Ramos-Rivera, L.; Londoño-Navarro, J.

2014-02-15

The magnetocaloric effect (MCE) of La{sub 1−x}Ca{sub x}MnO{sub 3} was analyzed when varying the stoichiometry (x=0.2, 0.33, 0.4 and 0.5) and the external applied magnetic field. Simulations were carried out using the Monte Carlo method having a configuration ascribed by the set S{sub z} of all-site spin projections, under the Metropolis algorithm. La{sub 1−x}Ca{sub x}MnO{sub 3} is characterized for three types of magnetic ions corresponding to Mn{sup 4+} (S=3/2), which are bonded to Ca{sup 2+}, and Mn{sup 3+}(e{sub g}) and Mn{sup 3+}(e{sub g′}, S=2), which are both bonded to La{sup 3+}. Different interactions must be considered depending on the type of interacting ions. The entropy change ΔS in an isothermal process as well as the temperature change ΔT in an adiabatic process was determined with this model. Both ΔS and ΔT show stoichiometry-dependent maximums near the paramagnetic–ferromagnetic transition temperature (T{sub C}), confirming the order–disorder change at this temperature. The strong dependence in La{sub 1−x}Ca{sub x}MnO{sub 3} of the MCE on the stoichiometry and the external magnetic field makes this phenomenon important for different technological applications, particularly in refrigeration. - Highlights: • Thermal behavior of entropy, susceptibility and isothermal entropy change is studied. • ΔS and ΔT present a transition at the critical temperature depending on the stoichiometry. • Semi-classical Heisenberg Hamiltonian allows simulation of magnetocaloric effect in LCMO. • External magnetic field produces changes in ΔS and ΔT observed in the shifting of T{sub C}.

Anomalously large anisotropic magnetoresistance in a perovskite manganite

Science.gov (United States)

Li, Run-Wei; Wang, Huabing; Wang, Xuewen; Yu, X. Z.; Matsui, Y.; Cheng, Zhao-Hua; Shen, Bao-Gen; Plummer, E. Ward; Zhang, Jiandi

2009-01-01

The signature of correlated electron materials (CEMs) is the coupling between spin, charge, orbital and lattice resulting in exotic functionality. This complexity is directly responsible for their tunability. We demonstrate here that the broken symmetry, through cubic to orthorhombic distortion in the lattice structure in a prototype manganite single crystal, La0.69Ca0.31MnO3, leads to an anisotropic magneto-elastic response to an external field, and consequently to remarkable magneto-transport behavior. An anomalous anisotropic magnetoresistance (AMR) effect occurs close to the metal-insulator transition (MIT) in the system, showing a direct correlation with the anisotropic field-tuned MIT in the system and can be understood by means of a simple phenomenological model. A small crystalline anisotropy stimulates a “colossal” AMR near the MIT phase boundary of the system, thus revealing the intimate interplay between magneto- and electronic-crystalline couplings. PMID:19706504

The right circular polarized waves in the three-dimensional anisotropic dispersive photonic crystals consisting of the magnetized plasma and uniaxial material as the Faraday effects considered

International Nuclear Information System (INIS)

Zhang, Hai-Feng; Liu, Shao-Bin; Tang, Yi-Jun; Zhen, Jian-Ping

2014-01-01

In this paper, the properties of the right circular polarized (RCP) waves in the three-dimensional (3D) dispersive photonic crystals (PCs) consisting of the magnetized plasma and uniaxial material with face-centered-cubic (fcc) lattices are theoretically investigated by the plane wave expansion method, which the homogeneous anisotropic dielectric spheres (the uniaxial material) immersed in the magnetized plasma background, as the Faraday effects of magnetized plasma are considered (the incidence electromagnetic wave vector is parallel to the external magnetic field at any time). The equations for calculating the anisotropic photonic band gaps (PBGs) for the RCP waves in the first irreducible Brillouin zone are theoretically deduced. The anisotropic PBGs and a flatbands region can be obtained. The effects of the ordinary-refractive index, extraordinary-refractive index, anisotropic dielectric filling factor, plasma frequency, and plasma cyclotron frequency (the external magnetic field) on the properties of first two anisotropic PBGs for the RCP waves are investigated in detail, respectively. The numerical results show that the anisotropy can open partial band gaps in fcc lattices at U and W points, and the complete PBGs for the RCP waves can be achieved compared to the conventional 3D dispersive PCs composed of the magnetized plasma and isotropic material. It is also shown that the first two anisotropic PBGs can be tuned by those parameters as mentioned above. Those PBGs can be enlarged by introducing the uniaxial material into such 3D PCs as the Faraday effects are considered

Magnetic properties and low-temperature large magnetocaloric effect in the antiferromagnetic HoCu{sub 0.33}Ge{sub 2} and ErCu{sub 0.25}Ge{sub 2} compounds

Energy Technology Data Exchange (ETDEWEB)

Gao, R.L. [School of Metallurgy and Materials Engineering, Chongqing University of Science and Technology, Chongqing 401331 (China); Xu, Z.Y., E-mail: zhyxu@nim.ac.cn [National Institute of Metrology, Beijing 100029 (China); Wang, L.C. [State Key Laboratory for Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Dong, Q.Y.; Zhang, Y. [Department of Physics, Capital Normal University, Beijing 100048 (China); Liu, F.H. [National Space Science Center, Beijing 100190 (China); Mo, Z.J. [School of material Science and Engineering, Hebei University of Technology, Tianjin 300401 (China); Niu, E. [State Key Laboratory for Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Fu, C.L.; Cai, W.; Chen, G.; Deng, X.L. [School of Metallurgy and Materials Engineering, Chongqing University of Science and Technology, Chongqing 401331 (China)

2015-05-15

Highlights: • Antiferromagnetic material RCu{sub x}Ge{sub 2} of high purity was prepared. • Large MCE as −10.2 J/kg K and −10.5 J/kg K for RCu{sub x}Ge{sub 2} (Ho, Er) was obtained for field change of 0–50 kOe. • The RCu{sub x}Ge{sub 2} compounds with variable x had different transition temperature which made them suitable for ‘table-like’ magnetocaloric refrigerant. - Abstract: Magnetic properties and magnetocaloric effect (MCE) of HoCu{sub 0.33}Ge{sub 2} and ErCu{sub 0.25}Ge{sub 2} compounds have been investigated. The compounds were determined to be antiferromagnetic with the Néel temperatures T{sub N} = 9 K and 3.9 K, respectively. The critical transition magnetic fields for the metamagnetic transition from antiferromagnetic to ferromagnetic state below T{sub N} were determined to be 10 kOe for HoCu{sub 0.33}Ge{sub 2} at 5 K and 6 kOe for ErCu{sub 0.25}Ge{sub 2} at 2 K. Large MCE with the maximal values of magnetic entropy changes (ΔS{sub M}) as −10.2 J/kg K at 10.5 K were found in HoCu{sub 0.33}Ge{sub 2} for field changes of 0–70 kOe and −10.5 J/kg K at 5.5 K in ErCu{sub 0.25}Ge{sub 2} for field changes of 0–50 kOe, respectively. The large ΔS{sub M} around T{sub N} as well as no hysteresis loss made RCu{sub x}Ge{sub 2} competitive candidates as low temperature magnetic refrigerant.

Odd number of coupled antiferromagnetic anisotropic Heisenberg chains: Spin wave theory

International Nuclear Information System (INIS)

Benyoussef, A.

1996-10-01

The effect of the chain and perpendicular anisotropies on the energy gap for odd number of coupled quantum spin-1/2 antiferromagnetic anisotropic Heisenberg chains is investigated using a spin wave theory. The energy gap opens above a critical anisotropic value. The known results of the isotropic case have been obtained. (author). 11 refs, 4 figs

Anisotropic dynamic mass density for fluidsolid composites

KAUST Repository

Wu, Ying; Mei, Jun; Sheng, Ping

2012-01-01

By taking the low frequency limit of multiple-scattering theory, we obtain the dynamic effective mass density of fluidsolid composites with a two-dimensional rectangular lattice structure. The anisotropic mass density can be described by an angle

Anisotropic Weyl invariance

Energy Technology Data Exchange (ETDEWEB)

Perez-Nadal, Guillem [Universidad de Buenos Aires, Buenos Aires (Argentina)

2017-07-15

We consider a non-relativistic free scalar field theory with a type of anisotropic scale invariance in which the number of coordinates ''scaling like time'' is generically greater than one. We propose the Cartesian product of two curved spaces, the metric of each space being parameterized by the other space, as a notion of curved background to which the theory can be extended. We study this type of geometries, and find a family of extensions of the theory to curved backgrounds in which the anisotropic scale invariance is promoted to a local, Weyl-type symmetry. (orig.)

Effect of anisotropic plasticity on mixed mode interface crack growth

DEFF Research Database (Denmark)

Tvergaard, Viggo; Legarth, Brian Nyvang

2007-01-01

different anisotropic yield criteria to account for the plastic anisotropy. Conditions of small-scale yielding are assumed, and due to the mismatch of elastic properties across the interface the corresponding oscillating stress singularity field is applied as boundary conditions on the outer edge...

Algebraic collapsing acceleration of the characteristics method with anisotropic scattering

International Nuclear Information System (INIS)

Le Tellier, R.; Hebert, A.; Roy, R.

2004-01-01

In this paper, the characteristics solvers implemented in the lattice code Dragon are extended to allow a complete anisotropic treatment of the collision operator. An efficient synthetic acceleration method, called Algebraic Collapsing Acceleration (ACA), is presented. Tests show that this method can substantially speed up the convergence of scattering source iterations. The effect of boundary conditions, either specular or white reflections, on anisotropic scattering lattice-cell problems is also considered. (author)

Enhancement of Magnetocaloric Effect in ({ {La}}_{0.67}{ {Ca}}_{0.33}{ {MnO}}_{3})/({ {La}}_{0.7}{ {Ba}}_{0.3}{ {MnO}}_{3}) ( La 0.67 Ca 0.33 MnO 3 ) / ( La 0.7 Ba 0.3 MnO 3 ) Composite

Science.gov (United States)

Khelifi, J.; Dhahri, E.; Hlil, E. K.

2018-03-01

The composite (La_{0.67}Ca_{0.33}MnO3)/La_{0.7}Ba_{0.3}MnO3) sample was prepared using the conventional solid-state reaction method, and their crystallographic structure was achieved by X-ray diffraction pattern analysis. The magnetic and magnetocaloric effect has been studied by magnetization measurements. Based on the relation: χ ^{-1}(T)∝ (T-T_C^Rand )^{1-λ }, the inverse of susceptibility shows a downturn before T_C indicating the existence of Griffiths phase for the temperature range T_C^Randphase has been obtained from detailed magnetization studies. Furthermore, a large magnetic entropy change is observed in (La_{0.67}Ca_{0.33}MnO3)/(La_{0.7}Ba_{0.3}MnO3) composite which possesses a large MCE characterized by two Δ S_M(T) peaks. It has revealed that the combination of manganite materials with different Curie temperatures is a possible method for enhancement of magnetocaloric effect. To determine the field dependence of the experimental Δ S_M(T), a local exponent n( T, H) can be calculated from the logarithmic derivative of the magnetic entropy change versus field; it is shown that for a multiphase system n evolves with field both at the Curie temperature of the system and at the Curie temperatures of the constituent phases.

Preconditioned conjugate gradient technique for the analysis of symmetric anisotropic structures

Science.gov (United States)

Noor, Ahmed K.; Peters, Jeanne M.

1987-01-01

An efficient preconditioned conjugate gradient (PCG) technique and a computational procedure are presented for the analysis of symmetric anisotropic structures. The technique is based on selecting the preconditioning matrix as the orthotropic part of the global stiffness matrix of the structure, with all the nonorthotropic terms set equal to zero. This particular choice of the preconditioning matrix results in reducing the size of the analysis model of the anisotropic structure to that of the corresponding orthotropic structure. The similarities between the proposed PCG technique and a reduction technique previously presented by the authors are identified and exploited to generate from the PCG technique direct measures for the sensitivity of the different response quantities to the nonorthotropic (anisotropic) material coefficients of the structure. The effectiveness of the PCG technique is demonstrated by means of a numerical example of an anisotropic cylindrical panel.

Influence of Mn incorporation for Ni on the magnetocaloric properties of rapidly solidified off-stoichiometric NiMnGa ribbons

Energy Technology Data Exchange (ETDEWEB)

Dey, Sushmita; Singh, Satnam; Roy, R.K.; Ghosh, M.; Mitra, A.; Panda, A.K., E-mail: akpanda@nmlindia.org

2016-01-01

The present investigation addresses the magnetocaloric behaviour in a series of Ni{sub 77−x}Mn{sub x}Ga{sub 23} (x=23, 24, 25, 27 and 29) rapidly solidified alloys prepared in the form of ribbons by melt spinning technique. The approach of the study is to identify the off-stoichiometric composition wherein room temperature magneto-structural transformation is achieved. The alloy chemistry was tailored through Mn incorporation for Ni such that the magnetic and structural transitions were at close proximity to achieve highest entropy value of ΔS equal to 8.51 J Kg{sup −1} K{sup −1} for #Mn{sub 24} ribbon measured at an applied field of 3 T. When such transitions are more staggered as in #Mn{sub 29} the entropy value of ribbon reduced to as low as 1.61 J Kg{sup −1} K{sup −1}. Near room temperature transformations in #Mn{sub 24} ribbon have been observed through calorimetric and thermomagnetic evaluation. Reverse martensitic transformation (martensite→autstenite) temperature indicates not only distinct change in the saturation flux density but also an inter-martensitic phase. Microstructural analysis of #Mn{sub 24} alloy ribbon revealed structural ordering with the existence of plate morphology evidenced for martensitic phase. - Highlights: • Magnetocaloric effect in a series of melt spun NiMnGa ribbon is addressed. • The alloy series revealed austenitic state as well as its presence with martensite. • The morphology of the ribbons has been shown and discussed through phase analysis. • Influence of magnetising field on entropy and relative cooling power is discussed. • Influence of intermartensitic state on magnetization plots have also been shown.

Anisotropic surface chemistry properties and adsorption behavior of silicate mineral crystals.

Science.gov (United States)

Xu, Longhua; Tian, Jia; Wu, Houqin; Fang, Shuai; Lu, Zhongyuan; Ma, Caifeng; Sun, Wei; Hu, Yuehua

2018-03-07

Anisotropic surface properties of minerals play an important role in a variety of fields. With a focus on the two most intensively investigated silicate minerals (i.e., phyllosilicate minerals and pegmatite aluminosilicate minerals), this review highlights the research on their anisotropic surface properties based on their crystal structures. Four surface features comprise the anisotropic surface chemistry of minerals: broken bonds, energy, wettability, and charge. Analysis of surface broken bond and energy anisotropy helps to explain the cleavage and growth properties of mineral crystals, and understanding surface wettability and charge anisotropy is critical to the analysis of minerals' solution behavior, such as their flotation performance and rheological properties. In a specific reaction, the anisotropic surface properties of minerals are reflected in the adsorption strengths of reagents on different mineral surfaces. Combined with the knowledge of mineral crushing and grinding, a thorough understanding of the anisotropic surface chemistry properties and the anisotropic adsorption behavior of minerals will lead to the development of effective relational models comprising their crystal structure, surface chemistry properties, and targeted reagent adsorption. Overall, such a comprehensive approach is expected to firmly establish the connection between selective cleavage of mineral crystals for desired surfaces and designing novel reagents selectively adsorbed on the mineral surfaces. As tools to characterize the anisotropic surface chemistry properties of minerals, DLVO theory, atomic force microscopy (AFM), and molecular dynamics (MD) simulations are also reviewed. Copyright © 2017 Elsevier B.V. All rights reserved.

Features of the electric-field distribution in anisotropic semiconductor wafers in a transverse magnetic field

International Nuclear Information System (INIS)

Filippov, V. V.; Bormontov, E. N.

2013-01-01

A macroscopic model of the Hall effects and magnetoresistance in anisotropic semiconductor wafers is developed. The results obtained by solving the electrodynamic boundary problem allow the potential and eddy currents in anisotropic semiconductors to be calculated at different current-contact locations, depending on the parameters of the sample material’s anisotropy. The results of this study are of great practical importance for investigating the physical properties of anisotropic semiconductors and simulating the electron-transport phenomena in devices based on anisotropic semiconductors

Features of the electric-field distribution in anisotropic semiconductor wafers in a transverse magnetic field

Energy Technology Data Exchange (ETDEWEB)

Filippov, V. V., E-mail: wwfilippow@mail.ru [Lipetsk State Pedagogical University (Russian Federation); Bormontov, E. N. [Voronezh State University (Russian Federation)

2013-07-15

A macroscopic model of the Hall effects and magnetoresistance in anisotropic semiconductor wafers is developed. The results obtained by solving the electrodynamic boundary problem allow the potential and eddy currents in anisotropic semiconductors to be calculated at different current-contact locations, depending on the parameters of the sample material's anisotropy. The results of this study are of great practical importance for investigating the physical properties of anisotropic semiconductors and simulating the electron-transport phenomena in devices based on anisotropic semiconductors.

Magnetic, transport, and magnetocaloric properties of boron doped Ni-Mn-In alloys

Energy Technology Data Exchange (ETDEWEB)

Pandey, S.; Quetz, A.; Aryal, A.; Dubenko, I.; Ali, N. [Department of Physics, Southern Illinois University, Carbondale, Illinois 62902 (United States); Rodionov, I. D.; Blinov, M. I.; Titov, I. S.; Prudnikov, V. N.; Granovsky, A. B. [Faculty of Physics, Lomonosov Moscow State University, Moscow 119991 (Russian Federation); Stadler, S. [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803 (United States)

2015-05-14

The impact of B substitution in Ni{sub 50}Mn{sub 35}In{sub 15−x}B{sub x} Heusler alloys on the structural, magnetic, transport, and parameters of the magnetocaloric effect (MCE) has been studied by means of room-temperature X-ray diffraction and thermomagnetic measurements (in magnetic fields (H) up to 5 T, and in the temperature interval 5–400 K). Direct adiabatic temperature change (ΔT{sub AD}) measurements have been carried out for an applied magnetic field change of 1.8 T. The transition temperatures (T-x) phase diagram has been constructed for H = 0.005 T. The MCE parameters were found to be comparable to those observed in other MCE materials such as Ni{sub 50}Mn{sub 34.8}In{sub 14.2}B and Ni{sub 50}Mn{sub 35}In{sub 14}X (X=In, Al, and Ge) Heusler alloys. The maximum absolute value of ΔT{sub AD} = 2.5 K was observed at the magnetostructural transition for Ni{sub 50}Mn{sub 35}In{sub 14.5}B{sub 0.5}.

Anisotropic hypersonic phonon propagation in films of aligned ellipsoids.

Science.gov (United States)

Beltramo, Peter J; Schneider, Dirk; Fytas, George; Furst, Eric M

2014-11-14

A material with anisotropic elastic mechanical properties and a direction-dependent hypersonic band gap is fabricated using ac electric field-directed convective self-assembly of colloidal ellipsoids. The frequency of the gap, which is detected in the direction perpendicular to particle alignment and entirely absent parallel to alignment, and the effective sound velocities can be tuned by the particle aspect ratio. We hypothesize that the band gap originates from the primary eigenmode peak, the m-splitted (s,1,2) mode, of the particle resonating with the effective medium. These results reveal the potential for powerful control of the hypersonic phononic band diagram by combining anisotropic particles and self-assembly.

Comparison of the order of magnetic phase transitions in several magnetocaloric materials using the rescaled universal curve, Banerjee and mean field theory criteria

Energy Technology Data Exchange (ETDEWEB)

Burrola-Gándara, L. A., E-mail: andres.burrola@gmail.com; Santillan-Rodriguez, C. R.; Rivera-Gomez, F. J.; Saenz-Hernandez, R. J.; Botello-Zubiate, M. E.; Matutes-Aquino, J. A. [Departamento de Física de Materiales, Centro de Investigación en Materiales Avanzados, S.C., Miguel de Cervantes 120, Complejo Industrial Chihuahua, Chihuahua 31109 (Mexico)

2015-05-07

Magnetocaloric materials with second order phase transition near the Curie temperature can be described by critical phenomena theory. In this theory, scaling, universality, and renormalization are key concepts from which several phase transition order criteria are derived. In this work, the rescaled universal curve, Banerjee and mean field theory criteria were used to make a comparison for several magnetocaloric materials including pure Gd, SmCo{sub 1.8}Fe{sub 0.2}, MnFeP{sub 0.46}As{sub 0.54}, and La{sub 0.7}Ca{sub 0.15}Sr{sub 0.15}MnO{sub 3}. Pure Gd, SmCo{sub 1.8}Fe{sub 0.2}, and La{sub 0.7}Ca{sub 0.15}Sr{sub 0.15}MnO{sub 3} present a collapse of the rescaled magnetic entropy change curves into a universal curve, which indicates a second order phase transition; applying Banerjee criterion to H/σ vs σ{sup 2} Arrot plots and the mean field theory relation |ΔS{sub M}| ∝ (μ{sub 0}H/T{sub c}){sup 2/3} for the same materials also determines a second order phase transition. However, in the MnFeP{sub 0.46}As{sub 0.54} sample, the Banerjee criterion applied to the H/σ vs σ{sup 2} Arrot plot indicates a first order magnetic phase transition, while the mean field theory prediction for a second order phase transition, |ΔS{sub M}| ∝ (μ{sub 0}H/T{sub c}){sup 2/3}, describes a second order behavior. Also, a mixture of first and second order behavior was indicated by the rescaled universal curve criterion. The diverse results obtained for each criterion in MnFeP{sub 0.46}As{sub 0.54} are apparently related to the magnetoelastic effect and to the simultaneous presence of weak and strong magnetism in Fe (3f) and Mn (3g) alternate atomic layers, respectively. The simultaneous application of the universal curve, the Banerjee and the mean field theory criteria has allowed a better understanding about the nature of the order of the phase transitions in different magnetocaloric materials.

Phase formation kinetics, hardness and magnetocaloric effect of sub-rapidly solidified LaFe11.6Si1.4 plates during isothermal annealing

Science.gov (United States)

Dai, Yuting; Xu, Zhishuai; Luo, Zhiping; Han, Ke; Zhai, Qijie; Zheng, Hongxing

2018-05-01

High-temperature phase transition behavior and intrinsic brittleness of NaZn13-type τ1 phase in La-Fe-Si magnetocaloric materials are two key problems from the viewpoint of materials production and practical applications. In the present work, the Johnson-Mehl-Avrami-Kolmogorov (JMAK) equation was introduced to quantitatively characterize the formation kinetics of τ1 phase in sub-rapidly solidified LaFe11.6Si1.4 plates during the isothermal annealing process. Avrami index was estimated to be 0.43 (∼0.5), which suggests that the formation of τ1 phase is in a diffusion-controlled one-dimensional growth mode. Meanwhile, it is found that the Vickers hardness as a function of annealing time for sub-rapidly solidified plates also agrees well with the JMAK equation. The Vickers hardness of τ1 phase was estimated to be about 754. Under a magnetic field change of 30 kOe, the maximum magnetic entropy change was about 22.31 J/(kg·K) for plates annealed at 1323 K for 48 h, and the effective magnetic refrigeration capacity reached 191 J/kg.

Anisotropic diffusion tensor applied to temporal mammograms

DEFF Research Database (Denmark)

Karemore, Gopal; Brandt, Sami; Sporring, Jon

2010-01-01

changes related to  specific  effects  like  Hormonal  Replacement  Therapy  (HRT) and aging. Given effect-grouped patient data, we demonstrated how  anisotropic  diffusion  tensor  and  its  coherence  features computed in an anatomically oriented breast coordinate system followed by statistical learning...

The influence of the anisotropic stress state on the intermediate strain properties of granular material

KAUST Repository

Goudarzy, M.

2017-07-20

This paper shows the effect of anisotropic stress state on intermediate strain properties of cylindrical samples containing spherical glass particles. Tests were carried out with the modified resonant column device available at Ruhr-Universität Bochum. Dry samples were subjected to two anisotropic stress states: (a) cell pressure, σ′h, constant and vertical stress, σ′v, increased (stress state GB-I) and (b) σ′v/σ′h equal to 2 (stress state GB-II). The experimental results revealed that the effect of stress state GB-II on the modulus and damping ratio was more significant and obvious than stress state GB-I. The effect of the anisotropic stress state was explained through the impact of confining pressure and anisotropic stress components on the stiffness and damping ratio. The results showed that: (a) G(γ) increased, η(γ) decreased and their strain non-linearity decreased with an increase in the confining pressure component σ′vσ′h; (b) G(γ) decreased, η(γ) increased and their strain non-linearity increased with an increase in the anisotropic stress component, σ′v/σ′h. The analysis of results revealed that reference shear strain was also affected by anisotropic stress state. Therefore, an empirical relationship was developed to predict the reference shear strain, as a function of confining pressure and anisotropic stress components. Additionally, the damping ratio was written as a function of the minimum damping ratio and the reference shear strain.

An analytical model of anisotropic low-field electron mobility in wurtzite indium nitride

International Nuclear Information System (INIS)

Wang, Shulong; Liu, Hongxia; Song, Xin; Guo, Yulong; Yang, Zhaonian

2014-01-01

This paper presents a theoretical analysis of anisotropic transport properties and develops an anisotropic low-field electron analytical mobility model for wurtzite indium nitride (InN). For the different effective masses in the Γ-A and Γ-M directions of the lowest valley, both the transient and steady state transport behaviors of wurtzite InN show different transport characteristics in the two directions. From the relationship between velocity and electric field, the difference is more obvious when the electric field is low in the two directions. To make an accurate description of the anisotropic transport properties under low field, for the first time, we present an analytical model of anisotropic low-field electron mobility in wurtzite InN. The effects of different ionized impurity scattering models on the low-field mobility calculated by Monte Carlo method (Conwell-Weisskopf and Brooks-Herring method) are also considered. (orig.)

Self-force on dislocation segments in anisotropic crystals

International Nuclear Information System (INIS)

Fitzgerald, S P; Aubry, S

2010-01-01

A dislocation segment in a crystal experiences a 'self-force', by virtue of the orientation dependence of its elastic energy. If the crystal is elastically isotropic, this force is manifested as a couple acting to rotate the segment toward the lower energy of the pure screw orientation (i.e. acting to align the dislocation line with its Burgers vector). If the crystal is anisotropic, there are additional contributions to the couple, arising from the more complex energy landscape of the lattice itself. These effects can strongly influence the dynamic evolution of dislocation networks, and via their governing role in dislocation multiplication phenomena, control plastic flow in metals. In this paper we develop a model for dislocation self-forces in a general anisotropic crystal, and briefly consider the technologically important example of α-iron, which becomes increasingly anisotropic as the temperature approaches that of the α-γ phase transition at 912 0 C.

Continuum mechanics of anisotropic materials

CERN Document Server

Cowin, Stephen C

2013-01-01

Continuum Mechanics of Anisotropic Materials(CMAM) presents an entirely new and unique development of material anisotropy in the context of an appropriate selection and organization of continuum mechanics topics. These features will distinguish this continuum mechanics book from other books on this subject. Textbooks on continuum mechanics are widely employed in engineering education, however, none of them deal specifically with anisotropy in materials. For the audience of Biomedical, Chemical and Civil Engineering students, these materials will be dealt with more frequently and greater accuracy in their analysis will be desired. Continuum Mechanics of Anisotropic Materials' author has been a leader in the field of developing new approaches for the understanding of anisotropic materials.

Anisotropic Thermoelectric Devices Made from Single-Crystal Semimetal Microwires in Glass Coating

Science.gov (United States)

Konopko, L. A.; Nikolaeva, A. A.; Kobylianskaya, A. K.; Huber, T. E.

2018-04-01

Thermoelectric heat conversion based on the Seebeck and Peltier effects generated at the junction between two materials of type-n and type-p is well known. Here, we present a demonstration of an unconventional thermoelectric energy conversion that is based on a single element made of an anisotropic material. In such materials, a heat flow generates a transverse thermoelectric electric field lying across the heat flow. Potentially, in applications involving miniature devices, the anisotropic thermoelectric (AT) effect has the advantage over traditional thermoelectrics that it simplifies the thermoelectric generator architecture. This is because the generator can be made of a single thermoelectric material without the complexity of a series of contacts forming a pile. A feature of anisotropic thermoelectrics is that the thermoelectric voltage is proportional to the element length and inversely proportional to the effective thickness. The AT effect has been demonstrated with artificial anisotropic thin film consisting of layers of alternating thermoelectric type, but there has been no demonstration of this effect in a long single-crystal. Electronic transport measurements have shown that the semimetal bismuth is highly anisotropic. We have prepared an experimental sample consisting of a 10-m-long glass-insulated single-crystal tin-doped bismuth microwire (d = 4 μm). Crucial for this experiment is the ability to grow the microwire as a single-crystal using a technique of recrystallization with laser heating and under a strong electric field. The sample was wound as a spiral, bonded to a copper disk, and used in various experiments. The sensitivity of the sample to heat flow is as high as 10-2 V/W with a time constant τ of about 0.5 s.

Anisotropic Thermoelectric Devices Made from Single-Crystal Semimetal Microwires in Glass Coating

Science.gov (United States)

Konopko, L. A.; Nikolaeva, A. A.; Kobylianskaya, A. K.; Huber, T. E.

2018-06-01

Thermoelectric heat conversion based on the Seebeck and Peltier effects generated at the junction between two materials of type- n and type- p is well known. Here, we present a demonstration of an unconventional thermoelectric energy conversion that is based on a single element made of an anisotropic material. In such materials, a heat flow generates a transverse thermoelectric electric field lying across the heat flow. Potentially, in applications involving miniature devices, the anisotropic thermoelectric (AT) effect has the advantage over traditional thermoelectrics that it simplifies the thermoelectric generator architecture. This is because the generator can be made of a single thermoelectric material without the complexity of a series of contacts forming a pile. A feature of anisotropic thermoelectrics is that the thermoelectric voltage is proportional to the element length and inversely proportional to the effective thickness. The AT effect has been demonstrated with artificial anisotropic thin film consisting of layers of alternating thermoelectric type, but there has been no demonstration of this effect in a long single-crystal. Electronic transport measurements have shown that the semimetal bismuth is highly anisotropic. We have prepared an experimental sample consisting of a 10-m-long glass-insulated single-crystal tin-doped bismuth microwire ( d = 4 μm). Crucial for this experiment is the ability to grow the microwire as a single-crystal using a technique of recrystallization with laser heating and under a strong electric field. The sample was wound as a spiral, bonded to a copper disk, and used in various experiments. The sensitivity of the sample to heat flow is as high as 10-2 V/W with a time constant τ of about 0.5 s.

Acoustic anisotropic wavefields through perturbation theory

KAUST Repository

Alkhalifah, Tariq Ali

2013-09-01

Solving the anisotropic acoustic wave equation numerically using finite-difference methods introduces many problems and media restriction requirements, and it rarely contributes to the ability to resolve the anisotropy parameters. Among these restrictions are the inability to handle media with η<0 and the presence of shear-wave artifacts in the solution. Both limitations do not exist in the solution of the elliptical anisotropic acoustic wave equation. Using perturbation theory in developing the solution of the anisotropic acoustic wave equation allows direct access to the desired limitation-free solutions, that is, solutions perturbed from the elliptical anisotropic background medium. It also provides a platform for parameter estimation because of the ability to isolate the wavefield dependency on the perturbed anisotropy parameters. As a result, I derive partial differential equations that relate changes in the wavefield to perturbations in the anisotropy parameters. The solutions of the perturbation equations represented the coefficients of a Taylor-series-type expansion of the wavefield as a function of the perturbed parameter, which is in this case η or the tilt of the symmetry axis. The expansion with respect to the symmetry axis allows use of an acoustic transversely isotropic media with a vertical symmetry axis (VTI) kernel to estimate the background wavefield and the corresponding perturbation coefficients. The VTI extrapolation kernel is about one-fourth the cost of the transversely isotropic model with a tilt in the symmetry axis kernel. Thus, for a small symmetry axis tilt, the cost of migration using a first-order expansion can be reduced. The effectiveness of the approach was demonstrated on the Marmousi model.

SO-FDTD analysis of anisotropic magnetized plasma

International Nuclear Information System (INIS)

Yang Hongwei; Nanjing Univ. of Science and Technology, Nanjing; Yuan Hong; Chen Rushan; Yang Yang

2007-01-01

A novel finite-difference time-domain (FDTD) method, called shift operator FDTD (SO-FDTD) method is developed for anisotropic magnetized dispersive media. The recursive relation between operators is used. In this paper, some expressions containing the dielectric constants of magnetized dispersive media are written as rational polynomial function. The SO-FDTD formulation for anisotropic magnetized plasma is derived. The high efficiency and effectiveness of the method are confirmed by computing the reflection and transmission through a magnetized plasma layer, with the direction of the propagation parallel to the direction of the biasing field. A comparison with frequency domain analytic results is included. The CPU time was several times shorter than that of the JEC method. (authors)

Inflationary perturbations in anisotropic, shear-free universes

International Nuclear Information System (INIS)

Pereira, Thiago S.; Carneiro, Saulo; Marugan, Guillermo A. Mena

2012-01-01

In this work, the linear and gauge-invariant theory of cosmological perturbations in a class of anisotropic and shear-free spacetimes is developed. After constructing an explicit set of complete eigenfunctions in terms of which perturbations can be expanded, we identify the effective degrees of freedom during a generic slow-roll inflationary phase. These correspond to the anisotropic equivalent of the standard Mukhanov-Sasaki variables. The associated equations of motion present a remarkable resemblance to those found in perturbed Friedmann-Robertson-Walker spacetimes with curvature, apart from the spectrum of the Laplacian, which exhibits the characteristic frequencies of the underlying geometry. In particular, it is found that the perturbations cannot develop arbitrarily large super-Hubble modes

Nonlinear constitutive relations for anisotropic elastic materials

Science.gov (United States)

Sokolova, Marina; Khristich, Dmitrii

2018-03-01

A general approach to constructing of nonlinear variants of connection between stresses and strains in anisotropic materials with different types of symmetry of properties is considered. This approach is based on the concept of elastic proper subspaces of anisotropic materials introduced in the mechanics of solids by J. Rychlewski and on the particular postulate of isotropy proposed by A. A. Il’yushin. The generalization of the particular postulate on the case of nonlinear anisotropic materials is formulated. Systems of invariants of deformations as lengths of projections of the strain vector into proper subspaces are developed. Some variants of nonlinear constitutive relations for anisotropic materials are offered. The analysis of these relations from the point of view of their satisfaction to general and limit forms of generalization of partial isotropy postulate on anisotropic materials is performed. The relations for particular cases of anisotropy are written.

Characterization of Anisotropic Behavior for High Grade Pipes

Science.gov (United States)

Yang, Kun; Huo, Chunyong; Ji, Lingkang; Li, Yang; Zhang, Jiming; Ma, Qiurong

With the developing requirement of nature gas, the property needs of steel for pipe line are higher and higher, especially in strength and toughness. It is necessary to improve the steel grade in order to ensure economic demand and safety. However, with the rise of steel grade, the differences on properties in different orientations (anisotropic behaviors) become more and more obvious after the process of hot rolling, which may affect the prediction of fracture for the pipes seriously (Thinking of isotropic mechanical properties for material in traditional predict way). In order to get the reason for anisotropic mechanics, a series of tests are carried out for high grade steel pipes, including not only mechanical properties but also microstructures. Result indicates that there are obviously anisotropic behaviors for high grade steel pipes in two orientations (rolling orientation and transverse orientation). Strength is better in T orientation because Rm is higher and Rt 0.5 rises more in T orientation, and toughness is better in L orientation because of the higher Akv and SA in L orientation under a same temperature. Banded structures are formed in T orientation, and the spatial distribution of inclusion and precipitated phases are different in T, L and S orientation. The anisotropic arrangement for the matrix in space (banded structures), which is formed after the process of hot rolling, may affect the mechanical properties in different orientation. Moreover, the elasticity modulus of particles is different from the elasticity modulus of matrix, deformation between particles and matrix may cause stress concentration, and damage forms in this place. Because of the different distribution of particles in space, the level of damage is anisotropic in different orientations, and the anisotropic mechanical properties occur finally. Therefore, the anisotropic mechanical properties are determined by the anisotropic microstructures, both the anisotropic of matrix and the

Orthonormal bases for anisotropic α-modulation spaces

DEFF Research Database (Denmark)

Rasmussen, Kenneth Niemann

2012-01-01

In this article we construct orthonormal bases for bi-variate anisotropic α-modulation spaces. The construction is based on generating a nice anisotropic α-covering and using carefully selected tensor products of univariate brushlet functions with regards to this covering. As an application, we...... show that n-term nonlinear approximation with the orthonormal bases in certain anisotropic α-modulation spaces can be completely characterized....

Orthonormal bases for anisotropic α-modulation spaces

DEFF Research Database (Denmark)

Rasmussen, Kenneth Niemann

In this article we construct orthonormal bases for bi-variate anisotropic α-modulation spaces. The construction is based on generating a nice anisotropic α-covering and using carefully selected tensor products of univariate brushlet functions with regards to this covering. As an application, we...... show that n-term nonlinear approximation with the orthonormal bases in certain anisotropic α-modulation spaces can be completely characterized....

Finite-volume scheme for anisotropic diffusion

Energy Technology Data Exchange (ETDEWEB)

Es, Bram van, E-mail: bramiozo@gmail.com [Centrum Wiskunde & Informatica, P.O. Box 94079, 1090GB Amsterdam (Netherlands); FOM Institute DIFFER, Dutch Institute for Fundamental Energy Research, The Netherlands" 1 (Netherlands); Koren, Barry [Eindhoven University of Technology (Netherlands); Blank, Hugo J. de [FOM Institute DIFFER, Dutch Institute for Fundamental Energy Research, The Netherlands" 1 (Netherlands)

2016-02-01

In this paper, we apply a special finite-volume scheme, limited to smooth temperature distributions and Cartesian grids, to test the importance of connectivity of the finite volumes. The area of application is nuclear fusion plasma with field line aligned temperature gradients and extreme anisotropy. We apply the scheme to the anisotropic heat-conduction equation, and compare its results with those of existing finite-volume schemes for anisotropic diffusion. Also, we introduce a general model adaptation of the steady diffusion equation for extremely anisotropic diffusion problems with closed field lines.

A pathway to optimize the properties of magnetocaloric Mn_2_-_xFe_xP_1_-_yGe_y for magnetic refrigeration

International Nuclear Information System (INIS)

Liu, D.M.; Zhang, Z.L.; Zhou, S.L.; Huang, Q.Z.; Deng, X.J.; Yue, M.; Liu, C.X.; Zhang, J.X.; Lynn, J.W.

2016-01-01

Magnetocaloric materials can be useful in magnetic refrigeration applications, but to be practical the magneto-refrigerant needs to have a very large magnetocaloric effect (MCE) near room temperature for modest applied fields (<2 T) with small hysteresis and magnetostriction, and should have a complete magnetic transition, and environmentally friendly. One system that may fulfill these requirements is Mn_2_-_xFe_xP_1_-_yGe_y, where a combined first-order structural and magnetic transition occurs between the high temperature paramagnetic and low temperature ferromagnetic phase. We have used neutron diffraction, differential scanning calorimetry, and magnetization measurements to study the effects of Mn and Ge location in the structure on the ordered magnetic moment, MCE, and hysteresis for a series of compositions of the system near optimal doping. The diffraction results indicate that the Mn ions located on the 3f site enhance the desirable properties, while those located on the 3 g sites are detrimental. The phase fraction that transforms, hysteresis of the transition, and entropy change can be affected greatly by both the compositional homogeneity and the particle size, and an annealing procedure has been developed that substantially improves the performance of all three properties of the material. We also establish a correlation between applied magnetic field to complete the transition and the temperature range of coexistence of the PM and FM phase. On the basis of these results we have identified a pathway to understand the nature and to optimize the MCE properties of this system for magnetic refrigeration applications. - Highlights: • Compositional homogeneity and particle size affect the MCE properties. • Mn ions located on the 3f site enhance the desirable MCE properties. • A pathway to understand the nature and to optimize the MCE properties was identified.

A Magnetocaloric Pump for Lab-On-A-Chip Technology: Phase I Report

Energy Technology Data Exchange (ETDEWEB)

Love, LJL

2004-05-08

A magnetocaloric pump provides a simple means of pumping fluid using only external thermal and magnetic fields. The principle, which can be traced back to the early work of Rosensweig, is straightforward. Magnetic materials tend to lose their magnetization as the temperature approaches the material's Curie point. Exposing a column of magnetic fluid to a uniform magnetic field coincident with a temperature gradient produces a pressure gradient in the magnetic fluid. As the fluid heats up, it loses its attraction to the magnetic field and is displaced by cooler fluid. The impact of such a phenomenon is obvious: fluid propulsion with no moving mechanical parts. Until recently, limitations in the magnetic and thermal properties of conventional materials severely limited practical operating pressure gradients. However, recent advancements in the design of metal substituted magnetite enable fine control over both the magnetic and thermal properties of magnetic nanoparticles, a key element in colloidal based magnetic fluids (ferrofluids). This manuscript begins with a basic description of the process and previous limitations due to material properties. This is followed by a review of existing methods of synthesizing magnetic nanoparticles as well as an introduction to a new approach based on thermophilic metal-reducing bacteria. We compare two compounds and show, experimentally, significant variation in specific magnetic and thermal properties. We develop the constitutive thermal, magnetic, and fluid dynamic equations associated with magnetocaloric pump and validate our finite element model with a series of experiments. Preliminary results show a good match between the model and experiment as well as approximately an order of magnitude increase in the fluid flow rate over conventional magnetite based ferrofluids operating below 80 C. Finally, as a practical demonstration, we describe a novel application of this technology: pumping fluids at the &apos

Textile-templated electrospun anisotropic scaffolds for regenerative cardiac tissue engineering.

Science.gov (United States)

Şenel Ayaz, H Gözde; Perets, Anat; Ayaz, Hasan; Gilroy, Kyle D; Govindaraj, Muthu; Brookstein, David; Lelkes, Peter I

2014-10-01

For patients with end-stage heart disease, the access to heart transplantation is limited due to the shortage of donor organs and to the potential for rejection of the donated organ. Therefore, current studies focus on bioengineering approaches for creating biomimetic cardiac patches that will assist in restoring cardiac function, by repairing and/or regenerating the intrinsically anisotropic myocardium. In this paper we present a simplified, straightforward approach for creating bioactive anisotropic cardiac patches, based on a combination of bioengineering and textile-manufacturing techniques in concert with nano-biotechnology based tissue-engineering stratagems. Using knitted conventional textiles, made of cotton or polyester yarns as template targets, we successfully electrospun anisotropic three-dimensional scaffolds from poly(lactic-co-glycolic) acid (PLGA), and thermoplastic polycarbonate-urethane (PCU, Bionate(®)). The surface topography and mechanical properties of textile-templated anisotropic scaffolds significantly differed from those of scaffolds electrospun from the same materials onto conventional 2-D flat-target electrospun scaffolds. Anisotropic textile-templated scaffolds electrospun from both PLGA and PCU, supported the adhesion and proliferation of H9C2 cardiac myoblasts cell line, and guided the cardiac tissue-like anisotropic organization of these cells in vitro. All cell-seeded PCU scaffolds exhibited mechanical properties comparable to those of a human heart, but only the cells on the polyester-templated scaffolds exhibited prolonged spontaneous synchronous contractility on the entire engineered construct for 10 days in vitro at a near physiologic frequency of ∼120 bpm. Taken together, the methods described here take advantage of straightforward established textile manufacturing strategies as an efficient and cost-effective approach to engineering 3D anisotropic, elastomeric PCU scaffolds that can serve as a cardiac patch. Copyright �

Anisotropic Effective Mass, Optical Property, and Enhanced Band Gap in BN/Phosphorene/BN Heterostructures.

Science.gov (United States)

Hu, Tao; Hong, Jisang

2015-10-28

Phosphorene is receiving great research interests because of its peculiar physical properties. Nonetheless, the phosphorus has a trouble of degradation due to oxidation. Hereby, we propose that the electrical and optical anisotropic properties can be preserved by encapsulating into hexagonal boron nitride (h-BN). We found that the h-BN contributed to enhancing the band gap of the phosphorene layer. Comparing the band gap of the pristine phosphorene layer, the band gap of the phosphorene/BN(1ML) system was enhanced by 0.15 eV. It was further enhanced by 0.31 eV in the BN(1ML)/phosphorene/BN(1ML) trilayer structure. However, the band gap was not further enhanced when we increased the thickness of the h-BN layers even up to 4 MLs. Interestingly, the anisotropic effective mass and optical property were still preserved in BN/phosphorene/BN heterostructures. Overall, we predict that the capping of phosphorene by the h-BN layers can be an excellent solution to protect the intrinsic properties of the phosphorene.

Transient anisotropic magnetic field calculation

International Nuclear Information System (INIS)

Jesenik, Marko; Gorican, Viktor; Trlep, Mladen; Hamler, Anton; Stumberger, Bojan

2006-01-01

For anisotropic magnetic material, nonlinear magnetic characteristics of the material are described with magnetization curves for different magnetization directions. The paper presents transient finite element calculation of the magnetic field in the anisotropic magnetic material based on the measured magnetization curves for different magnetization directions. For the verification of the calculation method some results of the calculation are compared with the measurement

Modulation infrared thermometry of caloric effects at up to kHz frequencies

Science.gov (United States)

Döntgen, Jago; Rudolph, Jörg; Waske, Anja; Hägele, Daniel

2018-03-01

We present a novel non-contact method for the direct measurement of caloric effects in low volume samples. The adiabatic temperature change ΔT of a magnetocaloric sample is very sensitively determined from thermal radiation. Rapid modulation of ΔT is induced by an oscillating external magnetic field. Detection of thermal radiation with a mercury-cadmium-telluride detector allows for measurements at field frequencies exceeding 1 kHz. In contrast to thermoacoustic methods, our method can be employed in vacuum which enhances adiabatic conditions especially in the case of small volume samples. Systematic measurements of the magnetocaloric effect as a function of temperature, magnetic field amplitude, and modulation frequency give a detailed picture of the thermal behavior of the sample. Highly sensitive measurements of the magnetocaloric effect are demonstrated on a 2 mm thick sample of gadolinium and a 60 μm thick Fe80B12Nb8 ribbon.

Angle-domain common-image gathers from anisotropic Gaussian ...

Indian Academy of Sciences (India)

3State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Chengdu University of Technology,. Chengdu ... studied the extraction scheme of ADCIGs by using. Kirchhoff ..... The effect of shale properties on anisotropic brittleness.

Cosmological signatures of anisotropic spatial curvature

International Nuclear Information System (INIS)

Pereira, Thiago S.; Marugán, Guillermo A. Mena; Carneiro, Saulo

2015-01-01

If one is willing to give up the cherished hypothesis of spatial isotropy, many interesting cosmological models can be developed beyond the simple anisotropically expanding scenarios. One interesting possibility is presented by shear-free models in which the anisotropy emerges at the level of the curvature of the homogeneous spatial sections, whereas the expansion is dictated by a single scale factor. We show that such models represent viable alternatives to describe the large-scale structure of the inflationary universe, leading to a kinematically equivalent Sachs-Wolfe effect. Through the definition of a complete set of spatial eigenfunctions we compute the two-point correlation function of scalar perturbations in these models. In addition, we show how such scenarios would modify the spectrum of the CMB assuming that the observations take place in a small patch of a universe with anisotropic curvature

Cosmological signatures of anisotropic spatial curvature

Energy Technology Data Exchange (ETDEWEB)

Pereira, Thiago S. [Departamento de Física, Universidade Estadual de Londrina, 86057-970, Londrina – PR (Brazil); Marugán, Guillermo A. Mena [Instituto de Estructura de la Materia, IEM-CSIC, Serrano 121, 28006, Madrid (Spain); Carneiro, Saulo, E-mail: tspereira@uel.br, E-mail: mena@iem.cfmac.csic.es, E-mail: saulo.carneiro@pq.cnpq.br [Instituto de Física, Universidade Federal da Bahia, 40210-340, Salvador – BA (Brazil)

2015-07-01

If one is willing to give up the cherished hypothesis of spatial isotropy, many interesting cosmological models can be developed beyond the simple anisotropically expanding scenarios. One interesting possibility is presented by shear-free models in which the anisotropy emerges at the level of the curvature of the homogeneous spatial sections, whereas the expansion is dictated by a single scale factor. We show that such models represent viable alternatives to describe the large-scale structure of the inflationary universe, leading to a kinematically equivalent Sachs-Wolfe effect. Through the definition of a complete set of spatial eigenfunctions we compute the two-point correlation function of scalar perturbations in these models. In addition, we show how such scenarios would modify the spectrum of the CMB assuming that the observations take place in a small patch of a universe with anisotropic curvature.

Views on the Anisotropic Nature of Ilva Valley Region

Directory of Open Access Journals (Sweden)

GABRIELA-ALINA MUREŞAN

2012-01-01

Full Text Available There are two concepts important for the authors of this article: anisotropic region and anisotropic space. Anisotropic region is defined by A. Dauphiné, the geographer (-mathematician, as a territorial unit whose structure results from the organisation of space along one or more axes. From the point of view of a territorial system, this type of region has some characteristics which differentiate it both from the homogeneous region and from the polarised one. These specificities have been analysed for Ilva Valley. The region of Ilva Valley is formed along the morphological axis represented by the Ilva River. The aim is to identify these specificities or their absence within this region. In this way we can determine whether this region is an anisotropic one or just an anisotropic space, namely whether it can be considered as evolving towards an anisotropic region, not yet complying with all characteristics of anisotropic regions.

Spin Wave Theory of Strongly Anisotropic Magnets

DEFF Research Database (Denmark)

Lindgård, Per-Anker

1977-01-01

A strong anisotropy gives rise to a non-spherical precession of the spins with different amplitudes in the x and y directions. The highly anharmonic exchange interaction thereby becomes effectively anisotropic. The possibility of detecting a genuine two-ion anisotropy is discussed, and comments...

Tunneling anisotropic magnetoresistance driven by magnetic phase transition.

Science.gov (United States)

Chen, X Z; Feng, J F; Wang, Z C; Zhang, J; Zhong, X Y; Song, C; Jin, L; Zhang, B; Li, F; Jiang, M; Tan, Y Z; Zhou, X J; Shi, G Y; Zhou, X F; Han, X D; Mao, S C; Chen, Y H; Han, X F; Pan, F

2017-09-06

The independent control of two magnetic electrodes and spin-coherent transport in magnetic tunnel junctions are strictly required for tunneling magnetoresistance, while junctions with only one ferromagnetic electrode exhibit tunneling anisotropic magnetoresistance dependent on the anisotropic density of states with no room temperature performance so far. Here, we report an alternative approach to obtaining tunneling anisotropic magnetoresistance in α'-FeRh-based junctions driven by the magnetic phase transition of α'-FeRh and resultantly large variation of the density of states in the vicinity of MgO tunneling barrier, referred to as phase transition tunneling anisotropic magnetoresistance. The junctions with only one α'-FeRh magnetic electrode show a magnetoresistance ratio up to 20% at room temperature. Both the polarity and magnitude of the phase transition tunneling anisotropic magnetoresistance can be modulated by interfacial engineering at the α'-FeRh/MgO interface. Besides the fundamental significance, our finding might add a different dimension to magnetic random access memory and antiferromagnet spintronics.Tunneling anisotropic magnetoresistance is promising for next generation memory devices but limited by the low efficiency and functioning temperature. Here the authors achieved 20% tunneling anisotropic magnetoresistance at room temperature in magnetic tunnel junctions with one α'-FeRh magnetic electrode.

A Variational Approach to Perturbed Discrete Anisotropic Equations

Directory of Open Access Journals (Sweden)

Amjad Salari

2016-01-01

Full Text Available We continue the study of discrete anisotropic equations and we will provide new multiplicity results of the solutions for a discrete anisotropic equation. We investigate the existence of infinitely many solutions for a perturbed discrete anisotropic boundary value problem. The approach is based on variational methods and critical point theory.

Nonlinear, anisotropic, and giant photoconductivity in intrinsic and doped graphene

Science.gov (United States)

Singh, Ashutosh; Ghosh, Saikat; Agarwal, Amit

2018-01-01

We present a framework to calculate the anisotropic and nonlinear photoconductivity for two band systems with application to graphene. In contrast to the usual perturbative (second order in the optical field strength) techniques, we calculate photoconductivity to all orders in the optical field strength. In particular, for graphene, we find the photoresponse to be giant (at large optical field strengths) and anisotropic. The anisotropic photoresponse in graphene is correlated with polarization of the incident field, with the response being similar to that of a half-wave plate. We predict that the anisotropy in the simultaneous measurement of longitudinal (σx x) and transverse (σy x) photoconductivity, with four probes, offers a unique experimental signature of the photovoltaic response, distinguishing it from the thermal-Seebeck and bolometric effects in photoresponse.

Effect of normal impurities on anisotropic superconductors with variable density of states

Science.gov (United States)

Whitmore, M. D.; Carbotte, J. P.

1982-06-01

We develop a generalized BCS theory of impure superconductors with an anisotropic electron-electron interaction represented by the factorizable model introduced by Markowitz and Kadanoff, and a variable electronic density of states N(ɛ), assumed to peak at the Fermi energy, which is modeled by a Lorentzian superimposed on a uniform background. As the impurity scattering is increased, the enhancement of T c by both the anisotropy and the peak in N(ɛ) is washed out. The reduction is investigated for different values of the anisotropy and different peak heights and widths. It is concluded that the effects of anisotropy and the peak are reduced together in such a way that any effect due to anisotropy is not easily distinguishable from that due to the peak.

Enhanced magnetocaloric properties and critical behavior of (Fe0.72Cr0.28)3Al alloys for near room temperature cooling

Science.gov (United States)

Sharma, V.; Maheshwar Repaka, D. V.; Chaudhary, V.; Ramanujan, R. V.

2017-04-01

Magnetic cooling is an environmentally friendly, energy efficient, thermal management technology relying on high performance magnetocaloric materials (MCM). Current research has focused on low cost, corrosion resistant, rare earth (RE) free MCMs. We report the structural and magnetocaloric properties of novel, low cost, RE free, iron based (Fe0.72Cr0.28)3Al alloys. The arc melted buttons and melt spun ribbons possessed the L21 crystal structure and B2 crystal structure, respectively. A notable enhancement of 33% in isothermal entropy change (-ΔS m) and 25% increase in relative cooling power (RCP) for the ribbons compared to the buttons can be attributed to higher structural disorder in the Fe-Cr and Fe-Al sub-lattices of the B2 structure. The critical behavior was investigated using modified Arrott plots, the Kouvel-Fisher plot and the critical isotherm technique; the critical exponents were found to correspond to the short-range order 3D Heisenberg model. The field and temperature dependent magnetization curves of (Fe0.72Cr0.28)3Al alloys revealed their soft magnetic nature with negligible hysteresis. Thus, these alloys possess promising performance attributes for near room temperature magnetic cooling applications.

Investigation on the structural, magnetic and magnetocaloric properties of nanocrystalline Pr-deficient Pr1-xSrxMnO3-δ manganites

Science.gov (United States)

Arun, B.; Athira, M.; Akshay, V. R.; Sudakshina, B.; Mutta, Geeta R.; Vasundhara, M.

2018-02-01

We have investigated the structural, magnetic and magnetocaloric properties of nanocrystalline Pr-deficient Pr1-xSrxMnO3-δ Perovskite manganites. Rietveld refinement of the X-ray powder diffraction patterns confirms that all the studied compounds have crystallized into an orthorhombic structure with Pbnm space group. Transmission electron microscopy analysis reveals nanocrystalline compounds with crystallite size less than 50 nm. The selected area electron diffraction patterns reveal the highly crystalline nature of the compounds and energy dispersive X-ray spectroscopic analysis shows that the obtained compositions are nearly identical with the nominal one. The oxygen stoichiometry is estimated by iodometric titration method and stoichiometric compositions are confirmed by X-ray Fluorescence Spectrometry analysis. A large bifurcation is observed in the ZFC/FC curves and Arrott plots not show a linear relation but have a convex curvature nature. The temperature dependence of inverse magnetic susceptibility at higher temperature confirms the existence of ferromagnetic clusters. The experimental results reveal that the reduction of crystallite size to nano metric scale in Pr-deficient manganites adversely influences structural, magnetic and magnetocaloric properties as compared to its bulk counterparts reported earlier.

Effects of the partial substitution of Ni by Cr on the transport, magnetic, and magnetocaloric properties of Ni50Mn37In13

Directory of Open Access Journals (Sweden)

Sudip Pandey

2017-05-01

Full Text Available The structural, magnetic, and magnetotransport properties of Ni50-xCrxMn37In13 Heusler alloys have been synthesized and investigated by x-ray diffraction (XRD, field and pressure dependent magnetization, and electrical resistivity measurements. The partial substitution of Ni by Cr in Ni50Mn37In13 significantly improves the magnetocaloric effect in the vicinity of the martensitic transition (TM. This system also shows a large negative entropy change at the Curie temperature (TC, making it a candidate material for application in a refrigeration cycle that exploits both positive and negative magnetic entropy changes. The refrigeration capacity (RC values at TM and TC increase significantly by more than 20 % with Cr substitution. The application of hydrostatic pressure increases the temperature stability of the martensitic phase in Ni45Cr5Mn37In13. The influence of Cr substitution on the transport properties of Ni48Cr2Mn37In13 is discussed. An asymmetric magnetoresistance, i.e., a spin-valve-like behavior, has been observed near TM for Ni48Cr2Mn37In13.

Fabrication of an Anisotropic Superhydrophobic Polymer Surface Using Compression Molding and Dip Coating

Directory of Open Access Journals (Sweden)

Kyong-Min Lee

2017-11-01

Full Text Available Many studies of anisotropic wetting surfaces with directional structures inspired from rice leaves, bamboo leaves, and butterfly wings have been carried out because of their unique liquid shape control and transportation. In this study, a precision mechanical cutting process, ultra-precision machining using a single crystal diamond tool, was used to fabricate a mold with microscale directional patterns of triangular cross-sectional shape for good moldability, and the patterns were duplicated on a flat thermoplastic polymer plate by compression molding for the mass production of an anisotropic wetting polymer surface. Anisotropic wetting was observed only with microscale patterns, but the sliding of water could not be achieved because of the pinning effect of the micro-structure. Therefore, an additional dip coating process with 1H, 1H, 2H, 2H-perfluorodecythricholosilanes, and TiO2 nanoparticles was applied for a small sliding angle with nanoscale patterns and a low surface energy. The anisotropic superhydrophobic surface was fabricated and the surface morphology and anisotropic wetting behaviors were investigated. The suggested fabrication method can be used to mass produce an anisotropic superhydrophobic polymer surface, demonstrating the feasibility of liquid shape control and transportation.

Waveguide effect under 'antiguiding' conditions in graded anisotropic media

Energy Technology Data Exchange (ETDEWEB)

Kozlov, A V; Mozhaev, V G; Zyryanova, A V, E-mail: av_kozlov@inbox.r, E-mail: vgmozhaev@mail.r, E-mail: annazyr@mail.r [Faculty of Physics, Moscow State University, Moscow, 119991 GSP-1 (Russian Federation)

2010-02-24

A new wave confinement effect is predicted in graded crystals with a concave slowness surface under conditions of growth of the phase velocity with decreasing distance from the waveguide axis. This finding overturns the common notion about the guiding and 'antiguiding' profiles of wave velocity in inhomogeneous media. The waveguide effect found is elucidated by means of ray analysis and particular exact wave solutions. The exact solution obtained for localized flexural waves in thin plates of graded cubic and tetragonal crystals confirms the predicted effect. Since this solution is substantially different with respect to the existence conditions from all others yet reported, and it cannot be deduced from the previously known results, the predicted waves can be classified as a new type of waveguide mode in graded anisotropic media. Although the concrete calculations are given in the article for acoustic waves, its general predictions are expected to be valid for waves of various natures, including spin, plasma, and optical waves.

Structural, magnetic and magnetocaloric properties of AMn{sub 1-x}Ga{sub x}O{sub 3} compounds with 0{<=}x{<=}0.2

Energy Technology Data Exchange (ETDEWEB)

Omri, A., E-mail: omriaref@yahoo.fr [Laboratoire de Physique Appliquee, Faculte des Sciences de Sfax, Universite de Sfax, BP 1171, Sfax 3000 (Tunisia); Bejar, M. [Laboratoire de Physique Appliquee, Faculte des Sciences de Sfax, Universite de Sfax, BP 1171, Sfax 3000 (Tunisia); Sajieddine, M. [Laboratoire de Physique et Mecanique des Materiaux, Faculte des Sciences et Techniques, BP 523, 23000, Beni-Mellal-Universite Sultan Moulay Sliman, Maroc (Morocco); Dhahri, E. [Laboratoire de Physique Appliquee, Faculte des Sciences de Sfax, Universite de Sfax, BP 1171, Sfax 3000 (Tunisia); Hlil, E.K. [Institut Neel, CNRS-Universite J. Fourier, BP 166, 38042 Grenoble (France); Es-Souni, M. [University of Applied Sciences, Institute for Materials and Surface Technology, Grenzstrasse 3, Kiel (Germany)

2012-07-01

Structural, magnetic and magnetocaloric properties of manganites series with the AMn{sub 1-x}Ga{sub x}O{sub 3} (A=La{sub 0.75}Ca{sub 0.08}Sr{sub 0.17} and x=0, 0.05, 0.1 and 0.2) composition have been investigated to shed light on Ga-doping influence. Solid-state reaction method was used for preparation. From XRD study, all samples are found single phase and crystallize in the orthorhombic structure with the Pnma space group. The variation of the magnetization M vs. temperature T, under an applied magnetic field of 0.05 T, reveals a ferromagnetic-paramagnetic transition for all samples. The experimental results indicate that T{sub C} decreases from 336 to 135 K with increasing Ga substitution. Magnetocaloric effect (MCE) was estimated, in terms of isothermal magnetic entropy change (-{Delta}S{sub M}), using the M(T, {mu}{sub 0}H) data and employing the thermodynamic Maxwell equation. The maximum entropy change and Relative Cooling Power (RCP) show non-monotonic behaviors with increasing the concentration of Gallium. In fact, the maximum value of {Delta}S{sub Mmax}of AMn{sub 1-x}Ga{sub x}O{sub 3} for x=0.00 and 0.2 samples is found to be, respectively, 2.87 and 1.17 J/kg/K under an applied magnetic field change of 2 T. For the same applied magnetic field ({mu}{sub 0}H=2 T), the RCP values are found to vary between 97.58 and 89 J/kg.

Magnetic, structural and magnetocaloric properties of Ni-Si and Ni-Al thermoseeds for self-controlled hyperthermia.

Science.gov (United States)

Pandey, Sudip; Quetz, Abdiel; Aryal, Anil; Dubenko, Igor; Mazumdar, Dipanjan; Stadler, Shane; Ali, Naushad

2017-11-01

Self-controlled hyperthermia is a non-invasive technique used to kill or destroy cancer cells while preserving normal surrounding tissues. We have explored bulk magnetic Ni-Si and Ni-Al alloys as a potential thermoseeds. The structural, magnetic and magnetocaloric properties of the samples were investigated, including saturation magnetisation, Curie temperature (T C ), and magnetic and thermal hysteresis, using room temperature X-ray diffraction and magnetometry. The annealing time, temperature and the effects of homogenising the thermoseeds were studied to determine the functional hyperthermia applications. The bulk Ni-Si and Ni-Al binary alloys have Curie temperatures in the desired range, 316 K-319 K (43 °C-46 °C), which is suitable for magnetic hyperthermia applications. We have found that T C strictly follows a linear trend with doping concentration over a wide range of temperature. The magnetic ordering temperature and the magnetic properties can be controlled through substitution in these binary alloys.

DNA-nanoparticle superlattices formed from anisotropic building blocks

Science.gov (United States)

Jones, Matthew R.; Macfarlane, Robert J.; Lee, Byeongdu; Zhang, Jian; Young, Kaylie L.; Senesi, Andrew J.; Mirkin, Chad A.

2010-11-01

Directional bonding interactions in solid-state atomic lattices dictate the unique symmetries of atomic crystals, resulting in a diverse and complex assortment of three-dimensional structures that exhibit a wide variety of material properties. Methods to create analogous nanoparticle superlattices are beginning to be realized, but the concept of anisotropy is still largely underdeveloped in most particle assembly schemes. Some examples provide interesting methods to take advantage of anisotropic effects, but most are able to make only small clusters or lattices that are limited in crystallinity and especially in lattice parameter programmability. Anisotropic nanoparticles can be used to impart directional bonding interactions on the nanoscale, both through face-selective functionalization of the particle with recognition elements to introduce the concept of valency, and through anisotropic interactions resulting from particle shape. In this work, we examine the concept of inherent shape-directed crystallization in the context of DNA-mediated nanoparticle assembly. Importantly, we show how the anisotropy of these particles can be used to synthesize one-, two- and three-dimensional structures that cannot be made through the assembly of spherical particles.

Reversible and irreversible magnetocaloric effect in the NdBa{sub 2}Cu{sub 3}O{sub 7} superconductor in relation to specific heat and magnetization

Energy Technology Data Exchange (ETDEWEB)

Plackowski, T [Departement de Physique de la Matiere Condensee, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Institute of Low Temperature and Structure Research, ulica Okolna 2, 50-422 Wroclaw (Poland); Wang, Y [Departement de Physique de la Matiere Condensee, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Lortz, R [Departement de Physique de la Matiere Condensee, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Junod, A [Departement de Physique de la Matiere Condensee, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Wolf, Th [Forschungszentrum Karlsruhe, Institut fuer Technische Physik, Postfach 3640, D-76021Karlsruhe (Germany)

2005-11-02

A recently developed technique for measuring the isothermal magnetocaloric coefficient (M{sub T}) is applied to the study of a superconducting NdBa{sub 2}Cu{sub 3}O{sub 7} single crystal. Results are compared with magnetization (M) and specific heat (C). In the reversible region both C and M{sub T} follow the scaling law of the 3D-xy universality class. The anomalies connected with flux-line lattice melting are visible on M{sub T}(B) curves as peaks and steps, similar to C(T) curves yet with much smaller background. At lower temperature, in the irreversible region the M{sub T}(B) behaviour resembles more that of M(B), exhibiting the 'fishtail' effect. Our results confirm that the peculiarities of the phase diagram known from the high-temperature superconductor YBa{sub 2}Cu{sub 3}O{sub 7}, e.g. vortex melting, dominance of critical fluctuations and absence of a B{sub c2} critical field line, are a common property of RE-123 systems.

Instabilities of collisionless current sheets revisited: The role of anisotropic heating

International Nuclear Information System (INIS)

Muñoz, P. A.; Kilian, P.; Büchner, J.

2014-01-01

In this work, we investigate the influence of the anisotropic heating on the spontaneous instability and evolution of thin Harris-type collisionless current sheets, embedded in antiparallel magnetic fields. In particular, we explore the influence of the macroparticle shape-function using a 2D version of the PIC code ACRONYM. We also investigate the role of the numerical collisionality due to the finite number of macroparticles in PIC codes. It is shown that it is appropriate to choose higher order shape functions of the macroparticles compared to a larger number of macroparticles per cell. This allows to estimate better the anisotropic electron heating due to the collisions of macroparticles in a PIC code. Temperature anisotropies can stabilize the tearing mode instability and trigger additional current sheet instabilities. We found a good agreement between the analytically derived threshold for the stabilization of the anisotropic tearing mode and other instabilities, either spontaneously developing or initially triggered ones. Numerical effects causing anisotropic heating at electron time scales become especially important for higher mass ratios (above m i /m e =180). If numerical effects are carefully taken into account, one can recover the theoretical estimated linear growth rates of the tearing instability of thin isotropic collisionless current sheets, also for higher mass ratios

An anisotropic elastoplasticity model implemented in FLAG

Energy Technology Data Exchange (ETDEWEB)

Buechler, Miles Allen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Canfield, Thomas R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-10-12

Many metals, including Tantalum and Zirconium, exhibit anisotropic elastoplastic behavior at the single crystal level, and if components are manufactured from these metals through forming processes the polycrystal (component) may also exhibit anisotropic elastoplastic behavior. This is because the forming can induce a preferential orientation of the crystals in the polycrystal. One example is a rolled plate of Uranium where the sti /strong orientation of the crystal (c-axis) tends to align itself perpendicular to the rolling direction. If loads are applied to this plate in di erent orientations the sti ness as well as the ow strength of the material will be greater in the through thickness direction than in other directions. To better accommodate simulations of such materials, an anisotropic elastoplasticity model has been implemented in FLAG. The model includes an anisotropic elastic stress model as well as an anisotropic plasticity model. The model could represent single crystals of any symmetry, though it should not be confused with a high- delity crystal plasticity model with multiple slip planes and evolutions. The model is most appropriate for homogenized polycrystalline materials. Elastic rotation of the material due to deformation is captured, so the anisotropic models are appropriate for arbitrary large rotations, but currently they do not account for signi cant change in material texture beyond the elastic rotation of the entire polycrystal.

Ultrasonic Beam Propagation in Highly Anisotropic Materials Simulated by Multi-Gaussian Beams

International Nuclear Information System (INIS)

Jeong, Hyun Jo; Schmerr, Lester W.

2007-01-01

The necessity of nondestructively inspecting fiber-reinforced composites, austenitic steels, and other inherently anisotropic materials has stimulated considerable interest in developing beam models for anisotropic media. The properties of slowness surface play key role in the beam models based on the paraxial approximation. In this paper, we apply a modular multi-Gaussian beam (MMGB) model to study the effects of material anisotropy on ultrasonic beam profile. It is shown that the anisotropic effects of beam skew and excess beam divergence enter into the MMGB model through parameters defining the slope and curvature of the slowness surface. The overall beam profile is found when the quasi longitudinal (qL) beam propagates in the symmetry plane of a transversely isotropic gr/ep composite. Simulation results are presented to illustrate the effects of these parameters on ultrasonic beam diffraction and beam skew. The MMGB calculations are also checked by comparing the anisotropy factor and beam skew angle with other analytical solutions

Determination of effective dose in anisotropic gamma radiation fields: application of dosimeters calibrated in terms of Hp(10)

International Nuclear Information System (INIS)

Chumak, V. V.; Bakhanova, E. V.

2003-01-01

In this presentation authors deals with determination of effective dose in anisotropic gamma radiation fields. It was conclude that: - Straightforward application of Hp(10) as surrogate for E may not work under certain conditions; - Partial data on behavior of E and Hp(10) for different dosimeters allow to estimate E/Hp(10) conversion coefficients for any particular composite source; - In practical situations, anisotropy of workplace fields may be measured by six- collimator device assessing contribution to a dose from six orthogonal directions; - Reasonably conservative conversion coefficients may be assessed for given energy spectrum and degree of anisotropy of workplace fields; - For strongly anisotropic fields multiple dosimetry approach gives the best estimate of E comparing to plain Hp(10) readouts or integral conversion coefficients

Thermodynamics of the Heat-Flux Avalanches at the First-Order Magnetic Transition in Magnetocaloric Materials

Science.gov (United States)

Piazzi, Marco; Bennati, Cecilia; Basso, Vittorio

2017-10-01

We investigate the kinetics of first-order magnetic phase transitions by measuring and modeling the heat-flux avalanches corresponding to the irreversible motion of the phase-boundary interface separating the coexisting low- and high-temperature stable magnetic phases. By means of out-of-equilibrium thermodynamics, we encompass the damping mechanisms of the boundary motion in a phenomenological parameter αs. By analyzing the time behavior of the heat-flux signals measured on La (Fe -Mn -Si )13-H magnetocaloric compounds through Peltier calorimetry temperature scans performed at low rates, we relate the linear rise of the individual avalanches to the intrinsic-damping parameter αs.

Theoretical and numerical study of highly anisotropic turbulent flows

NARCIS (Netherlands)

Biferale, L.; Daumont, I.; Lanotte, A.; Toschi, F.

2004-01-01

We present a detailed numerical study of anisotropic statistical fluctuations in stationary, homogeneous turbulent flows. We address both problems of intermittency in anisotropic sectors, and the relative importance of isotropic and anisotropic fluctuations at different scales on a direct numerical

Numerical simulation of anisotropic polymeric foams

Directory of Open Access Journals (Sweden)

Volnei Tita

Full Text Available This paper shows in detail the modelling of anisotropic polymeric foam under compression and tension loadings, including discussions on isotropic material models and the entire procedure to calibrate the parameters involved. First, specimens of poly(vinyl chloride (PVC foam were investigated through experimental analyses in order to understand the mechanical behavior of this anisotropic material. Then, isotropic material models available in the commercial software AbaqusTM were investigated in order to verify their ability to model anisotropic foams and how the parameters involved can influence the results. Due to anisotropy, it is possible to obtain different values for the same parameter in the calibration process. The obtained set of parameters are used to calibrate the model according to the application of the structure. The models investigated showed minor and major limitations to simulate the mechanical behavior of anisotropic PVC foams under compression, tension and multi-axial loadings. Results show that the calibration process and the choice of the material model applied to the polymeric foam can provide good quantitative results and save project time. Results also indicate what kind and order of error one will get if certain choices are made throughout the modelling process. Finally, even though the developed calibration procedure is applied to specific PVC foam, it still outlines a very broad drill to analyze other anisotropic cellular materials.

Anisotropic wave-equation traveltime and waveform inversion

KAUST Repository

Feng, Shihang; Schuster, Gerard T.

2016-01-01

The wave-equation traveltime and waveform inversion (WTW) methodology is developed to invert for anisotropic parameters in a vertical transverse isotropic (VTI) meidum. The simultaneous inversion of anisotropic parameters v0, ε and δ is initially

Understanding the anisotropic strain effects on lithium diffusion in graphite anodes: A first-principles study

Science.gov (United States)

Ji, Xiang; Wang, Yang; Zhang, Junqian

2018-06-01

The lithium diffusion in graphite anode, which is the most widely used commercial electrode material today, affects the charge/discharge performance of lithium-ion batteries. In this study, the anisotropic strain effects on lithium diffusion in graphite anodes are systematically investigated using first-principles calculations based on density functional theory (DFT) with van der Waals corrections. It is found that the effects of external applied strains along various directions of LixC6 (i.e., perpendicular or parallel to the basal planes of the graphite host) on lithium diffusivity are different. Along the direction perpendicular to the graphite planes, the tensile strain facilitates in-plane Li diffusion by reducing the energy barrier, and the compressive strain hinders in-plane Li diffusion by raising the energy barrier. In contrast, the in-plane biaxial tensile strain (parallel to the graphite planes) hinders in-plane Li diffusion, and the in-plane biaxial compressive strain facilitates in-plane Li diffusion. Furthermore, both in-plane and transverse shear strains slightly influence Li diffusion in graphite anodes. A discussion is presented to explain the anisotropic strain dependence of lithium diffusion. This research provides data for the continuum modelling of the electrodes in the lithium-ion batteries.

Behavior of the magnetocaloric effect in La0.7Ba0.2Ca0.1Mn1-xSnxO3 manganite oxides as promising candidates for magnetic refrigeration

Science.gov (United States)

Dhahri, Ja.; Mnefgui, Safa; Ben Hassine, A.; Tahri, Ta.; Oumezzine, M.; Hlil, E. K.

2018-05-01

The magnetocaloric effect along with magnetic phase transition in the peroveskite polycrystalline samples La0.7Ba0.2Ca0.1Mn1-xSnxO3 (x = 0 and 0.1) was investigated. The samples were synthesized using conventional solid state reaction at 1400 °C temperature. Magnetization vs. temperature measurements, under a magnetic field of μ0H = 0.05 T, showed a paramagnetic-ferromagnetic transition at Curie temperature, TC, which decreases from 310 K for x = 0-290 K for x = 0.1. A large magnetic entropy change | ΔSM | deduced from isothermal magnetization curves, has been observed in our samples with a peak centered on their respective TC. Interesting values of the relative cooling power (RCP), 237 J kg-1 for x = 0 and 248 J kg-1 x = 0.1, make these samples promising candidates for magnetic refrigeration around room temperature.

A continuum anisotropic damage model with unilateral effect

Directory of Open Access Journals (Sweden)

A. Alliche

2016-02-01

Full Text Available A continuum damage mechanics model has been derived within the framework of irreversible thermodynamics with internal variables in order to describe the behaviour of quasi-brittle materials under various loading paths. The anisotropic character induced by the progressive material degradation is explicitly taken into account, and the Helmholtz free energy is a scalar function of the basic invariants of the second order strain and damage tensors. The elastic response varies depending on the closed or open configuration of defects. The constitutive laws derived within the framework of irreversible thermodynamics theory display a dissymmetry as well as unilateral effects under tensile and compressive loading conditions. This approach verifies continuity and uniqueness of the potential energy. An application to uniaxial tension-compression loading shows a good adequacy with experimental results when available, and realistic evolutions for computed stresses and strains otherwise.

Effect of normal impurities on anisotropic superconductors with variable density of states

International Nuclear Information System (INIS)

Whitmore, M.D.; Carbotte, J.P.

1982-01-01

We develop a generalized BCS theory of impure superconductors with an anisotropic electron--electron interaction represented by the factorizable model introduced by Markowitz and Kadanoff, and a variable electronic density of states N(epsilon-c), assumed to peak at the Fermi energy, which is modeled by a Lorentzian superimposed on a uniform background. As the impurity scattering is increased, the enhancement of T/sub c/ by both the anisotropy and the peak in N(epsilon-c) is washed out. The reduction is investigated for different values of the anisotropy and different peak heights and widths. It is concluded that the effects of anisotropy and the peak are reduced together in such a way that any effect due to anisotropy is not easily distinguishable from that due to the peak

Obtuse triangle suppression in anisotropic meshes

KAUST Repository

Sun, Feng; Choi, Yi King; Wang, Wen Ping; Yan, Dongming; Liu, Yang; Lé vy, Bruno L.

2011-01-01

Anisotropic triangle meshes are used for efficient approximation of surfaces and flow data in finite element analysis, and in these applications it is desirable to have as few obtuse triangles as possible to reduce the discretization error. We present a variational approach to suppressing obtuse triangles in anisotropic meshes. Specifically, we introduce a hexagonal Minkowski metric, which is sensitive to triangle orientation, to give a new formulation of the centroidal Voronoi tessellation (CVT) method. Furthermore, we prove several relevant properties of the CVT method with the newly introduced metric. Experiments show that our algorithm produces anisotropic meshes with much fewer obtuse triangles than using existing methods while maintaining mesh anisotropy. © 2011 Elsevier B.V. All rights reserved.

Obtuse triangle suppression in anisotropic meshes

KAUST Repository

Sun, Feng

2011-12-01

Anisotropic triangle meshes are used for efficient approximation of surfaces and flow data in finite element analysis, and in these applications it is desirable to have as few obtuse triangles as possible to reduce the discretization error. We present a variational approach to suppressing obtuse triangles in anisotropic meshes. Specifically, we introduce a hexagonal Minkowski metric, which is sensitive to triangle orientation, to give a new formulation of the centroidal Voronoi tessellation (CVT) method. Furthermore, we prove several relevant properties of the CVT method with the newly introduced metric. Experiments show that our algorithm produces anisotropic meshes with much fewer obtuse triangles than using existing methods while maintaining mesh anisotropy. © 2011 Elsevier B.V. All rights reserved.

Integrated Sachs-Wolfe effect in a quintessence cosmological model: Including anisotropic stress of dark energy

International Nuclear Information System (INIS)

Wang, Y. T.; Xu, L. X.; Gui, Y. X.

2010-01-01

In this paper, we investigate the integrated Sachs-Wolfe effect in the quintessence cold dark matter model with constant equation of state and constant speed of sound in dark energy rest frame, including dark energy perturbation and its anisotropic stress. Comparing with the ΛCDM model, we find that the integrated Sachs-Wolfe (ISW)-power spectrums are affected by different background evolutions and dark energy perturbation. As we change the speed of sound from 1 to 0 in the quintessence cold dark matter model with given state parameters, it is found that the inclusion of dark energy anisotropic stress makes the variation of magnitude of the ISW source uncertain due to the anticorrelation between the speed of sound and the ratio of dark energy density perturbation contrast to dark matter density perturbation contrast in the ISW-source term. Thus, the magnitude of the ISW-source term is governed by the competition between the alterant multiple of (1+3/2xc-circumflex s 2 ) and that of δ de /δ m with the variation of c-circumflex s 2 .

Bringing Solid-State Magnetocaloric Cooling to the Market: A Commercialization Plan

Energy Technology Data Exchange (ETDEWEB)

Abu-Heiba, Ahmad [ORNL; Sikes, Karen [CSRA; Blackburn, Julia [CSRA; Abdelaziz, Omar [ORNL; Mehdizadeh Momen, Ayyoub [ORNL

2017-12-01

Air conditioning has become a staple in American life, bringing improved health, productivity, and comfort to 93% of single-family homes as of 2015, compared to only 76% in 1990. This rise in demand has contributed to the 2.51 quads (12.5%) of total annual energy consumption in residential buildings attributable to space cooling (U.S. Energy Information Administration 2017). Accompanying this upward trend in space cooling has been increased refrigerant use, which has historically contributed to ozone depletion, global warming, or both. The Oak Ridge National Laboratory – along with German-based partner Vacuumschmelze GmbH & Co. KG – is working to reduce energy consumption and refrigerant use through the development of a next-generation, solid-state magnetocaloric cooling system. The purpose of this study is to investigate market potential of these systems in the United States, including information on the industry landscape, market share and unit shipment projections, optimal price points, and barriers to market entry.

The traces of anisotropic dark energy in light of Planck

Energy Technology Data Exchange (ETDEWEB)

Cardona, Wilmar; Kunz, Martin [Département de Physique Théorique and Center for Astroparticle Physics, Université de Genève, 24 Quai Ernest Ansermet, 1211 Genève 4 (Switzerland); Hollenstein, Lukas, E-mail: wilmar.cardona@unige.ch, E-mail: lukas.hollenstein@zhaw.ch, E-mail: martin.kunz@unige.ch [IAS Institute of Applied Simulation, ZHAW Zurich University of Applied Sciences, Grüental, PO Box, 8820 Wädenswil (Switzerland)

2014-07-01

We study a dark energy model with non-zero anisotropic stress, either linked to the dark energy density or to the dark matter density. We compute approximate solutions that allow to characterise the behaviour of the dark energy model and to assess the stability of the perturbations. We also determine the current limits on such an anisotropic stress from the cosmic microwave background data by the Planck satellite, and derive the corresponding constraints on the modified growth parameters like the growth index, the effective Newton's constant and the gravitational slip.

Anisotropic turbulence and zonal jets in rotating flows with a β-effect

Directory of Open Access Journals (Sweden)

B. Galperin

2006-01-01

Full Text Available Numerical studies of small-scale forced, two-dimensional turbulent flows on the surface of a rotating sphere have revealed strong large-scale anisotropization that culminates in the emergence of quasi-steady sets of alternating zonal jets, or zonation. The kinetic energy spectrum of such flows also becomes strongly anisotropic. For the zonal modes, a steep spectral distribution, E(n=CZ (Ω/R2 n-5, is established, where CZ=O(1 is a non-dimensional coefficient, Ω is the angular velocity, and R is the radius of the sphere, respectively. For other, non-zonal modes, the classical, Kolmogorov-Batchelor-Kraichnan, spectral law is preserved. This flow regime, referred to as a zonostrophic regime, appears to have wide applicability to large-scale planetary and terrestrial circulations as long as those are characterized by strong rotation, vertically stable stratification and small Burger numbers. The well-known manifestations of this regime are the banded disks of the outer planets of our Solar System. Relatively less known examples are systems of narrow, subsurface, alternating zonal jets throughout all major oceans discovered in state-of-the-art, eddy-permitting simulations of the general oceanic circulation. Furthermore, laboratory experiments recently conducted using the Coriolis turntable have basically confirmed that the lateral gradient of ''planetary vorticity'' (emulated via the topographic β-effect is the primary cause of the zonation and that the latter is entwined with the development of the strongly anisotropic kinetic energy spectrum that tends to attain the same zonal and non-zonal distributions, −5 and , respectively, in both the slope and the magnitude, as the corresponding spectra in other environmental conditions. The non-dimensional coefficient CZ in the −5 spectral law appears to be invariant, , in a variety of simulated and natural flows. This paper provides a brief review of the zonostrophic regime. The review includes the

Tuning the magnetocaloric properties of La0.7Ca0.3MnO3 manganites through Ni-doping

Science.gov (United States)

Gómez, A.; Chavarriaga, E.; Supelano, I.; Parra, C. A.; Morán, O.

2018-04-01

The effect of Ni2+ doping on the magnetic and magnetocaloric properties of La0.7Ca0.3MnO3 manganites synthesized via the auto-combustion method is reported. The aim of studying Ni2+-substituted La0.7Ca0.3Mn1 - xNixO3 (x = 0 , 0.02 , 0.07, and 0.1) manganites was to explore the possibility of increasing the operating temperature range for the magnetocaloric effect through tuning of the magnetic transition temperature. X-ray diffraction analysis confirmed the phase purity of the synthesized samples. The substitution of Mn3+ ions by Ni2+ ions in the La0.7Ca0.3MnO3 lattice was also corroborated through this technique. The dependence of the magnetization on the temperature reveals that all the compositions exhibit a well-defined ferromagnetic to paramagnetic transition near the Curie temperature. A systematic decrease in the values of the Curie temperature is clearly observed upon Ni2+ doping. Probably the replacement of Mn3+ by Ni2+ ions in the La0.7Ca0.3MnO3 lattice weakens the Mn3+-O-Mn4+ double exchange interaction, which leads to a decrease in the transition temperature and the magnetic moment in the samples. By using Arrott plots, it was found that the phase transition from ferromagnetic to paramagnetic is second order. The maximum magnetic entropy changes observed for the x = 0 , 0.02 , 0.07, and 0.1 composites was 0.85, 0.77, 0.63, and 0.59 J/kg K, respectively, under a magnetic field of 1.5 T. In general, it was verified that the magnetic entropy change achieved for La0.7Ca0.3Mn1 - xNixO3 manganites synthesized via the auto-combustion method is higher than those reported for other manganites with comparable Ni2+-doping levels synthesized via standard solid state reaction. The addition of Ni2+ increases the value of the relative cooling power as compared to that of the parent compound. The highest value of this parameter (∼60 J/kg) is found for a Ni-doping level of 2% around 230 K in a field of 1.5 T.

Anisotropic semivortices in dipolar spinor condensates controlled by Zeeman splitting

Science.gov (United States)

Liao, Bingjin; Li, Shoubo; Huang, Chunqing; Luo, Zhihuan; Pang, Wei; Tan, Haishu; Malomed, Boris A.; Li, Yongyao

2017-10-01

Spatially anisotropic solitary vortices, i.e., bright anisotropic vortex solitons (AVSs), supported by anisotropic dipole-dipole interactions, were recently predicted in spin-orbit-coupled binary Bose-Einstein condensates (BECs), in the form of two-dimensional semivortices (complexes built of zero-vorticity and vortical components). We demonstrate that the shape of the AVSs—horizontal or vertical, with respect to the in-plane polarization of the atomic dipole moments in the underlying BEC—may be effectively controlled by the strength Ω of the Zeeman splitting (ZS). A transition from the horizontal to vertical shape with the increase of Ω is found numerically and explained analytically. At the transition point, the AVS assumes the shape of an elliptical ring. The mobility of horizontal AVSs is studied, too, with the conclusion that, with the increase of Ω , their negative effective mass changes the sign to positive via a point at which the effective mass diverges. Lastly, we report a new species of inverted AVSs, with the zero-vorticity and vortex component placed in lower- and higher-energy components, as defined by the ZS. They are excited states, with respect to the ground states provided by the usual AVSs. Quite surprisingly, inverted AVSs are stable in a large parameter region.

An optimization-based framework for anisotropic simplex mesh adaptation

Science.gov (United States)

Yano, Masayuki; Darmofal, David L.

2012-09-01

We present a general framework for anisotropic h-adaptation of simplex meshes. Given a discretization and any element-wise, localizable error estimate, our adaptive method iterates toward a mesh that minimizes error for a given degrees of freedom. Utilizing mesh-metric duality, we consider a continuous optimization problem of the Riemannian metric tensor field that provides an anisotropic description of element sizes. First, our method performs a series of local solves to survey the behavior of the local error function. This information is then synthesized using an affine-invariant tensor manipulation framework to reconstruct an approximate gradient of the error function with respect to the metric tensor field. Finally, we perform gradient descent in the metric space to drive the mesh toward optimality. The method is first demonstrated to produce optimal anisotropic meshes minimizing the L2 projection error for a pair of canonical problems containing a singularity and a singular perturbation. The effectiveness of the framework is then demonstrated in the context of output-based adaptation for the advection-diffusion equation using a high-order discontinuous Galerkin discretization and the dual-weighted residual (DWR) error estimate. The method presented provides a unified framework for optimizing both the element size and anisotropy distribution using an a posteriori error estimate and enables efficient adaptation of anisotropic simplex meshes for high-order discretizations.

Magnetostatics of anisotropic superconducting ellipsoid

International Nuclear Information System (INIS)

Saif, A.G.

1987-09-01

The magnetization and the magnetic field distribution inside (outside) an anisotropic type II superconducting ellipsoid, with filamentary structure, is formulated. We have shown that the magnetic field in this case is different from that of the general anisotropic one. The nucleations of the flux lines for specimens with large demagnetization factors are theoretically studied. We have shown that the nucleations of the flux lines, for specimens with large demagnetization factor, appears at a field larger than that of ellipsoidal shape. (author). 15 refs

Anisotropic silk fibroin/gelatin scaffolds from unidirectional freezing

Energy Technology Data Exchange (ETDEWEB)

Asuncion, Maria Christine Tankeh, E-mail: christine.asuncion@u.nus.edu [National University of Singapore, Department of Biomedical Engineering (Singapore); Goh, James Cho-Hong [National University of Singapore, Department of Biomedical Engineering (Singapore); National University of Singapore, Department of Orthopedic Surgery (Singapore); Toh, Siew-Lok [National University of Singapore, Department of Biomedical Engineering (Singapore); National University of Singapore, Department of Mechanical Engineering (Singapore)

2016-10-01

Recent studies have underlined the importance of matching scaffold properties to the biological milieu. Tissue, and thus scaffold, anisotropy is one such property that is important yet sometimes overlooked. Methods that have been used to achieve anisotropic scaffolds present challenges such as complicated fabrication steps, harsh processing conditions and toxic chemicals involved. In this study, unidirectional freezing was employed to fabricate anisotropic silk fibroin/gelatin scaffolds in a simple and mild manner. Morphological, mechanical, chemical and cellular compatibility properties were investigated, as well as the effect of the addition of gelatin to certain properties of the scaffold. It was shown that scaffold properties were suitable for cell proliferation and that mesenchymal stem cells were able to align themselves along the directed fibers. The fabricated scaffolds present a platform that can be used for anisotropic tissue engineering applications such as cardiac patches. - Highlights: • Silk/gelatin scaffolds with unidirectional alignment were fabricated using a simple and scalable process • Presence of gelatin in silk resulted to lesser shrinkage, better water retention and improved cell proliferation. • Mesenchymal stem cells were shown to align themselves according to the fiber alignment.

Anisotropic colloids: bulk phase behavior and equilibrium sedimentation

NARCIS (Netherlands)

Marechal, M.A.T.

2009-01-01

This thesis focuses on the phase behavior of anisotropically shaped (i.e. non-spherical) colloids using computer simulations. Only hard-core interactions between the colloids are taken into account to investigate the effects of shape alone. The bulk phase behavior of three different shapes of

Anisotropic pressure and hyperons in neutron stars

International Nuclear Information System (INIS)

Sulaksono, A.

2015-01-01

We study the effects of anisotropic pressure (AI-P) on properties of the neutron stars (NSs) with hyperons inside its core within the framework of extended relativistic mean field. It is found that the main effects of AI-P on NS matter is to increase the stiffness of the equation of state EOS, which compensates for the softening of the EOS due to the hyperons. The maximum mass and redshift predictions of anisotropic neutron star with hyperonic core are quite compatible with the result of recent observational constraints if we use the parameter of AI-P model h ≤ 0.8 [L. Herrera and W. Barreto, Phys. Rev. D 88 (2013) 084022.] and Λ ≤ -1.15 [D. D. Doneva and S. S. Yazadjiev, Phys. Rev. D 85 (2012) 124023.]. The radius of the corresponding NS at M = 1.4 M ⊙ is more than 13 km, while the effect of AI-P on the minimum mass of NS is insignificant. Furthermore, due to the AI-P in the NS, the maximum mass limit of higher than 2.1 M ⊙ cannot rule out the presence of hyperons in the NS core. (author)

Ballistic Anisotropic Magnetoresistance of Single-Atom Contacts.

Science.gov (United States)

Schöneberg, J; Otte, F; Néel, N; Weismann, A; Mokrousov, Y; Kröger, J; Berndt, R; Heinze, S

2016-02-10

Anisotropic magnetoresistance, that is, the sensitivity of the electrical resistance of magnetic materials on the magnetization direction, is expected to be strongly enhanced in ballistic transport through nanoscale junctions. However, unambiguous experimental evidence of this effect is difficult to achieve. We utilize single-atom junctions to measure this ballistic anisotropic magnetoresistance (AMR). Single Co and Ir atoms are deposited on domains and domain walls of ferromagnetic Fe layers on W(110) to control their magnetization directions. They are contacted with nonmagnetic tips in a low-temperature scanning tunneling microscope to measure the junction conductances. Large changes of the magnetoresistance occur from the tunneling to the ballistic regime due to the competition of localized and delocalized d-orbitals, which are differently affected by spin-orbit coupling. This work shows that engineering the AMR at the single atom level is feasible.

Enhanced magnetocaloric properties and critical behavior of (Fe0.72Cr0.28)3Al alloys for near room temperature cooling

International Nuclear Information System (INIS)

Sharma, V; Maheshwar Repaka, D V; Chaudhary, V; Ramanujan, R V

2017-01-01

Magnetic cooling is an environmentally friendly, energy efficient, thermal management technology relying on high performance magnetocaloric materials (MCM). Current research has focused on low cost, corrosion resistant, rare earth (RE) free MCMs. We report the structural and magnetocaloric properties of novel, low cost, RE free, iron based (Fe 0.72 Cr 0.28 ) 3 Al alloys. The arc melted buttons and melt spun ribbons possessed the L2 1 crystal structure and B2 crystal structure, respectively. A notable enhancement of 33% in isothermal entropy change (−Δ S m ) and 25% increase in relative cooling power (RCP) for the ribbons compared to the buttons can be attributed to higher structural disorder in the Fe–Cr and Fe–Al sub-lattices of the B2 structure. The critical behavior was investigated using modified Arrott plots, the Kouvel–Fisher plot and the critical isotherm technique; the critical exponents were found to correspond to the short-range order 3D Heisenberg model. The field and temperature dependent magnetization curves of (Fe 0.72 Cr 0.28 ) 3 Al alloys revealed their soft magnetic nature with negligible hysteresis. Thus, these alloys possess promising performance attributes for near room temperature magnetic cooling applications. (paper)

Jet quenching in a strongly coupled anisotropic plasma

Science.gov (United States)

Chernicoff, Mariano; Fernández, Daniel; Mateos, David; Trancanelli, Diego

2012-08-01

The jet quenching parameter of an anisotropic plasma depends on the relative orientation between the anisotropic direction, the direction of motion of the parton, and the direction along which the momentum broadening is measured. We calculate the jet quenching parameter of an anisotropic, strongly coupled {N} = 4 plasma by means of its gravity dual. We present the results for arbitrary orientations and arbitrary values of the anisotropy. The anisotropic value can be larger or smaller than the isotropic one, and this depends on whether the comparison is made at equal temperatures or at equal entropy densities. We compare our results to analogous calculations for the real-world quark-gluon plasma and find agreement in some cases and disagreement in others.

Effects of the molecular rotational dynamics on dielectric and far-infra-red spectra of anisotropic liquids

International Nuclear Information System (INIS)

Nordio, P.L.; Segre, U.

1981-01-01

Dielectric and far-infra-red spectra of uniaxial liquid-crystal phase are analysed in terms of correlation functions calculated by a memory function formalism. SAIL (strong anisotropic interaction limit) conditions are always found to apply, resulting in diffusional regime at low working frequencies. Dipole friction has been also included in the calculations to consider many-particle interactions, its effect being analogous to the introduction of slowly relaxing local structures. (author)

Jets in a strongly coupled anisotropic plasma

Energy Technology Data Exchange (ETDEWEB)

Fadafan, Kazem Bitaghsir [Shahrood University of Technology, Faculty of Physics, Shahrood (Iran, Islamic Republic of); University of Southampton, STAG Research Centre Physics and Astronomy, Southampton (United Kingdom); Morad, Razieh [University of Cape Town, Department of Physics, Rondebosch (South Africa)

2018-01-15

In this paper, we study the dynamics of the light quark jet moving through the static, strongly coupled N = 4, anisotropic plasma with and without charge. The light quark is presented by a 2-parameters point-like initial condition falling string in the context of the AdS/CFT. We calculate the stopping distance of the light quark in the anisotropic medium and compare it with its isotropic value. We study the dependency of the stopping distance to the both string initial conditions and background parameters such as anisotropy parameter or chemical potential. Although the typical behavior of the string in the anisotropic medium is similar to the one in the isotropic AdS-Sch background, the string falls faster to the horizon depending on the direction of moving. Particularly, the enhancement of quenching is larger in the beam direction. We find that the suppression of stopping distance is more prominent when the anisotropic plasma have the same temperature as the isotropic plasma. (orig.)

Anisotropic response of the moving vortex lattice in superconducting Mo(1-x)Gex amorphous films

International Nuclear Information System (INIS)

Dolz, M.I.; Shalóm, D.E.; Pastoriza, H.; López, D.O.

2012-01-01

We have performed magnetic susceptibility measurements in Mo 1-x Ge x amorphous thin films biased with an electrical current using anisotropic coils. We tested the symmetry of the vortex response changing the relative orientation between the bias current and the susceptibility coils. We found a region in the DC current-temperature phase diagram where the dynamical vortex structures behave anisotropically. In this region the shielding capability of the superconducting currents measured by the susceptibility coils is less effective along the direction of vortex motion compared to the transverse direction. This anisotropic response is found in the same region where the peak effect in the critical current is developed. On rising temperature the isotropic behavior is recovered.

Theory of Spin Waves in Strongly Anisotropic Magnets

DEFF Research Database (Denmark)

Lindgård, Per-Anker; Cooke, J. F.

1976-01-01

A new infinite-order perturbation approach to the theory of spin waves in strongly anisotropic magnets is introduced. The system is transformed into one with effective two-ion anisotropy and considerably reduced ground-state corrections. A general expression for the spin-wave energy, valid to any...

Table-like magnetocaloric effect in Gd{sub 56}Ni{sub 15}Al{sub 27}Zr{sub 2} alloy and its field independence feature

Energy Technology Data Exchange (ETDEWEB)

Agurgo Balfour, E.; Ma, Z.; Fu, H., E-mail: fuhao@uestc.edu.cn, E-mail: rockingsandstorm@163.com; Wang, L.; Luo, Y. [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China); Hadimani, R. L.; Jiles, D. C. [Department of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011 (United States); Ames Laboratory, U.S. Department of Energy, Ames, Iowa 50011 (United States); Wang, S. F., E-mail: fuhao@uestc.edu.cn, E-mail: rockingsandstorm@163.com [North Electronic Device Research Institute, Beijing 100141 (China)

2015-09-28

In order to obtain “table-like” magnetocaloric effect (MCE), multiple-phase Gd{sub 56}Ni{sub 15}Al{sub 27}Zr{sub 2} alloy was prepared by arc-melting followed by suck-casting method. Powder x-ray diffraction and calorimetric measurements reveal that the sample contains both glassy and crystalline phases. The fraction of the glassy phase is about 62%, estimated from the heat enthalpy of the crystallization. The crystalline phases, Gd{sub 2}Al and GdNiAl further broadened the relatively wider magnetic entropy change (−ΔS{sub M}) peak of the amorphous phase, which resulted in the table-like MCE over a maximum temperature range of 52.5 K to 77.5 K. The plateau feature of the MCE was found to be nearly independent of the applied magnetic field from 3 T to 5 T. The maximum −ΔS{sub M} value of the MCE platforms is 6.0 J/kg K under applied magnetic field change of 5 T. Below 3 T, the field independence of the table-like feature disappears. The relatively large constant values of −ΔS{sub M} for the respective applied magnetic fields have promising applications in magnetic refrigeration using regenerative Ericsson cycle.

Silicon as an anisotropic mechanical material

DEFF Research Database (Denmark)

Thomsen, Erik Vilain; Reck, Kasper; Skands, Gustav Erik

2014-01-01

While silicon is an anisotropic material it is often in literature treated as an isotropic material when it comes to plate calculations. This leads to considerable errors in the calculated deflection. To overcome this problem, we present an in-depth analysis of the bending behavior of thin crysta...... analytical models involving crystalline plates, such as those often found in the field of micro electro mechanical systems. The effect of elastic boundary conditions is taken into account by using an effective radius of the plate....

Magnetocaloric effects in Mn1.35Fe0.65P1−xSix compounds

International Nuclear Information System (INIS)

Geng Yao-Xiang; Tegus O; Bi Li-Ge

2012-01-01

The structural and magnetocaloric properties of Mn 1.35 Fe 0.65 P 1−x Si x compounds are investigated. The Si-substituted compounds, Mn 1.35 Fe 0.65 P 1−x Si x with x = 0.52, 0.54, 0.55, 0.56, and 0.57, are prepared by high-energy ball milling and the solid-state reaction. The X-ray diffraction shows that the compounds crystallize into the Fe 2 P-type hexagonal structure with space group P6-bar2m. The magnetic measurements show that the Curie temperature of the compound increases from 253 K for x = 0.52 to 296 K for x = 0.56. The isothermal magnetic-entropy change of the Mn 1.35 Fe 0.65 P 1−x Si x compound decreases with the Si content increasing. The maximal value of the magnetic-entropy change is about 7.0 J/kg·K in the Mn 1.35 Fe 0.65 P 0.48 Si 0.52 compound with a field change of 1.5 T. The compound quenched in water possesses a larger magnetic entropy change and a smaller thermal hysteresis than the non-quenched samples. The thermal hysteresis of the compound is less than 3.5 K. The maximum adiabatic temperature change is about 1.4 K in the Mn 1.35 Fe 0.65 P 0.45 Si 0.55 compound with a field change of 1.48 T. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

Quantitative multi-waves migration in elastic anisotropic media; Migration quantitative multi-ondes en milieu elastique anisotrope

Energy Technology Data Exchange (ETDEWEB)

Borgne, H.

2004-12-01

Seismic imaging is an important tool for ail exploration. From the filtered seismic traces and a subsurface velocity model, migration allows to localize the reflectors and to estimate physical properties of these interfaces. The subsurface is split up into a reference medium, corresponding to the low spatial frequencies (a smooth medium), and a perturbation medium, corresponding to the high spatial frequencies. The propagation of elastic waves in the medium of reference is modelled by the ray theory. The association of this theory with a principle of diffraction or reflection allows to take into account the high spatial frequencies: the Kirchhoff approach represents so the medium of perturbations with continuous surfaces, characterized by reflection coefficients. The target of the quantitative migration is to reconstruct this reflection coefficient, notably its behaviour according to the incidence angle. These information will open the way to seismic characterization of the reservoir domain, with. a stratigraphic inversion for instance. In order to improve the qualitative and quantitative migration results, one of the current challenges is to take into account the anisotropy of the subsurface. Taking into account rocks anisotropy in the imaging process of seismic data requires two improvements from the isotropic case. The first one roughly concerns the modelling aspect: an anisotropic propagator should be used to avoid a mis-positioning or bad focusing of the imaged reflectors. The second correction concerns the migration aspect: as anisotropy affects the reflectivity of subsurface, a specific anisotropic imaging formula should be applied in the migration kernel, in order to recover the correct A V A behavior of the subsurface reflectors, If the first correction is DOW made in most so-called anisotropic imaging algorithms, the second one is currently ignored. The first part of my work concerns theoretical aspects. 1 study first the preservation of amplitudes in the

Effect of spin reorientation on magnetocaloric and transport properties of NdAl{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Souza, M.V. de, E-mail: marcos_vinicios@hotmail.com [Núcleo de Pós-Graduação em Física, Campus Prof. José Aloísio de Campos, UFS, 49100-000 São Cristóvão, SE (Brazil); Silva, J.A. da [Núcleo de Pós-Graduação em Física, Campus Prof. José Aloísio de Campos, UFS, 49100-000 São Cristóvão, SE (Brazil); Silva, L.S. [Núcleo de Pós-Graduação em Física, Campus Prof. José Aloísio de Campos, UFS, 49100-000 São Cristóvão, SE (Brazil); Instituto Federal de Tocantins, IFTO – Campus Colinas do Tocantins, AV. Bernardo Sayao S/N, Chácara Raio de Sol, Setor Santa Maria, CEP 77760-000 Colinas do Tocantins, TO (Brazil)

2017-01-01

We report the magneto-thermal and resistive properties of rare-earth dialuminide NdAl{sub 2}, including spin reorientation transition. To this purpose, we used a theoretical model that considers the interactions of exchange and Zeeman, besides the anisotropy due to the electrical crystal field. The theoretical results obtained were compared to experimental data of the NdAl{sub 2} in single crystal and bulk forms. Explicitly, we have calculated the anisotropic variation of magnetic entropy with the magnetic field oriented along the three principal crystallographic directions: [100], [110], and [111] of NdAl{sub 2} single crystal, where a signature of the spin reorientation is observed in the [110] and [111] directions. Moreover, of magnetoresistivity we consider the applied magnetic field along the crystallographic directions [100] and [110]. In turn, for the polycrystalline form, the good agreement between theory and experiment confirms the presence of spin reorientation, which was predicted theoretically in magnetization curves. - Highlights: • Modeling of the thermodynamics quantities in NdAl{sub 2} single crystal and policrystal. • Modeling of the transport properties in NdAl{sub 2} single crystal. • Effect of reorientation of spin on caloric and transport properties.

Anisotropic magnetoresistance and anomalous Nernst effect in exchange biased permalloy/(1 0 0) NiO single-crystal

Energy Technology Data Exchange (ETDEWEB)

Holanda, J., E-mail: joseholanda@df.ufpe.br; Maior, D.S.; Azevedo, A.; Rezende, S.M.

2017-06-15

Highlights: • We have investigated the anisotropic magnetoresistance (AMR) and the anomalous Nernst effect (ANE) in an exchange-biased bilayer Py/(100) NiO single-Crystal. • The shift of the hysteresis loop, measured with the different techniques, yield approximately the same value of H{sub EB}. • In spite of the measurement techniques be based in different physical phenomena, our results confirm the robustness of the exchange anisotropy at the Py/NiO interface. • The strength of the anomalous Nernst effect for the exchange-biased permalloy film is compared to values measured in non biased films. - Abstract: We have investigated the anisotropic magnetoresistance (AMR) and the anomalous Nernst effect (ANE) in an exchange-biased bilayer consisting of a thin film of permalloy deposited on a single crystal antiferromagnetic NiO (1 0 0). The exchange bias field (H{sub EB}) value was obtained by means of AMR, ANE and magnetization hysteresis measurements. The shift of the hysteresis loop, measured with the three different techniques, yield approximately the same value of H{sub EB.} In spite of the measurement techniques be based in different physical phenomena, our results confirm the robustness of the exchange anisotropy at the Py/NiO interface. The strength of the anomalous Nernst effect for the exchange-biased permalloy film is compared to values measured in non biased films.

Anisotropic effects of terahertz emission from laser sparks in air

International Nuclear Information System (INIS)

Zharova, N. A.; Mironov, V. A.; Fadeev, D. A.

2010-01-01

Strong terahertz (THz) radiation can be generated by intense femtosecond laser pulses propagating in air. The excitation of transient current induced in the wake just behind the laser pulse is studied in detail using numerical simulations on the basis of Maxwell's equations for THz-band fields and hydrodynamic model for the plasma motion. It is shown that the thermal effects, anisotropic in character in the case of linear polarized laser field, can explain observed quadrupole-type THz radiation pattern in the experiment performed by Akhmedzhanov et al. [Radiophys. Quantum Electron. 52, 482 (2009)]. Taking into account the transverse structure of the plasma filament, our numerical code enables us to calculate the spatial distribution and temporal evolution of terahertz electron current, its spectrum, and angular emission pattern. It is shown that an expansion of full fields in terms of azimuthal modes is a useful tool for research of THz generation in many situations of practical interest.

Crystal structure, magnetic and magnetocaloric properties of aluminum-doped La{sub 0.6}Sr{sub 0.4}MnO{sub 3} perovskites

Energy Technology Data Exchange (ETDEWEB)

Elhamza, Amal; Dhahri, J. [Universite de Monastir, Laboratoire de la Matiere Condensee et des Nanosciences, Monastir (Tunisia); Rhouma, F.I.H. [Centre de Recherche des Sciences et Technologies de l' Energie, Laboratoire de Photovoltaique de Semi-Conducteurs et de Nanostructures, Hammam-Lif (Tunisia); Hlil, E.K. [CNRS-Universite Joseph Fourier, Institut Neel, Grenoble (France)

2017-05-15

In this paper, we report on the structural, magnetic and magnetocaloric properties of a series of nanocrystallines La{sub 0.6}Sr{sub 0.4}Mn{sub 1-x}Al{sub x}O{sub 3} (0 ≤ x ≤ 0.2) which were prepared by the sol-gel method. The X-ray powder diffraction showed that all our synthesized samples were of a single phase and have crystallized in the hexagonal symmetry with R anti 3c space group. Magnetic measurements showed that the sample exhibits a ferromagnetic-to-paramagnetic phase transition at a Curie temperature close to 206 K. The maximum value of the magnetic entropy change vertical stroke ΔS{sub M}{sup max} vertical stroke was found to be 1.09 J kg{sup -1} K{sup -1} for an applied magnetic field of 5T. At this value of magnetic field, the relative cooling power was 141 J kg{sup -1}. Our result on magnetocaloric properties suggests that La{sub 0.6}Sr{sub 0.4}Mn{sub 1-x}Al{sub x}O{sub 3} nanopowder with (0 ≤ x ≤ 0.2) is attractive as a potential refrigerant for high-temperature magnetic refrigeration. (orig.)

Generalized Fractional Derivative Anisotropic Viscoelastic Characterization

Directory of Open Access Journals (Sweden)

Harry H. Hilton

2012-01-01

Full Text Available Isotropic linear and nonlinear fractional derivative constitutive relations are formulated and examined in terms of many parameter generalized Kelvin models and are analytically extended to cover general anisotropic homogeneous or non-homogeneous as well as functionally graded viscoelastic material behavior. Equivalent integral constitutive relations, which are computationally more powerful, are derived from fractional differential ones and the associated anisotropic temperature-moisture-degree-of-cure shift functions and reduced times are established. Approximate Fourier transform inversions for fractional derivative relations are formulated and their accuracy is evaluated. The efficacy of integer and fractional derivative constitutive relations is compared and the preferential use of either characterization in analyzing isotropic and anisotropic real materials must be examined on a case-by-case basis. Approximate protocols for curve fitting analytical fractional derivative results to experimental data are formulated and evaluated.

Anisotropic power spectrum and bispectrum in the f(ϕ)F2 mechanism

Science.gov (United States)

Bartolo, Nicola; Matarrese, Sabino; Peloso, Marco; Ricciardone, Angelo

2013-01-01

A suitable coupling of the inflaton φ to a vector kinetic term F2 gives frozen and scale invariant vector perturbations. We compute the cosmological perturbations ζ that result from such coupling by taking into account the classical vector field that unavoidably gets generated at large scales during inflation. This generically results in a too-anisotropic power spectrum of ζ. Specifically, the anisotropy exceeds the 1% level (10% level) if inflation lasts ˜5 e-folds (˜50 e-folds) more than the minimal amount required to produce the cosmic microwave background modes. This conclusion applies, among others, to the application of this mechanism for magnetogenesis, for anisotropic inflation, and for the generation of anisotropic perturbations at the end of inflation through a waterfall field coupled to the vector (in this case, the unavoidable contribution that we obtain is effective all throughout inflation, and it is independent of the waterfall field). For a tuned duration of inflation, a 1% (10%) anisotropy in the power spectrum corresponds to an anisotropic bispectrum which is enhanced like the local one in the squeezed limit, and with an effective local fNL˜3(˜30). More in general, a significant anisotropy of the perturbations may be a natural outcome of all models that sustain higher than 0 spin fields during inflation.

Waves and discontinuities in relativistic and anisotropic magnetohydrodynamics

International Nuclear Information System (INIS)

Cissoko, Mahdy

1975-01-01

This work is devoted to the relativistic study of a non-dissipative anisotropic fluid diagram of infinite conductivity. Such a fluid diagram is constructed in part one. Starting from a macroscopic viewpoint a hydrothermodynamic study of the fluid diagram considered is carried out and the fundamental differential system of anisotropic magnetohydrodynamics is deduced. Part two concerns the study of characteristic varieties and propagation of waves for a polytropic anisotropic fluid diagram. Three types of characteristic varieties are revealed: entropy waves (or material waves), magnetosonic waves and Alfven waves. The propagation rates of Alfven and magnetosonic waves are situated with respect to each other. The study of wave cones showed up on the one hand certain special features of wave propagation in anisotropic magnetohydrodynamics and on the other hand the hyperbolic nature of differential operators associated with the various waves [fr

Anisotropic interpolation theorems of Musielak-Orlicz type

Directory of Open Access Journals (Sweden)

Jinxia Li

2016-10-01

Full Text Available Abstract Anisotropy is a common attribute of Nature, which shows different characterizations in different directions of all or part of the physical or chemical properties of an object. The anisotropic property, in mathematics, can be expressed by a fairly general discrete group of dilations { A k : k ∈ Z } $\\{A^{k}: k\\in\\mathbb{Z}\\}$ , where A is a real n × n $n\\times n$ matrix with all its eigenvalues λ satisfy | λ | > 1 $|\\lambda|>1$ . Let φ : R n × [ 0 , ∞ → [ 0 , ∞ $\\varphi: \\mathbb{R}^{n}\\times[0, \\infty\\to[0,\\infty$ be an anisotropic Musielak-Orlicz function such that φ ( x , ⋅ $\\varphi(x,\\cdot$ is an Orlicz function and φ ( ⋅ , t $\\varphi(\\cdot,t$ is a Muckenhoupt A ∞ ( A $\\mathbb {A}_{\\infty}(A$ weight. The aim of this article is to obtain two anisotropic interpolation theorems of Musielak-Orlicz type, which are weighted anisotropic extension of Marcinkiewicz interpolation theorems. The above results are new even for the isotropic weighted settings.

Layered Black Phosphorus: Strongly Anisotropic Magnetic, Electronic, and Electron-Transfer Properties.

Science.gov (United States)

Sofer, Zdeněk; Sedmidubský, David; Huber, Štěpán; Luxa, Jan; Bouša, Daniel; Boothroyd, Chris; Pumera, Martin

2016-03-01

Layered elemental materials, such as black phosphorus, exhibit unique properties originating from their highly anisotropic layered structure. The results presented herein demonstrate an anomalous anisotropy for the electrical, magnetic, and electrochemical properties of black phosphorus. It is shown that heterogeneous electron transfer from black phosphorus to outer- and inner-sphere molecular probes is highly anisotropic. The electron-transfer rates differ at the basal and edge planes. These unusual properties were interpreted by means of calculations, manifesting the metallic character of the edge planes as compared to the semiconducting properties of the basal plane. This indicates that black phosphorus belongs to a group of materials known as topological insulators. Consequently, these effects render the magnetic properties highly anisotropic, as both diamagnetic and paramagnetic behavior can be observed depending on the orientation in the magnetic field. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Anisotropic conductivity imaging with MREIT using equipotential projection algorithm

Energy Technology Data Exchange (ETDEWEB)

Degirmenci, Evren [Department of Electrical and Electronics Engineering, Mersin University, Mersin (Turkey); Eyueboglu, B Murat [Department of Electrical and Electronics Engineering, Middle East Technical University, 06531, Ankara (Turkey)

2007-12-21

Magnetic resonance electrical impedance tomography (MREIT) combines magnetic flux or current density measurements obtained by magnetic resonance imaging (MRI) and surface potential measurements to reconstruct images of true conductivity with high spatial resolution. Most of the biological tissues have anisotropic conductivity; therefore, anisotropy should be taken into account in conductivity image reconstruction. Almost all of the MREIT reconstruction algorithms proposed to date assume isotropic conductivity distribution. In this study, a novel MREIT image reconstruction algorithm is proposed to image anisotropic conductivity. Relative anisotropic conductivity values are reconstructed iteratively, using only current density measurements without any potential measurement. In order to obtain true conductivity values, only either one potential or conductivity measurement is sufficient to determine a scaling factor. The proposed technique is evaluated on simulated data for isotropic and anisotropic conductivity distributions, with and without measurement noise. Simulation results show that the images of both anisotropic and isotropic conductivity distributions can be reconstructed successfully.

Illusion thermal device based on material with constant anisotropic thermal conductivity for location camouflage

Science.gov (United States)

Hou, Quanwen; Zhao, Xiaopeng; Meng, Tong; Liu, Cunliang

2016-09-01

Thermal metamaterials and devices based on transformation thermodynamics often require materials with anisotropic and inhomogeneous thermal conductivities. In this study, still based on the concept of transformation thermodynamics, we designed a planar illusion thermal device, which can delocalize a heat source in the device such that the temperature profile outside the device appears to be produced by a virtual source at another position. This device can be constructed by only one kind of material with constant anisotropic thermal conductivity. The condition which should be satisfied by the device is provided, and the required anisotropic thermal conductivity is then deduced theoretically. This study may be useful for the designs of metamaterials or devices since materials with constant anisotropic parameters have great facility in fabrication. A prototype device has been fabricated based on a composite composed by two naturally occurring materials. The experimental results validate the effectiveness of the device.

Interfacial scattering effect on anisotropic magnetoresistance and anomalous Hall effect in Ta/Fe multilayers

KAUST Repository

Zhang, Qiang

2017-12-26

The effect of interfacial scattering on anisotropic magnetoresistance (AMR) and anomalous Hall effect (AHE) was studied in the (Ta12n/Fe36n)n multilayers, where the numbers give the thickness in nanometer and n is an integer from 1 to 12. The multilayer structure has been confirmed by the XRR spectra and STEM images of cross-sections. The magneto-transport properties were measured by four-point probe method in Hall bar shaped samples in the temperature range of 5 - 300 K. The AMR increases with n, which could be ascribed to the interfacial spin-orbit scattering. At 5 K, the longitudinal resistivity (ρ) increases by 6.4 times and the anomalous Hall resistivity (ρ) increases by 49.4 times from n =1 to n =12, indicative of the interfacial scattering effect. The skew-scattering, side-jump and intrinsic contributions to the AHE were separated successfully. As n increases from 1 to 12, the intrinsic contribution decreases because of the decaying crystallinity or finite size effect and the intrinsic contribution dominated the AHE for all samples. The side jump changes from negative to positive because the interfacial scattering and intralayer scattering in Fe layers both contribute to side jump in the AHE but with opposite sign.

Stability conditions for the Bianchi type II anisotropically inflating universes

International Nuclear Information System (INIS)

Kao, W.F.; Lin, Ing-Chen

2009-01-01

Stability conditions for a class of anisotropically inflating solutions in the Bianchi type II background space are shown explicitly in this paper. These inflating solutions were known to break the cosmic no-hair theorem such that they do not approach the de Sitter universe at large times. It can be shown that unstable modes of the anisotropic perturbations always exist for this class of expanding solutions. As a result, we show that these set of anisotropically expanding solutions are unstable against anisotropic perturbations in the Bianchi type II space

Anisotropic hydrodynamics: Motivation and methodology

Energy Technology Data Exchange (ETDEWEB)

Strickland, Michael

2014-06-15

In this proceedings contribution I review recent progress in our understanding of the bulk dynamics of relativistic systems that possess potentially large local rest frame momentum-space anisotropies. In order to deal with these momentum-space anisotropies, a reorganization of relativistic viscous hydrodynamics can be made around an anisotropic background, and the resulting dynamical framework has been dubbed “anisotropic hydrodynamics”. I also discuss expectations for the degree of momentum-space anisotropy of the quark–gluon plasma generated in relativistic heavy ion collisions at RHIC and LHC from second-order viscous hydrodynamics, strong-coupling approaches, and weak-coupling approaches.

An iterative, fast-sweeping-based eikonal solver for 3D tilted anisotropic media

KAUST Repository

Waheed, Umair bin; Yarman, Can Evren; Flagg, Garret

2015-01-01

Computation of first-arrival traveltimes for quasi-P waves in the presence of anisotropy is important for high-end near-surface modeling, microseismic-source localization, and fractured-reservoir characterization - and it requires solving an anisotropic eikonal equation. Anisotropy deviating from elliptical anisotropy introduces higher order nonlinearity into the eikonal equation, which makes solving the eikonal equation a challenge. We addressed this challenge by iteratively solving a sequence of simpler tilted elliptically anisotropic eikonal equations. At each iteration, the source function was updated to capture the effects of the higher order nonlinear terms. We used Aitken's extrapolation to speed up convergence rate of the iterative algorithm. The result is an algorithm for computing first-arrival traveltimes in tilted anisotropic media. We evaluated the applicability and usefulness of our method on tilted transversely isotropic media and tilted orthorhombic media. Our numerical tests determined that the proposed method matches the first arrivals obtained by wavefield extrapolation, even for strongly anisotropic and highly complex subsurface structures. Thus, for the cases where two-point ray tracing fails, our method can be a potential substitute for computing traveltimes. The approach presented here can be easily extended to compute first-arrival traveltimes for anisotropic media with lower symmetries, such as monoclinic or even the triclinic media.

An iterative, fast-sweeping-based eikonal solver for 3D tilted anisotropic media

KAUST Repository

Waheed, Umair bin

2015-03-30

Computation of first-arrival traveltimes for quasi-P waves in the presence of anisotropy is important for high-end near-surface modeling, microseismic-source localization, and fractured-reservoir characterization - and it requires solving an anisotropic eikonal equation. Anisotropy deviating from elliptical anisotropy introduces higher order nonlinearity into the eikonal equation, which makes solving the eikonal equation a challenge. We addressed this challenge by iteratively solving a sequence of simpler tilted elliptically anisotropic eikonal equations. At each iteration, the source function was updated to capture the effects of the higher order nonlinear terms. We used Aitken\\'s extrapolation to speed up convergence rate of the iterative algorithm. The result is an algorithm for computing first-arrival traveltimes in tilted anisotropic media. We evaluated the applicability and usefulness of our method on tilted transversely isotropic media and tilted orthorhombic media. Our numerical tests determined that the proposed method matches the first arrivals obtained by wavefield extrapolation, even for strongly anisotropic and highly complex subsurface structures. Thus, for the cases where two-point ray tracing fails, our method can be a potential substitute for computing traveltimes. The approach presented here can be easily extended to compute first-arrival traveltimes for anisotropic media with lower symmetries, such as monoclinic or even the triclinic media.

Insulating phase in Sr{sub 2}IrO{sub 4}: An investigation using critical analysis and magnetocaloric effect

Energy Technology Data Exchange (ETDEWEB)

Bhatti, Imtiaz Noor; Pramanik, A.K., E-mail: akpramanik@mail.jnu.ac.in

2017-01-15

The nature of insulating phase in 5d based Sr{sub 2}IrO{sub 4} is quite debated as the theoretical as well as experimental investigations have put forward evidences in favor of both magnetically driven Slater-type and interaction driven Mott-type insulator. To understand this insulating behavior, we have investigated the nature of magnetic state in Sr{sub 2}IrO{sub 4} through studying critical exponents, low temperature thermal demagnetization and magnetocaloric effect. The estimated critical exponents do not exactly match with any universality class, however, the values obey the scaling behavior. The exponent values suggest that spin interaction in present material is close to mean-field model. The analysis of low temperature thermal demagnetization data, however, shows dual presence of localized- and itinerant-type of magnetic interaction. Moreover, field dependent change in magnetic entropy indicates magnetic interaction is close to mean-field type. While this material shows an insulating behavior across the magnetic transition, yet a distinct change in slope in resistivity is observed around T{sub c}. We infer that though the insulating phase in Sr{sub 2}IrO{sub 4} is more close to be Slater-type but the simultaneous presence of both Slater- and Mott-type is the likely scenario for this material. - Highlights: • Critical analysis shows Sr{sub 2}IrO{sub 4} has ferromagnetic ordering temperature T{sub c}~225 K. • Obtained critical exponents imply spin interaction is close to mean-field model. • Analysis of magneto-entropy data also supports mean-field type interaction. • However, the presence of both itinerant and localized spin interaction is evident. • Sr{sub 2}IrO{sub 4} has simultaneous presence of both Slater- and Mott-type insulating phase.

Evaluation of anisotropic effective stress-strain criteria for the biaxial yield and flow of 2024 aluminum tubes

International Nuclear Information System (INIS)

Stout, M.G.; Hecker, S.S.; Bourcier, R.

1983-01-01

2024 aluminum tubes, heat treated to a T6 and T8 temper, were tested in combinations of tension-internal pressure and tension-torsion loading. Yield loci and flow behavior were determined for both modes of loading and compared to theoretical predictions. Both tempers of 2024 aluminum exhibited crystallographic textures and anisotropic yield and flow. Hill's quadratic yield criterion and the associated flow rule under-estimate balanced biaxial yield and flow, which is consistent with hydraulic bulge data on other face-centered cubic metals. Hill's nonquadratic criterion, which adds one additional parameter, and Bassani's criterion, which adds two parameters, predict the anisotropic yield behavior much more accurately. Predictions of the complete flow behavior, including strain paths, with these anisotropic criteria could be improved markedly by including provisions for planar anisotropy

The room-temperature synthesis of anisotropic CdHgTe quantum dot alloys: a "molecular welding" effect.

Science.gov (United States)

Taniguchi, Shohei; Green, Mark; Lim, Teck

2011-03-16

The room-temperature chemical transformation of spherical CdTe nanoparticles into anisotropic alloyed CdHgTe particles using mercury bromide in a toluene/methanol system at room temperature has been investigated. The resulting materials readily dissolved in toluene and exhibited a significant red-shift in the optical properties toward the infrared region. Structural transformations were observed, with electron microscopy showing that the CdTe nanoparticles were chemically attached ('welded') to other CdTe nanoparticles, creating highly complex anisotropic heterostructures which also incorporated mercury.

Hydrodynamic cavitation in Stokes flow of anisotropic fluids

Science.gov (United States)

Stieger, Tillmann; Agha, Hakam; Schoen, Martin; Mazza, Marco G.; Sengupta, Anupam

2017-05-01

Cavitation, the nucleation of vapour in liquids, is ubiquitous in fluid dynamics, and is often implicated in a myriad of industrial and biomedical applications. Although extensively studied in isotropic liquids, corresponding investigations in anisotropic liquids are largely lacking. Here, by combining liquid crystal microfluidic experiments, nonequilibrium molecular dynamics simulations and theoretical arguments, we report flow-induced cavitation in an anisotropic fluid. The cavitation domain nucleates due to sudden pressure drop upon flow past a cylindrical obstacle within a microchannel. For an anisotropic fluid, the inception and growth of the cavitation domain ensued in the Stokes regime, while no cavitation was observed in isotropic liquids flowing under similar hydrodynamic parameters. Using simulations we identify a critical value of the Reynolds number for cavitation inception that scales inversely with the order parameter of the fluid. Strikingly, the critical Reynolds number for anisotropic fluids can be 50% lower than that of isotropic fluids.

Effective Ohm's law for magnetized plasmas with anisotropic inhomogeneities

International Nuclear Information System (INIS)

Shamma, S.E.; Martinez-Sanchez, M.; Louis, J.F.

1978-01-01

Reduction formulae for the effective, or macroscopic, Ohm's law parameters are derived for inhomogeneous plasmas with anisotropic conductivity fluctuations having two general types of geometry: (a) elongated or shortened in the direction of the magnetic field and (b) two-dimensional, with the direction of constant properties lying in the plane perpendicular to the magnetic field. In each case, two approaches are used: (a) a small perturbation method and (b) an approximate method where each region in the plasma is considered separately, and consistency conditions are used to relate the results corresponding to each separate region to the effective properties of the whole plasma. Both methods are found to agree well when the fluctuations are weak, but differences appear at high fluctuation levels and, for nonuniformities very elongated along B, when the Hall parameter β is high. Comparison with available exact solutions valid at high β and strong fluctuation levels indicates that the self-consistency method gives accurate results even in these cases. The results of these analyses are used to evaluate the performance reduction in magnetohydrodynamic channels with plasma nonuniformities of several geometries, including axial streamers, perfectly isotropic fluctuations, and fluctuations elongated along B; the power density is reduced most strongly when β and the rms of the fluctuations are high, and also when the inhomogeneities are stretched along the magnetic field

Effect of reorientation of anisotropic point defects on relaxation of crystal elastic coefficients of high order

International Nuclear Information System (INIS)

Topchyan, I.I.; Dokhner, R.D.

1977-01-01

The effect of reorientation of anisotropic point defects in uniform fields of elastic stresses on the relaxation of the elastic coefficients of a crystal was investigated in the nonlinear elasticity theory approximation. In calculating the interaction of point defects with elastic-stress fields was taken into consideration. The expression for the relaxations of the elasticity coefficients are obtained in an analytical form. The relaxation of the second-order elasticity coefficients is due to the dimentional interaction of a point defect with an applied-stress field, whereas the relaxation of the higher-order elasticity coefficients is determined both by dimentional and module effects

A Morphing framework to couple non-local and local anisotropic continua

KAUST Repository

Azdoud, Yan

2013-05-01

In this article, we develop a method to couple anisotropic local continua with anisotropic non-local continua with central long-range forces. First, we describe anisotropic non-local models based on spherical harmonic descriptions. We then derive compatible classic continuum models. Finally, we apply the morphing method to these anisotropic non-local models and present three-dimensional numerical examples to validate the efficiency of the technique. © 2013 Elsevier Ltd. All rights reserved.

Electromagnetic Wave Transmittance Control using Anisotropic Plasma Lattice

Science.gov (United States)

Matlis, Eric; Corke, Thomas; Hoffman, Anthony

2017-11-01

Experiments of transmission through a lattice array of plasma columns have shown an absorption band close to the plasma frequency at 14 GHz. The beam was oriented at a 35° incident angle to the planar plasma cell. These experiments were designed to determine if the observed absorption was the result of the isotropic plasma medium or that of an anisotropic metamaterial. Transmission of the microwave energy was not consistent with an isotropic material in which absorption would monotonically increase below the plasma frequency. The experimental results are supported by an anisotropic model which was developed for the plasma permittivity using an effective medium approximation. The plasma columns were modeled as uniform rods with permittivity described by a Drude model while the components of the permittivity tensor was calculated using the Maxwell-Garnett effective medium theory. Electron densities of n = 4 x1012 cm-3 were assumed which is consistent with prior experimental measurements. This model confirms the existence of non-zero imaginary wave vector k in a narrow region centered about 14 GHz.

Modeling and experimental investigations of Lamb waves focusing in anisotropic plates

International Nuclear Information System (INIS)

Chapuis, Bastien; Terrien, Nicolas; Royer, Daniel

2011-01-01

The phenomenon of Lamb waves focusing in anisotropic plates is theoretically and experimentally investigated. An analysis based on a far field approximation of the Green's function shows that Lamb waves focusing is analog to the phonon focusing effect. In highly anisotropic structures like composite plates the focusing of A 0 and S 0 mode is strong; the energy propagates preferentially in the fibre directions, which are minima of the slowness. This has to be taken into account when developing, for example, a transducer array for structural health monitoring systems based on Lamb waves in order to avoid dead zones.

Anisotropic nanomaterials preparation, properties, and applications

CERN Document Server

Li, Quan

2015-01-01

In this book anisotropic one-dimensional and two-dimensional nanoscale building blocks and their assembly into fascinating and qualitatively new functional structures embracing both hard and soft components are explained. Contributions from leading experts regarding important aspects like synthesis, assembly, properties and applications of the above materials are compiled into a reference book. The anisotropy, i.e. the direction-dependent physical properties, of materials is fascinating and elegant and has sparked the quest for anisotropic materials with useful properties. With such a curiosi

Electromagnetism on anisotropic fractal media

Science.gov (United States)

Ostoja-Starzewski, Martin

2013-04-01

Basic equations of electromagnetic fields in anisotropic fractal media are obtained using a dimensional regularization approach. First, a formulation based on product measures is shown to satisfy the four basic identities of the vector calculus. This allows a generalization of the Green-Gauss and Stokes theorems as well as the charge conservation equation on anisotropic fractals. Then, pursuing the conceptual approach, we derive the Faraday and Ampère laws for such fractal media, which, along with two auxiliary null-divergence conditions, effectively give the modified Maxwell equations. Proceeding on a separate track, we employ a variational principle for electromagnetic fields, appropriately adapted to fractal media, so as to independently derive the same forms of these two laws. It is next found that the parabolic (for a conducting medium) and the hyperbolic (for a dielectric medium) equations involve modified gradient operators, while the Poynting vector has the same form as in the non-fractal case. Finally, Maxwell's electromagnetic stress tensor is reformulated for fractal systems. In all the cases, the derived equations for fractal media depend explicitly on fractal dimensions in three different directions and reduce to conventional forms for continuous media with Euclidean geometries upon setting these each of dimensions equal to unity.

Plane-wave diffraction by periodic structures with artificial anisotropic dielectrics

International Nuclear Information System (INIS)

Kazerooni, Azadeh Semsar; Shahabadi, Mahmoud

2010-01-01

Periodic structures with artificial anisotropic dielectrics are studied. The artificial anisotropic dielectric material in this work is made of two alternating isotropic dielectric layers. By a proper choice of the dielectric constant of the layers, we can realize a uniaxial anisotropic medium with controllable anisotropy. The artificial anisotropic dielectric is then used in periodic structures. For these structures, the optical axis of the artificial dielectric is assumed to be parallel or perpendicular to the period of the structure. Diffraction of plane waves by these structures is analyzed by a fully vectorial rigorous matrix method based on a generalized transmission line (TL) formulation. The propagation constants and field distributions are computed and diffraction properties of such structures are studied to show that, by a proper choice of structural parameters, these periodic structures with artificial anisotropic dielectrics can be used as polarizers or polarizing mirrors

The generalized PN synthetic acceleration method for linear transport problems with highly anisotropic scattering

International Nuclear Information System (INIS)

Khattab, K.M.

1997-01-01

The diffusion synthetic acceleration (DSA) method has been known to be an effective tool for accelerating the iterative solution of transport equations with isotropic or mildly anisotropic scattering. However, the DSA method is not effective for transport equations that have strongly anisotropic scattering. A generalization of the modified DSA (MDSA) method is proposed that converges (clock time) faster than the MDSA method. This method is developed, the results of a Fourier analysis that theoretically predicts its efficiency are described, and numerical results that verify the theoretical prediction are presented

Coupling two-phase fluid flow with two-phase darcy flow in anisotropic porous media

KAUST Repository

Chen, J.

2014-06-03

This paper reports a numerical study of coupling two-phase fluid flow in a free fluid region with two-phase Darcy flow in a homogeneous and anisotropic porous medium region. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Obtained results have shown the anisotropic properties effect on the velocity and pressure of the two-phase flow. 2014 Jie Chen et al.

Coupling Two-Phase Fluid Flow with Two-Phase Darcy Flow in Anisotropic Porous Media

Directory of Open Access Journals (Sweden)

Jie Chen

2014-06-01

Full Text Available This paper reports a numerical study of coupling two-phase fluid flow in a free fluid region with two-phase Darcy flow in a homogeneous and anisotropic porous medium region. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Obtained results have shown the anisotropic properties effect on the velocity and pressure of the two-phase flow.

Controlling competing orders via nonequilibrium acoustic phonons: Emergence of anisotropic effective electronic temperature

Science.gov (United States)

Schütt, Michael; Orth, Peter P.; Levchenko, Alex; Fernandes, Rafael M.

2018-01-01

Ultrafast perturbations offer a unique tool to manipulate correlated systems due to their ability to promote transient behaviors with no equilibrium counterpart. A widely employed strategy is the excitation of coherent optical phonons, as they can cause significant changes in the electronic structure and interactions on short time scales. One of the issues, however, is the inevitable heating that accompanies these resonant excitations. Here, we explore a promising alternative route: the nonequilibrium excitation of acoustic phonons, which, due to their low excitation energies, generally lead to less heating. We demonstrate that driving acoustic phonons leads to the remarkable phenomenon of a momentum-dependent effective temperature, by which electronic states at different regions of the Fermi surface are subject to distinct local temperatures. Such an anisotropic effective electronic temperature can have a profound effect on the delicate balance between competing ordered states in unconventional superconductors, opening a so far unexplored avenue to control correlated phases.

Anisotropic non-Fermi liquids

Science.gov (United States)

Sur, Shouvik; Lee, Sung-Sik

2016-11-01

We study non-Fermi-liquid states that arise at the quantum critical points associated with the spin density wave (SDW) and charge density wave (CDW) transitions in metals with twofold rotational symmetry. We use the dimensional regularization scheme, where a one-dimensional Fermi surface is embedded in (3 -ɛ ) -dimensional momentum space. In three dimensions, quasilocal marginal Fermi liquids arise both at the SDW and CDW critical points: the speed of the collective mode along the ordering wave vector is logarithmically renormalized to zero compared to that of Fermi velocity. Below three dimensions, however, the SDW and CDW critical points exhibit drastically different behaviors. At the SDW critical point, a stable anisotropic non-Fermi-liquid state is realized for small ɛ , where not only time but also different spatial coordinates develop distinct anomalous dimensions. The non-Fermi liquid exhibits an emergent algebraic nesting as the patches of Fermi surface are deformed into a universal power-law shape near the hot spots. Due to the anisotropic scaling, the energy of incoherent spin fluctuations disperse with different power laws in different momentum directions. At the CDW critical point, on the other hand, the perturbative expansion breaks down immediately below three dimensions as the interaction renormalizes the speed of charge fluctuations to zero within a finite renormalization group scale through a two-loop effect. The difference originates from the fact that the vertex correction antiscreens the coupling at the SDW critical point whereas it screens at the CDW critical point.

The effect of strongly anisotropic scattering on the critical size of a slab in one-speed neutron transport theory: Modified UN method

International Nuclear Information System (INIS)

Öztürk, Hakan

2014-01-01

Highlights: • The criticality problem for one-speed neutrons in homogeneous slab is investigated. • A combination of forward–backward and linear anisotropy is used. • The effect of the strongly anisotropic scattering on the critical size is analyzed. - Abstract: The criticality problem for one-speed neutrons in a uniform finite slab is studied in the case of a combination of forward and backward scattering with linearly anisotropic scattering using U N method based on the Chebyshev polynomials of second kind. The effect of the linear anisotropy on the critical thickness of the slab is investigated. The critical slab thicknesses are calculated by using Marshak boundary condition for various values of the anisotropy parameters and they are presented in the tables. In comparison to the results obtained by other methods, the results of this study are in compatible with the former ones