Sample records for andesites

  1. Co-magmatic andesite enclaves in the Late Eocene andesites from Recsk, North Hungary: Implication for the magma chamber processes.

    Czuppon, Gy.; Harangi, Sz.


    The eastrenmost occurrences of the Late Eocene-Oligocene Periadriatic magmatism can be found around Recsk, at the northeast Mátra Mts., Northern Hungary. This Late Eocene (37 Ma) igneous body was displaced several hundreds km away from their original position along the Balaton-Darnó line during the Early Miocene when the North Pannonian block escaped from the compressive Alpine regime. It is built up by andesite lava and subvolcanic bodies associating with porphyry copper deposits. The andesites contain numerous igneous enclaves, homogeneously distributed in the lava body. Based on the mineral assemblage, the igneosu inclusions are subdivided in two groups: 1. Type enclave contains hornblende, plagioclase, biotite, whereas 2. Type enclave consists also orthopyroxene. They show various textures from hypidiomorphic granular to pylotaxitic ones. The host andesite contains the same mineral assemblage, but with less mafic minerals. Composition of the mineral phases in the andesite and the inclusions overlaps each other. Plagioclases show various zoning patterns (normal, reverz and oscillatory) and a relatively large range in anorthite content from 40 to 85 mol%. The amphiboles are tschermakites and magnesio-hornblendes, having relatively high mg-number (0.69-0.91). They often show oscillatory zoning, too. The bulk rock compositions of the andesites and the igneous inclusions are induistinguishable from one another. They are medium-K calc-alkaline andesites with trace element characters typical of subduction-related volcanic rocks (high LILE/HFSE ratios, enrichment of LILE). Therefore, the igneous inclusions are cogenetic with the host andesites. The textural features and composition of the mineral phases indicate disequilibrium crystallization in the magma chamber and repeated replenishment of mafic magma batches. We propose that the igneous inclusions could be derived from the crystal-rich mush zone of the andesitic magma chamber. Intrusion of fresh magma could

  2. Exploring the scale-dependent permeability of fractured andesite

    Heap, Michael J.; Kennedy, Ben M.


    Extension fractures in volcanic systems exist on all scales, from microscopic fractures to large fissures. They play a fundamental role in the movement of fluids and distribution of pore pressure, and therefore exert considerable influence over volcanic eruption recurrence. We present here laboratory permeability measurements for porous (porosity = 0.03-0.6) andesites before (i.e., intact) and after failure in tension (i.e., the samples host a throughgoing tensile fracture). The permeability of the intact andesites increases with increasing porosity, from 2 ×10-17 to 5 ×10-11 m2. Following fracture formation, the permeability of the samples (the equivalent permeability) falls within a narrow range, 2- 6 ×10-11 m2, regardless of their initial porosity. However, laboratory measurements on fractured samples likely overestimate the equivalent permeability due to the inherent scale-dependence of permeability. To explore this scale-dependence, we first determined the permeability of the tensile fractures using a two-dimensional model that considers flow in parallel layers. Our calculations highlight that tensile fractures in low-porosity samples are more permeable (as high as 3.5 ×10-9 m2) than those in high-porosity samples (as low as 4.1 ×10-10 m2), a difference that can be explained by an increase in fracture tortuosity with porosity. We then use our fracture permeability data to model the equivalent permeability of fractured rock (with different host rock permeabilities, from 10-17 to 10-11 m2) with increasing lengthscale. We highlight that our modelling approach can be used to estimate the equivalent permeability of numerous scenarios at andesitic stratovolcanoes in which the fracture density and width and host rock porosity or permeability are known. The model shows that the equivalent permeability of fractured andesite depends heavily on the initial host rock permeability and the scale of interest. At a given lengthscale, the equivalent permeability of high

  3. Origin of High-Alumina Basalt, Andesite, and Dacite Magmas.

    Hamilton, W


    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it. PMID:17794034

  4. Correlation between aggregate quality and compressive strength of andesite from Hungary

    Czinder, Balázs; Török, Ákos


    Andesite is one of the most common lithology that is used as aggregate. Testing of aggregate quality traditionally includes Los Angeles, micro-Deval tests and the quality of the stone is assessed according to these values. In the present paper both aggregate properties and strength properties of andesites are compared in order to find correlation between aggregate strength, durability and compressive and tensile strength as well as frost resistance. Tests were made from andesite types obtained from two operating quarries of Nógrádkövesd and Gyöngyössolymos. Uniaxial compressive strength (UCS) values were compared with aggregate test results obtained from the same block. Air dry, water saturated and freeze-thaw subjected specimens were tested. According to lithological description and fabric analyses samples were grouped into 4 main lithotypes: one from Nógrádkövesd and three from Gyöngyössolymos. Fine porphyric andesite from Gyöngyössolymos provided the best micro-Deval values. In terms of uniaxial compressive strength the same trend was found, fine porphyric andesite from Gyöngyössolymos had the highest UCS under laboratory conditions, while coarser porphyritic andesite from the same quarry had lower strength. Water saturation decreased UCS as it was expected. Tensile strength values show a gradual deceases from air dry to water saturated and finally subjected to freeze-thaw cycles. Mean micro-Deval value of fine porphyric Gyöngyössolymos andesite was about 7, while that of the coarser porphyritic andesite was app. 16. These values are still higher than the mean micro-Deval test result of Nógrádkövesd andesite; which was 20. A good correlation was found in between Los Angeles and micro-Deval values, but there was no indication that micro-Deval values correlate well with UCS.

  5. Rare-earth element geochemistry and the origin of andesites and basalts of the Taupo Volcanic Zone, New Zealand

    Cole, J.W.; Cashman, K.V.; Rankin, P.C.


    Two types of basalt (a high-Al basalt associated with the rhyolitic centres north of Taupo and a "low-Al" basalt erupted from Red Crater, Tongariro Volcanic Centre) and five types of andesite (labradorite andesite, labradorite-pyroxene andesite, hornblende andesite, pyroxene low-Si andesite and olivine andesite/low-Si andesite) occur in the Taupo Volcanic Zone (TVZ), North Island, New Zealand. Rare-earth abundances for both basalts and andesites are particularly enriched in light rare-earth elements. High-Al basalts are more enriched than the "low-Al" basalt and have values comparable to the andesites. Labradorite and labradorite-pyroxene andesites all have negative Eu anomalies and hornblende andesites all have negative Ce anomalies. The former is probably due to changing plagioclase composition during fractionation and the latter to late-stage hydration of the magma. Least-squares mixing models indicate that neither high-Al nor "low-Al" basalts are likely sources for labradorite/labradorite-pyroxene andesites. High-Al basalts are considered to result from fractionation of olivine and clinopyroxene from a garnet-free peridotite at the top of the mantle wedge. Labradorite/labradorite-pyroxene andesites are mainly associated with an older NW-trending arc. The source is likely to be garnet-free but it is not certain whether the andesites result from partial melting of the top of the subducting plate or a hydrated lower portion of the mantle wedge. Pyroxene low-Si andesites probably result from cumulation of pyroxene and calcic plagioclase within labradorite-pyroxene andesites, and hornblende andesites by late-stage hydration of labradorite-pyroxene andesite magma. Olivine andesites, low-Si andesites and "low-Al" basalts are related to the NNE-trending Taupo-Hikurangi arc structure. Although the initial source material is different for these lavas they have probably undergone a similar history to the labradorite/labradorite-pyroxene andesites. All lavas show evidence

  6. Lead isotope constraints on the origin of andesite and dacite magmas at Tungurahua volcano (Ecuador)

    Nauret, Francois; Ancellin, Marie-Anne; Vlastelic, Ivan; Tournigand, Pierre-Yves; Samaniego, Pablo; Le Pennec, Jean Luc; Gannoun, Mouhcine; Hidalgo, Silvana; Schiano, Pierre


    Understanding the occurrence of large explosive eruptions involving silica-rich magmas at mostly andesitic volcanoes is crucial for volcanic hazard assessment Here we focus on the well-known active Tungurahua volcano (Ecuador), specifically its eruptive sequence for the last 3000 years BP, which are characterized by VEI 3 explosive events involving mostly homogeneous andesitic compositions (56-59 wt.% SiO2). However, some large eruptions (VEI ≥ 4) involving andesitic and dacitic magmas (up to 66 wt.% SiO2) also occur at 3000 BP, 1250 BP and 1886 AD. An additional outburst of siliceous magmas occurred during the last eruptive eruption of this volcano in 2006 [1]. Volcanic products at Tungurahua are described as been generated by a binary mixing between a silica-rich and a silica-poor end-member, but the origin of these components was not discussed [2]. Major, trace elements and Sr-Nd-Pb isotopes were used to investigate the genesis of the andesites and dacites. Andesites are heterogeneous in terms of Pb isotopes (206Pb/204Pb: 18.189-19.154, 207Pb/204Pb:15.658-15.696, 208Pb/204Pb: 38.752-38.918, 207Pb/206Pb: 0.8240-0.8275) but homogeneous in terms of major-trace element. Dacite are characterized by homogenous and low 207Pb/206Pb (0.8235±0.0001), very low Nb/U (1.97 to 4.49) and Ce/Pb (2.52-2.99) and high Th/La ratios (0.24 to 0.49). Triangular distribution of data in major element or trace element ratio vs. Pb isotopes plots suggests that at least three components control geochemical variability at Tungurahua. We interpret andesite compositions as reflecting mainly a deep mixture of two mantle components, with small addition of crustal material. We suggest that dacite results from a mixing between various andesite compositions and a larger amount of a contaminant derived from the volcanic basement of the Tungurahua made of late Cretaceous to Palaeogene oceanic plateau basalts and volcano-sedimentary rocks volcanic. Since andesite and dacite occur during the same

  7. The anatomy of an andesite volcano: A time-stratigraphic study of andesite petrogenesis and crustal evolution at Ruapehu volcano, New Zealand

    Price, R.C.; Gamble, J.A.; Smith, I.E.M.;


    Ruapehu, New Zealand’s largest active andesite volcano is located at the southern tip of the Taupo Volcanic Zone (TVZ), the main locus of subduction-related volcanism in the North Island. Geophysical data indicate that crustal thickness transitions from <25 km within the TVZ to 40 km beneath...... Ruapehu. The volcano is built on a basement of Mesozoic metagreywacke and geophysical evidence together with xenoliths contained in lavas indicates that this is underlain by oceanic, meta-igneous lower crust. The present-day Ruapehu edifice has been constructed by a series of eruptive events that produced...

  8. Mineralogy at the magma-hydrothermal system interface in andesite volcanoes, New Zealand

    Wood, C. Peter


    Ejecta from phreatomagmatic eruptions of Ruapehu and White Island andesite volcanoes in New Zealand provide insight into the mineralogical reactions that occur when magma invades a vent-hosted hydrothermal system. At the surface and in ejected blocks from shallow depths, hydrothermal alteration mineralogies are dominated by silica polymorphs, anhydrite, natroalunite, and pyrite. Blocks from greater depths are composed mainly of cristobalite, anhydrite, halite, and magnetite. Where altered material was heated to magmatic temperatures, thermal decomposition reactions produced mullite, wollastonite, and indialite. Some ejected breccias contain osumilite, cordierite, sanidine, and hypersthene, indicative of reactions occurring near the osumilite-cordierite phase boundary at >800 °C and water pressure hydrothermal deposits. High- temperature parageneses of these types have not been reported before in shallow, acidic volcano-hydrothermal systems. However, they may be typical of the magma- hydrothermal contact zone at many andesite volcanoes.

  9. Strontium isotope data for recent andesites in Ecuador and North Chile

    New Sr isotope data are presented for andesite lavas from active volcanoes in Ecuador and North Chile. Twenty-three samples from five Ecuadorian volcanoes have 87Sr/86Sr ratios most of which are essentially within analytical error, and average 0.7044. In contrast, 16 samples from the San Pedro-San Pablo volcano complex in North Chile have 87Sr/86Sr ratios between 0.7058 and 0.7072. These samples show no correlation between 87Sr/86Sr and 87Rb/86Sr, nor between 87Sr/86Sr and other elements or ratios. The major difference in setting between the two volcanic provinces lies in the thickness of the continental crust; 40-50 km beneath Ecuador, 70 km beneath North Chile. Andesites from both areas are derived primarily from the mantle, but those from North Chile show evidence of a significant Sr isotopic contribution from the continental crust. (Auth.)


    - Munaji


    Full Text Available Telah dilakukan penelitian untuk menentukan nilai resistivitas dan kedalaman batuan andesit di Desa Polosiri. Prinsip kerja metode geolistrik adalah mempelajari aliran listrik di dalam bumi dan cara mendeteksi di permukaan bumi. Metode tahanan jenis didasari oleh hukum Ohm, untuk mengetahui jenis lapisan batuan didasarkan pada distribusi nilai resistivitas pada tiap lapisan. Variasi harga tahanan jenis akan didapatkan jika jarak masing-masing elektroda diubah, sesuai konfigurasi alat yang dipakai (konfigurasi Schlumberger. Data hasil pengukuran di lapangan berupa beda potensial dan arus yang dapat digunakan untuk menghitung resistivitas semu. Penelitian ini dilakukan sebanyak tiga lintasan. Data hasil pengukuran diolah menggunakan software IPI2Win. Berdasarkan hasil penelitian diperoleh bahwa batuan andesit di Desa Polisiri memiliki resistivitas 212 Ωm – 300 Ωm dengan kedalaman 1.3 m - 1.86 m.

  11. Production of ferroan andesites by the experimental partial melting of an LL chondrite

    Mcguire, J. C.; Jurewicz, A. J. G.; Jones, J. H.


    A partial melting experiment on the St. Severin (LL) chondrite produced a melt that was andesitic, having 54-60 wt% silica, at 1200 C and an oxygen fugacity of IW+2, two log units above the iron-wustite (IW) buffer. Under these same conditions, CV, CM, and L chondrites produced low-silica melts resembling angrites. This experimental study attempts to reproduce and explain this unusual result.

  12. Magnetite-bubble aggregates at mixing interfaces in andesite magma bodies.

    Edmonds, M; Brett, A.; Herd, R.A.; Humphreys, M. C. S.; Woods, A


    Magnetite is a particularly favourable site for heterogeneous bubble nucleation in magma and yet only very rarely is evidence for this preserved, owing to the myriad of processes that act to overprint such an association. The possibility of bubble-magnetite aggregates in magmas carries with it interesting implications for the fluid mechanics of magma bodies and for the magma mixing process responsible for the formation of andesites. We use image analysis and statistical methods to...

  13. The nature and occurrence of discrete zoning in plagioclase from recently erupted andesitic volcanic rocks, Montserrat

    Stewart, M. L.; Fowler, A. D.


    Recently erupted rocks from Montserrat, Lesser Antilles, were found to be coarsely porphyritic including plagioclase, magnesio-hornblende, orthopyroxene, titano-magnetite, and rare quartz phenocrysts. Zonations within plagioclase show three distinct periods within the evolution of the andesitic magmas. Initial steady state oscillatory overgrowths (An 49-54) represent an early period of growth within a confined andesitic magma chamber. Interaction with an intruding more mafic hotter magma resulted in thick zones of dissolution features that cut through these early growth layers. The dissolution zones and crystal fragments are overgrown by thin calcic (An 86) plagioclase rims. A plagioclase growth rate of 10 -7cm/s suggests that the calcic plagioclase rims were formed in approximately 10 h, consistent with the idea that mineral growth may increase magma viscosity inducing conduit plugging and shallow pressurization resulting in cycles of dome inflation, eruption, and explosive activity. Thermodynamic modeling of heating and mixing of the andesitic magma with a basaltic liquid produces plagioclase of composition An 79, not the observed composition of the late plagioclase (An 86). We conclude that the final plagioclase grew under non-equilibrium conditions as a result of the mixing event.

  14. The Petrographical-Geochemical Properties and Industrial Availability of the Karadeniz Eregli Andesites (Zonguldak

    Gürkan Bacak


    Full Text Available Aim of this study is to determine the geological properties (lithology, petrography, geochemistry and industrial usibility of the Upper Cretaceous volcanics, seperated on the area, among Kozlu-Krd. Ereğli and Ormanlı, westside of Zonguldak. Volcanics, described as andesite, basaltic andesite and trachy-andesite by petrographically and geochemically, have subduction zone calk-alkaline character. Firstly, in laboratuary studies the aggregate tests (grading, specific gravity, water absorption, organic impurity, flakiness index, Los Angeles test for resistance to wear, peeling test, freezing resistance and UCS were realized on the 5 selected fresh patterns, match with the standarts (TS, ASTM, AASHO. Secondly, concrete tests (grading of the concrete aggregates, concrete preperation, slump test, specific density of concrete and UCS of the concrete were made on the concrete patterns with volcanic aggregate additive.Statistical relationships were determined between values of the agreggate and concrete tests results. Both petrographical, chemical, physical and mechanical tests values of the agreggates and concretes are also match with the standarts, given above.As a conclusion, realized that volcanic aggregates for superstructure materials and C 25/30 concrete which made with volcanic aggregate (by using the specimen of N-4 aggregate for rainforcement buildings, bridges, foundation walls can be used.

  15. Manupulation of microstructure, phase evolution and mechanical properties by devitrification of andesite for use as proppant

    Koseski, Ryan P.

    Small, roughly spherical ceramic particles, approximately 1mm in size are used for a number of applications including casting sands, catalysts, and cement fillers. The oil and natural gas industry utilizes such materials in tonnage quantities yearly as extraction aids. Particles intended for this application are referred to as proppants. Proppants are composed of materials that differ by density, strength and cost, and are selected on a site by site basis. Recently, competing usage and depletion of reserves of one of the most popular category of proppant materials, sintered aluminosilicates (e.g. kaolinite, bauxite) have driven the need for alternative raw materials for proppant manufacturing. Andesite, a by-product of mining operations in the south-west United States was identified as an abundant, readily available, and low cost alternative proppant material that can be fused and net-shaped into a glass which when crystallized results in microstructures which may offer substantial toughening and fracture characteristics which may serve to their advantage for use as proppants that do not decrease the permeability ("blind") the particle bed. This study addressed the devitrification behavior and its role on the mechanical properties of andesite-based glass-ceramic spheres for use as proppants. Timetemperature- transformation studies were performed to evaluate the devitrification behavior of andesite glass. Crystalline phase evolution and microstructural development were evaluated using quantitative x-ray diffraction, scanning electron microscopy, differential thermal analysis, and spectrophotometry. The andesite glass devitrification commenced with the precipitation of iron oxides (magnetite) which served as seeds for the epitaxial growth of dendritic pyroxenes. Mechanical properties, such as diametral compressive strength, fracture toughness, hardness, and fracture morphology were correlated with crystalline phase evolution. Selected heat treatments resulting in the

  16. Rhyolitic calderas and centers clustered within the active andesitic belt of Ecuador's Eastern Cordillera

    In the Ecuadorian volcanic arc a cluster of scattered rhyolitic and dacitic centers within the mainly andesitic Eastern Cordillera includes large caldera structures (Chalupas, Chacana, Cosanga) as well as smaller edifices, built upon the Paleozoic-Mesozoic metamorphic basement. At the Chacana caldera magmatism dates from 2.7 Ma to historic times. These centers erupted enormous ash flows and thick pumice lapilli falls that covered the InterAndean Valley near Quito. The role of the 50-70 km-thick crust with a notable negative gravity anomaly appears to be related to the generation of this highly silicic magmatism occurring along the crest of the Andes in the NVZ.

  17. Contrasting andesitic magmatic systems in adjacent North Island volcanoes, New Zealand: implications for predicting eruptions

    Price, R. C.; Smith, I. E.; Gamble, J. A.; Moebis, A.; Cronin, S. J.


    For active or dormant andesite volcanoes, detailed, stratigraphically controlled, geochemical and petrological information enables an understanding of the magma supply and plumbing system feeding eruptions at the surface. This can establish a basis for predictive eruption models and thus for hazard prediction and management. The potential for petrography to inform volcanic hazard management is demonstrated by comparing two andesitic volcanoes located at the southern end of the Taupo Volcanic Zone in New Zealand's North Island. Ngauruhoe has been constructed over the past 3-5 ka and last erupted in 1975. Nearby Ruapehu has a much longer eruptive history extending back beyond 230 ka B.P. Despite their close spatial proximity, the two volcanoes show geochemical contrasts suggesting that each magmatic system has operated separately. The petrology and geochemistry (major and trace element chemistry, U-series isotopes, Sr and Nd isotopes) of eruptives from each volcano reflect magma evolution in a complex magma storage and plumbing system with magma chemistry strongly influenced by fractional crystallisation and crustal assimilation but in the case of Ngauruhoe there is evidence for cyclicity in the evolution of magma batches and this appears to be driven by periodic replenishment of the magmatic system from the mantle. In contrast, the past 2 ka of eruptive history at Ruapehu reflects random tapping of shallow, volume magma reservoirs.

  18. Wide-angle seismic reflections as direct indictors of partial melt beneath an andesite arc

    Stern, T. A.; Benson, A.; Stratford, W. R.; Gamble, J. A.


    Quasi-linear arcs of andesite volcanoes that erupt above 120 ± 40 km deep Waditi-Benioff zones are one of the most striking surface manifestations of plate tectonics. The prevailing view is that andesite magma that feed these arcs are an end-product of fluid-assisted melting in the mantle wedge1. Two key questions remain unresolved: why is the line of an active arc so sharply defined? and where do parental mantle-derived melts pool and differentiate into mafic restite and more felsic magma components that are so distinctive of continental magmatic arc systems ? Here we present seismic evidence from the MORC (mantle or crust?) project for a focused zone of melt below the andesite arc within northern New Zealand. Nine ~ 0.4 - 1.3 tonne dynamite shots were recorded on ~ 700 seismographs spaced along a 120 km long array across, and normal to the axis of the Taupo Volcanic Zone (TVZ). Two important features of the ray tracing solution are: (i) a lower-crustal, 10 km thick, "rift-pillow" of rocks where the P-wave seismic velocities (Vp) are ~ 6.8-7.1 km/s. Seismic reflections from top and bottom of the pillow are termed R1 and R2 respectively. (ii) Strong seismic reflections (termed R3 reflector) are recorded from a relatively short (12 -18 km-long) reflector at a depth of ~ 32 ± 2 km. An analysis of interval velocities between the R2 and R3 reflectors show a P-wave speed of 7.6 +/- 0.2 km/s, which is interpreted as anomalous upper mantle. Thus R3 is regarded as being a reflector within the upper mantle. Ray-tracing locates R3 beneath the eastern margin of the TVZ and directly beneath the active volcanic (andesite) front and geothermal fields. A causal relationship between the R3 reflector and the andesite arc is therefore implied. The amplitude ratio of the R3/R2 reflections along common traces is as high as 4-6 for incidence angles of reflection of 45-60 degrees. These data suggest R3 is best explained with numerical methods by an interface across which there is a

  19. Thermal properties of andesite from Popocatepetl and Volcán de Colima, México.

    Cardenas-Sanchez, Enrique; De la Cruz-Reina, Servando; Varley, Nick


    The thermal conductivity (K), specific heat (Cp) and the coefficient of heat transfer surface (H) are the basic parameters to describe the process of cooling a volcanic rock fragment released in an explosive event. The analysis of the cooling process by conduction, convection and radiation of heat in volcanic rock fragments, has been limited to basalts, and various minerals such as olivine, pyroxene, quartz, etc. (Miao & Chen, 2014; Branlund & Hofmeister, 2012; Romine et al, 2012;. Schön, 2011; Stroberg et al, 2010;. Schatz & Simmons, 1972). There are no detailed studies on the thermal properties of the andesites, abundant in continental stratovolcanoes, and particularly susceptible from lava domes with frequent destruction processes, such as Popocatepetl and Volcan de Colima. Previously, we developed an algorithm for calculation of the grain-size distribution, degree of fragmentation, the thermal energy released and its possible correlation with Volcanic Explosive Index (VEI) from the cooling curves of fragments from vulcanian and strombolian explosions. These curves were obtained from sequences of time over incandescent deposits recorded at selected pixel thermal images of vulcanian activity in the Popocatepetl and Volcan de Colima, Mexico. However, the model was limited by the lack of thermal parameters of the andesites, forcing a first approximation using basalts data. We present a simple model for the cooling process using andesites samples from Popocatépetl and Volcan de Colima. First, the samples were subjected to a rounding process to minimize surface effects. Then, heated to 800 ° C were extracted from the muffle and cooling rate is measured. The thermal conductivity and coefficient of surface heat are determined using a thermal camera and three thermocouples embedded at various depths within the sample. An inversion method was implemented to determine the thermal properties parameters , by comparing the observed data regarding cooling model for a solid

  20. Paleoproterozoic andesitic volcanism in the southern Amazonian craton (northern Brazil); lithofacies analysis and geodynamic setting

    Roverato, Matteo; Juliani, Caetano; Capra, Lucia; Dias Fernandes, Carlos Marcelo


    Precambrian volcanism played an important role in geological evolution and formation of new crust. Most of the literature on Precambrian volcanic rocks describes settings belonging to subaqueous volcanic systems. This is likely because subaerial volcanic rocks in Proterozoic and Archean volcano-sedimentary succession are poorly preserved due to erosive/weathering processes. The late Paleoproterozoic Sobreiro Formation (SF) here described, seems to be one of the rare exceptions to the rule and deserves particular attention. SF represents the subaerial expression of an andesitic magmatism that, linked with the upper felsic Santa Rosa F., composes the Uatumã Group. Uatumã Group is an extensive magmatic event located in the Xingú region, southwestern of Pará state, Amazonian Craton (northern Brazil). The Sobreiro volcanism is thought to be related to an ocean-continent convergent margin. It is characterized by ~1880 Ma well-preserved calc-alkaline basaltic/andesitic to andesitic lava flows, pyroclastic rocks and associated reworked successions. The superb preservation of its rock-textures allowed us to describe in detail a large variety of volcaniclastic deposits. We divided them into primary and secondary, depending if they result from a direct volcanic activity (pyroclastic) or reworked processes. Our study reinforces the importance of ancient volcanic arcs and rocks contribution to the terrestrial volcaniclastic sedimentation and evolution of plate tectonics. The volcanic activity that produced pyroclastic rocks influenced the amount of detritus shed into sedimentary basins and played a major role in the control of sedimentary dispersal patterns. This study aims to provide, for the first time, an analysis of the physical volcanic processes for the subaerial SF, based in field observation, lithofacies analysis, thin section petrography and less geochemical data. The modern volcanological approach here used can serve as a model about the evolution of Precambrian

  1. Treatment of ammonium-rich swine waste in modified porphyritic andesite fixed-bed anaerobic bioreactor.

    Wang, Qinghong; Yang, Yingnan; Li, Dawei; Feng, Chuanping; Zhang, Zhenya


    In this study, a modified porphyritic andesite (WRS) was developed as ammonium adsorbent and bed material for the anaerobic digestion of ammonium-rich swine waste. The performance in bioreactors with modified WRS, natural WRS, calcium chloride and no additives was investigated. The bioreactor with modified WRS exhibited the best performance, with start-up time on the 7th day, methane yield of 359.71 ml/g-VS, and COD removal of 67.99% during all 44 days of the experiment at 35°C. The effective ammonium adsorption and essential ions dissociation for microorganisms by modified WRS, as well as the immobilization of microbial on the surface of the modified WRS play a great role on the high efficiency anaerobic digestion of ammonium-rich swine waste. PMID:22366608

  2. Andesitic Plinian eruptions at Mt. Ruapehu: quantifying the uppermost limits of eruptive parameters

    Pardo, Natalia; Cronin, Shane; Palmer, Alan; Procter, Jonathan; Smith, Ian


    New tephro-stratigraphic studies of the Tongariro Volcanic Centre (TgVC) on the North Island (New Zealand) allowed reconstruction of some of the largest, andesitic, explosive eruptions of Mt. Ruapehu. Large eruptions were common in the Late Pleistocene, before a transition to strombolian-vulcanian and phreatomagmatic eruptive styles that have predominated over the past 10,000 years. Considering this is the most active volcano in North Island of New Zealand and the uppermost hazard limits are unknown, we identified and mapped the pyroclastic deposits corresponding to the five largest eruptions since ~27 ka. The selected eruptive units are also characterised by distinctive lithofacies associations correlated to different behaviours of the eruptive column. In addition, we clarify the source of the ~10-9.7 ka Pahoka Tephra, identified by previous authors as the product of one of the largest eruptions of the TgVC. The most common explosive eruptions taking place between ~13.6 and ~10 ka cal years BP involved strongly oscillating, partially collapsing eruptive columns up to 37 km high, at mass discharge rates up to 6 × 108 kg/s and magnitudes of 4.9, ejecting minimum estimated volumes of 0.6 km3. Our results indicate that this volcano (as well as the neighbouring andesitic Mt. Tongariro) can generate Plinian eruptions similar in magnitude to the Chaitén 2008 and Askja 1875 events. Such eruptions would mainly produce pyroclastic fallout covering a minimum area of 1,700 km2 ESE of the volcano, where important touristic, agricultural and military activities are based. As for the 1995/1996 eruption, our field data indicate that complex wind patterns were critical in controlling the dispersion of the eruptive clouds, developing sheared, commonly bilobate plumes.

  3. The Origin of Voluminous Dacite (vs. Andesite) at Mature, Thick Continental Arcs: A Reflection of Processes in the Deep Crust

    Lange, R. A.


    An outstanding question is why some continental arc segments are characterized by voluminous eruptions of dacite (65-70 wt% SiO2), whereas others erupt more andesite (58-64 wt% SiO2) than any other magma type. An example of the former is the Altiplano-Puna region of the central Andean arc, which has erupted a predominance of dacite over all magma types 10-1 Ma (de Silva, 1989). In contrast, a 200-km arc segment of the Mexican volcanic arc (Michoacán-Guanajuato arc segment) has erupted ~75% andesite, ~26% basaltic andesite and literature, it is proposed that the andesites were derived by partial melting (>20%) of hornblende-rich (~40%) gabbronorite in the deep crust, driven by mantle-derived basalt intrusions at depths of 30-40 km. The absence of any dacite or rhyolite along this arc segment indicates that interstitial liquid from crystal-rich andesites never segregated to form eruptible magma. Thus, little upper-crust differentiation occurred along this arc segment. On the basis of phase-equilibrium experiments in the literature (e.g., Sisson et al., 2005), it is proposed that rhyolite and dacite did form during partial melting of the lower arc crust, but at melt fractions too low (≤15%) to permit efficient transport to the upper crust (Vigneresse and Tikoff, 1999). It is further proposed that the reason why dacite is so abundant at mature thick continental arcs (e.g., Altiplano-Puno complex) may be because mantle-derived basalts are primarily emplaced at similar depths (~30-40 km) in continental arc crustal columns. If so, in the central Andean arc, a depth of 30-40 km is within the middle dioritic crust (Graeber and Asch, 1999). Partial melts of hornblende diorite (vs. hornblende gabbro) are predicted to be dacitic (vs. andesitic) at melt fractions of 20-25%, which permits transport to the upper crust. It is therefore proposed that it is deep crustal processes that determine whether andesite or dacite is the most voluminous magma type emplaced into the upper

  4. The Bowen-Fenner Debate Revisited: A Review of Basalt Crystal Fractionation and the Generation of Andesite

    Conrey, R. M.


    The Bowen-Fenner debate over the nature of basalt crystal fractionation is still unresolved. Bowen's classic 1928 book detailed his basalt-andesite-rhyolite fractionation scheme, whereas Fenner emphasized the evidence for Fe-enrichment during most basalt crystallization, thus anticipating discovery of the Skaergaard. In the 1940's Bowen suggested only wet basalt generates common andesite. To address this debate MELTS simulations were performed with near-constant parents but varied water contents from 0-4 wt per cent. For comparison, data were compiled from mid-ocean ridge (MORB), back-arc basin (BABB), and arc basalts. There is a strong correlation between empirical fractionation patterns and the simulations. Dry basaltic magma exemplified by MORB shows fractionation patterns controlled by early plagioclase crystallization, whereas nearly all wet arc basaltic magmas have patterns controlled by crystallization of mafic minerals, with the later onset of highly calcic plagioclase. BABB have fractionation patterns between those two extremes. The fundamental antithetic behavior of Al and Fe during basalt crystal fractionation due to the sensitive control over plagioclase crystallization by water is completely obscured by the use of Harker and AFM diagrams. Mafic arc basalts which show evidence for significant crystallization of magnetite are largely lacking - most arc basalt fractionation patterns are consistent with 2-3 per cent H2O in the primitive melt and oxygen fugacity near the NNO buffer. A few mafic arc volcanoes have steep increases in Al content or slightly declining Fe content with only slight increases in FeO*/MgO suggestive of significant magnetite crystallization. Magma at these centers must be somewhat more hydrous and/or oxidized than is the normal case. Arc basalt clinopyroxene compositions support the inference that common high-alumina basalt (HAB) is a derivative magma, as empirical and experimental data, and MELTS simulations, all show coupled

  5. Paleoproterozoic crustal evolution in the East Sarmatian Orogen: Petrology, geochemistry, Sr-Nd isotopes and zircon U-Pb geochronology of andesites from the Voronezh massif, Western Russia

    Terentiev, R. A.; Savko, K. A.; Santosh, M.


    Andesites and related plutonic rocks are major contributors to continental growth and provide insights into the interaction between the mantle and crust. Paleoproterozoic volcanic rocks are important components of the East Sarmatian Orogen (ESO) belonging to the East European Craton, although their petrogenesis and tectonic setting remain controversial. Here we present petrology, mineral chemistry, bulk chemistry, Sr-Nd isotopes, and zircon U-Pb geochronological data from andesites and related rocks in the Losevo and Vorontsovka blocks of the ESO. Clinopyroxene phenocrysts in the andesites are depleted in LREE, and enriched in HFSE (Th, Nb, Zr, Hf, Ti) and LILE (Ba, Sr). Based on the chemistry of pyroxenes and whole rocks, as well as Fe-Ti oxides, we estimate a temperature range of 1179 to 1262 °C, pressures of 11.3 to 13.0 kbar, H2O content of 1-5 wt.%, and oxygen fu gacity close to the MH buffer for the melts of the Kalach graben (KG) and the Baygora area (BA) andesites. Our zircon U-Pb geochronological data indicate new zircon growth during the middle Paleoproterozoic as displayed by weighted mean 207Pb/206Pb ages of 2047 ± 17 Ma and 2040 ± 16 Ma for andesite and dacite-porphyry of the BA, and 2050 ± 16 Ma from high-Mg basaltic andesite of the KG. The andesites and related rocks of the KG and BA are characterized by high magnesium contents (Mg # up to 0.68). All these volcanic rocks are depleted in LREE and HFSE, and display negative Nb and Ti anomalies relative to primitive mantle. The high-Mg bulk composition, and the presence of clinopyroxene phenocrysts suggests that the parent melts of the KG and BA suite were in equilibrium with the mantle rocks. The rocks show positive εNd(T) values and low initial 87Sr/86Sr, suggesting that the magmas were mostly derived from metasomatized mantle source. The geochemical differences between the two andesite types are attributed to: the predominance of fractional crystallization, and minor role of contamination in the

  6. Evidence for Magma-Mixing and Disequilibrium in 'Primitive' Basaltic Andesites From Mount Shasta, Northern California

    Leeman, W. P.; Streck, M. J.; Chesley, J. T.; Tonarini, S.


    High-Mg basaltic andesites near Mt. Shasta volcano have been considered fundamental to establishing the existence of exceptionally water-rich primary magmas in this system, implying significant slab-derived fluid fluxes into the underlying mantle wedge (Grove et al., 2002). This notion was reinvestigated via new mineralogical and geochemical studies of fresh scoria blocks from the Whaleback volcano (loc. S17; Anderson,1979). These high-Mg andesites (58% SiO2, 8.5% MgO, Mg# = 76, 120 ppm Ni, 550 ppm Cr) carry small dunitic xenoliths and xeno/phenocrysts (ol+opx+cpx). Plagioclase is not a liquidus phase. Electron microprobe traverses and back-scattered images show that mafic silicates, particularly pyroxenes, have complex histories. Olivine compositions of larger crystals and interiors are often above Fo90 up to Fo94 whereas microphenocrysts and rims of larger crystals are ~Fo87. Complexities among pyroxenes include: (a) Cores of opx and cpx with low Mg# (~67) containing melt inclusions; this evidence indicates these pyroxenes crystallized from magma of roughly dacitic composition; (b) Virtually all low Mg# grains are resorbed and have overgrowths (~20 microns) of high Mg# (87-92) that may be internally zoned arriving at a Mg# near 80 at the outermost euhedral rim; (c) Another variant is orthopyroxene with 'wormy' texture and either a thin (~15 microns) euhedral overgrowth or anhedral outline; compositions of resorbed interiors and overgrowth are similar ( Mg# range: 80 to 90), but distribution of lower and higher Mg# in resorbed areas is patchy whereas any compositional zoning of overgrowth follows crystal shape and arrives again at a Mg# of ~80 at the outermost rim. These data record mixing of diverse magmas (dacite and one or more basaltic liquids) combined with entrainment of ultramafic crystal debris during wall rock contamination, and eventual cooling and equilibration. Low Al2O3 contents in the pyroxenes imply that these minerals grew at relatively low

  7. Petrographic and Geochemical Investigation of Andesitic Arc Volcanism: Mount Kerinci, Sunda Arc, Indonesia

    Tully, M.; Saunders, K.; Troll, V. R.; Jolis, E.; Muir, D. D.; Deegan, F. M.; Budd, D. A.; Astbury, R.; Bromiley, G. D.


    Present knowledge of the chain of dominantly andesitic volcanoes, which span the Sumatran portion of the Sunda Arc is extremely limited. Previous studies have focused on Toba and Krakatau, although over 13 further volcanic edifices are known. Several recent explosive eruptions in Sumatra such as that of Mt. Sinabung, 2014, have highlighted the potential hazard that these volcanoes pose to the local and regional communities. Mount Kerinci, is one of the most active of the volcanoes in this region, yet little is known about the petrogenesis of the magma by which it is fed. Kerinci is located approximately mid-way between Toba in the North and Krakatau in the south. Along arc variations are observed in the major, minor and trace elements of whole rock analyses. However, bulk rock approaches produce an average chemical composition for a sample, potentially masking important chemical signatures. In-situ micro-analytical analysis of individual components of samples such as melt inclusions, crystals and groundmass provides chemical signatures of individual components allowing the evolution of volcanic centres to be deciphered in considerably more detail. Examination of whole rock chemistry indicates its location may be key to unravelling the petrogenesis of the arc as significant chemical changes occur between Kerinci and Kaba, 250 km to the south. Kerinci samples are dominantly porphyritic with large crystals of plagioclase, pyroxene and Fe-Ti oxides, rare olivine crystals are observed. Plagioclase and pyroxene crystals are chemically zoned and host melt inclusions. Multiple plagioclase populations are observed. A combination of in-situ micro-analysis techniques will be used to characterise the chemical composition of melt inclusions and crystals. These data can be used along with extant geothermobarometric models to help determine the magma source, storage conditions and composition of the evolving melt. Integration of the findings from this study with existing data for

  8. Subaqueous cryptodome eruption, hydrothermal activity and related seafloor morphologies on the andesitic North Su volcano

    Thal, Janis; Tivey, Maurice; Yoerger, Dana R.; Bach, Wolfgang


    North Su is a double-peaked active andesite submarine volcano located in the eastern Manus Basin of the Bismarck Sea that reaches a depth of 1154 m. It hosts a vigorous and varied hydrothermal system with black and white smoker vents along with several areas of diffuse venting and deposits of native sulfur. Geologic mapping based on ROV observations from 2006 and 2011 combined with morphologic features identified from repeated bathymetric surveys in 2002 and 2011 documents the emplacement of a volcanic cryptodome between 2006 and 2011. We use our observations and rock analyses to interpret an eruption scenario where highly viscous, crystal-rich andesitic magma erupted slowly into the water-saturated, gravel-dominated slope of North Su. An intense fragmentation process produced abundant blocky clasts of a heterogeneous magma (olivine crystals within a rhyolitic groundmass) that only rarely breached through the clastic cover onto the seafloor. Phreatic and phreatomagmatic explosions beneath the seafloor cause mixing of juvenile and pre-existing lithic clasts and produce a volcaniclastic deposit. This volcaniclastic deposit consists of blocky, non-altered clasts next, variably (1-100%) altered clasts, hydrothermal precipitates and crystal fragments. The usually applied parameters to identify juvenile subaqueous lava fragments, i.e. fluidal shape or chilled margin, were not applicable to distinguish between pre-existing non-altered clasts and juvenile clasts. This deposit is updomed during further injection of magma and mechanical disruption. Gas-propelled turbulent clast-recycling causes clasts to develop variably rounded shapes. An abundance of blocky clasts and the lack of clasts typical for the contact of liquid lava with water is interpreted to be the result of a cooled, high-viscosity, crystal-rich magma that failed as a brittle solid upon stress. The high viscosity allows the lava to form blocky and short lobes. The pervasive volcaniclastic cover on North Su is

  9. Attenuation and scattering of gamma-ray through andesite and felsite

    The study of gamma-ray interactions with matter is increasingly important primarily due to new applications of gamma- emitting isotopes in agriculture, medicine and industry. Two igneous rocks, andesite and felsite, are investigated for radiation shields. The effects of particle size (grain diameter) d mm and sample density ρ on the linear μ, mass μ/ρ attenuation coefficients and side scattering coefficients φs of compressed and natural rocks has been studied with gamma radiation energy E ranging from 0.36 to 1.33 MeV. Flux distribution in samples and the half value layers X1/2 were determined. The results showed an inverse proportionality between the linear attenuation coefficient μ and both d and E. It was also found that μ has a direct proportionality with the sample density ρ. The side scattering coefficient φs is directly proportional to both d and E, but at the same time φs has an inverse proportionality with the sample density ρ

  10. The Cerro Bitiche Andesitic Field: petrological diversity and implications for magmatic evolution of mafic volcanic centers from the northern Puna

    Maro, Guadalupe; Caffe, Pablo J.


    The Cerro Bitiche Andesitic Field (CBAF) is one of the two largest mafic volcanic fields in northern Puna (22-24° S) and is spatially and temporally associated with ignimbrites erupted from some central Andean Altiplano-Puna Volcanic Complex calderas. The CBAF comprises seven scoria cones and widespread high-K calcalkaline lava flows that cover an area of 200 km2. Although all erupted rocks have a relatively narrow chemical range (56-62 % SiO2, 3-6 % MgO), there is a broad diversity of mineral compositions and textures. The least evolved lavas (˜58-61 % SiO2) are high-Mg andesites with scarce (<10 %) microphenocrysts of either olivine or orthopyroxene. The small compositional range and low phenocryst content indicate evolution controlled by low percentages (<10 %) of fractional crystallization of olivine and clinopyroxene of magmas similar to the least evolved rocks from the field, accompanied by assimilation during rapid ascent through the crust. Evolved andesites (˜62 wt% SiO2), on the other hand, are porphyritic rocks with plagioclase + orthopyroxene + biotite and ubiquitous phenocryst disequilibrium textures. These magmas were likely stored in crustal reservoirs, where they experienced convection caused by mafic magma underplating, magma mixing, and/or assimilation. Trace element and mineral compositions of CBAF lavas provide evidence for complex evolution of distinct magma batches.

  11. Natural analogues: Alamosa River monzonite intrusive into tuffaceous and andesitic rocks

    This project encompasses investigations of selected natural analogues of minerals and rocks containing radioelements and fission-product elements, to ascertain how radionuclides and their daughter elements may migrate from sites or origin in response to long-term natural processes such as heating due to an igneous intrusion, circulating hydrothermal systems, diffusion through the rock matrix, weathering and erosion. Comparison of natural occurrences with conceptual models based on laboratory data will furnish a test of such models over time periods comparable to or longer than those expected for a repository. For this study, we have examined large-scale intrusions of igneous rocks which have profoundly affected the thermal and hydrologic settings of large masses of surrounding country rock, and occurrences where migration of elements has occurred after intrusion and subsequent cooling. Specifically, we have investigated the Alamosa River stock, intrusive into tuffaceous rocks and andesites of the Platoro Caldera in the San Juan Mountains of southern Colorado. The oxygen isotopic studies show the effect of extensive hydrothermal activity on the intruded rocks, as well as the host tuffaceous and flow rocks. Convective cooling has been demonstrated for the Alamosa River Stock. The distribution of U, Th, REE, V, K, Ti, in each rock is apparently unaffected by the intrusion. This is true also for Rb, Sr, Ta, Na, and others, although for some of these elements there is no strong chemical gradient between the rocks. Some elements show some evidence for contact zone mobility, but only within ten meters or so of the contact (Cs, Cr, Co). Both the mozonite and tuff have retained their bulk chemistry during and after intrusion. The absence of elemental migration between the tuffs and monzonites, even in a convective system, supports continued assessment of such rocks for radwaste repository consideration

  12. The challenging retrieval of the displacement field from InSAR data for andesitic stratovolcanoes : case study of Popocatepetl and Colima Volcano, Mexico

    Pinel, Virginie; Hooper, A.; De la Cruz-Reyna, S.; Reyes-Davila, G.; Doin, M. P.; Bascou, P.


    Despite the ability of synthetic aperture radar (SAR) interferometry to measure ground motion with high-resolution, application of this remote sensing technique to monitor andesitic stratovolcanoes remains limited. Specific acquisition conditions characterizing andesitic stratovolcanoes, mainly vegetated areas with large elevation ranges, induce low signal coherence as well as strong tropospheric artefacts that result in small signal-to-noise ratio. We propose here a way to mitigate these dif...

  13. Geochemistry of Garibaldi Lake andesites and dacites indicates crustal contamination involved in formation of Northern Cascade arc lavas

    Martindale, M.; Mullen, E.; Weis, D.


    The Cascade Arc presents a unique setting for studying the controls on andesite genesis and the implications for growth and evolution of the continental crust. It is the type-locality for a ';hot' subduction zone, where the downgoing slab is young and subduction is relatively slow. The northern segment of the Cascade arc, the Garibaldi Volcanic Belt (GVB), hosts the youngest subducting crust in Cascadia and the termination of the subducting slab. These conditions may affect magma generation processes by reducing the amount of water reaching the area of melt generation [1,2] and imparting an adakitic signature to magmas generated there if the slab edge melts [3]. We provide insights on the origin of andesites and dacites from the Garibaldi Lake area using new high-precision Pb, Sr, Nd, Hf isotope ratios and trace element data. Andesites and dacites from the Garibaldi Lake area (The Black Tusk, Mt. Price, and The Table) are calc-alkaline and show evidence for crustal contamination such as positive correlations between Ba/Nb and SiO2. Silica variation diagrams show no systematic trend for any of the volcanic centres, suggesting the presence of distinct magma batches. Garibaldi Lake andesites and dacites have among the least radiogenic Pb isotope ratios of all Cascade arc lavas, and define a linear array in Pb-isotope space. This most likely reflects mixing between MORB-source mantle (similar to Gorda and Explorer plate sources) and locally subducting sediments [4]. However, relative to GVB basalts and lavas from the rest of the Cascades (High Cascades), the andesites and dacites have higher 207Pb/204Pb (15.55-15.56) for a given 206Pb/204Pb (18.66-18.74). The Garibaldi Lake lavas also have higher 87Sr/86Sr (0.7033-0.7036) and lower ɛNd (5.8-7.9) at a given 206Pb/204Pb than GVB basalts and High Cascades lavas but among the highest ɛNd for a given SiO2 for the whole of the Cascades. ɛHf values (10.5-13.5) are higher at a given SiO2 value for Garibaldi Lake evolved

  14. Geochemistry of the high-Mg andesites at Zhangwu, western Liaoning: Implication for delamination of newly formed lower crust

    HUANG; Hua; GAO; Shan; HU; ZhaoChu; LIU; XiaoMing; YUAN; HongLing


    Ten volcanic samples at Zhangwu, western Liaoning Province, North China were selected for a systematic geochemical, mineralogical and geochronological study, which provides an opportunity to explore the interaction between the continental crust and mantle beneath the north margin of the North China craton. Except one basalt sample (SiO2= 50.23%), the other nine samples are andesitic with SiO2 contents ranging from 53% to 59%. They have relatively high MgO (3.4%-6.1%, Mg#=50-64) and Ni and Cr contents (Ni 27×10-6-197×10-6, Cr 51×10-6-478×10-6). Other geochemical characteristics of Zhangwu high-Mg andesites (HMAs) include strong fractionation of light rare earth elements (LREE) from heavy rare earth elements (HREE), and Sr from Y, with La/Yb greater than 15, and high Sr/Y (34-115). Zircons of andesite YX270 yield three age groups with no Precambrian age, which precludes origin of the Zhangwu HMAs from the partial melting of the Precambrian crust. The oldest age group peaking at 253 Ma is interpreted to represent the collision of the Siberia block and the North China block, resulting in formation of the Central Asian orogenic belt by closure of the Mongol-Okhotsk Ocean. The intermediate age group corresponds to the basalt underplating which caused the widespread coeval granitoids in the North China craton with a peak 206Pb/238U age of 172 Ma. The youngest age group gives a 206Pb/238U age of 126±2 Ma, which is interpreted as the eruption age of the Zhangwu HMAs. The high 87Sr/86Sri(126 Ma)>0.706 and low -Nd(t)= -6.36--13.99 of the Zhangwu HMAs are distinct from slab melts. The common presence of reversely zoned clinopyroxene phenocrysts in the Zhangwu HMAs argues against the origin of the Zhangwu HMAs either from melting of the water saturated mantle or melting of the lower crust. In light of the evidence mentioned above, the envisaged scenario for the formation of the Zhangwu HMAs is related to the basaltic underplating at the base of the crust, which led to

  15. Soil development along elevational transects on granite, andesitic lahar and basalt in the western Sierra Nevada, California

    Dahlgren, R. A.; Rasmussen, C.; Southard, R. J.


    Soil development along three elevational transects, consisting of granite, andesitic lahar and basalt, were investigated on the western slopes of the Sierra Nevada, California to assess the effects of climate on soil properties and processes. The transects, each consisting of four to seven soils, spanned elevations between 150 to 2900 m with mean annual temperatures (3-17 C) decreasing and precipitation (33-150 cm) increasing with increasing elevation. All sites were characterized by a Mediterranean climate with warm to hot, dry summers and cool to cold, wet winters. Vegetation progressed from oak woodland/annual grasslands at low elevations to mixed conifer forest at mid elevations and subalpine mixed conifer forest at high elevations. Soil pH and base saturation decreased with increasing elevation with the largest decrease found on granite. Solum carbon pools ranged from 2 to 25 kg m-2 with the highest contents found in soils formed on andesitic lahar and in mid-elevation soils corresponding to the highest ecosystem net primary productivity. The degree of weathering and mineral assemblages exhibited a strong threshold change at the elevation of the permanent winter snowline (1200-1500 m). Measures of chemical weathering (e.g., clay and Fe oxide production) increased in a near-linear fashion to the winter snowline where they abruptly decreased by about 10-fold. The clay mineralogical assemblage in the rain-dominated weathering zone was dominated by kaolin minerals and was remarkably similar among all parent materials. Within the snow-dominated weathering zone, clay mineralogy was dominated by allophanic materials (allophone/imogolite) on the andesite and basalt compared to hydroxy-Al interlayered 2:1 layer silicates and gibbsite on the granite. Clay translocation resulting in the formation of argillic horizons was only found in the rain-dominated zone. With increasing elevation, soil development followed the order: Alfisols → Ultisols → Inceptisols (granite

  16. Flowage differentiation in an andesitic dyke of the Motru Dyke Swarm (Southern Carpathians, Romania) inferred from AMS, CSD and geochemistry

    Nkono, Collin; Féménias, Olivier; Diot, Hervé; Berza, Tudor; Demaiffe, Daniel


    Two dykes of different thickness (5.5 m for TJ31 and 23 m for TJ34) from the late Pan-African calc-alkaline Motru Dyke Swarm (S. Carpathians, Romania) have been studied by electron microprobe (mineral chemistry), crystal size distribution (CSD), anisotropy of magnetic susceptibility (AMS) and whole-rock geochemistry. All the physical and chemical variations observed across the dyke's width point to concordant results and show that the variations of both modal abundance and size of the amphibole and biotite microphenocrysts inside the dykes (deduced from the classical CSD measurements) are the result of a mechanical segregation of suspended crystals during magmatic transport. Despite a pene-contemporaneous regional tectonic, the flow-induced differentiation in the thicker dyke is characterized by the concentration of pre-existing Ti-rich pargasite-tschermakite, clinopyroxene and plagioclase crystals in the core of the dyke and of the extracted differentiated liquid near the walls. This mechanical differentiation induces a chemical differentiation with a basaltic andesite composition for the core of the dyke whereas the margins are andesitic. Thus the chilled margins appear as a slightly more evolved liquid with a Newtonian behaviour when compared to the average composition of the dyke. The localization of the liquid on both sides of the dyke has certainly facilitated the ascent of the central part of the dyke that behaved as a Binghamian mush.

  17. Soluble iron inputs to the Southern Ocean through recent andesitic to rhyolitic volcanic ash eruptions from the Patagonian Andes

    Simonella, L. E.; Palomeque, M. E.; Croot, P. L.; Stein, A.; Kupczewski, M.; Rosales, A.; Montes, M. L.; Colombo, F.; García, M. G.; Villarosa, G.; Gaiero, D. M.


    Patagonia, due to its geographic position and the dominance of westerly winds, is a key area that contributes to the supply of nutrients to the Southern Ocean, both through mineral dust and through the periodic deposits of volcanic ash. Here we evaluate the characteristics of Fe dissolved (into soluble and colloidal species) from volcanic ash for three recent southern Andes volcanic eruptions having contrasting features and chemical compositions. Contact between cloud waters (wet deposition) and end-members of andesitic (Hudson volcano) and rhyolitic (Chaitén volcano) materials was simulated. Results indicate higher Fe release and faster liberation rates in the andesitic material. Fe release during particle-seawater interaction (dry deposition) has higher rates in rhyolitic-type ashes. Rhyolitic ashes under acidic conditions release Fe in higher amounts and at a slower rate, while in those samples containing mostly glass shards, Fe release was lower and faster. The 2011 Puyehue eruption was observed by a dust monitoring station. Puyehue-type eruptions can contribute soluble Fe to the ocean via dry or wet deposition, nearly reaching the limit required for phytoplankton growth. In contrast, the input of Fe after processing by an acidic eruption plume could raise the amount of dissolved Fe in surface ocean waters several times, above the threshold required to initiate phytoplankton blooms. A single eruption like the Puyehue one represents more than half of the yearly Fe flux contributed by dust.

  18. Analysis of noise pollution in an andesite quarry with the use of simulation studies and evaluation indices.

    Kosała, Krzysztof; Stępień, Bartłomiej


    This paper presents the verification of two partial indices proposed for the evaluation of continuous and impulse noise pollution in quarries. These indices, together with the sound power of machines index and the noise hazard index at the workstation, are components of the global index of assessment of noise hazard in the working environment of a quarry. This paper shows the results of acoustic tests carried out in an andesite quarry. Noise generated by machines and from performed blasting works was investigated. On the basis of acoustic measurements carried out in real conditions, the sound power levels of machines and the phenomenon of explosion were determined and, based on the results, three-dimensional models of acoustic noise propagation in the quarry were developed. To assess the degree of noise pollution in the area of the quarry, the continuous and impulse noise indices were used. PMID:26652503

  19. Climate of the last glaciation in New Zealand, based on aerosolic quartz influx in an andesitic terrain

    Alloway, Brent V.; Stewart, Robert B.; Neall, Vincent E.; Vucetich, Colin G.


    On western North Island, New Zealand, a record of climatic change during the last glaciation is preserved in a terrestrial coverbed sequence of dominantly andesitic provenance. Here, a succession of five loess-like Andisol units postdates the global high sea-level stand of oxygen isotope substage 5e (<125,000 yr). Tephra erupted from western and central North Island allow precise chronological correlation of the loess-like units. Aerosolic quartz additions determined by quantitative X-ray diffraction (XRD) record two major peaks that correlate with oxygen isotope stages 2 and 4. The most likely source of quartz-rich dust at these times is the surrounding continental shelf, then exposed by low sea level; however, quartz of Australian provenance may also be represented. This study provides the first confirmation from the terrestrial New Zealand record that rates of atmospherically transported particles increase during glacial stages.

  20. A chilled margin of komatiite and Mg-rich basaltic andesite in the western Bushveld Complex, South Africa

    Maier, W. D.; Barnes, S.-J.; Karykowski, B. T.


    A chill sequence at the base of the Lower Zone of the western Bushveld Complex at Union Section, South Africa, contains aphanitic Mg-rich basaltic andesite and spinifex-textured komatiite. The basaltic andesite has an average composition of 15.2 % MgO, 52.8 % SiO2, 1205 ppm Cr, and 361 ppm Ni, whereas the komatiite has 18.7 % MgO, 1515 ppm Cr, and 410 ppm Ni. Both rock types have very low concentrations of immobile incompatible elements (0.14-0.72 ppm Nb, 7-31 ppm Zr, 0.34-0.69 ppm Th, 0.23-0.27 wt% TiO2), but high PGE contents (19-23 ppb Pt, 15-16 ppb Pd) and Pt/Pd ratios (Pt/Pd 1.4). Strontium and S isotopes show enriched signatures relative to most other Lower Zone rocks. The rocks could represent a ~20 % partial melt of subcontinental lithospheric mantle. This would match the PGE content of the rocks. However, this model is inconsistent with the high SiO2, Fe, and Na2O contents and, in particular, the low K2O, Zr, Hf, Nb, Ta, Th, LREE, Rb, and Ba contents of the rocks. Alternatively, the chills could represent a komatiitic magma derived from the asthenosphere that underwent assimilation of the quartzitic floor accompanied by crystallization of olivine and chromite. This model is consistent with the lithophile elements and the elevated Sr and S isotopic signatures of the rocks. However, in order to account for the high Pt and Pd contents of the magma, the mantle must have been twice as rich in PGE as the current estimate for PUM, possibly due to a component of incompletely equilibrated late veneer.

  1. Geochemical constraints on the origin of Late Mesozoic andesites from the Ningwu basin in the Middle-Lower Yangtze Valley, South China

    Chen, Long; Zheng, Yong-Fei; Zhao, Zi-Fu


    An integrated study of zircon U-Pb ages, Hf-O isotopes, whole-rock major-trace elements and Sr-Nd-Hf isotopes was carried out for Mesozoic andesites from the Ningwu basin in the Middle-Lower Yangtze Valley, South China. The results not only provide insights into the origin of anorogenic magmatism in the Middle-Lower Yangtze Valley but also shed light on the petrogenesis of continental arc andesites in general. The Ningwu andesites are mainly composed of trachyandesite and trachyte, with subordinate of basaltic trachy-andesites. They exhibit variable and low MgO contents of 0.1-3.7 wt.% and low Mg# values of 1.6-51.2, high K2O contents of 2.0-9.9 wt.%. They are characterized by arc-like trace element distribution patterns, with significant enrichment in LILE and LREE but depletion in HFSE. Furthermore, these rocks exhibit relatively enriched whole-rock Sr-Nd-Hf-Pb isotope compositions, with initial 87Sr/86Sr ratios of 0.7050-0.7082, negative εNd(t) values of - 8.1 to - 1.8, and negative εHf(t) values of - 6.7 to 0.4. Zircon U-Pb dating yields consistent ages of 128 ± 2 to 133 ± 2 Ma for magma emplacement through volcanic eruption. The zircon exhibits slightly high δ18O values of 5.7-7.8‰ and variable εHf(t) values of - 5.8 to 0.7. All andesites can be categorized into two groups in view of their distinct geochemical compositions, an integrated interpretation of which allows deciphering of their petrogenesis. Group I andesite was produced by a relatively larger extent of partial melting of a more fertile and enriched mantle source that contains a greater amount of phlogopite, whereas Group II andesite was generated by a relatively smaller extent of partial melting of a less fertile and enriched mantle source that contains a less amount of phlogopite. In either case, these two mantle sources are less ultramafic in lithochemistry than normal mantle peridotite due to its reaction with metasediment-derived hydrous felsic melts. This metasomatism would take place

  2. Potential reactivity of the andesitic rocks from Cabo de Gata (SE Spain); Reactividad potencial de las rocas andesiticas de Cabo de Gata (SE de Espana)

    Soriano, J.; Iglesia, A. la; Garcia Calleja, M. A.; Lopez-Ruiz, J.


    Andesitic rocks produce an alkali-silica reaction with the components of the interstitial phase of concrete. This reaction can be considered as belonging to the slow-kinetic type, since the incongruent dissolution of the rock-forming minerals leads to the late formation of siliceous calc-alkaline gel. As a conquence, the conventional mortar-bar method does not detect such reaction until 90 days later. (Author) 9 refs.

  3. Microtextural and mineral chemical analyses of andesite-dacite from Barren and Narcondam islands: Evidences for magma mixing and petrological implications

    Ray, Dwijesh; Rajan, S.; Ravindra, Rasik; Jana, Ashim


    Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains. In this study, we use the results of mineral chemical analyses of the calc-alkaline rock suite of rocks as proxies for magma mixing and mingling processes. Plagioclase, the most dominant mineral, shows zoning which includes oscillatory, patchy, multiple and repetitive zonation and `fritted' or `sieve' textures. Zoning patterns in plagioclase phenocrysts and abrupt fluctuations in An content record different melt conditions in a dynamic magma chamber. `Fritted' zones (An55) are frequently overgrown by thin calcic (An72) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing processes. We conclude that hybrid magma formed from the mixing of mafic and felsic magma by two-stage processes - initial intrusion of hotter mafic melt (andesitic) followed by cooler acidic melt at later stage.

  4. The role of slab melting in the petrogenesis of high-Mg andesites: evidence from Simbo Volcano, Solomon Islands

    König, S.; Schuth, S.; Münker, C.; Qopoto, C.


    The petrogenesis of high-Mg andesites (HMA) in subduction zones involves shallow melting of refractory mantle sources or, alternatively, the interaction of ascending slab-derived melts with mantle peridotite. To unravel the petrogenesis of HMA, we report major, trace element and Sr-Nd-Hf-Pb isotope data for a newly found occurrence of HMA in the New Georgia group, Solomon Islands, SW-Pacific. Volcanism in the Solomon Islands was initiated by subduction of the Pacific plate beneath the Indian-Australian plate until a reversal of subduction polarity occurred ca. 10 Ma ago. Currently, the Indian-Australian plate is subducted northeastwards along the San Cristobál trench, forming the younger and still active southwestern Solomon island arc. However, a fossil slab of Pacific crust is still present beneath the arc. The edifice of the active volcano Simbo is located directly in the San Cristobál trench on top of the subducting Indian-Australian plate. Simbo Island lies on top of a strike-slip fault of the adjacent Woodlark spreading centre that is subducted beneath the Pacific plate. Geochemical and petrological compositions of volcanic rocks from Simbo are in marked contrast to those of volcanic rocks from islands north of the trench (mostly arc basalts). Simbo-type rocks are opx-bearing HMA, displaying 60-62 wt% SiO2 but rather primitive Mg-Ni-Cr characteristics with 4-6 wt% MgO, up to 65 ppm Ni, up to 264 ppm Cr and Mg# from 67 to 75. The compositions of the Simbo andesites are explained by a binary mixture of silicic and basaltic melts. Relict olivine phenocrysts with Fo88-90 and reaction-rims of opx also support a mixing model. The basaltic endmember is similar to back-arc basalts from the Woodlark Ridge. A slab melt affinity of the silicic mixing component is indicated by Gd(N)/Yb(N) of up to 2.2 that is higher if compared to MORB and other arc basalts from the Solomon Islands. 87Sr/86Sr, ɛNd and ɛHf values in the analysed rocks range from 0.7035 to 0.7040, +6

  5. The Multiphase Rheology of Andesitic Magmas from the 1.9ka Eruption of Turrialba Volcano (Costa Rica)

    Vona, A.; Di Piazza, A.; Romano, C.; De Astis, G.; Soto, G. J.


    We present a study of high-temperature, uniaxial deformation experiments of natural magma from an andesitic eruption of Turrialba volcano (1.9ka Plinian eruption). The aim of this work is to investigate the multiphase rheology (liquid+vesicles+crystals) of natural samples and the effect of vesicles and crystals on the magma viscosity. The experiments were performed using a high-temperature uniaxial Geocomp LoadTrac II press at dry atmospheric conditions and controlled deformation rates. Cores of natural sample (with Φcrys=0.20-0.30 and Φves=0.41-0.58) were deformed isothermally (790-870°C) at variable strain rates (VSR, from 10-6 to 10-4 s-1) and constant strain rate (CSR, 10-5 s-1). VSR were performed at low total amount of strain (eflow behavior of these complex natural materials. The stress-strain rate relationships under flow conditions showed a linear trend between the applied stress and strain rate in the temperature interval investigated. All the samples display a steep linear trend, typical of Newtonian fluids (n index ~ 1), with a very small shear thinning behavior. CSR tests were performed at different total amount of strain (e=0.15-0.25-0.35). Strain hardening was observed with increasing deformation, resulting in an increase of apparent viscosity (up to 100.5 Pa s). This increase is related to the loss of total porosity (up to ΔΦves=0.15) due to compaction of the sample as indicated by post-run analyses . The measured multiphase rheology of Turrialba magmas was compared with literature models for both crystal- and bubble-bearing suspension. We calculate a difference of ~101 Pa s in magma apparent viscosity between high and low density samples, that coupled with a lateral temperature gradient inside the conduit of the volcano, could increase up to ~103 Pa s. The large difference in viscosity could be responsible of significant rheological contrasts, possibly resulting in strain localization and brittle fragmentation of magma.

  6. Storage conditions and evolution of andesitic magma prior to the 1991 95 eruption of Unzen volcano: Constraints from natural samples and phase equilibria experiments

    Botcharnikov, Roman E.; Holtz, Francois; Almeev, Renat R.; Sato, Hiroaki; Behrens, Harald


    The compositions of homogenized melt inclusions trapped in plagioclase (Pl) microphenocrysts (40-200 μm length) from mafic enclaves within dacitic rocks erupted at Unzen volcano in 1991-95 were investigated. The SiO 2 contents of the melt inclusions vary from 58 to 70 wt.% and Pl anorthite content is An 50-70. The stability fields (in terms of temperature and water activity) of natural Pl and coexisting melts from the melt inclusions were estimated from data of phase equilibria experiments performed with a synthetic andesite composition at T = 900-1140 °C, P = 200 MPa, log fO 2 = NNO-2-NNO, and water activity of about 0-1. This composition is representative of the average composition of mafic enclaves from the 1991-95 eruption and nearly identical to the composition of andesitic lavas from 1663 Unzen eruption. The temperatures and H 2O melt concentrations, calculated using the compositions of coexisting Pl and melt inclusions, provide an estimation of the conditions of andesitic magma evolution within the mafic enclaves prior to eruption. The formation of melt inclusions in plagioclase microphenocrysts occurred at a maximum temperature of ~ 1010 ± 35 °C for a melt containing 2 wt.% H 2O and a minimum temperature of ˜ 945 °C ± 30 °C for a melt with ˜ 4 wt.% dissolved H 2O. The compositional range of the melt inclusions indicates that the composition of the mafic enclave was not significantly contaminated by the host magma when inclusions were formed. The difference between concentrations of dissolved S (up to 0.06 wt.%) and Cl (up to 0.05 wt.%) in melt inclusions in Pl of mafic enclaves and concentrations of S (temperature andesitic magma whereas Cl was degassed from the low-temperature silicic magma. The combination of data from melt inclusions and phase equilibria experiments indicates that the mafic end-member magma at Unzen was already partially crystallized and contained significant proportions (20 to 40 wt.%) of Pl and orthopyroxene (Opx) when melt

  7. The challenging retrieval of the displacement field from InSAR data for andesitic stratovolcanoes: Case study of Popocatepetl and Colima Volcano, Mexico

    Pinel, V.; Hooper, A.; De la Cruz-Reyna, S.; Reyes-Davila, G.; Doin, M. P.; Bascou, P.


    Despite the ability of synthetic aperture radar (SAR) interferometry to measure ground motion with high-resolution, application of this remote sensing technique to monitor andesitic stratovolcanoes remains limited. Specific acquisition conditions characterizing andesitic stratovolcanoes, mainly vegetated areas with large elevation ranges, induce low signal coherence as well as strong tropospheric artefacts that result in small signal-to-noise ratio. We propose here a way to mitigate these difficulties and improve the SAR measurements. We derive ground motions for two of the most active Mexican stratovolcanoes: Popocatepetl and Colima Volcano, from the time series of SAR data acquired from December 2002 to August 2006. The SAR data are processed using a method that combines both persistent scatterers and small baseline approaches. Stratified tropospheric delays are estimated for each interferogram using inputs from the global atmospheric model NARR, up to a maximum of 10 rad/km. These delays are validated using spectrometer data, as well as the correlation between the wrapped phase and the elevation. The tropospheric effect is removed from the wrapped phase in order to improve the unwrapping process. On Popocatepetl, we observe no significant deformation. The Colima summit area exhibits a constant subsidence rate of more than 1 cm/year centered on the summit but enhanced (reaching more than 2 cm/year) around the 1998 lava flow. We model this subsidence considering both a deflating magma source at depth and the effect of the eruptive deposits load.

  8. Zircon LA-ICP MS U-Pb Dating of the Longkang Andesitic Ignimbrites from Jiuzhaigou: Evidence of the Mianlue Suture Westward Extension

    Qin Jiangfeng; Lai Shaocong; Zhang Guowei; Diwu Chunrong; Li Yongfei


    Genesis of metasedimentary-volcanics outcroped in Kangxian-Pipasi-Nanping (康县-琵琶寺-南坪) tectonic zone is closely related with tectonic evolution of the Mianlue (勉略) Ocean. In the west end of Kangxian-Pipasi-Nanping tectonic zone, there are hundred meters of andesitic ignimbrites and tuffites. Zircon U-Ph dating on these volcanies has great significance to the tectonic implication of zircons from Longkang andesitic ignimbrites are magmatic genesis with oscillatory zoning and high U ((35-750) ppm), Th ((311-717) ppm) contents with high Th/U (0.44-1.30) ratios. The measured 206pb/238U ratios are in good analytical precision, yielding a weighted mean age of (246±3) Ma (MSWD=2.6, n=12, 2σ). Some detrital zircons have also been observed, they have maximal concordia area. Combined with regional geology and the volcanic rocks in the studied area, the (246±3) Ma zircon U-Pb age suggests a Late Permian orogenic volcanism and provides important geochronology evidence for the Mianlue suture westward extension.

  9. Experimental constraints on the P/T conditions of high silica andesite storage preceding the 2006 eruption of Augustine Volcano, Alaska

    Henton, S.; Larsen, J. F.; Traxler, N.


    We present new experimental results to constrain the P/T storage conditions of the high silica andesite (HSA) prior to the 2006 eruption of Augustine Volcano, Alaska. Augustine Volcano forms a small island located in Alaska’s Cook Inlet, approximately 180 miles southwest of Anchorage. The 2006 eruption began January 11, 2006, and evolved from an initial phase of explosive activity, through continuous and effusive phases, ending approximately mid-March 2006. Lithologies erupted indicate pervasive hybridization between high- (HSA; 62.2-63.3 wt. % SiO2) and low-silica andesite (LSA; 56.6-58.7 wt% SiO2). This study focuses on experiments using the HSA as starting material to constrain magma storage conditions, based on amphibole stability. Experiments were conducted between 100-160 MPa and 800-900 °C, utilzing H2O saturated conditions and fO2 of Re-ReO. Both lightly crushed and sintered HSA were used as starting powders, seeded respectively with 5 wt. % amphibole and a mix of 5 wt. % amphibole and 20 wt. % plagioclase. Experiments with sintered starting material tended toward a bimodal distribution of experimental phenocrysts and microlites, whilst experiments of the lightly crushed material are more phenocryst rich. Preliminary results indicate that amphibole is stable at conditions of 120-140 MPa and 820-840 °C. These pressures correspond with depths of approximately 4.6-5.4 km, which are consistent with prior magma storage models for Augustine 1986 and 2006 magmas, as well as amphiboles found in other arc andesites (e.g., Redoubt and Soufriere Hills volcanoes). Experimental amphiboles are magnesio-hornblendes, which is in keeping with the natural HSA amphiboles. Experimental and natural hornblendes are similar in composition, with the main difference being a small FeO enrichment (2-3 wt%) and MgO depletion (1-2wt%) in the experimental grains. Further work will provide a more complete assessment of amphibole stability and composition, and will be applied towards

  10. Manganese mineralization in andesites of Brestovačka Banja, Serbia: evidence of sea-floor exhalations in the Timok Magmatic Complex

    Pačevski, Aleksandar; Cvetković, Vladica; Šarić, Kristina; Banješević, Miodrag; Hoefer, Heidi Eva; Kremenović, Aleksandar


    Andesites near Brestovačka Banja belong to the Late Cretaceous Timok Magmatic Complex (TMC), which hosts the world-class Bor metallogenic zone including numerous porphyry-copper and epithermal deposits. Two main volcanic phases are recognized in the TMC. The newly discovered Mn mineralization reported here is associated with the second volcanic phase of Turonian-Campanian age. Manganese mineralization containing 58 % MnO on average, occurs as black veins, lumps and nests filling cracks and cavities within an autoclastic andesite, which was deposited in a subaqueous environment. This rock also contains minor Fe mineralization, which is contemporaneous with the manganese mineralization. Manganese mineralization predominantly consists of Mn-Ca silicates (macfallite, pumpellyite-Mn, orientite, bustamite) and Mn oxides (pyrolusite, manganite). Micrometer-scale mineral intergrowths and locally preserved botryoidal and colloform textures are characteristic features of this uncommon mineral assemblage. The features could indicate that the mineralization was formed by deposition from a primary colloidal assemblage and is of sub-marine hydrothermal origin. Orientite is the only Mn mineral with grain size reaching several tenths of micrometers and showing prismatic crystal habit. Scarce to rare associated minerals are hollandite, crednerite, an unknown REE mineral, powellite, pyrite, barite and galena, in decreasing abundance. Trace element analyses of the Mn mineralization show different element contents and REE patterns compared to those of the volcanic host-rock. Manganese mineralization shows relatively high contents of Cu - 1784 ppm, Mo - 20 ppm and As - 268 ppm. These elements are commonly enriched in the Cu deposits of the Bor zone and their relatively high contents in the studied Mn crusts indicate sea-floor hydrothermal vents as a source of the metals.

  11. Manganese mineralization in andesites of Brestovačka Banja, Serbia: evidence of sea-floor exhalations in the Timok Magmatic Complex

    Pačevski, Aleksandar; Cvetković, Vladica; Šarić, Kristina; Banješević, Miodrag; Hoefer, Heidi Eva; Kremenović, Aleksandar


    Andesites near Brestovačka Banja belong to the Late Cretaceous Timok Magmatic Complex (TMC), which hosts the world-class Bor metallogenic zone including numerous porphyry-copper and epithermal deposits. Two main volcanic phases are recognized in the TMC. The newly discovered Mn mineralization reported here is associated with the second volcanic phase of Turonian-Campanian age. Manganese mineralization containing 58 % MnO on average, occurs as black veins, lumps and nests filling cracks and cavities within an autoclastic andesite, which was deposited in a subaqueous environment. This rock also contains minor Fe mineralization, which is contemporaneous with the manganese mineralization. Manganese mineralization predominantly consists of Mn-Ca silicates (macfallite, pumpellyite-Mn, orientite, bustamite) and Mn oxides (pyrolusite, manganite). Micrometer-scale mineral intergrowths and locally preserved botryoidal and colloform textures are characteristic features of this uncommon mineral assemblage. The features could indicate that the mineralization was formed by deposition from a primary colloidal assemblage and is of sub-marine hydrothermal origin. Orientite is the only Mn mineral with grain size reaching several tenths of micrometers and showing prismatic crystal habit. Scarce to rare associated minerals are hollandite, crednerite, an unknown REE mineral, powellite, pyrite, barite and galena, in decreasing abundance. Trace element analyses of the Mn mineralization show different element contents and REE patterns compared to those of the volcanic host-rock. Manganese mineralization shows relatively high contents of Cu - 1784 ppm, Mo - 20 ppm and As - 268 ppm. These elements are commonly enriched in the Cu deposits of the Bor zone and their relatively high contents in the studied Mn crusts indicate sea-floor hydrothermal vents as a source of the metals.

  12. Using mineral geochemistry to decipher slab, mantle, and crustal inputs to the generation of high-Mg andesites from Mount Baker and Glacier Peak, northern Cascade arc

    Sas, M.; DeBari, S. M.; Clynne, M. A.; Rusk, B. G.


    A fundamental question in geology is whether subducting plates get hot enough to generate melt that contributes to magmatic output in volcanic arcs. Because the subducting plate beneath the Cascade arc is relatively young and hot, slab melt generation is considered possible. To better understand the role of slab melt in north Cascades magmas, this study focused on petrogenesis of high-Mg andesites (HMA) and basaltic andesites (HMBA) from Mt. Baker and Glacier Peak, Washington. HMA have unusually high Mg# relative to their SiO2 contents, as well as elevated La/Yb and Dy/Yb ratios that are interpreted to result from separation of melt from a garnet-bearing residuum. Debate centers on the garnet's origin as it could be present in mineral assemblages from the subducting slab, deep mantle, thick lower crust, or basalt fractionated at high pressure. Whole rock analyses were combined with major, minor, and trace element analyses to understand the origin of these HMA. In the Tarn Plateau (Mt. Baker) flow unit (51.8-54.0 wt.% SiO2, Mg# 68-70) Mg#s correlate positively with high La/Yb in clinopyroxene equilibrium liquids, suggesting an origin similar to that of Aleutian adakites, where slab-derived melts interact with the overlying mantle to become Mg-rich and subsequently mix with mantle-derived basalts. The source for high La/Yb in the Glacier Creek (Mt. Baker) flow unit (58.3-58.7 wt.% SiO2, Mg# 63-64) is more ambiguous. High whole rock Sr/P imply origin from a mantle that was hydrated by an enriched slab component (fluid ± melt). In the Lightning Creek (Glacier Peak) flow unit (54.8-57.9 SiO2, Mg# 69-72) Cr and Mg contents in Cr-spinel and olivine pairs suggest a depleted mantle source, and high whole rock Sr/P indicate hydration-induced mantle melting. Hence Lightning Creek is interpreted have originated from a refractory mantle source that interacted with a hydrous slab component (fluid ± melt). Our results indicate that in addition to slab-derived fluids, slab

  13. Early Silurian (~ 440 Ma) adakitic, andesitic and Nb-enriched basaltic lavas in the southern Altay Range, Northern Xinjiang (western China): Slab melting and implications for crustal growth in the Central Asian Orogenic Belt

    Shen, Xiao-Ming; Zhang, Hai-Xiang; Wang, Qiang; Ma, Lin; Yang, Yue-Heng


    As an important part of the Central Asian Orogenic Belt (CAOB), the Altay Range contains large-scale Paleozoic magmatic rocks. However, owing to the lack of precise age constraints, the tectonic setting and petrogenesis of the magmatic rocks in this area have been controversial, which has led to the debate on Phanerozoic crustal growth mechanisms and accretionary orogenic processes in the CAOB. Herein, we report geochronological and geochemical data of the Suoerkuduke adakitic, andesitic and Nb-enriched basaltic (NEB) lavas in the southern margin of the southern Altay Range. LA-ICP-MS zircon U-Pb analyses for five adakitic, andesitic and NEB samples indicate that they were coevally generated in the Early Silurian (~ 440 Ma). The adakites and basaltic andesites are geochemically characterized by high Na2O/K2O, Sr/Y, Al2O3, Sr, εNd(t) and zircon εHf(t) values and relatively low (87Sr/86Sr)i ratios. The NEBs are sodium-rich and have higher TiO2, P2O5, Zr, Nb, and Nb/U values than those of typical arc basalts. They also have positive εNd(t) values and positive and variable zircon εHf(t) values. We suggest that the Suoerkuduke adakites were derived by a partial melting of the subducted oceanic crust with minor overlying sediments, and the continuous compositional variations between adakites and basaltic andesites confirm that the interaction between slab melts and mantle peridotite played an important role in the formation of basaltic andesites. The associated NEBs were possibly generated by a partial melting of mantle wedge peridotites metasomatized by slab-derived adakitic melts and minor fluids. In combination with the occurrence of voluminous Silurian-Devonian granitoids, coeval ophiolite mélanges, and a series of intra-arc basins, a slab window model triggered by slab tearing is proposed to account for the formation of the Suoerkuduke adakite-basaltic andesite-NEB suites. The upwelling of the asthenospheric mantle through the slab window probably caused

  14. Extremely high-Na adakite-like magmas derived from alkali-rich basaltic underplate. The late cretaceous Zhantang andesites in the Huichang Basin, SE China

    The Zhantang andesites, which erupted in the Late Cretaceous Huichang Basin of SE China interior, were associated the the Late Mesozoic lithospheric extension and basaltic underplating. They are high-Na(6.59-8.46 wt% Na2O), high-Al trondhjemitic rocks with high Sr and Ba, low Y and HREE, and high Sr/Y and La/Yb ratios, similar to modern adakites. However, they are much higher in Na2O but lower in CaO than adakites. Their εNd(T) values of -2.3 to -3.8 and initial 87Sr/86Sr ratios of 0.707 to 0.708 are also significantly different from those of adakites with MORB-like isotopic compositions. These chemical and isotopic features, along with the tectonic setting, suggest that they were not produced by partial melting of subducting slab. The Zhantang adakite-like magmas may be derived from underplated basaltic lower crust, but require a compositionally peculiar basaltic protolith to account for their extremely high-Na and low-Ca feature. They are compositionally comparable to the experimentally produced partial melts of alkali-rich basalt. We therefore interpret them as the products of melting of an alkali-rich basaltic rock. (author)

  15. Extremely high-Na adakite-like magmas derived from alkali-rich basaltic underplate. The late cretaceous Zhantang andesites in the Huichang Basin, SE China

    Xiong Xiaolin; Li Xianhua; Xu Jifeng; Li wuxian; Zhao Zhenhua; Wang Qiang [Chinese Academy of Sciences (China). Guangzhou Institute of Geochemistry; Chen Xiaoming [Nanjing Univ. (China). State Key Laboratory of Mineral Deposit Research


    The Zhantang andesites, which erupted in the Late Cretaceous Huichang Basin of SE China interior, were associated the the Late Mesozoic lithospheric extension and basaltic underplating. They are high-Na(6.59-8.46 wt% Na{sub 2}O), high-Al trondhjemitic rocks with high Sr and Ba, low Y and HREE, and high Sr/Y and La/Yb ratios, similar to modern adakites. However, they are much higher in Na{sub 2}O but lower in CaO than adakites. Their {epsilon}Nd(T) values of -2.3 to -3.8 and initial {sup 87}Sr/{sup 86}Sr ratios of 0.707 to 0.708 are also significantly different from those of adakites with MORB-like isotopic compositions. These chemical and isotopic features, along with the tectonic setting, suggest that they were not produced by partial melting of subducting slab. The Zhantang adakite-like magmas may be derived from underplated basaltic lower crust, but require a compositionally peculiar basaltic protolith to account for their extremely high-Na and low-Ca feature. They are compositionally comparable to the experimentally produced partial melts of alkali-rich basalt. We therefore interpret them as the products of melting of an alkali-rich basaltic rock. (author)

  16. Mantle peridotite xenoliths in andesite lava at El Peñon, central Mexican Volcanic Belt: Isotopic and trace element evidence for melting and metasomatism in the mantle wedge beneath an active arc

    Mukasa, Samuel B.; Blatter, Dawnika L.; Andronikov, Alexandre V.


    Peridotites in the mantle wedge and components added to them from the subducting slab are thought to be the source of most arc magmas. However, direct sampling of these materials, which provides a glimpse into the upper mantle beneath an active margin, is exceedingly rare. In the few arc localities where found, peridotite xenoliths are usually brought to the surface by basaltic magmas. Remarkably, the hornblende-bearing ultramafic xenoliths and clinopyroxene megaxenocrysts from El Peñon in the central Mexican Volcanic Belt were brought to the surface by a Quaternary high-Mg siliceous andesite, a rock type usually considered too evolved to be a direct product of mantle melting. The xenoliths and megaxenocrysts from El Peñon represent lithospheric mantle affected by significant subduction of oceanic lithosphere since as early as the Permian. Trace element and radiogenic isotope data we report here on these materials suggest a history of depletion by melt extraction, metasomatism involving a fluid phase, and finally, limited reaction between the ultramafic materials and the host andesite, probably during transport. They also show that high-Mg siliceous andesite can be a direct product of 1-5% melting of H 2O-bearing spinel lherzolite.

  17. Repeated magmatism at 34 Ma and 23-20 Ma producing high magnesian adakitic andesites and transitional basalts on southern Okushiri Island, NE Japan arc

    Sato, Makoto; Shuto, Kenji; Nohara-Imanaka, Rikako; Takazawa, Eiichi; Osanai, Yasuhito; Nakano, Nobuhiko


    The southern part of Okushiri Island in the present-day back-arc margin of the NE Japan arc is one of the rare convergent plate boundaries where similar magma types (high-magnesian adakitic andesite (HMAA) and high-TiO2 basalt (HTB)) have been erupted concurrently at more than one time. Oligocene HMAA can be divided into two types: HMAA-I is characterized by high Sr/Y and low Y, and HMAA-II by relatively low Sr/Y and high Y. HMAA-I is primitive in terms of MgO (8.5 wt.%), Mg# (67), Ni (232 ppm) and Cr (613 ppm) contents, and the most Mg-rich olivine phenocrysts plot within the mantle olivine array in terms of Fo and NiO. The similar Cr versus Ni relations of types I and II HMAA indicate some interaction of slab-derived adakitic melts with mantle peridotite, whereas Ni contents are higher than those of most boninites derived by partial melting of mantle peridotite at a given Cr content. Types I and II HMAA have more enriched Sr and Nd isotopic compositions than N-MORB. The petrography and geochemistry of these rocks, combined with published results on the genesis of high-magnesian andesite (HMA) indicate that types I and II HMAA could be produced by interaction of slab (N-MORB and sediment)-derived adakitic melts with mantle peridotite. The comagmatism of HMAA and HTB is ascribed to the following model. A cool, less hydrous, adakite magma (spherical diapir) would rise from the subducting slab (Pacific Plate) and become more hydrous as a result of its interaction with overlying hydrous peridotite. This hydrated adakitic diapir further ascends and is heated on entering the overlying mantle wedge. Subsequently, the temperature and H2O gradients in the ascending adakitic diapir and surrounding mantle peridotite would have been established. The HTB magma segregated from the surrounding mantle peridotite region (high temperature and low H2O content) at a depth of 60 km or more, whereas the adakitic diapir (low temperature and high H2O content) continued to rise, with its

  18. Effect of fO2 on phase relationship in basaltic andesites during magmatic differentiation: Control of fO2 and sulphur speciation in piston cylinder experiments.

    Matjuschkin, Vladimir; Tattitch, Brian; Blundy, Jonathan D.; Skora, Susanne


    Within the mantle wedge above subduction zones, oxidation reaction take place by interaction of reduced mantle rocks with more oxidized, hydrous fluids, which can cause a local drop of the solidus, resulting in partial melting (2,6,7). The resultant melts are more oxidized that their ocean floor counterparts, which has implications for their subsequent differentiation paths, the speciation of multivalent elements and the solubility and transport of chemical compounds in magmatic systems (1,4,5). We present a series of sulphur-doped high-pressure experiments conducted to investigate the effect of oxygen fugacity on phase relationships and the behaviour of sulphur in silicate melts. Natural aphyric andesite (FM37) erupted from Laguna del Maule volcano, Chile (3) was selected as a starting composition. Experiments were carried out at 5kbar, 950-1150° C and variable oxygen fugacity conditions. New experiments buffered at Co-CoO and Ni-NiO buffer conditions have been performed using a new "MTB capsule design" developed in order to accurately control fO2 by means of a double capsule containing metal-oxide buffers and a pyrex sleeve to minimise H2 diffusion. This new design constrains oxygen fugacity to within ±0.1-0.2logfO2 units of the target value. Before conducting these experiments, the assemblage was tested multiple times at 10kbar, 1000° C over 24-48 hours and demonstrated consistent, accurate fO2 control. Analyses of the preliminary experimental run products, from a related Chilean basaltic andesite starting composition, demonstrate a clear effect of fO2 on phase relationships and the proportion of melt generated during experiments. Under oxidized conditions, as temperature decreased from 1150° C to 1050° C, the amount of melt decreased from 100% to ~80%, due to the formation of orthopyroxene, anhydrite and plagioclase. In contrast, in reduced runs the system remains nearly liquid (~5% crystals) down to 950° C due to the change in sulphur speciation and

  19. High-K andesite petrogenesis and crustal evolution: Evidence from mafic and ultramafic xenoliths, Egmont Volcano (Mt. Taranaki) and comparisons with Ruapehu Volcano, North Island, New Zealand

    Price, Richard C.; Smith, Ian E. M.; Stewart, Robert B.; Gamble, John A.; Gruender, Kerstin; Maas, Roland


    This study uses the geochemistry and petrology of xenoliths to constrain the evolutionary pathways of host magmas at two adjacent andesitic volcanoes in New Zealand's North Island. Egmont (Mt. Taranaki) is located on the west coast of the North Island and Ruapehu lies 140 km to the east at the southern end of the Taupo Volcanic Zone, the principal locus of subduction-related magmatism in New Zealand. Xenoliths are common in the eruptives of both volcanoes but the xenoliths suites are petrographically and geochemically different. Ruapehu xenoliths are predominantly pyroxene-plagioclase granulites derived from Mesozoic meta-greywacke basement and the underlying oceanic crust. The xenolith population of Egmont Volcano is more complex. It includes sedimentary, metamorphic and plutonic rocks from the underlying basement but is dominated by coarse grained, mafic and ultramafic igneous rocks. Gabbroic xenoliths (Group 1) are composed of plagioclase, clinopyroxene and amphibole whereas ultramafic xenoliths are dominated by amphibole (Group 2) or pyroxene (Group 3) or, in very rare cases, olivine (Group 4). In Group 1 xenoliths plagioclase and clinopyroxene and in some cases amphibole show cumulate textures. Amphibole also occurs as intercumulate poikilitic crystals or as blebs or laminae replacing pyroxene. Some Group 2 xenoliths have cumulate textures but near monomineralic amphibole xenoliths are coarse grained with bladed or comb textures. Pyroxene in Group 3 xenoliths has a polygonal granoblastic texture that is commonly overprinted by veining and amphibole replacement. Group 1 and most Group 2 xenoliths have major, trace element and Sr, Nd and Pb isotope compositions indicating affinity with the host volcanic rocks. Geochemical variation can be modelled by assimilation fractional crystallisation (AFC) and fractional crystallisation (FC) of basaltic parents assuming an assimilant with the composition of average crystalline basement and Group 1 xenoliths have

  20. Etude de l’activité pouzzolanique d’une roche andésitique en Algérie Study of the pozzolanic activity of an andesitic rock in Algeria

    Clastres P.


    Full Text Available Ce travail s’inscrit dans le cadre de l’accord programme Tassili N° 09 MDU 773 entre le Laboratoire de Physicochimie des Matériaux, USTO-Oran et le Laboratoire des Matériaux et Durabilité des Constructions (LMDC, INSA-UPS-Toulouse, France. La présente étude est une contribution aux travaux de la recherche de nouvelles sources d’approvisionnement en ajouts et en matières premières et la valorisation des matériaux naturels locaux utilisés dans la fabrication du ciment. Cette étude porte sur l’activité pouzzolanique des roches volcaniques, elle a pour but de comparer les caractéristiques physiques et mécaniques d’un mortier témoin à ciment de type CEMI 52,5R fourni par la firme Lafarge et d’un mortier à ciment du même type avec ajout dont les taux de substitution de la roche Andésitique est de 0- 40%. Dans notre travail, nous avons utilisé des roches volcaniques appartenant à la famille des Andésites, provenant de la région de Tipaza, Nord Ouest Algérois. L’étude des caractéristiques mécaniques et de l’indice de pouzzolanicité ont montré que les ciments fabriqués sont capables de remplacer certains ciments Portland pour une éventuelle utilisation dans le domaine de construction. This work is a part of the agreement programs Tassili N° 09 MDU 773 between Laboratory of Physic-chemistry Materials, USTO-Oran and Laboratory of Materials and Durability of Constructions (LMDC, INSA-UPS-Toulouse, France. The present study is an attempt to the research of new supply sources in admixtures and raw materials and the evaluation of local natural materials used in the manufacture of cement. It deals with the pozzolanic activity of the volcanic rocks and aims to compare the physical and mechanical characteristics of a mortar control made with cement CEMI 52,5R provided by Lafarge firm and of a mortar made with the same cement incorporated by different replacement rate of andesitic rock in a range of 0 – 40

  1. Mid infrared throughput with 5 mu m aperture for H sub 2 O determination of an andesitic glass. Comparison of synchrotron radiation source at SPring-8 with conventional light sources

    Kawamoto, T; Kagi, H; Handa, T; Yamashita, S; Ikemoto, Y; Moriwaki, T; Kimura, H


    Mid infrared throughput using 5 mu m apertures was investigate using micro-FTIR spectrometers with conventional light sources at two laboratories and the synchrotron radiation infrared (SR-IR) light source at SPring-8. With both the light sources micro-FTIR microscopy can analyze the fundamental O-H vibration in andesitic glass with 1 weight % H sub 2 O through 5 mu m apertures. Spectra obtained at SPring-8 show better relative standard deviations due to the brighter and more highly collimated nature of SR-IR compared to conventional light sources. The spectra with 100 and 1000 scans at SPring-8 have similar relative standard deviations to those with 1000 and 10200 scans, respectively, at laboratories. The successful analysis with 5 mu m apertures using both light sources shows the potential for an improvement in the spatial resolution of micro-FTIR analyses. (author)

  2. Late Permian high-Mg andesite and basalt association from northern Liaoning, North China: Insights into the final closure of the Paleo-Asian ocean and the orogen-craton boundary

    Yuan, Lingling; Zhang, Xiaohui; Xue, Fuhong; Lu, Yinghuai; Zong, Keqing


    High-Mg andesites (HMAs) and related basalts constitute a volumetrically minor, but genetically important occurrence along most convergent plate margins of various ages on Earth. The details of their petrogenesis can contain critical information for resolving essential geodynamic and crustal evolutionary issues. This zircon U-Pb dating and geochemical study documents the late Permian metamorphosed high-Mg basaltic to andesitic suite from Kaiyuan of northern Liaoning, North China. These rocks feature SiO2 contents ranging from 48.7 to 63.2 wt.%, high Mg# values of 63-75, an enrichment in large-ion lithophile elements (LILE), and depletion in high field strength elements (HFSE). They possess whole-rock initial 87Sr/86Sr ratios of 0.70417-0.70457, εNd(t) values from - 0.4 to 5.0, and εHf(t) values from 5.1 to 11, as well as zircon εHf(t) values from - 9.4 to 0.4. These features indicate that their petrogenesis most likely involved precursory metasomatism of mantle peridotites by melts from subduction-related sediments, and subsequent partial melting. With a depleted mantle source and possible tectonic link to post-subduction slab break-off, the Kaiyuan suite could present a spatial reference not only for defining the demarcation line between the North China craton (NCC) and the Central Asian Orogenic belt (CAOB) in the region, but also for tracing the final location of the cryptic suturing zone of the Paleo-Asian Ocean. Synthesizing the suite with coeval igneous episodes as well as concomitant metamorphic events along the Solonker-Xra Moron-Changchun zone leads to the characterization of the eventual closure of the Paleo-Asian Ocean within a double-sided subduction system during late Permian-Early Triassic.

  3. Geochemical Evidence from the Kohistan Complex for Differentiation of Garnet Granulitic lower Crust in Island Arcs by Dehydration Melting of Amphibole-bearing Plutonics: Implications for the Andesite Model of Continental Crustal Growth

    Garrido, C. J.; Bodinier, J.; Burg, J.; Zeilinger, G.; Hussain, S. S.; Dawood, H.; Gervilla, F.


    We report a geochemical study of the Jijal and Sarangar complexes constituting the lower crust of the Mesozoic Kohistan paleo-island arc (N. Pakistan). The Jijal complex is composed of basal peridotites topped by a gabbroic section made up of mafic garnet granulite-with minor lenses of garnet hornblendite and granite-grading up section to hornblende gabbronorite. The Sarangar complex is constituted by metagabbro. Sarangar gabbro and Jijal hornblende gabbronorite have melt-like, LREE-enriched REE patterns similar to those of island arc basalts. These rocks and Jijal garnet granulite define altogether negative covariations of LaN, YbN and (La/Sm)N with Eu* (=2xEuN/SmN+GdN; N= chondrite normalized), and positive covariations of (Yb/Gd)N with Eu*. REE modeling indicates that these covariations cannot be accounted for by high-pressure crystal fractionation of hydrous primitive or derivative andesites. They are consistent with formation of garnet granulites as plagioclase-garnet assemblages with variable trapped melt fractions via either high-pressure crystallization of primitive island arc basalts or dehydration melting of hornblende gabbronorite, providing that the amount of segregated or restitic garnet was low (hornblende gabbronorite. Similarly, Jijal garnet-bearing hornblendite lenses were most likely generated by coeval dehydration melting of hornblendites. Furthermore, melting models and geochronological data point to intrusive leucogranites in the overlying Metaplutonic complex as the melts generated by dehydration melting of the plutonic protoliths of Jijal garnet-bearing restites. Consistently with the metamorphic evolution of the Kohistan lower arc crust, dehydration melting occurred at the mature stage of this island arc when shallower hornblende-bearing plutonics were buried to depth exceeding 25-30 km and heated at temperatures above ca. 900 oC. Available experimental data on dehydration melting of amphibolitic sources imply that thickening of oceanic arcs

  4. Devonian Nb-enriched basalts and andesites of north-central Tibet: Evidence for the early subduction of the Paleo-Tethyan oceanic crust beneath the North Qiangtang Block

    Zhang, Hongrui; Yang, Tiannan; Hou, Zengqian; Bian, Yeke


    The early evolution of the Tethyan Ocean in north-central Tibet is currently poorly constrained. A sequence of volcanic rocks ranging from basic to intermediate in composition has been identified in the Zaduo area of the North Qiangtang Block. SHRIMP U-Pb dating of zircons from a sample of Zaduo andesite suggests an eruption age of Late Devonian (~ 380 Ma). The Zaduo volcanic rocks exhibit geochemical characteristics similar to those of typical Nb-enriched basalts, with relatively high Nb, Ta, and Zr contents, resulting in high Nb/La ratios (0.70-1.08) and Nb/U ratios (10.57-34.37). The relative enrichment in high field strength elements, together with positive εNd(t) values of + 4.6 to + 5.8 and low (87Sr/86Sr)i ratios of 0.70367-0.70532, indicates the Zaduo volcanic rocks were derived from a depleted mantle source metasomatized by silicate melts of a subducted oceanic slab. The occurrence of Nb-enriched volcanic rocks in the North Qiangtang Block suggests that the subduction of Paleo-Tethyan oceanic crust was initiated in the Late Devonian. Available geochronological data from ophiolites surrounding the North Qiangtang Block suggest that the subducted slab is most likely the Longmucuo-Shuanghu Paleo-Tethyan oceanic crust.

  5. Geochemistry, age and strontium isotope composition of late tertiary and quaternary basalts and andesites in western Nevada and their relation to geothermal potential. Final report, October 1, 1982-December 31, 1983

    Fultz, L.A.; Bell, E.J.; Trexler, D.T.


    This research was undertaken to characterize the late Cenozoic volcanic rocks associated with active geothermal systems in west-central Nevada. Petrographic and microprobe, geochemical and isotopic analysis and age dating techniques were used to characterize these young volcanic rocks. These data were combined with the limited data previously reported in the literature on these same volcanic areas to interpret their petrogenesis. The overall characterization resulted from integrating the petrogenesis with a structural-tectonic model of the region. Potassium-argon isotopic ages ranging up to 14 million years were determined for eight localities within the Reno 1 x 2/sup 0/ study region. These ages are consistent with the morphology of the volcanic landforms, the active geothermal systems associated with them, and with other isotopic ages reported in the literature for these and similar rocks within the study region. Petrographic analysis of hand specimens and thin-sections indicated mineralogic assemblages of the respective rock types and specific mineral textures and phenocryst compositions and characteristics. These identifications were further substantiated by microprobe analysis of selected phenocrysts and groundmass phases. Classification of the respective rock types was also based on chemical composition and normative calculations using the program PETCAL. Basaltic andesites are identified and described for Steamboat Hills, Table Mountain, Silver Springs, Churchill Butte, Cleaver Peak, Desert Peak and Carson City sites.

  6. Andesita Cerro Bola: Nueva unidad vinculada al magmatismo mioceno de la Cordillera de Olivares, San Juan, Argentina (30°35´S; 69°30´O Cerro Bola Andesite: New unit linked to the Miocene magmatism of the Olivares Cordillera, San Juan (30°35' S ; 68°30' W

    A.F. Wetten


    properly in the regional stratigraphic context. The main outcrops were recognized in the Bola Hill and surroundings, where they are irregularly distributed, covering an area greater than 5 km². Dome and lava flow structures are present with the light gray andesite - phenoandesite rock. These outcrops can be correlated with the Pircas volcanic unit (Miocene, to the west, and could be further related to other porphyry bodies of different composition, situated both in Chita Creek and in Divisadero Hill. The extension of the area, lithological uniformity, the low alteration and a K/Ar radiometric age were considered, in order to propose these subvolcanic and volcanic bodies as a new lithostratigraphic unit, Upper Miocene in age, denominated "Cerro Bola Andesite".

  7. Licancabur, an andesitic volcano of the South-central Andes

    Figueroa A., O.; Déruelle, B.


    Le volcan Licancabur est un cône presque parfait, essentiellemnt constitué de coulées d'andésites à phénocristaux de plagioclase (An 78-52), clionopyroxène, orthopyroxène (En 78) et Ti-magnétite, rarement d'olivine, Mg-hornblende et ilménite. Les laves du cône seraient issues du mélange entre, d'une part, les magmas ayant engendré les coulées anciennes et, d'autre part, l'unique dacite reconnue. (Résumé d'auteur)

  8. Groundwater circulations within a tropical humid andesitic volcanic watershed using the temperature as a tracer

    Selles, Adrien; Violette, Sophie; Hendrayana, Heru


    Groundwater flow within volcano-detritic environment, is of prime importance to many human needs and activities, from the supply of clean drinking water to the extraction of hydrocarbons or geothermal energy. However, the heterogeneity of the geological formations makes difficult to quantify the groundwater spatial distribution. Moreover, its temporal variation in tropical humid regions is sometimes poorly known. For instance, the surronding of the Merapi volcano, in Central Java, Indonesia, is an area of high but seasonal rainfall, and extensive crop irrigation. It has a large population and a need to increase food and potable water supplies depending upon exploiting groundwater ressources. The stress on these resources increases with the intensification of the demography, the agricultural practices and the industrial exploitations. In order to implement a sustainable management of the water resources, the description of the groundwater circulations and the quantification of the resources is needed. A mutidisciplinary approach has been performed at the watershed scale, including geology, hydrogeochemistry and long term hydrogeological monitoring. The data synthesis and constisency have been confirm with a numerical model of physical processes. Based on a geological and geomorphological study, the hydrogeological watershed on the Eastern flank of the Merapi volcano is composed by an alternation of aquitards (mainly ashes, tuffs and clay) and aquifers (sand, gravel and boulders). The deep aquifers are agenced in conduit following the burried channel of the paleo-rivers. The eastern flank of Merapi provides excellent example of a volcanic-sedimentary environment. From 20 cold springs of 3 spring zones, sampled on 2 hydrological years (2011 to 2013), the study of the transfer into the saturated zone from upstream to downstream, given the geological context and topography, allows to estimate the role of supply from high and low altitudes to the recharge processes. The water temperature has been used as a tracer to understand the pattern of groundwater flow and to determine the mean recharge elevation for springs. Inferences from standard oxygen and hydrogen isotopic measurements are compared with temperature measurements made at the springs to confirm the recharge elevation estimation and whether groundwater circulates to shallow or deeper depths. The METIS model, coupling groundwater flow and heat transport simulations in 2D steady flow regime, has been used in order to confirm the findings of the temperature and mean flow rate analysis and to characterize the regional flow of the multi-layered aquifer system. This approach provides methodological insights into characterization of the groundwater pathway within complex porous media in tropical humid regions. This study enable us to provide guidance on the required level of model complexity as well as on the amount and type of observations data required.

  9. Posteruptive impacts of pyroclastic deposits from basaltic andesite stratovolcanoes on surface water composition

    Genareau, K.; Cronin, S. J.; Stewart, C.; Bhattacharyya, S.; Donahoe, R.


    Volcanic ash deposition following explosive eruptions can pose significant hazards for water quality, human health, agriculture, and infrastructure functionality. Many studies have examined how fresh ash deposition may lower the pH of, and introduce a range of potentially toxic elements into, exposed surface waters. However, no study has yet determined the effects on water composition as a result of mechanical pyroclast disaggregation and production of new fresh particle surfaces and increasingly fine grained particles. Such disaggregation could result from natural posteruptive processes such as debris avalanches, lahars, or fluvial/aeolian transport and human activities such as cleanup efforts or mining of pyroclastic deposits. The posteruption time scales of pyroclast disaggregation may vary from months in moist tropical or temperate environments to years or decades in arid settings. Here we show, for the first time in experimental studies, that mechanical milling of pyroclasts will introduce a range of elements into exposed waters, including Al, which can be toxic at elevated levels, and Na, which increases the electrical conductivity of solutions. The pH of leaching solutions also increases by several log units. Such dramatic changes on the experimental scale may have implications for surface water composition in posteruptive settings, necessitating longer-term risk assessments for ecosystem health and consideration of the role of pyroclastic deposits in element cycling in volcanically active regions.

  10. Sulfur Metabolizing Microbes Dominate Microbial Communities in Andesite-Hosted Shallow-Sea Hydrothermal Systems

    Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi


    To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan’s coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaea...

  11. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

    Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi


    To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4)) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4) was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4) concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan. PMID:22970260

  12. Wastewater Phosphorus Removal by Two Different Types of Andesitic Volcanic Tephra

    Liesch, Amanda M.


    Phosphorus (P) is the limiting nutrient controlling productivity in most inland freshwater systems. Several materials have been proposed for use to remove excess P from wastewater treatment, including volcanic lapilli and ash (tephra). There is limited data in using tephra as a P filter. There were two objectives of this study: (1) to determine…

  13. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

    Yao Zhang

    Full Text Available To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4 concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  14. New insights into the evolution of the magmatic system of a composite andesite volcano revealed by clasts from distal mass-flow deposits: Ruapehu volcano, New Zealand

    Tost, M.; Price, R. C.; Cronin, S. J.; Smith, I. E. M.


    Stratovolcanoes characteristically build large composite edifices over long periods with stacked lavas intercalated with pyroclastic deposits. In most cases, only the most recent volcanic products are exposed on the flanks of the volcano, and consequently the search for deposits recording an older eruptive and magmatic history is typically focussed far from the cone, within distal tephra deposits. Clasts within lahar and debris avalanche deposits may also provide unique insights into the earliest eruptive and magmatic history of long-lived volcanoes, especially when widespread fallout is absent. Careful sampling and subsequent petrological and geochemical analyses of lava and pumice clasts from six distal mass-flow deposit sequences (hyperconcentrated flow, debris flows and debris avalanche deposits) from Mt. Ruapehu (New Zealand), combined with detailed stratigraphic studies and radiometric age dating, give new perspectives on the pre-50 ka magmatic system of this complex volcano. A conglomerate emplaced between 340 and 310 ka contains evidence for the oldest episode of Mt. Ruapehu volcanism, and unusually for the composite cone, pumice clasts from this unit contain amphibole-bearing xenoliths. Chemical and petrological data for these oldest Ruapehu clasts indicate that a deep (˜40 km) crustal storage system had already developed under Mt. Ruapehu before ˜340 ka. From the very earliest stages, evolution was largely controlled by magma mixing, along with decoupled assimilation and fractional crystallization within numerous isolated small-scale magma batches stored throughout the crust. From around 340 to 160 ka, there was a progressive shift towards more primitive compositions, suggesting that during this period large-scale replenishment events involving mantle-derived basaltic magmas occurred within the mid- to upper crustal storage system. Subsequent magmas became progressively more evolved due to decoupled fractional crystallization and assimilation processes accompanied by magma recharge events, which triggered major phases of eruptive activity.

  15. The effect of kauri (Agathis australis) on grain size distribution and clay mineralogy of andesitic soils in the Waitakere Ranges, New Zealand

    Jongkind, A.G.; Buurman, P.


    Kauri (Agathis australis) is generally associated with intense podzolisation, but little research has been carried out to substantiate this. We studied soil profiles, grain size distribution patterns and clay mineralogy under kauri and broadleaf/tree fern vegetation in the Waitakere Ranges, North Is

  16. Potassium-argon geochronology of a basalt-andesite-dacite arc system: the Mount Adams volcanic field, Cascade Range of southern Washington

    Hildreth, W.; Lanphere, M.A.


    High-precision K-Ar dating and detailed mapping have established an eruptive chronology for a Cascade stratovolcano and its surrounding array of coeval basaltic centers. The time-volume-composition data bear upon several fundamental questions concerning the long-term behavior of arc volcanoes. -from Authors

  17. Evolution of the late Pleistocene Mojanda-Fuya Fuya volcanic complex (Ecuador), by progressive adakitic involvement in mantle magma sources

    Robin, Claude; Eissen, Jean-Philippe; Samaniego, Pablo; Martin, H; Hall, M; Cotten, J.


    The Mojanda-Fuya Fuya Volcanic Complex consists of two nearby volcanoes, Mojanda and Fuya Fuya. The older one, Mojanda volcano (0.6 to 0.2 Ma), was first constructed by andesites and high-silica andesites forming a large stratovolcano (Lower Mojanda). This edifice was capped by a basaltic andesite and andesitic cone (Upper Mojanda), which collapsed later to form a 3-km-wide summit caldera, after large phreatomagmatic eruptions. The Lower Fuya Fuya edifice was constructed by the extrusion of v...

  18. Research on isotope geology: Isotopes ages of volcanic rocks from Ryeongnam Massif, Korea

    Shin, Seong Cheon; Chi, Se Jung; Kim, Yoo Sook [Korea Institute of Geology Mining and Materials, Taejon (Korea, Republic of)


    Chronostratigraphy of most volcanic rocks in the Ryeongnam Massif have been undefined or mis-classified in different geological maps due to total absence of reported isotope ages. Twenty-four new isotope ages are given for age-undefined volcanic units and some related igneous bodies. Most of volcanic rocks show high [La/Yb]n ratios and LREE enrichments which are characteristics of subduction-related high-K calc-alkali volcanic rocks occurred in the active continental margin. Preliminary results on carbon and oxygen stable isotope ratios({delta}{sup 13}C=-1.7{approx}-6.2 per mil; {delta}{sup 18} O=-21.6{approx}-24.7 per mil) of druse- or phenocryst-calcite from andesitic and basaltic rocks in the southern coastal region indicate a magmatic origin. Based on new K-Ar whole-rock ages, chronological guidelines are established as follows: 1) Gayasan andesite (78{+-}4Ma) - Gurye andesitic tuff (81{+-}4Ma); 2) Gurye andesite (68{+-}4Ma) - Suncheon andesitic tuff (67{+-}3Ma) - Yeosu basaltic andesite (67{+-}3Ma) - Narodo andesite (70{+-}3Ma); 3) Taebaeg Baegbyeongsan basaltic andesite (62{+-}3Ma) - Gurye Obongsan andesite (64{+-}3Ma) - Yeosu dacite (63{+-}3Ma) - Dolsando andesite (62{+-}3Ma) - Jangheung Buyongsan andesite (65{+-}3Ma); 4) Suncheon Joryedong andesite (55{+-}2Ma) - Goheung andesite (56{+-}3Ma); 5) Taebaeg Baegbyeonsan basaltic andesite (48{+-}2Ma) - Yeosu basalt (51{+-}3Ma). Resetted age (49{+-}2Ma) of an intrusive rhyolite implies the timing of thermal alteration in the Wondong Fe-Mine of the Taebaegsan Mineralized Belt. K-Ar hornblende ages of two hornblendite stocks in the southern Jangsu suggests apparent emplacement-ages of late Triassic (210{+-}9Ma) and early Permian (274{+-}10Ma), independently. K-Ar hornblende age (1023{+-}37Ma) of the Ogbang amphibolite implies a reduction of original age due to later thermal effect probably attributed to either later intrusion or regional metamorphism. (author). 56 refs., 19 tabs., 14 figs.

  19. Does subduction zone magmatism produce average continental crust

    The question of whether present day subduction zone magmatism produces material of average continental crust composition, which perhaps most would agree is andesitic, is addressed. It was argued that modern andesitic to dacitic rocks in Andean-type settings are produced by plagioclase fractionation of mantle derived basalts, leaving a complementary residue with low Rb/Sr and a positive Eu anomaly. This residue must be removed, for example by delamination, if the average crust produced in these settings is andesitic. The author argued against this, pointing out the absence of evidence for such a signature in the mantle. Either the average crust is not andesitic, a conclusion the author was not entirely comfortable with, or other crust forming processes must be sought. One possibility is that during the Archean, direct slab melting of basaltic or eclogitic oceanic crust produced felsic melts, which together with about 65 percent mafic material, yielded an average crust of andesitic composition

  20. Mount Pinatubo, Philippines: June 1991 Eruptions

    National Oceanic and Atmospheric Administration, Department of Commerce — Mount Pinatubo is an andesitic island arc volcano, located on the southern Luzon Island, Philippines. Prior to 1991 it had been dormant for more than 635 years. On...

  1. The geology of the Rosas-Terreseo area (Sulcis, South Sardinia)

    Poll, J.J.K.


    Cambrian sandstones, limestones and slates, unconformably overlain by Ordovician and Silurian slates, intruded by Hercynian granodiorite and dolerite, and Alpine andesite, occur. The traditional rock stratigraphic subdivisions of the sequences below the Ordovician unconformity are here proposed as f

  2. Paleocene on-spreading-axis hotspot volcanism along the Ninetyeast Ridge: An interaction between the Kerguelen hotspot and the Wharton spreading center

    Krishna, K.S.; Gopala Rao, D.; SubbaRaju, L.V.; Chaubey, A.K.; Shcherbakov, V.S.; Pilipenko, A.I.; Murthy, I.V.R.

    with magnetic lineations and abondoned spreading centers of the eastern Indian Ocean and seismic structure and radiometric dates of the Ninetyeast Ridge. Furthermore, it is supported by the occurrence of oceanic andesites at Deep Sea Drilling Project (DSDP) Site...

  3. 1991 Pinatubo, Philippines Images

    National Oceanic and Atmospheric Administration, Department of Commerce — Mount Pinatubo is an andesitic island arc volcano, located on the southwestern part of the island of Luzon in the Philippines. Prior to 1991, it had been dormant...

  4. 長崎県に分布する赤黄色土の粘土鉱物組成

    江頭, 和彦; 中島, 康夫; 秋山, 美保子; 林, 由紀子; 和仁, 佳子


    Red-Yellow soils are widely distributed on the mountains, hills, and plateaus in Nagasaki Prefecture, located at the most western part of Japan, and used as an important agricultural land. They are derived from various kinds of parent rock including basalt, andesite, andesitic tuff breccia, welded tuff, Tertiary sedimentary rock, and crystalline schist. The purpose of the present study is to investigate the clay mineralogical composition of the Red-Yellow soils in relation to their parent roc...

  5. Spatial variations in the frequency-magnitude distribution of earthquakes in the southwestern Okinawa Trough

    Lin, Jing-yi; Sibuet, Jean-claude; Lee, Chao-Shing; Hsu, Shu-kun; Klingelhoefer, Frauke


    The relations between the frequency of occurrence and the magnitude of earthquakes are established in the southern Okinawa Trough for 2823 relocated earthquakes recorded during a passive ocean bottom seismometer experiment. Three high b-values areas are identified: (1) for an area offshore of the Ilan Plain, south of the andesitic Kueishantao Island from a depth of 50 km to the surface, thereby confirming the subduction component of the island andesites; (2) for a body lying along the 123.3 d...

  6. Geodetic determining of stockpile volume of mineral excavated in open pit mine

    Labant, Slavomír; Staňková, Hana; Weiss, Roland


    In the contemporary geodetic practice it is practically a must to use modern geodetic apparatuses and a variety of the CAD (Computer Aided Design) software for processing and visualising spatial data. The present paper deals with geodetic surveying of Kecerovce open pit mine to determine, for the purpose of mine reopening and commencing with mining of andesite, the volume of non-extracted volumes of andesite. The open pit mine is situated on the foot of Slanské vrchy mountain range. Determini...


    Nur, Irzal


    The Baturappe epithermal silver-base metal prospect is situated in south of Sulawesi island, Indonesia. The prospect lies in the shoshonitic/alkaline southern arm of the Tertiary western Sulawesi plutono-volcanic arc. The Baturappe prospect is developed in the late Middle-Miocene Baturappe Volcanics which in the study area consists of respectively from the older to the younger: basaltic-andesitic lava, gabbroic-dioritic stock, and basaltic-andesitic dykes. Mineralizat...

  8. Clay mineralogy and geochemistry of the soils derived from metamorphic and mafic igneous parent rocks in Lahijan area

    The mineralogical and geochemical composition of the soils of three representative pedons formed on basaltic andesite, andesitic basalt and phyllite were investigated. Results by x-ray diffraction showed that progressive weathering of rocks have been marked by gradual accumulation of Al, Fe, Ti, Mg, H3O+ and depletion of Na, K, Ca and Si in the soil; although, predominant clay, loss and gain trend of elements was different on the various rocks. Based on x-ray diffraction analysis, minerals in basaltic andesite and andesitic basalt were similar but, the intensity of mica to smectite or vermiculite transformation for latter was relatively higher than the former. This process revealed the degradation mineral because of two reasons: (i) - smectite and vermiculite increased whereas mica decreased in surface horizons. (i i)-Irregular mixed layer of mica-smectite or vermiculite was present in deeper part (170 cm) of the soils from andesitic basalt but shallower depth (75 em) of the soils from basaltic andesite. Clay minerals in phyllite were mica and chlorite that stratified with vermiculite. However, the absence of smectite in phyllite might be attributed to more acidic condition or position of the Fe ion in the mineral lattice of chlorite (higher Fe in the interlayer hydroxide sheet)

  9. The production of intermediate magmas through magma mixing and commingling: Evidence from the Hoover Dam Volcanics, Mohave County, Arizona and Clark County, Nevada

    Mills, J.G. Jr. (Univ. of Nevada, Las Vegas, NV (United States). Dept. of Geoscience)


    The Hoover Dam Volcanic section ([approximately]14 Ma) is composed of the reversely-zoned dacitic tuff of Hoover Dam, Switchyard basaltic andesite, Sugarloaf dacite, Black Canyon dacite and Kingman Wash basaltic andesite (Mills, 1985). The origin of this suite is best explained by the commingling and mixing of end-member mafic and felsic magmas. These end-member magmas were most likely formed by partial melting of the mantle and subsequent advective heating and melting of the crust respectively. Textural evidence for these processes is observed in the Black Canyon dacite which contains enclaves of basaltic andesite, and, in the Paint Pots pluton which contains commingled basaltic andesite and monzonite. The Black Canyon dacite is a biotite (4%), homblende (1%) and plagioclase 10% phyric dacite flow which contains up to 5% enclaves of basaltic andesite. The enclaves contain 54 wt% SiO[sub 2], 7.22 ppm Tl, 65 ppm Rb, 1,274 ppm Sr and 1,810 ppm Ba. The gray to purplish-red enclaves have crenulate margins, are commonly vesiculated and contain phenocrysts of biotite (< 1%), hornblende ([much lt]1%), plagioclase (1%) and clinopyroxene( ) (2%). Chemically, the enclaves are distinct from the Switchyard and Kingman Wash basaltic andesites. The enclaves most likely represent a more primitive magma from which the Switchyard and Kingman Wash basaltic andesites were derived. These two units were subsequently chemically modified by mixing with crustal melt and/or crystal fractionation. The presence of a small, clinopyroxenite xenolith (clinopyroxene 90%, garnet 5%, plagioclase 4%) within one of the enclaves indicates an upper mantle source for the enclave magma.

  10. The eruptive history of the Tequila volcanic field, western Mexico: ages, volumes, and relative proportions of lava types

    Lewis-Kenedi, Catherine B.; Lange, Rebecca A.; Hall, Chris M.; Delgado-Granados, Hugo


    The eruptive history of the Tequila volcanic field (1600 km2) in the western Trans-Mexican Volcanic Belt is based on 40Ar/39Ar chronology and volume estimates for eruptive units younger than 1 Ma. Ages are reported for 49 volcanic units, including Volcán Tequila (an andesitic stratovolcano) and peripheral domes, flows, and scoria cones. Volumes of volcanic units ≤1 Ma were obtained with the aid of field mapping, ortho aerial photographs, digital elevation models (DEMs), and ArcGIS software. Between 1120 and 200 kyrs ago, a bimodal distribution of rhyolite (~35 km3) and high-Ti basalt (~39 km3) dominated the volcanic field. Between 685 and 225 kyrs ago, less than 3 km3 of andesite and dacite erupted from more than 15 isolated vents; these lavas are crystal-poor and show little evidence of storage in an upper crustal chamber. Approximately 200 kyr ago, ~31 km3 of andesite erupted to form the stratocone of Volcán Tequila. The phenocryst assemblage of these lavas suggests storage within a chamber at ~2 3 km depth. After a hiatus of ~110 kyrs, ~15 km3 of andesite erupted along the W and SE flanks of Volcán Tequila at ~90 ka, most likely from a second, discrete magma chamber located at ~5 6 km depth. The youngest volcanic feature (~60 ka) is the small andesitic volcano Cerro Tomasillo (~2 km3). Over the last 1 Myr, a total of 128±22 km3 of lava erupted in the Tequila volcanic field, leading to an average eruption rate of ~0.13 km3/kyr. This volume erupted over ~1600 km2, leading to an average lava accumulation rate of ~8 cm/kyr. The relative proportions of lava types are ~22 43% basalt, ~0.4 1% basaltic andesite, ~29 54% andesite, ~2 3% dacite, and ~18 40% rhyolite. On the basis of eruptive sequence, proportions of lava types, phenocryst assemblages, textures, and chemical composition, the lavas do not reflect the differentiation of a single (or only a few) parental liquids in a long-lived magma chamber. The rhyolites are geochemically diverse and were likely

  11. Subcritical crack growth and long-term strength in rock and high-strength and ultra low-permeability concrete

    High-strength and ultra low-permeability concrete (HSULPC) is a strong candidate for a radioactive waste package containing transuranic radionuclides (TRU waste) for geological disposal. The information and knowledge of the time-dependent fracturing of HSULPC and surrounding rock mass are essential to assess the long-term stability of such underground repositories. Here we measured crack velocity in andesite and HSULPC both in air and water to examine slow crack growth (subcritical crack growth) by Double-Torsion method. In air, the crack velocity in andesite increased when the temperature increased. On the other hand, the temperature had little effect on the crack velocity in HSULPC in air. In water, the crack velocity increased when the temperature was higher for both andesite and HSULPC. By using the experimental results of subcritical crack growth, the long-term strength was estimated based on the model of a single crack subjected to tension in an infinite plate. It was shown that the long-term strength of HSULPC was higher than that of andesite. When the temperature increased, the long-term strength of andesite both in air and water and that of HSULPC in water decreased. The long-term strength in water was smaller than that in air for both materials. It is concluded that water remarkably affects subcritical crack growth and the long-term strength in these materials. (author)

  12. Petrography and geochemistry of lithic fragments in ignimbrites from the Mangakino Volcanic Centre : implications for the composition of the subvolcanic crust in western Taupo Volcanic Zone, New Zealand

    The Mangakino Volcanic Centre is the westernmost and oldest rhyolitic caldera volcano in the Taupo Volcanic Zone, North Island, New Zealand. The largest eruptions from Mangakino occurred in two periods of caldera-forming activity during the 1.68-1.53 Ma (Period I), and 1.21-0.95 Ma (Period IIA), producing several voluminous widespread welded and nonwelded ignimbrites and minor fall deposits. Other activity from Mangakino generated fall deposits and rhyolitic lava domes. Lithic fragments are common in all Mangakino ignimbrites (1-10 modal %), and consist of diverse lithologies including: rhyolite, dacite, andesite, and basaltic andesite lava, welded ignimbrite, tuff, volcanic breccia, biotite granite, granodiorite porphyry, siltstone, sandstone, greywacke, metagreywacke, metaconglomerate, biotite and hornblende-biotite schist. Lithic populations in Period I ignimbrites are dominated by andesite lavas, suggesting that there was a pre-existing andesite volcano in the Mangakino area, geochemically distinct from Titiraupenga and Pureora, the nearest roughly contemporaneous andesitic volcanoes. Later ignimbrites that erupted during Period IIA, contain predominantly rhyolitic lava lithics, implying that significant dome building activity occurred at Mangakino, which represented greater volumes of rhyolitic lava than previously described from the area. Petrographic, geochemical, and geophysical (density and magnetic susceptibility) data measured from the lithic fragments are used to propose a model for the shallow crust below Mangakino Volcanic Centre. This model postulates eruptions through a basement of Mesozoic biotite schists overlain by metagreywackes, a thin cover of Tertiary sandstones and siltsones, and an overlying volcanic succession of andesite, dacite and rhyolite lavas, welded ignimbrites, and lacustrine sediments. Ignimbrite eruptions incorporated comagmatic biotite granite fragments from the crystallised margins of the silicic magma chambers, and effectively

  13. Non-explosive magma water interaction in a continental setting: Miocene examples from the Eastern Cordillera (central Andes; NW Argentina)

    Vezzoli, Luigina; Matteini, Massimo; Hauser, Natalia; Omarini, Ricardo; Mazzuoli, Roberto; Acocella, Valerio


    The Middle-Upper Miocene Las Burras Almagro-El Toro (BAT) igneous complex within the Eastern Cordillera of the central Andes (˜24°S; NW Argentina) has revealed evidence of non-explosive interaction of andesitic magma with water or wet clastic sediments in a continental setting, including peperite generation. We describe and interpret lithofacies and emplacement mechanisms in three case studies. The Las Cuevas member (11.8 Ma) comprises facies related to: (i) andesite extruded in a subaqueous setting and generating lobe-hyaloclastite lava; and (ii) marginal parts of subaerial andesite lava dome(s) in contact with surface water, comprising fluidal lava lobes, hyaloclastite, and juvenile clasts with glassy rims. The Lampazar member (7.8 Ma) is represented by a syn-volcanic andesite intrusion and related peperite that formed within unconsolidated, water-saturated, coarse-grained volcaniclastic conglomerate and breccia. The andesite intrusion is finger-shaped and grades into intrusive pillows. Pillows are up to 2 m wide, tightly packed near the intrusion fingers, and gradually become dispersed in the host sediment ≥50 m from the parent intrusion. The Almagro A member (7.2 Ma) shows evidence of mingling between water-saturated, coarse-grained, volcaniclastic alluvial breccia and intruding andesite magma. The resulting intrusive pillows are characterized by ellipsoidal and tubular shape and concentric structure. The high-level penetration of magma in this coarse sediment was unconfined and irregular. Magma was detached in apophyses and lobes with sharp contacts and fluidal shapes, and without quench fragmentation and formation of a hyaloclastite envelope. The presence of peperite and magma water contact facies in the BAT volcanic sequence indicates the possible availability of water in the system between 11 7 Ma and suggests a depositional setting in this part of the foreland basin of the central Andes characterized by an overall topographically low coastal floodplain


    Dragomir Jovičić


    Full Text Available Andesite agregate, due to its suitable physical-mechanical properties, is known on market primarily of asphalt mixtures production for wear covers of roads, regardles to traffic intensity and impedance. The economic importance of the andesite Fužinski Benkovac (Gorski kotar is presented on the basis of the geological, genetic, technical-exploitable, technological, regional, marketing, and social-economic factors. Petrographic structure and tectonic fabric of the deposit have been separately elaborated. On the basis of these researches, quality, hydro-geological characteristics, natural and factors of evaluation, the deposit is economically evaluated as prosperous (the paper is published in Croatian.


    Karatepe, Yasin


    In this study, total N (Nt) and organic C of soils; and total N and organic matter of forest floor were compared in black pine (Pinus nigra Arn. supsp. pallasiana (Lamb.) Holmboe) stands developed on four different growing sites in Golcuk, Isparta. Average of total N reserves was greatest in soils on andesite parent material (8.568 ton/ha) while it was lowest in soils on Golcuk Formation (0.614 ton/ha). Average of organic carbon reserves was greatest in soils on andesite parent material (79.0...

  16. Magma Genesis in Kabanjahe Region Continental Margin Arc of Sumatra

    Bhakti H. Harahap


    DOI: 10.17014/ijog.v6i2.120Volcanic rocks in Kabanjahe region, Karo Regency, North Sumatra Province, are products of old Toba Caldera, Sibayak Volcano, and Sipiso-piso Volcano. Rhyolitic tuff is the main lithology distributed over a large area in this region. Others are basaltic, basaltic andesitic, andesitic, dacitic, and rhyolitic lavas. Data show that the rock was originated from magma of a continental origin formed at a subduction zone environment. Petrogenetic modelling suggests that the...

  17. A Geochemical Exploration of the Sagehen Volcanic Centre, Truckee-Tahoe Region, California, U.S.A

    Clarke, Christopher Angus Leo

    The assemblage of ca. 6--4 Ma volcanic rocks exposed at the Sagehen Research station in the Truckee-Tahoe region of the northern Sierra Nevada, United States, is interpreted to be, within the Ancestral Cascades volcanic arc, a Lassen-type stratovolcano complex. Sagehen is of particular importance because it is one of the few Tertiary arc volcanic centres in California which has not been heavily glaciated during the Pleistocene. The volcanic rocks are variably porphyritic or aphanitic, including abundant plagioclase with clinopyroxene and amphibole. The rocks range from basalt to basaltic-andesite to andesite in composition. Basalts are olivine- and clinopyroxene-bearing with minor phenocrysts of plagioclase. The basaltic-andesites are primarily pyroxene bearing while the andesites contain pyroxene-, plagioclase- and hornblende porphyritic phases. Sagehen arc lavas are calc-alkaline and enriched in the large ion lithophile elements and depleted in High Field Strength Elements. The basalts are depleted in Zr and Hf while the andesites are enriched with Zr and Hf relative to the middle rare earth elements. Compared to previously studied Ancestral Cascade arc samples, Sagehen region basalts have lower 143Nd/144Nd isotopic values that do not correspond to proposed mantle-lithosphere mixing lines, while the andesite samples appear to represent the interplay of these two components on a 87Sr/ 86Sr vs. 143Nd/144Nd. The trace element data and isotopic plots suggest that the melts that produced the basalts are from subduction modified mantle wedge peridotites that ponded near the base of the lithosphere similar to the generation of other subduction related calc-alkaline lavas along convergent continental margins. The andesitic samples appear to be the result of further modification through crustal assimilation as seen in the higher isotopic Sr contents in the andesites and Ce/Smpmn vs. Tb/Ybpmn plots. Finally, the proposed map units from Sylvester & Raines (2007) were found

  18. The evolution of young silicic lavas at Medicine Lake Volcano, California: Implications for the origin of compositional gaps in calc-alkaline series lavas

    Grove, T.L.; Donnelly-Nolan, J. M.


    At Medicine Lake Volcano, California, the compositional gap between andesite (57-62 wt.% SiO2) and rhyolite (73-74 wt.% SiO2) has been generated by fractional crystallization. Assimilation of silicic crust has also occurred along with fractionation. Two varieties of inclusions found in Holocene rhyolite flows, hornblende gabbros and aphyric andesites, provide information on the crystallization path followed by lavas parental to the rhyolite. The hornblende gabbros are magmatic cumulate residues and their mineral assemblages are preserved evidence of the phases that crystallized from an andesitic precursor lava to generate the rhyolite lavas. The andesitic inclusions represent samples of a parental andesite and record the early part of the differentiation history. Olivine, plagioclase and augite crystallization begins the differentiation history, followed by the disappearance of olivine and augite through reaction with the liquid to form orthopyroxene and amphibole. Further crystallization of the assemblage plagioclase, amphibole, orthopyroxene, magnetite, and apatite from a high-SiO2 andesite leads to rhyolite. This final crystallization process occurs on a cotectic that is nearly horizontal in temperature-composition space. Since a large amount of crystallization occurs over a limited temperature interval, a compositional gap develops between rhyolite and high SiO2 andesite. Liquidus surfaces with shallow slopes in temperature-composition space are characteristic of several late-stage crystallization assemblages in the andesite to rhyolite compositional range. Experimentally produced plagioclase+ amphibole+orthopyroxene+magnetite and plagioclase+ augite+low-Ca pyroxene+magnetite cotectics have liquidus slopes that are nearly flat. At other calc-alkaline volcanic centers crystallization processes involving large compositional changes over small temperature intervals may also be important in the development of bimodal volcanism (i.e. the existence of a composition

  19. Tungurahua volcano, Ecuador : structure, eruptive history and hazards

    Hall, M.L.; Robin, Claude; Beate, B.; Mothes, P.; Monzier, Michel


    Tungurahua, one of Ecuador's most active volcanoes, is made up of three volcanic edifices. Tungurahua 1 was a 14-km-wide andesitic stratocone which experienced at least one sector collapse followed by the extrusion of a dacite lava series. Tungurahua 2, mainly composed of acid andesite lava flows younger than 14,000 years BP, was partly destroyed by the last collapse event, 2955 plus or minus 90 years ago, which left a large amphitheater and produced an approximately 8-km3 debris deposit. The...

  20. New K-Ar ages of volcanic rocks and associated mineralization in Canada Honda district, San Luis, Argentina

    New K-Ar ages in the Late Tertiary gold-bearing volcanic belt of the Sierras Pampeanas of San Luis, Argentina are presented. At Canada Honda district, an age of 8.49±0.2 Ma yielded by Cerro del Valle andesite indicates that the dome emplacement postdates the Diente Verde eruptive event. An even younger age of 7.3±0.2 Ma was obtained for illite from hydrothermal alteration at La Reynela mineralization which is hosted by Cerro del Valle andesite (au)

  1. K-Ar dating of the magmatic activity in the Momchilgrad volcanotectonic depression

    The Momchilgrad volcanotectonic depression originated in the Southern parts of Eastern Rhodopes during the paleocene. The earliest products of the magmatic activity in the area are the rocks of the Kalabak andesite complex of Priabonian age (35 - 39 MA). The pyroclastic rocks and lavas of Beli Plast rhyodacite, Majarovo latite, Perperek trachyrhyolite, Zvezdel basaltic - andesite, Ustra rhyolite, Sveti Ilia trachyriodacite, Momchilgrad trachydacite complexes (28-34 MA) and Pcheloyad dyke complex (26.5-32.2 MA) formed lately during Rupelian and Rupelian-Chatian respectively. Obtained K-Ar age ranges for the different complexes overlap significantly indicating that the magmatic activity might have occurred during quite short period of time. (authors)

  2. Stratigraphy of the unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory, Idaho

    The unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory (INEL) are made up of at least 178 basalt-flow groups, 103 sedimentary interbeds, 6 andesite-flow groups, and 4 rhyolite domes. Stratigraphic units identified in 333 wells in this 890-mile2 area include 121 basalt-flow groups, 102 sedimentary interbeds, 6 andesite-flow groups, and 1 rhyolite dome. Stratigraphic units were identified and correlated using the data from numerous outcrops and 26 continuous cores and 328 natural-gamma logs available in December 1993. Basalt flows make up about 85% of the volume of deposits underlying the area

  3. Low-grade metamorphism of permian mafic rocks from the Gorzów Wielkopolski block (Fore Sudetic Monocline, NW Poland): age and mechanism

    Paweł Bylina


    Themetavolcanic rocks in the Gorzów Wielkopolski area (NWPoland) are andesite-basaltsand andesites derived from contaminated within-plate subalkaline basalt melts. K-Ar dating of primaryK-feldspar yields an extrusion age of 285±5 Ma. This new date suggests that these rocksmay be the youngestdated Permo-Carboniferous volcanic rocks within the eastern margin of theNorth German Basin.Petrological and micro-thermometric data indicate that the volcanic rocks were altered by a sub--greenschist faci...

  4. Geochemical and Sr-Nd Isotopic Characteristics of Post-Collisional Calc-Alkaline Volcanics in the Eastern Pontides (NE Turkey)



    Major, trace element, K-Ar age and Sr-Nd isotopic data are presented for the Eocene Torul volcanics in the eastern Pontide orogenic belt (NE Turkey). The studied rocks are composed of basaltic andesitic, andesitic, trachyandesitic, and minor trachydacitic lavas associated with their pyroclastics. These rocks contain plagioclase (An2-44), hornblende (Mg#= 0.78-0.98), clinopyroxene (Wo43-46 En41-43 Fs10-15), biotite, quartz, and minor sanidine phenocrysts. K-Ar ages on hornblendes ages range fr...

  5. Jurassic Volcanism in the Eastern Pontides: Is it Rift Related or Subduction Related?

    Şen, Cüneyt


    The Jurassic volcanic rocks in the centre of the northern zone (south of Trabzon City) provide important constraints on the evolution of Pontides. The investigated volcanic rocks form a transitional series between tholeiitic and calc-alkaline, and is dominated by basalt, basaltic andesite and andesite. Geochemically, they are enriched in LILE and LREE contents and depleted in HFSE [(La/Yb)N= 2.2 - 8.5; (Nb/La)N= 0.1 - 0.77)] compared to mid-ocean ridge basalts and have radiogenic Nd isotope r...

  6. Petrology and geochemistry of igneous inclusions in recent Merapi deposits

    Chadwick, J.P.; Troll, V.R.; Waight, Tod Earle;


    Recent basaltic-andesite lavas from Merapi volcano contain abundant and varied igneous inclusions suggesting a complex sub-volcanic magmatic system for Merapi volcano. In order to better understand the processes occurring beneath Merapi, we have studied this suite of inclusions by petrography, ge...

  7. Inca Volcanic Stone Provenance in the Cuzco Province, Peru

    Patrick N. Hunt


    Full Text Available The use of andesite and basalt as architectual ashlars by Inca stonemasons has been widely discussed throughout the literature. Most of these archaeological or architectural studies are in agreement that that primary Inca quarrying centers in the Cuzco area are in the Rio Huatanay valley at Rumiqolqa and Huaccoto, both to the southeast of Cuzco.

  8. Pedogenesis on volcanic rocks in protected landscape areas in Central and North Bohemia

    Žigová, Anna; Šťastný, Martin


    Roč. 9, č. 4 (2014), s. 153-160. ISSN 1801-5395 Institutional support: RVO:67985831 Keywords : andesite * basalt * Bw horizon * dolerite * mineral compostion * main pedogenic process Subject RIV: DF - Soil Science Impact factor: 0.659, year: 2014

  9. Geochronology and magmatic evolution of the Dieng Volcanic Complex, Central Java, Indonesia and their relationships to geothermal resources

    Harijoko, Agung; Uruma, Ryusuke; Wibowo, Haryo Edi; Setijadji, Lucas Doni; Imai, Akira; Yonezu, Kotaro; Watanabe, Koichiro


    We analyzed new radiometric dating and petrological data of DVC in an attempt to reconstruct volcanic history as groundwork to understand magmatic temporal and spatial evolution. The magma of DVC can be divided on the basis of mineral composition into three types: olivine bearing basalt-basaltic andesite, pyroxene basaltic andesite-andesite, and biotite andesite-dacite, which coincide with three volcanic episodes of DVC: pre-caldera, second, and youngest episode, respectively. The pre-caldera episode was active no later than 1 Ma, the second episode occurred between 0.3 and 0.4 Ma, and the youngest occurred after 0.27 Ma. Plots of CaO, K2O, Al2O3, and Rb/Sr against FeO*/MgO and/or MgO suggest that each volcanic episode has distinct differentiation trends, indicating the presence of multiple shallow magma chambers. The close spatial relationship between the geothermal manifestation, geophysical anomalies, geothermal production zones and volcanic edifices supports the presence of multiple shallow magma chambers beneath DVC, which act as a heat source for the existing geothermal system.

  10. The End of Sluiter’s Coral Reef at Krakatoa

    Umbgrove, J.H.F.


    It is well known that before the famous eruption of August 1883 took place, the island Krakatoa consisted of three volcanoes, the basaltic volcano Rakata and the andesitic volcanoes Danan and Perbuwatan. With the great explosion of August 28th of that year Danan, Perbuwatan and the northwestern part

  11. Chemical trends in a perhumid soil catena on the Turrialba volcano (Costa Rica)

    Meijer, E.L.; Buurman, P.


    The variation in chemical composition of soil samples (XRFS data) from a soil catena of 14 soil profiles on the northern slope and foot slope of the andesitic Turrialba volcano (3300 m) has been analysed to test the two hypotheses, which underlie our interpretation that this catena is a weathering s

  12. Carbonate assimilation at Merapi volcano, Java Indonesia

    Chadwick, J.P; Troll, V.R; Ginibre,, C.;


    Recent basaltic andesite lavas from Merapi volcano contain abundant, complexly zoned, plagioclase phenocrysts, analysed here for their petrographic textures, major element composition and Sr isotope composition. Anorthite (An) content in individual crystals can vary by as much as 55 mol% (An40^95...

  13. Geologic and preliminary reservoir data on the Los Humeros Geothermal System, Puebla, Mexico

    Ferriz, H.


    Exploratory drilling has confirmed the existence of a geothermal system in the Los Humeros volcanic center, located 180 km east of Mexico City. Volcanic activity in the area began with the eruption of andesites, followed by two major caldera-forming pyroclastic eruptions. The younger Los Potreros caldera is nested inside the older Los Humeros caldera. At later stages, basaltic andesite, dacite, and olivine basalt lavas erupted along the ring-fracture zones of both calderas. Geologic interpretation of structural, geophysical, and drilling data suggests that: (1) the water-dominated geothermal reservoir is hosted by the earliest andesitic volcanic pile, is bounded by the ring-fracture zone of the Los Potreros caldera, and is capped by the products of the oldest caldera-forming eruption; (2) permeability within the andesitic pile is provided by faults and fractures related to intracaldera uplift; (3) the geothermal system has potential for a large influx of meteoric water through portions of the ring-fracture zones of both calderas; and (4) volcanic centers with similar magmatic and structural conditions can be found in the eastern Cascades, USA.

  14. Stratigraphy, petrology, and geochemistry of the Spurr Volcanic Complex, eastern Aleutian Arc, Alaska. [(Appendix for geothermal fluid chemistry)

    Nye, C.J.


    The Spurr Volcanic Complex (SVC) is a calcalkaline, medium-K, sequence of andesites erupted over the last quarter of a million years by the easternmost currently active volcanic center in the Aleutian Arc. The ancestral Mt. Spurr was built mostly of andesites of uniform composition (58 to 60% SiO/sub 2/), although andesite production was episodically interrupted by the introduction of new batches of more mafic magma. Near the end of the Pleistocene the ancestral Mt. Spurr underwent Bezyianny-type avalanche caldera formation, resulting in the production of a volcanic debris avalanche with overlying ashflows. Immediately afterward, a large dome (the present Mt. Spurr) was emplaced in the caldera. Both the ashflows and dome are made of acid andesite more silicic than any analyzed lavas from the ancestral Mt. Spurr (60 to 63% SiO/sub 2/), yet contain olivine and amphibole xenocrysts derived from more mafic magma. The mafic magma (53 to 57% SiO/sub 2/) erupted during and after dome emplacement, forming proto-Crater Peak and Crater Peak. Hybrid pyroclastic flows and lavas were also produced. Proto-Crater Peak underwent glacial dissection prior to the formation of Crater Peak in approximately the same location. Appendices II through VIII contain a summary of mineral compositions; Appendix I contains geochemical data. Appendix IX by R.J. Motyka and C.J. Nye describes the chemistry of geothermal fluids. 78 refs., 16 figs., 3 tabs.

  15. 蛍光X線分析装置(XRF)による1:5希釈ガラスビードを用いた全岩主成分・微量成分元素の定量分析

    新城, 竜一; 宮本, 正雪; Shinjo, Ryuichi; Miyamoto, Masayuki


    Analytical results of major and trace elements(Ba, Co, Cr, Nb, Ni, Rb, Sr, V, Y, and Zr) for bulk rocks by XRF using 1:5 dilution glass bead were evaluated. Analytical conditions and protocol are also reported. The results show relatively good accuracy and precision for major and trace elements. This method could be suitable to basalts to andesites, with error

  16. Inca Volcanic Stone Provenance in the Cuzco Province, Peru

    Patrick N. Hunt


    The use of andesite and basalt as architectual ashlars by Inca stonemasons has been widely discussed throughout the literature. Most of these archaeological or architectural studies are in agreement that that primary Inca quarrying centers in the Cuzco area are in the Rio Huatanay valley at Rumiqolqa and Huaccoto, both to the southeast of Cuzco.

  17. Biogeochemistry of hydrothermally and adjacent non-altered soils

    As a field/lab project, students in the Soil Biogeochemistry class of the University of Nevada, Reno described and characterized seven pedons, developed in hydrothermally and adjacent non-hydrothermally altered andesitic parent material near Reno, NV. Hydrothermally altered soils had considerably lo...

  18. Nematodes from rocky grassland in Börzsöny Mountains, Hungary

    Kiss, M.


    Full Text Available This paper reports on investigations carried out on soil inhabiting nematodes living in andesitic rock regions ofBörzsöny Mountains. Seventeen species are listed. Heterodorus arcuatus (Thorne, 1939, new to the fauna of Hungary, isdescribed and illustrated in detail.

  19. Fading characteristics of martian analogue materials and the applicability of a correction procedure

    Morthekai, P.; Jain, Mayank; Murray, A.S.; Thomsen, Kristina Jørkov; Bøtter-Jensen, Lars

    The anomalous fading of trapped charge in martian analogue materials such as basalt and andesite rock samples is measured. Optically stimulated luminescence (OSL) signals show rapid fading (of between 4% and 27% per decade). Fading rates obtained using high temperature thermoluminescence signals ...... region of the growth curve. (C) 2008 Elsevier Ltd. All rights reserved....

  20. Estimating heat capacity and heat content of rocks

    Robertson, Eugene C.; Hemingway, Bruch S.


    New heat-capacity measurements are reported for four rock types; Westerly granite from Bradford, RI, andesite from Lake County, OR, peridotite from Sonoma County, CA, and basalt from the Columbia River Group. Measurements were made on powders of the rocks in the temperature range of 340 to about 1000 K.

  1. Formation of redox gradients during magma-magma mixing

    Ruprecht, P.; Fiege, A.; Simon, A. C.


    Magma-mixing is a key process that controls mass transfer in magmatic systems. The variations in melt compositions near the magma-magma interface potentially change the Fe oxidation state [1] and, thus, affect the solubility and transport of metals. To test this hypothesis, diffusion-couple experiments were performed at 1000 °C, 150 MPa and QFM+4. Synthesized crystal-bearing cylinders of hydrous dacite and hydrous basaltic andesite were equilibrated for up to 80 h. The run products show that mafic components (Fe, Mg, etc.) were transported from the andesite into the dacite, while Si, Na and K diffused from the dacite into the andesite. A crystal dissolution sequence in the order of cpx, opx, plag, and spl/il was observed for the andesite. We combined μ-XANES spectroscopy at Fe K-edge [2] with two-oxide oxybarometry [3] to measure redox profiles within our experiments. Here, fO2 decreased towards the interface within the dacite and increased towards the interface within the andesite. This discontinuous fO2 evolution, with a sharp redox gradient of ~1.8 log fO2 units at the interface was maintained throughout the time-series despite the externally imposed fO2 of the vessel. We propose a combination of two mechanisms that create and sustain this redox gradient: 1) The dissolution of cpx and opx in the andesite mainly introduced Fe2+ into the melt, which diffused towards the dacite, lowering Fe3+/SFe near the interface. 2) Charge balance calculations in the melt during diffusive exchange suggest net positive charge excess in the andesite near the interface (i.e., oxidation) and net negative charge excess in the dacite near the interface (i.e., reduction). We suggest that this (metastable) redox layer can help to explain the contrasting Au/Cu ratios observed for arc-related porphyry-type ore deposits. [1] Moretti (2005), Ann. Geophys. 48, 583-608. [2] Cottrell et al. (2009), Chem. Geol. 268, 167-179. [3] Ghiorso and Evans (2008), Am. J. Sci. 308, 957-1039.

  2. Park Volcanics, Murihiku Terrane, New Zealand : petrology, petrochemistry, and tectonic significance

    The Late Triassic to Early Jurassic Park Volcanics Group comprises minor shallow intrusive and extrusive bodies emplaced during mainly marine sedimentation of the Murihiku Terrane, southern New Zealand. Gowan Andesite in western Southland and Glenham Porphyry andesites in eastern Southland are high-K andesites. Glassy examples have commonly lost K during alteration. Orthoclase contents of Or3.6-3.7 in plagioclase phenocrysts at An50 confirm the high-K nature of the melts at the time of phenocryst crystallisation. The Gowan andesites have higher Fe/Mg than the Glenham and related differences in minor element chemistry suggesting lower ∫O2 during fractionation of the parent magma. Pinney Volcanics in western Southland are mostly high-K trachydacites but, like Glenham Porphyry, include minor rhyolite. Barnicoat Andesite in the Nelson area is medium-K olivine andesite, marginally tholeiitic in terms of its FeO*/MgO versus SiO2 behaviour, but otherwise is typically calc-alkaline, as are the Gowan, Glenham, and Pinney. Analyses of pyroxenes (augites, orthopyroxenes, reaction rim and groundmass pigeonites) reveal xenocrysts recording an early stage of magma fractionation, slight iron enrichment in the andesite stage, and lowered Fe/Mg and increased Ca contents in augites of the most felsic rocks. Titanian tschermakite and titanian magnesio-tschermakite of deep-seated origin participated in fractionation leading to the Pinney Volcanics, and magnesio-hornblende, edenite, and biotite crystallised as minor late stage minerals following high-level emplacement of Gowan Andesite and siliceous Glenham Porphyry members. Low87Sr/86Sr ratios (c. 0.7034-0.7037), REE and multi-element distribution patterns, and the mineralogical features collectively suggest fractionation of the andesites from parental basalt originating in an enriched mantle wedge above a subduction zone, with minimal contamination by continental crust. High-K andesites appear to be unknown in clearly established

  3. Miocene and early Pliocene epithermal gold-silver deposits in the northern Great Basin, western United States: Characteristics, distribution, and relationship to Magmatism

    John, D.A.


    Numerous important Miocene and early Pliocene epithermal Au-Ag deposits are present in the northern Great Basin. Most deposits are spatially and temporally related to two magmatic assemblages: bimodal basalt-rhyolite and western andesite. These magmatic assemblages are petrogenetic suites that reflect variations in tectonic environment of magma generation. The bimodal assemblage is a K-rich tholeiitic series formed during continental rifting. Rocks in the bimodal assemblage consist mostly of basalt to andesite and rhyolite compositions that generally contain anhydrous and reduced mineral assemblages (e.g., quartz + fayalite rhyolites). Eruptive forms include mafic lava flows, dikes, cinder and/or spatter cones, shield volcanoes, silicic flows, domes, and ash-flow calderas. Fe-Ti oxide barometry indicates oxygen fugacities between the magnetite-wustite and fayalite-magnetite-quartz oxygen buffers for this magmatic assemblage. The western andesite assemblage is a high K calc-alkaline series that formed a continental-margin are related to subduction of oceanic crust beneath the western coast of North America. In the northern Great Basin, most of the western andesite assemblage was erupted in the Walker Lane belt, a zone of transtension and strike-slip faulting. The western andesite assemblage consists of stratovolcanoes, dome fields, and subvolcanic plutons, mostly of andesite and dacite composition. Biotite and hornblende phenocrysts are abundant in these rocks. Oxygen fugacities of the western andesite assemblage magmas were between the nickel-nickel oxide and hematite-magnetite buffers, about two to four orders of magnitude greater than magmas of the bimodal assemblage. Numerous low-sulfidation Au-Ag deposits in the bimodal assemblage include deposits in the Midas (Ken Snyder), Sleeper, DeLamar, Mule Canyon, Buckhorn, National, Hog Ranch, Ivanhoe, and Jarbidge districts; high-sulfidation gold and porphyry copper-gold deposits are absent. Both high- and low

  4. Reverse Polarity Magnetized Melt Rocks from the Cretaceous/Tertiary Chicxulub Structure, Yucatan Peninsula, Mexico

    Urrutia-Fucugauchi, J.; Marin, Luis; Sharpton, Virgil L.


    We report paleomagnetic results for core samples of the breccia and andesitic rocks recovered from the Yucatan-6 Petrolcos Mexicanos exploratory well within the Chicxulub structure (about 60 km SSW from its center), northern Yucatan, Mexico. A previous study has shown that the rocks studied contain high iridium levels and shocked breccia clasts and an Ar/Ar date of 65.2 +/- 0.4 Ma. Andesitic rocks are characterized by stable single-component magnetizations with a mean inclination of -42.6 deg +/- 2.4 deg. Breccias present a complex paleomagnetic record characterized by multivectorial magnetizations with widely different initial NRM inclinations. However, after alternating field demagnetization, well defined characteristic components with upward inclinations are defined. IRM acquisition experiments, comparison of IRM and NRM coercivity spectra and the single component magnetization of the andesitic rocks indicate the occurrence of iron-rich titanomagnetites of single or pseudo-single domain states as the dominant magnetic carriers. Mean inclinations from the andesitic rocks and most of the breccia samples give a mean inclination of about -40 deg to -45 deg, indicating a reverse polarity for the characteristic magnetization that is consistent with geomagnetic chron 29R, which spans the Cretaceous/Tertiary (K/T) boundary. The inclination is also consistent with the expected value (and corresponding paleolatitude) for the site estimated from the reference polar wander curve for North America. We suggest that the characteristic magnetizations for the andesitic and breccia rocks are the result of shock heating at the time of formation of the impact structure and that the age, polarity and pateolatitude are consistent with a time at the K/T boundary.

  5. Geological and Geochemical Study on Some Dykes And Hosting Stone-grey in Sheikh Salem Area, South Eastern Desert, Egypt

    Sheikh Salem area (45 km west of coastal Mersa Alam town .south Eastern Desert of Egypt) is occupied by Precambrian basement rocks including volcaniclastic metasediments, metagabbro-diorite complexes, metavolcanics and syenogranite. The studied area is dissected by numerous dyke swarms. The syenogranite is of I-type and characterized by peraluminous nature. Two sets of nearly vertical dykes cut the syenogranite. The younger one trends NNW-SSE, while the older trends ENE-WSW. The younger dykes are lamprophyres and mainly composed of plagioclase, hornblende, pyroxene and olivine. Calcite, epidote, antigorite and chlorite are secondary minerals, whereas opaques are accessories. The older dykes are andesites and mainly composed of plagioclase, hornblende. Saussurite, calcite, and epidote are secondary minerals, whereas opaques are accessories. The separated minerals from the lamprophyre samples include graphite, pyrite and zircon. A very important observation is the occurrence of graphite in most lamprophyre samples. The original magma of the lamprophyres is of high K.-calc alkaline to shoshonitic type with basaltic nature, while the original magma of the andesites is of high K-calc alkaline to calc alkaline type with andesitic nature. The lamprophyres have high content in Y, Ni, Cu, V and Zr, and low content in Rb, Pb, Zn, Ba and Ga compared with andesites. Both the lamprophyres and andesites show enrichment in Ba, Rb, Pb, Sr, Zr, Zn and Y and depletion in Cr and Ni compared with primitive mantle. The Syenogranite of Sheikh Salem area shows background radioactivity level giving eU contents of 7.4 ppm while eTh average content is 18.7 ppm and the mean value of eU/eTh ratio is 0.42

  6. Southern Mexico Miocene Magmatic Activity

    Layer, P.


    Magmatic activity in southern Mexico have been occurred in three important volcanic regions: Los Tuxtlas Volcanic Field (TVF), Chiapanecan Volcanic Arc (CVA), and Tacaná Volcanic Complex (TVC). This activity produce alkaline and calc-alkaline products. The TVF has been active since 7 Ma ago producing Na-alkaline basanite, trachybasalt, and trachyandesite (41 63 wt% SiO2), and calc-alkaline basalts, basaltic-andesites, and andesites (45 63 wt% SiO2). The CVA including El Chichon Volcano produced calc-alkaline magmas varying from andesites to dacites (57 65 wt% SiO2) emitted between 2100 ka ago (Tzontehuitz) to 225 ka and K-alkaline magmas emitted from 1.1 Ma ago (trachybasalt, 46 51 wt% SiO2) to the Recent (trachyandesite, 57 63 wt% SiO2). The TVC emitted calc-alkaline products varying from basaltic-andesite (52 57 wt% SiO2) as mafic enclaves, andesites (57 63 wt% SiO2), and dacites (63 68 wt% SiO2). El Chichón and TVF present slight enrichments in K2O, Na2O, Rb, Sr, Th, U, Cs, and LREE respect to TVC, these are signatures related to subduction environment. The presence of alkaline magmas at El Chichón and TVF correspond to mantle low degree melts that reach the surface along with calc-alkaline lavas due to a tensional stress field that allows their pass to the surface. In the generation of the magmas of southern Mexico three components are involved: mantle partial melting fluids, fluid from subducted lithosphere, and continental crust, likely interacting in different ratios through time and in different proportions from SW to NE.

  7. Analisis stratigrafi awal kegiatan Gunung Api Gajahdangak di daerah Bulu, Sukoharjo; Implikasinya terhadap stratigrafi batuan gunung api di Pegunungan Selatan, Jawa Tengah

    Hill Gendoet Hartono


    Full Text Available, Tertiary volcanisms in the Southern Mountains, Central Jawa were started with the formation of pillow lavas having basalt to basaltic andesite in composition. This initial stage volcanism developed into a  construction period of composite volcanoes that consist of alternating basaltic to andesitic lava flows, breccias, and tuffs. The construction period could be followed by a destructive phase, producing pumice-rich pyroclastic breccias, lapillistones, and tuffs of high silica andesite to dacite, or even rhyolite in composition. A stratigraphic measuring section at Bulu area, Sukoharjo Regency, presents an alternat- ing fine-grained andesitic volcaniclastic material and some limestones, with the total thickness is 143.33 m. The thickness of bedded volcaniclastic material tends to be thickening upward from 35 m until 90 m. The grain size of the volcaniclastic material also tends to be coarsening upward from clay size through silt and fine sand to coarse sand and granules. Paleontological analysis on fossils contained in the lime- stone gives an age of Early Miocene (N7 - N9. The volcaniclastic rocks is conformably overlain by the Mandalika Formation, comprising alternating andesitic breccias, lavas, and tuffs. These data imply that the fine-grained volcaniclastic material is an initial product of the construction period of Gajahdangak Volcano in the area, that formed the Mandalika Formation. This Formation is overlain by the Semilir Formation, composed of pumice-rich pyroclastic breccias and tuffs with dacitic composition. This as- sociated volcanic rock reflects a product of a caldera explosion or a destructive phase. Based on the characteristics of lithology of volcanic products from the initial stage, to a construction and destruction period, and compiled age data, the Southern Mountains represent formal volcanic rock units that are able to be divided into many formations.  

  8. Evidencia textural y geoquímica de mezcla de magmas en el volcán Chimpa, Puna Salteña Textural and geochemical evidence for magma mixing in the Chimpa Volcano, Puna Salteña

    Marcelo Arnosio


    Full Text Available La historia eruptiva del volcán Chimpa (24º00´S-66º08´O comprende un ciclo explosivo que eruptó ignimbritas y depósitos de flujos de bloques y ceniza de composición andesítica, y un ciclo efusivo, representado por lavas andesíticas y andesíticas basálticas. Los primeros materiales emitidos durante el ciclo explosivo corresponden a ignimbritas, las cuales no poseen evidencias de interacción con magmas básicos. Por el contrario, en los depósitos de flujos de bloques y ceniza quedó registrada la interacción con un magma básico (mingling representado por inclusiones máficas y el desarrollo de texturas de desequilibrio en plagioclasa y biotita. Sin embargo, la composición del magma andesítico no se modificó durante la mezcla. En el ciclo efusivo se generó un nuevo magma, por mezcla y homogeneización (magma mixing entre el magma andesítico y un magma más básico. Este magma híbrido posee una asociación mineral en desequilibrio, que incluye olivino y cuarzo con corona de clinopiroxeno, hornblenda y biotita con coronas formadas por plagioclasa + ortopiroxeno + magnetita, así como ortopiroxeno con coronas de clinopiroxeno. Estas fases en desequilibrio coexisten junto a otros cristales de las mismas fases, pero en aparente equilibrio. En diagramas geoquímicos, las lavas híbridas ocupan una posición intermedia en la tendencia lineal definida por el extremo andesítico y andesítico basáltico. La proporción del magma básico involucrado en la mezcla es de 44%. Los datos petrográficos y geoquímicos indican un proceso creciente de interacción de magmas básicos con el magma andesítico residente en la cámara magmática a lo largo del tiempo.The eruptive history of the Chimpa volcano (24º00´S-66º08´O comprises an explosive cycle that erupted andesitic ignimbrites and blocks and ash flow deposits, and an effusive cycle, represented by the discharge of andesitic and basaltic andesite lava flows. The first material

  9. The 1723 A.D. violent strombolian and phreatomagmatic eruption at Irazú Volcano, Costa Rica

    Guillermo E. Alvarado


    Full Text Available The largest of the recorded historic eruptions at Irazú volcano began on February 16, 1723 and lasted until at least December 11. We here critically examine deposits of this eruption exposed on the summit of Irazú. Our reconstruction of the eruption is based on the unique chronicle of the Spanish governor Diego de la Haya. The eruption began with a < 10 cm thick surge deposit of phreatic origin showing block sag structures. The deposit is overlain by 6 m-thick coarse-grained basaltic andesitic non-graded juvenile fallout tephra consisting of highly vesicular (22-59 vol.% bombs and lapilli with minor hydrothermally altered lapilli (1-7 vol.% and rare light colored andesitic vesicular lapilli (< 1%. These fallout deposits are interpreted as strombolian, possible generated during a short-lived scoria cone at the end of February 1723, dominate volumetrically in the proximal facies. Overlying <1.2 m thick phreatomagmatic deposits of fi nely laminated lapilli-bearing gray ash (fallout and surge deposits some with contorted bedding and sag structures, are in turn overlain by a 1.2 m thick bed of ash matrix-rich bomb/block deposit. The 1723 eruption was accompanied by shallow volcano-tectonic earthquakes (Modifi ed Mercalli scale Intensity MMI VI-VII, magnitude ML ~5.5 that possibly facilitated magma/water interaction. Phenocrysts in the basaltic andesite (~53-55 wt.% SiO2 bombs comprise plagioclase (6.1-21.6 vol.%, An52-35, clinopyroxene (2.5-10 vol.%, orthopyroxene (0.7-2 vol.%, olivine (0.1-2.2 vol.%; Fo76-88 and Fe/Ti-oxides (0.1-1%, in a groundmass (66.5-90.3 vol. %, dominated by plagioclase (An69-54, clinopyroxene and opaques in brown and black glass with the same range of chemical composition (SiO2=57-64 wt.%. Rare white pumiceous lapilli in the scoria deposits are high-K, hornblende andesite (SiO2: 58-60 wt.%, geochemically unrelated to the scoria deposits. Thus, two different magmas co-existing in the magma chamber were mingled shortly before

  10. The composition of the foundered complement to the continental crust and a re-evaluation of fluxes in arcs

    Jagoutz, O.; Schmidt, M. W.


    Most primitive arc melts are basaltic in composition, yet the bulk continental crust, thought to be generated in arcs, is andesitic. In order to produce an andesitic crust from primitive arc basalts, rocks complementary to the andesitic crust have to be fractionated and subsequently removed, most likely through density sorting in the lower arc crust. The Kohistan Arc in northern Pakistan offers a unique opportunity to constrain the composition and volume of material fluxes involved in this process. In a lower crustal section >10 km cumulates (dunites, wehrlites, websterites, clinopyroxene-bearing garnetites and hornblendites, and garnet-gabbros) are exposed that are 0.1-0.3 g/cm3 denser than the underlying mantle. The cumulates combine with the andesitic bulk Kohistan Arc crust to reproduce the major and trace element composition of primitive basaltic arc melts. Our petrochemical analysis suggests that fractionation and subsequent foundering of wehrlites+ultramafic hornblende-garnet-clinopyroxene cumulates+garnet-gabbros is a viable mechanism for producing andesitic crust from a calc-alkaline/tholeiitic primitive high-Mg basalt. The mass of the foundered material is approximately twice that of the arc crust generated. For an overall andesitic arc composition, we estimate a magma flux into the arc (11-15 km3/yr) about three times the rate of arc crust production itself. Foundering fluxes of cumulates (6.4-8.1 km3/yr) are one third to half those of the globally subducted oceanic crust (~19 km3/yr). Hence, the delaminate forms a volumetrically significant, albeit refractory and depleted geochemical reservoir in the mantle. Owing to its low U/Pb and high Lu/Hf the foundered material evolves with time to a reservoir characterized by unradiogenic Pb and highly radiogenic Hf isotopes, unlike any of the common mantle endmembers defined by OIB chemistry. The unradiogenic Pb of the foundered arc cumulates could counterbalance the radiogenic Pb composition of the depleted

  11. Late Holocene hydrous mafic magmatism at the Paint Pot Crater and Callahan flows, Medicine Lake Volcano, N. California and the influence of H2O in the generation of silicic magmas

    Kinzler, R.J.; Donnelly-Nolan, J. M.; Grove, T.L.


    This paper characterizes late Holocene basalts and basaltic andesites at Medicine Lake volcano that contain high pre-eruptive H2O contents inherited from a subduction related hydrous component in the mantle. The basaltic andesite of Paint Pot Crater and the compositionally zoned basaltic to andesitic lavas of the Callahan flow erupted approximately 1000 14C years Before Present (14C years B.P.). Petrologic, geochemical and isotopic evidence indicates that this late Holocene mafic magmatism was characterized by H2O contents of 3 to 6 wt% H2O and elevated abundances of large ion lithophile elements (LILE). These hydrous mafic inputs contrast with the preceding episodes of mafic magmatism (from 10,600 to ~3000 14C years B.P.) that was characterized by the eruption of primitive high alumina olivine tholeiite (HAOT) with low H2O (magmatic inclusions similar in character to the mafic lavas at Callahan and Paint Pot Crater. The influence of H2O on fractional crystallization of hydrous mafic magma and melting of pre-existing granite crust beneath the volcano combined to produce the rhyolite. Fractionation under hydrous conditions at upper crustal pressures leads to the early crystallization of Fe-Mg silicates and the suppression of plagioclase as an early crystallizing phase. In addition, H2O lowers the saturation temperature of Fe and Mg silicates, and brings the temperature of oxide crystallization closer to the liquidus. These combined effects generate SiO2-enrichment that leads to rhyodacitic differentiated lavas. In contrast, low H2O HAOT magmas at Medicine Lake differentiate to iron-rich basaltic liquids. When these Fe-enriched basalts mix with melted granitic crust, the result is an andesitic magma. Since mid-Holocene time, mafic volcanism has been dominated primarily by hydrous basaltic andesite and andesite at Medicine Lake Volcano. However, during the late Holocene, H2O-poor mafic magmas continued to be erupted along with hydrous mafic magmas, although in

  12. Magma hybridisation at Soufriere Hills Volcano, Montserrat

    Humphreys, Madeleine; Edmonds, Marie; Christopher, Thomas; Hards, Vicky


    Arc volcanoes commonly show evidence of mingling between mafic and silicic magma. For example, the Soufrière Hills Volcano, Montserrat typically erupts andesitic magma containing basaltic to basaltic-andesite inclusions. However, the andesite also contains a wide variety of phenocryst textures as well as strongly zoned microlites, suggesting that more intimate physical mixing also occurs. Analysis of minor elements in both phenocrysts and microlites allows the discrimination of different crystal populations, and provides insight into their origins. Microlites of plagioclase and orthopyroxene are chemically distinct from the phenocrysts, being enriched in Fe and Mg, and Al and Ca respectively. However, they are indistinguishable from the compositions of these phases in the mafic inclusions. Microlite compositions also give anomalously high temperatures using standard geothermometry techniques, similar to those of the mafic inclusions. Compositions of clinopyroxene from overgrowth rims on quartz and orthopyroxene and coarse-grained breakdown rims on hornblende, are identical to those from the mafic inclusions, indicating that these rims form during interaction with mafic magma. We infer that the inclusions disaggregated under conditions of high shear stress during ascent in the conduit, transferring mafic material into the andesite groundmass. This implies that the mafic component of the system is greater than previously determined from the volume proportion of mafic enclaves. The presence of mafic-derived microlites in the andesite groundmass also means that care must be taken when using this as a starting material for phase equilibrium experiments. Melt inclusions and matrix glasses in the erupted include an anomalously K2O-rich population which overlaps with residual (high-K2O, high-TiO2) mafic inclusion glass. These glasses represent the effects of physical mixing with mafic magma, both during ascent and by diffusive exchange during the formation of mafic

  13. Repetitive mixing events and Holocene pyroclastic activity at Pico de Orizaba and Popocatepetl, Mexico

    Cantagrel, J.M.; Gourgaud, A.; Robin, C.


    The Holocene volcanic activity which built up the present terminal cones of Pico de Orizaba and Popocatepetl in eastern Mexico, was characterized by repeated pyroclastic Saint-Vincent type eruptions. Radiocarbon data show that these paroxysmal events occurred at more or less regular intervals, and were followed by moderate activity producing ash and pumice falls and andesitic lava flows from the summit craters. Typical ash and scoria pyroclastic flows exhibit a heterogeneous composition given by the interaction of a dacitic component with a more basic andesitic one. Scoria bombs are characterized by banded to emulsified textures, mineralogical disequilibrium assemblages and linear chemical variations on element-element plots as exemplified by the Loma Grande flow at Pico. Periodic replenishments of the magmatic reservoir could be the major phenomenon that started mixing and consequently triggered the pyroclastic eruptions. 22 references.

  14. Eruptive history and petrology of Mount Drum volcano, Wrangell Mountains, Alaska

    Richter, D.H.; Moll-Stalcup, E. J.; Miller, T.P.; Lanphere, M.A.; Dalrymple, G.B.; Smith, R.L.


    Mount Drum is one of the youngest volcanoes in the subduction-related Wrangell volcanic field (80x200 km) of southcentral Alaska. It lies at the northwest end of a series of large, andesite-dominated shield volcanoes that show a northwesterly progression of age from 26 Ma near the Alaska-Yukon border to about 0.2 Ma at Mount Drum. The volcano was constructed between 750 and 250 ka during at least two cycles of cone building and ring-dome emplacement and was partially destroyed by violent explosive activity probably after 250 ka. Cone lavas range from basaltic andesite to dacite in composition; ring-domes are dacite to rhyolite. The last constructional activity occured in the vicinity of Snider Peak, on the south flank of the volcano, where extensive dacite flows and a dacite dome erupted at about 250 ka. The climactic explosive eruption, that destroyed the top and a part of the south flank of the volcano, produced more than 7 km3 of proximal hot and cold avalanche deposits and distal mudflows. The Mount Drum rocks have medium-K, calc-alkaline affinities and are generally plagioclase phyric. Silica contents range from 55.8 to 74.0 wt%, with a compositional gap between 66.8 and 72.8 wt%. All the rocks are enriched in alkali elements and depleted in Ta relative to the LREE, typical of volcanic arc rocks, but have higher MgO contents at a given SiO2, than typical orogenic medium-K andesites. Strontium-isotope ratios vary from 0.70292 to 0.70353. The compositional range of Mount Drum lavas is best explained by a combination of diverse parental magmas, magma mixing, and fractionation. The small, but significant, range in 87Sr/86Sr ratios in the basaltic andesites and the wide range of incompatible-element ratios exhibited by the basaltic andesites and andesites suggests the presence of compositionally diverse parent magmas. The lavas show abundant petrographic evidence of magma mixing, such as bimodal phenocryst size, resorbed phenocrysts, reaction rims, and

  15. Early Archean sialic crust of the Siberian craton: Its composition and origin of magmatic protoliths

    Vovna, G. M.; Mishkin, M. A.; Sakhno, V. G.; Zarubina, N. V.


    This study demonstrates that the base of the Archean deep-seated granulite complexes within the Siberian craton consists of a metabasite-enderbite association. The major and trace element distribution patterns revealed that the protoliths of this association are represented by calc-alkaline andesites and dacites, containing several minor sequences of komatiitic-tholeiitic volcanic rocks. The origin of the primary volcanic rocks of the metabasite-enderbite association is inferred on the basis of a model of mantle plume magmatism, which postulates that both andesitic and dacitic melts were derived from the primary basitic crust at the expense of heat generated by ascending mantle plumes. The formation of the protoliths of the Archen metabasite-enderbite association of the Siberian craton began at 3.4 Ga and continued until the late Archean.

  16. Isparta' da Çıkarılan Andezit Ve Bazalt Kayaçlarının Radyasyon Soğurma Özelliklerinin İncelenmesi

    Kadir GÜNOĞLU


    Full Text Available Natural stones are generally igneous, metamorphic and sedimentary are divided into 3 classes including. A region of Isparta volcanic magmatic origin andesite and basalt stones which are classified as an area where there are plenty of rocks. These rocks are used as coating materials, especially in buildings. Therefore it is important to determine stones radiation absorbing properties. In this study, in Isparta andesite and basalt rocks extracted 137Cs and 60Co radiation absorbing properties obtained from the radioactive source 662, 1173, and 1332 keV gamma energy was measured for. Gamma Spectroscopy Laboratory measurements of Suleyman Demirel University, located in the 3 "x3" size NaI (Tl detector containing gamma spectroscopy was performed using the system

  17. Origin of groundwater in the tertiary volcanic complex in central Slovakia

    On the inner side of the Carpathian Mountain arch in central Slovakia, there is a sequence of Miocene to Pleistocene volcanic rocks predominantly of andesite type and their pyroclastics, forming a stratovolcanic structure up to 1500 m thick over an area of about 5400 km2. The volcanics are underlain by Mesozoic carbonate and by earlier crystalline rocks. The andesites were considered to be poor aquifers. A recent systematic hydrogeological investigation has confirmed that there is a concentration of groundwater flow in fractured zones along faults, this flow discharging into streams. The isotope analyser helped to explain the groundwater structure in the volcanic rocks in relation to the earlier structures, and contributed to knowledge on the development of groundwater and the evaluation of its resources. 2 figs, 1 tab


    Jakob Pamić


    Full Text Available In the paper are presented basic geological, petrologieca1, geochemi-cal and mineral deposit data for five main magmatic-metallogenic formations of the northwestern and central Dinarides: (lThe Permo Triassic rifting related andesite-diorite formations; (2 The Jurassic-Lower Cretaceous accretionary (ophiolite formations; (3 The Upper Cretaceous-Paleogene subduction related basalt-rhyohite formations; (4 The Paleogene collisional granite formations, and (5 The Oligo-cene-Neogene postsubduction andesite formations. All these magmatic-metallogenic formations originated in different geotectonic settings during the Alpine evolution of the Dinaridic parts of thc Tethys and the postorogenic evolution of the Paratethys and the Pannonian Basin, respectively.

  19. Andosols of Georgia

    Urushadze, T. F.; Blum, W. E. H.; Sanadze, E. V.; Kvrivishvili, T. O.


    Andosols formed on andesite-basalts, andesite, diabase, and dolerite in the central part of the Adzhar-Trialet Ridge are studied. Their morphological features and some chemical properties are characterized. The soils are diagnosed according to the World Reference Base for Soil Resources (WRB). The soil bulk density, the contents of oxalate-soluble R2O3, adsorbed phosphates, and organic carbon are determined. It is shown that vitric and andic diagnostic features predominate in the investigated soils. According to the adopted classification, these soils are classified as mountain meadow soils. Their morphological features and chemical characteristics correspond to those of Andosols, one of the soil groups in the WRB. It can be expected that these soils are developed in some other regions of volcanic activity in Georgia.

  20. Hydrogeology of Basins on Mars

    Arvidson, Raymond E.


    This document summarizes the work accomplished under NASA Grant NAG5-3870. Emphasis was put on the development of the FIDO rover, a prototype for the twin-Mers which will be operating on the surface of Mars in 2004, specifically the primary work was the analysis of FIDO field trials. The grantees also analyzed VIKING Lander 1 XRFS and Pathfinder APXS data. Results show that the Viking site chemistry is consistent with an andesite, and the Pathfinder site is consistent with a basaltic andesite. The grantees also worked to demonstrate the capability to simulate annealing methods to apply to the inversion of remote sensing data. They performed an initial analyses of Sojourner engineering telemetry and imaging data. They performed initial analyses of Viking Lander Stereo Images, and of Hematite deposits in Terra Meridiani. They also acquired and analyzed the New Goldstone radar data.

  1. New Insights to the Mid Miocene Calc-alkaline Lavas of the Strawberry Volcanics, NE Oregon Surrounded by the Coeval Tholeiitic Columbia River Basalt Province

    Steiner, A. R.; Streck, M. J.


    The Strawberry Volcanics (SV) of NE Oregon were distributed over 3,400 km2 during the mid-Miocene and comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The predominant composition of this volcanic suite is calc-alkaline (CA) basaltic andesite and andesite, although tholeiitic (TH) lavas of basalt to andesite occur as well. The coeval flood basalts of the Columbia River province surround the SV. Here we will discuss new ages and geochemical data, and present a new geologic map and stratigraphy of the SV. The SV are emplaced on top of pre-Tertiary accreted terranes of the Blue Mountain Province, Mesozoic plutonic rocks, and older Tertiary volcanic rocks thought to be mostly Oligocene of age. Massive rhyolites (~300 m thick) are exposed mainly along the western flank and underlie the intermediate composition lavas. In the southern portion of this study area, alkali basaltic lavas, thought to be late Miocene to early Pliocene in age, erupted and overlie the SV. In addition, several regional ignimbrites reach into the area. The 9.7 Ma Devine Canyon Tuff and the 7.1 Ma Rattlesnake Tuff also overlie the SV. The 15.9-15.4 Ma Dinner Creek Tuff is mid-Miocene, and clear stratigraphic relationships are found in areas where the tuff is intercalated between thick SV lava flows. All of the basalts of the SV are TH and are dominated by phenocryst-poor (≤2%) lithologies. These basalts have an ophitic texture dominated by plagioclase, clinopyroxene and olivine (often weathered to iddingsite). Basalts and basaltic andesites have olivine Fo #'s ranging from 44 at the rims (where weathered to iddingsite) and as high as 88 at cores. Pyroxene Mg #'s range from 65 to 85. Andesites of the SV are sub-alkaline, and like the basalts, are exceedingly phenocryst-poor (≤3%) with microphenocrysts of plagioclase and lesser pyroxene and olivine, which occasionally occur as crystal clots of ~1-3 mm instead of single crystals. In addition, minimal

  2. Multiple shallow level sill intrusions coupled with hydromagmatic explosive eruptions marked the initial phase of Ferrar large igneous province magmatism in northern Victoria Land, Antarctica

    Viereck-Goette, L.; Schöner, R.; Bomfleur, B.; Schneider, J.


    Field data gathered during GANOVEX IX (2005/2006) in Northern Victoria Land, Antarctica, indicate that volcaniclastic deposits of phreatomagmatic eruptions (so-called Exposure Hill Type events) are intercalated with fluvial deposits of Triassic-Jurassic age at two stratigraphic levels. Abundant scoriaceous spatter (locally welded) indicates a hawaiian/strombolian component. Breccia-filled diatremes, from which volcaniclastic deposits were sourced, are rooted in sills which intruded wet sediments. The deposits are thus subaerial expressions of initial Ferrar magmatism involving intrusion of multiple shallow-level sills. Due to magma-sediment interaction abundant clastic dikes are developed that intrude the sediments and sills. All igneous components in the volcaniclastic deposits are andesitic in composition, as are the chilled margins of the sills. They are more differentiated than the basaltic andesites of the younger effusive section of Kirkpatrick plateau lavas which in northern Victoria Land start with pillow lavas and small volume lava flows from volcanic necks.

  3. Geology and tectonic magmatic of emplacement of a longitudinal dyke swarm of Nico Perez(Minas) URUGUAY

    The Mina Verdun Group (Precambrian) was deposited prior to the subvolcanic emplacement of a longitudinal dyke swarm of basaltic to andesitic composition (Minas Subvolcanic Swarm of the Mina Verdun quarry - Nico Perez Terrane, Minas, Uruguay). The swarm and its country rocks predated a tectono-metamorphic event that produced fragileductile shear zones associated with very low- to low-grade dislocation metamorphism. We interpreted a K-Ar whole rock datum of 485,2 ± 12,5 Ma (andesitic dyke) as a minimum cooling age in relation with late- to post-swarm emplacement deuteric alteration stage. Another K-Ar whole rock datum of 108,5 ± 2,9 Ma on a basaltic dyke was assumed here as a degasification stage, while its geological meaning is still matter of debate. The Minas Subvolcanic Dyke Swarm was intruded at high crustal levels, suggesting that the Minas region was affected by a period of extensional tectonics

  4. Partition coefficients of Hf, Zr, and REE between zircon, apatite, and liquid

    Fujimaki, H.


    Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10-100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. ?? 1986 Springer-Verlag.

  5. Late Holocene tephrochronology of the northern Antarctic Peninsula

    Björck, Svante; Sandgren, Per; Zale, Rolf


    Andesitic and basaltic andesitic tephra layers are abundant in Holocene deposits from the Antarctic Peninsula. Visually discernible tephra horizons occur in three lakes on Livingston Island. Tephra in two other lakes and in a moss bank on Elephant Island, with very low ash concentrations, were detected magnetically. Deception Island is the most likely volcanic source for the tephra. With direct 14C dating, age/depth curves, and cross-correlations at least 14 tephra horizons dating to between ca. 4700 and 250 yr B.P. were identified and now form the basis for a preliminary regional tephrochronology that will be a valuable dating tool for investigating the Holocene climatic history of Antarctica.

  6. K-Ar ages of dike rocks in the southwestern region of Aso caldera, Kyushu, Japan

    Aso is a large caldera volcano in Kyushu, Japan. Several dikes, which cut the Pre-Aso volcanic rocks, are exposed in the southwestern region of the caldera (Ono and Watanabe, 1985). The dikes, trending NE-SW and N-S, are composed of pyroxene andesite and hornblende andesite. Systematic relation between the rocks type and direction of the dikes in not observed. In this study, K-Ar ages have been determined on these dike rocks. The ages of dike rocks range from ca. 0.8 to 0.5 Ma, being consistent with the ages of the Pre-Aso volcanic rocks at the caldera wall. There are no significant relations between the ages and the rock type. Except for one sample with weak alteration, the diskes trending NE-SW are older than those of N-S, suggesting a change of direction of the maximum pressure axis of regional stress in the volcanism. (author)

  7. Zeolitización de rocas andesíticas

    Plana, F.


    Full Text Available The study of some andesites from King George Island (South Shetland Islands, Anctartica has pointed out the existence of a hydrothermal alteration process going rise to a zeolitic secondary minerals of low-temperature assemblages. Two paragenesis have been identified (Smectite-Bytownite-Mordenite, Smectite-Albite-Laumontite which reflecting different conditions durign the hydrothermal alteration of these andesitic rocksEl estudio de rocas andesíticas de la Isla King George (Archipiélago de las Shetland del Sur, Antártida pone de manifiesto la existencia de procesos de alteración hidrotermal con la formación de minerales zeolíticos secundarios pertenecientes a asociaciones de baja temperatura. Se han identificado dos paragénesis (Esmectitas-Bytownita-Mordenita, Esmectitas-AlbitaLaumontita que reflejan distintas condiciones durante la alteración hidrotermal de dichas rocas andesíticas.

  8. Chemical and isotopic composition of the gaseous and solid products of the eruptive activity of Krakatau (Indonesia) between 1978 and 1980

    Between 1978 and 1980, a new eruptive cycle developed at Anak Krakatau. High-temperature gases and lavas were collected. The 13C/12C ratio of CO2 suggests that this volcano releases carbon of mantle-derivation. Lavas have a typical andesitic composition, which points out that the magma underwent a significant differenciation since the birth of the volcano, in 1928. This trend supports the earlier observations of Van Bemmelen and is tentatively interpreted in terms of cristal fractionation

  9. Late Neoproterozoic Nuqara Dokhan Volcanics, Central Eastern Desert, Egypt: Geochemistery and petrogenesis

    Hassan, Tharwat; Asran, Asran; Amron, Taha; Natflos, Theo


    The Nuqara volcanic is one of the northernmost outcrops of the Arabian-Nubian Shield Dokhan volcanics. The origin and tectonic setting of the late Neoproterozoic Dokhan volcanics (ca. 610-560 Ma) in the Egyptian Eastern Desert is highly debated. The debate concerns the tectonic setting where they formed during transition between convergent to extensional regime or after the East- and the West-Gondwana collision (~600Ma). In order to solve this problem, lavas from Nuqara area were studied geologically and geochemically. Nuqara Dokhan volcanics comprises two main rock suites: (a) an intermediate volcanic suite, consisting of basaltic andesite, andesite and their associated pyroclastics rocks; and (b) a felsic volcanic suite composed of dacite, rhyolite and ignimbrites. The two suites display well-defined major and trace element trends and continuum in composition with wide ranges in SiO2 (52-75.73%), CaO (9.19-0.22%), MgO (5.29-0.05%), Sr (1367-7.4 ppm), Zr (688.5-172.7 ppm), Cr (207-0.4 ppm), and Ni (94.3-0.2 ppm). The Nuqara Dokhan volcanics are characterized by strong enrichment in LILE relative to HFSE and affiliated to the calc-alkaline subducted - related magmatism. Geochemical Modeling displays that the evolution of these rocks was governed by fractional crystallization of plagioclase, amphiboles, pyroxene, magnetite and apatite in the intermediate varieties and plagioclase, amphibole, magnetite, apatite and zircon in the felsic varieties. The obtained mineral chemistry of these volcanics reveals: (a) Plagioclase range in composition from An55 to An40 in basaltic andesite and from An39 to An24 in andesite. (b) Alkali feldspars have sanidine composition. (c) Clinopyroxenes have augite composition. The low Al2O3 contents (1.94-5.588 wt %) indicate that clinopyroxene crystallized at low - pressure conditions. (d) Amphiboles have magnesio- hornblende composition.

  10. Stratigraphy and eruption age of the volcanic rocks in the west of Miyanoharu area, Kumamoto Prefecture

    The detailed stratigraphic survey, K-Ar age determinations and NRM measurements of the volcanic rocks in the west of Miyanoharu area revealed the volcanic history as follows: Hornblende andesite lava with plagioclase megacryst (Yoshinomoto lava) erupted during 2.8 - 2.5 Ma (Gauss normal epoch), accompanied by small amount of pyroclastic materials. After this eruption, Kamitarumizu hypersthene-augite andesite lava (1.7 - 1.3 Ma; reversed), Yabakei pyroclastic flow (0.99 Ma; Jaramillo normal event), Yamakogawa biotite rhyolite lava (0.9 Ma; reversed) and Daikanbo hypersthene-augite andesite lava (0.8 Ma; normal) erupted successively prior to the Aso-1 pyroclastic flow (0.3 - 0.4 Ma). Both the K-Ar ages and NRM data are consistent with the stratigraphic sequence (Fig. 2), which suggests that the activity of andesite and rhyolite is intercalated with each other during Pleistocene in the studied area. The compiled radiometric age data in the central-north Kyushu show that the age of volcanic activity that has previously been inferred as middle Miocene is of Pliocene, and its distribution is limited within the quadrilateral (60 km x 40 km) where the pre-Tertiary basement rocks are absent. The distribution of volcanic rocks is historically zonated such that the rocks of older age up to 5 Ma develop toward the outer rim of the quadrilateral, which coincides with the 0 mgal contour bordering the large low Bouguer anomaly. These facts suggest that the volcanic activity is remarkably relevant to the subsidence of this area, where the volcano-tectonic depression has been formed after 5 Ma to the present, and filled with lavas and pyroclastic materials with scarce sedimentary rocks in the tension stress field during Plio-Pleistocene age. (Kubozono, M.)

  11. Volcanic Markers of the Post-Subduction Evolution of Baja California and Sonora, Mexico: Slab Tearing Versus Lithospheric Rupture of the Gulf of California

    Calmus, Thierry; Pallares, Carlos; Maury, René C.; Aguillón-Robles, Alfredo; Bellon, Hervé; Benoit, Mathieu; Michaud, François


    Abstract?The study of the geochemical compositions and K-Ar or Ar-Ar ages of ca. 350 Neogene and Quaternary lavas from Baja California, the Gulf of California and Sonora allows us to discuss the nature of their mantle or crustal sources, the conditions of their melting and the tectonic regime prevailing during their genesis and emplacement. Nine petrographic/geochemical groups are distinguished: ??regular' calc-alkaline lavas; adakites; magnesian andesites and related basalts and basaltic and...

  12. Eocene volcanism during the incipient stage of Izu–Ogasawara Arc: Geology and petrology of the Mukojima Island Group, the Ogasawara Islands.

    Kanayama, Kyoko; Umino, Susumu; Ishizuka, Osamu


    The Ogasawara Islands mainly comprise Eocene volcanic strata formed when the Izu-Ogasawara-Mariana Arc began. We present the first detailed volcanic geology, petrography and geochemistry of the Mukojima Island Group, northernmost of the Ogasawara Islands, and show that the volcanic stratigraphy consists of arc tholeiitic rocks, ultra-depleted boninite-series rocks, and less-depleted boninitic andesites, which are correlatable to the Maruberiwan, Asahiyama and Mikazukiyama Formations on the Ch...

  13. Micromorphological Characterization of Some Volcanic Soil In West Java

    Mahfud Arifin; Rina Devnita

    2014-01-01 characterization has been studied on six pedons of soils developing in volcanic materials in West Java. The pedons represent deposits of different volcanoes (Mount Tangkuban Perahu, Mount Patuha and Mount Papandayan) with different ages (Pleistocene, Holocene) within two types of volcanisms (andesitic, basaltic), and three agroclimatic zones (A, B1, B2). Undisturbed soil samples were taken from each identifiable horizon for thin ...

  14. Effects of water-saturation on strength and ductility of three igneous rocks at effective pressures to 50 MPa and temperatures to partial melting

    Bauer, S.J.; Friedman, M.; Handin, J.


    Instantaneous-failure strengths and ductilities of water-saturated cylindrical specimens of Charcoal Granodiorite, Mount Hood Andesite, and Cuerbio Basalt are determined at a strain rate of 10{sup -4}s{sup -1} and at effective confining pressures (Pe) of 0 and 50 MPa and at temperatures to partial melting. The data indicate: (1) at Pe = 0 and 50 MPa (Pc and Pp of 50 MPa and of 100 and 50 MPa, respectively) the granodiorite does not water-weaken; (2) at these same Pe the more porous and finer-grained andesite begins to exhibit water-weakening at about 600/sup 0/C; (3) at Pe = 0 and 870-900{sup 0}C the andesite's wet strength averages 20 MPa compared to 100 MPa, dry; (4) at Pe = 50 MPa and 920{sup 0}C its wet strength is 45 MPa compared to 160 MPa dry; (5) at Pe = 0, the basalt appears to be water-weakened above 800{sup 0}C; (6) water-saturated specimens deformed at temperatures less than T{sub m} exhibit ultimate strengths at less than 2 percent shortening and then work-soften along faults; and (7) both dry and wet specimens deform primarily by brittle fracture. Extrapolations indicate: (1) crystalline rocks should be drillable because they remain brittle until partial melting occurs, and penetration rates should increase with temperature because there is a corresponding decrease in brittle fracture strength; (2) boreholes in ''water-filled'' holes will be stable to >10 km at temperatures 10 km; and (4) open boreholes in the andesite are apt to be much less stable, and at similar temperatures would fail at 2 to 5-km depth.

  15. Separation of supercritical slab-fluids to form aqueous fluid and melt components in subduction zone magmatism

    Kawamoto, Tatsuhiko; Kanzaki, Masami; Mibe, Kenji; Matsukage, Kyoko N.; Ono, Shigeaki


    Subduction-zone magmatism is triggered by the addition of H2O-rich slab-derived components: aqueous fluid, hydrous partial melts, or supercritical fluids from the subducting slab. Geochemical analyses of island arc basalts suggest two slab-derived signatures of a melt and a fluid. These two liquids unite to a supercritical fluid under pressure and temperature conditions beyond a critical endpoint. We ascertain critical endpoints between aqueous fluids and sediment or high-Mg andesite (HMA) me...

  16. Petrology, mineral chemistry and tectono-magmatic setting of volcanic rocks from northeast Farmahin, north of Arak

    Reza Zarei Sahamieh; Sara Ebrahimi


    Introduction The study area is a small part of the Urumieh-Dokhtar structural zone in the Markazi province, located in the northeastern part of the Farmahin, north of Arak (Hajian, 1970). The volcanic rocks studied from the area include andesite, dacite, rhyodacite, ignimbrite and tuff of Middle to Late Eocene age (middle Lutetian to upper Lutetian) (Ameri et al., 2009). It seems that folding and faulting is caused in sedimentary basin and volcanic activities. On the other hand, except of ...

  17. Airborne dust transport to the eastern Pacific Ocean off southern California: Evidence from San Clemente Island

    Muhs, D.R.; Budahn, J.; Reheis, M.; Beann, J.; Skipp, G.; Fisher, E.


    Islands are natural dust traps, and San Clemente Island, California, is a good example. Soils on marine terraces cut into Miocene andesite on this island are clay-rich Vertisols or Alfisols with vertic properties. These soils are overlain by silt-rich mantles, 5-20 cm thick, that contrast sharply with the underlying clay-rich subsoils. The silt mantles have a mineralogy that is distinct from the island bedrock. Silt mantles are rich in quartz, which is rare in the island andesite. The clay fraction of the silt mantles is dominated by mica, also absent from local andesite, and contrasts with the subsoils, dominated by smectite. Ternary plots of immobile trace elements (Sc-Th-La and Ta-Nd-Cr) show that the island andesite has a composition intermediate between average upper continental crust and average oceanic crust. In contrast, the silt and, to a lesser extent, clay fractions of the silt mantles have compositions closer to average upper continental crust. The silt mantles have particle size distributions similar to loess and Mojave Desert dust, but are coarser than long-range-transported Asian dust. We infer from these observations that the silt mantles are derived from airborne dust from the North American mainland, probably river valleys in the coastal mountains of southern California and/or the Mojave Desert. Although average winds are from the northwest in coastal California, easterly winds occur numerous times of the year when "Santa Ana" conditions prevail, caused by a high-pressure cell centered over the Great Basin. Examination of satellite imagery shows that easterly Santa Ana winds carry abundant dust to the eastern Pacific Ocean and the California Channel Islands. Airborne dust from mainland North America may be an important component of the offshore sediment budget in the easternmost Pacific Ocean, a finding of potential biogeochemical and climatic significance.

  18. Cogenetic late Pleistocene rhyolite and cumulate diorites from Augustine Volcano revealed by SIMS 238U-230Th dating of zircon, and implications for silicic magma generation by extraction from mush

    Coombs, Michelle L.; Vazquez, Jorge A.


    Volcano, a frequently active andesitic island stratocone, erupted a late Pleistocene rhyolite pumice fall that is temporally linked through zircon geochronology to cumulate dioritic blocks brought to the surface in Augustine's 2006 eruption. Zircon from the rhyolite yield a 238U-230Th age of ˜25 ka for their unpolished rims, and their interiors yield a bimodal age populations at ˜26 ka and a minority at ˜41 ka. Zircon from dioritic blocks, ripped from Augustine's shallow magmatic plumbing system and ejected during the 2006 eruption, have interiors defining a ˜26 ka age population that is indistinguishable from that for the rhyolite; unpolished rims on the dioritic zircon are dominantly younger (≤12 ka) indicating subsequent crystallization. Zircon from rhyolite and diorite overlap in U, Hf, Ti, and REE concentrations although diorites also contain a second population of high-U, high temperature grains. Andesites that brought dioritic blocks to the surface in 2006 contain zircon with young (≤9 ka) rims and a scattering of older ages, but few zircon that crystallized during the 26 ka interval. Both the Pleistocene-age rhyolite and the 2006 dioritic inclusions plot along a whole-rock compositional trend distinct from mid-Holocene-present andesites and dacites, and the diorites, rhyolite, and two early Holocene dacites define linear unmixing trends often oblique to the main andesite array and consistent with melt (rhyolite) extraction from a mush (dacites), leaving behind a cumulate amphibole-bearing residue (diorites). Rare zircon antecrysts up to ˜300 ka from all rock types indicate that a Quaternary center has been present longer than preserved surficial deposits.

  19. Behaviour of major, minor and trace elements (including REEs) during kaolinization processes at Zonouz deposit, northeast of Marand, East Azarbaidjan province

    Vahideh Alipour; Ali Abedini


    The Zonouz kaolin deposit is located ~15 km northeast of Marand, East-Azarbaidjan province. Based on physical features in field investigations, such as color, five distinct kaolin types including (1) white, (2) lemon, (3) gray, (4) brown, and (5) yellow are distinguished in the deposit. Field evidence and petrographic studies indicate that the deposit is genetically close to trachy-andesite rocks. According to mineralogical data, the deposit contains quartz, kaolinite, montmorillonite, calcit...

  20. The age and constitution of Cerro Campanario, a mafic stratovolcano in the Andes of central Chile

    Hildreth, W.; Singer, B.; Godoy, E.; Munizaga, F.


    Cerro Campanario, a towering landmark on the continental divide near Paso Pehuenche, is a glacially eroded remnant of a mafic stratovolcano that is much younger than previously supposed. Consisting of fairly uniform basaltic andesite, rich in olivine and plagioclase, the 10-15 km3 edifice grew rapidly near the end of the middle Pleistocene, about 150-160 ka, as indicated by 40Ar/39Ar and unspiked K-Ar analyses of its lavas.

  1. Tree-mould caves in Slovakia.

    Gaal Ludovit


    Four tube-shaped caves are described in this work, which origined in consequence of weathering the trees. Their length ranges from 5.8 to 17 m. All of them occur in neovolcanic rocks of Middle Slovakia, in epiclastic andesite conglomerates, breccias or in the tuffs. Some other caverns are close to the entrance of this caves, however they are inaccessible for a man. Thin rim of silicates (opal or chalcedony) occurs in some of them.

  2. Paleomagnetism of Rocks from the Island of Viti Levu, Fiji

    YASKAWA, Katsumi; INOKUCHI, Hiroo; MATSUDA, Jun-ichi; TAKAHASHI, Shinji; ISEZAKI, Nobuhiro; MIYATA, Takao; Rao, Bhaskar; Rodda, Peter; ヤスカワ, カツミ; イノクチ, ヒロオ; マツダ, ジュンイチ; タカハシ, シンジ; イセザキ, ノブヒロ; ミヤタ, タカオ


    Samples were collected at 19 sites in basalts, andesites, dacites, gabbros, sandstones and limestones in the island of Viti Levu. They were dated at about 4 to 40 Ma. New age data have been added in 2 sites. After partial demagnetization by alternating fields to remove unstable components of magnetization, the directions of magnetization became well grouped except for the rocks from a few sites. Both normal and reversed directions are present. The volume susceptibility of each specimen has al...

  3. The Mt. Read Volcanics: strontium and neodymium isotope geochemistry

    Strontium and neodymium isotope analysis have been carried out in an attempt to answer some of the questions relevant to the genesis of the Mt. Reid Volcanics and their contained ores. The isotope geochemistry of the low-grade metamorphosed basalt-andesite-dacite-rhyolite suite reveals a complex interaction between mantle and crust, with both isotopes highlighting the importance of the crustal component as a potential ore source. 4 refs., 2 figs

  4. Giant magmatic water reservoir beneath Uturuncu volcano and Altiplano-Puna region (Central Andes)

    Laumonier, Mickael; Gaillard, Fabrice; Muir, Duncan; Blundy, Jon; Unsworth, Martyn


    Volcanism at continental arcs is the surface manifestation of long-lived crustal magmatic processes whereby mantle-derived hydrous basalt magma differentiates to more silica-rich magmas by a combination of crystallization and crustal melting. What erupts is just a fraction of the total volume of magma produced by these processes; the unerupted, plutonic residues solidify and are inaccessible to direct study until millions of years of uplift and erosion bring them to the surface. In contrast, geophysical surveys, using electromagnetic and seismic waves, can provide real-time images of subduction zone magmatic systems. Several such studies have revealed that arc volcanoes are underlain by large partially molten regions at depths of >10 km, the largest known example being the Altiplano-Puna magma body (APMB) in central Andes. Interpreting such geophysical images in terms of amount, composition and distribution of partial melts is limited by our lack of knowledge of the physical properties of silicate melts at elevated pressures and temperatures. Here we present high-pressure, in situ experimental data showing that the electrical conductivity of andesitic melts is primarily controlled by their dissolved water contents. Linking our new measurements to petrological constraints from andesites erupted on the Altiplano, we show that the APMB is composed of 10-20% of an andesitic melt containing 8-10 wt% dissolved water. This implies that the APMB is a giant water anomaly in the global subduction system, with a total mass of dissolved magmatic water about half of the water contained within the Adriatic Sea. In addition to the controls on the physical properties of the melts, the abundance of dissolved water governs the structural levels of magma ponding, equivalent to the depth of water saturation, where degassing and crystallisation promote partial melting and weakening of the upper crust. Unexpectedly, very high concentrations of water in andesite magmas shall impede their

  5. Geochemical constraints on the evolution of mafic and felsic rocks in the Bathani volcanic and volcano-sedimentary sequence of Chotanagpur Granite Gneiss Complex

    Saikia, Ashima; Gogoi, Bibhuti; Ahmad, Mansoor; Ahmad, Talat


    The Bathani volcanic and volcano-sedimentary (BVS) sequence is a volcanic and volcano-sedimentary sequence, best exposed near Bathani village in Gaya district of Bihar. It is located in the northern fringe of the Chotanagpur Granite Gneiss Complex (CGGC). The volcano-sedimentary unit comprises of garnet-mica schist, rhyolite, tuff, banded iron formation (BIF) and chert bands with carbonate rocks as enclaves within the rhyolite and the differentiated volcanic sequence comprises of rhyolite, andesite, pillow basalt, massive basalt, tuff and mafic pyroclasts. Emplacement of diverse felsic and mafic rocks together testifies for a multi-stage and multi-source magmatism for the area. The presence of pillow basalt marks the eruption of these rocks in a subaqueous environment. Intermittent eruption of mafic and felsic magmas resulted in the formation of rhyolite, mafic pyroclasts, and tuff. Mixing and mingling of the felsic and mafic magmas resulted in the hybrid rock andesite. Granites are emplaced later, cross-cutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and calc-alkaline affinities of andesite, rhyolite and granite is consistent with their generation in an island arc, subduction related setting. The rocks of the BVS sequence probably mark the collision of the northern and southern Indian blocks during Proterozoic period. The explosive submarine volcanism may be related to culmination of the collision of the aforementioned blocks during the Neoproterozoic (1.0 Ga) as the Grenvillian metamorphism is well established in various parts of CGGC.

  6. Phase Segmentation of X-Ray Computer Tomography Rock Images using Machine Learning Techniques: an Accuracy and Performance Study

    Chauhan, Swarup; Rühaak, Wolfram; Anbergen, Hauke; Kabdenov, Alen; Freise, Marcus; Wille, Thorsten; Sass, Ingo


    Performance and accuracy of machine learning techniques to segment rock grains, matrix and pore voxels, from a 3D volume of X-ray tomographic (XCT) grey-scale rock images was evaluated. The segmentation and classification capability of unsupervised (k-means, fuzzy c-means, self-organized maps), supervised (artificial neural networks, least square support vector machines) and ensemble classifiers (bragging and boosting) was tested using XCT images of Andesite volcanic rock, Berea sandstone, Ro...

  7. 水田,畑,樹園地土壌化学性の因子分析による対比 : 佐賀県と熊本県農耕地土壌の事例

    江頭, 和彦


    Soil chemical properties of the surface horizon were compared between paddy, upland and orchard fields by conducting factor analysis on analytical data for agricultural lands of Saga and Kumamoto prefectures. Soils of Saga prefecture were mainly derived from alluvial marine or fluvial sediment in the paddy field and from granite or andesite in the orchard field. Factor analysis for agricultural lands of Saga prefecture reduced 11 variables (pH, total carbon and nitrogen, cation exchange capac...

  8. 水蒸気圧下の岩石の強度特性

    鄭, 海植; 尾原, 祐三; 菅原, 勝彦; オバラ, ユウゾウ; スギワラ, カツヒコ; Jeong, Hae-Sik; Obara, Yuzo; Sugiwara, Katsuhiko


    In order to investigate the environmental dependence on strength of rock, uniaxial compression test and Brazilian test under water vapor environment were conducted on Kumamoto andesite and Kitagishima granite. Tests were carried out under various water vapor pressures, which are controlled in special chambers, at a constant strain rate. The results obtained by the uniaxial compression test and Brazilian test are follows:The Young's moduli are almost constant with the change of water vapor pre...

  9. 非大気環境下における熊本安山岩の強度特性

    鄭, 海植; 尾原, 祐三; オバラ, ユウゾウ; Jeong, Hae-Sik; Obara, Yuzo


    The uniaxial compression tests and Brazil tests in non-atmospheric environments were conducted on Kumamoto andesite to investigate the environmental dependence on strength of rock. The environments used in the experiment were organic vapor environments as methanol, ethanol and acetone, inorganic gas environments as argon, nitrogen and oxygen and water vapor environment.The obtained results are as follows:1. From the uniaxial compression test, it was clear that the uniaxial compressive strengt...

  10. Composition and origin of aeolian and fluvial sands of Gavkhuni playa lake (southeast of Isfahan)

    H.R., Pakzad,; Van, M. A.; M., Pasandi,; Z., Aliniaie,


    Gavkhuni playa lake, located 130 km southeast of Isfahan, comprises of sand, mud and salt flats. This playa includes two environments as delta and playa lake. Sand dunes, 45 kilometers long, extend in the west of the playa. Rock fragments of andesite, dacite, tuff, granite, schist, gneiss, fossil bearing limestone, sandstone and also quartz and feldspar minerals form the alluvial and aeolian sediments. Heavy minerals including idocrase, tourmaline, biotite, wollastonite, magnetite, hematite, ...

  11. Low-K Tholeiitic Signatures in Calayan Island (Northern Luzon, Philippines)

    Pendón, R. R.; Corretgé, Luis Guillermo; Ordaz, J.


    The Calayan island is a Tertiary (7-4 Ma) volcanic island situated in the northern portion of the Philippine archipelago, a part of Babuyan segment of the Luzon arc. It is a product of subduction of South China Sea oceanic crust underneath the Philippine terrane. Rock spectrum in the island ranges from basalt to rhyolite with andesite as the most predominating lava. Geochemical signatures are characterized by low concentrations of large-ion lithophile and flat behavior of rare-earth elements,...

  12. Geological and Petrological Characteristics of Oligocene Magmatic Rocks in The Biga Peninsula, NW Turkey

    Erenoglu, Oya


    Oligocene magmatic activity in the Biga Peninsula (NW-Anatolia) produced widespread volcano-plutonic complexes. The study region, where in north of the Evciler village in the middle of Biga Peninsula includes these igneous assemblages. In this study, the petrographic and geochemical characteristics of igneous rocks in the region were investigated as well as the geological locations. The magmatic rocks are classified as 6 different units using their lithostratigraphical properties. The volcanism in the region starts with basaltic andesite lava including basalt dykes in the Lower Oligocene. In the Upper Oligocene, the evolved magma by crustal contamination produced commonly dacitic and andesitic lavas. The volcanism continued with andesitic lavas which had significant alterations in the region during this period. Evciler pluton including granite and granodiorite composition with shallow intrusive, was located with the related volcanism at the same time. The volcanic products, i.e. andesitic and trachydacitic lavas, was completed in the interval between Upper Oligocene and Lower Miocene. The post-collisional Oligocene sequence is associated with calc-alkaline composition and it has middle, high-K. Trace and rare earth elements (REE) diagrams show the enrichment in both large-ion lithophile elements (LILE) and light rare earth elements (LREE) with respect to the high field strength elements (HFSE), and a significant increment in heavy rare earth element consumption (HREE). The features of major, trace and rare earth elements of plutonic and volcanic rocks and the compositional variations of Oligocene volcanic group indicate increasing amounts of partial melting, crustal contamination and/or assimilation. The Oligocene post-collisional volcanism in Biga Peninsula points out the lithospheric mantle source enriched by subduction which controlled by slab break-off and lithospheric delamination. Acknowledgement. This study was supported by Canakkale Onsekiz Mart University

  13. Microscopic Rocks and Expansive Empires: Investigating Inca Ceramics from Cuzco, Peru

    Rob Ixer; Sara Lunt; Bill Sillar; Patrick Thompson


    High quality polychrome ceramics are an iconic aspect of Inca material culture. This ‘Cuzco Inca’ pottery appears suddenly in the archaeological record: but it draws upon technological and stylistic aspects of earlier local pottery and we discuss the specifics of how these pre-Inca traits were combined to form the distinctive new state ceramics. Using ceramic petrography, the dominant fabric of Cuzco Inca pottery is compared with those of two pre-Inca wares, Killke and Lucre. Andesite temper,...

  14. Post-middle Miocene accretion of Franciscan rocks, northwestern California.

    McLaughlin, R.J.; Kling, S.A.; Poore, R.Z.; McDougall, K.; Beutner, E.C.


    Deformed sedimentary rocks assigned to the Franciscan assemblage in the King Range S of Cape Mendocino, N California, are dominantly deep-water argillite and sandstone occurring as thick- to thin-bedded, locally channelized marine turbidities of arkosic to andesitic volcaniclastic composition. The King Range appears to be a displaced terrane of oceanic basement overlain by Palaeogene(?) and Neogene sedimentary and igneous rocks of continental and oceanic derivation.-Authors

  15. Geochemical constraints on the evolution of mafic and felsic rocks in the Bathani volcanic and volcano-sedimentary sequence of Chotanagpur Granite Gneiss Complex

    Ashima Saikia; Bibhuti Gogoi; Mansoor Ahmad; Talat Ahmad


    The Bathani volcanic and volcano-sedimentary (BVS) sequence is a volcanic and volcano-sedimentary sequence, best exposed near Bathani village in Gaya district of Bihar. It is located in the northern fringe of the Chotanagpur Granite Gneiss Complex (CGGC). The volcano-sedimentary unit comprises of garnet-mica schist, rhyolite, tuff, banded iron formation (BIF) and chert bands with carbonate rocks as enclaves within the rhyolite and the differentiated volcanic sequence comprises of rhyolite, andesite, pillow basalt, massive basalt, tuff and mafic pyroclasts. Emplacement of diverse felsic and mafic rocks together testifies for a multi-stage and multi-source magmatism for the area. The presence of pillow basalt marks the eruption of these rocks in a subaqueous environment. Intermittent eruption of mafic and felsic magmas resulted in the formation of rhyolite, mafic pyroclasts, and tuff. Mixing and mingling of the felsic and mafic magmas resulted in the hybrid rock andesite. Granites are emplaced later, crosscutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and calc-alkaline affinities of andesite, rhyolite and granite is consistent with their generation in an island arc, subduction related setting. The rocks of the BVS sequence probably mark the collision of the northern and southern Indian blocks during Proterozoic period. The explosive submarine volcanism may be related to culmination of the collision of the aforementioned blocks during the Neoproterozoic (1.0 Ga) as the Grenvillian metamorphism is well established in various parts of CGGC.

  16. International Uranium Resources Evaluation Project (IUREP) national favourability studies: Taiwan

    Taiwan is an island of 36,000 sq km located 160 km east of mainland China. Geologically, the oldest rocks are Tertiary, and the only igneous rocks on the island are Quaternary andesites and basalts. Copper, gold, and silver are the only known metallic minerals produced. Uranium occurrences and exploration efforts are unknown. The potential uranium resource of Taiwan is considered a category 1 resource. (author)

  17. Strontium isotope systematics of experimentally produced melts: understanding magma-carbonate interaction at Merapi volcano, Indonesia

    DEEGAN, F.M.; Uppsala University, Uppsala, Sweden; Troll, V. R.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma1, Roma, Italia; Freda, C.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma1, Roma, Italia; MCLEOD, C.; Durham University, Durham, United Kingdom; MALARKEY, J.; Durham University, Durham, United Kingdom; DAVIDSON, J.P.; Durham University, Durham, United Kingdom; CHADWICK, J.P.; Vrije Universiteit, Amsterdam, Netherlands


    There is considerable evidence for ongoing, late-stage interaction between the magmatic system at Merapi volcano, Indonesia, and local crustal carbonate. In order to resolve the interaction processes in detail, we have performed a series of time-variable carbonate dissolution experiments in silicate melt using Merapi basaltic-andesite and local limestone as starting materials, at magmatic pressure and temperature. Major element profiling of the experimental products has identified strongly co...

  18. Petro-structural study of volcano-plutonic rocks of Yaoure Mountains: Contribution to understanding the metallotectic gold mineralization (Central Côte d'Ivoire)

    Barthelemy Gnammytchet KOFFI; Gbele Ouattara; Alain Nicaise KOUAMELAN; Jean Paul DEROIN


    The petrographic study of rocks and some few outcrops revealed the great diversity of volcano-plutonic formations. Indeed, magmatism of the Yaouré Mountains is quite differentiated, ranging from basic terms (basalts) to acidic terms (rhyolites), passing to neutral terms (rhyodacites, andesites and dacites). The study also identifies several varieties of plutonic igneous rocks, including diorites, granodiorites, gabbros and sub-volcanic (microgranites). Diorites and granodiorites are dykes or ...

  19. Geology, alteration, mineralization and geochemistry at south of Arghash (Neyshabour)

    Zahra Karimi Saeid Abadi; Seyed Ahmad Mazaheri; Mohammad Hassan Karimpour


    The Arghash area is located 45 km to southwest of Neyshabour. The subvolcanic rocks in the area consist of biotite hornblende quartz monzodiorite porphyry, hornblende biotite quartz monzodiorite porphyry, hornblende monzonite porphyry, biotite hornblende monzonite porphyry, monzodiorite porphyry and biotite quartz monzodiorite porphyry units. The volcanic rocks consist of hornblende biotite dacite, biotite hornblende dacite, and andesite and pillow lava. The plutonic rocks consist of hornblen...

  20. Mineralogy and REE geochemistry at Gomish-Tappeh Zn-Pb-Cu (Ag) deposit, southwest of Zanjan

    Tooba Salehi; Majid Ghaderi; Nematoolah Rashidnejad Omran


    Gomish-Tappeh Zn-Pb-Cu (Ag) deposit is located 90 km southwest of Zanjan, in northwestern part of Urumieh-Dokhtar volcano-plutonic zone. Exposed rocks at the area include Oligo-Miocene volcano-sedimentary and sedimentary sequences as well as Pliocene volcano-plutonic sequence (andesite porphyry dykes, dacitic subvolcanic dome and rhyodacitic volcanics). Alteration in the deposit developed as silicic, silicic-sulfidic, sericitic, carbonate, argillic and propylitic. Main mineralization at the G...

  1. Geology, alteration, age dating and petrogenesis of intrusive bodies in Halak Abad prospect area, NE Iran

    Maliheh Ghourchi; Mohammad Hassan Karimpour; J. Lang Farmer; Charles Stern


    The Halak Abad prospect occurs in the northeastern part of Central Iran zone (Sabzevar structural zone). In this investigation, geochemical evolution, age and source of part of northeastern Iran magmatic arc (intrusive bodies) in Halak Abad area in the Khorasan Razavi province has been studied. The exposed rocks consist of volcanic rocks with andesite and dacite nature, limestone, plutonic rocks mostly diorite, quartz diorite, monzodiorite, quartz monzonite, granodiorite and granite and sedim...

  2. Volcanic eruptions with little warning: the case of Volcán Reventador's Surprise November 3, 2002 Eruption, Ecuador

    Minard Hall; Patricio Ramón; Patricia Mothes; Jean Luc LePennec; Alexander García; Pablo Samaniego; Hugo Yepes


    Successful mitigation of a possible volcanic disaster depends upon the early detection of renewed volcanic activity. With considerable optimism, volcano observatories instrument dangerous volcanoes, with the hope of an early recognition of the reactivation of a volcano. Reventador volcano's November 3, 2002 eruption came with little warning and had a tremendous socio-economic impact. Reventador volcano, a young andesitic cone in the Eastern Cordillera of Ecuador, has had, at least, 16 eruptio...

  3. Significado de fábricas magnéticas en rocas volcánicas cuaternarias de la Isla Decepción (Shetland del Sur, Antártida)

    Gil Imaz, Andrés; Gil Peña, Inmaculada; Galindo Zaldívar, Jesús; Rey Salgado, Jorge; Maestro González, Adolfo; Pueyo Anchuela, Óscar; Soto Marín, Ruth; Oliva Urcia, Belén; López Martínez, Jerónimo


    This work deals with the magnetic fabric (AMS technique) of different lithotypes related to quaternary volcanism of Deception Island (South Shetland Islands). The studied rocks include lava flows from basaltic to basaltic-andesitic composition, mafic dykes and several types of pyroclastic deposits. By combining the analysis of parametric aspects of the magnetic ellipsoids and their directional pattern, four types of magnetic fabrics have been recognized. Type I fabrics are related...

  4. Petrographical and Geochemical Features of the Pelitli (Bayburt) Granitoid



    In this study, the granitoid rocks exposed in the Pelitli (Bayburt) area was investigated to determineits petrographical and geochemical characteristics. In the studied area located on the northernzone in the eastern Pontides, the basement is represented by Eocene aged andesite and pyroclastic rocks. These units are cut by the Eocene Pelitli Granitoid (46 Ma, U-Pb zircon) and are overlaine uncorformably by Quaternary alluvium. Pelitli Granitoid is in ellipse shape and settled approximate...

  5. Magma storage and plumbing of adakite-type post-ophiolite intrusions in the Sabzevar ophiolitic zone, northeast Iran

    Jamshidi, K.; H. Ghasemi; Troll, V. R.; M. Sadeghian; B. Dahren


    Subduction-related adakite-type intrusive rocks emplaced into the late Cretaceous–Paleocene Sabzevar ophiolite zone, northeast Iran, range from Mg-andesite to rhyodacite in composition. Here we investigate the magma supply system to these subvolcanic intrusive rocks by applying thermobarometric mineral and mineral–melt equilibrium models, including amphibole thermobarometry, plagioclase–melt thermobarometry and clinopyroxene–melt barometry. Based on the results of these ther...

  6. Magma storage and plumbing of adakite-type post-ophiolite intrusions in the Sabzevar ophiolitic zone, NE Iran

    Jamshidi, K.; H. Ghasemi; Troll, V. R.; M. Sadeghian; B. Dahren


    Subduction-related adakite-type intrusive rocks emplaced into the late Cretaceous-Paleocene Sabzevar ophiolite zone, NE Iran, range from Mg-andesite to rhyodacite in composition. Here we investigate the magma supply system to these subvolcanic intrusive rocks by applying thermobarometric mineral and mineral-melt equilibrium models, including amphibole thermobarometry, plagioclase-melt thermobarometry and clinopyroxene-melt barometry. Based on the results of ...

  7. Plio-Pleistocene intra-plate magmatism from the southern Sulu Arc, Semporna peninsula, Sabah, Borneo : implications for high-Nb basalt in subduction zones.

    Macpherson, C. G.; Chiang, K.K.; Hall, R; Nowell, G.M.; Castillo, P.R.; Thirlwall, M. F.


    New analyses of major and trace element concentrations and Sr, Nd and Pb isotopic ratios are presented for Plio-Pleistocene basalts and basaltic andesites from the Semporna peninsula in Sabah, Borneo, at the southern end of the Sulu Arc. Depletion of high field strength elements (HFSE), which is characteristic of many subduction-related magmatic suites, is present in more evolved Semporna rocks but is associated with radiogenic Sr and Pb, and less radiogenic Nd isotopic ratios and results fro...

  8. Oxygen-isotope and trace element constraints on the origins of silica-rich melts in the subarc mantle

    Eiler, J. M.; Schiano, P.; Valley, J. W.; Kita, N. T.; Stolper, E. M.


    Peridotitic xenoliths in basaltic andesites from Batan island in the Luzon arc contain silica-rich (broadly dacitic) hydrous melt inclusions that were likely trapped when these rocks were within the upper mantle wedge underlying the arc. These melt inclusions have been previously interpreted to be slab-derived melts. We tested this hypothesis by analyzing the oxygen isotope compositions of these inclusions with an ion microprobe. The melt inclusions from Batan xenoliths have δ 18OVSMOW values...

  9. Geochemistry of the mantle source and magma feeding system beneath Turrialba volcano, Costa Rica

    Di Piazza, A.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma1, Roma, Italia; Rizzo, A. l.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia; Barberi, F.; Università Roma Tre; Carapezza, M. L.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma1, Roma, Italia; De Astis, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione OV, Napoli, Italia; Romano, C.; Università Roma Tre; Sortino, F.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia


    Turrialba volcano lies in the southern sector of the Central American Volcanic Front (CAVF) in Costa Rica. The geochemistry of major and trace elements, and Sr and Nd isotopes of a selected suite of volcanic rocks ranging in composition from basaltic andesite to dacite and belonging to the last 10 ka of activity of Turrialba volcano is described, together with the He-, Ne-, and Ar-isotope compositions of fluid inclusions hosted in olivine and pyroxene crystals. Most of the variabi...

  10. Dep??sitos sil??ceos hidrotermales y alteraciones asociadas en sedimentos carbon??ticos del Tortoniense siiperior( Agua Amarga, Almer??a)

    Bustillo Revuelta, Mar??a ??ngeles; Aparicio, A.


    Hydrothermal silica deposits occur in a small fault (dike) as well as in several veins located in the contact between the andesitic volcanic rocks (8.1-8.7 M years old) and the biocalcarenites (Upper Tortonian-lower Messinian) of the Agua Amarga area. The silica deposits have different colours (green, blue, greyish, white, red or brown etc.) and luminosity (shiny or matt surfaces). Their mineralogy was determined by X-ray diffraction (XRD), while their textures and microstructures were examin...

  11. Influence of crushed stone aggregate type on concrete consistency

    Topličić-Ćurčić Gordana; Grdić Zoran; Despotović Iva; Ristić Nenad


    The main reason for usage of crushed stone mineral aggregate is need for concrete construction building with care about environmental protection, water resources, etc. Influence of crushed stone mineral aggregate on concrete consistency is considered in this paper. River aggregate is used as a benchmark, and from crushed aggregates: limestone, andesite, diabase and basalt. The drawn conclusion is that fine crushed aggregate has an important influence on concrete consistency because it decreas...

  12. SHRIMP zircon U-Pb dating for volcanic rocks of the Dasi Formation in southeast Hubei Province, middle-lower reaches of the Yangtze River and its implications

    XIE Guiqing; MAO Jingwen; LI Ruiling; ZHOU Shaodong; YE Huishou; YAN Quanren; ZHANG Zusong


    The Jinniu Basin in southeast Hubei,located at the westernmost part of middle-lower valley of the Yangtze River, is one of the important volcanic basins in East China. Volcanic rocks in the Jinniu Basin are distributed mainly in the Majiashan Formation, the Lingxiang Formation and the Dasi Formation, consisting of rhyolite, basalt and basaltic andesite, (trachy)-basalt and basaltic trachy-andesite and (trachy)-andesite and (trachy)-dacite and rhyolite respectively, in which the Dasi volcanism is volumetrically dominant and widespread. The Dasi volcanic rocks were selected for SHRIMP zircon U-Pb dating to confirm the timing of volcanism. The results indicate that there exist a large amount of magmatic zircons characterized by high U and Th contents in the volcanic rocks. The concordia ages for 13 points are 128±1Ma (MSWD = 3.0). On account of the shape of zircons and Th/U ratios, this age is considered to represent the crystallization time of the Dasi volcanism. The volcanic rocks in the Dasi, Majiashan and Lingxiang Formations share similar trace element and REE partition patterns as well as Sr-Nd isotopic compositions. In combination with the regional geology, it is proposed that the southeast Hubei volcanic rocks were formed mainly during the Early Cretaceous, just like other volcanic basins in middle-lower Yangtze valley. A lithospheric extension is also suggested for tectonic regime in this region in the Cretaceous Period.

  13. K-Ar ages of the Hiruzen volcano group and the Daisen volcano

    Seventeen volcanic rocks of the Hiruzen volcano group and the Daisen volcano, in southwest Japan, were dated by the K-Ar method to clarify the age of volcanic activity in this region and the evolution of these composite volcanoes. The eruption ages of the Hiruzen volcano group were revealed to be about 0.9 Ma to 0.5 Ma, those of the Daisen volcano to be about 1 Ma to very recent. These results are consistent with geological and paleomagnetic data of previous workers. Effusion of lavas in the area was especially vigorous at 0.5+-0.1 Ma. It was generally considered that the Hiruzen volcano group had erupted during latest Pliocene to early Quaternary and it is older than the Daisen volcano, mainly from their topographic features. However, their overlapping eruption ages and petrographical similarities of the lavas of the Hiruzen volcano group and the Daisen volcano suggest that they may be included in the Daisen volcano in a broad sense. The aphyric andesite, whose eruption age had been correlated to Wakurayama andesite (6.34+-0.19 Ma) in Matsue city and thought to be the basement of the Daisen volcano, was dated to be 0.46+-0.04 Ma. It indicates that petrographically similar aphyric andesite erupted sporadically at different time and space in the San'in district. (author)

  14. Summary of the geology of the northern part of the Sierra Cuchillo, Socorroand Sierra Counties, southwestern New Mexico

    Maldonado, Florian


    The northern part of the Sierra Cuchillo is located within the northeastern part of the Mogollon-Datil volcanic field west of the Rio Grande rift in the Basin and Range Province, approximately 50 km northwest of Truth or Consequences in south-central New Mexico. The Sierra Cuchillo is a north-south, elongated horst block composed of Tertiary volcanic and intrusive rocks, sparse outcrops of Lower Permian and Upper Cretaceous rocks, and sediments of the Tertiary-Quaternary Santa Fe Group. The horst is composed mainly of a basal volcanic rock sequence of andesite-latite lava flows and mud-flow breccias with a 40Ar/39Ar isotopic age of about 38 Ma. The sequence is locally intruded by numerous dikes and plugs that range in composition from basaltic andesite through rhyolite and granite. The andesite-latite sequence is overlain by ash-flow tuffs and a complex of rhyolitic lava flows and domes. Some of these units are locally derived and some are outflow sheets derived from calderas in the San Mateo Mountains, northeast of the study area. These locally derived units and outflow sheets range in age from 28 to 24 Ma.

  15. Pliocene and pleistocene volcanism in Southern Kyushu

    Southern Kyushu has been the site of intense volcanism at least since Pliocene time. One of the characteristics is the prevalence of large scale pyroclastic flow eruption, most of which originated from the volcano-tectonic depression now occupied by Kagoshima Bay. The deposits of these pyroclastic flows cover wide areas, serving as excellent stratigraphic marker horizons, but the radiometric age of the volcanic rocks in the area has been hardly available so far. A sample of Isaku pyroclastic flow was taken from an abandoned quarry. Ushine andesite, Fumoto pyroclastic flow, Ushine basalt and Ushine rhyolite were collected from a 300 m high cliff toward the top from the bottom. Kiyoura horn-blende andesite was collected from the southeastern foot of Yaeyama. K-Ar age was determined for these rocks. It was indicated that from 2 to 3 Ma (i.e., million years) ago, large scale pyroclastic eruption had taken place in the northern part of Kagoshima Bay, and extensive andesitic to basaltic volcanism occurred in both Ushine and Yaeyama areas. The establishment of the volcanic stratigraphy in the areas must await until more radiometric age determination becomes available. (Kako, I.)

  16. Microtextural and mineral chemical analyses of andesite–dacite from Barren and Narcondam islands: Evidences for magma mixing and petrological implications

    Dwijesh Ray; S Rajan; Rasik Ravindra; Ashim Jana


    Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains. In this study, we use the results of mineral chemical analyses of the calc-alkaline rock suite of rocks as proxies for magma mixing and mingling processes. Plagioclase, the most dominant mineral, shows zoning which includes oscillatory, patchy, multiple and repetitive zonation and ‘fritted’ or ‘sieve’ textures. Zoning patterns in plagioclase phenocrysts and abrupt fluctuations in An content record different melt conditions in a dynamic magma chamber. ‘Fritted’ zones (An55) are frequently overgrown by thin calcic (An72) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing processes. We conclude that hybrid magma formed from the mixing of mafic and felsic magma by two-stage processes initial intrusion of hotter mafic melt (andesitic) followed by cooler acidic melt at later stage.

  17. Timing and geochemical characters of the Sanchazi magmatic arc in Mianlüe tectonic zone, South Qinling


    The Sanchazi mafic-ultramafic complex in Mianlue tectonic zone, South Qinling can be subdivided into two blocks, i.e. Sanchazi paleo-magmatic arc and Zhuangkegou paleo-oceanic crust fragment (ophiolite). The Sanchazi paleo-magmatic arc is mainly composed of andesite, basaltic and basalt-andesitic gabbro (or diorite), andesitic dyke, plagiogranite and minor ultramafic rocks, which have typical geochemical features of island arc volcanic rocks, such as high field strength element (e.g. Nb, Ti) depletions and lower Cr, Ni contents. The Light rare earth element (LREE) and K enrichments of these rocks and zircon xenocrystals of 900 Ma from plagiogranite suggest that this magmatic arc was developed on the South active continental margin of the South Qinling micro-continent. The U-Pb age of (300 ± 61)Ma for zircons from plagiogranite indicates that the Mianlue paleo-oceanic crust was probably subducted underneath the South Qinling micro-continent in Carboniferous. This is consistent with the formation time (309Ma) of the Huwan eclogite originating from oceanic subduction in Dabie Mountains, suggesting that the Mianlue paleo-ocean probably extended eastward to the Dabie Mountains in Carboniferous. The high-Mg adakitic rocks in Sanchazi paleo-magmatic arc suggest that the subducted oceanic crust was relatively young (<25Ma) and hot.

  18. The crust role at Paramillos Altos intrusive belt: Sr and Pb isotope evidence

    Paramillos Altos Intrusive Belt (PAIB) (Ostera, 1996) is located in the thick skinned folded-thrust belt of Malargue, southwestern Mendoza, Argentina. Geochemical, geochronologic and isotopic studies were carried out in it (Ostera 1996, 1997, Ostera et al. 1999; Ostera et al. 2000) and these previous papers suggested a minor involvement of the crust in the genesis of the PAIB. According with Ostera et al. (2000) it is composed by stocks, laccoliths, dykes and sills which range in composition from diorites to granodiorites, and from andesites to rhyolites, and divided in five Members, which range in age from Middle Miocene to Early Miocene: a- Calle del Yeso Dyke Complex (CYDC), with sills and dykes of andesitic composition (age: 20±2 Ma). b- Puchenque-Atravesadas Intrusive Complex (PAIC), composed by dykes and stocks ranging from diorites to granodiorites (age: 12.5±1 Ma). c- Arroyo Serrucho Stock (SAS), an epizonal and zoned stock, with four facies, with K/Ar and Ar/Ar dates of 10±1 and 9.5±0.5 Ma. d- Portezuelo de los Cerros Bayos (PCB), that includes porphyritic rocks of rhyolitic composition, of 7.5±0.5 Ma. e- Cerro Bayo Vitrophyres (CBV), with andesitic sills and dykes (age: 4.8±0.2 Ma). We present in this paper new Sr and Pb isotopes data that constrain the evolution of the PAIB (au)

  19. Petrological and geochemical characteristics of Cenozoic high-K calc-alkaline volcanism in Konya, Central Anatolia, Turkey

    Temel, Abidin; Gündoğdu, M. Niyazi; Gourgaud, Alain


    Late Miocene to Pliocene volcanic rocks outcrop west, northwest and southwest of the Konya area in Central Anatolia, Turkey. Volcanic products are lava domes, nuée ardentes and ignimbrite deposits, predominantly andesitic to dasitic in composition, together with rare basalt, basaltic andesite, basaltic trachyandesite and trachyandesite (50.35-69.39% SiO 2). The serie exhibits high-K calc-alkaline affinities. Fractional crystallization of pyroxene, plagioclase and Fe-Ti oxides is the main process in the magmatic evolution of Konya volcanic rocks. Volcanic units exhibit typical high-K calc-alkaline character. Their geochemical characteristics (e.g., enrichments in LIL elements such as K, Rb, Ba, Sr, depletion in HFSE such as Ti, Nb, and high Ba/Nb and Low Nb/Y ratios) are consistent with those of active continental margin regions. High 87Sr/ 86Sr (0.704841-0.707340) and low 143Nd/ 144Nd (0.512390-0.512618) ratios suggest crustal involvement in their petrogenesis. Correlations between 86Sr/ 87Sr isotope with Rb, Rb/Nb, Rb/Ba, and Rb/Sr also emphasize the effect of crustal contamination on the andesitic and dacitic magmas. As a consequence, Konya volcanic rocks are products of assimilation and fractional crystallization (AFC) processes of a magma which seems to be linked to the subduction of the African plate underneath the Anatolian plate during Miocene.

  20. Oligocene and Miocene arc volcanism in northeastern California: evidence for post-Eocene segmentation of the subducting Farallon plate

    Colgan, J.P.; Egger, A.E.; John, D.A.; Cousens, B.; Fleck, R.J.; Henry, C.D.


    The Warner Range in northeastern California exposes a section of Tertiary rocks over 3 km thick, offering a unique opportunity to study the long-term history of Cascade arc volcanism in an area otherwise covered by younger volcanic rocks. The oldest locally sourced volcanic rocks in the Warner Range are Oligocene (28–24 Ma) and include a sequence of basalt and basaltic andesite lava flows overlain by hornblende and pyroxene andesite pyroclastic flows and minor lava flows. Both sequences vary in thickness (0–2 km) along strike and are inferred to be the erosional remnants of one or more large, partly overlapping composite volcanoes. No volcanic rocks were erupted in the Warner Range between ca. 24 and 16 Ma, although minor distally sourced silicic tuffs were deposited during this time. Arc volcanism resumed ca. 16 Ma with eruption of basalt and basaltic andesite lavas sourced from eruptive centers 5–10 km south of the relict Oligocene centers. Post–16 Ma arc volcanism continued until ca. 8 Ma, forming numerous eroded but well-preserved shield volcanoes to the south of the Warner Range. Oligocene to Late Miocene volcanic rocks in and around the Warner Range are calc-alkaline basalts to andesites (48%–61% SiO2) that display negative Ti, Nb, and Ta anomalies in trace element spider diagrams, consistent with an arc setting. Middle Miocene lavas in the Warner Range are distinctly different in age, composition, and eruptive style from the nearby Steens Basalt, with which they were previously correlated. Middle to Late Miocene shield volcanoes south of the Warner Range consist of homogeneous basaltic andesites (53%–57% SiO2) that are compositionally similar to Oligocene rocks in the Warner Range. They are distinctly different from younger (Late Miocene to Pliocene) high-Al, low-K olivine tholeiites, which are more mafic (46%–49% SiO2), did not build large edifices, and are thought to be related to backarc extension. The Warner Range is ∼100 km east of the

  1. Petrological analysis of the pre-eruptive magmatic process prior to the 2006 explosive eruptions at Tungurahua volcano (Ecuador)

    Samaniego, Pablo; Le Pennec, Jean-Luc; Robin, Claude; Hidalgo, Silvana


    Understanding the processes at the origin of explosive events is crucial for volcanic hazard mitigation, especially during long-lasting eruptions at andesitic volcanoes. This work exposes the case of Tungurahua volcano, whose unrest occurred in 1999. Since this date, the eruptive activity was characterized by low-to moderate explosiveness, including phases with stronger canon-like explosions and regional ash fallout. However, in 2006, a sudden increase of the explosiveness led to pyroclastic flow-forming eruptions on July 14th (VEI 2) and August 16-17th (VEI 3). All magmas emitted from 1999 to 2005, as well as the samples from the 2006 eruptions, have homogeneous bulk-rock andesitic compositions (58-59 wt.% SiO 2), and contain the same mineral assemblage consisting of pl + cpx + opx + mag ± ol. However, during the August 16-17th event, the erupted tephra comprise two types of magmas: a dominant, brown andesitic scoria; and scarce, light-grey pumice representing a subordinate, silica-rich juvenile component. For the andesitic magma, thermobarometric data point to magmatic temperatures ranging from 950 to 1015 °C and pressures in the range of 200 to 250 MPa, which corresponds to 7.5-9.5 km below the summit. Disequilibrium textures in plagioclase and pyroxene phenocrysts, particularly thin overgrowth rims, indicate the recharge of this magma body by mafic magma. Between 1999 and 2005, repeated injections from depth fed the intermittent eruptive activity observed while silica-rich melts were produced by in-situ crystallization in the peripheral parts of the reservoir. In April 2006, the recharge of a primitive magma produced strong convection and homogenisation in the reservoir, as well as pressure increase and higher magma ascent rate after seven years of only moderately explosive activity. This work emphasizes the importance of petrological studies in constraining the pre-eruptive magmatic conditions and processes, as a tool for understanding the fundamental causes

  2. Origin of the ca. 90 Ma magnesia-rich volcanic rocks in SE Nyima, central Tibet: Products of lithospheric delamination beneath the Lhasa-Qiangtang collision zone

    Wang, Qing; Zhu, Di-Cheng; Zhao, Zhi-Dan; Liu, Sheng-Ao; Chung, Sun-Lin; Li, Shi-Min; Liu, Dong; Dai, Jin-Gen; Wang, Li-Quan; Mo, Xuan-Xue


    Bulk-rock major and trace element, Sr-Nd-Hf isotope, zircon U-Pb age, and zircon Hf isotopic data of the Late Cretaceous Zhuogapu volcanic rocks in the northern Lhasa subterrane provide a new insight into tectonic processes following the collision of the terrane with the Qiangtang zone. SHRIMP zircon U-Pb dating reveals that the Zhuogapu volcanic rocks crystallized at ca. 91 Ma, postdating the development of a regional angular unconformity between the Upper Cretaceous and the underlying strata in the Lhasa-Qiangtang collision zone. Compared to the Andean arc-type andesites and dacites, the Zhuogapu volcanic rocks are characterized by higher MgO of 2.78-5.86 wt.% and Mg# of 54-64 for andesites and MgO of 2.30-2.61 wt.% and Mg# of 55-58 for dacites. Eight andesite samples have whole-rock (87Sr/86Sr)i of 0.7054-0.7065, εNd(t) of - 3.2 to - 1.7, and εHf(t) of + 3.8-+ 6.4, similar to those of the three dacite samples with (87Sr/86Sr)i = 0.7056-0.7060, εNd(t) of - 2.7 to - 2.2, and εHf(t) of + 5.6-+ 7.0. Thirteen analyses from a dacite sample give positive zircon εHf(t) of + 5.6 to + 8.7. These signatures indicate that the Zhuogapu Mg-rich andesites were most likely derived from partial melting of a delaminated mafic lower crust (including the lowermost crust straddling the northern and central Lhasa subterranes) that led to the generation of the Zhuogapu primary melts with adakitic signatures and small negative εNd(t). Such melts subsequently experienced interaction of melt-asthenospheric mantle peridotite followed by the modification of highly fractionated magmas in shallow crustal magma chamber. Hornblende-controlled fractionation results in the change of geochemical composition from Mg-rich andesitic to Mg-rich dacitic magmas. Field observations, together with geochronological and geochemical data, indicate that the Zhuogapu Mg-rich volcanic rocks and coeval magmatism in the northern Lhasa subterrane may be the result of thickened lithospheric delamination

  3. The `Strawberry Volcanic Field' of Northeastern Oregon: Another Piece of the CRB Puzzle?

    Steiner, A. R.; Streck, M. J.


    The Mid to Late Miocene Strawberry Volcanics field (SVF) located along the southern margin of the John Day valley of NE Oregon, comprise a diverse group of volcanic rocks ranging from basalt to rhyolite. The main outcrop area of the SVF (3,400 km2) is bordered by units from the Columbia River Basalt Group (CRBG), with the main CRB units to the north, the Picture Gorge Basalt to the east and Steens Basalt to the south. The geographic position and age of the Strawberry Volcanics make a genetic relationship to CRB volcanism likely, yet little is known about this diverse volcanic field. This research aims at refining the stratigraphic and age relationships as well as the petrology and geochemistry of magmas associated with the SVF. Previous investigations (e.g. Robyn, 1977) found that the SVF was active between 20 to 10 Ma with the main pulse largely being coeval with the 15 Ma CRBG eruptions. Lavas and tuffs from the SVF are calc-alkaline with low FeO*/MgO (~ 2.56 wt. %), high Al2O3 (~ 16.4 wt. %), low TiO2 (~ 1.12 wt.%), and span the entire compositional range from basalt to rhyolite (47-78 wt. % SiO2) with andesite as the dominant lithology. Basaltic lavas from the SVF have compositional affinities to earlier Steens Basalt, and some trace element concentrations and ratios are indistinguishable from those of CRBG lavas (e.g. Zr, Ba, Sr, and Ce/Y). Andesites are calc-alkaline, but contrary to typical arc (orogenic) andesites, SVF andesites are exceedingly phenocryst poor (Strawberry Volcanics are largely the product of hot-spot related basaltic magmas interacting with the continental crust. The range in compositions from calc-alkaline andesite to rhyolite may be attributed to the hybridization of mantle-derived and crustal melts, with the more evolved compositions reflecting greater proportions of crustally derived material and/or higher degrees of differentiation. Furthermore, since the earliest SVF eruption is 3 Ma older than the proposed onset of the CRBG (~ 17 Ma

  4. Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the southern Andes

    Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33-460S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49-540S) range for 87Sr/86Sr from 0.70280 to 0.70591 and for 143Nd/144Nd from 0.51314 to 0.51255. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have 87Sr/86Sr, 143Nd/144Nd, La/Yb, Ba/La and Hf/Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 350S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 330 and 340S, basaltic andesites and andesites have higher 87Sr/86Sr, Rb/Cs, and Hf/Lu, and lower 143Nd/144Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (540S) has Sr and Nd isotopic compositions and K/Rb and Ba/La similar to MORB. The high La/Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO2, K2O, Rb, Ba, Ba/La, and 87Sr/86Sr and decrease in MgO, Sr, K/Rb, Rb/Cs, and 143Nd/144Nd, suggesting increasingly greater degrees of fractional crystallization and associated intra-crustal contamination. (orig./SHOE)

  5. Hybridisation during magma ascent at Soufrière Hills Volcano, Montserrat

    Humphreys, M.; Edmonds, M.; Christopher, T. E.; Hards, V.


    Intermediate arc magmas commonly contain magmatic inclusions that demonstrate mingling between mafic and silicic magma. These magmas also typically contain a wide variety of disequilibrium phenocryst textures as well as strongly zoned microlites, suggesting that smaller-scale interactions also occur. Minor-element analysis of phenocrysts and microlites in andesites erupted from Soufrière Hills volcano shows that different crystal populations can be distinguished chemically, providing insights into their origins. For plagioclase and orthopyroxene, the microlites are enriched in Fe and Mg (pl) and Al and Ca (opx) relative to the phenocrysts. However, the microlites (including cpx) are indistinguishable chemically from these phases in the mafic inclusions. The microlites also give anomalously high temperatures, similar to those given by the mafic inclusions. Clinopyroxene overgrowth rims on quartz and orthopyroxene phenocrysts and coarse-grained breakdown rims on hornblende are identical in composition to cpx from the mafic inclusions. This indicates that these rims formed during interaction with mafic magma. We infer that the mafic inclusions disaggregated under conditions of high shear stress during ascent in the conduit, transferring mafic material into the groundmass of the andesite. This implies that the mafic component of the system is greater than previously determined from the volume proportion of macroscopic mafic enclaves, and that the amount of decompression-driven microlite crystallisation may be lower than previousl thought. The presence of mafic-derived microlites in the andesite groundmass may also affect phase equilibrium studies that use this as a starting material. Melt inclusions and matrix glasses from the erupted andesites include a K-rich population which overlaps with residual mafic inclusion glass (high-K2O, high-TiO2). These glasses are affected by physical mixing with mafic magma during ascent and/or by diffusive exchange during the

  6. Reconstructing multiple arc-basin systems in the Altai-Junggar area (NW China): Implications for the architecture and evolution of the western Central Asian Orogenic Belt

    Li, Di; He, Dengfa; Tang, Yong


    The Altai-Junggar area in northwestern China is a critical region to gain insights on the tectonic framework and geological evolution of the western Central Asian Orogenic Belt (CAOB). In this study, we report results from integrated geological, geochemical and geophysical investigations on the Wulungu Depression of the Junggar Basin to determine the basement nature of the basin and understand its amalgamation history with the Chinese Altai, within the broad tectonic evolution of the Altai-Junggar area. Based on borehole and seismic data, the Wulungu Depression is subdivided into two NW-trending tectonic units (Suosuoquan Sag and Hongyan High) by southward-vergent thrust faults. The Suosuoquan Sag consists of the Middle-Late Devonian basaltic andesite, andesite, dacite, tuff, tuffaceous sandstone and tuffite, and the overlying Early Carboniferous volcano-sedimentary sequence with lava flows and shallow marine sediments from a proximal juvenile provenance (zircon εHf(t) = 6.0-14.9), compared to the Late Carboniferous andesite and rhyolite in the Hongyan High. Zircon SIMS U-Pb ages for dacites and andesites indicate that these volcanics in the Suosuoquan Sag and Hongyan High erupted at 376.3 Ma and 313.4 Ma, respectively. The Middle-Late Devonian basaltic andesites from well LC1 are calc-alkaline and exhibit primitive magma-like MgO contents (7.9-8.6%) and Mg# values (66-68), with low initial 87Sr/86Sr (0.703269-0.704808) and positive εNd(t) values (6.6-7.6), and relatively high Zr abundance (98.2-116.0 ppm) and Zr/Y ratios (5.1-5.4), enrichment in LREEs and LILEs (e.g., Th and U) and depletion in Nb, Ta and Ti, suggesting that they were probably derived from a metasomatized depleted mantle in a retro-arc extensional setting. The well LC1 andesitic tuffs, well L8 dacites, well WL1 dacitic tuffs and well L5 andesites belong to calc-alkaline and metaluminous to peraluminous (A/CNK = 0.8-1.7) series, and display low Mg# values (35-46) and variably positive εNd(t) (4

  7. Katmai volcanic cluster and the great eruption of 1912

    Hildreth, W.; Fierstein, J.


    In June 1912, the world's largest twentieth century eruption broke out through flat-lying sedimentary rocks of Jurassic age near the base of Trident volcano on the Alaska Peninsula. The 60 h ash-flow and Plinian eruptive sequence excavated and subsequently backfilled with ejecta a flaring funnel-shaped vent since called Novarupta. The vent is adjacent to a cluster of late Quaternary stratocones and domes that have released about 140 km3 of magma in the past 150 k.y. Although the 1912 vent is closest to the Trident group and is also close to Mageik and Griggs volcanoes, it was the summit of Mount Katmai, 10 km east of Novarupta, that collapsed during the eruption to form a 5.5 km3 caldera. Many earthquakes, including 14 in the range M 6-7, took place during and after the eruption, releasing 250 times more seismic energy than the 1991 caldera-forming eruption of the Philippine volcano, Pinatubo. The contrast in seismic behavior may reflect the absence of older caldera faults at Mount Katmai, lack of upward (subsidence opposing) magma flow owing to lateral magma withdrawal in 1912, and the horizontally stratified structure of the thick shale-rich Mesozoic basement. The Katmai caldera compensates for only 40% of the 13 km3 of 1912 magma erupted, which included 7-8 km3 of slightly zoned high-silica rhyolite and 4.5 km3 of crystal-rich dacite that grades continuously into 1 km3 of crystal-rich andesite. We have now mapped, sampled, and studied the products of all 20 components of the Katmai volcanic cluster. Pyroxene dacite and silicic andesite predominate at all of them, and olivine andesite is also common at Griggs, Katmai, and Trident volcanoes, but basalt and rhyodacite have erupted only at Mount Katmai. Rhyolite erupted only in 1912 and is otherwise absent among Quaternary products of the cluster. Pleistocene products of Mageik and Trident and all products of Griggs are compositionally distinguishable from those of 1912 at Novarupta. Holocene products of Mount

  8. Collision zone magmatism aids continental crustal growth

    Savov, Ivan; Meliksetian, Khachatur; Ralf, Halama; Gevorg, Navasardian; Chuck, Connor; Massimo, D'Antonio; Samuele, Agostini; Osamu, Ishizuka; Sergei, Karapetian; Arkadi, Karakhanian


    The continental crust has a broadly andesitic bulk composition and is predominantly generated at convergent margins. However, estimates of the bulk composition of oceanic arcs indicate a bulk composition closer to basalt than to andesite. Hence, reworking processes that transform basaltic island arc crust into andesitic continental crust are essential[1] and explaining growth of andesitic continental crust via accretion of arc crustal fragments remains problematic. Recent studies of magmatism in the Great Tibetan Plateau[2], as site of multiple and still active continent-continent collisions, have proposed that andesitic CC is generated via amalgamation of large volumes of collision-related felsic magmas generated by melting of hydrated oceanic crust with mantle geochemical signatures. We aim to test this hypothesis by evaluating geochemical data from the volcanically and tectonically active Lesser Caucasus region (Armenia, Azerbaijan, Georgia and E. Turkey), as the only other region where active continent-continent collision takes place. We will benefit from the newly compiled volcano-tectonic database of collision-related volcanic and plutonic rocks of Armenia that is comparable in quality and detail to the one available on Tibet. Our dataset combines several detailed studies from the large Aragats shield volcano[3] and associated monogenetic volcanic fields (near the capital city of Yerevan), as well as > 500 Quaternary to Holocene volcanoes from Gegham, Vardenis and Syunik volcanic highlands (toward Armenia-Nagorno-Karabakh-Azerbaijan-Iran border). The Armenian collision-related magmatism is diverse in volume, composition, eruption style and volatile contents. Interestingly, the majority of exposed volcanics are andesitic in composition. Nearly all collision-related volcanic rocks, even the highly differentiated dacite and rhyolite ignimbrites, have elevated Sr concentrations and 87Sr/86Sr and 143Nd/144Nd ratios varying only little (average ~ 0.7043 and ~ 0

  9. Miocene magmatism and tectonics within the Peri-Alboran orogen (western Mediterranean)

    El Azzouzi, M.; Bellon, H.; Coutelle, A.; Réhault, J.-P.


    The aim of this paper concerns Miocene igneous activity in the Alboran Sea and Peri-Alboran area (northern Morocco, western Algeria and Betic Cordilleras in Spain), considering its age and its location with regard to major tectonics structures. We have compiled previous K-Ar isotopic ages of lavas and plutonic boulders and intrusives with an error of ±1σ and completed this set by a new K-Ar isotopic age for andesitic tuffites from Alboran Island. Geochemistry of most of these samples has been considered after previous analyses completed with new data for Spain magmatism. These two sets of data allow us to place the magmatic activity within the regional stratigraphy and tectonics and their chronological framework of the three major tectonic phases of the Maghrebian orogen, at 17 Ma (Burdigalian), 15 Ma (Langhian) and 9 Ma (Tortonian). Petro-geochemical characteristics are compared through time and geographical locations. A major goal of this coupled approach is to help the elaboration of possible geodynamical processes. As an application, we present the case study of the Dellys, Djinet and Thenia region (east of Algiers) where the successive magmatic events between 19.4 ± 1 and 11.6 ± 0.5 Ma are closely related to the local tectonics and sedimentation. The Peri-Alboran igneous activity is placed in a multidisciplinary framework. Timing of activity is defined according to the ages of the neighbouring sedimentary units and the K-Ar ages of igneous rocks. In Spain, the Cabo de Gata-Carboneras magmatic province displays late Oligocene and early Miocene leucogranitic dikes, dated from 24.8 ± 1.3 to 18.1 ± 1.2 Ma; three following andesitic to rhyolitic events took place around 15.1 ± 0.8 to 14.0 ± 0.7 Ma, 11.8 ± 0.6 to 9.4 ± 0.4 Ma, 8.8 ± 0.4 to 7.9 ± 0.4 Ma; this last event displays also granitic rocks. Lamproitic magmas dated between 8.4 ± 0.4 and 6.76 ± 0.04 Ma were emplaced after the Tortonian phase. In Morocco, after the complex building of the Ras Tarf

  10. Geochemistry and Tectonic Setting of Marine Volcanic Rocks of Elashan Area in Qinghai%青海鄂拉山地区三叠系洪水川组火山岩地球化学特征及构造环境

    李善平; 李永祥; 潘彤; 白宗海; 王瑾; 舒树兰; 李小雪; 张志青; 赵海霞


    Elashan magmatic belt, an intersection location for East Kunlun, West Qinling and South Qilian orogenic belt, has complex internal structure and is an important junction in western China and ore concen-tration area in Qinghai. Marine volcanic widely outcrops in Elashan area and the rock types are ainly amyg-daloidal basaltic andesite, amygdaloidal andesite, andesitic volcanic breccia, andesitic crystal-vitric tuff debris, andesitic breccia tuff lava, dacite and rhyolite. Marine volcanic rocks occurs by the volcanic strata, or laminated and lenticular shapes in the Suolaqu sandstone, Xingfucun fine-turbidite and Hekashan coarse-turbidite of the Hongshuichuan Formation, which is the product of a marine environment eruption. Chemical composition of volcanic rocks similar with the average chemical composition of island arc calc-al-kaline andesite, The average SEu value is 0. 75 indicating a weak negative anomalies, (La/Sm)N, (Gd/ Yb)N values of the average were 5. 09, 1. 76, and There are significantly fractionated between light and heavy rare earth elements and enrich in LREE. The trace elements such as Ba, Rb and Th are strongly enriched and Ti, Cr and other elements are depleted. The Th× Ta/Hf2 value is between 0. 029 to 0. 162, shows volcanic arc character. From the above, volcanic rocks of the Hongchuichuan Formation produced in stretching after the collision environment.%鄂拉山岩浆岩地处东昆仑、西秦岭、南祁连造山带交汇部位,内部结构复杂,是中国西部重要的构造结和矿集区之一.海相火山岩出露广泛,岩石类型主要由杏仁状玄武安山岩、杏仁状安山岩、安山质火山角砾岩、安山质晶屑岩屑凝灰岩、安山质角砾凝灰熔岩及英安岩、流纹岩等组成,以火山地层、夹层状、透镜状等形式赋存于洪水川组索拉曲砂岩、幸福村细浊积岩、河卡山粗浊积岩中,属海相喷发环境的产物.火山岩岩石化学成分与岛弧钙碱性安山岩平均化

  11. Jurassic Oceanic Remnants In The Siuna Area (NE-Nicaragua) - Tracing The Chortis- Caribbean Paleo-plate Boundary

    Flores, K.; Baumgartner, P. O.; Skora, S.; Baumgartner, L.; Baumgartner-Mora, C.; Rodriguez, D.


    The southern limit of the Chortis Block has been commonly placed along a line between the Santa Elena Peninsula (Costa Rica) and the Hess Escarpment (Eastern Caribbean). However, we have mapped extensive occurrences of ultramafic and mafic rocks, associated with Jurassic radiolarites in the Siuna area. These are in conflict with the current plate tectonic schemes. In the area S and NE of Siuna, we observe three tectono-stratigraphic units: 1. A pre-Cretaceous, subduction-related melange outcropping in a 30 x 5 km sized erosional window. Serpentinite is a (tectonic) matrix for a variety of mappable blocks grouped into the following categories: Gabbros and peridotites preserving original cumulate textures, greenstones, epidote-bearing greenschists, barroisite-bearing metamafics that partially contain garnet+clinopyroxene inclusions, phengite-schists, blue- green amphibole-rich metacherts, detrital quartzites, radiolarian cherts, black shales and Mn-radiolarites- bearing Middle and Late Jurassic Radiolaria. Blocks with greenschists and higher pressure metamorphic facies appear to be concentrated in the central part of the window. In some blocks, greenstones (mainly altered metabasalts) are associated with ribbon-bedded radiolarites and siliceous shales suggesting an original sedimentary contact of sediments on the oceanic crust. This melange resembles (though more polymict) the subduction melanges of the Franciscan and indicates that the Siuna area exposes part of a major suture zone between the Chortis Block and the Caribbean Large Igneous Province (CLIP). 2. Thin-bedded calcareous hemipelagites yielding Aptian/Albian planktonic Foraminifera rest unconformably on the oceanic melange. Distal volcaniclastic turbitites are interbedded. The sequence contains shallow upsections into thick bedded limestones, in which andesitic flows may be intercalated. Well rounded/sorted and imbricated volcanic pebble conglomerates sometimes intervene between the andesites and

  12. Volcanostratigraphy, petrography and petrochemistry of Late Cretaceous volcanic rocks from the Görele area (Giresun, NE Turkey)

    Oguz, Simge; Aydin, Faruk; Baser, Rasim


    In this study, we have reported for lithological, petrographical and geochemical features of late Cretaceous volcanic rocks from the Çanakçı and the Karabörk areas in the south-eastern part of Görele (Giresun, NE Turkey) in order to investigate their origin and magmatic evolution. Based on the previous ages and recent volcano-stratigraphic studies, the late Cretaceous time in the study area is characterized by an intensive volcanic activity that occurred in two different periods. The first period of the late Cretaceous volcanism (Cenomanian-Santonian; 100-85 My), conformably overlain by Upper Jurassic-Lower Cretaceous massive carbonates (Berdiga Formation), is represented by bimodal units consisting of mainly mafic rock series (basaltic-andesitic lavas and hyaloclastites, dikes and sills) in the lower part (Çatak Formation), and felsic rock series (dacitic lavas and hyaloclastites, crystal- and pyrite-bearing tuffs) in the upper part (Kızılkaya Formation). The second period of the late Cretaceous volcanism (Santonian-Late Campanian; 85-75 Ma) is also represented by bimodal character and again begins with mafic rock suites (basaltic-basaltic andesitic lavas and hyaloclastites) in the lower part (Çağlayan Formation), and grades upward into felsic rock suites (biotite-bearing rhyolitic lavas, ignimbrites and hyaloclastites) through the upper part (Tirebolu Formation). These bimodal units are intercalated with volcanic conglomerates-sandstones, claystones, marl and red pelagic limestones throughout the volcanic sequence, and the felsic rock series have a special important due to hosting of volcanogenic massive sulfide deposits in the region. All volcano-sedimentary units are covered by Tonya Formation (Late Campanian-Paleocene) containing calciturbidites, biomicrites and clayey limestones. The mafic rocks in the two volcanic periods generally include basalt, basaltic andesite and minor andesite, whereas felsic volcanics of the first period mainly consists of

  13. Origins of large-volume, compositionally zoned volcanic eruptions: New constraints from U-series isotopes and numerical thermal modeling for the 1912 Katmai-Novarupta eruption

    Turner, Simon; Sandiford, Mike; Reagan, Mark; Hawkesworth, Chris; Hildreth, Wes


    We present the results of a combined U-series isotope and numerical modeling study of the 1912 Katmai-Novarupta eruption in Alaska. A stratigraphically constrained set of samples have compositions that range from basalt through basaltic andesite, andesite, dacite, and rhyolite. The major and trace element range can be modeled by 80–90% closed-system crystal fractionation over a temperature interval from 1279°C to 719°C at 100 MPa, with an implied volume of parental basalt of ∼65 km3. Numerical models suggest, for wall rock temperatures appropriate to this depth, that 90% of this volume of magma would cool and crystallize over this temperature interval within a few tens of kiloyears. However, the range in 87Sr/86Sr, (230Th/238U), and (226Ra/230Th) requires open-system processes. Assimilation of the host sediments can replicate the range of Sr isotopes. The variation of (226Ra/230Th) ratios in the basalt to andesite compositional range requires that these were generated less than several thousand years before eruption. Residence times for dacites are close to 8000 years, whereas the rhyolites appear to be 50–200 kyr old. Thus, the magmas that erupted within only 60 h had a wide range of crustal residence times. Nevertheless, they were emplaced in the same thermal regime and evolved along similar liquid lines of descent from parental magmas with similar compositions. The system was built progressively with multiple inputs providing both mass and heat, some of which led to thawing of older silicic material that provided much of the rhyolite.

  14. Production of hybrid granitic magma at the advancing front of basaltic underplating: Inferences from the Sesia Magmatic System (south-western Alps, Italy)

    Sinigoi, Silvano; Quick, James E.; Demarchi, Gabriella; Klötzli, Urs S.


    The Permian Sesia Magmatic System of the southwestern Alps displays the plumbing system beneath a Permian caldera, including a deep crustal gabbroic complex, upper crustal granite plutons and a bimodal volcanic field dominated by rhyolitic tuff filling the caldera. Isotopic compositions of the deep crustal gabbro overlap those of coeval andesitic basalts, whereas granites define a distinct, more radiogenic cluster (Sri ≈ 0.708 and 0.710, respectively). AFC computations starting from the best mafic candidate for a starting melt show that Nd and Sr isotopic compositions and trace elements of andesitic basalts may be modeled by reactive bulk assimilation of ≈ 30% of partially depleted crust and ≈ 15%-30% gabbro fractionation. Trace elements of the deep crustal gabbro cumulates require a further ≈ 60% fractionation of the andesitic basalt and loss of ≈ 40% of silica-rich residual melt. The composition of the granite plutons is consistent with a mixture of relatively constant proportions of residual melt delivered from the gabbro and anatectic melt. Chemical and field evidence leads to a conceptual model which links the production of the two granitic components to the evolution of the Mafic Complex. During the growth of the Mafic Complex, progressive incorporation of packages of crustal rocks resulted in a roughly steady state rate of assimilation. Anatectic granite originates in the hot zone of melting crust located above the advancing mafic intrusion. Upward segregation of anatectic melts facilitates the assimilation of the partially depleted restite by stoping. At each cycle of mafic intrusion and incorporation, residual and anatectic melts are produced in roughly constant proportions, because the amount of anatectic melt produced at the roof is a function of volume and latent heat of crystallization of the underplated mafic melt which in turn produces proportional amounts of hybrid gabbro cumulates and residual melt. Such a process can explain the

  15. Petrology, mineral chemistry and tectono-magmatic setting of volcanic rocks from northeast Farmahin, north of Arak

    Reza Zarei Sahamieh


    Full Text Available Introduction The study area is a small part of the Urumieh-Dokhtar structural zone in the Markazi province, located in the northeastern part of the Farmahin, north of Arak (Hajian, 1970. The volcanic rocks studied from the area include andesite, dacite, rhyodacite, ignimbrite and tuff of Middle to Late Eocene age (middle Lutetian to upper Lutetian (Ameri et al., 2009. It seems that folding and faulting is caused in sedimentary basin and volcanic activities. On the other hand, except of orogeny maybe rifting had rule in eruption so that this case has seen in the other area such as Taft and Khezrabad in central Iran (Zarei Sahamieh et al., 2008. The oldest formation in the studied area is Triassic limestones. The dominant textures of these rocks are porphyritic, microlite porphyritic, microlitic and rarely sieve-texture. Sieve texture and dusty texture (dusty plagioclases indicates magma mixing. Mineralogically, they contain plagioclases, clinopyroxenes, amphiboles, quartz and biotite as the main constituents and zircon, apatite, and opaque minerals as accessories. Plagioclases in the andesitic and basaltic- andesite rocks are labradorite, bytownite and anorthite (based on electron microprobe .Moreover, plagioclases in andesitic rocks show that H2O is lesser than 2.5 precent. Amphibole is found in both plagioclases and groundmass. Materials and methods In this article are used different analyses methods such as XRF, ICP-MS and EPMA. Whole-rock major and trace element analyses were determined with ICP-MS method. The major and trace element composition of some rock was determined by electron probe micro-analysis (EPMA using a Cameca SX100 instrument in Iran Mineral Processing Research Center (IMPRC. Moreover, whole-rock major and some trace element analyses for some samples were obtained by X-ray fluorescence (XRF, using an ARL Advant-XP automated X-ray spectrometer. Results Chemical data based on electron micro probe studies of minerals indicate

  16. Permo-triassic volcanism in the San Rafael Block (Mendoza province) and its uraniferous potential

    This paper describes the Permo-triassic volcanism in the San Rafael Block, Mendoza, Argentina, which forms part of the Choiyoi province and it represents by large volumes of intermediate to silicic ignimbrites with minor sub volcanic bodies of rhyolites, andesites and basandesites. Three different suites can be distinguished: the first one (Lower Section) of Early Permian age, is composed of dacites and rhyolites (SiO2 up to 71 %) with minor andesites, the second one (Upper Section) of Late Permian-Early Triassic age is made up of rhyolites (SiO2 up to 77 %) with some basandesites and andesites, and the third one, of Triassic age is composed of rhyolites (SiO2 > 75 %) and basandecites. These suites are easily distinguished by means of trace element data and are believed to represent the transition between a subduction-related magmatic arc and an extensional tectonic regime. This tectonic setting is similar to the prevalent during the Cenozoic in the Sierra Occidental of Mexico and is favourable for the development of long-lived hydrothermal systems which lead to economic U concentrations (i.e. Sierra de Pena Blanca). In the San Rafael Block, the Dr. Baulies-Los Reyunos U deposit, which is hosted in volcanic sediments, is associated to the first suite (Lower Section). Although minor U concentrations are known, up to date, to be related to the second and third suites, these rocks are fertile and seen to be potential source for the formation of uranium deposits within a volcanic caldera environment. (Author)

  17. Origin of a native sulfur chimney in the Kueishantao hydrothermal field, offshore northeast Taiwan

    ZENG; ZhiGang; LIU; ChangHua; CHEN; ChenTung; A; YIN; XueBo; CHEN; DaiGeng; WANG; XiaoYuan; WANG; XiaoMei; ZHANG; GuoLiang


    Analyses of rare earth and trace element concentrations of native sulfur samples from the Kueishantao hydrothermal field were performed at the Seafloor Hydrothermal Activity Laboratory of the Key Laboratory of Marine Geology and Environment,Institute of Oceanology,Chinese Academy of Sciences.Using an Elan DRC II ICP-MS,and combining the sulfur isotopic compositions of native sulfur samples,we studied the sources and formation of a native sulfur chimney.The results show,when comparing them with native sulfur from crater lakes and other volcanic areas,that the native sulfur content of this chimney is very high (99.96%),the rare earth element (REE) and trace element constituents of the chimney are very low (ΣREE<21×10-9),and the chondrite-normalized REE patterns of the native sulfur samples are similar to those of the Kueishantao andesite,implying that the interaction of subseafloor fluid-andesite at the Kueishantao hydrothermal field was of short duration.The sulfur isotopic compositions of the native sulfur samples reveal that the sulfur of the chimney,from H2S and SO2,originated by magmatic degassing and that the REEs and trace elements are mostly from the Kueishantao andesite and partly from seawater.Combining these results with an analysis of the thermodynamics,it is clear that from the relatively low temperature (<116℃),the oxygenated and acidic environment is favorable for formation of this native sulfur chimney in the Kueishantao hydrothermal field.

  18. Zircon U-Pb Age Determination of Volcanic Eruptions in Lutao and Lanyu in the Northern Luzon Magmatic Arc

    Wen-Yu Shao


    Full Text Available This paper reports for the first time zircon U-Pb ages of volcanic rocks and sands from Lutao and Lanyu, two islets off SE Taiwan in the north Luzon arc. The samples include (1 seven andesites from four volcanic units and three river/beach sands from Lutao and (2 five basaltic andesites from four volcanic units and two river/beach sands from Lanyu. The Lutao andesites contain abundant magmatic zircons, aging from ~1.54 to ~1.24 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 1.31 ±± 0.03 Ma (n = 190, MSWD = 2.6. This is slightly older than, or broadly coincident with, a mean 206Pb/238U age of 1.23 ±± 0.03 Ma (n = 103, MSWD = 1.9 given by detrital zircons from the three sands. The Lanyu volcanics appear to have less abundant magmatic zircons, aging from ~2.72 to ~2.35 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 2.61 ±± 0.13 Ma (n = 11, MSWD = 1.8. This accords with a mean 206Pb/238U age of 2.69 ±± 0.11 Ma (n = 34, MSWD = 4.7 obtained by detrital zircons from the two sands. The age data suggest that in Lutao and Lanyu the major volcanic eruptions occurred at ~1.3 and ~2.6 Ma, respectively. Moreover, volcanic samples from both islets contain various amounts of older inherited zircons, ~11% in Lutao and up to ~82% in Lanyu, which together with detrital zircons from the sands show main age peaks at ~150 Ma and ~1.9 and ~2.5 Ga, consistent with the notion for a _ continental crust involved in the genesis of the northern Luzon magmatic arc.

  19. Hydrogeological investigation of Melendiz basin (Aksaray)

    Within the scope of this M.Sc, study entitled Hydrogeologic Investigation of Melendiz basin, the geological, hydrological, hydrogeological and hydrochemical features of a 600 km2 area have been studied and, 1/100.000 scale geological and hydrogeological maps have been prepared. Tetriary-Guaternary aged young volkanic rocks occupy nearly 80% (480 km2 ) of the area. The major aquifers are alluvium and andesite and basalt which are extensively fractured and jointed. Aquitard units comprise of ignimbirite, some of the andesites-basalts and formations that composes of limestone-sandstone-marl intercalations. The youngest geologic unit of the area, Hasandag volcanic ash formation, and also the tuffs have been indentified as aquiclude units. Mean areal precipitation, potential and real evapotranspiration rates and mean annual streamflow have been calculated on the basis of available data and, a hydrologic budget of the basin has been established. Hydrogeologic units have been classified as aquifer, aquitard and aquiclude with respect to their geohydrologic properties, field observations and the results of the pumping tests. On the other hand, hydrodynamic mechanism of the groundwater flow reaching major cold and thermal water discharges have also been explained. A hydrogeologic budget for the area covering Ciftlik township and its vicinity where extensively joint and fractured andesite-basalt and alluvial aquifers outcrop has been established. Major water points as thermal and cold springs, wells and streams have been sampled for major ion analysis. Beyond this, some water points have also been sampled for organic, trace,metal ald environmental isotropic analyses. Environmental isotope data of thermal springs point out a long-deep groundwater flow path

  20. Chemical and isotopic composition of the gaseous and solid products of the eruptive activity of Krakatau (Indonesia) between 1978 and 1980

    Allard, P.; Jehanno, C.; Sabroux, J. (C.N.R.S., Gif-sur-Yvette (France))


    Between 1978 and 1980, a new eruptive cycle developed at Anak Krakatau. High-temperature gases and lavas were collected. The /sup 13/C//sup 12/C ratio of CO/sub 2/ suggests that this volcano releases carbon of mantle-derivation. Lavas have a typical andesitic composition, which points out that the magma underwent a significant differentiation since the birth of the volcano, in 1928. This trend supports the earlier observations of Van Bemmelen and is tentatively interpreted in terms of crustal fractionation.

  1. The Records of the Tectonic Evolution From the Volcanics in Qiangtang Basin, Tibet

    He Zhonghua; Yang Deming; Li Cai; Pu Zhongyu


    The volcanism in Qiangtang Basin is very frequent due to the divergence and subduction of the various plates. The study indicates that these volcanics are formed in different tectonic settings: 1 )Hercynian volcanics are mainly basalts and are formed in the intraplate and intercontinental rift. 2 ) Indosinian volcanics markedly vary in the distribution and composition and reflect transitional MORB and island are environments respectively. 3) Yanshanian volcanics consist predominantly of basalts, andesites, dacites and rhyolites and are characterized by calc- alkaline volcanic suite, indicating island arc setting. 4)Himalayan volcanics are complicated and associated with intraplate orogency. The volcanism provides important tectonic information for recognizing the evolution of Qiangtang Basin.

  2. Major, trace element and isotope geochemistry of historic (1945-1996) eruptions from Ruapehu volcano, New Zealand with implications for open system magmatic processes in arc volcanoes

    Detailed evaluation of the isotope data (87Sr/86Sr vs 143Nd/144Nd) reveals the 1945 sample as the most radiogenic, with samples from the 1995-96 eruptions overlapping the range of all intervening eruptives. It is suggested that the observed chemical and petrographic variations are best explained by injection of a fresh batch of andesitic magma into the volcano superstructure. This magma batch interacts and mixes with stagnated magma batches from previous events, and leads to abrupt chemical zonation (including reverse zoning) in the phenocryst assemblages. The 1995 - 96 eruptives appear to represent a new cycle of activity, suggesting that there should be no complacency on the monitoring front

  3. Complete Analytical Data for Samples of Jurassic Igneous Rocks in the Bald Mountain Mining District, Nevada

    du Bray, Edward A.


    This report presents all petrographic, major oxide, and trace element data for a set of 109 samples collected during an investigation of Jurassic igneous rocks in the Bald Mountain mining district, Nevada. Igneous rocks in the district include the Bald Mountain stock, quartz-feldspar porphyry dikes, basaltic andesite dikes, aplite sills, and rare lamprophyre dikes. These rocks, although variably altered near intrusion-related mineral deposits, are fresh in many parts of the district. Igneous rocks in the district are hosted by Paleozoic sedimentary rocks.

  4. On plate tectonics and the geologic evolution of southwestern North America

    Ward, P.L.


    Very rapid subduction of the Farallon plate under southwestern North America between 60 and 40 Ma was accompanied by a relatively low volume of magmatism throughout the southwestern United States and northern Mexico. Between 40 and 20 Ma, when subduction slowed significantly and in one area may have even stopped, magmatism became widespread and voluminous from Nevada and Utah to central Mexico. This correlation of rapid subduction with a relatively low volume of magmatism can be explained by the observation that subduction-related andesitic arc volcanism, often formed in a Laramide-style compressional regime, is relatively low volume compared to continental volcanism. -from Author

  5. Mineralogy and Geochemistry of Clay Rich Volcano-Sedimentary Units from South of Elazıǧ Basin (Eastern Turkey)

    Akkoca, Dicle Bal; Bakır, Zülfü


    The investigated area covers Upper Cretaeous Elazıǧ Magmatics and Middle Eocene Maden Group in the southern of Elazıǧ. X-ray powder diffraction (XRD), ICP-AES, ICP-MS were performed on three sections samples belonging to Elazıǧ Magmatics (Yemişlik and Kavallı sections) and Maden Group (Alıncık section), to investigate the depositional environment of volcano-sediments. The Elazıǧ magmatic rocks are composed of diorites, monzodiorites, quartz-diorites, and tonalites, basaltic pillow-lavas, andesitic lavas, and andesitic pyroclastic rocks. The Maden Group has a complex lithology consisting of limestones, red-green clayey limestones, sandstone, agglomerate, tuffs, reddish mudstone and basaltic-andesitic pillow lavas. Yemişlik section is composed mainly of altered grey tuffites, Kavallı section is represented by brown altered sediments, intercalated with basaltic, andesitic lava flows. Reddish mudstones constiture the Alıncık section. All samples consist of clay minerals (chlorite, illite), quartz, and feldspar. Yemişlik and Kavallı sections also contain calcite. Chlorite is the dominant clay in three sections. SiO2, Al2O3, Fe2O3, K2O contents show that Kavallı, Yemişlik and Alıncık samples are convenient with Fe shales and shales. The ratios of TiO2, Zr, Th/Sc, Zr/Sc, Y/Ni-Cr/V, Al/(Al+Fe+Mn) show dominance of neutral-basic volcanism in the area. REE concentrations of samples are normalized to chondrite values. It is determined that low light rare earth elements (LREEs) are enriched in comparison to high rare earth elements (HREEs), and the absence of Eu anomalies shows that our samples are generally mafic in composition. Rare earth elements (REE) of samples were compared with North American shale composite (NASC), European shale (ES) and Post-Archean Australian shale (PAAS). Elements are not in concurrence with these compositions. Th-Hf/3-Nb/16 tectono-magmatic discrimination diagram for samples in the study area indicate that all samples were

  6. Zeolites replacing plant fossils in the Denver formation, Lakewood, Colorado.

    Modreski, P.J.; Verbeek, E.R.; Grout, M.A.


    Well-developed crystals of heulandite and stilbite, within fossil wood, occur in sedimentary rocks in Lakewood, Jefferson County. The rocks belong to the Denver formation, a locally fossiliferous deposit of fluvial claystone, siltstone, sandstone and conglomerate, containing some volcanic mudflows (andesitic) of late Cretaceous to Palaeocene age. Altered volcanic glass released Na and Ca into the ground-water and subsequently zeolites were crystallized in the open spaces between grains and within fossil plant structures. Minor pyrite, quartz (jasper), calcite and apatite also occur as replacements of fossil wood. Similar zeolite occurrences in other areas are reviewed.-R.S.M.

  7. Petrology and geochemistry of ca. 2100-1000 a.B.P. magmas of Augustine volcano, Alaska, based on analysis of prehistoric pumiceous tephra

    Tappen, Christine M.; Webster, James D.; Mandeville, Charles W.; Roderick, David


    Geochemical and textural features of whole-rock samples, phenocrysts, matrix glasses, and silicate melt inclusions from five prehistoric pumiceous tephra units of Augustine volcano, Alaska, were investigated to interpret processes of magma storage and evolution. The bulk-rock compositions of the tephra (designated G, erupted ca. 2100 a.B.P.; I ca. 1700 a.B.P.; H ca. 1400 a.B.P.; and C1 and C2 ca. 1000 a.B.P.) are silicic andesite; they contain rhyolitic matrix glasses and silicate melt inclusions with 74-79 wt.% SiO 2. The rocks are comprised of microlite-bearing matrix glass and phenocrysts of plagioclase, orthopyroxene, clinopyroxene, magnesio-hornblende, titanomagnetite, and ilmenite ± Al-rich amphibole with minor to trace apatite and rare sulfides and quartz. The felsic melt inclusions in plagioclase, pyroxenes, and amphibole are variably enriched in volatile components and contain 1.6-8.0 wt.% H 2O, 2100-5400 ppm Cl, < 40-1330 ppm CO 2, and 30-390 ppm S. Constraints from Fe-Ti oxides imply that magma evolution occurred at 796 ± 6 °C to 896 ± 8 °C and log ƒ O2 of NNO + 2.2 to + 2.6. This is consistent with conditions recorded for 1976, 1986, and 2006 eruptive materials and implies that magmatic and eruptive processes have varied little during the past 2100 years. Prehistoric Augustine magmas represented by these silicic andesites evolved via fractional crystallization, magma mingling and mixing, and/or chemical contamination due to magma-volcanic rock interaction. The occurrence of fractional crystallization is supported by the abundance of normally zoned phenocrysts, the presence of felsic matrix glass and melt inclusions within andesitic rock samples, trace-element data, and by geochemical modeling. The modeling constrains the influence of crystal fractionation on melt differentiation and is consistent with the evolution of the melt phase from felsic andesite to rhyodacite compositions. Magma mixing, mingling, and/or contamination by magma-volcanic rock

  8. Palaeoenvironment reconstruction, volcanic evolution and geochronology of the Cerro Blanco subcomplex, Nevados de Chillan volcanic complex, Central Chile

    Mee, Katy; Gilbert, Jennie S.; McGarvie, David W.; Naranjo, Jose A.; Pringle, Malcolm S.


    Nevados de Chillán Volcanic Complex, central Chile, has been active for at least 640 ka—a period spanning a number of glacial and interglacial periods. Geologic mapping, radiometric dating and geochemical analysis have identified six new volcanic units and produced four new 40Ar/39Ar ages for Cerro Blanco, the northern subcomplex of Nevados de Chillán volcano. Compositions range from dacite to basaltic-andesite and a new geologic map is presented. Examination of lava fracture structures on bo...

  9. Silicate rock and rock forming mineral neutron activation analysis

    A neutron-activation scheme for the determination of nine rare earths and other trace elements in various rock forming minerals (feldspars, ilmenite, magnetite, pyroxenes) and silicate rocks is presented. The procedure is based on three different irradiations involving three separate samples: - epithermal neutron irradiation (2 days) followed by nondestructive analysis; - thermal neutron irradiation (1 day) followed by instrumental analysis; - thermal neutron irradiation (1 week) followed by radiochemical analysis (precipitation, anion exchange separation, liquid-liquid extraction). Two USGS reference samples - granite G-2 and andesite AGV-1 - have been analysed in order to assess the accuracy of the proposed procedure. Our results agree with previous neutron-activation data. (orig.)

  10. Trepça ore belt and lead and zinc distribution in Badovc mineral deposit, Kosovo (SE Europe)

    S. M. Hyseni; B. N. Durmishaj; B. L. Fetahaj; Large, D.


    The Trepça Belt of Pb-Zn-Ag mineralization is located the NNW-SSE trending Vardar zone. The Belt extends for ever 80 km, and supported five mines during period 1930-2010, and contains a number of the other Pb-Zn occurrences. The replacement and vein type mineralization is hosted primarily by Mesozoic carbonates, but also occasionally by amphibolites, and it display a clear structural control. Mineralization is spatially and genetically related to Neogene andesite-dacite extrusive and sub volc...

  11. Melting features along the Ryukyu slab tear, beneath the southwestern Okinawa Trough - art. no. L19607

    Lin, Jing-yi; Hsu, Sk; Sibuet, Jean-claude


    The present-day active volcanic front associated with the Ryukyu subduction zone extends from Japan to the Ilan plain (northern Taiwan) and is located within the Okinawa Trough, 80-100 km above the Ryukyu slab. An abnormal amount of arc volcanism, which consists of basalt, andesite and rhyolite occurs within the southwestern Okinawa Trough, above a slab tear of the Ryukyu subduction zone (CBVT). The power spectrum analysis of magnetic data shows the occurrence of a thin crust above the slab t...

  12. Syntectonic emplacement of the Middle Jurassic Concon Mafic Dike Swarm, Coastal Range, central Chile (33 degrees S)

    C. Creixell; M.A. Parada; Roperch, Pierrick; D. Morata; Arriagada, C; Arce, C.P. de


    The Concon Mafic Dike Swarm (CMDS) consists of basaltic to andesitic dikes emplaced into deformed Late Palcozoic granitoids during the development of the Jurassic arc of central Chile. The dikes are divided into an early group of thick dikes (512 in) and a late group of thin dikes (0.5-3 m). Two new amphibole Ar-40/Ar-39 dates obtained from undeformed and deformed dikes, constrain the age of emplacement and deformation of the CMDS between 163 and 157 Ma. Based on radiometric ages, field obser...

  13. Mineralogy and fluid inclusion studies in kalchoye Copper- gold deposit, East of Esfahan

    Rezvan Mehvary


    Full Text Available Kalchoye Copper-gold deposit is located about 110 kilometers east of Esfahan province and within the Eocene volcano sedimentary rocks. Sandy tuff and andesite lava are important members of this complex.The form of mineralization in area is vein and veinlet and quartz as the main gangue phase. The main ore minerals are chalcopyrite, chalcocite, galena and weathered minerals such as goethite, iron oxides, malachite and azurite. Studies in area indicate that ore mineralization Kalchoye is low sulfide, quartz type of hydrothermal ore deposits and results of thermometry studies on quartz minerals low- medium fluid with low potential mineralization is responsible for mineralization in this area.

  14. Trace Element Abundance Relationships in the Multi—stage Comagmatic Fractional Crystallization and Their Applications

    汪云亮; 李巨初


    In this study a mathematical expression of trace element abundance relationship for the mul-ti-stage comagmatic fractional crystallization has been established ,based on geochemical studies of the Emeishan basalt-trachyte series and adjacent mafic-ultramafic layered intrusions, as well as on the avail-able data for basalt, andesite, dacite and rhyolite series in southern Andes,Chile ,which have been well documented.It is demonstrated that the abundance constant (R) for a given trace element at dif-ferent stages of fractional crystallization of a parental magma is highly variable,which can be used as a criterion to divide fractional crystallization stages.

  15. The seismic reassessment Mochovce NPP

    The design of Mochovce NPP was based on the Novo-Voronez type WWER-440/213 reactor - twin units. Seismic characteristic of this region is characterized by very low activity. Mochovce NPP site is located on the rock soil with volcanic layer (andesit). Seismic reassessment of Mochovce NPP was done in two steps: deterministic approach up to commissioning confirmed value Horizontal Peak Ground Acceleration HPGA=0.1 g and activities after commissioning as a consequence of the IAEA mission indicate higher hazard values. (author)

  16. The age and constitution of Cerro Campanario, a mafic stratovolcano in the Andes of Central Chile

    Wes Hildreth; Brad Singer; Estanislao Godoy; Francisco Munizaga


    ABSTRACT Cerro Campanario, a towering landmark on the continental divide near Paso Pehuenche, is a glacially eroded remnant of a mafic stratovolcano that is much younger than previously supposed. Consisting of fairly uniform basaltic andesite, rich in olivine and plagioclase, the 10-15 km³ edifice grew rapidly near the end of the middle Pleistocene, about 150-160 ka, as indicated by 40Ar/39Ar and unspiked K-Ar analyses of its lavas.La edad y formación del cerro Campanario, un estratovolcán má...

  17. The zircon SHRIMP chronology and trace element geochemistry of the Carboniferous volcanic rocks in western Tianshan Mountains

    ZHU Yongfeng; ZHANG Lifei; GU Libing; GUO Xuan; ZHOU Jing


    The genesis of the Carboniferous volcanic rocks in the Dahalajunshan group, mainly consisting of trachytes and trachy-andesites and distributing widely in western Tianshan Mountains, remains to be controversial. It has been proposed to be relevant to "rift" or "plume". Detailed petrology and geochemical data presented in this paper show that these volcanic rocks represent typical continental arc magmatism. The volcanic rocks are mainly trachy-andesitic, and the magma source is enriched in LILE, Th and Pb, and depleted in HFSE and Ce. Trace element geochemical study suggests that the basalts could be modeled by 7%-11% partial melt of garnet lherzolite. The volcanic rocks in the Dahalajunshan group are neither the products of "rift" nor so-called "plume" but represent the continental island arc of the Paleo-Southern Tianshan Ocean. The mantle wedge had been modified by the melt generating in subduction zone during a long evolution history of this island arc. The continental crust materials (i.e. mainly sediment on ocean floor) had been added into island arc through melt in subduction zone. Volcanic rocks occurring in different regions might represent magma eruption in different time. The zircon SHRIMP dating indicates that the ages of the basalt varies between 334.0 Ma and 394.9 Ma. The 13 analyses give an average age of 353.7 (4.5 Ma (MSWD = 1.7). The apparent ages of zircons in trachy-andesite vary between 293.0 Ma and 465.4 Ma. All analyses fall on the U-Pb concordant line and are divided into two groups. 8 analyses produce an average age of 312.8(4.2 Ma (MSWD = 1.7), which represents the crystallizing age of zircon rims in trachy-andesite. The acquired two ages (i.e. 354 and 313 Ma) belong to the Early Carboniferous and Late Carboniferous epochs, respectively. Thus, the Dahalajunshan group would be separated into several groups with the accumulation of high-quality age dating and data of trace element and isotopic geochemistry, in our opinion.


    Sz. Fischer


    Full Text Available Purpose. Using adequate granular materials and layer structures in the railway super- and substructure is able to stabilise railway track geometry. For this purpose special behaviour of above materials has to be determined, e.g. inner shear resistance. Inner shear resistance of granular media with and without geogrid reinforcement in different depths is not known yet. Methodology. The author developed a special laboratory method to measure and define inner shear resistance of granular materials, it is called «multi-level shear box test». This method is adequate to determine inner shear resistance (pushing force vs. depth (distance from the «zero» surface. Two different granular materials: andesite railway ballast (31.5/63 mm and andesite railway protection layer material (0/56 mm, and seven different types of geogrids (GG1…GG7 were used during the tests. Findings. Values of inner shear resistance functions of andesite railway ballast without geogrid reinforcement and reinforced with different types of geogrids and andesite granular protection layer in function of the vertical distance from the geogrid plane were determined with multi-layer shear box tests when the material aggregation is uncompacted and compacted. Only the compacted sample was tested in case of the 0/56 mm protection layer. Cubic polynomial regression functions fitted on the mean values of the measurements are described graphically. Determination coefficients with values of R2>0.97 were resulted in all the cases of regression functions. Based on the polynomial regression functions fitted on the mean values of the test results, three increasing factors were determined in function of the distance measured from the geogrid. Increasing factor «A», «B» and «D». Originality. Multi-level shear box test, developed by the author, is certified unequivocally adequate for determining inner shear resistance of reinforced and unreinforced granular materials, e.g. railway ballast

  19. Mantle source beneath Turrialba volcano (Costa Rica): a geochemical investigation

    Di Piazza, A.; Rizzo, A. L.; Barberi, F.; Carapezza, M. L.; Sortino, F.; De Astis, G.; Romano, C.


    In this study we analysed rocks and noble gas composition of fluid inclusions (FIs) hosted in olivine crystals contained in a suite of eruptive products of the last 10ka of activity of Turrialba volcano, Cordillera Central, Costa Rica. The suite of analyzed rocks display a calc-alkaline affinity, ranging in composition from basaltic-andesite to dacite. Trace element patterns indicate a typical behavior of subduction-related magmas and also the clear contribution of an OIB-like signature at source. A group of andesites displays also adakite-like geochemical features, as evidenced by their constant depletion in HFSE elements. Sr isotope (0.703593 - 0.703678) and Nd isotope ratios (0.512960 - 0.512968) suggest that Turrialba magmas belong to one of the less contaminated mantle source of Central America. The 3He/4He ratio of fluid inclusions from the most mafic eruptive products (basaltic-andesites) varies from 7.86 to 8.07 Ra, while that from andesite lavas varies from 7.03 to 7.18 Ra. In order to understand the mantle source feeding Turrialba volcano, we performed a geochemical investigation on fumarolic gases of summit craters. The He isotope composition of dry gases of Turrialba volcano is characterized by extremely high R/Ra values (7.08-7.96 Ra). The highest 3He/4He ratios were measured at both West and Central Craters (7.93-7.96 Ra and 7.78-7.88 Ra, respectively), and are the highest values of the entire Central America. Despite the observed variability, the 3He/4He ratio of fumarolic gases and FIs from Turrialba volcano is well in the range of arc related volcanism (~7-8 Ra; Hilton et al., 2002), and represents the signature of a mantle wedge in which the contamination by crustal fluids is small to negligible. In addition the occurrence of recent adakite-like magmatism suggests the presence of an abnormal heating of the subducting lithosphere under Turrialba volcano, allowing even old or cold oceanic crust to melt.

  20. Trepça Ore Belt and Stan Terg mine – Geological overview and interpretation, Kosovo (SE Europe

    Sylejman Hyseni


    Full Text Available The Trepça Belt of Pb-Zn-Ag mineralization is located within the NNW-SSE trending Vardar zone. The Beltextends for over 80 km, and supported five mines during the period 1930-2008. It contains a number of the otherPb-Zn occurrences too. The replacement and vein type mineralization is hosted primarily by Mesozoic carbonates,but also occasionally by amphibolites, and displays a clear structural control. Mineralization is spatially and geneticallyrelated to Neogene andesite-dacite extrusives and sub-volcanic intrusives. Only Stan Terg mine is presentedin this paper.

  1. SCB試験による水蒸気環境下における岩石の破壊靱性の評価

    尾原, 祐三; 佐々木, 一裕; 吉永, 徹; オバラ, ユウゾウ; ササキ, カズヒロ; ヨシナガ, トオル; Obara, Yuzo; Sasaki, Kazuhiro; Yoshinaga, Toru


    The influence of water vapor pressure of surrounding environment on fracture toughness of rock is clarified, based on the results of a series of semi-circular bend (SCB) test under various water vapor pressures. The rocks used in the test are Kumamoto andesite and Kunnum basalt, and the range of water vapor pressure is from 10-3 to 103 Pa. The results obtained in this paper are summarized as follows:1) Elastic modulus at 60% of maximum load depends on water vapor pressure, and decreases with ...

  2. Update of map the volcanic hazard in the Ceboruco volcano, Nayarit, Mexico

    Suarez-Plascencia, C.; Camarena-Garcia, M. A.; Nunez-Cornu, F. J.


    The Ceboruco Volcano (21° 7.688 N, 104° 30.773 W) is located in the northwestern part of the Tepic-Zacoalco graben. Its volcanic activity can be divided in four eruptive cycles differentiated by their VEI and chemical variations as well. As a result of andesitic effusive activity, the "paleo-Ceboruco" edifice was constructed during the first cycle. The end of this cycle is defined by a plinian eruption (VEI between 3 and 4) which occurred some 1020 years ago and formed the external caldera. During the second cycle an andesitic dome built up in the interior of the caldera. The dome collapsed and formed the internal caldera. The third cycle is represented by andesitic lava flows which partially cover the northern and south-southwestern part of the edifice. The last cycle is represented by the andesitic lava flows of the nineteenth century located in the southwestern flank of the volcano. Actually, moderate fumarolic activity occurs in the upper part of the volcano showing temperatures ranging between 20° and 120°C. Some volcanic high frequency tremors have also been registered near the edifice. Shows the updating of the volcanic hazard maps published in 1998, where we identify with SPOT satellite imagery and Google Earth, change in the land use on the slope of volcano, the expansion of the agricultural frontier on the east sides of the Ceboruco volcano. The population inhabiting the area is 70,224 people in 2010, concentrated in 107 localities and growing at an annual rate of 0.37%, also the region that has shown an increased in the vulnerability for the development of economic activities, supported by highway, high road, railroad, and the construction of new highway to Puerto Vallarta, which is built in the southeast sector of the volcano and electrical infrastructure that connect the Cajon and Yesca Dams to Guadalajara city. The most important economic activity in the area is agriculture, with crops of sugar cane (Saccharum officinarum), corn, and jamaica

  3. Subsurface geology of Los Humeros geothermal field, Puebla, Mexico; Geologia del subsuelo del campo geotermico de Los Humeros, Puebla, Mexico

    Cedillo Rodriguez, Fidel [Comision federal de Electricidad, Perote, Veracruz, Mexico(Mexico)


    In the 1980s, most geologists correlated subsurface geology at Los Humeros geothermal field using penetrated by faults, as interpreted by photogeology. These were structural objectives for geothermal drilling programs. Recent petrology reinterpretation of data from well cutting lets us identify nine lithologic units, with the Toba Vitrea Humeros as the index horizon. The study of the subsurface geology allows us to demonstrate- based on the distribution, depth, and thickness of the lithologic units- that the augite andesites, the Toba Vitrea Humeros, the hornblende andesites, the basalt, and the metamorphosed limestone are affected by system of hidden faults (with no surface evidence) replaced by major fracture zones able to contain steam. Thus these hidden faults are the structural objectives controlling design and sitting of new wells. We conclude that the lithologic unit of augite andesites forms the upper geothermal reservoir, and the hornblende andesites and basalt comprise the lower reservoir- separated from each other by the Toba Vitrea Humeros lithologic unit. Based on the subsurface geologic model, we propose drilling 40 new wells, a long and parallel the north-south faults system. [Spanish] En la decada de los 80s se agrupo la geologia del subsuelo de Los Humeros en cuatro unidades litologicas afectadas por fallas interpretadas por fotogeologia. Estas fallas eran el objetivo estructural para programar la perforacion de pozos geotermicos. La reinterpretacion de los datos de petrologia de las muestras de canal permite identificar nueve unidades litologicas, de las cuales la unidad Toba Vietrea Humeros se comporta como horizonte indice. El estudio de la geologia del subsuelo permite demostrar, con base en la distribucion, profundidades y espesores de las unidades litologicas, que las andesitas de augita, la Toba Vitrea Humeros, las andesitas de hornblenda, los basaltos, y las calizasmetamorfizadas estan afectadas por sistemas de fallas ocultas (sin

  4. Multi-elemental characterization of volcanic and vulcano-sedimentary rocks from Pina petroleum ore, central Cuba

    Concentrations of 32 elements in 22 clay, limestone, tuff and volcanic rock samples from the Pina ore have been obtained by neutron activation and X-ray fluorescence analyses. Several LILE (large ion lithofile elements) and REE (rare earth element) concentration diagrams showed the calc-alkaline character of the volcanic rocks corresponding to the Greater Antilles Island, Arc. The basaltic andesite behavior of the rocks studied was confirmed by comparing the average concentrations obtained from tuffs and volcanic rocks with proper mean values of rock elemental compositions of the earth's crust. (Author)

  5. Photograph of the month


    Dykes in the Bidkhan strato-volcano located in the south eastern part of the Urumieh - Dokhtar magmatic arc, south west of Kerman, Iran. Repetitive dykes intrude through Oligo-Miocene Bidkhan pyroclastic sediments. A light dacitic dyke grew syntaxially within a gray andesitic dyke. The dykes trend NE and cross Oligo- Miocene lahar and pyroclastic sediments of the south west part of Bidkhan volcano caldera. Width of view appr. 10m. South of Bardsir city, SW Kerman, Iran. 29° 33.267≠ N, 056°, 27.25≠ E. Photograph © Reihaneh Keihanizadeh, Kerman, Iran. (

  6. Archaeomagnetic Investigation at Chapultepec, Mexico City: Case Study of Classical Settlers

    Lopez, V.; Romero, E.; Soler-Arechalde, A. M.; Espinosa, G.


    During the restoration campaign at the Chapultepec Park in Mexico City downtown, a teotihuacan settlement was found at the south flank of Chapultepec Hill. Samples represent a kind of irregular home kilns with a hole in their central part bounded by andesite rocks. Alternating field demagnetization had been employed. Rock magnetic measurements which included: Hysteresis, continuous susceptibility and isothermal remanence experiments revealed that some spinels, most probably magnetite or Ti-poor Titanomagnetites are responsible for the remanence. An archeomagnetic date obtained here is of 525 AD which is in good agreement with other evidences of the Teotihuacan Classic Metepec period (450-600 AD).

  7. Geochemical Signature of Mesozoic Volcanic and Granitic Rocks in Madina Regency Area, North Sumatra, Indonesia, and its Tectonic Implication

    Iskandar Zulkarnain

    2014-01-01 samples consisting of two Permian-Triassic basalts, two Triassic-Jurassic granitic rocks, and a Miocene andesite were collected from the Madina Regency area in North Sumatra that is regionally situated on the West Sumatra Block. Previous authors have proposed three different scenarios for the geological setting of West Sumatra Permian Plutonic-Volcanic Belt, namely an island-arc, subduction related continental margin arc, and continental break...

  8. Fading characteristics of martian analogue materials and the applicability of a correction procedure

    Morthekai, P. [Radiation Research Department, Riso National Laboratory, Technical University of Denmark, Roskilde (Denmark)], E-mail:; Jain, M. [Radiation Research Department, Riso National Laboratory, Technical University of Denmark, Roskilde (Denmark); Murray, A.S. [Nordic Laboratory for Luminescence Dating, Department of Earth Sciences, Arhus University, Riso National Laboratory, Roskilde (Denmark); Thomsen, K.J.; Botter-Jensen, L. [Radiation Research Department, Riso National Laboratory, Technical University of Denmark, Roskilde (Denmark)


    The anomalous fading of trapped charge in martian analogue materials such as basalt and andesite rock samples is measured. Optically stimulated luminescence (OSL) signals show rapid fading (of between 4% and 27% per decade). Fading rates obtained using high temperature thermoluminescence signals are smaller. The importance of knowing whether a standard fading correction method is applicable to samples of unknown age is illustrated by application to an 'infinitely old' known-age basalt, for which both the uncorrected and fading-corrected natural signals lie within the approximately linear region of the growth curve.

  9. Thermoluminescence dating in the South-West Pacific region

    The archaeometry laboratory of the University of Adelaide has undertaken a variety of dating projects for archaeologists in the region. For example, a survey of Pacific Island pottery has shown that themoluminescence dating is likely to be severely limited in usefulness on islands remote from the continental shelf i.e., the andesitic island arcs and oceanic islands. On the mainland of Australia, we have dated prehistoric campsites using ovenstones from fireplaces and have compared C-14 ages with themoluminescent ages. Where there is a close stratigraphic association of the C-14 and TL materials, there is good agreement between the two methods. (author)

  10. Magmas and their sources: A special issue honoring Frederick A. Frey

    Garcia, Michael O.; Rhodes, J. Michael; Huang, Shichun; Hickey-Vargas, Rosemary


    This special issue is dedicated to Frederick A. Frey (Fig. 1), a pioneer in the use of trace element geochemistry (especially the rare-earth elements, REE) to interpret the origin and evolution of basalts and andesites, peridotites, granites, meteorites, tektites and even sediments. Fred's remarkable career spans more than 5 decades starting in 1964 with his seminal paper with advisor Larry Haskin entitled "rare earths in oceanic basalts" (Frey and Haskin, 1964). Given that Fred was an Associate Editor of Geochimica et Cosmochimica Acta (GCA) for 20 years, GCA is a highly appropriate venue for this collection of twenty-seven new scientific papers in his honor.