Direction of reprocessing technology development based on 30 years operation of Tokai reprocessing plant

International Nuclear Information System (INIS)

Nomura, S; Tanaka, T.; Ohshima, H.

2006-01-01

Full text: Full text: Recent global interest focuses the possibility of recycling of spent fuel with advanced fast reactor fuel cycle system. Goal of closed fuel cycle is to achieve the maximum use of uranium resources and minimum disposal of waste by multi recycle of TRU as a competitive nuclear energy system. The future reprocessing and fuel fabrication system should be synchronized completely with the advanced reactor system and waste treatment and disposal back-end system to complete closed fuel cycle. To realize such system, current reprocessing system should be changed to handle Pu-U-Minor Actinide with more reductions in the cost and less waste volume, as well as an inherent proliferation resistance. For the successful industrialization of advanced reprocessing technology, it is necessary to combine three key elements of R and D efforts, engineering base demonstration and experiences of plant operation. Tokai Reprocessing Facilities licensed a maximum capacity of 0.7tHM/day began a hot operation in 1977 and reprocessed l,100tHM U02 spent fuel and 20tHM ATR-MOX with a continuous technological improvements under IAEA full scope safeguards. With 30 years experience, candidate of key technologies proposed for realizing the next advanced reprocessing are as follows: 1) Simplified co-extraction process of Pu-Np-U by using multistage centrifugal extractors in stead of pulsed columns; 2) Corrosion free components in acid condition by using corrosion resistant refractory alloys and ceramics; 3) Co-conversion technology to MA containing MOX powder by micro-wave heating method for a short process for MA containing MOX pellets fabrication; 4) Advanced verification of high level radioactive liquid waste combining separation technology of TRU and LLFP elements; 5) Advanced chemical analysis and monitoring system for TRU elements in a plant. These advanced reprocessing technologies will be applied mainly to reprocess the LWR spent fuel accumulated past and future

Technical study report on reprocessing system

International Nuclear Information System (INIS)

Tanaka, Hiroshi; Kasai, Yoshimitsu; Kawamura, Fumio

2000-07-01

The feasibility studies on commercialized fast breeder reactor (FBR) recycle system, in which reactor system and recycle technologies are related on consideration, are performed considering the attainable perspectives for the followings: ensuring safety, economic competitiveness to future LWRs, efficient utilization of resources, reduction of environmental burden, and enhancement of nuclear non-proliferation. In the studies of Reprocessing system of FBR, evaluation was made for the non-aqueous reprocessing of pyrochemical and fluoride volatility process and also for the aqueous reprocessing with a view to streamlining. As a result, it was estimated that each system has prospects of coming into practical use in terms of technique. In the economical efficiency assessment, it was estimated to have economic competitiveness to future LWRs. And the technical research items of each system are picked out. Hereafter, more detail design study will be performed for each system. (author)

Spent fuel reprocessing and minor actinide partitioning safety related research at the UK National Nuclear Laboratory

International Nuclear Information System (INIS)

Carrott, Michael; Flint, Lauren; Gregson, Colin; Griffiths, Tamara; Hodgson, Zara; Maher, Chris; Mason, Chris; McLachlan, Fiona; Orr, Robin; Reilly, Stacey; Rhodes, Chris; Sarsfield, Mark; Sims, Howard; Shepherd, Daniel; Taylor, Robin; Webb, Kevin; Woodall, Sean; Woodhead, David

2015-01-01

The development of advanced separation processes for spent nuclear fuel reprocessing and minor actinide recycling is an essential component of international R and D programmes aimed at closing the nuclear fuel cycle around the middle of this century. While both aqueous and pyrochemical processes are under consideration internationally, neither option will gain broad acceptance without significant advances in process safety, waste minimisation, environmental impact and proliferation resistance; at least when compared to current reprocessing technologies. The UK National Nuclear Laboratory (NNL) is developing flowsheets for innovative aqueous separation processes. These include advanced PUREX options (i.e. processes using tributyl phosphate as the extractant for uranium, plutonium and possibly neptunium recovery) and GANEX (grouped actinide extraction) type processes that use diglycolamide based extractants to co-extract all transuranic actinides. At NNL, development of the flowsheets is closely linked to research on process safety, since this is essential for assessing prospects for future industrialisation and deployment. Within this context, NNL is part of European 7. Framework projects 'ASGARD' and 'SACSESS'. Key topics under investigation include: hydrogen generation from aqueous and solvent phases; decomposition of aqueous phase ligands used in separations prior to product finishing and recycle of nitric acid; dissolution of carbide fuels including management of organics generated. Additionally, there is a strong focus on use of predictive process modelling to assess flowsheet sensitivities as well as engineering design and global hazard assessment of these new processes. (authors)

Development of Spectrophotometric Process Monitors for Aqueous Reprocessing Facilities

International Nuclear Information System (INIS)

Smith, N.; Krebs, J.; Hebden, A.

2015-01-01

The safeguards envelope of an aqueous reprocessing plant can be extended beyond traditional measures to include surveillance of the process chemistry itself. By observing the concentration of accountable species in solution directly, a measure of real time accountancy can be applied. Of equal importance, select information on the process chemistry can be determined that will allow the operator and inspectors to verify that the process is operating as intended. One of the process monitors that can be incorporated is molecular spectroscopy, such as UV-Visible absorption spectroscopy. Argonne National Laboratory has developed a process monitoring system that can be tailored to meet the specific chemistry requirements of a variety of processes. The Argonne Spectroscopic Process monitoring system (ASP) is composed of commercial-off-the-shelf (COTS) spectroscopic hardware, custom manufactured sample handling components (to meet end user requirements) and the custom Plutonium and Uranium Measurement and Acquisition System (PUMAS) software. Two versions of the system have been deployed at the Savannah River Site's H-Canyon facility, tailored for high and low concentration streams. (author)

Nuclear Fuel Reprocessing

International Nuclear Information System (INIS)

Simpson, Michael F.; Law, Jack D.

2010-01-01

This is a submission for the Encyclopedia of Sustainable Technology on the subject of Reprocessing Spent Nuclear Fuel. Nuclear reprocessing is the chemical treatment of spent fuel involving separation of its various constituents. Principally, it is used to recover useful actinides from the spent fuel. Radioactive waste that cannot be re-used is separated into streams for consolidation into waste forms. The first known application of nuclear reprocessing was within the Manhattan Project to recover material for nuclear weapons. Currently, reprocessing has a peaceful application in the nuclear fuel cycle. A variety of chemical methods have been proposed and demonstrated for reprocessing of nuclear fuel. The two most widely investigated and implemented methods are generally referred to as aqueous reprocessing and pyroprocessing. Each of these technologies is described in detail in Section 3 with numerous references to published articles. Reprocessing of nuclear fuel as part of a fuel cycle can be used both to recover fissionable actinides and to stabilize radioactive fission products into durable waste forms. It can also be used as part of a breeder reactor fuel cycle that could result in a 14-fold or higher increase in energy utilization per unit of natural uranium. Reprocessing can also impact the need for geologic repositories for spent fuel. The volume of waste that needs to be sent to such a repository can be reduced by first subjecting the spent fuel to reprocessing. The extent to which volume reduction can occur is currently under study by the United States Department of Energy via research at various national laboratories and universities. Reprocessing can also separate fissile and non-fissile radioactive elements for transmutation.

Power Reactor Fuel Reprocessing Plant-1: a stepping stone in Indian PHWR spent fuel reprocessing

International Nuclear Information System (INIS)

Pradhan, Sanjay; Dubey, K.; Qureshi, F.T.; Lokeswar, S.P.

2017-01-01

India has low reserves of uranium and high reserves of thorium. In order to optimize resource utilization India has adopted a closed fuel cycle to ensure long-term energy security. The optimum resource utilization is feasible only by adopting reprocessing, conditioning and recycle options. It is very much imperative to view spent fuel as a vital resource material and not a waste to be disposed off. Thus, spent nuclear fuel reprocessing forms an integral part of the Indian Nuclear Energy Programme. Aqueous reprocessing based on PUREX technology is in use for more than 50 years and has reached a matured status

The main chemical safety problems in main process of nuclear fuel reprocessing plant

International Nuclear Information System (INIS)

Song Fengli; Zhao Shangui; Liu Xinhua; Zhang Chunlong; Lu Dan; Liu Yuntao; Yang Xiaowei; Wang Shijun

2014-01-01

There are many chemical reactions in the aqueous process of nuclear fuel reprocessing. The reaction conditions and the products are different so that the chemical safety problems are different. In the paper the chemical reactions in the aqueous process of nuclear fuel reprocessing are described and the main chemical safety problems are analyzed. The reference is offered to the design and accident analysis of the nuclear fuel reprocessing plant. (authors)

Formation of aqueous complexes of metal ions formed during the reprocessing of nuclear fuels with ortho-phenanthroline and dibutylphosphate

International Nuclear Information System (INIS)

Musikas, C.; Le Marois, G.; Racinoux, J.

1979-01-01

In this work the formation of aqueous complexes of metalions (lanthanides, actinides) was investigated that occurs during reprocessing of nuclear combustibles with ortho-phenanthroline and dibutylphosphate. Complexes with different ligand numbers and solubility are formed. Cationic and anionic forms according to the DBP concentration in the extraction solution. Acid-base titrations, absorption spectra and solubility determinations were used for the characterization. (RB) [de

Reprocessing of ''fast'' fuel in France

International Nuclear Information System (INIS)

Sauteron, J.; Bourgeois, M.; Le Bouhellec, J.; Miquel, P.

1976-05-01

The results of laboratory studies as well as pilot testing (AT-I La Hague, Marcoule, Fontenay-aux-Roses) in reprocessing of fast breeder reactor fuels are described. The paper covers all steps: head end, aqueous and fluoride volatility processes, and waste treatment. In conclusion, it is demonstrated why it is still too early to define a strategy of industrial reprocessing for this reactor type

Report on the NGS3 Working Group on Safeguards by Design For Aqueous Reprocessing Plants

Energy Technology Data Exchange (ETDEWEB)

Johnson, Shirley J.; Ehinger, Michael; Schanfein, Mark

2011-02-01

The objective of the Working Group on SBD for Aqueous Reprocessing Facilities was to provide recommendations, for facility operators and designers, which would aid in the coordination and integration of nuclear material accountancy and the safeguards requirements of all concerned parties - operators, state/regional authorities, and the IAEA. The recommendations, which are to be provided to the IAEA, are intended to assist in optimizing facility design and operating parameters to ensure the safeguardability of the facility while minimizing impact on the operations. The one day Working Group session addressed a wide range of design and operating topics.

The reprocessing of advanced mixed lithium orthosilicate/metatitanate tritium breeder pebbles

Energy Technology Data Exchange (ETDEWEB)

Leys, Oliver, E-mail: oliver.leys@kit.edu [Karlsruhe Institute of Technology, Institute for Applied Materials, Eggenstein-Leopoldshafen, 76344 (Germany); Bergfeldt, Thomas; Kolb, Matthias H.H.; Knitter, Regina [Karlsruhe Institute of Technology, Institute for Applied Materials, Eggenstein-Leopoldshafen, 76344 (Germany); Goraieb, Aniceto A. [Karlsruhe Beryllium Handling Facility, Eggenstein-Leopoldshafen, 76344 (Germany)

2016-06-15

Highlights: • The recycling of advanced breeder pebbles without a deterioration of the material properties is possible using a melt-based process. • The only accumulation of impurities upon reprocessing, results from the platinum crucible alloy used for processing. • It is possible to replenish burnt-up lithium by additions of LiOH·H{sub 2}O to the melt during reprocessing. - Abstract: The recycling of tritium breeding materials will be necessary for any future use of nuclear fusion energy due to economical as well as ecological considerations. In the case of the solid breeder blanket concept, the ceramic pebble beds that are intended for the generation of tritium will eventually need to be restored due to depleted lithium levels as well as due to fractured pebbles, which will cause a deterioration of the pebble bed properties. It is proposed that the pebbles, which are fabricated using a melt-based process, are recycled using the same initial process, by replenishing the lithium levels and reforming the pebbles at the same time. To prove this recycling scheme, advanced ceramic pebbles were fabricated and then re-melted multiple times to prove that the reprocessing did not have any negative effect on the pebble properties and secondly, pebbles were produced with a simulated lithium burn-up and subsequently replenished by additions of LiOH to the melt. It was shown that the re-melting and lithium re-enrichment had no effect on the pebble properties, demonstrating that a melt-based process is suitable for recycling used breeder pebbles.

Design study on advanced nuclear fuel recycling system by pyrometallurgical reprocessing technology

Energy Technology Data Exchange (ETDEWEB)

Kasai, Yoshimitsu; Kakehi, Isao; Moro, Satoshi; Tobe, Kenji; Kawamura, Fumio; Higashi, Tatsuhiro; Yonezawa, Shigeaki [Japan Nuclear Cycle Development Inst., Oarai, Ibaraki (Japan). Oarai Engineering Center; Yoshiuji, Takahiro

1998-12-01

The Japan Nuclear Fuel Cycle Development Institute is conducting research and development on the nuclear fuel recycling system, which will improve the economy, safety, and environmental impact of the nuclear fuel recycling system in the age of the FBR. The System Engineering Division in the O-arai Engineering Center has conducted a design study on an advanced nuclear fuel recycling system for FBRs by using pyrometallurgical reprocessing technology. The system is an economical and compact module-type system, and can be used for reprocessing oxide fuel and also new types of fuel (metal fuel and nitride fuel). This report describes the concept of this system and results of the design study. (author)

Design study on advanced nuclear fuel recycling system by pyrometallurgical reprocessing technology

International Nuclear Information System (INIS)

Kasai, Yoshimitsu; Kakehi, Isao; Moro, Satoshi; Tobe, Kenji; Kawamura, Fumio; Higashi, Tatsuhiro; Yonezawa, Shigeaki; Yoshiuji, Takahiro

1998-01-01

The Japan Nuclear Fuel Cycle Development Institute is conducting research and development on the nuclear fuel recycling system, which will improve the economy, safety, and environmental impact of the nuclear fuel recycling system in the age of the FBR. The System Engineering Division in the O-arai Engineering Center has conducted a design study on an advanced nuclear fuel recycling system for FBRs by using pyrometallurgical reprocessing technology. The system is an economical and compact module-type system, and can be used for reprocessing oxide fuel and also new types of fuel (metal fuel and nitride fuel). This report describes the concept of this system and results of the design study. (author)

Advanced reprocessing developments in Europe contribution of European projects ACSEPT and ACTINET-I3

Energy Technology Data Exchange (ETDEWEB)

Bourg, S.; Poinssot, C. [CEA DEN, Nuclear Energy Div., RadioChemistry and Processes Dept., F-30207Bagnols sur Ceze (France); Geist, A. [KIT-INE (Germany); Cassayre, L. [CIEMAT (Spain); Rhodes, C. [NNL-UK (United Kingdom); Ekberg, C. [CHALMERS (Sweden)

2012-07-01

Nuclear energy has more than ever to demonstrate that it can contribute safely and on a sustainable way to answer the international increase in energy needs. Actually, in addition to an increased safety of the reactors themselves, its acceptance is still closely associated to our capability to reduce the lifetime of the nuclear waste, to manage them safely and to propose options for a better use of the natural resources. Spent fuel reprocessing can help to reach these objectives. But this cannot be achieved only by optimizing industrial processes through engineering studies. It is of a primary importance to increase our fundamental knowledge in actinide sciences in order to build the future of nuclear energy on reliable and scientifically-founded results, and therefore meet the needs of the future fuel cycles in terms of fabrication and performance of fuels, reprocessing and waste management. At the European level, both the collaborative project ACSEPT and the Integrated Infrastructure Initiative ACTINET-I3 work together to improve our knowledge in actinides chemistry and therefore develop advanced separation processes. These tools are complementary and work in close connection on some specific issues such as the understanding of the selectivity of extracting organic ligands. By offering trans-national access to the main nuclear research facility in Europe, ACTINET-I3 aims at increasing the knowledge in actinide sciences by gathering all the expertise available in European nuclear research institutes or university and giving them the opportunity to come and work in hot-labs (ITU, Atalante...) or beamlines (ESFR, ANKA, PSI) ACSEPT is focused on the development of advanced separation processes, both aqueous and pyrochemical. Head-end steps, fuel re-fabrication, solvent treatment, waste management are also taken into account. In aqueous process development, the SANEX and innovative SANEX flowsheets demonstration were successfully achieved. Chemical systems were

Management of spent solvents of reprocessing origin

International Nuclear Information System (INIS)

Manohar, S.; Srinivas, C.; Vincent, T.; Wattal, P.K.

2001-01-01

Spent solvents of reprocessing origin constitute a major portion of radioactive liquid organic wastes arising from nuclear activity. An in-depth study of this waste stream has led to the evolution of a complete management option, which addresses not only the concern of radioactivity but also its organic nature. This is based on alkaline hydrolysis of Tri-n-butyl phosphate (TBP), which converts it into aqueous soluble products, viz. sodium salt of dibutyl phosphoric acid and butanol. During the process of alkaline hydrolysis almost all the activity associated with the waste gets transferred into the aqueous phase. The recovered diluent virtually free of activity and TBP can be recycled, and in case of it not meeting reprocessing standards, can be incinerated. The process generated aqueous waste is found compatible with cement and can be immobilized in cement matrix. (author)

Advanced Purex process for the new French reprocessing plants

International Nuclear Information System (INIS)

Viala, M.; Ledermann, P.; Pradel, P.

1993-01-01

The paper describes the main process innovations of the new Cogema reprocessing plants of La Hague (UP3 and UP2 800). Major improvements of process like the use of rotary dissolvers and annular columns, and also entirely new processes like solvent distillation and plutonium oxidizing dissolution, yield an advanced Purex process. The results of these innovations are significant improvements for throughput, end-products purification performances and waste minimization. They contribute also to limit personnel exposure. The main results of the first three years of operation are described. (author). 3 refs., 5 figs

Chemical process developments in reprocessing from 1965--1975 in the Institute for Hot Chemistry

International Nuclear Information System (INIS)

Baumgaertner, F.

Work on the aqueous reprocessing of fuels is described. The following are discussed: LABEX (laboratory-scale extraction), MILLI facility (1 kg/day), problems of aqueous reprocessing, centrifugal extractor development, radiolytic products from Purex process, and TAMARA facility. Results of the MILLI operation are reviewed. Solutions to problems are discussed

Development of centrifugal contactor for FBR fuel reprocessing

International Nuclear Information System (INIS)

Washiya, Tadahiro; Takeuchi, Masayuki; Suganuma, Takashi; Aose, Shinichi; Ogino, Hideki

2003-01-01

In the Feasibility Study on Commercialized Fast Reactor Cycle Systems, the aqueous reprocessing technology is nominated as a candidate for future reprocessing system, which supposes to apply a centrifugal contactor in the extraction process. For the reprocessing plant, the centrifugal contactor has great advantages such as reducing solvent degradation, improving of equipment utilization rate, compact designing of equipment layout and critical safety domination. From these advantages, the centrifugal contactor is crucial equipment in the aqueous reprocessing process. Since 1985, JNC has been developing the centrifugal contactor. The single unit development has been accomplished and basic characteristics such as extraction performance, fluidic performance and remote maintenance performance have been determined. A durability test has been conducted for high longevity, with consideration given to the nitric acid mist and estimation of the equipment lifetime. System test equipment with centrifugal contactors of engineering scale was installed, and uranium test was conducted. Up to now, a standard flow sheet test in the extraction process and mal-operation test assuming the one stage shutdown condition have been performed. (author)

Advanced hybrid process with solvent extraction and pyro-chemical process of spent fuel reprocessing for LWR to FBR

International Nuclear Information System (INIS)

Fujita, Reiko; Mizuguchi, Koji; Fuse, Kouki; Saso, Michitaka; Utsunomiya, Kazuhiro; Arie, Kazuo

2008-01-01

Toshiba has been proposing a new fuel cycle concept of a transition from LWR to FBR. The new fuel cycle concept has better economical process of the LWR spent fuel reprocessing than the present Purex Process and the proliferation resistance for FBR cycle of plutonium with minor actinides after 2040. Toshiba has been developing a new Advanced Hybrid Process with Solvent Extraction and Pyrochemical process of spent fuel reprocessing for LWR to FBR. The Advanced Hybrid Process combines the solvent extraction process of the LWR spent fuel in nitric acid with the recovery of high pure uranium for LWR fuel and the pyro-chemical process in molten salts of impure plutonium recovery with minor actinides for metallic FBR fuel, which is the FBR spent fuel recycle system after FBR age based on the electrorefining process in molten salts since 1988. The new Advanced Hybrid Process enables the decrease of the high-level waste and the secondary waste from the spent fuel reprocessing plants. The R and D costs in the new Advanced Hybrid Process might be reduced because of the mutual Pyro-chemical process in molten salts. This paper describes the new fuel cycle concept of a transition from LWR to FBR and the feasibility of the new Advanced Hybrid Process by fundamental experiments. (author)

A study on adsorption onto TODGA resin after electrolytic reduction in ERIX process for reprocessing spent FBR-MOX fuel

International Nuclear Information System (INIS)

Hoshi, Harutaka; Arai, Tsuyoshi; Wei, Yuezhou; Kumagai, Mikio; Asakura, Toshihide; Morita, Yasuji

2005-01-01

For reprocessing spent FBR-MOX fuel, an advanced aqueous reprocessing process ''ERIX process'' has been developed. In this system, hydrazine is used as reduction holding reagent for the valance adjustment of U by electrolytic reduction in nitric acid solution. Therefore, hydrazine is contained in high level liquid waste after separation of U, Pu and Np. Effect of hydrazine on adsorption of FP onto TODGA resin was examined. When hydrazine concentration was less than 0.3 M, effect on the distribution coefficient was negligibly small. After electrolytic reduction, some elements exist as lower valence state. Ru and Tc are most difficult elements to control their behavior in aqueous process. The distribution coefficient of both Ru and Tc onto TODGA decreased after electrolytic reduction, because they are reduced to lower valence. Hence, it is difficult for Ru or Tc to diffuse to allover the process and separation of MA from Tc and Ru was enhanced by electrolytic reduction. (author)

Advanced concepts under development in the United States Breeder-Fuel-Reprocessing Program

International Nuclear Information System (INIS)

Burch, W.D.

1981-01-01

Advanced concepts and techniques for the fuel reprocessing step are being developed. These concepts have been incorporated into the conceptual design of a Hot Experimental Facility (HEF), which is intended to demonstrate reprocessing of the first US breeder demonstration reactor. To achieve system reliability and reduce occupational doses, a concept of totally remote operation and maintenance (termed Remotex) has been conceived and is being developed. In this concept, maintenance and mechanical operations are accomplished with remotely operated bilateral force-reflecting electronic master/slave manipulators. Suitable transport systems, coupled with remote closed-circuit television viewing, are provided to extend man's capabilities into the hostile cell environment. New equipment concepts are being developed for the fuel dismantling and shearing step, a high-temperature dry process termed voloxidation to remove tritium, a continuous rotary dissolver, and for an improved centrifugal solvent contractor. Techniques have been developed, using engineering-scale equipment with active tracers for retention of 85 Kr, radioiodine, 14 C, and 3 H

An overview on dry reprocessing of irradiated nuclear fuels

International Nuclear Information System (INIS)

Ouyang Yinggen

2002-01-01

Although spent nuclear fuels have been reprocessed successfully for many years by the well-know Purex process based on solvent extraction, other reprocessing method which do not depend upon the use of organic solvents and aqueous media appear to have important potential advantage. There are two main non-aqueous methods for the reprocessing of spent fuel: fluoride-volatility process and pyro-electrochemical process. The presence of a poser in the process is that PuF 6 is obviously thermodynamically stable only in the presence of a large excess of fluorine. Pyro-electrochemical process is suited to processing metallic, oxide and carbide fuels. First, the fuel is dissolved in fresh salts, then, electrodes are introduced into the bath, U and Pu are deposited on the cathode, third, separation and refinement U and Pu are deposited on the cathode. There is a couple of contradictions in the process that are not in harmonious proportion in the fields on the nuclear fuel is dissolved the ability in the molten salt and corrosiveness of the molten salt for equipment used in the process

Gas chromatographic analysis of extractive solvent in reprocessing plants

International Nuclear Information System (INIS)

Marlet, B.

1984-01-01

Operation of a reprocessing plant using the Purex process is recalled and analytical controls for optimum performance are specified. The aim of this thesis is the development of analytical methods using gas chromatography required to follow the evolution of the extraction solvent during spent fuel reprocessing. The solvent at different concentrations, is analysed along the reprocessing lines in organic or aqueous phases. Solvent degradation interferes with extraction and decomposition products are analysed. The solvent becomes less and less efficient, also it is distilled and quality is checked. Traces of solvent should also be checked in waste water. Analysis are made as simple as possible to facilitate handling of radioactive samples [fr

Radioactive Semivolatiles in Nuclear Fuel Reprocessing

Energy Technology Data Exchange (ETDEWEB)

Jubin, R. T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Strachan, D. M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Ilas, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Spencer, B. B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Soelberg, N. R. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2014-09-01

In nuclear fuel reprocessing, various radioactive elements enter the gas phase from the unit operations found in the reprocessing facility. In previous reports, the pathways and required removal were discussed for four radionuclides known to be volatile, 14C, 3H, 129I, and 85Kr. Other, less volatile isotopes can also report to the off-gas streams in a reprocessing facility. These were reported to be isotopes of Cs, Cd, Ru, Sb, Tc, and Te. In this report, an effort is made to determine which, if any, of 24 semivolatile radionuclides could be released from a reprocessing plant and, if so, what would be the likely quantities released. As part of this study of semivolatile elements, the amount of each generated during fission is included as part of the assessment for the need to control their emission. Also included in this study is the assessment of the cooling time (time out of reactor) before the fuel is processed. This aspect is important for the short-lived isotopes shown in the list, especially for cooling times approaching 10 y. The approach taken in this study was to determine if semivolatile radionuclides need to be included in a list of gas-phase radionuclides that might need to be removed to meet Environmental Protection Agency (EPA) and Nuclear Regulatory Commission (NRC) regulations. A list of possible elements was developed through a literature search and through knowledge and literature on the chemical processes in typical aqueous processing of nuclear fuels. A long list of possible radionuclides present in irradiated fuel was generated and then trimmed by considering isotope half-life and calculating the dose from each to a maximum exposed individual with the US EPA airborne radiological dispersion and risk assessment code CAP88 (Rosnick 1992) to yield a short list of elements that actually need to be considered for control because they require high decontamination factors to meet a reasonable fraction of the regulated release. Each of these elements is

Advanced fuel cycle on the basis of pyroelectrochemical process for irradiated fuel reprocessing and vibropacking technology

International Nuclear Information System (INIS)

Mayorshin, A.A.; Skiba, O.V.; Tsykanov, V.A.; Golovanov, V.N.; Bychkov, A.V.; Kisly, V.A.; Bobrov, D.A.

2000-01-01

For advanced nuclear fuel cycle in SSC RIAR there is developed the pyroelectrochemical process to reprocess irradiated fuel and produce granulated oxide fuel UO 2 , PuO 2 or (U,Pu)O 2 from chloride melts. The basic technological stage is the extraction of oxides as a crystal product with the methods either of the electrolysis (UO 2 and UO 2 -PuO 2 ) or of the precipitating crystalIization (PuO 2 ). After treating the granulated fuel is ready for direct use to manufacture vibropacking fuel pins. Electrochemical model for (U,Pu)O 2 coprecipitation is described. There are new processes being developed: electroprecipitation of mixed oxides - (U,Np)O 2 , (U,Pu,Np)O 2 , (U,Am)O 2 and (U,Pu,Am)O 2 . Pyroelectrochemical production of mixed actinide oxides is used both for reprocessing spent fuel and for producing actinide fuel. Both the efficiency of pyroelectrochemical methods application for reprocessing nuclear fuel and of vibropac technology for plutonium recovery are estimated. (author)

Why reprocess

International Nuclear Information System (INIS)

Hagen, M.

1977-01-01

The problem of whether to reprocess spent nuclear fuel elements has been studied already in the early days of the commercial utilization of nuclear power and has been answered positively. This also, and in particular, applies to the United States. Under the new American nuclear policy reprocessing is rejected only for reasons of non-proliferation. Although these are valid reasons, the effectiveness of a ban on reprocessing, as fas as the non-profileration of nuclear weapons is concerned, is not accepted worldwide because the necessary knowledge either already exists in many countries or can be obtained. Only if there had been a realistic chance to prevent the proliferation of nuclear weapons, also the other industrialized countries would have seconded the policy of the United States. A country like the Federal Republic of Germany, with a substantial long-term nuclear power program based initially on light water reactors, subsequently on advanced reactor systems, cannot do without a complete nuclear fuel cycle. This reasoning is outlined in the light of economic and radioecological aspects. Extensive experience on a technical scale is available in the reprocessing sector. The technical problems associated with this activity have been solved in principle and have largely been demonstrated to function in practice. (orig.) [de

Safeguarding a future industrial reprocessing plant

International Nuclear Information System (INIS)

1978-11-01

This paper is submitted to Working Group 5, Sub-Group B for information. It is being submitted to Working Group 4 for discussion at their meeting in January 1979 and shows that by a combination of accountancy, surveillance and containment a reliable safeguards system can be designed for the reprocessing of fuels of the BWR and PWR type. Its arguments can, in general terms, be applied to plants for reprocessing LMFBR fuels, with due allowance for future advances which should improve our overall knowledge of the reliability of safeguards systems. In the reprocessing of fast reactor (LMFBR) fuels, as compared with LWR fuels, the main differences are the higher plutonium concentration and lower heavy metal throughput in the early stages of the reprocessing operations. At later stages in the process (after plutonium/uranium separation) the plants could be similar and have similar safeguarding problems. Plants for reprocessing LMFBR on a commercial scale will not be in operation for a number of years. In these plants greater attention may have to be paid to safeguards at the early stages, especially to waste/raffinate streams, than in the PWR/BWR reprocessing plant. The actual balance between containment, surveillance and accountancy adopted will depend on the status of the technology of safeguards and reprocessing. It can be anticipated that improvements to measurement systems will be made which may allow greater reliance on actual measurement. Treatment and recycle of solid wastes will advance and could therefore lead to improvements in accountancy in, for example, the ''head-end''

Remote maintenance in nuclear fuel reprocessing

International Nuclear Information System (INIS)

Herndon, J.N.

1985-01-01

Remote maintenance techniques applied in large-scale nuclear fuel reprocessing plants are reviewed with particular attention to the three major maintenance philosophy groupings: contact, remote crane canyon, and remote/contact. Examples are given, and the relative success of each type is discussed. Probable future directions for large-scale reprocessing plant maintenance are described along with advanced manipulation systems for application in the plants. The remote maintenance development program within the Consolidated Fuel Reprocessing Program at the Oak Ridge National Laboratory is also described. 19 refs., 19 figs

Consolidated fuel reprocessing program. Developments for the future in reprocessing

International Nuclear Information System (INIS)

Burch, W.D.

1982-01-01

The future reprocessing developments focus on three major areas: (1) the retention of gaseous fission products to reduce off-site doses to very low values; (2) the initial steps of breakdown, shearing, and dissolution of breeder fuels; and (3) advanced facility and equipment concepts, which are expected to lead to a reliable, cost-effective, totally remotely operated and maintained plant. Work in the first area - removal of fission gases (the most important of which is 85 Kr) - is largely completed through tracer and bench-scale engineering equipment. Efforts are now mainly devoted to breeder fuels and advanced remote concepts. A facility, the Integrated Equipment Test Facility, which will be used to carry out much of this work, is nearing completion in Oak Ridge. In it a large, simulated, remote reprocessing cell will house a disassembly-shear machine for either breeder or LWR fuels, a rotary continuous dissolver, a solvent extraction cycle utilizing a new generation of centrifugal contactors, and related equipment

Research and development of FBR fuel reprocessing in PNC

International Nuclear Information System (INIS)

Hoshino, T.

1976-05-01

The research program of the PNC for FBR fuel reprocessing in Japan is discussed. The general characteristics of FBR fuel reprocessing are pointed out and a comparison with LWR fuel is made. The R and D program is based on reprocessing using the aqueous Purex process. So far, some preliminary steps of the research program have been carried out, these include solvent extraction test, off-gas treatment test, voloxidation process study, solidification test of high-level liquid waste, and study of the dissolution behaviour of irradiated mixed oxide fuel. By the end of the 1980s, a pilot plant for FBR fuel reprocessing will be completed. For the design of the pilot plant, further research will be carried out in the following fields: head-end techniques; voloxidation process; dissolution and extraction techniques; waste treatment techniques. A time schedule for the different steps of the program is included

Consolidated fuel reprocessing program

International Nuclear Information System (INIS)

Kuban, D.P.; Noakes, M.W.; Bradley, E.C.

1987-01-01

The Advanced Servomanipulator (ASM) System consists of three major components: the ASM slave, the dual arm master controller or master, and the control system. The ASM is a remotely maintainable force-reflecting servomanipulator developed at the Oak Ridge National Laboratory (ORNL) as part of the Consolidated Fuel Reprocessing Program of (CFRP). This new manipulator addresses requirements of advanced nuclear fuel reprocessing with emphasis on force reflection, remote maintainability, and reliability. It uses an all-gear force transmission system. The master arms were designed as a kinematic replica of ASM and use cable force transmission. Special digital control algorithms were developed to improve the system performance. The system is presently operational and undergoing evaluation. Preliminary testing has been completed and is reported. The system is now undergoing commercialization by transferring the technology to the private sector

Statement on the Consolidated Fuel Reprocessing Program

International Nuclear Information System (INIS)

Trauger, D.B.

1984-01-01

Oak Ridge National Laboratory has chosen the following objectives for future reprocessing plant design: reduced radiation exposure to workers; minimal environmental impact; improved plant operation and maintenance; improved accountability; no plutonium diversion; and reduced overall capital and operating cost. These objectives lead to a plant with totally remote operation. The Breeder Reactor Engineering Test (BRET) has been designed to perform a key role in demonstrating advanced reprocessing technology. It has been scheduled to be available to reprocess spent fuel from the Fast Flux Test Facility. The principal features of the Consolidated Fuel Reprocessing Program and of the BRET facility are appropriate for all reactor types

Design of an advanced human-centered supervisory system for a nuclear fuel reprocessing system

International Nuclear Information System (INIS)

Riera, B.; Lambert, M.; Martel, G.

1999-01-01

In the field of highly automated processes, our research concerns supervisory system design adapted to supervisory and default diagnosis by human operators. The interpretation of decisional human behaviour models shows that the tasks of human operators require different information, which has repercussions on the supervisory system design. We propose an advanced human-centred supervisory system (AHCSS) which is more adapted to human-beings, because it integrates new representation of the production system,(such as functional and behavioural aspects) with the use of advanced algorithms of detection and location. Based on an approach using these new concepts, and AHCSS was created for a nuclear fuel reprocessing system. (authors)

Developments of CHON-extractants and proliferation-resistant advanced reprocessing: ARTIST, in Japan

International Nuclear Information System (INIS)

Tachimori, S.; Yaita, T.; Suzuki, S.; Rais, J.

2008-01-01

Development of separation processes for the Partitioning and Transmutation (P and T) has been carried out in Japan for more than 30 years. From the Three Group Partitioning (3GP) and 4GP processes to the newest ARTIST processes, the main research results of Partitioning achieved at JAEA (former JAER1) are reviewed. In this report, the emphasis is put on the research works to develop the advanced reprocessing process: ARTIST, in which novel CHON-extractants were tailored to apply to separation of uranium (DO2EBA), transuranics (TODGA), cesium (DOC(4)C6), and Am-Cm from lanthanides (OcTolPTA). (author)

Present status of foreign reprocessing technology

International Nuclear Information System (INIS)

Otagaki, Takao; Ishikawa, Yasusi; Mori, Jyunichi

2000-03-01

In considering extensively and evaluating advanced nuclear fuel recycle technologies then selecting credible one among those technology options and establishing practicable plan of future fast reactor fuel recycle technology, it is important to investigate foreign reprocessing information extensively and minutely as much as possible then to know trends of reprocessing technology development in the world and present technology level of each country. This report is intending to present information of the status and the technology of operating, constructing and closed foreign reprocessing facilities in the world, including, mixed oxide (MOX) fuel reprocessing technology. The conceptual study of 'Foreign Reprocessing Technology Database' was also performed in order to add or revise the information easily. The eight countries, France, The U.K., Russia, The U.S., Germany, Belgium, India and China, were studied regarding outline of the facilities, operation status, future plan, technical information of process flow sheet, primary components, maintenance system etc, construction and operating costs, accidents or troubles, decommissioning status. (author)

Analysis of nuclear proliferation resistance reprocessing and recycling technologies

International Nuclear Information System (INIS)

Paviet-Hartmann, Patricia; Cerefice, Gary; Stacey, Marcela; Bakhtiar, Steven

2011-01-01

The PUREX process has been progressively and continuously improved during the past three decades, and these improvements account for successful commercialization of reprocessing in a few countries. The renewed interest in nuclear energy and the international growth of nuclear electricity generation do not equate - and should not be equated - with increasing proliferation risks. Indeed, the nuclear renaissance presents a unique opportunity to enhance the culture of non-proliferation. With the recent revival of interest in nuclear technology, technical methods for prevention of nuclear proliferation are being revisited. Robust strategies to develop new advanced separation technologies are emerging worldwide for sustainability and advancement of nuclear energy with enhanced proliferation resistance. On the other hand, at this moment, there are no proliferation resistance advanced technologies. Until now proliferation resistance as it applies to reprocessing has been focused on not separating a pure stream of weapons-usable plutonium. France, as an example, has proposed a variant of the PUREX process, the COEX TM process, which does not result on a pure plutonium product stream. A further step is to implement a process based on group extraction of actinides and fission products associated with a homogeneous recycling strategy (UNEX process in the US, GANEX process in France). Such scheme will most likely not be deployable on an industrial scale before 2030 or so because it requires intensive R and D and robust flowsheets. Finally, future generation recycling schemes will handle the used nuclear fuel in fast neutron reactors. This means that the plutonium throughput of the recycling process may increase. The need is obvious for advanced aqueous recycling technologies that are intrinsically more proliferation resistant than the commercial PUREX process. In this paper, we review the actual PUREX process along with the advanced recycling technologies that will enhance

Analysis of nuclear proliferation resistance reprocessing and recycling technologies

Energy Technology Data Exchange (ETDEWEB)

Patricia Paviet-Hartmann; Gary Cerefice; Marcela Stacey; Steven Bakhtiar

2011-05-01

The PUREX process has been progressively and continuously improved during the past three decades, and these improvements account for successful commercialization of reprocessing in a few countries. The renewed interest in nuclear energy and the international growth of nuclear electricity generation do not equate – and should not be equated -with increasing proliferation risks. Indeed, the nuclear renaissance presents a unique opportunity to enhance the culture of non-proliferation. With the recent revival of interest in nuclear technology, technical methods for prevention of nuclear proliferation are being revisited. Robust strategies to develop new advanced separation technologies are emerging worldwide for sustainability and advancement of nuclear energy with enhanced proliferation resistance. On the other hand, at this moment, there are no proliferation resistance advanced technologies. . Until now proliferation resistance as it applies to reprocessing has been focused on not separating a pure stream of weapons-usable plutonium. France, as an example, has proposed a variant of the PUREX process, the COEX TM process, which does not result on a pure plutonium product stream. A further step is to implement a process based on group extraction of actinides and fission products associated with a homogeneous recycling strategy (UNEX process in the US, GANEX process in France). Such scheme will most likely not be deployable on an industrial scale before 2030 or so because it requires intensive R&D and robust flowsheets. Finally, future generation recycling schemes will handle the used nuclear fuel in fast neutron reactors. This means that the plutonium throughput of the recycling process may increase. The need is obvious for advanced aqueous recycling technologies that are intrinsically more proliferation resistant than the commercial PUREX process. In this paper, we review the actual PUREX process along with the advanced recycling technologies that will enhance

Effect of diluent wash over the removal of aqueous dissolved TBP and DBP in reprocessing

International Nuclear Information System (INIS)

Manjula, R.; Dasi, Mahesh; Mohandas, Jaya; Vijaya Kumar, N.; Kumar, T.

2015-01-01

In reprocessing of nuclear spent fuels by PUREX process Tri-n-Butyl phosphate diluted with n-Dodecane (nDD) is used as solvent. This solvent undergoes degradation due to radiation yielding degradation products, mainly Di-n-butyl phosphate (HDBP). During extraction steps some amount of these organic gets dissolved in aqueous phase owing to its mutual solubility. Removal of dissolved organic from aqueous streams before evaporation is essential to prevent red oil related disasters. Diluent wash technique employing nDD as diluent is one of the commonly used method for the same. During the continuous operation of this process, the diluent will get loaded with dissolved organic and subsequently the performance of diluent will not remain same as pure diluent. While some reports are available in literature for the efficiency of removal of TBP by nDD, so far no work has been reported for the removal of DBP. The scope of the present work is to ascertain the efficiency of diluent wash technique on the removal of dissolved TBP as well as DBP. The results obtained indicate that the removal of dissolved TBP by nDD decreases with increase in percentage of TBP in nDD. In the case of DBP it is just reverse and the removal becomes more effective when the TBP percentage in the diluent increases. A/O ratio of 6:1 is found to be more suitable. As the DBP is getting extracted very effectively into nDD containing TBP, diluent wash solution should be treated as spent organic and managed accordingly for further utilization

An improved sampling system installed for reprocessing

International Nuclear Information System (INIS)

Finsterwalder, L.; Zeh, H.

1979-03-01

Sampling devices are needed for taking representative samples from individual process containers during the reprocessing of irradiated fuel. The aqueous process stream in a reprocessing plant frequently contains, in addition to the dissolved radioactive materials, more or less small quantities of solid matter fraction of fuel material still remaining undissolved, insoluble fission-, corrosion-, or degradation products as well, in exceptional cases, ion exchange resin or silica gel. The solid matter is deposited partly on the upper surfaces of the sampling system and the radiation due to this makes maintenance and repair of the sampler more difficult. The purpose of the development work was to reduce the chance of accident and the maintenance costs and to lower the radiation exposure of the personnel. A new sampling system was developed and is described. (author)

Compilation of papers presented to the KTG conference on 'Advanced LWR fuel elements: Design, performance and reprocessing', 17-18 November 1988, Karlsruhe Nuclear Research Center

International Nuclear Information System (INIS)

Bahm, W.

1989-05-01

The two expert groups of the Nuclear Society (KTG), 'chemistry and waste disposal' and 'fuel elements' discussed interdisciplinary problems concerning the development and reprocessing of advanced fuel elements. The 10 lectures deal with waste disposal, mechanical layout, operating behaviour, operating experiences and new developments of fuel elements for water moderated reactors as well as operational experiences of the Karlsruhe reprocessing plant (WAK) with reprocessing of high burnup LWR and MOX fuel elements, the distribution of fission products, the condition of the fission products during dissolution and with the effects of the higher burnup of fuel elements on the PUREX process. (DG) [de

Italian experience with pilot reprocessing plants

International Nuclear Information System (INIS)

Cao, S.; Dworschak, H.; Rolandi, G.; Simonetta, R.

1977-01-01

Problems and difficulties recently experienced in the reprocessing technology of high burnup power reactor fuel elements have shown the importance of pilot plant experiments to optimize the separation processes and to test advanced equipment on a representative scale. The CNEN Eurex plant, in Saluggia (Vercelli), with a 50 kg/d thruput, in operation since '71, has completed several reprocessing campaigns on MTR type fuel elements. Two different chemical flowsheets based respectively on TBP and tertiary amines were thoroughly tested and compared: a concise comparative evaluation of the results obtained with the two schemes is given. Extensive modifications have then been introduced (namely a new headend cell equipped with a shear) to make the plant suitable to reprocess power reactor fuels. The experimental program of the plant includes a joint CNEN-AECL reprocessing experiment on CANDU (Pickering) type fuel elements to demonstrate a two cycle, amine based recovery of the plutonium. Later, a stock of high burnup fuel elements from the PWR Trino power station will be reprocessed to recover Pu and U with a Purex type flowsheet. ITREC, the second CNEN experimental reprocessing plant located at Trisaia Nuclear Center (Matera), started active operation two years ago. In the first campaign Th-U mixed oxide fuel elements irradiated in the Elk River reactor were processed. Results of this experiment are reported. ITREC special design features confer a high degree of versability to the plant allowing for substantial equipment modification under remote control conditions. For this reason the plant will be principally devoted in the near future to advanced equipment testing. Along this line high speed centrifugal contactor of a new type developed in Poland will be tested in the plant in the frame of a joint experiment between CNEN and the Polish AEC. Later on the plant program will include experimental campaign on fast reactor fuels; a detailed study on this program is in

Management of reprocessed uranium. Current status and future prospects

International Nuclear Information System (INIS)

2007-02-01

There is worldwide interest in developing advanced and innovative technologies for nuclear fuel cycles, minimizing waste and environmental impacts. As of the beginning of 2003, about 171000 tonnes heavy metal spent nuclear fuel is in storage, while smaller amounts have been reprocessed. In several countries, including France, India, Japan and the Russian Federation, spent fuel has been viewed as a national energy resource. Some countries hold reprocessed uranium as the result of their commercial reprocessing service contracts for reprocessing the spent fuel of others. Reprocessed uranium has a potential value for recycling either directly or after appropriate treatment. This report analyses the existing options, approaches and developments in the management of reprocessed uranium. It includes the technical issues involved in managing reprocessed uranium which are RepU arisings, storage, chemical conversion, re-enrichment, fuel fabrication, transport, reactor irradiation, subsequent reprocessing and disposal options, as well as assessment of holistic environmental impacts. The objective of this document is to overview the information on the current status and future trends in the management of RepU and to identify major issues to be considered for future projects

Containment/surveillance concepts for international safeguards in reprocessing plants

International Nuclear Information System (INIS)

Bleck, M.E.; Cameron, C.P.; Camp, A.L.

1980-01-01

This paper examines the potential role of advanced containment/surveillance instrumentation systems for international safeguards in reprocessing plants. Several conceptual systems for the surveillance of containment boundary penetrations in a reference reprocessing plant are described and evaluated. The results of the evaluation aid in understanding the potential capabilities and limitations of containment/surveillance as an international safeguards concept in this type of facility

Advanced Aqueous Phase Catalyst Development using Combinatorial Methods, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Combinatorial methods are proposed to develop advanced Aqueous Oxidation Catalysts (AOCs) with the capability to mineralize organic contaminants present in effluents...

Spent Nuclear Fuel Reprocessing Flowsheet. A Report by the WPFC Expert Group on Chemical Partitioning of the NEA Nuclear Science Committee

International Nuclear Information System (INIS)

Na, Chan; Yamagishi, Isao; Choi, Yong-Joon; Glatz, Jean-Paul; Hyland, Bronwyn; Uhlir, Jan; Baron, Pascal; Warin, Dominique; De Angelis, Giorgio; Luce, Alfredo; INOUE, Tadashi; Morita, Yasuji; Minato, Kazuo; Lee, Han Soo; Ignatiev, Victor V.; Kormilitsyn, Mikhail V.; Caravaca, Concepcion; Lewin, Robert G.; Taylor, Robin J.; Collins, Emory D.; Laidler, James J.

2012-06-01

Under the auspices of the NEA Nuclear Science Committee (NSC), the Working Party on Scientific Issues of the Fuel Cycle (WPFC) has been established to co-ordinate scientific activities regarding various existing and advanced nuclear fuel cycles, including advanced reactor systems, associated chemistry and flowsheets, development and performance of fuel and materials, and accelerators and spallation targets. The WPFC has different expert groups to cover a wide range of scientific fields in the nuclear fuel cycle. The Expert Group on Chemical Partitioning was created in 2001 to (1) perform a thorough technical assessment of separations processes in application to a broad set of partitioning and transmutation (P and T) operating scenarios and (2) identify important research, development and demonstration necessary to bring preferred technologies to a deployable stage and (3) recommend collaborative international efforts to further technological development. This report aims to collect spent nuclear fuel reprocessing flowsheet of various processes developed by member states: aqueous, pyro and fluoride volatility. Contents: 1 - Hydrometallurgy process: Standard PUREX, Extended PUREX, UREX+3, Grind/Leach; 2 - Pyrometallurgy process: pyro-process (CRIEPI - Japan), 4-group partitioning process, pyro-process (KAERI - Korea), Direct electrochemical processing of metallic fuel, PyroGreen (reduce radiotoxicity to the level of low and intermediate level waste - LILW); 3 - Fluoride volatility process: Fluoride volatility process, Uranium and protactinium removal from fuel salt compositions by fluorine bubbling, Flowsheet studies on non-aqueous reprocessing of LWR/FBR spent nuclear fuel; Appendix A: Flowsheet studies of RIAR (Russian Federation), List of contributors, Members of the expert group

Why reprocess

International Nuclear Information System (INIS)

Greenwood, T.

1977-01-01

Prospective costs of reprocessing, waste management, and mixed oxide fuel fabrication have risen so much that the costs of U/P recycle and of spent fuel storage are nearly equal. This paper reviews the current state of the reprocessing industry, with a list of facilities all over the world, and examines the incentives and disincentives other than short-term economics that will affect the decision of states to acquire their own reprocessing facilities. Finally, it examines the possibility of avoiding a widespread commercial reprocessing industry

On-Line Monitoring for Control and Safeguarding of Radiochemical Streams at Spent Fuel Reprocessing Plant

International Nuclear Information System (INIS)

Bryan, Samuel A.; Levitskaia, Tatiana G.; Billing, Justin M.; Casella, Amanda J.; Johnsen, Amanda M.; Peterson, James M.

2009-01-01

Advanced techniques enabling enhanced safeguarding of the spent fuel reprocessing plants are urgently needed. Our approach is based on prerequisite that real time monitoring of the solvent extraction flowsheets provides unique capability to quickly detect unwanted manipulations with fissile isotopes present in the radiochemical streams during reprocessing activities. The methods used to monitor these processes must be robust and must be able to withstand harsh radiation and chemical environments. A new on-line monitoring system satisfying these requirements and featuring Raman spectroscopy combined with a Coriolis and conductivity probes, has been recently developed by our research team. It provides immediate chemical data and flow parameters of high-level radioactive waste streams with high brine content generated during retrieval activities from Hanford nuclear waste storage tanks. The nature of the radiochemical streams at the spent fuel reprocessing plant calls for additional spectroscopic information, which can be gained by the utilization of UV-vis-NIR capabilities. Raman and UV-vis-NIR spectroscopies are analytical techniques that have extensively been extensively applied for measuring the various organic and inorganic compounds including actinides. The corresponding spectrometers used under the laboratory conditions are easily convertible to the process-friendly configurations allowing remote measurements under the flow conditions. A fiber optic Raman probe allows monitoring of the high concentration species encountered in both aqueous and organic phases within the UREX suite of flowsheets, including metal oxide ions, such as uranyl, components of the organic solvent, inorganic oxo-anions, and water. The actinides and lanthanides are monitored remotely by UV-vis-NIR spectroscopy in aqueous and organic phases. In this report, we will present our recent results on spectroscopic measurements of simulant flowsheet solutions and commercial fuels available at

Tritium control in reprocessing plants

International Nuclear Information System (INIS)

Goumondy, J.P.; Miquel, P.

1977-01-01

There is a danger that the T which is formed in water reactors will prove detrimental to the environment over the next few years, and studies have been undertaken to develop techniques to contain and process it where possible. In order to retain T, which is present largely in the fuel and on the possible to adapt for use in the conventional design of reprocessing plant. In this process T is maintained in the form of an aqueous solution in the high-active area of the plant. Control is achieved by restricting as far as possible the ingress of non-tritiated water into this area, and by setting up a tritiated water barrier at the first U and Pu extraction stage, stripping the tritium-containing solvent at that point with ordinary water. In this way the T can be extracted in a small volume of water with a view to intermediate storage, disposal at sea additional processing to remove the T from the water. Experiments carried out so far have demonstrated the effectiveness of the T barrier and have shown what equipment would be required for the application of the process in new reprocessing plants. (orig.) [de

Consolidated fuel reprocessing. Program progress report, April 1-June 30, 1980

Energy Technology Data Exchange (ETDEWEB)

1980-09-01

This progress report is compiled from major contributions from three programs: (1) the Advanced Fuel Recycle Program at ORNL; (2) the Converter Fuel Reprocessing Program at Savannah River Laboratory; and (3) the reprocessing components of the HTGR Fuel Recycle Program, primarily at General Atomic and ORNL. The coverage is generally overview in nature; experimental details and data are limited.

The French R and D programme for fast reactor fuel reprocessing

International Nuclear Information System (INIS)

Auchapt, P.; Bourgeois, M.; Calame-Longjean, A.; Miquel, P.; Sauteron, J.

1979-01-01

The process employed is the Purex process adapted to the specific case of fast breeder reactor fuels. The results achieved have demonstrated that the aqueous method can be applied to these fuels: nearly ten years of operation in the ATl workshop which reprocesses RAPSODIE fuels, and the good results obtained at the Marcoule pilot facility on large batches of fuel attest to this achievement. The CEA effort continues principally on extrapolation to industrial scale, thanks mainly to experiments conducted on industrial prototypes and to the launching of the TOR project, which will, as of 1984, allow reprocessing of FBR fuels on a significant scale, and which will provide extensive additional resources for R and D activities

Optimizing near real time accountability for reprocessing

International Nuclear Information System (INIS)

Cipiti, Benjamin B.

2010-01-01

Near Real Time Accountability (NRTA) of actinides at high precision in reprocessing plants has been a long sought-after goal in the safeguards community. Achieving this goal is hampered by the difficulty of making precision measurements in the reprocessing environment, equipment cost, and impact to plant operations. Thus the design of future reprocessing plants requires an optimization of different approaches. The Separations and Safeguards Performance Model, developed at Sandia National Laboratories, was used to evaluate a number of NRTA strategies in a UREX+ reprocessing plant. Strategies examined include the incorporation of additional actinide measurements of internal plant vessels, more use of process monitoring data, and the option of periodic draining of inventory to key tanks. Preliminary results show that the addition of measurement technologies can increase the overall measurement uncertainty due to additional error propagation, so care must be taken when designing an advanced system. Initial results also show that relying on a combination of different NRTA techniques will likely be the best option. The model provides a platform for integrating all the data. The modeling results for the different NRTA options under various material loss conditions will be presented.

Remote maintenance lessons learned on prototypical reprocessing equipment

International Nuclear Information System (INIS)

Kring, C.T.; Schrock, S.L.

1990-01-01

A major objective of the Consolidated Fuel Reprocessing Program at the Oak Ridge National Laboratory is to develop and demonstrate the technology required to reprocess spent nuclear fuel. The Fuel Recycle Division, over the past 16 years, has undertaken this objective by designing and testing prototypical hardware representing essentially every major equipment item currently included in most fuel reprocessing plant conceptual designs. These designs are based on total remote maintenance to increase plant availability and reduce radiation exposure to plant operators. The designs include modular equipment to facilitate maintainability and the remote manipulation necessary to accomplish maintenance tasks. Prototypic equipment has been installed and tested in a cold mock-up of a reprocessing hot cell, called the remote operations and maintenance demonstration facility. The applied maintenance concept utilizes the dexterity and mobility of bridge-mounted, force-reflecting servomanipulators. Prototypic processing equipment includes a remote disassembly system, a remote shear system, a rotary dissolver, a remote automated sampler system, removable equipment racks to support chemical process equipment items, and the advanced servomanipulators. Each of these systems and a brief description of functions are discussed

Remote maintenance ''lessons learned'' on prototypical reprocessing equipment

International Nuclear Information System (INIS)

Kring, C.T.; Schrock, S.L.

1990-01-01

Hardware representative of essentially every major equipment item necessary for reprocessing breeder reactor nuclear fuel has been installed and tested for remote maintainability. This testing took place in a cold mock-up of a remotely maintained hot cell operated by the Consolidated Fuel Reprocessing Program (CFRP) within the Fuel Recycle Division at Oak Ridge National Laboratory (ORNL). The reprocessing equipment tested included a Disassembly System, a Shear System, a Dissolver System, an Automated Sampler System, removable Equipment Racks on which various chemical process equipment items were mounted, and an advanced servomanipulator (ASM). These equipment items were disassembled and reassembled remotely by using the remote handling systems that are available within the cold mock-up area. This paper summarizes the ''lessons learned'' as a result of the numerous maintenance activities associated with each of these equipment items. 4 refs., 3 figs., 1 tab

Flowsheet development for HTGR fuel reprocessing

International Nuclear Information System (INIS)

Baxter, B.; Benedict, G.E.; Zimmerman, R.D.

1976-01-01

Development studies to date indicate that the HTGR fuel blocks can be effectively crushed with two stages of eccentric jaw crushing, followed by a double-roll crusher, a screener and an eccentrically mounted single-roll crusher for oversize particles. Burner development results indicate successful long-term operation of both the primary and secondary fluidized-bed combustion systems can be performed with the equipment developed in this program. Aqueous separation development activities have centered on adapting known Acid-Thorex processing technology to the HTGR reprocessing task. Significant progress has been made on dissolution of burner ash, solvent extraction feed preparation, slurry transfer, solids drying and solvent extraction equipment and flowsheet requirements

Advanced remote handling for future applications: The advanced integrated maintenance system

International Nuclear Information System (INIS)

Herndon, J.N.; Kring, C.T.; Rowe, J.C.

1986-01-01

The Consolidated Fuel Reprocessing Program at Oak Ridge National Laboratory has been developing advanced techniques for remote maintenance of future US fuel reprocessing plants. The developed technology has a wide spectrum of application for other hazardous environments. These efforts are based on the application of teleoperated, force-reflecting servomanipulators for dexterous remote handling with television viewing for large-volume hazardous applications. These developments fully address the nonrepetitive nature of remote maintenance in the unstructured environments encountered in fuel reprocessing. This paper covers the primary emphasis in the present program; the design, fabrication, installation, and operation of a prototype remote handling system for reprocessing applications, the Advanced Integrated Maintenance System

Advanced Aqueous Separation Systems for Actinide Partitioning

Energy Technology Data Exchange (ETDEWEB)

Nash, Ken [Washington State Univ., Pullman, WA (United States); Martin, Leigh [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lumetta, Gregg [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2015-04-02

One of the most challenging aspects of advanced processing of used nuclear fuel is the separation of transplutonium actinides from fission product lanthanides. This separation is essential if actinide transmutation options are to be pursued in advanced fuel cycles, as lanthanides compete with actinides for neutrons in both thermal and fast reactors, thus limiting efficiency. The separation is difficult because the chemistry of Am3+ and Cm3+ is nearly identical to that of the trivalent lanthanides (Ln3+). The prior literature teaches that two approaches offer the greatest probability of devising a successful group separation process based on aqueous processes: 1) the application of complexing agents containing ligand donor atoms that are softer than oxygen (N, S, Cl-) or 2) changing the oxidation state of Am to the IV, V, or VI state to increase the essential differences between Am and lanthanide chemistry (an approach utilized in the PUREX process to selectively remove Pu4+ and UO22+ from fission products). The latter approach offers the additional benefit of enabling a separation of Am from Cm, as Cm(III) is resistant to oxidation and so can easily be made to follow the lanthanides. The fundamental limitations of these approaches are that 1) the soft(er) donor atoms that interact more strongly with actinide cations than lanthanides form substantially weaker bonds than oxygen atoms, thus necessitating modification of extraction conditions for adequate phase transfer efficiency, 2) soft donor reagents have been seen to suffer slow phase transfer kinetics and hydro-/radiolytic stability limitations and 3) the upper oxidation states of Am are all moderately strong oxidants, hence of only transient stability in media representative of conventional aqueous separations systems. There are examples in the literature of both approaches having been described. However, it is not clear at present that any extant process is sufficiently robust for application at the scale

HTGR fuel reprocessing technology

International Nuclear Information System (INIS)

Brooks, L.H.; Heath, C.A.; Shefcik, J.J.

1976-01-01

The following aspects of HTGR reprocessing technology are discussed: characteristics of HTGR fuels, criteria for a fuel reprocessing flowsheet; selection of a reference reprocessing flowsheet, and waste treatment

Separation of tritium from reprocessing effluents

International Nuclear Information System (INIS)

Bruggeman, A.; Doyen, W.; Harnie, R.; Leysen, R.; Meynendonckx, L.; Monsecour, M.; Goossens, W.R.A.; Baetsle, L.H.

1980-01-01

For several years tritium retention has been studied at the Belgian Nuclear Research Centre, SCK/CEN; initially attention was focused on the removal of tritium from gaseous reprocessing effluents. If tritium can be released from the spent fuel into the gaseous phase before any aqueous operation, adsorption on molecular sieves after some isotopic dilution with hydrogen and after complete conversion to (tritiated) water is the most practical collection method. A once-through 15 m 3 .h -1 oxidation-adsorption unit with a closed regeneration system and with a decontamination factor of 1000 at total (tritiated) hydrogen and water inlet concentrations down to 1000 vpm (parts per million by volume) has been constructed and tested at SCK/CEN and it is described in the text. If no special head-end treatment is used an appropriate liquid management inside the reprocessing plant restricts the volume of tritiated aqueous effluents to about 3 m 3 per tonne of LWR fuel processed. However, for further reduction an isotope separation process becomes necessary. SCK/CEN is developing the ELEX process, which is a combination of water ELectrolysis and tritium EXchange between hydrogen and water, the exchange being promoted by a hydrophobic catalyst. For electrolysis under normal conditions an elementary tritium separation factor of 11.6 with a standard deviation of 6% was obtained. As concerns the exchange step a hydrophobic catalyst has been developed which yields for the flow rates used at atmospheric pressure and at 20 0 C an overall exchange rate constant of 9 mol.s -1 .m -3 in a countercurrent trickle-bed reactor. At present an integrated bench scale de-tritiation unit is being built for further tests and for a dynamic demonstration of the ELEX process

Novel finishing concepts within BNFL'S advanced reprocessing programme

Energy Technology Data Exchange (ETDEWEB)

Hobbs, J.W.; Booth, R.; Lawson, S.; Parkes, P. [BNFL British Nuclear Fuels, Sellafield, Seascale, Cumbria, Research and Technology (United Kingdom)

2000-07-01

New methods of converting actinide nitrate solutions to oxide and fabricating the products from the reprocessing of high burn up and MOX fuels are necessary for the next generation of fuel cycle facilities in order to meet dose criteria and cost reduction targets. Options to support this include never fully separating the plutonium from the uranium and reducing decontamination factors. The product stream from such a reprocessing plant will require a finishing route capable of significant levels of automation and dose minimization. Casting of molten uranyl nitrate into pellets followed by de-nitration under vacuum has been investigated as a novel way of manufacturing oxide fuel pellets. Pellets were successfully cast over a range of temperatures and de-nitrated. Incorporation of uranium oxide into the melt was investigated to increase the density of the cast pellet. It has been demonstrated that it is possible to produce extrudates from powder and molten magnesium nitrate mixtures. Results of a preliminary study of the flow behaviour during extrusion of magnesium nitrate simulant loaded with alumina powder are also discussed. (authors)

Review of Design Data for Safety Assessment of Tokai Reprocessing Plant. Control of hydrogen gas produced by radiolysis of reprocessing solutions at Tokai Reprocessing Plant

International Nuclear Information System (INIS)

Omori, E.; Surugaya, N.; Takaya, A.; Nakamura, H.; Maki, A.; Yamanouchi, T.

1999-10-01

Radioactive materials in aqueous solution at a nuclear fuel reprocessing plant causes radiolytic generation of several gases including hydrogen. Hydrogen accumulating in equipment can be an explosion hazard. In such plants, though the consideration in the design has been fundamentally made in order to remove the ignition source from the equipment, the hydrogen concentration in the equipment should not exceed the explosion threshold. It is, therefore, desired to keep the hydrogen concentration lower than the explosion threshold by dilution with the air introduced into equipment, from the viewpoint which previously prevents the explosion. This report describes the calculation of hydrogen generation, evaluation of hydrogen concentration under abnormal operation and consideration of possible improvement at Tokai Reprocessing Plant. The amount of hydrogen generation was calculated for each equipment from available data on radiolysis induced by radioactive materials. Taking into consideration for abnormal condition that is single failure of air supply and loss of power supply, the investigation was made on the method for controlling so that the hydrogen concentration may not exceed the explosion threshold. Possible means which can control the concentration of hydrogen gas under the explosion threshold have been also investigated. As the result, it was found that hydrogen concentration of most equipment was kept under the explosion threshold. It was also shown that improvement of the facility was necessary on the equipment in which the concentration of the hydrogen may exceed the explosion threshold. Proposals based on the above results are also given in this report. The above content has been described in 'Examination of the hydrogen produced by the radiolysis' which is a part of 'Reviews of Design Data for Safety Assessment of Tokai Reprocessing Plant' (JNC TN8410 99-002) published in February 1999. This report incorporates the detail evaluation so that operation

Iodine Pathways and Off-Gas Stream Characteristics for Aqueous Reprocessing Plants – A Literature Survey and Assessment

Energy Technology Data Exchange (ETDEWEB)

R. T. Jubin; D. M. Strachan; N. R. Soelberg

2013-09-01

Used nuclear fuel is currently being reprocessed in only a few countries, notably France, England, Japan, and Russia. The need to control emissions of the gaseous radionuclides to the air during nuclear fuel reprocessing has already been reported for the entire plant. But since the gaseous radionuclides can partition to various different reprocessing off-gas streams, for example, from the head end, dissolver, vessel, cell, and melter, an understanding of each of these streams is critical. These off-gas streams have different flow rates and compositions and could have different gaseous radionuclide control requirements, depending on how the gaseous radionuclides partition. This report reviews the available literature to summarize specific engineering data on the flow rates, forms of the volatile radionuclides in off-gas streams, distributions of these radionuclides in these streams, and temperatures of these streams. This document contains an extensive bibliography of the information contained in the open literature.

Reprocessing of AHWR spent-fuel: Challenges and strategies

International Nuclear Information System (INIS)

Kant, S.

2005-01-01

Reprocessing of advanced heavy water reactor (AHWR) spent-fuel involves separation of Th, 233 U and Pu, from the fission products and from one another. A proper combination of Purex and Thorex processes is required. The technology development for a reprocessing facility is extremely complex owing to high fissile content, high levels of irradiation, presence high of levels of 232 U, difficulty in thoria dissolution, presence of thorium as the major constituent, problems due to third phase formation with Th, etc. It demands for development of suitable dissolution, solvent extraction, criticality control, U-Pu partitioning, and other equipments and/or techniques. Process modelling, simulation and optimisation are crucial in predicting behaviour of equipments/cycles, and in arriving at safe and optimum flowsheet. A significant success in this field has been achieved. This paper describes the reprocessing aspects pertaining to AHWR spent-fuel, indicating the major technological challenges, strategies to be followed and development requirements. A schematic flowsheet is proposed for Th- 233 U-Pu separation. (author)

The Nuclear Energy Advanced Modeling and Simulation Safeguards and Separations Reprocessing Plant Toolkit

Energy Technology Data Exchange (ETDEWEB)

McCaskey, Alex [ORNL; Billings, Jay Jay [ORNL; de Almeida, Valmor F [ORNL

2011-08-01

This report details the progress made in the development of the Reprocessing Plant Toolkit (RPTk) for the DOE Nuclear Energy Advanced Modeling and Simulation (NEAMS) program. RPTk is an ongoing development effort intended to provide users with an extensible, integrated, and scalable software framework for the modeling and simulation of spent nuclear fuel reprocessing plants by enabling the insertion and coupling of user-developed physicochemical modules of variable fidelity. The NEAMS Safeguards and Separations IPSC (SafeSeps) and the Enabling Computational Technologies (ECT) supporting program element have partnered to release an initial version of the RPTk with a focus on software usability and utility. RPTk implements a data flow architecture that is the source of the system's extensibility and scalability. Data flows through physicochemical modules sequentially, with each module importing data, evolving it, and exporting the updated data to the next downstream module. This is accomplished through various architectural abstractions designed to give RPTk true plug-and-play capabilities. A simple application of this architecture, as well as RPTk data flow and evolution, is demonstrated in Section 6 with an application consisting of two coupled physicochemical modules. The remaining sections describe this ongoing work in full, from system vision and design inception to full implementation. Section 3 describes the relevant software development processes used by the RPTk development team. These processes allow the team to manage system complexity and ensure stakeholder satisfaction. This section also details the work done on the RPTk ``black box'' and ``white box'' models, with a special focus on the separation of concerns between the RPTk user interface and application runtime. Section 4 and 5 discuss that application runtime component in more detail, and describe the dependencies, behavior, and rigorous testing of its constituent components.

Advance purex process for the new reprocessing plants in France and in Japan

International Nuclear Information System (INIS)

Viala, M.

1991-01-01

In the early Eighties, Japanese utilities formed the Japan Nuclear Fuel Service Co (JNFS), which is in charge of the construction and the operation of the first commercial reprocessing plant in Japan to be erected in Rokkasho Village, Aomori Prefecture. Following a thorough worldwide examination of available processes and technologies, JNFS selected the French technology developed for UP3 and UP2 800 for the plants' main facilities. For these three new plants, the 40-year old PUREX process which is used worldwide for spent fuel reprocessing, has been significantly improved. This paper describes some of the innovative features of the selected processes

Materials management in an internationally safeguarded fuels reprocessing plant

International Nuclear Information System (INIS)

Hakkila, E.A.; Cobb, D.D.; Dayem, H.A.; Dietz, R.J.; Kern, E.A.; Markin, J.T.; Shipley, J.P.; Barnes, J.W.; Scheinman, L.

1980-04-01

The first volume of this report summarizes the results and conclusions for this study of conventional and advanced nuclear materials accounting systems applicable for both large (1500 MTHM/y) and small (210 MTHM/y) spent-fuel reprocessing facilities subject to international verification

Materials management in an internationally safeguarded fuels reprocessing plant

International Nuclear Information System (INIS)

Hakkila, E.A.; Baker, A.L.; Cobb, D.D.

1980-04-01

The following appendices are included: aqueous reprocessing and conversion technology, reference facilities, process design and operating features relevant to materials accounting, operator's safeguards system structure, design principles of dynamic materials accounting systems, modeling and simulation approach, optimization of measurement control, aspects of international verification problem, security and reliability of materials measurement and accounting system, estimation of in-process inventory in solvent-extraction contactors, conventional measurement techniques, near-real-time measurement techniques, isotopic correlation techniques, instrumentation available to IAEA inspectors, and integration of materials accounting and containment and surveillance

Materials management in an internationally safeguarded fuels reprocessing plant

Energy Technology Data Exchange (ETDEWEB)

Hakkila, E.A.; Baker, A.L.; Cobb, D.D.

1980-04-01

The following appendices are included: aqueous reprocessing and conversion technology, reference facilities, process design and operating features relevant to materials accounting, operator's safeguards system structure, design principles of dynamic materials accounting systems, modeling and simulation approach, optimization of measurement control, aspects of international verification problem, security and reliability of materials measurement and accounting system, estimation of in-process inventory in solvent-extraction contactors, conventional measurement techniques, near-real-time measurement techniques, isotopic correlation techniques, instrumentation available to IAEA inspectors, and integration of materials accounting and containment and surveillance. (DLC)

Milestone Report - M4FT-17OR030107025 - Design of a tritium and iodine removal system for use with advanced TPOG

Energy Technology Data Exchange (ETDEWEB)

Spencer, Barry B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bruffey, Stephanie H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jordan, Jacob A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2017-03-01

US regulations will require the removal of iodine and tritium, along with other volatile and semi-volatile radionuclides, from the off-gas streams of nuclear fuel reprocessing plants. Advanced tritium pretreatment (TPT) is an additional head-end operation that could be incorporated within nuclear fuel reprocessing plants. It utilizes nitrogen dioxide (NOR2R) as an oxidant to convert UOR2R to UR3ROR8R prior to traditional aqueous dissolution. Advanced TPT can result in the quantitative volatilization of both tritium and iodine. Up-front removal of iodine is of significant advantage because otherwise it distributes to several unit operations and the associated off-gas streams. The off-gas streams will then require treatment to comply with US regulations. Advanced TPT is currently under development at Oak Ridge National Laboratory, and a kilogram-scale hot cell demonstration with used nuclear fuel (UNF) is planned for fiscal year (FY) 2018.

Nitrogen oxide closed system in the future reprocessing process

International Nuclear Information System (INIS)

Tanaka, S.; Takaoku, Y.; Sumida, Y.; Moriya, T.; Araya, S.

2006-01-01

Full text: Full text: The aqueous reprocessing process for the future type reactor like as Fast Breeder Reactor(FBR) is being developed in many institutes, while the existence of sodium nitrate as the secondary waste is considered as problematic due to an enormous quantity of sodium nitrate generated and the difficulty in its handling for disposal. As a means for solving the problem, a complete recycle of nitric acid and salt free system is considered, but it become a constraint in the process constitution. We have devised the alternative system, which shall approve the generation of sodium nitrate, and make the choice of a wide reprocessing process. Under this system nitric acid within sodium nitrate shall be reduced and made into harmless gas, while at the same time, the remaining sodium compound shall be re-used in a suitable form. In order to prevent the accumulation of radioactivity by re-use, we propose to use a part of remaining sodium compound as substitution of the fresh sodium within the glass material used for the vitrified solid waste. As a result of using this system, the waste originating from sodium nitrate can be reduced to 'zero'. We have studied a typical application case for the future reprocessing process, and got a good result at an economical point of view

Technology development of fast reactor fuel reprocessing technology in India

International Nuclear Information System (INIS)

Natarajan, R.; Raj, Baldev

2009-01-01

India is committed to the large scale induction of fast breeder reactors beginning with the construction of 500 MWe Prototype Fast Breeder Reactor, PFBR. Closed fuel cycle is a prerequisite for the success of the fast reactors to reduce the external dependence of the fuel. In the Indian context, spent fuel reprocessing, with as low as possible out of pile fissile inventory, is another important requirement for increasing the share in power generation through nuclear route as early as possible. The development of this complex technology is being carried out in four phases, the first phase being the developmental phase, in which major R and D issues are addressed, while the second phase is the design, construction and operation of a pilot plant, called CORAL (COmpact Reprocessing facility for Advanced fuels in Lead shielded cell. The third phase is the construction and operation of Demonstration of Fast Reactor Fuel Reprocessing Plant (DFRP) which will provide experience in fast reactor fuel reprocessing with high availability factors and plant throughput. The design, construction and operation of the commercial plant (FRP) for reprocessing of PFBR fuel is the fourth phase, which will provide the requisite confidence for the large scale induction of fast reactors

Reprocessing decision

International Nuclear Information System (INIS)

Heising, C.D.

1978-01-01

The United States must decide whether to permit, delay, or prohibit the reprocessing and recycling of nuclear spent fuel. To permit reprocessing would allow recycle as early as 1985; to delay the decision for a later administration to deal with means spent fuel would mount up at nuclear reactor sites; to prohibit would eliminate recycling and mandate permanent storage. Bayesian decision analysis was used to examine reprocessing costs associated with risks and economic benefits. Three distinct categories of risk that are important in the nuclear fuel cycle are discussed. These are: health, environment, and safety risks; nuclear theft and sabotage; and nuclear weapons proliferation risks. Results are discussed from comparing nine routes to weapons-usuable mterial available to nonweapons states that desire a nuclear capability. These are: production reactor and military reporcessor; research reacotr and military reprocessor; power plant plus military reprocessor or commercial reprocessor; enrichment (centrifuge, gaseous diffusion, electromagnetic separation, or aerodynamic jet cascade); and accelerator. It was found that the commercial power reactor-commercial reprocessor route is comparatively unattractive to a nonweapons state. In summary, allowing nuclear fuel reprocessing to go forward in the United States can be expected to increase the costs to society by a maximum $360 million a year. This is approximately one-seventh of the expected benefit (reduced electricity bills) to be dderived by society from closing the fuel cycle. It appears that the permitting reprocessing now is logically preferable to delaying or prohibiting the technology, the author concludes

Reprocessing

International Nuclear Information System (INIS)

Couture, J.; Rougeau, J.-P.

1987-01-01

The course of development of a comprehensive nuclear power industry has its own pace which implies the timely progressive and consistent mastery of each industrial step. In the nuclear fuel it is not surprising that the back-end services have lastly reached the industrial stage. In France, we have now fully completed the industrial demonstration of the closed fuel cycle. Our experience covers all necessary steps : transportation of spent fuel, storage, reprocessing, waste conditioning, recovered uranium recycling, plutonium recycling in thermal MOX fuels, plutonium-based fuel for FBR. While FBR development is a long term target, recycling of fissile materials in present LWR reactors appears to be a source of noticable savings. In the meantime rational management of waste material is the key for increased safety and better environment protection. Reprocessing activity is certainly the major achievement of the back-end strategy. The proven efficiency of this technique as it is implemented at La Hague facility gives the full assurance of a smooth operation of the under completion UP3 unit. The base-load management system which applies during the first ten years of its operation will make possible a noticable reduction of the commercial price for reprocessing services by the end of the century. Industrial maturity being confirmed, economic maturity is now the outstanding merit of the reprocessing and recycling strategy. It is a permanent challenge, to which the response is definitely positive in the sense of reducing the nuclear KWh production cost. (author)

MOX fuel reprocessing and recycling

International Nuclear Information System (INIS)

Guillet, J.L.

1990-01-01

This paper is devoted to the reprocessing of MOX fuel in UP2-800 plant at La Hague, and to the MOX successive reprocessing and recycling. 1. MOX fuel reprocessing. In a first step, the necessary modifications in UP2-800 to reprocess MOX fuel are set out. Early in the UP2-800 project, actions have been taken to reprocess MOX fuel without penalty. They consist in measures regarding: Dissolution; Radiological shieldings; Nuclear instrumentation; Criticality. 2. Mox successive reprocessing and recycling. The plutonium recycling in the LWR is now a reality and, as said before, the MOX fuel reprocessing is possible in UP2-800 plant at La Hague. The following actions in this field consist in verifying the MOX successive reprocessing and recycling possibilities. After irradiation, the fissile plutonium content of irradiated MOX fuel is decreased and, in this case, the re-use of plutonium in the LWR need an important increase of initial Pu enrichment inconsistent with the Safety reactor constraints. Cogema opted for reprocessing irradiated MOX fuel in dilution with the standard UO2 fuel in appropriate proportions (1 MOX for 4 UO2 fuel for instance) in order to save a fissile plutonium content compatible with MOX successive recycling (at least 3 recyclings) in LWR. (author). 2 figs

Fuel reprocessing/fabrication interface

International Nuclear Information System (INIS)

Benistan, G.; Blanchon, T.; Galimberti, M.; Mignot, E.

1987-01-01

EDF has conducted a major research, development and experimental programme concerning the recycling of plutonium and reprocessed uranium in pressurized water reactors, in collaboration with its major partners in the nuclear fuel cycle industry. Studies already conducted have demonstrated the technical and economic advantages of this recycling, as also its feasibility with due observance of the safety and reliability criteria constantly applied throughout the industrial development of the nuclear power sector in France. Data feedback from actual experience will make it possible to control the specific technical characteristics of MOX and reprocessed uranium fuels to a higher degree, as also management, viewed from the economic standpoint, of irradiated fuels and materials recovered from reprocessing. The next step will be to examine the reprocessing of MOX for reprocessed uranium fuels, either for secondary recycling in the PWR units, or, looking further ahead, in the fast breeders or later generation PWR units, after a storage period of a few years

Worldwide reprocessing supply and demand

International Nuclear Information System (INIS)

Pinto, S.

1987-01-01

The aim of this paper is to broadly examine the current situation in the LWR fuel reprocessing services market on a worldwide basis through 2010. The main factors influencing this market (nuclear programs, fuel discharges, reprocessing capacities, buyer philosophies, etc.) are identified in the paper and the most important are highlighted and discussed in more detail. Emphasis has been placed on the situation with respect to reprocessing in those countries having a significant influence on the reprocessing market

Environmental evaluation of reprocessing

International Nuclear Information System (INIS)

1979-01-01

This paper addresses two specific points. (a) The means by which it is established that reprocessing is carried out within the basic standards for radiological protection set by the ICRP. (b) A summary of the products, wastes and effluents of reprocessing together with the energy and water resources required. It is concluded that reprocessing of spent thermal reactor fuel can be undertaken whilst conforming to the basic standards set by ICRP. For domestic reasons of public acceptability some countries adopt very strict limits. Any attempt at comparisons between limits set by individual countries could lead to misunderstandings if account is not taken of these additional factors which may in turn influence the cost of reprocessing

Reprocessing: experience and future outlooks

International Nuclear Information System (INIS)

Rapin, M.

1981-01-01

It is shown that reprocessing is the best way to cope with irradiated fuels since it provides an optimized waste conditioning for long term storage, the possibility to recycle fissile material and the reduction of Pu diversion risk. The reprocessing constraints are discussed from political, technical, safety, public acceptance, and economical points of view. The French reprocessing programme (thermal reactor fuel fast breeder fuels) is presented together with a short review of the reprocessing experience and outlooks out of France [fr

Pyro-electrochemical reprocessing of irradiated MOX fast reactor fuel, testing of the reprocessing process with direct MOX fuel production

Energy Technology Data Exchange (ETDEWEB)

Kormilitzyn, M.V.; Vavilov, S.K.; Bychkov, A.V.; Skiba, O.V.; Chistyakov, V.M.; Tselichshev, I.V

2000-07-01

One of the advanced technologies for fast reactor fuel recycle is pyro-electrochemical molten salt technology. In 1998 we began to study the next phase of the irradiated oxide fuel reprocessing new process MOX {yields} MOX. This process involves the following steps: - Dissolution of irradiated fuel in molten alkaline metal chlorides, - Purification of melt from fission products that are co-deposited with uranium and plutonium oxides, - Electrochemical co-deposition of uranium and plutonium oxides under the controlled cathode potential, - Production of granulated MOX (crushing,salt separation and sizing), and - Purification of melt from fission products by phosphate precipitation. In 1998 a series of experiments were prepared and carried out in order to validate this process. It was shown that the proposed reprocessing flowsheet of irradiated MOX fuel verified the feasibility of its decontamination from most of its fission products (rare earths, cesium) and minor-actinides (americium, curium)

Pyro-electrochemical reprocessing of irradiated MOX fast reactor fuel, testing of the reprocessing process with direct MOX fuel production

International Nuclear Information System (INIS)

Kormilitzyn, M.V.; Vavilov, S.K.; Bychkov, A.V.; Skiba, O.V.; Chistyakov, V.M.; Tselichshev, I.V.

2000-01-01

One of the advanced technologies for fast reactor fuel recycle is pyro-electrochemical molten salt technology. In 1998 we began to study the next phase of the irradiated oxide fuel reprocessing new process MOX → MOX. This process involves the following steps: - Dissolution of irradiated fuel in molten alkaline metal chlorides, - Purification of melt from fission products that are co-deposited with uranium and plutonium oxides, - Electrochemical co-deposition of uranium and plutonium oxides under the controlled cathode potential, - Production of granulated MOX (crushing,salt separation and sizing), and - Purification of melt from fission products by phosphate precipitation. In 1998 a series of experiments were prepared and carried out in order to validate this process. It was shown that the proposed reprocessing flowsheet of irradiated MOX fuel verified the feasibility of its decontamination from most of its fission products (rare earths, cesium) and minor-actinides (americium, curium)

Reprocessing of nonoptimally exposed holograms

International Nuclear Information System (INIS)

Phipps, G.S.; Robertson, C.E.; Tamashiro, F.M.

1980-01-01

Two reprocessing techniques have been investigated that are capable of correcting the effects of nonoptimum optical density of photographic amplitude holograms recorded on Agfa-Gevaert type 10E75 plates. In some cases a reprocessed hologram will exhibit a diffraction efficiency even higher than that obtainable from a hologram exposed and processed to the optimum density. The SNR of the reprocessed holograms is much higher than that of the same holograms belached with cupric bromide. In some cases the SNR approaches the optimum value for a properly exposed amplitude hologram. Subjective image quality and resolution of reprocessed hologram reconstructins appear to be no different than for normal single-development holograms. Repeated reprocessing is feasible and in some cases desirable as a means of increasing diffraction efficiency

Operating experience in reprocessing

International Nuclear Information System (INIS)

Schueller, W.

1983-01-01

Since 1953, reprocessing has accumulated 180 years of operating experience in ten plants, six of them with 41 years of operation in reprocessing oxide fuel from light water reactors. After abortive, premature attempts at what is called commercial reprocessing, which had been oriented towards the market value of recoverable uranium and plutonium, non-military reprocessing technologies have proved their technical feasibility, since 1966 on a pilot scale and since 1976 on an industrial scale. Reprocessing experience obtained on uranium metal fuel with low and medium burnups can now certainly be extrapolated to oxide fuel with high burnup and from pilot plants to industrial scale plants using the same technologies. The perspectives of waste management of the nuclear power plants operated in the Federal Republic of Germany should be viewed realistically. The technical problems still to be solved are in a balanced relationship to the benefit arising to the national economy out of nuclear power generation and can be solved in time, provided there are clearcut political boundary conditions. (orig.) [de

Trends in fuel reprocessing safety research

International Nuclear Information System (INIS)

Tsujino, Takeshi

1981-01-01

With the operation of a fuel reprocessing plant in the Power Reactor and Nuclear Fuel Development Corporation (PNC) and the plan for a second fuel reprocessing plant, the research on fuel reprocessing safety, along with the reprocessing technology itself, has become increasingly important. As compared with the case of LWR power plants, the safety research in this field still lags behind. In the safety of fuel reprocessing, there are the aspects of keeping radiation exposure as low as possible in both personnel and local people, the high reliability of the plant operation and the securing of public safety in accidents. Safety research is then required to establish the safety standards and to raise the rate of plant operation associated with safety. The following matters are described: basic ideas for the safety design, safety features in fuel reprocessing, safety guideline and standards, and safety research for fuel reprocessing. (J.P.N.)

Reprocessing in Europe

Energy Technology Data Exchange (ETDEWEB)

Rossney, G [United Reprocessors G.m.b.H., Karlsruhe (F.R. Germany)

1976-04-01

The status of reprocessing activities within the member organizations of United Reprocessors is reviewed. The U.K. government has approved overseas deals by BNFL which will help to pay for their planned plant of 1000 te U p.a. at Windscale. In Germany KEWA has selected a site at Aschenburg as a fuel cycle centre where they plan to build a utility financed reprocessing plant of 1500 te U p.a. France has formed a new fuel cycle corporation, Cogema, which hopes to participate in the large volume of Japanese business negotiated by BNFL. United Reprocessors have agreed to pool their technology which may be available to organisations wishing to construct reprocessing plants in their own countries.

Prospect of spent fuel reprocessing and back-end cycling in China in 1990's

International Nuclear Information System (INIS)

Ke Youzhi; Wang Rengtao

1987-01-01

According to the CHinese Program of nuclear energy in 1990's, the amount of spent fuel by the year 2000 is estimated in this paper. Reprocessing is considered as an important link in the back-end fuel cycle. A pilot plant is scheduled for hot start up in 1996. The main goal of the study is LWR spent fuel reprocessing. We will use the experience gained from reprocessing of production reactor fuel and last research results. The advanced foreign technigue and experience will be introduced. The study emphasizes on the test of technology, equipments, instrumentation and automation, development of remote maintenance and decontamination. China will start to demonstrate the way for fuel cycle. (author)

R and D on fast reactor fuel reprocessing

International Nuclear Information System (INIS)

Subba Rao, R.V.; Vijaya Kumar, V.; Natarajan, R.

2012-01-01

disadvantages hence efforts to identify alternate partitioning reagents are also important for fast reactor fuel reprocessing. Aqueous phase partitioning method is another novel way to improve the partitioning performance of high plutonium bearing fuels, which is under development. Online monitoring of third phase formation, hull monitoring with gamma assaying, spectroscopic methods of direct measurement of plutonium are a few other important R and D activities being pursued. (author)

Reprocessing-recycling, or the application of the selective sorting and recycling policy to nuclear activities

International Nuclear Information System (INIS)

1998-12-01

In France, the reprocessing of spent fuels is the solution that has been retained for the management of the end-of-cycle. The sorting of the different components of spent fuels allows the recycling of uranium and plutonium for the further production of enriched uranium and mixed oxide fuels. This paper presents Cogema's advances in this domain (facilities and plants), the transfer of Cogema's reprocessing and recycling technologies in other countries (Japan, USA, Russia), the economical and environmental advantages of the recycling of spent fuels, the economical resources provided by this activity, and the cooperation with foreign countries for the reprocessing of their spent fuels at Cogema-La Hague. (J.S.)

Reprocessing in breeder fuel cycles

International Nuclear Information System (INIS)

Burch, W.D.; Groenier, W.S.

1982-01-01

Over the past decade, the United States has developed plans and carried out programs directed toward the demonstration of breeder fuel reprocessing in connection with the first breeder demonstration reactor. A renewed commitment to moving forward with the construction of the Clinch River Breeder Reactor (CRBR) has been made, with startup anticipated near the end of this decade. While plans for the CRBR and its associated fuel cycle are still being firmed up, the basic research and development programs required to carry out the demonstrations have continued. This paper updates the status of the reprocessing plans and programs. Policies call for breeder recycle to begin in the early to mid-1990's. Contents of this paper are: (1) evolving plans for breeder reprocessing (demonstration reprocessing plant, reprocessing head-end colocated at an existing facility); (2) relationship to LWR reprocessing; (3) integrated equipment test (IET) facility and related hardware development activities (mechanical considerations in shearing and dissolving, remote operations and maintenance demonstration phase of IET, integrated process demonstration phase of IET, separate component development activities); and (4) supporting process R and D

Advanced remote handling developments for high radiation applications

International Nuclear Information System (INIS)

Herndon, J.N.; Kring, C.T.; Feldman, M.J.; Kuban, D.P.; Martin, H.L.; Rowe, J.C.; Hamel, W.R.

1985-01-01

The Remote Control Engineering Task of the Consolidated Fuel Reprocessing Program at Oak Ridge National Laboratory has been developing advanced techniques for remote maintenance of future US fuel reprocessing plants. These efforts are based on the application of teleoperated, force-reflecting servomanipulators for dexterous remote handling with television viewing for large-volume hazardous applications. These developments fully address the nonrepetitive nature of remote maintenance in the unstructured environments encountered in fuel reprocessing. This paper covers the primary emphasis in the present program; the design, fabrication, and installation of a prototype remote handling system for reprocessing applications, the Advanced Integrated Maintenance System

Importance of nuclear fuel reprocessing

International Nuclear Information System (INIS)

Allday, C.

1977-01-01

The following topics are discussed: world energy requirements; energy conservation and the economics of recycle environmental considerations and the timescale of reprocessing; and problems associated with reprocessing. The conclusion is reached that reprocessing is essential to the conservation of the world's energy resources and is an environmentally, and probably an economically, more acceptable option to the ''throw away'' alternative

Recent R/D towards aqueous reprocessing of FBR fuels

Energy Technology Data Exchange (ETDEWEB)

Mallika, C.; Pandey, N.K.; Kumar, S.; Kamachi Mudali, U. [Materials, Process and Equipment Development Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India)

2016-07-01

The mixed Pu-rich carbide spent fuel with a burn up of 155 GWd/t from the Fast Breeder Test Reactor is being reprocessed in a hot-cell facility by PUREX process. Based on the input from the operation of this facility, research and development activities were carried out to improve the recovery, decontamination factors, economy and to reduce the waste volumes. Reduction of uranyl ions in a continuous flow electrochemical reactor and electrolytic as well as chemical reduction of 4 M HNO{sub 3} from liquid waste could be performed in continuous mode. Using the optimized parameters, suitable electrolytic cells/experimental setups were designed for the plant capacity of 6 L/h. Studies on the extraction kinetics of Ru with 30% TBP (tributyl phosphate) in NPH revealed that better decontamination factor with respect to Ru can be achieved using fast contactors like centrifugal extractors (CEs). Towards developing a spent solvent recovery system to reduce organic waste volumes, a pilot plant was set up, which could recover diluent as top product of distillation column and 40% TBP as bottom product from inactive degraded solvent. A solvent recovery system using short path distillation was also developed for installation in hot cells. (authors)

Current status and perspective of advanced loop type fast reactor in fast reactor cycle technology development project

International Nuclear Information System (INIS)

Niwa, Hajime; Aoto, Kazumi; Morishita, Masaki

2007-01-01

After selecting the combination of the sodium-cooled fast reactor (SFR) with oxide fuel, the advanced aqueous reprocessing and the simplified pelletizing fuel fabrication as the most promising concept of FR cycle system, 'Feasibility Study on Commercialized Fast Reactor Cycle Systems' was finalized in 2006. Instead, a new project, Fast Reactor Cycle Technology Development Project (FaCT Project) was launched in Japan focusing on development of the selected concepts. This paper describes the current status and perspective of the advanced loop type SFR system in the FaCT Project, especially on the design requirements, current design as well as the related innovative technologies together with the development road-map. Some considerations on advantages of the advanced loop type design are also described. (authors)

Electrochemical reactions of uranyl(VI) complexes in aqueous solution, non-aqueous solvents, and ionic liquids

International Nuclear Information System (INIS)

Ikeda, Yasuhisa

2006-01-01

Author's recent experimental results on the chemistry of U(V) in aqueous solution, non-aqueous solvents, and ionic solvents by cyclic voltametry are described. The U(V) was produced by electrochemical reduction of uranyl U(VI) ions or complexes such as carbonates, DMF(N, N-dimethylformamide), DMSO(dimethylsulfoxide), acetylacetonato, and other organic polydental ligands. The produced U(V) complexes were studied by spectrophotometry using optical-transmission thin-layer electrode. The U(V) complexes in non-aqueous solvents were found to be rather stable, they undergo ligand-dissociation reaction but not disproportionation reaction. The structure and electronic spectra as well as IR spectra of the complexes were studied. The present method was further developed to study the behavior of U(V) complexes in ionic liquids as molten salts, e.g., alkaline metals chlorides. Thus, the present research contributes to understanding the chemistry of 5fl system. Application to such nuclear technology as spent fuel reprocessing is discussed. (S. Ohno)

Design and fabrication of stainless steel components for long life of spent fuel reprocessing plants

International Nuclear Information System (INIS)

Natarajan, R.; Ramkumar, P.; Sundararaman, V.; Kamachi Mudali, U.; Baldev Raj; Shanmugam, K.

2010-01-01

Reprocessing of spent nuclear fuels based on the PUREX process is the proven process with many commercial plants operating satisfactorily worldwide. The process medium being nitric acid, austenitic stainless steel is the material of construction as it is the best commercially available material for meeting the conditions in the reprocessing plants. Because of the high radiation fields, contact maintenance of equipment and systems of these plants are very time consuming and costly unlike other chemical process plants. Though the plants constructed in the early years required extensive shut downs for replacement of equipment and systems within the first fifteen years of operation itself, development in the field of stainless steel metallurgy and fabrication techniques have made it possible to design the present day plants for an operating life period of forty years. A review of the operational experience of the PUREX process based aqueous reprocessing plants has been made in this paper and reveals that life limiting failures of equipment and systems are mainly due to corrosion while a few are due to stresses. Presently there are no standards for design specification of materials and fabrication of reprocessing plants like the nuclear power plants, where well laid down ASTM and ASME codes and standards are available which are based on the large scale operational feedbacks on pressure vessels for conventional and nuclear industries. (author)

Advanced Characterization of Molecular Interactions in TALSPEAK-like Separations Systems

Energy Technology Data Exchange (ETDEWEB)

Nash, Kenneth [Washington State Univ., Pullman, WA (United States); Guelis, Artem [Argonne National Lab. (ANL), Argonne, IL (United States); Lumetta, Gregg J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sinkov, Sergey [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2015-10-21

Combining unit operations in advanced aqueous reprocessing schemes brings obvious process compactness advantages, but at the same time greater complexity in process design and operation. Unraveling these interactions requires increasingly sophisticated analytical tools and unique approaches for adequate analysis and characterization that probe molecular scale interactions. Conventional slope analysis methods of solvent extraction are too indirect to provide much insight into such interactions. This project proposed the development and verification of several analytical tools based on studies of TALSPEAK-like aqueous processes. As such, the chemistry of trivalent fission product lanthanides, americium, curium, plutonium, neptunium and uranium figure prominently in these studies. As the project was executed, the primary focus fell upon the chemistry or trivalent lanthanides and actinides. The intent of the investigation was to compare and contrast the results from these various complementary techniques/studies to provide a stronger basis for predicting the performance of extractant/diluent mixtures as media for metal ion separations. As many/most of these techniques require the presence of metal ions at elevated concentrations, it was expected that these studies would take this investigation into the realm of patterns of supramolecular organization of metal complexes and extractants in concentrated aqueous/organic media. We expected to advance knowledge of the processes that enable and limit solvent extraction reactions as a result of the application of fundamental chemical principles to explaining interactions in complex media.

Use of reprocessed uranium. Proceedings of a technical committee meeting held in Vienna, August 2007

International Nuclear Information System (INIS)

2009-11-01

Reprocessed uranium (RepU), the uranium recovered from nuclear processing, is produced by several Member States in their facilities or through commercial contracts. From a sustainable development perspective, recycling of this uranium has become an attractive option for improving the efficiency of natural resource management and reducing radioactive waste accumulation. This publication demonstrates that reprocessing of spent fuel could form a key part of advanced fuel methodologies and describes various reuse options of RepU. In particular, it includes detailed review papers on management, storage, packaging and transport of RepU, reprocessing, utility experience and potential use of RepU. The importance of market aspects, economics and long term perspectives is also addressed

Experience of in-cell visual inspection using CCD camera in hot cell of Reprocessing Plant

International Nuclear Information System (INIS)

Reddy, Padi Srinivas; Amudhu Ramesh Kumar, R.; Geo Mathews, M.; Ravisankar, A.

2013-01-01

This paper describes the selection, customization and operating experience of the visual inspection system for the hot cell of a Reprocessing Plant. For process equipment such as fuel chopping machine, dissolver, centrifuge, centrifugal extractors etc., viewing of operations and maintenance using manipulators is required. For this, the service of in-cell camera is essential. The ambience of the hot cell of Compact facility for Reprocessing of Advanced fuels in Lead cell (CORAL) for the reprocessing of fast reactor spent fuel has high gamma radiation and acidic vapors. Black and white Charge Coupled Device (CCD) camera has been used in CORAL incorporating in-house modifications to suit the operating ambient conditions, thereby extending the operating life of the camera. (author)

R and D of On-line Reprocessing Technology for Molten-Salt Reactor Systems

International Nuclear Information System (INIS)

Uhlir, Jan; Tulackova, Radka; Chuchvalcova Bimova, Karolina

2006-01-01

The Molten Salt Reactor (MSR) represents one of promising future nuclear reactor concept included in the Generation IV reactors family. The reactor can be operated as the thorium breeder or as the actinide transmuter. However, the future deployment of Molten-Salt Reactors will be significantly dependent on the successful mastering of advanced reprocessing technologies dedicated to their fuel cycle. Here the on-line reprocessing technology connected with the fuel circuit of MSR is of special importance because the reactor cannot be operated for a long run without the fuel salt clean-up. Generally, main MSR reprocessing technologies are pyrochemical, majority of them are fluoride technologies. The proposed flow-sheets of MSR on-line reprocessing are based on a combination of molten-salt / liquid metal extraction and electro-separation processes, which can be added to the gas extraction process already verified during the MSRE project in ORNL. The crucial separation method proposed for partitioning of actinides from fission products is based on successive Anodic dissolution and Cathodic deposition processes in molten fluoride media. (authors)

Reprocessing of MTR fuel at Dounreay

International Nuclear Information System (INIS)

Hough, N.

1997-01-01

UKAEA at Dounreay has been reprocessing MTR fuel for over 30 years. During that time considerable experience has been gained in the reprocessing of traditional HEU alloy fuel and more recently with dispersed fuel. Latterly a reprocessing route for silicide fuel has been demonstrated. Reprocessing of the fuel results in a recycled uranium product of either high or low enrichment and a liquid waste stream which is suitable for conditioning in a stable form for disposal. A plant to provide this conditioning, the Dounreay Cementation Plant is currently undergoing active commissioning. This paper details the plant at Dounreay involved in the reprocessing of MTR fuel and the treatment and conditioning of the liquid stream. (author)

Transformative monitoring approaches for reprocessing.

Energy Technology Data Exchange (ETDEWEB)

Cipiti, Benjamin B.

2011-09-01

The future of reprocessing in the United States is strongly driven by plant economics. With increasing safeguards, security, and safety requirements, future plant monitoring systems must be able to demonstrate more efficient operations while improving the current state of the art. The goal of this work was to design and examine the incorporation of advanced plant monitoring technologies into safeguards systems with attention to the burden on the operator. The technologies examined include micro-fluidic sampling for more rapid analytical measurements and spectroscopy-based techniques for on-line process monitoring. The Separations and Safeguards Performance Model was used to design the layout and test the effect of adding these technologies to reprocessing. The results here show that both technologies fill key gaps in existing materials accountability that provide detection of diversion events that may not be detected in a timely manner in existing plants. The plant architecture and results under diversion scenarios are described. As a tangent to this work, both the AMUSE and SEPHIS solvent extraction codes were examined for integration in the model to improve the reality of diversion scenarios. The AMUSE integration was found to be the most successful and provided useful results. The SEPHIS integration is still a work in progress and may provide an alternative option.

Airborne effluent control for LMFBR fuel reprocessing plants

International Nuclear Information System (INIS)

Yarbro, O.O.; Groenier, W.S.; Stephenson, M.J.

1976-01-01

A significant part of the LMFBR fuel reprocessing development program has been devoted to the development of efficient removal systems for the volatile fission products, including 131 I, krypton, tritium, 129 I, and most recently 14 C. Flowsheet studies have indicated that very significant reductions of radioactive effluents can be achieved by integrating advanced effluent control systems with new concepts of containment and ventilation; however, the feasibility of such has not yet been established, nor have the economics been examined. This paper presents a flowsheet for the application of advanced containment systems to the processing of LMFBR fuels and summarizes the status and applicability of specific fission product removal systems

Nuclear fuel reprocessing in the UK

International Nuclear Information System (INIS)

Allardice, R.; Harris, D.; Mills, A.

1983-01-01

Nuclear fuel reprocessing has been carried out on an industrial scale in the United Kingdom since 1952. Two large reprocessing plants have been constructed and operated at Windscale, Cumbria and two smaller specialized plants have been constructed and operated at Dounreay, Northern Scotland. At the present time, the second of the two Windscale plants is operating, and Government permission has been given for a third reprocessing plant to be built on that site. At Dounreay, one of the plants is operating in its original form, whilst the second is now operating in a modified form, reprocessing fuel from the prototype fast reactor. This chapter describes the development of nuclear fuel reprocessing in the UK, commencing with the research carried out in Canada immediately after the Second World War. A general explanation of the techniques of nuclear fuel reprocessing and of the equipment used is given. This is followed by a detailed description of the plants and processes installed and operated in the UK

Nuclear fuel reprocessing in the UK

International Nuclear Information System (INIS)

Allardice, R.H.; Harris, D.W.; Mills, A.

1983-01-01

Nuclear fuel reprocessing has been carried out on an industrial scale in the United Kingdom since 1952. Two large reprocessing plants have been constructed and operated at Windscale, Cumbria and two smaller specialized plants have been constructed and operated at Dounreay, Northern Scotland. At the present time, the second of the two Windscale plants is operating, and Government permission has been given for a third reprocessing plant to be built on that site. At Dounreay, one of the plants is operating in its original form, whilst the second is now operating in a modified form, reprocessing fuel from the prototype fast reactor. This chapter describes the development of nuclear fuel reprocessing in the UK, commencing with the research carried out in Canada immediately after the Second World War. A general explanation of the techniques of nuclear fuel reprocessing and of the equipment used is given. This is followed by a detailed description of the plants and processes installed and operated in the UK. (author)

Advanced techniques for analytic liquid wastes management in the Rokkasho reprocessing plant

International Nuclear Information System (INIS)

Madic, C.; Moulin, J.P.; Runge, S.; Schott, R.; Kashiwai, T.; Hayashi, M.

1991-01-01

The JNFS Rokkasho reprocessing plant is a large scale commercial reprocessing plant. Liquid waste treatment relies on concentration by evaporation. The management of liquid wastes is rather sophisticated and implies, beside the organic wastes, sorting out between process and non-process, acidic and salt-bearing, tritiated and low tritiated streams and also according to their level of activity. A particular attention had to be paid to the analytical wastes, as their particularity is to contain not only a significant amount of radioactivity but also some fissile material and exotic chemicals which are useful for analytical purpose but unwanted in the main process mainly because of their corrosive and chelating properties. The analytical wastes are sorted out according to their activity level and fissile material content. On the one hand, a specific process has been developed to recover the bulk of plutonium from the analytical wastes. On the other hand, the foreseeable amount of unwanted chemicals (such as chloride ions) has been drastically reduced by carefully selecting all the analytical methods either by modification of already known methods or in some cases by working out new methods

Mono- and di-n-butyl phosphates of some metals in spent nuclear fuel reprocessing

Energy Technology Data Exchange (ETDEWEB)

Solovkin, A.S.

1982-01-01

Results of investigations which have been carried out in the Soviet Union for the last 10 years on the determination of the composition, structure, conditions of the formation and solubility of mono- and di-n-butyl phosphates of metals (U/sup 6 +/, Pu/sup 4 +/, Pu/sup 3 +/, Th, Zr, Fe/sup 3 +/, Am, Al, rare-earth elements), which are important for the processes of irradiated nuclear fuel reprocessing, are presented. A conclusion is made that zirconium mono- and di-n-butyl phosphates are the least soluble in aqueous and organic solvents of all investigated compounds. FeA/sub 3/ and AmA/sub 3/ are weakly soluble in aqueous solutions. The other compounds are sufficiently soluble in moderately acidic aqueous solutions or in DBP and TBP with dilutents. The obtained results indicate at the similarity of zirconium and plutonium (4) chemical properties; thorium, in this respect, is not an analogue of plutonium (4). Possible structural formulas of the investigated compounds are considered.

Safeguards for reprocessing and enrichment plants

International Nuclear Information System (INIS)

1977-01-01

material, uranium oxide powder, would have to be converted to uranium hexafluoride and then processed in an enrichment plant. The implication is that a technologically advanced plant (presumably clandestine) would have to be available to the diverter intending to make military use of material from a reactor or a fabrication plant. There is a vital difference in the situation with reprocessing and enrichment plants. These plants are designed to produce plutonium or enriched uranium, so that diversion now involves only misuse of the end product, which with a little further work could perhaps be used to produce a weapon. This, however, is only true for certain modes of operation of the plants in question. Nonetheless, it is certainly true as a very simplified generalization that a reprocessing or enrichment plant does represent a significant jump in the usability of material for weapons purposes. (author)

THORP and the economics of reprocessing

International Nuclear Information System (INIS)

Berkhout, F.; Walker, W.

1990-11-01

This Report compares the costs of reprocessing spent fuels at the new THORP reprocessing plant at Sellafield with the alternative of storing them prior to final disposal. It finds that even when the cost of constructing THORP is treated as a sunk cost, reprocessing has no decisive economic advantage over spent fuel storage. Electric utilities in Western Europe and Japan have already largely paid for the construction of the new British and French reprocessing plants. Today, their economic judgements therefore depend on the future costs of operating and eventually decommissioning the plants, and of dealing with the resulting wastes and separated products. The costs attached to reprocessing have risen mainly due to the higher estimated costs of waste management and decommissioning, and to the costs of coping with unwanted plutonium. Most of these costs are passed directly on to utilities and thus electricity consumers under the terms of cost-plus contracts. Using cost estimates favourable to the reprocessing option, the total future undiscounted liabilities arising from the first ten years of THORP reprocessing come to Pound 2.4-3.7 billion at today's prices. This compares with the more predictable although still burdensome fuel storage, conditioning and disposal costs of Pound 3.0-3.8 billion. If disposal is not anticipated, the economic advantage shifts decisively in favour of spent fuel storage: Pound 0.9-1.3 billion against Pound 1.4-2.4 billion for reprocessing. (author)

Case outsourcing medical device reprocessing.

Science.gov (United States)

Haley, Deborah

2004-04-01

IN THE INTEREST OF SAVING MONEY, many hospitals are considering extending the life of some single-use medical devices by using medical device reprocessing programs. FACILITIES OFTEN LACK the resources required to meet the US Food and Drug Administration's tough quality assurance standards. BY OUTSOURCING, hospitals can reap the benefits of medical device reprocessing without assuming additional staffing and compliance burdens. OUTSOURCING enables hospitals to implement a medical device reprocessing program quickly, with no capital investment and minimal effort.

Reprocessing of LEU silicide fuel at Dounreay

International Nuclear Information System (INIS)

Cartwright, P.

1996-01-01

UKAEA have recently reprocessed two LEU silicide fuel elements in their MTR fuel reprocessing plant at Dounreay. The reprocessing was undertaken to demonstrate UKAEA's commitment to the world-wide research reactor communities future needs. Reprocessing of LEU silicide fuel is seen as a waste treatment process, resulting in the production of a liquid feed suitable for conditioning in a stable form of disposal. The uranium product from the reprocessing can be used as a blending feed with the HEU to produce LEU for use in the MTR cycle. (author)

Reprocessing and waste management in the UK

International Nuclear Information System (INIS)

Mogg, C.S.; Howarth, G.G.

1987-01-01

The paper concerns the progress in irradiated fuel reprocessing and waste management at the Sellafield site. Magnox fuel reprocessing is reviewed and oxide fuel reprocessing, due to commence in the early 1990s, is compared with existing practices. The article describes how magnox fuel reprocessing will be sustained by recent additions of new plant and shows how waste management downstream of reprocessing will be integrated across the Sellafield site. This article was first presented as a paper at the Waste Management '87 (1-5 March, Tucson, Arizona) conference. (author)

Recycling of reprocessed uranium

International Nuclear Information System (INIS)

Randl, R.P.

1987-01-01

Since nuclear power was first exploited in the Federal Republic of Germany, the philosophy underlying the strategy of the nuclear fuel cycle has been to make optimum use of the resource potential of recovered uranium and plutonium within a closed fuel cycle. Apart from the weighty argument of reprocessing being an important step in the treatment and disposal of radioactive wastes, permitting their optimum ecological conditioning after the reprocessing step and subsequent storage underground, another argument that, no doubt, carried weight was the possibility of reducing the demand of power plants for natural uranium. In recent years, strategies of recycling have emerged for reprocessed uranium. If that energy potential, too, is to be exploited by thermal recycling, it is appropriate to choose a slightly different method of recycling from the one for plutonium. While the first generation of reprocessed uranium fuel recycled in the reactor cuts down natural uranium requirement by some 15%, the recycling of a second generation of reprocessed, once more enriched uranium fuel helps only to save a further three per cent of natural uranium. Uranium of the second generation already carries uranium-232 isotope, causing production disturbances, and uranium-236 isotope, causing disturbances of the neutron balance in the reactor, in such amounts as to make further fabrication of uranium fuel elements inexpedient, even after mixing with natural uranium feed. (orig./UA) [de

Reprocessing of spent nuclear fuel

International Nuclear Information System (INIS)

Kidd, S.

2008-01-01

The closed fuel cycle is the most sustainable approach for nuclear energy, as it reduces recourse to natural uranium resources and optimises waste management. The advantages and disadvantages of used nuclear fuel reprocessing have been debated since the dawn of the nuclear era. There is a range of issues involved, notably the sound management of wastes, the conservation of resources, economics, hazards of radioactive materials and potential proliferation of nuclear weapons. In recent years, the reprocessing advocates win, demonstrated by the apparent change in position of the USA under the Global Nuclear Energy Partnership (GNEP) program. A great deal of reprocessing has been going on since the fourties, originally for military purposes, to recover plutonium for weapons. So far, some 80000 tonnes of used fuel from commercial power reactors has been reprocessed. The article indicates the reprocessing activities and plants in the United Kigdom, France, India, Russia and USA. The aspect of plutonium that raises the ire of nuclear opponents is its alleged proliferation risk. Opponents of the use of MOX fuels state that such fuels represent a proliferation risk because the plutonium in the fuel is said to be 'weapon-use-able'. The reprocessing of used fuel should not give rise to any particular public concern and offers a number of potential benefits in terms of optimising both the use of natural resources and waste management.

Modeling of Pu(IV) extraction and HNO3 speciation in nuclear fuel reprocessing

International Nuclear Information System (INIS)

De-Sio, S.

2012-01-01

The PUREX process is a solvent extraction method dedicated to the reprocessing of irradiated nuclear fuel in order to recover pure uranium and plutonium from aqueous solutions of concentrated nitric acid. The tri-n-butylphosphate (TBP) is used as the extractant in the organic phase. The aim of this thesis work was to improve the modeling of liquid-liquid extraction media in nuclear fuel reprocessing. First, Raman and 14 N NMR measurements, coupled with theoretical calculations based on simple solutions theory and BIMSA modeling, were performed in order to get a better understanding of nitric acid dissociation in binary and ternary solutions. Then, Pu(IV) speciation in TBP after extraction from low nitric acid concentrations was investigated by EXAFS and vis-NIR spectroscopies. We were able to show evidence of the extraction of Pu(IV) hydrolyzed species into the organic phase. A new structural study was conducted on An(VI)/TBP and An(IV)/TBP complexes by coupling EXAFS measurements with DFT calculations. Finally, extraction isotherms modeling was performed on the Pu(IV)/HNO 3 /H 2 O/TBP 30%/dodecane system (with Pu at tracer scale) by taking into account deviation from ideal behaviour in both organic and aqueous phases. The best modeling was obtained when considering three plutonium (IV) complexes in the organic phase: Pu(OH) 2 (NO 3 ) 2 (TBP) 2 , Pu(NO 3 ) 4 (TBP) 2 and Pu(NO 3 ) 4 (TBP) 3 . (author) [fr

Method for increasing the lifetime of an extraction medium used for reprocessing spent nuclear fuel and/or breeder materials

International Nuclear Information System (INIS)

Schmieder, H.; Stieglitz, L.

1977-01-01

A method is provided for increasing the lifetime of an extraction medium containing an organophosphorus acid ester and a hydrocarbon and being used for reprocessing spent nuclear fuel and/or breeder materials. Impurities resulting from chemical and/or radiolytic decomposition and interfering compounds of such impurities with radionuclides are removed from the extraction medium by bringing the extraction medium, after use, into intimate contact with an aqueous hydrazine hydrate solution having a concentration of between 0.1 and 1.0 molar at a temperature between 20 to 75 0 C. The aqueous hydrazine hydrate solution is then separated from the extraction medium

Future trends in reprocessing

International Nuclear Information System (INIS)

Rouyer, H.

1994-01-01

This paper about future trends in reprocessing essentially reflects French experience and points of view as an example of countries which, like England and Japan, consider that reprocessing is the best solution for the back end of the fuel cycle. In order to know what the future will be, it is necessary to look back at the past and try to find what have been the main reasons for evolution in that period. For reprocessing, it appears that these motivations have been 'safety and economics'. They will remain the motivations for the future. In addition, new motivations for development are starting to appear which are still imprecise but can be expressed as follows: 'which guarantees will public opinion require in order to be convinced that solutions for waste management, proposed by specialists shall ensure that a healthy environment is preserved for the use of future generations'. Consequently the paper examines successively the evolution of reprocessing in the recent past, what the immediate future could be and finally what should be necessary in the long term. (Author)

Indian experience in fuel reprocessing

International Nuclear Information System (INIS)

Prasad, A.N.; Kumar, S.V.

1977-01-01

Plant scale experience in fuel reprocessing in India was started with the successful design, execution and commissioning of the Trombay plant in 1964 to reprocess aluminium clad metallic uranium fuel from the 40 MWt research reactor. The plant has helped in generating expertise and trained manpower for future reprocessing plants. With the Trombay experience, a larger plant of capacity 100 tonnes U/year to reprocess spent oxide fuels from the Tarapur (BWR) and Rajasthan (PHWR) power reactors has been built at Tarapur which is undergoing precommissioning trial runs. Some of the details of this plant are dealt with in this paper. In view of the highly corrosive chemical attack the equipment and piping are subjected to in a fuel reprocessing plant, some of them require replacement during their service if the plant life has to be extended. This calls for extensive decontamination for bringing the radiation levels low enough to establish direct accesss to such equipment. For making modifications in the plant to extend its life and also to enable expansion of capacity, the Trombay plant has been successfully decontaminated and partially decommissioned. Some aspects of thi decontamination campaign are presented in this paper

Status of advanced tritium breeder development for DEMO in the broader approach activities in Japan

International Nuclear Information System (INIS)

Hoshino, Tsuyoshi; Oikawa, Fumiaki; Nishitani, Takeo

2010-01-01

DEMO reactors require ' 6 Li-enriched ceramic tritium breeders' which have high tritium breeding ratios (TBRs) in the blanket designs of both EU and JA. Both parties have been promoting the development of fabrication technologies of Li 2 TiO 3 pebbles and of Li 4 SiO 4 pebbles including the reprocessing. However, the fabrication techniques of tritium breeders pebbles have not been established for large quantities. Therefore, these parties launch a collaborative project on scaleable and reliable production routes of advanced tritium breeders. In addition, this project aims to develop fabrication techniques allowing effective reprocessing of 6 Li. The development of the production and 6 Li reprocessing techniques includes preliminary fabrication tests of breeder pebbles, reprocessing of lithium, and suitable out-of-pile characterizations. The R and D on the fabrication technologies of the advanced tritium breeders and the characterization of developed materials has been started between the EU and Japan in the DEMO R and D of the International Fusion Energy Research Centre (IFERC) project as a part of the Broader Approach activities from 2007 to 2016. The equipment for production of advanced breeder pebbles is planned will be installed in the DEMO R and D building at Rokkasho, Japan. The design work in this facility was carried out. The specifications of the pebble production apparatuses and related equipment in this facility were fixed, and the basic data of these apparatuses was obtained. In this design work, the preliminary investigations of the dissolution and purification process of tritium breeders were carried out. From the results of the preliminary investigations, lithium resources of 90% above were recovered by the aqueous dissolving methods using HNO 3 and H 2 O 2 . The removal efficiency of 60 Co by the addition in the dissolved solutions of lithium ceramics were 97-99.9% above using activated carbon impregnated with 8-hydroxyquinolinol. In this report

Development of pulsed plate columns for fast reactor fuel reprocessing

International Nuclear Information System (INIS)

Jenkins, J.A.; Logsdail, D.H.; Lyall, E.; Myers, P.E.; Partridge, B.A.

1987-01-01

The UK Atomic Energy Authority has undertaken a development programme on solvent extraction equipment for reprocessing fast reactor fuels. As part of this programme a solvent extraction pilot plant has been built at Harwell in which a variety of flowsheet conditions can be simulated using the system uranyl nitrate/nitric acid (UN/HNO 3 ) - 20% tri-n-butyl phosphate in odourless kerosene (TBP/OK). The main purpose of present pilot plant operations is to study the performance of pulsed plate columns, with the following specific objectives: to measure the volumetric throughput capacity of the columns, - to study the effect of scale-up of column diameter on U mass transfer performance, - to provide hydraulic and mass transfer data for a dynamic simulation model of pulsed column operation, - to develop and test instruments and ancillary equipment. This poster describes the pilot plant and is illustrated by experimental data, with particular reference to an external settler for controlling the removal of aqueous phase from columns operated with the aqueous phase dispersed

Reprocessing of spent nuclear fuels in OECD countries

International Nuclear Information System (INIS)

1977-01-01

This report deals with the adequacy of projected reprocessing capacity, the short-term measures proposed in view of the lack of sufficient reprocessing capacity, the longer term measures proposed in view of the lack of sufficient reprocessing capacity, the alternatives to reprocessing and the cooperative arrangements

Reprocessing the truth

International Nuclear Information System (INIS)

Goldsmith, E.; Bunyard, P.; Hildyard, N.

1978-01-01

Comments are made on the Report by the Inspector, Mr. Justice Parker, after the public inquiry into the application by British Nuclear Fuels Limited for permission to construct and operate a thermal oxide reprocessing plant at their Windscale works. Particular questions raised include: corrosion or storage of spent fuel, vitrification of radioactive waste; radiation effects, and permissible levels; radioactive emissions, critical groups and critical pathways; risks; reprocessing economics; commitment to the FBR; sociological aspects, including employment, nuclear weapon proliferation and terrorism, and Britain's moral responsibilities. (U.K.)

Alternative reprocessing schemes evaluation

International Nuclear Information System (INIS)

1979-02-01

This paper reviews the parameters which determine the inaccessibility of the plutonium in reprocessing plants. Among the various parameters, the physical and chemical characteristics of the materials, the various processing schemes and the confinement are considered. The emphasis is placed on that latter parameter, and the advantages of an increased confinement in the socalled PIPEX reprocessing plant type are presented

Economic feasibility study of regional centers for nuclear fuel reprocessing in the developing countries

International Nuclear Information System (INIS)

Bakeshloo, A.A.

1977-01-01

The fuel cycle costs for the following three different economic alternatives were studied: (1) Reprocessing in an industrialized country (such as the U.S.); (2) Reprocessing in the individual developing country; (3) Reprocessing in a regional center. The nuclear fuel cycle cost for the ''Throw-away'' fuel cycle was evaluated. Among the six regions which were considered in this study, region one (South America including Mexico) was selected for the economic analysis of the nuclear fuel cycle for the above three alternatives. For evaluation of the cases where the fuel is reprocessed in a regional center or in an individual developing country, a unit reprocessing cost equation was developed. An economic evaluation was developed to estimate the least expensive method for transporting radioactive nuclear material by either leased or purchased shipping casks. The necessary equations were also developed for estimating plutonium transportation and the safeguard costs. On the basis of nuclear material and services requirements and unit costs for each component, the levelized nuclear fuel cycle costs for each alternative were estimated. Finally, by a comparison of cost, among these three alternatives plus the ''Throw-away'' case,it was found that it is not at all economical to build individual reprocessing plants inside the developing countries in region one. However, it also was found that the economic advantage of a regional center with respect to the first alternative is less than a 4% difference between their total fuel cycle costs. It is concluded that there is no great economic advantage in any developing countries to seek to process their fuel in one of the advanced countries. Construction of regional reprocessing centers is an economically viable concept

The case for reprocessing: the operational experience of a modern reprocessing industry

International Nuclear Information System (INIS)

Giraud, J.P.; Kelly, W.

1993-01-01

Reprocessing is a high-tech industry that works. An impressive effort of R and D, industrial deployment and operational experience has been accumulated by COGEMA and BNFL, leading these companies to offer a commercial service which is the only proper management of spent fuel and waste that is both technically demonstrated and qualified by the safety authorities of European and overseas countries. Reprocessing, as every technology-based industry will continue to progress in the future. Recycling the fissile materials reclaimed from spent fuel: uranium and plutonium, is the complementary and indispensable last link to effectively close the fuel cycle and control in particular the production of plutonium and other long-lived actinides. This paper will describe the state of development attained in France and Great Britain and will underline the main advantages of the reprocessing/recycling strategy

The uranium and thorium separation in the chemical reprocessing of the irradiated fuel of thorium and uranium mixed oxides

International Nuclear Information System (INIS)

Oliveira, E.F. de.

1984-09-01

A bibliographic research has been carried out for reprocessing techniques of irradiated thorium fuel from nuclear reactors. The Thorex/Hoechst process has been specially considered to establish a method for reprocessing thorium-uranium fuel from PWR. After a series of cold tests performed in laboratory it was possible to set the behavior of several parameters affecting the Thorex/Hoechst process. Some comments and suggestions are presented for modifications in the process flosheet conditions. A discussion is carried out for operational conditions such as the aqueous to organic flow ratio the acidity of strip and scrub solutions in the process steps for thorium and uranium recovery. The operation diagrams have been constructed using equilibrium experimental data which correspond to conditions observed in laboratory. (Author) [pt

Flory-Stockmayer analysis on reprocessable polymer networks

Science.gov (United States)

Li, Lingqiao; Chen, Xi; Jin, Kailong; Torkelson, John

Reprocessable polymer networks can undergo structure rearrangement through dynamic chemistries under proper conditions, making them a promising candidate for recyclable crosslinked materials, e.g. tires. This research field has been focusing on various chemistries. However, there has been lacking of an essential physical theory explaining the relationship between abundancy of dynamic linkages and reprocessability. Based on the classical Flory-Stockmayer analysis on network gelation, we developed a similar analysis on reprocessable polymer networks to quantitatively predict the critical condition for reprocessability. Our theory indicates that it is unnecessary for all bonds to be dynamic to make the resulting network reprocessable. As long as there is no percolated permanent network in the system, the material can fully rearrange. To experimentally validate our theory, we used a thiol-epoxy network model system with various dynamic linkage compositions. The stress relaxation behavior of resulting materials supports our theoretical prediction: only 50 % of linkages between crosslinks need to be dynamic for a tri-arm network to be reprocessable. Therefore, this analysis provides the first fundamental theoretical platform for designing and evaluating reprocessable polymer networks. We thank McCormick Research Catalyst Award Fund and ISEN cluster fellowship (L. L.) for funding support.

Spent fuel management: reprocessing or storage

International Nuclear Information System (INIS)

Lima Soares, M.L. de; Oliveira Lopes, M.J. de

1986-01-01

A review of the spent fuel management concepts generally adopted in several countries is presented, including an analysis of the brazilian situation. The alternatives are the reprocessing, the interim storage and the final disposal in a repository after appropriate conditioning. The commercial operating reprocessing facilities in the Western World are located in France and in the United Kingdom. In the USA the anti-reprocessing policy from 1977 changed in 1981, when the government supported the resumption of commercial reprocessing and designated the private sector as responsible for providing these services. Small scale facilities are operating in India, Italy, Japan and West Germany. Pilot plants for LWR fuel are being planned by Spain, Pakistan and Argentina. (Author) [pt

Spent fuel management: reprocessing or storage

International Nuclear Information System (INIS)

Lima Soares, M.L. de; Oliveira Lopes, M.J. de.

1986-01-01

A review of the spent fuel management concepts generally adopted in several countries is presented, including an analysis of the brazilian situation. The alternatives are the reprocessing, the interim storage and the final disposal in a repository after appropriate conditioning. The commercial operating reprocessing facilities in the Western World are located in France and in the United Kingdom. In the USA the anti-reprocessing policy from 1977 changed in 1981, when the Government supported the resumption of commercial reprocessing and designated the private sector as responsible for providing these services. Small scale facilities are operating in India, Italy, Japan and West Germany. Pilot plant for LWR fuel are being planned by Spain, Pakistan and Argentina. (Author) [pt

Nuclear fuel reprocessing and high level waste disposal: informational hearings. Volume V. Reprocessing. Part 2

Energy Technology Data Exchange (ETDEWEB)

None

1977-03-08

Testimony was presented by a four member panel on the commercial future of reprocessing. Testimony was given on the status of nuclear fuel reprocessing in the United States. The supplemental testimony and materials submitted for the record are included in this report. (LK)

Reprocessing of spent nuclear fuel

International Nuclear Information System (INIS)

Schmitt, D.

1985-01-01

How should the decision in favour of reprocessing and against alternative waste management concepts be judged from an economic standpoint. Reprocessing is not imperative neither for resource-economic reasons nor for nuclear energy strategy reasons. On the contrary, the development of an ultimate storage concept representing a real alternative promising to close, within a short period of time, the nuclear fuel cycle at low cost. At least, this is the result of an extensive economic efficiency study recently submitted by the Energy Economics Institute which investigated all waste management concepts relevant for the Federal Republic of Germany in the long run, i.e. direct ultimate storage of spent fuel elements (''Other waste disposal technologies'' - AE) as well as reprocessing of spent fuel elements where re-usable plutonium and uranium are recovered and radioactive waste goes to ultimate storage (''Integrated disposal'' - IE). Despite such fairly evident results, the government of the Federal Republic of Germany has favoured the construction of a reprocessing plant. From an economic point of view there is no final answer to the question whether or not the argumentation is sufficient to justify the decision to construct a reprocessing plant. This is true for both the question of technical feasibility and issues of overriding significance of a political nature. (orig./HSCH) [de

Handling and storage of high-level liquid wastes from reprocessing of spent fuel

International Nuclear Information System (INIS)

Finsterwalder, L.

1982-01-01

The high level liquid wastes arise from the reprocessing of irradiated nuclear fuels, which are dissolved in aqueous acid solution, and the plutonium and unburned uranium removed in the chemical separation plant. The remaining solution, containing more than 99% of the dissolved fission products, together with impurities from cladding materials, corrosion products, traces of unseparated plutonium and uranium and most of the transuranic elements, constitutes the high-level waste. At present, these liquid wastes are usually concentrated by evaporation and stored as an aqueous nitric acid solution in high-integrity stainless-steel tanks. There is now world-wide agreement that, for the long term, these liquid wastes should be converted to solid form and much work is in progress to develop techniques for the solidification of these wastes. This paper considers the design requirements for such facilities and the experience gained during nearly 30 years of operation. (orig./RW)

Experience and prospects in reprocessing

International Nuclear Information System (INIS)

Rougeau, J.-P.

1997-01-01

Reprocessing nuclear fuels is a long and successful industrial story. For decades, commercial reprocessing plants have been operating in France, the United Kingdom and Japan. The industrial outcome is clear and widely recognized: thousand tons of spent fuels have been reprocessed in these plants. Over the years, these facilities have been adapted to new types of fuel. Thus, the nuclear industry has fully demonstrated its ability to cope with technological change and its capacity to adapt itself to improvements. For decades, technical capability has been stressed and emphasized by nuclear industrial leaders as the most important point. This is no longer the case. Today the industry has to face a new commercial reality and to find the most adaptable answer to the utilities' requirements. This paper presents the current achievements and medium and long-term trends of the nuclear reprocessing activity, the ongoing commercial changes and gives an outlook for future evolutions. International political factors will also be examined. (author)

Improving Materials Accountancy for Reprocessing using hiRX

International Nuclear Information System (INIS)

Cipiti, B.; McDaniel, M.; Havrilla, G.

2015-01-01

The High Resolution X-ray (hiRX) technology has the potential to replace K-Edge and Hybrid K-Edge Densitometry (HKED) for routine accountability measurements in reprocessing. This technology may significantly reduce plutonium measurement uncertainty in a simpler and less costly instrument. X-ray optics are used to generate monochromatic excitation of a sample and selectively collect emitted X-rays of the target elements. The result is a spectrum with a peak specific to one element with negligible background. Modeling was used to examine how safeguards could be improved through the use of hiRX at existing aqueous reprocessing plants. This work utilized the Separation and Safeguards Performance Model (SSPM), developed at Sandia National Laboratories, to examine how reduced measurement uncertainty decreases the overall inventory difference measurement error. Material loss scenarios were also modelled to determine the effect on detection probability for protracted diversion of nuclear material. Current testing of hiRX is being used to inform the modelling effort, but a 0.1% measurement uncertainty for uranium and plutonium concentration is an optimistic goal based on laboratory results. Modeling results showed that a three-fold improvement in the ability to detect a protracted diversion of plutonium may be possible if the 0.1% uncertainty goal can be achieved. The modelling results will be presented along with a discussion of the current experimental campaign results. In addition, a qualitative cost analysis will be presented to compare the use of hiRX with HKED. (author)

The Planning of a Small Pilot Plant for Development Work on Aqueous Reprocessing of Nuclear Fuels

Energy Technology Data Exchange (ETDEWEB)

Sjoeborg, T U; Haeffner, E; Hultgren, Aa

1963-10-15

A shielded volume (42 m{sup 3}) in the hot laboratory at Kjeller, Norway, has been used for the installation of a small pilot plant intended for studies on nuclear fuel reprocessing. During the first period of operation (1963) a plutonium separation method (the Silex process) developed at AB Atomenergi will be studied. This document is a description of the project during the stage of technical planning and chemical process development.

Reprocessing considerations for a developing country

International Nuclear Information System (INIS)

This paper describes some of the alternatives for dealing with spent fuel that face a developing country. It then discusses the considerations that affect decisions on the size and siting of reprocessing plants, and shows how small plants may be suitable in countries without the means to transport spent fuel easily. The paper also outlines the reasons for reprocessing in India, and describes the development of India's reprocessing capability. It shows how the economic conditions in India, such as low skilled labour costs, make reprocessing plants of 100 to 200 tonnes U/yr capacity economic, and includes a table giving technical data on a 100 t U/yr national plant for inclusion in the reference cases used by INFCE Working Group 4

Gloves Reprocessing: Does It Really Save Money?

Science.gov (United States)

Arora, Pankaj; Kumari, Santosh; Sodhi, Jitender; Talati, Shweta; Gupta, Anil Kumar

2015-12-01

Gloves are reprocessed and reused in health-care facilities in resource-limited settings to reduce the cost of availability of gloves. The study was done with the aim to compute the cost of reprocessing of gloves so that an economically rationale decision can be taken. A retrospective record-based cross-sectional study was undertaken in a central sterile supply department where different steps during reprocessing of gloves were identified and the cost involved in reprocessing per pair of gloves was calculated. The cost of material and manpower was calculated to arrive at the cost of reprocessing per pair of gloves. The cost of a reprocessed pair of surgical gloves was calculated to be Indian Rupee (INR) 14.33 which was greater than the cost of a new pair of disposable surgical gloves (INR 9.90) as the cost of sterilization of one pair of gloves itself came out to  be INR 10.97. The current study showed that the purchase of sterile disposable single-use gloves is cheaper than the process of recycling. Reprocessing of gloves is not economical on tangible terms even in resource-limited settings, and from the perspective of better infection control as well as health-care worker safety, it further justifies the use of disposable gloves.

Will the world SNF be reprocessed in Russia?

International Nuclear Information System (INIS)

Gagarinski, A.

2000-01-01

Russia's possibilities in nuclear fuel reprocessing are well known. RT-1 plant with 400 tons/year in the Chelyabinsk region can provide reprocessing of fuel from Russian and Central European WWER-440 reactors, as well as from transport and research reactors. Former military complex Krasnoyarsk-26 with unique underground installations situated in rock galleries, already has an aqueous facility for storage of 6000 tons of spent nuclear fuel (SNF), half-built plant RT-2 for nuclear fuel reprocessing with 1500 tons/year capacity, as well as the projects of dry storage facility for 30000 tons of SNF and of MOX fuel production plant. Russian nuclear specialists understand well, that the economic efficiency of nuclear fuel reprocessing industry is shown only in case of large-scale production, which would require consolidation of the countries, which develop nuclear energy. They also understand, that Russia has all the possibilities to become one of the centers of such a consolidation and to use these possibilities for the benefit of the country. The idea of foreign nuclear fuel reprocessing (for a long time realized for East and Central European countries, which operate Soviet-design reactors) has existed in the specialists' minds, and sometimes has appeared in the mass media. On the other hand, rehabilitation of territories of nuclear fuel cycle enterprises in Russia continues, including the Karachai lake, which contains 120 million Curie of radioactivity. Unfortunately, Russia simply has no money for complete solution of the problems of radiation military legacy. During discussion of the budget for 2000, the Russian Minatom has made a daring step. A real program, how to find money needed for solving the 'radiation legacy' problem, was proposed. With this purpose, it was proposed to permit storage and further reprocessing of other countries' SNF on Russian territory. It is well known, that another countries' SNF is accepted for reprocessing by UK and France, and Russia

Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities

Directory of Open Access Journals (Sweden)

Nick R. Soelberg

2013-01-01

Full Text Available The removal of volatile radionuclides generated during used nuclear fuel reprocessing in the US is almost certain to be necessary for the licensing of a reprocessing facility in the US. Various control technologies have been developed, tested, or used over the past 50 years for control of volatile radionuclide emissions from used fuel reprocessing plants. The US DOE has sponsored, since 2009, an Off-gas Sigma Team to perform research and development focused on the most pressing volatile radionuclide control and immobilization problems. In this paper, we focus on the control requirements and methodologies for 85Kr and 129I. Numerous candidate technologies have been studied and developed at laboratory and pilot-plant scales in an effort to meet the need for high iodine control efficiency and to advance alternatives to cryogenic separations for krypton control. Several of these show promising results. Iodine decontamination factors as high as 105, iodine loading capacities, and other adsorption parameters including adsorption rates have been demonstrated under some conditions for both silver zeolite (AgZ and Ag-functionalized aerogel. Sorbents, including an engineered form of AgZ and selected metal organic framework materials (MOFs, have been successfully demonstrated to capture Kr and Xe without the need for separations at cryogenic temperatures.

Workshop on instrumentation and analyses for a nuclear fuel reprocessing hot pilot plant

International Nuclear Information System (INIS)

Babcock, S.M.; Feldman, M.J.; Wymer, R.G.; Hoffman, D.

1980-05-01

In order to assist in the study of instrumentation and analytical needs for reprocessing plants, a workshop addressing these needs was held at Oak Ridge National Laboratory from May 5 to 7, 1980. The purpose of the workshop was to incorporate the knowledge of chemistry and of advanced measurement techniques held by the nuclear and radiochemical community into ideas for improved and new plant designs for both process control and inventory and safeguards measurements. The workshop was athended by experts in nuclear and radiochemistry, in fuel recycle plant design, and in instrumentation and analysis. ORNL was a particularly appropriate place to hold the workshop since the Consolidated Fuel Reprocessing Program (CFRP) is centered there. Requirements for safeguarding the special nuclear materials involved in reprocessing, and for their timely measurement within the process, within the reprocessing facility, and at the facility boundaries are being studied. Because these requirements are becoming more numerous and stringent, attention is also being paid to the analytical requirements for these special nuclear materials and to methods for measuring the physical parameters of the systems containing them. In order to provide a focus for the consideration of the workshop participants, the Hot Experimental Facility (HEF) being designed conceptually by the CFRP was used as a basis for consideration and discussions

Economic evaluation of reprocessing

International Nuclear Information System (INIS)

This paper, which also appears as an Appendix to the Final Working Group 4 report, considers the economics of the four basic options available in nuclear programmes namely: the once-through cycle; reprocessing with uranium recycle and plutonium storage; reprocessing with both uranium and plutonium recycle; and the fast reactor. These options are represented by four separate areas on a ''phase diagram'' showing the relationship between relative generating costs and uranium ore price. The basic algebra defining each component of electricity cost is given for each option. The diagram can take different forms depending upon the relative magnitudes of the costs of reprocessing and MOX fuel fabrication and whether the once-through fuel cycle is acceptable or not on grounds other than strictly economic, i.e. environmental grounds. The shortcomings of this form of presentation are also identified

Japanese national reference reprocessing plant

International Nuclear Information System (INIS)

1978-08-01

This paper gives a general description of the proposed Japanese national reprocessing plant and of the design philosophy. The plant is in most respects similar to the base case reprocessing plant, with an annual throughput of 100-1500 tU. The plant would be co-located with a fuel fabrication facility

Silver iodide reduction in aqueous solution: application to iodine enhanced separation during spent nuclear fuels reprocessing

International Nuclear Information System (INIS)

Badie, Jerome

2002-01-01

Silver iodide is a key-compound in nuclear chemistry either in accidental conditions or during the reprocessing of spent nuclear fuel. In that case, the major part of iodine is released in molecular form into the gaseous phase at the time of dissolution in nitric acid. In French reprocessing plants, iodine is trapped in the dissolver off-gas treatment unit by two successive steps: the first consists in absorption by scrubbing with a caustic soda solution and in the second, residual iodine is removed from the gaseous stream before the stack by chemisorption on mineral porous traps made up of beds of amorphous silica or alumina porous balls impregnated with silver nitrate. Reactions of iodine species with the impregnant are assumed to lead to silver iodide and silver iodate. Enhanced separation policy would make necessary to recover iodine from the filters by silver iodide dissolution during a reducing treatment. After a brief silver-iodine chemical bibliographic review, the possible reagents listed in the literature were studied. The choice has been made to use ascorbic acid and hydroxylamine. An experimental work on silver iodide reduction by this two compounds allowed us to determinate reaction products, stoichiometry and kinetics parameters. Finally, the process has been initiated on stable iodine loaded filters samples. (author) [fr

The regulations concerning the reprocessing business of spent fuels

International Nuclear Information System (INIS)

1987-01-01

Regulations specified here cover application for such matters as designation of reprocessing undertaking, permission of construction of reprocessing facilities, permission and approval of alteration (of plan for reprocessing facilities), etc. The regulations also cover application for prior inspection, execution of prior inspection, technical standards concerning performance of reprocessing facilities, certificate of prior inspection, reprocessing facilities subject to welding inspection, application for welding inspection, execution of welding inspection, facilities not subject to welding inspection, approval of welding method, welding inspection for imported equipment, certificate of welding inspection, reprocessing facilities subject to regular inspection, application for regular inspection, technical standards for regular inspection, operation plan, application for approval of joint management, record keeping, restriction on access to areas under management, measures concerning exposure to radioactive rays, patrol and checking in reprocessing facilities, operation of reprocessing facilities, self-imposed regular inspection of reprocessing facilities, transportation within plant or operation premises, storage, waste disposal within plant or operation premises, safety rules, notice of disassembly, measures for emergency, notice of abolition of business, notice of disorganization, measures concerning cancellation of designation, submission of report, etc. (Nogami, K.)

Management of radioactive waste from reprocessing plants

International Nuclear Information System (INIS)

Kanwar Raj

2010-01-01

Reprocessing and recycling of both fissile and fertile components back into appropriate reactor systems is an integral part of three stage nuclear energy programme of India. Different steps involved in processing of spent nuclear fuel (SNF) are decladding, dissolution and recovery of fissile and fertile materials. Reprocessing of SNF is a complex process involving handling of large quantity of radioactive materials and processing chemicals. There are three reprocessing plants in operation in the country at Trombay, Tarapur and Kalpakkam. Out of these plants, Trombay reprocessing plant is engaged in reprocessing of SNF from research reactors and other two plants are processing of SNF from PHWRs. A facility is being built for reprocessing of thorium based spent fuel at BARC, Trombay based on the experience of pilot plant scale. Like other industrial activities of nuclear fuel cycle, fuel reprocessing facilities too generate various types of radioactive waste streams. These are generated in all the three physical forms namely solid, liquid and gas. These waste streams are primarily categorized on the basis of concentration of radionuclides, their half lives and toxicity. Management of these wastes aims at (a) recovery and recycle of useful materials, (b) concentration and confinement of radioactivity in inert and stable matrices, (c) minimization of final waste volume for disposal, (d) decontamination of effluents following ALARA principle and (e) minimization of radioactive discharge to the environment. The present paper outlines the salient features of management of different types of radioactive waste generated in reprocessing plants handling SNF from research reactors and PHWR

Fast reactor fuel reprocessing. An Indian perspective

International Nuclear Information System (INIS)

Natarajan, R.; Raj, Baldev

2005-01-01

The Department of Atomic Energy (DAE) envisioned the introduction of Plutonium fuelled fast reactors as the intermediate stage, between Pressurized Heavy Water Reactors and Thorium-Uranium-233 based reactors for the Indian Nuclear Power Programme. This necessitated the closing of the fast reactor fuel cycle with Plutonium rich fuel. Aiming to develop a Fast Reactor Fuel Reprocessing (FRFR) technology with low out of pile inventory, the DAE, with over four decades of operating experience in Thermal Reactor Fuel Reprocessing (TRFR), had set up at the India Gandhi Center for Atomic Research (IGCAR), Kalpakkam, R and D facilities for fast reactor fuel reprocessing. After two decades of R and D in all the facets, a Pilot Plant for demonstrating FRFR had been set up for reprocessing the FBTR (Fast Breeder Test Reactor) spent mixed carbide fuel. Recently in this plant, mixed carbide fuel with 100 GWd/t burnup fuel with short cooling period had been successfully reprocessed for the first time in the world. All the challenging problems encountered had been successfully overcome. This experience helped in fine tuning the designs of various equipments and processes for the future plants which are under construction and design, namely, the DFRP (Demonstration Fast reactor fuel Reprocessing Plant) and the FRP (Fast reactor fuel Reprocessing Plant). In this paper, a comprehensive review of the experiences in reprocessing the fast reactor fuel of different burnup is presented. Also a brief account of the various developmental activities and strategies for the DFRP and FRP are given. (author)

The importance of nuclear fuel reprocessing

International Nuclear Information System (INIS)

Allday, C.

1977-01-01

The subject is discussed under the following main headings: introduction; world energy requirement; energy conservation and the economics of recycle; environmental considerations and the timescale of reprocessing; and problems associated with reprocessing. It is concluded that reprocessing is essential to the conservation of the world's energy resources and is an environmentally and probably an economically more acceptable option to the 'throw away' alternative. The associated problems of proliferation and terrorism, although of the utmost importance, can and will be solved. (U.K.)

Development of new decladding system in the reprocessing process for FBR fuel

International Nuclear Information System (INIS)

Yamada, Seiya; Washiya, Tadahiro; Takeuchi, Masayuki; Koizumi, Tsutomu; Aose, Shinichi

2005-01-01

As a part of the feasibility study on commercialized fast reactor cycle systems, Japan Nuclear Cycle Development Institute (JNC) has been developing the fuel decladding technology for the dry reprocessing process (oxide electrowinning process) and aqueous reprocessing process. Particularly, in the oxide electrowinning process, the spent fuel should be reduced to powder for quick dissolution in the molten salt at electrolyzer. Therefore, JNC proposes new decladding system with innovative mechanical decladding devices. The decladding system consists of fuel crushing stage, hull separation stage and hull rinsing stage. In the fuel crushing stage, disassembled spent fuel pins are crushed and powdered by mechanical decladding device, then the following stage, the hull and the fuel powder are separated by magnetic separator. Only the fuel powder is fed to the electrolyzer. On the other side, the separated hull is melted by induction heating method, and the small amount of oxide included in the hull fragments is recovered at the hull rinsing stage. The recovered oxide fuel is fed back to the electrolyzer. In this paper, the basic performance of the element equipment that composes this new decladding system will be described. (author)

Reprocessing of spent fuel and public acceptance

International Nuclear Information System (INIS)

Imai, Ryukichi

1977-01-01

The public acceptance has to be considered regarding whole atomic power rather than the reprocessing of nuclear fuel separately, and the problems concerned are as follows; the release of radioactive materials in the normal and abnormal operations of reprocessing plants, the disposal of wastes with high level radioactivity, the transportation of high level radioactive material, the relation to the economic activity near nuclear plants, the environmental effect of 85 Kr. and 3 H, etc., and the physical protection for reprocessing facility itself, the special handling of the materials of very high radioactivity level such as fission products and plutonium, the radiation exposure of operators, and the demonstration of reprocessing techniques of commercial base, etc., as a part of the nuclear fuel cycle, and the relation between atomic power and other technologies in energy supply, the evalution of atomic power as the symbol of huge scale science, and the energy problem within the confrontation of economic development and the preservation of environment and resources regarding whole nuclear energy. The situations of fuel reprocessing in USA, UK, France, Germany and Japan are explained from the viewpoint of the history. The general background for the needs of nuclear energy in Japan, the image of nuclear energy and fuel reprocessing entertained by the general public, and the special feature of reprocessing techniques are described. (Nakai, Y.)

Fast breeder reactor fuel reprocessing in France

International Nuclear Information System (INIS)

Bourgeois, M.; Le Bouhellec, J.; Eymery, R.; Viala, M.

1984-08-01

Simultaneous with the effort on fast breeder reactors launched several years ago in France, equivalent investigations have been conducted on the fuel cycle, and in particular on reprocessing, which is an indispensable operation for this reactor. The Rapsodie experimental reactor was associated with the La Hague reprocessing plant AT1 (1 kg/day), which has reprocessed about one ton of fuel. The fuel from the Phenix demonstration reactor is reprocessed partly at the La Hague UP2 plant and partly at the Marcoule pilot facility, undergoing transformation to reprocess all the fuel (TOR project, 5 t/y). The fuel from the Creys Malville prototype power plant will be reprocessed in a specific plant, which is in the design stage. The preliminary project, named MAR 600 (50 t/y), will mobilize a growing share of the CEA's R and D resources, as the engineering needs of the UP3 ''light water'' plant begins to decline. Nearly 20 tonnes of heavy metals irradiated in fast breeder reactors have been processed in France, 17 of which came from Phenix. The plutonium recovered during this reprocessing allowed the power plant cycle to be closed. This power plant now contains approximately 140 fuel asemblies made up with recycled plutonium, that is, more than 75% of the fuel assemblies in the Phenix core

Reliability engineering analysis of ATLAS data reprocessing campaigns

International Nuclear Information System (INIS)

Vaniachine, A; Golubkov, D; Karpenko, D

2014-01-01

During three years of LHC data taking, the ATLAS collaboration completed three petascale data reprocessing campaigns on the Grid, with up to 2 PB of data being reprocessed every year. In reprocessing on the Grid, failures can occur for a variety of reasons, while Grid heterogeneity makes failures hard to diagnose and repair quickly. As a result, Big Data processing on the Grid must tolerate a continuous stream of failures, errors and faults. While ATLAS fault-tolerance mechanisms improve the reliability of Big Data processing in the Grid, their benefits come at costs and result in delays making the performance prediction difficult. Reliability Engineering provides a framework for fundamental understanding of the Big Data processing on the Grid, which is not a desirable enhancement but a necessary requirement. In ATLAS, cost monitoring and performance prediction became critical for the success of the reprocessing campaigns conducted in preparation for the major physics conferences. In addition, our Reliability Engineering approach supported continuous improvements in data reprocessing throughput during LHC data taking. The throughput doubled in 2011 vs. 2010 reprocessing, then quadrupled in 2012 vs. 2011 reprocessing. We present the Reliability Engineering analysis of ATLAS data reprocessing campaigns providing the foundation needed to scale up the Big Data processing technologies beyond the petascale.

Fast reactor fuel reprocessing development in the United States: an overview

International Nuclear Information System (INIS)

Groenier, W.S.; Burch, W.D.

1979-01-01

As a result of the reduced nuclear power demand and the growing concerns over the potential proliferation of sensitive nuclear materials, there has not been a necessity to make immediate decisions regarding near-term reprocessing and breeder reactor commercialization. Programs which formed the basic thrust of nuclear development in the early 1970's have already been adjusted: increased emphasis on problems of radioactive waste management; increased attention to nonproliferation objectives and subsequent reorientation of the overall fuel cycle and breeder programs; increased emphasis on a once-through light-water reactor technology; increased concern for a more detailed knowledge of the uranium resource base; reorientation of the uranium enrichment programs; and exploration of alternative fuel cycles (such as thorium) to minimize the use of plutonium. Nevertheless, major strategic decisions still loom over breeder commercialization, the breeder's requisite demand for reprocessing, and the future role of more proliferation-resistant nuclear technologies. The current program in the United States is organized to provide the necessary technology for the reprocessing of breeder fuels on a timetable that is consistent with the reactor development and demonstration program. Also addressed in this paper are the present day concerns of environmental protection, safety, nuclear material safeguards, and proliferation resistance. It is structured on the well-known Purex processing method but includes new efforts aimed at advanced and alternative fuels. At the present time, the program consists mainly of a generic effort that is planned to progress through an integrated equipment engineering demonstration to an eventual pilot-plant operation. Each of these facilities is viewed as a test bed for advanced and alternative processing steps to address the many significant technical and political issues. 16 figures

Fast reactor fuel reprocessing in the UK

International Nuclear Information System (INIS)

Allardice, R.H.; Williams, J.; Buck, C.

1977-01-01

Enriched uranium metal fuel irradiated in the Dounreay Fast Reactor has been reprocessed and refabricated in plants specifically designed for the purpose in the U.K. since 1961. Efficient and reliable fuel recycle is essential to the development of a plutonium based fast reactor system and the importance of establishing at an early stage fast reactor fuel reprocessing has been reinforced by current world difficulties in reprocessing high burn-up thermal reactor oxide fuel. In consequence, the U.K. has decided to reprocess irradiated fuel from the 250 MW(E) Prototype Fast Reactor as an integral part of the fast reactor development programme. Flowsheet and equipment development work for the small scale fully active demonstration plant have been carried out over the past 5 years and the plant will be commissioned and ready for active operation during 1977. In parallel, a comprehensive waste management system has been developed and installed. Based on this development work and the information which will arise from active operation of the plant a parallel development programme has been initiated to provide the basis for the design of a large scale fast reactor fuel reprocessing plant to come into operation in the late 1980s to support the projected U.K. fast reactor installation programme. The paper identifies the important differences between fast reactor and thermal reactor fuel reprocessing technologies and describes some of the development work carried out in these areas for the small scale P.F.R. fuel reprocessing operation. In addition, the development programme in aid of the design of a larger scale fast reactor fuel reprocessing plant is outlined and the current design philosophy is discussed

Development, experience and innovation in reprocessing

International Nuclear Information System (INIS)

Delange, M.

1985-01-01

The author describes landmarks in the development of the reprocessing industry in France and then presents objectives for the future (extension of reprocessing of fuel from breeder reactors) together with the technological resources deployed to attain them [fr

Existing reflection seismic data re-processing

International Nuclear Information System (INIS)

Higashinaka, Motonori; Sano, Yukiko; Kozawa, Takeshi

2005-08-01

This document is to report the results of existing seismic data re-processing around Horonobe town, Hokkaido, Japan, which is a part of the Horonobe Underground Research Project. The main purpose of this re-processing is to recognize the subsurface structure of Omagari Fault and fold system around Omagari Fault. The seismic lines for re-processing are TYHR-A3 line and SHRB-2 line, which JAPEX surveyed in 1975. Applying weathering static correction using refraction analysis and noise suppression procedure, we have much enhanced seismic profile. Following information was obtained from seismic re-processing results. TYHR-A3 line: There are strong reflections, dipping to the west. These reflections are corresponding western limb of anticline to the west side of Omagari Fault. SHRB-2 line: There are strong reflections, dipping to the west, at CDP 60-140, while there are reflections, dipping to the east, to the east side of CDP 140. These reflections correspond to the western limb and the eastern limb of the anticline, which is parallel to Omagari FAULT. This seismic re-processing provides some useful information to know the geological structure around Omagari Fault. (author)

The regulations concerning the reprocessing business of spent fuels

International Nuclear Information System (INIS)

1981-01-01

This rule is stipulated under the provisions of reprocessing business in the law concerning regulation of nuclear raw materials, nuclear fuel materials and nuclear reactors and to execute them. Basic terms are defined, such as exposure radiation dose, cumulative dose, control area, security area, surrounding monitoring area, worker, radioactive waste and facility for discharging into the sea. The application for the designation for reprocessing business under the law shall include the maximum reprocessing capacities per day and per year of each kind of spent fuel, to be reprocessed and the location, structure and equipment of reprocessing facilities as specified in the regulation. Records shall be made in each works or enterprise on the inspection, operation and maintenance of reprocessing facilities, radiation control, accidents and weather, and kept for particular periods respectively. Reprocessing enterprisers shall set up control area, security area and surrounding monitoring area to restrict entrance, etc. Specified measures shall be taken by these enterprisers concerning the exposure radiation doses of workers. Reprocessing facilities shall be inspected and examined more than once a day. The regular self-inspection and operation of reprocessing facilities, the transport and storage of nuclear fuel materials, the disposal of radioactive wastes in works or enterprises where reprocessing facilities are located, and security rules are defined in detail, respectively. (Okada, K.)

Lessons Learned in International Safeguards - Implementation of Safeguards at the Rokkasho Reprocessing Plant

International Nuclear Information System (INIS)

Ehinger, Michael H.; Johnson, Shirley

2010-01-01

The focus of this report is lessons learned at the Rokkasho Reprocessing Plant (RRP). However, the subject of lessons learned for application of international safeguards at reprocessing plants includes a cumulative history of inspections starting at the West Valley (New York, U.S.A.) reprocessing plant in 1969 and proceeding through all of the efforts over the years. The RRP is the latest and most challenging application the International Atomic Energy Agency has faced. In many ways the challenges have remained the same, timely inspection and evaluation with limited inspector resources, with the continuing realization that planning and preparations can never start early enough in the life cycle of a facility. Lessons learned over the years have involved the challenges of using ongoing advances in technology and dealing with facilities with increased throughput and continuous operation. This report will begin with a review of historical developments and lessons learned. This will provide a basis for a discussion of the experiences and lessons learned from the implementation of international safeguards at RRP.

New rules set for uranium reprocessing

International Nuclear Information System (INIS)

Anon.

1981-01-01

The Australian Government policy regarding the reprocessing of Australian uranium overseas is outlined. Buyer nations will be required to sign an agreement that the uranium will be reprocessed only for energy uses and that approved waste management standards will be met

Proceedings of GLOBAL 2007 conference on advanced nuclear fuel cycles and systems

International Nuclear Information System (INIS)

2007-01-01

In keeping with the 12-year history of this conference, GLOBAL 2007 focuses on future nuclear energy systems and fuel cycles. With the increasing public acceptance and political endorsement of nuclear energy, it is a pivotal time for nuclear energy research. Significant advances have been made in development of advanced nuclear fuels and materials, reactor designs, partitioning, transmutation and reprocessing technologies, and waste management strategies. In concert with the technological advances, it is more important than ever to develop sensible nuclear proliferation policies, to promote sustainability, and to continue to increase international collaboration. To further these aims, GLOBAL 2007 highlights recent developments in the following areas: advanced integrated fuel cycle concepts, spent nuclear fuel reprocessing, advanced reprocessing technology, advanced fuels and materials, advanced waste management technology, novel concepts for waste disposal and repository development, advanced reactors, partitioning and transmutation, developments in nuclear non-proliferation technology, policy, and implementation, sustainability and expanded global utilization of nuclear energy, and international collaboration on nuclear energy

Commercial Nuclear Reprocessing in the United States

Energy Technology Data Exchange (ETDEWEB)

Sherrill, Charles Leland [Brigham Young Univ., Provo, UT (United States); Balatsky, Galya Ivanovna [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2015-09-09

The short presentation outline: Reprocessing Overview; Events leading up to Carter’s Policy; Results of the decision; Policy since Nuclear Nonproliferation Act. Conclusions reached: Reprocessing ban has become an easy and visible fix to the public concern about proliferation, but has not completely stopped proliferation; and, Reprocessing needs to become detached from political considerations, so technical research can continue, regardless of the policy decisions we decide to take.

Advanced servomanipulator development

International Nuclear Information System (INIS)

Kuban, D.P.

1985-01-01

The Advanced Servomanipulator (ASM) System consists of three major components: the ASM slave, the dual arm master controller (DAMC) or master, and the control system. The ASM is remotely maintainable force-reflecting servomanipulator developed at the Oak Ridge National Laboratory (ORNL) as part of the Consolidated Fuel Reprocessing Program. This new manipulator addresses requirements of advanced nuclear fuel reprocessing with emphasis on force reflection, remote maintainability, reliability, radiation tolerance, and corrosion resistance. The advanced servomanipulator is uniquely subdivided into remotely replaceable modules which will permit in situ manipulator repair by spare module replacement. Manipulator modularization and increased reliability are accomplished through a force transmission system that uses gears and torque tubes. Digital control algorithms and mechanical precision are used to offset the increased backlash, friction, and inertia resulting from the gear drives. This results in the first remotely maintainable force-reflecting servomanipulator in the world

Reprocessing of research reactor fuel the Dounreay option

Energy Technology Data Exchange (ETDEWEB)

Cartwright, P.

1997-08-01

Reprocessing is a proven process for the treatment of spent U/Al Research Reactor fuel. At Dounreay 12679 elements have been reprocessed during the past 30 years. For reactors converting to LEU fuel the uranium recovered in reprocessing can be blended down to less than 20% U{sub 235}, enrichment and be fabricated into new elements. For reactors already converted to LEU it is technically possible to reprocess spent silicide fuel to reduce the U{sub 235} burden and present to a repository only stable conditioned waste. The main waste stream from reprocessing which contains the Fission products is collected in underground storage tanks where it is kept for a period of at least five years before being converted to a stable solid form for return to the country of origin for subsequent storage/disposal. Discharges to the environment from reprocessing are low and are limited to the radioactive gases contained in the spent fuel and a low level liquid waste steam. Both of these discharges are independently monitored, and controlled within strict discharge limits set by the UK Government`s Scottish Office. Transportation of spent fuel to Dounreay has been undertaken using many routes from mainland Europe and has utilised over the past few years both chartered and scheduled vessel services. Several different transport containers have been handled and are currently licensed in the UK. This paper provides a short history of MTR reprocessing at Dounreay, and provides information to show reprocessing can satisfy the needs of MTR operators, showing that reprocessing is a valuable asset in non-proliferation terms, offers a complete solution and is environmentally acceptable.

Power Reactor Fuel Reprocessing Plant-2, Tarapur: a benchmark in Indian PHWR spent fuel reprocessing

International Nuclear Information System (INIS)

Pradhan, Sanjay; Dubey, K.; Qureshi, F.T.; Lokeswar, S.P.

2017-01-01

Power Reactor Fuel Reprocessing Plant-2 (PREFRE-2) is latest operating spent nuclear fuel reprocessing plant in India. This plant has improved design based on latest technology and feedback provided by the earlier plants. The design of PREFRE-2 plant is in five cycles of solvent extraction using TBP as extractant. The plant is commissioned in year 2011 after regulatory clearances

Handbook on process and chemistry on nuclear fuel reprocessing

Energy Technology Data Exchange (ETDEWEB)

Suzuki, Atsuyuki [Tokyo Univ., Tokyo (Japan); Asakura, Toshihide; Adachi, Takeo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; and others

2001-12-01

'Wet-type' nuclear fuel reprocessing technology, based on PUREX technology, has wide applicability as the principal reprocessing technology of the first generation, and relating technologies, waste management for example, are highly developed, too. It is quite important to establish a database summarizing fundamental information about the process and the chemistry of 'wet-type' reprocessing, because it contributes to establish and develop fuel reprocessing process and nuclear fuel cycle treating high burn-up UO{sub 2} fuel and spent MOX fuel, and to utilize 'wet-type' reprocessing technology much widely. This handbook summarizes the fundamental data on process and chemistry, which was collected and examined by 'Editing Committee of Handbook on Process and Chemistry of Nuclear Fuel Reprocessing', from FY 1993 until FY 2000. (author)

Handbook on process and chemistry on nuclear fuel reprocessing

International Nuclear Information System (INIS)

Suzuki, Atsuyuki; Asakura, Toshihide; Adachi, Takeo

2001-12-01

'Wet-type' nuclear fuel reprocessing technology, based on PUREX technology, has wide applicability as the principal reprocessing technology of the first generation, and relating technologies, waste management for example, are highly developed, too. It is quite important to establish a database summarizing fundamental information about the process and the chemistry of 'wet-type' reprocessing, because it contributes to establish and develop fuel reprocessing process and nuclear fuel cycle treating high burn-up UO 2 fuel and spent MOX fuel, and to utilize 'wet-type' reprocessing technology much widely. This handbook summarizes the fundamental data on process and chemistry, which was collected and examined by 'Editing Committee of Handbook on Process and Chemistry of Nuclear Fuel Reprocessing', from FY 1993 until FY 2000. (author)

The regulations concerning the reprocessing business of spent fuels

International Nuclear Information System (INIS)

1980-01-01

The office ordinance is established under the provisions related to reprocessing businesses of the law concerning regulation of nuclear raw materials, nuclear fuel materials and reactors, to enforce the provisions. The basic terms are defined, such as exposure radiation dose; accumulated dose; controlled area; maintenance area; surrounding watch area; employee; radioactive waste; the facilities for discharge to sea. An application for the designation of reprocessing businesses shall be filed, listing the following matters: the maximum daily and yearly reprocessing capacities for each kind of spent fuel; the location and general structure of reprocessing facilities; the structures of buildings; the structure and equipments of main reprocessing facilities, the storage facilities for products and the disposal facilities for radioactive wastes; the equipments of measuring and control system facilities and radiation control facilities, etc. Records shall be made on the inspection of reprocessing facilities, radiation control, operation, maintenance, the accidents of reprocessing facilities and weather, and kept for the period from one to ten years, respectively. Any person engaging in reprocessing businesses shall set up control, maintenance and surrounding watch areas, and take specified measures to restrict the entrance of persons. The measures to be taken against exposure radiation dose, the inspection, regular independent examination and operation of reprocessing facilities and other related matters are stipulated in detail. (Okada, K.)

Consolidated fuel reprocessing program

Science.gov (United States)

1985-04-01

A survey of electrochemical methods applications in fuel reprocessing was completed. A dummy fuel assembly shroud was cut using the remotely operated laser disassembly equipment. Operations and engineering efforts have continued to correct equipment operating, software, and procedural problems experienced during the previous uranium compaigns. Fuel cycle options were examined for the liquid metal reactor fuel cycle. In high temperature gas cooled reactor spent fuel studies, preconceptual designs were completed for the concrete storage cask and open field drywell storage concept. These and other tasks operating under the consolidated fuel reprocessing program are examined.

Fuel reprocessing and waste management

International Nuclear Information System (INIS)

Philippone, R.L.; Kaiser, R.A.

1989-01-01

Because of different economic, social and political factors, there has been a tendency to compartmentalize the commercial nuclear power industry into separate power and fuel cycle operations to a greater degree in some countries compared to other countries. The purpose of this paper is to describe how actions in one part of the industry can affect the other parts and recommend an overall systems engineering approach which incorporates more cooperation and coordination between individual parts of the fuel cycle. Descriptions are given of the fuel cycle segments and examples are presented of how a systems engineering approach has benefitted the fuel cycle. Descriptions of fuel reprocessing methods and the waste forms generated are given. Illustrations are presented describing how reprocessing options affect waste management operations and how waste management decisions affect reprocessing

Chemical analysis used in nuclear fuels reprocessing of uranium and thorium

International Nuclear Information System (INIS)

Schvartzman, M.M.A.M.

1986-01-01

An overall review of the analytical chemistry in nuclear fuel reprocessing is done. In Purex and Thorex process flowsheets, the analyses required to the control of the process, balance and accountability of fissile and fertile materials, and final product specification are pointed out. Some analytical methods applied to the determination of uranium, plutonium, thorium, nitric acid, tributylphosphate and fission products are described. Specific features of the analytical laboratories are presented. The radioactivity level of the samples requires facilities as shielded cells and glove boxes, and handling by remote control. Finally it is reported an application of one analytical method to evaluate thorium content in organic and aqueous solutions, in cold tests of Thorex process. These tests were performed at CDTN/NUCLEBRAS. (author) [pt

Influence of formulation and processing variables on properties of itraconazole nanoparticles made by advanced evaporative precipitation into aqueous solution.

Science.gov (United States)

Bosselmann, Stephanie; Nagao, Masao; Chow, Keat T; Williams, Robert O

2012-09-01

Nanoparticles, of the poorly water-soluble drug, itraconazole (ITZ), were produced by the Advanced Evaporative Precipitation into Aqueous Solution process (Advanced EPAS). This process combines emulsion templating and EPAS processing to provide improved control over the size distribution of precipitated particles. Specifically, oil-in-water emulsions containing the drug and suitable stabilizers are sprayed into a heated aqueous solution to induce precipitation of the drug in form of nanoparticles. The influence of processing parameters (temperature and volume of the heated aqueous solution; type of nozzle) and formulation aspects (stabilizer concentrations; total solid concentrations) on the size of suspended ITZ particles, as determined by laser diffraction, was investigated. Furthermore, freeze-dried ITZ nanoparticles were evaluated regarding their morphology, crystallinity, redispersibility, and dissolution behavior. Results indicate that a robust precipitation process was developed such that size distribution of dispersed nanoparticles was shown to be largely independent across the different processing and formulation parameters. Freeze-drying of colloidal dispersions resulted in micron-sized agglomerates composed of spherical, sub-300-nm particles characterized by reduced crystallinity and high ITZ potencies of up to 94% (w/w). The use of sucrose prevented particle agglomeration and resulted in powders that were readily reconstituted and reached high and sustained supersaturation levels upon dissolution in aqueous media.

Handbook on process and chemistry on nuclear fuel reprocessing

Energy Technology Data Exchange (ETDEWEB)

Suzuki, Atsuyuki (ed.) [Tokyo Univ., Tokyo (Japan); Asakura, Toshihide; Adachi, Takeo (eds.) [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment] [and others

2001-12-01

'Wet-type' nuclear fuel reprocessing technology, based on PUREX technology, has wide applicability as the principal reprocessing technology of the first generation, and relating technologies, waste management for example, are highly developed, too. It is quite important to establish a database summarizing fundamental information about the process and the chemistry of 'wet-type' reprocessing, because it contributes to establish and develop fuel reprocessing process and nuclear fuel cycle treating high burn-up UO{sub 2} fuel and spent MOX fuel, and to utilize 'wet-type' reprocessing technology much widely. This handbook summarizes the fundamental data on process and chemistry, which was collected and examined by 'Editing Committee of Handbook on Process and Chemistry of Nuclear Fuel Reprocessing', from FY 1993 until FY 2000. (author)

Current Status of Spent Fast Reactor Fuel Reprocessing and Waste Treatment in Various Countries: United States of America

International Nuclear Information System (INIS)

2011-01-01

Due to the previous strategic US decision on treating SNF as waste and not pursuing the reprocessing option, development work for the FR fuel cycle was only performed in a few laboratories, although interest is now increasing again. ORNL together with ANL have been influential in promoting the wider use of centrifugal contactors (favoured due to the high fissile content and decay power of FR fuel materials), associated remote handling systems and hardware prototypes for most unit operations in the reprocessing conceptual designs in the context of their development of the Consolidated Fuel Reprocessing Program. There is limited experience with reprocessing tests on the Fast Flux Text Facility (FFTF) MOX fuel. ORNL has undertaken small tests on laboratory scale dissolution and solvent extraction of MOX fuel irradiated to 220 GW/t HM burnup at around 2 kg batch scale [180-186]. The initiative called the breeder reprocessing engineering test (BRET) was started in the 1980s with a focus on the developmental activity of the US DOE to demonstrate breeder fuel reprocessing technology while closing the fuel cycle for the FFTF. The process was supposed to be installed at the existing Fuels and Materials Examination Facility (FMEF) at the Hanford Site, Richland, Washington. The major objectives of BRET were to: - Develop and demonstrate reprocessing technology and systems for breeder fuel; - Close the fuel cycle for the FFTF; - Provide an integrated test of breeder reactor fuel cycle technology - reprocessing, safeguards and waste management. The quest for pyrochemical alternatives to aqueous reprocessing has been under way in the USA since the late 1950s. Approaches examined at various levels of development and for a variety of fuels include alloy melting, FP volatilization and adsorption, fluoride and chloride volatility methods, redox solvent extractions between liquid salt and metal phases, precipitation and fractional crystallization, and electrowinning and electro

Problems of nuclear fuel reprocessing in Japan

International Nuclear Information System (INIS)

Tanaka, Naojiro

1974-01-01

The reprocessing capacity of the plant No. 1 of Power Reactor and Nuclear Fuel Development Corporation, which is scheduled to start operation in fiscal year 1975, will be insufficient after fiscal year 1978 for the estimated demand for reprocessing based on Japanese nuclear energy development program. Taking into consideration the results examined by JAIF's study team to Europe and the U.S., it is necessary that Japan builds 2nd reprocessing plant. But there will be a gap from 1978 to 1984 during which Japan must rely on overseas reprocessing services. The establishment of a reprocessing system is a task of national scale, and there are many problems to be solved before it can be done. These include the problems of site and environment, the problem of treatment and disposal of radioactive wastes, the raising of huge required funds and so on. Therefore, even if a private enterprise is allowed to undertake the task, it will be impossible to achieve the aim without the cooperation and assistance of the government. (Wakatsuki, Y.)

Corrosion control in nuclear fuel reprocessing

International Nuclear Information System (INIS)

Steele, D.F.

1986-01-01

This article looks in detail at tribology-related hazards of corrosion in irradiated fuel reprocessing plants and tries to identify and minimize problems which could contribute to disaster. First, the corrosion process is explained. Then the corrosion aspects at each of four stages in reprocessing are examined, with particular reference to oxide fuel reprocessing. The four stages are fuel receipt and storage, fuel breakdown and dissolution, solvent extraction and product concentration and waste management. Results from laboratory and plant corrosion trails are used at the plant design stage to prevent corrosion problems arising. Operational procedures which minimize corrosion if it cannot be prevented at the design stage, are used. (UK)

Reprocessing input data validation

International Nuclear Information System (INIS)

Persiani, P.J.; Bucher, R.G.; Pond, R.B.; Cornella, R.J.

1990-01-01

The Isotope Correlation Technique (ICT), in conjunction with the gravimetric (Pu/U ratio) method for mass determination, provides an independent verification of the input accountancy at the dissolver or accountancy stage of the reprocessing plant. The Isotope Correlation Technique has been applied to many classes of domestic and international reactor systems (light-water, heavy-water, graphite, and liquid-metal) operating in a variety of modes (power, research, production, and breeder), and for a variety of reprocessing fuel cycle management strategies. Analysis of reprocessing operations data based on isotopic correlations derived for assemblies in a PWR environment and fuel management scheme, yielded differences between the measurement-derived and ICT-derived plutonium mass determinations of (-0.02 ± 0.23)% for the measured U-235 and (+0.50 ± 0.31)% for the measured Pu-239, for a core campaign. The ICT analyses has been implemented for the plutonium isotopics in a depleted uranium assembly in a heavy-water, enriched uranium system and for the uranium isotopes in the fuel assemblies in light-water, highly-enriched systems. 7 refs., 5 figs., 4 tabs

Reprocessing plants safety

International Nuclear Information System (INIS)

Davies, A.G.; Leighton, C.; Millington, D.

1989-01-01

The reprocessing of irradiated nuclear fuel at British Nuclear Fuels (BNFL) Sellafield site consists of a number of relatively self-contained activities carried out in separate plants across the site. The physical conditions and time scales applied in reprocessing and storage make it relatively benign. The potential for minor releases of radioactivity under fault conditioning is minimised by plant design definition of control procedures, training and supervision. The risks to both the general public and workforce are shown to be low with all the safety criteria being met. Normal operating conditions also have the potential for some occupational radiation exposure and the plant and workers are monitored continuously. Exposure levels have been reduced steadily and will continue to fall with plant improvements. (U.K.)

TIGA Tide Gauge Data Reprocessing at GFZ

Science.gov (United States)

Deng, Zhiguo; Schöne, Tilo; Gendt, Gerd

2014-05-01

To analyse the tide gauge measurements for the purpose of global long-term sea level change research a well-defined absolute reference frame is required by oceanographic community. To create such frame the data from a global GNSS network located at or near tide gauges are processed. For analyzing the GNSS data on a preferably continuous basis the International GNSS Service (IGS) Tide Gauge Benchmark Monitoring Working Group (TIGA-WG) is responsible. As one of the TIGA Analysis Centers the German Research Centre for Geosciences (GFZ) is contributing to the IGS TIGA Reprocessing Campaign. The solutions of the TIGA Reprocessing Campaign will also contribute to 2nd IGS Data Reprocessing Campaign with GFZ IGS reprocessing solution. After the first IGS reprocessing finished in 2010 some improvements were implemented into the latest GFZ software version EPOS.P8: reference frame IGb08 based on ITRF2008, antenna calibration igs08.atx, geopotential model (EGM2008), higher-order ionospheric effects, new a priori meteorological model (GPT2), VMF mapping function, and other minor improvements. GPS data of the globally distributed tracking network of 794 stations for the time span from 1994 until end of 2012 are used for the TIGA reprocessing. To handle such large network a new processing strategy is developed and described in detail. In the TIGA reprocessing the GPS@TIGA data are processed in precise point positioning (PPP) mode to clean data using the IGS reprocessing orbit and clock products. To validate the quality of the PPP coordinate results the rates of 80 GPS@TIGA station vertical movement are estimated from the PPP results using Maximum Likelihood Estimation (MLE) method. The rates are compared with the solution of University of LaRochelle Consortium (ULR) (named ULR5). 56 of the 80 stations have a difference of the vertical velocities below 1 mm/yr. The error bars of PPP rates are significant larger than those of ULR5, which indicates large time correlated noise in

Radioactive wastes from reprocessing plants

International Nuclear Information System (INIS)

Huppert, K.L.

1977-01-01

The lecture deals with definition, quantity and type of radioactive waste products occurring in a fuel reprocessing plant. Solid, liquid and gaseous fission and activation products are formed during the dissolution of the fuel and during the extraction process, and they must be separated from the fissionalble uranium and plutonium not spent. The chemical behaviour of these products (Zr, Ru, Np, gaseous substances, radiolysis products), which is sometimes very problematic, necessitates careful process control. However, the lifetime of nuclides is just as important for the conditions of the reprocessing procedure. The types of waste obtained after reprocessing are classified according to their state of aggregation and level of activity and - on the basis of the operational data of a prototype plant - they are quantitatively extrapolated for the operation of a large-scale facility of 1,400 tons of fuel annually. (RB) [de

Advances in technologies for the treatment of low and intermediate level radioactive liquid wastes

International Nuclear Information System (INIS)

1994-01-01

In recent years the authorized maximum limits for radioactive discharges into the environment have been reduced considerably, and this, together with the requirement to minimize the volume of waste for storage or disposal and to declassify some wastes from intermediate to low level or to non-radioactive wastes, has initiated studies of ways in which improvements can be made to existing decontamination processes and also to the development of new processes. This work has led to the use of more specific precipitants and to the establishment of ion exchange treatment and evaporation techniques. Additionally, the use of combinations of some existing processes or of an existing process with a new technique such as membrane filtration is becoming current practice. New biotechnological, solvent extraction and electrochemical methods are being examined and have been proven at laboratory scale to be useful for radioactive liquid waste treatment. In this report an attempt has been made to review the current research and development of mature and advanced technologies for the treatment of low and intermediate level radioactive liquid wastes, both aqueous and non-aqueous. Non-aqueous radioactive liquid wastes or organic liquid wastes typically consist of oils, reprocessing solvents, scintillation liquids and organic cleaning products. A brief state of the art of existing processes and their application is followed by the review of advances in technologies, covering chemical, physical and biological processes. 213 refs, 33 figs, 3 tabs

Base case industrial reprocessing plant

International Nuclear Information System (INIS)

1978-11-01

This paper briefly describes an industrial scale plant for reprocessing thermal oxide fuel. This description was used as a base case by the Group for their later assessments and for comparing actual national plans for reprocessing plants. The plant described uses the Purex process and assumes an annual throughput of 1000 t/U. The maintenance, safety and safeguards philosophy is described. An indication of the construction schedule and capital and operating costs is also given

Fast-reactor fuel reprocessing in the United Kingdom

International Nuclear Information System (INIS)

Allardice, R.H.; Buck, C.; Williams, J.

1977-01-01

Enriched uranium metal fuel irradiated in the Dounreay Fast Reactor has been reprocessed and refabricated in plants specifically designed for the purpose in the United Kingdom since 1961. Efficient and reliable fuel recycle is essential to the development of a plutonium-based fast-reactor system, and the importance of establishing at an early stage fast-reactor fuel reprocessing has been reinforced by current world difficulties in reprocessing high-burnup thermal-reactor oxide fuel. The United Kingdom therefore decided to reprocess irradiated fuel from the 250MW(e) Prototype Fast Reactor (PFR) as an integral part of the fast reactor development programme. Flowsheet and equipment development work for the small-scale fully active demonstration plant has been carried out since 1972, and the plant will be commissioned and ready for active operation during 1977. In parallel, a comprehensive waste-management system has been developed and installed. Based on this development work and the information which will arise from active operation of the plant, a parallel development programme has been initiated to provide the basis for the design of a large-scale fast-reactor fuel-reprocessing plant to come into operation in the late 1980s to support the projected UK fast-reactor installation programme. The paper identifies the important differences between fast-reactor and thermal-reactor fuel-reprocessing technologies and describes some of the development work carried out in these areas for the small-scale PFR fuel-reprocessing operation. In addition, the development programme in aid of the design of a larger scale fast-reactor fuel-reprocessing plant is outlined and the current design philosophy discussed. (author)

Structural damage and chemical contaminants on reprocessed arthroscopic shaver blades.

Science.gov (United States)

Kobayashi, Masahiko; Nakagawa, Yasuaki; Okamoto, Yukihiro; Nakamura, Shinichiro; Nakamura, Takashi

2009-02-01

In response to socioeconomic pressure to cut budgets in medicine, single-use surgical instruments are often reprocessed despite potential biological hazard. To evaluate the quality and contaminants of reprocessed shaver blades. Reprocessed shaver blades have mechanical damage and chemical contamination. Controlled laboratory study. Seven blades and 3 abraders were reprocessed 1 time or 3 times and then were assessed. In the first part of the study, structural damage on the blades after 3 reprocessings was compared to that after 1 reprocessing using optical microscopy. In the second part, surface damage was observed using optical microscopy and scanning electron microscopy; elemental and chemical analyses of contaminants found by the microscopy were performed using scanning electron microscopy/energy dispersive x-ray spectroscopy, scanning Auger microscopy, and Fourier transform infrared spectroscopy. Optical microscopic examination revealed abrasion on the surface of the inner blade and cracks on the inner tube after 1 reprocessing. These changes were more evident after 3 reprocessings. Scanning electron microscopy/energy dispersive x-ray spectroscopy of the inner cutter of the blade reprocessed once showed contaminants containing calcium, carbon, oxygen, and silicon, and Fourier transform infrared spectroscopy demonstrated biological protein consisting mainly of collagen, some type of salts, and polycarbonate used in plastic molding. Scanning electron microscopy/energy dispersive x-ray spectroscopy of the inner cutter of the reprocessed abrader revealed contaminants containing carbon, calcium, phosphorous, and oxygen, and Fourier transform infrared spectroscopy showed H2O, hydroxyapatite, and hydroxyl proteins. Scanning Auger microscopy showed that the tin-nickel plating on the moving blade and abrader was missing in some locations. This is the first study to evaluate both mechanical damage and chemical contaminants containing collagen, hydroxyapatite, and salts

Alternate extractants to tributyl phosphate for reactor fuel reprocessing

International Nuclear Information System (INIS)

Crouse, D.J.; Arnold, W.D.; Hurst, F.J.

1983-01-01

Both tri(n-hexyl) phosphate (THP) and tri(2-ethylhexyl) phosphate (TEHP) have some important potential process advantages over TBP for reactor fuel reprocessing. These include negligible aqueous phase solubility and less tendency toward third phase and crud formation. The alkyl chain branching of TEHP makes it much more stable to chemical degradation than TBP and probably also accounts for its much weaker ruthenium extraction. The higher uranium and plutonium extraction power of THP and TEHP allows higher solvent loadings in extraction but makes them somewhat more difficult to strip. The phase separation properties of 1.09 M solutions of THP and TEHP are inferior to those of 1.09 M TBP (30 vol %) but are favorable at lower concentrations. Use of more dilute THP and TEHP solutions is recommended for this reason and to obtain a better balance of extraction power in the extraction versus stripping steps

Review of thorium fuel reprocessing experience

International Nuclear Information System (INIS)

Brooksbank, R.E.; McDuffee, W.T.; Rainey, R.H.

1978-01-01

The review reveals that experience in the reprocessing of irradiated thorium materials is limited. Plants that have processed thorium-based fuels were not optimized for the operations. Previous demonstrations of several viable flowsheets provide a sound technological base for the development of optimum reprocessing methods and facilities. In addition to the resource benefit by using thorium, recent nonproliferation thrusts have rejuvenated an interest in thorium reprocessing. Extensive radiation is generated as the result of 232 U-contamination produced in the 233 U, resulting in the remote operation and fabrication operations and increased fuel cycle costs. Development of the denatured thorium flowsheet, which is currently of interest because of nonproliferation concerns, represents a difficult technological challenge

Discharges from a fast reactor reprocessing plant

International Nuclear Information System (INIS)

Barnes, D.S.

1987-01-01

The purpose of this paper is to assess the environmental impact of the calculated routine discharges from a fast reactor fuel reprocessing plant. These assessments have been carried out during the early stages of an evolving in-depth study which culminated in the design for a European demonstration reprocessing plant (EDRP). This plant would be capable of reprocessing irradiated fuel from a series of European fast reactors. Cost-benefit analysis has then been used to assess whether further reductions in the currently predicted routine discharges would be economically justified

Fuel reprocessing and environmental problem

International Nuclear Information System (INIS)

Ichikawa, Ryushi

1977-01-01

The radioactive nuclides which are released from the reprocessing plants of nuclear fuel are 137 Cs, 106 Ru, 95 Zr and 3 H in waste water and 85 Kr in the atmosphere. This release affects the environment for example, the reprocessing plant of the Nuclear Fuel Service Co in the USA releases about 2 x 10 5 Ci/y of 85 Kr, which is evaluated as about 0.025 mr/y as external exposure dose. The radioactivity in milk around this plant was measured as less than 10 pCi/lit of 129sup(I. The radioactive concentration in the sea, especially in fish and shellfish, was measured near the reprocessing plant of Windscale in UK. The radioactive release rate from this plants more than 10)5sup( Ci/y as the total amount of )137sup(Cs, )3sup(H, )106sup(Ru, )95sup(Zr, )95sup(Nb, )90sup(Sr, )144sup(Ce, etc., and the radioactivity in seaweeds near Windscale is about 400 pCi/g as the maximum value, and the mayonnaise which was made of this seaweeds contained about 1 pCi/g of )106sup(Ru, which is estimated as about 7 mr/y for the digestive organ if 100 g is eaten every day. On the other hand, the experimental result is presented for the reprocessing plant of La Hague in France, in which the radioactive release rate from this plant is about 10)4sup( Ci/y, and the radioactivity in sea water and shellfish is about 4 pCi/l of )106sup(Ru and about 400 pCi/kg of )137 Cs, respectively, near this plant. The philosophy of ALAP (as low as practicable) is also applied to reprocessing plants. (Nakai, Y.)

Effect of repeated tracheostomy tube reprocessing on biofilm formation.

Science.gov (United States)

Rodney, Jennifer; Ojano-Dirain, Carolyn P; Antonelli, Patrick J; Silva, Rodrigo C

2016-04-01

To determine the effect of repeated reprocessing of pediatric tracheostomy tubes (TTs) on biofilm formation. In vitro microbiological study. Pediatric, uncuffed, polyvinyl chloride (PVC) TTs from two different manufacturers (Tracoe Mini and Shiley) were reprocessed mechanically with household detergent and soaked in sodium hypochlorite (bleach). Two TTs of each brand were reprocessed 0 (control), 10, or 20 times. Twenty 2-mm coupons were then obtained from each TT, immersed in human mucus, and cultured with either Staphylococcus aureus or Pseudomonas aeruginosa. Biofilm formation was evaluated with bacterial counts. Bacterial counts of S. aureus for both brands were significantly higher on the TTs that were reprocessed 20 times compared to those that were not reprocessed (Tracoe: P = .040, Shiley: P  attachment. Further investigation is needed to determine the optimal technique and limits of reprocessing TTs in clinical practice. NA. Laryngoscope published by Wiley on behalf of the American Laryngological, Rhinological and Otological Society, Inc, “The Triological Society” and American Laryngological Association (the “Owner”).

Status and prospects for reprocessing

International Nuclear Information System (INIS)

Rossney, G.K.

1977-01-01

Following the formation of United Reprocessors (U.R.G.) in 1976 by British Nuclear Fuels Limited (B.N.F.L.) in the United Kingdom, the Commissariat a l'Energie Atomique (C.E.A.) in France and K.E.W.A. Kernbrennstoff-Wiederaufarbeitungs-Gesellschaft MBH (K.E.W.A.) in Germany, collaboration is now well established for the marketing of their reprocessing services for irradiated oxide fuel from thermal reactors. In addition collaboration in the continued evolution of the technology has progressed and an extensive research and development programme has been established, the results of which are exchanged between the shareholders. During 1976 the U.K. Government has given approval to B.N.F.L. to sign further contracts with foreign customers, subject to certain conditions. In France, the fuel cycle activities of the C.E.A. have been vested in a new company (Compagnie Generale Des Matieres Nucleaires (C.O.G.E.M.A.)) and their La Hague plant has commenced reprocessing operations on irradiated oxide fuel. In Germany, an agreement has been signed between K.E.W.A. and P.W.K. for the pre-project study for the proposed German plant. Against this background this paper reviews the present status of reprocessing by the shareholders of U.R.G. and the prospects for reprocessing

Improved annular centrifugal contactor for solvent extraction reprocessing of nuclear reactor fuel

International Nuclear Information System (INIS)

Bernstein, G.J.; Leonard, R.A.; Ziegler, A.A.; Steindler, M.J.

1978-01-01

An improved annular centrifugal contactor has been developed for solvent extraction reprocessing of spent nuclear reactor fuel. The design is an extension of a contactor developed several years ago at Argonne National Laboratory. Its distinguishing features are high throughput, high stage efficiency and the ability to handle a broad range of aqueous-to-organic phase flow ratios and density ratios. Direct coupling of the mixing and separating rotor to a motorized spindle simplifies the design and makes the contactor particularly suitable for remote maintenance. A unit that is critically safe by geometry is under test and a larger unit is being fabricated. Multi-stage miniature contactors operating on the annular mixing principle are being used for laboratory flow sheet studies. 8 figures

Reprocessing of nuclear fuels - status report

International Nuclear Information System (INIS)

Schueller, W.

1976-01-01

The paper gives a survey on reprocessing plants at present under construction, in operation, and planned, as well as on the most important process steps such as receipt, storage, conversion, the extraction process, purification of the end products, gaseous waste treatment and waste treatment, and repair and maintenance of reprocessing plants. An outline on operational experience with WAK follows. (HR/LN) [de

Analysis and study of spent fuel reprocessing technology from birth to present

International Nuclear Information System (INIS)

Takahashi, Keizo

2006-01-01

As for the nuclear fuel reprocessing of the spent fuel, although there was argument of pros and cons, it was decided to start Rokkasho reprocessing project further at the Japan Atomic Energy Commission of ''Long-Term Program for Research, Development and Utilization of Nuclear Energy'' in year 2004. The operation of Tokai Reprocessing is going steadily to reprocess spent fuel more than 1,100 tons. In this paper, history, present status and future of reprocessing technology is discussed focusing from military Pu production, Magnox fuel reprocessing to oxide fuel reprocessing. Amount of reprocessed fuel are estimated based on fuel type. Then, history of reprocessing, US, UK, France, Germany, Russian, Belgian and Japan is presented and compared on technology, national character, development organization, environmental protection, and high active waste vitrification. Technical requirements are increased from Pu production fuel, Magnox fuel and oxide fuel mainly because of higher burnup. Reprocessing technology is synthetic of engineering and accumulation of operational experience. The lessons learned from the operational experience of the world will be helpful for establishment of nuclear fuel reprocessing technology in Japan. (author)

Removal efficiency of silver impregnated filter materials and performance of iodie filters in the off-gas of the Karlsruhe reprocessing plant WAK

International Nuclear Information System (INIS)

Herrmann, F.J.; Herrmann, B.; Hoeflich, V.

1997-01-01

An almost quantitative retention of iodine is required in reprocessing plants. For the iodine removal in the off-gas streams of a reprocessing plant various sorption materials had been tested under realistic conditions in the Karlsruhe reprocessing plant WAK in cooperation with the Karlsruhe research center FZK. The laboratory results achieved with different iodine sorption materials justified long time performance tests in the WAK Plant. Technical iodine filters and sorption materials for measurements of iodine had been tested from 1972 through 1992. This paper gives an overview over the most important results, Extended laboratory, pilot plant, hot cell and plant experiences have been performed concerning the behavior and the distribution of iodine-129 in chemical processing plants. In a conventional reprocessing plant for power reactor fuel, the bulk of iodine-129 and iodine-127 is evolved into the dissolver off-gas. The remainder is dispersed over many aqueous, organic and gaseous process and waste streams of the plant. Iodine filters with silver nitrate impregnated silica were installed in the dissolver off-gas of the Karlsruhe reprocessing plant WAK in 1975 and in two vessel vent systems in 1988. The aim of the Karlsruhe iodine research program was an almost quantitative evolution of the iodine during the dissolution process to remove as much iodine with the solid bed filters as possible. After shut down of the WAK plant in December 1990 the removal efficiency of the iodine filters at low iodine concentrations had been investigated during the following years. 12 refs., 2 figs., 2 tabs

Removal efficiency of silver impregnated filter materials and performance of iodie filters in the off-gas of the Karlsruhe reprocessing plant WAK

Energy Technology Data Exchange (ETDEWEB)

Herrmann, F.J.; Herrmann, B.; Hoeflich, V. [Wiederaufarbeitungsanlage Karlsruhe (Germany)] [and others

1997-08-01

An almost quantitative retention of iodine is required in reprocessing plants. For the iodine removal in the off-gas streams of a reprocessing plant various sorption materials had been tested under realistic conditions in the Karlsruhe reprocessing plant WAK in cooperation with the Karlsruhe research center FZK. The laboratory results achieved with different iodine sorption materials justified long time performance tests in the WAK Plant. Technical iodine filters and sorption materials for measurements of iodine had been tested from 1972 through 1992. This paper gives an overview over the most important results, Extended laboratory, pilot plant, hot cell and plant experiences have been performed concerning the behavior and the distribution of iodine-129 in chemical processing plants. In a conventional reprocessing plant for power reactor fuel, the bulk of iodine-129 and iodine-127 is evolved into the dissolver off-gas. The remainder is dispersed over many aqueous, organic and gaseous process and waste streams of the plant. Iodine filters with silver nitrate impregnated silica were installed in the dissolver off-gas of the Karlsruhe reprocessing plant WAK in 1975 and in two vessel vent systems in 1988. The aim of the Karlsruhe iodine research program was an almost quantitative evolution of the iodine during the dissolution process to remove as much iodine with the solid bed filters as possible. After shut down of the WAK plant in December 1990 the removal efficiency of the iodine filters at low iodine concentrations had been investigated during the following years. 12 refs., 2 figs., 2 tabs.

Predicting the behaviour or neptunium during nuclear fuel reprocessing

International Nuclear Information System (INIS)

Drake, V.A.

1988-01-01

Behaviour of Np and its distribution over reprocessing flowsheet is studied due to the necessity of improvement of reprocessing methods of wastes formed during purex-process. Valency states of Np in solutions of reprocessing cycles, Np distribution in organic and acid phases, Np(5) oxidation by nitric acid at the stage of extraction, effect of U and Pu presence on Np behaviour, are considered. Calculation and experimental data are compared; the possibility of Np behaviour forecasting in the process of nuclear fuel reprocessing, provided initial data vay, is shown. 7 refs.; 4 figs.; 1 tab

Separation of tritium from aqueous effluents

International Nuclear Information System (INIS)

Geens, L.; Bruggeman, A.; Meynendonckx, L.; Parmentier, C.; Belien, H.; Ooms, E.; Smets, D.; Stevens, J.; van Vlerken, J.

1988-01-01

From 1975 until 1982 - within the framework of the CEC indirect action programme on management and storage of radioactive waste - the SCK/CEN has developed the ELEX process from laboratory scale experiments up to the construction of an integrated pilot installation. The ELEX process combines water electrolysis and catalytical isotope exchange for the separation of tritium from aqueous reprocessing effluents by isotope enrichment. Consequently, the pilot installation consists of two main parts: an 80 kW water electrolyser and a 10 cm diameter trickle bed exchange column. The feed rate of tritiated water amounts to 5 dm 3 .h -1 , containing up to 3.7 GBq.dm -3 of tritium. This report describes the further development of the process during the second phase of the second programme. Three main items are reported: (i) research work in the field of pretreatment of real reprocessing effluents, before feeding them to an ELEX installation; (ii) demonstration of the technical feasibility of the ELEX process with simulated active effluent streams in the pilot installation; (iii) a cost estimation for the ELEX installation, comprising the required investments and the annual operation costs

Safety guide data on radiation shielding in a reprocessing facility

International Nuclear Information System (INIS)

Sekiguchi, Noboru; Naito, Yoshitaka

1986-04-01

In a reprocessing facility, various radiation sources are handled and have many geometrical conditions. To aim drawing up a safety guidebook on radiation shielding in order to evaluate shielding safety in a reprocessing facility with high reliability and reasonableness, JAERI trusted investigation on safety evaluation techniques of radiation shielding in a reprocessing facility to Nuclear Safety Research Association. This report is the collection of investigation results, and describes concept of shielding safety design principle, radiation sources in reprocessing facility and estimation of its strength, techniques of shielding calculations, and definite examples of shielding calculation in reprocessing facility. (author)

Reprocessed and combined thorium fuel cycles in a PER system with a micro heterogeneous approaches

International Nuclear Information System (INIS)

Monteiro, Fabiana B.A.; Castro, Victor F.; Faria, Rochkhudson B. de; Pereira, Claubia; Fortini, Angela

2015-01-01

A micro heterogeneous approaches were used to study the behavior of reprocessed fuel spiked with thorium in a PWR fuel element considering (TRU-Th) cycle. The goal is to achieve a higher burnup using three different configurations to model the fuel element using SCALE 6.0. The reprocessed fuels were obtained using the ORIGEN 2.1 code from a spent PWR standard fuel (33,000 MWd/tHM burned), with 3.1% of initial enrichment. The spent fuel remained in the cooling pool for five years and then reprocessed using the UREX+ technique. Three configurations of micro heterogeneous approaches were analyzed, and the k inf and plutonium evolution during the burnup were evaluated. The preliminary results show that the behavior of advanced fuel based on transuranic elements spiked with thorium, and micro heterogeneous approach are satisfactory in PWRs, and the configuration that use a combination of Th and TRU (configuration 1) seems to be the most promising once has higher values for k inf during the burnup, compared with other configurations. (author)

The regulations concerning the reprocessing business of spent fuels

International Nuclear Information System (INIS)

1979-01-01

The regulations are defined under provisions concerning the reprocessing business in the law for the regulations of nuclear source materials, nuclear fuel materials and reactors. The basic concepts and terms are explained, such as: exposure dose; accumulative dose; controlled area; safeguarded area; inspected surrounding area; employee; radioactive waste and marine discharging facilities. Any person who gets permission for design of reprocessing facilities and method of the construction shall file an application, listing name and address of the person and the works or the place of enterprise where reprocessing facilities are to be set up, design of such facilities and method of the construction, in and out-put chart of nuclear fuel materials in reprocessing course, etc. Records shall be made and kept for particularly periods in each works or enterprise on inspection of reprocessing facilities, control of dose, operation, maintenance, accident of reprocessing facilities and weather. Detailed prescriptions are settled on entrance limitation to controlled area, exposure dose, inspection and check, regular independent examination and operation of reprocessing facilities, transportation in the works or the enterprise, storage, disposal, safeguard and measures in dangerous situations, etc. Reports shall be filed on exposure dose of employees and other specified matters in the forms attached and in the case otherwise defined. (Okada, K.)

Transport and reprocessing of irradiated nuclear fuel

International Nuclear Information System (INIS)

Lenail, B.

1981-01-01

This contribution deals with transport and packaging of oxide fuel from and to the Cogema reprocessing plant at La Hague (France). After a general discussion of nuclear fuel and the fuel cycle, the main aspects of transport and reprocessing of oxide fuel are analysed. (Auth.)

Refurbishment of the BNFL Magnox reprocessing plant

International Nuclear Information System (INIS)

Carr, V.M.; Edgar, R.

1998-01-01

The Magnox Reprocessing Plant was commissioned in 1964. Since then it has reprocessed more than 35,000 t of irradiated uranium metal fuel. The plant is subject to routine shutdowns to allow maintenance and project work to be undertaken. During the 1997 shutdown the opportunity was taken to replace several life limiting parts of the plant to ensure Magnox reprocessing capability well beyond the year 2010. This shutdown was the largest and most complex undertaken by Magnox Reprocessing, with a total committed value of 130 million UK pounds, 17.5 million UK pounds committed in the shutdown itself and the balance on installation, design and procurement preparing for the shutdown. The work was completed within safety targets, to programme and within budget. The lessons learned and experience gained have been fed into the methodologies and procedures for planning future project and shutdown work within BNFL. This report is part of the output from this process of continually improving performance. (author)

Methodology for evaluation of alternative technologies applied to nuclear fuel reprocessing

International Nuclear Information System (INIS)

Selvaduray, G.S.; Goldstein, M.K.; Anderson, R.N.

1977-07-01

An analytic methodology has been developed to compare the performance of various nuclear fuel reprocessing techniques for advanced fuel cycle applications including low proliferation risk systems. The need to identify and to compare those processes, which have the versatility to handle the variety of fuel types expected to be in use in the next century, is becoming increasingly imperative. This methodology allows processes in any stage of development to be compared and to assess the effect of changing external conditions on the process

The 4th technological meeting of Tokai Reprocessing Plant

International Nuclear Information System (INIS)

Ohnishi, Tohru; Maki, Akira; Shibata, Satomi; Yatogi, Hideo; Nyui, Daisuke; Hashimoto, Takakazu; Fukuda, Kazuhito; Ohzeki, Tatsuya

2001-11-01

''The 4th technological meeting of Tokai Reprocessing Plant (TRP)'' was held in JNFL Rokkasho site on October 11 th , 2001. The report contains the proceedings, transparencies and questionnaires of the meeting. This time, we reported about ''Maintenance and repair results of Tokai Reprocessing Plant'' based on technology and knowledge accumulated in Tokai Reprocessing Plant. (author)

EOS Data Products Latency and Reprocessing Evaluation

Science.gov (United States)

Ramapriyan, H. K.; Wanchoo, L.

2012-12-01

NASA's Earth Observing System (EOS) Data and Information System (EOSDIS) program has been processing, archiving, and distributing EOS data since the launch of Terra platform in 1999. The EOSDIS Distributed Active Archive Centers (DAACs) and Science-Investigator-led Processing Systems (SIPSs) are generating over 5000 unique products with a daily average volume of 1.7 Petabytes. Initially EOSDIS had requirements to make process data products within 24 hours of receiving all inputs needed for generating them. Thus, generally, the latency would be slightly over 24 and 48 hours after satellite data acquisition, respectively, for Level 1 and Level 2 products. Due to budgetary constraints these requirements were relaxed, with the requirement being to avoid a growing backlog of unprocessed data. However, the data providers have been generating these products in as timely a manner as possible. The reduction in costs of computing hardware has helped considerably. It is of interest to analyze the actual latencies achieved over the past several years in processing and inserting the data products into the EOSDIS archives for the users to support various scientific studies such as land processes, oceanography, hydrology, atmospheric science, cryospheric science, etc. The instrument science teams have continuously evaluated the data products since the launches of EOS satellites and improved the science algorithms to provide high quality products. Data providers have periodically reprocessed the previously acquired data with these improved algorithms. The reprocessing campaigns run for an extended time period in parallel with forward processing, since all data starting from the beginning of the mission need to be reprocessed. Each reprocessing activity involves more data than the previous reprocessing. The historical record of the reprocessing times would be of interest to future missions, especially those involving large volumes of data and/or computational loads due to

Reprocessing RTR fuel in the La Hague plants

International Nuclear Information System (INIS)

Thomasson, J.; Drain, F.; David, A.

2001-01-01

Starting in 2006, research reactors operators will be fully responsible for the back-end management of their spent fuel. It appears that the only solution for this management is treatment-conditioning, which could be done at the La Hague reprocessing complex in France. The fissile material can be separated in the reprocessing plants and the final waste can be encapsulated in a matrix adapted to its potential hazards. RTR reprocessing at La Hague would require some modifications, since the plant had been primarily designed to reprocess fuel from light water reactors. Many provisions have been taken at the plant design stage, however, and the modifications would be feasible even during active operations, as was done from 1993 to 1995 when a new liquid waste management was implemented, and when one of the two vitrification facilities was improved. To achieve RTR back-end management, COGEMA and its partners are also conducting R and D to define a new generation of LEU fuel with performance characteristics approximating those of HEU fuel. This new-generation fuel would be easier to reprocess. (author)

Reprocessing RTR fuel in the La Hague plants

Energy Technology Data Exchange (ETDEWEB)

Thomasson, J. [Cogema, F-78140 Velizy (France); Drain, F.; David, A. [SGN, F-78182 Saint Quentin en Yvelines (France)

2001-07-01

Starting in 2006, research reactors operators will be fully responsible for the back-end management of their spent fuel. It appears that the only solution for this management is treatment-conditioning, which could be done at the La Hague reprocessing complex in France. The fissile material can be separated in the reprocessing plants and the final waste can be encapsulated in a matrix adapted to its potential hazards. RTR reprocessing at La Hague would require some modifications, since the plant had been primarily designed to reprocess fuel from light water reactors. Many provisions have been taken at the plant design stage, however, and the modifications would be feasible even during active operations, as was done from 1993 to 1995 when a new liquid waste management was implemented, and when one of the two vitrification facilities was improved. To achieve RTR back-end management, COGEMA and its partners are also conducting R and D to define a new generation of LEU fuel with performance characteristics approximating those of HEU fuel. This new-generation fuel would be easier to reprocess. (author)

Reprocessing RTR fuel in the La Hague plants

Energy Technology Data Exchange (ETDEWEB)

Thomasson, J. [Cogema, 78 - Velizy Villacoublay (France); Drain, F.; David, A. [SGN, 78 - Saint Quentin en Yveline (France)

2001-07-01

Starting in 2006, research reactors operators will be fully responsible for their research and testing reactors spent fuel back-end management. It appears that the only solution for this management is treatment-conditioning, which could be done at the La Hague reprocessing complex in France. The fissile material can be separated in the reprocessing plants and the final waste can be encapsulated in a matrix adapted to its potential hazards. RTR reprocessing at La Hague would require some modifications, since the plant had been primarily designed to reprocess fuel from light water reactors. Many provisions have been taken at the plant design stage, however, and the modifications would be feasible even during active operations, as was done from 1993 to 1995 when a new liquid waste management was implemented, and when one of the two vitrification facilities was improved. To achieve RTR back-end management, COGEMA and its partners are also conducting R and D to define a new generation of LEU fuel with performance characteristics approximating those of HEU fuel. This new-generation fuel would be easier to reprocess. (author)

Spent fuel reprocessing past experience and future prospects

International Nuclear Information System (INIS)

Megy, J.

1983-09-01

A large experience has been gathered from the early fifties till now in the field of spent fuel reprocessing. As the main efforts in the world have been made for developping the reactors and the fuel fabrication industry to feed them, the spent fuel reprocessing activities came later and have not yet reached the industrial maturity existing to day for plants such as PWRs. But in the principal nuclear countries spent fuel reprocessing is to day considered as a necessity with two simultaneous targets: 1. Recovering the valuable materials, uranium and plutonium. 2. Conditionning the radioactive wastes to ensure safe definitive storage. The paper reviews the main steps: 1. Reprocessing for thermal reactor fuels: large plants are already operating or in construction, but in parallel a large effort of R and D is still under way for improvements. 2. The development of fast breeder plants implies associated fuel reprocessing facilities: pilot plants have demonstrated the closing of the cycle. The main difficulties encountered will be examined and particularly the importance of taking into account the problems of effluents processing and wastes storage [fr

Aerosols released from solvent fire accidents in reprocessing plants

International Nuclear Information System (INIS)

Jordan, S.; Lindner, W.

1985-01-01

Thermodynamic, aerosol characterizing and radiological data of solvent fires in reprocessing plants have been established in experiments. These are the main results: Depending on the ventilation in the containment, kerosene-TBP mixtures burn at a rate up to 120 kg/m 2 h. The aqueous phase of inorganic-organic mixtures might be released during the fire. The gaseous reaction products contain unburnable acidic compounds. Solvents with TBP-nitrate complex shows higher (up to 25%) burning rates than pure solvents (kerosene-TBP). The nitrate complex decomposes violently at about 130 0 C with a release of acid and unburnable gases. Up to 20% of the burned kerosene-TBP solvents are released during the fire in the form of soot particles, phosphoric acid and TBP decomposition products. The particles have an aerodynamic mass median diameter of about 0.5 μm and up to 1.5% of the uranium fixed in the TBP-nitrate complex is released during solvent fires. (orig.)

Fuel reprocessing at a loss to prove its justification

International Nuclear Information System (INIS)

Traube, K.

1986-01-01

Commercial utilization of nuclear energy is possible with or without fuel reprocessing of spent fuel elements. Demands on terminal storage are about equal in both cases. There is no reason - excluding the military one - to decide in favour of fuel reprocessing instead of direct terminal storage, for neither does fuel reprocessing offer advantages in regard of the safety of nuclear waste disposal, nor is it necessary to produce plutonium for the breeder reactor. Fuel reprocessing is analyzed considering those changed aspects with a view to scarcer uranium resources, juridical motives, and what is termed the development deficit. (DG) [de

Development of Tokai reprocessing plant maintenance support system (TORMASS) in the Tokai reprocessing plant

International Nuclear Information System (INIS)

Shimizu, Kazuyuki; Tomita, Tsuneo; Sakai, Katsumi

2008-01-01

The maintenance work of many equipments such as mechanical, electrical and instrumentations installed in Tokai reprocessing plant has been performed more then 10,000 times per year and about 90% of maintenances were preventive work. For the maintenance management, optimization of maintenance information is required. Therefore, Tokai Reprocessing Plant Maintenance Support System (TORMASS) was developed from 1985 to 1992 as the aim of construction for suitable maintenance management system. About 24,000 equipments of specifications and about 261,000 maintenance detail were registered in this system. TORMASS has been used for the repair, inspection and replacement of equipment since 1992. (author)

Overview of technologies to reprocess ion-exchange resins

International Nuclear Information System (INIS)

Gavrish, V.M.; Chernikova, N.P.; Ivanets, V.G.

2010-01-01

The article deals with overview of technologies for reprocessing of ion-exchange resins and determining the most optimal solutions for Ukraine. The technologies for cementations, thermal reprocessing, bituminization and deep decontamination are considered.

Optimization of the sizes and dates of starting up of reprocessing plants

International Nuclear Information System (INIS)

Nagashima, Kikusaburo

1977-01-01

It is desirable to complete the nuclear fuel cycle domestically for promoting nuclear power generation in Japan, and the reprocessing of spent fuel is indispensable. However, the capacity of the reprocessing plant in PNC and the reprocessing by the commissioning to foreign countries will be insufficient by the latter half of 1980s. In the planning of the second reprocessing plant in Japan, the following problems remain yet to be solved. The international regulation and the laws in Japan regarding the storage and transport of spent fuel, the disposal of radioactive wastes, and the recycling of plutonium must be established. The consensus of the public on the necessity and the safety of fuel reprocessing must be obtained. The technical investigation about fuel reprocessing and related business must be carried out sufficiently, including the necessity of introducing the technology from abroad. The economy and various conditions for industrializing fuel reprocessing must be studied. The economy of fuel reprocessing plants, the reprocessing cost taking escalation into account, mean reprocessing cost, the optimization of the time of starting full operation and the time of starting-up, the rise of reprocessing cost due to the escalation of operational cost are explained. Numerical calculation was carried out about the second reprocessing plant in Japan, and the results are examined. (Kako, I.)

Used mixed oxide fuel reprocessing at RT-1 plant

Energy Technology Data Exchange (ETDEWEB)

Kolupaev, D.; Logunov, M.; Mashkin, A.; Bugrov, K.; Korchenkin, K. [FSUE PA ' Mayak' , 30, Lenins str, Ozersk, 460065 (Russian Federation); Shadrin, A.; Dvoeglazov, K. [ITCP ' PRORYV' , 2/8 Malaya Krasmoselskay str, Moscow, 107140 (Russian Federation)

2016-07-01

Reprocessing of the mixed uranium-plutonium spent nuclear fuel of the BN-600 reactor was performed at the RT-1 plant twice, in 2012 and 2014. In total, 8 fuel assemblies with a burn-up from 73 to 89 GW day/t and the cooling time from 17 to 21 years were reprocessed. The reprocessing included the stages of dissolution, clarification, extraction separation of U and Pu with purification from the fission products, refining of uranium and plutonium at the relevant refining cycles. Dissolution of the fuel composition of MOX used nuclear fuel (UNF) in nitric acid solutions in the presence of fluoride ion has occurred with the full transfer of actinides into solution. Due to the high content of Pu extraction separation of U and Pu was carried out on a nuclear-safe equipment designed for the reprocessing of highly enriched U spent nuclear fuel and Pu refining. Technological processes of extraction, separation and refining of actinides proceeded without deviations from the normal mode. The output flow of the extraction outlets in their compositions corresponded to the regulatory norms and remained at the level of the compositions of the streams resulting from the reprocessing of fuel types typical for the RT-1 plant. No increased losses of Pu into waste have been registered during the reprocessing of BN-600 MOX UNF an compare with VVER-440 uranium UNF reprocessing. (authors)

The recycling of reprocessed uranium

International Nuclear Information System (INIS)

Lannegrace, J.-P.

1991-01-01

The 1990 update to the Uranium Institute's report ''Uranium Market Issues'', presented to this Symposium last year (1990) stated that the impact of recycled reprocessing products on uranium demand would be limited in the near future to that due to MOX fuel fabrication. The report stated that the recycling of reprocessed uranium was still at an early discussion stage, rather than being a short-term prospect. This paper will set out to challenge this assertion, on the basis both of facts and of economic and environmental incentives. (author)

Spent fuel reprocessing system availability definition by process simulation

International Nuclear Information System (INIS)

Holder, N.; Haldy, B.B.; Jonzen, M.

1978-05-01

To examine nuclear fuel reprocessing plant operating parameters such as maintainability, reliability, availability, equipment redundancy, and surge storage requirements and their effect on plant throughput, a computer simulation model of integrated HTGR fuel reprocessing plant operations is being developed at General Atomic Company (GA). The simulation methodology and the status of the computer programming completed on reprocessing head end systems is reported

Capability of minor nuclide confinement in fuel reprocessing

International Nuclear Information System (INIS)

Fujine, Sachio; Uchiyama, Gunzo; Mineo, Hideaki; Kihara, Takehiro; Asakura, Toshihide

1999-01-01

Experiment with spent fuels has started with the small scale reprocessing facility in NUCEF-BECKY αγ cell. Primary purpose of the experiment is to study the capability of long-lived nuclide confinement both in the PUREX flow sheet applied to the large scale reprocessing plant and also in the PARC (Partitioning Conundrum key process) flow sheet which is our proposal as a simplified reprocessing of one cycle extraction system. Our interests in the experiment are the behaviors of minor long-lived nuclides and the behaviors of the heterogeneous substances, such as sedimentation in the dissolver, organic cruds in the extraction banks. The significance of those behaviors will be assessed from the standpoint of the process safety of reprocessing for high burn-up fuels and MOX fuels. (author)

Microchemical chip technology and nuclear energy. To develop new analytical system for process control in reprocessing plant

International Nuclear Information System (INIS)

Tokeshi, Manabu; Ikeda, Yasuhisa; Kitamori, Takehiko

2006-01-01

A feasibility study for two years has been done to apply micro-chemical chip technology to nuclear fuel reprocessing plant. Desktop-sized thermal lens microscope (DT-TLM) combined with integrated glass ship was examined in order to find a rapid and sensitive analytical method. A laser-beam is split into two beams, one as the reference while the other to be absorbed in a small quantity of sample solution in a cell with short optical-path length. The solution, on absorbing laser photons, increases in temperature accompanied with change in refractive index, which can be detected by using thermal lens microscope. After examinations of Co-complexes in the presence of 10 -6 M Cu ions by using micro chip-extraction behavior from aqueous phase to chloroform organic phase, and of U(VI) solutions in 3M nitric acid with added 8-quinolinol and others to develop optical density at absorbing wavelength, the author concluded that the system may be applicable for the practical analysis of U(VI) and H + in the spent fuel reprocessing plant. (S. Ohno)

Fuel reprocessing experience in India: Technological and economic considerations

International Nuclear Information System (INIS)

Prasad, A.N.; Kumar, S.V.

1983-01-01

The approach to the reprocessing of irradiated fuel from power reactors in India is conditioned by the non-availability of highly enriched uranium with the consequent need for plutonium for the fast-reactor programme. With this in view, the fuel reprocessing programme in India is developing in stages matching the nuclear power programme. The first plant was set up in Trombay to reprocess the metallic uranium fuel from the research reactor CIRUS. The experience gained in the construction and operation of this plant, and in its subsequent decommissioning and reconstruction, has not only provided the know-how for the design of subsequent plants but has indicated the fruitful areas of research and development for efficient utilization of limited resources. The Trombay plant also handled successfully, on a pilot scale, the reprocessing of irradiated thorium fuel to separate uranium-233. The second plant at Tarapur has been built for reprocessing spent fuels from the power reactors at Tarapur (BWR) and Rajasthan (PHWR). The third plant, at present under design, will reprocess the spent fuels from the power reactors (PHWR) and the Fast Breeder Test Reactor (FBTR) located at Kalpakkam. Through the above approach experience has been acquired which will be useful in the design and construction of even larger plants which will become necessary in the future as the nuclear power programme grows. The strategies considered for the sizing and siting of reprocessing plants extend from the idea of small plants, located at nuclear power station sites, to a large-size central plant, located at an independent site, serving many stations. The paper discusses briefly the experience in reprocessing uranium and thorium fuels and also in decommissioning. An attempt is made to outline the technological and economic aspects which are relevant under different circumstances and which influence the size and siting of the fuel reprocessing plants and the expected lead times for construction

Iodine-129 in the environment of a nuclear fuel reprocessing plant by neutron activation analysis

International Nuclear Information System (INIS)

Anderson, T.J.

1978-01-01

129 I has been analyzed in both aqueous and soil samples to characterize the environmental impact of the Savannah River Plant (SRP) reprocessing operations. 129 I was quantified by a neutron activation procedure with γ-ray spectrometric detection [Ge(Li)]. For many samples, natural iodine ( 127 I) was also quantified. A wide range of samples can be accommodated by a combustion-based preirradiation isolation technique. 129 I amounts as low as 3.8 fCi can be determined with counting times of less than 30 minutes (s/sub rel/ = 10%). Deposition of 129 I in the environment via aqueous and airborne emissions has been studied. Data from analysis of seepage basin contents, spring water, on-plant streams, and the Savannah River show that 129 I from the seepage basins migrates easily through the soil with the groundwater, eventually reaching the Savannah River. Annual aqueous release rates were estimated to be 16 to 27 mCi/year. Data from analysis of soils from distances up to 159 km from SRP show above background levels of 129 I in both the minimum and maximum airborne transport directions. The soil results are compared with a wind dispersion model. The vertical distribution of 129 I in the soil was determined to a depth of 61 cm

EURATOM safeguards. Safeguards verifications in reprocessing plants

International Nuclear Information System (INIS)

Heppleston, M.

1999-01-01

This paper provides a brief historical view of the legal basis for EURATOM. The specific application of safeguards to large scale reprocessing plants, from the theoretical model to the practical application of inspection is considered. The challenge to adequately safeguard major commercial reprocessing facilities has led to many novel approaches being developed. These lessons will also benefit other safeguard projects as a result. Good cooperation between the operator and regulator is essential for the satisfactory installation of adequate safeguard controls. The use of modern data processing technology combined with other diverse monitoring techniques has shown that a major industrial scale reprocessing plant can be controlled under international safeguards to provide a high level of assurance [ru

Innovative Separations Technologies

International Nuclear Information System (INIS)

Tripp, J.; Soelberg, N.; Wigeland, R.

2011-01-01

Reprocessing used nuclear fuel (UNF) is a multi-faceted problem involving chemistry, material properties, and engineering. Technology options are available to meet a variety of processing goals. A decision about which reprocessing method is best depends significantly on the process attributes considered to be a priority. New methods of reprocessing that could provide advantages over the aqueous Plutonium Uranium Reduction Extraction (PUREX) and Uranium Extraction + (UREX+) processes, electrochemical, and other approaches are under investigation in the Fuel Cycle Research and Development (FCR and D) Separations Campaign. In an attempt to develop a revolutionary approach to UNF recycle that may have more favorable characteristics than existing technologies, five innovative separations projects have been initiated. These include: (1) Nitrogen Trifluoride for UNF Processing; (2) Reactive Fluoride Gas (SF6) for UNF Processing; (3) Dry Head-end Nitration Processing; (4) Chlorination Processing of UNF; and (5) Enhanced Oxidation/Chlorination Processing of UNF. This report provides a description of the proposed processes, explores how they fit into the Modified Open Cycle (MOC) and Full Recycle (FR) fuel cycles, and identifies performance differences when compared to 'reference' advanced aqueous and fluoride volatility separations cases. To be able to highlight the key changes to the reference case, general background on advanced aqueous solvent extraction, advanced oxidative processes (e.g., volumetric oxidation, or 'voloxidation,' which is high temperature reaction of oxide UNF with oxygen, or modified using other oxidizing and reducing gases), and fluorination and chlorination processes is provided.

Innovative Separations Technologies

Energy Technology Data Exchange (ETDEWEB)

J. Tripp; N. Soelberg; R. Wigeland

2011-05-01

Reprocessing used nuclear fuel (UNF) is a multi-faceted problem involving chemistry, material properties, and engineering. Technology options are available to meet a variety of processing goals. A decision about which reprocessing method is best depends significantly on the process attributes considered to be a priority. New methods of reprocessing that could provide advantages over the aqueous Plutonium Uranium Reduction Extraction (PUREX) and Uranium Extraction + (UREX+) processes, electrochemical, and other approaches are under investigation in the Fuel Cycle Research and Development (FCR&D) Separations Campaign. In an attempt to develop a revolutionary approach to UNF recycle that may have more favorable characteristics than existing technologies, five innovative separations projects have been initiated. These include: (1) Nitrogen Trifluoride for UNF Processing; (2) Reactive Fluoride Gas (SF6) for UNF Processing; (3) Dry Head-end Nitration Processing; (4) Chlorination Processing of UNF; and (5) Enhanced Oxidation/Chlorination Processing of UNF. This report provides a description of the proposed processes, explores how they fit into the Modified Open Cycle (MOC) and Full Recycle (FR) fuel cycles, and identifies performance differences when compared to 'reference' advanced aqueous and fluoride volatility separations cases. To be able to highlight the key changes to the reference case, general background on advanced aqueous solvent extraction, advanced oxidative processes (e.g., volumetric oxidation, or 'voloxidation,' which is high temperature reaction of oxide UNF with oxygen, or modified using other oxidizing and reducing gases), and fluorination and chlorination processes is provided.

Legal questions concerning the termination of spent fuel element reprocessing

International Nuclear Information System (INIS)

John, Michele

2005-01-01

The thesis on legal aspects of the terminated spent fuel reprocessing in Germany is based on the legislation, jurisdiction and literature until January 2004. The five chapters cover the following topics: description of the problem; reprocessing of spent fuel elements in foreign countries - practical and legal aspects; operators' responsibilities according to the atomic law with respect to the reprocessing of Geman spent fuel elements in foreign countries; compatibility of the prohibition of Geman spent fuel element reprocessing in foreign countries with international law, European law and German constitutional law; results of the evaluation

Combined orbits and clocks from IGS second reprocessing

Science.gov (United States)

Griffiths, Jake

2018-05-01

The Analysis Centers (ACs) of the International GNSS Service (IGS) have reprocessed a large global network of GPS tracking data from 1994.0 until 2014.0 or later. Each AC product time series was extended uniformly till early 2015 using their weekly operational IGS contributions so that the complete combined product set covers GPS weeks 730 through 1831. Three ACs also included GLONASS data from as early as 2002 but that was insufficient to permit combined GLONASS products. The reprocessed terrestrial frame combination procedures and results have been reported already, and those were incorporated into the ITRF2014 multi-technique global frame released in 2016. This paper describes the orbit and clock submissions and their multi-AC combinations and assessments. These were released to users in early 2017 in time for the adoption of IGS14 for generating the operational IGS products. While the reprocessing goal was to enable homogeneous modeling, consistent with the current operational procedures, to be applied retrospectively to the full history of observation data in order to achieve a more suitable reference for geophysical studies, that objective has only been partially achieved. Ongoing AC analysis changes and a lack of full participation limit the consistency and precision of the finished IG2 products. Quantitative internal measures indicate that the reprocessed orbits are somewhat less precise than current operational orbits or even the later orbits from the first IGS reprocessing campaign. That is even more apparent for the clocks where a lack of robust AC participation means that it was only possible to form combined 5-min clocks but not the 30-s satellite clocks published operationally. Therefore, retrospective precise point positioning solutions by users are not recommended using the orbits and clocks. Nevertheless, the orbits do support long-term stable user solutions when used with network processing with either double differencing or explicit clock

International and institutional aspects of reprocessing and plutonium management

International Nuclear Information System (INIS)

1978-09-01

Various institutional alternatives applicable to reprocessing, plutonium management and recycle are considered, not as a definitive analysis but rather as a basis for identifying the institutional approaches and measures which the Working Group might wish to examine more thoroughly. Seven alternatives arrangements for reprocessing are presented. These range from suspending the operation of existing reprocessing plants through placing national facilities under safeguards to limiting reprocessing to a few large facilities subject to plutonium management, multinational or international control. Finally, the comprehensive alternative of an International Nuclear Fuel Authority with worldwide responsibility for reprocessing and plutonium management is considered. Plutonium management alternatives to complement the reprocessing options, are then outlined. These include national discretion on the separation and disposition of plutonium under safeguards, an agreed Code of Practice for plutonium management at national facilities and the international storage of plutonium. The advantages and disadvantages of the alternative are discussed tentatively. It is recognised that the alternatives are presented in a simplified form and that their elements can be combined or separated in many ways. Although strengthening the institutions relating to the peaceful uses of nuclear energy is imperative and can contribute to non-proliferation, such arrangements might open other proliferation risks through the spread of sensitive materials, facilities and technology. While there are risks with any fuel cycle, where plutonium in quantity is separated these risks are of a high order. Although these can be mitigated, they will have to be set against the energy and economic case for reprocessing and alternatives other than plutonium considered

Inventory estimation for nuclear fuel reprocessing systems

International Nuclear Information System (INIS)

Beyerlein, A.L.; Geldard, J.F.

1987-01-01

The accuracy of nuclear material accounting methods for nuclear fuel reprocessing facilities is limited by nuclear material inventory variations in the solvent extraction contactors, which affect the separation and purification of uranium and plutonium. Since in-line methods for measuring contactor inventory are not available, simple inventory estimation models are being developed for mixer-settler contactors operating at steady state with a view toward improving the accuracy of nuclear material accounting methods for reprocessing facilities. The authors investigated the following items: (1) improvements in the utility of the inventory estimation models, (2) extension of improvements to inventory estimation for transient nonsteady-state conditions during, for example, process upset or throughput variations, and (3) development of simple inventory estimation models for reprocessing systems using pulsed columns

Wastes from fuel reprocessing

International Nuclear Information System (INIS)

Eschrich, H.

1976-01-01

Handling, treatment, and interim storage of radioactive waste, problems confronted with during the reprocessing of spent fuel elements from LWR's according to the Purex-type process, are dealt with in detail. (HR/LN) [de

Effectiveness of reprocessing for flexible bronchoscopes and endobronchial ultrasound bronchoscopes.

Science.gov (United States)

Ofstead, Cori L; Quick, Mariah R; Wetzler, Harry P; Eiland, John E; Heymann, Otis L; Sonetti, David A; Ferguson, J Scott

2018-05-30

Infections have been linked to inadequately-reprocessed flexible bronchoscopes, and recent investigations determined that pathogen transmission occurred even when bronchoscope cleaning and disinfection practices aligned with current guidelines. This multisite, prospective study evaluated the effectiveness of real-world bronchoscope reprocessing methods using a systematic approach. This study involved direct observation of reprocessing methods for flexible bronchoscopes, multifaceted evaluations performed after manual cleaning and after high-level disinfection, and assessments of storage conditions. Visual inspections of ports and channels were performed using lighted magnification and borescopes. Contamination was detected using microbial cultures and tests for protein, hemoglobin, and adenosine triphosphate. Researchers assessed reprocessing practices, and storage cabinet cleanliness was evaluated by visual inspection and adenosine triphosphate tests. Researchers examined 24 clinically used bronchoscopes. After manual cleaning, 100% of bronchoscopes had residual contamination. Microbial growth was found in 14 (58%) fully-reprocessed bronchoscopes, including mold, Stenotrophomonas maltophilia, and Escherichia coli/Shigella spp. Visible irregularities were observed in 100% of bronchoscopes, including retained fluid; brown, red, or oily residue; scratches; damaged insertion tubes and distal ends; and filamentous debris in channels. Reprocessing practices were substandard at two of three sites. Damaged and contaminated bronchoscopes were in use at all sites. Inadequate reprocessing practices may have contributed to bioburden found on bronchoscopes. However, even when guidelines were followed, high-level disinfection was not effective. A shift toward the use of sterilized bronchoscopes is recommended. In the meantime, quality management programs and updated reprocessing guidelines are needed. Copyright © 2018. Published by Elsevier Inc.

Application of electrochemical techniques in fuel reprocessing- an overview

Energy Technology Data Exchange (ETDEWEB)

Rao, M K; Bajpai, D D; Singh, R K [Power Reactor Fuel Reprocessing Plant, Tarapur (India)

1994-06-01

The operating experience and development work over the past several years have considerably improved the wet chemical fuel reprocessing PUREX process and have brought the reprocessing to a stage where it is ready to adopt the introduction of electrochemical technology. Electrochemical processes offer advantages like simplification of reprocessing operation, improved performance of the plant and reduction in waste volume. At Power Reactor Fuel Reprocessing plant, Tarapur, work on development and application of electrochemical processes has been carried out in stages. To achieve plant scale application of these developments, a new electrochemical cycle is being added to PUREX process at PREFRE. This paper describes the electrochemical and membrane cell development activities carried out at PREFRE and their current status. (author). 5 refs., 4 tabs.

Reprocessing yields and material throughput: HTGR recycle demonstration facility

International Nuclear Information System (INIS)

Holder, N.; Abraham, L.

1977-08-01

Recovery and reuse of residual U-235 and bred U-233 from the HTGR thorium-uranium fuel cycle will contribute significantly to HTGR fuel cycle economics and to uranium resource conservation. The Thorium Utilization National Program Plan for HTGR Fuel Recycle Development includes the demonstration, on a production scale, of reprocessing and refabrication processes in an HTGR Recycle Demonstration Facility (HRDF). This report addresses process yields and material throughput that may be typically expected in the reprocessing of highly enriched uranium fuels in the HRDF. Material flows will serve as guidance in conceptual design of the reprocessing portion of the HRDF. In addition, uranium loss projections, particle breakage limits, and decontamination factor requirements are identified to serve as guidance to the HTGR fuel reprocessing development program

Reprocessing business in the UK

Energy Technology Data Exchange (ETDEWEB)

Wilkinson, W L

1985-01-01

The development of the process for separating uranium, plutonium and fission products from irradiated fuel began in Britain in late 1940s, and the first separation plant was operated at Sellafield in 1952. This plant was operated very well for more than 12 years with the overall availability over 95%. The second separation plant to meet the needs of the growing nuclear power program became operational in 1964. This plant has been extremely successful, but the significant improvement was made to extend the operating life of the key items. In mid 1970s, by the introduction of uranium oxide fuel reactors, significant reprocessing capacity became to be required. Therefore, it was decided to embark upon the development of a thermal oxide reprocessing plant (THORP) to complement the existing facilities at Sellafield. The THORP is a very large complex of plants. The first duty for the THORP is to reprocess 6,000 t U of oxide fuel in 10 years. But the plant is designed for the life of 25 years. The plant has the capacity of 1200 tes/year. The scope covered by the THORP, the plant processes and the wastes produced from the THORP are described. (Kako, I.).

Spectrophotometric determination of zirconium with Chrome Azurol s in aqueous streams of nuclear fuel reprocessing

International Nuclear Information System (INIS)

Ganesh, S.; Velavendan, P.; Pandey, N.K.; Kamachi Mudali, U.; Natarajan, R.

2014-01-01

A sensitive and reproducible spectrophotometric method for the determination of zirconium is developed. The method is based on the formation of stable bluish violet colour complex with Chrome Azurol S (CAS) with maximum absorption at 598 nm. The complex formed obeys Beer's law in the range of 1-7 μg/mL. Under optimum conditions, the sensitivity of the proposed method, (i.e. the detection limit), molar absorptivity and Sandell's sensitivity values are 2.42 μg/mL, 3.93 x10 3 L.Mol -1 .cm -1 and 2.54 x 10 -4 μg/cm 2 respectively. Relative standard deviation is less than 2% and correlation coefficient is 0.997. The present method is highly sensitive, selective, rapid and simple. It can be applied for the direct determination of zirconium in environmental, industrial, water and nuclear reprocessing samples. (author)

Thermal decomposition studies of aqueous and nitric solutions of hydroxyurea

International Nuclear Information System (INIS)

Shekhar Kumar; Pranay Kumar Sinha; Kamachi Mudali, U.; Natarajan, R.

2012-01-01

Hydroxyurea and its derivatives are important nonsalt forming reductants in partitioning of uranium and plutonium in the nuclear fuel reprocessing operations. There is no experimental data available in open literature describing pressurization due to the thermal decomposition of aqueous and nitric solutions of hydroxyurea at elevated temperatures. Authors studied thermal decomposition of hydroxyurea-nitric acid system and resultant pressurization at various concentrations of nitric acid in an adiabatic calorimeter in closed-vent conditions. During these experiments, pressurization was observed. In this paper, results of these experiments have been discussed. (author)

The aqueous chemistry of oxides

CERN Document Server

Bunker, Bruce C

2016-01-01

The Aqueous Chemistry of Oxides is a comprehensive reference volume and special topics textbook that explores all of the major chemical reactions that take place between oxides and aqueous solutions. The book highlights the enormous impact that oxide-water reactions have in advanced technologies, materials science, geochemistry, and environmental science.

Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, Task 17208: Final report

Energy Technology Data Exchange (ETDEWEB)

Amoroso, J. W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Marra, J. C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2015-08-26

A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics) over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).

Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, task 17208: Final report

Energy Technology Data Exchange (ETDEWEB)

Amoroso, J. W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Marra, J. C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2015-08-26

A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics) over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).

Reliability Engineering Analysis of ATLAS Data Reprocessing Campaigns

CERN Document Server

Vaniachine, A; The ATLAS collaboration; Karpenko, D

2013-01-01

During three years of LHC data taking, the ATLAS collaboration completed three petascale data reprocessing campaigns on the Grid, with up to 2 PB of data being reprocessed every year. In reprocessing on the Grid, failures can occur for a variety of reasons, while Grid heterogeneity makes failures hard to diagnose and repair quickly. As a result, Big Data processing on the Grid must tolerate a continuous stream of failures, errors and faults. While ATLAS fault-tolerance mechanisms improve the reliability of Big Data processing in the Grid, their benefits come at costs and result in delays making the performance prediction difficult. Reliability Engineering provides a framework for fundamental understanding of the Big Data processing on the Grid, which is not a desirable enhancement but a necessary requirement. In ATLAS, cost monitoring and performance prediction became critical for the success of the reprocessing campaigns conducted in preparation for the major physics conferences. In addition, our Reliability...

Reliability Engineering Analysis of ATLAS Data Reprocessing Campaigns

CERN Document Server

Vaniachine, A; The ATLAS collaboration; Karpenko, D

2014-01-01

During three years of LHC data taking, the ATLAS collaboration completed three petascale data reprocessing campaigns on the Grid, with up to 2 PB of data being reprocessed every year. In reprocessing on the Grid, failures can occur for a variety of reasons, while Grid heterogeneity makes failures hard to diagnose and repair quickly. As a result, Big Data processing on the Grid must tolerate a continuous stream of failures, errors and faults. While ATLAS fault-tolerance mechanisms improve the reliability of Big Data processing in the Grid, their benefits come at costs and result in delays making the performance prediction difficult. Reliability Engineering provides a framework for fundamental understanding of the Big Data processing on the Grid, which is not a desirable enhancement but a necessary requirement. In ATLAS, cost monitoring and performance prediction became critical for the success of the reprocessing campaigns conducted in preparation for the major physics conferences. In addition, our Reliability...

Critical experiment needs and plans of the consolidated fuel reprocessing program

International Nuclear Information System (INIS)

Primm, R.T.

1984-01-01

An integral part of the United States Department of Energy (DOE) plan for the development of breeder reactors is the development of the capability for fuel reprocessing. The Consolidated Fuel Reprocessing Program (CFRP) was established by the DOE to identify and conduct research and development activities in this area. The DOE is currently proposing that a capability to reprocess fast reactor fuel be established in the Fuels and Materials Examination Facility at the Hanford Engineering Development Laboratory. This capability would include conversion of plutonium nitrate to plutonium oxide. The reprocessing line is designated the Breeder Reprocessing Engineering Test (BRET). Criticality safety remains an important critetion in the design of the BRET. The different steps in the reprocessing are reviewed and areas where additional critical experiments are needed have been indentified as also areas where revision or clarification of existing criticality safety standards are desirable

Simulation of nuclear fuel reprocessing for safeguards

International Nuclear Information System (INIS)

Canty, M.J.; Dayem, H.A.; Kern, E.A.; Spannagel, G.

1983-11-01

For safeguarding the chemical process area of future reprocessing plants the near-real-time material accountancy (NRTMA) method might be applied. Experimental data are not yet available for testing the capability of the NRTMA method but can be simulated using a digital computer. This report describes the mathematical modeling of the Pu-bearing components of reprocessing plants and presents first results obtained by simulation models. (orig.) [de

French experience and prospects in the reprocessing of fast breeder reactor fuels

International Nuclear Information System (INIS)

Megy, J.

1983-06-01

Experience acquired in France in the field of reprocessing spent fuels from fast breeder reactors is recalled. Emphasis is put on characteristics and quantities of spent fuels reprocessed in La Hague and Marcoule facilities. Then reprocessing developments with the realisation of the new pilot plant TOR at Marcoule, new equipments and study of industrial reprocessing units are reviewed [fr

Evaluation on maintenance technology developed in Tokai Reprocessing Plant

International Nuclear Information System (INIS)

Yamamura, Osamu

2008-01-01

Tokai reprocessing plant (TRP) has been processing 1,140 tons of spent fuels, including 29tons of Fugen MOX fuels, since the beginning of its active operation in Sept.1977. For 30 years operation of TRP, many technological problems have been overcome to obtain the stable and reliable operation. This knowledge of maintenance technology could contribute to the safety and stable operation of Rokkasho reprocessing plant (RRP), as well as to the design and construction of the next reprocessing plant. (author)

ERDA activities related to reprocessing and plutonium recycle

International Nuclear Information System (INIS)

Spurgeon, D.R.

1977-01-01

ERDA has redirected its program in support of the LWR fuel cycle from one emphasizing the commercialization of existing fuel cycle technology to a broader based assessment of alternative fuel cycle concepts with the emphasis on safeguardability and avoidance of proliferation risks. As part of this program, ERDA will evaluate a number of possible technical and institutional options to reduce proliferation risks. ERDA will continue its current program of LWR fuel reprocessing R and D with added emphasis on improved safeguards capability as well as the applicability of conventional reprocessing technology to large multinational plants. These activities and supporting design studies will provide the basis for a decision regarding the design of an optimized system for the management of spent LWR fuel. Such a system would provide a model for the development of future domestic and foreign facilities and programs. A recently completed ERDA study of the benefits of LWR reprocessing and recycle would also be expected to be factored into such a decision. The study concluded that based on currently available data, recycle of uranium and plutonium in LWR's is attractive from the standpoint of economics and resource utilization relative to the discarding of spent fuel. The LWR reprocessing/recycle picture today is clouded by several unresolved policy issues. These include the need for adequate spent fuel storage capacity for both domestic and foreign reactors; the possibility of foreign reprocessing of U.S. produced fuel; the possibility of the disposal of foreign fuel in the U.S.; the possible need to dispose of wastes generated by multinational reprocessing plants; and finally, determination of the optimum balance between recycling recovered plutonium and saving it for the breeder

Occupational dose at Rokkasho reprocessing plant (RRP)

International Nuclear Information System (INIS)

Takashima, F.; Taguchi, R.; Kano, M.; Moriyama, T.; Ogaki, K.; Noda, K.

2008-01-01

In Japan, Rokkasho Reprocessing Plant (RRP) is going to start the operation in service as the first large-scale commercial reprocessing plant of spent fuels that has annual reprocessing quantity of 800tU pr in maximum. The occupational external exposure is controlled for the purpose of keeping dose as low as reasonably achievable, and it is monitored by the personal dosimeter. On the other hand, the occupational internal exposure is controlled for the purpose of preventing, and it is monitored by the periodical evaluation of internal dose from the radioactive concentration in air of workplace. The individual doses of radiation workers are less than the dose limits in the statute and our lower management values enough. Dose data will be stored continuously and the rational management method will be examined. (author)

Determination of free acid in highly concentrated organic and aqueous solutions of plutonium (IV) and uranium (VI) nitrate

International Nuclear Information System (INIS)

Wagner, J.F.; Lacour, J.L.

1989-01-01

Free acidity is an important parameter in the nuclear reprocessing control. The accuracy on the determination of free acidity is not really required in the nuclear reprocessing control itself but is necessary for certain types of analysis such as spectrophotometry (Pu (VI), Am (III),...), density determinations. A new titripotentiometric method for free acidity determination in concentrated U(VI) and Pu(IV) solutions is presented. This method is based on the complexing properties of dipicolinic acid (pyridine 2.6 dicarboxylic acid) and medium effect with H 2 O/DMSO mixture. This method can be used either in organic or aqueous phases with ratio /H + I/ metal ≥ 5.10 -2 and a relative standard deviation of 1%

Nuclear fuel cycle: (5) reprocessing of irradiated fuel

Energy Technology Data Exchange (ETDEWEB)

Williams, J.A.

1977-09-01

The evolution of the reprocessing of irradiated fuel and the recovery of plutonium from it is traced out, starting by following the Manhatten project up to the present time. A brief description of the plant and processes used for reprocessing is given, while the Purex process, which is used in all plants today, is given special attention. Some of the important safety problems of reprocessing plants are considered, together with the solutions which have been adopted. Some examples of the more important safety aspects are the control of activity, criticality control, and the environmental impact. The related topic of irradiated fuel transport is briefly discussed.

Summary of nuclear fuel reprocessing activities around the world

International Nuclear Information System (INIS)

Mellinger, P.J.; Harmon, K.M.; Lakey, L.T.

1984-11-01

This review of international practices for nuclear fuel reprocessing was prepared to provide a nontechnical summary of the current status of nuclear fuel reprocessing activities around the world. The sources of information are widely varied

Irradiated uranium reprocessing

International Nuclear Information System (INIS)

Gal, I.

1961-12-01

Task concerned with reprocessing of irradiated uranium covered the following activities: implementing the method and constructing the cell for uranium dissolving; implementing the procedure for extraction of uranium, plutonium and fission products from radioactive uranium solutions; studying the possibilities for using inorganic ion exchangers and adsorbers for separation of U, Pu and fission products

Future of the reprocessing business at the RT-1 plant

International Nuclear Information System (INIS)

Bukharin, O.

1995-01-01

Economic viability of reprocessing operations at the RT-1 plant is provided by the contracts with nuclear utilities from Finland and Hungary. Finland will stop sending fuel to Mayak for reprocessing after 1996. Hungary will be capable to resolve the problem of spent fuel domestically some time in the future. This increases vulnerability of the reprocessing business at Mayak to future political uncertainties. (author)

The influence of size of plant upon reprocessing costs

International Nuclear Information System (INIS)

1978-10-01

This paper reviews recent published estimates for capital and operating costs of reprocessing plants in an attempt to establish a relative variation of unit reprocessing costs with plant design capacity and load factor. It is concluded that capital costs follow the well established ''rule of thumb'' for chemical plants in being proportional to (design capacity)sup(2/3). Operating costs vary significantly with variation in labour costs. Unit reprocessing costs are presented as a function of plant design capacity, load factor and method of financing

Benchmark data for a large reprocessing plant for evaluation of advanced data analysis algorithms and safeguards system design

International Nuclear Information System (INIS)

Burr, T.L.; Coulter, C.A.; Wangen, L.E.

1998-02-01

This report describes the simulation and analysis of solution level and density (L,D) in all key main process tanks in a large reprocessing plant. In addition, initial provisions were made to include temperature (T) data in the analysis at a later time. FacSim, a simulation program developed at Los Alamos, was used to generate simulated process operating data for the Rokkasho Reprocessing Plant (RRP) that is now under construction in Japan. Both normal facility operation and more than thirty abrupt diversion scenarios were modeled over 25-day periods of simulated operation beginning with clean startup of the facility. The simulation tracked uranium, plutonium (both +3 and +4 oxidation states), HNO 3 diluent, and tributyl phosphate from the input accountability vessel to the plutonium output accountability vessel, with the status of each process vessel and many pipes recorded at intervals of approximately four minutes. These data were used to determine solution volume and density values in each process vessel as a function of time

The environmental impact of reprocessing

International Nuclear Information System (INIS)

Mummery, P.W.; Howells, H.; Scriven, A.

1980-01-01

The subject is discussed under the headings: introduction; basis of hazard assessment (dose limits - ICRP recommendations; biological radiation effects); comparison of standards and practice in the UK and USA in the limitation of exposure of the public as a consequence of discharges of radioactive effluent to the environment; nature of reprocessing operations (Thermal Oxide Fuel Reprocessing Plant (THORP); storage ponds; fuel shearing; leaching; clarification; solvent extraction; finishing); waste management (liquids, solids, gases); waste discharges; environmental impact of normal operations (identification of the critical groups; exposure of critical groups; risks and exposures, occupational and collective); environmental impact of accidents (risk - probability multiplied by consequence of the event; types of accident considered); conclusion. (U.K.)

Chemical problems associated with reprocessing

International Nuclear Information System (INIS)

Chesne, A.

1981-09-01

This paper is an attempt to pinpoint the chemical problems raised by the reprocessing of oxide base fuels. Taking the reprocessing of slightly irradiated metallic fuels as a reference, for which long experience has been gained, a review is made of the various stages of the Purex process, in which the increase in mass and activity of the actinides and fission products engenders constraints related to the recovery of fissile materials, their purification, the release rate and, in general, the operation of the installations. The following subjects are discussed: dissolution from the standpoint of dissolution residues and iodine trapping, extraction cycles with respect to the behavior of ruthenium, neptunium, plutonium, technetium and palladium, the recycling of medium activity wastes

ELEX process for tritium separation from aqueous effluents

International Nuclear Information System (INIS)

Bruggeman, A.; Doyen, W.; Leysen, R.; Meynendonckx, L.; Monsecour, M.; Goossens, W.R.A.

1980-01-01

Within the framework of the European Communities' indirect action program on management and storage of radioactive waste the Belgian Nuclear Research Centre, S.C.K./C.E.N., is developing the ELEX process for tritium separation from aqueous reprocessing effluents. This process is a combination of water electrolysis and tritium exchange between hydrogen and water, the exchange being promoted by a hydrophobic catalyst. For classical electrolysis under normal working conditions with elementary tritium separation factor of 11.6 with a standard deviation of 6% was obtained. As to the exchange step an appropriate hydrophobic catalyst has been developed, and overall tritium exchange rates were measured in a countercurrent packed-bed reactor. Extrapolation of these results to the 3 m 3 per day scale of a reprocessing plant leads to an electrolyser capacity of about 1 MW and to an exchange volume of about 1 m 3 for an ELEX installation that concentrates 90% of the original tritium in 1% of the original volume. At the moment the construction of a small integrated detritiation unit is nearly finished. A larger pilot installation will be built later on

Interim guidance for the safe transport of reprocessed uranium

International Nuclear Information System (INIS)

1994-06-01

Increasingly reprocessed uranium is being used for the fabrication of nuclear fuel elements. Different intermediate reprocessing steps are carried out at different locations. Therefore, transportation of uranium material is necessary. Due to the difference in isotope composition of reprocessed uranium then unirradiated uranium a doubt is casted on the presumption that packages used for the transport of unirradiated uranium are automatically suitable for reprocessed uranium compounds. The Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM) recommended that the issue be reviewed by consultants and that a document be developed that would give guidance to users of the Regulations. This TECDOC is the result of the endeavors of the experts convened at two Consultants Services meetings. It contains guidance on the provisions in the current Regulations as well as proposals for changes to the new Revised Edition whose publication is planned for 1996. This document demonstrates that under the present Transport Regulations it is possible in most cases to ship reprocessed uranium compounds in the same packages as unirradiated uranium compounds. In few cases a more stringent package type is required. 8 refs, 22 figs, 19 tabs

Development of the system for the estimation of materials flow in pyrochemical reprocessing plant. Characteristic evaluation of the oxide electrowinning plant

International Nuclear Information System (INIS)

Okamura, Nobuo; Tozawa, Katuhiro; Sato, Koji

2002-07-01

The operation of the plant with the non-aqueous reprocessing technology depends on the materials handling equipment closely. Because the value of decontamination factor of the products in the plant is low, treatment of nuclear materials requires remote operation technology. So the system for the evaluation of materials flow in the plant was built to evaluate the production ability of the plant and to check out the plant operation from the viewpoint of materials flow. The system is only based on information of the treatment abilities of materials handling machines and process installations and the arrangement of process installations in the reprocessing cell that influences a way to operate materials handling machines intensity. Therefore the system can be used to estimate the characteristics of non-aqueous plants that are not in detail design stage. The amount of production and the characteristics of the oxide electrowinning plant (operation term 200days/year, plant capacity 50tHM/year in design) designed in Feasibility Study Phase1 were estimated using the system. The results show that the practical amount of production of the plant design is about 88% of the designed value. To increase the amount of production, it is more useful to speed up materials handling machine time than to install new installation or to give priority to conduct bottleneck processes. It is because materials handling influences the production ability of the plant deeply. (author)

Technological study of electrochemical uranium fuel reprocessing in fused chloride bath

International Nuclear Information System (INIS)

Fernandes, Damaris

2002-01-01

This study is applied to metallic fuels recycling, concerning advanced reactor concept, which was proposed and tested in LMR type reactors. Conditions for electrochemical non-irradiated uranium fuel reprocessing in fused chloride bath in laboratory scale were established. Experimental procedures and parameters for dehydration treatment of LiCl-KCl eutectic mixture and for electrochemical study of U 3+ /U system in LiCl-KCl were developed and optimized. In the voltammetric studies many working electrodes were tested. As auxiliary electrodes, graphite and stainless steels crucibles were verified, with no significant impurities inclusions in the system. Ag/AgCl in Al 2 O 3 with 1 w% in AgCl were used as reference electrode. The experimental set up developed for electrolyte treatment as well as for the study of the system U 3+ /U in LiCl-KCl showed to be adequate and efficient. Thermogravimetric Techniques, Scanning Electron Microscopy with Energy Dispersive X-Ray Spectrometry and cyclic voltametry showed an efficient dehydration method by using HCl gas and than argon flux for 12 h. Scanning Electron Microscopy, with Energy Dispersive X-Ray Spectrometry and Inductively Coupled Plasma Emission Spectrometry and DC Arc Emission Spectrometry detected the presence of uranium in the cadmium phase. X-ray Diffraction and also Inductively Coupled Plasma Emission Spectrometry and DC Arc Emission Spectrometry were used for uranium detection in the salt phase. The obtained results for the system U 3+ /U in LiCl-KCl showed the viability of the electrochemical reprocessing process based on the IFR advanced fuel cycle. (author)

Reprocessing and reuse of urological armamentarium: How correct are we!

Directory of Open Access Journals (Sweden)

Krutik Vipulbhai Raval

2017-01-01

Full Text Available Healthcare is expensive for a large proportion of the population in spite of high per capita income and good health insurance penetration. In an effort to reduce cost of the procedure, reprocessing of devices was started in the late 1970s. Reprocessing practice includes various measures such as proper cleaning, disinfection, and sterilization procedures. As reprocessing is aimed at reducing cost, there is a potential risk of compromising patient safety due to cross contamination after inadequate sterilization. There is also risk of performance alteration of urological reprocessed devices during sterilization/disinfection processing. Therefore, there is a need for formulating proper guidelines to decide methods of reprocessing for various urological equipment. There is also need to discuss the problematic areas that urologists face and to find their solutions. A PubMed search was made in September 2016, using key words “reprocessing of medical devices,” “Single Use Devices,” “methods of reprocessing of devices in clinical practice,” “use of formalin chamber,” “urological disposable sterilization,” etc., After excluding duplicates, all English articles were reviewed by title and abstract. Full texts of selected articles were obtained, and these articles were cross-referenced to find any other related articles. All the articles were reviewed. A product can be reused if it can be economically reprocessed with validated protocols with preservation of its function. There is no reason to discard it after one use. This practice is useful for controlling economics of a urological case and to reduce the financial burden. Current Food and Drug Administration guidelines are stringent. The contamination described to test the sterilization process in the suggested guidelines actually does never exist in clinical practice. Therefore, new guidelines considering the clinical practice scenario are desirable.

Economic assessment factors relating to spent nuclear fuel reprocessing

International Nuclear Information System (INIS)

This paper is in two parts. Part I discusses the factors to be applied in an economic assessment of reprocessing. It sets forth three basic cost components, namely capital costs, operating costs and the cost of capital utilization. It lists the various components of each cost area. Part II proposes a relationship between these respective cost areas, tabulates a range of costs and then develops unit costs for reprocessing operations. Finally, an addendum to the paper gives a more detailed breakdown of the capital costs of a reprocessing plant

Reprocessing of nuclear fuels: economical, ecological and technical aspects

International Nuclear Information System (INIS)

Kueffer, K.

1994-01-01

The report deals with the questions on reprocessing and final storage of spent fuel elements from the point of view of the Swiss. The contractual obligations were discussed, of the present situation of reprocessing and their assessment. 1 fig

Enhancement of safety for reprocessing facilities

International Nuclear Information System (INIS)

2012-06-01

The adequacy of the safety measures for utility loss accidents in nuclear fuel reprocessing facilities which have been formulated by the nuclear enterprises is investigated in JNES which organizes an advanced committee to specifically study this problem. The results are reviewed in the present report including the case of such severe accidents as in Fukushima Daiichi Nuclear Power Plant. The report also represents a tentative proposal for examination standards of such unimaginable severe accidents as 'station blackout,' urgent safety measures necessary for reoperation of nuclear power plants and requested by nuclear and industrial safety agency, and pointing out and clarification of the potential weakness from the safety point of view, and collective and composite evaluation of safety of the relevant facilities. Furthermore, the definition of accident management is given as of controlled condition and the authorized way of thinking for the cases of plural events happening at the same time and the cases when risks exist radioactivity emits with explosion. (S. Ohno)

Open problems in reprocessing of a molten salt reactor fuel

International Nuclear Information System (INIS)

Lelek, Vladimir; Vocka, Radim

2000-01-01

The study of fuel cycle in a molten salt reactor (MSR) needs deeper understanding of chemical methods used for reprocessing of spent nuclear fuel and preparation of MSR fuel, as well as of the methods employed for reprocessing of MSR fuel itself. Assuming that all the reprocessing is done on the basis of electrorefining, we formulate some open questions that should be answered before a flow sheet diagram of the reactor is designed. Most of the questions concern phenomena taking place in the vicinity of an electrode, which influence the efficiency of the reprocessing and sensibility of element separation. Answer to these questions would be an important step forward in reactor set out. (Authors)

Measuring process solutions in a reprocessing plant to 0.1%

International Nuclear Information System (INIS)

Crawford, J.M.; Ehinger, M.H.; Ellis, J.H.

1980-03-01

Measurement of SNM in reprocessing plant solutions involves two major problems; measurement of bulk solution quantities and analysis of highly radioactive samples. It has been shown at the BNFP that bulk measurements can be made routinely under operating conditions to less than 0.1% total uncertainty. Two specific advances in measurement technology have been largely responsible for this improved performance. The quartz bourdon tube electromanometer replaces the fluid manometer for differential pressure measurements. The vibrating tube densimeter provides accurate measurement of density in lab samples. These instruments, coupled with a rigorous measurement and quality control procedures, are the means to achieve better than 0.1% performance

Feasibility study on commercialization of fast breeder reactor cycle systems interim report of phase II. Technical study report for nuclear fuel cycle systems

International Nuclear Information System (INIS)

Sato, Koji; Amamoto, Ippei; Inoue, Akira

2004-06-01

As a part of the feasibility study on commercialization of fast breeder reactor cycle systems, the plant concept concerning the fuel cycle systems (combination of the reprocessing and the fuel fabrication) has been constructed to reduce their total cost by the introduction of various innovative techniques and to apply their utmost superior efficiency from such standpoints of a decrease in the environmental burden, better resource utilization and proliferation resistance improvement by the low decontamination transuranium element (TRU) recycle. This interim report of Phase II describes the results of an on-going study which will cover a five-year period. For oxide fuels, the system which combines the use of the advanced aqueous reprocessing using three main methods such as the crystallization method, the simplified solvent extraction method, and the extraction chromatography method for minor actinide (MA) recovery, as well as the simplified pelletizing fuel fabrication which rationalized a powder mixing process etc., has abundant current results and a high technical feasibility for the basic process. Though this system faces difficulties in the technical development of control technology of the extraction chromatography and the fabrication technology of low decontamination TRU fuel etc., its expected practical use is possible at an early stage. As for the super-critical direct extraction reprocessing, it is necessary to fulfill more basic data although further economical improvement of an advanced aqueous reprocessing is expected. The system which combines the advanced aqueous reprocessing and the gelation sphere packing fuel fabrication has the advantage of lesser dispersion of the fine powder due to the use of solution and granule in the fuel fabrication process. However, this system will shoulder additional cost for the reagent recovery process and the waste liquid treatment process due to need to dispose of a large bulk of process waste liquid. The system which

The need to study of bounding accident in reprocessing plant

International Nuclear Information System (INIS)

Segawa, Satoshi; Fujita, Kunio

2013-01-01

There is a clear consensus that the severe accident corresponds to the core damage accident for power reactors. On the other hand, for FCFs, there is no clear consensus on what is the accident to assess the safety in the region of beyond design basis, or what is the accident which has very low probability but large consequence. The need to examine a bounding consequence of each type of accident is explained to advance the rationality of safety management and regulation and, as a result, to reinforce the safety of a reprocessing plant. The likelihood of occurrence of an accident causing a bounding consequence should correspond to that of a severe accident at a nuclear power plant. The bounding consequence will be derived using the deterministic method and sound engineering judgment supplemented by the probabilistic method. Once an agreement on such a concept is reached among regulators, operators and related experts it will help to provide a solid basis to ensure the safety of a reprocessing plant independent of that of a nuclear power plant. In this paper, we show a preliminary risk profile of RRP calculated by QSA (Quantitative Safety Assessment) which JNFL developed. The profile shows that bounding consequences of various accidents in a range of occurrence frequency corresponding to a severe accident at a nuclear power plant. And we find that the bounding consequence of high-level liquid waste boiling is the largest among all in this range. Therefore, the risk of this event is shown in this paper as an example. To build a common consensus about bounding accidents among concerned parties will encourage regulatory body to introduce such an idea for more effective regulation with scientific rationality. Additionally the study of bounding accidents can contribute to substantial development for accident management strategy as reprocessing operators. (authors)

Characteristics of radioactive waste streams generated in HTGR fuel reprocessing

International Nuclear Information System (INIS)

Lin, K.H.

1976-01-01

Results are presented of a study concerned with identification and characterization of radioactive waste streams from an HTGR fuel reprocessing plant. Approximate quantities of individual waste streams as well as pertinent characteristics of selected streams have been estimated. Most of the waste streams are unique to HTGR fuel reprocessing. However, waste streams from the solvent extraction system and from the plant facilities do not differ greatly from the corresponding LWR fuel reprocessing wastes

Revisit of analytical methods for the process and plant control analyses during reprocessing of fast reactor fuels

International Nuclear Information System (INIS)

Subba Rao, R.V.

2016-01-01

CORAL (COmpact facility for Reprocessing of Advanced fuels in Lead cell) is an experimental facility for demonstrating the reprocessing of irradiated fast reactor fuels discharged from the Fast Breeder Test Reactor (FBTR). The objective of the reprocessing plant is to achieve nuclear grade plutonium and uranium oxides with minimum process waste volumes. The process flow sheet for the reprocessing of spent Fast Reactor Fuel consists of Transport of spent fuel, Chopping, Dissolution, Feed conditioning, Solvent Extraction cycle, Partitioning Cycle and Re-conversion of Plutonium nitrate and uranium nitrate to respective oxides. The efficiency and performance of the plant to achieve desired objective depends on the analyses of various species in the different steps adopted during reprocessing of fuels. The analytical requirements in the plant can be broadly classified as 1. Process control Analyses (Analyses which effect the performance of the plant- PCA); 2. Plant control Analyses (Analyses which indicates efficiency of the plant-PLCA); 3. Nuclear Material Accounting samples (Analyses which has bearing on nuclear material accounting in the plant - NUMAC) and Quality control Analyses (Quality of the input bulk chemicals as well as products - QCA). The analytical methods selected are based on the duration of analyses, precision and accuracies required for each type analytical requirement classified earlier. The process and plant control analyses requires lower precision and accuracies as compared to NUMAC analyses, which requires very high precision accuracy. The time taken for analyses should be as lower as possible for process and plant control analyses as compared to NUMAC analyses. The analytical methods required for determining U and Pu in process and plant samples from FRFR will be different as compared to samples from TRFR (Thermal Reactor Fuel Reprocessing) due to higher Pu to U ratio in FRFR as compared TRFR and they should be such that they can be easily

Advanced remotely maintainable force-reflecting servomanipulator concept

International Nuclear Information System (INIS)

Kuban, D.P.; Martin, H.L.

1984-01-01

A remotely maintainable force-reflecting servomanipulator concept is being developed at the Oak Ridge National Laboratory as part of the Consolidated Fuel Reprocessing Program. This new manipulator addresses requirements of advanced nuclear fuel reprocessing with emphasis on force reflection, remote maintainability, reliability, radiation tolerance, and corrosion resistance. The advanced servomanipulator is uniquely subdivided into remotely replaceable modules which will permit in situ manipulator repair by spare module replacement. Manipulator modularization and increased reliability are accomplished through a force transmission system that uses gears and torque tubes. Digital control algorithms and mechanical precision are used to offset the increased backlash, friction, and inertia resulting from the gear drives. This results in the first remotely maintainable force-reflecting servomanipulator in the world. 10 references, 4 figures, 1 table

Status and trends in spent fuel reprocessing

International Nuclear Information System (INIS)

2005-09-01

The management of spent fuel arising from nuclear power production is a crucial issue for the sustainable development of nuclear energy. The IAEA has issued several publications in the past that provide technical information on the global status and trends in spent fuel reprocessing and associated topics, and one reason for this present publication is to provide an update of this information which has mostly focused on the conventional technology applied in the industry. However, the scope of this publication has been significantly expanded in an attempt to make it more comprehensive and by including a section on emerging technologies applicable to future innovative nuclear systems, as are being addressed in such international initiatives as INPRO, Gen IV and MICANET. In an effort to be informative, this publication attempts to provide a state-of-the-art review of these technologies, and to identify major issues associated with reprocessing as an option for spent fuel management. It does not, however, provide any detailed information on some of the related issues such as safety or safeguards, which are addressed in other relevant publications. This report provides an overview of the status of reprocessing technology and its future prospects in terms of various criteria in Section 2. Section 3 provides a review of emerging technologies which have been attracting the interest of Member States, especially in the international initiatives for future development of innovative nuclear systems. A historical review of IAEA activities associated with spent fuel reprocessing, traceable back to the mid-1970s, is provided in Section 4, and conclusions in Section 5. A list of references is provided at the end the main text for readers interested in further information on the related topics. Annex I summarizes the current status of reprocessing facilities around the world, including the civil operational statistics of Purex-based plants, progress with decommissioning and

Optimizing Endoscope Reprocessing Resources Via Process Flow Queuing Analysis.

Science.gov (United States)

Seelen, Mark T; Friend, Tynan H; Levine, Wilton C

2018-05-04

The Massachusetts General Hospital (MGH) is merging its older endoscope processing facilities into a single new facility that will enable high-level disinfection of endoscopes for both the ORs and Endoscopy Suite, leveraging economies of scale for improved patient care and optimal use of resources. Finalized resource planning was necessary for the merging of facilities to optimize staffing and make final equipment selections to support the nearly 33,000 annual endoscopy cases. To accomplish this, we employed operations management methodologies, analyzing the physical process flow of scopes throughout the existing Endoscopy Suite and ORs and mapping the future state capacity of the new reprocessing facility. Further, our analysis required the incorporation of historical case and reprocessing volumes in a multi-server queuing model to identify any potential wait times as a result of the new reprocessing cycle. We also performed sensitivity analysis to understand the impact of future case volume growth. We found that our future-state reprocessing facility, given planned capital expenditures for automated endoscope reprocessors (AERs) and pre-processing sinks, could easily accommodate current scope volume well within the necessary pre-cleaning-to-sink reprocessing time limit recommended by manufacturers. Further, in its current planned state, our model suggested that the future endoscope reprocessing suite at MGH could support an increase in volume of at least 90% over the next several years. Our work suggests that with simple mathematical analysis of historic case data, significant changes to a complex perioperative environment can be made with ease while keeping patient safety as the top priority.

Radiation risk assessment of reprocessed uranium

International Nuclear Information System (INIS)

Cardenas, Hugo R.; Perez, Aldo E.; Luna, Manuel F.; Becerra, Fabian A.

1999-01-01

Reprocessed uranium contains 232 U, which is not found in nature, as well as 234 U which is present in higher proportion than in natural uranium. Both isotopes modify the radiological properties of the material. The paper evaluates the increase of the internal and external radiation risk on the base of experimental data and theoretical calculations. It also suggests measures to be taken in the production of fuel elements with slightly enriched uranium.The radiation risk of reprocessed uranium is directly proportional to the content of 232 U and 234 U as well as to the aging time of the material

Working conditions in nuclear reprocessing plants

International Nuclear Information System (INIS)

1986-12-01

In the context of the project, the working conditions of workers in reprocessing plants and associated plant of the fuel circuit were thoroughly examined. The project design and course of the project are a good example of a precautionary technical assessment necessary for social policy reasons, which is in the public interest and is required by the Trade Unions. By working conditions, one means the whole set of scientific/technical, medical, legal, economic and political conditions for the permanent employment of workers in reprocessing plants including the associated parts of the fuel circuit. (orig./HP) [de

The transport of irradiated fuel. An activity closely related to reprocessing

International Nuclear Information System (INIS)

Lenail, B.; Curtis, H.W.

1987-01-01

With a proven reprocessing capacity of 400 tonnes of uranium per year and the rapid expansion of this capacity, the need to feed the reprocessing plants at La Hague has become vital to ensure continuous and economic reprocessing. The programming of transports by the reprocessor and transporter to ensure a constant supply of fuel for reprocessing has therefore become increasingly important. These transports use the public roads and the railway system and the reprocessor and transporter must cooperate in maintaining the highest possible standards of safety. Safety must take priority over all other factors, including the economics of the operation

Evironmental assessment factors relating to reprocessing of spent nuclear fuel

International Nuclear Information System (INIS)

1978-05-01

This document is in two parts. Part I presents the criteria and evaluation factors, based primarily on US experience, which may be used to carry out an environmental assessment of spent fuel reprocessing. The concept of As Low as is Reasonably Achievable (ALARA) is introduced in limiting radiation exposure. The factors influencing both occupational and general public radiation exposure are reviewed. Part II provides information on occupational and general public radiation exposure in relation to reprocessing taken from various sources including UNSCEAR and GESMO. Some information is provided in relation to potential accidents at reprocessing or MOX fuel refabrication plants. The magnitude of the services, energy, land use and non-radiological effluents for the reference design of reprocessing plant are also presented

Reprocessing flowsheet and material balance for MEU spent fuel

International Nuclear Information System (INIS)

Abraham, L.

1978-10-01

In response to nonproliferation concerns, the high-temperature gas-cooled reactor (HTGR) Fuel Recycle Development Program is investigating the processing requirements for a denatured medium-enriched uranium--thorium (MEU/Th) fuel cycle. Prior work emphasized the processing requirements for a high-enriched uranium--thorium (HEU/Th) fuel cycle. This report presents reprocessing flowsheets for an HTGR/MEU fuel recycle base case. Material balance data have been calculated for reprocessing of spent MEU and recycle fuels in the HTGR Recycle Reference Facility (HRRF). Flowsheet and mass flow effects in MEU-cycle reprocessing are discussed in comparison with prior HEU-cycle flowsheets

Structure-properties relationships in melt reprocessed PLA/hydrotalcites nanocomposites

Directory of Open Access Journals (Sweden)

R. Scaffaro

2017-07-01

Full Text Available In this work the effect of multiple reprocessing was studied on molecular structure, morphology and properties of poly(lactic acid/hydrotalcites (PLA/HT nanocomposites compared to neat PLA. In addition, the influence of two different kinds of HT – organically modified (OM-HT and unmodified (U-HT – was evaluated. Thermo-mechanical degradation was induced by means of five subsequent extrusion cycles. The performance of the recycled materials was investigated by mechanical and rheological tests, differential scanning calorimetry (DSC, intrinsic viscosity measurements and SEM observation. The results indicated that the best morphology was achieved in the systems incorporating OM-HT. On increasing the extrusion reprocessing cycles, the properties showed behavior due to two opposite effects: i chain scission due to thermo-mechanical degradation and ii filler dispersion effect resulting from multiple processing. In particular, at low reprocessing cycles, both tensile and rheological properties seem to be mainly affected by HT dispersion, especially when OM-HT was added. After five reprocessing cycles, on the contrary, chain scission, i.e. thermo-mechanical degradation, dominated. As regards the effect of the presence of organic modifier in HT, the results indicated that this variable apparently did not affect the macroscopic performance of the nanocomposites, especially at high reprocessing cycles.

Handbook on process and chemistry of nuclear fuel reprocessing. 3rd edition

International Nuclear Information System (INIS)

2015-03-01

The fundamental data on spent nuclear fuel reprocessing and related chemistry was collected and summarized as a new edition of 'Handbook on Process and Chemistry of Nuclear Fuel Reprocessing'. The purpose of this handbook is contribution to development of the fuel reprocessing and fuel cycle technology for uranium fuel and mixed oxide fuel utilization. Contents in this book was discussed and reviewed by specialists of science and technology on fuel reprocessing in Japan. (author)

Fast reactor system factors affecting reprocessing plant design

International Nuclear Information System (INIS)

Allardice, R.H.; Pugh, O.

1982-01-01

The introduction of a commercial fast reactor electricity generating system is very dependent on the availability of an efficient nuclear fuel cycle. Selection of fuel element constructional materials, the fuel element design approach and the reactor operation have a significant influence on the technical feasibility and efficiency of the reprocessing and waste management plants. Therefore the fast reactor processing plant requires liaison between many design teams -reactor, fuel design, reprocessing and waste management -often with different disciplines and conflicting objectives if taken in isolation and an optimised approach to determining several key parameters. A number of these parameters are identified and the design approach discussed in the context of the reprocessing plant. Radiological safety and its impact on design is also briefly discussed. (author)

Reprocessing decision: a study in policymaking under uncertainty

International Nuclear Information System (INIS)

Heising, C.D.

1978-01-01

The U.S. reprocessing decision is examined in this thesis. Decision analysis is applied to develop a rational framework for the assessment of policy alternatives. Benefits and costs for each alternative are evaluated and compared in dollar terms to determine the optimal decision. A fuel cycle simulation model is constructed to assess the economic value of reprocessing light water reactor (LWR) spent fuel and recycling plutonium. In addition, a dynamic fuel substitution model is used to estimate the economic effects of the reprocessing decision's influence on the introduction date of the liquid metal fast breeder reactor (LMFBR). Risks estimated in dollar terms for comparison with the economic values include those related to health, the environment and safety, nuclear theft and sabotage, and nuclear proliferation

Tritium in reprocessing plants: a study of the inventory, behavior, and the possibilities of separation of the tritium isotope

International Nuclear Information System (INIS)

Schnez, H.; Laser, M.; Merz, E.

The path followed by tritium in reprocessing plants is described in quantitative terms based on the Purex and Thorex processes. Flowsheets are given for the Purex process which are on the one hand based on the present state of technology, but make provision at the same time for a recycling of the aqueous phase and a tritium separation. As an alternative approach the technical and economic aspects have been examined of a prior separation of the tritium after reduction of the fuel elements, followed by separation from the aqueous phase. The ultimate storage and transport of the separated tritium were included in the cost determination. The conclusion is reached as a result of the study that tritium separation is possible on scientific and technical grounds. The estimates made show the financial outlay to be less than 10 DM/GWh, but may on occasion be substantially higher, since no practical or industrial experience of the process is yet available

Review of the literature for dry reprocessing oxide, metal, and carbide fuel: The AIROX, RAHYD, and CARBOX pyrochemical processes

Energy Technology Data Exchange (ETDEWEB)

Hoyt, R.C.; Rhee, B.W. [Rockwell International Corp., Canoga Park, CA (United States). Energy Systems Group

1979-09-30

The state of the art of dry processing oxide, carbide, and metal fuel has been determined through an extensive literature review. Dry processing in one of the most proliferation resistant fuel reprocessing technologies available to date, and is one of the few which can be exported to other countries. Feasibility has been established for oxide, carbide, and metal fuel on a laboratory scale, and large-scale experiments on oxide and carbide fuel have shown viability of the dry processing concept. A complete dry processing cycle has been demonstrated by multicycle processing-refabrication-reirradiation experiments on oxide fuel. Additional experimental work is necessary to: (1) demonstrate the complete fuel cycle for carbide and metal fuel, (2) optimize dry processing conditions, and (3) establish fission product behavior. Dry process waste management is easier than for an aqueous processing facility since wastes are primarily solids and gases. Waste treatment can be accomplished by techniques which have been, or are being, developed for aqueous plants.

Determination of particle size distribution of salt crystals in aqueous slurries

International Nuclear Information System (INIS)

Miller, A.G.

1977-10-01

A method for determining particle size distribution of water-soluble crystals in aqueous slurries is described. The salt slurries, containing sodium salts of predominantly nitrate, but also nitrite, sulfate, phosphate, aluminates, carbonate, and hydroxide, occur in radioactive, concentrated chemical waste from the reprocessing of nuclear fuel elements. The method involves separating the crystals from the aqueous phase, drying them, and then dispersing the crystals in a nonaqueous medium based on nitroethane. Ultrasonic treatment is important in dispersing the sample into its fundamental crystals. The dispersed crystals are sieved into appropriate size ranges for counting with a HIAC brand particle counter. A preponderance of very fine particles in a slurry was found to increase the difficulty of effecting complete dispersion of the crystals because of the tendency to retain traces of aqueous mother liquor. Traces of moisture produce agglomerates of crystals, the extent of agglomeration being dependent on the amount of moisture present. The procedure is applicable to particles within the 2 to 600 μm size range of the HIAC particle counter. The procedure provides an effective means for measuring particle size distribution of crystals in aqueous salt slurries even when most crystals are less than 10 μm in size. 19 figures

Cost and availability of gadolinium for nuclear fuel reprocessing plants

International Nuclear Information System (INIS)

Klepper, O.H.

1985-06-01

Gadolinium is currently planned for use as a soluble neutron poison in nuclear fuel reprocessing plants to prevent criticality of solutions of spent fuel. Gadolinium is relatively rare and expensive. The present study was undertaken therefore to estimate whether this material is likely to be available in quantities sufficient for fuel reprocessing and at reasonable prices. It was found that gadolinium, one of 16 rare earth elements, appears in the marketplace as a by-product and that its present supply is a function of the production rate of other more prevalent rare earths. The potential demand for gadolinium in a fuel reprocessing facility serving a future fast reactor industry amounts to only a small fraction of the supply. At the present rate of consumption, domestic supplies of rare earths containing gadolinium are adequate to meet national needs (including fuel reprocessing) for over 100 years. With access to foreign sources, US demands can be met well beyond the 21st century. It is concluded therefore that the supply of gadolinium will quite likely be more than adequate for reprocessing spent fuel for the early generation of fast reactors. The current price of 99.99% pure gadolinium oxide lies in the range $50/lb to $65/lb (1984 dollars). By the year 2020, in time for reprocessing spent fuel from an early generation of large fast reactors, the corresponding values are expected to lie in the $60/lb to $75/lb (1984 dollars) price range. This increase is modest and its economic impact on nuclear fuel reprocessing would be minor. The economic potential for recovering gadolinium from the wastes of nuclear fuel reprocessing plants (which use gadolinium neutron poison) was also investigated. The cost of recycled gadolinium was estimated at over twelve times the cost of fresh gadolinium, and thus recycle using current recovery technology is not economical. 15 refs., 4 figs., 11 tabs

Multipurpose simulator ''MR TRIOS'' for reprocessing plant

International Nuclear Information System (INIS)

Mitsui, Takeshi; Uehara, Shigeru; Takata, Hideo; Kamishima, Naoyuki

1993-01-01

MHI (Mitsubishi Heavy Industries) has developed MR TRIOS (Mitsubishi Reprocessing plant TRansient simulation code for Integrated process for Operation Support), the realtime dynamic simulator, for multipurpose use to support the Reprocessing Plant operation in various aspects. MR TRIOS integrates the Simulation Models of the unit process in a Reprocessing Plant, including Shearing, Dissolution, NOx absorption, Accountability and Adjustment and Co-decontamination process, where each Simulation Model has two kinds of models: Process and Control System. MR TRIOS can simulate the process behavior of the unit process in an integrated manner as well as independently. It is supported by MR CONTROL, the simulator control program developed by MHI. From MR TRIOS one can obtain real-time process values, such as temperature, pressure, density, flow rate, and concentration of nuclides, enabling the evaluation of the process dynamic characteristics under various operating conditions. MR TRIOS has proved to be an effective tool for the comprehensive study of the process and system dynamics, for operation technique improvements and for training

FaCT phase-I evaluation on the advanced aqueous reprocessing process (2). Development of mechanical disassembly and short stroke shearing systems for FBR fuel reprocessing

International Nuclear Information System (INIS)

Takeuchi, Masayuki; Kitagaki, Toru; Higuchi, Hidetoshi; Fukushima, Mineo; Washiya, Tadahiro; Kobayashi, Tsuguyuki

2011-01-01

JAEA promotes a development of an advanced head-end process in FaCT project. We selected mechanical cutting method for disassembly process and short stroke method for shearing process. In the FaCT phase-I, the criteria was set for decision about the innovative technology and some fundamental performances of the innovative technology such as precision, speed, durability, operation performance and system concept were discussed by the engineering test and design work. We designed and fabricated an engineering-scale test device for mechanical disassembly and short stroke shearing and have carried out the engineering tests using simulated fuel assemblies. As a part of the engineering test results, the effects of cutting conditions on the durability of cutting tool and cutting stability were discussed. Also, the reduction of magazine width is effective to improve the precision of sheared pin length, and the bundle of simulated fuel pins were successfully sheared to 10 ± 5mm, which is a target for the sheared pin length. The criteria for the mechanical disassembly technology and the short stroke shearing technology were satisfied, so we judged that the development of innovative technologies has worth going on for the next phase in the FaCT project. (author)

Legal problems of nuclear fuel reprocessing

International Nuclear Information System (INIS)

Rossnagel, A.

1987-01-01

The contributions in this book are intended to exemplify the legal situation in connection with the reprocessing of spent nuclear fuel from the point of view of constitutional law, administrative law, and international law. Outline solutions are presented with regard to ensuring health, personal freedom, democratic rights and other rights, and are discussed. The author Rossnagel investigates whether the principle of essential matter can guarantee a parliamentary prerogative concerning this field of large-scale technology. The author Schmidt shows that there is no legal obligation of commitment to a reprocessing technology that would exclude research for or application of a less hazardous technology. The contribution by Baumann explains the problems presented by a technology not yet developed to maturity with regard to the outline approval of the technological concept, which is a prerequisite of any partial licence to be issued. The final contribution by Guendling investigates the duties under international law, as for instance transfrontier information, consultation, and legal protection, and how these duties can be better put into practice in order to comply the seriousness of the hazards involved in nuclear fuel reprocessing. (orig./HP) [de

Use of risk information to safety regulation. Reprocessing facilities

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-08-15

A procedure of probabilistic risk assessment (PRA) for a reprocessing facility has been under the development aiming to utilize risk information for safety regulations in this project. Activities in the fiscal year 2012 are summarized in the paper. A major activity is a fundamental study on a concept of serious accidents, requirements of serious accident management, and a policy of utilizing risk information for fabrication and reprocessing facilities. Other than the activity a study on release and transport of aerial radioactive materials at a serious accident in a reprocessing facility has been conducted. The outline and results are provided in the chapter 1 and 2 respectively. (author)

Waste management in reprocessing plants

International Nuclear Information System (INIS)

Mortreuil, M.

1982-01-01

This lecture will give a survey of the French policy for the management of wastes in reprocessing plants. In consideration of their radioactivity, they must be immobilized in matrix in such a manner that they are stored under optimal safety conditions. A general review on the nature, nucleide content and quantity of the various wastes arising from thermal nuclear fuel reprocessing is given in the light of the French plants UP1 at Marcoule and UP2 at La Hague. The procedures of treatment of such wastes and their conditioning into inert packages suitable for temporary or terminal storage are presented, especially concerning the continuous vitrification process carried out for fission product solutions. The requirements of each option are discussed and possible alternative solutions are exposed. (orig./RW)

Contamination of incinerator at Tokai Reprocessing Plant

International Nuclear Information System (INIS)

Takahashi, Mutsuo

1994-01-01

Originally, at Tokai Reprocessing Plant an incinerator was provided in the auxiliary active facility(waste treatment building). This incinerator had treated low level solid wastes generated every facilities in the Tokai Reprocessing Plant since 1974 and stopped the operation in March 1992 because of degeneration. The radioactivity inventory and distribution was evaluated to break up incinerator, auxiliary apparatuses(bag filter, air scrubbing tower, etc.), connecting pipes and off-gas ducts. This report deals with the results of contamination survey of incinerator and auxiliary apparatuses. (author)

Advances of aqueous rechargeable lithium-ion battery: A review

Science.gov (United States)

Alias, Nurhaswani; Mohamad, Ahmad Azmin

2015-01-01

The electrochemical characteristic of the aqueous rechargeable lithium-ion battery has been widely investigated in efforts to design a green and safe technology that can provide a highly specific capacity, high efficiency and long life for high power applications such as the smart grid and electric vehicle. It is believed that the advantages of this battery will overcome the limitations of the rechargeable lithium-ion battery with organic electrolytes that comprise safety and create high fabrication cost issues. This review focuses on the opportunities of the aqueous rechargeable lithium-ion battery compared to the conventional rechargeable lithium-ion battery with organic-based electrolytes. Previously reported studies are briefly summarised, together with the presentation of new findings based on the conductivity, morphology, electrochemical performance and cycling stability results. The factors that influence the electrochemical performance, the challenges and potential of the aqueous rechargeable lithium-ion battery are highlighted in order to understand and maintained the excellent battery performance.

Selective absorption pilot plant for decontamination of fuel reprocessing plant off-gas

Energy Technology Data Exchange (ETDEWEB)

Stephenson, M.J.; Eby, R.S.; Huffstetler, V.C.

1977-10-01

A fluorocarbon-based selective absorption process for removing krypton-85, carbon-14, and radon-222 from the off-gas of conventional light water and advanced reactor fuel reprocessing plants is being developed at the Oak Ridge Gaseous Diffusion Plant in conjunction with fuel recycle work at the Oak Ridge National Laboratory and at the Savannah River Laboratory. The process is characterized by an especially high tolerance for many other reprocessing plant off-gas components. This report presents detailed drawings and descriptions of the second generation development pilot plant as it has evolved after three years of operation. The test facility is designed on the basis of removing 99% of the feed gas krypton and 99.9% of the carbon and radon, and can handle a nominal 15 scfm (425 slm) of contaminated gas at pressures from 100 to 600 psig (7.0 to 42.2 kg/cm/sup 2/) and temperatures from minus 45 to plus 25/sup 0/F (-43 to -4/sup 0/C). Part of the development program is devoted to identifying flowsheet options and simplifications that lead to an even more economical and reliable process. Two of these applicative flowsheets are discussed.

Processes for the control of 14CO2 during reprocessing

International Nuclear Information System (INIS)

Notz, K.J.; Holladay, D.W.; Forsberg, C.W.; Haag, G.L.

1980-01-01

The fixation of 14 CO 2 may be required at some future time because of the significant fractional contribution of 14 C, via the ingestion pathway, to the total population dose from the nuclear fuel cycle, even though the actual quantity of this dose is very small when compared to natural background. The work described here was done in support of fuel reprocessing development, of both graphite fuel (HTGRs) and metal-clad fuel (LWRs and LMFBRs), and was directed to the control of 14 CO 2 released during reprocessing operations. However, portions of this work are also applicable to the control of 14 CO 2 released during reactor operation. The work described falls in three major areas: (1) The application of liquid-slurry fixation with Ca(OH) 2 , which converts the CO 2 to CaCO 3 , carried out after treatment of the CO 2 -containing stream to remove other gaseous radioactive components, mainly 85 Kr. This approach is primarily for application to HTGR fuel reprocessing. (2) The above process for CO 2 fixation, but used ahead of Kr removal, and followed by a molecular sieve process to take out the 85 Kr. This approach was developed for use with HTGR reprocessing, but certain aspects also have application to metal-clad fuel reprocessing and to reactor operation. (3) The use of solid Ba(OH) 2 hydrate reacting directly with the gaseous phase. This process is generally applicable to both reprocessing and to reactor operation

Reprocessing of spent plasma

International Nuclear Information System (INIS)

Pierini, G.

1981-01-01

This invention relates to a process for removing helium and other impurities from a mixture containing deuterium and tritium, a deuterium/tritium mixture when purified in accordance with such a process and, more particularly, to a process for the reprocessing of spent plasma removed from a thermofusion reactor. (U.K.)

NO/sub x/ emissions from Hanford nuclear fuels reprocessing plants

International Nuclear Information System (INIS)

Pajunen, A.L.; Dirkes, R.L.

1978-01-01

Operation of the existing Hanford nuclear fuel reprocessing facilities will increase the release of nitrogen oxides (NO/sub x/) to the atmosphere over present emission rates. Stack emissions from two reprocessing facilities, one waste storage facility and two coal burning power plants will contain increased concentrations of NO/sub x/. The opacity of the reprocessing facilities' emissions is predicted to periodically exceed the State and local opacity limit of twenty percent. Past measurements failed to detect differences in the ambient air NO/sub x/ concentration with and without reprocessing plant operations. Since the facilities are not presently operating, increases in the non-occupational ambient air NO/sub x/ concentration were predicted from theoretical diffusion models. Based on the calculations, the annual average ambient air NO/sub x/ concentration will increase from the present level of less than 0.004 ppM to less than 0.006 ppM at the Hanford site boundaries. The national standard for the annual mean ambient air NO 2 concentration is 0.05 ppM. Therefore, the non-occupational ambient air NO/sub x/ concentration will not be increased to significant levels by reprocessing operations in the Hanford 200 Areas

Sterilization and reprocessing of materials and medical devices--reusability.

Science.gov (United States)

Jayabalan, M

1995-07-01

Problems associated with reprocessing of disposable medical devices such as hemodialysers with resterilization for reuse and changes in material properties with resterilization of polymeric (PVC, polypropylene, polyester, polycarbonate) materials intended for development of disposable devices are reviewed. Reprocessing of hospital supplies, polystyrene microtiter plate and angiographic catheter for reuse is also discussed.

Development of safety evaluation technology for fire and explosion in reprocessing plant

International Nuclear Information System (INIS)

Miura, Akihiko

2005-01-01

Based on some lessons learned from the accidents in the reprocessing plant all over the world, Japan Nuclear Cycle Development Institute (JNC) has researched and developed the safety technologies for the reprocessing plants and its related facilities. This paper describes some accidental information around the reprocessing plants and its related research activities in JNC. (author)

How can Korea secure uranium enrichment and spent fuel reprocessing rights?

International Nuclear Information System (INIS)

Roh, Seungkook; Kim, Wonjoon

2014-01-01

South Korea is heavily dependent on energy resources from other countries and nuclear energy accounts for 31% of Korea's electric power generation as a major energy. However, Korea has many limitations in uranium enrichment and spent fuel reprocessing under the current Korea-U.S. nuclear agreement, although they are economically and politically important to Korea due to a significant problems in nuclear fuel storages. Therefore, in this paper, we first examine those example countries – Japan, Vietnam, and Iran – that have made nuclear agreements with the U.S. or have changed their agreements to allow the enrichment of uranium and the reprocessing of spent fuel. Then, we analyze those countries' nuclear energy policies and review their strategic repositioning in the relationship with the U.S. We find that a strong political stance for peaceful usage of nuclear energy including the legislation of nuclear laws as was the case of Japan. In addition, it is important for Korea to acquire advanced technological capability such as sodium-cooled fast reactor (SFR) because SFR technologies require plutonium to be used as fuel rather than uranium-235. In addition, Korea needs to leverage its position in nuclear agreement between China and the U.S. as was the case of Vietnam

Head-end reprocessing equipment remote maintenance demonstration

International Nuclear Information System (INIS)

Evans, J.H.; Metz, C.F. III.

1989-01-01

Prototype equipment for reprocessing breeder reactor nuclear fuel was installed in the Remote Operation and Maintenance Demonstration (ROMD) area of the Consolidated Fuel Reprocessing Program (CFRP) facility at the Oak Ridge National Laboratory (ORNL) in order to evaluate the design of this equipment in a cold mock-up of a remotely maintained hot cell. This equipment included the Remote Disassembly System (RDS) and the Remote Shear System (RSS). These systems were disassembled and reassembled remotely by using the extensive remote handling systems that are installed in this simulated hot-cell environment. 5 refs., 5 figs

PYRO, a system for modeling fuel reprocessing

International Nuclear Information System (INIS)

Ackerman, J.P.

1989-01-01

Compact, on-site fuel reprocessing and waste management for the Integral Fast Reactor are based on the pyrochemical reprocessing of metal fuel. In that process, uranium and plutonium in spent fuel are separated from fission products in an electrorefiner using liquid cadmium and molten salt solvents. Quantitative estimates of the distribution of the chemical elements among the metal and salt phases are essential for development of both individual pyrochemical process steps and the complete process. This paper describes the PYRO system of programs used to generate reliable mass flows and compositions

Nondestructive assay measurements applied to reprocessing plants

International Nuclear Information System (INIS)

Ruhter, Wayne D.; Lee, R. Stephen; Ottmar, Herbert; Guardini, Sergio

1999-01-01

Nondestructive assay for reprocessing plants relies on passive gamma-ray spectrometry for plutonium isotopic and plutonium mass values of medium-to-low-density samples and holdup deposits; on active x-ray fluorescence and densitometry techniques for uranium and plutonium concentrations in solutions; on calorimetry for plutonium mass in product; and passive neutron techniques for plutonium mass in spent fuel, product, and waste. This paper will describe the radiation-based nondestructive assay techniques used to perform materials accounting measurements. The paper will also discuss nondestructive assay measurements used in inspections of reprocessing plants [ru

Light water reactor fuel reprocessing and recycling

International Nuclear Information System (INIS)

1977-07-01

This document was originally intended to provide the basis for an environmental impact statement to assist ERDA in making decisions with respect to possible LWR fuel reprocessing and recycling programs. Since the Administration has recently made a decision to indefinitely defer reprocessing, this environmental impact statement is no longer needed. Nevertheless, this document is issued as a report to assist the public in its consideration of nuclear power issues. The statement compares the various alternatives for the LWR fuel cycle. Costs and environmental effects are compared. Safeguards for plutonium from sabotage and theft are analyzed

Fuel salt reprocessing influence on the MSFR behavior and on its associated reprocessing unit

International Nuclear Information System (INIS)

Doligez, X.

2010-10-01

In order to face with the growing of the energy demand, the nuclear industry has to reach the fourth generation technology. Among those concept, molten salt reactor, and especially the fast neutron spectrum configuration, seems very promising: indeed breeding is achievable while the feedback coefficient are still negative. However, the reprocessing salt scheme is not totally set down yet. A lot of uncertainties remain on chemical properties of the salt. Thanks to numerical simulation we studied the behavior of the molten Salt Fast Reactor coupled to a nominal reprocessing unit. We are now able to determine heat transfer and radiation in each elementary step of the unit and, by this way determine those that need special study for radioprotection. We also studied which elements are fundamental to extract for the reactor operation. Finally, we present a sensibility analysis of the chemical uncertainties to few relevant properties of the reactor behavior. (author)

Air conditioning facilities in a fuel reprocessing plant

International Nuclear Information System (INIS)

Kawasaki, Michitaka; Oka, Tsutomu

1987-01-01

Reprocessing plants are the facilities for separating the plutonium produced by nuclear reaction and unconsumed remaining uranium from fission products in the spent fuel taken out of nuclear reactors and recovering them. The fuel reprocessing procedure is outlined. In order to ensure safety in handling radioactive substances, triple confinement using vessels, concrete cells and buildings is carried out in addition to the prevention of criticality and radiation shielding, and stainless steel linings and drip trays are installed as occasion demands. The ventilation system in a reprocessing plant is roughly divided into three systems, that is, tower and tank ventilation system to deal with offgas, cell ventilation system for the cells in which main towers and tanks are installed, and building ventilation system. Air pressure becomes higher from tower and tank system to building system. In a reprocessing plant, the areas in a building are classified according to dose rate. The building ventilation system deals with green and amber areas, and the cell ventilation system deals with red area. These three ventilation systems are explained. Radiation monitors are installed to monitor the radiation dose rate and air contamination in working places. The maintenance and checkup of ventilation systems are important. (Kako, I.)

Ventilating system for reprocessing of nuclear fuel rods

International Nuclear Information System (INIS)

Szulinski, M.J.

1981-01-01

In a nuclear facility such as a reprocessing plant for nuclear fuel rods, the central air cleaner discharging ventilating gas to the atmosphere must meet preselected standards not only as to the momentary concentration of radioactive components, but also as to total quantity per year. In order to comply more satisfactorily with such standards, reprocessing steps are conducted by remote control in a plurality of separate compartments. The air flow for each compartment is regulated so that the air inventory for each compartment has a slow turnover rate of more than a day but less than a year, which slow rate is conveniently designated as quasihermetic sealing. The air inventory in each such compartment is recirculated through a specialized processing unit adapted to cool and/or filter and/or otherwise process the gas. Stale air is withdrawn from such recirculating inventory and fresh air is injected (eg., By the less than perfect sealing of a compartment) into such recirculating inventory so that the air turnover rate is more than a day but less than a year. The amount of air directed through the manifold and duct system from the reprocessing units to the central air cleaner is less than in reprocessing plants of conventional design

The economic influence of reprocessing strategy in the early stages of a commercial breeder programme

International Nuclear Information System (INIS)

Pounder, F.

1982-01-01

The effect on reprocessing cost of constructing fast reactors in nuclear parks is examined and compared with carrying out reprocessing for a range of installation programmes of fast reactor in central reprocessing facilities. Consideration is also given to the economics of storing irradiated fuel to improve the load factor of reprocessing plants and to reprocessing both thermal reactor and fast reactor fuel in a common plant. (author)

The reprocessing-recycling of spent nuclear fuel. Actinides separation - Application to wastes management

International Nuclear Information System (INIS)

2008-01-01

After its use in the reactor, the spent fuel still contains lot of recoverable material for an energetic use (uranium, plutonium), but also fission products and minor actinides which represent the residues of nuclear reactions. The reprocessing-recycling of the spent fuel, as it is performed in France, implies the chemical separation of these materials. The development and the industrial implementation of this separation process represent a major contribution of the French science and technology. The reprocessing-recycling allows a good management of nuclear wastes and a significant saving of fissile materials. With the recent spectacular rise of uranium prices, this process will become indispensable with the development of the next generation of fast neutron reactors. This book takes stock of the present and future variants of the chemical process used for the reprocessing of spent fuels. It describes the researches in progress and presents the stakes and recent results obtained by the CEA. content: the separation of actinides, a key factor for a sustainable nuclear energy; the actinides, a discovery of the 20. century; the radionuclides in nuclear fuels; the aquo ions of actinides; some redox properties of actinides; some complexing properties of actinide cations; general considerations about treatment processes; some characteristics of nuclear fuels in relation with their reprocessing; technical goals and specific constraints of the PUREX process; front-end operations of the PUREX process; separation and purification operations of the PUREX process; elaboration of finite products in the framework of the PUREX process; management and treatment of liquid effluents; solid wastes of the PUREX process; towards a joint management of uranium and plutonium: the COEX TM process; technical options of treatment and recycling techniques; the fuels of generation IV reactors; front-end treatment processes of advanced fuels; hydrometallurgical processes for future fuel cycles

UP3 plant first reprocessing campaigns

International Nuclear Information System (INIS)

Leudet, A.; Hugelmann, D.; Fournier, W.; Dalverny, G.

1991-01-01

The UP3 plant start up has been achieved in two successive steps. The first one, from November 89 to April 90, involved all the facilities but T1, the head-end facility. During that period, shearing, dissolution and the first cycle extraction operations were performed in UP2 plant. 100 tons of fuel have been reprocessed that way. The second step began in August 1990, with the T1 facility start-up and the reprocessing of the resulting active solutions in the rest of the plant. This second phase involving the entire UP3 plant continued until the end of January 1991. At that time, 160 tons of fuel have been completely treated in UP3 plant

Noble gas atmospheric monitoring at reprocessing facilities

International Nuclear Information System (INIS)

Nakhleh, C.W.; Perry, R.T. Jr.; Poths, J.; Stanbro, W.D.; Wilson, W.B.; Fearey, B.L.

1997-01-01

The discovery in Iraq after the Gulf War of the existence of a large clandestine nuclear-weapon program has led to an across-the-board international effort, dubbed Programme 93+2, to improve the effectiveness and efficiency of International Atomic Energy Agency (IAEA) safeguards. One particularly significant potential change is the introduction of environmental monitoring (EM) techniques as an adjunct to traditional safeguards methods. Monitoring of stable noble gas (Kr, Xe) isotopic abundances at reprocessing plant stacks appears to be able to yield information on the burnup and type of the fuel being processed. To estimate the size of these signals, model calculations of the production of stable Kr, Xe nuclides in reactor fuel and the subsequent dilution of these nuclides in the plant stack are carried out for two case studies: reprocessing of PWR fuel with a burnup of 35 GWd/tU, and reprocessing of CAND fuel with a burnup of 1 GWd/tU. For each case, a maximum-likelihood analysis is used to determine the fuel burnup and type from the isotopic data

Cost analysis of the US spent nuclear fuel reprocessing facility

Energy Technology Data Exchange (ETDEWEB)

Schneider, E.A.; Deinert, M.R. [Department of Mechanical Engineering, University of Texas, Austin TX (United States); Cady, K.B. [Department of Theoretical and Applied Mechanics, Cornell University, Ithaca NY (United States)

2009-09-15

The US Department of Energy is actively seeking ways in which to delay or obviate the need for additional nuclear waste repositories beyond Yucca Mountain. All of the realistic approaches require the reprocessing of spent nuclear fuel. However, the US currently lacks the infrastructure to do this and the costs of building and operating the required facilities are poorly established. Recent studies have also suggested that there is a financial advantage to delaying the deployment of such facilities. We consider a system of government owned reprocessing plants, each with a 40 year service life, that would reprocess spent nuclear fuel generated between 2010 and 2100. Using published data for the component costs, and a social discount rate appropriate for intergenerational analyses, we establish the unit cost for reprocessing and show that it increases slightly if deployment of infrastructure is delayed by a decade. The analysis indicates that achieving higher spent fuel discharge burnup is the most important pathway to reducing the overall cost of reprocessing. The analysis also suggests that a nuclear power production fee would be a way for the US government to recover the costs in a manner that is relatively insensitive to discount and nuclear power growth rates. (author)

Comparison of Five Advanced Oxidation Processes for Degradation of Pesticide in Aqueous Solution

Directory of Open Access Journals (Sweden)

Augustine Chioma Affam

2018-01-01

Full Text Available The study compared the technical efficiency and economic cost of five advanced oxidation processes (Fenton, UV photo-Fenton, solar photo-Fenton, UV/TiO2/H2O2 and FeGAC/H2O2 for degradation of the pesticides chlorpyrifos cypermethrin and chlorothalonil in aqueous solution. The highest degradation in terms of COD and TOC removals and improvement of the biodegradability (BOD5/COD ratio index (BI were observed to be (i Fenton - 69.03% (COD, 55.61% (TOC, and 0.35 (BI; (ii UV photo-Fenton -78.56% (COD, 63.76% (TOC and 0.38 (BI;  (iii solar photo-Fenton - 74.19% (COD, 58.32% (TOC and 0.36 (BI; (iv UV/TiO2/H2O2 - 53.62% (COD, 21.54% (TOC, and 0.26 (BI; and  (v the most technical efficient and cost effective process was FeGAC/H2O2. At an optimum condition (FeGAC 5 g/L, H2O2 100 mg/L, and reaction time of 60 min at pH 3, the COD and TOC removal efficiency were 96.19 and 85.60%, respectively, and the biodegradation index was 0.40. The degradation rate constant and cost were 0.0246 min-1 and $0.74/kg TOC, respectively. The FeGAC/H2O2 process is the most technically efficient and cost effective for pretreatment of the pesticide wastewater before biological treatment. Copyright © 2018 BCREC Group. All rights reserved Received: 26th July 2017; Revised: 26nd September 2017; Accepted: 27th September 2017; Available online: 22nd January 2018; Published regularly: 2nd April 2018 How to Cite: Affam, A.C., Chaudhuri, M., Kutty, S.R.M. (2018. Comparison of Five Advanced Oxidation Processes for Degradation of Pesticide in Aqueous Solution. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (1: 179-186 (doi:10.9767/bcrec.13.1.1394.179-186

Plutonium, proliferation, and the price of reprocessing

International Nuclear Information System (INIS)

Gilinsky, V.

1978-01-01

France and Britain disagree with the US on whether deferring fuel reprocessing that provides plutonium for export can help contain proliferation. The US has veto power over reprocessing of US-supplied fuels for non-EURATOM countries, but exceptions will be made for movement within the EURATOM community. Political issues will be influenced by the magnitude of the financial investments, however, and commercial considerations have until recently dominated and complicated international safeguards. The author notes that US policy was reversed by the gradual acknowledgment that the same international inspection of plutonium stockpiles would not work as it had for low-enriched fuel and that economic interests must have a lower priority to avoiding proliferation. He cites the combination of sudden policy shifts, failure to prove that present reactors are best, and long-term distrust of US economic motives as failing to persuade either the French or British, who feel the best safeguard is provided by their high-security reprocessing facilities. Still to be resolved are the conditions under which plutonium must be returned to its owners, a problem that must determine safe international transport and storage and international management. Technical fixes, such as the CIVEX process, cannot contribute to the solution for several decades, while reprocessing is no longer considered a first step in waste disposal and would be more expensive and complicated than present waste disposal procedures. The author concedes merit in President Carter's requirement of separating ''the legitimate and necessary use of uranium'' and nuclear fuels that are also explosives

Development of exhaust air filters for reprocessing plants

International Nuclear Information System (INIS)

Furrer, J.; Kaempffer, R.; Jannakos, K.; Apenberg, W.

1975-01-01

Investigations of the iodine loading capacity of highly impregnated iodine sorption material (AC 6,120/H 1 ) for the GWA-filters (GWA: reprocessing plant for 1,500 metric tons per year of uranium) have been continued for low NO 2 -contents of the simulated dissolver offgas from GWA. When fully loading AC 6,120/H 1 , a conversion to silver iodides of Ag + of the impregnation of about 80% was reached in experiments with 1% NO 2 in the carrier gas. Despite the consumption of a substantial portion of the impregnation removal efficiencies > 99.99% were measured for a bed depth corresponding to a GWA filter stage. The test facility allowing to examine the behavior and the capacity of the AC 6,120/H 1 iodine sorption material under actual conditions at SAP Marcoule (reprocessing plant) has been completed except for installation in the reprocessing plant. (orig.) [de

Equipment specifications for an electrochemical fuel reprocessing plant

International Nuclear Information System (INIS)

Hemphill, Kevin P.

2010-01-01

Electrochemical reprocessing is a technique used to chemically separate and dissolve the components of spent nuclear fuel, in order to produce new metal fuel. There are several different variations to electrochemical reprocessing. These variations are accounted for by both the production of different types of spent nuclear fuel, as well as different states and organizations doing research in the field. For this electrochemical reprocessing plant, the spent fuel will be in the metallurgical form, a product of fast breeder reactors, which are used in many nuclear power plants. The equipment line for this process is divided into two main categories, the fuel refining equipment and the fuel fabrication equipment. The fuel refining equipment is responsible for separating out the plutonium and uranium together, while getting rid of the minor transuranic elements and fission products. The fuel fabrication equipment will then convert this plutonium and uranium mixture into readily usable metal fuel.

Status of project design work for a German reprocessing plant

International Nuclear Information System (INIS)

Lang, K.; Zuehlke, P.

1976-01-01

A reprocessing plant will be built within the framework of a comprehensive waste management center planned by the Federal Government to treat the fuel elements unloaded from German nuclear power stations. On the basis of an annual throughput of 1,400 te of uranium averaged over the life of the plant, the center will be able to serve between 45,000 and 50,000 MWe of installed nuclear generating capacity. A comprehensive conceptual design study of the reprocessing plant to be built has been completed on the basis of the operating experience accumulated at the Karlsruhe reprocessing plant and the development work carried out by the Karlsruhe Nuclear Research Center and in the light also of an intensive exchange of experience with British and French reprocessing companies within the framework of United Reprocessors GmbH. This conceptual design study is the foundation for the preliminary project to be carried out on a collaborative basis by KEWA and PWK. (orig.) [de

Aplikasi eye moving desensitization dan reprocessing dalam konseling post-traumatic stress disorder

Directory of Open Access Journals (Sweden)

Hengki Satrianta

2017-06-01

Full Text Available Akhir-akhir ini banyak peristiwa yang berpotensi memunculkan efek traumatik yang jika tidak ditangani akan menimbulkan gangguan stres pascatrauma. Olehnya itu, dibutuhkan upaya-upaya untu menangani masalah ini. Salah satu upaya yang dimaksud adalah penggunaan eye moving desensitization and reprocessing. Artikel ini ditulis dengan fokus pada penanganan gangguan stres pascatrauma melalui eye moving desensitization and reprocessing. Tujuan penulisan artikel ini adalah untuk mengetahui gambaran umum pelaksanaan eye moving desensitization and reprocessing. Eye moving desensitization and reprocessing mampu menjadi salah satu teknik dalam penanganan gangguan stres pascatrauma. Oleh karena itu disarankan bagi praktisi konseling di Indonesia mampu menjadikan “terapi unik” ini sebagai teknik penanganan gangguan stres pascatrauma.

Industrial experience of irradiated nuclear fuel reprocessing

International Nuclear Information System (INIS)

Delange, M.

1981-01-01

At the moment and during the next following years, France and La Hague plant particularly, own the greatest amount of industrial experience in the field of reprocessing, since this experience is referred to three types of reactors, either broadly spread all through the world (GCR and LWR) or ready to be greatly developed in the next future (FBR). Then, the description of processes and technologies used now in France, and the examination of the results obtained, on the production or on the security points of view, are a good approach of the actual industrial experience in the field of spent fuel reprocessing. (author)

Method of denitrification and stabilization of radioactive aqueous solutions of radioisotope nitrates

International Nuclear Information System (INIS)

Pecak, V.; Matous, V.

1983-01-01

The method is solved of denitrification and of the stabilization of aqueous solutions of radioactive isotopes produced during the reprocessing of nuclear fuel. The aqueous solution is first mixed with the vitreous component, most frequently phosphoric acid, ammonium phosphate or boric acid and if needed with the addition of alkalis, possibly with clarifying or anti-foam components, e.g., arsenic trioxide, antimony or cerium oxide. The mixture is further adjusted with ammonia to pH 5 - 9. The liquid mixture is then thermally and pyrolytically processed, e.g., by calcinator or fluid-bed reactor or by pot melting at temperatures of 3O0 to 900 degC while of a powder product or glass melt is formed in the presence of gaseous emissions composed of nitrous oxide - nitrogen. The resulting product is further processed by containerization or is sealed in a metal matrix. (B.S.)

(reprocessed)pooled_ctss - FANTOM5 | LSDB Archive [Life Science Database Archive metadata

Lifescience Database Archive (English)

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A spectrophotometric study of cerium IV and chromium VI species in nuclear fuel reprocessing process streams

International Nuclear Information System (INIS)

Nickson, I D; Boxall, C; Jackson, A; Whillock, G O H

2010-01-01

Nuclear fuel reprocessing schemes such as PUREX and UREX utilise HNO 3 media. An understanding of the corrosion of process engineering materials such as stainless steel in such media is a major concern for the nuclear industry. Two key species are cerium and chromium which, as Ce(IV), Cr(VI), may act as corrosion accelerants. An on-line analytical technique for these quantities would be useful for determining the relationship between corrosion rate and [Ce(IV)] and [Cr(VI)]. Consequently, a strategy for simultaneous quantification of Ce(IV), Cr(VI) and Cr(III) in the presence of other ions found in average burn-up Magnox / PWR fuel reprocessing stream (Fe, Mg, Nd, Al) is being developed. This involves simultaneous UV-vis absorbance measurement at 620, 540, 450 nm, wavelengths where Ce and Cr absorb but other ions do not. Mixed solutions of Cr(VI) and Ce(IV) are found to present higher absorbance values at 540 nm than those predicted from absorbances recorded from single component solutions of those ions. This is attributed to the formation of a 3:1 Cr(VI)-Ce(IV) complex and we report on the complexation and UV-visible spectrophotometric characteristics of this species. To the best of our knowledge this is the first experimental study of this complex in aqueous nitric acid solution systems.

Multi-purpose simulator 'MR TRIOS' for reprocessing plant

International Nuclear Information System (INIS)

Mitsui, Takeshi; Ariyoshi, Masahiro

1993-01-01

MHI(Mitsubishi Heavy Industries, Ltd.) has developed MR TRIOS(Mitsubishi Reprocessing plant TRansient simulator of Integrated process for Operation Support), the realtime dynamic simulator, for multipurpose use to support the Reprocessing Plant operation in various aspects. MR TRIOS integrates the simulation models of the unit process in reprocessing plant, including shearing, dissolution, NO x absorption, accountability and adjustment and co-decontamination process, where each simulation model has two kinds of models, one is Process and the other is Control System. MR TRIOS can simulate the process behavior of the above listed unit process in an integrated manner as well as independently. It is realized by MR CONTROL, the simulator control program developed by MHI. We can get from MR TRIOS the real-time process values, such as temperature, pressure, density, flow rate and concentration of eminent nuclides etc. enabling the evaluation of the process dynamic characteristics under various operating conditions. MR TRIOS has been proved to be an effective tool for the comprehensive study of the process and system dynamics, for operation technique improvements and for training. In this report we will show the introductory outline of multi-purpose simulator 'MR TRIOS' for reprocessing plant and also show the possibility to clarify the fundamental technical requirement to realize the effective material accountancy measure for Head-end Area. (author)

Data used for safety assessment of reprocessing facilities

International Nuclear Information System (INIS)

Nomura, Yasushi; Suzuki, Atsuyuki; Kanagawa, Akira

1990-08-01

For safety assessment of a reprocessing facility, it is important to know performance of radioactive materials in their accidental release and transfer. Accordingly, it is necessary to collect and prepare data for use in analyses for their performance. In JAERI, experiments such as for data acquisition, for source-term evaluation and for radioactive material transfer, are now planned to be performed. Prior to these experiments, it is decided to investigate data in use for accidental safety assessment of reprocessing plants and their based experimental data, thus to make it possible to recommend reasonable values for safety analysis parameters by evaluating the investigated results, to select the experimental items, to edit a safety assessment handbook and so on. In this line of objectives, JAERI rewarded a two-year contract of investigation to Nuclear Safety Research Association, to make a working group under a special committee on data investigation for reprocessing facility safety assessment. This report is a collection of results reviewed and checked by the working group. The contents consist of two parts, one for investigation and review of data used for safety assessment of domestic or oversea reprocessing facilities, and the other for investigation, review and evaluation of ANSI recommended American standard data reported by E. Walker together with their based experimental data resorting to the original referred reports. (author)

The regulations concerning the reprocessing business of spent fuels

International Nuclear Information System (INIS)

1978-01-01

In compliance with ''The law for the regulations of nuclear source material, nuclear fuel material and reactors'' these regulations prescribe concerning reprocessing facilities: The procedures to apply for the approval of the design and method of construction and the approval of the change thereof; as well as the procedure to apply for the inspection of the facilities, and details of the inspection (in sections 2-6). After that, the regulations require the enterpriser of reprocessing business to keep necessary records and take necessary measures for safety concerning the facilities, operation of reprocessing equipments, and transportation, storage on disposal of used fuel, materials separated therefrom or materials contaminated by either of them (in sections 8-16). Further, the regulations prescribe the procedure to apply for the approval of the safety rule required to the enterpriser of reprocessing business by above mentioned law and specifies items which should be included into the rule (section 17). Moreover, the regulations require the enterpriser to submit reports of each use of the internationally controllled material and specifies the items which should be included into these reports (section 19). (Matsushima, A.)

Development of the ELEX process for tritium separation at reprocessing plants

International Nuclear Information System (INIS)

Bruggeman, A.; Meynendonckx, L.; Parmentier, C.; Goossens, W.R.A.; Baetsle, L.H.

1985-01-01

The ELEX process for isotopic enrichment and separation of tritium from aqueous reprocessing effluents is described. After the development of an appropriate hydrophobic catalyst and the study of the separate constituent steps of the ELEX process, an integrated bench-scale installation with a detritiation capacity of 10 mol water per hour was constructed. It comprises essentially a 1.5 kW electrolyser and two 2 cm diameter by 3 m high exchange columns. In this mini-pilot the ELEX process was successfully demonstrated by detritiating more than 1000 dm 3 water containing up to 100 mCi tritium per dm 3 , which is the feed concentration expected for application of the process in a reprocessing plant. The process decontamination factor was always larger than 100 and the overall tritium balance could be kept within the experimental errors of the various measurements. Depending on the duration of the runs, the volume reduction factor was between 10 and 15, but this factor will become much higher when the present electrolyser will be replaced by the low-volume one now under construction at S.C.K./C.E.N. The technical availability of the mini-pilot amounted to 99% or more for the last experiments. During the nearly 6000 hours of operation there were no tritium contamination problems. At present the construction of a 280 mol.h -1 or 0.12 m 3 H 2 O (HTO) per day pilot detritiation installation nears completion. In this unit, which will have a total tritium inventory of maximum 1000 Ci, the ELEX process will be demonstrated with a volume reduction factor of 100 and a process decontamination factor of 100. Again the feed concentration will be 100 Ci tritium per m 3 . In the future this installation will be supplemented with a pre-treatment unit for the removal of fission products, organics and nitric acid

Operational experiences in radiation protection in fast reactor fuel reprocessing facility

International Nuclear Information System (INIS)

Meenakshisundaram, V.; Rajagopal, V.; Santhanam, R.; Baskar, S.; Madhusoodanan, U.; Chandrasekaran, S.; Balasundar, S.; Suresh, K.; Ajoy, K.C.; Dhanasekaran, A.; Akila, R.; Indira, R.

2008-01-01

The Compact Reprocessing facility for Advanced fuels in Lead cells (CORAL), situated at Indira Gandhi Centre for Atomic Research (IGCAR), Kalpakkam is a pilot plant to reprocess the mixed carbide fuel, for the first time in the world. Reprocessing of fuel with varying burn-ups up to 155 G Wd/t, irradiated at Fast Breeder Test Reactor (FBTR), has been successfully carried out at CORAL. Providing radiological surveillance in a fuel reprocessing facility itself is a challenging task, considering the dynamic status of the sources and the proximity of the operator with the radioactive material and it is more so in a fast reactor fuel reprocessing facility due to handling of higher burn-up fuels associated with radiation fields and elevated levels of fissile material content from the point of view of criticality hazard. A very detailed radiation protection program is in place at CORAL. This includes, among others, monitoring the release of 85 Kr and other fission products and actinides, if any, through stack on a continuous basis to comply with the regulatory limits and management of disposal of different types of radioactive wastes. Providing radiological surveillance during the operations such as fuel transport, chopping and dissolution and extraction cycle was without any major difficulty, as these were carried out in well-shielded and high integrity lead cells. Enforcement of exposure control assumes more importance during the analysis of process samples and re-conversion operations due to the presence of fission product impurities and also since the operations were done in glove boxes and fume hoods. Although the radiation fields encountered in process area were marginally higher, due to the enforcement of strict administrative controls, the annual exposure to the radiation workers was well within the regulatory limit. As the facility is being used as test bed for validation of prototype equipment, periodic inspection and maintenance of components such as centrifuge

Study on remain actinides recovery in pyro reprocessing

International Nuclear Information System (INIS)

Suharto, Bambang

1996-01-01

The spent fuel reprocessing by dry process called pyro reprocessing have been studied. Most of U, Pu and MA (minor actinides) from the spent fuel will be recovered and be fed back to the reactor as new fuel. Accumulation of remain actinides will be separated by extraction process with liquid cadmium solvent. The research was conducted by computer simulation to calculate the stage number required. The calculation's results showed on the 20 stages extractor more than 99% actinides can be separated. (author)

Concept of off-gas purification in reprocessing plants

International Nuclear Information System (INIS)

Henrich, E.; von Ammon, R.

1986-01-01

Concepts and individual processes for the off-gas purification in reprocessing plants are described which are suited to achieve a better retention of the gaseous and volatile radionuclides 129 I, 85 Kr, 14 C, and tritium. Improved and new process steps have been developed to the cold pilot plant scale. Essential individual process steps are an efficient iodine desorption from the dissolver solution, improved and new off-gas scrubs with nitric acid, a cryogenic as well as a selective absorption process for rare gas recovery plus the required prepurification steps and a process for the continuous and pressure-free fixation and storage of krypton in a metal matrix. Individual facilities have been selected and combined to investigate integrated dissolver off-gas systems. Advanced concepts based on a process using low flows and loads of all off-gas streams including the cell ventilation off-gas are briefly discussed

Trivalent lanthanide/actinide separation in the spent nuclear fuel wastes' reprocessing

International Nuclear Information System (INIS)

Narbutt, J.; Krejzler, J.

2006-01-01

Separation of trivalent actinides, in particular americium and curium, from lanthanides is an important step in an advanced partitioning process for future reprocessing of spent nuclear fuels. Since the trivalent actinides and lanthanides have similar chemistries, it is rather difficult to separate them from each other. The aim of presented work was to study solvent extraction of Am(III) and Eu(III) in a system containing diethylhemi-BTP (6-(5,6-diethyl-1,2,4-triazin-3-yl)-2,2'-bipyridine) and COSAN (protonated bis(chlorodicarbollido)cobalt(III)). The system was chosen by several groups working in the integrated EC research Project EUROPART. Several physicochemical properties of the extraction system were analyzed and discussed

Methodology for estimating reprocessing costs for nuclear fuels

International Nuclear Information System (INIS)

Carter, W.L.; Rainey, R.H.

1980-02-01

A technological and economic evaluation of reprocessing requirements for alternate fuel cycles requires a common assessment method and a common basis to which various cycles can be related. A methodology is described for the assessment of alternate fuel cycles utilizing a side-by-side comparison of functional flow diagrams of major areas of the reprocessing plant with corresponding diagrams of the well-developed Purex process as installed in the Barnwell Nuclear Fuel Plant (BNFP). The BNFP treats 1500 metric tons of uranium per year (MTU/yr). Complexity and capacity factors are determined for adjusting the estimated facility and equipment costs of BNFP to determine the corresponding costs for the alternate fuel cycle. Costs of capacities other than the reference 1500 MT of heavy metal per year are estimated by the use of scaling factors. Unit costs of reprocessed fuel are calculated using a discounted cash flow analysis for three economic bases to show the effect of low-risk, typical, and high-risk financing methods

Fuel reprocessing at THORP: profitability and public liabilities

International Nuclear Information System (INIS)

Berkhout, F.

1992-01-01

Since the economics of British Nuclear Fuels Limited's (BNFL) Thermal Oxide Reprocessing Plant (THORP) were analysed in an earlier report, a number of domestic and international developments have affected the prospects for THORP. The present report outlines these changes, and analyses their implications for the profits and public liabilities associated with the project. Timing is of some significance because once THORP becomes radioactive (planned to occur in March 1993) the bill for decommissioning the plant will rise from a trivial sum to a very large one - Pound 900 million (1992 prices) in BNFL's own estimates. The report begins with a brief outline of reprocessing and the THORP project. It then examines the market prospects for reprocessing beyond THORP's first ten years and revises BNFL's own projections. It then considers the potential profitability of THORP in relation to various possible cost increases and finally outlines the possible implications of different THORP scenarios for the public purse. (author)

On permission of reprocessing project change at the Reprocessing Works of the Japan Nuclear Fuel Ltd. (Reply)

International Nuclear Information System (INIS)

1997-01-01

The Nuclear Safety Commission replied as follows to the Prime Minister on July 14, 1997 on permission of reprocessing project change at the Reprocessing Works of the Japan Nuclear Fuel Ltd. inquired on Dec. 26, 1996. Contents of the inquiry consisted of change of refinery facility and its related instruments, integration of low level wasted liquid treating instrument and change of low level solid waste treating instrument, integration of high level wasted liquid storing building and high level wasted liquid glassification building, installation of used fuel transporting container maintenance instrument and its relating instruments, and so forth. As a result of careful discussion at the Commission for these items, they were admitted to be valid on her technical ability and her safety. (G.K.)

Remote handling developments for inspection and repair of highly active reprocessing plant

International Nuclear Information System (INIS)

Jones, E.L.

1988-01-01

Having the capability to carry out regular and comprehensive inspection of active plant can have benefits beyond the need to satisfy the possible requirements of National Regulatory Authorities. Intermediate inspection can provide qualitative data on the state of the plant, whilst regular inspection can provide quantitative data on which to base predictive judgments. Information of this sort can allow confidence in predicting the actual life of the plant as opposed to the theoretical. The following paper addresses the areas of plant inspection and repair by reference to specific projects either already completed or at an advanced stage of development at BNFL's Sellafield reprocessing plant. (author)

Material control for a reprocessing plant

International Nuclear Information System (INIS)

Rundquist, D.; Bray, G.; Donelson, S.; Glancy, J.; Gozani, T.; Harris, L.; McNamera, R.; Pence, D.; Ringham, M.

1976-01-01

Adequate control of special nuclear material (SNM) implies a basic knowledge of the quantities of SNM processed through or contained within a fuels processing facility with sufficient accuracy that diversion of the SNM for deleterious purposes can be detected in a timely manner. This report to the Lawrence Livermore Laboratory (LLL) describes the primary process streams containing plutonium that are handled routinely within a spent fuel reprocessing plant and conversion facility. As an aid in implementing the objectives of the accountability system in a realistic situation, the Allied General Nuclear Services (AGNS) reprocessing plant now under construction near Barnwell, South Carolina, was chosen as the study model. The AGNS plant processes are discussed in detail emphasizing those portions of the process that contain significant quantities of plutonium. The unit processes within the separations plant, nitrate storage, plutonium product facility and the analytical laboratory are described with regard to the SNM control system currently planned for use in the facilities. A general discussion of laboratory techniques, nondestructive assay and process instrumentation for plutonium process and product material from a reprocessing plant is included. A comprehensive discussion is given of holdup measurements in plutonium recycle facilities. A brief preliminary overview is presented of alternative processing strategies for LWR fuel. An extensive review and summary of modeling efforts for liquid-liquid extraction cycles is included. A comprehensive bibliography of previous modeling efforts is covered

Status of ANSI standards on decommissioning of nuclear reprocessing facilities

International Nuclear Information System (INIS)

Graham, H.B.

1975-01-01

A definition of decommissioning is given, and the preparation of ANSI Standard, ''General Design Criteria for Nuclear Reprocessing Facilities'' (N101.3) is discussed. A Eurochemic report, entitled ''The Shutdown of Reprocessing Facilities--Results of Preliminary Studies on the Installations Belonging to Eurochemic,'' was used in the preparation of this standard. (U.S.)

Fully integrated safeguards and security for reprocessing plant monitoring

International Nuclear Information System (INIS)

Duran, Felicia Angelica; Ward, Rebecca; Cipiti, Benjamin B.; Middleton, Bobby D.

2011-01-01

Nuclear fuel reprocessing plants contain a wealth of plant monitoring data including material measurements, process monitoring, administrative procedures, and physical protection elements. Future facilities are moving in the direction of highly-integrated plant monitoring systems that make efficient use of the plant data to improve monitoring and reduce costs. The Separations and Safeguards Performance Model (SSPM) is an analysis tool that is used for modeling advanced monitoring systems and to determine system response under diversion scenarios. This report both describes the architecture for such a future monitoring system and present results under various diversion scenarios. Improvements made in the past year include the development of statistical tests for detecting material loss, the integration of material balance alarms to improve physical protection, and the integration of administrative procedures. The SSPM has been used to demonstrate how advanced instrumentation (as developed in the Material Protection, Accounting, and Control Technologies campaign) can benefit the overall safeguards system as well as how all instrumentation is tied into the physical protection system. This concept has the potential to greatly improve the probability of detection for both abrupt and protracted diversion of nuclear material.

Læreprocesser gennem struktureret refleksion

DEFF Research Database (Denmark)

Engell, Christian; Hansen, Torben

2009-01-01

Udgangspunktet for "Læreprocesser Gennem strukturerede refleksion" er spørgsmålet om, hvordan strukturering af refleksion kan bidrage til at sikre (det nærmeste umulige) at eleverne lærer, det tilsigtede i (boldspil-)undervisningen. Forfatterne Christian Engell og Torben Hansen viser, hvordan beg...

Nuclear fuel re-processing plant

International Nuclear Information System (INIS)

Sasaki, Yuko; Honda, Takashi; Shoji, Saburo; Kobayashi, Shiro; Furuya, Yasumasa

1989-01-01

In a nuclear fuel re-processing plant, high Si series stainless steels not always have sufficient corrosion resistance in a solution containing only nitric acid at medium or high concentration. Further, a method of blowing NOx gases may possibly promote the corrosion of equipment constituent materials remarkably. In view of the above, the corrosion promoting effect of nuclear fission products is suppressed without depositing corrosive metal ions as metals in the nitric acid solution. That is, a reducing atmosphere is formed by generating NOx by electrolytic reduction thereby preventing increase in the surface potential of stainless steels. Further, an anode is disposed in the nitric acid solution containing oxidative metal ions to establish an electrical conduction and separate them by way of partition membranes and a constant potential or constant current is applied while maintaining an ionic state so as not to deposit metals. Thus, equipments of re-processing facility can be protected from corrosion with no particular treatment for wastes as radioactive materials. (K.M.)

Development of a computerized nuclear materials control and accounting system for a fuel reprocessing plant

International Nuclear Information System (INIS)

Crawford, J.M.; Ehinger, M.H.; Joseph, C.; Madeen, M.L.

1979-07-01

A computerized nuclear materials control and accounting system (CNMCAS) for a fuel reprocessing plant is being developed by Allied-General Nuclear Services at the Barnwell Nuclear Fuel Plant. Development work includes on-line demonstration of near real-time measurement, measurement control, accounting, and processing monitoring/process surveillance activities during test process runs using natural uranium. A technique for estimating in-process inventory is also being developed. This paper describes development work performed and planned, plus significant design features required to integrate CNMCAS into an advanced safeguards system

Defining the Costs of Reusable Flexible Ureteroscope Reprocessing Using Time-Driven Activity-Based Costing.

Science.gov (United States)

Isaacson, Dylan; Ahmad, Tessnim; Metzler, Ian; Tzou, David T; Taguchi, Kazumi; Usawachintachit, Manint; Zetumer, Samuel; Sherer, Benjamin; Stoller, Marshall; Chi, Thomas

2017-10-01

Careful decontamination and sterilization of reusable flexible ureteroscopes used in ureterorenoscopy cases prevent the spread of infectious pathogens to patients and technicians. However, inefficient reprocessing and unavailability of ureteroscopes sent out for repair can contribute to expensive operating room (OR) delays. Time-driven activity-based costing (TDABC) was applied to describe the time and costs involved in reprocessing. Direct observation and timing were performed for all steps in reprocessing of reusable flexible ureteroscopes following operative procedures. Estimated times needed for each step by which damaged ureteroscopes identified during reprocessing are sent for repair were characterized through interviews with purchasing analyst staff. Process maps were created for reprocessing and repair detailing individual step times and their variances. Cost data for labor and disposables used were applied to calculate per minute and average step costs. Ten ureteroscopes were followed through reprocessing. Process mapping for ureteroscope reprocessing averaged 229.0 ± 74.4 minutes, whereas sending a ureteroscope for repair required an estimated 143 minutes per repair. Most steps demonstrated low variance between timed observations. Ureteroscope drying was the longest and highest variance step at 126.5 ± 55.7 minutes and was highly dependent on manual air flushing through the ureteroscope working channel and ureteroscope positioning in the drying cabinet. Total costs for reprocessing totaled $96.13 per episode, including the cost of labor and disposable items. Utilizing TDABC delineates the full spectrum of costs associated with ureteroscope reprocessing and identifies areas for process improvement to drive value-based care. At our institution, ureteroscope drying was one clearly identified target area. Implementing training in ureteroscope drying technique could save up to 2 hours per reprocessing event, potentially preventing expensive OR delays.

Economic evaluation of reprocessing - Indicative Canadian position

International Nuclear Information System (INIS)

1979-05-01

This paper, which also appears as an Appendix to the final Working Group 4 report, forms part of the overall economic evaluation of reprocessing. The indicative national position and illustrative ''phase diagram'' for Canada is presented. Three fuel cycles are considered. (1) CANDU operating on the natural uranium, once-through fuel cycle. (2) CANDU operating with low enrichment (1.2%) once-through fuel cycle. (3) CANDU operating with recycle of plutonium and depleted uranium which has been extracted from spent CANDU natural uranium fuel. The diagrams show that reprocessing and recycle of fuel can be used to reduce further the sensitivity of CANDU fuelling costs to increasing uranium ore price

Criticality safety evaluation in Tokai Reprocessing Plant

International Nuclear Information System (INIS)

Shirai, Nobutoshi; Nakajima, Masayoshi; Takaya, Akikazu; Ohnuma, Hideyuki; Shirouzu, Hidetomo; Hayashi, Shinichiro; Yoshikawa, Koji; Suto, Toshiyuki

2000-04-01

Criticality limits for equipments in Tokai Reprocessing Plant which handle fissile material solution and are under shape and dimension control were reevaluated based on the guideline No.10 'Criticality safety of single unit' in the regulatory guide for reprocessing plant safety. This report presents criticality safety evaluation of each equipment as single unit. Criticality safety of multiple units in a cell or a room was also evaluated. The evaluated equipments were ones in dissolution, separation, purification, denitration, Pu product storage, and Pu conversion processes. As a result, it was reconfirmed that the equipments were safe enough from a view point of criticality safety of single unit and multiple units. (author)

Conditions for Australian consent to reprocessing

International Nuclear Information System (INIS)

Anon.

1980-01-01

This article contains the text of the statement by the Australian Minister for Foreign Affairs to the House of Representatives, Noember 1980, on conditions for Australian consent to the reprocessing of nuclear material of Australian origin

Radiological impact of emissions from reprocessing plants during normal operation

International Nuclear Information System (INIS)

Bonka, H.; Gruendler, D.; Hesel, D.; Muenster, M.; Schmidtlein, P.; Suender, B.

1977-01-01

When comparing the expected radiation exposure due to emissions from reprocessing plants with those from nuclear power plants it can be seen that the emissions from reprocessing plants contribute much more to the radiation exposure of the population than those from nuclear power plants. In the vicinity of reprocessing plants the highest contributions to the radiation exposure of the population are delivered by the following radionuclides: T, C 14 , Kr 85 , Sr 90 , Ru 106 , I 129 , Cs 134 , Cs 137 and Ce 144 as will as the Pu- and Cm-isotopes. Among these nuclides T, C 14 , Kr 85 und I 129 are globally distributed. While for T the contribution to the collective dose due to globally distributed T is small in comparison with the first pass exposure, the global contribution predominates for C 14 and Kr 85 . If an integration time of less than 10 5 years is considered, the contribution due to first pass exposure predominates for I 129 . When taking the radiation protection of the population into consideration, it seems sensible to retain 10% of T, 80 to 90% of C 14 , 90% of Kr 85 and 99,5% of I 129 in reprocessing plants and dispose of this material in a controlled manner. The fraction of the aerosols released should be about 10 -9 . Considering the global effects and the increasing number of nuclear power plants and reprocessing plants, an international agreement should be reached on these matters. (orig.) [de

On-line reprocessing of a molten salt reactor: a simulation tool

International Nuclear Information System (INIS)

Simon, Nicole; Gastaldi, Olivier; Penit, Thomas; Cohin, Olivier; Campion, Pierre-Yves

2008-01-01

The molten salt reactor (MSR) is one of the concepts studied in the frame of GEN IV road-map. Due to the specific features of its liquid fuel, the reprocessing unit may be directly connected to the reactor. A modelling of this unit is presented. The final objective is to create a flexible computer reprocessing code which can use data from neutron calculations and can be coupled to a neutron code. Such a code allows the description of the whole behaviour of MSR, including, in a coupled manner, both the design of the core and the optimised reprocessing scheme effects. (authors)

Impact of the Tokai reprocessing plant on the workers and on the surrounding environment

International Nuclear Information System (INIS)

Tago, I.

1996-01-01

The Tokai reprocessing plant began operation in September 1977 to establish oxide fuel reprocessing technology in Japan. Its designed capacity is about 0.7 metric tons of uranium per day. This report gives an example of the evaluation of the health and environmental aspects of a reprocessing plant. (author)

The economics of reprocessing versus direct disposal of spent nuclear fuel

International Nuclear Information System (INIS)

Bunn, M.; Holdren, J.P.; Fetter, S.; Zwaan, B. van der

2007-01-01

The economics of reprocessing versus direct disposal of spent nuclear fuel are assessed. The break-even uranium price at which reprocessing spent nuclear fuel from existing light water reactors (LWRs) and recycling the resulting plutonium and uranium in LWRs would become economic is estimated for a wide range of reprocessing prices and other fuel cycle costs and parameters. The contribution of each fuel cycle option to the cost of electricity is also estimated. A similar analysis is performed for the breakeven uranium price at which deploying fast neutron reactors (FRs) would become competitive compared with a once-through fuel cycle in LWRs, for a range of differences in capital cost between LWRs and FRs. Available information about reprocessing prices and various other fuel cycle costs and input parameters are reviewed, as well as the quantities of uranium likely to be recoverable worldwide at a range of different possible future prices. It is concluded that the once-through fuel cycle is likely to remain significantly cheaper than reprocessing and recycling in either LWRs or FRs for at least the next 50 years. Finally, there is a discussion of how scarce and expensive repository space would have to become before separation and transmutation would be economically attractive. (author)

Application of advanced remote systems technology to future waste handling facilities

International Nuclear Information System (INIS)

Kring, C.T.; Meacham, S.A.

1987-01-01

The Consolidated Fuel Reprocessing Program (CFRP) at Oak Ridge National Laboratory (ORNL) has been advancing the technology of remote handling and remote maintenance for in-cell systems planned for future nuclear fuel reprocessing plants. Much of the experience and technology developed over the past decade in this endeavor is directly applicable to the proposed in-cell systems being considered for the facilities of the Federal Waste Management System (FWMS). The application of teleoperated, force-reflecting servomanipulators with television viewing could be a major step forward in waste handling facility design. Primary emphasis in the current program is the operation of a prototype remote handling and maintenance system, the advanced servomanipulator (ASM), which specifically addresses the requirements of fuel reprocessing and waste handling with emphasis on force reflection, remote maintainability, reliability, radiation tolerance, and corrosion resistance. Concurrent with the evolution of dexterous manipulators, concepts have also been developed that provide guidance for standardization of the design of the remotely operated and maintained equipment, the interface between the maintenance tools and the equipment, and the interface between the in-cell components and the facility

Status of radioiodine control for nuclear fuel reprocessing plants

International Nuclear Information System (INIS)

Burger, L.L.; Scheele, R.D.

1983-07-01

This report summarizes the status of radioiodine control in a nuclear fuel reprocessing plant with respect to capture, fixation, and disposal. Where possible, we refer the reader to a number of survey documents which have been published in the last four years. We provide updates where necessary. Also discussed are factors which must be considered in developing criteria for iodine control. For capture from gas streams, silver mordenite and a silver nitrate impregnated silica (AC-6120) are considered state-of-the-art and are recommended. Three aqueous scrubbing processes have been demonstrated: Caustic scrubbing is simple but probably will not give an adequate iodine retention by itself. Mercurex (mercuric nitrate-nitric acid scrubbing) has a number of disadvantages including the use of toxic mercury. Iodox (hyperazeotropic nitric acid scrubbing) is effective but employs a very corrosive and hazardous material. Other technologies have been tested but require extensive development. The waste forms recommended for long-term storage or disposal are silver iodide, the iodates of barium, strontium, or calcium, and silver loaded sorbents, all fixed in cement. Copper iodide in bitumen (asphalt) is a possibility but requires testing. The selection of a specific form will be influenced by the capture process used

Simulation codes of chemical separation process of spent fuel reprocessing. Tool for process development and safety research

International Nuclear Information System (INIS)

Asakura, Toshihide; Sato, Makoto; Matsumura, Masakazu; Morita, Yasuji

2005-01-01

This paper reviews the succeeding development and utilization of Extraction System Simulation Code for Advanced Reprocessing (ESSCAR). From the viewpoint of development, more tests with spent fuel and calculations should be performed with better understanding of the physico-chemical phenomena in a separation process. From the viewpoint of process safety research on fuel cycle facilities, it is important to know the process behavior of a key substance; being highly reactive but existing only trace amount. (author)

Reprocessing technology for present water reactor fuels

International Nuclear Information System (INIS)

McMurray, P.R.

1977-01-01

The basic Purex solvent extraction technology developed and applied in the U.S. in the 1950's provides a well-demonstrated and efficient process for recovering uranium and plutonium for fuel recycle and separating the wastes for further treatment and packaging. The technologies for confinement of radioactive effluents have been developed but have had limited utilization in the processing of commercial light water reactor fuels. Technologies for solidification and packaging of radioactive wastes have not yet been demonstrated but significant experience has been gained in laboratory and engineering scale experiments with simulated commercial reprocessing wastes and intermediate level wastes. Commercial scale experience with combined operations of all the required processes and equipment are needed to demonstrate reliable reprocessing centers

Development of a computerized nuclear materials control and accounting system for a fuel reprocessing plant

International Nuclear Information System (INIS)

Crawford, J.M.; Ehinger, M.H.; Joseph, C.; Madeen, M.L.

1979-01-01

A computerized nuclear materials control and accounting system (CNMCAS) for a fuel reprocessing plant is being developed by Allied-General Nuclear Services at the Barnwell Nuclear Fuel Plant. Development work includes on-line demonstration of near real-time measurement, measurement control, accounting, and processing monitoring/process surveillance activities during test process runs using natural uranium. A technique for estimating in-process inventory is also being developed. This paper describes development work performed and planned, plus significant design features required to integrate CNMCAS into an advanced safeguards system. 2 refs

Feasibility study for adapting ITREC plant to reprocessing LMFBR fuels

International Nuclear Information System (INIS)

Moccia, A.; Rolandi, G.

1976-05-01

The report evaluates the feasibility of adapting ITREC plant to the reprocessing LMFBR fuels, with the double purpose of: 1) recovering valuable Pu contained in these fuels and recycling it to the fabrication plant; 2) trying, on a pilot scale, the chemical process technology to be applied in a future industrial plant for reprocessing the fuel elements discharged from fast breeder power reactors

Summary of the function and the safety design of the Tokai Reprocessing Utility Center

International Nuclear Information System (INIS)

Yanai, Chisato; Yamazaki, Toshihiko; Tomita, Tsuneo; Horii, Shinichi; Uryu, Mituru; Ishiguro, Nobuharu; Kobayashi, Kentarou

1998-01-01

The Tokai Reprocessing Utility Center is a new facility to replace the utilities to the Tokai Reprocessing Plant such as the emergency power supply, compressed air, etc. which are scattered about the site and have became superannuated. The Facility building has a base-isolation system that is a strongly resistant to earthquake. After completion, the center will supply utilities to the Main Plant, the Central Building, the Auxiliary Active Facility, etc. of the Tokai Reprocessing Plant. This document outlines the function and the safety design of the Tokai Reprocessing Utility Center. (author)

Corrosion penetration monitoring of advanced ceramics in hot aqueous fluids

Directory of Open Access Journals (Sweden)

Klaus G. Nickel

2004-03-01

Full Text Available Advanced ceramics are considered as components in energy related systems, because they are known to be strong, wear and corrosion resistant in many environments, even at temperatures well exceeding 1000 °C. However, the presence of additives or impurities in important ceramics, for example those based on Silicon Nitride (Si3N4 or Al2O3 makes them vulnerable to the corrosion by hot aqueous fluids. The temperatures in this type of corrosion range from several tens of centigrade to hydrothermal conditions above 100 °C. The corrosion processes in such media depend on both pH and temperature and include often partial leaching of the ceramics, which cannot be monitored easily by classical gravimetric or electrochemical methods. Successful corrosion penetration depth monitoring by polarized reflected light optical microscopy (color changes, Micro Raman Spectroscopy (luminescence changes and SEM (porosity changes will be outlined. The corrosion process and its kinetics are monitored best by microanalysis of cross sections, Raman spectroscopy and eluate chemistry changes in addition to mass changes. Direct cross-calibrations between corrosion penetration and mechanical strength is only possible for severe corrosion. The methods outlined should be applicable to any ceramics corrosion process with partial leaching by fluids, melts or slags.

The international reprocessing situation

International Nuclear Information System (INIS)

Sornein, J.

1976-01-01

It is investigated what volume and availability of reprocessing capacity is needed for LWR (and AGR) fuel elements for Western Europe, USA, and Japan during the period from 1980 to 1990. Taking into account the technical, financial, and licensing difficulties, an optimistic and pessimistic assessment is made especially for Western Europe, and from the findings conclusions are drawn for spent fuel element storage and nuclear power plant construction. (HR/LN) [de

Aerosols released in accidents in reprocessing plants

International Nuclear Information System (INIS)

Ballinger, M.Y.; Owczarski, P.C.; Hashimoto, K.; Nishio, G.; Jordan, S.; Lindner, W.

1987-01-01

For analyzing the thermodynamic and radiological consequences of solvent fire accidents in reprocessing plants, intensive investigations on burning contaminated condensible liquids were performed at Kernforschungszentrum Karlsruhe (KfK), Pacific Northwest Laboratory (PNL), and Japan Atomic Energy Research Institute (JAERI). In small- and large-scale tests, KfK studied the behavior of kerosene, tributyl phosphate, HNO 3 mixture fires in open air and closed containments. The particle release from uranium-contaminated pool fires was investigated. Different filter devices were tested. For analyzing fires, PNL has developed the FIRIN computer code and has generated small-scale fire data in support of that code. The results of the experiments in which contaminated combustible liquids were burned demonstrate the use of the FIRIN code in simulating a solvent fire in a nuclear reprocessing plant. To demonstrate the safety evaluation of a postulated solvent fire in an extraction process of a reprocessing pant, JAERI conducted large-scale fire tests. Behavior of solvent fires in a cell and the integrity of high-efficiency particulate air (HEPA) filters due to smoke plugging were investigated. To evaluate confinement of radioactive materials released from the solvent fire, the ventilation systems with HEPA filters were tested under postulated fire conditions

Status of power reactor fuel reprocessing in India

International Nuclear Information System (INIS)

Kansra, V.P.

1999-01-01

Spent fuel reprocessing in India started with the commissioning of the Trombay Plutonium Plant in 1964. This plant was intended for processing spent fuel from the 40 MWth research reactor CIRUS and recovering plutonium required for the research and development activities of the Indian Atomic Energy programme. India's nuclear energy programme aims at the recycle of plutonium in view of the limited national resources of natural uranium and abundant quantities of thorium. This is based on the approach which aims at separating the plutonium from the power reactor spent fuel, use it in the fast reactors to breed 233 U and utilise the 233 U generated to sustain a virtually endless source of power through thorium utilisation. The separated plutonium is also being utilised to fabricate MOX fuel for use in thermal reactors. Spent fuel treatment and extracting plutonium from it makes economic sense and a necessity for the Indian nuclear power programme. This paper describes the status and trends in the Indian programme for the reprocessing of power reactor fuels. The extraction of plutonium can also be seen as a far more positive approach to long-term waste management. The closed cycle approach visualised and pursued by the pioneers in the field is now steadily moving India towards the goal of a sustainable source of power through nuclear energy. The experience in building, operating and refurbishing the reprocessing facilities for uranium and thorium has resulted in acquiring the technological capability for designing, constructing, operating and maintaining reprocessing plants to match India's growing nuclear power programme. (author)

(reprocessed)CAGE_peaks_annotation - FANTOM5 | LSDB Archive [Life Science Database Archive metadata

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Potential safety-related incidents with possible applicability to a nuclear fuel reprocessing plant

International Nuclear Information System (INIS)

Perkins, W.C.; Durant, W.S.; Dexter, A.H.

1980-12-01

The occurrence of certain potential events in nuclear fuel reprocessing plants could lead to significant consequences involving risk to operating personnel or to the general public. This document is a compilation of such potential initiating events in nuclear fuel reprocessing plants. Possible general incidents and incidents specific to key operations in fuel reprocessing are considered, including possible causes, consequences, and safety features designed to prevent, detect, or mitigate such incidents

Radiation exposures in reprocessing facilities at the Savannah River Plant

International Nuclear Information System (INIS)

Hayes, G.; Caldwell, R.D.; Hall, R.M.

1979-01-01

Two large reprocessing facilities have been operating at the Savannah River Plant since 1955. The plant, which is near Aiken, South Carolina, is operated for the U.S. Department of Energy by the Du Pont Company. The reprocessing facilities have a work force of approximately 1,800. The major processes in the facilities are chemical separations of irradiated material, plutonium finishing, and waste management. This paper presents the annual radiation exposure for the reprocessing work force, particularly during the period 1965 through 1978. It also presents the collective and average individual annual exposures for various occupations including operators, mechanics, electricians, control laboratory technicians, and health physicists. Periodic and repetitive work activities that result in the highest radiation exposures are also described. The assimilation of radionuclides, particularly plutonium, by the work force is reviewed. Methods that have been developed to minimize the exposure of reprocessing personnel are described. The success of these methods is illustrated by experience - there has been no individual worker exposure of greater than 3.1 rems per year and only one plutonium assimilation greater than the maximum permissible body burden during the 24 years of operation of the facilities

Radiation exposures in reprocessing facilities at the Savannah River Plant

International Nuclear Information System (INIS)

Hayes, G.; Caldwell, R.D.; Hall, R.M.

1979-06-01

Two large reprocessing facilities have been operating at the Savannah River Plant since 1955. The plant, which is near Aiken, South Carolina, is operated for the US Department of Energy by the Du Pont Company. The reprocessing facilities have a work force of approximately 1,800. The major processes in the facilities are chemical separations of irradiated material, plutonium finishing, and waste management. This paper presents the annual radiation exposure for the reprocessing work force, particularly during the period 1965 through 1978. It also presents the collective and average individual annual exposures for various occupations including operators, mechanics, electricians, control laboratory technicians, and health physicists. Periodic and repetitive work activities that result in the highest radiation exposures are also described. The assimilation of radionuclides, particularly plutonium, by the work force is reviewed. Methods that have been developed to minimize the exposure of reprocessing personnel are described. The success of these methods is illustrated by experience - there has been no individual worker exposure of greater than 3.1 rems per year and only one plutonium assimilation greater than the maximum permissible body burden during the 24 years of operation of the facilities

Reprocessing ability of high density fuels for research and test reactors

International Nuclear Information System (INIS)

Gay, A.; Belieres, M.

1997-01-01

The development of a new high density fuel is becoming a key issue for Research Reactors operators. Such a new fuel should be a Low Enrichment Uranium (LEU) fuel with a high density, to improve present in core performances. It must be compatible with the reprocessing in an industrial plant to provide a steady back-end solution. Within the framework of a work group CEA/CERCA/COGEMA on new fuel development for Research Reactors, COGEMA has performed an evaluation of the reprocessing ability of some fuel dispersants selected as good candidates. The results will allow US to classify these fuel dispersants from a reprocessing ability point of view. (author)

Fuel reprocessing and waste management in the UK

International Nuclear Information System (INIS)

Heafield, W.; Griffin, N.L.

1994-01-01

The currently preferred route for the management of irradiated fuel in the UK is reprocessing. This paper, therefore, concentrates on outlining the policies, practices and achievement of British Nuclear Fuels plc (BNFL) associated with the management of its irradiated fuel facilities at Sellafield. The paper covers reprocessing and how the safe management of each of the major waste categories is achieved. BNFL's overall waste management policy is to develop, in close consultation with the regulatory authorities, a strategy to minimize effluent discharges and provide a safe, cost effective method of treating and preparing for disposal all wastes arising on the site

Reprocessing of spent nuclear fuel

International Nuclear Information System (INIS)

Gal, I.

1964-12-01

This volume contains the following reports: Experimental facility for testing and development of pulsed columns and auxiliary devices; Chemical-technology study of the modified 'Purex' process; Chemical and radiometric control analyses; Chromatographic separation of rare earth elements on paper treated by di-n butylphosphate; Preliminary study of some organic nitrogen extracts significant in fuel reprocessing

Benefit analysis of reprocessing and recycling light water reactor fuel

International Nuclear Information System (INIS)

1976-12-01

The macro-economic impact of reprocessing and recycling fuel for nuclear power reactors is examined, and the impact of reprocessing on the conservation of natural uranium resources is assessed. The LWR fuel recycle is compared with a throwaway cycle, and it is concluded that fuel recycle is favorable on the basis of economics, as well as being highly desirable from the standpoint of utilization of uranium resources

Reprocessing process simulation network; PRONET

International Nuclear Information System (INIS)

Mitsui, T.; Takada, H.; Kamishima, N.; Tsukamoto, T.; Harada, N.; Fujita, N.; Gonda, K.

1991-01-01

The effectiveness of simulation technology and its wide application to nuclear fuel reprocessing plants has been recognized recently. The principal aim of applying simulation is to predict the process behavior accurately based on the quantitative relations among substances in physical and chemical phenomena. Mitsubishi Heavy Industries Ltd. has engaged positively in the development and the application study of this technology. All the software products of its recent activities were summarized in the integrated form named 'PRONET'. The PRONET is classified into two independent software groups from the viewpoint of computer system. One is off-line Process Simulation Group, and the other is Dynamic Real-time Simulator Group. The former is called 'PRONET System', and the latter is called 'PRONET Simulator'. These have several subsystems with the prefix 'MR' meaning Mitsubishi Reprocessing Plant. Each MR subsystem is explained in this report. The technical background, the objective of the PRONET, the system and the function of the PRONET, and the future application to an on-line real-time simulator and the development of MR EXPERT are described. (K.I.)

Example of material accounting and verification of reprocessing input

International Nuclear Information System (INIS)

Koch, L.; Schoof, S.

1981-01-01

An example is described in this paper of material accounting at the reprocessing input point. Knowledge of the fuel history and chemical analyses of the spent fuel permitted concepts to be tested which have been developed for the determination of the input by the operator and for its verification by nuclear material safeguards with the intention of detecting a protracted as well as an abrupt diversion. Accuracies obtained for a material balance of a PWR fuel reprocessing campaign are given. 6 refs

The integral fast reactor fuels reprocessing laboratory at Argonne National Laboratory, Illinois

International Nuclear Information System (INIS)

Wolson, R.D.; Tomczuk, Z.; Fischer, D.F.; Slawecki, M.A.; Miller, W.E.

1986-09-01

The processing of Integral Fast Reactor (IFR) metal fuel utilizes pyrochemical fuel reprocessing steps. These steps include separation of the fission products from uranium and plutonium by electrorefining in a fused salt, subsequent concentration of uranium and plutonium for reuse, removal, concentration, and packaging of the waste material. Approximately two years ago a facility became operational at Argonne National Laboratory-Illinois to establish the chemical feasibility of proposed reprocessing and consolidation processes. Sensitivity of the pyroprocessing melts to air oxidation necessitated operation in atmosphere-controlled enclosures. The Integral Fast Reactor Fuels Reprocessing Laboratory is described

Spent nuclear fuel reprocessing and international law. Germany's obligations under international law in matters of spent fuel reprocessing and the relevant contracts concluded with France and the United Kingdom

International Nuclear Information System (INIS)

Heintschel v Heinegg, W.

1999-01-01

The review presented is an excerpt from an expert opinion written by the author in December last year, in response to changes in nuclear energy policy announced by the new German government. The reprocessing of spent nuclear fuels from German power reactors in the reprocessing facilities of France (La Hague) and the UK (Sellafield) is not only based on contracts concluded by the German electric utilities and the French COGEMA or the British BNFL, but has been agreed as well by an exchange of diplomatic notes between the French Ministry of Foreign Affairs and the German ambassador in Paris, the German Foreign Ministry and the French ambassador as well as the British ambassador in Bonn. The article therefore first examines from the angle of international law the legal obligations binding the states involved, and Germany in particular, in matters of spent fuel reprocessing contracts. The next question arising in this context and discussed by the article is that of whether and how much indemnification can be demanded by the reprocessing companies, or their governments, resp., if Germany should discontinue spent fuel reprocessing and thus might be made liable for breach of the bilateral agreements. (orig/CB) [de

Analytical chemistry needs for nuclear safeguards in nuclear fuel reprocessing

International Nuclear Information System (INIS)

Hakkila, E.A.

1977-01-01

A fuel reprocessing plant designed to process 1500 tons of light water reactor fuel per year will recover 15 tons of Pu during that time, or approximately 40 to 50 kg of Pu per day. Conventional nuclear safeguards accountability has relied on batch accounting at the head and tail ends of the reprocessing plant with semi-annual plant cleanout to determine in-process holdup. An alternative proposed safeguards system relies on dynamic material accounting whereby in-line NDA and conventional analytical techniques provide indications on a daily basis of SNM transfers into the system and information of Pu holdup within the system. Some of the analytical requirements and problems for dynamic materials accounting in a nuclear fuel reprocessing plant are described. Some suggestions for further development will be proposed

Consolidated Reprocessing Progam. Quarterly progress report ending February 28, 1979

International Nuclear Information System (INIS)

1979-03-01

This publication continues the quarterly series presenting results of work performed under the Consolidated Reprocessing Program at General Atomic Company. Results of work on this program prior to June 1974 were included in a quarterly series on the HTGR Base Program. The work reported includes the development of unit processes and equipment for reprocessing of High-Temperature Gas-Cooled Reactor (HTGR) fuel, the design and development of an integrated pilot line to demonstrate the head end of HTGR reprocessing using unirradiated fuel materials, and design work in support of Hot Engineering Tests (HET). Work is also described on trade-off studies concerning the required design of facilities and equipment for the large-scale recycle of HTGR fuels in order to guide the development activities for HTGR fuel recycle

Expression of cytokines in aqueous humor from fungal keratitis patients.

Science.gov (United States)

Zhang, Yingnan; Liang, Qingfeng; Liu, Yang; Pan, Zhiqiang; Baudouin, Christophe; Labbé, Antoine; Lu, Qingxian

2018-04-19

Although a series of reports on corneal fungal infection have been published, studies on pathogenic mechanisms and inflammation-associated cytokines remain limited. In this study, aqueous humor samples from fungal keratitis patients were collected to examine cytokine patterns and cellular profile for the pathogenesis of fungal keratitis. The aqueous humor samples were collected from ten patients with advanced stage fungal keratitis. Eight aqueous humor samples from patients with keratoconus or corneal dystrophy were taken as control. Approximately 100 μl to 300 μl of aqueous humor in each case were obtained for examination. The aqueous humor samples were centrifuged and the cells were stained and examined under optical microscope. Bacterial and fungal cultures were performed on the aqueous humor and corneal buttons of all patients. Cytokines related to inflammation including IL-1β, IL-6, IL-8, IL-10, TNF-α, and IFN-γ were examined using multiplex bead-based Luminex liquid protein array systems. Fungus infection was confirmed in these ten patients by smear stains and/or fungal cultures. Bacterial and fungal cultures revealed negative results in all aqueous humor specimens. Polymorphonuclear leukocytes were the predominant infiltrating cells in the aqueous humor of fungal keratitis. At the advanced stages of fungal keratitis, the levels of IL-1β, IL-6, IL-8, and IFN-γ in the aqueous humor were significantly increased when compared with control (phumor was associated with fungal keratitis.

Nuclear fuel reprocessing is challenged

International Nuclear Information System (INIS)

Anon.

1994-01-01

This article is a brief discussion of litigation to determine if the Thermal Oxide Reprocessing Plant (THORP) in the United Kingdom will be allowed to operate. Litigants (including Greenpeace) contend that the government's December approval of discharge permits for the plant was unlawful without a public hearing. A description of the THORP process is also provided in this article

Reprocessing: A reasonable way of waste disposal

International Nuclear Information System (INIS)

Merz, E.

1986-01-01

Reprocessing is the only way to recover the valuable substances contained in the burnt fuel elements and to make them utilizable for energy generation again. It is easier to adapt a national solution to the special domestic needs than a waste management plant which is operated on an international basis and is therefore simpler to be implemented. It guarantees independence, stands for the meeting of requirements resulting from the Non-Proliferation Treaty and creates safe jobs. Furthermore, it offers more liberty in applying optimized recycling strategies. A national reprocessing industry leads to an improved competitive position in the nuclear business, due to technological development and demonstration. A country like the Federal Republic of Germany, which depends on exports, does need top-level technologies. (HSCH) [de

Reprocessing in Sweden: History and perspective

International Nuclear Information System (INIS)

Hultgren, Aa.; Oesterlund, C.G.

1990-10-01

Against the background of nuclear power development and installation in Sweden an overview is presented of the parallel domestic development of the reprocessing of spent nuclear fuel. The original selection of the natural uranium - heavy water reactor in the 1950s included spent fuel reprocessing and recycle, and process and plant studies were performed to that end. The switch to light water reactors in the 1960s did not change the planning to recycle; however, the participation in the Eurochemic undertaking, and the delay in the nuclear programme stopped further domestic development work. A number of governmental committee investigations in the 1970s on the radioactive waste issue and, above all, the decision to phase out nuclear power by 2010, after a referendum following the TMI-accident, finally resulted in a decision to plan only for direct disposal of spent nuclear fuel. This policy still prevails. (42 refs.)

Mechanical and Instrumental Experiences from the Erection, Commissioning, and Operation of a Small Pilot Plant for Development Work on Aqueous Reprocessing of Nuclear Fuels

International Nuclear Information System (INIS)

Joensson, K.

1965-05-01

A radio chemical pilot plant for the reprocessing of irradiated nuclear fuels has been built by AB Atomenergi at Kjeller in Norway. In the report a short description of the main equipment is given as well as of the procedure during the erection of the plant. Finally the results and experiences from the cold tests, tracer tests and active runs are indicated

Mechanical and Instrumental Experiences from the Erection, Commissioning, and Operation of a Small Pilot Plant for Development Work on Aqueous Reprocessing of Nuclear Fuels

Energy Technology Data Exchange (ETDEWEB)

Joensson, K

1965-05-15

A radio chemical pilot plant for the reprocessing of irradiated nuclear fuels has been built by AB Atomenergi at Kjeller in Norway. In the report a short description of the main equipment is given as well as of the procedure during the erection of the plant. Finally the results and experiences from the cold tests, tracer tests and active runs are indicated.

General Atomic reprocessing pilot plant: description and results of initial testing

International Nuclear Information System (INIS)

1977-12-01

In June 1976 General Atomic completed the construction of a reprocessing head-end cold pilot plant. In the year since then, each system within the head end has been used for experiments which have qualified the designs. This report describes the equipment in the plant and summarizes the results of the initial phase of reprocessing testing

Coupled study of the Molten Salt Fast Reactor core physics and its associated reprocessing unit

International Nuclear Information System (INIS)

Doligez, X.; Heuer, D.; Merle-Lucotte, E.; Allibert, M.; Ghetta, V.

2014-01-01

Highlights: • The limit on the reprocessing is due to the redox potential control. • Alkali and Earth-alkaline elements do not have to be extracted. • Criticality risks have to be studied in the reprocessing unit. • The neutronics properties are not sensitive to chemical data. • The reprocessing chemistry, from a pure numerical point of view, is an issue. - Abstract: Molten Salt Reactors (MSRs) are liquid-fuel reactors, in which the fuel is also the coolant and flows through the core. A particular configuration presented in this paper called the Molten Salt Fast Reactor consists in a Molten Salt Reactor with no moderator inside the core and a salt composition that leads to a fast neutron spectrum. Previous studies showed that this concept (previously called Thorium Molten Salt Reactor – Nonmoderated) has very promising characteristics. The liquid fuel implies a special reprocessing. Each day a small amount of the fuel salt is extracted from the core for on-site reprocessing. To study such a reactor, the materials evolution within the core has to be coupled to the reprocessing unit, since the latter cleans the salt quasi continuously and feeds the reactor. This paper details the issues associated to the numerical coupling of the core and the reprocessing. It presents how the chemistry is introduced inside the classical Bateman equation (evolution of nuclei within a neutron flux) in order to carry a numerical coupled study. To achieve this goal, the chemistry has to be modeled numerically and integrated to the equations of evolution. This paper presents how is it possible to describe the whole concept (reactor + reprocessing unit) by a system of equations that can be numerically solved. Our program is a connection between MCNP and a homemade evolution code called REM. Thanks to this tool; constraints on the fuel reprocessing were identified. Limits are specified to preserve the good neutronics properties of the MSFR. In this paper, we show that the limit

Quantitative analysis of residual protein contamination of podiatry instruments reprocessed through local and central decontamination units

Directory of Open Access Journals (Sweden)

Ramage Gordon

2011-01-01

Full Text Available Abstract Background The cleaning stage of the instrument decontamination process has come under increased scrutiny due to the increasing complexity of surgical instruments and the adverse affects of residual protein contamination on surgical instruments. Instruments used in the podiatry field have a complex surface topography and are exposed to a wide range of biological contamination. Currently, podiatry instruments are reprocessed locally within surgeries while national strategies are favouring a move toward reprocessing in central facilities. The aim of this study was to determine the efficacy of local and central reprocessing on podiatry instruments by measuring residual protein contamination of instruments reprocessed by both methods. Methods The residual protein of 189 instruments reprocessed centrally and 189 instruments reprocessed locally was determined using a fluorescent assay based on the reaction of proteins with o-phthaldialdehyde/sodium 2-mercaptoethanesulfonate. Results Residual protein was detected on 72% (n = 136 of instruments reprocessed centrally and 90% (n = 170 of instruments reprocessed locally. Significantly less protein (p Conclusions Overall, the results show the superiority of central reprocessing for complex podiatry instruments when protein contamination is considered, though no significant difference was found in residual protein between local decontamination unit and central decontamination unit processes for Blacks files. Further research is needed to undertake qualitative identification of protein contamination to identify any cross contamination risks and a standard for acceptable residual protein contamination applicable to different instruments and specialities should be considered as a matter of urgency.

Analysis of the options - rationale for servomanipulator maintenance in future reprocessing plants

International Nuclear Information System (INIS)

Herndon, J.N.; Hamel, W.R.

1984-04-01

The currently available maintenance systems which can be applied, in various combinations, to large-volume in-cell maintenance operations are: (1) contact, (2) overhead cranes, (3) power manipulators, (4) mechanical master/slave manipulators, and (5) servomanipulators. The requirements for reprocessing plant maintenance are reviewed, and the capabilities of remote maintenance systems are described. A basic trade-off analysis of these remote maintenance systems considering reprocessing plant requirements is given. Justification is given for selecting the overhead crane/servomanipulator-based maintenance concept as the option most desirable for future large reprocessing plant maintenance. 23 references, 6 tables

Pilot and pilot-commercial plants for reprocessing spent fuels of FBR type reactors

International Nuclear Information System (INIS)

Shaldaev, V.S.; Sokolova, I.D.

1988-01-01

A review of modern state of investigations on the FBR mixed oxide uranium-plutonium fuel reprocessing abroad is given. Great Britain and France occupy the leading place in this field, operating pilot plants of 5 tons a year capacity. Technology of spent fuel reprocessing and specific features of certain stages of the technological process are considered. Projects of pilot and pilot-commercial plants of Great Britain, France, Japan, USA are described. Economic problems of the FBR fuel reprocessing are touched upon

R and D status of oxide electro-refining reprocessing technology

International Nuclear Information System (INIS)

Myochin, Munetaka

2005-01-01

The oxide electro-refining pyrochemical reprocessing is excellent in the resistivity against nuclear material diversion and in the suitability for oxide fuel cycle and has an excellent affinity for the technology of fuel production using the vibropac method. The oxide electro-refining pyrochemical reprocessing system has therefore been examined as a part of studies of commercialization of FBR cycle. This report outlines the examination results of fundamental data acquired for the system design. (M.H.)

Management and disposal of used nuclear fuel and reprocessing wastes

International Nuclear Information System (INIS)

1983-01-01

The subject is dealt with in chapters, entitled: introduction (general statement of problem); policy framework (criteria for waste management policy); waste management and disposal, as practised and planned (general; initial storage; reprocessing and conditioning of reprocessing wastes; intermediate storage; transportation; packaging; disposal); international co-operation. Details of the situation in each country concerned (Australia, Belgium, Canada, France, Federal Republic of Germany, Spain, Sweden, Switzerland and United Kingdom) are included as annexes. (U.K.)

Gaseous isotope correlation technique for safeguards at reprocessing facilities

International Nuclear Information System (INIS)

Ohkubo, Michiaki.

1988-03-01

The isotope correlation technique based on gaseous stable fission products can be used as a means of verifying the input measurement to fuel reprocessing plants. This paper reviews the theoretical background of the gaseous fission product isotope correlation technique. The correlations considered are those between burnup and various isotopic ratios of Kr and Xe nuclides. The feasibility of gaseous ICT application to Pu input accountancy of reprocessing facilities is also discussed. The technique offers the possibility of in situ measurement verification by the inspector. (author). 16 refs, 7 figs

Storage and Reprocessing of Spent Nuclear Fuel

Energy Technology Data Exchange (ETDEWEB)

Karpius, Peter Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-02-02

Addressing the problem of waste, especially high-level waste (HLW), is a requirement of the nuclear fuel cycle that cannot be ignored. We explore the two options employed currently, long-term storage and reprocessing.

International safeguards for reprocessing plants. Final report

International Nuclear Information System (INIS)

Kratzer, M.; Scheinman, L.; Sievering, N.; Wonder, E.; Lipman, D.; Immerman, W.; Elliott, J.M.; Crane, F.

1981-04-01

Proliferation risks inherent in reprocessing show the need to employ technically effective safeguards which can detect, with a high degree of assurance and on a timely basis, the diversion of significant quantities of fissionable material. A balance must be struck between what is technically feasible and effective and what is institutionally acceptable. Purpose of this report is to examine the several technical approaches to safeguards in light of their prospective acceptability. This study defines the economic, political and institutional nature of the safeguards problem; surveys generically alternative technical approaches to international safeguards including their effectiveness and relative development; characterizes the institutional implications and uncertainties associated with the acceptance and implementation of each technical alternative; and integrates these assessments into a set of overall judgments on feasible directions for reprocessing plant safeguards systems

International safeguards for reprocessing plants. Final report

Energy Technology Data Exchange (ETDEWEB)

Kratzer, M.; Scheinman, L.; Sievering, N.; Wonder, E.; Lipman, D.; Immerman, W.; Elliott, J.M.; Crane, F.

1981-04-01

Proliferation risks inherent in reprocessing show the need to employ technically effective safeguards which can detect, with a high degree of assurance and on a timely basis, the diversion of significant quantities of fissionable material. A balance must be struck between what is technically feasible and effective and what is institutionally acceptable. Purpose of this report is to examine the several technical approaches to safeguards in light of their prospective acceptability. This study defines the economic, political and institutional nature of the safeguards problem; surveys generically alternative technical approaches to international safeguards including their effectiveness and relative development; characterizes the institutional implications and uncertainties associated with the acceptance and implementation of each technical alternative; and integrates these assessments into a set of overall judgments on feasible directions for reprocessing plant safeguards systems.

Crud in the solvent extraction process for spent fuel reprocessing

International Nuclear Information System (INIS)

Chen Jing

2004-01-01

The crud occurred in Purex process is caused by the degradations of extractant and solvent and the existence of insoluble solid particle in the nuclear fuel reprocessing. The crud seriously affects the operation of the extraction column. The present paper reviews the study status on the crud in the Purex process. It is generally accepted that in the Purex process, particularly in the first cycle, the crud occurrence is related to the capillary chemistry phenomena resulting from the deposits of Zr with TBP degradation products HDBP, H 2 MBP, H 3 PO 4 and the insoluble particle RuO 2 and Pd. The occurrence of deposits and the type of crud are tightly related to the molar ratio of HDBP and Zr, and the aqueous pH. In addition, the effect of degradation products from the diluent, such as kerosene, is an unnegligible factor to cause the crud. The crud can be discharged from the extraction equipment with Na 2 CO 3 or oxalic acid. In the study on simulating the crud, the effects of the deposits of Zr with TBP degradation products HDBP, H 2 MBP and H 2 PO 4 , and the insoluble particle RuO 2 and Pd should be considered at the same time. (authors)

Nuclear energy without reprocessing: a future made possible by energy conservation

International Nuclear Information System (INIS)

Feiveson, Harold

1987-01-01

The achievements of energy conservation and the promise of future progress have rendered economically unattractive for many decades the separation of plutonium from spent reactor fuel (reprocessing) and its recycle into breeder or light water reactors. Despite this, reprocessing and recycle are already underway in Europe and Japan. If unchecked, these activities, by the end of the century, will lead to an annual flow in routine commerce of tens of thousands of kilograms of separated plutonium, a circumstance which would pose a grave threat to international security. However, continued stagnation of nuclear power programs in much of the world, due significantly to greatly reduced growth rates in electricity demand, will underscore the economic folly of reprocessing and recycle and may eventually encourage their abandonment. (author)

Quantitative analysis of residual protein contamination of podiatry instruments reprocessed through local and central decontamination units.

Science.gov (United States)

Smith, Gordon Wg; Goldie, Frank; Long, Steven; Lappin, David F; Ramage, Gordon; Smith, Andrew J

2011-01-10

The cleaning stage of the instrument decontamination process has come under increased scrutiny due to the increasing complexity of surgical instruments and the adverse affects of residual protein contamination on surgical instruments. Instruments used in the podiatry field have a complex surface topography and are exposed to a wide range of biological contamination. Currently, podiatry instruments are reprocessed locally within surgeries while national strategies are favouring a move toward reprocessing in central facilities. The aim of this study was to determine the efficacy of local and central reprocessing on podiatry instruments by measuring residual protein contamination of instruments reprocessed by both methods. The residual protein of 189 instruments reprocessed centrally and 189 instruments reprocessed locally was determined using a fluorescent assay based on the reaction of proteins with o-phthaldialdehyde/sodium 2-mercaptoethanesulfonate. Residual protein was detected on 72% (n = 136) of instruments reprocessed centrally and 90% (n = 170) of instruments reprocessed locally. Significantly less protein (p podiatry instruments when protein contamination is considered, though no significant difference was found in residual protein between local decontamination unit and central decontamination unit processes for Blacks files. Further research is needed to undertake qualitative identification of protein contamination to identify any cross contamination risks and a standard for acceptable residual protein contamination applicable to different instruments and specialities should be considered as a matter of urgency.

Hybrid KED/XRF measurement of minor actinides in reprocessing plants

International Nuclear Information System (INIS)

Hsue, S.T.; Collins, M.L.

1996-01-01

Minor actinides have received considerable attention recently in the nuclear power industry. Because of their potential value as recycle fuels in thermal and breeder reactors, reprocessing plants may have an economic incentive to extract Np, Am, and Cm from their waste streams. This report discusses the technique of hybrid densitometry and its potential to measure Np and Am in reprocessing plants. Precision estimates are made for the hybrid analysis of Np and Am in two types of dissolver solutions

Fuel reprocessing data validation using the isotope correlation technique

International Nuclear Information System (INIS)

Persiani, P.J.; Bucher, R.G.; Pond, R.B.; Cornella, R.J.

1990-01-01

The Isotope Correlation Technique (ICT), in conjunction with the gravimetric (Pu/U ratio) method for mass determination, provides an independent verification of the input accountancy at the dissolver or accountancy stage of the reprocessing plant. The Isotope Correlation Technique has been applied to many classes of domestic and international reactor systems (light-water, heavy-water, and graphite reactors) operating in a variety of modes (power, research, and production reactors), and for a variety of reprocessing fuel cycle management strategies. Analysis of reprocessing operations data based on isotopic correlations derived for assemblies in a PWR environment and fuel management scheme, yielded differences between the measurement-derived and ICT-derived plutonium mass determinations of (- 0.02 ± 0.23)% for the measured U-235 and (+ 0.50 ± 0.31)% for the measured Pu-239, for a core campaign. The ICT analyses has been implemented for the plutonium isotopics in a depleted uranium assembly in a heavy-water, enriched uranium system and for the uranium isotopes in the fuel assemblies in light-water, highly-enriched systems

Review of recent ORNL studies in solvent cleanup and diluent degradation. Consolidated Fuel-Reprocessing Program

International Nuclear Information System (INIS)

Mailen, J.C.; Tallent, O.K.

1982-01-01

Testing of solvent cleanup methods to replace the use of sodium carbonate in the Purex process has been ongoing for several years in order to reduce the quantity of waste sodium nitrate generated and to improve phase separation. Alternate solvent cleanup methods include the use of packed columns of base-treated silica gel or solvent scrubbing with hydrazine oxalate. Degradation of the diluent was shown to generate long-chain organic acids which appear to be the major culprits in the phase separation problems encountered in sodium carbonate scrubbers. Solvent scrubbing with hydrazine oxalate gives improved phase separations. Solvent cleanup in columns packed with base-treated silica gel avoids the phase separation problem since a dispersable aqueous phase is not present. Removals of TBP degradation products and metal-ion complexes by sodium carbonate, hydrazine salts, or by packed beds of base-treated silica gel are all satisfactory. Solvent scrubbing by hydrazine oxalate solutions is the prime candidate for solvent cleanup in fuel reprocessing plants

Advanced and sustainable fuel cycles for innovative reactor systems

International Nuclear Information System (INIS)

Glatz, J. P.; Malmbeck, R.; Purroy, D. S.; Soucek, P.; Inoue, T.; Uozumi, K.

2007-01-01

The key objective of nuclear energy systems of the future as defined by the Generation IV road map is to provide a sustainable energy generation for the future. It includes the requirement to minimize the nuclear waste produced and thereby notably reduce the long term stewardship burden in the future. It is therefore evident that the corresponding fuel cycles will play a central role in trying to achieve these goals by creating clean waste streams which contain almost exclusively the fission products. A new concept based on a grouped separation of actinides is widely discussed in this context, but it is of course a real challenge to achieve this type of separation since technologies available today have been developed to separate actinides from each other. In France, the CEA has launched extensive research programs in the ATALANTE facility in Marcoule to develop the advanced fuel cycles for new generation reactor systems. In this so called global actinide management (GAM) concept, the actinides are extracted in a sequence of chemical reactions (grouped actinide extraction (GANEX)) and immediately reintroduced in the fuel fabrication process is to use all actinides in the energy production process. The new group separation processes can be derived as in this case from aqueous techniques but also from so-called pyrochemical partitioning processes. Significant progress was made in recent years for both routes in the frame of the European research projects PARTNEW, PYROREP and EUROPART, mainly devoted to the separation of minor actinides in the frame of partitioning and transmutation (P and T) studies. The fuels used in the new generation reactors will be significantly different from the commercial fuels of today. Because of the fuel type and the very high burn-ups reached, pyrometallurgical reprocessing could be the preferred method. The limited solubility of some of the fuel materials in acidic aqueous solutions, the possibility to have an integrated irradiation and

Efficiency of Advanced H2O2/ZnO Oxidation Process in Ceftriaxone Antibiotic Removal from Aqueous Solutions

Directory of Open Access Journals (Sweden)

Maryam Noroozi cholcheh

2017-11-01

Full Text Available A major concern about pharmaceutical pollution is the presence of antibiotics in water resources through their release into sewers where they cause bacterial resistance and enhanced drug-resistance in human-borne pathogens and growing microbial populations in the environment. The objective of this study was to investigate the efficiency of  the advanced H2O2/ZnO oxidation process in removing ceftriaxone from aqueous solutions. For this purpose, an experimental study was conducted in which the SEM, XRD, and TEM techniques were employed to determine the size of Zinc oxide nano-particles. Additionally, the oxidation process parameters of pH (3-11, molar ratio of H2O2/ZnO (1.5-3, initial concentration of ceftriaxone (5–15 mg/L, and contact time (30-90 min were investigated. Teh data thus obntained were subjected top statistical analysis using the SPSS (ANOVA test. XRD results revealeda hexagonal crystal structure for the nano-ZnO. TEM images confirmed the spherical shape of the nanoparticles. Finally, SEM images revealed that the Zn nanoparticles used in this study were less than 30 nanometers in diameter. Based on the results, an optimum pH of 11, a contact time of 90 minutes, and a H2O2/ZnO molar ratio equal to 1.5 were the optimum conditions to achieve a ceftriaxone removal efficiency of 92%. The advance H2O2/ZnO oxidation process may thus be claimed to be highly capable of removing ceftriaxone from aqueous solutions.

Historical fuel reprocessing and HLW management in Idaho

International Nuclear Information System (INIS)

Knecht, D.A.; Staiger, M.D.; Christian, J.D.

1997-01-01

This article review some of the key decision points in the historical development of spent fuel reprocessing and waste management practices at the Idaho Chemical Processing Plant that have helped ICPP to successfully accomplish its mission safely and with minimal impact on the environment. Topics include ICPP reprocessing development; batch aluminum-uranium dissolution; continuous aluminum uranium dissolution; batch zirconium dissolution; batch stainless steel dissolution; semicontinuous zirconium dissolution with soluble poison; electrolytic dissolution of stainless steel-clad fuel; graphite-based rover fuel processing; fluorinel fuel processing; ICPP waste management consideration and design decisions; calcination technology development; ICPP calcination demonstration and hot operations; NWCF design, construction, and operation; HLW immobilization technology development. 80 refs., 4 figs

Survey of economics of spent nuclear fuel reprocessing

International Nuclear Information System (INIS)

Valvoda, Z.

1976-01-01

Literature data are surveyed on the economic problems of reprocessing spent fuel from light-water reactors in the period 1970 to 1975 and on the capacity of some reprocessing plants, such as NFS, Windscale, Marcoule, etc. The sharp increase in capital and production costs is analyzed and the future trend is estimated. The question is discussed of the use of plutonium and the cost thereof. The economic advantageousness previously considered to be the primary factor is no longer decisive due to new circumstances. The main objective today is to safeguard uninterrupted operation of nuclear power plants and the separation of radioactive wastes from the fuel cycle and the safe disposal thereof. (Oy)

Remote handling in reprocessing plants

International Nuclear Information System (INIS)

Streiff, G.

1984-01-01

Remote control will be the rule for maintenance in hot cells of future spent fuel reprocessing plants because of the radioactivity level. New handling equipments will be developed and intervention principles defined. Existing materials, recommendations for use and new manipulators are found in the PMDS' documentation. It is also a help in the choice and use of intervention means and a guide for the user [fr

Spent fuel reprocessing system security engineering capability maturity model

International Nuclear Information System (INIS)

Liu Yachun; Zou Shuliang; Yang Xiaohua; Ouyang Zigen; Dai Jianyong

2011-01-01

In the field of nuclear safety, traditional work places extra emphasis on risk assessment related to technical skills, production operations, accident consequences through deterministic or probabilistic analysis, and on the basis of which risk management and control are implemented. However, high quality of product does not necessarily mean good safety quality, which implies a predictable degree of uniformity and dependability suited to the specific security needs. In this paper, we make use of the system security engineering - capability maturity model (SSE-CMM) in the field of spent fuel reprocessing, establish a spent fuel reprocessing systems security engineering capability maturity model (SFR-SSE-CMM). The base practices in the model are collected from the materials of the practice of the nuclear safety engineering, which represent the best security implementation activities, reflect the regular and basic work of the implementation of the security engineering in the spent fuel reprocessing plant, the general practices reveal the management, measurement and institutional characteristics of all process activities. The basic principles that should be followed in the course of implementation of safety engineering activities are indicated from 'what' and 'how' aspects. The model provides a standardized framework and evaluation system for the safety engineering of the spent fuel reprocessing system. As a supplement to traditional methods, this new assessment technique with property of repeatability and predictability with respect to cost, procedure and quality control, can make or improve the activities of security engineering to become a serial of mature, measurable and standard activities. (author)

Equilibrium constants in aqueous lanthanide and actinide chemistry from time-resolved fluorescence spectroscopy: The role of ground and excited state reactions

International Nuclear Information System (INIS)

Billard, I.; Luetzenkirchen, K.

2003-01-01

Equilibrium constants for aqueous reactions between lanthanide or actinide ions and (in-) organic ligands contain important information for various radiochemical problems, such as nuclear reprocessing or the migration of radioelements in the geosphere. We study the conditions required to determine equilibrium constants by time-resolved fluorescence spectroscopy measurements. Based on a simulation study it is shown that the possibility to determine equilibrium constants depends upon the reaction rates in the photoexcited states of the lanthanide or actinide ions. (orig.)

Extraction behavior of radionuclides in the first separation cycle in reprocessing

International Nuclear Information System (INIS)

Uchiyama, Gunzo; Asakura, Toshihide; Hotoku, Shinobu; Watanabe, Makio; Fujine, Sachio; Nemoto, Hideyuki.

1997-01-01

The chemical flowsheet experiment by using three mixer-settlers was conducted to study the extraction behavior of radionuclides such as technetium, neptunium, iodine, zirconium and ruthenium in the uranium-TBP-nitric acid solution system in the simulated first separation cycle in current reprocessing plants. The following results were obtained: More than 99.999% of the total uranium fed to the co-decontamination step in the simulated dissolver solution was extracted by TBP solvent. About 90% of the total uranium was recovered in the uranium back-extraction step. About 30% of the total neptunium fed to the co-decontamination step was in the raffinate solution in the co-decontamination step, 12% of the total neptunium was in the Tc solution in the Tc separation step and about 58% of the total neptunium was in the Pu solution in the U/Pu partitioning step. As for technetium, about 99% of the total technetium was extracted by TBP in the co-decontamination step, 86% of the total technetium was scrubbed with high acid nitric acid solution in the Tc separation step and 13% of the total technetium was in the Pu solution in the U/Pu partitioning step. As for the other radionuclides, 99% of the total ruthenium and 93% of the total zirconium were distributed into the raffinate in the co-decontamination step. In the Tc separation step, ruthenium was scrubbed more effectively than ruthenium with high acid solution. About 45% of the total iodine fed to the co-decontamination step was vaporized during the experiment. Iodine in aqueous solutions in the flowsheet was mainly in volatile I 2 form. Iodine was rarely distributed into the aqueous solution and was distributed with TBP solvent in the flowsheet. Significant amounts of iodine was contained in the washed solvent. (author)

EdF speaks about economic advantages of fuel reprocessing as compared with interim storage

International Nuclear Information System (INIS)

Anon.

1997-01-01

The French company Electricite de France (EdF) will prefer nuclear fuel reprocessing and plutonium recycling to spent fuel storage also in the years after 2000. This option is economically advantageous if the proportional cost of reprocessing does not exceed 1900 FRF/kg heavy metal. Economic analysis shows that this is feasible. EdF will soon have to reprocess annually about 1000 Mt spent fuel to supply enough plutonium for MOX fuel fabrication to feed as many as 28 PWR units and the Superphenix reactor. Spent fuel reprocessing is seen as promising as long as the efficiency of the MOX fuel approaches that of natural uranium based fuel. The French national industrial, political and legal context of EdF operations is also considered. (P.A.)

Integrated international safeguards concepts for fuel reprocessing

International Nuclear Information System (INIS)

Hakkila, E.A.; Gutmacher, R.G.; Markin, J.T.; Shipley, J.P.; Whitty, W.J.; Camp, A.L.; Cameron, C.P.; Bleck, M.E.; Ellwein, L.B.

1981-12-01

This report is the fourth in a series of efforts by the Los Alamos National Laboratory and Sandia National Laboratories, Albuquerque, to identify problems and propose solutions for international safeguarding of light-water reactor spent-fuel reprocessing plants. Problem areas for international safeguards were identified in a previous Problem Statement (LA-7551-MS/SAND79-0108). Accounting concepts that could be verified internationally were presented in a subsequent study (LA-8042). Concepts for containment/surveillance were presented, conceptual designs were developed, and the effectiveness of these designs was evaluated in a companion study (SAND80-0160). The report discusses the coordination of nuclear materials accounting and containment/surveillance concepts in an effort to define an effective integrated safeguards system. The Allied-General Nuclear Services fuels reprocessing plant at Barnwell, South Carolina, was used as the reference facility

Advanced teleoperation in nuclear applications

International Nuclear Information System (INIS)

Hamel, W.R.; Feldman, M.J.; Martin, H.L.

1984-01-01

A new generation of integrated remote maintenance systems is being developed to meet the needs of future nuclear fuel reprocessing at the Oak Ridge National Laboratory. Development activities cover all aspects of an advanced teleoperated maintenance system with particular emphasis on a new force-reflecting servomanipulator concept. The new manipulator, called the advanced servomanipulator, is microprocessor controlled and is designed to achieve force-reflection performance near that of mechanical master/slave manipulators. The advanced servomanipulator uses a gear-drive transmission which permits modularization for remote maintainability (by other advanced servomanipulators) and increases reliability. Human factors analysis has been used to develop an improved man/machine interface concept based upon colorgraphic displays and menu-driven tough screens. Initial test and evaluation of two advanced servomanipulator slave arms and several other development components have begun. 9 references, 5 figures

Ecological risk of reprocessing of uranium wastes of the Gafurov's tailing pit

International Nuclear Information System (INIS)

Khakimov, N.; Nazarov, Kh.M.; Kamalov, D.D.; Mirsaidov, U.M.

2010-01-01

Present article is devoted to assessment ecological risk of reprocessing of uranium wastes of the Gafurov's tailing pit. Authors set as their purpose the investigation of ecological risk of reprocessing of uranium wastes of the Gafurov-city's tailing pit. Having carried out their investigations, the authors came to the conclusion that the effect of radon gas during reprocessing to workers and specialists is minimal if they follow all the required safety rules.

A rapid method to estimate uranium using ionic liquid as extracting agent from basic aqueous media

International Nuclear Information System (INIS)

Prabhath Ravi, K.; Sathyapriya, R.S.; Rao, D.D.; Ghosh, S.K.

2016-01-01

Room temperature ionic liquids, as their name suggests are salts with a low melting point typically less than 100 °C and exist as liquid at room temperature. The common cationic parts of ionic liquids are imidazolium, pyridinium, pyrrolidinium, quaternary ammonium, or phosphonium ions, and common anionic parts are chloride, bromide, boron tetrafluorate, phosphorous hexafluorate, triflimide etc. The physical properties of ionic liquids can be tuned by choosing appropriate cations with differing alkyl chain lengths and anions. Application of ionic liquids in organic synthesis, liquid-liquid extractions, electrochemistry, catalysis, speciation studies, nuclear reprocessing is being studied extensively in recent times. In this paper a rapid method to estimate the uranium content in aqueous media by extraction with room temperature ionic liquid tricaprylammoniumthiosalicylate ((A- 336)(TS)) followed by liquid scintillation analysis is described. Re-extraction of uranium from ionic liquid phase to aqueous phase was also studied

Environmental assessment for Breeder Reprocessing Engineering Test (BRET): Revision 1

International Nuclear Information System (INIS)

Lerch, R.E.

1989-03-01

This Environmental Assessment (EA) is for the proposed installation and operation of an integrated breeder fuel reprocessing test system in the shielded cells of the Fuels and Materials Examination Facility (FMEF) at Hanford and the associated modifications to the FMEF to accommodate BRET. These modifications would begin in FY-1986 subject to Congressional authorization. Hot operations would be scheduled to start in the early 1990's. The system, called the Breeder Reprocessing Engineering Test (BRET), is being designed to provide a test capability for developing the demonstrating fuel reprocessing, remote maintenance, and safeguards technologies for breeder reactor fuels. This EA describes (1) the action being proposed, (2) the existing environment which would be affected, (3) the potential environmental impacts from normal operations and severe accidents from the proposed action, (4) potential conflicts with federal, state, regional, and/or local plans for the area, and (5) environmental implications of alternatives considered to the proposed action. 41 refs., 10 figs., 31 tabs

Status of the decommissioning program of the Eurochemic reprocessing plant

International Nuclear Information System (INIS)

Detilleux, E.J.

1976-01-01

Reprocessing operations at the Eurochemic demonstration plant stopped in December 1974, after 8 years of operation. Immediately thereafter, cleaning and decontamination were begun as the first phase of the decommissioning program. The facility and reprocessing program are described to indicate the magnitude of the problem, and the requirements of the local authorities are reviewed. The technical decommissioning program consists of several phases: (1) plant cleaning and rinsing, (2) establishment of the final fissile-material balance, (3) plant decontamination for access to process equipment, (4) equipment dismantling, and (5) conditioning and storage of newly generated wastes. The two first phases have been completed, and the third one is nearing completion. Some dismantling has been performed, including the plutonium dioxide production unit. Waste-conditioning and surface-storage facilities have been built to meet the dismantling requirements. Since reprocessing may be resumed in the future, decontamination has been performed with ''smooth'' reagents to limit corrosion and dismantling has been limited to subfacilities

TASTEX: Tokai Advanced Safeguards Technology Exercise

International Nuclear Information System (INIS)

1982-01-01

During the years 1978 to 1981 the Governments of France, Japan and the United States of America cooperated with the International Atomic Energy Agency in the TASTEX (Tokai Advanced Safeguards Technology Exercise) programme. The aim of this programme was to improve the technology for the application of international safeguards at reprocessing facilities, and the results are presented in the present report

Irradiated uranium reprocessing; Prerada ozracenog urana

Energy Technology Data Exchange (ETDEWEB)

Gal, I [Institute of Nuclear Sciences Boris Kidric, Laboratorijaza visoku aktivnost, Vinca, Beograd (Serbia and Montenegro)

1961-12-15

Task concerned with reprocessing of irradiated uranium covered the following activities: implementing the method and constructing the cell for uranium dissolving; implementing the procedure for extraction of uranium, plutonium and fission products from radioactive uranium solutions; studying the possibilities for using inorganic ion exchangers and adsorbers for separation of U, Pu and fission products.

Nuclear energy without waste reprocessing in West Germany?

International Nuclear Information System (INIS)

Ebert, K.

1989-01-01

The decision to discontinue construction of the Wackersdorf waste reprocessing plant has been an item of public interest for only a short period; even supporters of nuclear power seemed to have been just relieved that this controversial project was off the agenda, and done with. So only little was to be heard from experts about the facts, background, and consequences of this decision. The author of the article in hand is head of the Hot Chemistry Institute of the Karlsruhe Nuclear Research Centre and therefore has been a leading scientist in the development of reprocessing technology. He presents from his point of view the facts and reasons leading to the decision, and explains the possible consequences for the F.R.G. (orig./RB) [de

Reprocessing seismic data: better results below diabase sills

Energy Technology Data Exchange (ETDEWEB)

Makler, Marisa [Halliburton Servicos Ltda., Rio de Janeiro, RJ (Brazil); Pellizzon, Marcela

2008-07-01

The effect of the diabase sills in the seismic data processing has been studied in the last twenty years. These rocks strongly influence the exploratory activities in a basin, because the diabase disturbs the sign and generates multiple and spherical divergence, increasing the exploratory risk in these areas. In the present work a method of 2D seismic reprocessing will be presented using Prestack Kirchhoff Time Migration in an older seismic data of Solimoes basin. The objective of this paper is to show the high results on the reprocessing seismic data below the diabase sills. The 2D lines processed give relevant improvement of the quality of signal, showing better the faults zones and preserving the geological structures than the older data. (author)

Chemical engineering in fuel reprocessing. The French experience

International Nuclear Information System (INIS)

Viala, M.; Sombret, C.; Bernard, C.; Miquel, P.; Moulin, J.P.

1992-01-01

Reprocessing is the back-end of the nuclear fuel cycle, designed to recover valuable fissile materials, especially plutonium, and to condition safely all the wastes ready for disposal. For its new commercial reprocessing plants (UP 3 and UP 2 800) COGEMA decided to include many engineering innovations as well as new processes and key-components developed by CEA. UP 3 is a complete new plant with a capacity of 800 t/y which was put in operation in August 1990. UP 2 800 is an extension of the existing UP 2 facility, designed to achieve the same annual capacity of 800 t/y, to be put in operation at the end of 1993 by the commissioning of a new head-end and highly active chemical process facilities

Advanced High-Voltage Aqueous Lithium-Ion Battery Enabled by "Water-in-Bisalt" Electrolyte.

Science.gov (United States)

Suo, Liumin; Borodin, Oleg; Sun, Wei; Fan, Xiulin; Yang, Chongyin; Wang, Fei; Gao, Tao; Ma, Zhaohui; Schroeder, Marshall; von Cresce, Arthur; Russell, Selena M; Armand, Michel; Angell, Austen; Xu, Kang; Wang, Chunsheng

2016-06-13

A new super-concentrated aqueous electrolyte is proposed by introducing a second lithium salt. The resultant ultra-high concentration of 28 m led to more effective formation of a protective interphase on the anode along with further suppression of water activities at both anode and cathode surfaces. The improved electrochemical stability allows the use of TiO2 as the anode material, and a 2.5 V aqueous Li-ion cell based on LiMn2 O4 and carbon-coated TiO2 delivered the unprecedented energy density of 100 Wh kg(-1) for rechargeable aqueous Li-ion cells, along with excellent cycling stability and high coulombic efficiency. It has been demonstrated that the introduction of a second salts into the "water-in-salt" electrolyte further pushed the energy densities of aqueous Li-ion cells closer to those of the state-of-the-art Li-ion batteries. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Comparison of the waste management aspects of spent fuel disposal and reprocessing: post-disposal radiological impact

International Nuclear Information System (INIS)

Mobbs, S.F.; Harvey, M.P.; Martin, J.S.; Mayall, A.; Jones, M.E.

1991-01-01

A joint project involving contractors from France, Germany and the UK was set up by the Commission of the European Communities to assess the implications of two waste management options: the direct disposal of spent fuel and reprocessing of that fuel. This report describes the calculation of the radiological impact on the public of the management and disposal of the wastes associated with these two options. Six waste streams were considered: discharge of liquid reprocessing effluents, discharge of gaseous reprocessing effluents, disposal of low-level solid wastes arising from reprocessing, disposal of intermediate-level solid wastes arising from reprocessing, disposal of vitrified high-level reprocessing wastes, and direct disposal of spent fuel. The results of the calculations are in the form of maximum annual doses and risks to individual members of the public, and collective doses to four population groups, integrated over six time periods. These results were designed for input into a computer model developed by another contractor, Yard Ltd, which combines costs and impacts in a multi-attribute hierarchy to give an overall measure of the impact of a given option

Access control system for two person rule at Rokkasho Reprocessing Plant

International Nuclear Information System (INIS)

Yanagisawa, Sawako; Ino, Munekazu; Yamada, Noriyuki; Oota, Hiroto; Iwasaki, Mitsuaki; Kodani, Yoshiki; Iwamoto, Tomonori

2014-01-01

Following the amendment and enforcement of Regulation of Reprocessing Activity on March 29th 2012, two person rule has become compulsory for the specific rooms to counter and prevent the sabotage or theft of nuclear materials by the insiders at reprocessing plant in Japan. The rooms will include those which contains cooling systems for decay heat removal from spent fuels and so on, scavenging systems to prevent the hydrogen accumulation, and those which contains nuclear material. To ensure the two person rule at Rokkasho Reprocessing Plant, JNFL has recently, after comprehensive study, introduced efficient and effective access control system for the rooms mentioned above. The system is composed of bio-attestation devices, surveillance cameras and electronic locks to establish access control system. This report outlines the access control system for two person rule and introduces the operation. (author)

Results from the JPL IGS Analysis Center IGS14 Reprocessing Campaign

Science.gov (United States)

Ries, P. A.; Amiri, N.; Heflin, M. B.; Sakumura, C.; Sibois, A. E.; Sibthorpe, A.; David, M. W.

2017-12-01

The JPL IGS analysis center has begun a campaign to reprocess GPS orbits and clocks in the IGS14 reference frame. Though the new frame is only a few millimeters offset from the previous IGb08 frame, a reprocessing is required for consistent use of the new frame due to a change in the satellite phase center offsets between the frames. We will present results on the reprocessing campaign from 2002 to present in order to evaluate any effects caused by the new frame. We also create long-term time-series and periodograms of translation, rotation, and scale parameters to see if there is any divergence between the frames. We will also process long-term PPP time series and derived velocities for a well-distributed set of stations in each frame to compare with the published frame offsets.

Economic evaluation of reprocessing

International Nuclear Information System (INIS)

1979-02-01

This paper presents a progress report of work undertaken relevant to the economic evaluation of reprocessing. It sets out the assumptions to be made for the preparation of the economic ''phase diagram'' - a plot of fast reactor premium against uranium (U 3 O 8 ) price. The paper discusses the assumptions to be made in respect of present worth methodology, LWR fuel logistics, U 3 O 8 price, enrichment tails, plutonium values, fast reactor premium and proposes a set of reference costs to be used for the preparation of the phase diagram

Features in the aspect of materials in reprocessing plants

International Nuclear Information System (INIS)

Tanaka, Toshikazu; Suzuki, Kazuhiro

1992-01-01

The process of the reprocessing plant installed in Rokkasho, Aomori Prefecture, by Japan Nuclear Fuel Service Co., Ltd. is the Purex wet process experienced in Japan and abroad, and which can obtain the uranium and plutonium products of high purity at high recovery rate. This process is to melt spent fuel with nitric acid, and extract and separate uranium, plutonium and fission products from the obtained solution by utilizing the difference in chemical properties. The yearly amount of treatment of the reprocessing plant of this company is 800 t uranium. In order to ensure the safety in the reprocessing plant that handles the solution with high radioactivity, the function of confining radioactive substances in definite areas is demanded. For the purpose, the machinery, equipment and piping containing radioactive substances are made of the materials having the corrosion resistance against nitric acid, and welded structure is adopted to prevent leakage. Negative pressure is maintained in waste gas treatment facilities in relation to cells, and in the cells in relation to the building. The outline of the facilities, the materials of the main machinery and equipment, and the applied technologies are reported. (K.I.)

Reprocessing free nuclear fuel production via fusion fission hybrids

Energy Technology Data Exchange (ETDEWEB)

Kotschenreuther, Mike, E-mail: mtk@mail.utexas.edu [Intitute for Fusion Studies, University of Texas at Austin (United States); Valanju, Prashant; Mahajan, Swadesh [Intitute for Fusion Studies, University of Texas at Austin (United States)

2012-05-15

Fusion fission hybrids, driven by a copious source of fusion neutrons can open qualitatively 'new' cycles for transmuting nuclear fertile material into fissile fuel. A totally reprocessing-free (ReFree) Th{sup 232}-U{sup 233} conversion fuel cycle is presented. Virgin fertile fuel rods are exposed to neutrons in the hybrid, and burned in a traditional light water reactor, without ever violating the integrity of the fuel rods. Throughout this cycle (during breeding in the hybrid, transport, as well as burning of the fissile fuel in a water reactor) the fissile fuel remains a part of a bulky, countable, ThO{sub 2} matrix in cladding, protected by the radiation field of all fission products. This highly proliferation-resistant mode of fuel production, as distinct from a reprocessing dominated path via fast breeder reactors (FBR), can bring great acceptability to the enterprise of nuclear fuel production, and insure that scarcity of naturally available U{sup 235} fuel does not throttle expansion of nuclear energy. It also provides a reprocessing free path to energy security for many countries. Ideas and innovations responsible for the creation of a high intensity neutron source are also presented.

Reprocessing free nuclear fuel production via fusion fission hybrids

International Nuclear Information System (INIS)

Kotschenreuther, Mike; Valanju, Prashant; Mahajan, Swadesh

2012-01-01

Fusion fission hybrids, driven by a copious source of fusion neutrons can open qualitatively “new” cycles for transmuting nuclear fertile material into fissile fuel. A totally reprocessing-free (ReFree) Th 232 –U 233 conversion fuel cycle is presented. Virgin fertile fuel rods are exposed to neutrons in the hybrid, and burned in a traditional light water reactor, without ever violating the integrity of the fuel rods. Throughout this cycle (during breeding in the hybrid, transport, as well as burning of the fissile fuel in a water reactor) the fissile fuel remains a part of a bulky, countable, ThO 2 matrix in cladding, protected by the radiation field of all fission products. This highly proliferation-resistant mode of fuel production, as distinct from a reprocessing dominated path via fast breeder reactors (FBR), can bring great acceptability to the enterprise of nuclear fuel production, and insure that scarcity of naturally available U 235 fuel does not throttle expansion of nuclear energy. It also provides a reprocessing free path to energy security for many countries. Ideas and innovations responsible for the creation of a high intensity neutron source are also presented.

Coordinated safeguards for materials management in a fuel reprocessing plant. Volume I

International Nuclear Information System (INIS)

Hakkila, E.A.; Cobb, D.D.; Dayem, H.A.; Dietz, R.J.; Kern, E.A.; Schelonka, E.P.; Shipley, J.P.; Smith, D.B.; Augustson, R.H.; Barnes, J.W.

1977-09-01

A materials management system is described for safeguarding special nuclear materials in a fuel-reprocessing plant. Recently developed nondestructive-analysis techniques and process-monitoring devices are combined with conventional chemical analyses and process-control instrumentation for improved materials accounting data. Unit-process accounting based on dynamic material balances permits localization of diversion in time and space, and the application of advanced statistical methods supported by decision-analysis theory ensures optimum use of accounting information for detecting diversion. This coordinated safeguards system provides maximum effectiveness consistent with modest cost and minimum process interference. Modeling and simulation techniques are used to evaluate the sensitivity of the system to single and multiple thefts and to compare various safeguards options. The study identifies design criteria that would improve the safeguardability of future plants

Waste Minimization Study on Pyrochemical Reprocessing Processes

International Nuclear Information System (INIS)

Boussier, H.; Conocar, O.; Lacquement, J.

2006-01-01

Ideally a new pyro-process should not generate more waste, and should be at least as safe and cost effective as the hydrometallurgical processes currently implemented at industrial scale. This paper describes the thought process, the methodology and some results obtained by process integration studies to devise potential pyro-processes and to assess their capability of achieving this challenging objective. As example the assessment of a process based on salt/metal reductive extraction, designed for the reprocessing of Generation IV carbide spent fuels, is developed. Salt/metal reductive extraction uses the capability of some metals, aluminum in this case, to selectively reduce actinide fluorides previously dissolved in a fluoride salt bath. The reduced actinides enter the metal phase from which they are subsequently recovered; the fission products remain in the salt phase. In fact, the process is not so simple, as it requires upstream and downstream subsidiary steps. All these process steps generate secondary waste flows representing sources of actinide leakage and/or FP discharge. In aqueous processes the main solvent (nitric acid solution) has a low boiling point and evaporate easily or can be removed by distillation, thereby leaving limited flow containing the dissolved substance behind to be incorporated in a confinement matrix. From the point of view of waste generation, one main handicap of molten salt processes, is that the saline phase (fluoride in our case) used as solvent is of same nature than the solutes (radionuclides fluorides) and has a quite high boiling point. So it is not so easy, than it is with aqueous solutions, to separate solvent and solutes in order to confine only radioactive material and limit the final waste flows. Starting from the initial block diagram devised two years ago, the paper shows how process integration studies were able to propose process fittings which lead to a reduction of the waste variety and flows leading at an 'ideal

Effect of Reprocessing and Excipient Characteristics on Ibuprofen ...

African Journals Online (AJOL)

Methods: The effect of excipient type, technology and reprocessing on flow, compressibility and compactibility was ... granulation technology is used, the ... powders improve particle size distribution, .... 8.04 (Stat-Easy Inc., Minneapolis, USA).

Separation of mobile long-lived nuclides in a simplified reprocessing

International Nuclear Information System (INIS)

Fujine, Sachio; Uchiyama, Gunzo; Kihara, Takehiro; Asakura, Toshihide; Sakurai, Tsutomu

1997-01-01

Enhancing confinement efficiency of long-lived nuclides in a simplified Purex process is the primary subject of our PARC (Partitioning Conundrum Key) R and D project. Nuclides focused here are all susceptible to diffuse into the environment and highly concerned as potential hazard among the long-lived nuclides in spent fuels. New functions in PARC concept are designed to mitigate the environmental impacts of reprocessing wastes and also to improve the economy of reprocessing in the future. Experimental work has been conducted to demonstrate the feasibility of the concept. (author)

Report of the LASCAR forum: Large scale reprocessing plant safeguards

International Nuclear Information System (INIS)

1992-01-01

This report has been prepared to provide information on the studies which were carried out from 1988 to 1992 under the auspices of the multinational forum known as Large Scale Reprocessing Plant Safeguards (LASCAR) on safeguards for four large scale reprocessing plants operated or planned to be operated in the 1990s. The report summarizes all of the essential results of these studies. The participants in LASCAR were from France, Germany, Japan, the United Kingdom, the United States of America, the Commission of the European Communities - Euratom, and the International Atomic Energy Agency

Administrative and managerial controls for the operation of nuclear fuel reprocessing plants

International Nuclear Information System (INIS)

Anon.

1979-01-01

Guidelines are provided for the administrative and managerial controls necessary for the safe and efficient operation of nuclear fuel reprocessing plants. Topics covered include: administrative organization; review and audit; facility administrative policies and procedures; and tests and inspections. Recognizing that administrative practices vary among organizations operating nuclear fuel reprocessing plants, the standard incorporates flexibility that provides for compliance by any organization

Reprocessed uranium recycling: the ideal and the facts

International Nuclear Information System (INIS)

Comte, D.

1998-01-01

Commercial reprocessing of Light Water Reactor (LWR) spent fuel provides Reprocessed Uranium (RepU) and plutonium, both products containing a large amount of energy. As the gap, already quite large, between uranium consumption and production threatens to grow, these materials show today a strong strategic benefit, constituting a substantial and reliable source of supply for nuclear fuel manufacturing. RepU, which represents about 96% of recycled materials, can be used in all major types of nuclear power reactor currently in operation. This paper focuses on RepU recycling in LWRs, the feasibility of which is technically well established world-wide, and industrially demonstrated through experience gained within the COGEMA Group. Contrary to a commonly accepted assumption, which probably derives from natural uranium prices remaining for more than a decade at a low level which cannot be sustained into the future, recycling RepU can also bring strong economic benefits to the utilities. It generates savings on uranium procurement that exceed expenditures associated with storing and processing RepU. Thus, the use of this product is an attractive option. The strategic and economic benefits of recycling RepU will become compelling in the near future. Anticipating these needs, the COGEMA Group has developed capabilities to offer utilities the services covering all steps from reprocessing of spent fuel to fuel fabrication using RepU. (author)

Green light for Japanese reprocessing

International Nuclear Information System (INIS)

Patermann, C.

1981-01-01

In the last few years, international discussions of peaceful nuclear energy use and non-proliferation have been greatly influenced by the attitude of the US Government. Since the mid-Seventies, in the Carter area, this attitude has changed due to the fear that world-wide use of so-called sensitive technologies, i.e. uranium enrichment, reprocessing, and fast breeder development may increase the hazard of misuse for the production of nuclear weapons. (orig.) [de

Status and trends in spent fuel reprocessing. Proceedings of an advisory group meeting

International Nuclear Information System (INIS)

1999-08-01

Spent fuel management has always been an important part of the nuclear fuel cycle and is still one of the most important activities in all countries exploiting the peaceful use of nuclear energy. Continuous attention is being given by the IAEA to the collection, analysis and exchange of information on spent fuel management. Its role in this area is to provide a forum for exchanging information and to coordinate and encourage closer co-operation among Member States in certain research and developing activities that are of common interest. As part of spent fuel management, reprocessing activities have been reviewed from time to time on a low profile level under the terminology 'spent fuel treatment'. However, spent fuel treatment covers, in broad terms, spent fuel storage (short, interim and long term), fuel rod consolidation, reprocessing and, in case the once-through cycle is selected, conditioning of the spent fuel for disposal. Hence the reprocessing activities under the heading 'spent fuel treatment' were somewhat misleading. Several meetings on spent fuel treatment have been organized during the fast decade: an Advisory Group meeting (AGM) in 1992, a Technical Committee meeting in 1995 and recently an Advisory Group meeting from 7 to 10 September 1998. The objectives of the meetings were to review the status and trends of spent fuel reprocessing, to discuss the environmental impact and safety aspects of reprocessing facilities and to define the most important issues in this field. Notwithstanding the fact that the Summary of the report does not include aspects of military reprocessing, some of the national presentations do refer to some relevant aspects (e.g. experience, fissile stockpiles)

Measurement of actinide concentration in solution samples from the NUCEF reprocessing facility by X-ray and low energy gamma-ray spectroscopy

International Nuclear Information System (INIS)

Howarth, P.J.A.; Uchiyama, Gunzo; Asakura, Toshihide; Sawada, Mutsumi; Hagiya, Hiromichi; Fujine, Sachio

1999-01-01

X-ray and low-energy gamma-ray spectroscopy has been used to measure actinide concentration within the backend nuclear fuel reprocessing research facility at NUCEF. Research on advanced reprocessing techniques at NUCEF is based on the PARC refinement of the PUREX process which aims to recover Am and Cm from the highly active waste stream and to control and partition Np and Tc. It is hoped that the PARC process will mitigate the environmental impact of the wastes and improve the economy of reprocessing. The main actinides for which assay is required are U, Pu, Np and Am and knowledge of these concentrations will enable the following to be determined: i.) evaluation of the distribution of actinides throughout the reprocessing facility ii.) verification of the simulated actinide distribution from chemical kinetic simulations of the PARC process and iii.) assurance of safety and control over migrant radioactive species. The research presented here shows that passive measurement of x-rays and low-energy gamma-rays from solution samples provides an accurate and non-destructive means for assaying the concentration. The measurement technique is based on the use of the characteristic low energy gamma-rays and internal conversion x-ray emission from actinides (11 keV to 22 keV). The x-ray emission is a few orders of magnitude more intense than the characteristic gamma-ray emission and can be easily detected from solutions. The experimental system described here can be used for solution monitoring to a minimum concentration of typically 10-6 M for Pu, 10-10 M for Am and 10-6 M for Np. (author)

Framework conditions and requirements to ensure the technical functional safety of reprocessed medical devices.

Science.gov (United States)

Kraft, Marc

2008-09-03

Testing and restoring technical-functional safety is an essential part of medical device reprocessing. Technical functional tests have to be carried out on the medical device in the course of the validation of reprocessing procedures. These ensure (in addition to the hygiene tests) that the reprocessing procedure is suitable for the medical device. Functional tests are, however, also a part of reprocessing procedures. As a stage in the reprocessing, they ensure for the individual medical device that no damage or other changes limit the performance. When determining which technical-functional tests are to be carried out, the current technological standard has to be taken into account in the form of product-specific and process-oriented norms. Product-specific norms primarily define safety-relevant requirements. The risk management method described in DIN EN ISO 14971 is the basis for recognising hazards; the likelihood of such hazards arising can be minimised through additional technical-functional tests, which may not yet have been standardised. Risk management is part of a quality management system, which must be bindingly certified for manufacturers and processors of critical medical devices with particularly high processing demands by a body accredited by the competent authority.

Materials and coating technology for pyrochemical reprocessing applications

International Nuclear Information System (INIS)

Jayakumar, T.; Kamachi Mudali, U.

2013-01-01

Metallic fuelled fast breeder reactors with co-located pyrochemical reprocessing plants have been proposed as the best option in order to increase the breeding gain, reduce the doubling time of the fuel and reprocess short cooled and high burnup fuel. To establish the pyrochemical reprocessing plants with various unit operations, it is necessary to identify, develop and qualify reliable corrosion resistant materials and coatings for service in molten LiCI-KCI salt and molten uranium environment operating at 773 to 1573 K. Towards materials and coating technology development and testing for molten salt environment a high temperature corrosion testing laboratory was established and studies were initiated. Molten salt test assembly for testing materials and coatings in molten LiCI-KCI salt under controlled ultra high pure (UHP) argon environment at high temperatures has been designed, fabricated, commissioned and tests were carried out on various candidate materials and coatings. Electro-formed (EF) Ni, Ni with Ni-W coating, coatings of ZrN, TiN, HfN and Ti-Si-N on high density (HD) graphite, candidate materials like 2.25Cr-1Mo steel, 9Cr-1Mo steel, 316L stainless steel, Ni base alloys (INCONEL 600, 625 and 690), HD graphite, pyrolytic graphite (PyG), and yttria stabilized zirconia (YSZ) and alumina-40wt% titania thermal barrier coatings were tested for their suitability for molten salt applications. Corrosion studies indicated that YSZ and PyG showed superior corrosion resistance in molten LiCI-KCI salt at 873 K up to 2000 h exposure. Surface modification techniques like annealing, laser remelting and laser shock processing were pursued to consolidate the coatings and improve their high temperature performance. Coating integrity using dielectric electrochemical system and thermal cycling furnace established that, compared to plain 9Cr-1Mo steel YSZ coated 9Cr-1Mo steel performed better from 473 K to 1223 K. The presentation highlights the results of the

Signal transmission techniques for large-scale nuclear fuel reprocessing applications

International Nuclear Information System (INIS)

Herndon, J.N.; Bible, D.W.

1985-01-01

The RCE is currently developing a prototypic microwave-based signal transmission system for reprocessing cell applications. This system, being developed for use in the Advanced Integrated Maintenance System (AIMS), will operate in the 10-GHz frequency range. Provisions are being made for five real-time video channels, three bidirectional data channels at one megabaud data rate each, and two audio channels. The basic utility of the concept has been proven in a laboratory demonstration using gallium arsenide gunn diode transmitter/receivers with horn antennas. Unidirectional transmission of one real-time video channel over a distance of 200 ft was demonstrated. No evidence of multipath interference was detected even when the transmission path was surrounded by metallic reflectors. The microwave signal transmission system for the AIMS application is in final design. Fabrication in the ORNL instrument shops will begin in October 1985, and the system should be operational in the Maintenance Systems Test Area (MSTA) at ORNL in the latter half of 1986

Determination of zirconium 93 and molybdenum 93 in reprocessing nuclear waste

International Nuclear Information System (INIS)

Puech, P.

1998-01-01

The aim of this work is to find new determination methods of zirconium 93 and molybdenum 93 (two long-lived radioelements) contained in reprocessing nuclear waste. 93 Zr has a very long period: 1.5 * 10 6 years. The measurement of this isotope is more performing by the ICP-MS method than by the classical radiochemical measurement methods. 93 Mo disintegrates with a radioactive period of 4000 years and can be detected by radiochemical measurement in particular by X spectrometry. But these radioelements cannot be directly measured on the reprocessing nuclear waste; they require a preliminary chemical separation (removing the radioelements able to interfere and those responsible of the radioactivity of the nuclear waste). The separation is implemented with very potentially selective techniques, using Mo and Zr specific extracting molecules: solvent extraction, emulsified liquid membrane extraction and liquid chromatography extraction (on a resin impregnated by solvent). Studies carried out in CEA/Cadarache, on a synthetic solution simulating a reprocessing nuclear waste, have allowed to show the selective properties of the L'-benzoinoxime for extracting Mo and of TBP for extracting Zr for the three studied techniques. The optimal extraction and separation conditions have been reached with a methodology including experiment plans. At last, the methods have been tested on real reprocessing nuclear waste at Cogema/La Hague. 93 Zr and 93 Mo have been measured in a dissolution solution and in a fission product solution. The obtained values are 2 * 10 6 Bq/l and 10 7 Bq/l for 93 Zr and 500 Bq/l for 93 Mo in a dissolution solution. These methods have allowed to determine too the isotopic compositions for Mo and Zr elements contained in reprocessing nuclear waste. The results are in accordance with those obtained with the Cesar code. (O.M.)

International cooperation in the field of reprocessing

International Nuclear Information System (INIS)

Busekist, O. von

1983-01-01

Following a definition of the concept of international cooperation, this paper discusses existing and possible legal and institutional arrangements in the reprocessing field, with particular reference to the legal framework set up for the European Company for the Chemical Processing of Irradiated Fuels (Eurochemic). (NEA) [fr

Fuel reprocessing: Citizens' questions and experts' answers

International Nuclear Information System (INIS)

1982-10-01

In connection with the intention of DWK to erect a fuel reprocessing plant in the Oberpfalz, citizens have asked a great number of questions which are of interest to the general public. They have been collected, grouped into subject categories and answered by experts. (orig./HSCH) [de

Development of some operations in technological flowsheet for spent VVER fuel reprocessing at a pilot plant

International Nuclear Information System (INIS)

Lazarev, L.N.; Galkin, B.Ya; Lyubtsev, R.I.; Romanovskii, V.N.; Velikhov, E.P.

1981-01-01

The fuel reprocessing pilot plants for high active materials would permit the study and development or particular processing steps and flowsheet variations; in some cases, these experimental installations realize on a small scale practically all technological chains of large reprocessing plants. Such a fuel reprocessing pilot plant with capacity of 3 kg U/d has been built at V. G. Khlopin Radium Institute. The pilot plant is installed in the hot cell of radiochemical compartment, and is composed of the equipments for fuel element cutting and dissolving, the preparation of feed solution (clarification, correction), extraction reprocessing and the production of uranium, plutonium and neptunium concentrates, the complex processing of liquid and solid wastes and a special unit for gas purification and analysis. In the last few years, a series of experiments have been carried out on the reprocessing of spent VVER fuel. (J.P.N.)

Aplikasi eye moving desensitization dan reprocessing dalam konseling post-traumatic stress disorder

OpenAIRE

Hengki Satrianta

2017-01-01

Akhir-akhir ini banyak peristiwa yang berpotensi memunculkan efek traumatik yang jika tidak ditangani akan menimbulkan gangguan stres pascatrauma. Olehnya itu, dibutuhkan upaya-upaya untu menangani masalah ini. Salah satu upaya yang dimaksud adalah penggunaan eye moving desensitization and reprocessing. Artikel ini ditulis dengan fokus pada penanganan gangguan stres pascatrauma melalui eye moving desensitization and reprocessing. Tujuan penulisan artikel ini adalah untuk mengetahui gambaran u...

(reprocessed)CAGE peaks - FANTOM5 | LSDB Archive [Life Science Database Archive metadata

Lifescience Database Archive (English)

Full Text Available switchLanguage; BLAST Search Image Search Home About Archive Update History Data List Contact us FANTOM...g38/mm10). Data file File name: (reprocessed)CAGE_peaks (Homo sapiens) File URL: ftp://ftp.biosciencedbc.jp/archive/fantom...)CAGE_peaks (Mus musculus) File URL: ftp://ftp.biosciencedbc.jp/archive/fantom5/d...his Database Site Policy | Contact Us (reprocessed)CAGE peaks - FANTOM5 | LSDB Archive ...

The future of reprocessing: a synergy of enhanced processes and new approaches

International Nuclear Information System (INIS)

Boullis, B.; Josso, F.; Montmain, J.; Buffereau, M.

1996-01-01

The December 30, 1991 french law has led scientists to develop new reprocessing processes in order to implement different strategies for the management of long-lived radioactive wastes from spent fuels. Various existing reprocessing processes and facility operation supervision and control techniques (PUREX, DIAMEX, SESAME, ACTINEX, DIAPASON) are briefly described. Three leading CEA scientists discuss the challenges of the future and according research programs. (C.B.)

A review of reprocessing, partitioning, and transmutation of spent nuclear fuel and the implications for Canada

International Nuclear Information System (INIS)

Jackson, D.P.

2006-01-01

The current status of the reprocessing, partitioning, and transmutation of used nuclear fuel are reviewed in the context of assessing the possible application of these technologies to used CANDU fuel. The status of commercial reprocessing is briefly surveyed and recent progress in world R and D programs on the transmutation of FP's and actinides using Accelerator Driven Systems is summarized. The implications of reprocessing for Canada are explored from the point of view of a long strategy for managing used CANDU fuel in terms of the costs of initiating reprocessing domestically at some time in the future including public and occupational radiation doses, and the wastes generated. (author)

Reprocessable thermosets for sustainable three-dimensional printing.

Science.gov (United States)

Zhang, Biao; Kowsari, Kavin; Serjouei, Ahmad; Dunn, Martin L; Ge, Qi

2018-05-08

Among all three-dimensional (3D) printing materials, thermosetting photopolymers claim almost half of the market, and have been widely used in various fields owing to their superior mechanical stability at high temperatures, excellent chemical resistance as well as good compatibility with high-resolution 3D printing technologies. However, once these thermosetting photopolymers form 3D parts through photopolymerization, the covalent networks are permanent and cannot be reprocessed, i.e., reshaped, repaired, or recycled. Here, we report a two-step polymerization strategy to develop 3D printing reprocessable thermosets (3DPRTs) that allow users to reform a printed 3D structure into a new arbitrary shape, repair a broken part by simply 3D printing new material on the damaged site, and recycle unwanted printed parts so the material can be reused for other applications. These 3DPRTs provide a practical solution to address environmental challenges associated with the rapid increase in consumption of 3D printing materials.

Power Reactor Thoria Reprocessing Facility (PRTRF), Trombay

International Nuclear Information System (INIS)

Dhami, P.S; Yadav, J.S; Agarwal, K.

2017-01-01

Exploitation of the abundant thorium resources to meet sustained energy demand forms the basis of the Indian nuclear energy programme. To gain reprocessing experience in thorium fuel cycle, thoria was irradiated in research reactor CIRUS in early sixties. Later in eighties, thoria bundles were used for initial flux flattening in some of the pressurized heavy water reactors (PHWRs). The research reactor irradiated thoria contained small content (∼ 2-3ppm) of "2"3"2U in "2"3"3U product, which did not pose any significant radiological problems during processing in Uranium Thorium Separation Facility (UTSF), Trombay. Thoria irradiated in PHWRs on discharge contained (∼ 0.5-1.5% "2"3"3U with significant "2"3"2U content (100-500 ppm) requiring special radiological attention. Based on the experience from UTSF, a new facility viz. Power Reactor Thoria Reprocessing Facility (PRTRF), Trombay was built which was hot commissioned in the year 2015

To reprocess to recycle. The nuclear safety

International Nuclear Information System (INIS)

1999-01-01

After a summary of fundamental notions of radioactivity and nuclear safety, the first part of this work is devoted to the organisation in France to provide the nuclear facilities safety. The second part related to the fuel cycle describes the big steps of this cycle and particularly the stakes and objectives of the reprocessing -recycling as well as the valorization of reusable matters such plutonium and uranium. The risks identification, means to control them, in conception, realisation and operation are described in the third, fourth and fifth parts. In this last part the managements of accidental situations is treated. The sixth and last part is devoted to the environment protection, treats the control of waste release of reprocessing -recycling facilities, of these waste management that is to say every disposition made by Cogema to limit the impact of its installations on environment. In this last part are also described the safety of nuclear and radioactive matters transport, and the definitive breakdown of installations. (N.C.)

Advanced oxidation treatment of high strength bilge and aqueous petroleum waste

Energy Technology Data Exchange (ETDEWEB)

Hulsey, R.A.; Kobylinski, E.A. [Black and Veatch, Kansas City, MO (United States); Leach, B. [EEC, Inc., Virginia Beach, VA (United States); Pearce, L. [TRITECH, Greensboro, NC (United States)

1996-11-01

The Craney Island Fuel Depot is the largest US Navy fuel terminal in the continental US. Services provided at this facility include fuel storage (current capacity is 1.5 million barrels), fuel reclamation (recovery of oil from oily wastewater), and physical/chemical treatment for the removal of residual oil from bilge water and from aqueous petroleum waste. Current wastewater treatment consists of storage/equalization, oil/water separation, dissolved air flotation, sand filtration, and carbon adsorption. The Navy initiated this study to comply with the State requirement that its existing physical/chemical oily wastewater treatment plant be upgraded to remove soluble organics and produce an effluent which would meet acute toxicity limits. The pilot tests conducted during the study included several variations of chemical and biological wastewater treatment processes. While biological treatment alone was capable of meeting the proposed BOD limit of 26 mg/L, the study showed that the effluent of the biological process contained a high concentration of refractory (nonbiodegradable) organics and could not consistently meet the proposed limits for COD and TOC when treating high-strength wastewater. Additional tests were conducted with advanced oxidation processes (AOPs). AOPs were evaluated for use as independent treatment processes as well as polishing processes following biological treatment. The AOP processes used for this study included combinations of ozone (O{sub 3}) ultraviolet radiation (UV), and hydrogen peroxide (H{sub 2}O{sub 2}).

Simulation of solvent extraction in reprocessing

Energy Technology Data Exchange (ETDEWEB)

Kumar, Shekhar; Koganti, S B [Reprocessing Group, Indira Gandhi Centre for Atomic Research, Kalpakkam (India)

1994-06-01

A SIMulation Program for Solvent EXtraction (SIMPSEX) has been developed for simulation of PUREX process used in nuclear fuel reprocessing. This computer program is written in double precision structured FORTRAN77 and at present it is used in DOS environment on a PC386. There is a plan to port it to ND supermini computers in future. (author). 5 refs., 3 figs.

Analyzing the reprocessing decision: plutonium recycle and nuclear proliferation. Final report

International Nuclear Information System (INIS)

Heising, C.D.; Connolly, T.J.

1978-11-01

The United States decision to defer indefinitely the reprocessing of spent nuclear fuel is examined in this thesis. Bayesian decision analysis is applied to develop a rational framework for the assessment of alternatives. Benefits and costs for each alternative are evaluated and compared in dollar terms to determine the optimal decision. A fuel cycle simulation model is constructed to assess the economic value of reprocessing light water reactor (LWR) spent fuel and recycling plutonium. In addition, a dynamic fuel substitution model is used to estimate the economic effects of the reprocessing decision's influence on the introduction date of the liquid metal fast breeder reactor (LMFBR). The analysis of benefits and costs is extended to include the social costs due to technological risks, such as accident risk, nuclear theft and/or sabotage, and international nuclear proliferation. These social costs are expressed in dollar terms for comparison with the conventional economic values. Results of the analysis indicate that the domestic social costs are less than the economic benefits by more than three orders of magnitude, and that the permit option dominates those of delay or prohibit. An examination of proliferation risk indicates a factor of approximately 7 between cost-benefits. Thus, on the basis of this analysis, it appears that to permit reprocessing is optimal over delaying or prohibiting the technology

A study of statistical tests for near-real-time materials accountancy using field test data of Tokai reprocessing plant

International Nuclear Information System (INIS)

Ihara, Hitoshi; Nishimura, Hideo; Ikawa, Koji; Miura, Nobuyuki; Iwanaga, Masayuki; Kusano, Toshitsugu.

1988-03-01

An Near-Real-Time Materials Accountancy(NRTA) system had been developed as an advanced safeguards measure for PNC Tokai Reprocessing Plant; a minicomputer system for NRTA data processing was designed and constructed. A full scale field test was carried out as a JASPAS(Japan Support Program for Agency Safeguards) project with the Agency's participation and the NRTA data processing system was used. Using this field test data, investigation of the detection power of a statistical test under real circumstances was carried out for five statistical tests, i.e., a significance test of MUF, CUMUF test, average loss test, MUF residual test and Page's test on MUF residuals. The result shows that the CUMUF test, average loss test, MUF residual test and the Page's test on MUF residual test are useful to detect a significant loss or diversion. An unmeasured inventory estimation model for the PNC reprocessing plant was developed in this study. Using this model, the field test data from the C-1 to 85 - 2 campaigns were re-analyzed. (author)

The refurbishment of the D1206 fuel reprocessing plant

International Nuclear Information System (INIS)

Bailey, G.

1988-01-01

The term decommissioning can be applied not only to reactors but to any nuclear plant, laboratory, building or part of a building that may have been associated with radioactive material and needs to be restored to clean conditions. In this case the decommissioning and reconstruction of the Dounreay Fast Reactor fuel reprocessing plant, so that plutonium oxide could be reprocessed as well as enriched uranium fuel, is described. The work included improving containment and shielding, building a new head-end treatment cave for the more complex and larger fuel elements, improving the ventilation and constructing a new dissolver. In this paper the breakdown cave and dissolver cell are described and compared and the work done explained. (U.K.)

Ecological risk of reprocessing of uranium wastes of the Gafurov-city's tailing pit

International Nuclear Information System (INIS)

Hakimov; Nazarov, H.M.; Mirsaidov, U.M.

2005-01-01

The authors set as their purpose the investigation of ecological risk of reprocessing of uranium wastes of the Gafurov-city's tailing pit. Having carried out their investigations, the authors came to the conclusion that the effect of radon gas during reprocessing to workers and specialists is minimal if they follow all the required safety rules

EDRP public local inquiry, UKAEA/BNFL precognition on: PFR fuel reprocessing and radioactive waste management at Dounreay

International Nuclear Information System (INIS)

Pugh, O.

1986-01-01

A description of PFR fuel reprocessing at Dounreay is given, including brief details of fuel assembly transport, dismantling, chemical separation processes and reprocessing experience. The origin of radioactive wastes from PFR reprocessing, and the types of radioactive waste are outlined. The management of radioactive waste, including storage, treatment and disposal is described. (U.K.)

Economic evaluation of reprocessing

International Nuclear Information System (INIS)

1978-11-01

This discussion paper first identifies the main factors which influence the economic assessment of reprocessing. It proposes the use of a diagram - the so-called ''phase diagram'' - which plots the fast reactor premium against the price of uranium. The diagram delineates areas where the once-through fuel cycle, thermal recycle and fast reactor will be the preferred choice from micro-economic considerations. The paper then goes on to consider the circumstances under which a country may or may not wish to introduce thermal recycle or fast reactors. Finally, a procedure for further discussion on economic considerations with WG4 is proposed

Study of the 60Co speciation in the aqueous radioactive waste of the la Hague nuclear reprocessing plant; environmental behaviour after discharges in the waters of the channel

International Nuclear Information System (INIS)

Gaudaire, J.M.

1999-01-01

60 Co is produced as an activation product and is present in the low-level aqueous radioactive waste released from the La Hague plant. At present, the concentration in the sea (non filtered at 0.45 μm) at the Goury site are close to or even below, the detection limit: 0.2 mBq.l -1 . The 60 Co speciation depends on the type of effluent considered: in the effluent A ('active'), the cobalt is in the form of a stable trivalent complex; in the effluent V (to be checked), the cobalt is in majority (50% of the activity release) in the form of particles (>0.45 μm), and then in the form of two soluble species: ionic divalent (Co 2+ ) and some stable complexes. The evolution of the reprocessing techniques used does not affect the speciation. So, since the nuclear reprocessing plant started at the La Hague plant in 1966, the chemical species discharged in the sea shows time variation related to the evolution of the type of effluent discharged. Thus, since 1994, the particles of cobalt are the main species discharged in the Channel (the V effluents represent more than 85% of the total 60 Co activity released). The effect of instantaneous dilution into the marine conditions involving a variation of pH, oxido-reduction, ionic strength, a gradient of salinity, does not interfere with the evolution of the chemical species discharged. Nevertheless, during the discharge of the V effluent, the main constituents of the sea water (Mg 2+ and Ca 2+ ) go through a precipitation. This comes with the coprecipitation of the ion Co 2+ and with the particles of cobalt (complexes are not affected), and it can be responsible for an increase in the concentration in the particles. The chemical behaviour of the cobalt in the Channel is different from those of conservative element such as antimony. The ionic cobalt and the particles have a small dispersion in the water (cobalt has a very high particle/dissolved distribution factor, it is a non-conservative radionuclide). This sedimentary stock can

General Atomic Reprocessing Pilot Plant: engineering-scale dissolution system description

International Nuclear Information System (INIS)

Yip, H.H.

1979-04-01

In February 1978, a dissolver-centrifuge system was added to the cold reprocessing pilot plant at General Atomic Company, which completed the installation of an HTGR fuel head-end reprocessing pilot plant. This report describes the engineering-scale equipment in the pilot plant and summarizes the design features derived from development work performed in the last few years. The dissolver operating cycles for both thorium containing BISO and uranium containinng WAR fissile fuels are included. A continuous vertical centrifuge is used to clarify the resultant dissolver product solution. Process instrumentation and controls for the system reflect design philosophy suitable for remote operation

Nuclear material inventory estimation in a nuclear fuel reprocessing facility

International Nuclear Information System (INIS)

Bennett, J.E.; Beyerlein, A.L.

1981-01-01

A new approach in the application of modern system identification and estimation techniques is proposed to help nuclear reprocessing facilities meet the nuclear accountability requirement proposed by the International Atomic Energy Agency. The proposed identification and estimation method considers the material inventory in a portion of the chemical separations area of a reprocessing facility. The method addresses the nonlinear aspects of the problem, the time delay through the separation facility, and the lack of measurement access. The method utilizes only input-output measured data and knowledge of the uncertainties associated with the process and measured data. 14 refs

Safety highlights of UP2 reprocessing in La Hague

International Nuclear Information System (INIS)

Marc, A.; Dubois, G.

1998-01-01

The UP2-800 reprocessing plant basically implements the same proven process (PUREX) as UP3 plant. However, some evolutions and additions have been realised: - to reprocess high burn up and MOX fuel assemblies; - to dissolve scraps from reprocessing facilities or from the fabrication of MOX fuels such as UO 2 - PuO 2 powders; - to recover plutonium from ash resulting from alpha waste incineration prior to ash conditioning; - to reduce solid waste alpha activity below the regulatory limits for shallow land disposal. Safety considerations relating to these functions have been taken into account in each step of process design. Safety design rules have been implemented for the UP2-800 plant with the same goals as for the UP3 plant: - keeping the discharge of radioactive liquids and gas within the annual limits authorized under normal operating conditions; - reducing the personnel exposure to a minimum so that 'the number of operators whose integrated dose over a year exceeds 5 mSv be nil or practically nil under normal operating conditions'; - preventing the accidental situations and having at one's disposal the dysfunction monitoring and detection systems and the means to limit their consequences. Particular risks prevention related to the UP2-800 specific functions are described in this paper. (author)

A comprehensive fuel nuclide analysis at the reprocessing plant

International Nuclear Information System (INIS)

Arenz, H.J.; Koch, L.

1983-01-01

The composition of spent fuel can be determined by various methods. They rely partially on different information. Therefore the synopsis of the results of all methods permits a detection of systematic errors and their explanation. Methods for determining the masses of fuel nuclides at the reprocessing input point range from pure calculations (shipper data) to mere experimental determinations (volumetric analysis). In between, a mix of ''fresh'' experimental results and ''historical'' data is used to establish a material balance. Deviations in the results obtained by the individual methods can be attributed to the information source, which is unique for the method in question. The methodology of the approach consists of three steps: by paired comparison of the operator analysis (usually volumetric or gravimetric) with remeasurements the error components are determined on a batch-by-batch basis. Using the isotope correlation technique the operator data as well as the remeasurements are checked on an inter-batch basis for outliers, precision and bias. Systematic errors can be uncovered by inter-lab comparison of remeasurements and confirmed by using historical information. Experience collected during the reprocessing of LWR fuel at two reprocessing plants prove the flexibility and effectiveness of this approach. An example is presented to demonstrate its capability in detecting outliers and determining systematic errors. (author)

Safety problems in fuel reprocessing plants

International Nuclear Information System (INIS)

Amaury, P.; Jouannaud, C.; Niezborala, F.

1979-01-01

The document first situates the reprocessing in the fuel cycle as a whole. It shows that a large reprocessing plant serves a significant number of reactors (50 for a plant of 1500 tonnes per annum). It then assesses the potential risks with respect to the environment as well as with respect to the operating personnel. The amounts of radioactive matter handled are very significant and their easily dispersible physical form represents very important risks. But the low potential energy likely to bring about this dispersion and the very severe and plentiful confinement arrangements are such that the radioactive risks are very small, both with respect to the environment and the operating personnel. The problems of the interventions for maintenance or repairs are mentioned. The intervention techniques in a radioactive environment are perfected, but they represent the main causes of operating personnel irradiation. The design principle applied in the new plants take this fact into account, involving a very significant effort to improve the reliability of the equipment and ensuring the provision of devices enabling the failing components to be replaced without causing irradiation of the personnel [fr

Electrochemical Methods for Reprocessing Defective Fuel Elements and for Decontaminating Equipment

International Nuclear Information System (INIS)

Mikheykin, S. V.; Rybakov, K. A.; Simonov, V. P.

2002-01-01

Reprocessing of fuel elements receives much consideration in nuclear engineering. Chemical and electrochemical methods are used for the purpose. For difficultly soluble materials based on zirconium alloys chemical methods are not suitable. Chemical reprocessing of defective or irradiated fuel elements requires special methods for their decladding because the dissolution of the clad material in nitric acid is either impossible (stainless steel, Zr alloys) or quite slow (aluminium). Fuel elements are cut in air-tight glove-boxes equipped with a dust collector and a feeder for crushed material. Chemical treatment is not free from limitations. For this reason we started a study of the feasibility of electrochemical methods for reprocessing defective and irradiated fuel elements. A simplified electrochemical technology developed makes it possible to recover expensive materials which were earlier wasted or required multi-step treatment. The method and an electrochemical cell are suitable for essentially complete dissolution of any fuel elements, specifically those made of materials which are difficultly soluble by chemical methods

Experience acquired by FRAGEMA in the utilization of reprocessed products in PWRs

International Nuclear Information System (INIS)

Francillon, G.; Morel, M.

1989-01-01

In France, the closure of the fuel cycle has for effect to conduct at the use in PWR of products descended from reprocessing, namely reprocessed Uranium and Plutonium. In this presentation limited at the thermo-mechanical conception of the fuel rod and at the neutronic conception of the fuel assembly we describe the requirements to take into account for the conception and give the experience acquired by FRAGEMA [fr

Experience of iodine removal in Tokai reprocessing plant

International Nuclear Information System (INIS)

Kikuchi, K.; Komori, Y.; Takeda, K.

1985-01-01

In the Tokai reprocessing plant about 170 ton of irradiated fuels have been processed since the beginning of hot operations in 1977. There was no effective equipment for iodine removal from the off-gas except for alkaline scrubbers when the plant construction was completed. In order to reduce the iodine discharge to the atmosphere, silver-exchanged zeolite (AgX) filters were installed additionally in 1979 and 1980, and they have been effective. However, those decontamination factors (DFs) were not as high as expected, and increasing the reprocessing amount of spent fuels it became necessary to lower the iodine discharge to the atmosphere. Therefore, other iodine removal equipment is planned to be installed in the plant. Concerning these investigations and development of iodine removal techniques, the iodine concentration of actual off-gases was measured and useful data were obtained

Prospective microbiologic evaluation of the forceps elevator in closed-channel duodenoscopes after reprocessing.

Science.gov (United States)

Paula, Helga; Tribl, Barbara; Presterl, Elisabeth; Diab-El Schahawi, Magda

2017-02-01

Endoscopes are well-known sources of bacterial transmission in health care facilities offering endoscopy services. The association between multidrug-resistant bacterial infections in patients who had undergone an endoscopic retrograde cholangiopancreatography procedure with reprocessed duodenoscopes has been much discussed. Bacterial contamination of duodenoscopes has been attributed to difficulties with reprocessing these devices, specifically the distal end of the scope, which features a movable forceps elevator. In light of a recent Food and Drug Administration warning letter to Olympus regarding their closed-channel duodenoscope model TJF-Q180V, the aim of our study was to prospectively evaluate the efficacy and safety of our current reprocessing procedures with regard to the TJF-Q180V duodenoscope models used in our hospital. From August 2015-March 2016, we prospectively collected microbiologic surveillance samples from 6 TJF-Q180V model duodenoscopes in routine use at the Division of Gastroenterology and Hepatology using the ESwab collection system (COPAN Diagnostics Inc, Murrieta, CA). A total of 237 microbiologic samples from the forceps elevator were obtained during the survey period. None of the samples yielded microorganism growth. These findings suggest that when following a diligent and validated reprocessing standard in accordance with manufacturer's recommendations, closed-channel endoscope models can still be used. Nevertheless, validated adaptions of current closed-channel duodenoscope models are needed to allow for simple and safe reprocessing. Furthermore, comprehensive postmarket surveillance needs to be established. Copyright © 2017. Published by Elsevier Inc.

A survey of methods to immobilize tritium and carbon-14 arising from a nuclear fuel reprocessing plant

International Nuclear Information System (INIS)

Taylor, P.

1991-02-01

This report reviews the literature on methods to separate and immobilize tritium ( 3 H) and carbon-14 ( 14 C) released from U0 2 fuel in a nuclear fuel reprocessing plant. It was prepared as part of a broader review of fuel reprocessing waste management methods that might find future application in Canada. The calculated inventories of both 3 H and 14 C in used fuel are low; special measures to limit releases of these radionuclides from reprocessing plants are not currently in place, and may not be necessary in future. If required, however, several possible approaches to the concentration and immobilization of both radionuclides are available for development. Technology to control these radionuclides in reactor process streams is in general more highly developed than for reprocessing plant effluent, and some control methods may be adaptable to reprocessing applications

Nuclear safety in fuel-reprocessing plants

International Nuclear Information System (INIS)

Hennies, H.H.; Koerting, K.

1976-01-01

The danger potential of nuclear power and fuel reprocessing plants in normal operation is compared. It becomes obvious that there are no basic differences. The analysis of possible accidents - blow-up of an evaporator for highly active wastes, zircaloy burning, cooling failure in self-heating process solutions, burning of a charged solvent, criticality accidents - shows that they are kept under control by the plant layout. (HP) [de

Waste streams from reprocessing operations

International Nuclear Information System (INIS)

Andersson, B.; Ericsson, A.-M.

1978-03-01

The three main products from reprocessing operations are uranium, plutonium and vitrified high-level-waste. The purpose of this report is to identify and quantify additional waste streams containing radioactive isotops. Special emphasis is laid on Sr, Cs and the actinides. The main part, more than 99 % of both the fission-products and the transuranic elements are contained in the HLW-stream. Small quantities sometimes contaminate the U- and Pu-streams and the rest is found in the medium-level-waste

Reprocessing techniques of LWR spent fuel for reutilization in hybrid systems and IV generation reactors

Energy Technology Data Exchange (ETDEWEB)

Aruquipa, Wilmer; Velasquez, Carlos E.; Pereira, Claubia; Veloso, Maria Auxiliadora F.; Costa, Antonella L. [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Nuclear; Barros, Graiciany de P. [Comissao Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil)

2017-07-01

Since the era of nuclear technology begins, nuclear reactors have been produced spent fuel. This spent fuel contains material that could be recycle and reprocessed by different processes. All these processes aim to reduce the contribution to the final repository through the re-utilization of the nuclear material. Therefore, some new reprocessing options with non-proliferation characteristics have been proposed and the goal is to compare the different techniques used to maximize the effectiveness of the spent fuel utilization and to reduce the volume and long-term radiotoxicity of high-level waste by irradiation with neutron with high energy such as the ones created in hybrid reactors. In order to compare different recovery methods, the cross sections of fuels are calculated with de MCNP code, the first set consists of thorium-232 spiked with the reprocessed material and the second set in depleted uranium that containing 4.5% of U-235 spiked with the reprocessed material; These sets in turn are compared with the cross section of the UO{sub 2} in order to evaluate the efficiency of the reprocessed fuel as nuclear fuel. (author)

Current status of the active test at RRP and development programs for the advanced melter

International Nuclear Information System (INIS)

Kanehira, Norio

2016-01-01

The vitrification facility in Rokkasho Reprocessing Plant started the active tests to solidify HAW into the glass in 2007 which was the examination of the final stage before the operation, but the active test had to be discontinued due to the trouble of glass melter operation with down of pouring by deposit of noble metals on the melter bottom. After the equipment and operating conditions were improved in response to the result of the mock-up tests, a series of active tests were restarted active tests in May, 2012. These tests were finished with enough confirmation of stability in the state such as glass temperature and controlling the noble metals. JNFL has been developed the advanced melter, Joule heated ceramic melter, and the design of the advanced melter is largely different from the existing one. For the confirmation of the advanced melter performances, the full-scale inactive tests had been performed and successfully finished. This paper describes outline of development for advanced melter in Rokkasho Reprocessing Plant. (author)

Synthesis and evaluation of aqueous complexing agents for the Am/Cm separation

International Nuclear Information System (INIS)

Chapron, Simon

2014-01-01

After the reprocessing of uranium, plutonium and eventually neptunium by the PUREX process, the spent fuel is still composed of half of the periodic table. Among these elements, the main responsible for the heat of the wastes is americium. Its reprocessing could allow improving the compactness of deep geological storage of the wastes. Thus the liquid-liquid extraction process called EXAm was developed in order to recover the americium alone. The key step of the process is the Am/Cm separation. An extractant mixture is used with an aqueous complexing agent: TEDGA (N,N',N,N'-tetraethyl-diglycolamide). It allows to enhance the Am/Cm separation by keeping preferentially curium in the aqueous phase, but its structure selectivity relationship is not well known yet. Therefore, the purpose of this thesis is to synthesize and evaluate some structural analogues of TEDGA, in order to better understand the impact of its structure on the Am/Cm selectivity in the EXAm process. During this study, 14 analogues of TEDGA were synthesized and 17 molecules were evaluated in liquid-liquid extraction. Several structural modifications were studied: length and steric hindrance of the N-alkyl chains, size of the spacer, and the introduction of secondary amide functions. This work shows that it is not possible to maintain the ligand in the aqueous phase from tetrabutyl derivatives, and the addition of steric hindrance, or modification of hydrophilicity/lipophilicity balance, systematically decreases the selectivity of ligands. The addition of secondary amide functions (-CONHR) makes the molecules extractable by the solvent (formation of hydrogen bonds with the extractants), therefore they are unsuitable to be used in the EXAm process. The spacer has the main impact on the selectivity: the complexation capacity in high acid medium disappears when it is shortened (malonamide), whereas the ligand has a preference for Am instead of Cm (inversion of selectivity) when it is lengthen

Experience in the construction of a spent nuclear fuel reprocessing plant

International Nuclear Information System (INIS)

Yamashita, Hiroshi

1976-01-01

The construction and operation of a reprocessing plant was first published in 1956. The Reprocessing Expert Committee of AEC was established in 1959, and the preliminary design was finished in 1964 by NCP of Britain. The detailed design was completed in 1969 by SGN of France, and the training of operators was carried out in parallel with this in France. The results of the safety investigation was approved in Jan. 1970, and the construction was started in June 1971. The site of the reprocessing plant is the eastern part of the Tokai Establishment of PNC. The process adopted is the wet Purex process having been established in large practical plants. The treating capacity is 0.7 t/day. The main processes are acceptance and storage, mechanical treatment, and chemical treatment. The reprocessing facilities comprise the main shop, the analysis station, the main exhaust stack, the decontamination station, the solid waste store, the sea discharge pipe, and other incidental facilities. The construction works were about 7 months behind the schedule when the water flow test was finished. The chemical test was finished in March, 1975, and the uranium test is in progress since Sept., 1975. The problems for future are the developments of effective waste treatment and storing techniques, and the researches have been carried out by PNC. The construction project of the second plant is urgently required, since it takes 10 years from planning to operation. (Kako, I.)

Remotex and servomanipulator needs in nuclear fuel reprocessing plants

International Nuclear Information System (INIS)

Garin, J.

1981-01-01

Work on the conceptual design of a pilot-scale plant for reprocessing breeder reactor fuels is being performed at Oak Ridge National Laboratory. The plant design will meet all current federal regulations for repocessing plants and will serve as prototype for future production plants. A unique future of the concept is the incorporation of totally remote operation and maintenance of the process equipment within a large barn-like hot cell. This approach, caled Remotex, utilizes servomanipulators coupled with television viewing to extend man's capabilities into the hostile cell environment. The Remotex concept provides significant improvements for fuel reprocessing plants and other nuclear facilities in the areas of safeguarding nuclear materials, reducing radiation exposure, improving plant availability, recovering from unplanned events, and plant decommissioning

Simulation tool of the on-line reprocessing unit of a molten salt reactor

International Nuclear Information System (INIS)

Simon, Nicole; Conocar, Olivier; Boussier, Hubert; Gastaldi, Olivier; Penit, Thomas; Walle, Eric; Huguet, Anne

2006-01-01

Molten salt reactor (MSR) is an interesting technology selected in the frame of the Generation IV forum. In the MSR, actinides are diluted in a molten salt which is both the fuel and the coolant. The ability of such a reactor is the reducing of the long-lived wastes due to high burn-up and the on-site simplified reprocessing directly connected with the core which preserve the salt properties necessary for its correct operation. Here is defined a flexible computer reprocessing code which can use data from neutronic calculations and can be coupled to a neutronic code. The code allow the description the whole behaviour of MSR, including, a coupled manner, both the design of the core and the optimised reprocessing scheme effects. (authors)

Guide to the selection, training, and licensing or certification of reprocessing plant operators. Volume I

International Nuclear Information System (INIS)

1976-06-01

The Code of Federal Regulations, Title 10, Part 55, establishes procedures and criteria for the licensing of operators, including senior operators, in ''Production and Utilization Facilities'', which includes plants for reprocessing irradiated fuel. A training guide is presented which will facilitate the licensing of operators for nuclear reprocessing plants by offering generalized descriptions of the basic principles (theory) and the unit operations (mechanics) employed in reprocessing spent fuels. In the present volume, details about the portions of a training program that are of major interest to management are presented

Guide to the selection, training, and licensing or certification of reprocessing plant operators. Volume I

Energy Technology Data Exchange (ETDEWEB)

None

1976-06-01

The Code of Federal Regulations, Title 10, Part 55, establishes procedures and criteria for the licensing of operators, including senior operators, in ''Production and Utilization Facilities'', which includes plants for reprocessing irradiated fuel. A training guide is presented which will facilitate the licensing of operators for nuclear reprocessing plants by offering generalized descriptions of the basic principles (theory) and the unit operations (mechanics) employed in reprocessing spent fuels. In the present volume, details about the portions of a training program that are of major interest to management are presented. (JSR)

Reprocessing technology of liquid metal cooled fast breeder reactor fuel

International Nuclear Information System (INIS)

Baetsle, L.H.; Broothaerts, J.; Heylen, P.R.; Eschrich, H.; Geel, J. van

1974-11-01

All the important aspects of LMFBR fuel reprocessing are critically reviewed in this report. Storage and transportation techniques using sodium, inert gas, lead, molten salts and organic coolants are comparatively discussed in connection with cooling time and de-activation techniques. Decladding and fuel disaggregation of UO 2 -PuO 2 fuel are reviewed according to the present state of R and D in the main nuclear powers. Strong emphasis is put on on voloxidation, mechanical pulverization and molten salt disaggregation in connection with volatilization of gaseous fission products. Release of fission gases and the resulting off-gas treatment are discussed in connection with cooling time, burn up and dissagregation techniques. The review is limited to tritium, iodine xenon-krypton and radioactive airborne particulates. Dissolution, solvent extraction and plutonium purification problems specifically connected to LMFBR fuel are reviewed with emphasis on the differences between LWR and fast fuel reprocessing. Finally the categories of wastes produced by reprocessing are analysed according to their origin in the plant and their alpha emitters content. The suitable waste treatment techniques are discussed in connection with the nature of the wastes and the ultimate disposal technique. (author)

Nuclear accountability data at the EUREX reprocessing plant

International Nuclear Information System (INIS)

Ilardi, S.; Pozzi, F.

1976-01-01

In the present work the physical inventory's and fissile material balance's data, which have been collected during the irradiated MTR fuel reprocessing campaign at the EUREX plant in Saluggia (VC), are reported, together with the most important procedures of fissile material accountability

Evaluation of methods for seismic analysis of nuclear fuel reprocessing plants, part 1

International Nuclear Information System (INIS)

Tokarz, F.J.; Murray, R.C.; Arthur, D.F.; Feng, W.W.; Wight, L.H.; Zaslawsky, M.

1975-01-01

Currently, no guidelines exist for choosing methods of structural analysis to evaluate the seismic hazard of nuclear fuel reprocessing plants. This study examines available methods and their applicability to fuel reprocessing plant structures. The results of this study should provide a basis for establishing guidelines recommending methods of seismic analysis for evaluating future fuel reprocessing plants. The approach taken is: (1) to identify critical plant structures and place them in four categories (structures at or near grade; deeply embedded structures; fully buried structures; equipment/vessels/attachments/piping), (2) to select a representative structure in each of the first three categories and perform static and dynamic analysis on each, and (3) to evaluate and recommend method(s) of analysis for structures within each category. The Barnwell Nuclear Fuel Plant is selected as representative of future commercial reprocessing plants. The effect of site characteristics on the structural response is also examined. The response spectra method of analysis combined with the finite element model for each category is recommended. For structures founded near or at grade, the lumped mass model could also be used. If a time history response is required, a time-history analysis is necessary. (U.S.)

Economic evaluation of reprocessing - Indicative Belgian position

International Nuclear Information System (INIS)

1979-05-01

This paper, which also appears as an Appendix to the final Working Group 4 report, forms part of the overall economic evaluation of reprocessing. The indicative national position and illustrative ''phase diagram'' for Belgium is presented. Other factors which influence the Belgian viewpoint and which are not included on the phase diagram are given

Outline of center for research and development in Rokkasho reprocessing plant site

International Nuclear Information System (INIS)

Araya, S.; Kanatsugu, K.; Shakutsui, M.

1998-01-01

Japan Nuclear Fuel Ltd.(JNFL) is now constructing a commercial nuclear fuel reprocessing plant at Rokkasho Mura, introducing French Technology on the main processes of it. In October 1995 prior to the reprocessing plant operation, JNFL established the CENTER FOR RESEARCH and DEVELOPMENT (Center for R and D) inside the plant site to perform various tests which are intended to improve the safety, availability and reliability of the reprocessing plant. The test facility of the center was constructed from 1991 to 1995, and now many tests have been being performed in the center. A full-scale mock-up of the Head end process components based on French Technology, which consist of a tilting crane, shearing machine, dissolver, hull rinser, end piece rinser and maintenance equipment, was moved into a new building from the Head End Demonstration Test facility in Kobe (reported in RECOD '91). Functional tests and system performance tests are carried out under cold conditions (non radioactive). As equipment and piping layout in the cell and working area layout outside of the cell are simulated to the reprocessing plant design, it is possible to test remote maintainability and repairability under the same condition as the reprocessing plant except radioactive condition. A full-scale mock-up of the Centrifugal clarifier based on French Technology, which can clarify the dissolution solution is operated to confirm clarification performance under various cold conditions and is tested for the maintainability and the repairability. A sampling bench imported from France is the same one planed to be operated in the reprocessing plant which samples for various analysis from each process. The sampling bench is tested to confirm operability, maintainability and reliability. Also the sampling piping and pneumatic piping are going to be install to the sampling bench for a system test of sampling system. Two types of MERC (Mobile Equipment Replacement Cask), which replace worn parts remotely

Decommissioning and dismantling of the reprocessing plant Karlsruhe

International Nuclear Information System (INIS)

Eiben, K.; Fritz, P.

1995-01-01

Reprocessing activities were discontinued in late 1990. The facility was drained and rinsed, and 80 m3 of HLWC have since been stored in special tanks, awaiting vitrification. Decommissioning work is scheduled to proceed in six phases. The reprocessing areas of the facility will be prepared for release from radiological control and dismantled in the first phase. The remaining facilities can be deregulated, and storage tanks dismantled, only after termination of phase 1. The goal of the following phase is clearance from radiological control of all controlled areas, and the last phase is to cover dismantling of all buildings and restoration of a green field site. The overall costs of these activities are estimated to amount to DM 1.657 million. The article explains the contents of the first permits for decommissioning as well as the documents prepared for planning of work and licence application. (orig./HP) [de

Research and development on air cleaning system of reprocessing plant in Japan

International Nuclear Information System (INIS)

Naruki, K.

1985-01-01

Present status in Japan of R and D on air cleaning systems, especially of the fuel reprocessing plant is summarized. The description is centered on the R and D and experience of Tokai-reprocessing plant, which covers the plant air cleaning system, effort carried out for decreasing I 2 effluence in the actual vented off-gas, and R and D for recovery of Kr and 3 H. Some experimental results for the evaluation of HEPA filter are also described

Review of advanced core designs for LMFBRs

International Nuclear Information System (INIS)

Yoshida, Kazuo