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Sample records for adaptation and use of bituminous materials

  1. Effects of bituminous layer as backfill material on mechanical behavior in tunnel model

    Moriyoshi, Akihiro; Takano, Shin-ei; Urata, Hiroyuki; Suzuki, Tetsuya; Yoshida, Takaki

    2001-01-01

    This paper describes the effects of bituminous material as a backfill material on mechanical behavior in model tunnel in laboratory. It is known that load spreading and relaxation of bituminous material are good properties. Then if we use bituminous material as a backfill material of tunnel, the tunnel will have waterproof, good load spreading property. We used new bituminous material (Aquaphalt) which can solidify in water. We conducted relaxation test in tension for new bituminous mat...

  2. Effect of asphaltene and resin oils on the viscosity of bituminous petroleum materials to be used as asphalt primers

    Bencomo, M. R.

    2006-03-01

    Full Text Available The bituminous crude from the Machete, Venezuela, area, which has such a fluid consistency that it falls outside the normal scope of the A5TM D-5 (1 penetration test exceeding the 3D-mm ceiling specified in that standard and can be used as an asphalt primer: Like other asphalt products, these materials are -chemically speaking- a mix of numerous naphthenic, paraffinic and aromatic hydrocarbons and heterocyclic compounds containing sulphur, nitrogen, oxygen and so on. They have a dense and a malthene oil phase which, along with the natural hydrocarbons additives used in these products acts as a volatile fluidizer. The former is described as a mix of asphaltenes: complex high molecular weight substances that are insoluble in paraffinic hydrocarbons and soluble in aromatic compounds such as benzene. The malthene oil phase, in turn, consists in a mix of resins and hydrocarbons and together the two constitute a colloidal system. The experiments discussed in the present paper were conducted to determine the effect of the proportion of asphaltenes and resin oils on the viscosity of such bituminous crude emulsions/ with a view to their use as primers. These experiments were run in a Parr batch reactor in a nitrogen atmosphere using n-heptane as a solvent. The resins were separated after the asphaltenes precipitated from the samples and subsequently from the malthene fraction obtained. The results showed that the asphaltenes account for the structural characteristics and consistency of the medium and the resin oils for its cohesive properties/,the malthene oils act as solvents.Los crudos extrapesados procedentes del área Machete (Venezuela son materiales de consistencia blanda o fluida, por lo que se salen del campo en el que normalmente se aplica el ensayo de penetración a productos asfálticos según el método ASTM D-5 (1, cuyo límite máximo es 30 mm, y pueden ser utilizados como pinturas asfálticas de imprimación. Al igual que otros productos

  3. Modelling the quasi-static behaviour of bituminous material using a cohesive zone model

    Tabakovic, Amir; Karac, Aleksandar; Ivankovic, Alojz; Gibney, Amanda; McNally, Ciaran; Gilchrist, M. D.

    2010-01-01

    This paper investigates the applicability of a cohesive zone model for simulating the performance of bituminous material subjected to quasistatic loading. The Dugdale traction law was implemented within a finite volume code in order to simulate the binder course mortar material response when subjected to indirect tensile loading. A uniaxial tensile test and a threepoint bend test were employed to determine initial stress-strain curves at different test rates and the cohesive zone parameters (...

  4. 8th RILEM International Symposium on Testing and Characterization of Sustainable and Innovative Bituminous Materials

    Partl, Manfred

    2016-01-01

    This work presents the results of RILEM TC 237-SIB (Testing and characterization of sustainable innovative bituminous materials and systems). The papers have been selected for publication after a rigorous peer review process and will be an invaluable source to outline and clarify the main directions of present and future research and standardization for bituminous materials and pavements. The following topics are covered: - Characterization of binder-aggregate interaction - Innovative testing of bituminous binders, additives and modifiers - Durability and aging of asphalt pavements - Mixture design and compaction analysis - Environmentally sustainable materials and technologies - Advances in laboratory characterization of bituminous materials - Modeling of road materials and pavement performance prediction - Field measurement and in-situ characterization - Innovative materials for reinforcement and interlayer systems - Cracking and damage characterization of asphalt pavements - Rec...

  5. Microstructural self-healing of bituminous materials: Combined experimental and numerical study

    Pauli, A; Schmets, A. J. M.; Kasbergen, C.; Varveri, K.; Scarpas, A.

    2013-01-01

    Bituminous materials form a class of materials that possess the intrinsic ability to selfheal. This self-healing capability is evidenced by the observation that the service life of these materials ‘in the field’ exceeds the service life as predicted by standard mechanical laboratory tests. This mismatch between laboratory prediction and field service life is usually accounted for by applying a shift or healing factor. In this contribution we demonstrate a model that is based on the observatio...

  6. A Method to Estimate the Dynamic Displacement and Stress of a Multi-layered Pavement with Bituminous or Concrete Materials

    LU, ZHENG; Yao, Hailin; Zhang, JingBo

    2014-01-01

    In this research work, a method to estimate the dynamic characteristics of a multilayered pavement with bituminous or concrete materials is proposed. A mechanical model is established to investigate the dynamic displacement and stress of the multi-layered pavement structure. Both the flexible and the rigid pavements, corresponding to bituminous materials and concrete materials, respectively, are studied. The theoretical solutions of the multi-layered pavement structure are deduced considering...

  7. Study of the contribution from gamma dose rate and radon concentration in civilian housing caused by the use of construction material having processing residues from uranium containing bituminous coal in Freital, Saxony

    The past, widerspread use of residues from processing uranium containing bituminous coal in the former mining region of Freital, Saxony, for construction led to increased concentrations of natural radionuclides in the building material of civilian housing. Measurement of the local dose levels in such housing, analytical characterization of the building material, and model calculations allow for the assessment of the contribution of the material to the total radioactive exposure of residents. (orig.)

  8. Comparative study of test methods for bituminized and other low- and medium-level solidified waste materials

    Various aspects of the behaviour of bituminized or cemented simulated low- or medium-level radioactive waste in contact with water or salt solutions have been investigated. The solubility (approximately 0.5%) and the diffusion coefficient (approximately 5.10-8 cm2/sec) determining transort of water in pure bitumen have been measured for Mexphalte 40/50 at room temperature. A weighing method has been used to study water uptake and swelling of bituminized sodium nitrate, sodium sulphate or cation-exchange resin. The swelling of samples in contact with water was in some cases very pronounced. In strong salt solutions the tendency to swell is much less. The particle size of the embedded waste material is an important parameter. Thermal pre-treatment of cation-exchange resin before bituminization does not seem to improve the quality of the final product. The interaction between bituminized-exchange resin and concrete barrier materials has been studied. Microbial degradation of bitumen and bituminized waste under aerobic conditions has been investigated. It is probably of minor importance as far as leaching is concerned. A method for measuring leaching from a plane surface of cemented waste has been developed. The method avoids the problem of cracks between the sample and the container. Leaching from cemented sodium nitrate or sulphate was investigated. Absorption of CO2 from the atmosphere was found to have only minor effect on Cs- and Na-leaching but gave a pronounced decrease in Ca-leaching. The use of silica-fume as an additive to cemented sodium nitrate decreased the leach rate by a factor 4. (author)

  9. The effect of petrographical composition of coals and bituminous sediments on the material and isotopic composition of dry natural gases from artificial recoalification reactions. 2

    Experimental results indicate that on the basis of the material and isotopic composition of natural gases conclusions can be drawn with regard to the character (humic or bituminous) of the parent rock. Thus, genetic relations assumed to exist between humic sediments (e.g. coal seams) and dry natural gases as well as bituminous rocks and wet natural gases are experimentally confirmed. In addition, from analyses of the materials approximate data can be derived on the degree of carbonization of coal or bituminous sediments in the main phase of gas separation. Furthermore, these analyses were used to elucidate the question whether authochthonous or allochthonous deposits are present. It could be shown that the maceral composition of coals and of the organo-petrographical inclusions in bituminous sediments determines the isotopic composition of methane in recoalification gases to a considerable degree. (author)

  10. A Method to Estimate the Dynamic Displacement and Stress of a Multi-layered Pavement with Bituminous or Concrete Materials

    Zheng LU

    2014-12-01

    Full Text Available In this research work, a method to estimate the dynamic characteristics of a multilayered pavement with bituminous or concrete materials is proposed. A mechanical model is established to investigate the dynamic displacement and stress of the multi-layered pavement structure. Both the flexible and the rigid pavements, corresponding to bituminous materials and concrete materials, respectively, are studied. The theoretical solutions of the multi-layered pavement structure are deduced considering the compatibility condition at the interface of the structural layers. By introducing FFT (Fast Fourier Transform algorithm, some numerical results are presented. Comparisons of the theoretical and experimental result implied that the proposed method is reasonable in predicting the stress and displacement of a multi-layered pavement with bituminous or concrete materials. DOI: http://dx.doi.org/10.5755/j01.ms.20.4.6071

  11. A preliminary investigation into the physical and chemical properties of biomass ashes used as aggregate fillers for bituminous mixtures.

    Melotti, Roberto; Santagata, Ezio; Bassani, Marco; Salvo, Milena; Rizzo, Stefano

    2013-09-01

    Fly and bottom ashes are the main by-products arising from the combustion of solid biomass. Since the production of energy from this source is increasing, the processing and disposal of the resulting ashes has become an environmental and economic issue. Such ashes are of interest as a construction material because they are composed of very fine particles similar to fillers normally employed in bituminous and cementitious mixtures. This research investigates the potential use of ash from biomass as filler in bituminous mixtures. The morphological, physical and chemical characteristics of 21 different ashes and two traditional fillers (calcium carbonate and "recovered" plant filler) were evaluated and discussed. Leaching tests, performed in order to quantify the release of pollutants, revealed that five ashes do not comply with the Italian environmental re-use limits. Experimental results show a wide range of values for almost all the investigated properties and a low correlation with biomass type in terms of origin and chemical composition. Furthermore, sieving and milling processes were found to improve the properties of the raw material in terms of grading and sample porosity. The effectiveness of these treatments and the low content of organic matter and harmful fines suggest that most of the biomass ashes investigated may be regarded as potential replacements for natural filler in bituminous mixtures. PMID:23790672

  12. Advances in Interlaboratory Testing and Evaluation of Bituminous Materials State-of-the-Art Report of the RILEM Technical Committee 206-ATB

    Bahia, Hussain; Canestrari, Francesco; Roche, Chantal; Benedetto, Hervé; Piber, Herald; Sybilski, Dariusz

    2013-01-01

    This STAR on asphalt materials presents the achievements of RILEM TC 206 ATB, acquired over many years of interlaboratory tests and international knowledge exchange. It covers experimental aspects of bituminous binder fatigue testing; the background on compaction methods and imaging techniques for characterizing asphalt mixtures including validation of a new imaging software; it focuses on experimental questions and analysis tools regarding mechanical wheel tracking tests, comparing results from different labs and using finite element techniques. Furthermore, long-term rutting prediction and evaluation for an Austrian road are discussed, followed by an extensive analysis and test program on interlayer bond testing of three different test sections which were specifically constructed for this purpose. Finally, the key issue of manufacturing reclaimed hot mix asphalt in the laboratory is studied and recommendations for laboratory ageing of bituminous mixtures are given.

  13. Mix design of bituminous materials including reclaimed asphalt pavement

    Dubois, Vincent; De La Roche, Chantal

    2008-01-01

    Reclaimed asphalt, obtained by milling of asphalt road layers can be re-used at once or stored. In the case of storage, an heterogeneity issue may occur when several types of materials, with different origins are mixed. At the scale of a storage zone or a stock pile, composition and properties of the reclaimed asphalts will be different, including variations of the final material properties, constraints for the stock manager, and the necessary adaptation of the manufacturing process. The recl...

  14. Bituminization of low- and intermediate-level radioactive concentrates

    The results and experiences are summed up from the research and development of the technology of bituminization of low- and intermediate-level radioactive concentrates generated in the operation of nuclear power plants with WWER-440 reactors. The experiments took place on a pilot plant bituminization line with various model solutions at an evaporator capacity of 70, 100 and 140 litres per hour. The composition of the solutions changed in dependence on the knowledge of the composition of actual concentrates in the V-1 nuclear power plant at Jaslovske Bohunice. The following factors were studied in the concentrate: the effect of its pH, its borate content and content of metal carbonates, the content of organic acid salts, the content of detergents, etc., on the process of bituminization. Physico-chemical conditions are described under which the operation of the evaporator was fail-safe and filling of the bituminization product with salts homogeneous. A low water content of up to 1% was achieved. The properties of the bituminization product were negatively affected by a high level of heavy metal oxides, surfactants, oxalates and citrates. In order to improve the properties of the product it will be necessary to replace bitumen emulsion Silembit-60 used as reinforcement matrix, by a different type of bitumen. (Z.M.)

  15. Characterization and modelling of self healing of bituminous materials towards durable asphalt pavement

    Qiu, J.; Van de Ven, M.F.C.; Schlangen, H.E.J.G.; Wu, S.; Molenaar, A.A.A.

    2012-01-01

    The traffic volume and the number of heavy vehicles are growing enormously nowadays. There is a need for designing a durable asphalt pavement with innovative technologies. Pavement structures and materials with self healing and self repairing capability are believed to be very useful in such a syste

  16. Characterization and modelling of self healing of bituminous materials towards durable asphalt pavement

    Qiu, J.; Van de Ven, M.F.C.; Schlangen, H.E.J.G.; Wu, S.; Molenaar, A.A.A.

    2012-01-01

    The traffic volume and the number of heavy vehicles are growing enormously nowadays. There is a need for designing a durable asphalt pavement with innovative technologies. Pavement structures and materials with self healing and self repairing capability are believed to be very useful in such a system. This paper is aiming to understand the self healing behaviour through mechanical testing and finite element modelling. Instead of a complex and time consuming fatigue involved self healing inves...

  17. Elemental analysis of Indonesian and Australian bituminous coal used at Kapar Power Station

    An instrumental neutron activation analytical (INAA) technique is used for the determination of thirty elements in five coal samples collected from Kapar power station, imported from Indonesia and Australia. Analyses of the samples are being associated with standards. All irradiation were performed in the nuclear reactor of Malaysia Nuclear Agency (MNA). samples were counted by Hyper Pure Germanium (HPGe) detector for short period irradiations at MNA, while for the long period irradiations the samples were counted at Universiti Kebangsaan Malaysia (UKM). The concentrations of thirty elements have been determined: The major components are Cl, Ca, Mg, K, Fe, Ti, and Na with the mean concentrations in the range between 70±69 ppm-6100±1639 ppm; and the trace elements are Zr, V, Mn, Sc, Cr, Co, As, Br, Rb, Sb, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, Lu, Hf, Th, U and Ta with the mean concentrations in the range between 0.1381±0.0202 - 69.0±2.8 ppm. The results have been compared to the reported data of eight coal samples from the United States and the reported data of Australian bituminous coal. (Author)

  18. Dye-adsorption capacity of bituminous fly ash and its pozzolanic property after used as dye-adsorbent

    Penpolcharoen, M.

    2004-01-01

    Bituminous fly ash, which is an industrial waste, was used as an adsorbent to remove dyestuff from the textile-dye wastewater. The batch kinetic and isotherm experiments of the synthetic wastewater were firstly conducted to determine the adsorption behavior and optimal conditions for adsorption. The optimal conditions were then applied to the actual textile-dye wastewater. Under the original conditions of fly ash and wastewater, the results indicated that the color could be removed up to 86.6...

  19. Bituminous and asphaltic membranes for radioactive waste repositories on land

    The aim of the study has been to identify, within generic designs for waste facilities, areas where bituminous materials might be incorporated as a barrier. The report is presented in three sections: Part I - The properties of bitumen are described, with particular reference to the long-term behaviour of the material. The durability of bitumen is discussed, including aspects such as ageing, microbial degradation, chemical resistance and radiation resistance. Part II -The use of bituminous materials in hydraulic engineering is outlined. Much of this section of the report concentrates on the use of bituminous materials in embankment dams and reservoir construction. A review of material technology and construction techniques is presented and a detailed assessment made of the performance of the materials in service. Part III - Generic trench type radioactive waste repository designs incorporating bituminous materials are presented. Material and construction specifications for the designs are detailed, and a performance assessment presented. (author)

  20. Dye-adsorption capacity of bituminous fly ash and its pozzolanic property after used as dye-adsorbent

    Penpolcharoen, M.

    2004-02-01

    Full Text Available Bituminous fly ash, which is an industrial waste, was used as an adsorbent to remove dyestuff from the textile-dye wastewater. The batch kinetic and isotherm experiments of the synthetic wastewater were firstly conducted to determine the adsorption behavior and optimal conditions for adsorption. The optimal conditions were then applied to the actual textile-dye wastewater. Under the original conditions of fly ash and wastewater, the results indicated that the color could be removed up to 86.65% by 12 g of the fly ash /L of the wastewater within 30 min. Its adsorption was described by the Freundlich isotherm. The dye-adsorbed fly ash was further studied on its pozzolanic property in terms of compressive strength by using it as a partial substitute to Portland cement type I to produce mortar. The result revealed that the highest compressive strength was of the sample containing 10% by weight of the dye-adsorbed fly ash in replacement of cement. It possessed 215 kg/cm2 at 28 days, which is 92.67% of the sample containing 10% by weight of the original fly ash in replacement of cement, or 83.33 of the cement mortar. For the environmental concern, leachabilities of lead (Pb, chromium (Cr, copper (Cu and zinc (Zn from all mortars were also carried out. No leaching of the heavy metals from any samples could be detected. Hence, the dye-adsorbed fly ash can be used as an environmental friendly construction material.

  1. Testing of the possibility for the use of BEWAG-coal cinder in bituminous supporting layers of asphalt fastening

    Ueckert, H.W.

    1981-01-01

    In order to develop further use of coal cinder granulate the suitability of that granulate has been tested for use as an additional material for bituminous supporting layers. Results: (1) The granulate can be used for asphalt supporting layers Type B according TVT 72. (2) The granulation scope 0/5 mm is recommended. (3) The granular share of the mineral mixture can amount up to 30% of weight. (4) Standard-Bitumen B 65 can be used as bituminous binders. (5) The optimum consistence of the bituminous materials has to be found according of an aptitude test.

  2. Sorption of aqueous phosphorus onto bituminous and lignitous coal ashes

    Yan Jinying; Kirk, Donald W. [Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, Ontario, M5S 3E5 (Canada); Jia, Charles Q. [Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, Ontario, M5S 3E5 (Canada)], E-mail: cqjia@chem-eng.toronto.edu; Liu Xinan [College of Chemical Engineering, Chongqing University, Chongqing (China)

    2007-09-05

    Aiming at the development of a phosphorus removal technology for waste water, phosphate (PO{sub 4}{sup 3-}) retention behavior of bituminous and lignitous coal ashes was investigated using a batch reactor. Ash samples, including fresh and weathered fly and bottom ashes, were studied for their sorption isotherms and reversibility. Fly ashes had a much higher phosphate retention capacity (4000-30,000 mg P/kg) than bottom ashes (15-600 mg P/kg). Lignitous coal ashes were more capable of retaining phosphate than bituminous coal ashes. The retention process was largely irreversible, and the irreversibility increased with the increase in the retention capacity. Weathering enlarged the retention capacity of the bituminous bottom ash, but substantially lowered that of the fly ash, likely due to the difference in the weather-induced changes between the fly and bottom ashes. Sorption isotherms of fly ashes were found to be adequately represented by the Langmuir model while those of bottom ashes fitted better to the Freundlich model. Concentrations of Ca{sup 2+} and PO{sub 4}{sup 3-} in the aqueous phase were measured at the end of sorption and desorption experiments, and were compared with solubilities of three calcium phosphate minerals. The aqueous solutions were saturated or super-saturated with respect to tricalcium phosphate (Ca{sub 3}(PO{sub 4}){sub 2}) and hydroxyapatite (Ca{sub 5}(PO{sub 4}){sub 3}OH), and slightly under-saturated with respect to amorphous calcium phosphate. It is concluded that precipitation of calcium phosphate is the predominant mechanism for phosphate retention by coal ash under the conditions studied. There is a strong and positive correlation between alkalinity and phosphate sorption capacity. Consequently, acid neutralization capacity (ANC) can be used as an indicator of phosphate sorption capacity of coal ashes.

  3. Sorption of aqueous phosphorus onto bituminous and lignitous coal ashes

    Aiming at the development of a phosphorus removal technology for waste water, phosphate (PO43-) retention behavior of bituminous and lignitous coal ashes was investigated using a batch reactor. Ash samples, including fresh and weathered fly and bottom ashes, were studied for their sorption isotherms and reversibility. Fly ashes had a much higher phosphate retention capacity (4000-30,000 mg P/kg) than bottom ashes (15-600 mg P/kg). Lignitous coal ashes were more capable of retaining phosphate than bituminous coal ashes. The retention process was largely irreversible, and the irreversibility increased with the increase in the retention capacity. Weathering enlarged the retention capacity of the bituminous bottom ash, but substantially lowered that of the fly ash, likely due to the difference in the weather-induced changes between the fly and bottom ashes. Sorption isotherms of fly ashes were found to be adequately represented by the Langmuir model while those of bottom ashes fitted better to the Freundlich model. Concentrations of Ca2+ and PO43- in the aqueous phase were measured at the end of sorption and desorption experiments, and were compared with solubilities of three calcium phosphate minerals. The aqueous solutions were saturated or super-saturated with respect to tricalcium phosphate (Ca3(PO4)2) and hydroxyapatite (Ca5(PO4)3OH), and slightly under-saturated with respect to amorphous calcium phosphate. It is concluded that precipitation of calcium phosphate is the predominant mechanism for phosphate retention by coal ash under the conditions studied. There is a strong and positive correlation between alkalinity and phosphate sorption capacity. Consequently, acid neutralization capacity (ANC) can be used as an indicator of phosphate sorption capacity of coal ashes

  4. Fuel properties of bituminous coal and pyrolytic oil mixture

    Hamdan, Hazlin; Sharuddin, Munawar Zaman; Daud, Ahmad Rafizan Mohamad; Syed-Hassan, Syed Shatir A.

    2014-10-01

    Investigation on the thermal decomposition kinetics of coal-biooil slurry (CBS) fuel prepared at different ratios (100:0,70:30,60:40,0:100) was conducted using a Thermogravimetric Analyzer (TGA). The materials consisted of Clermont bituminous coal (Australia) and bio-oil (also known as pyrolytic oil) from the source of Empty Fruit Bunch (EFB) that was thermally converted by means of pyrolysis. Thermal decomposition of CBS fuel was performed in an inert atmosphere (50mL/min nitrogen) under non-isothermal conditions from room temperature to 1000°C at heating rate of 10°C/min. The apparent activation energy (Ea.) and pre-exponential factor (A) were calculated from the experimental results by using an Arrhenius-type kinetic model which first-order decomposition reaction was assumed. All kinetic parameters were tabulated based on the TG data obtained from the experiment. It was found that, the CBS fuel has higher reactivity than Clermont coal fuel during pyrolysis process, as the addition of pyrolytic oil will reduce the Ea values of the fuel. The thermal profiles of the mixtures showed potential trends that followed the characteristics of an ideal slurry fuel where high degradation rate is desirable. Among the mixture, the optimum fuel was found at the ratio of 60:40 of pyrolytic oil/coal mixtures with highest degradation rate. These findings may contribute to the development of a slurry fuel to be used in the vast existing conventional power plants.

  5. Deformation Properties and Fatigue of Bituminous Mixtures

    Frantisek Schlosser; Jan Mikolaj; Viera Zatkalikova; Juraj Sramek; Dominika Durekova; Lubos Remek

    2013-01-01

    Deformation properties and fatigue performance are important characteristics of asphalt bound materials which are used for construction of pavement layers. Viscoelastic asphalt mixtures are better characterized via dynamic tests. This type of tests allows us to collate materials with regard to axle vibrations which lie usually in the range of 6 Hz–25 Hz for standard conditions. Asphalt modified for heat sensitivity in the range from −20°C to +60°C has significant impact on the overall charact...

  6. Deformation Properties and Fatigue of Bituminous Mixtures

    Frantisek Schlosser

    2013-01-01

    Full Text Available Deformation properties and fatigue performance are important characteristics of asphalt bound materials which are used for construction of pavement layers. Viscoelastic asphalt mixtures are better characterized via dynamic tests. This type of tests allows us to collate materials with regard to axle vibrations which lie usually in the range of 6 Hz–25 Hz for standard conditions. Asphalt modified for heat sensitivity in the range from −20°C to +60°C has significant impact on the overall characteristics of the mixture. Deformation properties are used as inputs for empirical mixture design, and fatigue performance of asphalt mixtures reflects the parameters of functional tests. Master curves convey properties of asphalt mixtures for various conditions and allow us to evaluate them without the need of time expensive testing.

  7. Use of bottom ash from thermal power plant and lime as filler in bituminous mixtures

    López-López, E.

    2015-06-01

    Full Text Available This study focuses on the characterization of bottom ash (PCC-BA and determining the mechanical characteristics of hot mix asphalt (HMA using PCC-BA and hydrated lime (HL as filler. Physical and chemical characterization of the bottom ash was carried out to evaluate its eventual reutilization as filler substitute. The materials tested in this study were made using 0%, 25%, 50%, 70% and 100% of PCC-BA combined with HL. HMA mixes were evaluated in terms of their engineering properties, namely: air voids in the mixes, water sensitivity, stiffness modulus, performance in wheel tracking test and fatigue resistance. The results obtained indicate that HMA mixes with a filler blend of 70% PCC-BA and 30% HL fulfil European standards and are suitable for light traffic or small infrastructures.Este estudio se centra en la caracterización de las cenizas de fondo (PCC-BA y la determinación de las características mecánicas de mezclas bituminosas en caliente (HMA, utilizando cenizas de fondo y la cal hidratada (HL como filler. Se realizó la caracterización física y química de las cenizas de fondo para evaluar su empleo como sustituto de filler. Las mezclas ensayadas en este estudio se realizaron utilizando 0%, 25%, 50%, 70% y 100% de cenizas de fondo combinadas con cal hidratada. Se evaluaron propiedades ingenieriles de las mezclas bituminosas, tales como los huecos de aire en las mezclas, la sensibilidad al agua, el módulo de rigidez, el ensayo de pista y la resistencia a la fatiga. Los resultados obtenidos indican que las mezclas bituminosas fabricadas con una combinación de filler del 70% de cenizas de fondo y el 30% cal hidratada, cumplen con las normas europeas y son adecuados para su aplicación con tráficos ligeros o en pequeñas infraestructuras.

  8. Fatigue and healing properties of bituminous mastics reinforced with nano-sized additives

    Santagata, Ezio; Baglieri, Orazio; Tsantilis, Lucia; Dalmazzo, Davide; Chiappinelli, Giuseppe

    2016-03-01

    The research work described in the paper focused on fatigue and healing properties of bituminous mastics reinforced with nano-sized additives. Commercially available multiwall carbon nanotubes (CNTs) and montmorillonite nanoclay (NC) were combined with a single base bitumen and a standard mineral filler to produce bituminous mastics. These blends were prepared in the laboratory by making use of a technique consisting in simple shear mixing followed by sonication. Fatigue behaviour of mastics under repeated loading was investigated by means of time sweeps performed in the strain-controlled mode at various amplitudes. Healing potential was assessed by adopting a testing protocol specifically conceived to discriminate between recovery of damage induced by fatigue loading and other artefact phenomena which may affect material response. All rheological measurements were carried out with a dynamic shear rheometer in the parallel plates geometry. Outcomes of the experimental investigation were found to be highly dependent on the nature of additive type, as a result of the key role played by interaction mechanisms that nano-particles can establish within the bituminous mastic.

  9. Time dependent viscoelastic rheological response of pure, modified and synthetic bituminous binders

    Airey, G. D.; Grenfell, J. R. A.; Apeagyei, A.; Subhy, A.; Lo Presti, D.

    2016-04-01

    Bitumen is a viscoelastic material that exhibits both elastic and viscous components of response and displays both a temperature and time dependent relationship between applied stresses and resultant strains. In addition, as bitumen is responsible for the viscoelastic behaviour of all bituminous materials, it plays a dominant role in defining many of the aspects of asphalt road performance, such as strength and stiffness, permanent deformation and cracking. Although conventional bituminous materials perform satisfactorily in most highway pavement applications, there are situations that require the modification of the binder to enhance the properties of existing asphalt material. The best known form of modification is by means of polymer modification, traditionally used to improve the temperature and time susceptibility of bitumen. Tyre rubber modification is another form using recycled crumb tyre rubber to alter the properties of conventional bitumen. In addition, alternative binders (synthetic polymeric binders as well as renewable, environmental-friendly bio-binders) have entered the bitumen market over the last few years due to concerns over the continued availability of bitumen from current crudes and refinery processes. This paper provides a detailed rheological assessment, under both temperature and time regimes, of a range of conventional, modified and alternative binders in terms of the materials dynamic (oscillatory) viscoelastic response. The rheological results show the improved viscoelastic properties of polymer- and rubber-modified binders in terms of increased complex shear modulus and elastic response, particularly at high temperatures and low frequencies. The synthetic binders were found to demonstrate complex rheological behaviour relative to that seen for conventional bituminous binders.

  10. The hydrogasification of lignite and sub-bituminous coals

    Bhatt, B.; Fallon, P. T.; Steinberg, M.

    1981-02-01

    A North Dakota lignite and a New Mexico sub-bituminous coal have been hydrogenated at up to 900°C and 2500 psi hydrogen pressure. Yields of gaseous hydrocarbons and aromatic liquids have been studied as a function of temperature, pressure, residence time, feed rates and H2/coal ratio. Coal feed rates in excess of 10 lb/hr have been achieved in the 1 in. I. D.×8 ft reactor and methane concentration as high as 55% have been observed. A four-step reaction model was developed for the production and decomposition of the hydrocarbon products. A single object function formulated from the weighted errors for the four dependent process, variables, CH4, C2H6, BTX, and oil yields, was minimized using a program containing three independent iterative techniques. The results of the nonlinear regression analysis for lignite show that a first-order chemical reaction model with respect to C conversion satisfactorily describes the dilute phase hydrogenation. The activation energy for the initial products formation was estimated to be 42,700 cal/gmole and the power of hydrogen partial pressure was found to be +0.14. The overall correlation coefficient was 0.83. The mechanism, the rate expressions, and the design curves developed can be used for scale-up and reactor design.

  11. Bituminization of simulated waste, spent resins, evaporator concentrates and animal ashes by extrusion process

    The results of the study of bituminization of simulated radwaste - spennt ion-exchange resins, borate evaporator/concentrates and animal ashes, are presented and discussed. Distilled and oxidizer bitumen were used. Characterization of the crude material and simulated wastes-bitumen mixtures of varying weigt composition (30, 40, 50, 60% by weight of dry waste material) was carried out. The asphaltene and parafin contents in the bitumens were also determined. Some additives and were used with an aim to improve the characteristcs of solidified wastes. For leaching studies, granular ion-exchange resins were with Cs - 134 and mixtures of resin-bitumen were prepared. The leaching studies were executed using the IAEA recommendation and the ISO method. A conventional screw-extruder, common in plastic industry, was used determine operational parameters and process difficulties. Mixtures of resin-bitumen and evaporator concentrate-bitumen obtained from differents operational conditions were characterized. (Author)

  12. Is Atomic Force Microscopy suited as Tool for fast Screening of Bituminous Materials? An Inter-laboratory Comparison Study

    Nahar, S.N.; Dillingh, B.; Erkens, S.M.J.G.; Schmets, A. J. M.; Fischer, H.R.; Scarpas, A.; Schitter, G.

    2013-01-01

    Bituminous binders are known to have microstructures at typical length scales of micrometers. This microstructure can be probed with Atomic Force Microscopy (AFM). Now that worldwide several research groups are reporting AFM results on bitumen, it is becoming important to improve the understanding of the reproducibility and objectivity of the technique for studying bituminous samples. When reproducibility and stability are proven, AFM can be a tool for asphalt professionals to rapidly screen ...

  13. A Predictive Model of Fragmentation using Adaptive Mesh Refinement and a Hierarchical Material Model

    Koniges, A E; Masters, N D; Fisher, A C; Anderson, R W; Eder, D C; Benson, D; Kaiser, T B; Gunney, B T; Wang, P; Maddox, B R; Hansen, J F; Kalantar, D H; Dixit, P; Jarmakani, H; Meyers, M A

    2009-03-03

    Fragmentation is a fundamental material process that naturally spans spatial scales from microscopic to macroscopic. We developed a mathematical framework using an innovative combination of hierarchical material modeling (HMM) and adaptive mesh refinement (AMR) to connect the continuum to microstructural regimes. This framework has been implemented in a new multi-physics, multi-scale, 3D simulation code, NIF ALE-AMR. New multi-material volume fraction and interface reconstruction algorithms were developed for this new code, which is leading the world effort in hydrodynamic simulations that combine AMR with ALE (Arbitrary Lagrangian-Eulerian) techniques. The interface reconstruction algorithm is also used to produce fragments following material failure. In general, the material strength and failure models have history vector components that must be advected along with other properties of the mesh during remap stage of the ALE hydrodynamics. The fragmentation models are validated against an electromagnetically driven expanding ring experiment and dedicated laser-based fragmentation experiments conducted at the Jupiter Laser Facility. As part of the exit plan, the NIF ALE-AMR code was applied to a number of fragmentation problems of interest to the National Ignition Facility (NIF). One example shows the added benefit of multi-material ALE-AMR that relaxes the requirement that material boundaries must be along mesh boundaries.

  14. Long-term behavior of bituminized waste: modelling of auto-irradiation and leaching

    During interim storage, the main evolution factor of the bituminized wastes is radiolysis under auto-irradiation, while in deep disposal conditions, after radioactive decrease, site resaturation with water, and container corrosion, the main factor of evolution is leaching by water. This paper presents two models, designed to describe respectively radiolytic gas evacuation, and bituminized waste alteration under leaching. The first model is based on the integration of simple descriptions of gas production by radiolysis, gas diffusive transport, bubble nucleation and ripening, and bubble transport under buoyancy and viscosity. The second model is based on simple descriptions of water adsorption and solubilization at the surface, water diffusion into the matrix, water uptake by the most soluble salts, salt grain swelling and alteration of matrix waterproofing, diffusive transport of salts out of the waste. Copyright (2001) Material Research Society

  15. Feasibility study of producing lump fuel using oil-bituminous sands

    Moldybaev, A.B.; Ermagambetov, B.T.; Mamraeva, K.M.; Shin, R.G.; Bakirova, R.K. (Institut Organicheskogo Sinteza i Uglekhimii AN KazSSR (USSR))

    1991-04-01

    Describes production of lump fuel by briquetting and coking different mixtures of non-caking coal with coal preparation sludge and bitumen extracted from oil sands. The coal used was from the Shubarkol'sk coal deposit (USSR); the sludge was from the Saburkhanskaya preparation plant. Properties and composition of oil-bituminous sands and of bitumen to be used as binder are given. Technological details of the briquetting and coking processes are provided. Results show that briquets produced from mixtures of coal and oil-bituminous sands can only be used as a high-ash lump fuel, which cannot be further processed into semicoke. Experiments were carried out briquetting coal or coke, sludge and 6-8% bitumen extracted from the sands, varying coal or coke grain fractions and composition of the mixture. An increased briquet strength was found after using the vacuum-distilled 300-350 C bitumen fraction. Briquets from this non-caking coal with bitumen binder are regarded as ecologically clean fuel. 5 refs.

  16. Development of non-standard equipment of bituminization line

    A brief description is presented of some components of the bituminization line developed at the Research Institute of Chemical Installations in Brno. The film rotor evaporator has an evaporation area of 2 m2. The mixing tank is the main technological assembly for processing loose materials, i.e., sorbents and fly ash which it mixes with melted bitumen. The screw conveyor with a three-way valve is designed for batching the dried radioactive sorbent and fly ash into mixing tanks. Attention is also devoted to certain systems of measurement and control of the bituminization line, namely to measurement of the level of the bituminization product, the flow rate of bituminization emulsion and the water-sorbent mixture and to the diagnostics of failure and accident conditions of the film rotor evaporator. (Z.M.)

  17. Bituminous reference document: synthesis of knowledge on the long time behavior of bituminous packages

    This document is a synthesis of the knowledge acquired at the CEA on the behavior of bituminous packages. In this framework, the CEA studied bituminous packages in generic conditions of a package lifetime. The main factors, the evolution mechanisms and influential parameters have been determined and quantitative s simulation have been developed. After a description of the main initial bituminous packages characterizations, the evolutions in saturated and un-saturated environment are exposed. (A.L.B.)

  18. Slagging behavior of upgraded brown coal and bituminous coal in 145 MW practical coal combustion boiler

    Akiyama, Katsuya; Pak, Haeyang; Takubo, Yoji [Kobe Steel, Ltd, Kobe (Japan). Mechanical Engineering Research Lab.; Tada, Toshiya [Kobe Steel, Ltd, Takasago (Japan). Coal and Energy Technology Dept.; Ueki, Yasuaki [Nagoya Univ. (Japan). Energy Science Div.; Yoshiie, Ryo; Naruse, Ichiro [Nagoya Univ. (Japan). Dept. of Mechanical Science and Engineering

    2013-07-01

    The purpose of this study is to quantitatively evaluate behaviors of ash deposition during combustion of Upgraded Brown Coal (UBC) and bituminous coal in a 145 MW practical coal combustion boiler. A blended coal consisting 20 wt% of the UBC and 80 wt% of the bituminous coal was burned for the combustion tests. Before the actual ash deposition tests, the molten slag fractions of ash calculated by chemical equilibrium calculations under the combustion condition was adopted as one of the indices to estimate the tendency of ash deposition. The calculation results showed that the molten slag fraction for UBC ash reached approximately 90% at 1,523 K. However, that for the blended coal ash became about 50%. These calculation results mean that blending the UBC with a bituminous coal played a role in decreasing the molten slag fraction. Next, the ash deposition tests were conducted, using a practical pulverized coal combustion boiler. A water-cooled stainless-steel tube was inserted in locations at 1,523 K in the boiler to measure the amount of ash deposits. The results showed that the mass of deposited ash for the blended coal increased and shape of the deposited ash particles on the tube became large and spherical. This is because the molten slag fraction in ash for the blended coal at 1,523 K increased and the surface of deposited ash became sticky. However, the mass of the deposited ash for the blended coal did not greatly increase and no slagging problems occurred for 8 days of boiler operation under the present blending conditions. Therefore, appropriate blending of the UBC with a bituminous coal enables the UBC to be used with a low ash melting point without any ash deposition problems in a practical boiler.

  19. Uraniferous lignites and bituminous clays of the Serres Basin. Pt. A

    The lignites of the southern area (Christos-Vissiani-Lefkes-Perdikari) and the bituminous clay silts of the northern area (Maramena, Ano Metohi, Chrysopigi) are the main uraniferous beds in the Serres Basin. The sediments of the basin (Upper Miocene to recent) have been stratigraphically divided into three informal unities: the Lefkon, Georgios and Spilia formations. The uraniferous lignites pertaining to the Lefkon limnic-fluvial formation are developed into two discrete horizons, the upper Double Seam and the lower Main Seam. The bituminous clays are of the same age with the lignites, those of Maramena being, however, younger, equivalent to the marine and brackish Georgios formation. The continuity, thickness and dip of the strata reveal considerable regional changes resulting from the intense tectonism of the basin. Further to the surface works the upper lignites have been reached through small excavations and also about 100 boreholes totalling 10,000 m have been drilled. The composition of the organic constituents and the calorific value show a dull transitional to shiny hard lignite with ash rich in pyrite and sulphur. There have been no discrete U minerals detected, while the electron microprobe analysis showed that the uranium is uniformly disseminated into the lignite mass, mainly absorbed through its humic acids. More than 75% of the uranium is extractable, the control of its combustion conditions being, however, a major problem. The potential reserves have been up to date estimated to be of over 4,000 tons (uranium metal), this figure resulting mainly from data evaluated from the borehole γ-ray logs using the computer programmes LOGFILE and LOGPLOT developed at the Radioactive Raw Materials Dept. of the Greek AEC. (author)

  20. Leachability of bituminized radioactive waste. Literature survey

    Bituminized radioactive waste that will be returned from COGEMA, France is planned to be disposed of in deep geologic repository in Japan. Data on leachability of radionuclides from bituminized waste are required for the performance assessment of the disposal. We made a literature survey on bitumen and bituminized radioactive waste, placing emphasis on leach tests and leach data in terms of geologic disposal. This survey revealed that reliable leach data on transuranium elements and data obtained under reducing conditions that is characteristic to deep underground are lacking. (author). 64 refs

  1. Use of waste plastic in construction of bituminous road

    Abhijeet Jirge

    2012-05-01

    Full Text Available Bottles, containers and packing strips etc. is increasing day by day. As a result amount of waste plastic also increases. This leads to various environmental problems. Many of the wastes produced today will remain in the environment for many years leading to various environmental concerns. Therefore it is necessary to utilize thewastes effectively with technical development in each field. Many by-products are being produced using the plastic wastes. Our present work is helping to take care of these aspects. Plastic waste, consisting of carry bags, cups and other utilized plastic can be used as a coating over aggregate and this coated stone can be used for roadconstruction. The mix polymer coated aggregate and tyre modified bitumen have shown higher strength. Use of this mix for road construction helps to use plastics waste. Once the plastic waste is separated from municipal solid waste, the organic matter can be converted into manure and used. Our paper will discuss in detail theprocess and its successful applications.

  2. Use of waste plastic in construction of bituminous road

    Abhijeet Jirge; Karan patil; Mrs.Vidula Swami; Suhas patil; Sushil patil; Karan salokhe

    2012-01-01

    Bottles, containers and packing strips etc. is increasing day by day. As a result amount of waste plastic also increases. This leads to various environmental problems. Many of the wastes produced today will remain in the environment for many years leading to various environmental concerns. Therefore it is necessary to utilize thewastes effectively with technical development in each field. Many by-products are being produced using the plastic wastes. Our present work is helping to take care of...

  3. Project and design of apparatus and equipment of pilot plant experimental bituminization line PS 44 EBO

    The modifications are described made in the design of major components of the pilot plant experimental bituminization line involving: the mixing equipment, the film rotor evaporator, the calciner, and various transport mechanisms for handling drums and containers. The difficulty and complexity of the problem which Kralovopolska strojirna Brno, the end supplier of the bituminization line, will have to tackle is evident mainly from the case of bridge cranes, which feed the line, and the full-portal gantry crane which handles the containers and drums at regional sites of radioactive waste disposal. (Z.M.)

  4. Evaluating Self Healing Capability of Bituminous Mastics

    Qiu, J.; Ven, M. van de; Wu, S.; Yu, J.; Molenaar, A.

    2012-01-01

    The self-healing capability of bituminous materials has been known for many years. Researches were mostly focused on the self healing behaviour during load repetitions. The tests are either time consuming and/or complex. In this paper, a simple self healing test procedure is presented combining the fracture-healing-re-fracture test (FHR) with morphological observations. A fast displacement speed loading was applied first to produce a flat open crack with a crack width of 100–200 μm. Then the ...

  5. Study on Plastic Coated Overburnt Brick Aggregate as an Alternative Material for Bituminous Road Construction

    Dipankar Sarkar

    2016-01-01

    Full Text Available There are different places in India where natural stone aggregates are not available for constructional work. Plastic coated OBBA can solve the problem of shortage of stone aggregate to some extent. The engineers are always encouraged to use locally available materials. The present investigation is carried out to evaluate the plastic coated OBBA as an alternative material for bituminous road construction. Shredded waste plastics are mixed with OBBA in different percentages as 0.38, 0.42, 0.46, 0.50, 0.54, and 0.60 of the weight of brick aggregates. Marshall Method of mix design is carried out to find the optimum bitumen content of such bituminous concrete mix prepared by plastic coated OBBA. Bulk density, Marshall Stability, flow, Marshall Quotient, ITS, TSR, stripping, fatigue life, and deformations have been determined accordingly. Marshall Stability value of 0.54 percent of plastic mix is comparatively higher than the other mixes except 0.60 percent of plastic mix. Test results are within the prescribed limit for 0.54 percent of plastic mix. There is a significant reduction in rutting characteristics of the same plastic mix. The fatigue life of the mix is also significantly higher. Thus plastic coated OBBA is found suitable in construction of bituminous concrete road.

  6. Development and operation experience from pilot-plant for bituminization of liquid radioactive wastes (UBD-200)

    The results are given for investigations of liquid radioactive wastes bituminization on the pilot-plant of continious operation. The bituminization process is divided into two stages. On the first stage salts with definite moisture content are obtained. On the second stage, wet salts are mixed with melted bitumen. In this process the salts are finally dryed and bitumen compound produced is transported towards the discharge assembly. Design of the dryer and mixer is described and their technical parameters are given. Salt-bitumen compound is discharged in moulding bogies with volume of 0.5 m3. After hardening, salt-bitumen compound blocks are removed for burial. Average composition of liquid radioactive wastes coming for solidification is given. Dependences of the salt-bitumen compound characteristics on the parameters of the technological process of bituminization are given as well as the results of analysis of filling of compound by salts at the block height of 0.3 m. It is shown that division of the bituminization process into two stages do not affect on the chemical stability of compound. (I.T.)

  7. Natural analogues of bitumen and bituminized radioactive waste

    Occurrences of natural bitumen provide possibilities to identify and assess materials, processes, phenomena and conditions in nature which can serve as model cases valid also with respect to a final repository. Natural bitumens meet the basic requirements for use as natural analogues. In natural sites, processes of bitumen formation and degradation often work simultaneously. The major processes are thermal alteration, evaporation, reaction with water, biodegradation, oxidation, weathering and radiation degradation. Progress in analytical organic geochemistry made during recent years has enabled a deeper understanding of the structural and compositional effects of these processes on bitumen. This is necessary in natural analogue applications. The time scales involved in degradation processes, as observed in natural occurrences, exceed the time scales dictated by the half-lives of most important fission products in low and medium level waste by orders of magnitude. Only exposure to the weather at the surface leads to a more rapid destruction of bitumen. Trace metals in bitumen arenot released until the matrix is completely destroyed. Products of radiation degradation and weathering of bitumen are able, to a certain degree, to delay migration of the metal ions released. Impregnation with bitumen may effectively reduce the microbial decomposition of easily destructable organic waste components, as can be deduced on the basis of the excellent preservation of fossils observed in bitumen. The complexity of all the natural sites described requires extensive understanding of the origin and kind of organic material in bitumen, its maturation, migration, alteration and degradation and of the geological and tectonic evolution of the site. The latter is used for establishing the time scale

  8. Examination and comparision of structure: lignite, bituminous and anthracite coal. [10 references

    Winans, R.E.; Hayatsu, R.; Scott, R.G.; Moore, L.P.; Studier, M.H.

    1976-01-01

    Coal can be described as an amorphous mixture of macromolecules each made up of a complex array of organic molecules chemically linked together. Methods for breaking up these macromolecules in order to characterize the aromatic structural types have been explored. Pyrolysis is a common method for depolymerizing coal, but under the conditions necessary for pyrolysis much structural rearrangement occurs making a comparison of the products to the initial structural groups in coal difficult if not impossible. One approach has been to use a variety of selective oxidation methods. Aqueous sodium dichromate, aqueous air oxidation with uv light, and hydrogen peroxide in acetic acid have been used. Initial results of some of these studies have been published. This work has been extended to include characterization and comparison of a lignite, bituminous coal, and anthracite. Besides the oxidation products, the monomeric organic molecules trapped within the macromolecules are examined and the results interpreted in relation to coal structure and the coalification process.

  9. Petrography and geochemistry of Oligocene bituminous coal from the Jiu Valley, Petrosani basin (southern Carpathian Mountains), Romania

    Belkin, Harvey E.; Tewalt, Susan J. [U.S. Geological Survey, 956 National Center, Reston, VA 20192 (United States); Hower, James C. [University of Kentucky Center for Applied Energy Research, 2540 Research Park Drive, Lexington, KY 40511 (United States); Stucker, J.D. [University of Kentucky Center for Applied Energy Research, 2540 Research Park Drive, Lexington, KY 40511 (United States); University of Kentucky Department of Earth and Environmental Sciences, Lexington, KY 40506 (United States); O' Keefe, Jennifer M.K. [Morehead State University, Morehead, KY, 40351 (United States); Tatu, Calin A. [University of Medicine and Pharmacy, Department of Immunology, Clinical Laboratory No. 1, Pta. E. Murgu No. 2, RO-1900 Timisoara (Romania); Buia, Grigore [University of Petrosani, Department of Geology, University St. 20, RO-2675 Petrosani (Romania)

    2010-05-01

    Belt samples of Oligocene (Chattian) bituminous coal from 10 underground mines located in the Jiu Valley, Hunedoara County, Petrosani basin, Romania, have been examined and analyzed for proximate and ultimate analysis, major-, minor- and trace-element chemistry, organic petrography, and vitrinite reflectance. The mineral chemistry and mode of occurrence of trace elements also have been investigated using SEM and electron microprobe techniques. Twenty coal beds occur in the Jiu Valley and most of the samples are from bed no. 3, the most productive bed of the Dilja-Uricani Formation of Oligocene age. The Petrosani basin, oriented SW-NE, is 48-km long, 10-km wide at the eastern part and 2-km wide at the western part. The coal mines are distributed along the center of the valley generally following the Jiu de Vest River. Reflectance measurements indicate that the rank of the coals ranges from high-volatile B to high-volatile A bituminous. Overall, rank decreases from the southwest to the northeast. In bed no. 3, R{sub max} varies from 0.75% in the northeast to 0.93% in the southwest. Although, most Oligocene coals in Romania and adjacent countries are lignite in rank, the Jiu Valley bituminous coals have been affected by regional metamorphism and attending hydrothermal fluids related to the Alpine orogenic event. The coals are all dominated by vitrinite; resinite and funginite are important minor macerals in most of the coals. Pyrite and carbonate generally dominate the mineral assemblages with carbonate more abundant in the northwest. Siderite occurs as nodules and masses within the macerals (generally vitrinite). Dolomite and calcite occur as fracture fillings, plant-cell fillings, and in other authigenic forms. Late-stage fracture fillings are siderite, dolomite, calcite, and ankerite. In one instance, two populations of siderite ({proportional_to} 35 and {proportional_to} 45 wt.% FeO) plus ankerite fill a large fracture. Late-stage pyrite framboid alteration is Ni

  10. Parametric and dynamic studies of an iron-based 25-kWth coal direct chemical looping unit using sub-bituminous coal

    Highlights: • Integrated, moving bed chemical looping reactor with iron-oxide based oxygen carrier. • Coal carbon conversion from 84.8% to 99.9%, thermal capacity 7.4 to 27.7 kWth, O2 demand less than 1.3%. • Dynamic temperature of moving bed reducer is established and tracked during coal injection. • CH4 and CO present at initial coal injection, eliminated after oxygen carrier activated. • Lower coal injection had higher volatiles residence time and conversion. - Abstract: The iron-based Coal-Direct Chemical Looping (CDCL) combustion process is an alternative to conventional oxy-combustion technologies, where the oxygen used for fuel conversion in the CDCL process is provided by an iron-oxide based oxygen carrier instead of an air separation unit. The iron oxide is reduced using coal in the reducer reactor, producing highly-pure CO2 in the flue gas, and the reduced iron oxide is regenerated in a separate combustor reactor using air. The CDCL process at Ohio State has been developed and demonstrated in a 25 kWth sub-pilot unit, and it is the first chemical looping demonstration unit with a circulating moving bed reactor for solid fuel conversion. To date, the CDCL sub-pilot unit at OSU has been operated for more than 680 h, with a 200-h continuous operation, providing important data on long term operability as well as parametric optimization. This paper discusses recent parametric operational experience with sub-bituminous coal as the fuel, where dynamic changes in variables were performed to observe the effects on the unit itself. Measurements included temperature, pressure, and gas concentrations from the reducer and combustor. Furthermore, effects of different variables, such as flue gas recycle ratios (enhancer gas flow rates), feed port injection, and temperature, were observed. Tests confirmed high coal conversions with high purity of CO2 achieved in the flue gas. Overall, the moving bed design of the reducer results in nearly full coal conversion

  11. Physical properties of solid fuel briquettes from bituminous coal waste and biomass

    ZARRINGHALAM-MOGHADDAM A; GHOLIPOUR-ZANJANI N; DOROSTIS; VAEZ M

    2011-01-01

    Biomass and bituminous coal fines from four different coalfields were used to produce fuel briquettes.Two physical properties of briquettes,water resistance index and compressive strength were analyzed.The influence of type and quantity of biomass on physical properties was also studied.The results reveal that depending on the mineral content of the coal,the physical properties of the briquettes differ noticeably.The comparison of briquettes with and without biomass showed that the presence of the beet pulp increased CS in all types of coal samples.Samples containing beet pulp had better physical properties than sawdust.Mezino Ⅱ coal briquettes had highest CS and WRI than the other ones.Calorific value of biomass/Mezino Ⅱ coal briquettes was lessened in comparison with raw coal,but it remained in an acceptable range.

  12. Effect of organic calcium compounds on combustion characteristics of rice husk, sewage sludge, and bituminous coal: thermogravimetric investigation.

    Zhang, Lihui; Duan, Feng; Huang, Yaji

    2015-04-01

    Experiments were conducted in a thermogravimetric analyzer to assess the enhancement of combustion characteristics of different solid fuels blended with organic calcium compounds (OCCs). Rice husk, sewage sludge, and bituminous coal, and two OCC were used in this study. Effect of different mole ratios of calcium to sulfur (Ca/S ratio) on the combustion characteristics were also investigated. Results indicated that combustion performance indexes for bituminous coal impregnated by OCC were improved, however, an inverse trend was found for sewage sludge because sewage sludge has lower ignition temperature and higher volatile matter content compared to those of OCC. For rice husk, effect of added OCC on the combustion characteristics is not obvious. Different solid fuels show different combustion characteristics with increases of Ca/S ratio. The maximum combustion performance indexes appear at Ca/S ratios of 1:1, 2:1, and 3:1 for OCC blended with Shenhua coal, rice husk, and sewage sludge, respectively. PMID:25638405

  13. Computational micromechanical analysis of the representative volume element of bituminous composite materials

    Ozer, Hasan; Ghauch, Ziad G.; Dhasmana, Heena; Al-Qadi, Imad L.

    2016-08-01

    Micromechanical computational modeling is used in this study to determine the smallest domain, or Representative Volume Element (RVE), that can be used to characterize the effective properties of composite materials such as Asphalt Concrete (AC). Computational Finite Element (FE) micromechanical modeling was coupled with digital image analysis of surface scans of AC specimens. Three mixtures with varying Nominal Maximum Aggregate Size (NMAS) of 4.75 mm, 12.5 mm, and 25 mm, were prepared for digital image analysis and computational micromechanical modeling. The effects of window size and phase modulus mismatch on the apparent viscoelastic response of the composite were numerically examined. A good agreement was observed in the RVE size predictions based on micromechanical computational modeling and image analysis. Micromechanical results indicated that a degradation in the matrix stiffness increases the corresponding RVE size. Statistical homogeneity was observed for window sizes equal to two to three times the NMAS. A model was presented for relating the degree of statistical homogeneity associated with each window size for materials with varying inclusion dimensions.

  14. Distribution of inorganic and organic substances in the hydrocyclone separated Slovak sub-bituminous coal

    Anton Zubrik; Slavomir Hredzak; Ludmila Turcaniova; Michal Lovas; Ingo Bergmann; Klaus Dieter Becker; Maria Lukcova; Vladimir Sepelak [Slovak Academy of Sciences, Kosice (Slovakia). Institute of Geotechnics

    2010-08-15

    A low-rank Slovak sub-bituminous coal from the Handlova deposit was physically treated by washing in a water-only cyclone with the goal to find the separation effect for inorganic (mainly Fe-bearing minerals) and organic substances (humic acids, diterpanes). A high-quality coal product with the ash content in the dry matter of 9.02% and carbon content of C{sup d} = 68.12% at a mass yield of 29.51% was obtained using the water-only cyclone processing. At first, the physically treated coal samples were detailed characterized by XRD, {sup 57}Fe Moessbauer spectroscopy, FT-IR and HR-TEM. In addition to non-crystalline organic coal components, inorganic compounds belonging to silicate minerals (kaolinite, muscovite and quartz) as well as to Fe-bearing sulphide minerals (pyrite) were identified in the sub-bituminous coal by XRD. {sup 57}Fe Moessbauer spectroscopy detected the presence of iron carbonate (siderite), iron-containing clay mineral and two sulphur-containing minerals (pyrite, jarosite) in the untreated coal. On the other hand, only one Fe-bearing mineral, (pyrite) was found in the washed coal. Effect of the physical separation is also demonstrated in FT-IR spectra, where the peak at 1040 cm{sup -1} representing the silicate component in the untreated sample is not detectable in the washed coal sample. Presence of extractive organic substances, i.e. humic acids and tetracyclic diterpane (16a(H)-phyllocladane), in the hydrocyclone products is also evidenced. It was confirmed that the isolated diterpenoic compound is attendant in the washed product with the lowest ash content and it is assimilated with the organic part of coal. Surprisingly, humic acids were found in the highest concentration in the slurry that has the highest content of ash (63.14%). 54 refs., 8 figs., 5 tabs.

  15. Adaptive Strategies for Materials Design using Uncertainties

    Balachandran, Prasanna V.; Xue, Dezhen; Theiler, James; Hogden, John; Lookman, Turab

    2016-01-01

    We compare several adaptive design strategies using a data set of 223 M2AX family of compounds for which the elastic properties [bulk (B), shear (G), and Young’s (E) modulus] have been computed using density functional theory. The design strategies are decomposed into an iterative loop with two main steps: machine learning is used to train a regressor that predicts elastic properties in terms of elementary orbital radii of the individual components of the materials; and a selector uses these predictions and their uncertainties to choose the next material to investigate. The ultimate goal is to obtain a material with desired elastic properties in as few iterations as possible. We examine how the choice of data set size, regressor and selector impact the design. We find that selectors that use information about the prediction uncertainty outperform those that don’t. Our work is a step in illustrating how adaptive design tools can guide the search for new materials with desired properties.

  16. Skid resistance of bituminous surfaces in Ohio

    Colony, D. C.

    1984-03-01

    Statistical studies of skid number (SN) on the state highway system in Ohio reveal apparently systematic variations in distributions of SN among the twelve districts in the state. These variations appear to be significantly related to traffic and to geological characteristics of a given district. Regression calculations using traffic index, a function of ADT and age of the pavement surface in months, show a high correlation with SN, although standard errors of estimate were too large to make the equations useful for predicting SN from traffic variables. Similar results were obtained by elating SN to physiographic features in the state. Pavement surface type (bituminous or pcc) and coarse aggregate type (limestone, gravel or slag) are significantly related to SN.

  17. Organic geochemistry of Upper Carboniferous bituminous coals and clastic sediments from the Lublin Coal Basin

    Gola, Marek R.; Karger, Michał; Gazda, Lucjan; Grafka, Oliwia

    2013-09-01

    Bituminous coals and clastic rocks from the Lublin Formation (Pennsylvanian, Westphalian B) were subjected to detailed biomarker and Rock-Eval analyses. The investigation of aliphatic and aromatic fractions and Rock-Eval Tmax suggests that the Carboniferous deposits attained relatively low levels of thermal maturity, at the end of the microbial processes/initial phase of the oil window. Somewhat higher values of maturity in the clastic sediments were caused by postdiagenetic biodegradation of organic matter. The dominance of the odd carbon-numbered n-alkanes in the range n-C25 to n-C31 , high concentrations of moretanes and a predominance of C 28 and C29 steranes are indicative of a terrigenous origin of the organic matter in the study material. This is supported by the presence of eudesmane, bisabolane, dihydro-ar-curcumene and cadalene, found mainly in the coal samples. In addition, tri- and tetracyclic diterpanes, e. g. 16β(H)-kaurane, 16β(H)-phyllocladane, 16α(H)-kaurane and norisopimarane, were identified, suggesting an admixture of conifer ancestors among the deposited higher plants. Parameters Pr/n-C17 and Rdit in the coal samples show deposition of organic matter from peat swamp environments, with the water levels varying from high (water-logged swamp) to very low (ephemeral swamp). Clastic deposits were accumulated in a flood plain environment with local small ponds/lakes. In pond/lake sediments, apart from the dominant terrigenous organic matter, research also revealed a certain quantity of algal matter, indicated, i.a., by the presence of tricyclic triterpanes C28 and C29 and elevated concentrations of steranes. The Paq parameter can prove to be a useful tool in the identification of organic matter, but the processes of organic matter biodegradation observed in clastic rocks most likely influence the value of the parameter, at the same time lowering the interpretation potential of these compounds. The value of Pr/Ph varies from 0.93 to 5.24 and from 3

  18. Environmental problems caused by bituminous schist and possible solutions

    Schist, as a disposal of mine, has harmful effects on environment. however, several manners can be utilized to prevent the environmental destruction as well as an economical benefit is gained. In this study, environmental problems caused by bituminous schist and other disposals have been investigated on a specific lignite coal mine where schist is disposed as waste material. Pollution and damage on land and in water sources around the coal district and the villages have been observed, recorded and several solutions to environmental problems have been proposed. Discussed proposals will not only solve the environmental pollution problem but also provide waste management facility. Industrial structure of the district enables such a disposal to be used as an economical raw material. Besides, general effects of the coal mine and the power plant nearby have been discussed from environmental point of view, too. 7 refs

  19. Measurement of heat generation from simulated bituminized product

    The fire and explosion incident occurred at Bituminization Demonstration Facility of PNC Tokai Works on March 11, 1997. In order to ascertain the cause of incident, the investigation has been pushed forward. For the investigation, we prepared simulated bituminized product of measurement of heat generation in low temperature region less than 200degC. We used calvet Calorimeter MS80 for the heat generation measurement. Result of measurement, we were able to catch the feeble heat generation from bituminized product. The maximum calorific value that was able to detect it in isothermal measurement was approximately 1 mW/g in 160degC. It was approximately 2 mW/g in 200degC. And, as the another measurement, the measurement condition went heat rate by 0.01degC/minute, the highest temperature 190degC. As a result, the maximum generation of heat value that was able to detect it was approximately 0.5 mW/g. I changed simulated bituminized products and measured these. A difference of condition is salt particle size, salt content rate (45%, 60%), addition of the simulated precipitate. But there was not a difference in the generation of heat characteristic detected. (author)

  20. THE HISTORY OF EXPLORATION AND EXPLOITATION OF BITUMINOUS AND KEROGENOUS DEPOSITS IN CROATIA

    Berislav Šebečić

    1995-12-01

    Full Text Available It is assumed thal the first known sedimens of natural bitumen or asphalt in coastal Croatia were exploited as the early moddle ages. Yet authenticated written documents about Vinišće near Trogir derive from no earlier than 1628, about Vrgorac/Paklina from only 1753. By the end of the 18th century, many deposits were discovered in Dalmatia, but it was Škrip on the Island of Brač and Suhi Dolac that were important. The earliest known deposits and occurrences of kerogenous rocks, or bituminous or oil shales, are mentioned as stone or fossil coal in Sovinjak, in the upper course of the River Mirna, and in Rebići in Istria; near Sinj, Slivno not far from the River Neretva, Mirta and near Nerežišće on the Island uf Brač. All if these were well known and described in 1804, while Sovinjak was mentioned in the 16th century. In the article, some of new information derived from mining and geological research into bituminous and kerogenous sediments and deposits are provided (the paper is published in Croatian.

  1. Disposal of bituminized and other low- and medium-level wastes: Waste characterization and the retention of migrating radionuclides by steel corrosion products

    Biegalski, Kendra Mylene Foltz

    1998-09-01

    The validity of using scaling factors with the reference nuclide, sp{137}Cs, for activity determinations of sp{238}Pu, sp{239,\\ 240}Pu, and sp{241}Am in low- and medium-level bituminized and unconditioned evaporator concentrates (ECs) produced at Riso National Laboratory (RNL), Denmark was investigated. The presence of constant activity ratios between sp{137}Cs and the Pu isotopes above was predicted because a large part of this waste stream originated from research on irradiated light water reactor fuel. Activity ratios were measured in different waste samples by comparison of gamma-measurements to results from destructive analyses using alpha-spectrometry. Results were verified using activity ratios of spent low-enriched fuel from the literature. Continuation studies on the mechanisms influencing releases from bituminized low- and medium-level wastes were performed by leach tests on samples of various compositions and exposed to diverse environments. Four compositions of bituminized materials were studied including (1) bitumen with NaNOsb3 and BaSOsb4, (2) bitumen with NaNOsb3, BaSOsb4, and Nisb2Fe(CN)sb6, (3) bitumen with NaNOsb3, BaSOsb4, Nisb2Fe(CN)sb6, and K-soap, and (4) bituminized RNL ECs. Leachant solutions used included (1) filtered deionized water, (2) 0.001-N KOH, (3) 0.01-N KOH, and (4) 0.001-N Ca(OH)sb2. One trial was exposed to high-humidity air while two others had a cement disk suspended in the leachant. Some of the resulting data was used for the on-going validation of the SWL (Swelling, Water uptake, and Leaching) code created at RNL. To improve the accuracy of projected releases from radioactive waste disposal systems, the sorption characteristics of steel corrosion products were investigated with a special emphasis on competitive sorption between Sr and Na. The corrosion rate of steel exposed to various environments was studied qualitatively and, with some systems, quantitatively. Traditional and non-traditional adsorption

  2. Fire and explosion incident at bituminization demonstration facility of PNC Tokai works, on march 11, 1997

    On March 11, a fire and explosion incident occurred at the Bituminization Demonstration Facility (BDF) of Tokai Reprocessing Plant in Power Reactor and Nuclear Fuel Development Corporation (PNC). Soon after the incident, PNC (now reorganized to JNC) started to investigate the facility damage, operational records around the incident, technical notes including facility design and reviews of R and D results, operators witness and to perform several analysis, tests and calculations. This paper describes outline and cause of the incident which were concluded based on the results of continuous serious investigation, analysis and calculation. (author)

  3. Analysis and modeling of 3D complex modulus tests on hot and warm bituminous mixtures

    Pham, Nguyen Hoang; Sauzéat, Cédric; Di Benedetto, Hervé; González-León, Juan A.; Barreto, Gilles; Nicolaï, Aurélia; Jakubowski, Marc

    2015-05-01

    This paper presents the results of laboratory testing of hot and warm bituminous mixtures containing Reclaimed Asphalt Pavement (RAP). Complex modulus measurements, using the tension-compression test on cylindrical specimens, were conducted to determine linear viscoelastic (LVE) behavior. Sinusoidal cyclic loadings, with strain amplitude of approximately 50ṡ10-6, were applied at several temperatures (from -25 to +45 °C) and frequencies (from 0.03 Hz to 10 Hz). In addition to axial stresses and strains, radial strains were also measured. The complex modulus E ∗ and complex Poisson's ratios ν ∗ were then obtained in two perpendicular directions. Measured values in these two directions do not indicate anisotropy on Poisson's ratio. The time-temperature superposition principle (TTSP) was verified with good approximation in one-dimensional (1D) and three-dimensional (3D) conditions for the same values of shift factor. Experimental results were modeled using the 2S2P1D model previously developed at the University of Lyon/ENTPE. In addition, specific analysis showed that eventual damage created during complex modulus test is very small and is equivalent to the effect of an increase of temperature of about 0.25 °C.

  4. Single particle ignition and combustion of anthracite, semi-anthracite and bituminous coals in air and simulated oxy-fuel conditions

    Riaza Benito, Juan; Khatami, Reza; Levendis, Yiannis A.; Álvarez González, Lucía; Gil Matellanes, María Victoria; Pevida García, Covadonga; Rubiera González, Fernando; Pis Martínez, José Juan

    2014-01-01

    A fundamental investigation has been conducted on the combustion behavior of single particles (75–150 μm) of four coals of different ranks: anthracite, semi-anthracite, medium-volatile bituminous and high-volatile bituminous. A laboratory-scale transparent laminar-flow drop-tube furnace, electrically-heated to 1400 K, was used to burn the coals. The experiments were performed in different combustion atmospheres: air (21%O2/79%N2) and four simulated dry oxy-fuel conditions: 21%O2/79%CO2, 30%O2...

  5. Bituminization of radioactive waste concentrates from reprocessing, nuclear research establishments and nuclear power plants

    This report is a summary of the major results of R and D work performed at the Karlsruhe Nuclear Research Center from 1967 until 1977 for fixing radioactive waste concentrates in bitumen and for characterizing the resulting products. Moreover, the report provides a compilation of operating experience gathered at the Karlsruhe Nuclear Research Center in bituminizing low and medium level evaporator concentrates. The report also contains the results of R and D work carried out by external institutes on behalf of the KfK. (orig.)

  6. Characterisation of cemented/bituminized LAW and MAW waste products

    In the context of work for characterising low and medium activity waste products, investigations were carried out to determine the release of radioactivity from binding waste in given accidents, such as mechanical and thermal loading for the operating phase of a final store. The effects of mechanical loads on MAW cement products and the effects of thermal laods on MAW cement and MAW bitumen products were examined. The release of fine dust reaching the lungs, with a particle size of ≤10 μm from a 200 litre roller seam cement binder with a maximum mechanical load of 3x105 Nm covering the accident case is about 1.5 g and therefore corresponds to ≅ 10-4% of the total radio-activity inventory for homogeneous products. With thermal loading (60 minute oil fire, 8000C) ≅ 10-3% of the radioactivity inventory is released via the release of water from the waste binder. The activity release of MAW bitumen products containing NaNO3 (175 litre drum) with thermal load is considerably higher, as due to the NaNO3 content of the products, after an induction period of about 20 minutes there is an exothermal reaction between the bitumen and the NaNO3, which leads to burning of the bitumen with considerable aerosol formation. The Na losses are about 32% and the Pu losses, derived from the results of laboratory experiments with samples containing Eu and Pu and samples containing Eu on the original size, are only 15% maximum, even with complete burn up. It was shown for all the investigations with samples of the original size that the effects of the load cases considered can be reduced or completely avoided by additional packing (concrete shielding). (orig./RB)

  7. Contribution to physico-chemical study of Timahdit bituminous schists (Morocco): Organic matters and metalloporphyrins

    The Timahdit bituminous schists have been analysed by different methods. The experimental results obtained using these methods concern the behaviour of the schists and the Kerogen facing the pyrolysis, as well as the separation of the hydrocarbons and the metalloporphyrins. For this purpose the techniques used are: 'Rock Eval' pyrolysis, thermogravimetric analysis and electron paramagnetic resonance (E.P.R.) for the raw rock and the Kerogen; infrared (I.R.), gas chromatography and E.P.R. for the extracted organic matters; E.P.R., I.R., nuclear magnetic resonance (N.M.R.), ultraviolet (U.V.) and mass spectrometry for the metalloporphyrins identification and characterization. The analysis of these schists has shown that: We can extract per solvent only 1% of organic matters, ferric oxide hasn't any effect neither on the pyrolysis nor on the organic matters extraction and that the Kerogen of these schists are relatively rich in hydrocarbonic compounds. The gas chromatography reveal the presence of alkanes with odd number of carbons and isoprenoids. All these criteria indicate an immature, little developped organic matter which having probably a marine origin but possessing a good oil potential. It has also been observed that a part of Iron, Nickel and Vanadium in the schists are incorporated into the organic matters. Nickel and Vanadium are into macrocycles which are porphyrins. A method for extracting and separating these porphyrins has been developped. 43 figs., 21 tabs., 58 refs. (author)

  8. Assessment of 137Cs and 90Sr leachate rate from bituminous radioactive wastes in surface soil disposal

    Experimental disposal of tested bitumen units with 107 Bq/kg 137Cs and 90Sr specific activity in surface soil was conducted to evaluate environmental impact of bituminized radioactive wastes. Calculations of volume integral were carried out using computer. Due to determination of integral numerical value it was founded, that 1.6x108 Bq enter soil from the unit during 10 years. The obtained value may be used as normalizing parameter at simulation of radionuclide leaching from monolithic forms as well as for correct selection of boundary conditions in dispersion equation at simulation of radioactive contamination migration

  9. Radiation-chemical transformation of synthetic oil from oil-bituminous rock

    Full text : Like as test subject was used synthetic oil from oil-bituminous rocks of Balakhany deposit. The regularities of synthetic oils radiation-chemical transformations were studied. Laboratory researches were carried out in an interval of absorbed dose 43-216 kGr and dose rate 0.5 Gr/s. Concentration, radiation-chemical yields of the received gases in the various absorbed doses were established. Results of researches allow to estimate possibility use of oil products received from synthetic oil for isolation of radioactive sources from environment. The purpose of the given work is research of radiation stability of synthetic oil from bituminous rock. Results of such researches will allow to estimate possibility of production different purpose oil products from synthetic oil in a radiation-chemical way and also use of these materials for isolation of radioactive sources from environment

  10. Study on the submicron and micron morphology and the properties of poor bituminous coal burnout

    Pei-Fang Fu; Huai-Chun Zhou; Qing-Yan Fang; Hai Yao; Jianrong Qiu; Minghou Xu [Huazhong University of Science and Technology, Wuhan (China). State Key Laboratory of Coal Combustion

    2007-05-15

    Carbon burnout and its reaction mechanism have been widely focused on in the past decades. The properties of burnout, submicron and micron morphology and the reaction mechanism of poor bituminous coal/char (PBC) in a W-shaped power plant boiler was studied and was compared with those in DTF and in TGA, which showed that the degree of PBC burnout in TGA at 1450{sup o}C was greater than or approximately equal to that in a W-shaped boiler, and that the complexity of the reactions among residual char, oxygen and SiO{sub 2} did not seem to result in mass loss in TGA, although the weight percentage of the residual char in ash decreased from 33% ad (air dry basis) at 900{sup o}C to 9% and at 1450{sup o}C. According to the distribution of pores and the properties of the char burnout, the char can be simply categorized into three classes: char burnout easy, char burnout difficult and char burnout very difficult. The differences of the reaction mechanism must be considered while predicting the burning rate and degree of char burnout in a full-scale boiler by making use of experimental results from TGA and DTF. A different char particle contains markedly different amount of carbons, but for a special char particle, the ratio of carbon to ash is generally constant, and an ash shell does not exist on the char surface. The fusion mineral matter composing of C-O-Si-Al is amorphous, not in the form of Al{sub 2}O{sub 3} and SiO{sub 2} above 1450{sup o}C.

  11. Combustion characteristics and arsenic retention during co-combustion of agricultural biomass and bituminous coal.

    Zhou, Chuncai; Liu, Guijian; Wang, Xudong; Qi, Cuicui; Hu, Yunhu

    2016-08-01

    A combination of thermogravimetric analysis (TG) and laboratory-scale circulated fluidized bed combustion experiment was conducted to investigate the thermochemical, kinetic and arsenic retention behavior during co-combustion bituminous coal with typical agricultural biomass. Results shown that ignition performance and thermal reactivity of coal could be enhanced by adding biomass in suitable proportion. Arsenic was enriched in fly ash and associated with fine particles during combustion of coal/biomass blends. The emission of arsenic decreased with increasing proportion of biomass in blends. The retention of arsenic may be attributed to the interaction between arsenic and fly ash components. The positive correlation between calcium content and arsenic concentration in ash suggesting that the arsenic-calcium interaction may be regarded as the primary mechanism for arsenic retention. PMID:27136608

  12. Long-term properties of bituminized waste products

    This study is a survey of the factors of importance for long term behaviour of bituminized ion exchange resins. Phenomena occurring in bituminized waste products affected by the treatment, storage and disposal are identified. Test methods have been developed for characterizing product properties, which are important for the long-term behaviour. The long-term properties of bituminized ion-exchange resins are studied in a repository environment with access of water equilibrated with concrete. In these circumstances the most important properties are ralated to the interactions of bituminized waste with the surrounding barriers. The most important phenomena are water uptake due to rehydration of the resins and subsequent swelling of the product. (author)

  13. Long-term properties of bituminized waste products

    This study is a survey of the factors of importance for the long term behaviour of bituminized ion exchange resins. Phenomena occurring in bituminized waste products affected by the treatment, storage and disposal are identified. Test methods have been developed for characterizing product properties, which are important for the long-term behaviour. The long-term properties of bituminized ion-exchange resins are studied in a repository environment with access of water equilibrated with concrete. In these circumstances the most important properties are related to the interactions of bituminized waste with the surrounding barriers. The most important phenomena are water uptake due to rehydration of the resins and subsequent swelling of the product

  14. Amenability of Muzret bituminous coal to oil agglomeration

    Sahinoglu, E.; Uslu, T. [Karadeniz Technical University, Department of Mining Engineering, 61080 Trabzon (Turkey)

    2008-12-15

    Laboratory scale agglomeration tests were undertaken to investigate the amenability of Muzret (Yusufeli-Artvin) bituminous coal to oil agglomeration. Kerosene was extensively used as oil in the tests. In addition, fuel oil, diesel oil, and hazelnut oil were also used in order to determine the effect of oil type. The effects of the parameters including coal content, kerosene content, agglomeration time, coal particle size, pH, oil type, and agitation rate, on the combustible matter recovery, ash reduction and pyritic sulphur reduction, were investigated. It was found that Muzret bituminous coal could be readily cleaned by oil agglomeration with substantial reductions in ash and pyritic sulphur content. Maximum combustible matter recovery, ash reduction and pyritic sulphur reduction were achieved to be 85.54%, 59.98%, and 85.17%, respectively. (author)

  15. Effect of Cement on Properties of Over-Burnt Brick Bituminous Concrete Mixes

    Sarkar, Dipankar; Pal, Manish

    2016-06-01

    The present investigation is carried out to propose the use of cement coated over burnt brick aggregate in the preparation of bituminous concrete mix. The effect of cement on various mechanical properties such as Marshall stability, flow, Marshall quotient (stability to flow ratio), indirect tensile strength, stripping, rutting and fatigue life of bituminous concrete overlay has been evaluated. In this study, different cement percentages such as 2, 3, 4 and 5 % by weight of aggregate have been mixed with Over Burnt Brick Aggregate (OBBA). The laboratory results indicate that bituminous concrete prepared by 4 % cement coated OBBA gives the highest Marshall stability. The bituminous concrete mix with 4 % cement shows considerable improvement in various mechanical properties of the mix compared to the plain OBBA concrete mix.

  16. Inoculum density of Glomus mosseae and growth of onion plants in unsterilized bituminous coal spoil

    Khan, A.G.

    1988-01-01

    The effect of inoculum, density (number of vesicular-arbuscular mycorrhizal (VAM) propagules g/sup -1/ of inoculum) on the growth of onions (Allium cepa L.) infected by Glomus mosseae (Nicol and Gerd). Gerdemann and Trappe, Comb nov in unsterilized coal spoil containing indigenous VAM fungi, including G. mosseae, was investigated. The amount of onion roots converted to mycorrhizas by inoculant fungus, estimated by a gridline intersect method, increased with inoculum density (..gamma..0.62, P0.05) until a plateau was reached. Onion growth responses also increased significantly (P<0.05) with the amount of VAM inoculum present in the coal spoil. The initial linear relationship between inoculum propagules (MPN estimates), percent colonization of onion roots and onion shoot dry weight became quadratic as the number of infection propagules increased. VAM infection had no significant effect on root:shoot ratios. Similarly there was no significant interaction (P>0.05) between the inoculum density, VAM-colonized root mass and the onion root:shoot fresh weight ratios. The amount of the windswept bituminous coal spoil bound to VAM (presumably because of VAM external hyphae) also increased as inoculum density increased (..gamma..0.63, P<0.05). There was a stronger correlation (ga0.85, P<0.05) between the amount of spoil adhered per plant and the root fresh wt plant/sup -1/ indicating that root effects were primarily responsible for increasing spoil adherence. There were negative correlations (P<0.05) between root fresh wt plant/sup -1/ (..gamma..-0.68), inoculum density (..gamma..-0.589), percent root elngth infected (..gamma..-0.73) and the amount of spoil adhered g/sup -1/ root fresh wt. The possible exploitation of VAM in revegetation of bituminous coal spoil is discussed. 25 refs., 2 tabs.

  17. Identification of aggregates for Tennessee bituminous surface courses

    Sauter, Heather Jean

    Tennessee road construction is a major venue for federal and state spending. Tax dollars each year go to the maintenance and construction of roads. One aspect of highway construction that affects the public is the safety of its state roads. There are many factors that affect the safety of a given road. One factor that was focused on in this research was the polish resistance capabilities of aggregates. Several pre-evaluation methods have been used in the laboratory to predict what will happen in a field situation. A new pre-evaluation method was invented that utilized AASHTO T 304 procedure upscaled to accommodate surface bituminous aggregates. This new method, called the Tennessee Terminal Textural Condition Method (T3CM), was approved by Tennessee Department of Transportation to be used as a pre-evaluation method on bituminous surface courses. It was proven to be operator insensitive, repeatable, and an accurate indication of particle shape and texture. Further research was needed to correlate pre-evaluation methods to the current field method, ASTM E 274-85 Locked Wheel Skid Trailer. In this research, twenty-five in-place bituminous projects and eight source evaluations were investigated. The information gathered would further validate the T3CM and find the pre-evaluation method that best predicted the field method. In addition, new sources of aggregates for bituminous surface courses were revealed. The results of this research have shown T3CM to be highly repeatable with an overall coefficient of variation of 0.26% for an eight sample repeatability test. It was the best correlated pre-evaluation method with the locked wheel skid trailer method giving an R2 value of 0.3946 and a Pearson coefficient of 0.710. Being able to predict field performance of aggregates prior to construction is a powerful tool capable of saving time, money, labor, and possibly lives.

  18. Kinetics and equilibrium modeling of uranium(VI) sorption by bituminous shale from aqueous solution

    Highlights: • Oil shales are sedimentary rocks containing a polymeric matter in a mineral matrix. • Sorption potential of bituminous shale (BS) for uranium recovery was investigated. • U(VI) sorption increased with decreasing pH and increasing temperature. • Kinetic data were analyzed based on single and two resistance diffusion models. • The results fit well to the McKay equation assuming film and intraparticle diffusion. - Abstract: Sorption of U(VI) onto a bituminous shale (BS) from a nuclear power plant project site in Black Sea region was investigated for potential risk assessment when it releases into the environment with contaminated ground and surface water. The sorption characteristics of the BS for U(VI) recovery were evaluated as a function of contact time, adsorbent dosage, initial concentration, pH and temperature. Kinetic results fit better with pseudo-second-order model rather than pseudo-first-order. The possibility of diffusion process was analyzed based on Weber–Morris intra-particle diffusion model. The McKay equation assuming film- and intraparticle diffusion better predicted the data than the Vermeulen approximation presuming surface diffusion. Equilibrium sorption data were modeled according to the Langmuir, Dubinin–Radushkevich (D–R) and Freundlich isotherm equations. Sorption capacity increased from 0.10 to 0.15 mmol g−1 in 298–318 K temperature range. FT-IR analysis and pH dependent sorption studies conducted in hydroxide and carbonate media revealed that U(VI) species were sorbed in uranyl and its hydroxo forms on the BS. Desorption studies showed that U(VI) leaching with Black Sea water was negligible from the loaded BS. The activation parameters (Ea, ΔH∗ and ΔG∗) estimated from diffusion coefficients indicated the presence of an energy barrier in the sorption system. However, thermodynamic functions derived from sorption equilibrium constants showed that overall sorption process was spontaneous in nature and

  19. Comparison of marginal adaptation of mineral trioxide aggregate, glass ionomer cement and intermediate restorative material as root-end filling materials, using scanning electron microscope: An in vitro study

    Sirisha Gundam; Jayaprakash Patil; Bhuvan Shome Venigalla; Sravanthi Yadanaparti; Radhika Maddu; Sindhura Reddy Gurram

    2014-01-01

    Aim: The present study compares the marginal adaption of Mineral Trioxide Aggregate (MTA), Glass Ionomer Cement (GIC) and Intermediate Restorative Material (IRM) as root-end filling materials in extracted human teeth using Scanning Electron Microscope (SEM). Materials and Methods: Thirty single rooted human teeth were obturated with Gutta-percha after cleaning and shaping. Apical 3 mm of roots were resected and retrofilled with MTA, GIC and IRM. One millimeter transverse section of the retrof...

  20. Adaptation of College English Classroom Materials

    余跃

    2015-01-01

    Materials adaptation involves changing existing materials so that they become more suitable for specific learners, teach⁃ers or situations. This paper reviews the current state of this field, and makes suggestions for and gives example of innovative and principled approaches to college English classroom materials adaptation.

  1. Effect of oxidation on the chemical nature and distribution of low-temperature pyrolysis products from bituminous coal

    Furimsky, E.; MacPhee, J.A.; Vancea, L.; Ciavaglia, L.A.; Nandi, B.N.

    1983-04-01

    Two bituminous coals, a high volatile Eastern Canadian and a medium volatile Western Canadian, were used to investigate the effect of oxidation on yields and chemical composition of gases, liquids and chars produced during coal pyrolysis. Pyrolysis experiments were performed at 500 C using the Fischer assay method. Mild oxidation of coals resulted in a decrease of liquid hydrocarbon yields. Further coal oxidation increased the proportion of aromatic carbon in liquid products as determined by N.M.R. and also increased the content of oxygen in liquid products. The content of oxygen in chars was markedly lower than in corresponding coals. An attempt is made to explain reactions occurring during oxidation and subsequent pyrolysis of coal on the basis of differences in chemical composition of gases, liquids and chars. (19 refs.)

  2. Effect of oxidation on the chemical nature and distribution of low-temperature pyrolysis products from bituminous coal

    Furimsky, E.; Ciavaglia, L.A.; MacPhee, J.A.; Nandi, B.N.; Vancea, L.

    1983-04-01

    Two bituminous coals, a high volatile Eastern Canadian and a medium volatile Western Canadian, were used to investigate the effect of oxidation on yields and chemical composition of gases, liquids and chars produced during coal pyrolysis. Pyrolysis experiments were performed at 500/sup 0/C using the Fischer assay method. Mild oxidation of coals resulted in a decrease of liquid hydrocarbon yields. Further coal oxidation increased the proportion of aromatic carbon in liquid products as determined by n.m.r., and also increased the content of oxygen in liquid products. The content of oxygen in chars was markedly lower than in corresponding coals. An attempt is made to explain reactions occurring during oxidation and subsequent pyrolysis of coal on the basis of differences in chemical composition of gases, liquids and chars.

  3. Study on the cause of the fire and explosion incident at Bituminization Demonstration Facility of PNC Tokai Works

    On March 11, 1997, a fire and explosion incident occurred in Bituminization Demonstration Facility (BDF) at Tokai Reprocessing Plant (TRP). The cause of the incident was thoroughly investigated and after thirty meetings of 'Investigation Committee of Science and Technology Agency (STA)'. STA reported possible cause of this incident. Continually detailed investigation was discussed at 'Follow-up Committee of STA'. Based on the results of five meetings, JNC concluded that the main cause of fire was frictional heating and viscous heating in the extruder, which provided an unusually high temperature in the bituminized product at filling, since there was no chemical analysis data suggesting the generation of chemical heat. It is considered that these excessive heat generations were due to the decreased feed rate of liquid waste to the extruder. The Follow-up Committee almost agreed to this conclusion. This paper describes general information concerning the incident and details of the cause of the incident. (author)

  4. The bituminization in Marcoule and la Hague plants. Description of the processes and the fire risk prevention

    Chemical precipitation is an efficient process to decontaminate liquid effluents and has been selected as early as 1966 for the liquid waste treatment of MARCOULE. The process has been designed by the French CEA and improved along the time. The first implementation in LA HAGUE was for the STE 2 facility (Station de Traitement d'Effluents no 2). A new facility, STE 3, has been commissioned in 1989 in LA HAGUE, benefiting from these previous experience and therefore contributing into a drastic reduction of liquid discharges. The sludges coming from the treatment in MARCOULE and STE 3 are bituminized into continuous extruders. The resulting waste is kept in interim storage, waiting for final disposal. The industrial production, up to now, is close to 10000 drums (55 gallons) in LA HAGUE and 60000 drums in MARCOULE. A retrieval operation of the MARCOULE drums from the present storage has been launched to send them into a recently built interim storage operating since the beginning of 2000. At the present time, in LA HAGUE, evaporation has been preferred to chemical precipitation for the treatment of liquid effluents. After concentration, the effluents go to the vitrification and the volume of resulting waste is much smaller. However, bituminization is still the preferred option for the 10000 m3 of sludges resulting from the STE 2 operations which are being stored in tanks. A complete reevaluation of the operation safety measures of bituminization has been made lately in both plants following recent incidents on other installations. The paper describes the chemical precipitation and the bituminization processes and focuses on safety measures which are implemented for prevention, detection and fight. (authors)

  5. Combustion characteristics of Malaysian oil palm biomass, sub-bituminous coal and their respective blends via thermogravimetric analysis (TGA).

    Idris, Siti Shawalliah; Rahman, Norazah Abd; Ismail, Khudzir

    2012-11-01

    The combustion characteristics of Malaysia oil palm biomass (palm kernel shell (PKS), palm mesocarp fibre (PMF) and empty fruit bunches (EFB)), sub-bituminous coal (Mukah Balingian) and coal/biomass blends via thermogravimetric analysis (TGA) were investigated. Six weight ratios of coal/biomass blends were prepared and oxidised under dynamic conditions from temperature 25 to 1100°C at four heating rates. The thermogravimetric analysis demonstrated that the EFB and PKS evolved additional peak besides drying, devolatilisation and char oxidation steps during combustion. Ignition and burn out temperatures of blends were improved in comparison to coal. No interactions were observed between the coal and biomass during combustion. The apparent activation energy during this process was evaluated using iso-conversional model free kinetics which resulted in highest activation energy during combustion of PKS followed by PMF, EFB and MB coal. Blending oil palm biomass with coal reduces the apparent activation energy value. PMID:22944493

  6. Adaptability of Alfalfa and Ryegrass to New Reclamation Materials

    WANG ZHAO-FENG; ZHANG Lei-na; FENG Yong-jun; KANG Jing-tao

    2006-01-01

    This paper discussed the adaptability of the alfalfa and ryegrass to the new artificial soil that was composed of fly ash and furfural residue. The potted experiments were taken to compare the growth conditions, yields, and qualities of both grasses. Some pots were covered with wheat stalks and others without. The medium Fluvo-aquic soil was taken as control. The results indicated that the growth of two grasses in the mixture were inferior to their growth in the control in initial period. With the leaching of rain and irrigation, the two grasses improved gradually. The alfalfa and ryegrass both could grow in the new mixture, and the ryegrass would be better to plant in no covered material and the alfalfa in covered. This will be a new way to reclaim subsided land and to improve the environment in mining area.

  7. Retardation of the spontaneous ignition of bituminous coal

    Dong, X.; Drysdale, D. [University of Edinburgh, Edinburgh (United Kingdom). Department of Civil Engineering and Building Science

    1995-12-31

    The effect of five retardants on a bituminous coal has been investigated in a temperature-controlled oven. The activation energy of oxidation in the coal inhibited by one of the retardants increases by up to 20kJ/mol, in comparison to that of the coal wetted with water. The factors affecting inhibition are considered. A kinetic interpretation of the retardation mechanism is proposed, and the possibility of using the most effective retarder in practice is discussed. 12 refs., 1 fig., 2 tabs.

  8. Effect of transesterification degree and post-treatment on the in-service performance of NCO-functionalized vegetable oil bituminous products

    Cuadri Vega, Antonio Abad; García Morales, Moisés; Navarro Domínguez, Francisco Javier; Partal López, Pedro

    2014-01-01

    The bitumen modification through polyurethane prepolymers presents significant benefits for the manufacture of bituminous products for the paving industry. In this sense, this work explores the use, as bitumen modifier, of a novel reactive prepolymer synthesized by reaction of 4,4´,diphenylmethane diisocyanate (MDI) and a vegetable oil-based polyol, castor oil (CO), previously transesterified with pentaerythritol. On the one hand, thermal analysis on transesterified CO revealed a highly stabl...

  9. Detection of rare earth elements in Powder River Basin sub-bituminous coal ash using laser-induced breakdown spectroscopy (LIBS)

    Tran, Phuoc [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United State; Mcintyre, Dustin [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United State

    2015-10-01

    We reported our preliminary results on the use of laser-induced breakdown spectroscopy to analyze the rare earth elements contained in ash samples from Powder River Basin sub-bituminous coal (PRB-coal). We have identified many elements in the lanthanide series (cerium, europium, holmium, lanthanum, lutetium, praseodymium, promethium, samarium, terbium, ytterbium) and some elements in the actinide series (actinium, thorium, uranium, plutonium, berkelium, californium) in the ash samples. In addition, various metals were also seen to present in the ash samples

  10. Comparison of marginal adaptation of mineral trioxide aggregate, glass ionomer cement and intermediate restorative material as root-end filling materials, using scanning electron microscope: An in vitro study

    Gundam, Sirisha; Patil, Jayaprakash; Venigalla, Bhuvan Shome; Yadanaparti, Sravanthi; Maddu, Radhika; Gurram, Sindhura Reddy

    2014-01-01

    Aim: The present study compares the marginal adaption of Mineral Trioxide Aggregate (MTA), Glass Ionomer Cement (GIC) and Intermediate Restorative Material (IRM) as root-end filling materials in extracted human teeth using Scanning Electron Microscope (SEM). Materials and Methods: Thirty single rooted human teeth were obturated with Gutta-percha after cleaning and shaping. Apical 3 mm of roots were resected and retrofilled with MTA, GIC and IRM. One millimeter transverse section of the retrofilled area was used to study the marginal adaptation of the restorative material with the dentin. Mounted specimens were examined using SEM at approximately 15 Kv and 10-6 Torr under high vacuum condition. At 2000 X magnification, the gap size at the material-tooth interface was recorded at 2 points in microns. Statistical Analysis: One way ANOVA Analysis of the data from the experimental group was carried out with gap size as the dependent variable, and material as independent variable. Results: The lowest mean value of gap size was recorded in MTA group (0.722 ± 0.438 μm) and the largest mean gap in GIC group (1.778 ± 0.697 μm). Conclusion: MTA showed least gap size when compared to IRM and GIC suggesting a better marginal adaptation. PMID:25506146

  11. Wetting of bituminized ion-exchangers under simulated repository conditions

    According to the present plans the spent nuclear fuel from four Finnish nuclear power units will be transferred after interim storage to the final disposal site where it will be encapsulated and disposed of in a final repository constructed into the bedrock at a depth of 500 meters. Low and medium level waste generated at nuclear power plants will be finally disposed of in caverns constructed in the bedrock at the power plant site. The safety of the final disposal is based on a multibarrier concept and the degree of safety is estimated by using predictive models. The properties of the waste form are taken into account in the design of the repository construction. Bitumen has been chosen as an immobilisation agent for the wet wastes at Olkiluoto Power Plant, where two BWR units, TVO 1 and TVO 2, have separate bituminization facilities designed by Asea-Atom. Properties of bituminized spent ion-exchange resins from Olkiluoto power plant have been studied by VTT Chemical Technology since the late 70's. These studies have concentrated mainly on determining the long-term behaviour of the bituminization product under the repository conditions. Current interest lies on wetted product as a diffusion barrier. For this purpose a microscopic method for the visualisation of the structure of the wetted product has been developed. The equilibration of the samples in simulated concrete groundwater is currently going on at a temperature of 5-8 deg. C. Preliminary results are presented in this paper. Diffusion experiments have been planned for the further characterising of the wetted product as a release barrier for radionuclides including modelling. (author)

  12. Petrographic and Vitrinite Reflectance Analyses of a Suite of High Volatile Bituminous Coal Samples from the United States and Venezuela

    Hackley, Paul C.; Kolak, Jonathan J.

    2008-01-01

    This report presents vitrinite reflectance and detailed organic composition data for nine high volatile bituminous coal samples. These samples were selected to provide a single, internally consistent set of reflectance and composition analyses to facilitate the study of linkages among coal composition, bitumen generation during thermal maturation, and geochemical characteristics of generated hydrocarbons. Understanding these linkages is important for addressing several issues, including: the role of coal as a source rock within a petroleum system, the potential for conversion of coal resources to liquid hydrocarbon fuels, and the interactions between coal and carbon dioxide during enhanced coalbed methane recovery and(or) carbon dioxide sequestration in coal beds.

  13. Cold bituminous mixes

    Delak, Boštjan

    2012-01-01

    Asphalt mix (short also asphalt) can be obtained from nature (natural asphalt) or produced technically (artificial asphalt), i. e. as a mix of bituminous binder, stone grain, and other additives that improve the asphalt properties. The beginnings of the use of asphalt can be traced from 6,000 to 4,000 BC since people back then knew some materials that contained bitumen as a binder. A more frequent use of the natural asphalt, however, starts around 3,000 BC. Different peoples used it primar...

  14. Utilization of Waste Clay from Boron Production in Bituminous Geosynthetic Barrier (GBR-B Production as Landfill Liner

    Müfide Banar

    2016-01-01

    Full Text Available Bituminous geomembranes, one type of geosynthetics, include a hot bituminous mixture with mineral filler and reinforcement. In this study, boron production waste clay (CW was used as filler to produce a geosynthetic barrier with bentonite, waste tire, and bitumen. Bentonite and waste tires were used as auxiliary fillers and bitumen as the binder. CW/bitumen, CW/bentonite/bitumen, and CW/waste tire/bitumen mixtures were prepared by using a laboratory mixer at 100°C. Hot mixtures were extruded into strips by using a lab-scale corotating twin screw extruder (L/D: 40 followed by die casting (2 mm × 100 mm. Glass fleece or nonwoven polyester was used as reinforcement material and while die casting, both sides of the reinforcement materials were covered with bituminous mixture. Thickness, mass per unit area, tensile strength, elongation at yield, and hydraulic conductivity were used to characterize the geomembranes. Among all geomembranes, nonwoven polyester covered with 30% bitumen-70% boron waste clay mixture (PK-BTM30CW70 was found to be the most promising in terms of structure and mechanical behaviour. After that, consequences of its exposure to distilled water (DW, municipal solid waste landfill leachate (L-MSW, and hazardous waste landfill leachate (L-HW were examined to use for an innovative impermeable liner on solid waste landfills.

  15. Unexpectedly high uptake of palladium by bituminous coals

    Lakatos, J. [Research Lab. for Mining Chemistry, Hungarian Academy of Sciences, Miskolc-Egyetemvaros (Hungary); Brown, S.D.; Snape, C.E. [Univ. of Strathclyde, Dept. of Pure and Applied Chemistry, Glasgow (United Kingdom)

    1997-12-31

    The uptake of palladium as a conversion catalyst onto coals of different rank was investigated. Palladium fixation occurs by a different mode to that for alkaline earth and first row transition metals. Therefore, the dispersion of relatively high concentration of palladium by an ion sorption process is even possible for bituminous coals. (orig.)

  16. Applied Technological Direction of Power Plant Ash and Slag Waste Management when Kuznetsk Bituminous Coal is Burned

    Lihach Snejana A.

    2016-01-01

    Full Text Available Currently a lot of power plants have a problem with storage of coal combustion solid by-products (ash and slag. Holding capacity of existing power plants available ash dumps were enlarged and modernized repeatedly. Many plants have two or even three of them. Today new ash dump construction is economically inconvenient due to need to assign new plots of land and their inconveniently big distance from a plant, which increase ash and slag transportation expenses. The goal of our research work is to find promising directions for ash and slag waste mass utilization based on Kuznetsk bituminous coals experimental data on ultimate composition and properties. The experimental research of ash, slag and their mixture samples from ash dumps brought us to conclusion that the most promising direction for these materials application in large quantities is construction industry including road construction. Be-sides, we lined up some other directions for ash, slag, and ash and slag mixture possible application. These directions might not provide mass utilization but they are promising from a point of view of the researched waste properties.

  17. Characterization of burning and CO2 gasification of chars from mixtures of Zonguldak (Turkey) and Australian bituminous coals

    In this study, different mixtures (30 wt.% + 70 wt.% and 50 wt.% + 50 wt.%, respectively) of Zonguldak bituminous coal (Turkey) and an Australian bituminous coal are carbonized to obtain char samples. The ignition temperatures of the samples are determined by sending O2 onto the samples in a system designed for determining the ignition temperature. The gasification reactivity of the chars in a CO2 atmosphere is also measured at temperatures between 800 deg. C and 1050 deg. C. The relationship between the ignition temperature and the burning character of the same samples is investigated thermogravimetrically. The moisture, ash and volatile matter analyses are also performed. An increase in carbonization temperature leads to a decrease in the amount of volatile matter. The differences between the effects of volatile matter on the ignition temperature and the gasification reactivity of the samples with CO2 might be explained by the change in pore structure and the varying catalytic effect of mineral components in the structure. It is also seen that there is a good correlation between the thermal analysis and the complete analysis results of the samples

  18. Behaviour of bituminized ion-exchangers under repository conditions

    This is a final report containing all the research activities and results from the period 13 July 1997-28 February 2001. The purpose of the research was to study the ageing behaviour of bituminized ion-exchanger product under simulated repository conditions. The chosen temperature in this study was 5-8 deg. C and the equilibration solution used was artificial concrete water to simulate the conditions in the final disposal. The aim was to study the properties of wetted product as a release barrier for such important waste nuclides as Sr-90 and Cs-137, which are normal constituents of the bituminized ion-exchangers. All the nine exchanged waters were analysed by ion chromatography (IC) including the follow-up of the water absorption of the samples. All the samples, which were picked up for microscopic examination, have also been analysed. A saturation-elution test was performed with one diffusion sample using tritium (H-3) as a tracer. The results have been presented and further modelling will be performed later. Further two diffusion samples were tested using H-3, Na-22 and Cl-36 as radioactive tracers. The equilibration solution was artificial concrete ground water spiked with H-3 and Na-22 and in the other case with H-3 and Cl-36. Tritium was an internal reference when comparing the results of the equilibration behaviour of Na-22 and Cl-36. From the radioactive input cells samples were taken as a function of time to monitor the equilibration process. Elution of the samples and modelling of the results will be performed later. Na-22 and Cl-36 were chosen to demonstrate the behaviour of a simple anion and cation. Diffusion tests with important waste nuclides Sr-90 and Cs-137 have been scheduled to years 2001-2002. The aim of the performed research project was to study the barrier properties of the bituminized product. The measured parameters and modelling of the results will reflect the behaviour of the wetted product as a part of the multibarrier system providing

  19. Low SO2 emission from CFB co-firing MSW and bituminous.

    Lu, Qing-Gang; Li, Zhi-Wei; Na, Yong-Jie; Ba, Shao-Lin; Sun, Yun-Kai; He, Jun

    2004-01-01

    Influence of co-firing rate on SO2 emission from co-firing municipal solid waste (MSW) and bituminous containing high amount of sulfur (1.79%) was studied in a 0.15 MWt circulating fluidized bed (CFB). The temperature selected is 1123 K, typical for MSW incineration using CFB. The particle concentration in the dilution zone of the furnace, the alkali metal concentration and sulfate concentration in the recirculating ash and fly ash, and flue gas composition were determined. The results showed that the addition of MSW leads to a significant decrease in SO2 emission. Concentration of SO2 in flue gas decreased to 0 with the co-firing rate greater than 51%. This reduction in SO2 emission is attributed both to the high particle concentration in the dilution zone of the furnace, the high content of alkali metals in the bed material, and to the comparatively high concentration of HCI in flue gas during co-firing of MSW and bituminous. PMID:15559820

  20. Performance of PAHs emission from bituminous coal combustion

    严建华; 尤孝方; 李晓东; 倪明江; 尹雪峰; 岑可法

    2004-01-01

    Carcinogenic and mutagenic polycyclic aromatic hydrocarbons (PAHs) generated in coal combustion have caused great environmental health concern. Seventeen PAHs (16 high priority PAHs recommended by USEPA plus Benzo[e]pyrene) present in five raw bituminous coals and released during bituminous coal combustion were studied. The effects of combustion temperature, gas atmosphere, and chlorine content of raw coal on PAHs formation were investigated. Two additives (copper and cupric oxide) were added when the coal was burned. The results indicated that significant quantities of PAHs were produced from incomplete combustion of coal pyrolysis products at high temperature, and that temperature is an important causative factor of PAHs formation. PAHs concentrations decrease with the increase of chlorine content in oxygen or in nitrogen atmosphere. Copper and cupric oxide additives can promote PAHs formation (especially the multi-ring PAHs) during coal combustion.

  1. Effect of bituminous coal properties on carbon dioxide and methane high pressure sorption

    Weishauptová, Zuzana; Přibyl, Oldřich; Sýkorová, Ivana; Machovič, Vladimír

    2015-01-01

    Roč. 139, JAN 1 (2015), s. 115-124. ISSN 0016-2361 Institutional support: RVO:67985891 Keywords : bituminous coal * sorption capacity * maceral composition * Upper Silesian Coal Basin Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.520, year: 2014

  2. Suitability of UK bituminous and Spanish lignitious coals and their blends of two stage liquefaction

    Flatman-Fairs, D.P.; Harrison, G. [Staffordshire University, Stoke-on-Trent (United Kingdom). School of Sciences

    1999-11-01

    Liquefaction experiments were carried out in spinning/falling basket autoclaves using samples of Kellingly (UK) and Samca (Spain) coals, and a process derived recycle solvent (PDRS). Hydrocracking experiments were carried out in a bomb type autoclave using sulphided NiMo catalyst. For the dissolution, experiments with the individual coals, the influence of temperature 380, 400 and 420{degree}C, and time 1 or 2 h was considered. For hydrocracking, preliminary experiments were carried out with a Kellingly coal liquid to establish appropriate reaction conditions for the hydrocracking of Kellingly and Samca coal liquid blends. There was some evidence of synergistic activity for conversion to dichloromethane (DCM) soluble material and antagonistic behaviour for conversion to tetrahydrofuran soluble/DCM insoluble material for dissolution of the coal blends, but hydrocracking of the coal liquid blends resulted in additive behaviour. For each of the coals, the extent of dissolution correlated with the extent of desulphurisation. The sulphur contents of the solid residues from dissolution tended to increase with the temperature of dissolution, but their H:C ratios decreased and their calorific values were independent. 12 refs., 7 figs., 3 tabs.

  3. DEVELOPMENT OF TEST PROTOCOLS FOR THE ANALYSIS OF MAGNETO-RHEOLOGICAL PROPERTIES OF FIELD-RESPONSIVE BITUMINOUS BINDERS

    Ezio Santagata

    2014-01-01

    Full Text Available Magneto-rheological fluids are materials that exhibit a significant change in their rheological properties in the presence of a magnetic field. Because of such a field-dependent behavior, they can act as smart materials in applications in which changeable performances are desired. In road pavement engineering, the use of bitumen-based magneto-rheological fluids may open innovative scenarios related to the construction of smart pavement sections and to the investigation of damage mechanisms in binders and mixtures. The research work presented in this study explored magneto-rheological properties of several field-responsive bituminous binders obtained from two different base bitumens combined with multi-wall carbon nanotubes and powder iron. The experimental program included oscillatory shear loading tests at different temperatures, performed in the strain controlled mode by means of a dynamic shear rheometer equipped with a magneto-rheological device. The investigation was carried out with the specific goal of identifying critical issues which should be taken into account in materials preparation, testing procedures and data analysis. Undesired overheating of specimens during testing was identified and taken into account for a correct interpretation of experimental data. Thus, while the field-sensitivity of carbon nanotubes was found to be negligible as a result of the magnetic shielding action of bitumen, it was shown that powder iron can significantly affect the magneto-rheological properties of bituminous binders when employed in sufficiently high amounts. Moreover, obtained results indicated that selection of base bitumen is a key factor in designing bituminous-based smart materials. Practical implications which derive from the study are mainly relative to the fine-tuning of laboratory characterization procedures which should necessarily overcome current limitations in temperature regulation and magnetic field generation. Experimental data

  4. Effect of structural alteration on the macromolecular properties of brown and bituminous coals, quantitative relationships to the hydrogenation reactivity with tetralin

    Kuznetsov, P.N.; Kuznetsova, L.I. [Inst. of Chemistry and Chemico-Metallurgical Processes, Krasnoyarsk (Russian Federation); Bimer, J.; Salbut, P.D. [Inst. of Organic Chemistry, Warszawa (Poland); Gruber, R. [Univ. de Metz (France)

    1996-12-31

    The mobility of macromolecular network has been found to be the fundamental property of both brown and bituminous coals governing the reactivity for hydrogenation with tetralin. In Kansk-Achinsk brown coal, this was primarily affected by carboxylate cross-linking via polyvalent cations like Ca.

  5. Functional group and individual maceral chemistry of high volatile bituminous coals from southern Indiana: Controls on coking

    Walker, R.; Mastalerz, Maria

    2004-01-01

    The individual maceral chemistries of two Pennsylvanian, high volatile bituminous coals, the Danville Coal Member (Dugger Formation, R o=0.55%) and the Lower Block Coal Member (Brazil Formation, R o=0.56%) of Indiana, were investigated using electron microprobe and Fourier Transform Infrared Spectrometry (FTIR) techniques, with the purpose of understanding differences in their coking behavior. Microprobe results reveal that carbon contents are highest in inertinite and sporinite, followed by desmocollinite and telocollinite. Oxygen and organic nitrogen are most abundant in telocollinite and desmocollinite; sporinite and inertinite contain lesser amounts of these two elements. Organic sulfur contents are highest in sporinite, lowest in inertinite, and intermediate in desmocollinite and telocollinite. Vitrinites within the Danville and Lower Block coals are very similar in elemental composition, while Lower Block inertinites and sporinites have higher carbon, lower oxygen, and sulfur contents which, when combined with the inertinite-and sporinite-rich composition of the Lower Block seam, strongly influences its whole coal chemistry. Fourier transform infrared spectrometry revealed greater aromatic hydrogen in the Lower Block coal, along with higher CH2/CH3 ratios, which suggest that liptinites contribute considerable amounts of long-chain, unbranched aliphatics to the overall kerogen composition of the Lower Block coal. Long-chain, unbranched aliphatics crack at higher temperatures, producing tar and oily byproducts during coking; these may help increase Lower Block plasticity. Electron microprobe and FTIR results indicate that individual maceral chemistries, combined with the maceral composition of the seam, are the primary control of better coking properties of the Lower Block coal. ?? 2003 Elsevier B.V. All rights reserved.

  6. Effects of coal rank on the chemical composition and toxicological activity of coal liquefaction materials

    Wright, C.W.; Dauble, D.D.

    1986-05-01

    This report presents data from the chemical analysis and toxicological testing of coal liquefaction materials from the EDS and H-Coal processes operated using different ranks of coal. Samples of recycle solvent from the bottoms recycle mode of the EDS direct coal liquefaction process derived from bituminous, sub-bituminous, and lignite coals were analyzed. In addition, the H-Coal heavy fuel oils derived from bituminous and sub-bituminous coals were analyzed. Chemical methods of analysis included adsoprtion column chromatography, high-resolution gas chromatography, gas chromatography/mass spectrometry, and low-voltage probe-inlet mass spectrometry. The toxicological activity of selected samples was evaluated using the standard microbial mutagenicity assay, an initiation/promotion assay for mouse-skin tumorigenicity, and a static bioassy with Daphnia magna for aquatic toxicity of the water-soluble fractions. 22 refs., 16 figs., 14 tabs.

  7. Mechanical properties of hot bituminous mixes manufactured with recycled aggregate of Silestone® waste

    Rubio, M. C.

    2011-03-01

    Full Text Available This article presents the results of a research project which analyzes the viability of incorporating waste material from decorative quartz solid surfacing in the manufacture of hot bituminous mixes. For this purpose, various bituminous mixes were manufactured with waste aggregate in different percentage. A set of tests were carried out that permitted the characterization of the mechanical behavior of these mixes. The results of these tests were similar to the results obtained when conventional mixes made from virgin quarry aggregate were tested. The results for moisture sensitivity as well as for wheel track rutting on mixes showed the optimal performance of this waste material even under very demanding traffic conditions. Laboratory studies showed that the use of this waste material in the manufacture of bituminous mixes is technically viable and can provide high-quality recycled aggregates at a very low cost, which can be used in the pavement of road.

    Este artículo muestra los resultados de un proyecto de investigación que tiene por objeto analizar la viabilidad de incorporación de residuos procedentes de piedra decorativa en la fabricación de mezclas bituminosas en caliente. Para ello se fabricaron mezclas con áridos reciclados de residuos procedentes de piedra decorativa en distintos porcentajes, realizando un conjunto de ensayos que posibilitaron caracterizar el comportamiento mecánico de dichas mezclas. Los resultados obtenidos fueron similares a los de las mezclas convencionales fabricadas con áridos vírgenes procedentes de cantera. Los valores de resistencia conservada ante la acción del agua y deformación en pista, pusieron de manifiesto la aptitud del residuo incluso ante las condiciones de tráfico más exigentes. Los trabajos realizados en el laboratorio indican que la utilización del residuo en la fabricación de mezclas bituminosas es técnicamente viable, pudiendo obtenerse áridos reciclados de gran calidad y

  8. Bituminous reference document: synthesis of knowledge on the long time behavior of bituminous packages; Dossier de reference bitume: synthese des connaissances sur le comportement a long terme des colis bitumes

    Sercombe, J.; Adenot, F.; Vistoli, P.P.; Parraud, S.; Riglet-Martial, C.; Gwinner, B.; Felines, I.; Tiffreau, C.; Libert, M

    2004-07-01

    This document is a synthesis of the knowledge acquired at the CEA on the behavior of bituminous packages. In this framework, the CEA studied bituminous packages in generic conditions of a package lifetime. The main factors, the evolution mechanisms and influential parameters have been determined and quantitative s simulation have been developed. After a description of the main initial bituminous packages characterizations, the evolutions in saturated and un-saturated environment are exposed. (A.L.B.)

  9. The microstructure of petroleum vacuum residue films for bituminous concrete: a microscopy approach.

    Sourty, E D; Tamminga, A Y; Michels, M A J; Vellinga, W-P; Meijer, H E H

    2011-02-01

    Selected carbon-rich refinery residues ('binders') mixed with mineral particles can form composite materials ('bituminous concrete') with bulk mechanical properties comparable to those of cement concrete. The microstructural mechanism underlying the remarkable composite properties has been related to the appearance of a rigid percolating network consisting of asphaltenes and mineral particles [Wilbrink M. et al. (2005) Rigidity percolation in dispersions with a structured visco-elastic matrix. Phys. Rev. E71, 031402]. In this paper, we explore the microstructure of thin binder films of varying thickness with a number of microscopic characterization techniques, and attempt to relate the observed microstructure to the distinctive mechanical behaviour. Two binders, only one of which has been proven to be suitable for bituminous concrete were investigated, and their microstructure compared. Both binders show the formation of asphaltene aggregates. The binder suitable for bituminous concrete is distinguished by the fact that the asphaltenes show a stronger tendency towards such aggregation, due to a higher concentration and less stabilization in the maltene phase. They also show a clear affinity to other species (such as waxes) and may act as nucleation sites for crystals and aggregates of those species. PMID:21118207

  10. State of the art report on bituminized waste forms of radioactive wastes

    Kim, Tae Kook; Shon, Jong Sik; Kim, Kil Jeong; Lee, Kang Moo; Jung, In Ha

    1998-03-01

    In this report, research and development results on the bituminization of radioactive wastes are closely reviewed, especially those regarding waste treatment technologies, waste solidifying procedures and the characteristics of asphalt and solidified forms. A new concept of the bituminization method is suggested in this report which can improve the characteristics of solidified forms. Stable solid forms with high leach resistance, high thermal resistance and good compression strength were produced by the suggested bituminization method, in which spent polyethylene from agricultural farms was added. This report can help further research and development of improved bituminized forms of radioactive wastes that will maintain long term stabilities in disposal sites. (author). 59 refs., 19 tabs., 18 figs

  11. State of the art report on bituminized waste forms of radioactive wastes

    In this report, research and development results on the bituminization of radioactive wastes are closely reviewed, especially those regarding waste treatment technologies, waste solidifying procedures and the characteristics of asphalt and solidified forms. A new concept of the bituminization method is suggested in this report which can improve the characteristics of solidified forms. Stable solid forms with high leach resistance, high thermal resistance and good compression strength were produced by the suggested bituminization method, in which spent polyethylene from agricultural farms was added. This report can help further research and development of improved bituminized forms of radioactive wastes that will maintain long term stabilities in disposal sites. (author). 59 refs., 19 tabs., 18 figs

  12. Comparison of marginal adaptation of mineral trioxide aggregate, glass ionomer cement and intermediate restorative material as root-end filling materials, using scanning electron microscope: An in vitro study

    Sirisha Gundam

    2014-01-01

    Statistical Analysis: One way ANOVA Analysis of the data was carried out with gap size as the dependent variable, and material as independent variable. Results: The lowest mean value of gap size was recorded in MTA group (0.722 ± 0.438 μm and the largest mean gap in GIC group (1.778 ± 0.697 μm. Conclusion: MTA showed least gap size when compared to IRM and GIC suggesting a better marginal adaptation.

  13. Utilization of Waste Clay from Boron Production in Bituminous Geosynthetic Barrier (GBR-B) Production as Landfill Liner

    Müfide Banar; Yücel Güney; Aysun Özkan; Zerrin Günkaya; Eren Bayrakcı; Derya Ulutaş

    2016-01-01

    Bituminous geomembranes, one type of geosynthetics, include a hot bituminous mixture with mineral filler and reinforcement. In this study, boron production waste clay (CW) was used as filler to produce a geosynthetic barrier with bentonite, waste tire, and bitumen. Bentonite and waste tires were used as auxiliary fillers and bitumen as the binder. CW/bitumen, CW/bentonite/bitumen, and CW/waste tire/bitumen mixtures were prepared by using a laboratory mixer at 100°C. Hot mixtures were extruded...

  14. Influence of properties of bituminous binders on the strength of formed coke

    Sharma, Ashok K.; Das, Bani P.; Tripathi, Prem S.M. [Central Fuel Research Institute, P.O. FRI-828108, Dhanbad (India)

    2002-03-20

    The role of different chemical characteristics (coking value, quinoline insolubles, elemental composition, {beta}-resin, toluene solubles) of various coal tar- and petroleum-based bituminous binders, such as heavy fraction of HTC tar, processed LTC tar, pitch and asphalt as also the mixed binder in controlling the strength of formed coke made from char prepared from non-coking Chirimiri coal and coke breeze (prepared after carbonising Jharia coal), respectively, has been studied in some detail. The objective was to investigate as to whether and how the properties of these bituminous binders govern the strength of formed coke. It is found that these properties of the binders do play significantly important role in controlling the strength of formed coke both during curing and carbonisation. These parameters of the binders are found to be closely related with their atomic C/H ratios. Notwithstanding the varying composition of the binders of different origin, be they coal tar or petroleum based, the atomic C/H ratio seems to be the most important characteristics of the bituminous binders, upon which the strength of formed coke depends predominantly. This also holds true when mixed binders were used. The results show that at a C/H ratio of about 1, the strength of the briquettes either on curing or on carbonising remains almost similar and that strong cured briquettes can be produced by using a bituminous binder with a C/H ratio less than 1, whilst for obtaining strong carbonised briquettes, binders with C/H ratio greater than 1 are preferable.

  15. Synthesis document on the long time behavior of packages: operational document ''bituminous'' 2204

    This document is realized in the framework of the law of 1991 on the radioactive wastes management. The 2004 synthesis document on long time behavior of bituminous sludges packages is constituted by two documents, the reference document and the operational document. This paper presents the operational model describing the water alteration of the packages and the associated radioelements release, as the gas term source and the swelling associated to the self-irradiation and the bituminous radiolysis. (A.L.B.)

  16. Simulation and Rapid Prototyping of Adaptive Control Systems using the Adaptive Blockset for Simulink

    Ravn, Ole

    1998-01-01

    The paper describes the design considerations and implementational aspects of the Adaptive Blockset for Simulink which has been developed in a prototype implementation. The concept behind the Adaptive Blockset for Simulink is to bridge the gap between simulation and prototype controller...... implementation. This is done using the code generation capabilities of Real Time Workshop in combination with C s-function blocks for adaptive control in Simulink. In the paper the design of each group of blocks normally found in adaptive controllers is outlined. The block types are, identification, controller...... design, controller and state variable filter.The use of the Adaptive Blockset is demonstrated using a simple laboratory setup. Both the use of the blockset for simulation and for rapid prototyping of a real-time controller are shown....

  17. Bituminous solidification, disposal, transport and burial of spent ion-exchange resins. Part of a coordinated programme on treatment of spent ion exchange resins

    The project dealing with the incorporation of spent ion-exchange resins into bitumen was performed within the Agency coordinated research programme on treatment of spent ion-exchange resins. Physical and chemical properties of commercial ion-exchange resins, bitumens and bituminized resins were studied. It was shown that bitumen with low oil content and with a softening point of 60-70 deg. C are applicable for the incorporation of resins. The final waste form is allowed to contain maximum 50% resin. The comprehensive study of the biological resistance of B-30 bitumen was performed. That showed that any bacteriological attack can be regarded as generally insignificant. A continuously operating technology was realized on a semi-plant scale. The best operating conditions of this technology were determined. On the basis of the experience gained from the experiments a design of the bituminization plant of 50m3 dry resin/year treatment capacity was proposed

  18. Bituminization plant Jaslovske Bohunice

    In this leaflet the principle of the bituminization plant for radioactive concentrate (the intermediate liquid radioactive waste generated during the NPP A1, V-1, V-2 operations) solidification used in the Bohunice Radwaste Treatment Centre (BSC RAO) is presented

  19. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor

    Yan Cao; Hongcang Zhou; Junjie Fan; Houyin Zhao; Tuo Zhou; Pauline Hack; Chia-Chun Chan; Jian-Chang Liou; Wei-ping Pan [Western Kentucky University (WKU), Bowling Green, KY (USA). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150{sup o}C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650{sup o}C in the upper part of the fluidized bed combustor seemed to be responsible for the reduction of gaseous chlorine and, consequently, limited mercury emissions reduction during cofiring. 36 refs., 3 figs. 1 tab.

  20. Progressive oxidation of pyrite in five bituminous coal samples: An As XANES and 57Fe Moessbauer spectroscopic study

    Naturally occurring pyrite commonly contains minor substituted metals and metalloids (As, Se, Hg, Cu, Ni, etc.) that can be released to the environment as a result of its weathering. Arsenic, often the most abundant minor constituent in pyrite, is a sensitive monitor of progressive pyrite oxidation in coal. To test the effect of pyrite composition and environmental parameters on the rate and extent of pyrite oxidation in coal, splits of five bituminous coal samples having differing amounts of pyrite and extents of As substitution in the pyrite, were exposed to a range of simulated weathering conditions over a period of 17 months. Samples investigated include a Springfield coal from Indiana (whole coal pyritic S = 2.13 wt.%; As in pyrite = detection limit (d.l.) to 0.06 wt.%), two Pittsburgh coal samples from West Virginia (pyritic S = 1.32-1.58 wt.%; As in pyrite = d.l. to 0.34 wt.%), and two samples from the Warrior Basin, Alabama (pyritic S = 0.26-0.27 wt.%; As in pyrite = d.l. to 2.72 wt.%). Samples were collected from active mine faces, and expected differences in the concentration of As in pyrite were confirmed by electron microprobe analysis. Experimental weathering conditions in test chambers were maintained as follows: (1) dry Ar atmosphere; (2) dry O2 atmosphere; (3) room atmosphere (relative humidity ∼20-60%); and (4) room atmosphere with samples wetted periodically with double-distilled water. Sample splits were removed after one month, nine months, and 17 months to monitor the extent of As and Fe oxidation using As X-ray absorption near-edge structure (XANES) spectroscopy and 57Fe Moessbauer spectroscopy, respectively. Arsenic XANES spectroscopy shows progressive oxidation of pyritic As to arsenate, with wetted samples showing the most rapid oxidation. 57Fe Moessbauer spectroscopy also shows a much greater proportion of Fe3+ forms (jarosite, Fe3+ sulfate, FeOOH) for samples stored under wet conditions, but much less difference among samples stored

  1. Transformism in Alberta: The Environmental Political Economy of the Bituminous Sands

    Katz-Rosene, Ryan

    This thesis attempts to help establish environmental political economy as a viable academic field while providing an example of work in the discipline. It offers an analysis of societal processes resulting in the co-optation and/or neutralization of critical environmentalist ideas. Using Alberta's bituminous sands as a case study, and a Gramsci-influenced eco-Marxist theory as a foundation, the thesis argues that the term 'environmental transformism' (inspired by the Gramscian term trasformismo) is helpful in describing and framing such processes. Accordingly, the ensuing chapters provide an analysis of why environmental transformism is happening in Alberta, and demonstrate how this mechanism works at protecting the status quo from threatening ideologies, thereby consolidating neoliberal capitalism. A concluding argument discusses the inherent dangers posed to society by the transformism of certain environmental subjectivities. The thesis begins by introducing the contentious social and environmental issues surrounding the development of the bituminous sands.

  2. Co-combustion of bituminous coal and biomass fuel blends: Thermochemical characterization, potential utilization and environmental advantage.

    Zhou, Chuncai; Liu, Guijian; Wang, Xudong; Qi, Cuicui

    2016-10-01

    The thermochemical characteristics and gaseous trace pollutant behaviors during co-combustion medium-to-low ash bituminous coal with typical biomass residues (corn stalk and sawdust) were investigated. Lowering of ignition index, burnout temperature and activation energy in the major combustion stage are observed in the coal/biomass blends. The blending proportion of 20% and 30% are regarded as the optimum blends for corn stalk and sawdust, respectively, in according the limitations of heating value, activation energy, flame stability and base/acid ratio. The reductions of gaseous As, Cd, Cu, Pb, Zn and polycyclic aromatic hydrocarbon (PAHs) were 4.5%, 7.8%, 6.3%, 9.8%, 9.4% and 17.4%, respectively, when co-combustion coal with 20% corn stalk. The elevated capture of trace elements were found in coal/corn stalk blend, while the coal/sawdust blend has the better PAHs control potential. The reduction mechanisms of gaseous trace pollutants were attributed to the fuel property, ash composition and relative residence time during combustion. PMID:27393832

  3. Use of Adaptive Study Material in Education in E-Learning Environment

    Kostolányová, Katerina; Šarmanová, Jana

    2014-01-01

    Personalised education is a topical matter today and the impact of ICT on education has been covered extensively. The adaptation of education to various types of student is an issue of a vast number of papers presented at diverse conferences. The topic incorporates the fields of information technologies and eLearning, but in no small part also the…

  4. Adsorption of SO2 on bituminous coal char and activated carbon fiber

    DeBarr, J.A.; Lizzio, A.A.; Daley, M.A.

    1997-01-01

    The SO2 adsorption behaviors of activated carbons produced from Illinois coal and of commercially prepared activated carbon fibers (ACFs) were compared. There was no relation between surface area of coal-based carbons and SO2 adsorption, whereas adsorption of SO2 on the series of ACFs was inversely proportional to N2 BET surface area. Higher surface area ACFs had wider pores and adsorbed less SO2; thus, pore size distribution is thought to play a significant role in SO2 adsorption for these materials. Oxidation with HNO3 and/or H2SO4, followed by heat treatment at 700-925 ??C to remove carbon-oxygen complexes, resulted in increased SO2 adsorption for both coal chars and ACFs. This behavior was explained by an increase in the available number of free sites, previously occupied by oxygen and now available for SO2 adsorption. The use of nitrogen-containing functional groups on ACFs of proper pore size shows promise for further increasing SO2 adsorption capacities. Knowledge of the relationship among the number of free sites, pore size, and surface chemistry on corresponding SO2 adsorption should lead to the development of more efficient adsorbents prepared from either coal or ACFs.

  5. Thermotropic and Thermochromic Polymer Based Materials for Adaptive Solar Control

    Olaf Mühling; Ralf Ruhmann; Arno Seeboth

    2010-01-01

    The aim of this review is to present the actual status of development in adaptive solar control by use of thermotropic and organic thermochromic materials. Such materials are suitable for application in smart windows. In detail polymer blends, hydrogels, resins, and thermoplastic films with a reversible temperature-dependent switching behavior are described. A comparative evaluation of the concepts for these energy efficient materials is given as well. Furthermore, the change of strategy from...

  6. Translation and adaptation of smoking relapse-prevention materials for pregnant and postpartum Hispanic women.

    Simmons, Vani Nath; Cruz, Ligia M; Brandon, Thomas H; Quinn, Gwendolyn P

    2011-01-01

    Quitting smoking is one of the most important behavior changes a pregnant woman can make, with health benefits extending beyond pregnancy for the woman and her child. Increasing numbers of pregnant women are quitting smoking; however, the majority resume smoking later in their pregnancy or shortly after giving birth. Previous research has demonstrated the efficacy of self-help smoking relapse-prevention booklets; however, there is a dearth of materials available in Spanish for Hispanic smokers. The goal of the present study was to translate and adapt existing, theoretically based, smoking relapse-prevention materials for pregnant and postpartum Hispanic women. This article describes the transcreation approach used to ensure the Forever Free for Baby and Me booklets were linguistically and culturally relevant for the heterogeneous populations of Hispanic women. The authors conducted multistage formative research to adapt the booklets and modify vignettes and graphics. Compared with previous research conducted with pregnant non-Hispanic women, results revealed the following: (a) a lack of association or concern about smoking and weight gain, (b) the importance of family approval of behavior, and (c) stress related to difficulties surrounding the immigration experience. The authors' qualitative findings confirm and extend past research that has suggested ways to enhance the cultural relevance and acceptability of a health intervention. PMID:21120739

  7. Thermo-mechanical behavior of bituminous mixtures at low temperatures. Links between the binder characteristics and the mix properties; Comportement thermomecanique des enrobes bitumeux a basses temperatures: relations entre les proprietes du liant et de l'enrobe

    Olard, F.

    2003-10-01

    This thesis has been realized within the framework of a partnership between the Ecole Nationale des TPE, APPIA and EUROVIA. The company Total has also been associated to this project. The study deals with the thermo-mechanical behavior of bituminous materials at low temperatures. The aim is to establish the links between the characteristics of the binder and the properties of bituminous mixes at low temperatures, and to better understand the existing low-temperature parameters and criteria for binders (or to propose new ones), related to the in-situ behavior of bituminous mixtures. A large experimental campaign has been carried out so as to fulfill this goal. After a bibliographical study on the rheology and the thermo-mechanical properties of (pure or modified) binders, putties and mixes, the experimental campaign carried out both in the small strain domain and in the large strain domain, is presented. The low temperature behavior of binders has been evaluated with three common fundamental tests: i)the complex modulus determination, ii)the Bending Beam Rheometer and iii)the tensile strength at a constant strain rate and constant temperatures. A new three point bending test on pre-notched bitumen beams has also been developed at the ENTPE. The low-temperature fracture properties of bitumens were studied at constant temperatures and cross-head speeds considering the Linear Elastic Fracture Mechanics (LEFM) assumptions. The thermo-mechanical behavior of bituminous mixtures has been studied by performing i)complex modulus tests, ii)measurements of the coefficient of thermal dilatation and contraction, iii)tensile tests at constant temperatures and strain rates, and iv)Thermal Stress Restrained Specimen Tests. Apart from the determination of some pertinent links between binder and mix properties and discriminating characteristics with regard to the thermal cracking of bituminous mixes at low temperatures, the analysis has also consisted in modeling the behavior of

  8. JV Task-123 Determination of Trace Element Concentrations at an Eastern Bituminous Coal Plant Employing an SCR and Wet FGD

    Dennis Laudal

    2008-05-01

    The Energy & Environmental Research Center (EERC), in partnership with Babcock & Wilcox (B&W) and with funding from U.S. Department of Energy (DOE), conducting tests to prove that a high level of mercury control (>90%) can be achieved at a power plant burning a high-sulfur eastern bituminous coal. With funding from the Electric Power Research Institute (EPRI), DOE, and Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates Program, the EERC completed an additional sampling project to provide data as to the behavior of a number of trace elements across the various pollution control devices, with a special emphasis on the wet flue gas desulfurization (FGD) system. Results showed that the concentrations of almost all the elements of interest leaving the stack were very low, and a high percentage of the trace elements were captured in the electrostatic precipitator (ESP) (for most, >80%). Although, with a few exceptions, the overall mass balances were generally quite good, the mass balances across the wet FGD were more variable. This is most likely a result of some of the concentrations being very low and also the uncertainties in determining flows within a wet FGD.

  9. 纤维沥青混合料的拌和成型工艺研究%Research on Mixing and Shaping Technology of Fiber Bituminous Mixture

    程英伟; 何晓鸣

    2012-01-01

    利用正交试验对剑麻纤维沥青混凝土混合料的拌和成型工艺进行研究.在固定配合比的前题下,以拌和方案、沥青加热温度、集料加热温度和成型温度为试验因素,模拟路面施工的各种拌和成型情况设计了L9正交表分别进行马歇尔试验.运用极差分析法对试验结果进行分析,确定了纤维沥青混合料拌和成型的优选方案为“同步法拌和+沥青加热温度为175℃+集料加热温度为206℃+成型温度为165℃”.最后分析了几种试验因素对试验指标的影响机理.%In this paper, mixing and shaping technology of bituminous concrete mixture with sisal fiber is researched by orthogonal experiment. Under a fixed mix proportion, mixing solutions, asphalt heating temperature, aggregate heating temperature and shaping temperature are selected as test factors. The variety of mixing and shaping in pavement construction is simulated by designing a L9 orthogonal table for Marshall tests. Range Analysis Method is used to analyze test results, and then the optimal scheme of mixing and shaping for fiber bituminous concrete mixture is determined. The optimal scheme is "synchronization method of mixing+asphalt heating temperature of 175℃+aggregate heating temperature of 206℃ + shaping temperature of 165℃”. Last, the influence mechanism of test factors on test indicators is analyzed.

  10. Cultural Adaptation and Translation of Outreach Materials on Autism Spectrum Disorder

    Grinker, Roy R.; Kang-Yi, Christina D.; Ahmann, Chloe; Beidas, Rinad S.; Lagman, Adrienne; Mandell, David S.

    2015-01-01

    In order to connect with families and influence treatment trajectories, outreach materials should address cultural perceptions of the condition, its causes, and post-diagnostic care. This paper describes the cultural adaptation and translation of the Autism Speaks First 100 Days Kit into Korean for the purpose of improving autism spectrum disorder…

  11. Study of thermal reactivity during bituminization of radioactive waste

    This work deals with the study of chemical reactions and phases transitions which can occur between magnesium nitrate, sodium nitrate, cobalt sulphur product, and nickel potassium ferrocyanide, when they are heated together during bituminization process of nuclear waste. The applied methodology associates a few techniques: temperature, enthalpy, and kinetics of reaction are determined by calorimetry, reaction products are characterised by chemical analyses, mass spectrometry and XRD analysis. Three fields of temperature and energy are observed in function of composition (one compound or a mixture of compounds). The study of reactions between NaNO3 and cobalt sulphur product shows that the presence of water has got an effect on reaction temperature. The study of Mg(NO3)2, 6 H2O and CoS shows an overlapping of different signals, and that the reaction rate is very slow (a few hours). (author)

  12. Material and Social Construction: A Framework for the Adaptation of Buildings

    Jesse M. Keenan

    2014-12-01

    Full Text Available This article is a formulation of a framework for understanding the nature of change, particularly climate change, as it applies to the scale of a building. Through an exploration of various scientific and social scientific literutre, the article positions the concept of adaptation as the appropriate mode for understanding and managing change. Through the classification of a duality of material and social construction in the ontological composition of a building, various lines of thought relating to adaptive capacity and adaptive cycling within systems theory are appropriated within an integrated framework for adaptation. Specifically, it is theorized that as buildings as objects are developing greater capacities for intergrated operations and management through artificial intelligence, they will possess an ex ante capacity to autonomously adapt in dynamic relation to and with the ex post adaptation of owners and operators. It is argued that this top-down and bottom-up confluence of multi-scalar dynamic change is consistent with the prevailing theory of Panarchy applied in social-ecological systems theory. The article concludes with normative perspectives on the limitations of systems theory in architecture, future directions for research and an alternative positioning of professional practices.

  13. Development prospects for Bazhenov formation bituminous claystones in the southeast of the West Siberian Plate (Tomsk Region)

    The article considers the use of time-tested bituminous shale development technologies in the southeast of the West Siberian Plate (Tomsk Region). A research target is the bituminous claystones of the Bazhenov formation. The Bazhenov formation was divided into stratigraphic units, and the sequence of forming these units within the territory under study was restored on the basis of the peculiarities of the Bazhenov formation section structure with gamma-ray logging data. The joint analysis of logs (gamma-ray logging, resistivity logging, SP logging, neutron gamma-ray logging, induction logging) and core data revealed the wide development of carbonatization processes in the lower stratigraphic units of the Bazhenov formation, whereas the upper, most bituminous units do not have the signs of carbonatization. It is a favorable factor for using the existing technologies of producing hydrocarbons from analogous sedimentary deposits. Considering the degree of lithological disconnection of an oilbearing object from adjacent reservoir formations allows making a conclusion that the application of the existing technologies for developing bituminous claystones can be implemented only in the insignificant territory of the area under study where the Bazhenov formation overlies Georgiev formation claystones being over 8 meters thick. To develop the oil and gas potential of the Bazhenov formation in other territories, there will be a need for new technologies that allow forming a fracture-cavernous matrix in a carbonate rock

  14. Effects of salt content on leaching properties of synthetic bituminized wastes

    The leaching properties of soluble components (Na+, NO3−, and NO2−) in synthetic bituminized wastes with various characteristics, such as salt content, salt composition, and bitumen matrix, were quantitatively evaluated by means of an aqueous leaching test. Micropores were formed in the bituminized waste by the leaching of soluble salts. The penetrability of bitumen and the salt content affected the size and the shape of the micropores observed by scanning electron microscopy. The linear relationship between leaching fraction of the soluble components and square root of leaching time was observed, and the diffusion coefficient of the soluble component was determined by Fick's law. The diffusion coefficients of ionic species of interest were similar to each other. Moreover, the diffusion coefficient agreed among bituminized wastes with the same salt content, even if salt composition and bitumen matrix were different. The diffusion coefficient of the component was proportional to the salt content in the synthetic bituminized wastes. It was found that the salt content in the bituminized waste was one of the key factors to determine the diffusion coefficient. (author)

  15. Influence of Extrusion Conditions on the Rheological Behavior of Nuclear Bituminized Waste Products

    In France, bitumen has been used since four decades as a container material for low/intermediate activity and long lifetime radionuclides. Industrial Bituminized Waste Products (BWP) are produced by continuous extrusion of 60 wt.% bitumen and 40 wt.% salts, in which a very small fraction is radioactive. These incorporated salts are, in majority, of two types: soluble or insoluble. During storage, the organic matrix subjected to irradiation produces gases, which can give rise to BWP swelling in the container and then to a possible overflow. The extent of gas production is directly linked to the degree of dispersion of the salts into the bitumen matrix. To quantify this dispersion, the effect of extrusion operating conditions, such as feed rate and screw speed, have been studied using a laboratory scale co-rotating twin screw extruder. BWP rheological characterization shows the development of a pseudo-solid plateau at low frequency and a change in the linear viscoelastic domain when screw speed and feed rate are varied, indicating a modification of the dispersion state. Samples characterization with environmental scanning electron microscopy (ESEM) confirms in the case of insoluble and soluble salts a change in the number of agglomerates, accompanied by an improvement of the dispersion at high screw speed but less remarkable with the feed rate. A Carreau-Yasuda law with a yield stress is proposed to describe the theological behaviour of these materials. The effects of volume fraction and maximum volume fraction on viscosity are described using a Krieger-Dougherty equation. (authors)

  16. Exploring preservice elementary teachers' critique and adaptation of science curriculum materials in respect to socioscientific issues

    Forbes, Cory T.; Davis, Elizabeth A.

    2008-09-01

    The work presented here represents a preliminary effort undertaken to address the role of teachers in supporting students’ learning and decision-making about socioscientific issues (SSI) by characterizing preservice elementary teachers’ critique and adaptation of SSI-based science curriculum materials and identifying factors that serve to mediate this process. Four undergraduate preservice elementary teachers were studied over the course of one semester. Results indicate that the teachers navigated multiple learning goals, as well as their own subject-matter knowledge, informal reasoning about SSI, and role identity, in their critique and adaptation of SSI-oriented science instructional materials. Implications for science teacher education and the design of curriculum materials in respect to SSI are discussed.

  17. Formation of hydrogen cyanide and ammonia during the gasification of sewage sludge and bituminous coal

    N. Paterson; Y. Zhuo; D. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2005-06-01

    HCN and NH{sub 3} released during the gasification of sewage sludge have been measured during a program of tests with a laboratory-scale spouted-bed gasifier. The data have been compared with results from gasification tests with coal. The effect of altering the bed temperature has been investigated, and the results have been related to reactions involving gaseous N species known to occur in the gasifier. The effect of steam addition on the HCN release has been examined. It has been found that the HCN concentrations in the exit gas increase with the operating temperature, which is thought to indicate increased formation as a primary product of the decomposition of the fuel-N compounds. Increasing the height of the char bed caused a significant reduction in the HCN concentration at the exit, as this promoted the decomposition of HCN to NH{sub 3}. Steam addition caused a rise in the HCN concentration during tests with sewage sludge and a similar effect had previously been reported on the NH{sub 3} concentration during tests with coal. The NH{sub 3} concentration decreased with increasing temperature, and this is thought to reflect the increased rate of the equilibration of NH{sub 3} in the gas phase to form N{sub 2} and H{sub 2}. 18 refs., 4 figs., 5 tabs.

  18. Development and evaluation of an automated reflectance microscope system for the petrographic characterization of bituminous coals

    Hoover, D. S.; Davis, A.

    1980-10-01

    The development of automated coal petrographic techniques will lessen the demands on skilled personnel to do routine work. This project is concerned with the development and successful testing of an instrument which will meet these needs. The fundamental differences in reflectance of the three primary maceral groups should enable their differentiation in an automated-reflectance frequency histogram (reflectogram). Consequently, reflected light photometry was chosen as the method for automating coal petrographic analysis. Three generations of an automated system (called Rapid Scan Versions I, II and III) were developed and evaluated for petrographic analysis. Their basic design was that of a reflected-light microscope photometer with an automatic stage, interfaced with a minicomputer. The hardware elements used in the Rapid Scan Version I limited the system's flexibility and presented problems with signal digitization and measurement precision. Rapid Scan Version II was designed to incorporate a new microscope photometer and computer system. A digital stepping stage was incorporated into the Rapid Scan Version III system. The precision of reflectance determination of this system was found to be +- 0.02 percent reflectance. The limiting factor in quantitative interpretation of Rapid Scan reflectograms is the resolution of reflectance populations of the individual maceral groups. Statistical testing indicated that reflectograms were highly reproducible, and a new computer program, PETAN, was written to interpret the curves for vitrinite reflectance parameters ad petrographic.

  19. Rheological behaviour of polymer-modified bituminous mastics : a comparative analysis between physical and chemical modification

    Shivokhin, Maxim; García Morales, Moisés; Partal López, Pedro; Cuadri Vega, Antonio Abad; Gallegos Montes, Críspulo

    2012-01-01

    Mastic, a bitumen/filler blend which naturally forms when bitumen is mixed with aggregates is the actual product used to bind coarse mineral particles in the asphalt mixtures. As a result, the characterisation of mastics is essential to improve the understanding of the response and performance of asphalt concrete pavements. On the other hand, the lack of experimental data concerning the behaviour of mastics and, above all, polymer-modified mastics has been lately claimed. In that sense, this ...

  20. Mapping and prediction of Coal Workers' Pneumoconiosis with bioavailable iron content in the bituminous coals

    Huang, X.; Li, W.; Attfield, M.D.; Nadas, A.; Frenkel, K.; Finkelman, R.B.

    2005-01-01

    Based on the first National Study of Coal Workers' Pneumoconiosis (CWP) and the U.S. Geological Survey database of coal quality, we show that the prevalence of CWP in seven coal mine regions correlates with levels of bioavailable iron (BAI) in the coals from that particular region (correlation coefficient r = 0.94, p < 0.0015). CWP prevalence is also correlated with contents of pyritic sulfur (r = 0.91, p < 0.0048) or total iron (r = 0.85, p < 0.016) but not with coal rank (r = 0.59, p < 0.16) or silica (r = 0.28, p < 0.54). BAI was calculated using our model, taking into account chemical interactions of pyrite, sulfuric acid, calcite, and total iron. That is, iron present in coals can become bioavailable by pyrite oxidation, which produces ferrous sulfate and sulfuric acid. Calcite is the major component in coals that neutralizes the available acid and inhibits iron's bioavailabiity. Therefore, levels of BAI in the coals are determined by the available amounts of acid after neutralization of calcite and the amount of total iron in the coals. Using the linear fit of CWP prevalence and the calculated BAI in the seven coal mine regions, we have derived and mapped the pneumoconiotic potencies of 7,000 coal samples. Our studies indicate that levels of BAI in the coals may be used to predict coal's toxicity, even before large-scalen mining.

  1. Surface Properties of Photo-Oxidized Bituminous Coals: Final report

    NONE

    1998-09-01

    Natural weathering has a detrimental effect on the hydrophobic nature of coal, which in turn can influence clean-coal recovery during flotation. Few techniques are available that can establish the quality of coal surfaces and that have a short analysis time to provide input for process control. Luminescence emissions which can be quantified with an optical microscope and photometer system, are measurably influenced by degree of weathering as well as by mild storage deterioration. In addition, it has been shown that when vitrinite is irradiated with a relatively high intensity flux of violet- or ultraviolet- light in the presence of air, photo-oxidation of the surface occurs. The combination of measuring the change in luminescence emission intensity with degree of surface oxidation provided the impetus for the current investigation. The principal aim of this research was to determine whether clear correlations could be established among surface oxygen functionality, hydrophobicity induced by photo-oxidation, and measurements of luminescence intensity and alteration. If successful, the project would result in quantitative luminescence techniques based on optical microscopy that would provide a measure of the changes in surface properties as a function of oxidation and relate them to coal cleanability. Two analytical techniques were designed to achieve these goals. Polished surfaces of vitrain bands or a narrow size fraction of powdered vitrain concentrates were photo-oxidized using violet or ultraviolet light fluxes and then changes in surface properties and chemistry were measured using a variety of near-surface analytical techniques. Results from this investigation demonstrate that quantitative luminescence intensity measurements can be performed on fracture surfaces of bituminous rank coals (vitrains) and that the data obtained do reveal significant variations depending upon the level of surface oxidation. Photo-oxidation induced by violet or ultraviolet light

  2. Global market trade policy analysis for petroleum oils and oils obtained from bituminous minerals, crude

    Bagheri, F.

    2012-01-01

    Full Text Available This article is based on surveying the custom tariffs imposed on the world export market of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. We obtained the data according to the most updated available data provided online by UNCTAD and World Bank. The results indicate that none of the 142 countries in the world market of this product have imposed non-tariff trade barriers on the import of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. The developed countries and the countries with transition economies are the main world import partners. European Union, United States, China, Japan, South Korea, Canada, Singapore, Taiwan, Thailand, South Africa, Australia, Turkey, Brazil, Sweden and Belarus are the examples and have imposed low custom tariffs on Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude.

  3. Assessing radionuclide release and migration during deep geological disposal of bituminized waste: the COLONBO model

    Full text of publication follows: Bitumen is being used for many years in France as an embedding matrix for the conditioning of low and medium level activity waste resulting from nuclear effluent treatment. Long term management options for this kind of waste include at present deep geological disposal. As a consequence, the COLONBO model has been developed by CEA to predict the long term release of chemical species out of bitumen waste and the subsequent radionuclide migration in the deep geological near field. The COLONBO model is divided into a 'waste package' module, coupled with a 'near field' module. In the first module, the waste package is represented as a bitumen matrix containing an homogeneous dispersion of the salts resulting from the effluent insolubilization treatment. Radionuclides initially present in the waste are thus associated with a mixture of soluble (NaNO3 and Na2SO4) and sparingly soluble (mainly BaSO4) salts. Under leaching, solubilization of water in the bitumen occur at the wasteform surface, followed by water diffusion through the bitumen matrix. Consequently, the soluble salts are progressively dissolved by water accumulation, resulting in a local swelling of the waste package. This swelling induces a local alteration of the diffusive properties of the bitumen matrix, allowing an outward diffusion of the dissolved salts and radionuclides. The resulting migration of chemical species through the storage facility near field is then described in a 'near field' module. In this module, transport is accounted by a simplified reactive diffusion model through porous media, in both saturated or unsaturated conditions. Up to three different zones of the near field can be included, which are described by their respective porosity, hydraulic conductivity, diffusion and retention (Kd) parameters. In the whole system (waste package + near field), water concentration profiles, the position of salt dissolution fronts and chemical species migration are

  4. DIRECT AND ADAPTIVE SLICING ON CAD MODEL OF IDEAL FUNCTIONAL MATERIAL COMPONENTS (IFMC)

    Xu Daoming; Jia Zhenyuan; Guo Dongming

    2005-01-01

    A brand new direct and adaptive slicing approach is proposed, which can apparently improve the part accuracy and reduce the building time. At least two stages are included in this operation: getting the crossing contour of the cutting plane with the solid part and determining the layer thickness. Apart from usual SPI algorithm, slicing of the solid model has its special requirements.Enabling the contour line segments of the cross-section as long as possible is one of them, which is for improving manufacturing efficiency and is reached by adaptively adjusting the step direction and the step size at every crossing point to obtain optimized secant height. The layer thickness determination can be divided into two phases: the geometry-based thickness estimation and the material-based thickness verifying. During the former phase, the geometry tolerance is divided into two parts: a variety of curves are approximated by a circular arc, which introduces the first part, and the deviation error between the contour line in LM process and the circular arc generates the second part. The latter phase is mainly verifying the layer thickness estimated in the former stage and determining a new one if necessary. In addition, an example using this slicing algorithm is also illustrated.

  5. The materiality of materials and artefacts used in science classrooms

    Cowie, Bronwen; Otrel-Cass, Kathrin; Moreland, Judy

    2015-01-01

    between materials as natural objects in this world and artefacts as manmade objects. We are aware that in a classroom material objects and artefacts shape, and are shaped by classroom practice through the way they selectively present scientific explanations. However, materials and artefacts have no...... as fossils, plant samples and artefacts like test tubes, worksheets and digital tools along with written inscriptions produced during interactions and that served as artefacts in subsequent interactions (Roehl, 2012). Data sources Data were generated via classroom observation using video, student...... but thought about means and ends of artefacts/ materials. They explored artefacts/materials and how they could be used and through this exemplified materiality in the objects. More deliberate and focused attention to what constitutes materiality can support collaboration and communication to support...

  6. Installation in the A-1 plant of an experimental bituminization line by VUCHZ

    Following the termination of the experimental operation of the bituminization line at the Research Institute for Chemical Installations in Brno, the line was dismantled and transferred to the nucler power plant in Jaslovske Bohunice. The installation of the line, the layout of the assemblies are described and the results of tests with non-radioactive simulated wastes and actual radioactive wastes briefly described. An amount of 3.2 m3 of actual radioactive wastes from the V-1 nuclear power plant was processed in the tests. The results confirmed the suitability of bituminization for processing liquid radioactive wastes from WWER nuclear power plants. (Z.M.)

  7. Survey on product properties of bituminized waste concentrates from reprocessing, nuclear installations and nuclear power plants

    This report contains a brief survey on the product properties after solidification with bitumen of waste concentrates from reprocessing plants, nuclear research installations and nuclear power plants. The leach behaviour of bitumen products in water and saturated salt solutions is described as well as the radiolytic and thermal stability of the products. The reports also contain some data on sedimentation of salts fixed in bitumen. (orig.)

  8. Assessing radioactive concentrates and waste vapor condensate in solidifying radioactive wastes by bituminization

    A brief overview is presented of chemical and radiochemical methods used in the world for the analysis of the concentrate of liquid radioactive wastes from nuclear power plants destined for bituminization. Most methods are also suitable for an analysis of the condensate of waste vapors produced in bituminization. The methods of analysis of the radioactive concentrate from the V-1 nuclear power plant in Jaslovske Bohunice and of the waste vapors condensate were developed and tested in practice. Gross gamma activity was measured using a well-type Na(Tl) scintillation detector, the content of radionuclides was determined using semiconductor Ge(Li) spectrometry. The concentration of boric acid in the concentrate was determined by titration with mannite; in the condensate, using spectrophotometry with curcumine. The content of nitrates in both the concentrate and the condensate was determined spectrophotometrically using salicylic acid, the content of nitrites was determined by spectrophotometry using sulfanilic acid and α-naphthylamine. Carbonates and chlorides were determined by titration, sodium and potassium by flame photometry. The content of organic acids was measured by gravimetry of extracted methyl esters, the content of surfactants by spectrophotometry. Infrared spectrophotometry was used in determining hydrocarbons in the waste vapor condensate. The measured value range and the measurement errors are shown for each method. (A.K.)

  9. XRD and FT–IR investigations of sub-bituminous Assam coals

    Binoy K Saikia; R K Boruah; P K Gogoi

    2007-08-01

    Two coal samples collected from Makum coal field, Assam, India were studied by XRD and FT–IR techniques. The X-ray diffractogram shows the existence of some crystalline carbons in Assam coals as proven by the appearance of peaks. The radial distribution functional (RDF) method was applied for the determination of structural aspects of the coals. The study indicates that the coals are lignite in type and there is no evidence of graphite-like structures. The maximum in the () plots of function of radial distribution of atoms (FRDA) relates to different distances between carbon atoms of aliphatic chains. The first significant maximum relates to the C–C bond (type C–CH=CH–C), the second maximum relates to the distance between carbon atoms of aliphatic chains that are located across one carbon atom. The curve intensity profiles obtained from FRDA show quite regular molecular packets for this coal. The coals were found to be lignite in nature. FT–IR study shows the presence of aliphatic carbon, C=O and C–O stretching associated with –OH and –NH stretching vibrations. Kaolinite and quartz were also found to be major minerals in Assam coals by FTIR spectroscopy. The difference in intensities of carbonyl groups of the coal samples is likely to relate with the rank.

  10. Safety assessment for the bituminization facility of the medium-level waste

    The safety assessment for the home-made bituminization facility of the medium-level waste during hot test is made. The average external dose equivalent per month is 0.136 x 10-2 Sv. The radioactive substance released into the environment is much lower than the permissible limit. The danger of burning and exploding of the bituminized product is avoided because the operation temperature is controlled strictly below 170 C degree. The report also briefly describes the structural characteristic of the facility, the main process and radiation protection and safety measures

  11. Urban adaptation planning: the use and limits of climate science

    Dodman, David; Carmin, Joann

    2011-11-15

    Cities face a mounting challenge from climate change. In developed and developing countries alike, rising temperatures, changing rainfall patterns, higher sea levels, and more frequent and severe extreme events such as droughts and floods threaten to overwhelm urban infrastructure, services and management systems. City officials recognise the need to adapt to climate change, and use scientific evidence to support their plans for doing so. But the precise details of these changes and the local impacts they will have cannot be predicted. Decision makers must learn to draw on scientific data while simultaneously managing the uncertainty inherent in future projections. Across the world, forward-looking city officials are proving themselves to be 'urban adaptation leaders' — mobilising political and public support for and devising flexible approaches to adaptation.

  12. Development of a method to determine the nuclide inventory in bituminized waste packages

    Until the 1980s, bitumen was used as a conditioning agent for weak to medium radioactive liquid waste. Its use can be ascribed mainly to the properties that indicated that the matrix was optimal. However, fires broke out repeatedly during the conditioning process, so that the method is meanwhile no longer permitted in Germany. There are an estimated 100 waste packages held by the public authorities in Germany that require a supplementary declaration. In contrast to the common matrices, such as for example resins or sludges, there is still no standardized technology for taking samples and subsequently determining the radio-nuclide for bitumen. Aspects, such as the thermoplastic behaviour, make determining the nuclide inventory more difficult in bituminized waste packages. The development of a standardized technology to take samples with a subsequent determination of the radio-nuclide analysis is the objective of a project funded by the BMBF. Known, new methods, specially developed for the project, are examined on inactive bitumen samples and then transferred to active samples. At first non-destructive methods are used. The resulting information forms an important basis to work out and apply destructive strategy for sampling and analysis. Since the project is on-going, this report can only address the development of the sampling process. By developing a sampling system, it will be possible to take samples from an arbitrary selected location of the package across the entire matrix level and thus gain representative analysis material. The process is currently being optimized. (orig.)

  13. Development and use of reference materials and quality control materials

    Current knowledge is summarized on correct use of commercially available certified reference materials (CRMs) and reference materials (RMs). Acknowledged are also the limitations and restrictions analysts have to face if they want to apply quality control. The concept of in-house RMs or quality control materials (QCMs) is advocated to supplement the use of CRMs for quality control purposes. On hand advice on how to select, prepare, characterize and use these QCMs is given from the experts' perspective. Several scenarios are described to make this concept widely applicable to: advanced laboratories with CRMs with validated analytical techniques available, laboratories with less experience and facilities, as well as cases were labile compounds and unstable matrices are involved. Each scenario considers different approaches to overcome the lack of appropriate CRMs and advise on the preparation of QCMs, which might fit the particular purpose

  14. Alkaline hydrolysis of mouse-adapted scrapie for inactivation and disposal of prion-positive material.

    Murphy, R G L; Scanga, J A; Powers, B E; Pilon, J L; Vercauteren, K C; Nash, P B; Smith, G C; Belk, K E

    2009-05-01

    Prion diseases such as bovine spongiform encephalopathy, chronic wasting disease, and scrapie pose serious risks to human and animal health due to a host of disease-specific factors, including the resistance of infectious prions (PrP(Sc)) to natural degradation and to most commercial inactivation procedures. In an attempt to address this concern, a mouse model was used to compare the efficacy of an alkaline hydrolysis process with a simulated continuous-flow rendering treatment for disposal of PrP(Sc)-infected biological material. Female C57/BL6 mice (N = 120) were randomly divided into 4 treatment groups (n = 30), and each mouse was injected intraperitoneally with their designated treatment inoculum. Treatment groups 1 and 2 served as the positive and negative controls, respectively. Group 3 was inoculated with rendered scrapie-positive mouse brain material to investigate the effectiveness of simulated continuous-flow rendering practices to reduce or eliminate PrP(Sc). Group 4 was inoculated with hydrolyzed scrapie-positive mouse brain material to determine the sterilizing effect of alkaline hydrolysis on PrP(Sc). Mice were monitored for overt signs of disease, and those showing clinical signs were killed to prevent undue suffering. Brains were obtained from all mice that died (or were killed) and analyzed with an ELISA for the presence of PrP(Sc). Results indicated that the simulated continuous-flow rendering treatment used for preparing the rendering treatment group inoculum failed to completely eliminate PrP(Sc). Rendering delayed, but did not stop, clinical mouse-adapted scrapie transmission. Compared with positive controls, the rendering treatment group experienced an approximate 45-d average delay in days to death (250 vs. 205 d for positive controls; P loss of 73.9% (P = 0.0094). Positive controls suffered 100% death loss. The results validated the efficacy of the alkaline hydrolysis treatment to inactivate all PrP(Sc) because no alkaline hydrolysis

  15. Impact of Adaptive Materials on Teachers and their Students with Visual Impairments in Secondary Science and Mathematics Classes

    Rule, Audrey C.; Stefanich, Greg P.; Boody, Robert M.; Peiffer, Belinda

    2011-04-01

    Science, technology, engineering, and mathematics (STEM) fields, important in today's world, are underrepresented by students with disabilities. Students with visual impairments, although cognitively similar to sighted peers, face challenges as STEM subjects are often taught using visuals. They need alternative forms of access such as enlarged or audio-converted text, tactile graphics, and involvement in hands-on science. This project focused on increasing teacher awareness of and providing funds for the purchase of supplemental adaptive resources, supplies, and equipment. We examined attitude and instructional changes across the year of the programme in 15 science and mathematics teachers educating students with visual impairments. Positive changes were noted from pretest to posttest in student and teacher perspectives, and in teacher attitudes towards students with disabilities in STEM classes. Teachers also provided insights into their challenges and successes through a reflective narrative. Several adolescent students resisted accommodations to avoid appearing conspicuous to peers. Teachers implemented three strategies to address this: providing the adaptations to all students in the class; convincing the student of the need for adaptation; and involving the class in understanding and accepting the student's impairment. A variety of teacher-created adaptations for various science and mathematics labs are reported. Another finding was many adaptations provided for the student with visual impairment benefitted the entire class. This study supports the claim that given knowledgeable, supportive teachers, and with appropriate accommodations such as tactile or auditory materials, students with visual impairments can be as successful and engaged as other students in science and mathematics.

  16. Thermotropic and Thermochromic Polymer Based Materials for Adaptive Solar Control

    Olaf Mühling

    2010-12-01

    Full Text Available The aim of this review is to present the actual status of development in adaptive solar control by use of thermotropic and organic thermochromic materials. Such materials are suitable for application in smart windows. In detail polymer blends, hydrogels, resins, and thermoplastic films with a reversible temperature-dependent switching behavior are described. A comparative evaluation of the concepts for these energy efficient materials is given as well. Furthermore, the change of strategy from ordinary shadow systems to intrinsic solar energy reflection materials based on phase transition components and a first remark about their realization is reported. Own current results concerning extruded films and high thermally stable casting resins with thermotropic properties make a significant contribution to this field.

  17. Adaptation of Instructional Materials Motivation Survey to Turkish: A Validity and Reliability Study

    Hülya Kutu

    2011-06-01

    Full Text Available The purpose of this study was to adapt “Instructional Materials Motivation Survey [IMMS]”, developed by J. M. Keller, to Turkish and investigate validity and reliability of the Turkish version of the survey. The original version of the survey was composed of 36 items gathered under four factors (attention, relevance, confidence, satisfaction. The survey was translated into Turkish. Views of 15 faculty members who were expert in Turkish and foreign language were sought in terms of correctness of meaning in Turkish and integrity of items into culture of Turkish education system. Turkish version of the survey was administered to total of 262 university students from Education Faculties of Ataturk and Erzincan Universities. The item-total correlations were calculated, and items which had negative or low correlation with the total survey score (r<.30 were excluded from the survey. The construct validity of the survey was examined by exploratory factor analysis. Varimax rotation technique was used due to the separation into irrelevant factors. Finally the survey was constructed from 24 item gathered under two factors. The reliability coefficient (Cronbach Alpha for the whole survey was calculated as 0.83, and 0.79 and 0.69 for the two sub-factors respectively.

  18. Bituminization system of low level liquid waste in Genkai Nuclear Power Plant

    The bituminization system for low level radioactive liquid wastes has such advantages as its volume reduction is 6 to 10 times higher than the cementing systems, and the exuding ratio of radioactive nuclides from bituminized body into sea water is smaller, because the solids containing radioactive nuclides are solidified into oily bitumen which is very water repellent. Therefore, Genkai No.2 reactor plant has adopted the batch bituminization system, the main equipment of which being a drum mixer. This equipment has the capacity of treating 35 m3 of drain from the machines (boron 21,000 ppm) yearly, mainly composed of boric acid, and 85 m3 of floor drain/laundry drain yearly (solids 1.1 wt.%). This paper describes the outline of the system, the improvement of the installation, operating method, operation control, and the results of cold and hot operations. At the beginning of the trial operation, the concentrated laundry drain from No.1 reactor during the regular inspection was bituminized, and the concentrated sodium borate solution from No.2 reactor was treated since July, 1980. These results show the good volume reduction, condensate-processing capability, mixer controllability and mixer decontamination efficiency. (Wakatsuki, Y.)

  19. Inlays made from a hybrid material: adaptation and bond strengths.

    Bottino, M A; Campos, F; Ramos, N C; Rippe, M P; Valandro, L F; Melo, R M

    2015-01-01

    The aim of this study was to evaluate the internal fit, marginal adaptation, and bond strengths of inlays made of computer-aided design/computer-aided manufacturing feldspathic ceramic and polymer-infiltrated ceramic. Twenty molars were randomly selected and prepared to receive inlays that were milled from both materials. Before cementation, internal fit was achieved using the replica technique by molding the internal surface with addition silicone and measuring the cement thicknesses of the pulpal and axial walls. Marginal adaptation was measured on the occlusal and proximal margins of the replica. The inlays were then cemented using resin cement (Panavia F2.0) and subjected to two million thermomechanical cycles in water (200 N load and 3.8-Hz frequency). The restored teeth were then cut into beams, using a lathe, for microtensile testing. The contact angles, marginal integrity, and surface patterns after etching were also observed. Statistical analysis was performed using two-way repeated measures analysis of variance (p<0.05), the Tukey test for internal fit and marginal adaptation, and the Student t-test for bond strength. The failure types (adhesive or cohesive) were classified on each fractured beam. The results showed that the misfit of the pulpal walls (p=0.0002) and the marginal adaptation (p=0.0001) of the feldspathic ceramic were significantly higher when compared to those of the polymer-infiltrated ceramic, while the bond strength values of the former were higher when compared to those of the latter. The contact angle of the polymer-infiltrated ceramic was also higher. In the present study, the hybrid ceramic presented improved internal and marginal adaptation, but the bond strengths were higher for the feldspathic ceramic. PMID:25405903

  20. Progress in developing a model for interaction of bituminized waste products with water

    The reported work is part of a study of long-term properties of bituminized waste products. The long-term goal is: - estimating the swelling and degradation of an agglomerate of ion exchange resins and bitumen when submerged in water, - estimating the consequent pressure build-up and degradation of surrounding barriers in the repository. The report describes the first steps in calculating diffusion of water into the heterogeneous medium of ion exchange resins and bitumen and the consequent swelling of the material. Different models for the effective diffusivity are applied and implemented into a new version of the code GEOPATH which then also considers the swelling due to water uptake. Two-dimensional cylindrical geometry is considered. Results from some test calculations are shown. It is concluded that swelling is an important effect which can be handled theoretically if basic data are available. (authors)

  1. Noise Reduction Properties of an Experimental Bituminous Slurry with Crumb Rubber Incorporated by the Dry Process

    Moisés Bueno

    2014-08-01

    Full Text Available Nowadays, cold technology for asphalt pavement in the field of road construction is considered as an alternative solution to conventional procedures from both an economic and environmental point of view. Among these techniques, bituminous slurry surfacing is obtaining an important role due to the properties of the obtained wearing course. The functional performance of this type of surfaces is directly related to its rough texture. Nevertheless, this parameter has a significant influence on the tire/road noise generation. To reduce this undesirable effect on the sound performance, new designs of elastic bituminous slurries have been developed. Within the FENIX project, this work presents the acoustical characterization of an experimental bituminous slurry with crumb rubber from wasted automobile tires incorporated by the dry process. The obtained results show that, under controlled operational parameters, the close proximity sound levels associated to the experimental slurry are considerably lower than those emitted by a conventional slurry wearing course. However, after one year of supporting traffic loads and different weather conditions, the evaluated bituminous slurry, although it conserves the original noise reduction properties in relation to the conventional one, noticeably increases the generated sound emission. Therefore, it is required to continue improving the design of experimental surfaces in order to enhance its long-term performance.

  2. Polygenic formation model of the planet's bituminous belts

    Dmitrievsky, A. N.; Balanyuk, I. E.

    2011-05-01

    In recent years, much attention has been paid to nontraditional hydrocarbon sources. Today the portion of nontraditional gas in the world extraction is 15% or 450 billion cubic meters, which hat makes up the volume of total gas exports from Russia. As is known, the easy-prospecting oil has been already found. The innovative technologies in geophysics, drilling, and excavation and the increased extraction coefficient expect further development and industrial compliance with these requirements. Based on calculations, the world oil reserves are now one trillion of stock tank barrels and one trillion barrels have been already extracted. The evergrowing demand for energy gives rise to the necessity of searching for and extracting more oil resources, and both these aspects are unique problems. The search for profitable petroleum deposits has become more and more difficult even in the leading companies. The increment of the world resources is a key vital question; therefore, the elaboration of criteria for the discovery of nontraditional deposits take on special significance in the economic respect. The authors are working out a conception that will be a guideline for future finding of the richest oil deposits in active geodynamic zones. For the first time, we suggest the polygenic formation model of the planet's bituminous belts.

  3. Gasification of high ash, high ash fusion temperature bituminous coals

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  4. A process for the bituminization of radioactive wastes

    A process is described for the incorporation of sodium nitrate solutions in bitumen, with a view to the bituminization of radioactive wastes. This process has involved the development of a chemical process and its technological application. A double jacket reactor equipped with an anchor-type stirrer has been built. Sodium nitrate (NaNO3) solutions with sodium hydroxide (NaOH) are fed into the reactor simultaneously with a bitumen emulsion while heated oil is circulated through the double jacket. After all the water has evaporated, the mixture is ''simmered'' at 170/180 deg C for up to 5 hours in order to get a homogeneous product which will be suitable for final storage. The product contains small salt crystals (10/50 μm) and has high viscosity (200/2000 poise at 160 deg C and 12 rpm), so that the possibility of sedimentation is eliminated. In comparative experiments with molten bitumen, large salt aggregates, inhomogeneously distributed, make the product unsuitable. It has been found that NaOH is responsible for the polimerization of the bitumen, which raises its viscosity. The degree of polimerization depends on the NaOH concentration and ''simmering'' time and temperature. NaOH is added to NaNO3 in order to raise the mixture's viscosity and thereby prevent sedimentation

  5. Microbial activity in argillite waste storage cells for the deep geological disposal of French bituminous medium activity long lived nuclear waste: Impact on redox reaction kinetics and potential

    Albrecht, A.; Leone, L.; Charlet, L.

    2009-04-01

    Micro-organisms are ubiquitous and display remarkable capabilities to adapt and survive in the most extreme environmental conditions. It has been recognized that microorganisms can survive in nuclear waste disposal facilities if the required major (P, N, K) and trace elements, a carbon and energy source as well as water are present. The space constraint is of particular interest as it has been shown that bacteria do not prosper in compacted clay. An evaluation of the different types of French medium and high level waste, in a clay-rich host rock storage environment at a depth between 500 and 600 m, has shown that the bituminous waste is the most likely candidate to accommodate significant microbial activity. The waste consists of a mixture of bitumen (source of bio-available organic matter and H2 as a consequence of its degradation and radiolysis) and nitrates and sulphates kept in a stainless steel container. The assumption, that microbes only have an impact on reaction kinetics needs to be reassessed in the case where nitrates and sulphates are present since both are known not to react at low temperatures without bacterial catalysis. The additional impact of both oxy-anions and their reduced species on redox conditions, radionuclide speciation and mobility gives this evaluation their particular relevance. Storage architecture proposes four primary waste containers positioned into armoured cement over packs and placed with others into the waste storage cell itself composed of a cement mantle enforcing the argillite host rock, the latter being characterized by an excavation damaged zone constricted both in space and in time and a pristine part of 60 m thickness. Bacterial activity within the waste and within the pristine argillite is disregarded because of the low water activity (low mobility of critical RN, • increased retardation of mobile RN in biofilms (i.e. adsorption on microbial cell surfaces and products of possible biomineralization); complexation by

  6. Development of New Bituminous Pavement Design Method

    Ullidtz, Per

    The report and work of COST Action 333 sets in place the foundation for a coherent, cost-effective and harmonised European pavement design method. In order to do this, the work programme focused on information gathering, identification of requirements and the selection of the necessary design...

  7. Valuation of investments in natural resources using contingent-claim framework with application to bituminous coal developments in Korea

    As Brennan and Schwartz [Brennan M, Schwartz E. Evaluating natural resource investment. Journal of Business 1985;58:135-57] point out in their pioneering work, the valuation of natural resources projects is particularly difficult due to the high degree of uncertainty in output prices of resources. In general, there are two competing procedures to evaluate risky projects in natural resources developments. One is decision analytic, based on traditional discounted cash flow and stochastic dynamic programming [Fleten SE, Maribu KM, Wangensteen I. Optimal investment strategies in decentralized renewable power generation under uncertainty. Energy 2007;32:803-15; Smith J, McCardle K. Valuing oil properties: integrating option pricing and decision analysis approaches. Operations Research 1998;46(2):198-217; Szklo AS, Carneiro JTG, Machado G. Break-even price for upstream activities in Brazil: evaluation of the opportunity cost of oil production delay in a non-mature sedimentary production region. Energy 2008;33:589-600], and the other is contingent claims analysis, based on the no-arbitrage theory of financial markets [Brennan M, Schwartz E. Evaluating natural resource investment. Journal of Business 1985;58:135-57; Emhjellen M, Alaouze CM. A comparison of discounted cash flow and modern asset pricing methods - project selection and policy implications. Energy Policy 2003;31:1213-20; Laughton D. The management of flexibility in the upstream petroleum industry. The Energy Journal 1998;19:83-114; Paddock L, Siegel D, Smith J. Option valuation of claims on real assets: the case of offshore petroleum leases. Quarterly Journal of Economics 1988;103(3):479-508; Schwartz ES. Valuing long-term commodity assets. Journal of Energy Finance and Development 1998;3(2):85-99; Sezgen O, Goldman CA, Krishnarao P. Option value of electricity demand response. Energy 2007;32:108-19]. In this paper, we use the second approach to develop a new model, and the main contributions are providing a

  8. Valuation of investments in natural resources using contingent-claim framework with application to bituminous coal developments in Korea

    As Brennan and Schwartz [Brennan M, Schwartz E. Evaluating natural resource investment. Journal of Business 1985;58:135-57] point out in their pioneering work, the valuation of natural resources projects is particularly difficult due to the high degree of uncertainty in output prices of resources. In general, there are two competing procedures to evaluate risky projects in natural resources developments. One is decision analytic, based on traditional discounted cash flow and stochastic dynamic programming [Fleten SE, Maribu KM, Wangensteen I. Optimal investment strategies in decentralized renewable power generation under uncertainty. Energy 2007;32:803-15; Smith J, McCardle K. Valuing oil properties: integrating option pricing and decision analysis approaches. Operations Research 1998;46(2):198-217; Szklo AS, Carneiro JTG, Machado G. Break-even price for upstream activities in Brazil: evaluation of the opportunity cost of oil production delay in a non-mature sedimentary production region. Energy 2008;33:589-600], and the other is contingent claims analysis, based on the no-arbitrage theory of financial markets [Brennan M, Schwartz E. Evaluating natural resource investment. Journal of Business 1985;58:135-57; Emhjellen M, Alaouze CM. A comparison of discounted cash flow and modern asset pricing methods - project selection and policy implications. Energy Policy 2003;31:1213-20; Laughton D. The management of flexibility in the upstream petroleum industry. The Energy Journal 1998;19:83-114; Paddock L, Siegel D, Smith J. Option valuation of claims on real assets: the case of offshore petroleum leases. Quarterly Journal of Economics 1988;103(3):479-508; Schwartz ES. Valuing long-term commodity assets. Journal of Energy Finance and Development 1998;3(2):85-99; Sezgen O, Goldman CA, Krishnarao P. Option value of electricity demand response. Energy 2007;32:108-19]. In this paper, we use the second approach to develop a new model, and the main contributions are providing a

  9. Modular titanium alloy neck adapter failures in hip replacement - failure mode analysis and influence of implant material

    Bloemer Wilhelm

    2010-01-01

    Full Text Available Abstract Background Modular neck adapters for hip arthroplasty stems allow the surgeon to modify CCD angle, offset and femoral anteversion intraoperatively. Fretting or crevice corrosion may lead to failure of such a modular device due to high loads or surface contamination inside the modular coupling. Unfortunately we have experienced such a failure of implants and now report our clinical experience with the failures in order to advance orthopaedic material research and joint replacement surgery. The failed neck adapters were implanted between August 2004 and November 2006 a total of about 5000 devices. After this period, the titanium neck adapters were replaced by adapters out of cobalt-chromium. Until the end of 2008 in total 1.4% (n = 68 of the implanted titanium alloy neck adapters failed with an average time of 2.0 years (0.7 to 4.0 years postoperatively. All, but one, patients were male, their average age being 57.4 years (36 to 75 years and the average weight 102.3 kg (75 to 130 kg. The failures of neck adapters were divided into 66% with small CCD of 130° and 60% with head lengths of L or larger. Assuming an average time to failure of 2.8 years, the cumulative failure rate was calculated with 2.4%. Methods A series of adapter failures of titanium alloy modular neck adapters in combination with a titanium alloy modular short hip stem was investigated. For patients having received this particular implant combination risk factors were identified which were associated with the occurence of implant failure. A Kaplan-Meier survival-failure-analysis was conducted. The retrieved implants were analysed using microscopic and chemical methods. Modes of failure were simulated in biomechanical tests. Comparative tests included modular neck adapters made of titanium alloy and cobalt chrome alloy material. Results Retrieval examinations and biomechanical simulation revealed that primary micromotions initiated fretting within the modular tapered neck

  10. Thermal management of electronic components with thermal adaptation composite material

    Thermal adaptation composite material is a kind of composite material with required thermal conductivity or coefficient of thermal expansion through the selection and design of its components. A kind of thermal adaptation composite material that has excellent thermal conductivity and heat storage capacity is prepared by absorbing paraffin into expanded graphite. An electronic cooling experimental system based on the thermal adaptation composite material is built. The temperature variations of the simulative chip are respectively measured in this system and the traditional cooling system to investigate the effect of the thermal adaptation composite material on electronic cooling. At the same time, the impacts of composite material dosage and combining active cooling manner on the performance of electronic cooling are also studied. The experimental results show that the apparent heat transfer coefficients of the electronic cooling experimental system are 1.25-1.30 times higher than those of the traditional cooling system. It also can be found that the dosage of composite material has positive impact on the performance of electronic cooling. By combining active cooling manner, it can compensate the deficiency of cooling capacity in phase change thermal control.

  11. Using proximate analysis to characterize airborne dust generation from bituminous coals

    Page, S.J.; Organiscak, J.A.

    2005-11-01

    Prolonged exposure to airborne respirable coal dust is responsible for coal workers pneumoconiosis (CWP), commonly called black lung. Health research studies have identified that the prevalence and severity of CWP are directly related to both the amount of dust exposure and the coal rank. The amount of airborne respirable dust (ARD) smaller than 10 micrometers generated from breakage of different coals varies widely. To investigate the cause, researchers for the National Institute for Occupational Safety and Health (NIOSH) have conducted experiments to identify the causes of airborne respirable dust liberation. Laboratory crushing experiments were conducted on a range of low to high volatile bituminous coals from eight mines. The results indicate that the proximate analysis of a coal sample can provide a very good indicator of the potential for a dust problem. For application to the coal mining, processing, and utilization industries, data from 977 US coal seams compiled by the Department of Energy (DoE) has been used to calculate this dust generation potential from an equation based on the NIOSH measured data. A simple procedure for this calculation is provided. 1 fig.

  12. Effect of Guide Materials Developed in “Adaptation and Natural Selection” Subject on Remedying Grade 8 Students Alternative Conceptions

    Bakırcı, Hasan; Çalık, Muammer

    2013-01-01

    The purpose of this study is to examine effect of guide materials developed in ‘adaptation and natural selection’ subject on grade 8 students’ alternative conceptions. This study was conducted with 31 grade 8 students in spring semester of 2009-2010. In this context, to define the students’ conceptual problems cited in related literature, an extensive literature review was initially carried out. Adaptation and Natural Selection Concept Test was employed as a pre-test one week before the teach...

  13. The Implication and Application of Communicative Approach to Designing and Adapting ELT Materials for Chinese College Students

    张靓

    2009-01-01

    The Communicative approach is a main stream in current ELT classroom.This approach mainly aims at developing leamers'communicative competences to equip them to be,proficient in real life communication in English.The communicative approach influences the belief of language learning,teaching,methodology and inevitably the syllabus and also ELT materials.However.communicative materials are not quite suitable for Chinese learners all the time,cause it can not meet the some specific expectations and competences of Chinese learners and teachers.Thus,adaptation is needed to make materials more.workable and help learners to develop their language proficiency.This essay will first introduce the communicative approach and materials briefly and then analyses the reasons of adaptation according to the specific context of Chinese college learners.

  14. The Implication and Application of Communicative Approach to Designing and Adapting ELT Materials for Chinese College Students

    张靓

    2009-01-01

    The Communicative approach is a main stream in current ELT classroom.This approach mainly aims at developing learners'communicative competences to equip them to be proficient in real life communication in English.The communicative approach influences the belief of language learning,teaching,methodology and inevitably the syllabus and also ELT materials.However,communicative materials are not quite suitable for Chinese learners all the time,cause it can not meet the some specific expectations and competences of Chinese learners and teachers.Thus,adaptation is needed to make materials more workable and help learners to develop their language proficiency.This essay will first introduce the communicative approach and materials briefly and then analyses the reasons of adaptation according to the specific context of Chinese college learners.

  15. Briquetting of Afsin-Elbistan lignite

    Gurbuz-Beker, U.; Kucukbayrak, S.; Ozer, A. [Istanbul Technical University, Istanbul (Turkey). Chemical Engineering Dept.

    1998-05-01

    Low-quality Afsin-Elbistan lignite was mixed with a high-quality Siberian bituminous coal and optimum briquetting conditions were investigated for blends with and without binder materials. The blends of lignite and bituminous coal were prepared to contain 30, 40 and 50% bituminous coal and briquetted under pressures of 566 MPa and 708 MPa. The blends of lignite and bituminous coal were also briquetted using sunflower shell, sawdust and molasses as additives. In these experiments, the percentage of the lignite in the blends was fixed at 50%, so that the sum of the percentages of the bituminous coal and binder additive was always 50%. In this way, the low-grade lignite and high-quality bituminous coal fines are converted into a compact and stable fuel which has a higher quality. 14 refs., 11 figs., 2 tabs.

  16. Development of new non destructive methods for bituminized radioactive waste drums characterization

    Radioactive waste constitute a major issue for the nuclear industry. One of the key points is their characterization to optimize their management: treatment and packaging, orientation towards the suited disposal. This thesis proposes an evaluation method of the low-energy photon attenuation, based on the gamma-ray spectra Compton continuum. Effectively, the 241Am measurement by gamma-ray spectrometry is difficult due to the low energy of its main gamma-ray (59.5 keV). The photon attenuation strongly depends on the bituminous mix composition, which includes very absorbing elements. As the Compton continuum also depends on this absorption, it is possible to link the 59.5 keV line attenuation to the Compton level. Another technique is proposed to characterize uranium thanks to its fluorescence X-rays induced by the gamma emitters already present in the waste. The uranium present in the drums disturbs the neutron measurements and its measurement by self-induced X-ray fluorescence allows to correct this interference. Due to various causes of error, the total uncertainty is around 50 % on the activity of the radioisotope 241Am, corrected by the peak to Compton technique. The same uncertainty is announced on the uranium mass measured by self induced X-ray fluorescence. As a consequence of these promising results, the two methods were included in the industrial project of the 'Marcoule Sorting Unit'. One major advantage is that they do not imply any additional material because they use information already present in the gamma-ray spectra. (author)

  17. Generalization of Hindi OCR Using Adaptive Segmentation and Font Files

    Agrawal, Mudit; Ma, Huanfeng; Doermann, David

    In this chapter, we describe an adaptive Indic OCR system implemented as part of a rapidly retargetable language tool effort and extend work found in [20, 2]. The system includes script identification, character segmentation, training sample creation, and character recognition. For script identification, Hindi words are identified in bilingual or multilingual document images using features of the Devanagari script and support vector machine (SVM). Identified words are then segmented into individual characters, using a font-model-based intelligent character segmentation and recognition system. Using characteristics of structurally similar TrueType fonts, our system automatically builds a model to be used for the segmentation and recognition of the new script, independent of glyph composition. The key is a reliance on known font attributes. In our recognition system three feature extraction methods are used to demonstrate the importance of appropriate features for classification. The methods are tested on both Latin and non-Latin scripts. Results show that the character-level recognition accuracy exceeds 92% for non-Latin and 96% for Latin text on degraded documents. This work is a step toward the recognition of scripts of low-density languages which typically do not warrant the development of commercial OCR, yet often have complete TrueType font descriptions.

  18. Adapted VTA and SIA method in tree static assessment with use of resistography

    PERNEK, MILAN; Lacković, Nikola; MAČAK-HADŽIOMEROVIĆ, AMRA; Stamenković, Vanja

    2013-01-01

    Background and Purpose: This paper introduces a method for assessment of static safety by using the combination of adapted VTA and SIA methods and a resistograph. The aim is to assess the static as reliably as possible and without the need for expensive equipment. The purpose of this paper is to propose amethod for the static assessment which could be applied in practice in the future. Materials and Methods: Seven trees in the Botanical Garden of the Faculty of Science (University of Z...

  19. On the oxidation of the dissolved organic matter in Boom clay by NaNO3 and NaNO2 from disposed Eurobitum bituminized waste

    Document available in extended abstract form only. In Belgium, Boom Clay is studied as a potential host clay formation for the final disposal of EUROBITUM bituminized waste, which consists of 60 wt% hard bitumen (Mexphalt R85/40) and 40 wt% waste. The main salts that are present in the bituminized waste are NaNO3, 20-30 wt%, and CaSO4, 4-6 wt%. After disposal of the waste in the clay, an uptake of pore water by the embedded, dehydrated and hygroscopic salts will lead to a swelling of the waste and to a release of the salts into the Boom Clay. A possible consequence of the salt release is the oxidation of the clay by nitrate and, possibly, nitrite, resulting in a lower reducing capacity of the clay towards redox sensitive radionuclides, which in turn could have an impact on the migration behaviour of these radionuclides. The extent of oxidation of authigenic Boom Clay redox sensitive components, like organic matter and pyrite is studied at the SCK.CEN. As a first step in the study of the influence of nitrate and nitrite on the redoxactive Boom Clay components, we performed batch tests with dissolved organic matter (DOM). DOM was exposed to different concentrations of nitrate and nitrite for more than one year in both biotic and abiotic conditions. This paper will discuss the results obtained by exposing DOM to nitrate and nitrite and comparing two methods for the determination of its redox capacity. NaNO3 or NaNO2, previously stored under inert atmosphere to remove all oxygen gas, was added to Boom Clay water collected from a piezometer to obtain final salt concentrations of 0.1 and 0.005 M NaNO3, or 0.05 and 0.005 M NaNO2. Sodium azide, also stored under inert atmosphere, was added (0.2 wt. %) to inhibit the microbial activity in the tests, creating abiotic conditions. All solutions were prepared in an anaerobic glove box. The nitrate and nitrite reduction by DOM was followed by analysing the concentrations of nitrate, nitrite and ammonium in the solutions and of

  20. Changes in optical properties, chemistry, and micropore and mesopore characteristics of bituminous coal at the contact with dikes in the Illinois Basin

    Mastalerz, Maria; Drobniak, A.; Schimmelmann, A.

    2009-01-01

    Changes in high-volatile bituminous coal (Pennsylvanian) near contacts with two volcanic intrusions in Illinois were investigated with respect to optical properties, coal chemistry, and coal pore structure. Vitrinite reflectance (Ro) increases from 0.62% to 5.03% within a distance of 5.5??m from the larger dike, and from 0.63% to 3.71% within 3.3??m from the small dike. Elemental chemistry of the coal shows distinct reductions in hydrogen and nitrogen content close to the intrusions. No trend was observed for total sulfur content, but decreases in sulfate content towards the dikes indicate thermochemical sulfate reduction (TSR). Contact-metamorphism has a dramatic effect on coal porosity, and microporosity in particular. Around the large dike, the micropore volume, after a slight initial increase, progressively decreases from 0.0417??cm3/g in coal situated 4.7??m from the intrusive contact to 0.0126??cm3/g at the contact. Strongly decreasing mesopore and micropore volumes in the altered zone, together with frequent cleat and fracture filling by calcite, indicate deteriorating conditions for both coalbed gas sorption and gas transmissibility. ?? 2008 Elsevier B.V. All rights reserved.

  1. Crumb Rubber in cold recycled bituminous mixes

    Dondi, Giulio; Tataranni, Piergiorgio; Pettinari, Matteo;

    2014-01-01

    . Cold recycling is, among the recycling techniques, certainly the most studied and developed: it allows the recovering of bituminous material from an existing pavement without the addition of heat, whilst ensuring the creation of high quality bound base layers. A wide range of materials have been tested...... together with Reclaimed Asphalt Pavement (RAP) and, consequently, there is a large number of variables that can be considered in the mix-design process of new eco-friendly Cold Recycled Mixes. In particular, the present research involves the use of Crumb Rubber within a mixture containing 100% Reclaimed...... Asphalt Pavement, cold recycled with bitumen emulsion and cement. Two different Crumb Rubbers were adopted: one from the ambient production method, and one produced with the cryogenic process. The goal of this research project was to analyze and evaluate the different physical and mechanical...

  2. Apical adaptation, sealing ability and push-out bond strength of five root-end filling materials

    Pablo Andrés AMOROSO-SILVA

    2014-08-01

    Full Text Available This study compared the fluid filtration, adaptation to the root canal walls, and the push-out bond strength of two resin-based sealers and three calcium silicate-based retrograde filling materials. Fifty maxillary canines were shaped using manual instruments and the apical portion was sectioned. Retrograde cavities of 3-mm depth were prepared. The specimens were divided into five groups (n = 10: Sealer 26 (S26; MBPc (experimental; MTA; Portland cement with 20% zirconium oxide (PC/ZO, and Portland cement with 20% calcium tungstate (PC/CT. The fluid filtration was measured at 7 and 15 days. To evaluate the interfacial adaptation, sections of the teeth, 1 and 2 mm from the apex, were prepared and the percentage of gaps was calculated. The push-out bond strength at 2 mm from the apex was evaluated. Statistical analysis was performed using the ANOVA/Tukey’s test (p < 0.05. At 7 and 15 days (p = 0.0048, p = 0.006, the PC/CT group showed higher fluid filtration values when compared to other groups. At 1 mm from the apex, no statistical differences in the adaptation were found among the cements (p = 0.44. At 2 mm from the apex, the PC/ZO group presented statistically lower percentage of gaps than S26, MBPc, and MTA (p = 0.0007. The MBPc group showed higher push-out bond strength than other cements evaluated (p = 0.0008. The fluid filtration and interfacial adaptation of the calcium silicate-based cements were similar to those of the resin-based cements. The resinous cement MBPc showed superior push-out bond strength.

  3. Development of bituminous coal liquefaction technology. ; Study using a small device (study on synthetic iron sulfide catalyst). Rekiseitan ekika gijutsu no kaihatsu. ; Kogata sochi ni yoru kenkyu (gosei ryukatetsu shokubai no kenkyu)

    Ueda, S. (New Energy and Industrial Technology Development Organization, Tokyo (Japan))

    1993-09-01

    This paper reports the execution of device procurement and building construction of small equipment to manufacture synthetic iron sulfide for catalysts used in the NEDOL bituminous coal liquefaction process, carried out in the fiscal year 1992. To study synthetic iron sulfide catalysts manufactured by the dry manufacturing method, it has been planned to install small equipment with a catalyst manufacturing capacity of 10 kg/hr in a process supporting unit (PSU) plant. Major devices and electric measuring instruments have been procured. The construction work included civil engineering and building constructions for part of buildings to accommodate the whole equipment used in the sintering process and an electric room adjoining thereto. Because this small equipment serves also as a PSU exhaust gas treatment facility to treat exhaust gas containing SO2 produced as a sub-product in the sintering process, the PSU exhaust gas treatment process was modified, and the trial operation was carried out in September 1992. Technical standards and operation methods were discussed on each of the sintering process and the exhaust gas treatment process in the small equipment. A process instruction document, and an operation standard for steady operation, start-up and shutdown were prepared.

  4. Adaptive coupling between damage mechanics and peridynamics: a route for objective simulation of material degradation up to complete failure

    Han, Fei

    2016-05-17

    The objective (mesh-independent) simulation of evolving discontinuities, such as cracks, remains a challenge. Current techniques are highly complex or involve intractable computational costs, making simulations up to complete failure difficult. We propose a framework as a new route toward solving this problem that adaptively couples local-continuum damage mechanics with peridynamics to objectively simulate all the steps that lead to material failure: damage nucleation, crack formation and propagation. Local-continuum damage mechanics successfully describes the degradation related to dispersed microdefects before the formation of a macrocrack. However, when damage localizes, it suffers spurious mesh dependency, making the simulation of macrocracks challenging. On the other hand, the peridynamic theory is promising for the simulation of fractures, as it naturally allows discontinuities in the displacement field. Here, we present a hybrid local-continuum damage/peridynamic model. Local-continuum damage mechanics is used to describe “volume” damage before localization. Once localization is detected at a point, the remaining part of the energy is dissipated through an adaptive peridynamic model capable of the transition to a “surface” degradation, typically a crack. We believe that this framework, which actually mimics the real physical process of crack formation, is the first bridge between continuum damage theories and peridynamics. Two-dimensional numerical examples are used to illustrate that an objective simulation of material failure can be achieved by this method.

  5. Review Of Parameter Estimation Using Adaptive Filtering

    LALITA RANI, SHALOO KIKAN

    2013-07-01

    Full Text Available In this paper, a comparative study of different adaptive filter algorithm for channel parameter estimation is described. We presented different parameter estimation approaches of adaptive filtering. An extended Kalman filter is then applied as a near-optimal solution to the adaptive channel parameter estimation problem. Kalman filtering is applied for motion parameters resulting in optimal pose estimation. A parallel Kalman filter is applied for joint estimation of code delay, multipath gains and Doppler shift. In this paper, a complete review of parameter estimation using adaptive filtering is explained.

  6. Evolution of adaptation mechanisms: Adaptation energy, stress, and oscillating death.

    Gorban, Alexander N; Tyukina, Tatiana A; Smirnova, Elena V; Pokidysheva, Lyudmila I

    2016-09-21

    In 1938, Selye proposed the notion of adaptation energy and published 'Experimental evidence supporting the conception of adaptation energy.' Adaptation of an animal to different factors appears as the spending of one resource. Adaptation energy is a hypothetical extensive quantity spent for adaptation. This term causes much debate when one takes it literally, as a physical quantity, i.e. a sort of energy. The controversial points of view impede the systematic use of the notion of adaptation energy despite experimental evidence. Nevertheless, the response to many harmful factors often has general non-specific form and we suggest that the mechanisms of physiological adaptation admit a very general and nonspecific description. We aim to demonstrate that Selye׳s adaptation energy is the cornerstone of the top-down approach to modelling of non-specific adaptation processes. We analyze Selye׳s axioms of adaptation energy together with Goldstone׳s modifications and propose a series of models for interpretation of these axioms. Adaptation energy is considered as an internal coordinate on the 'dominant path' in the model of adaptation. The phenomena of 'oscillating death' and 'oscillating remission' are predicted on the base of the dynamical models of adaptation. Natural selection plays a key role in the evolution of mechanisms of physiological adaptation. We use the fitness optimization approach to study of the distribution of resources for neutralization of harmful factors, during adaptation to a multifactor environment, and analyze the optimal strategies for different systems of factors. PMID:26801872

  7. [In vitro comparison of marginal adaptation of various filling materials. I. Effect of the filling material on marginal adaptation].

    Kóhalmi, T; Gorzo, I; Mari, A; Nagy, K

    1999-03-01

    In a two-month in vitro experiment cervical marginal adaptation was examined in relation to the preparation, filling method and restorative material. Fifty Class II cavities were prepared in fifty extracted sound human premolar and molar teeth extending to the approximal cement-enamel junction. The cavities to receive composite restorations were bevelled at the vestibulo-occlusal and -approximal enamel margins, the other aspects of the cavity enamel and gingival margins at the cement-enamel junction being prepared conventionally. The cavities for amalgam were prepared and filled conventionally. The specimens were cycled in different buffer solutions and temperature, modelling possible variations in the oral environment and examined with SEM. The results were analysed using ANOVA. The best marginal adaptation among the composites was achieved with Charisma, Estilux Posterior, Durafil and Prisma AP. H at the bevelled enamel margins, the worst marginal fit was with Heliomolar and Polofil. It was concluded, that adhesive technique reduces, but does not eliminate marginal leakage. PMID:10205985

  8. Solution-verified reliability analysis and design of bistable MEMS using error estimation and adaptivity.

    Eldred, Michael Scott; Subia, Samuel Ramirez; Neckels, David; Hopkins, Matthew Morgan; Notz, Patrick K.; Adams, Brian M.; Carnes, Brian; Wittwer, Jonathan W.; Bichon, Barron J.; Copps, Kevin D.

    2006-10-01

    This report documents the results for an FY06 ASC Algorithms Level 2 milestone combining error estimation and adaptivity, uncertainty quantification, and probabilistic design capabilities applied to the analysis and design of bistable MEMS. Through the use of error estimation and adaptive mesh refinement, solution verification can be performed in an automated and parameter-adaptive manner. The resulting uncertainty analysis and probabilistic design studies are shown to be more accurate, efficient, reliable, and convenient.

  9. Techno-economic Comparison of IGCC Systems Employing Bituminous and Lignite%基于烟煤、褐煤的IGCC系统技术经济性对比

    李政; 梁心玉; 薛亚丽

    2012-01-01

    近年来,褐煤提质技术的发展使得褐煤的高效利用成为可能。基于一种先进的褐煤干燥技术—内部废热利用流化床干燥(wirbelschicht-trocknung mit interner abw rmenu-tzung,WTA),采用ASPEN Plus软件及美国电力研究协会(electric power research institute,EPRI)的技术评价准则(technical assessment guide,TAG),分别对烟煤整体煤气化联合循环(integrated gasification combined cycle,IGCC)电站和褐煤IGCC电站进行技术经济性分析。详细介绍了WTA单元及燃气轮机变工况的建模方法。计算结果表明,引入WTA技术后,褐煤IGCC电站的发电效率比采用传统干燥方式时约提高4.6个百分点,整体性能与烟煤IGCC电站相差不大;而褐煤IGCC电站的发电成本比烟煤IGCC电站低24.4%。高效的褐煤干燥技术能显著提高褐煤IGCC电站的效率,而褐煤低廉的价格又对降低发电成本十分有利,褐煤很可能成为比烟煤更适合IGCC的燃料。%The development of lignite upgrading has enabled the efficient utilization of lignite recently.Based on the description of an advanced lignite drying techniquewirbelschicht-trocknung mit interner abw rmenutzung(WTA),techno-economic analysis of two integrated gasification combined cycle(IGCC) systems employing bituminous and lignite were performed by using ASPEN Plus software and the EPRI technical assessment guide.The WTA model and gas turbine off-design model were explained in detail.The result shows that pre-drying lignite by WTA can increase the net thermal efficiency of lignite IGCC power plant by up to 4.6% points compared to traditional lignite drying technology,making the performance of lignite IGCC as good as bituminous IGCC;but the cost of electricity of lignite IGCC is 24.4% lower than that of bituminous IGCC.Advanced drying technique can improve the performance of lignite IGCC and lignite’s cheap price helps to bring down the cost of electricity.Therefore lignite is

  10. Study on the conditions of bituminization of radioactive wastes and their influence on the stability of stored products

    Investigations carried out on a laboratory and semi-industrial scale showed that the Polish oxidised industrial bitumen P-60 was suitable for the solidification of liquid radioactive waste and particularly for non-concentrated post-precipitation sludges. The bitumen products were highly stable and were resistant to leaching by acids, salt solutions and water. Laboratory leach tests gave values similar to those obtained by others using different bitumen. By evaluating the sorption characteristics of the soil and the hydrogeological conditions existing at a proposed storage site, it was shown that the solidified wastes could be stored directly in the soil without further isolation from the soil water. Based on the liquid wastes arising from a nuclear power plant it has been shown that solidification of the wastes in bitumen will be cheaper than solidification of the same wastes using cement

  11. Experimental and theoretical investigation of organometallic radioprotective materials adapted to radiation sources with complex isotope composition

    Attenuation of γ-radiation dose rate (60Co, 58Co, 198Au, 54Mn, 24Na) by homogeneous radioprotective material Abris RZ depending on composition and thickness is studied. The technology of homogeneous radioprotective materials permits to form necessary chemical and percentage composition of filling agents (barium sulfate, lead) with good attenuating properties. It is shown that the difference between experimental and calculated dose rate attenuation factors is within 5 %

  12. Effect of adaptation and pulp density on bioleaching of mine waste using indigenous acidophilic bacteria

    Cho, K.; Kim, B.; Lee, D.; Choi, N.; Park, C.

    2011-12-01

    Adaptation to environment is a natural phenomena that takes place in many animals, plants and microorganisms. These adapted organisms achieve stronger applicability than unadapted organisms after habitation in a specific environment for a long time. In the biohydrometallurgical industry, adaptation to special environment conditions by selective culturing is the most popular method for improving bioleaching activity of strains-although that is time consuming. This study investigated the influence of the bioleaching efficiency of mine waste under batch experimental conditions (adaptation and pulp density) using the indigenous acidophilic bacteria collected from acid mine drainage in Go-seong and Yeon-hwa, Korea. We conducted the batch experiments at the influences of parameters, such as the adaptation of bacteria and pulp density of the mine waste. In the adaptation case, the value of pH in 1'st adaptation bacteria sample exhibited lower than in 2'nd adaptation bacteria sample. And the content of both Cu and Zn at 1'st adaptation bacteria sample appeared lower than at 2'nd adaptation bacteria sample. In the SEM analysis, the rod-shaped bacteria with 1μm in length were observed on the filter paper (pore size - 0.45μm). The results of pulp density experiments revealed that the content of both Cu and Zn increased with increasing pulp density, since the increment of pulp density resulted in the enhancement of bioleaching capacity.

  13. Adaptive Tests of Significance Using Permutations of Residuals with R and SAS

    O'Gorman, Thomas W

    2012-01-01

    Provides the tools needed to successfully perform adaptive tests across a broad range of datasets Adaptive Tests of Significance Using Permutations of Residuals with R and SAS illustrates the power of adaptive tests and showcases their ability to adjust the testing method to suit a particular set of data. The book utilizes state-of-the-art software to demonstrate the practicality and benefits for data analysis in various fields of study. Beginning with an introduction, the book moves on to explore the underlying concepts of adaptive tests, including:Smoothing methods and normalizing transforma

  14. The projects of reducing environmental pollution at the collieries belonging to Petrosani Autonomous Bituminous Coal Administration

    The economic development in the Jiu Valley, as practised in the mining and processing of bituminous coal, has had a dynamic character without taking into account, however, the harmful impact on the environment. The most severe problem of environmental pollution in the Jiu Valley is that of the pollution of the Jiu River due to the discharge of waste water from the technological processes of mining and processing coal. This paper presents some solutions for reducing this environmental pollution, especially the Jiu water pollution. 1 ref

  15. Investigation of activity release from bituminized intermediate-level waste forms under thermal stresses

    To determine the consequences of a fire during fabrication, intermediate storage and transport of bituminized NaNO3 waste forms, the fractions of plutonium released from the waste forms were assessed. For this purpose, laboratory tests were made with PuO2-containing specimens as well as a field test with specimens containing Eu2O3. By the evaluation of plutonium release in the laboratory and by the determination of the total sodium release and the relative Eu/Na release in the field tests the plutonium release can be deduced from full-scale specimens. The results show that for bituminized waste forms with high NaNO3 contents (approx. 36 wt%) the average plutonium release obtained in laboratory testing is 15%. In the field tests (IAEA fire test conditions) an average Eu release of 8% was found. These results justify the statement that also for waste forms in open 175 L drum inserts a maximum plutonium release of about 15% can be expected. From the time-dependence of Eu/Na release in the field tests an induction period of 15-20 minutes between the start of testing and the first Na/Eu release can be derived. The maximum differential Na/Eu release occurs after a test period of 45 to 60 minutes duration and after 90 to 105 minutes (tests K2 and K4, respectively); after that time also the highest temperatures in the products are measured. The release values were determined for products in open 175 L drum inserts which in this form are not eligible for intermediate and ultimate storage. For bituminized waste forms in concrete packages (lost concrete shieldings) a delayed increase in temperature to only 70-80 deg. C takes place (4-5 hours after extinction of the fire) if the fire lasts 45 minutes. The concrete package remains intact under test conditions. This means that activity release from bituminized waste forms packaged in this way can be ruled out in the case under consideration. (author)

  16. Comparative Scanning Electron Microscopic Study of the Marginal Adaptation of Four Root-End Filling Materials in Presence and Absence of Blood

    Behnam Bolhari

    2015-10-01

    Full Text Available Objectives: The aim of this study was to evaluate marginal adaptation of mineral trioxide aggregate (MTA, calcium enriched mixture (CEM cement, Biodentine and BioAggregate in presence of normal saline and human blood.Materials and Methods: In this in-vitro experimental study, 80 extracted single-rooted human teeth were instrumented and filled with gutta-percha. After resect- ing the root-end, apical cavity preparation was done and the teeth were randomly divided into 4 groups (N=20(a total of 8 subgroups. Root-end filling materials were placed in 3mm root-end cavities prepared ultrasonically. Half the specimens in each group were exposed to normal saline and the other half to fresh whole human blood. After 4 days, epoxy resin replicas of the apical portion of samples were fabricated and scanning electron microscopy (SEM analysis was performed to find gaps in the adaptation of the root-end filling materials at their interface with dentin. The Kruskal-Wallis and Mann-Whitney tests were used for statistical analysis of data with P<0.05 as the limit of significance.Results: There were no significant differences in marginal adaptation of the 8 tested groups (P>0.05.Conclusion: Based on the results, blood contamination does not affect the mar- ginal adaptation of MTA, CEM cement, Biodentine or BioAggregate .

  17. Recycling of polyethylene terephthalate (PET plastic bottle wastes in bituminous asphaltic concrete

    Adebayo Olatunbosun Sojobi

    2016-12-01

    Full Text Available This research sheds light on the concept of eco-friendly road construction which comprises eco-design, eco-extraction, eco-manufacturing, eco-construction, eco-rehabilitation, eco-maintenance, eco-demolition, and socioeconomic empowerment. It also revealed the challenges being faced in its adoption and the benefits derivable from its application. Furthermore, the effects of recycling PET plastic bottle wastes produced in North Central Nigeria in bituminous asphaltic concrete (BAC used in flexible pavement construction were also evaluated. The mix design consists of 60/70 penetration-grade asphaltic concrete (5%, 68% coarse aggregate, 6% fine aggregate, and 21% filler using the dry process at 170°C. The optimum bitumen content (OBC for conventional BAC was obtained as 4% by weight of total aggregates and filler. Polymer-coated aggregate (PCA-modified BAC seems preferable because it has the potential to utilize more plastic wastes with a higher optimum plastic content (OPC of 16.7% by weight of total aggregates and filler compared to that of 9% by weight of OBC achieved by PMB-BAC. For both PMB- and PCA-modified BAC, an increase in air void, void in mineral aggregate, and Marshall stability were observed. Eco-friendly road construction which recycles PET wastes should be encouraged by government considering its potential environmental and economic benefits.

  18. 基于热重分析法的烟煤掺烧褐煤特性研究%Combustion Characteristics of Bituminous Coal Blended with Lignite Using Thermo-gravimetric Method

    杨志斌; 马莹; 戴新; 赵建军; 关彦军; 张锴

    2015-01-01

    针对电厂掺烧褐煤缺乏相关理论指导的技术需求,采用热重分析方法系统考察了包煤、准煤和褐煤的单独燃烧特性,并将两种烟煤分别以10%、30%、50%和70%的比例在相同条件下与褐煤混合燃烧,根据各燃料燃烧特征参数计算了单一煤种及其不同掺混比例的着火指数、燃尽指数和综合燃烧指数。结果表明,褐煤最易着火和燃尽;包煤着火特性较好,但在550~660℃范围内出现难燃峰致使燃尽特性变差;准煤的着火特性最差,燃尽特性略优于包煤;将包煤和准煤与褐煤掺混后燃烧特性有所改善,各燃烧特征温度降低,且综合燃烧指数随褐煤掺烧比例的增加而增加。建议在电厂实际应用时,褐煤的掺烧比例控制在30%-50%之间。%Based on the actual requirement for fundamental theory of blending lignite in coal-fired power stations, combustion characteristics of lignite, bituminous coal and their blends were investigated by using thermogravimetric method ( TGA) in this paper.Lignite was blended with two types of bituminous coals in proportions of 10%, 30%, 50%and 70%, respectively.The ignition index, burnout index and comprehensive combustion index of single and mixed fuels were calculated by means of combustion characteristic parameters.The results show that lig-nite displays the best ignition and burnout performace, Bao coal is easier to ignite but hard to burn out in the tem-perature range of 550 and 660℃.Compared to Bao coal, Zhun coal is the hardest to ignite but better to burn out. The performance of combustion can be improved after blending lignite, which is largely because the comprehensive combustion index of blended coals increases with the increasing ratio of lignite.Therefore, the blending ratio of lig-nite suggested lignite ration should be controlled between 30%and 50%.

  19. Topology optimization of compliant adaptive wing leading edge with composite materials

    Tong Xinxing; Ge Wenjie; Sun Chao; Liu Xiaoyong

    2014-01-01

    An approach for designing the compliant adaptive wing leading edge with composite material is proposed based on the topology optimization. Firstly, an equivalent constitutive relationship of laminated glass fiber reinforced epoxy composite plates has been built based on the symmetric laminated plate theory. Then, an optimization objective function of compliant adaptive wing leading edge was used to minimize the least square error (LSE) between deformed curve and desired aerodynamics shape. Af...

  20. Evaluation of bituminized waste reactivity; Maitrise de la reactivite thermique lors de l'elaboration d'un conditionnement de dechets radioactifs par le bitume

    Camaro, S.; Moulinier, D. [CEA Saclay, Dept. d' Entreposage et de Stockage des Dechets (DCC/DESD/SEP), 91 - Gif-sur-Yvette (France)

    2000-07-01

    The bituminization process has been used for conditioning low and medium level (LML) radioactive waste, particularly to immobilize coprecipitation slurries and evaporation concentrates generated by effluent treatment. The process consists in mixing bitumen matrix with inactive soluble and slightly soluble salts added to insolubilize the radionuclides or resulting from the neutralization of acid effluents. This operation is performed at a sufficient temperature - depending on waste composition and bitumen grade to ensure the flow of the resulting mixture into metal containers. Exothermicity due to salts/salts or salts/bitumen reactions depending on the type of waste can be induced during or after the mixing step. This could produce an additional heat emission that the drum must be able to release to avoid a potentially incidental pattern with ignition risk, explaining why the CEA has been involved in evaluating the thermal reactivity of bituminized waste and its repercussions on the bituminization process. Given the difficulty of discriminating each exothermal reaction, the characterization of a global reactivity appears as a further precautionary measure, in addition to the definition of a working safety margin. The CEA has accordingly developed studies on this aspect. The article discusses the experimental methodology developed for the determination of the global reactivity. (authors)

  1. Down-scaling of bituminous coal mining, restructuring of steel works and heavy engineering in the Ostrava region

    Klusáček, Petr

    2005-01-01

    Roč. 13, č. 2 (2005), s. 3-12. ISSN 1210-8812 R&D Projects: GA AV ČR(CZ) IBS3086005 Institutional research plan: CEZ:AV0Z30860518 Keywords : Ostrava region * restructuring * steemaking and heavy industry * downscaling of coal- mining Subject RIV: DE - Earth Magnetism, Geodesy, Geography

  2. Comparative Scanning Electron Microscopic Study of the Marginal Adaptation of Four Root-End Filling Materials in Presence and Absence of Blood

    Bolhari, Behnam; Ashofteh Yazdi, Kazem; Sharifi, Farnood; Pirmoazen, Salma

    2015-01-01

    Objectives: The aim of this study was to evaluate marginal adaptation of mineral trioxide aggregate (MTA), calcium enriched mixture (CEM) cement, Biodentine and BioAggregate in presence of normal saline and human blood. Materials and Methods: In this in-vitro experimental study, 80 extracted single-rooted human teeth were instrumented and filled with gutta-percha. After resecting the root-end, apical cavity preparation was done and the teeth were randomly divided into 4 groups (N=20)(a total of 8 subgroups). Root-end filling materials were placed in 3mm root-end cavities prepared ultrasonically. Half the specimens in each group were exposed to normal saline and the other half to fresh whole human blood. After 4 days, epoxy resin replicas of the apical portion of samples were fabricated and scanning electron microscopy (SEM) analysis was performed to find gaps in the adaptation of the root-end filling materials at their interface with dentin. The Kruskal-Wallis and Mann-Whitney tests were used for statistical analysis of data with P0.05). Conclusion: Based on the results, blood contamination does not affect the marginal adaptation of MTA, CEM cement, Biodentine or BioAggregate. PMID:26622276

  3. The guide to PAMIR theory and use of Parameterized Adaptive Multidimensional Integration Routines

    Adler, Stephen L

    2013-01-01

    PAMIR (Parameterized Adaptive Multidimensional Integration Routines) is a suite of Fortran programs for multidimensional numerical integration over hypercubes, simplexes, and hyper-rectangles in general dimension p, intended for use by physicists, applied mathematicians, computer scientists, and engineers. The programs, which are available on the internet at website and are free for non-profit research use, are capable of following localized peaks and valleys of the integrand. Each program comes with a Message-Passing Interface (MPI) parallel version for cluster use as well as serial versions. The first chapter presents introductory material, similar to that on the PAMIR website, and the next is a "manual" giving much more detail on the use of the programs than is on the website. They are followed by many examples of performance benchmarks and comparisons with other programs, and a discussion of the computational integration aspects of PAMIR, in comparison with other methods in the literature. The final chapt...

  4. Implementation and use of composite materials in Fedem

    Tyldum, Tor Helge

    2010-01-01

    The main goal of this master thesis was to implement composite materials in the analyzing software Fedem. Composite materials have become much used materials for various applications; they are used in everything from windmill blades and offshore diving life boats to sporting equipment.Because of the increasing use of composite materials Fedem Technology AS analyses more and more mechanisms containing parts made from these materials. They therefore wanted to implement an element in Fedem that ...

  5. Development of refilling techniques of LA-type bituminized waste products

    In JAEA, 13,296 drums of low-radioactivity bituminized waste products (BWPs) have been stored in asphalt solidification storages. In order to effectively utilize the space of the BWP in a repository site, refilling techniques of the BWP from the drum to a box-shaped container were studied. Tentative processes, which we devised, consisted of (1) take-off of BWP from the drum, (2) separation of a post filling part from BWP and (3) refilling of BWP to a box-shaped container. Two methods for each process were selected, and work efficiencies of the methods were investigated by using a synthetic BWP. (1) Two take-off methods: one was falling down of the BWP from the drum at high temperature such as 100°C and 150°C, and the other was removing the cut drum from the BWP at low temperature. In the former case, it was found that at least 20wt% of the BWP was attached on the container. In the latter case, ca. 100wt% of the BWP was easily recovered by cutting and peeling the drum below 10°C. (2) Two separation methods: one was cutting off the post filling part by using a flat blade, and the other was crushing the post filling part by using a mechanical hammer. In the former case, the BWP could be cut in 2 h, but it was observed that some BWP was attached on the blade. In the latter case, it was found that the post filling part was easily crushed from the BWP below 0°C. (3) Two filling methods: one was filling the softened BWP by heating, and the other was pressure filling. In the both method, filling rates of the BWP were 100wt% and 98.8wt%, respectively. Volume of the BWP after the filling tests increased 6vol% and 2vol% compared to theoretical volume, respectively. (author)

  6. Simulation Research on Adaptive Control of a Six-degree-of-freedom Material-testing Machine

    Dan Wang

    2014-02-01

    Full Text Available This paper presents an adaptive controller equipped with a stiffness estimation method for a novel material-testing machine, in order to alleviate the performance depression caused by the stiffness variance of the tested specimen. The dynamic model of the proposed machine is built using the Kane method, and the kinematic model is established with a closed-form solution. The stiffness estimation method is developed based on the recursive least-squares method and the proposed stiffness equivalent matrix. Control performances of the adaptive controller are simulated in detail. The simulation results illustrate that the proposed controller can greatly improve the control performance of the target material-testing machine by online stiffness estimation and adaptive parameter tuning, especially in low-cycle fatigue (LCF and high-cycle fatigue (HCF tests.

  7. Qualification of tribological materials and coatings for use in sodium

    This paper describes some of the essential performance measures used to qualify materials for tribological applications in liquid sodium environments and summarizes relative properties of some of the newer tribological materials now qualified for use in sodium systems

  8. Application of laser microprobe (LAMMA 1000) to "fingerprinting" of coal constituents in bituminous coal

    Lyons, P.C.; Hercules, D.M.; Morelli, J.J.; Sellers, G.A.; Mattern, D.; Thompson-Rizer, C. L.; Brown, F.W.; Millay, M.A.

    1987-01-01

    A laser microprobe (LAMMA-1000) microchemical analysis of vitrinites of different morphologies but similar reflectances within the same bituminous coal bed indicates distinct "fingerprint" spectra. The banded form of vitrinite contains Li, Ti, Ba, Sr, F, and Cl which were not detected in the nonbanded vitrinite. These differences may indicate a different plant source or the introduction of these elements from fluids mobilized during diagenesis. The nonbanded vitrinite (called corpocollinite), which was contained in a pyrite coal-ball seed fern permineralization of Myeloxylon, may have been protected from influx of these elements due to entrapment by pyrite during an early peat stage. An ion at M/Z 65, which is characteristic of the banded vitrinite, may indicate C5H5+ and, perhaps a difference in the chemical structure of the two vitrinites. These results demonstrate that "fingerprint" spectra can be obtained from vitrinite macerals by LAMMA and that these "fingerprints" have genetic implications. ?? 1987.

  9. A review of diabetes prevention program translations: use of cultural adaptation and implementation research.

    Tabak, Rachel G; Sinclair, Kàimi A; Baumann, Ana A; Racette, Susan B; Sebert Kuhlmann, Anne; Johnson-Jennings, Michelle D; Brownson, Ross C

    2015-12-01

    The Diabetes Prevention Program (DPP) has been shown to prevent type 2 diabetes through lifestyle modification. The purpose of this study was to describe the literature on DPP translation, synthesizing studies using cultural adaptation and implementation research. A systematic search was conducted. Original studies evaluating DPP implementation and/or cultural adaptation were included. Data about cultural adaptation, implementation outcomes, and translation strategies was abstracted. A total of 44 were included, of which 15 reported cultural adaptations and 38 explored implementation. Many studies shortened the program length and reported a group format. The most commonly reported cultural adaptation (13 of 15) was with content. At the individual level, the most frequently assessed implementation outcome (n = 30) was adoption. Feasibility was most common (n = 32) at the organization level. The DPP is being tested in a variety of settings and populations, using numerous translational strategies and cultural adaptations. Implementation research that identifies, evaluates, and reports efforts to translate the DPP into practice is crucial. PMID:26622913

  10. Increase of company performances and shareholders’ satisfaction by using design for adaptability (DFA)

    Briciu, Sorin; Sorinel CĂPUŞNEANU; Dan TOPOR; Raul BURDEA

    2014-01-01

    The article handles the increase in performances of an electrical appliances company and in the satisfaction degree of its shareholders by using the design for adaptability method. A strategic decision is based on the quality of accounting information provided by the company’s management. The design for adaptability method and the target costing method highlight the importance of the reliability of accounting information provided by both of them for the solid foundation of strategic decisions...

  11. Dosimetric- and Geometric Evaluation of Adaptive H&N IMRT Using Deformable Image Registration

    Eiland, R.B.; Behrens, C. F.; Sjöström, D.;

    2012-01-01

    performance of a DIR algorithm, using geometric and dosimetric measures. Materials and Methods: Seven patients treated with IMRT were included in this study, each with a planning- and midterm CT (pCT, ReCT) as well as a CBCT, acquired on the same day as the ReCT. ReCT served as the ground truth for evaluation...... of the DIR. A deformed CT (dCT) with contours was created by deforming the pCT and associated manually drawn contours to the CBCT. A commercially software using the Demons DIR algorithm (SmartAdapt, Varian Medical Systems, v.11.0) was utilized. A geometrical comparison was based on the estimated...

  12. Thermal stability of carboxylic acid functionality in coal; Sekitanchu ni sonzaisuru karubokishiruki no netsubunkai kyodo

    Tsutsumi, Y.; Aida, T. [Kinki University, Osaka (Japan). Faculty of Engineering

    1996-10-28

    Carboxyl in coal was focused in discussing its pyrolytic behavior while tracking change of its absolute amount relative to the heating temperatures. A total of four kinds of coals, consisting of two kinds brown coals, sub-bituminous coal and bituminous coal were used. Change in the absolute amount of carboxyl due to heating varies with coalification degree. Decomposition starts in the bituminous coal from around 300{degree}C, and is rapidly accelerated when 400{degree}C is exceeded. Carboxyls in brown coals exist two to three times as much as those in bituminous and sub-bituminous coals, of which 40% is decomposed at a temperature as low as about 300{degree}C. Their pyrolytic behavior at temperatures higher than 400{degree}C resembles that of the bituminous coal. Carboxyls consist of those easy to decompose and difficult to decompose. Aromatic and aliphatic carboxylic acids with simple structure are stable at temperatures lower than 300{degree}C, and decompose abruptly from about 400{degree}C, hence their behavior resembles that of carboxyls in bituminous and sub-bituminous coals. Structure of low-temperature decomposing carboxyls in brown coals is not known, but it is assumed that humic acid originated from natural materials remains in the structure. 4 refs., 3 figs., 1 tab.

  13. Discovery and Optimization of Materials Using Evolutionary Approaches.

    Le, Tu C; Winkler, David A

    2016-05-25

    Materials science is undergoing a revolution, generating valuable new materials such as flexible solar panels, biomaterials and printable tissues, new catalysts, polymers, and porous materials with unprecedented properties. However, the number of potentially accessible materials is immense. Artificial evolutionary methods such as genetic algorithms, which explore large, complex search spaces very efficiently, can be applied to the identification and optimization of novel materials more rapidly than by physical experiments alone. Machine learning models can augment experimental measurements of materials fitness to accelerate identification of useful and novel materials in vast materials composition or property spaces. This review discusses the problems of large materials spaces, the types of evolutionary algorithms employed to identify or optimize materials, and how materials can be represented mathematically as genomes, describes fitness landscapes and mutation operators commonly employed in materials evolution, and provides a comprehensive summary of published research on the use of evolutionary methods to generate new catalysts, phosphors, and a range of other materials. The review identifies the potential for evolutionary methods to revolutionize a wide range of manufacturing, medical, and materials based industries. PMID:27171499

  14. The process of organisational adaptation through innovations, and organisational adaptability

    Tikka, Tommi

    2010-01-01

    This study is about the process of organisational adaptation and organisational adaptability. The study generates a theoretical framework about organisational adaptation behaviour and conditions that have influence on success of organisational adaptation. The research questions of the study are: How does an organisation adapt through innovations, and which conditions enhance or impede organisational adaptation through innovations? The data were gathered from five case organisations withi...

  15. Radiation stability of bitumunous oils and its tar fraction

    Full text : The radiation-chemical transformation of bituminous oil from Balakhani oil deposit and its tar fraction have been studied. The mechanism of radiation-chemical transformation of bituminous oil and its tar fraction have been established by methods of mass-spectrometry, infrared spectroscopy and chromatography. It has been shown that bituminous oils has a high radiation stability at the temperature under 50 degrees Celsius. The ratio of radiation stabilities of oil and tar fraction is 4:1. The radiation-chemical yield of decomposition of polycyclic aromatic compounds in the tar fraction changes in limits 10-2 - 10-3. It was concluded that high radiation stability of bituminous oil and its tar fraction, allows to use them as a initial raw material for production of the hydroisolation material, which can be used in conditions of influence of radiation

  16. Investigation on Adaptive Re-use of Heritage Building in George Town, Penang

    Marhamah Abdul Hadi; Md Azree Othuman Mydin; Noor Faisal Abas

    2013-01-01

    Adaptive re-use of heritage buildings in George Town has gained attention from their owners. Their owners either private owners or government, want to adapt their respective buildings to new usage for instance to become a gallery, museum, restaurant, boutique hotel and many more. Every heritage building that is being adapted to paper main objective is to identify the changes made in terms of structure, space and material when adapting the heritage buildings to a new usage ...

  17. Topology optimization of compliant adaptive wing leading edge with composite materials

    Tong Xinxing

    2014-12-01

    Full Text Available An approach for designing the compliant adaptive wing leading edge with composite material is proposed based on the topology optimization. Firstly, an equivalent constitutive relationship of laminated glass fiber reinforced epoxy composite plates has been built based on the symmetric laminated plate theory. Then, an optimization objective function of compliant adaptive wing leading edge was used to minimize the least square error (LSE between deformed curve and desired aerodynamics shape. After that, the topology structures of wing leading edge of different glass fiber ply-orientations were obtained by using the solid isotropic material with penalization (SIMP model and sensitivity filtering technique. The desired aerodynamics shape of compliant adaptive wing leading edge was obtained based on the proposed approach. The topology structures of wing leading edge depend on the glass fiber ply-orientation. Finally, the corresponding morphing experiment of compliant wing leading edge with composite materials was implemented, which verified the morphing capability of topology structure and illustrated the feasibility for designing compliant wing leading edge. The present paper lays the basis of ply-orientation optimization for compliant adaptive wing leading edge in unmanned aerial vehicle (UAV field.

  18. Spanish Round Robin test on water sensitivity test of bituminous mixtures; Ejercicio espanol interlaboratorios sobre el ensayo de sensibilidad al gua de mezclas bituminosas

    Jimenez Saez, R.; Enrique Gabeiras, L.; Miranda Perez, L.; Valor Hernandez, F.

    2011-07-01

    The amendment of Article 542 and 543 on the hot asphalt mixtures included in the Spanish Technical specifications for Road Construction (PG-3), by Circular Order 24/2008, introduced a new series of modification to adapt Spanish regulations to European standards series EN 13108. Among the various amendments, new tests methods and design criteria are considered, as UNE-EN 12697-12 for assessing the water sensitivity on compacted specimens, which is mandatory for every kind of bituminous mixture. In this paper, firstly a comparison between the European method and the old Spanish method described in the NLT-162 is made, explaining the experimental conditions selected. The results of an interlaboratory study or Round Robin Test conducted in ten Spanish laboratories are subsequently described and analyzed, in order to allow each laboratory to assess its technical performance, and also to determine quantitatively the precision of the new method in terms of repeatability and reproducibility. (Author) 15 refs.

  19. Problem of the NPP liquid radioactive wastes processing and disposal

    Modern methods of NPP radioactive waste processing and disposal are briefly presented, bituminization with the following disposal in the clayey soil in particular. Soviet installations of liquid waste bituminization and results of proving ground preservation of bituminic blocks are briefly described. These results indicate a possibility of bituminic material disposal with specific activity of 1 Ci/l directly in the soil without waterproofing. High safety and effectivity of waste bituminization is shown in comparison with preservation variant of liquid radioactive concentrates in capacities

  20. Issues in development, evaluation, and use of the NASA Preflight Adaptation Trainer (PAT)

    Lane, Norman E.; Kennedy, Robert S.

    1988-01-01

    The Preflight Adaptation Trainer (PAT) is intended to reduce or alleviate space adaptation syndrome by providing opportunities for portions of that adaptation to occur under normal gravity conditions prior to space flight. Since the adaptation aspects of the PAT objectives involve modification not only of the behavior of the trainee, but also of sensiomotor skills which underly the behavioral generation, the defining of training objectives of the PAT utilizes four mechanisms: familiarization, demonstration, training and adaptation. These mechanisms serve as structural reference points for evaluation, drive the content and organization of the training procedures, and help to define the roles of the PAT instructors and operators. It was determined that three psychomotor properties are most critical for PAT evaluation: reliability; sensitivity; and relevance. It is cause for concern that the number of measures available to examine PAT effects exceed those that can be properly studied with the available sample sizes; special attention will be required in selection of the candidate measure set. The issues in PAT use and application within a training system context are addressed through linking the three training related mechanisms of familiarization, demonstration and training to the fourth mechanism, adaptation.

  1. Increasing Time-Efficiency and Accuracy of Robotic Machining Processes Using Model-Based Adaptive Force Control

    Sörnmo, Olof; Olofsson, Björn; Robertsson, Anders; Johansson, Rolf

    2012-01-01

    Machining processes in the industry of today are rarely performed using industrial robots. In the cases where robots are used, machining is often performed using position control with a conservative feed-rate, to avoid excessive process forces. There is a great benefit in controlling the process forces instead, so as to improve the time-efficiency by applying the maximum allowed force, and thus removing the maximum amount of material per time unit. This paper presents a novel adaptive force c...

  2. Simulation Research on Adaptive Control of a Six-degree-of-freedom Material-testing Machine

    Dan Wang; Rui Fan; Wuyi Chen

    2014-01-01

    This paper presents an adaptive controller equipped with a stiffness estimation method for a novel material-testing machine, in order to alleviate the performance depression caused by the stiffness variance of the tested specimen. The dynamic model of the proposed machine is built using the Kane method, and the kinematic model is established with a closed-form solution. The stiffness estimation method is developed based on the recursive least-squares method and the proposed stiffness equivale...

  3. Modular Sequence: English as a Second Language, Methods and Techniques. TTP 001.13 Evaluating and Adapting Materials. Teacher Corps Bilingual Project.

    Hernandez, Alberto; Melnick, Susan L.

    The purpose of this unit of work is to provide the teacher participant with some useful guidelines for evaluating and adapting written materials for specific English as a second language (ESL) classes. There is pre- and post-assessment of specific learning tasks relevant to evaluating and adapting materials as well as learning activities, which…

  4. Moving HAIRS: Towards adaptive, homeostatic materials

    Aizenberg, Joanna

    Dynamic structures that respond reversibly to changes in their environment are central to self-regulating thermal and lighting systems, targeted drug delivery, sensors, and self-propelled locomotion. Since an adaptive change requires energy input, an ideal strategy would be to design materials that harvest energy directly from the environment and use it to drive an appropriate response. This lecture will present the design of a novel class of reconfigurable materials that use surfaces bearing arrays of nanostructures put in motion by environment-responsive gels. Their unique hybrid architecture, and chemical and mechanical properties can be optimized to confer a wide range of adaptive behaviors. Using both experimental and modeling approaches, we are developing these hydrogel-actuated integrated responsive systems (HAIRS) as new materials with reversible optical and wetting properties, as a multifunctional platform for controlling cell differentiation and function, and as a first homeostatic system with autonomous self-regulation.

  5. Mechanical, sorption and transport experiments on a German high volatile bituminous coal

    Gensterblum, Y.; Krooss, B.M. [RWTH Aachen Univ. (Germany). Inst. of Geology and Geochemistry of Petroleum and Coal; Massarotto, Paul [Queensland Univ., Brisbane, St Lucia, QLD (Australia). School of Engineering

    2013-08-01

    A high volatile bituminous coal (vitrinite reflectance: 0.93%, carbon content: 83%) from the Prosper-Haniel mine, North Rhine-Westphalia has been studied using a comprehensive set of measurements and experimental procedures at RWTH Aachen University and the University of Queensland. Using the True Triaxial Stress Coal Permeameter (TTSCP) (Massarotto 2003) of the University of Queensland, permeability and gas displacement tests were performed on an 80 mm cube of the Prosper-Haniel coal. Extensive data sets were recorded to assess the effects of stress changes on gas transport and the impact of nitrogen, methane and CO{sub 2} sorption on the mechanical properties. We investigate the permeability coefficients for helium, nitrogen, methane and carbon dioxide measured on this sample as a function of net stress. As expected, permeability values decrease with increasing stress. Methane and nitrogen have nearly identical permeability coefficients throughout the entire net stress range, while permeability coefficients measured with helium are higher and those measured with CO{sub 2} significantly lower. During the permeability measurements with CO{sub 2} an anisotropic swelling of the coal cube by about 0.19% to 0.23% was observed. The volumetric effect (swelling) is 100 times slower than gas displacement. Simultaneous mechanical tests indicated a softening of the coal block upon exposure to CO{sub 2}. Thus, a decrease of Young's modulus (YM) of the coal cube during the CO{sub 2} flow test was observed as compared to the methane and nitrogen tests. High-pressure sorption isotherms with CH{sub 4} and CO{sub 2} were determined on different grain-size fractions of the Prosper-Haniel coal at 318K and different moisture contents. Methane sorption capacity decreases by 29% with increasing moisture content. Also, a decrease of sorption rate was observed with increasing moisture content. While sorption rates are generally faster for CO{sub 2} than for CH{sub 4}, the sorption

  6. Sliding mode control of wind-induced vibrations using fuzzy sliding surface and gain adaptation

    Thenozhi, Suresh; Yu, Wen

    2016-04-01

    Although fuzzy/adaptive sliding mode control can reduce the chattering problem in structural vibration control applications, they require the equivalent control and the upper bounds of the system uncertainties. In this paper, we used fuzzy logic to approximate the standard sliding surface and designed a dead-zone adaptive law for tuning the switching gain of the sliding mode control. The stability of the proposed controller is established using Lyapunov stability theory. A six-storey building prototype equipped with an active mass damper has been used to demonstrate the effectiveness of the proposed controller towards the wind-induced vibrations.

  7. Use Case Design for AdaptIVe

    Wolter, Stefan; Kelsch, Johann

    2014-01-01

    AdaptIVe is a large scale European project on vehicle automation and the pertaining human-machine interaction. The use case design process is a crucial part of the system design process and a part of the human-vehicle integration subproject. This paper explains the methodology for describing use cases in AdaptIVe. They are primarily based on sequence diagrams with main and alternative flows.

  8. A STUDY OF BITUMINOUS SHUNGITE BINDER ON THE SCANNING MICROSCOPE

    K. A. Andrianov; D V Ivanov; V. P. Yartsev

    2012-01-01

    Statement of the problem. It is possible to improve working conditions of road pavement and to use it more efficiently by regulating water-thermal conditions of the subgrade thereby reducing humidity in the design period and mitigating its seasonal changes.Results and conclusions. It is suggested to use extruded foam polystyrene as a heating layer. The thermal fluctuation approach was applied to failure and deformation processes. Physical constants for the analytical description of these proc...

  9. Preparation and quality control of materials used in the reference buffer material

    Dixon, D.A.; Hnatiw, D.S.J.; Kohle, C.L.

    1992-09-15

    This document summarizes the methodologies developed for preparing the reference buffer material (RBM) for use in laboratory-scale and field-scale experiments. Two commercially available concrete mixers have been successfully used to repeatedly produce homogeneous bulk buffer and backfill materials. The components, blending procedures, quality control sampling requirements, and mixing checklists used in the production of the reference buffer material are presented. Use of these directions will ensure that consistent batching of sealing materials is achieved and operator-induced variability is minimized.

  10. Development of a method to determine the nuclide inventory in bituminized waste packages; Entwicklung eines Verfahrens zur Bestimmung des Nuklidinventars in bituminierten Abfallgebinden

    Mesalic, E.; Kortman, F.; Lierse von Gostomski, C. [Technische Univ. Muenchen, Garching (Germany). Zentrale Technisch-Wissenschaftliche Betriebseinheit Radiochemie Muenchen (RCM)

    2014-01-15

    Until the 1980s, bitumen was used as a conditioning agent for weak to medium radioactive liquid waste. Its use can be ascribed mainly to the properties that indicated that the matrix was optimal. However, fires broke out repeatedly during the conditioning process, so that the method is meanwhile no longer permitted in Germany. There are an estimated 100 waste packages held by the public authorities in Germany that require a supplementary declaration. In contrast to the common matrices, such as for example resins or sludges, there is still no standardized technology for taking samples and subsequently determining the radio-nuclide for bitumen. Aspects, such as the thermoplastic behaviour, make determining the nuclide inventory more difficult in bituminized waste packages. The development of a standardized technology to take samples with a subsequent determination of the radio-nuclide analysis is the objective of a project funded by the BMBF. Known, new methods, specially developed for the project, are examined on inactive bitumen samples and then transferred to active samples. At first non-destructive methods are used. The resulting information forms an important basis to work out and apply destructive strategy for sampling and analysis. Since the project is on-going, this report can only address the development of the sampling process. By developing a sampling system, it will be possible to take samples from an arbitrary selected location of the package across the entire matrix level and thus gain representative analysis material. The process is currently being optimized. (orig.)

  11. The estimation postradiational adaptation and the recovering processes using parameters of radiocapacity on model ecosystem

    The results of investigations of effect of adaptation and the recovering processes of plants in condition of the ionizing radiation on model ecosystem are shown in this article. The estimation using the parameter of radiocapacity biotic component in water culture of plants of maize on model monoecosystem was conducted

  12. A STUDY OF BITUMINOUS SHUNGITE BINDER ON THE SCANNING MICROSCOPE

    K. A. Andrianov

    2012-07-01

    Full Text Available Statement of the problem. It is possible to improve working conditions of road pavement and to use it more efficiently by regulating water-thermal conditions of the subgrade thereby reducing humidity in the design period and mitigating its seasonal changes.Results and conclusions. It is suggested to use extruded foam polystyrene as a heating layer. The thermal fluctuation approach was applied to failure and deformation processes. Physical constants for the analytical description of these processes at varying temperatures and stresses are calculated. The technique for determining acting stresses and temperatures was described. The prediction of the durability of extruded foam polystyrene in road structure is presented.

  13. Overcoming Barriers in the Use of Adaptive and Assistive Technology in Special Education.

    Bushrow, Kathy M.; Turner, Keith D.

    This paper examines change and change facilitators as they affect full use of adaptive and assistive technology (AAT) in special education, and compares qualitative versus quantitative methods of researching the change process. Four administrators and two teachers from a rural school district completed the Stages of Concern Questionnaire, which…

  14. Quality Assessment of Adaptive Bitrate Videos using Image Metrics and Machine Learning

    Søgaard, Jacob; Forchhammer, Søren; Brunnström, Kjell

    2015-01-01

    Adaptive bitrate (ABR) streaming is widely used for distribution of videos over the internet. In this work, we investigate how well we can predict the quality of such videos using well-known image metrics, information about the bitrate levels, and a relatively simple machine learning method...

  15. Analysis and Design of a Morphing Wing Tip using Multicellular Flexible Matrix Composite Adaptive Skins

    Hinshaw, Tyler

    2009-01-01

    The material presented in this thesis uses concepts of the finite element and doublet panel methods to develop a structural-aerodynamic coupled mathematical model for the analysis of a morphing wing tip composed of smart materials. Much research is currently being performed within many facets of engineering on the use of smart or intelligent materials. Examples of the beneficial characteristics of smart materials might include altering a structureâ s mechanical properties, controlling its dy...

  16. Sensorless control of salient PMSM with adaptive integrator and resistance online identification using strong tracking filter

    Ma, Shaokang; Wu, Peijun; Ji, Jinhu; Li, Xuchun

    2016-02-01

    This article presents a sensorless control approach of salient PMSM with an online parameter identifier. Adaptive Integrator is proposed and utilised for the estimation of active flux and rotor position. As a result, integrator overflow caused by DC offset is avoided. Meanwhile, an online stator resistance identification algorithm using strong tracking filter is employed, and the identified stator resistance is fed back to the estimating algorithm. Thus, the estimating algorithm can calculate the rotor position correctly. Simulations and experimental results validate the feasibility of both adaptive integrator and the parameter identification method.

  17. Automation of Packaging and Material Handling Using Programmable Logic Controller

    Joanna Marie M. Baroro, Melchizedek I. Alipio, Michael Lawrence T. Huang, Teodoro M. Ricamara, Angelo A. Beltran Jr.

    2014-01-01

    This paper presents an automation of packaging and material handling using a programmable logic controller. The idea is to automate the process of placing the materials inside a box, detecting good and bad items in terms of weight, and sealing using a packaging tape. The purpose of the study is to replace the manual system being used in the industry, compare the time, and manpower requirement for both the existing system with the proposed automated system. The ...

  18. REGISTRATION OF BRAIN IMAGES USING MODIFIED ADAPTIVE POLAR TRANSFORM

    D.Sasikala,

    2010-09-01

    Full Text Available Image registration has great significance in medicine, with a lot of techniques anticipated in it. This paper discusses an approach for medical image registration. It registers images of the mono or multi modalities for CT or MRI images using Modified Adaptive Polar Transform. The performance of the Adaptive Polar Transform with theproposed technique is examined. The results prove that the proposed method performs better than Adaptive Polar Transform technique. The proposed method reduces the errors and also the elapsed time for registration. An analysis is presented for the medical image registration of brain images using Adaptive Polar Transform and Modified Adaptive Polar Transform.

  19. Explosion characteristics of pulverised torrefied and raw Norway spruce (Picea abies) and Southern pine (Pinus palustris) in comparison to bituminous coal

    Pre-treatments, such as torrefaction, can improve biomass fuels properties. Dedicated and coal co-firing plants, in which pulverised biomass and torrefied biomass can be used, are exposed to explosion hazards during handling, storage and transport from the mills to the boiler. Data on the explosion characteristics of biomass and torrefied biomass are scarce. This study presents explosion characteristics (maximum explosion pressure, deflagration index and minimum explosible concentration) of two torrefied wood samples and compares their reactivity to that of their corresponding untreated biomass materials and to a sample of Kellingley coal. Torrefied biomass samples showed higher reactivity, overpressures were around 9 bar (0.9 MPa, 1 bar = 105 Pa) for all biomass samples irrespective of size or sample composition. Derived laminar burning velocities ranged between 0.1–0.12 m s−1, and were therefore similar to that of coal (0.12 m s−1). The differences in explosion reactivity influence the design of explosion protection measures and can be used to introduce suitable modifications for safe operations with torrefied biomass. - Highlights: • Explosion characteristics were measured for two torrefied biomass samples. • Properties were compared to those of coal and corresponding untreated biomass. • Maximum explosion overpressures were similar for all biomass at about 9 bar. • Torrefied biomass was more reactive than coal and untreated biomass. • Biomass explosion data can be used to design better safety systems

  20. Measuring yield performance of upland cotton varieties using adaptability, stability and principal component analyses

    Nine upland cotton varieties/strains were tested over 36 environments in Pakistan so as to determine their stability in yield performance. The regression coefficient (b) was used as a measure of adaptability, whereas parameters such as coefficient of determination (r2) and sum of squared deviations from regression (s/sup 2/d) were used as measure of stability. Although the regression coefficients (b) of all varieties did not deviate significantly from the unit slope, the varieties CRIS-5A. BII-89, DNH-40 and Rehmani gave b value closer to unity implying their better adaptation. Lower s/sub 2/d and higher r/sub 2/ of CRIS- 121 and DNH-40 suggest that both of these are fairly stable. The results indicate that, generally, adaptability and stability parameters are independent of each in as much as not all of the parameters simultaneously favoured one variety over the other excepting the variety DNH-40, which was stable based on majority of the parameters. Principal component analysis revealed that the first two components (latent roots) account for about 91.4% of the total variation. The latent vectors of first principal component (PCA1) were smaller and positive which also suggest that most of the varieties were quite adaptive to all of the test environments. (author)

  1. Access and comprehension - Teachers use of simplified language materials

    Rix, Jonathan

    2004-01-01

    This paper examines the current use of simplified language materials (SLMs) by primary and secondary teachers across England. Drawing on a survey of 33 schools the paper examines the degree to which teachers and support teachers currently use simplified language materials and the reasons they give for their usage. It discusses both the contradictions and similarities between teachers' perceptions of the value of SLMs and the existing research base. It focuses on current national guidance, the...

  2. The Vulnerability of Threatened Species: Adaptive Capability and Adaptation Opportunity

    Andrew McVey

    2013-07-01

    Full Text Available Global targets to halt the loss of biodiversity have not been met, and there is now an additional Aichi target for preventing the extinction of known threatened species and improving their conservation status. Climate change increasingly needs to be factored in to these, and thus there is a need to identify the extent to which it could increase species vulnerability. This paper uses the exposure, sensitivity, and adaptive capacity framework to assess the vulnerability of a selection of WWF global priority large mammals and marine species to climate change. However, it divides adaptive capacity into adaptive capability and adaptation opportunity, in order to identify whether adaptation is more constrained by the biology of the species or by its environmental setting. Lack of evidence makes it difficult to apply the framework consistently across the species, but it was found that, particularly for the terrestrial mammals, adaptation opportunities seems to be the greater constraint. This framework and analysis could be used by conservationists and those wishing to enhance the resilience of species to climate change.

  3. Research and development of advanced materials using ion beam

    Namba, Susumu [Nagasaki Inst. of Applied Science, Nagasaki (Japan)

    1997-03-01

    A wide range of research and development activities of advanced material synthesis using ion beams will be discussed, including ion beam applications to the state-of-the-art electronics from giant to nano electronics. (author)

  4. Supervised and Unsupervised Speaker Adaptation Using Confidence Measure

    LIUJia; LIHusheng; LIUJing; LIURunsheng

    2003-01-01

    The speaker adaptation is an effective means of improving the performance of a speech recognition system,and it can be divided into supervised or unsupervised speaker adaptation.In this paper a kind of confidence measure based on the word lattice structure is proposed and is used for the supervised and unsupervised speaker adaptation.The reliability of the recognition results can be evaluated by the confidence measure,and the uncertain parts in the recognition results can be removed or be given smaller weights in the speaker adaptation process.The experiments show that the confidence can effectively eliminate the suspicious speech and improve the performance of the supervised and unsupervised adaptation considerably.The performance difference between the supervised and unsupervised adaptation is reduced by using the confidence measure based on the word lattice structure.

  5. Curriculum-Dependent and Curriculum-Independent Factors in Preservice Elementary Teachers' Adaptation of Science Curriculum Materials for Inquiry-Based Science

    Forbes, Cory T.

    2013-02-01

    In this nested mixed methods study I investigate factors influencing preservice elementary teachers' adaptation of science curriculum materials to better support students' engagement in science as inquiry. Analyses focus on two `reflective teaching assignments' completed by 46 preservice elementary teachers in an undergraduate elementary science methods course in which they were asked to adapt existing science curriculum materials to plan and enact inquiry-based science lessons in elementary classrooms. Data analysis involved regression modeling of artifacts associated with these lessons, as well as in-depth, semester-long case studies of six of these preservice teachers. Results suggest that features of the existing science curriculum materials, including measures of how inquiry-based they were, have a relatively small influence on the preservice teachers' curricular adaptations, while teacher-specific variables account for a much greater percentage of the variance. Evidence from the case studies illustrates the critical impact of the preservice teachers' field placement contexts as an explanatory, teacher-specific factor in their curricular adaptations. These findings have important implications for science teacher educators and science curriculum developers, in terms of not only better understanding how preservice teachers engage with curriculum materials, but also how programmatic features of teacher education programs influence their ability to do so.

  6. Active materials for adaptive architectural envelopes based on plant adaptation principles

    Marlen Lopez; Ramon Rubio; Santiago Martın; Ben Croxford; Richard Jackson

    2015-01-01

    In this paper, the authors present research into adaptive architectural envelopes that adapt to environmental changes using active materials, as a result of application of biomimetic principles from plants to architecture. Buildings use large amounts of energy in order to maintain their internal comfort, because conventional buildings are designed to provide a static design solution. Most of the current solutions for facades are not designed for optimum adaptation to contextual issues and nee...

  7. A Novel Broadband MIMO/OFDM System Using Adaptive Modulation and Adaptive Diversity

    PANYahan; KhaledBenLetaief; CAOZhigang; QIUYonghong

    2005-01-01

    OFDM (Orthogonal frequency division multiplexing) has been widely regarded as an effective modulation technique for mitigating the effects of ISI in a frequency selective fading channel and for providing reliable high-data transmission over wireless links. Adaptive modulation combined with adaptive transmit and receive diversity can achieve further increases in system's capacity and bandwidth efficiency, as well as in QoS improvement in conventional OFDM systems. In this paper, we propose a novel broadband MIMO/OFDM system using adaptive modulation and adaptive transmit and receive diversity. By applying an EVD on each sub-carrier channel matrix, joint optimal transmit and receive antenna weights as well as maximal SNR on each sub-carrier are obtained. Then, by employing adaptive modulation on each sub-carrier, the maximal SNR on each sub-carrier obtained by adaptive transmit and receive diversity is further maximized through adaptive bit assignment and power assignment on each sub-carrier under the constraint of power and overall bit rate. Simulation results show that the proposed system can achieve better performance than an adaptive antenna array based OFDM system without adaptive modulation over multipath fading channels.

  8. Characterization and Mechanical Behavior of Composite Material Using FEA

    S. Irfan Sadaq

    2013-04-01

    Full Text Available Composites have been used extensively in applications such as pipes and pressure vessels. Therefore there is need for furtherstudies on the physical and mechanical properties of these materials. In the present work composite laminates made of gl;ass fiber and epoxy resin are tested to find the strength of the laminate and also its mechanical properties. By using FEA (Ansys 11.0 the optimum helix angle is determined for the composite material

  9. Characterization and Mechanical Behavior of Composite Material Using FEA

    S. Irfan Sadaq; J. Dhanraj Pamar; Dr.N Seetharamaih; Afroz Mehar

    2013-01-01

    Composites have been used extensively in applications such as pipes and pressure vessels. Therefore there is need for furtherstudies on the physical and mechanical properties of these materials. In the present work composite laminates made of gl;ass fiber and epoxy resin are tested to find the strength of the laminate and also its mechanical properties. By using FEA (Ansys 11.0) the optimum helix angle is determined for the composite material

  10. Temperature induced healing in strained bituminous materials observed by atomic force microscopy

    Nahar, S.N.; Schmets, A. J. M.; Scarpas, A.; Schitter, G.

    2013-01-01

    Bitumen is the binder in the composite material named asphalt concrete. Under cyclic mechanical loading of traffic passing over the pavement, eventually damage will initiate in the pavement, leading to eventual structural failure. This damaging process is accelerated by time dependent change of the mechanical properties of asphalt concrete due to ageing mechanisms like oxidation. Bitumen displays spatial heterogeneity at the micrometer scale, which has been observed by atomic force microscopy...