WorldWideScience

Sample records for active hybrid lubrication

  1. Compensation of Cross-Coupling Stiffness and Increase of Direct Damping in Multirecess Journal Bearings using Active Hybrid Lubrication

    Santos, Ilmar; Watanabe, F.Y.

    2004-01-01

    Fluid film forces are generated in hydrostatic journal bearings by two types of lubrication mechanisms: the hydrostatic lubrication in the bearing recesses and hydrodynamic lubrication in the bearing lands, when operating in rotation. The combination of both lubrication mechanisms leads to hybrid...... journal bearings (HJB). When part of hydrostatic pressure is also dynamically modified by means of hydraulic control systems, one refers to the active lubrication. The main contribution of the present theoretical work is to show that it is possible to reduce cross-coupling stiffness and increase the...... direct damping coefficients by means of the active lubrication, what leads to rotor-bearing systems with larger threshold of stability....

  2. Feasibility of Influencing the Dynamic Fluid Film Coefficients of a Multirecess Journal Bearing by means of Active Hybrid Lubrication

    Santos, Ilmar; Watanabe, F. Y.

    2003-01-01

    The main objective of this research project is the investigation of multirecess hydrostatic journal bearings with active hybrid (hydrostatic and hydrodynamic) lubrication. This paper gives a theoretical contribution to the modeling of this kind of bearing, combining computational fluid dynamics a...... significant modifications of active hybrid forces, which can be useful while reducing vibration and stabilizing rotating machines.......The main objective of this research project is the investigation of multirecess hydrostatic journal bearings with active hybrid (hydrostatic and hydrodynamic) lubrication. This paper gives a theoretical contribution to the modeling of this kind of bearing, combining computational fluid dynamics and...

  3. Graphite and Hybrid Nanomaterials as Lubricant Additives

    Zhenyu J. Zhang

    2014-04-01

    Full Text Available Lubricant additives, based on inorganic nanoparticles coated with organic outer layer, can reduce wear and increase load-carrying capacity of base oil remarkably, indicating the great potential of hybrid nanoparticles as anti-wear and extreme-pressure additives with excellent levels of performance. The organic part in the hybrid materials improves their flexibility and stability, while the inorganic part is responsible for hardness. The relationship between the design parameters of the organic coatings, such as molecular architecture and the lubrication performance, however, remains to be fully elucidated. A survey of current understanding of hybrid nanoparticles as lubricant additives is presented in this review.

  4. Nanoscale Organic−Inorganic Hybrid Lubricants

    Kim, Daniel

    2011-03-15

    Silica (SiO2) nanoparticles densely grafted with amphiphilic organic chains are used to create a family of organic-inorganic hybrid lubricants. Short sulfonate-functionalized alkylaryl chains covalently tethered to the particles form a dense corona brush that stabilizes them against aggregation. When these hybrid particles are dispersed in poly-α-olefin (PAO) oligomers, they form homogeneous nanocomposite fluids at both low and high particle loadings. By varying the volume fraction of the SiO2 nanostructures in the PAO nanocomposites, we show that exceptionally stable hybrid lubricants can be created and that their mechanical properties can be tuned to span the spectrum from simple liquids to complex gels. We further show that these hybrid lubricants simultaneously exhibit lower interfacial friction coefficients, enhanced wear and mechanical properties, and superior thermal stability in comparison with either PAO or its nanocomposites created at low nanoparticle loadings. Profilometry and energy dispersive X-ray spectroscopic analysis of the wear track show that the enhanced wear characteristics in PAO-SiO2 composite lubricants originate from two sources: localization of the SiO2 particles into the wear track and extension of the elastohydrodynamic lubrication regime to Sommerfeld numbers more than an order of magnitude larger than for PAO. © 2011 American Chemical Society.

  5. From Hybrid to Actively-Controlled Gas Lubricated Bearings – Theory and Experiment

    Morosi, Stefano

    bearings, tilting pad and flexure pivot gas bearings. These solutions proved to be effective in improving static and dynamic properties of the bearings, however issues related to the manufacturing and accuracy of predictions has so far limited their applications. Another drawback is that passive bearings...... determined by the appearance of subsynchronous whirl instability. In fact, postponing the onset speed of instability poses one of the greatest challenges in high-speed gas bearing design. A great deal of research is devoted to attack such issues, where most propose passive designs such as compliant foil...... offer a low degree of robustness, meaning that an accurate optimization is necessary for each application. Another way of improving gas bearings operation performance is by using active control systems, transforming conventional gas bearings in an electro-mechanical machine component. In this framework...

  6. Three Types of Active Lubrication Systems for the Main Bearings of Reciprocating Machines

    Santos, Ilmar; Pulido, E. E.

    2010-01-01

    In the paper the authors investigate three different schemes for the realization of the controllable oil injection system to be couple to the main engine bearings. The use of active lubrication in fluid film bearings helps to enhance the hydrodynamic fluid film by increasing the fluid film...... engine, where the conventional lubrication of the main bearing is modified by applying radial oil injection. The performance of such a hybrid bearing is compared to an equivalent conventional lubricated bearing in terms of the maximum fluid film pressures, minimum fluid film thicknesses and reduction of...... thickness and consequently reducing viscous friction losses and vibrations. One refers to active lubrication when conventional hydrodynamic lubrication is combined with dynamically modified hydrostatic lubrication. In this case, the hydrostatic lubrication is modified by injecting oil at controllable...

  7. Schemes for applying active lubrication to main engine bearings

    Estupinan, Edgar Alberto; Santos, Ilmar

    2009-01-01

    The work presented here is a theoretical study that describes two different schemes for the oil injection system in actively lubricated main engine bearings. The use of active lubrication in journal bearings helps to enhance the hydrodynamic fluid film by increasing the fluid film thickness and...... orifices circumferentially located around the bearing surface. The pressure distribution of the hydrodynamic fluid film in journal bearings is governed by the Reynolds equation, which is modified to accommodate the dynamics of active lubrication, and which can be numerically solved using finite...... consequently reducing viscous friction losses and vibrations. One refers to active lubrication when conventional hydrodynamic lubrication is combined with dynamically modified hydrostatic lubrication. In this case, the hydrostatic lubrication is modified by injecting oil at controllable pressures, through...

  8. Performance of High-Speed Grease Lubricated Hybrid Ceramic Ball Bearing

    李秀娟; 王黎钦; 古乐

    2004-01-01

    To simplify the lubricating system for high-speed bearings and improve its reliability, grease lubricated high-speed hybrid ceramic bearings were theoretically and experimentally researched.Bearings with an outer race of 62 mm and eleven 9.525-mm balls were investigated.Traction coefficient and flash temperature between the bearing races and the balls were calculated and the results show that the traction coefficient of Si3N4 hybrid ceramic bearings is 74% that of the steel AISI 440B ones at 30 000 r/min and 1750 N, and the flash temperature of the hybrid bearings is 49% that of steel ones.Simulating the high-speed bearing rotational conditions, the grease lubricated hybrid ceramic ball bearings were tested and the results show that the power consumption of hybrid ceramic bearing lubricated by grease D at 24 000 r/min and axial load 1750 N is 80% that of steel ones.

  9. Chemical modification of hybrid nanostructures (POSS for application as lubricant

    Caroline Luvison

    2014-08-01

    Full Text Available Polyhedral oligomeric silsesquioxanes (POSS are hybrid structures type RSiO15n, with n organic groups R. These molecules can be easily functionalized by simply changing the chemical constitution of the organic groups. In this work, chemical modification of POSS-NH2 was performed by amidation reaction with butyric acid at elevated temperature, 160°C. The formation of the amide group is evinced by the appearance of NH angular deformation band at 1540 cm-1 in the FTIR spectra. Approximately 40% of the amino groups reacted, according to titration results. The formation of the amide groups resulted in a shift of the glass transition temperature (Tg from -36.9°C to -25.6°C for the modified-POSS sample. Both POSS-NH2 and modified-POSS samples exhibited similar thermal degradation pattern. Analysis of the pairs distribution function (PDF has determined that the hybrid nanoparticles are separated by a periodic distance of approximately 1.32 nm. POSS-NH2 and modified-POSS exhibit newtonian behavior, which will range from 10-1 s-1 and 1000 s-1. The viscosity decreased with increasing temperature, a typical behavior of liquid lubricants.

  10. Stability analysis of slot-entry hybrid journal bearings operating with non-newtonian lubricant

    H.C. Garg

    2015-09-01

    Full Text Available This paper presents theoretical investigations of rheological effects of lubricant on stability parameters of various configurations of slot-entry hybrid journal bearing system. FEM has been used to solve Reynolds equation governing flow of lubricant in bearing clearance space along with restrictor flow equation using suitable iterative technique. The non-Newtonian lubricant has been assumed to follow cubic shear stress law. The stability parameters in terms of stiffness coefficients, damping coefficients, threshold speed and whirl frequency of different configurations of slot-entry hybrid journal bearing have been computed and presented for wide range of external load while operating with Newtonian and Non-Newtonian lubricants. The computed results reveal that variation of viscosity due to non-Newtonian behavior of lubricant affects bearing stability quite significantly. The results are presented in graphical form and logical conclusions are drawn to identify best possible configuration from stability point of view.

  11. Experimental Identification of Dynamic Coefficients of Tilting-Pad Bearings with Active Lubrication

    Salazar, Jorge Andrés González; Cerda Varela, Alejandro Javier; Santos, Ilmar

    supply unit, b) servovalves, c) radial injection nozzles, d) displacement sensors and e) well-tuned digital controllers which turn the bearing static and dynamic properties controllable. A scaled-down industrial rotor, composed by a flexible rotor supported by a four rocker LBP tilting-pad journal......This article presents the experimental identification of the equivalent dynamic coefficients of an activelylubricated bearing under different lubrication regimes, namely: passive (no injection flow), hybrid (constant injection flow) and feedback-controlled (variable injection flow) lubrication. The...... bearing featuring active lubrication under light load conditions, is used for such a goal. The experimental identification is performed in the frequency domain by means of the measured FRFs and a finite element model of the rotor. The comparison between results under the different lubrication regimes...

  12. Load-Induced Confinement Activates Diamond Lubrication by Water

    Zilibotti, G.; Corni, S.; Righi, M. C.

    2013-10-01

    Tribochemical reactions are chemical processes, usually involving lubricant or environment molecules, activated at the interface between two solids in relative motion. They are difficult to be monitored in situ, which leaves a gap in the atomistic understanding required for their control. Here we report the real-time atomistic description of the tribochemical reactions occurring at the interface between two diamond films in relative motion, by means of large scale ab initio molecular dynamics. We show that the load-induced confinement is able to catalyze diamond passivation by water dissociative adsorption. Such passivation decreases the energy of the contacting surfaces and increases their electronic repulsion. At sufficiently high coverages, the latter prevents surface sealing, thus lowering friction. Our findings elucidate effects of the nanoscale confinement on reaction kinetics and surface thermodynamics, which are important for the design of new lubricants.

  13. Calculation of flash temperature for hybrid ceramic ball bearing lubricated with solid

    李秀娟; 王黎钦; 古乐; 齐毓霖

    2002-01-01

    The scuffing behavior of hybrid ceramic bearing lubricated with solid is greatly affected by the contact flash temperature. Formulas are dedused using Lee' s asperity flash temperature method, to calculate the flash temperature of ball bearing lubricated with solid. The maximum flash temperature is calculated for hybrid ceramic ball bearings. The results show that under given conditions, the flash temperature of inner race is higher than that of outer race, the flash temperature of the hybrid ceramic bearing is sensitive to the load, rotational speed and race curvature. The flash temperature of inner race at 20 000 r/min is 66.9% more than that that at 11 000 r/min, and with the load changing from 1.1 kN to 2 kN, the flash temperature inner race goes up to 165.7%. Very common for high speed ball bearings, when curvature coefficients of both inner and outer race change from 0. 515 to 0.56, the inner race flash temperature decreases from 421. 446℃ to 56.2℃.

  14. Actively lubricated bearings applied as calibrated shakers to aid parameter identification in rotordynamics

    Santos, Ilmar; Cerda Varela, Alejandro Javier

    2013-01-01

    between hydrodynamic, hydrostatic and controllable lubrication regimes, can be used either to control or to excite rotor lateral vibrations. An accurate characterization of the active oil film forces is of fundamental importance to elucidate the feasibility of applying the active lubrication as non......-invasive perturbation forces, or in other words, as a "calibrated shaker", to perform in-situ rotordynamic tests. The main original contributions of this paper are three: a) the experimental characterization of the active fluid film forces generated in an actively-lubricated tilting-pad journal bearing in the frequency...... systems; c) experimental indication of how small such active fluid film forces (perturbation forces) should be, in order to perturb the rotor-journal bearing system without significantly changing its dynamic characteristics. To validate the experimental procedure and results obtained via actively-lubricated...

  15. Feasibility of Applying Active Lubrication to Dynamically Loaded Fluid Film Bearings

    Estupinan, Edgar Alberto; Santos, Ilmar

    2009-01-01

    The feasibility of modifying the dynamics of the thin fluid films of dynamically loaded journal bearings, using different strategies of active lubrication is studied in this work. A significant reduction in the vibration levels, wear and power friction losses, is expected. Particularly, the focus...... of this study is on the analysis of main crankshaft bearings, where the conventional hydrodynamic lubrication is modified by injecting oil at actively controllable pressures, through orifices circumferentially located along the bearing surface....

  16. Experimental Study on the Dynamic Performance of a New High-Speed Spindle Supported by Water-Lubricated Hybrid Bearings

    Lin Wang; Hua Xu

    2016-01-01

    The dynamic performance of a new high-speed spindle supported by water-lubricated hybrid bearings is experimentally studied on a test rig. The present design allows the speed of the spindle up to 30,000 rpm, with a bearing internal diameter of 40 mm, which makes it possible to simulate many actual machining processes. Some experiments have been presented to study the mechanical and thermal behaviors of the spindle and its supporting hybrid bearings. The maximum temperature rise is less than 1...

  17. Linear and Non-Linear Control Techniques Applied to Actively Lubricated Journal Bearings

    Nicoletti, Rodrigo; Santos, Ilmar

    2003-01-01

    The main objectives of actively lubricated bearings are the simultaneous reduction of wear and vibration between rotating and stationary machinery parts. For reducing wear and dissipating vibration energy until certain limits, one can count with the conventional hydrodynamic lubrication....... For further reduction of shaft vibrations one can count with the active lubrication action, which is based on injecting pressurised oil into the bearing gap through orifices machined in the bearing sliding surface. The design and efficiency of some linear (PD, PI and PID) and non-linear controllers, applied...... vibration reduction of unbalance response of a rigid rotor, where the PD and the non-linear P controllers show better performance for the frequency range of study (0 to 80 Hz). The feasibility of eliminating rotor-bearing instabilities (phenomena of whirl) by using active lubrication is also investigated...

  18. Lubrication fundamentals

    Pirro, DM

    2001-01-01

    This work discusses product basics, machine elements that require lubrication, methods of application, lubricant storage and handling, and lubricant conservation. This edition emphasizes the need for lubrication and careful lubricant selection.

  19. Is wetter better? An evaluation of over-the-counter personal lubricants for safety and anti-HIV-1 activity.

    Dezzutti, Charlene S; Brown, Elizabeth R; Moncla, Bernard; Russo, Julie; Cost, Marilyn; Wang, Lin; Uranker, Kevin; Kunjara Na Ayudhya, Ratiya P; Pryke, Kara; Pickett, Jim; Leblanc, Marc-André; Rohan, Lisa C

    2012-01-01

    Because lubricants may decrease trauma during coitus, it is hypothesized that they could aid in the prevention of HIV acquisition. Therefore, safety and anti-HIV-1 activity of over-the-counter (OTC) aqueous- (n = 10), lipid- (n = 2), and silicone-based (n = 2) products were tested. The rheological properties of the lipid-based lubricants precluded testing with the exception of explant safety testing. Six aqueous-based gels were hyperosmolar, two were nearly iso-osmolar, and two were hypo-osmolar. Evaluation of the panel of products showed Gynol II (a spermicidal gel containing 2% nonoxynol-9), KY Jelly, and Replens were toxic to Lactobacillus. Two nearly iso-osmolar aqueous- and both silicone-based gels were not toxic toward epithelial cell lines or ectocervical or colorectal explant tissues. Hyperosmolar lubricants demonstrated reduction of tissue viability and epithelial fracture/sloughing while the nearly iso-osmolar and silicon-based lubricants showed no significant changes in tissue viability or epithelial modifications. While most of the lubricants had no measurable anti-HIV-1 activity, three lubricants which retained cell viability did demonstrate modest anti-HIV-1 activity in vitro. To determine if this would result in protection of mucosal tissue or conversely determine if the epithelial damage associated with the hyperosmolar lubricants increased HIV-1 infection ex vivo, ectocervical tissue was exposed to selected lubricants and then challenged with HIV-1. None of the lubricants that had a moderate to high therapeutic index protected the mucosal tissue. These results show hyperosmolar lubricant gels were associated with cellular toxicity and epithelial damage while showing no anti-viral activity. The two iso-osmolar lubricants, Good Clean Love and PRÉ, and both silicone-based lubricants, Female Condom 2 lubricant and Wet Platinum, were the safest in our testing algorithm. PMID:23144863

  20. Is wetter better? An evaluation of over-the-counter personal lubricants for safety and anti-HIV-1 activity.

    Charlene S Dezzutti

    Full Text Available Because lubricants may decrease trauma during coitus, it is hypothesized that they could aid in the prevention of HIV acquisition. Therefore, safety and anti-HIV-1 activity of over-the-counter (OTC aqueous- (n = 10, lipid- (n = 2, and silicone-based (n = 2 products were tested. The rheological properties of the lipid-based lubricants precluded testing with the exception of explant safety testing. Six aqueous-based gels were hyperosmolar, two were nearly iso-osmolar, and two were hypo-osmolar. Evaluation of the panel of products showed Gynol II (a spermicidal gel containing 2% nonoxynol-9, KY Jelly, and Replens were toxic to Lactobacillus. Two nearly iso-osmolar aqueous- and both silicone-based gels were not toxic toward epithelial cell lines or ectocervical or colorectal explant tissues. Hyperosmolar lubricants demonstrated reduction of tissue viability and epithelial fracture/sloughing while the nearly iso-osmolar and silicon-based lubricants showed no significant changes in tissue viability or epithelial modifications. While most of the lubricants had no measurable anti-HIV-1 activity, three lubricants which retained cell viability did demonstrate modest anti-HIV-1 activity in vitro. To determine if this would result in protection of mucosal tissue or conversely determine if the epithelial damage associated with the hyperosmolar lubricants increased HIV-1 infection ex vivo, ectocervical tissue was exposed to selected lubricants and then challenged with HIV-1. None of the lubricants that had a moderate to high therapeutic index protected the mucosal tissue. These results show hyperosmolar lubricant gels were associated with cellular toxicity and epithelial damage while showing no anti-viral activity. The two iso-osmolar lubricants, Good Clean Love and PRÉ, and both silicone-based lubricants, Female Condom 2 lubricant and Wet Platinum, were the safest in our testing algorithm.

  1. Experimental Study on the Dynamic Performance of a New High-Speed Spindle Supported by Water-Lubricated Hybrid Bearings

    Lin Wang

    2016-01-01

    Full Text Available The dynamic performance of a new high-speed spindle supported by water-lubricated hybrid bearings is experimentally studied on a test rig. The present design allows the speed of the spindle up to 30,000 rpm, with a bearing internal diameter of 40 mm, which makes it possible to simulate many actual machining processes. Some experiments have been presented to study the mechanical and thermal behaviors of the spindle and its supporting hybrid bearings. The maximum temperature rise is less than 15°C with a speed of 30,000 rpm and a water supply pressure of 2.5 MPa. The spindle radial run-out of the rotational frequency is about 1 µm. Stability of the spindle system has been improved. The experimental results indicate that water-lubricated hybrid bearings are valuable choices to replace ceramic bearings and air bearings as support for spindles under high-speed, high-precision, and heavy-load machining conditions.

  2. Feasibility of Applying Active Lubrication to Reduce Vibration in Industrial Compressors

    Santos, Ilmar; Nicoletti, Rodrigo; Scalabrin, A.

    2004-01-01

    the orifices distributed over the sliding surface. The dynamic coefficients of tilting-pad bearings with and without active lubrication and their influence on an industrial compressor of 391 Kg, which operates with a maximum speed of 10,200 rpm, are analyzed. In the original compressor design, the...... bearing housings are mounted on squeeze-film dampers in order to ensure reasonable stability margins during full load condition (high maximum continuous speed). Instead of having a combination of tilting-pad bearings and squeeze-film dampers, another design solution is proposed and theoretically......In this paper the complete set of modified Reynolds´ equations for the active lubrication is presented. The solution of such a set of equations allows the determination of stiffness and damping coefficients of actively lubricated bearings. These coefficients are not just dependent on Sommerfeld...

  3. Frequency Response Analysis of an Actively Lubricated Rotor/Tilting-Pad Bearing System

    Nicoletti, Rodrigo; Santos, Ilmar

    2005-01-01

    In the present paper the dynamic response of a rotor supported by an active lubricated tilting-pad bearing is investigated in the frequency domain. The theoretical part of the investigation is based on a mathematical model obtained by means of rigid body dynamics. The oil film forces are inserted...... active lubricated tilting-pad bearing. By applying a simple proportional controller it is possible to reach 30% reduction of the resonance peak associated with the first rigid body mode shape of the system. One of the most important consequences of such a vibration reduction in rotating machines is the...

  4. Linear and Non-Linear Control Techniques Applied to Actively Lubricated Journal Bearings

    Nicoletti, Rodrigo; Santos, Ilmar

    2003-01-01

    The main objectives of actively lubricated bearings are the simultaneous reduction of wear and vibration between rotating and stationary machinery parts. For reducing wear and dissipating vibration energy until certain limits, one can count with the conventional hydrodynamic lubrication. For...... further reduction of shaft vibrations one can count with the active lubrication action, which is based on injecting pressurised oil into the bearing gap through orifices machined in the bearing sliding surface. The design and efficiency of some linear (PD, PI and PID) and non-linear controllers, applied...... to a tilting-pad journal bearing, are analysed and discussed. Important conclusions about the application of integral controllers, responsible for changing the rotor-bearing equilibrium position and consequently the "passive" oil film damping coefficients, are achieved. Numerical results show an...

  5. Reducing Friction and Wear of Tribological Systems through Hybrid Tribofilm Consisting of Coating and Lubricants

    Shuichiro Yazawa

    2014-06-01

    Full Text Available The role of surface protective additives becomes vital when operating conditions become severe and moving components operate in a boundary lubrication regime. After protecting film is slowly removed by rubbing, it can regenerate through the tribochemical reaction of the additives at the contact. However, there are limitations about the regeneration of the protecting film when additives are totally consumed. On the other hand, there are a lot of hard coatings to protect the steel surface from wear. These can enable the functioning of tribological systems, even in adverse lubrication conditions. However, hard coatings usually make the friction coefficient higher, because of their high interfacial shear strength. Amongst hard coatings, diamond-like carbon (DLC is widely used, because of its relatively low friction and superior wear resistance. In practice, conventional lubricants that are essentially formulated for a steel/steel surface are still used for lubricating machine component surfaces provided with protective coatings, such as DLCs, despite the fact that the surface properties of coatings are quite different from those of steel. It is therefore important that the design of additive molecules and their interaction with coatings should be re-considered. The main aim of this paper is to discuss the DLC and the additive combination that enable tribofilm formation and effective lubrication of tribological systems.

  6. Frequency Response Analysis of an Actively Lubricated Rotor/Tilting-Pad Bearing System

    Nicoletti, Rodrigo; Santos, Ilmar

    2004-01-01

    In the present paper, the dynamic response of a rotor supported by an active lubricated tilting-pad bearing is investigated in the frequency domain. The theoretical part of the investigation is based on a mathematical model obtained by means of rigid body dynamics. The oil film forces are inserted...... lubricated tilting-pad bearing. By applying a simple proportional controller, it is possible to reach 30% reduction of the resonance peak associated with the first rigid body mode shape of the system. One of the most important consequences of such a vibration reduction in rotating machines is the feasibility...

  7. Active Lubrication: Feasibility and Limitations on Reducing Vibration in Rotating Machinery

    Nicoletti, Rodrigo; Santos, Ilmar

    2003-01-01

    In the present work, experimental results show the feasibility of reducing the amplitude of resonance peaks in rotor-bearing test rig, in the frequency domain, by using active lubricated bearings. The most important consequence of this vibration reduction in rotating machines is the feasibility o...

  8. Active Lubrication: Feasibility and Limitations on Reducing Vibration in Rotating Machinery

    Nicoletti, Rodrigo; Santos, Ilmar

    2004-01-01

    In the present work, experimental results show the feasibility of reducing the amplitude of resonance peaks in rotor-bearing test rig, in the frequency domain, by using active lubricated bearings. The most important consequence of this vibration reduction in rotating machines is the feasibility o...

  9. Investigation of microstructure and mechanical properties of aluminum hybrid nano-composites with the additions of solid lubricant

    Highlights: • Aluminium hybrid nano-composite was made by mechanical alloying successfully. • High energy ball milling resulted in homogeneous distribution of reinforcements. • MA combined with pressing allowed to produce nano-crystalline matrix composites. • Hybrid nano-composites exhibited the best mechanical properties. • Wear resistance of the aluminum hybrid nano-composites found increased with increased filler content. - Abstract: In this experimental study, the tribological behavior of Al 2024–5 wt.% SiC–X wt.% graphite (X = 5 and 10) hybrid nano-composites was produced using powder metallurgy (P/M) technique. All specimens were prepared by mechanical milling of Al 2024 and SiC–Gr nano-composite powders, followed by a blend–press–sinter methodology. Pin on disc type apparatus has been used for determining the wear loss. The sintered samples have been characterized by XRD. Wear mechanisms are discussed based on scanning electron microscopy observations of worn surface and wear debris morphology. The hardness and wear resistance of the hybrid nano-composites were increased considerably by increasing the reinforcement content. The nano-composite with 5 wt.% SiC and 10 wt.% Gr showed the greatest improvement in tribological performance. Primary wear mechanisms for hybrid nano-composites were determined to be formation of lubricating layer on the surface of samples. The overall results revealed that hybrid aluminium nano-composites can be considered as an outstanding material where high strength and wear-resistant components are of major importance, particularly structural applications in the aerospace, automotive and military industries

  10. Frequency Response Analysis of an Actively Lubricated Rotor/Tilting-Pad Bearing System

    Nicoletti, Rodrigo; Santos, Ilmar

    In the present paper, the dynamic response of a rotor supported by an active lubricated tilting-pad bearing is investigated in the frequency domain. The theoretical part of the investigation is based on a mathematical model obtained by means of rigid body dynamics. The oil film forces are inserted...... into the model by using two different approaches: (a) linearized active oil film forces and the assumption that the hydrodynamic forces and the active hydraulic forces can be decoupled; (b) equivalent dynamic coefficients of the active oil film and the solution of the modified Reynolds' equation for...... the active lubrication. The second approach based on the equivalent dynamic coefficients leads to more accurate results since it includes the frequency dependence of the active hydraulic forces. Theoretical and experimental results reveal the feasibility of reducing resonance peaks by using the active...

  11. Linear and non-linear control techniques applied to actively lubricated journal bearings

    Nicoletti, R.; Santos, I. F.

    2003-03-01

    The main objectives of actively lubricated bearings are the simultaneous reduction of wear and vibration between rotating and stationary machinery parts. For reducing wear and dissipating vibration energy until certain limits, one can use the conventional hydrodynamic lubrication. For further reduction of shaft vibrations one can use the active lubrication action, which is based on injecting pressurized oil into the bearing gap through orifices machined in the bearing sliding surface. The design and efficiency of some linear (PD, PI and PID) and a non-linear controller, applied to a tilting-pad journal bearing, are analysed and discussed. Important conclusions about the application of integral controllers, responsible for changing the rotor-bearing equilibrium position and consequently the "passive" oil film damping coefficients, are achieved. Numerical results show an effective vibration reduction of unbalance response of a rigid rotor, where the PD and the non-linear P controllers show better performance for the frequency range of study (0-80 Hz). The feasibility of eliminating rotor-bearing instabilities (phenomena of whirl) by using active lubrication is also investigated, illustrating clearly one of its most promising applications.

  12. Lubrication fundamentals

    This book is organized under the following headings: lubricating oils; lubricating greases; synthetic lubricants; machine elements; lubricant application; internal combustion engines; stationary gas turbines; steam turbines; hydraulic turbines; nuclear power plants; automotive chassis components; automotive power transmissions; compressors; handling, storing, and dispensing lubricants, in-plant handling for lubricant conservation

  13. Reducing Friction and Wear of Tribological Systems through Hybrid Tribofilm Consisting of Coating and Lubricants

    Shuichiro Yazawa; Ichiro Minami; Braham Prakash

    2014-01-01

    The role of surface protective additives becomes vital when operating conditions become severe and moving components operate in a boundary lubrication regime. After protecting film is slowly removed by rubbing, it can regenerate through the tribochemical reaction of the additives at the contact. However, there are limitations about the regeneration of the protecting film when additives are totally consumed. On the other hand, there are a lot of hard coatings to protect the steel surface from ...

  14. Lubricants and lubrication

    Mang, T.; Dresel, W. [eds.] [Fuchs Petrolub AG, Mannheim (Germany)

    2001-07-01

    The use of lubricants is as old as mankind but the scientific analysis of lubrication, friction and wear, as an aspect of tribology is relatively new. Only recently have lubricants begun to be viewed as functional elements in engineering and this group of substances is also receiving increased attention from engineers. This book provides chemists and engineers with a clear interdisciplinary introduction and orientation to all major lubricant applications, focusing not only on the various products but also on specific application engineering criteria. (orig.)

  15. Exploring integral controllers in actively-lubricated tilting-pad journal bearings

    Salazar, Jorge Andrés González; Santos, Ilmar

    2015-01-01

    Active tilting-pad journal bearings with radial oil injection combine good stability properties of conventional tilting-pad journal bearings with the capability of improving their dynamic properties even more by control techniques. The main contribution of this work is the experimental...... investigation of integral controllers for feedback-controlled lubrication with the aim of: a) presetting the static journal center and consequently exploring the changes of bearing dynamic properties; b) obtaining an integral controller capable of re-positioning the static journal eccentricity for matching...... equilibria under conventional hydrodynamic and feedback-controlled lubrication regimes. A novel application is proposed, that tries to build non-invasive perturbation forces and uses the active fluid film forces of the bearing as a calibrated shaker....

  16. Active lubrication applied to radial gas journal bearings. Part 2: Modelling improvement and experimental validation

    Pierart, Fabián G.; Santos, Ilmar F.

    2016-01-01

    Actively-controlled lubrication techniques are applied to radial gas bearings aiming at enhancing one of their most critical drawbacks, their lack of damping. A model-based control design approach is presented using simple feedback control laws, i.e. proportional controllers. The design approach...... combines three main domains: tribology, dynamics and control. The Reynolds equation with radial injection, including piezoelectrically controlled jet, describes the non-linear interaction between bearing surface and rotating shaft. Dynamics of the flexible shaft and rotating parts are modelled aid by...... finite element method and the global model is used as control design tool. Active lubrication allows for significant increase in damping factor of the rotor-bearing system. Very good agreement between theory and experiment is obtained, supporting the multi-physic design tool developed....

  17. Active lubrication applied to internal combustion engines - evaluation of control strategies

    Estupinan, Edgar Alberto; Santos, Ilmar

    2009-01-01

    The performance of fluid film bearings in a combustion engine affects key functions such as durability, noise and vibration. Therefore, this work evaluates different control strategies for applying active radial oil injection in the main bearings of internal combustion engines with the aim of...... reducing friction losses and vibrations between the crankshaft and the bearings. The conventional hydrodynamic lubrication is combined with hydrostatic lubrication which is actively modified by radially injecting oil at controllable pressures, through orifices circumferentially located around the bearing...... surface. The behaviour of a main bearing of a medium size combustion engine, operating with radial oil injection and with four different control strategies is analyzed, giving some insights into the minimum fluid film thickness, maximum fluid film pressure, friction losses and maximum vibration levels...

  18. Improvement of Dynamic Performance of Hybrid Gas Bearings via Adjustable Lubrication

    Pierart Vásquez, Fabián Gonzalo; Santos, Ilmar

    2013-01-01

    and the pressure and velocity fields in the injection nozzle are compared. The simplified theoretical model has been validated against the CFD results and experimentally using a test rig. The test rig consists of a flexible rotor supported by a ball bearing and a controllable hybrid gas bearing. The results show...

  19. Actively lubricated bearings applied as calibrated shakers to aid parameter identification in rotordynamics

    Santos, Ilmar; Cerda Varela, Alejandro Javier

    2013-01-01

    -invasive perturbation forces, or in other words, as a "calibrated shaker", to perform in-situ rotordynamic tests. The main original contributions of this paper are three: a) the experimental characterization of the active fluid film forces generated in an actively-lubricated tilting-pad journal bearing in the frequency......The servo valve input signal and the radial injection pressure are the two main parameters responsible for dynamically modifying the journal oil film pressure and generating active fluid film forces in controllable fluid film bearings. Such fluid film forces, resulting from a strong coupling...... domain and the application of such a controllable bearing as a calibrated shaker aiming at determining the frequency response function (FRF) of rotordynamic systems; b) experimental quantification of the influence of the supply pressure and servo valve input signal on the FRF of rotor-journal bearing...

  20. Comparative evaluation of tableting compression behaviors by methods of internal and external lubricant addition: Inhibition of enzymatic activity of trypsin preparation by using external lubricant addition during the tableting compression process

    Otsuka, Makoto; Sato, Mitsuyo; Matsuda, Yoshihisa

    2001-01-01

    This study evaluated tableting compression by using internal and external lubricant addition. The effect of lubricant addition on the enzymatic activity of trypsin, which was used as a model drug during the tableting compression process, was also investigated. The powder mixture (2% crystalline trypsin, 58% crystalline lactose, and 40% microcrystalline cellulose) was kneaded with 5% hydroxypropyl cellulose aqueous solution and then granulated using an extruding granulator equipped with a 0.5-...

  1. DSP Control of Line Hybrid Active Filter

    Dan, Stan George; Benjamin, Doniga Daniel; Magureanu, R.;

    2005-01-01

    Active Power Filters have been intensively explored in the past decade. Hybrid active filters inherit the efficiency of passive filters and the improved performance of active filters, and thus constitute a viable improved approach for harmonic compensation. In this paper a parallel hybrid filter...... is studied for current harmonic compensation. The hybrid filter is formed by a single tuned Le filter and a small-rated power active filter, which are directly connected in series without any matching transformer. Thus the required rating of the active filter is much smaller than a conventional standalone...... active filter. Simulation and experimental results obtained in laboratory confirmed the validity and effectiveness of the control....

  2. Is Wetter Better? An Evaluation of Over-the-Counter Personal Lubricants for Safety and Anti-HIV-1 Activity

    Dezzutti, Charlene S.; Brown, Elizabeth R.; Bernard Moncla; Julie Russo; Marilyn Cost; Lin Wang; Kevin Uranker; Kunjara Na Ayudhya, Ratiya P.; Kara Pryke; Jim Pickett; Marc-André Leblanc; Rohan, Lisa C.

    2012-01-01

    Because lubricants may decrease trauma during coitus, it is hypothesized that they could aid in the prevention of HIV acquisition. Therefore, safety and anti-HIV-1 activity of over-the-counter (OTC) aqueous- (n = 10), lipid- (n = 2), and silicone-based (n = 2) products were tested. The rheological properties of the lipid-based lubricants precluded testing with the exception of explant safety testing. Six aqueous-based gels were hyperosmolar, two were nearly iso-osmolar, and two were hypo-osmo...

  3. Adjustable ETHD lubrication applied to the improvement of dynamic performance of flexible rotors supported by active TPJB

    Salazar, Jorge Andrés González; Cerda Varela, Alejandro Javier; Santos, Ilmar

    2013-01-01

    pressurized oil directly into the bearing clearance through a nozzle placed in a radial bore at the middle of the pad and connected to a high pressure supply unit by servovalves. The theoretical model is based on a finite element model, where the active TPJB with adjustable lubrication is included using...

  4. Tilting-Pad Journal Bearings with Active Lubrication Applied as Calibrated Shakers: Theory and Experiment

    Cerda Varela, Alejandro Javier; Santos, Ilmar

    2014-01-01

    In recent years, a continuous research effort has transformed the conventional tilting-pad journal bearing into a mechatronic machine element. The addition of electromechanical elements provides the possibility of generating controllable forces over the rotor as a function of a suitable control...... dependent calibration function, i.e. the transfer function between control signal and force over the rotor. This work presents a theoretical model of the calibration function for a tilting-pad journal bearing with active lubrication. The bearing generates controllable forces by injecting pressurized oil...... signal. Such forces can be applied in order to perform parameter identification procedures in-situ, which enables evaluation of the mechanical condition of the machine in a non-invasive way. The usage of a controllable bearing as a calibrated shaker requires obtaining the bearing specific frequency...

  5. Active Lubrication for Reducing Wear and Vibration: A combination of Fluid Power Control and Tribology

    Nicoletti, Rodrigo; Santos, Ilmar

    2002-01-01

    The use of fluid power to reduce and control rotor vibration in rotating machines is investigated. An active hybrid bearing is studied, whose main objective is to reduce wear and vibration between rotating and stationary machinery parts. By injecting pressurised oil into the oil film, through...

  6. Lubrication background

    Hamrock, B. J.; Dowson, D.

    1981-01-01

    Surface topography, including the various physical methods of measuring surfaces, and the various lubrication regimes (hydrodynamic, elastohydrodynamic, boundary, and mixed) are discussed. The historical development of elastohydrodynamic lubrication is outlined. The major accomplishments in four periods, the pre-1950's, the 1950's, the 1960's, and the 1970's are presented.

  7. Lubrication a practical guide to lubricant selection

    Lansdown, A R

    1982-01-01

    Lubrication: A Practical Guide to Lubricant Selection provides a guide to modern lubrication practice in industry, with emphasis on practical application, selection of lubricants, and significant factors that determine suitability of a lubricant for a specific application. Organized into 13 chapters, this book begins with a brief theoretical opening chapter on the basic principles of lubrication. A chapter then explains the choice of lubricant type, indicating how to decide whether to use oil, grease, dry lubricant, or gas lubrication. Subsequent chapters deal with detailed selection of lubric

  8. Developments in lubricant technology

    Srivastava, S P

    2014-01-01

    Provides a fundamental understanding of lubricants and lubricant technology including emerging lubricants such as synthetic and environmentally friendly lubricants Teaches the reader to understand the role of technology involved in the manufacture of lubricants Details both major industrial oils and automotive oils for various engines Covers emerging lubricant technology such as synthetic and environmentally friendly lubricants Discusses lubricant blending technology, storage, re-refining and condition monitoring of lubricant in equipment

  9. Marine Lubricants

    Carter, B. H.; Green, D.

    Marine diesel engines are classified by speed, either large (medium speed) or very large (slow speed) with high efficiencies and burning low-quality fuel. Slow-speed engines, up to 200 rpm, are two-stroke with separate combustion chamber and sump connected by a crosshead, with trunk and system oil lubricants for each. Medium-speed diesels, 300-1500 rpm, are of conventional automotive design with one lubricant. Slow-speed engines use heavy fuel oil of much lower quality than conventional diesel with problems of deposit cleanliness, acidity production and oxidation. Lubricants are mainly SAE 30/40/50 monogrades using paraffinic basestocks. The main types of additives are detergents/dispersants, antioxidants, corrosion inhibitors, anti-wear/load-carrying/ep, pour-point depressants and anti-foam compounds. There are no simple systems for classifying marine lubricants, as for automotive, because of the wide range of engine design, ratings and service applications they serve. There are no standard tests; lubricant suppliers use their own tests or the Bolnes 3DNL, with final proof from field tests. Frequent lubricant analyses safeguard engines and require standard sampling procedures before determination of density, viscosity, flash point, insolubles, base number, water and wear metal content.

  10. Experimental identification of dynamic coefficients of lightly loaded tilting-pad bearings under several lubrication regimes

    Salazar, Jorge G.; Santos, Ilmar F.

    2016-01-01

    ) radial injection nozzles, (d) displacement sensors and (e) well-tuned digital controllers. A scaled-down industrial rotor featuring active lubrication, composed of a flexible rotor supported by a four-rocker load-between-pads tilting-pad bearing under light load condition, is used for this objective. The......This paper presents the identified dynamic coefficients of a lightly loaded actively lubricated bearing under three lubrication regimes: passive, hybrid and feedback-controlled. The goal is to experimentally demonstrate the feasibility of modifying the bearing dynamic properties via active...... lubrication. Dominated by the latest two regimes, the bearing properties become adjustable or controllable due to the injection of either a constant or variable pressurized oil flow. Such a flow is regulated by a hydraulic control system composed of (a) a high-pressure oil supply unit, (b) servovalves, (c...

  11. Active lubrication applied to radial gas journal bearings. Part 1: Modeling

    Morosi, Stefano; Santos, Ilmar

    2011-01-01

    regulating radial injection of lubricant through the means of piezoelectric actuators mounted on the back of the bearing sleeves. A feedback law is used to couple the dynamic of a simplified rotor-bearing system with the pneumatic and dynamic characteristics of a piezoelectric actuated valve system. Selected...

  12. Numerical analysis of capillary compensated micropolar fluid lubricated hole-entry journal bearings

    Nathi Ram

    2016-06-01

    Full Text Available The micropolar lubricated symmetric/asymmetric hole-entry bearings using capillary restrictor have been analyzed in the present work. Reynolds equation for micropolar lubricant has been derived and solved by FEM. The results have been computed using selected parameters of micropolar lubricant for hole-entry hydrostatic/hybrid journal bearings. A significant increase in damping and stiffness coefficients is observed for bearings having micropolar parameter N2=0.9, lm=10 than similar bearings under Newtonian lubricant. The threshold speed gets increased when symmetric bearing lubricated under micropolar fluid than Newtonian lubricant. The threshold speed gets increased when symmetric bearing lubricated under micropolar fluid than Newtonian lubricant.

  13. Tribological Performance Optimization of Electroless Ni-B Coating under Lubricated Condition using Hybrid Grey Fuzzy Logic

    Mukhopadhyay, Arkadeb; Duari, Santanu; Barman, Tapan Kumar; Sahoo, Prasanta

    2015-11-01

    Deposition of nickel coating and its alloys using electroless method has received wide acceptance by researchers and even the industries because of their excellent tribological properties. The present experimental investigation deals with the behaviour of electroless Ni-B coating under lubricated condition on a pin-on-disc tribotester. An attempt is made to minimize the friction and wear characteristics simultaneously by optimizing three test parameters i.e. the applied normal load, speed and time of sliding using grey fuzzy reasoning analysis. The friction and wear tests are carried out based on Taguchi's L27 orthogonal array of experiments. 3D surface and contour plots are generated to analyze the trends in variation of friction and wear of the deposits considering the combined effect of the design variables. Analysis of variance is done to find out the contribution of each test parameter and their interactions in controlling the friction and wear behaviour of electroless Ni-B coating. Surface morphology, phase transformation and coating composition analysis are done with the help of scanning electron microscopy, X-ray diffraction analysis and energy dispersive X-ray analysis respectively.

  14. Comparative study of the tribological behavior under hybrid lubrication of diamond-like carbon films with different adhesion interfaces

    Costa, R. P. C.; Lima-Oliveira, D. A.; Marciano, F. R.; Lobo, A. O.; Corat, E. J.; Trava-Airoldi, V. J.

    2013-11-01

    This paper reports the influence of the adhesion interlayer between stainless steel and diamond-like carbon (DLC) films in two different contact conditions: in dry air and deionized water. The water was the liquid used to understand the mechanism and chemical reactions of the tribolayer formation under boundary lubrication. The effect of silicon and carbonitride adhesion interlayer was investigated on uncoated and coated DLC films. The results show that DLC/DLC pairs using carbonitride in air (30% RH) showed 60% less friction coefficient and wear less than three orders of magnitude than DLC/DLC pairs using silicon as interlayer. In deionized water, DLC/DLC pairs using carbonitride as interlayer showed 31% less friction coefficient when compared to DLC/DLC pairs with silicon. Raman related the chemical and structural changes in the DLC films during sliding in air and in the presence of water. Scratch tests showed a critical load of 14 N and 33 N in DLC films with silicon and carbonitride, respectively.

  15. On The Modelling Of Hybrid Aerostatic - Gas Journal Bearings

    Morosi, Stefano; Santos, Ilmar

    2011-01-01

    modeling for hybrid lubrication of a compressible fluid film journal bearing. Additional forces are generated by injecting pressurized air into the bearing gap through orifices located on the bearing walls. A modified form of the compressible Reynolds equation for active lubrication is derived. By solving......Gas journal bearing have been increasingly adopted in modern turbo-machinery applications, as they meet the demands of operation at higher rotational speeds, in clean environment and great efficiency. Due to the fact that gaseous lubricants, typically air, have much lower viscosity than more...... and drawbacks of this special kind of hybrid fluid film bearing....

  16. Aviation Lubricants

    Lansdown, A. R.; Lee, S.

    Aviation lubricants must be extremely reliable, withstand high specific loadings and extreme environmental conditions within short times. Requirements are critical. Piston engines increasingly use multi-grade oils, single grades are still used extensively, with anti-wear and anti-corrosion additives for some classes of engines. The main gas turbine lubricant problem is transient heat exposure, the main base oils used are synthetic polyol esters which minimise thermal degradation. Aminic anti-oxidants are used together with anti-wear/load-carrying, corrosion inhibitor and anti-foam additives. The majority of formulation viscosities are 5 cSt at 100°C. Other considerations are seal compatibility and coking tendency.

  17. Tractor Mechanics. Maintaining and Servicing the Engine, Learning Activity Packages 78-89; Lubricating the Tractor, Learning Activity Packages 90-94; Painting the Tractor, Learning Activity Packages 95-96.

    Clemson Univ., SC. Vocational Education Media Center.

    This series of learning activity packages focuses on three areas of tractor mechanics: (1) maintaining and servicing the engine, (2) lubricating the tractor, and (3) painting the tractor. Each of the nineteen illustrated learning activity packages follows a typical format: introduction, directions, objectives, learning activities, tools and…

  18. Rotor Vibration Reduction via Active Hybrid Bearings

    Nicoletti, Rodrigo; Santos, Ilmar

    2002-01-01

    The use of fluid power to reduce and control rotor vibration in rotating machines is investigated. An active hybrid bearing is studied, whose main objective is to reduce wear and vibration between rotating and stationary machinery parts. By injecting pressurised oil into the oil film, through...... orifices machined in the bearing pads, one can alter the machine dynamic characteristics, thus enhancing its operational range. A mathematical model of the rotor-bearing system, as well as of the hydraulic system, is presented. Numerical results of the system frequency response show good agreement with...

  19. New lubricating material for hydraulic turbine equipment

    The release of lubricant into the water stream after passage through hydraulic turbines is an environmental issue of concern. To address concerns about the self-lubricating bearing materials being used to replace the standard grease lubricated bronze bearings for wicket gates, a survey was carried out to determine the availability and use of self-lubricating bearing materials. Included in the survey were users, bearing suppliers and turbine manufacturers. Information derived from the survey included extent of use, historical data, bearing design parameters, lubrication practices, maintenance activity, and environmental issues. Results of the survey are tabulated. It was found that the use of self-lubricating bearing materials is the predominant technology available to satisfy environmental concerns for hydraulic equipment. A number of materials are available based on both metallic and polymer materials. A numer of materials are available that have demonstrated satisfactory service life for at least 10 years. As an alternative, hydraulic equipment can be lubricated with an environmentally friendly lubricant, although there are none commercially available that are biodegradable and non-toxic. In new equipment the cost of using self-lubricating bearings could be less than grease lubricated bronze bearings with automatic lubrication system. 3 refs., 4 figs., 3 tabs

  20. Lubricant composition

    Lubricating compositions and shaped articles composed thereof are described which consist essentially of about 30 to about 60% by weight of an oil of lubricating viscosity, about 20 to about 50% by weight of a high molecular weight polymer, and about 20 about 50% by weight of a heat conductive agent capable of conducting heat away from a bearing surface where it is generated. The high molecular weight polymer may, for example, be polyethylene, having average molecular weights in the range from about 1.0 X 105 to about 5.0 X 106. The oil may be a mineral oil, a diester oil or preferably a synthetic hydrocarbon oil having a viscosity in the range from about 13 to about 1200 mm''/s (Mm2/s) at 380C. (1000F.) the heat conductive agent may be powdered zinc oxide, aluminum powder, or equivalents thereof in this invention. The compositions are semi-rigid gels which may be formed in a mold and used as is, or which may be shaped further after molding. The gels are formed by blending the heat conductive agent and polymer and then blending that mixture with the oil and heating to a temperature above the softening temperature of the polymer for a period of time (About 5 to about 75 minutes) sufficient that the mixture will form a firm, tough solid gel on cooling having an oily surface provided by oil exuding from the gel thus producing a lubricative mass operable for extended periods of time. The heat conductive substance dispersed in the gel aids in dissipating heat produced at the bearing surfaces during use thus improving the performance of the gel both in withstanding higher bulk operating temperatures and in resisting breakdown of the gel under prolonged use

  1. Cost-Cutting Powdered Lubricant

    2005-01-01

    Scientists at NASA's Glenn Research Center developed a high-temperature, solid lubricant coating material that is saving the manufacturing industry millions of dollars. The material came out of 3 decades of tribological research, work studying high-temperature friction, lubrication, and the wearing of interacting surfaces that are in relative motion. It was developed as a shaft coating deposited by thermal spraying to protect foil air bearings used in oil-free turbomachinery, like gas turbines, and is meant to be part of a larger project: an oil-free aircraft engine capable of operating at high temperatures with increased reliability, lowered weight, reduced maintenance requirements, and increased power. This advanced coating, PS300, is a self-lubricating bearing material containing chromium oxide, with additions of a low-temperature start up lubricant (silver) and a high-temperature lubricant, making it remarkably stable at high temperatures, and better suited than previously available materials for high-stress conditions. It improves efficiency, lowers friction, reduces emissions, and has been used by NASA in advanced aeropropulsion engines, refrigeration compressors, turbochargers, and hybrid electrical turbogenerators. PS300 is ideal in any application where lowered weight and reduced maintenance are desired, and high-temperature uses and heavy operating speeds are expected. It has notable uses for the Space Agency, but it has even further-reaching potential for the industrial realm.

  2. Impact of Lubricant Additives on thePhysicochemical Properties and Activity of Three‐Way Catalysts

    Chao Xie

    2016-04-01

    Full Text Available As alternative lubricant anti‐wear additives are sought to reduce friction and improve overall fuel economy, it is important that these additives are also compatible with current emissions control catalysts. In the present work, an oil‐miscible phosphorous‐containing ionic liquid (IL, trihexyltetradecylphosphonium bis(2‐ethylhexyl phosphate ([P66614][DEHP], is evaluated for its impact on three‐way catalysts (TWC and benchmarked against the industry standard zinc‐dialkyl‐dithio‐phosphate (ZDDP. The TWCs are aged in different scenarios: neat gasoline (no‐additive, or NA, gasoline+ZDDP, and gasoline+IL. The aged samples, along with the as‐received TWC, are characterized through various analytical techniques including catalyst reactivity evaluation in a bench‐flow reactor. The temperatures of 50% conversion (T50 for the ZDDP‐aged TWCs increased by 30, 24, and 25 °C for NO, CO, and C3H6, respectively, compared to the no‐additive case. Although the IL‐aged TWC also increased in T50 for CO and C3H6, it was notably less than ZDDP, 7 and 9 °C, respectively. Additionally, the IL‐aged samples had higher water‐gas‐shift reactivity and oxygen storage capacity than the ZDDP‐aged TWC. Characterization of the aged samples indicated the predominant presence of CePO4 in the ZDDP‐aged TWC aged by ZDDP, while its formation was retarded in the case of IL where higher levels of AlPO4 is observed. Thus, results in this work indicate that the phosphonium‐phosphate IL potentially has less adverse impact on TWC than ZDDP.

  3. From Hybrid to Actively-Controlled Gas Lubricated Bearings – Theory and Experiment

    Morosi, Stefano; Santos, Ilmar

    2011-01-01

    Fra et rotordynamisk synspunkt er der to fænomener der begrænser udbredelsen af den traditionelle gas smøring: 1) lav dæmpning gør drift på tværs af kritiske hastigheder usikker, da selv et lavt niveau af ubalance kan generere store vibrationsamplituder, 2) den øvre grænse for superkritisk drift bestemmes af forekomsten af sub-synkrone hvirvel ustabiliteter. Forøgelsen af den hastighed hvorved ustabilitet indtræder er en af de største udfordringer ved design af højhastigheds gaslejer. Meget f...

  4. Elasto-hydrodynamic lubrication

    Dowson, D; Hopkins, D W

    1977-01-01

    Elasto-Hydrodynamic Lubrication deals with the mechanism of elasto-hydrodynamic lubrication, that is, the lubrication regime in operation over the small areas where machine components are in nominal point or line contact. The lubrication of rigid contacts is discussed, along with the effects of high pressure on the lubricant and bounding solids. The governing equations for the solution of elasto-hydrodynamic problems are presented.Comprised of 13 chapters, this volume begins with an overview of elasto-hydrodynamic lubrication and representation of contacts by cylinders, followed by a discussio

  5. Lubricants in Pharmaceutical Solid Dosage Forms

    Jinjiang Li

    2014-02-01

    Full Text Available Lubrication plays a key role in successful manufacturing of pharmaceutical solid dosage forms; lubricants are essential ingredients in robust formulations to achieve this. Although many failures in pharmaceutical manufacturing operations are caused by issues related to lubrication, in general, lubricants do not gain adequate attention in the development of pharmaceutical formulations. In this paper, the fundamental background on lubrication is introduced, in which the relationships between lubrication and friction/adhesion forces are discussed. Then, the application of lubrication in the development of pharmaceutical products and manufacturing processes is discussed with an emphasis on magnesium stearate. In particular, the effect of its hydration state (anhydrate, monohydrate, dihydrate, and trihydrate and its powder characteristics on lubrication efficiency, as well as product and process performance is summarized. In addition, the impact of lubrication on the dynamics of compaction/compression processes and on the mechanical properties of compacts/tablets is presented. Furthermore, the online monitoring of magnesium stearate in a blending process is briefly mentioned. Finally, the chemical compatibility of active pharmaceutical ingredient (API with magnesium stearate and its reactive impurities is reviewed with examples from the literature illustrating the various reaction mechanisms involved.

  6. Control System Design for Active Lubrication with Theoretical and Experimental Examples

    Santos, Ilmar; Scalabrin, A.

    2003-01-01

    This work focuses on the theoretical and experimental behavior of rigid rotors controlled by tilting-pad journal bearings with active oil injection. Initially the mathematical model of the active bearing is presented: The equations that describe the dynamics of hydraulic actuators are introduced...... the control system of the active bearing based on root locus curves. The active system stability is analyzed by calculating its eigenvalues and frequency response curves. The theoretical and experimental results show that this kind of bearing can significantly reduce the vibration level of rotating...

  7. Solar air-conditioning-active, hybrid and passive

    Yellott, J. I.

    1981-04-01

    After a discussion of summer air conditioning requirements in the United States, active, hybrid, and passive cooling systems are defined. Active processes and systems include absorption, Rankine cycle, and a small variety of miscellaneous systems. The hybrid solar cooling and dehumidification technology of desiccation is covered as well as evaporative cooling. The passive solar cooling processes covered include convective, radiative and evaporative cooling. Federal and state involvement in solar cooling is then discussed. (LEW)

  8. Control system design for flexible rotors supported by actively lubricated bearings

    Nicoletti, Rodrigo; Santos, Ilmar

    2008-01-01

    and keeping the lengths of the two eigenvalues constant in the real-imaginary plane. The methodology is applied to an industrial gas compressor supported by active tilting-pad journal bearings. The unbalance response functions and mode shapes of the flexible rotor with and without active control are...... displacement and velocity of the shaft at the bearing positions....

  9. Dynamic Coefficients of a Tilting Pad With Active Lubrication: Comparison Between Theoretical and Experimental Results

    Cerda Varela, Alejandro Javier; Santos, Ilmar

    2015-01-01

    This paper deals with the validation of the mathematical model for predicting the equivalent stiffness and damping of an active tilting-pad bearing. The active bearing design includes an injection nozzle in the pad and a hydraulic supply system featuring a servovalve, which enables to modify...

  10. Solid Lubricant For Alumina

    Dellacorte, Christopher; Pepper, Stephen V.; Honecy, Frank S.

    1993-01-01

    Outer layer of silver lubricates, while intermediate layer of titanium ensures adhesion. Lubricating outer films of silver deposited on thin intermediate films of titanium on alumina substrates found to reduce sliding friction and wear. Films provide effective lubrication for ceramic seals, bearings, and other hot sliding components in advanced high-temperature engines.

  11. Hybrid Particle Swarm Optimization for Hybrid Flowshop Scheduling Problem with Maintenance Activities

    Jun-qing Li; Quan-ke Pan; Kun Mao

    2014-01-01

    A hybrid algorithm which combines particle swarm optimization (PSO) and iterated local search (ILS) is proposed for solving the hybrid flowshop scheduling (HFS) problem with preventive maintenance (PM) activities. In the proposed algorithm, different crossover operators and mutation operators are investigated. In addition, an efficient multiple insert mutation operator is developed for enhancing the searching ability of the algorithm. Furthermore, an ILS-based local search procedure is embedd...

  12. The determination of trace elements in new and used lubricating oils by neutron activation analysis

    The trace elements on unused and used motor oils of different brands utilized in different light, medium and heavy weight vehicles by neutron activation analysis(N A A) has been measured. To find out the exact amount of trace elements in used motor oil only due to erosion was investigated both qualitatively and quantitatively through neutron activation analysis by thermal neutrons and X ray fluorescence analysis. Forty sample of motor oil with natural basis and ten samples with synthetic basis, plus thirteen samples as filters, gas and oil rings, fix and moving bearing has been provided. For determining the quality of elements in the given samples the time of radiation for short lived elements was from one minute to ten minutes in 1 MW reactor power, using pneumatic rabbit system. The elements Al, V, Ca, and specially S have been recognized. For long lived elements the irradiation time was one hour, one and a half hour and 2 hours. As a whole, for all samples 250 time radiations have been determined. Counting of samples have been done by multichannel analyzers connected to computer P D P/11 and IBM/P C at different times from 200 seconds to 4000 seconds. The time interval between the end of irradiation till start of counting, was from three minutes to a year. Analysis of samples have been provided by software O R A C L in computer P D P/11 and software M A S T E R O in computer IBM/P C. As a whole, nine hundred spectra and analysis have been provide. Thirty one elements have been identified. They are as follows. Al, V, S, Cu, Ca, Mg, Cl, In, Mn, K, Na, As, Br, Cd, Cr, Fe, Sb, Sc, Zn, Ag, Co, Ni, Au, Cs, Eu, Sm, Lu, La, W, Xe, Ba, Hf. These elements were found in all samples. But elements La, Lu, Au, Cs, Ni, Eu, Xe, W, Ba, and Hf were found in some samples. By comparing methods with standards and using thermal neutron flux, the quantitative amounts of elements were found. By using X-ray fluorescence Zn was found in some samples and in some others (used oil) Zn, Br

  13. CALCIUM SOAP LUBRICANTS

    Alaz, Izer; Tugce, Nefise; Devrim, Balköse

    2014-01-01

    The article studies the properties of calcium stearate (CaSt2) and lubricants produced on its basis. These lubricants were prepared using sodium stearate and calcium chloride by subsidence from aqueous solutions. The CaSt2 and the light fraction of crude oil were mixed together to obtain lubricating substances. The article shows that CaSt2 had the melting temperature of 142.8 C that is higher than the melting temperature of crude oil (128 C). The compositions of obtained lubricants were stu...

  14. Grease lubrication in rolling bearings

    Lugt, Piet M

    2012-01-01

    The definitive book on the science of grease lubrication for roller and needle bearings in industrial and vehicle engineering. Grease Lubrication in Rolling Bearings provides an overview of the existing knowledge on the various aspects of grease lubrication (including lubrication systems) and the state of the art models that exist today. The book reviews the physical and chemical aspects of grease lubrication, primarily directed towards lubrication of rolling bearings. The first part of the book covers grease composition, properties and rheology, including thermal

  15. Synthesis, Characterization, and Tribological Evaluation of TiO2-Reinforced Boron and Nitrogen co-Doped Reduced Graphene Oxide Based Hybrid Nanomaterials as Efficient Antiwear Lubricant Additives.

    Jaiswal, Vinay; Kalyani; Umrao, Sima; Rastogi, Rashmi B; Kumar, Rajesh; Srivastava, Anchal

    2016-05-11

    The microwave-synthesized reduced graphene oxide (MRG), boron-doped reduced graphene oxide (B-MRG), nitrogen-doped reduced graphene oxide (N-MRG), boron-nitrogen-co-doped reduced graphene oxide (B-N-MRG), and TiO2-reinforced B-N-MRG (TiO2-B-N-MRG) nanomaterials have been synthesized and characterized by various state-of-the-art techniques, like Raman spectroscopy, powder X-ray diffraction, scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy. Furthermore, the tribological properties of prepared nanomaterials as antiwear additives in neutral paraffin oil have been evaluated using a four-ball machine at an optimized additive concentration (0.15% w/v). The tribological parameters, like mean wear scar diameter, coefficient of friction, and wear rates, revealed that these nanomaterials have potential to be developed as environmentally friendly sulfated-ash-, phosphorus-, and sulfur-free antiwear lubricant additives. The friction- and wear-reducing behavior of MRG increased upon successive doping of nitrogen, boron, and both nitrogen and boron. Among these additives, B-N-co-doped MRG shows superior tribological behavior in paraffin base oil. Besides this, the load-carrying properties of B-N-co-doped MRG have significantly improved after its reinforcement with TiO2 nanoparticles. A comparative study of the surface morphology of a lubricated track in the presence of various additives has been assessed by SEM and contact-mode atomic force microscopy. The X-ray photoelectron spectroscopy studies have proved that the excellent lubrication properties of TiO2-B-N-MRG are due to the in situ formation of a tribofilm composed of boron nitride, adsorbed graphene layers, and tribosintered TiO2 nanoparticles during the tribocontact. Being sulfur-, halogen-, and phosphorus-free, these graphene-based nanomaterials act as green antiwear additives, protecting interacting

  16. Feasibility of Applying Controllable Lubrication Techniques to Reciprocating Machines

    Pulido, Edgar Estupinan

    The use of active lubrication in journal bearings helps to enhance the thin fluid films by increasing the fluid film thickness and consequently reducing viscous friction losses and vibrations. One refers to active lubrication when conventional hydrodynamic lubrication is combined with dynamically...... conventional lubrication conditions, a mathematical model of a reciprocating mechanism connected to a rigid / flexible rotor via thin fluid films was developed. The mathematical model involves the use of multibody dynamics theory for the modelling of the reciprocating mechanism (rigid bodies), finite elements...... method for the modelling of the flexible rotor (crankshaft) and hydrodynamic fluid film theory for describing the dynamics of the thin fluid films. When active lubrication is introduced to modify conventional hydrodynamic lubrication, by means of aplying radial oil injection at controllable oil pressures...

  17. Metal forming and lubrication

    Bay, Niels

    2000-01-01

    Lubrication is essential in most metal forming processes. The lubricant film has two basic functions, [1]: i. to separate the work piece and tool surfaces and ii. to cool the workpiece and the tool. Separation of the two surfaces implies lower friction facilitating deformation and lowering the tool...

  18. Active low intrusion hybrid monitor for wireless sensor networks

    Marlon Navia; Campelo, Jose C.; Alberto Bonastre; Rafael Ors; Capella, Juan V.; Juan J. Serrano

    2015-01-01

    Several systems have been proposed to monitor wireless sensor networks (WSN). These systems may be active (causing a high degree of intrusion) or passive (low observability inside the nodes). This paper presents the implementation of an active hybrid (hardware and software) monitor with low intrusion. It is based on the addition to the sensor node of a monitor node (hardware part) which, through a standard interface, is able to receive the monitoring information sent by a piece of software ex...

  19. A Hybrid Approach to Active Learning.

    Ramsier, R. D.

    2001-01-01

    Describes an approach to incorporate active learning strategies into the first semester of a university-level introductory physics course. Combines cooperative and peer-based methods inside the classroom with project-based learning outside the classroom in an attempt to develop students' transferable skills as well as improving their understanding…

  20. Design and control of hybrid active power filters

    Lam, Chi-Seng

    2014-01-01

    Design and Control of Hybrid Active Power Filters presents an overview of the current quality problems and their compensators. To get a balance between the system cost and performance, hybrid active power filters (HAPFs) are valuable. The book presents the coverage of resonance phenomena prevention capability, filtering performance and system robustness analysis of HAPF; nonlinear inverter current slope characteristics and their linear operation region requirement analysis of the hysteresis PWM for the HAPF; minimum inverter capacity design procedure of HAPF, adaptive dc-link voltage controller for the HAPF and the real design example of a 220V 10kVA HAPF, in which the system performance analysis method, minimum dc voltage deduction concept and adaptive dc voltage idea can be further extended into the other active compensators, such as APF, static synchronous compensator STATCOM, etc. This book will benefit researchers, graduate students, and electrical power engineers in the field of power-quality compensati...

  1. Dairy Equipment Lubrication

    1978-01-01

    Lake To Lake Dairy Cooperative, Manitowoc, Wisconsin, operates four plants in Wisconsin for processing milk, butter and cheese products from its 1,300 member farms. The large co-op was able to realize substantial savings by using NASA information for improved efficiency in plant maintenance. Under contract to Marshall Space Flight Center, Midwest Research Institute compiled a handbook consolidating information about commercially available lubricants. The handbook details chemical and physical properties, applications, specifications, test procedures and test data for liquid and solid lubricants. Lake To Lake's plant engineer used the handbook to effect savings in maintenance labor and materials costs by reducing the number of lubricants used on certain equipment. Strict U.S. Department of Agriculture and Food and Drug Administration regulations preclude lubrication changes n production equipment, but the co-op's maintenance chief was able to eliminate seven types of lubricants for ancillary equipment, such as compressors and high pressure pumps. Handbook data enabled him to select comparable but les expensive lubricants in the materials consolidation process, and simplified lubrication schedules and procedures. The handbook is in continuing use as a reference source when a new item of equipment is purchased.

  2. PRODUCTION OF HIGH QUALITY LUBRICATING BASE OIL

    2001-01-01

    @@High VI lubricating oil is produced in hydrocracker through hydrocracking (HDC) and hydroisome-rization reactions. In order to effectively produce high VI component, such as iso-pafaffins and monocyclic naphtenes, it is important to load suitable HDC catalysts and operate them in the appropriate reaction conditions.   Nippon Mitsubishi Oil Corporation (NMOC) and its affiliate company, Nippon Mitsubishi Petroleum Refining Company (NMPRC) reported their original HDC catalysts four years ago in this Japan-China joint se-minar in Beijing[1]. NMOC and NMPRC operate their hydrocracker both in fuel oil production mode and in lubricating oil production mode. In lubricating oil production mode, high VI lubricating oil called VHDC are produced.   In this paper, at first, the advantages of high VI lubricating oil are described. And then it is announced that NMOC and NMPRC have developed a new generation of HDC catalyst with higher cracking activity, higher middle distillate selectivity and longer life than the other commercial HDC catalysts. In addition to those properties, the catalyst is able to yield high VI lubricating oil as well.

  3. Active graphene–silicon hybrid diode for terahertz waves

    Li, Quan; Tian, Zhen; Zhang, Xueqian; Singh, Ranjan; Du, Liangliang; Gu, Jianqiang; Han, Jiaguang; Zhang, Weili

    2015-01-01

    Controlling the propagation properties of the terahertz waves in graphene holds great promise in enabling novel technologies for the convergence of electronics and photonics. A diode is a fundamental electronic device that allows the passage of current in just one direction based on the polarity of the applied voltage. With simultaneous optical and electrical excitations, we experimentally demonstrate an active diode for the terahertz waves consisting of a graphene–silicon hybrid film. The di...

  4. Architecture for Collaborative Learning Activities in Hybrid Learning Environments

    Ibáñez, María Blanca; Maroto, David; García Rueda, José Jesús; Leony, Derick; Delgado Kloos, Carlos

    2012-01-01

    3D virtual worlds are recognized as collaborative learning environments. However, the underlying technology is not sufficiently mature and the virtual worlds look cartoonish, unlinked to reality. Thus, it is important to enrich them with elements from the real world to enhance student engagement in learning activities. Our approach is to build learning environments where participants can either be in the real world or in its mirror world while sharing the same hybrid space in a collaborative ...

  5. Active removal of large massive objects by hybrid propulsion module

    Luigi T. De Luca; Lavagna, Mich?le; Maggi, Filippo; Tadini, Pietro; Pardini, Carmen; Anselmo, Luciano; Grassi, Michele; Tancredi, Urbano; Francesconi, Alessandro; Chiesa, Sergio; Viola, Nicole; Bonnal, Christophe

    2013-01-01

    This paper deals with the feasibility study of a mission for the active removal of a large massive object, such as the second stage of the Zenit launcher or the Envisat spacecraft, abandoned in the most populated orbit region in low Earth orbit. Critical mission aspects and related technologies are investigated at a preliminary level. In particular, an innovative electro-adhesive system for target capture, mechanical systems for chaser-debris hard docking and a hybrid propulsion module for re...

  6. Metallic nanoparticles in active layer for hybrid photovoltaic device applications

    In this study, Poly (3-hexylthiophene) (P3HT): [6,6]-phenyl C61-butyric (PCBM): titania (TiO2): platinum (Pt) nanoparticles (NPs) hybrid films were prepared and used as the active layer of solar cells. The use of nano-Pt in hybrid films may increase the efficiency of solar cells because of its high carrier mobility. The polyol reduction reaction was used to synthesize inorganic Pt NPs by dissolving H2PtCl6·6H2O in ethylene glycol and refluxing the solvent for several hours. Then, the prepared Pt NPs were used to prepare the solar cells. The experimental results showed that the short-circuit current density and efficiency of solar cells increased from 7.31 mA/cm2 and 2.17% to 10.10 mA/cm2 and 3.26%, respectively. In addition, the value of incident photon-to-electron conversion efficiency reached 55% as 0.03 wt.% Pt NPs were added into the active layer P3HT:PCBM:TiO2. - Highlights: • A P3HT:PCBM:TiO2 hybrid film was applied as an active layer. • Effect of Pt content on the efficiency of a solar cell was examined. • Solar cell with a 3.26% efficiency was fabricated

  7. Metallic nanoparticles in active layer for hybrid photovoltaic device applications

    Yu, Yang-Yen, E-mail: yyyu@mail.mcut.edu.tw [Department of Materials Engineering, Ming Chi University of Technology, 84 Gunjuan Rd., Taishan Dist., New Taipei City, 24301, Taiwan (China); Center for Thin Film Technologies and Applications, Ming Chi University of Technology, 84 Gunjuan Rd., Taishan Dist., New Taipei City, 24301, Taiwan (China); Battery Research Center of Green Energy, Ming Chi University of Technology, 84 Gunjuan Rd., Taishan Dist., New Taipei City, 24301, Taiwan (China); Chan, Si-Han [Department of Materials Engineering, Ming Chi University of Technology, 84 Gunjuan Rd., Taishan Dist., New Taipei City, 24301, Taiwan (China)

    2013-10-01

    In this study, Poly (3-hexylthiophene) (P3HT): [6,6]-phenyl C61-butyric (PCBM): titania (TiO{sub 2}): platinum (Pt) nanoparticles (NPs) hybrid films were prepared and used as the active layer of solar cells. The use of nano-Pt in hybrid films may increase the efficiency of solar cells because of its high carrier mobility. The polyol reduction reaction was used to synthesize inorganic Pt NPs by dissolving H{sub 2}PtCl{sub 6}·6H{sub 2}O in ethylene glycol and refluxing the solvent for several hours. Then, the prepared Pt NPs were used to prepare the solar cells. The experimental results showed that the short-circuit current density and efficiency of solar cells increased from 7.31 mA/cm{sup 2} and 2.17% to 10.10 mA/cm{sup 2} and 3.26%, respectively. In addition, the value of incident photon-to-electron conversion efficiency reached 55% as 0.03 wt.% Pt NPs were added into the active layer P3HT:PCBM:TiO{sub 2}. - Highlights: • A P3HT:PCBM:TiO{sub 2} hybrid film was applied as an active layer. • Effect of Pt content on the efficiency of a solar cell was examined. • Solar cell with a 3.26% efficiency was fabricated.

  8. Potential of palm kernel activated carbon epoxy (PKAC-E composite as solid lubricant: Effect of load on friction and wear properties

    K.W. Chua

    2014-09-01

    Full Text Available The aim of this study is to investigate the effect of load on the friction and wear properties of palm kernel activated carbon epoxy (PKAC-E composite. The PKAC-E composite specimen was fabricated by hot compression molding method. Dry sliding test was performed by using a pin-on-disc tribometer at various load conditions with constant sliding speed and distance. The experimental results show that wear rate and friction coefficient of PKAC-E composite decreases with applied load. However, at higher load, friction coefficient increases slightly and remains almost invariant with applied load. In addition, some adhesive and abrasive wear types were identified on the worn surfaces. The main conclusion of this work is that PKAC-E composite show unique properties as solid lubricant at low load under unlubricated conditions.

  9. Importance of lubricant analysis

    Sreten R. Perić

    2012-04-01

    Full Text Available Monitoring the performance of lubricants in practical application has multiple significance for both the consumer and the lubricant manufacturer. The primary significance for the consumer is extended life and timely change of lubricants, which keeps the costs of maintenance down. The lubricant manufacturer gains by creating a partner relationship with the consumer, as well as creating the possibility of gathering information about the performance of his product which will serve as the foundation for its further improvement and development. If we wish to maintain technical systems so that they have minimum halts and costs caused by halt removal or system failures, we must monitor data indicating equipment condition throughout the system operation. It is especially difficult to obtain data on equipment condition for parts which cannot be observed due to their position. In such cases, the oil analysis enables a continuous equipment condition monitoring and timely response in order to prevent undesirable prolonged halts.

  10. Fuels and Lubricants Facility

    Federal Laboratory Consortium — Modern naval aircraft and turbine-powered craft require reliable and high-quality fuels and lubricants to satisfy the demands imposed upon them for top performance...

  11. Numerical analysis of capillary compensated micropolar fluid lubricated hole-entry journal bearings

    Nathi Ram

    2016-01-01

    The micropolar lubricated symmetric/asymmetric hole-entry bearings using capillary restrictor have been analyzed in the present work. Reynolds equation for micropolar lubricant has been derived and solved by FEM. The results have been computed using selected parameters of micropolar lubricant for hole-entry hydrostatic/hybrid journal bearings. A significant increase in damping and stiffness coefficients is observed for bearings having micropolar parameter N2=0.9, lm=10 than similar bearings ...

  12. Lubrication by glycoprotein brushes.

    Zappone, Bruno; Ruths, Marina; Greene, George W.; Israelachvili, Jacob

    2006-03-01

    Grafted polyelectrolyte brushes show excellent lubricating properties under water and have been proposed as a model to study boundary lubrication in biological system. Lubricin, a glycoprotein of the synovial fluid, is considered the major boundary lubricant of articular joints. Using the Surface Force Apparatus, we have measured normal and friction forces between model surfaces (negatively charged mica, positively charged poly-lysine and aminothiol, hydrophobic alkanethiol) bearing adsorbed layers of lubricin. Lubricin layers acts like a versatile anti-adhesive, adsorbing on all the surfaces considered and creating a repulsion similar to the force between end-grafted polymer brushes. Analogies with polymer brushes also appear from bridging experiment, where proteins molecules are end-adsorbed on two opposing surfaces at the same time. Lubricin `brushes' show good lubricating ability at low applied pressures (P<0.5MPa), especially on negatively charged surfaces like mica. At higher load, the adsorbed layers wears and fails lubricating the surfaces, while still protecting the underlying substrate from wearing. Lubricin might thus be a first example of biological polyelectrolytes providing `brush-like' lubrication and wear-protection.

  13. On the stability analysis of flexible rotors supported by Hybrid Aerostatic - Gas Journal Bearings

    Morosi, Stefano; Santos, Ilmar

    external pressurization. The present contribution presents a detailed mathematical modeling for hybrid lubrication of a compressible fluid film journal bearing. Piezo-actuated valves are used in order to inject pressurized air into the bearing gap through orifices located on the bearing walls. A modified...... form of the compressible Reynolds equation for active lubrication is derived. Particular attention is given to the injections terms and a comparison is carried on between fully nonlinear and linearized expressions. By solving this equation, stiffness and damping coefficients can be determined. A...... this special kind of hybrid fluid film bearing....

  14. Synthesis and antitumor activity of tetrahydrocarbazole hybridized with dithioate derivatives.

    El-Nassan, Hala Bakr

    2015-04-01

    The present study reported the synthesis of tetrahydrocarbazoles hybridized with dithioate derivatives. Three series were synthesized namely alkyl dithiocarbonates (4a-d), heterocyclic dithiocarbamates (6a-g) and dialkyl dithiocarbamate (7). The synthesized compounds were tested in vitro on human breast adenocarcinoma cell line (MCF7) and the human colon tumor cell line (HCT116). Most of the synthesized compounds exploited potent antitumor activity, especially compound 6f [4-chlorophenylpiperazine derivative], which showed cytotoxic activity against MCF7 superior to doxorubicin with IC50 value of 7.24 nM/mL. PMID:24899376

  15. Optically Active Hybrid Materials Constructed from Helically Substituted Polyacetylenes.

    Zhang, Huanyu; Zhao, Biao; Deng, Jianping

    2016-04-01

    Functional materials derived from synthetic helical polymers are attracting increasing interest. Helically substituted polyacetylenes (HSPAs) are especially interesting as typical artificial helical polymers. In recent years, we designed and prepared a series of functional materials based on HSPAs and inorganic materials. The target is to establish some novel hybrid materials that combine the superior properties of both. The examined inorganic materials include silica, graphene, and magnetic Fe3 O4 nanoparticles. Such new functional materials hold great promise and are expected to find practical applications, for instance, as chiral absorbents, chiral sensors, chiral selectors for inducing enantioselective crystallization, chiral catalysts towards asymmetric catalysis, and chiral carriers for enantioselective release. The Personal Account summarizes our major achievements in preparing optically active hybrid materials. We hope it will speed up progress in chiral-related research areas. PMID:26991679

  16. Active graphene-silicon hybrid diode for terahertz waves

    Li, Quan; Tian, Zhen; Zhang, Xueqian; Singh, Ranjan; Du, Liangliang; Gu, Jianqiang; Han, Jiaguang; Zhang, Weili

    2015-05-01

    Controlling the propagation properties of the terahertz waves in graphene holds great promise in enabling novel technologies for the convergence of electronics and photonics. A diode is a fundamental electronic device that allows the passage of current in just one direction based on the polarity of the applied voltage. With simultaneous optical and electrical excitations, we experimentally demonstrate an active diode for the terahertz waves consisting of a graphene-silicon hybrid film. The diode transmits terahertz waves when biased with a positive voltage while attenuates the wave under a low negative voltage, which can be seen as an analogue of an electronic semiconductor diode. Here, we obtain a large transmission modulation of 83% in the graphene-silicon hybrid film, which exhibits tremendous potential for applications in designing broadband terahertz modulators and switchable terahertz plasmonic and metamaterial devices.

  17. Natural cinnamic acids, synthetic derivatives and hybrids with antimicrobial activity.

    Guzman, Juan David

    2014-01-01

    Antimicrobial natural preparations involving cinnamon, storax and propolis have been long used topically for treating infections. Cinnamic acids and related molecules are partly responsible for the therapeutic effects observed in these preparations. Most of the cinnamic acids, their esters, amides, aldehydes and alcohols, show significant growth inhibition against one or several bacterial and fungal species. Of particular interest is the potent antitubercular activity observed for some of these cinnamic derivatives, which may be amenable as future drugs for treating tuberculosis. This review intends to summarize the literature data on the antimicrobial activity of the natural cinnamic acids and related derivatives. In addition, selected hybrids between cinnamic acids and biologically active scaffolds with antimicrobial activity were also included. A comprehensive literature search was performed collating the minimum inhibitory concentration (MIC) of each cinnamic acid or derivative against the reported microorganisms. The MIC data allows the relative comparison between series of molecules and the derivation of structure-activity relationships. PMID:25429559

  18. Natural Cinnamic Acids, Synthetic Derivatives and Hybrids with Antimicrobial Activity

    Juan David Guzman

    2014-11-01

    Full Text Available Antimicrobial natural preparations involving cinnamon, storax and propolis have been long used topically for treating infections. Cinnamic acids and related molecules are partly responsible for the therapeutic effects observed in these preparations. Most of the cinnamic acids, their esters, amides, aldehydes and alcohols, show significant growth inhibition against one or several bacterial and fungal species. Of particular interest is the potent antitubercular activity observed for some of these cinnamic derivatives, which may be amenable as future drugs for treating tuberculosis. This review intends to summarize the literature data on the antimicrobial activity of the natural cinnamic acids and related derivatives. In addition, selected hybrids between cinnamic acids and biologically active scaffolds with antimicrobial activity were also included. A comprehensive literature search was performed collating the minimum inhibitory concentration (MIC of each cinnamic acid or derivative against the reported microorganisms. The MIC data allows the relative comparison between series of molecules and the derivation of structure-activity relationships.

  19. Power system with an integrated lubrication circuit

    Hoff, Brian D.; Akasam, Sivaprasad; Algrain, Marcelo C.; Johnson, Kris W.; Lane, William H.

    2009-11-10

    A power system includes an engine having a first lubrication circuit and at least one auxiliary power unit having a second lubrication circuit. The first lubrication circuit is in fluid communication with the second lubrication circuit.

  20. Vibration active control of tilting pad journal bearing rotor system based on the active lubrication%基于主动润滑可倾瓦轴承转子系统的振动主动控制

    刘宏; 宫晓春; 王晋麟

    2011-01-01

    研究一类可倾瓦支承的单盘非对称转子系统的振动主动控制问题.首先建立了系统的非线性动力学方程,针对主动润滑控制系统设计了BP神经网络PID控制器对转子系统进行振动主动控制.通过计算分析可知,采用基于BP-PID的主动润滑系统能够很好的抑制系统的振幅,使系统在很高的转速时才发生油膜失稳,拓宽转子系统稳定运转的转速范围,在转子系统发生油膜失稳时系统的振幅也能够得到极大程度的控制.%The vibration active control of an unsymmetrical rotor supported by two tilting pad journal bearings is investigated in this paper. Firstly, the nonlinear governing equation of the rotor system is formulated. Then the BP neural network PID controller is designed with regard to the active lubricated control system is applied to suppress the vibration of the concerning rotor system. After calculation and analysis the persuasive results are obtained. The vibration amplitude of the rotor system is greatly reduced by means of the active lubricated control system through the BP neural network PID controller. The whip instability of the controlled system occurs at a very high rotational speed and the stable operation range is greatly broadened. The vibration amplitude can be significantly suppressed by the active lubricated control system when the rotor runs up against the whip instability.

  1. Computational Chemistry and Lubrication

    Zehe, Michael J.

    1998-01-01

    Members of NASA Lewis Research Center's Tribology and Surface Science Branch are applying high-level computational chemistry techniques to the development of new lubrication systems for space applications and for future advanced aircraft engines. The next generation of gas turbine engines will require a liquid lubricant to function at temperatures in excess of 350 C in oxidizing environments. Conventional hydrocarbon-based lubricants are incapable of operating in these extreme environments, but a class of compounds known as the perfluoropolyether (PFAE) liquids (see the preceding illustration) shows promise for such applications. These commercially available products are already being used as lubricants in conditions where low vapor pressure and chemical stability are crucial, such as in satellite bearings and composite disk platters. At higher temperatures, however, these compounds undergo a decomposition process that is assisted (catalyzed) by metal and metal oxide bearing surfaces. This decomposition process severely limits the applicability of PFAE's at higher temperatures. A great deal of laboratory experimentation has revealed that the extent of fluid degradation depends on the chemical properties of the bearing surface materials. Lubrication engineers would like to understand the chemical breakdown mechanism to design a less vulnerable PFAE or to develop a chemical additive to block this degradation.

  2. Surfactant-activated lipase hybrid nanoflowers with enhanced enzymatic performance

    Cui, Jiandong; Zhao, Yamin; Liu, Ronglin; Zhong, Cheng; Jia, Shiru

    2016-01-01

    Increasing numbers of materials have been extensively used as platforms for enzyme immobilization to improve catalytic performance. However, activity of the most of the enzymes was declined after immobilization. Here, we develop a surfactant-activated lipase-inorganic flowerlike hybrid nanomaterials with rational design based on interfacial activation and self-assembly. The resulting surfactant-activated lipase-inorganic hybird nanoflower (activated hNF-lipase) exhibited 460% and 200% higher activity than native lipase and conventional lipase-inorganic hybird nanoflower (hNF-lipase). Furthermore, the activated hNF-lipase displayed good reusability due to its monodispersity and mechanical properties, and had excellent long-time stability. The superior catalytic performances were attributed to both the conformational modulation of surfactants and hierarchical structure of nanoflowers, which not only anchored lipases in an active form, but also decreased the enzyme-support negative interaction and mass-transfer limitations. This new biocatalytic system is promising to find widespread use in applications related to biomedicine, biosensor, and biodiesel. PMID:27297609

  3. ES and H-compatible lubrication for duplex bearings

    Steinhoff, R.G.

    1997-10-01

    Two ES and H-compatible lubricants (environment, safety, and health) for duplex bearing applications and one hybrid material duplex bearing were evaluated and compared against duplex bearings with trichlorotrifluoroethane (Freon) deposition of low molecular weight polytetrafluoroethylene (PTFE) bearing lubricant extracted from Vydax{trademark}. Vydax is a product manufactured by DuPont consisting of various molecular weights of PTFE suspended in trichlorotrifluoroethane (Freon), which is an ozone-depleting solvent. Vydax has been used as a bearing lubricant in strong link mechanisms since 1974. Hybrid duplex bearings with silicon nitride balls and molded glass-nylon-Teflon retainers, duplex bearings lubricated with sputtered MoS{sub 2} on races and retainers, and duplex bearings lubricated with electrophoretic deposited MoS{sub 2} were evaluated. Bearings with electrophoretic deposited MoS{sub 2} performed as well as bearings with Freon deposition of PTFE from Freon-based Vydax. Hybrid bearings with silicon nitride balls performed worse than bearings lubricated with Vydax, but their performance would still be acceptable for most applications. Bearings lubricated with sputtered MoS{sub 2} on the races and retainers had varying amounts of film on the bearings. This affected the performance of the bearings. Bearings with a uniform coating performed to acceptable levels, but bearings with no visible MoS{sub 2} on the races and retainers did not perform as well as bearings with the other coatings. Unless process controls are incorporated in the sputtering process or the bearings are screened, they do not appear to be acceptable for duplex bearing applications.

  4. Active Low Intrusion Hybrid Monitor for Wireless Sensor Networks

    Navia, Marlon; Campelo, Jose C.; Bonastre, Alberto; Ors, Rafael; Capella, Juan V.; Serrano, Juan J.

    2015-01-01

    Several systems have been proposed to monitor wireless sensor networks (WSN). These systems may be active (causing a high degree of intrusion) or passive (low observability inside the nodes). This paper presents the implementation of an active hybrid (hardware and software) monitor with low intrusion. It is based on the addition to the sensor node of a monitor node (hardware part) which, through a standard interface, is able to receive the monitoring information sent by a piece of software executed in the sensor node. The intrusion on time, code, and energy caused in the sensor nodes by the monitor is evaluated as a function of data size and the interface used. Then different interfaces, commonly available in sensor nodes, are evaluated: serial transmission (USART), serial peripheral interface (SPI), and parallel. The proposed hybrid monitor provides highly detailed information, barely disturbed by the measurement tool (interference), about the behavior of the WSN that may be used to evaluate many properties such as performance, dependability, security, etc. Monitor nodes are self-powered and may be removed after the monitoring campaign to be reused in other campaigns and/or WSNs. No other hardware-independent monitoring platforms with such low interference have been found in the literature. PMID:26393604

  5. Active Low Intrusion Hybrid Monitor for Wireless Sensor Networks.

    Navia, Marlon; Campelo, Jose C; Bonastre, Alberto; Ors, Rafael; Capella, Juan V; Serrano, Juan J

    2015-01-01

    Several systems have been proposed to monitor wireless sensor networks (WSN). These systems may be active (causing a high degree of intrusion) or passive (low observability inside the nodes). This paper presents the implementation of an active hybrid (hardware and software) monitor with low intrusion. It is based on the addition to the sensor node of a monitor node (hardware part) which, through a standard interface, is able to receive the monitoring information sent by a piece of software executed in the sensor node. The intrusion on time, code, and energy caused in the sensor nodes by the monitor is evaluated as a function of data size and the interface used. Then different interfaces, commonly available in sensor nodes, are evaluated: serial transmission (USART), serial peripheral interface (SPI), and parallel. The proposed hybrid monitor provides highly detailed information, barely disturbed by the measurement tool (interference), about the behavior of the WSN that may be used to evaluate many properties such as performance, dependability, security, etc. Monitor nodes are self-powered and may be removed after the monitoring campaign to be reused in other campaigns and/or WSNs. No other hardware-independent monitoring platforms with such low interference have been found in the literature. PMID:26393604

  6. Active Low Intrusion Hybrid Monitor for Wireless Sensor Networks

    Marlon Navia

    2015-09-01

    Full Text Available Several systems have been proposed to monitor wireless sensor networks (WSN. These systems may be active (causing a high degree of intrusion or passive (low observability inside the nodes. This paper presents the implementation of an active hybrid (hardware and software monitor with low intrusion. It is based on the addition to the sensor node of a monitor node (hardware part which, through a standard interface, is able to receive the monitoring information sent by a piece of software executed in the sensor node. The intrusion on time, code, and energy caused in the sensor nodes by the monitor is evaluated as a function of data size and the interface used. Then different interfaces, commonly available in sensor nodes, are evaluated: serial transmission (USART, serial peripheral interface (SPI, and parallel. The proposed hybrid monitor provides highly detailed information, barely disturbed by the measurement tool (interference, about the behavior of the WSN that may be used to evaluate many properties such as performance, dependability, security, etc. Monitor nodes are self-powered and may be removed after the monitoring campaign to be reused in other campaigns and/or WSNs. No other hardware-independent monitoring platforms with such low interference have been found in the literature.

  7. Voltage harmonics mitigation through hybrid active power filer

    Fast dynamic response, high efficiency, low cost and small size of power electronic converters have exponentially increased their use in modern power system which resulted in harmonically distorted voltage and currents. Voltage harmonics mainly caused by current harmonics are more dangerous as performance and expected operating life of other power system equipment are affected by harmonically distorted supply voltage. Electronic filter circuits are used to improve system power quality by mitigating adverse effects of harmonics. Hybrid filters having advantages of both passive and active filters are preferred to resolve the problem of harmonics efficiently and avoiding any chance of resonance. In this paper, a three phase three wire network is considered to supply an adjustable speed drive represented by a resistive load connected across a three phase bridge rectifier. Simulation of the considered system shows THD (Total Harmonic Distortion) of 18.91 and 7.61 percentage in supply current and voltage respectively. A HAPF (Hybrid Active Power Filter) is proposed to reduce these THD values below 5 percentage as recommended by IEEE Standard-519. P-Q theorem is used to calculate required parameters for proposed filter, which is implemented through hysteresis control. Simulation results confirm the effectiveness of the designed filter as THD for both current and voltage have reduced below allowable limit of 5 percentage. (author)

  8. Voltage Harmonics Mitigation through Hybrid Active Power Filter

    Anwer Ali Sahito

    2016-01-01

    Full Text Available Fast dynamic response, high efficiency, low cost and small size of power electronic converters have exponentially increased their use in modern power system which resulted in harmonically distorted voltage and currents. Voltage harmonics mainly caused by current harmonics are more dangerous as performance and expected operating life of other power system equipment are affected by harmonically distorted supply voltage. Electronic filter circuits are used to improve system power quality by mitigating adverse effects of harmonics. Hybrid filters having advantages of both passive and active filters are preferred to resolve the problem of harmonics efficiently and avoiding any chance of resonance. In this paper, a three phase three wire network is considered to supply an adjustable speed drive represented by a resistive load connected across a three phase bridge rectifier. Simulation of the considered system shows THD (Total Harmonic Distortion of 18.91 and 7.61% in supply current and voltage respectively. A HAPF (Hybrid Active Power Filter is proposed to reduce these THD values below 5% as recommended by IEEE Standard-519. P-Q theorem is used to calculate required parameters for proposed filter, which is implemented through hysteresis control. Simulation results confirm the effectiveness of the designed filter as THD for both current and voltage have reduced below allowable limit of 5%.

  9. Multifunctional Chitosan-Copper Oxide Hybrid Material: Photocatalytic and Antibacterial Activities

    Yuvaraj Haldorai; Jae-Jin Shim

    2013-01-01

    Chitosan (CS) anchored copper oxide (CuO) hybrid material was prepared by chemical precipitation method. Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) confirmed the formation of CS-CuO hybrid. Transmission electron microscopy (TEM) analysis showed the immobilization of CuO nanoparticles on the surface of CS. The hybrid was also characterized by thermogravimetric analysis (TGA) and zeta potential. The hybrid exhibited high photocatalytic activity as evident from t...

  10. Active space debris removal by a hybrid propulsion module

    DeLuca, L. T.; Bernelli, F.; Maggi, F.; Tadini, P.; Pardini, C.; Anselmo, L.; Grassi, M.; Pavarin, D.; Francesconi, A.; Branz, F.; Chiesa, S.; Viola, N.; Bonnal, C.; Trushlyakov, V.; Belokonov, I.

    2013-10-01

    During the last 40 years, the mass of the artificial objects in orbit increased quite steadily at the rate of about 145 metric tons annually, leading to a total tally of approximately 7000 metric tons. Now, most of the cross-sectional area and mass (97% in LEO) is concentrated in about 4600 intact objects, i.e. abandoned spacecraft and rocket bodies, plus a further 1000 operational spacecraft. Simulations and parametric analyses have shown that the most efficient and effective way to prevent the outbreak of a long-term exponential growth of the catalogued debris population would be to remove enough cross-sectional area and mass from densely populated orbits. In practice, according to the most recent NASA results, the active yearly removal of approximately 0.1% of the abandoned intact objects would be sufficient to stabilize the catalogued debris in low Earth orbit, together with the worldwide adoption of mitigation measures. The candidate targets for removal would have typical masses between 500 and 1000 kg, in the case of spacecraft, and of more than 1000 kg, in the case of rocket upper stages. Current data suggest that optimal active debris removal missions should be carried out in a few critical altitude-inclination bands. This paper deals with the feasibility study of a mission in which the debris is removed by using a hybrid propulsion module as propulsion unit. Specifically, the engine is transferred from a servicing platform to the debris target by a robotic arm so to perform a controlled disposal. Hybrid rocket technology for de-orbiting applications is considered a valuable option due to high specific impulse, intrinsic safety, thrust throttle ability, low environmental impact and reduced operating costs. Typically, in hybrid rockets a gaseous or liquid oxidizer is injected into the combustion chamber along the axial direction to burn a solid fuel. However, the use of tangential injection on a solid grain Pancake Geometry allows for more compact design of

  11. MWCNT/CdS hybrid nanocomposite for enhanced photocatalytic activity

    Chaudhary, Deepti; Khare, Neeraj; Vankar, V. D.

    2016-05-01

    Multi-walled carbon nanotubes (MWCNT)/CdS hybrid nanocomposite were synthesized by one step hydrothermal method. MWCNTs were used as a substrate for the growth of CdS nanoparticles. MWCNT/CdS nanocomposite and pure CdS were characterized by XRD, TEM, UV-vis and photoluminescence spectroscopy. HRTEM study confirms the intimate contact of CdS with MWCNT. The photocatalytic activity of nanocomposite was studied for the degradation of methylene blue dye under UV irradiation. The enhanced photocatalytic activity of MWCNT/CdS nanocomposite as compared to pure CdS has been attributed to reduced recombination of photogenerated charge carriers due to interfacial electron transfer from CdS to MWCNT.

  12. Influence of service temperature on tribological characteristics of self-lubricant coatings: A review

    Jun-Feng YANG; Yan JIANG; Jens HARDELL; Braham PRAKASH; Qian-Feng FANG

    2013-01-01

    Self-lubricating coatings have been widely used to reduce friction in moving machine assemblies. However, the tribological performance of these coatings is strongly dependent on the service temperature. In this paper, an extensive review pertaining to the influence of operating service temperature on tribological performance of self-lubricating coatings has been carried out. Based on the effective lubricating temperature range, the self-lubricating coatings developed in the past have been divided into three groups: low temperature lubricant coating (from -200℃ to room temperature), moderate temperature lubricant coating (from room temperature to 500℃) and high temperature lubricant coating (〉 500℃). Ideas concerning possible ways to extend the operating temperature range of self-lubricating coatings have been presented as follows: hybridized tribological coating, adaptive tribological coatings, and diffusion rate limited solid lubricant coating, in addition, a new self-lubricating coating formulation for potential application at a wide operating temperature range has been proposed.

  13. Temperature dependence on the synthesis of Jatropha bio lubricant

    Full text: Jatropha oil has good potential as the renewable energy as well as lubricant feedstock. The synthesis of jatropha bio lubricant was performed by transesterification of jatropha methyl ester (JME) with trimethyl-ol-propane (TMP) with sodium methoxide (NaOCH3) catalyst. The effects of temperature on the synthesis were studied at a range between 120 degree Celsius and 200 degree Celsius with pressure kept at 10 mbar. The conversion of JME to jatropha bio lubricant was found to be the highest (47 %) at 200 degree Celsius. However, it was suggested that the optimum temperature of the reaction is at 150 degree Celsius due to insignificant improvement in bio lubricant production. To maintain forward reaction, the excess amount of JME was maintained at 3.9:1 ratios to TMP. Kinetic study was done and compared. The synthesis was found to follow a second order reaction with overall rate constant of 1.49 x 10-1 (% wt/ wt.min.degree Celsius)-1. The estimated activation energy was 3.94 kJ/mol. Pour point for jatropha bio lubricant was at -3 degree Celsius and Viscosity Index (VI) ranged from 178 to 183. The basic properties of jatropha bio lubricant, pour point and viscosities are found comparable to other plant based bio lubricant, namely palm oil and soybean based bio lubricant. (author)

  14. Mixed lubricated line contacts

    Faraon, Irinel Cosmin

    2005-01-01

    The present work deals with friction in mixed lubricated line contacts. Components in systems are becoming smaller and due to, for instance power transmitted, partial contact may occur. In industrial applications, friction between the moving contacting surfaces cannot be avoided, therefore it is ess

  15. Glass microsphere lubrication

    Geiger, Michelle; Goode, Henry; Ohanlon, Sean; Pieloch, Stuart; Sorrells, Cindy; Willette, Chris

    1991-01-01

    The harsh lunar environment eliminated the consideration of most lubricants used on earth. Considering that the majority of the surface of the moon consists of sand, the elements that make up this mixture were analyzed. According to previous space missions, a large portion of the moon's surface is made up of fine grained crystalline rock, about 0.02 to 0.05 mm in size. These fine grained particles can be divided into four groups: lunar rock fragments, glasses, agglutinates (rock particles, crystals, or glasses), and fragments of meteorite material (rare). Analysis of the soil obtained from the missions has given chemical compositions of its materials. It is about 53 to 63 percent oxygen, 16 to 22 percent silicon, 10 to 16 percent sulfur, 5 to 9 percent aluminum, and has lesser amounts of magnesium, carbon, and sodium. To be self-supporting, the lubricant must utilize one or more of the above elements. Considering that the element must be easy to extract and readily manipulated, silicon or glass was the most logical choice. Being a ceramic, glass has a high strength and excellent resistance to temperature. The glass would also not contaminate the environment as it comes directly from it. If sand entered a bearing lubricated with grease, the lubricant would eventually fail and the shaft would bind, causing damage to the system. In a bearing lubricated with a solid glass lubricant, sand would be ground up and have little effect on the system. The next issue was what shape to form the glass in. Solid glass spheres was the only logical choice. The strength of the glass and its endurance would be optimal in this form. To behave as an effective lubricant, the diameter of the spheres would have to be very small, on the order of hundreds of microns or less. This would allow smaller clearances between the bearing and the shaft, and less material would be needed. The production of glass microspheres was divided into two parts, production and sorting. Production includes the

  16. Carbon-based tribofilms from lubricating oils.

    Erdemir, Ali; Ramirez, Giovanni; Eryilmaz, Osman L; Narayanan, Badri; Liao, Yifeng; Kamath, Ganesh; Sankaranarayanan, Subramanian K R S

    2016-08-01

    Moving mechanical interfaces are commonly lubricated and separated by a combination of fluid films and solid 'tribofilms', which together ensure easy slippage and long wear life. The efficacy of the fluid film is governed by the viscosity of the base oil in the lubricant; the efficacy of the solid tribofilm, which is produced as a result of sliding contact between moving parts, relies upon the effectiveness of the lubricant's anti-wear additive (typically zinc dialkyldithiophosphate). Minimizing friction and wear continues to be a challenge, and recent efforts have focused on enhancing the anti-friction and anti-wear properties of lubricants by incorporating inorganic nanoparticles and ionic liquids. Here, we describe the in operando formation of carbon-based tribofilms via dissociative extraction from base-oil molecules on catalytically active, sliding nanometre-scale crystalline surfaces, enabling base oils to provide not only the fluid but also the solid tribofilm. We study nanocrystalline catalytic coatings composed of nitrides of either molybdenum or vanadium, containing either copper or nickel catalysts, respectively. Structurally, the resulting tribofilms are similar to diamond-like carbon. Ball-on-disk tests at contact pressures of 1.3 gigapascals reveal that these tribofilms nearly eliminate wear, and provide lower friction than tribofilms formed with zinc dialkyldithiophosphate. Reactive and ab initio molecular-dynamics simulations show that the catalytic action of the coatings facilitates dehydrogenation of linear olefins in the lubricating oil and random scission of their carbon-carbon backbones; the products recombine to nucleate and grow a compact, amorphous lubricating tribofilm. PMID:27488799

  17. Limits of Lubrication in

    Olsson, David Dam

    Strategic stainless steel surfaces have been developed and investigated during the project in close cooperation with the Department of Chemistry, DTU with the purpose of enhancing the tribological properties. This has been achieved successfully by applying electrochemical treatments of normal as...... delivered stainless steel surfaces implying microstructure changes in terms of larger ratio of closed lubricant pockets due to selective grain boundary etching. Strategic surfaces have also been created by macroscopic texturing using spherical indentations having a very small edge slope in order to promote...... using plain mineral oil is possible without any lubricant breakdown. In deep drawing, 2mm stainless steel blanks can be drawn to drawing ratio of DR=2.0 over a die entry radius of rd=3mm again using a plain mineral oil containing no additives. In stretch forming, friction is reduced considerably by...

  18. Creatinyl amino acids: new hybrid compounds with neuroprotective activity.

    Burov, Sergey; Leko, Maria; Dorosh, Marina; Dobrodumov, Anatoliy; Veselkina, Olga

    2011-09-01

    Prolonged oral creatine administration resulted in remarkable neuroprotection in experimental models of brain stroke. However, because of its polar nature creatine has poor ability to penetrate the blood-brain barrier (BBB) without specific creatine transporter (CRT). Thus, synthesis of hydrophobic derivatives capable of crossing the BBB by alternative pathway is of great importance for the treatment of acute and chronic neurological diseases including stroke, traumatic brain injury and hereditary CRT deficiency. Here we describe synthesis of new hybrid compounds-creatinyl amino acids, their neuroprotective activity in vivo and stability to degradation in different media. The title compounds were synthesized by guanidinylation of corresponding sarcosyl peptides or direct creatine attachment using isobutyl chloroformate method. Addition of lipophilic counterion (p-toluenesulfonate) ensures efficient creatine dissolution in DMF with simultaneous protection of guanidino group towards intramolecular cyclization. It excludes the application of expensive guanidinylating reagents, permits to simplify synthetic procedure and adapt it to large-scale production. The biological activity of creatinyl amino acids was tested in vivo on ischemic stroke and NaNO(2) -induced hypoxia models. One of the most effective compounds-creatinyl-glycine ethyl ester increases life span of experimental animals more than two times in hypoxia model and has neuroprotective action in brain stroke model when applied both before and after ischemia. These data evidenced that creatinyl amino acids can represent promising candidates for the development of new drugs useful in stroke treatment. PMID:21644247

  19. Cooling lubricants; Kuehlschmierstoffe

    Pfeiffer, W. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Breuer, D. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Blome, H. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Deininger, C. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Hahn, J.U. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Kleine, H. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Nies, E. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Pflaumbaum, W. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Stockmann, R. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Willert, G. [Berufsgenossenschaftliches Inst. fuer Arbeitssicherheit, St. Augustin (Germany); Sonnenschein, G. [Maschinenbau- und Metall-Berufsgenossenschaft, Duesseldorf (Germany)

    1996-08-01

    As a rule, the base substances used are certain liquid hydrocarbons from mineral oils as well as from native and synthetic oils. Through the addition of further substances the cooling lubricant takes on the particular qualities required for the use in question. Employees working with cooling lubricants are exposed to various hazards. The assessment of the concentrations at the work station is carried out on the basis of existing technical rules for contact with hazardous substances. However, the application/implementation of compulsory investigation and supervision in accordance with these rules is made difficult by the fact that cooling lubricants are, as a rule, made up of complicated compound mixtures. In addition to protecting employees from exposure to mists and vapours from the cooling lubricants, protection for the skin is also of particular importance. Cooling lubricants should not, if at all possible, be brought into contact with the skin. Cleansing the skin and skin care is just as important as changing working clothes regularly, and hygiene and cleanliness at the workplace. Unavoidable emissions are to be immediately collected at the point where they arise or are released and safely disposed of. This means taking into account all sources of emissions. The programme presented in this report therefore gives a very detailed account of the individual protective measures and provides recommendations for the design of technical protection facilities. (orig./MG) [Deutsch] Als Basisstoffe dienen in der Regel bestimmte fluessige Kohlenwasserstoffverbindungen aus Mineraloelen sowie aus nativen oder synthetischen Oelen. Durch die Zugabe von weiteren Stoffen erlangt der Kuehlschmierstoff seine fuer den jeweiligen Anwendungsabfall geforderten Eigenschaften. Beschaeftigte, die mit Kuehlschmierstoffen umgehen, sind unterschiedliche Gefahren ausgesetzt. Die Beurteilung der Kuehlschmierstoffkonzentrationen in der Luft am Arbeitsplatz erfolgt auf der Grundlage bestehender

  20. Green Lubricants for Metal Forming

    Bay, Niels

    The increasing focus on legislation towards diminishing the impact on working environment as well as external environment has driven efforts to develop new, environmentally benign lubricants for metal forming. The present paper gives an overview of these efforts to substitute environmentally haza...... hazardous lubricants in cold, warm and hot forging as well as sheet forming and punching/blanking with new, less harmful lubricants.......The increasing focus on legislation towards diminishing the impact on working environment as well as external environment has driven efforts to develop new, environmentally benign lubricants for metal forming. The present paper gives an overview of these efforts to substitute environmentally...

  1. Stability Analysis of an Industrial Gas Compressor Supported by Tilting-Pad Bearings Under Different Lubrication Regimes

    Cerda, Alejandro; Santos, Ilmar

    2012-01-01

    This work is aimed at a theoretical study of the dynamic behavior of a rotor-tilting pad journal bearing (TPJB) system under different lubrication regimes, namely, thermohydrodynamic (THD), elastohydrodynamic (EHD), and hybrid lubrication regime. The rotor modeled corresponds to an industrial...

  2. High Performing PFPE Nanofluid Lubricants Project

    National Aeronautics and Space Administration — Space missions could benefit from improved lubricant technology. PSI intends to develop novel liquid lubricant formulations which are applicable for future NASA...

  3. Improved Ionic Liquids as Space Lubricants Project

    National Aeronautics and Space Administration — Ionic liquids are candidate lubricant materials. However for application in low temperature space mechanisms their lubrication performance needs to be enhanced. UES...

  4. Halden Project activities relating to hybrid control room automation systems

    This paper is a high-level presentation of OECD Halden Reactor projects activities that relate to hybrid control room design, implementation and V and V. The Halden Project has a long tradition working on the human factors related aspects influencing the usability of any (hybrid) control room. Yet, the paper start out with a review of experiences on a much broader scale that takes into account many other contributing factors involved in a control room upgrade projects, e.g. change management principles, work procedures and methods, communication and crew interaction as well as crew training. The reported review was implemented back in 2001 but it is deemed of current value to many planned and ongoing control room upgrade projects. The reported project distributed a questionnaire to obtain input from as many industry contracts and members of the HPG as possible. The review is thus a synthesis of experiences and opinions of the persons and organizations participating. Next, the paper presents a selection of human factors issues that should be taken into account when doing control room design and upgrades. Moreover, some methods to implement V and V related to these issues are presented - some of which are based on experiments in a simulator environment. These V and V methods are exemplified by a few real plant upgrades in which HRP staff acted as consultants. The paper ends with a description of an ongoing project that uses virtual reality (VR) technology to enable the study of human factors issues at a very early stage during the design process. Applying VR for this purpose has obvious potential advantages as it can be used to identify costly errors within the design. It has already been proven that VR can be used to improve the communication within the design team, establishing a common reference model that can be understood by all members of the team. It is hoped that functional- and job analysis directly supported by the visualization of planned control room

  5. Carbon-based tribofilms from lubricating oils

    Erdemir, Ali; Ramirez, Giovanni; Eryilmaz, Osman L.; Narayanan, Badri; Liao, Yifeng; Kamath, Ganesh; Sankaranarayanan, Subramanian K. R. S.

    2016-08-01

    Moving mechanical interfaces are commonly lubricated and separated by a combination of fluid films and solid ‘tribofilms’, which together ensure easy slippage and long wear life. The efficacy of the fluid film is governed by the viscosity of the base oil in the lubricant; the efficacy of the solid tribofilm, which is produced as a result of sliding contact between moving parts, relies upon the effectiveness of the lubricant’s anti-wear additive (typically zinc dialkyldithiophosphate). Minimizing friction and wear continues to be a challenge, and recent efforts have focused on enhancing the anti-friction and anti-wear properties of lubricants by incorporating inorganic nanoparticles and ionic liquids. Here, we describe the in operando formation of carbon-based tribofilms via dissociative extraction from base-oil molecules on catalytically active, sliding nanometre-scale crystalline surfaces, enabling base oils to provide not only the fluid but also the solid tribofilm. We study nanocrystalline catalytic coatings composed of nitrides of either molybdenum or vanadium, containing either copper or nickel catalysts, respectively. Structurally, the resulting tribofilms are similar to diamond-like carbon. Ball-on-disk tests at contact pressures of 1.3 gigapascals reveal that these tribofilms nearly eliminate wear, and provide lower friction than tribofilms formed with zinc dialkyldithiophosphate. Reactive and ab initio molecular-dynamics simulations show that the catalytic action of the coatings facilitates dehydrogenation of linear olefins in the lubricating oil and random scission of their carbon–carbon backbones; the products recombine to nucleate and grow a compact, amorphous lubricating tribofilm.

  6. Wastewater treatment in a hybrid activated sludge baffled reactor

    A novel hybrid activated sludge baffled reactor (HASBR), which contained both suspended and attached-growth biomass perfect mixing cells in series, was developed by installing standing and hanging baffles and introducing plastic brushes into a conventional activated sludge (CAS) reactor. It was used for the treatment of domestic wastewater. The effects on the operational performance of developing the suspended and attached-growth biomass and reactor configuration were investigated. The change of the flow regime from complete-mix to plug-flow, and the addition of plastic brushes as a support for biofilm, resulted in considerable improvements in the COD, nitrogen removal efficiency of domestic wastewater and sludge settling properties. In steady state, approximately 98 ± 2% of the total COD and 98 ± 2% of the ammonia of the influent were removed in the HASBR, when the influent wastewater concentration was 593 ± 11 mg COD/L and 43 ± 5 mg N/L, respectively, at a HRT of 10 h. These results were 93 ± 3 and 6 ± 3% for the CAS reactor, respectively. Approximately 90 ± 7% of the total COD was removed in the HASBR, when the influent wastewater concentration was 654 ± 16 mg COD/L at a 3 h HRT, and in the organic loading rate (OLR) of 5.36 kg COD m-3 day-1. The result for the CAS reactor was 60 ± 3%. Existing CAS plants can be upgraded by changing the reactor configuration and introducing biofilm support media into the aeration tank

  7. Evaluating Solid-Lubricant Films

    Fusaro, Robert L.

    1988-01-01

    Report describes experimental techniques for measuring properties of solid-lubricant films. Discusses experimental parameters. Reviews basic pin-on-disk configurations and methods of preparing disks and applying solid lubricants. Techniques for constant-temperature testing, low-contact-stress testing, and temperature-versus-time testing presented. Suggests methods of measuring pin-wear volume and recommends ways of presenting data.

  8. Self lubricating fluid bearings

    The invention concerns self lubricating fluid bearings, which are used in a shaft sealed system extending two regions. These regions contain fluids, which have to be isolated. A first seal is fluid tight for the first region between the carter shaft and the shaft. The second seal is fluid tight between the carter and the shaft, it communicates with the second region. The first fluid region is the environment surrounding the shaft carter. The second fluid region is a part of a nuclear reactor which contains the cooling fluid. The shaft is conceived to drive a reactor circulating and cooling fluid

  9. Improving Diagnosability of Hybrid Systems through Active Diagnosis

    National Aeronautics and Space Administration — Fault diagnosis is key to ensuring system safety through fault-adaptive control. This task is diffcult in hybrid systems with combined continuous and discrete...

  10. Optical Imaging of Water Condensation on Lubricant Impregnated Micropillar Arrays

    Kajiya, Tadashi; Schellenberger, Frank; Papadopoulos, Periklis; Vollmer, Doris; Butt, Hans-Jürgen

    2015-11-01

    We explored the condensation of water drops on a lubricant-impregnated surface, i.e., a micropillar patterned surface impregnated with a ionic liquid. Growing drops were imaged in 3D using a laser scanning confocal microscope equipped with a temperature and humidity control. On a lubricant-impregnated hydrophobic micropillar array, different stages of condensation can be discriminated: - Nucleation on a lubricant surface. - Regular alignement between micropillars and formation of a three-phase contact line on a bottom of the substrate. - Deformation and bridging by coalescence, leading to a detachment of the drops from the bottom substrate to pillars'top faces. However, on a lubricant-impregnated hydrophilic micropillar array, the condensed water covers the micropillars by dewetting the lubricant. As a result, the surface loses its slippery property. Our results provide fundamental concepts how these solid/liquid hybrid surfaces can be applied for facile removal of condensed water, as well as necessity of the appropriate surface treatment. Financial support from ERC for the advanced grant 340391-SUPRO is gratefully acknowledged.

  11. Lubrication of soft viscoelastic solids

    Pandey, Anupam; Venner, Kees; Snoeijer, Jacco

    2015-01-01

    Lubrication flows appear in many applications in engineering, biophysics, and in nature. Separation of surfaces and minimisation of friction and wear is achieved when the lubrication fluid builds up a lift force. In this paper we analyse soft lubricated contacts by treating the solid walls as viscoelastic: soft materials are typically not purely elastic, but dissipate energy under dynamical loading conditions. We present a method for viscoelastic lubrication and focus on three canonical examples, namely Kelvin-Voigt-, Standard Linear-, and Power Law-rheology. It is shown how the solid viscoelasticity affects the lubrication process when the timescale of loading becomes comparable to the rheological timescale. We derive asymptotic relations between lift force and sliding velocity, which give scaling laws that inherit a signature of the rheology. In all cases the lift is found to decrease with respect to purely elastic systems.

  12. Biodegradation of pharmaceuticals in hospital wastewater by a hybrid biofilm and activated sludge system (Hybas)

    Escola Casas, Monica; Chhetri, Ravi Kumar; Ooi, Gordon Tze Hoong;

    2015-01-01

    Hospital wastewater contributes a significant input of pharmaceuticals into municipal wastewater. The combination of suspended activated sludge and biofilm processes, as stand-alone or as hybrid process, has been suggested as a possible solution for hospital wastewater treatment. HybasTM is a...... hybrid process, based on the integrated fixed-film activated sludge technology, where plastic carriers for biofilm growth are suspended within activated sludge. To investigate the potential of a hybrid system for the removal of pharmaceuticals in hospital wastewater a pilot plant consisting of a series...

  13. Technological lubricating means: Evolution of materials and ideas

    Godlevskiy, Vladimir A.

    2016-03-01

    The main stages of technological lubricating material development from ancient times to date are described. How the chemical composition of these products changed with time, how new ideas revealing the physical and chemical basics of external media that influence the mechanical processing of materials appeared, how these ideas explained the differences between traditional tribology and specific technology of metal processing are discussed. The question of the possible realization of Rehbinder's adsorption effect in contact zone is also stated. The description of a very captivating problem is related to the explanation of the mechanism of lubricant penetration into the contact zone between the material being processed and the tool. The birth and development of the hypothesis of microcapillary penetration of the lubricant into the dynamically changed intersurface clearance that has finally led to formulating the "necessary kinetic condition of the lubricating activity" is relayed.

  14. Agent-based power sharing scheme for active hybrid power sources

    Jiang, Zhenhua

    The active hybridization technique provides an effective approach to combining the best properties of a heterogeneous set of power sources to achieve higher energy density, power density and fuel efficiency. Active hybrid power sources can be used to power hybrid electric vehicles with selected combinations of internal combustion engines, fuel cells, batteries, and/or supercapacitors. They can be deployed in all-electric ships to build a distributed electric power system. They can also be used in a bulk power system to construct an autonomous distributed energy system. An important aspect in designing an active hybrid power source is to find a suitable control strategy that can manage the active power sharing and take advantage of the inherent scalability and robustness benefits of the hybrid system. This paper presents an agent-based power sharing scheme for active hybrid power sources. To demonstrate the effectiveness of the proposed agent-based power sharing scheme, simulation studies are performed for a hybrid power source that can be used in a solar car as the main propulsion power module. Simulation results clearly indicate that the agent-based control framework is effective to coordinate the various energy sources and manage the power/voltage profiles.

  15. One-step electrochemical synthesis of a graphene–ZnO hybrid for improved photocatalytic activity

    Graphical abstract: - Highlights: • Graphene–ZnO hybrid was synthesized by one-step electrochemical deposition. • Graphene–ZnO hybrid presents a special structure and wide UV–vis absorption spectra. • Graphene–ZnO hybrid exhibits an exceptionally higher photocatalytic activity for the degradation of dye methylene blue. - Abstract: A graphene–ZnO (G-ZnO) hybrid was synthesized by one-step electrochemical deposition. During the formation of ZnO nanostructure by cathodic electrochemical deposition, the graphene oxide was electrochemically reduced to graphene simultaneously. Scanning electron microscope images, X-ray photoelectron spectroscopy, X-ray diffraction, Raman spectra, and UV–vis absorption spectra indicate the resulting G-ZnO hybrid presents a special structure and wide UV–vis absorption spectra. More importantly, it exhibits an exceptionally higher photocatalytic activity for the degradation of dye methylene blue than that of pure ZnO nanostructure under both ultraviolet and sunlight irradiation

  16. Automotive gear oil lubricant from soybean oil

    The use of lubricants that are based on renewable materials is rapidly increasing. Vegetable oils have good lubricity, wear protection and low volatility which are desired properties for automotive gear lubricant applications. Soybean oil is used widely in the lubricant industry due to its properti...

  17. Antifungal Activity and Action Mechanism of Histatin 5-Halocidin Hybrid Peptides against Candida ssp.

    Juhye Han

    Full Text Available The candidacidal activity of histatin 5 is initiated through cell wall binding, followed by translocation and intracellular targeting, while the halocidin peptide exerts its activity by attacking the Candida cell membrane. To improve antimicrobial activities and to understand the killing mechanism of two peptides, six hybrid peptides were designed by conjugating histatin 5 and halocidin. A comparative approach was established to study the activity, salt tolerance, cell wall glucan binding assay, cytotoxicity, generation of ROS and killing kinetics. CD spectrometry was conducted to evaluate secondary structures of these hybrid peptides. Furthermore the cellular localization of hybrid peptides was investigated by confocal fluorescence microscopy. Of the six hybrid congeners, di-PH2, di-WP2 and HHP1 had stronger activities than other hybrid peptides against all tested Candida strains. The MIC values of these peptides were 1-2, 2-4 and 2-4 μg/ml, respectively. Moreover, none of the hybrid peptides was cytotoxic in the hemolytic assay and cell-based cytotoxicity assay. Confocal laser microscopy showed that di-PH2 and HHP1 were translocated into cytoplasm whereas di-WP2 was accumulated on surface of C. albicans to exert their candidacidal activity. All translocated peptides (Hst 5, P113, di-PH2 were capable of generating intracellular ROS except HHP1. Additionally, the KFH residues at C-terminal end of these peptides were assumed for core sequence for active translocation.

  18. Advances in lubrication technology and modelling. Novel nanoscale friction modifiers - Piezoviscosity effect in EHL contacts

    Petrone, Vincenzo

    2014-01-01

    2012 - 2013 Lubricant additives have an important influence on the lubrication performances. These additives are active ingredients which can be added during a blending process to base oils in order either to enhance the existing performance of the base fluids or to impart new properties that the base fluids lack. In modern industry, the ever growing demand on the duration and efficiency of machineries stimulates the research for lubricant additives with better performance. At the same tim...

  19. Controllable Lubrication for Main Engine Bearings Using Mechanical and Piezoelectric Actuators

    Estupinan, Edgar; Santos, Ilmar

    2012-01-01

    Although mechatronic systems are nowadays implemented in a large number of systems in vehicles, active lubrication systems are still incipient in industrial applications. This study is an attempt to extend the active lubrication concept to combustion engines and gives a theoretical contribution t...

  20. Structural lubricity under ambient conditions

    Cihan, Ebru; İpek, Semran; Durgun, Engin; Baykara, Mehmet Z.

    2016-01-01

    Despite its fundamental importance, physical mechanisms that govern friction are poorly understood. While a state of ultra-low friction, termed structural lubricity, is expected for any clean, atomically flat interface consisting of two different materials with incommensurate structures, some associated predictions could only be quantitatively confirmed under ultra-high vacuum (UHV) conditions so far. Here, we report structurally lubric sliding under ambient conditions at mesoscopic (∼4,000–130,000 nm2) interfaces formed by gold islands on graphite. Ab initio calculations reveal that the gold–graphite interface is expected to remain largely free from contaminant molecules, leading to structurally lubric sliding. The experiments reported here demonstrate the potential for practical lubrication schemes for micro- and nano-electromechanical systems, which would mainly rely on an atomic-scale structural mismatch between the slider and substrate components, via the utilization of material systems featuring clean, atomically flat interfaces under ambient conditions. PMID:27350035

  1. Synthesis and anticancer activity of novel curcumin-quinolone hybrids.

    Raghavan, Saiharish; Manogaran, Prasath; Gadepalli Narasimha, Krishna Kumari; Kalpattu Kuppusami, Balasubramanian; Mariyappan, Palanivelu; Gopalakrishnan, Anjana; Venkatraman, Ganesh

    2015-09-01

    A number of new curcumin-quinolone hybrids were synthesised from differently substituted 3-formyl-2-quinolones and vanillin and their in vitro cytotoxicity was determined on a panel of representative cell lines (A549, MCF7, SKOV3 and H460) using MTT assay. The most potent compound 14, was analysed for its mode of action using various cell biology experiments. SKOV3 cells treated with compound 14 showed distorted cell morphology under phase contrast imaging and induction of apoptosis was confirmed by Annexin V/PE assay. Further experiments on generation of reactive oxygen species (ROS) and cell cycle analysis revealed that these hybrids induce apoptosis by ROS generation and arrest cell cycle progression in S and G2/M phase. PMID:26174555

  2. Polymer/Perovskite Amplifying Waveguides for Active Hybrid Silicon Photonics.

    Suárez, Isaac; Juárez-Pérez, Emilio J; Bisquert, Juan; Mora-Seró, Iván; Martínez-Pastor, Juan P

    2015-10-28

    The emission properties of hybrid halide perovskites are exploited to implement a stable and very low power operation waveguide optical amplifier integrated in a silicon platform. By optimizing its design with a poly(methyl methacrylate) (PMMA) encapsulation, this novel photonic device presents a net gain of around 10 dB cm(-1) and 3-4 nm linewidth with an energy threshold as low as 2 nJ pulse(-1) and exhibiting no degradation after one year. PMID:26331838

  3. Biodegradable lubricants for road vehicles

    Schramm, J. [Denmark Technical Univ., Lyngby (Denmark). Dept. of Mechanical Engineering

    2004-07-01

    This presentation outlined the characteristics of biolubricants and their use in vehicles. Experiments with compression ignition (CI) and spark ignition (SI) engines were also presented. Biolubes can be used in 4-stroke and 2-stroke engines, bearing compressors and hydraulic equipment. Studies have shown that biolubes do not cause unusual engine wear. They are produced from biomass, with the base material being vegetable oils and synthetic esters. Conventional lubricants are produced from fossil fuels, with the base material being mineral oils, polyglycol or synthetic ester. This presentation rated the characteristics of various lubricants in terms of viscosity temperature behaviour, low temperature behaviour, liquid range, oxidation stability, thermal stability, volatility, fire resistance, hydrolytic stability, corrosion protection, seal material compatibility, paints compatibility, miscibility with mineral oil, solubility of additives, lubricating properties, toxicity, and biodegradability. The environmental impacts of biolubes regarding emissions of carbon dioxide, nitrous oxide and particulate matter were discussed along with the impact of combining biolubes with alternative fuels. The future beneficial applications include outboard engines, off road vehicle engines and road vehicle engines. Currently, vegetable oil based biolubricants are 2 to 3 times more expensive than mineral based oils, and synthetic lubricants are even more expensive. It was suggested that future studies should examine the biodegradability of used lubricants, the performance of biodegradable lubricants, alternative fuels and fuel economy. tabs., figs.

  4. Biosynthesis of mesoporous organic-inorganic hybrid Fe2O3 with high photocatalytic activity

    A very simple approach with yeast cells as a biotemplate was proposed to synthesize a mesoporous hybrid Fe2O3 photocatalyst. The mesoporous structure of the resultant samples was characterized by BET, N2 adsorption-desorption isotherms (NADI) and transmission electron microscopy (TEM). The chemical bond linkages in hybrid Fe2O3 samples were confirmed by Fourier transform infrared spectroscopy (FT-IR). The catalytic activities of mesoporous hybrid Fe2O3 on degradation of methyl orange were investigated under UV-light irradiation. The hybrid Fe2O3 (yeast cell amount is 0.6 g) samples dried at 80 deg. C and calcined at 300 deg. C exhibit high surface area and photocatalytic activity.

  5. The molluscicidal activities of some Euphorbia milii hybrids against the snail Indoplanorbis exustus.

    Sermsart, Bunguorn; Sripochang, Somphong; Suvajeejarun, Thongdee; Kiatfuengfoo, Rachada

    2005-01-01

    The objective of this study was to observe the molluscicidal activities of Euphorbia milli, known as "poysean" in Thailand, against Indoplanorbis exustus. Latex from 12 different E. milii hybrids was screened for its molluscicidal activities. Indoplanorbis exustus were exposed for 24 and 48 hours to the latex at various concentrations ranging from 6 to 25 ppm and mortality rates were recorded. Eight hybrids of latex were effective. The six most effective hybrids were E. milii Dang-udom, E. milii Arunroong, E. milii Raweechotchuong, E. milii Srisompote, E. milii Sri-umporn and E. milii Tongnopakun, which killed all snails after 24 hours of exposure. Under the same conditions, latex of E. milii Dowpraket and E. milii Promsatid killed 50% of the snails. Such results indicate that these 6 hybrids seem promising as natural molluscicidal agents. PMID:16438208

  6. Hybrid Active Filter with Variable Conductance for Harmonic Resonance Suppression in Industrial Power Systems

    Lee, Tzung-Lin; Wang, Yen-Ching; Li, Jian-Cheng;

    2015-01-01

    Unintentional series and/or parallel resonances, due to the tuned passive filter and the line inductance, may result in severe harmonic distortion in the industrial power system. This paper presents a hybrid active filter to suppress harmonic resonance and reduce harmonic distortion as well....... The proposed hybrid filter is operated as variable harmonic conductance according to the voltage total harmonic distortion, so harmonic distortion can be reduced to an acceptable level in response to load change or parameter variation of power system. Since the hybrid filter is composed of a seventh......-tuned passive filter and an active filter in series connection, both dc voltage and kVA rating of the active filter are dramatically decreased compared with the pure shunt active filter. In real application, this feature is very attractive since the active power filter with fully power electronics is very...

  7. Analysis on mechanism of thin film lubrication

    ZHANG Chaohui; LUO Jianbin; HUANG Zhiqiang

    2005-01-01

    It is an important concern to explore the properties and principles of lubrication at nano or molecularscale. For a long time, measurement apparatus for filmthickness of thin film lubrication (TFL) at nano scale havebeen devised on the basis of superthin interferometry technique. Many experiments were carried out to study the lubrication principles of TFL by taking advantages of aforementioned techniques, in an attempt to unveil the mechanism of TFL. Comprehensive experiments were conducted to explore the distinctive characteristics of TFL. Results show that TFL is a distinctive lubrication state other than any known lubrication ones, and serves as a bridge between elastohydrodynamic lubrication (EHL) and boundary lubrication (BL). Two main influence factors of TFL are the solid surface effects and the molecular properties of the lubricant, whose combination effects result in alignment of liquid molecules near the solid surfaces and subsequently lubrication with ordered film emerged. Results of theoretical analysis considering microstructure are consistent with experimental outcomes, thus validating the proposed mechanism.

  8. Preparation of zeolite-A/chitosan hybrid composites and their bioactivities and antimicrobial activities

    Yu, Liang; Gong, Jie [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China); Zeng, Changfeng [College of Mechanic and Power Engineering, Nanjing University of Technology, Nanjing 210009 (China); Zhang, Lixiong, E-mail: lixiongzhang@yahoo.com [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China)

    2013-10-15

    Zeolite-A/chitosan hybrid composites with zeolite contents of 20–55 wt.% were prepared by in situ transformation of silica/chitosan mixtures in a sodium aluminate alkaline solution through impregnation–gelation–hydrothermal synthesis. The products were characterized by X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy, scanning electron microscopy, thermogravimetric analysis, and mercury penetration porosimetry. Their in vitro bioactivities were examined using as-synthesized and Ca{sup 2+}-exchanged hybrid composites in simulated body fluid (SBF) for hydroxyapatite (HAP) growth. Their antimicrobial activities for Escherichia coli (E. coli) in trypticase soy broth (TSB) were evaluated using Ag{sup +}-exchanged hybrid composites. The zeolite-A/chitosan hybrid composites could be prepared as various shapes, including cylinders, plates and thin films. They possessed macropores with pore sizes ranging from 100 to 300 μm and showed compressive mechanical strength as high as 3.2 MPa when the zeolite content was 35 wt.%. Fast growth on the Ca{sup 2+}-exchanged hybrid composites was observed with the highest weight gain of 51.4% in 30 days. The 35 wt.% Ag{sup +}-exchanged hybrid composite showed the highest antimicrobial activity, which could reduce the 9 × 10{sup 6} CFU mL{sup −1}E. coli concentration to zero within 4 h of incubation time with the Ag{sup +}-exchanged hybrid composite amount of 0.4 g L{sup −1}. The bioactivity and antimicrobial activity could be combined by ion-exchanging the composites first with Ca{sup 2+} and then with Ag{sup +}. These zeolite-A/chitosan hybrid composites have potential applications on tissue engineering and antimicrobial food packaging. - Graphical abstract: Zeolite A/chitosan hybrid composites were prepared by in situ transformation of precursors in the chitosan matrix, which possess macroporous structures and exhibit superior bioactivity and antimicrobial activity and potential biomedical

  9. Preparation of zeolite-A/chitosan hybrid composites and their bioactivities and antimicrobial activities

    Zeolite-A/chitosan hybrid composites with zeolite contents of 20–55 wt.% were prepared by in situ transformation of silica/chitosan mixtures in a sodium aluminate alkaline solution through impregnation–gelation–hydrothermal synthesis. The products were characterized by X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy, scanning electron microscopy, thermogravimetric analysis, and mercury penetration porosimetry. Their in vitro bioactivities were examined using as-synthesized and Ca2+-exchanged hybrid composites in simulated body fluid (SBF) for hydroxyapatite (HAP) growth. Their antimicrobial activities for Escherichia coli (E. coli) in trypticase soy broth (TSB) were evaluated using Ag+-exchanged hybrid composites. The zeolite-A/chitosan hybrid composites could be prepared as various shapes, including cylinders, plates and thin films. They possessed macropores with pore sizes ranging from 100 to 300 μm and showed compressive mechanical strength as high as 3.2 MPa when the zeolite content was 35 wt.%. Fast growth on the Ca2+-exchanged hybrid composites was observed with the highest weight gain of 51.4% in 30 days. The 35 wt.% Ag+-exchanged hybrid composite showed the highest antimicrobial activity, which could reduce the 9 × 106 CFU mL−1E. coli concentration to zero within 4 h of incubation time with the Ag+-exchanged hybrid composite amount of 0.4 g L−1. The bioactivity and antimicrobial activity could be combined by ion-exchanging the composites first with Ca2+ and then with Ag+. These zeolite-A/chitosan hybrid composites have potential applications on tissue engineering and antimicrobial food packaging. - Graphical abstract: Zeolite A/chitosan hybrid composites were prepared by in situ transformation of precursors in the chitosan matrix, which possess macroporous structures and exhibit superior bioactivity and antimicrobial activity and potential biomedical application. Highlights: • Zeolite A/chitosan hybrid composites

  10. Digital Simulation of a Hybrid Active Filter - An Active Filter in Series with a Shunt Passive Filter

    Sitaram, Mahesh I; Padiyar, KR; Ramanarayanan, V

    1998-01-01

    Active filters have long been in use for the filtering of power system load harmonics. In this paper, the digital simulation results of a hybrid active power filter system for a rectifier load are presented. The active filter is used for filtering higher order harmonics as the dominant harmonics are filtered by the passive filter. This reduces the rating of the active filter significantly. The DC capacitor voltage of the active filter is controlled using a PI controller.

  11. Activation of different split functionalities on re-association of RNA-DNA hybrids

    Afonin, Kirill A.; Viard, Mathias; Martins, Angelica N.; Lockett, Stephen J.; Maciag, Anna E.; Freed, Eric O.; Heldman, Eliahu; Jaeger, Luc; Blumenthal, Robert; Shapiro, Bruce A.

    2013-04-01

    Split-protein systems, an approach that relies on fragmentation of proteins with their further conditional re-association to form functional complexes, are increasingly used for various biomedical applications. This approach offers tight control of protein functions and improved detection sensitivity. Here we report a similar technique based on a pair of RNA-DNA hybrids that can be used generally for triggering different split functionalities. Individually, each hybrid is inactive but when two cognate hybrids re-associate, different functionalities are triggered inside mammalian cells. As a proof of concept, this work mainly focuses on the activation of RNA interference. However, the release of other functionalities (such as resonance energy transfer and RNA aptamer) is also shown. Furthermore, in vivo studies demonstrate a significant uptake of the hybrids by tumours together with specific gene silencing. This split-functionality approach presents a new route in the development of `smart' nucleic acid-based nanoparticles and switches for various biomedical applications.

  12. Continuous cellularization of calcium phosphate hybrid scaffolds induced by plasma polymer activation.

    Bergemann, Claudia; Cornelsen, Matthias; Quade, Antje; Laube, Thorsten; Schnabelrauch, Matthias; Rebl, Henrike; Weißmann, Volker; Seitz, Hermann; Nebe, Barbara

    2016-02-01

    The generation of hybrid materials based on β-tricalcium phosphate (TCP) and various biodegradable polymers like poly(l-lactide-co-d,l-lactide) (PLA) represents a common approach to overcoming the disadvantages of pure TCP devices. These disadvantages lie in TCP's mechanical properties, such as brittleness. The positive characteristic of PLA - improvement of compressive strength of calcium phosphate scaffolds - is diametrically opposed to its cell attractiveness. Therefore, the objective of this work was to optimize osteoblast migration and cellularization inside a three-dimensionally (3D) printed, PLA polymer stabilized TCP hybrid scaffold by a plasma polymer process depositing amino groups via allylamine. MG-63 osteoblastic cells inside the 10mm hybrid scaffold were dynamically cultivated for 14days in a 3D model system integrated in a perfusion reactor. The whole TCP/PLA hybrid scaffold was continuously colonized due to plasma polymerized allylamine activation inducing the migration potential of osteoblasts. PMID:26652403

  13. Investigation of the Wheel-Flange Lubrication of Railway Trains

    A tracer method was applied to investigate the wheel-flange lubrication action of the new Austrian multiple-unit train ''Transalpin''. On electric engines the flanges of the first pair of wheels are lubricated by a pendulum oil pump. This pump starts to work when there is lateral movement of the engine in curves or at high speed on straight lines. The lubricating oil is transferred, while the train is underway, from the first wheel to the inner surface of the rail. From there it should be taken up by the following wheels of the train. In this way the friction between the rails and the wheel flanges can be reduced and as a consequence the wear of material is decreased. Until the present investigation it has not been possible to get quantitative information about the action of this type of lubrication. By adding the tracer 198Au in the form of a colloid to the lubricating oil (specific activity 0.5 Ci/litre), quantitative measurements of the oil transport mechanism could be made on the moving train. The detection of the labelled lubricant was possible even on the last wheels of a train of 44 axles. The oil films which were still detectable on the wheel flanges had a thickness of about 0. 3 microns. By this tracer method, the dependence of lubrication on the speed and the line conditions can also be determined. The tracer method has a wide range of applications in the study of underway conditions in railroad operation including the investigation of the sine movement of trains. (author)

  14. Ionic Liquids as Novel Lubricants and /or Lubricant Additives

    Qu, J. [ORNL; Viola, M. B. [General Motors Company

    2013-10-31

    This ORNL-GM CRADA developed ionic liquids (ILs) as novel lubricants or oil additives for engine lubrication. A new group of oil-miscible ILs have been designed and synthesized with high thermal stability, non-corrosiveness, excellent wettability, and most importantly effective anti-scuffing/anti-wear and friction reduction characteristics. Mechanistic analysis attributes the superior lubricating performance of IL additives to their physical and chemical interactions with metallic surfaces. Working with a leading lubricant formulation company, the team has successfully developed a prototype low-viscosity engine oil using a phosphonium-phosphate IL as an anti-wear additive. Tribological bench tests of the IL-additized formulated oil showed 20-33% lower friction in mixed and elastohydrodynamic lubrication and 38-92% lower wear in boundary lubrication when compared with commercial Mobil 1 and Mobil Clean 5W-30 engine oils. High-temperature, high load (HTHL) full-size engine tests confirmed the excellent anti-wear performance for the IL-additized engine oil. Sequence VID engine dynamometer tests demonstrated an improved fuel economy by >2% for this IL-additized engine oil benchmarked against the Mobil 1 5W-30 oil. In addition, accelerated catalyst aging tests suggest that the IL additive may potentially have less adverse impact on three-way catalysts compared to the conventional ZDDP. Follow-on research is needed for further development and optimization of IL chemistry and oil formulation to fully meet ILSAC GF-5 specifications and further enhance the automotive engine efficiency and durability.

  15. Top-of-Rail lubricant

    Alzoubi, M. F.; Fenske, G. R.; Erck, R. A.; Boparai, A. S.

    2000-07-14

    Analysis of the volatile and semivolatile fractions collected after use of the TOR lubricant indicated that other than contaminants in the collection laboratory, no compounds on the EPA's Target Compound Lists (Tables 2 and 5) were detected in these fractions. The data of these qualitative analyses, given in the various tables in the text, indicate only the relative amounts of the tentatively identified compounds. The authors recommend that quantitative analysis be performed on the volatile and semivolatile fractions to allow confirmation of the tentatively identified compounds and to obtain absolute amounts of the detected compounds. Additionally, the semivolatile fraction should be analyzed by liquid chromatography/mass spectrometry to identify compounds that are not chromatographable under the temperature program used for determination of semivolatile compounds. Introducing the top-of-rail (TOR) lubricant into the wheel/rail interface results in a reduction of almost 60% of lateral friction force over the forces encountered under dry conditions. This reveals good potential for energy savings, as well as wear reduction, for railroad companies. In TOR lubrication, an increase in the angle of attack and axle load results in increased lateral friction and rate of lubricant consumption. The most efficient TOR lubricant quantity to be used in the wheel/rail interface must be calculated precisely according to the number of cars, axle loads, train speed, and angle of attack.

  16. Metalworking corrosion inhibition/drawing lubricant

    Lipinski, H.F.; Wantling, S.J.

    1980-05-06

    A metalworking lubricant composition is disclosed which is effective as both a corrosion inhibitor and drawing lubricant and comprises a mineral oil and an additive combination of barium lanolate soap and barium sulfonate.

  17. Effect of surface condition on the formation of solid lubricating films at high temperatures

    Hanyaloglu, Bengi; Graham, E. E.

    1992-01-01

    Solid films were produced on active metal or ceramic surfaces using lubricants (such as tricresyl phosphate) delivered as a vapor at high temperatures, and the lubricity of these deposits under different dynamic wear conditions was investigated. A method is described for chemically activating ceramic surfaces resulting in a surface that could promote the formation of lubricating polymeric derivative of TCP. Experiments were carried out to evaluate the wear characteristics of unlubricated cast iron and of Sialon ceramic at 25 and 280 C, and lubricated with a vapor of TCP at 280 C. It is shown that continuous vapor phase lubrication of chemically treated Sialon reduced its coefficient of friction from 0.7 to less than 0.1.

  18. Biodegradation and toxicological evaluation of lubricant oils

    Ivo Shodji Tamada; Paulo Renato Matos Lopes; Renato Nallin Montagnolli; Ederio Dino Bidoia

    2012-01-01

    The aim of this work was to compare different toxicity levels of lubricant oils. The tests were performed using the earthworm (Eisenia andrei), arugula seeds (Eruca sativa) and lettuce seeds (Lactuca sativa), with three types of contaminants (mineral lubricant oil, synthetic lubricant oil and used lubricant oil) for various biodegradation periods in the soil. The toxicity tests indirectly measured the biodegradation of the contaminants. The samples were analyzed at t0, t60, t120 and t180 days...

  19. CYLINDER AND SYSTEM LUBRICATING OILS

    ION ADRIAN GIRBA

    2016-06-01

    Full Text Available Increased thermal efficiency, savings in the fuel consumption and the possibility to burn low quality fuels conducted to an intense development of marine engines in past 20 years, this progress being emphasized by the increased combustion pressures and better combustion properties. These improvements represent a continuous challenge for lubricating oil manufacturers: the rise in combustion temperatures and pressures is making difficult to preserve the oil film in critical areas and the longer strokes of the piston leads to issues of spreading the oil. Adding here the new type of engines using gas or biofuel which requires different types of lubricating oils. Therefore, the success of new generation of engines will depend on lubricating oils quality. :

  20. Tethered Lubricants for Small Systems

    Lynden A. Archer

    2006-01-09

    The objective of this research project is two-fold. First, to fundamentally understand friction and relaxation dynamics of polymer chains near surfaces; and second, to develop novel self-lubricated substrates suitable for MEMS devices. During the three-year performance period of this study the PI and his students have shown using theory and experiments that systematic introduction of disorder into tethered lubricant coatings (e.g. by using self-assembled monolayer (SAM) mixtures or SAMs with nonlinear, branched architectures) can be used to significantly reduce the friction coefficient of a surface. They have also developed a simple procedure based on dielectric spectroscopy for quantifying the effect of surface disorder on molecular relaxation in lubricant coatings. Details of research accomplishments in each area of the project are described in the body of the report.

  1. HybridPLAY: A New Technology to Foster Outdoors Physical Activity, Verbal Communication and Teamwork.

    Díaz, Diego José; Boj, Clara; Portalés, Cristina

    2016-01-01

    This paper presents HybridPLAY, a novel technology composed of a sensor and mobile-based video games that transforms urban playgrounds into game scenarios. With this technology we aim to stimulate physical activity and playful learning by creating an entertaining environment in which users can actively participate and collaborate. HybridPLAY is different from other existing technologies that enhance playgrounds, as it is not integrated in them but can be attached to the different elements of the playgrounds, making its use more ubiquitous (i.e., not restricted to the playgrounds). HybridPLAY was born in 2007 as an artistic concept, and evolved after different phases of research and testing by almost 2000 users around the world (in workshops, artistic events, conferences, etc.). Here, we present the temporal evolution of HybridPLAY with the different versions of the sensors and the video games, and a detailed technical description of the sensors and the way interactions are produced. We also present the outcomes after the evaluation by users at different events and workshops. We believe that HybridPLAY has great potential to contribute to increased physical activity in kids, and also to improve the learning process and monitoring at school centres by letting users create the content of the apps, leading to new narratives and fostering creativity. PMID:27120601

  2. HybridPLAY: A New Technology to Foster Outdoors Physical Activity, Verbal Communication and Teamwork

    Díaz, Diego José; Boj, Clara; Portalés, Cristina

    2016-01-01

    This paper presents HybridPLAY, a novel technology composed of a sensor and mobile-based video games that transforms urban playgrounds into game scenarios. With this technology we aim to stimulate physical activity and playful learning by creating an entertaining environment in which users can actively participate and collaborate. HybridPLAY is different from other existing technologies that enhance playgrounds, as it is not integrated in them but can be attached to the different elements of the playgrounds, making its use more ubiquitous (i.e., not restricted to the playgrounds). HybridPLAY was born in 2007 as an artistic concept, and evolved after different phases of research and testing by almost 2000 users around the world (in workshops, artistic events, conferences, etc.). Here, we present the temporal evolution of HybridPLAY with the different versions of the sensors and the video games, and a detailed technical description of the sensors and the way interactions are produced. We also present the outcomes after the evaluation by users at different events and workshops. We believe that HybridPLAY has great potential to contribute to increased physical activity in kids, and also to improve the learning process and monitoring at school centres by letting users create the content of the apps, leading to new narratives and fostering creativity. PMID:27120601

  3. Evaluation of methods for extraction of the volitional EMG in dynamic hybrid muscle activation

    Mizrahi Joseph

    2006-11-01

    Full Text Available Abstract Background Hybrid muscle activation is a modality used for muscle force enhancement, in which muscle contraction is generated from two different excitation sources: volitional and external, by means of electrical stimulation (ES. Under hybrid activation, the overall EMG signal is the combination of the volitional and ES-induced components. In this study, we developed a computational scheme to extract the volitional EMG envelope from the overall dynamic EMG signal, to serve as an input signal for control purposes, and for evaluation of muscle forces. Methods A "synthetic" database was created from in-vivo experiments on the Tibialis Anterior of the right foot to emulate hybrid EMG signals, including the volitional and induced components. The database was used to evaluate the results obtained from six signal processing schemes, including seven different modules for filtration, rectification and ES component removal. The schemes differed from each other by their module combinations, as follows: blocking window only, comb filter only, blocking window and comb filter, blocking window and peak envelope, comb filter and peak envelope and, finally, blocking window, comb filter and peak envelope. Results and conclusion The results showed that the scheme including all the modules led to an excellent approximation of the volitional EMG envelope, as extracted from the hybrid signal, and underlined the importance of the artifact blocking window module in the process. The results of this work have direct implications on the development of hybrid muscle activation rehabilitation systems for the enhancement of weakened muscles.

  4. HybridPLAY: A New Technology to Foster Outdoors Physical Activity, Verbal Communication and Teamwork

    Diego José Díaz

    2016-04-01

    Full Text Available This paper presents HybridPLAY, a novel technology composed of a sensor and mobile-based video games that transforms urban playgrounds into game scenarios. With this technology we aim to stimulate physical activity and playful learning by creating an entertaining environment in which users can actively participate and collaborate. HybridPLAY is different from other existing technologies that enhance playgrounds, as it is not integrated in them but can be attached to the different elements of the playgrounds, making its use more ubiquitous (i.e., not restricted to the playgrounds. HybridPLAY was born in 2007 as an artistic concept, and evolved after different phases of research and testing by almost 2000 users around the world (in workshops, artistic events, conferences, etc.. Here, we present the temporal evolution of HybridPLAY with the different versions of the sensors and the video games, and a detailed technical description of the sensors and the way interactions are produced. We also present the outcomes after the evaluation by users at different events and workshops. We believe that HybridPLAY has great potential to contribute to increased physical activity in kids, and also to improve the learning process and monitoring at school centres by letting users create the content of the apps, leading to new narratives and fostering creativity.

  5. The Electrochemical Characteristics of Hybrid Capacitor Prepared by Chemical Activation of NaOH

    Choi, Jeong Eun; Bae, Ga Yeong; Yang, Jeong Min; Lee, Jong Dae [Chungbuk National Univ., Chungju (Korea, Republic of)

    2013-06-15

    Active carbons with high specific surface area and micro pore structure were prepared from the coconut shell char using the chemical activation method of NaOH. The preparation process has been optimized through the analysis of experimental variables such as activating chemical agents to char ratio and the flow rate of gas during carbonization. The active carbons with the surface area (2,481m{sup 2}/g) and mean pore size (2.32 nm) were obtained by chemical activation with NaOH. The electrochemical performances of hybrid capacitor were investigated using LiMn{sub 2}O{sub 4}, LiCoO{sub 2} as the positive electrode and prepared active carbon as the negative electrode. The electrochemical behaviors of hybrid capacitor using organic electrolytes (LiPF{sub 6}, TEABF{sub 4}) were characterized by constant current charge/discharge, cyclic voltammetry, cycle and leakage tests. The hybrid capacitor using LiMn{sub 2}O{sub 4}/AC electrodes had better capacitance than other hybrid systems and was able to deliver a specific energy as high as 131 Wh/kg at a specific power of 1,448 W/kg.

  6. Growth and opportunities in the lubricants business in Asia

    The demand for lubricants is increasing faster in Asia than any other part of the world. This development is being propelled largely by the expansion of the transportation and manufacturing sectors. By the year 2000, lubricant consumption in Asia will exceed that of Western Europe, Africa and the Middle East combined. Aside from this growth, most of the region is shifting from very low quality to higher quality value-added products. In view of these factors, there has been an explosion of activity over the past few years as lubricant blenders and additive suppliers attempt to position themselves within the market. Over the past year, Chem Systems has undertaken an extensive study of the lubricants business in East Asia, focusing on the evolution of this complex market structure and the identification of attractive opportunities. The overview presented in this paper is a product of these efforts. Whether you are a multinational oil company, independent blender, national oil company or multinational additive suppler, the questions are the same when developing a strategy for the region: regional overview of lubricant business structure; outlook for Asian demand; profile of lube/additives businesses; and successful competition--what is required?

  7. Laboratory services series: a lubrication program

    Bowen, H.B.; Miller, T.L.

    1976-05-01

    The diversity of equipment and operating conditions at a major national research and development laboratory requires a systematic, effective lubrication program. The various phases of this program and the techniques employed in formulating and administering this program are discussed under the following topics: Equipment Identification, Lubrication Requirements, Assortment of Lubricants, Personnel, and Scheduling.

  8. A new lubricant carrier for metal forming

    Arentoft, Mogens; Bay, Niels; Tang, Peter Torben;

    2009-01-01

    A lubricant carrier for metal forming processes is developed. Surfaces with pores of micrometer size for entrapping lubricant are generated by electrochemical deposition of an alloy, consisting of two immiscible metals, of which one metal subsequently is etched away leaving 5 mu m layers with a s...... extrusion at high reduction and excessive stroke comparing with conventionally lubrication using phosphate coating and soap....

  9. Improving the vibration suppression capabilities of a magneto-rheological damper using hybrid active and semi-active control

    Ullah Khan, Irfan; Wagg, David; Sims, Neil D.

    2016-08-01

    This paper presents a new hybrid active and semi-active control method for vibration suppression in flexible structures. The method uses a combination of a semi-active device and an active control actuator situated elsewhere in the structure to suppress vibrations. The key novelty is to use the hybrid controller to enable the magneto-rheological damper to achieve a performance as close to a fully active device as possible. This is achieved by ensuring that the active actuator can assist the magneto-rheological damper in the regions where energy is required. In addition, the hybrid active and semi-active controller is designed to minimize the switching of the semi-active controller. The control framework used is the immersion and invariance control technique in combination with sliding mode control. A two degree-of-freedom system with lightly damped resonances is used as an example system. Both numerical and experimental results are generated for this system, and then compared as part of a validation study. The experimental system uses hardware-in-the-loop to simulate the effect of both the degrees-of-freedom. The results show that the concept is viable both numerically and experimentally, and improved vibration suppression results can be obtained for the magneto-rheological damper that approach the performance of an active device.

  10. Lubrication greases for nuclear reactors

    Lubricating greases are essential components of many machines used in nuclear power plants. Where these machines are subject to radiation the life of the grease will be reduced due to deterioration of the components of the grease. According to the chemical nature of the grease used a greater or lesser resistance to radiation will be observed. Tests and techniques to evaluate the performance of greases before and after irradiation are described. The results of these tests show that conventional premium greases will resist comparatively low levels of irradiation, whilst greases formulated from correctly selected components can tolerate quite high levels of radiation permitting the machines they lubricate to attain their designed service lives

  11. Hybrid energy storage systems utilizing redox active organic compounds

    Wang, Wei; Xu, Wu; Li, Liyu; Yang, Zhenguo

    2015-09-08

    Redox flow batteries (RFB) have attracted considerable interest due to their ability to store large amounts of power and energy. Non-aqueous energy storage systems that utilize at least some aspects of RFB systems are attractive because they can offer an expansion of the operating potential window, which can improve on the system energy and power densities. One example of such systems has a separator separating first and second electrodes. The first electrode includes a first current collector and volume containing a first active material. The second electrode includes a second current collector and volume containing a second active material. During operation, the first source provides a flow of first active material to the first volume. The first active material includes a redox active organic compound dissolved in a non-aqueous, liquid electrolyte and the second active material includes a redox active metal.

  12. Feasibility of Applying Controllable Lubrication to Dynamically Loaded Journal Bearings

    Estupinan, Edgar Alberto; Santos, Ilmar

    2009-01-01

    fluid films, based on fluid film theory. For a dynamically loaded journal bearing, the fluid film pressure distribution can be computed by numerically solving the Reynolds equation, by means of finite-difference method. Particularly, in this study the main focus is on the lubrication behavior of the...... reaction forces in a reciprocating compressor have a cyclic behavior, periodic oil pressure injection rules based on the instantaneous crank angle and load bearing condition can be established. In this paper, several bearing configurations working under different oil pressure injection rules conditions are...... analyzed. The behavior of the following parameters is investigated when the system operates with hybrid controllable lubrication conditions: a) maximum fluid film pressure, b) minimum fluid film thickness, c) maximum vibration levels and d) injection oil pressures....

  13. Phosphorous digestibility and activity of intestinal phytase in hybrid tilapia, Oreochromis niloticus X O. aureus

    La Vorgna, M.W.; Hafez, Y.; Hughes, S.G.; Handwerker, T.

    2003-01-01

    Experiments were conducted to determine the degree to which phytate-bound phosphorus from plant protein sources could be used by hybrid tilapia (Oreochromis niloticus X O. aureus). Utilizing an inert marker technique with chromic oxide, hybrid tilapia in our study were effective at utilizing both inorganic and phytate phosphorus as evidenced by average apparent digestibility values of 93.2% and 90.0% for total and phytate phosphorus, respectively. Analysis of the intestinal brush border membrane of the tilapia revealed enzyme activity that was capable of hydrolyzing phytic acid. The presence of phytic acid hydrolyzing enzyme activity in the intestinal brush border provides a probable mechanism by which these hybrid tilapia are able to utilize phytate phosphorus effectively. ?? 2003 by The Haworth Press, Inc. All rights reserved.

  14. Hybrid active-passive constrained layer damping treatments in beams, plates and shells

    Koh, Byungjun

    2016-01-01

    The basic concept of Hybrid Active-Passive Constrained Layer Damping (HAPCLD) treatment was proposed by introducing active control to the concept of passive constrained layer damping configuration in the 1990s to compensate for weak points in active and passive controls by using their respective merits for more robust and stable control. Since then, combinations of various configurations and applicable control strategies have been proposed and studied in many engineering areas. However, there...

  15. New approach in lubrication engineering using neutron reflectometry

    According to historic papers in lubrication engineering, lubrication modes between two solids are essentially classified into three groups - boundary lubrication, mixed lubrication and full-film lubrication. This paper proposed some novel approaches for elucidation of lubrication phenomena using neutron reflectometry. For the studies on boundary lubrication, the neutron reflectometry is helpful to in-situ observe the 'absorbed layer' near the solid surface, while for the studies on full-film lubrication, it can reveal the density of lubricants at the solid-liquid interface. Those information will help to clarify the friction mechanism under lubrication in the field of tribology. (author)

  16. Design of embedded-hybrid antimicrobial peptides with enhanced cell selectivity and anti-biofilm activity.

    Wei Xu

    Full Text Available Antimicrobial peptides have attracted considerable attention because of their broad-spectrum antimicrobial activity and their low prognostic to induce antibiotic resistance which is the most common source of failure in bacterial infection treatment along with biofilms. The method to design hybrid peptide integrating different functional domains of peptides has many advantages. In this study, we designed an embedded-hybrid peptide R-FV-I16 by replacing a functional defective sequence RR7 with the anti-biofilm sequence FV7 embedded in the middle position of peptide RI16. The results demonstrated that the synthetic hybrid the peptide R-FV-I16 had potent antimicrobial activity over a wide range of Gram-negative and Gram-positive bacteria, as well as anti-biofilm activity. More importantly, R-FV-I16 showed lower hemolytic activity and cytotoxicity. Fluorescent assays demonstrated that R-FV-I16 depolarized the outer and the inner bacterial membranes, while scanning electron microscopy and transmission electron microscopy further indicated that this peptide killed bacterial cells by disrupting the cell membrane, thereby damaging membrane integrity. Results from SEM also provided evidence that R-FV-I16 inherited anti-biofilm activity from the functional peptide sequence FV7. Embedded-hybrid peptides could provide a new pattern for combining different functional domains and showing an effective avenue to screen for novel antimicrobial agents.

  17. Recent Progress on Cellulose-Based Electro-Active Paper, Its Hybrid Nanocomposites and Applications.

    Khan, Asif; Abas, Zafar; Kim, Heung Soo; Kim, Jaehwan

    2016-01-01

    We report on the recent progress and development of research into cellulose-based electro-active paper for bending actuators, bioelectronics devices, and electromechanical transducers. The cellulose electro-active paper is characterized in terms of its biodegradability, chirality, ample chemically modifying capacity, light weight, actuation capability, and ability to form hybrid nanocomposites. The mechanical, electrical, and chemical characterizations of the cellulose-based electro-active paper and its hybrid composites such as blends or coatings with synthetic polymers, biopolymers, carbon nanotubes, chitosan, and metal oxides, are explained. In addition, the integration of cellulose electro-active paper is highlighted to form various functional devices including but not limited to bending actuators, flexible speaker, strain sensors, energy harvesting transducers, biosensors, chemical sensors and transistors for electronic applications. The frontiers in cellulose paper devices are reviewed together with the strategies and perspectives of cellulose electro-active paper and cellulose nanocomposite research and applications. PMID:27472335

  18. Recent Progress on Cellulose-Based Electro-Active Paper, Its Hybrid Nanocomposites and Applications

    Asif Khan

    2016-07-01

    Full Text Available We report on the recent progress and development of research into cellulose-based electro-active paper for bending actuators, bioelectronics devices, and electromechanical transducers. The cellulose electro-active paper is characterized in terms of its biodegradability, chirality, ample chemically modifying capacity, light weight, actuation capability, and ability to form hybrid nanocomposites. The mechanical, electrical, and chemical characterizations of the cellulose-based electro-active paper and its hybrid composites such as blends or coatings with synthetic polymers, biopolymers, carbon nanotubes, chitosan, and metal oxides, are explained. In addition, the integration of cellulose electro-active paper is highlighted to form various functional devices including but not limited to bending actuators, flexible speaker, strain sensors, energy harvesting transducers, biosensors, chemical sensors and transistors for electronic applications. The frontiers in cellulose paper devices are reviewed together with the strategies and perspectives of cellulose electro-active paper and cellulose nanocomposite research and applications.

  19. Self lubrication of bitumen froth in pipelines

    Joseph, D.D. [Univ. of Minnesota, Minneapolis, MN (United States)

    1997-12-31

    In this paper I will review the main properties of water lubricated pipelines and explain some new features which have emerged from studies of self-lubrication of Syncrudes` bitumen froth. When heavy oils are lubricated with water, the water and oil are continuously injected into a pipeline and the water is stable when in a lubricating sheath around the oil core. In the case of bitumen froth obtained from the Alberta tar sands, the water is dispersed in the bitumen and it is liberated at the wall under shear; water injection is not necessary because the froth is self-lubricating.

  20. Kinetic analysis of enhanced biological phosphorus removal in a hybrid integrated fixed film activated sludge process

    Hybrid integrated fixed film activated sludge is a promising process for the enhancement of nitrification, denitrification and phosphorus removal in conventional activated sludge systems that can be used for upgrading biological nutrient removal, particularly when they have space limitations or need modifications that will require large monetary expenses. In this research, successful implementation of hybrid integrated fixed film activated sludge process at temperate zone wastewater treatment facilities has been studied by the placement of fixed film media into aerobic, anaerobic and anoxic zones. The primary objective of this study was to investigate the incorporation of enhanced biological phosphorus removal into hybrid integrated fixed film activated sludge systems and study the interactions between the fixed biomass and the mixed liquor suspended solids with respect to substrate competition and nutrient removal efficiencies. A pilot-scale anaerobic-anoxic-oxic configuration system was used. The system was operated at different mean cell residence times and influent chemical oxygen demand/total phosphorus ratios and with split influent flows. The experimental results confirmed that enhanced biological phosphorus removal could be incorporated successfully into hybrid integrated fixed film activated sludge system, but the redistribution of biomass resulting from the integration of fixed film media and the competition of organic substrate between enhanced biological phosphorus removal and denitrification would affect performances. Also, kinetic analysis of the reactor with regarding to phosphorus removal has been studied with different kinetic models and consequently the modified Stover-Kincannon kinetic model has been chosen for modeling studies and experimental data analysis of the hybrid integrated fixed film activated sludge reactor

  1. A Hybrid Estimator for Active/Reactive Power Control of Single-Phase Distributed Generation Systems with Energy Storage

    Pahlevani, Majid; Eren, Suzan; Guerrero, Josep M.;

    2016-01-01

    This paper presents a new active/reactive power closed-loop control system for a hybrid renewable energy generation system used for single-phase residential/commercial applications. The proposed active/reactive control method includes a hybrid estimator, which is able to quickly and accurately...

  2. Longevity Of Dry Film Lubricants

    Kannel, J. W.; Stockwell, R. D.

    1993-01-01

    Report describes evaluation of dry film lubricants candidate for use in rotary joints of proposed Space Station. Study included experiments and theoretical analyses focused on longevity of sputtered molybdenum disulfide films and ion-plated lead films under conditions partially simulating rolling contact.

  3. Vegetable oil basestocks for lubricants

    Garces, R.; Martinez-Force, E.; Salas, J.

    2011-07-01

    The use of vegetable biodegradable basestocks for lubricant oils present several advantages over the much more extended mineral bases. These advantages refer to biodegradability, a renewable feedstock of local production, lubricant and viscosity index and lower costs than synthetic lubricant bases. Despite these benefits, their use in industry and motor vehicles is not yet extensive due their lower stability and higher pour points. Vegetable oils are esters of fatty acids and glycerol, and their physicochemical properties rely mainly on the composition of their acyl moieties. Thus, to assure the maximum levels of stability while maintaining acceptable behavior at low temperatures, monounsaturated fatty acids are preferred for this purpose. The presence of natural antioxidants also improves the properties of these vegetable based stocks as lubricants. These oils usually require additives to improve their viscosity value, oxidative stability and properties at low temperatures. In the present work, the different sources of vegetable oils appropriate for biolubricant production were reviewed. Their properties and the future improvement of the oil bases, oil based stock production, uses and additives are discussed. (Author).

  4. Automotive Cooling and Lubricating Systems.

    Marine Corps Inst., Washington, DC.

    This correspondence course, originally developed for the Marine Corps, is designed to provide new mechanics with a source of study materials to assist them in becoming more proficient in their jobs. The course contains four study units covering automotive cooling system maintenance, cooling system repair, lubricating systems, and lubrication…

  5. Thin Film Solid Lubricant Development

    Benoy, Patricia A.

    1997-01-01

    Tribological coatings for high temperature sliding applications are addressed. A sputter-deposited bilayer coating of gold and chromium is investigated as a potential solid lubricant for protection of alumina substrates during sliding at high temperature. Evaluation of the tribological properties of alumina pins sliding against thin sputtered gold films on alumina substrates is presented.

  6. Full Life Wind Turbine Gearbox Lubricating Fluids

    Lutz, Glenn A.; Jungk, Manfred; Bryant, Jonathan J.; Lauer, Rebecca S.; Chobot, Anthony; Mayer, Tyler; Palmer, Shane; Kauffman, Robert E.

    2012-02-28

    using PFPE as the gearbox lubricating fluid. It is important to note the largest portion of savings comes in Levelized Replacement Cost, which is dictated by the assumption on gearbox reliability. Thus, verifying and quantifying the potential of PFPE fluid to effect gearbox reliability is the key assumption that would need to be further validated. In summary the proof of concept to use PFPE fluid as wind turbine gear box lubricant was validated with this project. The increase in life time was qualitatively demonstrated and this supports the need for future activity of field trials and laboratory aging studies to quantify the predicted 20 year life. With micro-pitting being the major failure mechanism in the last years, recent publications show that white etch cracking of bearings seem to have the highest impact on wind turbine reliability. With its higher film thicknesses compared to PAO reference oils, PFPE fluids have the potential to reduce this failure occurrence as well.

  7. Friction Regimes in the Lubricants Solid-State Regime

    Schipper, D.J.; Maathuis, O.; Dowson, D; Taylor, C.M.; Childs, T.H.C.; Dalmaz, G.

    1995-01-01

    Friction measurements were performed in the lubricant's solid-state regime to study the transition from full-film lubrication, in which the separation is maintained by a solidified lubricant, to mixed lubrication. Special attention is paid to the influence of temperature (inlet viscosity) and roughness on this transition. The friction measurements showed that in the lubricants solid-state region three lubrication modes can be distinguished: A) full-film lubrication; separation is maintained b...

  8. The vancomycin-nisin(1-12) hybrid restores activity against vancomycin resistant Enterococci.

    Arnusch, Christopher J; Bonvin, Alexandre M J J; Verel, Anne Marie; Jansen, Wouter T M; Liskamp, Rob M J; de Kruijff, Ben; Pieters, Roland J; Breukink, Eefjan

    2008-12-01

    Lipid II is a crucial component in bacterial cell wall synthesis [Breukink, E., et al. (1999) Science 286, 2361-2364]. It is the target of a number of important antibiotics, which include vancomycin and nisin [Breukink, E., and de Kruijff, B. (2006) Nat. Rev. Drug Discovery 5, 321-332]. Here we show that a hybrid antibiotic that consists of vancomycin and nisin fragments is significantly more active than the separate fragments against vancomycin resistant entercocci (VRE). Three different hybrids were synthesized using click chemistry and compared. Optimal spacer lengths and connection points were predicted using computer modeling. PMID:18989934

  9. Overview of PV Wind hybrid system activities in Germany

    Bopp, G.; Gabler, H.; Kiefer, K.; Preiser, K.; Wiemken, E. [Fraunhofer Institute for Solar Energy Systems ISE, Freiburg (Germany)

    1997-12-31

    Photovoltaic solar generators combined with diesel engines, in some cases additionally with wind energy converters, and battery energy storage are powering isolated mountain lodges, information centers in nature parks, isolated farms or dwellings all over Europe. A total of 300,000 buildings in Europe are estimated to be not connected to the public grid. This represents a major market potential for photovoltaic, as often photovoltaic power generation is less expensive than a connection to the electric utility. The Fraunhofer Institute for Solar Energy Systems ISE has planned, realized and monitored about 30 hybrid remote energy supply systems with PV generators typically around 5 kW for loads typically around 20 kWh per day. More than one hundred years of operational experience accumulated so far, are a sound foundation on which to draw an interim balance over problems solved and technical questions still under development. Room for further technical development is seen in the domain of system reliability and the reduction of operating costs as well as in the optimization of the utilization of the electric energy produced by the PV generator. [Espanol] Para la electrificacion en toda Europa de casas de campo en la montana, centros de informacion, parques naturales, granjas aisladas o conjuntos habitacionales, se estan usando generadores fotovoltaicos combinados con maquinas diesel, en algunos casos adicionalmente con convertidores de energia del viento y baterias para el almacenamiento de energia. Se estima que en Europa un total de 300,000 edificios no estan conectados a la red publica. Esto representa un gran mercado potencial para los sistemas fotovoltaicos, ya que a menudo la generacion fotovoltaica es menos costosa que una conexion a la empresa electrica. El Instituto Fraunhofer para Sistemas de Energia Solar ISE ha planeado, llevado a cabo y monitoreado alrededor de 30 sistemas hibridos remotos de suministro de energia con generadores fotovoltaicos

  10. The Power Quality Compensation Strategy for Power Distribution System Based on Hybrid Parallel Active Power Filters

    Rachid DEHINI

    2010-12-01

    Full Text Available In this paper, the main aim is to confront the performance of shunt active power filter (SAPF and the shunt hybrid active power filter (SHAPF to achieve flexibility and reliability of the filter devices. Both of the two devices used the classical proportional-integral controller for pulse generation to trigger the inventers MOSFET’s. In the adopted hybrid active filter there is a passive power filter with high power rating to filter the low order harmonies and one active filter with low power rating to filter the other high order harmonies. In order to investigate the effectiveness of (SHAPF, the studies have been accomplished using simulation with the MATLAB-SIMULINK. The results show That (SHAPF is more effective than (SAPF, and has lower cost.

  11. Antibacterial Activity and Cytocompatibility of PLGA/CuO Hybrid Nanofiber Scaffolds Prepared by Electrospinning

    Adnan Haider

    2015-01-01

    Full Text Available The PLGA/CuO hybrid nanofibers scaffolds were prepared via electrospinning technique. The presence of CuO in the PLGA scaffolds was confirmed by transmission electron microscope (TEM and X-ray photoelectron spectroscopy (XPS. The scaffolds were subjected to various antibacterial and cytobiocompatibility tests. The results not only showed excellent adhesion, proliferation, and viability (live/dead staining for fibroblastic cells but also revealed that PLGA/CuO hybrid nanofiber scaffolds inhibited both Gram-positive and Gram-negative bacterial growth. The mechanism of the antibacterial activity was concluded to be based on the CuO nanoparticles and Cu++ ions release. It is, therefore, evaluated that PLGA/CuO hybrid nanofiber scaffolds can be a useful candidate for wound dressing.

  12. Overcoming Chloroquine Resistance in Malaria: Design, Synthesis, and Structure-Activity Relationships of Novel Hybrid Compounds.

    Boudhar, Aicha; Ng, Xiao Wei; Loh, Chiew Yee; Chia, Wan Ni; Tan, Zhi Ming; Nosten, Francois; Dymock, Brian W; Tan, Kevin S W

    2016-05-01

    Resistance to antimalarial therapies, including artemisinin, has emerged as a significant challenge. Reversal of acquired resistance can be achieved using agents that resensitize resistant parasites to a previously efficacious therapy. Building on our initial work describing novel chemoreversal agents (CRAs) that resensitize resistant parasites to chloroquine (CQ), we herein report new hybrid single agents as an innovative strategy in the battle against resistant malaria. Synthetically linking a CRA scaffold to chloroquine produces hybrid compounds with restored potency toward a range of resistant malaria parasites. A preferred compound, compound 35, showed broad activity and good potency against seven strains resistant to chloroquine and artemisinin. Assessment of aqueous solubility, membrane permeability, and in vitro toxicity in a hepatocyte line and a cardiomyocyte line indicates that compound 35 has a good therapeutic window and favorable drug-like properties. This study provides initial support for CQ-CRA hybrid compounds as a potential treatment for resistant malaria. PMID:26953199

  13. Piezoelectric properties of the new generation active matrix hybrid (micro-nano) composites

    Parali, Levent; Şabikoğlu, İsrafil; Kurbanov, Mirza A.

    2014-11-01

    A hybrid piezoelectric composite structure is obtained by addition of nano-sized BaTiO3, SiO2 to the micro-sized PZT and polymers composition. Although the PZT material itself has excellent piezoelectric properties, PZT-based composite variety is limited. Piezoelectric properties of PZT materials can be varied with an acceptor or a donor added to the material. In addition, varieties of PZT-based sensors can be increased with doping polymers which have physical-mechanical, electrophysical, thermophysical and photoelectrical properties. The active matrix hybrid structure occurs when bringing together the unique piezoelectric properties of micro-sized PZT with electron trapping properties of nano-sized insulators (BaTiO3 or SiO2), and their piezoelectric, mechanic and electromechanic properties significantly change. In this study, the relationship between the piezoelectric constant and the coupling factor values of microstructure (PZT-PVDF) and the hybrid structure (PZT-PVDF-BaTiO3) composite are compared. The d33 value and the coupling factor of the hybrid structure have shown an average of 54 and 62% increase according to microstructure composite, respectively. In addition, the d33 value and the coupling factor of the hybrid structure (PZT-HDPE-SiO2) have exhibited about 68 and 52% increase according to microstructure composite (PZT-HDPE), respectively.

  14. Energy Conservation Analysis and Control of Hybrid Active Semiactive Suspension with Three Regulating Damping Levels

    Long Chen; Dehua Shi; Ruochen Wang; Huawei Zhou

    2016-01-01

    Active suspension has not been popularized for high energy consumption. To address this issue, this paper introduces the concept of a new kind of suspension. The linear motor is considered to be integrated into an adjustable shock absorber to form the hybrid active semiactive suspension (HASAS). To realize the superiority of HASAS, its energy consumption and regeneration mechanisms are revealed. And the system controller which is composed of linear quadratic regulator (LQR) controller, mode d...

  15. Hybrid Active/Passive Jet Engine Noise Suppression System

    Parente, C. A.; Arcas, N.; Walker, B. E.; Hersh, A. S.; Rice, E. J.

    1999-01-01

    A novel adaptive segmented liner concept has been developed that employs active control elements to modify the in-duct sound field to enhance the tone-suppressing performance of passive liner elements. This could potentially allow engine designs that inherently produce more tone noise but less broadband noise, or could allow passive liner designs to more optimally address high frequency broadband noise. A proof-of-concept validation program was undertaken, consisting of the development of an adaptive segmented liner that would maximize attenuation of two radial modes in a circular or annular duct. The liner consisted of a leading active segment with dual annuli of axially spaced active Helmholtz resonators, followed by an optimized passive liner and then an array of sensing microphones. Three successively complex versions of the adaptive liner were constructed and their performances tested relative to the performance of optimized uniform passive and segmented passive liners. The salient results of the tests were: The adaptive segmented liner performed well in a high flow speed model fan inlet environment, was successfully scaled to a high sound frequency and successfully attenuated three radial modes using sensor and active resonator arrays that were designed for a two mode, lower frequency environment.

  16. Predicting eruptions from precursory activity using remote sensing data hybridization

    Reath, K. A.; Ramsey, M. S.; Dehn, J.; Webley, P. W.

    2016-07-01

    Many volcanoes produce some level of precursory activity prior to an eruption. This activity may or may not be detected depending on the available monitoring technology. In certain cases, precursors such as thermal output can be interpreted to make forecasts about the time and magnitude of the impending eruption. Kamchatka (Russia) provides an ideal natural laboratory to study a wide variety of eruption styles and precursory activity prior to an eruption. At Bezymianny volcano for example, a clear increase in thermal activity commonly occurs before an eruption, which has allowed predictions to be made months ahead of time. Conversely, the eruption of Tolbachik volcano in 2012 produced no discernable thermal precursors before the large scale effusive eruption. However, most volcanoes fall between the extremes of consistently behaved and completely undetectable, which is the case with neighboring Kliuchevskoi volcano. This study tests the effectiveness of using thermal infrared (TIR) remote sensing to track volcanic thermal precursors using data from both the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Advanced Very High Resolution Radiometer (AVHRR) sensors. It focuses on three large eruptions that produced different levels and durations of effusive and explosive behavior at Kliuchevskoi. Before each of these eruptions, TIR spaceborne sensors detected thermal anomalies (i.e., pixels with brightness temperatures > 2 °C above the background temperature). High-temporal, low-spatial resolution (i.e., ~ hours and 1 km) AVHRR data are ideal for detecting large thermal events occurring over shorter time scales, such as the hot material ejected following strombolian eruptions. In contrast, high-spatial, low-temporal resolution (i.e., days to weeks and 90 m) ASTER data enables the detection of much lower thermal activity; however, activity with a shorter duration will commonly be missed. ASTER and AVHRR data are combined to track low

  17. Biodegradation of pharmaceuticals in hospital wastewater by a hybrid biofilm and activated sludge system (Hybas)

    Escola Casas, Monica; Chhetri, Ravi Kumar; Ooi, Gordon Tze Hoong;

    2015-01-01

    hybrid process, based on the integrated fixed-film activated sludge technology, where plastic carriers for biofilm growth are suspended within activated sludge. To investigate the potential of a hybrid system for the removal of pharmaceuticals in hospital wastewater a pilot plant consisting of a series...... of one activated sludge reactor, two HybasTM reactors and one moving bed biofilm reactor (MBBR) has been operated for 10 months, where after batch and continuous flow tests were performed for the degradation of pharmaceuticals. Removal of organic matter and nitrification mainly occurred in the first...... reactor. Most pharmaceuticals were removed significantly. The removal of pharmaceuticals (including x-ray contrast media, ß-blockers, analgesics and antibiotics) were fitted to a single first-order kinetics degradation function, giving degradation rate constants from 0 to 1.49 h-1, from 0 to 7.78×10-1 h-1...

  18. Hybrid Active-Passive Microwave Photonic Filter with High Quality Factor

    A hybrid high quality factor (Q-factor) microwave photonic filter with a cascaded active filter and a passive filter is presented and experimentally demonstrated. The active infinite impulse response filter is realized by a recirculating delay line loop with a semiconductor optical amplifier, and a much narrower 3 dB bandwidth of response peaks can be achieved. A passive finite impulse response filter is realized by an unbalance Mach–Zehnder interferometer, and it is cascaded to select the desired filter frequencies and to suppress the intermediate peaks. Compared with the purely active filter scheme, the free spectrum range and the Q-factor of the hybrid structure can be doubled. Stable operation and a high Q-factor of 362 are experimentally demonstrated

  19. Assembly of a Metalloporphyrin-Polyoxometalate Hybrid Material for Highly Efficient Activation of Molecular Oxygen.

    Zhu, Shu-Lan; Xu, Xuan; Ou, Sha; Zhao, Min; He, Wei-Long; Wu, Chuan-De

    2016-08-01

    Organic metalloporphyrins and inorganic polyoxometalates (POMs) are two kinds of efficient molecular catalysts to prompt a variety of chemical reactions. They have been used as active moieties for the synthesis of porous materials to realize highly efficient heterogeneous catalysis. Both of them are regarded as the organic/inorganic equivalent counterparts to complement the individual features. Therefore, the combination of metalloporphyrins and POMs in the same hybrid materials might generate interesting catalytic properties by emerging their unique individual functions. To avoid the random connections between metalloporphyrins, POMs, and lanthanide connecting nodes, we have developed a "step-by-step" aggregation strategy, including the reaction of POMs with metal ions to bind metal nodes on the surfaces of POMs at the first step and the reaction of the resulting POM derivatives with metalloporphyrin linkers to result in hybrid materials at the second step. Catalytic experiments demonstrate that the resulting hybrid material exhibits interesting catalytic properties in the heterogeneous epoxidation of olefins, in which the conversion, epoxide selectivity, turnover number, and turnover frequency for the epoxidation of styrene to (1,2-epoxyethyl)benzene are >99%, 94%, 220000, and 22000 h(-1), respectively. These results demonstrate that the collaborative work of multiple active sites in hybrid materials can achieve superior high efficiency in heterogeneous catalysis. PMID:27408952

  20. Piezoelectric properties of the new generation active matrix hybrid (micro-nano) composites

    Highlights: • We prepared hybrid structured piezocomposites. • We examine thermostimulated depolarization of piezocomposites. • We examine frequency characteristic of piezocomposites with SiO2 and BaTiO3. • The piezocomposites can be used in acoustic applications at 5 Hz–40 kHz. - Abstract: A hybrid piezoelectric composite structure is obtained by addition of nano-sized BaTiO3, SiO2 to the micro-sized PZT and polymers composition. Although the PZT material itself has excellent piezoelectric properties, PZT-based composite variety is limited. Piezoelectric properties of PZT materials can be varied with an acceptor or a donor added to the material. In addition, varieties of PZT-based sensors can be increased with doping polymers which have physical-mechanical, electrophysical, thermophysical and photoelectrical properties. The active matrix hybrid structure occurs when bringing together the unique piezoelectric properties of micro-sized PZT with electron trapping properties of nano-sized insulators (BaTiO3 or SiO2), and their piezoelectric, mechanic and electromechanic properties significantly change. In this study, the relationship between the piezoelectric constant and the coupling factor values of microstructure (PZT–PVDF) and the hybrid structure (PZT–PVDF–BaTiO3) composite are compared. The d33 value and the coupling factor of the hybrid structure have shown an average of 54 and 62% increase according to microstructure composite, respectively. In addition, the d33 value and the coupling factor of the hybrid structure (PZT–HDPE–SiO2) have exhibited about 68 and 52% increase according to microstructure composite (PZT–HDPE), respectively

  1. Piezoelectric properties of the new generation active matrix hybrid (micro-nano) composites

    Parali, Levent, E-mail: levent.parali@cbu.edu.tr [Department of Electronics and Automation, Celal Bayar University, Manisa (Turkey); Şabikoğlu, İsrafil [Department of Physics, Celal Bayar University, Manisa (Turkey); Kurbanov, Mirza A. [Institute of Physics, Academy of Sciences of Azerbaijan, Baku (Azerbaijan)

    2014-11-01

    Highlights: • We prepared hybrid structured piezocomposites. • We examine thermostimulated depolarization of piezocomposites. • We examine frequency characteristic of piezocomposites with SiO{sub 2} and BaTiO{sub 3}. • The piezocomposites can be used in acoustic applications at 5 Hz–40 kHz. - Abstract: A hybrid piezoelectric composite structure is obtained by addition of nano-sized BaTiO{sub 3}, SiO{sub 2} to the micro-sized PZT and polymers composition. Although the PZT material itself has excellent piezoelectric properties, PZT-based composite variety is limited. Piezoelectric properties of PZT materials can be varied with an acceptor or a donor added to the material. In addition, varieties of PZT-based sensors can be increased with doping polymers which have physical-mechanical, electrophysical, thermophysical and photoelectrical properties. The active matrix hybrid structure occurs when bringing together the unique piezoelectric properties of micro-sized PZT with electron trapping properties of nano-sized insulators (BaTiO{sub 3} or SiO{sub 2}), and their piezoelectric, mechanic and electromechanic properties significantly change. In this study, the relationship between the piezoelectric constant and the coupling factor values of microstructure (PZT–PVDF) and the hybrid structure (PZT–PVDF–BaTiO{sub 3}) composite are compared. The d{sub 33} value and the coupling factor of the hybrid structure have shown an average of 54 and 62% increase according to microstructure composite, respectively. In addition, the d{sub 33} value and the coupling factor of the hybrid structure (PZT–HDPE–SiO{sub 2}) have exhibited about 68 and 52% increase according to microstructure composite (PZT–HDPE), respectively.

  2. Lubricated friction between incommensurate substrates

    Vanossi, Andrea; Santoro, Giuseppe E.; Manini, Nicola; Tosatti, Erio; Braun, O. M.

    2007-01-01

    This paper is part of a study of the frictional dynamics of a confined solid lubricant film - modelled as a one-dimensional chain of interacting particles confined between two ideally incommensurate substrates, one of which is driven relative to the other through an attached spring moving at constant velocity. This model system is characterized by three inherent length scales; depending on the precise choice of incommensurability among them it displays a strikingly different tribological beha...

  3. Wet friction materials and lubricants

    Matsumoto, Takayuki

    1988-02-01

    There are wet and dry friction materials used for friction clutches and friction brakes. Wet friction materials include sintered alloys and semimetallic substances. Paper friction materials which are the most common wet friction materials used in automobiles were studied for their performance and their relation to lubricants. All present paper friction materials are non-asbestos paper friction materials. The requirements for paper friction material performance are as follows: (1) The heat resistance and durability are so high that the material can stand sliding for a long time. (2) The friction curve is flat. (3) The mechanical strength, wear resistance, and resistance to oil pressure are high. (4) The coefficient of friction (particularly, of static friction) is very high. (5) Variations in the coefficient of friction with time are low. The friction characteristics and wear of paper friction materials are influenced by the lubricant used together with the paper friction materials. It is necessary to develop materials which are immune to the influence of the lubricant. (11 figs, 3 tabs, 21 refs)

  4. Used lubricants and ecological problems

    This planet is undergoing a severe ecological crisis. The consequent problems include not only how to prevent the destruction of contemporary civilization, but also how to preserve mankind as a biological species. In the onset of this crisis, used lubricants (ULs) play a role that is by no means the least important. Every year, the worldwide discharge of petroleum products to the biosphere is approximately 6 million tonnes, of which more than 50% consists of ULs. The ecologically dangerous components of both commercial lubricants and used lubricants are the polycyclic aromatic hydrocarbons (PAHs) that are originally present in crude oil; polyhalobiphenyls, mainly polychlorobiphenyls (PCBs) of anthropogenic origin; sulfur- and chlorine-containing additives; a number of biocides; organic compounds of metals (lead, barium, antimony, zinc); and nitrites. These substances are distributed in the atmosphere, water, and soil, entering the food chain and appearing in foodstuffs. Moreover, hydrocarbons of petroleum and synthetic oils with a low degree of biodegradability (10-30%) accumulate in the environment and may shift the ecological equilibrium (accelerated multiplication and mutation of microorganisms that assimilate petroleum products). 32 refs., 1 fig

  5. Synthesis, characterization and catalytic activity of carbon-silica hybrid catalyst from rice straw

    Janaun, J.; Safie, N. N.; Siambun, N. J.

    2016-07-01

    The hybrid-carbon catalyst has been studied because of its promising potential to have high porosity and surface area to be used in biodiesel production. Silica has been used as the support to produce hybrid carbon catalyst due to its mesoporous structure and high surface area properties. The chemical synthesis of silica-carbon hybrid is expensive and involves more complicated preparation steps. The presence of natural silica in rice plants especially rice husk has received much attention in research because of the potential as a source for solid acid catalyst synthesis. But study on rice straw, which is available abundantly as agricultural waste is limited. In this study, rice straw undergone pyrolysis and functionalized using fuming sulphuric acid to anchor -SO3H groups. The presence of silica and the physiochemical properties of the catalyst produced were studied before and after sulphonation. The catalytic activity of hybrid carbon silica acid catalyst, (H-CSAC) in esterification of oleic acid with methanol was also studied. The results showed the presence of silica-carbon which had amorphous structure and highly porous. The carbon surface consisted of higher silica composition, had lower S element detected as compared to the surface that had high carbon content but lower silica composition. This was likely due to the fact that Si element which was bonded to oxygen was highly stable and unlikely to break the bond and react with -SO3H ions. H-CSAC conversions were 23.04 %, 35.52 % and 34.2 7% at 333.15 K, 343.15 K and 353.15 K, respectively. From this research, rice straw can be used as carbon precursor to produce hybrid carbon-silica catalyst and has shown catalytic activity in biodiesel production. Rate equation obtained is also presented.

  6. Effect of Lubricant Additives on the WDLC Coating Structure When Tested in Boundary Lubrication Regime

    Yang, L; Neville, A; Brown, A; Ransom, P; Morina, A

    2015-01-01

    Improvements in coating deposition technology enable the mass production of high-quality diamond-like carbon (DLC) coatings at an industrial scale and also increase their use in lubricated contacts. However, the understanding of the interactions of different lubricant additives with this material is not yet fully developed. This study focuses on several fundamental aspects of the tungsten-doped DLC coating (denoted as WDLC) behaviour under boundary lubrication conditions with model lubricants...

  7. Effect of powdered activated carbon (PAC) and cationic polymer on biofouling mitigation in hybrid MBRs.

    Jamal Khan, S; Visvanathan, C; Jegatheesan, V

    2012-06-01

    In this study, the influence of powdered activated carbon (PAC) and cationic polymer (MPE50) was investigated on the fouling propensity in hybrid MBRs. Three laboratory scale MBRs were operated simultaneously including MBR(Control), MBR(PAC), and MBR(Polymer). Optimum dosages of PAC and polymer to the MBR(PAC) and MBR(Polymer), respectively were determined using jar tests. It was found that the MBR(PAC) exhibited low fouling tendency and prolonged filtration as compared to the other MBRs. Improved filtration in MBR(PAC) was attributed to the flocculation and adsorption phenomena. The effective stability of the biomass by PAC in the form of biological activated carbon (BAC) was verified by the increase in mean particle size. The BAC aided sludge layer exhibited porous cake structure resulting in the prolong filtration. However, both the membrane hybrid systems revealed effective adsorption of organic matter by 40% reduction in the soluble EPS concentration. PMID:22264429

  8. Activation of different split functionalities on re-association of RNA-DNA hybrids.

    Afonin, Kirill A; Viard, Mathias; Martins, Angelica N; Lockett, Stephen J; Maciag, Anna E; Freed, Eric O; Heldman, Eliahu; Jaeger, Luc; Blumenthal, Robert; Shapiro, Bruce A

    2013-04-01

    Split-protein systems, an approach that relies on fragmentation of proteins with their further conditional re-association to form functional complexes, are increasingly used for various biomedical applications. This approach offers tight control of protein functions and improved detection sensitivity. Here we report a similar technique based on a pair of RNA-DNA hybrids that can be used generally for triggering different split functionalities. Individually, each hybrid is inactive but when two cognate hybrids re-associate, different functionalities are triggered inside mammalian cells. As a proof of concept, this work mainly focuses on the activation of RNA interference. However, the release of other functionalities (such as resonance energy transfer and RNA aptamer) is also shown. Furthermore, in vivo studies demonstrate a significant uptake of the hybrids by tumours together with specific gene silencing. This split-functionality approach presents a new route in the development of 'smart' nucleic acid-based nanoparticles and switches for various biomedical applications. PMID:23542902

  9. Active Semi-Supervised Learning Method with Hybrid Deep Belief Networks

    Shusen Zhou; Qingcai Chen; Xiaolong Wang

    2014-01-01

    In this paper, we develop a novel semi-supervised learning algorithm called active hybrid deep belief networks (AHD), to address the semi-supervised sentiment classification problem with deep learning. First, we construct the previous several hidden layers using restricted Boltzmann machines (RBM), which can reduce the dimension and abstract the information of the reviews quickly. Second, we construct the following hidden layers using convolutional restricted Boltzmann machines (CRBM), which ...

  10. Programmable SERS active substrates for chemical and biosensing applications using amorphous/crystalline hybrid silicon nanomaterial

    Jeffery Alexander Powell; Krishnan Venkatakrishnan; Bo Tan

    2016-01-01

    We present the creation of a unique nanostructured amorphous/crystalline hybrid silicon material that exhibits surface enhanced Raman scattering (SERS) activity. This nanomaterial is an interconnected network of amorphous/crystalline nanospheroids which form a nanoweb structure; to our knowledge this material has not been previously observed nor has it been applied for use as a SERS sensing material. This material is formed using a femtosecond synthesis technique which facilitates a laser plu...

  11. The vancomycin-nisin(1-12) hybrid restores activity against vancomycin resistant enterococci

    Arnusch, C.J.; Bonvin, A.M.J.J.; Verel, A.M.; Jansen, W. T. M.; Liskamp, R. M. J.; de Kruijff, B.; Pieters, R. J.; Breukink, E.J.

    2008-01-01

    Lipid II is a crucial component in bacterial cell wall synthesis [Breukink, E., et al. (1999) Science 286, 2361−2364]. It is the target of a number of important antibiotics, which include vancomycin and nisin [Breukink, E., and de Kruijff, B. (2006) Nat. Rev. Drug Discovery 5, 321−332]. Here we show that a hybrid antibiotic that consists of vancomycin and nisin fragments is significantly more active than the separate fragments against vancomycin resistant entercocci (VRE). Three different hyb...

  12. Influence of Lubricant Pocket Geometry upon Lubrication Mechanisms on Tool-Workpiece Interfaces in Metal Forming

    Shimizu, I; Martins, P.A.F.; Bay, Niels; Andreasen, Jan Lasson; Bech, Jakob I.

    Micro lubricant pockets located on the surface of plastically deforming workpieces are recognized to improve the performance of fluid lubrication in a metal forming processes. This work investigates the joint influence of pocket geometry and process working conditions on micro lubrication mechani...

  13. Solid lubrication technology of HTGR under helium

    Because Helium is used as coolant in High Temperature Gas-cooled Reactor (HTGR), the change of tribological properties of HTGR structure component under Helium is a big problem. Under Helium, tribological properties of material becomes worse and fluid lubrication can not be used. Bonded solid lubrication film and fusion sintering solid film are used in control rod and can solve the tribological problem well. Methods of replenishment solid lubricant are discussed for continuously operating friction components. The necessity and possibility for solid lubrication film used in Helium fan is also discussed

  14. Lubrication System with Tolerance for Reduced Gravity

    Portlock, Lawrence E. (Inventor); McCune, Michael E. (Inventor); Dobek, Louis J. (Inventor)

    2013-01-01

    A lubrication system includes an auxiliary lubricant tank 48, a supply conduit 58 extending from a source of lubricant 26 to the auxiliary lubricant tank. A reduced-G bypass line 108 branches from the conduit and enters the auxiliary tank at a first elevation E.sub.1. The system also includes an auxiliary tank discharge conduit 116, a portion of which resides within the tank. The resident portion has an opening 122 at least partially at a second elevation E.sub.2 higher than the first elevation.

  15. Aqueous lubrication natural and biomimetic approaches

    Spencer, Nicholas D

    2014-01-01

    Man lubricates mostly with oil. Nature lubricates exclusively with water. Pure water is a poor lubricant, but the addition of proteins, especially glycoproteins, can modify surfaces to make them far more lubricating at slow speeds. Understanding how nature does this, and the physical structures involved, is not only important for the understanding of diseases such as osteoarthritis, but also essential for the successful application of articulating implants, such as hips and knees, as well as the development of medical devices such as catheters and contact lenses. A host of important applicati

  16. Ecotoxicological study of used lubricating oil

    Used lubricating oil is more toxic than crude oil and fuel oil since it contains comparatively high levels of heavy metals and polycyclic aromatic hydrocarbons (PAHs). No detail toxicological study has been conducted to evaluate the hazards of used lubricating oil to the environment. This study reports a battery of bioassays using bacteria (Microtox test and Mutatox test), algae, amphipod and shrimp larvae to determine the toxicity of water soluble fraction of used lubricating oil. The results will be used to formulate a complete and extensive ecotoxicological assessment of the impacts of used lubricating oil on aquatic environment

  17. Lubricant for cold stamping of metal

    Tulik, V.T.; Movshovich, V.S.; Speranskiy, B.S.; Tseloval' nikov, V.M.; Yudovich, S.Z.

    1980-03-19

    Hydrogenated thermally thickened vegetable oil and the product of condensation of triethanolamine with the bottoms of synthetic fatty acids are added to the oil, which contains petroleum oil, lanolin and a nonionogenic wetting agent, in order to increase the lubricating properties and to give it mothballing properties. The contents of the components are in %: lanolin, 10-20; nonionogenic wetting agent, 1-5; vegetable oil, 10-50; product of condensation, 1-5 and petroleum oil to 100%. The lubricant is produced through the introduction of the cited components in petroleum oil heated to 65-75/sup 0/C with careful mixing. Comparative laboratory tests of the lubricant samples were conducted through identifying the degree of drawing, the drawing force and the degree of deformation. The tests showed that the new lubricant has high lubricating and washing properties. Also studied was the corrosion stability in a moisture chamber as compared with I-20 A lubricant. The time after which the corrosion appeared in days for the I-20 A is 1 and the sample of the lubricant, 28. Industrial tests showed that the proposed lubricant may be used in sheet stamping production in the manufacture of complex parts of motor vehicles without the additional application of industrial lubricant in conditions of press production.

  18. Direct observation of lubricant additives using tomography techniques

    Chen, Yunyun; Sanchez, Carlos; Parkinson, Dilworth Y.; Liang, Hong

    2016-07-01

    Lubricants play important roles in daily activities such as driving, walking, and cooking. The current understanding of mechanisms of lubrication, particularly in mechanical systems, has been limited by the lack of capability in direct observation. Here, we report an in situ approach to directly observe the motion of additive particles in grease under the influence of shear. Using the K-edge tomography technique, it is possible to detect particular additives in a grease and observe their distribution through 3D visualization. A commercial grease as a reference was studied with and without an inorganic additive of Fe3O4 microparticles. The results showed that it was possible to identify these particles and track their movement. Under a shear stress, Fe3O4 particles were found to adhere to the edge of calcium complex thickeners commonly used in grease. Due to sliding, the grease formed a film with increased density. This approach enables in-line monitoring of a lubricant and future investigation in mechanisms of lubrication.

  19. Estimation of appropriate lubricating film thickness in ceramic-on-ceramic hip prostheses

    Tauviqirrahman, M.; Muchammad, Bayuseno, A. P.; Ismail, R.; Saputra, E.; Jamari, J.

    2016-04-01

    Artificial hip prostheses, consisting of femoral head and acetabular cup are widely used and have affected the lives of many people.However, the primary issue associated with the long term performance of hip prostheses is loosening induced by excessive wear during daily activity. Therefore, an effective lubrication is necessary to significantly decrease the wear. To help understand the lubricating performance of such typical hip joint prostheses, in the present paper a hydrodynamic lubrication model based on Reynolds equationwas introduced. The material pairs of ceramic acetabular cup against ceramic femoral head was investegated.The main aim of this study is to investigate of the effect of loading on the formation of lubricating film thickness.The model of a ball-in-socket configuration was considered assuming that the cup was stationary while the ball was to rotate at a steady angular velocityvarying loads.Based on simulation result, it was found that to promote fluid film lubrication and prevent the contacting components leading to wear, the film thickness of lubricant should be determined carefully based on the load applied. This finding may have useful implication in predicting the failure of lubricating synovial fluid film and wear generation in hip prostheses.

  20. Energy efficient reduced graphene oxide additives: Mechanism of effective lubrication and antiwear properties

    Gupta, Bhavana; Kumar, N.; Panda, Kalpataru; Dash, S.; Tyagi, A. K.

    2016-01-01

    Optimized concentration of reduced graphene oxide (rGO) in the lube is one of the important factors for effective lubrication of solid body contacts. At sufficiently lower concentration, the lubrication is ineffective and friction/wear is dominated by base oil. In contrast, at sufficiently higher concentration, the rGO sheets aggregates in the oil and weak interlayer sliding characteristic of graphene sheets is no more active for providing lubrication. However, at optimized concentration, friction coefficient and wear is remarkably reduced to 70% and 50%, respectively, as compared to neat oil. Traditionally, such lubrication is described by graphene/graphite particle deposited in contact surfaces that provides lower shear strength of boundary tribofilm. In the present investigation, graphene/graphite tribofilm was absent and existing traditional lubrication mechanism for the reduction of friction and wear is ruled out. It is demonstrated that effective lubrication is possible, if rGO is chemically linked with PEG molecules through hydrogen bonding and PEG intercalated graphene sheets provide sufficiently lower shear strength of freely suspended composite tribofilm under the contact pressure. The work revealed that physical deposition and adsorption of the graphene sheets in the metallic contacts is not necessary for the lubrication.

  1. Influence of Particles on the Loading Capacity and the Temperature Rise of Water Film in Ultra-high Speed Hybrid Bearing

    ZHU Aibin; LI Pei; ZHANG Yefan; CHEN Wei; YUAN Xiaoyang

    2015-01-01

    Ultra-high speed machining technology enables high efficiency, high precision and high integrity of machined surface. Previous researches of hybrid bearing rarely consider influences of solid particles in lubricant and ultra-high speed of hybrid bearing, which cannot be ignored under the high speed and micro-space conditions of ultra-high speed water-lubricated hybrid bearing. Considering the impact of solid particles in lubricant, turbulence and temperature viscosity effects of lubricant, the influences of particles on pressure distribution, loading capacity and the temperature rise of the lubricant film with four-step-cavity ultra-high speed water-lubricated hybrid bearing are presented in the paper. The results show that loading capacity of the hybrid bearing can be affected by changing the viscosity of the lubricant, and large particles can improve the bearing loading capacity higher. The impact of water film temperature rise produced by solid particles in lubricant is related with particle diameter and minimum film thickness. Compared with the soft particles, hard particles cause the more increasing of water film temperature rise and loading capacity. When the speed of hybrid bearing increases, the impact of solid particles on hybrid bearing becomes increasingly apparent, especially for ultra-high speed water-lubricated hybrid bearing. This research presents influences of solid particles on the loading capacity and the temperature rise of water film in ultra-high speed hybrid bearings, the research conclusions provide a new method to evaluate the influence of solid particles in lubricant of ultra-high speed water-lubricated hybrid bearing, which is important to performance calculation of ultra-high speed hybrid bearings, design of filtration system, and safe operation of ultra-high speed hybrid bearings.

  2. Influence of particles on the loading capacity and the temperature rise of water film in Ultra-high speed hybrid bearing

    Zhu, Aibin; Li, Pei; Zhang, Yefan; Chen, Wei; Yuan, Xiaoyang

    2015-04-01

    Ultra-high speed machining technology enables high efficiency, high precision and high integrity of machined surface. Previous researches of hybrid bearing rarely consider influences of solid particles in lubricant and ultra-high speed of hybrid bearing, which cannot be ignored under the high speed and micro-space conditions of ultra-high speed water-lubricated hybrid bearing. Considering the impact of solid particles in lubricant, turbulence and temperature viscosity effects of lubricant, the influences of particles on pressure distribution, loading capacity and the temperature rise of the lubricant film with four-step-cavity ultra-high speed water-lubricated hybrid bearing are presented in the paper. The results show that loading capacity of the hybrid bearing can be affected by changing the viscosity of the lubricant, and large particles can improve the bearing loading capacity higher. The impact of water film temperature rise produced by solid particles in lubricant is related with particle diameter and minimum film thickness. Compared with the soft particles, hard particles cause the more increasing of water film temperature rise and loading capacity. When the speed of hybrid bearing increases, the impact of solid particles on hybrid bearing becomes increasingly apparent, especially for ultra-high speed water-lubricated hybrid bearing. This research presents influences of solid particles on the loading capacity and the temperature rise of water film in ultra-high speed hybrid bearings, the research conclusions provide a new method to evaluate the influence of solid particles in lubricant of ultra-high speed water-lubricated hybrid bearing, which is important to performance calculation of ultra-high speed hybrid bearings, design of filtration system, and safe operation of ultra-high speed hybrid bearings.

  3. Dynamics of SAMs in Boundary Lubrication

    J. Manojlović

    2013-09-01

    Full Text Available Surfactant molecules have some properties responsible for a number ofremarkable phenomena, such as oriented adsorption of surfactants at surfaces and interfaces. The capability to self -assemble into well- defined structures is often seen as being more important than their surface activity. When a surfactant solution is in contact with a solid surface, the surfactant molecules adsorb onto the surface, ideally forming an adsorbed layer of a high order, termed as a self- assembled monolayer (SAM. Many surface properties are influenced bysuch a film, and therefore, SAMs offer the capability to form ordered organic surface coatings, suitable for various applications, such as wetting or corrosion protection. Due to the flexibility in choosing the molecular architecture, organic molecules have many interesting applications, such as biosensors, in Photoelectronics, in controlling water adsorption or boundary lubricant coating. This paper Focuses on cationic surfactants (quaternary ammonium surfactants with some unique properties that are not present in other surfactants.

  4. Synthesis, Antiplasmodial Activity, and β-Hematin Inhibition of Hydroxypyridone-Chloroquine Hybrids.

    Andayi, Warren A; Egan, Timothy J; Gut, Jiri; Rosenthal, Philip J; Chibale, Kelly

    2013-07-11

    A series of noncytotoxic 4-aminoquinoline-3-hydroxypyridin-4-one hybrids were synthesized on the basis of a synergistic in vitro combination of a precursor N-alkyl-3-hydroxypyridin-4-one with chloroquine (CQ) and tested in vitro against CQ resistant (K1 and W2) and sensitive (3D7) strains of Plasmodium falciparum. In vitro antiplasmodial activity of the precursors was negated by blocking the chelator moiety via complexation with gallium(III) or benzyl protection. None of the precursors inhibited β-hematin formation. Most hybrids were more potent inhibitors of β-hematin formation than CQ, and a correlation between antiplasmodial activity and inhibition of β-hematin formation was observed. Potent hybrids against K1, 3D7, and W2, respectively, were 8c (0.13, 0.004, and 0.1 μM); 8d (0.08, 0.01, and 0.02 μM); and 7g (0.07, 0.03, and 0.08 μM). PMID:24900724

  5. Development of Control Structure for Hybrid Wind Generators with Active Power Capability

    Mehdi Niroomand

    2014-01-01

    Full Text Available A hierarchical control structure is proposed for hybrid energy systems (HES which consist of wind energy system (WES and energy storage system (ESS. The proposed multilevel control structure consists of four blocks: reference generation and mode select, power balancing, control algorithms, and switching control blocks. A high performance power management strategy is used for the system. Also, the proposed system is analyzed as an active power filter (APF with ability to control the voltage, to compensate the harmonics, and to deliver active power. The HES is designed with parallel DC coupled structure. Simulation results are shown for verification of the theoretical analysis.

  6. Hybrid Modulation of Bidirectional Three-Phase Dual-Active-Bridge DC Converters for Electric Vehicles

    Yen-Ching Wang

    2016-06-01

    Full Text Available Bidirectional power converters for electric vehicles (EVs have received much attention recently, due to either grid-supporting requirements or emergent power supplies. This paper proposes a hybrid modulation of the three-phase dual-active bridge (3ΦDAB converter for EV charging systems. The designed hybrid modulation allows the converter to switch its modulation between phase-shifted and trapezoidal modes to increase the conversion efficiency, even under light-load conditions. The mode transition is realized in a real-time manner according to the charging or discharging current. The operation principle of the converter is analyzed in different modes and thus design considerations of the modulation are derived. A lab-scaled prototype circuit with a 48V/20Ah LiFePO4 battery is established to validate the feasibility and effectiveness.

  7. Improved performance of cylindrical hybrid supercapacitor using activated carbon/ niobium doped hydrogen titanate

    Lee, Jeong Hyun; Kim, Hong-Ki; Baek, Esther; Pecht, Michael; Lee, Seung-Hwan; Lee, Young-Hie

    2016-01-01

    A cylindrical hybrid supercapacitor is fabricated using activated carbon positive electrode and H2Ti12-xNbxO25 (0 ≤ x ≤ 0.6) negative electrode materials. The hybrid supercapacitor using H2Ti11.85Nb0.15O25 exhibits the best electrochemical performance. It has a capacitance of 78.4 F g-1, charge transfer resistance (Rct) of 0.03 Ω, capacitance retention of 91.4% after 1000 cycles at 3.0 A g-1 and energy density of 24.3 W h kg-1 at a power density of 1794.6 W kg-1. Therefore, the Nb doped HTO negative electrode material is a promising candidate as an energy storage system for electric vehicles (EVs).

  8. Electrocatalytically Active MOF/Graphite Oxide Hybrid for Electrosynthesis of Dimethyl Carbonate

    Graphical abstract: - Abstract: Electrochemical oxidative carbonylation of methanol with CO to dimethyl carbonate from heterogeneous electrocatalyst was studied at normal temperature and pressure. For the purpose of decrease the crystalline size and the agglomerative force of metal-organic framework (MOF), this paper first introduced graphite oxide (GO) into MOF/GO hybrid material with enhanced electrocatalytic performance and the stability of electrocatalyst for the dimethyl carbonate (DMC) synthesis. The introduction of GO is important to build the hybrid materials with synergistic properties. The composite materials and its parent materials were characterized using X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and the electrochemical property of the samples was measured. The results show that the MOF/GO was active for the electrolytic reaction and could be reused at least five times. A plausible Cu(II)/Cu(I) electrocatalytic cycle mechanism was proposed

  9. Experimental study and modelling of mixed particulate lubrication with MoS2 powder solid lubricant

    H. Wiśniewska-Weinert

    2011-12-01

    Full Text Available Purpose: The purpose of the paper is experimental study and modelling of mixed particulate lubrication with MoS2 powder solid lubricant.Design/methodology/approach: In the present investigation, ball-on-disc experiments were carried out to determine the lubrication performance of MoS2 solid lubricant powder that could be used for hard PVD coatings applied for forging and stamping tools.Findings: The proposed solid lubricant nano- and submicroparticles mixture demonstrates excellent potential for use in mixed lubrication regimes The quasi-hydrodynamic behaviour of solid lubricant and wear debris particles results in low friction coefficients of hard coating – steel ball friction pairs.Research limitations/implications: The solid lubricant particle exfoliation and formation of tribofilms on micro-asperities allow to achieve the boundary lubrication effects which is found to more preferable for steel contacts rather than for hard coatings.Originality/value: The model of mixed lubrication based on non Newtonian behaviour of powder solid lubricant was validated based on the experimental results. Results of calculation of Stribeck curves demonstrate the potential of modelling of friction process by sharing boundary and quasi-hydrodynamic processes.

  10. How to control optical activity in organic-silver hybrid nanoparticles

    Hidalgo, Francisco; Noguez, Cecilia

    2016-07-01

    The mechanisms that originate and control optical activity in organic-metal hybrid nanoparticles (NPs) are identified using a time-perturbed density functional theory. Electronic circular dichroism (CD) is studied in terms of the intrinsic chirality of the ligands, the number of ligands and the induced chirality by the arrangement of the ligands on the NP. Left-handed cysteine and achiral methylthio ligands adsorbed on an icosahedral silver NP are investigated. The analysis of CD allows the identification of the spectral regions when the induced chirality by the ligand array dominates over the intrinsic chirality of the ligands, determining conditions for CD control and enlargement. These results would be significant in the discussion of experimental CD spectra of organic-metal hybrid NPs, which might allow the development of new strategies to improve the sensitivity of chiroptical spectroscopies for the identification of bio and organic molecules.The mechanisms that originate and control optical activity in organic-metal hybrid nanoparticles (NPs) are identified using a time-perturbed density functional theory. Electronic circular dichroism (CD) is studied in terms of the intrinsic chirality of the ligands, the number of ligands and the induced chirality by the arrangement of the ligands on the NP. Left-handed cysteine and achiral methylthio ligands adsorbed on an icosahedral silver NP are investigated. The analysis of CD allows the identification of the spectral regions when the induced chirality by the ligand array dominates over the intrinsic chirality of the ligands, determining conditions for CD control and enlargement. These results would be significant in the discussion of experimental CD spectra of organic-metal hybrid NPs, which might allow the development of new strategies to improve the sensitivity of chiroptical spectroscopies for the identification of bio and organic molecules. Electronic supplementary information (ESI) available. See DOI: 10.1039/C6

  11. Hybrid Monte Carlo/Deterministic Methods for Accelerating Active Interrogation Modeling

    Peplow, Douglas E. [ORNL; Miller, Thomas Martin [ORNL; Patton, Bruce W [ORNL; Wagner, John C [ORNL

    2013-01-01

    The potential for smuggling special nuclear material (SNM) into the United States is a major concern to homeland security, so federal agencies are investigating a variety of preventive measures, including detection and interdiction of SNM during transport. One approach for SNM detection, called active interrogation, uses a radiation source, such as a beam of neutrons or photons, to scan cargo containers and detect the products of induced fissions. In realistic cargo transport scenarios, the process of inducing and detecting fissions in SNM is difficult due to the presence of various and potentially thick materials between the radiation source and the SNM, and the practical limitations on radiation source strength and detection capabilities. Therefore, computer simulations are being used, along with experimental measurements, in efforts to design effective active interrogation detection systems. The computer simulations mostly consist of simulating radiation transport from the source to the detector region(s). Although the Monte Carlo method is predominantly used for these simulations, difficulties persist related to calculating statistically meaningful detector responses in practical computing times, thereby limiting their usefulness for design and evaluation of practical active interrogation systems. In previous work, the benefits of hybrid methods that use the results of approximate deterministic transport calculations to accelerate high-fidelity Monte Carlo simulations have been demonstrated for source-detector type problems. In this work, the hybrid methods are applied and evaluated for three example active interrogation problems. Additionally, a new approach is presented that uses multiple goal-based importance functions depending on a particle s relevance to the ultimate goal of the simulation. Results from the examples demonstrate that the application of hybrid methods to active interrogation problems dramatically increases their calculational efficiency.

  12. A Biomimetic Approach to Lubricate Engineering Materials

    Røn, Troels

    electrostatic repulsion between charged PAA blocks, hindering the facile formation of the lubricating layer under cyclic tribological stress. It is well known that graft copolymers anchor more efficiently to surfaces than their diblock counterparts, thus the synthesis and study on lubricating capabilities of...

  13. Pressure-viscosity coefficient of biobased lubricants

    Film thickness is an important tribological property that is dependent on the combined effect of lubricant properties, material property of friction surfaces, and the operating conditions of the tribological process. Pressure-viscosity coefficient (PVC) is one of the lubricant properties that influe...

  14. 30 CFR 56.14204 - Machinery lubrication.

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Machinery lubrication. 56.14204 Section 56... MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Machinery and Equipment Safety Practices and Operational Procedures § 56.14204 Machinery lubrication. Machinery...

  15. 30 CFR 57.14204 - Machinery lubrication.

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Machinery lubrication. 57.14204 Section 57... MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Machinery and Equipment Safety Practices and Operational Procedures § 57.14204 Machinery lubrication. Machinery...

  16. Lubricity studies with biodiesel and related compounds

    Biodiesel, the alkyl esters of vegetable oils or animal fats, possesses excellent lubricity. This feature has rendered biodiesel of special interest for blending with ultra-low sulfur diesel fuels with poor lubricity. However, some minor components, mainly free fatty acids and monoacylglycerols, of ...

  17. An emulsion lubricant for metallic molds

    Dovzhik, O.I.; Cherkayev, V.G.; Min' kovskiy, M.M.; Romanyuk, V.G.; Shapiro, L.D.; Sokolov, V.A.

    1980-02-26

    An emulsion lubricant for metallic molds used in production of concrete products for eliminating adhesion of concrete with the metallic mold, and to eliminate potential for air pore formation on surface of product, contains lanolin production waste materials. Compos. of lubricant %: Synthetic emulsol oxide 5-10; wastes from lanolin production in conversion to wax 5-10; water the rest.

  18. VOLATILIZED LUBRICANT EMISSIONS FROM STEEL ROLLING OPERATIONS

    The report gives results of a study of the volatilization of lubricants used in steel rolling. Data from nine steel mills were used to: define the volatilized portion of lubricants used in rolling; and prepare total oil, grease, and hydraulic material balances for actual and typi...

  19. 大型动静力径向可倾瓦轴承热弹流体润滑研究%Study on Thermal Elastohydrodynamic Lubrication of Large Hybrid Tilting-Pad Journal Bearings

    王凤才; 徐华; 朱均

    2001-01-01

    用有限元素法建立瓦块3维弹性变形计算模型。针对小包角瓦块支点非均匀布置方式及下方瓦块设有高压油顶起油囊的大型低速重载动静力润滑径向可倾瓦轴承,研究了由于瓦块3维弹性变形对轴承热动力润滑性能的影响。结果表明,在低速重载条件下需要考虑瓦块的弹性变形对动静力可倾瓦轴承热动力润滑性能的影响。%The finite element method has been used to solve thethree-dimension pad elasticity equations governing the displacement field in the tilting-pad.The influences of the three-dimension pad deformations on the thermohydrodynamic performances of a hybrid tilting-pad journal bearings have been studied under the conditions of the low speed and heavy duty for the non-uniform pivot distribution of the small wrap angle pads and the low pads with high pressure oil recess.The results show that the effects of the small wrap angle pad deformations should be taken into account on the thermohydrodynamic performances of the hybrid tilting-pad journal bearings under the heavy duty condition.

  20. Turbulence Models of Hydrodynamic Lubrication

    张直明; 王小静; 孙美丽

    2003-01-01

    The main theoretical turbulence models for application to hydrodynamic lubrication problems were briefly reviewed, and the course of their development and their fundamentals were explained. Predictions by these models on flow fields in turbulent Couette flows and shear-induced countercurrent flows were compared to existing measurements, and Zhang & Zhang' s combined k-ε model was shown to have surpassingly satisfactory results. The method of application of this combined k-ε model to high speed journal bearings and annular seals was summarized, and the predicted results were shown to be satisfactory by comparisons with existing experiments of journal bearings and annular seals.

  1. New lubricating material for hydraulic turbine generators

    The current state-of-the-art of lubricating practices for major hydraulic equipment which is in contact with water, such as wicket gates, were surveyed by the Canadian Electrical Association by means of a questionnaire. Participants in the survey included owners and operators, designers and bearing and lubricant suppliers. Current practices, major technical issues and potential constraints of using alternative, environmentally friendly lubricant practices were identified. It was found that self lubricating bearing materials were commonly used to address environmental concerns. Results of the survey also revealed that regulations for underwater hydraulic equipment have not been established in Canada nor the U.S. Several recommendations for adopting environmentally friendly lubricants into current practices were made

  2. Biodegradation and toxicological evaluation of lubricant oils

    Ivo Shodji Tamada

    2012-12-01

    Full Text Available The aim of this work was to compare different toxicity levels of lubricant oils. The tests were performed using the earthworm (Eisenia andrei, arugula seeds (Eruca sativa and lettuce seeds (Lactuca sativa, with three types of contaminants (mineral lubricant oil, synthetic lubricant oil and used lubricant oil for various biodegradation periods in the soil. The toxicity tests indirectly measured the biodegradation of the contaminants. The samples were analyzed at t0, t60, t120 and t180 days of biodegradation. The used lubricant oil was proved very toxic in all the tests and even after biodegradation its toxicity was high. The mineral and synthetic oils were biodegraded efficiently in the soil although their toxicity did not disappear completely after 180 days.

  3. Topical Anti-inflammatory Activity of New Hybrid Molecules of Terpenes and Synthetic Drugs

    Cristina Theoduloz

    2015-06-01

    Full Text Available The aim of the study was to assess changes in the activity of anti-inflammatory terpenes from Chilean medicinal plants after the formation of derivatives incorporating synthetic anti-inflammatory agents. Ten new hybrid molecules were synthesized combining terpenes (ferruginol (1, imbricatolic acid (2 and oleanolic acid (3 with ibuprofen (4 or naproxen (5. The topical anti-inflammatory activity of the compounds was assessed in mice by the arachidonic acid (AA and 12-O-tetradecanoyl phorbol 13-acetate (TPA induced ear edema assays. Basal cytotoxicity was determined towards human lung fibroblasts, gastric epithelial cells and hepatocytes. At 1.4 µmol/mouse, a strong anti-inflammatory effect in the TPA assay was observed for oleanoyl ibuprofenate 12 (79.9% and oleanoyl ibuprofenate methyl ester 15 (80.0%. In the AA assay, the best activity was observed for 12 at 3.2 µmol/mouse, with 56.8% reduction of inflammation, in the same range as nimesulide (48.9%. All the terpenyl-synthetic anti-inflammatory hybrids showed better effects in the TPA assay, with best activity for 6, 12 and 15. The cytotoxicity of the compounds 8 and 10 with a free COOH, was higher than that of 2. The derivatives from 3 were less toxic than the triterpene. Several of the new compounds presented better anti-inflammatory effect and lower cytotoxicity than the parent terpenes.

  4. Hybrid feedforward-feedback active noise reduction for hearing protection and communication.

    Ray, Laura R; Solbeck, Jason A; Streeter, Alexander D; Collier, Robert D

    2006-10-01

    A hybrid active noise reduction (ANR) architecture is presented and validated for a circumaural earcup and a communication earplug. The hybrid system combines source-independent feedback ANR with a Lyapunov-tuned leaky LMS filter (LyLMS) improving gain stability margins over feedforward ANR alone. In flat plate testing, the earcup demonstrates an overall C-weighted total noise reduction of 40 dB and 30-32 dB, respectively, for 50-800 Hz sum-of-tones noise and for aircraft or helicopter cockpit noise, improving low frequency (noise reduction provided by the ANR earplug of 46-48 dB for sum-of-tones 80-2000 Hz and 40-41 dB from 63 to 3000 Hz for UH-60 helicopter noise, with negligible degradation in attenuation during speech communication. For both hearing protectors, a stability metric improves by a factor of 2 to several orders of magnitude through hybrid ANR. PMID:17069300

  5. Synthesis, characterisation and antibacterial activity of PVA/TEOS/Ag-Np hybrid thin films.

    Bryaskova, Rayna; Pencheva, Daniela; Kale, Girish M; Lad, Umesh; Kantardjiev, T

    2010-09-01

    Novel hybrid material thin films based on polyvinyl alcohol (PVA)/tetraethyl orthosilicate (TEOS) with embedded silver nanoparticles (AgNps) were synthesized using sol-gel method. Two different strategies for the synthesis of silver nanoparticles in PVA/TEOS matrix were applied based on reduction of the silver ions by thermal annealing of the films or by preliminary preparation of silver nanoparticles using PVA as a reducing agent. The successful incorporation of silver nanoparticles ranging from 5 to 7nm in PVA/TEOS matrix was confirmed by TEM and EDX analysis, UV-Vis spectroscopy and XRD analysis. The antibacterial activity of the synthesized hybrid materials against etalon strains of three different groups of bacteria -Staphylococcus aureus (gram-positive bacteria), Escherichia coli (gram-negative bacteria), Pseudomonas aeruginosa (non-ferment gram-negative bacteria) has been studied as they are commonly found in hospital environment. The hybrid materials showed a strong bactericidal effect against E. coli, S. aureus and P. aeruginosa and therefore have potential applications in biotechnology and biomedical science. PMID:20557895

  6. Squeezing Molecularly thin Lubricant Films between curved Corrugated Surfaces with long range Elasticity

    Sivebæk, Ion Marius; Samoilov, Vladimir N.; Persson, Bo N. J.

    2010-01-01

    The present work investigates the ability of two nm thick lubrication films to stay in a contact and thereby to prevent excessive wear of the surfaces. At this thickness the film is no longer a fluid but it is the very important intermediate between the lubricated and the dry regimes, the latter...... one being associated with devastating wear progress. The properties of alkane lubricants confined between two approaching solids are investigated by a model that accounts for the roughness, curvature and elastic properties of the solid surfaces. We consider linear alkanes of different chain lengths, C......3H8, C4H10, C8H18, C9H20, C10H22, C14H30 and C16H34, confined between corrugated gold surfaces. Well defined molecular layers develop in the lubricant film when the width is of the order of a few atomic diameters. An external squeezing pressure induces discontinuous, thermally activated changes in...

  7. Role of arc mode in laser-metal active gas arc hybrid welding of mild steel

    Highlights: • Pulsed arc is more effective to improve the stability of laser-arc hybrid welding. • LCHW has the highest fraction of acicular ferrite and high-angle grain boundaries. • Grain refinement depends on effective current of the arc. • LSHW has the most apparent vestige of texture components. • The microstructure and microtexture formation mechanisms were summarized. - Abstract: Arc mode plays an important role in joint characterizations of arc welding, but it has been seldom considered in laser-arc hybrid welding. This paper investigated the role of arc mode on laser-metal active gas (MAG) arc hybrid welding of mild steel. Three arc modes were employed, which were cold metal transfer (CMT), pulsed spray arc and standard short circuiting arc. Microtexture of the joints were observed and measured via electron back scattering diffraction (EBSD) system to reveal the effect of arc mode on microstructure. Mechanical properties of the joints were evaluated by tensile and Charpy V-notch impact tests. It was found that both the stability and mechanical properties of laser-CMT hybrid welding (LCHW) is the best, while those of laser-standard short circuiting arc welding (LSHW) is the worst. OM and EBSD results showed that the fraction of acicular ferrite and high-angle grain boundaries in fusion zone decreases gradually in the sequence of LCHW, laser-pulsed spray arc welding and LSHW, while the mean grain size increases gradually. Finally, the microstructure formation mechanisms and the relationship between microstructure and mechanical properties were summarized by the loss of alloying element and the stirring effect in molten pool

  8. Loss of wild-type ATRX expression in somatic cell hybrids segregates with activation of Alternative Lengthening of Telomeres.

    Kylie Bower

    Full Text Available Alternative Lengthening of Telomeres (ALT is a non-telomerase mechanism of telomere lengthening that occurs in about 10% of cancers overall and is particularly common in astrocytic brain tumors and specific types of sarcomas. Somatic cell hybridization analyses have previously shown that normal telomerase-negative fibroblasts and telomerase-positive immortalized cell lines contain repressors of ALT activity, indicating that activation of ALT results from loss of one or more unidentified repressors. More recently, ATRX or DAXX was shown to be mutated both in tumors with telomere lengths suggestive of ALT activity and in ALT cell lines. Here, an ALT cell line was separately fused to each of four telomerase-positive cell lines, and four or five independent hybrid lines from each fusion were examined for expression of ATRX and DAXX and for telomere lengthening mechanism. The hybrid lines expressed either telomerase or ALT, with the other mechanism being repressed. DAXX was expressed normally in all parental cell lines and in all of the hybrids. ATRX was expressed normally in each of the four telomerase-positive parental cell lines and in every telomerase-positive hybrid line, and was abnormal in the ALT parental cells and in all but one of the ALT hybrids. This correlation between ALT activity and loss of ATRX expression is consistent with ATRX being a repressor of ALT.

  9. Process for producing biodiesel, lubricants, and fuel and lubricant additives in a critical fluid medium

    Ginosar, Daniel M.; Fox, Robert V.

    2005-05-03

    A process for producing alkyl esters useful in biofuels and lubricants by transesterifying glyceride- or esterifying free fatty acid-containing substances in a single critical phase medium is disclosed. The critical phase medium provides increased reaction rates, decreases the loss of catalyst or catalyst activity and improves the overall yield of desired product. The process involves the steps of dissolving an input glyceride- or free fatty acid-containing substance with an alcohol or water into a critical fluid medium; reacting the glyceride- or free fatty acid-containing substance with the alcohol or water input over either a solid or liquid acidic or basic catalyst and sequentially separating the products from each other and from the critical fluid medium, which critical fluid medium can then be recycled back in the process. The process significantly reduces the cost of producing additives or alternatives to automotive fuels and lubricants utilizing inexpensive glyceride- or free fatty acid-containing substances, such as animal fats, vegetable oils, rendered fats, and restaurant grease.

  10. Benzimidazole-1,2,3-triazole Hybrid Molecules: Synthesis and Evaluation for Antibacterial/Antifungal Activity

    Ouahrouch, Abdelaaziz; Ighachane, Hana; Taourirte, Moha; Joachim W. Engels; Sedra, My Hassan; Lazrek, Hassan B.

    2014-01-01

    A novel series of hybrid molecules 4a–i and 5a–i were prepared by condensation of 4-(trimethylsilylethynyl)benzaldehyde 1 with substituted o-phenylenediamines. These in turn were reacted with 2-(azidomethoxy)ethyl acetate in a Cu alkyne–azide cycloaddition (CuAAC) to generate the 1,2,3-triazole pharmacophore under microwave assistance. The newly synthesized compounds were examined for their in vitro antimicrobial activities against Gram-positive and Gram-negative bacteria and the phytopathoge...