Reactive evaporation of low-defect density hafnia

International Nuclear Information System (INIS)

Chow, R.; Falabella, S.; Loomis, G.E.; Rainer, F.; Stolz, C.J.; Kozlowski, M.R.

1993-01-01

Motivation for this work includes observations at Lawrence Livermore National Laboratory of a correlation between laser damage thresholds and both the absorption and the nodular-defect density of coatings. Activated oxygen is used to increase the metal-oxidation kinetics at the coated surface during electron-beam deposition. A series of hafnia layers are made with various conditions: two μ-wave configuations, two sources (hafnium and hafnia), and two reactive oxygen pressures. Laser damage thresholds (1064-nm, 10-ns pulses), absorption (at 511 nm), and nodular-defect densities from these coatings are reported. The damage thresholds are observed to increase as the absorption of the coatings decreases. However, no significant increase in damage thresholds are observed with the coatings made from a low nodular-defect density source material (hafnium). Hafnia coatings can be made from hafnium sources that have lower nodular-defect densities, lower absorption, and damage thresholds that are comparable with coatings made from a conventional hafnia source

Plasma synthesis of titanium nitride, carbide and carbonitride nanoparticles by means of reactive anodic arc evaporation from solid titanium

International Nuclear Information System (INIS)

Kiesler, D.; Bastuck, T.; Theissmann, R.; Kruis, F. E.

2015-01-01

Plasma methods using the direct evaporation of a transition metal are well suited for the cost-efficient production of ceramic nanoparticles. In this paper, we report on the development of a simple setup for the production of titanium-ceramics by reactive anodic arc evaporation and the characterization of the aerosol as well as the nanopowder. It is the first report on TiC X N 1 − X synthesis in a simple anodic arc plasma. By means of extensive variations of the gas composition, it is shown that the composition of the particles can be tuned from titanium nitride over a titanium carbonitride phase (TiC X N 1 − X ) to titanium carbide as proven by XRD data. The composition of the plasma gas especially a very low concentration of hydrocarbons around 0.2 % of the total plasma gas is crucial to tune the composition and to avoid the formation of free carbon. Examination of the particles by HR-TEM shows that the material consists mostly of cubic single crystalline particles with mean sizes between 8 and 27 nm

Influence of substrate temperature and annealing on structural and optical properties of TiO{sub 2} films deposited by reactive e-beam evaporation

Energy Technology Data Exchange (ETDEWEB)

Pjević, D., E-mail: dejanp@vinca.rs [VINČA Institute of Nuclear Sciences, University of Belgrade, PO Box 522, 11001 Belgrade (Serbia); Marinković, T.; Savić, J.; Bundaleski, N.; Obradović, M.; Milosavljević, M. [VINČA Institute of Nuclear Sciences, University of Belgrade, PO Box 522, 11001 Belgrade (Serbia); Kulik, M. [Frank Laboratory of Neutron Physics, JINR, Joliot-Curie St. 6, Dubna 141980, Moscow Region (Russian Federation)

2015-09-30

The influence of deposition and post-deposition annealing parameters on the structure and optical properties of TiO{sub 2} thin films synthesized by reactive e-beam evaporation is reported. Pure Ti (99.9%) was evaporated in oxygen atmosphere to form thin films on Si (100) and glass substrates. Depositions were conducted on substrates held at room temperature and at 200–400 °C heated substrates. Post-deposition annealing was done for 3 h at 500 °C in air. Compositional and structural studies were performed by Rutherford backscattering spectrometry, X-ray diffraction, and X-ray photoelectron spectroscopy, and optical properties were studied by ultraviolet–visible spectroscopy and analytically by pointwise unconstrained minimization approach method. It was found that both the structure and optical properties of the films are strongly influenced by the deposition and processing parameters. All deposited samples showed good stoichiometry of Ti:O ~ 1:2. Depending on the substrate temperature and oxygen pressure in the chamber during the deposition, anatase–rutile mixed films were obtained, and in some cases TiO and Ti{sub 2}O{sub 3} phases were observed. Substrate deposition temperature appears to play the major role on the final structure of the films, while post-deposition annealing adds up for the lack of oxygen in some cases and invokes crystal grain growth of already initiated phases. The results can be interesting towards the development of TiO{sub 2} thin films with defined structure and optical properties. - Highlights: • TiO{sub 2} films were deposited by reactive e-beam evaporation. • Structure and properties were studied as a function of deposition temperature. • Stoichiometry of as-deposited films was Ti:O ~ 1:2, containing different Ti-O phases. • Post-deposition annealing yielded phase transformation, affecting the properties. • Refractive index increases with the substrate deposition temperature.

242-A evaporator dangerous waste permit application

International Nuclear Information System (INIS)

1991-01-01

The 242-A Evaporator is a waste management unit within the Hanford Facility that consists of process vessels and support systems for heating, evaporating, and condensing double-shell tank (DST) waste generated by Hanford Site operations. Operation of the 242-A Evaporator serves to reduce the volume of waste solutions within the DSTs that do not self-boil, while separating inorganic and radionuclide constituents from organic constituents. This operation reduces the number of underground DSTs required for waste storage and also makes the mixed waste more suitable for future treatment and disposal (i.e., grouting and vitrification). The 242-A Evaporator receives mixed-waste streams from the DSTs that contain organic and inorganic constituents and radionuclides. The waste is a dangerous waste (DW) because of corrosivity, reactivity, and toxicity characteristics, and is an extremely hazardous waste (EHW) as a result of toxicity (state criteria only), carcinogenicity, and persistence under the state mixture rule. The waste also contains spent nonhalogenated solvents

Measuring low radium activity concentration in water with RAD7 by means of evaporation

International Nuclear Information System (INIS)

Kappke, Jaqueline; Marussig, Camila G.T.; Paschuk, Sergei; Zambianchi Junior, Pedro; Correa, Janine N.; Perna, Allan Felipe Nunes; Martin, Aline

2015-01-01

Preliminary activity measurements of low radium concentration in mineral water by using RAD7 equipment showed high values of statistical errors. Therefore, the need to develop a new protocol for measuring and proofing the evaporation test for radium measurements in water is in place. This study evaluates the possibility of using RAD7 equipment to measure Ra-226 activity in equilibrium with Rn-222 present in water samples. The technique involves evaporation process so as to increase the Ra-226 concentration in the sample in a controlled manner and thus reduce statistical errors. Two samples were compared, 10 L sample of distilled water and a 7.75 L sample of known concentration (0.1 Bq/L). The evaporation was carried out starting with different initial volumes for both samples: 500 mL, 1000 mL, 2000 mL, 4000 mL and a 250 mL sample not subject to evaporation. All samples reached a final volume of approximately 250 mL. After evaporation, the samples were stored for 30 days until secular equilibrium was achieved between Ra-226 and Rn-222. The values obtained, by using RAD7 detector, for distilled water, as expected, are near zero averaging 0.021 ± 0.016 Bq/L. The average value found in the water of known concentration was 0.099 ± 0.011 Bq/L, also close to the expected 0.1 Bq/L. The conclusion is that the application of an evaporation process is efficient and the proposed methodology is a proven alternative to decrease the statistical errors. (author)

Cardiovascular Reactivity, Stress, and Physical Activity

Directory of Open Access Journals (Sweden)

Chun-Jung eHuang

2013-11-01

Full Text Available Psychological stress has been proposed as a major contributor to the progression of cardiovascular disease (CVD. Acute mental stress can activate the sympathetic-adrenal-medullary (SAM axis, eliciting the release of catecholamines (NE and EPI resulting in the elevation of heart rate (HR and blood pressure (BP. Combined stress (psychological and physical can exacerbate these cardiovascular responses, which may partially contribute to the elevated risk of CVD and increased proportionate mortality risks experienced by some occupations (e.g., firefighting and law enforcement. Studies have supported the benefits of physical activity on physiological and psychological health, including the cardiovascular response to acute stress. Aerobically trained individuals exhibit lower sympathetic nervous system (e.g., HR reactivity and enhanced cardiovascular efficiency (e.g., lower vascular reactivity and decreased recovery time in response to physical and/or psychological stress. In addition, resistance training has been demonstrated to attenuate cardiovascular responses and improve mental health. This review will examine stress-induced cardiovascular reactivity and plausible explanations for how exercise training and physical fitness (aerobic and resistance exercise can attenuate cardiovascular responses to stress. This enhanced functionality may facilitate a reduction in the incidence of stroke and myocardial infarction. Finally, this review will also address the interaction of obesity and physical activity on cardiovascular reactivity and CVD.

Treatment of liquid radioactive waste: Evaporation

International Nuclear Information System (INIS)

Pfeiffer, R.

1982-01-01

About 10.000 m 3 of low active liquid waste (LLW) arise in the Nuclear Research Center Karlsruhe. Chemical contents of this liquid waste are generally not declared. Resulting from experiments carried out in the Center during the early sixties, the evaporator facility was built in 1968 for decontamination of LLW. The evaporators use vapor compression and concentrate recirculation in the evaporator sump by pumps. Since 1971 the medium active liquid waste (MLW) from the Karlsruhe Reprocessing Plant (WAK) was decontaminated in this evaporator facility, too. By this time the amount of low liquid waste (LLW) had been decontaminated without mentionable interruptions. Afterwards a lot of interruptions of operations occurred, mainly due to leakages of pumps, valves and pipes. There was also a very high radiation level for the operating personnel. As a consequence of this experience a new evaporator facility for decontamination of medium active liquid waste was built in 1974. This facility started operation in 1976. The evaporator has natural circulation and is heated by steam through a heat exchanger. (orig./RW)

Strong pinning in very fast grown reactive co-evaporated GdBa2Cu3O7 coated conductors

Directory of Open Access Journals (Sweden)

J. L. MacManus-Driscoll

2014-08-01

Full Text Available We report on compositional tuning to create excellent field-performance of Jc in “self-doped,” GdBa2Cu3O7−y (GdBCO coated conductors grown by ultrafast reactive co-evaporation. In order to give excess liquid and Gd2O3, the overall compositions were all Ba-poor and Cu-rich compared to GdBCO. The precise composition was found to be critical to the current carrying performance. The most copper-rich composition had an optimum self-field Jc of 3.2 MA cm−2. A more Gd-rich composition had the best in-field performance because of the formation of low coherence, splayed Gd2O3 nanoparticles, giving Jc (77 K, 1 T of over 1 MA cm−2 and Jc (77 K, 5 T of over 0.1 MA cm−2.

Characterizing Nanoparticles Reactivity: Structure-Photocatalytic Activity Relationship

International Nuclear Information System (INIS)

Piella, J; Bastús, N G; Casals, E; Puntes, V

2013-01-01

Nanoparticles are reactive, and their final interactions with the surrounding media are ultimately determined by their reactivity, which in turns depends on the nanoparticles morphology, surface chemistry and environment in which they are embedded. One simple and informative approach for the study of the reactivity of nanoparticles is the determination of their photocatalytic activity. In the present work, we briefly summarize the importance of different parameters such as the size, shape and agglomeration state on the photocatalytic activity of colloidal inorganic nanoparticles. The study of the use of nanoparticles as photocatalyts is relevant not only for its potential applications in environmental remediation issues but also it can provide relevant information about the role of these parameters at the nanoscale.

Evaporation

International Nuclear Information System (INIS)

Delaney, B.T.; Turner, R.J.

1989-01-01

Evaporation has long been used as a unit operation in the manufacture of various products in the chemical-process industries. In addition, it is currently being used for the treatment of hazardous wastes such as radioactive liquids and sludges, metal-plating wastes, and other organic and inorganic wastes. Design choice is dependent on the liquid to be evaporated. The three most common types of evaporation equipment are the rising-film, falling-film, and forced-circulation evaporators. The first two rely on boiling heat transfer and the latter relies on flash vaporization. Heat exchangers, flash tanks, and ejectors are common auxiliary equipment items incorporated with evaporator bodies to complete an evaporator system. Properties of the liquid to be evaporated are critical in final selection of an appropriate evaporator system. Since operating costs are a significant factor in overall cost, heat-transfer characteristics and energy requirements are important considerations. Properties of liquids which are critical to the determination of final design include: heat capacity, heat of vaporization, density, thermal conductivity, boiling point rise, and heat-transfer coefficient. Evaporation is an expensive technology, both in terms of capital costs and operating costs. Additionally, mechanical evaporation produces a condensate and a bottoms stream, one or both of which may require further processing or disposal. 3 figs

High-rate deposition of photocatalytic TiO2 films by oxygen plasma assist reactive evaporation method

International Nuclear Information System (INIS)

Sakai, Tetsuya; Kuniyoshi, Yuji; Aoki, Wataru; Ezoe, Sho; Endo, Tatsuya; Hoshi, Yoichi

2008-01-01

High-rate deposition of titanium dioxide (TiO 2 ) film was attempted using oxygen plasma assisted reactive evaporation (OPARE) method. Photocatalytic properties of the film were investigated. During the deposition, the substrate temperature was fixed at 400 deg. C. The film deposition rate can be increased by increasing the supply of titanium atoms to the substrate, although oversupply of the titanium atoms causes oxygen deficiency in the films, which limits the deposition rate. The film structure depends strongly on the supply ratio of oxygen molecules to titanium atoms O 2 /Ti and changes from anatase to rutile structure as the O 2 /Ti supply ratio increased. Consequently, the maximum deposition rates of 77.0 nm min -1 and 145.0 nm min -1 were obtained, respectively, for the anatase and rutile film. Both films deposited at such high rates showed excellent hydrophilicity and organic decomposition performance. Even the film with rutile structure deposited at 145.0 nm min -1 had a contact angle of less than 2.5 deg. by UV irradiation for 5.0 h and an organics-decomposition performance index of 8.9 [μmol l -1 min -1 ] for methylene blue

Investigation of the evaporation process conditions on the optical constants of zirconia films

International Nuclear Information System (INIS)

Dobrowolski, J.A.; Grant, P.D.; Simpson, R.; Waldorf, A.

1989-01-01

Deposition parameters required for producing zirconia films for use in optical multilayer systems by electron-beam gun evaporation of zirconia and zirconium starting materials were investigated. The optical constants were determined as a function of distance, partial pressure of oxygen, and angle of incidence. The direct and reactive evaporation processes yielded ZrO 2 films with refractive indices of 2.08 and 2.14, respectively, for vapor incident on the substrate at normal incidence

Iodine-catalyzed diazo activation to access radical reactivity.

Science.gov (United States)

Li, Pan; Zhao, Jingjing; Shi, Lijun; Wang, Jin; Shi, Xiaodong; Li, Fuwei

2018-05-17

Transition-metal-catalyzed diazo activation is a classical way to generate metal carbene, which are valuable intermediates in synthetic organic chemistry. An alternative iodine-catalyzed diazo activation is disclosed herein under either photo-initiated or thermal-initiated conditions, which represents an approach to enable carbene radical reactivity. This metal-free diazo activation strategy were successfully applied into olefin cyclopropanation and epoxidation, and applying this method to pyrrole synthesis under thermal-initiated conditions further demonstrates the unique reactivity using this method over typical metal-catalyzed conditions.

242-A evaporator hazards assessment

International Nuclear Information System (INIS)

Johnson, T.L.

1998-01-01

This document establishes the technical basis in support of Emergency Planning activities for the 242-A Evaporator, on the Hanford Site. Through this document the technical basis for the development of facility specific Emergency Action Levels and the Emergency Planning Zone is demonstrated. The evaporator sues a conventional, forced-circulation, vacuum evaporation system to concentrate radioactive waste solutions. This concentration results in the reduction in waste volume and reduces the number of double-shelled tanks required to store the waste

On Variable Reverse Power Flow-Part I: Active-Reactive Optimal Power Flow with Reactive Power of Wind Stations

Directory of Open Access Journals (Sweden)

Aouss Gabash

2016-02-01

Full Text Available It has recently been shown that using battery storage systems (BSSs to provide reactive power provision in a medium-voltage (MV active distribution network (ADN with embedded wind stations (WSs can lead to a huge amount of reverse power to an upstream transmission network (TN. However, unity power factors (PFs of WSs were assumed in those studies to analyze the potential of BSSs. Therefore, in this paper (Part-I, we aim to further explore the pure reactive power potential of WSs (i.e., without BSSs by investigating the issue of variable reverse power flow under different limits on PFs in an electricity market model. The main contributions of this work are summarized as follows: (1 Introducing the reactive power capability of WSs in the optimization model of the active-reactive optimal power flow (A-R-OPF and highlighting the benefits/impacts under different limits on PFs. (2 Investigating the impacts of different agreements for variable reverse power flow on the operation of an ADN under different demand scenarios. (3 Derivation of the function of reactive energy losses in the grid with an equivalent-π circuit and comparing its value with active energy losses. (4 Balancing the energy curtailment of wind generation, active-reactive energy losses in the grid and active-reactive energy import-export by a meter-based method. In Part-II, the potential of the developed model is studied through analyzing an electricity market model and a 41-bus network with different locations of WSs.

Evaporative and Convective Instabilities for the Evaporation of a Binary Mixture in a Bilayer System

Science.gov (United States)

Guo, Weidong; Narayanan, Ranga

2006-11-01

Evaporative convection in binary mixtures arises in a variety of industrial processes, such as drying of paint and coating technology. There have been theories devoted to this problem either by assuming a passive vapor layer or by isolating the vapor fluid dynamics. Previous work on evaporative and convective instabilities in a single component bilayer system suggests that active vapor layers play a major role in determining the instability of the interface. We have investigated the evaporation convection in binary mixtures taking into account the fluid dynamics of both phases. The liquid mixture and its vapor are assumed to be confined between two horizontal plates with a base state of zero evaporation but with linear vertical temperature profile. When the vertical temperature gradient reaches a critical value, the evaporative instability, Rayleigh and Marangoni convection set in. The effects of vapor and liquid depth, various wave numbers and initial composition of the mixture on the evaporative and convective instability are determined. The physics of the instability are explained and detailed comparison is made between the Rayleigh, Marangoni and evaporative convection in pure component and those in binary mixtures.

The analysis of false prolongation of the activated partial thromboplastin time (activator: silica): Interference of C-reactive protein.

Science.gov (United States)

Liu, Jie; Li, Fanfan; Shu, Kuangyi; Chen, Tao; Wang, Xiaoou; Xie, Yaoqi; Li, Shanshan; Zhang, Zhaohua; Jin, Susu; Jiang, Minghua

2018-05-13

To investigate the effect of C-reactive protein on the activated partial thromboplastin time (APTT) (different activators) in different detecting systems. The C-reactive protein and coagulation test of 112 patients with the infectious disease were determined by automation protein analyzer IMMAG 800 and automation coagulation analyzer STA-R Evolution, respectively. The pooled plasma APTT with different concentrations of C-reactive protein was measured by different detecting system: STA-R Evolution (activator: silica, kaolin), Sysmex CS-2000i (activator: ellagic acid), and ACL TOP 700 (activator: colloidal silica). In addition, the self-made platelet lysate (phospholipid) was added to correct the APTT prolonged by C-reactive protein (150 mg/L) on STA-R Evolution (activator: silica) system. The good correlation between C-reactive protein and APTT was found on the STA-R Evolution (activator: silica) system. The APTT on the STA-R Evolution (activator: silica) system was prolonged by 24.6 second, along with increasing C-reactive protein concentration. And the APTT of plasma containing 150 mg/L C-reactive protein was shortened by 3.4-6.9 second when the plasma was mixed with self-made platelet lysate. However, the APTT was prolonged unobviously on other detecting systems including STA-R Evolution (activator: kaolin), Sysmex CS-2000i, and ACL TOP 700. C-reactive protein interferes with the detection of APTT, especially in STA-R Evolution (activator: silica) system. The increasing in C-reactive protein results in a false prolongation of the APTT (activator: silica), and it is most likely that C-reactive protein interferes the coagulable factor binding of phospholipid. © 2018 Wiley Periodicals, Inc.

Re-Active Passive devices for control of noise transmission through a panel

Science.gov (United States)

Carneal, James P.; Giovanardi, Marco; Fuller, Chris R.; Palumbo, Dan

2008-01-01

Re-Active Passive devices have been developed to control low-frequency (transmission through a panel. These devices use a combination of active, re-active, and passive technologies packaged into a single unit to control a broad frequency range utilizing the strength of each technology over its best suited frequency range. The Re-Active Passive device uses passive constrained layer damping to cover relatively high-frequency range (>150 Hz), reactive distributed vibration absorber to cover the medium-frequency range (50-200 Hz), and active control for controlling low frequencies (transmission through a panel mounted in the Transmission Loss Test Facility at Virginia Tech. Experimental results are presented for the bare panel, and combinations of passive treatment, reactive treatment, and active control. Results indicate that three Re-Active Passive devices were able to increase the overall broadband (15-1000 Hz) transmission loss by 9.4 dB. These three devices added a total of 285 g to the panel mass of 6.0 kg, or approximately 5%, not including control electronics.

Photoelectrochemical behavior of Al{sub x}In{sub 1−x}N thin films grown by plasma-assisted dual source reactive evaporation

Energy Technology Data Exchange (ETDEWEB)

Alizadeh, M., E-mail: alizadeh_kozerash@yahoo.com; Ganesh, V.; Pandikumar, A.; Goh, B.T.; Azianty, S.; Huang, N.M.; Rahman, S.A., E-mail: saadah@um.edu.my

2016-06-15

In this work the dependence of photoelectrochemical (PEC) behavior of Al{sub x}In{sub 1−x}N (0.48 ≤x ≤ 0.66) thin films grown by plasma-assisted dual source reactive evaporation, on the plasma dynamics and the alloys properties was studied. The influence of nitrogen flow rate on the compositional, morphological, structural and optical properties of the as-prepared films were investigated using X-ray photoelectron spectroscopy (XPS), Field emission scanning electron microscopy (FESEM), micro Raman spectroscopy and UV–vis spectroscopy. The PEC study of the as-grown Al{sub x}In{sub 1−x}N thin films targeted for water splitting application were performed in the presence of simulated solar irradiation of AM 1.5G (100 mW/cm{sup 2}). The PEC results revealed that the photocurrent for the Al{sub x}In{sub 1−x}N thin film grown at nitrogen flow rate of 80 sccm is ∼10-fold higher than the dark current. From the Mott–Schottky (MS) plots it was deduced that by increasing N{sub 2} flow rate up to 80 sccm, the flat band potential shifts toward more negative values. The good photoelectrochemical behavior of Al{sub x}In{sub 1−x}N thin films showed that this material could be a potential candidate for PEC water splitting. - Highlights: • Al{sub x}In{sub 1−x}N films were grown by Plasma-aided dual source reactive evaporation. • Effect of nitrogen flow rate on the films properties was investigated. • The band gap of the films decreased from 2.33 to 1.92 eV. • A good photoelectrochemical behavior of the Al{sub x}In{sub 1−x}N thin films was shown. • The photocurrent for the Al{sub 0.55}In{sub 0.45}N films is ∼10-fold higher than dark current.

Redox-active media for permeable reactive barriers

International Nuclear Information System (INIS)

Sivavec, T.M.; Mackenzie, P.D.; Horney, D.P.; Baghel, S.S.

1997-01-01

In this paper, three classes of redox-active media are described and evaluated in terms of their long-term effectiveness in treating TCE-contaminated groundwater in permeable reactive zones. Zero-valent iron, in the form of recycled cast iron filings, the first class, has received considerable attention as a reactive media and has been used in about a dozen pilot- and full-scale subsurface wall installations. Criteria used in selecting commercial sources of granular iron, will be discussed. Two other classes of redox-active media that have not yet seen wide use in pilot- or full-scale installations will also be described: Fe(II) minerals and bimetallic systems. Fe(II) minerals, including magnetite (Fe 3 O 4 ), and ferrous sulfide (troilite, FeS), are redox-active and afford TCE reduction rates and product distributions that suggest that they react via a reductive mechanism similar to that which operates in the FeO system. Fe(II) species within the passive oxide layer coating the iron metal may act as electron transfer mediators, with FeO serving as the bulk reductant. Bimetallic systems, the third class of redox-active media, are commonly prepared by plating a second metal onto zero-valent iron (e.g., Ni/Fe and Pd/Fe) and have been shown to accelerate solvent degradation rates relative to untreated iron metal. The long-term effectiveness of this approach, however, has not yet been determined in groundwater treatability tests. The results of a Ni-plated iron column study using site groundwater indicate that a change in reduction mechanism (to catalytic dehydrohalogenation/hydrogenation) accounts for the observed rate enhancement. A significant loss in media reactivity was observed over time, attributable to Ni catalyst deactivation or poisoning. Zero-valent iron systems have not shown similar losses in reactivity in long-term laboratory, pilot or field investigations

Vortices generation in the reactive flow on the evaporative surface

Energy Technology Data Exchange (ETDEWEB)

Park, Cha Ryeom; Lee, Chang Jin [Konkuk University, Seoul (Korea, Republic of)

2015-02-15

Vortices generation and flow dynamics are investigated by a numerical calculation with LES methodology on the evaporative surface including chemical reactions. For simplicity, fuel is radially injected from the surface in order to decouple pyrolysis of solid fuel from the governing equation and consideration of heat transfer balance. Nevertheless its simple treatment of chemical reactions and fuel pyrolysis, numerical results captured very fundamental understandings in terms of averaged temperature, velocity profile, and mixture fraction distribution. Results showed that a well-defined turbulent velocity profile at the inlet becomes twisted and highly wrinkled in the downstream reaching the maximum velocity at far above the surface, where the flame is located. And the thickness of boundary layer increases in the downstream due to the enhanced interaction of axial flow and mass injection from the surface. Also, chemical reaction appears highly active and partially concentrated along the plane where flow condition is in stoichiometric. In particular, flame front locates at the surface where mixture fraction Z equals to 0.07. Flame front severely wrinkles in the downstream by the interaction with turbulences in the flow. Partial reactions on the flame front contribute to produce hot spots periodically in the downstream attaining the max temperature at the center of each spot. This may take the role of additional unsteady heat generations and pressure perturbations in the downstream. Future study will focus on the evolution of hot spots and pressure perturbations in the post chamber of lab scale hybrid rocket motors.

Reactive Coevaporation Synthesis and Characterization of SrTiO3 Thin Films

Science.gov (United States)

Yamaguchi, Hiromu; Matsubara, Shogo; Miyasaka, Yoichi

1991-09-01

SrTiO3 thin films were prepared by the reactive coevaporation method, where the Ti and Sr metals were evaporated in oxygen ambient with an E-gun and K-cell, respectively. A uniform depth profile in composition was achieved by altering the Ti evaporation rate according to the Sr evaporation rate change. A typical dielectric constant of 170 was measured on films of 75 nm in thickness. The in-situ annealing in oxygen plasma reduced the leakage current.

Miniature electron bombardment evaporation source: evaporation rate measurement

International Nuclear Information System (INIS)

Nehasil, V.; Masek, K.; Matolin, V.; Moreau, O.

1997-01-01

Miniature electron beam evaporation sources which operate on the principle of vaporization of source material, in the form of a tip, by electron bombardment are produced by several companies specialized in UHV equipment. These sources are used primarily for materials that are normally difficult to deposit due to their high evaporation temperature. They are appropriate for special applications such as heteroepitaxial thin film growth requiring a very low and well controlled deposition rate. A simple and easily applicable method of evaporation rate control is proposed. The method is based on the measurement of ion current produced by electron bombardment of evaporated atoms. The absolute evaporation flux values were measured by means of the Bayard-Alpert ion gauge, which enabled the ion current vs evaporation flux calibration curves to be plotted. (author). 1 tab., 4 figs., 6 refs

Evaporators

DEFF Research Database (Denmark)

Knudsen, Hans Jørgen Høgaard

1996-01-01

Type of evaporators. Regulation. Thermal dimensioning. Determination of pressure loss and heat transfer coefficients.......Type of evaporators. Regulation. Thermal dimensioning. Determination of pressure loss and heat transfer coefficients....

The experience of liquid radwaste evaporator performance improvement

International Nuclear Information System (INIS)

Kwon, S. H.

1997-01-01

Ulchin NPP has only one monobloc evaporation column which treated all radwaste liquid for two units. Since commercial operation in 1988 the evaporator performance is very poor. I think that the bad condition of evaporator is because of the bad quality of liquid radwaste, the large volume of liquid radwaste to treated, the poor skill of operation and some mistake in equipment design. Because of above conditions the average released activity by liquid radwaste is 35.153mCi/year in last eight years(1988∼1995). So it is necessary that we have to improve the evaporator performance and to reduce the liquid radwaste volume to evaporate

Evaporation equipment for the rational measurement of the radioactivity of water; Dispositif d'evaporation pour la mesure rationnelle de la radioactivite de l'eau

Energy Technology Data Exchange (ETDEWEB)

Hasenjager, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1960-07-01

An apparatus is described whereby the water can be evaporated directly in the radioactive sample holder in which the sample is counted. Rapid evaporation is obtained by the heating of the dish combined with the application of a jet of hot air. Liquid is added to the dish and the heating stopped automatically at the end of evaporation. The speed of evaporation and the Losses in activity as a function of the degree of heating were studied for various substances and different qualities of water (permuted water, tap water, rainwater). Complexones are added to avoid losses of activity. (author) [French] Un ensemble d'appareils permet d'evaporer l'eau directement dans la coupelle de mesure. Le chauffage de la coupelle combine avec l'application d'un jet d'air chaud assure une evaporation rapide. L'alimentation de la coupelle et l'arret du chauffage a la fin de l'evaporation sont automatiques. La vitesse d'evaporation et les pertes d'activite en fonction de l'intensite de chauffage ont ete etudiees pour differents corps et differentes qualites d'eau (eau permutee, eau de ville, eau de pluie). On ajoute des complexons pour eviter des pertes d'activites. (auteur)

GRANULAR ACTIVATED CARBON ADSORPTION AND INFRARED REACTIVATION: A CASE STUDY

Science.gov (United States)

A study evaluated the effectiveness and cost of removing trace organic contaminants and surrogates from drinking water by granular activated carbon (GAC) adsorption. The effect of multiple reactivations of spent GAC was also evaluated. Results indicated that reactivated GAC eff...

Flash evaporator

OpenAIRE

1997-01-01

A device and method for flash evaporating a reagent includes an evaporation chamber that houses a dome on which evaporation occurs. The dome is solid and of high thermal conductivity and mass, and may be heated to a temperature sufficient to vaporize a specific reagent. The reagent is supplied from an external source to the dome through a nozzle, and may be supplied as a continuous stream, as a shower, and as discrete drops. A carrier gas may be introduced into the evaporation chamber and cre...

Active and reactive power neurocontroller for grid-connected photovoltaic generation system

Directory of Open Access Journals (Sweden)

I. Abadlia

2016-03-01

Full Text Available Many researchers have contributed to the development of a firm foundation for analysis and design of control applications in grid-connected renewable energy sources. This paper presents an intelligent control algorithm fond on artificial neural networks for active and reactive power controller in grid-connected photovoltaic generation system. The system is devices into two parts in which each part contains an inverter with control algorithm. A DC/DC converter in output voltage established by control magnitude besides maximum power point tracker algorithm always finds optimal power of the PV array in use. A DC/AC hysteresis inverter designed can synchronize a sinusoidal current output with the grid voltage and accurate an independent active and reactive power control. Simulation results confirm the validation of the purpose. Neurocontroller based active and reactive power presents an efficiency control that guarantees good response to the steps changing in active and reactive power with an acceptable current/voltage synchronism. In this paper the power circuit and the control system of the presented grid-connected photovoltaic generation system is simulated and tested by MatLab/Simulink.

Genotype modulates testosterone-dependent activity and reactivity in male mice.

Science.gov (United States)

Broida, J; Svare, B

1983-03-01

Adult castration significantly reduced the homecage locomotor activity of both inbred C57BL/6J and DBA/2J and outbred Rockland-Swiss (R-S) male mice. Castrated C57BL animals exhibited greater reductions in this behavior than did the other genotypes. Locomotor activity in a novel environment (reactivity) was also reduced by castration but only for inbred males. In both test situations, postcastration reductions in ambulation were prevented by implants of testosterone (T)-containing Silastic capsules. Thus, testicular hormones promote activity and reactivity in the male mouse in a genotype-dependent fashion.

Removal of Sulfate Ion From AN-107 by Evaporation

International Nuclear Information System (INIS)

GJ Lumetta; GS Klinger; DE Kurath; RL Sell; LP Darnell; LR Greenwood; CZ Soderquist; MJ Steele; MW Urie; JJ Wagner

2000-01-01

Hanford low-activity waste solutions contain sulfate, which can cause accelerated corrosion of the vitrification melter and unacceptable operating conditions. A method is needed to selectively separate sulfate from the waste. An experiment was conducted to evaluate evaporation for removing sulfate ion from Tank AN-107 low-activity waste. Two evaporation steps were performed. In the first step, the volume was reduced by 55% while in the second step, the liquid volume was reduced another 22%. Analysis of the solids precipitated during these evaporations revealed that large amounts of sodium nitrate and nitrite co-precipitated with sodium sulfate. Many other waste components precipitated as well. It can be concluded that sulfate removal by precipitation is not selective, and thus, evaporation is not a viable option for removing sulfate from the AN-107 liquid

Water Evaporation from Acoustically Levitated Aqueous Solution Droplets.

Science.gov (United States)

Combe, Nicole A; Donaldson, D James

2017-09-28

We present a systematic study of the effect of solutes on the evaporation rate of acoustically levitated aqueous solution droplets by suspending individual droplets in a zero-relative humidity environment and measuring their size as a function of time. The ratios of the early time evaporation rates of six simple salts (NaCl, NaBr, NaNO 3 , KCl, MgCl 2 , CaCl 2 ) and malonic acid to that of water are in excellent agreement with predictions made by modifying the Maxwell equation to include the time-dependent water activity of the evaporating aqueous salt solution droplets. However, the early time evaporation rates of three ammonium salt solutions (NH 4 Cl, NH 4 NO 3 , (NH 4 ) 2 SO 4 ) are not significantly different from the evaporation rate of pure water. This finding is in accord with a previous report that ammonium sulfate does not depress the evaporation rate of its solutions, despite reducing its water vapor pressure, perhaps due to specific surface effects. At longer evaporation times, as the droplets approach crystallization, all but one (MgCl 2 ) of the solution evaporation rates are well described by the modified Maxwell equation.

Evaporation equipment for the rational measurement of the radioactivity of water

International Nuclear Information System (INIS)

Hasenjager, H.

1960-01-01

An apparatus is described whereby the water can be evaporated directly in the radioactive sample holder in which the sample is counted. Rapid evaporation is obtained by the heating of the dish combined with the application of a jet of hot air. Liquid is added to the dish and the heating stopped automatically at the end of evaporation. The speed of evaporation and the Losses in activity as a function of the degree of heating were studied for various substances and different qualities of water (permuted water, tap water, rainwater). Complexones are added to avoid losses of activity. (author) [fr

242-A Evaporator quality assurance plan. Revision 2

International Nuclear Information System (INIS)

Basra, T.S.

1995-01-01

The purpose of this quality assurance project plan (Plan) is to provide requirements for activities pertaining to sampling, shipping, and analyses associated with candidate feed tank samples for the 242-A Evaporator project. The purpose of the 242-A Evaporator project is to reduce the volume of aqueous waste in the Double Shell Tank (DST) System and will result in considerable savings to the disposal of mixed waste. The 242-A Evaporator feed stream originates from DSTs identified as candidate feed tanks. The 242-A Evaporator reduces the volume of aqueous waste contained in DSTs by boiling off water and sending the condensate (called process condensate) to the Liquid Effluent Retention Facility (LEPF) storage basin where it is stored prior to treatment in the Effluent Treatment Facility (ETF). The objective of this quality assurance project plan is to provide the planning, implementation, and assessment of sample collection and analysis, data issuance, and validation activities for the candidate feed tanks

Evaporational losses under different soil moisture regimes and atmospheric evaporativities using tritium

International Nuclear Information System (INIS)

Saxena, P.; Chaudhary, T.N.; Mookerji, P.

1991-01-01

Tritium as tracer was used in a laboratory study to estimate the contribution of moisture from different soil depths towards actual soil water evaporation. Results indicated that for comparable amounts of free water evaporation (5 cm), contribution of moisture from 70-80 cm soil layer towards total soil moisture loss through evaporation increased nearly 1.5 to 3 folds for soils with water table at 90 cm than without water table. Identical initial soil moistures were exposed to different atmospheric evaporativities. Similarly, for a given initial soil moisture status, upward movement of moisture from 70-80 cm soil layer under low evaporativity was nearly 8 to 12 times that of under high evaporativity at 5 cm free water evaporation value. (author). 6 refs., 4 tabs., 2 figs

2H Evaporator CP class instrumentation uncertainties evaluations

International Nuclear Information System (INIS)

Hwang, E.

1994-01-01

The Evaporator Pot Temperature Instrumentations and the Steam Condensate Gamma Monitors are two instrumentation systems in the 2H Evaporator facilities that are classified as the critical protection. The temperature high alarm and interlock circuit and the temperature recorder circuit of the pot temperature instrumentation loop are described. From the gamma monitor loop, the high gamma alarm and interlock circuit, failure alarm and interlock circuit, cesium activity recorder circuit, and americium activity recorder circuit are described

2H Evaporator CP class instrumentation uncertainties evaluations

Energy Technology Data Exchange (ETDEWEB)

Hwang, E.

1994-02-10

The Evaporator Pot Temperature Instrumentations and the Steam Condensate Gamma Monitors are two instrumentation systems in the 2H Evaporator facilities that are classified as the critical protection. The temperature high alarm and interlock circuit and the temperature recorder circuit of the pot temperature instrumentation loop are described. From the gamma monitor loop, the high gamma alarm and interlock circuit, failure alarm and interlock circuit, cesium activity recorder circuit, and americium activity recorder circuit are described. (GHH)

Heat and mass transfer analogies for evaporation models at high evaporation rate

OpenAIRE

Trontin , P.; Villedieu , P.

2014-01-01

International audience; In the framework of anti and deicing applications, heated liquid films can appear above the ice thickness, or directly above the wall. Then, evaporation plays a major role in the Messinger balance and evaporated mass has to be predicted accurately. Unfortunately, it appears that existing models under-estimate evaporation at high temperature. In this study, different evaporation models at high evaporation rates are studied. The different hypothesis on which these models...

Modeling Coupled Evaporation and Seepage in Ventilated Cavities

International Nuclear Information System (INIS)

Ghezzehei, T.; Trautz, R.; Finsterle, S.; Cook, P.; Ahlers, C.

2004-01-01

Cavities excavated in unsaturated geological formations are important to activities such as nuclear waste disposal and mining. Such cavities provide a unique setting for simultaneous occurrence of seepage and evaporation. Previously, inverse numerical modeling of field liquid-release tests and associated seepage into cavities were used to provide seepage-related large-scale formation properties by ignoring the impact of evaporation. The applicability of such models was limited to the narrow range of ventilation conditions under which the models were calibrated. The objective of this study was to alleviate this limitation by incorporating evaporation into the seepage models. We modeled evaporation as an isothermal vapor diffusion process. The semi-physical model accounts for the relative humidity, temperature, and ventilation conditions of the cavities. The evaporation boundary layer thickness (BLT) over which diffusion occurs was estimated by calibration against free-water evaporation data collected inside the experimental cavities. The estimated values of BLT were 5 to 7 mm for the open underground drifts and 20 mm for niches closed off by bulkheads. Compared to previous models that neglected the effect of evaporation, this new approach showed significant improvement in capturing seepage fluctuations into open cavities of low relative humidity. At high relative-humidity values (greater than 85%), the effect of evaporation on seepage was very small

Evaporation equipment for the rational measurement of the radioactivity of water; Dispositif d'evaporation pour la mesure rationnelle de la radioactivite de l'eau

Energy Technology Data Exchange (ETDEWEB)

Hasenjager, H. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1960-07-01

An apparatus is described whereby the water can be evaporated directly in the radioactive sample holder in which the sample is counted. Rapid evaporation is obtained by the heating of the dish combined with the application of a jet of hot air. Liquid is added to the dish and the heating stopped automatically at the end of evaporation. The speed of evaporation and the Losses in activity as a function of the degree of heating were studied for various substances and different qualities of water (permuted water, tap water, rainwater). Complexones are added to avoid losses of activity. (author) [French] Un ensemble d'appareils permet d'evaporer l'eau directement dans la coupelle de mesure. Le chauffage de la coupelle combine avec l'application d'un jet d'air chaud assure une evaporation rapide. L'alimentation de la coupelle et l'arret du chauffage a la fin de l'evaporation sont automatiques. La vitesse d'evaporation et les pertes d'activite en fonction de l'intensite de chauffage ont ete etudiees pour differents corps et differentes qualites d'eau (eau permutee, eau de ville, eau de pluie). On ajoute des complexons pour eviter des pertes d'activites. (auteur)

Re-active Passive (RAP) Devices for Control of Noise Transmission through a Panel

Science.gov (United States)

Carneal, James P.; Giovanardi, Marco; Fuller, Chris R.; Palumbo, Daniel L.

2008-01-01

Re-Active Passive (RAP) devices have been developed to control low frequency (transmission through a panel. These devices use a combination of active, re-active, and passive technologies packaged into a single unit to control a broad frequency range utilizing the strength of each technology over its best suited frequency range. The RAP device uses passive constrained layer damping to cover the relatively high frequency range (>200 Hz), reactive distributed vibration absorber) to cover the medium frequency range (75 to 250 Hz), and active control for controlling low frequencies (transmission through a panel mounted in a transmission loss test facility. Experimental results are presented for the bare panel, and combinations of passive treatment, reactive treatment, and active control. Results indicate that three RAP devices were able to increase the overall broadband (15-1000 Hz) transmission loss by 9.4 dB. These three devices added a total of 285 grams to the panel mass of 6.0 kg, or approximately 5%, not including control electronics.

HETEROGENEITY OF POLYCLONAL IMMUNOGLOBULINS NUCLEASE ACTIVITY IN RHEUMATOID AND REACTIVE ARTHRITIS

Directory of Open Access Journals (Sweden)

M. V. Volkova

2017-01-01

Full Text Available Catalytic properties of immunoglobulins are widely studied within recent years. It was found that nuclease activity of immunoglobulins is increased in systemic autoimmune diseases. Given some pathogenetic features of rheumatoid arthritis and reactive arthritis, it is appropriate to clarify the nature of nuclease activity in these diseases. Determination of DNAse activity of immunoglobulins with different DNA substrates, and search for specific substrates for distinct clinical entities could serve these purposes. The aim of present work is to determine DNase activity of the polyclonal class G immunoglobulins in rheumatoid and reactive arthritis using various methods.Different methods are used to evaluate nuclease activity. In this paper we present newly developed and modified techniques for determination of DNAse activity of polyclonal IgGs. Particular attention was paid to the electrophoretic method of DNase activity assessment. Polyclonal IgG isolated from blood serum of patients with rheumatoid arthritis and reactive arthritis were used for assays. In this study, we demonstrated the presence of an inhomogeneous DNase activity of immunoglobulins in relation to different substrates.Along with calf thymus DNA, we used bacterial plasmid DNA and PCR products based on bacterial gene sequences. Levels of DNase activity by rivanol clot method with calf thymus DNA as substrate proved to be higher in patients with rheumatoid arthritis than the control values (p < 0.01. DNase abzyme activity in patients with rheumatoid arthritis was elevated, as compared to the patients with reactive arthritis (p < 0.01.When examining ability of the IgG to hydrolyze procaryotic DNA (bacterial plasmid DNA and PCR products, based on bacterial genes, we obtained heterogeneous results. Different Ig samples showed varying degrees of DNA hydrolysis. Abzyme hydrolysis of DNA substrates longer than 700 bp was more pronounced, as compared to short DNA substrates (100 base pairs

Insight into the molecular mechanism of water evaporation via the finite temperature string method.

Science.gov (United States)

Musolino, Nicholas; Trout, Bernhardt L

2013-04-07

The process of water's evaporation at its liquid/air interface has proven challenging to study experimentally and, because it constitutes a rare event on molecular time scales, presents a challenge for computer simulations as well. In this work, we simulated water's evaporation using the classical extended simple point charge model water model, and identified a minimum free energy path for this process in terms of 10 descriptive order parameters. The measured free energy change was 7.4 kcal/mol at 298 K, in reasonable agreement with the experimental value of 6.3 kcal/mol, and the mean first-passage time was 1375 ns for a single molecule, corresponding to an evaporation coefficient of 0.25. In the observed minimum free energy process, the water molecule diffuses to the surface, and tends to rotate so that its dipole and one O-H bond are oriented outward as it crosses the Gibbs dividing surface. As the water molecule moves further outward through the interfacial region, its local density is higher than the time-averaged density, indicating a local solvation shell that protrudes from the interface. The water molecule loses donor and acceptor hydrogen bonds, and then, with its dipole nearly normal to the interface, stops donating its remaining hydrogen bond. At that point, when the final, accepted hydrogen bond is broken, the water molecule is free. We also analyzed which order parameters are most important in the process and in reactive trajectories, and found that the relative orientation of water molecules near the evaporating molecule, and the number of accepted hydrogen bonds, were important variables in reactive trajectories and in kinetic descriptions of the process.

Evaporator Cleaning Studies

International Nuclear Information System (INIS)

Wilmarth, W.R.

1999-01-01

Operation of the 242-16H High Level Waste Evaporator proves crucial to liquid waste management in the H-Area Tank Farm. Recent operational history of the Evaporator showed significant solid formation in secondary lines and in the evaporator pot. Additional samples remain necessary to ensure material identity in the evaporator pot. Analysis of these future samples will provide actinide partitioning information and dissolution characteristics of the solid material from the pot to ensure safe chemical cleaning

Mixed phase evaporation source

International Nuclear Information System (INIS)

1975-01-01

Apparatus for reducing convection current heat loss in electron beam evaporator is described. A material to be evaporated (evaporant) is placed in the crucible of an electron beam evaporation source along with a porous mass formed of a powdered or finely divided solid to act as an impedance to convection currents. A feed system is employed to replenish the supply of evaporant as it is vaporized

KEPLER PLANETS: A TALE OF EVAPORATION

International Nuclear Information System (INIS)

Owen, James E.; Wu, Yanqin

2013-01-01

Inspired by the Kepler mission's planet discoveries, we consider the thermal contraction of planets close to their parent star, under the influence of evaporation. The mass-loss rates are based on hydrodynamic models of evaporation that include both X-ray and EUV irradiation. We find that only low mass planets with hydrogen envelopes are significantly affected by evaporation, with evaporation being able to remove massive hydrogen envelopes inward of ∼0.1 AU for Neptune-mass objects, while evaporation is negligible for Jupiter-mass objects. Moreover, most of the evaporation occurs in the first 100 Myr of stars' lives when they are more chromospherically active. We construct a theoretical population of planets with varying core masses, envelope masses, orbital separations, and stellar spectral types, and compare this population with the sizes and densities measured for low-mass planets, both in the Kepler mission and from radial velocity surveys. This exercise leads us to conclude that evaporation is the driving force of evolution for close-in Kepler planets. In fact, some 50% of the Kepler planet candidates may have been significantly eroded. Evaporation explains two striking correlations observed in these objects: a lack of large radius/low density planets close to the stars and a possible bimodal distribution in planet sizes with a deficit of planets around 2 R ⊕ . Planets that have experienced high X-ray exposures are generally smaller than this size, and those with lower X-ray exposures are typically larger. A bimodal planet size distribution is naturally predicted by the evaporation model, where, depending on their X-ray exposure, close-in planets can either hold on to hydrogen envelopes ∼0.5%-1% in mass or be stripped entirely. To quantitatively reproduce the observed features, we argue that not only do low-mass Kepler planets need to be made of rocky cores surrounded with hydrogen envelopes, but few of them should have initial masses above 20 M ⊕ and

KEPLER PLANETS: A TALE OF EVAPORATION

Energy Technology Data Exchange (ETDEWEB)

Owen, James E. [Canadian Institute for Theoretical Astrophysics, 60 St. George Street, Toronto, ON M5S 3H8 (Canada); Wu, Yanqin, E-mail: jowen@cita.utoronto.ca, E-mail: wu@astro.utoronto.ca [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada)

2013-10-01

Inspired by the Kepler mission's planet discoveries, we consider the thermal contraction of planets close to their parent star, under the influence of evaporation. The mass-loss rates are based on hydrodynamic models of evaporation that include both X-ray and EUV irradiation. We find that only low mass planets with hydrogen envelopes are significantly affected by evaporation, with evaporation being able to remove massive hydrogen envelopes inward of ∼0.1 AU for Neptune-mass objects, while evaporation is negligible for Jupiter-mass objects. Moreover, most of the evaporation occurs in the first 100 Myr of stars' lives when they are more chromospherically active. We construct a theoretical population of planets with varying core masses, envelope masses, orbital separations, and stellar spectral types, and compare this population with the sizes and densities measured for low-mass planets, both in the Kepler mission and from radial velocity surveys. This exercise leads us to conclude that evaporation is the driving force of evolution for close-in Kepler planets. In fact, some 50% of the Kepler planet candidates may have been significantly eroded. Evaporation explains two striking correlations observed in these objects: a lack of large radius/low density planets close to the stars and a possible bimodal distribution in planet sizes with a deficit of planets around 2 R{sub ⊕}. Planets that have experienced high X-ray exposures are generally smaller than this size, and those with lower X-ray exposures are typically larger. A bimodal planet size distribution is naturally predicted by the evaporation model, where, depending on their X-ray exposure, close-in planets can either hold on to hydrogen envelopes ∼0.5%-1% in mass or be stripped entirely. To quantitatively reproduce the observed features, we argue that not only do low-mass Kepler planets need to be made of rocky cores surrounded with hydrogen envelopes, but few of them should have initial masses above

Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

Energy Technology Data Exchange (ETDEWEB)

Adamson, Duane J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nash, Charles A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Crawford, Charles L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Wilmarth, William R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2014-01-01

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter

Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

International Nuclear Information System (INIS)

Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

2014-01-01

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter

The characterisation of non-evaporable getters by Auger electron spectroscopy Analytical potential and artefacts

CERN Document Server

Scheuerlein, C; Taborelli, M

2002-01-01

The surfaces of getter materials are particularly difficult to analyse because of their high chemical reactivity. The results obtained can be strongly influenced by the experimental set-up and procedures. In this paper the experimental influence on the Auger electron spectroscopy results is discussed, based on the measurements of more than 100 different non-evaporable getter (NEG) materials. There are four typical changes in the Auger electron spectra when a NEG becomes activated. The oxygen peak intensity decreases, the shape of the metal peaks changes, the carbon peak shape changes shape and intensity and a chlorine peak occurs. All these changes are affected by instrumental artefacts. The Zr-MNV peak shape changes occurring during the reduction of ZrO2 are well suited to determine the onset of NEG activation, while the slope with which the O-KLL peak intensity decreases in a certain temperature range is a better criterion for the determination of the temperature at which activation is complete. The O-KLL i...

Evaporation of boric acid from sea water

Energy Technology Data Exchange (ETDEWEB)

Gast, J A; Thompson, T G

1959-01-01

Previous investigators have shown that the boron-chlorinity ratios of rain waters are many times greater than the boron-chlorinity ratio of sea water. The presence of boron in the atmosphere has been attributed to sea spray, volcanic activity, accumulation in dust, evaporation from plants, and industrial pollution. In this paper data are presented to demonstrate that boric acid in sea water has a vapor pressure at ordinary temperatures of the sea and, when sea water evaporates, boric acid occurs in the condensate of the water vapor. It is postulated that, while some of the boron in the atmosphere can be attributed to the sources mentioned above, most of the boric acid results from evaporation from the sea.

Forest evaporation models: Relationships between stand growth and evaporation

CSIR Research Space (South Africa)

Le Maitre, David C

1997-06-01

Full Text Available The relationships between forest stand structure, growth and evaporation were analysed to determine whether forest evaporation can be estimated from stand growth data. This approach permits rapid assessment of the potential impacts of afforestation...

Review of Active and Reactive Power Sharing Strategies in Hierarchical Controlled Microgrids

DEFF Research Database (Denmark)

Han, Yang; Li, Hong; Shen, Pan

2017-01-01

Microgrids consist of multiple parallel-connected distributed generation (DG) units with coordinated control strategies, which are able to operate in both grid-connected and islanded mode. Microgrids are attracting more and more attention since they can alleviate the stress of main transmission...... systems, reduce feeder losses, and improve system power quality. When the islanded microgrids are concerned, it is important to maintain system stability and achieve load power sharing among the multiple parallel-connected DG units. However, the poor active and reactive power sharing problems due...... in this paper for active power sharing. Moreover, nonlinear and unbalanced loads could further affect the reactive power sharing when regulating the active power, and it is difficult to share the reactive power accurately only by using the enhanced virtual impedance method. Therefore, the hierarchical control...

Influence of the evaporation rate and the evaporation mode on the hydrogen sorption kinetics of air-exposed magnesium films

International Nuclear Information System (INIS)

Leon, A.; Knystautas, E.J.; Huot, J.; Schulz, R.

2006-01-01

It has been shown that the hydrogen sorption properties of air-exposed magnesium films are influenced by the deposition parameters such as the evaporation rate or the evaporation mode used during their preparation. As the evaporation rate increases, the structure of the film tends to be highly oriented along the [002] direction and the kinetics of hydrogen absorption and desorption are faster. Moreover, the hydrogen sorption kinetics of magnesium films prepared with an electron beam source under a high vacuum are faster by almost a factor of two compared to those prepared using resistive heating under low vacuum. These two parameters reduce drastically the activation and the incubation period during hydrogen absorption and desorption, respectively

Evaporative cooling: Effective latent heat of evaporation in relation to evaporation distance from the skin

NARCIS (Netherlands)

Havenith, G.; Bröde, P.; Hartog, E.A. den; Kuklane, K.; Holmer, I.; Rossi, R.M.; Richards, M.; Farnworth, B.; Wang, X.

2013-01-01

Calculation of evaporative heat loss is essential to heat balance calculations. Despite recognition that the value for latent heat of evaporation, used in these calculations, may not always reflect the real cooling benefit to the body, only limited quantitative data on this is available, which has

Introducing ultrasonic falling film evaporator for moderate temperature evaporation enhancement.

Science.gov (United States)

Dehbani, Maryam; Rahimi, Masoud

2018-04-01

In the present study, Ultrasonic Falling Film (USFF), as a novel technique has been proposed to increase the evaporation rate of moderate temperature liquid film. It is a proper method for some applications which cannot be performed at high temperature, such as foodstuff industry, due to their sensitivity to high temperatures. Evaporation rate of sodium chloride solution from an USFF on an inclined flat plate compared to that for Falling Film without ultrasonic irradiation (FF) at various temperatures was investigated. The results revealed that produced cavitation bubbles have different effects on evaporation rate at different temperatures. At lower temperatures, size fluctuation and collapse of bubbles and in consequence induced physical effects of cavitation bubbles resulted in more turbulency and evaporation rate enhancement. At higher temperatures, the behavior was different. Numerous created bubbles joined together and cover the plate surface, so not only decreased the ultrasound vibrations but also reduced the evaporation rate in comparison with FF. The highest evaporation rate enhancement of 353% was obtained at 40 °C at the lowest Reynolds number of 250. In addition, the results reveal that at temperature of 40 °C, USFF has the highest efficiency compared to FF. Copyright © 2017 Elsevier B.V. All rights reserved.

Active control of evaporative solution deposition by means of modulated gas phase convection

NARCIS (Netherlands)

Wedershoven, H.M.J.M.; Deuss, K.R.M.; Fantin, C.; Zeegers, J.C.H.; Darhuber, A.A.

2018-01-01

In solution processing, functional materials are dissolved or dispersed in a solvent and deposited typically as a thin liquid film on a substrate. After evaporation of the solvent, a dry layer remains. We propose an ‘active’, non-contact technique for evaporative pattern formation that does not

Preparation and evaporation of Hanford Waste treatment plant direct feed low activity waste effluent management facility simulant

Energy Technology Data Exchange (ETDEWEB)

Adamson, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nash, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Howe, A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-09-07

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Melter Off-Gas Condensate, LMOGC) from the off-gas system. The baseline plan for disposition of this stream during full WTP operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation, and recycled to the LAW vitrification facility. However, during the Direct Feed LAW (DFLAW) scenario, planned disposition of this stream involves concentrating the condensate in a new evaporator at the Effluent Management Facility (EMF) and returning it to the LAW melter. The LMOGC stream will contain components, e.g. halides and sulfates, that are volatile at melter temperatures, have limited solubility in glass waste forms, and present a material corrosion concern. Because this stream will recycle within WTP, these components are expected to accumulate in the LMOGC stream, exacerbating their impact on the number of LAW glass containers that must be produced. Diverting the stream reduces the halides and sulfates in the glass and is a key objective of this program. In order to determine the disposition path, it is key to experimentally determine the fate of contaminants. To do this, testing is needed to account for the buffering chemistry of the components, determine the achievable evaporation end point, identify insoluble solids that form, determine the formation and distribution of key regulatoryimpacting constituents, and generate an aqueous stream that can be used in testing of the subsequent immobilization step. This overall program examines the potential treatment and immobilization of the LMOGC stream to enable alternative disposal. The objective of this task was to (1) prepare a simulant of the LAW Melter Off-gas Condensate expected during DFLAW operations, (2) demonstrate evaporation in order to predict the final composition of the effluents from the EMF

Formation of Particulate Matter from the Oxidation of Evaporated Wastewater from Hydraulic Fracturing Activity

Science.gov (United States)

Hildebrandt Ruiz, L.; Bean, J. K.; Bilotto, A.

2017-12-01

The use of hydraulic fracturing for production of petroleum and natural gas has increased dramatically in the last decade, but the environmental impacts of this technology remain unclear. Experiments were conducted to quantify airborne emissions from twelve samples of hydraulic fracturing flowback wastewater collected in the Permian Basin, as well as the photochemical processing of these emissions leading to the formation of particulate matter. The concentration of total volatile carbon (TVC, hydrocarbons evaporating at room temperature) averaged 29 milligrams of carbon per liter (mgC/L) and the TVC evaporation rate averaged 1357 mgC/L-m2-min. After photochemical oxidation under high NOx conditions the amount of organic particulate matter formed per milliliter of wastewater evaporated averaged 24 micrograms (µg); the amount of ammonium nitrate formed averaged 262 µg. In the state of Texas, the potential formation of PM from evaporated flowback wastewater is similar to the estimated PM emissions from diesel engines used in oil rigs, emphasizing the need to quantify wastewater evaporation and atmospheric processing of these emissions.

Vacuum evaporation of pure metals

OpenAIRE

Safarian, Jafar; Engh, Thorvald Abel

2013-01-01

Theories on the evaporation of pure substances are reviewed and applied to study vacuum evaporation of pure metals. It is shown that there is good agreement between different theories for weak evaporation, whereas there are differences under intensive evaporation conditions. For weak evaporation, the evaporation coefficient in Hertz-Knudsen equation is 1.66. Vapor velocity as a function of the pressure is calculated applying several theories. If a condensing surface is less than one collision...

Evaporation in hydrology and meteorology

OpenAIRE

Brandsma, T.

1990-01-01

In this paper the role of evaporation in hydrology and meteorology is discussed, with the emphasis on hydrology. The basic theory of evaporation is given and methods to determine evaporation are presented. Some applications of evaporation studies in literature are given in order to illustrate the theory. Further, special conditions in evaporation are considered, followed by a fotmulation of the difficulties in determining evaporation, The last part of the paper gives a short discussion about ...

Humidity-insensitive water evaporation from molecular complex fluids.

Science.gov (United States)

Salmon, Jean-Baptiste; Doumenc, Frédéric; Guerrier, Béatrice

2017-09-01

We investigated theoretically water evaporation from concentrated supramolecular mixtures, such as solutions of polymers or amphiphilic molecules, using numerical resolutions of a one-dimensional model based on mass transport equations. Solvent evaporation leads to the formation of a concentrated solute layer at the drying interface, which slows down evaporation in a long-time-scale regime. In this regime, often referred to as the falling rate period, evaporation is dominated by diffusive mass transport within the solution, as already known. However, we demonstrate that, in this regime, the rate of evaporation does not also depend on the ambient humidity for many molecular complex fluids. Using analytical solutions in some limiting cases, we first demonstrate that a sharp decrease of the water chemical activity at high solute concentration leads to evaporation rates which depend weakly on the humidity, as the solute concentration at the drying interface slightly depends on the humidity. However, we also show that a strong decrease of the mutual diffusion coefficient of the solution enhances considerably this effect, leading to nearly independent evaporation rates over a wide range of humidity. The decrease of the mutual diffusion coefficient indeed induces strong concentration gradients at the drying interface, which shield the concentration profiles from humidity variations, except in a very thin region close to the drying interface.

Refractory material crucibles evaluation for U evaporation

International Nuclear Information System (INIS)

Damiao, A.J.; Vasconcelos, G.; Silveira, C.A.B.; Rodrigues, N.A.S.

1996-01-01

In studies that involve small amounts of U vapor generation, such as spectroscopy or thin films, most of the E-gun power is delivered to the cooling system. Normally crucibles are used as container and thermal insulator. Since liquid U is extremely reactive at evaporation temperatures, the crucibles are seriously attacked, decreasing the insulation efficiency and adding contaminants to the U vapor. There is no complete solution for the problem, however, with a careful choice of materials, one can design crucibles with extended lifetime and reduced contamination. This work reports some preliminary results we have obtained in the assessing of crucible materials and design, such as, graphite, Si C, vitreous carbon and Al 2 O 3 . (author)

DMPD: NF-kappaB activation by reactive oxygen species: fifteen years later. [Dynamic Macrophage Pathway CSML Database

Lifescience Database Archive (English)

Full Text Available 16723122 NF-kappaB activation by reactive oxygen species: fifteen years later. Gloi...svg) (.html) (.csml) Show NF-kappaB activation by reactive oxygen species: fifteen years later. PubmedID 167...23122 Title NF-kappaB activation by reactive oxygen species: fifteen years later.

The influence of pH, temperature and hydrolyzate concentration on the removal of volatile and nonvolatile compounds from sugarcane bagasse hemicellulosic hydrolyzate treated with activated charcoal before or after vacuum evaporation

Directory of Open Access Journals (Sweden)

R.C.L.B. Rodrigues

2001-09-01

Full Text Available This paper analyzes the influence of pH, temperature and degree of hydrolyzate concentration on the removal of volatile and nonvolatile compounds from sugarcane bagasse hemicellulosic hydrolyzate treated with activated charcoal before or after the vacuum evaporation process. Furfural and 5-Hydroxymethylfurfural were almost totally removed in all the experiments, irrespective of pH and temperature and whether the charcoal was added before or after the vacuum evaporation process. Adding activated charcoal before the vacuum evaporation process favored the removal of phenolic compounds for all values of pH. Acetic acid, on the contrary, was most effectively removed when the activated charcoal was added after the vacuum evaporation process at an acid pH (0.92 and at the highest degree of hydrolyzate concentration (f=4. However, addition of activated charcoal before or after vacuum evaporation at an acid pH (0.92 and at the highest degree of hydrolyzate concentration (f=4 favored the removal of both acetic acid and phenolic compounds.

On the link between potential evaporation and regional evaporation from a CBL perspective

Science.gov (United States)

Lhomme, J. P.; Guilioni, L.

2010-07-01

The relationship between potential evaporation and actual evaporation was first examined by Bouchet (Proc Berkeley Calif Symp IAHS Publ, 62:134-142, 1963) who considered potential evaporation as the consequence of regional evaporation due to atmospheric feedbacks. Using a heuristic approach, he derived a complementary relationship which, despite no real theoretical background, has proven to be very useful in interpreting many experimental data under various climatic conditions. Here, the relationship between actual and potential evaporation is reinterpreted in the context of the development of the convective boundary layer (CBL): first, with a closed-box approach, where the CBL has an impermeable lid; and then with an open system, where air is exchanged between the CBL and its external environment. By applying steady forcing to these systems, it is shown that an equilibrium state is reached, where potential evaporation has a specific equilibrium formulation as a function of two parameters: one representing large-scale advection and the other the feedback effect of regional evaporation on potential evaporation, i.e. a kind of “medium-scale advection”. It is also shown that the original form of Bouchet’s complementary relationship is not verified in the equilibrium state. This analysis leads us to propose a new and more rational approach of the relationship between potential and actual evaporation through the effective surface resistance of the region.

EVAPORATION FORM OF ICE CRYSTALS IN SUBSATURATED AIR AND THEIR EVAPORATION MECHANISM

OpenAIRE

ゴンダ, タケヒコ; セイ, タダノリ; Takehiko, GONDA; Tadanori, SEI

1987-01-01

The evaporation form and the evaporation mechanism of dendritic ice crystals grown in air of 1.0×(10)^5 Pa and at water saturation and polyhedral ice crystals grown in air of 4.0×10 Pa and at relatively low supersaturation are studied. In the case of dendritic ice crystals, the evaporation preferentially occurs in the convex parts of the crystal surfaces and in minute secondary branches. On the other hand, in the case of polyhedral ice crystals, the evaporation preferentially occurs in the pa...

Evaporation and Climate Change

NARCIS (Netherlands)

Brandsma, T.

1993-01-01

In this article the influence of climate change on evaporation is discussed. The emphasis is on open water evaporation. Three methods for calculating evaporation are compared considering only changes in temperature and factors directly dependent on temperature. The Penman-method is used to

Convection-enhanced water evaporation

OpenAIRE

B. M. Weon; J. H. Je; C. Poulard

2011-01-01

Water vapor is lighter than air; this can enhance water evaporation by triggering vapor convection but there is little evidence. We directly visualize evaporation of nanoliter (2 to 700 nL) water droplets resting on silicon wafer in calm air using a high-resolution dual X-ray imaging method. Temporal evolutions of contact radius and contact angle reveal that evaporation rate linearly changes with surface area, indicating convective (instead of diffusive) evaporation in nanoliter water droplet...

Evaporation in hydrology and meteorology

NARCIS (Netherlands)

Brandsma, T.

1990-01-01

In this paper the role of evaporation in hydrology and meteorology is discussed, with the emphasis on hydrology. The basic theory of evaporation is given and methods to determine evaporation are presented. Some applications of evaporation studies in literature are given in order to illustrate the

Duplex Tear Film Evaporation Analysis.

Science.gov (United States)

Stapf, M R; Braun, R J; King-Smith, P E

2017-12-01

Tear film thinning, hyperosmolarity, and breakup can cause irritation and damage to the human eye, and these form an area of active investigation for dry eye syndrome research. Recent research demonstrates that deficiencies in the lipid layer may cause locally increased evaporation, inducing conditions for breakup. In this paper, we explore the conditions for tear film breakup by considering a model for tear film dynamics with two mobile fluid layers, the aqueous and lipid layers. In addition, we include the effects of osmosis, evaporation as modified by the lipid, and the polar portion of the lipid layer. We solve the system numerically for reasonable parameter values and initial conditions and analyze how shifts in these cause changes to the system's dynamics.

Evaporation Of Hanford Waste Treatment Plant Direct Feed Low Activity Waste Effluent Management Facility Core Simulant

Energy Technology Data Exchange (ETDEWEB)

Adamson, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nash, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Mcclane, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-09-01

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Melter Off-Gas Condensate, LMOGC) from the off-gas system. The baseline plan for disposition of this stream during full WTP operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation, and recycled to the LAW vitrification facility. However, during the Direct Feed LAW (DFLAW) scenario, planned disposition of this stream is to evaporate it in a new evaporator, in the Effluent Management Facility (EMF), and then return it to the LAW melter. It is important to understand the composition of the effluents from the melter and new evaporator, so that the disposition of these streams can be accurately planned and accommodated. Furthermore, alternate disposition of the LMOGC stream would eliminate recycling of problematic components, and would reduce the need for closely integrated operation of the LAW melter and the Pretreatment Facilities. Long-term implementation of this option after WTP start-up would decrease the LAW vitrification mission duration and quantity of glass waste, amongst the other operational complexities such a recycle stream presents. In order to accurately plan for the disposition path, it is key to experimentally determine the fate of contaminants. To do this, testing is needed to accurately account for the buffering chemistry of the components, determine the achievable evaporation end point, identify insoluble solids that form, and determine the distribution of key regulatory-impacting constituents. The LAW Melter Off-Gas Condensate stream will contain components that are volatile at melter temperatures, have limited solubility in the glass waste form, and represent a materials corrosion concern, such as halides and sulfate. Because this stream will recycle within WTP, these components will accumulate in the Melter Condensate

Refractory material crucibles evaluation for U evaporation

Energy Technology Data Exchange (ETDEWEB)

Damiao, A.J.; Vasconcelos, G.; Silveira, C.A.B.; Rodrigues, N.A.S. [Centro Tecnico Aeroespacial (CTA-IEAv), Sao Jose dos Campos, SP (Brazil). Inst. de Estudos Avancados

1996-12-31

In studies that involve small amounts of U vapor generation, such as spectroscopy or thin films, most of the E-gun power is delivered to the cooling system. Normally crucibles are used as container and thermal insulator. Since liquid U is extremely reactive at evaporation temperatures, the crucibles are seriously attacked, decreasing the insulation efficiency and adding contaminants to the U vapor. There is no complete solution for the problem, however, with a careful choice of materials, one can design crucibles with extended lifetime and reduced contamination. This work reports some preliminary results we have obtained in the assessing of crucible materials and design, such as, graphite, Si C, vitreous carbon and Al{sub 2} O{sub 3}. (author) 1 refs., 3 figs.,2 tabs.

Variability in cold front activities modulating cool-season evaporation from a southern inland water in the USA

International Nuclear Information System (INIS)

Liu Heping; Blanken, Peter D; Weidinger, Tamas; Nordbo, Annika; Vesala, Timo

2011-01-01

Understanding seasonal variations in the evaporation of inland waters (e.g., lakes and reservoirs) is important for water resource management as well as the prediction of the hydrological cycles in response to climate change. We analyzed eddy covariance-based evaporation measurements from the Ross Barnett Reservoir (32 deg. 26'N, 90 0 02'W; which is always ice-free) in central Mississippi during the cool months (i.e., September-March) of 2007 and 2008, and found that the variability in cold front activities (i.e., passages of cold fronts and cold/dry air masses behind cold fronts) played an important role in modulating the exchange of sensible (H) and latent (λE) heat fluxes. Our analysis showed that 2007's warmer cool season had smaller mean H and λE than 2008's cooler cool season. This implies that the warmer cool season did not accelerate evaporation and heat exchange between the water surface and the atmosphere. Instead, more frequent cold fronts and longer periods of cold/dry air masses behind the cold fronts in 2008 resulted in overall larger H and λE as compared with 2007, this primarily taking the form of sporadic short-term rapid 'pulses' of H and λE losses from the water's surface. These results suggest that future climate-induced changes in frequency of cold fronts and the meteorological properties of the air masses behind cold fronts (e.g., wind speeds, temperature, and humidity), rather than other factors of climate change, would produce significant variations in the water surface's energy fluxes and subsequent evaporation rates.

Out-of-tank evaporator demonstration. Final report

International Nuclear Information System (INIS)

Lucero, A.J.; Jennings, H.L.; VanEssen, D.C.

1998-02-01

The project reported here was conducted to demonstrate a skid-mounted, subatmospheric evaporator to concentrate liquid low-level waste (LLLW) stored in underground tanks at Oak Ridge National Laboratory (ORNL). This waste is similar to wastes stored at Hanford and Savannah River. A single-stage subatmospheric evaporator rated to produce 90 gallons of distillate per hour was procured from Delta Thermal, Inc., of Pensacola, Florida, and installed in an existing building. During the 8-day demonstration, 22,000 gal of LLLW was concentrated by 25% with the evaporator system. Decontamination factors achieved averaged 5 x 10 6 (i.e., the distillate contained five million times less Cesium 137 than the feed). Evaporator performance substantially exceeded design requirements and expectations based on bench-scale surrogate test data. Out-of tank evaporator demonstration operations successfully addressed the feasibility of hands-on maintenance. Demonstration activities indicate that: (1) skid-mounted, mobile equipment is a viable alternative for the treatment of ORNL LLLW, and (2) hands-on maintenance and decontamination for movement to another site is achievable. Cost analysis show that 10% of the demonstration costs will be immediately recovered by elimination of solidification and disposal costs. The entire cost of the demonstration can be recovered by processing the inventory of Melton Valley Storage Tank waste and/or sluice water prior to solidifications. An additional savings of approximately $200,000 per year can be obtained by processing newly generated waste through the system. The results indicate that this type of evaporator system should be considered for application across the DOE complex. 25 refs., 11 figs., 2 tabs

Peroxide Activation for Electrophilic Reactivity by the Binuclear Non-heme Iron Enzyme AurF

International Nuclear Information System (INIS)

Park, Kiyoung; Li, Ning; Kwak, Yeonju; Srnec, Martin

2017-01-01

Binuclear non-heme iron enzymes activate O 2 for diverse chemistries that include oxygenation of organic substrates and hydrogen atom abstraction. This process often involves the formation of peroxo-bridged biferric intermediates, only some of which can perform electrophilic reactions. To elucidate the geometric and electronic structural requirements to activate peroxo reactivity, the active peroxo intermediate in 4-aminobenzoate N-oxygenase (AurF) has been characterized spectroscopically and computationally. A magnetic circular dichroism study of reduced AurF shows that its electronic and geometric structures are poised to react rapidly with O 2 . Nuclear resonance vibrational spectroscopic definition of the peroxo intermediate formed in this reaction shows that the active intermediate has a protonated peroxo bridge. Density functional theory computations on the structure established here show that the protonation activates peroxide for electrophilic/single-electron-transfer reactivity. As a result, this activation of peroxide by protonation is likely also relevant to the reactive peroxo intermediates in other binuclear non-heme iron enzymes.

Thermodynamic Modeling of the SRS Evaporators: Part II. The 3H System

Energy Technology Data Exchange (ETDEWEB)

Jantzen, C.M.

2001-10-02

Accumulations of two solid phases have formed scale deposits in the Savannah River Site 2H Evaporator system since late 1996. The aluminosilicate scale deposits caused the evaporator pot to become inoperable in October 1999. Accumulations of the diuranate phase have caused criticality concerns in the SRS 2H Evaporator. In order to ensure that similar deposits are not and will not form in the SRS 3H Evaporator, thermodynamically derived activity diagrams specific to the feeds processed from Tanks 30 and 32 are evaluated in this report.

Turkish Undergraduates' Misconceptions of Evaporation, Evaporation Rate, and Vapour Pressure

Science.gov (United States)

Canpolat, Nurtac

2006-01-01

This study focused on students' misconceptions related to evaporation, evaporation rate, and vapour pressure. Open-ended diagnostic questions were used with 107 undergraduates in the Primary Science Teacher Training Department in a state university in Turkey. In addition, 14 students from that sample were interviewed to clarify their written…

Hydrothermal waves in evaporating sessile drops

OpenAIRE

Brutin, D.; Rigollet, F.; Niliot, C. Le

2009-01-01

Drop evaporation is a simple phenomena but still unclear concerning the mechanisms of evaporation. A common agreement of the scientific community based on experimental and numerical work evidences that most of the evaporation occurs at the triple line. However, the rate of evaporation is still empirically predicted due to the lack of knowledge on the convection cells which develop inside the drop under evaporation. The evaporation of sessile drop is more complicated than it appears due to the...

Does evaporation paradox exist in China?

Directory of Open Access Journals (Sweden)

Z. T. Cong

2009-03-01

Full Text Available One expected consequence of global warming is the increase in evaporation. However, lots of observations show that the rate of evaporation from open pans of water has been steadily decreasing all over the world in the past 50 years. The contrast between expectation and observation is called "evaporation paradox". Based on data from 317 weather stations in China from 1956 to 2005, the trends of pan evaporation and air temperature were obtained and evaporation paradox was analyzed. The conclusions include: (1 From 1956 to 2005, pan evaporation paradox existed in China as a whole while pan evaporation kept decreasing and air temperature became warmer and warmer, but it does not apply to Northeast and Southeast China; (2 From 1956 to 1985, pan evaporation paradox existed narrowly as a whole with unobvious climate warming trend, but it does not apply to Northeast China; (3 From 1986 to 2005, in the past 20 years, pan evaporation paradox did not exist for the whole period while pan evaporation kept increasing, although it existed in South China. Furthermore, the trend of other weather factors including sunshine duration, windspeed, humidity and vapor pressure deficit, and their relations with pan evaporation are discussed. As a result, it can be concluded that pan evaporation decreasing is caused by the decreasing in radiation and wind speed before 1985 and pan evaporation increasing is caused by the decreasing in vapor pressure deficit due to strong warming after 1986. With the Budyko curve, it can be concluded that the actual evaporation decreased in the former 30 years and increased in the latter 20 year for the whole China.

Design and development of a split-evaporator heat-pump system

Energy Technology Data Exchange (ETDEWEB)

Somerville, M.H.; Penoncello, S.G.

1981-12-01

The designs and experimental results of three types of multiple source heat pumps are presented. The three designs are the parallel evaporator, the series evaporator, and the parallel evaporator with active subcooling, with the parallel evaporator with the active subcooling showing the most promise for solving the problem of defrosting of air evaporators. Three design procedures for multiple source heat pumps were developed. One of these is a hand calculational procedure, the others are computer based. The models are based upon the refrigerant flow rate, rather than the refrigeration effect of the evaporator. The technical results of a detailed analytical and experimental model of the heat transfer rates on a flat plate ice maker are presented. It is shown, both analytically and experimentally, that the temperature of the air surrounding the flat plate ice maker can play a dominant role in the rate of ice formation. A detailed weather analysis for forty cities located throughout the nation was completed. These data were processed to allow easy computation of thermal storage requirements for full, partial, or minimum ACES systems, or upon other design requirements, such as off-peak air conditioning. The results of an innovative ice storage system that is thermally coupled to the earth are described. This system has the potential for meeting both the off-peak air conditioning needs and the thermal storage requirements for the heating cycle. An economic and energy comparison of multiple source heat pumps with ACES, and air-to-air heat pump systems is presented.

Droplet bubbling evaporatively cools a blowfly.

Science.gov (United States)

Gomes, Guilherme; Köberle, Roland; Von Zuben, Claudio J; Andrade, Denis V

2018-04-19

Terrestrial animals often use evaporative cooling to lower body temperature. Evaporation can occur from humid body surfaces or from fluids interfaced to the environment through a number of different mechanisms, such as sweating or panting. In Diptera, some flies move tidally a droplet of fluid out and then back in the buccopharyngeal cavity for a repeated number of cycles before eventually ingesting it. This is referred to as the bubbling behaviour. The droplet fluid consists of a mix of liquids from the ingested food, enzymes from the salivary glands, and antimicrobials, associated to the crop organ system, with evidence pointing to a role in liquid meal dehydration. Herein, we demonstrate that the bubbling behaviour also serves as an effective thermoregulatory mechanism to lower body temperature by means of evaporative cooling. In the blowfly, Chrysomya megacephala, infrared imaging revealed that as the droplet is extruded, evaporation lowers the fluid´s temperature, which, upon its re-ingestion, lowers the blowfly's body temperature. This effect is most prominent at the cephalic region, less in the thorax, and then in the abdomen. Bubbling frequency increases with ambient temperature, while its cooling efficiency decreases at high air humidities. Heat transfer calculations show that droplet cooling depends on a special heat-exchange dynamic, which result in the exponential activation of the cooling effect.

Microwave heating type evaporator

International Nuclear Information System (INIS)

Taura, Masazumi; Nishi, Akio; Morimoto, Takashi; Izumi, Jun; Tamura, Kazuo; Morooka, Akihiko.

1987-01-01

Purpose: To prevent evaporization stills against corrosion due to radioactive liquid wastes. Constitution: Microwaves are supplied from a microwave generator by way of a wave guide tube and through a microwave permeation window to the inside of an evaporatization still. A matching device is attached to the wave guide tube for transmitting the microwaves in order to match the impedance. When the microwaves are supplied to the inside of the evaporization still, radioactive liquid wastes supplied from a liquid feed port by way of a spray tower to the inside of the evaporization still is heated and evaporated by the induction heating of the microwaves. (Seki, T.)

Vapor-based interferometric measurement of local evaporation rate and interfacial temperature of evaporating droplets.

Science.gov (United States)

Dehaeck, Sam; Rednikov, Alexey; Colinet, Pierre

2014-03-04

The local evaporation rate and interfacial temperature are two quintessential characteristics for the study of evaporating droplets. Here, it is shown how one can extract these quantities by measuring the vapor concentration field around the droplet with digital holographic interferometry. As a concrete example, an evaporating freely receding pending droplet of 3M Novec HFE-7000 is analyzed at ambient conditions. The measured vapor cloud is shown to deviate significantly from a pure-diffusion regime calculation, but it compares favorably to a new boundary-layer theory accounting for a buoyancy-induced convection in the gas and the influence upon it of a thermal Marangoni flow. By integration of the measured local evaporation rate over the interface, the global evaporation rate is obtained and validated by a side-view measurement of the droplet shape. Advective effects are found to boost the global evaporation rate by a factor of 4 as compared to the diffusion-limited theory.

Coordinated Volt/Var Control in Distribution Systems with Distributed Generations Based on Joint Active and Reactive Powers Dispatch

Directory of Open Access Journals (Sweden)

Abouzar Samimi

2016-01-01

Full Text Available One of the most significant control schemes in optimal operation of distribution networks is Volt/Var control (VVC. Owing to the radial structure of distribution systems and distribution lines with a small X/R ratio, the active power scheduling affects the VVC issue. A Distribution System Operator (DSO procures its active and reactive power requirements from Distributed Generations (DGs along with the wholesale electricity market. This paper proposes a new operational scheduling method based on a joint day-ahead active/reactive power market at the distribution level. To this end, based on the capability curve, a generic reactive power cost model for DGs is developed. The joint active/reactive power dispatch model presented in this paper motivates DGs to actively participate not only in the energy markets, but also in the VVC scheme through a competitive market. The proposed method which will be performed in an offline manner aims to optimally determine (i the scheduled active and reactive power values of generation units; (ii reactive power values of switched capacitor banks; and (iii tap positions of transformers for the next day. The joint active/reactive power dispatch model for daily VVC is modeled in GAMS and solved with the DICOPT solver. Finally, the plausibility of the proposed scheduling framework is examined on a typical 22-bus distribution test network over a 24-h period.

Thermogravimetric analysis of fuel film evaporation

Institute of Scientific and Technical Information of China (English)

HU Zongjie; LI Liguang; YU Shui

2006-01-01

Thermogravimetric analysis (TGA) was compared with the petrochemical distillation measurement method to better understand the characteristics of fuel film evaporation at different wall tem- peratures. The film evaporation characteristics of 90# gasoline, 93# gasoline and 0# diesel with different initial thicknesses were investigated at different environmental fluxes and heating rates. The influences of heating rate, film thickness and environmental flux on fuel film evaporation for these fuels were found. The results showed that the environmental conditions in TGA were similar to those for fuel films in the internal combustion engines, so data from TGA were suitable for the analysis of fuel film evaporation. TGA could simulate the key influencing factors for fuel film evaporation and could investigate the basic quantificational effect of heating rate and film thickness. To get a rapid and sufficient fuel film evaporation, sufficiently high wall temperature is necessary. Evaporation time decreases at a high heating rate and thin film thickness, and intense gas flow is important to promoting fuel film evaporation. Data from TGA at a heating rate of 100℃/min are fit to analyze the diesel film evaporation during cold-start and warming-up. Due to the tense molecular interactions, the evaporation sequence could not be strictly divided according to the boiling points of each component for multicomponent dissolved mixture during the quick evaporation process, and the heavier components could vaporize before reaching their boiling points. The 0# diesel film would fully evaporate when the wall temperature is beyond 250℃.

Investigation of Adsorption Thermodynamics on Removal of Reactive Blue 19 onto Activated Carbon under Ultrasonic Irradiation

International Nuclear Information System (INIS)

Sayan, E.; Nuri, O.; Edecan, M.E.

2014-01-01

Adsorption thermodynamics of reactive blue 19, which is commonly used in textile industry, has been studied onto activated carbon. The adsorption experiments have been carried out using combined ultrasound/activated carbon. The equilibrium adsorption data were analyzed by using the Langmuir and Freundlich isotherms. The equilibrium parameter, RL indicates that adsorption of reactive blue 19 onto activated carbon is favorable for all the concentrations studied. Thermodynamics parameters, Gads, Hads, Sads have also been calculated from the slope and intercept of the plot of ln Kd vs. 1/T. The thermodynamic parameters studied show that the adsorption of Reactive Blue 19 onto activated carbon is endothermic. (author)

Thermodynamic Modeling of Savannah River Evaporators

Energy Technology Data Exchange (ETDEWEB)

Weber, C.F.

2001-08-02

A thermodynamic model based on the code SOLGASMIX is developed to calculate phase equilibrium in evaporators and related tank wastes at the Savannah River Site (SRS). This model uses the Pitzer method to calculate activity coefficients, and many of the required Pitzer parameters have been determined in the course of this work. Principal chemical species in standard SRS simulant solutions are included, and the temperature range for most parameters has been extended above 100 C. The SOLGASMIX model and calculations using the code Geochemists Workbench are compared to actual solubility data including silicate, aluminate, and aluminosilicate solutions. In addition, SOLGASMIX model calculations are also compared to transient solubility data involving SRS simulant solutions. These comparisons indicate that the SOLGASMIX predictions closely match reliable data over the range of temperature and solution composition expected in the SRS evaporator and related tanks. Predictions using the Geochemists Workbench may be unreliable, due primarily to the use of an inaccurate activity coefficient model.

Effect of nitrogen flow rate on structural, morphological and optical properties of In-rich In{sub x}Al{sub 1−x}N thin films grown by plasma-assisted dual source reactive evaporation

Energy Technology Data Exchange (ETDEWEB)

Alizadeh, M., E-mail: alizadeh_kozerash@yahoo.com [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Ganesh, V.; Goh, B.T. [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Dee, C.F.; Mohmad, A.R. [Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, Bangi, Selangor (Malaysia); Rahman, S.A., E-mail: saadah@um.edu.my [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

2016-08-15

Highlights: • In-rich In{sub x}Al{sub 1−x}N films were grown by Plasma-aided reactive evaporation. • Effect of nitrogen flow rate on the films properties was investigated. • The band gap of the films was varied from 1.17 to 0.90 eV. • By increasing N{sub 2} flow rate the In{sub x}Al{sub 1−x}N films tend to turn into amorphous state. • At higher N{sub 2} flow rate agglomeration of the particles is highly enhanced. - Abstract: In-rich In{sub x}Al{sub 1−x}N thin films were deposited on quartz substrate at various nitrogen flow rates by plasma-assisted dual source reactive evaporation technique. The elemental composition, surface morphology, structural and optical properties of the films were investigated by X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Raman spectroscopy, X-ray diffraction (XRD), UV–vis spectrophotometer and photoluminescence (PL) measurements. XPS results revealed that the indium composition (x) of the In{sub x}Al{sub 1−x}N films increases from 0.90 to 0.97 as the nitrogen flow rate is increased from 40 to 100 sccm, respectively. FESEM images of the surface and cross-sectional microstructure of the In{sub x}Al{sub 1−x}N films showed that by increasing the N{sub 2} flow rate, the grown particles are highly agglomerated. Raman and XRD results indicated that by increasing nitrogen flow rate the In-rich In{sub x}Al{sub 1−x}N films tend to turn into amorphous state. It was found that band gap energy of the films are in the range of 0.90–1.17 eV which is desirable for the application of full spectra solar cells.

WTP Pilot-Scale Evaporation Tests

International Nuclear Information System (INIS)

QURESHI, ZAFAR

2004-01-01

This report documents the design, assembly, and operation of a Pilot-Scale Evaporator built and operated by SRTC in support of Waste Treatment Plant (WTP) Project at the DOE's Hanford Site. The WTP employs three identical evaporators, two for the Waste Feed and one for the Treated LAW. The Pilot-Scale Evaporator was designed to test simulants for both of these waste streams. The Pilot-Scale Evaporator is 1/76th scale in terms of evaporation rates. The basic configuration of forced circulation vacuum evaporator was employed. A detailed scaling analysis was performed to preserve key operating parameters such as basic loop configuration, system vacuum, boiling temperature, recirculation rates, vertical distances between important hardware pieces, reboiler heat transfer characteristics, vapor flux, configuration of demisters and water spray rings. Three evaporation test campaigns were completed. The first evaporation run used water in order to shake down the system. The water runs were important in identifying a design flaw that inhibited mixing in the evaporator vessel, thus resulting in unstable boiling operation. As a result the loop configuration was modified and the remaining runs were completed successfully. Two simulant runs followed the water runs. Test 1: Simulated Ultrafiltration Recycles with HLW SBS, and Test 2: Treated AN102 with Envelop C LAW. Several liquid and offgas samples were drawn from the evaporator facility for regulatory and non-regulatory analyses. During Test 2, the feed and the concentrate were spiked with organics to determine organic partitioning. The decontamination factor (DF) for Test 1 was measured to be 110,000 (more than the expected value of 100,000). Dow Corning Q2-3183A antifoam agent was tested during both Tests 1 and 2. It was determined that 500 ppm of this antifoam agent was sufficient to control the foaminess to less than 5 per cent of the liquid height. The long-term testing (around 100 hours of operation) did not show any

Evaporation of Lennard-Jones clusters

International Nuclear Information System (INIS)

Roman, C.E.; Garzon, I.L.

1991-01-01

Extensive molecular dynamics simulations have been done to study the evaporation of a 13-atom Lennard-Jones cluster. The survival probability and the evaporative lifetime are calculated as a function of the cluster total energy from a classical trajectory analysis. The results are interpreted in terms of the RRK theory of unimolecular dissociation. The calculation of the binding energy of the evaporated species from the evaporation rate and the average kinetic energy release is discussed. (orig.)

Evaporation of inclined water droplets

Science.gov (United States)

Kim, Jin Young; Hwang, In Gyu; Weon, Byung Mook

2017-01-01

When a drop is placed on a flat substrate tilted at an inclined angle, it can be deformed by gravity and its initial contact angle divides into front and rear contact angles by inclination. Here we study on evaporation dynamics of a pure water droplet on a flat solid substrate by controlling substrate inclination and measuring mass and volume changes of an evaporating droplet with time. We find that complete evaporation time of an inclined droplet becomes longer as gravitational influence by inclination becomes stronger. The gravity itself does not change the evaporation dynamics directly, whereas the gravity-induced droplet deformation increases the difference between front and rear angles, which quickens the onset of depinning and consequently reduces the contact radius. This result makes the evaporation rate of an inclined droplet to be slow. This finding would be important to improve understanding on evaporation dynamics of inclined droplets. PMID:28205642

Re-activation of degraded nickel cermet anodes - Nano-particle formation via reverse current pulses

DEFF Research Database (Denmark)

Hauch, Anne; Marchese, M.; Lanzini, A.

2018-01-01

The Ni/yttria-stabilized-zirconia (YSZ) cermet is the most commonly applied fuel electrode for solid oxide cells (SOCs). Loss of Ni/YSZ electrode activity is a key life-time limiting factor of the SOC. Developing means to mitigate this loss of performance or re-activate a fuel electrode is theref......The Ni/yttria-stabilized-zirconia (YSZ) cermet is the most commonly applied fuel electrode for solid oxide cells (SOCs). Loss of Ni/YSZ electrode activity is a key life-time limiting factor of the SOC. Developing means to mitigate this loss of performance or re-activate a fuel electrode...

Resveratrol Reactivates Latent HIV through Increasing Histone Acetylation and Activating Heat Shock Factor 1.

Science.gov (United States)

Zeng, Xiaoyun; Pan, Xiaoyan; Xu, Xinfeng; Lin, Jian; Que, Fuchang; Tian, Yuanxin; Li, Lin; Liu, Shuwen

2017-06-07

The persistence of latent HIV reservoirs presents a significant challenge to viral eradication. Effective latency reversing agents (LRAs) based on "shock and kill" strategy are urgently needed. The natural phytoalexin resveratrol has been demonstrated to enhance HIV gene expression, although its mechanism remains unclear. In this study, we demonstrated that resveratrol was able to reactivate latent HIV without global T cell activation in vitro. Mode of action studies showed resveratrol-mediated reactivation from latency did not involve the activation of silent mating type information regulation 2 homologue 1 (SIRT1), which belonged to class-3 histone deacetylase (HDAC). However, latent HIV was reactivated by resveratrol mediated through increasing histone acetylation and activation of heat shock factor 1 (HSF1). Additionally, synergistic activation of the latent HIV reservoirs was observed under cotreatment with resveratrol and conventional LRAs. Collectively, this research reveals that resveratrol is a natural LRA and shows promise for HIV therapy.

Block of glucocorticoid synthesis during re-activation inhibits extinction of an established fear memory.

Science.gov (United States)

Blundell, Jacqueline; Blaiss, Cory A; Lagace, Diane C; Eisch, Amelia J; Powell, Craig M

2011-05-01

The pharmacology of traumatic memory extinction has not been fully characterized despite its potential as a therapeutic target for established, acquired anxiety disorders, including post-traumatic stress disorder (PTSD). Here we examine the role of endogenous glucocorticoids in traumatic memory extinction. Male C57BL/6J mice were injected with corticosterone (10 mg/kg, i.p.) or metyrapone (50 mg/kg, s.c.) during re-activation of a contextual fear memory, and compared to vehicle groups (N=10-12 per group). To ensure that metyrapone was blocking corticosterone synthesis, we measured corticosterone levels following re-activation of a fear memory in metyrapone- and vehicle-treated animals. Corticosterone administration following extinction trials caused a long-lasting inhibition of the original fear memory trace. In contrast, blockade of corticosteroid synthesis with metyrapone prior to extinction trials enhanced retrieval and prevented extinction of context-dependent fear responses in mice. Further behavioral analysis suggested that the metyrapone enhancement of retrieval and prevention of extinction were not due to non-specific alterations in locomotor or anxiety-like behavior. In addition, the inhibition of extinction by metyrapone was rescued by exogenous administration of corticosterone following extinction trials. Finally, we confirmed that the rise in corticosterone during re-activation of a contextual fear memory was blocked by metyrapone. We demonstrate that extinction of a classical contextual fear memory is dependent on endogenous glucocorticoid synthesis during re-activation of a fear memory. Our data suggest that decreased glucocorticoids during fear memory re-activation may contribute to the inability to extinguish a fear memory, thus contributing to one of the core symptoms of PTSD. Copyright © 2011 Elsevier Inc. All rights reserved.

Autonomous Active and Reactive Power Distribution Strategy in Islanded Microgrids

DEFF Research Database (Denmark)

Wu, Dan; Tang, Fen; Guerrero, Josep M.

2014-01-01

This paper proposes an autonomous active and reactive power distribution strategy that can be applied directly on current control mode (CCM) inverters, being compatible as well with conventional droop-controlled voltage control mode (VCM) converters. In a microgrid, since renewable energy sources...

The Effect Of Organic Surfactants On The Properties Of Common Hygroscopic Particles: Effective Densities, Reactivity And Water Evaporation Of Surfactant Coated Particles

Science.gov (United States)

Cuadrarodriguez, L.; Zelenyuk, A.; Imre, D.; Ellison, B.

2006-12-01

Measurements of atmospheric aerosol compositions routinely show that organic compounds account for a very large fraction of the particle mass. The organic compounds that make up this aerosol mass represent a wide range of molecules with a variety of properties. Many of the particles are composed of hygroscopic salts like sulfates, nitrates and sea-salt internally mixed with organics. While the properties of the hygroscopic salts are known, the effect of the organic compounds on the microphysical and chemical properties which include CCN activity is not clear. .One particularly interesting class of internally mixed particles is composed of aqueous salts solutions that are coated with organic surfactants which are molecules with long aliphatic chain and a water soluble end. Because these molecules tend to coat the particles' surfaces, a monolayer might be sufficient to drastically alter their hygroscopic properties, their CCN activity, and reactivity. The aliphatic chains, being exposed to the oxidizing atmosphere are expected to be transformed through heterogeneous chemistry, yielding complex products with mixed properties. We will report the results from a series of observations on ammonium sulfate, sodium chloride and sea salt particles coated with three types of surfactant molecules: sodium lauryl sulfate, sodium oleate and laurtrimonium chloride. We have been able to measure the effective densities of internally mixed particles with a range of surfactant concentration that start below a monolayer and extend all the way to particles composed of pure surfactant. For many of the measurements the data reveal a rather complex picture that cannot be simply interpreted in terms of the known pure-compound densities. For unsaturated hydrocarbons we observed and quantified the effect of oxidation by ozone on particle size, effective density and individual particle mass spectral signatures. One of the more important properties of these surfactants is that they can form a

Performance improvement of a hybrid air conditioning system using the indirect evaporative cooler with internal baffles as a pre-cooling unit

Directory of Open Access Journals (Sweden)

A.E. Kabeel

2017-12-01

Full Text Available In the present paper, the effects of the indirect evaporative cooler with internal baffle on the performance of the hybrid air conditioning system are numerically investigated. The hybrid air conditioning system contains two indirect evaporative coolers with internal baffle, one is utilized to pre-cool the air inlet to the desiccant wheel and the other is utilized to pre-cool the supply air inlet to the room. The effects of the inlet conditions of the process and reactivation air and working air ratio on the thermal performance of the hybrid air conditioning system have been analyzed. The results of this study show that in the hybrid air conditioning system for using the indirect evaporative cooler with internal baffle as a pre-cooling unit, the supply air temperature reduced by 21% and the coefficient of performance improved by 71% as compared to previous designs of the hybrid air conditioning system at the same inlet conditions. For increasing process air inlet temperature from 25 °C to 45 °C, supply air temperature increases from 12.7 °C to 14.2 °C, thermal COP increases from 1.87 to 2.84, and supply air relative humidity increases from 76.7% to 77.4%. Also, for increasing the reactivation air inlet temperature from 70 °C to 110 °C, supply air temperature dropped from 15.9 °C to 10.9 °C, supply air relative humidity dropped from 82.7% to 71.8%, and thermal COP dropped from 4.5 to 1.7. The recommended optimal air working ratio in the indirect evaporative cooler with internal baffle should be 0.15. Keywords: Desiccant material, Solar air collector, Evaporative cooler, Internal baffles, Air conditioning

Nabarlek evaporation and storage ponds: possible role of biological activity in the escape of toxic substances to the general environment

International Nuclear Information System (INIS)

Martinick, W.

1982-01-01

An investigation was undertaken to determine whether or not game birds might become contaminated with radionuclides while visiting the evaporating ponds at the Nabarlek uranium mine. The level of biological community development in the ponds and water bird activity were low. It is concluded that at present escape of radionuclides or toxic elements from the ponds as a result of biological activity is not a problem

Process control plan for 242-A Evaporator Campaign 95-1

Energy Technology Data Exchange (ETDEWEB)

Le, E.Q.; Guthrie, M.D.

1995-05-18

The wastes from tanks 106-AP, 107-AP, and 106-AW have been selected to be candidate feed wastes for Evaporator Campaign 95-1. The wastes in tank 106-AP and 107-AP are primarily from B-Plant strontium processing and PUREX neutralized cladding removal, respectively. The waste in tank 106-AW originated primarily from the partially concentrated product from 242-A Evaporator Campaign 94-2. Approximately 8.67 million liters of waste from these tanks will be transferred to tank 102-AW during the campaign. Tank 102-AW is the dedicated waste feed tank for the evaporator and currently contains 647,000 liters of processable waste. The purpose of the 242-A Evaporator Campaign 95-1 Process Control Plan (hereafter referred to as PCP) is to certify that the wastes in tanks 106-AP, 107-AP, 102-AW, and 106-AW are acceptable for processing through evaporator and provide a general description of process strategies and activities which will take place during Campaign 95-1. The PCP also summarizes and presents a comprehensive characterization of the wastes in these tanks.

Process control plan for 242-A Evaporator Campaign 95-1

International Nuclear Information System (INIS)

Le, E.Q.; Guthrie, M.D.

1995-01-01

The wastes from tanks 106-AP, 107-AP, and 106-AW have been selected to be candidate feed wastes for Evaporator Campaign 95-1. The wastes in tank 106-AP and 107-AP are primarily from B-Plant strontium processing and PUREX neutralized cladding removal, respectively. The waste in tank 106-AW originated primarily from the partially concentrated product from 242-A Evaporator Campaign 94-2. Approximately 8.67 million liters of waste from these tanks will be transferred to tank 102-AW during the campaign. Tank 102-AW is the dedicated waste feed tank for the evaporator and currently contains 647,000 liters of processable waste. The purpose of the 242-A Evaporator Campaign 95-1 Process Control Plan (hereafter referred to as PCP) is to certify that the wastes in tanks 106-AP, 107-AP, 102-AW, and 106-AW are acceptable for processing through evaporator and provide a general description of process strategies and activities which will take place during Campaign 95-1. The PCP also summarizes and presents a comprehensive characterization of the wastes in these tanks

Radioactive Waste Evaporation: Current Methodologies Employed for the Development, Design, and Operation of Waste Evaporators at the Savannah River Site and Hanford Waste Treatment Plant

International Nuclear Information System (INIS)

Calloway, T.B.

2003-01-01

Evaporation of High level and Low Activity (HLW and LAW) radioactive wastes for the purposes of radionuclide separation and volume reduction has been conducted at the Savannah River and Hanford Sites for more than forty years. Additionally, the Savannah River Site (SRS) has used evaporators in preparing HLW for immobilization into a borosilicate glass matrix. This paper will discuss the methodologies, results, and achievements of the SRTC evaporator development program that was conducted in support of the SRS and Hanford WTP evaporator processes. The cross pollination and application of waste treatment technologies and methods between the Savannah River and Hanford Sites will be highlighted. The cross pollination of technologies and methods is expected to benefit the Department of Energy's Mission Acceleration efforts by reducing the overall cost and time for the development of the baseline waste treatment processes

Liquid evaporation process and evaporator

International Nuclear Information System (INIS)

Bergey, Claude; Ravenel, Jacques.

1975-01-01

The process described enables a liquid to be evaporated rapidly without any projection. A jet of hot gas is applied to the liquid, the power and angle of the jet being chosen so as to spin the liquid. It is particularly used in the case of radioactive products [fr

Physicochemical model for reactive sputtering of hot target

Energy Technology Data Exchange (ETDEWEB)

Shapovalov, Viktor I., E-mail: vishapovalov@mail.ru; Karzin, Vitaliy V.; Bondarenko, Anastasia S.

2017-02-05

A physicochemical model for reactive magnetron sputtering of a metal target is described in this paper. The target temperature in the model is defined as a function of the ion current density. Synthesis of the coating occurs due to the surface chemical reaction. The law of mass action, the Langmuir isotherm and the Arrhenius equation for non-isothermal conditions were used for mathematical description of the reaction. The model takes into consideration thermal electron emission and evaporation of the target surface. The system of eight algebraic equations, describing the model, was solved for the tantalum target sputtered in the oxygen environment. It was established that the hysteresis effect disappears with the increase of the ion current density. - Highlights: • When model is applied for a cold target, hysteresis width is proportional to the ion current density. • Two types of processes of hot target sputtering are possible, depending on the current density: with and without the hysteresis. • Sputtering process is dominant at current densities less than 50 A/m{sup 2} and evaporation can be neglected. • For current densities over 50 A/m{sup 2} the hysteresis width reaches its maximum and the role of evaporation increases.

Putting evaporators to work: wiped film evaporator for high level wastes

International Nuclear Information System (INIS)

Dierks, R.D.; Bonner, W.F.

1976-01-01

At Battelle, Pacific Northwest Laboratories, a pilot scale, wiped film evaporator was tested for concentrating high level liquid wastes from Purex-type nuclear fuel recovery processes. The concentrates produced up to 60 wt-percent total solids; and the simplicity of operation and design of the evaporator gave promise for low maintenance and high reliability

Active and reactive power control of a current-source PWM-rectifier using space vectors

Energy Technology Data Exchange (ETDEWEB)

Salo, M.; Tuusa, H. [Tampere University of Technology (Finland). Department of Electrical Engineering, Power Electronics

1997-12-31

In this paper the current-source PWM-rectifier with active and reactive power control is presented. The control system is realized using space vector methods. Also, compensation of the reactive power drawn by the line filter is discussed. Some simulation results are shown. (orig.) 8 refs.

Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing

Institute of Scientific and Technical Information of China (English)

SHAO; Min; FU; Linlin; LIU; Ying; LU; Sihua; ZHANG; Yuanhan

2005-01-01

Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing.

Evaporating firewalls

Science.gov (United States)

Van Raamsdonk, Mark

2014-11-01

In this note, we begin by presenting an argument suggesting that large AdS black holes dual to typical high-energy pure states of a single holographic CFT must have some structure at the horizon, i.e. a fuzzball/firewall, unless the procedure to probe physics behind the horizon is state-dependent. By weakly coupling the CFT to an auxiliary system, such a black hole can be made to evaporate. In a case where the auxiliary system is a second identical CFT, it is possible (for specific initial states) that the system evolves to precisely the thermofield double state as the original black hole evaporates. In this case, the dual geometry should include the "late-time" part of the eternal AdS black hole spacetime which includes smooth spacetime behind the horizon of the original black hole. Thus, if a firewall is present initially, it evaporates. This provides a specific realization of the recent ideas of Maldacena and Susskind that the existence of smooth spacetime behind the horizon of an evaporating black hole can be enabled by maximal entanglement with a Hawking radiation system (in our case the second CFT) rather than prevented by it. For initial states which are not finely-tuned to produce the thermofield double state, the question of whether a late-time infalling observer experiences a firewall translates to a question about the gravity dual of a typical high-energy state of a two-CFT system.

Evaporation under vacuum condition

International Nuclear Information System (INIS)

Mizuta, Satoshi; Shibata, Yuki; Yuki, Kazuhisa; Hashizume, Hidetoshi; Toda, Saburo; Takase, Kazuyuki; Akimoto, Hajime

2000-01-01

In nuclear fusion reactor design, an event of water coolant ingress into its vacuum vessel is now being considered as one of the most probable accidents. In this report, the evaporation under vacuum condition is evaluated by using the evaporation model we have developed. The results show that shock-wave by the evaporation occurs whose behavior strongly depends on the initial conditions of vacuum. And in the case of lower initial pressure and temperature, the surface temp finally becomes higher than other conditions. (author)

Evaporation of Lennard-Jones fluids.

Science.gov (United States)

Cheng, Shengfeng; Lechman, Jeremy B; Plimpton, Steven J; Grest, Gary S

2011-06-14

Evaporation and condensation at a liquid/vapor interface are ubiquitous interphase mass and energy transfer phenomena that are still not well understood. We have carried out large scale molecular dynamics simulations of Lennard-Jones (LJ) fluids composed of monomers, dimers, or trimers to investigate these processes with molecular detail. For LJ monomers in contact with a vacuum, the evaporation rate is found to be very high with significant evaporative cooling and an accompanying density gradient in the liquid domain near the liquid/vapor interface. Increasing the chain length to just dimers significantly reduces the evaporation rate. We confirm that mechanical equilibrium plays a key role in determining the evaporation rate and the density and temperature profiles across the liquid/vapor interface. The velocity distributions of evaporated molecules and the evaporation and condensation coefficients are measured and compared to the predictions of an existing model based on kinetic theory of gases. Our results indicate that for both monatomic and polyatomic molecules, the evaporation and condensation coefficients are equal when systems are not far from equilibrium and smaller than one, and decrease with increasing temperature. For the same reduced temperature T/T(c), where T(c) is the critical temperature, these two coefficients are higher for LJ dimers and trimers than for monomers, in contrast to the traditional viewpoint that they are close to unity for monatomic molecules and decrease for polyatomic molecules. Furthermore, data for the two coefficients collapse onto a master curve when plotted against a translational length ratio between the liquid and vapor phase.

Reactive oxygen species inhibit catalytic activity of peptidylarginine deiminase

DEFF Research Database (Denmark)

Damgaard, Dres; Bjørn, Mads Emil; Jensen, Peter Østrup

2017-01-01

on calcium and reducing conditions. However, reactive oxygen species (ROS) have been shown to induce citrullination of histones in granulocytes. Here we examine the ability of H2O2 and leukocyte-derived ROS to regulate PAD activity using citrullination of fibrinogen as read-out. H2O2 at concentrations above...... from stimulated leukocytes was unaffected by exogenously added H2O2 at concentrations up to 1000 µM. The role of ROS in regulating PAD activity may play an important part in preventing hypercitrullination of proteins....

Economic-environmental active and reactive power scheduling of modern distribution systems in presence of wind generations: A distribution market-based approach

International Nuclear Information System (INIS)

Samimi, Abouzar; Kazemi, Ahad; Siano, Pierluigi

2015-01-01

Highlights: • A new market-based approach is proposed to schedule active and reactive powers. • Multi-component reactive power bidding structures for DERs is introduced. • A new economical/environmental operational scheduling method is proposed. • At distribution level, a reactive power market is developed in presence of DERs. - Abstract: Distribution System Operator (DSO) is responsible for active and reactive power scheduling in a distribution system. DSO purchases its active and reactive power requirements from Distributed Energy Resources (DERs) as well as the wholesale electricity market. In this paper, a new economical/environmental operational scheduling method based on sequential day-ahead active and reactive power markets at distribution level is proposed to dispatch active and reactive powers in distribution systems with high penetration of DERs. In the proposed model, after day-ahead active power market was cleared the participants submit their reactive power bids and then the reactive power market will be settled. At distribution level, developing a Var market, in which DERs like synchronous machine-based Distributed Generation (DG) units and Wind Turbines (WTs) could offer their reactive power prices, DERs are motivated to actively participate in the Volt/VAr Control (VVC) problem. To achieve this purpose, based on the capability curves of considered DERs, innovative multi-component reactive power bidding structures for DERs are introduced. Moreover, the effect of reactive power market clearing on the active power scheduling is explicitly considered into the proposed model by rescheduling of active power by usage of energy-balance service bids. On the other hand, environmental concerns that arise from the operation of fossil fuel fired electric generators are included in the proposed model by employing CO_2 emission penalty cost. The suggested reactive power market is cleared through a mixed-integer nonlinear optimization program. The

Film flow analysis for a vertical evaporating tube with inner evaporation and outer condensation

International Nuclear Information System (INIS)

Park, Il Seouk

2008-01-01

A numerical study for the flow, heat and mass transfer characteristics of the evaporating tube with the films flowing down on both the inside and outside tube walls has been carried out. The condensation occurs along the outside wall while the evaporation occurs at the free surface of the inside film. The transport equations for momentum and energy are parabolized by the boundary-layer approximation and solved by using the marching technique. The calculation domain of 2 film flow regions (evaporating and condensation films at the inside and outside tube wall respectively) and tube wall is solved simultaneously. The coupling technique for the problem with the 3 different regions and the 2 interfaces of them has been developed to calculated the temperature field. The velocity and temperature fields and the amount of the condensed and evaporated mass as well as the position where the evaporating film is completely dried out are successfully predicted for various inside pressures and inside film inlet flow rates

Pentacene Active Channel Layers Prepared by Spin-Coating and Vacuum Evaporation Using Soluble Precursors for OFET Applications

OpenAIRE

Ochiai, Shizuyasu; Palanisamy, Kumar; Kannappan, Santhakumar; Shin, Paik-Kyun

2012-01-01

Pentacene OFETs of bottom-gate/bottom-contact were fabricated with three types of pentacene organic semiconductors and cross linked Poly(4-vinylphenol) or polycarbonate as gate dielectric layer. Two different processes were used to prepare the pentacene active channel layers: (1) spin-coating on dielectric layer using two different soluble pentacene precursors of SAP and DMP; (2) vacuum evaporation on PC insulator. X-ray diffraction studies revealed coexistence of thin film and bulk phase of ...

THE USE OF POROUS CERAMICS FOR EVAPORATIVE AND EVAPORATIVE – VAPOR –COMPRESSION SYSTEMS

Directory of Open Access Journals (Sweden)

Cheban D.N.

2013-04-01

Full Text Available The use of natural evaporative cooling is one of technical solutions of problem of energy efficiency in air conditioning systems. The use of evaporative cooling in the first combined cooling stage allows reducing the load on the condenser of the cooling machine due to reducing of the condensing temperature. This combination allows the use of this type of system in any climatic conditions, including regions with small water resources. Multi-porous ceramic structure is used in evaporative air coolers and water coolers in this case. The objective of this paper is to show advantages of the using of porous ceramic as a working attachment, and to show advantages of the proposed scheme of compression-evaporation systems in comparison with standard vapor compression systems. Experimental research proved the fact, that in the film mode cooling efficiency of air flow is between EA=0,6÷0,7 and is slightly dependent of water flow. For countries with hot and dry climate where reserves of water are limited, it is recommended to use cyclical regime with EA≈0,65 value, or to use channel regime with a value of EA≈0,55. This leads to considerable energy savings. It has been determined, that combined air conditioning system is completely closed on the consumption of water at the parameters of the outside air equal to tA =32ºC and XA>13g/kg (in system with direct evaporative cooling machine, and tA=32ºC and XA>12g/kg (in system with indirect evaporative cooling machine. With these parameters, the cost of water in evaporative cooling stage can be fully compensated by condensate from the evaporator chiller.

Evaluation of bituminized waste reactivity

International Nuclear Information System (INIS)

Camaro, S.; Moulinier, D.

2000-01-01

The bituminization process has been used for conditioning low and medium level (LML) radioactive waste, particularly to immobilize coprecipitation slurries and evaporation concentrates generated by effluent treatment. The process consists in mixing bitumen matrix with inactive soluble and slightly soluble salts added to insolubilize the radionuclides or resulting from the neutralization of acid effluents. This operation is performed at a sufficient temperature - depending on waste composition and bitumen grade to ensure the flow of the resulting mixture into metal containers. Exothermicity due to salts/salts or salts/bitumen reactions depending on the type of waste can be induced during or after the mixing step. This could produce an additional heat emission that the drum must be able to release to avoid a potentially incidental pattern with ignition risk, explaining why the CEA has been involved in evaluating the thermal reactivity of bituminized waste and its repercussions on the bituminization process. Given the difficulty of discriminating each exothermal reaction, the characterization of a global reactivity appears as a further precautionary measure, in addition to the definition of a working safety margin. The CEA has accordingly developed studies on this aspect. The article discusses the experimental methodology developed for the determination of the global reactivity. (authors)

DWPF Recycle Evaporator Simulant Tests

International Nuclear Information System (INIS)

Stone, M

2005-01-01

Testing was performed to determine the feasibility and processing characteristics of an evaporation process to reduce the volume of the recycle stream from the Defense Waste Processing Facility (DWPF). The concentrated recycle would be returned to DWPF while the overhead condensate would be transferred to the Effluent Treatment Plant. Various blends of evaporator feed were tested using simulants developed from characterization of actual recycle streams from DWPF and input from DWPF-Engineering. The simulated feed was evaporated in laboratory scale apparatus to target a 30X volume reduction. Condensate and concentrate samples from each run were analyzed and the process characteristics (foaming, scaling, etc) were visually monitored during each run. The following conclusions were made from the testing: Concentration of the ''typical'' recycle stream in DWPF by 30X was feasible. The addition of DWTT recycle streams to the typical recycle stream raises the solids content of the evaporator feed considerably and lowers the amount of concentration that can be achieved. Foaming was noted during all evaporation tests and must be addressed prior to operation of the full-scale evaporator. Tests were conducted that identified Dow Corning 2210 as an antifoam candidate that warrants further evaluation. The condensate has the potential to exceed the ETP WAC for mercury, silicon, and TOC. Controlling the amount of equipment decontamination recycle in the evaporator blend would help meet the TOC limits. The evaporator condensate will be saturated with mercury and elemental mercury will collect in the evaporator condensate collection vessel. No scaling on heating surfaces was noted during the tests, but splatter onto the walls of the evaporation vessels led to a buildup of solids. These solids were difficult to remove with 2M nitric acid. Precipitation of solids was not noted during the testing. Some of the aluminum present in the recycle streams was converted from gibbsite to

A Hybrid Estimator for Active/Reactive Power Control of Single-Phase Distributed Generation Systems with Energy Storage

DEFF Research Database (Denmark)

Pahlevani, Majid; Eren, Suzan; Guerrero, Josep M.

2016-01-01

This paper presents a new active/reactive power closed-loop control system for a hybrid renewable energy generation system used for single-phase residential/commercial applications. The proposed active/reactive control method includes a hybrid estimator, which is able to quickly and accurately es...

Evaporation-triggered microdroplet nucleation and the four life phases of an evaporating Ouzo drop

Science.gov (United States)

Tan, Huanshu; Diddens, Christian; Lv, Pengyu; Kuerten, J. G. M.; Zhang, Xuehua; Lohse, Detlef

2016-01-01

Evaporating liquid droplets are omnipresent in nature and technology, such as in inkjet printing, coating, deposition of materials, medical diagnostics, agriculture, the food industry, cosmetics, or spills of liquids. Whereas the evaporation of pure liquids, liquids with dispersed particles, or even liquid mixtures has intensively been studied over the past two decades, the evaporation of ternary mixtures of liquids with different volatilities and mutual solubilities has not yet been explored. Here we show that the evaporation of such ternary mixtures can trigger a phase transition and the nucleation of microdroplets of one of the components of the mixture. As a model system, we pick a sessile Ouzo droplet (as known from daily life—a transparent mixture of water, ethanol, and anise oil) and reveal and theoretically explain its four life phases: In phase I, the spherical cap-shaped droplet remains transparent while the more volatile ethanol is evaporating, preferentially at the rim of the drop because of the singularity there. This leads to a local ethanol concentration reduction and correspondingly to oil droplet nucleation there. This is the beginning of phase II, in which oil microdroplets quickly nucleate in the whole drop, leading to its milky color that typifies the so-called “Ouzo effect.” Once all ethanol has evaporated, the drop, which now has a characteristic nonspherical cap shape, has become clear again, with a water drop sitting on an oil ring (phase III), finalizing the phase inversion. Finally, in phase IV, all water has evaporated, leaving behind a tiny spherical cap-shaped oil drop. PMID:27418601

Performance investigation of advanced adsorption desalination cycle with condenser-evaporator heat recovery scheme

KAUST Repository

Thu, Kyaw

2013-01-01

Energy or heat recovery schemes are keys for the performance improvement of any heat-activated cycles such as the absorption and adsorption cycles. We present two innovative heat recovery schemes between the condensing and evaporating units of an adsorption desalination (AD) cycle. By recovering the latent heat of condenser and dumping it into the evaporative process of the evaporator, it elevates the evaporating temperature and hence the adsorption pressure seen by the adsorbent. From isotherms, this has an effect of increasing the vapour uptake. In the proposed configurations, one approach is simply to have a run-about water circuit between the condenser and the evaporator and a pump is used to achieve the water circulation. This run-around circuit is a practical method for retrofitting purposes. The second method is targeted towards a new AD cycle where an encapsulated condenser-evaporator unit is employed. The heat transfer between the condensing and evaporative vapour is almost immediate and the processes occur in a fully integrated vessel, thereby minimizing the heat transfer resistances of heat exchangers. © 2013 Desalination Publications.

242-A evaporator safety analysis report

International Nuclear Information System (INIS)

CAMPBELL, T.A.

1999-01-01

This report provides a revised safety analysis for the upgraded 242-A Evaporator (the Evaporator). This safety analysis report (SAR) supports the operation of the Evaporator following life extension upgrades and other facility and operations upgrades (e.g., Project B-534) that were undertaken to enhance the capabilities of the Evaporator. The Evaporator has been classified as a moderate-hazard facility (Johnson 1990). The information contained in this SAR is based on information provided by 242-A Evaporator Operations, Westinghouse Hanford Company, site maintenance and operations contractor from June 1987 to October 1996, and the existing operating contractor, Waste Management Hanford (WMH) policies. Where appropriate, a discussion address the US Department of Energy (DOE) Orders applicable to a topic is provided. Operation of the facility will be compared to the operating contractor procedures using appropriate audits and appraisals. The following subsections provide introductory and background information, including a general description of the Evaporator facility and process, a description of the scope of this SAR revision,a nd a description of the basic changes made to the original SAR

242-A evaporator safety analysis report

Energy Technology Data Exchange (ETDEWEB)

CAMPBELL, T.A.

1999-05-17

This report provides a revised safety analysis for the upgraded 242-A Evaporator (the Evaporator). This safety analysis report (SAR) supports the operation of the Evaporator following life extension upgrades and other facility and operations upgrades (e.g., Project B-534) that were undertaken to enhance the capabilities of the Evaporator. The Evaporator has been classified as a moderate-hazard facility (Johnson 1990). The information contained in this SAR is based on information provided by 242-A Evaporator Operations, Westinghouse Hanford Company, site maintenance and operations contractor from June 1987 to October 1996, and the existing operating contractor, Waste Management Hanford (WMH) policies. Where appropriate, a discussion address the US Department of Energy (DOE) Orders applicable to a topic is provided. Operation of the facility will be compared to the operating contractor procedures using appropriate audits and appraisals. The following subsections provide introductory and background information, including a general description of the Evaporator facility and process, a description of the scope of this SAR revision,a nd a description of the basic changes made to the original SAR.

EFFECT OF REACTIVE MAGNESIUM OXIDE ON PROPERTIES OF ALKALI ACTIVATED SLAG GEOPOLYMER CEMENT PASTES

Directory of Open Access Journals (Sweden)

H. A. Abdel-Gawwad

2015-03-01

Full Text Available The effect of different proportions and different reactivities of MgO on the drying shrinkage and compressive strength of alkali activated slag pastes (AAS has been investigated. The slag was activated by 6 wt.% sodium hydroxide and liquid sodium silicate at ratio of 3:3 (wt.. The different reactivities of MgOs were produced from the calcination of hydromagnesite at different temperatures (550, 1000, 1250 C. The results showed that the reactivity of magnesium oxide decreases with increasing the calcination temperature. Also, the drying shrinkage of AAS was reduced by the replacement of slag with MgOs. The highly reactive MgO accelerated the hydration of AAS at early ages. The replacement of slag with 5% MgO550 increased one day compressive strength by ~26 % while MgO1250 had little effect. A significant increase in strength was observed after 7 days in case of replacement of slag with 5 % MgO1250. The MgO reacts with slag to form hydrotalcite likephases (Ht as detected by XRD, FTIR spectroscopy, TGA/DTG analysis and SEM.

Environmental Projects. Volume 8: Modifications of wastewater evaporation ponds

Science.gov (United States)

1989-01-01

The Goldstone Deep Space Communications Complex (GDSCC), located in the Mojave Desert about 45 miles north of Barstow, California, and about 160 miles northeast of Pasadena, is part of NASA's Deep Space Network, one of the world's largest and most sensitive scientific telecommunications and radio navigation networks. The Goldstone Complex is managed, technically directed, and operated for NASA by the Jet Propulsion Laboratory (JPL) of the California Institute of Technology in Pasadena, California. Activities at the GDSCC are carried out in support of seven parabolic dish antennas. These activities may give rise to environmental hazards: use of hazardous chemicals, asbestos, and underground storage tanks as well as the generation of hazardous wastes and the disposal of wastewater. Federal, state, and local laws governing the management of hazardous substances, asbestos, underground storage tanks and wastewater disposal have become so complex there is a need to devise specific programs to comply with the many regulations that implement these laws. In support of the national goal of the preservation of the environment and the protection of human health and safety, NASA, JPL, and the GDSCC have adopted a position that their operating installations shall maintain a high level of compliance with these laws. One of the environmental problems at the GDSCC involved four active, operational, wastewater evaporation ponds designed to receive and evaporate sewage effluent from upstream septic tank systems. One pair of active wastewater evaporation ponds is located at Echo Site, while another operational pair is at Mars Site.

Playa Soil Moisture and Evaporation Dynamics During the MATERHORN Field Program

Science.gov (United States)

Hang, Chaoxun; Nadeau, Daniel F.; Jensen, Derek D.; Hoch, Sebastian W.; Pardyjak, Eric R.

2016-06-01

We present an analysis of field data collected over a desert playa in western Utah, USA in May 2013, the most synoptically active month of the year, as part of the Mountain Terrain Atmospheric Modeling and Observations (MATERHORN) program. The results show that decreasing surface albedo, decreasing Bowen ratio and increasing net radiation with increasing soil moisture sustained a powerful positive feedback mechanism promoting large evaporation rates immediately following rain events. Additionally, it was found that, while nocturnal evaporation was negligible during dry periods, it was quite significant (up to 30 % of the daily cumulative flux) during nights following rain events. Our results further show that the highest spatial variability in surface soil moisture is found under dry conditions. Finally, we report strong spatial heterogeneities in evaporation rates following a rain event. The cumulative evaporation for the different sampling sites over a five-day period varied from ≈ 0.1 to ≈ 6.6 mm. Overall, this study allows us to better understand the mechanisms underlying soil moisture dynamics of desert playas as well as evaporation following occasional rain events.

Observation and Modeling of Chromospheric Evaporation in a Coronal Loop Related to Active Region Transient Brightening

Science.gov (United States)

Gupta, G. R.; Sarkar, Aveek; Tripathi, Durgesh

2018-04-01

Using the observations recorded by the Atmospheric Imaging Assembly (AIA) on board the Solar Dynamics Observatory and the Interface Region Imaging Spectrograph (IRIS) and the Extreme-ultraviolet Imaging Spectrometer and X-Ray Telescope both on board Hinode, we present evidence of chromospheric evaporation in a coronal loop after the occurrence of two active region transient brightenings (ARTBs) at the two footpoints. The chromospheric evaporation started nearly simultaneously in all of the three hot channels of AIA 131, 94, and 335 Å and was observed to be temperature dependent, being fastest in the highest temperature channel. The whole loop became fully brightened following the ARTBs after ≈25 s in 131 Å, ≈40 s in 94 Å, and ≈6.5 minutes in 335 Å. The differential emission measurements at the two footpoints (i.e., of two ARTBs) and at the loop top suggest that the plasma attained a maximum temperature of ∼10 MK at all these locations. The spectroscopic observations from IRIS revealed the presence of redshifted emission of ∼20 km s‑1 in cooler lines like C II and Si IV during the ARTBs that was cotemporal with the evaporation flow at the footpoint of the loop. During the ARTBs, the line width of C II and Si IV increased nearly by a factor of two during the peak emission. Moreover, enhancement in the line width preceded that in the Doppler shift, which again preceded enhancement in the intensity. The observed results were qualitatively reproduced by 1D hydrodynamic simulations, where energy was deposited at both of the footpoints of a monolithic coronal loop that mimicked the ARTBs identified in the observations.

Titanium carbide coatings on molybdenum by means of reactive sputtering and electron beam techniques

International Nuclear Information System (INIS)

Obata, T.; Aida, H.; Hirohata, Y.; Mohri, M.; Yamashina, T.

1982-01-01

This study is an experimental investigation of TiC coatings on Mo substrate by means of a reactive r.f. sputtering in the presence of CH 4 and a chemical reaction with interdiffusion in the sandwich structure of Ti/C/Mo by electron beam evaporation and heating. Using the reactive sputtering method, a homogeneous TiC coating with stoichiometric composition and good adhesion could be produced in the conditions of the partial pressure range of CH 4 , 2 approx. equal to 5 x 10 -4 Torr (total pressure, Psub(Ar) + Psub(CH) 4 = 5.6 x 10 -2 Torr) at 300 0 C (substrate). By using the electron beams, successively evaporated carbon and Ti on a Mo substrate was heated to 700 0 C to form a TiC surface layer on the top which then remained stable during further heating to 1000 0 C. Godd adhesion was brought about by interdiffusion to produce Mo 2 C layer between TiC layer and Mo substrate. It was also found that further heating of the coating layers subsequent to Ti evaporation on the TiC layer produced thicker TiC layer due to a chemical reaction between Ti and inner carbon layers. This could be a promising method of in situ replenishment for TiC coatings on the first wall and the limiter materials. (orig.)

Preparation of Candesartan and Atorvastatin Nanoparticles by Solvent Evaporation

Directory of Open Access Journals (Sweden)

Josef Jampilek

2012-11-01

Full Text Available The solubility, absorption and distribution of a drug are involved in the basic aspects of oral bioavailability Solubility is an essential characteristic and influences the efficiency of the drug. Over the last ten years, the number of poorly soluble drugs has steadily increased. One of the progressive ways for increasing oral bioavaibility is the technique of nanoparticle preparation, which allows many drugs to thus reach the intended site of action. Candesartan cilexetil and atorvastatin, belonging to class II of the biopharmaceutical classification system, were chosen as model active pharmaceutical ingredients in this study. Forty samples were prepared either by antisolvent precipitation/solvent evaporation method or by the emulsion/solvent evaporation technique with various commonly used surface-active excipients as nanoparticle stabilizers. All samples were analyzed by means of dynamic light scattering. The particle size of the determined 36 nanoparticle samples was to 574 nm, whereas 32 samples contained nanoparticles of less than 200 nm. Relationships between solvents and excipients used and their amount are discussed. Based on the results the investigated solvent evaporation methods can be used as an effective and an affordable technique for the preparation of nanoparticles.

Preliminary Results of Testing of Flow Effects on Evaporator Scaling

Energy Technology Data Exchange (ETDEWEB)

Hu, M.Z.

2002-02-15

This investigation has focused on the effects of fluid flow on solids deposition from solutions that simulate the feed to the 2H evaporator at the Savannah River Site. Literature studies indicate that the fluid flow (or shear) affects particle-particle and particle-surface interactions and thus the phenomena of particle aggregation in solution and particle deposition (i.e., scale formation) onto solid surfaces. Experimental tests were conducted with two configurations: (1) using a rheometer to provide controlled shear conditions and (2) using controlled flow of reactive solution through samples of stainless steel tubing. All tests were conducted at 80 C and at high silicon and aluminum concentrations, 0.133 M each, in solutions containing 4 M sodium hydroxide and 1 A4 each of sodium nitrate and sodium nitrite. Two findings from these experiments are important for consideration in developing approaches for reducing or eliminating evaporator scaling problems: (1) The rheometer tests suggested that for the conditions studied, maximum solids deposition occurs at a moderate shear rate, approximately 12 s{sup -1}. That value is expected to be on the order of shear rates that will occur in various parts of the evaporator system; for instance, a 6 gal/min single-phase liquid flow through the 2-in. lift or gravity drain lines would result in a shear rate of approximately 16 s{sup -1}. These results imply that engineering approaches aimed at reducing deposits through increased mixing would need to generate shear near all surfaces significantly greater than 12 s{sup -1}. However, further testing is needed to set a target value for shear that is applicable to evaporator operation. This is because the measured trend is not statistically significant at the 95% confidence interval due to variability in the results. In addition, testing at higher temperatures and lower concentrations of aluminum and silicon would more accurately represent conditions in the evaporator. Without

Restart oversight assessment of Hanford 242-A evaporator: Technical report

International Nuclear Information System (INIS)

Lagdon, R.; Lasky, R.

1994-08-01

An assessment team from the Office of Environment, Safety and Health (EH), US Department of Energy (DOE), conducted an independent assessment of the 242-A Evaporator at the Hanford Site during January 17--28, 1994. An EH team member remained on-site following the assessment to track corrective actions and resolve prestart findings. The primary objective of this assessment was independent assurance that the DOE Office of Environmental Management (EM), the DOE Richland Operations Office (DOE-RL), and Westinghouse Hanford Company (WHC) can safely restart the evaporator. Another objective of the EH team was to assess EM's Operational Readiness Evaluation (ORE) to determine if the programs, procedures, and management systems implemented for operation of the 241-A Evaporator ensure the protection of worker safety and health. The following section of this report provides background information on the 242-A Evaporator and Operational Readiness Review (ORR) activities conducted to date. The next chapter is divided into sections that address the results of discrete assessment activities. Each section includes a brief statement of conclusions for the functional area in question, descriptions of the review bases and methods, and a detailed discussion of the results. Concerns identified during the assessment are listed for the section to which they apply, and the specific findings upon which the concern is based can be found immediately thereafter

Evaporation Kinetics of Polyol Droplets: Determination of Evaporation Coefficients and Diffusion Constants

Science.gov (United States)

Su, Yong-Yang; Marsh, Aleksandra; Haddrell, Allen E.; Li, Zhi-Ming; Reid, Jonathan P.

2017-11-01

In order to quantify the kinetics of mass transfer between the gas and condensed phases in aerosol, physicochemical properties of the gas and condensed phases and kinetic parameters (mass/thermal accommodation coefficients) are crucial for estimating mass fluxes over a wide size range from the free molecule to continuum regimes. In this study, we report measurements of the evaporation kinetics of droplets of 1-butanol, ethylene glycol (EG), diethylene glycol (DEG), and glycerol under well-controlled conditions (gas flow rates and temperature) using the previously developed cylindrical electrode electrodynamic balance technique. Measurements are compared with a model that captures the heat and mass transfer occurring at the evaporating droplet surface. The aim of these measurements is to clarify the discrepancy in the reported values of mass accommodation coefficient (αM, equals to evaporation coefficient based on microscopic reversibility) for 1-butanol, EG, and DEG and improve the accuracy of the value of the diffusion coefficient for glycerol in gaseous nitrogen. The uncertainties in the thermophysical and experimental parameters are carefully assessed, the literature values of the vapor pressures of these components are evaluated, and the plausible ranges of the evaporation coefficients for 1-butanol, EG, and DEG as well as uncertainty in diffusion coefficient for glycerol are reported. Results show that αM should be greater than 0.4, 0.2, and 0.4 for EG, DEG, and 1-butanol, respectively. The refined values are helpful for accurate prediction of the evaporation/condensation rates.

Reactive oxygen species and associated reactivity of peroxymonosulfate activated by soluble iron species

Science.gov (United States)

Watts, Richard J.; Yu, Miao; Teel, Amy L.

2017-10-01

The activation of peroxymonosulfate by iron (II), iron (III), and iron (III)-EDTA for in situ chemical oxidation (ISCO) was compared using nitrobenzene as a hydroxyl radical probe, anisole as a hydroxyl radical + sulfate radical probe, and hexachloroethane as a reductant + nucleophile probe. In addition, activated peroxymonosulfate was investigated for the treatment of the model groundwater contaminants perchloroethylene (PCE) and trichloroethylene (TCE). The relative activities of hydroxyl radical and sulfate radical in the degradation of the probe compounds and PCE and TCE were isolated using the radical scavengers tert-butanol and isopropanol. Iron (II), iron (III), and iron (III)-EDTA effectively activated peroxymonosulfate to generate hydroxyl radical and sulfate radical, but only a minimal flux of reductants or nucleophiles. Iron (III)-EDTA was a more effective activator than iron (II) and iron (III), and also provided a non-hydroxyl radical, non-sulfate radical degradation pathway. The contribution of sulfate radical relative to hydroxyl radical followed the order of anisole > > TCE > PCE > > nitrobenzene; i.e., sulfate radical was less dominant in the oxidation of more oxidized target compounds. Sulfate radical is often assumed to be the primary oxidant in activated peroxymonosulfate and persulfate systems, but the results of this research demonstrate that the reactivity of sulfate radical with the target compound must be considered before drawing such a conclusion.

Reactive oxygen species and associated reactivity of peroxymonosulfate activated by soluble iron species.

Science.gov (United States)

Watts, Richard J; Yu, Miao; Teel, Amy L

2017-10-01

The activation of peroxymonosulfate by iron (II), iron (III), and iron (III)-EDTA for in situ chemical oxidation (ISCO) was compared using nitrobenzene as a hydroxyl radical probe, anisole as a hydroxyl radical+sulfate radical probe, and hexachloroethane as a reductant+nucleophile probe. In addition, activated peroxymonosulfate was investigated for the treatment of the model groundwater contaminants perchloroethylene (PCE) and trichloroethylene (TCE). The relative activities of hydroxyl radical and sulfate radical in the degradation of the probe compounds and PCE and TCE were isolated using the radical scavengers tert-butanol and isopropanol. Iron (II), iron (III), and iron (III)-EDTA effectively activated peroxymonosulfate to generate hydroxyl radical and sulfate radical, but only a minimal flux of reductants or nucleophiles. Iron (III)-EDTA was a more effective activator than iron (II) and iron (III), and also provided a non-hydroxyl radical, non-sulfate radical degradation pathway. The contribution of sulfate radical relative to hydroxyl radical followed the order of anisole>TCE>PCE >nitrobenzene; i.e., sulfate radical was less dominant in the oxidation of more oxidized target compounds. Sulfate radical is often assumed to be the primary oxidant in activated peroxymonosulfate and persulfate systems, but the results of this research demonstrate that the reactivity of sulfate radical with the target compound must be considered before drawing such a conclusion. Published by Elsevier B.V.

Lake Nasser evaporation reduction study

Directory of Open Access Journals (Sweden)

Hala M.I. Ebaid

2010-10-01

Full Text Available This study aims to evaluate the reduction of evaporation of Lake Nasser’s water caused by disconnecting (fully or partially some of its secondary channels (khors. This evaluation integrates remote sensing, Geographic Information System (GIS techniques, aerodynamic principles, and Landsat7 ETM+ images. Three main procedures were carried out in this study; the first derived the surface temperature from Landsat thermal band; the second derived evaporation depth and approximate evaporation volume for the entire lake, and quantified evaporation loss to the secondary channels’ level over one month (March by applied aerodynamic principles on surface temperature of the raster data; the third procedure applied GIS suitability analysis to determine which of these secondary channels (khors should be disconnected. The results showed evaporation depth ranging from 2.73 mm/day at the middle of the lake to 9.58 mm/day at the edge. The evaporated water-loss value throughout the entire lake was about 0.86 billion m3/month (March. The analysis suggests that it is possible to save an approximate total evaporation volume loss of 19.7 million m3/month (March, and thus 2.4 billion m3/year, by disconnecting two khors with approximate construction heights of 8 m and 15 m. In conclusion, remote sensing and GIS are useful for applications in remote locations where field-based information is not readily available and thus recommended for decision makers remotely planning in water conservation and management.

PTSD Psychotherapy Outcome Predicted by Brain Activation During Emotional Reactivity and Regulation.

Science.gov (United States)

Fonzo, Gregory A; Goodkind, Madeleine S; Oathes, Desmond J; Zaiko, Yevgeniya V; Harvey, Meredith; Peng, Kathy K; Weiss, M Elizabeth; Thompson, Allison L; Zack, Sanno E; Lindley, Steven E; Arnow, Bruce A; Jo, Booil; Gross, James J; Rothbaum, Barbara O; Etkin, Amit

2017-12-01

Exposure therapy is an effective treatment for posttraumatic stress disorder (PTSD), but many patients do not respond. Brain functions governing treatment outcome are not well characterized. The authors examined brain systems relevant to emotional reactivity and regulation, constructs that are thought to be central to PTSD and exposure therapy effects, to identify the functional traits of individuals most likely to benefit from treatment. Individuals with PTSD underwent functional MRI (fMRI) while completing three tasks assessing emotional reactivity and regulation. Participants were then randomly assigned to immediate prolonged exposure treatment (N=36) or a waiting list condition (N=30). A random subset of the prolonged exposure group (N=17) underwent single-pulse transcranial magnetic stimulation (TMS) concurrent with fMRI to examine whether predictive activation patterns reflect causal influence within circuits. Linear mixed-effects modeling in line with the intent-to-treat principle was used to examine how baseline brain function moderated the effect of treatment on PTSD symptoms. At baseline, individuals with larger treatment-related symptom reductions (compared with the waiting list condition) demonstrated 1) greater dorsal prefrontal activation and 2) less left amygdala activation, both during emotion reactivity; 3) better inhibition of the left amygdala induced by single TMS pulses to the right dorsolateral prefrontal cortex; and 4) greater ventromedial prefrontal/ventral striatal activation during emotional conflict regulation. Reappraisal-related activation was not a significant moderator of the treatment effect. Capacity to benefit from prolonged exposure in PTSD is gated by the degree to which prefrontal resources are spontaneously engaged when superficially processing threat and adaptively mitigating emotional interference, but not when deliberately reducing negative emotionality.

Enhancing radiolytic stability upon concentration of tritium-labeled pharmaceuticals utilizing centrifugal evaporation.

Science.gov (United States)

Marques, Rosemary; Helmy, Roy; Waterhouse, David

2015-05-30

Tritium radiopharmaceuticals are often used in drug development because of their desirable specific activity. The inherent instability of these radioactive tracers often leads to a requirement to purify prior to use. Purification methodologies such as preparative chromatography and solid/liquid extractions often utilize water as a solvent, which is not suitable for long-term storage and necessitates removal. Rotary evaporation has traditionally been utilized for the removal of this unwanted solvent, however, this method has been shown to lead to decomposition of the tritium species in some cases. Centrifugal evaporation is a milder concentration method which has been demonstrated to effectively remove solvents. In this study, we show that centrifugal evaporation leads to effective concentration of tritium samples without the decomposition typically observed by rotary evaporation. Copyright © 2015 John Wiley & Sons, Ltd.

Transforming the Organic Chemistry Lab Experience: Design, Implementation, and Evaluation of Reformed Experimental Activities--REActivities

Science.gov (United States)

Collison, Christina G.; Kim, Thomas; Cody, Jeremy; Anderson, Jason; Edelbach, Brian; Marmor, William; Kipsang, Rodgers; Ayotte, Charles; Saviola, Daniel; Niziol, Justin

2018-01-01

Reformed experimental activities (REActivities) are an innovative approach to the delivery of the traditional material in an undergraduate organic chemistry laboratory. A description of the design and implementation of REActivities at both a four- and two-year institution is discussed. The results obtained using a reformed teaching observational…

242-A evaporator quality assurance project plan: Revision 1

International Nuclear Information System (INIS)

Tucker, B.J.

1994-01-01

The scope of this quality assurance project plan (Plan) is sampling and analytical services including, but not limited to, sample receipt, handling and storage, analytical measurements, submittal of data deliverables, archiving selected portions of samples, returning unneeded sample material to Westinghouse Hanford Company (WHC), and/or sample disposal associated with candidate feed samples and process condensate compliance samples. Sampling and shipping activities are also included within the scope. The purpose of this project is to provide planning, implementation, and assessment guidance for achieving established data quality objectives measurement parameters. This Plan requires onsite and offsite laboratories to conform to that guidance. Laboratory conformance will help ensure that quality data are being generated and therefore, that the 242-A evaporator is operating in a safe and compliant manner. The 242-A evaporator feed stream originates from double-shell tanks (DSTs) identified as candidate feed tanks. The 242-A evaporator reduces the volume of aqueous waste contained in DSTs by boiling off water and sending it to the Liquid Effluent Retention Facility (LERF) storage basin before further treatment. The slurry product is returned to DSTs. Evaporation results in considerable savings by reducing the volume of mixed waste for disposal

Activation of glucocorticoid receptors in Müller glia is protective to retinal neurons and suppresses microglial reactivity.

Science.gov (United States)

Gallina, Donika; Zelinka, Christopher Paul; Cebulla, Colleen M; Fischer, Andy J

2015-11-01

Reactive microglia and macrophages are prevalent in damaged retinas. Glucocorticoid signaling is known to suppress inflammation and the reactivity of microglia and macrophages. In the vertebrate retina, the glucocorticoid receptor (GCR) is known to be activated and localized to the nuclei of Müller glia (Gallina et al., 2014). Accordingly, we investigated how signaling through GCR influences the survival of neurons using the chick retina in vivo as a model system. We applied intraocular injections of GCR agonist or antagonist, assessed microglial reactivity, and the survival of retinal neurons following different damage paradigms. Microglial reactivity was increased in retinas from eyes that were injected with vehicle, and this reactivity was decreased by GCR-agonist dexamethasone (Dex) and increased by GCR-antagonist RU486. We found that activation of GCR suppresses the reactivity of microglia and inhibited the loss of retinal neurons resulting from excitotoxicity. We provide evidence that the protection-promoting effects of Dex were maintained when the microglia were selectively ablated. Similarly, intraocular injections of Dex protected ganglion cells from colchicine-treatment and protected photoreceptors from damage caused by retinal detachment. We conclude that activation of GCR promotes the survival of ganglion cells in colchicine-damaged retinas, promotes the survival of amacrine and bipolar cells in excitotoxin-damaged retinas, and promotes the survival of photoreceptors in detached retinas. We propose that suppression of microglial reactivity is secondary to activation of GCR in Müller glia, and this mode of signaling is an effective means to lessen the damage and vision loss resulting from different types of retinal damage. Copyright © 2015 Elsevier Inc. All rights reserved.

The evaporative vector: Homogeneous systems

International Nuclear Information System (INIS)

Klots, C.E.

1987-05-01

Molecular beams of van der Waals molecules are the subject of much current research. Among the methods used to form these beams, three-sputtering, laser ablation, and the sonic nozzle expansion of neat gases - yield what are now recognized to be ''warm clusters.'' They contain enough internal energy to undergo a number of first-order processes, in particular that of evaporation. Because of this evaporation and its attendant cooling, the properties of such clusters are time-dependent. The states of matter which can be arrived at via an evaporative vector on a typical laboratory time-scale are discussed. Topics include the (1) temperatures, (2) metastability, (3) phase transitions, (4) kinetic energies of fragmentation, and (5) the expression of magical properties, all for evaporating homogeneous clusters

Extension of a reactive distillation process design methodology: application to the hydrogen production through the Iodine-Sulfur thermochemical cycle; Generalisation d'une approche de conception de procedes de distillation reactive: application a la production d'hydrogene par le cycle thermochimique I-S

Energy Technology Data Exchange (ETDEWEB)

Belaissaoui, B

2006-02-15

Reactive distillation is a promising way to improve classical processes. This interest has been comforted by numerous successful applications involving reactive systems in liquid phase but never in vapour phase. In this context, general design tools have been developed for the analysis of reactive distillation processes whatever the reactive phase. A general model for open condensation and evaporation of vapour or liquid reactive systems in chemical equilibrium has been written and applied to extend the feasibility analysis, synthesis and design methods of the sequential design methodology of R. Thery (2002). The extended design methodology is applied to the industrial production of hydrogen through the iodine-sulphur thermochemical cycle by vapour phase reactive distillation. A column configuration is proposed with better performance formerly published configuration. (author)

Physical organogels: mechanism and kinetics of evaporation of the solvents entrapped within network scaffolding

International Nuclear Information System (INIS)

Markovic, Nov; Dutta, Naba K.

2005-01-01

A series of hydrocarbon gels (based on leaded petrol and decalin) using physically crosslinked networks have been prepared using Al-salt of fatty acid as the physical gelling agent. The effects of gel network scaffolding on the mechanism and kinetics of evaporation of the solvents from the gels were investigated using conventional, isothermal and modulated thermogravimetric analysis. It has been clearly observed that the evaporation of solvent from gels followed a complex evaporation pattern compared to the pure solvent. It appears that with increase in network scaffolding the maximum rate of evaporation of the solvent decreases and its distribution become broader. The activation energy of evaporation for these solvents was found not to be dramatically dependent on the concentration of the gelator and tightness of the network scaffolding. Amongst different methods employed, isothermal measurements provided reliable information about the mechanism of evaporation. Modulated thermogravimetric analysis proved to be an efficient method to achieve kinetic parameters of evaporation from a single dynamic experiment. Scanning electron microscopy was used to probe for both dry gelator and gel network after evaporation of the solvents for evaluation of their surface morphology

Measurements of the evaporation rate upon evaporation of thin layer at different heating modes

OpenAIRE

Gatapova E.Ya.; Korbanova E.G.

2017-01-01

Technique for measurements of the evaporation rate of a heated liquid layer is presented. The local minimum is observed which is associated with the point of equilibrium of the liquid–gas interface. It is shown when no heat is applied to the heating element temperature in gas phase is larger than in liquid, and evaporation occurs with the rate of 0.014–0.018 μl/s. Then evaporation rate is decreasing with increasing the heater temperature until the equilibrium point is reached at the liquid–ga...

Enhancing Water Evaporation with Floating Synthetic Leaves

Science.gov (United States)

Boreyko, Jonathan; Vieitez, Joshua; Berrier, Austin; Roseveare, Matthew; Shi, Weiwei

2017-11-01

When a wetted nanoporous medium is exposed to a subsaturated ambient environment, the water menisci assume a concave curvature to achieve a negative pressure. This negative water pressure is required to balance the mismatch in water activity across the water-air interface to achieve local equilibrium. Here, we show that the diffusive evaporation rate of water can be greatly modulated by floating a nanoporous synthetic leaf at the water's free interface. For high ambient humidities, adding the leaf serves to enhance the evaporation rate, presumably by virtue of the menisci enhancing the effective liquid-vapor surface area. For low humidities, the menisci cannot achieve a local equilibrium and retreat partway into the leaf, which increases the local humidity directly above the menisci. In light of these two effects, we find the surprising result that leaves exposed to an ambient humidity of 90 percent can evaporate water at the same rate as leaves exposed to only 50 percent humidity. These findings have implications for using synthetic trees to enhance steam generation or water harvesting. This work was supported by the National Science Foundation (CBET-1653631).

Agent-based Simulation of Reactive, Pro-active, and Social Animal Behaviour

NARCIS (Netherlands)

Jonker, C.M.; Treur, J.; Mira, J.

1998-01-01

In this paper it is shown how animal behaviour can be simulated in an agent-based manner. Different models are shown for different types of behaviour, varying from purely reactive behaviour to pro-active and social behaviour. The compositional development method for multi-agent systems DESIRE and

Ensemble statistics of active and reactive sound intensity in reverberation rooms

DEFF Research Database (Denmark)

Jacobsen, Finn; Molares, Alfonso Rodrıguez

2011-01-01

This paper examines fundamental statistical properties of the active and reactive sound intensity in reverberant enclosures driven with pure tones. The existing theory for sound intensity in a diffuse sound field, which is based on Waterhouse’s random wave model and therefore limited to the region...

Evaporation-triggered microdroplet nucleation and the four life phases of an evaporating Ouzo droplet

NARCIS (Netherlands)

Tan, H.; Diddens, C.; Lv, P.; Kuerten, J.G.M.; Zhang, X.; Lohse, D.

2016-01-01

Evaporating liquid droplets are omnipresent in nature and technology, such as in inkjet printing, coating, deposition of materials, medical diagnostics, agriculture, the food industry, cosmetics, or spills of liquids. Whereas the evaporation of pure liquids, liquids with dispersed particles, or even

Evaporation-triggered microdroplet nucleation and the four life phases of an evaporating Ouzo drop

NARCIS (Netherlands)

Tan, Huanshu; Diddens, Christian; Lv, Pengyu; Kuerten, J.G.M.; Zhang, Xuehua; Lohse, Detlef

2016-01-01

Evaporating liquid droplets are omnipresent in nature and technology, such as in inkjet printing, coating, deposition of materials, medical diagnostics, agriculture, the food industry, cosmetics, or spills of liquids. Whereas the evaporation of pure liquids, liquids with dispersed particles, or even

Plasma-assisted co-evaporation of {beta}-indium sulfide thin films

Energy Technology Data Exchange (ETDEWEB)

Kosaraju, Sreenivas; Marino, Joseph A.; Harvey, John A.; Wolden, Colin A. [Department of Chemical Engineering, Colorado School of Mines, Golden, CO 80401 (United States)

2006-05-05

This paper describes the development of plasma-assisted co-evaporation (PACE) for the formation of {beta}-In{sub 2}S{sub 3} thin films. Indium was supplied by conventional thermal evaporation, while the chalcogen gas precursor (H{sub 2}S) was activated using an inductively coupled plasma (ICP) source. Using a combination of optical emission spectroscopy and mass spectrometry it was shown that the ICP effectively dissociated H{sub 2}S, producing atomic sulfur. Transport modeling was used to quantify the flux distributions of the co-evaporated metal and the plasma-generated species impinging the substrate. Model predictions were validated by measurements of deposition rate and film properties. Substantial improvements in both materials utilization and substrate temperature reduction were realized with respect to conventional co-evaporation. {beta}-In{sub 2}S{sub 3} was formed as low as 100{sup o}C and it was observed that quality was a strong function of S/In ratio. The grain size decreased and the optical band gap increased as the substrate temperature was reduced. (author)

Drop evaporation and triple line dynamics

Science.gov (United States)

Sobac, Benjamin; Brutin, David; Gavillet, Jerome; Université de Provence Team; Cea Liten Team

2011-03-01

Sessile drop evaporation is a phenomenon commonly came across in nature or in industry with cooling, paintings or DNA mapping. However, the evaporation of a drop deposited on a substrate is not completely understood due to the complexity of the problem. Here we investigate, with several nano-coating of the substrate (PTFE, SiOx, SiOc and CF), the influence of the dynamic of the triple line on the evaporation process. The experiment consists in analyzing simultaneously the motion of the triple line, the kinetics of evaporation, the internal thermal motion and the heat and mass transfer. Measurements of temperature, heat-flux and visualizations with visible and infrared cameras are performed. The dynamics of the evaporative heat flux appears clearly different depending of the motion of the triple line

Trends in evaporation of a large subtropical lake

Science.gov (United States)

Hu, Cheng; Wang, Yongwei; Wang, Wei; Liu, Shoudong; Piao, Meihua; Xiao, Wei; Lee, Xuhui

2017-07-01

How rising temperature and changing solar radiation affect evaporation of natural water bodies remains poor understood. In this study, evaporation from Lake Taihu, a large (area 2400 km2) freshwater lake in the Yangtze River Delta, China, was simulated by the CLM4-LISSS offline lake model and estimated with pan evaporation data. Both methods were calibrated against lake evaporation measured directly with eddy covariance in 2012. Results show a significant increasing trend of annual lake evaporation from 1979 to 2013, at a rate of 29.6 mm decade-1 according to the lake model and 25.4 mm decade-1 according to the pan method. The mean annual evaporation during this period shows good agreement between these two methods (977 mm according to the model and 1007 mm according to the pan method). A stepwise linear regression reveals that downward shortwave radiation was the most significant contributor to the modeled evaporation trend, while air temperature was the most significant contributor to the pan evaporation trend. Wind speed had little impact on the modeled lake evaporation but had a negative contribution to the pan evaporation trend offsetting some of the temperature effect. Reference evaporation was not a good proxy for the lake evaporation because it was on average 20.6 % too high and its increasing trend was too large (56.5 mm decade-1).

New models for droplet heating and evaporation

KAUST Repository

Sazhin, Sergei S.

2013-02-01

A brief summary of new models for droplet heating and evaporation, developed mainly at the Sir Harry Ricardo Laboratory of the University of Brighton during 2011-2012, is presented. These are hydrodynamic models for mono-component droplet heating and evaporation, taking into account the effects of the moving boundary due to evaporation, hydrodynamic models of multi-component droplet heating and evaporation, taking and not taking into account the effects of the moving boundary, new kinetic models of mono-component droplet heating and evaporation, and a model for mono-component droplet evaporation, based on molecular dynamics simulation. The results, predicted by the new models are compared with experimental data and the prehctions of the previously developed models where possible. © 2013 Asian Network for Scientific Information.

Evaporation, Boiling and Bubbles

Science.gov (United States)

Goodwin, Alan

2012-01-01

Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The…

SYNTHESIS, REACTIVITY AND BIOLOGICAL ACTIVITY OF QUINOXALIN-2-ONE DERIVATIVES

OpenAIRE

El Mokhtar Essassi; R. Bouhfid; Y. Kandri Rodi; S. Ferfra; H. Benzeid; Y. Ramli

2010-01-01

Quinoxalines have a great interest in various fields and particularly in chemistry, biology and pharmacology. It enabled the researchers to develop many methods for their preparations and to seek new fields of application. In this review, we’ll expose different methods of synthesis of the quinoxalin-2-one, its reactivity and finally we’ll discuss the various biological activities of its derivatives.

Sustained Na+/H+ exchanger activation promotes gliotransmitter release from reactive hippocampal astrocytes following oxygen-glucose deprivation.

Directory of Open Access Journals (Sweden)

Pelin Cengiz

Full Text Available Hypoxia ischemia (HI-related brain injury is the major cause of long-term morbidity in neonates. One characteristic hallmark of neonatal HI is the development of reactive astrogliosis in the hippocampus. However, the impact of reactive astrogliosis in hippocampal damage after neonatal HI is not fully understood. In the current study, we investigated the role of Na(+/H(+ exchanger isoform 1 (NHE1 protein in mouse reactive hippocampal astrocyte function in an in vitro ischemia model (oxygen/glucose deprivation and reoxygenation, OGD/REOX. 2 h OGD significantly increased NHE1 protein expression and NHE1-mediated H(+ efflux in hippocampal astrocytes. NHE1 activity remained stimulated during 1-5 h REOX and returned to the basal level at 24 h REOX. NHE1 activation in hippocampal astrocytes resulted in intracellular Na(+ and Ca(2+ overload. The latter was mediated by reversal of Na(+/Ca(2+ exchange. Hippocampal astrocytes also exhibited a robust release of gliotransmitters (glutamate and pro-inflammatory cytokines IL-6 and TNFα during 1-24 h REOX. Interestingly, inhibition of NHE1 activity with its potent inhibitor HOE 642 not only reduced Na(+ overload but also gliotransmitter release from hippocampal astrocytes. The noncompetitive excitatory amino acid transporter inhibitor TBOA showed a similar effect on blocking the glutamate release. Taken together, we concluded that NHE1 plays an essential role in maintaining H(+ homeostasis in hippocampal astrocytes. Over-stimulation of NHE1 activity following in vitro ischemia disrupts Na(+ and Ca(2+ homeostasis, which reduces Na(+-dependent glutamate uptake and promotes release of glutamate and cytokines from reactive astrocytes. Therefore, blocking sustained NHE1 activation in reactive astrocytes may provide neuroprotection following HI.

The evaporation of crude oil and petroleum products

International Nuclear Information System (INIS)

Fingas, M. F.

1996-01-01

The physics of oil and petroleum evaporation was studied by means of an experimental apparatus. The evaporation was determined by weight loss and recorded on a computer. Examination of the data showed that most oil and petroleum products (those with seven to ten components) evaporate at a logarithmic rate with respect to time, while other petroleum products (those with fewer chemical components) evaporate at a rate which is square root with respect to time. Evaporation of oil and petroleum was not strictly boundary-layer regulated because the typical oil evaporation rate rates do not exceed that of molecular diffusion and thus turbulent diffusion does not increase the evaporation rates. Overall, boundary layer regulation can be ignored in the prediction of oil and petroleum evaporation. The simple equation relating only the logarithm of time (or the square root of time in the case of narrow-cut products) and temperature are sufficient to accurately describe oil evaporation. refs., figs

Water evaporation: a transition path sampling study.

Science.gov (United States)

Varilly, Patrick; Chandler, David

2013-02-07

We use transition path sampling to study evaporation in the SPC/E model of liquid water. On the basis of thousands of evaporation trajectories, we characterize the members of the transition state ensemble (TSE), which exhibit a liquid-vapor interface with predominantly negative mean curvature at the site of evaporation. We also find that after evaporation is complete, the distributions of translational and angular momenta of the evaporated water are Maxwellian with a temperature equal to that of the liquid. To characterize the evaporation trajectories in their entirety, we find that it suffices to project them onto just two coordinates: the distance of the evaporating molecule to the instantaneous liquid-vapor interface and the velocity of the water along the average interface normal. In this projected space, we find that the TSE is well-captured by a simple model of ballistic escape from a deep potential well, with no additional barrier to evaporation beyond the cohesive strength of the liquid. Equivalently, they are consistent with a near-unity probability for a water molecule impinging upon a liquid droplet to condense. These results agree with previous simulations and with some, but not all, recent experiments.

Modeling Evaporation and Particle Assembly in Colloidal Droplets.

Science.gov (United States)

Zhao, Mingfei; Yong, Xin

2017-06-13

Evaporation-induced assembly of nanoparticles in a drying droplet is of great importance in many engineering applications, including printing, coating, and thin film processing. The investigation of particle dynamics in evaporating droplets can provide fundamental hydrodynamic insight for revealing the processing-structure relationship in the particle self-organization induced by solvent evaporation. We develop a free-energy-based multiphase lattice Boltzmann method coupled with Brownian dynamics to simulate evaporating colloidal droplets on solid substrates with specified wetting properties. The influence of interface-bound nanoparticles on the surface tension and evaporation of a flat liquid-vapor interface is first quantified. The results indicate that the particles at the interface reduce surface tension and enhance evaporation flux. For evaporating particle-covered droplets on substrates with different wetting properties, we characterize the increase of evaporate rate via measuring droplet volume. We find that droplet evaporation is determined by the number density and circumferential distribution of interfacial particles. We further correlate particle dynamics and assembly to the evaporation-induced convection in the bulk and on the surface of droplet. Finally, we observe distinct final deposits from evaporating colloidal droplets with bulk-dispersed and interface-bound particles. In addition, the deposit pattern is also influenced by the equilibrium contact angle of droplet.

Evaporation From Soil Containers With Irregular Shapes

Science.gov (United States)

Assouline, Shmuel; Narkis, Kfir

2017-11-01

Evaporation from bare soils under laboratory conditions is generally studied using containers of regular shapes where the vertical edges are parallel to the flow lines in the drying domain. The main objective of this study was to investigate the impact of irregular container shapes, for which the flow lines either converge or diverge toward the surface. Evaporation from initially saturated sand and sandy loam soils packed in cones and inverted cones was compared to evaporation from corresponding cylindrical columns. The initial evaporation rate was higher in the cones, and close to potential evaporation. At the end of the experiment, the cumulative evaporation depth in the sand cone was equal to that in the column but higher than in the inverted cone, while in the sandy loam, the order was cone > column > inverted cone. By comparison to the column, stage 1 evaporation was longer in the cones, and practically similar in the inverted cones. Stage 2 evaporation rate decreased with the increase of the evaporating surface area. These results were more pronounced in the sandy loam. For the sand column, the transition between stage 1 and stage 2 evaporation occurred when the depth of the saturation front was approximately equal to the characteristic length of the soil. However, for the cone and the inverted cone, it occurred for a shallower depth of the saturation front. It seems therefore that the concept of the characteristic length derived from the soil hydraulic properties is related to drying systems of regular shapes.

Evaporative lithographic patterning of binary colloidal films.

Science.gov (United States)

Harris, Daniel J; Conrad, Jacinta C; Lewis, Jennifer A

2009-12-28

Evaporative lithography offers a promising new route for patterning a broad array of soft materials. In this approach, a mask is placed above a drying film to create regions of free and hindered evaporation, which drive fluid convection and entrained particles to regions of highest evaporative flux. We show that binary colloidal films exhibit remarkable pattern formation when subjected to a periodic evaporative landscape during drying.

Evaporative cooling in polymer electrolyte fuel cell

Energy Technology Data Exchange (ETDEWEB)

Shimotori, S; Sonai, A [Toshiba Corp. Tokyo (Japan)

1996-06-05

The concept of the evaporative cooling for the internally humidified PEFC was confirmed by the experiment. The evaporative cooling rates at the anode and the cathode were mastered under the various temperatures and air utilizations. At a high temperature the proportion of the evaporative cooling rate to the heat generation rate got higher, the possibility of the evaporative cooling was demonstrated. 2 refs., 7 figs., 1 tab.

Evaporation, diffusion and self-assembly at drying interfaces.

Science.gov (United States)

Roger, K; Sparr, E; Wennerström, H

2018-04-18

Water evaporation from complex aqueous solutions leads to the build-up of structure and composition gradients at their interface with air. We recently introduced an experimental setup for quantitatively studying such gradients and discussed how structure formation can lead to a self-regulation mechanism for controlling water evaporation through self-assembly. Here, we provide a detailed theoretical analysis using an advection/diffusion transport equation that takes into account thermodynamically non-ideal conditions and we directly relate the theoretical description to quantitative experimental data. We derive that the concentration profile develops according to a general square root of time scaling law, which fully agrees with experimental observations. The evaporation rate notably decreases with time as t-1/2, which shows that diffusion in the liquid phase is the rate limiting step for this system, in contrast to pure water evaporation. For the particular binary system that was investigated experimentally, which is composed of water and a sugar-based surfactant (α-dodecylmaltoside), the interfacial layer consists in a sequence of liquid crystalline phases of different mesostructures. We extract values for mutual diffusion coefficients of lamellar, hexagonal and micellar cubic phases, which are consistent with previously reported values and simple models. We thus provide a method to estimate the transport properties of oriented mesophases. The macroscopic humidity-independence of the evaporation rate up to 85% relative humidities is shown to result from both an extremely low mutual diffusion coefficient and the large range of water activities corresponding to relative humidities below 85%, at which the lamellar phase exists. Such a humidity self-regulation mechanism is expected for a large variety of complex system.

Intrinsic Evaporative Cooling by Hygroscopic Earth Materials

Directory of Open Access Journals (Sweden)

Alexandra R. Rempel

2016-08-01

Full Text Available The phase change of water from liquid to vapor is one of the most energy-intensive physical processes in nature, giving it immense potential for cooling. Diverse evaporative cooling strategies have resulted worldwide, including roof ponds and sprinklers, courtyard fountains, wind catchers with qanats, irrigated green roofs, and fan-assisted evaporative coolers. These methods all require water in bulk liquid form. The evaporation of moisture that has been sorbed from the atmosphere by hygroscopic materials is equally energy-intensive, however, yet has not been examined for its cooling potential. In arid and semi-arid climates, hygroscopic earth buildings occur widely and are known to maintain comfortable indoor temperatures, but evaporation of moisture from their walls and roofs has been regarded as unimportant since water scarcity limits irrigation and rainfall; instead, their cool interiors are attributed to well-established mass effects in delaying the transmission of sensible gains. Here, we investigate the cooling accomplished by daily cycles of moisture sorption and evaporation which, requiring only ambient humidity, we designate as “intrinsic” evaporative cooling. Connecting recent soil science to heat and moisture transport studies in building materials, we use soils, adobe, cob, unfired earth bricks, rammed earth, and limestone to reveal the effects of numerous parameters (temperature and relative humidity, material orientation, thickness, moisture retention properties, vapor diffusion resistance, and liquid transport properties on the magnitude of intrinsic evaporative cooling and the stabilization of indoor relative humidity. We further synthesize these effects into concrete design guidance. Together, these results show that earth buildings in diverse climates have significant potential to cool themselves evaporatively through sorption of moisture from humid night air and evaporation during the following day’s heat. This finding

Towards a rational definition of potential evaporation

Directory of Open Access Journals (Sweden)

J.-P. Lhommel

1997-01-01

Full Text Available The concept of potential evaporation is defined on the basis of the following criteria: (i it must establish an upper limit to the evaporation process in a given environment (the term 'environment' including meteorological and surface conditions, and (ii this upper limit must be readily calculated from measured input data. It is shown that this upper limit is perfectly defined and is given by the Penman equation, applied with the corresponding meteorological data (incoming radiation and air characteristics measured at a reference height and the appropriate surface characteristics (albedo, roughness length, soil heat flux. Since each surface has its own potential evaporation, a function of its own surface characteristics, it is useful to define a reference potential evaporation as a short green grass completely shading the ground. Although the potential evaporation from a given surface is readily calculated from the Penman equation, its physical significance or interpretation is not so straightforward, because it represents only an idealized situation, not a real one. Potential evaporation is the evaporation from this surface, when saturated and extensive enough to obviate any effect of local advection, under the same meteorological conditions. Due to the feedback effects of evaporation on air characteristics, it does not represent the 'real' evaporation (i.e. the evaporation which could be physically observed in the real world from such an extensive saturated surface in these given meteorological conditions (if this saturated surface were substituted for an unsaturated one previously existing. From a rigorous standpoint, this calculated potential evaporation is not physically observable. Nevertheless, an approximate representation can be given by the evaporation from a limited saturated area, the dimension of which depends on the height of measurement of the air characteristics used as input in the Penman equation. If they are taken at a height

Modelling refrigerant distribution in microchannel evaporators

DEFF Research Database (Denmark)

Brix, Wiebke; Kærn, Martin Ryhl; Elmegaard, Brian

2009-01-01

of the refrigerant distribution is carried out for two channels in parallel and for two different cases. In the first case maldistribution of the inlet quality into the channels is considered, and in the second case a non-uniform airflow on the secondary side is considered. In both cases the total mixed superheat...... out of the evaporator is kept constant. It is shown that the cooling capacity of the evaporator is reduced significantly, both in the case of unevenly distributed inlet quality and for the case of non-uniform airflow on the outside of the channels.......The effects of refrigerant maldistribution in parallel evaporator channels on the heat exchanger performance are investigated numerically. For this purpose a 1D steady state model of refrigerant R134a evaporating in a microchannel tube is built and validated against other evaporator models. A study...

Is evaporative colling important for shallow clouds?

Science.gov (United States)

Gentine, P.; Park, S. B.; Davini, P.; D'Andrea, F.

2017-12-01

We here investigate and test using large-eddy simulations the hypothesis that evaporative cooling might not be crucial for shallow clouds. Results from various Shallow convection and stratocumulus LES experiments show that the influence of evaporative cooling is secondary compared to turbulent mixing, which dominates the buoyancy reversal. In shallow cumulus subising shells are not due to evaporative cooling but rather reflect a vortical structure, with a postive buoyancy anomaly in the core due to condensation. Disabling evaporative cooling has negligible impact on this vortical structure and on buoyancy reversal. Similarly in non-precipitating stratocumuli evaporative cooling is negeligible copmared to other factors, especially turbulent mixing and pressure effects. These results emphasize that it may not be critical to icnlude evaporative cooling in parameterizations of shallow clouds and that it does not alter entrainment.

Dual manifold heat pipe evaporator

Science.gov (United States)

Adkins, D.R.; Rawlinson, K.S.

1994-01-04

An improved evaporator section is described for a dual manifold heat pipe. Both the upper and lower manifolds can have surfaces exposed to the heat source which evaporate the working fluid. The tubes in the tube bank between the manifolds have openings in their lower extensions into the lower manifold to provide for the transport of evaporated working fluid from the lower manifold into the tubes and from there on into the upper manifold and on to the condenser portion of the heat pipe. A wick structure lining the inner walls of the evaporator tubes extends into both the upper and lower manifolds. At least some of the tubes also have overflow tubes contained within them to carry condensed working fluid from the upper manifold to pass to the lower without spilling down the inside walls of the tubes. 1 figure.

Evaporation from a sphagnum moss surface

Science.gov (United States)

D.S. Nichols; J.M. Brown

1980-01-01

Peat cores, 45 cm in diameter, were collected from a sphagnum bog in northern Minnesota, and used to measure the effects of different temperatures and water levels on evaporation from a sphagnum moss surface in a growth chamber. Under all conditions, evaporation from the moss surface was greater than that from a free-water surface. Evaporation from the moss increased...

Rapid heating evaporation of Pb(NO3)2. Evidence for heterogeneous ion-molecule reactions

International Nuclear Information System (INIS)

Radus, T.P.; Udseth, H.R.; Friedman, L.

1979-01-01

A mass spectrometric investigation of the lead nitrate system is reported in which the lead nitrate was evaporated from a probe filament that was heated as rapidly as 5000 0 C/s. Both electron impact (EI) and chemical ionization (CI) source techniques were used in this study. Fragment ions and decomposition products were observed under EI conditions. Under CI conditions solvated fragment ions and protonated solvated molecular ions were detected. Temperature measurements of rates of evaporation were made by monitoring the resistance of the probe filament as it was heated. Activation energies calculated by using these temperature coefficients of evaporation rates indicate that evaporations under CI conditions are assisted by heterogeneous ion-molecule reactions

SYNTHESIS, REACTIVITY AND BIOLOGICAL ACTIVITY OF QUINOXALIN-2-ONE DERIVATIVES

Directory of Open Access Journals (Sweden)

El Mokhtar Essassi

2010-04-01

Full Text Available Quinoxalines have a great interest in various fields and particularly in chemistry, biology and pharmacology. It enabled the researchers to develop many methods for their preparations and to seek new fields of application. In this review, we’ll expose different methods of synthesis of the quinoxalin-2-one, its reactivity and finally we’ll discuss the various biological activities of its derivatives.

Reactive sites influence in PMMA oligomers reactivity: a DFT study

Science.gov (United States)

Paz, C. V.; Vásquez, S. R.; Flores, N.; García, L.; Rico, J. L.

2018-01-01

In this work, we present a theoretical study of methyl methacrylate (MMA) living anionic polymerization. The study was addressed to understanding two important experimental observations made for Michael Szwarc in 1956. The unexpected effect of reactive sites concentration in the propagation rate, and the self-killer behavior of MMA (deactivating of living anionic polymerization). The theoretical calculations were performed by density functional theory (DFT) to obtain the frontier molecular orbitals values. These values were used to calculate and analyze the chemical interaction descriptors in DFT-Koopmans’ theorem. As a result, it was observed that the longest chain-length species (related with low concentration of reactive sites) exhibit the highest reactivity (behavior associated with the increase of the propagation rate). The improvement in this reactivity was attributed to the crosslinking produced in the polymethyl methacrylate chains. Meanwhile, the self-killer behavior was associated with the intermolecular forces present in the reactive sites. This behavior was associated to an obstruction in solvation, since the active sites remained active through all propagation species. The theoretical results were in good agreement with the Szwarc experiments.

Epstein-Barr Virus Lytic Reactivation Activates B Cells Polyclonally and Induces Activation-Induced Cytidine Deaminase Expression: A Mechanism Underlying Autoimmunity and Its Contribution to Graves' Disease.

Science.gov (United States)

Nagata, Keiko; Kumata, Keisuke; Nakayama, Yuji; Satoh, Yukio; Sugihara, Hirotsugu; Hara, Sayuri; Matsushita, Michiko; Kuwamoto, Satoshi; Kato, Masako; Murakami, Ichiro; Hayashi, Kazuhiko

2017-04-01

Graves' disease is an autoimmune disease that results in and is the most common cause of hyperthyroidism, and the reactivation of persisting Epstein-Barr virus (EBV) in B lymphocytes induces the differentiation of host B cells into plasma cells. We previously reported that some EBV-infected B cells had thyrotropin receptor antibodies (TRAbs) as surface immunoglobulins (Igs), and EBV reactivation induced these TRAb+EBV+ cells to produce TRAbs. EBV reactivation induces Ig production from host B cells. The purpose of the present study was to examine total Ig productions from B cell culture fluids and to detect activation-induced cytidine deaminase (AID), nuclear factor kappa B (NF-κB), and EBV latent membrane protein (LMP) 1 in culture B cells during EBV reactivation induction and then we discussed the mechanisms of EBV reactivation-induced Ig production in relation to autoimmunity. We showed that the EBV reactivation induces the production of every isotype of Ig and suggested that the Ig production was catalyzed by AID through LMP1 and NF-κB. The results that the amount of IgM was significantly larger compared with IgG suggested the polyclonal B cell activation due to LMP1. We proposed the pathway of EBV reactivation induced Ig production; B cells newly infected with EBV are activated by polyclonal B cell activation and produce Igs through plasma cell differentiation induced by EBV reactivation. LMP1-induced AID enabled B cells to undergo class-switch recombination to produce every isotype of Ig. According to this mechanism, EBV rescues autoreactive B cells to produce autoantibodies, which contribute to the development and exacerbation of autoimmune diseases.

Evaporation dynamics of a sessile droplet on glass surfaces with fluoropolymer coatings: focusing on the final stage of thin droplet evaporation.

Science.gov (United States)

Gatapova, Elizaveta Ya; Shonina, Anna M; Safonov, Alexey I; Sulyaeva, Veronica S; Kabov, Oleg A

2018-03-07

The evaporation dynamics of a water droplet with an initial volume of 2 μl from glass surfaces with fluoropolymer coatings are investigated using the shadow technique and an optical microscope. The droplet profile for a contact angle of less than 5° is constructed using an image-analyzing interference technique, and evaporation dynamics are investigated at the final stage. We coated the glass slides with a thin film of a fluoropolymer by the hot-wire chemical vapor deposition method at different deposition modes depending on the deposition pressure and the temperature of the activating wire. The resulting surfaces have different structures affecting the wetting properties. Droplet evaporation from a constant contact radius mode in the early stage of evaporation was found followed by the mode where both contact angle and contact radius simultaneously vary in time (final stage) regardless of wettability of the coated surfaces. We found that depinning occurs at small contact angles of 2.2-4.7° for all samples, which are smaller than the measured receding contact angles. This is explained by imbibition of the liquid into the developed surface of the "soft" coating that leads to formation of thin droplets completely wetting the surface. The final stage, which is little discussed in the literature, is also recorded. We have singled out a substage where the contact line velocity is abruptly increasing for all coated and uncoated surfaces. The critical droplet height corresponding to the transition to this substage is about 2 μm with R/h = 107. The duration of this substage is the same for all coated and uncoated surfaces. Droplets observed at this substage for all the tested surfaces are axisymmetric. The specific evaporation rate clearly demonstrates an abrupt increase at the final substage of the droplet evaporation. The classical R 2 law is justified for the complete wetting situation where the droplet is disappearing in an axisymmetric manner.

Silver Eco-Solvent Ink for Reactive Printing of Polychromatic SERS and SPR Substrates.

Science.gov (United States)

Dustov, Mavlavi; Golovina, Diana I; Polyakov, Alexander Yu; Goldt, Anastasia E; Eliseev, Andrei A; Kolesnikov, Efim A; Sukhorukova, Irina V; Shtansky, Dmitry V; Grünert, Wolfgang; Grigorieva, Anastasia V

2018-02-09

A new reactive ink based on a silver citrate complex is proposed for a photochemical route to surface-enhanced Raman spectroscopy active substrates with controllable extinction spectra. The drop-cast test of the ink reveals homogeneous nucleation of silver and colloid particle growth originating directly from photochemical in situ reduction in droplets, while the following evaporation of the deposited ink produces small nano- and micron-size particles. The prepared nanostructures and substrates were accurately characterized by electron microscopy methods and optical extinction spectroscopy. Varying the duration of UV irradiation allows tuning the morphology of individual silver nanoparticles forming hierarchical ring structures with numerous "hot spots" for most efficient Raman enhancement. Raman measurements of probe molecules of rhodamine 6G and methylene blue reached the largest signal enhancement of 10⁶ by the resonance effects.

New models for droplet heating and evaporation

KAUST Repository

Sazhin, Sergei S.; Elwardani, Ahmed Elsaid; Gusev, Ivan G.; Xie, Jianfei; Shishkova, Irina N.; Cao, Bingyang; Snegirev, Alexander Yu.; Heikal, Morgan Raymond

2013-01-01

and evaporation, taking into account the effects of the moving boundary due to evaporation, hydrodynamic models of multi-component droplet heating and evaporation, taking and not taking into account the effects of the moving boundary, new kinetic models of mono

Evaporative removal of sodium: interim progress report and preliminary facility specification

International Nuclear Information System (INIS)

Welch, F.H.

1978-01-01

A summary of the current Evaporative Removal of Sodium (ERNA) activities at the Energy Systems Group is presented. Also included is a review of earlier work on sodium evaporation. As a result of this work it was concluded that the ERNA process was extremely successful and worthy of future consideration as a recognized process for reactor components. Also included in the report is a Preliminary Outline Specification for a large facility to remove sodium from full size CRBR fuel rod assemblies

From field evaporation to focused ion beams

International Nuclear Information System (INIS)

Forbes, R.G.

2004-01-01

Full text: This paper report various items of recent progress in the theory of field evaporation and the theory of the liquid-metal ion source. The research has, in part, been driven by a desire to find out how to reduce the beam-spot size in a focused ion beam machine, which is developing as a significant tool of nanotechnology. A major factor in determining beam spot size seems to be the behavior of the liquid-metal ion source (LMIS), and one route might be to reduce the minimum emission current of a LMIS, if this is possible. Theories of LMIS minimum emission current have been re-examined. Some progress has been made, but development of more accurate theory has been constrained by several factors, include the long-known limitations of the present theory of field evaporation (FEV). This, in turn, has stimulated a wider re-examination of FEV theory. As part of some general theoretical remarks, the following items of recent progress will be covered. Various results concerning the prediction of the field F e at which the activation energy Q for field evaporation is zero, including calculations in which vacuum electrostatic energy changes are taken into account, and another look at the views of Kingham and Tsong concerning escape charge-state. Some years ago, the following approximate formula was derived for the dependence of FEV activation energy on field F: Q=B(F e /F - 1) 2 . It has recently been possible to show that the parameter B can be estimated as B= βYΩ/8, where Y is Young's modulus, Ω is the atomic volume, and β is a correction factor of order. In the framework of the charge-draining mechanism, another look at how the activation-energy hump can be modelled, in order to predict/explain the conditions under which FEV becomes dominated by ion tunnelling rather than field evaporation. A review of the changes in LMIS theory that result from applying the equation of continuity to the metal/vacuum interface, including modifications to the theory of minimum

Exploring Ultimate Water Capillary Evaporation in Nanoscale Conduits.

Science.gov (United States)

Li, Yinxiao; Alibakhshi, Mohammad Amin; Zhao, Yihong; Duan, Chuanhua

2017-08-09

Capillary evaporation in nanoscale conduits is an efficient heat/mass transfer strategy that has been widely utilized by both nature and mankind. Despite its broad impact, the ultimate transport limits of capillary evaporation in nanoscale conduits, governed by the evaporation/condensation kinetics at the liquid-vapor interface, have remained poorly understood. Here we report experimental study of the kinetic limits of water capillary evaporation in two dimensional nanochannels using a novel hybrid channel design. Our results show that the kinetic-limited evaporation fluxes break down the limits predicated by the classical Hertz-Knudsen equation by an order of magnitude, reaching values up to 37.5 mm/s with corresponding heat fluxes up to 8500 W/cm 2 . The measured evaporation flux increases with decreasing channel height and relative humidity but decreases as the channel temperature decreases. Our findings have implications for further understanding evaporation at the nanoscale and developing capillary evaporation-based technologies for both energy- and bio-related applications.

Combined Active and Reactive Power Control of Wind Farms based on Model Predictive Control

DEFF Research Database (Denmark)

Zhao, Haoran; Wu, Qiuwei; Wang, Jianhui

2017-01-01

This paper proposes a combined wind farm controller based on Model Predictive Control (MPC). Compared with the conventional decoupled active and reactive power control, the proposed control scheme considers the significant impact of active power on voltage variations due to the low X=R ratio...... of wind farm collector systems. The voltage control is improved. Besides, by coordination of active and reactive power, the Var capacity is optimized to prevent potential failures due to Var shortage, especially when the wind farm operates close to its full load. An analytical method is used to calculate...... the sensitivity coefficients to improve the computation efficiency and overcome the convergence problem. Two control modes are designed for both normal and emergency conditions. A wind farm with 20 wind turbines was used to verify the proposed combined control scheme....

Evaporation of Particle-Stabilized Emulsion Sunscreen Films.

Science.gov (United States)

Binks, Bernard P; Fletcher, Paul D I; Johnson, Andrew J; Marinopoulos, Ioannis; Crowther, Jonathan M; Thompson, Michael A

2016-08-24

We recently showed (Binks et al., ACS Appl. Mater. Interfaces, 2016, DOI: 10.1021/acsami.6b02696) how evaporation of sunscreen films consisting of solutions of molecular UV filters leads to loss of UV light absorption and derived sun protection factor (SPF). In the present work, we investigate evaporation-induced effects for sunscreen films consisting of particle-stabilized emulsions containing a dissolved UV filter. The emulsions contained either droplets of propylene glycol (PG) in squalane (SQ), droplets of SQ in PG or droplets of decane in PG. In these different emulsion types, the SQ is involatile and shows no evaporation, the PG is volatile and evaporates relatively slowly, whereas the decane is relatively very volatile and evaporates quickly. We have measured the film mass and area, optical micrographs of the film structure, and the UV absorbance spectra during evaporation. For emulsion films containing the involatile SQ, evaporation of the PG causes collapse of the emulsion structure with some loss of specular UV absorbance due to light scattering. However, for these emulsions with droplets much larger than the wavelength of light, the light is scattered only at small forward angles so does not contribute to the diffuse absorbance and the film SPF. The UV filter remains soluble throughout the evaporation and thus the UV absorption by the filter and the SPF remain approximately constant. Both PG-in-SQ and SQ-in-PG films behave similarly and do not show area shrinkage by dewetting. In contrast, the decane-in-PG film shows rapid evaporative loss of the decane, followed by slower loss of the PG resulting in precipitation of the UV filter and film area shrinkage by dewetting which cause the UV absorbance and derived SPF to decrease. Measured UV spectra during evaporation are in reasonable agreement with spectra calculated using models discussed here.

Water evaporation in silica colloidal deposits.

Science.gov (United States)

Peixinho, Jorge; Lefèvre, Grégory; Coudert, François-Xavier; Hurisse, Olivier

2013-10-15

The results of an experimental study on the evaporation and boiling of water confined in the pores of deposits made of mono-dispersed silica colloidal micro-spheres are reported. The deposits are studied using scanning electron microscopy, adsorption of nitrogen, and adsorption of water through attenuated total reflection-infrared spectroscopy. The evaporation is characterized using differential scanning calorimetry and thermal gravimetric analysis. Optical microscopy is used to observe the patterns on the deposits after evaporation. When heating at a constant rate and above boiling temperature, the release of water out of the deposits is a two step process. The first step is due to the evaporation and boiling of the surrounding and bulk water and the second is due to the desorption of water from the pores. Additional experiments on the evaporation of water from membranes having cylindrical pores and of heptane from silica deposits suggest that the second step is due to the morphology of the deposits. Copyright © 2013 Elsevier Inc. All rights reserved.

Controlling water evaporation through self-assembly.

Science.gov (United States)

Roger, Kevin; Liebi, Marianne; Heimdal, Jimmy; Pham, Quoc Dat; Sparr, Emma

2016-09-13

Water evaporation concerns all land-living organisms, as ambient air is dryer than their corresponding equilibrium humidity. Contrarily to plants, mammals are covered with a skin that not only hinders evaporation but also maintains its rate at a nearly constant value, independently of air humidity. Here, we show that simple amphiphiles/water systems reproduce this behavior, which suggests a common underlying mechanism originating from responding self-assembly structures. The composition and structure gradients arising from the evaporation process were characterized using optical microscopy, infrared microscopy, and small-angle X-ray scattering. We observed a thin and dry outer phase that responds to changes in air humidity by increasing its thickness as the air becomes dryer, which decreases its permeability to water, thus counterbalancing the increase in the evaporation driving force. This thin and dry outer phase therefore shields the systems from humidity variations. Such a feedback loop achieves a homeostatic regulation of water evaporation.

An fMRI study of nicotine-deprived smokers' reactivity to smoking cues during novel/exciting activity.

Directory of Open Access Journals (Sweden)

Xiaomeng Xu

Full Text Available Engaging in novel/exciting ("self-expanding" activities activates the mesolimbic dopamine pathway, a brain reward pathway also associated with the rewarding effects of nicotine. This suggests that self-expanding activities can potentially substitute for the reward from nicotine. We tested this model among nicotine-deprived smokers who, during fMRI scanning, played a series of two-player cooperative games with a relationship partner. Games were randomized in a 2 (self-expanding vs. not x 2 (cigarette cue present vs. absent design. Self-expansion conditions yielded significantly greater activation in a reward region (caudate than did non-self-expansion conditions. Moreover, when exposed to smoking cues during the self-expanding versus the non-self-expanding cooperative games, smokers showed less activation in a cigarette cue-reactivity region, a priori defined [temporo-parietal junction (TPJ] from a recent meta-analysis of cue-reactivity. In smoking cue conditions, increases in excitement associated with the self-expanding condition (versus the non-self-expanding condition were also negatively correlated with TPJ activation. These results support the idea that a self-expanding activity promoting reward activation attenuates cigarette cue-reactivity among nicotine-deprived smokers. Future research could focus on the parameters of self-expanding activities that produce this effect, as well as test the utility of self-expansion in clinical interventions for smoking cessation.

Waste Feed Evaporation Physical Properties Modeling

International Nuclear Information System (INIS)

Daniel, W.E.

2003-01-01

This document describes the waste feed evaporator modeling work done in the Waste Feed Evaporation and Physical Properties Modeling test specification and in support of the Hanford River Protection Project (RPP) Waste Treatment Plant (WTP) project. A private database (ZEOLITE) was developed and used in this work in order to include the behavior of aluminosilicates such a NAS-gel in the OLI/ESP simulations, in addition to the development of the mathematical models. Mathematical models were developed that describe certain physical properties in the Hanford RPP-WTP waste feed evaporator process (FEP). In particular, models were developed for the feed stream to the first ultra-filtration step characterizing its heat capacity, thermal conductivity, and viscosity, as well as the density of the evaporator contents. The scope of the task was expanded to include the volume reduction factor across the waste feed evaporator (total evaporator feed volume/evaporator bottoms volume). All the physical properties were modeled as functions of the waste feed composition, temperature, and the high level waste recycle volumetric flow rate relative to that of the waste feed. The goal for the mathematical models was to predict the physical property to predicted simulation value. The simulation model approximating the FEP process used to develop the correlations was relatively complex, and not possible to duplicate within the scope of the bench scale evaporation experiments. Therefore, simulants were made of 13 design points (a subset of the points used in the model fits) using the compositions of the ultra-filtration feed streams as predicted by the simulation model. The chemistry and physical properties of the supernate (the modeled stream) as predicted by the simulation were compared with the analytical results of experimental simulant work as a method of validating the simulation software

Spray and evaporation characteristics of ethanol and gasoline direct injection in non-evaporating, transition and flash-boiling conditions

International Nuclear Information System (INIS)

Huang, Yuhan; Huang, Sheng; Huang, Ronghua; Hong, Guang

2016-01-01

Highlights: • Sprays can be considered as non-evaporating when vapour pressure is lower than 30 kPa. • Ethanol direct injection should only be applied in high temperature engine environment. • Gasoline spray collapses at lower fuel temperature (350 K) than ethanol spray does (360 K). • Flash-boiling does not occur when fuel temperature reaches boiling point until ΔT is 14 K. • Not only spray evaporation mode but also breakup mechanism change with fuel temperature. - Abstract: Ethanol direct injection plus gasoline port injection (EDI + GPI) represents a more efficient and flexible way to utilize ethanol fuel in spark ignition engines. To exploit the potentials of EDI, the mixture formation characteristics need to be investigated. In this study, the spray and evaporation characteristics of ethanol and gasoline fuels injected from a multi-hole injector were investigated by high speed Shadowgraphy imaging technique in a constant volume chamber. The experiments covered a wide range of fuel temperature from 275 K (non-evaporating) to 400 K (flash-boiling) which corresponded to cold start and running conditions in an engine. The spray transition process from normal-evaporating to flash-boiling was investigated in greater details than the existed studies. Results showed that ethanol and gasoline sprays demonstrated the same patterns in non-evaporating conditions. The sprays could be considered as non-evaporating when vapour pressure was lower than 30 kPa. Ethanol evaporated more slowly than gasoline did in low temperature environment, but they reached the similar evaporation rates when temperature was higher than 375 K. This suggested that EDI should only be applied in high temperature engine environment. For both ethanol and gasoline sprays, when the excess temperature was smaller than 4 K, the sprays behaved the same as the subcooled sprays did. The sprays collapsed when the excess temperature was 9 K. Flash-boiling did not occur until the excess temperature

Isotope Fractionation of Water During Evaporation Without Condensation

International Nuclear Information System (INIS)

Cappa, Christopher D.; Drisdell, Walter S.; Smith, Jared D.; Saykally, Richard J.; Cohen, Ronald C.

2005-01-01

The microscopic events engendering liquid water evaporation have received much attention over the last century, but remain incompletely understood. We present measurements of isotope fractionation occurring during free molecular evaporation from liquid microjets and show that the isotope ratios of evaporating molecules exhibit dramatic differences from equilibrium vapor values, strong variations with the solution deuterium mole fraction, and a clear temperature dependence. These results indicate the existence of an energetic barrier to evaporation and that the evaporation coefficient of water is less than unity. These new insights into water evaporation promise to advance our understanding of the processes that control the formation and lifetime of clouds in the atmosphere.

Boilers, evaporators, and condensers

International Nuclear Information System (INIS)

Kakac, S.

1991-01-01

This book reports on the boilers, evaporators and condensers that are used in power plants including nuclear power plants. Topics included are forced convection for single-phase side heat exchangers, heat exchanger fouling, industrial heat exchanger design, fossil-fuel-fired boilers, once through boilers, thermodynamic designs of fossil fuel-first boilers, evaporators and condensers in refrigeration and air conditioning systems (with respect to reducing CFC's) and nuclear steam generators

An evaporation driven pump for microfluidics applications

NARCIS (Netherlands)

Nie, C.; Mandamparambil, R.; Frijns, A.J.H.; den Toonder, J.M.J.; Tadrist, L.; Graur, I.

2014-01-01

We present an evaporation driven micro-pump for micro fluidic applications on a foil. In such a device, the evaporation rate is controlled by the geometry of the channel outlet and its temperature. The evaporation is also influenced by environmental parameters such as air humidity and temperature.

Water droplet evaporation from sticky superhydrophobic surfaces

Science.gov (United States)

Lee, Moonchan; Kim, Wuseok; Lee, Sanghee; Baek, Seunghyeon; Yong, Kijung; Jeon, Sangmin

2017-07-01

The evaporation dynamics of water from sticky superhydrophobic surfaces was investigated using a quartz crystal microresonator and an optical microscope. Anodic aluminum oxide (AAO) layers with different pore sizes were directly fabricated onto quartz crystal substrates and hydrophobized via chemical modification. The resulting AAO layers exhibited hydrophobic or superhydrophobic characteristics with strong adhesion to water due to the presence of sealed air pockets inside the nanopores. After placing a water droplet on the AAO membranes, variations in the resonance frequency and Q-factor were measured throughout the evaporation process, which were related to changes in mass and viscous damping, respectively. It was found that droplet evaporation from a sticky superhydrophobic surface followed a constant contact radius (CCR) mode in the early stage of evaporation and a combination of CCR and constant contact angle modes without a Cassie-Wenzel transition in the final stage. Furthermore, AAO membranes with larger pore sizes exhibited longer evaporation times, which were attributed to evaporative cooling at the droplet interface.

Wetting and evaporation of binary mixture drops.

Science.gov (United States)

Sefiane, Khellil; David, Samuel; Shanahan, Martin E R

2008-09-11

Experimental results on the wetting behavior of water, methanol, and binary mixture sessile drops on a smooth, polymer-coated substrate are reported. The wetting behavior of evaporating water/methanol drops was also studied in a water-saturated environment. Drop parameters (contact angle, shape, and volume) were monitored in time. The effects of the initial relative concentrations on subsequent evaporation and wetting dynamics were investigated. Physical mechanisms responsible for the various types of wetting behavior during different stages are proposed and discussed. Competition between evaporation and hydrodynamic flow are evoked. Using an environment saturated with water vapor allowed further exploration of the controlling mechanisms and underlying processes. Wetting stages attributed to differential evaporation of methanol were identified. Methanol, the more volatile component, evaporates predominantly in the initial stage. The data, however, suggest that a small proportion of methanol remained in the drop after the first stage of evaporation. This residual methanol within the drop seems to influence subsequent wetting behavior strongly.

Snap evaporation of droplets on smooth topographies.

Science.gov (United States)

Wells, Gary G; Ruiz-Gutiérrez, Élfego; Le Lirzin, Youen; Nourry, Anthony; Orme, Bethany V; Pradas, Marc; Ledesma-Aguilar, Rodrigo

2018-04-11

Droplet evaporation on solid surfaces is important in many applications including printing, micro-patterning and cooling. While seemingly simple, the configuration of evaporating droplets on solids is difficult to predict and control. This is because evaporation typically proceeds as a "stick-slip" sequence-a combination of pinning and de-pinning events dominated by static friction or "pinning", caused by microscopic surface roughness. Here we show how smooth, pinning-free, solid surfaces of non-planar topography promote a different process called snap evaporation. During snap evaporation a droplet follows a reproducible sequence of configurations, consisting of a quasi-static phase-change controlled by mass diffusion interrupted by out-of-equilibrium snaps. Snaps are triggered by bifurcations of the equilibrium droplet shape mediated by the underlying non-planar solid. Because the evolution of droplets during snap evaporation is controlled by a smooth topography, and not by surface roughness, our ideas can inspire programmable surfaces that manage liquids in heat- and mass-transfer applications.

Simultaneous spreading and evaporation: recent developments.

Science.gov (United States)

Semenov, Sergey; Trybala, Anna; Rubio, Ramon G; Kovalchuk, Nina; Starov, Victor; Velarde, Manuel G

2014-04-01

The recent progress in theoretical and experimental studies of simultaneous spreading and evaporation of liquid droplets on solid substrates is discussed for pure liquids including nanodroplets, nanosuspensions of inorganic particles (nanofluids) and surfactant solutions. Evaporation of both complete wetting and partial wetting liquids into a nonsaturated vapour atmosphere are considered. However, the main attention is paid to the case of partial wetting when the hysteresis of static contact angle takes place. In the case of complete wetting the spreading/evaporation process proceeds in two stages. A theory was suggested for this case and a good agreement with available experimental data was achieved. In the case of partial wetting the spreading/evaporation of a sessile droplet of pure liquid goes through four subsequent stages: (i) the initial stage, spreading, is relatively short (1-2 min) and therefore evaporation can be neglected during this stage; during the initial stage the contact angle reaches the value of advancing contact angle and the radius of the droplet base reaches its maximum value, (ii) the first stage of evaporation is characterised by the constant value of the radius of the droplet base; the value of the contact angle during the first stage decreases from static advancing to static receding contact angle; (iii) during the second stage of evaporation the contact angle remains constant and equal to its receding value, while the radius of the droplet base decreases; and (iv) at the third stage of evaporation both the contact angle and the radius of the droplet base decrease until the drop completely disappears. It has been shown theoretically and confirmed experimentally that during the first and second stages of evaporation the volume of droplet to power 2/3 decreases linearly with time. The universal dependence of the contact angle during the first stage and of the radius of the droplet base during the second stage on the reduced time has been

Theory of evapotranspiration. 2. Soil and intercepted water evaporation

OpenAIRE

Budagovskyi, Anatolij Ivanovič; Novák, Viliam

2011-01-01

Evaporation of water from the soil is described and quantified. Formation of the soil dry surface layer is quantitatively described, as a process resulting from the difference between the evaporation and upward soil water flux to the soil evaporating level. The results of evaporation analysis are generalized even for the case of water evaporation from the soil under canopy and interaction between evaporation rate and canopy transpiration is accounted for. Relationships describing evapotranspi...

Sessile Drop Evaporation and Leidenfrost Phenomenon

OpenAIRE

A. K. Mozumder; M. R. Ullah; A. Hossain; M. A. Islam

2010-01-01

Problem statement: Quenching and cooling are important process in manufacturing industry for controlling the mechanical properties of materials, where evaporation is a vital mode of heat transfer. Approach: This study experimentally investigated the evaporation of sessile drop for four different heated surfaces of Aluminum, Brass, Copper and Mild steel with a combination of four different liquids as Methanol, Ethanol, Water and NaCl solution. The time of evaporation for the droplet on the hot...

How internal drainage affects evaporation dynamics from soil surfaces ?

Science.gov (United States)

Or, D.; Lehmann, P.; Sommer, M.

2017-12-01

Following rainfall, infiltrated water may be redistributed internally to larger depths or lost to the atmosphere by evaporation (and by plant uptake from depths at longer time scales). A large fraction of evaporative losses from terrestrial surfaces occurs during stage1 evaporation during which phase change occurs at the wet surface supplied by capillary flow from the soil. Recent studies have shown existence of a soil-dependent characteristic length below which capillary continuity is disrupted and a drastic shift to slower stage 2 evaporation ensues. Internal drainage hastens this transition and affect evaporative losses. To predict the transition to stage 2 and associated evaporative losses, we developed an analytical solution for evaporation dynamics with concurrent internal drainage. Expectedly, evaporative losses are suppressed when drainage is considered to different degrees depending on soil type and wetness. We observe that high initial water content supports rapid drainage and thus promotes the sheltering of soil water below the evaporation depth. The solution and laboratory experiments confirm nonlinear relationship between initial water content and total evaporative losses. The concept contributes to establishing bounds on regional surface evaporation considering rainfall characteristics and soil types.

Pick up screens for x-ray image intensifier tubes employing evaporated activated scintillator layer

International Nuclear Information System (INIS)

Spicer, W.E.

1976-01-01

The present invention relates in general to methods for making pick-up screens for x-ray image intensifier tubes and, more particularly, to an improved method wherein the x-ray fluorescent phosphor screen element is formed by evaporation of an alkali metal halide material in vacuum and condensing the evaporated material on an x-ray transparent portion of the x-ray intensifier tube, whereby a curved x-ray image pick-up screen is formed which has improved quantum efficiency and resolution. Such improved x-ray image intensifier tubes are especially useful for, but not limited in use to x-ray systems and for intensifying gamma ray images obtained in applications of nuclear medicine. 7 claims, 5 drawing figures

Portable brine evaporator unit, process, and system

Science.gov (United States)

Hart, Paul John; Miller, Bruce G.; Wincek, Ronald T.; Decker, Glenn E.; Johnson, David K.

2009-04-07

The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

Spacesuit Water Membrane Evaporator; An Enhanced Evaporative Cooling Systems for the Advanced Extravehicular Mobility Unit Portable Life Support System

Science.gov (United States)

Bue, Grant C.; Makinen, Janice V.; Miller, Sean.; Campbell, Colin; Lynch, Bill; Vogel, Matt; Craft, Jesse; Petty, Brian

2014-01-01

Spacesuit Water Membrane Evaporator - Baseline heat rejection technology for the Portable Life Support System of the Advanced EMU center dot Replaces sublimator in the current EMU center dot Contamination insensitive center dot Can work with Lithium Chloride Absorber Radiator in Spacesuit Evaporator Absorber Radiator (SEAR) to reject heat and reuse evaporated water The Spacesuit Water Membrane Evaporator (SWME) is being developed to replace the sublimator for future generation spacesuits. Water in LCVG absorbs body heat while circulating center dot Warm water pumped through SWME center dot SWME evaporates water vapor, while maintaining liquid water - Cools water center dot Cooled water is then recirculated through LCVG. center dot LCVG water lost due to evaporation (cooling) is replaced from feedwater The Independent TCV Manifold reduces design complexity and manufacturing difficulty of the SWME End Cap. center dot The offset motor for the new BPV reduces the volume profile of the SWME by laying the motor flat on the End Cap alongside the TCV.

Influence of organic films on the evaporation and condensation of water in aerosol.

Science.gov (United States)

Davies, James F; Miles, Rachael E H; Haddrell, Allen E; Reid, Jonathan P

2013-05-28

Uncertainties in quantifying the kinetics of evaporation and condensation of water from atmospheric aerosol are a significant contributor to the uncertainty in predicting cloud droplet number and the indirect effect of aerosols on climate. The influence of aerosol particle surface composition, particularly the impact of surface active organic films, on the condensation and evaporation coefficients remains ambiguous. Here, we report measurements of the influence of organic films on the evaporation and condensation of water from aerosol particles. Significant reductions in the evaporation coefficient are shown to result when condensed films are formed by monolayers of long-chain alcohols [C(n)H(2n+1)OH], with the value decreasing from 2.4 × 10(-3) to 1.7 × 10(-5) as n increases from 12 to 17. Temperature-dependent measurements confirm that a condensed film of long-range order must be formed to suppress the evaporation coefficient below 0.05. The condensation of water on a droplet coated in a condensed film is shown to be fast, with strong coherence of the long-chain alcohol molecules leading to islanding as the water droplet grows, opening up broad areas of uncoated surface on which water can condense rapidly. We conclude that multicomponent composition of organic films on the surface of atmospheric aerosol particles is likely to preclude the formation of condensed films and that the kinetics of water condensation during the activation of aerosol to form cloud droplets is likely to remain rapid.

Influence of organic films on the evaporation and condensation of water in aerosol

Science.gov (United States)

Davies, James F.; Miles, Rachael E. H.; Haddrell, Allen E.; Reid, Jonathan P.

2013-01-01

Uncertainties in quantifying the kinetics of evaporation and condensation of water from atmospheric aerosol are a significant contributor to the uncertainty in predicting cloud droplet number and the indirect effect of aerosols on climate. The influence of aerosol particle surface composition, particularly the impact of surface active organic films, on the condensation and evaporation coefficients remains ambiguous. Here, we report measurements of the influence of organic films on the evaporation and condensation of water from aerosol particles. Significant reductions in the evaporation coefficient are shown to result when condensed films are formed by monolayers of long-chain alcohols [CnH(2n+1)OH], with the value decreasing from 2.4 × 10−3 to 1.7 × 10−5 as n increases from 12 to 17. Temperature-dependent measurements confirm that a condensed film of long-range order must be formed to suppress the evaporation coefficient below 0.05. The condensation of water on a droplet coated in a condensed film is shown to be fast, with strong coherence of the long-chain alcohol molecules leading to islanding as the water droplet grows, opening up broad areas of uncoated surface on which water can condense rapidly. We conclude that multicomponent composition of organic films on the surface of atmospheric aerosol particles is likely to preclude the formation of condensed films and that the kinetics of water condensation during the activation of aerosol to form cloud droplets is likely to remain rapid. PMID:23674675

Control of black hole evaporation?

International Nuclear Information System (INIS)

Ahn, Doyeol

2007-01-01

Contradiction between Hawking's semi-classical arguments and the string theory on the evaporation of a black hole has been one of the most intriguing problems in fundamental physics. A final-state boundary condition inside the black hole was proposed by Horowitz and Maldacena to resolve this contradiction. We point out that the original Hawking effect can also be regarded as a separate boundary condition at the event horizon for this scenario. Here, we found that the change of the Hawking boundary condition may affect the information transfer from the initial collapsing matter to the outgoing Hawking radiation during the evaporation process and as a result the evaporation process itself, significantly

Interfacial Instabilities in Evaporating Drops

Science.gov (United States)

Moffat, Ross; Sefiane, Khellil; Matar, Omar

2007-11-01

We study the effect of substrate thermal properties on the evaporation of sessile drops of various liquids. An infra-red imaging technique was used to record the interfacial temperature. This technique illustrates the non-uniformity in interfacial temperature distribution that characterises the evaporation process. Our results also demonstrate that the evaporation of methanol droplets is accompanied by the formation of wave-trains in the interfacial temperature field; similar patterns, however, were not observed in the case of water droplets. More complex patterns are observed for FC-72 refrigerant drops. The effect of substrate thermal conductivity on the structure of the complex pattern formation is also elucidated.

Advanced evaporator technology progress report FY 1992

Energy Technology Data Exchange (ETDEWEB)

Chamberlain, D.; Hutter, J.C.; Leonard, R.A. [and others

1995-01-01

This report summarizes the work that was completed in FY 1992 on the program {open_quotes}Technology Development for Concentrating Process Streams.{close_quotes} The purpose of this program is to evaluate and develop evaporator technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process. Concentrating these streams and minimizing the volume of waste generated can significantly reduce disposal costs; however, equipment to concentrate the streams and recycle the decontaminated condensates must be installed. LICON, Inc., is developing an evaporator that shows a great deal of potential for this application. In this report, concepts that need to be incorporated into the design of an evaporator operated in a radioactive environment are discussed. These concepts include criticality safety, remote operation and maintenance, and materials of construction. Both solubility and vapor-liquid equilibrium data are needed to design an effective process for concentrating process streams. Therefore, literature surveys were completed and are summarized in this report. A model that is being developed to predict vapor phase compositions is described. A laboratory-scale evaporator was purchased and installed to study the evaporation process and to collect additional data. This unit is described in detail. Two new LICON evaporators are being designed for installation at Argonne-East in FY 1993 to process low-level radioactive waste generated throughout the laboratory. They will also provide operating data from a full-sized evaporator processing radioactive solutions. Details on these evaporators are included in this report.

Advanced evaporator technology progress report FY 1992

International Nuclear Information System (INIS)

Chamberlain, D.; Hutter, J.C.; Leonard, R.A.

1995-01-01

This report summarizes the work that was completed in FY 1992 on the program open-quotes Technology Development for Concentrating Process Streams.close quotes The purpose of this program is to evaluate and develop evaporator technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process. Concentrating these streams and minimizing the volume of waste generated can significantly reduce disposal costs; however, equipment to concentrate the streams and recycle the decontaminated condensates must be installed. LICON, Inc., is developing an evaporator that shows a great deal of potential for this application. In this report, concepts that need to be incorporated into the design of an evaporator operated in a radioactive environment are discussed. These concepts include criticality safety, remote operation and maintenance, and materials of construction. Both solubility and vapor-liquid equilibrium data are needed to design an effective process for concentrating process streams. Therefore, literature surveys were completed and are summarized in this report. A model that is being developed to predict vapor phase compositions is described. A laboratory-scale evaporator was purchased and installed to study the evaporation process and to collect additional data. This unit is described in detail. Two new LICON evaporators are being designed for installation at Argonne-East in FY 1993 to process low-level radioactive waste generated throughout the laboratory. They will also provide operating data from a full-sized evaporator processing radioactive solutions. Details on these evaporators are included in this report

Steady Method for the Analysis of Evaporation Dynamics.

Science.gov (United States)

Günay, A Alperen; Sett, Soumyadip; Oh, Junho; Miljkovic, Nenad

2017-10-31

Droplet evaporation is an important phenomenon governing many man-made and natural processes. Characterizing the rate of evaporation with high accuracy has attracted the attention of numerous scientists over the past century. Traditionally, researchers have studied evaporation by observing the change in the droplet size in a given time interval. However, the transient nature coupled with the significant mass-transfer-governed gas dynamics occurring at the droplet three-phase contact line makes the classical method crude. Furthermore, the intricate balance played by the internal and external flows, evaporation kinetics, thermocapillarity, binary-mixture dynamics, curvature, and moving contact lines makes the decoupling of these processes impossible with classical transient methods. Here, we present a method to measure the rate of evaporation of spatially and temporally steady droplets. By utilizing a piezoelectric dispenser to feed microscale droplets (R ≈ 9 μm) to a larger evaporating droplet at a prescribed frequency, we can both create variable-sized droplets on any surface and study their evaporation rate by modulating the piezoelectric droplet addition frequency. Using our steady technique, we studied water evaporation of droplets having base radii ranging from 20 to 250 μm on surfaces of different functionalities (45° ≤ θ a,app ≤ 162°, where θ a,app is the apparent advancing contact angle). We benchmarked our technique with the classical unsteady method, showing an improvement of 140% in evaporation rate measurement accuracy. Our work not only characterizes the evaporation dynamics on functional surfaces but also provides an experimental platform to finally enable the decoupling of the complex physics governing the ubiquitous droplet evaporation process.

Design and operation of evaporators for radioactive wastes

Energy Technology Data Exchange (ETDEWEB)

Yamomoto, Y [comp.; Tokyo Univ. (Japan)

1968-05-01

A manual dealing with the application of evaporators to the treatment of liquid radioactive wastes. This book is the second of three commissioned by the IAEA on the three on the three principal techniques for concentrating radioactive wastes, namely chemical precipitation, evaporation and ion-exchange. Informations on different types of evaporators and related equipment and their operational procedures are given in this document. It also gives different means of disposal of evaporator condensates and concentrates and a rough estimate of costs of radioactive waste evaporator plant and its operation. 58 refs, 43 figs, 5 tabs.

Design and operation of evaporators for radioactive wastes

International Nuclear Information System (INIS)

Yamomoto, Y.

1968-01-01

A manual dealing with the application of evaporators to the treatment of liquid radioactive wastes. This book is the second of three commissioned by the IAEA on the three on the three principal techniques for concentrating radioactive wastes, namely chemical precipitation, evaporation and ion-exchange. Informations on different types of evaporators and related equipment and their operational procedures are given in this document. It also gives different means of disposal of evaporator condensates and concentrates and a rough estimate of costs of radioactive waste evaporator plant and its operation. 58 refs, 43 figs, 5 tabs

Low-temperature field evaporation of Nb3Sn compound

International Nuclear Information System (INIS)

Ksenofontov, V.A.; Kul'ko, V.B.; Kutsenko, P.A.

1986-01-01

Investigation results on field evaporation of superconducting Nb 3 Sn compound wth A15 lattice are presented. Compound evaporation is shown to proceed in two stages. Evaporation field and ionic composition of evaporating material are determined. It is found out that in strong electric fields compound surface represents niobium skeleton, wich does not form regular image. Comparison of ion-microscopic and calculated images formed by low-temperature field evaporation indicates to possibility of sample surface reconstruction after preferable tin evaporation

Evaporation of nanofluid droplet on heated surface

Directory of Open Access Journals (Sweden)

Yeung Chan Kim

2015-04-01

Full Text Available In this study, an experiment on the evaporation of nanofluid sessile droplet on a heated surface was conducted. A nanofluid of 0.5% volumetric concentration mixed with 80-nm-sized CuO powder and pure water were used for experiment. Droplet was applied to the heated surface, and images of the evaporation process were obtained. The recorded images were analyzed to find the volume, diameter, and contact angle of the droplet. In addition, the evaporative heat transfer coefficient was calculated from experimental result. The results of this study are summarized as follows: the base diameter of the droplet was maintained stably during the evaporation. The measured temperature of the droplet was increased rapidly for a very short time, then maintained constantly. The nanofluid droplet was evaporated faster than the pure water droplet under the experimental conditions of the same initial volume and temperature, and the average evaporative heat transfer coefficient of the nanofluid droplet was higher than that of pure water. We can consider the effects of the initial contact angle and thermal conductivity of nanofluid as the reason for this experimental result. However, the effect of surface roughness on the evaporative heat transfer of nanofluid droplet appeared unclear.

Evaporation rate-based selection of supramolecular chirality.

Science.gov (United States)

Hattori, Shingo; Vandendriessche, Stefaan; Koeckelberghs, Guy; Verbiest, Thierry; Ishii, Kazuyuki

2017-03-09

We demonstrate the evaporation rate-based selection of supramolecular chirality for the first time. P-type aggregates prepared by fast evaporation, and M-type aggregates prepared by slow evaporation are kinetic and thermodynamic products under dynamic reaction conditions, respectively. These findings provide a novel solution reaction chemistry under the dynamic reaction conditions.

High-rate reactive deposition of transparent SiO.sub.2./sub. films containing low amount of Zr from molten magnetron target

Czech Academy of Sciences Publication Activity Database

Musil, Jindřich; Satava, V.; Baroch, P.

2010-01-01

Roč. 519, č. 2 (2010), s. 775-777 ISSN 0040-6090 Institutional research plan: CEZ:AV0Z10100520 Keywords : sputtering * evaporation * reactive deposition * target power density Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.909, year: 2010

A remote sensing method for estimating regional reservoir area and evaporative loss

Science.gov (United States)

Zhang, Hua; Gorelick, Steven M.; Zimba, Paul V.; Zhang, Xiaodong

2017-12-01

Evaporation from the water surface of a reservoir can significantly affect its function of ensuring the availability and temporal stability of water supply. Current estimations of reservoir evaporative loss are dependent on water area derived from a reservoir storage-area curve. Such curves are unavailable if the reservoir is located in a data-sparse region or questionable if long-term sedimentation has changed the original elevation-area relationship. We propose a remote sensing framework to estimate reservoir evaporative loss at the regional scale. This framework uses a multispectral water index to extract reservoir area from Landsat imagery and estimate monthly evaporation volume based on pan-derived evaporative rates. The optimal index threshold is determined based on local observations and extended to unobserved locations and periods. Built on the cloud computing capacity of the Google Earth Engine, this framework can efficiently analyze satellite images at large spatiotemporal scales, where such analysis is infeasible with a single computer. Our study involves 200 major reservoirs in Texas, captured in 17,811 Landsat images over a 32-year period. The results show that these reservoirs contribute to an annual evaporative loss of 8.0 billion cubic meters, equivalent to 20% of their total active storage or 53% of total annual water use in Texas. At five coastal basins, reservoir evaporative losses exceed the minimum freshwater inflows required to sustain ecosystem health and fishery productivity of the receiving estuaries. Reservoir evaporative loss can be significant enough to counterbalance the positive effects of impounding water and to offset the contribution of water conservation and reuse practices. Our results also reveal the spatially variable performance of the multispectral water index and indicate the limitation of using scene-level cloud cover to screen satellite images. This study demonstrates the advantage of combining satellite remote sensing and

Urban evaporation rates for water-permeable pavements.

Science.gov (United States)

Starke, P; Göbel, P; Coldewey, W G

2010-01-01

In urban areas the natural water balance is disturbed. Infiltration and evaporation are reduced, resulting in a high surface runoff and a typical city climate, which can lead to floods and damages. Water-permeable pavements have a high infiltration rate that reduces surface runoff by increasing the groundwater recharge. The high water retention capacity of the street body of up to 51 l/m(2) and its connection via pores to the surface lead to higher evaporation rates than impermeable surfaces. A comparison of these two kinds of pavements shows a 16% increase in evaporation levels of water-permeable pavements. Furthermore, the evaporation from impermeable pavements is linked directly to rain events due to fast-drying surfaces. Water-permeable pavements show a more evenly distributed evaporation after a rain event. Cooling effects by evaporative heat loss can improve the city climate even several days after rain events. On a large scale use, uncomfortable weather like sultriness or dry heat can be prevented and the urban water balance can be attenuated towards the natural.

Estimating soil water evaporation using radar measurements

Science.gov (United States)

Sadeghi, Ali M.; Scott, H. D.; Waite, W. P.; Asrar, G.

1988-01-01

Field studies were conducted to evaluate the application of radar reflectivity as compared with the shortwave reflectivity (albedo) used in the Idso-Jackson equation for the estimation of daily evaporation under overcast sky and subhumid climatic conditions. Soil water content, water potential, shortwave and radar reflectivity, and soil and air temperatures were monitored during three soil drying cycles. The data from each cycle were used to calculate daily evaporation from the Idso-Jackson equation and from two other standard methods, the modified Penman and plane of zero-flux. All three methods resulted in similar estimates of evaporation under clear sky conditions; however, under overcast sky conditions, evaporation fluxes computed from the Idso-Jackson equation were consistently lower than the other two methods. The shortwave albedo values in the Idso-Jackson equation were then replaced with radar reflectivities and a new set of total daily evaporation fluxes were calculated. This resulted in a significant improvement in computed soil evaporation fluxes from the Idso-Jackson equation, and a better agreement between the three methods under overcast sky conditions.

Systematics of evaporation

International Nuclear Information System (INIS)

Klots, C.E.

1991-01-01

Beginning with rather basic principles, general relations are obtained for evaporative rate constants. These are established both as a function of energy and of temperature. In parallel with this, expressions are developed for the kinetic energy distribution of the separating species. Explicit evaluation of the rate constants in the case of 'chemical' evaporation from an entity containing n monomeric units yields as a typical result k(T)(s -1 )=3.10 13 n 2/3 exp[6/n 1/3 ]exp(-ΔE a (n)/k B T). Experimental evidence in support of this relation is cited. Applications to thermionic emission are also noted. (orig.)

Validation of a simple evaporation-transpiration scheme (SETS) to estimate evaporation using micro-lysimeter measurements

Science.gov (United States)

Ghazanfari, Sadegh; Pande, Saket; Savenije, Hubert

2014-05-01

Several methods exist to estimate E and T. The Penman-Montieth or Priestly-Taylor methods along with the Jarvis scheme for estimating vegetation resistance are commonly used to estimate these fluxes as a function of land cover, atmospheric forcing and soil moisture content. In this study, a simple evaporation transpiration method is developed based on MOSAIC Land Surface Model that explicitly accounts for soil moisture. Soil evaporation and transpiration estimated by SETS is validated on a single column of soil profile with measured evaporation data from three micro-lysimeters located at Ferdowsi University of Mashhad synoptic station, Iran, for the year 2005. SETS is run using both implicit and explicit computational schemes. Results show that the implicit scheme estimates the vapor flux close to that by the explicit scheme. The mean difference between the implicit and explicit scheme is -0.03 mm/day. The paired T-test of mean difference (p-Value = 0.042 and t-Value = 2.04) shows that there is no significant difference between the two methods. The sum of soil evaporation and transpiration from SETS is also compared with P-M equation and micro-lysimeters measurements. The SETS predicts the actual evaporation with a lower bias (= 1.24mm/day) than P-M (= 1.82 mm/day) and with R2 value of 0.82.

300 area solvent evaporator interim status closure plan: Revision 2

International Nuclear Information System (INIS)

1989-02-01

This document describes activities for the closure of a hazardous waste tank treatment facility operated by the US Department of Energy-Richland Operations Office (DOE-RL) and co-operated by the Westinghouse Hanford Company (WHC). This treatment facility was a solvent evaporator located in the 300 Area of the Hanford Site, from 1975 to 1985 on behalf of DOE-RL. The 300 Area Solvent Evaporator (300 ASE) was a modified load lugger (dumpster) in which solvent wastes were evaporated. Some of the solvents were radioactively contaminated because they came from a degreaser which processed bare uranium metal billets from the N Reactor Fuel Manufacturing Facility. The waste was composed of perchloroethylene, trichloroethylene, 1,1,1-trichloroethane, ethyl acetate/bromine solution, paint shop solvents and possibly some used oil. Also, small amounts of uranium, copper, zirconium and possibly beryllium were present in the degreaser solvents as particulates. Radioactive and non-radioactive solvents were not segregated in the 300 ASE, and the entire mixture was regarded as mixed waste

The continuous similarity model of bulk soil-water evaporation

Science.gov (United States)

Clapp, R. B.

1983-01-01

The continuous similarity model of evaporation is described. In it, evaporation is conceptualized as a two stage process. For an initially moist soil, evaporation is first climate limited, but later it becomes soil limited. During the latter stage, the evaporation rate is termed evaporability, and mathematically it is inversely proportional to the evaporation deficit. A functional approximation of the moisture distribution within the soil column is also included in the model. The model was tested using data from four experiments conducted near Phoenix, Arizona; and there was excellent agreement between the simulated and observed evaporation. The model also predicted the time of transition to the soil limited stage reasonably well. For one of the experiments, a third stage of evaporation, when vapor diffusion predominates, was observed. The occurrence of this stage was related to the decrease in moisture at the surface of the soil. The continuous similarity model does not account for vapor flow. The results show that climate, through the potential evaporation rate, has a strong influence on the time of transition to the soil limited stage. After this transition, however, bulk evaporation is independent of climate until the effects of vapor flow within the soil predominate.

Re-activation of degraded nickel cermet anodes - Nano-particle formation via reverse current pulses

Science.gov (United States)

Hauch, A.; Marchese, M.; Lanzini, A.; Graves, C.

2018-02-01

The Ni/yttria-stabilized-zirconia (YSZ) cermet is the most commonly applied fuel electrode for solid oxide cells (SOCs). Loss of Ni/YSZ electrode activity is a key life-time limiting factor of the SOC. Developing means to mitigate this loss of performance or re-activate a fuel electrode is therefore important. In this work, we report a series of five tests on state-of-the-art Ni/YSZ-YSZ-CGObarrier-LSC/CGO cells. All cells were deliberately degraded via gas stream impurities in CO2/CO or harsh steam electrolysis operation. The cells were re-activated via a variety of reverse current treatments (RCTs). Via electrochemical impedance spectroscopy, we found that the Ni/YSZ electrode performance could be recovered via RCT, but not via constant fuel cell operation. For optimized RCT, we obtained a lower Ni/YSZ electrode resistance than the initial resistance. E.g. at 700 °C we measured fuel electrode resistance of 180 mΩ cm2, 390 mΩ cm2, and 159 mΩ cm2 before degradation, after degradation and after re-activation via RCT, respectively. Post-test SEM revealed that the RCT led to formation of nano-particles in the fuel electrode. Besides the remarkable improvement, the results also showed that RCTs can weaken Ni/YSZ interfaces and the electrode/electrolyte interface. This indicates that finding an optimum RCT profile is crucial for achieving maximum benefit.

Lattice-Boltzmann simulations of droplet evaporation

KAUST Repository

Ledesma-Aguilar, Rodrigo; Vella, Dominic; Yeomans, Julia M.

2014-01-01

© the Partner Organisations 2014. We study the utility and validity of lattice-Boltzmann (LB) simulations to explore droplet evaporation driven by a concentration gradient. Using a binary-fluid lattice-Boltzmann algorithm based on Cahn-Hilliard dynamics, we study the evaporation of planar films and 3D sessile droplets from smooth solid surfaces. Our results show that LB simulations accurately reproduce the classical regime of quasi-static dynamics. Beyond this limit, we show that the algorithm can be used to explore regimes where the evaporative and diffusive timescales are not widely separated, and to include the effect of boundaries of prescribed driving concentration. We illustrate the method by considering the evaporation of a droplet from a solid surface that is chemically patterned with hydrophilic and hydrophobic stripes. This journal is

Lattice-Boltzmann simulations of droplet evaporation

KAUST Repository

Ledesma-Aguilar, Rodrigo

2014-09-04

© the Partner Organisations 2014. We study the utility and validity of lattice-Boltzmann (LB) simulations to explore droplet evaporation driven by a concentration gradient. Using a binary-fluid lattice-Boltzmann algorithm based on Cahn-Hilliard dynamics, we study the evaporation of planar films and 3D sessile droplets from smooth solid surfaces. Our results show that LB simulations accurately reproduce the classical regime of quasi-static dynamics. Beyond this limit, we show that the algorithm can be used to explore regimes where the evaporative and diffusive timescales are not widely separated, and to include the effect of boundaries of prescribed driving concentration. We illustrate the method by considering the evaporation of a droplet from a solid surface that is chemically patterned with hydrophilic and hydrophobic stripes. This journal is

High temperature evaporation of titanium, zirconium and hafnium carbides

International Nuclear Information System (INIS)

Gusev, A.I.; Rempel', A.A.

1991-01-01

Evaporation of cubic nonstoichiometric carbides of titanium, zirconium and hafnium in a comparatively low-temperature interval (1800-2700) with detailed crystallochemical sample certification is studied. Titanium carbide is characterized by the maximum evaporation rate: at T>2300 K it loses 3% of sample mass during an hour and at T>2400 K titanium carbide evaporation becomes extremely rapid. Zirconium and hafnium carbide evaporation rates are several times lower than titanium carbide evaporation rates at similar temperatures. Partial pressures of metals and carbon over the carbides studied are calculated on the base of evaporation rates

Spacesuit Evaporator-Absorber-Radiator (SEAR)

Science.gov (United States)

Hodgson, Ed; Izenson, Mike; Chan, Weibo; Bue, Grant C.

2012-01-01

For decades advanced spacesuit developers have pursued a regenerable, robust nonventing system for heat rejection. Toward this end, this paper investigates linking together two previously developed technologies, namely NASA s Spacesuit Water Membrane Evaporator (SWME), and Creare s Lithium Chloride Absorber Radiator (LCAR). Heat from a liquid cooled garment is transported to SWME that provides cooling through evaporation. This water vapor is then captured by solid LiCl in the LCAR with a high enthalpy of absorption, resulting in sufficient temperature lift to reject heat to space by radiation. After the sortie, the LCAR would be heated up and dried in a regenerator to drive off and recover the absorbed evaporant. A engineering development prototype was built and tested in vacuum conditions at a sink temperature of 250 K. The LCAR was able to stably reject 75 W over a 7-hour period. A conceptual design of a full-scale radiator is proposed. Excess heat rejection above 240 W would be accomplished through venting of the evaporant. Loop closure rates were predicted for various exploration environment scenarios.

Equilibrium evaporation behavior of polonium and its homologue tellurium in liquid lead-bismuth eutectic

International Nuclear Information System (INIS)

Ohno, Shuji; Miyahara, Shinya; Kurata, Yuji; Katsura, Ryoei; Yoshida, Shigeru

2006-01-01

Experimental study using the transpiration method investigates equilibrium evaporation behavior of radionuclide polonium ( 210 Po) generated and accumulated in liquid lead-bismuth eutectic (LBE) cooled nuclear systems. The experiment consists of two series of tests: preliminary evaporation tests for homologue element tellurium (Te) in LBE, and evaporation tests for 210 Po-accumulated LBE in which test specimens are prepared by neutron irradiation. The evaporation tests of Te in LBE provide the suggestion that Te exists in a chemical form of PbTe as well as the information for confirming the validity of technique and conditions of Po test. From the evaporation tests of 210 Po in LBE, we obtain fundamental data and empirical equations such as 210 Po vapor concentration in the gas phase, 210 Po partial vapor pressure, thermodynamic activity coefficients, and gas-liquid equilibrium partition coefficient of 210 Po in LBE in the temperature range from 450 to 750degC. Additionally, radioactivity concentration of 210 Po and 210m Bi vapor in a cover gas region of a typical LBE-cooled nuclear system is specifically estimated based on the obtained experimental results, and the importance of 210 Po evaporation behavior is quantitatively demonstrated. (author)

A microwave evaporation system for the waste treatment of radioactive animals

International Nuclear Information System (INIS)

Saito, Tomoo; Nishiyama, Yumiko; Hikita, Akio; Takaoka, Ayako; Nakamura, Aiko.

1979-01-01

A microwave evaporation system was developed for the waste treatment of animal wastes contaminated with tritium or carbon-14. The apparatus composed of a 2450 MHz microwave range, a cooling unit, a receiver, a 3 H and 14 C sampler, an evacuating system and an automatic controller unit gave satisfactory results. The extent of evaporation can be optionally controlled in the range of 80% to 100%. The maximum rate of evaporation under reduced pressure reaches 10 g of water per minute at 480 W high frequency power level and 12.5 g per minute at 600 W. The evaporation of water in the carcass weighing 1 kg is generally completed in about 1 hour, and the weight is reduced by approximately 70%. The distribution in the apparatus of tritium or carbon-14 released from carcass by the microwave evaporation was studied using such labelled compounds as [ 3 H] water, [6- 3 H] thymidine, [methyl- 3 H] thymidine, [2- 14 C] thymidine, [U- 14 C] glutamic acid, [U- 14 C] fructose and [U- 14 C] glucose. The difference in activity trapped by the cooler and sampler was observed between the case of aqueous solutions of labelled compounds and that of animals administered with the same labelled compounds. The reason for this difference probably lies in metabolism of labelled compounds or exchange of tritium atoms within the animal body. (author)

Fundamentals of evaporation and condensation phenomena

International Nuclear Information System (INIS)

Munir, Z.A.

1979-01-01

Fundamental relationships governing evaporation and condensation processes are reviewed. The terrace-ledge-kink (TLK) model is discussed in terms of atomic steps comprising growth and evaporation of crystals. Recent results in the field are described

Performance of evaporative condensers

Energy Technology Data Exchange (ETDEWEB)

Ettouney, Hisham M.; El-Dessouky, Hisham T.; Bouhamra, Walid; Al-Azmi, Bader

2001-07-01

Experimental investigation is conducted to study the performance of evaporative condensers/coolers. The analysis includes development of correlations for the external heat transfer coefficient and the system efficiency. The evaporative condenser includes two finned-tube heat exchangers. The system is designed to allow for operation of a single condenser, two condensers in parallel, and two condensers in series. The analysis is performed as a function of the water-to-air mass flow rate ratio (L/G) and the steam temperature. Also, comparison is made between the performance of the evaporative condenser and same device as an air-cooled condenser. Analysis of the collected data shows that the system efficiency increases at lower L/G ratios and higher steam temperatures. The system efficiency for various configurations for the evaporative condenser varies between 97% and 99%. Lower efficiencies are obtained for the air-cooled condenser, with values between 88% and 92%. The highest efficiency is found for the two condensers in series, followed by two condensers in parallel and then the single condenser. The parallel condenser configuration can handle a larger amount of inlet steam and can provide the required system efficiency and degree of subcooling. The correlation for the system efficiency gives a simple tool for preliminary system design. The correlation developed for the external heat transfer coefficient is found to be consistent with the available literature data. (Author)

Reactive Programming in Standard ML

OpenAIRE

Pucella, Riccardo

2004-01-01

Reactive systems are systems that maintain an ongoing interaction with their environment, activated by receiving input events from the environment and producing output events in response. Modern programming languages designed to program such systems use a paradigm based on the notions of instants and activations. We describe a library for Standard ML that provides basic primitives for programming reactive systems. The library is a low-level system upon which more sophisticated reactive behavi...

Study on Evaporation Characteristics of Bio-oil and its Compound Models

Directory of Open Access Journals (Sweden)

Tan Long

2014-05-01

Full Text Available In this study, bio-oil was analyzed by gas chromatography mass spectrometry (GC-MS, and the evaporation characteristics of bio-oil were studied at different heating rates (10, 20, and 30 °C/min from 35 °C to 250 °C by a thermal analyzer (TG-DSC. The TG-DSC results of bio-oil showed that the heat requirement of bio-oil during the evaporation process ranged from 2.072103 to 2.299103 J/g, and the bio-oil activation energy ranged from 1.22×104 to 3.34×104 J/mol. Moreover, four models with five compounds (methanol, water, ethanol, furfural, and phenol were established to study the bio-oil evaporation process. By comparing the TG-DSC results of bio-oil and its models at 30 °C/min, it was shown that the optimal model was model 2, which has the following chemical composition: methanol (27.10 wt.%, water (44.96 wt.%, ethanol (16.24 wt.%, furfural (4.40 wt.%, and phenol (7.30 wt.%. Model 2 exhibited a minimal relative error in dynamic parameters and characteristic curve parameters. The errors for activation energy of the TG, activation energy of the DSC, maximum endothermic rates, and the total of the heat absorption were 3.04%, 5.88%, 2.49%, and 1.06%, respectively.

STUDI EKSPERIMENTAL FALLING FILM EVAPORATOR PADA EVAPORASI NIRA KENTAL

Directory of Open Access Journals (Sweden)

Medya Ayunda Fitri

2016-06-01

Full Text Available Falling film evaporator is a constructed equipment for concentrating dilute solution that are sensitive to heat flowing form a thin film. This research aims to study the evaporation of cane juice concentrated with air flow on falling film evaporator and knowing evaporation rate occured in falling film evaporator used. In the process, cane juice from plant pumped to the falling film evaporator that used in this experiment. This research used concentrated cane juice and air flow rate for variables of this experiment. Cane juice flow from top of evaporator through distributor to form thin film and air flow from the bottom of evaporator. After that, temperatur of pipe wall, inlet and outlet temperature of cane juice and air were measured. This experiment concluded that the highest concentration of outlet solution is 59 brix for liquid flow rate 154 l/h and air flow rate 10 m3/h, and the other hand inlet solution concentration 51 brix. Optimum evaporation rate is 35 kg/m2.h for 51 brix and air flow rate 10 m3/h.

Mini-Membrane Evaporator for Contingency Spacesuit Cooling

Science.gov (United States)

Makinen, Janice V.; Bue, Grant C.; Campbell, Colin; Petty, Brian; Craft, Jesse; Lynch, William; Wilkes, Robert; Vogel, Matthew

2015-01-01

The next-generation Advanced Extravehicular Mobility Unit (AEMU) Portable Life Support System (PLSS) is integrating a number of new technologies to improve reliability and functionality. One of these improvements is the development of the Auxiliary Cooling Loop (ACL) for contingency crewmember cooling. The ACL is a completely redundant, independent cooling system that consists of a small evaporative cooler--the Mini Membrane Evaporator (Mini-ME), independent pump, independent feedwater assembly and independent Liquid Cooling Garment (LCG). The Mini-ME utilizes the same hollow fiber technology featured in the full-sized AEMU PLSS cooling device, the Spacesuit Water Membrane Evaporator (SWME), but Mini-ME occupies only approximately 25% of the volume of SWME, thereby providing only the necessary crewmember cooling in a contingency situation. The ACL provides a number of benefits when compared with the current EMU PLSS contingency cooling technology, which relies upon a Secondary Oxygen Vessel; contingency crewmember cooling can be provided for a longer period of time, more contingency situations can be accounted for, no reliance on a Secondary Oxygen Vessel (SOV) for contingency cooling--thereby allowing a reduction in SOV size and pressure, and the ACL can be recharged-allowing the AEMU PLSS to be reused, even after a contingency event. The first iteration of Mini-ME was developed and tested in-house. Mini-ME is currently packaged in AEMU PLSS 2.0, where it is being tested in environments and situations that are representative of potential future Extravehicular Activities (EVA's). The second iteration of Mini-ME, known as Mini-ME2, is currently being developed to offer more heat rejection capability. The development of this contingency evaporative cooling system will contribute to a more robust and comprehensive AEMU PLSS.

Evaporative water loss, relative water economy and evaporative partitioning of a heterothermic marsupial, the monito del monte (Dromiciops gliroides).

Science.gov (United States)

Withers, Philip C; Cooper, Christine E; Nespolo, Roberto F

2012-08-15

We examine here evaporative water loss, economy and partitioning at ambient temperatures from 14 to 33°C for the monito del monte (Dromiciops gliroides), a microbiotheriid marsupial found only in temperate rainforests of Chile. The monito's standard evaporative water loss (2.58 mg g(-1) h(-1) at 30°C) was typical for a marsupial of its body mass and phylogenetic position. Evaporative water loss was independent of air temperature below thermoneutrality, but enhanced evaporative water loss and hyperthermia were the primary thermal responses above the thermoneutral zone. Non-invasive partitioning of total evaporative water loss indicated that respiratory loss accounted for 59-77% of the total, with no change in respiratory loss with ambient temperature, but a small change in cutaneous loss below thermoneutrality and an increase in cutaneous loss in and above thermoneutrality. Relative water economy (metabolic water production/evaporative water loss) increased at low ambient temperatures, with a point of relative water economy of 15.4°C. Thermolability had little effect on relative water economy, but conferred substantial energy savings at low ambient temperatures. Torpor reduced total evaporative water loss to as little as 21% of normothermic values, but relative water economy during torpor was poor even at low ambient temperatures because of the relatively greater reduction in metabolic water production than in evaporative water loss. The poor water economy of the monito during torpor suggests that negative water balance may explain why hibernators periodically arouse to normothermia, to obtain water by drinking or via an improved water economy.

Decomposition of thermally unstable substances in film evaporators

Energy Technology Data Exchange (ETDEWEB)

Matz, G

1982-10-01

It is widely known that film evaporators are considered to permit really gentle evaporation of heat-sensitive substances. Nevertheless, decomposition of such substance still occurs to an extent depending upon the design and operation of the evaporator. In the following a distinction is made between evaporators with films not generated mechanically, namely the long tube evaporator (lTE) or climbing film evaporator, the falling film evaporator (FFE) and the multiple phase helical tube (MPT) or helical coil evaporators (TFE). Figs 1 and 2 illustrate the mode of operation. A theory of the decomposition of thermally unstable substances in these evaporators is briefly outlined and compared with measurements. Such a theory cannot be developed without any experimental checks; on the other hand, meausrements urgently need a theoretical basis if only to establish what actually has to be measured. All experiments are made with a system of readily adjustable decomposability, namely with aqueous solutions of saccharose; the thermal inversion of this compound can be controlled by addition of various amounts or concentrations of hydrochloric acid. In the absence of any catalysis by hydrochloric acid, the decomposition rates within in the temperature interval studied (60-130/sup 0/C) are so low that the experiments would take much too long and determination of the concentration differences (generally by polarimetric methods) would be very complicated. Such slight effects would also be very unfavourable for comparison with theory. (orig.)

Prediction of water droplet evaporation on zircaloy surface

International Nuclear Information System (INIS)

Lee, Chi Young; In, Wang Kee

2014-01-01

In the present experimental study, the prediction of water droplet evaporation on a zircaloy surface was investigated using various initial droplet sizes. To the best of our knowledge, this may be the first valuable effort for understanding the details of water droplet evaporation on a zircaloy surface. The initial contact diameters of the water droplets tested ranged from 1.76 to 3.41 mm. The behavior (i.e., time-dependent droplet volume, contact angle, droplet height, and contact diameter) and mode-transition time of the water droplet evaporation were strongly influenced by the initial droplet size. Using the normalized contact angle (θ*) and contact diameter (d*), the transitions between evaporation modes were successfully expressed by a single curve, and their criteria were proposed. To predict the temporal droplet volume change and evaporation rate, the range of θ* > 0.25 and d* > 0.9, which mostly covered the whole evaporation period and the initial contact diameter remained almost constant during evaporation, was targeted. In this range, the previous contact angle functions for the evaporation model underpredicted the experimental data. A new contact angle function of a zircaloy surface was empirically proposed, which represented the present experimental data within a reasonable degree of accuracy. (author)

Multilayer composite material and method for evaporative cooling

Science.gov (United States)

Buckley, Theresa M. (Inventor)

2002-01-01

A multilayer composite material and method for evaporative cooling of a person employs an evaporative cooling liquid that changes phase from a liquid to a gaseous state to absorb thermal energy. The evaporative cooling liquid is absorbed into a superabsorbent material enclosed within the multilayer composite material. The multilayer composite material has a high percentage of the evaporative cooling liquid in the matrix. The cooling effect can be sustained for an extended period of time because of the high percentage of phase change liquid that can be absorbed into the superabsorbent. Such a composite can be used for cooling febrile patients by evaporative cooling as the evaporative cooling liquid in the matrix changes from a liquid to a gaseous state to absorb thermal energy. The composite can be made with a perforated barrier material around the outside to regulate the evaporation rate of the phase change liquid. Alternatively, the composite can be made with an imperveous barrier material or semipermeable membrane on one side to prevent the liquid from contacting the person's skin. The evaporative cooling liquid in the matrix can be recharged by soaking the material in the liquid. The multilayer composite material can be fashioned into blankets, garments and other articles.

How a gold substrate can increase the reactivity of a Pt overlayer

DEFF Research Database (Denmark)

Pedersen, Morten Ø.; Helveg, Stig; Ruban, Andrei

1999-01-01

The growth and chemical reactivity of Pt on Au(111) have been studied using scanning tunneling microscopy (STM) and temperature programmed desorption (TPD). Deposition of Pt at coverages from 0.02 ML up to 2.5 ML on Au(111) at room temperature initially leads to the formation of a surface alloy......, in which 3% of the Au atoms are replaced by Pt. Subsequent Pt evaporation leads to island growth with a mixed Pt-Au island composition. The reactivity of the Pt/Au system is studied using CO as a probe molecule. We show that a stronger bonding of CO to the first layer of Pt on Au(111) exists compared...... with the binding of CO on clean Pt. The Au substrate therefore very surprisingly increases the Pt overlayer reactivity. The results can be understood in a simple model, in which the change in the CO binding energy is directly proportional to the shift of the d-band center of the metal overlayer. According...

Safety mechanism for evaporations apparatus for radioactive liquids

International Nuclear Information System (INIS)

1975-01-01

The apparatus works as two step evaporator preferably using evaporation by expansion. The vapor coming from the first evaporation step is condensed in a mixed condenser which is fed over a circulating pump with a part of the liquid of the second step. The resulting mixture is then led to the second evaporation step. According to the invention between the first step vapor pipe and the mixed condensor there is arranged a flow regulator which causes a drop in pressure corresponding to the pressure difference between the first and second evaporation step, if the vapor flow is above normal operation but still admissible. (P.K.)

Cortical Regions Recruited for Complex Active-Learning Strategies and Action Planning Exhibit Rapid Reactivation during Memory Retrieval

Science.gov (United States)

Voss, Joel L.; Galvan, Ashley; Gonsalves, Brian D.

2011-01-01

Memory retrieval can involve activity in the same sensory cortical regions involved in perception of the original event, and this neural "reactivation" has been suggested as an important mechanism of memory retrieval. However, it is still unclear if fragments of experience other than sensory information are retained and later reactivated during…

Evaporation of petroleum products from contaminated soils

International Nuclear Information System (INIS)

Kang, S.H.

1996-01-01

Bioremediation can remove petroleum products from soil that has been contaminated by leaking underground storage tanks, but abiotic processes such as evaporation can contribute significantly to the overall removal process. The mathematical model described in this paper was developed to predict the evaporation rate of volatile liquids from petroleum-contaminated sand. The model is based on simple concepts relating to molecular diffusion embodied in the theory underlying the estimation of binary diffusivities using measurements made with an Arnold diffusion cell. The model in its simplified form indicates that the rate of evaporation for a particular volatile liquid is proportional to the square root of the product of diffusivity and partial pressure divided by the molecular weight of the liquid. This in part explains why evaporative losses from sand are so much higher for gasoline than for diesel fuel. The model also shows that the time for evaporation is directly proportional to the square of the depth dried out and inversely proportional to the vapor pressure of the volatile liquid. The model was tested using gravimetric measurements of the evaporation of n-heptane, unleaded gasoline, and diesel fuel from sand under laboratory conditions

Arsenite activates NFκB through induction of C-reactive protein

International Nuclear Information System (INIS)

Druwe, Ingrid L.; Sollome, James J.; Sanchez-Soria, Pablo; Hardwick, Rhiannon N.; Camenisch, Todd D.; Vaillancourt, Richard R.

2012-01-01

C-reactive protein (CRP) is an acute phase protein in humans. Elevated levels of CRP are produced in response to inflammatory cytokines and are associated with atherosclerosis, hypertension, cardiovascular disease and insulin resistance. Exposure to inorganic arsenic, a common environmental toxicant, also produces cardiovascular disorders, namely atherosclerosis and is associated with insulin-resistance. Inorganic arsenic has been shown to contribute to cardiac toxicities through production of reactive oxygen species (ROS) that result in the activation of NFκB. In this study we show that exposure of the hepatic cell line, HepG2, to environmentally relevant levels of arsenite (0.13 to 2 μM) results in elevated CRP expression and secretion. ROS analysis of the samples showed that a minimal amount of ROS are produced by HepG2 cells in response to these concentrations of arsenic. In addition, treatment of FvB mice with 100 ppb sodium arsenite in the drinking water for 6 months starting at weaning age resulted in dramatically higher levels of CRP in both the liver and inner medullary region of the kidney. Further, mouse Inner Medullary Collecting Duct cells (mIMCD-4), a mouse kidney cell line, were stimulated with 10 ng/ml CRP which resulted in activation of NFκB. Pretreatment with 10 nM Y27632, a known Rho-kinase inhibitor, prior to CRP exposure attenuated NFκB activation. These data suggest that arsenic causes the expression and secretion of CRP and that CRP activates NFκB through activation of the Rho-kinase pathway, thereby providing a novel pathway by which arsenic can contribute to metabolic syndrome and cardiovascular disease. -- Highlights: ► Exposure to arsenic can induce the expression and secretion of CRP. ► Mice treated with NaAsO 2 showed higher levels of CRP in both the liver and kidney. ► mIMCD-3 were stimulated with CRP which resulted in activation of NFκB. ► CRP activates NFκB through activation of the Rho-kinase pathway. ► Data provide

Arsenite activates NFκB through induction of C-reactive protein

Energy Technology Data Exchange (ETDEWEB)

Druwe, Ingrid L.; Sollome, James J.; Sanchez-Soria, Pablo; Hardwick, Rhiannon N.; Camenisch, Todd D.; Vaillancourt, Richard R., E-mail: vaillancourt@pharmacy.arizona.edu

2012-06-15

C-reactive protein (CRP) is an acute phase protein in humans. Elevated levels of CRP are produced in response to inflammatory cytokines and are associated with atherosclerosis, hypertension, cardiovascular disease and insulin resistance. Exposure to inorganic arsenic, a common environmental toxicant, also produces cardiovascular disorders, namely atherosclerosis and is associated with insulin-resistance. Inorganic arsenic has been shown to contribute to cardiac toxicities through production of reactive oxygen species (ROS) that result in the activation of NFκB. In this study we show that exposure of the hepatic cell line, HepG2, to environmentally relevant levels of arsenite (0.13 to 2 μM) results in elevated CRP expression and secretion. ROS analysis of the samples showed that a minimal amount of ROS are produced by HepG2 cells in response to these concentrations of arsenic. In addition, treatment of FvB mice with 100 ppb sodium arsenite in the drinking water for 6 months starting at weaning age resulted in dramatically higher levels of CRP in both the liver and inner medullary region of the kidney. Further, mouse Inner Medullary Collecting Duct cells (mIMCD-4), a mouse kidney cell line, were stimulated with 10 ng/ml CRP which resulted in activation of NFκB. Pretreatment with 10 nM Y27632, a known Rho-kinase inhibitor, prior to CRP exposure attenuated NFκB activation. These data suggest that arsenic causes the expression and secretion of CRP and that CRP activates NFκB through activation of the Rho-kinase pathway, thereby providing a novel pathway by which arsenic can contribute to metabolic syndrome and cardiovascular disease. -- Highlights: ► Exposure to arsenic can induce the expression and secretion of CRP. ► Mice treated with NaAsO{sub 2} showed higher levels of CRP in both the liver and kidney. ► mIMCD-3 were stimulated with CRP which resulted in activation of NFκB. ► CRP activates NFκB through activation of the Rho-kinase pathway. ► Data

Modelling evaporation from a drained and rewetted peatland

NARCIS (Netherlands)

Spieksma, J F M; Moors, EJ; Dolman, A J; Schouwenaars, J M

1997-01-01

Evaporation from a cutover raised bog in The Netherlands was modelled using a detailed, physically based evaporation model for heterogeneous vegetation and unsaturated soil water how ''SWAPS''. The model enables a quantification of the role of heterogeneity on evaporation. Micro-meteorological

Exploring the correlation between annual precipitation and potential evaporation

Science.gov (United States)

Chen, X.; Buchberger, S. G.

2017-12-01

The interdependence between precipitation and potential evaporation is closely related to the classic Budyko framework. In this study, a systematic investigation of the correlation between precipitation and potential evaporation at the annual time step is conducted at both point scale and watershed scale. The point scale precipitation and potential evaporation data over the period of 1984-2015 are collected from 259 weather stations across the United States. The watershed scale precipitation data of 203 watersheds across the United States are obtained from the Model Parameter Estimation Experiment (MOPEX) dataset from 1983 to 2002; and potential evaporation data of these 203 watersheds in the same period are obtained from a remote-sensing algorithm. The results show that majority of the weather stations (77%) and watersheds (79%) exhibit a statistically significant negative correlation between annual precipitation and annual potential evaporation. The aggregated data cloud of precipitation versus potential evaporation follows a curve based on the combination of the Budyko-type equation and Bouchet's complementary relationship. Our result suggests that annual precipitation and potential evaporation are not independent when both Budyko's hypothesis and Bouchet's hypothesis are valid. Furthermore, we find that the wet surface evaporation, which is controlled primarily by short wave radiation as defined in Bouchet's hypothesis, exhibits less dependence on precipitation than the potential evaporation. As a result, we suggest that wet surface evaporation is a better representation of energy supply than potential evaporation in the Budyko framework.

Water evaporation on highly viscoelastic polymer surfaces.

Science.gov (United States)

Pu, Gang; Severtson, Steven J

2012-07-03

Results are reported for a study on the evaporation of water droplets from a highly viscoelastic acrylic polymer surface. These are contrasted with those collected for the same measurements carried out on polydimethylsiloxane (PDMS). For PDMS, the evaporation process involves the expected multistep process including constant drop area, constant contact angle, and finally a combination of these steps until the liquid is gone. In contrast, water evaporation from the acrylic polymer shows a constant drop area mode throughout. Furthermore, during the evaporation process, the drop area actually expands on the acrylic polymer. The single mode evaporation process is consistent with formation of wetting structures, which cannot be propagated by the capillary forces. Expansion of the drop area is attributed to the influence of the drop capillary pressure. Furthermore, the rate of drop area expansion is shown to be dependent on the thickness of the polymer film.

Sodium evaporation into a forced argon flow

International Nuclear Information System (INIS)

Kumada, Toshiaki; Kasahara, Fumio; Ishiguro, Ryoji

1975-01-01

Evaporation from a rectangular sodium free surface into an argon flow was measured. Tests were carried out with varying sodium temperature, argon velocity and argon temperature respectively under conditions of fog formation being possible. In order to clarify the enhancement of evaporation by fog formation, convection heat transfer from a plate of the same geometry into an air flow was also measured. The evaporation rate and Sherwood number were compared with those predicted by both the heat transfer experiment and the theory proposed by Hill and Szekely, and also a comparison was run with the previously reported experimental results of sodium evaporation. As a result it was shown that the sodium evaporation rate in this experiment is at least four times as large as that predicted by the heat transfer experiment and varies almost linearly with the heat transfer rate and the sodium vapour pressure. (auth.)

Modeling black hole evaporation

CERN Document Server

Fabbri, Alessandro

2005-01-01

The scope of this book is two-fold: the first part gives a fully detailed and pedagogical presentation of the Hawking effect and its physical implications, and the second discusses the backreaction problem, especially in connection with exactly solvable semiclassical models that describe analytically the black hole evaporation process. The book aims to establish a link between the general relativistic viewpoint on black hole evaporation and the new CFT-type approaches to the subject. The detailed discussion on backreaction effects is also extremely valuable.

Activation of Reactive MALDI Adduct Ions Enables Differentiation of Dihydroxylated Vitamin D Isomers

Science.gov (United States)

Qi, Yulin; Müller, Miriam J.; Volmer, Dietrich A.

2017-12-01

Vitamin D compounds are secosteroids, which are best known for their role in bone health. More recent studies have shown that vitamin D metabolites and catabolites such as dihydroxylated species (e.g., 1,25- and 24,25-dihydroxyvitamin D3) play key roles in the pathologies of various diseases. Identification of these isomers by mass spectrometry is challenging and currently relies on liquid chromatography, as the isomers exhibit virtually identical product ion spectra under collision induced dissociation conditions. Here, we developed a simple MALDI-CID method that utilizes ion activation of reactive analyte/matrix adducts to distinguish isomeric dihydroxyvitamin D3 species, without the need for chromatography separation or chemical derivatization techniques. Specifically, reactive 1,5-diaminonaphthalene adducts of dihydroxyvitamin D3 compounds formed during MADI were activated and specific cleavages in the secosteroid's backbone structure were achieved that produced isomer-diagnostic fragment ions. [Figure not available: see fulltext.

The influence of chlorine on the fate and activity of alkali metals during the gasification of wood

Energy Technology Data Exchange (ETDEWEB)

Struis, R; Scala, C von; Schuler, A; Stucki, S [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

1999-08-01

Chlorine clearly inhibits the CO{sub 2}-gasification reaction of charcoal at 800{sup o}C. From this and other observations the picture emerges that the reduction in the gasification reactivity of the charcoal is intimately related to the deactivation of the catalytically active alkali metals residing in the wood due to the formation of the chloride salt. It is argued that the heavy metal chlorides will likely transfer the chlorine to the indigenous alkali metals during the pyrolysis stage of the wood. The fate of the thus formed alkali metal chlorides can then be either their removal from the sample (evaporation), or, when present at the gasification stage, re-activation (i.e., de-chlorination) under our gasification conditions. (author) 3 figs., 4 refs.

Experimental and theoretical investigation of an evaporative fuel system for heat engines

International Nuclear Information System (INIS)

Thern, Marcus; Lindquist, Torbjoern; Torisson, Tord

2007-01-01

The evaporative gas turbine (EvGT) pilot plant has been in operation at Lund University in Sweden since 1997. This project has led to improved knowledge of evaporative techniques and the concept of introducing fuel into gas turbines by evaporation. This results in, amongst others, power augmentation, efficiency increase and lower emissions. This article presents the experimental and theoretical results of the evaporation of a mixture of ethanol and water into an air stream at elevated pressures and temperatures. A theoretical model has been established for the simultaneous heat and mass transfer occurring in the ethanol humidification tower. The theoretical model has been validated through experiments at several operating conditions. It has been shown that the air, water and ethanol can be calculated throughout the column in a satisfactory way. The height of the column can be estimated within an error of 15% compared with measurements. The results from the model are most sensitive to the properties of diffusion coefficient, viscosity, thermal conductivity and activity coefficient due to the complexity of the polar gas mixture of water and air

Hydrothermal waves in evaporating sessile drops (APS 2009)

OpenAIRE

Brutin, D.; Rigollet, F.; LeNiliot, C.

2009-01-01

This fluid dynamics video was submitted to the Gallery of Fluid Motion for the 2009 APS Division of Fluid Dynamics Meeting in Minneapolis, Minnesota. Drop evaporation is a simple phenomena but still unclear concerning the mechanisms of evaporation. A common agreement of the scientific community based on experimental and numerical work evidences that most of the evaporation occurs at the triple line. However, the rate of evaporation is still empirically predicted due to the lack of knowledge o...

The Synthesis of Calcium Salt from Brine Water by Partial Evaporation and Chemical Precipitation

Science.gov (United States)

Lalasari, L. H.; Widowati, M. K.; Natasha, N. C.; Sulistiyono, E.; Prasetyo, A. B.

2017-02-01

In this study would be investigated the effects of partial evaporation and chemical precipitation in the formation of calcium salt from brine water resources. The chemical reagents used in the study was oxalate acid (C2H2O4), ammonium carbonate (NH4)2CO3) and ammonium hydroxide (NH4OH) with reagent concentration of 2 N, respectively. The procedure was 10 liters brine water evaporated until 20% volume and continued with filtration process to separate brine water filtrate from residue (salt). Salt resulted from evaporation process was characterized by Scanning Electron Microscopy (SEM), X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD) techniques. Filtrate then was reacted with C2H2O4, (NH4)2CO3 and NH4OH reagents to get salt products in atmospheric condition and variation ratio volume brine water/chemicals (v/v) [10/1; 10/5; 10/10; 10/20; 10/30; 10:50; 20/1; 20/5; 20/10; 20/20; 20/30; 20:50]. The salt product than were filtered, dried, measured weights and finally characterized by SEM/EDS and XRD techniques. The result of experiment showed the chemical composition of brine water from Tirta Sanita, Bogor was 28.87% Na, 9.17% Mg, 2.94% Ca, 22.33% O, 0.71% Sr, 30.02% Cl, 1.51% Si, 1.23% K, 0.55% S, 1.31% Al. The chemical composition of salt resulted by partial evaporation was 53.02% Ca, 28.93%O, 9.50% Na, 2.10% Mg, 1.53% Sr, 1.20% Cl, 1.10% Si, 0.63% K, 0.40% S, 0.39% Al. The salt resulted by total evaporation was indicated namely as NaCl. Whereas salt resulted by partial evaporation was CaCO3 with a purity of 90 % from High Score Plus analysis. In the experiment by chemical precipitation was reported that the reagents of ammonium carbonate were more reactive for synthesizing calcium salt from brine water compared to reagents of oxalate acid and ammonium hydroxide. The salts precipitated by NH4OH, (NH4)2CO3, and H2C2O4 reagents were indicated as NaCl, CaCO3 and CaC2O4.H2O, respectively. The techniques of partial evaporation until 20% volume sample of brine water and

Evaporation measurement in the validation drift - part 1

International Nuclear Information System (INIS)

Watanabe, Kunio

1991-01-01

Evaporation rate distribution over the wall surface of the validation drift was detaily mapped by using an equipment newly developed. The evaporation measurement was carried out to make clear the spatial variability of the inflow rate of groundwater seeping toward the tunnel. Air in the tunnel was warmed by an electric heater during the measurement period for reducing the relative humidity of air and for drying up the wall surface. Evaporation rates from rock matrix as well as from some major fractures were measured at about 500 points. Spatial distributions of evaporation rates over the tunnel wall were obtained under two different ventilation conditions. The average evaporation rates from the rock matrix of the wall were 0.29-0.35 mg/m 2 /s under these ventilation conditions. The average evaporation rate measured on some major fractures was about 1.3 mg/m 2 /s. The maximum evaporation rate measured was 12.8 mg/m 2 /s. Some spots of high evaporation rate were clearly found along some major fractures and these spots seemed to be the special seepage ways (channels) developed in those fractures. The fracture flow is relatively small compared with the matrix flow in the inner part of the drift. This measurement was performed about 1 month after the excavation of the validation drift. Groundwater flow around the tunnel might not be in a steady state because the period between tunnel excavation and the measurement was not so long. The evaporation rate distribution under the steady state of groundwater flow will be studied in 1991. (au)

242-A evaporator vacuum condenser system

International Nuclear Information System (INIS)

Smith, V.A.

1994-01-01

This document is written for the 242-A evaporator vacuum condenser system (VCS), describing its purpose and operation within the evaporator. The document establishes the operating parameters specifying pressure, temperature, flow rates, interlock safety features and interfacing sub-systems to support its operation

Assessment of evaporative water loss from Dutch cities

NARCIS (Netherlands)

Jacobs, C.M.J.; Elbers, J.A.; Brolsma, R.; Hartogensis, O.K.; Moors, E.J.; Rodríguez-CarreteroMárquez, M.T.; Hove, van B.

2015-01-01

Reliable estimates of evaporative water loss are required to assess the urban water budget in support of division of water resources among various needs, including heat mitigation measures in cities relying on evaporative cooling. We report on urban evaporative water loss from Arnhem and Rotterdam

Evaporation equipment with electron beam heating for the evaporation of metals and other conducting materials

International Nuclear Information System (INIS)

Mueller, P.

1977-01-01

Equipment for the evaporation of metals and other conducting materials by electron beam heating is to be improved by surrou nding the evaporation equipment with a grid, which has a negative voltage compared to the cathode. This achieves the state where the cathode is hit and damaged less by the ions formed, so that its life period is prolonged. (UWI) [de

The desorptivity model of bulk soil-water evaporation

Science.gov (United States)

Clapp, R. B.

1983-01-01

Available models of bulk evaporation from a bare-surfaced soil are difficult to apply to field conditions where evaporation is complicated by two main factors: rate-limiting climatic conditions and redistribution of soil moisture following infiltration. Both factors are included in the "desorptivity model', wherein the evaporation rate during the second stage (the soil-limiting stage) of evaporation is related to the desorptivity parameter, A. Analytical approximations for A are presented. The approximations are independent of the surface soil moisture. However, calculations using the approximations indicate that both soil texture and soil moisture content at depth significantly affect A. Because the moisture content at depth decreases in time during redistribution, it follows that the A parameter also changes with time. Consequently, a method to calculate a representative value of A was developed. When applied to field data, the desorptivity model estimated cumulative evaporation well. The model is easy to calculate, but its usefulness is limited because it requires an independent estimate of the time of transition between the first and second stages of evaporation. The model shows that bulk evaporation after the transition to the second stage is largely independent of climatic conditions.

Spent-fuel pool thermal hydraulics: The evaporation question

International Nuclear Information System (INIS)

Yilmaz, T.P.; Lai, J.C.

1996-01-01

Many nuclear power plants are currently using dense fuel arrangements that increase the number of spent fuel elements stored in their spent-fuel pools (SFPs). The denser spent-fuel storage results in higher water temperatures, especially when certain event scenarios are analyzed. In some of these event scenarios, it is conservative to maximize the evaporation rate, while in other circumstances it is required to minimize the evaporation rates for conservatism. Evaporation is such a fundamental phenomenon that many branches of engineering developed various equations based on theory and experiments. The evaporation rates predicted by existing equations present a wide range of variation, especially at water temperatures >40 degrees C. Furthermore, a study on which equations provide the highest and lowest evaporation rates has not been done until now. This study explores the sensitivity of existing evaporation equations to various parameters and recommends the limiting evaporation equations for use in the solution of SFP thermal problems. Note that the results of this study may be applicable to a much wider range of applications from irrigation ponds, cooling lakes, and liquid-waste management to calculating adequate air exchange rate for swimming pools and health spas

Solubility of plutonium and waste evaporation

International Nuclear Information System (INIS)

Karraker, D.G.

1993-01-01

Chemical processing of irradiated reactor elements at the Savannah River Site separates uranium, plutonium and fission products; fission products and process-added chemicals are mixed with an excess of NaOH and discharged as a basic slurry into large underground tanks for temporary storage. The slurry is composed of base-insoluble solids that settle to the bottom of the tank; the liquid supemate contains a mixture of base-soluble chemicals--nitrates, nitrites aluminate, sulfate, etc. To conserve space in the waste tanks, the supemate is concentrated by evaporation. As the evaporation proceeds, the solubilities of some components are exceeded, and these species crystallize from solution. Normally, these components are soluble in the hot solution discharged from the waste tank evaporator and do not crystallize until the solution cools. However, concern was aroused at West Valley over the possibility that plutonium would precipitate and accumulate in the evaporator, conceivably to the point that a nuclear accident was possible. There is also a concern at SRS from evaporation of sludge washes, which arise from washing the base-insoluble solids (open-quote sludge close-quote) with ca. 1M NaOH to reduce the Al and S0 4 -2 content. The sludge washes of necessity extract a low level of Pu from the sludge and are evaporated to reduce their volume, presenting the possibility of precipitating Pu. Measurements of the solubility of Pu in synthetic solutions of similar composition to waste supernate and sludge washes are described in this report

Active-Reactive Additional Damping Control of a Doubly-Fed Induction Generator Based on Active Disturbance Rejection Control

Directory of Open Access Journals (Sweden)

Yanfeng Ma

2018-05-01

Full Text Available Large-scale wind power interfacing to the power grid has an impact on the stability of the power system. However, with an additional damping controller of the wind generator, new ways for improving system damping and suppressing the low frequency oscillation (LFO of power systems can be put forward. In this paper, an active-reactive power additional damping controller based on active disturbance rejection control (ADRC is proposed. In order to improve the precision of the controller, the theory of data driven control is adopted, using the numerical algorithms for subspace state space system identification (N4SID to obtain the two order model of the ADRC controlled object. Based on the identification model, the ADRC additional damping controller is designed. Taking a 2-area 4-machine system containing the doubly fed induction generator (DFIG wind farm as an example, it is verified that the active-reactive additional damping controller designed in this paper performs well in suppressing negative-damping LFO and forced power oscillation. When the operation state of the power system changes, it can still restrain the LFO effectively, showing stronger robustness and better effectiveness compared to the traditional proportional–integral–derivative (PID additional damping controller.

Fabrication of Josephson Junction without shadow evaporation

Science.gov (United States)

Wu, Xian; Ku, Hsiangsheng; Long, Junling; Pappas, David

We developed a new method of fabricating Josephson Junction (Al/AlOX/Al) without shadow evaporation. Statistics from room temperature junction resistance and measurement of qubits are presented. Unlike the traditional ``Dolan Bridge'' technique, this method requires two individual lithographies and straight evaporations of Al. Argon RF plasma is used to remove native AlOX after the first evaporation, followed by oxidation and second Al evaporation. Junction resistance measured at room temperature shows linear dependence on Pox (oxidation pressure), √{tox} (oxidation time), and inverse proportional to junction area. We have seen 100% yield of qubits made with this method. This method is promising because it eliminates angle dependence during Junction fabrication, facilitates large scale qubits fabrication.

Universal evaporation dynamics of a confined sessile droplet

Science.gov (United States)

Bansal, Lalit; Hatte, Sandeep; Basu, Saptarshi; Chakraborty, Suman

2017-09-01

Droplet evaporation under confinement is ubiquitous to multitude of applications such as microfluidics, surface patterning, and ink-jet printing. However, the rich physics governing the universality in the underlying dynamics remains grossly elusive. Here, we bring out hitherto unexplored universal features of the evaporation dynamics of a sessile droplet entrapped in a 3D confined fluidic environment. We show, through extensive set of experiments and theoretical formulations, that the evaporation timescale for such a droplet can be represented by a unique function of the initial conditions. Moreover, using same theoretical considerations, we are able to trace and universally merge the volume evolution history of the droplets along with evaporation lifetimes, irrespective of the extent of confinement. We also showcase the internal flow transitions caused by spatio-temporal variation of evaporation flux due to confinement. These findings may be of profound importance in designing functionalized droplet evaporation devices for emerging engineering and biomedical applications.

Enhanced Evaporation and Condensation in Tubes

Science.gov (United States)

Honda, Hiroshi

A state-of-the-art review of enhanced evaporation and condensation in horizontal microfin tubes and micro-channels that are used for air-conditioning and refrigeration applications is presented. The review covers the effects of flow pattern and geometrical parameters of the tubes on the heat transfer performance. Attention is paid to the effect of surface tension which leads to enhanced evaporation and condensation in the microfin tubes and micro-channels. A review of prior efforts to develop empirical correlations of the heat transfer coefficient and theoretical models for evaporation and condensation in the horizontal microfin tubes and micro-channels is also presented.

Thermocapillary flow about an evaporating meniscus

Science.gov (United States)

Schmidt, G. R.; Chung, T. J.

1992-01-01

The steady motion and thermal behavior of an evaporating superheated liquid in a small cavity bounded by isothermal sidewalls is examined. Scaling analyses and a two-dimensional finite element model are used to investigate the influence of thermocapillarity, buoyancy, and temperature-dependent mass flux on flowfield, interfacial heat transfer, and meniscus morphology. Numerical investigations indicate the existence of two counter-rotating cells symmetric about the cavity center. Results also show that evaporation tends to counteract this circulation by directing flow toward the hotter sidewalls. Although thermocapillarity and evaporation yield different flowfield distributions, both effects tend to increase interfacial temperature and heat transfer.

Accelerated evaporation of water on graphene oxide.

Science.gov (United States)

Wan, Rongzheng; Shi, Guosheng

2017-03-29

Using molecular dynamics simulations, we show that the evaporation of nanoscale volumes of water on patterned graphene oxide is faster than that on homogeneous graphene oxide. The evaporation rate of water is insensitive to variation in the oxidation degree of the oxidized regions, so long as the water film is only distributed on the oxidized regions. The evaporation rate drops when the water film spreads onto the unoxidized regions. Further analysis showed that varying the oxidation degree observably changed the interaction between the outmost water molecules and the solid surface, but the total interaction for the outmost water molecules only changed a very limited amount due to the correspondingly regulated water-water interaction when the water film is only distributed on the oxidized regions. When the oxidation degree is too low and some unoxidized regions are also covered by the water film, the thickness of the water film decreases, which extends the lifetime of the hydrogen bonds for the outmost water molecules and lowers the evaporation rate of the water. The insensitivity of water evaporation to the oxidation degree indicates that we only need to control the scale of the unoxidized and oxidized regions for graphene oxide to regulate the evaporation of nanoscale volumes of water.

Optimized evaporation technique for leachate treatment: Small scale implementation.

Science.gov (United States)

Benyoucef, Fatima; Makan, Abdelhadi; El Ghmari, Abderrahman; Ouatmane, Aziz

2016-04-01

This paper introduces an optimized evaporation technique for leachate treatment. For this purpose and in order to study the feasibility and measure the effectiveness of the forced evaporation, three cuboidal steel tubs were designed and implemented. The first control-tub was installed at the ground level to monitor natural evaporation. Similarly, the second and the third tub, models under investigation, were installed respectively at the ground level (equipped-tub 1) and out of the ground level (equipped-tub 2), and provided with special equipment to accelerate the evaporation process. The obtained results showed that the evaporation rate at the equipped-tubs was much accelerated with respect to the control-tub. It was accelerated five times in the winter period, where the evaporation rate was increased from a value of 0.37 mm/day to reach a value of 1.50 mm/day. In the summer period, the evaporation rate was accelerated more than three times and it increased from a value of 3.06 mm/day to reach a value of 10.25 mm/day. Overall, the optimized evaporation technique can be applied effectively either under electric or solar energy supply, and will accelerate the evaporation rate from three to five times whatever the season temperature. Copyright © 2016. Published by Elsevier Ltd.

Effects of NaF evaporation during low temperature Cu(In,Ga)Se{sub 2} growth

Energy Technology Data Exchange (ETDEWEB)

Bissig, B., E-mail: benjamin.bissig@empa.ch; Reinhard, P.; Pianezzi, F.; Hagendorfer, H.; Nishiwaki, S.; Buecheler, S.; Tiwari, A.N.

2015-05-01

Co-evaporation of NaF during the 3{sup rd} stage of the low temperature Cu(In,Ga)Se{sub 2} multi-stage process is compared to post-deposition treatment (PDT) with NaF in view of their influence on the electronic and structural properties. In case of NaF co-evaporation, quantum efficiency losses in the near infrared region and thus lower short circuit current density cause a reduced efficiency compared to solar cells prepared with NaF PDT. The formation of a deep defect with activation energy of ~ 250 meV is measured by capacitance spectroscopy and can explain the deteriorated performance in such devices. In addition, NaF co-evaporation during the 3{sup rd} stage causes reduced grain size in the top part of Cu(In,Ga)Se{sub 2} and altered In, Ga, and Cu distribution. - Highlights: • NaF was co-evaporated in a low temperature CIGS process during and after the 3rd stage. • CIGS grains size is reduced in the top 300 nm when NaF is co-evaporated. • C-f measurements indicate deep defect formation when NaF is co-evaporated.

Prodrugs activated by reactive oxygen species for use in the treatment of inflammatory diseases and cancer

DEFF Research Database (Denmark)

2018-01-01

Prodrugs activated predominantly or exclusively in inflammatory tissue, more particularly prodrugs of methotrexate and derivatives thereof, which are selectively activated by Reactive Oxygen Species (ROS) in inflammatory tissues associated with cancer and inflammatory diseases, as well as method...

Characterization and re-activation of oxygen sensors for use in liquid lead-bismuth

International Nuclear Information System (INIS)

Kurata, Yuji; Abe, Yuji; Futakawa, Masatoshi; Oigawa, Hiroyuki

2010-01-01

Control of oxygen concentration in liquid lead-bismuth is one of the most important tasks to develop accelerator driven systems. In order to improve the reliability of oxygen sensors, re-activation treatments were investigated as well as characterization of oxygen sensors for use in liquid lead-bismuth. The oxygen sensor with a solid electrolyte of yttria-stabilized zirconia and a Pt/gas reference electrode showed almost the same electromotive force values in gas and liquid lead-bismuth, respectively, as the theoretical ones at temperatures above 400 deg. C or 450 deg. C. After long-term use of 6500 h, the outputs of the sensor became incorrect in liquid lead-bismuth. The state of the sensor that indicated incorrect outputs could not be recovered by cleaning with a nitric acid. However, it was found that the oxygen sensor became a correct sensor indicating theoretical values in liquid lead-bismuth after re-activation by the Pt-treatment of the outer surface of the sensor.

Raman Thermometry Measurements of Free Evaporation from Liquid Water Droplets

International Nuclear Information System (INIS)

Smith, Jared D.; Cappa, Christopher D.; Drisdell, Walter S.; Cohen, Ronald C.; Saykally, Richard J.

2006-01-01

Recent theoretical and experimental studies of evaporation have suggested that on average, molecules in the higher-energy tail of the Boltzmann distribution are more readily transferred into the vapor during evaporation. To test these conclusions, the evaporative cooling rates of a droplet train of liquid water injected into vacuum have been studied via Raman thermometry. The resulting cooling rates are fit to an evaporative cooling model based on Knudsen's maximum rate of evaporation, in which we explicitly account for surface cooling. We have determined that the value of the evaporation coefficient (γ e ) of liquid water is 0.62 ± 0.09, confirming that a rate-limiting barrier impedes the evaporation rate. Such insight will facilitate the formulation of a microscopic mechanism for the evaporation of liquid water

Evaporative water loss from welded tuff

International Nuclear Information System (INIS)

Hadley, G.R.; Turner, J.R. Jr.

1980-04-01

Welded tuff is one of the many candidate rocks presently being considered as a host medium for the disposal of radioactive waste. In the case where the disposal site lies above the water table, the host rock will in general be only partially saturated. This condition leads to a number of mass transfer processes of interest, including evaporative drying, two-phase water flow due to pressure gradients, capillary movement, plus others. Although these processes have all been known about for decades, it is not clear at this time what the relative importance of each is with regard to geologic media in a waste disposal environment. In particular, there seems to be no data available for tuff that would allow an investigator to sort out mechanisms. This work is intended to be a start in that direction. This paper reports the measurement of water loss rate for welded tuff at various temperatures due to the action of evaporative drying. The initial saturation was unknown, but the average initial water content was found to be 7% by weight. The resulting data show that the water loss rate declines monotonically with time at a given temperature and increases with increasing temperature as expected. Somewhat surprising, however, is the fact that over 90% of the water from a sample was lost by evaporation at room temperature within 72 hours. All the water loss data, including that taken at temperatures as high as 150 0 C, are explained to within a factor of two by a simple evaporation front model. The latter assumes the water is lost by the molecular diffusion of water vapor from a receding evaporation front. The motion of the evaporation front seems to depend on mass balance rather than energy balance. Capillary forces and the resulting liquid diffusion are evidently not strong enough to wash out the evaporation front, since the front model seems to fit the data well

In patients with neovascular age-related macular degeneration, physical activity may influence C-reactive protein levels

DEFF Research Database (Denmark)

Subhi, Yousif; Singh, Amardeep; Falk, Mads Krüger

2014-01-01

Association of neovascular age-related macular degeneration (AMD) with C-reactive protein (CRP) was previously reported, indicating a relation to systemic low-grade inflammation. However, visual impairment limits physical activity, and physical activity modulates CRP levels. Here, we investigated...

Determination of reactive oxygen species from ZnO micro-nano structures with shape-dependent photocatalytic activity

Energy Technology Data Exchange (ETDEWEB)

He, Weiwei; Zhao, Hongxiao; Jia, Huimin [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Henan 461000 (China); Yin, Jun-Jie [Center for Food Safety and Applied Nutrition, U.S. Food and Drug Administration, College Park, MD 20740 (United States); Zheng, Zhi, E-mail: zhengzhi99999@gmail.com [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Henan 461000 (China)

2014-05-01

Graphical abstract: ZnO micro/nano structures with shape dependent photocatalytic activity were prepared by hydrothermal reaction. The generations of hydroxyl radical, superoxide and singlet oxygen from irradiated ZnO were identified precisely by electron spin resonance spectroscopy. The type of reactive oxygen species was determined by band gap structure of ZnO. - Highlights: • ZnO micro/nano structures with different morphologies were prepared by solvothermal reaction. • Multi-pod like ZnO structures exhibited superior photocatalytic activity. • The generations of hydroxyl radical, superoxide and singlet oxygen from irradiated ZnO were characterized precisely by electron spin resonance spectroscopy. • The type of reactive oxygen species was determined by band gap structure of ZnO. - Abstract: ZnO micro/nano structures with different morphologies have been prepared by the changing solvents used during their synthesis by solvothermal reaction. Three typical shapes of ZnO structures including hexagonal, bell bottom like and multi-pod formed and were characterized by scanning electron microscopy and X-ray diffraction. Multi pod like ZnO structures exhibited the highest photocatalytic activity toward degradation of methyl orange. Using electron spin resonance spectroscopy coupled with spin trapping techniques, we demonstrate an effective way to identify precisely the generation of hydroxyl radicals, superoxide and singlet oxygen from the irradiated ZnO multi pod structures. The type of reactive oxygen species formed was predictable from the band gap structure of ZnO. These results indicate that the shape of micro-nano structures significantly affects the photocatalytic activity of ZnO, and demonstrate the value of electron spin resonance spectroscopy for characterizing the type of reactive oxygen species formed during photoexcitation of semiconductors.

Determination of reactive oxygen species from ZnO micro-nano structures with shape-dependent photocatalytic activity

International Nuclear Information System (INIS)

He, Weiwei; Zhao, Hongxiao; Jia, Huimin; Yin, Jun-Jie; Zheng, Zhi

2014-01-01

Graphical abstract: ZnO micro/nano structures with shape dependent photocatalytic activity were prepared by hydrothermal reaction. The generations of hydroxyl radical, superoxide and singlet oxygen from irradiated ZnO were identified precisely by electron spin resonance spectroscopy. The type of reactive oxygen species was determined by band gap structure of ZnO. - Highlights: • ZnO micro/nano structures with different morphologies were prepared by solvothermal reaction. • Multi-pod like ZnO structures exhibited superior photocatalytic activity. • The generations of hydroxyl radical, superoxide and singlet oxygen from irradiated ZnO were characterized precisely by electron spin resonance spectroscopy. • The type of reactive oxygen species was determined by band gap structure of ZnO. - Abstract: ZnO micro/nano structures with different morphologies have been prepared by the changing solvents used during their synthesis by solvothermal reaction. Three typical shapes of ZnO structures including hexagonal, bell bottom like and multi-pod formed and were characterized by scanning electron microscopy and X-ray diffraction. Multi pod like ZnO structures exhibited the highest photocatalytic activity toward degradation of methyl orange. Using electron spin resonance spectroscopy coupled with spin trapping techniques, we demonstrate an effective way to identify precisely the generation of hydroxyl radicals, superoxide and singlet oxygen from the irradiated ZnO multi pod structures. The type of reactive oxygen species formed was predictable from the band gap structure of ZnO. These results indicate that the shape of micro-nano structures significantly affects the photocatalytic activity of ZnO, and demonstrate the value of electron spin resonance spectroscopy for characterizing the type of reactive oxygen species formed during photoexcitation of semiconductors

Production and characterization of activated carbon prepared from safflower seed cake biochar and its ability to absorb reactive dyestuff

Energy Technology Data Exchange (ETDEWEB)

Angın, Dilek, E-mail: angin@sakarya.edu.tr [Department of Food Engineering, Faculty of Engineering, Sakarya University, Sakarya (Turkey); Köse, T. Ennil, E-mail: ennilb@ogu.edu.tr [Department of Chemical Engineering, Faculty of Engineering and Architecture, Eskisehir Osmangazi University, 26480 Meselik-Eskisehir (Turkey); Selengil, Uğur, E-mail: uselen@ogu.edu.tr [Department of Chemical Engineering, Faculty of Engineering and Architecture, Eskisehir Osmangazi University, 26480 Meselik-Eskisehir (Turkey)

2013-09-01

The use of activated carbon obtained from biochar for the removal of reactive dyestuff from aqueous solutions at various contact times, pHs and temperatures was investigated. The biochar was chemically modified with potassium hydroxide. The surface area and micropore volume of activated carbon was 1277 m{sup 2}/g and 0.4952 cm{sup 3}/g, respectively. The surface characterization of both biochar and activated carbon was undertaken using by Fourier transform infrared spectroscopy and scanning electron microscopy. The experimental data indicated that the adsorption isotherms are well described by the Dubinin–Radushkevich (DR) isotherm equation. The adsorption kinetics of reactive dyestuff obeys the pseudo second-order kinetic model. The thermodynamic parameters such as ΔG{sup o}, ΔH{sup o} and ΔS{sup o} were calculated to estimate the nature of adsorption. The activation energy of the system was calculated as 1.12 kJ/mol. According to these results, prepared activated carbon could be used as a low-cost adsorbent to compare with the commercial activated carbon for the removal reactive dyestuff from waste water.

Water evaporation from substrate tooth surface during dentin treatments.

Science.gov (United States)

Kusunoki, Mizuho; Itoh, Kazuo; Gokan, Yuka; Nagai, Yoshitaka; Tani, Chihiro; Hisamitsu, Hisashi

2011-01-01

The purpose of this study was to evaluate changes in the quantity of water evaporation from tooth surfaces. The amount of water evaporation was measured using Multi probe adapter MPA5 and Tewameter TM300 (Courage+Khazaka Electric GmbH, Köln, Germany) after acid etching and GM priming of enamel; and after EDTA conditioning and GM priming of dentin. The results indicated that the amount of water evaporation from the enamel surface was significantly less than that from the dentin. Acid etching did not affect the water evaporation from enamel, though GM priming significantly decreased the evaporation (83.48 ± 15.14% of that before priming). The evaporation from dentin was significantly increased by EDTA conditioning (131.38 ± 42.08% of that before conditioning) and significantly reduced by GM priming (80.26 ± 7.43% of that before priming). It was concluded that dentin priming reduced water evaporation from the dentin surface.

Artificial weathering of oils by rotary evaporator

International Nuclear Information System (INIS)

Fieldhouse, B.; Hollebone, B.P.; Singh, N.R.; Tong, T.S.; Mullin, J.

2009-01-01

Oil weathering has a considerable affect on the behaviour, impact and ultimate fate of an oil spill. As such, efforts have been made to study weathering as a whole using bench-scale procedures. The studies are generally divided into individual processes where the effect of other major processes are introduce as an amended sample input rather than a concurrent process. The weathering process that has the greatest effect immediately following an oil spill is evaporation, particularly for lighter oils. The rotary evaporator apparatus offers a convenient means of producing artificially weathered oil for laboratory studies. This paper reported on a study that examined the representativeness of samples obtained by this method compared to pan evaporation and the impact of changes to the apparatus or method parameters on sample chemistry. Experiments were performed on Alberta Sweet Mixed Blend no. 5 in a rotary evaporator under varying conditions of temperature and air flow at ambient pressure using 2 apparatus. The rate of mass loss increased with temperature and air flow rate as expected, but the quantitative relationships could not be defined from the data due to contributions by other uncontrolled factors. It was concluded that the rotary evaporator is not suited for evaporation rate studies, but rather for producing samples suitable for use in other studies. Chemical analysis showed that the relative abundance distributions of target n-alkane hydrocarbons varied with the degree of weathering of an oil in a consistent manner at ambient pressure, regardless of the temperature, rate of air exchange or other factors related to the apparatus and procedure. The composition of the artificially weathered oil was also consistent with that from an open pan simulation of a weathered oil slick. Loss of water content varied with the conditions of evaporation because of the differential rates of evaporation due to relative humidity considerations. It was concluded that weathering

The mystery of gold's chemical activity: local bonding, morphology and reactivity of atomic oxygen.

Science.gov (United States)

Baker, Thomas A; Liu, Xiaoying; Friend, Cynthia M

2011-01-07

Recently, gold has been intensely studied as a catalyst for key synthetic reactions. Gold is an attractive catalyst because, surprisingly, it is highly active and very selective for partial oxidation processes suggesting promise for energy-efficient "green" chemistry. The underlying origin of the high activity of Au is a controversial subject since metallic gold is commonly thought to be inert. Herein, we establish that one origin of the high activity for gold catalysis is the extremely reactive nature of atomic oxygen bound in 3-fold coordination sites on metallic gold. This is the predominant form of O at low concentrations on the surface, which is a strong indication that it is most relevant to catalytic conditions. Atomic oxygen bound to metallic Au in 3-fold sites has high activity for CO oxidation, oxidation of olefins, and oxidative transformations of alcohols and amines. Among the factors identified as important in Au-O interaction are the morphology of the surface, the local binding site of oxygen, and the degree of order of the oxygen overlayer. In this Perspective, we present an overview of both theory and experiments that identify the reactive forms of O and their associated charge density distributions and bond strengths. We also analyze and model the release of Au atoms induced by O binding to the surface. This rough surface also has the potential for O(2) dissociation, which is a critical step if Au is to be activated catalytically. We further show the strong parallels between product distributions and reactivity for O-covered Au at low pressure (ultrahigh vacuum) and for nanoporous Au catalysts operating at atmospheric pressure as evidence that atomic O is the active species under working catalytic conditions when metallic Au is present. We briefly discuss the possible contributions of oxidants that may contain intact O-O bonds and of the Au-metal oxide support interface in Au catalysis. Finally, the challenges and future directions for fully

Growth of high quality large area MgB2 thin films by reactive evaporation

OpenAIRE

Moeckly, Brian H.; Ruby, Ward S.

2006-01-01

We report a new in-situ reactive deposition thin film growth technique for the production of MgB2 thin films which offers several advantages over all existing methods and is the first deposition method to enable the production of high-quality MgB2 films for real-world applications. We have used this growth method, which incorporates a rotating pocket heater, to deposit MgB2 films on a variety of substrates, including single-crystalline, polycrystalline, metallic, and semiconductor materials u...

A kinetic model of droplet heating and evaporation: Effects of inelastic collisions and a non-unity evaporation coefficient

KAUST Repository

Sazhin, Sergei S.; Xie, Jianfei; Shishkova, Irina N.; Elwardani, Ahmed Elsaid; Heikal, Morgan Raymond

2013-01-01

The previously developed kinetic model for droplet heating and evaporation into a high pressure air is generalised to take into account the combined effects of inelastic collisions between molecules in the kinetic region, a non-unity evaporation

Intracellular-activated Notch1 can reactivate Kaposi's sarcoma-associated herpesvirus from latency

International Nuclear Information System (INIS)

Lan, Ke; Murakami, Masanao; Choudhuri, Tathagata; Kuppers, Daniel A.; Robertson, Erle S.

2006-01-01

Kaposi's sarcoma-associated herpesvirus (KSHV) establishes a predominantly latent infection in the infected host. Importantly, during latency, only a small number of viral encoded genes are expressed. This viral gene expression pattern contributes to the establishment of long-term infection as well as the ability of the virus to evade the immune system. Previous studies have been shown that the replication and transcription activator (RTA) encoded by ORF50 activates it downstream genes and initiates viral lytic reactivation through functional interaction with RBP-Jκ, the major downstream effector of the Notch signaling pathway. This indicates that RTA can usurp the conserved Notch signaling pathway and mimic the activities of intracellular Notch1 to modulate gene expression. In this report, we show that the activated intracellular domain of Notch1 (ICN) is aberrantly accumulated in KSHV latently infected pleural effusion lymphoma (PEL) cells. ICN activated the RTA promoter in a dose-dependent manner, and forced expression of ICN in latently infected KSHV-positive cells initiated full blown lytic replication with the production of infectious viral progeny. However, latency-associated nuclear antigen (LANA) which is predominantly expressed during latency can specifically down-modulate ICN-mediated transactivation of RTA and so control KSHV for lytic reactivation. These results demonstrate that LANA can inhibit viral lytic replication by antagonizing ICN function and suggest that LANA is a critical component of the regulatory control mechanism for switching between viral latent and lytic replication by directly interacting with effectors of the conserved cellular Notch1 pathway

Mercuric iodide crystals obtained by solvent evaporation using ethanol

International Nuclear Information System (INIS)

Ugucioni, J.C.; Ghilardi Netto, T.; Mulato, M.

2010-01-01

Millimeter-sized mercuric iodide crystals were fabricated by the solvent evaporation technique using pure ethanol as a solvent. Three different conditions for solution evaporation were tested: (i) in the dark at room temperature; (ii) in the presence of light at room temperature and (iii) in an oven at 40 deg. C. Morphology, structure, optical and electrical properties were investigated using several techniques. Crystals fabricated in the dark show better properties and stability than others, possibly because the larger the energy of the system, the larger the number of induced growth defects. The crystals fabricated in the dark have adequate structure for higher resistivity and activation energy close to half the optical band-gap, as desired. With proper encapsulation these crystals might be good candidates for the development of ionizing radiation sensors.

Reactivation of desensitized formyl peptide receptors by platelet activating factor: a novel receptor cross talk mechanism regulating neutrophil superoxide anion production.

Directory of Open Access Journals (Sweden)

Huamei Forsman

Full Text Available Neutrophils express different chemoattractant receptors of importance for guiding the cells from the blood stream to sites of inflammation. These receptors communicate with one another, a cross talk manifested as hierarchical, heterologous receptor desensitization. We describe a new receptor cross talk mechanism, by which desensitized formyl peptide receptors (FPRdes can be reactivated. FPR desensitization is induced through binding of specific FPR agonists and is reached after a short period of active signaling. The mechanism that transfers the receptor to a non-signaling desensitized state is not known, and a signaling pathway has so far not been described, that transfers FPRdes back to an active signaling state. The reactivation signal was generated by PAF stimulation of its receptor (PAFR and the cross talk was uni-directional. LatrunculinA, an inhibitor of actin polymerization, induced a similar reactivation of FPRdes as PAF while the phosphatase inhibitor CalyculinA inhibited reactivation, suggesting a role for the actin cytoskeleton in receptor desensitization and reactivation. The activated PAFR could, however, reactivate FPRdes also when the cytoskeleton was disrupted prior to activation. The receptor cross talk model presented prophesies that the contact on the inner leaflet of the plasma membrane that blocks signaling between the G-protein and the FPR is not a point of no return; the receptor cross-talk from the PAFRs to the FPRdes initiates an actin-independent signaling pathway that turns desensitized receptors back to a signaling state. This represents a novel mechanism for amplification of neutrophil production of reactive oxygen species.

A new stationary droplet evaporation model and its validation

Directory of Open Access Journals (Sweden)

Fang WANG

2017-08-01

Full Text Available The liquid droplet evaporation character is important for not only combustion chamber design process but also high-accuracy spray combustion simulation. In this paper, the suspended droplets’ evaporation character was measured in a quiescent high-temperature environment by micro high-speed camera system. The gasoline and kerosene experimental results are consistent with the reference data. Methanol, common kerosene and aviation kerosene droplet evaporation characteristics, as well as their evaporation rate changing with temperature, were obtained. The evaporation rate experimental data were compared with the prediction result of Ranz-Marshall boiling temperature model (RMB, Ranz-Marshall low-temperature model (RML, drift flux model (DFM, mass analogy model (MAM, and stagnant film model (SFM. The disparity between the experimental data and the model prediction results was mainly caused by the neglect of the natural convection effect, which was never introduced into the droplet evaporation concept. A new droplet evaporation model with consideration of natural convection buoyancy force effect was proposed in this paper. Under the experimental conditions in this paper, the calculation results of the new droplet evaporation model were agreed with the experimental data for kerosene, methanol and other fuels, with less than 20% relative deviations. The relative deviations between the new evaporation model predictions for kerosene and the experimental data from the references were within 10%.

Decommissioning of evaporation technology for processing liquid radioactive waste in UJV Rez, a. s

International Nuclear Information System (INIS)

Tous, M.; Otcovsky, T.; Podlaha, J.

2015-01-01

The UJV Rez, a. s. is the main leader in processing institutional radioactive waste (RAW) in the Czech Republic and the Waste Management Department has been established since the research reactor VVR-S (now LVR-15) was put in operation. Due to the large activities in nuclear research and engineering in the past, a big capacity of waste management technologies was needed. The low pressure compactor for volume reduction of solid RAW, as well as chemical pre-treatment technology of liquid RAW were installed and later the evaporation technology for effective processing the liquid RAW with the cementation and bituminization unit for final conditioning of concentrated liquid RAW were used. During the years of research reactor operation and research activities in UJV Rez, a. s. there were two installed evaporation technologies in row. After the latest evaporator lifetime, changes in liquid RAW production and together with higher decontamination factor requirements, this technology was decided to be decommissioned. The decommissioned evaporation technology was installed and put in operation in 1991. This technology was used for processing liquid aqueous RAW produced from internal research activities and of course for external producers and institutions (e.g. universities, medicine, research institutes, industry). The approved decommissioning plan was prepared and the licence for immediate decommissioning was obtained in 2012. Then the decommissioning project started. The preparing stages as dosimetric survey, expected material balance and of course initial decontamination activities were performed. Evaporation technology dismantling and processing the arising RAW were done by the internal staff of Waste Management Department. The total volume of produced RAW was 49,5 m 3 of RAW. The secondary liquid RAW (from decontamination) of amount 1,4 m 3 , contaminated sludge of amount 0,5 m 3 , solid RAW (construction steel) of amount 39,1 m 3 , solid compressible RAW (protective

Converting Simulated Sodium-bearing Waste into a Single Solid Waste Form by Evaporation: Laboratory- and Pilot-Scale Test Results on Recycling Evaporator Overheads

Energy Technology Data Exchange (ETDEWEB)

Griffith, D.; D. L. Griffith; R. J. Kirkham; L. G. Olson; S. J. Losinski

2004-01-01

Conversion of Idaho National Engineering and Environmental Laboratory radioactive sodium-bearing waste into a single solid waste form by evaporation was demonstrated in both flask-scale and pilot-scale agitated thin film evaporator tests. A sodium-bearing waste simulant was adjusted to represent an evaporator feed in which the acid from the distillate is concentrated, neutralized, and recycled back through the evaporator. The advantage to this flowsheet is that a single remote-handled transuranic waste form is produced in the evaporator bottoms without the generation of any low-level mixed secondary waste. However, use of a recycle flowsheet in sodium-bearing waste evaporation results in a 50% increase in remote-handled transuranic volume in comparison to a non-recycle flowsheet.

Parametric study of thin film evaporation from nanoporous membranes

Science.gov (United States)

Wilke, Kyle L.; Barabadi, Banafsheh; Lu, Zhengmao; Zhang, TieJun; Wang, Evelyn N.

2017-10-01

The performance and lifetime of advanced electronics are often dictated by the ability to dissipate heat generated within the device. Thin film evaporation from nanoporous membranes is a promising thermal management approach, which reduces the thermal transport distance across the liquid film while also providing passive capillary pumping of liquid to the evaporating interface. In this work, we investigated the dependence of thin film evaporation from nanoporous membranes on a variety of geometric parameters. Anodic aluminum oxide membranes were used as experimental templates, where pore radii of 28-75 nm, porosities of 0.1-0.35, and meniscus locations down to 1 μm within the pore were tested. We demonstrated different heat transfer regimes and observed more than an order of magnitude increase in dissipated heat flux by operating in the pore-level evaporation regime. The pore diameter had little effect on pore-level evaporation performance due to the negligible conduction resistance from the pore wall to the evaporating interface. The dissipated heat flux scaled with porosity as the evaporative area increased. Furthermore, moving the meniscus as little as 1 μm into the pore decreased the dissipated heat flux by more than a factor of two due to the added resistance to vapor escaping the pore. The experimental results elucidate thin film evaporation from nanopores and confirm findings of recent modeling efforts. This work also provides guidance for the design of future thin film evaporation devices for advanced thermal management. Furthermore, evaporation from nanopores is relevant to water purification, chemical separations, microfluidics, and natural processes such as transpiration.

Uranium concentration monitor manual, secondary intermediate evaporator

International Nuclear Information System (INIS)

Russo, P.A.; Sprinkle, J.K. Jr.; Slice, R.W.; Strittmatter, R.B.

1985-08-01

This manual describes the design, operation, and measurement control procedures for the automated uranium concentration monitor on the secondary intermediate evaporator at the Oak Ridge Y-12 Plant. The nonintrusive monitor provides a near-real time readout of uranium concentration in the return loop of time recirculating evaporator for purposes of process monitoring and control. A detector installed near the bottom of the return loop is used to acquire spectra of gamma rays from the evaporator solutions during operation. Pulse height analysis of each spectrum gives the information required to deduce the concentration of uranium in the evaporator solution in near-real time. The visual readout of concentration is updated at the end of every assay cycle. The readout includes an alphanumeric display of uranium concentration and an illuminated, colored LED (in an array of colored LEDs) indicating whether the measured concentration is within (or above or below) the desired range. An alphanumeric display of evaporator solution acid molarity is also available to the operator. 9 refs., 16 figs., 4 tabs

An evaporation based digital microflow meter

NARCIS (Netherlands)

Nie, C; Frijns, A J H; Mandamparambil, R; Zevenbergen, M A G; den Toonder, J M J

2015-01-01

In this work, we present a digital microflow meter operating in the range 30-250 nl min-1 for water. The principle is based on determining the evaporation rate of the liquid via reading the number of wetted pore array structures in a microfluidic system, through which continuous evaporation takes

An evaporation based digital microflow meter

NARCIS (Netherlands)

Nie, C.; Frijns, A.J.H.; Mandamparambil, R.; Zevenbergen, M.A.G.; Toonder, den J.M.J.

2015-01-01

In this work, we present a digital microflow meter operating in the range 30–250 nl min-1 for water. The principle is based on determining the evaporation rate of the liquid via reading the number of wetted pore array structures in a microfluidic system, through which continuous evaporation takes

Microdroplet evaporation in closed digital microfluidic biochips

International Nuclear Information System (INIS)

Ahmadi, Ali; Buat, Matthew D; Hoorfar, Mina

2013-01-01

In this paper, microdroplet evaporation in the closed digital microfluidic systems is studied for hydrophobic and hydrophilic surfaces. The contact angle and contact radius are measured by an enhanced automated polynomial fitting approach. It is observed that the contact angle for both hydrophobic and hydrophilic surfaces remains constant during the evaporation process. However, a higher evaporation rate is observed for hydrophilic droplets compared to the hydrophobic droplets. Since no contact line pinning is observed, first, an analytical model based on the uniform vapor mass flux along the liquid–vapor interface is proposed. Interestingly, it is observed that in the hydrophobic case, the analytical model gives a higher evaporation rate, whereas for the hydrophilic case, the analytical model gives a lower evaporation rate. The discrepancy between the results of the analytical modeling and the experimental values is hypothesized to be due the constant flux assumption. To verify the hypothesis, a finite volume-based numerical model is developed to find the local flux along the liquid–vapor interface. The numerical modeling results confirm that for hydrophilic droplets, the evaporation flux increases very close to the three-phase contact line. In the case of the hydrophobic droplets, on the other hand, the flux decreases close to the contact line due to vapor saturation; as a result the uniform flux assumption overestimates the mass loss. (paper)

Investigating performance of microchannel evaporators with different manifold structures

Energy Technology Data Exchange (ETDEWEB)

Shi, Junye; Qu, Xiaohua; Qi, Zhaogang; Chen, Jiangping [Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, No. 800, Dongchuan Rd, Shanghai 200240 (China)

2011-01-15

In this paper, the performances of microchannel evaporators with different manifold structures are experimentally investigated. Eight evaporator samples with 7 different designs of the I/O manifold and 5 different designs of the return manifold are made for this study. The performances of the evaporator samples are tested on a psychometric calorimeter test bench with the refrigerant 134A at a real automotive AC condition. The results on the variations of the cooling capacity and air temperature distribution of the evaporator due to the deflector designs in the I/O manifold and flow hole arrangements in the return manifold are presented and analyzed. By studying the KPI's for the performance of an evaporator, the design trade-off for an evaporator designer is summarized and discussed. (author)

Mathematical modeling of wiped-film evaporators

International Nuclear Information System (INIS)

Sommerfeld, J.T.

1976-05-01

A mathematical model and associated computer program were developed to simulate the steady-state operation of wiped-film evaporators for the concentration of typical waste solutions produced at the Savannah River Plant. In this model, which treats either a horizontal or a vertical wiped-film evaporator as a plug-flow device with no backmixing, three fundamental phenomena are described: sensible heating of the waste solution, vaporization of water, and crystallization of solids from solution. Physical property data were coded into the computer program, which performs the calculations of this model. Physical properties of typical waste solutions and of the heating steam, generally as analytical functions of temperature, were obtained from published data or derived by regression analysis of tabulated or graphical data. Preliminary results from tests of the Savannah River Laboratory semiworks wiped-film evaporators were used to select a correlation for the inside film heat transfer coefficient. This model should be a useful aid in the specification, operation, and control of the full-scale wiped-film evaporators proposed for application under plant conditions. In particular, it should be of value in the development and analysis of feed-forward control schemes for the plant units. Also, this model can be readily adapted, with only minor changes, to simulate the operation of wiped-film evaporators for other conceivable applications, such as the concentration of acid wastes

Flavonoids: hemisynthesis, reactivity, characterization and free radical scavenging activity.

Science.gov (United States)

Es-Safi, Nour-Eddine; Ghidouche, Souhila; Ducrot, Paul Henri

2007-09-26

Phenolic compounds form one of the main classes of secondary metabolites. They display a large range of structures and they are responsible for the major organoleptic characteristics of plant-derived-foods and beverages, particularly color and taste properties and they also contribute to the nutritional qualities of fruits and vegetables. Phenolic compounds are also highly unstable compounds which undergo numerous enzymatic and chemical reactions during postharvest food storage and processing thus adding to the complexity of plant polyphenol composition. Among these compounds flavonoids constitute one of the most ubiquitous groups of all plant phenolics. Owing to their importance in food organoleptic properties and in human health, a better understanding of their structures, their reactivity and chemical properties in addition to the mechanisms generating them appears essential to predict and control food quality. The purpose of this work is an overview of our findings concerning the hemisynthesis, the reactivity and the enzymatic oxidation of some flavonoids and shed light on the mechanisms involved in some of these processes and the structures of the resulting products. The free radical scavenging activity of some of the synthesized compounds is also presented and a structure-activity relationship is discussed. The first part of this review concerns the synthesis and structural characterization of modified monomeric flavanols. The use of these compounds as precursor for the preparation of natural and modified dimeric procyanidin derivatives was then explored through different coupling reactions. The full characterization of the synthesized compounds was achieved by concerted use of NMR and ESI-MS techniques. The free radical scavenging activity of some of the synthesized compounds was investigated. The second part of this review concerns the enzymatic oxidation of several flavonols by Trametes versicolor laccase. Most of the major oxidation products have been

Flavonoids: Hemisynthesis, Reactivity, Characterization and Free Radical Scavenging Activity

Directory of Open Access Journals (Sweden)

Paul Henri Ducrot

2007-09-01

Full Text Available Phenolic compounds form one of the main classes of secondary metabolites. They display a large range of structures and they are responsible for the major organoleptic characteristics of plant-derived-foods and beverages, particularly color and taste properties and they also contribute to the nutritional qualities of fruits and vegetables. Phenolic compounds are also highly unstable compounds which undergo numerous enzymatic and chemical reactions during postharvest food storage and processing thus adding to the complexity of plant polyphenol composition. Among these compounds flavonoids constitute one of the most ubiquitous groups of all plant phenolics. Owing to their importance in food organoleptic properties and in human health, a better understanding of their structures, their reactivity and chemical properties in addition to the mechanisms generating them appears essential to predict and control food quality. The purpose of this work is an overview of our findings concerning the hemisynthesis, the reactivity and the enzymatic oxidation of some flavonoids and shed light on the mechanisms involved in some of these processes and the structures of the resulting products. The free radical scavenging activity of some of the synthesized compounds is also presented and a structure-activity relationship is discussed. The first part of this review concerns the synthesis and structural characterization of modified monomeric flavanols. The use of these compounds as precursor for the preparation of natural and modified dimeric procyanidin derivatives was then explored through different coupling reactions. The full characterization of the synthesized compounds was achieved by concerted use of NMR and ESI-MS techniques. The free radical scavenging activity of some of the synthesized compounds was investigated. The second part of this review concerns the enzymatic oxidation of several flavonols by Trametes versicolor laccase. Most of the major oxidation

Clustered field evaporation of metallic glasses in atom probe tomography

International Nuclear Information System (INIS)

Zemp, J.; Gerstl, S.S.A.; Löffler, J.F.; Schönfeld, B.

2016-01-01

Field evaporation of metallic glasses is a stochastic process combined with spatially and temporally correlated events, which are referred to as clustered evaporation (CE). This phenomenon is investigated by studying the distance between consecutive detector hits. CE is found to be a strongly localized phenomenon (up to 3 nm in range) which also depends on the type of evaporating ions. While a similar effect in crystals is attributed to the evaporation of crystalline layers, CE of metallic glasses presumably has a different – as yet unknown – physical origin. The present work provides new perspectives on quantification methods for atom probe tomography of metallic glasses. - Highlights: • Field evaporation of metallic glasses is heterogeneous on a scale of up to 3 nm. • Amount of clustered evaporation depends on ion species and temperature. • Length scales of clustered evaporation and correlative evaporation are similar.

Quantum Evaporation from Liquid 4He by Rotons

Science.gov (United States)

Hope, F. R.; Baird, M. J.; Wyatt, A. F. G.

1984-04-01

We have shown that rotons as well as phonons can evaporate 4He atoms in a single-quantum process. Measurements of the time of flight and the angular distribution of the evaporated atoms clearly distinguish between evaporation by phonons and rotons. The results indicate that energy and the parallel component of momentum are conserved at the free liquid surface.

Effects of Topography-driven Micro-climatology on Evaporation

Science.gov (United States)

Adams, D. D.; Boll, J.; Wagenbrenner, N. S.

2017-12-01

The effects of spatial-temporal variation of climatic conditions on evaporation in micro-climates are not well defined. Current spatially-based remote sensing and modeling for evaporation is limited for high resolutions and complex topographies. We investigated the effect of topography-driven micro-climatology on evaporation supported by field measurements and modeling. Fourteen anemometers and thermometers were installed in intersecting transects over the complex topography of the Cook Agronomy Farm, Pullman, WA. WindNinja was used to create 2-D vector maps based on recorded observations for wind. Spatial analysis of vector maps using ArcGIS was performed for analysis of wind patterns and variation. Based on field measurements, wind speed and direction show consequential variability based on hill-slope location in this complex topography. Wind speed and wind direction varied up to threefold and more than 45 degrees, respectively for a given time interval. The use of existing wind models enables prediction of wind variability over the landscape and subsequently topography-driven evaporation patterns relative to wind. The magnitude of the spatial-temporal variability of wind therefore resulted in variable evaporation rates over the landscape. These variations may contribute to uneven crop development patterns observed during the late growth stages of the agricultural crops at the study location. Use of hill-slope location indexes and appropriate methods for estimating actual evaporation support development of methodologies to better define topography-driven heterogeneity in evaporation. The cumulative effects of spatially-variable climatic factors on evaporation are important to quantify the localized water balance and inform precision farming practices.

Out-of-tank evaporator demonstration: Tanks focus area

International Nuclear Information System (INIS)

1998-11-01

Approximately 100 million gal of liquid waste is stored in underground storage tanks (UST)s at the Hanford Site, Idaho National Engineering and Environmental Laboratory (INEEL), Savannah River Site (SRS), and Oak Ridge Reservation (ORR). This waste is radioactive with a high salt content. The US Department of Energy (DOE) wants to minimize the volume of radioactive liquid waste in USTs by removing the excess water. This procedure conserves tank space; lowers the cost of storage; and reduces the volume of wastes subsequently requiring separation, immobilization, and disposal. The Out-of-Tank Evaporator Demonstration (OTED) was initiated to test a modular, skid-mounted evaporator. A mobile evaporator system manufactured by Delta Thermal Inc. was selected. The evaporator design was routinely used in commercial applications such as concentrating metal-plating wastes for recycle and concentrating ethylene glycol solutions. In FY 1995, the skid-mounted evaporator system was procured and installed in an existing ORNL facility (Building 7877) with temporary shielding and remote controls. The evaporator system was operational in January 1996. The system operated 24 h/day and processed 22,000 gal of Melton Valley Storage Tank (MVST) supernatant. The distillate contained essentially no salts or radionuclides. Upon completion of the demonstration, the evaporator underwent decontamination testing to illustrate the feasibility of hands-on maintenance and potential transport to another DOE facility. This report describes the process and the evaporator, its performance at ORNL, future plans, applications of this technology, cost estimates, regulatory and policy considerations, and lessons learned

Study on Evaporation Characteristics of Bio-oil and its Compound Models

OpenAIRE

Tan Long; Ming Li; Yixin Chen; Xifeng Zhu

2014-01-01

In this study, bio-oil was analyzed by gas chromatography mass spectrometry (GC-MS), and the evaporation characteristics of bio-oil were studied at different heating rates (10, 20, and 30 °C/min) from 35 °C to 250 °C by a thermal analyzer (TG-DSC). The TG-DSC results of bio-oil showed that the heat requirement of bio-oil during the evaporation process ranged from 2.072103 to 2.299103 J/g, and the bio-oil activation energy ranged from 1.22×104 to 3.34×104 J/mol. Moreover, four models with fi...

Different parameter and technique affecting the rate of evaporation on active solar still -a review

Science.gov (United States)

A, Muthu Manokar; D, Prince Winston; A. E, Kabeel; Sathyamurthy, Ravishankar; T, Arunkumar

2018-03-01

Water is one of the essential sources for the endurance of human on the earth. As earth having only a small amount of water resources for consumption purpose people in rural and urban areas are getting affected by consuming dirty water that leads to water-borne diseases. Even though ground water is available in small quantity, it has to be treated properly before its use for internal consumption. Brackish water contains dissolve and undissolved contents, and hence it is not suitable for the household purpose. Nowadays, distillation process is done by using passive and active solar stills. The major problem in using passive solar still is meeting higher demand for fresh water. The fresh water production from passive solar still is critically low to meet the demand. To improve the productivity of conventional solar still, input feed water is preheated by integrating the solar still to different collector panels. In this review article, the different parameters that affect the rate of evaporation in an active solar still and the different methods incorporated has been presented. In addition to active distillation system, forced convection technique can be incorporated to increase the yield of fresh water by decreasing the temperature of cover. Furthermore, it is identified that the yield of fresh water from the active desalination system can be improved by sensible and latent heat energy storage. This review will motivate the researchers to decide appropriate active solar still technology for promoting development.

Promoting Conceptual Change in First Year Students' Understanding of Evaporation

Science.gov (United States)

Costu, Bayram; Ayas, Alipasa; Niaz, Mansoor

2010-01-01

We constructed the PDEODE (Predict-Discuss-Explain-Observe-Discuss-Explain) teaching strategy, a variant of the classical POE (Predict-Observe-Explain) activity, to promote conceptual change, and investigated its effectiveness on student understanding of the evaporation concept. The sample consisted of 52 first year students in a primary science…

21 CFR 131.130 - Evaporated milk.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Evaporated milk. 131.130 Section 131.130 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION MILK AND CREAM Requirements for Specific Standardized Milk and Cream § 131.130 Evaporated milk. (a...

Floating convection barrier for evaporation source

International Nuclear Information System (INIS)

1975-01-01

A floating matrix of titanium in an uranium evaporation source, melted by an electron beam, serves as a barrier for preventing cooler material from reaching the evaporation area. This construction allows a big volume of melted uranium to be present and new uranium to be furnished in regulated intervals without manual intervention

The evaporation of the charged and uncharged water drops

Indian Academy of Sciences (India)

Drop evaporation; ventilation coefficient; evaporation-effect of electrical forces. ... to study the effect of ventilation on the rate of evaporation of the millimeter sized ... a ventilated drop to reach its equilibrium temperature increases with the drop ...

Evaporation effect on two-dimensional wicking in porous media.

Science.gov (United States)

Benner, Eric M; Petsev, Dimiter N

2018-03-15

We analyze the effect of evaporation on expanding capillary flow for losses normal to the plane of a two-dimensional porous medium using the potential flow theory formulation of the Lucas-Washburn method. Evaporation induces a finite steady state liquid flux on capillary flows into fan-shaped domains which is significantly greater than the flux into media of constant cross section. We introduce the evaporation-capillary number, a new dimensionless quantity, which governs the frontal motion when multiplied by the scaled time. This governing product divides the wicking behavior into simple regimes of capillary dominated flow and evaporative steady state, as well as the intermediate regime of evaporation influenced capillary driven motion. We also show flow dimensionality and evaporation reduce the propagation rate of the wet front relative to the Lucas-Washburn law. Copyright © 2017 Elsevier Inc. All rights reserved.

Numerical simulation of droplet evaporation between two circular plates

International Nuclear Information System (INIS)

Bam, Hang Jin; Son, Gi Hun

2015-01-01

Numerical simulation is performed for droplet evaporation between two circular plates. The flow and thermal characteristics of the droplet evaporation are numerically investigated by solving the conservation equations of mass, momentum, energy and mass fraction in the liquid and gas phases. The liquid-gas interface is tracked by a sharp-interface level-set method which is modified to include the effects of evaporation at the liquid-gas interface and contact angle hysteresis at the liquid-gas-solid contact line. An analytical model to predict the droplet evaporation is also developed by simplifying the mass and vapor fraction equations in the gas phase. The numerical results demonstrate that the 1-D analytical prediction is not applicable to the high rate evaporation process. The effects of plate gap and receding contact angle on the droplet evaporation are also quantified.

Evaporation thermal anslysis of Swallow-tailed Axial-grooved Heat Pipe

Science.gov (United States)

Zhang, Renping

2018-03-01

A detailed mathematical model that describes evaporating characteristics through thin liquid film at the evaporator section of swallow-tailed axial-grooved heat pipe was developed. The numerical simulation results about thin film profile, liquid-vapour interface temperature, evaporating rate and heat flux at the evaporating thin film region were given by the current investigation and the effect of superheat on the liquid-vapour interface temperature, evaporating mass rate and heat flux was discussed. Meanwhile, thermal model of the meniscus region at the evaporating section was developed to calculate the rate of heat transfer. The ratio of the heat conduction in the evaporating thin liquid film region and total heat rate were also discussed. It is indicated that the thickness of thin liquid film rises in a nearly linear fashion. The disjoining pressure can be neglected with increasing the liquid film thickness, tends to be negligibly small. The heat transfer rate at the intrinsic meniscus cannot be compared with that of the evaporating liquid film region.

New mechanism of cluster-field evaporation in rf breakdown

Directory of Open Access Journals (Sweden)

Z. Insepov

2004-12-01

Full Text Available Using a simple field evaporation model and molecular dynamics simulations of nanoscale copper tip evolution in a high electric field gradient typical for linacs, we have studied a new mechanism for rf-field evaporation. The mechanism consists of simultaneous (collective field evaporation of a large group of tip atoms in high-gradient fields. Thus, evaporation of large clusters is energetically more favorable when compared with the conventional, “one-by-one” mechanism. The studied mechanism could also be considered a new mechanism for the triggering of rf-vacuum breakdown. This paper discusses the mechanism and the experimental data available for electric field evaporation of field-emission microscopy tips.

Characterization of Uranium in Archived 2H Evaporator Scale

International Nuclear Information System (INIS)

DUFF, MC

2004-01-01

This research was conducted to improve our fundamental understanding of the mechanisms of U accumulation with NAS in the evaporators and in other process areas at the SRS that may concentrate U in the presence of silicates, aluminum and NAS. Our study uses information gained from the characterization of solids formed in laboratory tests under similar HLW evaporator conditions to aid our interpretation of characterization data of an actual archived 2H Evaporator scale sample. These basic scientific studies will help support the basis for the continued safe operation of SRS evaporators and this fundamental information will be used to help mitigate U accumulation during evaporator operation

Characterization of lithium evaporators for LTX

Science.gov (United States)

Nieto-Perez, M.; Majeski, R.; Timberlake, J.; Lundberg, D.; Kaita, R.; Arevalo-Torres, B.

2010-11-01

The presence of lithium on the internal components of fusion devices has proven to be beneficial for reactor performance. The Lithium Tokamak Experiment (LTX) will be the first experimental fusion device operating with a significant portion of its internal surface coated with lithium. One of the key capabilities in the device is the reliable production of lithium films inside the reactor. This task is accomplished with the use of lithium evaporators, specially designed for LTX using resistively heated yttria crucibles. In the present work, results from the operation of one of these evaporators on a separate test stand are presented. Deposition measurements at different power levels were performed using a quartz crystal deposition monitor, and temperature distributions in the evaporator crucible and its content were obtained using an infrared camera and a dip-in thermocouple probe. Modeling of the evaporation cloud was done with the raytracing software OptiCAD, and comparisons between the computations and the temperature and flux measurements were performed, in order to accurately predict spatial lithium deposition rates in different locations of the LTX device.

Device for measuring active, reactive and apparent power

Energy Technology Data Exchange (ETDEWEB)

Bartosinski, E.; Wieland, J.

1982-09-30

The plan consists of a traditional electrodynamic mechanism for measuring power (IM) supplemented by three switches, two rectifiers, resistor, included in parallel, and phaseshifting throttle included in series with the voltage coil of the IM. This makes it possible by selection to perform three types of measurements: active power of alternating current or power of direct current, only the voltage coils and the IM current are engaged; reactive power, the resistor and the throttle are additionally engaged by the aforementioned method; complete (apparent) power--the current and the voltage are supplied directly to the IM coils, but in contrast to the first case, through rectifiers. The influence of the highest harmonic components of voltage and current which are not significant for industrial measurements can be eliminated in necessary cases using filtering devices.

Brain activation patterns associated with cue reactivity and craving in abstinent problem gamblers, heavy smokers and healthy controls: an fMRI study

NARCIS (Netherlands)

Goudriaan, A.E.; de Ruiter, M.B.; van den Brink, W.; Oosterlaan, J.; Veltman, D.J.

2010-01-01

Abnormal cue reactivity is a central characteristic of addiction, associated with increased activity in motivation, attention and memory related brain circuits. In this neuroimaging study, cue reactivity in problem gamblers (PRG) was compared with cue reactivity in heavy smokers (HSM) and healthy

Evaluation of granular activated carbon reactivation and regeneration alternatives for the 200 West Area carbon tetrachloride Expedited Response Action

International Nuclear Information System (INIS)

Green, J.W.; Tranbarger, R.K.

1996-07-01

This document presents the results of an engineering study to evaluate alternative technologies for the reactivation or regeneration of granular activated carbon (GAC) resulting from remediation operations in the 200 West Area of the Hanford Site. The objective of the study was to determine whether there is a more cost-effective (onsite or offsite) method of regenerating/reactivating GAC than the present method of shipping the GAC offsite to a commercial reactivation facility in Pennsylvania

Simultaneous ion and neutral evaporation in aqueous nanodrops: experiment, theory, and molecular dynamics simulations.

Science.gov (United States)

Higashi, Hidenori; Tokumi, Takuya; Hogan, Christopher J; Suda, Hiroshi; Seto, Takafumi; Otani, Yoshio

2015-06-28

We use a combination of tandem ion mobility spectrometry (IMS-IMS, with differential mobility analyzers), molecular dynamics (MD) simulations, and analytical models to examine both neutral solvent (H2O) and ion (solvated Na(+)) evaporation from aqueous sodium chloride nanodrops. For experiments, nanodrops were produced via electrospray ionization (ESI) of an aqueous sodium chloride solution. Two nanodrops were examined in MD simulations: a 2500 water molecule nanodrop with 68 Na(+) and 60 Cl(-) ions (an initial net charge of z = +8), and (2) a 1000 water molecule nanodrop with 65 Na(+) and 60 Cl(-) ions (an initial net charge of z = +5). Specifically, we used MD simulations to examine the validity of a model for the neutral evaporation rate incorporating both the Kelvin (surface curvature) and Thomson (electrostatic) influences, while both MD simulations and experimental measurements were compared to predictions of the ion evaporation rate equation of Labowsky et al. [Anal. Chim. Acta, 2000, 406, 105-118]. Within a single fit parameter, we find excellent agreement between simulated and modeled neutral evaporation rates for nanodrops with solute volume fractions below 0.30. Similarly, MD simulation inferred ion evaporation rates are in excellent agreement with predictions based on the Labowsky et al. equation. Measurements of the sizes and charge states of ESI generated NaCl clusters suggest that the charge states of these clusters are governed by ion evaporation, however, ion evaporation appears to have occurred with lower activation energies in experiments than was anticipated based on analytical calculations as well as MD simulations. Several possible reasons for this discrepancy are discussed.

Synthesis and characterisation of co-evaporated tin sulphide thin films

Science.gov (United States)

Koteeswara Reddy, N.; Ramesh, K.; Ganesan, R.; Ramakrishna Reddy, K. T.; Gunasekhar, K. R.; Gopal, E. S. R.

2006-04-01

Tin sulphide films were grown at different substrate temperatures by a thermal co-evaporation technique. The crystallinity of the films was evaluated from X-ray diffraction studies. Single-phase SnS films showed a strong (040) orientation with an orthorhombic crystal structure and a grain size of 0.12 μm. The films showed an electrical resistivity of 6.1 Ω cm with an activation energy of 0.26 eV. These films exhibited an optical band gap of 1.37 eV and had a high optical absorption coefficient (>104 cm-1) above the band-gap energy. The results obtained were analysed to evaluate the potentiality of the co-evaporated SnS films as an absorber layer in solar photovoltaic devices.

Drivers of atmospheric evaporative demand during African droughts

Science.gov (United States)

Blakeley, S. L.; Harrison, L.; Hobbins, M.; Dewes, C.; Funk, C. C.; Shukla, S.; Husak, G. J.

2017-12-01

Seeking to advance the practice of famine early warning across sub-Saharan Africa we illuminate past drivers of high-impact droughts to gain a better understanding of the evaporative processes involved in drought dynamics. Atmospheric evaporative demand (ETo) is often used to estimate plant water balance and drought impacts to vegetation, and previously demonstrated linkages between precipitation, temperature, and ETo need to be better understood. This work is timely as new data streams will enable near-real-time monitoring of ETo and incorporation of ETo forecasts into seasonal outlooks for African growing seasons. For historical droughts during major growing seasons in sub-Saharan Africa, we evaluate ETo and identify main drivers for drought cases-identified based on below-normal precipitation during the wettest three months of the growing season-and contrast these with the ETo drivers that dominate in wetter years (we also consider droughts triggered by above normal ETo). Our focus is on regions of Africa where adequate precipitation is important for productive agriculture and pastoral activities and where evaporative demand might exacerbate moisture limitations. It is expected that important ETo drivers are partly connected with precipitation-related processes but that there are variations between regions and events. The goal here is to provide a generalized understanding of what aspects of evaporative demand historically have posed an additional hazard to plant stress and how precipitation outcomes are responsible for the ETo drivers. In addition, we explore whether there have been discernible changes through time in regard to ETo drivers during below-normal precipitation seasons. Upper and lower terciles of CHIRPS precipitation are used to identify anomalous dry and wet cases. The ETo dataset spans the 1980-near present period and is calculated following ASCE's formulation of Penman-Monteith method driven by daily temperature, humidity, wind speed, and solar

Bubble-assisted film evaporation correlation for saline water at sub-atmospheric pressures in horizontal-tube evaporator

KAUST Repository

Shahzad, Muhammad Wakil

2013-01-01

In falling film evaporators, the overall heat transfer coefficient is controlled by film thickness, velocity, liquid properties and the temperature differential across the film layer. This article presents the heat transfer behavior for evaporative film boiling on horizontal tubes, but working at low pressures of 0.93-3.60 kPa (corresponding solution saturation temperatures of 279-300 K) as well as seawater salinity of 15,000 to 90,000 mg/l or ppm. Owing to a dearth of literature on film-boiling at these conditions, the article is motivated by the importance of evaporative film boiling in the desalination processes such as the multi-effect distillation (MED) or multi-stage flashing (MSF): It is observed that in addition to the above-mentioned parameters, evaporative heat transfer of seawater is affected by the emergence of micro-bubbles within the thin film layer, particularly when the liquid saturation temperatures drop below 298 K (3.1 kPa). Such micro bubbles are generated near to the tube wall surfaces and they enhanced the heat transfer by two or more folds when compared with the predictions of conventional evaporative film boiling. The appearance of micro-bubbles is attributed to the rapid increase in the specific volume of vapor, i.e., dv/dT, at low saturation temperature conditions. A new correlation is thus proposed in this article and it shows good agreement to the measured data with an experimental uncertainty of 8% and regression RMSE of 3.5%. © 2012 Elsevier Ltd. All rights reserved.

Evaporation measurement in the validation drift - part 3

International Nuclear Information System (INIS)

Watanabe, K.

1991-12-01

Two evaporation measurement series were carried out during April 3 - April 18, 1990 and May 27 . June 13, 1991 respectively in the validation drift. The first and the second measurement series were performed about one month and 14 months after the excavation, respectively. The results obtained by these measurement series are compared to each other with the aim to know the evaporation rate change during the period between these series. The evaporation rate from the matrix part of the rock mass decreased from the first measurement to the second. The average evaporation rate obtained from the second measurement series was about 1/4 of the first measurement. The frequency distribution of the evaporation rate measured in the second measurement series was more concentrated compared to the distribution of the first measurement series. The frequency distribution obtained by the second measurement seems to be approximated with a normal distribution curve. The evaporation rate from some major fractures did not decrease so much compared to the rate on the matrix part. The average rate obtained in the second measurement series on some fractures was about 80% of that of the first measurement series. The reduction of the evaporation rate may be due to the creation of an unsaturated zone around the drift. As the permeability decreases significantly when the saturation of the rock mass decreases, the evaporation rate or in the other word, the inflow rate must become smaller. An attempt was made to estimate the ratio between the matrix flow and the fracture flow. However, a detailed study is needed on unsaturated flow in rock mass for precise estimation. (au)

Evaporator bulb

International Nuclear Information System (INIS)

Stoll, W.

1977-01-01

In order to prevent the hazard of a possible excursion in an evaporator bulb for radioactive liquids there is provided in the bottom of the vessel a recess filled with a neutron-absorbing and moderating material. The bottom drain pipe is coming out sideways and connected with a heated pipe feeding above into the vessel tangentially. (TK) [de

Titanium dioxide induces apoptotic cell death through reactive oxygen species-mediated Fas upregulation and Bax activation

Directory of Open Access Journals (Sweden)

Yoon TH

2012-03-01

Full Text Available Ki-Chun Yoo1, Chang-Hwan Yoon1, Dongwook Kwon2, Kyung-Hwan Hyun1, Soo Jung Woo1, Rae-Kwon Kim1, Eun-Jung Lim1, Yongjoon Suh1, Min-Jung Kim1, Tae Hyun Yoon2, Su-Jae Lee11Laboratory of Molecular Biochemistry, 2Laboratory of Nanoscale Characterization and Environmental Chemistry, Department of Chemistry, Hanyang University, Seoul, Republic of KoreaBackground: Titanium dioxide (TiO2 has been widely used in many areas, including biomedicine, cosmetics, and environmental engineering. Recently, it has become evident that some TiO2 particles have a considerable cytotoxic effect in normal human cells. However, the molecular basis for the cytotoxicity of TiO2 has yet to be defined.Methods and results: In this study, we demonstrated that combined treatment with TiO2 nanoparticles sized less than 100 nm and ultraviolet A irradiation induces apoptotic cell death through reactive oxygen species-dependent upregulation of Fas and conformational activation of Bax in normal human cells. Treatment with P25 TiO2 nanoparticles with a hydrodynamic size distribution centered around 70 nm (TiO2P25–70 together with ultraviolet A irradiation-induced caspase-dependent apoptotic cell death, accompanied by transcriptional upregulation of the death receptor, Fas, and conformational activation of Bax. In line with these results, knockdown of either Fas or Bax with specific siRNA significantly inhibited TiO2-induced apoptotic cell death. Moreover, inhibition of reactive oxygen species with an antioxidant, N-acetyl-L-cysteine, clearly suppressed upregulation of Fas, conformational activation of Bax, and subsequent apoptotic cell death in response to combination treatment using TiO2P25–70 and ultraviolet A irradiation.Conclusion: These results indicate that sub-100 nm sized TiO2 treatment under ultraviolet A irradiation induces apoptotic cell death through reactive oxygen species-mediated upregulation of the death receptor, Fas, and activation of the preapoptotic protein

Optimal control of evaporator and washer plants

International Nuclear Information System (INIS)

Niemi, A.J.

1989-01-01

Tests with radioactive tracers were used for experimental analysis of a multiple-effect evaporator plant. The residence time distribution of the liquor in each evaporator was described by one or two perfect mixers with time delay and by-pass flow terms. The theoretical model of a single evaporator unit was set up on the basis of its instantaneous heat and mass balances and such models were fitted to the test data. The results were interpreted in terms of physical structures of the evaporators. Further model parameters were evaluated by conventional step tests and by measurements of process variables at one or more steady states. Computer simulation and comparison with the experimental results showed that the model produces a satisfactory response to solids concentration input and could be extended to cover the steam feed and liquor flow inputs. An optimal feedforward control algorithm was developed for a two unit, co-current evaporator plant. The control criterion comprised the deviations of the final solids content of liquor and the consumption of fresh steam, from their optimal steady-state values. In order to apply the algorithm, the model of the solids in liquor was reduced to two nonlinear differential equations. (author)

Evaporation rate of nucleating clusters.

Science.gov (United States)

Zapadinsky, Evgeni

2011-11-21

The Becker-Döring kinetic scheme is the most frequently used approach to vapor liquid nucleation. In the present study it has been extended so that master equations for all cluster configurations are included into consideration. In the Becker-Döring kinetic scheme the nucleation rate is calculated through comparison of the balanced steady state and unbalanced steady state solutions of the set of kinetic equations. It is usually assumed that the balanced steady state produces equilibrium cluster distribution, and the evaporation rates are identical in the balanced and unbalanced steady state cases. In the present study we have shown that the evaporation rates are not identical in the equilibrium and unbalanced steady state cases. The evaporation rate depends on the number of clusters at the limit of the cluster definition. We have shown that the ratio of the number of n-clusters at the limit of the cluster definition to the total number of n-clusters is different in equilibrium and unbalanced steady state cases. This causes difference in evaporation rates for these cases and results in a correction factor to the nucleation rate. According to rough estimation it is 10(-1) by the order of magnitude and can be lower if carrier gas effectively equilibrates the clusters. The developed approach allows one to refine the correction factor with Monte Carlo and molecular dynamic simulations.

Recent progress in design of evaporators and condensors

International Nuclear Information System (INIS)

Semeria, R.

1981-01-01

Heat transfer coefficients for boilers and condensors have been improved very much during the two last decades. Particularly, for sea water desalination plants, the falling liquid film evaporator and the horizontal tube evaporator were improved for having good performances with small temperature differences. A discussion follows of research undertaken at C.E.N. Grenoble (France) which leads to heat transfer enhancement in evaporators or in condensors. Principles are investigated such as role of interfaces and effect of a good nucleation in boiling. Examples of improved techniques are given; namely: - evaporators: falling film, fluted tubes, specific liquids, - condensors: fluted tubes, special materials such as titanium, droplet condensation [fr

An automated tunnel evaporation measurement system for confined spaces

Science.gov (United States)

Salve, Rohit

2002-04-01

An automated tunnel evaporation-rate measurement system (TEMS) has been designed to measure automatically the evaporation from a cylinder 0·30 m in diameter and 0·10 m tall. This cylinder continuously maintains a constant height of water, with losses to evaporation replenished from a stilling cylinder connected to a water reservoir. The evaporation rate is measured by a transducer located at the bottom of the stilling well. The TEMS was tested over a period of 3 months in an underground research facility with relatively strong wind effects, changing temperature, and changing humidity. During this period, the TEMS continued to function uninterrupted, automatically measuring the evaporation amounts along a tunnel and an enclosed niche. These observations suggest that this tool can be useful for investigations of evaporation processes both in enclosed and ventilated environments. Published in 2002 by John Wiley & Sons, Ltd.

CFD Analysis of Evaporation-Condensation Phenomenon In an Evaporation Chamber of Natural Vacuum Solar Desalination

Science.gov (United States)

Ambarita, H.; Ronowikarto, A. D.; Siregar, R. E. T.; Setyawan, E. Y.

2018-01-01

Desalination technologies is one of solutions for water scarcity. With using renewable energy, like solar energy, wind energy, and geothermal energy, expected will reduce the energy demand. This required study on the modeling and transport parameters determination of natural vacuum solar desalination by using computational fluid dynamics (CFD) method to simulate the model. A three-dimensional case, two-phase model was developed for evaporation-condensation phenomenon in natural vacuum solar desalination. The CFD simulation results were compared with the avalaible experimental data. The simulation results shows inthat there is a phenomenon of evaporation-condensation in an evaporation chamber. From the simulation, the fresh water productivity is 2.21 litre, and from the experimental is 2.1 litre. This study shows there’s an error of magnitude 0.4%. The CFD results also show that, vacuum pressure will degrade the saturation temperature of sea water.

Quantifying Evaporation in a Permeable Pavement System

Science.gov (United States)

Studies quantifying evaporation from permeable pavement systems are limited to a few laboratory studies and one field application. This research quantifies evaporation for a larger-scale field application by measuring the water balance from lined permeable pavement sections. Th...

Modelling hourly rates of evaporation from small lakes

Directory of Open Access Journals (Sweden)

R. J. Granger

2011-01-01

Full Text Available The paper presents the results of a field study of open water evaporation carried out on three small lakes in Western and Northern Canada. In this case small lakes are defined as those for which the temperature above the water surface is governed by the upwind land surface conditions; that is, a continuous boundary layer exists over the lake, and large-scale atmospheric effects such as entrainment do not come into play. Lake evaporation was measured directly using eddy covariance equipment; profiles of wind speed, air temperature and humidity were also obtained over the water surfaces. Observations were made as well over the upwind land surface.

The major factors controlling open water evaporation were examined. The study showed that for time periods shorter than daily, the open water evaporation bears no relationship to the net radiation; the wind speed is the most significant factor governing the evaporation rates, followed by the land-water temperature contrast and the land-water vapour pressure contrast. The effect of the stability on the wind field was demonstrated; relationships were developed relating the land-water wind speed contrast to the land-water temperature contrast. The open water period can be separated into two distinct evaporative regimes: the warming period in the Spring, when the land is warmer than the water, the turbulent fluxes over water are suppressed; and the cooling period, when the water is warmer than the land, the turbulent fluxes over water are enhanced.

Relationships were developed between the hourly rates of lake evaporation and the following significant variables and parameters (wind speed, land-lake temperature and humidity contrasts, and the downwind distance from shore. The result is a relatively simple versatile model for estimating the hourly lake evaporation rates. The model was tested using two independent data sets. Results show that the modelled evaporation follows the observed values

Evaporation-driven instability of the precorneal tear film.

Science.gov (United States)

Peng, Cheng-Chun; Cerretani, Colin; Braun, Richard J; Radke, C J

2014-04-01

Tear-film instability is widely believed to be a signature of eye health. When an interblink is prolonged, randomly distributed ruptures occur in the tear film. "Black spots" and/or "black streaks" appear in 15 to 40 s for normal individuals. For people who suffer from dry eye, tear-film breakup time (BUT) is typically less than a few seconds. To date, however, there is no satisfactory quantitative explanation for the origin of tear rupture. Recently, it was proposed that tear-film breakup is related to locally high evaporative thinning. A spatial variation in the thickness of the tear-film lipid layer (TFLL) may lead to locally elevated evaporation and subsequent tear-film breakup. We examine the local-evaporation-driven tear-film-rupture hypothesis in a one-dimensional (1-D) model for the evolution of a thin aqueous tear film overriding the cornea subject to locally elevated evaporation at its anterior surface and osmotic water influx at its posterior surface. Evaporation rate depends on mass transfer both through the coating lipid layer and through ambient air. We establish that evaporation-driven tear-film breakup can occur under normal conditions but only for higher aqueous evaporation rates. Predicted roles of environmental conditions, such as wind speed and relative humidity, on tear-film stability agree with clinical observations. More importantly, locally elevated evaporation leads to hyperosmolar spots in the tear film and, hence, vulnerability to epithelial irritation. In addition to evaporation rate, tear-film instability depends on the strength of healing flow from the neighboring region outside the breakup region, which is determined by the surface tension at the tear-film surface and by the repulsive thin-film disjoining pressure. This study provides a physically consistent and quantitative explanation for the formation of black streaks and spots in the human tear film during an interblink. Copyright © 2013 Elsevier B.V. All rights reserved.

Reinstatement versus Reactivation Effects on Active Memory in Infants.

Science.gov (United States)

Adler, Scott A.; Rovee-Collier, Carolyn; Wilk, Amy

2000-01-01

Four experiments examined whether reinstatement and reactivation reminder paradigms affected memory performance of 102 three-month-olds. Results indicated that a single reinstatement protracted retention twice as long after training as a single reactivation. The novelty of the reminder stimulus also affected duration and specificity of memory in…

Assessment of water droplet evaporation mechanisms on hydrophobic and superhydrophobic substrates.

Science.gov (United States)

Pan, Zhenhai; Dash, Susmita; Weibel, Justin A; Garimella, Suresh V

2013-12-23

Evaporation rates are predicted and important transport mechanisms identified for evaporation of water droplets on hydrophobic (contact angle ~110°) and superhydrophobic (contact angle ~160°) substrates. Analytical models for droplet evaporation in the literature are usually simplified to include only vapor diffusion in the gas domain, and the system is assumed to be isothermal. In the comprehensive model developed in this study, evaporative cooling of the interface is accounted for, and vapor concentration is coupled to local temperature at the interface. Conjugate heat and mass transfer are solved in the solid substrate, liquid droplet, and surrounding gas. Buoyancy-driven convective flows in the droplet and vapor domains are also simulated. The influences of evaporative cooling and convection on the evaporation characteristics are determined quantitatively. The liquid-vapor interface temperature drop induced by evaporative cooling suppresses evaporation, while gas-phase natural convection acts to enhance evaporation. While the effects of these competing transport mechanisms are observed to counterbalance for evaporation on a hydrophobic surface, the stronger influence of evaporative cooling on a superhydrophobic surface accounts for an overprediction of experimental evaporation rates by ~20% with vapor diffusion-based models. The local evaporation fluxes along the liquid-vapor interface for both hydrophobic and superhydrophobic substrates are investigated. The highest local evaporation flux occurs at the three-phase contact line region due to proximity to the higher temperature substrate, rather than at the relatively colder droplet top; vapor diffusion-based models predict the opposite. The numerically calculated evaporation rates agree with experimental results to within 2% for superhydrophobic substrates and 3% for hydrophobic substrates. The large deviations between past analytical models and the experimental data are therefore reconciled with the

Influence of surface wettability on transport mechanisms governing water droplet evaporation.

Science.gov (United States)

Pan, Zhenhai; Weibel, Justin A; Garimella, Suresh V

2014-08-19

Prediction and manipulation of the evaporation of small droplets is a fundamental problem with importance in a variety of microfluidic, microfabrication, and biomedical applications. A vapor-diffusion-based model has been widely employed to predict the interfacial evaporation rate; however, its scope of applicability is limited due to incorporation of a number of simplifying assumptions of the physical behavior. Two key transport mechanisms besides vapor diffusion-evaporative cooling and natural convection in the surrounding gas-are investigated here as a function of the substrate wettability using an augmented droplet evaporation model. Three regimes are distinguished by the instantaneous contact angle (CA). In Regime I (CA ≲ 60°), the flat droplet shape results in a small thermal resistance between the liquid-vapor interface and substrate, which mitigates the effect of evaporative cooling; upward gas-phase natural convection enhances evaporation. In Regime II (60 ≲ CA ≲ 90°), evaporative cooling at the interface suppresses evaporation with increasing contact angle and counterbalances the gas-phase convection enhancement. Because effects of the evaporative cooling and gas-phase convection mechanisms largely neutralize each other, the vapor-diffusion-based model can predict the overall evaporation rates in this regime. In Regime III (CA ≳ 90°), evaporative cooling suppresses the evaporation rate significantly and reverses entirely the direction of natural convection induced by vapor concentration gradients in the gas phase. Delineation of these counteracting mechanisms reconciles previous debate (founded on single-surface experiments or models that consider only a subset of the governing transport mechanisms) regarding the applicability of the classic vapor-diffusion model. The vapor diffusion-based model cannot predict the local evaporation flux along the interface for high contact angle (CA ≥ 90°) when evaporative cooling is strong and the

Thiazolidinone prodrugs activated by reactive oxygen species for use in the treatment of inflammatory diseases and cancer

DEFF Research Database (Denmark)

2018-01-01

Prodrugs activated predominantly or exclusively in inflammatory tissue, more particularly prodrugs of methotrexate and derivatives thereof, which are selectively activated by Reactive Oxygen Species (ROS) in inflammatory tissues associated with cancer and inflammatory diseases, as well as method...

Adsorption of Reactive Blue 171 from Aqueous Solution using Low Cost Activated Carbon Prepared from Agricultural Solid Waste: Albizia amara

Directory of Open Access Journals (Sweden)

K. Anitha

2015-07-01

Full Text Available The adsorption of Reactive Blue 171 (Reactive Dye from aqueous solution using activated carbon prepared from Albizia amara pod shell waste as an adsorbent have been carried out. The experimental adsorption data fitted reasonably well to Langmuir and Freundlich adsorption isotherms. Kinetic parameters as a function of Initial dye concentration have been calculated and the kinetic data were substituted in Pseudo First Order, Elovich and Pseudo Second order equations. A probable explanation is offered to account for the results of kinetic study. The thermodynamic parameter enthalpy change (∆H suggests the exothermic nature of absorption of Reactive Blue 171 onto activated Albizia amara pod shell waste carbon.

Evaporation behaviour of different organic effluents from open surfaces.

Science.gov (United States)

Jhorar, B S; Malik, R S

1993-01-01

Production of large quantities of effluents from different industrial units and the problems of their disposal necessitated this evaporation study. The evaporation of water, sewage water, oil refinery effluent, papermill effluent and liquor distillery effluent was observed in glass beakers when placed (i) in an oven at 60 degrees C and (ii) in screen house for 30 days, by periodically weighing of the beakers. In other experiments, the effect of increasing the frequency of stirring on increasing the evaporation efficiency of the liquor distillery effluent (ELD) was examined in detail. All of the organic effluents except ELD had similar evaporation behaviours as water, but formation of a self-forming film caused the evaporation of ELD to be considerably lower. Resistance to evaporation caused by this film was found to be a decreasing function of the frequency of stirring. This study has a bearing on improving the efficiency of evaporation lagoons, and three stirrings in a day with a manually drawn stirrer in a full-scale lagoon are proposed as a practical and economically viable technique to save 44% of lagoon land in arid and semi-arid regions of the world.

Steady parallel flow in an evaporating fluid heated from sidewalls

International Nuclear Information System (INIS)

Das, Kausik S.

2009-01-01

Evaporation is ubiquitous in nature, but very few attempts have been made in the past to couple the effects of evaporation with fluid flow behavior. In this theoretical paper we have discussed the effects of evaporation on the dynamics of steady state thermocapillary convection in a two-dimensional rectangular container. The liquid is heated by differentially heated sidewalls and mass loss from the interface due to evaporation is compensated by the liquid entering into the container through a lower inlet, thus keeping the thickness of the liquid layer constant. We show that for an evaporating liquid one can obtain a plane parallel base state profile which depends on the evaporative mass flux.

Cooling clothing utilizing water evaporation

DEFF Research Database (Denmark)

Sakoi, Tomonori; Tominaga, Naoto; Melikov, Arsen Krikor

2014-01-01

. To prevent wet discomfort, the T-shirt was made of a polyester material having a water-repellent silicon coating on the inner surface. The chest, front upper arms, and nape of the neck were adopted as the cooling areas of the human body. We conducted human subject experiments in an office with air......We developed cooling clothing that utilizes water evaporation to cool the human body and has a mechanism to control the cooling intensity. Clean water was supplied to the outer surface of the T-shirt of the cooling clothing, and a small fan was used to enhance evaporation on this outer surface...... temperature ranging from 27.4 to 30.7 °C to establish a suitable water supply control method. A water supply control method that prevents water accumulation in the T-shirt and water dribbling was validated; this method is established based on the concept of the water evaporation capacity under the applied...

Structural and reactivity models for copper oxygenases: cooperative effects and novel reactivities.

Science.gov (United States)

Serrano-Plana, Joan; Garcia-Bosch, Isaac; Company, Anna; Costas, Miquel

2015-08-18

Dioxygen is widely used in nature as oxidant. Nature itself has served as inspiration to use O2 in chemical synthesis. However, the use of dioxygen as an oxidant is not straightforward. Its triplet ground-state electronic structure makes it unreactive toward most organic substrates. In natural systems, metalloenzymes activate O2 by reducing it to more reactive peroxide (O2(2-)) or superoxide (O2(-)) forms. Over the years, the development of model systems containing transition metals has become a convenient tool for unravelling O2-activation mechanistic aspects and reproducing the oxidative activity of enzymes. Several copper-based systems have been developed within this area. Tyrosinase is a copper-based O2-activating enzyme, whose structure and reactivity have been widely studied, and that serves as a paradigm for O2 activation at a dimetal site. It contains a dicopper center in its active site, and it catalyzes the regioselective ortho-hydroxylation of phenols to catechols and further oxidation to quinones. This represents an important step in melanin biosynthesis and it is mediated by a dicopper(II) side-on peroxo intermediate species. In the present accounts, our research in the field of copper models for oxygen activation is collected. We have developed m-xylyl linked dicopper systems that mimick structural and reactivity aspects of tyrosinase. Synergistic cooperation of the two copper(I) centers results in O2 binding and formation of bis(μ-oxo)dicopper(III) cores. These in turn bind and ortho-hydroxylate phenolates via an electrophilic attack of the oxo ligand over the arene. Interestingly the bis(μ-oxo)dicopper(III) cores can also engage in ortho-hydroxylation-defluorination of deprotonated 2-fluorophenols, substrates that are well-known enzyme inhibitors. Analysis of Cu2O2 species with different binding modes show that only the bis(μ-oxo)dicopper(III) cores can mediate the reaction. Finally, the use of unsymmetric systems for oxygen activation is a field

Production of active lysozyme films by matrix assisted pulsed laser evaporation at 355 nm

DEFF Research Database (Denmark)

Purice, Andreea; Schou, Jørgen; Kingshott, P.

2007-01-01

Thin lysozyme films have been produced in a dry environment by MAPLE (matrix assisted pulsed laser evaporation) from a water ice matrix irradiated by laser light at 355 nm above the absorption threshold of the protein. A significant part of the lysozyme molecules are transferred to the film without...

Evaporation of Sunscreen Films: How the UV Protection Properties Change.

Science.gov (United States)

Binks, Bernard P; Brown, Jonathan; Fletcher, Paul D I; Johnson, Andrew J; Marinopoulos, Ioannis; Crowther, Jonathan M; Thompson, Michael A

2016-06-01

We have investigated the evaporation of thin sunscreen films and how the light absorption and the derived sun protection factor (SPF) change. For films consisting of solutions of common UV filters in propylene glycol (PG) as solvent, we show how evaporation generally causes three effects. First, the film area can decrease by dewetting leading to a transient increase in the average film thickness. Second, the film thins by evaporative loss of the solvent. Third, precipitation of the UV filter occurs when solvent loss causes the solubility limit to be reached. These evaporation-induced changes cause the UV absorbance of the film to decrease with resultant loss of SPF over the time scale of the evaporation. We derive an approximate model which accounts semiquantitatively for the variation of SPF with evaporation. Experimental results for solutions of different UV filters on quartz, different skin mimicking substrates, films with added nanoparticles, films with an added polymer and films with fast-evaporating decane as solvent (instead of slow evaporating PG) are discussed and compared with model calculations. Addition of either nanoparticles or polymer suppress film dewetting. Overall, it is hoped that the understanding gained about the mechanisms whereby film evaporation affects the SPF will provide useful guidance for the formulation of more effective sunscreens.

Evaporation experiments and modelling for glass melts

NARCIS (Netherlands)

Limpt, J.A.C. van; Beerkens, R.G.C.

2007-01-01

A laboratory test facility has been developed to measure evaporation rates of different volatile components from commercial and model glass compositions. In the set-up the furnace atmosphere, temperature level, gas velocity and batch composition are controlled. Evaporation rates have been measured

The Activation of Non-evaporable Getters Monitored by AES, XPS, SSIMS and Secondary Electron Yield Measurements

CERN Document Server

Scheuerlein, C

2002-01-01

In this thesis the potential of the three classical surface analysis techniques Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS) and static secondary ion mass spectrometry (SSIMS) for the characterisation of non-evaporable getter (NEG) materials is assessed and artefacts are described. The various NEG samples have been analysed in the context of the development of NEG thin film coatings for use in accelerator ultra high vacuum (UHV) systems. The secondary electron yield (SEY), which is a functional surface property of great importance for the application of NEG to accelerators, has been measured. The maximum SEY of an air exposed TiZr and TiZrV coating can be reduced from above 2.0 to below 1.1 during a 2 h heat treatment at 250 and 200 °C, respectively. Saturating an activated TiZrV surface in UHV increases the maximum SEY by about 0.1. Thus, in UHV the SEY of an activated NEG coating does not exceed the threshold value of 1.35, above which multipacting is predicted to occur in th...

Reactive Landing of Dendrimer Ions onto Activated Self-assembled Monolayer Surfaces

Energy Technology Data Exchange (ETDEWEB)

Hu, Qichi; Laskin, Julia

2014-02-06

The reactivity of gaseous, amine-terminated polyamidoamine (PAMAM) dendrimer ions with activated self-assembled monolayer (SAM) surfaces terminated with N-hydroxysuccinimidyl ester groups (NHS-SAM) is examined using mass-selected ion deposition combined with in situ infrared reflection absorption spectroscopy (IRRAS). The reaction extent is determined from depletion of the infrared band at 1753 cm-1, corresponding to the stretching vibration of the NHS carbonyl groups following ion deposition. For reaction yields below 10%, NHS band depletion follows a linear dependence on the ion dose. By comparing the kinetics plots obtained for 1,12-dodecanediamine and different generations of dendrimer ions (G0–G3) containing 4, 8, 16, and 32 terminal amino group, we demonstrate that the relative reaction efficiency increases linearly with the number of NH2 groups in the molecule. This finding is rationalized assuming the formation of multiple amide bonds upon collision of higher-generation dendrimers with NHS-SAM. Furthermore, by comparing the NHS band depletion following deposition of [M+4H]4+ ions of the G2 dendrimer at 30, 80, and 120 eV, we demonstrate that the ion’s kinetic energy has no measurable effect on reaction efficiency. Similarly, the ion’s charge state only has a minor effect on the reactive landing efficiency of dendrimer ions. Our results indicate that reactive landing is an efficient approach for highly selective covalent immobilization of complex multifunctional molecules onto organic surfaces terminated with labile functional groups.

Half-of-the-sites reactivity of outer-membrane phospholipase A against an active-site-directed inhibitor.

Science.gov (United States)

Ubarretxena-Belandia, I; Cox, R C; Dijkman, R; Egmond, M R; Verheij, H M; Dekker, N

1999-03-01

The reaction of a novel active-site-directed phospholipase A1 inhibitor with the outer-membrane phospholipase A (OMPLA) was investigated. The inhibitor 1-p-nitrophenyl-octylphosphonate-2-tridecylcarbamoyl-3-et hanesulfonyl -amino-3-deoxy-sn-glycerol irreversibly inactivated OMPLA. The inhibition reaction did not require the cofactor calcium or an unprotonated active-site His142. The inhibition of the enzyme solubilized in hexadecylphosphocholine micelles was characterized by a rapid (t1/2 = 20 min) and complete loss of enzymatic activity, concurrent with the covalent modification of 50% of the active-site serines, as judged from the amount of p-nitrophenolate (PNP) released. Modification of the remaining 50% occurred at a much lower rate, indicative of half-of-the-sites reactivity against the inhibitor of this dimeric enzyme. Inhibition of monomeric OMPLA solubilized in hexadecyl-N,N-dimethyl-1-ammonio-3-propanesulfonate resulted in an equimolar monophasic release of PNP, concurrent with the loss of enzymatic activity (t1/2 = 14 min). The half-of-the-sites reactivity is discussed in view of the dimeric nature of this enzyme.

Mapping energetics of atom probe evaporation events through first principles calculations.

Science.gov (United States)

Peralta, Joaquín; Broderick, Scott R; Rajan, Krishna

2013-09-01

The purpose of this work is to use atomistic modeling to determine accurate inputs into the atom probe tomography (APT) reconstruction process. One of these inputs is evaporation field; however, a challenge occurs because single ions and dimers have different evaporation fields. We have calculated the evaporation field of Al and Sc ions and Al-Al and Al-Sc dimers from an L1₂-Al₃Sc surface using ab initio calculations and with a high electric field applied to the surface. The evaporation field is defined as the electric field at which the energy barrier size is calculated as zero, corresponding to the minimum field that atoms from the surface can break their bonds and evaporate from the surface. The evaporation field of the surface atoms are ranked from least to greatest as: Al-Al dimer, Al ion, Sc ion, and Al-Sc dimer. The first principles results were compared with experimental data in the form of an ion evaporation map, which maps multi-ion evaporations. From the ion evaporation map of L1₂-Al₃Sc, we extract relative evaporation fields and identify that an Al-Al dimer has a lower evaporation field than an Al-Sc dimer. Additionally, comparatively an Al-Al surface dimer is more likely to evaporate as a dimer, while an Al-Sc surface dimer is more likely to evaporate as single ions. These conclusions from the experiment agree with the ab initio calculations, validating the use of this approach for modeling APT energetics. Copyright © 2013 Elsevier B.V. All rights reserved.

Isotope effects accompanying evaporation of water from leaky containers.

Science.gov (United States)

Rozanski, Kazimierz; Chmura, Lukasz

2008-03-01

Laboratory experiments aimed at quantifying isotope effects associated with partial evaporation of water from leaky containers have been performed under three different settings: (i) evaporation into dry atmosphere, performed in a dynamic mode, (ii) evaporation into dry atmosphere, performed in a static mode, and (iii) evaporation into free laboratory atmosphere. The results demonstrate that evaporative enrichment of water stored in leaky containers can be properly described in the framework of the Craig-Gordon evaporation model. The key parameter controlling the degree of isotope enrichment is the remaining fraction of water in the leaking containers. Other factors such as temperature, relative humidity, or extent of kinetic fractionation play only minor roles. Satisfactory agreement between observed and predicted isotope enrichments for both (18)O and (2)H in experiments for the case of evaporation into dry atmosphere could be obtained only when molecular diffusivity ratios of isotope water molecules as suggested recently by Cappa et al. [J. Geophys. Res., 108, 4525-4535, (2003).] were adopted. However, the observed and modelled isotope enrichments for (2)H and (18)O could be reconciled also for the ratios of molecular diffusivities obtained by Merlivat [J. Chem. Phys., 69, 2864-2871 (1978).], if non-negligible transport resistance in the viscous liquid sub-layer adjacent to the evaporating surface is considered. The evaporation experiments revealed that the loss of mass of water stored in leaky containers in the order of 1%, will lead to an increase of the heavy isotope content in this water by ca. 0.35 and 1.1 per thousand, for delta (18)O and delta (2)H, respectively.

Physical activity and negative affective reactivity in daily life.

Science.gov (United States)

Puterman, Eli; Weiss, Jordan; Beauchamp, Mark R; Mogle, Jacqueline; Almeida, David M

2017-12-01

The results from experimental studies indicate that physically active individuals remain calmer and report less anxiety after the induction of a standardized stressor. The current study extends this research to real life, and examines whether daily physical activity attenuates negative affect that occurs in response to naturally occurring daily stressors. The current study used data from the second wave of the National Study of Daily Experiences, a sub-study of the second wave of the Midlife in the United States Study (MIDUS-II) of 2,022 individuals aged 33-84 questioned nightly for eight consecutive days about their general affect and affective responses to stressful events and their engagement in physical activity. Results indicated that while negative affect is significantly elevated on days with stressful events compared to days free of events in all individuals, these effects are attenuated in those who remain physically active when compared to those who were underactive. This was also true for any day participants were physically active. Importantly, negative affect in response to any specific stressor was reduced the closer in time that the stressor occurred to the bout of exercise in underactive participants, while, in active participants, negative affect in response to any stressor remained low throughout the entire day that participants reported that they were active. Given the significant mental and physical health implications of elevated affective reactivity observed in previous studies, the current study sheds further light on the importance of remaining physically active in times of stress. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

PFR evaporator leak

International Nuclear Information System (INIS)

Smedley, J.A.

1975-01-01

PFR has three heat removal circuits each one having an evaporator, superheater, reheater; all separate units. The status of the system was that circuit No 3 was steaming with 10 MW thermal nuclear power; No 1 circuit was filled with sodium but with the evaporator awaiting modification to cure gas entrainment problems already reported. The leak was in No 2 circuit and was located in the evaporator unit. The evaporator is rated at 120 M thermal at full power and as such is a large unit. The circuit was filled with both sodium and water for the first time three weeks before the conference so it was recent history being reported and therefore any figures quoted should be taken as indicative only. The history of the steam generator was that it was built at works to a very high standard and underwent all the usual tests of strength, inspection of welds and helium leak testing. The steam generator is of U tube design with a tube plate to which the boiler tubes are welded, with all the welds in one of two gas spaces. The inlet and outlet sides are separated by a baffle and the salient features are illustrated in the attached figure. The unit achieved a leak tightness better than the detection limit in the helium leak test at works. This limit was assessed as being less than an equivalent leak of 10 -6 g/s water under steam generator service conditions. However even though all the steam generator units passed this test at works a further test was carried out when the circuits had been completed. The test was carried out during commissioning after sodium filling and with the units hot. The method was to introduce a mixture of helium/ argon at 500 pounds/square inch into the water side of the steam generators and measure the helium concentration in the sodium side gas spaces of the circuit. The test lasted many days and under these conditions the sensitivity is such that a leak equivalent to somewhere between 10 -7 to 10 -6 g/s equivalent water leak could be detected, i

PFR evaporator leak

Energy Technology Data Exchange (ETDEWEB)

Smedley, J A

1975-07-01

PFR has three heat removal circuits each one having an evaporator, superheater, reheater; all separate units. The status of the system was that circuit No 3 was steaming with 10 MW thermal nuclear power; No 1 circuit was filled with sodium but with the evaporator awaiting modification to cure gas entrainment problems already reported. The leak was in No 2 circuit and was located in the evaporator unit. The evaporator is rated at 120 M thermal at full power and as such is a large unit. The circuit was filled with both sodium and water for the first time three weeks before the conference so it was recent history being reported and therefore any figures quoted should be taken as indicative only. The history of the steam generator was that it was built at works to a very high standard and underwent all the usual tests of strength, inspection of welds and helium leak testing. The steam generator is of U tube design with a tube plate to which the boiler tubes are welded, with all the welds in one of two gas spaces. The inlet and outlet sides are separated by a baffle and the salient features are illustrated in the attached figure. The unit achieved a leak tightness better than the detection limit in the helium leak test at works. This limit was assessed as being less than an equivalent leak of 10{sup -6} g/s water under steam generator service conditions. However even though all the steam generator units passed this test at works a further test was carried out when the circuits had been completed. The test was carried out during commissioning after sodium filling and with the units hot. The method was to introduce a mixture of helium/ argon at 500 pounds/square inch into the water side of the steam generators and measure the helium concentration in the sodium side gas spaces of the circuit. The test lasted many days and under these conditions the sensitivity is such that a leak equivalent to somewhere between 10{sup -7} to 10{sup -6} g/s equivalent water leak could be

Structuring of polymer solutions upon solvent evaporation

NARCIS (Netherlands)

Schaefer, C.; van der Schoot, P.|info:eu-repo/dai/nl/102140618; Michels, J. J.

2015-01-01

The morphology of solution-cast, phase-separated polymers becomes finer with increasing solvent evaporation rate. We address this observation theoretically for a model polymer where demixing is induced by steady solvent evaporation. In contrast to what is the case for a classical, thermal quench

Shadow mask evaporation through monolayer modified nanostencils

NARCIS (Netherlands)

Kolbel, M.; Tjerkstra, R.W.; Brugger, J.P.; van Rijn, C.J.M.; Nijdam, W.; Huskens, Jurriaan; Reinhoudt, David

2002-01-01

Gradual clogging of the apertures of nanostencils used as miniature shadow masks in metal evaporations can be reduced by coating the stencil with self-assembled monolayers (SAM). This is quantified by the dimensions (height and volume) of gold features obtained by nanostencil evaporation as measured

Evaluation of malodor for automobile air conditioner evaporator by using laboratory-scale test cooling bench.

Science.gov (United States)

Kim, Kyung Hwan; Kim, Sun Hwa; Jung, Young Rim; Kim, Man Goo

2008-09-12

As one of the measures to improve the environment in an automobile, malodor caused by the automobile air-conditioning system evaporator was evaluated and analyzed using laboratory-scale test cooling bench. The odor was simulated with an evaporator test cooling bench equipped with an airflow controller, air temperature and relative humidity controller. To simulate the same odor characteristics that occur from automobiles, one previously used automobile air conditioner evaporator associated with unpleasant odors was selected. The odor was evaluated by trained panels and collected with aluminum polyester bags. Collected samples were analyzed by thermal desorption into a cryotrap and subsequent gas chromatographic separation, followed by simultaneous olfactometry, flame ionization detector and identified by atomic emission detection and mass spectrometry. Compounds such as alcohols, aldehydes, and organic acids were identified as responsible odor-active compounds. Gas chromatography/flame ionization detection/olfactometry combined sensory method with instrumental analysis was very effective as an odor evaluation method in an automobile air-conditioning system evaporator.

The simultaneous mass and energy evaporation (SM2E) model.

Science.gov (United States)

Choudhary, Rehan; Klauda, Jeffery B

2016-01-01

In this article, the Simultaneous Mass and Energy Evaporation (SM2E) model is presented. The SM2E model is based on theoretical models for mass and energy transfer. The theoretical models systematically under or over predicted at various flow conditions: laminar, transition, and turbulent. These models were harmonized with experimental measurements to eliminate systematic under or over predictions; a total of 113 measured evaporation rates were used. The SM2E model can be used to estimate evaporation rates for pure liquids as well as liquid mixtures at laminar, transition, and turbulent flow conditions. However, due to limited availability of evaporation data, the model has so far only been tested against data for pure liquids and binary mixtures. The model can take evaporative cooling into account and when the temperature of the evaporating liquid or liquid mixture is known (e.g., isothermal evaporation), the SM2E model reduces to a mass transfer-only model.

Rate control for electron gun evaporation

International Nuclear Information System (INIS)

Schellingerhout, A.J.G.; Janocko, M.A.; Klapwijk, T.M.; Mooij, J.E.

1989-01-01

Principles for obtaining high-quality rate control for electron gun evaporation are discussed. The design criteria for rate controllers are derived from this analysis. Results are presented which have been obtained with e-guns whose evaporation rate is controlled by a Wehnelt electrode or by sweeping of the electron beam. Further improvements of rate stability can be obtained by improved design of e-guns and power supplies

NWCF Evaporator Tank System 2001 Offgas Emissions Inventory

Energy Technology Data Exchange (ETDEWEB)

Boardman, Richard Doin; Lamb, Kenneth Mitchel; Matejka, Leon Anthony; Nenni, Joseph A

2002-02-01

An offgas emissions inventory and liquid stream characterization of the Idaho New Waste Calcining Facility (NWCF) Evaporator Tank System (ETS), formerly known as the High Level Liquid Waste Evaporator (HLLWE), has been completed. The emissions rates of volatile and semi-volatile organic compounds, multiple metals, particulate, and hydrochloric acid were measured in accordance with an approved Quality Assurance Project Plan (QAPjP) and Test Plan that invoked U.S. Environmental Protection Agency (EPA) standard sample collection and analysis procedures. Offgas samples were collected during the start up and at the end of evaporator batches when it was hypothesized the emissions would be at peak rates. Corresponding collection of samples from the evaporator feed overhead condensate, and bottoms was made at approximately the same time as the emissions inventory to support material balance determinations for the evaporator process. The data indicate that organic compound emissions are slightly higher at the beginning of the batch while metals emissions, including mercury, are slightly higher at the end of the evaporator batch. The maximum emissions concentrations are low for all constituents of primary concern. Mercury emissions were less than 5 ppbv, while the sum of HCl and Cl2 emissions was less than 1 ppmv. The sum of all organic emissions also was less than 1 ppmv. The estimated hazardous quotient (HQ) for the evaporator was 6.2e-6 as compared to 0.25 for the EPA target criteria. The cancer risk was 1.3e-10 compared to an EPA target of le-5.

NWCF Evaporator Tank System 2001 Offgas Emissions Inventory

International Nuclear Information System (INIS)

Boardman, R.D.; Lamb, K.M.; Matejka, L.A.; Nenni, J.A.

2002-01-01

An offgas emissions inventory and liquid stream characterization of the Idaho New Waste Calcining Facility (NWCF) Evaporator Tank System (ETS), formerly known as the High Level Liquid Waste Evaporator (HLLWE), has been completed. The emissions rates of volatile and semi-volatile organic compounds, multiple metals, particulate, and hydrochloric acid were measured in accordance with an approved Quality Assurance Project Plan (QAPjP) and Test Plan that invoked U.S. Environmental Protection Agency (EPA) standard sample collection and analysis procedures. Offgas samples were collected during the start up and at the end of evaporator batches when it was hypothesized the emissions would be at peak rates. Corresponding collection of samples from the evaporator feed overhead condensate, and bottoms was made at approximately the same time as the emissions inventory to support material balance determinations for the evaporator process. The data indicate that organic compound emissions are slightly higher at the beginning of the batch while metals emissions, including mercury, are slightly higher at the end of the evaporator batch. The maximum emissions concentrations are low for all constituents of primary concern. Mercury emissions were less than 5 ppbv, while the sum of HCl and Cl2 emissions was less than 1 ppmv. The sum of all organic emissions also was less than 1 ppmv. The estimated hazardous quotient (HQ) for the evaporator was 6.2e-6 as compared to 0.25 for the EPA target criteria. The cancer risk was 1.3e-10 compared to an EPA target of le-5

Potential for natural evaporation as a reliable renewable energy resource.

Science.gov (United States)

Cavusoglu, Ahmet-Hamdi; Chen, Xi; Gentine, Pierre; Sahin, Ozgur

2017-09-26

About 50% of the solar energy absorbed at the Earth's surface drives evaporation, fueling the water cycle that affects various renewable energy resources, such as wind and hydropower. Recent advances demonstrate our nascent ability to convert evaporation energy into work, yet there is little understanding about the potential of this resource. Here we study the energy available from natural evaporation to predict the potential of this ubiquitous resource. We find that natural evaporation from open water surfaces could provide power densities comparable to current wind and solar technologies while cutting evaporative water losses by nearly half. We estimate up to 325 GW of power is potentially available in the United States. Strikingly, water's large heat capacity is sufficient to control power output by storing excess energy when demand is low, thus reducing intermittency and improving reliability. Our findings motivate the improvement of materials and devices that convert energy from evaporation.The evaporation of water represents an alternative source of renewable energy. Building on previous models of evaporation, Cavusoglu et al. show that the power available from this natural resource is comparable to wind and solar power, yet it does not suffer as much from varying weather conditions.

In-line high-rate evaporation of aluminum for the metallization of silicon solar cells

Energy Technology Data Exchange (ETDEWEB)

Mader, Christoph Paul

2012-07-11

This work focuses on the in-line high-rate evaporation of aluminum for contacting rear sides of silicon solar cells. The substrate temperature during the deposition process, the wafer bow after deposition, and the electrical properties of evaporated contacts are investigated. Furthermore, this work demonstrates for the first time the formation of aluminum-doped silicon regions by the in-line high-rate evaporation of aluminum without any further temperature treatment. The temperature of silicon wafers during in-line high-rate evaporation of aluminum is investigated in this work. The temperatures are found to depend on the wafer thickness W, the aluminum layer thickness d, and on the wafer emissivity {epsilon}. Two-dimensional finite-element simulations reproduce the measured peak temperatures with an accuracy of 97%. This work also investigates the wafer bow after in-line high-rate evaporation and shows that the elastic theory overestimates the wafer bow of planar Si wafers. The lower bow is explained with plastic deformation in the Al layer. Due to the plastic deformation only the first 79 K in temperature decrease result in a bow formation. Furthermore the electrical properties of evaporated point contacts are examined in this work. Parameterizations for the measured saturation currents of contacted p-type Si wafers and of contacted boron-diffused p{sup +}-type layers are presented. The contact resistivity of the deposited Al layers to silicon for various deposition processes and silicon surface concentrations are presented and the activation energy of the contact formation is determined. The measured saturation current densities and contact resistivities of the evaporated contacts are used in one-dimensional numerical Simulations and the impact on energy conversion efficiency of replacing a screen-printed rear side by an evaporated rear side is presented. For the first time the formation of aluminum-doped p{sup +}-type (Al-p{sup +}) silicon regions by the in

Real-Time Control of Active and Reactive Power for Doubly Fed Induction Generator (DFIG-Based Wind Energy Conversion System

Directory of Open Access Journals (Sweden)

Aman Abdulla Tanvir

2015-09-01

Full Text Available This paper presents the modeling, rapid control prototyping, and hardware-in-the-loop testing for real-time simulation and control of a grid-connected doubly fed induction generator (DFIG in a laboratory-size wind turbine emulator for wind energy conversation systems. The generator is modeled using the direct-quadrature rotating reference frame circuit along with the aligned stator flux, and the field-oriented control approach is applied for independent control of the active and reactive power and the DC-link voltage at the grid side. The control of the active, reactive power and the DC-link voltage are performed using a back-to-back converter at sub- and super-synchronous as well as at variable speeds. The control strategy is experimentally validated on an emulated wind turbine driven by the Opal-RT real-time simulator (OP5600 for simultaneous control of the DC-link voltage, active and reactive power.

Active and reactive behaviour in human mobility: the influence of attraction points on pedestrians

Science.gov (United States)

Gutiérrez-Roig, M.; Sagarra, O.; Oltra, A.; Palmer, J. R. B.; Bartumeus, F.; Díaz-Guilera, A.; Perelló, J.

2016-07-01

Human mobility is becoming an accessible field of study, thanks to the progress and availability of tracking technologies as a common feature of smart phones. We describe an example of a scalable experiment exploiting these circumstances at a public, outdoor fair in Barcelona (Spain). Participants were tracked while wandering through an open space with activity stands attracting their attention. We develop a general modelling framework based on Langevin dynamics, which allows us to test the influence of two distinct types of ingredients on mobility: reactive or context-dependent factors, modelled by means of a force field generated by attraction points in a given spatial configuration and active or inherent factors, modelled from intrinsic movement patterns of the subjects. The additive and constructive framework model accounts for some observed features. Starting with the simplest model (purely random walkers) as a reference, we progressively introduce different ingredients such as persistence, memory and perceptual landscape, aiming to untangle active and reactive contributions and quantify their respective relevance. The proposed approach may help in anticipating the spatial distribution of citizens in alternative scenarios and in improving the design of public events based on a facts-based approach.

Active and reactive behaviour in human mobility: the influence of attraction points on pedestrians.

Science.gov (United States)

Gutiérrez-Roig, M; Sagarra, O; Oltra, A; Palmer, J R B; Bartumeus, F; Díaz-Guilera, A; Perelló, J

2016-07-01

Human mobility is becoming an accessible field of study, thanks to the progress and availability of tracking technologies as a common feature of smart phones. We describe an example of a scalable experiment exploiting these circumstances at a public, outdoor fair in Barcelona (Spain). Participants were tracked while wandering through an open space with activity stands attracting their attention. We develop a general modelling framework based on Langevin dynamics, which allows us to test the influence of two distinct types of ingredients on mobility: reactive or context-dependent factors, modelled by means of a force field generated by attraction points in a given spatial configuration and active or inherent factors, modelled from intrinsic movement patterns of the subjects. The additive and constructive framework model accounts for some observed features. Starting with the simplest model (purely random walkers) as a reference, we progressively introduce different ingredients such as persistence, memory and perceptual landscape, aiming to untangle active and reactive contributions and quantify their respective relevance. The proposed approach may help in anticipating the spatial distribution of citizens in alternative scenarios and in improving the design of public events based on a facts-based approach.

Influence of Evaporation on Soap Film Rupture.

Science.gov (United States)

Champougny, Lorène; Miguet, Jonas; Henaff, Robin; Restagno, Frédéric; Boulogne, François; Rio, Emmanuelle

2018-03-13

Although soap films are prone to evaporate due to their large surface to volume ratio, the effect of evaporation on macroscopic film features has often been disregarded in the literature. In this work, we experimentally investigate the influence of environmental humidity on soap film stability. An original experiment allows to measure both the maximum length of a film pulled at constant velocity and its thinning dynamics in a controlled atmosphere for various values of the relative humidity [Formula: see text]. At first order, the environmental humidity seems to have almost no impact on most of the film thinning dynamics. However, we find that the film length at rupture increases continuously with [Formula: see text]. To rationalize our observations, we propose that film bursting occurs when the thinning due to evaporation becomes comparable to the thinning due to liquid drainage. This rupture criterion turns out to be in reasonable agreement with an estimation of the evaporation rate in our experiment.

Activation of glucocorticoid receptors in Müller glia is protective to retinal neurons and suppresses microglial reactivity

OpenAIRE

Gallina, Donika; Zelinka, Christopher Paul; Cebulla, Colleen; Fischer, Andy J.

2015-01-01

Reactive microglia and macrophages are prevalent in damaged retinas. Glucocorticoid signaling is known to suppress inflammation and the reactivity of microglia and macrophages. In the vertebrate retina, the glucocorticoid receptor (GCR) is known to be activated and localized to the nuclei of Müller glia (Gallina et al., 2014). Accordingly, we investigated how signaling through GCR influences the survival of neurons using the chick retina in vivo as a model system. We applied intraocular injec...

Variability of Evaporation and Precipitation over the Ocean from Satellite Data

Science.gov (United States)

Malinin, V. N.; Gordeeva, S. M.

2017-12-01

HOAPS-3 and PMWC satellite archives for 1988-2008 are used to estimate moisture-exchange components between the ocean and atmosphere (evaporation, precipitation, and the difference between them or effective evaporation). Moisture-exchange components for the entire World Ocean and for the North Atlantic Ocean within 30°-60° N are calculated. A strong overestimation of the global values of effective evaporation by HOAPS data (mainly caused by a decrease in precipitation) is shown. In the interannual variability of effective evaporation, there is clearly an overestimated positive trend, which contradicts the real increase in the Global Sea Level. Large systematic errors in moisture-exchange components are revealed for the North Atlantic water area. According to HOAPS data, there is a significant underestimation of evaporation and effective evaporation. According to PMWC data, the amount of precipitation is significantly overestimated and evaporation is underestimated. As a consequence, effective evaporation becomes negative, which is impossible. Low accuracy in the estimation of moisture-exchange components and the need to improve old estimates and develop new evaporation and precipitation databases based on satellite data are noted.

Computational Fluid Dynamics Analysis of an Evaporative Cooling System

Directory of Open Access Journals (Sweden)

Kapilan N.

2016-11-01

Full Text Available The use of chlorofluorocarbon based refrigerants in the air-conditioning system increases the global warming and causes the climate change. The climate change is expected to present a number of challenges for the built environment and an evaporative cooling system is one of the simplest and environmentally friendly cooling system. The evaporative cooling system is most widely used in summer and in rural and urban areas of India for human comfort. In evaporative cooling system, the addition of water into air reduces the temperature of the air as the energy needed to evaporate the water is taken from the air. Computational fluid dynamics is a numerical analysis and was used to analyse the evaporative cooling system. The CFD results are matches with the experimental results.

Effects of Preventative Ankle Taping on Planned Change-of-Direction and Reactive Agility Performance and Ankle Muscle Activity in Basketballers

Directory of Open Access Journals (Sweden)

Matthew D. Jeffriess, Adrian B. Schultz, Tye S. McGann, Samuel J. Callaghan, Robert G. Lockie

2015-12-01

Full Text Available This study investigated the effects of preventative ankle taping on planned change-of-direction and reactive agility performance and peak ankle muscle activity in basketballers. Twenty male basketballers (age = 22.30 ± 3.97 years; height = 1.84 ± 0.09 meters; body mass = 85.96 ± 11.88 kilograms with no ankle pathologies attended two testing sessions. Within each session, subjects completed six planned and six reactive randomized trials (three to the left and three to the right for each condition of the Y-shaped agility test, which was recorded by timing lights. In one session, subjects had both ankles un-taped. In the other, both ankles were taped using a modified subtalar sling. Peak tibialis anterior, peroneus longus (PL, peroneus brevis (PB, and soleus muscle activity was recorded for both the inside and outside legs across stance phase during the directional change, which was normalized against 10-meter sprint muscle activity (nEMG. Both the inside and outside cut legs during the change-of-direction step were investigated. Repeated measures ANOVA determined performance time and nEMG differences between un-taped and taped conditions. There were no differences in planned change-of-direction or reactive agility times between the conditions. Inside cut leg PL nEMG decreased when taped for the planned left, reactive left, and reactive right cuts (p = 0.01. Outside leg PB and soleus nEMG increased during the taped planned left cut (p = 0.02. There were no other nEMG changes during the cuts with taping. Taping did not affect change-of-direction or agility performance. Inside leg PL activity was decreased, possibly due to the tape following the line of muscle action. This may reduce the kinetic demand for the PL during cuts. In conclusion, ankle taping did not significantly affect planned change-of-direction or reactive agility performance, and did not demonstrate large changes in activity of the muscle complex in healthy basketballers.

Evaluating the hydrological consistency of evaporation products

KAUST Repository

Lopez Valencia, Oliver Miguel; Houborg, Rasmus; McCabe, Matthew

2017-01-01

Advances in space-based observations have provided the capacity to develop regional- to global-scale estimates of evaporation, offering insights into this key component of the hydrological cycle. However, the evaluation of large-scale evaporation retrievals is not a straightforward task. While a number of studies have intercompared a range of these evaporation products by examining the variance amongst them, or by comparison of pixel-scale retrievals against ground-based observations, there is a need to explore more appropriate techniques to comprehensively evaluate remote-sensing-based estimates. One possible approach is to establish the level of product agreement between related hydrological components: for instance, how well do evaporation patterns and response match with precipitation or water storage changes? To assess the suitability of this "consistency"-based approach for evaluating evaporation products, we focused our investigation on four globally distributed basins in arid and semi-arid environments, comprising the Colorado River basin, Niger River basin, Aral Sea basin, and Lake Eyre basin. In an effort to assess retrieval quality, three satellite-based global evaporation products based on different methodologies and input data, including CSIRO-PML, the MODIS Global Evapotranspiration product (MOD16), and Global Land Evaporation: the Amsterdam Methodology (GLEAM), were evaluated against rainfall data from the Global Precipitation Climatology Project (GPCP) along with Gravity Recovery and Climate Experiment (GRACE) water storage anomalies. To ensure a fair comparison, we evaluated consistency using a degree correlation approach after transforming both evaporation and precipitation data into spherical harmonics. Overall we found no persistent hydrological consistency in these dryland environments. Indeed, the degree correlation showed oscillating values between periods of low and high water storage changes, with a phase difference of about 2–3 months

Evaluating the hydrological consistency of evaporation products

KAUST Repository

Lopez Valencia, Oliver Miguel

2017-01-18

Advances in space-based observations have provided the capacity to develop regional- to global-scale estimates of evaporation, offering insights into this key component of the hydrological cycle. However, the evaluation of large-scale evaporation retrievals is not a straightforward task. While a number of studies have intercompared a range of these evaporation products by examining the variance amongst them, or by comparison of pixel-scale retrievals against ground-based observations, there is a need to explore more appropriate techniques to comprehensively evaluate remote-sensing-based estimates. One possible approach is to establish the level of product agreement between related hydrological components: for instance, how well do evaporation patterns and response match with precipitation or water storage changes? To assess the suitability of this "consistency"-based approach for evaluating evaporation products, we focused our investigation on four globally distributed basins in arid and semi-arid environments, comprising the Colorado River basin, Niger River basin, Aral Sea basin, and Lake Eyre basin. In an effort to assess retrieval quality, three satellite-based global evaporation products based on different methodologies and input data, including CSIRO-PML, the MODIS Global Evapotranspiration product (MOD16), and Global Land Evaporation: the Amsterdam Methodology (GLEAM), were evaluated against rainfall data from the Global Precipitation Climatology Project (GPCP) along with Gravity Recovery and Climate Experiment (GRACE) water storage anomalies. To ensure a fair comparison, we evaluated consistency using a degree correlation approach after transforming both evaporation and precipitation data into spherical harmonics. Overall we found no persistent hydrological consistency in these dryland environments. Indeed, the degree correlation showed oscillating values between periods of low and high water storage changes, with a phase difference of about 2–3 months

Evaporation rate and vapor pressure of selected polymeric lubricating oils.

Science.gov (United States)

Gardos, M. N.

1973-01-01

A recently developed ultrahigh-vacuum quartz spring mass sorption microbalance has been utilized to measure the evaporation rates of several low-volatility polymeric lubricating oils at various temperatures. The evaporation rates are used to calculate the vapor pressures by the Langmuir equation. A method is presented to accurately estimate extended temperature range evaporation rate and vapor pressure data for polymeric oils, incorporating appropriate corrections for the increases in molecular weight and the change in volatility of the progressively evaporating polymer fractions. The logarithms of the calculated data appear to follow linear relationships within the test temperature ranges, when plotted versus 1000/T. These functions and the observed effusion characteristics of the fluids on progressive volatilization are useful in estimating evaporation rate and vapor pressure changes on evaporative depletion.

Sequence crystallization during isotherm evaporation of southern ...

African Journals Online (AJOL)

Southern Algerian's natural brine sampled from chott Baghdad may be a source of mineral salts with a high economic value. These salts are recoverable by simple solar evaporation. Indeed, during isothermal solar evaporation, it is possible to recover mineral salts and to determine the precipitation sequences of different ...

Water-evaporation-induced electricity with nanostructured carbon materials.

Science.gov (United States)

Xue, Guobin; Xu, Ying; Ding, Tianpeng; Li, Jia; Yin, Jun; Fei, Wenwen; Cao, Yuanzhi; Yu, Jin; Yuan, Longyan; Gong, Li; Chen, Jian; Deng, Shaozhi; Zhou, Jun; Guo, Wanlin

2017-05-01

Water evaporation is a ubiquitous natural process that harvests thermal energy from the ambient environment. It has previously been utilized in a number of applications including the synthesis of nanostructures and the creation of energy-harvesting devices. Here, we show that water evaporation from the surface of a variety of nanostructured carbon materials can be used to generate electricity. We find that evaporation from centimetre-sized carbon black sheets can reliably generate sustained voltages of up to 1 V under ambient conditions. The interaction between the water molecules and the carbon layers and moreover evaporation-induced water flow within the porous carbon sheets are thought to be key to the voltage generation. This approach to electricity generation is related to the traditional streaming potential, which relies on driving ionic solutions through narrow gaps, and the recently reported method of moving ionic solutions across graphene surfaces, but as it exploits the natural process of evaporation and uses cheap carbon black it could offer advantages in the development of practical devices.

Evaporation components of a boreal forest: variations during the growing season

Science.gov (United States)

Grelle, A.; Lundberg, A.; Lindroth, A.; Morén, A.-S.; Cienciala, E.

1997-10-01

To improve the understanding of interactions between the boreal forest and the climate system as a key issue for global climate change, the water budget of a mixed pine and spruce forest in central Sweden was estimated by measurements of the water flux components and the total evaporation flux during the period 16 May-31 October 1995. Total evaporation was measured using eddy correlation and the components were obtained using measurements of precipitation, throughfall, tree transpiration, and forest floor evaporation. On a daily basis, tree transpiration was the dominant evaporation component during the vegetation period. However, it could be efficiently blocked by a wet canopy associated with large interception evaporation. The accumulated total evaporation was 399 mm, transpiration was 243 mm, forest floor evaporation was 56 mm and interception evaporation was 74 mm. The accumulated sum of interception, transpiration, and floor evaporation was 51 mm larger than the actual measured total evaporation. This difference was mainly attributed to the fact that transpiration was measured in a rather dense 50-year-old stand while total evaporation represented the average conditions of older, roughly 100-year-old stands. To compare eddy-correlation measurements with small-scale measurements of evaporation components, a source area analysis was made to select the flux data that give the best representation of the investigated stand. Especially under stable atmospheric conditions the requirements for surface homogeneity were very high and extreme care had to be taken to be aware of the flux source areas. Canopy water storage was determined by two methods: by the water balance of the canopy, which gave a result of 3.3 mm; and by the so-called minimum method based on plots of throughfall versus precipitation, which gave a much lower value of 1.5 mm. Seasonal interception evaporation constituted 30% of the precipitation.

Performance analysis of a refrigeration system with parallel control of evaporation pressure

International Nuclear Information System (INIS)

Lee, Jong Suk

2008-01-01

The conventional refrigeration system is composed of a compressor, condenser, receiver, expansion valve or capillary tube, and an evaporator. The refrigeration system used in this study has additional expansion valve and evaporator along with an Evaporation Pressure Regulator(EPR) at the exit side of the evaporator. The two evaporators can be operated at different temperatures according to the opening of the EPR. The experimental results obtained using the refrigeration system with parallel control of evaporation pressure are presented and the performance analysis of the refrigeration system with two evaporators is conducted

The Savannah River Site Replacement High Level Radioactive Waste Evaporator Project

International Nuclear Information System (INIS)

Presgrove, S.B.

1992-01-01

The Replacement High Level Waste Evaporator Project was conceived in 1985 to reduce the volume of the high level radioactive waste Process of the high level waste has been accomplished up to this time using Bent Tube type evaporators and therefore, that type evaporator was selected for this project. The Title I Design of the project was 70% completed in late 1990. The Department of Energy at that time hired an independent consulting firm to perform a complete review of the project. The DOE placed a STOP ORDER on purchasing the evaporator in January 1991. Essentially, no construction was to be done on this project until all findings and concerns dealing with the type and design of the evaporator are resolved. This report addresses two aspects of the DOE design review; (1) Comparing the Bent Tube Evaporator with the Forced Circulation Evaporator, (2) The design portion of the DOE Project Review - concentrated on the mechanical design properties of the evaporator. 1 ref

Electron beam assisted field evaporation of insulating nanowires/tubes

Energy Technology Data Exchange (ETDEWEB)

Blanchard, N. P., E-mail: nicholas.blanchard@univ-lyon1.fr; Niguès, A.; Choueib, M.; Perisanu, S.; Ayari, A.; Poncharal, P.; Purcell, S. T.; Siria, A.; Vincent, P. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France)

2015-05-11

We demonstrate field evaporation of insulating materials, specifically BN nanotubes and undoped Si nanowires, assisted by a convergent electron beam. Electron irradiation leads to positive charging at the nano-object's apex and to an important increase of the local electric field thus inducing field evaporation. Experiments performed both in a transmission electron microscope and in a scanning electron microscope are presented. This technique permits the selective evaporation of individual nanowires in complex materials. Electron assisted field evaporation could be an interesting alternative or complementary to laser induced field desorption used in atom probe tomography of insulating materials.

Performance investigation of advanced adsorption desalination cycle with condenser-evaporator heat recovery scheme

KAUST Repository

Thu, Kyaw; Kim, Youngdeuk; Myat, Aung; Chakraborty, Anutosh; Ng, K. C.

2013-01-01

Energy or heat recovery schemes are keys for the performance improvement of any heat-activated cycles such as the absorption and adsorption cycles. We present two innovative heat recovery schemes between the condensing and evaporating units

Improvement of ZnO TCO film growth for photovoltaic devices by reactive plasma deposition (RPD)

International Nuclear Information System (INIS)

Iwata, K.; Sakemi, T.; Yamada, A.; Fons, P.; Awai, K.; Yamamoto, T.; Shirakata, S.; Matsubara, K.; Tampo, H.; Sakurai, K.; Ishizuka, S.; Niki, S.

2005-01-01

Reactive plasma deposition (RPD) is a technique for depositing a thin film on a substrate using a pressure-slope type plasma ion gun. This method offers the advantage of low-ion damage, low deposition temperature, large area deposition and high growth rates. Ga-doped zinc oxide (ZnO) thin film was grown on a moving glass substrate by RPD. Evaporation of very small quantity of tungsten from anode electrode by plasma collision lets the resistivity of grown ZnO transparent conductive oxide (TCO) film to increase. However, no reduction of carrier concentration was observed but only reduction of carrier mobility. It indicates that reduction of evaporation of tungsten from anode electrode induces increase of carrier mobility without any increase of carrier concentration. After installation of an anode cooling system in order to avoid the tungsten evaporation, increase of the mobility (37 cm 2 /Vsec) was observed and the lowest resistivity (2.0x10 -4 no. OMEGAno. cm) film was obtained from large size grown ZnO TCO of 200x200 mm at low growth temperature of 200 deg. C with high growth rate of 24 no. muno. m/h

Improvements of evaporation drag model

International Nuclear Information System (INIS)

Li Xiaoyan; Yang Yanhua; Xu Jijun

2004-01-01

A special observable experiment facility has been established, and a series of experiments have been carried out on this facility by pouring one or several high-temperature particles into a water pool. The experiment has verified the evaporation drag model, which believe the non-symmetric profile of the local evaporation rate and the local density of the vapor would bring about a resultant force on the hot particle so as to resist its motion. However, in Yang's evaporation drag model, radiation heat transfer is taken as the only way to transfer heat from hot particle to the vapor-liquid interface and all of the radiation energy is deposited on the vapor-liquid interface, thus contributing to the vaporization rate and mass balance of the vapor film. So, the heat conduction and the heat convection are taken into account in improved model. At the same time, the improved model given by this paper presented calculations of the effect of hot particles temperature on the radiation absorption behavior of water

Effects on evaporation rates from different water-permeable pavement designs.

Science.gov (United States)

Starke, P; Göbel, P; Coldewey, W G

2011-01-01

The urban water balance can be attenuated to the natural by water-permeable pavements (WPPs). Furthermore, WPPs have a 16% higher evaporation rate than impermeable pavements, which can lead to a better urban climate. Evaporation rates from pavements are influenced by the pavement surface and by the deeper layers. By a compared evaporation measurement between different WPP designs, the grain size distribution of the sub-base shows no influence on the evaporation rates in a significant way. On the contrary, a sub-base made of a twin-layer decreases the evaporation by 16% compared to a homogeneous sub-base. By a change in the colour of the paving stone, 19% higher evaporation rates could be achieved. A further comparison shows that the transpiration-effect of the grass in grass pavers increases the evaporation rates more than threefold to pervious concrete pavements. These high evapotranspiration rates can not be achieved with a pervious concrete paving stone. In spite of this, the broad field of application of the pervious concrete paving stone increases the importance in regard to the urban climate.

Geometry Effects of Capillary on the Evaporation from the Meniscus

International Nuclear Information System (INIS)

Choi, Choong Hyo; Jin, Song Wan; Yoo, Jung Yul

2007-01-01

The effect of capillary cross-section geometry on evaporation is investigated in terms of the meniscus shape, evaporation rate and evaporation-induced flow for circular, square and rectangular cross-sectional capillaries. The shapes of water and ethanol menisci are not much different from each other in square and rectangular capillaries even though the surface tension of water is much larger than that of ethanol. On the other hand, the shapes of water and ethanol menisci are very different from each other in circular capillary. The averaged evaporation fluxes in circular and rectangular capillaries are measured by tracking the meniscus position. At a given position, the averaged evaporation flux in rectangular capillaries in much larger than that in circular capillary with comparable hydraulic diameter. The flow near the evaporating meniscus is also measured using micro-PIV, so that the rotating vortex motion is observed near the evaporating ethanol and methanol menisci except for the case of methanol meniscus in rectangular capillary. This difference is considered to be due to the existence of corner menisci at the four corners

Evaporation Kinetics of Laboratory Generated Secondary Organic Aerosols at Elevated Relative Humidity

Energy Technology Data Exchange (ETDEWEB)

Wilson, Jacqueline M.; Imre, D.; Beranek, Josef; Shrivastava, ManishKumar B.; Zelenyuk, Alla

2015-01-06

Secondary organic aerosols (SOA) dominate atmospheric organic aerosols that affect climate, air quality, and health. Recent studies indicate that, contrary to previously held assumptions, at low relative humidity (RH) these particles are semi-solid and evaporate orders of magnitude slower than expected. Elevated relative humidity has the potential to affect significantly formation, properties, and atmospheric evolution of SOA particles. Here we present a study of the effect of RH on the room-temperature evaporation kinetics of SOA particles formed by ozonolysis of α-pinene and limonene. Experiments were carried out on SOA particles generated, evaporated, and aged at 0%, 50% and 90% RH. We find that in all cases evaporation begins with a relatively fast phase, during which 30% to 70% of the particle mass evaporates in 2 hours, followed by a much slower evaporation rate. Evaporation kinetics at 0% and 50% RH are nearly the same, while at 90% RH a slightly larger fraction evaporates. In all cases, aging the particles prior to inducing evaporation reduces the evaporative losses, with aging at elevated RH leading to more significant effect. In all cases, SOA evaporation is nearly size-independent, providing direct evidence that oligomers play a crucial role in determining the evaporation kinetics.

Evaporation of Nanosuspensions on Substrates with Different Hydrophobicity.

Science.gov (United States)

Perrin, Lionel; Pajor-Swierzy, Anna; Magdassi, Shlomo; Kamyshny, Alexander; Ortega, Francisco; Rubio, Ramón G

2018-01-24

Liquid drop evaporation on surfaces is present in many industrial and medical applications, e.g., printed electronics, spraying of pesticides, DNA mapping, etc. Despite this strong interest, a theoretical description of the dynamic of the evaporation of complex liquid mixtures and nanosuspensions is still lacking. Indeed, one of the aspects that have not been included in the current theoretical descriptions is the competition between the kinetics of evaporation and the adsorption of surfactants and/or particles at the liquid/vapor and liquid/solid interfaces. Materials formed by an electrically isolating solid on which a patterned conducting layer was formed by the deposits left after drop evaporation have been considered as very promising for building electrical circuits on flexible plastic substrates. In this work, we have done an exhaustive study of the evaporation of nanosuspensions of latex and hydrophobized silver nanoparticles on four substrates of different hydrophobicity. The advancing and receding contact angles as well as the time dependence of the volume of the droplets have been measured over a broad range of particle concentrations. Also, mixtures of silver particles and a surfactant, commonly used in industrial printing, have been examined. Furthermore, the adsorption kinetics at both the air/liquid and solid/liquid interfaces have been measured. Whereas the latex particles do not adsorb at the solid/liquid and only slightly reduce the surface tension, the silver particles strongly adsorb at both interfaces. The experimental results of the evaporation process were compared with the predictions of the theory of Semenov et al. (Evaporation of Sessile Water Droplets: Universal Behavior in the Presence of Contact Angle Hysteresis. Colloids Surf. Physicochem. Eng. Asp. 2011, 391 (1-3), 135-144) and showed surprisingly good agreement despite that the theory was developed for pure liquids. The morphology of the deposits left by the droplets after total

Numerical study of the evaporation process and parameter estimation analysis of an evaporation experiment

Directory of Open Access Journals (Sweden)

K. Schneider-Zapp

2010-05-01

Full Text Available Evaporation is an important process in soil-atmosphere interaction. The determination of hydraulic properties is one of the crucial parts in the simulation of water transport in porous media. Schneider et al. (2006 developed a new evaporation method to improve the estimation of hydraulic properties in the dry range. In this study we used numerical simulations of the experiment to study the physical dynamics in more detail, to optimise the boundary conditions and to choose the optimal combination of measurements. The physical analysis exposed, in accordance to experimental findings in the literature, two different evaporation regimes: (i a soil-atmosphere boundary layer dominated regime (regime I close to saturation and (ii a hydraulically dominated regime (regime II. During this second regime a drying front (interface between unsaturated and dry zone with very steep gradients forms which penetrates deeper into the soil as time passes. The sensitivity analysis showed that the result is especially sensitive at the transition between the two regimes. By changing the boundary conditions it is possible to force the system to switch between the two regimes, e.g. from II back to I. Based on this findings a multistep experiment was developed. The response surfaces for all parameter combinations are flat and have a unique, localised minimum. Best parameter estimates are obtained if the evaporation flux and a potential measurement in 2 cm depth are used as target variables. Parameter estimation from simulated experiments with realistic measurement errors with a two-stage Monte-Carlo Levenberg-Marquardt procedure and manual rejection of obvious misfits lead to acceptable results for three different soil textures.

Reactive oxygen species in the paraventricular nucleus of the hypothalamus alter sympathetic activity during metabolic syndrome.

Directory of Open Access Journals (Sweden)

JOSIANE CAMPOS CRUZ

2015-12-01

Full Text Available The paraventricular nucleus of the hypothalamus (PVN contains heterogeneous populations of neurons involved in autonomic and neuroendocrine regulation. The PVN plays an important role in the sympathoexcitatory response to increasing circulating levels of angiotensin II (Ang-II, which activates AT1 receptors in the circumventricular organs (OCVs, mainly in the subfornical organ (SFO. Circulating Ang-II induces a de novo synthesis of Ang-II in SFO neurons projecting to pre-autonomic PVN neurons. Activation of AT1 receptors induces intracellular increases in reactive oxygen species (ROS, leading to increases in sympathetic nerve activity (SNA. Chronic sympathetic nerve activation promotes a series of metabolic disorders that characterizes the metabolic syndrome (MetS: dyslipidemia, hyperinsulinemia, glucose intolerance, hyperleptinemia and elevated plasma hormone levels, such as noradrenaline, glucocorticoids, leptin, insulin and Ang-II. This review will discuss the contribution of our laboratory and others regarding the sympathoexcitation caused by peripheral Ang-II-induced reactive oxygen species along the subfornical organ and paraventricular nucleus of the hypothalamus. We hypothesize that this mechanism could be involved in metabolic disorders underlying MetS.

Freezing of Water Droplet due to Evaporation

Science.gov (United States)

Satoh, Isao; Fushinobu, Kazuyoshi; Hashimoto, Yu

In this study, the feasibility of cooling/freezing of phase change.. materials(PCMs) due to evaporation for cold storage systems was experimentally examined. A pure water was used as the test PCM, since the latent heat due to evaporation of water is about 7 times larger than that due to freezing. A water droplet, the diameter of which was 1-4 mm, was suspended in a test cell by a fine metal wire (O. D.= 100μm),and the cell was suddenly evacuated up to the pressure lower than the triple-point pressure of water, so as to enhance the evaporation from the water surface. Temperature of the droplet was measured by a thermocouple, and the cooling/freezing behavior and the temperature profile of the droplet surface were captured by using a video camera and an IR thermo-camera, respectively. The obtained results showed that the water droplet in the evacuated cell is effectively cooled by the evaporation of water itself, and is frozen within a few seconds through remarkable supercooling state. When the initial temperature of the droplet is slightly higher than the room temperature, boiling phenomena occur in the droplet simultaneously with the freezing due to evaporation. Under such conditions, it was shown that the degree of supercooling of the droplet is reduced by the bubbles generated in the droplet.

Experimental study of falling film evaporation in large scale rectangular channel

International Nuclear Information System (INIS)

Huang, X.G.; Yang, Y.H.; Hu, P.

2015-01-01

Highlights: • This paper studies the falling film evaporation in large scale rectangular channel experimentally. • The effects of air flow rate, film temperature and film flow rate on falling film evaporation are analyzed. • Increasing the air flow rate is considered as an efficient method to enhance the evaporation rate. • A correlation including the wave effect for falling film evaporation is derived based on heat and mass transfer analogy. - Abstract: The falling film evaporation in a large scale rectangular channel is experimentally studied in this paper for the design and improvement of passive containment cooling system. The evaporation mass transfer coefficient h D is obtained by the evaporation rate and vapor partial pressure difference of film surface and air bulk. The experimental results indicate that increasing of air flow rate appears to enhance h D , while the film temperature and film flow rate have little effect on h D . Since the wave effect on evaporation is noticed in experiment, the evaporation mass transfer correlation including the wave effect is developed on the basis of heat and mass transfer analogy and experimental data

PREDICTING EVAPORATION RATES AND TIMES FOR SPILLS OF CHEMICAL MIXTURES

Science.gov (United States)

Spreadsheet and short-cut methods have been developed for predicting evaporation rates and evaporation times for spills (and constrained baths) of chemical mixtures. Steady-state and time-varying predictions of evaporation rates can be made for six-component mixtures, includ...

AMPK Re-Activation Suppresses Hepatic Steatosis but its Downregulation Does Not Promote Fatty Liver Development.

Science.gov (United States)

Boudaba, Nadia; Marion, Allison; Huet, Camille; Pierre, Rémi; Viollet, Benoit; Foretz, Marc

2018-02-01

Nonalcoholic fatty liver disease is a highly prevalent component of disorders associated with disrupted energy homeostasis. Although dysregulation of the energy sensor AMP-activated protein kinase (AMPK) is viewed as a pathogenic factor in the development of fatty liver its role has not been directly demonstrated. Unexpectedly, we show here that liver-specific AMPK KO mice display normal hepatic lipid homeostasis and are not prone to fatty liver development, indicating that the decreases in AMPK activity associated with hepatic steatosis may be a consequence, rather than a cause, of changes in hepatic metabolism. In contrast, we found that pharmacological re-activation of downregulated AMPK in fatty liver is sufficient to normalize hepatic lipid content. Mechanistically, AMPK activation reduces hepatic triglyceride content both by inhibiting lipid synthesis and by stimulating fatty acid oxidation in an LKB1-dependent manner, through a transcription-independent mechanism. Furthermore, the effect of the antidiabetic drug metformin on lipogenesis inhibition and fatty acid oxidation stimulation was enhanced by combination treatment with small-molecule AMPK activators in primary hepatocytes from mice and humans. Overall, these results demonstrate that AMPK downregulation is not a triggering factor in fatty liver development but in contrast, establish the therapeutic impact of pharmacological AMPK re-activation in the treatment of fatty liver disease. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

Odors from evaporation of acidified pig urine

NARCIS (Netherlands)

Willers, H.C.; Hobbs, P.J.; Ogink, N.W.M.

2004-01-01

In the Dutch Hercules project feces and urine from pigs are collected separately underneath the slatted floor in a pig house and treated in two processes. Feces are composted and urine is concentrated by water evaporation in a packed bed. Exhaust air from the pig house is used for the evaporation in

Dynamics of contact line depinning during droplet evaporation based on thermodynamics.

Science.gov (United States)

Yu, Dong In; Kwak, Ho Jae; Doh, Seung Woo; Ahn, Ho Seon; Park, Hyun Sun; Kiyofumi, Moriyama; Kim, Moo Hwan

2015-02-17

For several decades, evaporation phenomena have been intensively investigated for a broad range of applications. However, the dynamics of contact line depinning during droplet evaporation has only been inductively inferred on the basis of experimental data and remains unclear. This study focuses on the dynamics of contact line depinning during droplet evaporation based on thermodynamics. Considering the decrease in the Gibbs free energy of a system with different evaporation modes, a theoretical model was developed to estimate the receding contact angle during contact line depinning as a function of surface conditions. Comparison of experimentally measured and theoretically modeled receding contact angles indicated that the dynamics of contact line depinning during droplet evaporation was caused by the most favorable thermodynamic process encountered during constant contact radius (CCR mode) and constant contact angle (CCA mode) evaporation to rapidly reach an equilibrium state during droplet evaporation.

Probing loop quantum gravity with evaporating black holes.

Science.gov (United States)

Barrau, A; Cailleteau, T; Cao, X; Diaz-Polo, J; Grain, J

2011-12-16

This Letter aims at showing that the observation of evaporating black holes should allow the usual Hawking behavior to be distinguished from loop quantum gravity (LQG) expectations. We present a full Monte Carlo simulation of the evaporation in LQG and statistical tests that discriminate between competing models. We conclude that contrarily to what was commonly thought, the discreteness of the area in LQG leads to characteristic features that qualify evaporating black holes as objects that could reveal quantum gravity footprints. © 2011 American Physical Society

Evaporation from Lake Mead, Nevada and Arizona, March 2010 through February 2012

Science.gov (United States)

Moreo, Michael T.; Swancar, Amy

2013-01-01

Evaporation from Lake Mead was measured using the eddy-covariance method for the 2-year period starting March 2010 and ending February 2012. When corrected for energy imbalances, annual eddy-covariance evaporation was 2,074 and 1,881 millimeters (81.65 and 74.07 inches), within the range of previous estimates. There was a 9-percent decrease in the evaporation rate and a 10-percent increase in the lake surface area during the second year of the study compared to the first. These offsetting factors resulted in a nearly identical 720 million cubic meters (584,000 acre feet) evaporation volume for both years. Monthly evaporation rates were best correlated with wind speed, vapor pressure difference, and atmospheric stability. Differences between individual monthly evaporation and mean monthly evaporation were as much as 20 percent. Net radiation provided most of the energy available for evaporative processes; however, advected heat from the Colorado River was an important energy source during the second year of the study. Peak evaporation lagged peak net radiation by 2 months because a larger proportion of the net radiation that reaches the lake goes to heating up the water column during the spring and summer months. As most of this stored energy is released, higher evaporation rates are sustained during fall months even though net radiation declines. The release of stored heat also fueled nighttime evaporation, which accounted for 37 percent of total evaporation. The annual energy-balance ratio was 0.90 on average and varied only 0.01 between the 2 years, thus implying that 90 percent of estimated available energy was accounted for by turbulent energy measured using the eddy-covariance method. More than 90 percent of the turbulent-flux source area represented the open-water surface, and 94 percent of 30-minute turbulent-flux measurements originated from wind directions where the fetch ranged from 2,000 to 16,000 meters. Evaporation uncertainties were estimated to be 5

Effect of evaporator temperature on vapor compression refrigeration system

Directory of Open Access Journals (Sweden)

Abdullah A.A.A. Al-Rashed

2011-12-01

Full Text Available This paper presents a comparable evaluation of R600a (isobutane, R290 (propane, R134a, R22, for R410A, and R32 an optimized finned-tube evaporator, and analyzes the evaporator effect on the system coefficient of performance (COP. Results concerning the response of a refrigeration system simulation software to an increase in the amount of oil flowing with the refrigerant are presented. It is shown that there is optima of the apparent overheat value, for which either the exchanged heat or the refrigeration coefficient of performance (COP is maximized: consequently, it is not possible to optimize both the refrigeration COP and the evaporator effect. The obtained evaporator optimization results were incorporated in a conventional analysis of the vapor compression system. For a theoretical cycle analysis without accounting for evaporator effects, the COP spread for the studied refrigerants was as high as 11.7%. For cycle simulations including evaporator effects, the COP of R290 was better than that of R22 by up to 3.5%, while the remaining refrigerants performed approximately within a 2% COP band of the R22 baseline for the two condensing temperatures considered.

Effect of mechanical activation on structure changes and reactivity in further chemical modification of lignin.

Science.gov (United States)

Zhao, Xiaohong; Zhang, Yanjuan; Hu, Huayu; Huang, Zuqiang; Yang, Mei; Chen, Dong; Huang, Kai; Huang, Aimin; Qin, Xingzhen; Feng, Zhenfei

2016-10-01

Lignin was treated by mechanical activation (MA) in a customized stirring ball mill, and the structure and reactivity in further esterification were studied. The chemical structure and morphology of MA-treated lignin and the esterified products were analyzed by chemical analysis combined with UV/vis spectrometer, FTIR,NMR, SEM and particle size analyzer. The results showed that MA contributed to the increase of aliphatic hydroxyl, phenolic hydroxyl, carbonyl and carboxyl groups but the decrease of methoxyl groups. Moreover, MA led to the decrease of particle size and the increase of specific surface area and roughness of surface in lignin. The reactivity of lignin was enhanced significantly for the increase of hydroxyl content and the improvement of mass transfer in chemical reaction caused by the changes of molecular structure and morphological structure. The process of MA is green and simple, and is an effective method for enhancing the reactivity of lignin. Copyright © 2016 Elsevier B.V. All rights reserved.

Measurement of grassland evaporation using a surface-layer ...

African Journals Online (AJOL)

Measurement of grassland evaporation using a surface-layer scintillometer. ... Water SA. Journal Home · ABOUT THIS JOURNAL · Advanced Search ... of soil heat flux and net irradiance, evaporation rates were calculated as a residual of the ...

Regulatory off-gas analysis from the evaporation of Hanford simulated waste spiked with organic compounds.

Science.gov (United States)

Saito, Hiroshi H; Calloway, T Bond; Ferrara, Daro M; Choi, Alexander S; White, Thomas L; Gibson, Luther V; Burdette, Mark A

2004-10-01

After strontium/transuranics removal by precipitation followed by cesium/technetium removal by ion exchange, the remaining low-activity waste in the Hanford River Protection Project Waste Treatment Plant is to be concentrated by evaporation before being mixed with glass formers and vitrified. To provide a technical basis to permit the waste treatment facility, a relatively organic-rich Hanford Tank 241-AN-107 waste simulant was spiked with 14 target volatile, semi-volatile, and pesticide compounds and evaporated under vacuum in a bench-scale natural circulation evaporator fitted with an industrial stack off-gas sampler at the Savannah River National Laboratory. An evaporator material balance for the target organics was calculated by combining liquid stream mass and analytical data with off-gas emissions estimates obtained using U.S. Environmental Protection Agency (EPA) SW-846 Methods. Volatile and light semi-volatile organic compounds (1 mm Hg vapor pressure) in the waste simulant were found to largely exit through the condenser vent, while heavier semi-volatiles and pesticides generally remain in the evaporator concentrate. An OLI Environmental Simulation Program (licensed by OLI Systems, Inc.) evaporator model successfully predicted operating conditions and the experimental distribution of the fed target organics exiting in the concentrate, condensate, and off-gas streams, with the exception of a few semi-volatile and pesticide compounds. Comparison with Henry's Law predictions suggests the OLI Environmental Simulation Program model is constrained by available literature data.

The Savannah River Site Replacement High Level Radioactive Waste Evaporator Project

International Nuclear Information System (INIS)

Brock Presgrove, S.

1992-01-01

The Replacement High Level Waste Evaporator Project was conceived in 1985 to reduce the volume of the high level radioactive waste currently stored at the DOE Savannah River Site Tank Farm. Process of the high level waste has been accomplished up to this time using Bent Tube type evaporators and therefore, that type evaporator was selected for this project. The Title I Design of the project was 70% completed in late 1990. The Department of Energy at that time hired an independent consulting firm to perform a complete review of the project. The DOE placed a STOP ORDER on purchasing the evaporator in January 1991. Essentially, no construction was to be done on the project until all findings and concerns dealing with the type and design of the evaporator are resolved. This report addresses two aspects of the DOE design review: Comparing the Bent Tube Evaporator with the Forced Circulation Evaporator; The design portion of the DOE Project Review - concentrated on the mechanical design properties of the evaporator. (author)

Method of suppressing evaporation loss of ruthenium

International Nuclear Information System (INIS)

Muromura, Tadazumi; Sato, Tadashi.

1987-01-01

Purpose: To prevent evaporation loss of ruthenium from liquid wastes by adding an aluminum compound upon applying evaporating and drying to solid treatment to reprocessing liquid wastes for spent fuels. Method: An aluminum compound such as aluminum nitrate or aluminum hydroxide to reprocessing liquid wastes of spent fuels such that aluminum/ruthenium mixing ratio corresponds to 1.3 - 70.0 by g/atom ratio (0.34 - 187 by weight ratio), and the liquid mixture is heated to a temperature of about 130 deg C to be evaporated and dried to solidness. This enables to recover ruthenium without settling and depositing insoluble matters in the liquid wastes and without decomposing nitric acid. (Yoshino, Y.)

Leader completes installation of process water evaporation system

Energy Technology Data Exchange (ETDEWEB)

Anon.

2005-11-01

The installation of a patent-pending evaporation system at a facility in northeast British Columbia was discussed. The system captures excess waste exhaust heat from natural gas-fired compressor engines and is used to evaporate process water. The disposal of process water is a major cost in the production of natural gas and is usually hauled and disposed at water disposal wells located off-site. The cost to truck and dispose of the water at the facility was estimated at between $30 to $40 per cubic metre. The evaporation system can evaporate 4 to 8 cubic metres of process water every 24 hours and has an estimated useful life of 20 years. The evaporator relies on heat that would otherwise be expelled directly into the atmosphere, and the systems are expected to provide substantial savings. A wide-ranging manufacturing and marketing strategy was expected to commence by the end of 2005. With rising energy prices, operators of facilities are seeking more efficient ways of managing energy needs. The system was created by Leader Energy Services Ltd., a company that provides essential field services for oil and gas well stimulation in Alberta.

Activation of chalcogens and chalcogenides at reactive uranium centers

Energy Technology Data Exchange (ETDEWEB)

Franke, Michael Sebastian

2015-07-23

The high reactivity of many trivalent uranium complexes was investigated in the Meyer group, however, these studies were not limited to small-molecule activation, but were extended to other relatively inert reagents like the heavier elemental chalcogens sulfur, selenium, and tellurium. The tripodal N-anchored chelate ({sup Ad,Me}ArO){sub 3}N{sup 3-} (trianion of tris(3-Adamantyl-2-hydroxy-5-methylbenzyl)amine) was found to be a very suitable candidate for this task and the respective uranium(III) complex [(({sup Ad,Me}ArO){sub 3}N)U{sup III}(DME)] is able to activate elemental sulfur and selenium to form the dinuclear, chalcogenido-bridged complexes [{(("A"d","M"eArO)_3N)U"I"V(DME)}{sub 2}(μ-E)] (E = S, Se). Starting from this previously accomplished work, research in this thesis aimed at furthering reactivity studies of trivalent [(({sup Ad,Me}ArO){sub 3}N)U{sup III}(DME)], but also its chalcogenido-bridged uranium(IV) products, and the spectroscopic characterization of all newly synthesized compounds. Furthermore, the development of the new phenol HOAr* (Ar* = 2,6-(CHPh{sub 2}){sub 2}-4-Me-C{sub 6}H{sub 2}, 2,6-bis(diphenylmethyl)-4-methylphenyl) and its establishment as a ligand to be used for uranium coordination chemistry was another goal of this thesis. The activation of CO{sub 2} by uranium(III) complex [(({sup Ad,Me}ArO){sub 3}N)U{sup III}(DME)] to yield the dinuclear, carbonate-bridged uranium(IV/IV) complex [{(("A"d","M"eArO)_3N)U"I"V(DME)}{sub 2}(μ-κ{sup 1}:κ{sup 2}-CO{sub 3})] and CO was reported in 2010 by Meyer and co-workers. These previous results led to the pursuit of the isolation of mixed chalcogenocarbonate complexes from the reaction of the bridging chalcogenidos [{(("A"d","M"eArO)_3N)U"I"V(DME)}{sub 2}(μ-E)] (E = S, Se) with either CO{sub 2} or its heterocumulene analogs COS or CS{sub 2}. The chalcogeno-carbonates [{(("A"d","M"eArO)_3N)U"I"V(DME)}{sub 2}(μ-κ{sup 1}:κ{sup 2}-CO{sub 2}E)] und [{(("A"d","M"eArO)_3N)U"I"V-(DME)}{sub 2}(�

Atmospheric evaporative demand observations, estimates and driving factors in Spain (1961-2011)

KAUST Repository

Azorin-Molina, Cesar

2015-04-01

We analyzed the spatio-temporal evolution of evaporation observations from Piché atmometers (1961-2011; 56 stations) and Pan evaporimeters (1984-2011; 21 stations) across Spain, and compared both measurements with evaporation estimates obtained by four physical models: i.e., Food and Agricultural Organization-56 Penman-Monteith, Food and Agricultural Organization-Pan, PenPan and Penman, based on climate data. In this study we observed a positive and statistically significant correlation between Piché and Pan evaporation measurements during the common period (1984-2011; 19 stations), mainly in summer. When evaporation observations and estimates were compared, we detected positive and statistically significant correlations with the four methods, except for winter. Among the four physical models, the FAO-Pan showed the best fitting to both Piché and Pan evaporation measurements; the PenPan model overestimated evaporation rates; and the FAO-Penman-Monteith and Penman methods underestimated evaporation observations. We also observed a better spatial agreement between Pan evaporation and estimates than that obtained by Piché measurements. Annual and seasonal trends of evaporation estimates show a statistically significant increase for 1961-2011, which do not agree with long-term Piché evaporation trends; e.g. a discontinuity was found around the 1980s. Radiative and aerodynamic driving factors suggest that this discontinuity, and the observed evaporation trends across Spain could be associated with the abrupt increase in air temperature observed during last few decades (i.e., global warming). Further investigations using available Piché evaporation observations for other regions are needed to better understand physical components influencing long-term trends of evaporation.

Atmospheric evaporative demand observations, estimates and driving factors in Spain (1961-2011)

KAUST Repository

Azorin-Molina, Cesar; Vicente-Serrano, Sergio M.; Sanchez-Lorenzo, Arturo; McVicar, Tim R.; Morá n-Tejeda, Enrique; Revuelto, Jesú s; El Kenawy, Ahmed M.; Martí n-Herná ndez, Natalia; Tomà s, M.

2015-01-01

We analyzed the spatio-temporal evolution of evaporation observations from Piché atmometers (1961-2011; 56 stations) and Pan evaporimeters (1984-2011; 21 stations) across Spain, and compared both measurements with evaporation estimates obtained by four physical models: i.e., Food and Agricultural Organization-56 Penman-Monteith, Food and Agricultural Organization-Pan, PenPan and Penman, based on climate data. In this study we observed a positive and statistically significant correlation between Piché and Pan evaporation measurements during the common period (1984-2011; 19 stations), mainly in summer. When evaporation observations and estimates were compared, we detected positive and statistically significant correlations with the four methods, except for winter. Among the four physical models, the FAO-Pan showed the best fitting to both Piché and Pan evaporation measurements; the PenPan model overestimated evaporation rates; and the FAO-Penman-Monteith and Penman methods underestimated evaporation observations. We also observed a better spatial agreement between Pan evaporation and estimates than that obtained by Piché measurements. Annual and seasonal trends of evaporation estimates show a statistically significant increase for 1961-2011, which do not agree with long-term Piché evaporation trends; e.g. a discontinuity was found around the 1980s. Radiative and aerodynamic driving factors suggest that this discontinuity, and the observed evaporation trends across Spain could be associated with the abrupt increase in air temperature observed during last few decades (i.e., global warming). Further investigations using available Piché evaporation observations for other regions are needed to better understand physical components influencing long-term trends of evaporation.

Semiclassical Approach to Black Hole Evaporation

OpenAIRE

Lowe, David A.

1992-01-01

Black hole evaporation may lead to massive or massless remnants, or naked singularities. This paper investigates this process in the context of two quite different two dimensional black hole models. The first is the original CGHS model, the second is another two dimensional dilaton-gravity model, but with properties much closer to physics in the real, four dimensional, world. Numerical simulations are performed of the formation and subsequent evaporation of black holes and the results are fou...

Concentration of involatile salts at evaporating water surfaces

International Nuclear Information System (INIS)

Gardner, G.C.

1988-02-01

Safety cases for the PWR often need to know how much of the soluble salts in the water will evaporate with the steam during flashing and when the steam is discharged to the atmosphere. Some ideal evaporating systems to give guidance. Simple formulae are derived for the surface concentration relative to the bulk concentration. An analysis is also presented which derives a formula for the mass transfer process in the steam due to both diffusion and convection, which arises from the evaporation process. The convection process will usually dominate. (author)

Influence of evaporation conditions of Alq3 on the performance of organic light emitting diodes

International Nuclear Information System (INIS)

Zhang Fujun; Xu Zheng; Zhao Dewei; Zhao Suling; Jiang Weiwei; Yuan Guangcai; Song Dandan; Wang Yongsheng; Xu Xurong

2007-01-01

The influence of evaporation conditions of organic semiconductor material tris(8-hydroxyquinoline)aluminium (Alq 3 ) on the performance of organic light emitting diodes (OLEDs) is reported. In the process of organic material thermal evaporation, the chamber was dark or had white light from a 100 W filament lamp. The devices prepared in the dark show higher emission intensity and efficiency compared with the ones prepared in white light under the same driving voltage. Atomic force microscopy measurements show that surface morphology and phase of Alq 3 thin films are quite different for the previous cases. The different evaporation conditions are found to have direct effects on the electrical and luminance performance. The Alq 3 thin films prepared in the dark as active emission layers of OLEDs show higher intensity and efficiency

performance evaluation of a composite-padded evaporative cooling

African Journals Online (AJOL)

user

average temperature drop and saturation efficiency in the evaporative cooler during the no-load test were 5°C and 42%, ... flow rate wetting the pad and the construction material .... principle of evaporation which results in a cooling effect.

Marangoni Flow Induced Evaporation Enhancement on Binary Sessile Drops.

Science.gov (United States)

Chen, Pin; Harmand, Souad; Ouenzerfi, Safouene; Schiffler, Jesse

2017-06-15

The evaporation processes of pure water, pure 1-butanol, and 5% 1-butanol aqueous solution drops on heated hydrophobic substrates are investigated to determine the effect of temperature on the drop evaporation behavior. The evolution of the parameters (contact angle, diameter, and volume) during evaporation measured using a drop shape analyzer and the infrared thermal mapping of the drop surface recorded by an infrared camera were used in investigating the evaporation process. The pure 1-butanol drop does not show any thermal instability at different substrate temperatures, while the convection cells created by the thermal Marangoni effect appear on the surface of the pure water drop from 50 °C. Because 1-butanol and water have different surface tensions, the infrared video of the 5% 1-butanol aqueous solution drop shows that the convection cells are generated by the solutal Marangoni effect at any substrate temperature. Furthermore, when the substrate temperature exceeds 50 °C, coexistence of the thermal and solutal Marangoni flows is observed. By analyzing the relation between the ratio of the evaporation rate of pure water and 1-butanol aqueous solution drops and the Marangoni number, a series of empirical equations for predicting the evaporation rates of pure water and 1-butanol aqueous solution drops at the initial time as well as the equations for the evaporation rate of 1-butanol aqueous solution drop before the depletion of alcohol are derived. The results of these equations correspond fairly well to the experimental data.

Evaporative demand, transpiration, and photosynthesis: How are they changing?

Science.gov (United States)

Farquhar, G. D.; Roderick, M. L.

2009-04-01

Carbon dioxide concentration is increasing. This affects photosynthesis via increases in substrate availability (Farquhar et al. 1980). It reduces the amount of water transpired by plants to fix a given amount of carbon into an organic form; i.e it increases transpiration efficiency (Wong et al. 1979). It also warms the earth's surface. It is commonly supposed that this warming causes an increase in evaporative demand - the rate of water loss from a wet surface. This supposition has then been extended to effects on plant water availability, with the idea that there would be offsets to the gains in productivity associated with increased transpiration efficiency. The assumption that increased temperature means increased evaporative demand has also been applied to global maps of changes in soil water content. However, observations of pan evaporation rate show that this measure of evaporative demand has been decreasing in most areas examined over the last few decades. We reconcile these observations with theory by noting that, on long time scales, warming also involves water bodies, so that the vapour pressure at the earth's surface also increases. Using the physics of pan evaporation (Rotstayn et al. 2006) we show that the reduction in evaporative demand has been associated with two main effects, (1) "dimming", a reduction in sunlight received at the earth's surface because of aerosols and clouds, being the first phenomenon identified (Roderick and Farquhar 2002), and (2) "stilling", a reduction in wind speed, being the second (Roderick et al. 2007). We show that better accounting for changes in evaporative demand is important for estimating soil water changes, particularly in regions where precipitation exceeds evaporative demand (i.e where there are rivers) (Hobbins et al. 2008). We synthesise some of these results with others on vegetation change. References: Farquhar, GD, von Caemmerer, S, and Berry, JA, 1980: A biochemical model of photosynthetic CO2 assimilation

Refrigerant falling film evaporation review: Description, fluid dynamics and heat transfer

International Nuclear Information System (INIS)

Fernández-Seara, José; Pardiñas, Ángel Á.

2014-01-01

Falling film horizontal tube evaporators for refrigeration equipment are an interesting alternative to pool boiling evaporators concerning operation costs, safety, thermodynamic efficiency, charge of refrigerant or size. Plenty of literature works studied falling film evaporation, but for its application in fields such as desalination and petrochemical industry or OTEC. This review focuses mainly on those works from the literature that analysed the main issues of falling film evaporation of refrigerants, to better understand heat transfer and fluid dynamics in such evaporators. First, falling film evaporation is described and compared to pool boiling, to define its main advantages and inconveniences. Then, the literature concerning film around the tubes and between them is analysed, as well as the phenomenon of film breakdown, which sharply deteriorates the heat transfer performance of falling film evaporators. After it, the results from those works that studied analytically and experimentally the heat transfer coefficients (HTCs) with different types of tubes and refrigerants are discussed. The review finishes with a brief summary of important parameters of falling film evaporation, which might be useful for the design of such equipment. - Highlights: •We defined falling film evaporation and compared it with pool boiling. •We reviewed works from the literature concerning refrigerant falling film evaporation. •We classified the ideas from the works attending to crucial aspects of the process. •We developed a summary of the main ideas which could be useful for design purpose

Evaluation of the correlations for predicting evaporative loss from water body

International Nuclear Information System (INIS)

Yilmaz, T.P.; Aybar, H.S.

1999-01-01

Water evaporation (evaporation from here on) is a natural phenomenon that is important for system design and system safety in many engineering branches. Indeed, evaporative heat and mass loss are observed and calculated in very diverse situations, such as irrigation plants, water purification plants, cooling ponds, lakes, dams, swimming pools, health spas, management of liquid wastes as in evaporation pools, and spent fuel pools in nuclear power plants. There are a number of correlations obtained from experimental studies that predict the evaporative heat and mass loss from a water body. This study aims to summarize and to compare the existing evaporation correlations to determine the upper and lower bounding correlations for use in various thermal-hydraulic analyses of systems. Currently and widely used, six correlations found in the literature have been selected and tested using the major parameters of evaporation such as water temperature, air relative humidity, air velocity, and temperature. The comparison test cases show that ASHRAE (1991) and Ryan et al. (1974) equations result in the highest evaporative loss, while the Brady et al. (1969) equation provides the lowest evaporative loss in most conditions. Engineering designers may sometimes need the upper bound value of evaporative loss or sometimes the lower bound value for a conservative calculation. The authors conclude that using a single equation does not provide the conservative calculation for every situation and show which correlation gives the lower or upper bound for different conditions

A Method for a Multi-Platform Approach to Generate Gridded Surface Evaporation

Science.gov (United States)

Badger, A.; Livneh, B.; Small, E. E.; Abolafia-Rosenzweig, R.

2017-12-01

Evapotranspiration is an integral component of the surface water balance. While there are many estimates of evapotranspiration, there are fewer estimates that partition evapotranspiration into evaporation and transpiration components. This study aims to generate a CONUS-scale, observationally-based soil evaporation dataset by using the time difference of surface soil moisture by Soil Moisture Active Passive (SMAP) satellite with adjustments for transpiration and a bottom flux out of the surface layer. In concert with SMAP, the Moderate-Resolution Imaging Spectroradiometer (MODIS) satellite, North American Land Data Assimilation Systems (NLDAS) and the Hydrus-1D model are used to fully analyze the surface water balance. A biome specific estimate of the total terrestrial ET is calculated through a variation of the Penman-Monteith equation with NLDAS forcing and NLDAS Noah Model output for meteorological variables. A root density restriction and SMAP-based soil moisture restriction are applied to obtain terrestrial transpiration estimates. By forcing Hydrus-1D with NLDAS meteorology and our terrestrial transpiration estimates, an estimate of the flux between the soil surface and root zone layers (qbot) will dictate the proportion of water that is available for soil evaporation. After constraining transpiration and the bottom flux from the surface layer, we estimate soil evaporation as the residual of the surface water balance. Application of this method at Fluxnet sites shows soil evaporation estimates of approximately 0­3 mm/day and less than ET estimates. Expanding this methodology to produce a gridded product for CONUS, and eventually a global-scale product, will enable a better understanding of water balance processes and contribute a dataset to validate land-surface model's surface flux processes.

The influence of the surface composition of mixed monolayer films on the evaporation coefficient of water.

Science.gov (United States)

Miles, Rachael E H; Davies, James F; Reid, Jonathan P

2016-07-20

coated particle, the droplet is found to have lost a greater proportion of its initial water content. A greater degree of slowing in the evaporative flux can be achieved by increasing the chain length of the surface active alcohol, leading to a greater degree of dehydration.

Flashing evaporation under different pressure levels

International Nuclear Information System (INIS)

Liao, Yixiang; Lucas, Dirk; Krepper, Eckhard; Rzehak, Roland

2013-01-01

Highlights: • CFD simulation based on two-fluid model for flashing boiling inside a vertical pipe. • Effect of pressure level on the maximum thermal energy available for evaporation. • Effect of presumed bubble size on the onset of flashing as well as evaporation rate. • Effect of pressure level on the critical bubble size that can start stable flashing. • Effect of pressure level on nucleation rate and mechanism. - Abstract: Flashing evaporation of water inside a vertical pipe under four pressure levels is investigated both experimentally and numerically. In the experiment depressurization is realized through a blow-off valve, and the evaporation rate is controlled by the opening rate and degree of the valve. In the CFD simulation phase change is assumed to be caused by thermal heat transfer between steam–water interface and the surrounding water. Consequently, the evaporation rate is determined by heat transfer coefficient, interfacial area density as well as liquid superheat degree. The simulated temporal course of cross-section averaged steam volume fraction is compared with the measured one. It is found that the increasing rate and maximum value of steam volume fraction is over-predicted under low-pressure conditions, which is mainly caused by the neglect of bubble growth in the mono-dispersed simulation. The agreement is notably improved by performing poly-dispersed simulations with the inhomogeneous MUSIG approach (IMUSIG). On the other hand an underestimation of the maximum steam volume fraction is observed in high-pressure cases, since the contribution of nucleation to the total steam generation rate becomes large as the system pressure increases. Reliable models for nucleation rate as well as bubble detachment size are indispensable for reliable predictions. An effect of the system pressure level on the nucleation mechanism is observed in the experiment

The evaporative fraction as a measure of surface energy partitioning

Energy Technology Data Exchange (ETDEWEB)

Nichols, W.E. [Pacific Northwest Lab., Richland, WA (United States); Cuenca, R.H. [Oregon State Univ., Corvallis, OR (United States)

1990-12-31

The evaporative fraction is a ratio that expresses the proportion of turbulent flux energy over land surfaces devoted to evaporation and transpiration (evapotranspiration). It has been used to characterize the energy partition over land surfaces and has potential for inferring daily energy balance information based on mid-day remote sensing measurements. The HAPEX-MOBILHY program`s SAMER system provided surface energy balance data over a range of agricultural crops and soil types. The databases from this large-scale field experiment was analyzed for the purpose of studying the behavior and daylight stability of the evaporative fraction in both ideal and general meteorological conditions. Strong linear relations were found to exist between the mid-day evaporative fraction and the daylight mean evaporative fraction. Statistical tests however rejected the hypothesis that the two quantities were equal. The relations between the evaporative fraction and the surface soil moisture as well as soil moisture in the complete vegetation root zone were also explored.

The evaporative fraction as a measure of surface energy partitioning

Energy Technology Data Exchange (ETDEWEB)

Nichols, W.E. (Pacific Northwest Lab., Richland, WA (United States)); Cuenca, R.H. (Oregon State Univ., Corvallis, OR (United States))

1990-01-01

The evaporative fraction is a ratio that expresses the proportion of turbulent flux energy over land surfaces devoted to evaporation and transpiration (evapotranspiration). It has been used to characterize the energy partition over land surfaces and has potential for inferring daily energy balance information based on mid-day remote sensing measurements. The HAPEX-MOBILHY program's SAMER system provided surface energy balance data over a range of agricultural crops and soil types. The databases from this large-scale field experiment was analyzed for the purpose of studying the behavior and daylight stability of the evaporative fraction in both ideal and general meteorological conditions. Strong linear relations were found to exist between the mid-day evaporative fraction and the daylight mean evaporative fraction. Statistical tests however rejected the hypothesis that the two quantities were equal. The relations between the evaporative fraction and the surface soil moisture as well as soil moisture in the complete vegetation root zone were also explored.

Evaporation rate of water in hydrophobic confinement.

Science.gov (United States)

Sharma, Sumit; Debenedetti, Pablo G

2012-03-20

The drying of hydrophobic cavities is believed to play an important role in biophysical phenomena such as the folding of globular proteins, the opening and closing of ligand-gated ion channels, and ligand binding to hydrophobic pockets. We use forward flux sampling, a molecular simulation technique, to compute the rate of capillary evaporation of water confined between two hydrophobic surfaces separated by nanoscopic gaps, as a function of gap, surface size, and temperature. Over the range of conditions investigated (gaps between 9 and 14 Å and surface areas between 1 and 9 nm(2)), the free energy barrier to evaporation scales linearly with the gap between hydrophobic surfaces, suggesting that line tension makes the predominant contribution to the free energy barrier. The exponential dependence of the evaporation rate on the gap between confining surfaces causes a 10 order-of-magnitude decrease in the rate when the gap increases from 9 to 14 Å. The computed free energy barriers are of the order of 50 kT and are predominantly enthalpic. Evaporation rates per unit area are found to be two orders of magnitude faster in confinement by the larger (9 nm(2)) than by the smaller (1 nm(2)) surfaces considered here, at otherwise identical conditions. We show that this rate enhancement is a consequence of the dependence of hydrophobic hydration on the size of solvated objects. For sufficiently large surfaces, the critical nucleus for the evaporation process is a gap-spanning vapor tube.

Quantification of soil water evaporation using TDR-microlysimetry

Science.gov (United States)

Soil water evaporation is conventionally measured using microlysimeters by evaluating the daily change in mass. Daily removal is laborious and replacement immediately after irrigation events is impractical because of field wetness which leads to delays and an underestimation of evaporation. Irrigati...

Cost of reactive nitrogen release from human activities to the environment in the United States

Science.gov (United States)

The leakage of reactive nitrogen (N) from human activities to the environment can cause human health and ecological problems. Often these harmful effects are not reflected in the costs of food, fuel, and fiber that derive from N use. Spatial analyses of economic costs and benef...

Defense Waste Processing Facility Recycle Stream Evaporation

International Nuclear Information System (INIS)

STONE, MICHAEL

2006-01-01

The Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) stabilizes high level radioactive waste (HLW) by vitrification of the waste slurries. DWPF currently produces approximately five gallons of dilute recycle for each gallon of waste vitrified. This recycle stream is currently sent to the HLW tank farm at SRS where it is processed through the HLW evaporators with the concentrate eventually sent back to the DWPF for stabilization. Limitations of the HLW evaporators and storage space constraints in the tank farm have the potential to impact the operation of the DWPF and could limit the rate that HLW is stabilized. After an evaluation of various alternatives, installation of a dedicated evaporator for the DWPF recycle stream was selected for further evaluation. The recycle stream consists primarily of process condensates from the pretreatment and vitrification processes. Other recycle streams consist of process samples, sample line flushes, sump flushes, and cleaning solutions from the decontamination and filter dissolution processes. The condensate from the vitrification process contains some species, such as sulfate, that are not appreciably volatile at low temperature and could accumulate in the system if 100% of the evaporator concentrate was returned to DWPF. These species are currently removed as required by solids washing in the tank farm. The cleaning solutions are much higher in solids content than the other streams and are generated 5-6 times per year. The proposed evaporator would be required to concentrate the recycle stream by a factor of 30 to allow the concentrate to be recycled directly to the DWPF process, with a purge stream sent to the tank farm as required to prevent buildup of sulfate and similar species in the process. The overheads are required to meet stringent constraints to allow the condensate to be sent directly to an effluent treatment plant. The proposed evaporator would nearly de-couple the DWPF process from the

Linking soil type and rainfall characteristics towards estimation of surface evaporative capacitance

Science.gov (United States)

Or, D.; Bickel, S.; Lehmann, P.

2017-12-01

Separation of evapotranspiration (ET) to evaporation (E) and transpiration (T) components for attribution of surface fluxes or for assessment of isotope fractionation in groundwater remains a challenge. Regional estimates of soil evaporation often rely on plant-based (Penman-Monteith) ET estimates where is E is obtained as a residual or a fraction of potential evaporation. We propose a novel method for estimating E from soil-specific properties, regional rainfall characteristics and considering concurrent internal drainage that shelters soil water from evaporation. A soil-dependent evaporative characteristic length defines a depth below which soil water cannot be pulled to the surface by capillarity; this depth determines the maximal soil evaporative capacitance (SEC). The SEC is recharged by rainfall and subsequently emptied by competition between drainage and surface evaporation (considering canopy interception evaporation). We show that E is strongly dependent on rainfall characteristics (mean annual, number of storms) and soil textural type, with up to 50% of rainfall lost to evaporation in loamy soil. The SEC concept applied to different soil types and climatic regions offers direct bounds on regional surface evaporation independent of plant-based parameterization or energy balance calculations.

Deposition of silicon films in presence of nitrogen plasma— A ...

Indian Academy of Sciences (India)

Unknown

Abstract. A design, development and validation work of plasma based 'activated reactive evaporation (ARE) system' is implemented for the deposition of the silicon films in presence of nitrogen plasma on substrate maintained at room temperature. This plasma based deposition system involves evaporation of pure silicon by.

Using evaporation to control capillary instabilities in micro-systems.

Science.gov (United States)

Ledesma-Aguilar, Rodrigo; Laghezza, Gianluca; Yeomans, Julia M; Vella, Dominic

2017-12-06

The instabilities of fluid interfaces represent both a limitation and an opportunity for the fabrication of small-scale devices. Just as non-uniform capillary pressures can destroy micro-electrical mechanical systems (MEMS), so they can guide the assembly of novel solid and fluid structures. In many such applications the interface appears during an evaporation process and is therefore only present temporarily. It is commonly assumed that this evaporation simply guides the interface through a sequence of equilibrium configurations, and that the rate of evaporation only sets the timescale of this sequence. Here, we use Lattice-Boltzmann simulations and a theoretical analysis to show that, in fact, the rate of evaporation can be a factor in determining the onset and form of dynamical capillary instabilities. Our results shed light on the role of evaporation in previous experiments, and open the possibility of exploiting diffusive mass transfer to directly control capillary flows in MEMS applications.

Evaporation and skin penetration characteristics of mosquito repellent formulations

International Nuclear Information System (INIS)

Reifenrath, W.G.; Hawkins, G.S.; Kurtz, M.S.

1989-01-01

Formulations of the mosquito repellent N,N-diethyl-3-methylbenzamide (deet) in combination with a variety of additives were developed to control repellent evaporation and percutaneous penetration. Deet was also formulated with the repellent dimethyl phthalate to study the interaction of the two compounds on the skin. The evaporation and penetration processes were evaluated on whole and split-thickness pig skin using radiolabeled repellents with an in vitro apparatus. Under essentially still air and air flow conditions, one of the deet formulations resulted in significantly reduced total evaporation and percutaneous penetration of deet as compared to unformulated repellent. When deet and dimethyl phthalate were combined, neither repellent affected the total amount of evaporation and penetration of the other compound. However, initial percutaneous penetration and evaporation rates were slightly less and decayed less rapidly than when both chemicals were tested separately at the same dose. These results indicated a degree of competition of the two compounds for the same avenues of loss

Influence of electron evaporative cooling on ultracold plasma expansion

International Nuclear Information System (INIS)

Wilson, Truman; Chen, Wei-Ting; Roberts, Jacob

2013-01-01

The expansion of ultracold neutral plasmas (UCP) is driven primarily by the thermal pressure of the electron component and is therefore sensitive to the electron temperature. For typical UCP spatial extents, evaporative cooling has a significant influence on the UCP expansion rate at lower densities (less than 10 8 /cm 3 ). We studied the effect of electron evaporation in this density range. Owing to the low density, the effects of three-body recombination were negligible. We modeled the expansion by taking into account the change in electron temperature owing to evaporation as well as adiabatic expansion and found good agreement with our data. We also developed a simple model for initial evaporation over a range of ultracold plasma densities, sizes, and electron temperatures to determine over what parameter range electron evaporation is expected to have a significant effect. We also report on a signal calibration technique, which relates the signal at our detector to the total number of ions and electrons in the ultracold plasma