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Sample records for acrylonitrile potentiates hearing

  1. Acrylonitrile Potentiates Noise-Induced Hearing Loss in Rat

    Fechter, Laurence D.; Gearhart, Caroline; Shirwany, Najeeb A

    2003-01-01

    Acrylonitrile, one of the 50 most commonly produced industrial chemicals, has recently been identified as a promoter of noise-induced hearing loss (NIHL). This agent has the potential to produce oxidative stress through multiple pathways. We hypothesize that acrylonitrile potentiates NIHL as a consequence of oxidative stress. The objectives of this study were to characterize acrylonitrile exposure conditions that promote permanent NIHL in rats and determine the ability of this nitrile to prod...

  2. Acrylonitrile potentiates hearing loss and cochlear damage induced by moderate noise exposure in rats

    The diversity of chemical and drugs that can potentiate noise-induced hearing loss (NIHL) has impeded efforts to predict such interactions. We have hypothesized that chemical contaminants that disrupt intrinsic antioxidant defenses hold significant risk for potentiating NIHL. If this is true, then acrylonitrile (ACN) would be expected to potentiate NIHL. ACN, one of the 50 most commonly used chemicals in the United States, is metabolized via two pathways that are likely to disrupt intrinsic reactive oxygen species (ROS) buffering systems: (1) it conjugates glutathione, depleting this important antioxidant rapidly; (2) a second pathway involves the formation of cyanide, which can inhibit superoxide dismutase. We hypothesized that moderate noise exposure, that does not produce permanent hearing loss by itself, could initiate oxidative stress and that ACN could render the inner ear more sensitive to noise by disrupting intrinsic antioxidant defenses. Temporary and persistent effects of ACN alone (50 mg/kg, sc 5 days), noise alone (95 or 97 dB octave band noise, 4 h/day for 5 days), or ACN in combination with noise were determined using distortion product otoacoustic emissions (DPOAEs) and compound action potential (CAP) amplitudes. Histopathological damage to hair cells resulting from these treatments was also investigated using surface preparations of the organ of Corti. Individually, neither ACN nor noise exposures caused any permanent hearing or hair cell loss; only a reversible temporary threshold shift was measured in noise-exposed animals. However, when given in combination, ACN and noise induced permanent threshold shifts (13-16 dB between 7 and 40 kHz) and a decrease in DPOAE amplitudes (up to 25 dB at 19 kHz), as well as significant outer hair cell (OHC) loss (up to 20% in the first row between 13 and 47 kHz). This investigation demonstrates that ACN can potentiate NIHL at noise levels that are realistic in terms of human exposure, and that the OHCs are the

  3. Determination of potentially carcinogenic compounds in food : trace analysis of vinylchloride, vinylidenechloride, acrylonitrile, epichlorohydrin and diethylpyrocarbonate

    Lierop, van J.B.H.

    1979-01-01

    Toxicological evidence shows that some monomers present in packaging materials may be carcinogenic. These monomers, notably vinylchloride, vinylidenechloride, acrylonitrile and epichlorohydrin, may migrate from the packaging material into the food. Therefore, severe limits are set to the contents of

  4. Synthesis and Thermal Properties of Acrylonitrile/Butyl Acrylate/Fumaronitrile and Acrylonitrile/Ethyl Hexyl Acrylate/Fumaronitrile Terpolymers as a Potential Precursor for Carbon Fiber

    Siti Nurul Ain Md Jamil

    2014-09-01

    Full Text Available A synthesis of acrylonitrile (AN/butyl acrylate (BA/fumaronitrile (FN and AN/EHA (ethyl hexyl acrylate/FN terpolymers was carried out by redox polymerization using sodium bisulfite (SBS and potassium persulphate (KPS as initiator at 40 °C. The effect of comonomers, BA and EHA and termonomer, FN on the glass transition temperature (Tg and stabilization temperature was studied using Differential Scanning Calorimetry (DSC. The degradation behavior and char yield were obtained by Thermogravimetric Analysis. The conversions of AN, comonomers (BA and EHA and FN were 55%–71%, 85%–91% and 76%–79%, respectively. It was found that with the same comonomer feed (10%, the Tg of AN/EHA copolymer was lower at 63 °C compared to AN/BA copolymer (70 °C. AN/EHA/FN terpolymer also exhibited a lower Tg at 63 °C when compared to that of the AN/BA/FN terpolymer (67 °C. By incorporating BA and EHA into a PAN system, the char yield was reduced to ~38.0% compared to that of AN (~47.7%. It was found that FN reduced the initial cyclization temperature of AN/BA/FN and AN/EHA/FN terpolymers to 228 and 221 °C, respectively, in comparison to that of AN/BA and AN/EHA copolymers (~260 °C. In addition, FN reduced the heat liberation per unit time during the stabilization process that consequently reduced the emission of volatile group during this process. As a result, the char yields of AN/BA/FN and AN/EHA/FN terpolymers are higher at ~45.1% and ~43.9%, respectively, as compared to those of AN/BA copolymer (37.1% and AN/EHA copolymer (38.0%.

  5. Selective Vulnerability of the Cochlear Basal Turn to Acrylonitrile and Noise

    B. Pouyatos

    2009-01-01

    Full Text Available Exposure to acrylonitrile, a high-production industrial chemical, can promote noise-induced hearing loss (NIHL in the rat even though this agent does not itself produce permanent hearing loss. The mechanism by which acrylonitrile promotes NIHL includes oxidative stress as antioxidant drugs can partially protect the cochlea from acrylonitrile+noise. Acrylonitrile depletes glutathione levels while noise can increase the formation of reactive oxygen species. It was previously noted that the high-frequency or basal turn of the cochlea was particularly vulnerable to the combined effects of acrylonitrile and noise when the octave band noise (OBN was centered at 8 kHz. Normally, such a noise would be expected to yield damage at a more apical region of the cochlea. The present study was designed to determine whether the basal cochlea is selectively sensitive to acrylonitrile or whether, by adjusting the frequency of the noise band, it would be possible to control the region of the auditory impairment. Rats were exposed to one of three different OBNs centered at different frequencies (4 kHz, 110 dB and 8 or 16 kHz at 97 dB for 5 days, with and without administration of acrylonitrile (50 mg/kg/day. The noise was set to cause limited NIHL by itself. Auditory function was monitored by recording distortion products, by compound action potentials, and by performing cochlear histology. While the ACN-only and noise-only exposures induced no or little permanent auditory loss, the three exposures to acrylonitrile+noise produced similar auditory and cochlear impairments above 16 kHz, despite the fact that the noise exposures covered 2 octaves. These observations show that the basal cochlea is much more sensitive to acrylonitrile+noise than the apical partition. They provide an initial basis for distinguishing the pattern of cochlear injury that results from noise exposure from that which occurs due to the combined effects of noise and a chemical

  6. Auditory Evoked Potential Response and Hearing Loss: A Review

    Paulraj, M. P; Subramaniam, Kamalraj; Yaccob, Sazali Bin; Adom, Abdul H. Bin; Hema, C.R.

    2015-01-01

    Hypoacusis is the most prevalent sensory disability in the world and consequently, it can lead to impede speech in human beings. One best approach to tackle this issue is to conduct early and effective hearing screening test using Electroencephalogram (EEG). EEG based hearing threshold level determination is most suitable for persons who lack verbal communication and behavioral response to sound stimulation. Auditory evoked potential (AEP) is a type of EEG signal emanated from the brain scalp...

  7. A potential source of hearing impairment; headphones

    Technological expansions have been observed in recent years for portable devices with hi-fi audio playback capability such as MP4 players, multimedia phones and hand-held game consoles. Usually these devices are used with headphones; therefore the noise levels of different headphones are of particular relevance. Despite of its several benefits, noise levels can be quite high and may cause hearing impairment. In this research, different headphones were selected to check noise levels at varying volumes. It was found in majority of cases that noise levels ranged from 75dB to 85 dB; surpassing the NEQ's and OSHA standard values. (author)

  8. Theoretical and experimental investigations of the 2-(4-chlorophenyl)-3-{[5-(2-cyano-2-phenylethenyl)]furan-2-yl}acrylonitrile molecule as a potential acceptor in organic solar cells.

    Kazici, Mehmet; Bozar, Sinem; Yuksel, Sureyya Aydin; Ongul, Fatih; Gokce, Halil; Gunes, Serap; Goreci, Cigdem Yorur

    2016-06-10

    A novel soluble asymmetric acrylonitrile derivative, 2-(4-Chlorophenyl)-3-{[5-(2-cyano-2-phenylethenyl)]furan-2-yl}acrylonitrile (CPCPFA, 3) was synthesized in three steps by Knoevenagel condensation. The structure of the CPCPFA was characterized using UV-vis, FTIR, (1)H NMR, (13)C NMR, and LC-MS. CPCPFA was evaluated as an electron acceptor in bulk heterojunction organic solar cells. Its optical and electronic properties as well as photovoltaic performance were investigated. PMID:27145976

  9. Theoretical and experimental investigations of the 2-(4-chlorophenyl)-3-{[5-(2-cyano-2-phenylethenyl)]furan-2-yl}acrylonitrile molecule as a potential acceptor in organic solar cells

    Kazici, Mehmet; Bozar, Sinem; Aydin Yuksel, Sureyya; Ongul, Fatih; Gokce, Halil; Gunes, Serap; Yorur Goreci, Cigdem

    2016-06-01

    A novel soluble asymmetric acrylonitrile derivative, 2-(4-Chlorophenyl)-3-{[5-(2-cyano-2-phenylethenyl)]furan-2-yl}acrylonitrile (CPCPFA, 3) was synthesized in three steps by Knoevenagel condensation. The structure of the CPCPFA was characterized using UV–vis, FTIR, 1H NMR, 13C NMR, and LC-MS. CPCPFA was evaluated as an electron acceptor in bulk heterojunction organic solar cells. Its optical and electronic properties as well as photovoltaic performance were investigated.

  10. Ocular vestibular evoked myogenic potentials in normal-hearing adults

    Mohammad Kamali

    2012-06-01

    Full Text Available Background and Aim: Ocular vestibular-evoked myogenic potential (oVEMP is a novel vestibular function test. This short-latency response can be recorded through contracting extraocular muscles by high-intensity acoustic stimulation and can be used to evaluate contralateral ocular-vestibular reflex. The aim of this study was to record and compare the amplitude, latency, asymmetry ratio and occurrence percentage of oVEMP (n10 and cervical VEMP (p13 responses in a group of normal adult subjects.Methods: We carried out a cross-sectional study on 20 adult subjects' mean age 22.18 years, SD=2.19 with normal hearing sensitivity and no history of vestibular diseases. oVEMP and cVEMP responses in both ears were recorded using air conducted stimuli 500 Hz short tone burst, 95 dB nHL via insert earphone and compared.Results: cVEMP was recorded in all subjects but oVEMP was absent in two subjects. Mean amplitude and latency were 140.77 μv and 15.56 ms in p13; and 3.18 μv and 9.32 ms in n10. There were statistically significant differences between p13 and n10 amplitudes (p<0.001.Conclusion: This study showed that occurrence percentage and amplitude of oVEMP were less than those of cVEMP. Since these two tests originate from different sections of vestibular nerve, we can consider them as parallel vestibular function tests and utilize them for evaluation of vestibular disorders.

  11. Hearing Screening

    Johnson-Curiskis, Nanette

    2012-01-01

    Hearing levels are threatened by modern life--headsets for music, rock concerts, traffic noises, etc. It is crucial we know our hearing levels so that we can draw attention to potential problems. This exercise requires that students receive a hearing screening for their benefit as well as for making the connection of hearing to listening.

  12. 21 CFR 180.22 - Acrylonitrile copolymers.

    2010-04-01

    ..., distilled water, 8 percent or 50 percent ethanol, 3 percent acetic acid, and either n-heptane or an... conditions for the use of acrylonitrile copolymers have been, or soon will be, undertaken. Toxicity...

  13. Starch Modification by Graft Copolymerization of Acrylonitrile

    刘瑞贤; 李莉; 茹宗玲; 张黎明; 高建平; 田汝川

    2003-01-01

    The graft copolymerization of acrylonitrile (AN) onto starch under the initiation of potassium permanganate was investigated. The effect of various reaction conditions on the graft copolymerization was studied. The relationships between the grafting rate and the initiator concentration of potassium permanganate, monomer acrylonitrile and backbone starch, as well as reaction temperature were established. The oxidation reaction of starch with manganic ions and valence changes of manganic ions during the graft copolymerization were discussed. The results show that manganic ion Mn7+ underwent a series of valence changes during the graft copolymerization: Mn(Ⅶ) → Mn(Ⅳ) → Mn(Ⅲ) → Mn(Ⅱ). The grafting rate of the graft copolymerization of acrylonitrile onto starch is also given.

  14. Cortical Auditory Evoked Potentials Reveal Changes in Audibility with Nonlinear Frequency Compression in Hearing Aids for Children: Clinical Implications.

    Ching, Teresa Y C; Zhang, Vicky W; Hou, Sanna; Van Buynder, Patricia

    2016-02-01

    Hearing loss in children is detected soon after birth via newborn hearing screening. Procedures for early hearing assessment and hearing aid fitting are well established, but methods for evaluating the effectiveness of amplification for young children are limited. One promising approach to validating hearing aid fittings is to measure cortical auditory evoked potentials (CAEPs). This article provides first a brief overview of reports on the use of CAEPs for evaluation of hearing aids. Second, a study that measured CAEPs to evaluate nonlinear frequency compression (NLFC) in hearing aids for 27 children (between 6.1 and 16.8 years old) who have mild to severe hearing loss is reported. There was no significant difference in aided sensation level or the detection of CAEPs for /g/ between NLFC on and off conditions. The activation of NLFC was associated with a significant increase in aided sensation levels for /t/ and /s/. It also was associated with an increase in detection of CAEPs for /t/ and /s/. The findings support the use of CAEPs for checking audibility provided by hearing aids. Based on the current data, a clinical protocol for using CAEPs to validate audibility with amplification is presented. PMID:27587920

  15. Assessment of potential effects of the electromagnetic fields of mobile phones on hearing

    Gradauskiene Egle

    2005-04-01

    Full Text Available Abstract Background Mobile phones have become indispensable as communication tools; however, to date there is only a limited knowledge about interaction between electromagnetic fields (EMF emitted by mobile phones and auditory function. The aim of the study was to assess potential changes in hearing function as a consequence of exposure to low-intensity EMF's produced by mobile phones at frequencies of 900 and 1800 MHz. Methods The within-subject study was performed on thirty volunteers (age 18–30 years with normal hearing to assess possible acute effect of EMF. Participants attended two sessions: genuine and sham exposure of EMF. Hearing threshold levels (HTL on pure tone audiometry (PTA and transient evoked otoacoustic emissions (TEOAE's were recorded before and immediately after 10 min of genuine and/or sham exposure of mobile phone EMF. The administration of genuine or sham exposure was double blind and counterbalanced in order. Results Statistical analysis revealed no significant differences in the mean HTLs of PTA and mean shifts of TEOAE's before and after genuine and/or sham mobile phone EMF 10 min exposure. The data collected showed that average TEOAE levels (averaged across a frequency range changed less than 2.5 dB between pre- and post-, genuine and sham exposure. The greatest individual change was 10 dB, with a decrease in level from pre- to post- real exposure. Conclusion It could be concluded that a 10-min close exposure of EMFs emitted from a mobile phone had no immediate after-effect on measurements of HTL of PTA and TEOAEs in young human subjects and no measurable hearing deterioration was detected in our study.

  16. Catalytic Polymerization of Acrylonitrile by Khulays Bentonite

    Matar M. Al-Esaimi

    2007-04-01

    Full Text Available The aqueous polymerization of acrylonitrile (AN catalyzed with exchanged Khulays bentonite . The influence of various polymerization parameters ( e.g., concentrations of Potassium Persulfate (K2S2O8 and monomer , various of organic solvents, and different temperature has been investigated. It was found that the rate of polymerization of AN was found to be dependent on monomer concentration, initiator and temperature. The activation energy of polymerization was calculated .Thermal properties of the polymer were studied by TGA and DSC techniques. © 2007 CREC UNDIP. All rights reserved.Received: 5 February 2007; Received in revised: 19 April 2007; Accepted: 7 May 2007[How to Cite: M. M. Al-Esaimi. (2007. Catalytic Polymerization of Acrylonitrile by Khulays Bentonite. Bulletin of Chemical Reaction Engineering and Catalysis, 2 (2-3: 32-36.  doi:10.9767/bcrec.2.1.4.6-10][How to Link/DOI: http://dx.doi.org/10.9767/bcrec.2.1.4.6-10 || or local: http://ejournal.undip.ac.id/index.php/bcrec/article/view/4] 

  17. [Migrants from disposable gloves and residual acrylonitrile].

    Wakui, C; Kawamura, Y; Maitani, T

    2001-10-01

    Disposable gloves made from polyvinyl chloride with and without di(2-ethylhexyl) phthalate (PVC-DEHP, PVC-NP), polyethylene (PE), natural rubber (NR) and nitrile-butadiene rubber (NBR) were investigated with respect to evaporation residue, migrated metals, migrants and residual acrylonitrile. The evaporation residue found in n-heptane was 870-1,300 ppm from PVC-DEHP and PVC-NP, which was due to the plasticizers. Most of the PE gloves had low evaporation residue levels and migrants, except for the glove designated as antibacterial, which released copper and zinc into 4% acetic acid. For the NR and NBR gloves, the evaporation residue found in 4% acetic acid was 29-180 ppm. They also released over 10 ppm of calcium and 6 ppm of zinc into 4% acetic acid, and 1.68-8.37 ppm of zinc di-ethyldithiocarbamate and zinc di-n-butyldithiocarbamate used as vulcanization accelerators into n-heptane. The acrylonitrile content was 0.40-0.94 ppm in NBR gloves. PMID:11775358

  18. Hearing Aid

    ... and Food and Drug Administration Staff FDA permits marketing of new laser-based hearing aid with potential ... feeds Follow FDA on Twitter Follow FDA on Facebook View FDA videos on YouTube View FDA photos ...

  19. Gas-phase photocatalytic oxidation of acrylonitrile.

    Krichevskaya, Marina; Jõks, Svetlana; Kachina, Anna; Preis, Sergei

    2009-05-01

    Photocatalytic oxidation (PCO) of acrylonitrile (AN) on titanium dioxide in the gaseous phase was studied. AN readily undergoes photocatalytic degradation in a gas-solid system by using TiO(2) Degussa P25. The AN PCO volatile products, visible in the infrared spectra, included nitrogen dioxide, nitrous oxide, carbon dioxide, water, hydrogen cyanide and carbon monoxide. Longer contact time resulted in deeper oxidation of AN with decreasing hydrogen cyanide and increasing nitrogen dioxide content. The effect of temperature increasing from 60 to 130 degrees C was observed to be slightly negative in terms of AN degradation rate. However, the effect of increased temperature was noticeable in terms of the character and yields of the PCO products: HCN peaks diminished with growing peaks of NO(2). PMID:19424531

  20. Acrylonitrile characterization and high energetic photochemistry at Titan temperatures

    Toumi, A.; Piétri, N.; Chiavassa, T.; Couturier-Tamburelli, I.

    2016-05-01

    Laboratory infrared spectra of amorphous and crystalline acrylonitrile (C2H3CN) ices were recorded between 4000 and 650 cm-1. Heating up the acrylonitrile sample to 160 K shows details on the transition between amorphous and crystalline ice at ∼94 K. This molecule can be used as an indicator of the surface temperature of Titan since it is known also to be ∼94 K. The desorption energy of acrylonitrile was determined using two methods (IRTF and mass spectrometries) to be around 35 kJ mol-1. Solid phase acrylonitrile was irradiated with vacuum ultraviolet (VUV) light at low temperatures (20, 70, 95 and 130 K) using a microwave-discharge hydrogen flow lamp. Isoacrylonitrile, cyanoacetylene (HC3N), isocyanoacetylene (HC2NC), acetylene (C2H2) and hydrogen cyanide (HCN) were identified as photoproducts by using FTIR spectroscopy. The branching ratio of each pathway has been calculated for the different temperatures. We have estimated the acrylonitrile, HCN and HC3N νCtbnd N stretching band strengths to be respectively A = 3.98 ×10-18 , A = 1.38 ×10-18 and A = 2.92 ×10-18cmmolecule-1 .

  1. Radiation grafting of styrene and acrylonitrile to cellulose and polyethylene

    Hassanpour, S.

    1999-06-01

    Radiation induced graft polymerization is one of the best methods for obtaining material with new properties. In this work, radiation grafting of styrene, mixture of styrene and acrylonitrile to cellulose and polyethylene in the presence of methanol as a solvent by mutual method is discussed. At a low dose rate, high grafting yields were obtained from the two systems used, due to lesser termination of free radicals with the polymer growing radicals and recombination of primary radicals, resulting in a longer chain length of the grafted copolymer. In the system of styrene and acrylonitrile, comonomer technique was used and the styrene controlled the homopolymer formation during graft polymerization. Water uptake of cellulose decreased by increasing the grafting yields. Grafted cellulose can be molded to some extent and in a high percent of grafting, a new transparent material was obtained. By radiation grafting of styrene-acrylonitrile to low density polyethylene a high degree of crosslinking was observed.

  2. Modification of PVC compounds with butadiene-acrylonitrile elastomers

    J. Stabik

    2006-04-01

    Full Text Available Purpose: The purpose of the paper is to present the research programme on influence of acrylonitrile-butadiene copolymers on properties of plasticized polyvinylchloride as window gaskets material.Design/methodology/approach: Short literature review concerning application of modified PVC as gasket material was presented. In experimental part two types of acrylonitrile-butadiene copolymers were used as elastomeric plasticizers. Compounds with fifteen different levels of modifiers content (up to 25% by weight were prepared and tested. Additionally three commercial compounds were tested as reference formulations. The following test were performed: Shore hardness, short-term and long-term elastic recovery, tensile strength, elongation at break and migration of plasticizers from gasket material to unplasticized PVC.Findings: Application of acrylonitrile-butadiene copolymers as PVC modifier enhanced many properties essential for window gasket materials such as long-term and short term elastic recovery, tensile strength and elongation at break. At the same time addition of these elastomers did not change migration of other plasticizers contained in gasket material. Obtained results indicated that among tested compounds best properties as gasket material exhibited plasticized PVC with 23% of acrylonitrile-butadiene copolymer Chemigum P83. Reference commercial compounds exhibited worse performance properties than compounds with this acrylonitrile-butadiene copolymer. Practical implications: Research programme allowed to elaborate plasticized PVC compounds modified with acrylonitrile-butadiene copolymer that can be industrially applied for PVC window gaskets.Originality/value: Obtained results are of scientific and practical value. Research programme allowed to investigate the influence of elastomeric modifiers on plasticized PVC properties. Research results are also of practical importance.

  3. Commercial Application of the XYA-5 Catalyst in Acrylonitrile Unit

    Li Zhengguang

    2008-01-01

    The XYA-5 catalyst was first applied in commercial scale on an 80-kt/a acrylonitrile unit at the Daqing Refining and Chemical Company.Test results had shown that the once-through yield of acrylonitrile exceeded 80% with the unit consumption of propylene reaching 1032 kg on each ton of acryionitrile.The product quality could be easily put under control and the distribution of reaction products was reasonable with good cleaning performance and stability of the catalyst that was suitable for use on this commercial unit.

  4. 21 CFR 177.1050 - Acrylonitrile/styrene copoly-mer modified with butadiene/styrene elastomer.

    2010-04-01

    .... (e) Accelerated extraction end test. The modified copolymer shall yield acrylonitrile monomer not in... room temperature. A sample of the extracting solvent is then withdrawn and analyzed for acrylonitrile... Acrylonitrile Monomer in Acrylonitrile-Containing Polymers and Food Simulating Solvents,” which is...

  5. Gas permeability of polyvinyltrimethylsilane modified by irradiation-induced grafting of acrylonitrile

    Gas permeability and diffusion at 20-80 deg through homogeneous polyvinyltrimethylsilane membranes modified by acrylonitrile grafting have been studied. Coefficients of diffusion and permeability of all gases under study for the samples containing PAN are lower than for pure polymer. An increase of PAN content in membranes resuls in increasing of selectivity of permeability for He-CH4, He-N2, He-CO2, H2-CH4 gas pairs. The correlation of the coefficient of diffusion with the effective cross-section of gas molecules and of the coefficient of solubility with their strength constants of the Lennard-Jones potential is observed

  6. Investigation of the cathodic electropolymerization of acrylonitrile, ethylacrylate and methylmethacrylate by coupled quartz crystal microbalance analysis and cyclic voltammetry

    Baute, Noëlle; Martinot, Lucien; Jérôme, Robert

    1999-01-01

    The cathodic electropolymerization of acrylonitrile (AN), ethylacrylate (EA) and methylmethacrylate (MMA), has been monitored for the first time by coupled electrochemical quartz crystal microbalance (QCM) and cyclic voltammetry analyses. These data have been compared to the previously published analyses for methacrylonitrile (MAN). At the potential Ep1 of the less cathodic of the two voltammetric peaks observed (peak I), the polymer formed is anchored firmly to the cathode even in a good sol...

  7. NOISE INDUCED HEARING LOSS IN CHINA:A POTENTIALLY COSTLY PUB-LIC HEALTH LSSUE

    Shi Yongbing; William Hal Martin

    2013-01-01

    Hearing loss and tinnitus are among the most common consequences of long term noise exposure and re-main an under-addressed heath issue in most developing nations including China. The rapid industrializa-tion and life style changes in China increase the concern over noise exposure and noise induced hearing loss (NIHL). Research on NIHL in China is limited. The current paper reviews studies published in English and Chinese language literatures regarding noise exposure and NIHL in China. Their implication on the Chi-nese population is discussed. The possible utility of a research model such as the Dangerous Decibels® as a means to increase understanding of the scope of NIHL among the Chinese population, to educate the gener-al public in China (especially the young) about NIHL and its prevention, and to study effects of language and cultural factors on international information dissemination and behavioral interventions is proposed.

  8. Polyacrylamide polymers derived from acrylonitrile without intermediate isolation

    Norton, C.J.; Falk, D.O.

    1977-04-05

    Hydrolyzed and neutralized acrylonitrile is polymerized in solution without isolation to produce a high molecular weight polyacrylamide useful for mobility control in secondary recovery of petroleum. The polyacrylamide optionally may be hydrolyzed, methylolated, and sulfomethylated to further enhance its water-thickening properties. This procedure reduces the cost of making polyacrylamide. (5 claims)

  9. Detection Rates of Cortical Auditory Evoked Potentials at Different Sensation Levels in Infants with Sensory/Neural Hearing Loss and Auditory Neuropathy Spectrum Disorder.

    Gardner-Berry, Kirsty; Chang, Hsiuwen; Ching, Teresa Y C; Hou, Sanna

    2016-02-01

    With the introduction of newborn hearing screening, infants are being diagnosed with hearing loss during the first few months of life. For infants with a sensory/neural hearing loss (SNHL), the audiogram can be estimated objectively using auditory brainstem response (ABR) testing and hearing aids prescribed accordingly. However, for infants with auditory neuropathy spectrum disorder (ANSD) due to the abnormal/absent ABR waveforms, alternative measures of auditory function are needed to assess the need for amplification and evaluate whether aided benefit has been achieved. Cortical auditory evoked potentials (CAEPs) are used to assess aided benefit in infants with hearing loss; however, there is insufficient information regarding the relationship between stimulus audibility and CAEP detection rates. It is also not clear whether CAEP detection rates differ between infants with SNHL and infants with ANSD. This study involved retrospective collection of CAEP, hearing threshold, and hearing aid gain data to investigate the relationship between stimulus audibility and CAEP detection rates. The results demonstrate that increases in stimulus audibility result in an increase in detection rate. For the same range of sensation levels, there was no difference in the detection rates between infants with SNHL and ANSD. PMID:27587922

  10. Enhanced photorefractive performance in CdSe quantum-dot-dispersed poly(styrene-co-acrylonitrile) polymers

    This paper reports on the enhanced photorefractive behavior of a CdSe quantum-dot-dispersed less expensive polymer of poly(styrene-co-acrylonitrile). The capability of CdSe quantum dots used as photosensitizers and the associated photorefractive performance are characterized through a photocurrent experiment and a two-beam coupling experiment, respectively. An enhanced two-beam coupling gain coefficient of 12.2 cm-1 at 46 V/μm was observed owning to the reduced potential barrier. The photorefractive performance per CdSe quantum dot is three orders of magnitude higher than that in the sample sensitized by trinitrofluorenone in poly(styrene-co-acrylonitrile), and almost ten times higher than that in the CdSe quantum-dot-sensitized poly(N-vinylcarbazole) polymers.

  11. Exploring potentials of sense-making theory for understanding social processes in public hearing

    Lyhne, Ivar

    This paper has point of departure in a planning process on energy infrastructure in Denmark and focuses on a particular public hearing meeting characterised by trenchant opposition and distrust to the authorities among the public. It points at the need to understand the interaction between...... authorities and the public in such planning often characterised by conflict. A sense-making framework is developed based on Karl Weick's theory to investigate how participants at the meeting change their understanding aspects like other actors' opinions and the infrastructure project. Through interviews and...

  12. Potential barriers and facilitators for implementation of an integrated care pathway for hearing-impaired persons: an exploratory survey among patients and professionals

    Verschuure Hans

    2007-04-01

    Full Text Available Abstract Background Because of the increasing costs and anticipated shortage of Ear Nose and Throat (ENT specialists in the care for hearing-impaired persons, an integrated care pathway that includes direct hearing aid provision was developed. While this direct pathway is still under investigation, in a survey we examined expectations and potential barriers and facilitators towards this direct pathway, of patients and professionals involved in the pathway. Methods Two study populations were assessed: members of the health professions involved in the care pathway for hearing-impaired persons (general practitioners (GPs, hearing aid dispensers, ENT-specialists and clinical audiologists and persons with hearing complaints. We developed a comprehensive semi-structured questionnaire for the professionals, regarding expectations, barriers, facilitators and conditions for implementation. We developed two questionnaires for persons with hearing complaints, both regarding evaluations and preferences, and administered them after they had experienced two key elements of the direct pathway: the triage and the hearing aid fitting. Results On average GPs and hearing aid dispensers had positive expectations towards the direct pathway, while ENT-specialists and clinical audiologists had negative expectations. Professionals stated both barriers and facilitators towards the direct pathway. Most professionals either supported implementation of the direct pathway, provided that a number of conditions were satisfied, or did not support implementation, unless roughly the same conditions were satisfied. Professionals generally agreed on which conditions need to be satisfied. Persons with hearing complaints evaluated the present referral pathway and the new direct pathway equally. Many, especially older, participants stated however that they would still visit the GP and ENT-specialist, even when this would not be necessary for reimbursement of the hearing aid, and

  13. Sensitivity of cortical auditory evoked potential detection for hearing-impaired infants in response to short speech sounds

    Bram Van Dun

    2012-01-01

    Full Text Available

    Background: Cortical auditory evoked potentials (CAEPs are an emerging tool for hearing aid fitting evaluation in young children who cannot provide reliable behavioral feedback. It is therefore useful to determine the relationship between the sensation level of speech sounds and the detection sensitivity of CAEPs.

    Design and methods: Twenty-five sensorineurally hearing impaired infants with an age range of 8 to 30 months were tested once, 18 aided and 7 unaided. First, behavioral thresholds of speech stimuli /m/, /g/, and /t/ were determined using visual reinforcement orientation audiometry (VROA. Afterwards, the same speech stimuli were presented at 55, 65, and 75 dB SPL, and CAEP recordings were made. An automatic statistical detection paradigm was used for CAEP detection.

    Results: For sensation levels above 0, 10, and 20 dB respectively, detection sensitivities were equal to 72 ± 10, 75 ± 10, and 78 ± 12%. In 79% of the cases, automatic detection p-values became smaller when the sensation level was increased by 10 dB.

    Conclusions: The results of this study suggest that the presence or absence of CAEPs can provide some indication of the audibility of a speech sound for infants with sensorineural hearing loss. The detection of a CAEP provides confidence, to a degree commensurate with the detection probability, that the infant is detecting that sound at the level presented. When testing infants where the audibility of speech sounds has not been established behaviorally, the lack of a cortical response indicates the possibility, but by no means a certainty, that the sensation level is 10 dB or less.

  14. Negotiating hearing disability and hearing disabled identities

    Lykke Hindhede, Anette

    2012-01-01

        Using disability theory as a framework and social science theories of identity to strengthen the arguments, this paper explores empirically how working-age adults confront the medical diagnosis of hearing impairment. For most participants hearing impairment threatens the stability of social...... interaction and the construction of hearing disabled identities is seen as shaped in the interaction with the hearing impaired person‟s surroundings. In order to overcome the potential stigmatisation the „passing‟ as normal becomes predominant. For many the diagnosis provokes radical redefinitions of the self....... The discursively produced categorisation and subjectivity of senescence mean that rehabilitation technologies such as hearing aids identify a particular life-style (disabled) which determines their social significance. Thus wearing a hearing aid works against the contemporary attempt to create socially ideal...

  15. Two-dimensional spectra of electron collisions with acrylonitrile and methacrylonitrile reveal nuclear dynamics

    Regeta, K., E-mail: khrystyna.regeta@unifr.ch; Allan, M., E-mail: michael.allan@unifr.ch [Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg (Switzerland)

    2015-05-14

    Detailed experimental information on the motion of a nuclear packet on a complex (resonant) anion potential surface is obtained by measuring 2-dimensional (2D) electron energy loss spectra. The cross section is plotted as a function of incident electron energy, which determines which resonant anion state is populated, i.e., along which normal coordinate the wave packet is launched, and of the electron energy loss, which reveals into which final states each specific resonant state decays. The 2D spectra are presented for acrylonitrile and methacrylonitrile, at the incident energy range 0.095-1.0 eV, where the incoming electron is temporarily captured in the lowest π{sup ∗} orbital. The 2D spectra reveal selectivity patterns with respect to which vibrations are excited in the attachment and de-excited in the detachment. Further insight is gained by recording 1D spectra measured along horizontal, vertical, and diagonal cuts of the 2D spectrum. The methyl group in methacrylonitrile increases the resonance width 7 times. This converts the sharp resonances of acrylonitrile into boomerang structures but preserves the essence of the selectivity patterns. Selectivity of vibrational excitation by higher-lying shape resonances up to 8 eV is also reported.

  16. Two-dimensional spectra of electron collisions with acrylonitrile and methacrylonitrile reveal nuclear dynamics

    Detailed experimental information on the motion of a nuclear packet on a complex (resonant) anion potential surface is obtained by measuring 2-dimensional (2D) electron energy loss spectra. The cross section is plotted as a function of incident electron energy, which determines which resonant anion state is populated, i.e., along which normal coordinate the wave packet is launched, and of the electron energy loss, which reveals into which final states each specific resonant state decays. The 2D spectra are presented for acrylonitrile and methacrylonitrile, at the incident energy range 0.095-1.0 eV, where the incoming electron is temporarily captured in the lowest π∗ orbital. The 2D spectra reveal selectivity patterns with respect to which vibrations are excited in the attachment and de-excited in the detachment. Further insight is gained by recording 1D spectra measured along horizontal, vertical, and diagonal cuts of the 2D spectrum. The methyl group in methacrylonitrile increases the resonance width 7 times. This converts the sharp resonances of acrylonitrile into boomerang structures but preserves the essence of the selectivity patterns. Selectivity of vibrational excitation by higher-lying shape resonances up to 8 eV is also reported

  17. Comparison of Vestibular Evoked Myogenic Potential and Caloric Tests Findings in Noise Induced Hearing Loss-Affected and Healthy Individuals

    Farinoosh Fakharnia

    2010-06-01

    Full Text Available Background and Aim: Balance disturbance is one of the non-auditory effects of noisy industrial environments that is usually neglected. The aim of the current study was to investigate the effect of occupational noise on vestibular system among workers with noise-induced hearing loss (NIHL, based on both vestibular evoked myogenic potentials (VEMP and caloric tests.Methods: Thirty male workers with noise-induced hearing loss and thirty male matched controls were examined by VEMP and caloric tests. Study parameters included unilateral weakness, p13 and n23 latencies, and p13-n23 amplitude. Caloric test was performed only for 20 patients.Results: No significant difference was observed in unilateral weakness between the two groups. On the other hand, the difference in mean latencies of p13 in the right ear (p=0.003 and left ear (p=0.01 was significant between the two groups. However, the difference in n23 latency was significant only in the right ear (p=0.03. There was no significant difference between groups in p13-n23 amplitude.Conclusion: It seems that pars inferior of vestibule is the susceptible part in individuals with NIHL. In general, abnormal findings in both VEMP and caloric tests were more common compared to functional symptoms such as vertigo, which may be due to central compensation and the symmetry of the disorder.

  18. Potential hazard of hearing damage to students in undergraduate popular music courses.

    Barlow, Christopher

    2010-12-01

    In recent years, there has been a rapid growth in university courses related to popular and commercial music, with a commensurate increase in the number of students studying these courses. Students of popular music subjects are frequently involved in the use of electronically amplified sound for rehearsal and recording, in addition to the "normal" noise exposure commonly associated with young people. The combination of these two elements suggests a higher than average noise exposure hazard for these students. To date, the majority of noise studies on students have focused on exposure from personal music players and on classical, orchestral, and marching band musicians. One hundred students across a range of university popular music courses were surveyed using a 30-point questionnaire regarding their musical habits both within and external to their university courses. This was followed by noise dosimetry of studios/recording spaces and music venues popular with students. Questionnaire responses showed 76% of subjects reported having experienced symptoms associated with hearing loss, while only 18% reported using hearing protection devices. Rehearsals averaged 11.5 hrs/wk, with a mean duration 2 hrs 13 mins and mean level of 98 dB LAEQ. Ninety-four percent of subjects reported attending concerts or nightclubs at least once per week, and measured exposure in two of these venues ranged from 98 to 112 dB LAEQ with a mean of 98.9 dB LAEQ over a 4.5-hr period. Results suggested an extremely high hazard of excessive noise exposure among this group from both their social and study-based music activities. PMID:21170480

  19. Thermal Stability of Poly (acrylonitrile-methyl acrylate) Copolymers

    HAN Na; ZHANG Xing-xiang; WANG Xue-chen

    2008-01-01

    Poly (acrylonitrile-methyl acrylate) copolymer was synthesized by water depositing polymerization and has a typical feed ratio of 85/15. And then 1 - 3 wt% lauryl alcohol maleic anhydride (LAM) was adopted as stabilizer to mix with the acrylonitrile based copolymer. The mixtures were characterized by using Fourier Transform Infrared Spectroscopy (FTIR), Nuclear Magnetic Resonance (1H NMR ), Gel Permeation Chromatography ( GPC ), Differential Scanning Calorimetry (DSC), optic microscope and Ubbelohde viscosimetryr etc. The melting point (Tm) and glass transition temperature (Tg) of the 85/15 AN/MA copolymer mixed with LAM all decrease with the increase of stabilizer content. The lowest Tg and Tm were 116.1 ℃ and 209. 1℃ respectively at the heating rate of 100℃/min when the content of LAM is 2 wt%. The 85°/15 AN/MA copolymer mixed with 1 - 3 w t% LAM possess good thermal stability up to 30 min at 220 ℃.

  20. Study on irradiated polymerization of acrylonitrile by NMR

    Sup 13 C CP/MAS spectra and nuclear Overhauser effects (NOE) at room temperature have been measured for acrylonitrile (AN) in homophase irradiated polymerization. With the increase of radiation dose the chemical shift of cracking peaks and NOE are variation. This implies that the polymerized mechanism of AN were changed with the variation of irradiated doses and dose rate. There is the stronger affinity electron group (-CN) in acrylonitrile monomer. It may be polymerized by various ways and mechanism and be gained the polymer of difference structures and molecular weight of polyacrylonitrile (PAN). Starmicarbon and Starker obtained higher molecular weight of polyacrylonitrile by peroxysulfate-pyrosulfite in oxidation-reduction system. The superhigh molecular weight of PAN was synthesized chemically according to the method of Wu et. al. by suspension polymerization. In this paper we discussed that the relative concentrations of steric dyads and triads in the chain structure in PAN and the irradiation polymerized mechanism of acrylonitrile monomer in room temperature by different dose and dose rate

  1. Acoustically Induced Streaming Flows near a Model Cod Otolith and their Potential Implications for Fish Hearing

    Kotas, Charlotte W [ORNL; Rogers, Peter [Georgia Institute of Technology; Yoda, Minami [Georgia Institute of Technology

    2011-01-01

    The ears of fishes are remarkable sensors for the small acoustic disturbances associated with underwater sound. For example, each ear of the Atlantic cod (Gadus morhua) has three dense bony bodies (otoliths) surrounded by fluid and tissue, and detects sounds at frequencies from 30 to 500 Hz. Atlantic cod have also been shown to localize sounds. However, how their ears perform these functions is not fully understood. Steady streaming, or time-independent, flows near a 350% scale model Atlantic cod otolith immersed in a viscous fluid were studied to determine if these fluid flows contain acoustically relevant information that could be detected by the ear s sensory hair cells. The otolith was oscillated sinusoidally at various orientations at frequencies of 8 24 Hz, corresponding to an actual frequency range of 280 830 Hz. Phaselocked particle pathline visualizations of the resulting flows give velocity, vorticity, and rate of strain fields over a single plane of this mainly two-dimensional flow. Although the streaming flows contain acoustically relevant information, the displacements due to these flows are likely too small to explain Atlantic cod hearing abilities near threshold. The results, however, may suggest a possible mechanism for detection of ultrasound in some fish species.

  2. Hearing Aids

    ... more in both quiet and noisy situations. Hearing aids help people who have hearing loss from damage ... your doctor. There are different kinds of hearing aids. They differ by size, their placement on or ...

  3. Hearing aid adjustment

    Heinemann, Trine; Matthews, Ben; Raudaskoski, Pirkko Liisa

    2012-01-01

    to the interaction during hearing aid fitting. This report of a Danish pilot study describes two such problems. The first problem arises from the requirement that the audiologist needs to ‘translate’ the patient’s subjective hearing description for making technological decisions. The second problem...... is the way in which the hearing aid user’s implicit and often unrealistic expectations are handled. This kind of research has potential application for developing a model of best practices....

  4. 21 CFR 177.1020 - Acrylonitrile/butadiene/sty-rene co-polymer.

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Acrylonitrile/butadiene/sty-rene co-polymer. 177... SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: POLYMERS Substances.../butadiene/sty-rene co-polymer. Acrylonitrile/butadiene/styrene copolymer identified in this section may...

  5. Intensity-Modulated vs. Conformal Radiotherapy of Parotid Gland Tumors: Potential Impact on Hearing Loss

    In 3-dimensional (3D) conformal radiotherapy of parotid gland tumors, little effort is made to avoid the auditory system or the oral cavity. Damage may occur when the ear is located inside the treatment field. The purpose of this study was to design and evaluate an intensity-modulation radiotherapy (IMRT) class solution, and to compare this technique to a 3D conformal approach with respect to hearing loss. Twenty patients with parotid gland cancer were retrospectively planned with 2 different techniques using the original planning target volume (PTV). First, a conventional technique using a wedged beam pair was applied, yielding a dose distribution conformal to the shape of the PTV. Next, an IMRT technique using a fluence map optimization with predefined constraints was designed. A dose of 66 Gy in the PTV was given at the International Commission on Radiation Units and Measures (ICRU) dose prescription point. Dose-volume histograms of the PTV and organs at risk (OARs), such as auditory system, oral cavity, and spinal cord, were compared. The dose in the OARs was lower in the IMRT plans. The mean volume of the middle ear receiving a dose higher than 50 Gy decreased from 66.5% to 33.4%. The mean dose in the oral cavity decreased from 19.4 Gy to 16.6 Gy. The auditory system can be spared if the distance between the inner ear and the PTV is 0.6 cm or larger, and if the overlap between the middle ear and the PTV is smaller than 10%. The maximum dose in the spinal cord was below 40 Gy in all treatment plans. The mean volume of the PTV receiving less than 95% of the prescribed dose increased in the IMRT plan slightly from 3.3% to 4.3 % (p = 0.01). The mean volume receiving more than 107% increased from 0.9% to 2.5% (p = 0.02). It can be concluded that the auditory system, as well as the oral cavity, can be spared with IMRT, but at the cost of a slightly larger dose inhomogeneity in the PTV. The IMRT technique can therefore, in most cases, be recommended as the treatment

  6. Imaging Evaluation of Pediatric Sensorineural Hearing Loss in Potential Candidates for Cochlear Implantation.

    Jallu, Aleena Shafi; Jehangir, Majid; Ul Hamid, Waqar; Pampori, Rafiq Ahmad

    2015-12-01

    Computerized tomography (CT) and magnetic resonance (MR) are complementary in the imaging of the labyrinth, the internal auditory canal and the brain in children with sensorineural hearing loss who are being evaluated for cochlear implantation. An accurate anatomical description of the inner ear is essential in the preoperative work up. Computerized tomography visualizes the bony structures, whereas MR can discern soft-tissue components including intra labyrinthine fluid, cerebrospinal fluid (CSF), nerves, and vessels within the IAC. This prospective study was conducted in the Department of Otorhinolaryngology, Head & Neck Surgery, Government Medical College, Srinagar. 40 children in the age group of 1-16 years with unidentified causes of bilateral SNHL were analysed radiologically over the period of 2 years from Dec 2011 to Jan 2014. Each patient underwent MRI and high resolution CT scanning of temporal bone in axial and coronal planes. Out of the 40 patients 22 were males (55 %) and 18 were females (45 %). 30 patients (72.5 %)in our study had normal radiological scans. Five patients (12.5 %) had B/L large vestibular aqueduct and two patients (5 %) had internal auditory canal stenosis with cochlear nerve hypoplasia on CT and MR imaging. Cochlear dysplasia was present in two patients (5 %) and semicircular canal dysplasia was present in one patient (2.5 %) as an isolated finding on HRCT. In addition isolated cochlear nerve hypoplasia was present in one patient (2.5 %). Hyperintense basal ganglia lesion suggestive of kernicterus was present in one patient (2.5 %) and hyperintense posterior parietal and occipital white matter lesions suggestive of congenital CMV infection was present in one patient (2.5 %) on MR imaging. Arachnoid cysts of middle cranial fossa was an incidental finding present in one patient. Radiological abnormalities of the inner ear are not uncommon. Computerized tomography and MRI are important modalities to analyze the inner ear in

  7. Kinetic and equilibrium studies of acrylonitrile binding to cytochrome c peroxidase and oxidation of acrylonitrile by cytochrome c peroxidase compound I

    Chinchilla, Diana, E-mail: Diana_Chinchilla@yahoo.com; Kilheeney, Heather, E-mail: raindropszoo@yahoo.com; Vitello, Lidia B., E-mail: lvitello@niu.edu; Erman, James E., E-mail: jerman@niu.edu

    2014-01-03

    Highlights: •Cytochrome c peroxidase (CcP) binds acrylonitrile in a pH-independent fashion. •The spectrum of the CcP/acrylonitrile complex is that of a 6c–ls ferric heme. •The acrylonitrile/CcP complex has a K{sub D} value of 1.1 ± 0.2 M. •CcP compound I oxidizes acrylonitrile with a maximum turnover rate of 0.61 min{sup −1}. -- Abstract: Ferric heme proteins bind weakly basic ligands and the binding affinity is often pH dependent due to protonation of the ligand as well as the protein. In an effort to find a small, neutral ligand without significant acid/base properties to probe ligand binding reactions in ferric heme proteins we were led to consider the organonitriles. Although organonitriles are known to bind to transition metals, we have been unable to find any prior studies of nitrile binding to heme proteins. In this communication we report on the equilibrium and kinetic properties of acrylonitrile binding to cytochrome c peroxidase (CcP) as well as the oxidation of acrylonitrile by CcP compound I. Acrylonitrile binding to CcP is independent of pH between pH 4 and 8. The association and dissociation rate constants are 0.32 ± 0.16 M{sup −1} s{sup −1} and 0.34 ± 0.15 s{sup −1}, respectively, and the independently measured equilibrium dissociation constant for the complex is 1.1 ± 0.2 M. We have demonstrated for the first time that acrylonitrile can bind to a ferric heme protein. The binding mechanism appears to be a simple, one-step association of the ligand with the heme iron. We have also demonstrated that CcP can catalyze the oxidation of acrylonitrile, most likely to 2-cyanoethylene oxide in a “peroxygenase”-type reaction, with rates that are similar to rat liver microsomal cytochrome P450-catalyzed oxidation of acrylonitrile in the monooxygenase reaction. CcP compound I oxidizes acrylonitrile with a maximum turnover number of 0.61 min{sup −1} at pH 6.0.

  8. Hearing Impairment

    ... hearing loss is present at birth. Acquired hearing loss happens later in life — during childhood, the teen years, or in adulthood — ... for your ears to avoid a permanent hearing loss. See your doctor right away ... basis. What's Life Like for People Who Are Hearing Impaired? For ...

  9. Equivalent lifetime prediction of acrylonitrile butadiene rubber for thermal aging

    Thermal degradation of acrylonitrile butadiene rubber(NBR), which is used for O-ring material as elastomeric sealed diaphragm valve in the nuclear power plants, is examined. The thermal degradation is accelerated at 130 .deg. C by arrhenius exploit method using the activation energy calculated by thermogravimetric analysis. The weight loss temperature and glass transition temperature are verified for thermally aged NBR. The relationship between dynamic mechanical properties and elongation at break are also investigated. The threshold valued of thermally aged NBR is a ten year in the change of elongation at break

  10. Preparation and Characterization of Acrylonitrile Copolymers by Emulsion Technique

    Acrylonitrile (AN) binary copolymers with styrene (St) and maleic acid (MA) of different compositions were prepared by free radical emulsion copolymerization using potassium persulfate and sodium bisulfite as a redox pair initiation system and sodium dodecyl benzene sulfonate as an emulsifier. Based on the copolymerization data of the (AN/St) and (AN/MA) in emulsion polymerization process, the reactivity ratios of the prepared copolymers were investigated by different methods. Thermogravimetric analysis and X-ray diffraction were studied to characterize the prepared copolymers. Physicomechanical properties of some copolymeric lattices films were also identified

  11. Evoked potential measurement of the masked hearing threshold of a Pacific white-sided dolphin (Lagenorhynchus obliquidens)

    Au, Whitlow W. L.; Jeanette, Thomas; Western, A.; Rameriz, Kenneth M.

    2003-04-01

    The masked hearing threshold of a Pacific white-sided dolphin (Lagenorhynchus obliquidens) was determined by measuring the animal's auditory brainstem response (ABR). The dolphin was trained to wear surface-contact electrodes embedded in suction cups and to swim into a hoop centered at 1 m below the water surface facing a sound projector 5 m away. Broadband transient signals with center frequencies of 8, 16, 32, 64, 80, and 100 kHz were used as the stimuli. ABR signals were measured by digitizing the electrode signals in 32 point blocks at a sampling rate of 20 kHz. Five hundred blocks were averaged in order to obtain an ABR. The response latency for suprathreshold threshold signals was approximately 1.9 ms with the highest peak-to-peak ABR amplitude of approximately 2.8 uV occurring for a signal frequency of 64 kHz. The spectrum of the ABR signal was similar to that of Tursiops truncatus, with a major peak at 1120 Hz and a secondary peak at 664 Hz. Threshold was determined by progressively reducing the amplitude of the stimulus until an evoked potential could not be detected. The energy signal-to-noise ratio within an integration window at threshold varied between 1 and 8 dB.

  12. NOX3 NADPH oxidase couples transient receptor potential vanilloid 1 to signal transducer and activator of transcription 1-mediated inflammation and hearing loss.

    Mukherjea, Debashree; Jajoo, Sarvesh; Sheehan, Kelly; Kaur, Tejbeer; Sheth, Sandeep; Bunch, Jennifer; Perro, Christopher; Rybak, Leonard P; Ramkumar, Vickram

    2011-03-15

    Transient receptor potential vanilloid 1 (TRPV1) is implicated in cisplatin ototoxicity. Activation of this channel by cisplatin increases reactive oxygen species generation, which contribute to loss of outer hair cells in the cochlea. Knockdown of TRPV1 by short interfering RNA protected against cisplatin ototoxicity. In this study, we examined the mechanism underlying TRPV1-mediated ototoxicity using cultured organ of Corti transformed cells (UB/OC-1) and rats. Trans-tympanic injections of capsaicin produced transient hearing loss within 24 h, which recovered by 72 h. In UB/OC-1 cells, capsaicin increased NOX3 NADPH oxidase activity and activation of signal transducer and activator of transcription 1 (STAT1). Intratympanic administration of capsaicin transiently increased STAT1 activity and expression of downstream proinflammatory molecules. Capsaicin produced a transient increase in CD14-positive inflammatory cells into the cochlea, which mimicked the temporal course of STAT1 activation but did not alter the expression of apoptotic genes or damage to outer hair cells. In addition, trans-tympanic administration of STAT1 short interfering RNA protected against capsaicin-induced hearing loss. These data suggest that activation of TRPV1 mediates temporary hearing loss by initiating an inflammatory process in the cochlea via activation of NOX3 and STAT1. Thus, these proteins represent reasonable targets for ameliorating hearing loss. PMID:20712533

  13. Seeing sounds and hearing colors: an event-related potential study of auditory-visual synesthesia.

    Goller, Aviva I; Otten, Leun J; Ward, Jamie

    2009-10-01

    In auditory-visual synesthesia, sounds automatically elicit conscious and reliable visual experiences. It is presently unknown whether this reflects early or late processes in the brain. It is also unknown whether adult audiovisual synesthesia resembles auditory-induced visual illusions that can sometimes occur in the general population or whether it resembles the electrophysiological deflection over occipital sites that has been noted in infancy and has been likened to synesthesia. Electrical brain activity was recorded from adult synesthetes and control participants who were played brief tones and required to monitor for an infrequent auditory target. The synesthetes were instructed to attend either to the auditory or to the visual (i.e., synesthetic) dimension of the tone, whereas the controls attended to the auditory dimension alone. There were clear differences between synesthetes and controls that emerged early (100 msec after tone onset). These differences tended to lie in deflections of the auditory-evoked potential (e.g., the auditory N1, P2, and N2) rather than the presence of an additional posterior deflection. The differences occurred irrespective of what the synesthetes attended to (although attention had a late effect). The results suggest that differences between synesthetes and others occur early in time, and that synesthesia is qualitatively different from similar effects found in infants and certain auditory-induced visual illusions in adults. In addition, we report two novel cases of synesthesia in which colors elicit sounds, and vice versa. PMID:18823243

  14. Hearing loss and potential hazards of metallic middle-ear implants in NMR-magnetic fields

    Concurrent with the expanding clinical applications of nuclear magnetic resonance (NMR) imaging, patients with metallic middle-ear implants will certainly be exposed to this strong magnetic field in the future. To determine potential hazards, associated with movements of steel- or Platinium stapes-prostheses, several tests were performed in a 0.5 tesla NMR unit and the induced forces were calculated. Although the commonly used paramagnetic steel-wire or platinium-alloys will not dislodge in vivo, ferromagnetic prostheses may present a hazardous risk. Prior to exposure to the magnetic field, information about the implanted material should therefore be obtained. A side-effect of the induced current flow is the attenuation of the sound-vibrations of the stapes prosthesis. This, 5-10 dB impairment of transmission develops only at a certain position of the patient's head, when the prosthesis vibrates perpendicularly to the magnetic field's Z-axis. Patients with a metallic prosthesis should be informed about this purely physical, harmless phenomenon prior to entering the NMR-cylinder. (orig.)

  15. Inflammatory and immune responses in the cochlea: potential therapeutic targets for sensorineural hearing loss

    Masato eFujioka

    2014-12-01

    Full Text Available The inner ear was previously assumed to be an immune-privileged organ due to the existence of its tight junction-based blood-labyrinth barrier. However, studies performed during the past decade revealed that the mesenchymal region of the cochlea, including its lateral wall, is a common site of inflammation. Neutrophils do not enter this region, which is consistent with the old dogma; however, bone marrow-derived resident macrophages are always present in the spiral ligament of the lateral wall and are activated in response to various types of insults, including noise exposure, ischemia, mitochondrial damage and surgical stress. Recent studies have also revealed another type of immune cell, called perivascular melanocyte-like macrophages (PVM/Ms, in the stria vascularis. These dedicated antigen-presenting cells also control vascular contraction and permeability. This review discusses a series of reports regarding inflammatory/immune cells in the cochlear lateral wall, the pathways involved in cochlear damage and their potential as therapeutic targets.

  16. Hearing Aids

    ... electrical nerve impulses and send them to the auditory nerve, which connects the inner ear to the ... prefer. Cleaning makes a difference in hearing aid comfort. A perfectly comfortable hearing aid can become pretty ...

  17. Molecular biology of hearing [

    Diensthuber, Marc

    2012-04-01

    Full Text Available [english] The inner ear is our most sensitive sensory organ and can be subdivided into three functional units: organ of Corti, stria vascularis and spiral ganglion. The appropriate stimulus for the organ of hearing is sound, which travels through the external auditory canal to the middle ear where it is transmitted to the inner ear. The inner ear houses the hair cells, the sensory cells of hearing. The inner hair cells are capable of mechanotransduction, the transformation of mechanical force into an electrical signal, which is the basic principle of hearing. The stria vascularis generates the endocochlear potential and maintains the ionic homeostasis of the endolymph. The dendrites of the spiral ganglion form synaptic contacts with the hair cells. The spiral ganglion is composed of neurons that transmit the electrical signals from the cochlea to the central nervous system. In recent years there has been significant progress in research on the molecular basis of hearing. An increasing number of genes and proteins related to hearing are being identified and characterized. The growing knowledge of these genes contributes not only to greater appreciation of the mechanism of hearing but also to a deeper understanding of the molecular basis of hereditary hearing loss. This basic research is a prerequisite for the development of molecular diagnostics and novel therapies for hearing loss.

  18. Development of cartilage conduction hearing aid

    Hosoi, H; S. Yanai; Nishimura, T; Sakaguchi, T.; T. Iwakura; Yoshino, K.

    2010-01-01

    Purpose: The potential demand for hearing aids is increasing in accordance with aging of populations in many developed countries. Because certain patients cannot use air conduction hearing aids, they usually use bone conduction hearing aids. However, bone does not transmit sound as efficiently as air, and bone conduction hearing aids require surgery (bone anchored hearing aid) or great pressure to the skull. The first purpose of this study is to examine the efficacy of a new sound conduction ...

  19. Structure and activity of tellurium-cerium oxide acrylonitrile catalysts

    Ammoxidation of propylene to acrylonitrile (ACN) was investigated over various silica-supported (Te,Ce)O catalysts at 360 and 4400C. The binary oxide system used consists of a single nonstoichiometric fluorite-type phase α-(Ce,Te)O2 up to about 80 mole% TeO2 and a tellurium-saturated solid solution β-(Ce,Te)O2 at higher tellurium concentrations. The ACN yield varies almost linearly with the tellurium content of (Ce,Te)O2. The β-(Ce,Te)O2 phase is the most active component of the system (propylene conversion and ACN selectivity at 440 C of 76.7 and 74%, respectively) and is slightly more selective to ACN than α-Te02. Tellurium reduces the overoxidation properties of cerium and selective oxidation occurs through Te(IV)-bonded oxygen

  20. BARRIER PROPERTY AND STRUCTURE OF ACRYLONITRILE/ACRYLIC COPOLYMERS

    YANG Zhenghua; LI Yuesheng

    1997-01-01

    A series of acrylonitrile (AN) copolymers with methyl acrylate (MA) or ethyl acrylate (EA) as comonomer (5-23 wt%) was prepared by free-radical copolymerization. The permeability coefficients of the copolymers to oxygen and carbon dioxide were measured at 1.0 MPa and at 30 ℃, and those to water vapor also measured at 100% relative humidity and at 30 ℃. All the AN/acrylic copolymers are semicrystalline. As the acrylate content increase, the permeability coefficients of the copolymers to oxygen and carbon dioxide are increased progressively, but those to water vapor are decreased progressively. The gas permeability coefficients of the polymers were correlated with free-volume fractions or the ratio of free volume to cohesive energy.

  1. Grafting of acrylonitrile onto cellulosic material derived from bamboo (Dendrocalamus strictus

    2008-01-01

    Full Text Available Bamboo, a lignocellulosic biopolymer material, is of interest as feedstock for production of cellulose derivatives by chemical functionalization. Optimization of grafting of acrylonitrile onto cellulosic material (average Degree of Polymerization 816, isolated from bamboo (Dendrocalamus stictus was performed by varying the process parameters such as duration of soaking of cellulosic material in ceric ammonium nitrate solution, ceric ammonium nitrate concentration, polymerization time, temperature of reaction and acrylonitrile concentration to study their influence on percent grafting and grafting efficiency. Graft copolymerization of acrylonitrile onto cellulosic material derived from bamboo (Dendrocalamus strictus in heterogenous medium can be initiated effectively with ceric ammonium nitrate. The optimum reaction conditions obtained for grafting of acrylonitrile onto cellulosic material were: duration of dipping cellulosic material in ceric ammonium nitrate solution 1 hr, ceric ammonium nitrate concentration 0.02 M, acrylonitrile concentration 24.6 mol/anhydroglucose unit, temperature of reaction 40°C and polymerization time 4 hrs. The percent grafting for optimized samples is 210.3% and grafting efficiency is 97%. The characterization of the grafted products by means of FTIR and Scanning Electron Microscopy furnished the evidence of grafting of acrylonitrile onto the cellulosic material.

  2. Types of Hearing Aids

    ... Devices Consumer Products Hearing Aids Types of Hearing Aids Share Tweet Linkedin Pin it More sharing options ... some features for hearing aids? What are hearing aids? Hearing aids are sound-amplifying devices designed to ...

  3. Hearing Assistive Technology

    ... for the Public / Hearing and Balance Hearing Assistive Technology Hearing Assistive Technology: FM Systems | Infrared Systems | Induction ... Assistive Technology Systems Solutions What are hearing assistive technology systems (HATS)? Hearing assistive technology systems (HATS) are ...

  4. Recycling of Chrome Tanned Leather Dust in Acrylonitrile Butadiene Rubber

    El-Sabbagh, Salwa H.; Mohamed, Ola A.

    2010-06-01

    Concerns on environmental waste problem caused by chrome tanned leather wastes in huge amount have caused an increasing interest in developing this wastes in many composite formation. This leather dust was used as filler in acrylonitrile butadiene rubber (NBR) before treatment and after treatment with ammonia solution and sod. formate. Different formulations of NBR/ leather dust (untreated-treated with ammonia solution—treated with sod. formate) composites are prepared. The formed composite exhibit a considerable improvement in some of their properties such as rheometric characteristics especially with composites loaded with treated leather dust. Tensile strength, modulus at 100% elongation, hardness and youngs modulus were improved then by further loading start to be steady or decrease. Cross linking density in toluene were increased by incorporation of leather dust treated or untreated resulting in decreases in equilibrium swelling. Distinct increase in the ageing coefficient of both treated and untreated leather with drop in NBR vulcanizates without leather dust. Addition of leather dust treated or untreated exhibit better thermal stability.

  5. The Formation and characteristics of Acrylonitrile/Urea Inclusion Compound

    Zou, Jun-Ting; Pang, Wen-Min; Shi, Lei; Lu, Fei

    2012-01-01

    The formation process and composition of the acrylonitrile/urea inclusion compounds (AN/UIC) with different aging times and AN/urea molar feed ratios are studied by differential scanning calorimetry (DSC) and X-ray diffraction (XRD). It is suggested that DSC could be one of the helpful methods to determine the guest/host ratio and the heat of decomposition. Meanwhile, the guest/host ratio and heat of deformation are obtained, which are 1.17 and 5361.53 J/mol, respectively. It is found that the formation of AN/UIC depends on the aging time. The formation process ends after enough aging time and the composition of AN/UIC becomes stable. It is suggested AN molecules included in urea canal lattice may be packed flat against each other. XRD results reveal that once AN molecules enter urea lattice, AN/UIC are formed, which possess the final structure. When AN molecules are sufficient, the content of AN/UIC increased as aging time prolonging until urea tunnels are saturated by AN.

  6. Hearing Aids

    ... prefer the open-fit hearing aid because their perception of their voice does not sound “plugged up.” ... My voice sounds too loud. The “plugged-up” sensation that causes a hearing aid user’s voice to ...

  7. An experimental Raman and theoretical DFT study on the self-association of acrylonitrile.

    Alía, Jose M; Edwards, Howell G M; Fawcett, W Ronald; Smagala, Thomas G

    2007-02-01

    The liquid structure of acrylonitrile (propenenitrile) has been investigated using Raman spectroscopy and density functional theory (DFT) ab initio calculations with the 6-311++G** basis set. Two different and complementary experimental approaches were undertaken: FT-Raman spectra of 13 acrylonitrile solutions in carbon tetrachloride (concentration range=0.25-12.0 mol.L-1) were studied in detail including principal component analysis (PCA) of the CN stretching band. Furthermore, dispersive Raman spectra of neat acrylonitrile were obtained at eight different temperatures from 238 up to 343 K. The complex and asymmetric acrylonitrile Raman CN stretching band can be decomposed into two components attributed to monomeric and self-associated forms. Ab initio results fully support this assignment and suggest that the self-associated complex is a nonplanar trimer held together by dipole-dipole interactions. At ambient temperature, the composition of acrylonitrile can be expressed as a mixture of 25% monomers and 75% trimers. Close to the boiling point, trimers still represent 65% of the liquid composition. The corresponding enthalpy of association was estimated to be -22+/-2 kJ.mol-1. PMID:17266219

  8. Self-Fitting Hearing Aids

    Keidser, Gitte; Convery, Elizabeth

    2016-01-01

    A self-contained, self-fitting hearing aid (SFHA) is a device that enables the user to perform both threshold measurements leading to a prescribed hearing aid setting and fine-tuning, without the need for audiological support or access to other equipment. The SFHA has been proposed as a potential solution to address unmet hearing health care in developing countries and remote locations in the developed world and is considered a means to lower cost and increase uptake of hearing aids in develo...

  9. [Progressive hearing loss].

    Reiss, M; Reiss, G

    2000-01-01

    Progressive sensorineural hearing loss (SNHL) is defined as hearing loss of unknown etiology with fairly high-speed progression. Its diagnostic criteria consist of the following: that it is 1) progressive, 2) with bilateral involvement, and 3) of unknown etiology. Due to recent advances in diagnostics, imaging and management, SNHL has gained much interest from otologists in the last few years. They provide new insight into the physiology and pathophysiology of hearing. SNHL which is sudden in onset, fluctuating, and/or progressive complicates medical management, hearing aid selection, and individualized educational planning for a hearing-impaired patient. Existing hypotheses on the etiology of SNHL are judged on experimental, clinical, laboratory and radiological evidence. Cardiovascular and rheologic diseases, hereditary disorders, immunological phenomena, infections, environmental causes like noise, ototoxic drugs and industrial substances and systemic maladies must be included in the diagnostic reflections. Potential concepts of treatment include rheologic medications and corticosteroids. Hearing aids and timely cochlear implant operation are further possible forms of treatment. PMID:10893764

  10. Chrome-tanned leather shavings as a filler of butadiene-acrylonitrile rubber.

    Przepiórkowska, A; Chrońska, K; Zaborski, M

    2007-03-01

    The noxious wastes from the tanning industry such as chrome-tanned leather shavings were used as the only filler of rubber mixes containing carboxylated butadiene-acrylonitrile rubber (XNBR) or butadiene-acrylonitrile rubber (NBR), and a dispersing agent Limanol PEV (Schill & Seilacher). The best form addition of leather powder to the rubber mixes is mixed the waste protein with zinc oxide. The leather powder added to the rubber mixes improves the mechanical properties: tensile strength (T(s)), elongation at break (epsilon(b)) and increase the cross-linking density of carboxylated XNBR and NBR rubber mixes. Satisfactory results of these studies are presented in this work. PMID:16942836

  11. Hearing Loss

    ... the choices that can help people with hearing problems. home | health topics A-Z | videos A-Z | training | about us | contact us | site map National Institute on Aging | U.S. National Library of Medicine | National Institutes of ...

  12. New Star-Branched Poly(acrylonitrile) Architectures : ATRP Synthesis and Solution Properties

    Pitto, Valentina; Voit, Brigitte I.; Loontjens, Ton J.A.; Benthem, Rolf A.T.M. van

    2004-01-01

    Atom transfer radical polymerization (ATRP) has been chosen as ‘‘living’’/controlled free radical polymerization system to synthesize a number of novel poly(acrylonitrile) (PAN) architectures. The reaction conditions for the synthesis of linear samples with control over molar mass and molar mass dis

  13. ABSORPTION OF CO2 AND SUBSEQUENT VISCOSITY REDUCTION OF AN ACRYLONITRILE COPOLYMER. (R829555)

    Acrylonitrile (AN) copolymers (AN content greater than about 85 mol%) are traditionally solution processed to avoid a cyclization and crosslinking reaction that takes place at temperatures where melt processing would be feasible. It is well known that carbon dioxide (CO

  14. New grafted copolymer of polystyrene with acrylonitrile using gamma-irradiation

    Commercial polystyrene aggregates were purified and grafted with acrylonitrile using gamma-irradiation. New copolymer was obtained, characterized and its properties were investigated. The results indicated that the best grafting percentage ratio could be obtained when the concentration of the ferrous ammonium sulphate (FAS) is about 0.25% and the monomer concentration is 80% at 1.5 Mrad dos

  15. Development of a conductimetric biosensor using immobilised Rhodococcus ruber whole cells for the detection and quantification of acrylonitrile.

    Roach, P C J; Ramsden, D K; Hughes, J; Williams, P

    2003-10-30

    A conductimetric biosensor for the detection of acrylonitrile in solution was designed and characterised using whole cells of Rhodococcus ruber NCIMB 40757, which were immobilised into a disc of dimethyl silicone sponge (ImmobaSil). The biosensor described was capable of the detection and quantification of acrylonitrile in aqueous solution, having a linear response to concentrations between 2 and 50 mM (106-2650 ppm) acrylonitrile. The biosensor has been shown to be reproducible with respect to the data obtained over a number of days, and retains stability for a minimum period of at least 5 days before recalibration of the biosensor is required. PMID:14559001

  16. Heck Arylation of Acrylonitrile with Aryl Iodides Catalyzed by a Silica-bound Arsine Palladium(0) Complex

    Ming Zhong CAI; Hong ZHAO; Rong Li ZHANG

    2005-01-01

    Acrylonitrile reacts with aryl iodides in the presence of tri-n-butylamine and a catalytic amount of a silica-bound arsine palladium(0) complex to afford stereoselectively (E)-cinnamonitriles in high yields.

  17. Non-organic hearing loss.

    Nelson, Sarah C

    2012-12-01

    Annual hearing tests are compulsory in the British Armed Forces. This case report presents a 24-year old soldier who was found to have severe deterioration on her annual audiogram without any significant noise exposure. After two years of specialist audiological investigations she was diagnosed with non-organic hearing loss; further interrogation of her social circumstances suggested potential psychosocial triggers. This diagnosis should be considered early in military primary care in those with objective hearing loss on audiogram where there has been no exposure to significant noise. PMID:23402072

  18. Noise sensitivity and hearing disability

    Marja Heinonen-Guzejev; Tapani Jauhiainen; Heikki Vuorinen; Anne Viljanen; Taina Rantanen; Markku Koskenvuo; Kauko Heikkilä; Helena Mussalo-Rauhamaa; Jaakko Kaprio

    2011-01-01

    The aim of this study was to investigate the association of noise sensitivity with self-reported hearing disability and hearing levels, with consideration of the role of self-reported history of noise exposure and use of hearing protectors. The study is based on the Finnish Twin Cohort. In 1988, a noise questionnaire was sent to 1005 twin pairs, 1495 individuals (688 men, 807 women) replied. The age range was 31-88 years. Information on some potential confounders was obtained from the questio...

  19. Dimedone-catalyzed Addition of Amines into Cyano Group: Facile Synthesis of Thiazol-2-yl Substituted E-Acrylonitriles

    朱伟军; 屠兴超; 冯惠; 屠蔓苏; 姜波; 吴飞跃; 屠树江

    2012-01-01

    An efficient dimedone-catalyzed synthesis of highly functionalized thiazol-2-yl substituted E-acrylonitrile derivatives has been established through two-step reaction of a-thiocyanate ketones with malononitrile and amines. The a-thiocyanate ketones were subjected with malononitrile to provide thiazol-2-ylidenemalononitrile derivatives, followed with various amines in the presence of dimedone to yield the final thiazol-2-yl substituted acrylonitrile derivatives.

  20. Free Eenergy as a Dynamical and Geometric Invariant (or Can You Hear the Shape of a Potential?)

    Pollicott, M

    2003-01-01

    The lattice gas provides an important and illuminating family of models in statistical physics. An interaction $\\Phi$ on a lattice $L \\subset \\Bbb Z^d$ determines an idealized lattice gas system with potential $A_\\Phi$. The pressure $P(A_\\Phi)$ and free energy $F_{A_\\Phi}(\\beta)= -(1/\\beta) P(\\beta A_\\Phi)$ are fundamental characteristics of the system. However, even for the simplest lattice systems, the information about the potential that the free energy captures is subtle and poorly understood. We study whether, or to what extent, potentials for certain model systems are determined by their free energy. In particular, we show that for a one-dimensional lattice gas, the free energy of finite range interactions typically determines the potential, up to natural equivalence, and there is always at most a finite ambiguity; we exhibit exceptional potentials where uniqueness fails; and we establish deformation rigidity for the free energy. The proofs use a combination of thermodynamic formalism, algebraic geometr...

  1. Vestibular Evoked Myogenic Potential Produced by Bone-Conducted Stimuli: A Study on its Basics and Clinical Applications in Patients With Conductive and Sensorineural Hearing Loss and a Group With Vestibular Schawannoma

    Parvane Mahdi

    2013-06-01

    Full Text Available Introduction: Vestibular evoked myogenic potential (VEMP has recently been broadly studied in vestibular disorders. As it is evoked by loud sound stimulation, even mild conductive hearing loss may affect VEMP results. Bone-conducted (BC stimulus is an alternative stimulation for evoking this response. This study aims to assess the characteristics of BC-VEMP in different groups of patients.   Materials and Methods: We performed a cross sectional analysis on 20 healthy volunteers with normal pure-tone audiometry as a control group; and on a group of patients consisted of 20 participants with conductive hearing loss, five with bilateral sensorineural hearing loss and four with vestibular schawannoma. AC and BC-VEMP were performed in all participants.   Results: In control group the VEMP responses to both kinds of stimuli had an acceptable morphology and consisted of p13 and n23 waves. Latency value of these main components in each type of stimulus was not significantly different (P>0.05. However, the mean amplitude was larger in BC modality than AC stimulation (P=0.025. In the group with conductive hearing loss, the VEMP response was absent in fifteen (46.87% of the 32 ears using the AC method, whereas all (100% displayed positive elicitability of VEMP by BC method. Normal VEMP responses in both stimuli were evoked in all patients with sensorineural hearing loss. In patients with unilateral vestibular schwannomas (VS, 2 (50.00% had neither AC-VEMP nor BC-VEMP. Conclusion:  Auditory stimuli delivered by bone conduction can evoke VEMP response. These responses are of vestibular origin and can be used in vestibular evaluation of patients with conductive hearing loss.

  2. Hearing loss in Diabetes Mellitus

    Pemmaiah K.D

    2011-10-01

    Full Text Available Background: The complex arrangement of inner ear makes it potential target of hyperglycaemic damage. A study was conducted to identify the probable occurrence of hearing loss as a complication of Diabetes Mellitus (DM.Aims and objective:· To assess the hearing loss in type 2 diabetic patients and correlate with age, duration of diabetes, HbA1C.· To correlate hearing loss with nerve conduction study.Design: Cross sectional study was done involving randomly 110 Type 2 DM patients. Data regarding their age and duration of diabetes was collected. Pure tone Audiometry and Nerve conduction study was done. HbA1c level determined. Data statistically analysed using Pearson correlation coefficient.Results: Out of 110 patients 48 patients (43.6% had bilateral Sensorineural hearing in higher frequency (2000hz, 4000hz. Among them Severe hearing loss (71 dB to 90dB was seen in 7 patients (6.36%, moderately severe hearing loss (61dB to 70dB in 16 patients (14.54% and moderate hearing loss(30dB to 60 dB in 25 patients (22.7%. Among 47 patients who had diabetes for more than 10 years, 29 patients (61.7% showed at least mild hearing loss. Duration of DM and sensorineural hearing loss at 2000Hz and 4000Hz showed statistically significant correlation (Pearson coefficient r= 0.561 and r= 0.727 respectively at 0.01 level. In other frequencies no significant correlation was found. Coefficient of determination was r2=0.31(31% and r2=0.52(52% respectively between duration of DM and hearing loss at 2000Hz and 4000Hz. The correlation of hearing loss in lower frequency with HbA1c did not show any statistical significance. However HbA1c and hearing loss in higher frequency (2000 hz and 4000hz showed statistically significant correlation (Pearson coefficient r= 0.282 and r= 0.385 respectively. The correlation of hearing loss with Nerve conduction study did not show any statistical significance.

  3. Detection of acrolein and acrylonitrile with a pulsed room temperature quantum cascade laser

    Manne, J.; Jäger, W.; Tulip, J.

    2010-06-01

    We investigated the use of a pulsed, distributed feedback quantum cascade laser centered at 957 cm-1 in combination with an astigmatic Herriot cell with 250 m path length for the detection of acrolein and acrylonitrile. These molecules have been identified as hazardous air-pollutants because of their adverse health effects. The spectrometer utilizes the intra-pulse method, where a linear frequency down-chirp, that is induced when a top-hat current pulse is applied to the laser, is used for sweeping across the absorption line. Up to 450 ns long pulses were used for these measurements which resulted in a spectral window of ~2.2 cm-1. A room temperature mercury-cadmium-telluride detector was used, resulting in a completely cryogen free spectrometer. We demonstrated detection limits of ~3 ppb for acrylonitrile and ~6 ppb for acrolein with ~10 s averaging time. Laser characterization and optimization of the operational parameters for sensitivity improvement are discussed.

  4. Copolymerization of Indene with Acrylic Acid, Itaconic Acid and Acrylonitrile: Characterization and Reactivity Ratios

    Random copolymers of indene (In) with acrylic acid (AA), itaconic acid (IA) and acrylonitrile (AN) were synthesized by free radical polymerization in dioxane in the presence of azobisisobutyronitrile as an initiator at 60 degree C. The homopolymer of indene and acrylonitrile was prepared using K2MnO4 and sulphuric acid as an initiator, while acrylic acid and itaconic acid were prepared using K2S2O8 solution. The reactivity ratios of the monomers were calculated by different methods. X-ray diffraction as well as thermal analyses were studied. The latter was studied via thermogravimetric analysis and differential thermal analysis. The complexation with metal ions such as Cu+2 and Fe+2 was investigated. The copolymerization and the complexation processes were confirmed by FTIR spectroscopy. Also the activation energy of the prepared copolymers was determined

  5. Nitrilase-catalysed conversion of acrylonitrile by free and immobilized cells of Streptomyces sp.

    V K Nigam; A K Khandelwal; R K Gothwal; M K Mohan; B Choudhury; A S Vidyarthi; P Ghosh

    2009-03-01

    The biotransformation of acrylonitrile was investigated using thermophilic nitrilase produced from a new isolate Streptomyces sp. MTCC 7546 in both the free and immobilized state. Under optimal conditions, the enzyme converts nitriles to acids without the formation of amides. The whole cells of the isolate were immobilized in agar-agar and the beads so formed were evaluated for 25 cycles at 50°C. The enzyme showed a little loss of activity during reuse. Seventy-one per cent of 0.5 M acrylonitrile was converted to acid at 6 h of incubation at a very low density of immobilized cells, while 100% conversion was observed at 3 h by free cells.

  6. Ultrafine conducting fibers: metallization of poly(acrylonitrile-co-glycidyl methacrylate) nanofibers

    Menceloğlu, Yusuf Z.; Menceloglu, Yusuf Z.; Demir, Mustafa Muammer; Uğur, Gökçe; Ugur, Gokce; Gülgün, Mehmet Ali; Gulgun, Mehmet Ali

    2005-01-01

    Electrospun poly(glycidylmethacrylate) (PGMA) and poly(acrylonitrile-co-glycidyl methacrylate) (P(AN-GMA)) nanofibers were coated with monodisperse silver nanoparticles by using an electroless plating technique at ambient conditions. Oxirane groups on the surface of nanofibers were replaced with reducing agent, hydrazine. Surface modified nanofibers were allowed to react with ammonia solution of AgNO3. A redox reaction takes place and metallic silver nucleate on fibers surface. Parameters aff...

  7. Adsorption of Acrylonitrile on Some Soils and Minerals from Aqueous Solutions

    WUDE-YI; N.MATSUE; 等

    1993-01-01

    Equilibrium and kinetic studies have been made on the adsorption of acrylonitrile(CH2=CHCN) on three soils and four minerals from aqueous solutions.It was shown that the organic matter was the major factor affecting the adsorption process in the soils.The conformity of the equilibrium data to linear type(one soil) and Langmuir type(two soils) isotherms indicated that different mechanisms were involved in the adsorption.This behavior appears bo be related to the hydrophobicity of soil organic matter due to their composition and E4/E6 ratio of humic acids.The adsorption kinetics were also different among the soils,indicating the difference in porosity of organic matter among the soils,and the kinetics strongly affected the adsorption capacity of soils for acrylonitrile.Acrylonitrile was slightly adsorbed from aqueous solutions on pyrophyllite with electrically neutral and hydrophobic nature,and practically not on montmorillonite and kaolinite saturated with Ca.However,much higher adsorption occurred on the zeolitized coal ash,probably caused by high organic carbon content(107g/kg).

  8. Electromechanical responses of poly(3-thiopheneacetic acid/acrylonitrile-butadiene rubbers

    2008-12-01

    Full Text Available Acrylonitrile-butadiene rubber (NBR and blends of poly(3-thiopheneacetic acid/ acrylonitrile-butadiene rubber, P3TAA/NBR, were fabricated, and the electrorheological properties, dielectric, and electrical conductivities were investigated . The electrorheological properties were determined under an oscillatory shear mode in a frequency range of 0.1 to 100 rad/s at various electric field strengths, from 0 to 2 kV/mm, at a fixed 27°C to observe the effects of acrylonitrile content (ACN in the rubber systems and the conductive particle concentration in the blends. For the pure rubber systems, the storage modulus response (ΔG′ is linearly dependent on its dielectric constant (ε′, and increases with the ACN content. For the NBR/P3TAA blends, the storage modulus response varies nonlinearly with the dielectric constant. The bending responses of the rubbers and the blends were investigated in a vertical cantilever fixture. For the pure rubber system, the bending angle and the dielectrophoresis force vary linearly with electric field strength. For the blend system, the bending angle and the dielectrophoresis force vary nonlinearly with electric field strength.

  9. Measurements on Hearing

    Poulsen, Torben

    1996-01-01

    Background material for measurements of hearing for grammar school pupils. The note gives the necessary background for the exercise 'Measurement on Hearing'. The topics comprise sound and decibel, the ear, basic psychoacoustics, hearing threshold, audiometric measurement methods, speech and speech...

  10. Protecting Your Hearing

    ... everywhere. But how do you know if loud noise has affected your hearing? A. Julianna Gulya, M.D.: Well, the hearing loss that's just occurred very rapidly -- sometimes like a sudden hearing loss, when you've been ...

  11. Help with Hearing

    ... hearing. This problem can make it more diffi- cult to learn speech sounds and language correctly. Take ... how your child is hearing. See how diffi- cult it is to hear words correctly? Some children ...

  12. Protecting Your Hearing

    Full Text Available ... noise. [loud electric motors] A. Julianna Gulya, M.D.: Loud noise is an important cause of hearing ... has affected your hearing? A. Julianna Gulya, M.D.: Well, the hearing loss that's just occurred very ...

  13. Protecting Your Hearing

    Full Text Available ... affected your hearing? A. Julianna Gulya, M.D.: Well, the hearing loss that's just occurred very rapidly -- ... not that lucky and that hearing loss may be permanent. Narrator: There are two general types of ...

  14. Protecting Your Hearing

    Full Text Available ... have problems with our hearing. There are many causes of hearing loss. Hearing can get worse as we age. Other causes include certain prescription drugs, heredity, head injury, infection, ...

  15. How to Get Hearing Aids

    ... Consumer Products Hearing Aids How to get Hearing Aids Share Tweet Linkedin Pin it More sharing options ... my hearing aids? How do I get hearing aids? To get hearing aids, you should first have ...

  16. Bone conduction hearing in congenital aural atresia.

    Zhang, Lichun; Gao, Na; Yin, Yanbo; Yang, Lin; Xie, Youzhou; Chen, Ying; Dai, Peidong; Zhang, Tianyu

    2016-07-01

    Previous researches focusing on BC hearing mechanisms proved that the two routes, (1) EAC sound radiation and (2) inertial of ossicular chain, partially contribute to normal BC hearing. Therefore, the BC hearing for those patients with congenital aural atresia should partially decrease theoretically due to their abnormal anatomy. However, there are not many studies which mention these patients' BC hearing up till now. The objective of this study is to investigate congenital aural atresia patient's BC hearing by analysis of pre-surgical audiogram and to study their potential BC hearing mechanisms using animal modeling and their ABR measurements. The study methoed involves analyzing 75 patients' pre-operative audiogram. Then we produced an animal model by surgery to measure their BC hearing threshold changes. Clinical data showed that those patients had some BC hearing loss; and there were 25 cases (25/75, 33.3 %) which present with typical Carhart's Notch. The animal experiments proved that inertia of ossicular chain contribute to partial BC hearing, which demonstrated that the inertia produced more affects on high frequencies by comparing with low frequencies. The patients with congenital aural atresia present BC hearing loss, which could be mainly ascribed to the absence of inertia of ossicular chain. PMID:26205153

  17. Development of cartilage conduction hearing aid

    H. Hosoi

    2010-04-01

    Full Text Available Purpose: The potential demand for hearing aids is increasing in accordance with aging of populations in many developed countries. Because certain patients cannot use air conduction hearing aids, they usually use bone conduction hearing aids. However, bone does not transmit sound as efficiently as air, and bone conduction hearing aids require surgery (bone anchored hearing aid or great pressure to the skull. The first purpose of this study is to examine the efficacy of a new sound conduction pathway via the cartilage. The second purpose is to develop a hearing aid with a cartilage conduction transducer for patients who cannot use regular air conduction hearing aids.Design/methodology/approach: We examined the hearing ability of a patient with atresia of both external auditory meatuses via three kinds of conduction pathways (air, bone, and cartilage. After the best position for the cartilage conduction transducer was found, audiometric evaluation was performed for his left ear with an insertion earphone (air conduction, a bone conduction transducer, and a cartilage conduction transducer. Then we made a new hearing aid using cartilage conduction and got subjective data from the patients.Findings: The tragal cartilage was the best position for the cartilage conduction transducer. The patient’s mean hearing levels were 58.3 dBHL, 6.7 dBHL, and 3.3 dBHL for air conduction, bone conduction, and cartilage conduction respectively. The hearing ability of the patients obtained from the cartilage conduction hearing aid was comparable to those from the bone conduction hearing aid.Practical implications: Hearing levels using cartilage conduction are very similar to those via bone conduction. Cartilage conduction hearing aids may overcome the practical disadvantages of bone conduction hearing aids such as pain and the need for surgery.Originality/value: We have clarified the efficacy of the cartilage conduction pathway and developed a prototype

  18. Ab initio investigation of the passivation effect of the acrylonitrile molecule on the Si(100)-(2 × 1) surface

    Usanmaz, D., E-mail: demetusanmaz@gmail.com [Physics Program, Middle East Technical University, Northern Cyprus Campus, Kalkanlı, Güzelyurt, KKTC, Mersin 10 (Turkey); Srivastava, G.P. [School of Physics, University of Exeter, Stocker Road, Exeter EX4 4QL (United Kingdom)

    2014-08-17

    Highlights: • Different bonding configurations of acrylonitrile molecule on the Si(2 × 1) surface based on reported experimental results have been investigated. • The acrylonitrile molecule has the minimum energy configuration at the on-top adsorption site. • The adsorption of the acrylonitrile molecule passivates the Si(2 × 1) surface both chemically as well as electronically. • The resulting surface structure is passivated both chemically as well as electronically. - Abstract: Based on pseudopotentials and the density functional theory, we have investigated the atomic geometry and electronic structure of the acrylonitrile molecule adsorbed on the Si(100)-(2 × 1) surface. By considering different bonding configurations based on reported experimental results, we have investigated several possible geometries. Our total energy results suggest that the acrylonitrile molecule has the minimum energy configuration at the on-top adsorbtion site. The electronic surface properties of the most stable structure have been discussed. Our results show that the adsorption of this molecule fully passivates the Si(001)(2 × 1) surface.

  19. CERN hearing day

    2005-01-01

    1 in 10 people suffer from hearing loss - do you? The Medical Service invites everyone working on CERN premises to participate in the National Hearing Day on: Thursday 10th March From 9am to 4pm The Infirmary, Blg. 57, Gr.Fl. We will be offering hearing tests (audiogram); information, advice on hearing loss, tinnitus and more. Deafness does not just affect the elderly: in Europe, 50% the hearing-impaired are under the age of 55. Exposure to excessive noise is one of the main reasons for hearing loss. But prevention is possible and effective: for example, Hearing protection devices could reduce tinnitus cases by 80%.

  20. CERN hearing day

    2005-01-01

    1 in 10 people suffer from hearing loss ? do you? The Medical Service invites everyone working on the CERN site to participate in the NATIONAL HEARING DAY on: Thursday 10th March 2005 From 9am to 4pm The Infirmary, Blg. 57, Ground Floor We will be offering hearing tests (audiograms), as well as information and advice on hearing loss, tinnitus, etc. Deafness does not just affect the elderly: in Europe, 50% of the hearing-impaired are under the age of 55. Exposure to excessive noise is one of the main reasons for hearing problems but prevention is possible. For example, hearing protection devices can prevent 80% of tinnitus cases.

  1. CERN hearing day

    2005-01-01

    1 in 10 people suffer from hearing loss - do you? The Medical Service invites everyone working on the CERN site to participate in the NATIONAL HEARING DAY on: Thursday 10th March 2005 From 9am to 4pm The Infirmary, Blg. 57, Ground Floor We will be offering hearing tests (audiograms), as well as information and advice on hearing loss, tinnitus, etc. Deafness does not just affect the elderly: in Europe, 50% of the hearing-impaired are under the age of 55. Exposure to excessive noise is one of the main reasons for hearing problems but PREVENTION IS POSSIBLE. For example, hearing protection devices can prevent 80% of tinnitus cases.

  2. CERN hearing day

    2005-01-01

    1 in 10 people suffer from hearing loss - do you? The Medical Service invites everyone working on CERN premises to participate in the National Hearing Day on: Thursday 10th March From 9am to 4pm The Infirmary, Blg. 57, Gr.Fl. We will be offering hearing tests (audiogram); information, advice on hearing loss, tinnitus and more. Deafness does not just affect the elderly: in Europe, 50% the hearing-impaired are under the age of 55. Exposure to excessive noise is one of the main reasons for hearing loss. But PREVENTION IS POSSIBLE AND EFFECTIVE: for example, Hearing protection devices could reduce tinnitus cases by 80%.

  3. Thermosensitive Poly(N-isopropylacrylamide-co-acrylonitrile) Hydrogels with Rapid Response%非离子型凝胶球在水中的溶胀行为

    黄健; 黄志明; 包永忠; 翁志学

    2006-01-01

    Acrylonitrile (AN) was copolymerized with N-isopropylacrylamide (NIPA) to synthesize thermosensitive bydrogels, and the on-off switch behavior of poly(NIPA-co-AN) hydrogels with different fraction of hydrophobic component (AN) was investigated. It is found that the lower critical solution temperature (LCST), the swelling ratio at certain temperature and the reswelling rate of poly(NIPA-co-AN) hydrogels decreased as AN unit fraction in copolymers increased. In order to improve the responsive rate of poly(NIPA-co-AN) hydrogels, they were further treated by surface crosslinking using N, N'-methylene bisacrylamide (BIS) as a crosslinking agent. The swelling and deswelling behaviors of these copolymers were compared with those of the untreated hydrogels. The results indicated that the responsive rate of poly(NIPA-co-AN) hydrogel was improved by surface crosslinking. The resulting hydrogels bearing cyano groups with fast response have potential applications in the field of drug-controlled release and immobilization of biomolecules.

  4. Hearing loss and disability exit: measurement issues and coping strategies

    Christensen, Vibeke T.; Gupta, Nabanita Datta; Rasmussen, Martin V.

    2007-01-01

    Using unique representative data containing self-reported functional and clinically measured hearing ability for the Danish population aged 50-64, we estimate the effect of hearing loss on receipt of disability benefits accounting for potential endogeneity of functional hearing. Our identification strategy involves simultaneous estimation of labor supply, functional hearing and coping strategies i.e. using assistive devices at work or informing one's employer about the problem. We find that f...

  5. Hearing Aids: A Review for the Family Physician

    Gaudry, Florent

    1987-01-01

    Hearing impairment is a common disability which can often be minimized by the use of hearing aids. Various types of hearing aids have been developed which are appropriate for most hearing losses that are not medically or surgically treatable, and these devices have been variously applied. Potential benefits and limitations of amplification need to be considered for each patient. Changes in technology, assistive devices, and the development of the cochlear implant have improved the ability of ...

  6. Music exposure and hearing disorders: an overview.

    Zhao, Fei; Manchaiah, Vinaya K C; French, David; Price, Sharon M

    2010-01-01

    It has been generally accepted that excessive exposure to loud music causes various hearing symptoms (e.g. tinnitus) and consequently leads to a risk of permanent hearing damage, known as noise-induced hearing loss (NIHL). Such potential risk of NIHL due to loud music exposure has been widely investigated in musicians and people working in music venues. With advancements in sound technology and rapid developments in the music industry, increasing numbers of people, particularly adolescents and young adults, are exposing themselves to music on a voluntary basis at potentially harmful levels, and over a substantial period of time, which can also cause NIHL. However, because of insufficient audiometric evidence of hearing loss caused purely by music exposure, there is still disagreement and speculation about the risk of hearing loss from music exposure alone. Many studies have suggested using advanced audiological measurements as more sensitive and efficient tools to monitor hearing status as early indicators of cochlear dysfunction. The purpose of this review is to provide further insight into the potential risk of hearing loss caused by exposure to loud music, and thus contribute to further raising awareness of music induced hearing loss. PMID:20001447

  7. General Framework of Hearing Aid Fitting Management

    Oh, Soo Hee

    2016-01-01

    Hearing aids are one of the most widely used treatment options for the hearing impaired and optimal outcomes of hearing aids are supported by comprehensive hearing aid fitting protocols. Currently, the term 'hearing aid fitting' is prevalently used among service and industry sectors with its comprehensive procedures not systematically explicated. In addition, a variety of non-normalized guidelines for hearing aid fitting has led to non-uniform care, outcome variability, and dissatisfaction of the use of hearing aids. The main purpose of the present study is to suggest a general framework of standardized practice for hearing aid fitting management including its pre- and post-fitting stages. The management framework centers on its fitting process with its prior steps of assessment as well as its posterior steps of follow-up, thereby eliminating diverging interpretations and non-uniform practices. Outcomes of this study are also expected to improve potential benefits such as quality of hearing aid fitting, user satisfaction, and cost effectiveness across relevant stakeholders. PMID:27144226

  8. Positron lifetime study of polycarbonate/poly(styrene-co-acrylonitrile) blends

    Čížek, J.; Motyčka, V.; Procházka, I.; Ilavský, Michal; Kolařík, Jan

    2001-01-01

    Roč. 363, č. 3 (2001), s. 340-342. ISSN 0255-5476. [International Conference on Positron Annihilation /12./. Munchen, 06.08.2000-12.08.2000] R&D Projects: GA ČR GA106/98/0700; GA AV ČR KSK2050602 Institutional research plan: CEZ:AV0Z4050913 Keywords : partial miscibility of polymers * polycarbonate/poly(styrene-co- acrylonitrile ) blends * positron lifetime spectroscopy Subject RIV: CD - Macromolecular Chemistry Impact factor: 0.461, year: 2001

  9. Effect of strain on dielectric properties of poly(styrene-co-acrylonitrile)/polycarbonate blend

    Nedbal, J.; Valentová, H.; Ilavský, Michal

    Bratislava : Polymer Institute of the Slovak Academy of Sciences, 2003 - (Omastová, M.). s. 58 ISBN 80-968433-2-X. [Bratislava International Conference on Modified Polymers ModPol /18./. 05.10.2003-08.10.2003, Stará Lesná] R&D Projects: GA AV ČR IAA4112901 Grant ostatní: GA UK(CZ) 166/2001/B Institutional research plan: CEZ:AV0Z4050913 Keywords : dielectric properties * poly(styrene-co- acrylonitrile )/polycarbonate blends Subject RIV: BM - Solid Matter Physics ; Magnetism

  10. Ion exchange membranes based on vinylphosphonic acid-co-acrylonitrile copolymers for fuel cells

    Žitka, Jan; Bleha, Miroslav; Schauer, Jan; Galajdová, Barbora; Paidar, M.; Hnát, J.; Bouzek, K.

    2015-01-01

    Roč. 56, č. 12 (2015), s. 3167-3173. ISSN 1944-3994. [International Conference on Membrane and Electromembrane Processes - MELPRO 2014. Prague, 18.05.2014-21.05.2014] R&D Projects: GA ČR(CZ) GPP106/12/P643 EU Projects: European Commission(XE) 608931 - MAT4BAT Institutional support: RVO:61389013 Keywords : vinylphosphonic acid * poly(vinylphosphonic acid-co-acrylonitrile) * ionic conductivity Subject RIV: CD - Macromolecular Chemistry Impact factor: 1.173, year: 2014

  11. Modification of fiber properties through grafting of acrylonitrile to rayon by chemical and radiation methods

    Inderjeet Kaur; Neelam Sharma; Vandna Kumari

    2013-01-01

    Fibrous properties of rayon has been modified through synthesis of graft copolymers of rayon with acrylonitrile (AN) by chemical method using ceric ammonium nitrate (CAN/HNO3) as a redox initiator and gamma radiation mutual method. Percentage of grafting (Pg) was determined as a function of initiator concentration, monomer concentration, irradiation dose, temperature, time of reaction and the amount of water. Maximum percentage of grafting (160.01%) using CAN/HNO3 was obtained at [CAN] = 22.8...

  12. ION CONDUCTION IN COMPLEX OF ACRYLONITRILE-COPOLYMERIZED COMB POLYETHER WITH LITHIUM PERCHLORATE

    XU Kang; DENG Zhenghua; WAN Guoxiang

    1991-01-01

    Poly ( oligoether methacrylate- co- acrylonitrile ) s, P ( MEOn- AN ), with oligoether pendants of different lengths were synthesized and the ion conduction property of their Li-salt complexes was studied as the function of polymer structure. At proper copolymer composition, lithium concentration and pendant length, the ion conductivity reaches 7.0×10-5S/cm at ambient temperature, together with improved mechanical strength. The ion transport in the polymer media is assisted by segmental relaxation ,which is confirmed both by the consistency between ion conductivity and Tg and by the study of TSC.

  13. Autodetachment dynamics of acrylonitrile anion revealed by 2D electron impact spectra

    We have measured the elastic and vibrationally inelastic differential cross sections in acrylonitrile at the scattering angle of 135°. We have found out that the bands at 2.9 and 4.4 eV are shape resonances, while sharp structures in the region 0 -0.5 eV are either boomerang structure of a shape resonance or vibrational Feshbach resonances. We gain detailed view of the autodetachment dynamics from a 2D spectrum where cross section is plotted against the incident energy and the energy loss.

  14. [Carcinogenicity of acrylonitrile and evaluation of approaches to pathogenetic correction of acrylate toxicity and antitumorigenic anthracycline doxorubicin toxicity during chemotherapy].

    Tarskikh, M M; Shumbasov, M A; Kolesnikov, S I

    2013-01-01

    Statistical analysis within the 20-year period showed that approximately 49% of workers who were exposed to widespread industrial poison acrylonitrile subsequently died from malignancy of different localization. The conducted experimental investigations demonstrated that acrylonitrile with the subacute intoxication of animals, the anti-tumor antibiotic doxorubicin, their combination, interwoven tumor and tumor developed against the background the introduction of acrylate and subsequent treatment doxorubicin led to onset of free-radical reactions. These reactions by themselves might stimulate development of malignancy. This fact confirms the need for antioxidant tracking of chemotherapy of tumors in the similar clinical cases. PMID:23819331

  15. Onderzoek naar de mutagene werking van acrylonitril met microorganismen Drosophila melanogaster en L5178Y muize-lymfoomcellen

    Voogd CE; van der Stel JJ; Verharen HW; Kramers PGN; Mout HCA; Knaap AGAC; Langbroek PG

    1985-01-01

    Acrylonitril was mutageen bij 5 mmol/l in de fluctuatietest zonder metabolische activering ; in gasfase werd bij 0,5 mmol/l lucht een mutagene werking gevonden. Deze stof was ook mutageen in de Ames-test voor Salmonella typhimurium TA1535 (15 mmol/plaat) met metabolische activering doch niet met de stammen TA98 en TA100. In de gasfase werd in de Ames-test geen mutagene werking gevonden, groeiremming trad op bij ca. 0,1 mmol/l lucht. Met acrylonitril werd geen mutagene werking gevonden op Dros...

  16. Hearing and hearing loss: Causes, effects, and treatments

    Schmiedt, Richard A.

    2003-04-01

    Hearing loss can have multiple causes. The outer and middle ears are conductive pathways for acoustic energy to the inner ear (cochlea) and help shape our spectral sensitivity. Conductive hearing loss is mechanical in nature such that the energy transfer to the cochlea is impeded, often from eardrum perforations or middle ear fluid buildup. Beyond the middle ear, the cochlea comprises three interdependent systems necessary for normal hearing. The first is that of basilar-membrane micromechanics including the outer hair cells. This system forms the basis of the cochlear amplifier and is the most vulnerable to noise and drug exposure. The second system comprises the ion pumps in the lateral wall tissues of the cochlea. These highly metabolic cells provide energy to the cochlear amplifier in the form of electrochemical potentials. This second system is particularly vulnerable to the effects of aging. The third system comprises the inner hair cells and their associated sensory nerve fibers. This system is the transduction stage, changing mechanical vibrations to nerve impulses. New treatments for hearing loss are on the horizon; however, at present the best strategy is avoidance of cochlear trauma and the proper use of hearing aids. [Work supported by NIA and MUSC.

  17. Externalization versus Internalization of Sound in Normal-hearing and Hearing-impaired Listeners

    Ohl, Björn; Laugesen, Søren; Buchholz, Jörg; Dau, Torsten

    2010-01-01

    listeners in the hearing-impaired group. Partly, there was an influence by the direction of sound incidence. On average across subjects, the dynamic range available to perceive externalization was reduced compared to normal-hearing subjects. Overall, it was shown that hearing-impaired listeners are able to...... perceive externalization, but also that they are less sensitive to minor deviations from complete internalization and externalization.......The externalization of sound, i. e. the perception of auditory events as being located outside of the head, is a natural phenomenon for normalhearing listeners, when perceiving sound coming from a distant physical sound source. It is potentially useful for hearing in background noise, but the...

  18. Sensitive detection of acrolein and acrylonitrile with a pulsed quantum-cascade laser

    Manne, J.; Lim, A.; Tulip, J.; Jäger, W.

    2012-05-01

    We report on spectroscopic measurements of acrolein and acrylonitrile at atmospheric pressure using a pulsed distributed feedback quantum-cascade laser in combination with intra- and inter-pulse techniques and compare the results. The measurements were done in the frequency region around 957 cm-1. In the inter-pulse technique, the laser is excited with short current pulses (5-10 ns), and the pulse amplitude is modulated with an external current ramp resulting in a ˜2.3 cm-1 frequency scan. In the intra-pulse technique, a linear frequency down-chirp during the pulse is used for sweeping across the absorption line. Long current pulses up to 500 ns were used for these measurements which resulted in a spectral window of ˜2.2 cm-1 during the down-chirp. These comparatively wide spectral windows facilitated the measurements of the relatively broad absorption lines (˜1 cm-1) of acrolein and acrylonitrile. The use of a room-temperature mercury-cadmium-telluride detector resulted in a completely cryogen-free spectrometer. We demonstrate ppb level detection limits within a data acquisition time of ˜10 s with these methodologies.

  19. Novel in situ coordinated cerium salt/acrylonitrile-butadiene rubber composite

    A novel rubber composite of acrylonitrile-butadiene rubber (NBR) filled with cerium salt particles was vulcanized via in situ coordination for the first time. The resulting materials exhibit good mechanical properties. Curing characteristics analysis, differential scanning calorimetry, X-ray photoelectron spectroscopy, tensile testing, and an equilibrium swelling method were used for the characterization of the composite. The results in this paper indicate that the composite is a kind of elastomer based on the in situ coordination crosslinking interactions between the nitrile groups (–CN) of NBR and cerium ions. The mechanical properties of vulcanized cerium salt/ NBR rubber are altered when changing the sorts of cerium salt. Moreover, these materials show good irradiation resistance because of the introduction of the cerium salt. -- Highlights: ► Cerium salts were firstly used to vulcanize the acrylonitrile-butadiene rubber. ► Cerium salts act as not only crosslink agents but also reinforcing fillers in the matrix. ► These materials show good irradiation resistance and mechanical properties at same time.

  20. Synthesis and gas permeability of block copolymers composed of poly(styrene-co-acrylonitrile) and polystyrene blocks

    Lokaj, Jan; Brožová, Libuše; Holler, Petr; Pientka, Zbyněk

    2002-01-01

    Roč. 67, č. 2 (2002), s. 267-278. ISSN 0010-0765 R&D Projects: GA ČR GA203/99/0572 Institutional research plan: CEZ:AV0Z4050913 Keywords : azeotropic styrene- acrylonitrile copolymers * block copolymers * nitroxide-mediated copolymerization Subject RIV: CD - Macromolecular Chemistry Impact factor: 0.848, year: 2002

  1. Synthesis of diblock copolymers comprising poly(2-vinylpyridine-co-acrylonitrile) and polystyrene blocks by nitroxide-mediated radical polymerization

    Lokaj, Jan; Poláková, Lenka; Holler, Petr; Starovoytova, Larisa; Štěpánek, Petr; Diat, O.

    2007-01-01

    Roč. 105, č. 3 (2007), s. 1616-1622. ISSN 0021-8995 R&D Projects: GA ČR GESON/03/E001 Institutional research plan: CEZ:AV0Z40500505 Keywords : 2-vinylpyridine-acrylonitrile copolymers * nitroxide-mediated radical copolymerization * chain extension Subject RIV: CD - Macromolecular Chemistry Impact factor: 1.008, year: 2007

  2. Ultrasonic velocity and absorption study of binary mixtures of cyclohexane with acrylonitrile by interferometric method at different frequencies

    Pawar, N. R.; Chimankar, O. P.; Bhandakkar, V. D.; Padole, N. N.

    2012-12-01

    The ultrasonic velocity (u), absorption (α), density (ρ), and viscosity (η) has been measured at different frequencies (1MHz to 10MHz) in the binary mixtures of cyclohexane with acrylonitriile over the entire range of composition at temperature 303K. Vander Waal's constant (b), adiabatic compressibility (βa), acoustic impedance (Z), molar volume (V), free length (Lf), free volume, internal pressure, intermolecular radius and relative association have been also calculated. A special application for acrylonitrile is in the manufacture of carbon fibers. These are produced by paralysis of oriented poly acrylonitrile fibers and are used to reinforce composites for high-performance applications in the aircraft, defense and aerospace industries. Other applications of acrylonitrile are in the production of fatty amines, ion exchange resins and fatty amine amides used in cosmetics, adhesives, corrosion inhibitors and water-treatment resins. Cyclohexane derivatives can be used for the synthesis of pharmaceuticals, dyes, herbicides, plant growth regulator, plasticizers, rubber chemicals, nylon, cyclamens and other organic compounds. In the view of these extensive applications of acrylonitrile and cyclohexane in the engineering process, textile and pharmaceutical industries present study provides qualitative information regarding the nature and strength of interaction in the liquid mixtures through derive parameters from ultrasonic velocity and absorption measurement.

  3. Ultrasonic velocity and absorption study of binary mixtures of cyclohexane with acrylonitrile by interferometric method at different frequencies

    The ultrasonic velocity (u), absorption (α), density (ρ), and viscosity (η) has been measured at different frequencies (1MHz to 10MHz) in the binary mixtures of cyclohexane with acrylonitriile over the entire range of composition at temperature 303K. Vander Waal's constant (b), adiabatic compressibility (βa), acoustic impedance (Z), molar volume (V), free length (Lf), free volume, internal pressure, intermolecular radius and relative association have been also calculated. A special application for acrylonitrile is in the manufacture of carbon fibers. These are produced by paralysis of oriented poly acrylonitrile fibers and are used to reinforce composites for high-performance applications in the aircraft, defense and aerospace industries. Other applications of acrylonitrile are in the production of fatty amines, ion exchange resins and fatty amine amides used in cosmetics, adhesives, corrosion inhibitors and water-treatment resins. Cyclohexane derivatives can be used for the synthesis of pharmaceuticals, dyes, herbicides, plant growth regulator, plasticizers, rubber chemicals, nylon, cyclamens and other organic compounds. In the view of these extensive applications of acrylonitrile and cyclohexane in the engineering process, textile and pharmaceutical industries present study provides qualitative information regarding the nature and strength of interaction in the liquid mixtures through derive parameters from ultrasonic velocity and absorption measurement.

  4. Protecting Your Hearing

    Full Text Available ... Julianna Gulya, M.D.: Loud noise is an important cause of hearing loss. The inner ear organ ... gone, they're gone and so it's very important to protect one's hearing from exposure to any ...

  5. Types of Hearing Loss

    ... on this topic can be found in our Audiology Information Series [PDF]. Hearing loss can be categorized ... speech-language pathologists; speech, language, and hearing scientists; audiology and speech-language pathology support personnel; and students. ...

  6. Protecting Your Hearing

    Full Text Available ... an important cause of hearing loss. The inner ear organ of hearing is a structure called the ... rock concert, people will typically complain that their ear feels blocked up, they feel like they have ...

  7. Protecting Your Hearing

    Full Text Available ... circulation problems such as high blood pressure. But one cause of hearing loss that is 100% preventable ... gone and so it's very important to protect one's hearing from exposure to any loud noise. Narrator: ...

  8. Protecting Your Hearing

    Full Text Available ... essential part of every day life. But as we grow older, we are more likely to have problems with our ... of hearing loss. Hearing can get worse as we age. Other causes include certain prescription drugs, heredity, ...

  9. Protecting Your Hearing

    Full Text Available ... re gone and so it's very important to protect one's hearing from exposure to any loud noise. ... from loud noise. There are ways you can protect yourself from noise-induced hearing loss. A. Julianna ...

  10. Hearing Disorders and Deafness

    ... impossible, to hear. They can often be helped. Deafness can keep you from hearing sound at all. ... certain medicines, and surgery. NIH: National Institute on Deafness and Other Communication Disorders

  11. Genes and Hearing Loss

    ... Meeting Calendar Find an ENT Doctor Near You Genes and Hearing Loss Genes and Hearing Loss Patient ... mutation may only have dystopia canthorum. How Do Genes Work? Genes are a road map for the ...

  12. Protecting Your Hearing

    Full Text Available ... an essential part of every day life. But as we grow older, we are more likely to ... causes of hearing loss. Hearing can get worse as we age. Other causes include certain prescription drugs, ...

  13. Noise and Hearing Protection

    ... Meeting Calendar Find an ENT Doctor Near You Noise and Hearing Protection Noise and Hearing Protection Patient ... it is. How can I tell if a noise is dangerous? People differ in their sensitivity to ...

  14. Protecting Your Hearing

    Full Text Available ... loud noise. There are ways you can protect yourself from noise-induced hearing loss. A. Julianna Gulya, ... taking good care of your hearing and by talking to your doctor if you think you have ...

  15. Genetics of Hearing Loss

    ... in Latin America Information For... Media Policy Makers Genetics of Hearing Loss Language: English Español (Spanish) Recommend ... of hearing loss in babies is due to genetic causes. There are also a number of things ...

  16. RESONANCE THEORY OF HEARING

    Husnija Hasanbegović

    2014-01-01

    The processes of hearing the sounds and speech are not yet explicable enough, and therefore rehabilitation audiology is continuously facing practical problems of hearing and speech stimulation with heavy out of hearing children. Hearing successes with children who have implanted cochlear apparatus may indicate to resonance problem, rather than damaged nerve cells problem with deaf children, as it is alleged today. This paper presents a new theory (the theory of resonance rehabilit...

  17. Protecting Your Hearing

    Full Text Available ... everywhere. But how do you know if loud noise has affected your hearing? A. Julianna Gulya, M.D.: Well, the hearing loss that's just occurred very rapidly -- sometimes like a sudden hearing loss, when you've been ...

  18. Hearing loss and music

    Noise induced hearing loss - music; Sensory hearing loss - music ... damaged by loud sounds. The human ear is like any other body part -- too much use can damaged it. Over time, repeated exposure to loud noise and music can cause hearing loss.

  19. Protecting Your Hearing

    Full Text Available ... it is an essential part of every day life. But as we grow older, we are more likely to have problems with our hearing. There are many causes of hearing loss. Hearing can get worse as we age. Other ...

  20. Hearing Aids Communication

    Globally, hearing loss is the second most frequent disability. About 80% of the persons affected by hearing loss do not use hearing aids. The goal of this edited volume is to present a theoretically founded, interdisciplinary approach geared at understanding and improving social interaction impac...

  1. Studies of plastic crystal gel polymer electrolytes based on poly(vinylidene chloride-co-acrylonitrile)

    Hambali, D.; Zainuddin, Z.; Supa'at, I.; Osman, Z.

    2016-02-01

    In this work, we have prepared systems of poly(vinylidene chloride-co-acrylonitrile) (PVdC-co-AN) based gel polymer electrolytes (GPEs) which are single plasticized-GPEs and double plasticized-GPEs. Both systems comprised plastic crystal succinonitrile SN to form plastic crystal gel polymer electrolyte (PGPE) films. The ionic conductivity of the PGPE films were analysed by means of a.c. impedance spectroscopy at room temperature as well as at the temperature range of 303 K to 353 K. The temperature dependence ionic conductivity was found to obey the VTF rule. To study the interactions among the constituents in the PGPEs, Fourier Transform Infrared Spectroscopy (FTIR) was carried out and hence, the complexation between them has also been confirmed.

  2. Structures and Properties Characterization of Acrylonitrile-butadiene-styrene/Organo-palygorskite Clay Composites

    ZHANG Zhe; CHANG Ying; XU Jian; WU Zhancui; MA Hengchang; LEI Ziqiang

    2012-01-01

    Palygorskite (PGS) and vinyl tris-(2-methoxyethoxy) silane (KH-172) modified palygorskite (OPGS) were used to prepare acrylonitrile-butadiene-styrene (ABS)/clay composites.Thermal stability of the composites was evaluated by using thermogravimetric analysis (TGA).The morphology of the fractured surface and the degree of dispersion of the clay in the ABS matrix were observed by scanning electron microscopy (SEM).X-ray diffraction (XRD) analysis results showed the variation of the crystal structure.Measurements of the tensile properties of the ABS/clay composites proved that the ABS/OPGS composited material represented the most excellent tensile property,because of good compatibility and dispersion of ABS with OPGS.

  3. Flame Retardant Effects of Nano-Clinoptilolite on AcrylonitrileButadiene-Styrene (ABS Nano-Composite

    Aboulfazl Barati

    2012-01-01

    Full Text Available In recent years, intumescent technology has found a place in polymer science as a method of providing flame retardance to polymeric materials. On heating, fire-retardant intumescent material restricts the action of the heat flux or flame. The proposed mechanism is based on charred layer acting as physical barrier, which slows down heat and mass transfer between the gas and the condensed phases. In this paper, the flammability of intumescent fire-retardant acrylonitrile-butadiene-styrene (ABS matrix composites consisting of hydromagnesite (HMg as an acid source and blowing agent, pentaerythritol (PER as a carbonisation agent and natural zeolite (clinoptilolite rich, Kansar Shargh as a synergistic agent were examined. The flammability of composites was characterized by limiting oxygen index (LOI measurement and horizontal burning tests. A synergistic effect in flame retardancy was observed when natural zeolites were used in combination with HMg and PER.

  4. Certification of mercury in acrylonitrile butadiene styrene by using isotope dilution mass spectrometry

    Under the framework of a co-certification system for the development of Certified Reference Materials (CRMs) among China, Japan and Korea, the 1st co-certification campaign of mercury in acrylonitrile butadiene styrene (ABS) for Japanese CRMs was taken. In this campaign isotope dilution mass spectrometry (IDMS) was used. First, all abundances of Hg in spike 202Hg, CRM and ABS were analyzed by MC-ICP-MS before the certification. Then the concentrations of 202Hg and Hg in ABS were determined with IDMS by Q-ICP-MS. A new procedure to reduce memory effect was used. first, dilute with 5 μg/g Au solution for 1 min; then, 5 μg/g EDTA solution for 2 min. The results accord to each other very well and this implies that the co-certification system can run swimmingly. (authors)

  5. Acrylonitrile-14C metabolism in rats: effect of the route of administration on the elimination of thiocyanate and other radioactive metabolites in urine and feces

    In Wistar rats, the elimination of the sum of radioactive metabolites of acrylonitrile-14C was not markedly influenced by the route of acrylonitrile administration. The elimination of thiocyanate, however, was significantly higher after oral (23% of the dose) than after intraperitoneal (4%), subcutaneous (4.6%), or intravenous (1.2%) administrations. The elimination of the sum of radioactive metabolites was highest in the first 4 hours after acrylonitrile administration and rapidly decreased whereas the excretion of thiocyanate reached the maximum between hours 8 and 14 after oral or intraperitoneal administration. Less than 1% of the radioactivity of the acrylonitrile-14C dose was eliminated in feces irrespective of the route of administration. (author)

  6. Covalent immobilization of glucose oxidase onto new modified acrylonitrile copolymer/silica gel hybrid supports.

    Godjevargova, Tzonka; Nenkova, Ruska; Dimova, Nedyalka

    2005-08-12

    New polymer/silica gel hybrid supports were prepared by coating high surface area of silica gel with modified acrylonitrile copolymer. The concentrations of the modifying agent (NaOH) and the modified polymer were varied. GOD was covalently immobilized on these hybrid supports and the relative activity and the amount of bound protein were determined. The highest relative activity and sufficient amount of bound protein of the immobilized GOD were achieved in 10% NaOH and 2% solution of modified acrylonitrile copolymer. The influence of glutaraldehyde concentration and the storage time on enzyme efficiency were examined. Glutaraldehyde concentration of 0.5% is optimal for the immobilized GOD. It was shown that the covalently bound enzyme (using 0.5% glutaraldehyde) had higher relative activity than the activity of the adsorbed enzyme. Covalently immobilized GOD with 0.5% glutaraldehyde was more stable for four months in comparison with the one immobilized on pure silica gel, hybrid support with 10% glutaraldehyde and the free enzyme. The effect of the pore size on the enzyme efficiency was studied on four types of silica gel with different pore size. Silica with large pores (CPC-Silica carrier, 375 A) presented higher relative activity than those with smaller pore size (Silica gel with 4, 40 and 100 A). The amount of bound protein was also reduced with decreasing the pore size. The effect of particle size was studied and it was found out that the smaller the particle size was, the greater the activity and the amount of immobilized enzyme were. The obtained results proved that these new polymer/silica gel hybrid supports were suitable for GOD immobilization. PMID:16080168

  7. Photoinitiated decomposition of substituted ethylenes: The photodissociation of vinyl chloride and acrylonitrile at 193 nm

    Blank, D.A.; Suits, A.G.; Lee, Y.T. [Lawrence Berkeley National Lab., CA (United States)] [and others

    1997-04-01

    Ethylene and its substituted analogues (H{sub 2}CCHX) are important molecules in hydrogen combustion. As the simplest {pi}-bonded hydrocarbons these molecules serve as prototypical systems for understanding the decomposition of this important class of compounds. The authors have used the technique of photofragment translational spectroscopy at beamline 9.0.2.1 to investigate the dissociation of vinyl chloride (X=Cl) and acrylonitrile (X=CN) following absorption at 193 nm. The technique uses a molecular beam of the reactant seeded in helium which is crossed at 90 degrees with the output of an excimer laser operating on the ArF transition, 193.3 nm. The neutral photoproducts which recoil out of the molecular beam travel 15.1 cm where they are photoionized by the VUV undulator radiation, mass selected, and counted as a function of time. The molecular beam source is rotatable about the axis of the dissociation laser. The authors have directly observed all four of the following dissociation channels for both systems: (1) H{sub 2}CCHX {r_arrow} H + C{sub 2}H{sub 2}X; (2) H{sub 2}CCHX {r_arrow} X + C{sub 2}H{sub 3}; (3) H{sub 2}CCHX {r_arrow} H{sub 2} + C{sub 2}HX; and (4) H{sub 2}CCHX {r_arrow} HX + C{sub 2}H{sub 2}. They measured translational energy distributions for all of the observed channels and measured the photoionization onset for many of the photoproducts which provided information about their chemical identity and internal energy content. In the case of acrylonitrile, selective product photoionization provided the ability to discriminate between channels 2 and 4 which result in the same product mass combination.

  8. Ionizing radiation effect study by electron beam on acrylonitrile butadiene styrene - ABS terpolymer

    The great advantage in the researches involving development has as objective to increase significantly the quality of the products. The ABS (acrylonitrile, butadiene, styrene) resins are terpolymers formed by an elastomer and two thermoplastics amorphous components. The three different monomeric units from the terpolymer ABS contribute separately to the material characteristics exhibited. The molecular stiffness originating from polystyrene and the benzene ring hanging on the chain is responsible for the flexion module ABS. The acrylonitrile and the styrene incorporated butadiene exercises strong influence in the resistance to the impact because it reduces the bonding among them. The engineering use of this terpolymer became important due their mechanical properties and mainly, for the responses of this to tensions or deformations applied. The polymeric materials, when submitted to the ionizing radiation are modified by the transference of energy to these materials, introducing excitation and ionization of the molecules, generating chemical reactions that can produce permanent modifications in the polymeric physicochemical structure. The induced modifications can result in the polymeric material degradation or crosslinking, which can result in the improvement of some properties. This work has, as objective, to study the electron beam ionizing radiation effect, at different doses, in the properties of the polymer ABS. The studied properties were: tensile strength at break, elongation at break, Izod impact strength, flexural strength, melt flow index, Vicat softening temperature and the thermic distortion temperature. Also researches on Differential Scanning Calorimetry (DSC) and Thermogravimetric Analyses (TGA) were accomplished. From the experimental results, it was showed that for doses until 500 kGy, at 22.6 kGy/s dose rate, in the presence of air, the crosslinking process of ABS prevails. (author)

  9. Laboratory methods of assessing hearing loss.

    Møller, A R

    1982-01-01

    Methods for assessing hearing loss in human loss in human and in animal are reviewed with special reference to the use of brainstem auditory evoked potentials (BSEP). The technique of recording and digital filtering of BSEP is described and compared with the results obtained by use of traditional analog filtering. The use of electrophysiological methods in assessing threshold shifts in studies of the effect of noise exposure on hearing in experimental animals is described for examples of resu...

  10. Music and hearing aids.

    Madsen, Sara M K; Moore, Brian C J

    2014-01-01

    The signal processing and fitting methods used for hearing aids have mainly been designed to optimize the intelligibility of speech. Little attention has been paid to the effectiveness of hearing aids for listening to music. Perhaps as a consequence, many hearing-aid users complain that they are not satisfied with their hearing aids when listening to music. This issue inspired the Internet-based survey presented here. The survey was designed to identify the nature and prevalence of problems associated with listening to live and reproduced music with hearing aids. Responses from 523 hearing-aid users to 21 multiple-choice questions are presented and analyzed, and the relationships between responses to questions regarding music and questions concerned with information about the respondents, their hearing aids, and their hearing loss are described. Large proportions of the respondents reported that they found their hearing aids to be helpful for listening to both live and reproduced music, although less so for the former. The survey also identified problems such as distortion, acoustic feedback, insufficient or excessive gain, unbalanced frequency response, and reduced tone quality. The results indicate that the enjoyment of listening to music with hearing aids could be improved by an increase of the input and output dynamic range, extension of the low-frequency response, and improvement of feedback cancellation and automatic gain control systems. PMID:25361601

  11. Morphology of polystyrene-block-poly(styrene-co-acrylonitrile) and polystyrene-block-poly(styrene-co-acrylonitrile-co-5-vinyltetrazole) diblock copolymers prepared by nitroxide-mediated radical polymerization and „click“ chemistry

    Gromadzki, Daniel; Lokaj, Jan; Černoch, Peter; Diat, O.; Nallet, F.; Štěpánek, Petr

    2008-01-01

    Roč. 44, č. 1 (2008), s. 189-199. ISSN 0014-3057 R&D Projects: GA ČR GESON/06/E005 Grant ostatní: Marie Curie Fellowship(EU) HPMT-CT-2001-00396 Institutional research plan: CEZ:AV0Z40500505 Keywords : polystyrene-block-poly(styrene-co- acrylonitrile -co-5-vinyltetrazole) * TEMPO * click chemistry Subject RIV: CD - Macromolecular Chemistry Impact factor: 2.143, year: 2008

  12. [Inner Ear Hearing Loss].

    Hesse, G

    2016-06-01

    Hearing loss is one of the most dominant handicaps in modern societies, which additionally very often is not realized or not admitted. About one quarter of the general population suffers from inner ear hearing loss and is therefore restricted in communicational skills. Demographic factors like increasing age play an important role as well as environmental influences and an increasing sound and noise exposure especially in leisure activities. Thus borders between a "classical" presbyacusis - if it ever existed - and envirionmentally induced hearing loss disappear. Today restrictions in hearing ability develop earlier in age but at the same time they are detected and diagnosed earlier. This paper can eventually enlighten the wide field of inner ear hearing loss only fragmentarily; therefore mainly new research, findings and developments are reviewed. The first part discusses new aspects of diagnostics of inner ear hearing loss and different etiologies. PMID:27259171

  13. Comparing Analog and Digital Hearing Aids in Reducing Hearing Disability

    Ghassem Mohammad Khani; Mohammad Hassan Khalesi; Soghrat Faghih Zadeh; Bahieh Kohansal; Zahra Jafari

    2004-01-01

    Objective: Comparing analog and digital hearing aids reducing disability caused by hearing deficiency among moderate to severe sensorineural hearing-impaired persons. Method and Material: This descriptive-analytic study was carried out on two groups of subjects participated in this study in some audiology clinics of hearing aid since May 2002 to October 2003. Twenty subjects wore analog hearing aids and twenty one subjects wore digital hearing aids. In this study , no subject had previous mid...

  14. Pre-irradiation induced emulsion co-graft polymerization of acrylonitrile and acrylic acid onto a polyethylene nonwoven fabric

    A pre-irradiation induced emulsion co-graft polymerization method was used to introduce acrylonitrile and acrylic acid onto a PE nonwoven fabric. The use of acrylic acid is meant to improve the hydrophilicity of the modified fabric. The kinetics of co-graft polymerization were studied. The existence of polyacrylonitrile (PAN) and poly(acrylic acid) (PAAc) graft chains was proven by Fourier transform infrared spectroscopy (FTIR) analysis. The existence of the nitrile groups in the graft chains indicates that they are ready for further amidoximation and adsorption of heavy metal ions. - Highlights: • Acrylonitrile and acrylic acid were co-grafted onto a PE nonwoven fabric. • Pre-irradiation induced emulsion graft polymerization technique is applied. • The existence of AAc resulted in the increased hydrophilicity of the grafted fabric

  15. Antibacterial activity of poly(vinyl alcohol)-b-poly(acrylonitrile) based micelles loaded with silver nanoparticles.

    Bryaskova, Rayna; Pencheva, Daniela; Kyulavska, Mariya; Bozukova, Dimitriya; Debuigne, Antoine; Detrembleur, Christophe

    2010-04-15

    A new amphiphilic poly(vinyl alcohol)-b-poly(acrylonitrile) (PVOH-b-PAN) copolymer obtained by selective hydrolysis of well-defined poly(vinyl acetate)-b-poly(acrylonitrile) copolymer synthesized by cobalt mediated radical polymerization was used for the preparation of PVOH-b-PAN based micelles with embedded silver nanoparticles. The successful formation of silver loaded micelles has been confirmed by UV-vis, DLS and TEM analysis and their antibacterial activity against Escherichia coli (E. coli), Staphylococcus aureus (S. aureus), Pseudomonas aeruginosa (P. aeruginosa) and spore solution of Bacillus subtilis (B. subtilis) has been studied. PVOH-b-PAN based micelles with embedded silver nanoparticles showed a strong bactericidal effect against E. coli, S. aureus and P. aeruginosa and the minimum bactericidal concentration for each system (MBC) has been determined. PMID:20074742

  16. Ion complex membranes of acrylonitrile copolymers having methacrylic acid and amphiphilic quaternized ammonium groups for uracil molecular imprinting

    Copolymers having methacrylic acid and amphiphilic quaternized ammonium groups were used for preparation of molecular imprinting membrane of uracil (URA) template. The imprinted polymeric membranes were prepared by phase inversion molecular imprinting by using poly(acrylonitrile-co-methylacrylic acid) [P(AN-co-MAA)] and poly(acrylonitrile-co-vinylbenzyl-stearyldimethylamine chloride) [P(AN-co-SMA)]. Evidence confirmed that both copolymers were mixed to form ion complex by electrostatic interaction between the methacrylic acid and the quaternized ammonium groups. The electrostatic networks of the resultant membranes made the membrane dense and useful for molecule recognition of the template. The imprinted membranes made of different mole ratio of their copolymer segments were examined in binding of URA and other analog molecules

  17. Self-Fitting Hearing Aids

    Convery, Elizabeth

    2016-01-01

    A self-contained, self-fitting hearing aid (SFHA) is a device that enables the user to perform both threshold measurements leading to a prescribed hearing aid setting and fine-tuning, without the need for audiological support or access to other equipment. The SFHA has been proposed as a potential solution to address unmet hearing health care in developing countries and remote locations in the developed world and is considered a means to lower cost and increase uptake of hearing aids in developed countries. This article reviews the status of the SFHA and the evidence for its feasibility and challenges and predicts where it is heading. Devices that can be considered partly or fully self-fitting without audiological support were identified in the direct-to-consumer market. None of these devices are considered self-contained as they require access to other hardware such as a proprietary interface, computer, smartphone, or tablet for manipulation. While there is evidence that self-administered fitting processes can provide valid and reliable results, their success relies on user-friendly device designs and interfaces and easy-to-interpret instructions. Until these issues have been sufficiently addressed, optional assistance with the self-fitting process and on-going use of SFHAs is recommended. Affordability and a sustainable delivery system remain additional challenges for the SFHA in developing countries. Future predictions include a growth in self-fitting products, with most future SFHAs consisting of earpieces that connect wirelessly with a smartphone and providers offering assistance through a telehealth infrastructure, and the integration of SFHAs into the traditional hearing health-care model. PMID:27072929

  18. Hearing Aids and Music

    Chasin, Marshall; Russo, Frank A.

    2004-01-01

    Historically, the primary concern for hearing aid design and fitting is optimization for speech inputs. However, increasingly other types of inputs are being investigated and this is certainly the case for music. Whether the hearing aid wearer is a musician or merely someone who likes to listen to music, the electronic and electro-acoustic parameters described can be optimized for music as well as for speech. That is, a hearing aid optimally set for music can be optimally set for speech, even...

  19. Synthesis and quaternization of nitroxide-terminated poly(4-vinylpyridine-co-acrylonitrile) macroinitiators and related diblock copolymers

    Poláková, Lenka; Lokaj, Jan; Holler, Petr; Starovoytova, Larisa; Pekárek, Michal; Štěpánek, Petr

    -, 065 (2010), s. 1-10. ISSN 1618-7229 R&D Projects: GA ČR GESON/06/E005; GA ČR GA203/07/0659 Institutional research plan: CEZ:AV0Z40500505 Keywords : 4-vinylpyridine-acrylonitrile copolymers * block copolymers * nitroxide-mediated radical polymerization Subject RIV: CD - Macromolecular Chemistry Impact factor: 0.574, year: 2010 http://www.e-polymers.org/journal/papers/lpolakova_240710.pdf

  20. Carboxyl-terminated butadiene-acrylonitrile-toughened epoxy/carboxyl-modified carbon nanotube nanocomposites: Thermal and mechanical properties

    H. F. Xie; Wang, Y. T.; Wang, C. S.; H. Y. Yin; Wang, L.L.; R. S. Cheng

    2012-01-01

    Carboxyl-modified multi-walled carbon nanotubes (MWCNT–COOHs) as nanofillers were incorporated into diglycidyl ether of bisphenol A (DGEBA) toughened with carboxyl-terminated butadiene-acrylonitrile (CTBN). The carboxyl functional carbon nanotubes were characterized by Fourier-transform infrared spectroscopy and thermogravimetric analysis. Furthermore, cure kinetics, glass transition temperature (Tg), mechanical properties, thermal stability and morphology of DGEBA/CTBN/MWCNT–COOH...

  1. Bone Anchored Hearing Treatment Procedure

    Full Text Available ... near-normal hearing in one ear and no functional hearing on the other side. There are several ... surgery that can leave a patient with no functional hearing on one side. And there are cases ...

  2. Hearing, Ear Infections, and Deafness

    ... Noise and Hearing Loss Prevention - National Institute for Occupational Safety and Health Infographic: Hearing Loss and Hearing Aid ... Into Health ® National Institute on Deafness and Other Communication Disorders 31 Center Drive, MSC 2320, Bethesda, MD ...

  3. Screening Newborns' Hearing Now Standard

    ... Hearing, Language, Voice, Balance Screening Newborns' Hearing Now Standard Past Issues / Fall 2013 Table of Contents Click ... the World from Spinning / Screening Newborns' Hearing Now Standard Fall 2013 Issue: Volume 8 Number 3 Page ...

  4. Age-Related Hearing Loss

    ... hearing loss. Here are the most common ones: Styles of hearing aids Source: NIH/NIDCD Hearing aids ... list of organizations, contact: NIDCD Information Clearinghouse 1 Communication Avenue Bethesda, MD 20892-3456 Toll-free Voice: ( ...

  5. Bone Anchored Hearing Treatment Procedure

    Full Text Available ... among other injuries, lost her hearing on the right side. And she has lived the last nearly 30 years without having any hearing on the right and normal hearing on the left. And as ...

  6. Noise-Induced Hearing Loss

    ... Home » Health Info » Hearing, Ear Infections, and Deafness Noise-Induced Hearing Loss On this page: What is ... I find additional information about NIHL? What is noise-induced hearing loss? Every day, we experience sound ...

  7. Hearing Conservation Live #2430

    Chochoms, Michael [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-08-09

    Occupational hearing loss is one of the most common work-related illnesses in the United States (US). From 22 to 30 million US workers are exposed to hazardous noise levels at work, and 25% of these workers will develop permanent hearing loss. Hearing loss from noise is slow and painless, and you can have a disability before you notice it. This course presents the hazards associated with workplace noise, the purpose and elements of the Los Alamos National Laboratory (LANL) Hearing Conservation Program (HCP), and controls that are available to reduce your exposure to hazardous levels of noise.

  8. International hearing protector standardization

    Poulsen, Torben

    2002-01-01

    Hearing protectors shall fulfill some minimum requirements to their performance. As hearing protector manufacturers sell the products all over the world, the testing and certification of hearing protectors has become an international issue. The ISO working group WG17 under the headlines Acoustics......, Noise, produce hearing protector standards to be used at an international level. The presentation will cover the ongoing work in WG17, including the revision of existing standards (ISO 4869-1, ISO 4869-3), upcoming new standards (ISO 4869-7) and the plans and status for future standards (performance in...

  9. Physiological modeling for hearing aid design

    Bruce, Ian C.; Young, Eric D.; Sachs, Murray B.

    2002-05-01

    Physiological data from hearing-impaired cats suggest that conventional hearing aid signal-processing schemes do not restore normal auditory-nerve responses to a vowel [Miller et al., J. Acoust. Soc. Am. 101, 3602 (1997)] and can even produce anomalous and potentially confounding patterns of activity [Schilling et al., Hear. Res. 117, 57 (1998)]. These deficits in the neural representation may account at least partially for poor speech perception in some hearing aid users. An amplification scheme has been developed that produces neural responses to a vowel more like those seen in normal cats and that reduces confounding responses [Miller et al., J. Acoust. Soc. Am. 106, 2693 (1999)]. A physiologically accurate model of the normal and impaired auditory periphery would provide simpler and quicker testing of such potential hearing aid designs. Details of such a model, based on that of Zhang et al. [J. Acoust. Soc. Am. 109, 648 (2001)], will be presented. Model predictions suggest that impairment of both outer- and inner-hair cells contribute to the degraded representation of vowels in hearing-impaired cats. The model is currently being used to develop and test a generalization of the Miller et al. speech-processing algorithm described above to running speech. [Work supported by NIDCD Grants DC00109 and DC00023.] a)Now with the Dept. of Electrical and Computer Engineering, McMaster Univ., 1280 Main St. W., Hamilton, ON L8S 4K1, Canada.

  10. Pharmacological reversal of endothelin-1 mediated constriction of the spiral modiolar artery: a potential new treatment for sudden sensorineural hearing loss

    Arnold Wolfgang

    2005-11-01

    Full Text Available Abstract Background Vasospasm of the spiral modiolar artery (SMA may cause ischemic stroke of the inner ear. Endothelin-1 (ET-1 induces a strong, long-lasting constriction of the SMA by increasing contractile apparatus Ca2+ sensitivity via Rho-kinase. We therefore tested several Rho-kinase inhibitors and a cell-permeable analogue of cAMP (dbcAMP for their ability to reverse ET-1-induced constriction and Ca2+-sensitization. Methods The present study employed SMA isolated from gerbil temporal bones. Ca2+sensitivity was evaluated by correlating vascular diameter and smooth muscle cell [Ca2+]i, measured by fluo-4-microfluorometry and videomicroscopy. Results The Rho-kinase inhibitors Y-27632, fasudil, and hydroxy-fasudil reversed ET-1-induced vasoconstriction with an IC50 of 3, 15, and 111 μmol/L, respectively. DbcAMP stimulated a dose-dependent vasodilation (Ec50 = 1 mmol/L and a reduction of [Ca2+]i (EC50 = 0.3 μmol/L of ET-1-preconstricted vessels (1 nmol/L. Fasudil and dbcAMP both reversed the ET-1-induced increase in Ca2+ sensitivity. Conclusion Rho-kinase inhibition and dbcAMP reversed ET-1-induced vasoconstriction and Ca2+-sensitization. Therefore, Rho-kinase inhibitors or cAMP modulators could possess promise as pharmacological tools for the treatment of ET-1-induced constriction, ischemic stroke and sudden hearing loss.

  11. Clusters of acrylonitrile in methanol/ethanol: A structure-spectra correlation by quantum chemical and polarized Raman study

    Graphical abstract: Ab initio and DFT calculations were performed to obtain the ground state geometry of neat acrylonitrile (C2H3C≡N, Acr), self-associated dimer, trimer and their hydrogen bonded complexes with methanol (M) and ethanol (E) in gas phase. Polarized Raman study was made for neat Acr and its binary mixtures with M/E. The ν(C≡N) line profile of neat Acr was analyzed to two component bands as free and self-associated Acr, respectively. The dephasing of the ν(C≡N) mode as a function of concentration was explained in terms of two contributions, one arising from micro viscosity dependence and the other from concentration fluctuation. Research highlights: → This paper deals with the Polarized Raman spectroscopic study of acrylonitrile and its hydrogen bonded complex with methanol and ethanol. → Quantum chemical study of molecular interactions of acrylonitrile clusters with methanol and ethanol. → Peak position and linewidth variation of ν(C≡N) stretching of acrylonitrile with concentration. → Spectra-structure correlation. - Abstract: Ab initio and DFT calculations were performed to obtain the ground state geometry of neat acrylonitrile (C2H3C≡N, Acr), self-associated dimer, trimer and their hydrogen bonded complexes with methanol (M) and ethanol (E) in gas phase. Polarized Raman study was made for neat Acr and its binary mixtures with M/E. The ν(C≡N) line profile of neat Acr was analyzed to two component bands at 2228.7 and 2226.9 cm-1 and attributed to free and self-associated Acr, respectively. The calculated ν(C≡N) mode of self-associated dimer/trimer complex and hydrogen bonded complex were compared with the experimentally observed Raman spectra. The dephasing of the ν(C≡N) mode as a function of concentration was explained in terms of two contributions, one arising from micro viscosity dependence and the other from concentration fluctuation. The viscosity dependent contribution, however, dominates over the concentration

  12. Protecting Your Hearing

    Full Text Available Narrator: Hearing -- it is an essential part of every day life. But as we grow older, we are more likely to ... they're gone, they're gone and so it's very important to protect one's hearing from exposure ...

  13. Hearing aid and Noise

    Ahmad Reza Nazeri

    1999-01-01

    Prescription of hearing aid is an extensive special category of knowledge in the field of audiology. This article is aimed at discussing the function of hearing aid and also management of patients in the noisy environments and presenting solutions to overcome problems regarding to this issue along with taking a look to the equipments prepared nowadays to cope with noisy situations.

  14. Hearing poorly with skill

    Day, Dennis

    2012-01-01

    This paper offers an account of ongoing research into hearing. I offer a characterization of 'skil- led practitioners' from an Ethnomethodological perspective. The skilled practitioner in question is a generic 'hard of hearing' person. The ambition is that such a characterization, both in its...

  15. Hereditary Hearing Loss.

    Tran, LenhAnh P.; Grundfast, Kenneth M.

    1997-01-01

    This article discusses inheritance patterns in hearing loss, epidemiology, clues to genetic causes, locating genes that cause hereditary disorders, genes related to hearing loss disorders in individuals with Usher syndrome, Waardenburg syndrome, Treacher-Collins syndrome, Branchio-oto-renal and Pendred syndromes, and the significance of finding…

  16. OI Issues: Hearing Loss

    ... that focuses on hearing loss and hearing issues. Miracle Ear Children’s Foundation P.O. Box 59261 Minneapolis, MN 55459-0261 (800) 234-5422 www.miracle-ear.com Miracle Ear Children’s Foundation provides free ...

  17. The physical and degradation properties of starch-graft-acrylonitrile/carboxylated nitrile butadiene rubber latex films.

    Misman, M A; Azura, A R; Hamid, Z A A

    2015-09-01

    Starch-graft-acrylonitrile (ANS) is compounded with carboxylated nitrile butadiene rubber (XNBR) latex. The control XNBR and the ANS/XNBR latex films were prepared through a coagulant dipping process. The films were subjected to ageing and soil burial procedures. For the biodegradation experiment, the surface of the film was assessed after the 2nd, 4th and 8th week of soil burial. The ANS, XNBR, and ANS/XNBR colloidal stability were determined with a Malvern Zetasizer. For the dipped latex films, the mechanical, morphological and thermal properties were analyzed. The addition of ANS into the XNBR latex increased the stability of the colloidal dispersions, decreased the latex film tensile strength, but increased the elongation at break due to the bipolar interaction of the ANS and XNBR particles. The ANS/XNBR latex films aged faster than the control films while the morphological analysis showed the existence of a starch crystal region and the formation of microbial colonies on the surfaces of the films. Based on the TGA-DTA curves, a higher ΔT was observed for the ANS/XNBR latex films signifying high thermal energy needed for the film to thermally degrade. PMID:26005134

  18. Regenerated thermosetting styrene-co-acrylonitrile sandwich composite panels reinforced by jute fibre: structures and properties

    Jinglong Li; Qin Peng; Anrong Zeng; Junlin Li; Xiaole Wu; Xiaofei Liu

    2016-02-01

    Jute fibres-reinforced sandwich regenerated composite panels were fabricated using industrial waste thermosetting styrene-co-acrylonitrile (SAN) foam scraps via compression moulding for the purpose of recycling waste SAN foam and obtaining high physical performance. The jute fibres were, respectively, treated by heat, sodium hydroxide (NaOH) solution (5.0 wt%), and N,N-dimethylacetamide (DMAc) in order to improve the mechanical properties of the composites. The structures and mechanical properties of the composites were studied. The SAN matrix got compact and some crystalline region formed in SAN matrix via compression moulding. The composite reinforced by DMAc-treated jute fibres performed optimum mechanical properties among the regenerated panels whose impact strength, flexural strength, and compressive strength were 19.9 kJ m−2, 41.7 MPa, and 61.0 MPa, respectively. Good interfacial bonding between DMAc-treated fibres and SAN matrix was verified by peel test and exhibited in SEM photographs. Besides, the water absorption of DMAc-treated fibres composite was lower than other SAN/jute fibre-reinforced sandwich composite panels.

  19. Covalent Immobilization of Lipase on Poly ( acrylonitrile-co-maleic acid) Ultrafiltration Hollow Fiber Membrane

    YE Peng; XU Zhi-kang; WU Jian; DENG Hong-tao; SETA Patrick

    2005-01-01

    Lipase from Candida rugosa was covalently immobilized on the surface of an ultrafiltration hollow fiber membrane fabricated from poly (acrylonitrile-co-maleic acid) (PANCMA) in which the carboxyl groups were activated with 1-ethyl-3-(dimethylaminopropyl) carbodiimide hydrochloride (EDC) and dicyclohexyl carbodiimide (DCC)/N-hydroxyl succinimide(NHS), respectively. The properties of the immobilized lipase were assayed and compared with those of the free enzyme. The maximum activities were observed in a relatively broader pH value range at high temperatures for the immobilized lipase compared to the free one. It was also found that the thermal and pH stabilities of lipase were improved upon immobilization and at 50 ℃ the thermal inactivation rate constant values are 2.1×10-2 for the free lipase, 3.2×10-3 for the immobilized lipase on the EDC-activated PANCMA membrane and 3.5×10-3 for the immobilized lipase on the DCC/NHS-activated PANCMA membrane, respectively.

  20. Method for the separation of high impact polystyrene (HIPS) and acrylonitrile butadiene styrene (ABS) plastics

    Jody, Bassam J.; Arman, Bayram; Karvelas, Dimitrios E.; Pomykala, Jr., Joseph A.; Daniels, Edward J.

    1997-01-01

    An improved method is provided for separating acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) plastics from each other. The ABS and HIPS plastics are shredded to provide a selected particle size. The shredded particles of the ABS and HIPS plastics are applied to a solution having a solution density in a predefined range between 1.055 gm/cm.sup.3 and 1.07 gm/cm.sup.3, a predefined surface tension in a range between 22 dynes/cm to 40 dynes/cm and a pH in the range of 1.77 and 2.05. In accordance with a feature of the invention, the novel method is provided for separating ABS and HIPS, two solid thermoplastics which have similar densities by selectively modifying the effective density of the HIPS using a binary solution with the appropriate properties, such as pH, density and surface tension, such as a solution of acetic acid and water or a quaternary solution having the appropriate density, surface tension, and pH.

  1. Preparation and evaluation of some investigated natural and acrylonitrile rubber vulcanizations for physiotherapeutic purposes

    A trial was made to design and prepare rubber article that can be used to reactivate, strengthen and reinforce the hand muscles and fingers which had suffered from trouble movement.The investigated rubber article was prepared from natural and acrylonitrile rubber formulations. These formulations were processed in the form of compounds which contain significant quantities of fillers as Hisil, CaCO3 and TiO2.The rheological characteristics and physicochemical properties of the vulcanizations were determined according to standard tests. It was found that it is possible to prepare the designated rubber article for the desired purpose. The test results show that the prepared rubber article has a good chemical resistant against acid, alkali, and salt. Also it possesses high resistance to deterioration and deformation. The prepared article has an ability to retain its elastic property after the action of compressive forces at 70 degree C for 24 hours.This was conformed with applied commercial hand exercise therapeutic article

  2. Optical properties of polycarbonate/styrene-co-acrylonitrile blends: effects of molecular weight of the matrix.

    Yi, Ping; Xiong, Ying; Guo, Shaoyun

    2015-12-01

    In this paper, the effects of the molecular weight of a polycarbonate (PC) matrix on the phase morphology and optical properties of a PC/styrene-co-acrylonitrile (SAN) blend were investigated. A scanning electron microscope is used to analyze the phase morphology of the blends, and Mie scattering theory is used to analyze the changing laws of the optical properties of PC/SAN blends with the increasing of PC molecular weight. Results show that the average particle diameter is not strongly changed with different PC molecular weight because the values of the viscosity ratios are very close to each other. But it is obvious that the number of large particles gradually reduced while small particles (especially dmolecular weight. And the increase in small particles will result in an increase in backward scattering so the transmittance of PC/SAN blends decreases with the increase of PC molecular weight. However, the balance of the scattering coefficients and the number concentration of particles eventually lead to the haze of the blends being very close, despite having different PC molecular weights. Meanwhile, the photographs of scattering patterns indicate that the PC/SAN blends whose component weight ratios are fixed at 70:30 have excellent antiglare properties, despite the changes in molecular weight of the PC matrix. PMID:26836652

  3. An investigation on chloroprene-compatibilized acrylonitrile butadiene rubber/high density polyethylene blends

    Khalil Ahmed

    2015-11-01

    Full Text Available Blends of acrylonitrile butadiene rubber/high density polyethylene (NBR/HDPE compatibilized by Chloroprene rubber (CR were prepared. A fixed quantity of industrial waste such as marble waste (MW, 40 phr was also included. The effect of the blend ratio and CR on cure characteristics, mechanical and swelling properties of MW-filled NBR/HDPE blends was investigated. The results showed that the MW-filled NBR/HDPE blends revealed an increase in tensile strength, tear, modulus, hardness and cross-link density for increasing weight ratio of HDPE. The minimum torque (ML and maximum torque (MH of blends increased with increasing weight ratio of HDPE while scorch time (ts2 cure time (tc90, compression set and abrasion loss of blends decreased with increasing weight ratio of HDPE. The blends also showed a continuous reduction in elongation at break as well as swelling coefficient with increasing HDPE amount in blends. MW filled blends based on CR provided the most encouraging balance values of overall properties.

  4. Microstrueture and Properties of Fluoroelastomer/Butadiene-Acrylonitrile Rubber Interpenetrating Polymer Networks

    CHEN Chunming; XIONG Chuanxi; YANG Jian; DONG Lijie

    2008-01-01

    Interpenetrating polymer networks(IPNs)based on fluoroelastomer/butadiene-acrylonitrile rubber(FKM/NBR)by molten blending at a high temperature and chemical cross-linking of two components were prepared.The influence of the two networks component on the mechanical properties and thermostabilities was studied.The experimental results show that the mechanical properties of the IPNs are superior to those of the individual FKM and NBR networks due to forming the case of interpenetrating and intercross-linking between the two networks,the mechanical properties and thermal resistance exhibit higher values when 80/20(w/w)FKM and NBR is blended and respectively cured simultaneously.The co-continuous morphology of the IPNs in the blends of 80/20(w/w)FKM/NBR is found by transmission electron microscopy(TEM),the differential scanning calorimetry(DSC)determination shows that the blends of 80/20(w/w)FKM/NBR have better compatibility,and the glass transition temperature of the elastomer is -21.5℃.

  5. Latex stage blending of multiwalled carbon nanotube in carboxylated acrylonitrile butadiene rubber: Mechanical and electrical properties

    Highlights: ► MWCNT can act as a reinforcing filler in XNBR at very low concentration. ► SEM and XRD analysis confirm uniform distribution of nanotube in the matrix. ► Mechanical properties showed considerable improvement. ► Thermal stability of the composite is marginally improved. -- Abstract: Multiwalled carbon nanotube (MWCNT) was dispersed in sodium dodecyl benzene sulphonate (SDBS) by sonication. The dispersed MWCNT (0.05–0.3 gm) was incorporated in carboxylated acrylonitrile butadiene rubber (XNBR) latex. Mechanical, electrical and thermal properties of these composites were studied. Mechanical properties of the composites increased up to an optimum concentration and then decreased. Dielectric properties of the composites were studied in the S band (frequency range 2–4 GHz) by Cavity Perturbation method. Direct current (DC) electrical conductivity shows a percolation behaviour and conductivity increased by about 10 orders of magnitude. Thermal studies were conducted using Differential Scanning Calorimetry (DSC) and Thermo Gravimetric Analysis (TGA). As expected with the very small concentration of multiwalled carbon nanotube, glass transition temperature (Tg) and thermal stability of the composite showed a marginal increase. Composites were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Scanning electron microscope (SEM) analysis.

  6. Peroxydisulfate initiated synthesis of potato starch-graft-poly(acrylonitrile under microwave irradiation

    2007-01-01

    Full Text Available Potato starch-graft-poly(acrylonitrile could be efficiently synthesized using small concentration of ammonium peroxydisulfate (0.0014M in aqueous medium under microwave irradiation. A representative microwave synthesized graft copolymer was characterized using Fourier Transform Infrared Spectroscopy, X-ray Diffraction, Scanning Electron Microscopy and Thermogravimetric Analysis. Under microwave conditions oxygen removal from the reaction vessel was not required and the graft copolymer was obtained in high yield using very small amount of ammonium peroxydisulfate, however using the same amount of ammonium peroxydisulfate (0.0014M on thermostatic water bath no grafting was observed up to 98°C (even in inert atmosphere. Raising the concentration of the initiator to 0.24 M resulted into 10% grafting at 50 °C but in inert atmosphere.The viscosity/shear stability of the grafted starch (aqueous solution and water/saline retention ability of the microwave synthesized graft copolymer were also studied and compared with that of the native potato starch.

  7. Preirradiation grafting of acrylonitrile onto polypropylene monofilament for biomedical applications: I. Influence of synthesis conditions

    Graft polymerization of acrylonitrile onto polypropylene (PP) monofilament was carried out by a preirradiation method using a 6Co gamma radiation source. The influence of synthesis conditions, such as preirradiation dose, reaction time, monomer concentration, reaction temperature and additives was determined. The grafting was considerably influenced by the instantaneous swelling of the monofilament in the reaction mixture during the course of the grafting process. The order of dependence of the rate of grafting on monomer concentration was found to be 1.04. The nature of the medium of the grafting and the additives had profound influence over the grafting reaction. The accelerative effects of solvent medium on the grafting were higher in methylethyl ketone (MEK) and dimethylformamide (DMF) as compared to methanol. At the same time, partial replacement of DMF with water led to acceleration in the grafting with peak maxima at 20% solvent composition. The addition of a small amount of sulfuric acid to the reaction mixture also resulted in a significant acceleration of the degree of grafting

  8. Nanostructured synthetic carbons obtained by pyrolysis of spherical acrylonitrile/divinylbenzene copolymers.

    Danish J Malik

    Full Text Available Novel carbon materials have been prepared by the carbonization of acrylonitrile (AN/divinylbenzene (DVB suspension porous copolymers having nominal crosslinking degrees in the range of 30-70% and obtained in the presence of various amounts of porogens. The carbons were obtained by pre-oxidation of AN/DVB copolymers at 250-350°C in air followed by pyrolysis at 850°C in an N(2 atmosphere. Both processes were carried out in one furnace and the resulting material needed no further activation. Resulting materials were characterized by XPS and low temperature nitrogen adsorption/desorption. It was found that maximum pyrolysis yield was ca. 50% depending on the oxidation conditions but almost independent of the crosslinking degree of the polymers. Porous structure of the carbons was characterized for the presence of micropores and macropores, when obtained from highly crosslinked polymers or polymers oxidized at 350°C and meso- and macropores in all other cases. The latter pores are prevailing in the structure of carbons obtained from less porous AN/DVB resins. Specific surface area (BET of polymer derived carbons can vary between 440 m(2/g and 250 m(2/g depending on the amount of porogen used in the synthesis of the AN/DVB polymeric precursors.

  9. AGET ATRP of acrylonitrile with ionic liquids as reaction medium without any additional ligand

    Atom transfer radical polymerization using activators generated by electron transfer (AGET ATRP) of acrylonitrile (AN) was carried out for the first time in 1-methylimidazolium acetate ([mim][AT]), 1-methylimidazolium propionate([mim][PT]), and 1-methylimidazolium butyrate ([mim][BT]), respectively. The polymerization was approached by using ascorbic acid (VC) as a reducing agent, ethyl 2-bromoisobutyrate (EBiB) as initiator, only FeBr3 as catalyst without any additional ligand. Kinetic studies showed that both AGET ATRP of AN in the absence of oxygen and in the presence of air proceeded in a well-controlled manner. Under the same conditions, the polymerization in the presence of air provided rather slower reaction rate and showed better control of molecular weight and its distribution than in the absence of oxygen. The sequence of the apparent polymerization rate constants of AGET ATRP of AN in three ionic liquids was kapp([mim][AT]) > kapp([mim][PT]) > kapp([mim][BT]). The living nature of the polymerization was confirmed by chain end analysis and block copolymerization of methyl methacrylate with polyacrylonitrile as macroinitiator. All the three ionic liquids and FeBr3 could be recycled and reused and had no effect on the living nature of polymerization.

  10. Zinc chelates as new activators for sulphur vulcanization of acrylonitrile-butadiene elastomer

    2009-04-01

    Full Text Available The goal of this work was to apply several zinc chelates as activators for sulphur vulcanization of acrylonitrilebutadiene elastomer (NBR, in order to find alternatives for the conventionally used zinc oxide. In this article, we discuss the effects of different zinc complexes on the cure characteristics, crosslinks distribution in the elastomer network and mechanical properties of acrylonitrile-butadiene rubber. Zinc chelates seem to be good substitutes for zinc oxide as activators for sulphur vulcanization of NBR rubber, without detrimental effects on the crosslinking process and physical properties of the obtained vulcanizates. Moreover, application of zinc complexes allows to reduce the amount of zinc ions in rubber compounds by 40% compared to conventionally crosslinked vulcanizates with zinc oxide. It is a very important ecological goal since zinc oxide is classified as toxic to aquatic species and its amount in rubber products must be reduced below 2.5% at least. From a technological point of view it is a very important challenge.

  11. Kinetic studies of uranyl ion adsorption on acrylonitrile (AN) / polyethylene glycol (PEG) interpenetrating networks (IPN)

    The kinetics of the adsorption of uranyl ions on amidoximated acrylonitrile (AN)/ polyethylene glycol (PEG) interpenetrating network (IPNs) from aqueous solutions was studied as a function of time and temperature. Adsorption analyses were performed for definite uranyl ion concentrations of 1x10-2M and at four different temperatures as 290K, 298K, 308K and 318K. Adsorption time was increased from zero to 48 hours. Adsorption capacities of uranyl ions by PEG/AN IPNS were determined by gamma spectrometer. The results indicate that adsorption capacity increases linearly with increasing temperature. The max adsorption capacity was found as 602 mgu/g IPN at 308K. Adsorption rate was evaluated from the curve plotted of adsorption capacity versus time, for each temperature. Rate constants for uranyl ions adsorption on amidoximated ipns were calculated for 290K, 298K, 308K and 318K at the solution concentration of 1x10-2M . The results showed that as the temperature increases the rate constant increases exponentially too. The mean activation energy of uranyl ions adsorption was found as 34.6 kJ/mole by using arrhenius equation. (author)

  12. Study of the Effect of Grafted Antioxidant on the Acrylonitrile-Butadiene Copolymer Properties

    Abdulaziz Ibrahim Al-Ghonamy

    2010-01-01

    Full Text Available The grafting of ADPEA onto natural rubber was executed with UV radiation. Benzoyl peroxide was used to initiate the free-radical grafting copolymerization. Natural rubber-graft-N-(4-aminodiphenylether acrylamide (NR-g-ADPEA was characterized with an IR technique. The paper aims interested to determine the crosslinking density by using the ultrasonic technique. The ultrasonic velocities of both longitudinal and shear waves were measured in thermoplastic discs of NBR vulcanizates as a function of aging time. Ultrasonic velocity measurements were taken at 2 MHz ultrasonic frequency using the pulse echo method. We studied the effect of aging on the mechanical properties, crosslinking density, and the swelling and extraction phenomena for acrylonitrile-butadiene copolymer (NBR vulcanizates, which contained the prepared NR-g-ADPEA and a commercial antioxidant, N-isopropyl-N−-phenyl-p-phenylenediamine. The prepared antioxidant enhanced both the mechanical properties of the NBR vulcanizates and the permanence of the ingredients in these vulcanizates.

  13. Crack initiation and propagation on the polymeric material ABS (Acrylonitrile Butadiene Styrene, under ultrasonic fatigue testing

    G. M. Domínguez Almaraz

    2015-10-01

    Full Text Available Crack initiation and propagation have been investigated on the polymeric material ABS (Acrylonitrile Butadiene Styrene, under ultrasonic fatigue testing. Three controlled actions were implemented in order to carry out fatigue tests at very high frequency on this material of low thermal conductivity, they are: a The applying load was low to limit heat dissipation at the specimen neck section, b The dimensions of testing specimen were small (but fitting the resonance condition, in order to restraint the temperature gradient at the specimen narrow section, c Temperature at the specimen neck section was restrained by immersion in water or oil during ultrasonic fatigue testing. Experimental results are discussed on the basis of thermo-mechanical behaviour: the tail phenomenon at the initial stage of fatigue, initial shear yielding deformation, crazed development on the later stage, plastic strain on the fracture surface and the transition from low to high crack growth rate. In addition, a numerical analysis is developed to evaluate the J integral of energy dissipation and the stress intensity factor K, with the crack length

  14. Carbon nanotube buckypaper reinforced acrylonitrile-butadiene-styrene composites for electronic applications.

    Díez-Pascual, Ana M; Gascón, David

    2013-11-27

    Novel acrylonitrile-butadiene-styrene (ABS) nanocomposites reinforced with pristine or functionalized single- or multiwalled carbon nanotube buckypaper (BP) sheets were manufactured via hot-compression and vacuum infiltration. Their morphology, thermal, mechanical, and electrical properties were comparatively investigated. Scanning electron microscopy and thermogravimetric analysis showed that the infiltration process leads to better BP impregnation than the hot-press technique. BPs made from functionalized or short nanotubes form compact networks that hamper the penetration of the matrix chains, whereas those composed of pristine tubes possess large pores that facilitate the polymer flow, resulting in composites with low degree of porosity and improved mechanical performance. Enhanced thermal and electrical properties are found for samples incorporating functionalized BPs since dense networks lead to more conductive pathways, and a stronger barrier effect to the diffusion of degradation products, thus better thermal stability. According to dynamic mechanical analysis these composites exhibit the highest glass transition temperatures, suggesting enhanced filler-matrix interactions as corroborated by the Raman spectra. The results presented herein demonstrate that the composite performance can be tailored by controlling the BP architecture and offer useful insights into the structure-property relationships of these materials to be used in electronic applications, particularly for EMI shielding and packaging of integrated circuits. PMID:24171494

  15. Modification of dicyanate ester resin by liquid carboxyl-terminated butadiene acrylonitrile copolymer

    Bisphenol A dicyanate ester (BADCy) was modified with liquid carboxyl-terminated butadiene acrylonitrile (LCTBN). The cured BADCy resin was formed through the cyclotrimerization of cyanate functional groups into triazine rings, and there was the chemical reaction between BADCy and LCTBN. Mechanical performance indicated that the introduction of LCTBN into BADCy resin improved the impact strength with maintenance in flexural strength. Scanning electron microscopy (SEM) showed that the pure resin had a smooth glassy fracture surface, whereas cured blends containing LCTBN showed rougher fracture surfaces, and exhibited enhanced impact resistance. The TEM observation showed that the two phases in the cured resins exhibit a good interaction adhesion. Thermograms of BADCy modified with LCTBN showed the little reduction of heat deflection temperature, and a reduction in thermal stability temperature by 30 K. Dynamic mechanical analysis (DMA) showed that the pure BADCy had higher storage modulus (E') values than that of the BADCy modified with LCTBN, whereas the loss modulus (E'') was lower, and that the glass transition temperature (Tg) of modified BADCy was 229 deg. C and lower than that (249 deg. C) of pure BADCy resin.

  16. AGET ATRP of acrylonitrile with ionic liquids as reaction medium without any additional ligand

    Chen Hou, E-mail: lduchenhou@hotmail.com [School of Chemistry and Materials Science, Ludong University, Yantai 264025 (China); Liang Ying; Liu Delong; Tan Zhi; Zhang Shaohong; Zheng Meiling; Qu Rongjun [School of Chemistry and Materials Science, Ludong University, Yantai 264025 (China)

    2010-05-10

    Atom transfer radical polymerization using activators generated by electron transfer (AGET ATRP) of acrylonitrile (AN) was carried out for the first time in 1-methylimidazolium acetate ([mim][AT]), 1-methylimidazolium propionate([mim][PT]), and 1-methylimidazolium butyrate ([mim][BT]), respectively. The polymerization was approached by using ascorbic acid (VC) as a reducing agent, ethyl 2-bromoisobutyrate (EBiB) as initiator, only FeBr{sub 3} as catalyst without any additional ligand. Kinetic studies showed that both AGET ATRP of AN in the absence of oxygen and in the presence of air proceeded in a well-controlled manner. Under the same conditions, the polymerization in the presence of air provided rather slower reaction rate and showed better control of molecular weight and its distribution than in the absence of oxygen. The sequence of the apparent polymerization rate constants of AGET ATRP of AN in three ionic liquids was k{sub app}([mim][AT]) > k{sub app}([mim][PT]) > k{sub app}([mim][BT]). The living nature of the polymerization was confirmed by chain end analysis and block copolymerization of methyl methacrylate with polyacrylonitrile as macroinitiator. All the three ionic liquids and FeBr{sub 3} could be recycled and reused and had no effect on the living nature of polymerization.

  17. Microwave absorption properties of lightweight absorber based on Fe50Ni50-coated poly(acrylonitrile) microspheres and reduced graphene oxide composites

    Zhang, Bin; Wang, Jun; Wang, Junpeng; Huo, Siqi; Zhang, Bin; Tang, Yushan

    2016-09-01

    In this paper, we proposed a facile method to obtain the lightweight composites consisting of surface modified Fe50Ni50-coated poly(acrylonitrile) microspheres (PANS@SMF), reduced graphene oxide (RGO) and epoxy resin. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometry (VSM) and vector network analyzer (VNA). Impedance matching condition and electromagnetic wave attenuation characteristic were used for the reflection loss (RL) performance of the composites. Compared with pure PANS@SMF and RGO composites, the -10 dB absorption bandwidth and the minimum RL of the hybrid composites were enhanced. The bandwidth less than -10 dB was almost 4.5 GHz in the range of 10 GHz to 14.5 GHz, with a matching thickness of 2.5 mm. The density of the hybrid composites was in the range of 0.25-0.34 g/cm3. Therefore, the hybrid composite can be considered as a potential lightweight microwave absorber.

  18. Is All Human Hearing Cochlear?

    Seyede Faranak Emami

    2013-01-01

    Full Text Available The objective of this cross-sectional study was to investigate the possibility that the saccule may contribute to human hearing. The forty participants included twenty healthy people and twenty other subjects selected from patients who presented with benign paroxysmal positional vertigo to Audiology Department of Hazrat Rasoul Akram hospital (Tehran, Iran. Assessments comprised of audiological evaluations, cervical vestibular evoked myogenic potentials (cVEMPs, recognition of spoken phonemes in white noise (Rsp in wn, and auditory brainstem response to 500 Hz tone burst (ABR500 HZ. Twenty affected ears with decreased vestibular excitability as detected by abnormal cVEMPs revealed decreased scores of Rsp in wn and abnormal findings of ABR500 HZ. Both unaffected and normal ears had normal results. Multiple comparisons of mean values of cVEMPs and ABR500 HZ between three groups were significant (P<0.05, ANOVA. The correlation between RSP in wn and p13 latencies was significant. The peak-to-peak amplitudes showed significant correlation to RSP in wn. The correlation between RSP in wn and the latencies of n23 was significant. In high-level of noisy competing situations, healthy human saccular sensation can mediate the detection of low frequencies and possibly help in cochlear hearing for frequency and intensity discrimination. So, all human hearing is not cochlear.

  19. Sensitivity in Interactions between Hearing Mothers and their Toddlers with Hearing Loss: The Effect of Cochlear Implantation

    Bakar, Zaharah Abu; Brown, P. Margaret; Remine, Maria D.

    2010-01-01

    This study investigated the potential effects of cochlear implantation and age at implantation on maternal interactional sensitivity. Three groups of dyads were studied at two points over 1 year. The hearing aid (HA) group wore hearing aids throughout the study, the early cochlear implanted (ECI) group were implanted prior to 22 months of age, and…

  20. Micromechanics of hearing

    Hudspeth, A. J.

    2015-12-01

    The following summarizes the key points addressed during a tutorial session on the Micromechanics of Hearing that took place at the 12th International Workshop on the Mechanics of Hearing held at Cape Sounio, Greece, in June 2014. The tutorial was intended to present an overview of basic ideas and to address topics of current interest relevant to the Workshop. The session was recorded, and the audio file and accompanying visual content of the presentation can be found in the Mechanics of Hearing Digital Library (www.mechanicsofhearing.org).

  1. Hearing Aid Personalization

    Nielsen, Jens Brehm; Nielsen, Jakob; Jensen, Bjørn Sand;

    2013-01-01

    Modern digital hearing aids require and offer a great level of personalization. Today, this personalization is not performed based directly on what the user actually perceives, but on a hearing-care professional’s interpretation of what the user explains about what is perceived. In this paper, an...... interactive personalization system based on Gaussian process regression and active learning is proposed, which personalize the hearing aids based directly on what the user perceives. Preliminary results demonstrate a significant difference between a truly personalized setting obtained with the proposed system...

  2. Treating hearing disorders with cell and gene therapy

    Gillespie, Lisa N.; Richardson, Rachael T.; Nayagam, Bryony A.; Wise, Andrew K.

    2014-12-01

    Hearing loss is an increasing problem for a substantial number of people and, with an aging population, the incidence and severity of hearing loss will become more significant over time. There are very few therapies currently available to treat hearing loss, and so the development of new therapeutic strategies for hearing impaired individuals is of paramount importance to address this unmet clinical need. Most forms of hearing loss are progressive in nature and therefore an opportunity exists to develop novel therapeutic approaches to slow or halt hearing loss progression, or even repair or replace lost hearing function. Numerous emerging technologies have potential as therapeutic options. This paper details the potential of cell- and gene-based therapies to provide therapeutic agents to protect sensory and neural cells from various insults known to cause hearing loss; explores the potential of replacing lost sensory and nerve cells using gene and stem cell therapy; and describes the considerations for clinical translation and the challenges that need to be overcome.

  3. 国内外丙烯腈供需现状和发展趋势%Global Supply & Demand Situation and Developing Trend of Acrylonitrile

    吴宇红

    2012-01-01

    介绍了丙烯腈的国内外供需现状,分析了未来丙烯腈装置的投资计划及下游应用领域的需求情况,并预测了未来丙烯腈供需状况。估计到2015年全球丙烯腈产能将出现过剩,投资还需谨慎。%The global supply and demand situation of acrylinitrile was introduced.Based on anaysis of acrylinitrile plant investment plans and demand situation of downstream application filelds,the supply and demand situation of acrylonitrile in the future was predicted.It is predicted that global acrylonitrile capability would be surplus by 2015,so investment on acrylonitrile needs discretion.

  4. Occupational hearing loss

    ... music can cause hearing loss. Sounds above 80 decibels (dB, a measurement of the loudness or strength ... is allowed. Both the length of exposure and decibel level are considered. If the sound is at ...

  5. Protecting Your Hearing

    Full Text Available ... hearing from exposure to any loud noise. Narrator: People are exposed to loud noises every day. In the home, on the streets, in public places -- noise is everywhere. But how ...

  6. Buying a Hearing Aid

    ... Treatments & Cures Buying a Hearing Aid Cancer Treatment Scams Cancer Treatment Scams CURE-ious Bookmark Direct-to-Consumer Genetic Tests ... Money Privacy, Identity & Online Security Blog Video & Media Scam Alerts Get health and fitness updates by email ...

  7. Protecting Your Hearing

    Full Text Available ... it is an essential part of every day life. But as we grow older, we are more ... hearing problem, you can continue participating fully in life, while enjoying some of its most important sounds.

  8. What's Hearing Loss?

    ... cochlea during an operation. It takes over the job of the damaged or destroyed hair cells in the ... and Communicating A kid with hearing loss may attend a special school, special classes within ...

  9. Protecting Your Hearing

    Full Text Available ... Hearing -- it is an essential part of every day life. But as we grow older, we are ... Narrator: People are exposed to loud noises every day. In the home, on the streets, in public ...

  10. Protecting Your Hearing

    Full Text Available ... is a structure called the cochlea. The cochlea has little cells called hair cells because they have ... But how do you know if loud noise has affected your hearing? A. Julianna Gulya, M.D.: ...

  11. Hearing Conservation Team

    Federal Laboratory Consortium — The Hearing Conservation Team focuses on ways to identify the early stages of noise-induced damage to the human ear. Our current research involves the evaluation of...

  12. Dynamic and kinetic aspects of the adsorption of acrylonitrile on Si(001)-2x1

    Using scanning tunnelling microscopy (STM), photoelectron and photoabsorption spectroscopies, we have examined how acrylonitrile (H2C=CH-C≡N) reacts with the Si(001)-2x1 surface for coverages ranging from ∼1012 molecules/cm2 to ∼1014 molecules/cm2. At 300 K, in the very low coverage regime (below 1013 molecules/cm2), filled- and empty-state STM images show that the molecule bridges, via its β carbon and nitrogen ends, two silicon dangling bonds, across the trench separating two dimer rows. A cumulative-double-bond unit (C=C=N) is formed. The 300 K STM image results from the dynamic flipping of the molecule between two equivalent equilibrium positions, which can be seen when the molecular motion is slowed down at 80 K. For coverages larger than 1013 molecules/cm2, for which STM does not show ordered adsorption any more, the adsorption kinetics were observed in real-time using valence band photoemission and resonant Auger yield, associated with N 1s x-ray absorption spectroscopy (NEXAFS). At 300 K, these techniques point to a situation more complex than the one explored by STM at very low coverage. Three species (cyano-bonded, vinyl-bonded, and cumulative-double-bond species) are detected. Their distribution does not vary with increasing coverage. All dimerization-related surface states are quenched at saturation. The uptake rates versus coverage relationship points to the presence of a mobile precursor. Finally, the paper discusses a possible mechanism leading to the formation of cross-trench C=C=N unit at low coverage, and the reasons why the product branching ratio changes with increasing coverage

  13. Nanofibrous poly(acrylonitrile-co-maleic acid) membranes functionalized with gelatin and chitosan for lipase immobilization.

    Ye, Peng; Xu, Zhi-Kang; Wu, Jian; Innocent, Christophe; Seta, Patrick

    2006-08-01

    Nanofibrous membranes with an average diameter of 100 and 180 nm were fabricated from poly(acrylonitrile-co-maleic acid) (PANCMA) by the electrospinning process. These nanofibrous membranes contain reactive groups which can be used to covalently immobilize biomacromolecules. Two natural macromolecules, chitosan and gelatin, were tethered on these nanofibrous membranes to fabricate dual-layer biomimetic supports for enzyme immobilization in the presence of 1-ethyl-3-(dimethyl-aminopropyl) carbodiimide hydrochloride (EDC)/N-hydroxyl succinimide (NHS). Lipase from Candida rugosa was then immobilized on these dual-layer biomimetic supports using glutaraldehyde (GA), and on the nascent PANCMA fibrous membrane using EDC/NHS as coupling agent, respectively. The properties of the immobilized lipases were assayed. It was found that there is an increase of the activity retention of the immobilized lipase on the chitosan-modified nanofibrous membrane (45.6+/-1.8%) and on the gelatin-modified one (49.7+/-1.8%), compared to that on the nascent one (37.6+/-1.8%). The kinetic parameters of the free and immobilized lipases, K(m) and V(max), were also assayed. In comparison with the immobilized lipase on the nascent nanofibrous membrane, there is an increase of the V(max) value for the immobilized lipases on the chitosan- and gelatin-modified nanofibrous membranes. Results also indicate that the pH and thermal stabilities of lipases increase upon immobilization. The residual activities of the immobilized lipases are 55% on the chitosan-modified nanofibrous membrane and 60% on the gelatin-modified one, after 10 uses. PMID:16584770

  14. Chitosan-tethered poly(acrylonitrile-co-maleic acid) hollow fiber membrane for lipase immobilization.

    Ye, Peng; Xu, Zhi-Kang; Che, Ai-Fu; Wu, Jian; Seta, Patrick

    2005-11-01

    A protocol was used to prepare a dual-layer biomimetic membrane as support for enzyme immobilization by tethering chitosan on the surface of poly(acrylonitrile-co-maleic acid) (PANCMA) ultrafiltration hollow fiber membrane in the presence of 1-ethyl-3-(dimethylaminopropyl) carbodiimide hydrochloride (EDC)/N-hydroxylsuccin-imide (NHS). The chemical change of the chitosan-modified PANCMA membrane surface was confirmed with Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Lipase from Candida rugosa was immobilized on this dual-layer biomimetic membrane using glutaraldehyde (GA), and on the nascent PANCMA membrane using EDC/NHS as coupling agent. The properties of the immobilized enzymes were assayed and compared with those of the free one. It was found that both the activity retention of the immobilized lipase and the amount of bound protein on the dual-layer biomimetic membrane (44.5% and 66.5 mg/m2) were higher than those on the nascent PANCMA membrane (33.9% and 53.7 mg/m2). The kinetic parameters of the free and immobilized lipases, Km and Vmax, were also assayed. The Km values were similar for the immobilized lipases, while the Vmax value of the immobilized lipase on the dual-layer biomimetic membrane was higher than that on the nascent PANCMA membrane. Results indicated that the pH and thermal stabilities of lipase increased upon immobilization. The residual activity of the immobilized lipase after 10 uses was 53% on the dual-layer biomimetic membrane and 62% on the nascent PANCMA membrane. PMID:15919112

  15. Microporous poly(acrylonitrile-methyl methacrylate) membrane as a separator of rechargeable lithium battery

    We studied microporous poly(acrylonitrile-methyl methacrylate), AMMA, membrane as the separator of Li/LiMn2O4 cell. The porous AMMA membrane was prepared by the phase inversion method with N,N-dimethylformamide (DMF) as the solvent and water as the non-solvent. We observed that morphology of the resulting membrane was strongly affected by the concentration of polymer solution: low concentration produced finger-like pores with dense skin on two surfaces of the membrane, while high concentration yielded open voids with dense layer on the other surface of the membrane. Regardless of their morphology, both membranes could be rapidly wetted by the liquid electrolyte (1.0 m LiBF4 dissolved in 1:3 wt.% mixture of ethylene carbonate (EC) and γ-butyrolactone (GBL)), and could be swollen at elevated temperatures, which resulted in the formation of a microporous gel electrolyte (MGE). It was shown that the resulting MGE not only had high ionic conductivity and but also had good compatibility with metal lithium even at 60 deg. C. Cyclic voltammetric test showed that the MGE had an electrochemical window of 4.9 V versus Li+/Li. At room temperature, the Li/MGE/LiMn2O4 cell showed excellent cycliability with a specific capacity of 121-125 mA h g-1 LiMn2O4. It was shown that even at 60 deg. C good mechanical strength of the MGE remained. Therefore, the MGE is suitable for the application of battery separator at elevated temperatures

  16. Pre-irradiation grafting of acrylonitrile onto chitin for adsorption of arsenic in water

    Radiation-induced grafting is an effective technique for preparation of novel materials. In this study, partially deacetylated chitin with deacetylation degree (DDA) of about 40% was graft-copolymerized with acrylonitrile (AN) by a γ-ray pre-irradiation method. The maximal grafting degree of AN onto pre-irradiated chitin at 25±1.2 kGy was 114% for AN concentration in dimethylformamide of 40% (v/v) at 70 °C for 8 h. The mixture ratio of 0.1 N NH2OH·HCl to 0.1 N NaOH was selected to be 7:3 (v/v) for amidoxime conversion of cyano-groups on grafted chitin (Chi-g-AN). The characteristics of modified chitin were depicted by the FT-IR spectra, BET area and SEM images. Adsorption equilibrium of As(III) onto Chi-g-AN converted amidoxime (Chi-g-AN-C) fits with the Langmuir model and the maximal adsorption capacity was 19.724 mg/g. The break-through times of As(III) on Chi-g-AN-C in column adsorption experiments increased with the increase in bed depths. - Highlights: • Partially deacetylated chitin was used for grafting AN by pre-irradiation. • The maximal grafting degree of AN onto chitin was 114%. • The cyano- of AN was converted into amidoxime to enhance adsorption. • The adsorption capacity of As(III) onto modified chitin was 19.724 mg/g. • Removal of arsenic in groundwater samples was tested by continuous adsorption

  17. Influence of metal coordination on conductivity behavior in poly(butadiene-acrylonitrile)-CoCl2 system

    The metal complex formation and the electrical properties of amorphous solid polymer electrolytes, based on poly(butadiene-acrylonitrile) copolymer (PBAN) and CoCl2, have been studied over the homogeneity region of the system limited by the CoCl2 concentration of 1.89 mol kg-1. It has been found that ionic conductivity is carried out by the unipolar anion transfer at lower CoCl2 concentrations (up to 0.10 mol kg-1). As the CoCl2 concentration increases, electronic conductivity appears in addition to ionic conductivity, and the former becomes dominant, starting from 0.38 mol kg-1. It has been shown that the nature of charge carriers is determined by the composition of metal complexes formed by CoCl2 and the macromolecular solvent PBAN. At lower concentrations, the [Co2L2Cl4]0 dimers are the predominant species (L being macromolecule side groups C≡N), and their dissociation is followed by the formation of mobile Cl- anions and immobile binuclear [Co2Cl3]+ complexes. As CoCl2 concentration increases, polynuclear [ConL2Cl2n]0 (n > 2) complexes appear (L being C≡N and C=C groups of PBAN). Specific features of chemical bonds in π-complexes of transition metals result in the appearance of electronic charge carriers. The abrupt increase in conductivity observed at the highest CoCl2 concentration is connected with the formation of a percolation network of polynuclear [ConL2Cl2n]0 complexes

  18. Modification of fiber properties through grafting of acrylonitrile to rayon by chemical and radiation methods

    Inderjeet Kaur

    2013-11-01

    Full Text Available Fibrous properties of rayon has been modified through synthesis of graft copolymers of rayon with acrylonitrile (AN by chemical method using ceric ammonium nitrate (CAN/HNO3 as a redox initiator and gamma radiation mutual method. Percentage of grafting (Pg was determined as a function of initiator concentration, monomer concentration, irradiation dose, temperature, time of reaction and the amount of water. Maximum percentage of grafting (160.01% using CAN/HNO3 was obtained at [CAN] = 22.80 × 10−3 mol/L, [HNO3] = 112.68 × 10−2 mol/L and [AN] = 114.49 × 10−2 mol/L in 20 mL of water at 45 °C within 120 min while in case of gamma radiation method, maximum Pg (90.24% was obtained at an optimum concentration of AN of 76.32 × 10−2 mol/L using 10 mL of water at room temperature with total dose exposure of 3.456 kGy/h. The grafted fiber was characterized by FTIR, SEM, TGA and XRD studies. Swelling behavior of grafted rayon in different solvents such as water, methanol, ethanol, DMF and acetone was studied and compared with the unmodified rayon. Dyeing behavior of the grafted fiber was also investigated.

  19. Modeling contaminant transport and remediation at an acrylonitrile spill site in Turkey

    Şengör, S. Sevinç; Ünlü, Kahraman

    2013-07-01

    The August 1999 earthquake in Turkey damaged three acrylonitrile (AN) storage tanks at a plant producing synthetic fiber by polymerization. A numerical modeling study was carried out to analyze the groundwater flow and contaminant (AN) transport at the spill site. This study presents the application of a numerical groundwater model to determine the hydrogeological parameters of the site, where such data were not available during the field surveys prior to the simulation studies. The two- and three-dimensional transient flow and transport models were first calibrated using the first 266 days of observed head and concentration data and then verified using the remaining 540-day observed data set. Off-site migration of the contaminant plume was kept under control within the site boundaries owing to the favorable geology of the site, the characteristics of the local groundwater flow regime and the pumping operations. As expected, the applied pump-and-treat system was effective at high-permeability zones, but not fully effective at low-permeability zones. The results of long-term simulations for unconfined aquifer showed that the size of the plume in the high permeability zone shrank significantly due to the dilution by natural recharge. However, in the low permeability zone, it was not significantly affected. The study showed that accurate and sufficient data regarding the source characteristics, concentration and groundwater level measurements, groundwater pumping rates and their durations at each of the extraction points involved in the pump-and-treat system along with the hydrogeological site characterization are the key parameters for successful flow and transport model calibrations.

  20. The effect of unsaturated polyester resin from recycled PET as compatibilizer for styrene-butadiene (SBR)/ acrylonitrile-butadiene

    Unsaturated polyester resin (UPR) from recycled PET flakes was prepared by depolymerization with propylene glycol and poly esterified with adipic acid. The effect of addition of 5, 10 and 15 phr of unsaturated polyester resin (UPR) on the compatibility and physicomechanical properties of styrene-butadiene rubber (SBR) and acrylonitrile-butadiene rubber (NBR) blends were studied. DSC, TGA, MDR, FTIR and chemical methods were used to determine the degree of compatibility. The mechanical and physical properties of the blends were found to improve with addition of 10 phr UPR for SBR/NBR blend. (author)

  1. SELECTIVE SEPARATION OF WATER—ETHANOL MIXTURE THROUGH COPOLYMERIC MEMBRANES.Ⅱ.ACRYLONITRILE AND MALEIC ANHYDRIDE COPOLYMERIC MEMBRANES

    ZHangFuyao; ZhangYifeng; 等

    1993-01-01

    Acrylonitrile(AN) and maleic anhydride(MA) copolymer has been synthesized by radical polymerization using ammonium persulfate and sodium bisulfite as initiator.The pervaporation properties of the copolymeric membranes prepared have been investigated for the first time. The dependences of pervaporation characteristics on coplymer composition,feed concentration and operating temperature have been studied.In order to improve the separation properties of the copolymeric membranes,the membranes were hydrolyzed with 10 wt% soldium hydroxide or potassium hydroxide aqueous solution.The hydrolyzed membranes containing more than 0.069MA mol fraction showed higher tensile strength and separation properties than the original membranes.

  2. Radiation grafting of acrylonitrile on ethylene-propylene diene terpolymer rubber. Optimization of grafting parameters and oil resistance properties

    Radiation induced grafting of acrylonitrile (ACN) on ethylene-propene diene terpolymer (EPDM) rubber film was investigated by mutual radiation grafting technique. Effect of experimental variables viz. radiation dose, dose rate, type of solvent and monomer content on extent of grafting was studied. From the kinetic studies a mathematical relation Rgα[M]0.7D0.68 showing non-linear relationship for rate of grafting with monomer concentration and dose was deduced. The grafted samples showed increased hardness and oil resistance. (author)

  3. Computational Investigation of the Competition between the Concerted Diels-Alder Reaction and Formation of Diradicals in Reactions of Acrylonitrile with Non-Polar Dienes

    James, Natalie C.; Um, Joann M.; Padias, Anne B.; Hall, H. K.; Houk, K. N.

    2013-01-01

    The energetics of the Diels-Alder cycloaddition reactions of several 1,3-dienes with acrylonitrile, and the energetics of formation of diradicals, were investigated with density functional theory (B3LYP and M06-2X) and compared to experimental data. For the reaction of 2,3-dimethyl-1,3-butadiene with acrylonitrile, the concerted reaction is favored over the diradical pathway by 2.5 kcal/mol using B3LYP/6-31G(d); experimentally this reaction gives both cycloadduct and copolymer. The concerted ...

  4. Does erythropoietin augment noise induced hearing loss?

    Frederiksen, Birgitte Lidegaard; Cayé-Thomasen, Per; Lund, Søren Peter;

    2007-01-01

    in fact augment noise-induced hearing loss. This is contradictory to the beneficial effect of EPO reported by the vast majority of studies on stressed neural tissues. EPO administration may alter the blood flow dynamics of the cochlear vascular bed during or after noise exposure, by a potential...

  5. 30 CFR 764.17 - Hearing requirements.

    2010-07-01

    ... advertisement once a week for 2 consecutive weeks in the locale of the area covered by the petition and once during the week prior to the public hearing. The consecutive weekly advertisement must begin between 4... information on the potential coal resources of the area, the demand for coal resources, and the impact of...

  6. Hearing Preservation in Acoustic Neuroma Surgery

    HAN Dongyi; YU Limei; YANG Shiming; YU Liming

    2006-01-01

    Objective To report the authors' experiences in hearing preservation during acoustic neuroma (AN)resection procedures. Methods Two cases of AN removal via retrosigmoid approach were reviewed. Hearing preservation was attempted in the aid of endoscopic technique along with continuous monitoring of the compound action potential (CAP) and auditory brainstem response(ABR) during the surgery. Results The tumor in Case 1 was 1.5 cm in diameter. The average pure-tone hearing threshold was 30 dB HL and ABR was normal. Waves Ⅰ, Ⅲ and V of ABR were present following tumor removal. At 7th month follow-up, audiometric thresholds and ABR inter-peak intervals had recovered to pre-operative levels, with normal facial nerve function. The patient in Case 2 had bilateral AN. The tumors measured 4.0 cm (left) and 5.0 cm (right) on MRI scans. The AN on the right side was removed first, followed by removal of the left AN four months later. Intraoperative CAP monitoring was employed during removal of the left AN. While efforts to preserve the cochlear nerve were not successful, CAPs were still present after tumor removal. Conclusions Intraoperatively recorded CAPs are not reliable in predicting postoperative hearing outcomes. In contrast, ABRs are an indicator of function of the peripheral auditory pathway. Presence of waves Ⅰ, Ⅲ and V following tumor removal may represent preservation of useful hearing.

  7. Measuring Hearing in Wild Beluga Whales.

    Mooney, T Aran; Castellote, Manuel; Quakenbush, Lori; Hobbs, Roderick; Goertz, Caroline; Gaglione, Eric

    2016-01-01

    We measured the hearing abilities of seven wild beluga whales (Delphinapterus leucas) during a collection-and-release experiment in Bristol Bay, AK. Here we summarize the methods and initial data from one animal and discuss the implications of this experiment. Audiograms were collected from 4 to 150 kHz. The animal with the lowest threshold heard best at 80 kHz and demonstrated overall good hearing from 22 to 110 kHz. The robustness of the methodology and data suggest that the auditory evoked potential audiograms can be incorporated into future collection-and-release health assessments. Such methods may provide high-quality results for multiple animals, facilitating population-level audiograms and hearing measures in new species. PMID:26611025

  8. Noise-induced hearing loss and hearing aids requirement

    C. Giordano; Garzaro, M; Nadalin, J; Pecorari, G; Boggero, R; ARGENTERO, P.; Albera, R

    2008-01-01

    Subjective disturbances, due to hearing loss, are auditory disability and handicap which can be evaluated with a questionnaire. The present study refers to a population of industrial workers affected by noise-induced hearing loss. Aim of the study is to identify the minimal level of hearing loss over which the patient felt changes in his quality of life, and the average auditory threshold at which the patient considered the application of a hearing aid useful or necessary. The sample comprise...

  9. Effect of solution-blended poly(styrene-co-acrylonitrile copolymer on crystallization of poly(vinylidene fluoride

    2010-05-01

    Full Text Available Effect of solution-blended poly(styrene-co-acrylonitrile (SAN copolymer on crystallization of poly(vinylidene fluoride (PVDF was investigated by Fourier transform infrared spectroscopy (FTIR, differential scanning calorimetry (DSC and wide angle X-ray diffraction (WAXD. Acrylonitrile segment in SAN copolymer was partially miscible with PVDF. Styrene segment in SAN reduced the copolymer’s polarity and its miscibility with PVDF. FTIR and WAXD tests both showed as-prepared PVDF was mainly β-phase. We employed an index Aβdivided by Xc, suggesting that blended SAN could decrease the content of β-phase of PVDF. By DSC, the smaller content of PVDF made the system more miscible so that the Tg,SAN of pure SAN decreased from 86.6 to 81.6°C of sample PVDF/SAN = 20/80; further increase PVDF to 50/50, the Tg,SAN had a relative increase to be 84.2°C. However, for SAN by melt molding, Tg,SAN increased with the increase of PVDF content, which might be due to the incorporation of SAN into inter-spacing of PVDF lamellae, because PVDF molecular chains had not enough mobility to retreat from the SAN’s embrace and crystallize despite of the exit of SAN.

  10. Fire and Gas Barrier Properties of Poly(styrene-co-acrylonitrile Nanocomposites Using Polycaprolactone/Clay Nanohybrid Based-Masterbatch

    S. Benali

    2008-01-01

    Full Text Available Exfoliated nanocomposites are prepared by dispersion of poly(ε-caprolactone (PCL grafted montmorillonite nanohybrids used as masterbatches in poly(styrene-co-acrylonitrile (SAN. The PCL-grafted clay nanohybrids with high inorganic content are synthesized by in situ intercalative ring-opening polymerization of ε-caprolactone between silicate layers organomodified by alkylammonium cations bearing two hydroxyl functions. The polymerization is initiated by tin alcoholate species derived from the exchange reaction of tin(II bis(2-ethylhexanoate with the hydroxyl groups borne by the ammonium cations that organomodified the clay. These highly filled PCL nanocomposites (25 wt% in inorganics are dispersed as masterbatches in commercial poly(styrene-co-acrylonitrile by melt blending. SAN-based nanocomposites containing 3 wt% of inorganics are accordingly prepared. The direct blend of SAN/organomodified clay is also prepared for sake of comparison. The clay dispersion is characterized by wide-angle X-ray diffraction (WAXD, atomic force microscopy (AFM, and solid state NMR spectroscopy measurements. The thermal properties are studied by thermogravimetric analysis. The flame retardancy and gas barrier resistance properties of nanocomposites are discussed both as a function of the clay dispersion and of the matrix/clay interaction.

  11. Dye-sensitized solar cell with poly(acrylic acid-co-acrylonitrile)-based gel polymer electrolyte

    Highlights: ► A nontoxic, easily synthesized poly(acrylic acid-co-acrylonitrile) showed suitable transmittance for dye-sensitized solar cell. ► A cell with relatively large active area fabricated with this polymer material showed acceptable efficiency. ► The gel polymer matrix affected the charge recombination, I3− diffusion, double layer capacitance, and electron lifetime in the cell. - Abstract: A non-conducting, nontoxic poly(acrylic acid-co-acrylonitrile) (PAA) was prepared and used as a supporting matrix for the electrolyte of dye-sensitized solar cells (DSSCs). DSSCs of active area 0.80 cm × 1.10 cm fabricated with PAA, 0.5 M LiI, 0.05 M I2, 0.5 M 3-tert-butylpyridine, and 0.1 M 1-methyl-3-propylimidazolium iodide in 3-methoxypropionitrile solvent showed an average solar energy conversion efficiency of 1.61% under simulated sunlight illumination of 100 mW cm−2, AM 1.5. The effects of the gel polymer matrix on the electrochemical properties of DSSCs were studied using the electrochemical impedance spectroscopy. Relative to the non-gel reference cells, the results showed a decrease in charge recombination, ionic diffusion, and double layer capacitance and an increase in electron lifetime. These results could play an important role in determining the future direction for the development of high-performance gel polymer electrolytes.

  12. Fabrication of Acrylonitrile-Butadiene-Styrene Nanostructures with Anodic Alumina Oxide Templates, Characterization and Biofilm Development Test for Staphylococcus epidermidis.

    Camille Desrousseaux

    Full Text Available Medical devices can be contaminated by microbial biofilm which causes nosocomial infections. One of the strategies for the prevention of such microbial adhesion is to modify the biomaterials by creating micro or nanofeatures on their surface. This study aimed (1 to nanostructure acrylonitrile-butadiene-styrene (ABS, a polymer composing connectors in perfusion devices, using Anodic Alumina Oxide templates, and to control the reproducibility of this process; (2 to characterize the physico-chemical properties of the nanostructured surfaces such as wettability using captive-bubble contact angle measurement technique; (3 to test the impact of nanostructures on Staphylococcus epidermidis biofilm development. Fabrication of Anodic Alumina Oxide molds was realized by double anodization in oxalic acid. This process was reproducible. The obtained molds present hexagonally arranged 50 nm diameter pores, with a 100 nm interpore distance and a length of 100 nm. Acrylonitrile-butadiene-styrene nanostructures were successfully prepared using a polymer solution and two melt wetting methods. For all methods, the nanopicots were obtained but inside each sample their length was different. One method was selected essentially for industrial purposes and for better reproducibility results. The flat ABS surface presents a slightly hydrophilic character, which remains roughly unchanged after nanostructuration, the increasing apparent wettability observed in that case being explained by roughness effects. Also, the nanostructuration of the polymer surface does not induce any significant effect on Staphylococcus epidermidis adhesion.

  13. The Protective Value of Hesperidin in Mitigating the Biochemical Perturbations and Trace Element alterations induced by Acrylonitrile in Rats

    N. M. Abdallah*, N. E. Amien**, M. R. Mohamed*, A. S. Nada**, M. A. Mohamed

    2013-07-01

    Full Text Available Objective: Acrylonitrile (a chemical pollutant has been reported to induce harmful effects in humans. Therefore, this study was designed to evaluate the protective effects of hesperidin, a natural bioflavonoid, against the toxicity induced by acrylonitrile (AN in rats. Material&Methods: This study includes determination of serum total scavenger capacity “TSC”, liver enzymes (aspartate transaminase “ASAT”, alanine transaminase “ALAT” and alkaline phosphatase “ALP”, total proteins, albumin, glucose, creatinine, urea and lipid profile. Moreover, liver and kidney homogenate glutathione content “GSH”, catalase, superoxide dismutase “SOD”, glutathione peroxidase “GPx”, malondialdehyde “MDA” and some minerals were estimated. Results: revealed that administration of AN (orally 50mg/ kg b.wt. induced alterations in TSC level as well as liver, kidney and lipid profiles. In addition, a decrease in GSH-content and catalase, SOD and GPx activities was observed with an increase in MDA levels in both liver and kidney. There was disturbance in certain minerals such as Cu, Zn, Fe, Se, Ca, Mg and Mn. Conclusion: particularly, Hesperidin administration (orally 200 mg/kg b.wt. ameliorates the oxidative stress induced by AN, consistent with the reported antioxidant activity of hesperidin

  14. Smartphone serious games for vision and hearing assessment.

    Dias, Pedro; Aguiar, Bruno; Sousa, Filipe; Sousa, Augusto

    2015-01-01

    Falls are the second leading cause of accidental injury deaths worldwide. In this paper, it is intended to define methodologies that permit the evaluation of two potential factors which might have an impact on fall risk, these are: visual and hearing loss. The aim of the work developed is not to replace clinic visits, but to offer the user the means to continue the tracking of his vision and hearing at home, during the long time intervals between clinical tests. Tests conducted in a sample of our target users indicate a good ability to measure vision and hearing using an android smartphone and the proposed methodologies. While some tests require further validation, promising results were achieved in the most common tests for vision and hearing, presenting a good correlation between the system's results when compared to the traditional tests (for distance visual acuity) and the data gathered from the users (for hearing tests). PMID:25980863

  15. 18 CFR 401.84 - Hearing procedure.

    2010-04-01

    ... ADMINISTRATIVE MANUAL RULES OF PRACTICE AND PROCEDURE Administrative and Other Hearings § 401.84 Hearing procedure. (a) Participation in the hearing. In any hearing, the person requesting the hearing shall be... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Hearing procedure....

  16. Hearing speech in music

    Seth-Reino Ekström

    2011-01-01

    Full Text Available The masking effect of a piano composition, played at different speeds and in different octaves, on speech-perception thresholds was investigated in 15 normal-hearing and 14 moderately-hearing-impaired subjects. Running speech (just follow conversation, JFC testing and use of hearing aids increased the everyday validity of the findings. A comparison was made with standard audiometric noises [International Collegium of Rehabilitative Audiology (ICRA noise and speech spectrum-filtered noise (SPN]. All masking sounds, music or noise, were presented at the same equivalent sound level (50 dBA. The results showed a significant effect of piano performance speed and octave (P<.01. Low octave and fast tempo had the largest effect; and high octave and slow tempo, the smallest. Music had a lower masking effect than did ICRA noise with two or six speakers at normal vocal effort (P<.01 and SPN (P<.05. Subjects with hearing loss had higher masked thresholds than the normal-hearing subjects (P<.01, but there were smaller differences between masking conditions (P<.01. It is pointed out that music offers an interesting opportunity for studying masking under realistic conditions, where spectral and temporal features can be varied independently. The results have implications for composing music with vocal parts, designing acoustic environments and creating a balance between speech perception and privacy in social settings.

  17. Underwater Hearing in Turtles.

    Willis, Katie L

    2016-01-01

    The hearing of turtles is poorly understood compared with the other reptiles. Although the mechanism of transduction of sound into a neural signal via hair cells has been described in detail, the rest of the auditory system is largely a black box. What is known is that turtles have higher hearing thresholds than other reptiles, with best frequencies around 500 Hz. They also have lower underwater hearing thresholds than those in air, owing to resonance of the middle ear cavity. Further studies demonstrated that all families of turtles and tortoises share a common middle ear cavity morphology, with scaling best suited to underwater hearing. This supports an aquatic origin of the group. Because turtles hear best under water, it is important to examine their vulnerability to anthropogenic noise. However, the lack of basic data makes such experiments difficult because only a few species of turtles have published audiograms. There are also almost no behavioral data available (understandable due to training difficulties). Finally, few studies show what kinds of sounds are behaviorally relevant. One notable paper revealed that the Australian snake-necked turtle (Chelodina oblonga) has a vocal repertoire in air, at the interface, and under water. Findings like these suggest that there is more to the turtle aquatic auditory scene than previously thought. PMID:26611091

  18. Hearing is Believing

    2003-01-01

    This paper presents a discussion on the cochlear implant. This device was developed by Adam Kissiah, who suffers from hearing loss. Driven by his own hearing problem and three failed corrective surgeries, Kissiah started working in the mid-1970s on this surgically implantable device that provides hearing sensation to persons with severe-to-profound hearing loss who receive little or no benefit from hearing aids. Uniquely, the cochlear implant concept was not based on theories of medicine, as Kissiah had no medical background whatsoever. Instead, he utilized the technical expertise he learned while working as an electronics instrumentation engineer at NASA s Kennedy Space Center for the basis of his invention. This took place over 3 years, when Kissiah would spend his lunch breaks and evenings in Kennedy s technical library, studying the impact of engineering principles on the inner ear. In April of 2003, Kissiah was inducted into the Space Foundation's U.S. Space Technology Hall of Fame for his invention

  19. Geological disposal concept hearings

    The article outlines the progress to date on AECL spent-nuclear fuel geological disposal concept. Hearings for discussion, organised by the federal Environmental Assessment Review Panel, of issues related to this type of disposal method occur in three phases, phase I focuses on broad societal issues related to long term management of nuclear fuel waste; phase II will focus on the technical aspects of this method of disposal; and phase III will consist of community visits in New Brunswick, Quebec, Ontario, Manitoba and Saskatchewan. This article provides the events surrounding the first two weeks of phase I hearings (extracted from UNECAN NEWS). In the first week of hearings, where submissions on general societal issues was the focus, there were 50 presentations including those by Natural Resources Canada, Energy Probe, Ontario Hydro, AECL, Canadian Nuclear Society, Aboriginal groups, environmental activist organizations (Northwatch, Saskatchewan Environmental Society, the Inter-Church Uranium Committee, and the Canadian Coalition for Nuclear responsibility). In the second week of hearings there was 33 presentations in which issues related to siting and implementation of a disposal facility was the focus. Phase II hearings dates are June 10-14, 17-21 and 27-28 in Toronto

  20. Comparative analysis of endurance of not hearing and hearing students

    Iwańska Dagmara

    2013-11-01

    Full Text Available Study aim: Sport participation is important for deaf children, as participants experience physical, psychological and social benefits [23]. This study is a summary of four year’s researches on the endurance level of deaf and well hearing girls and boys. The aim of this study was to compare endurance of not hearing and hearing students.

  1. 49 CFR 1113.1 - Scheduling hearings; continued hearings.

    2010-10-01

    ... 49 Transportation 8 2010-10-01 2010-10-01 false Scheduling hearings; continued hearings. 1113.1 Section 1113.1 Transportation Other Regulations Relating to Transportation (Continued) SURFACE TRANSPORTATION BOARD, DEPARTMENT OF TRANSPORTATION RULES OF PRACTICE ORAL HEARING § 1113.1 Scheduling...

  2. Hearing Disability Assessment - Report of the Expert Hearing Group

    Department of Health (Ireland)

    1998-01-01

    In November 1997, the Department of Health and Children established an expert group to examine and make recommendations on an appropriate system and criteria for the assessment of hearing disability arising from hearing loss, with particular reference to noise induced hearing loss. The group was to prepare a report for the Minister for Health and Children. Download the Report here

  3. Hearing Protection and Hearing Symptoms in Danish Symphony Orchestras

    Laitinen, Heli; Poulsen, Torben

    2006-01-01

    A study about hearing protectors, problems involving hearing protector usage, hearing problems and working surroundings of classical musicians was made in three Danish symphony orchestras. The questionnaire used in the study was based on a previous study, a study made in Sweden to rock musicians,...

  4. Bone Anchored Hearing Treatment Procedure

    Full Text Available ... where one minute you may be hearing very well because the sound is being presented to the ... where you're not able to hear as well, or background noise may suddenly start up and ...

  5. Bone Anchored Hearing Treatment Procedure

    Full Text Available ... deafness, live from Hartford Hospital in Hartford, Connecticut. Ear, nose and throat specialist Dr. Marc Eisen will ... is normal or near-normal hearing in one ear and no functional hearing on the other side. ...

  6. Bone Anchored Hearing Treatment Procedure

    Full Text Available ... hearing on the other side. There are several causes for this condition. It can be a congenital ... with sudden onset hearing loss with no known cause. In cases where there is deafness on one ...

  7. 78 FR 64026 - Investigative Hearing

    2013-10-25

    ... program; Adequacy of existing Federal passenger car safety standards emphasizing `forward end' car... SAFETY BOARD Investigative Hearing On Wednesday, November 6, 2013, and Thursday, November 7, 2013, the National Transportation Safety Board (NTSB) will convene an investigative hearing to gather...

  8. Noise and Hearing Loss Prevention

    ... Follow us on Twitter Noise Manufacturing Construction SafeInSound Noise and Hearing Loss on the NIOSH Science Blog ... Topics Publications and Products Programs Contact NIOSH NIOSH NOISE AND HEARING LOSS PREVENTION Recommend on Facebook Tweet ...

  9. Bone Anchored Hearing Treatment Procedure

    Full Text Available ... not able to hear as well, or background noise may suddenly start up and then be an ... It allows for localization and improved hearing and noise. This device also lacks some of the disadvantages ...

  10. Bone Anchored Hearing Treatment Procedure

    Full Text Available ... one because she has experience with how hearing aids in general affect tinnitus. Tinnitus is, again, that ... want to talk about your experience with hearing aids and how people respond with their tinnitus? 00: ...