WorldWideScience

Sample records for accurate sr isotope

  1. Genesis of Sr Isotopes in Groundwater of Hebei Plain

    2007-01-01

    To analyze the genesis of Sr isotopes in groundwater of Hebei plain, time-accumulative effect of 87Sr/86Sr ratio was studied. It is shown that 87Sr/86Sr ratio increases with the increasing age and depth of groundwater and has a positive correlation to 4Heexc and a negative correlation to δ18O and δD.The groundwater is divided into three groups to discuss the relation between 87Sr/86Sr ratio and Sr2+ content: ① moderate Sr2+ content and higher 87Sr/86Sr ratio (water Ⅰ); ② lower Sr2+ content and higher 87Sr/86Sr ratio (water Ⅱ); and ③ higher Sr2+ content and lower 87Sr/86Sr ratio (water Ⅲ), that is hot water. On the basis of integrated analysis, it was considered that ① the radiogenic Sr in the Quaternary groundwater (Q4-Q1) originates from weathering of silicate rich in Na and Rb, mainly from plagioclase; ② the radiogenic Sr of hot water in Huanghua port is attributed to carbonate dissolution, with lower 87Sr/86Sr ratio and higher Sr/Na ratio; ③ the recharge area is laterally recharged by the groundwater flowing through igneous and metamorphic rocks, with moderate 87Sr/86Sr ratio. However, the formation mechanism of Sr isotopes in Tertiary groundwater needs further studies.

  2. Estimating the distribution of strontium isotope ratios (87Sr/86Sr in the Precambrian of Finland

    Lars Kaislaniemi

    2011-12-01

    Full Text Available A method to estimate the 87Sr/86Sr ratio of a rock based on its age and Rb/Sr ratio is presented. This method, together with data from the Rock Geochemical Database of Finland (n=6544 is used to estimate the 87Sr/86Sr ratios in the Precambrian of Finland and in its different major units. A generalization to cover the whole area of Finland is achieved by smoothing of estimation points. The estimation method is evaluated by comparing its results to published Rb-Sr isotope analyses (n=138 obtained on the Finnish Precambrian. The results show correspondence to different geological units of Finland,but no systematic difference between Archaean and younger areas is evident. Evaluation of the method shows that most of the estimates are reliable and accurate to be used as background material for provenance studies in archaeology, paleontology and sedimentology. However, some granitic rocks may have large (>1.0 % relative errors.Strontium concentration weighted average of the estimates differs only by 0.001 from the average 87Sr/86Sr ratio (0.730 of the rivers on the Fennoscandian shield.

  3. 87Sr/86Sr isotope composition of bottled British mineral waters for environmental and forensic purposes

    Mineral waters in Britain show a wide range of 87Sr/86Sr isotope compositions ranging between 87Sr/86Sr = 0.7059 from Carboniferous volcanic rock sources in Dunbartonshire, Scotland to 87Sr/86Sr = 0.7207 in the Dalradian aquifer of Aberdeenshire, Scotland. The 87Sr/86Sr composition of the waters shows a general correlation with the aquifer rocks, resulting in the waters from older rocks having a more radiogenic signature than those from younger rocks. This wide range of values means that the Sr isotope composition of mineral water has applications in a number of types of studies. In the modern commercial context, it provides a way of fingerprinting the various mineral waters and hence provides a method for recognising and reducing fraud. From an environmental perspective, it provides the first spatial distribution of bio-available 87Sr/86Sr in Britain that can be used in modern, historical and archaeological studies

  4. Accurate hydrocarbon estimates attained with radioactive isotope

    To make accurate economic evaluations of new discoveries, an oil company needs to know how much gas and oil a reservoir contains. The porous rocks of these reservoirs are not completely filled with gas or oil, but contain a mixture of gas, oil and water. It is extremely important to know what volume percentage of this water--called connate water--is contained in the reservoir rock. The percentage of connate water can be calculated from electrical resistivity measurements made downhole. The accuracy of this method can be improved if a pure sample of connate water can be analyzed or if the chemistry of the water can be determined by conventional logging methods. Because of the similarity of the mud filtrate--the water in a water-based drilling fluid--and the connate water, this is not always possible. If the oil company cannot distinguish between connate water and mud filtrate, its oil-in-place calculations could be incorrect by ten percent or more. It is clear that unless an oil company can be sure that a sample of connate water is pure, or at the very least knows exactly how much mud filtrate it contains, its assessment of the reservoir's water content--and consequently its oil or gas content--will be distorted. The oil companies have opted for the Repeat Formation Tester (RFT) method. Label the drilling fluid with small doses of tritium--a radioactive isotope of hydrogen--and it will be easy to detect and quantify in the sample

  5. Sr isotopic tracer study of the Samail ophiolite, Oman

    We have measured Rb and Sr concentrations and Sr isotopic compositions in 41 whole-rock samples and 12 mineral separates from units of the Samail ophiolite, including peridotite, gabbro, plagiogranite diabase dikes, and gabbro and websterite dikes within the metamorphic peridotite. Ten samples of cummulate gabbro from the Wadir Kadir section and nine samples from the Wadi Khafifah section have mean 87Sr/86Sr ratios and standard deviations of 0.70314 +- 0.00030 and 0.70306 +- 0.00034, respectively. The dispersion in Sr isotopic composition may reflect real heterogeneities in the magma source region. The average Sr isotopic composition of cumulate gabbro falls in the range of isotopic compositions of modern midocean ridge basalt. The 87Sr/86Sr ratios of noncumulate gabbro, plagiogranite, and diabase dikes range from 0.7034 to 0.7047, 0.7038 to 0.7046, and 0.7037 to 0.7061, respectively. These higher 87Sr/86Sr ratios are due to alteration of initial magmatic compositions by hydrothermal exchange with seawater. Mineral separates from dikes that cut harzburgite tectonite have Sr isotopic compositions which agree with that of cumulate gabbro. These data indicate that the cumulate gabbro and the different dikes were derived from partial melting of source regions that had similar long-term histories and chemical compositions

  6. Sr-isotopic systematics in soils (Sardinia, Italy)

    Full text: The Sr-isotope ratios of selected samples from the various horizons of representative soils in the southern east corner of the island of Sardinia were determined. The autochtonous soils are developed on an acidic meta volcanic formation of the Lower Paleozoic. The samples were dissolved using the sequential extraction technique, allowing to separate the labile strontium from that contained in the insoluble residue. Sr was then analyzed by mass spectrometry. The Sr-isotope ratios generally increase from the bottom to the top of the soils; increase being particularly significant in the insoluble residue fraction and, subordinately, in the HNO3 -soluble fraction. However, the labile Sr exhibits a isotopic range (0.710916 - 0.711454) lower than the insoluble Sr (0.719142 - 0.749583), that is, in turn, lower than the average Sr-isotopic ratio of the parent rock (0.750756). The results indicate that the bulk of the labile Sr is provided by a distinct source from the parent rock. Such a source is likely represented by the Sr contained in cyclic salts carried by rainwater (87Sr/86Sr 0.70918). Calculations show that the fraction of the labile strontium released by leaching of soil minerals vary from 6 to 18 % moving from the depth to the top of the soils. (author)

  7. Resolving archaeological populations with Sr-isotope mixing models

    Strontium isotope analysis of tooth enamel is a useful provenancing technique to investigate the childhood origins and residential mobility of ancient people. However, where different geographical target regions have similar biosphere 87Sr/86Sr it is often difficult to resolve the 87Sr/86Sr ranges of two different groups of people and establish what constitutes the local range at each site. Here a multi-period study is presented from the Outer Hebrides, Scotland and an investigation of Neolithic and Early Bronze Age populations from the Yorkshire Wolds, NE England. The aim is to demonstrate that, despite complex human dietary strategies, simple mixing systems with only two end-members do occur in archaeological human populations in certain geological provinces and, despite overlapping 87Sr/86Sr ranges, it is possible to separate two populations based on the structure within the data set

  8. C, Sr and Sr isotopic composition on probable vendian- tommotian carbonate sequences in Nw Argentina

    C-isotope stratigraphy is one of the most powerfool tools in Precambrian chronostratigraphy, especially when sediments lack recognizable animal fossils. The δ13C secular variation curves for marine carbonates in the Neoproterozoic-Cambrian interval show strong positive-negative excursions, several of them interpreted as the stratigraphic position of ancient ice ages (Hoffman et al. 1998). The Sr isotope composition of the seawater for this age interval is characterized by a continuous increase of 87Sr/86Sr that is interrupted, several times, by sharp rises, which represent important changes in the Earth history (Montanez et al. 2000). Only limited data on the behavior of C and Sr isotopes in carbonates are available in South America. We examine here carbonate sequences from the Argentine Precordillera, San Juan province, and from other carbonate sequences in NW Argentina that could be, potentially, proxies for the Precambrian-Cambrian transition. We have studied their δ13C and 87Sr/86Sr chemostratigraphy and compare it to global C and Sr isotope secular variation curves for this time span. This study aims to improve the relatively coarse stratigraphic resolution provided only by the study of the fossil record in some of the carbonate successions under consideration (au)

  9. Isotope Selection Characteristics of MOT for the Detection of the Sr Rare Isotopes

    Trace isotope analysis has become an essential tool in basic research, environmental science, archaeological dating and geology. Especially, the detection of the trace radio isotope 90Sr, which is a fission product, has been of an interest because of the nuclear industry and environmental assessment. Recently, the neutral atom trap method has been developed for analyzing ultra trace isotopes, such as 81Kr, 85Kr and 41Ca. This method is not only free of contamination from different isotopes or isobar, but it is also a higher isotope selective method than any other laser based methods. To develop the higher isotope selective analytical system to detect rare 90Sr, MOT(magneto optical trap) has been applied as an isotope selective excitation method. In this paper, MOT has been demonstrated and the fluorescence characteristics have been investigated to have knowledge of the isotope selective process of MOT

  10. Do foraminifera accurately record seawater neodymium isotope composition?

    Scrivner, Adam; Skinner, Luke; Vance, Derek

    2010-05-01

    , Earth Planet. Sci. Lett. 265, 571-587. Lacan, F., and Jeandel, C., 2005a. Neodymium isotopes as a new tool for quantifying exchange fluxes at the continent-ocean interface, Earth Planet. Sci. Lett. 232, 245-257. Piepgras, D.J., and Wasserburg, G.J., 1987. Rare earth element transport in the western North Atlantic inferred from Nd isotopic observations. Geochim. Cosmochim. Acta 51, 1257-1271. Rutberg, R.L., Hemming, S.R., and Goldstein, S.L., 2000. Reduced North Atlantic deep water flux to the glacial southern ocean inferred from neodymium isotope ratios. Nature 405, 935-938. Tachikawa, K., Roy-Barman, M., Michard, A., Thouron, D., Yeghicheyan, D., and Jeandel, C., 2004. Neodymium isotopes in the Mediterranean Sea: comparison between seawater and sediment signals. Geochim. Cosmochim. Acta 68, 3095-3106.

  11. Investigation of a dynamic seawater intrusion event using strontium isotopes (87Sr/86Sr)

    Jørgensen, Niels Oluf; Andersen, Martin S.; Engesgaard, Peter Knudegaard

    2008-01-01

    of Palaeocene (Danian) limestone. Stable isotopes (18O and 2H), strontium isotopes (87Sr/86Sr) and the elements Sr and Cl were measured to delineate the mixing of seawater and groundwater in the shallow aquifer and to determine the contribution from different water sources along the flow paths. The...... stable isotopes reflect recharge conditions and mixing between groundwater and seawater. The 87Sr/86Sr isotope ratios are controlled by aquifer matrix chemistry. The 87Sr/86Sr ratio distribution and Sr content reveal a ternary mixing system in the shallow aquifer, encompassing brackish seawater, fresh...... sandy aquifer through the Pleistocene sedimentary sequence. The upper part of the sandy aquifer is thoroughly dominated by mixing processes between infiltrating fresh groundwater and brackish seawater from Isefjord. Prior to the intrusion experiment there appeared to be limited mixing between the upper...

  12. Sr isotopic characteristics in two small watersheds draining typical silicate and carbonate rocks: implication for the studies on seawater Sr isotopic evolution

    Wu, W. H.; Zheng, H. B.; Yang, J. D.

    2013-06-01

    We systematically investigated Sr isotopic characteristics of small silicate watershed - the tributary Xishui River of the Yangtze River, and small carbonate watershed - the tributary Guijiang River of the Pearl River. The results show that the Xishui River has relatively high Sr concentrations (0.468-1.70 μmol L-1 in summer and 1.30-3.17 μmol L-1 in winter, respectively) and low 87Sr/86Sr ratios (0.708686-0.709148 in summer and 0.708515-0.709305 in winter), which is similar to the characteristics of carbonate weathering. The Guijiang River has low Sr concentrations (0.124-1.098 μmol L-1) and high 87Sr/86Sr ratios (0.710558-0.724605), being characterized by silicate weathering. In the Xishui River catchment, chemical weathering rates in summer are far higher than those in winter, indicating significant influence of climate regime. However, slight differences of 87Sr/86Sr ratios between summer and winter show that influence of climate on Sr isotope is uncertainty owing to very similar Sr isotope values in silicate and carbonate bedrocks. As 87Sr/86Sr ratios in the Xishui River are lower than those in seawater, they will decrease 87Sr/86Sr ratio of seawater after transported into oceans. Previous studies also showed that some basaltic watersheds with extremely high chemical weathering rates reduced the seawater Sr isotope ratios. In other words, river catchments with high silicate weathering rates do not certainly transport highly radiogenic Sr into oceans. Therefore, it may be questionable that using the variations of seawater 87Sr/86Sr ratio to indicate the continental silicate weathering intensity. In the Guijiang River catchment, 87Sr/86Sr ratios of carbonate rocks and other sources (rainwater, domestic and industrial waste water, and agricultural fertilizer) are lower than 0.71. In comparison, some non-carbonate components, such as, sand rocks, mud rocks, shales, have relatively high Sr isotopic compositions. Moreover, granites accounted for only 5% of the

  13. An analytical approach to Sr isotope ratio determination in Lambrusco wines for geographical traceability purposes.

    Durante, Caterina; Baschieri, Carlo; Bertacchini, Lucia; Bertelli, Davide; Cocchi, Marina; Marchetti, Andrea; Manzini, Daniela; Papotti, Giulia; Sighinolfi, Simona

    2015-04-15

    Geographical origin and authenticity of food are topics of interest for both consumers and producers. Among the different indicators used for traceability studies, (87)Sr/(86)Sr isotopic ratio has provided excellent results. In this study, two analytical approaches for wine sample pre-treatment, microwave and low temperature mineralisation, were investigated to develop accurate and precise analytical method for (87)Sr/(86)Sr determination. The two procedures led to comparable results (paired t-test, with tisotopic values were compared with isotopic data coming from (i) soils of their territory of origin and (ii) wines obtained by same grape varieties cultivated in different districts. The obtained results have shown no significant variability among the different vintages of wines and a perfect agreement between the isotopic range of the soils and wines has been observed. Nevertheless, the investigated indicator was not enough powerful to discriminate between similar products. To this regard, it is worth to note that more soil samples as well as wines coming from different districts will be considered to obtain more trustworthy results. PMID:25466059

  14. Least destructive sampling of human remains using laser drilling for Sr isotope analysis by TIMS

    Willmes, Malte; Moffat, Ian; Grün, Rainer; Armstrong, Richard; Kinsley, Les; McMorrow, Linda

    2013-04-01

    Strontium isotope ratios (87Sr/86Sr) measured in ancient human remains can be used to reconstruct migration patterns of ancient human populations. This application is based on the fact that different geologic regions have distinct Sr isotope signatures that are cycled through the soils, plants and rivers, and eventually enter the food cycle. Sr isotope ratios measured in skeletal remains (bones and teeth) reflect the average of dietary Sr that was consumed when the tissue was formed, allowing the investigation of human migration between geologically distinct terrains. The analysis of human remains is always a sensitive topic requiring minimal damage to the sample, while at the same time providing highly precise and accurate results. Samples can be analysed either by solution methods like thermal ionisation mass spectrometry (TIMS), or by in-situ laser ablation MC-ICP-MS. For TIMS a drill is used to extract a small amount of sample, which is then digested in acid and Sr is separated out using ion exchange chromatography. This technique provides highly precise and accurate results, because any isobaric interferences are removed during chemical separation. The drawback is that drilling may cause visible damage to the sample, restricting access to precious human remains. LA-MC-ICP-MS analysis is very fast and nearly destruction free. However, the accuracy and precision of LA-MC-ICP-MS is limited by a number of factors including large instrumental mass discrimination, laser-induced isotopic and elemental fractionations and molecular interferences on 87Sr. Its application thus requires rigorous data reduction, which can introduce significant uncertainties into the analysis. This is especially true for samples with relatively low Sr concentrations such as human teeth (e.g., Woodhead et al., 2005; Horstwood et al., 2008; Vroon et al., 2008). In addition, LA-MC-ICP-MS has traditionally required a flat sample surface, thus an unbroken tooth needs to be cut, which is rather

  15. An accurate DNA marker assay for stem rust resistance gene Sr2 in wheat

    The stem rust resistance gene Sr2 has provided broad-spectrum protection against stem rust (Puccinia graminis) since its wide spread deployment in wheat from the 1940s. Because Sr2 confers partial resistance which is difficult to select under field conditions, a DNA marker is desirable that accurate...

  16. Sr - an element shows the way - Applications of Sr isotopes for provenance, tracing and migration (Invited)

    Prohaska, T.; Irrgeher, J.; Zitek, A.; Teschler Nicola, M.

    2010-12-01

    Strontium - named after the small Scottish town Strontian - as such is an element with little popularity. Firstly described by Martin Heinrich Klaproth in 1798, the metal is used in metallurgy to some extent whereas its compounds are interesting in glass industries, electronics and pyrotechnics. The element has chemical similarity to Ca and makes up 1/60 of the earth’s amount of the latter. Nonetheless, it is its isotopic composition which makes Sr so interesting for a large number of scientists. The natural composition of the four naturally occurring isotopes (84Sr, 86Sr 87Sr and 88Sr) varies in nature due to the radioactive decay of 87Rb to 87Sr. Thus, it was early recognized as geochronometer especially in Ca rich matrices. With increasing precision of applied methodology, the natural variation of the 87Sr/86Sr isotope ratio (analyzed at first mainly by thermal ionization mass spectrometry (TIMS)) became more and more popular in provenance studies. The natural variation of the ratio is mainly determined by the geological age and the original composition of the rock and can be used therefore as fingerprint of the local geology. The ratio is transferred with no significant fractionation via the water into plants and finally via the food chain into animal and human tissues (especially bones and teeth). As the element is chemically similar to Ca, it appears in most matrices. The use for provenance studies is supported by the fact that the long half life (4.8 x 1010 years) does not lead to an alteration during the time scales which are investigated (from recent samples to human or animal skeletal remains which date back up to 30.000 BC). The uniqueness of the system besides the natural variation is defined by the ubiquity in nature and the relatively high (and thus measurable) elemental concentration in most tissues. It was finally the advent of multiple collector inductively coupled plasma mass spectrometry (MC-ICP-MS) which augmented the number of applications

  17. Sr ISOTOPES AND ROMAGNA WINES: AN OPPORTUNITY FOR BETTER TRADING?

    Umberto Masi; Francesca Castorina

    2011-01-01

    The Sr isotopic compositions of 11 wines from Romagna were determined with the aim of providing a new parameter to track the origin of these wines and serving for better trading. The 87Sr values measured ranged narrowly from -0.07 to +0.33 permil, in agreement with the provenance of the parent grapes from an area characterized by substantial uniformity of soil composition. However, so far, it is possible to make a preliminary distinction of the Sangiovese wines from the other wines analyzed b...

  18. Mass measurements of neutron-rich Rb and Sr isotopes

    Klawitter, R.; Bader, A.; Brodeur, M.; Chowdhury, U.; Chaudhuri, A.; Fallis, J.; Gallant, A. T.; Grossheim, A.; Kwiatkowski, A. A.; Lascar, D.; Leach, K. G.; Lennarz, A.; Macdonald, T. D.; Pearkes, J.; Seeraji, S.; Simon, M. C.; Simon, V. V.; Schultz, B. E.; Dilling, J.

    2016-04-01

    We report on the mass measurements of several neutron-rich Rb and Sr isotopes in the A ≈100 region with the TITAN Penning-trap mass spectrometer. By using highly charged ions in the charge state q =10 + , the masses of Rb,9998 and Sr-10098 have been determined with a precision of 6-12 keV, making their uncertainty negligible for r -process nucleosynthesis network calculations. The mass of 101Sr has been determined directly for the first time with a precision eight times higher than the previous indirect measurement and a deviation of 3 σ when compared to the Atomic Mass Evaluation. We also confirm the mass of 100Rb from a previous measurement. Furthermore, our data indicate the existence of a low-lying isomer with 80 keV excitation energy in 98Rb. We show that our updated mass values lead to minor changes in the r process by calculating fractional abundances in the A ≈100 region of the nuclear chart.

  19. Mass measurements of neutron-rich Rb and Sr isotopes

    Klawitter, R; Brodeur, M; Chowdhury, U; Chausdhuri, A; Fallis, J; Gallant, A T; Grossheim, A; Kwiatkowski, A A; Lascar, D; Leach, K G; Lennarz, A; Macdonald, T D; Pearkes, J; Seeraji, S; Simon, M C; Simon, V V; Schultz, B E; Dilling, J

    2015-01-01

    We report on the mass measurements of several neutron-rich $\\mathrm{Rb}$ and $\\mathrm{Sr}$ isotopes in the $A \\approx 100$ region with the TITAN Penning-trap mass spectrometer. Using highly charged ions in the charge state $q=10+$, the masses of $^{98,99}\\mathrm{Rb}$ and $^{98-100}\\mathrm{Sr}$ have been determined with a precision of $6 - 12\\ \\mathrm{keV}$, making their uncertainty negligible for r-process nucleosynthesis network calculations. The mass of $^{101}\\mathrm{Sr}$ has been determined directly for the first time with a precision eight times higher than the previous indirect measurement and a deviation of $3\\sigma$ when compared to the Atomic Mass Evaluation. We also confirm the mass of $^{100}\\mathrm{Rb}$ from a previous measurement. Furthermore, our data indicates the existance of a low-lying isomer with $80\\ \\mathrm{keV}$ excitation energy in $^{98}\\mathrm{Rb}$. We show that our updated mass values lead to minor changes in the r-process by calculating fractional abundances in the $A\\approx 100$ re...

  20. Sr isotope evolution during chemical weathering of granites -- impact of relative weathering rates of minerals

    2001-01-01

    The Sr isotopic systematics in the weathering profiles of biotite granite and granite porphyry in southern Jiangxi Province were investigated. The results showed that during the chemical weathering of granites, remarked fractionation occurred between Rb and Sr. During the early stages of chemical weathering of granites, the released Sr/Si and Sr/Ca ratios are larger than those of the parent rocks, and the leaching rate of Sr is higher than those of Si, Ca, K, Rb, etc. Dynamic variations in relative weathering rates of the main Sr-contributing minerals led to fluctuation with time in 87Sr/86Sr ratios of inherent and released Sr in the weathering crust of granite. Successive weathering of biotite, plagioclase and K-feldspar made 87Sr/86Sr ratios in the weathering residues show such a fluctuation trend as to decrease first, increase, and then decrease again till they maintain stable. This work further indicates that when Sr isotopes are used to trace biogeochemical processes on both the catchment and global scales, one must seriously take account of the prefer-ential release of Sr from dissolving solid phase and the fluctuation of 87Sr/86Sr ratios caused by the variations of relative weathering rates of Sr-contributing minerals.

  1. Sr fluxes and isotopic compositions of the eleven rivers originating from the Qinghai-Tibet Plateau and their contributions to 87Sr/86Sr evolution of seawater

    2009-01-01

    To evaluate influence of chemical weathering of the Qinghai-Tibet Plateau (QTP) on seawater 87Sr/86Sr variation, river water and sediment samples were collected, and their Sr concentrations and isotopic compositions analyzed, from the seven large rivers that originated from the QTP. By combining these with the data of the Ganges, Brahmaputra, Indus and Irrawaddy originated in the southern QTP, the total Sr flux of the eleven rivers reaches 3.47×109 mol·a-1, which accounts for 10.2% of the total Sr flux transported by the global rivers. The weighted mean 87Sr/86Sr is 0.71694, higher than the average value of the global rivers. The 87Srex (87Sr flux in excess of the seawater 87Sr/86Sr ratio) of the Chinese seven rivers is 1.55×106 mol·a-1, only accounting for about 6% of the value of the eleven rivers originated from QTP, and the Ganges-Brahmaputra system accounts for 86%. We assume that the QTP rivers have no strontium contributions to the oceans before ~40 Ma and the Sr fluxes of the global rivers, except the QTP eleven rivers, are constant, then a maximum linear increase in Sr fluxes of the QTP rivers from zero to the modern value in response to tectonic uplift can explain ~69% increase of seawater 87Sr/86Sr over the past ~40 Ma and the remainder of 31% is perhaps provided from other factors.

  2. Modeling of lunar basalt petrogenesis - Sr isotope evidence from Apollo 14 high-alumina basalts

    This paper reexamines the Sr isotope data available for the Apollo 14 high-alumina basalts in light of the assimilation and fractional crystallization (AFC) process model proposed by Neal et al. (1987, 1988, 1989). Positive linear correlations of Sr-87/Sr-86 with Rb-87/Rb-86 and the Sr abundance (both leading to KREEP) are used as evidence of such an AFC process in the petrogenesis of Apollo 14 high-alumina basalts. The existing Sr isotope data for Apollo 14 high-alumina basalts suggest that there were three AFC cycles. 33 refs

  3. Pb and Sr isotopic compositions of ancient pottery: a method to discriminate production sites

    The discriminating of production sites of ancient pottery samples using multi-isotopic systematics was described. Previous work has proven that Pb isotopic ratios can be used for discriminating the production sites of ancient pottery under certain conditions. The present work suggests that although Nd isotopic ratios are not sensitive to the production sites of ancient pottery, Sr isotopic ratios are important for the purpose. Pb isotopic ratios are indistinguishable for the pottery excavated from the Jiahu relict, Wuyang, Henan Province and for famous Qin Terra-cotta Figures. But, the 87Sr/86Sr ratios for the former (about 0.715) are significantly lower than that of the latter (0.717-0.718). The authors concluded that a combined use of Pb and Sr isotopes would be a more powerful method for discriminating the production site of ancient pottery. (authors)

  4. Sr-Nd ISOTOPES IN MOSSES FROM ROMAGNA (ITALY) AND THEIR ENVIRONMENTAL SIGNIFICANCE

    Francesca Castorina; Umberto Masi

    2010-01-01

    Sr-Nd isotopes were applied for the first time to the study of several moss samples from a transect stretching through Romagna from the Apennines to the Adriatic sea coast. The isotopic data suggest that the mosses uptake Sr and Nd via atmospheric depositions from both marine carbonates and old siliceous crustal rocks. Anthropic pollution cannot be precisely evaluated because of the lack of univocal isotopic signature of the sources.

  5. Sr-Nd ISOTOPES IN MOSSES FROM ROMAGNA (ITALY AND THEIR ENVIRONMENTAL SIGNIFICANCE

    Francesca Castorina

    2010-04-01

    Full Text Available Sr-Nd isotopes were applied for the first time to the study of several moss samples from a transect stretching through Romagna from the Apennines to the Adriatic sea coast. The isotopic data suggest that the mosses uptake Sr and Nd via atmospheric depositions from both marine carbonates and old siliceous crustal rocks. Anthropic pollution cannot be precisely evaluated because of the lack of univocal isotopic signature of the sources.

  6. Sr isotopes in the Orgueil CI meteorite: Chronology of early solar system hydrothermal activity

    J D Macdougall

    2000-03-01

    New Sr isotopic analyses and calculated formation ages of carbonates from the Orgueil CI meteorite are reported. Among the samples analyzed in this work, dolomites give the youngest formation ages and may have been deposited intermittently starting near the time of parent body formation and continuing for at least 30 Ma. The Sr isotope data also suggest that breunnerites (Fe-Mn-Mg carbonates) crystallized after dolomite formation. Leaching experiments on bulk meteorite samples provide evidence for a very mobile, water soluble Sr reservoir in Orgueil that is characterized by extremely radiogenic Sr (87Sr/86Sr ≈ 0.81- 0.82). This unsupported Sr reflects recent element redistribution, possibly at the time of parent body breakup recorded by the ∼10 Ma exposure age of Orgueil. The carbonate data in particular corroborate earlier indications that hydrothermal processes were among the earliest events to affect the CI parent body.

  7. Sr fluxes and isotopic compositions of the eleven rivers originating from the Qinghai-Tibet Plateau and their contributions to 87Sr/86Sr evolution of seawater

    WU WeiHua; YANG JieDong; XU ShiJin; LI GaoJun; YIN HongWei; TAO XianCong

    2009-01-01

    To evaluate influence of chemical weathering of the Qinghai-Tibet Plateau (QTP) on seawater 87Sr/66Srvariation, river water and sediment samples were collected, and their Sr concentrations and isotopic compositions analyzed, from the seven large rivers that originated from the QTP. By combining these with the data of the Ganges, Brahmaputra, Indus and Irrawaddy originated in the southern QTP, the total transported by the global rivers. The weighted mean 87Sr/86Sr is 0.71694, higher than the average value of the global rivers. The 87Srex (87Sr flux in excess of the seawater 87Sr/66Sr ratio) of the Chinese seven QTP, and the Ganges-Brahmaputra system accounts for 86%. We assume that the QTP rivers have no strontium contributions to the oceans before -40 Ma and the Sr fluxes of the global rivers, except the QTP eleven rivers, are constant, then a maximum linear increase in Sr fluxes of the QTP rivers from zero to the modern value in response to tectonic uplift can explain -69% increase of seawater 87Sr/86Sr over the past -40 Ma and the remainder of 31% is perhaps provided from other factors.

  8. Shape coexistence in neutron-rich Sr isotopes : Coulomb excitation of $^{96}$Sr

    Clement, E; Siem, S; Czosnyka, T

    2007-01-01

    The nuclei in the mass region A $\\cong$ 100 around Sr and Zr show a dramatic change of the nuclear ground-state shape from near spherical for N $\\leq$ 58 to strongly deformed for N $\\geq$ 60. Theoretical calculations predict the coexistence of slightly oblate and strongly prolate deformed configurations in the transitional region. However, excited rotational structures based on the highly deformed configuration, which becomes the ground state at N = 60, are not firmly established in the lighter isotopes, and the earlier interpretation of a very abrupt change of shape has been challenged by recent experimental results in favor of a rather gradual change. We propose to study the electromagnetic properties of the neutron-rich nucleus $_{38}^{96}$Sr$_{58}$ by low-energy Coulomb excitation using the REX-ISOLDE facility and the MINIBALL detector array. Both transitional and diagonal matrix elements will be extracted, resulting in a complete description of the transition strengths and quadrupole moments of the low-l...

  9. Isotopic equilibration during partial melting: an experimental test of the behaviour of Sr

    Hammouda, T.; Pichavant, M.; Chaussidon, M.

    1996-10-01

    Experiments using isotopically enriched, Sr doped minerals designed to test for isotopic equilibrium between source and melt during partial melting reveal that 87Sr/ 86Sr ratios of the liquids are primarily determined by the proportions of minerals consumed and vary with the advancement of the melting reaction. The experiments were performed at 1 atm on model crustal assemblages composed of pairs of natural plagioclase (An 68; 87Sr/ 86Sr= 0.701 ) and synthetic fluorphlogopite doped with 90 ppm Sr having 87Sr/ 86Sr= 4.2 . SIMS traverses showed that during the initial stages of the reaction, liquids are isotopically zoned. All the analyzed melts have 87Sr/ 86Sr markedly higher than that of the bulk starting assemblage (i.e. the source), because of the faster melting rate of fluorphlogopite. At 1200°C and 1250°C melting occurs above a critical temperature, wherein the dissolution rates of the crystals are controlled by diffusion of species in the melt, and reactants and reaction products are out of isotopic equilibrium. This is due to faster melt-crystal boundary migration when compared to Sr diffusion in the crystals. Equilibration is possible only if melting stops. Calculations show that total equilibration between melt and residue by Sr tracer diffusion in the crystals takes 10 4-10 6 yr (for temperature and grain size ranging, respectively, from 800°C to 1000°C, and 0.1 to 1 cm). When compared to the proposed residence time of crustal magmas at their sources, this result strongly suggests that magmas that do not reflect the bulk isotopic characteristics of their source regions can be produced.

  10. Evidence for stable Sr isotope fractionation by silicate weathering in a small sedimentary watershed in southwestern Taiwan

    Chao, Hung-Chun; You, Chen-Feng; Liu, Hou-Chun; Chung, Chuan-Hsiung

    2015-09-01

    Radiogenic Sr isotopes (87Sr/86Sr) are robust for provenance identification in hydrology, affected mainly by the age of background lithologies and the degree of chemical weathering. However, there is limited knowledge concerning the fractionation mechanism of stable Sr isotopes (88Sr/86Sr) in rivers. In this study, river water was collected on a weekly to monthly basis throughout dry and wet seasons. Furthermore, to study the variations of radiogenic and stable Sr isotopes during intense weathering, a major flooding event (2000 mm precipitation in three days, Typhoon Morakot), water was captured within a small drainage catchment system (161 km2) along the Hou-ku River in southwestern Taiwan. For a better constraint on the end member compositions, bedload sediments, suspended particles, and several host rocks were sampled for a systematic investigation. The carbonate and silicate phases of these solids were chemically separated. Dissolved major elements indicate that the watersheds were predominated by silicate weathering. Stable Sr isotopes show no significant variation (δ88Sr = 0.24-0.31‰) temporally and spatially with an average of 0.28‰. Additionally, all solids showed lower δ88Sr values than the river water while the host rocks had higher δ88Sr values (δ88Sr = 0.20-0.26‰) than the residual weathering products (δ88Sr = 0.08-0.22‰), indicating preferential leaching of heavy Sr into the hydrosphere and leaving light Sr in the residual solids. Results of laboratory acid leaching experiments reveal that dissolution of high δ88Sr value minerals occurred at an early stage of weathering. The variation of weathering intensity does not alter stable Sr isotopes in silicate weathering dominated river water, which contains higher stable Sr isotopes than the associated sediments. The silicatic sedimentary rocks preferentially released higher stable Sr isotopes into the hydrosphere during chemical weathering, thus leaving lower stable Sr isotopes in the residual

  11. Tracing the geographical origin of wines using Sr-isotope as crucial geochemical tracer

    Tommasini, S; Braschi, E.; Bucelli, P.; Priori, S.; Costantini, E.; Bollati, A; Mattei, M.; Conticelli, S.

    2011-01-01

    The Department of Earth Sciences of the University of Firenze has been involved in the research project ISSUOVINO with the aim to define a geochemical marker suitable to associate the wine to its grape harvest terroir. Following this research guideline, we have determined Sr isotope ratios (87Sr/86Sr) in a number of microvinifications on single grapevines belonging to the "Azienda Barone Ricasoli S.p.A." at Brolio, and, in order to make a comparison, in other high-quality wi...

  12. Mineral-scale Sr isotope variation in plutonic rocks – a tool for unraveling the evolution of magma systems.

    Davidson, J. P.; Font, L.; Charlier, B.L.A.; Tepley, F.J. III

    2006-01-01

    Isotope ratios of elements such as Sr, Nd, Pb and Hf can be used as tracers of magmatic sources and processes. Analytical capabilities have evolved so that isotope ratios can now be analysed in situ, and isotopic tracers can therefore be used within single minerals to track the changing magmatic environment in which a given mineral grew. This contribution shows that Sr isotope ratios in feldspars that make up plutonic rocks will typically preserve initial isotopic variations, provided precise...

  13. Determination of transfer factors for 137Cs and 90Sr isotopes in soil-plant system

    Studies on the determination of transfer factors (TF) for 137Cs and 90Sr isotopes from soil to plant are presented. Experiments were performed on grass from meadows of Bug river valleys and vegetables from Zwierzyniec region. The influence of potassium and calcium on the transfer factor of both isotopes is discussed. (author)

  14. Identification of Marchfeld asparagus using Sr isotope ratio measurements by MC-ICP-MS.

    Swoboda, S; Brunner, M; Boulyga, S F; Galler, P; Horacek, M; Prohaska, T

    2008-01-01

    This work focuses on testing and application of Sr isotope signatures for the fast and reliable authentication and traceability of Asparagus officinalis originating from Marchfeld, Austria, using multicollector inductively coupled plasma mass spectrometry after optimised Rb/Sr separation. The major sample pool comprises freeze-dried and microwave-digested asparagus samples from Hungary and Slovakia which are compared with Austrian asparagus originating from the Marchfeld region, which is a protected geographical indication. Additional samples from Peru, The Netherlands and Germany were limited in number and allowed therefore only restricted statistical evaluation. Asparagus samples from Marchfeld were harvested within two subsequent years in order to investigate the annual variation. The results show that the Sr isotope ratio is consistent within these 2 years of investigation. Moreover, the Sr isotope ratio of total Sr in soil was found to be significantly higher than in an NH4NO3 extract, reflecting the mobile (bioavailable) phase. The isotope composition in the latter extract corresponds well to the range found in the asparagus samples in Marchfeld, even though the concentration of Sr in asparagus shows no direct correlation to the concentration of Sr in the mobile phase of the soil. The major question was whether the 'Marchfelder Spargel' can be distinguished from samples from the neighbouring countries of Hungary and Slovakia. According to our findings, they can be clearly (100%) singled out from the Hungarian samples and can be distinguished from the Slovakian asparagus samples with a probability of more than 80%. PMID:17874075

  15. Sr-Nd isotopic composition of lamprophyre dykes from Queen Maud Land, East Antarctica

    Alkali basaltic-lamprophyric dykes intrude precambrian gneisses in the Schirmacher oasis, Queen Maud land, East Antarctica. Rb-Sr and Sm-Nd isotopic data on two lamprophyre dykes are reported from the Schirmacher oasis. The lamprophyre dykes have given Rb-Sr biotite/whole rock isochron age of 439 ± 10 Ma (2σ). Large variations in εSr and εNd indicate higher degree of crustal assimilation. Higher εSr (+54 to +72) and lower εNd (-7 to -13) of these dykes also suggest that the source was contaminated by older crust. Biotite/whole rock Rb-Sr isotope data on lamprophyre dykes show that the terrain was affected by thermal event during early paleozoic which is correlated with the end of Pan-African orogeny. (author)

  16. Geochemistry Meets Anthropology: the use of Sr Isotopes as Tracers for Ancient Human Migration.

    Solis, G.; Schaaf, P.; Hernandez, T.; Horn, P.; Manzanilla, L.

    2005-12-01

    Sr isotopes have increasingly become an important tool in archeology and anthropology in determining provenance of humans. By comparing isotopic signatures of human teeth and bone with the soil environment, Sr isotope ratios have been used as tracers identifying living areas. Sr isotope ratios in tooth enamel reflect the source of diet during youth, whereas ratios in dentine and bones come from the food growing in local geologies around the time of death. However, since analytical procedures vary from lab to lab we present here our new technique and how it affects results. We studied 11 teeth and 12 bone samples from the archeological site of Teotihuacan, central Mexico, as well as soil and water from the locality. Mechanical sample preparation of all teeth involved isolation of the enamel layer with the aid of an orthodontical micro-tool. For some enamel samples up to three fractions (two leachates and residue) were obtained for measurement. Thoroughly cleaned bone material underwent no leaching. As an example, 87Sr/86Sr results from a sample with ratios of 0.70477 for bone (which is identical to highland soil), 0.70530 for first leachate, 0.70590 for second leachate, and 0.70668 (mean accuracy +/- 0.00004) for enamel, clearly show enamel contamination by mobile Sr probably from soil. We thus find that repeated cleaning and particularly repeated leaching procedures, including isotopic measurement of the leachates, are critical to differentiate primary from secondary Sr isotope ratios as product of interaction of soil, sediments and water from the substrate where burials took place.

  17. Re-evaluation of interferences of doubly charged ions of heavy rare earth elements on Sr isotopic analysis using multi-collector inductively coupled plasma mass spectrometry

    We re-evaluate the interference of doubly charged heavy rare earth elements during Sr isotopic analysis using multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). A series of mixed solutions of standard reference material SRM 987, rare earth elements, and Sr separated from rock reference materials are measured to assess the influence of isobaric interferences on the MC-ICP-MS analysis of Sr isotopes. After sample dissolution, conventional cation-exchange chromatography is employed for Sr purification of rock reference materials prior to MC-ICP-MS measurement. It has been demonstrated that if the natural abundances of Er and Yb are used to correct for doubly charged ion interferences on Sr, an overcorrection results. In contrast, the use of measured doubly charged ion ratios results in an accurate and precise correction of isobaric interference. This finding is confirmed by analytical results for several certified reference materials from mafic (basaltic) to felsic (granitic) silicate rocks. It is noteworthy that, because Er is more prone to doubly charged ion formation, it dominates over Yb doubly charged ions as an interference source. - Highlights: • We re-investigated interference of doubly charged HREE ion on Sr isotope. • Natural abundance of Er and Yb to correct the interference leads to an overcorrection. • Er is more prone to doubly charged ion formation than Yb

  18. Modelling the Phanerozoic carbon cycle and climate - Constraints from the Sr-87/Sr-86 isotopic ratio of seawater

    Francois, Louis M.; Walker, James C. G.

    1992-01-01

    A numerical model is developed for simulating the long-term changes of atmospheric CO2 and climate during the Phanerozoic. The model describes the coupled evolution of the biogeochemical cycles of C, S, Ca, Mg, P, and Sr, with the emphasis on the effect of coupling the cycles of carbon and strontium and on interpreting the observed seawater Sr-87/Sr-86 ratios. The abilities of continental weathering, volcanism, and surface lithology in generating that signal are tested and compared. The results obtained are used to reconstruct a history of atmospheric CO2 and climate during Phanerozoic time, consistent with the strontium isotopic data. It is shown that the predicted history is compatible with paleoclimatic indicators, such as the timing of glaciation and the estimates of Cretaceous paleotemperatures.

  19. Tracking selenium in the Chalk aquifer of northern France: Sr isotope constraints

    Highlights: • We report the chemistry of the Chalk groundwater affected by Se contamination. • Strontium isotopes were used to identify the groundwater bodies and their mixings. • The spatial and temporal Se variability is mainly linked to the presence of Se-rich clays. • Saturation or desaturation of Se-rich clays control Se mobility. - Abstract: Groundwater at the southern and eastern edges of France’s Paris Basin has a selenium content that at times exceeds the European Framework Directive’s drinking-water limit value of 10 μg/L. To better understand the dynamics of the Chalk groundwater being tapped to supply the city of Lille and the Se origins, we used a combination of geochemical and isotopic tools. Strontium isotopes, coupled with Ca/Sr, Mg/Sr and Se/Sr ratios, were used to identify the main groundwater bodies and their mixings, with the Mg/Sr and Se/Sr ratios constraining a ternary system. Groundwater in the agricultural aquifer-recharge zone represents a first end-member and displays the youngest water ages of the catchment along with the highest Sr isotopic signature (0.70842) and low Se contents. Anaerobic groundwater constitutes a second major end-member affected by water-rock interactions over a long residence time, with the lowest Sr isotopic signature (0.70789) and the lowest Se content, its low SF6 content confirming the contribution of old water. Se-rich groundwater containing up to 30 μg/L of Se represents a third major end-member, with an intermediate Sr isotopic ratio (0.70826), and is mainly constrained by the clayey Se-rich formation overlying the Chalk aquifer. The spatial and temporal Se variability in the groundwater is clearly linked to the presence of this formation identified as Tertiary and also to the hydrological conditions; saturation of the Se-rich clays by oxygenated groundwater enhances Se mobility and also Sr adsorption onto the clays. This multi-tool study including Sr isotopes successfully identified the Se

  20. Sr Isotopes and human skeletal remains, improving a methodological approach in migration studies

    Solis Pichardo, G.; Schaaf, P. E.; Hernandez, T.; Horn, P.; Manzanilla, L. R.

    2013-12-01

    Asserting mobility of ancient humans is a major issue for anthropologists. Sr isotopes are widely used in anthropological sciences to trace human migration histories from ancient burials. Sr in bone approximately reflects the isotopic composition of the geological region where the person lived before death; whereas the Sr isotopic system in tooth enamel is thought to remain as a closed system and thus conserves the isotope ratio acquired during childhood. A comparison of the 87Sr/86Sr ratios found in tooth enamel and in bone is performed to determine if the human skeletal remains belonged to a local or a migrant. Until now, tooth enamel was considered to be less sensitive to secondary Sr contamination due to its higher crystallinity and larger sizes of the biogenic apatites in comparison to that in bone and dentine. In the past, enamel as well as bone material was powdered, dissolved and analyzed by thermal ionization mass spectrometry (TIMS). In this contribution we show, however, that simple dissolution of enamel frequently yields erroneous results. Tooth enamel is often affected by secondary strontium contamination processes such as caries or diagenetic and environmental input, which can change the original isotopic composition. To avoid these problems we introduced a pre-treatment and three-step leaching procedure in enamel samples. Leaching is carried out with acetic acid of different concentrations, yielding two leachates and one residue of each sample. Frequently the 87Sr/86Sr results of the three leachates display different values confirming that secondary contamination did occur. Several examples from Teotihuacan, central Mexico demonstrate that enamel 87Sr/86Sr without leaching can show correct biogenic values, but there is also a considerable probability for these values to represent a mixture of original and secondary Sr without significance for migration reconstructions. Only the residue value is interpreted by us as the representative ratio for

  1. Ca-Mg-Sr-Nd Isotopes in Granitic Rocks of the Lhasa Terrane, Southern Tibet

    Peterson, B. T.; Simon, J. I.; Depaolo, D. J.; Christensen, J. N.; Harrison, T. M.

    2010-12-01

    Magnesium (Mg) and Calcium (Ca) isotopes are fractionated by aqueous precipitation and incongruent silicate weathering, resulting in sedimentary reservoirs with characteristic isotopic compositions. Limestones and dolomites are isotopically light in both elements, whereas shales/pelites can have heavy Mg and light Ca. The isotopic character of these reservoirs may persist through anatexis (Shen, et al., PNAS 106(49), 2009). Mg and Ca isotopes could therefore be used to gain new insights into the sources of granitic magmas and hence the mechanisms by which the continental crust forms and evolves. Radiogenic 40Ca gives additional information about the K/Ca ratios of magma sources, and Sr and Nd isotopes provide complementary age and lithology information. To evaluate the potential of Ca and Mg isotopes for studying granite petrogenesis we made measurements on a suite of granitic intrusive rocks of Jurassic to Miocene age in southern Tibet that exhibit large variations in Nd (ɛNd = +5 to -12) and Sr isotopes (87Sr/86Sr = 0.704 to 0.722). Our samples represent a transect northward from the Indus-Yalu Suture (IS), west of Lhasa. Rocks close to the IS have mantle-like Nd and Sr isotopic compositions, whereas those farther to the north have low ɛNd and higher 87Sr/86Sr, and include Mesozoic, Paleogene and Neogene peraluminous (2-mica) granites (DePaolo, et al., Goldschmidt, 2008; Kapp, et al., JGR 110, 2005; Hou et al., EPSL 220, 2004). Radiogenic 40Ca is detectable in peraluminous (2-mica) granites and correlates with high 87Sr/86Sr, but does not correlate with Nd isotopes, indicating that 2-mica granite magmas come from both low-K and high-K sources. Stable isotopes of both Ca and Mg show substantial variation. Relative to bulk silicate Earth (BSE, which we define as δ=0 for discussion) δ44Ca values vary from 0 to -0.7, and δ26Mg varies from -0.3 to +0.6. Thus to first order Ca is light and Mg is heavy relative to BSE. For samples with mantle-like Nd and Sr, δ44Ca

  2. Accurate γ-ray spectrometry measurements of the half-life of 92Sr

    Studies of the nuclear fuel cycle require an accurate knowledge of the energy release from the decay of radioactive nuclides produced in a reactor, including precise half-life data for the short-lived radionuclides. Moreover, short-lived fission products are crucial for fission rate distribution measurements performed in low-power facilities, such as EOLE and MINERVE of CEA Cadarache [Fougeras, P., 2005. EOLE, MINERVE and MASURCA facilities and their associated neutron experimental programs. In: 13th International Conference on Nuclear Engineering, Beijing, China, 16-20 May 2005], and their nuclear decay data need to be known to high precision. For these reasons, the half-life of 92Sr has been measured to solve a recently observed inconsistency identified with the quoted value in the main nuclear applications libraries (including JEFF3.1): T1/2=2.71±0.01 h [Parsa, B., Ashari, A., Goolvard, L., Nobar, Y.M., 1971. Decay scheme of 2.71 h 92Sr. Nucl. Phys. A 175, 629-640]. An overestimation of 4.5% has been identified in this work, based on two independent methods. Specific γ-ray spectrometry measurements on activated fissile foils have been carried out, using two HPGe detectors. Influencing factors such as net area measurements of photopeaks, pulse pile-up accuracy and dead time corrections in the presence of decaying activity are discussed. A new value has been obtained by combining eight series of measurements: T1/2=2.594 0.006 h. The uncertainty has been reduced by a factor of two with respect to previous evaluations. This measured value also shows good agreement with the most recent studies of T1/2=2.627±0.009 h [Nir-El, Y., 2003. Private Communications. Soreq Research Centre, Yavne, Israel

  3. Accurate gamma-ray spectrometry measurements of the half-life of 92Sr.

    Leconte, P; Hudelot, J P; Antony, M

    2008-10-01

    Studies of the nuclear fuel cycle require an accurate knowledge of the energy release from the decay of radioactive nuclides produced in a reactor, including precise half-life data for the short-lived radionuclides. Moreover, short-lived fission products are crucial for fission rate distribution measurements performed in low-power facilities, such as EOLE and MINERVE of CEA Cadarache [Fougeras, P., 2005. EOLE, MINERVE and MASURCA facilities and their associated neutron experimental programs. In: 13th International Conference on Nuclear Engineering, Beijing, China, 16-20 May 2005], and their nuclear decay data need to be known to high precision. For these reasons, the half-life of (92)Sr has been measured to solve a recently observed inconsistency identified with the quoted value in the main nuclear applications libraries (including JEFF3.1): T(1/2)=2.71+/-0.01 h [Parsa, B., Ashari, A., Goolvard, L., Nobar, Y.M., 1971. Decay scheme of 2.71 h (92)Sr. Nucl. Phys. A 175, 629-640]. An overestimation of 4.5% has been identified in this work, based on two independent methods. Specific gamma-ray spectrometry measurements on activated fissile foils have been carried out, using two HPGe detectors. Influencing factors such as net area measurements of photopeaks, pulse pile-up accuracy and dead time corrections in the presence of decaying activity are discussed. A new value has been obtained by combining eight series of measurements: T(1/2)=2.594+/-0.006 h. The uncertainty has been reduced by a factor of two with respect to previous evaluations. This measured value also shows good agreement with the most recent studies of T(1/2)=2.627+/-0.009 h [Nir-El, Y., 2003. Private Communications. Soreq Research Centre, Yavne, Israel]. PMID:18456504

  4. Sr Isotopic Evidence on the Spilitic Degradation of the Deccan Basalt

    K V Subbarao

    2000-03-01

    Similar Sr isotopic ratios (∼0.7055) for the tholeiite-spilite flow unit and the associated mineral phases, of Bombay (Deccan Traps) provide a direct evidence for the spilitic degradation of tholeiite. In contrast, a dramatic increase in the rare earth elements (REE) from basalt to spilite is rather puzzling as rare earths are considered to be relatively immobile. The geochemistry thus suggests that the process of spilitization is due to the reaction with a complex fluid having identical Sr-isotopic composition as that of the basaltic magma - thereby masking the details of the mixing process.

  5. Some Pb and Sr isotopic measurements on eclogites from the Roberts Victor Mine, South Africa.

    Manton, W. I.; Tatsumoto, M.

    1971-01-01

    Five nodules of eclogite, one nodule of garnet peridotite, and one sample of kimberlite from the Roberts Victor Mine in the Orange Free State were analyzed for concentrations of U, Th, Pb, Rb, and Sr, and also isotopic compositions of Pb and Sr. Results are presented and analyzed. They indicate that the Roberts Victor eclogites have been contaminated by lead from the host rock of kimberlite. This finding suggests that stepwise extraction of lead may be a means of obtaining the isotopic composition of the primary lead in kimberlitic eclogites.

  6. Charge radii and structural evolution in Sr, Zr, and Mo isotopes

    Rodriguez-Guzman, R.; Sarriguren, P.; Robledo, L. M.; Perez-Martin, S.

    2010-01-01

    The evolution of the ground-state nuclear shapes in neutron-rich Sr, Zr, and Mo isotopes, including both even-even and odd-A nuclei, is studied within a self-consistent mean-field approximation based on the D1S Gogny interaction. Neutron separation energies and charge radii are calculated and compared with available data. A correlation between a shape transition and a discontinuity in those observables is found microscopically. While in Sr and Zr isotopes the steep behavior observed in the is...

  7. Geothermal waters from the Taupo Volcanic Zone, New Zealand: Li, B and Sr isotopes characterization

    Chemical and isotopic data for 23 geothermal water samples collected in New Zealand within the Taupo Volcanic Zone (TVZ) are reported. Major and trace elements including Li, B and Sr and their isotopic compositions (δ7Li, δ11B, 87Sr/86Sr) were determined in high temperature geothermal waters collected from deep boreholes in different geothermal fields (Ohaaki, Wairakei, Mokai, Kawerau and Rotokawa geothermal systems). Lithium concentrations are high (from 4.5 to 19.9 mg/L) and Li isotopic compositions (δ7Li) are homogeneous, ranging between −0.5‰ and +1.4‰. In particular, it is noteworthy that, except for the samples from the Kawerau geothermal field having slightly higher δ7Li values (+1.4%), the other geothermal waters have a near constant δ7Li signature around a mean value of 0‰ ± 0.6 (2σ, n = 21). Boron concentrations are also high and relatively homogeneous for the geothermal samples, falling between 17.5 and 82.1 mg/L. Boron isotopic compositions (δ11B) are all negative, and display a range between −6.7‰ and −1.9‰. These B isotope compositions are in agreement with those of the Ngawha geothermal field in New Zealand. Lithium and B isotope signatures are in a good agreement with a fluid signature mainly derived from water/rock interaction involving magmatic rocks with no evidence of seawater input. On the other hand, Sr concentrations are lower and more heterogeneous and fall between 2 and 165 μg/L. The 87Sr/86Sr ratios range from 0.70549 to 0.70961. These Sr isotope compositions overlap those of the Rotorua geothermal field in New Zealand, confirming that some geothermal waters (with more radiogenic Sr) have interacted with bedrocks from the metasedimentary basement. Each of these isotope systems on their own reveals important information about particular aspects of either water source or water/rock interaction processes, but, considered together, provide a more integrated understanding of the geothermal systems from the TVZ in New

  8. Stable Strontium Isotopes (δ88/86Sr) As a Tracer of Sr Sources and Biogeochemical Cycling in Two Catchments Draining Fiordland, New Zealand

    Andrews, G.; Jacobson, A. D.; Lehn, G. O.

    2014-12-01

    To understand how Sr isotopes behave during chemical weathering and biogeochemical cycling, we analyzed the stable Sr isotope composition (δ88/86Sr) of rivers, rocks, sediments, plants, and soils from the Cleddau and Hollyford catchments in Fiordland, New Zealand. We leached rocks, sediments, and soils to isolate relatively soluble Sr sources. δ88/86Sr values were measured using an 87Sr-84Sr double-spike MC-TIMS method, which was optimized according to the Monte Carlo error model described in Lehn et al. (2013). The long-term, external reproducibility of the method is ±0.020‰ (2σSD) based on repeated measurements of NBS-987 [δ88/86Sr = 0.000 ± 0.004‰ (2σSEM), n=77] and IAPSO seawater [δ88/86Sr = 0.396 ± 0.005‰ (2σSEM), n=54]. Although the study site receives abundant rainfall (6700mm/yr), atmospheric inputs of Sr are negligible. We find that δ88/86Sr values can distinguish between silicate- versus carbonate- derived riverine Sr sources when traditional tracers, such as radiogenic Sr isotope (87Sr/86Sr) and molar Ca/Sr ratios, are equivocal. Moreover, rivers draining gabbro bedrock in the Cleddau and Upper Hollyford catchments have higher δ88/86Sr values (0.368‰) as compared to bulk silicate rock (0.162 - 0.284‰) and sediment (0.286‰). In the Lower Hollyford catchment, tributary rivers draining volcanic and sedimentary rocks also have higher δ88/86Sr values (0.328‰) as compared to bulk silicate rock (0.177‰) and sediment (0.260‰). We examine several hypotheses to explain the elevated riverine δ88/86Sr values, including end-member mixing, fractionation during chemical weathering, and plant uptake. We attribute the riverine δ88/86Sr values to mixing with the soil pore water pool, which is isotopically heavy due to preferential uptake of 86Sr by plants.

  9. Signatures of structural changes in neutron-rich Sr, Zr and Mo isotopes

    The evolution of the ground-state nuclear shapes in neutron-rich Sr, Zr, and Mo isotopes, including both even-even and odd-A nuclei, is discussed within the mean-field approximation based on the Gogny-D1S Gogny Energy Density Functional. Calculations for neutron separation energies and charge radii are presented and compared with available data. A correlation between a shape transition and a discontinuity in those observables is found within our microscopic framework. It is shown that, while in Sr and Zr isotopes the steep behavior observed in the isotopic dependence of the charge radii is a consequence of a sharp prolate-oblate transition, the smooth behavior found in Mo isotopes has its origin in an emergent region of triaxiality.

  10. Charge radii and structural evolution in Sr, Zr, and Mo isotopes

    Rodriguez-Guzman, R; Robledo, L M; Perez-Martin, S

    2010-01-01

    The evolution of the ground-state nuclear shapes in neutron-rich Sr, Zr, and Mo isotopes, including both even-even and odd-A nuclei, is studied within a self-consistent mean-field approximation based on the D1S Gogny interaction. Neutron separation energies and charge radii are calculated and compared with available data. A correlation between a shape transition and a discontinuity in those observables is found microscopically. While in Sr and Zr isotopes the steep behavior observed in the isotopic dependence of the charge radii is a consequence of a sharp prolate-oblate transition, the smooth behavior found in Mo isotopes has its origin in an emergent region of triaxiality.

  11. Identification of Marchfeld asparagus using Sr isotope ratio measurements by MC-ICP-MS

    Swoboda, S.; Brunner, M.; Boulyga, S.F.; Galler, P.; Prohaska, T. [University of Natural Resources and Applied Life Sciences, Department of Chemistry-VIRIS Project, Vienna (Austria); Horacek, M. [Austrian Research Centers GmbH, Seibersdorf (Austria)

    2008-01-15

    This work focuses on testing and application of Sr isotope signatures for the fast and reliable authentication and traceability of Asparagus officinalis originating from Marchfeld, Austria, using multicollector inductively coupled plasma mass spectrometry after optimised Rb/Sr separation. The major sample pool comprises freeze-dried and microwave-digested asparagus samples from Hungary and Slovakia which are compared with Austrian asparagus originating from the Marchfeld region, which is a protected geographical indication. Additional samples from Peru, the Netherlands and Germany were limited in number and allowed therefore only restricted statistical evaluation. Asparagus samples from Marchfeld were harvested within two subsequent years in order to investigate the annual variation. The results show that the Sr isotope ratio is consistent within these 2 years of investigation. Moreover, the Sr isotope ratio of total Sr in soil was found to be significantly higher than in an NH{sub 4}NO{sub 3} extract, reflecting the mobile (bioavailable) phase. The isotope composition in the latter extract corresponds well to the range found in the asparagus samples in Marchfeld, even though the concentration of Sr in asparagus shows no direct correlation to the concentration of Sr in the mobile phase of the soil. The major question was whether the 'Marchfelder Spargel' can be distinguished from samples from the neighbouring countries of Hungary and Slovakia. According to our findings, they can be clearly (100%) singled out from the Hungarian samples and can be distinguished from the Slovakian asparagus samples with a probability of more than 80%. (orig.)

  12. Sr Isotopes and Migration of Prairie Mammoths (Mammuthus columbi) from Laguna de las Cruces, San Luis Potosi, Mexico

    Solis-Pichardo, G.; Perez-Crespo, V.; Schaaf, P. E.; Arroyo-Cabrales, J.

    2011-12-01

    Asserting mobility of ancient humans is a major issue for anthropologists. For more than 25 years, Sr isotopes have been used as a resourceful tracer tool in this context. A comparison of the 87Sr/86Sr ratios found in tooth enamel and in bone is performed to determine if the human skeletal remains belonged to a local or a migrant. Sr in bone approximately reflects the isotopic composition of the geological region where the person lived before death; whereas the Sr isotopic system in tooth enamel is thought to remain as a closed system and thus conserves the isotope ratio acquired during childhood. Sr isotope ratios are obtained through the geologic substrate and its overlying soil, from where an individual got hold of food and water; these ratios are in turn incorporated into the dentition and skeleton during tissue formation. In previous studies from Teotihuacan, Mexico we have shown that a three-step leaching procedure on tooth enamel samples is important to assure that only the biogenic Sr isotope contribution is analyzed. The same Sr isotopic tools can function concerning ancient animal migration patterns. To determine or to discard the mobility of prairie mammoths (Mammuthus columbi) found at Laguna de las Cruces, San Luis Potosi, México the leaching procedure was applied on six molar samples from several fossil remains. The initial hypothesis was to use 87Sr/86Sr values to verify if the mammoth population was a mixture of individuals from various herds and further by comparing their Sr isotopic composition with that of plants and soils, to confirm their geographic origin. The dissimilar Sr results point to two distinct mammoth groups. The mammoth population from Laguna de Cruces was then not a family unit because it was composed by individuals originated from different localities. Only one individual was identified as local. Others could have walked as much as 100 km to find food and water sources.

  13. Development of high through-put Sr isotope analysis for monitoring reservoir integrity for CO{sub 2} storage.

    Wall, Andy; Jain, Jinesh; Stewart, Brian; Capo, Rosemary; Hakala, Alexandra J.; Hammack, Richard; Guthrie, George

    2012-01-01

    Recent innovations in multi-collector ICP-mass spectrometry (MC-ICP-MS) have allowed for rapid and precise measurements of isotope ratios in geological samples. Naturally occurring Sr isotopes has the potential for use in Monitoring, Verification, and Accounting (MVA) associated with geologic CO2 storage. Sr isotopes can be useful for: Sensitive tracking of brine migration; Determining seal rock leakage; Studying fluid/rock reactions. We have optimized separation chemistry procedures that will allow operators to prepare samples for Sr isotope analysis off site using rapid, low cost methods.

  14. Sr isotope composition of atmospheric mineral dust at Ahmedabad: provenance and seasonal variability

    Atmospheric aerosol has profound impact on global climate, biogeochemical cycles and human health. Mineral dust is one of the major components in the aerosol budget which comprise ∼ 35% of total global aerosol emission. Asian dust production is estimated to be about 800 Tg / year, which is almost half of world mineral dust emission. To improve our understanding of their sources, transport, deposition and biogeochemical impact, a comprehensive study involving chemical and isotopic composition of ambient aerosols is essential. Towards this, Sr isotopic compositions of ambient aerosol at Ahmedabad, a representative location in semi-arid region in western India, are measured since they are powerful finger print for identifying mineral dust sources and undergo insignificant alteration during transport and atmospheric processes. Ambient aerosol samples were collected using high-volume sampler with an inlet size cut off 10 μm diameter on quartz filters (8x10 inch) during 2007-2008. One fourth of the filter samples were cut and leached with 0.6N HCI to remove carbonate/labile fraction. The remaining fraction is digested with con. HF + HNO3 mixture two times and subsequently with cone. HCI + HNO3 mixture. The dried residue is taken in 0.16 N HCI and passed on Biorad AG-50w-8x resin column to separate Sr. The Sr fraction is collected and evaporated. The residue is dissolved in 0.4 NHO3 and analyzed for 87Sr/86Sr on MC-ICP-MS. Sr isotopic composition at Ahmedabad exhibits significant seasonal variation indicating pronounced temporal variability in dust sources and transport in this region. Soil derived from Decan basalt is the major dust source from western and southern region of sampling location with characteristic 87Sr/86Sr ratio 87Sr/86Sr ∼0.75. The seasonal variation in Sr isotopic composition in an annual cycle reflects the differences in source region of mineral aerosol consistent with synoptic scale wind direction over this region and demonstrates that there is

  15. The Rb-Sr isotope system as an index of origin and diagenetic evolution of southern Pacific red clays

    Morphological, mineralogical, chemical and Rb-Sr isotopic studies have been made on Fe-smectites (nontronites) from southern Pacific red clays cored near the Marquisas Islands. These minerals have at the top of the core, an 87Sr/86Sr ratio of 0.70917 +- 0.00007, which indicates an authigenic origin in isotopic equilibrium with seawater. Weak leaching experiments with 1N HCl show that the nontronites also contain a volcanic component with a lower 87Sr/86Sr ratio which, combined with the morphology of the particles, suggests a transportation by bottom currents of clay formed elsewhere. During burial, the nontronites experience diagenetic modifications resulting in an increase in Fe, K and Rb contents, a concomitant decrease of Mg, Ca, Ti, Na and Sr, and a preferential migration of radiogenic 87Sr from the clays into the surrounding pore waters. The 87Sr/86Sr ratio of the Sr adsorbed on the outermost surfaces of the nontronites does not change with depth in the core, and is, therefore, independent of diagenetic influence, which is rather characterized by the 87Sr/86Sr ratios of the interstitial waters. The isotopic composition of both the adsorbed Sr and that of the pore fluids may yield useful information on the crystallization environment and subsequent history of deep sea red clays. (author)

  16. Sr isotope tracing of multiple water sources in a complex river system, Noteć River, central Poland.

    Zieliński, Mateusz; Dopieralska, Jolanta; Belka, Zdzislaw; Walczak, Aleksandra; Siepak, Marcin; Jakubowicz, Michal

    2016-04-01

    Anthropogenic impact on surface waters and other elements in the environment was investigated in the Noteć River basin in central Poland. The approach was to trace changes in the Sr isotope composition ((87)Sr/(86)Sr) and concentration in space and time. Systematic sampling of the river water shows a very wide range of (87)Sr/(86)Sr ratios, from 0.7089 to 0.7127. This strong variation, however, is restricted to the upper course of the river, whereas the water in the lower course typically shows (87)Sr/(86)Sr values around 0.7104-0.7105. Variations in (87)Sr/(86)Sr are associated with a wide range of Sr concentrations, from 0.14 to 1.32mg/L. We find that strong variations in (87)Sr/(86)Sr and Sr concentrations can be accounted for by mixing of two end-members: 1) atmospheric waters charged with Sr from the near-surface weathering and wash-out of Quaternary glaciogenic deposits, and 2) waters introduced into the river from an open pit lignite mine. The first reservoir is characterized by a low Sr content and high (87)Sr/(86)Sr ratios, whereas mine waters display opposite characteristics. Anthropogenic pollution is also induced by extensive use of fertilizers which constitute the third source of Sr in the environment. The study has an important implication for future archeological studies in the region. It shows that the present-day Sr isotope signatures of river water, flora and fauna cannot be used unambiguously to determine the "baseline" for bioavailable (87)Sr/(86)Sr in the past. PMID:26802358

  17. A depleted mantle source for kimberlites from Zaire: Nd, Sr and Pb isotopic evidence

    Nd and Sr isotopic compositions in kimberlites from Zaire indicate a time-integrated depleted mantle source (epsilonsub(Nd)=+6 to +2 and 87Sr/86Sr=0.7040). Slight upper crust contamination is reflected only by the Pb isotopic system. Differences in the isotopic compositions of kimberlites from two kimberlite provinces, Mbuji Mayi and Kundelungu, point to the existence of regional heterogeneities in the subcontinental mantle, with a range comparable to that observed in the suboceanic mantle. This suggests that the deep mantle (asthenosphere) has comparable chracteristics under the oceans and under the continents. Cr-diopside megacrysts, with a more depleted signature (epsilonsub(Nd)=+6.5 and 87Sr/86Sr=0.7030) than their host kimberlites, could either be xenocrysts derived from a higher level within the mantle and incorporated during the ascent of the kimberlites or, alternatively to an early crystallization stage from a ''proto-kimberlitic magma'' which was subseqently mixed with an enriched mantle component. These data preclude a primary undifferentiated mantle from being the source of these kimberlites. (orig.)

  18. Stable Isotopes of Sr and Pb as Tracers of Sources of Airborne Particulate Matter in Kyrgyzstan

    ConclusionsElemental concentrations were higher at the LIDAR site compared to the Bishkek site. Also, concentrations were higher during dust than non-dust events at both sites.The Sr isotopic ratios suggest dust from another region, such as from Western China, Africa, or Middle E...

  19. Ca, Sr and Ba stable isotopes reveal the fate of soil nutrients along a tropical climosequence

    Bullen, Thomas D.; Chadwick, Oliver A.

    2016-01-01

    Nutrient biolifting is an important pedogenic process in which plant roots obtain inorganic nutrients such as phosphorus (P) and calcium (Ca) from minerals at depth and concentrate those nutrients at the surface. Here we use soil chemistry and stable isotopes of the alkaline earth elements Ca, strontium (Sr) and barium (Ba) to test the hypothesis that biolifting of P has been an important pedogenic process across a soil climosequence developed on volcanic deposits at Kohala Mountain, Hawaii. The geochemical linkage between these elements is revealed as generally positive site-specific relationships in soil mass gains and losses, particularly for P, Ba and Ca, using the ratio of immobile elements titanium and niobium (Ti/Nb) to link individual soil samples to a restricted compositional range of the chemically and isotopically diverse volcanic parent materials. At sites where P is enriched in surface soils relative to abundances in deeper soils, the isotope compositions of exchangeable Ca, Sr and Ba in the shallowest soil horizons (isotope composition of exchangeable Ba in deeper soil horizons (> 10 cm depth) at those sites is consistently heavier than the volcanic parent materials. The isotope compositions of exchangeable Ca and Sr trend toward heavier compositions with depth more gradually, reflecting increasing leakiness from these soils in the order Ba isotopically light exchangeable Ca, Sr and Ba in the shallowest soil horizons requires that the uptake flux to plants from those near-surface layers is less than the recycling flux returned to the surface as litterfall. This observation implicates an uptake flux from an additional source which we attribute to biolifting. We view the heavy exchangeable Ba relative to soil parent values in deeper soils at sites where P is enriched in surface soils, and indeed at all but the wettest site across the climosequence, to represent the complement of an isotopically light Ba fraction removed from these soils by plant

  20. Sea level and climate forcing of the Sr isotope composition of late Miocene Mediterranean marine basins

    Schildgen, T. F.; Cosentino, D.; Frijia, G.; Castorina, F.; Dudas, F. Ö.; Iadanza, A.; Sampalmieri, G.; Cipollari, P.; Caruso, A.; Bowring, S. A.; Strecker, M. R.

    2014-07-01

    isotope records from marginal marine basins track the mixing between seawater and local continental runoff, potentially recording the effects of sea level, tectonic, and climate forcing in marine fossils and sediments. Our 110 new 87Sr/86Sr analyses on oyster and foraminifera samples from six late Miocene stratigraphic sections in southern Turkey, Crete, and Sicily show that 87Sr/86Sr fell below global seawater values in the basins several million years before the Messinian Salinity Crisis, coinciding with tectonic uplift and basin shallowing. 87Sr/86Sr from more centrally located basins (away from the Mediterranean coast) drop below global seawater values only during the Messinian Salinity Crisis. In addition to this general trend, 55 new 87Sr/86Sr analyses from the astronomically tuned Lower Evaporites in the central Apennines (Italy) allow us to explore the effect of glacio-eustatic sea level and precipitation changes on 87Sr/86Sr. Most variation in our data can be explained by changes in sea level, with greatest negative excursions from global seawater values occurring during relative sea level lowstands, which generally coincided with arid conditions in the Mediterranean realm. We suggest that this greater sensitivity to lowered sea level compared with higher runoff could relate to the inverse relationship between Sr concentration and river discharge. Variations in the residence time of groundwater within the karst terrain of the circum-Mediterranean region during arid and wet phases may help to explain the single (robust) occurrence of a negative excursion during a sea level highstand, but this explanation remains speculative without more detailed paleoclimatic data for the region.

  1. The use of Pb, Sr, and Hg isotopes in Great Lakes precipitation as a tool for pollution source attribution

    The anthropogenic emission and subsequent deposition of heavy metals including mercury (Hg) and lead (Pb) present human health and environmental concerns. Although it is known that local and regional sources of these metals contribute to deposition in the Great Lakes region, it is difficult to trace emissions from point sources to impacted sites. Recent studies suggest that metal isotope ratios may be useful for distinguishing between and tracing source emissions. We measured Pb, strontium (Sr), and Hg isotope ratios in daily precipitation samples that were collected at seven sites across the Great Lakes region between 2003 and 2007. Lead isotope ratios (207Pb/206Pb = 0.8062 to 0.8554) suggest that Pb deposition was influenced by coal combustion and processing of Mississippi Valley-Type Pb ore deposits. Regional differences in Sr isotope ratios (87Sr/86Sr = 0.70859 to 0.71155) are likely related to coal fly ash and soil dust. Mercury isotope ratios (δ202Hg = − 1.13 to 0.13‰) also varied among the sites, likely due to regional differences in coal isotopic composition, and fractionation occurring within industrial facilities and in the atmosphere. These data represent the first combined characterization of Pb, Sr, and Hg isotope ratios in precipitation collected across the Great Lakes region. We demonstrate the utility of multiple metal isotope ratios in parallel with traditional trace element multivariate statistical modeling to enable more complete pollution source attribution. - Highlights: • We measured Pb, Sr, and Hg isotopes in precipitation from the Great Lakes region. • Pb isotopes suggest that deposition was impacted by coal combustion and metal production. • Sr isotope ratios vary regionally, likely due to soil dust and coal fly ash. • Hg isotopes vary due to fractionation occurring within facilities and the atmosphere. • Isotope results support conclusions of previous trace element receptor modeling

  2. Initial Sr-isotope, dating and ancillary geochemical studies on kimberlite and associated inclusions

    The feasibility of dating the time of pipe intrusions by the Rb-Sr method was first considered. However, the main objective was to investigate the limitations imposed by Sr isotopic evidence (and ancillary elemental abundance data) on the nature and genesis of kimberlite. Measurements, mainly by mass spectroscopy, of K, Rb and Sr isotopic ratios were made on kimberlite whole rocks (16 samples), peridotite and eclogite nodules (12 samples), mineral concentrates from the above rock types, and phlogopite and diopside nodules (94 mica and other separates, mainly clinopyroxenes), pipe wall rocks (6 whole rocks and 5 separated muscovites) and ground waters (6 samples). Studies on phlogopite micas which occur in kimberlite groundmass and associated peridotite and eclogite inclusions suggest that valid ages for pipe emplacement may be obtained by the Rb-Sr isochron method. Phlogopite nodule samples give anomalous results due to radiogenic Sr retention. Results for the following pipes are reported: Wesselton, Du Toitspan, De Beers, Bultfontein and Monastery (mean age 86 plus minus 3 m.y.); Roberts Victor (127 plus minus 3 m.y., possibly less reliable); Swartruggens (147 plus minus 4 m.y.); Gross Brukkaros (84 m.y. - not considered reliable); Lashaine Volcano, Tanzania (270 m.y. - tentative, pre-emplacement date). Certain samples cannot be used for dating: nodular whole rocks and garnets because they are contaminated; kimberlite and clinopyroxenes because they are insufficiently enriched in radiogenic Sr. The granite-gneiss basement wall-rock of the Kimberley pipes has an age of 2 900 m.y. An interesting outcome of the age work is the postulated existence of phlogopite calcite in the mantle. Incomplete (partial) Sr-isotopic equilibration probably occured between constituent minerals

  3. Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the southern Andes

    Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33-460S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49-540S) range for 87Sr/86Sr from 0.70280 to 0.70591 and for 143Nd/144Nd from 0.51314 to 0.51255. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have 87Sr/86Sr, 143Nd/144Nd, La/Yb, Ba/La and Hf/Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 350S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 330 and 340S, basaltic andesites and andesites have higher 87Sr/86Sr, Rb/Cs, and Hf/Lu, and lower 143Nd/144Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (540S) has Sr and Nd isotopic compositions and K/Rb and Ba/La similar to MORB. The high La/Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO2, K2O, Rb, Ba, Ba/La, and 87Sr/86Sr and decrease in MgO, Sr, K/Rb, Rb/Cs, and 143Nd/144Nd, suggesting increasingly greater degrees of fractional crystallization and associated intra-crustal contamination. (orig./SHOE)

  4. Rb-Sr isotope systematics in the magmatic rocks of the Oslo Rift

    Fifty-one different units of Oslo Rift magmatic rocks have been investigated by the Rb-Sr isotope method. Isochron ages obtained for all but three of the units vary between 295 Ma and 240 Ma. The ages from the southern segment of the rift are generally older than those from the northern segment, suggesting a northward migration of the magmatic activity time. 87Sr/86Sr initial ratios obtained for rhomb-porphyry lavas, larvikites and related rocks are compatible with a moderately LIL-depleted mantle source with a Rb/Sr ratio of about 0.04. Crustal contamination in magma chambers and/or during ascent to the surface is also demonstrated for these rocks. 72 refs., 7 figs., 3 tabs

  5. Rb-Sr isotopic and geochronological studies of the granitic rocks of Dalhousie area, Himachal Pradesh

    Rb-Sr isotopic and geochronological investigations have been carried out on the granitic rocks of Dalhousie area, Himachal Pradesh. The data give an isochron age of 316 ± 11 Ma with initial ratio of 87Sr/86Sr equal to 0.7698 ± 0.0041 based on nine samples of granitic rocks of inner or eastern band. The initial Sr ratio is quite high which indicates that the granitic rocks of inner or eastern band were formed by remobilization of older sialic rocks. The thickness of outer or western band varies from 120 m to 150 m, so it is not possible to obtain the isochron age. The data of outer or western granitic band give model ages ranging from 2045 Ma to 2158 Ma where as BN-2 and BN-3 provide model ages of 1686 Ma and 1845 Ma, respectively

  6. Conservation of (87)Sr/(86)Sr isotopic ratios during the winemaking processes of 'Red' wines to validate their use as geographic tracer.

    Marchionni, Sara; Buccianti, Antonella; Bollati, Andrea; Braschi, Eleonora; Cifelli, Francesca; Molin, Paola; Parotto, Maurizio; Mattei, Massimo; Tommasini, Simone; Conticelli, Sandro

    2016-01-01

    (87)Sr/(86)Sr has been determined in wines, musts grape juices, soils and rocks from six selected vineyards of 'Cesanese' wine area. Cesanese is a monocultivar wine from a small region characterised by different geologic substrata, a key locality to test the influence of both substratum and winemaking procedure on the (87)Sr/(86)Sr of wines. Experimental work has been performed on wines from different vintage years to check possible seasonal variations. The data reveal that (87)Sr/(86)Sr does not change through time, to validate the selection of wineries performed, and in addition no isotopic variations are observed during winemaking. Indeed, no significant isotopic variations have been observed in musts and wines. These findings reinforce the hypothesis that the isotopic signature of wines is strongly related to the bioavailable fraction of the soil rather than to its bulk. The data corroborate the possibility that Sr-isotopes of high-quality wines can be used as a reliable tool for fingerprinting wine geographic provenance. PMID:26213038

  7. Sr, Ca, and C isotope systematic in small tropical catchments, La Selva, Costa Rica

    Wiegand, B. A.; Schwendenmann, L.

    2010-12-01

    Sr, Ca, and C isotopes were analyzed to assess sources and biogeochemical processes affecting surface and groundwater composition of four small catchments located at La Selva Biological Station, Costa Rica. 87Sr/86Sr ratios were employed to quantify inputs from mineral weathering and atmospheric sources. δ13C values of dissolved organic carbon (DOC) and δ44Ca values provide information on biological processes that affect water chemistry. Sr2+ and Ca2+ concentrations of surface and groundwater show large variations due to intermixture of bedrock groundwater with local groundwater [1]. Low 87Sr/86Sr ratios suggest weathering of volcanic rocks as the primary solute source in bedrock groundwater, while atmospheric and in situ weathering contributions are predominant in local groundwater. Contributions of bedrock groundwater constitute > 60 % in the Salto, Saltito and Arboleda catchments, whereas the Taconazo catchment receives atmospheric inputs of > 95 % in addition to local weathering contributions. Surface water and groundwater wells show δ13C-DOC values between -24 ‰ and -30 ‰ due to transfer of organic carbon from the soil zone. δ44Ca values of dissolved Ca2+ in surface and groundwater are considerably fractionated from the input sources rainwater and bedrock groundwater. Light δ44Ca values are preferentially distributed in stream water and shallow groundwater horizons and contrast with heavy Ca isotopes in deeper groundwater wells. Biological processes including plant uptake and decomposition in combination with cation exchange processes in the soils may explain the fractionation of Ca isotopes. [1]Genereux et al., 2009. Water Resour. Res, 45, W08413, doi:10.1029/2008WR007630

  8. Rb-Sr and Sm-Nd Isotopic Studies of Lunar Green and Orange Glasses

    Shih, C.-Y.; Nyquist, L. E.; Reese, Y.

    2012-01-01

    Lunar volcanic glassy beads have been considered as quenched basaltic magmas derived directly from deep lunar mantle during fire-fountaining eruptions [1]. Since these sub-mm size glassy melt droplets were cooled in a hot gaseous medium during free flight [2], they have not been subject to mineral fractionations. Thus, they represent primary magmas and are the best samples for the investigation of the lunar mantle. Previously, we presented preliminary Rb- Sr and Sm-Nd isotopic results for green and orange glassy samples from green glass clod 15426,63 and orange soil 74220,44, respectively [3]. Using these isotopic data, initial Sr-87/Sr-86 and Nd ratios for these pristine mare glass sources can be calculated from their respective crystallization ages previously determined by other age-dating techniques. These isotopic data were used to evaluate the mineralogy of the mantle sources. In this report, we analyzed additional glassy samples in order to further characterize isotopic signatures of their source regions. Also, we'll postulate a relationship between these two major mare basalt source mineralogies in the context of lunar magma ocean dynamics.

  9. Identifying mantle carbonatite metasomatism through Os-Sr-Mg isotopes in Tibetan ultrapotassic rocks

    Liu, Dong; Zhao, Zhidan; Zhu, Di-Cheng; Niu, Yaoling; Widom, Elisabeth; Teng, Fang-Zhen; DePaolo, Donald J.; Ke, Shan; Xu, Ji-Feng; Wang, Qing; Mo, Xuanxue

    2015-11-01

    Mantle-derived magmas at convergent plate boundaries provide unique insights into the nature of materials subducted to and recycled from depths. Here we present a study of Os-Sr-Mg isotopes on the Oligocene-Miocene ultrapotassic rocks aimed at better understanding sediment subduction and recycling beneath southern Tibet. New isotopic data confirm that ultrapotassic rocks in southern Tibet are of mantle origin, but underwent crustal contamination as evidenced by the variably high 187Os/188Os that obviously deviates from normal mantle reservoir. Still some samples with mantle-like 187Os/188Os exhibit δ26Mg significantly lower than mantle and crustal lithologies, suggesting that the isotopically light Mg may not result from crustal contamination but retain specific fingerprint of carbonate-related metasomatism in mantle sources. Mantle carbonatite metasomatism is manifested by the inverse δ26Mg-87Sr/86Sr correlations, as well as the depletion of high field strength elements relative to rare earth elements and the enrichment of CaO in ultrapotassic rocks. The positive co-variations between δ26Mg and Hf/Sm defined by those low-187Os/188Os ultrapotassic rocks provide evidence for the potential of recycled dolomites to modify mantle Mg isotopic composition. The correlated spatial variations of δ26Mg and Hf/Sm are interpreted to reflect carbonatitic metasomatism associated with the northward subduction of the Neo-Tethyan oceanic slab and its profound influence on postcollisional ultrapotassic magmatism.

  10. Early solar system aqueous activity - Sr isotope evidence from the Orgueil CI meteorite

    Macdougall, J. D.; Lugmair, G. W.; Kerridge, J. F.

    1984-01-01

    The Sr isotopic composition and Rb-87/Sr-86 ratio have been measured in carbonates and sulfate separated from the Orgueil meteorite in order to determine the time when liquid water may have acted on the parent body. Both of the studied phases probably precipitated from aqueous solution. The results show that carbonate deposition occurred contemporaneously with parent body formation or shortly after it, probably within 100 Myr. On the other hand, at least some of the calcium sulfate seems to have been formed recently.

  11. Gamma-spectrometric determination of the sup 8 sup 9 Sr isotope half-life

    Popov, Y S; Markushin, M N; Kupriyanov, V N; Timofeev, G A

    2002-01-01

    Using the method of semiconductor [Ge(Li)-detector] gamma-spectroscopy by the results of measurements of 913 keV ( sup 8 sup 9 Sr) gamma-line intensity for 6000 h, using as internal reference the 661.7 keV ( sup 1 sup 3 sup 7 Cs) gamma-line, the value of sup 8 sup 9 Sr isotope half-life has been calculated, which proved to be 1208+-9 h or 50.34+-0.37 days. Error is provided for confidential probability P = 0.95

  12. Age and genesis of carbonatites of the Khibiny alkaline massif (Rb and Sr isotope data)

    Rubidium and strontium isotope composition in six rocks and seven carbonatite minerals of the Khibiny alkaline massif is studied, isochrone is constructed. The obtained data testify to carbonite pallial sources. Though 87Sr/86Sr primary ratio in carbonatites of the Khibiny massif significantly exceeds this value for rocks and apatite deposits of the Khibiny massif. Consanguinity and belonging of the carbonatites from the Khibiny massif to universal Paleozoic complex of ultrabasic-alkaline rocks including giant massifs of agpaitic nepheline syenites - Khibiny, Lovozero aged about 365 mln years is shown

  13. Sr and Nd isotopes of suspended sediments from rivers of the Amazon basin

    Hatting, Karina; Santos, Roberto V.; Sondag, Francis

    2014-05-01

    The Rb-Sr and Sm-Nd isotopic systems are important tools to constrain the provenance of sediment load in river systems. This study presents the isotopic composition of Sr and Nd isotopes and major and minor elements in suspended sediments from the Marañón-Solimões, Amazonas and Beni-Madeira rivers. The data were used to constrain the source region of the sediments and to better understand the main seasonal and spatial transport processes within the basin based on the variations of the chemical and isotopic signals. They also allow establishing a relationship between sediment concentrations and flow rate values. The study presents data collected during a hydrological year between 2009 and 2010. The Marañón-Solimões River presents low Sr isotopic values (0.7090-0.7186), broad EpslonNd(0) range (-15.17 to -8.09) and Nd model (TDM) ages varying from 0.99 to 1.81 Ga. Sources of sediments to the Marañón-Solimões River include recent volcanic rocks in northern Peru and Ecuador, as well as rocks with long crustal residence time and carbonates from the Marañón Basin, Peru. The Beni-Madeira River has more radiogenic Sr isotope values (0.7255-0.7403), more negative EpslonNd(0) values (-20.46 to -10.47), and older Nd isotope model ages (from 1.40 to 2.35 Ga) when compared to the Marañón-Solimões River. These isotope data were related to the erosion of Paleozoic and Cenozoic foreland basins that are filled with Precambrian sediments derived from the Amazonian Craton. These basins are located in Bolivian Subandina Zone. The Amazon River presents intermediate isotopic values when compared to those found in the Marañón-Solimões and Beni-Madeira rivers. Its Sr isotope ratios range between 0.7193 and 0.7290, and its EpslonNd(0) values varies between -11.09 and -9.51. The Nd isotope model ages of the suspended sediments vary between 1.28 and 1.77 Ga. Concentrations of soluble and insoluble elements indicate a more intense weathering activity in sediments of the Beni

  14. NGRI LAM-MC-ICPMS National Facility: reproducibility of Sr, Nd and Hf isotopic measurements

    A laboratory facility was established at the NGRI, primarily to support research in Isotope Geochemistry and Geochronology. Central to this facility are a Multiple Collector-Inductively Coupled Plasma Mass Spectrometer (MC-ICPMS: Nu Plasma HR, Nu Instruments, UK) and a 213 nm Nd-YAG UV Laser Ablation Microprobe (LAM: UP-213, New Wave Research, USA) and a clean chemistry laboratory for dissolution and chromatographic extraction of a range of elements. This article presents a summary of the accuracy and precision of MC-ICPMS Sr, Nd and Hf isotopic measurements (solution mode) on Standard Reference Materials: SRM-987, JNdi and JMC-475 respectively, measured between October 2007 and August 2009

  15. Petrogenesis of Miocene alkaline volcanic suites from western Bohemia. Whole rock geochemistry and Sr-Nd-Pb isotopic signatures.

    Ulrych, Jaromír; Krmíček, Lukáš; Tomek, Č.; Lloyd, F. E.; Ladenberger, A.; Ackerman, Lukáš; Balogh, K.

    2106-01-01

    Roč. 76, č. 1 (2106), s. 77-93. ISSN 0009-2819 Institutional support: RVO:67985831 Keywords : Bohemian Massif * Cenozoic alkaline volcanism * Geochemistry * K-Ar ages * Sr-Nd-Pb isotopes Subject RIV: DD - Geochemistry

  16. Provenance of sedimentary kaolin deposits in Egypt: Evidences from the Pb, Sr and Nd isotopes

    Baioumy, Hassan

    2014-12-01

    This work reports, for the first time, the Pb, Sr and Nd isotopes of the clay fractions (kaolin deposits in Egypt of different ages (Carboniferous and lower Cretaceous), localities (Sinai, Red Sea and Aswan), lithologies (flint and plastic) and clay minerals composition (pure kaolinite and mixture of kaolinite, illite and chlorite) to determine their source area compositions and examine the effect of provenance on their isotopic compositions. Measured (present day) and age-corrected Pb isotopes data (100 and 300 My for the Cretaceous and Carboniferous deposits, respectively) are more or less homogeneous in all deposits regardless of their ages, localities, and compositions. This, therefore, suggests that the Pb isotopes cannot be used as a tracer for source area compositions of these kaolin deposits. On the other hand, the studied kaolin deposits show variations in their measured and age-corrected Sr and Nd isotopes regarding to their ages and compositions. The Carboniferous illite-rich kaolin deposits in the Khaboba and Hasbar areas, Sinai have higher measured and age-corrected 87Sr/86Sr ratios (average of 0.715742 and 0.711156 for measured and age-corrected, respectively) compared to the non-illitic Carboniferous deposit at Abu Natash area (average of 0.70772 and 0.70769 for measured and age-corrected, respectively) and the lower Cretaceous deposits in all areas (average of 0.70827 and 0.70821 for measured and age-corrected, respectively). The Carboniferous kaolin deposits in the Khaboba and Hasbar areas also have lower 143Nd/144Nd ratios (average of 0.51206 and 0.51180 for measured and age-corrected, respectively) compared to the Carboniferous Abu Natash deposit (average of 0.51253 and 0.51231 for measured and age-corrected, respectively) as well as the lower Cretaceous deposits in all areas (average of 0.51248 and 0.51239 for measured and age-corrected, respectively). Initial εNd values are negative in the Carboniferous kaolin deposits in the Khaboba and

  17. Geographical variations in Sr and Nd isotopic ratios of cryoconite on Asian glaciers

    Cryoconite is a dark-coloured surface dust deposited on glaciers that consists of wind-blown mineral particles, as well as organic matter derived from microbes living on glaciers. In this paper, we analyse the Sr and Nd isotopic ratios of four mineral fractions (i.e., the saline, carbonate, phosphate, and silicate mineral fractions), as well as the organic fraction, of cryoconite samples obtained from six Asian glaciers (the Altai, Pamir, Tien Shan, Qillian Shan, and Himalayan regions), and discuss their geographical variations in terms of the geological origins of the mineral particles and the biogeochemical processes on the glaciers. The silicate mineral fraction showed lower Sr and higher Nd ratios for the glaciers located to the north (Altai, 87Sr/86Sr: 0.713 490–0.715 284, εNd(0): −6.4 to −5.6), while higher Sr and lower Nd ratios for the glaciers located to the south (Himalayas, 87Sr/86Sr: 0.740 121–0.742 088, εNd(0): −16.4 to −15.7); the ratios were similar to those of desert sand, loess, and river sediments in the respective regions of the glaciers. This result suggests that the silicate minerals within the cryoconites were derived from different sources depending on the geographical locations of the glaciers. The isotopic ratios of the saline, carbonate, and phosphate mineral fractions were distinct from those of the silicate fraction, and were similar to those of evaporites and apatite deposits from the Asian deserts, but also varied geographically, indicating that they are likely to reflect their geological origin. The Sr isotopic ratios of the organic fraction were similar to those of the saline and carbonate fractions from glaciers in the central area (Tien Shan and Qillian Shan), but were higher than those of the saline and carbonate fractions, and lower than the phosphate mineral fraction, in the northern and southern areas. The ratios of organic fraction may be determined from the mixing ratio of calcium sources incorporated by

  18. Penning trap mass spectrometry of neutron-deficient Rb- and Sr-isotopes

    We present a mass spectrometer for radioactive nuclei. The principle of measurement is the confinement of the ions in a penning trap and the subsequent determination of their cyclotron frequency νc which is inversely proportional to the mass. The resolution of the method is approximately 106, the achieved accuracy in mass determination 10-7. We present some results from our survey of light Rb- and Sr-isotopes. 3 figs., 8 refs. (author)

  19. Sr isotopic features of the ophiolitic rocks in the Kamuikotan Zone, Hokkaido

    Rb and Sr contents and Sr isotopic ratios were determined for the ophiolitic rocks in the Kamuikotan Zone, Hokkaido. The initial ratios of these rocks are as follows; Sorachi Group basic rocks (0.7019 - 0.7045), ultrabasic rocks (dunite, harzburgite and serpentinite) (0.7069 - 0.7113), olivine clinopyroxenites (0.7037 - 0.7103), microdiorites (0.7039 - 0.7054), rodingite (0.7038), quartz albitite (0.7048), amphibolitic rocks (0.7032 - 0.7053), and trondhjemites (0.7028 - 0.7052). The genertical relationship between the Sorachi Group basic rocks and the associated ultrabasic rocks can be explained by considering them as the complementary products formed by partial melting of certain lherzolitic mantle material, which is composed of various minerals with different Sr contents and Sr isotopic ratios. It seems plausible to consider that the dike rocks such as olivine clinopyroxenite, microdiorite and gabbroic pegmatite were formed from the liquids trapped within the hot residual mantle diapir. (author)

  20. Musa's granite and Rio Maria's granodiorite Rb/Sr isotopic ages and geochemistry

    The Musa Granite and the Rio Maria Granodiorite are located at the eastern margin of the Amazonian craton, in the Rio Maria region, where a typical granite-greenstone terrain is characterized. Rb-Sr dating of six samples from different facies of Rio Maria Granodiorite furnished an age of 2564 ± 68 Ma with initial 87Sr/86Sr radio (IR) of 0.70288 ± 0.00092 (whole rock isochron; 1 ο error; MSWD = 2.26). Thirteen samples from the three facies of Musa Granite (monzogranites, syenogranites and intermediate to felsic hypabyssal rocks) gave Rb-Sr whole rock isochron with an age of 1692 ± 11 Ma and IR of 0.70777 ± 0.00023 (1 ο error, MSWD = 1.89). A preliminary attempt to individualize geochronologically the three facies was done resulting different ages and IRs. There is a coincidence between these ages and the emplacement sequence of these facies of the pluton. The actual meaning of the Rio Maria Granodiorite Rb-Sr age is still uncertain. It could be related to the end of the magmatic crystallization of the batholith as well as to the metamorphic-mylonitic event that affect it. Considering that the Jamon and Musa Granites are petrologically similar that they occur in the same area, it is interesting to note that latter is apparently a little older than the former. The IRs obtained for the two plutons are also not coincident. The isotopic Rb-Sr available data show that the exposed rocks of the Rio Maria Granodiorite have not been able to generate magmas with the compositions of the monzongranitic and the hypabyssal facies of the Musa pluton. On the other hand, rocks isotopically similar to the Rio Maria Granodiorite would theorically be able to generate the Jamon and a magma with the characteristics of the syenogranitic facies of the Musa pluton. (author)

  1. Accurate determination of the 235U isotope abundance by gamma spectrometry

    The purpose of this manual is to serve as guide in applications of the Certified Reference Material EC-NRM-171/NBS-SRM-969 for accurate U-235 isotope abundance measurements on bulk uranium samples by means of gamma spectrometry. The manual provides a thorough description of this non-destructive assay technique. Crucial measurement parameters affecting the accuracy of the gamma-spectrometric U-235 isotope abundance determination are discussed in detail and, whereever possible, evaluated quantitatively. The correction terms and tolerance limits given refer both to physical and chemical properties of the samples under assay and to relevant parameters of typical measurement systems such as counting geometry, signal processing, data evaluation and calibration. (orig.)

  2. Determination of plutonium, uranium and americium/curium isotopes in environmental samples with anion exchange, UTEVA, Sr and DGA resin

    This study presents a quantitative sequential radiochemical separation method for the Pu, U, Sr and Am/Cm isotopes with an anion exchange resin, UTEVA resin, Sr resin and DGA resin in environmental samples. After the radionuclides were leached from samples with 8M HNO3, the Pu, U, Sr and Am/Cm isotopes were sequentially adsorbed on the anion exchange column, UTEVA column connected with Sr Spec column and DGA column. The Pu isotopes were purified from other nuclides through the anion exchange column, and the uranium isotopes were separated from other nuclides through the UTEVA column. Also, 90Sr was separated from other hindrance elements such as Ca2+, Ba2+ and Y3+ with the Sr Spec column. Finally, Am/Cm fractions were purified with the DGA and anion exchange resins. After α source preparation for the purified Pu, U and Am/Cm isotopes with the micro-coprecipitation method, the Pu, U and Am/Cm isotopes were measured by an alpha spectrometry. Strontium-90 was measured by a low level liquid scintillation counter. The radiochemical procedure for Pu, U and Am nuclides investigated in this study has been validated by application to IAEA Reference soils. (orig.)

  3. Sr and Nd Isotopic and Geochemical Analysis of the Vanda Dike Swarm, Antarctica

    Bray, B.; Harpp, K. S.; Geist, D.; Garcia, M. O.; Swarr, G. J.; Garman, K. A.; Buck, S. A.; Parcheta, C. E.; Matulaitis, I.

    2009-12-01

    The Vanda dike swarm, in the Dry Valleys of Antarctica, crosscuts synorogenic Cambro-Ordovician granitoid plutons produced during the Ross Orogeny, circa 500 Ma. The emplacement of the dikes broadly coincides with the transition between the cessation of subduction and the onset of extensional magmatism. Recent fieldwork included field documentation of over 600 dikes, with subsequent whole rock major and trace element analysis and Sr and Nd isotopic analyses of a representative subset. Although originally characterized as being compositionally bimodal, the compositions of the dikes range continuously from 48% to 78% SiO2. New radiogenic isotopic data from 24 samples exhibit a surprisingly wide range of ɛNd and 87Sr/86Sri values; the bulk of the samples have an age-corrected ɛNd from -12.7 to -3.0, however a subset of four of the dikes (both mafic and felsic) have ɛNd values ranging from +2.1 to 8.0. The 87Sr/86Sri ratios vary from 0.7085 to 0.7118. Notably, there is significant overlap between the isotopic signatures of the mafic and felsic rocks and no strong correlation between ɛNd and 87Sr/86Sri. Likewise, there is no correlation between either isotopic ratio and SiO2. These variations indicate that the Vanda dikes may be derived from compositionally heterogeneous sources. Additionally, Nd model ages (τDM) of the felsic dikes yield an average of ~900 Ma, suggesting derivation from a Neoproterozoic crustal source. The Vanda dike samples’ 87Sr/86Sri overlap with the high end of the range defined by the youngest plutons in the region emplaced during the Ross Orogeny (adakitic DV1b, monzonitic DV2; Cox et al., 2000). Similarly, ɛNd values of the Vanda samples most closely resemble those of the DV1b and DV2 plutons, but also extend to significantly more negative and more positive values. None of the isotopic signatures of the dikes are similar to those of the older, orogenic granites in the region (DV1a), which have lower 87Sr/86Sri averages than both the

  4. Rb-Sr Isotopic Systematics of Felsic Igneous Rocks, Wichita Mountains, Oklahoma

    Min, K.; Gilbert, M. C.

    2001-12-01

    Recently determined Rb-Sr isotopic characteristics of twelve of the recognized felsic units of the Cambrian Southern Oklahoma Aulacogen, which crop out in the Wichita Mountains of the southwestern Oklahoma, give some clues to the petrogenesis of these felsic units. 1) Plots of 87Rb/86Sr vs. 87Sr/86Sr form subsets yielding dates of 516 Ma and 522 Ma, discrepancies of about 10 to 20 Ma from the U-Pb zircon age for the Mount Scott Granite of 534 Ma, probably attributable to a systematic loss of radiogenic 87Sr for these units. 2) The Mount Scott Granite and related units (n=7) including Medicine Park Granite and Saddle Mountain Granite give a probable pseudoisochron of 516\\pm4{}Ma and an initial 87Sr/86Sr of 0.7045\\pm4{}, indicating derivation from a primitive mantle source with little crustal contamination. 3) A well-regressed line of 522\\pm2{} Ma with an initial 87Sr/86Sr of 0.7059\\pm7{} is shown by the Long Mountain Granite (n=3), one of the finer-grained western granites, and the Fort Sill Section of the Carlton Rhyolite (n=2) in the eastern Wichitas, which indicates that both were possibly derived contemporaneously from a mixed crustal-mantle source. 4) The Lugert Granite of the western Wichitas has variable and relatively high 87Sr/86Sr initials at 516 Ma probably indicating heterogeneous crustal sources. Interpretation of these data can be made with the following scenario: The earliest known felsic unit is the Carlton Rhyolite, Fort Sill Section. This must have been generated mostly from crustal melting around large mafic plutons in the mid- to lower crust. Crustal melting around the mafic plutons continued to generate liquids rising to the emplacement position, e.g., Long Mountain Granite. Following this, the host magma for the Mount Scott set of units originated dominantly by fractional crystallization from the mafic plutons. Subsequently, additional mafic magma must have moved into the lower- to mid-crust, at some other stratigraphic level, melting a

  5. Development of a rapid method to determine SR-isotopes and its application for the analysis of 90Sr in milk

    A rapid method was developed to determine radioactive Strontium isotopes in environmental samples after a nuclear fallout which is based on precipitation and extraction chromatography of Strontium. By this method 90Sr and 89Sr are determined, after separation, by liquid scintillation spectroscopy. The method was applied to determine the activity of 90Sr in milk samples in Austria in 1997 which is only achievable by the very low detection limit of 0.01Bq/l 90Sr in fresh milk. Furthermore, the variation of the ratio 90Sr / 137Cs in milk in Austria in dependence of the 137Cs concentration in milk in 1997 and thus the 137Cs deposition is given and the reasons for this distribution are discussed. (orig.)

  6. Final Progress Report: Isotope Identification Algorithm for Rapid and Accurate Determination of Radioisotopes Feasibility Study

    Rawool-Sullivan, Mohini [Los Alamos National Laboratory; Bounds, John Alan [Los Alamos National Laboratory; Brumby, Steven P. [Los Alamos National Laboratory; Prasad, Lakshman [Los Alamos National Laboratory; Sullivan, John P. [Los Alamos National Laboratory

    2012-04-30

    This is the final report of the project titled, 'Isotope Identification Algorithm for Rapid and Accurate Determination of Radioisotopes,' PMIS project number LA10-HUMANID-PD03. The goal of the work was to demonstrate principles of emulating a human analysis approach towards the data collected using radiation isotope identification devices (RIIDs). It summarizes work performed over the FY10 time period. The goal of the work was to demonstrate principles of emulating a human analysis approach towards the data collected using radiation isotope identification devices (RIIDs). Human analysts begin analyzing a spectrum based on features in the spectrum - lines and shapes that are present in a given spectrum. The proposed work was to carry out a feasibility study that will pick out all gamma ray peaks and other features such as Compton edges, bremsstrahlung, presence/absence of shielding and presence of neutrons and escape peaks. Ultimately success of this feasibility study will allow us to collectively explain identified features and form a realistic scenario that produced a given spectrum in the future. We wanted to develop and demonstrate machine learning algorithms that will qualitatively enhance the automated identification capabilities of portable radiological sensors that are currently being used in the field.

  7. Extreme heterogeneity in Sr isotope systematic in the Himalayan leucogranites: A possible mechanism of partial melting based on thermal modeling

    Dilip K Mukhopadhyay

    2001-06-01

    The small leucogranite plutons occurring in linear belts in the Higher Himalayas have formed due to post-collision partial melting within the Himalayan crust. Several studies have documented that the Sr isotopic ratios in the granite bodies show chaotic variation and meaningful Rb-Sr isochron ages are difficult, if not impossible, to obtain. In tectonically overthickened crust, the depth-temperature profile (geotherm) remains strongly transient for the first tens of millions of years. It is proposed here that the intersecting relations between the transient geotherms and activity-dependent solidus/melting curves may generate small pods of magma at di erent depths and at di erent times. Each of these pods will have its unique Sr isotopic ratios. Coalescence of these small pods of magma without any e ective homogenization due to deformation-induced fast segregation, ascent and emplacement may lead to pluton-wide extreme heterogeneity in Sr isotopic ratios.

  8. Deciphering fluid sources of hydrothermal systems: A combined Sr- and S-isotope study on barite (Schwarzwald, SW Germany)

    Staude, S.; Gob, S.; Pfaff, K.; Strobele, F.; Premo, W.R.; Markl, G.

    2011-01-01

    Primary and secondary barites from hydrothermal mineralizations in SW Germany were investigated, for the first time, by a combination of strontium (Sr) isotope systematics (87Sr/86Sr), Sr contents and δ34S values to distinguish fluid sources and precipitation mechanisms responsible for their formation. Barite of Permian age derived its Sr solely from crystalline basement rocks, whereas all younger barite also incorporate Sr from formation waters of the overlying sediments. In fact, most of the Sr in younger barite is leached from Lower and Middle Triassic sediments. In contrast, most of the sulfur (S) of Permian, Jurassic and northern Schwarzwald Miocene barite originated from basement rocks. The S source of Upper Rhinegraben (URG)-related Paleogene barite differs depending on geographic position: for veins of the southern URG, it is the Oligocene evaporitic sequence, while central URG mineralizations derived its S from Middle Triassic evaporites. Using Sr isotopes of barite of known age combined with estimates on the Sr contents and Sr isotopic ratios of the fluids' source rocks, we were able to quantify mixing ratios of basement-derived fluids and sedimentary formation waters for the first time. These calculations show that Jurassic barite formed by mixing of 75–95% ascending basement-derived fluids with 5–25% sedimentary formation water, but that only 20–55% of the Sr was brought by the basement-derived fluid to the depositional site. Miocene barite formed by mixing of an ascending basement-derived brine (60–70%) with 30–40% sedimentary formation waters. In this case, only 8–15% of the Sr was derived from the deep brine. This fluid-mixing calculation is an example for deposits in which the fluid source is known. This method applied to a greater number of deposits formed at different times and in various geological settings may shed light on more general causes of fluid movement in the Earth's crust and on the formation of hydrothermal ore deposits.

  9. Tracking selenium behaviour in chalk aquifer (northern France): Sr and 34S-sulphates isotopes constraints.

    Cary, Lise; Benabderraziq, Hind; Elkhattabi, Jamal; Parmentier, Marc; Gourcy, Laurence; Négrel, Philippe

    2014-05-01

    Groundwaters in parts of the Paris Basin (France) are facing increasing selenium (Se) contents that can exceed the drinking water limit of 10 μg/L according to the European Framework Directive in the field of water policy (2000/60/EC). To better understand the groundwater origins and the selenium dynamics, the water chemistry of the Chalk aquifer supplying drinkable water to Lille city was studied. This area is submitted to quantitative and qualitative pressure from industrial, urban and agriculture origins. An integrated study was settled to determine the water sources and dynamics of elements, with a focus on Se. After a large chemical characterisation of the groundwater chemistry in the four field wells, a monthly monitoring was held in four wells and in the Deûle channel. Chemical analysis of major and trace elements, stable isotopes (δ18O, δ2H), strontium isotopes, and δ34S and δ18O of sulphates were realised. The chemical composition of solids sampled at various depths at vicinity of the four wells was also analysed. The specific geochemical signature of groundwater as revealed by Sr isotopes, in addition to element concentrations ratios like Mg/Sr and Se/Sr, highlighted mixture of three main groundwaters bodies: (1) the upstream groundwaters in the recharge area with the most radiogenic 87Sr/86Sr isotopic signature; (2) the confined groundwaters with high Sr concentrations due to water-rock interactions and the lowest 87Sr/86Sr isotopic signature close to the one of the chalk in Paris and London basins; (3) the Se-rich formations of Tertiary and Quaternary. The contents of Se, mainly present as SeV I (and locally as SeIV ), displayed spatial and temporal disparities that can be explained by geological and hydrogeological conditions. Se-rich clayed sediments originating from the dismantling of Se-rich tertiary formations (i.e. Ypresian) overlay the chalk formation and can be found in saturated conditions depending of the water table level. Oxidation of

  10. Dissolved constituents and Sr isotopes in river waters from a mountainous island - The Danshuei drainage system in northern Taiwan

    Taiwan is a typical active orogenic belt situated at the collision boundary between the Eurasian Continental Plate and the Philippine Sea Plate. Dissolved major and trace constituents, as well as Sr and Sr isotopes in river waters collected from the Danshuei River basin in northern Taiwan have been studied to evaluate chemical weathering processes. The results of principal component analysis show that the ion sources in these river waters can be categorized into 3 major components: chemical weathering, seasalt contribution and local anthropogenic input. The chemical weathering is the most dominant factor that contributes about 85% of total variances. Significantly increased Na/Cl and Ca/Cl, as well 87Sr/86Sr, were observed in most upper stream samples. The Na/Cl and Ca/Cl ratios in the Dahan Stream, however, are much higher than the Shindien Stream. Even though average rainfall is stronger in the Shindien drainage basin, chemical evidence from river waters supports less intense weathering in the region. Selective dissolution of secondary calcites explains the observed high Ca/Cl, Sr/Cl and Ca/Na in the Dahan Stream. These results highlight the potential importance of tectonic factors, such as uplift and physical erosion in studying chemical weathering in an active orogenic belt. The variations of 87Sr/86Sr in the Danshuei River are quite large, reflecting some strata that released Sr. Most of the upstream waters exhibit more radiogenic 87Sr/86Sr, 0.713243-0.714338, due to weathering of ambient low-grade metamorphic rocks, 0.71678-0.72216. The distributions of Cl, Sr and 87Sr/86Sr in the main stream were affected by somewhat conservative mixing with sources varing between ambient rocks and seasalt. In the upper Dahan Stream, heavy 87Sr/86Sr ratios were coincident with large deviations of Na/Cl from the average seawater value, as high as 40. The degree of chemical weathering in ambient rocks plays a dominant role in affecting the distribution of Sr and 87Sr/86Sr in

  11. Artificial (Pu 90Sr, 241Am) and natural (U) isotopes in human bones from Poland

    In two papers we have presented results if analyses of artificial isotopes (238,239,240Pu, 241Am and 90Sr) content in human bones, using samples collected during hip joint replacement surgery. Since the patients were members of general population (not exposed in any particular form to artificial radionuclides) results can be treated as current background level for Poland and perhaps also whole central Europe. During this project the open question appeared - what is the level in human bones of natural alpha emitters like 238U-, 234U, for instance. Therefore about 30 human hip joint bone samples are being now analysed for the presence of uranium along with mentioned above artificial radionuclides. Samples are ashen and sequential radiochemical analyse is applied for separation of Pu, Sr and Am isotopes followed by separation of uranium using anion exchange resin. Measurements of plutonium, americium and uranium are performed using alpha spectrometry. That for 90Sr is done by LSC. Results will be presented during conference. Document available in abstract form only. (authors)

  12. Accurate determination and certification of bromine in plastic by isotope dilution inductively coupled plasma mass spectrometry

    Ohata, Masaki, E-mail: m-oohata@aist.go.jp; Miura, Tsutomu

    2014-07-21

    Highlights: • Accurate analytical method of Br in plastic was studied by isotope dilution ICPMS. • A microwave acid digestion using quartz vessel was suitable for Br analysis. • Sample dilution by NH{sub 3} solution could remove memory effect for ICPMS measurement. • The analytical result of the ID-ICPMS showed consistency with that of INAA. • The ID-ICPMS developed could apply to certification of Br in candidate plastic CRM. - Abstract: The accurate analytical method of bromine (Br) in plastic was developed by an isotope dilution inductively coupled plasma mass spectrometry (ID-ICPMS). The figures of merit of microwave acid digestion procedures using polytetrafluoroethylene (PTFE) or quartz vessels were studied and the latter one was suitable for Br analysis since its material was free from Br contamination. The sample dilution procedures using Milli-Q water or ammonium (NH{sub 3}) solution were also studied to remove memory effect for ICPMS measurement. Although severe memory effect was observed on Milli-Q water dilution, NH{sub 3} solution could remove it successfully. The accuracy of the ID-ICPMS was validated by a certified reference material (CRM) as well as the comparison with the analytical result obtained by an instrumental neutron activation analysis (INAA) as different analytical method. From these results, the ID-ICPMS developed in the present study could be evaluated as accurate analytical method of Br in plastic materials and it could apply to certification of Br in candidate plastic CRM with respect to such regulations related to RoHS (restriction of the use of hazardous substances in electrical and electronics equipment) directive.

  13. Accurate determination and certification of bromine in plastic by isotope dilution inductively coupled plasma mass spectrometry

    Highlights: • Accurate analytical method of Br in plastic was studied by isotope dilution ICPMS. • A microwave acid digestion using quartz vessel was suitable for Br analysis. • Sample dilution by NH3 solution could remove memory effect for ICPMS measurement. • The analytical result of the ID-ICPMS showed consistency with that of INAA. • The ID-ICPMS developed could apply to certification of Br in candidate plastic CRM. - Abstract: The accurate analytical method of bromine (Br) in plastic was developed by an isotope dilution inductively coupled plasma mass spectrometry (ID-ICPMS). The figures of merit of microwave acid digestion procedures using polytetrafluoroethylene (PTFE) or quartz vessels were studied and the latter one was suitable for Br analysis since its material was free from Br contamination. The sample dilution procedures using Milli-Q water or ammonium (NH3) solution were also studied to remove memory effect for ICPMS measurement. Although severe memory effect was observed on Milli-Q water dilution, NH3 solution could remove it successfully. The accuracy of the ID-ICPMS was validated by a certified reference material (CRM) as well as the comparison with the analytical result obtained by an instrumental neutron activation analysis (INAA) as different analytical method. From these results, the ID-ICPMS developed in the present study could be evaluated as accurate analytical method of Br in plastic materials and it could apply to certification of Br in candidate plastic CRM with respect to such regulations related to RoHS (restriction of the use of hazardous substances in electrical and electronics equipment) directive

  14. U-Sr isotopic speedometer: Fluid flow and chemical weatheringrates inaquifers

    Maher, Kate; DePaolo, Donald J.; Christensen, John N.

    2005-12-27

    Both chemical weathering rates and fluid flow are difficultto measure in natural systems. However, these parameters are critical forunderstanding the hydrochemical evolution of aquifers, predicting thefate and transport of contaminants, and for water resources/water qualityconsiderations. 87Sr/86Sr and (234U/238U) activity ratios are sensitiveindicators of water-rock interaction, and thus provide a means ofquantifying both flow and reactivity. The 87Sr/86Sr values in groundwaters are controlled by the ratio of the dissolution rate to the flowrate. Similarly, the (234U/238U) ratio of natural ground waters is abalance between the flow rate and the dissolution of solids, andalpha-recoil loss of 234U from the solids. By coupling these two isotopesystems it is possible to constrain both the long-term (ca. 100's to1000's of years) flow rate and bulk dissolution rate along the flow path.Previous estimates of the ratio of the dissolution rate to theinfiltration flux from Sr isotopes (87Sr/86Sr) are combined with a modelfor (234U/238U) to constrain the infiltration flux and dissolution ratefor a 70-m deep vadose zone core from Hanford, Washington. The coupledmodel for both (234U/238U) ratios and the 87Sr/86Sr data suggests aninfiltration flux of 5+-2 mm/yr, and bulk silicate dissolution ratesbetween 10-15.7 and 10-16.5 mol/m2/s. The process of alpha-recoilenrichment, while primarily responsible for the observed variation in(234U/238U) of natural systems, is difficult to quantify. However, therate of this process in natural systems affects the interpretation ofmost U-series data. Models for quantifying the alpha-recoil loss fractionbased on geometric predictions, surface area constraints, and chemicalmethods are also presented. The agreement between the chemical andtheoretical methods, such as direct measurement of (234U/238U) of thesmall grain size fraction and geometric calculations for that sizefraction, is quite good.

  15. Multi-isotopic (Li, B, Sr, Nd) approach for geothermal reservoir characterization in the Limagne Basin (Massif Central, France)

    A multi-isotopic study of thermo-mineral waters from the Limagne Basin (French Massif Central) is reported. Lithium, B, Sr and Nd isotopic signatures in thermo-mineral waters and bedrocks were combined in order to determine the origin of these fluids from a reservoir point of view. Strontium and Nd isotopic systems showed that the thermo-mineral waters are mostly derived from a granitic reservoir type, with the exception of a few water samples having Sr and Nd isotopic signatures also reflecting a volcanic contribution (basalts). In a second step, Li and B isotopes were investigated, given that Li and B isotopic systematics are potentially affected by mass dependent fractionation during water/rock interaction and could provide some information on what takes place during this process. A great diversity of thermo-mineral waters within the Aigueperse area was clearly observed, which is directly related to the origin of these thermal waters in terms of reservoirs. These different geothermal reservoirs are characterized by different geological settings and intensity of water/rock interaction (i.e. depth and temperature). The combination of Li, B, Sr and Nd isotopic systems highlight the complexity of the study of these geothermal reservoirs and that the use of only one isotopic tool could lead to an incomplete interpretation of the origin of water. The new approach using Li isotopes shows a very interesting potential with additional information on the intensity of water/rock interaction

  16. Palaeoenvironmental Changes of the Ancient Nihewan Lake Area—Sr Isotope Evidence from Xiaodukou Foraminifera

    王世杰

    1996-01-01

    By using the improved trace(50μg) Sr isotope analytical method the 87Sr/86Sr ratios of Xiaodukou foraminifera fossils were measured,giving a range of 0.71105-0.71274,apparently higher than the value of contemporaneous seawater(0.709087-0.709147)and also slightly higher than the average value of modern Yellow River(0.7111),demonstrating that the contemporaneous environment where Xiaodukou foraminifera inhabited was an inland lake.Detailed analyses of △ Sr values showed that there occurred an event responsible for environmental changes in the ancient Nihewan Lake area during the time(about 1.0Ma ago)when Xiaodukou foraminifera appeared.Because of strong evaporation the salinity of the lake would increase and a regional salt-water of brackish-water lacustrine environment would be produced,thus providing a suitable and inhabitable environment for foraminiferae.It is concluded that Xiaodukou foraminiferal fossil assemblaes belong to non-marine foraminiferal species.

  17. Precision frequency measurement of 1S0–3P1 intercombination lines of Sr isotopes

    We report on frequency measurement of the intercombination (5s2)1S0–(5s5p)3P1 transition of the four natural isotopes of strontium, including 88Sr (82.58%), 87Sr (7.0%), 86Sr (9.86%), and 84Sr (0.56%). A narrow-linewidth laser that is locked to an ultra-low expansion (ULE) optical cavity with a finesse of 12000 is evaluated at a linewidth of 200 Hz with a fractional frequency drift of 2.8×10−13 at an integration time of 1 s. The fluorescence collector and detector are specially designed, based on a thermal atomic beam. Using a double-pass acousto-optic modulator (AOM) combined with a fiber and laser power stabilization configuration to detune the laser frequency enables high signal-to-noise ratios and precision saturated spectra to be obtained for the six transition lines, which allows us to determine the transition frequency precisely. The optical frequency is measured using an optical frequency synthesizer referenced to an H maser. Both the statistical values and the final values, including the corrections and uncertainties, are derived for a comparison with the values given in other works. (paper)

  18. Modelling the Phanerozoic carbon cycle and climate: constraints from the 87Sr/86Sr isotopic ratio of seawater

    Francois, L. M.; Walker, J. C.

    1992-01-01

    A numerical model describing the coupled evolution of the biogeochemical cycles of carbon, sulfur, calcium, magnesium, phosphorus, and strontium has been developed to describe the long-term changes of atmospheric carbon dioxide and climate during the Phanerozoic. The emphasis is on the effects of coupling the cycles of carbon and strontium. Various interpretations of the observed Phanerozoic history of the seawater 87Sr/86Sr ratio are investigated with the model. More specifically, the abilities of continental weathering, volcanism, and surface lithology in generating that signal are tested and compared. It is suggested that the observed fluctuations are mostly due to a changing weatherability over time. It is shown that such a conclusion is very important for the modelling of the carbon cycle. Indeed, it implies that the conventional belief that the evolution of atmospheric carbon dioxide and climate on a long time scale is governed by the balance between the volcanic input of CO2 and the rate of silicate weathering is not true. Rather carbon exchanges between the mantle and the exogenic system are likely to have played a key role too. Further, the increase of the global weathering rates with increasing surface temperature and/or atmospheric CO2 pressure usually postulated in long-term carbon cycle and climate modelling is also inconsistent with the new model. Other factors appear to have modulated the weatherability of the continents through time, such as mountain building and the existence of glaciers and ice sheets. Based on these observations, a history of atmospheric carbon dioxide and climate during Phanerozoic time, consistent with the strontium isotopic data, is reconstructed with the model and is shown to be compatible with paleoclimatic indicators, such as the timing of glaciation and the estimates of Cretaceous paleotemperatures.

  19. Determination of Sr and Ca sources in small tropical catchments (La Selva, Costa Rica) - A comparison of Sr and Ca isotopes

    Wiegand, B. A.; Schwendenmann, L.

    2013-04-01

    SummaryA comparative study of Sr and Ca isotopes was conducted to assess solute sources and effects of biogeochemical processes on surface water and groundwater in four small tropical catchments located at La Selva Biological Station, Costa Rica. Variable concentrations of dissolved Sr2+ and Ca2+ in the catchments are related to mixing of waters from different origin. Three catchments are influenced by high-solute bedrock groundwater, while another catchment is primarily supplied by local recharge. 87Sr/86Sr ratios were employed to discriminate contributions from mineral weathering and atmospheric sources. Solutes in bedrock groundwater have a predominant geogenic origin, whereas local recharge is characterized by low-solute inputs from rainwater and minor in situ weathering releases from nutrient-depleted soils. Bedrock groundwater contributes more than 60% of dissolved Sr2+ to surface discharge in the Salto, Saltito, and Arboleda catchments, whereas the Taconazo catchment receives more than 95% of dissolved Sr2+ from rainwater. δ44/40Ca values of dissolved Ca2+ vary greatly in the catchments, mainly as a result of heterogeneous Ca isotope compositions of the contributing sources. Based on differences in δ44/40Ca values, two distinct bedrock groundwaters discharging at the Salto and the Arboleda catchments are suggested. Effects of biological processes in the plant-soil system on solute generation in the catchments are indicated by variable Ca/Sr ratios. However, these effects cannot clearly be assessed by Ca isotopes due to the strong heterogeneity of δ44/40Ca values of Ca2+ sources and high Ca2+ concentrations in bedrock groundwater.

  20. Petrochemistry and Rb-Sr isotopic study of bandal granites, district Kulu, Himachal Pradesh

    Bandal granites which form the subject matter of the present study occur as a concordant body of batholithic size and cover an area of about 500 sq. km. consider these granites to be the result of granitization of arkose and pelitie rocks. Whereas treats them as intrusive into the Banjar Formation, recognized two components i.e. foliated and non-foliated which made the Bandal pluton the latter is intrusive into the former. This gave an isochron age of 1220±100 Ma for the foliated granite. This paper presents the results of a petrochemical and Rb-Sr isotopic studies of these granites with a view to understand their petrogenesis

  1. Sr isotope stratigraphy and lithogenic grain-size distributions of the Pleistocene Turkana Basin, Kenya

    Lubbe, J. V. D.; Sier, M.; Feibel, C. S.; Beck, C.; Dupont-Nivet, G.; Vonhof, H.; Joordens, J. J.; Cohen, A.; Prins, M. A.; Olago, D.

    2015-12-01

    The Pleistocene sedimentary infillings of the Turkana basin, a hotspot for early human evolution, document both human evolutionary and climatic events between 2.1-1.4 Ma. During this time interval, several early Homo species inhabited the vicinity of the Lorenyang paleo-lake, which was mainly fed by the Omo River, draining the Ethiopian Highlands. Paleo-Omo discharge could be expected to be modulated by changes in orbital eccentricity, causing wet-dry climate variability at ~20 kyr timescales, superimposed upon a long-term transition to drier conditions. To reconstruct climate and environmental changes during this key period of human evolution, we obtained high-resolution records of strontium (Sr) isotope ratios in lacustrine fossils as well as lithogenic grain-size distributions. High resolution sampling of sediment sequences containing abundant lacustrine fossils was carried out at outcrops situated to the east and the west of the lake. The sequences can be stratigraphically linked by several volcanic tuff layers, as well as paleomagnetic data. The Turkana basin is a half-graben and, as a consequence, the lacustrine sediment sequences along the western margin are relatively more continuous and deposited in a relatively deeper part of the lake, when compared to sequences at the eastern margin, where the paleo-Omo delta was situated. The outcrops to the west of Lake Turkana are situated in close proximity to core WTK13-1A, which was retrieved for the Hominin Sites and Paleolakes Drilling Project (HSDPD), and span approximately the same stratigraphic interval. In this study, we successfully linked the stratigraphies of the sediment core and the outcrops, the latter of which were logged in great detail in the field. In addition, time-synchronous Sr isotope records from both sides of Lake Lorenyang display similar trends in Sr isotope stratigraphy, thereby confirming the lateral correlations. However, large differences in grain-size distribution and accumulation of

  2. Sr and Pb isotopic geochemistry of feldspars and implications for the growth of megacrysts in plutonic settings.

    Munnikhuis, J.; Glazner, A. F.; Coleman, D. S.; Mills, R. D.

    2015-12-01

    Why megacrystic textures develop in silicic igneous rocks is still unknown. One hypothesis is that these crystals nucleate early in a magma chamber with a high liquid content. A supportive observation of this hypothesis is areas in plutons with high concentrations of megacrysts suggesting flow sorting. Another group of hypotheses suggest megacrystic textures form during protracted late-stage coarsening in a low-melt, interlocked matrix due to either thermal oscillations from incremental pluton emplacement, or Ostwald ripening. Isotopic analyses of large, euhedral K-feldspar megacrysts from the Cretaceous intrusive suites of the Sierra Nevada batholith (SNB) provide new insight into their origin. Megacrysts from the SNB reach the decimeter scale, are Or rich (85-90%), are perthitic, and host mineral inclusions of nearly all phases in the host rock. In-situ micro-drilling of transects, from core to rim, of the alkali feldspars provides material for Sr and Pb isotopic analyses by thermal ionization mass spectrometry (TIMS). Preliminary 87Sr/86Sr(i) isotopic data from samples from the Cathedral Peak Granodiorite, of the Tuolumne Intrusive Suite range from 0.706337 to 0.706452 (~1.6ɛSr) near the cores, whereas a sawtooth pattern with larger variability, 0.706179 to 0.706533 (~5ɛSr), occurs nears the rims. We interpret these preliminary data to indicate that the late portion of growth (i.e. crystal rim) was dominated by either cannibalism of small K-feldspar crystals with isotopic variability, or by addition of isotopically diverse late components to the magma. By comparing the Sr and Pb isotopic stratigraphy of megacrysts from a variety of rock matrices and different granitoids in the SNB isotopic trends can be evaluated to determine if crystals sizes are dependent on disequilibrium processes or grow at a steady state.

  3. Isotopes (18O, 14C, 87Sr/86Sr) and hydrogeochemical modelling since 11,000 years BP, Bolivian Altiplano

    The phreatic aquifer of the central Altiplano shows a Cl concentration that increases from 0.5 meq 1-1 upstream to 150 meq 1-1 downstream. Values of more than 20 meq 1-1 may not be explained by the present hydrological conditions. The main outflow process from the aquifer is the evaporation (E) whose regional quantification has been conducted using the relation established for all arid zone areas on the base of isotopic profiles: E (mm a-1) = 63 Z-1.5 where Z (m) is the water table depth under soil surface. The aquifer under study may have acquired its high chlorine content during last lacustrine phase (Tauca, 12 ka BP). Arguments for this hypothesis are: (i) maximum level of the lake (3780 m) higher than present soil elevation in the area, (ii) same order of salinity in the paleolake and in the more saline groundwater, (iii) identical values of Sr isotopic ratio in calcareous deposits from the Tauca and in saline groundwater, (iv) weak molar ratio of Li/Cl in saline groundwater and in the Tauca, (v) modelling of Cl transport over 11,000 years consistent with observed spatial evolution of Cl in groundwater. To this scenario, might be superimposed the assumption of a delay for the convective transfer of salt towards south by the coupled effects of accumulation of salt in the unsaturated zone by evaporation from the aquifer during thousand or so years, and of the subsequent return of this salt downwards to the aquifer during some short rainy periods. (author)

  4. Reconstructing conditions during dolomite formation on a Carnian coastal sabkha/alluvial plain using 87Sr/86Sr isotopes - Travenanzes Formation, northern Italy

    Rieder, Maximilian; Wegner, Wencke; Horschinegg, Monika; Preto, Nereo; Breda, Anna; Klötzli, Urs; Peckmann, Jörn; Meister, Patrick

    2016-04-01

    The study of large amounts of dolomite that formed in the Triassic Tethyan realm is hampered by late diagenetic or hydrothermal overprint. These dolomites are difficult to link to past environmental and early diagenetic conditions, and their correlation to models for dolomite formation in modern environments is problematic. Preto et al. (2015) suggested, based on evidence from nano-scale structure analysis by transmission electron microscopy and petrographic observations, that dolomites in the Carnian Travenanzes Formation of the Southern Alps (Dolomites area) represent a preserved primary phase. The Travenanzes Formation was deposited in an extended alluvial plain or coastal sabkha environment subject to a semi-arid climate. Beds and nodules of nearly stoichiometric dolomite are embedded in large amounts of clay, which shielded early formed dolomite from diagenetic fluids. This finding of penecontemporaneous dolomite provides an ideal model case for reconstructing past environmental conditions at the time of dolomite precipitation. While Preto et al. (2015) argued that dolomite formation was mediated by extracellular polymeric substances produced by sulphate-reducing bacteria, it remains unclear whether precipitation occurred from evaporating seawater or mainly from brine derived from evaporating continental groundwater. Both cases exist in modern environments of dolomite formation. In the coastal sabkhas of Abu Dhabi and Qatar, dolomite precipitates from concentrated brine derived from seawater, either through seepage and reflux or through evaporative pumping (the sabkha model). In the coastal ephemeral lakes of the Coorong Lagoon system (South Australia) dolomite precipitation occurs from evaporating groundwater. The goal of this study is to distinguish marine from continental influence during formation of Carnian dolomite using 87Sr/86Sr isotope ratios. Sr isotopes could reveal different origins of ionic solutions for dolomite precipitation, which is not

  5. The geographic distribution of Sr isotopes from surface waters and soil extracts over the island of Bornholm (Denmark) – A base for provenance studies in archaeology and agriculture

    Frei, Robert; Frei, Karin Margarita

    2013-01-01

    provenance studies, including archaeological migration and authenticity proof for particular food products. The Sr isotopic compositions of surface waters range from 87Sr/86Sr = 0.7097–0.7281 (average 0.7175 ± 0.0049; 1σ), whereas 0.1 M HNO3, 0.05 M HNO3, and 0.01 M CaCl2 soil extracts range from 87Sr/86Sr...

  6. The use Pb- and Sr- isotopes for the study of Pacific Islander population

    Lead isotope measurements of dental enamel are regularly used as a means of determining information as to the source of the lead burden in modern human populations (Gulson and Wilson 1994). Lead ions have a considerable propensity to replace calcium ions in skeletal hard tissue; principally composed of hydroxy-apatite. The lead isotopic composition of teeth in adult humans has been shown to relate directly to the subject's exposure to the element at the time of eruption of their adult teeth and is unaffected by changes in the lead burden of an individual in latter life. In children, the analogous lead burden relates to the lead exposure of the mother during pregnancy and in the neo-natal period. Moreover due to its high crystallinity and density dental enamel does not undergo post-mortem recrystallization. This fact raised the exciting possibility that isotopic measurements of hard tissue could be used as a means of determining whether and individual is a migrant to a particular region. Despite a number of complications, briefly described, this paper presents the results of the ongoing study which uses measurements of Sr and Pb isotopes within dental enamel to determine the origin of Pacific Islander populations

  7. The use Pb- and Sr- isotopes for the study of Pacific Islander population

    Budd, P.; Gulson, B.L.; Montgomery, J.; Rainbird, P.; Thomas, R.G.; Young, S. [New England Univ., Armidale, NSW (Australia)

    1997-12-31

    Lead isotope measurements of dental enamel are regularly used as a means of determining information as to the source of the lead burden in modern human populations (Gulson and Wilson 1994). Lead ions have a considerable propensity to replace calcium ions in skeletal hard tissue; principally composed of hydroxy-apatite. The lead isotopic composition of teeth in adult humans has been shown to relate directly to the subject`s exposure to the element at the time of eruption of their adult teeth and is unaffected by changes in the lead burden of an individual in latter life. In children, the analogous lead burden relates to the lead exposure of the mother during pregnancy and in the neo-natal period. Moreover due to its high crystallinity and density dental enamel does not undergo post-mortem recrystallization. This fact raised the exciting possibility that isotopic measurements of hard tissue could be used as a means of determining whether and individual is a migrant to a particular region. Despite a number of complications, briefly described, this paper presents the results of the ongoing study which uses measurements of Sr and Pb isotopes within dental enamel to determine the origin of Pacific Islander populations. Paper no. 72; Extended abstract. 4 refs.

  8. Fast and accurate dating of nuclear events using La-140/Ba-140 isotopic activity ratio.

    Yamba, Kassoum; Sanogo, Oumar; Kalinowski, Martin B; Nikkinen, Mika; Koulidiati, Jean

    2016-06-01

    This study reports on a fast and accurate assessment of zero time of certain nuclear events using La-140/Ba-140 isotopic activity ratio. For a non-steady nuclear fission reaction, the dating is not possible. For the hypothesis of a nuclear explosion and for a release from a steady state nuclear fission reaction the zero-times will differ. This assessment is fast, because we propose some constants that can be used directly for the calculation of zero time and its upper and lower age limits. The assessment is accurate because of the calculation of zero time using a mathematical method, namely the weighted least-squares method, to evaluate an average value of the age of a nuclear event. This was done using two databases that exhibit differences between the values of some nuclear parameters. As an example, the calculation method is applied for the detection of radionuclides La-140 and Ba-140 in May 2010 at the radionuclides station JPP37 (Okinawa Island, Japan). PMID:27058322

  9. A Sr-isotopic study of a suite of precambrian shoshonites from the Sinclair Group in Southern Namibia

    Sr isotope analyses of 14 whole rock samples of shoshonitic lavas and intrusives of the Barby Formation, a member of the Sinclair Group in Namibia, indicate that the age of emplacement of these units is 1 392 plus minus 33 Ma with an initial 87Sr/86Sr ratio of 0.7023 plus minus 0.0002. Resetting of the Rb-Sr isotopic systems appears to have resulted in some of the samples defining a second isochron giving an age of 1 151 plus minus 32 Ma. This re-equilibration may be related to the final stages of metamorphism and deformation associated with the formation of the Namaqua Mobile Belt lying to the south of the shoshonite occurrences. The low initial ratio is suggestive of a mantle origin for the K-rich magmas and insignificant contamination by crustal material indicates that the highly potassic character of these rocks is a primary magmatic feature

  10. Sr ISOTOPIC EVIDENCE FOR STUDYING THE SALINIZATION OF SOILS: AN EXAMPLE FROM THE SAN VITALE PINEWOOD (RAVENNA

    Umberto Masi

    2009-12-01

    Full Text Available In the frame of a multidisciplinary project of research on the San Vitale Pinewood ecosystem, north of Ravenna, the Sr isotope study of a soil profile developed on an old coastal dune aiming at detecting the effect of salinization is presented. The Sr isotope ratios of the bulk soil samples decreased significantly from upper (0.717 to lower (0.712 horizons because of the abundant marine salts deposited by the brackish water present in the deep soil. While the main source of Sr in the upper horizons is the silicates, especially the feldspaths contained in the old dune sediments; in contrast, Sr in the lower horizons is significantly also of evaporitic origin (0.707-0.709. This latter is dominantly the strontium bio-available to the plants.

  11. Sr isotopes in natural waters: Applications to source characterisation and water-rock interaction in contrasting landscapes

    Strontium isotopes (87Sr/86Sr) are routinely measured in hydrochemical studies to determine sources and mixing relationships. They have proved particularly useful in determining weathering processes and quantifying end-member mixing processes. A number of routine case studies are presented which highlight that Sr isotopes represent a powerful tool in the geochemists toolbox helping to constrain weathering reactions, weathering rates, flow pathways and mixing scenarios. Differences in methodologies for determining the weathering component in natural environments, inherent differences in weathering rates of different minerals, and mineral heterogeneity often cause difficulties in defining the weathering component of different catchments or aquifer systems. Nevertheless, Sr isotopes are useful when combined with other hydrochemical data, to constrain models of water-rock interaction and mixing as well as geochemical processes such as ion-exchange. This paper presents a summary of recent work by the authors in constraining the sources of waters and weathering processes in surface catchments and aquifers, and indicates cases where Sr isotopes alone are insufficient to solve hydrological problems.

  12. Sr, Pb and Nd isotope studies and their bearing on the petrogenesis of the Jalor and Siwana complexes, Rajasthan, India

    The Jalor and Siwana complexes belong to the Malani igneous suite, Rajasthan, India and are characterised by within - plate, A - type granites associated with coeval felsic and mafic volcanism. Sr, Pb and Nd isotopic compositions of the two complexes have been determined. Sr isotopic studies reveal an isochron age of 725 ± 7 Ma for the felsic rocks of the Jalor complex, with an initial 87Sr/86Sr ratio of 0.7062±0.0020. Three highly differentiated granites from Siwana plot on the same near-isochron, indicating that the complexes are coeval. The Pb and Nd isotopic ratios range between (206Pb/204Pb = 18.52-21.28., 207Pb/204Pb = 15.58-15.98, 208Pb/204Pb/204 Pb=38.53.-40.8) and (143Nd/144Nd=0.5122-0.5127, 147Sm/144Nd=0.1260-0.157) respectively. Pb and Nd isotopic compositions of the Siwana samples show that the magma is mantle derived; for the Jalor complex the combined Sr, Nd and Pb data indicate primary mantle derivation with a variable degree of crustal contamination, with the assimilated crust being most likely of Archaean age. The petrogenesis of the two complexes is interpreted as an effect of fractionation of a primary mantle derived magma, simultaneous with assimilation of rocks from the lower crust. The data further document the presence of Archaean crust in the area. (author). 27 refs., 6 figs., 3 tabs

  13. Ion microprobe analysis of Rb and Sr isotopes in K-rich minerals: an attempt of radiometric dating

    We report here in situ measurements of Rb and Sr isotopes in K-rich minerals (muscovite, phlogopite, and K-feldspar) using Sensitive High-Resolution Ion MicroProbe (SHRIMP). Several grains of the K-rich minerals were extracted from eight granitic rocks with various formation ages and mounted on epoxy-resin disks. Chemical compositions were measured by an electron probe microanalyzer (EPMA). Then they were set in the source chamber of SHRIMP. A 4-5 nA mass filtered O2- primary beam was used to sputter a 30-λm-diameter flat-bottomed crater and secondary positive ions were extracted by a 10 kV accelerating voltage for mass analysis. A mass resolution of 8900-9300 at 1% peak height was attained to reduce isobaric hydride interferences such as 87RbH+ on 88Sr+. The magnet was cyclically peak-stepped from mass 84 (84Sr and 28Si56Fe) to mass 88 (88Sr and 30Si58Fe), including the background, mass 85 for 85Rb ad 29Si56Fe, mass 86 for 86Sr and 30Si56Fe, and mass 87 for 87Rb, 87Sr, and 29Si58Fe, respectively. No SiFe compounds of any mass number contributed significantly for the samples analyzed. Observed 87A/85A ratios (where A is an arbitrary element) were plotted against 88A/85A ratios for each sample. A least-square fitting was made in the diagram. The gradient and Y-intercept correspond to initial 87Sr/88Sr and initial 87Rb/85Rb ratios or present (87Rb/85Rb) + (87Sr*/85Rb) ratios, respectively, where ''*'' denotes radiogenic. The initial 87Sr/88Sr ratios are mostly consistent with the upper mantle 87Sr/88Sr ratios of various ages within experimental error. There is a positive correlation between the initial 87Rb/85Rb ratios and formation ages of the granitic rock samples, as it is expected from 87Rb decay. Further evaluation of the instrumental isotopic mass fractionation and relative sensitivities for Rb and Sr are required before the in situ 87Rb-87Sr measurement is routinely applied as a dating method. (author)

  14. Sr-Nd isotopes constrain on the deposit history of the basins in the Gulf of Mexico

    Li, Y.; Jiang, S.

    2015-12-01

    The Brazos-Trinity Basin IV and Ursa Basin are situated on the northern slope of the Gulf of Mexico. The Ursa basin lies in the center of late Pleistocene Mississippi River deposition, received the sediment deposition during Marine Isotope Stage (MIS) 2- 4. The Brazos-Trinity Basin IV belongs to a part of the Brazos-Trinity fan, it recorded the turbidite deposition and hemiplegic deposition during MIS1- 5. The Sr and Nd isotopic composition of the detrital composition of the sediment in both basins indicates the change of the sediment provenance during the basin-filled process. In the Ursa basin, The difference of 87Sr/86Sr ratio and ɛNd of the detrital component between MIS1,2 (87Sr/86Sr ~ 0.7219 - 0.7321, ɛNd ~ -12 - -13.4) and MIS3,4(87Sr/86Sr ~ 0.7310 - 0.7354, ɛNd ~ -16 - -17.9) is suggested to be related with the provenance change of the detrital particles since LGM. The addition of detrital particle from Appalachians with less radiogenic 87Sr/86Sr and positive ɛNd altered the character of the sediment of the Mississippi River during the last glaciation and deglaciation. In the Brazos-Trinity Basin IV, the narrow range of 87Sr/86Sr and ɛNd indicate that the sediment source of Brazos-Trinity Basin IV had not changed obviously during MIS5e to MIS2, mostly from coastal rivers such as Brazos River, Trinity River and Sabine River. The pre-fan with 87Sr/86Sr ~0.735 and ɛNd ~ -14.5 to -16.9, which is very similar to the deep sediment in the Ursa Basin with 87Sr/86Sr ~0.733 to 0.735 and ɛNd ~ -16 to -18. It is suggested that sediments of the pre-fan of the Brazos-Trinity Basin IV were supplied from the ancestral Mississippi River Delta during the low sea level (MIS 6). During the MIS5, the discharge of Mississippi River is thought switched to its present course, ~300 km to the east.

  15. Tracing Nile sediment sources by Sr and Nd isotope signatures (Uganda, Ethiopia, Sudan)

    Padoan, Marta; Garzanti, Eduardo; Harlavan, Yehudit; Villa, Igor Maria

    2011-06-01

    Strontium and neodymium isotopes, measured on diverse mud and sand fractions of sediment in transit along all major Nile branches, identify detritus sourced from Precambrian basements, Mesozoic strata, and Tertiary volcanic rocks exposed along the shoulders of the East African rift and in Ethiopian highlands. Sr and Nd isotopic ratios reflect the weighted average of detrital components generated in different catchments, allowing us to discriminate provenance, calculate sediment budgets, and investigate grain-size and hydraulic-sorting effects. 87Sr/ 86Sr and 143Nd/ 144Nd range, respectively, from as high as 0.722 and as low as 0.5108 for sediment derived from Archean gneisses in northern Uganda, to 0.705 and 0.5127 for sediment derived from Neoproterozoic Ethiopian and Eritrean basements. 87Sr/ 86Sr and 143Nd/ 144Nd, ranging 0.705-0.709 and 0.5124-0.5130 for Blue Nile tributaries, are 0.704-0.705 and 0.5127-0.5128 for largely volcaniclastic sediments of River Tekeze-Atbara, and 0.705-0.706 and 0.5126-0.5127 for main Nile sediments upstream Lake Nasser. Model mantle derivation ages ( tDM), oldest in Uganda where sediment is principally derived from the Congo Craton (3.4-3.0 Ga for Victoria and Albert Nile), progressively decrease northward across the Saharan Metacraton, from 2.6 Ga (Bahr el Jebel in South Sudan), to 2.4-2.2 Ga (Bahr ez Zeraf across the Sudd), and finally 1.6-1.3 Ga (White Nile upstream Khartoum). Instead, tDM ages of Sobat mud increase from 0.9 to 1.5 Ga across the Machar marshes. TDM ages are younger for sediments shed by Ethiopian (1.2-0.7 Ga) and Eritrean basements (1.5-1.2 Ga), and youngest for sediments shed from Ethiopian flood basalts (0.3-0.2 Ga). Integrated geochemical, mineralogical, and settling-equivalence analyses suggest influence on the Nd isotopic signal by volcanic lithic grains and titanite rather than by LREE-rich monazite or allanite. Because contributions by ultradense minerals is subordinate, intrasample variability of Sr and

  16. Geochemical research on C-O and Sr-Nd isotopes of mantle-derived rocks from Shandong Province, China

    LIU Jianming; ZHANG Hongfu; SUN Jinggui; YE Jie

    2004-01-01

    This paper presents systematic studies on the C-O and Sr-Nd isotopic compositions for Cretaceous Badou carbonatites, Fangcheng basalts, and Jiaodong lamprophyres and Paleozoic Mengyin kimberlites in Shandong Province, China. Paleozoic kimberlites have normal and uniform C-O isotopic compositions with δ13C and δ18O in the range of -4.8‰--7.6‰ and +9.9‰-+13.2‰, respectively. However, Cretaceous three different types of mantle-derived rocks have quite different C-O isotopic compositions, indicating that the mantle sources are probably partially contaminated with organic carbon-bearing crustal materials. These Cretaceous rocks show uniform and EMII-like Sr-Nd isotopic compositions and also indicate that the mantle sources were affected by recycled crustal materials. Comparative studies of C-O and Sr-Nd isotopes reveal that the lithospheric mantle beneath the eastern North China Craton had different isotope characteristics in the Paleozoic, the early Cretaceous, and the Tertiary time. This demonstrates that the lithospheric mantle beneath the region underwent at least twice reconstructions since the Paleozoic. Available data imply that the first reconstruction mainly happened during the Triassic-Jurassic time with gradual changes and the second in the Cretaceous with abrupt changes. Results also show that the early Cretaceous (especially at 120-130 Ma) was perhaps the key period leading to the dramatic change of the Mesozoic geodynamics on the eastern North China Craton.

  17. Accurate Modeling of the Cubic and Antiferrodistortive Phases of SrTiO3 with Screened Hybrid Density Functional Theory

    El-Mellouhi, Fadwa; Lucero, Melissa J; Scuseria, Gustavo E

    2011-01-01

    We have calculated the properties of SrTiO3 (STO) using a wide array of density functionals ranging from standard semi-local functionals to modern range-separated hybrids, combined with several basis sets of varying size/quality. We show how these combination's predictive ability varies signi?cantly, both for STO's cubic and antiferrodistortive (AFD) phases, with the greatest variation in functional/basis set e?cacy seen in modeling the AFD phase. The screened hybrid functionals we utilized predict the structural properties of both phases in very good agreement with experiment, especially if used with large (but still computationally tractable) basis sets. The most accurate results presented in this study, namely those from HSE06/modi?ed-def2-TZVP, stand as the most accurate modeling of STO to date when compared to the literature; these results agree well with experimental structural and electronic properties as well as providing insight into the band structure alteration during the phase transition.

  18. Comprehensive Pb-Sr-Nd-Hf isotopic, trace element, and mineralogical characterization of mafic to ultramafic rock reference materials

    Fourny, Anaïs.; Weis, Dominique; Scoates, James S.

    2016-03-01

    Controlling the accuracy and precision of geochemical analyses requires the use of characterized reference materials with matrices similar to those of the unknown samples being analyzed. We report a comprehensive Pb-Sr-Nd-Hf isotopic and trace element concentration data set, combined with quantitative phase analysis by XRD Rietveld refinement, for a wide range of mafic to ultramafic rock reference materials analyzed at the Pacific Centre for Isotopic and Geochemical Research, University of British Columbia. The samples include a pyroxenite (NIM-P), five basalts (BHVO-2, BIR-1a, JB-3, BE-N, GSR-3), a diabase (W-2), a dolerite (DNC-1), a norite (NIM-N), and an anorthosite (AN-G); results from a leucogabbro (Stillwater) are also reported. Individual isotopic ratios determined by MC-ICP-MS and TIMS, and multielement analyses by HR-ICP-MS are reported with 4-12 complete analytical duplicates for each sample. The basaltic reference materials have coherent Sr and Nd isotopic ratios with external precision below 50 ppm (2SD) and below 100 ppm for Hf isotopes (except BIR-1a). For Pb isotopic reproducibility, several of the basalts (JB-3, BHVO-2) require acid leaching prior to dissolution. The plutonic reference materials also have coherent Sr and Nd isotopic ratios (<50 ppm), however, obtaining good reproducibility for Pb and Hf isotopic ratios is more challenging for NIM-P, NIM-N, and AN-G due to a variety of factors, including postcrystallization Pb mobility and the presence of accessory zircon. Collectively, these results form a comprehensive new database that can be used by the geochemical community for evaluating the radiogenic isotope and trace element compositions of volcanic and plutonic mafic-ultramafic rocks.

  19. Using Monte Carlo transport to accurately predict isotope production and activation analysis rates at the University of Missouri research reactor

    A detailed Monte Carlo N-Particle Transport Code (MCNP5) model of the University of Missouri research reactor (MURR) has been developed. The ability of the model to accurately predict isotope production rates was verified by comparing measured and calculated neutron- capture reaction rates for numerous isotopes. In addition to thermal (1/v) monitors, the benchmarking included a number of isotopes whose (n, γ) reaction rates are very sensitive to the epithermal portion of the neutron spectrum. Using the most recent neutron libraries (ENDF/ B-VII.0), the model was able to accurately predict the measured reaction rates in all cases. The model was then combined with ORIGEN 2.2, via MONTEBURNS 2.0, to calculate production of 99Mo from fission of low-enriched uranium foils. The model was used to investigate both annular and plate LEU foil targets in a variety of arrangements in a graphite irradiation wedge to optimize the production of 99Mo. (author)

  20. Environmental isotopes (18O, 2H, and 87Sr/86Sr) as a tool in groundwater investigations in the Keta Basin, Ghana

    Jørgensen, Niels; Banoeng-Yakubo, Bruce

    2001-03-01

    Analyses of environmental isotopes (18O, 2H, and 87Sr/86Sr) are applied to groundwater studies with emphasis on saline groundwater in aquifers in the Keta Basin, Ghana. The 87Sr/86Sr ratios of groundwater and surface water of the Keta Basin primarily reflect the geology and the mineralogical composition of the formations in the catchments and recharge areas. The isotopic compositions of 18O and 2H of deep groundwater have small variations and plot close to the global meteoric water line. Shallow groundwater and surface water have considerably larger variations in isotopic compositions, which reflect evaporation and preservation of seasonal fluctuations. A significant excess of chloride in shallow groundwater in comparison to the calculated evaporation loss is the result of a combination of evaporation and marine sources. Groundwaters from deep wells and dug wells in near-coastal aquifers are characterized by relatively high chloride contents, and the significance of marine influence is evidenced by well-defined mixing lines for strontium isotopes, and hydrogen and oxygen stable isotopes, with isotopic compositions of seawater as one end member. The results derived from environmental isotopes in this study demonstrate that a multi-isotope approach is a useful tool to identify the origin and sources of saline groundwater. Résumé. L'analyse des isotopes du milieu (18O, 2H, et 87Sr/86Sr) a été mise en œuvre pour des études hydrogéologiques portant sur des eaux souterraines salées des aquifères du bassin de Keta (Ghana). Les rapports isotopiques 87Sr/86Sr de l'eau souterraine et de l'eau de surface du bassin de Keta reflètent principalement la géologie et la composition minéralogique des formations des bassins d'alimentation et des zones de recharge. Les compositions isotopiques en 18O et en 2H des eaux souterraines profondes présentent de faibles variations et se placent près de la droite des eaux météoriques mondiales. Les eaux des nappes peu profondes

  1. Environmental isotopes (18O, 2H, and 87Sr/86Sr) as a tool in groundwater investigations in the Keta Basin, Ghana

    Jørgensen, Niels; Banoeng-Yakubo, Bruce

    2001-03-01

    Analyses of environmental isotopes (18O, 2H, and 87Sr/86Sr) are applied to groundwater studies with emphasis on saline groundwater in aquifers in the Keta Basin, Ghana. The 87Sr/86Sr ratios of groundwater and surface water of the Keta Basin primarily reflect the geology and the mineralogical composition of the formations in the catchments and recharge areas. The isotopic compositions of 18O and 2H of deep groundwater have small variations and plot close to the global meteoric water line. Shallow groundwater and surface water have considerably larger variations in isotopic compositions, which reflect evaporation and preservation of seasonal fluctuations. A significant excess of chloride in shallow groundwater in comparison to the calculated evaporation loss is the result of a combination of evaporation and marine sources. Groundwaters from deep wells and dug wells in near-coastal aquifers are characterized by relatively high chloride contents, and the significance of marine influence is evidenced by well-defined mixing lines for strontium isotopes, and hydrogen and oxygen stable isotopes, with isotopic compositions of seawater as one end member. The results derived from environmental isotopes in this study demonstrate that a multi-isotope approach is a useful tool to identify the origin and sources of saline groundwater. Résumé. L'analyse des isotopes du milieu (18O, 2H, et 87Sr/86Sr) a été mise en œuvre pour des études hydrogéologiques portant sur des eaux souterraines salées des aquifères du bassin de Keta (Ghana). Les rapports isotopiques 87Sr/86Sr de l'eau souterraine et de l'eau de surface du bassin de Keta reflètent principalement la géologie et la composition minéralogique des formations des bassins d'alimentation et des zones de recharge. Les compositions isotopiques en 18O et en 2H des eaux souterraines profondes présentent de faibles variations et se placent près de la droite des eaux météoriques mondiales. Les eaux des nappes peu profondes

  2. Nd and SR isotopic compositions of tektite material from Barbados and their relationship to North American tektites

    Ngo, H. H.; Wasserburg, J.; Glass, B. P.

    1985-06-01

    The isotopic composition of microtektites from Barbados was determined to establish their possible source and their relationship to known tektite strewn fields. Analyzed samples included microtektites and tektite fragments from the Barbados oceanic beds, samples of deep sea ooze, in which they occur, and of underlying volcanic ash, as well as glass beads from Lake Wanapitei Crater. Isotope ratios (Sr-87/Sr-86, Nd-143/Nd-144, Rb-87/Sr-86, and Sm-147/Nd-144) were determined, and the epsilon values for Sr and Nd plotted on the diagram available for the fields of North America, Australia, Ivory Coast, and Moldavite tektites. The epsilon coordinates of all Barbados microtektite and bulk tektite samples plot precisely within the narrow field determined by North American tektites (epsilon Sr, 111; epsilon Nd, -6.2), yield an Nd model age of 0.6 AE, and are distinct from all other fields. The isotopic signatures of samples from sea ooze, ash layer, and of the Lake Wanapitei glass beads are clearly different from all known tektite classes. It is concluded that the Barbados tektites are of the same source and temporal event as the North American tektites.

  3. Sr, Nd, Pb and Hf isotopic constraints on mantle sources and crustal contaminants in the Payenia volcanic province, Argentina

    Søager, Nina; Holm, Paul Martin; Thirlwall, Matthew F.

    The presented Sr, Nd, Hf and double-spike Pb-isotopic analyses of Quaternary basalts from the Payenia volcanic province in southern Mendoza, Argentina, confirm the presence of two distinct mantle types feeding the Payenia volcanism. The southern Payenia mantle source feeding the intraplate-type Río...

  4. Sr-Nd isotope geology and tectonomagmatic setting of the Dehsalm intrusives (Lut Block, Eastern Iran)

    Arjmandzadeh, Reza; Francisco Santos, Jose; Ribeiro, Sara

    2013-04-01

    The Dehsalm porphyritic shallow intrusives belong to the Lut Block volcanic-plutonic belt (central eastern Iran). Previous research on alteration, mineralization and hydrothermal fluids indicates that a Cu-Mo porphyry type mineralization system is related with these intrusives (Arjmandzadeh et al., 2012). The rocks studied in this work range in composition from gabbro-diorite to granite, with dominance of monzonites and quartz monzonites, and have geochemical features of high-K calc alkaline to shoshonitic volcanic arc suites. The trends of major element oxides on Harker diagrams, together with textural evidence, point to the crystal fractionation of clinopyroxene, Ca - plagioclase, hornblende, apatite and oxide minerals. Primitive mantle - normalized trace element spider diagrams display strong enrichment in LILE, such as Rb, Ba and Cs, and depletions in some high field strength elements (HFSE), such as Nb, Ti, Y and HREE. Chondrite-normalized plots show significant LREE enrichments, high LaN/YbN (21.5 to 31.0) and the lack of Eu anomaly. Sr/Y and La/Yb ratios of Dehsalm intrusives are respectively 31.6-72.2 and 21.5-33.5, which reveals that, despite their K-rich composition, these rocks also have some adakitic affinity. A Rb-Sr whole rock-feldspar-biotite age of 33.4±1 Ma was obtained in a quartz monzonite sample; this date may be interpreted as close to the intrusion age, considering that the chosen sample is almost unaltered and should have suffered fast cooling. The obtained age coincides, within error, with a previous geochronological result in a similar rock from the Chah-Shaljami area (Arjmandzadeh et al., 2011), further northwest along the eastern border of the Lut Block. 87Sr/86Sr(33Ma) and ɛNd(33Ma) values range from 0.70481 to 0.70508 and from +1.5 to +2.5, respectively, which fits into a supra-subduction mantle wedge source for the parental melts and indicates that crustal contribution for magma diversification was not relevant. Sr and Nd isotope

  5. Microscopic study of low-lying yrast spectra and deformation systematics in neutron-rich 98−106Sr isotopes

    Anil Chandan; Suram Singh; Arun Bharti; S K Khosa

    2009-10-01

    Variation-after-projection (VAP) calculations in conjunction with Hartree–Bogoliubov (HB) ansatz have been carried out for = 98–106 strontium isotopes. In this framework, the yrast spectra with ≥ 10+, (2) transition probabilities, quadrupole deformation parameter and occupation numbers for various shell model orbits have been obtained. The results of the calculation for yrast spectra give an indication that it is important to include the hexadecapole–hexadecapole component of the two-body interaction for obtaining various nuclear structure quantities in Sr isotopes. Besides this, it is also found that the simultaneous polarization of 3/2 and 5/2 proton subshells is a significant factor in making a sizeable contribution to the deformation in neutron-rich Sr isotopes.

  6. Use of Sr and Pb isotopes in gneissic-migmatic rocks in Itacambira-Barrocao, MG, Brazil

    This work tries to show the potential of the Rb-Sr, Pb-Pb and K-Ar methods applied to basic geological mapping. The different interpretative values of these methodologies contribute to the understanding of the tectonic processes developed in the southeastern border of the Sao Francisco Craton. The Rb-Sr and Pb-Pb isotopic data for the gneissic-migmatitic unit of this sector indicates their generation during the Archean (-2.7 Ga) and Early Proterozoic (-2.1 Ga.). The high (Sr87 /Sr86) and μ1 values also suggest an origin through reworking of older crustal rocks. The K-Ar data (and one fission track age) allow the thermal history of this domain to be delineated and suggest a vertical tectonic in the Late Brazilian Cycle, putting side by side blocks formed in different depths. (M.V.M.)

  7. Hydrogeochemistry of the surface waters of the Ebro River Basin (Spain): a view through Li-B-Sr isotopes

    Millot, R.; Guerrot, C.; Petelet-Giraud, E.; Brenot, A.; Negrel, P. J.

    2012-12-01

    In the present study, we report hydrogen, oxygen, lithium, boron and strontium isotope measurements (δ2H, δ18O, δ7Li, δ11B and 87Sr/86Sr) together with major and trace elements in the dissolved load of 25 river samples collected within the Ebro River Basin in Spain. The Ebro River Basin is mainly dominated by carbonates and evaporites from the Paleozoic and Mesozoic terrains. The Ebro river mainstream was sampled at Amposta one time per month between June 2005 and May 2006. And secondly, the Ebro river along its main course and its main tributaries were sampled during one field campaign in April 2006. The main objective of the present work is to characterize the hydrogeochemistry of the surface waters within the Ebro River Basin and to constrain the behavior of Li and B and their isotopes during water/rock interactions at the scale of a large river basin having various lithologies with a specific aim to investigate spatio-temporal variations for both Li and B isotopes signatures within the Ebro River Basin. The main goal of this study is thus to determine the sources contributing to Li and B in the river waters of the Ebro Basin, as well as to characterize the controlling factors that can determine the distribution of Li and B and their isotopes in the river waters of the Ebro Basin. Stable water isotopes (δ2H, δ18O) show that all the river waters have a purely local origin from precipitation, without significant evaporation or water/rock interaction, as all points plot close to the general meteoric-water line. In the river waters, Li isotopic signatures (δ7Li) are comprised between +12.9 and +20.9‰, δ11B values are ranging from +9.9 to +25.0‰ and 87Sr/86Sr are between 0.70786 and 0.70897.

  8. The crust role at Paramillos Altos intrusive belt: Sr and Pb isotope evidence

    Paramillos Altos Intrusive Belt (PAIB) (Ostera, 1996) is located in the thick skinned folded-thrust belt of Malargue, southwestern Mendoza, Argentina. Geochemical, geochronologic and isotopic studies were carried out in it (Ostera 1996, 1997, Ostera et al. 1999; Ostera et al. 2000) and these previous papers suggested a minor involvement of the crust in the genesis of the PAIB. According with Ostera et al. (2000) it is composed by stocks, laccoliths, dykes and sills which range in composition from diorites to granodiorites, and from andesites to rhyolites, and divided in five Members, which range in age from Middle Miocene to Early Miocene: a- Calle del Yeso Dyke Complex (CYDC), with sills and dykes of andesitic composition (age: 20±2 Ma). b- Puchenque-Atravesadas Intrusive Complex (PAIC), composed by dykes and stocks ranging from diorites to granodiorites (age: 12.5±1 Ma). c- Arroyo Serrucho Stock (SAS), an epizonal and zoned stock, with four facies, with K/Ar and Ar/Ar dates of 10±1 and 9.5±0.5 Ma. d- Portezuelo de los Cerros Bayos (PCB), that includes porphyritic rocks of rhyolitic composition, of 7.5±0.5 Ma. e- Cerro Bayo Vitrophyres (CBV), with andesitic sills and dykes (age: 4.8±0.2 Ma). We present in this paper new Sr and Pb isotopes data that constrain the evolution of the PAIB (au)

  9. Pb, Nd, Sr and Os isotopic systematics of Brazilian cretaceous potassic rocks

    Mafic potassic rocks of the Alto Paranaiba (Minas Gerais), Juina (Mato Grosso), and Pimenta BUeno (Mato Grosso) belong to a large lineament of rocks that crosses from western to southeastern Brazil and have been associated to a hot spot track by several authors. These provinces intruded the Neoproterozoic Brasilia and Paraguay fold belts (Alto Paranaiba, Paranatinga), and the Mesoproterozoic Rio Negro-Jurema belt (Juina, Pimenta Vueno). Pb isotopic compositions of the studied provinces show a wide variation. 206 Pb/204 Pb of kimberlites (18.47-19.23) and kamafugities (17.79-18.71) from the Alto Paranaiba Province are close to the Tristaan/Walvis Ridge composition. The 206 Pb/204 Pb of the paranatinga (19.38-19.87) and Pimenta Bueno (19.78-21.00) provinces are similar to the South African Group I Kimberlite compositional fields, while Juina is displaced to higher Pb isotopic ratios (21.38.22.26), close to those shown ny HIMU ocean island +(OIB).Although the Pb isotopic composition of the more northern alkalic provinces ranges towards the values seen for HIMU OIB, the Sr andNd isotopic composition of these samples is not like HIMU, nor in combination with Pb, like any other ocean island basalt. With the exception of the limberlites from the Alto Paranaiba, which range to quite unradiogenic compositions, most of the samples have 187 Os/188 Os between 0.13 and 0.15. The Nd model ages of Juina kimberlites vary from 1.70-1.73 Ga, and could be indicating a prior accretion period into the mobile belt. Nd model ages for paranatinga kimberlites vary between 0.56 and 0.64 Ga and Pimenta Bueno kimberlites from 0.72 to 1.05 Ga. Minimum Re depletion model ages for Paranatinga kimberlites vary between 0.74 and 0.93 and Pimenta Bueno kimberlites from 0.9 to 1.3 Ga, indicating that the Nd isotopic signartures could have been affected by metasomatic overprint in Neoroterozoic. (author)

  10. Combination of the (87)Sr/(86)Sr ratio and light stable isotopic values (δ(13)C, δ(15)N and δD) for identifying the geographical origin of winter wheat in China.

    Liu, Hongyan; Wei, Yimin; Lu, Hai; Wei, Shuai; Jiang, Tao; Zhang, Yingquan; Guo, Boli

    2016-12-01

    This study aims to investigate whether isotopic signatures can be used to develop reliable fingerprints for discriminating the geographical origin of Chinese winter wheat, and to evaluate the discrimination effects of δ(13)C, δ(15)N and δD, alone or with (87)Sr/(86)Sr. In this study, the values of δ(13)C, δ(15)N and δD, and the (87)Sr/(86)Sr ratios of wheat and provenance soils from three regions were determined. Significant differences were found in all parameters of wheat and (87)Sr/(86)Sr in soil extract (reflecting the bioavailable fraction of soil) among different regions. A significantly positive correlation was observed between the (87)Sr/(86)Sr ratios of wheat and soil extracts. An overall correct classification rate of 77.8% was obtained for discriminating wheat from three regions based on light stable isotopes (δ(13)C, δ(15)N, and δD). The correct classification rate of 98.1% could be obtained with the combination of the (87)Sr/(86)Sr ratio and the light stable isotopic values. PMID:27374544

  11. Sr isotopic composition in Upper Jatulian dolomites of the Tulomozero formation, South-Eastern Karelia

    Results of determining 87Sr/86Sr ratio in dolomites of the Tulomozero formation of Jatulian section of Northern Prionezshie are presented. It is shown that the pattern of initial 87Sr/86Sr ratios in dolomites of the Tulomozero formation reflects the alteration of carbonate sediment accumulation conditions and/or the degree of their secondary transformations. Carbonates in lower levels with the 87Sr/86Sr ratio of about 0.70668 formed under conditions of isolated water reservoir while in upper part deposited in semi(open) marine basins the 87Sr/86Sr ratio in which was about 0.70419

  12. Stable (Cu, Mg) and radiogenic (Sr, Nd) isotope fractionation in colloids of boreal organic-rich waters

    Stable (Cu and Mg) and radiogenic (Sr and Nd) isotopic compositions in filtrates and ultra filtrates of various size fractions have been measured in waters of subarctic watersheds (NW Russia) and in temperate rivers and lakes of the south boreal zone. A large volume of samples were filtered in the field using cascade filtration and ultrafiltration employing progressively decreasing pore sizes (100, 20, 10, 5, 0.8, 0.4, 0.22, and 0.1 μm; 100, 10 and 1 kDa) followed by element isotopic analysis using thermal ionization mass spectrometers and a Neptune multi collector ICP-MS. In the boreal watershed underlain by Archean and Proterozoic rocks, the 87Sr/86Sr ratio decreased in the 1-100 kDa ultra filtrates and dialysates by 0.0001-0.0004 units compared to the 0.45 μm filtrates. Despite the dominance of colloids in the Nd speciation in surface waters, the isotopic value of Nd in the filtrates and ultra filtrates remained constant within the uncertainty of the measurements. We hypothesize the absence of an atmospheric input of silicate dust for Nd but the presence of marine aerosols for Sr. It follows that the Sr in the investigated surface waters has a short residence time compared to the time required for achieving isotopic equilibrium between the colloidal (1 kDa-0.22 μm) and truly dissolved (≤1 kDa) pools. For Nd, the residence time is long enough to achieve this equilibrium. The stable isotope composition of Cu in the streams remained constant within ±0.1 per thousand during filtration through 100 μm to 1 kDa membranes, despite the fact that 40-60% of Cu was colloidal. This result suggests that the homogeneity of the Cu isotopic composition within the colloidal and truly dissolved pools is likely associated with the similarity of the structure and stability of Cu(II) complexes with fulvic acids of different molecular weights. The stable isotope composition of dissolved Mg in soil solution and bog surface water demonstrates similar,within the analytical

  13. Origin and Dynamics of Rare Earth Elements during Flood Events in Contaminated River Basins: Sr-Nd-Pb Isotopic Evidence.

    Hissler, Christophe; Stille, Peter; Iffly, Jean François; Guignard, Cédric; Chabaux, François; Pfister, Laurent

    2016-05-01

    In order to precisely quantify the contribution of anthropogenic activities and geogenic sources to the dissolved and suspended loads of rivers we have combined for the first time Rare Earth Element (REE) concentrations with Sr-Nd-Pb isotope ratios. We observed enrichments in Anthropogenic Rare Earth Elements (AREE) for dissolved (Gd) and suspended (Ce and Nd) loads of river water. During flood events, AREE anomalies progressively disappeared and gave way to the geogenic chemical signature of the basin in both dissolved and suspended loads. The isotopic data confirm these observations and shed new light on the trace elements sources. On the one hand, dissolved loads have peculiar isotopic characteristics and carry mainly limestone-derived and anthropogenic Sr and Nd as well as significant amounts of anthropogenic Pb. On the other hand, the results clearly indicate that anthropogenic contributions impact the suspended loads in all hydrological conditions. This study demonstrates that anthropogenic contributions to the river may change not only Pb but also Sr and Nd isotopic compositions in both dissolved and suspended loads. This is of importance for future provenance studies. PMID:27045616

  14. Sr-Nd isotope geochemistry and petrogenesis of the Chah-Shaljami granitoids (Lut Block, Eastern Iran)

    Arjmandzadeh, R.; Karimpour, M. H.; Mazaheri, S. A.; Santos, J. F.; Medina, J. M.; Homam, S. M.

    2011-05-01

    Chah-Shaljami porphyritic granitoids belong to the Lut Block volcanic-plutonic belt of central eastern Iran. These intrusive rocks are mostly quartz monzonites, granodiorites and diorites. Geochemical evidence reveals that they are co-genetic and that they have features typical of high-K calc-alkaline to shoshonitic rocks from volcanic arc setting. Primitive mantle-normalized trace element spider diagrams display strong enrichment in LILE, such as Rb, Ba, and Cs, and depletion in some HFSE, e.g. Nb, Ti, Y and HREE. Chondrite-normalized plots show a very marked REE fractionation, with significant LREE enrichment (23 ⩾ La N/Yb N ⩾ 14) and the lack of Eu anomaly. Sr/Y and La/Yb ratios of Chah-shaljami intrusives are respectively 20-67 and 21-34, which reveals that, despite their K-rich composition, these rocks also, have some adakitic affinity. Plots on the Sr/Y-Y and La/Yb-Yb diagrams show that the Chah-Shaljami intrusives may be subdivided into two distinct classes. A Rb-Sr age of 33.5 ± 1 Ma, mainly dependent on the Sr isotopic composition of biotite, was obtained in a quartz monzonite sample. Taking into account that this sample was almost unaffected by hydrothermal and meteoric alteration and that cooling was probably fast, the 33-34 Ma date is interpreted as the intrusion age. With the exception of two samples, initial 87Sr/ 86Sr ratios and C̵Nd values are clustered in the restricted ranges of 0.70470-0.70506 and +1.9-+2.7, which fits into a supra-subduction mantle wedge source for the parental melts and indicates that, in general, crustal contribution for magma diversification was not relevant; however, one sample shows higher 87Sr/ 86Sr and lower C̵Nd, revealing that, occasionally, crustal rock assimilation also contributed to geochemical variation; one other sample, strongly affected by hydrothermal alteration, departs from the main group only by higher 87Sr/ 86Sr, suggesting that its alteration involved crustal fluids. Sr and Nd isotope compositions

  15. Tracing of aerosol sources in an urban environment using carbonaceous, major ions, Sr isotope, and mineralogical compositional data

    Paula, A; S. Lopes; Ribeiro, S.; Santos, J. F.; Patinha, C.; Silva, E. A. Ferreira da; Soares, R.; Duarte, R.; A. Duarte

    2015-01-01

    Understanding the chemical composition of atmospheric particulate matter (PM), particularly with a diameter less than 2.5 μm (PM2.5), has became an emergent topic in atmospheric research due to its relation to climate change and serious health issues. In this study, a comprehensive assessment of the carbonaceous (organic carbon, water-soluble organic carbon, elemental carbon), major water-soluble inorganic ions (SO42-, NO3-, NH4+, Cl-, K+, Na+), 86Sr/87Sr isotope ratios, and mineralogical com...

  16. Hydrogeochemistry of the surface waters of the Ebro River Basin (Spain): a view through Li-B-Sr isotopes

    Millot, Romain; Guerrot, Catherine; Petelet Giraud, Emmanuelle; Brenot, Agnès; Négrel, Philippe

    2012-01-01

    In the present study, we report hydrogen, oxygen, lithium, boron and strontium isotope measurements (d2H, d18O, d7Li, d11B and 87Sr/86Sr) together with major and trace elements in the dissolved load of 25 river samples collected within the Ebro River Basin in Spain. The Ebro River Basin is mainly dominated by carbonates and evaporites from the Paleozoic and Mesozoic terrains. The Ebro river mainstream was sampled at Amposta one time per month between June 2005 and May 2006. And secondly, the ...

  17. Nd and Sr isotope compositions in modern and fossil bones - Proxies for vertebrate provenance and taphonomy

    Tütken, Thomas; Vennemann, Torsten W.; Pfretzschner, Hans-U.

    2011-10-01

    Rare earth elements (REE), while not essential for the physiologic functions of animals, are ingested and incorporated in ppb concentrations in bones and teeth. Nd isotope compositions of modern bones of animals from isotopically distinct habitats demonstrate that the 143Nd/ 144Nd of the apatite can be used as a fingerprint for bedrock geology or ambient water mass. This potentially allows the provenance and migration of extant vertebrates to be traced, similar to the use of Sr isotopes. Although REE may be enriched by up to 5 orders of magnitude during diagenesis and recrystallization of bone apatite, in vivo143Nd/ 144Nd may be preserved in the inner cortex of fossil bones or enamel. However, tracking the provenance of ancient or extinct vertebrates is possible only for well-preserved archeological and paleontological skeletal remains with in vivo-like Nd contents at the ppb-level. Intra-bone and -tooth REE analysis can be used to screen for appropriate areas. Large intra-bone Nd concentration gradients of 10 1-10 3 are often measured. Nd concentrations in the inner bone cortex increase over timescales of millions of years, while bone rims may be enriched over millenial timescales. Nevertheless, ɛ Nd values are often similar within one ɛ Nd unit within a single bone. Larger intra-bone differences in specimens may either reflect a partial preservation of in vivo values or changing ɛ Nd values of the diagenetic fluid during fossilization. However, most fossil specimens and the outer rims of bones will record taphonomic 143Nd/ 144Nd incorporated post mortem during diagenesis. Unlike REE patterns, 143Nd/ 144Nd are not biased by fractionation processes during REE-uptake into the apatite crystal lattice, hence the ɛ Nd value is an important tracer for taphonomy and reworking. Bones and teeth from autochthonous fossil assemblages have small variations of ±1 ɛ Nd unit only. In contrast, fossil bones and teeth from over 20 different marine and terrestrial fossil

  18. Basic magmatism in geological history of Elbrus neovolcanic area (Greater Caucasus): evidence from K-Ar and Sr-Nd isotope data

    The results of isotope-geochronological study of two samples of basites and two samples of basic lavas of Elbrus neovolcanic area are presented. According to K-Ar dating the lavas isotope age falls in the range of 3.85-3.65 mln. years. The results of studying Sr-Nd isotope systematization of Elbrus area basic lavas suggest that the rocks studied are characterized by different isotope parameters of strontium and neodymium

  19. 137Cs(90Sr) and Pu isotopes in the Pacific Ocean sources & trends

    Hamilton, T.F., Millies-Lacrox, J.C. [Service Mixte de Securite Radologique, Mondhery (France); Hong, G.H. [Korea Ocean Research and Development Institute, Ansan (Korea)

    1996-11-01

    The main source of artificial radioactivity in the world`s oceans can be attributed to worldwide fallout from atmospheric nuclear weapons testing. Measurements of selected artificial radionuclides in the Pacific Ocean were first conducted in the 1960`s where it was observed that fallout radioactivity had penetrated the deep ocean. Extensive studies carried out during the 1973-74 GEOSECS provided the first comprehensive data on the lateral and vertical distributions of {sup 9O}Sr, {sup 137}Cs and Pu isotopes in the Pacific on a basin wide scale. Estimates of radionuclide inventories in excess of amounts predicted to be delivered by global fallout alone were attributed to close-in fallout and tropospheric inputs from early U.S. tests conducted on Bikini and Enewetak Atolls in the Equatorial Pacific. In general, levels of fallout radionuclides (including {sup 9O}Sr, {sup 137}Cs and Pu isotopes) in the surface waters of the Pacific Ocean have decreased considerably over the past 4 decades and are now much more homogeneously distributed. Resuspension and the subsequent deposition of fallout radionuclides from previously deposited debris on land has become an important source term for the surface ocean. This can be clearly seen in measurements of fallout radionuclides in mineral aerosols over the Korean Peninsula (Yellow dust events). Radionuclides may also be transported from land to sea in river runoff-these transport mechanisms are more important in the Pacific Ocean where large quantities of river water and suspended sands/fluvial sediments reach the coastal zone. Another unique source of artificial radionuclides in the Pacific Ocean is derived from the slow resolubilization and transport of radionuclides deposited in contaminated lagoon and slope sediments near U.S. and French test sites. Although there is a small but significant flux of artificial radionuclides depositing on the sea floor, > 80% of the total 239, {sup 240}Pu inventory and > 95% of the total {sup

  20. Os, Sr, Nd, and Pb isotope systematics of southern African peridotite xenoliths - Implications for the chemical evolution of subcontinental mantle

    Walker, R. J.; Carlson, R. W.; Shirey, S. B.; Boyd, F. R.

    1989-01-01

    Isotope analyses of Os, Sr, Nd, and Pb elements were caried out on twelve peridotite xenoliths from the Jagersfontein, Letseng-la-terae, Thaba Patsoa, Mothae, and Premier kimberlites of southern Africa, to investigate the timing and the nature of melt extraction from the continental lithosphere and its relation to the continent formation and stabilization. The distinct Os and Pb isotopic characteristics found in these samples suggested that both the low- and the high-temperature peridotites reside in an ancient stable lithospheric 'keel' to the craton that has been isolated from chemical exchange with the sublithospheric mantle for time periods in excess of 2 Ga.

  1. Rb-Sr Isotopic Systematics of Alkali-Rich Fragments in the Yamato-74442 LL-Chondritic Breccia

    Yokoyama, T.; Misawa, K.; Okano, O.; Shih, C.-Y.; Nyquist, L. E.; Simo, J. I.; Tappa, M. J.; Yoneda, S.

    2012-01-01

    Alkali-rich igneous fragments were identified in the brecciated LL-chondrites, Kr henberg (LL5)], Bhola (LL3-6) and Yamato (Y)-74442 (LL4), and show characteristic fractionation patterns of alkaline elements. The K-Rb-Cs-rich fragments in Kr henberg, Bhola, and Y-74442 are very similar in mineralogy and petrography (olivine + pyroxene + glass), suggesting that they could have come from related precursor materials. We have undertaken Rb-Sr isotopic studies on alkali-rich fragments in Y-74442 to precisely determine their crystallization ages and the isotopic signatures of their precursor material(s).

  2. Archean and proterozoic in the West-European Hercynian chain: isotopic geochemistry (Sr-Nd-Pb) and U-Pb geochronology on zircons

    The first part of this research thesis reports the study of isotopic (Sr-Nd-Pb) geochemistry and U-Pb geochronology on zircons in the immersed granulites of the Bay of Biscay: U-Pb geochronology on zircons, Nd isotopic geochemistry, Sr isotopic geochemistry, common Pb, Rb-Sr, Sm-Nd and rare earth data on minerals, comparison with other European granulites, comparison with West-Africa, study of Archean and proterozoic in the Hercynian chain. The second part reports the study of the U-Pb geochronology on zircon in the Cadomian, and the third part addresses the Sr-Nd isotopic geochemistry of some Cadomian granitoid, and the crust contamination in different regions

  3. Sr-Pb-Nd isotopic evidence that both MORB and OIB sources contribute to oceanic island arc magmas in Fiji

    Twenty-eight new Pb, 20 Sr, and 9 Nd isotopic compositions are presented for 32 rocks and one galena from Fiji and the South Fiji (back-arc) Basin. The Fijian rocks range in age from 35 to 143Nd/144Nd and low 206Pb/204Pb). Nearly constant 207Pb/204Pb, and an OIB source component lying within the conventional Sr-Nd-Pb mantle array. In later calc-alkaline and shoshonitic series rocks, these same trace element and isotopic ratios are more like those of OIB. The change was not accompanied by an increase in 207Pb/204Pb or Cs/K, indeed, 207Pb/204Pb is closer to the mantle array in these later series. Consequently, the change indicates a greater contribution from OIB sources, rather than from recycled ocean crust. These interpretations require that both MORB and OIB sources coexist in the uppermost mantle above subducted lithosphere. (orig./WB)

  4. Cooling of Sr to high phase-space density by laser and sympathetic cooling in isotopic mixtures

    Ferrari, G; Drullinger, R. E.; Poli, N.; Sorrentino, F.; Tino, G. M.

    2006-01-01

    Based on an experimental study of two-body and three-body collisions in ultracold strontium samples, a novel optical-sympathetic cooling method in isotopic mixtures is demonstrated. Without evaporative cooling, a phase-space density of $6\\times10^{-2}$ is obtained with a high spatial density that should allow to overcome the difficulties encountered so far to reach quantum degeneracy for Sr atoms.

  5. Nd, O and Sr isotopic constraints on the origin of Precambrian rocks, Southern Black Hills, South Dakota

    The Nd, O and Sr isotopic characteristics of Precambrian metasedimentary, metavolcanic and granitic rocks from the Black Hills of South Dakota are examined. Two late-Archean granites (2.5-2.6 Ga) have Tsub(DM) ages of 3.05 and 3.30 Ga, suggesting that at least one of the granites was derived through the melting of significantly older crust. Early-Proterozoic metasedimentary rocks have Tsub(DM) ages that range from 2.32 to 2.45 Ga. Two granite samples taken from the same sill, however, give two-point Rb-Sr and Sm-Nd ages of 2.08 +- 0.08 and 2.20 +- 0.20 Ga (epsilon2200sub(Nd) = -15.5), respectively. In addition, whole-rock and apatite samples of the spatially associated Tin Mountain pegmatite give a Sm-Nd isochron age of 2000 +- 100 Ma (epsilon2000sub(Nd) = -5.8 +- 1.8). The Sm-Nd, O and Rb-Sr isotopic systematics of these granitic rocks have been complicated to some degree by both crystallization and post-crystallization processes, and the age of the pegmatite and parts of the Harney Peak Granite complex remain uncertain. Processes that probably complicated the isotopic systematics of these rocks include derivation from heterogeneous source material, assimilation, mixing of REE between granite and country rock during crystallization via a fluid phase, and post-crystallization mobility of Sr. The Nd isotopic compositions of the pegmatite and the Harney Peak Granite indicate that they were not derived primarily from the exposed metasedimentary rocks. (author)

  6. Pervasive Crustal Melting on a Regional Scale: Sr-Nd Isotopic Evidence from Eocene Intrusions in NE Washington

    Loewen, M. W.; Tepper, J. H.; Asmerom, Y.

    2007-12-01

    During the Eocene the Pacific Northwest was the site of a short-lived but voluminous and geochemically diverse magmatic episode, commonly termed the Challis event. To investigate the origins of this event we have measured whole rock Sr and Nd isotopic compositions of 12 plutonic and hypabyssal samples, ranging from basalt to two-mica granite, collected along a 250 km transect across NE Washington. This transect crosses the 0.706 line (Armstrong 1977), the boundary between dominantly Mesozoic crust to the west and older crust to the east. The results reveal a wide spread in isotopic compositions (87Sr/86Srm = 0.7041 - 0.7262; ɛNdm = +3.8 to -18.5) with no systematic relationship between isotopic composition and bulk composition (e.g., MgO). This decoupling of isotopic composition and bulk chemistry suggests mixing between mantle and crustal melts was of minimal importance, and that these rocks are dominantly of crustal origin. The range in ɛNdm also indicates melting of crustal sources that varied considerably in age. Samples with ɛNdm > +2 range from basalt (13 wt.% MgO) to two-mica granite (0.3 wt.% MgO). Such juvenile ɛNdm in a two-mica granite precludes significant involvement of ancient metasedimentary material and implies rapid intracrustal differentiation of a mantle-derived source, which may have been deep arc crust of Mesozoic age. At the other end of the spectrum, samples with ɛNdm Monzonite and attributed to melting of late Archean to Early Proterozoic crust (Whitehouse et al. 1992). Other samples analyzed in this study are broadly similar in isotopic composition (ɛNdm = +1 to -8; 87Sr/86Srm = 0.706-0.709) to rocks of the Colville Igneous Province and probably formed by melting of Proterozoic arc crust (Morris 2000). Geographic variability in Sr-Nd data indicates that isotopically distinct crustal domains are juxtaposed laterally and/or vertically, in some cases on a small scale. The sample with the highest 87Sr/86Srm (0.7262; ɛNdm = -13.3) is a

  7. Textural and Rb-Sr isotopic evidence for late Paleozoic mylonitization within the Honey Hill fault zone southeastern Connecticut

    A petrographic and Rb-Sr isotopic study of rocks within and near the Honey Hill fault zone places important constraints on its history of movement. Rb-Sr apparent ages for micas and plagioclase from these rocks have been reset and range from Permian to Triassic, considerably younger than the minimum stratigraphic age (Ordovician) of the rocks studied or of Acadian (Devonian) regional metamorphism. Permian Rb-Sr ages of dynamically recrystallized muscovite date the development of mylonite fabric. An older age is precluded by the excellent preservation of unrecovered quartz, which indicates that these rocks did not experience temperatures high enough to anneal quartz or thermally reset Rb-Sr isotopic systems in muscovite since the time of mylonitization. Metamorphic mineral assemblages and mineral apparent ages in rocks north of the fault zone indicate recrystallization under similar upper greenschist-lower amphibolite grade conditions during Permian to Triassic time. Collectively these results indicate that the Honey Hill fault zone was active during the Late Paleozoic and that ductile deformation and metamorphism associated with the Alleghanian orogeny extend well into southern Connecticut. An Alleghanian age for mylonitization within the Honey Hill fault zone suggests it should be considered as a possible site for the major Late Paleozoic strike-slip displacements inferred from paleomagnetic studies for parts of coastal New England and maritime Canada

  8. Rb-Sr isotopic study of the Muruntau deposit: magmatism, metamorphism, and mineralization

    The results of Rb-Sr isochrone isotopic-geochronological studies of metamorphic and igneous rocks in the vicinity of the Muruntau deposit, central Kyzyl Kum Desert, are reported. Combined with the previously published data for the hydrothermal-metasomatic rocks, this study outlines the chronology of this gigantic deposit. Greenschist-facies metamorphism of the ore-hosting Besapan Formation is dated at 40±11 Ma. The main stage of productive hydrothermal activity at the Muruntau deposit was coeval with the formation of Stage 2 igneous rocks (273.1±1.6 Ma), but not coeval with the emplacement of Stage 1 granitoids. The temporal association of the early productive metasomatites and Stage 2 dykes indicates that Stage 2 magmatism and early metasomatism had a common source of energy. Subsequent ore redeposition occurred in discrete pulses at 257.6±2.2, 230.2±3.5 and 219.4±4.2 Ma, which were due to the pulses of regional tectonic activity. 27 refs.; 4 figs.; 3 tabs

  9. Sr-Nd-Pb isotopes of the post-paleozoic magmatism from eastern Paraguay

    The Parana Angola-Namibia igneous province (PAN) is characterized by Early Cretaceous flood tholeiites and tholeiitic dyke swarms associated with alkaline rocks of Early and Late Cretaceous ages, respectively, and with scarce post-Mesozoic magmatic rocks (Comin-Chiaramonti et al., 1997; 1999; Marques et al., 1999). The Eastern Paraguay, at the westernmost side of the Parana Basin, is of special interest because: (1) it is located between two main cratonic blocks, i.e. the southernmost tip of the Amazon Craton, and the northermost exposure of the Rio de La Plata Craton; (2) it was the site of repeated Na-K-alkaline magmatism since Late-Permian-Triassic times (i.e.: 250-240 Ma, Na-alkaline; c. 145 Ma, K-alkaline; 128-126 Ma, K-alkaline; 120-90 Ma, Na-alkaline; 61-33 Ma, Na-alkaline; cf. Comin-Chiaramonti and Gomes, 1996; Comin-Chiaramonti et al., 1999), and of Early Cretaceous tholeiitic magmatism, both low- and high-Ti variants, L-Ti and H-Ti, respectively (133-131 Ma; cf. Marzoli et al., 1999); (3) the younger sodic magmatic rocks are closely associated in space to the potassic analogues (Comin- Chiaramonti et al., 1999). The paper aims discussing the most important Sr- Nd-Pb isotope features of the alkaline and tholeiitic magmas from Eastern Paraguay in comparison with the PAN analogues (au)

  10. The geographic distribution of Sr isotopes from surface waters and soil extracts over the island of Bornholm (Denmark) – A base for provenance studies in archaeology and agriculture

    Highlights: • Establishment of distribution map of bioavailable strontium signatures on Bornholm. • Surface water and soil extract signatures incompletely reflect basement geology. • Baselines allow distinction between a northern and southern provenance on Bornholm. • Marine salts have a strong influence on bioavailable strontium signatures. • Successful application of baselines to the Grødbygård archaelogical site on Bornholm. - Abstract: In this paper we report the Sr isotope signatures, and Sr, Al and Na concentrations of 30 surface waters (lakes/ponds and rivers/creeks) and 19 soil sample extracts from the island of Bornholm (Denmark) and present a categorized 87Sr/86Sr value distribution map that may serve as a base for provenance studies, including archaeological migration and authenticity proof for particular food products. The Sr isotopic compositions of surface waters range from 87Sr/86Sr = 0.7097–0.7281 (average 0.7175 ± 0.0049; 1σ), whereas 0.1 M HNO3, 0.05 M HNO3, and 0.01 M CaCl2 soil extracts range from 87Sr/86Sr = 0.7095–0.7197 and define somewhat lower but statistically indistinguishable averages of 0.7125 ± 0.003 (1s). These compositions are lower than the values expected from the Precambrian granitoid basement (87Sr/86Sr = 0.758–0.944), and from the overlying, mainly clastic Paleozoic sediments. Combined Sr isotope composition vs. Sr, Na and Al concentration relationships of soil extracts imply that lowering of the isotopic composition of leachable Sr on Bornholm results as a consequence of significant admixture to this fraction of Sr deposited as marine salts (aerosols), and that rainwater only has a minor influence on the Sr budget of the surface waters. Positively correlated Al/Na and [1/Sr] vs. 87Sr/86Sr relationships in soil extracts and surface waters indicate that the surface run-off on Bornholm is characterized by two predominant sources, namely marine aerosols (sea salts) with high Sr and low 87Sr/86Sr values, and a

  11. Sr Nd Pb isotopic constraints on multiple mantle domains for Mesozoic mafic rocks beneath the South China Block hinterland

    Wang, Yuejun; Fan, Weiming; Cawood, Peter A.; Li, Sanzhong

    2008-12-01

    The Sr-Nd and Pb isotopic compositions of middle Jurassic to late Cretaceous mafic rocks across the Chenzhou-Linwu Fault within the South China Block are presented to constrain the characteristics and evolution of Mesozoic mantle source. These data, in combination with geochronological results, can be divided into four groups. Group 1 (~ 175-170 Ma) occurs on either side of the Chenzhou-Linwu Fault and has moderately depleted Sr-Nd and radiogenic Pb isotopes, akin to a FOZO-like source and is inferred to have originated from deep asthenospheric mantle with delaminated lower crustal signatures. Group 2 (~ 175-145 Ma) is restricted to the west of the fault and shows a significant Dupal anomaly and a binary mixing array between a component from an enriched mantle source (EM1) with low ɛNd( t) values and 206Pb/ 204Pb, and intermediate 87Sr/ 86Sr ratios and a FOZO-like component characterized by Group 1. Group 3 (~ 175-125 Ma) occurs to the east of the fault and exhibits low ɛNd( t) values and high Sr-Pb isotopic ratios, similar to EM2 component with minor DMM component. The Sr-Nd-Pb isotopic systematics for Group 4 (~ 93-80 Ma) resembles those of SE China Cenozoic basalts, suggestive of DMM-EM2 reservoir in response to the uppermost asthenospheric mantle source. These temporal and spatial variations, together with other geologic and paleomagnetic data, suggest that (1) the multiple mantle reservoirs include FOZO-, DMM-, EM1- and EM2-like components beneath the South China Block; (2) DMM-EM2 sources have dominated the mantle domains beneath SE Asia since late Cretaceous; (3) the Chenzhou-Linwu Fault corresponds with the early Mesozoic lithospheric boundary between the Yangtze and Cathaysia blocks within the South China Block. The Mesozoic mafic rocks within the South China Block developed in an active rift setting in response to the delamination of partially over-thickened lithospheric keel and upwelling of asthenosphere rather than a supra-subduction environment.

  12. Pb-Sr-O-C isotope compositions of metacarbonate rocks of the Derbina Formation (East Sayan): Chemostratigraphic and geochronological significance

    Gorokhov, I. M.; Kuznetsov, A. B.; Ovchinnikova, G. V.; Nozhkin, A. D.; Azimov, P. Ya.; Kaurova, O. K.

    2016-01-01

    The Pb-Sr-O-C isotope compositions of calcite marbles of the Derbina Formation, exposed in the northwestern part of the Derbina block of the East Sayan, were studied. Rocks of the Derbina Formation were metamorphosed under high-temperature amphibolite facies conditions. The carbonate constituent of marbles contains (ppm) 15-130 Mn, 130-160 Fe, 0.008-0.039 Rb, 645-2190 Sr, 0.565-0.894 U, and 0.288-1.42 Pb. These concentrations are similar to those in modern carbonate sediments. The values of δ13C in marbles of the Derbina Formation range from-0.6 to +1.4‰ PDB; the values of δ18O range from 21.5 to 28.6‰ SMOW. The 87Sr/86Sr ratio values in the two least altered rocks, which meet geochemical criteria of the Rb-Sr system preservation in high-grade carbonate rocks, are 0.70804 and 0.70829. The protolith ages of marbles determined using Sr and C chemostratigraphy lie within the interval of 560-530 Ma, which is regarded as the period of carbonate sedimentation. The slope of the straight line on the 206Pb/204Pb-207Pb/204Pb diagram ( n = 9, MSWD = 19) constructed on the basis of the data points of bulk carbonate constituents of all samples studied and those representing leachate steps of one of them in 0.5N HBr yields Late Vendian age (556 ± 31 (2σ) Ma. Taking into account the data on Sr and C isotope systematics of Derbina marbles, this age is regarded as the age of early diagenesis of carbonate sediments close to the age of sedimentation. Thus, metacarbonate rocks of the Derbina Formation preserved the pre-metamorphic chemostratigraphic and isotope-geochronological information. The age obtained testifies that formation of the carbonate cover of the Derbina block occurred in the Late Vendian. At the end of the Cambrian, carbonate deposits were metamorphosed during the Early Caledonian tectonic event in the southeastern part of the Central Asian Fold Belt.

  13. Accurate measurement of neodymium isotopic composition using Neptune MC-ICP-MS

    Yueheng YANG; Hongfu ZHANG; Liewen XIE; Fuyuan WU

    2008-01-01

    This paper reports the measurement of the Neodymium isotopic composition by Neptune Multiple Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS) over the last two years. Although there is concomitant Cerium in the chemical separation process, this has no significant influence on the Neodymium analysis. As for the sample containing small amounts of Samarium (Sm/Nd<0.04), direct calibration for isobaric interference and mass discrimina-tion by the exponential law can be obtained by assuming that Samarium mass discrimination is the same as that of Neodymium. Geological samples after traditional chemi-cal separation were measured by Neptune MC-ICP-MS and Thermal Ionization Mass Spectrometry (TIMS) respectively. The results show that Neptune MC-ICP-MS can measure Neodymium isotopic composition as precisely the TIMS does and is even more effective and less time-consuming than the TIMS Method.

  14. Paleo water–rock interaction determined through isotopic tracing (Sr, O, C, U) in fracture-fill minerals: Evidence from the Vienne granitoids (France)

    Highlights: ► Fractures filling were investigated by means of Sr, O, C, U isotopes. ► Recent uranium migration processes were evidenced. ► Two major fluid events responsible for most of the vein fillings can be characterized. - Abstract: Based on the concepts (a) that the stable C and O isotopes combined with the Sr isotope ratios of fracture fills should reflect the source groundwater from which the solid phases precipitated and (b) that U-series disequilibria (USD) enable the calculation of residence time for the U by using Fe oxides as the best candidate, an “isotopic toolbox” was applied to fracture fill from the crystalline basement of the Vienne district. The fracture fills are formed mainly of carbonates, clays and Fe oxides. The isotope data indicate two main generations of carbonate that originated from hydrothermal circulation and equilibrium with present-day groundwaters but the Sr isotope ratios highlight another component with a higher 87Sr/86Sr ratio reflecting the complexity of the water–rock interactions. For the USD, the Fe-hydroxides located at 207 m depth yield an age of 102 ± 5 ka (St. Germain I interglacial stage), whereas those located at 277 m and 300 m yield respective ages of 173 ± 15 ka and 181 ± 10 ka. These corresponding to the transition between the penultimate glacial period (isotopic stage 6) and the end of the preceding interglacial stage (isotopic sub-stage 7a). Investigating water–rock interaction (87Sr/86Sr, 18O, 13C, USD) in the fracture-fill minerals from the crystalline basement has shown that such an approach is relevant to developing an understanding of how the groundwater system has changed over time

  15. Constraints on mantle source and interactions from He-Sr isotope variation in Italian Plio-Quaternary volcanism

    Martelli, M.; Nuccio, P. M.; Stuart, F. M.; di Liberto, V.; Ellam, R. M.

    2008-02-01

    Helium isotope ratios of olivine and pyroxene phenocrysts from Plio-Quaternary volcanic rocks from southern Italy (seven Aeolian Islands, Mt. Vulture, Etna, Ustica, and Pantelleria) range from 2.3 to 7.1 Ra. Importantly, the phenocryst 3He/4He correlate well with whole rock Sr isotopic composition (0.70309-0.70711), reflecting the mixing of two sources. A significant contribution of He from crustal contamination is recorded only occasionally (e.g., pyroxenes from Vulcano). When merged with data from the Roman Comagmatic Province, a remarkably strong near-linear He-Sr isotope correlation is apparent. The general northward decrease in 3He/4He corresponds to an increase in 87Sr/86Sr (and a decrease in 143Nd/144Nd and 206Pb/204Pb) that is due to increasing metasomatic enrichment of the mantle wedge via subduction of the Ionian-Adriatic plate. Calculations based on the ingrowth of 4He in the wedge and on the 4He content of the subducting crust show that mechanisms of enrichment in radiogenic He are effective only if the wedge is strongly depleted in He relative to best estimates of the depleted mantle. This can be accommodated if the process of metasomatism by the subduction fluids depletes the mantle wedge. The 3He/4He of Pantelleria, Etna, Iblei, Ustica, Alicudi, and Filicudi basalts (7.0 ± 0.6 Ra) define the mantle composition least affected by subduction-related metasomatism. Although these volcanoes are from a variety of tectonic regimes (subduction-related, intraplate, rifting), their similarities suggest a common origin of geochemical features. Their characteristics are consistent with a HIMU-type mantle that either is younger than the Cook-Austral island end-member or has a lower 238U/204Pb.

  16. Elemental and Sr-Nd isotopic geochemistry of Permian Emeishan flood basalts in Zhaotong, Yunnan Province, SW China

    Li, Juan; Zhong, Hong; Zhu, Wei-Guang; Bai, Zhong-Jie; Hu, Wen-Jun

    2016-05-01

    This study presents new whole-rock elemental and isotopic data for the basalts from the Zhaotong area, located in the intermediate zone of the ~260 Ma Emeishan large igneous province (ELIP). The Zhaotong basalts belong to high-Ti series with TiO2 from 2.93 to 5.26 % and Ti/Y from 519 to 974. The parental magma was subjected to minor crustal contamination as indicated by slight Nb-Ta depletion (Nb/La: 0.72-1.10). Meanwhile, the relatively invariable Sr-Nd isotopes (ɛNd(t): -0.74 to +2.86, mostly +1.10 to +2.86; (87Sr/86Sr)i: 0.7050-0.7072) and the light rare earth elements (LREE) enrichment (La/Yb: 10.3-19.1) of the basalts prefer a mantle plume origin. A garnet-dominated peridotite mantle source was further suggested on the basis of the REE distribution patterns and high Sm/Yb and high La/Yb ratios. This study further confirms the geochemical zoning of the high-Ti basalts in the ELIP, which is in accordance with both the spatial distribution and the thickness of the basalts. The high-Ti basalts in the intermediate and outer zones of ELIP (e.g., Zhaotong and Guizhou) share similar Sr-Nd isotopic and elemental compositions, suggesting that they originated directly from the Emeishan mantle plume. By contrast, the high-Ti basalts in the inner zone (e.g., Longzhoushan and Binchuan) have variable compositions, indicating a rather heterogeneous mantle source possibly involved with subcontinental lithospheric mantle (SCLM) components.

  17. Integrated Sr isotope variations and global environmental changes through the Late Permian to early Late Triassic

    Song, Haijun; Wignall, Paul B.; Tong, Jinnan; Song, Huyue; Chen, Jing; Chu, Daoliang; Tian, Li; Luo, Mao; Zong, Keqing; Chen, Yanlong; Lai, Xulong; Zhang, Kexin; Wang, Hongmei

    2015-08-01

    New 87Sr/86Sr data based on 127 well-preserved and well-dated conodont samples from South China were measured using a new technique (LA-MC-ICPMS) based on single conodont albid crown analysis. These reveal a spectacular climb in seawater 87Sr/86Sr ratios during the Early Triassic that was the most rapid of the Phanerozoic. The rapid increase began in Bed 25 of the Meishan section (GSSP of the Permian-Triassic boundary, PTB), and coincided closely with the latest Permian extinction. Modeling results indicate that the accelerated rise of 87Sr/86Sr ratios can be ascribed to a rapid increase (>2.8×) of riverine flux of Sr caused by intensified weathering. This phenomenon could in turn be related to an intensification of warming-driven runoff and vegetation die-off. Continued rise of 87Sr/86Sr ratios in the Early Triassic indicates that continental weathering rates were enhanced >1.9 times compared to those of the Late Permian. Continental weathering rates began to decline in the middle-late Spathian, which may have played a role in the decrease of oceanic anoxia and recovery of marine benthos. The 87Sr/86Sr values decline gradually into the Middle Triassic to an equilibrium values around 1.2 times those of the Late Permian level, suggesting that vegetation coverage did not attain pre-extinction levels thereby allowing higher runoff.

  18. Sr isotope chemistry of the magmatism from Momchilgrad depression (Eastern Rhodopes)

    The (87Sr/86Sr)i of Zvezdel basaltic-andesite complex ranges between 0.705087 and 0.708613. Acid complexes have lower values of these ratios: Perperek trachyrhyolite - 0.69534, Ursula rhyolite - 0.70119, Sveti Ilia trachyrhyodacite - 0.70270 and Momchilgrad trachydacite - 0.70589. Considering all acid complexes the (87Sr/86Sr)i of Sveti Ilia trachyrhyodacite and Sveti Ilia trachyrhyodacite complexes are comparable with these of Zvezdel basaltic-andesite complex. The outcrops of their products associate spatially with the intermediate complexes as both acid and intermediate varieties have similar petrochemical features and trace element abundance. These complexes might have been produced by one magma reservoir of intermediate composition. Obtained (87Sr/86Sr)i values are typical of continental tectonic settings. The occurrences of Ustra rhyolite and Perperek trachyrhyolite complexes are located apart from the intermediate volcanics. The have significantly lower Sr contents, lower (87Sr/86Sr)i and specific petrochemical features and trace element distribution patterns and probably resulted from the evolution of separate and not large magma reservoirs of acid composition. Calculated (87Sr/86Sr)i for Perperek and Ustra complexes are typical of the island-arc or even mid-oceanic ridge tectonic settings. These data indirectly confirm the idea of involving both oceanic and continental crust during a process of 'continental subduction'. (authors)

  19. Sources, migration and transformation of antimony contamination in the water environment of Xikuangshan, China: Evidence from geochemical and stable isotope (S, Sr) signatures.

    Wen, Bing; Zhou, Jianwei; Zhou, Aiguo; Liu, Cunfu; Xie, Lina

    2016-11-01

    The Xikuangshan (XKS) mine in central China is the largest antimony (Sb) mine in the world. The mining activity has seriously contaminated the waters in the area. To determine the sources, migration and transformation of Sb contamination, 32 samples from groundwater (aquifer water), surface water and mine water were collected for water chemistry, trace element and SSO4 and Sr stable isotope analyses. The results showed that the groundwater and surface water were in an oxidized environment. The SSO4 and Sr isotope compositions in the water indicated that dissolved Sb and SO4(2) originated from sulfide mineral (Sb2S3) oxidation, whereas radiogenic Sr may have been sourced from silicified limestone and stibnite in the Shetianqiao aquifer. Furthermore, a positive correlation between δ(34)SSO4 and δ(87)Sr values revealed that the Sr, S and Sb in the waters had a common contamination source, i.e., silicified limestone and stibnite, whereas the Sr, S and Sb in rock and ore were sourced from Proterozoic basement clastics. The analysis also indicated that the isotope composition of dissolved SO4(2-) had been influenced by slight bacterial SO4 reduction in the Magunao aquifer. Mining or rock collapse may have caused Shetianqiao aquifer water to contaminate the Magunao aquifer water via mixing. This study has demonstrated that the stable isotopes of (34)SSO4 and (87)Sr, combined with hydrochemical methods, are effective in tracking the sources, migration and transformation of Sb contamination. PMID:27341112

  20. APPLICATION OF O-H-B-Sr ISOTOPE SYSTEMATICS TO THE EXPLORATION OF SALINIZATION AND FLUSHING IN COASTAL AQUIFERS : PRELIMINARY DATA FROM THE PIALASSA BAIONA ECOSYSTEM (ADRIATIC SEA

    Riccardo Petrini

    2009-07-01

    Full Text Available O, H, B and Sr isotopes were identified from surface-waters, ground-waters and waters percolating in soils at the Pialassa Baiona lagoon and nearby inland areas. The preliminary data demonstrate the occurrence of both conservative mixtures between seawater and freshwaters and cation exchange at the salt/fresh water interface during the intrusion. The O and H isotopes indicate that the freshwater component in the binary mixing had the isotopic features of the rainwater from Apennine catchments. Coupled O-H-B isotopes also show that the major contribution of the moving seawater was confined to the deeper aquifers and some of the soil waters. The Sr isotopes highlight the role of cation exchanges when seawater flushes freshwater aquifers, and allow the recognition of the different components of the solute. Deviations from these processes as revealed by B isotopes are interpreted as the evidence of possible anthropogenic inputs.

  1. C- and Sr-isotope stratigraphy of the São Caetano complex, Northeastern Brazil: a contribution to the study of the Meso-Neoproterozoic seawater geochemistry

    Juan C. Silva

    2005-03-01

    Full Text Available C-isotope and 87Sr/86Sr values for five carbonate successions from the São Caetano Complex, northeastern Brazil, were used to constrain their depositional age and to determine large variations in the C- and Sr-isotopic composition of seawater under the framework of global tectonic events. Three C-isotope stages were identified from base to top in a composed chemostratigraphic section: (1 stage in which delta13C values vary from +2 to +3.7‰ PDB and average 3‰ PDB, (2 stage with delta13C values displaying stronger oscillations (from -2‰ to +‰ PDB, and (3 stage with an isotopic plateau with values around +3.7‰ PDB. Constant 87Sr/86Sr values (~ 0.70600 characterize C-isotope stage 1, whereas slightly fluctuating values (from 0.70600 to 0.70700 characterize C-isotope stage 2. Finally, 87Sr/86Sr values averaging 0.70600 characterize C-isotope stage 3. The C- and Sr- chemostratigraphic pathways permit to state: (a the C- and Sr-isotope secular curves registered primary fluctuations of the isotope composition of seawater during late Mesoproterozoic- early Neoproterozoic transition in the Borborema Province, and (b onset of the Cariris Velhos/Greenville cycle, widespread oceanic rifting, continental magmatic arc formation and onset of the agglutination of Rodinia supercontinent, mostly controlled the C- and Sr-isotope composition of seawater during the C-isotope stages 1, 2 and 3.Valores de isótopos de C e 87Sr/86Sr de cinco seqüências de carbonatos do Complexo São Caetano, nordeste do Brasil; foram usados para estimar a sua idade de deposição e relacionar variações da composição isotópica na água do mar com eventos tectônicos globais. Três estágios de variação de isótopos de carbono foram identificados de base para o topo numa seção quimioestratigráfica composta: (1 estágio em que delta13C varia de +2 a +3.7‰PDB (media 3‰PDB, (2 estágio no qual delta13C varia consideravelmente (de -2 a +3‰PDB e (3 est

  2. Rb, Sr and strontium isotopic composition, K/Ar age and large ion lithophile trace element abundances in rocks and glasses from the Wanapitei Lake impact structure

    Shock metamorphosed rocks and shock-produced melt glasses from the Wanapitei Lake impact structure have been examined petrographically and by electron microprobe. Eleven clasts exhibiting varying degrees of shock metamorphism and eight impact-produced glasses have been analyzed for Rb, Sr and Sr isotopic composition. Five clasts and one glass have also been analyzed for large ion lithophile (LIL) trace element abundances including Li, Rb, Sr, and Ba and the REE's. The impact event forming the Wanapitei Lake structure occurred 37 m.y. ago based on K/Ar dating of glass and glassy whole-rock samples. Rb/Sr isotopic dating failed to provide a meaningful whole-rock or internal isochron. The isotopic composition of the glasses can be explained by impact-produced mixing and melting of metasediments. Large ion lithophile trace element abundance patterns confirm the origin of the glasses by total shock melting of metasediments. (author)

  3. Experimental study of the Mg and Sr isotopic evolution of seawater interacting with basalt between 150 and 300 ° C.

    Voigt, Martin; Pearce, Christopher R.; Oelkers, Eric H.

    2016-04-01

    The chemical exchange of material between seawater and the oceanic crust plays a major role in marine geochemical cycles [1]. Isotopic signatures provide an important means of tracing elemental transfer in hydrothermal environments, yet only a limited amount of experimental data on the extent of isotopic fractionation under these conditions is currently available. This study consequently investigated the extent of δ26/24Mg and 87Sr/86Sr isotopic variation during a seawater-basalt interaction experiments at 150, 250 and 290 ° C. A suite of closed system experiments were run for several months at each temperature under saturated water pressure, using either crystalline or glassy basalt as the starting material and a water/rock ratio of 10 or 25. Our results demonstrate that the dissolution of basaltic material in hydrothermal environments occurs at the same time as the precipitation of alteration minerals (mainly smectite and anhydrite), which is consistent with results from similar studies in the past (e.g. [2]). As expected, the rate of reaction using crystalline basalt was slower than with basaltic glass, and both sample types reacted faster at higher temperatures. The 87Sr/86Sr composition of the experimental fluids decreased from the initial seawater value (0.70916) towards the lower basaltic signature during the experiments (0.70317), demonstrating the progressive release of Sr during basalt dissolution. Magnesium was steadily removed from the fluid via the precipitation of clay minerals, with the residual fluids having progressively lighter δ26/24Mg compositions. The mean Mg isotope fractionation factor (αsolid‑solution) observed at 250 oC was 1.0005±0.0002, supporting low-temperature evidence that clay minerals preferentially incorporate isotopically heavy magnesium [3]. These experiments provide quantitative information on the extent of Mg isotopic fractionation between fluids and secondary silicate minerals in hydrothermal systems, and demonstrate

  4. Midcontinent rift volcanism in the Lake Superior region: Sr, Nd, and Pb isotopic evidence for a mantle plume origin

    Nicholson, S.W. (Geological Survey, Reston, VA (USA) Univ. of Minnesota, MN (USA)); Shirey, S.B. (Carnegie Institution of Washington, DC (USA))

    1990-07-10

    Between 1091 and 1098 Ma, most of a 15- to 20-km thickness of dominantly tholeiitic basalt erupted in the Midcontinent Rift System of the Lake Superior region, North American. The Portage Lake Volcanics in Michigan, which are the youngest MRS flood basalts, fall into distinctly high- and low-TiO{sub 2} types having different liquid lines of descent. Incompatible trace elements in both types of tholeiites are enriched compared to depleted or primitive mantle (La/Yb = 4.3-5.3; Th/Ta = 2.12-2.16; Zr/Y = 4.3-4.4), and both basalt types are isotopically indistinguishable. Sr, Nd, and Pb isotopic compositions of the Portage Lake tholeiites have {sup 87}Sr/{sup 86}Sr{sub i} {approx}0.7038, {epsilon}{sub Nd(1095 Ma)} {approx}0 {plus minus} 2, and {mu}{sub 1} {approx}8.2. Model ages with respect to a depleted mantle source (T{sub DM}) average about 1950-2100 Ma. Portage Lake rhyolits fall into two groups. Type I rhyolites have Nd and Pb isotopic characteristics ({epsilon}{sub Nd(1095 Ma)} {approx}0 to {minus}4.7; {mu}{sub 1} {approx}8.2-7.8) consistent with contamination of tholeiitic rocks by 5-10% Archean crust. The one type II rhyolite analyzed has Nd and Pb isotopic compositions ({epsilon}{sub Nd(1095 Ma)} {approx}{minus}13 to {minus}16; {mu}{sub 1} {approx}7.6-7.7) which are consistent with partial melting of Archean crust. Early Proterozoic crust was not a major contaminant of MRS rocks in the Lake Superior region. Most reported Nd and Pb isotopic compositions of MRS tholeiites from the main stage of volcanism in the Lake Superior region and of the Duluth Complex are comparable to the Nd and Pb isotopic data for Portage lake tholeiites. The isotopic enrichment of the MRS source compared to depleted mantle is striking and must have occurred at least 700 m.y. before 1100 Ma.

  5. Accurate mass measurements of short-lived isotopes with the MISTRAL rf spectrometer

    Toader, C F; Borcea, C; Doubre, H; Duma, M; Jacotin, M; Henry, S; Képinski, J F; Lebée, G; Le Scornet, G; Lunney, M D; Monsanglant, C; De Saint-Simon, M; Thibault, C

    1999-01-01

    The MISTRAL experiment has measured its first masses at ISOLDE. Installed in May 1997, this radiofrequency transmission spectrometer is to concentrate on nuclides with particularly short half-lives. MISTRAL received its first stable beam in October and first radioactive beam in November 1997. These first tests, with a plasma ion source, resulted in excellent isobaric separation and reasonable transmission. Further testing and development enabled first data taking in July 1998 on neutron-rich Na isotopes having half-lives as short as 31 ms.

  6. Can serum isotope levels accurately measure intestinal calcium absorption compared to gold-standard methods?

    Vreede, Andrew P; Jones, Andrea N; Hansen, Karen E

    2015-01-01

    Background Low fractional calcium absorption (FCA) contributes to osteoporosis but is not measured clinically, as the gold-standard method requires administration of two calcium tracers and a subsequent 24-h urine collection. We evaluated alternate methods to measure FCA, compared to the gold standard method. Methods We administered two stable calcium isotope tracers (~8 mg oral 44Ca and ~3 mg intravenous 42Ca) with breakfast to 20 fasting post-menopausal women (Cohort 1) 59 ± 7 years old wit...

  7. APPLICATION OF O-H-B-Sr ISOTOPE SYSTEMATICS TO THE EXPLORATION OF SALINIZATION AND FLUSHING IN COASTAL AQUIFERS : PRELIMINARY DATA FROM THE PIALASSA BAIONA ECOSYSTEM (ADRIATIC SEA)

    Riccardo Petrini; Maddalena Pennisi; Alessandra Adorni Braccesi; Barbara Stenni; Onelio Flora; Umberto Aviani

    2009-01-01

    O, H, B and Sr isotopes were identified from surface-waters, ground-waters and waters percolating in soils at the Pialassa Baiona lagoon and nearby inland areas. The preliminary data demonstrate the occurrence of both conservative mixtures between seawater and freshwaters and cation exchange at the salt/fresh water interface during the intrusion. The O and H isotopes indicate that the freshwater component in the binary mixing had the isotopic features of the rainwater from Apennine catchments...

  8. Pb, Sr, Nd, and Hf isotopic constraints on the origin of Hawaiian basalts and evidence for a unique mantle source

    Pb, Sr, Nd, and Hf isotopic relationships among basalts from the Hawaiian Islands suggest that these basalts were derived from three sources; the oceanic lithosphere (Kea end member), the depleted asthenosphere (posterosional end member) and a deep-mantle plume (Koolau end member). Hawaiian tholeiites are derived within the lithosphere and the isotopic trends collectively defined by the tholeiite data are interpreted as a plume-lithosphere mixing trend. The isotopic characteristics of late-stage basalts are derived from the tholeiite source (lithosphere + plume) with additional input from the lithosphere, asthenosphere, or both. These basalts probably originate from near the asthenosphere-lithosphere boundary. Posterosional basalts are derived from the depleted asthenosphere, but their isotopic characteristics have been slightly modified by either the plume or the source of previously erupted volcanics. The isotopic data require little or no mixing of asthenospheric material into the plume during tholeiite production and thus are consistent with the concept of a rapidly ascending, fluid-rich plume. In addition to providing a source of heat, the plume may supply volatiles to both the sources of tholeiites and posterosional basalts. The isotopic characteristics of the Koolau (plume) component are unique among OIB sources. If undifferentiated or 'primitive' mantle material still exists, then the radiogenic-isotope data for Koolau in combination with rare gas data for Hawaiian basalts in general suggest that the Hawaiian plume may be derived from such material. In any case, the Hawaiian Islands data, when compared to those of other OIB, serve to illustrate the isotopically diverse nature of mantle sources. (author)

  9. Geochemical and Sr-Nd isotopic evidence for a rift-related origin of magmas in Tizayuca volcanic field, central Mexican volcanic belt

    New geochemical and Sr and Nd isotope data are presented on six selected rock samples of hy-normative late Quaternary basalt, basaltic trachy desite, basaltic andesite, andesite, and dacite from Tizilyuca Volcanic Field (TVF), located in the State of Hidalgo, Mexico, at the central part of the Mexican Volcanic Belt (MVB). This province (MVB) is a modern volcanic zone (Miocene to Recent), which in spite of ongoing subduction, presents widespread magmas whose origin is shown to be unrelated to subduction. The initial isotopic ratios of the sampled rocks, practically identical to their measured ratios, range as follows: 87Sr/86Sr 0.70390-0.70540 and 143Nd/l44Nd 0.512598-0.512907. There is a general increase in 87Sr/86Sr and a decrease in 143Nd/144Nd with increasing SiO2 and decreasing MgO contents. The combined geochemical and isotopic evidence supports the generation of these magmas from the mantle or even in the lower crust, and subsequent modification through crustal assimilation processes. In spite of on going subduction of the Cocos plate, the TVF seems to own its origin to rift-related processes as is the case of many other areas of the central and eastern MVB. A broader implication of the isotopic data from the MVB is that the basic assumption of geochronology of the same initial isotopic ratios seems to fall apart because none of the so far studied areas of the MVB shows a uniform Sr or Nd isotopic ratio. Indeed, the 87Sr/86Sr and 143Nd/144Nd ratios vary according to the rock-type for rocks of practically zero age. (author)

  10. Isotope geochemistry of recent magmatism in the Aegean arc: Sr, Nd, Hf, and O isotopic ratios in the lavas of Milos and Santorini-geodynamic implications

    Briqueu, L.; Javoy, M.; Lancelot, J.R.; Tatsumoto, M.

    1986-01-01

    In this comparative study of variations in the isotopic compositions (Sr, Nd, O and Hf) of the calc-alkaline magmas of the largest two volcanoes, Milos and Santorini, of the Aegean arc (eastern Mediterranean) we demonstrate the complexity of the processes governing the evolution of the magmas on the scale both of the arc and of each volcano. On Santorini, the crustal contamination processes have been limited, effecting the magma gradually during its differentiation. The most differentiated lavas (rhyodacite and pumice) are also the most contaminated. On Milos, by contrast, these processes are very extensive. They are expressed in the 143Nd/144Nd vs. 87Sr/86Sr diagram as a continuous mixing curve between a mantle and a crustal end member pole defined by schists and metavolcanic rocks outcropping on these volcanoes. In contrast with Santorini, the least differentiated lavas on Milos are the most contaminated. These isotopic singularities can be correlated with the geodynamic evolution of the Aegean subduction zone, consisting of alternating tectonic phases of distension and compression. The genesis of rhyolitic magmas can be linked to the two phases of distension, and the contamination of the calc-alkaline mantle-derived magmas with the intermediate compressive phase. The isotopic characteristics of uncontaminated calc-alkaline primitive magmas of Milos and Santorini are directly comparable to those of magmas generated in subduction zones for which a contribution of subducted sediments to partial melts from the mantle is suggested, such as in the Aleutian, Sunda, and lesser Antilles island arcs. However, in spite of the importance of the sediment pile in the eastern Mediterranen oceanic crust (6-10 km), the contribution of the subducted terrigenous materials remains of limited amplitude. ?? 1986.

  11. Artificial (Pu {sup 90}Sr, {sup 241}Am) and natural (U) isotopes in human bones from Poland

    Mietelski, J.W.; Tomankiewicz, E. [Institute of Nuclear Phyics (Poland); Golec, E.; Golec, J.; Nowak, S.; Szczygiel, E. [The 5th Military Clinical Hospital and Polyclinic (Poland); Kuzma, K. [General Hospital (Poland)

    2014-07-01

    In two papers we have presented results if analyses of artificial isotopes ({sup 238,239,240}Pu, {sup 241}Am and {sup 90}Sr) content in human bones, using samples collected during hip joint replacement surgery. Since the patients were members of general population (not exposed in any particular form to artificial radionuclides) results can be treated as current background level for Poland and perhaps also whole central Europe. During this project the open question appeared - what is the level in human bones of natural alpha emitters like {sup 238}U-, {sup 234}U, for instance. Therefore about 30 human hip joint bone samples are being now analysed for the presence of uranium along with mentioned above artificial radionuclides. Samples are ashen and sequential radiochemical analyse is applied for separation of Pu, Sr and Am isotopes followed by separation of uranium using anion exchange resin. Measurements of plutonium, americium and uranium are performed using alpha spectrometry. That for {sup 90}Sr is done by LSC. Results will be presented during conference. Document available in abstract form only. (authors)

  12. Uranium-Lead Zircon Ages and Sr, Nd, and Pb Isotope Geochemistry of Selected Plutonic Rocks from Western Idaho

    Unruh, Daniel M.; Lund, Karen; Kuntz, Mel A.; Snee, Lawrence W.

    2008-01-01

    Across the Salmon River suture in western Idaho, where allochthonous Permian to Cretaceous oceanic rocks are juxtaposed against Proterozoic North American rocks, a wide variety of plutonic rocks are exposed. Available data indicate much variation in composition, source, and structural state of these plutons. The plutonic rocks were long described as the western border zone of the Cretaceous Idaho batholith but limited pre-existing age data indicate more complicated origins. Because the affinity and age of the plutonic rocks cannot be reliably determined from field relations, TIMS U-Pb dating in conjunction with Sr, Nd, and Pb isotopic studies of selected plutons across the suture in western Idaho were undertaken. The data indicate three general groups of plutons including (1) those that intruded the island arc terranes during the Triassic and Jurassic, those that intruded near the western edge of oceanic rocks along the suture in the Early Cretaceous, and the plutons of the Idaho batholith that intruded Proterozoic North American rocks in the Late Cretaceous. Plutons that intruded Proterozoic North American rocks commonly include xenocrystic zircons and in several cases, ages could not be determined. The least radiogenic Sr and most radiogenic Nd are found among the Blue Mountains superterrane island arc samples. Suture-zone plutons have isotopic characteristics that span the range between Idaho batholith and island arc samples but mostly follow island arc signatures. Plutons of the Idaho batholith have the most radiogenic initial Pb and Sr ratios and the least radiogenic Nd of the samples analyzed.

  13. Magma Mixing for the Origin of the Granites. Geochemistry, Sr-Nd Isotopic, Zircon U-Pb Dating and Hf Isotopic Evidences from the Triassic Mishuling Monzonitic Granite and Its Enclaves, Qinling Orogen (Central China)

    QIN Jiang-feng; LAI Shao-cong; DIWU Chun-rong; JU Yin-juan; LI Yong-fei

    2008-01-01

    @@ Major and trace element, whole rock Sr-Nd isotope, mineral chemistry, zircon U-Pb and Hf isotope compositions are reported for a suite of I-type monzogranite and its marie microgranular enclaves from the Triassic (210±2 Ma) Mishuling pluton, Qinling orogen, central China, with the aim of investigating the sources and petrogenesis of I-type granites.

  14. Sr-Nd-Pb Isotope Geochemistry of Lesser Qinling%小秦岭碳酸岩的Sr-Nd-Pb同位素地球化学

    王林均; 许成; 吴敏; 宋文磊; 唐红峰

    2012-01-01

    The Lesser Qinling carbonatite is located at the southern margin of North China craton.The Sr,Nd isotopic characteristics are close to the EM1 mantle member [(87Sr/86Sr)i =0.70495~0.70552;εNd =-10.1~4.6],but with low Sr and Nd compared to EM1.The Pb isotopic characteristics of the carbonate rocks are in the range of southern Qinling Mountains,completely different from the North China plate.This implies that the lower crust or mantle of the southern margin of the North China Craton has been mixed with the lower crust of South Qinling.So the carbonatites formed at the stage of extension after collision in the Qinling orogeric belt.This paper also argues that the Triassic granitoids formed under an extension background and were involved in mantle materials from Qinling Orogenic belt.%小秦岭碳酸岩位于华北板块南缘,其(87Sr/86Sr)i与εNd值分别介于0.70495~0.70552和-10.1~4.6之间,紧靠EM1地幔端元,但相对EM1具有低Sr和低Nd特征。Pb同位素与华北板块南缘完全不同,而是落在了南秦岭下地壳范围之内,这表明华北板块南缘下地壳或地幔已经受到南秦岭地壳物质俯冲置换的影响,即在晚三叠纪时期,秦岭地区的碰撞造山作用可能已经结束,转入伸展拉张的构造环境。并进一步论述了秦岭地区三叠纪花岗岩是在深部拉张的构造环境下形成以及具有幔源物质参与的特征。

  15. Considerations on the age of the Bambui Group (MG, Brazil) based on isotopic analyses of Sr and Pb

    Based on radiometric ages, the Bambui Group deposition time is related to the end of the Precambrian. However, the ages determined and released through scientific magazines are mot in agreement (600-1350 m.y.) and many doubts about the geochrological picture of this important lithostratigraphic unit remained for a long time. As a result of the work developed by Metamig, CPGeo (IG-USP) and IPEN (SP), Rb/Sr and Pb/Pb isotopic determinations were done on 31 rocks samples and 17 galenas collected from the Bambui Basin distributed in Minas Gerais State. The Rb/Sr ages of 590 m.y. for Pirapora Formation, 620 m.y. for Tres Marias Formation, and 640 m.y. for the Paraopeba Formation situated in the stable area are linked to sedimentation processes. In the Paracatu region the age of 680 m.y. found for the Paraopeba Formation is related to metamorphic events. The lead isotopic ratios from the galenas suggest an isotopic evolution in two stages. The first ended with the lead separation from the mantle and its incorporation to the crust during events of the Transamazonic Cycle. The second ended when the lead were incorporated to the galenas and seems to be related to one or more events of the Brazilian Cycle. (Author)

  16. Carbonate verse silicate Sr isotope in lake sediments and its response to Little Ice Age

    2003-01-01

    The 87Sr/86Sr ratios of silicate (acid-insoluble, AI) and carbonate (acid-soluble, AS) of the lake sediments from the Daihai Lake, Inner Mongolia, since the last 500 years are measured respectively, indicating that chemical weathering of silicate minerals was in an early stage since the Little Ice Age within the Daihai watershed by combination with mineral constitute, Rb/Sr ratio and CaCO3 content in the sediments. During the Little Ice Age maximum, an evident peak in the 87Sr/86Sr ratios of both silicate and carbonate in sediments suggests that a cold climate condition is unfavorable to dissolving radiogenic strontium from silicate minerals. Meanwhile, the variation of 87Sr/86Sr ratios of silicate and carbonate also reflects a projected warming climate favorable to intensifying chemical weathering after the Little Ice Age. Consequently, the 87Sr/86Sr ratio of both silicate and carbonate in inland lake sediments can be used as an effective proxy of the past climate in single watershed.

  17. Sr and Nd isotopic evidence for petrogenesis of mid-Tertiary felsic volcanism in the mineral district of Zacatecas, Zac. (Sierra Madre Occidental), Mexico

    Twelve samples of mid-Tertiary felsic volcanic rocks from Zacatecas and San Luis Potosi (both belonging to the Sierra Madre Occidental) and one sample of Lower Tertiary porphyritic andesite from Zacatecas are analyzed for 87Sr/86Sr, K, Rb, and Sr. Eight selected samples are also analyzed for 143Nd/144Nd. A linear regression of the present-day 87Sr/86Sr and 87Rb/86Sr of the felsic volcanic rocks in Zacatecas gives an approximate date of 30 +- 8 Ma. The initial 87Sr/86Sr ratios are high and widely distributed (from 0.705 to 0.712 or higher) whereas the initial 143Nd/144Nd ratios are somewhat low and show a narrow range (0.5125-0.5127). The available isotopic and trace-element data are best explained in terms of a binary mixing model in which the magmas derived from a slightly depleted-mantle fractionate and mix with varying proportions of the overlying middle/upper continental crust and undergo further shallow-level fractional crystallization before eruption. This model is also compatible with the trace-element and Sr isotopic data published from other areas of the Sierra Madre Occidental for which a purely mantle origin has been proposed. (orig.)

  18. Pb and Sr isotope and geochemical data from the Pb-Zn deposit Bleiberg (Austria): constraints on the age of mineralization

    The timing of Zn-Pb mineralization hosted by early dolomitized lagoonal limestones (Crest facies) at Bleiberg (Carinthia, Austria) has been constrained using Sr-isotopes. This late stage Zn-Pb mineralization is a special feature of the Bleiberg deposit. Samples of the mineralized Crest facies are characterized by higher concentrations of minor and trace elements (except Ba and Sr) compared to samples from the weakly mineralized Wetterstein limestone of the lagoonal facies. The samples from the Crest facies indicate that a fluid with a minimum 87Sr/86Sr ratio of 0.7083 reacted at 210 ± 30 Ma with carbonate rocks having 87Sr/86Sr ratios of approximately 0.7077 during a late stage of ore formation. The 87Sr/86Sr ratios correlate with the Mn and Cl concentrations. Lead isotope data of whole rock samples of Bleiberg yielded an isochron age of 180 ± 40 Ma. They furthermore confirm the presence of two types of common lead; an isotopically distinct ore lead component is present within and close to the ore bodies. The other common Pb component is present in host rocks and in gangue minerals and is distinguished from the ore lead by lower 207Pb/204Pb and 208Pb/204Pb ratios. The Sr and the Pb ages are consistent with geological evidence indicating a Triassic age of Pb-Zn mineralization and support genetic models emphasizing the role of bacteriogenic sulfate reduction at low temperatures prior to subsidence and burial. Elevated 87Sr/86Sr values (>0.7080) of gangue minerals indicate an epigenetic origin of strontium. Our results are consistent with a genetic model postulating formation of the ore-bearing hydrothermal fluids 'at depth' where they leached lead from pre-upper carboniferous basement rocks. (author)

  19. A summary of Rb-Sr isotope studies in the Archean Hopedale Block and the adjacent proterozoic Makkovik subprovince, Labrador

    Rb-Sr isotope study of thirteen whole-rock suites of Archean and Proterozoic rocks from Hopedale block and Makkovik Subprovince shows that the crustal history began about 3115 Ma ago. We tentatively recognize younger crustal segments that formed 2920 Ma ago, from which Kanairktok intrusives were derived at 2832 +- 178 Ma. In Makkovik Subprovince the Island Harbour granites range in age from 1843 +- 90 to 1794 +- 71 Ma. These ages overlap with the 1847 +-87 Ma age for Kanairktok shear zone mylonites. The Island Harbour granodiorites from inland localities to the southwest are contaminated with Archean rocks in Makkovik Subprovince and their initial 87Sr/86 ratios imply a crustal contribution to their source. In contrast, the Island Harbour granites of Striped Island were derived from a mantle source. The sills of Striped Island are 1635 +- 47 Ma old. An undeformed northeast trending Kikkertavak dolerite dyke from Hopedale block is 1206 +- 120 Ma

  20. B, Sr, O and H Isotopic Compositions of Formation Waters from the Bachu Bulge in the Tarim Basin

    CAI Chunfang; PENG Licai; MEI Bowen; XIAO Yingkai

    2006-01-01

    In order to elucidate the origin and migration of basinal brines in the Bachu Bulge, Tarim Basin, we have carried out analyses on chemical composition, and boron, hydrogen and oxygen isotopes of formation waters together with the XRD of clay minerals from the Paleozoic strata. The waters show Ca, B, Li and Sr enrichment and SO4 depletion in the Carboniferous and Ordovician and K enrichment in part of the Ordovician relative to seawater. The relationship between δD and δ18O shows that all the data of the waters decline towards the Global Meteoric Water Line with the intersection of them close to the present-day local meteoric water, suggesting that modern meteoric water has mixed with evaporated seawater. The 87Sr/86Sr ratios range from 0.7090 to 0.7011, significantly higher than those of the contemporary seawater. The δ11B values range from +19.7 to +32.3‰, showing a decrease with the depth and B concentrations. The results suggest that isotopically distinct B and Sr were derived from external sources. However, since the percentages of illite are shown to increase with depth among clay minerals in the study area, i.e., illite is due to precipitation rather than leaching during deeper burial, it is unlikely for illite to have contributed a significant amount of B to the waters. Thus, B with low δ11B values is interpreted to have been added mainly from thermal degradation of kerogen or the basalts in the Cambrian and Lower Ordovician.

  1. Definition of the optimal terms isotope 82Sr obtaining on cyclotrons U-240

    Analysis of the various nuclear reactions for the production of radionuclide 82Sr was performed and optimum process for the production of this radionuclide was determined. Proton beam energy range for minimizing 85Sr impurity was also determined. The thickness of the RbCl target was calculated

  2. Hydrocarbon filling history and reservoir continuity of oil fields evaluated using {sup 87}Sr/{sup 86}Sr isotope ratio variations in formation water, with examples from the North Sea

    Mearns, E.W.; McBride, J.J. [Isotopic Analytical Services Ltd., Aberdeen (United Kingdom)

    1999-02-01

    This paper describes how {sup 87}Sr/{sup 86}Sr ratios in formation waters are used to evaluate compartmentalisation of hydrocarbon reservoirs. Strontium Isotope Residual Salt Analysis (SrRSA) of core samples provides a means of measuring {sup 87}Sr/{sup 86}Sr ratios in formation water from hydrocarbon columns and aquifers. Smooth SrRSA profiles suggest progressive, uninterrupted, filling and the absence of sealed barriers, while a step change in a profile normally suggests a barrier sealed up-dip from the well penetration. Inferences about lateral connectivity are made by comparing SrRSA profiles from neighbouring wells at TVD. Profiles that are superimposed when plotted at TVD suggest the well sections share a common filling history and lie in the same flow unit. Neighbouring SrRSA profiles that are not superimposed normally suggest segmented compartmentalisation of the reservoir. Post-fill structural tilting of reservoirs and hydrodynamism synchronous with filling are processes which complicate data interpretation. Drilling mud contamination of core water is the most serious technical limitation of the SrRSA technique. (Author)

  3. Monitoring the interaction of hydraulic fracturing fluid with Marcellus Shale using Sr isotopes: a comparison of laboratory experiments with field scale observations (Invited)

    Wall, A. J.; Hakala, A.; Marcon, V.; Joseph, C.

    2013-12-01

    Strontium isotopes have the potential to be an effective tool for differentiating Marcellus Shale derived-fluids from other sources in surface and ground waters (Chapman et al. 2012, doi: 10.1021/es204005g). Water that is co-produced during gas extraction is likely influenced by fluid/rock interactions during hydraulic fracturing (HF) and monitoring changes in Sr isotope ratios can provide insight into reactions occurring within the shale formation. However, questions persist as to what controls the Sr isotopic composition of Marcellus Shale fluids, especially during HF. Here we compare laboratory experiments, simulating the dissolution of the Marcellus Shale during HF, with a time-series of water samples taken from a Marcellus Shale gas wells after HF has occurred. For the laboratory experiments, a core sample of Marcellus Shale from Greene County, PA was crushed and placed into a high P and T reaction vessel. Solutions were added in two different experiments: one with synthetic brine, and another using brine+HF fluid. The HF fluid was made up of components listed on fracfocus.org. Experiments were run for ~16 days at 27.5 MPa and 130oC. Aqueous samples were periodically removed for analysis and Sr isotope ratios were measured by MC-ICP-MS. Using just brine, the pH of the solution decreased from 7.6 to 5.3 after 24 hrs, then reached a steady state at ~6.1. Sr/Ca molar ratios in the fluid started at 2.3 after 24 hours and decreased to 1.8 over ~16 days. During this time only 6% of the total inorganic carbon (TIC) dissolved from the shale. The ɛSr values started at +43.2 and decreased to +42.4. In the experiment using brine+HF fluid, the pH started at 1.8 and rose slowly to a steady value of 5.6 by day 6. The Sr and Ca concentrations were higher than the brine experiment, but the Sr/Ca ratios remained lower at ~0.3 through the experiment. The increased Ca release, as well as the dissolution of over 60% of the TIC, suggests the dissolution of a carbonate mineral

  4. Sr-Nd-Hf-Pb isotopic constraints on the origin of silicic lavas in the northern Cascade Arc

    Martindale, M.; Mullen, E.; Weis, D.

    2015-12-01

    The Cascade Arc is the type-locality for a 'hot' subduction zone, where the downgoing slab is young and subduction is relatively slow; a unique setting for studying the controls on silicic (>56 wt% SiO2) magma genesis [1,2]. We present high precision Sr-Nd-Hf-Pb isotopic and trace element data for silicic lavas and country rocks from the major centres of the Garibaldi Volcanic Belt (GVB) in British Columbia, which are hosted by the Mesozoic Coast Plutonic Complex and accreted Coast Belt terranes. In isotopic plots, the silicic GVB lavas define mixing curves between northern Cascadia Basin sediment [3] and Juan de Fuca MORB. The silicic GVB lavas have lower ɛNd, and higher ɛHf, 87Sr/86Sr, 208Pb/204Pb and 207Pb/204Pb for a given 206Pb/204Pb than co-existing alkalic mafic lavas [2,4] which define a separate isotopic cluster. The alkalic mafic lavas have OIB-like trace element compositions [2,4], but the silicic lavas are calc-alkaline with a typical 'arc' trace element signature. Geochemical systematics suggest that a mafic, isotopically 'depleted' contaminant may be affecting the composition of GVB silicic lavas. However, modelling indicates that slab melts do not constitute a major component of the lavas despite high slab temperatures. Geochemical models also rule out the accreted Coast Belt terranes as an assimilant. However, AFC modelling using 147 Ma Cloudburst quartz diorite [5] as the assimilant can explain both the trace element and isotopic compositional range displayed by GVB silicic magmas, consistent with the Coast Plutonic Complex as a major component of the deep crust in this region. Crustal assimilation would have partially overprinted any alkalic mantle-derived signature of parental magmas, while imparting a calc-alkaline arc signature to resulting silicic magmas. [1] Green & Harry (1999) EPSL, 171; [2] Mullen & Weis (2013) G3, 14; [3] Carpentier et al. (2014) Chem Geol, 382; [4] Mullen & Weis (2015) EPSL, 414; [5] Friedman & Armstrong (1995) GSA

  5. Sr evolution in the Upper Permian and Lower Triassic carbonates, northeast Sichuan basin, China: Constraints from chemistry, isotope and fluid inclusions

    Petrographic features, C, O and Sr isotopes, rare earth and trace elements were determined, and fluid inclusions were analyzed on various stages of interparticle cements and vug-fillings from the Upper Permian and Lower Triassic sour reservoirs in northeastern Sichuan basin. The aim was to assess the origin and evolution of palaeo-waters in the carbonates. The original water was contemporary seawater, from which marine cements precipitated with slightly high Sr contents (mean 1911 ppm), 87Sr/86Sr ratios from 0.7067 to 0.7082 and nonluminescent CL. The palaeo-seawater was diluted by meteoric water, as indicated by bright cathodoluminescence (CL) and Sr-depletion (0–516 ppm) in low-temperature calcite. When buried to temperatures of about 60–90 °C during Middle to Late Triassic, the palaeo-water was enriched in Sr released from the transformation of precursor aragonite and calcite to dolomite, resulting in precipitation of substantial pre-bitumen Sr-rich minerals (SrSO4 and SrCO3). For un-dolomitized limestone sections, aragonite neomorphism may have contributed Sr to the precipitation of small amounts of Sr-bearing minerals and calcite crystals with elevated homogenization temperatures (HTs, mainly from 90 to 130 °C) and wide Sr contents (from 34 to 3825 ppm), as recorded in stage III calcite. Since the Middle Jurassic, almost all of the early stage celestite and significant amounts of solid CaSO4 have been consumed by reactions with hydrocarbons (i.e., TSR), resulting in water enriched in isotopically light CO2 and HCO3-,Sr2+,Ba2+ and Eu2+, as recorded in calcite with low δ13C values (down to −18.9‰), 87Sr/86Sr ratios from 0.7072 to 0.7076, high HTs (mainly 110–198 °C), positive Eu anomalies and high Sr and Ba contents. Subsequently, the water was uplifted and cooled down to about 115 °C, celestite and strontianite were precipitated with the occurrence of natural elemental S immiscible inclusions. TSR may have produced significant amounts of

  6. Accurate measurements of 129I concentration by isotope dilution using MC-ICPMS for half-life determination

    Determining the 129I concentration, a long-lived radionuclide present in spent nuclear fuel, is a major issue for nuclear waste disposal purpose. 129I also has to be measured in numerous environmental, nuclear and biological samples. To be able to accurately determine the 129I concentration, an analytical method based on the use of a multicollector-inductively coupled plasma mass spectrometer (MC-ICPMS) combined with an isotope dilution technique using an 127I spike, was developed. First, the influence of different media (HNO3, NaOH and TMAH) on natural 127I signal intensity and stability and on memory effects was studied. Then an analytical procedure was developed by taking into account the correction of blanks and interferences. Tellurium was chosen for instrumental mass bias correction, as no certified standards with suitable 127I/129I ratio are available. Finally, the results, reproducibility and uncertainties obtained for the 129I concentration determined by isotope dilution with a 127I spike are presented and discussed. The final expanded relative uncertainty obtained for the iodine-129 concentration was lower than 0.7% (k = 1). This precise 129I determination in association with further activity measurements of this nuclide on the same sample will render it possible to determine a new value of the 129I half-life with a reduced uncertainty (0.76%, k = 1).

  7. Accurate measurements of {sup 129}I concentration by isotope dilution using MC-ICPMS for half-life determination

    Isnard, Helene; Nonell, Anthony; Marie, Mylene [Commissariat a l' Energie Atomique et aux Energies alternatives (CEA), Gif Sur Yvette (France). DEN, DPC, SEARS, LANIE; Chartier, Frederic [Commissariat a l' Energie Atomique et aux Energies alternatives (CEA), Gif Sur Yvette (France). DEN, DPC

    2016-05-01

    Determining the {sup 129}I concentration, a long-lived radionuclide present in spent nuclear fuel, is a major issue for nuclear waste disposal purpose. {sup 129}I also has to be measured in numerous environmental, nuclear and biological samples. To be able to accurately determine the {sup 129}I concentration, an analytical method based on the use of a multicollector-inductively coupled plasma mass spectrometer (MC-ICPMS) combined with an isotope dilution technique using an {sup 127}I spike, was developed. First, the influence of different media (HNO{sub 3}, NaOH and TMAH) on natural {sup 127}I signal intensity and stability and on memory effects was studied. Then an analytical procedure was developed by taking into account the correction of blanks and interferences. Tellurium was chosen for instrumental mass bias correction, as no certified standards with suitable {sup 127}I/{sup 129}I ratio are available. Finally, the results, reproducibility and uncertainties obtained for the {sup 129}I concentration determined by isotope dilution with a {sup 127}I spike are presented and discussed. The final expanded relative uncertainty obtained for the iodine-129 concentration was lower than 0.7% (k = 1). This precise {sup 129}I determination in association with further activity measurements of this nuclide on the same sample will render it possible to determine a new value of the {sup 129}I half-life with a reduced uncertainty (0.76%, k = 1).

  8. Rb-Sr isotope chronology of the mesozoic volcanics northwestern Zhejiang province (China)

    The volcanic complex of Northwestern Zhejiang were previously classified as Jiande Group (upper Jurassic) which was subdivided into Laocun, Huangjian, Shouchang and Henshan formation. The age from the acid volcanic samples of these formation i.e. 132 Ma, 107 Ma and 93 Ma respectively has got by the authors. The results reflect that Laocun and Huangjiang formatiions belong to lower Cretaceous, but Shouchang formation should be classified as upper Cretaceous. The initial 87Sr/86Sr value, in the range of 0.70561-0.71434, showed the volcanic rocks are the anatexisic product of middle-lower sialic crust, and mixed with a little some of the mantle materials since there is individual lower value of 87Sr/86Sr

  9. The origin of the Merensky cyclic unit: Sr-isotopic and mineralogical evidence for an alternative orthomagmatic model

    Mineralogical, Sr-isotopic and field data on the Critical and Main Zones of the Bushveld Complex indicate that the major input of magma at the Merensky level was fundamentally different to the resident magma. The data indicate that the new magma was more evolved and probably compositionally and thermally denser than the resident magma. This implies that the influxes were of a 'fountain' type, and involved the input of cool dense 'gabbroic' magma with a high Sr-isotopic initial ratio into the chamber containing warm buoyant 'noritic' magma with a lower initial ratio. The first fountain of magma entrained and mixed with the resident magma in the chamber, and the blended liquid then flowed along the interface between the resident and the crystalline floor. This cooler magma fountain resulted in the evolution of the two phase blobs as well as immiscible sulphide from the overlaying warmer liquid. These plunged through the new liquid layer to form the Merensky Reef. 37 refs., 5 figs., 1 tab

  10. Ion microprobe Sr isotope analysis of carbonates with about 5 μm spatial resolution: An example from an ayu otolith

    A high lateral resolution secondary ion mass spectrometer (NanoSIMS NS50 ion microprobe) has been used to measure 87Sr/86Sr ratios in natural CaCO3 samples. A ∼2 nA O- primary beam was used to sputter a 5-7-μm diameter crater on the sample surface and secondary positive ions were extracted for mass analysis using an accelerating voltage of 8 kV and a Mattauch-Herzog geometry. The multi-collector system was adjusted to detect 43Ca+ (by a detector EM2), 80Ca2+ (EM3), 86Sr+ (EM4), and 87Sr+ (EM4b) ions at the same time. Then the magnetic field was scanned for the EM4 to detect 85Rb+, 86Sr+ and 87Sr+, while the EM4b can measure 86Sr+, 87Sr+ and 88Sr+, respectively. A mass resolution of 3600 at 10% peak height was attained with a flat peak top, while the sensitivity of Sr was about 10 cps/nA/ppm. An aragonite sample (coral skeleton standard; JCp-1) was used as a reference for Sr isotope ratio calibration. Repeated analyses of the JCp-1 show that the 87Sr/86Sr ratio agrees well with the seawater signature within a precision of 0.3 per mille at 2σ, after the series of corrections such as the Ca dimer, 87Rb, and a mass bias estimated by the 88Sr/86Sr ratio. The method was applied to an otolith (ear-stone) from ayu (Plecoglossus altivelis altivelis) collected from the Yodo river, Japan. Although experimental errors are relatively large, up to 3 per mille at 2σ, the ratios of the core region are higher than the seawater signature while more distal values agree well with seawater. The very outermost part again shows the relatively higher 87Sr/86Sr ratios. The spatial variation of 87Sr/86Sr ratios was consistent with amphidromous migration of the fish, namely, born in the lake and grown in the coastal sea and finally collected in a river

  11. Re-Os, Rb-Sr, and O isotopic systematics of the Archean Kolar schist belt, Karnataka, India

    Walker, R.J.; Shirey, S.B.; Hanson, G.N.; Rajamani, V.; Horan, M.F.

    1989-01-01

    The Re-Os, Rb-Sr, and O isotopic compositions of mafic and ultramafic amphibolites, gold ores, and granitic gneisses of the circa 2700 Ma Kolar schist belt reveal at least two episodes of post-magmatic alteration that affected these systems. The Re-Os isotopic systematics of many of the rocks of the belt indicate that Os was introduced to the area via fluids that carried very radiogenic Os ( 187Os 186Os2.4Ga > 39). The source of the radiogenic Os was likely ancient crust. On an outcrop scale, this alteration is also characterized by relatively minor additions of excess 87Sr and ??18O values higher than magmatic. The Rb-Sr systematics of most of these rocks are consistent with closed-system behavior since a period between 2700 and 2400 Ma ago, indicating that the alteration event likely occurred no later than the early Proterozoic. In contrast to this late Archean or early Proterozoic alteration, samples of several komatiitic amphibolites have very 187Os-depleted compositions, indicating that open-system behavior also occurred at a much later time. This alteration may have been caused by surficial weathering or the interaction of the rocks with fluids bearing unradiogenic Os. Results suggest that the Re-Os system may have only limited utility for geochronologic applications in regions for which post-crystallization noble metal mineralization is evident (e.g., gold ores). In such regions, however, the system may have an important application in assessing the timing and the ultimate sources of noble metal additions. ?? 1989.

  12. Ca, Sr, Mo and U isotopes evidence ocean acidification and deoxygenation during the Late Permian mass extinction

    Silva-Tamayo, Juan Carlos; Payne, Jon; Wignall, Paul; Newton, Rob; Eisenhauer, Anton; Weyer, Stenfan; Neubert, Nadja; Lau, Kim; Maher, Kate; Paytan, Adina; Lehrmann, Dan; Altiner, Demir; Yu, Meiyi

    2014-05-01

    The most catastrophic extinction event in the history of animal life occurred at the end of the Permian Period, ca. 252 Mya. Ocean acidification and global oceanic euxinia have each been proposed as causes of this biotic crisis, but the magnitude and timing of change in global ocean chemistry remains poorly constrained. Here we use multiple isotope systems - Ca, Sr, Mo and U - measured from well dated Upper Permian- Lower Triassic sedimentary sections to better constrain the magnitude and timing of change in ocean chemistry and the effects of ocean acidification and de-oxygenation through this interval. All the investigated carbonate successions (Turkey, Italy and China) exhibit decreasing δ44/40Ca compositions, from ~-1.4‰ to -2.0‰ in the interval preceding the main extinction. These values remain low during most of the Griesbachian, to finally return to -1.4‰ in the middle Dienerian. The limestone succession from southern Turkey also displays a major decrease in the δ88/86Sr values from 0.45‰ to 0.3‰ before the extinction. These values remain low during the Griesbachian and finally increase to 0.55‰ by the middle Dienerian. The paired negative anomalies on the carbonate δ44/40Ca and δ88/86Sr suggest a decrease in the carbonate precipitation and thus an episode of ocean acidification coincident with the major biotic crisis. The Mo and U isotope records also exhibit significant rapid negative anomalies at the onset of the main extinction interval, suggesting rapid expansion of anoxic and euxinic marine bottom waters during the extinction interval. The rapidity of the isotope excursions in Mo and U suggests substantially reduced residence times of these elements in seawater relative to the modern, consistent with expectations for a time of widespread anoxia. The large C-isotope variability within Lower Triassic rocks, which is similar to that of the Lower-Middle Cambrian, may reflect biologically controlled perturbations of the oceanic carbon cycle

  13. A model that helps explain Sr-isotope disequilibrium between feldspar phenocrysts and melt in large-volume silicic magma systems

    Duffield, Wendell A.; Ruiz, Joaquin

    1998-12-01

    Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.

  14. Multiple sources for the origin of granites: Geochemical and Nd/Sr isotopic evidence from the Gudaoling granite and its mafic enclaves, northeast China

    Yang, Jin-Hui; Wu, Fu-Yuan; Chung, Sun-Lin; Wilde, Simon A.; Chu, Mei-Fei

    2004-11-01

    Geochemical and Sr- and Nd-isotopic data have been determined for mafic to intermediate microgranular enclaves and host granitoids from the Early Cretaceous Gudaoling batholith in the Liaodong Peninsula, NE China. The rocks include monzogranite, porphyric granodiorite and quartz diorite. Monzogranites have relatively high 87Rb/ 86Sr ratios (0.672-0.853), low initial 87Sr/ 86Sr ratios (0.7052-0.7086) and ɛ Nd(t) values (-18.5 to -20.9) indicating that they were mainly derived from a newly underplated crustal source with a short crustal residence time. Quartz diorites have high initial 87Sr/ 86Sr ratios (0.7118-0.7120) and negative ɛ Nd(t) values (-13.2 to -18.1) coupled with high Al 2O 3 and MgO contents, indicating they were derived from enriched lithospheric mantle with contributions of radiogenic Sr from plagioclase-rich metagreywackes or meta-igneous rocks, i.e., ancient lower crust. Two groups of enclaves with igneous textures and abundant acicular apatites are distinguished: dioritic enclaves and biotite monzonitic enclaves. Dioritic enclaves have low Al 2O 3 (13.5-16.4 wt%) and high MgO (Mg# = ˜72.3) concentrations, low initial 87Sr/ 86Sr ratios (0.7058-0.7073) and negative ɛ Nd(t) values (˜-7.2), and are enriched in LILEs and LREEs and depleted in HFSEs, suggesting they were derived from an enriched lithospheric mantle source. Biotite monzonitic enclaves have Sr and Nd isotopic compositions similar to the monzogranites, indicating they were crystal cumulates of the parental magmas of these monzogranites. Granodiorites have transitional geochemistry and Nd- and Sr-isotopic compositions, intermediate between the monzogranites, quartz diorites and the enclaves. Geochemical and Sr- and Nd-isotopic compositions rule-out simple crystal-liquid fractionation or restite unmixing as the major genetic link between enclaves and host rocks. Instead, magma mixing of mafic mantle-derived and juvenile crustal-derived magmas, coupled with crystal fractionation and

  15. Sr, Nd, and Pb isotopes in Proterozoic intrusives astride the Grenville Front in Labrador - Implications for crustal contamination and basement mapping

    Ashwal, L. D.; Wooden, J. L.; Emslie, R. F.

    1986-01-01

    Trace element and Pb, Sr, and Nd isotopic compositions of anorthosites and related rocks, and of younger mafic dikes from Harp Lake and Mealy Mountains in Labrador, Canada are estimated and compared. The effects of crustal component contaminants on the isotopic compositions of the dikes are investigated. The correlation between the isotopic data and the crustal contamination model is studied. It is observed that for Harp Lake the initial Sr ratios are higher and the Nd values are lower than Mealy samples, and the data do not correspond to the crustal contamination model; however, the Pb isotope data favor a crustal contamination model. It is noted that the Labrador segment of the Grenville Front appears to coincide with the southern margin of the Archean North Atlantic craton, and may represent a pre mid-Proterozoic suture.

  16. Channelling of hydrothermal fluids during the accretion and evolution of the upper oceanic crust: Sr isotope evidence from ODP Hole 1256D

    Harris, Michelle; Coggon, Rosalind M.; Smith-Duque, Christopher E.; Cooper, Matthew J.; Milton, James A.; Teagle, Damon A. H.

    2015-04-01

    ODP Hole 1256D in the eastern equatorial Pacific is the first penetration of a complete section of fast spread ocean crust down to the dike-gabbro transition, and only the second borehole to sample in situ sheeted dikes after DSDP Hole 504B. Here a high spatial resolution record of whole rock and mineral strontium isotopic compositions from Site 1256 is combined with core observations and downhole wireline geophysical measurements to determine the extent of basalt-hydrothermal fluid reaction and to identify fluid pathways at different levels in the upper ocean crust. The volcanic sequence at Site 1256 is dominated by sheet and massive lava flows but the Sr isotope profile shows only limited exchange with seawater. However, the upper margins of two anomalously thick (>25 m) massive flow sequences are strongly hydrothermally altered with elevated Sr isotope ratios and appear to be conduits of lateral low-temperature off-axis fluid flow. Elsewhere in the lavas, high 87Sr/86Sr are restricted to breccia horizons. Mineralised hyaloclastic breccias in the Lava-Dike Transition are strongly altered to Mg-saponite, silica and pyrite, indicating alteration by mixed seawater and cooled hydrothermal fluids. In the Sheeted Dike Complex 87Sr/86Sr ratios are pervasively shifted towards hydrothermal fluid values (∼0.705). Dike chilled margins display secondary mineral assemblages formed during both axial recharge and discharge and have higher 87Sr/86Sr than dike cores, indicating preferential fluid flow along dike margins. Localised increases in 87Sr/86Sr in the Dike-Gabbro Transition indicates the channelling of fluids along the sub-horizontal intrusive boundaries of the 25 to 50 m-thick gabbroic intrusions, with only minor increases in 87Sr/86Sr within the cores of the gabbro bodies. When compared to the pillow lava-dominated section from Hole 504B, the Sr isotope measurements from Site 1256 suggest that the extent of hydrothermal circulation in the upper ocean crust may be

  17. Toward Complete Isotopic Analysis of Individual Presolar Silicon Carbide Grains: C, N, Si, Sr, Zr, Mo, and Ba in Single Grains of Type X

    Pellin, M. J.; Calaway, W. F.; Davis, A. M.; Lewis, R. S.; Amari, S.; Clayton, R. N.

    2000-01-01

    The isotopic compositions of Sr, Ba, Zr and Mo in single presolar SiC grains from supernovae are different from those expected from either of the dominant heavy element neutron capture nucleosynthesis mechanisms, the s-process and the r-process.

  18. Lithogeochemistry and Sr-Nd isotopic composition of Neoproterozoic metasedimentary rocks of the Teplá Crystalline Complex, western Bohemian Massif: a geotectonic interpretation

    Fiala, Jiří; Henjes-Kunst, F.; Müller-Sigmund, H.; Vejnar, Zdeněk

    2014-01-01

    Roč. 59, č. 4 (2014), s. 293-311. ISSN 1802-6222 Institutional support: RVO:67985831 Keywords : metasedimentary rocks * geochemistry * Sr-Nd isotopes * provenance * Tepla Crystalline Complex * Bohemian Massif Subject RIV: DD - Geochemistry Impact factor: 1.405, year: 2014

  19. Petrochemical and Sr-Nd isotope investigations of Cretaceous intrusive rocks and their enclaves in the Togouchi-Yoshiwa district, northwest Hiroshima prefecture, SW Japan

    Petrographic, petrochemical and Sr-Nd isotopic data are presented for granitoids and microdioritic enclaves from two Cretaceous stocks (Togouchi granodiorite and Tateiwayama granite porphyry) from the Togouchi-Yoshiwa district, northwest Hiroshima prefecture, SW Japan. The data are used to examine the genetic relationships between the microdioritic enclaves and their granitoid hosts. The granodiorite, granite porphyry and the microdioritic enclaves are all calc-alkaline in nature, and belong to the I-type ilmenite series. The Togouchi graniodiorite has a Rb-Sr whole rock isochron age of 85.6±4.7 Ma with an initial Sr isotope ratio (SrI) of 0.70634±0.00012 (2σ). The Tateiwayama granite porphyry has a slightly younger Rb-Sr whole isochron age (77.4±3.1 Ma) but similar SrI of 0.70653±0.00015, suggesting that both stocks may have been derived from the same source. Despite diverse whole rock chemistry, the microdioritic enclaves in the respective intrusives have quite similar initial Sr and Nd isotope ratios, suggesting that they formed by fractional crystallization of a single magma, and also that the source of the enclaves in both intrusives had similar geochemical characteristics. In both stocks, however, the enclaves have distinctly lower initial Sr isotope ratios than their respective host rocks, indicating that they were derived from a different source than their hosts. In view of the geochemical and Sr-Nd isotope data, we infer that the enclave magmas were derived from a similar LILE- and LREE-enriched source to that of the Cretaceous basalts and gabbroic-dioritic rocks that are sporadically distributed in SW Japan. Such mafic to intermediate magmas were probably derived from the upper mantle, and transferred both heat and material to the lower crust, thus producing granitic magmas by partial melting. Successive mafic magmas or their differentiates could then have been injected into the granitic magma chamber, trapped and quenched, resulting in the formation

  20. Major and trace element abundances, and Sr and Nd isotopic composition of Carbonatites from Amba Dongar, Gujarat, India

    Chandra, Jyoti; Paul, Debajyoti; Viladkar, Shrinivas G.; Sensarma, Sarajit

    2015-04-01

    Despite significant progress during the last decade, the petrogenesis of carbonatites is still highly debated regarding the exact mechanism of carbonatite magma generation (fractional crystallization of carbonated-silicate magmas, liquid immiscibility of carbonated-silicate magmas, partial melting of carbonated mantle peridotite or carbonated lherzolitic mantle) and its evolution. The Amba Dongar carbonatite complex in Chhota Udaipur district, Gujarat is the youngest Indian carbonatite complex, which intruded into the ~ 90 Ma Bagh sandstones and limestone and 68-65 Ma Deccan flood basalts. The emplacement age (40Ar/39Ar age of 65±0.3 Ma; Ray and Pande, 1999) coincides with the age of main pulse of Deccan flood basalts at ca. 65 Ma. We report new geochemical data (major oxide and trace element abundances, and Sr and Nd isotopic ratios) on 23 carbonatite samples from Amba Dongar. The Amba Dongar carbonatite complex consists of carbonatite (sövite, and ankerite), and associated nephelinite, phonolite, and both pre- and post-carbonatite basalts. Detailed minerology of carbonatite include dominant calcite along with pyrochlore, apatite, magnetite, aegirine-augite and accessory phases. Apatite crystals are observed in carbonatite as well as in nephelinite. In sövites, apatite occur in various forms including cumulus, clusters and scattered within and along the boundary of calcite crystals. Two generation of apatite crystals are commonly observed in sövite and nephelinite; textural changes suggest presence of different five pulses of sövitic magma during the emplacement of the sövite ring dike. Bulk major oxides and trace element (including REEs) compositions of carbonatites and associated silicate rocks are determined by WD-XRF and ICP-MS, respectively. Major oxides abundances are consistent with the already available data on the Amba Dongar carbonatite complex. Trace element concentrations for the sövite reveals high concentrations of Sr (929-7476 ppm), Ba (344

  1. Fractionation of cesium isotopes and 90Sr in snowmelt run-off and lake waters from a contaminated Norwegian mountain catchment

    Cesium isotopes and 90Sr have been determined in the inflow and outflow rivers of a Norwegian subalpine lake. The lake is situated in an area contaminated by Chernobyl fallout. Sampling was carried out during the spring peak discharge period associated with snowmelt. Transported coarse particulate plant material was collected by traps. Particles and colloids were removed from water samples by hollow fibre ultrafiltration. The results illustrate that run-off during the spring snowmelt is an important pathway for these radionuclides. The cesium isotopes are predominantly transported as colloids, while 90Sr is present in the form of low molecular weight mobile species. Based on lake budget calculations, more than 50% of the cesium input is retained in the lake, while more than 90% of the 90Sr is transported through the lake and into lower parts of the drainage system. (author) 16 refs.; 6 figs.; 3 tabs

  2. Cluster emission in superdeformed Sr isotopes in the ground state and formed in heavy-ion reaction

    K P Santhosh; Antony Joseph

    2005-01-01

    Cluster decay of superdeformed 76,78,80Sr isotopes in their ground state are studied taking the Coulomb and proximity potential as the interacting barrier for the post-scission region. The predicted 1/2 values are found to be in close agreement with those values reported by the preformed cluster model (PCM). Our calculation shows that these nuclei are stable against both light and heavy cluster emissions. We studied the decay of these nuclei produced as an excited compound system in heavy-ion reaction. It is found that inclusion of excitation energy increases the decay rate (decreases 1/2 value) considerably and these nuclei become unstable against decay. These findings support earlier observation of Gupta et al based on PCM.

  3. Sr-Nd isotope changes of late cretaceous to early miocene volcanic rocks in central Chile (33oS)

    A longitudinal depression, the Central Valley, separates the Coast Range from the Andean Cordillera in central Chile. It contains volcanic and volcaniclastic rocks of Late Cretaceous to Tertiary age deposited in a continental environment, and partly eroded Tertiary volcanic complexes. The age of the rocks at the northern end of the Central Valley and their grouping in formations have been a long-standing controversy in Chilean geology (Thomas, 1958; Aguirre, 1960; Drake et al., 1976; Vergara and Drake, 1979; Thiele, 1980; Moscoso et al., 1982; Gana and Wall, 1997; Lopez-Escobar and Vergara, 1997; Selles, 1999). Here, we report new 40Ar/39Ar data and Sr-Nd isotope ratios for lavas, pyroclastic flows and associated subvolcanic rocks from this part of central Chile (au)

  4. A hydrogen gas-water equilibration method produces accurate and precise stable hydrogen isotope ratio measurements in nutrition studies

    Stable hydrogen isotope methodology is used in nutrition studies to measure growth, breast milk intake, and energy requirement. Isotope ratio MS is the best instrumentation to measure the stable hydrogen isotope ratios in physiological fluids. Conventional methods to convert physiological fluids to ...

  5. A sensitive and accurate method for determination of radium isotopes in environmental samples by alpha-spectrometry

    A sensitive and accurate method for determination of radium isotopes in water and soil samples by alpha-spectrometry has been developed. Ra-225, which is in equilibrium with its mother 229Th, was used as a yield tracer. Radium in water samples was preconcentrated by coprecipitation with BaSO4 and iron (III) hydroxide at pH 8-9 using ammonia solution, isolated from uranium, thorium and iron using a Microthene-TOPO chromatography column at 8 M HCl, separated from barium in a cation-exchange resin column using 0.05 M 1,2-cyclo hexylene- dinitrilo-tetraacetic acid monohydrate at pH 8.5 as an eluant, electrodeposited on a stainless steel disc in a medium of 0.17 M (NH4)2C2O4 at pH 2.6 and current density of 400 mA cm-2, and counted by α-spectrometry. Radium in soil samples was fused with Na2CO3 and Na2O2 at 600 degree C, leached with HNO3, HCl and HF, and. preconcentrated by coprecipitation with BaSO4 at pH 3. The procedure for further separation, purification electrodeposition and measurement of radium in soil samples was same as that for water samples.

  6. Multiple linear regression for isotopic measurements

    Garcia Alonso, J. I.

    2012-04-01

    There are two typical applications of isotopic measurements: the detection of natural variations in isotopic systems and the detection man-made variations using enriched isotopes as indicators. For both type of measurements accurate and precise isotope ratio measurements are required. For the so-called non-traditional stable isotopes, multicollector ICP-MS instruments are usually applied. In many cases, chemical separation procedures are required before accurate isotope measurements can be performed. The off-line separation of Rb and Sr or Nd and Sm is the classical procedure employed to eliminate isobaric interferences before multicollector ICP-MS measurement of Sr and Nd isotope ratios. Also, this procedure allows matrix separation for precise and accurate Sr and Nd isotope ratios to be obtained. In our laboratory we have evaluated the separation of Rb-Sr and Nd-Sm isobars by liquid chromatography and on-line multicollector ICP-MS detection. The combination of this chromatographic procedure with multiple linear regression of the raw chromatographic data resulted in Sr and Nd isotope ratios with precisions and accuracies typical of off-line sample preparation procedures. On the other hand, methods for the labelling of individual organisms (such as a given plant, fish or animal) are required for population studies. We have developed a dual isotope labelling procedure which can be unique for a given individual, can be inherited in living organisms and it is stable. The detection of the isotopic signature is based also on multiple linear regression. The labelling of fish and its detection in otoliths by Laser Ablation ICP-MS will be discussed using trout and salmon as examples. As a conclusion, isotope measurement procedures based on multiple linear regression can be a viable alternative in multicollector ICP-MS measurements.

  7. Ca, Sr, O and D isotope approach to defining the chemical evolution of hydrothermal fluids: example from Long Valley, CA, USA

    Brown, Shaun T.; Kennedy, B. Mack; DePaolo, Donald J.; Hurwitz, Shaul; Evans, William C.

    2013-01-01

    We present chemical and isotopic data for fluids, minerals and rocks from the Long Valley meteoric-hydrothermal system. The samples encompass the presumed hydrothermal upwelling zone in the west moat of the caldera, the Casa Diablo geothermal field, and a series of wells defining a nearly linear, ∼16 km long, west-to-east trend along the likely fluid flow path. Fluid samples were analyzed for the isotopes of water, Sr, and Ca, the concentrations of major cations and anions, alkalinity, and total CO2. Water isotope data conform to trends documented in earlier studies, interpreted as indicating a single hydrothermal fluid mixing with local groundwater. Sr isotopes show subtle changes along the flow path, which requires rapid fluid flow and minimal reaction between the channelized fluids and the wallrocks. Sr and O isotopes are used to calculate fracture spacing using a dual porosity model. Calculated fracture spacing and temperature data for hydrothermal fluids indicate the system is (approximately) at steady-state. Correlated variations among total CO2, and the concentration and isotopic composition of Ca suggest progressive fluid degassing (loss of CO2), which drives calcite precipitation as the fluid flows west-to-east and cools. The shifts in Ca isotopes require that calcite precipitated at temperatures of 150–180 °C is fractionated by ca. −0.3‰ to −0.5‰ relative to aqueous species. Our data are the first evidence that Ca isotopes undergo kinetic fractionation at high temperatures (>100 °C) and can be used to trace calcite precipitation along hydrothermal fluid flow paths.

  8. Age and petrology of the Kalaupapa Basalt, Molokai, Hawaii ( geochemistry, Sr isotopes).

    Clague, D.A.

    1982-01-01

    The post-erosional Kalaupapa Basalt on East Molokai, Hawaii, erupted between 0.34 and 0.57 million years ago to form the Kalaupapa Peninsula. The Kalaupapa Basalt ranges in composition from basanite to lava transitional between alkalic and tholeiitic basalt. Rare-earth and other trace-element abundances suggest that the Kalaupapa Basalt could be generated by 11-17% partial melting of a light-REE-enriched source like that from which the post-erosional lavas of the Honolulu Group on Oahu were generated by 2-11% melting. The 87Sr/86Sr ratios of the lavas range from 0.70320 to 0.70332, suggesting that the variation in composition mainly reflects variation in the melting process rather than heterogeneity of sources. The length of the period of volcanic quiescence that preceded eruption of post-erosional lavas in the Hawaiian Islands decreased as volcanism progressed from Kauai toward Kilauea. - Authors

  9. Toward complete isotopic analysis of individual presolar silicon carbide grains : C, N, Si, Sr, Zr, Mo, and Ba in single grains of type X.

    Pellin, M. J.; Calaway, W. F.; Davis, A. M.; Lewis, R. S.; Amari, S.; Clayton, R. N.

    2000-03-01

    Presolar silicon carbide grains form in a variety of types of stars, including asymptotic giant branch red giant stars and supernovae. The dominant mechanisms of heavy element nucleosynthesis, the s-process and r-process, are thought to occur mainly in AGB stars and supernovae, respectively [1]. We have previously reported that mainstream SiC grains have strong enrichments in the s-process isotopes of Sr, Zr and Mo [2-4] and initial results for X-type SiC grains showing enrichments in the r-process isotopes of Mo[5]. We report here the first measurements of Zr, Sr, and Ba isotopes along with expanded studies of Mo in individual X-type SiC grains, which have previously been identified as having formed from supernova ejects.

  10. A Nd and Sr isotopic study of the Trinity peridotite; implications for mantle evolution

    Field evidence indicates that the Trinity peridotite was partially melted during its rise as a part of the upwelling convecting mantle at a spreading center. A Sm-Nd mineral isochron for a plagioclase Iherzolite yields an age, T=427+-32 Ma and initial epsilonsub(Nd)=+10.4-+0.4 which is distinctly higher than that expected for typical depleted mantle at this time. This age is interpreted as the time of crystallization of trapped melt in the plagioclase Iherzolite P-T field. This time of crystallization probably represents the time when the massif was incorporated as a part of the oceanic lithosphere. The Sm-Nd model age of the plagioclase Iherzolite total rock is Tsub(CHUR)sup(Nd)=3.4 AE. This suggests that the Trinity peridotite was derived from a mantle that was depleted rather early in earth history. The peridotite contains many generations of pyroxenite dikes and some microgabbro dikes. We report data for two dikes that clearly crosscut the main metamorphic fabric of the peridotite. A microgabbro dike yields a Sm-Nd mineral isochron age of T=435+-21 Ma and epsilonsub(Nd)=+6.7-+0.3. A pyroxenite dike yields an initial epsilonsub(Nd)=+7.3+-0.4. The initial epsilonsub(Nd) values for the pyroxenite and gabbro dikes are fairly similar to those for the depleted mantle at this time and are distinct from the Iherzolit - demonstrating that they are not genetically related. Rb-Sr data do not give any coherent pattern. However, some bounds can be put on initial Sr values of epsilonsub(Sr)<=-21 for the plagioclase Iherzolite and epsilonsub(Sr)<=-8.7 for the microgabbro dike. (orig.)

  11. U and Sr Isotopes in ground water and calcite, Yucca Mountain, Nevada: Evidence against upwelling water

    Stuckless, J.S.; Peterman, Z.E.; Muhs, D.R.

    1991-01-01

    Hydrogenic calcite and opaline silica deposits in fault zones at Yucca Mountain, Nevada, have created considerable public and scientific controversy because of the possible development of a high-level nuclear waste repository at this location. Strontium and uranium isotopic compositions of hydrogenic materials were used to test whether the veins could have formed by upwelling of deep-seated waters. The vein deposits are isotopically distinct from ground water in the two aquifers that underlie Yucca Mountain, indicating that the calcite could not have precipitated from ground water. The data are consistent with a surficial origin for the hydrogenic deposits.

  12. Rb-Sr and Sm-Nd isotopic study of the Glen Mountains layered complex: Initiation of rifting within the southern Oklahoma aulacogen

    Lambert, David D.; Unruh, D. M.; Gilbert, M. Charles

    1988-01-01

    Rb-Sr and Sm-Nd isotopic data for rocks and minerals of the Glen Mountains layered complex (GMLC), a midcontinent mafic layered intrusion in the Wichita Mountains of southwestern Oklahoma, constrain the time of initiation of rifting within the southern Oklahoma aulacogen and provide information on the chemistry of the early Paleozoic mantle. Four whole-rock samples define a Rb-Sr isochron corresponding to a maximum crystallization age of 577 ±165 Ma and an initial Sr isotopic composition of 0.70359 ±2. These whole-rock analyses do not define a Sm-Nd isochron; rather, they display a significant range in initial Nd isotopic composition (ɛNd = 3.63-5.35). A three-point Sm-Nd mineral-whole-rock (internal) isochron for an anorthositic gabbro provides a crystallization age of 528 ±29 Ma. These data suggest that the GMLC was emplaced into the southern Oklahoma aulacogen during the initial phase of rifting along the southern margin of the North American craton in the early Paleozoic. This Sm-Nd internal isochron age is within analytical uncertainty of U-Pb zircon ages for granites and rhyolites from the Wichita Mountains; therefore, mafic and felsic magmatism may have been contemporaneous within the rift during the early stages of development. Hybrid rocks and composite dikes in the Wichita Mountains provide field evidence for contemporaneous mafic and felsic magmas. Initial Sr and Nd isotopic data suggest that magmas parental to the GMLC were derived from a depleted mantle source. However, Nd isotopic data for the GMLC plot distinctly below data for the depleted mantle source cited by DePaolo and thus suggest that the parental magmas of the GMLC were either contaminated by Proterozoic crust of the southern midcontinent or were derived from a heterogeneous mantle source region that had variable initial Nd isotopic compositions.

  13. Petrology, Geochemistry and Nd-Sr-Pb Isotopic Properties of Volcanic Rocks in Daheishan Island, Penglai, Shandong Province

    Fu Yongtao; Li Anchun

    2003-01-01

    The major elements, trace elements, K-Ar age and Sr-Nd-Pb isotopic systems of the Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province are measured. The volcanic rocks ( olivine-nephelinite and nepheline-basanite ) in Daheishan Island erupted periodically in an interval of 0.32 Ma, from 8.72 Ma, 8.39 Ma, 8.08 Ma to 7.73 Ma. The volcanic rocks are all rich in light REEs. They are similar to the OIB-type alkali basalt in the trace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta, and imcompatible elements such as Cs, Rb, Ba, Th, U. The volcanic rocks show a depletion of K and Rb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Island is originated from deep resources under the continental mantle. ε Nd (0) values of the volcanic rocks in Daheishan Island and Cisban are 5.31 ~ 8.51 and 7.33 respectively, suggesting that the volcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR. 143Nd /144Nd ratios of Daheishan Island olivine-nephelinite and Cishan alkali basalts are 0.512 910 ~ 0.513 074 and 0.513 014 respectively. The 87Sr /86Sr of Daheishan Island volcanic rocks are lower than that of Cishan, 0.703 427 ~ 0.703 482 and 0.703 895 respectively. The Daheishan Island olivinenephelinite has the Pb isotopic values as follows: 206Pb /204pb = 18.028 9 ~ 17.972 8, 207Pb /204pb= 15.435 8 ~ 15.402 2 and 208Pb /204Pb = 38.087 6 ~ 37.997 5, lower than those of Cishan basanite. The Cishan basanite has 206Pb /204pb = 18.240 1, 207Pb /204Pb = 15.564 5 and 208Pb /204pb = 38.535. The authors suggest that the olivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkali basalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM+PREMA and perhaps DM ( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Island and Cishan. The

  14. Geochemistry of Late Mesozoic mafic dykes in western Fujian Province of China:Sr-Nd isotope and trace element constraints

    2007-01-01

    The Bancun diabase dyke and the Bali hornblende gabbro dyke in western Fuiian Province were emplaced in the Early and Late Cretaceous periods,respectively;the former is designated to calc-alkaline series and the latter to K-high-calc-alkaline rock series.Both the dykes are characterized by such geochemical characteristics as high Al and Na2O>K2O.As for the Bancun dyke,A12O3=16.32%-17.54%and K2O/Na2O=0.65-0.77;as for the Bali dyke,A12O3=16.89%-17.81%and K2O,Na2O=O.93-O.99.Both the Bancun and Bali mafic dykes are relatively endched in LILE and LREE,but depleted in HSFE, displaying the geochemical characteristics of continental marginal arc,with high initial Sr isotopic ratios and low εNd values,The (87Sr/86Sr)i ratios of the Bancun diabase dyke are within the range of 0.708556-0.70903 and their εNd(t)values vary between-6.8 and-6.3;those of the Bali hornblende dyke are within the range of 0.708556-0.710746 and their εNd(t) values are -4.7--4.7,showing the characteristics of enriched mantle EM Ⅱ.The isotope and trace element data showed that the mafic dykes have not experienced obvious crustal contamination,and metasomatism caused by subduction fluids is the main factor leading to LILE and UREE enrichments.The enriched mantle is the source region for the mafic dykes,and mixing of subduction fluid metasomatized enriched mantle and EM Ⅱ-type mantle constituted the mantle source region of both the Bancun and Bali mafic dykes.Upwelling of the asthenosphere mantle provided sufficient heat energy for the generation of magmas.In accordance with the discrimination diagram of their tectonic settings as well as their trace element geochemical characteristics,it is considered that the dykes both at Bancun and Bali possess the characteristics of continental marginal arc,revealing the tectonic environment of formation of the mafic dykes,the continental dynamic background as an intraplate tensional belt in which the mafic dykes were emplaced.Meanwhile,it is also indicated

  15. Geochemical and Sr-Nd-Pb isotopic evidence for ancient lower continental crust beneath the Xi Ujimqin area of NE China

    Gao, Xiaofeng; Guo, Feng; Xiao, Peixi; Kang, Lei; Xi, Rengang

    2016-05-01

    The Central Asian Orogenic Belt (CAOB) is the largest Phanerozoic accretionary orogen on Earth. The role that Precambrian continental microblocks played in its formation, however, remains a highly controversial topic. New zircon U-Pb age data and whole-rock geochemical and Sr-Nd-Pb isotopic studies on Permian (253-251 Ma) andesites from the Xi Ujimqin area provide the first evidence for the existence of a continental lower mafic crust in the eastern segment of the CAOB. These Permian lavas generally have chemical compositions similar to experimental melts of garnet pyroxenites. Based on Sr-Nd-Pb isotopic compositional differences, they can be further subdivided into two groups. Group 1 has moderately radiogenic Sr (87Sr/86Sr(i) = 0.7060-0.7062) and nonradiogenic Nd (εNd(t) = - 9.0-8.3) and Pb (e.g., 206Pb/204Pb = 17.18-17.23) isotopic compositions similar to the ancient lower mafic crust beneath the North China Craton (NCC). Compared with Group 1, Group 2 has less radiogenic Sr (87Sr/86Sr(i) = 0.7051-0.7055), and more radiogenic Nd (εNd(t) = - 0.2-+1.4) and Pb (e.g., 206Pb/204Pb = 18.04-18.20) isotopic compositions as observed in the Phanerozoic granitoids and felsic lavas of the CAOB. The combined geochemical and isotopic data indicate that Group 1 was derived from ancient lower mafic crust of the NCC affinity, with a residual assemblage of pyroxene + plagioclase + amphibole. The source for Group 2 was a mixture of ancient lower mafic crust and a juvenile crustal component, and melting left a residue of orthopyroxene + clinopyroxene + plagioclase + garnet + amphibole. Generation of these two types of late Permian andesites favors a model whereby breakoff of a subducted slab and subsequent lithospheric extension triggered extensive asthenospheric upwelling and melting of the continental mafic lower crust of the eastern CAOB. The discovery of ancient lower continental crust of the NCC affinity in the CAOB implies that the NCC experienced continental breakup during

  16. Impact of transboundary air pollution on our alpine water resources: Application of multi-isotope (N, S, O, Pb, Sr)

    Karst and other sensitive aquifers contribute up to 90% to the total drinking water supply in some European regions. However, they are more vulnerable to contamination than other aquifers due to short transfer times from recharge to source. Therefore, the main objective of this paper is to show possibilities to quantify the impact, even small of long distance air pollution on sensitive water resources (e.g. karst) even in relatively pristine and remote areas as the front-range of the Northern Calcareous Alps in Austria. The monthly precipitation (May and September 2005) samples show 18O-rich nitrate and sulphate ions, whereas the soil nitrate shows variable contribution of atmospheric nitrogen with depth. Sulphate in the soil profile changes in the direction to lower 18O and higher 34S values with depth. Assuming the values of precipitation and soil for nitrate and precipitation and the dolomite rocks for sulphate and end-members the contribution of atmospheric nitrate and sulphate in the groundwater are estimated in the range of 20-40%. In addition, strontium isotopes support that up to 25% more atmospheric radiogenic Sr is added to the groundwater. Isotope data confirm that considerable amounts of atmospheric pollution is added to sensitive karst-groundwater by preferential flow. (author)

  17. Quantum critical origin of the superconducting dome and the isotope effect in SrTiO3

    Kedem, Yaron; Edge, Jonathan; Aschauer, Ulrich; Spaldin, Nicola; Balatsky, Alexander

    We expand the notion that quantum criticality can induce superconductivity, by proposing a concrete mechanism for superconductivity due to quantum ferroelectric fluctuations. To this end, we investigate the origin of superconductivity in doped SrTiO3 (STO) using a combination of density functional and strong coupling theories within the framework of quantum criticality. Our density functional calculations of the ferroelectric soft mode frequency as a function of doping reveal a crossover related to quantum paraelectricity at a doping level coincident with the experimentally observed top of the superconducting dome. Thus, we suggest a model in which the soft mode fluctuations provide the pairing interaction for superconductivity carriers. Within our model, the low doping limit of the superconducting dome is explained by the emergence of the Fermi surface, and the high doping limit by departure from the quantum critical regime. This results in a prediction that the highest critical temperature will increase and shift to lower carrier doping with increasing 18O isotope substitution, a scenario that is experimentally verifiable. In addition we show a connection between the isotope exponent of superconductivity and the critical exponent pertaining to quantum phase transition. This work was supported by US DOE BES E304, by the ETH Zürich (NAS and UA) and by the ERC Advanced Grant Program, No. 291151 (NAS and UA), No321031, KAW and LDRD (YK).

  18. The Kipushi Cu-Zn deposit (DR Congo) and its host rocks: A petrographical, stable isotope (O, C) and radiogenic isotope (Sr, Nd) study

    Van Wilderode, J.; Heijlen, W.; De Muynck, D.; Schneider, J.; Vanhaecke, F.; Muchez, Ph.

    2013-03-01

    Near the city of Kipushi, located in the southern part of the Central African Copperbelt, a major vein-type Cu-Zn ore deposit occurs. A combination of petrographic techniques and both stable (O, C) and radiogenic (Sr, Nd) isotope analysis is used to investigate the influence of the mineralisation on the Neoproterozoic dolomite host rocks. A quantification of the abundance and size of the different host rock constituents (dolomite types, quartz, phyllosilicates) revealed a lithostratigraphical controlled variation, without trends towards the ore body. The bulk oxygen isotopic composition of the host rock varies between -2.54‰ and -9.64‰ V-PDB, with most values within the range of Neoproterozoic marine dolomite. Samples with more positive δ18O all originate from the same stratigraphic interval and are interpreted as the result of reflux dolomitisation by an evaporated brine. Few samples with depleted δ18O signatures could indicate the influence of a depleted or high temperature fluid, but are not related to the ore deposit. Moreover, the presence of the ore body cannot be traced through the host rock oxygen isotopic composition. δ18O of gangue dolomite is significantly depleted in comparison with the host rocks and ranges between -7.67‰ and -12.46‰ V-PDB. For an estimated mineralisation temperature of 310 °C, this implies a δ18Ofluid between 10.7‰ and 15.6‰ V-SMOW. This is a significant enrichment compared to Neoproterozoic seawater, indicating that the mineralising fluid underwent significant fluid-rock interactions. δ13C of both host rock and gangue dolomite are in range of Neoproterozoic marine dolomites. However, a limited stratigraphic interval has clearly more negative δ13C signatures, due to in situ maturation of carbonaceous material. At the time of mineralisation (450 Ma), the host rock dolomite has a strontium isotopic composition partly more radiogenic than Neoproterozoic marine carbonates (0.70793 gangue dolomite is significantly more

  19. Sm-Nd and Rb-Sr isotope systematics of an Archean anorthosite and related rocks from the Superior Province of the Canadian Shield

    Sm-Nd and Rb-Sr isotopic data for the Bad Vermilion Lake anorthosite complex (BVL) in the Rainy Lake area of the Superior Province of northwestern Ontario show that direct ages of Archean anorthosites can be obtained with these isotopic systems despite the effects of low-grade metamorphism. There is sufficient spread in Sm/Nd between plagioclase megacrysts and coexisting mafic groundmass to allow the determination of reasonably precise internal Sm-Nd isochrons. Anorthosite samples from BVL show an unusually large range in LIL concentrations such that there is sufficient spread in Rb/Sr for a whole-rock isochron (2.69+-0.10 Ga, Isub(Sr)=0.70079+-8). This variability may have been caused by Rb introduction during hydrothermal alteration and/or low-grade metamorphism. The Sm-Nd isochron for BVL (2747+-58 Ma, epsilonsub(Nd)=+2.0+-1.4) includes data for anorthosite, gabbro and metabasalt, and is consistent with the consanguineity of these units in the Rainy Lake area. The age is interpreted as the time of crystallization of the anorthosite complex and related mafic plutonics and volcanics. Visibly altered samples show evidence for disturbance of the Sm-Nd and Rb-Sr isotopic systems. In one altered porphyritic dike plagioclase appears to have exchanged light REE with the relatively REE-rich basaltic matrix. This sample yields an internal Sm-Nd age of 2.16+-0.05 Ga, which may correspond to the time of local heating or represent a partial resetting from a still younger event. Initial isotopic ratios of Nd and Sr determined here add to the growing body of data indicating that the Superior Province is underlain by depleted mantle. (orig.)

  20. Tracing Anthropogenic Salinity Inputs to the Semi-arid Rio Grande River: A Multi-isotope Tracer (U, S, B and Sr) Approach

    Garcia, S.; Nyachoti, S. K.; Ma, L.; Szynkiewicz, A.; McIntosh, J. C.

    2015-12-01

    High salinity in the Rio Grande has led to severe reductions in crop productivity and accumulation of salts in soils. These pressing issues exist for other arid rivers worldwide. Salinity contributions to the Rio Grande have not been adequately quantified, especially from agriculture, urban activities, and geological sources. Here, we use major element concentrations and U, S, B, Sr isotopic signatures to fingerprint the salinity sources. Our study area focuses on a 200 km long stretch of the Rio Grande from Elephant Butte Reservoir, NM to El Paso, TX. River samples were collected monthly from 2014 to 2015. Irrigation drains, groundwater wells, city drains and wastewater effluents were sampled as possible anthropogenic salinity end-members. Major element chemistry, U, S and Sr isotope ratios in the Rio Grande waters suggest multiple salinity inputs from geological, agricultural, and urban sources. Natural upwelling of groundwater is significant for the Rio Grande near Elephant Butte, as suggested by high TDS values and high (234U/238U), 87Sr/86Sr, δ34S ratios. Agricultural activities (e.g. flood irrigation, groundwater pumping, fertilizer use) are extensive in the Mesilla Valley. Rio Grande waters from this region have characteristic lower (234U/238U), 87Sr/86Sr, and δ34S ratios, with possible agricultural sources from use of fertilizers and gypsum. Agricultural practices during flood irrigation also intensify evaporation of Rio Grande surface water and considerably increase water salinity. Shallow groundwater signatures were also identified at several river locations, possibly due to the artificial pumping of local groundwater for irrigation. Impacts of urban activities to river chemistry (high NO3 and B concentrations) were evident for locations downstream to Las Cruces and El Paso wastewater treatment plants, supporting the use of the B isotope as an urban salinity tracer. This study improves our understanding of human impacts on water quality and elemental

  1. Nd-Sr isotopic compositions of dissolved and particulate material transported by the Parana and Uruguay rivers during high (december 1993) and low (september 1994) water periods

    Our motivation is to better constrain the neodymium and strontium isotopic signatures of the closest continental riverine source (Parana and Uruguay rivers) to the Brazil/Malvinas Confluence zone in the Southwest Atlantic Ocean. We thus present new isotopic data on the Nd and Sr of the dissolved and suspended loads of the Parana and Uruguay rivers for two water periods forming the Rio de la Plata whose drainage basin is the second largest one in South America. The Parana dissolved material shows less radiogenic (εNd (0) ranging between -12.1 and -8.2) than the Uruguay one with a mean εNd (0) value of -6.3 ± 0.3. Suspended particulates display the same isotopic trend (mean εNd (0) value of -10.3 and -6.0 for the Parana and Uruguay rivers, respectively). Dissolved load 87Sr/86Sr in the Parana (0.7123) is found to be more radiogenic than the Uruguay one (0.7097); the suspended load follows the same trend with 87Sr/86Sr ratios of 0.7247 and 0.7115 in the Parana and Uruguay rivers, respectively. The relatively radiogenic Nd and non radiogenic Sr of the Uruguay River as compared to the Parana River could be attributed to a predominance of tholeiitic basalts in the drainage basin. A revisited estimation of the fluxes of Nd considering all South American rivers delivering into the western South and Tropical Atlantic Ocean yields a Nd particulate flux to estuarine water two orders of magnitude higher than the Nd dissolved flux. Considering the net dissolved and suspended fluxes of Nd reaching the Rio de la Plata, we have calculated a resulting εNd (0) equal to -10.2. The computation of εNd (0) of the Rio de la Plata outflow waters gives a value of -8.3, taking into account various removal processes within the estuary. (authors)

  2. Saturation of Deformation and Identical Bands in Very-Neutron Rich Sr Isotopes

    2002-01-01

    The present proposal aims at establishing nuclear properties in an isotopic chain showing unique features. These features include the saturation of ground state deformation at its onset and the existence of ground state identical bands in neighbouring nuclei with the same deformation. The measurements should help to elucidate the role played by the proton-neutron residual interaction between orbitals with large spatial overlap, i.e. $\\pi g _{9/2} \

  3. Hf-Nd-Sr isotopes and incompatible element abundances in island arcs: Implications for magma origins and crust-mantle evolution

    We present Hf, Nd and Sr isotopic data and abundances of K, Rb, Cs, Ba, Sr, Hf and REE for 32 samples from seven intra-oceanic island arcs. Samples from the Marianas, Izu, Aleutian and New Britain arcs have tightly grouped 176Hf/177Hfproportional0.28320, 143Nd/144Ndproportional0.51303 and 87Sr/86Srproportional0.7035 close to, but distinct from, mid-ocean ridge basalts (MORB) for 143Nd/144Nd and 87Sr/86Sr. In contrast, samples from the Sunda, Banda and Lesser Antilles arcs are much more variable towards lower 176Hf/177Hf and 143Nd/144Nd, and higher 87Sr/86Sr. Isotopically, island arcs on the whole are closely similar to ocean islands. Some commonly-occurring features of the trace element geochemistry of island arcs are apparent in our data: alkali and alkaline-earth elements, particularly Cs, have high abundance relative to LREE compared to oceanic basalts; negative Ce anomalies occur in six out of seven arcs. However, Hf does not appear underabundant relative to REE. The isotopic data require a continental component in all island arcs, in addition to probable mantle and oceanic crust contributions, even for the arcs with isotope ratios close to MORB. In the absence of continental crust, we can best explain this component by subducted pelagic sediment in the arc magma source region. The involvement of sediments in all arcs implies that there is an inherent recycling of older continent to island arcs, and potentially to new continent, of at least 1%. Conservative calculations show that the upper subducted slab (basalt + sediment) passes beyond the arc magma genesis zone and enters the deep mantle with a minimum of 500-1000 ppm K, and corresponding amounts of other incompatible elements. If this material is not completely homogenized with the mantle and later becomes part of the source of ocean island magmas, then the ocean island-island arc isotopic similarity is a result of their similar mix of source materials-mantle peridotite with trace element signatures from

  4. Rb-Sr and Sm-Nd isotopic study of the Glen Mountains layered complex: initiation of rifting within the southern Oklahoma aulacogen

    Lambert, D.D.; Unruh, D.M.; Gilbert, M.C.

    1988-01-01

    Rb-Sr and Sm-Nd isotopic data for rocks and minerals of the Glen Mountains layered complex (GMLC), a midcontinent mafic layered intrusion in the Wichita Mountains of southwestern Oklahoma, constrain the time of initiation of rifting within the southern Oklahoma aulacogen and provide information on the chemistry of the early Paleozoic mantle. Four whole-rock samples define a Rb-Sr isochron corresponding to a maximum crystallization age of 577 +/- 165 Ma and an initial Sr isotopic composition of 0.70359 +/- 2. A three-point Sm-Nd mineral-whole-rock (internal) isochron for an anorthositic gabbro provides a crystallization age of 528 +/- 29 Ma. These data suggest that the GMLC was emplaced into the southern Oklahoma aulacogen during the initial phase of rifting along the southern margin of the North American craton in the early Paleozoic. This Sm-Nd internal isochron age is within analytical uncertainty of U-Pb zircon ages for granites and rhyolites from the Wichita Mountains; therefore, mafic and felsic magmatism may have been contemporaneous within the rift during the early stages of development. Hybrid rocks and composite dikes in the Wichita Mountains provide field evidence for contemporaneous mafic and felsic magmas. Initial Sr and Nd isotopic data suggest that magmas parental to the GMLC were derived from a depleted mantle source. However, Nd isotopic data for the GMLC plot distinctly below data for the depleted mantle source cited by DePaolo and thus suggest that the parental magmas of the GMLC were either contaminated by Proterozoic crust of the southern midcontinent or were derived from a heterogenous mantle source region that had variable initial Nd isotopic compositions.

  5. A multi-isotope (B, Sr, O, H) and age dating (3H-3He, 14C) study of groundwater from Salinas Valley, California

    This study investigates the chemical and isotopic compositions of groundwater from Salinas Valley, California in order to constrain the origin and rates of groundwater contamination. We use an array of geochemical, environmental isotopes of water (18O/16O, D/H, 3H-3He) and dissolved salts (11B/10B, 87Sr/86Sr, 14C) to establish a reliable conceptual model for the basin. The basin consists of a deep, confined '400-foot aquifer' overlying the '180-foot aquifer' and a perched aquifer, all made up of sand, gravels, clays, and alluvial deposits. Our 3H-3He, 14C, and δ18O results show different replenishment zones and rates in the basin: (1) rapid replenishment (14C concentrations of 72 to 98 pmc) in the perched and 180-foot aquifers in the northern area; (2) fast arrival (15 years) of 18O- and NO3-enriched agriculture-return flows in the unconfined 180-foot aquifer in the central valley; (3) young water recharge (6 to 20 years) fi-om the Salinas River, which is enriched in 18O and D relative to GMWL, occurs in the southern basin; and (4) travel time of >10,000 years (14C = 21.3 PMC) in the deep 400-foot aquifer in the northern area of the valley, indicating pristine slow recharge. We identified several different end-member saline components with distinguishable chemical and isotopic fingerprints: (1) agriculture return flow in the perched aquifer (e.g., high NO3 and SO4, low 87Sr/86Sr 0.7082, δ11B = 19 per mille); (2) salt-water intrusion in the northern basin (e.g., low Na/Cl, marine Br/Cl, high Ca/Mg, δ11B = 17 to 38 per mille, 87Sr/86Sr = 0.7088 to 0.7096; (3) non-marine saline water in the southern part of the valley (e.g., high SO4, high Na/Cl, δ11B = 24 to 30 per mille, 87Sr/86Sr = 0.70852). The geochemical and isotopic fingerprints of the different water sources enables us to delineate the impact of these sources in different areas of the valley as well as to evaluate the origin of the saline, Sod-enriched plume, that is located north of Salinas City Our data

  6. O, Sr and Nd isotopic constraints on Cenozoic granitoids of Northwestern Anatolia, Turkey: Enrichment by subduction zone fluids

    Yücel-Öztürk, Yeşim

    2016-05-01

    The oxygen and strontium isotope compositions of Cenozoic granitoids cropping out in the İzmir-Ankara-Erzincan suture zone help constrain the petrological evolution of magmatism in northwest Anatolia. The magmatism was mostly widespread between late Eocene (∼37 Ma) and the middle Miocene (∼14-15 Ma), and is represented by volcanic and plutonic rocks of orogenic affinity, of which Ezine, Eğrigöz, Çataldağ and Kozak are the largest Tertiary granitic plutons exposed in northwest Anatolia. They vary from granite to granodiorite, and are subalkaline, belonging to the high-K calc-alkaline I-type granite series. All these characteristics, combined with major, trace element geochemical data as well as mineralogical and textural evidence, reveal that the Oligocene-Miocene granitoids of NW Anatolia are comparable with volcanic arc granites, formed in a transitional oceanic to continental collisional tectonic setting, from a hybrid source, having crustal and mantle components that underwent further interaction with the upper crust. These plutons have initial 87Sr/86Sr ratios of 0.7072-0.7094, and εNd(t) values ranging from -3.48 to -1.20. These characteristics also indicate that a crustal component played an important role in the petrogenesis of NW Anatolian Oligocene-Miocene granitoids. The moderately evolved Ezine, Eğrigöz, Çataldağ and Kozak granitoids, have δ18O values that are consistent with those of normal I-type granites (6-10‰), but the δ18O relationships among minerals of samples collected from the intrusive contacts which are closest to mineralized zones, indicate a major influence of hydrothermal processes under subsolidus conditions. The oxygen isotope systematics of the samples from these plutons result from the activity of high-δ18O fluids (magmatic water), with major involvement of low-δ18O fluids (meteoric water) evident, near the edge zone of these plutons. This is most evident in δ18O quartz-feldspar pairs from these granitoids, which

  7. A Sr-Nd-Hf isotope characterization of dust source areas in Victoria Land and the McMurdo Sound sector of Antarctica

    Blakowski, Molly A.; Aciego, Sarah M.; Delmonte, Barbara; Baroni, Carlo; Salvatore, Maria Cristina; Sims, Kenneth W. W.

    2016-06-01

    Determining the geographical provenance of dust provides crucial insight into the global dust cycle. For the East Antarctic Ice Sheet (EAIS), the importance of Southern hemisphere potential dust sources has been thoroughly investigated using radiogenic isotopes, whereas proximal dust source areas located on the periphery of the ice sheet remain poorly documented from a geochemical standpoint. In this work, we expand the existing isotopic (Srsbnd Nd) catalogue of dust and sand-sized sediments from Victoria Land and the McMurdo Sound sector, and incorporate Hf isotopic data to place additional constraints on dust source identification. The isotopic field for materials considered in this study is characterized by 87Sr/86Sr ratios ranging from 0.703 to 0.783, εNd between -12.01 and 6.36, and εHf from -16.77 to 6.89. As reported in previous works, the data reveal close relationships between Antarctic sediments and distinct parent lithologies; in addition, our findings emphasize the background presence of very fine dusts originating from dominant global sources and regional volcanic activity as barriers to direct source-to-sink comparison of isotopic signatures. Thus, geochemical characterizations of dust sources to the Antarctic ice sheet involving multiple size fractions, including coarser-grained particles more susceptible to short-range transport, can help us to rule out global sources of dust when examining local sediment cores and ice cores.

  8. Use of Pb and Sr isotopes on the determination of lead mineralization sources from Ribeira valley - Sao Paulo and Parana states

    A lead and strontium isotope study was carried out on galena, barite and calcite from Pb-Ag syngenetic stratiform (Perau type) and hydrothermal veins (Panela type) deposits from Vale do Ribeira region (Sao Paulo and Parana states). The leads from the Perau and Panelas type deposits have respectively isotope ratios (sup(206)Pb/ sup(204)Pb 16.157 to 16.505 amd 16.520 to 17.273; sup(207)Pb/ sup(204)Pb = 15.466 to 15.720 and 15.470 to 15.780 and sup(208)Pb/ sup(204)Pb = 36.370 to 36.763 and 37.043 to 38.243), that defined a Stacey and Kramers model ages mainly concentrate within 1.7-1.5Ga. A review of published Pb isotopic compositions for these deposits and considerations of new Sr isotope data and Pb results using plumbotectonics model, indicate that the Perau type mineralizations are related to the syngenetic process and the Pb are derived from upper crust with a short crustal residence time. For the Panelas type deposits the Pb and Sr isotope studies support the conclusion that the ores were emplaced during regional metamorphism and the Pb were derived from lithologically complex source which may include metasedimentary and basement rocks. (author)

  9. Petrology and Sr-Nd-Pb isotope geochemistry of Late Cretaceous continental rift ignimbrites, Kap Washington peninsula, North Greenland

    Thorarinsson, Sigurjon B.; Holm, Paul M.; Duprat, Helene I.; Tegner, Christian

    2012-03-01

    The Late Cretaceous-Palaeocene (71-61 Ma) Kap Washington Group (KWG) volcanic sequence is exposed at the north coast of Greenland. The sequence is bimodal and was erupted in a continental rift setting during the opening of the Arctic Ocean. The succession exposed on the Kap Washington peninsula, which forms the bulk of the KWG sequence (> 5 km thick), has been sampled along four traverses with a combined stratigraphic thickness of ca. 1500 m. The sampled sequence is dominated by silicic ignimbrites (69-79 wt.% SiO2) showing geochemical features typical of ferroan, A-type granitoids. The ignimbrites range from sparsely phyric, mildly peraluminous compositions [ASI = Al2O3/(CaO + Na2O + K2O) = 1.05-1.20] to feldspar + quartz ± sodic amphibole ± Fe-Ti oxide phyric peralkaline compositions [PI = (Na2O + K2O)/Al2O3 = 1.00-1.40]. The peraluminous ignimbrites appear to overlie the peralkaline ignimbrites, although stratigraphy is complicated by faulting. Fiamme imbrication indicates that both types were erupted from a vent area located north of the Kap Washington peninsula. The peralkaline ignimbrites have Sr-Nd-Pb isotopic compositions which overlap with the compositions of KWG basalts, indicating a dominantly basaltic source. The more peralkaline compositions were generated by up to ca. 50% fractional crystallisation of alkali feldspar-quartz-dominated assemblages from mildly peralkaline parental magmas, themselves probably derived by fractionation of trachytic magmas. The peraluminous ignimbrites have slightly negative ɛNd(i) and more radiogenic 207Pb/204Pbi and 208Pb/204Pbi. Modelling indicates that they are not cogenetic with the peralkaline ignimbrites and they are inferred to have originated by partial melting of hybridised mafic crust. Petrographic evidence suggests that magma mixing was an important process and variations in Nd-Pb isotopes and trace element ratios indicate mixing between peralkaline and peraluminous magma batches.

  10. Sm-Nd and Rb-Sr Isotopic Studies of Meteorite Kalahari 009: An Old VLT Mare Basalt

    Shih, C.-Y.; Nyquist, L. E.; Reese, Y.; Bischoff, A.

    2008-01-01

    Lunar meteorite Kalahari 009 is a fragmental basaltic breccia contain ing various very-low-Ti (VLT) mare basalt clasts embedded in a fine-g rained matrix of similar composition. This meteorite and lunar meteorite Kalahari 008, an anorthositic breccia, were suggested to be paired mainly due to the presence of similar fayalitic olivines in fragment s found in both meteorites. Thus, Kalahari 009 probably represents a VLT basalt that came from a locality near a mare-highland boundary r egion of the Moon, as compared to the typical VLT mare basalt samples collected at Mare Crisium during the Luna-24 mission. The concordant Sm-Nd and Ar-Ar ages of such a VLT basalt (24170) suggest that the extrusion of VLT basalts at Mare Crisium occurred 3.30 +/- 0.05 Ga ag o. Previous age results for Kalahari 009 range from approximately 4.2 Ga by its Lu-Hf isochron age to 1.70?0.04 Ga of its Ar-Ar plateau ag e. However, recent in-situ U-Pb dating of phosphates in Kalahari 009 defined an old crystallization age of 4.35+/- 0.15 Ga. The authors su ggested that Kalahari 009 represents a cryptomaria basalt. In this r eport, we present Sm-Nd and Rb-Sr isotopic results for Kalahari 009, discuss the relationship of its age and isotopic characteristics to t hose of other L-24 VLT mare basalts and other probable cryptomaria ba salts represented by Apollo 14 aluminous mare basalts, and discuss it s petrogenesis.

  11. U-Pb zircon geochronology, petrochemical and Sr-Nd isotopic characteristic of Late Neoproterozoic granitoid of the Bornaward Complex (Bardaskan-NE Iran)

    Bagherzadeh, R. Monazzami; Karimpour, M. H.; Farmer, G. Lang; Stern, C. R.; Santos, J. F.; Rahimi, B.; Heidarian Shahri, M. R.

    2015-11-01

    The Bornaward Granitoid Complex (BGC) in the Taknar Zone is located in the northeast of Central Iranian Block. The BGC consists of granite, alkaligranite, syenogranite, leucogranite, granophyre, monzogranite, granodiorite, tonalite and diorite that have intruded into the center of Taknar Zone. These intrusive rocks affected by low grade metamorphism. Because of there are no reliable isotope dating data, for the Bornaward Granitoid Complex rocks have been proposed discordant ages (Jurassic, Cretaceous or even younger ages) by many studies. In the present study, new isotopic information based on zircon U-Pb dating has revealed the origin and time of the formation of the BGC. These new results do not confirm previously proposed ages. The results obtained from zircon U-Pb dating of the BGC rocks suggest late-Neoproterozoic (Precambrian) age (540-550 Ma). The Bornaward Granitoid Complex is middle-high metaluminous to lower-middle peraluminous and belongs to tholeiite, calc-alkaline to high-K calc-alkaline rock series with enrichment in LIL (Cs, Rb and Ba, U, K, Zr, Y, Th) and depletion in HIL (Sr and Nb, Ta, Ti) elements. Chondrite-normalized Rare Earth Elements (REE) plots indicate minor enrichment of LREE compared to HREE, and strong negative anomaly of Eu compared to other Rare Earth Elements. Furthermore, initial 87Sr/86Sr and 143Nd/144Nd range from 0.70351 to 0.71689 and 0.511585 to 0.512061, respectively, and initial εNd isotope values for granite, granodiorite and diorite range from -6.73 to 2.52. These all indicate that the BGC has derived from partial melting of distinct basement source regions with very high initial 87Sr/86Sr and undergoing extensive crustal contamination (S-type granite).

  12. Isotopic compositions of Sr in waters and of Pb in sediments and ashes from an urban incinerator using an ICP-MS

    The analytical precision of the Sr and the Pb isotopic compositions of natural samples obtained with a conventional ICP-MS is of 3 to 7 x 10-3 (internal 2 σ) for the 87Sr/86Sr ratio, 6 to 8 x 10-3 for the 206Pb/207Pb and 1 to 4 x 10-1 for the 206Pb/204Pb and 207Pb/204Pb ratios. Such accuracy is obtained with a procedure including a resin-chromatographic purification, a correction with respect to standard values (NBS 987 and 981) and a routine of four determinations for each sample. This procedure should allow rapid geochemical investigations ahead of more precise determinations by thermo-ionization mass spectrometry. (authors). 8 refs., 6 figs., 5 tabs

  13. Genetic relationship between post-caldera and caldera-forming magmas from Aso volcano, SW Japan. Constraints from Sr isotope and trace element compositions

    We analyzed the Sr isotope and trace element compositions of the post-caldera volcanic products of Aso volcano in central Kyushu, with the aim of investigating the genetic relationship between the last caldera-forming (Aso-4) magmas and post-caldera magmas. The 87Sr/86Sr ratio of the magmas drastically changed from the homogeneous (0.7041-0.7042) caldera-forming stage to the heterogeneous (0.7040-0.7044) post-caldera stage. In addition, the obtained geochemical data suggested that the Aso-4 magma did not contribute to the origin and compositional evolution of the post-caldera magmas. These observations indicated that the generation of post-caldera magmas was probably independent of the Aso-4 magma. (author)

  14. Origin of brines, salts and carbonate from shales of the Marcellus Formation: Evidence from geochemical and Sr isotope study of sequentially extracted fluids

    Highlights: • Cuttings from the Marcellus Shale and adjacent units were sequentially leached. • 87Sr/86Sr ratios of extractable Sr are similar to Marcellus produced water values. • Marcellus produced water chemistry is not explained only by water-shale interaction. • Shale leachates record the early geologic history of fluid-shale interaction. • Some Middle Devonian formation water has been isolated since the late Paleozoic. - Abstract: Fluids co-produced with methane from hydraulically fractured organic-rich shales of the Marcellus Formation (USA) are characterized by high total dissolved solids (TDS), including elevated levels of Ba, Sr and Br. To investigate the source and geologic history of these high-TDS fluids and their dissolved constituents, we carried out a series of sequential extraction experiments on dry-drilled cuttings extracted within, below and above the Marcellus Shale from a well in Tioga County, New York State. The experiments were designed to extract (1) water soluble components, (2) exchangeable cations, (3) carbonate minerals, and (4) hydrochloric acid-soluble constituents. The geochemistry of the resultant leachates highlights the different geochemical reservoirs for extractable elements within the shale; notably, Na and Br were largely water-soluble, while Ba was extracted primarily from exchangeable sites, and Ca and Sr were found both in exchangeable sites and carbonate. Strontium isotope ratios measured on the leachates indicate that each of the element reservoirs has a distinct value. Measured 87Sr/86Sr ratios in the water soluble component are similar to those of Marcellus produced water, while the ion exchange reservoir yields lower ratios, and carbonate Sr is lower still, approaching Devonian-Silurian seawater values. Despite the isotopic similarity of water leachates and produced water, the total water chemistry argues against generation of produced water by interaction of hydraulic fracturing fluid with “dry” shale

  15. Astronomically-Forced Lake Expansion and Contraction Cycles: Sr Isotopic Evidence from the Eocene Green River Formation, Western USA

    Baddouh, M.; Meyers, S. R.; Carroll, A.; Beard, B. L.; Johnson, C.

    2014-12-01

    87Sr/86Sr ratio from ancient lake deposits offer a unique insight into the astronomical forcing of lake expansion and contraction, by recording changes in runoff/groundwater provenance. We present new high-resolution 87Sr/86Sr data from the upper Wilkins Peak Member, to investigate linkages between astronomical forcing, water sources, and lake level in a classic rhythmic succession. Fifty-one 87Sr/86Sr ratios from White Mountain core #1 were acquired with a sampling interval of ~30 cm starting from the top of alluvial "I" bed to the lower Laney Member. The 87Sr/86Sr data show a strong and significant negative correlation with oil-yield, a traditional proxy for paleolake level and organic productivity. Application of a radioisotopic time scale, using previously dated ash beds, reveals that both 87Sr/86Sr and oil yield have a strong 20 kyr rhythm. The 87Sr/86Sr data more clearly express a longer period 100 kyr signal, similar to the Laskar 10D eccentricity solution. Using our nominal radioisotopic time scale, the Laskar 10D solution and 87Sr/86Sr data suggest that highest lake levels and greatest organic enrichment are attained during greatest precession and eccentricity. Regional geologic studies and modern river water analyses have shown that less radiogenic waters mostly originate west of the basin, where drainage is strongly influenced by thick Paleozoic and Mesozoic marine carbonate units. Decreased in 87Sr/86Sr therefore imply greater relative water contributions from the Sevier orogenic highlands, relative to lower relief, more radiogenic ranges lying to the east. We therefore propose that highstands of Lake Gosiute record increased penetration of Pacific moisture, related either to increased El Niño frequency or southward displacement of major storm tracks. We hypothesize that the occurrence of wetter winters caused expansion of Lake Gosiute, deposition of organic carbon rich facies, and decreased lake water 87Sr/86Sr.

  16. Systematics of one-quasiparticle configurations in neutron-rich Sr, Zr, and Mo odd isotopes with the Gogny energy density functional

    Rodriguez-Guzman, R.; Sarriguren, Pedro; Robledo, L. M.

    2010-01-01

    The systematics of one-quasiparticle configurations in neutron-rich Sr, Zr, and Mo odd isotopes is studied within the Hartree-Fock-Bogoliubov plus equal filling approximation method preserving both axial and time-reversal symmetries. Calculations based on the Gogny energy density functional with both the standard D1S parametrization and the new D1M incarnation of this functional are included in our analysis. The nuclear deformation and shape coexistence inherent to this mass region are shown ...

  17. Decoupling of the Lu-Hf, Sm-Nd, and Rb-Sr isotope systems in eclogites and a garnetite from the Sulu ultra-high pressure metamorphic terrane: Causes and implications

    Liu, Yung-Hsin; Yang, Huai-Jen; Takazawa, Eiichi; Satish-Kumar, Madhusoodhan; You, Chen-Feng

    2015-10-01

    The whole-rock Hf, Sr and Nd isotope data of five high-Fe-Ti eclogites, nine high-Al eclogites, and a garnetite from the Sulu ultrahigh pressure (UHP) metamorphic terrane at eastern China were analyzed to resolve the causes for the decoupling of the Lu-Hf, Sm-Nd, and Rb-Sr isotope systems in these UHP rocks and to infer their protolith characteristics. Seven of the nine high-Al eclogites define an 87Rb/86Sr-87Sr/86Sr errorchron age of 192 ± 43 Ma (MSWD = 2.8), which is within the time span of retrograde metamorphism despite the large uncertainty. The high-Fe-Ti eclogites and garnetite, however, have low 87Rb/86Sr ratios of eclogites. These arc signatures together with the felsic-mafic bimodal geochemical features of the UHP rocks from the Sulu terrane are explained as the characteristics of protoliths generated by backarc rifting.

  18. Man, nutrition and mobility: A comparison of teeth and bone from the Medieval era and the present from Pb and Sr isotopes

    Naturally occurring isotopic systems, such as strontium (Sr) and lead (Pb), are very useful for characterizing different sources and to produce background information. Norwegian teeth from the Medieval era have 206Pb/204Pb ratios between 18.8 and 18.2, in comparison with present day ratios of between 18.0 and 17.6 showing the impact of Pb from modern industrialization and from traffic. Sr analyses of Medieval teeth show that an individual living in a coastal town on the west coast of Norway can easily be distinguished from one in a rural area at that time. The Sr signature shows that Medieval people lived on local products while present people to a greater degree live on imported or domestic industrially processed food. Medieval and modern teeth from one site give similar Pb signatures and concentrations indicating no increase in pollution over time. However, the impact of industrial pollution can be seen from Pb analyses on contemporary teeth, so that the method can be used to monitor emission of heavy metals from local industry. Whilst the Pb and Sr natural isotopic systems individually provide valuable information, a combination of the two techniques is a very powerful tool in environmental and archaeological research. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

  19. Petrogenesis of the Mesozoic Zijinguan mafic pluton from the Taihang Mountains, North China Craton: Petrological and Os-Nd-Sr isotopic constraints

    Liu, An-Kun; Chen, Bin; Suzuki, Katsuhiko; Liu, Ling

    2010-09-01

    Mantle peridotites show low Re/Os ratios and sub-chondritic 187Os/ 188Os ratios (hornblende pyroxenites, hornblende gabbros and gabbrodiorites. These rocks are enriched in LILE (e.g., Ba and Sr) and LREE, depleted in HFSE (e.g., Nb, Zr). They possess radiogenic Os isotopic compositions with 187Os/ 188Os = 0.187-0.603, and EM1-like Sr-Nd isotopic compositions (I Sr = 0.7058-0.7066, ɛNd( t) = -13.8 to -18.2). Petrography and elemental data suggest a significant fractionation and accumulation of olivine + pyroxene + hornblende in forming the mafic pluton. Clinopyroxene and plagioclase from the gabbrodiorites show complicated compositional zoning, suggesting a process of magma recharge in the late-stage of magma evolution. This is supported by their higher ɛNd( t) values (-14) than the other two rock types (-15 to -18). The parental magmas to the mafic pluton should be hydrous, which originated from an old, enriched lithospheric mantle, and were significantly contaminated by Precambrian mafic lower crust and TTG gneisses during magma evolution, as is suggested by the highly radiogenic Os- and unradiogenic Nd isotopic compositions of the mafic pluton.

  20. Pb, Sr and Nd isotope study of two co-existing magmas in the Nízke Tatry Mountains, Western Carpathians (Slovakia)

    Poller, U.; Kohút, M.; Gaab, A. S.; Todt, W.

    2005-07-01

    Two co-existing plutonic rocks (diorite and granodiorite) were studied from an intrusion of Variscan age in the Raztocna Valley Nízke Tatry Mountains, Western Carpathians. Geochemical analyses of major and trace elements constrain a volcanic arc as emplacement environment and give the first hints of a mixture of two magmatic end-members: the so-called Prasivá granodiorite and the Raztocna diorite. The 87Sr/86Sr(0) ratios vary between 0.7075 and 0.7118, the ɛ Nd(0) values range from -1.4 to -5.0. Common Pb isotopes reveal a dominant crustal source with minor influences from a mantle and a lower crustal source. Modelling based on Sr and Nd isotope data and using three component mixing calculations indicates that mixing of 2/3 of upper mantle material with 1/3 upper crustal material can produce the isotopic composition of the Raztocna diorite. Very minor amounts of lower crust were incorporated in the diorite. For the Prasivá granodiorite, the mixing ratio of upper mantle and upper crust is similar, but a lower crustal reservoir contributed about 5 10% of the source material.

  1. Development of a fully automated open-column chemical-separation system—COLUMNSPIDER—and its application to Sr-Nd-Pb isotope analyses of igneous rock samples

    Miyazaki, Takashi; Vaglarov, Bogdan Stefanov; Takei, Masakazu; Suzuki, Masahiro; Suzuki, Hiroaki; Ohsawa, Kouzou; Chang, Qing; Takahashi, Toshiro; Hirahara, Yuka; Hanyu, Takeshi; Kimura, Jun-Ichi; Tatsumi, Yoshiyuki

    A fully automated open-column resin-bed chemical-separation system, named COLUMNSPIDER, has been developed. The system consists of a programmable micropipetting robot that dispenses chemical reagents and sample solutions into an open-column resin bed for elemental separation. After the initial set up of resin columns, chemical reagents, and beakers for the separated chemical components, all separation procedures are automated. As many as ten samples can be eluted in parallel in a single automated run. Many separation procedures, such as radiogenic isotope ratio analyses for Sr and Nd, involve the use of multiple column separations with different resin columns, chemical reagents, and beakers of various volumes. COLUMNSPIDER completes these separations using multiple runs. Programmable functions, including the positioning of the micropipetter, reagent volume, and elution time, enable flexible operation. Optimized movements for solution take-up and high-efficiency column flushing allow the system to perform as precisely as when carried out manually by a skilled operator. Procedural blanks, examined for COLUMNSPIDER separations of Sr, Nd, and Pb, are low and negligible. The measured Sr, Nd, and Pb isotope ratios for JB-2 and Nd isotope ratios for JB-3 and BCR-2 rock standards all fall within the ranges reported previously in high-accuracy analyses. COLUMNSPIDER is a versatile tool for the efficient elemental separation of igneous rock samples, a process that is both labor intensive and time consuming.

  2. Sr, Nd isotope geochemistry of volcanic rock series and its geological significance in the middle Okinawa Trough

    2000-01-01

    There exists extensive basic-acidic volcanic rock series in the middle section of the Okinawa Trough. Different types of these volcanic rocks have their own average strontium ratios of 0.704 749, 0.705 062, 0.708 771, 0.704 840 and 0.720 301 with average 143Nd/144Nd ratios of 0.512 820, 0.512 673, 0.512 413, 0.512 729 and 0.512 034. These ratios of Sr and Nd isotopes all fall on a theoretic hyperbolic curve of mixing between two end-members of MORB and rhyolitic magma. So we infer that these different kinds of volcanic rocks in the middle Okinawa Trough are the erupted product in different stages of formation and evolution of the trough crust. MORB magma, which had suffered assimilation, mixed with the early-formed crust-derived rhyolitic partial melt mass at different ratios; then, these mixed magma erupted and formed volcanic rock types of the trough. This study indicates that the Okinawa Trough is coming into a stage of submarine spreading from the stage of continental rift.

  3. Sr, Nd isotope geochemistry of volcanic rock series and its geological significance in the middle Okinawa Trough

    孟宪伟; 陈志华; 杜德文; 吴金龙

    2000-01-01

    There exists extensive basic-acidic volcanic rock series in the middle section of the Okinawa Trough. Different types of these volcanic rocks have their own average strontium ratios of 0.704749, 0.705062, 0.708771, 0.704840 and 0.720301 with average 143Nd/144Nd ratios of 0.512 820, 0.512 673, 0.512 413, 0.512 729 and 0.512 034. These ratios of Sr and Nd isotopes all fall on a theoretic hyperbolic curve of mixing between two end-members of MORE and rhyolitic magma. So we infer that these different kinds of volcanic rocks in the middle Okinawa Trough are the erupted product in different stages of formation and evolution of the trough crust. MORE magma, which had suffered assimilation, mixed with the early-formed crust-derived rhyolitic partial melt mass at different ratios; then, these mixed magma erupted and formed volcanic rock types of the trough. This study indicates that the Okinawa Trough is coming into a stage of submarine spreading from the stage of continental rift.

  4. Melt extraction and enrichment processes in the New Caledonia lherzolites: Evidence from geochemical and Sr-Nd isotope data

    Secchiari, Arianna; Montanini, Alessandra; Bosch, Delphine; Macera, Patrizia; Cluzel, Dominique

    2016-09-01

    The New Caledonia ophiolite (Peridotite Nappe) is dominated by mantle lithologies, composed of forearc-related refractory harzburgites and minor lherzolites in both the spinel and plagioclase facies. In this study, a comprehensive geochemical data set (major, trace elements and Sr-Nd isotopes) is used to constrain the mantle evolution of the lherzolites and their relationships with the basalts from the Poya Terrane, which tectonically underlies the mantle rocks. The majority of the lherzolites are low-strain porphyroclastic tectonites. They likely record an asthenospheric origin followed by re-equilibration at lithospheric conditions, as supported by geothermometric estimates (T = 1100-940 °C and 920-890 °C for porphyroclastic and neoblastic spinel-facies assemblages, respectively). Olivine composition (Fo = 88.5-90.0 mol%), spinel Cr# ([molar 100 • Cr/(Cr + Al)] = 13-17) and relatively high amounts (7-8 vol%) of Al2O3- and Na2O-rich clinopyroxene (up to 0.5 and 6.5 wt.%, respectively) indicate a moderately depleted geochemical signature for the spinel lherzolites. Bulk rock and clinopyroxene rare earth elements (REE) patterns display a typical abyssal-type signature, i.e. steeply plunging LREE accompanied by nearly flat HREE to MREE. Clinopyroxene REE compositions of the spinel lherzolites may be reproduced by small amounts of fractional melting of a garnet lherzolite precursor (~ 4%), followed by 4%-5% melting in the spinel peridotite field. The plagioclase lherzolites show melt impregnation microstructures, Cr- and Ti-rich spinels and incompatible trace element enrichments (REE, Ti, Y, and Zr) in bulk rocks and clinopyroxenes. Impregnation modelling for these elements suggests that the plagioclase lherzolites originated from residual spinel lherzolites by entrapment of highly depleted (non-aggregated) MORB melt fractions in the shallow oceanic lithosphere. Nd isotope compositions of the investigated peridotites are consistent with derivation from an

  5. Accurate experimental determination of the isotope effects on the triple point temperature of water. I. Dependence on the 2H abundance

    Faghihi, V.; Peruzzi, A.; Aerts-Bijma, A. T.; Jansen, H. G.; Spriensma, J. J.; van Geel, J.; Meijer, H. A. J.

    2015-12-01

    Variation in the isotopic composition of water is one of the major contributors to uncertainty in the realization of the triple point of water (TPW). Although the dependence of the TPW on the isotopic composition of the water has been known for years, there is still a lack of a detailed and accurate experimental determination of the values for the correction constants. This paper is the first of two articles (Part I and Part II) that address quantification of isotope abundance effects on the triple point temperature of water. In this paper, we describe our experimental assessment of the 2H isotope effect. We manufactured five triple point cells with prepared water mixtures with a range of 2H isotopic abundances encompassing widely the natural abundance range, while the 18O and 17O isotopic abundance were kept approximately constant and the 18O  -  17O ratio was close to the Meijer-Li relationship for natural waters. The selected range of 2H isotopic abundances led to cells that realised TPW temperatures between approximately  -140 μK to  +2500 μK with respect to the TPW temperature as realized by VSMOW (Vienna Standard Mean Ocean Water). Our experiment led to determination of the value for the δ2H correction parameter of A2H  =  673 μK / (‰ deviation of δ2H from VSMOW) with a combined uncertainty of 4 μK (k  =  1, or 1σ).

  6. Multi-Isotopic (o, H, Sr, Li) Tracing of the Fluxes Involved in the Water Status of a Peatland (la Sauvetat, Massif Central, France)

    Agnès, B.; Negrel, P. J.; Millot, R.; Clotilde, B.

    2010-12-01

    The bio-diversity (vegetation and fauna) of peatlands, like all wetlands ecosystems, are strongly fragile as they are requiring very specific wet conditions. In the past 20 years, increasing efforts were engaged to restore degraded wetlands, to create new wetlands where they have been totally lost and to manage wetlands sustainably in order to assess their multiple benefits. However, engaging specific actions to restore and preserve wetlands require an important knowledge on the water cycle in such systems. In this study, we propose to use chemical and multi-isotopic approaches combined with hydrological measurements (piezometric level and stream flow measurements) to trace the fluxes of water and dissolved element involved in the “Narces de la Sauvetat” peatland (France) and for the stream draining the area. Aims are to evaluate the water status of this ecosystem as well as the origin of dissolved elements and possible anthropogenic impacts. These approaches clearly demonstrated their effectiveness to improve the knowledge on the hydrological functioning of wetlands ecosystems. Main results are (1) at least three fluxes with distinct chemical and isotopic signatures are providing water supplies to peatland (Sr and stable isotopes), (2) water flow that comes out of the peatland through the stream is certainly negligible (Li isotopes) and 3) water within the peat land exhibits Sr and Li -isotopes values consistent with carbonate amendments inputs used in local agriculture. The outcomes of this study are that peatland ecosystem water balance is poorly affected by its outlet but are strongly controlled by groundwater replenishment. This could lead to a better adjustment of decision maker choices to maintain the water balance of the peatland, which is essential for the preservation of this fragile ecosystem. This study also opens a new field for Li isotope investigations in hydro-systems and highlights the possibility of using Li isotopes as environmental tracers.

  7. Coral Sr-U thermometry

    DeCarlo, Thomas M.; Gaetani, Glenn A.; Cohen, Anne L.; Foster, Gavin L.; Alpert, Alice E.; Stewart, Joseph A.

    2016-06-01

    Coral skeletons archive past climate variability with unrivaled temporal resolution. However, extraction of accurate temperature information from coral skeletons has been limited by "vital effects," which confound, and sometimes override, the temperature dependence of geochemical proxies. We present a new approach to coral paleothermometry based on results of abiogenic precipitation experiments interpreted within a framework provided by a quantitative model of the coral biomineralization process. DeCarlo et al. (2015a) investigated temperature and carbonate chemistry controls on abiogenic partitioning of Sr/Ca and U/Ca between aragonite and seawater and modeled the sensitivity of skeletal composition to processes occurring at the site of calcification. The model predicts that temperature can be accurately reconstructed from coral skeleton by combining Sr/Ca and U/Ca ratios into a new proxy, which we refer to hereafter as the Sr-U thermometer. Here we test the model predictions with measured Sr/Ca and U/Ca ratios of 14 Porites sp. corals collected from the tropical Pacific Ocean and the Red Sea, with a subset also analyzed using the boron isotope (δ11B) pH proxy. Observed relationships among Sr/Ca, U/Ca, and δ11B agree with model predictions, indicating that the model accounts for the key features of the coral biomineralization process. By calibrating to instrumental temperature records, we show that Sr-U captures 93% of mean annual temperature variability (26-30°C) and has a standard deviation of prediction of 0.5°C, compared to 1°C using Sr/Ca alone. The Sr-U thermometer may offer significantly improved reliability for reconstructing past ocean temperatures from coral skeletons.

  8. Rapid, accurate and precise measurement of the isotopic composition of atmospheric gases: A generalized GC-IRMS solution

    The measurement of the isotopic composition of individual gas species in air is an analytical challenge faced by researchers in many disciplines. The existence of many different types of air (atmospheric air, dissolved air, air bubbles in ice, soil air, growth chamber atmospheres) and the enormous dynamic range of concentrations makes the problem difficult. The recent combination of gas chromatography with isotope ratio mass spectrometry (GC-IRMS) has allowed the solution of many previously difficult or intractable problems of this sort. Interest is divided between analysis of trace gases (CO2, CH4, N2O and CH3Cl) and the major species (N2, O2 and Ar). Recent instrumental developments have allowed us to assemble a generalized GC-IRMS approach capable of high precision isotopic analysis of both trace and major species at natural and enriched abundances, while permitting high throughput automated analysis using sample containers compatible with field collection

  9. Stable isotope labeling by amino acids in cell culture, SILAC, as a simple and accurate approach to expression proteomics

    Ong, S.E.; Blagoev, B.; Kratchmarova, I.;

    2002-01-01

    . Here we describe a method, termed SILAC, for stable isotope labeling by amino acids in cell culture, for the in vivo incorporation of specific amino acids into all mammalian proteins. Mammalian cell lines are grown in media lacking a standard essential amino acid but supplemented with a non......Quantitative proteomics has traditionally been performed by two-dimensional gel electrophoresis, but recently, mass spectrometric methods based on stable isotope quantitation have shown great promise for the simultaneous and automated identification and quantitation of complex protein mixtures......-radioactive, isotopically labeled form of that amino acid, in this case deuterated leucine (Leu-d3). We find that growth of cells maintained in these media is no different from growth in normal media as evidenced by cell morphology, doubling time, and ability to differentiate. Complete incorporation of Leu-d3 occurred...

  10. Source and evolution of the "perfect Asian dust storm" in early April 2001: Implications of the Sr-Nd isotope ratios

    Nakano, Takanori; Nishikawa, Masataka; Mori, Ikuko; Shin, Kicheol; Hosono, Takahiro; Yokoo, Yoriko

    The "perfect Asian dust storm," so-called from the huge, clear picture obtained of it by earth-orbiting satellites, occurred over a vast area of northern China and Mongolia and moved eastward across the northern Pacific in early April 2001. We determined the Sr-Nd isotopic ratios of acid-resistant minerals and the Sr isotopic ratios of weak-acid-soluble minerals in the dust from this storm deposited at nine sites from northern China to Japan and compared these data with those ratios of surface arid soils in northern China. The isotopic compositions of the dust minerals resembled those from soils of the Badain Juran, Tengger, and Ulan Buh deserts and the area to their north, which on meteorological grounds are considered to be the emission area of the dust plume, but they varied regionally, reflecting the heterogeneity of the source soils. Our results and those of other meteorological and modeling studies suggest that this variation was caused by mixing with local soils uplifted into the lower part of the dust plume, but further downwind the dust was less mixed with local soils and was derived mainly from the upper dust plume. Mineral isotope, mineralogical, and elemental data on Asian dusts and soils in northern China and Mongolia provide invaluable information on physical and chemical processes of dust storms and on dust source areas.

  11. Geochemical and C, O, Sr, and U-series isotopic evidence for the meteoric origin of calcrete at Solitario Wash, Crater Flat, Nevada, USA

    Neymark, L. A.; Paces, J. B.; Marshall, B. D.; Peterman, Z. E.; Whelan, J. F.

    2005-08-01

    Calcite-rich soils (calcrete) in alluvium and colluvium at Solitario Wash, Crater Flat, Nevada, USA, contain pedogenic calcite and opaline silica similar to soils present elsewhere in the semi-arid southwestern United States. Nevertheless, a ground-water discharge origin for the Solitario Wash soil deposits was proposed in a series of publications proposing elevation-dependent variations of carbon and oxygen isotopes in calcrete samples. Discharge of ground water in the past would raise the possibility of future flooding in the unsaturated zone at Yucca Mountain, Nevada, site of a proposed high-level nuclear waste repository. New geochemical and carbon, oxygen, strontium, and uranium-series isotopic data disprove the presence of systematic elevation-isotopic composition relations, which are the main justification given for a proposed ground-water discharge origin of the calcrete deposits at Solitario Wash. Values of δ13C (-4.1 to -7.8 per mil [‰]), δ18O (23.8-17.2‰), 87Sr/86Sr (0.71270-0.71146), and initial 234U/238U activity ratios of about 1.6 in the new calcrete samples are within ranges previously observed in pedogenic carbonate deposits at Yucca Mountain and are incompatible with a ground-water origin for the calcrete. Variations in carbon and oxygen isotopes in Solitario Wash calcrete likely are caused by pedogenic deposition from meteoric water under varying Quaternary climatic conditions over hundreds of thousands of years.

  12. In situ determination of U-Pb ages and Sr-Nd-Hf isotopic constraints on the petrogenesis of the Phalaborwa carbonatite Complex, South Africa

    Wu, Fu-Yuan; Yang, Yue-Heng; Li, Qiu-Li; Mitchell, Roger H.; Dawson, J. Barry; Brandl, Günther; Yuhara, Masaki

    2011-11-01

    The Phalaborwa carbonatite Complex, situated in the northeastern part of South Africa, is characterized by copper and zirconium mineralization, and is composed principally of pyroxenites, phoscorite and carbonatite (banded and transgressive). The complex is transected by mafic dykes, and is geographically associated with a satellite syenite and minor granite intrusions. Zircon and baddeleyite U-Pb isotopic age determinations using CAMECA 1280 secondary ion mass spectrometry have shown that the outer pegmatitic pyroxenite at the Loolekop pipe was emplaced at 2060 ± 4 Ma, and the main phoscorite at 2062 ± 2 Ma. Both ages are identical to those of 2060 ± 2 and 2060 ± 1 Ma for the banded and transgressive carbonatites, respectively. The satellite syenite, which forms plug-like bodies outside of the border of the main complex, and the later mafic dyke have “similar” emplacement ages of 2068 ± 17 and 2062 ± 53 Ma, indicating that these intrusions were apparently near-synchronously emplaced. In contrast to other carbonatites, the Phalaborwa Complex is characterized by high initial Sr and low initial Nd and Hf isotopic compositions. In situ isotopic analyses of apatite, calcite, zircon and baddeleyite indicate that the primary magma was derived from an enriched mantle. As the complex was emplaced slightly earlier at ~ 2060 Ma than the nearby mafic phase of the Bushveld Complex (~ 2055 Ma), it is proposed that the Phalaborwa carbonatite magmatism was triggered by the same mantle plume activity, which partially melted the overlying lithospheric mantle. This contribution also highlights that isotopic studies used to constrain the genesis of ancient igneous complexes should concentrate on minerals with low parent/daughter elemental ratios, such as apatite and calcite for Sr isotopes, and zircon and baddeleyite for Hf isotopes.

  13. Geochemistry and Nd Sr isotopic studies of Late Mesozoic granitoids in the southeastern Hubei Province, Middle Lower Yangtze River belt, Eastern China: Petrogenesis and tectonic setting

    Xie, Guiqing; Mao, Jingwen; Li, Ruiling; Bierlein, Frank P.

    2008-08-01

    A geochemical and isotopic study was carried out for the Mesozoic Yangxin, Tieshan and Echeng granitoid batholiths in the southeastern Hubei Province, eastern China, in order to constrain their petrogenesis and tectonic setting. These granitoids dominantly consist of quartz diorite, monzonite and granite. They are characterized by SiO 2 and Na 2O compositions of between 54.6 and 76.6 wt.%, and 2.9 to 5.6 wt.%, respectively, enrichment in light rare earth elements (LREE) and large ion lithophile elements (LILE), and relative depletion in Y (concentrations ranging from 5.17 to 29.3 ppm) and Yb (0.34-2.83 ppm), with the majority of the granitoids being geochemically similar to high-SiO 2 adakites (HSA). Their initial Nd ( ɛNd = - 12.5 to - 6.1) and Sr (( 87Sr/ 86Sr) i = 0.7054-0.7085) isotopic compositions, however, distinguish them from adakites produced by partial melting of subducted slab and those produced by partial melting of the lower crust of the Yangtze Craton in the Late Mesozoic. The granitoid batholiths in the southeastern Hubei Province exhibit very low MgO ranging from 0.09 to 2.19 wt.% with an average of 0.96 wt.%, and large variations in negative to positive Eu anomalies (Eu/Eu * = 0.22-1.4), especially the Tieshan granites and Yangxin granite porphyry (Eu/Eu * = 0.22-0.73). Geochemical and Nd-Sr isotopic data demonstrate that these granitoids originated as partial melts of an enriched mantle source that experienced significant contamination of lower crust materials and fractional crystallization during magma ascent. Late Mesozoic granitoids in the southeastern Hubei Province of the Middle-Lower Yangtze River belt were dominantly emplaced in an extensional tectonic regime, in response to basaltic underplating, which was followed by lithospheric thinning during the early Cretaceous.

  14. Sr-Nd isotope geochemistry and tectonomagmatic setting of the Dehsalm Cu-Mo porphyry mineralizing intrusives from Lut Block, eastern Iran

    Arjmandzadeh, R.; Santos, J. F.

    2014-01-01

    The Dehsalm Cu-Mo-bearing porphyritic granitoids belong to the Lut Block volcanic-plutonic belt (central eastern Iran). These rocks range in composition from gabbro-diorite to granite, with dominance of monzonites and quartz monzonites, and have geochemical features of high-K calc-alkaline to shoshonitic volcanic arc suites. Primitive mantle-normalized trace element spider diagrams display strong enrichment in large-ion lithophile elements such as Rb, Ba and Cs and depletions in some high-field strength elements, e.g., Nb, Ti, Y and HREE. Chondrite-normalized plots display significant LREE enrichments, high LaN/YbN and a lack of Eu anomaly. High Sr/Y and La/Yb ratios of Dehsalm intrusives reveal that, despite their K-rich composition, these granitoids show some resemblances with adakitic rocks. A Rb-Sr whole rock-feldspar-biotite age of 33 ± 1 Ma was obtained in a quartz monzonite sample and coincides, within error, with a previous geochronological result in Chah-Shaljami granitoids, further northwest within the Lut Block. (87Sr/86Sr)i and ɛNdi isotopic ratios range from 0.70481 to 0.70508 and from +1.5 to +2.5, respectively, which fits into a supra-subduction mantle wedge source for the parental melts and indicates that crustal contribution for magma diversification was of limited importance. Sr and Nd isotopic compositions together with major and trace element geochemistry point to an origin of the parental magmas by melting of a metasomatized mantle source, with phlogopite breakdown playing a significant role in the geochemical fingerprints of the parental magmas; small amounts of residual garnet in the mantle source also help to explain some trace element patterns. Geochemical features of Dehsalm porphyries and its association with Cu-Mo mineralization agree with a mature continental arc setting related to the convergence of Afghan and Lut plates during Oligocene.

  15. Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies

    The French Atomic Energy Commission has carried out several experiments including the mini-INCA (INcineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in 248Cm (∼97 %) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides formations ranged from 0.3% to 1.3%. This uncertainties range is quite acceptable for the nuclear data to be used in transmutation studies.

  16. Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in Cm-248 samples for transmutation studies

    The French Atomic Energy Commission has carried out several experiments including the mini-INCA (Incineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in 248Cm (similar to 97%) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides' formations ranged from 0. 3% to 1. 3%. This uncertainties' range is quite acceptable for the nuclear data to be used in transmutation studies. (authors)

  17. Elemental geochemistry and Sr-Nd isotopic fingerprinting of sediments in monsoon dominated river systems along the west coast of India.

    Pradhan, S. U.; Zhang, J.; Baskaran, M. M.; Shirodkar, P.; Wu, Y.

    2014-12-01

    Strontium-Neodymium isotopes have been widely utilized as provenance tracers of major global river basins. Using HR-ICPMS (elements) and MC-ICPMS (isotopes), we measured a suite of trace elements, 87Sr/86Sr and 143Nd/144Nd isotopic ratios from silicate (Si) and carbonate (CO32-) fractions of 37 bottom sediment samples during 3 seasons along a transect from the estuary upstream in Narmada (ND) and Netravati (NT), the two large rivers along the west coast of India, discharge into the Arabian Sea. Strontium isotopic values ranged from 0.70910 to 0.71778 (NR CO32-), 0.71014 to 0.72427 (NT CO32-) and 0.71085 to 0.72825 (NR Si), and 0.71025 to 0.73349 (NT Si). The ɛNd(0) values ranged from -22.1 to -0.8 (NR CO32-), and -32.2 to -24.3 (NT, CO32-), and -23.7 to -6.2 (NR Si) and -37.4 to -21.2 (NT Si). Variable extents of seasonal and spatial variations on the isotopic compositions of Sr and Nd (both in CO32- and Si fractions), were observed in both rivers. A comparison of the 'model age' of the sediments calculated from the time-depleted-mantle (TDM) model using the concentrations of Nd and Sm and isotopic composition of Nd indicate the following: i) For NT, the TDM-based 'model age', 2.8 to 3.3 Ga, agrees with the age of Peninsular Gneiss, an older gneissic complex (3.2-3.4 Ga) found in this watershed; ii) For NR, there is discordance between the TDM-based 'model age' (1.3-2.4 Ga) and the age of the rocks in this watershed (Deccan basalt, ~65 Ma). We attribute this discordance to mixing of older material from the Precambrian rocks derived by weathering at the head waters of NR. From the observed differences in the Sr isotopes in the main stream and tributaries, we estimate that ~90% of the sediments are derived from main stream and ~10% is derived from tributaries using binary mixing equation in NT and additional sediment source(s) in NR. The Sr isotopic signatures of carbonate fractions in both rivers are close to the global average modern seawater (0.7092) and river

  18. Kinetics of the Reaction of the Heaviest Hydrogen Atom with H2, the 4Heμ + H2 -> 4HeμΗ + H Reaction: Experiments, Accurate Quantal Calculations, and Variational Transition State Theory, including Kinetic Isotope Effects for a Factor of 36.1 in Isotopic Mass

    Fleming, Donald G.; Arseneau, Donald J.; Sukhorukov, Oleksandr; Brewer, Jess H.; Mielke, Steven L.; Truhlar, Donald G.; Schatz, George C.; Garrett, Bruce C.; Peterson, Kirk A.

    2011-11-14

    The neutral muonic helium atom {sup 4}He{mu}, in which one of the electrons of He is replaced by a negative muon, may be effectively regarded as the heaviest isotope of the hydrogen atom, with a mass of 4.115 amu. We report details of the first muon spin rotation ({mu}SR) measurements of the chemical reaction rate constant of {sup 4}He{mu} with molecular hydrogen, {sup 4}He{mu} + H{sub 2} {yields} {sup 4}He{mu}H + H, at temperatures of 295.5, 405, and 500 K, as well as a {mu}SR measurement of the hyperfine coupling constant of muonic He at high pressures. The experimental rate constants, k{sub He{mu}}, are compared with the predictions of accurate quantum mechanical (QM) dynamics calculations carried out on a well converged Born-Huang (BH) potential energy surface, based on complete configuration interaction calculations and including a Born-Oppenheimer diagonal correction. At the two highest measured temperatures the agreement between the quantum theory and experiment is good to excellent, well within experimental uncertainties that include an estimate of possible systematic error, but at 295.5 K the quantum calculations for k{sub He{mu}} are below the experimental value by 2.1 times the experimental uncertainty estimates. Possible reasons for this discrepancy are discussed. Variational transition state theory calculations with multidimensional tunneling have also been carried out for k{sub He{mu}} on the BH surface, and they agree with the accurate QM rate constants to within 30% over a wider temperature range of 200-1000 K. Comparisons between theory and experiment are also presented for the rate constants for both the D + H{sub 2} and Mu + H{sub 2} reactions in a novel study of kinetic isotope effects for the H + H{sub 2} reactions over a factor of 36.1 in isotopic mass of the atomic reactant.

  19. Major element, REE, and Pb, Nd and Sr isotopic geochemistry of Cenozoic volcanic rocks of eastern China: implications for their origin from suboceanic-type mantle reservoirs

    Basu, A.R.; Wang, Junwen; Huang, Wankang; Xie, Guanghong; Tatsumoto, M.

    1991-01-01

    Major- and rare-earth-element (REE) concentrations and UThPb, SmNd, and RbSr isotope systematics are reported for Cenozoic volcanic rocks from northeastern and eastern China. These volcanic rocks, characteristically lacking the calc-alkaline suite of orogenic belts, were emplaced in a rift system which formed in response to the subduction of the western Pacific plate beneath the eastern Asiatic continental margin. The rocks sampled range from basanite and alkali olivine basalt, through olivine tholeiite and quartz tholeiite, to potassic basalts, alkali trachytes, pantellerite, and limburgite. These rock suites represent the volcanic centers of Datong, Hanobar, Kuandian, Changbaishan and Wudalianchi in northeastern China, and Mingxi in the Fujian Province of eastern China. The major-element and REE geochemistry is characteristic of each volcanic suite broadly evolving through cogenetic magmatic processes. Some of the outstanding features of the isotopic correlation arrays are as follows: (1) NdSr shows an anticorrelation within the field of ocean island basalts, extending from the MORB end-member to an enriched, time-averaged high Rb Sr and Nd Sr end-member (EM1), (2) SrPb also shows an anticorrelation, similar to that of Hawaiian and walvis Ridge basalts, (3) NdPb shows a positive correlation, and (4) the 207Pb 204Pb vs 206Pb 204Pb plot shows linear arrays parallel to the general trend (NHRL) for MORB on both sides of the geochron, although in the 208Pb 204Pb vs 206Pb 204Pb plot the linear array is significantly displaced above the NHRL in a pattern similar to that of the oceanic island basalts that show the Dupal signatures. In all isotope correlation patterns, the data arrays define two different mantle components-a MORB-like component and an enriched mantle component. The isotopic data presented here clearly demonstrate the existence of Dupal compositions in the sources of the continental volcanic rocks of eastern China. We suggest that the subcontinental mantle

  20. Sources of granite magmatism in the Embu Terrane (Ribeira Belt, Brazil): Neoproterozoic crust recycling constrained by elemental and isotope (Sr-Nd-Pb) geochemistry

    Alves, Adriana; Janasi, Valdecir de Assis; Campos Neto, Mario da Costa

    2016-07-01

    Whole rock elemental and Sr-Nd isotope geochemistry and in situ K-feldspar Pb isotope geochemistry were used to identify the sources involved in the genesis of Neoproterozoic granites from the Embu Terrane, Ribeira Belt, SE Brazil. Granite magmatism spanned over 200 Ma (810-580 Ma), and is dominated by crust-derived relatively low-T (850-750 °C, zircon saturation) biotite granites to biotite-muscovite granites. Two Cryogenian plutons show the least negative εNdt (-8 to -10) and highest mg# (30-40) of the whole set. Their compositions are strongly contrasted, implying distinct sources for the peraluminous (ASI ∼ 1.2) ∼660 Ma Serra do Quebra-Cangalha batholith (metasedimentary rocks from relatively young upper crust with high Rb/Sr and low Th/U) and the metaluminous (ASI = 0.96-1.00) ∼ 630 Ma Santa Catarina Granite. Although not typical, the geochemical signature of these granites may reflect a continental margin arc environment, and they could be products of a prolonged period of oceanic plate consumption started at ∼810 Ma. The predominant Ediacaran (595-580 Ma) plutons have a spread of compositions from biotite granites with SiO2 as low as ∼65% (e.g., Itapeti, Mauá, Sabaúna and Lagoinha granites) to fractionated muscovite granites (Mogi das Cruzes, Santa Branca and Guacuri granites; up to ∼75% SiO2). εNdT are characteristically negative (-12 to -18), with corresponding Nd TDM indicating sources with Paleoproterozoic mean crustal ages (2.0-2.5 Ga). The Guacuri and Santa Branca muscovite granites have the more negative εNdt, highest 87Sr/86Srt (0.714-0.717) and lowest 208Pb/206Pb and 207Pb/206Pb, consistent with an old metasedimentary source with low time-integrated Rb/Sr. However, a positive Nd-Sr isotope correlation is suggested by data from the other granites, and would be consistent with mixing between an older source predominant in the Mauá granite and a younger, high Rb/Sr source that is more abundant in the Lagoinha granite sample. The

  1. A late Miocene-early Pliocene chain of lakes fed by the Colorado River: Evidence from Sr, C, and O isotopes of the Bouse Formation and related units between Grand Canyon and the Gulf of California

    Roskowski, J.A.; Patchett, P.J.; Spencer, J.E.; Pearthree, P.A.; Dettman, D.L.; Faulds, J.E.; Reynolds, A.C.

    2010-01-01

    We report strontium isotopic results for the late Miocene Hualapai Limestone of the Lake Mead area (Arizona-Nevada) and the latest Miocene to early Pliocene Bouse Formation and related units of the lower Colorado River trough (Arizona-California-Nevada), together with parallel oxygen and carbon isotopic analyses of Bouse samples, to constrain the lake-overflow model for integration of the Colorado River. Sr iso topic analyses on the basal 1-5 cm of marl, in particular along a transect over a range of altitude in the lowest-altitude basin that contains freshwater, brackish, and marine fossils, document the 87Sr/86Sr of first-arriving Bouse waters. Results reinforce the similarity between the 87Sr/86Sr of Bouse Formation carbonates and present-day Colorado River water, and the systematic distinction of these values from Neogene marine Sr. Basal Bouse samples show that 87Sr/86Sr decreased from 0.7111 to values in the range 0.7107-0.7109 during early basin filling. 87Sr/86Sr values from a recently identified marl in the Las Vegas area are within the range of Bouse Sr ratios. 87Sr/86Sr values from the Hualapai Limestone decrease upsection from 0.7195 to 0.7137, in the approach to a time soon after 6 Ma when Hualapai deposition ceased and the Colorado River became established through the Lake Mead area. Bouse Formation ??18O values range from -12.9??? to +1.0??? Vienna Pee Dee belemnite (VPDB), and ??13C between -6.5??? and +3.4??? VPDB. Negative ??18O values appear to require a continental origin for waters, and the trend to higher ??18O suggests evaporation in lake waters. Sr and stable isotopic results for sectioned barnacle shells and from bedding planes of the marine fish fossil Colpichthys regis demonstrate that these animals lived in saline freshwater, and that there is no evidence for incursions of marine water, either long-lived or brief in duration. Lack of correlation of Sr and O isotopic variations in the same samples also argue strongly against systematic

  2. Precise and accurate isotopic analysis of microscopic uranium-oxide grains using LA-MC-ICP-MS

    Lloyd, Nicholas S.; Parrish, Randall R.; Horstwood, Matthew S.A.; Chenery, Simon R.N.

    2009-01-01

    Uranium isotope (235U, 236U, 238U) ratios were determined for microscopic uranium-oxide grains using laser-ablation multi-collector inductively-coupled-plasma mass-spectrometry (LA-MC-ICP-MS). The grains were retrieved from contaminated soil and dust samples. The analytical technique utilised is rapid, requires minimal sample preparation, and is well suited for nuclear forensic applications. Precision and accuracy were assessed by replicate analyses of natural uraninite grains: relative uncer...

  3. Isotopic Systematics (U, nitrate and Sr) of the F-Area Acidic Contamination Plume at the Savannah River Site: Clues to Contaminant History and Mobility

    Christensen, J. N.; Conrad, M. E.; Bill, M.; Denham, M.; Wan, J.; Rakshit, S.; Stringfellow, W. T.; Spycher, N.

    2010-12-01

    Seepage basins in the F-Area of the Savannah River Site were used from 1955 to 1989 for the disposal of low-level radioactive acidic (ave. pH ˜2.9) waste solutions from site operations involving irradiated uranium billets and other materials used in the production of radionuclides. These disposal activities resulted in a persistent acidic groundwater plume (pH as low as 3.2) beneath the F-Area including contaminants such as tritium, nitrate, 90Sr, 129I and uranium and that has impinged on surface water (Four Mile Branch) about 600 m from the basins. After cessation of disposal in 1989, the basins were capped in 1991. Since that time, remediation has consisted of a pump-and-treat system that has recently been replaced with in situ treatment using a funnel-and-gate system with injection of alkaline solutions in the gates to neutralize pH. In order to delineate the history of contamination and the current mobility and fate of contaminants in F-Area groundwater, we have undertaken a study of variations in the isotopic compositions of U (234U/238U, 235U/238U, 236U/238U), Sr (87Sr/86Sr) and nitrate (δ15N, δ18O) within the contaminant plume. This data can be used to trace U transport within the plume, evaluate chemical changes of nitrate, and potentially track plume/sediment chemical interaction and trace the migration of 90Sr. We have analyzed a suite of groundwater samples from monitoring wells, as well as pore-water samples extracted from aquifer sediment cores to map out the isotopic variation within the plume. The isotopic compositions of U from well samples and porewater samples are all consistent with the variable burn-up of depleted U. The variation in U isotopic composition requires at least three different endmembers, without any significant influence of background natural U. The δ15N and δ18O of nitrate from F-Area plume groundwater are distinct both from natural and unaltered synthetic nitrate, and likely represents fractionation due to waste volume

  4. Accurate experimental determination of the isotope effects on the triple point temperature of water. II. Combined dependence on the 18O and 17O abundances

    Faghihi, V.; Kozicki, M.; Aerts-Bijma, A. T.; Jansen, H. G.; Spriensma, J. J.; Peruzzi, A.; Meijer, H. A. J.

    2015-12-01

    This paper is the second of two articles on the quantification of isotope effects on the triple point temperature of water. In this second article, we address the combined effects of 18O and 17O isotopes. We manufactured five triple point cells with waters with 18O and 17O abundances exceeding widely the natural abundance range while maintaining their natural 18O/17O relationship. The 2H isotopic abundance was kept close to that of VSMOW (Vienna Standard Mean Ocean Water). These cells realized triple point temperatures ranging between  -220 μK to 1420 μK with respect to the temperature realized by a triple point cell filled with VSMOW. Our experiment allowed us to determine an accurate and reliable value for the newly defined combined 18, 17O correction parameter of AO  =  630 μK with a combined uncertainty of 10 μK. To apply this correction, only the 18O abundance of the TPW needs to be known (and the water needs to be of natural origin). Using the results of our two articles, we recommend a correction equation along with the coefficient values for isotopic compositions differing from that of VSMOW and compare the effect of this new equation on a number of triple point cells from the literature and from our own institute. Using our correction equation, the uncertainty in the isotope correction for triple point cell waters used around the world will be  <1 μK.

  5. Pb, Sr and Nd isotopic compositions of a suite of Late Archean, igneous rocks, eastern Beartooth Mountains: Implications for crust-mantle evolution

    A series of compositionally diverse, Late Archean rocks (2.74-2.79 Ga old) from the eastern Beartooth Mountains, Montana and Wyoming, U.S.A., have the same initial Pb, Sr, and Nd isotopic ratios. Lead and Sr initial ratios are higher and Nd initial ratios lower than would be expected for rocks derived from model mantle sources and strongly indicate the involvement of an older crustal reservoir in the genesis of these rocks. Crustal contamination during emplacement can be ruled out for a variety of reasons. Instead a model involving subduction of continental detritus and contamination of the overlying mantle as is often proposed for modern subduction environments is preferred. This contaminated mantle would have all the isotopic characteristics of mantle enriched by internal mantle metasomatism but would require no long-term growth or changes in parent to daughter element ratios. This contaminated mantle would make a good source for some of the Cenozoic mafic volcanics of the Columbia River, Snake River Plain, and Yellowstone volcanic fields that are proposed to come from ancient, enriched lithospheric mantle. The isotopic characteristics of the 2.70 Ga old Stillwater Complex are a perfect match for the proposed contaminated mantle which provides an alternative to crustal contamination during emplacement. The Pb isotopic characteristics of the Late Archean rocks of the eastern Beartooth Mountains are similar to those of other Late Archean rocks of the Wyoming Province and suggest that Early Archean, upper crustal rocks were common in this terrane. The isotopic signatures of Late Archean rocks in the Wyoming Province and distinctive from those of other Archean cratons in North America which are dominated by a MORB-like, Archean mantle source (Superior Province) and/or a long-term depleted crustal source (Greenland). (orig.)

  6. First K-Ar-data and Sr-isotopic composition of explosion pipe basanites of Chulimo-Yenisei depression

    The first data of K-Ar-determination of age and value of 87Sr/86Sr ratio in basanites of volcanic pipes of Chulimo-Yenisei depression are presented. The data testify to the formation of volcanic pipes in Paleogene beginning from the boundary with the upper Creataceous period and up to Oligocene inclusively (71-28 millions of years), in this case the maximum in diameter formation falls within Paleocene. 87Sr/86Sr ratio in basanites changes within narrow limits - from 0.7030 to 0.7036, underlining the closeness of formation conditions during 40 millions of years

  7. Geochemistry and Sr-Nd isotopic compositions of mantle xenoliths from the Monte Vulture carbonatite-melilitite volcano, central southern Italy

    Downes, H.; Kostoula, T.; Jones, A. P.; Beard, A. D.; Thirlwall, M. F.; Bodinier, J.-L.

    2002-08-01

    Spinel peridotite xenoliths found in the Monte Vulture carbonatite-melilitite volcano have been derived from the subcontinental lithospheric mantle beneath central southern Italy. Clinopyroxene-poor lherzolites and harzburgites are the most common rock types, with subordinate wehrlites and dunites. Small quantities of phlogopite and carbonate are present in a few samples. The peridotites record a large degree of partial melting and have experienced subsequent enrichment which has increased their LILE and LREE contents, but in most cases their HFSE contents are low. Despite being carried to the surface by a carbonatite-melilitite host, the whole-rock and clinopyroxene compositions of the xenoliths have a trace-element signature more closely resembling that of silicate-melt metasomatised mantle rather than carbonatite-metasomatised peridotites. 87Sr/86Sr and 143Nd/144Nd isotopic ratios for clinopyroxene from the Vulture peridotites are 0.7042-0.7058 and 0.51260-0.5131 respectively. They form a trend away from the depleted mantle to the composition of the host magmas, and show a significant enrichment in 87Sr/86Sr compared with most European mantle samples. The mantle beneath Monte Vulture has had a complex evolution - we propose that the lithosphere had already undergone extensive partial melting before being affected by metasomatism from a silicate melt which may have been subduction-related.

  8. Phase equilibria constraints on liquid lines of descent generated by paired assimilation and fractional crystallization: Trace elements and Sr and Nd isotopes

    Utilizing a phase equilibria based trace element isotope model for low pressure igneous differentiation, it is now possible to update the methods presently being used to evaluate the effect of assimilation and fractional crystallization (AFC) processes. The results of the calculations presented here indicate that bulk partition coefficients (D) for Sr and Nd are strongly dependent on the chemistry of the assimilants will increase bulk D for network-modifying cations because of the positive correlation of most trace element partition coefficients with reciprocal temperature, and the amount of network forming components in the melt. In addition to the effect of temperature and melt composition, the addition of a magma of different composition from the magma chamber will generally cause a change in the fractionating mineral proportions. For example, a peraluminous assimilant will increase the proportion of plagioclase, and a peralkaline assimilant will increase the proportion of augite. This will in turn have an effect on bulk D. For most multiply saturated mafic to intermediate systems differentiating at low pressure, bulk DSr is >1, and bulk DNd is Sr away from 1 and a peralkaline assimilant drives bulk DNd toward 1. Compared to the results derived in this study, existing models using fixed bulk Ds calculated from closed system conditions will generate results that underestimate the assimilation rate, 87/86Sr and bulk Sr content for a peraluminous assimilant, and over-estimate the assimilation rate, 143/144Nd and Nd content of the assimilant for a peralkaline assimilant

  9. A combined Sm-Nd, Rb-Sr, and U-Pb isotopic study of Mg-suite norite 78238: Further evidence for early differentiation of the Moon

    Edmunson, J; E.Borg, L; Nyquist, L E; Asmerom, Y

    2008-11-17

    Lunar Mg-suite norite 78238 was dated using the Sm-Nd, Rb-Sr, and U-Pb isotopic systems in order to constrain the age of lunar magma ocean solidification and the beginning of Mg-suite magmatism, as well as to provide a direct comparison between the three isotopic systems. The Sm-Nd isotopic system yields a crystallization age for 78238 of 4334 {+-} 37 Ma and an initial {var_epsilon}{sub Nd}{sup 143} value of -0.27 {+-} 0.74. The age-initial {var_epsilon}{sub Nd}{sup 143} (T-I) systematics of a variety of KREEP-rich samples, including 78238 and other Mg-suite rocks, KREEP basalts, and olivine cumulate NWA 773, suggest that lunar differentiation was completed by 4492 {+-} 61 Ma assuming a Chondritic Uniform Reservoir bulk composition for the Moon. The Rb-Sr isotopic systematics of 78238 were disturbed by post-crystallization processes. Nevertheless, selected data points yield two Rb-Sr isochrons. One is concordant with the Sm-Nd crystallization age, 4366 {+-} 53 Ma. The other is 4003 {+-} 95 Ma and is concordant with an Ar-Ar age for 78236. The {sup 207}Pb-{sup 206}Pb age of 4333 {+-} 59 Ma is concordant with the Sm-Nd age. The U-Pb isotopic systematics of 78238 yield linear arrays equivalent to younger ages than the Pb-Pb system, and may reflect fractionation of U and Pb during sample handling. Despite the disturbed nature of the U-Pb systems, a time-averaged {mu} ({sup 238}U/{sup 204}Pb) value of the source can be estimated at 27 {+-} 30 from the Pb-Pb isotopic systematics. Because KREEP-rich samples are likely to be derived from source regions with the highest U/Pb ratios, the relatively low {mu} value calculated for the 78238 source suggests the bulk Moon does not have an exceedingly high {mu} value.

  10. Inferences on sediment provenance and source weathering using major, trace and Sr-Nd isotopic compositional variations in alluvial sediments from Sirhind, Punjab, India

    Paul, D.; Amir, M.; Sinha, R.; Singh, A.; Balakrishnan, S.

    2013-12-01

    Variations in major oxides and selected trace element concentrations, and Sr and Nd isotope ratios in sediments from two ~45m long cores drilled on the trace of a paleochannel near Sirhind, Sutlej plains, are used to characterize sediment provenance and source weathering vis-à-vis climate change. Drill core lithostratigraphy shows slit/clay layers down to a depth of 4m, and coarse to fine channel-sand bodies between ~4 and ~45m, occasionally interspersed by thin slity-clay layers. OSL ages of three samples constrain an age of 15.8 Ka at ~10m depth, corresponding to post Last Glacial Maximum (LGM) period. Major elemental abundances in de-carbonated bulk sediments (44 samples) fall within the range of surface sediments of present-day rivers sourced in the Himalayas. Strong positive correlations (R2>0.8) of Al2O3 (8.7-19.3 wt%) with K2O (2.23-4.03), MgO (0.49-2.72), Fe2O3 (0.89-7.21) and TiO2 (0.35-0.95), and negative correlation (R2=0.95) with SiO2 (62.5-83.7 wt%) are observed. Fe2O3/K2O ratio in these sediments suggest that sands are chemically immature and dominantly arkosic. A-CN-K plot reveals a weathering trend towards illite running parallel to the A-CN line, indicating weak to moderate weathering at source; similar conclusion is drawn from the chemical index of alternation (CIA) values ranging between 54 and 79. The Cr/Th ratios as well as the La-Th-Sc ternary plot suggest that sediments are dominantly derived from granitic to granodioritic sources. The radiogenic Sr-Nd isotopic composition in 18 samples from one drill-core shows range of values (87Sr/86Sr: 0.7409-0.7946; ɛNd: -23.2 to -15) similar to those of silicate rocks from the Higher and Lesser Himalaya, and the down-core variation pattern is similar to that reported for the Ganga-Yamuna interfluve sediments of similar age1. Down-core variations in 87Sr/86Sr and ɛNd reflect mixing of varying proportions of Higher and Lesser Himalayan sediments, the two dominant sources to the core site. Holocene

  11. Onset of collectivity in neutron-rich Sr and Kr isotopes: Prompt spectroscopy after Coulomb excitation at REX-ISOLDE, CERN

    Clément E.

    2013-12-01

    Full Text Available A rapid onset of quadrupole deformation is known to occur around the neutron number 60 in the neutron-rich Zr and Sr isotopes. This shape change has made the neutron-rich A = 100 region an active area of experimental and theoretical studies for many decades now. We report in this contribution new experimental results in the neutron rich 96,98Sr investigated by safe Coulomb excitation of radioactive beams at the REX-ISOLDE facility, CERN. Reduced transition probabilities and spectroscopic quadrupole moments have been extracted from the differential Coulomb excitation cross section supporting the scenario of shape coexistence/change at N = 60. Future perspectives are presented including the recent experimental campaign performed at ILL-Grenoble.

  12. Elemental and Sr Nd Pb isotopic geochemistry of Late Paleozoic volcanic rocks beneath the Junggar basin, NW China: Implications for the formation and evolution of the basin basement

    Zheng, Jianping; Sun, Min; Zhao, Guochun; Robinson, Paul T.; Wang, Fangzheng

    2007-03-01

    The basement beneath the Junggar basin has been interpreted either as a micro-continent of Precambrian age or as a fragment of Paleozoic oceanic crust. Elemental and Sr-Nd-Pb isotopic compositions and zircon Pb-Pb ages of volcanic rocks from drill cores through the paleo-weathered crust show that the basement is composed mainly of late Paleozoic volcanic rock with minor shale and tuff. The volcanic rocks are mostly subalkaline with some minor low-K rocks in the western Kexia area. Some alkaline lavas occur in the central Luliang uplift and northeastern Wulungu depression. The lavas range in composition from basalts to rhyolites and fractional crystallization played an important role in magma evolution. Except for a few samples from Kexia, the basalts have low La/Nb (<1.4), typical for oceanic crust derived from asthenospheric melts. Zircon Pb-Pb ages indicate that the Kexia andesite, with a volcanic arc affinity, formed in the early Carboniferous (345 Ma), whereas the Luliang rhyolite and the Wucaiwan dacite, with syn-collisional to within-plate affinities, formed in the early Devonian (395 and 405 Ma, respectively). Positive ɛNd( t) values (up to +7.4) and low initial 87Sr/ 86Sr isotopic ratios of the intermediate-silicic rocks suggest that the entire Junggar terrain may be underlain by oceanic crust, an interpretation consistent with the juvenile isotopic signatures of many granitoid plutons in other parts of the Central Asia Orogenic Belt. Variation in zircon ages for the silicic rocks, different Ba, P, Ti, Nb or Th anomalies in the mafic rocks, and variable Nb/Y and La/Nb ratios across the basin, suggest that the basement is compositionally heterogeneous. The heterogeneity is believed to reflect amalgamation of different oceanic blocks representing either different evolution stages within a single terrane or possibly derivation from different terranes.

  13. A petrologic, geochemical and Sr-Nd isotopic study on contact metamorphism and degassing of Devonian evaporites in the Norilsk aureoles, Siberia

    Pang, Kwan-Nang; Arndt, Nicholas; Svensen, Henrik; Planke, Sverre; Polozov, Alexander; Polteau, Stephane; Iizuka, Yoshiyuki; Chung, Sun-Lin

    2013-04-01

    Devonian evaporites and associated sedimentary rocks in the Norilsk region were contact metamorphosed during emplacement of mafic sills that form part of the end-Permian (~252 Ma) Siberian Traps. We present mineralogical, geochemical and Sr-Nd isotopic data on sedimentary rocks unaffected by metamorphism, and meta-sedimentary rocks from selected contact aureoles at Norilsk, to examine the mechanisms responsible for magma-evaporite interaction and its relation to the end-Permian environmental crisis. The sedimentary rocks include massive anhydrite, rock salt, dolostone, calcareous siltstones and shale, and the meta-sedimentary rocks comprise calcareous hornfels, siliceous hornfels and minor meta-anhydrite and meta-sandstone. Contact metamorphism took place at low pressure and at maximum temperatures corresponding to the phlogopite-diopside stability field. Calcareous hornfels have high CaO, MgO, CΟ2, SΟ3, low SiO2 and initial Sr isotopic ratios of 0.7079-0.7092, features indicative of calcareous siltstone protoliths. Siliceous hornfels, in contrast, have high SiO2, Al2O3, Na2O, low in other major element oxides and initial Sr isotopic ratios of 0.7083-0.7152, consistent with pelitic or shaley protoliths. Loss of CO2 in a subset of calcareous hornfels can be explained by decarbonation reactions during metamorphism, but release of SO2 from evaporites cannot be accounted for by a similar mechanism. Occurrences of wollastonite and a variety of hydrous minerals in the calcareous hornfels are consistent with equilibration with hydrous fluid, which was capable of leaching large quantities of anhydrite in the presence of dissolved NaCl. In this way, substantial sediment-derived sulfur could have been mobilized, incorporated into the magmatic system and released to the atmosphere. The release of CO2 and SO2 from Siberian evaporites added to the variety of toxic gases generated during metamorphism of organic matter, coal and rock salt, contributing to the end

  14. Geochemistry, water dynamics and metals: Major, trace elements, Pb and Sr isotope constraints on their origins and movements in a small anthropized catchment over a flood

    Luck, J.M.; Othman, D.B. [University Montpellier II, Laboratoire Geofluides, Bassins, Eaux, Montpellier (France)

    1997-10-01

    Major, trace elements and Sr-Pb isotope data on the dissolved and particulate phases are reported for water samples taken regularly over the September flood of a Mediterranean river (S France). This river drains runoff from a small, carbonate, karstified watershed with Miocene and Jurassic lithologies, and characterized by agricultural, urban and road network activities. The objective is to combine all the data into a dynamic model for constraining the origin(s) and movements of waters and of their loads. Furthermore, for metals, it becomes then feasible to know their fate and bioavailability downstream 18 refs., 4 figs.

  15. Systematics of one-quasiparticle configurations in neutron-rich Sr, Zr, and Mo odd isotopes with the Gogny energy density functional

    Rodriguez-Guzman, R; Robledo, L M

    2010-01-01

    The systematics of one-quasiparticle configurations in neutron-rich Sr, Zr, and Mo odd isotopes is studied within the Hartree-Fock-Bogoliubov plus Equal Filling Approximation method preserving both axial and time reversal symmetries. Calculations based on the Gogny energy density functional with both the standard D1S parametrization and the new D1M incarnation of this functional are included in our analysis. The nuclear deformation and shape coexistence inherent to this mass region are shown to play a relevant role in the understanding of the spectroscopic features of the ground and low-lying one-quasineutron states.

  16. Geochemical and Sr-Nd Isotopic Characteristics of Post-Collisional Calc-Alkaline Volcanics in the Eastern Pontides (NE Turkey)

    KAYGUSUZ, ABDULLAH; Arslan, Mehmet; ŞEN, WOLFGANG SIEBEL & CÜNEYT

    2011-01-01

    Major, trace element, K-Ar age and Sr-Nd isotopic data are presented for the Eocene Torul volcanics in the eastern Pontide orogenic belt (NE Turkey). The studied rocks are composed of basaltic andesitic, andesitic, trachyandesitic, and minor trachydacitic lavas associated with their pyroclastics. These rocks contain plagioclase (An2-44), hornblende (Mg#= 0.78-0.98), clinopyroxene (Wo43-46 En41-43 Fs10-15), biotite, quartz, and minor sanidine phenocrysts. K-Ar ages on hornblendes ages range fr...

  17. U-Pb Zircon geochronology and Sr-Nd isotopic characteristic of Late Neo proterozoic Born award granitoids (Taknar zone exotic block), Iran

    The study area (Born award granite) is located in northeast of Iran (Khorasan Razavi province), about 280 km southwest of Mashhad city. Taknar zone is an exotic block, bordered by two major faults, Great Kavir fault (Drouneh) to the south and Rivash fault in the north. A complex of granite, granodiorite, monzonite and diorite crop out at the center of Taknar zone. They are named as Bornaward granite. Published data using Rb-Sr whole-rock and biotite isotopic methods on granitoid rocks (Born award granite) gave ages of 154 to 111 Ma. The results of U-Pb zircon dating of granodiorite is 552.69 ± 10.89 Ma and granite is 538.22 - 1.82, + 4.28 Ma (Late Neo proterozoic time). Both granite and granodiorite are classified as belonging to the ilmenite-series of reduced S-type granitoids. Chemically, they are per-aluminous, high-K calc-alkaline with relatively enriched in LILE, Rb, K and depleted in Sr, Ba, Nb, Ti, Ta, Y and Yb. Chondrite-normalized Rare Earth Element plots indicate minor enrichments of light Rare Earth Element in composition with heavy Rare Earth Element, with (La/Yb)N between 3.5-5.6 and high total Rare Earth Element (193-252) with strong negative anomaly of Eu. They have a initial 87Sr/86Sr and 143Nd/144Nd ranging from 0.713566 to 0.716888 and 0.511791 to 0.511842, respectively, when recalculated to an age of 553 and 538 Ma, consistent with the new radiometric results. Initial εNd isotope values for granite and granodiorite range from -2,62 to -2,01. Granite and granodiorite of Born award yields a TDM age of 1.4-1.41 Ga. This indicates that the granites and granodiorite being derived from partial melting of distinct basement source regions with very high initial 87Sr/86Sr.

  18. Geochemical and Sr-Nd isotopic constraints on the mantle source of Neoproterozoic mafic dikes of the rifted eastern Laurentian margin, north-central Appalachians, USA

    Volkert, Richard A.; Feigenson, Mark D.; Mana, Sara; Bolge, Louise

    2015-01-01

    Abundant and widely distributed unmetamorphosed mafic dikes intrude Mesoproterozoic rocks of the New Jersey Highlands. The age of the dikes is imprecisely known but interpreted to fall between 615 and 576 Ma, which is consistent with the range of ages of mafic dikes from Labrador and Nova Scotia south to Pennsylvania that were emplaced along the rifted eastern Laurentian margin. New Jersey Highlands dikes are a few cm to 18 m wide and have lengths of as much as several km. They have sharp, largely discordant contacts against enclosing Mesoproterozoic rocks and aphanitic chilled margins that grade into coarser grained interiors. Columnar joints are present locally and suggest emplacement at a shallow crustal level. Geochemical compositions of the dikes range from alkalic to less common tholeiitic basalt having generally high TiO2, P2O5, Zr, Nb, Y, and La/Yb, and low MgO, Cr, and Ni. TiO2 contents define high-Ti and low-Ti dikes that differ in high field strength elements (HFSE) and light rare earth elements (LREE) but overlap in abundances of most other elements. Dike magma evolved in an ascending mantle plume of OIB-like asthenosphere from enriched higher TiO2 compositions to more depleted lower TiO2 compositions. Subtle differences in the dike compositions are due to variations in the amount of partial melting within the plume and the depth of melt segregation. Sr-Nd isotope values of both dike compositions overlap and are characterized by εNd (T) of + 1.5 to + 3.8 and initial 87Sr/86Sr ranging from 0.7032 to 0.7077. Higher Sr isotope ratios are interpreted as resulting from local interaction of the dike magma with heterogeneous, high 87Sr/86Sr lithospheric mantle having EMI or EMII-like geochemical characteristics. Dikes form tabular structures that have long segments striking an average of N44°E and short segments striking about east-west. Their regional geometries form right-stepping, rhomb-shaped patterns due to emplacement into rift-related dilational

  19. Geochronology (U-Pb/Pb-Pb) and isotopic signatures (Rb-Sr/Sm-Nd) of the Paleoproterozoic Guanambi Batholith, southwest Bahia State (NE Brazil)

    The Guanambi batholith (GB) is located in south-western Bahia, Brazil, where it forms part of the Urandi-Paratinga mobile belt. The batholith extends over an area of almost 6,000 km2 and is mainly composed of syenites and monzonites, with subordinate granites, mafic syenites and lamprophyric dykes. Two main units can be recognized: the multiple intrusions, being divided into four regions (Paratinga, Laguna, Igapora and Guanambi) and the so-called late-intrusions forming the Cara Suja, Ceraima and Estreito massifs. U-Pb and Pb-Pb isotopic data demonstrate that the batholith was emplaced 2.05 Ga ago. GB has highly negative initial εNd (-7.4 to -10.6), pointing to an enriched source, and Sr initial ratios between 0.704 and 0.707. Both chemical and isotopic signatures suggest that GB formed by fractional crystallization of a lamprophiric magma derived from a Paleoproterozoic enriched mantle source. (author)

  20. Development of isotope dilution-liquid chromatography/mass spectrometry combined with standard addition techniques for the accurate determination of tocopherols in infant formula

    Graphical abstract: -- Highlights: •ID-LC/MS method showed biased results for tocopherols analysis in infant formula. •H/D exchange of deuterated tocopherols in sample preparation was the source of bias. •Standard addition (SA)-ID-LC/MS was developed as an alternative to ID-LC/MS. •Details of calculation and uncertainty evaluation of the SA-IDMS were described. •SA-ID-LC/MS showed a higher-order metrological quality as a reference method. -- Abstract: During the development of isotope dilution-liquid chromatography/mass spectrometry (ID-LC/MS) for tocopherol analysis in infant formula, biased measurement results were observed when deuterium-labeled tocopherols were used as internal standards. It turned out that the biases came from intermolecular H/D exchange and intramolecular H/D scrambling of internal standards in sample preparation processes. Degrees of H/D exchange and scrambling showed considerable dependence on sample matrix. Standard addition-isotope dilution mass spectrometry (SA-IDMS) based on LC/MS was developed in this study to overcome the shortcomings of using deuterium-labeled internal standards while the inherent advantage of isotope dilution techniques is utilized for the accurate recovery correction in sample preparation processes. Details of experimental scheme, calculation equation, and uncertainty evaluation scheme are described in this article. The proposed SA-IDMS method was applied to several infant formula samples to test its validity. The method was proven to have a higher-order metrological quality with providing very accurate and precise measurement results

  1. Pb and Sr isotopes and trace metals in molluscs: constraints on metal sources and water fluxes in a coastal lagoon (Thau, France)

    Because of its unique ability to characterize the origins and quantify the fluxes of waters and their loads, isotopic geochemistry is being increasingly used in environmental problems. On the other hand, molluscs are known to concentrate metals in a very strong manner and equilibrate relatively rapidly with their environment. They are used in many programs of coastal survey (Mussel Watch, RNO,...). The originality of our work is to apply isotopic systems (Pb, Sr) to living organisms, in order to: 1- identify the metal sources; 2- determine their proportions in the lagoon and 3- to trace the water movements. The Thau lagoon (Herault, S. France) presents various potential sources of metals inputs: heavy traffic road, Sete harbour, various industries (cement factory, fertilizers...), agriculture, camping areas and leisure ports, not to mention natural (rock) sources. Our study deals with the metal and alkali, alkali-earth concentrations, Pb and Sr isotopes determined on both mussels implanted in the lagoon and wild mussels. We also compare our mussel results with those determined on clams which live at the water/sediments interface. A first study deals with the metal accumulation in laboratory experiments using mono-isotopic tracers 'spike'. It shows that the new metal is being superimposed to the metals initially present in the organisms; this effect is seen within a few days, although variable depending on elements (Zn, Cd, Pb). We have sampled the introduced mussels 4 times a year and we see that the concentration fluctuations are principally related to animal weight variations. The flesh isotopic compositions usually define nice alignments depending on season, indicative of a progressive mixing between two main components: one natural, one anthropogenic. Depending on winds,two influences of seawater entries or local water treatment plants effluents can be shown. We have compared past and present metal levels and origins in the area by analysing also ancient shells

  2. Using otoliths from a non-migratory fish (Slimy sculpin - Cottus cognatus) to evaluate temporal and spatial variability in 87Sr/86Sr ratios of river waters from a large and remote watershed in southwest AK, USA - the Nushagak River

    Brennan, S.; Fernandez, D. P.; Zimmerman, C.; Cerling, T. E.; Wooller, M. J.

    2013-12-01

    Heterogeneity in 87Sr/86Sr ratios of river-dissolved strontium (Sr) across geologically diverse watersheds and landscapes is a useful tool for investigating provenance, connectivity and movement patterns of various materials and organisms. Evaluating temporal variation across watersheds at different spatial scales is expensive and difficult, especially in remote areas, but is necessary to accurately interpret Sr isotopic data. We used the time-keeping properties inherent to otoliths, the ever-growing aragonitic auditory structure of teleost fish, from non-migratory Slimy sculpin (Cottus cognatus) to evaluate seasonal and inter-annual temporal variability in 87Sr/86Sr ratios of river waters throughout a large watershed in remote Alaska, USA - the Nushagak River. Using laser ablation multi-collector inductively coupled plasma mass-spectrometry, 87Sr/86Sr ratios were measured from core to edge of otoliths from Slimy sculpin (n = 20) ranging in age from 3 to 6 years old captured at various sites within the Nushagak River watershed. Generalized additive models (GAMs) of 87Sr/86Sr profiles indicate that the majority of individuals (n = 14) exhibit no significant isotopic variation (p > 0.05) from core to edge of otoliths, though some did exhibit significant isotopic variation (n = 6, p << 0.05). In some instances, sculpin caught at the same site showed characteristically different 87Sr/86Sr profiles, which we interpret as variations in the micro-movements and life histories of these fish versus time-dependent changes in the 87Sr/86Sr ratio of water at a particular site. This study illustrates the use of otoliths from non-migratory fish to evaluate seasonal and inter-annual variability in 87Sr/86Sr ratios of river-dissolved Sr at multiple spatial scales within a watershed.

  3. Sr-Nd-Pb isotope compositions of felsic intrusions in the El Teniente and Laguna La Huifa areas, Central Chile

    ) for being the main source of this type of magmatism. The presence of silicic lower crustal melts in the El Teniente region was earlier suggested by Kay and Kurtz (1995), who identified the geochemical fingerprint of mafic lower crust in postmineralization intrusives of the area. There is a growing regional scale, isotope data base that covers the timing of the magmatism at the El Teniente deposit (Kay and Kurtz, 1995; Stern and Skewes, 1995, Skewes and Stern, 1996 and Kurtz et al., 1997). Notwithstanding, there is still a need of additional data on a mine scale. The objective of this communication is to cover, at least partly, this need, presenting new Sr-Nd-Pb data. In the discussion section, we also discuss published Os isotope data from the El Teniente mine in order to further constrain the source of felsic magmatism linked to copper mineralization in the El Teniente and Laguna La Huifa areas (au)

  4. Origin of the deep fluids in the paleosubduction zones in western Tianshan: Evidence from Pb- and Sr-isotope compositions of high-pressure veins and host rocks

    HUANG; Dezhi; GAO; Jun; DAI; Tageng; ZOU; Haiyang; XIONG; X

    2005-01-01

    Fluids in the deep subduction zones play an important role in crust-mantle exchange related to the subduction process. Identification of fluids origin, internal or external, can help us to evaluate the contribution of crust materials to mantle during this process. High-pressure veins, which developed in the western Tianshan HP-metamorphic belt extensively, are the direct products of the fluids in subduction zones. In western Tianshan, high-pressure veins and host rocks have overall Pb- and Sr-isotope compositions. At t = 340 Ma, the high-pressure metamorphic time, the ratios of 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb and 87Sr/86Sr of high pressure veins are 17.122―18.431, 15.477―15.611, 37.432―38.689 and 0.70529―0.70705, and are 17.605―17.834, 15.508―15.564, 37.080―38.145 and 0.70522―0.70685 for host rocks. However, high-pressure veins show a much larger variation in Pb-isotope compositions than host rocks. Plots of samples are distributed roughly along a line parallel to and far away from the Northern Hemisphere reference line (NHRL) on the plot of 206Pb/204Pb vs 207Pb/204Pb. On the plot of 206Pb/204Pb vs 208Pb/204Pb, plots of data are distributed nearby mid-ocean-ridge basalts (MORB) area or along a line parallel to and not far away from NHRL, which shows that the data plots are farther away from MORB and ocean island basalts (OIB) areas on the plot of 206Pb/204Pb vs 207Pb/204Pb than on the plot of 206Pb/204Pb vs 208Pb/204Pb. The compositions of Pb- and Sr-isotopes of these high-pressure metamorphic rocks are between that of enriched mantle 1(EMI) and of sediments or upper crust. A notable characteristic can be seen from plots of Pb-isotope ratio vs Pb-isotope ratio and 206Pb/204Pb vs 87Sr/86Sr that array of plots shows an evident tendency of mixture of two end members. Ratios of Rb/Ba, Ce/Pb, Nb/U and Ta/U of high-pressure veins and host rocks are between that of OIB or MORB and that of continental crust, which indicates that continental crust

  5. Contamination in mafic mineral-rich calc-alkaline granites: a geochemical and Sr-Nd isotope study of the Neoproterozoic Piedade Granite, SE Brazil

    Leite Renato J.

    2006-01-01

    Full Text Available The Piedade Granite (~600 Ma was emplaced shortly after the main phase of granite magmatism in the Agudos Grandes batholith, Apiaí-Guaxupé Terrane, SE Brazil. Its main units are: mafic mineral-rich porphyritic granites forming the border (peraluminous muscovite-biotite granodiorite-monzogranite MBmg unit and core (metaluminous titanite-bearing biotite monzogranite BmgT unit and felsic pink inequigranular granite (Bmg unit between them. Bmg has high LaN/YbN (up to 100, Th/U (>10 and low Rb, Nb and Ta, and can be a crustal melt derived from deep-seated sources with residual garnet and biotite. The core BmgT unit derived from oxidized magmas with high Mg# (~45, Ba and Sr, fractionated REE patterns (LaN/YbN= 45, 87Sr/86Sr(t~ 0.710, epsilonNd(t ~ -12 to -14, interpreted as being high-K calc-alkaline magmas contaminated with metasedimentary rocks that had upper-crust signature (high U, Cs, Ta. The mafic-rich peraluminous granites show a more evolved isotope signature (87Sr/86Sr(t = 0.713-0.714; epsilonNd(t= -14 to -16, similar to Bmg, and Mg# and incompatible trace-element concentrations intermediate between Bmg and BmgT. A model is presented in whichMBmgis envisaged as the product of contamination between a mafic mineral-rich magma consanguineous with BmgT and pure crustal melts akin to Bmg.

  6. Source contamination and mantle heterogeneity in the genesis of Italian potassic and ultrapotassic volcanic rocks: Sr-Nb-Pb isotope data from Roman Province and Southern Tuscany

    The Tyrrhenian border of the Italian peninsula has been the site of intense magmatism from Pliocene to recent times. Although calc-alkaline, potassic and ultrapotassic volcanism overlaps in space and time, a decrease of alkaline character in time and space (southward) is observed. Alkaline ultrapotassic and potassic volcanic rocks are characterized by variable enrichment in K and incompatible elements, coupled with consistently high LILE/IFSE values, similar to those of calc-alkaline volcanic rocks from the nearby Aeolian arc. On the basis of mineralogy and major and trace element chemistry two different arrays can be recognized among primitive rocks; a silica saturated trend, which resulted in formation of leucite-free mafic rocks, and a silica under saturated trend, characterized by leucite-bearing rocks. Initial 87Sr/87Sr and 143Nd/144Nd values of Italian ultrapotassic and potassic mafic rocks range from 0.70506 to 0.71672 and from 0.51173 to 0.51273, respectively. 207Pb/204Pb values range between 18.50 and 19.15, 207Pb/204Pb values range between 15.63 and 15.70, and 208Pb/204Pb values range between 38.35 and 39.20. The general εSr vs. εNd array, along with crustal lead isotopic values, clearly indicates that a continental crustal component has played an important role in the genesis of those magmas. The main question is where this continental crustal component has been acquired by the magmas. Volcanological and petrologic data indicate continental crustal contamination to be a leading process along with fractional crystallization and magma mixing. Considering, however, only the samples thought to represent primary magmas, which have been in equilibrium with their mantle source, a clearer picture emerges. A large variation of εSr vs. εNd is still observed, with εSr from -2 to +180 and εNd from +2 to -12. A bifurcation of this array is observed in the samples that plot in the lower right quadrant, with mafic leucite-bearing Roman Province rocks buffered at

  7. U-Pb geochronology and Sr-Nd isotopes of Galileia and Urucum neo proterozoic granitoids suites in south-eastern Brazil

    U-Pb zircon and monazite dating and whole-rock Sr-Nd isotopes have been applied on Neo-Proterozoic granitoids from the Atlantic shear belt, south-eastern Brazil. U-Pb zircon results on the Galileia met-aluminous and Urucum per-aluminous suites indicate crystallisation ages of 594 ± 6 Ma and 582 ± 2 Ma respectively. Whole-rock Rb-Sr and Sm-Nd analyses on representative samples from both suites demonstrate that they mainly derive from melting of older crustal rocks. The occurrence of an old isotopic memory in the zircons from the Urucum granitoids around 2.2 Ga, in agreement with Nd model ages, suggests a Palaeo-Proterozoic age for the crustal proto-lith of these two suites, probably associated with the Transamazonico event. Owing to these new dating results and previous regional geochronological data, it can be proposed that the met-aluminous magmatism ended around 590 Ma and that the collisional peraluminous magmatism associated with the Brasiliano orogeny occurred between 584 and 570 Ma. (authors)

  8. Trindade and Martı´n Vaz Islands, South Atlantic: Isotopic (Sr, Nd, Pb) and trace element constraints on plume related magmatism

    Siebel, W.; Becchio, R.; Volker, F.; Hansen, M. A. F.; Viramonte, J.; Trumbull, R. B.; Haase, G.; Zimmer, M.

    2000-05-01

    Highly alkaline silica undersaturated lavas erupted at Trindade Island over its 5 Ma geologic history and comprise primitive nephelinites-basanites and more evolved nepheline-bearing phonolitic rocks. Nephelinites-basanites and phonolitic rocks are thought to be genetically related via crystal fractionation, as indicated by the very limited range in Sr, Nd and Pb isotope ratios, systematically increasing contents of incompatible trace elements from primitive to evolved rock types, and similar variation in chemical composition of the major phenocryst phases (clinopyroxene, amphibole, feldspar) in all rock types. Tb/Yb ratios of the primitive lavas are high (2.6-4.1) and silica contents are low (39.8-42.9 wt.% SiO 2), indicating that the melts were generated at deep mantle depths (˜150 km), within the garnet lherzolite stability field. Non-radiogenic 87Sr/ 86Sr (0.70377-0.70421) and radiogenic 143Nd/ 144Nd (0.512752-0.512837) values show that the Trindade and Martı´n Vaz rocks are derived from moderately depleted sources relative to bulk-earth. The lavas have moderate radiogenic 206Pb/ 204Pb ratios of 19.00-19.33, 207Pb/ 204Pb of 15.56-15.60, and 208Pb/ 204Pb of 38.89-39.34; they plot close to the Northern Hemisphere Reference Lines (NHRL). The narrow range of Sr, Nd, and Pb isotopic compositions in the Trindade and Martı´n Vaz lavas suggests either that the source region was homogeneous (similar to the common mantle components FOZO and "C"), or that melts from a heterogeneous three-component mantle source, involving HIMU, enriched mantle EM I, and depleted N-type MORB, were well mixed before eruption. Late Cretaceous to Present volcanism ranging from interior Brazil towards Trindade is thought to record the passage of the South American plate over the Trindade mantle plume (e.g., O'Connor and Duncan, 1990). Comparison with published data from other mafic rocks along the suggested plume track shows that Trindade isotopic compositions match those of transitional

  9. Shoshonite and sub-alkaline magmas from an ultrapotassic volcano: Sr-Nd-Pb isotope data on the Roccamonfina volcanic rocks, Roman Magmatic Province, Southern Italy

    Conticelli, Sandro; Marchionni, Sara; Rosa, Davide; Giordano, Guido; Boari, Elena; Avanzinelli, Riccardo

    2009-01-01

    The Roccamonfina volcano is characterised by two stages of volcanic activity that are separated by volcano-tectonic caldera collapses. Ultrapotassic leucite-bearing rocks are confined to the pre-caldera stage and display geochemical characteristics similar to those of other volcanoes in the Roman Province. After the major sector collapse of the volcano, occurred at ca. 400 ka, shoshonitic rocks erupted from cinder cones and domes both within the caldera and on the external flanks of the pre-caldera Roccamonfina volcano. On the basis of new trace element and Sr-Nd-Pb isotope data, we show that the Roccamonfina shoshonitic rocks are distinct from shoshonites of the Northern Roman Province, but are very similar to those of the Neapolitan volcanoes. The last phases of volcanic activity erupted sub-alkaline magmas as enclaves in trachytic domes, and as lavas within the Monte Santa Croce dome. Ultrapotassic rocks of the pre-caldera composite volcano are plagioclase-bearing leucitites characterised by high levels of incompatible trace elements with an orogenic signature having troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of 87Sr/86Sr range from 0.70926 to 0.70999, 143Nd/144Nd ranges from 0.51213 to 0.51217, while the lead isotope rations vary between 18.788-18.851 for 206Pb/204Pb, 15.685-15.701 for 207Pb/204Pb, and 39.048-39.076 for 208Pb/204Pb. Shoshonites show a similar pattern of trace element depletions and enrichments to the earlier ultrapotassic leucite-bearing rocks but have a larger degree of differentiation and lower concentrations of incompatible trace elements. On the other hand, shoshonitic rocks have Sr, Nd, and Pb isotopes consistently different than pre-caldera ultrapotassic leucite-bearing rocks. 87Sr/86Sr ranges from 0.70665 to 0.70745, 143Nd/144Nd ranges from 0.51234 to 0.51238, 206Pb/204Pb ranges from 18.924 to 19.153, 207Pb/204Pb ranges from 15.661 to 15.694, and 208Pb/204Pb ranges from 39.084 to 39.212. High-K calc

  10. Zircon U-Pb geochronology, geochemistry, and Sr-Nd-Hf isotopes of granitoids in the Yulekenhalasu copper ore district, northern Junggar, China: Petrogenesis and tectonic implications

    Yang, Fuquan; Chai, Fengmei; Zhang, Zhixin; Geng, Xinxia; Li, Qiang

    2014-03-01

    The Yulekenhalasu porphyry copper deposit is located in the Kalaxiange'er metallogenic belt in northern Junggar, China. We present the results from zircon U-Pb geochronology, and geochemical and Sr-Nd-Hf isotope analyses of the granitoids associated with the ore deposits with a view to constrain their petrogenesis and tectonic setting. The granitoids consist of quartz diorite, diorite porphyry, porphyritic monzonite, and quartz porphyry, emplaced at 382, 379, 375-374, and 348 Ma, respectively, which span Late Devonian to early Carboniferous ages. The ore-bearing intrusion is mainly diorite porphyry, with subordinate porphyritic monzonite. The Late Devonian intrusions are characterized by SiO2 contents of 54.5-64.79 wt.%, Na2O contents of 3.82-8.24 wt.%, enrichment in Na, light rare-earth elements (LREEs), and large ion lithophile elements. They also display relative depletion in Y, Ba, P, Nb, Ta, and Ti, and weak negative Eu anomalies (δEu = 0.6-0.87). The early Carboniferous quartz porphyry is characterized by high SiO2 content (72.26-73.35 wt.%), enrichment in LREEs, K, and Sr, and relative depletion in Y (10.82-12.52 ppm) and Yb (1.06-1.15 ppm). The Late Devonian and early Carboniferous granitoids are characterized by positive ɛNd(t) values (5.2-10.1, one sample at - 1.9), positive ɛHf(t) values (7.46-18.45), low (87Sr/86Sr)i values (0.70363-0.70476), and young crustal residence ages. These data indicate that the sources of the granitoids were mainly mantle-derived juvenile rocks. Geochemical and Nd-Sr-Hf isotopic data demonstrate that the Late Devonian granitoids formed in an oceanic island arc, and they were formed from different sources, among which the mineralized diorite porphyry might have originated from a mixed slab-derived and mantle wedge melt source. The early Carboniferous quartz porphyry was likely emplaced in a mature island arc environment, and was probably derived from juvenile crust.

  11. Late Archaean mantle metasomatism below eastern Indian craton: Evidence from trace elements, REE geochemistry and Sr-Nd-O isotope systematics of ultramafic dykes

    Abhijit Roy; A Sarkar; S Jeyakumar; S K Aggrawal; M Ebihara; H Satoh

    2004-12-01

    Trace, rare earth elements (REE), Rb-Sr, Sm-Nd and O isotope studies have been carried out on ultramafic (harzburgite and lherzolite) dykes belonging to the newer dolerite dyke swarms of eastern Indian craton. The dyke swarms were earlier considered to be the youngest mafic magmatic activity in this region having ages not older than middle to late Proterozoic. The study indicates that the ultramafic members of these swarms are in fact of late Archaean age (Rb-Sr isochron age 2613 ± 177 Ma, Sri ∼0.702 ± 0.004) which attests that out of all the cratonic blocks of India, eastern Indian craton experienced earliest stabilization event. Primitive mantle normalized trace element plots of these dykes display enrichment in large ion lithophile elements (LILE), pronounced Ba, Nb and Sr depletions but very high concentrations of Cr and Ni. Chondrite normalised REE plots exhibit light REE (LREE) enrichment with nearly flat heavy REE (HREE; ( HREE)N ∼ 2-3 times chondrite, (Gd/Yb)N∼1). The Nd(t) values vary from +1.23 to −3.27 whereas 18O values vary from +3.16‰ to +5.29‰ (average +3.97‰ ± 0.75‰) which is lighter than the average mantle value. Isotopic, trace and REE data together indicate that during 2.6 Ga the nearly primitive mantle below the eastern Indian Craton was metasomatised by the fluid (±silicate melt) coming out from the subducting early crust resulting in LILE and LREE enriched, Nb depleted, variable Nd, low Sri(0.702) and low 18O bearing EMI type mantle. Magmatic blobs of this metasomatised mantle were subsequently emplaced in deeper levels of the granitic crust which possibly originated due to the same thermal pulse.

  12. The significance of PGE variations with Sr-Nd isotopes and lithophile elements in the Emeishan flood basalt province from SW China to northern Vietnam

    Li, Chusi; Ripley, Edward M.; Tao, Yan; Hu, Ruizhong

    2016-04-01

    New analyses of siderophile-lithophile elements and Sr-Nd isotopes in the Permian basalts and picrites from northern Vietnam, the southernmost occurrence of the Emeishan flood basalt province, together with previously published data, are used to address the question of whether any meaningful correlation between these elements and isotopes exists at a province scale. The available data show that negative correlations between εNd, (87Sr/86Sr)i and mantle-normalized (Nb/Th)n are present in the basalts but not in the associated picrites. This indicates that crustal contamination is negligible in the picrites but significant in some of the basalts. The picrites and basalts from the entire province show negative correlations between (Rh/Ru)n, (Pt/Ru)n, (Pd/Ru)n and Mg-number. This indicates that Ru behaves compatibly whereas Rh, Pt and Pd behave incompatibly during magma differentiation. The incompatible behavior of Rh in natural basaltic systems is also supported by the fact that (Pt/Rh)n remains constant with decreasing Mg-number in the lavas. Depletions of Pd and Pt, and to a lesser degree Cu, in some basaltic samples characterized by relatively low εNd and (Nb/Th)n support the notion that sulfide saturation in the magmas was triggered by a combination of siliceous crustal contamination and addition of external sulfur. Within the entire flood basalt province only the picrites from Song Da, northern Vietnam show clear depletion in Ir relative to Ru. These picrites are also characterized higher Al2O3/TiO2 and lower mantle-normalized La/Yb (0.2-2.4) than those from elsewhere in the province, possibly due to the involvement of an Ir-depleted, fertile mantle component in magma generation at this location.

  13. Mantle influence on the character of I-type granitoids of the New England batholith: evidence from Sr and Nd isotopes

    Granitoid samples, together with an array of mafic to felsic dyke rocks, were collected from both the southern members of the high-K Moonbi Suite (Moonbi district) and the southern members of the low-K Clarence River Suite (Barrington Tops Granodiorite). These constitute the two most divergent compositions in the spectrum of I-type granitoids in the New England Batholith. Mafic plutonic rocks (quartz diorites) also coexist with granitoids at Barrington Tops (Eggins and Hensen 1987), and mafic dykes (high-K lamprophyres) have been observed in association with Moonbi Suite granitoids in the Hillgrove area (Kent 1994). Kent (1994) noted that lamprophyres in the Rockvale area extend the linear trends of the Moonbi granitoids on Harker plots, and the petrographic and chemical similarities between mafic and felsic intrusives at Barrington Tops have been described by Eggins and Hensen (1987). Shaw et al. (1992) also noted that lamprophyre dykes at Tulcumba Ridge (to the west of Tamworth) have similar ages and initial Sr isotopic compositions to Moonbi Suite granitoids (87Sr/86Sri 0.7042-0.7048). Lamprophyre dykes and felsic dykes of dacitic composition within the Moonbi Adamellite and the surrounding area were analysed for their Sr and Nd isotopic compositions, in an attempt to determine a link between mafic, mantle derived magmas and their granitoid hosts. Although isotopic and geochemical evidence provides a clear link between mantle-derived mafic magmas and granitoids within both the Moonbi and Clarence River suites, a clear explanation of the mechanisms and source rocks involved in magma generation remains elusive. Of critical importance is identification of the character of the lower crustal sources involved in each case, and clarification of the mechanism of interaction between the mantle and crustal sources. In particular, although the lamprophyres associated with the Moonbi Suite appear partly responsible for the isotopic and geochemical character (in particular

  14. Kinetic isotope effect of the 16O + 36O2 and 18O + 32O2 isotope exchange reactions: Dominant role of reactive resonances revealed by an accurate time-dependent quantum wavepacket study

    The O + O2 isotope exchange reactions play an important role in determining the oxygen isotopic composition of a number of trace gases in the atmosphere, and their temperature dependence and kinetic isotope effects (KIEs) provide important constraints on our understanding of the origin and mechanism of these and other unusual oxygen KIEs important in the atmosphere. This work reports a quantum dynamics study of the title reactions on the newly constructed Dawes-Lolur-Li-Jiang-Guo (DLLJG) potential energy surface (PES). The thermal reaction rate coefficients of both the 18O + 32O2 and 16O + 36O2 reactions obtained using the DLLJG PES exhibit a clear negative temperature dependence, in sharp contrast with the positive temperature dependence obtained using the earlier modified Siebert-Schinke-Bittererova (mSSB) PES. In addition, the calculated KIE shows an improved agreement with the experiment. These results strongly support the absence of the “reef” structure in the entrance/exit channels of the DLLJG PES, which is present in the mSSB PES. The quantum dynamics results on both PESs attribute the marked KIE to strong near-threshold reactive resonances, presumably stemming from the mass differences and/or zero point energy difference between the diatomic reactant and product. The accurate characterization of the reactivity for these near-thermoneutral reactions immediately above the reaction threshold is important for correct characterization of the thermal reaction rate coefficients

  15. Isotopic Ratio Outlier Analysis of the S. cerevisiae Metabolome Using Accurate Mass Gas Chromatography/Time-of-Flight Mass Spectrometry: A New Method for Discovery.

    Qiu, Yunping; Moir, Robyn; Willis, Ian; Beecher, Chris; Tsai, Yu-Hsuan; Garrett, Timothy J; Yost, Richard A; Kurland, Irwin J

    2016-03-01

    Isotopic ratio outlier analysis (IROA) is a (13)C metabolomics profiling method that eliminates sample to sample variance, discriminates against noise and artifacts, and improves identification of compounds, previously done with accurate mass liquid chromatography/mass spectrometry (LC/MS). This is the first report using IROA technology in combination with accurate mass gas chromatography/time-of-flight mass spectrometry (GC/TOF-MS), here used to examine the S. cerevisiae metabolome. S. cerevisiae was grown in YNB media, containing randomized 95% (13)C, or 5%(13)C glucose as the single carbon source, in order that the isotopomer pattern of all metabolites would mirror the labeled glucose. When these IROA experiments are combined, the abundance of the heavy isotopologues in the 5%(13)C extracts, or light isotopologues in the 95%(13)C extracts, follows the binomial distribution, showing mirrored peak pairs for the molecular ion. The mass difference between the (12)C monoisotopic and the (13)C monoisotopic equals the number of carbons in the molecules. The IROA-GC/MS protocol developed, using both chemical and electron ionization, extends the information acquired from the isotopic peak patterns for formulas generation. The process that can be formulated as an algorithm, in which the number of carbons, as well as the number of methoximations and silylations are used as search constraints. In electron impact (EI/IROA) spectra, the artifactual peaks are identified and easily removed, which has the potential to generate "clean" EI libraries. The combination of chemical ionization (CI) IROA and EI/IROA affords a metabolite identification procedure that enables the identification of coeluting metabolites, and allowed us to characterize 126 metabolites in the current study. PMID:26820234

  16. Further Rb-Sr age and isotope data on early and late Archaean rocks from the Rhodesian craton

    Whole-rock Rb-Sr age measurements are presented which supplement and extend published data from the Rhodesian Archaean craton of southern Africa and demonstrate that (a) the Shabani area gneisses, which form the basement to the ca. 2700-2800 Ma-old Belingwe greenstone belt succession, give an age of 3570+-60 Ma with an initial 87Sr/86Sr ratio of 0.7000+-0.0005; (b) a suite of gneisses from the so-called Rhodesdale Batholith northeast of Que Que gives an age of 2760+-40 Ma with an initial ratio of 0.7015+-0.0002; (c) the Somabula tonalite pluton, which intrudes gneisses east of Shangani, gives an age of 2650+-40 Ma, with an initial ratio of 0.7012+-0.0001 (all errors at 1 sigma). The initial 87Sr/86Sr ratios again demonstrate that Late Archaean granitic (sensu lato) rocks were not produced by reworking of similar rocks of Early Archaean age

  17. A hybrid origin for two Cretaceous monzonitic plutons in eastern Zhejiang Province, Southeast China: Geochronological, geochemical, and Sr-Nd-Hf isotopic evidence

    Liu, Liang; Qiu, Jian-Sheng; Zhao, Jiao-Long

    2016-01-01

    Monzonites can provide important information about the nature of the mantle sources and the mechanism of crust-mantle interactions. However, details on the origin of Late Mesozoic monzonites in the Southeastern China remain poorly constrained. This paper presents whole-rock geochemical, Sr-Nd isotopic and zircon U-Pb and Hf isotopic data for two monzonitic plutons (Huangtanyang and Kanggu) in eastern Zhejiang Province, with the aim of elucidating their petrogenesis, and providing important insights into the process of crust-mantle interaction. LA-ICP-MS zircon U-Pb dating results imply that the Huangtanyang and Kanggu quartz monzonites were emplaced in Cretaceous (104-109 Ma). All quartz monzonites are intermediate to acidic, metaluminous to weakly peraluminous, subalkaline, and K-rich in composition. They are enriched in large ion lithophile (e.g., Rb, Ba and Pb) and light rare earth elements, depleted in high-field strength elements (e.g., Nb, Ta, and Ti), and show weakly negative or no Eu anomalies (δEu = 0.78-1.02). All quartz monzonites have homogeneous initial ISr values (0.7084-0.7090) and εNd(t) values (-7.50 to -6.84). They are characterised by highly variable zircon Hf isotopic compositions, with εHf(t) values ranging from -13.3 to -5.7. The combined geochemical evidences (such as high Mg# values, low Nb/U and Ta/U ratios, and variable zircon Hf isotopic compositions) suggests that both depleted asthenospheric and metasomatically enriched mantle components were involved in the formation of the monzonites. The existence of some zircons with unusually low εHf(t) values (low to -13.3) and Palaeoproterozoic two-stage Hf model ages from the Huangtanyang and Kanggu quartz monzonites also argues strongly for Palaeoproterozoic crustal involvement. Magma mixing played a dominated role in the genesis of these monzonites, as indicated by their wide range in zircon Hf isotopic compositions and the occurrence of mafic microgranular enclaves (MMEs). The MMEs show

  18. Nd-Sr Isotopic Geochemistry of the Late Archean-Paleoproterozoic Granitoids in the Lüliang-Wutai Terrain, North China Craton,and Implications for Petrogenesis

    CHEN Bin; LIU Shuwen; WANG Rui; CHEN Zhichao; LIU Chaoqun

    2006-01-01

    In this paper we report geochemical and Nd-Sr isotopic data for a late Archean gneissic granitic pluton (Hengling pluton), an early Paleoproterozoic complex (Xipan complex) and a late China, to trace the source of these late Archean-Paleoproterozoic granitoids and, particularly, to understand the nature and mechanism of continental growth at that time. The Hengling granitic gneisses (ca. 2.51 Ga) are characterized by high Na2O and LILEs, TTG-like REE patterns (highly depleted HREE and minor Eu anomalies) and moderately depleted Nd-Sr isotopic compositions (εNd(t)=1.2-2.7, ISr=0.7015-0.7019), and were considered as being products of arc magmatism that was developed upon the North China craton. The Xipan complex (ca. 2.2 Ga) contain gabbroic diorite and monzonite, mostly being Na2O-rich, highly fractionated REE patterns and isotopically enriched (εNd(t)=-1.5 to -4.1, ISr=0.7038-0.706). The gabbroic diorites probably originated from melting of an enriched mantle source, but significantly contaminated by lower crustal material, and the monzonites probably represent a product of a mixture between the gabbroic dioritic magma and granitic melts of crustal origin. The Yunzhongshan post-collisional granitoids (ca. 1.8 Ga) are characterized by high-K affinity and highly-enriched and homogeneous Nd isotopic compositions (εNd(t)=-4.9 to -5.7), although they split into two groups in terms of REE patterns: one group showing elevated HREE (and Sc, Y and Zr)with significant negative Eu anomalies and the other showing highly depleted HREE and, to a lesser extent, mid-REE with negligible Eu anomalies. These granites are genetically related to a process of extensional collapse of a thickened orogen. They formed through magma mixing between mantlederived basaltic magmas and crust-derived granitic melts, followed by significant fractionation of ferromagnesian phases (like hornblende and Cpx) and feldspar and accessory zircons. Some Yunzhongshan granites show very old Nd model ages

  19. Rb-Sr and Sm-Nd isotopic studies of the Upper Paleozoic ignimbrites from Tokrau depression (Central Kazakhstan)

    Allowing for errors , Rb-Sr isochronous age of the Akron's massif ignimbrites (303±5 million years) and that of Korgants massif ones supper imposing them (299±5 million years) should be dated by 310±3 million years. The initial ratios (87Sr/86Sr), constitute 0.7046-0.7048 in the rocks of both massifs. And is positive and makes up 0.94-2.92. The crust's age, i. e. the source of ignimbrites forming molten runs up to 0.8-1.0 billion years by Nd-model dating. Within boundary of Middle Late Carboniferous there was no Pre-Raphanin granite continental crust below the Tokrau depression. (author)

  20. Isotopegeochemical investigations and dating on minerals and fossils from sedimentary rocks: 1. Glauconites from Jura, Molasse and Helveticum (K-Ar, Rb-Sr), 2. 87Sr/86Sr-Isotope stratigraphy on marine and limnetic micro- and macro-fossils, 3. Primary minerals from tertiary bentonites and tuffs (U-Pb, K-Ar)

    Glauconite investigations: the main problem in dating glauconites lies in the identification of authigenic minerals which have not been influenced by post-sedimentary processes. The age determination on glauconites from the three different tectonic units: the Jura mountains, the molasse basin and the Helvetic nappes, yield inconsistent results. Up to 35% too young K-Ar ''ages'' of glauconites from limestones from the Helvetic nappes can be traced to partial Ar loss caused by sediment-lithification and tectonic events. Sr-isotope stratigraphy: multiple analyses of recent samples from the Mediterranean Sea and from the North Atlantic show that the 87Sr/86Sr isotope ratios correspond well. In a stratigraphic ideal section from the Upper marine molasse a resolution of 206Pb/238U method zircons from the Fish Canyon Tuff were measured and yielded ages of 28.49±0.10, 24.46±0.11 and 28.46±0.13 Ma. These values correspond well with the published mean value of zircon and apatite fission track age of 28.4±0.7 Ma. Thus, the U-Pb method for dating young volcanic minerals seems to be suitable. However, the published mean value (''solid state age'') of Naeser et al. (1981) is higher than the published (''gas age'') mean value of 27.2±0.7 Ma based on biotite, sanidine, hornblende and plagioclase. (author) figs., tabs., refs

  1. The role of magma mixing in the evolution of high-K calc-alkaline granitoid suites: in situ trace element and Sr-Nd-Hf isotope constraints

    Laurent, Oscar; Zeh, Armin; Gerdes, Axel; Slaby, Ewa; Villaros, Arnaud

    2015-04-01

    The so-called "I-type", high-K calc-alkaline granitoids are often considered as "hybrid" in origin, i.e. involving both mantle and crustal components in their petrogenesis. The interactions between both components either take place (1) at mantle levels (i.e. enriched mantle source); (2) at emplacement levels (i.e. crustal contamination and/or magma mixing with crustal melts) or (3) both. Magma mixing is, in particular, frequently invoked to explain the compositional range of high-K calc-alkaline granitoid suites, especially phases of intermediate composition (SiO2 = 60-65 wt.%) such as quartz-diorites or granodiorites. We investigated the role of magma mixing in the origin of such rocks using elemental and isotope (Sr-Nd-Hf) chemistry of magmatic minerals (plagioclase, zircon, apatite, titanite, epidote), measured in situ by LA-(MC-)ICPMS, allowing a much greater spatial resolution than classical whole-rock geochemistry. We focused on a suite of late-Archaean (2.69 Ga-old) high-K, calc-alkaline granitoids from the Pietersburg block, northern Kaapvaal Craton (South Africa): the Mashashane, Matlala, Matok and Moletsi plutons. Those plutons range from diorites to monzogranites, emplaced at different crustal levels but all within a relatively short time span and showing evidence for interactions (mingling), both at the outcrop and mineral scale. Hf isotope data on zircon confirm that all rocks are cogenetic (identical ɛHf(t)), but trace element and Sr isotopes in plagioclase point to the involvement of several components in their petrogenesis, at different stages of the magma evolution. The most mafic rocks (diorites) derive from the interaction, at mantle levels, between depleted peridotite and a sedimentary component of quartzofeldspathic nature. The mineral chemistry of more felsic rocks can be explained by (1) differentiation from the diorite magmas through Amp + Plag fractionation; (2) interactions with magmas derived from melting of local crust (tonalites

  2. Impact of transboundary air pollution on our alpine water resources: application of a multi-isotope (N, O, S, Pb, Sr) approach

    This paper shows possibilities to quantify the impact of air pollution on sensitive water resources (e.g. karst), to develop an innovative surveillance tool based on isotopes and meteorological considerations. Comparison of lead isotope measurements in precipitation, spring waters, soil profiles and dolomite bedrock in a relatively pristine and remote area at the front-range of the Northern Calcareous Alps in Austria with literature data indicate that radiogenic gasoline-lead still dominates with 60-80% the composition of the trace lead in the spring waters. In addition to the lead leached from the dolomite bedrock a third source contributes about 5-10%. This second long distance Pb-contribution may originate from coal burning and/or Ag-Pb-ore smelting in Central Europe in the past. The monthly precipitation (May and September 2005) samples show 18O-rich sulphate ions, whereas the soil sulphates have depleted 18O and higher 34S values with depth. The spring waters and the bedrock dolomites show relatively low δ34S values (4-9 per mille). Assuming the precipitation and the dolomite bed rocks are end-members the contribution of atmospheric sulphate is estimated to be 20% in the spring waters and between 10 to 45 % in the soil samples. The 87Sr/86Sr of the precipitation (0.7092) support at least a more radiogenic, far transported source in addition to a possible recycling of local dolomite and limestone (0.7080-0.7083) dust. Spring waters show similar ratios between 0.7083-0.7084 confirming Sr-isotopes are good indicators for groundwater contact with specific host rocks. The nitrate concentration in the precipitation is fairly low (2 mg/L) and increases in the spring and surface waters to 4.6-6.0 mg/L only by leaching the forest soils. The monthly precipitation show 18O-rich nitrate ions in spring and winter samples indicating higher concentrations of more atmospheric derived nitrate, whereas less 18O-rich and negative δ15N nitrate ions in summer indicating more

  3. Crustal contamination and crystal entrapment during polybaric magma evolution at Mt. Somma-Vesuvius volcano, Italy: Geochemical and Sr isotope evidence

    Piochi, M.; Ayuso, R.A.; de Vivo, B.; Somma, R.

    2006-01-01

    New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma-Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Sr-isotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation-Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC-AFC) formulation. J. Petrol. 999-1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energy-constrained assimilation-fractional crystallization (EC-AFC) model to magmatic systems. J. Petrol. 1019-1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9-10 km) is a fundamental process controlling magma compositions at Mt. Somma

  4. The use of environmental isotopic (C, Sr, S) and hydrochemical tracers to characterize anthropogenic effects on karst groundwater quality: A case study of the Shuicheng Basin, SW China

    Research highlights: → Groundwater is mostly Ca-HCO3 type in the Shuicheng Basin, Southwest China. → Groundwater quality was seriously affected by anthropogenic activities. → Cl- and Na+ were derived mostly from domestic sewage containing table salt. → High NO3- concentrations could be a result of domestic sewage and nitrogen fertilizers. → SO42- ion was derived mostly from domestic wastewater, rainwater, and sulfide oxidation. - Abstract: Rapidly increasing populations, and associated intensification of agriculture, urbanization and industrialization, place increased demands on water resources and increased likelihood of pollution in many areas of the world. The Shuicheng Basin, southwestern China, is one such area and in order to understand water-rock interactions (carbonate dissolution) and anthropogenic impacts on groundwater quality in this karstic landform-dominated area, chemical as well as C, Sr and S isotopic compositions of groundwater (spring and well) and surface water (river) were measured during and following rainy seasons. The concentrations of various ions in groundwater were characterized by the dominant cations (Ca2+, Mg2+) and anions (HCO3-, SO42-), which account for more than 80% of the total ion concentration. Strontium isotope ratios (87Sr/86Sr, 0.70760-0.70918, mean 0.70831) and δ13CDIC (-14.2 per mille to -8.4 per mille, mean -10.7 per mille) indicate that the weathering dissolution of limestone controls Ca2+ and HCO3-. The decrease in δ13CDIC values with increasing concentrations of anthropogenic species (Cl-, NO3- and Na+) shows that the C isotopic composition of DIC can be a useful tracer of contaminants. Chemical compositions, hydrogeological conditions and δ34S analyses showed increasing SO42- concentration, resulting from domestic wastewater, fertilizer applications, atmospheric inputs through coal combustion, and oxidation of sulfide minerals, which typically are abundant in coal formations in the basin. Groundwater from

  5. Geothermal waters from the Taupo Volcanic Zone; New Zealand: a view through Li, B and Sr isotopes

    Millot, Romain; Hegan, Aimee; Négrel, Philippe

    2011-01-01

    International audience In the present work, we report chemical and isotope data for 23 geothermal water samples from the Taupo Volcanic Zone (TVZ) in New Zealand. The Taupo Volcanic Zone has anomalously high heat flow and widespread hydrothermal activity. Chemical and isotope data were analyzed for these deep geothermal waters in order to provide further constraints on the characterization of the associated deep geothermal reservoirs. The present study aims therefore to characterize the fl...

  6. A multi-isotope approach (N-, S-, O, Sr and Pb) to estimate the impact of long distance air pollution on sensitive alpine karst groundwater

    Full text: Karst and other sensitive aquifers contribute up to 90 % to the total drinking water supply in some European regions. However, they are more vulnerable to contamination than other aquifers due to short transfer times from recharge to source. Therefore, the main objective of this study is to show possibilities to quantify the impact of even small long distance air pollution on sensitive water resources (e.g. karst). In spite of strong efforts initiated by the European Union and other international organisations in the past 20 years, air pollution from industry, traffic and agriculture is still significant. Transboundary transport processes by atmospheric circulation are responsible for its long range distribution. There is evidence that even remote mountainous regions in the Pyrenees or Alps as well as the Mediterranean islands are contaminated by inorganic and organic airborne pollution. This is most evident on the surface, but also may penetrate straight into aquifers, particularly in carbonate areas with strong karstification. In a pilot study precipitation, soil, rock and spring waters were collected in a small catchment at the front of the Northern Calcareous Alps to test the application of isotope analyzes to estimate the amount of far transported contaminants and their impact on the spring water quality. The hydrochemistry and the isotopic composition of nitrate, sulphate, strontium, lead and the water molecule itself has been analyzed in five laboratories, each of them specialized in a certain group of isotopes. Comparison of strontium isotope measurements in precipitation, spring waters and dolomite bedrock in a relatively pristine and remote area at the front-range of the Northern Calcareous Alps in Austria with literature data indicate that 87Sr/86Sr isotope ratios in participation (0.7092) support at least a more radiogenic, far transported source in addition to a possible recycling of local dolomite and limestone dust (0.7080-0.7083). Spring

  7. Isotopic characteristics (Nd and Sr) of the intrusive plutonism at the northwestern Amazonian Craton, Venezuela, and implications for the Paleoproterozoic evolution

    Nd and Sr analyses were performed on selected granitoid plutons that intrude Archean and Paleoproterozoic domains of the Guyana shield (Venezuela). The isotopic signatures of these plutons together with the geochronologic background of the country rocks are used to constrain their magma genesis and tectonic setting within the Paleoproterozoic evolutions of mobile belts (Maroni-Itacaiunas and Ventuari-Tapajos provinces) of the Amazonian Craton. The Encrucijada Suite (2187 +- 94 Ma), which intrudes Archean rocks of the Imataca Complex, originated predominantly from partial melt of this crust, as supported by negative epsilonNd(2.1Ga) values (-2.2 to - 4.9) and TDM ages between 2.82 and 2.49 Ga. Conversely, the plutons from the Supamo Complex (2230 - 2050 Ma) and Cuchivero Group (1980 - 1830 Ma), occurring within the adjoining Paleoproterozoic provinces, are juvenile in nature (derived from roughly contemporary protoliths). These bodies display TDM ages between 2.13 and 2.22 Ga, as well as positive epsilonNd(2.1Ga) values (+0.74 to + 3.05). Isotopic correlation diagrams 143 Nd/144 Nd vs. 147 Sm/144 Nd and 143 Nd/144 Nd vs. time) plotted together with the plutonic rocks and Imataca Complex rocks were evaluated taking into account the geologic background of the NW part of the Amazonian Craton. Interpretation of these isotopic data supports the idea of tectonic juxtaposition between the Imataca Complex and the Maroni-Itacaiunas province during the Transamazonian orogeny (2.25 - 2.05 Ga). On the other hand, the Cuchivero Group plutons have a contrasting isotopic signature compared to the other Paleoproterozoic plutonic rocks. This is consistent with the existence of a tectonic boundary between the Maroni-Itacaiunas and the Ventuari-Tapajos province in the late Paleoproterozoic. (author)

  8. A Sr-Nd isotopic study of sand-sized sediment provenance and transport for the San Francisco Bay coastal system

    Rosenbauer, Robert J.; Foxgrover, Amy C.; Hein, James R.; Swarzenski, Peter W.

    2013-01-01

    A diverse suite of geochemical tracers, including 87Sr/86Sr and 143Nd/144Nd isotope ratios, the rare earth elements (REEs), and select trace elements were used to determine sand-sized sediment provenance and transport pathways within the San Francisco Bay coastal system. This study complements a large interdisciplinary effort (Barnard et al., 2012) that seeks to better understand recent geomorphic change in a highly urbanized and dynamic estuarine-coastal setting. Sand-sized sediment provenance in this geologically complex system is important to estuarine resource managers and was assessed by examining the geographic distribution of this suite of geochemical tracers from the primary sources (fluvial and rock) throughout the bay, adjacent coast, and beaches. Due to their intrinsic geochemical nature, 143Nd/144Nd isotopic ratios provide the most resolved picture of where sediment in this system is likely sourced and how it moves through this estuarine system into the Pacific Ocean. For example, Nd isotopes confirm that the predominant source of sand-sized sediment to Suisun Bay, San Pablo Bay, and Central Bay is the Sierra Nevada Batholith via the Sacramento River, with lesser contributions from the Napa and San Joaquin Rivers. Isotopic ratios also reveal hot-spots of local sediment accumulation, such as the basalt and chert deposits around the Golden Gate Bridge and the high magnetite deposits of Ocean Beach. Sand-sized sediment that exits San Francisco Bay accumulates on the ebb-tidal delta and is in part conveyed southward by long-shore currents. Broadly, the geochemical tracers reveal a complex story of multiple sediment sources, dynamic intra-bay sediment mixing and reworking, and eventual dilution and transport by energetic marine processes. Combined geochemical results provide information on sediment movement into and through San Francisco Bay and further our understanding of how sustained anthropogenic activities which limit sediment inputs to the system (e

  9. Stages of weathering mantle formation from carbonate rocks in the light of rare earth elements (REE) and Sr-Nd-Pb isotopes

    Hissler, Christophe; Stille, Peter

    2015-04-01

    Weathering mantles are widespread and include lateritic, sandy and kaolinite-rich saprolites and residuals of partially dissolved rocks. These old regolith systems have a complex history of formation and may present a polycyclic evolution due to successive geological and pedogenetic processes that affected the profile. Until now, only few studies highlighted the unusual high content of associated trace elements in weathering mantles originating from carbonate rocks, which have been poorly studied, compared to those developing on magmatic bedrocks. For instance, these enrichments can be up to five times the content of the underlying carbonate rocks. However, these studies also showed that the carbonate bedrock content only partially explains the soil enrichment for all the considered major and trace elements. Up to now, neither soil, nor saprolite formation has to our knowledge been geochemically elucidated. Therefore, the aim of this study was to examine more closely the soil forming dynamics and the relationship of the chemical soil composition to potential sources. REE distribution patterns and Sr-Nd-Pb isotope ratios have been used because they are particularly well suited to identify trace element migration, to recognize origin and mixing processes and, in addition, to decipher possible anthropogenic and/or "natural" atmosphere-derived contributions to the soil. Moreover, leaching experiments have been applied to identify mobile phases in the soil system and to yield information on the stability of trace elements and especially on their behaviour in these Fe-enriched carbonate systems. All these geochemical informations indicate that the cambisol developing on such a typical weathering mantle ("terra fusca") has been formed through weathering of a condensed Bajocian limestone-marl facies. This facies shows compared to average world carbonates important trace element enrichments. Their trace element distribution patterns are similar to those of the soil

  10. Geology, mineralization, U-Pb dating and Sr-Nd isotope geochemistry of intrusive bodies in northeast of Kashmar

    Alireza Almasi

    2015-04-01

    Full Text Available Alireza Almasi1, Mohammad Hassan Karimpour1*, Khosrow Ebrahimi Nasrabadi1, Behnam Rahimi1, Urs KlÖtzli2 and Jose Francisco Santos3 Introduction The study area is located in central part of the Khaf- Kashmar-Bardeskan belt which is volcano-plutonic belt at the north of the Dorouneh fault in the north of Lut block. The north of the Lut block is affected by tectonic rotation and subduction processes which occur in the east of Iran (Tirrul et al., 1983. The magmatism of Lut block begins in Jurassic and continues in Tertiary (Aghanabati, 1995. Karimpour (Karimpour, 2006 pointed out the Khaf-Kashmar-Bardeskan belt has significant potential for IOCG type mineralization such as Kuh-e-Zar, Tannurjeh, and Sangan (Karimpour, 2006; Mazloumi, 2009. The data gathered on the I-type intrusive rocks include their field geology, petrography, U–Pb zircon dating and Sr–Nd isotope and also alteration and mineralization in the study area. Materials and methods - Preparation of 150 thin sections of rock samples for study of petrography and alteration of the intrusive rocks. - Magnetic susceptibility measuring of intrusive rocks. - U-Pb dating in zircon of I-type intrusive rocks by Laser-Ablation Multi Collector ICP-MS method. - Sr-Nd analysis on 5 samples of I-type intrusive rocks by Multi-Collector Thermal Ionization Mass Spectrometer (TIMS VG Sector 54 instrument. - Mineralography and paragenetic studies of ore-bearing quartz veins and geochemical analysis for 28 samples. - Production of the geology, alteration and mineralization maps by scale: 1:20000 in GIS. Results Oblique subduction in southern America initiated an arc-parallel fault and shear zones in the back of continental magmatic arc (Sillitoe, 2003. Because of this event, pull-apart basins were formed and high-K to shoshonitic calc-alkalineI- and A-type magmatism occur (Sillitoe, 2003. Most important deposits accompany with this magmatism are Au-Cu deposits types and Fe-Skarns (Sillitoe, 2003. We have

  11. Important role of magma mixing in generating the Mesozoic monzodioritic-granodioritic intrusions related to Cu mineralization, Tongling, East China: Evidence from petrological and in situ Sr-Hf isotopic data

    Chen, C. J.; Chen, B.; Li, Z.; Wang, Z. Q.

    2016-04-01

    The Mesozoic ore-bearing high-Mg monzodioritic-granodioritic rocks in the Tongling mining district (East China) have been described as having adakitic affinities, and their origin has been attributed to partial melting of delaminated eclogite at depth in the mantle, followed by interaction of the resultant granitic magma with mantle peridotite. Here we present petrological data and in situ Sr isotopic data for zoned plagioclase that are inconsistent with the eclogite-derived model and instead propose a model that involves magma mixing of siliceous crustal melts and basaltic magma that was derived from metasomatized mantle in a back-arc extensional regime. The principal geochemical signatures of these Mesozoic rocks include a high-K calc-alkaline affinity, high values of Mg#, high Sr-Ba abundances, high Sr/Y and La/Yb ratios, εNd(t) = - 13.1 to - 9.0, and ISr = 0.70707-0.70824. The magma mixing model is supported by (1) the common existence of mafic microgranular enclaves (MMEs) and the disequilibrium textures of plagioclase and amphibole, (2) the 87Sr/86Sr ratios of embayed high-Ca cores of plagioclase that are distinctly lower than in the euhedral low-Ca overgrowth rims, (3) the negative correlations between whole-rock Nd and Sr isotopic ratios, and (4) the significant differences in the values of εHf(t) (- 9.5 to - 26) within different zircons from the same intrusion.

  12. Rb/Sr and U/Pb isotopic ages in basement rocks of Mina Gonzalito and Arroyo Salado, Atlantic North-Patagonian Massif, Rio Negro, Argentina

    Isotopic ages from metamorphic and plutonic rocks of the Atlantic area of North Patagonian basement indicate that the main crustal tectonic events occurred during the late Proterozoic to early Paleozoic times. Rb/Sr and U/Pb data in the 550-470 Ma interval suggest an old tecto-thermal activity during the upper Brazilian Cycle (Rio Doce Orogeny). At regional scale, the comparable Neo proterozoic basement of Ventania and sedimentary for eland cover of Tandilia continues to the Northeast, in the Dom Feliciano Belt. A possible correlation of the North Patagonian basement with igneous-metamorphic relics of Central Argentina (Pampean Ranges of San Luis-Cordoba and at La Pampa province) is also indicated. (author)

  13. C, Sr and Pb isotopic chemostratigraphy in precambrian carbonate sequences in the eastern transversal domain of the Borborema Province, northastern Brazil

    The Transversal Domain, in the Borborema Structural Province, northeastern Brazil, is characterized by a system of NE-trending, left-lateral, transcurrent mega-structure and dextral E-W trending fault zones (Jardim de Sa, 1994). This domain is formed by supracrustal metasedimentary and metavolcansedimentary sequences overlying a gneissic-migmatitic basement. Geological sequences of this domain exhibit distinct lithotectono-stratigraphy that characterize different terranes, separated by shear zones developed during the Cariris Velhos cycle (1.1-0.95 Ga), and that have been reworked during the Brasiliano orogen at the end of the Neoproterozoic (Brito Neves et al., 1995). The objective of this work is to show the results of C, Sr and Pb isotope studies performed in marble lens located near (and in both sides) the proposed boundary between two tectono-stratigraphic terranes (Alto Moxoto and Rio Capibaribe) in the Transversal Domain (au)

  14. Accurate determination of sulfur in gasoline and related fuel samples using isotope dilution ICP-MS with direct sample injection and microwave-assisted digestion

    Heilmann, Jens; Boulyga, Sergei F.; Heumann, Klaus G. [Johannes Gutenberg-University, Institute of Inorganic Chemistry and Analytical Chemistry, Mainz (Germany)

    2004-09-01

    Inductively coupled plasma isotope-dilution mass spectrometry (ICP-IDMS) with direct injection of isotope-diluted samples into the plasma, using a direct injection high-efficiency nebulizer (DIHEN), was applied for accurate sulfur determinations in sulfur-free premium gasoline, gas oil, diesel fuel, and heating oil. For direct injection a micro-emulsion consisting of the corresponding organic sample and an aqueous {sup 34}S-enriched spike solution with additions of tetrahydronaphthalene and Triton X-100, was prepared. The ICP-MS parameters were optimized with respect to high sulfur ion intensities, low mass-bias values, and high precision of {sup 32}S/{sup 34}S ratio measurements. For validation of the DIHEN-ICP-IDMS method two certified gas oil reference materials (BCR 107 and BCR 672) were analyzed. For comparison a wet-chemical ICP-IDMS method was applied with microwave-assisted digestion using decomposition of samples in a closed quartz vessel inserted into a normal microwave system. The results from both ICP-IDMS methods agree well with the certified values of the reference materials and also with each other for analyses of other samples. However, the standard deviation of DIHEN-ICP-IDMS was about a factor of two higher (5-6% RSD at concentration levels above 100 {mu}g g{sup -1}) compared with those of wet-chemical ICP-IDMS, mainly due to inhomogeneities of the micro-emulsion, which causes additional plasma instabilities. Detection limits of 4 and 18 {mu}g g{sup -1} were obtained for ICP-IDMS in connection with microwave-assisted digestion and DIHEN-ICP-IDMS, respectively, with a sulfur background of the used Milli-Q water as the main limiting factor for both methods. (orig.)

  15. Non-depleted sub-continental mantle beneath the Superior Province of the Canadian Shield: Nd-Sr isotopic and trace element evidence from Midcontinent Rift basalts

    Paces, J.B. (Michigan Technological Univ., Houghton (USA)); Bell, K. (Carleton Univ., Ottawa, Ontario (Canada))

    1989-08-01

    Midcontinent Rift flood basalts represent a sample of the relatively shallow, sub-continental upper mantle beneath the Canadian Shield at 1.1 Ga. A thick sequence of olivine tholeiite lavas, including minor intermediate to rhyolitic lavas, from the Portage Lake Volcanics (PLV) in northern Michigan have initial Nd and Sr isotopic compositions which cluster near Bulk Earth values. The effects of assimilation of old LREE-enriched continental crust into mantle-derived fractionating liquids are isotopically discernible in evolved lavas as well as in olivine tholeiites from the lowest portion of the volcanic pile. However, the effects of crustal contamination decrease with stratigraphic height and are absent in more primitive lavas in the upper half of the section. The source for PLV tholeiites is substantially less depleted than previously reported mantle values from the Superior Province. An origin for the PLV source is compatible with either of several mantle evolution models. The PLV source may have been associated with upwelling of a LIL element-enriched, asthenospheric plume which emplaced non-depleted material from deeper sources into the shallow sub-continental mantle beneath the Midcontinent Rift during continental break-up. Alternatively, the PLV source may have originated by enrichment of refractory sub-continental lithospheric mantle which was previously depleted in incompatible trace elements during Archean-aged melt extraction and continental crust formation. Concurrent generation of carbonatite magmas in other areas beneath the Superior Province indicates the widespread presence of sub-continental mantle with substantially higher {epsilon}{sub Nd}(T) and lower {epsilon}{sub Sr}(T) than the PLV source.

  16. Petrogenesis of Granitoids, U-Pb zircon geochronology, Sr-Nd Petrogenesis of granitoids, U-Pb zircon geochronology, Sr-Nd isotopic characteristics, and important occurrence of Tertiary mineralization within the Lut block, eastern Iran

    M.H. Karimpour

    2012-04-01

    Full Text Available Tertiary intrusive granitoids within the Lut block in the Khorasan Razavi and South Khorasan provinces are mainly sub-volcanic with porphyry texture and their composition varies from granite to diorite but monzonite is dominant. With the exception of Hired, these are classified as belonging to the magnetite-series of I-type granitoids. Chemically, these rocks are meta-aluminous. Those with mineralization are K-rich and those without mineralization such as Najmabad are Na-rich. All intrusive rocks plot in the field of calc-alkaline to adakite except Najmabad that plot in the adakite field. Based on low content of Nb (30, low initial 87Sr/86Sr (17 ppm, low ratio of Zr/Nb (0.707 and low initial εNd value (-3, magmas in the Kaybar-Kuh were more contaminated in the continental crust. Based on depletion in HREE and high ratio of (La/YbN (17-23, magma in Najmabad originated in the deep region in which garnet was present. Based on REE pattern and ration of Eu/Eu* (0.8-1, intrusive rocks within Maherabad, Khoopik, Chah-Shaljami, Kuh Shah and Dehsalm are calc-alkaline and their magma formed in an oxidant condition whereas Kaybar Kuh magma with low ratio of Eu/Eu* (<0.8 was contaminated in the continental crust under reduced conditions. The age of these granitoids is between Middle Eocene and Lower Oligocene. Kaybar-Kuh (43.3 Ma is situated in the north and Chah-Shaljami (33.3 Ma in the south. The initial 87Sr/86Sr ratios decrease from north (0.7077 to south (0.7047 as the age decreases. εNd of Maherabad, Khoopik, Dehsalm, and Chah-Shaljami granitoids is between +0.5 and +2.49 and the initial 87Sr/86Sr ratio is less than 0.7055. The age of the source rock (TDM, which was calculated based on Sm-Nd isotopes indicates that these magma originated from oceanic crust with different ages. Kaybar-Kuh originated from the oldest oceanic crust (840 Ma and was contaminated more in continental crust, but Najmabad originated from a younger oceanic crust (360 Ma with

  17. Zircon U-Pb age, geochemical, and Sr-Nd-Pb isotopic constraints on the origin of alkaline intrusions in eastern Shandong Province, China

    Liu, Shen; Feng, Caixia; Hu, Ruizhong; Gao, Shan; Wang, Tao; Feng, Guangying; Qi, Youqiang; Coulson, Ian M.; Lai, Shaocong

    2013-08-01

    Alkaline intrusions in the eastern Shandong Province consist of quartz monzonite and granite. U-Pb zircon ages, geochemical data, and Sr-Nd-Pb isotopic data for these rocks are reported in the present paper. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon analyses yielded consistent ages ranging from 114.3 ± 0.3 to 122.3 ± 0.4 Ma for six samples of the felsic rocks. The felsic rocks are characterised by a wide range of chemical compositions (SiO2 = 55.14-77.63 wt. %, MgO = 0.09-4.64 wt. %, Fe2O3 = 0.56-7.6 wt. %, CaO = 0.40-5.2 wt. %), light rare earth elements (LREEs) and large ion lithophile elements (LILEs) (i.e., Rb, Pb, U) enrichment, as well as significant rare earth elements (HREEs) and heavy field strength (HFSEs) (Nb, Ta, P and Ti) depletion, various and high (87Sr/86Sr) i ranging from 0.7066 to 0.7087, low ɛ Nd (t) values from -14.1 to -17.1, high neodymium model ages (TDM1 = 1.56-2.38Ga, TDM2 = 2.02-2.25Ga), 206Pb/204Pb = 17.12-17.16, 207Pb/204Pb = 15.44-15.51, and 208Pb/204Pb = 37.55-37.72. The results suggested that these rocks were derived from an enriched crustal source. In addition, the alkaline rocks also evolved as the result of the fractionation of potassium feldspar, plagioclase, +/- ilmenite or rutile and apatite. However, the alkaline rocks were not affected by crustal contamination. Moreover, the generation of the alkaline rocks can be attributed to the structural collapse of the Sulu organic belt due to various processes.

  18. Rb-Sr and Sm-Nd isotopic and REE studies of igneous components in the bulk matrix domain of Martian breccia Northwest Africa 7034

    Nyquist, Laurence E.; Shih, Chi-Yu; McCubbin, Francis M.; Santos, Alison R.; Shearer, Charles K.; Peng, Zhan X.; Burger, Paul V.; Agee, Carl B.

    2016-03-01

    The bulk matrix domain of the Martian breccia NWA 7034 was examined petrographically and isotopically to better understand the provenance and age of the source material that make up the breccia. Both 147Sm-143Nd and 146Sm-142Nd age results for mineral separates from the bulk matrix portion of breccia NWA 7034 suggest that various lithological components in the breccia probably formed contemporaneously ~4.44 Ga ago. This old age is in excellent agreement with the upper intersection ages (4.35-4.45 Ga) for U-Pb discordia and also concordia defined by zircon and baddeleyite grains in matrix and igneous-textured clasts. Consequently, we confirm an ancient age for the igneous components that make up the NWA 7034 breccia. Substantial disturbance in the Rb-Sr system was detected, and no age significance could be gleaned from our Rb-Sr data. The disturbance to the Rb-Sr system may be due to a thermal event recorded by bulk-rock K-Ar ages of 1.56 Ga and U-Pb ages of phosphates at about 1.35-1.5 Ga, which suggest partial resetting from an unknown thermal event(s), possibly accompanying breccia formation. The NWA 7034 bulk rock is LREE enriched and similar to KREEP-rich lunar rocks, which indicates that the earliest Martian crust was geochemically enriched. This enrichment supports the idea that the crust is one of the enriched geochemical reservoirs on Mars that have been detected in studies of other Martian meteorites.

  19. C, O and Sr isotopic stratigraphy of carbonates pre and pos Jequitai glaciation: Bezerra-Formosa area, Goias, BR;Variacoes dos isotopos de C e Sr em carbonatos pre e pos-glaciacao Jequitai (Esturtiano) na regiao de Bezerra-Formosa, Goias

    Alvarenga, Carlos Jose Souza de; Della Giustina, Maria Emilia Schuteski; Silva, Nivea Goulart Carramal; Santos, Roberto Ventura; Gioia, Simone Maria Costa Lima; Guimaraes, Edi Mendes; Dardenne, Marcel Auguste, E-mail: alva1@unb.b [Universidade de Brasilia (IG/UnB), DF (Brazil). Inst. de Geociencias; Sial, Alcides Nobrega; Ferreira, Valderez Pinto [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Lab. de Isotopos Estaveis (LABISE)

    2007-12-15

    Carbonate rocks of the upper Paranoa Group and lower Bambui Group (Sete Lagoas Formation) have been founded at the occidental border of the Sao Francisco craton. These units have been separated by the Sturtian glaciation, identified by Jequitai Formation, but in some localities the glacial record is absent and is difficult to separate these two carbonates units. In this paper two sections with a good stratigraphic control have been chosen to find C, O and Sr isotopic values to have tools for the correlations. Carbonates of the Paranoa Group present a trend of positive {delta}{sup 13}C{sub PDB} varying between +0.8 e +2.7 %o, of {delta}{sup 18}O{sub PDB} varying between -9.0 e -4.7 %o and {sup 87}Sr/{sup 86}Sr ranging from 0.7063 to 0.7068. The diamictite sample of Jequitai Formation has {delta}{sup 13}C{sub PDB} values of -1.8%o and {delta}{sup 18}O{sub PDB} values of -5.1%o. The cap dolomites of the Sete Lagoas Formation are associated with an extremely negative {delta}{sup 13}C{sub PDB} values between -6.0 e -3.2 %o, {delta}{sup 18}O{sub PDB} values between -9.1 e -5.3%o and high {sup 87}Sr/{sup 86}Sr ratios suggesting a radiogenic Sr isotope anomaly. Limestone and muddy-limestone above the cap dolomite still starts with extremely negative {delta}{sup 13}C{sub PDB} values (-6.0%o) and are followed by an upward trend of increasing carbon isotope values up to +9.2 %o. In the same interval the {delta}{sup 18}O{sub PDB} values ranging from -10.1%o at the base to -5.5%o in direction to the top of formation and primary {sup 87}Sr/{sup 86}Sr ratios between 0.70745 and 0.70758. The Carbon and Sr isotope data presented here reveal significant differences between carbonates from the Paranoa Group and the Bambui Group. These data developed here provides the framework for a new regional isotopic correlation model to the carbonates units of the Paranoa and Bambui groups. (author)

  20. Petrogenesis of Tertiary continental intra-plate lavas between Siebengebirge and Westerwald, Germany: Constraints from trace element systematics and Nd, Sr and Pb isotopes

    Schubert, S.; Jung, S.; Pfänder, J. A.; Hauff, F.; Garbe-Schönberg, D.

    2015-10-01

    New 39Ar/40Ar ages and major- and trace-element and radiogenic isotope data are presented for basanites and alkali basalts from the transition area between the Westerwald and Siebengebirge volcanic fields (Germany) that belongs to the Central European Volcanic Province (CEVP). The 39Ar/40Ar ages indicate ages of c. 24 and c. 5 Ma which are fully compatible with previous K/Ar ages indicating that the evolution of this volcanic field belongs to the Westerwald area (28-22 Ma and 5 Ma) rather than to the Siebengebirge area (26-23 Ma). Based on the occurrence of > 30 isolated volcanic plugs with a simple igneous history, this volcanic field can be viewed as a monogenetic volcanic field. Compositions of some basanites are primitive, whereas others and the alkali basalts show decreasing Cr and Ni contents and CaO/Al2O3 ratios. However, increasing TiO2, Al2O3 and incompatible elements (Sr, Zr, Y, Hf, Ta) concentrations with decreasing MgO indicating fractionation of mainly olivine with minor amounts of clinopyroxene and spinel can be noticed. Rare earth element systematics suggest that most of the alkaline rocks are generated by different degrees of melting (5%-10%) of a garnet-bearing peridotite containing some residual amphibole. Negative anomalies of Rb and K in primitive mantle-normalized diagrams and a lack of Ba/Rb fractionation suggest that amphibole was the major OH-bearing mineral phase in the mantle. The alkaline rocks have a restricted range in 87Sr/86Sr and 143Nd/144Nd ratios ranging from 0.7033 to 0.7044 and from 0.51275 to 0.51285, respectively. Lead isotope compositions (206Pb/204Pb: 19.21-19.65; 207Pb/204Pb: 15.62-15.67; 208Pb/204Pb: 39.10-39.46) of the alkaline rocks are within the range of most OIB in which the higher values approach the composition of the European Asthenospheric Reservoir (EAR). The correlation between Sr and Nd isotopes and trace element constraints (Ce/Pb; Nb/U) indicates that for some samples interaction with crustal rocks during

  1. Geochemistry of major and trace elements and Pb–Sr isotopes of a weathering profile developed on the Lower Cambrian black shales in central Hunan, China

    Highlights: • The chemical changes during black shale weathering are geochemically estimated. • Chemical changes and Pb–Sr data suggest four types of chemical reactions. • There were two stages of geochemical processes during black shale weathering. • Early stage of chemical differentiation led elements leaching and redistribution. • Soil was formed by later chemical homogenisation after the early differentiation. - Abstract: This paper reports a geochemical study on the major and trace elements and Pb–Sr isotopes of a weathering profile developed in the Lower Cambrian black shales in central Hunan (China). Six weathering horizons were identified and sampled vertically throughout the profile. The chemical composition of the profile consists of variable concentrations of the major elements Fe2O3, FeO, MnO, MgO, CaO, Na2O, and P2O5 and of less variable concentrations of SiO2, TiO2, Al2O3, and K2O. The chemical change caused by weathering is estimated by mass-balance calculations, and the results show that the element mobility is characterised by substantial loss of SiO2, FeO, CaO, K2O, Na2O, LOI, Cr, V, Ba, Cs, Rb, Sr, U, and Th, and moderate loss of Al2O3, MgO, Fe2O3, Ni, Cu, Pb, Tl, Sn, Sc, Ge and REE (Y). The high field strength elements TiO2, Sn, Sc, U, Ga, Ge, Zr, Hf, Nb, and Ta were immobile during weathering. The chemical changes and the Pb–Sr isotopic data suggest that four types of chemical reactions occurred: the oxidation of sulphide minerals (e.g., pyrite) and organic carbon (OS), the dissolution of less resistant clinochlore-Ia, calcite, and P-bearing minerals (DL), the dissolution of detrital albite and microcline (DA), and the transformation of clay (TC) minerals (e.g., muscovite and illite–smectite). These chemical reactions then led to two stages of geochemical processes, an early stage of chemical differentiation and a later stage of chemical homogenisation. The chemical differentiation dominated by the OS, DL, and DA reactions

  2. Paleoproterozoic crustal evolution in the East Sarmatian Orogen: Petrology, geochemistry, Sr-Nd isotopes and zircon U-Pb geochronology of andesites from the Voronezh massif, Western Russia

    Terentiev, R. A.; Savko, K. A.; Santosh, M.

    2016-03-01

    Andesites and related plutonic rocks are major contributors to continental growth and provide insights into the interaction between the mantle and crust. Paleoproterozoic volcanic rocks are important components of the East Sarmatian Orogen (ESO) belonging to the East European Craton, although their petrogenesis and tectonic setting remain controversial. Here we present petrology, mineral chemistry, bulk chemistry, Sr-Nd isotopes, and zircon U-Pb geochronological data from andesites and related rocks in the Losevo and Vorontsovka blocks of the ESO. Clinopyroxene phenocrysts in the andesites are depleted in LREE, and enriched in HFSE (Th, Nb, Zr, Hf, Ti) and LILE (Ba, Sr). Based on the chemistry of pyroxenes and whole rocks, as well as Fe-Ti oxides, we estimate a temperature range of 1179 to 1262 °C, pressures of 11.3 to 13.0 kbar, H2O content of 1-5 wt.%, and oxygen fu gacity close to the MH buffer for the melts of the Kalach graben (KG) and the Baygora area (BA) andesites. Our zircon U-Pb geochronological data indicate new zircon growth during the middle Paleoproterozoic as displayed by weighted mean 207Pb/206Pb ages of 2047 ± 17 Ma and 2040 ± 16 Ma for andesite and dacite-porphyry of the BA, and 2050 ± 16 Ma from high-Mg basaltic andesite of the KG. The andesites and related rocks of the KG and BA are characterized by high magnesium contents (Mg # up to 0.68). All these volcanic rocks are depleted in LREE and HFSE, and display negative Nb and Ti anomalies relative to primitive mantle. The high-Mg bulk composition, and the presence of clinopyroxene phenocrysts suggests that the parent melts of the KG and BA suite were in equilibrium with the mantle rocks. The rocks show positive εNd(T) values and low initial 87Sr/86Sr, suggesting that the magmas were mostly derived from metasomatized mantle source. The geochemical differences between the two andesite types are attributed to: the predominance of fractional crystallization, and minor role of contamination in the

  3. Accurate multiconfiguration calculations of energy levels, lifetimes, and transition rates for the silicon isoelectronic sequence. Ti IX - Ge XIX, Sr XXV, Zr XXVII, Mo XXIX

    Jönsson, P.; Radžiūtė, L.; Gaigalas, G.; Godefroid, M. R.; Marques, J. P.; Brage, T.; Froese Fischer, C.; Grant, I. P.

    2016-01-01

    Multiconfiguration Dirac-Hartree-Fock (MCDHF) calculations and relativistic configuration interaction (RCI) calculations are performed for states of the 3s23p2, 3s3p3 and 3s23p3d configurations in the Si-like ions Ti IX - Ge XIX, Sr XXV, Zr XXVII and Mo XXIX. Valence and core-valence electron correlation effects are accounted for through large configuration state function expansions. Calculated energy levels are compared with data from other calculations and with experimental data from the reference databases. Lifetime and transition rates along with uncertainty estimations are given for all ions. Energies from the calculations are in excellent agreement with observations and computed wavelength are almost of spectroscopic accuracy, aiding line identification in spectra. Full Tables 2, 3, and 5 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/585/A26

  4. Stable (O, H) and Sr isotope tracing of the Narces de la Sauvetat peatland (Massif Central, France) water fluxes

    Brenot, Agnès; Négrel, Philippe; Millot, Romain; Bertin, Clotilde

    2011-01-01

    Increasing efforts were engaged to restore degraded or lost wetlands and to manage wetlands sustainably in order to assess their multiple benefits during the past decades. In this context, important knowledge on the water cycle in the wetlands is required to manage specific actions to restore and preserve these areas. In this study, we propose to use chemical and multi-isotopic approaches combined with hydrological measurements (piezometric level and stream flow measurements) to trace the flu...

  5. Sr, C and O isotopes as markers of alkaline disturbances in the Toarcian argillites of the Tournemire experimental platform (France). Case of a 15-years old engineered analogue.

    Techer, I.; Boulvais, P.; Bartier, D.; Tinseau, E.

    2009-04-01

    argillites close to the cement-concrete contact. These data are detailed in another session of this meeting (Techer et al., ERE6 session). In order to precise the spatial extent of the disturbances and to discuss the nature of the responsible fluids, a systematic chemical and isotopic study was performed focusing on the Sr, C and O isotopes known to be very good markers of alkaline fluids percolation (Fourcade et al. 2006). Four studied levels were selected according to their location on the DM overcore and the nature of the cementitious material in contact to the argillites: -155 cm level (DM155) and -180 cm level (DM180) where argillites were in contact with a 1.5 to 3 cm thick concrete; -245 cm level (DM245) and -300 cm level (DM300) where the cementitious material was represented by a fine grained Portland cement 2 to 5 cm thick. Samples of the cementitious materials were collected at each level. Argillites were sampled perpendicularly to the cement-concrete contact with a continuous sampling every 2 to 5 mm millimeters (P1). Micro-fissures developed perpendicularly to the cement-concrete contact were opened and infilling secondary minerals were collected by scrap as a function of the distance to the cement-concrete (P3). Along P1 and P3, no significant variation of the carbonates d18O isotopic values was observed in the argillites. On the opposite d13C and 87Sr/86Sr values of these minerals changed significantly in the direct contact with the cement-concrete over a distance of 15 to 25 mm. Beyond this distance, argillites were again well bedded and showed values similar to those measured in a reference sample. Negative d13C values measured in the disturbed zone and close to those encountered in the cement and the concrete argued for a perturbation induced by an alkaline solution. 87Sr/86Sr isotopic ratios showed a progressive evolution in the disturbed zone, with increasing trends towards the cementitious material. Thanks to complementary Sr elementary contents

  6. Accurate Quantification of Selenoprotein P (SEPP1) in Plasma Using Isotopically Enriched Seleno-peptides and Species-Specific Isotope Dilution with HPLC Coupled to ICP-MS/MS.

    Deitrich, Christian L; Cuello-Nuñez, Susana; Kmiotek, Diana; Torma, Frank Attila; Del Castillo Busto, Maria Estela; Fisicaro, Paola; Goenaga-Infante, Heidi

    2016-06-21

    A novel strategy for the absolute quantification of selenium (Se) included in selenoprotein P (SEPP1), an important biomarker for human nutrition and disease, including diabetes and cancer, is presented here for the first time. It is based on the use of species-specific double isotope dilution mass spectrometry (SSIDA) in combination with HPLC-ICP-MS/MS for the determination of protein bound Se down to the peptide level in a complex plasma matrix with a total content of Se of 105.5 μg kg(-1). The method enabled the selective Se speciation analysis of human plasma samples without the need of extensive cleanup or preconcentration steps as required for traditional protein mass spectrometric approaches. To assess the method accuracy, two plasma reference materials, namely, BCR-637 and SRM1950, for which literature data and a reference value for SEPP1 have been reported, were analyzed using complementary hyphenated methods and the species-specific approach developed in this work. The Se mass fractions obtained via the isotopic ratios (78)Se/(76)Se and (82)Se/(76)Se for each of the Se-peptides, namely, ENLPSLCSUQGLR (ENL) and AEENITESCQUR (AEE) (where U is SeCys), were found to agree within 2.4%. A relative expanded combined uncertainty (k = 2) of 5.4% was achieved for a Se (as SEPP1) mass fraction of approximately 60 μg kg(-1). This work represents a systematic approach to the accurate quantitation of plasma SEPP1 at clinical levels using SSIDA quantification. Such methodology will be invaluable for the certification of reference materials and the provision of reference values to clinical measurements and clinical trials. PMID:27108743

  7. Rapid and precise determination of Sr and Nd isotopic ratios in geological samples from the same filament loading by thermal ionization mass spectrometry employing a single-step separation scheme

    Li Chaofeng, E-mail: cfli@mail.iggcas.ac.cn [State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029 (China); School of Earth Sciences, Graduate University of Chinese Academy of Sciences, Beijing 100039 (China); Li Xianhua; Li Qiuli; Guo Jinghui; Li Xianghui; Yang Yueheng [State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029 (China)

    2012-05-21

    Graphical abstract: Our analytical protocol compared with traditional methods. Highlights: Black-Right-Pointing-Pointer Sr and Nd from the same filament loading were sequentially measured without venting using TIMS. Black-Right-Pointing-Pointer This protocol shows a great improvement in the analytical efficiency. Black-Right-Pointing-Pointer Experimental costs and labour intensity are significantly cut down. - Abstract: Thermal ionization mass spectrometry (TIMS) offers the excellent precision and accuracy of the Sr and Nd isotopic ratio analysis for geological samples, but this method is labour intensive, expensive and time-consuming. In this study, a new analytical protocol by TIMS is presented that aims at improving analytical efficiency and cutting down experimental cost. Using the single-step cation exchange resin technique, mixed Sr and rare earth elements (REEs) fractions were separated from matrix and evaporated to dryness. Afterwards, mixed Sr + REEs fractions were dissolved and loaded onto the same Re filament using 1 {mu}L of 2 M HCl. Then, Sr and Nd were sequentially measured without venting using TIMS. In contrast to conventional TIMS methods, the merits of this analytical protocol are its cost- and time-saving adaptations. The applicability of our method is evaluated by replicated measurements of {sup 87}Sr/{sup 86}Sr and {sup 143}Nd/{sup 144}Nd for nine international silicate rock reference materials, spanning a wide range of bulk compositions. The typical internal precision in this study is ca. 0.001% (RSE) for {sup 87}Sr/{sup 86}Sr and {sup 143}Nd/{sup 144}Nd; the analytical results obtained for these standard rocks show a good agreement with reported values, indicating the effectiveness of the proposed method.

  8. Zircon U-Pb ages, geochemical and Sr-Nd-Pb-Hf isotopic constraints on petrogenesis of the Tarom-Olya pluton, Alborz magmatic belt, NW Iran

    Nabatian, Ghasem; Jiang, Shao-Yong; Honarmand, Maryam; Neubauer, Franz

    2016-02-01

    A petrological, geochemical and Sr-Nd-Pb isotopic study was carried out on the Tarom-Olya pluton, Iran, in the central part of the Alpine-Himalayan orogenic belt. The pluton is composed of diorite, monzonite, quartz-monzonite and monzogranite, which form part of the Western Alborz magmatic belt. LA-ICP-MS analyses of zircons yield ages from 35.7 ± 0.8 Ma to 37.7 ± 0.5 Ma, interpreted as the ages of crystallization of magmas. Rocks from the pluton have SiO2 contents ranging from 57.0 to 69.9 wt.%, high K2O + Na2O (5.5 to 10.3 wt.%) and K2O/Na2O ratio of 0.9 to 2.0. Geochemical discrimination criteria show I-type and shoshonitic features for the studied rocks. All investigated rocks are enriched in light rare earth elements (LREEs), large ion lithophile elements (LILEs), depleted in high-field strength elements (HFSEs), and show weak or insignificant Eu anomalies (Eu/Eu* = 0.57-1.02) in chondrite-normalized trace element patterns. The Tarom-Olya pluton samples also show depletions in Nb, Ta and Ti typical of subduction-related arc magmatic signatures. The samples have relatively low ISr (0.7047-0.7051) and positive εNd(36 Ma) (+ 0.39 to + 2.10) values. The Pb isotopic ratios show a (206Pb/204Pb)i ratio of 18.49-18.67, (207Pb/204Pb)i ratio of 15.58-15.61 and (208Pb/204Pb)i ratio of 38.33-38.77. The εHf(t) values of the Tarom-Olya pluton zircons vary from - 5.9 to + 8.4, with a peak at + 2 to + 4. The depleted mantle Hf model ages for the Tarom-Olya samples are close to 600 Ma. These isotope evidences indicate contribution of juvenile sources in petrogenesis of the Tarom-Olya pluton. Geochemical and isotopic data suggest that the parental magma of the Tarom-Olya pluton was mainly derived from a sub-continental lithospheric mantle source, which was metasomatized by fluids and melts from the subducted Neotethyan slab with a minor crustal contribution. Subsequent hot asthenospheric upwelling and lithospheric extension caused decompression melting in the final stage of

  9. Influence of the Sierra Leone mantle plume on the equatorial Mid-Atlantic Ridge: A Nd-Sr-Pb isotopic study

    Schilling, J.-G.; Hanan, B. B.; McCully, B.; Kingsley, R. H.; Fontignie, D.

    1994-06-01

    We report on a Pb-Nd-Sr isotope and rare earth study of Mid-Atlantic Ridge (MAR) basalt glasses collected across the equatorial fracture zones from 7°S to 5°N (65 stations). The 1600-km-long profile reveals two mixing zones in the mantle that are isotopically distinct but cover the same range of (La/Sm)n ratios (0.3-2), with a gradational boundary between the Romanche and the Chain fracture zones. The potential mantle temperature profile inferred from Na2O content is also quite distinct. The north zone is dominated by a major, La/Sm and HIMU type Pb isotope anomaly centered at 1.7°N±300 km, which is flanked by two zones mildly radiogenic in Pb but depleted in light REE. A kinematic and evolutionary model describing the dispersion and interaction of the Sierra Leone plume with the asthenosphere and the MAR in the last 75 m.y. is proposed for this zone, which includes St. Paul and St. Peter's Rocks. In contrast, over the south zone the isotope/geochemical profiles are well correlated at all length scales and opposite in sign from the inferred potential mantle temperature profile and mean percent fusion. Broad negative gradients are observed between the Romanche and the Charcot fracture zones, superimposed by spikelike anomalies at the intersection with the eastern part of the Romanche and Chain transform faults, where cold plate edge effects prevail. The heterogeneous mantle model of Sleep [1984] and Langmuir and Bender [1984] is applicable to this zone, that is the volatile and radiogenic Pb-rich lumps are preferentially melted during mantle decompression and passively sampled. The lumps may reflect the early dispersion of the St. Helena or Ascension mantle plumes under a thick lithosphere, followed by redistribution due to intense shearing, continental lithosphere delamination, and secondary mantle convection. The presence of a depleted asthenosphere unpolluted by plumes along the 400-km-long MAR segment between the Charcot and Ascension fracture zones is also

  10. Crustal evolution of granitoids and gneisses from the Cambaizinho belt, southern Brazil: Review zircon Pb-Pb evaporation ages and Pb-Nd-Sr isotopes

    Deformed granitoids and gneisses from the Cambai Complex (900-700 Ma) along Cambaizinho Creek and in the Vila Nova do Sul region, state of Rio Grande do Sul, Brazil, were formed in a remarkably short time, about 10 m.y., between 704±13 and 697±3 Ma. The data base of this work includes eighteen zircon Pb/Pb evaporation analyses, five Pb isotope in feldspar and whole rock. The oldest known rocks in the region are polydeformed dioritic gneisses dated by conventional U-Pb zircon at 704±13 Ma. New Pb-Pb zircon evaporation data on the late transcurrent, less deformed and more evolved granitoids (Sanga do Jobim Granitoids) yield a 697± Ma age and indicates that the evolution of the plutonic magmatism in the area was nearly contemporaneous. These data contrast with previous interpretations based on Rb-Sr data which considered that these rock associations were formed during a longer time period (700-640 Ma). All these granitoids intruded the supracrustal sequence. These granitoids yield a minimum age of about 700 Ma for the formation of the supracrustal sequence and its regional dynamothermal metamorphism. Lead isotope composition of K-feldspar from Sanga do Jobim Granitoids plot close to, but slightly below the lead isotope evolution curve of orogeny in the Zartmann and Doe model (1981). This indicates that the setting for these granitoids was that of a juvenile magmatic arc. These new data plus previous data in the region also corroborate that the crustal evolution involved juvenile crust accreted between 760-700 Ma. In contrast, the Cacapava and Sao Sepe Granites intruded the supracrustal sequences along the eastern side of the Sao Gabriel Block at 562 Ma and 550 Ma, respectively, and show Pb and Nd isotope signatures from an old basement. This evidence suggests that the juvenile terrane was thrusted over the older basement situated along the eastern part of the shield during the Dom Feliciano collisional orogeny at about 620-590 Ma (au)

  11. U–Pb, Rb–Sr, and U-series isotope geochemistry of rocks and fracture minerals from the Chalk River Laboratories site, Grenville Province, Ontario, Canada

    Highlights: • AECL evaluates Chalk River Laboratories site as potential nuclear waste repository. • Isotope-geochemical data for rocks and fracture minerals at CRL site are reported. • Zircons from gneiss and granite yielded U–Pb ages of 1472 ± 14 and 1045 ± 6 Ma. • WR Rb–Sr and Pb–Pb systems do not show substantial large-scale isotopic mobility. • U-series and REE data do not support oxidizing conditions at depth in the past 1 Ma. - Abstract: As part of the Geologic Waste Management Facility feasibility study, Atomic Energy of Canada Ltd. (AECL) is evaluating the suitability of the Chalk River Laboratories (CRL) site in Ontario, situated in crystalline rock of the southwestern Grenville Province, for the possible development of an underground repository for low- and intermediate-level nuclear waste. This paper presents petrographic and trace element analyses, U–Pb zircon dating results, and Rb–Sr, U–Pb and U-series isotopic analyses of gneissic drill core samples from the deep CRG-series characterization boreholes at the CRL site. The main rock types intersected in the boreholes include hornblende–biotite (±pyroxene) gneisses of granitic to granodioritic composition, leucocratic granitic gneisses with sparse mafic minerals, and garnet-bearing gneisses with variable amounts of biotite and/or hornblende. The trace element data for whole-rock samples plot in the fields of within-plate, syn-collision, and volcanic arc-type granites in discrimination diagrams used for the tectonic interpretation of granitic rocks. Zircons separated from biotite gneiss and metagranite samples yielded SHRIMP-RG U–Pb ages of 1472 ± 14 (2σ) and 1045 ± 6 Ma, respectively, in very good agreement with widespread Early Mesoproterozoic plutonic ages and Ottawan orogeny ages in the Central Gneiss Belt. The Rb–Sr, U–Pb, and Pb–Pb whole-rock errorchron apparent ages of most of the CRL gneiss samples are consistent with zircon U–Pb age and do not indicate

  12. Mg/Ca, Sr/Ca, and stable isotopes in modern and Holocene Protothaca staminea shells from a northern California coastal upwelling region

    Takesue, R.K.; VanGeen, A.

    2004-01-01

    This study explores the potential of intertidal Protothaca staminea shells as high-resolution geochemical archives of environmental change in a coastal upwelling region. Mg/Ca and Sr/Ca ratios were analyzed by excimer laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) at sub-weekly temporal resolution in shells growing ???1 mm per month. Growth patterns of a modern P. staminea shell from Humboldt Bay, California, collected in December 1999 made it possible to infer a lifespan from 1993 to 1998. Growth hiatuses in the shell may have excluded records of extreme events. Mg/Ca ratios appeared to be partly controlled by water temperature; the correlation coefficient between temperature and Mg/Ca was r = 0.71 in one of four growth increments. Significant year-to-year differences in the sensitivity of Mg/Ca to temperature in P. staminea could not be explained, however. Sr/Ca ratios appeared to be more closely related to shell growth rate. Oxygen isotopes, measured at 2-week temporal resolution in the same shell, did not show a clear relation to local temperature in summer, possibly because temperatures were higher and less variable at the King Salmon mudflat, where the shell was collected, than in the main channel of Humboldt Bay, where water properties were monitored. Negative shell ??13C values (upwelling events. The Mg contents of P. staminea midden shells dated to ???3 ka and ???9 ka were significantly lower than in the modern shell. This may have resulted from degradation of a Mg-rich shell organic matrix and precluded quantitative interpretation of the older high-resolution records. Elevated ??13C values in the ???3 ka shell suggested that the individual grew in highly productive or stratified environment, such as a shallow coastal embayment or lagoon. Copyright ?? 2004 Elsevier Ltd.

  13. Geochronology, geochemistry and Sr-Nd-Hf isotopes of mafic dikes in the Huicheng Basin: Constraints on intracontinental extension of the Qinling orogen

    Li, Wei; Dong, Yunpeng; Guo, Anlin; Liu, Xiaoming; Wang, Yuejun; Liu, Wenhang; Yang, Yuanzhen

    2015-05-01

    The diabase dikes intruded the Lower Cretaceous sandstone in the Huicheng Basin are key to understanding the Mesozoic tectonic evolution of the Qinling orogen. LA-ICP-MS zircon U-Pb dating yields a crystallization age of 107 ± 1 Ma for them. The dikes have low contents of SiO2 (42.46-50.16 wt.%), MgO (3.47-5.59 wt.%) with low Mg# of 49-59, and TiO2 (1.35-1.63 wt.%), high TFe2O3 (8.15-9.36 wt.%), Al2O3 (14.75-17.23 wt.%) and K2O (0.87-3.61 wt.%). Their Ni and Cr contents are in range of 16.8-111 and 45.7-315 ppm, respectively. They are significantly enriched in light rare earth elements and large ion lithophile elements (e.g., Cs, Pb and Ba), and depleted in Rb, K, P, and Ti. The dikes show relatively high whole-rock initial 87Sr/86Sr ratios (0.7071-0.7079) and negative εNd (t) values (-1.5 to -4.8) with single-stage Nd model ages of 941-1186 Ma. In addition, they have low zircon εHf (t) values (-8.6 to +3.5) with single-stage Hf model ages of 674-1117 Ma. Both elemental and isotopic geochemistry suggests that the magma of these dikes has undergone significant crystallization fractionation of olivine and pyroxene but weak crustal contamination during magma evolution. They were derived from partial melting of an enriched lithospheric mantle source. Together with regional geological data, these results suggest that the Qinling orogen experienced an intracontinental extension during the late Early Cretaceous.

  14. Geochemical and Sr-Pb-Nd isotopic characteristics of the Shakhtama porphyry Mo-Cu system (Eastern Transbaikalia, Russia)

    Berzina, A. P.; Berzina, A. N.; Gimon, V. O.

    2014-01-01

    The Shakhtama Mo-Cu porphyry deposit is located within the eastern segment of the Central Asian Orogenic Belt, bordering the southern margin of the Mongol-Okhotsk suture zone. The deposit includes rocks of two magmatic complexes: the precursor plutonic (J2) and ore-bearing porphyry (J3) complexes. The plutonic complex was emplaced at the final stages of the collisional regime in the region; the formation of the porphyry complex may have overlapped with a transition to extension. The Shakhtama rocks are predominantly metaluminous, I-type high K calc-alkaline to shoshonitic in composition, with relatively high Mg#, Ni, Cr and V. They are characterized by crustal-like ISr (0.70741-0.70782), relatively radiogenic Pb isotopic compositions, ɛNd(T) values close to CHUR (-2.7 to +2.1) and Nd model ages from 0.8 to 1.2 Ga. Both complexes are composed of rocks with K-adakitic features and rocks without adakite trace element signatures. The regional geological setting together with geochemical and isotopic data indicate that both juvenile and old continental crust contributed to their origin. High-Mg# K-adakitic Shakhtama magmas were most likely generated by partial melting of thickened lower crust during delamination and interaction with mantle material, while magmas lacking adakite-like signatures were probably generated at shallower levels of lower crust. The derivation of melts, related to the formation of plutonic and porphyry complexes involved variable amounts of old Precambrian lower crust and juvenile Phanerozoic crust. Isotopic data imply stronger contribution of juvenile mantle-derived material to the fertile magmas of the porphyry complex. Juvenile crust is proposed as an important source of fluids and metals for the Shakhtama ore-magmatic system.

  15. Multiple magma evolution and ore-forming processes of the Hongge layered intrusion, SW China: Insights from Sr-Nd isotopes, trace elements and platinum-group elements

    Liao, Mingyang; Tao, Yan; Song, Xieyan; Li, Yubang; Xiong, Feng

    2015-12-01

    The Hongge layered intrusion (259 Ma), which is located in the inner zone of the Emeishan large igneous province (ELIP), is one of the most typical Fe-Ti-V ore deposits in the Pan-Xi area. Mafic-ultramafic layered intrusions of the ELIP have attracted a lot of attention lately because these intrusions host world class Fe-Ti-V oxide deposits plus interesting Cu-Ni-(PGE) mineralization which may have economic potential. This paper, reports new whole-rock major and trace element compositions, PGE abundances and Sr-Nd isotopic data for selected cumulate rocks and basalts. We use these data to investigate the nature of parental magmas and the controls on its evolution from the source mantle en route to the surface involving the Hongge ore-bearing intrusion. Two abrupt changes in Mt/Ilm and trace element ratios such as Ba/Th with depths in the Hongge layered intrusion indicate that this intrusion formed by at least two pluses of relatively primitive magma. The whole rock Sr-Nd isotopic data of basaltic and intrusive rocks plot in the region of Emeishan low-Ti basalts and the compositions of residual liquid (at ∼1260 °C and 1155 °C) calculated by MELTS are similar to our actual high-Ti (BFQ-2) and low-Ti (BC-1) basltic samples, indicate they are co-magmatic rather than derivation from a distinct source. Total PGE abundances in the Hongge samples are extremely low, ranging from 0.5 to 10 ppb. Sulfide-bearing rocks in the Hongge intrusion and the nearby coeval Banfangqing and Baicao basalts have similar mantle-like Pd/Pt ratios (2-6) and extremely high Cu/Pd ratios (3 × 104 to 4 × 105), indicating that sulfide segregation took place at depth prior to emplacement at Hongge and eruption in this region. Sulfide saturation in the Hongge magma may have resulted from such crustal contamination event. Crystallization of silicate minerals under the anhydrous magma, magma hydration plus Fe-Ti enrichments in the parental magma are three critical factors for the formation of Fe

  16. Geological, geochronological, geochemical, and Sr-Nd-O-Hf isotopic constraints on origins of intrusions associated with the Baishan porphyry Mo deposit in eastern Tianshan, NW China

    Wang, Yinhong; Xue, Chunji; Liu, Jiajun; Zhang, Fangfang

    2016-03-01

    The Baishan porphyry Mo deposit (0.72 Mt; 0.06 % Mo) is located in the interior of the eastern Tianshan orogenic belt in Xinjiang, NW China. The deposit comprises 15 orebodies that are associated with monzogranite and granite porphyry stocks and are structurally controlled by roughly EW-trending faults. Secondary ion mass spectrometry (SIMS) zircon U-Pb dating of the monzogranite and granite porphyry yielded the Middle Triassic age (228 ± 2 to 227 ± 2 Ma), which coincide with the molybdenite Re-Os model ages ranging from 226 ± 3 to 228 ± 3 Ma. The Triassic monzogranite and granite porphyry belong to high-K calc-alkaline series and are characterized by high SiO2 and Al2O3 and low MgO, TiO2, and P2O5 concentrations, with negative Eu anomalies (δEu = 0.55-0.91). The least-altered monzogranite and granite porphyry yield uniform ɛ Nd(t) values from +1.6 to +3.6, and wide (87Sr/86Sr) i ratios ranging between 0.7035 and 0.7071, indicating that they were derived from the lower crust. In situ O-Hf isotopic analyses on zircon using SIMS and laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS) indicate that the δ18O and ɛ Hf(t) values of zircon from a monzogranite sample vary from 6.1 to 7.3 ‰ and +8.0 to +11.7, respectively, whereas zircon from a granite porphyry sample vary from 6.2 to 6.9 ‰ and +7.3 to +11.2, respectively. The geochemical and isotopic data imply that the primary magmas of the Baishan granite were likely derived from partial melts from the lower crust involving some mantle components. The Baishan Mo deposit and granitic emplacement were proposed to be most likely related to post-orogenic lithospheric extension and magmatic underplating. An extensional event coupled with the rising of hot mantle-derived melts triggered partial melting of the lower crust, as well as provided metals (Mo).

  17. Interaction between ultrapotassic magmas and carbonate rocks: Evidence from geochemical and isotopic (Sr, Nd, O) compositions of granular lithic clasts from the Alban Hills Volcano, Central Italy

    Peccerillo, Angelo; Federico, Marcella; Barbieri, Mario; Brilli, Mauro; Wu, Tsai-Wan

    2010-05-01

    Magma-carbonate rock interaction is investigated through a geochemical and Sr-Nd-O isotope study of granular lithic clasts ( ejecta) from the Alban Hills ultrapotassic volcano, Central Italy. Some samples (Group-1) basically represent intrusive equivalents of Alban Hills magmas. A few samples (Group-2) are ultramafic, have high MgO (˜30 to 40 wt%) and δ 18O‰, and originated by accumulation of mafic phases that crystallised from ultrapotassic melts during assimilation of dolomitic rocks. Group-3 ejecta consist of dominant K-feldspar, and show major element compositions similar to phonolites, which, however, are absent among the Alban Hills volcanics. Finally, another group (Group-4) contains corroded K-feldspars, surrounded by a microgranular to porphyritic matrix, made of igneous minerals (K-feldspar, foids, clinopyroxene, phlogopite) plus wollastonite, garnet, and some cuspidine. Group-4 ejecta are depleted in SiO 2 and enriched in CaO with respect to Group-3. The analysed ejecta have similar 143Nd/ 144Nd (0.51204-0.51217) as the Alban Hills lavas, whereas 87Sr/ 86Sr (0.70900-0.71067) is similar to lower. Whole rocks δ 18O‰ ranges from +7.0 to +13.2, reaching maximum values in ultramafic samples. A positive correlation with CaO is observed in single rock groups. Large Ion Lithophile Element (LILE) abundances and REE fractionation are generally high, and extreme values of Th, U and LREE are found in some Group-3 and Group-4 rocks. Mineralogical, petrological and geochemical data reveal extensive interaction between magma and carbonate wall rocks, involving both dolostones and limestones. These processes had dramatic effects on magma compositions, especially on phonolites, which were transformed to foidites. Evidence of such a process is found in Group-4 samples, in which K-feldspar is observed to react with a matrix that represents strongly undersaturated melts formed by interaction between silicate magma and carbonates. Trace element data also testify to a

  18. Midcontinent rift volcanism in the Lake Superior region: Sr, Nd, and Pb isotopic evidence for a mantle plume origin

    Nicholson, S.W.; Shirey, S.B.

    1990-01-01

    Between 1091 and 1098 Ma, most of a 15- to 20-km thickness of dominantly tholeiitic basalt erupted in the Midcontinent Rift System of the Lake Superior region, North America. The Portage Lake Volcanics in Michigan, which are the younget MRS flood basalts, fall into distinctly high- and low-TiO2 types having different liquid lines of descent. Incompatible trace elements in both types of tholeiites are enriched compared to depleted or primitive mantle and both basalt types are isotopically indistinguishable. The isotopic enrichment of the MRS source compared to depleted mantle is striking and must have occurred at least 700 m.y. before 1100 Ma. There are two likely sources for such magmatism: subcontinental lithospheric mantle enriched during the early Proterozoic or enriched mantle derived from an upwelling plume. Decompression melting of an upwelling enriched mantle plume in a region of lithosphere thinned by extension could have successfully generated the enormous volume (850 ?? 103 km3) of relatively homogeneous magma in a restricted time interval. -from Authors

  19. Ion microprobe measurement of strontium isotopes in calcium carbonate with application to salmon otoliths

    Weber, P.K.; Bacon, C.R.; Hutcheon, I.D.; Ingram, B.L.; Wooden, J.L.

    2005-01-01

    The ion microprobe has the capability to generate high resolution, high precision isotopic measurements, but analysis of the isotopic composition of strontium, as measured by the 87Sr/ 86Sr ratio, has been hindered by isobaric interferences. Here we report the first high precision measurements of 87Sr/ 86Sr by ion microprobe in calcium carbonate samples with moderate Sr concentrations. We use the high mass resolving power (7000 to 9000 M.R.P.) of the SHRIMP-RG ion microprobe in combination with its high transmission to reduce the number of interfering species while maintaining sufficiently high count rates for precise isotopic measurements. The isobaric interferences are characterized by peak modeling and repeated analyses of standards. We demonstrate that by sample-standard bracketing, 87Sr/86Sr ratios can be measured in inorganic and biogenic carbonates with Sr concentrations between 400 and 1500 ppm with ???2??? external precision (2??) for a single analysis, and subpermil external precision with repeated analyses. Explicit correction for isobaric interferences (peak-stripping) is found to be less accurate and precise than sample-standard bracketing. Spatial resolution is ???25 ??m laterally and 2 ??m deep for a single analysis, consuming on the order of 2 ng of material. The method is tested on otoliths from salmon to demonstrate its accuracy and utility. In these growth-banded aragonitic structures, one-week temporal resolution can be achieved. The analytical method should be applicable to other calcium carbonate samples with similar Sr concentrations. Copyright ?? 2005 Elsevier Ltd.

  20. Target rocks, impact glasses, and melt rocks from the Lonar crater, India: Highly siderophile element systematics and Sr-Nd-Os isotopic signatures

    Schulz, Toni; Luguet, Ambre; Wegner, Wencke; Acken, David; Koeberl, Christian

    2016-07-01

    The Lonar crater is a ~0.57-Myr-old impact structure located in the Deccan Traps of the Indian peninsula. It probably represents the best-preserved impact structure hosted in continental flood basalts, providing unique opportunities to study processes of impact cratering in basaltic targets. Here we present highly siderophile element (HSE) abundances and Sr-Nd and Os isotope data for target basalts and impactites (impact glasses and impact melt rocks) from the Lonar area. These tools may enable us to better constrain the interplay of a variety of impact-related processes such as mixing, volatilization, and contamination. Strontium and Nd isotopic compositions of impactites confirm and extend earlier suggestions about the incorporation of ancient basement rocks in Lonar impactites. In the Re-Os isochron plot, target basalts exhibit considerable scatter around a 65.6 Myr Re-Os reference isochron, most likely reflecting weathering and/or magma replenishment processes. Most impactites plot at distinctly lower 187Re/188Os and 187Os/188Os ratios compared to the target rocks and exhibit up to two orders of magnitude higher abundances of Ir, Os, and Ru. Moreover, the impactites show near-chondritic interelement ratios of HSE. We interpret our results in terms of an addition of up to 0.03% of a chondritc component to most impact glasses and impact melt rocks. The magnitude of the admixture is significantly lower than the earlier reported 12-20 wt% of extraterrestrial component for Lonar impact spherules, reflecting the typical difference in the distribution of projectile component between impact glass spherules and bulk impactites.

  1. Trace element and Sr-Nd-Pb isotope geochemistry of Rungwe Volcanic Province, Tanzania: Implications for a superplume source for East Africa Rift magmatism

    Paterno R Castillo

    2014-09-01

    Full Text Available The recently discovered high, plume-like 3He/4He ratios at Rungwe Volcanic Province (RVP in southern Tanzania, similar to those at the Main Ethiopian Rift in Ethiopia, strongly suggest that magmatism associated with continental rifting along the entire East African Rift System (EARS has a deep mantle contribution (Hilton et al., 2011. New trace element and Sr-Nd-Pb isotopic data for high 3He/4He lavas and tephras from RVP can be explained by binary mixing relationships involving Early Proterozoic (+/- Archaean lithospheric mantle, present beneath the southern EARS, and a volatile-rich carbonatitic plume with a limited range of compositions and best represented by recent Nyiragongo lavas from the Virunga Volcanic Province also in the Western Rift. Other lavas from the Western Rift and from the southern Kenya Rift can also be explained through mixing between the same endmember components. In contrast, lavas from the northern Kenya and Main Ethiopian rifts can be explained through variable mixing between the same mantle plume material and the Middle to Late Proterozoic lithospheric mantle, present beneath the northern EARS. Thus, we propose that the bulk of EARS magmatism is sourced from mixing among three endmember sources: Early Proterozoic (+/- Archaean lithospheric mantle, Middle to Late Proterozoic lithospheric mantle and a volatile-rich carbonatitic plume with a limited range of compositions. We propose further that the African Superplume, a large, seismically anomalous feature originating in the lower mantle beneath southern Africa, influences magmatism throughout eastern Africa with magmatism at RVP and Main Ethiopian Rift representing two different heads of a single mantle plume source. This is consistent with a single mantle plume origin of the coupled He-Ne isotopic signatures of mantle-derived xenoliths and/or lavas from all segments of the EARS (Halldorsson et al., 2014.

  2. Target rocks, impact glasses, and melt rocks from the Lonar crater, India: Highly siderophile element systematics and Sr-Nd-Os isotopic signatures

    Schulz, Toni; Luguet, Ambre; Wegner, Wencke; Acken, David; Koeberl, Christian

    2016-06-01

    The Lonar crater is a ~0.57-Myr-old impact structure located in the Deccan Traps of the Indian peninsula. It probably represents the best-preserved impact structure hosted in continental flood basalts, providing unique opportunities to study processes of impact cratering in basaltic targets. Here we present highly siderophile element (HSE) abundances and Sr-Nd and Os isotope data for target basalts and impactites (impact glasses and impact melt rocks) from the Lonar area. These tools may enable us to better constrain the interplay of a variety of impact-related processes such as mixing, volatilization, and contamination. Strontium and Nd isotopic compositions of impactites confirm and extend earlier suggestions about the incorporation of ancient basement rocks in Lonar impactites. In the Re-Os isochron plot, target basalts exhibit considerable scatter around a 65.6 Myr Re-Os reference isochron, most likely reflecting weathering and/or magma replenishment processes. Most impactites plot at distinctly lower 187Re/188Os and 187Os/188Os ratios compared to the target rocks and exhibit up to two orders of magnitude higher abundances of Ir, Os, and Ru. Moreover, the impactites show near-chondritic interelement ratios of HSE. We interpret our results in terms of an addition of up to 0.03% of a chondritc component to most impact glasses and impact melt rocks. The magnitude of the admixture is significantly lower than the earlier reported 12-20 wt% of extraterrestrial component for Lonar impact spherules, reflecting the typical difference in the distribution of projectile component between impact glass spherules and bulk impactites.

  3. Determination of δ88/86Sr Using Matrix Correction by MC-ICP-MS

    Zhu, B.; Yang, T.; Bian, X. P.; Zhu, Z. Y.

    2014-12-01

    Stable Sr isotopic compositions (δ88/86Sr) in marine carbonates potentially provide key information on paleoseawater temperature (Rüggeberg et al. 2008). Traditional methods for δ88/86Sr determination by 87Sr-84Sr double-spike TIMS or MC-ICP-MS require chemical purification of Sr before spectrometric measurements because of matrix effects. Recent studies suggested that the matrix-matching method, in which matrix-matched standard solutions were used to bracket untreated water samples, gave precise and accurate results for sulfur isotopic ratios by MC-ICP-MS (Lin et al., 2014). The obvious advantage of this method is that there is no need for chemical purification, thus eliminating the possibility of isotope fractionation during the ion chromatography and expediting sample throughput. In this study, we applied the matrix-matching method to δ88/86Sr determination by MC-ICP-MS. NIST 987 Sr solution and a purified seawater sample (collected from the South China Sea) were selected for this study. Given that major matrices in carbonate come form Ca2+, NIST 987 and SW solutions containing 40 ppm Ca2+ were prepared by adding high-purity Ca solution. All solutions used contained 200 ppb Sr and the 88Sr/86Sr ratios were measured using a Neptune MC-ICP-MS. The purified SW was first determined using SSB method, in which pure NIST 987 was used as standard to bracket SW and yielded δ88/86Sr value of 0.366 ± 0.008‰ (2SE, n = 10). The δ88/86Sr values of Ca-bearing SW were then measured by using pure NIST 987 solution as the working standard to investigate matrix effects. The determined δ88/86Sr value (0.039 ± 0.021‰; 2SE, n = 10) deviated obviously from the reference value. Finally, the matrix-matched NIST 987 was applied as the working standard to bracket the Ca-bearing SW, and the measured δ88/86Sr value is 0.351 ± 0.009‰ (2SE, n = 10), consistent with the reference value within uncertainties. The consistent δ88/86Sr values and comparable external precision

  4. Sr and Nd isotope systematics and Pb-Pb step wise leaching of banded hematite quartzites from Morar sub group, Gwalior Basin M.P. : implications on their diagenetic history and petrogenesis. CP-8

    The low abundances of Rb, Sr, Sm and Nd in Banded Iron Formations (B,F's) result in insufficient spread of data points to obtain reliable isochrons using conventional geochronometers. Under these constraints, stepwise Pb leaching has been used effectively to obtain a better spread in Pb ratios so as to yield a reliable age data. Since B, F's are formed by marine chemical sedimentation, their isotopic signatures carry a record of the source of Rb b and Fe in these sediments

  5. Crystal recycling in the steady-state system of the active Stromboli volcano : a 2.5-ka story inferred from in situ Sr-isotope and trace element data.

    Francalanci, Lorella; Avanzinelli, Riccardo; Nardini, Isabella; Tiepolo, Massimo; Davidson, Jon P.; Vannucci, Riccardo

    2011-01-01

    In situ Sr-isotope data by microdrilling, cou- pled with major and trace element analyses, have been performed on plagioclase and clinopyroxene from seven samples collected during the 2002–2003 eruptive crisis at Stromboli volcano (Aeolian Islands, Italy). On 28 December 2002, the persistent moderate explosive activity was broken by an effusive event lasting about 7 months. A more violent explosion (paroxysm) occurred on 5 April 2003. Two magma types were erupted, namely a volatile- poor and ...

  6. Occurrence and mobilization of radium in fresh to saline coastal groundwater inferred from geochemical and isotopic tracers (Sr, S, O, H, Ra, Rn)

    Highlights: • The radium (Ra) isotope association with groundwater salinity is locally variable. • Water from 2 coastal aquifers exhibits at least one apparent Ra removal mechanism. • Ra may be removed by multiple mechanisms (e.g. adsorption, BaSO4 precipitation). • Adsorption and coprecipitation depend on local geochemical and redox conditions. • Other isotopes (87Sr/86Sr, δ34S–SO42-,δ18O–SO42-) trace solute sources and redox state. - Abstract: Salinization in groundwater systems can induce water–rock interaction, including the release of naturally-occurring trace elements of health significance such as radium (Ra), with possible implications for the usability of water resources in addition to the increase of dissolved solids (TDS) concentrations. In general, radium mobility is limited by chemical removal mechanisms including adsorption onto clays and/or Mn and Fe oxides, exchange processes, and coprecipitation with secondary barite. In order to examine the effect of aquifer salinity gradients on the distribution of naturally-occurring Ra in fresh to saline groundwater and the relationship to water–rock interaction and Ra removal mechanisms, two contrasting systems were investigated: the shallow unconfined coastal aquifer in Agadir (southwestern Morocco) and the confined Cretaceous (Cape Fear) and Pliocene (Yorktown) aquifers of the Atlantic Coastal Plain (North Carolina, USA). Geochemical and isotopic indicators of salinity sources (e.g. cation ratios, δ18O, δ2H, Br−/Cl−, δ34S–SO42-,δ18O–SO42-) were used to identify the relative contributions of seawater and other saline waters and subsequent geochemical modification by water–rock interaction. Radium activities (224Ra, 226Ra, 228Ra), radon-222, alkaline earth metal (Mg, Ca, Sr, Ba) concentrations and ratios, and 87Sr/86Sr ratios were analyzed to identify water–rock interaction processes affecting alkaline earth metals including Ra. The Morocco coastal aquifer is generally oxic

  7. Use of Pb and Sr isotopes as tracers of anthropogenic and natural inputs in rain waters and rivers of the Paris basin

    The isotopic composition of Pb and Sr, measured in the soluble phase of rain waters and rivers are used to determine and quantify the anthropogenic inputs and the weathering rates in the Seine basin. Atmospheric lead from rain waters is exclusively anthropogenic and is derived from gasoline and industrial emissions. These rain waters transfer lead, and certain other heavy metals, into the Seine, where the anthropogenic signal perturbs the natural geochemical cycle of these metals. This transfer to the river occurs principally in the city of Paris, in contrast, in the catchment area upstream of Paris, these elements are mainly trapped in soils, rather than transferred to the river. The anthropogenic inputs comprise three-quarters of the total transport of these metals by the Seine. In the river, lead transport is due to adsorption process occurring within the suspended load. Thus, soluble lead concentrations are linked to the river flow and the intensity of mechanical erosion. After correction for atmospheric and anthropogenic inputs, it is possible to estimate the silicate weathering rate for the Seine basin. This estimate is close to that obtained for large plain rivers, such as the Congo or Amazon, indicating that chemical erosion is linked to tectonic processes rather than climatic conditions. (author)

  8. Petrogenesis of Tarom high-potassic granitoids in the Alborz-Azarbaijan belt, Iran: Geochemical, U-Pb zircon and Sr-Nd-Pb isotopic constraints

    Nabatian, Ghasem; Ghaderi, Majid; Neubauer, Franz; Honarmand, Maryam; Liu, Xiaoming; Dong, Yunpeng; Jiang, Shao-Yong; von Quadt, Albrecht; Bernroider, Manfred

    2014-01-01

    Large-scale Upper Eocene plutons in the Western Alborz-Azarbaijan orogenic belt mostly show calc-alkaline and I-type geochemical features contrasted by the Tarom complex with its high-potassic to shoshonitic affinity. The pluton was emplaced in the Tarom subzone of the orogenic belt and its laser ICP-MS zircon U-Pb age of 41 Ma is interpreted as the age of magma crystallization. The Tarom complex is composed of quartz monzodiorite, quartz-monzonite and monzogranite, the SiO2 contents range from 57 to 70 wt.%, the K2O + Na2O content is high (5.0-8.9 wt.%) and K2O/Na2O ratio ranges from 0.4 to 1.9. All the investigated rocks are enriched in light rare earth elements (LREEs), large ion lithophile elements (LILEs) and depleted in high field strength elements (HFSEs), and bear a weak Eu anomaly (Eu/Eu* = 0.46 to 1.38) in chondrite-normalized trace element patterns. The samples display some variety in initial Sr and Nd isotopic compositions, marked with low ISr = 0.704-0.705 and ɛNd (40 Ma) = - 4.2 to + 3.4 (- 5.7 for an enclave) values. The Pb isotopic ratios are (206Pb/204Pb) = 18.52-18.86, (207Pb/204Pb) = 15.57-15.72 and (208Pb/204Pb) = 38.47-39.08. Comparison with experimental studies, together with mantle-like isotopic ratios and comparisons of REE patterns, points to an origin of chemically enriched lithospheric mantle source for the Tarom plutonic complex. Partial melting process involving different partial melting degrees affecting heterogeneously metasomatized mantle is a process that seems likely to have occurred in the studied complex as the major differentiation process. The Tarom monzonitic plutons are considered to be post-orogenic intrusions that were emplaced in an environment of lithospheric extension, causing asthenospheric upwelling. Asthenospheric upwelling induced a thermal anomaly which caused partial melting of metasomatized subcontinental lithospheric mantle in the Tarom area.

  9. Algoma-type Neoproterozoic BIFs and related marbles in the Seridó Belt (NE Brazil): REE, C, O, Cr and Sr isotope evidence

    Sial, Alcides N.; Campos, Marcel S.; Gaucher, Claudio; Frei, Robert; Ferreira, Valderez P.; Nascimento, Rielva C.; Pimentel, Marcio M.; Pereira, Natan S.; Rodler, Alexandra

    2015-08-01

    The Jucurutu Formation in the Seridó Belt, northeastern Brazil, encompasses fine-to coarse-grained amphibolite-facies marbles, locally with cross-bedding and stromatolites. Banded iron formations (BIF) at three localities in this belt comprise itabirites (actinolite- or cummingtonite-itabirite and quartz-hematite itabirite) and iron ores, which are overlain by marbles of the Jucurutu Formation. Diamictites of uncertain stratigraphic position in the Seridó Belt exhibit gneiss and quartzite clasts up to 0.6 m long and a fine-grained metapelitic matrix. The C-isotope stratigraphic pathways for the Jucurutu Formation show negative δ13C values at the base of the formation followed upsection by positive values. At the Ferro do Bonito iron Mine, values as low as -12‰ in carbonates just above the contact with underlying BIF are followed by values of ca. -5‰ and by positive values up section (+4 to +10‰). δ13C values for carbonates of the Jucurutu Formation deposited on top of BIFs at the Riacho Fundo, São João do Sabugi, and Serra da Formiga sections are all positive, the contact surfaces between carbonates and BIFs being covered by weathered material. The 87Sr/86Sr values for carbonate rocks of the Jucurutu Formation are mostly in the 0.7074-0.7075 interval, a ratio commonly observed in the late Cryogenian to the early Ediacaran. The studied BIFs exhibit Cr concentrations one magnitude higher than usual and largely unfractionated Cr isotope composition, similar to average magmatic values. They are characterized by δ53Cr values between -0.42 and -0.12‰, by Ce anomalies (Ce/Ce*) ranging from -0.4 to 0.7, by positive Eu anomalies, and by super-chondritic Y/Ho ratios (>20). The combination of geochemical parameters and association with mafic rocks resemble Algoma-type BIFs. These BIFs possibly formed proximally to hydrothermal vents, in anoxic and acidic deep waters, whereby Fe and Cr were leached from mafic or ultramafic rocks. High concentrations of Cr in the

  10. The Messinian marine to nonmarine gypsums of Jumilla (Northern Betic Cordillera, SE Spain): Isotopic and Sr concentration constraints on the origin of parent brines

    Rossi, Carlos; Vilas, Lorenzo; Arias, Consuelo

    2015-10-01

    The origin of the Messinian Hoya de la Sima (HS) gypsum (Betic foreland) is constrained using 87Sr/86Sr, δ34S, Sr concentration, and petrographic data. The Lower and Middle HS units consist of subaqueous vertically-aligned and stromatolitic selenites, the latter containing unusual microbial depositional textures. The Upper Unit consists of very-shallow-water bioturbated lenticular gypsum with Paracamelus ichnites. 87Sr/86Sr and δ34S indicate precipitation from predominantly marine waters, with upward increasing continental influence. Mixing models between Messinian seawater and continental water that dissolved Triassic evaporites show that the percentages of seawater required to explain the measured 87Sr/86Sr are analogous to the percentages obtained using δ34S, supporting precipitation from such mixtures. 87Sr/86Sr and δ34S of Lower HS selenites resemble those of the Primary Lower Gypsum (PLG) of the Messinian Salinity Crisis (MSC), in both cases indicating precipitation from seawater-continental water mixtures in which most Sr and SO4 were supplied by Messinian seawater. In the Lower HS selenites, Sr concentrations indicate contributing continental waters with Sr/Ca ratios similar to seawater. However, Sr concentrations of PLG selenites from other Betic basins (Bajo Segura, Sorbas indicate parent waters with Sr/Ca ratios lower than seawater. If the Sr contents of the betic PLG selenites are representative, it is unlikely that the Lower HS selenites represent the PLG. However, we cannot completely discard that option since different LPG subbasins could have had variable Sr/Ca. The HS gypsums formed coevally to diapirism of Triassic evaporites, in a restricted lagoonal basin developed during or slightly after a phase of strike-slip faulting in the Betic Cordillera. More general implications of this work are that Sr concentrations, combined with 87Sr/86Sr and δ34S data, provide key constraints on the origin of parent brines, and using Sr concentrations as

  11. Rb–Sr and Sm–Nd isotope systematics and geochemical studies on metavolcanic rocks from Peddavura greenstone belt: Evidence for presence of Mesoarchean continental crust in easternmost part of Dharwar Craton, India

    M Rajamanickam; S Balakrishnan; R Bhutani

    2014-07-01

    Linear, north–south trending Peddavura greenstone belt occurs in easternmost part of the Dharwar Craton. It consists of pillowed basalts, basaltic andesites, andesites (BBA) and rhyolites interlayered with ferruginous chert that were formed under submarine condition. Rhyolites were divided into type-I and II based on their REE abundances and HREE fractionation. Rb–Sr and Sm–Nd isotope studies were carried out on the rock types to understand the evolution of the Dharwar Craton. Due to source heterogeneity Sm–Nd isotope system has not yielded any precise age. Rb–Sr whole-rock isochron age of 2551 ± 19 (MSWD = 1.16) Ma for BBA group could represent time of seafloor metamorphism after the formation of basaltic rocks. Magmas representing BBA group of samples do not show evidence for crustal contamination while magmas representing type-II rhyolites had undergone variable extents of assimilation of Mesoarchean continental crust (< 3.3 Ga) as evident from their initial Nd isotope values. Trace element and Nd isotope characteristics of type I rhyolites are consistent with model of generation of their magmas by partial melting of mixed sources consisting of basalt and oceanic sediments with continental crustal components. Thus this study shows evidence for presence of Mesoarchean continental crust in Peddavura area in eastern part of Dharwar Craton.

  12. Zircon U-Pb dating, geochemical and Sr-Nd-Hf isotopic characteristics of the Jintonghu monzonitic rocks in western Fujian Province, South China: Implication for Cretaceous crust-mantle interactions and lithospheric extension

    Li, Bin; Jiang, Shao-Yong; Lu, An-Huai; Zhao, Hai-Xiang; Yang, Tang-Li; Hou, Ming-Lan

    2016-09-01

    Comprehensive petrological, in situ zircon U-Pb dating, Ti-in-zircon temperature and Hf isotopic compositions, whole rock geochemical and Sr-Nd isotopic data are reported for the Jintonghu monzonitic intrusions in the western Fujian Province (Interior Cathaysia Block), South China. The Jintonghu monzonitic intrusions were intruded at 95-96 Ma. Their Sr-Nd-Hf isotopic compositions are similar to the coeval and nearby enriched lithospheric mantle-derived mafic and syenitic rocks, indicating that the Jintonghu monzonitic rocks were likely derived from partial melting of the enriched mantle sources. Their high Nb/Ta ratios (average 21.6) suggest that the metasomatically enriched mantle components were involved, which was attributed to the modification of slab-derived fluid and melt by the subduction of the paleo-Pacific Plate. The presence of mafic xenoliths, together with geochemical and isotopic features indicates a mafic-felsic magma mixing. Furthermore, the Jintonghu intrusions may have experienced orthopyroxene-, biotite- and plagioclase-dominated crystallization. Crust-mantle interaction can be identified as two stages, including that the Early Cretaceous mantle metasomatism and lithospheric extension resulted from the paleo-Pacific slab subduction coupled with slab rollback, and the Late Cretaceous crustal activation and enhanced extension induced by dip-angle subduction and the underplating of mantle-derived mafic magma.

  13. Zircon U-Pb dating, geochemistry and Sr-Nd-Pb-Hf isotopes of the Wajilitag alkali mafic dikes, and associated diorite and syenitic rocks: Implications for magmatic evolution of the Tarim large igneous province

    Zou, Si-Yuan; Li, Zi-Long; Song, Biao; Ernst, Richard E.; Li, Yin-Qi; Ren, Zhong-Yuan; Yang, Shu-Feng; Chen, Han-Lin; Xu, Yi-Gang; Song, Xie-Yan

    2015-01-01

    The Early Permian Tarim large igneous province (Tarim LIP) consists mainly of basaltic lavas, mafic-ultramafic intrusions including dikes and, syenite bodies in the Tarim Basin, NW China. A major unit of the Tarim LIP, the Wajilitag intrusive complex, consists of olivine pyroxenite, clinopyroxenite and gabbro units (from bottom to top), diorite and syenite rocks occurred in the upper part of the complex and alkali mafic dikes intrude the clinopyroxenite phase. Here we report the zircon U-Pb age and Hf isotopes, geochemical characteristics and Sr-Nd-Pb isotopic data of the alkali mafic dikes, and diorite, aegirine-nepheline syenite and syenite porphyry units in the Wajilitag intrusive complex. Zircons from the diorite and alkali mafic rocks yield concordant crystallization ages of 275.2 ± 1.2 Ma and 281.4 ± 1.7 Ma, respectively. The diorite and syenitic rocks in Wajilitag area have a narrow range of SiO2 contents (51.9-57.3 wt.%), and are enriched in total alkalis (Na2O + K2O = 8.3-14.3 wt.%), among which the aegirine-nepheline syenite and syenite porphyry have the geochemical affinity of A-type granites. The alkali mafic rocks and syenitic rocks have high Al2O3 (19.4-21.1 wt.%), Zr, Hf, Ba contents, total rare earth element abundances and LREE/HREE ratios and low Mg# value, K, P and Ti contents. Diorites have lower Al2O3 contents, total REE abundances and LREE/HREE ratios and higher Mg# values than the alkali mafic rocks and syenitic rocks. The diorites and syenitic rocks have low initial 87Sr/86Sr ratios (0.7034-0.7046), and high εNd(t) values (0.1-4.1) and zircon εHf(t) values (- 0.9-4.4). All the diorites and syenitic rocks show the 206Pb/204Pb ratios ranging of 18.0-19.5, 207Pb/204Pb of 15.4-15.6 and 208Pb/204Pb of 38.0-39.9. Sr-Nd isotopic ratios indicate a FOZO-like mantle source for the diorite and syenitic rocks, similar to that of the mafic-ultramafic rocks in the Wajilitag complex. In contrast, zircon Hf isotopes of basalt and syenite elsewhere in the

  14. Single crystal U-Pb zircon age and Sr-Nd isotopic composition of impactites from the Bosumtwi impact structure, Ghana: Comparison with country rocks and Ivory Coast tektites.

    Ferrière, Ludovic; Koeberl, Christian; Thöni, Martin; Liang, Chen

    2010-08-01

    The 1.07 Myr old Bosumtwi impact structure (Ghana), excavated in 2.1-2.2 Gyr old supracrustal rocks of the Birimian Supergroup, was drilled in 2004. Here, we present single crystal U-Pb zircon ages from a suevite and two meta-graywacke samples recovered from the central uplift (drill core LB-08A), which yield an upper Concordia intercept age of ca. 2145 ± 82 Ma, in very good agreement with previous geochronological data for the West African Craton rocks in Ghana. Whole rock Rb-Sr and Sm-Nd isotope data of six suevites (five from inside the crater and one from outside the northern crater rim), three meta-graywacke, and two phyllite samples from core LB-08A are also presented, providing further insights into the timing of the metamorphism and a possibly related isotopic redistribution of the Bosumtwi crater rocks. Our Rb-Sr and Sm-Nd data show also that the suevites are mixtures of meta-greywacke and phyllite (and possibly a very low amount of granite). A comparison of our new isotopic data with literature data for the Ivory Coast tektites allows to better constrain the parent material of the Ivory Coast tektites (i.e., distal impactites), which is thought to consist of a mixture of metasedimentary rocks (and possibly granite), but with a higher proportion of phyllite (and shale) than the suevites (i.e., proximal impactites). When plotted in a Rb/Sr isochron diagram, the sample data points (n = 29, including literature data) scatter along a regression line, whose slope corresponds to an age of 1846 ± 160 Ma, with an initial Sr isotope ratio of 0.703 ± 0.002. However, due to the extensive alteration of some of the investigated samples and the lithological diversity of the source material, this age, which is in close agreement with a possible "metamorphic age" of ∼ 1.8-1.9 Ga tentatively derived from our U-Pb dating of zircons, is difficult to consider as a reliable metamorphic age. It may perhaps reflect a common ancient source whose Rb-Sr isotope

  15. Dating the Indo-Asia collision in NW Himalaya: constraints from Sr-Nd isotopes and detrital zircon (U-Pb) and Hf isotopes of Paleogene-Neogene rocks in the Katawaz basin, NW Pakistan

    Zhuang, Guangsheng; Najman, Yani; Millar, Ian; Chauvel, Catherine; Guillot, Stephane; Carter, Andrew

    2015-04-01

    The time of collision between the Indian and Asian plates is key for understanding the convergence history and the impact on climatic systems and marine geochemistry. Despite much active research, the fundamental questions still remain elusive regarding when and where the Indian plate collided with the Asian plate. Especially in the west Himalaya, the questions become more complex due to disputes on the amalgamation history of interoceanic Kohistan-Ladakh arcs (KLA) with Karakoram of the Asian plate and the Indian plate. Here, we present a result of multiple-isotopic geochemistry and geochronology study in the Katawaz Basin in NW Pakistan, a remnant oceanic basin on the western Indian plate which was the repository for the sediments eroded from the west Himalaya ( Qayyum et al., 1996, 1997a, 1997b, 2001; Carter et al., 2010), to evaluate the time and character of collision in this region. In this study, we analyzed 22 bulk mudstone samples for Sr-Nd isotopes and 11 medium-grained sandstones for detrital zircon (U-Pb) geochronology and Hf isotopes. We constructed the Cenozoic chronology in the Katawaz Basin based on our newly collected detrital zircon U-Pb ages and fission track ages. We present the first record of Katawaz chronology that constrained the Khojak Formation to be origin, revealing the arrival of Asian detritus on the Indian plate prior to 50 Ma. There are two parallel lines of evidence supporting this conclusion: (1) young zircon grains (Journal of the Geological Society 154, 753-756. Qayyum, M., Lawrence, R.D., Niem, A.R., 1997b. Molasse-Delta-flysch continuum of the Himalayan orogeny and closure of the Paleogene Katawaz Remnant Ocean, Pakistan. International geology review 39, 861-875. Qayyum, M., Niem, A.R., Lawrence, R.D., 1996. Newly discovered Paleogene deltaic sequence in Katawaz basin, Pakistan, and its tectonic implications. Geology 24, 835-838. Qayyum, M., Niem, A.R., Lawrence, R.D., 2001. Detrital modes and provenance of the Paleogene Khojak

  16. Magneto structural phase separation and giant isotope effect in R0.5Sr0.5MnO3

    The results of structural neutron experiments on determining crystal and magnetic phase states of perovskite-like manganite R0.5Sr0.5MnO3 (R=152Sm, Nd0.772Tb0.228, and Nd0.544Tb0.456) are reported. Experiments are carried out for revealing microscopic factors responsible for the giant oxygen isotope effect that was discovered recently in Sm1-'x SrxMnO3 for x ∼0.5. It is shown that separation into two crystal phases P1 and P2 with the same spatial symmetry but different types of Jahn-Teller distortions in MnO6 octahedra and magnetic ordering of Mn atoms takes place in all studied compounds at low temperatures. Structural analysis has been carried out successfully owing to exceptionally large differences in the unit cell parameters of the coexisting phases. The P1 phase is ferromagnetic and MnO6 octahedra are distorted only slightly. The P2 phase is antiferromagnetic (A-type ordering) and MnO6 octahedra are strongly compressed in the apical direction. The relative volumes occupied by the P1 and P2 phases depend on the mean radius of the A cation, and the replacement of 16O by 18O results in their redistribution in favor of the P2 phase. The results unambiguously point to the percolation nature of the metal-insulator transition in a Sm-containing compound upon isotopic substitution of oxygen due to a sharp decrease (from 65 to 13%) in the fraction of ferromagnetic phase P1. In all investigated compounds, the ordered magnetic moment of manganese Mn in the P1 and P2 phases varies from 1.7μB to 3.5μB. The data on the evolution of the microstructure parameters during a phase transition to the stratified state indicate that the initial spread in the A cation radii, as well as the internal microstrains, produce a critical effect on the formation of mesoscopic phase separation. (author)

  17. Isotope-geochemical Nd-Sr evidence of Palaeoproterozoic plume magmatism in Fennoscandia and mantle-crust interaction on stages of layered intrusions formation

    Serov, Pavel; Bayanova, Tamara; Kunakkuzin, Evgeniy; Steshenko, Ekaterina

    2016-04-01

    Palaeoproterozoic Fennoscandian layered intrusions belong to the pyroxenite-gabbronorite-anorthosite formation and spread on a vast area within the Baltic Shield. Based on isotope U-Pb, Sm-Nd, Rb-Sr and Re-Os data the duration of this formation can be to 100-130 Ma (2.53-2.40 Ga) [Serov et. al., 2008; Bayanova et. al., 2009]. We have studied rocks of layered PGE-bearing Fedorovo-Pansky, Monchetundra, Burakovsky, Olanga group intrusions and Penikat intrusion. According to recent and new complex Nd-Sr-REE data magma source of the vast majority of these intrusions was a mantle reservoir with unusual characteristics: negative values of ɛNd (from 0 to -4) and ISr = 0.702-0.706, flat spectra of REE (value of (La/Yb)N ~ 1.0-5.8) with positive Eu-anomalies [Bayanova et. al., 2009; Bayanova et. al., 2014]. However, the distribution of REE for ore-bearing gabbronorite intrusions Penikat (Sm-Nd age is 2426 ± 38 Ma [Ekimova et. al., 2011]) has a negative Eu-anomalies. This may be due to the formation of plagioclase and its removal from the magma chamber. One of the aims of isotope geochemical investigations is to establish the contribution of mantle components in the formation of layered intrusions rocks and the degrees of contamination of the magma source by crustal material. To calculate the proportion of mantle component model binary mixture was used [Jahn et. al., 2000]. As the mantle components we used data for CHUR: ɛNd = 0, [Nd] = 1.324 [Palm, O'Neil, 2003] and for crustal components were used host-rocks Nd-data. The proportion of mantle component for the studied intrusions was 77-99%. Also, data were obtained for the Monchetundra dike complex and amphibolized gabbro, for which the proportion of mantle material was 20-40%. For these rocks a significant crustal contamination is most likely. This process resulted in low values of ɛNd, a direct relationship between ɛNd and Nd concentration, and significant differences between the U-Pb and Sm-Nd model ages. A

  18. Primary differentiation in the early Earth: Nd and Sr isotopic evidence from diamondiferous eclogites for both old depleted and old enriched mantle, Yakutia, Siberia

    Snyder, Gregory A.; Jerde, Eric A.; Taylor, Lawrence A.; Halliday, Alex N.; Sobolev, Vladimir N.; Sobolev, Nickolai V.; Clayton, Robert N.; Mayeda, Toshiko K.; Deines, Peter

    1993-01-01

    Ancient, stable, continental cratons possess thick, subcontinental-lithospheric mantle 'keels' which favor particularly the emplacement of diamondiferous kimberlites and included peridotites and eclogites. These refractory mantle samples of the roots provide hard constraints on the theories of formation, growth, and evolution of these cratons. Xenoliths containing only primary garnet and clinopyroxene (eclogites), although rare in most kimberlites, can retain the geochemical signatures of their parent protoliths (e.g., subducted oceanic crust, ancient mantle) thus offering the opportunity to address mantle processes which may have taken place at earlier times in the Earth's history. In fact, it has been postulated that some eclogites are residues from the accretion of the early Earth. Nd and Sr isotopic data are presented which may be interpreted as evidence of an early (greater than 4 Ga) mantle differentiation event. The kimberlites of Yakutia are located both marginal and central to the Siberian craton, and a wide variety of xenoliths are present within them. The Siberian mantle samples have received little attention in the western world, largely because suitable suites of Yakutian samples have not been readily available. Importantly, there is evidence that metasomatism of the Siberian lithosphere has been considerably less intense or extensive than for the Kaapvaal craton. Therefore, it should be considerably easier to elicit the igneous/metamorphic histories of Siberian kimberlitic xenoliths. One of the notable features of the Siberian eclogites is the common appearance of diamonds, especially in the Mir and Udachnaya pipes. In all, eight eclogite samples (eight garnet separates and eight clinopyroxene separates) have been analyzed to date on the Udachnaya pipe, seven from our group.

  19. Efficient Separation and Accurate Isotopic Determination of Lithium in Brine%盐湖卤水中锂的高效分离及其同位素比值的精确测定进展

    马茹莹; 韩凤清; 罗重光; 闫建平; 张燕霞

    2012-01-01

    The significant relative mass difference between the two stable isotopes of lithium makes a great lithium isotopic fractionation in nature materials. Lithium isotopes, as a tracer, have been used to indicate the material source and formation mechanism of lithium deposit. At present,the lithium isotope ratio was measured by thermal ionization mass spectrometry (TIMS) or the multiple collector inductively coupled plasma mass spectrometry ( MC-ICP-MS). Both methods require the lithium completely separated from other elements. The adsorption method, in all the lithium extractive technique,could produce higher recovery rate and minimize isotopic fractionation. This paper mainly introduced the progress of the separation and accurate isotopic determination of lithium in brine at home and abroad in recent years.%锂的两个稳定同位素相对质量差较大,导致了自然界中的锂同位素分馏强烈.卤水中锂同位素作为良好示踪剂,可用以指示盐湖锂矿床的物质来源和形成机理.现阶段一般用热电离质谱法(TIMS)或多接收器电感耦合等离子质谱法(MC-ICP-MS)测量锂同位素比值,这两种方法都需要将锂从样品中与其它元素完全分离.在现有的卤水提锂方法中,吸附法能够得到较高的锂回收率,减少了锂同位素在提取过程中的分馏效应.本文主要介绍国内外近年来在提取锂和准确测定锂同位素比值方面所取得的进展.

  20. The transfer of (137)Cs, Pu isotopes and (90)Sr to bird, bat and ground-dwelling small mammal species within the Chernobyl exclusion zone.

    Beresford, N A; Gaschak, S; Maksimenko, Andrey; Wood, M D

    2016-03-01

    Protected species are the focus of many radiological environmental assessments. However, the lack of radioecological data for many protected species presents a significant international challenge. Furthermore, there are legislative restrictions on destructive sampling of protected species to obtain such data. Where data are not available, extrapolations are often made from 'similar' species but there has been little attempt to validate this approach. In this paper we present what, to our knowledge, is the first study purposefully designed to test the hypothesis that radioecological data for unprotected species can be used to estimate conservative radioecolgical parameters for protected species; conservatism being necessary to ensure that there is no significant impact. The study was conducted in the Chernobyl Exclusion Zone. Consequently, we are able to present data for Pu isotopes in terrestrial wildlife. There has been limited research on Pu transfer to terrestrial wildlife which contrasts with the need to assess radiation exposure of wildlife to Pu isotopes around many nuclear facilities internationally. Our results provide overall support for the hypothesis that data for unprotected species can be used to adequately assess the impacts for ionising radiation on protected species. This is demonstrated for a range of mammalian and avian species. However, we identify one case, the shrew, for which data from other ground-dwelling small mammals would not lead to an appropriately conservative assessment of radiation impact. This indicates the need to further test our hypothesis across a range of species and ecosystems, and/or ensure adequate conservatism within assessments. The data presented are of value to those trying to more accurately estimate the radiation dose to wildlife in the Chernobyl Exclusion Zone, helping to reduce the considerable uncertainty in studies reporting dose-effect relationships for wildlife. A video abstract for this paper is available from

  1. Geochemical and Sr-Nd isotope variations within Cretaceous continental flood-basalt suites of the Canadian High Arctic, with a focus on the Hassel Formation basalts of northeast Ellesmere Island

    Estrada, Solveig

    2015-11-01

    Early- to mid-Cretaceous flood-basalt suites of the northeast Canadian High Arctic assigned to a High Arctic Large Igneous Province (HALIP) were studied for their whole-rock geochemistry and Sr-Nd isotopes. Data from basalt flows within the upper Albian to lower Cenomanian Hassel Formation of northeast Ellesmere Island are compared with former published data and new inductively coupled plasma mass spectrometry data of the stratigraphic equivalent Strand Fiord basalts and the older, late Hauterivian to Aptian Isachsen basalts from Axel Heiberg Island. The transitional to mildly alkaline aphyric Hassel basalts, with ocean island basalt (OIB)-like geochemical signatures in parts, have an Ar-Ar whole-rock age of on average 96.4 ± 1.6 Ma. They represent two geochemically different flow units without a fractional crystallization relationship: the high-phosphorous (HP) and low-phosphorous (LP) basalts. The Hassel HP basalts differ from the LP basalts by additionally higher Ba, K, Rb, Th and LREE contents, a pronounced positive Eu anomaly (Eu/Eu* = 1.74-1.76), as well as lower Ta, Nb, Zr and Hf concentrations. The Nd and Sr isotope ratios of the Hassel HP basalts [ ɛ Nd( t) of -1.3 to -1.4, 87Sr/86Sr( t) of 0.70706-0.70707] and the LP basalts [ ɛ Nd( t) of 4.5-4.9, 87Sr/86Sr( t) of 0.7038-0.7040] indicate an origin from different mantle sources. The geochemically similar tholeiitic Isachsen (ca. 130-113 Ma) and Strand Fiord basalts (ca. 105-95 Ma) are also incompatible element enriched relative to the primitive mantle, however, with negative Sr-P anomalies as well as partially negative K, Ta and Nb anomalies. In terms of incompatible element ratios (Zr/Nb, Nb/Th), several mantle components are involved in the formation of the flood-basalt suites: a component with primitive mantle composition, an OIB-like component (probably subducted and recycled oceanic crust) and an enriched lithospheric component. The latter component, probably metasomatized subcontinental

  2. A Multi-Isotope (B, Sr, O, H, C) and Age Dating (3H-3He, 14C) Study of Ground Water From Salinas Valley, California: Hydrochemistry, Dynamics, and Contamination Processes

    Vengosh, A; Gill, J; Davisson, M L; Hudson, B G

    2001-08-01

    The chemical and isotopic ({sup 11}B/{sup 10}B, {sup 87}Sr/{sup 86}Sr, {sup 18}O/{sup 16}O, {sup 2}H/H, {sup 13}C/{sup 12}C, {sup 14}C, {sup 3}He/{sup 3}H) compositions of groundwater from the upper aquifer system of the Salinas Valley in coastal central California were investigated in order to delineate the origin and processes of groundwater contamination in this complex system. The Salinas Valley has a relatively deep, confined ''400-foot'' aquifer, overlain by a ''180-foot'' aquifer, and a shallower perched aquifer, all made up of alluvial sand, gravel, and clay deposits. Groundwater from the aquifers have different {sup 14}C ages; fossil ({sup 14}C = 21.3 pmc) for the 400-foot, and modern ({sup 14}C = 72.2 to 98.2 pmc) for the 180-foot. Fresh groundwater in all aquifers is recharged naturally and artificially and through the Salinas River. The two modes of recharge can be distinguished chemically. We identified several different saline components with distinguishable chemical and isotopic fingerprints. (1) Salt-water intrusion in the northern basin has Cl concentrations up to 1700 mg/l, a Na/Cl ratio seawater, {delta}{sup 11}B between +17 and +38 per mil, and {sup 87}Sr/{sup 86}Sr between 0.7088 and 0.7096. Excess dissolved Ca, relative to the expected concentration for simple dilution of seawater, correlates with {sup 87}Sr/{sup 86}Sr ratios, suggesting base exchange reaction with clay minerals. (2) Agriculture return flow is high in NO{sub 3} and SO{sub 4}, with a {sup 87}Sr/{sup 86}Sr = 0.7082, {delta}{sup 11}B = 19 per mil; and {delta}{sup 13}C between -23 and -17 per mil. The {sup 3}H-{sup 3}He ages (5-17 years) and {sup 14}C data suggest vertical infiltration rates of irrigation water of 3 to 10 m/yr. (3) Non-marine saline water in the southern part of the valley has high TDS up to 3800 mg/l, high SO{sub 4}, Na/Cl ratio >1, {delta}{sup 11}B between +24 and +30 per

  3. Nd and Sr Isotopic, Geochemical and Petrographic Characteristics of the Morro de São João Alkaline Intrusion: Geodynamic Implications and the Composition of the Sub-lithosperical Mantle

    Renata de Oliveira Loureiro

    2009-01-01

    Full Text Available The Morro de São João Alkaline Complex (MSJ is located in the NE part of Rio de Janeiro State and shows pronounced topography, with the following lithology: coarse-grained felsic syenites (K-feldspar, nepheline, hornblende, titanite and pseudoleucite, and mafi c syenites (with K-feldspar, hornblende and piroxene. Petrography and lithogeochemistry data suggest a bimodal suite. Felsic and mafi c magma mixing and mingling textures are locally observed indicating thepresence of coeval magmas. Nd and Sr isotope compositions correspond to EMI (Enriched Mantle I mantle reservoir signatures,suggesting an asthenospheric enriched mantle source with low 87Sr/86Sr values (from 0.7049 to 0.7061 and low 143Nd/144Nd (from 0.512361 to 0.512428. The εNd values range from -4.03 to -5.54, indicating an anomalous enriched mantle reservoir, confi rmed by the high TDM values between 730 - 830 Ma, very different from the 72 - 56 Ma K-Ar cooling ages. The comparison of Sr and Nd signatures with related hotspot traces (Trindade, St. Helena and Tristan da Cunha indicates that they are similar to those of Tristan da Cunha, but somewhat different from those of Trindade and St. Helena.

  4. Rapid Simultaneous Determination of 89Sr and 90Sr in Milk: A Procedure Using Cerenkov and Scintillation Counting

    Since 2004, the IAEA programme related to the terrestrial environment has included activities aimed at developing and testing a set of procedures for the determination of radionuclides in environmental samples. Both 89Sr and 90Sr are fission products that can be, and have been, released to the environment during nuclear explosions and nuclear reactor accidents. Since strontium uptake from milk is an important pathway for incorporation of radioactive strontium into the human body, the rapid and accurate analysis of radioactive strontium isotopes in milk is of crucial importance in emergency situations in order to protect the public from radiation hazards. This report describes a new approach for the rapid determination of 89Sr and 90Sr in milk using Cerenkov and scintillation counting methods that was tested and validated by the analysis of four spiked milk samples in terms of repeatability, reproducibility and trueness (relative bias) in accordance with ISO guidelines. The report also describes the calculation of the uncertainty budget. This research was proposed in 2007 at the Asia-Pacific regional meeting of the IAEA Analytical Laboratories for the Measurement of Environmental Radioactivity (ALMERA) network. Several ALMERA network laboratories participated in the validation procedure by performing reproducibility tests. The resulting recommended procedure is designed to be of general use to a wide range of laboratories, including those in the ALMERA network. It is expected that this rapid method for determining 89Sr and 90Sr in milk will be useful in emergency conditions and for routine environmental monitoring of elevated levels of radioactivity

  5. U-Pb zircon SHRIMP ages, geochemical and Sr-Nd isotopic compositions of the Early Cretaceous I-type Sarıosman pluton, Eastern Pontides, NE Turkey

    KAYGUSUZ, ABDULLAH; Chen, Bin; Zafer ASLAN; ŞEN, WOLFGANG SIEBEL & CÜNEYT

    2009-01-01

    The petrogenesis and U-Pb SHRIMP zircon ages of the Late Cretaceous Sarıosman pluton in the Eastern Pontides is investigated by means of whole-rock Sr-Nd isotope data with field, petrographic and whole-rock geochemical studies. The bulk of the I-type Sarıosman pluton consists of biotite-hornblende monzogranite, with minor quantities of porphyritic hornblende-biotite monzogranite. The biotite-hornblende monzogranite contains a number of mafic microgranular enclaves (MMEs) of quartz monzodiorit...

  6. Geochemistry and Sr-Nd isotopes of the subvolcanic sill complex and sandstone geochronology from María Magdalena island, Nayarit, Mexico

    Villanueva, D.; Schaaf, P. E.; Hernandez, T.; Solis, G.; Weber, B.; Pompa, V.

    2013-12-01

    María Magdalena island is part of the Islas Marías archipielago, located at the mouth of the Gulf of California. Understanding the nature and origin of the archipelago is very important for reconstructing the paleoposition of Baja California Peninsula prior to the opening of the Gulf of California. We present the first geochemical, isotopic and geochronologic data from María Magdalena, a lithologically different island compared to the rest of the archipelago. María Magdalena island is located southeast of María Madre and northeast of María Cleofas islands and is composed by a sedimentary sequence of sandstones and minor shale, which is intruded by gabbroic sills. The sedimentary sequence dips approximately 20 degrees to the NW. The thickness of sills range from 1 to 3 meters with mineralogical variations of plagioclase +/- orthopyroxene +/- clinopyroxene +/- hornblende and some altered olivine crystals. Textures are mostly porphyritic with plagioclase crystals sizes up to 5 cm and olivines up to 5 mm. The gabbroic sills show SiO2 contents from 42.7 to 47.5 wt. %; TiO2 from 0.8 to 2 wt. %; Fe2O3t from 7.7 to 11.9 wt. %; MgO from 6.2 to 19.8 wt. % and of CaO from 6 to 11.6 wt. %, indicating mafic to ultramafic compositions. A multielement spider diagram as well as REE patterns show compositions very similar to N-MORB or even peridotites, which is confirmed by 87Sr/86Sr values from 0.70273 to 0.70497, and 143Nd/144Nd values from 0.513003 to 0.513100. U-Pb single zircon geochronology of the intruded sandstones display the following age distribution: eight crystals show ages from 80 to 86 Ma, three crystals have ages from 61 to 72 Ma, and three are around 21 Ma which constrains a maximum sandstone deposition age. Consequently, the sills must be younger than 21 Ma. There is not much lithological similarity with neighboring María Madre island to the NW (containing a metamorphic complex, granitoids and acid volcanic roks) and with María Cleofas island to the SE

  7. Isotopic imprints of mountaintop mining contaminants.

    Vengosh, Avner; Lindberg, T Ty; Merola, Brittany R; Ruhl, Laura; Warner, Nathaniel R; White, Alissa; Dwyer, Gary S; Di Giulio, Richard T

    2013-09-01

    Mountaintop mining (MTM) is the primary procedure for surface coal exploration within the central Appalachian region of the eastern United States, and it is known to contaminate streams in local watersheds. In this study, we measured the chemical and isotopic compositions of water samples from MTM-impacted tributaries and streams in the Mud River watershed in West Virginia. We systematically document the isotopic compositions of three major constituents: sulfur isotopes in sulfate (δ(34)SSO4), carbon isotopes in dissolved inorganic carbon (δ(13)CDIC), and strontium isotopes ((87)Sr/(86)Sr). The data show that δ(34)SSO4, δ(13)CDIC, Sr/Ca, and (87)Sr/(86)Sr measured in saline- and selenium-rich MTM impacted tributaries are distinguishable from those of the surface water upstream of mining impacts. These tracers can therefore be used to delineate and quantify the impact of MTM in watersheds. High Sr/Ca and low (87)Sr/(86)Sr characterize tributaries that originated from active MTM areas, while tributaries from reclaimed MTM areas had low Sr/Ca and high (87)Sr/(86)Sr. Leaching experiments of rocks from the watershed show that pyrite oxidation and carbonate dissolution control the solute chemistry with distinct (87)Sr/(86)Sr ratios characterizing different rock sources. We propose that MTM operations that access the deeper Kanawha Formation generate residual mined rocks in valley fills from which effluents with distinctive (87)Sr/(86)Sr and Sr/Ca imprints affect the quality of the Appalachian watersheds. PMID:23909446

  8. U/Pb, Sm/Nd and Rb/Sr geochronological and isotopic study of northern Sierra Nevada ophiolitic assemblages, California

    Saleeby, J. B.; Shaw, H. F.; Niemeyer, Sidney; Moores, E. M.; Edelman, S. H.

    1989-06-01

    Distinct ophiolitic assemblages occur as oceanic basement within three of the four regional tectonic belts of the northern Sierra Nevada. New U/Pb zircon, Sm/Nd and Rb/Sr data are presented for each assemblage, providing critical geochronological and isotopic constraints on the petrogenesis and tectonic evolution of the ophiolitic and associated ensimatic assemblages. Ophiolitic assemblages include from west to east the Smartville complex, Central belt and Feather River belt. The Smartville complex represents an island arc volcanic-plutonic sequence with a major late-stage sheeted dike swarm. The Sm/Nd systems from a wide compositional spectrum of rocks record a 178±21 Ma petrogenetic age and an ɛ Nd(T)=+9.2±0.6. Zircon U/Pb systems on an uppermost dacite yield a 164±2 Ma age, and on a number of plagiogranite screens and dikes from the sheeted complex 162±1 Ma ages. The Central and Feather River belts are structurally complex polygenetic assemblages. The U/Pb zircon and Sm/Nd systems record major ˜205 Ma and ˜315 Ma petrogenetic events respectively both involving depleted mantle derived magmas. Such magmatism probably occurred in marginal basin/transform systems developed within an older oceanic depleted mantle basement regime. Both Sm/Nd and U/Pb zircon systems show local components of Proterozoic sialic material. The sialic contaminants were probably introduced into the system as craton derived detritus. It is doubtful that any of the ophiolitic assemblages studied represent genetically related crust-upper mantle sequences generated during the development of new oceanic lithosphere. Integration of the geochronological data with geological relations reveals a pattern of petrogenesis and tectonics whereby progressively younger ensimatic terranes were added to the continental margin through time by plate convergence, and were ultimately welded into North American sial by a crosscutting batholithic belt. This accretionary pattern is reflected in both the

  9. B, Sr and Pb isotope geochemistry of high-pressure Alpine metaperidotites monitors fluid-mediated element recycling during serpentinite dehydration in subduction mélange (Cima di Gagnone, Swiss Central Alps)

    Cannaò, E.; Agostini, S.; Scambelluri, M.; Tonarini, S.; Godard, M.

    2015-08-01

    Tectonic mixing of slab- and mantle-derived materials at the interface between converging plates highly enhances fluid-mediated mass transfer from the slab to the overlying mantle. Subduction mélanges can provide information about the interaction among different slices accreted at plate interface domains, with implications on the tectonic and geochemical evolution of the plate-interface itself. At Cima di Gagnone, pelitic schists and gneiss enclose chlorite harzburgite and garnet peridotite lenses, like in subduction mélanges located in-between downgoing slabs and overlying mantle. These peridotites host MORB-type eclogite and metarodingite, and derive from dehydration of serpentinized mantle protoliths. Their enrichment in fluid-mobile B, As, Sb, U, Th is the result of an early-stage oceanic serpentinization, followed by interaction with host metasediments during subduction burial. Here we define the element exchange process in the Gagnone mélange by means of the B, Sr and Pb isotope analysis of its main lithologies (ultramafic, mafic rocks and paragneiss). The 87Sr/86Sr and 206Pb/204Pb ratios of ultramafic rocks (0.7090-0.7124 and 18.292-18.837, respectively) show enrichments in radiogenic Sr and Pb after exchange with the host paraschist (up to 0.7287 87Sr/86Sr; 18.751 206Pb/204Pb). The δ11B values of peridotites (down to -10‰) point to a combined effect of (1) 11B release to deserpentinization fluids (serpentinized protoliths likely had positive δ11B and lower radiogenic Sr, Pb), and of (2) exchange with fluids from the surrounding metasediments. The whole Gagnone rock-suite is finally overprinted by retrograde fluids that essentially bring to an increase in radiogenic Pb (about 19.0 206Pb/204Pb) and to values of 0.710 87Sr/86Sr and of -10‰ δ11B. The recognition of different stages of interaction between mantle rocks and sedimentary/crustal reservoirs allows us to define the geochemical effects related to the early coupling of such rocks along the

  10. Accurate measurement of stable isotopes 46Ca and 48Ca in human feces, plasma, and urine in relation to human nutrition of calcium

    A method based on Radiochemical Neutron Activation Analysis (RNAA) is described which allows simultaneous measurement of two stable isotopes of calcium, 46Ca and 48Ca, in human feces, plasma, and urine for the purpose of studying human nutrition and metabolism of calcium. It is shown that these measurements can be made with relative analytical precision of 1-5% depending on the particulars of a given experiment. The method has been applied in humans and data are given showing that kinetics of plasma appearance of 46Ca administered orally with food can be readily investigated. This method allows investigation of a number of important nutritional and metabolic issues in all human population groups without regard to radioisotope safety considerations, and should prove especially helpful in relation to studies of calcium bioavailability from different foods in a variety of population groups for whom use of radiocalcium is not warranted. (Auth.)

  11. Overlapping Sr-Nd-Hf-O isotopic compositions in Permian mafic enclaves and host granitoids in Alxa Block, NW China: Evidence for crust-mantle interaction and implications for the generation of silicic igneous provinces

    Dan, Wei; Wang, Qiang; Wang, Xuan-Ce; Liu, Yu; Wyman, Derek A.; Liu, Yong-Sheng

    2015-08-01

    In general, the mantle provides heat and/or material for the generation of the silicic igneous provinces (SIPs). The rarity of mafic microgranular enclaves (MMEs), however, hampers understanding of the mantle's role in generating SIPs and the process of crust-mantle interaction. The widespread distributed MMEs in the newly reported Alxa SIP provide an opportunity to study these processes. This study integrates in situ zircon U-Pb age and Hf-O isotope analyses, whole-rock geochemistry and Sr-Nd isotope results for the MMEs and host granitoids in the Alxa Block. SIMS zircon U-Pb dating reveals that there are two generations of MMEs and host granitoids. The MMEs in the Bayannuoergong batholith were formed at ca. 278 Ma, similar to the age (280 Ma) of host granitoids, and the MMEs and host granitoids in the Yamaitu pluton were formed at ca. 272-270 Ma. All MMEs have relatively low SiO2 (50.7-61.4 wt.%) and Th (0.8-2.8 ppm), but relatively high MgO (2.6-4.9 wt.%), Cr (23-146 ppm) and Ni (6-38 ppm) contents compared to the host granitoids, with SiO2 (63.6-77.5 wt.%), Th (5.2-41 ppm), MgO (0.23-2.1 wt.%), Cr (10-38 ppm) and Ni (5-14 ppm). All MMEs have whole rock Sr-Nd and zircon Hf-O isotope compositions similar to their corresponding host granitoids. The 280 Ma MMEs have lower whole rock εNd(t) (- 13.5) and higher initial 87Sr/86Sr values (0.7095) and zircon δ18O values (6.3‰) compared to the εNd(t) (- 11.5), initial 87Sr/86Sr values (0.7070) and zircon δ18O values (5.6‰) of the 270 Ma MMEs. The occurrences of quartz xenocrysts, K-feldspar megacrysts, corroded feldspars and acicular apatites indicate that the MMEs are the products of the mixing between mantle- and crust-derived magmas. The striking similarities in the zircon Hf-O isotopic compositions in both MME-host granitoid pairs indicate that the granitoids and MMEs have similar sources. The granitoids are proposed to be mainly sourced from magmas generated by remelting of newly formed mafic rocks, which

  12. Constraints on the evolution of the Japan Sea based on 40Ar-39Ar ages and Sr isotopic ratios for volcanic rocks of the Yamato Seamount chain in the Japan Sea

    40Ar-39Ar and Sr isotope analyses were performed on basalts and andesites dredged from the Yamato Seamount chain in the Japan Sea. The 40Ar-39Ar plateau ages range from about 11 to 17 Ma, though most samples show ages between 10 and 14 Ma. The seamounts seem to have formed within a period of a few million years, although some of them might have formed earlier. Based on the present results together with previously reported radiometric age data, it is thought that the Yamato Basin formed during some period prior to 17 Ma and probably later than around 25 Ma. Taking into account the radiometric age data on rocks from the Japan Basin, it is conjectured that the opening of the Japan Sea might have started almost at this time or a little earlier. The observed 87Sr/86Sr ratios range from 0.70357 to 0.70388, suggesting incorporation of some time-integrated components enriched in incompatible elements such as continental crustal materials. This may indicate that in the Japan Sea area, at least the Yamato Basin had not developed enough to show the characteristics of typical N-type MORB source materials without being affected by pre-existing continental crustal materials. (orig.)

  13. Influence of bacteria on lanthanide and actinide transfer from specific soil components (humus, soil minerals and vitrified municipal solid waste incinerator bottom ash) to corn plants: Sr-Nd isotope evidence

    Experiments have been performed to test the stability of vitrified municipal solid waste (MSW) incinerator bottom ash under the presence of bacteria (Pseudomonas aeruginosa) and plants (corn). The substratum used for the plant growth was a humus-rich soil mixed with vitrified waste. For the first time, information on the stability of waste glasses in the presence of bacteria and plants is given. Results show that inoculated plant samples contained always about two times higher lanthanide and actinide element concentrations. Bacteria support the element transfer since plants growing in inoculated environment developed a smaller root system but have higher trace element concentrations. Compared with the substratum, plants are light rare earth element (LREE) enriched. The vitrified bottom ash has to some extent been corroded by bacteria and plant activities as indicated by the presence of Nd (REE) and Sr from the vitrified waste in the plants. 87Sr/86Sr and 143Nd/144Nd isotope ratios of plants and soil components allow the identification of the corroded soil components and confirm that bacteria accelerate the assimilation of elements from the vitrified bottom ash. These findings are of importance for landfill disposal scenarios, and similar experiments should be performed in order to better constrain the processes of microbially mediated alteration of the MSW glasses in the biosphere

  14. Multiple sources for the origin of Late Jurassic Linglong adakitic granite in the Shandong Peninsula, eastern China: Zircon U-Pb geochronological, geochemical and Sr-Nd-Hf isotopic evidence

    Ma, Liang; Jiang, Shao-Yong; Dai, Bao-Zhang; Jiang, Yao-Hui; Hou, Ming-Lan; Pu, Wei; Xu, Bin

    2013-03-01

    The Linglong granite is one of the most important Mesozoic plutons in the Shandong Peninsula, eastern China, and its petrogenesis has long been controversial, particularly with regard to the nature of source region and geodynamic setting. Our new precise zircon U-Pb dating results reveal that the Linglong granite was emplaced in the Late Jurassic (157-160 Ma). In addition, abundant inherited zircons are identified in the granite with four groups of age peaked at ~ 208, ~ 750, ~ 1800 and ~ 2450 Ma. Geochemical studies indicate that the Linglong granite is weakly peraluminous I-type granite, and is characterized by high SiO2, Sr and La, but low MgO, Y and Yb contents, strongly fractionated REE pattern and high Sr/Y and La/Yb ratios. It also exhibits high initial 87Sr/86Sr ratios (0.7097 to 0.7125), low ɛNd(t) (- 17.7 to - 20.3) and variable zircon ɛHf(t) (- 22.2 to - 8.7) values. Calculation of the zircon saturation temperature (TZr) reveals that the magma temperatures are 760 ± 20 °C, and the lowest TZr value of 740 °C may be close to initial magma temperature of this inheritance-rich rock. Interpretation of the elemental and isotopic data suggests that the Linglong granite has some affinities with the adakite, and was most likely derived from partial melting of thickened lower crust without any significant contribution of mantle components. The presence of a large number of inherited zircons and variable Sr-Nd-Hf isotopic compositions reveal that the Linglong granite probably has multiple sources consisting of the lower crust of both South China Block and North China Block, as well as the collision-related alkaline rocks and UHP metamorphic rocks. The continental arc-rifting related to the Izanagi plate subduction was the most likely geodynamic force for formation of the Jurassic Linglong adakatic granite in the Shandong Peninsula.

  15. U-Pb zircon, geochemical and Sr-Nd-Hf-O isotopic constraints on age and origin of the ore-bearing intrusions from the Nurkazgan porphyry Cu-Au deposit in Kazakhstan

    Shen, Ping; Pan, Hongdi; Seitmuratova, Eleonora; Jakupova, Sholpan

    2016-02-01

    Nurkazgan, located in northeastern Kazakhstan, is a super-large porphyry Cu-Au deposit with 3.9 Mt metal copper and 229 tonnage gold. We report in situ zircon U-Pb age and Hf-O isotope data, whole rock geochemical and Sr-Nd isotopic data for the ore-bearing intrusions from the Nurkazgan deposit. The ore-bearing intrusions include the granodiorite porphyry, quartz diorite porphyry, quartz diorite, and diorite. Secondary ion mass spectrometry (SIMS) zircon U-Pb dating indicates that the granodiorite porphyry and quartz diorite porphyry emplaced at 440 ± 3 Ma and 437 ± 3 Ma, respectively. All host rocks have low initial 87Sr/86Sr ratios (0.70338-0.70439), high whole-rock εNd(t) values (+5.9 to +6.3) and very high zircon εHf(t) values (+13.4 to +16.5), young whole-rock Nd and zircon Hf model ages, and consistent and slightly high zircon O values (+5.7 to +6.7), indicating that the ore-bearing magmas derived from the mantle without old continental crust involvement and without marked sediment contamination during magma emplacement. The granodiorite porphyry and quartz diorite porphyry are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE) and depleted in high-field strength elements (HFSE), Eu, Ba, Nb, Sr, P and Ti. The diorite and quartz diorite have also LILE and LREE enrichment and HFSE, Nb and Ti depletion, but have not negative Eu, Ba, Sr, and P anomalies. These features suggest that the parental magma of the granodiorite porphyry and quartz diorite porphyry originated from melting of a lithospheric mantle and experienced fractional crystallization, whereas the diorite and quartz diorite has a relatively deeper lithospheric mantle source region and has not experienced strong fractional crystallization. Based on these, together with the coeval ophiolites in the area, we propose that a subduction of the Balkhash-Junggar oceanic plate took place during the Early Silurian and the ore-bearing intrusions and associated Nurkazgan

  16. Pb, Nd and Sr isotopic compositions of feldspar, apatite and sphene as a guide to the nature of the sub-Andean mantle and crust-mantle interaction in the coastal batholith, Peru

    Mukasa, S.B.; Barreiro, B.A.

    1985-01-01

    Common Pb isotopic compositions for 65 feldspar samples from the 188-37 Ma gabbroic to monzogranitic plutons of the Peruvian Coastal batholith (PCB) show changes along strike that can be related to variable contamination of mantle-derived magmas by Precambrian basement (PB). The dominant Pb component in mafic plutons of the Lima segment (LS) is similar to the isotopically homogeneous reservoir (IHR) identified by others for rocks in central and southern Chile. It has been suggested that the IHR is enriched subcontinental mantle. More siliceous rocks in the LS have considerably higher Pb ratios, suggesting that they have a component of supracrustal materials. Feldspars from plutons in the Arequipa and Toquepala segments (ATS) of the PCB have low PB ratios. The data plot between the PB and IHR fields on Pb correlation diagrams, indicating that these end members were the principal magma sources in southern Peru. /sup 143/Nd//sup 144/Nd and /sup 87/Sr//sup 86/Sr compositions for a small group of apatite and sphene samples selected on the basis of extreme PB ratios in coexisting feldspars are negatively correlated and support the magmagenetic models proposed using the more thorough Pb analyses. Also, mass balance considerations using Nd and Sr concentrations suggest that contamination of IHR magmas by PB was magmatic and not the result of subsolidus diffusion. Contamination of plutons in the ATS by PB and lack of it in the LS supports crustal models by Couch et al. (1981) and Jones (1981) which show a thick PB layer in southern Peru and an extremely thin layer beneath the LS.

  17. Zircon U-Pb geochronology, geochemical and Sr-Nd-Hf isotopic compositions of the Triassic granite and diorite dikes from the Wulonggou mining area in the Eastern Kunlun Orogen, NW China: Petrogenesis and tectonic implications

    Ding, Qing-Feng; Jiang, Shao-Yong; Sun, Feng-Yue

    2014-09-01

    The Wulonggou mining area in the Eastern Kunlun Orogen of NW China is characterized by extensive granitoid magmatism, ductile faulting, and skarn-type Cu-Pb-Zn and orogenic gold mineralizations. The Balugou granite dike, which hosts skarn-type Cu-Pb-Zn mineralizations, is located in northeast Wulonggou, whereas the Huanglonggou diorite dike, which is cut by the Huanglonggou gold veins, is located in the central part of the area. This study investigated the major and trace-element compositions, zircon U-Pb dates, and Sr-Nd-Hf isotopic compositions of these rocks. Three Balugou granite dike samples yielded an average zircon U-Pb age of ~ 244 Ma (Anisian), and two Huanglonggou diorite dike samples yielded an average zircon U-Pb age of ~ 215 Ma (Norian). Therefore, the skarn-type mineralizations in the Wulonggou area formed during the early Anisian (~ 244 Ma), and the orogenic gold mineralizations formed after 215 Ma. The Anisian Balugou granite dike is metaluminous to slightly peraluminous and has high alkali contents of 7.19-9.57 wt.%, high Zr + Nb + Ce + Y contents, high Fe2O3T/MgO ratios, and high Rb/Nb and Y/Nb ratios, which suggest an A-type affinity. The Norian Huanglonggou diorite dike is metaluminous and has high Al2O3 contents (15.61-16.40 wt.%), high Mg# values (0.49-0.54), relatively high Sr contents (370-507 ppm), high Sr/Y ratios, high (La/Yb)N ratios, and low HREE and Y contents, which suggest an adakite-like high-Mg diorite. The Anisian granite dike has initial 87Sr/86Sr (ISr) ratios of 0.707289 to 0.708981, εNd(t) values of - 3.6 to - 3.1, and zircon εHf(t) values of - 3.9 to + 1.3. The Norian diorite dike has initial 87Sr/86Sr (ISr) ratios of 0.709166 to 0.709529, εNd(t) values of - 5.7 to - 5.1, and zircon εHf(t) values of - 4.9 to - 1.0. The Sr-Nd-Hf isotopic data suggest that the Anisian granite dike was likely derived from partial melting of dominantly Mesoproterozoic mafic lower crust, whereas the Norian diorite dike was likely derived from

  18. Origin of groundwater salinity (current seawater vs. saline deep water) in a coastal karst aquifer based on Sr and Cl isotopes. Case study of the La Clape massif (southern France)

    Highlights: • Increase in salinity of studied groundwater is due to a rise of deep saline water. • No evidence of seawater intrusion, most likely due to thick offshore deposit. • Geochemical modelling differentiates between modern and old evolved seawaters. • 87Sr/86Sr and 36Cl/Cl ratios are suitable tracers of costal karst waters. • Anthropogenic contaminations are identified in the studied groundwater. - Abstract: In this study a typical coastal karst aquifer, developed in lower Cretaceous limestones, on the western Mediterranean seashore (La Clape massif, southern France) was investigated. A combination of geochemical and isotopic approaches was used to investigate the origin of salinity in the aquifer. Water samples were collected between 2009 and 2011. Three groundwater groups (A, B and C) were identified based on the hydrogeological setting and on the Cl− concentrations. Average and maximum Cl− concentrations in the recharge waters were calculated (ClRef. and ClRef.Max) to be 0.51 and 2.85 mmol/L, respectively). Group A includes spring waters with Cl− concentrations that are within the same order of magnitude as the ClRef concentration. Group B includes groundwater with Cl− concentrations that range between the ClRef and ClRef.Max concentrations. Group C includes brackish groundwater with Cl− concentrations that are significantly greater than the ClRef.Max concentration. Overall, the chemistry of the La Clape groundwater evolves from dominantly Ca–HCO3 to NaCl type. On binary diagrams of the major ions vs. Cl, most of the La Clape waters plot along mixing lines. The mixing end-members include spring waters and a saline component (current seawater or fossil saline water). Based on the Br/Clmolar ratio, the hypothesis of halite dissolution from Triassic evaporites is rejected to explain the origin of salinity in the brackish groundwater. Groundwaters display 87Sr/86Sr ratios intermediate between those of the limestone aquifer matrix and

  19. 90Sr liquid scintillation urine analysis utilizing different approaches for tracer recovery.

    Piraner, Olga [Centers for Disease Control and Prevention, Atlanta, GA; Preston, Rose T. [Sandia Staffing Alliance, LLC, Albuquerque, NM; Shanks, Sonoya Toyoko; Jones, Robert [Centers for Disease Control and Prevention, Atlanta, GA

    2010-08-01

    90Sr is one of the isotopes most commonly produced by nuclear fission. This medium lived isotope presents serious challenges to radiation workers, the environment, and following a nuclear event, the general public. Methods of identifying this nuclide have been in existence for a number of years (e.g. Horwitz, E.P. [1], Maxwell, S.L.[2], EPA 905.0 [3]) which are time consuming, requiring a month or more for full analysis. This time frame is unacceptable in the present security environment. It is therefore important to have a dependable and rapid method for the determination of Sr. The purposes of this study are to reduce analysis time to less than half a day by utilizing a single method of radiation measurement while continuing to yield precise results. This paper presents findings on three methods that can meet this criteria; (1) stable Sr carrier, (2) 85Sr by gamma spectroscopy, and (3) 85Sr by LSC. Two methods of analyzing and calculating the 85Sr tracer recovery were investigated (gamma spectroscopy and a low energy window-Sr85LEBAB by LSC) as well as the use of two different types of Sr tracer (85Sr and stable Sr carrier). Three separate stock blank urine samples were spiked with various activity levels of 239Pu, 137Cs, 90Sr /90Y to determine the effectiveness of the Eichrome Sr-spec%C2%AE resin 2mL extractive columns. The objective was to compare the recoveries of 85Sr versus a stable strontium carrier, attempt to compare the rate at which samples can be processed by evaluating evaporation, neutralization, and removing the use of another instrument (gamma spectrometer) by using the LSC spectrometer to obtain 85Sr recovery. It was found that when using a calibration curve comprised of a different cocktail and a non-optimum discriminator setting reasonable results (bias of %C2%B1 25%) were achieved. The results from spiked samples containing 85Sr demonstrated that a higher recovery is obtained when using gamma spectroscopy (89-95%) than when using the LEB window

  20. U-Pb geochronology and Sr-Nd isotopes of Galileia and Urucum neo proterozoic granitoids suites in south-eastern Brazil; Geochronologie U-Pb et geochimie isotopique Sr-Nd des granitoides neoproterozoiques des suites Galileia et Urucum, vallee du Rio Doce, Sud-Est du Bresil

    Herminio Arias Nalini Jr [Universidade Federal de Ouro Preto, Dept. de Geologia, Minas Gerais (Brazil); Herminio Arias Nalini Jr; Essaid Bilal [Ecole Nationale Superieure des Mines, Dept. de Geochimie, Centre SPIN, 42 - Saint-Etienne (France); Paquette, J.L.; Pin, Ch. [Universite Blaise Pascal, Clermont-Ferrand II, (CNRS-UMR 6525), 63 - Aubiere (France); Romulo, M. [IGG Universite de Sao Paulo (Brazil)

    2000-10-01

    U-Pb zircon and monazite dating and whole-rock Sr-Nd isotopes have been applied on Neo-Proterozoic granitoids from the Atlantic shear belt, south-eastern Brazil. U-Pb zircon results on the Galileia met-aluminous and Urucum per-aluminous suites indicate crystallisation ages of 594 {+-} 6 Ma and 582 {+-} 2 Ma respectively. Whole-rock Rb-Sr and Sm-Nd analyses on representative samples from both suites demonstrate that they mainly derive from melting of older crustal rocks. The occurrence of an old isotopic memory in the zircons from the Urucum granitoids around 2.2 Ga, in agreement with Nd model ages, suggests a Palaeo-Proterozoic age for the crustal proto-lith of these two suites, probably associated with the Transamazonico event. Owing to these new dating results and previous regional geochronological data, it can be proposed that the met-aluminous magmatism ended around 590 Ma and that the collisional peraluminous magmatism associated with the Brasiliano orogeny occurred between 584 and 570 Ma. (authors)

  1. Clay minerals and Sr-Nd isotopes of the sediments along the western margin of India and their implication for sediment provenance

    Kessarkar, P.M.; Rao, V.P.; Ahmad, S.M.; Babu, G.A.

    the central Indian Basin, Bengal Fan and the Ocean Drilling Program (ODP) cores of the distal Bengal Fan (Rea, 1992; Fagel et al., 1994, 1997; Bouquillon et al., 1990; France-Lanord et al., 1993; Derry and France-Lanord, 1996; Colin et al., 1999) were reported...¡ the Ganges^Brahmaputra (0.720^ 0.726; 312.5 to 312.8), or the Ganges River (s0.735; 315.0) (see Bouquillon et al., 1990; France-Lanord et al., 1993; Derry and France- Lanord, 1996; Colin et al., 1999). The 87 Sr/ 86 Sr vs. O Nd plot of the samples also falls...

  2. Rb-Sr and Sm-Nd isotopic compositions and Petrogenesis of ore-related intrusive rocks of gold-rich porphyry copper Maherabad prospect area (North of Hanich), east of Iran

    The Maherabad gold-rich porphyry copper prospect area is located in the eastern part of Lut block, east of Iran. This is the first porphyry Cu-Au prospecting area which is discovered in eastern Iran. Fifteen mineralization-related intrusive rocks range (Middle Eocene 39 Ma) in composition from diorite to monzonite have been distinguished. Monzonitic porphyries had major role in Cu-Au mineralization. The ore bearing porphyries are I-type, meta luminous, high-Kcalc-alkaline to shoshonite intrusive rocks which were formed in island arc setting. These rocks are characterized by average of SiO2> 59 wt %, Al2O3 > 15 wt %, MgO2O> 3 wt %, Sr> 870 ppm, Y 55, moderate Light rare earth elements, relatively low heavy rare earth elements and enrichment LILE (Sr, Cs, Rb, K and Ba) relative to HFSE (Nb, Ta, Ti, Hf and Zr). They are chemically similar to some adakites, but their chemical signatures differ in some ways from normal adakites, including higher K2O contents and K2O/Na2O ratios and lower Mg, (La/Yb)N, (Ce/Yb)N and εNd in Maherabad rocks. Maherabad intrusive rocks are the first K-rich adakites that can be related with subduction zone. Partial melting of mantle hybridized by hydrous, silica-rich slab-derived melts or/and input of enriched mantle-derived ultra-potassic magmas during or prior to the formation and migration of adakitic melts could be explain their high K2O contents and K2O/Na2ratios. Low Mg values and relatively low MgO, Cr and Ni contents imply limited interaction between adakite-like magma and mantle wedge peridotite. The initial 87Sr/86Sr and (143Nd/144Nd)i was recalculated to an age of 39 Ma (unpublished data). Initial 87Sr/86Sr ratios for hornblende monzonite porphyry are 0.7047-0.7048. The (143Nd/144Nd)i isotope composition are 0.512694-0.512713. Initial εNd isotope values 1.45-1.81. These values could be considered as representative of oceanic slab-derived magmas. Source modeling indicates that high-degree of partial melting (relatively up to 50

  3. Geochemical and Sr-Nd-Hf isotopic constraints on the origin of Late Triassic granitoids from the Qinling orogen, central China: Implications for a continental arc to continent-continent collision

    Jiang, Yao-Hui; Jin, Guo-Dong; Liao, Shi-Yong; Zhou, Qing; Zhao, Peng

    2010-06-01

    The Qinling-Dabie-Sulu orogen marks the junction between the North and South China Blocks. However, the exact timing of the final coalescence of the North and South China Blocks in the Qinling orogen is poorly constrained. This paper presents new SHRIMP zircon U-Pb chronology, major and trace elements, and Sr-Nd-Hf isotope data for five early Mesozoic granitic plutons across the Qinling orogen. SHRIMP zircon U-Pb dating shows that four plutons were emplaced in the Carnian (227-218 Ma) of Late Triassic with a southward-younging trend and one pluton was emplaced in the Norian (˜ 211 Ma) of Late Triassic. The Carnian plutons consist of high-K calc-alkaline granitoids (quartz monzodiorite, quartz monzonite, granodiorite and monzogranite) and calc-alkaline diorite. These rocks are mainly metaluminous and are characterized by high Sr and low Y and Yb contents, with high Sr/Y and La/Yb ratios, and by high Mg#, higher than pure crustal melts. The Norian pluton is composed of high-K calc-alkaline two-mica granites, which are peraluminous. These granites have low Sr and high Y and Yb contents and show similar Mg# to pure crustal melts. Detailed elemental and isotopic data suggest that the Carnian plutons were emplaced in a continental arc setting coupled with the northward subduction of the Paleo-Tethyan oceanic crust. Partial melting of subducted sediments triggered by dehydration of the underlying igneous oceanic crust, with subsequent melts interacting with the overlying mantle wedge, formed the high-K calc-alkaline granitic magmas. Partial melting of the hybridized peridotitic mantle wedge induced by slab melts generated the calc-alkaline dioritic magma. The Norian pluton was emplaced during continental collision between the South Qinling terrane and South China Block, which marks the final integration of the North and South China Blocks. Partial melting of subducted sediments at a shallow depth (origin of the Norian peraluminous granites. Our new data suggest that the

  4. A method to determine 89Sr and 90Sr when they are in mixture

    89Sr and 90Sr are among the most dangerous types of radioactive fallout from biological view point. Particular concern about 89Sr and 90Sr is due to their chemical similarity to calcium. These radionuclides in water soluble form are absorbed by rain and they are eventually incorporated into human bones and teeth causing a potential danger to human life. Because of the great need for accurate measurement of 90Sr in environmental samples which also contain 89Sr and because no specific method has been published for the determination of 90Sr and 89Sr when they are in mixture, the following method was established: (1) enough time is allowed for the sample to reach the steady state between 90Sr and its daughter 90Y then the 90Y is milked; (2) 90Y is counted separately to determine the activity of 90Sr; (3) the solution, after 90Y is milked, is purified by hidroxide scavenging and counted for the combined 89Sr and 90Sr activity; (4) 89Sr activity is determined by substracting the 90Sr activity from the combined activity. The method has been applied by the authors to analyse an unknown solution of 89Sr and 90Sr at approximately environmental levels of activity obtaining the following results: (154+-19) dpm 90Sr and (1210+-260) dpm 89Sr per gram of original solution

  5. Rb-Sr and Sm-Nd Isotope Systematics of Shergottite NWA 856: Crystallization Age and Implications for Alteration of Hot Desert SNC Meteorites

    Brandon, A. D.; Nyquist, L. E.; Shih, C.-Y.; Wiesmann, H.

    2004-01-01

    Nakhlite NWA 998 was discovered in Algeria in 2001, and is unique among the six known members of this group of Martian meteorites in containing significant modal orthopyroxene. Initial petrologic and isotopic data were reported by Irving et al. This 456 gram stone consists mainly of sub-calcic augite with subordinate olivine and minor orthopyroxene, titanomagnetite, pyrrhotite, chlorapatite, and intercumulus An(sub 35) plagioclase. We report here preliminary results of radiogenic isotopic analyses conducted on fragmental material from the main mass.

  6. Evaluation of the effects of microscale chemical and isotopic heterogeneity of coral skeleton on conventional Sr/Ca and O paleothermometers

    Mitsuguchi, Takehiro

    2013-10-01

    Recent studies using secondary ion mass spectrometry revealed microscale heterogeneity of Sr/Ca and O in shallow-water coral skeletons, i.e., Sr/Ca and O differ significantly between two basic microfeatures of the skeleton: the center of calcification (COC) and surrounding fibrous skeleton (SFS). The COC, in contrast with the SFS, consists of highly irregular crystals intermingled with significant amount of organic matter; therefore, analyzing the SFS only would probably be favourable for paleotemperature reconstruction. Conventional Sr/Ca and O paleothermometers are, however, based on the analysis of the mixture of the COC and SFS, and thus may be significantly affected by the above-mentioned heterogeneity. In this study, I have evaluated the heterogeneity-induced effects on the conventional paleothermometers of Porites skeletons using published Sr/Ca, O and volume-fraction data of the COC and SFS and published observations of seasonal variability of bulk skeletal density. Results indicate that the effects may yield significant or serious errors in paleotemperature reconstruction.

  7. Evaluation of the effects of microscale chemical and isotopic heterogeneity of coral skeleton on conventional Sr/Ca and 18O paleothermometers

    Takehiro Mitsuguchi

    2013-10-01

    Recent studies using secondary ion mass spectrometry revealed microscale heterogeneity of Sr/Ca and 18O in shallow-water coral skeletons, i.e., Sr/Ca and 18O differ significantly between two basic microfeatures of the skeleton: the center of calcification (COC) and surrounding fibrous skeleton (SFS). The COC, in contrast with the SFS, consists of highly irregular crystals intermingled with significant amount of organic matter; therefore, analyzing the SFS only would probably be favourable for paleotemperature reconstruction. Conventional Sr/Ca and 18O paleothermometers are, however, based on the analysis of the mixture of the COC and SFS, and thus may be significantly affected by the above-mentioned heterogeneity. In this study, I have evaluated the heterogeneity-induced effects on the conventional paleothermometers of Porites skeletons using published Sr/Ca, 18O and volume-fraction data of the COC and SFS and published observations of seasonal variability of bulk skeletal density. Results indicate that the effects may yield significant or serious errors in paleotemperature reconstruction.

  8. Sulfide mineralization associated with arc magmatism in the Qilian Block, western China: zircon U-Pb age and Sr-Nd-Os-S isotope constraints from the Yulonggou and Yaqu gabbroic intrusions

    Zhang, Zhao-Wei; Li, Wen-Yuan; Gao, Yong-Bao; Li, Chusi; Ripley, Edward M.; Kamo, Sandra

    2014-02-01

    The sulfide-bearing Yulonggou and Yaqu mafic intrusions are located in the southern margin of the Qilian Block, Qinghai Province, western China. They are small dike-like bodies mainly composed of gabbros and diorites. Disseminated sulfides (pyrrhotite, pentlandite, and chalcopyrite) are present as concordant lenses within the intrusions. Precise CA-ID-TIMS zircon U-Pb dating yields the crystallization ages of 443.39 ± 0.42 and 440.74 ± 0.33 Ma for the Yulonggou and Yaqu intrusions, respectively. Whole rock samples from both intrusions show light rare earth element (REE) enrichments relative to heavy REE and pronounced negative Nb-Ta anomalies relative to Th and La, which are consistent with the products of arc basaltic magmatism. The Yulonggou intrusion has negative ɛ Nd values from -5.7 to -7.7 and elevated (87Sr/86Sr) i ratios from 0.711 to 0.714. In contrast, the Yaqu intrusion has higher ɛ Nd values from -4.1 to +8.4 and lower (87Sr/86Sr) i ratios from 0.705 to 0.710. The δ34S values of sulfide separates from the Yulonggou and Yaqu deposits vary from 0.8 to 2.4 ‰ and from 2 to 4.3 ‰, respectively. The γ Os values of sulfide separates from the Yulonggou and Yaqu deposits vary between 80 and 123 and between 963 and 1,191, respectively. Higher γ Os values coupled with higher δ34S values for the Yaqu deposit relative to the Yulonggou deposit indicate that external sulfur played a bigger role in sulfide mineralization in the Yaqu intrusion than in the Yulonggou intrusion. Mixing calculations using Sr-Nd isotope data show that contamination with siliceous crustal materials is more pronounced in the Yulonggou intrusion (up to 20 wt%) than in the Yaqu intrusion (market condition due to small sizes and low Ni grades, which can be explained by late-stage sulfide saturation after extensive olivine fractional crystallization from the magmas. Based on these observations, we suggest a shift of focus for Ni exploration in the region from mafic/gabbroic intrusions

  9. Abrupt Change Analyses of Oxygen, Carbon Isotope Values and Sr Contents in a Stalagmite Retrieved from Songjia Cave, NE Sichuan%大滁城人居环境适宜性研究

    李军利; 徐松南; 李建梅; 潘静

    2012-01-01

    以1km×1km栅格为基本单元,选取交通路网指数、水域指数、学校指数、居住影响力指数与地被指数等影响因子,运用GIS技术建立大滁城人居环境指数模型,定量研究大滁城规划区人居环境的适宜程度及其空间规律性。结果表明:大滁城人居环境指数呈现由中心区域向周边地区递减的趋势;人居环境指数与人口密度有较好的相关性,二者的一次拟合度R2=0.8361。一般适宜以上的地区132km2,接近大滁城面积的2.96%,相应的人口占大滁城8.75%,其中3.3%的人口聚集在0.78%人居环境高度适宜和比较适宜地区;临界适宜地区698km2,占大滁城面积的15.69%,人口39.33万;适宜性相对较差的地区3619km2,人口108.91万,占大滁城总面积的81.35%。%We analyze the abrupt changes of oxygen, carbon isotope values and Sr contents in stalagmite S J3 retrieved from Song:jia Cave, Central China. Some conclusions are given below : ( 1 ) Oxygen isotope values record the transition from Last Glacial Maximum to Heinrich Event One period;(2) Carbon isotope values record the transition from H1 cold period to BoilingAllerod warm period ; ( 3 ) The correlation between Carbon isotope values and Sr contents indicate that the local East Asian summer monsoon were in - phase with the winter monsoon during 19.8 - 15.3ka while out of phase during 15.3 - 14.8ka. It' s obvious that stalagmite S J3 records the palaeoclimate changes between colddry and warm wet conditions while different climate proxies were dissimilar in sensitivities with regard to climate changes.

  10. Determination on 87Sr/86Sr ratio and stratigraphic dating of single-grain foraminifera

    TONG Jinggui; LI Shengrong; LI Xianghui; LI Qiuli; FANG Nianqiao; CHU Fengyou; CHEN Fukun

    2006-01-01

    The Sr isotopic composition of foraminifera has been used in studies of chronstratigraphy and sedimentary geochemistry. However, it is difficult to sample foraminifera without overprinting of later diagenesis, which contains enough amount of Sr for isotopic measurement. Analysis of single-grain foraminifera was successively conducted by a combination of low Sr procedural blank and high precision determination of 87Sr/86Sr ratio. This combination of single-grain foraminifera can be significant for the study and application of Sr isotopic composition of foraminifera. Measured foraminifera of this study, having a size between 250 um and 400 um, were sampled from the carbonate basement of a ferromanganese crust in western Pacific. Mean value of 87Sr/86Sr ratios of the analyzed single-grain foraminifera is 0.709150 ±0.000013 with internal precision between 4 ppm and 8 ppm for each measurement run. Average value of total procedural blank of Sr is 14 pg. It is significant but difficult to date foraminifera in carbonate basements of ferromanganese crusts. Based on the obtained value of 87Sr/86Sr ratio, the analyzed foraminifera can be dated at 0.91 +0.33/-0.39 Ma.

  11. Contrasted crustal sources as defined by whole-rock and Sr-Nd-Pb isotope geochemistry of neoproterozoic early post-collisional granitic magmatism within the Southern Brazilian Shear Belt, Camboriú, Brazil

    Florisbal, Luana Moreira; de Assis Janasi, Valdecir; de Fátima Bitencourt, Maria; Stoll Nardi, Lauro Valentim; Heaman, Larry M.

    2012-11-01

    The early phase of post-collisional granitic magmatism in the Camboriú region, south Brazil, is represented by the porphyritic biotite ± hornblende Rio Pequeno Granite (RPG; 630-620 Ma) and the younger (˜610 Ma), equigranular, biotite ± muscovite Serra dos Macacos Granite (SMG). The two granite types share some geochemical characteristics, but the more felsic SMG constitutes a distinctive group not related to RPG by simple fractionation processes, as indicated by its lower FeOt, TiO2, K2O/Na2O and higher Zr Al2O3, Na2O, Ba and Sr when compared to RPG of similar SiO2 range. Sr-Nd-Pb isotopes require different sources. The SMG derives from old crustal sources, possibly related to the Paleoproterozoic protoliths of the Camboriú Complex, as indicated by strongly negative ɛNdt (-23 to -24) and unradiogenic Pb (e.g., 206Pb/204Pb = 16.0-16.3; 207Pb/204Pb = 15.3-15.4) and confirmed by previous LA-MC-ICPMS data showing dominant zircon inheritance of Archean to Paleoproterozoic age. In contrast, the RPG shows less negative ɛNdt (-12 to -15) and a distinctive zircon inheritance pattern with no traces of post-1.6 Ga sources. This is indicative of younger sources whose significance in the regional context is still unclear; some contribution of mantle-derived magmas is indicated by coeval mafic dykes and may account for some of the geochemical and isotopic characteristics of the least differentiated varieties of the RPG. The transcurrent tectonics seems to have played an essential role in the generation of mantle-derived magmas despite their emplacement within a low-strain zone. It may have facilitated their interaction with crustal melts which seem to be to a large extent the products of reworking of Paleoproterozoic orthogneisses from the Camboriú Complex.

  12. Origin of the granites and related Sn and Pb-Zn polymetallic ore deposits in the Pengshan district, Jiangxi Province, South China: constraints from geochronology, geochemistry, mineral chemistry, and Sr-Nd-Hf-Pb-S isotopes

    Xu, Bin; Jiang, Shao-Yong; Luo, Lan; Zhao, Kui-Dong; Ma, Liang

    2016-05-01

    The Pengshan Sn and Pb-Zn polymetallic deposits are located in the south margin of the Jiujiang-Ruichang (Jiurui) district of the Middle-Lower Yangtze River Metallogenic Belt in South China. Four large deposits include Huangjinwa, Zengjialong, Jianfengpo, and Zhangshiba, the former three are Sn-dominant deposits which occur as stratiform orebodies in the contact zones of the Pengshan granites and within the country rock strata, whereas Zhangshiba consists of stratiform Pb-Zn orebodies within the Precambrian metasedimentary strata. In this study, we present results on zircon U-Pb ages, major and trace elements, and mineral chemistry as well as Sr-Nd-Hf isotope data of the granites, Pb and S isotopes of both the Sn-dominant and Pb-Zn dominant deposits, and U-Pb dating of cassiterite from the Pengshan district. SHRIMP and LA-ICP-MS zircon U-Pb dating shows that the Pengshan granites were emplaced in the Early Cretaceous (129-128 Ma), which is in good agreement with the U-Pb dating (130-128 Ma) of cassiterite from the Jianfengpo Sn deposit. The Pengshan granites consist mainly of weakly peraluminous highly fractionated I-type affinity granitic rocks. Detailed elemental and isotopic data suggest that the granites formed by partial melting of Mesoproterozoic metamorphic basement materials with minor input of mantle-derived melts. The mineral chemistry of biotite demonstrates that the Pengshan granitic magma had a low oxygen fugacity, thereby precluding the tin dominantly partitioning into the rock-forming silicate minerals and favoring accumulation in the exsolved residual liquid during magma crystallization stages. Sulfur isotopes show a relatively heavy sulfur isotopic composition from 5.8 to 17.6 ‰, and no difference for sulfur isotopes between the Sn deposits (5.8-13.4 ‰, Huangjinwa, Zengjialong, Jianfengpo) and the Pb-Zn deposit (mostly 7.1-13.0 ‰, except for one 17.6 ‰, Zhangshiba). The sulfur isotope data of pyrite from the host sedimentary rocks show

  13. 87Sr/86Sr-ratios and Sr-contents of deep ground waters, minerals and rocks from the crystalline and the Trias of Northern Switzerland

    In order to determine the origin of groundwaters and their interaction with the host rock, the amount and ratio of strontium isotopes in groundwaters, vein minerals, authigenic cements and whole rocks were measured in the crystalline basement and Triassic sediments of northern Switzerland. The groundwaters in the fractured basement aquifer generally show Sr-isotope ratios that range between 0.716 and 0.718. These ratios in the groundwaters are mainly determined by reaction with Sr-rich minerals that were formed during a Permian hydrothermal event. With minor exceptions, the Sr-isotope ratios of most vein minerals are not in equilibrium with those of the present groundwaters. The waters of the Buntsandstein aquifer are characterized by slightly lower Sr-isotope ratios and a higher Sr-content than in the corresponding basement aquifer waters. Buntsandstein waters are considered to have evolved from the waters of the basement aquifer through dissolution of calcite and sulphate present in the Buntsandstein. Although the Sr-isotope ratios in Buntsandstein vein minerals and waters are similar the relative amount of Sr (assuming equilibrium partitioning) suggests these vein minerals did not precipitate from the present waters. The much lower Sr-isotope ratio characteristic of waters in the Muschelkalk aquifer (0.708 to 0.709) readily distinguishes these from the Buntsandstein and basement waters. The low Sr-isotope ratios in the Muschelkalk waters are, however, higher than those measured from marine sulphates in the Muschelkalk, and may result from dissolution of dolomite and continental sulphates. Measured variations in the Sr-isotope ratios of successive authigenic minerals indicate that the Sr-isotope composition in the groundwaters fluctuated through geological time. (author) 32 refs., 4 figs., 1 tab

  14. Overview of the geochemistry and Rb/Sr, Sm/Nd isotopes of Middle Jurassic and Tertiary granitoid intrusions: a new insight on tectono-magmatism and mineralization of this period in Iran

    Mohammad Ali Jazi

    2012-10-01

    Full Text Available One of the most intensive occurrences of magmatism in Iran was in the middle Jurassic period. Among the granitoid intrusions in this period as discrete bodies or complexes can be pointed to Aligoodarz, Alvand, Astaneh, Boroujerd, Malayer, and Chah-Dozdan in the Sanandaj-Sirjan zone; Shir-kuh and Ayrakan in the Central Iran zone; Shah-kuh, Sorkh-kuh and Kalateh-Ahani in the Lut Block. These granitoids are mostly peraluminous and belong to high-K calc-alkaline series. CaO/Na2O ratios (0.12 to 8.37 mostly suggest a clay-free source for formation of the intrusive rocks magma. Chondrite-normalized Rare Earth Elements (REEs diagram do not display high enrichment of Light Rare Earth Elements (LREEs than Heavy Rare Earth Elements (HREEs and general pattern is relatively flat. In addition, diagram shows Eu negative anomaly, which can be attributed to indicate reducing conditions in formation of magma and/or magma derived from plagioclase depth as source. The lower continental crust-normalized spider diagram indicates enrichment in LILE (Rb, Cs, and K and LREE (La and Ce and depletion in Ba, Nb, Ta, Sr, and Ti. Initial 87Sr/86Sr ratios are 0.70609 to 0.71938 and initial εNd values are negative (from -6.51 to -1.1 indicating that magma derived from continental crust. Geochemical and isotopic evidence of the intrusive rocks shows continental crust origin (S-type granitoid and due to continental collision. Geological findings such as stop in sedimentation, regional metamorphism, ophiolite displacement, and continental collision-related mineralization confirm continental collision between Iranian and Arabian plates in the Middle Jurassic period.

  15. Isotopic characteristics (Nd and Sr) of the intrusive plutonism at the northwestern Amazonian Craton, Venezuela, and implications for the Paleoproterozoic evolution; Caracteristicas isotopicas (Nd e Sr) do plutonismo intrusivo no extremo NW do Craton Amazonico, Venezuela, e implicacoes para a evolucao paleoproterozoica

    Teixeira, Wilson; Tassinari, Colombro Celso G. [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias. Dept. de Mineralogia e Geotectonica; Mondin, M. [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias. Programa de Pos-graduacao em Recursos Minerais e Hidrogeologia

    2002-12-15

    Nd and Sr analyses were performed on selected granitoid plutons that intrude Archean and Paleoproterozoic domains of the Guyana shield (Venezuela). The isotopic signatures of these plutons together with the geochronologic background of the country rocks are used to constrain their magma genesis and tectonic setting within the Paleoproterozoic evolutions of mobile belts (Maroni-Itacaiunas and Ventuari-Tapajos provinces) of the Amazonian Craton. The Encrucijada Suite (2187 +- 94 Ma), which intrudes Archean rocks of the Imataca Complex, originated predominantly from partial melt of this crust, as supported by negative epsilon{sub Nd(2.1Ga)} values (-2.2 to - 4.9) and T{sub DM} ages between 2.82 and 2.49 Ga. Conversely, the plutons from the Supamo Complex (2230 - 2050 Ma) and Cuchivero Group (1980 - 1830 Ma), occurring within the adjoining Paleoproterozoic provinces, are juvenile in nature (derived from roughly contemporary protoliths). These bodies display T{sub DM} ages between 2.13 and 2.22 Ga, as well as positive epsilon{sub Nd(2.1Ga)} values (+0.74 to + 3.05). Isotopic correlation diagrams (143 Nd/144 Nd vs. 147 Sm/144 Nd and 143 Nd/144 Nd vs. time) plotted together with the plutonic rocks and Imataca Complex rocks were evaluated taking into account the geologic background of the NW part of the Amazonian Craton. Interpretation of these isotopic data supports the idea of tectonic juxtaposition between the Imataca Complex and the Maroni-Itacaiunas province during the Transamazonian orogeny (2.25 - 2.05 Ga). On the other hand, the Cuchivero Group plutons have a contrasting isotopic signature compared to the other Paleoproterozoic plutonic rocks. This is consistent with the existence of a tectonic boundary between the Maroni-Itacaiunas and the Ventuari-Tapajos province in the late Paleoproterozoic. (author)

  16. New sequential separation procedure for Sr, Nd and Pb isotope ratio measurement in geological material using MC-ICP-MS and TIMS

    Makishima, A.; Nath, B.N.; Nakamura, E.

    of interference from HClO 4 , therefore, Sr–Nd and Pb chemistry are carried out separately. As details for mass spectrometry and analytical performances using the Pb separated in the chemistry developed in this study are al- ready demonstrated elsewhere (Makishima... et al., 2007), this paper describes Sr and Nd separation, mass spectrometry (MC-ICP-MS and TIMS) and analytical performances. EXPERIMENTAL Reagents and silicate reference materials Water, HF and HCl were purified as described else- where (Nakamura et...

  17. Sr and Nd isotopic signature of the high-K calc-alkaline magmatism of the central Ribeira belt: the Sao Pedro Granite in Lumiar, RJ

    In the central-northern Ribeira belt there are many granitic to granodioritic bodies showing varied shape and size, characterizing a late- to post-collisional Ca-alkaline, cordilleran I-type province. The Sao Pedro Granite occurs in the mountain region of Rio de Janeiro State as small post-collisional bodies. It presents isotropic fabric, equigranular to seriate inequigranular texture, as well as local concentration of allanite, which gives discrete composition and texture variation to the rock. The granite has a high-K calcalkaline to alkali-calcic character and weakly peraluminous nature. Despite its short geochemical variation, high Ba, Zr and Th contents besides low concentrations of MgO and CaO are noticeable. High REE contents are associated with fractionated REE patterns showing strong negative Eu anomalies. A crustal origin for the granite can be assumed by its very negative and positive .Nd and .Sr values, respectively, as well as by 87Sr/86Sr initial ratios ranging from 0,718 to 0,740. TDM ages point to paleoproterozoic source, which agrees with geological time of intensive crust generation. (author)

  18. Petrology, 40Ar/39Ar age, Sr-Nd isotope systematics, and geodynamic significance of an ultrapotassic (lamproitic) dyke with affinities to kamafugite from the easternmost margin of the Bastar Craton, India

    Rao, N. V. Chalapathi; Atiullah; Burgess, R.; Nanda, Purnendu; Choudhary, A. K.; Sahoo, Samarendra; Lehmann, B.; Chahong, Ngazipmi

    2016-04-01

    We report the mineralogy, bulk-rock geochemistry, 40Ar/39Ar (whole-rock) age and radiogenic (Sr and Nd) isotope composition of an ultrapotassic dyke from Sakri (Nuapada lamproite field) located at the tectonic contact between the easternmost margin of the Bastar craton and Eastern Ghats Mobile Belt, India. The Sakri dyke has a mineralogy which strongly resembles a lamproite sensu stricto (viz.,Ti-rich phlogopite, Na-poor diopside, Fe-rich sanidine, ulvospinel trend and Sr-rich apatite). However, its bulk-rock major element geochemical characteristics (viz., extreme silica-undersaturated nature) resemble sensu lato kamafugite from Toro Ankole, Uganda, East African Rift, and Alto Paranaiba Province, Brazil. The Sakri dyke also displays certain compositional peculiarities (viz., high degree of evolution of mica composition from phlogopite to biotite, elevated titanium and aluminum in clinopyroxene and significantly lower bulk Mg#) when compared to the ultrapotassic rocks from various Indian cratons. 40Ar/39Ar dating gave a plateau age of 1045 ± 9 Ma which is broadly similar to that of other Mesoproterozoic (i) lamproites from the Bastar and Bundelkhand cratons, and (ii) kimberlites from the Eastern Dharwar craton. Initial bulk-rock Sr (0.705865-0.709024) and Nd (0.511063-0.511154) isotopic ratios reveal involvement of an `enriched' source region with long-term incompatible element enrichment and a depleted mantle (TDM) Nd model age of 2.56 Ga straddling the Archaean-Proterozoic chronostratigraphic boundary. The bulk-rock incompatible trace element ratios (Ta/Yb, Th/Yb, Rb/Ba and Ce/Y) of the Sakri ultrapotassic dyke negate any significant influence of crustal contamination. Small-degree melting (1 to 1.5 %) of a mixed garnet-facies and spinel-facies phlogopite lherzolite can account for its observed REE concentrations. Whereas the emplacement of the Sakri ultrapotassic dyke is related to the amalgamation of the supercontinent of Rodinia, its overlapping geochemical

  19. The Rb-Sr system

    This manual is intended to serve as a guide to the chemical procedures involved in Rb-Sr isotopic analysis as conducted at the Institute of Nuclear Sciences. Included are notes on the experimental developments made over the last 2.5 years, especially those involving rock dissolution and cation exchange chromatography

  20. Kinetic isotope effect of the {sup 16}O + {sup 36}O{sub 2} and {sup 18}O + {sup 32}O{sub 2} isotope exchange reactions: Dominant role of reactive resonances revealed by an accurate time-dependent quantum wavepacket study

    Sun, Zhigang, E-mail: zsun@dicp.ac.cn; Yu, Dequan; Xie, Wenbo; Hou, Jiayi [State Key Laboratory of Molecular Reaction Dynamics and Center for Theoretical and Computational Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China and Center for Advanced Chemical Physics and 2011 Frontier Center for Quantum Science and Technology, University of Science and Technology of China, 96 Jinzhai Road, Hefei 230026 (China); Dawes, Richard [Department of Chemistry, Missouri University of Science and Technology, Rolla, Missouri 65409 (United States); Guo, Hua [Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87131 (United States)

    2015-05-07

    The O + O{sub 2} isotope exchange reactions play an important role in determining the oxygen isotopic composition of a number of trace gases in the atmosphere, and their temperature dependence and kinetic isotope effects (KIEs) provide important constraints on our understanding of the origin and mechanism of these and other unusual oxygen KIEs important in the atmosphere. This work reports a quantum dynamics study of the title reactions on the newly constructed Dawes-Lolur-Li-Jiang-Guo (DLLJG) potential energy surface (PES). The thermal reaction rate coefficients of both the {sup 18}O + {sup 32}O{sub 2} and {sup 16}O + {sup 36}O{sub 2} reactions obtained using the DLLJG PES exhibit a clear negative temperature dependence, in sharp contrast with the positive temperature dependence obtained using the earlier modified Siebert-Schinke-Bittererova (mSSB) PES. In addition, the calculated KIE shows an improved agreement with the experiment. These results strongly support the absence of the “reef” structure in the entrance/exit channels of the DLLJG PES, which is present in the mSSB PES. The quantum dynamics results on both PESs attribute the marked KIE to strong near-threshold reactive resonances, presumably stemming from the mass differences and/or zero point energy difference between the diatomic reactant and product. The accurate characterization of the reactivity for these near-thermoneutral reactions immediately above the reaction threshold is important for correct characterization of the thermal reaction rate coefficients.

  1. Archean evolution of Enderby Land (Antarctica) and isotope-geochronological evidences for its ancient history

    Revew of published isotope-geochronological data on Ender by Land (Antarctica), which is the region of highly metamorphic formations predominant development which includes ancient rock relicts, is presented. Three tectonic-thermal events present the Archeau evolution in the region. Correlation of isotope-geochronological (U-Pb, Rb-Sr, Sm-Nd) data with micro textural processing allows to estimate tectonic-thermal events age: 3000-3100 about 2900 and about 2500 million years. Metamorphism of 3000-3100 million years age has essentially modified all the isotope systems, while model calculations for evolution of U-Pb, Rb-Sr, Sm-Nd systems have shown that rocks primary formation accurred 3500-3900 million years ago

  2. Zircon U-Pb age and Sr-Nd-Hf isotope geochemistry of the Ganluogou dioritic complex in the northern Triassic Yidun arc belt, Eastern Tibetan Plateau: Implications for the closure of the Garzê-Litang Ocean

    Wu, Tao; Xiao, Long; Wilde, Simon A.; Ma, Chang-Qian; Li, Zi-Long; Sun, Yi; Zhan, Qiong-Yao

    2016-04-01

    The Triassic Yidun arc belt (YAB) lies between the Jinshajiang suture zone to the west and the Garzê-Litang suture zone to the east, Eastern Tibetan Plateau. To study the YAB can not only help us to better understand the evolutionary history of the Garzê-Litang Ocean but can also provide some important information to constrain the evolution of the eastern Paleo-Tethys. In this paper, the geochronological and geochemical data of the Ganluogou dioritic complex were systematically investigated in order to decipher the geodynamic setting of the complex and to further determine the final closure time of the Garzê-Litang Ocean. The Ganluogou dioritic complex is located in the northern part of the YAB. It consists of ferrodiorite, diorite and a mixing zone between them and is the largest intermediate-mafic pluton in the YAB. The ferrodiorites were emplaced at 213 ± 2 Ma have low SiO2 and high Fe2O3* contents, whereas the diorites formed at 209 ± 2 Ma and have relatively higher SiO2, Na2O + K2O, Th, U, Zr, and Hf contents, but lower Al2O3, MgO, CaO, Co, and Sr contents than the ferrodiorites. Relative to the primitive mantle both the ferrodiorites and diorites are depleted in Nb and Ta. However, the ferrodiorites exhibit strong depletion in Zr and Hf, whereas the diorites contain relatively higher Th and U contents without negative Zr and Hf anomalies. Both rock-types have similar chondrite-normalized rare earth element patterns with (La/Yb)N ratios = 4.4 to 18.2, and show weak Eu anomalies, with Eu/Eu* of 0.47 to 1. They both show narrow ranges in Sr-Nd-Hf isotopic compositions. However, the ferrodiorites contain lower initial 87Sr/86Sr ratios (0.7052-0.7057) and relatively higher εNd(t) values (- 3.8 to - 2.4) than the diorites, which record values of 0.7062-0.7066 and - 5.5 to - 5.7, respectively. For the zircon Hf isotopic composition, the ferrodiorites also exhibit higher 176Hf/177Hf ratios (0.282738-0.282804) and more depleted εHf(t) values (3.4-5.6) than

  3. Geochemical and Nd-Sr-Pb-O isotopic constrains on Permo-Triassic magmatism in eastern Qaidam Basin, northern Qinghai-Tibetan plateau: Implications for the evolution of the Paleo-Tethys

    Chen, Xuanhua; Gehrels, George; Yin, An; Zhou, Qi; Huang, Penghui

    2015-12-01

    Eastern Qaidam Basin of the northern Qinghai-Tibetan plateau is located in a transitional zone between the Permo-Triassic Paleo-Tethyan orogenic belt in the south and the early Paleozoic Qilian orogenic belt in the north. Here we present geochemical and Sr-Nd-Pb-O isotopic data for the Permo-Triassic plutons in eastern Qaidam Basin. Bulk-rock geochemical data and regional geological studies indicate that these plutons consist mainly of subduction-related high-K calc-alkaline metaluminous, I-type granitoids, which occurred during the northward subduction of the Paleo-Tethyan oceanic lithosphere below the southern continental margin of the Kunlun-Qaidam terrane. The εNd(t) values of these Permo-Triassic granitoids are between -9.4 and -3.0, and εSr(t) values are from -20.33 to +168.20. Nd isotopic compositions indicate that the granitoids can come from a pre-existed materials formerly originated from an enriched mantle (EM II) source. The TDM2 model ages of 1.28-1.78 Ga implies that the arc-induced Triassic granitoids were derived melts of Meso-Proterozoic basement rocks of the Kunlun-Qaidam terrane that is bounded by the early Paleozoic Qilian suture zone to the north and the Triassic Kunlun suture zone in the south. The Permo-Triassic granitoids yield initial ratios of 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values from 18.295 to 19.096, 15.617 to 15.692, and 37.960 to 38.531, respectively. The Pb isotope composition of the granitoids is very similar to that of the Mesozoic granitoids from the western segment of the east of the study area. Geochemical analyses of the plutons, integrated with previous LA ICP-MS U-Pb zircon dating, reveal two series of Permo-Triassic arc magmatisms in eastern Qaidam Basin. Both the series of magmatism display reversed trends with the classic Bowen's reaction series. The new geochemical evidence suggest that the arc magmatism in eastern Qaidam Basin was induced by fluid-fluxing melting of an enriched lithospheric mantle and rock

  4. Melt evolution beneath a rifted craton edge: 40Ar/39Ar geochronology and Sr-Nd-Hf-Pb isotope systematics of primitive alkaline basalts and lamprophyres from the SW Baltic Shield

    Tappe, Sebastian; Smart, Katie A.; Stracke, Andreas; Romer, Rolf L.; Prelević, Dejan; van den Bogaard, Paul

    2016-01-01

    A new high-precision 40Ar/39Ar anorthoclase feldspar age of 176.7 ± 0.5 Ma (2-sigma) reveals that small-volume alkaline basaltic magmatism occurred at the rifted SW margin of the Baltic Shield in Scania (southern Sweden), at a time of global plate reorganization associated with the inception of Pangea supercontinent break-up. Our combined elemental and Sr-Nd-Hf-Pb isotope dataset for representative basanite and nephelinite samples (>8 wt.% MgO) from 16 subvolcanic necks of the 30 by 40 km large Jurassic volcanic field suggests magma derivation from a moderately depleted mantle source (87Sr/86Sri = 0.7034-0.7048; εNdi = +4.4 to +5.2; εHfi = +4.7 to +8.1; 206Pb/204Pbi = 18.8-19.5). The mafic alkaline melts segregated from mixed peridotite-pyroxenite mantle with a potential temperature of ∼1400 °C at 2.7-4.2 GPa (∼90-120 km depths), which places ultimate melt generation within the convecting upper mantle, provided that the lithosphere-asthenosphere boundary beneath the southern Baltic Shield margin was at ⩽100 km depth during Mesozoic-Cenozoic rifting. Isotopic shifts and incompatible element enrichment relative to Depleted Mantle reflect involvement of at least 20% recycled oceanic lithosphere component (i.e., pyroxenite) with some minor continent-derived sediment during partial melting of well-stirred convecting upper mantle peridotite. Although pargasitic amphibole-rich metasomatized lithospheric mantle is excluded as the main source of the Jurassic magmas from Scania, hydrous ultramafic veins (i.e., hornblendite) may have caused subtle modifications to the compositions of passing sublithospheric melts. For example, modeling suggests that the more radiogenic Hf (εHfi = +6.3 to +8.1) and Pb (206Pb/204Pbi = 18.9-19.5) isotopic compositions of the more sodic and H2O-rich nephelinites, compared with relatively homogenous basanites (εHfi = +4.7 to +6.1; 206Pb/204Pbi = 18.8-18.9), originate from minor interactions between rising asthenospheric melts and

  5. Distribution of Natural Radioactivity, 137Cs, 90Sr, and Plutonium Isotopes in a Water Column and Sediment Core along the Algerian Coast

    R. Boudjenoun

    2008-02-01

    Full Text Available Concentrations of natural (40K, 210Pb, uranium, and thorium series and artificial radioelements (137Cs, 90Sr, 239+240Pu were determined in seawater and sediment samples collected from stations along the Algerian coast. Seawater was collected from the surface to a maximum depth of 2000 m; the sediment cores were sampled from a depth of around 1500 m. This work was carried out in August 2001, in the framework of the Regional African project /7/004 (RAF, by the accomplishment of an oceanographic campaign organized by the International Atomic Energy Agency (IAEA in collaboration with Commissariat à l'Energie Atomique (COMENA and L'Institut des Sciences de la Mer et de L'Amenagement du Littoral (ISMAL, on board of the research vessel of M.S. Benyahia of ISMAL. In addition to the record of the conductivity (mS and temperature (°C data at each station, seawater samples were treated and preconcentrated on board, those of sediment cores were divided into different layers in order to undergo analyses in the laboratory of radiological impact studies of Algiers. Concentration results were obtained for 137Cs and 90Sr in mBq/L and 239+240Pu in μBq/L in seawater, and also for natural and artificial radionuclides in Bq/kg dry weight in the layers of the sediment cores. The different profiles of 137Cs, 239+240Pu, 90Sr, and 210Pb concentrations against depth were presented to show artificial radioactivity distribution in the water column and sediment core. Concentrations of 137Cs in the sediment core were also used to identify the 137Cs peak in the area of interest.

  6. Distribution of Natural Radioactivity, 137Cs, 90Sr, and Plutonium Isotopes in a Water Column and Sediment Core along the Algerian Coast

    Noureddine, A; M. BENKRID; R. Maoui; Menacer, M.; R. BOUDJENOUN

    2007-01-01

    Concentrations of natural (40K, 210Pb, uranium, and thorium series) and artificial radioelements (137Cs, 90Sr, 239+240Pu) were determined in seawater and sediment samples collected from stations along the Algerian coast. Seawater was collected from the surface to a maximum depth of 2000 m; the sediment cores were sampled from a depth of around 1500 m. This work was carried out in August 2001, in the framework of the Regional African project /7/004 (RAF), by the accomplishment of an oceanogra...

  7. Some problems and main prospects of developing parametric series of unified radio-isotope thermoelectric generators on the 90Sr base

    Consideration is being given to studies on unification of radioisotope thermoelectric generators (RITG) on the 90Sr base, aimed at reducing types of products, creation of unified element base, development of modern base RITG designs. Various ways of creating unified RITG models were discussed. The conducted investigations showed that development of RITG designs of required rated values of electric power was the most effective one for 5-80-100 W power range. As for powers of above 100 W the required power can be provided by a set of several products of lower power

  8. A physical-chemical modeling of strontium isotopes behavior in Chernobyl Exclusion zone fresh water

    Radiogeochemical models for dissolution and sedimentation of isotopic forms of strontium compounds in the exclusion zone's freshwater environments were created and verified. It was established that isotope effects shall be observed both during dissolution and deposition of strontium isotopic forms. For both models, solid phase (with respect to the solution) is depleted by light isotopes of strontium (84SR, 86Sr and 87Sr) and enriched by 90Sr. Isotopic composition of strontium in the solution is governed by isotopic composition of ion mSr2+

  9. Chemical, multi-isotopic (Li-B-Sr-U-H-O) and thermal characterization of Triassic formation waters from the Paris Basin

    Millot, Romain; Guerrot, Catherine; Innocent, Christophe; Négrel, Philippe; Sanjuan, Bernard

    2011-01-01

    International audience This work reports chemical and isotope data and temperature estimates for seven water samples collected from Triassic formations in the Paris Basin in France. Four samples were collected in the central part of the Basin (saline waters) and three were collected at the edge of the Basin near the recharge zone (dilute waters). The saline waters collected from the Chaunoy and Champotran boreholes have high salinities (around 120 g/L) and very similar chemical and isotopi...

  10. The Aguablanca Cu–Ni ore deposit (Extremadura, Spain), a case of synorogenic orthomagmatic mineralization: age and isotope composition of magmas (Sr, Nd) and ore (S)

    Casquet, César; Galindo Francisco, Mª del Carmen; Tornos Arroyo, Fernando; Velasco Roldán, Francisco; Canales Gallarosa, Ángel

    2001-01-01

    The Aguablanca Cu–Ni orthomagmatic ore deposit is hosted by mafic and ultramafic rocks of the Aguablanca stock, which is part of the larger, high-K calc-alkaline Santa Olalla plutonic complex. This intrusive complex, ca. 338 Ma in age, is located in the Ossa-Morena Zone (OMZ) of the Iberian Variscan Belt. Mineralization consists mainly of pyrrhotite, pentlandite and chalcopyrite resulting from the crystallization of an immiscible sulphide-rich liquid. Isotope work on the host igne...

  11. Geochemical and Pb, Sr, and O isotopic study of the Tiva Canyon Tuff and Topopah Spring Tuff, Yucca Mountain, Nye County, Nevada

    Yucca Mountain is currently being studied as a potential site for an underground repository for high-level radioactive waste. One aspect of the site characterization studies is an evaluation o the resource potential at Yucca Mountain. Geochemical and isotopic signatures of past alteration of the welded tuffs that underlie Yucca Mountain provide a means of assessing the probability of hydrothermal ore deposits being present within Yucca Mountain. In this preliminary report, geochemical and isotopic measurements of altered Tiva Canyon Tuff and Topopah Spring Tuff collected from fault zones exposed on the east flank of Yucca Mountain and from one drill core are compared to their unaltered equivalents sampled both in outcrop and drill core. The geochemistry and isotopic compositions of unaltered Tiva Canyon Tuff and Topopah Spring Tuff (high-silica rhyolite portions) are fairly uniform; these data provide a good baseline for comparisons with the altered samples. Geochemical analyses indicate that the brecciated tuffs are characterized by addition of calcium carbonate and opaline silica; this resulted in additions of calcium and strontium,increases in oxygen-18 content, and some redistribution of trace elements. After leaching the samples to remove authigenic carbonate, no differences in strontium or lead isotope compositions between altered and unaltered sections were observed. These data show that although localized alteration of the tuffs has occurred and affected their geochemistry, there is no indication of additions of exotic components. The lack of evidence for exotic strontium and lead in the most severely altered tuff samples at Yucca Mountain strongly implies a similar lack of exotic base or precious metals

  12. Channelling of hydrothermal fluids during the accretion and evolution of the upper oceanic crust: Sr isotope evidence from ODP Hole 1256D

    Harris, Michelle; Coggon, Rosalind M.; Smith-duque, Christopher E.; Cooper, Matthew J.; Milton, James A.; Teagle, Damon A. H.

    2015-01-01

    ODP Hole 1256D in the eastern equatorial Pacific is the first penetration of a complete section of fast spread ocean crust down to the dike–gabbro transition, and only the second borehole to sample in situ sheeted dikes after DSDP Hole 504B. Here a high spatial resolution record of whole rock and mineral strontium isotopic compositions from Site 1256 is combined with core observations and downhole wireline geophysical measurements to determine the extent of basalt–hydrothermal fluid reaction ...

  13. Sr and O isotopic characteristics of porphyries in the Qinling molybdenum deposit belt and their implication to genetic mechanism and type

    陈衍景; 李超; 张静; 李震; 王海华

    2000-01-01

    A great deal of Mesozoic hypobatholithic granites and hypabyssal porphyries develop in the Qinling Mountains. The former has long been regarded as transformation type (or S-type), and the latter associated with Mo-mineralization regarded as syntexis type (or l-type) granitoids. Statistics show that Sr, andδ18O of hypabyssal porphyries respectively range from 0.705 to 0.714, and from 7.2‰ to 12.1‰, agreeing with those of hypobatholithes (Sr1=0.705-0.710, δ18O = 6.1‰-10.4‰), which indicates that they share similar material sources and petrogenic mechanism. Based on analysis of lithological, mineralogical and geochemical characteristics of these granitoids and on study of their petrogenic tectonic background and regional geophysical data, we argue that both the shallow-seated porphyries and deep-seated batholithes were the products of Mesozoic collision between South China and North China paleocontinents. Subsequently, all these granti-toids should be attributed to collision type.

  14. 87Sr/86Sr measurements on marine sediments by inductively coupled plasma-mass spectrometry

    The application of inductively coupled plasma-mass spectrometry (ICP-MS) is documented for the study of the strontium isotopic composition (87Sr/86Sr) in geological samples, i.e. in the marine lithic fraction of core sediments. Methods for the determination of the isotopic composition, its accuracy and precision are reported. The results obtained simultaneously on 11 samples by both ICP-MS and thermal ionization mass spectrometry (TIMS) reveal a very good correlation (r2 = 0.955). (orig.)

  15. Trace elemental and Nd-Sr-Pb isotopic compositional variation in 37 lava flows of the Mandla lobe and their chemical relation to the western Deccan stratigraphic succession, India

    Shrivastava, J. P.; Mahoney, J. J.; Kashyap, M. R.

    2014-12-01

    The Mandla lobe is a 900 m thick lava pile that forms a 29,400 km2 northeastern extension of the Deccan Traps. Earlier, combined field, petrographic, and major element studies have shown that this lobe comprises 37 lava flows. Using a combination of trace elements (Ba, Ti, Zr, Rb, Sr) and Nb/Zr values, we group the flows into six chemical types (A-F) that are separated stratigraphically. Combined trace element and Nd-Pb-Sr isotopic data, document the presence of lavas resembling those of the Poladpur Formation and less abundantly, the Ambenali Formation of the southwestern Deccan are in conformity with the earlier reconnaissance work. In addition, our data reveal several flows similar to those of the Mahabaleshwar Formation, the type sections of which are located ~ 900 km to the southwest. Based on the isotopic data the superposition of Mahabaleshwar-like flows over flows with Ambenali- and Poladpur-like characteristics is in the same stratigraphic order seen in the southwestern Deccan type section. However, from the stratigraphy indicated by the Discriminant Function Analysis (DFA) results and the serious discrepancy between the DFA and isotopic data, it seems that few Mandla lobe flows are different and not in the same stratigraphic order as in the southwestern part of the province. To some extent the differences may be explained by faulting along four large post-Deccan normal faults near Nagapahar, Kundam, Deori, and Dindori areas across which offsets of ~150 m have been measured. This post-emplacement faulting accounts for the presence of several chemically Mahabaleshwar-like lavas at the base of the ~900 m thick Mandla lobe pile, at a lower elevation than a thick sequence dominated by chemically Poladpur-like flows. However, presence of common signature lavas (similar to that in the northeastern Deccan) cannot be ruled out in this area. They are similar to Poladpur-type lavas both chemically and isotopically. They appear in different formations and erupted at

  16. Integrating isotopic fingerprinting with petrology: how do igneous rocks evolve?

    Davidson, J. P.

    2002-12-01

    In the title of his seminal work, N.L. Bowen recognized the fundamental importance of magmatic evolution in producing the spectrum of igneous rocks. Indeed it is difficult to imagine a hot highly reactive fluid passing through c. 100 km of a chemically distinct medium (lithosphere) without evolving through cooling, crystallization and interaction with the wall rocks. The fact that magmas evolve - almost invariably through open system processes - has been largely marginalized in the past 30 years by the desire to use them as probes of mantle source regions. This perspective has been driven principally by advances offered by isotope geochemistry, through which components and sources can be effectively fingerprinted. Two fundamental observations urge caution in ignoring differentiation effects; 1) the scarcity of truly primary magmas according to geochemical criteria (recognized long ago by petrologists), and 2) the common occurrence of petrographic criteria attesting to open system evolution. Recent advances in multicollector mass spectrometry permit integration of the powerful diagnostic tools of isotope geochemistry with petrographic observations through accurate and precise analysis of small samples. Laser ablation and microdrilling enable sampling within and between mineral phases. The results of our microsampling investigations give widespread support for open system evolution of magmas, and provide insights into the mechanisms and timescales over which this occurs. For example; 1) core-rim decreases in 87Sr/86Sr in zoned plagioclase crystals from 1982 lavas of El Chichon volcano, Mexico, argue that the zoning and isotopic changes are in response to magma recharge mixing with an originally contaminated resident magma; 2) Single grain and intra-grain isotopic analyses of mineral phases from Ngauruhoe andesites (New Zealand) are highly variable, arguing that bulk rock data reflect mechanical aggregations of components which have evolved in discrete domains of the

  17. In situ Sr/Sr investigation of igneous apatites and carbonates using laser-ablation MC-ICP-MS

    Bizzarro, Martin; Simonetti, A.; Stevenson, R.K.;

    2003-01-01

    In situ Sr isotopic compositions of coexisting apatite and carbonate for carbonatites from the Sarfartoq alkaline complex, Greenland, have been determined by laser-ablation multicollector inductively coupled plasma mass spectrometry. This study is the first to examine the extent of Sr isotopic...... (regional) scale open-system processes, possibly involving mixing of carbonatitic melts derived from distinct mantle sources or from a common isotopically heterogeneous mantle. Copyright © 2003 Elsevier Science Ltd....

  18. Penning-trap mass spectrometry of highly charged, neutron-rich Rb and Sr isotopes in the vicinity of $A\\approx100$

    Simon, V V; Chowdhury, U; Eberhardt, B; Ettenauer, S; Gallant, A T; Mané, E; Simon, M C; Delheij, P; Pearson, M R; Audi, G; Gwinner, G; Lunney, D; Schatz, H; Dilling, J

    2012-01-01

    The neutron-rich mass region around $A\\approx100$ presents challenges for modeling the astrophysical $r$-process because of rapid shape transitions. We report on mass measurements using the TITAN Penning trap at TRIUMF-ISAC to attain more reliable theoretical predictions of $r$-process nucleosynthesis paths in this region. A new approach using highly charged ($q=15+$) ions has been applied which considerably saves measurement time and preserves accuracy. New mass measurements of neutron-rich $^{94,97,98}$Rb and $^{94,97-99}$Sr have uncertainties of less than 4 keV and show deviations of up to 11$\\sigma$ to previous measurements. An analysis using a parameterized $r$-process model is performed and shows that mass uncertainties for the A=90 abundance region are eliminated.

  19. Sr/Ca and stable isotopes in a coral from the Venezuelan coast: A record of 20th-century changes in SST, SSS and cloud cover?

    Hetzinger, S.; Pfeiffer, M.; Dullo, W.; Zinke, J.; Garbe-Schoenberg, C.

    2011-12-01

    We present a record of monthly δ18O and Sr/Ca variations in coral aragonite from a massive Diploria strigosa colony retrieved from a coastal NW-Venezuelan reef site (10.55°N, 67.24°W; 1940-2004). Linear regression of coral proxies to high resolution satellite sea surface temperature (SST) data (NASA OBPG MODIS-Aqua, 9-km resolution) demonstrates that both geochemical proxies record seasonal temperature variability in ambient seawater (Sr/Ca: r=-0.68 monthly, r=-0.60 annual; δ18O: r=-0.57 monthly, r=-0.46 annual; 1985-2004). On longer time scales both proxies record local as well as regional SST dynamics in the southeastern Caribbean and northern North Tropical Atlantic. A statistically significant relationship is observed between coral δ18O and local air temperature (r=-0.56; 1951-2002), while correspondence of δ18O to SST products (e.g. ERSST, SODA reanalysis) is lower than for Sr/Ca ratios. However, coral δ18O is a function of both temperature and δ18Oseawater and δ18Oseawater in turn is dependent on salinity. A comparison of δ18O to sea surface salinity (SSS) data confirms the existence of a strong salinity component in coral δ18O on annual and longer time scales (SODA reanalysis, r=0.65 for annual means, r=0.84 for 3-year average; 1958-2001). A decreasing trend from the mid-1980s onwards is evident in both SSS and coral δ18O, corresponding to trends seen in other Caribbean studies. Further, both geochemical proxies show a significant negative correlation to cloud cover averaged over a regional box (r=-0.66 for Sr/Ca; r=-0.48 for δ18O; 1941-2003). A significant drop in cloud cover is seen around the year 1947, which is displayed in both proxies as a distinct positive peak and coincides with a drop in instrumental SST. Interestingly, a marked decrease in annual coral growth rate is observed in the uppermost years of the core (1999 to 2004), as well as a reduced seasonal amplitude in δ18O variability and a trend to more negative δ18O-values at the

  20. Petrogenesis of subvolcanic rocks from the Khunik prospecting area, south of Birjand, Iran: Geochemical, Sr-Nd isotopic and U-Pb zircon constraints

    Samiee, Somayeh; Karimpour, Mohammad Hassan; Ghaderi, Majid; Haidarian Shahri, Mohammad Reza; Klöetzli, Urs; Santos, José Francisco

    2016-01-01

    The Khunik prospecting area is located 106 km south of Birjand in eastern Iran, and is considered as an epithermal gold prospecting area. The mineralization is related to subvolcanic rocks. There are several outcrops of subvolcanic intrusions in the area which intruded into Paleocene-Eocene volcanic rocks (andesite, trachy-andesite and pyroclastic rocks). Petrographic studies indicate that subvolcanic rocks consist mainly of diorite, monzonite, quartz-monzonite, monzodiorite and quartz-monzodiorite. Mineralogically, these rocks contain plagioclase, K-feldspar, amphibole, pyroxene, biotite and quartz. Geochemically, they have features typical of high-K calk-alkaline to shoshonitic and are metaluminous, and also belong to magnetite granitoid series (I-type). Primitive mantle normalized trace element spider diagrams display enrichment in LILE, such as Rb, Ba, and Cs, compared to HFSE. Chondrite-normalized REE plots show moderately LREE enriched patterns (7.45 diagrams also show affinities with modern convergent margin magmas, suggesting that magmas of Khunik area formed in volcanic arc setting related to subduction of the oceanic crust under the Lut Block plate. The initial 87Sr/86Sr ratios (0.704196-0.704772) and εNdi values (+1.3 to +3.3) are compatible with an origin of the parental melts in a supra-subduction mantle wedge. Zircon U-Pb dating by LA-ICP-MS indicates the age of 38 ± 1 Ma (late Eocene) for subvolcanic units that are related to mineralization. A biotite granodiorite porphyry is the testimony of the youngest magmatic activity in the area, with an age of 31 ± 1 Ma (early Oligocene). The represented dates are interpreted as magmatic crystallization ages of subvolcanic intrusions.

  1. Geochronological synthesis of Bahia state and the crustal evolution, based in evolution diagram of Sr and initial rate of Sr87/Sr86

    The crustal evolution of the ancient terrains of the State of Bahia, Brazil, is attempted with the aid of Sr isotopic results as natural tracers. Some Nd and Pb isotopic data are also available, and support the main conclusions based on Sr evolution diagrams. The analysis of the Sr evolution diagrams shows that the Archean Terrains are mainly formed by accretion from mantle-derived material, but crustal reworking is indicated by the high initial 87Sr/86Sr value of the Jequie Complex. The Transamazonian mobile belt include both types of materials, but the 87Sr/86Sr value, generally lower than those of the Jequie Complex, markes improbable a direct derivation. During Middle and Late Proterozoic, the continental crust was already well consolidated, and reworking of crustal material predominated within the Espinhaco and Brasiliano folded systems

  2. Mantle-like Sr-Nd isotope composition of Fe-K subalkaline granites : the Peneda-Gerês Variscan massif (NW Iberian Peninsula)

    Mendes, Anabela Carreira; Dias, G.

    2004-01-01

    The Peneda-Gerês massif is one of the most representative NW Iberian late- to post-orogenic Variscan granitic plutons. It resulted essentially from the subsynchronous emplacement, at 290-296 Ma, of two granitic magmas of Fe-K subalkaline affinity, with primitive isotopic composition: Sri = 0.703-0.707 and eNdi = -1.5 to -2.4. An origin by mantle input followed by mantle-crust interactions is proposed, implying the contribution of a less enriched mantle component than that involved in the gene...

  3. Experiences with the determination of Sr-89 and Sr-90 using fast methods; Erfahrungen bei der Bestimmung von {sup 89}Sr und {sup 90}Sr mittels Schnellmethoden

    Kowalik, C.; Fueger, J. [Thueringer Landesanstalt fuer Umwelt und Geologie, Jena (Germany). Landesmessstelle fuer Umweltradioaktivaet

    2014-01-20

    Quick methods of the measurement of {sup 89}Sr and {sup 90}Sr have a great importance in the supervision of the environmental radioactivity. It is necessary to receive in short time dependable analytical data to be able to carry out suitable assessments or to give recommendations. The aim of the investigations was to be guaranteed the demands for these methods (test preparation, measurement and evaluation). The use of the solid phase extraction by means of commercial Sr Resin trademark columns (4.4' (5')-Di-tert-butylcyclohexanol-18-kronen-6-aether) (Triskem) to the radiochemical separation of the Sr isotopes was suitable. The measurements occurred to the FHT 770 T12 - Multi Low Level Alpha/Beta Sample Counter (Thermo Scientific). The results contain the summary activities of all available Sr isotopes, as for example {sup 89}Sr and {sup 90}Sr. The calculations of the single activities occur about the mathematical algorithm of the linear development on the basis of the works of G. Kanisch. The first results show, this method is suitable for the analysis of {sup 89}Sr and {sup 90}Sr and is used therefore in future in Thuringia.

  4. Petrogenesis of the Yaochong granite and Mo deposit, Western Dabie orogen, eastern-central China: Constraints from zircon U-Pb and molybdenite Re-Os ages, whole-rock geochemistry and Sr-Nd-Pb-Hf isotopes

    Chen, Wei; Xu, Zhaowen; Qiu, Wenhong; Li, Chao; Yu, Yang; Wang, Hao; Su, Yang

    2015-05-01

    The Dabie orogen is among the most famous continent-continent collisional orogenic belts in the world, and is characterized by intensive post-collisional extension, magmatism and Mo mineralization. However, the genetic links between the mineralization and the geodynamic evolution of the orogen remain unresolved. In this paper, the Yaochong Mo deposit and its associated granitic stocks were investigated to elucidate this issue. Our new zircon U-Pb ages yielded an Early Cretaceous age (133.3 ± 1.3 Ma) for the Yaochong granite, and our molybdenite Re-Os dating gave a similar age (135 ± 1 Ma) for the Mo deposit. The Yaochong stock is characterized by high silica and alkali but low Mg, Fe and Ca. It is enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs: Rb, K, Th and U), but strongly depleted in heavy REEs, and high field strength elements (HFSEs: Nb, Ta, Ti and Y). The Yaochong granite has initial 87Sr/86Sr ratios of 0.7087-0.7096, and Pb isotopic ratios of (206Pb/204Pb)i = 16.599-16.704, (207Pb/204Pb)i = 15.170-15.618 and (208Pb/204Pb)i = 36.376-38.248. The granite has εNd(t) of -18.0 to -16.3 and εHf(t) values of -26.5 to -20.0. All these data indicate that the Yaochong granite is a high-K calc-alkaline fractionated I-type granite, and may have originated from partial melting of the thickened Yangtze continental crust. The Mo ores also show low radiogenic Pb isotopes similar to the Yaochong stock. Medium Re content in molybdenite (21.8-74.8 ppm) also suggests that the ore-forming materials were derived from the thickened lower crust with possibly minor mixing with the mantle. Similar to the Eastern Dabie orogen, the thickened crust beneath the Western Dabie orogen may also have experienced tectonic collapse, which may have exerted fundamental geodynamic controls on the two-stage Mo mineralization in the region.

  5. 40Ar/39Ar Geochronology, Isotope Geochemistry (Sr, Nd, Pb), and petrology of alkaline lavas near Yampa, Colorado: migration of alkaline volcanism and evolution of the northern Rio Grande rift

    Cosca, Michael A.; Thompson, Ren A.; Lee, John P.; Turner, Kenzie J.; Neymark, Leonid A.; Premo, Wayne R.

    2014-01-01

    Volcanic rocks near Yampa, Colorado (USA), represent one of several small late Miocene to Quaternary alkaline volcanic fields along the northeast margin of the Colorado Plateau. Basanite, trachybasalt, and basalt collected from six sites within the Yampa volcanic field were investigated to assess correlations with late Cenozoic extension and Rio Grande rifting. In this paper we report major and trace element rock and mineral compositions and Ar, Sr, Nd, and Pb isotope data for these volcanic rocks. High-precision 40Ar/39Ar geochronology indicates westward migration of volcanism within the Yampa volcanic field between 6 and 4.5 Ma, and the Sr, Nd, and Pb isotope values are consistent with a primary source in the Proterozoic subcontinental lithospheric mantle. Relict olivine phenocrysts have Mg- and Ni-rich cores, whereas unmelted clinopyroxene cores are Na and Si enriched with finely banded Ca-, Mg-, Al-, and Ti-enriched rims, thus tracing their crystallization history from a lithospheric mantle source region to one in contact with melt prior to eruption. A regional synthesis of Neogene and younger volcanism within the Rio Grande rift corridor, from northern New Mexico to southern Wyoming, supports a systematic overall southwest migration of alkaline volcanism. We interpret this Neogene to Quaternary migration of volcanism toward the northeast margin of the Colorado Plateau to record passage of melt through subvertical zones within the lithosphere weakened by late Cenozoic extension. If the locus of Quaternary alkaline magmatism defines the current location of the Rio Grande rift, it includes the Leucite Hills, Wyoming. We suggest that alkaline volcanism in the incipient northern Rio Grande rift, north of Leadville, Colorado, represents melting of the subcontinental lithospheric mantle in response to transient infiltration of asthenospheric mantle into deep, subvertical zones of dilational crustal weakness developed during late Cenozoic extension that have been

  6. 87Sr/ 86Sr and Sr/Ca in speleothems for paleoclimate reconstruction in Central China between 70 and 280 kyr ago

    Li, Hong-Chun; Ku, Teh-Lung; You, Chen-Feng; Cheng, Hai; Edwards, R. Lawrence; Ma, Zhi-Bang; Tsai, Wang-sheng; Li, Mung-Dar

    2005-08-01

    Limestone cave deposits (speleothems) provide archives for past changes in regional climates over a range of timescales. While δ 18O and δ 13C in speleothem calcite have been commonly used for reconstruction of paleoclimates, we report here further efforts in the use of 87Sr/ 86Sr and Sr/Ca signals in speleothem calcite to deduce paleomonsoon variability near the Loess Plateau of central China. A two end-member mass-balance model of concentration and isotopic composition of strontium in a cave system is used to estimate variation of the 87Sr/ 86Sr ratio in sediments overlying a limestone cave. We show that this ratio reflects climate-driven variations in the provenance and the extent of chemical weathering of the epikarstic sediments. The measurements of 87Sr/ 86Sr made on a well-dated stalagmite, SFL, from Buddha Cave (33 o40N' 109 o05'E) show ratios of 0.71092 to 0.71133 (±0.00001 as 2σ) during relatively cold periods (e.g., Marine Isotope Stage (MIS) 5b, 5d, and 8), lower than ratios of 0.71133 to 0.71194 during relatively warm periods (e.g., MIS 5a, 5c, 5e, and 7). As changes in the Sr/Ca ratio may affect speleothem 87Sr/ 86Sr, we show that the direct use of speleothem 87Sr/ 86Sr is less ideal than our modeled 87Sr/ 86Sr for the exogenic Sr source above the cave as a paleomonsoon proxy. Using the δ 18O, δ 13C, Sr/Ca, and 87Sr/ 86Sr records of the stalagmite, we reconstruct the variability of the East Asian monsoon for the time period between 70 and 280 kyr ago. The results show that summer monsoons were more intense during interglacial periods than during glacial periods.

  7. Development of an accurate, sensitive, and robust isotope dilution laser ablation ICP-MS method for simultaneous multi-element analysis (chlorine, sulfur, and heavy metals) in coal samples

    A method for the direct multi-element determination of Cl, S, Hg, Pb, Cd, U, Br, Cr, Cu, Fe, and Zn in powdered coal samples has been developed by applying inductively coupled plasma isotope dilution mass spectrometry (ICP-IDMS) with laser-assisted introduction into the plasma. A sector-field ICP-MS with a mass resolution of 4,000 and a high-ablation rate laser ablation system provided significantly better sensitivity, detection limits, and accuracy compared to a conventional laser ablation system coupled with a quadrupole ICP-MS. The sensitivity ranges from about 590 cps for 35Cl+ to more than 6 x 105 cps for 238U+ for 1 μg of trace element per gram of coal sample. Detection limits vary from 450 ng g-1 for chlorine and 18 ng g-1 for sulfur to 9.5 pg g-1 for mercury and 0.3 pg g-1 for uranium. Analyses of minor and trace elements in four certified reference materials (BCR-180 Gas Coal, BCR-331 Steam Coal, SRM 1632c Trace Elements in Coal, SRM 1635 Trace Elements in Coal) yielded good agreement of usually not more than 5% deviation from the certified values and precisions of less than 10% relative standard deviation for most elements. Higher relative standard deviations were found for particular elements such as Hg and Cd caused by inhomogeneities due to associations of these elements within micro-inclusions in coal which was demonstrated for Hg in SRM 1635, SRM 1632c, and another standard reference material (SRM 2682b, Sulfur and Mercury in Coal). The developed LA-ICP-IDMS method with its simple sample pretreatment opens the possibility for accurate, fast, and highly sensitive determinations of environmentally critical contaminants in coal as well as of trace impurities in similar sample materials like graphite powder and activated charcoal on a routine basis. (orig.)

  8. Zircon U-Pb geochronology and Sr-Nd isotopes of volcanic rocks from the Dahalajunshan Formation: implications for Late Devonian-Middle Carboniferous tectonic evolution of the Chinese Western Tianshan

    Yu, Xinqi; Wang, Zongxiu; Zhou, Xiang; Xiao, Weifeng; Yang, Xinpeng

    2016-07-01

    The widespread Late Devonian-Middle Carboniferous volcanic rocks in the Chinese Western Tianshan provide important constraints on the subduction history of the South Tianshan oceanic lithosphere. Here, we investigate the basalt, basaltic andesite, andesite, trachyandesite, and rhyolite from the Dahalajunshan Formation from Western Tianshan. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology constrains their age of formation to between 376 and 333 Ma (i.e., Late Devonian-Middle Carboniferous) with distinct variation in space (from west to east) and time (from early to late). Based on geochemical, zircon geochronological, and Sr-Nd isotopic data, we demonstrate that the Dahalajunshan volcanic was generated in a continental arc setting associated with the subduction of the south Tianshan Ocean during Late Devonian to Middle Carboniferous. The volcanic rocks belonging to Dahalajunshan Formation in the northwestern part of the Yili Block suggest that the northward subduction of the south Tianshan Ocean was initiated in the Early Devonian; those in the southern and eastern part of the Yili Block were probably produced by a northward subduction of South Tianshan Ocean during Late Devonian to Middle Carboniferous.

  9. Automated Sample Preparation for Radiogenic and Non-Traditional Metal Isotopes: Removing an Analytical Barrier for High Sample Throughput

    Field, M. Paul; Romaniello, Stephen; Gordon, Gwyneth W.; Anbar, Ariel D.; Herrmann, Achim; Martinez-Boti, Miguel A.; Anagnostou, Eleni; Foster, Gavin L.

    2014-05-01

    MC-ICP-MS has dramatically improved the analytical throughput for high-precision radiogenic and non-traditional isotope ratio measurements, compared to TIMS. The generation of large data sets, however, remains hampered by tedious manual drip chromatography required for sample purification. A new, automated chromatography system reduces the laboratory bottle neck and expands the utility of high-precision isotope analyses in applications where large data sets are required: geochemistry, forensic anthropology, nuclear forensics, medical research and food authentication. We have developed protocols to automate ion exchange purification for several isotopic systems (B, Ca, Fe, Cu, Zn, Sr, Cd, Pb and U) using the new prepFAST-MC™ (ESI, Nebraska, Omaha). The system is not only inert (all-flouropolymer flow paths), but is also very flexible and can easily facilitate different resins, samples, and reagent types. When programmed, precise and accurate user defined volumes and flow rates are implemented to automatically load samples, wash the column, condition the column and elute fractions. Unattended, the automated, low-pressure ion exchange chromatography system can process up to 60 samples overnight. Excellent reproducibility, reliability, recovery, with low blank and carry over for samples in a variety of different matrices, have been demonstrated to give accurate and precise isotopic ratios within analytical error for several isotopic systems (B, Ca, Fe, Cu, Zn, Sr, Cd, Pb and U). This illustrates the potential of the new prepFAST-MC™ (ESI, Nebraska, Omaha) as a powerful tool in radiogenic and non-traditional isotope research.

  10. Geochemical, zircon U-Pb dating and Sr-Nd-Hf isotopic constraints on the age and petrogenesis of an Early Cretaceous volcanic-intrusive complex at Xiangshan, Southeast China

    Yang, Shui-Yuan; Jiang, Shao-Yong; Jiang, Yao-Hui; Zhao, Kui-Dong; Fan, Hong-Hai

    2011-01-01

    The Late Mesozoic geology of Southeast China is characterized by extensive Jurassic to Cretaceous magmatism consisting predominantly of granites and rhyolites and subordinate mafic rocks, forming a belt of volcanic-intrusive complexes. The Xiangshan volcanic-intrusive complex is located in the NW region of the belt and mainly contains the following lithologies: rhyodacite and rhyodacitic porphyry, porphyritic lava, granite porphyry with mafic microgranular enclaves, quartz monzonitic porphyry, and lamprophyre dyke. Major and trace-element compositions, zircon U-Pb dating, and Sr-Nd-Hf isotopic compositions have been investigated for these rocks. The precise SHRIMP and LA-ICP-MS zircon U-Pb dating shows that the emplacement of various magmatic units at Xiangshan took place within a short time period of less than 2 Myrs. The stratigraphically oldest rhyodacite yielded a zircon U-Pb age of 135 ± 1 Ma and the overlying rhyodacitic porphyry has an age of 135 ± 1 Ma. Three porphyritic lava samples yielded zircon U-Pb ages of 136 ± 1 Ma, 132 ± 1 Ma, and 135 ± 1 Ma, respectively. Two subvolcanic rocks (granite porphyry) yielded zircon U-Pb ages of 137 ± 1 Ma and 137 ± 1 Ma. A quartz monzonitic porphyry dyke, which represented the final stage of magmatism at Xiangshan, also yielded a zircon U-Pb age of 136 ± 1 Ma. All these newly obtained precise U-Pb ages demonstrate that the entire magmatic activity at Xiangshan was rapid and possibly took place at the peak of extensional tectonics in SE China. The geochemical data indicate that all these samples from the volcanic-intrusive complex have an A-type affinity. Sr-Nd-Hf isotopic data suggest that the Xiangshan volcanic-intrusive complex derived mainly from remelting of Paleo-Mesoproterozoic crust without significant additions of mantle-derived magma. However, the quartz monzonitic porphyry, which has zircon Hf model ages older than the whole-rock Nd model ages, and which has ɛNd(T) value higher than the other rocks

  11. Paleoenvironments in Meso-Neoproterozoic carbonates of the Mbuji-Mayi Supergroup (Democratic Republic of Congo) - Microfacies analysis combined with C-O-Sr isotopes, major-trace elements and REE + Y distributions

    Delpomdor, F.; Blanpied, C.; Virgone, A.; Préat, A.

    2013-12-01

    The Meso- and Neoproterozoic Mbuji-Mayi Supergroup (1155 Ma to ca. 800 Ma) was deposited in the SE-NW trending siliciclastic-carbonate failed-rift in the Sankuru-Mbuji-Mayi-Lomami-Lovoy Basin. Drillcore- and outcrop-derived microfacies, isotope (C, O and Sr) compositions of carbonates and REE + Y distributions are integrated to unravel the paleoenvironmental and chemical conditions prevailing during deposition and alteration (or contamination) of the Mbuji-Mayi carbonates. The carbonate succession (BIe subgroup and BIIa to BIIe subgroups), composed of 11 microfacies (MF), records the evolution of a marine ramp submitted to evaporation, with basinal and low-energy outer-ramp environments (MF1-MF5), biohermal mid-ramp (MF6) and restricted tide-dominated lagoon inner-ramp (MF7-MF9) settings, overlain by lacustrine (MF10) and sabkha (MF11) environments. The ramp margin is characterized by thick stacks of stromatolitic bioherms. δ13C and δ18O relationships in the Mbuji-Mayi carbonates allow discrimination between meteoric (δ13C: -7.5‰ to +0.0‰, δ18O: -7.0‰ to -1.0‰) and burial lithifications (δ13C: -1.5‰ to +0.0‰, δ18O: -15.1‰ to -7.0‰), that overprinted a primary marine signal (δ13C: -1.5‰ to +2.0‰, δ18O: -3.0‰ to +0.5‰) partially preserved in the subgroups. Unaltered pristine signals are found in the Mbuji-Mayi carbonates with 87Sr/86Sr ratios (0.7065-0.7082) similar to those of the marine-preserved strontium signatures of the early Neoproterozoic oceans. The PAAS-normalized REE + Y distributions indicate that the BIe carbonates were altered by Fe-oxide-rich hydrothermal fluids. BIIb and BIIe carbonates exhibit uniform light REE depleted patterns suggesting inputs of detrital river material whereas a marine seawater, highlighted by the REE + Y distributions is preserved in BIIc and BIId carbonates. The pattern of carbon, oxygen and strontium isotopic variations in the Mbuji-Mayi carbonates reflects deposition and early diagenesis in

  12. Strontium isotope characterization of wines from Quebec, Canada.

    Vinciguerra, Victor; Stevenson, Ross; Pedneault, Karine; Poirier, André; Hélie, Jean-François; Widory, David

    2016-11-01

    The (87)Sr/(86)Sr isotope ratios were measured on grape, wine and soil samples collected in 13 commercial vineyards located in three major wine producing areas of Quebec (Canada). The soils yield Sr isotope ratios that are intimately related to the local geology and unambiguously discriminate the different producing areas. A strong relationship exists between the (87)Sr/(86)Sr isotope ratios of the wine and the grapes. This suggests that the vinification process does not alter the overall Sr budget. Although the Sr isotope ratios of the grapes do not show a strong correlation with the bulk Sr isotope composition of the soil, they do correlate strongly with the Sr isotope composition contained in the labile fraction of the soil. This indicates that the labile fraction of the soil represents the Sr reservoir available to the plant during its growth. This study demonstrates that the Sr isotope approach can be used as a viable tool in forensic science for investigating the provenance of commercial wines. PMID:27211629

  13. Sr-Nd-Hf isotopes of the intrusive rocks in the Cretaceous Xigaze ophiolite, southern Tibet: Constraints on its formation setting

    Zhang, Liang-Liang; Liu, Chuan-Zhou; Wu, Fu-Yuan; Zhang, Chang; Ji, Wei-Qiang; Wang, Jian-Gang

    2016-08-01

    The Cretaceous Xigaze ophiolite is best exposed at the central part of the Yarlung-Zangbo Suture Zone, Tibet Plateau. It consists of a thick section of mantle peridotites, but a relatively thin mafic sequence. This study presents geochronological and geochemical data for intrusive dykes (both mafic and felsic) and basalts to revisit the formation setting of the Xigaze ophiolite. The rodingites are characterized by high CaO and low Na2O contents relative to mafic dykes and show big variations in trace element compositions. Both gabbros and diabases have similar geochemical compositions, with MgO contents of 6.42-11.48 wt% and Mg# of 0.56-0.71. They display REE patterns similar to N-MORB and are variably enriched in large ion lithophile elements. Basalts have fractionated compositions and display LREE-depleted patterns very similar to N-MORB. They do not show obvious enrichment in LILE and depletion in high-field-strength elements, but a negative Nb anomaly is present. The studied plagiogranites have compositions of trondhjemite to tonalite, with high Na2O and low K2O contents. They have low TiO2 contents less than 1 wt%, consistent with melts formed by anatexis of gabbros rather than by differentiation of basalts. Zircons from seven samples, including three rodingites, three plagiogranites, and one gabbro, have been dated and yielded U-Pb ages of 124.6 ~ 130.5 Ma, indicating the Xigaze ophiolite was formed during the Early Cretaceous. They have mantle-like δ18O values of + 4.92 ~ + 5.26‰ and very positive εHf(t) values of + 16 ~ + 13.3. Ages of the rodingites and less altered gabbros indicate that serpentinization was occurred at ~ 125 Ma. Occurrence of both gabbroic and diabase dykes within the serpentinites suggests that the mantle lithosphere of the Xigaze ophiolite was rapidly exhumed. Both mafic and felsic dykes have slightly more radiogenic 87Sr/86Sr ratios relative to MORB, but depleted Hf-Nd isotpe compositions. They have a limited range of ε

  14. Zircon U-Pb and molybdenite Re-Os geochronology and Sr-Nd-Pb-Hf isotopic constraints on the genesis of the Xuejiping porphyry copper deposit in Zhongdian, Northwest Yunnan, China

    Leng, Cheng-Biao; Zhang, Xing-Chun; Hu, Rui-Zhong; Wang, Shou-Xu; Zhong, Hong; Wang, Wai-Quan; Bi, Xian-Wu

    2012-10-01

    The Xuejiping porphyry copper deposit is located in northwestern Yunnan Province, China. Tectonically, it lies in the southern part of the Triassic Yidun island arc. The copper mineralization is mainly hosted in quartz-dioritic and quartz-monzonitic porphyries which intruded into clastic-volcanic rocks of the Late Triassic Tumugou Formation. There are several alteration zones including potassic, strong silicific and phyllic, argillic, and propylitic alteration zones from inner to outer of the mineralized porphyry bodies. The ages of ore-bearing quartz-monzonitic porphyry and its host andesite are obtained by using the zircon SIMS U-Pb dating method, with results of 218.3 ± 1.6 Ma (MSWD = 0.31, N = 15) and 218.5 ± 1.6 Ma (MSWD = 0.91, N = 16), respectively. Meanwhile, the molybdenite Re-Os dating yields a Re-Os isochronal age of 221.4 ± 2.3 Ma (MSWD = 0.54, N = 5) and a weighted mean age of 219.9 ± 0.7 Ma (MSWD = 0.88). They are quite in accordance with the zircon U-Pb ages within errors. Furthermore, all of them are contemporary with the timing of the Garzê-Litang oceanic crust subduction in the Yidun arc. Therefore, the Xuejiping deposit could be formed in a continental margin setting. There are negative ɛNd(t) values ranging from -3.8 to -2.1 and relatively high initial 87Sr/86Sr ratios from 0.7051 to 0.7059 for the Xuejiping porphyries and host andesites. The (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t values of the Xuejiping porphyries and host andesites vary from 17.899 to 18.654, from 15.529 to 15.626, and from 37.864 to 38.52, respectively, indicative of high radiogenic Pb isotopic features. In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS exhibit that there are quite uniform and slightly positive ɛHf(t) values ranging from -0.2 to +3.2 (mostly between 0 and +2), corresponding to relatively young single-stage Hf model ages from 735 Ma to 871 Ma. These isotopic features suggest that the primary magmas of the Xuejiping porphyries and

  15. Extraction chromatographic separation of Sr, Pu and Am in environmental samples

    Sidhu, Rajdeep

    2004-04-01

    An accurate determination of radionuclides from various sources in the environment is essential for assessment of the potential hazards and suitable countermeasures both in case of an authorised release, accidents and routine surveillance. Due to the short range of alpha and beta radiation, the accurate determination of pure alpha and beta emitters must always include radiochemical separations to separate the analytes from the matrix and from other interfering stable and radioactive nuclides. Hence, the procedures used for their determination are usually tedious and involve several preconcentration and separation steps. This work deals with the determination of {sup 90}Sr, {sup 241}Am, {sup 238}Pu, {sup 239,240}Pu and {sup 244}Cm, whic some of the most important artificial radionuclides. Due to either absence or low yield of gamma radiation, a secure determination of low concentrations of all these nuclides requires a dedicated chemistry. Selective extraction chromatographic resins (TRU- and Sr-Resin) have been utilised to develop new procedures for the analyses of Pu, Am and Cm isotopes in seawater and both these and {sup 90}Sr in soil, sediment, urine and low-level liquid radioactive effluents. The proposed method for the analyses of Pu and Am in seawater offers a quick and secure mode for the determination of these radionuclides in marine waters. Combined pre-concentration of actinides and strontium (oxalate or phosphate precipitation) followed by dual column separation on TRU- and Sr-Resin significantly reduces the through put time and costs compared to traditional ion exchange and precipitation methods. The greatest gain in productivity and environmental friendliness is achieved in Sr separations using Sr-Resin instead of precipitations involving fuming nitric acid and oxalate, hydroxide, chromate and carbonate precipitations. (author)

  16. Experiences with the determination of Sr-89 and Sr-90 using fast methods

    Quick methods of the measurement of 89Sr and 90Sr have a great importance in the supervision of the environmental radioactivity. It is necessary to receive in short time dependable analytical data to be able to carry out suitable assessments or to give recommendations. The aim of the investigations was to be guaranteed the demands for these methods (test preparation, measurement and evaluation). The use of the solid phase extraction by means of commercial Sr Resin trademark columns (4.4' (5')-Di-tert-butylcyclohexanol-18-kronen-6-aether) (Triskem) to the radiochemical separation of the Sr isotopes was suitable. The measurements occurred to the FHT 770 T12 - Multi Low Level Alpha/Beta Sample Counter (Thermo Scientific). The results contain the summary activities of all available Sr isotopes, as for example 89Sr and 90Sr. The calculations of the single activities occur about the mathematical algorithm of the linear development on the basis of the works of G. Kanisch. The first results show, this method is suitable for the analysis of 89Sr and 90Sr and is used therefore in future in Thuringia.

  17. Small scale inhomogeneity in the mantle source of the Cape Verde hotspot is probably related to plume complexity: implications from Sr, Nd and high precision Pb isotopes and geochemistry

    Holm, P. M.; Sørensen, R. V.

    2009-04-01

    The volcanic rocks of one of the major islands of the Cape Verde hotspot have been investigated in order to test mantle plume models. From the centre of the Cape Verde Rise an array of islands trend west, the northern HIMU-type Cape Verde Islands. Of these, São Nicolau (SN) is the easternmost and Santo Antão the westernmost. Sixty samples of primitive (MgO = 9-14 wt%) basanitic composition from SN that represent the four volcanic stages of the 9 - 0.1 Ma evolution of the island have been analysed for Sr, Nd and high precision Pb isotopic composition. Pb ranges to a less radiogenic composition than on SA [1] and has lower 8/4 than the rocks of the southern EM1-type Cape Verde islands. Most SN lavas have a young HIMU character with negative 7/4. The most radiogenic Pb at SN is less thorogenic than Pb at SA. Temporal variation is also evident: An intermediate age group of samples have particularly low La/Nb = 0.4 - 0.5 and the least LREE-enrichment for SN. The youngest group of rocks has the lowest Zr/Nb = 2.5 - 3.0 and the most unradiogenic Sr and radiogenic Nd in the archipelago. At least four of the mantle source components for the SN magmas are different from any found in the SA magmas. High precision Pb data allow identification of parallel trends for northern SN and the southern island Santiago, which therefore must have unrelated source components. For the northern Cape Verde islands source compositions vary from E to W as well as with time. This cannot be explained by stationary enriched lithosphere components. The derivation of melts from a complex plume source is modelled. [1] Holm P.M., Wilson J.R., Christensen B.P., Hansen S.L., Hein K.M., Mortensen A.K., Pedersen R., Plesner S., and Runge M.K. (2006) JPetrol 47, 145-189.

  18. Geochemistry, zircon U-Pb ages and Sr-Nd-Hf isotopes of an Ordovician appinitic pluton in the East Kunlun orogen: New evidence for Proto-Tethyan subduction

    Xiong, Fuhao; Ma, Changqian; Wu, Liang; Jiang, Hong'an; Liu, Bin

    2015-11-01

    Appinite is commonly derived from a mantle source in subduction zones and thus holds a key to constrain the tectonic evolution of ancient orogens. This study presents chronological, mineralogical and geochemical data for one appinitic pluton from the south Tethyan suture zone in the East Kunlun orogen, Northern Tibetan Plateau. The pluton is predominantly composed of hornblende-rich mafic appinites, with minor amounts of granodiorite. Zircon U-Pb age of the granodiorite (466 Ma) is identical to the mafic appinites (447-450 Ma). The mafic appinites are commonly hornblende diorites, which comprise large amounts of magnesio-hornblende [Mg/(Fe + Mg) = 0.61-0.68] and andesine (An43-54). The hornblende diorites have low contents of SiO2 (48.62-54.95 wt.%), high contents of total FeO (7.90-12.84 wt.%) and MgO (4.32-11.89 wt.%) and moderate values of Mg# [Mg# = molar 100 ∗ Mg/(Mg + Fe); 49-69]. Their geochemistry displays: slight enrichment of light rare earth elements ((La/Yb)N = 1.89-6.84) and flat heavy rare earth elements ((Ga/Yb)N = 1.49-2.22); enrichment in large ion lithophile elements and depletion in high field strength elements; less-enriched isotopic compositions with initial 87Sr/86Sr ratios of 0.70536-0.70617, εNd(t) of 0.79-3.02 and zircon εHf(t) of 8.73-12.82. The associated granodiorites comprise plagioclase (45-50 vol.%, An = 26-39), quartz (15-20 vol.%), K-feldspar (5-10 vol.%), ferrohornblende [2-5 vol.%, (Mg/(Fe + Mg) = 0.45-0.49] and epidote (1-5 vol.%). The epidotes have pistacite components ranging from 23 to 28. The granodiorites exhibit calc-alkaline character, and have rare earth and trace element patterns similar to the hornblende diorites. The geochemical compositions and simulations suggest that the parental magma of the mafic appinites was generated by partial melting of one depleted mantle source which was metasomatised by subducted sediment-derived felsic melts (ca. 20-25%). Fractional crystallization of clinopyroxene, hornblende

  19. Development of an accurate, sensitive, and robust isotope dilution laser ablation ICP-MS method for simultaneous multi-element analysis (chlorine, sulfur, and heavy metals) in coal samples

    Boulyga, Sergei F. [University of Natural Resources and Applied Life Sciences, Department of Chemistry, Division of Analytical Chemistry-VIRIS Laboratory, Vienna (Austria); Johannes Gutenberg-University, Institute of Inorganic Chemistry and Analytical Chemistry, Mainz (Germany); Heilmann, Jens; Heumann, Klaus G. [Johannes Gutenberg-University, Institute of Inorganic Chemistry and Analytical Chemistry, Mainz (Germany); Prohaska, Thomas [University of Natural Resources and Applied Life Sciences, Department of Chemistry, Division of Analytical Chemistry-VIRIS Laboratory, Vienna (Austria)

    2007-10-15

    A method for the direct multi-element determination of Cl, S, Hg, Pb, Cd, U, Br, Cr, Cu, Fe, and Zn in powdered coal samples has been developed by applying inductively coupled plasma isotope dilution mass spectrometry (ICP-IDMS) with laser-assisted introduction into the plasma. A sector-field ICP-MS with a mass resolution of 4,000 and a high-ablation rate laser ablation system provided significantly better sensitivity, detection limits, and accuracy compared to a conventional laser ablation system coupled with a quadrupole ICP-MS. The sensitivity ranges from about 590 cps for {sup 35}Cl{sup +} to more than 6 x 10{sup 5} cps for {sup 238}U{sup +} for 1 {mu}g of trace element per gram of coal sample. Detection limits vary from 450 ng g{sup -1} for chlorine and 18 ng g{sup -1} for sulfur to 9.5 pg g{sup -1} for mercury and 0.3 pg g{sup -1} for uranium. Analyses of minor and trace elements in four certified reference materials (BCR-180 Gas Coal, BCR-331 Steam Coal, SRM 1632c Trace Elements in Coal, SRM 1635 Trace Elements in Coal) yielded good agreement of usually not more than 5% deviation from the certified values and precisions of less than 10% relative standard deviation for most elements. Higher relative standard deviations were found for particular elements such as Hg and Cd caused by inhomogeneities due to associations of these elements within micro-inclusions in coal which was demonstrated for Hg in SRM 1635, SRM 1632c, and another standard reference material (SRM 2682b, Sulfur and Mercury in Coal). The developed LA-ICP-IDMS method with its simple sample pretreatment opens the possibility for accurate, fast, and highly sensitive determinations of environmentally critical contaminants in coal as well as of trace impurities in similar sample materials like graphite powder and activated charcoal on a routine basis. (orig.)

  20. Isotope hydrogeochemistry in exploration for buried and blind mineralisation

    Detection of concealed orebodies using the isotopic composition of Pb, S and Sr in groundwaters has been tested in several base metal exploration prospects in Australia Lead and S isotopes provide easily interpretable direct ore indicators, Pb isotopes provide a local target whereas S isotopes have application in regional target definition with isotopically-defined ore signatures recognisable for up to several kilometres from known mineralisation High 87Sr/86Sr ratios in groundwaters, apparently reflecting alteration related to mineralisation, also appear to provide a useful regional exploration tool

  1. Isotopic signature of Madeira basaltic magmatism

    Chemical composition of the basalts of Madeira Island is studied. To assess the isotopic sources of magmatism the Pb-Sr, Sm-Nd, U-Th-Pb systems were investigated in a number of basalts. It is shown that the island's rocks are characterized by the mostly deplet sources in relation to Pb-Sr and Sm-Nd systems (87Sr/86Sr - 0.70282-0.70292, 143Nd/144Nd - 0.52303-0.51314). Isotopic composition of lead testifies that the magmatism reservoir is some enriched. It is concluded that the magmatism of Madeira Island is a new example of world ocean island's volcanism

  2. Zircon U-Pb ages and Sr-Nd-Hf isotopes of the highly fractionated granite with tetrad REE patterns in the Shamai tungsten deposit in eastern Inner Mongolia, China: Implications for the timing of mineralization and ore genesis

    Jiang, Si-Hong; Bagas, Leon; Hu, Peng; Han, Ning; Chen, Chun-Liang; Liu, Yuan; Kang, Huan

    2016-09-01

    The Shamai tungsten deposit is located in the eastern part of the Central Asian Orogenic Belt (CAOB). Tungsten mineralization is closely related to the emplacement of fine- to medium-grained biotite monzogranite (G1) and porphyritic biotite monzogranite (G2) in the Shamai Granite. NW-trending joints and faults host orebodies in the Shamai Granite and Devonian hornfels. The mineralization is characterized by a basal veinlet zone progressing upwards to a thick vein zone followed by a mixed zone, a veinlet zone, and a thread vein zone at the top. The ore-related alteration typically consists of muscovite, greisen, and hornfels. In order to constrain the timing of the Shamai mineralization and discuss the ore genesis, muscovite Ar-Ar, molybdenite Re-Os, and zircon U-Pb geochronological, geochemical, and Sr-Nd-Hf isotopic studies were completed on the deposit. The U-Pb zircon dating yielded weighted mean ages of 153 ± 1 Ma for G1 and 146 ± 1 Ma for G2. Muscovite from a wolframite-bearing quartz vein yielded an Ar-Ar plateau age of 140 ± 1 Ma, whereas two molybdenite samples yielded identical Re-Os model ages of 137 ± 2 Ma. These two ages are younger than the two monzogranites, suggesting a prolonged magmatic-hydrothermal interaction during tungsten mineralization. Major and trace element geochemistry shows that both G1 and G2 are characterized by high SiO2 and K2O contents, high A/CNK values (1.08-1.40), a spectacular tetrad effect in their REE distribution patterns, and non-CHARAC (charge-and-radius-controlled) trace element behavior. This suggests that both G1 and G2 are highly differentiated peraluminous rocks with strong hydrothermal interaction. The Nd-Hf isotope data for the Shamai Granite (εNd(t) between - 1.9 and + 7.4, ɛHf(t) from 5.2 to 12.8) are largely compatible with the general scenario for much of the Phanerozoic granite emplaced in the CAOB. It is here suggested that the Shamai Granite originated from partial melting of a juvenile lower crust with

  3. 华北克拉通北缘东段海沟岩体的锆石U-Pb年龄、Sr-Nd-Hf同位素组成及其动力学背景%Zircon U-Pb ages and Sr-Nd-Hf isotopic composition of the Haigou granitoids at the northeastern margin of North China Craton: Implications for geodynamic setting

    张松; 王永彬; 褚少雄

    2012-01-01

    海沟岩体位于华北克拉通北缘东段,由二长岩和二长花岗岩组成.本文对该岩体主微量元素、Sr-Nd-Hf同位素和锆石的U-Pb年龄进行了系统研究.高精度锆石U-Pb年龄测试结果表明,二长岩和二长花岗岩形成的精确年龄分别为322.9±3.4Ma和320.3±3.5 Ma,为海西期构造-岩浆活动产物.海沟岩体为准铝质-弱过铝质的Ⅰ型花岗岩,其K2O/Na2O比值介于0.51 ~0.93之间,A/CNK介于0.87 ~0.94之间.微量元素方面表现为轻稀土富集、轻重稀土分馏明显、弱铕正异常、大离子亲石元素(如Rb、Ba、K)富集,以及高场强元素(如Nb、Ta、Ti、P)相对亏损等.锶同位素初始比值为(87Sr/86Sr)i=0.7054~0.7059,εNd(t)=- 10.4~ -8.6,亏损地幔的钕模式年龄分别介于1.84 ~ 1.99Ga和1.84~ 1.93Ga之间.二长岩和二长花岗岩锆石的εHf(t)变化范围分别为-7.6~ -0.8和-11.5~ -5.4,对应的两阶段Hf模式年龄分别为1.39 ~1.81Ga和1.67 ~2.06Ga.同位素特征表明两者可能来自中元古代和古元古代的下地壳物质的部分熔融,并可能有较多地幔物质的加入.根据其形成时代、岩石地球化学、同位素特征以及区域地质演化史,认为海沟岩体的形成可能与古生代古亚洲洋消减作用密切相关.%The Haigou granitoids, located in the northeastern margin of the North China Craton, consists of monzonite and monzogranite.. This study presents zircon U-Pb age, geochemical compositions and Sr-Nd-Hf isotopes of the Haigou granitoids, to discuss the origin and tectonic setting of the magmas. The zircon U-Pb dating for the monzonite and monzogranite yields 322. 9 ± 3. 4Ma and 320. 3 ±3. 5Ma respectively, indicating the magmas emplaced during the Hercynian Period. Petrochemical data indicate that they belong to calc-alkaline I-type granitoids with metaluminous affinity. They have similar geochemical features such as K2O/Na2O ratios being between 0. 51 and 0. 93 , A/CNK ranging from 0

  4. The applicability of an 87Sr/86Sr river isoscape to fish ecological questions in the Danube catchment

    Zitek, A.; Irrgeher, J.; Sailer, K.; Trautwein, C.; Waidbacher, H.; Prohaska, T.

    2012-04-01

    Isoscapes are spatial maps of the distribution of isotopes on Earth. As a basis for ecological studies such as long distance migrations of animals or for determining the origin of food these tools are increasingly being developed, until now - mainly for terrestrial systems. In contrast, in case of aquatic systems only few maps were established up to now. As far as variation in the isotopic distribution in a studied area exists, the isotopic composition bears the potential to be used as natural tracer e.g. for ecological questions or food authentication. Above all the 87Sr/86Sr ratio taken up from the environment by organisms without any significant fractionation is known to provide a direct link to geologically distinct regions. Within the 'IsoMark' project (www.isomark.at), a database ('Isoscape Austria') containing all available spatially explicit isotope data (terrestrial and aquatic) with a focus on isotope distributions in Austrian rivers is being developed. Water samples from different rivers, mainly along the Danube in Austria, were collected and analyzed for their elemental and Sr isotopic composition. Analyses of water samples yielded several 'Isozones' along the Austrian part of the Danube, indicating diverse geology in these river catchments. Studying migration phenomena of fish using natural isotopic marks in hard parts is especially possible between these 'Isozones'. In geologically similar regions with little differences, element distributions or artificial marking methods (tagging, spiking) can serve as additional means. A significant positive relationship between the 87Sr/86Sr ratio in river water and the proportion of siliceous geological formations in the catchment was found on a national and European level. These analyses proved the possibility to predict the 87Sr/86Sr ratios in river catchments all over Europe. This relationship allows for an estimation of the applicability of the 87Sr/86Sr ratio for fish ecological questions on a European scale

  5. Determination of the source of bioavailable Sr using ⁸⁷Sr/⁸⁶Sr tracers: a case study of hot pepper and rice.

    Song, Byeong-Yeol; Ryu, Jong-Sik; Shin, Hyung Seon; Lee, Kwang-Sik

    2014-09-24

    The geographical origin of agricultural products has been intensively studied, but links between agricultural products and the environments are poorly established. Soils, water (streamwater and groundwater), and plants (hot pepper, Capsicum annuum; and rice, Oryza sativa) were collected from all regions of South Korea and measured Sr isotope ratios ((87)Sr/(86)Sr). Sequential leaching of soil showed that Sr in the exchangeable and carbonate fractions (bioavailable) had a lower (87)Sr/(86)Sr ratio than that in the silicate fraction, consistent with a low (87)Sr/(86)Sr ratio in the plant. Although the bedrock-soil-water-plant system is closely linked, statistical analysis indicated that (87)Sr/(86)Sr ratios of the plant showed the greatest agreement with those of water and the exchangeable fraction of soil. This study is the first report of (87)Sr/(86)Sr isoscapes in South Korea and first demonstrates that the agricultural product is strongly linked with the exchangeable fraction of soil and water. PMID:25186083

  6. Isotopic geochemistry of calcretes

    Sr, C, O, U and Th isotopes have been studied in calcium carbonates accumulated in soils of semi-arid regions (calcretes). We have investigated 1) the role of in-situ weathering and climatic conditions in the genesis of calcretes from Central Spain (Toledo) and Atlantic Morocco (Sidi Ifni), 2) the origin of Ca, and 3) the age of these accumulations. Our results show that calcium carbonates replace the parent rock (granite) and preserve the bulk-volume. Sr isotopic data suggest that 90 % of Ca in the spanish calcretes is allochthonous and related to atmospheric input. O and C isotopic compositions of the carbonates are compatible with soil temperatures and respiration rates during the beginning of the summer season. U-series disequilibrium in the carbonates suggests ages ranging between 40 to 270 ky, commensurate with the climatic cycle. The Sr isotopic signatures of spanish and moroccan calcretes are similar to those of the Quaternary marine carbonates. Assuming that only Ca-rich aerosols have been the source for calcretes of the studied regions, we propose that the wide continental plateaus exposed during glacial periods (low sea level) provided a major part of the calcic input to the soils. Semi-arid conditions of Spain and Morocco allowed the percolation and precipitation in the soil profiles to form calcretes. (author)

  7. Volcano Pectusan: composition of rocks, chronology of eruption (K-Ar) and evolution (87Sr/86Sr and δ18O)

    Paper presents the results of the isotope study of the Pectusan volcano northeast and western slopes located at the North Korea and China boundary. Fresh data on the K-Ar-isotope geochronology, on the rock mass composition enabled to trace the stages and the cycles in the evolution of the mentioned volcano. On the basis of the isotope study (87Sr/86Sr and δ18O) data one analyzed some problems dealing with the genesis of the alkali-sialic rocks

  8. LA-ICP MS zircon dating, whole-rock and Sr-Nd-Pb-O isotope geochemistry of the Camiboğazı pluton, Eastern Pontides, NE Turkey: Implications for lithospheric mantle and lower crustal sources in arc-related I-type magmatism

    Kaygusuz, Abdullah; Arslan, Mehmet; Siebel, Wolfgang; Sipahi, Ferkan; İlbeyli, Nurdane; Temizel, İrfan

    2014-04-01

    Late Cretaceous I-type plutons are widespread in the Eastern Pontides, NE Turkey. The studied Camiboğazı pluton is a composite pluton consisting of diorite, tonalite, monzodiorite, monzonite, quartz monzonite, granite, and mafic microgranular enclaves (MMEs). Laser ablation ICP-MS U-Pb dating of zircon yielded crystallization ages of 76.21 ± 0.79 Ma, 75.65 ± 0.50 Ma, 75.04 ± 0.83 Ma, and 74.73 ± 0.86 Ma for diorite, monzodiorite, monzonite, and granite, respectively. The rocks of the pluton have I-type, high-K to shoshonitic and metaluminous character, displaying whole-rock geochemical features of arc-related granites. They are enriched in large-ion lithophile and light rare-earth elements, and depleted in high-field-strength elements. Major element variations can be attributed to fractionation of plagioclase, clinopyroxene, hornblende, and Fe-Ti oxides. The rocks show considerable variation in 87Sr/86Sr(i) (0.70498 to 0.70622), ɛNd(i) (- 2.79 to - 0.36), δ18O values (+ 6.3 to + 11.4) and Nd model ages (TDM) (0.81 Ga to 1.26 Ga). Besides, they have (206Pb/204Pb) = 18.44-19.09, (207Pb/204Pb) = 15.64-15.69, and (208Pb/204Pb) = 38.37-38.89. Although isotope signatures of the mafic microgranular enclaves (MMEs) (87Sr/86Sr(i) = 0.70551 to 0.70622; ɛNd(i) = - 2.9 to - 1.23; δ18O = + 8.3 to + 9.7) are largely similar to the host rocks, MMEs are characterized by relatively high Mg-numbers (32-36), low contents of SiO2 (52-56 wt.%) and low ASI (0.7-0.9). Estimated crystallization temperatures for the rocks of the pluton range from 735 ± 58 °C to 844 ± 24 °C and a shallow intrusion depth (< 10 km) is estimated from Al-in-hornblende thermobarometry. Whole-rock geochemical and isotopic data suggest magma generation by dehydration melting of an amphibolite-type lower crustal component with additional input of a subcontinental lithospheric mantle component. Furthermore, Sr-Nd isotope mixing model reveals ~ 30% to 40% lower crustal magma contribution to the mantle

  9. Geographical origin of Amazonian freshwater fishes fingerprinted by ⁸⁷Sr/⁸⁶Sr ratios on fish otoliths and scales.

    Pouilly, Marc; Point, David; Sondag, Francis; Henry, Manuel; Santos, Roberto V

    2014-08-19

    Calcified structures such as otoliths and scales grow continuously throughout the lifetime of fishes. The geochemical variations present in these biogenic structures are particularly relevant for studying fish migration and origin. In order to investigate the potential of the (87)Sr/(86)Sr ratio as a precise biogeochemical tag in Amazonian fishes, we compared this ratio between the water and fish otoliths and scales of two commercial fish species, Hoplias malabaricus and Schizodon fasciatus, from three major drainage basins of the Amazon: the Madeira, Solimões, and Tapajós rivers, displaying contrasted (87)Sr/(86)Sr ratios. A comparison of the (87)Sr/(86)Sr ratios between the otoliths and scales of the same individuals revealed similar values and were very close to the Sr isotopic composition of the local river where they were captured. This indicates, first, the absence of Sr isotopic fractionation during biological uptake and incorporation into calcified structures and, second, that scales may represent an interesting nonlethal alternative for (87)Sr/(86)Sr ratio measurements in comparison to otoliths. Considering the wide range of (87)Sr/(86)Sr variations that exist across Amazonian rivers, we used variations of (87)Sr/(86)Sr to discriminate fish origin at the basin level, as well as at the sub-basin level between the river and savannah lakes of the Beni River (Madeira basin). PMID:24971992

  10. Experimental autoabsorption curve 90Sr in SrCO3. Efficiency calculation to detection of 90Sr, 90Y and 90Sr + 90Y in a beta gas proportional counter

    Strontium-90 has been determined by radiochemical separation techniques in environmental samples. These techniques, of course, cannot separate the two strontium radionuclides from each other of from stable strontium. Consequently the end product of the chemical separation contains all strontium isotopes in SrCO3. The beta particules emitted by 90Sr are absorbed by the SrCO3 precipitate. This is the main source of error in the activity measurement. It has been prepared sources of 90Sr in SrCO3 in order to determinate the counting efficiency and autoabsorption curve. Also detection efficiencies have been calibrated using known activities of 90Y and equilibrium mixture of 90Sr+90Y in the same geometry than our samples. The activity of 90Sr by ingrowth of 90Y has been calculated by our computer program. (author). 2 figs., 3 refs

  11. Magnesium stable isotope ecology using mammal tooth enamel

    Martin, Jeremy E.; Vance, Derek; Balter, Vincent

    2015-01-01

    Geochemical inferences on ancient diet using bone and enamel apatite rely mainly on carbon isotope ratios (δ13C) and to a lesser extent on strontium/calcium (Sr/Ca) and barium/calcium (Ba/Ca) elemental ratios. Recent developments in nontraditional stable isotopes provide an unprecedented opportunity to use additional paleodietary proxies to disentangle complex diets such as omnivory. Of particular relevance for paleodietary reconstruction are metals present in large quantity in bone and enamel apatite, providing that biologically mediated fractionation processes are constrained. Calcium isotope ratios (δ44Ca) meet these criteria but exhibit complex ecological patterning. Stable magnesium isotope ratios (δ26Mg) also meet these criteria but a comprehensive understanding of its variability awaits new isotopic data. Here, 11 extant mammal species of known ecology from a single locality in equatorial Africa were sampled for tooth enamel and, together with vegetation and feces, analyzed for δ26Mg, δ13C, Sr/Ca, and Ba/Ca ratios. The results demonstrate that δ26Mg incorporated in tooth enamel becomes heavier from strict herbivores to omnivores/faunivores. Using data from experimentally raised sheep, we suggest that this 26Mg enrichment up the trophic chain is due to a 26Mg enrichment in muscle relative to bone. Notably, it is possible to distinguish omnivores from herbivores, using δ26Mg coupled to Ba/Ca ratios. The potential effects of metabolic and dietary changes on the enamel δ26Mg composition remain to be explored but, in the future, multiproxy approaches would permit a substantial refinement of dietary behaviors or enable accurate trophic reconstruction despite specimen-limited sampling, as is often the case for fossil assemblages.

  12. Magnesium stable isotope ecology using mammal tooth enamel.

    Martin, Jeremy E; Vance, Derek; Balter, Vincent

    2015-01-13

    Geochemical inferences on ancient diet using bone and enamel apatite rely mainly on carbon isotope ratios (δ(13)C) and to a lesser extent on strontium/calcium (Sr/Ca) and barium/calcium (Ba/Ca) elemental ratios. Recent developments in nontraditional stable isotopes provide an unprecedented opportunity to use additional paleodietary proxies to disentangle complex diets such as omnivory. Of particular relevance for paleodietary reconstruction are metals present in large quantity in bone and enamel apatite, providing that biologically mediated fractionation processes are constrained. Calcium isotope ratios (δ(44)Ca) meet these criteria but exhibit complex ecological patterning. Stable magnesium isotope ratios (δ(26)Mg) also meet these criteria but a comprehensive understanding of its variability awaits new isotopic data. Here, 11 extant mammal species of known ecology from a single locality in equatorial Africa were sampled for tooth enamel and, together with vegetation and feces, analyzed for δ(26)Mg, δ(13)C, Sr/Ca, and Ba/Ca ratios. The results demonstrate that δ(26)Mg incorporated in tooth enamel becomes heavier from strict herbivores to omnivores/faunivores. Using data from experimentally raised sheep, we suggest that this (26)Mg enrichment up the trophic chain is due to a (26)Mg enrichment in muscle relative to bone. Notably, it is possible to distinguish omnivores from herbivores, using δ(26)Mg coupled to Ba/Ca ratios. The potential effects of metabolic and dietary changes on the enamel δ(26)Mg composition remain to be explored but, in the future, multiproxy approaches would permit a substantial refinement of dietary behaviors or enable accurate trophic reconstruction despite specimen-limited sampling, as is often the case for fossil assemblages. PMID:25535375

  13. ID-TIMS 准确测定国际关键比对大米粉中痕量镉%Accurate Determination of Trace Amount of Cadmium in Rice for International Key Comparison by Isotope Dilution Thermal Ionization Mass Spectrometry

    王军; 赵墨田; 逯海

    2005-01-01

    The method of isotope dilution thermal ionization mass spectrometry able to trace to SI was developed to accurately measure trace amount of cadmium in the rice powder sample from CCQM-K24 international key comparison organized by CCQM(Comité Consultatif pour la Quantité de Matière, Paris). By comparison with our previous work, there was much improvement in aspects of digestion of the rice powder sample, separation of cadmium from the sample and dry-mass correction. As a result, the blank of this procedure was reduced and the measurement precisions of isotopic ratios of cadmium were increased. In addition, the uncertainty evaluation of the entire process of measurement was profoundly studied. The analytical result of this work (14.53±0.15) nmol/g was in agreement with the certified value.

  14. Geochemistry and Sr- Nd Isotopic Characteristics of the Carboniferous Volcanic Rocks from the Eastern Tianshan Suture Zone and Tectonic Implications%东天山板块缝合带石炭纪火山岩地球化学和Sr-Nd同位素特征及其大地构造意义

    曹锐; 木合塔尔·扎日; 陈斌; 李德威; 曹福根; 刘德民

    2012-01-01

    对东天山沿康古尔塔格缝合带分布的企鹅山群和梧桐窝子组火山岩的地球化学特征及Rb - Sr和Sm - Nd同位素进行了系统研究.结果显示:企鹅山群火山岩富集LREE,Eu异常变化较大(从明显负异常到微弱正异常),富集Sr、Ba和U等大离子亲石元素,相对亏损Nb、Zr、Ti等高场强元素,Sr - Nd同位素特征是Isr=0.703 97~0.704 26,εNd (t) =5.61~6.99,具有亏损地幔性质,表明其岩浆源区可能来自古生代期间被古亚洲洋俯冲板片释放的流体/熔体交代过的岩石圈地幔楔;梧桐窝子组玄武岩富集轻稀土元素(LREE)和大离子亲石元素,而高场强元素没有明显负异常,样品的εNd值都在9以上,Isr (330 Ma)为0.704 71~0.705 33,表明梧桐窝子组玄武岩可能来自亏损的软流圈地幔的部分熔融.企鹅山群和梧桐窝子组火山岩在Zr - Zr/Y判别图解中分别落在岛弧拉斑玄武岩(IAB)和板内玄武岩(WPB)范围内,表明企鹅山群可能为准噶尔洋盆向南俯冲形成的石炭纪岛弧火山岩,而梧桐窝子组火山岩可能形成于在弧后盆地的基础上拉张为裂陷槽的伸展环境.%Geochemistry, Rb - Sr and Sm - Nd isotopic compositions of the volcanic rocks, from the Qi'eshan Group and Wutongwozi Formation in the eastern Tianshan plate suture zone have been studied in this paper. The basalt from the Qi' eshan Group is highly enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) such as Sr, Ba and U, and depleted in high field strength elements (Nb, Ti and Zr) , with variable Eu anomalies (varying from significant negative Eu anomalies to minor positive Eu anomalies) in the chondrite-normalized REE patterns. It is charactered by isotopic signatures of depleted mantle source, with εNd(t) = 5. 61 -6. 99, and Isr(330 Ma)=0. 703 97 -0. 704 26. All these geochemical characteristics suggest that the basalt in Qi'eshan Group probably was derived from the lithospheric

  15. Strontium isotope data for recent andesites in Ecuador and North Chile

    New Sr isotope data are presented for andesite lavas from active volcanoes in Ecuador and North Chile. Twenty-three samples from five Ecuadorian volcanoes have 87Sr/86Sr ratios most of which are essentially within analytical error, and average 0.7044. In contrast, 16 samples from the San Pedro-San Pablo volcano complex in North Chile have 87Sr/86Sr ratios between 0.7058 and 0.7072. These samples show no correlation between 87Sr/86Sr and 87Rb/86Sr, nor between 87Sr/86Sr and other elements or ratios. The major difference in setting between the two volcanic provinces lies in the thickness of the continental crust; 40-50 km beneath Ecuador, 70 km beneath North Chile. Andesites from both areas are derived primarily from the mantle, but those from North Chile show evidence of a significant Sr isotopic contribution from the continental crust. (Auth.)

  16. 远源地下水入侵阿拉善高原沙漠:酸溶物 Sr 同位素证据%Invasion of Remote Groundwater into Deserts on the Alxa Plateau:Acid Soluble Sr Isotopic Evidence

    潘耀东; 饶文波; 王啸

    2014-01-01

    选取北方西-东向气候剖面上物质组成相似的4个沙漠(塔克拉玛干、巴丹吉林、腾格里和毛乌素),测定其地表沙酸溶物87 Sr/86 Sr 比值(质量之比)及 Ca2+和 Sr2+质量比.结果表明,Ca2+和 Sr2+质量比相关性极好,在降雨量低的塔克拉玛干沙漠中最高,向东逐渐降低,在降雨量多的毛乌素沙漠中最低.降雨量是控制阳离子浓度变化的主导因素.酸溶物87 Sr/86 Sr 比值在4个沙漠中有不同于阳离子变化的区域特征.酸溶物87 Sr/86 Sr 比值在塔克拉玛干沙漠中低于0.7100,在巴丹吉林和腾格里沙漠中大于0.7112,而在毛乌素沙漠中介于0.7100~0.7112之间.塔克拉玛干和毛乌素沙漠地表沙酸溶物87 Sr/8