KoreaScience (Korea)

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UK PubMed Central (United Kingdom)

Rationale: Ventilator-induced lung injury (VILI) leads to an unacceptably high mortality. In this regard, the antiinflammatory properties of inhaled carbon monoxide (CO) may provide...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Methylene chloride is an organic solvent with many industrial uses. Inhalation of methylene chloride fumes can result in toxicity, caused by hepatic biotransformation of methylene chloride to carbon monoxide. A case of acute methylene chloride poisoning is presented, including successful treatment of this patient with the use of hyperbaric oxygenation. The rationale for the use of hyperbaric oxygenation in the treatment of methylene chloride poisoning is discussed. (aw)

Wastenet

...contributions from the following fields: Catalytic elimination of environmental pollutants, such as nitrogen oxides, carbon monoxide, sulfur compounds, chlorinated and other organic compounds, ...contributions from the following fields: Catalytic elimination of environmental pollutants, such as nitrogen oxides, carbon monoxide, sulfur compounds, chlorinated and other organic compounds, ...

Energy Technology Data Exchange (ETDEWEB)

Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.

Wastenet

Emissions and residues: Emissions may include, inter alia, nitrogen oxides, carbon monoxide, sulphur dioxide and other oxides

Energy Technology Data Exchange (ETDEWEB)

French scientists think they have discovered one of the key steps in the methanol-to-gasoline reaction pathway and their British counterparts have learned a new way of converting methanol into acetic acid without carbon monoxide.

UK PubMed Central (United Kingdom)

A rebreathing method was developed for measuring diffusing lung capacity for carbon monoxide (DLCO) in a hyperbaric environment. Twenty two professional naval divers with normal lung function were included...Full Text Available

Science.gov (United States)

Coke consumption may be cut as much as fifty percent using a coal reactor to furnish carbon monoxide for ore reduction in a blast furnace while lowering the sulfur content of pig iron accompanied by a smaller slag volume.

Energy Technology Data Exchange (ETDEWEB)

The production of and emission factors for the air-polluting matters sulfur dioxide, nitrogen oxides, carbon monoxide, hydrocarbons (esp. benz(a)pyrene), aldehyde and soot with regard to natural gas, excluding process furnaces, are dealt with. The comparison with other fuels indicates that only as to nitrogen oxides and carbon monoxide are emission factors equal in order of magnitude. As a summary measure of all air-polluting matters the emission index as proposed already in 1972 is applied. It shows emissions with single-room furnaces for heating oil EL to be six times as high as with natural gas; with black-coal briquettes the factor is at least 33, with wood chimneys about 200.

International Nuclear Information System (INIS)

The consequences of converting a facility from brown coal fuel to gas fuel were analyzed by model simulation. Treated were a district heating plant with an output of 700 TJ/yr and minor local heating sources (stoves) at a density of 1 family house per 100 m"2. Emissions of particulate matter, sulfur dioxide, nitrogen oxides, carbon monoxide, and hydrocarbons before and after the conversion are given for the two types of source. Conversion of a major air pollution source to gas fuel would result in a reduction of the contribution of sulfur dioxide emissions of the order of 10"-"4, of particulate matter and carbon monoxide of the order of 10"-"3, and of hydrocarbons of the order of 10"-"2. The decrease will be lowest for nitrogen oxides, viz. about 40%. Analogous data for local heating sources in towns would be 10"-"5 for sulfur dioxide, 10"-"4 for particulate matter, 10"-"3 for ...

Energy Technology Data Exchange (ETDEWEB)

Six different groups of non-smoking young male subjects were studied separately for 18 consecutive days each in a closed controlled-environmental human exposure chamber. Each group was subjected to a 5-day control period in fresh air followed successively by an 8-day period of continuous exposure to 50 ppm, 15 ppm or 0 ppm (control) by volume of carbon monoxide (CO) in air, and a 5-day recovery period in fresh air. The subjects performed a 1-h auditory vigilance task every day at the same time of day in a fixed qualitative, quantitative, and temporal relationship with food intake, consumption of stimulating beverages, physical activity, and sleep. It was concluded that such CO exposure, involving the continuous carriage of carboxyhaemoglobin loads up to 7%, was without significant effect on auditory vigilance.

International Nuclear Information System (INIS)

Carbon monoxide can be produced in severe accidents from interaction of ex-vessel molten core with concrete. Depending on the particular core-melt scenario, the type of concrete and geometric factors affecting the interaction, the quantities of carbon monoxide produced can vary widely, up to several volume percent in the containment. Carbon monoxide is a combustible gas. The carbon monoxide thus produced is in addition to the hydrogen produced by metal-water reactions and by radiolysis, and represents a possibly significant contribution to the combustible gas inventory in the containment. Assessment of possible accident loads to containment thus requires knowledge of the combustion properties of both CO and H_2 in the containment atmosphere. Extensive studies have been carried out and are still continuing in the nuclear ...

Energy Technology Data Exchange (ETDEWEB)

This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

International Nuclear Information System (INIS)

This paper presents a brief overview of refuse derived fuel (RDF) processing systems, and the different types of RDF. The quality of RDF, combustion of RDF in fluidized beds, and moving grate reactors, operating conditions, emissions (sulphur dioxide, nitrogen oxides, carbon monoxide and hydrogen chloride) and thermal efficiency are discussed. (UK).

International Nuclear Information System (INIS)

Pollutant emissions due to fossil fuel and biomass energy utilization in Turkey have been estimated. Standard emission factors were used for estimating the levels of particulate matter, sulfur oxides, nitrogen oxides, carbon monoxide, volatile organic compounds, and aldehydes. The results are presented for different fuels and energy-consuming sectors for the reference year 1987. Total Turkish emissions vs energy consumption are presented for every fifth year since. 1960. (author).

Energy Technology Data Exchange (ETDEWEB)

Green River oil shale was air oxidized at subretorting temperatures. Off gases consisting of nitrogen, oxygen, carbon monoxide, carbon dioxide, and water were monitored and quantitatively determined. A mathematical model of the oxidation reactions based on a shrinking core model has been developed. This model incorporates the chemical reaction of oxygen and the organic material in the oil shale as well as the diffusivity of the oxygen into the shale particle. Diffusivity appears to be rate limiting for the oxidation. Arrhenius type equations, which include a term for oil shale grade, have been derived for both the chemical reaction and the diffusivity.

Energy Technology Data Exchange (ETDEWEB)

This report presents estimates of the annual anthropogenic UK emissions of greenhouse gases for the years 1990-93 for submission under the Framework Convention on Climate Change. The gases considered are carbon dioxide, methane, nitrous oxide, nitrogen oxides, carbon monoxide and non-methane volatile organic compounds. Emissions of all the gases have declined since 1990. In particular, those of carbon dioxide have fallen by 4%; those of methane by 8% and those of nitrous oxide by 28%. Emission estimates are reported in the IPCC Standard Tables format disaggregated by source category and fuel. The methodology used for the estimates and how they relate to the UK National Atmospheric Emissions Inventory is discussed in an appendix. (author)

Energy Technology Data Exchange (ETDEWEB)

Carbon monoxide, H{sub 2}, and CO{sub 2} in synthesis gas can be converted to CH{sub 4} by employing a triculture of Rhodospirillum rubrum, Methanosarcina barkeri, and Methanobacterium formicicum. Trickle-bed reactors have been found to be effective for this conversion because of their high mass-transfer coefficients. This paper compares results obtained for the conversion of synthesis gas to CH{sub 4} in 5-cm- and 16.5-cm-diameter trickle-bed reactors. Mass-transfer and scale-up parameters are defined, and light requirements for R. rubrum are considered in bioreactor design.

Science.gov (United States)

Using low-temperature adsorbed dihydrogen and carbon monoxide as molecular probes, the dehydroxylation of the hydrogen forms of the zeolites Y, and ZSM-5 has been studied. The high stability of the high-silica zeolites to dealumination and their difference from faujasites has been established as being due not only to the strength of their Broensted acid sites but also to the nature of their Lewis acid sites. The chemical properties of the Lewis acid sites and their possible role in catalytic reactions are discussed.

International Nuclear Information System (INIS)

The production of atmospheric pollutants in combustion processes depends on plant characteristic, combustion conditions and fuel quality. The influence of fuel quality on the emission of sulphur oxides, nitrogen oxides, carbon monoxide, dust and carbon dioxide and on the emission of some toxic pollutants, such as heavy metals and polycyclic aromatic hydrocarbons, is analysed. The comparison between the emission limits, fixed by the Italian legislation, and the uncontrolled pollutant emissions, produced by fossil fuel combustion in power plants and industrial use, shows that, in order to comply with the limits, a reduction of pollutant emissions is required through the use of abatement systems and cleaner fuels where natural gas has a primary role. The use of cleaner fuels is particularly required in heating plants and appliances for the residential sector, where the development of new gas technologies further increases the ...

British Library Electronic Table of Contents (United Kingdom)

Carbon monoxide (CO) and carbon dioxide (CO2) emissions during a spontaneous heating event in a coal mine are important gases to monitor for detecting the spontaneous heating at an early stage. However, in underground coal mines, the CO and CO2 concentrations and their related fire ratios may be affected by mine ventilation. In this study, CO and CO2 emissions from spontaneous heating of a U.S. coal sample were evaluated in an isothermal oven under different airflow ventilation rates ranging from 100 to 500cm^3/min. Laboratory experiments were conducted at oven temperatures of 70, 90, and 100^oC. The temperature at the center of the coal sample was continually monitored, while the CO, CO2, and oxygen (O2) concentrations of the exit gas were continually measured. The results indicate that C...

Energy Technology Data Exchange (ETDEWEB)

Issues regarding the development of mechanisms to reduce greenhouse gas emissions in the electricity sector are discussed. Environmental groups have proposed mechanisms such as carbon taxes. Three other mechanisms have also been proposed under the Framework Convention on Climate Change (FCCC). These include the Clean Development Mechanism, Joint Implementation and carbon trading. A pilot emission reduction trading project began in Ontario in 1996 as an initiative to control smog and ozone in the southern provincial airshed. Substances of interest include NO{sub x}, volatile organic compounds (VOCs), SO{sub x}, carbon monoxide and other greenhouse gases. Ontario Hydro alone has conducted 10 trades, five with companies in the U.S., two of those for carbon emissions. An analysis of the pilot trade deals will provide an idea of the value of this mechanism. In addition to details of the ...

Energy Technology Data Exchange (ETDEWEB)

Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as committed carbon,'' or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, ...

International Nuclear Information System (INIS)

CT is the most accurate method to detect pulmonary emphysema in vivo. They compared prospectively two different methods for emphysema quantitation in 5 normal volunteers and 20 consecutive patients with chronic obstructive pulmonary disease (COPD). All subjects were submitted to function tests and HRCT; three scans were acquired at preselected levels during inspiration. The type and extent of pulmonary emphysema were defined by two independent observers under blind conditions. Disagreements were subsequently settled by consent. All subjects were also examined with expiratory spiral CT using a density mask program, at two different cut-off levels (-850,-900 HU). Visual score and expiratory spiral density mask values (-850 HU) were significantly correlated (r = 0.86), but the visual extent of emphysema was always higher than shown by expiratory spiral CT. The emphysema extent assessed with both CT methods correlated with the function result of expiratory airflow obstruction and gas ...

Energy Technology Data Exchange (ETDEWEB)

Modern combined cycle power plants with natural gas as the only fuel reach efficiencies of up to 55% for electric power generation. Nevertheless the reserve of natural gas is more limited compared to the reserve of coal. Therefore possibilities should be investigated to use coal for such plants also. One concept, that combines the use of coal in a combined cycle application with high efficiencies is examined in this paper. According to this concept the exhaust gas of the gas turbine (vitiated air) is the combustion air for the pulverized coal combustion, that takes place in the bottoming steam generator. Due to the low oxygen content of the vitiated air the burnout of the coal may be incomplete. In order to avoid the incomplete combustion of the coal and the resulting decrease of the efficiency of the plant and possible emission problems, a catalyst, that converts carbon monoxide and unburnt carbon to ...

International Nuclear Information System (INIS)

The future use of single-molecule magnets in applications will require the ability to control and manipulate the spin state and magnetization of the magnets by external means. There are different approaches to this control, one being the modification of the magnets by adsorption of small ligand molecules. In this paper we use iron phthalocyanine supported by an Au(111) surface as a model compound and demonstrate, using x-ray photoelectron spectroscopy and density functional theory, that the spin state of the molecule can be tuned to different values (S #approx# 0, 1/2, 1) by adsorption of ammonia, pyridine, carbon monoxide or nitric oxide on the iron ion. The interaction also leads to electronic decoupling of the iron phthalocyanine from the Au(111) support. (fast track communication)

Energy Technology Data Exchange (ETDEWEB)

The main pollutants from marine diesel engines are oxides of nitrogen (NOx), sulfur oxides (SOx) and particulates (soot). However, the proposed marine diesel engine emission regulations will primarily focus on the levels of NOx and SOx. In the future, once the proposed regulations are met, the limits and levels of other emissions will come under increasing scrutiny, such as particulates, hydrocarbons and carbon monoxide. Regardless of the type of pollutant, there are generally two classes of emission control: (1) techniques that reduce the amount of pollutant formed in the combustion process, or (2) prevent the pollutants from reaching the atmosphere. Unfortunately, some of these control techniques will not be able to meet the incoming regulations. Therefore, this paper identifies the diesel engine emissions of concern, the impending regulations, and the merits of current and future emission control technologies required to meet these ...

Energy Technology Data Exchange (ETDEWEB)

Tests to measure the maximum horsepower of commercial vehicles converted for use with natural gas fuel indicate a reduction of approximately 20% in horsepower compared with gasoline-driven vehicles. This reduction in horsepower resulting from the use of gas is due basically to the lower thermal efficiency of the cycle of natural gas compared with that of gasoline and to its lower volumetric efficiency, since natural gas is injected into the combustion chamber in gaseous form, unlike gasoline, in which part of the fuel entering the cylinder is in the liquid phase. Natural gas used as a fuel generates lower quantities of air pollutants, particularly unburned hydrocarbons (HCs) and carbon monoxide (CO). Despite the downside of reduced horsepower, the use of natural gas as a fuel for automotive vehicles equipped with Otto-cycle engines is economically viable owing to the wide availability of natural gas. 34 refs., 5 figs., 2 tabs.

Energy Technology Data Exchange (ETDEWEB)

The structure and catalytic properties of 2 wt.-% Pd/SiO/sub 2/ catalysts promoted with 2 wt.-% MgO and 0.2-5 wt.-% iron have been investigated. Catalysts were characterized by TPR, hydrogen chemisorption, and Moessbauer spectroscopy and their catalytic performance in methanol formation was also measured. At 16 at.-% iron a sharp maximum was observed in the activity which can be interpreted as being due to simultaneous promotion with iron and MgO. Independent mechanisms of promotion were found for the two modifiers: iron influenced the metallic component by forming bimetallic PdFe particles while MgO changed the properties of silica in a favourable way. 6 figs., 29 refs., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

A multi-zone computational model in conjunction with some engine tests are used to examine the combustion process of gas fueled diesel engines common known as dual fuel engine to provide information about details of the production of exhaust emissions, especially at light load when very lean mixtures are employed. Detailed chemical reaction kinetic simulation is employed for each of these individual combustion zones so as to establish the associated temporal variations in the concentrations of reacting species right to the exhaust stage. The influence of changes in major operating and design parameters such as the concentration of the gaseous fuel in the cylinder charge, intake temperature and the size of the diesel pilot fuel employed on the production of the exhaust emissions are examined. It is demonstrated in general that any measure that tends to increase the size of the combustion regions within the overly lean cylinder charge will reduce markedly the concentrations of the ...

Energy Technology Data Exchange (ETDEWEB)

The report presents details of the distributions of air pollution in the Berlin area and the developments of the past 20 years. Highly polluted areas are indicated in which air pollution reduction measures are particularly urgent. The report therefore intends not only to inform but also to point out the deficiencies of air pollution abatement measures, so that political consequences can be derived and measures can be taken. In all, data were recorded by 39 measuring stations in West Berlin, 16 in East Berlin, and 7 in Potsdam and Frankfurt/Oder. In most stations, sulphur dioxide and airborne dust were measured; 14 stations in West Berlin and one in East Berlin measured carbon monoxide and nitric oxides; 8 stations in West Berlin recorded ozone concentrations. (orig./KW).

Science.gov (United States)

In the Advance Coal Liquefaction Concept Proposal (ACLCP) carbon monoxide (CO) and water have been proposed as the primary reagents in the pretreatment process. The main objective of this project is to develop a methodology for pretreating coal under mild conditions based on a combination of existing processes which have shown great promise in liquefaction, extraction and pyrolysis studies. The aim of this pretreatment process is to partially depolymerise the coal, eliminate oxygen and diminish the propensity for retograde reactions during subsequent liquefaction. The desirable outcome of the CO pretreatment step should be: (1) enhanced liquefaction activity and/or selectivity toward products of higher quality due to chemical modification of the coal structure; (2) cleaner downstream products; (3) overall improvement in operability and process economics.

Energy Technology Data Exchange (ETDEWEB)

There is a need to reduce air pollutant emissions in some U.S. urban regions to meet federal and state air quality guidelines. Opportunities exist for reducing pollutant emissions from natural gas appliances in the residential sector. A cost-benefit analysis on various pollutant-reducing strategies is needed to evaluate these opportunities. The effectiveness of these pollutant-reducing strategies (e.g., low-emission burners, energy conservation) can then be ranked among themselves and compared with other pollutant-reducing strategies available for the region. A key step towards conducting a cost-benefit analysis is to collect information on pollutant emissions from existing residential natural gas appliances. An extensive literature search was conducted to collect data on residential natural-gas-appliance pollutant emission factors. The literature primarily describes laboratory tests and may not reflect actual emission factor distributions in the field. Pollutant emission factors for ...

International Nuclear Information System (INIS)

The influence of carbon monoxide (CO) exposure on regional cerebral blood flow (r-CBF) in rat brain was studied using autoradiography and "1"2"5I-IMP. Fuji computed radiography (FCR) was used to obtain improved autoradiograms in this study. R-CBF was determined in a relative measure by calculating hippocampus/cortex and putamen/cortex ratios of RI accumulation from the autoradiogram using a densitometer. Comparison of autoradiograms with pathological findings in the area of the hippocampus and putamen yield the following results. In the animals that were exposed to 6400 ppm or 10000 ppm of CO for 30 minutes, and then were followed up for 2 weeks without further exposure, r-CBF was decreased but no pathological changes occurred. In the animals that were exposed to 6400 ppm or 10000 ppm of CO, and then were followed up for 4 weeks without further exposure, pathological changes appeared. In animals exposed to 3200 ppm of CO, the r-CBF tended to ...

Energy Technology Data Exchange (ETDEWEB)

Alkaline promoted active carbon supported iron catalysts are very active in the oxidative dehydrogenation of ethylbenzene to styrene in the presence of carbon dioxide. The best results were obtained at 550 C for a Li-promoted catalyst with a conversion of ethylbenzene of 75% and a selectivity towards styrene of nearly 95%. These results are better than those obtained with industrial catalysts which perform the dehydrogenation process with an excess of water. The main product of the dehydrogenation reaction with CO{sub 2} was styrene, but the following by-products were detected - benzene and toluene. The selectivity towards toluene was always higher than towards benzene. We observed also the formation of carbon monoxide and water, which were produced with a constant molar ratio of about 0.8. The weight of the catalysts increased up to 20% during the reaction due to deposition of ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the sampling and chemical analyses of smoke gas components for combustion performed in the SP Industry Calorimeter, where continuous measurements of oxygen, carbon dioxide and carbon monoxide are an integrated part of the Calorimeter system. On-line measurements of nitrogen oxides and total amounts of unburnt hydrocarbons were performed. Hydrogen cyanide, hydrogen chloride and ammonia in the smoke were sampled and absorbed in impinger bottles and subsequently analyzed using wet chemical techniques. An adsorbent sampling system was designed to allow the identification and quantitative analysis of individual organic compounds in the smoke. Gas chromatography was utilized with a mass spectrometric detector for the identification and a FID for quantification of the total amounts as well as individual components. A procedure for cleaning the smoke gas duct in between the combustion experiments was designed ...

International Nuclear Information System (INIS)

A laminated material composed of glass cloth/polyimide film/epoxy resin will be used as an insulating material for superconducting coil of International Thermonuclear Experimental Reactor (ITER). In order to keep safe and stable operation of the superconducting coil system, it is indispensable to evaluate radiation resistance of the material, because the material is exposed to severe environments such as high radiation field and low temperature of 4 K. Especially, it is important to estimate the amount of gases evolved from the insulating material by irradiation, because the gases affect on the purifying system of liquid helium in the superconducting coil system. In this work, the gas evolution from the laminated material by gamma ray irradiation at liquid nitrogen temperature (77 K) was investigated, and the difference of gas evolution behavior due to difference of composition in the epoxy resin was discussed. It was found that the main gases evolved from the laminated material by the ...

International Nuclear Information System (INIS)

The DOE is conducting a comprehensive technical analysis of a flexible-fuel transportation system in the United States -- that is, a system that could easily switch between petroleum and another fuel, depending on price and availability. The DOE Alternative Fuels Assessment is aimed directly at questions of energy security and fuel availability, but covers a wide range of issues. This report examines environmental, health, and safety concerns associated with a switch to alternative- and flexible-fuel vehicles. Three potential alternatives to oil-based fuels in the transportation sector are considered: methanol, compressed natural gas (CNG), and electricity. The objective is to describe and discuss qualitatively potential environmental, health, and safety issues that would accompany widespread use of these three fuels. This report presents the results of exhaustive literature reviews; discussions with specialists in the vehicular and fuel-production industries and with Federal, State, ...

Energy Technology Data Exchange (ETDEWEB)

The reaction of uranium oxides and chlorine to prepare anhydrous uranium tetrachloride (UCl{sub 4}) are important to more economical preparation of uranium metal. The most practical reactions require carbon or carbon monoxide (CO) to give CO or carbon dioxide (CO{sub 2}) as waste gases. The chemistry of U-O-Cl compounds is very complex with valances of 3, 4, 5, and 6 and with stable oxychlorides. Literature was reviewed to collect thermochemical data, phase equilibrium information, and results of experimental studies. Calculations using thermodynamic data can identify the probable reactions, but the results are uncertain. All the U-O-Cl compounds have large free energies of formation and the calculations give uncertain small differences of large numbers. The phase diagram for UCl{sub 4}-UO{sub 2} shows a reaction to form uranium oxychloride (UOCl{sub 2}) that has a good solubility in molten UCl{sub 4}. ...

Energy Technology Data Exchange (ETDEWEB)

Hydrogenation of carbon monoxide at 101.3 kPa has been studied over a series of ion-exchanged Ru catalysts supported on NaX, NaY, KL, Na mordenite, and HY zeolites. The type of zeolite had pronounced effects on the activity and selectivity of the Ru. The specific activity would appear to be related to the dispersion of reduced ruthenium in the zeolite. Methane selectivity, however, seems to be strongly influenced by the type and concentration of alkali cations remaining in the ion-exchanged zeolite. These cations appear to promote chain growth much as traditional alkali promoters would, though perhaps more indirectly. Due to bifunctional properties of the zeolite-supported catalysts, a significant fraction of C/sub 4/ was in the form of isobutane. Formation of isobutane seems to be related to either the Si/Al ratio in the zeolites or the concentration of the remaining alkali cations, but not to the OH concentration. In addition, H/sub 2/ ...

Energy Technology Data Exchange (ETDEWEB)

Tests with a 61 cm diameter fluidized-bed combustor revealed that raw cotton gin trash could be efficiently burned while satisfying Federal standards for particulate emissions. Certain chemicals within cotton gin trash zone can cause slagging or caking of ash and bed particles in the combustion zone. They can also corrode and accumulate on the heat recovery equipment. These problems are not considered insurmountable and methods of control are being studied. Raw cotton gin trash was also converted into a low Btu gas using fluidized-bed technology. Tests with a 30 cm diameter gasifier revealed that raw gin trash could be converted to a combustible gas, containing carbon monoxide and hydrogen. The heating value of the gas ranged from 3.65 to 5.29 MJ/m3 and about 50 percent of the heat value of the raw trash was converted to combustible gases. Economic analyses have shown that these techniques can be economically competitive with present fuels in ...

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia ...

Energy Technology Data Exchange (ETDEWEB)

Diesel engines operating on gaseous fuels are commonly known as dual-fuel engines. In the present work, a single-cylinder, compression ignition, indirect injection research (Ricardo E6) engine has been installed at United Arab Emirates University for investigation of the exhaust emissions when the engine is operating as a dual-fuel engine. The influence of changes in major operating and design parameters, such as the concentration of gaseous fuel in the cylinder charge, pilot fuel quantity, injection timing and intake temperature, on the production of exhaust emissions was investigated. Diesel fuel was used as the pilot fuel, while methane or propane was used as the main fuel which was inducted in the intake manifold and mixed with the intake air. The experimental investigations showed that the poor emissions at light loads can be improved significantly by increasing the concentration of gaseous fuel (total equivalence ratio), employing a large pilot fuel quantity, advancing the ...

Energy Technology Data Exchange (ETDEWEB)

Until now the assumption has been that synthesis gas - mixtures of carbon monoxide and hydrogen - would be the principal source for many of the chemicals and fuels to be made via C/sub 1/ chemistry. Efforts to make cheap synthesis gas continue. But the pressure to circumvent the stranglehold that OPEC has on petroleum has caused other avenues to be explored. The current oversupply of natural gas offers an interim solution to the problem of nonpetroleum alternate source materials for C/sub 1/ chemicals production. The paper discusses the constraints and advantages of four processes: conventional steam reforming, steam reforming with oxygen secondary, partial oxidation, and catalytic partial oxidation. The end product in all cases is methanol. Direct use of methanol as a fuel has encountered numerous difficulties. conversion of methanol is, thus, of more immediate interest in C/sub 1/ chemistry. The Mobil MTG process and its second-generation ...

Science.gov (United States)

The effect of hydrogen sulfide (H2S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxidesssuch as iron oxide, nickel oxide, manganese oxide, and copper oxideswas investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H2S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H2S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H2S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation ...

Energy Technology Data Exchange (ETDEWEB)

The EPA proposed air emission guidelines for existing Municipal Waste Combustion (MWC) facilities on December 20, 1989. The regulation, 40 CFR Subpart Ca, was eventually issued on February 11, 1991, but Section 129 of the Clean Air Act Amendments of 1990 required the EPA to review and revise the regulations. On October 31, 1995, Subpart Ca was withdrawn and replaced by a more stringent regulation, 40 CFR Subpart Cb. The new guidelines apply to all existing MWC facilities for which construction began before September 20, 1994 and have a capacity to combust over 35 megagrams per day. Most facilities will be required to be in compliance with the new regulations four years from the date Subpart Cb was issued, or by December 19, 1999. Subpart Cb requires significant capital expenditures and increases in operating costs. The major modifications EPA based the guidelines on are summarized. Pollutants of concern include sulfur dioxide, hydrochloric acid, dioxin/furans, metals, particulates, ...

Energy Technology Data Exchange (ETDEWEB)

Catalytic combustion has demonstrated the ability to provide low NO /SUB x/ emissions while maintainin high combustion efficiency. Recently, under joint NASA Lewis, EPA, and Acurex sponsorship, a catalytic reactor was tested for 1000 hours to demonstrate durability in combustion environments representative of advanced automotive gas turbine engines. At a 740K air preheat temperature and a propane fuel/air ratio of 0.028 by mass (/phi/FA = 0.44), the adiabatic flame temperature was held at about 1700K. The graded cell monolithic reactor measured 5 cm in diameter by 10.2 cm in length and was operated at a reference velocity of 13.4 m/s at 1 atmosphere pressure Measured NO /SUB x/ levels remained below 5 ppm while unburned hydrocarbon concentrations registered near zero and carbon monoxide levels were nominally below 20 ppm. The durability test included several parametric turndown studies and ended with a series of on/off cycling tests to further ...

International Nuclear Information System (INIS)

This study was undertaken to collect emissions performance data for Canadian and comparable American refineries. The objective was to examine parameters that affect refinery air emissions performance and develop methods or correlations to normalize emissions performance. Another objective was to correlate and compare the performance of Canadian refineries to comparable American refineries. For the purpose of this study, benchmarking involved the determination of levels of emission performance that are being achieved for generic groups of facilities. A total of 20 facilities were included in the benchmarking analysis, and 74 American refinery emission correlations were developed. The recommended benchmarks, and the application of those correlations for comparison between Canadian and American refinery performance, were discussed. The benchmarks were: sulfur oxides, nitrogen oxides, carbon monoxide, particulate, volatile organic compounds, ...

Science.gov (United States)

Maternal exposure to ambient air pollution has increasingly been linked to adverse pregnancy outcomes. The evidence linking this exposure to congenital anomalies is still limited and controversial. This case-control study investigated the association between maternal exposure to ambient particulate matter with aerodynamic diameter less than 10 ?m (PM(10)), sulfur dioxide (SO(2)), nitrogen dioxide, nitric oxide (NO), ozone (O(3)), and carbon monoxide (CO) and the occurrence of congenital heart disease in the population of Northeast England (1993-2003). Each case and control was assigned weekly average (weeks 3-8 of pregnancy) of pollutant levels measured by the closest monitor to the mother's residential postcode. Using exposure as both continuous and categorical variables, logistic regression models were constructed to quantify the adjusted odds ratios of exposure to air pollutants and the occurrence of each outcome group. We found exposure to ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared

Energy Technology Data Exchange (ETDEWEB)

The ingestion pathway consequences following an accidental tritium release from the Savannah River Site Tritium Facilities are evaluated.

UK PubMed Central (United Kingdom)

Hydrogen peroxide is a commonly used oxidizing agent with a variety of uses depending on its concentration. Ingestion of hydrogen peroxide is not an uncommon source of poisoning, and results in morbidity...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Physico-chemical characterizations performed on samples of 100Cr6 steel implanted both with boron and nitrogen revealed the formation of boron nitride along with the following new phases: Fe{sub 1-x}(B, N), Fe{sub 2-x}(B, N) and Fe{sub 3-x}(B, N). A thorough analysis of boron NITRIDE (5BN) indicates that a low ion current density (3 {mu}A.cm{sup -2}) in the case of the boron plus nitrogen sequence favours the formation of sp{sup 2} bonds (hexagonal-BN) while a higher ion current density (6{mu}A.cm{sup -2}) promotes sp{sup 3} bonds (cubic-BN) in the opposite sequence. Tribological tests carried out on these samples revealed that nitrogen and boron implantations do not lead to any significant improvement of friction and wear at variance with the results obtained by others authors. However, on a set samples accidentally contaminated with carbon during implantation, we noticed a considerable improvement of these tribological parameters. As this ...

International Nuclear Information System (INIS)

Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO_2 absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the P branch of the fundamental absorption band (2150--1950 cm"-"1) while the CO_2 vibrational-rotational lines were from the far wing of the R branch of the #nu#_3 fundamental band (2395--2380 cm"-"1). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO_2/N_2 gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the spectrometer and for peak overlap. Line strength measurements were made from the corrected peaks by using the Bouguer-Lambert law and ...

International Nuclear Information System (INIS)

The world's 500 million road vehicles using internal combustion engines account for roughly half of global oil consumption and, in Italy, for about 50% of all nitrogen oxide and 90% of carbon monoxide emissions. In efforts to conserve petroleum reserves and reduce air pollution, research programs are being conducted to develop hydrogen fueled automotive engines. Hydrogen combustion products are carbon dioxide free, and when burned with a large excess of air, this fuel produces water vapour and only small amounts of nitrogen oxides. Hydrogen fueled vehicles can be made to operate in a dual fuel mode so as to allow the use of petrol or diesel fuel in travel over long distances. Currently, because technical and economic difficulties relevant to hydrogen fuel storage limit driving range and payload (there are bulk and weight problems in compressed gas and metal hydride storage systems, and cost problems in cryogenic storage), ...

Energy Technology Data Exchange (ETDEWEB)

In this investigation natural gas has been used as an alternative fuel in diesel engines. Experiments have been performed to study the performance of the dual fuel engine with different diesel quantities as pilot injection. It was suggested in this research that combustion in the dual fuel engine occurred in four stages: the delay period, the slow stage of combustion, the rapid stage of combustion and the fourth stage of combustion. Because of the slower flame speed of natural gas and also because of the prolonged delay period, the combustion of the gas-air continued well into the expansion stroke. These resulted in lower efficiency and higher brake specific fuel consumption, and also higher exhaust gas temperature and higher carbon monoxide in the exhaust when the engine ran on dual fuel. The carbon dioxide and black smoke in the exhaust decreased as the gas was introduced in the engine. The ratio of alternative to diesel ...

UK PubMed Central (United Kingdom)

Hexachlorobenzene (HCB) is a persistent environmental pollutant. The toxicity of HCB has been extensively studied after an accidental human poisoning in Turkey and more recently it has been shown that...Full Text Available

UK PubMed Central (United Kingdom)

The Poison Control Centre at Toronto's Hospital for Sick Children received over 25,000 telephone inquiries in 1981. Those at greatest risk of accidental poisoning are children under age five. Education...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This study examines some radiation accidents occurred in the past. This information has been systematically assessed to get global lessons. The experience feedback shows that the most of accidents happened in certain conditions. These conditions can be distributed in four categories: 1- perception and vigilance in occupation: accidental exposure happened by lack of vigilance in details and lack of vigilance and perception; 2- procedures: accidental exposure happened following a lack of procedures or control that were not enough complete, not enough documented or not completely implemented; 3- training and understanding: accidental exposures happened because the personnel was not enough qualified and educated, did not get the general training nor the the necessary specialized training; 4- liabilities: accidental exposures happened following lacks and ambiguity in the definition of functions of the ...

UK PubMed Central (United Kingdom)

Background:During transurethral resection surgery (TUR), accidental stimulation of the obturator nerve can cause violent adductor contraction, leading to serious intraoperative...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Temperature and concentration profiles of CO in a laminar, axisymmetric, premixed methane-air Bunsen flame are measured using line-of-sight diode laser absorption spectroscopy and computer tomographic (CT) reconstruction. Absorption spectra for P(20) (v=2<-1) and P(27) (v=1<-0) vibrotational transitions of CO were measured at 21 evenly spaced positions over a 1.33 cm span for a 1.3 cm radius flame. CT reconstruction algorithm was based on Fourier convolution. The tomographically reconstructed normalized transmission profiles derived from absorption spectra, in conjunction with a quantum mechanical model for vibrotational behavior of CO, yielded both temperature and concentration profiles. The Bunsen flame had 3 distinct zones: an inner rich-premixed flame zone, an outer non-premixed flame zone and an unburnt core region. The reconstructed temperature profile showed that the core region temperature was close to ambient and rapidly increased to adiabatic flame temperature at the ...

Energy Technology Data Exchange (ETDEWEB)

This article presents the comparative bench testing results of a naturally aspirated, four stroke, four cylinder, water cooled, direct injection Diesel engine when running on diesel fuel and shale oil that is produced in Estonia from local oil shale. The purpose of this research is to investigate the possibility of practical usage of the shale oil as the alternative fuel for a high speed Diesel engine as well as to evaluate the combustion efficiency, brake specific fuel consumption, emission composition changes and the smoke opacity of the exhausts. Test results show that when fuelling a fully loaded engine with shale oil, the brake specific fuel consumption at the maximum torque and rated power is correspondingly higher by 12.3% and 20.4%. However, the brake thermal efficiencies do not differ widely and their maximum values remain equal to 0.36-0.37 for Diesel fuel and 0.32-0.33 for shale oil. The total nitrogen oxide emissions from the shale oil at engine partial loads remain ...

Science.gov (United States)

The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. The baseline fuel ...

Energy Technology Data Exchange (ETDEWEB)

Conversion of coal gas into liquid products is a multistep process which involves numerous unit processes. Compared with similar processes using natural gas as feedstock, there are challenges, particularly with the gas purification. There are, however, also advantages when using a carbon-monoxide-rich gas which ultimately may result in a greatly simplified process. This paper discusses the challenges when converting a gas from an entrained coal gasifier into a liquid product and the paper presents the various options available. The following issues will be touched upon: sour gas shift and adjustment of the H{sub 2}/CO ratio; acid Gas Removal (AGR) - when and how; syngas purification; methanol and combined methanol/DME synthesis; gasoline synthesis; future integrated processes. Here, various options are available depending on the gasifier; not only dry or slurry feed but also the question of quench as well as the selected scrubbing temperature are relevant. The WGS ...

Energy Technology Data Exchange (ETDEWEB)

Formaldehyde oxidation was examined in a laboratory reactor over alumina-supported Pt, Pd, Rh, Ag, Cu-Cr, and Pd-Ag catalysts as part of a program to develop catalysts for lean-exhaust methanol-fueled vehicles. In general, the H/sub 2/CO oxidation behavior of the catalysts paralleled the CH/sub 3/OH oxidation behavior reported in Parts 1 and 2 of this series (Appl. Catal. 27(1986) 83; J. Catal. 103(1987) 419). Principal similarities were: high activity of Pt when there was no carbon monoxide (CO) in the feed, but strong inhibition by added CO; lower activity of Ag and Cu-Cr catalysts, but only weak inhibition due to added CO; enhanced activity of the Pd-Ag catalyst compared to Pd and Ag alone for feeds containing CO in addition to H/sub 2/CO; and, relatively poor activity of the Rh catalyst. The most unusual behavior was observed with the Pd catalyst, which showed local minima in the H/sub 2/CO conversion vs. temperature profiles. These saddles ...

International Nuclear Information System (INIS)

The World Bank is analyzing the role of economic policy instruments for the control of air pollution in Poland, in cooperation with Polish and international experts. The first stage, covering Poland as a whole, was recently completed, jointly financed with the U.S. E.P.A. and the Government of the Netherlands. The second stage, now under way, will extend the analysis into a specific regional framework. Stage 2 is financed by the World Bank, the Polish Government, and the U.K. Environment Know-How Fund. Air Pollution in Poland is overwhelmingly caused by energy production and uses, due to the fact that the Polish economy depends heavily on coal and lignite. At present, vehicles contribute less to total emissions than do coal burning and industrial processes, although they account for 25-35% of nitrogen oxides, carbon monoxide, hydrocarbons and lead; and the concentrated in areas of high population density. The paper shows how economic, technical ...

Energy Technology Data Exchange (ETDEWEB)

As part of its air quality monitoring activities, Alberta Environment conducts unannounced mobile air quality surveys each year using the Department's Mobile Air Monitoring Laboratory (MAML). This laboratory provides a snapshot of the air quality at the location monitored for a particular time and space. The MAML measures several pollutants in the air including ammonia, carbon monoxide, hydrocarbons, oxides of nitrogen, ozone, particulate matter, reduced sulphur compounds and sulphur dioxide. Alberta Environment conducted a series of ambient air quality monitoring surveys in the Lloydminster Area in 2002, 2003 and 2004. This report presents the results of the five monitored locations over eight seasons of monitoring, which were selected in consultation with stakeholders and staff from Alberta Environment's Central Region office. Canister samples were also collected during these surveys for later laboratory analyses of volatile ...

Energy Technology Data Exchange (ETDEWEB)

This feasibility study of the uve Institut fuer Technische Chemie und Umweltschutz GmbH discusses the scientific and technical fundamentals of a catalytic process for complete removal of organic pollutants (PAH, H-HC, PCB, phenols, nitro-aromatics and organometallic compounds, e.g. from polluted soil and groundwater) by thermal-catalytic cracking and conversion into simple gases. The process is based on the catalytic reaction of the hydrocarbon compounds with water vapour in the temperature range of 700-900 degrees centigrade. The resulting gas mixtures consist mainly of hydrogen, carbon monoxide, carbon dioxide and methane which can be used as fuels, e.g. for heating or in gas engines. The process is an alterntive to combustion. It is therefore well suited whenever the pollutant to be removed is already mixed with water or water vapour and wherever in-situ removal would be too great a hazard. [Deutsch] Die vorliegende ...

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of NiO reduction with H{sub 2}S is higher than ...

International Nuclear Information System (INIS)

Non-traumatic osteonecrosis of the femoral head (ONF) is considered to be a disease that occurs primarily due to ischemia of the femoral head, while its etiology and pathology are not fully understood. It is therefore necessary to identify the characteristics of the hemodynamics of the femoral head. In this study, the hemodynamics in the ilium and proximal regions of the femur, including the femoral head, was investigated using positron emission tomography (PET). The subjects of this study consisted of 8 hip joints of four healthy male adults and 3 hip joints on the contralateral side of a femoral neck fracture, avulsion fracture of the greater trochanter and coxarthrosis (1 case each, all females) for a total of 11 hip joints of 7 subjects. The ages of the subjects ranged from 25 to 87 years (average age: 54 years). Blood flow was measured by means of the H_2"1"5O dynamic study method and blood volume was measured by means of the "1"5O-labeled carbon ...

Energy Technology Data Exchange (ETDEWEB)

This document is the safety analysis made by the national association of the local commissions of information about nuclear activities (ANCLI), about the safety of graphite storage silos of Saint Laurent des Eaux nuclear facility. The analysis covers: the operation safety and the accident hypothesis, the monitoring of indoor and outdoor contamination in routine situation, the geotechnical characteristics of the site environment, the isotopic inventory and the estimation of radioactivity in routine and accidental situation, the estimation of doses received by the population in accidental situation and the internal emergency plan. After examination of these different points, the scientific committee of the ANCLI considers that a new global evaluation of risks, which integrates more recent exposure data, has to be carried out. (J.S.)

Energy Technology Data Exchange (ETDEWEB)

The aims of the work described here were to provide an experimental basis for evaluating the committed effective dose equivalent per unit intake together with the ALI for four industrial oxide bearing dusts, and to assess the extent to which {sup 241}Am could be used for estimating the {sup 239}Pu content of the lung after an accidental intake of these materials. (author).

Science.gov (United States)

A mathematical model describing the behavior of a gas of any density released into a turbulent atmosphere was developed. A numerical treatment was established for two dimensional flow. An understanding of the effects of accidental or continuous release wa...

Energy Technology Data Exchange (ETDEWEB)

The food ingestion consequences due to radioactive particulates of an accidental release, scenario 1-RD-3, are evaluated for Savannah River Technology Center. The sizes of land areas requiring the protective action of food interdiction are calculated. The consequences of the particulate portion of the release are evaluated with the HOTSPOT model and an EXCEL spreadsheet for particulates.

UK PubMed Central (United Kingdom)

An 8-year-old child presented with severe chest pain and respiratory distress after he accidentally bit an automobile tyre tube which burst into his mouth. The chest radiograph revealed left-sided pneumothorax....Full Text Available

CERN Document Server

Compact Proton and Carbon Ion Synchrotrons for Radiation Therapy

International Nuclear Information System (INIS)

The work presented here demonstrates the ability of proton-transfer-reaction mass spectrometry (PTR-MS) to perform fast-response measurements of volatile organic compounds (VOCs) (including methanol, acetonitrile, acetaldehyde, acetone, PAN-type compounds, alpha- and beta-pinene, nopinone and pinonaldehyde) at the pptv level and its versatile applicability in the field of environmental trace gas analysis. Laboratory and field experiments including various calibration techniques and intercomparisons with other measurement techniques such as gas chromatography, atmospheric pressure chemical ionization and Fourier transformation infrared spectroscopy were performed providing a first characterization of the PTR-MS instrument performance (sensitivity, detection limit, precision, accuracy). Typically a detection limit (S/N=2) of 50 pptv for a 10 s signal integration time, a precision of 5 % and an accuracy in the range between 10 and 25 % were observed. Due to its compactness and ruggedness ...

UK PubMed Central (United Kingdom)

The transition-metal-catalyzed functionalization of C-H bonds is a powerful method for generating carbon-carbon...Full Text Available

International Nuclear Information System (INIS)

The purpose of this document is to provide a framework for developing protective strategies in the longer term following an accidental release of radionuclides to the offsite environment. This advice covers all forms and scales of accidental release, including releases from nuclear sites and reactors, weapons accidents, and damaged industrial or medical sealed sources. The countermeasures considered are those intended to protect the public from external irradiation from radionuclides deposited in the environment, from the inhalation of resuspended radionuclides, and from inadvertent ingestion of radionuclides resulting from contact with contaminated surfaces. The Board terms these recovery countermeasures. They can be broadly grouped as either decontamination measures (ie measures that deal directly with the radionuclides, whether by removing them, shielding them or physically or chemically bonding them) or as restricted access measures (ie ...

International Nuclear Information System (INIS)

The potential public safety impacts from accidents in conceptual fusion power plants were investigated. Fusion was found to have some potential for accidents, as does any energy generating system. Functions of fusion power plants were identified that possess sufficient potential for an accidental release of toxic materials to the environment. An assessment was made of the impact of the potential accidents and recommendations are included for R and D that will allow incorporation of safety concerns in fusion power plant design. This work was based on a review of information available in conceptual design documents of fusion reactor systems.

CERN Document Server

In this study we consider relations between companies in Poland taking into account common branches they belong to. It is clear that companies belonging to the same branch compete for similar customers, so the market induces correlations between them. On the other hand two branches can be related by companies acting in both of them. To remove weak, accidental links we shall use a concept of threshold filtering for weighted networks where a link weight corresponds to a number of existing connections (common companies or branches) between a pair of nodes.

Energy Technology Data Exchange (ETDEWEB)

A study for Cs-137 radionuclide dispersion in the marine environment through of compartmental model (Box Model) is presented. The model simulates the surface water contamination caused by direct atmospheric deposition, surface wash off, desorption from sediments and transfer with the ground water of accidentally released radionuclides. For this study the model was applied to the North Sea, near to Sellafield, based on the transfer coefficients obtain at the literature. The results obtained are in good agreement with the literature, being that the model developed can be applied in to the brazilian coastal regions. (author). 7 refs, 7 figs.

Energy Technology Data Exchange (ETDEWEB)

This paper is intended to describe how the citizens who are living near power plants or more generally nuclear facilities can be involved in the radiological control of their environment. Through the experience of the last twenty years, the article describes the conditions of the progressive setting up of a non- governmental system of control to build its principles of action and put them into practice. Three kinds of actions are described, the first two dealing with the problems in France and the last one related to a post-accidental situation in the contaminated areas of Belarus. The conclusion underlines how important it is to encourage this kind of involvement in order to increase public awareness of nuclear activities and their consequences. (authors)

Energy Technology Data Exchange (ETDEWEB)

Benchmark calculations for SCALE4.4 CSAS6 module have been performed for 31 UO{sub 2} fuel, 15MOX fuel and 10 metal material criticality experiments and then calculation biases of the SCALE 4.4 CSAS6 module have been revealed to be 0.00982, 0.00579 and 0.02347, respectively. When CSAS6 is applied to the criticality safety analysis for the mockup facility in which several kinds of nuclear material components are included, the calculation bias of CSAS6 is conservatively taken to be 0.02347. With the aid of this benchmarked code system, criticality safety analyses for the mockup facility at normal and hypothetical accidental conditions have been carried out. It appears that the maximum K{sub eff} is 0.28356 well below than the critical limit, K{sub eff}=0.95 at normal condition. In a hypothetical accidental condition, the maximum K{sub eff} is found to be 0.73527 much lower than the subcritical limit. For another hypothetical ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

ScienceCinema

...global warming and so ...

Science.gov (United States)

... 1981. Retention of diphenyls, terphenyls, phenylalkanes and fluorene on graphitized thermal carbon black. Chromatographia 14:510-514. ...

Energy Technology Data Exchange (ETDEWEB)

The carbon cycle is an important part of major biogeochemical cycles. Many techniques may be used to characterize carbon amounts and sources in the environment. Here we first review the most popular techniques for the determination of organic and inorganic carbon concentrations. Decarbonatation techniques are also reviewed in details since it is often an important part of organic carbon analysis. The second part of this paper addresses the use of carbon stable isotopes to characterize organic carbon sources and processes in the environment. An overview of general stable isotopes background and terminology is given as well as the most popular analytical techniques.

International Nuclear Information System (INIS)

(Pb_1_-_x La_x) (Zr_0_._6_5 Ti_0_._3_5) ceramics, with x = 0.09 (PLZT 9/65/35) were prepared using lead monoxide (Pb O) with different amount of litharge (tetragonal) and massicot (orthorhombic) phases. Results, based on x-ray diffraction patterns, remanent polarization and dielectric measurements, show that the Pb O polymorphic phase does not change the final structure of the PLZT but causes changes on the remanent polarization and dielectric permittivity temperature dependence. (author). 11 refs, 2 figs, 2 tabs.

Energy Technology Data Exchange (ETDEWEB)

Carbon supported catalysts can lose their activity over a period of time due to the sintering of the nanometer-sized catalyst particles. The sintering of metal clusters on carbon supports can occur due to the weak interaction between the metal and the support and also due to the corrosion of carbon, especially in fuel cell electrocatalysts. The sintering may be reduced by increasing the interaction between the metal and the support and also by increasing the corrosion resistance of carbon supports. In an effort to mitigate the growth of the nanoparticles, carbon-substituted boron defects were introduced in the carbon lattice. The interaction between the Pt nanoparticles on the pure and boron-doped carbon supports was examined using X-ray photoelectron spectroscopy (XPS). The results indicate that the interaction between the Pt nanoparticles ...

International Nuclear Information System (INIS)

Carbon-14 was analysed by direct absorption of carbon dioxide on the mixture of organic amine compound and scintillation cocktail then counted by low level liquid scintillation counter. This method can be applied for radiocarbon dating. In this study, the effects of carbon dioxide absorption, and counting efficiency were investigated using various commercial available cocktail. It was found that permafluor V and Ready Gel showed the highest carbon dioxide absorption whereas the Permafluor V showed the highest counting efficiency

Energy Technology Data Exchange (ETDEWEB)

Wetlands can potentially sequester vast amounts of carbon. However, over 50% of wetlands globally have been degraded or lost. Restoration of wetland systems may therefore result in increased sequestration of carbon. Preliminary results of our investigations into atmospheric carbon sequestration by restored coastal wetlands indicate that carbon can be sequestered in substantial quantities in the first 2-50 years after restoration of natural hydrology and sediment accretion processes.

International Nuclear Information System (INIS)

During the normal operation of a Nuclear Power Plant (NPP), radioactive releases into the atmosphere will be in small quantities. During major accidental situations, though the probability is extremely small, there may be significant release of radioactivity to the environment through the stack or at ground level. To study the external radiation exposure, if any, to the members of public due to releases during the normal operation of a nuclear power plant (NPP) and also to meet the requirement of emergency preparedness for the NPP site, continuous recording and analysis of environmental dose rate data is essential. This paper presents analysis of the gamma dose rates recorded by the Environmental Dose Logging Systems (EDLS) installed around the site during the last six years in the Emergency Planning Zone (EPZ) of Tarapur Atomic Power Station (TAPS). (author)

Energy Technology Data Exchange (ETDEWEB)

A relocatable storage magazine apparatus for storing and retrieving explosives and ordnance and for partially containing and attenuating the blast, conflagration and flying debris from an accidental explosion is described comprising: (a) a container having an access hole; (b) a debris trap attached to the container, the debris trap communicating with said container via the access hole, said debris trap having vent holes for venting the pressure of an explosion from said debris trap to the atmosphere; (c) means for covering said access hole; (d) means for suspending explosives and ordnance from the covering means; (e) means for entering the storage magazine to store and retrieve explosives and ordnance; (f) means for retaining said covering means in a position above the access hole wherein said explosives and ordnance are accessible from the entering means.

British Library Electronic Table of Contents (United Kingdom)

Summary Background Current management of egg allergy relies on egg elimination from the diet. It does not protect patients from reactions after accidental ingestion of the food and it has a negative influence on quality of life. To solve these problems, some desensitization protocols have been described that are safe and effective, but only one study of a rush regimen for egg with a small patient sample has been published. Objective To evaluate the safety, efficacy and immunologic effects of an oral rush desensitization protocol for immediate egg allergy. Methods Subjects aged 5 years or older with symptomatic IgE-mediated allergy to hen's egg underwent a 5-day oral tolerance induction regimen and were subsequently maintained on a regular egg intake. The variables studied were the reaction...

International Nuclear Information System (INIS)

The aim of this thesis is the design of a faults diagnosis-aiding system in a nuclear facility of the Cea. Actually the existing system allows the optimization of the production processes in regular operating conditions. Meanwhile during accidental events, the alarms, managed by threshold, are bringing no relevant information. To increase the reliability and the safety, the human operator needs a faults diagnosis-aiding system. The developed system, SECAPI, combines problem solving techniques and automatic learning techniques, that allow the diagnosis and the the simulation of various faults happening on nuclear facilities. Its reasoning principle uses case-based and rules-based techniques. SECAPI owns a learning module which reads out knowledge connected with faults. It can then simulate various faults, using the inductive logical computing. SECAPI has been applied on a radioactive tritium treatment operating channel, at the Cea with good results. (A.L.B.)

Science.gov (United States)

Rapid administration of stable iodine is essential for the saturation and subsequent protection of the thyroid gland against the potential harm caused by radioiodines. This paper proposes the Dutch risk analysis that uses an atmospheric dispersion model to calculate the size of the zones around nuclear power plants where radiological thyroid doses for children might be sufficiently high to warrant iodine administration. Dose calculations for possible releases from the nuclear power plants of Borssele (The Netherlands), Doel (Belgium) and Emsland (Germany) are based on two scenarios in combination with a 1-y set of authentic, high-resolution meteorological data. The dimensions of the circular zones were defined for each nuclear power plant. In these zones, with a radius up to 50 km, distribution of stable iodine tablets is advised. PMID:20332130

International Nuclear Information System (INIS)

Nuclear and other radioactive materials may get smuggled into the country aimed at malicious acts. Radioactive material detected accidentally or during inspection at the entry points/national borders may indicate illicit trafficking for the purpose of nuclear/radiological terrorism. As country requires prevention and preparedness for response to these malicious acts, nuclear forensic techniques are to be developed incorporating radiological safety aspects. Nuclear forensics helps in determining the origin, intended use, legal owner and the smuggled route etc. by using fingerprinting as well as comparison with reference data. The suggested sequence of methods for analysis of radioactive material/samples will be radiological assessment, physical characterization, traditional forensic analysis, isotope analysis along with elemental/chemical analysis

UK PubMed Central (United Kingdom)

The carbon-isotope ratio recently obtained for the carbon found in the Murchison meteorite, which has been shown (by the racemic nature of twelve component amino acids) to be free of terrestrial contamination,...Full Text Available

UK PubMed Central (United Kingdom)

Carbon dioxide is a waste product of aerobic cellular respiration in all aerobic life forms. PaCO₂ represents the balance between the carbon dioxide produced and that eliminated. Hypocapnia...Full Text Available

International Nuclear Information System (INIS)

The compressive and torsional buckling behavior of carbon nanotube bundles at room temperature is examined with classical molecular dynamics simulation. The critical compressive load and stiffness of a single carbon nanotube in the bundle are found to be similar to those of individual carbon nanotubes. However, the critical torsional moment and stiffness of a single carbon nanotube in the bundle are found to be higher than those of individual carbon nanotubes. In addition, this study demonstrates that van der Waals interactions between the nanotubes in the bundle significantly affect the critical compressive load of the nanotube bundle.

Energy Technology Data Exchange (ETDEWEB)

We prepared cathodes with various types of activated carbon and measured the cathodes' electrochemical performance according to the kind of activated carbon. Activated carbon supplies airflow channels and reaction sites in the cathode of zinc air batteries. When we use activated carbon with a high specific surface area as the cathode's catalyst substrate, we expect high electrochemical performance because this type of carbon provides more air flow channels and reaction sites. We focused on investigating the relationship between the cathode's pore structure and its electrochemical characterizations. We also studied the effects of the various activated carbon materials on the zinc air batteries' performance. Increasing the macropores or mesopores in the activated carbon resulted in achieving more power from ...

Science.gov (United States)

... rate on the tensile properties of SA-106 carbon steel pipe, in support of analysis and experimental modeling of postulated pipe whip in nuclear ...

Science.gov (United States)

... The fuel proposed was a medium-thermal carbon black-liquid JP-i1 mixture. JP-iO or exo-tetrahydrodi (cyclopentadieue) is a pure hydrocarbon with ...

Energy Technology Data Exchange (ETDEWEB)

Ab initio planewave pseudopotential method is used to study carbon diffusion and pairing in crystalline silicon. The calculation is performed with a 40 Ry planewave cutoff and 2x2x2 special k-point sampling with a supercell of 64 atoms. It is found that substitutional carbon attracts interstitial Si forming a <001> C interstitial with a large binding energy of 1.45 eV. The interstitial carbon is mobile and can migrate with a migration energy of 0.5 eV. The interstitial carbon can bind further to another substitutional carbon forming a substitutional carbon-interstitutional carbon pair with a binding energy of 1.0 eV. This model is used to understand the effect of high C concentration on the transient enhanced diffusion in Si.

Energy Technology Data Exchange (ETDEWEB)

A process is described for removing carbon dioxide from a feed stream of natural gas, having at least methane, ethane and heavier hydrocarbon, comprising: separating the feed stream in a first separator to form a first stream, having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane, and a second stream, having methane, carbon dioxide and ethane; mixing the second stream with a polar compound to form a third stream; separating the vapor and liquid of the third stream in the bottom portion of an absorber; absorbing carbon dioxide and ethane from the separated vapor of Step C in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane forming a fourth stream; separating the ethane from the polar compound and carbon dioxide in a separator; separating the first stream in a third separator to ...

Energy Technology Data Exchange (ETDEWEB)

Carbon Black and activated carbon materials providing high surface areas and a distinct pore distribution are prime materials for supercapacitor applications at frequencies < 0.5 Hz. A number of these materials were tested for their specific capacitance, surface and pore size distribution. High capacitance electrodes were manufactured on the laboratory scale with attention to ease of processability. (author) 1 fig., 1 ref.

KoreaScience (Korea)

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ScienceCinema

...great global warming ...global warming and and uh if something is known about ...

KoreaScience (Korea)

Full Text Available

Science.gov (United States)

... Examples are when carbon dioxide and volcanic ash emitted into the atmosphere by volcanic eruptions ...

International Nuclear Information System (INIS)

... aurorae carbon dioxide emission spectra infrared radiation nitrogen nitrogen

Science.gov (United States)

... entitled: In-country Pilot Activities: Reducing Emissions from Deforestation and Degradation)...

British Library Electronic Table of Contents (United Kingdom)

Layered carbon fiber mats have been prepared by layer-by-layer (LBL) electrospinning of polyacrylonitrile onto thin natural cellulose paper and subsequent carbonization. The layered carbon fiber mat has been proved to be a promising microbial fuel cell anode for high density layered biofilm propagation and high bioelectrocatalytic anodic current density.

KoreaScience (Korea)

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KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

The carbon content of silicon single crystals and polycrystals has been measured by charged particle activation analysis (CPAA) and infrared absorption. The authors obtained a linear relationship between the absorption coefficient at 605 cm/sup -1/ and the carbon content obtained by CPAA. They obtained a conversion factor of (1.00 +- 0.03) 10/sup 17//cm/sup 2/ for a 100% substitutional carbon.

Energy Technology Data Exchange (ETDEWEB)

The metabolism of organic matter in the coastal regions of the ocean may significantly affect the oceanic carbon budget. This paper describes the high percentage (30%) of oceanic oxidation that occurs in coastal areas and the impact of this metabolism on the carbon cycle and climate of earth. Organic metabolism in the ocean appears to be a source of carbon dioxide release into the atmosphere. Oxidation in the coastal zone is of special interest, as it is likely influenced by anthropogenic activity. Recommendations for future research on this topic are proposed. 129 refs., 2 figs., 6 tabs.

KoreaScience (Korea)

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ScienceCinema

...carbon dioxide in the atmosphere contributes to global warming anything that could ...

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In this work, a comprehensive model has been developed for the absorption of carbon dioxide into promoted hot potassium carbonate solution. The model, which is based on penetration theory, incorporates an extensive set of important reactions and takes into account the coupling between mass transfer and chemical kinetics. The penetration theory provides an appropriate absorption rate and enhancement factor for the chemical absorption. Operating data for carbon dioxide absorption into DEA-hot potassium carbonate solution has been compared with model predictions. The impact of parameters such inlet temperature of lean solution, promoter concentration, liquid split fraction, hot feed location and type of promoter on the performance of a split-flow absorber have been examined. The use of other promoters is an efficient way to enhance the carbon dioxide absorption, which has been ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes the estimated the rate of carbon accumulation in the woody biomass and total carbon storage in the forests including trees, soil and litter in Korea. The relevant data come from the Statistical Yearbook of Forestry and major results of the studies on forest biomass in Korea. Most of the forests, which has been denuded or degraded during the 2nd World War and the Korean War, were recovered through ``Reforestation Project(1973-1987)`` and natural regeneration. So, now they are mostly young secondary forests and grow rapidly. Total carbon removal by forests is estimated at 8.1 million tonnes of carbon(MtC) and the carbon emission by commercial harvesting at 0.9 MtC. therefore, the forests in Korea play an essential role as a net carbon sink. The annul net carbon removal is 7.2 MtC and accounts for about 11.0% of total ...

International Nuclear Information System (INIS)

A high-voltage cathode initiates an electron emission, resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition, the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.

Energy Technology Data Exchange (ETDEWEB)

The interest of irradiation by carbon ions is in the fact that the carbon ions leave all their energy to a determined depth. ( phenomenon known under the name of Bragg peak)This high diffusion in tissue gives an RBE particularly high. The indications of this therapy are chordomas, and chondrosarcomas of the skull base, some cyst adenoid carcinomas, pulmonary cancer, sarcomas, hepato carcinomas, melanomas. In the light of results in term of efficiency, the place of irradiation by carbon ions should widen. (N.C.)

International Nuclear Information System (INIS)

Tensile properties of reduced-activation 10Cr-30Mn austenitic steels with carbon levels from 0.003 to 0.55% were investigated over the temperature range from room temperature to 873 K after neutron irradiation in the Japan Materials Testing Reactor at 573 K to 8.5x10"2"2 n/m"2. Irradiation-induced increase in yield stress increased significantly with carbon concentration up to about 0.1% and it was constant above 0.1% carbon. A high density of dislocation loops with small (below 10 nm) and large (20-30 nm) sizes formed during irradiation. The high density, small loops caused a large irradiation hardening, while the large loops contributed only slightly to irradiation hardening. It was considered that carbon atoms formed the small loops together with irradiation defects. The deformation channeling was observed in the irradiated high carbon steels, 0.11 and 0.55% ...

Energy Technology Data Exchange (ETDEWEB)

This issue of Carbon Market Perspectives on 'Pathways for implementing REDD+: Experience from carbon markets and communities' discusses the role of carbon markets in scaling up investments for REDD+ in developing countries. Nine articles authored by experienced negotiators on REDD+, carbon market actors, project developers and other leading experts share experiences and make suggestions on the key elements of a future international REDD+ regime: Architecture and underlying principles, measuring, reporting and verification (MRV), private-sector involvement, the rights of indigenous people and local communities, biodiversity conservation and environmental integrity. The articles are grouped under three main topics: the lessons of existing REDD+ projects; the future REDD+ regime and the role of carbon markets; and experiences and ideas about the involvement of ...

British Library Electronic Table of Contents (United Kingdom)

Carbon black is widely used as an active filler in the rubber industry to improve the physical properties of rubber. The surface energy of carbon black is high compared to that of various elastomers like styrene?butadiene rubber (SBR), butadiene rubber (BR) and ethylene?propylene?diene rubber (EPDM). The work aims at reducing the surface energy of carbon black by modifying its surface for application especially in rubber blends. The present paper looks into the possibility of using plasma polymerisation of acetylene as a surface modification technique for carbon black in comparison with silica. Thermogravimetric analysis, wetting behaviour with various liquids of known surface tension and time of flight secondary ion mass spectrometry (ToF-SIMS) were used to characterise the carbon black b...

Energy Technology Data Exchange (ETDEWEB)

Methane and carbon dioxide are the two main constituents of biogas. Biogas also contains traces of nitrogen, hydrogen, oxygen and hydrogen sulphide. When diesel engine runs on biogas, the combustion is poor as compared to diesel fuel. One of the reasons of poor combustion is the presence of carbon dioxide in the biogas. Percentage of methane and carbon dioxide in biogas varies with maturities of feed stock, temperature, water content, loading rate of raw material and bacterial actions. This paper examines the effect of variations of carbon dioxide in biogas on the performance of the engine to simulate the performance of the engine running with biogas from different sources (varying proportion of methane and carbon dioxide). (Author)

Energy Technology Data Exchange (ETDEWEB)

The moment analysis of pulse responses was applied to a biological activated carbon (BAC) bed to evaluate the microbial activity. Glucose and activated carbon fiber (ACF) were employed in experiments as a model tracer and an activated carbon respectively. No significant difference in biodegradation rates of glucose by microorganisms attached on different solid supports such as activated carbon inactivated carbon and glass fibers was observed. However, higher microbial activity was obtained from microorganisms supported on the ACF in terms of the apparent degradation of total organic including metabolic byproducts by microorganisms, since part of the metabolic byproducts was irreversibly deposited onto the ACF. 11 refs., 6 figs.

Energy Technology Data Exchange (ETDEWEB)

To apply the CO{sub 2} absorber at about 1000{sup o}C for integrated coal gasification combined cycle (IGCC) furnace, the reactions of calcium oxide and CO{sub 2} at high temperatures was examined. Calcium carbonate reacts with sodium hydrogen carbonate below 200{sup o}C and forms sodium-calcium complex carbonate. The sodium-calcium complex carbonate melts at 813{sup o}C, and the carbon dioxide absorption and discharge reversible reactions of calcium-oxide takes place via liquid at around 1000{sup o}C. Sintering of calcium oxide at high temperature has been successfully avoided by the addition of sodium.

Energy Technology Data Exchange (ETDEWEB)

This paper introduces the summary of design guideline (draft) for the limit state design method for foundation structures, and examples of calculations on pile foundations. The limit states were set using the load to transformation curves, and the limit state No. 3 in particular assumed a large earthquake, a state that a foundation is fatally damaged because of rarely acting loads that lead to generation of displacement and loss of stability and functions. Ground survey coefficient, ground resistance coefficient, and ground property coefficient were defined especially as the safety coefficients. With respect to the displacement in the limit state No. 3, a restriction value was set for the plasticity of the foundation. Loads were given considerations of combination of permanent load, variation load, and accidental load, each having been set with a load coefficient. It was decided regarding earthquakes to discuss strength and toughness of members, displacement of ...

International Nuclear Information System (INIS)

The authors present arguments against nuclear energy and pro renewable energy sources. Thus, the water used in Uranium mining and primary ore processing becomes contaminated in long lived radioisotopes and so a threat for local ecosystems and communities. Then, during the fabrication, enrichment, and handling of nuclear fuel the workers are exposed to radiations and dangerous accidental radioactive leaks can occur. But, by far, the most menacing aspect of nuclear power exploitation remains the human errors in operating the nuclear plants which can result in major accidents like that from Chernobyl which spread radioactivity all over the Europe. The equipment used in nuclear facilities which is highly contaminated as well as the burned fuel implies transportation and long term storage which also present high risks. The major advantage of the nuclear energy consists in its very low environment impact and its null contribution to the greenhouse effect. In contrast, ...

Science.gov (United States)

Ballistics involves the study of the scientific properties of projectiles, their behavior and their terminal effects on biological tissues and other materials. Wound ballistics deals with the analysis of injuries caused by projectiles and the behavior of projectiles within human or other biological tissues. The nineteenth century witnessed the development of both of these areas with Kocher's hydrodynamic theory and the understanding of the significance of bullet deformation in causing tissue injury. The degree of traumatic disruption of tissues and organs was also related to direct energy transfer from projectiles. While subsequent research has concentrated on elucidating further mechanisms of injury, the exact cause of remote tissue damage from high energy projectiles is still the subject of ongoing research. Much of the contemporary literature regarding wound ballistics concentrates on the forensic aspects and their application for legal purposes, in particular the investigation of ...

International Nuclear Information System (INIS)

The SPring-8 linac has been improved to realize stable top-up injection into the SPring-8 and the NewSUBARU storage rings. The beam energy instability of 0.02% rms in the long term was achieved by means of reducing RF variations, providing beam energy compensation, reinforcement of monitor systems and introduction of beam feedback controls: Variations in the RF power and phase have been reduced by improving the voltage regulation system for the klystron modulator, and by stabilizing the temperature drift of the atmosphere and cooling water in order to reduce the phase variation. A new synchronous oscillator synchronizes a beam trigger pulse and a 2856 MHz reference signal, reducing variation in the beam charge. A beam energy compression system (ECS) was installed to compensate for accidental energy variation and reduce the energy spread. Beam feedback controls compensate for residual long-term variations of beam trajectory and energy. (author)

International Nuclear Information System (INIS)

The program package COSYMA for assessing the radiological and economic consequences of nuclear accidents, developed with the support of the European Commission, was applied to investigate the health effects and risks from accidental releases of radioactive material from the Daya Bay nuclear power plant. Population distribution data in the range of 80 km around the site and hourly meteorological data for the year 1985 representative of accident consequence analysis were used. The results showed that early effects are more important at distances closer to the site, while the number of fatal cancers is closely related to the population density and the late effects are still important at distances larger than 50 km from the site. The mean annual expected values for early mortality and late mortality estimated for the population within a circle of 80 km around the Daya Bay nuclear power plant are 4.5x10"-"3 and 0.1 yr"-"1, respectively.

Energy Technology Data Exchange (ETDEWEB)

Population residing in the northern part of the Chelyabinsk oblast and the south eastern part of the Sverdlovsk oblast of Russia affected to accidental exposure since 1957. The territory (East Ural Radioactive Trace - EURT) was contaminated after explosion of container with highly radioactive wastes at the Mayak Production Association. Studies of health effects of exposure in the southern, head part of EURT are conducted in the Ural Research and Practical Center of Radiation Medicine (U.R.P.R.M.). In the 1990's U.R.P.C.R.M. formed a cohort of EURT within Chelyabinsk oblast (14,500 cases and 19,400 external controls). The cohort was followed in 1957-1987 and the results of the study are discussed by Crestinina et al. First results of study on exposure late health effects among rural population in the northern part of the EURT are presented in this paper. Firstly, or the period 1958-2000 a statistically significant increase in cancer mortality associated ...

UK PubMed Central (United Kingdom)

This study was designed to evaluate the suitability of a novel bioabsorbable material in treating bone defects. A poly(desaminotyrosyl-tyrosine-ethyl ester carbonate) (PDTE carbonate) membrane (thickness...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Porous carbon with high surface area and pore volume was prepared by a reverse replication process and its toluene equilibrium adsorption behavior was investigated. The preparation process of the porous carbon was composed of following sub-processes in series: synthesis and template preparation of silica gel, impregnation and polymerization of DVB monomer in silica template, carbonization of DVB polymer in a silica-polymer composite, and HF-assisted selective etching of silica in carbon-silica composite, The prepared porous carbon was nano porous and had ultrahigh specific surface area (2007 m{sup 2}/g) and large pore volume (3.07cm{sup 3}/g). The nanoporous carbon showed rapid toluene adsorption rate and good toluene adsorption capacity, compared with a commercial Y-type zeolite, In the present study, a reverse replication process to prepare nanoporous ...

Energy Technology Data Exchange (ETDEWEB)

Recently we have found that carbon nano-materials have ability to recognize softer actinides(III). In this presentation, separation of americium(III) from lanthanides(III) by chromatography with carbon nano-materials, such as carbon nano-tubes and graphite, has been investigated by batch adsorption experiments and chromatography. The separation factor (SF) between americium(III) and lanthanide(III) was about 2 in the range of pH from 1 to 4 by using carbon nano-tube, graphite and activated charcoal. The separation factor depended on the diameter of carbon nano-tubes. Smaller one, 3-20 nm diameter, showed the best selectivity for americium(III), which separation factor was about 2.0, although larger one, 40-70 nm, showed almost no selectivity. The same behavior has been observed by using graphite powder and activated charcoal although acid- or alkali pretreated activated charcoal ...

UK PubMed Central (United Kingdom)

BackgroundThe precision in carbon ion radiotherapy depends on the calibration of Hounsfield units (HU) as measured with computed tomography (CT) to water equivalence. This calibration...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank--Turnbull reactions. This study of boron TED reduction in Si{sub 1-x-y}Ge{sub x}C{sub y} during 750{sup o}C inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes {l_brace}311{r_brace} defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank--Turnbull reaction, and a carbon interstitial-carbon substitutional ...

Energy Technology Data Exchange (ETDEWEB)

A laboratory differential simulation method is used for the design of carbonization columns at coal-tar processing in which phenols are regenerated from phenolate solution by carbon dioxide absorption. The design method is based on integration of local absorption rates of carbon dioxide along the column. The local absorption rates into industrial phenolate mixture are measured in a laboratory model contactor for various compositions of the gas and liquid phases under the conditions that ensure the absorption rates in the laboratory absorber simulate the local rates in the industrial column. On the bases of the calculations, two-step carbonization columns were designed for 30000 t/year of the phenolate solution treatment by carbon dioxide. The absorption proceeds at higher pressure of 500 kPa and temperatures from 50 to 65 C, pure carbon dioxide is used and ...

Energy Technology Data Exchange (ETDEWEB)

Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.

Energy Technology Data Exchange (ETDEWEB)

Several inexpensive and non-toxic solvents with low vapour pressures were investigated for their suitability as alternative solvents for the absorption of carbon dioxide from flue gas. The solvents include poly(ethylene glycol)s, poly(ethylene glycol) ethers, poly(ethylenimine) and glycerol-based substances. Solvent properties such as thermal stability, solubility of carbon dioxide and selectivity over nitrogen were investigated in a systematic study using a thermogravimetric analyser. Absorption results are reported for pure carbon dioxide and nitrogen as well as a mixture of both gases. Desorption and long-term sorption behaviour are also discussed. Glycerol and poly(ethylene glycol)s show a high solubility of carbon dioxide. Due to the high viscosity of the solvent, carbon dioxide absorption in poly(ethylenimine) is very slow in spite of the presence of favourable amine groups. ...

Energy Technology Data Exchange (ETDEWEB)

A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.))

KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

A billet of low-density carbon-bonded carbon fiber (CBCF) composite is machined into a desired attenuator or load element shape (usually tapering). The CBCF composite is used as a free-standing load element or, preferably, brazed to the copper, brass or aluminum components of coaxial transmission lines or microwave waveguides. A novel braze method was developed for the brazing step. The resulting attenuator and/or load devices are robust, relatively inexpensive, more easily fabricated, and have improved performance over conventional graded-coating loads.

International Nuclear Information System (INIS)

... carbon 14 cholera gels labelling membranes molecules proteins receptors

Energy Technology Data Exchange (ETDEWEB)

Mixed microstructures have been studied in low- carbon microalloyed steels suitable for automotive applications, after continuous cooling from the hot-rolled condition. Microstructural features such as polygonal ferrite, bainitic and acicular ferrite and microphase constituent are identified using transmission electron microscopy. The influence of these mixed structures on the tensile strength, impact toughness and fracture behaviour is examined. It is found that improvements in impact toughness as compared with microalloyed medium- carbon ferrite/pearlite steels can be achieved from these predominantly acicular structures developed by controlling alloy composition and continuous cooling of these lower carbon steels. (orig.).

Science.gov (United States)

A sandwich construction, composed of hybrid carbon-glass fiber-reinforced plastic skins and a

Energy Technology Data Exchange (ETDEWEB)

In the framework of the carbon storage two forestry methods are analyzed by the author: the standing capitalization (slowing of the crops) and the spices substitution (slow growing species by fast growing species). The construction of a model taking into account the all stage of the carbon implication (biomass, soil, forest products) offers simulation and quantitative results on these methods. (A.L.B.)

International Nuclear Information System (INIS)

... Industry, Material Science Research Laboratory, Yokosuka, Kanagawa (Japan)

KoreaScience (Korea)

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Science.gov (United States)

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Science.gov (United States)

One of the major problems associated with solid waste processing technologies is the release of

Science.gov (United States)

... The ultimate compressive strength (UCS) for the HMU/BSG composite is essentially equivalent to the tensile strength exhibited by this system. ...

Science.gov (United States)

... be easily replaceable, and its compartment or container ... in a simple, efficient manner for storage or disposal. ... and enters the reactor at approximatel ...

Energy Technology Data Exchange (ETDEWEB)

The present report concerns a research for the tritium and for the carbon 14 in lichens in a spirit of bio-indication: the first results appear in Daillant and al (2004 ) and additional results were presented to the congress B.I.O.M.A.P. in Slovenia, organized collectively by the institute Josef Stefan from Ljubljana and the international atomic energy agency from Vienna (Daillant and al 2003). (N.C.)

Science.gov (United States)

The thermodynamic characteristics of adsorption of sulfur-containing amino acids and their derivatives on the surface of graphitized thermal carbon black were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the S atom in amino acids and the graphite C atom were determined. It was shown that an intramolecular H-bond influenced the adsorption of amino acids on the surface of graphitized thermal carbon black.

Energy Technology Data Exchange (ETDEWEB)

In this paper structure and mechanical properties of PBZT and PBO fibers are briefly discussed. One limitation of the high-modulus polymeric fibers and ultrahigh-modulus carbon fibers in reinforced composites is their poor compressive strength. Issues related to the compressive strength of polymeric and carbon fibers are considered. 62 references, 7 figures, 4 tables.

Energy Technology Data Exchange (ETDEWEB)

The objective of this research is to gain a better understanding of the corrosion of the aluminized type 316 stainless steel employed in the seal areas of the molten carbonate fuel cell. The seals are formed between the aluminized Type 316 SS surface and the electrolyte (generally a mixture of molten alkali carbonates and lithium aluminate).

International Nuclear Information System (INIS)

Mutual influence of phosphorus and carbon on the tendency to integranular corrosion (IGC) of tempered austenitic stainless steels in boiling solutions of 65% HNO_3 and 27% of HNO_3+40 g/l Cr"6"+ was investigated. It is ascertained that under the action of carbon additions susceptibility of phosphorus-containing steels to IGC increases considerably in pure nitric acid and decreases in nitric acid containing the oxidant. Possible reasons for the effects observed are discussed.

International Nuclear Information System (INIS)

In this article carbon co-implantation and step-by-step thermal treatments of shallow p"+-n-junctions formation were used with the purpose of extended defect suppression and reduction of boron transient enhanced diffusion. A substantial improvement of the structural and electrical parameters of shallow p"+-n-junctions has been achieved by using the additional carbon implantation and step-by-step thermal treatments. (authors)

Energy Technology Data Exchange (ETDEWEB)

This paper investigates the spectral characteristics of three-dimensionally porous carbon dioxide indicators based on a porous silicate glass and phenolphthalein. The absorption spectra of the original solutions of phenolphthalein in alkaline and acid solutions are shown. The solutions were acidified by bubbling CO/sub 2/ through an alkaline phenolphthalein solution. The authors have succeeded in producing a reversible colorimetric adsorption indicator for carbon dioxide which after proper calibration enables the CO/sub 2/ content of an atmosphere to be estimated quantitatively.

British Library Electronic Table of Contents (United Kingdom)

Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433?479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.

Energy Technology Data Exchange (ETDEWEB)

Carbon films have been made by a variety of techniques, including evaporation, sputtering, and laser or thermal pyrolysis of organic polymers. Polyacrylonitrile (PAN) is often used as a carbon precursor, since low-temperature thermo-oxidative pretreatment produces a material which can be pyrolyzed without loss of shape. This is the basis for the production of carbon fibers with good mechanical properties. We report here the formation of very thin films of carbon (500 to 1500 A) by pyrolysis of spin-cast PAN. Using this technique, large, conductive films can be made which are sufficiently robust to allow intact lift-off and transfer of the films from one substrate to another. Such films are chemically inert, but can be photolithographically patterned and etched with an oxygen plasma.

British Library Electronic Table of Contents (United Kingdom)

The shift to renewable energy options and low-carbon technologies, in response to the concerns over energy security and climate change, is proceeding more slowly than many would like. The usual argument against rapid deployment of new technologies is the costs imposed on the economy, commonly interpreted in terms of upfront costs to be borne or involving large cash transfers to fund, for example, efforts to preserve rainforests. In this contribution I argue that such a perspective provides a continuing barrier to taking effective action, whereas a perspective based on creation and use of carbon credits provides a means of avoiding the shock of abrupt industrial change. Carbon credits granted for bona fide carbon load reductions could be created through private initiative, for example by me...

British Library Electronic Table of Contents (United Kingdom)

A pilot cropland carbon sequestration program within north central Montana has allowed farmers to receive carbon credit for management adjustments associated with changing from tillage-based agricultural systems to no-till. Carbon credit can also be obtained by adopting conservation reserve, where cropland is planted into perennial vegetation. Summer fallowing is also considered within the crediting process as credit is not given in years that a field is left un-vegetated. The carbon sequestration program has been advocated as a means to mitigate climate change while providing an added source of income for Montana farmers. There is lack of data, however, pertaining to the percentage of lands within this region that have not converted to no-till management, lands under certain crop intensit...

British Library Electronic Table of Contents (United Kingdom)

This objective of this work was to summarize the main results obtained in previous papers related to the adsorbent-adsorbate interactions involved in the adsorption of naphthalenesulphonic acids and heavy metals (Cd(II) or Hg(II)) by modified activated carbons. The adsorption of organic compounds (1-naphthalenesulphonic acid, 1,5-naphthalenedisulphonic acid and 1,3,6-naphthalenetrisulphonic acid) and inorganic species (Cd(II) and Hg(II)) was studied on a series of ozonized activated carbon in aqueous phase. Commercial activated carbon (Filtrasorb 400) was treated with different ozone doses to study the effect of ozone treatment on its surface properties and investigate the behavior of the treated carbon samples in the above adsorption processes. After ozonation, carbonyl- and carboxyl-type...

Energy Technology Data Exchange (ETDEWEB)

Carbons derived from the phase separation of polyacrylonitrile/solvent mixtures were investigated as lithium intercalation anodes for rechargeable lithium-ion batteries. The carbon electrodes have a bulk density of 0.35-0.5 g/cm{sup 3}, relatively low surface areas (< 10 m{sup 2}/g), and micron-size cells. Pyrolysis temperature influences the reversible lithium intercalation and the irreversible capacity (associated with the formation of the passivating layer). Carbon electrodes pyrolyzed at 600{degrees}C have first-cycle capacity as high as 550 mAh/g as well as large irreversible capacity, 440 mAh/g. Electrodes prepared at 1050{degrees}C have reversible capacities around 270 mAh/g with relatively lower capacity losses (120 mAh/g). Doping the organic precursors with phosphoric acid, prior to pyrolysis at 1050{degrees}C, leads to carbon electrodes with reversible capacities as high as 450 mAh/g. The ...

Energy Technology Data Exchange (ETDEWEB)

The carbon transfer has been analyzed in the Alloy 800/sodium/stainless steel system by determining the carbon-uptake of Alloy 800 foils, which were exposed in liquid sodium of known carburizing potential. Under equilibrium conditions between 650 and 550/sup 0/C the measured total carbon concentrations in the Alloy 800 tabs were found to be roughly related to the carbon activities of the sodium environment by the equation already stated for the 18 Cr-8/10 Ni stainless steels, extrapolated to the chemical composition of the Ni-rich austenitic alloy. However the Alloy 800 was not found to undergo any decarburization in low-carbon activity environments. The carbon diffusion kinetics was determined as a function of temperature, it was found to be similar to that reported for the AISI-304 type of steel. The effects of sodium exposure on microstructural and mechanical ...

Energy Technology Data Exchange (ETDEWEB)

This thesis deals with the analysis of dominant loss mechanisms in direct methanol fuel cells (DMFC) and hydrogen fed polymer electrolyte membrane fuel cells (PEFC) by means of experimental characterization and modeling work. Due to different fuels used in these two fuel cell types, the dominant loss mechanisms are different in their nature. All in-situ characterization techniques that are used in this work are based on a novel test fuel cell with embedded reference electrodes. The first part of this work presents a new concept for realizing a reference electrode configuration in a polymer electrolyte membrane fuel cell by means of laser ablation. The laser beam is used to evaporate a small gap into the electrode surface of a catalyst coated membrane (CCM) to isolate the reference electrode from the working/counter electrode (WE/CE). This method enables the simultaneous ablation of the electrodes on both sides of the CCM because the membrane is transparent for the laser beam. ...

Energy Technology Data Exchange (ETDEWEB)

This paper reports the estimates concerning the atmospheric carbon dioxide absorption and storage by living plants all over the world. It is necessary to decrease atmospheric carbon dioxide concentrations for avoiding global warming. As living plants absorb carbon dioxide by photosynthesis and accumulate carbon in their bodies, they can play an important role to remove atmospheric carbon dioxide. Literatures describing distribution areas, biomass values and net primary productivity (NPP) of forests, marine plants and microorganisms were collected. Examining those data, the biomass and NPP of forests, marine plants and microorganisms can be summarized as follows: (1) Forest biomass and their NPP of the world. The world's forest area is recently estimated as 4 billion hectares, and their biomass is about 400 billion tons of carbon which is equal to 2/3 of ...

Science.gov (United States)

In this paper we investigate the effects of surface mediation on the adsorption behavior of argon at different temperatures on homogeneous graphitized thermal carbon black and on heterogeneous nongraphitized carbon black surface. The grand canonical Monte Carlo (GCMC) simulation is used to study the adsorption, and its performance is tested against a number of experimental data on graphitized thermal carbon black (which is known to be highly homogeneous) that are available in the literature. The surface-mediation effect is shown to be essential in the correct description of the adsorption isotherm because without accounting for that effect the GCMC simulation results are always greater than the experimental data in the region where the monolayer is being completed. This is due to the overestimation of the fluid-fluid interaction between particles in the first layer close to the solid surface. It is the surface mediation ...

International Nuclear Information System (INIS)

The aim of this paper was to describe ability to intercalation of laboratory prepared carbon composites and their constituents. In work the following materials were tested; pinch-based fibres of P-120 and K-1100 manufacturer's designations, carbon matrix and resulting composites. To prepare a matrix of composites, phenol-formaldehyde resin (Z) and pinch-based precursor (PAK) were used. After initial carbonization, the carbon matrix was heated to 2150 "oC i to improve ability to the future intercalation. Three kinds of composites (P/Z, K/Z and K/PAK), with two directional reinforcement (2D), were prepared. All carbon samples were intercalated with copper chloride(II). To study the structure of all materials, before and after intercalation, X-ray diffraction method was used. It enabled to measure microstructure parameters (L_c and L_a), interplanar distance (d_0_0_2) thickness of an ...

Energy Technology Data Exchange (ETDEWEB)

We examined, using thermo analytical methods, the effects of 2000 deg. C heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnation but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30 wt%. graphite powders of furfuryl alcohol and the heating rate 35 deg. C/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above 1000 deg. C was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization {yields} impregnation {yields} cure {yields} re-carbonization) required to density a ...

Energy Technology Data Exchange (ETDEWEB)

The deposition of platinum on various carbon blacks was carried out by forming active functional groups on the surface of the carbon support, and exchanging these active groups with different platinum complexes. Using H{sub 2}PtCl{sub 6} solution, an impregnation rather than an exchange takes place. However, using divalent platinum complexes [Pt(NH{sub 3}){sub 4}]{sup 2+}, a fast exchange takes place which leads to extremely small platinum particles highly dispersed on the surface of carbon black. A comparison of the catalytic activities of platinum supported on various carbon blacks was also carried out. The performances of PEFC (Polymer Electrolyte Fuel Cell) based on the process of the ion exchange are reported. (authors) 3 refs.

Energy Technology Data Exchange (ETDEWEB)

An assessment was carried out to identify where the Carbon Trust's Low Carbon Innovation Programme (LCIP) should concentrate its investment. LCIP acts in a similar manner to a venture capital company, seeking the best carbon return rather than a specific financial return. Over the next 3 years LCIP plans to invest 75 million dollars in selected technologies and businesses that can help the UK move towards a low carbon economy. The assessment will be updated annually. 49 technologies were assessed in areas of: demand-side: buildings; demand-side: industry; supply-side: fuels and conventional energy production; supply-side: renewables; transport; and enabling technologies. Technologies were rated in categories according to their technology impact and the extent to which LCIP funding could make an impact. Coal bed methane is identified as one technology profile to consider; cleaner coal production ...

Energy Technology Data Exchange (ETDEWEB)

The possible contribution of short rotation cultures (SRC) to carbon sequestration in both current and elevated carbon dioxide concentrations was investigated using the free-air carbon dioxide enrichment (FACE) technique. Three poplar species were grown in an SRC plantation for three growing seasons. Above-ground and below-ground biomass increased by 15 to 27 per cent and by 22 to 38 per cent, respectively; light-efficiency also increased as a result. Depletion of inorganic nitrogen from the soil increased after three growing seasons at elevated carbon dioxide levels, but carbon dioxide showed no effect on stem wood density. Stem wood density also differed significantly from species to species. These results confirmed inter-specific differences in biomass production in poplar, and demonstrated that elevated carbon dioxide enhanced biomass productivity and ...

Energy Technology Data Exchange (ETDEWEB)

Sterile aqueous N-methylaniline solutions were allowed to equilibrate at various nitrite, F-400 granular-activated carbon, and pH levels for 1 week. The aqueous and activated carbon phases were extracted and analyzed for nitrosamines relative to an added internal standard. Selected ion monitoring GC/MS, utilizing continuous monitoring of the NO/sup +/ ion (m/z 29.9980) characteristic of nitrosamines, at medium resolution (R = 2500-3000) was applied to quantitatively measure nitrosamines at picograms per microliter concentrations. This method selected for nitrosamine products only and eliminated interferences from non-nitrosamine reaction products. Results indicate that the pressure of granular-activated carbon significantly enhanced the formation of nitrosamine from N-methyl-aniline (F = 145, P< 0.0001). The amount of N-nitrosomethylaniline formed in the presence of activated carbon was 75 times more ...

Energy Technology Data Exchange (ETDEWEB)

This invention relates to the production method of composite electrode substrate for fuel cell. An impermeable material is used for edge sealant. The sealant is put in the clearance between two electrodes consisting of porous carbon material via thermoplastic resin sheet, and heated while being pressed. This production method increases the adherence between the porous carbon bodies and reduces the contact resistivity at the joint interface. Consequently, it becomes possible to produce the composite electrode for fuel cell without separator, resulting in simplification of assembly work, weight reduction, and downsizing. The preferable porous carbon body is made from shrinkage-treated fiber. After sheet forming, the thermosetting resin is impregnated, and then it is burnt to carbonization. Or mixed sheet of rayon and acrylic fiber is laminated to be heated and pressed without impregnating the resin. The ...

Energy Technology Data Exchange (ETDEWEB)

A stable isotope mass-balance of dissolved inorganic carbon during a blue-green algae bloom in a softwater lake demonstrates that at low partial pressure of carbon dioxide there must be a large net negative carbon isotope fractionation between atmospheric CO/sub 2/ and the CO/sub 2/ absorbed by lake water at pH = 9.5. Chemical enhancement of CO/sub 2/ invasion at high pH by the reaction CO/sub 2/ + OH/sup -/ ..-->.. HCO/sub 3//sup -/ at large apparent film thicknesses may result in carbon isotope fractionation approaching that for a hydroxide solution. This phenomenon, coupled with a decrease in the photosynthetic fractionation, forced the surface water of a softwater lake to achieve increasingly negative delta /sup 13/C values during an algal bloom, which is in the opposite sense to the trend that results from photosynthesis under less extreme conditions. This and other similar systems must operate ...

Energy Technology Data Exchange (ETDEWEB)

Samples of 100Cr6 steel were treated by different ion beams in order to study the evolution of their tribological properties. A strong correlation was found between the amount of surface carbon, whatever its origin (contamination, direct C implantation or ion-beam mixing of a deposited carbon layer), and the reduction of the friction coefficient as well as the improvement of the wear resistance. These results are discussed in the framework of a recent statistical model founded on the asperity concept and describing the tribological behaviour of bilayer systems.

International Nuclear Information System (INIS)

Growing competitiveness of alternative manufacturing routes requires cost minimization in the production of drop forged components. The authors analyse the potential of medium carbon, vanadium microalloyed steels for drop forging. Laboratory and industrial experiments have been carried out emphasizing deformation and temperature cycles, strain rates and dwell times showing a typical processing path, associated mechanical properties and corresponding microstructures. The steels the required levels of mechanical properties on cooling after forging, eliminating subsequent heat treatment. The machinability of V-microalloyed steels is also improved when compared with plain medium carbon steels. (author)