British Library Electronic Table of Contents (United Kingdom)

A highly sensitive and stable tris(2,2prime-bipyridyl)ruthenium(II) (Ru(bpy)32+) electrogenerated chemiluminescence (ECL) sensor was developed based on carbon nanotube (CNT) dispersed in mesoporous composite films of sol-gel titania and perfluorosulfonated ionomer (Nafion). Single-wall (SWCNT) and multi-wall carbon nanotubes (MWCNT) can be easily dispersed in the titania-Nafion composite solution. The hydrophobic CNT in the titania-Nafion composite films coated on a glassy carbon electrode certainly increased the amount of Ru(bpy)32+ immobilized in the ECL sensor by adsorption of Ru(bpy)32+ onto CNT surface, the electrocatalytic activity towards the oxidation of hydrophobic analytes, and the electronic conductivity of the composite films. Therefore, the present ECL sensor based on the CNT-...

British Library Electronic Table of Contents (United Kingdom)

We have investigated the effect of manganese (Mn) doping on properties of nanosized biphasic calcium phosphate powders and their dense bodies. Manganese levels of 0.6, 1.3, 1.9, 4.3, 7.0 and 11.9at.% were successfully incorporated into biphasic calcium phosphate via a sol-gel route. The prepared powders were calcined at temperatures of 500-1200^oC. The X-ray diffraction analysis revealed that a mix phase comprising of hydroxyapatite and @b-tricalcium phosphate were present, however the content of each phases in the structure was affected by the Mn content. The studies found that the largest portion of @b-tricalcium phosphate was detected at 4.3at.% Mn doping. The incorporation of Mn has also greatly increased the crystallinity of the biphasic calcium phosphate powder due to progressive den...

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International Nuclear Information System (INIS)

The sol-gel-immobilized Tris(2,2'-bipyridyl)ruthenium(II) [Ru(bpy)_3 "2"+] electrogenerated chemiluminescence (ECL) sensor was applied to the reversed-phase high-performance liquid chromatography (HPLC) determination of phenothiazine derivatives (promazine, chlorpromazine, triflupromazine, thioridazine, and trifluoperazine) and erythromycin in human urine samples. In this method, Ru(bpy)_3 "2"+ was immobilized in sol-gel-derived titania (TiO_2)-Nafion nanocomposite films coated on a dual platinum electrode. This method eliminates an extra pump needed for the delivery of Ru(bpy)_3 "2"+ reagent into a reaction/observation zone in front of photomultiplier tube because the immobilized-Ru(bpy)_3 "2"+ is recycled on the electrode surface by an applied potential at +1.3 V versus Ag/AgCl (3 M NaCl) reference electrode. The resulting analytical performances such as detection limit, working range, sensitivity, and measurement ...

International Nuclear Information System (INIS)

Buffer layers with 100% lattice match with YBa2Cu3O7 - ? (YBCO) were prepared from mixed rare-earth-oxides applying a simple sol-gel process and dip-coating method. Structural analysis of the sol-gel derived powder by X-ray diffraction revealed that the mixing parameter, which eliminates the lattice mismatch with YBCO, is x = 0.2382, 0.1852, 0.1252, 0.0906, 0.0793 and 0.0395 in (Eu1 - xHox)2O3, (Eu1 - xErx)2O3, (Eu1 - xYbx)2O3, (Gd1 - xHox)2O3, (Gd1 - xYx)2O3 and (Gd1 - xYbx)2O3, respectively. Microstructural investigations were carried out for Gd1.819Ho0.181O3 films epitaxially grown on cube-textured Ni (100) substrates by sol-gel dip-coating process. X-ray diffraction of the buffer showed strong out-of-plane orientation on Ni tape. The (Gd1 - xHox)2O3 (222) pole figure indicated a single cube-on-cube textured structure. The omega and phi scans revealed good out-of-plane and in-plane alne alignments. ...

International Nuclear Information System (INIS)

A highly sensitive and stable tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)_3 "2"+) electrogenerated chemiluminescence (ECL) sensor was developed based on carbon nanotube (CNT) dispersed in mesoporous composite films of sol-gel titania and perfluorosulfonated ionomer (Nafion). Single-wall (SWCNT) and multi-wall carbon nanotubes (MWCNT) can be easily dispersed in the titania-Nafion composite solution. The hydrophobic CNT in the titania-Nafion composite films coated on a glassy carbon electrode certainly increased the amount of Ru(bpy)_3 "2"+ immobilized in the ECL sensor by adsorption of Ru(bpy)_3 "2"+ onto CNT surface, the electrocatalytic activity towards the oxidation of hydrophobic analytes, and the electronic conductivity of the composite films. Therefore, the present ECL sensor based on the CNT-titania-Nafion showed improved ECL sensitivity for tripropylamine (TPA) compared to the ECL sensors based on both titania-Nafion composite films without CNT and pure ...

British Library Electronic Table of Contents (United Kingdom)

N-doped TiO2 has been prepared by use of sol?gel systems containing titanium alkoxide, with nitric acid as the nitrogen source. The time needed for gelation of the systems was drastically reduced by ultrasonic irradiation. The peaks assigned to the nitrate and nitrous ions were observed by FT-IR measurement during the sol?gel reaction. The N-doping was confirmed by the observation of N?O peaks in the XPS spectrum of the sample heated at 400??C. The nitrate ion acted as an oxidizer of the ethanol solvent and titanium species. The TiO2 became doped with nitrogen oxide species as a result of reduction of nitrate ion incorporated into the dried gel samples. These results indicated that the added nitric acid was reduced during the sol?gel transition and heating process, and the resulting NO spe...

British Library Electronic Table of Contents (United Kingdom)

Mesoporous V2O5/Nafion composite films have been used for the immobilization of tris(2,2prime-bipyridyl)ruthenium (II) (Ru(bpy)$\\rm{ {_{3}^{2+}}}$) on an electrode surface to yield a solid-state electrogenerated chemiluminescence (ECL) sensor. The electrochemical and ECL behavior of Ru(bpy)$\\rm{ {_{3}^{2+}}}$ ion-exchanged into the composite films has been characterized as a function of the amount of Nafion incorporated into the V2O5/Nafion composite. The composite film with 80% Nafion content has the largest pore diameter (4.19 nm) and yields the maximum ECL response for tripropylamine (TPA) because of the fast diffusion of analyte into the film with large pores. Due to the enlarged pore size and enhanced conductivity of the V2O5/Nafion composite, the present ECL sensor based on the compo...

British Library Electronic Table of Contents (United Kingdom)

In this project, nanocrystalline SnO2 powders were successfully prepared by (a) citrate sol-gel and (b) direct precipitation methods. Powders were characterized using thermal analysis techniques (DTA-TG-DSC), X-ray powder Diffraction (XRD), surface area (BET) and electrical conductivity measurements. XRD patterns showed the presence of the cassiterite structure. SnO2 particles, prepared through sol-gel method exhibit crystallite sizes in the range from 3.1 to 22.3 nm when the gel is heat treated at different temperatures up to 900?C. SnO2 nanocrystallites prepared by the precipitation method are comparatively larger in size. The higher specific surface area was obtained for the powder prepared using sol-gel method and the obtained average grain size (d) is relatively large compared with th...

Energy Technology Data Exchange (ETDEWEB)

LaAlO{sub 3} and CeO{sub 2} films have been successfully grown using sol-gel precursors. LaAlO{sub 3} precursor solution has been prepared from a metal alkoxide route and spun-cast on a SrTiO{sub 3} (100) single crystal to yield an epitaxial film following pyrolysis at 800{degrees}C in a rapid thermal annealer. A CeO{sub 2} precursor solution has been made using both an aqueous and an alkoxide route.

Science.gov (United States)

Calcium stannate (CaSnO3) powders with the distorted perovskite structure have been synthesized by solid state and the sol-gel methods and their electrochemical performance was compared. The sol-gel CaSnO3 shows stable cycling performance with a reversible capacity of 430-440 mAh/g (0.005-1.0 V; 60 mA/g) up to 50 cycles. The role of preparatory conditions, morphology and cycling conditions (current density and potential window) on the anodic performance of the compounds are addressed.

International Nuclear Information System (INIS)

Hybrid organic-inorganic coatings with phosphonate functionalities have been synthesized and evaluated as prospective surface treatments for magnesium materials. These coatings have been processed via a sol-gel route by hydrolysis and condensation of a mixture of diethylphosphonatoethyltriethoxy-silane and tetraethoxy-silane with variable molar ratios. The coatings morphology and the surface chemistry at the coating/substrate interface have been characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, "3"1P nuclear magnetic resonance spectroscopy, and time-of-flight secondary ion mass spectrometry. The corrosion protection performance of the coatings deposited on magnesium alloy AZ31B has been examined by a group of electrochemical techniques including potentiodynamic polarization and electrochemical impedance spectroscopy. In addition, a scanning Kelvin probe technique has been used to investigate interfacial properties of the coatings. ...

International Nuclear Information System (INIS)

The intensity of erbium up-conversion luminescence could be limited by a saturation effect due to increased pump power. We studied the luminescence saturation of the 550 nm emission on erbium-doped, SiO_2-TiO_2 sol-gel powders under pulsed excitation at 979 and 1532 nm. From the latter, the up-converted luminescence intensity decreased with increasing excitation power, whereas no saturation was observed at 979 nm excitation. We proposed that the saturation effect is determined by the pump power, the erbium content and the lifetime of the corresponding first excited states at different pumping schemes.

British Library Electronic Table of Contents (United Kingdom)

Silica-reinforced natural rubber (NR) composite was prepared by using tetraethoxysilane (TEOS) as a precursor to generate silica particles inside the rubber. The silica was generated in situ by the sol-gel process of TEOS that was mixed directly into commercial-graded NR latex having 60% dry rubber content and 0.7% ammonia. The conversions of TEOS to silica inside the rubber were ranging from 90 to 97%. The silica particles dispersed evenly without extensive aggregation with sizes between 100 and 500 nm, as determined by scanning electron microscopy (SEM). An experimental design methodology, namely "two-level factorial design," was used to evaluate the influence of the amounts of TEOS, ammonia, and gelation time on the tensile modulus, tensile strength, and tear strength of the vulcanizate...

British Library Electronic Table of Contents (United Kingdom)

In this study a novel sol-gel auto-combustion method, using n-decyltrimethylammonium bromide as a cationic surfactant, has been used to synthesize strontium hexaferrite nanocrystalline powder. The dried nitrate-citrate gel, prepared from a solution of ferric nitrate, strontium nitrate, citric acid, trimethylamine and cationic surfactant, exhibited an auto-combustion behavior after ignition in air. The formation reaction temperature, phase identification, crystallites size, particles size distribution and morphology of resultant strontium hexaferrite powder were investigated by DTA/TGA, FTIR, XRD, LPSA, TEM and SEM techniques. The results showed that in presence of the cationic surfactant, the combustion intensity increases and the crystallite size decreases. The crystallite size of stronti...

British Library Electronic Table of Contents (United Kingdom)

To improve the photocatalytic application performances of TiO2, in this work, firstly CdS modified Degussa P25 TiO2 (CdS/TiO2) composites were prepared by two methods, sol-gel method and precipitation method. Next they, sol-gel-CdS/TiO2 (sg-CdS/TiO2) and precipitation-CdS/TiO2 (pp-CdS/TiO2), were loaded on activated carbon fibers (ACFs) by dip-coating method using the sodium carboxymethyl cellulose as adhesives. The composites were characterized by XRD, UV-vis absorbance spectra, SEM, EDS and BET. The photocatalytic activities under sunlight were investigated by the degradation of methylene blue. The results showed that CdS/TiO2 composites were mainly composed of anatase-TiO2 and little CdS cubic phases. The absorption wavelengths of sg-CdS/TiO2 and pp-CdS/TiO2 composites were extended to ...

British Library Electronic Table of Contents (United Kingdom)

The nanostructure Ni-doped CdO films have been prepared by sol gel spin coating method. Atomic force microscopy results indicate that the CdO films are formed from the nanoparticles and the grain size is changed with nickel content. X-ray diffraction patterns of the films indicate that the undoped and Ni-doped CdO films have polycrystalline structure with a cubic sodium chloride structure, showing two main characteristic peaks assigned to the (111) and (200) planes. The optical band gap values of undoped and Ni-doped CdO films were determined by optical absorption method. The Eg values of the CdO films were found to be in the range of 2.26?2.60?eV. The Eg values of the CdO films increase with the content of Ni dopant (up to 6% Ni). It is evaluated that the optical band gap and grain size o...

International Nuclear Information System (INIS)

The nanosized luminescent Tb-MCM-41 (1:10) is synthesized by means of sol-gel-assisted self-assembly under basic conditions at room temperature. The results of "2"9Si-MAS NMR and XRD prove that Tb"3"+ doped Si-O framework. The HRTEM image shows that the regular uniform particles with a diameter of 10 nm possess ultralarge pore with diameter 2.0 nm, which is consistent with the result of N_2 adsorption. The BET surface area and porosity of Tb-MCM-41 (1:10) are 1127 m"2/g and 0.84 cm"3/g, respectively. The patterns of selected-area electron diffraction and XRD of Tb-MCM-41 (1:10) show an Fm3m space group in the cubic. FT-IR results show that the peaks near 970 cm"-"1 are assigned to the deformation vibration of silanol group. The as-products are calcined at 800 deg. C and the mesoporous materials possess enormous specific areas and large porosity, it shows that the mesoporous materials are ultrastable.

Science.gov (United States)

With the help of self-assembly, thermal sintering, selective etching techniques and sol-gel process, the non-close packed (ncp) face-centered cubic (fcc) photonic crystals of titanium dioxide (TiO2) hollow spheres connected by TiO2 cylindrical tubes have been fabricated using silica template. The photonic bandgap calculations indicate that the ncp structure of TiO2 hollow spheres was easier to open the pseudogaps than close packed system at the lowest energy. PMID:17097102

Science.gov (United States)

The liquid-phase synthesis of metal oxide nanoparticles in organic solvents under exclusion of water is nowadays a well-established alternative to aqueous sol-gel chemistry. In this article, we highlight some of the advantages of these routes based on selected examples. The first part reviews some recent developments in the synthesis of ternary metal oxide nanoparticles by surfactant-free nonaqueous sol-gel routes, followed by the discussion of the morphology-controlled synthesis of lanthanum hydroxide nanoparticles, and the presentation of structural peculiarities of manganese oxide nanoparticles with an ordered Mn vacancy superstructure. These examples show that nonaqueous systems, on the one hand, allow the preparation of compositionally complex oxides, and, on the other hand, make use of the organic components (initially present or formed in situ) in the reaction mixture to tailor the morphology. Furthermore, obviously even the crystal ...

British Library Electronic Table of Contents (United Kingdom)

Fluoroalkyl end-capped vinyltrimethoxysilane oligomer suffered the sol-gel reaction under alkaline conditions in the presence of titanium oxide nanoparticles in tetrahydrofuran to afford the corresponding fluorinated oligomer/titanium oxide nanocomposites[RF-(VM-SiO2)n-RF/TiO2] in excellent to moderate isolated yields. These fluorinated composites thus obtained were nanometer size-controlled fine particles, and exhibited good dispersibility and stability in traditional organic solvents except for water. These fluorinated nanocomposites were applied to the surface modification of glass to exhibit not only a completely superhydrophobic characteristic (a water contact angle: 180degree) with a non-wetting property against water droplets but also a good oleophobicity imparted by fluoroalkyl seg...

British Library Electronic Table of Contents (United Kingdom)

Alumina-reinforced carbon nanofiber nanocomposites were prepared using different routes; powders mixture, colloidal route and sol?gel process followed by spark plasma sintering (SPS). CNFs/xAl2O3 (x = 10?50 vol.%) were prepared through nanopowders mixing in a high-energy attrition milling. The main limitations in the preparation of this kind of nanocomposites are related to the difficulty in obtaining materials with a homogeneous distribution of both phases and the different chemical nature of CNFs and Al2O3, which causes poor interaction between them. A surface coating of CNFs by wet chemical routes with an alumina precursor is proposed as a very effective way to improve the interaction between CNFs and Al2O3. An improvement of 50% in fracture strength was found for similar nanocomposite ...

Scientific Electronic Library Online (English)

Abstract in english Ru(1%)/SiO2 and Cu(1%)Ru(1%)/SiO2 catalysts were prepared by cogelation. The effect of pH and the amount of water on the physical-chemical properties and the catalytic properties of them were analyzed. The acid medium increased the formation of microporosity and the formation of small size of metallic ruthenium particle. The variation of the water quantity used in the gelation not modify considerably the texture neither the dispersion of the noble metal. The reduction lev (more) el of all prepared catalyst was similar, showing displacement in some of reduction peaks. The toluene hydrogenation indicated that the conversion and the quantity of hydrogenate product varied with the pH and the quantity of water used in the gelation. The addition of copper to Ru/SiO2 catalysts diminished the reactive conversion and their hydrogenant activity

Energy Technology Data Exchange (ETDEWEB)

The entrapment of proteins using the sol-gel route provides a means to retain its native properties and artificially reproduce the molecular crowding and confinement experienced by proteins in the cell allowing investigation of the physico-chemical and structural properties of biomolecules at the biotic/abiotic interface. The biomolecules are spatially separated and 'caged' in the gel structure but solutes can freely permeate the matrix. Thus, properties such as the folding of ensembles of individual molecules can be examined in the absence of aggregation effects that can occur in solution studies. Green fluorescent protein from Aequorea coerulescens was used as a model protein to examine the unfolding/re-folding properties of protein in silica gels. The recombinant protein was isolated and purified from Escherichia coli extracts by cell lysis, three-phase partitioning, dialysis, and anion exchange chromatography. The purity of the protein was ...

Energy Technology Data Exchange (ETDEWEB)

Nb{sub 2}O{sub 5} thin films were formed on aluminum foils by a sol-gel process in order to increase the capacitance of the aluminum foils which are used as aluminum electrolytic capacitors. Investigations focussed on the preparation and characterization of the coating solution, the formation of Nb{sub 2}O{sub 5} thin films on aluminum foils, and the heat treatment and anodization of the films. The phase transition and electrical properties, such as capacitance, leakage current, and withstand voltage of the Nb{sub 2}O{sub 5} thin films were also measured. The Nb{sub 2}O{sub 5} thin films annealed at temperatures below 550 degree C were found to be amorphous, but they were crystallized to the orthorhombic phase by annealing at temperatures higher than 580 degree C. The capacitance of the coated samples increased with an increase in the thickness of the formed Nb{sub 2}O{sub 5} thin films, but an increase in leakage current and a decrease in withstand voltage were ...

Energy Technology Data Exchange (ETDEWEB)

Y{sub 2-x}Tb{sub x}SiO{sub 5} and Y{sub 2-x}Eu{sub x}SiO{sub 5} nanophosphors with seven different kinds of silicate sources were synthesized by sol-gel method. The structures have been investigated to be composed of nanometer-size grains of 30-60 nm through X-ray diffraction (XRD) and scanning electron microscopy (SEM) was used to compare the different morphology of patterns from seven different silicon sources. The photoluminescence of Y{sub 2-x}Tb{sub x}SiO{sub 5} was investigated as a function of silicate sources and the results revealed that these nanometer materials showed the characteristic emission {sup 5}D{sub 4} {yields} {sup 7}F{sub J} (J 6, 5, 4, 3) of Tb ions. The characteristic emission {sup 5}D{sub 0} {yields} {sup 7}F{sub J} (J = 1, 2, 4) of Eu ions was also found in the materials of Y{sub 2-x}Eu{sub x}SiO{sub 5}.

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Silica and bridged polysilsesquioxane aerogels are low-density materials that are attractive for applications such as thermal insulation, porous separation media or catalyst supports, adsorbents, and cometary dust capture agents. However, aerogels are notoriously weak and brittle making it difficult to handle and machine monoliths into desired forms. This complication prevents the development of many applications that would otherwise benefit from the use of the low-density materials. Here, we will describe our efforts to chemically modify and mechanically enhance silica-based aerogels using chemical vapor techniques without sacrificing their characteristic low densities. Monolithic silica and organic-bridged polysilsesquioxane aerogels were prepared by sol-gel polymerization of the respective methoxysilane monomers followed by supercritical carbon dioxide drying of the gels. Then the gels were reactively modified with silylating agents to demonstrate the viability ...

Energy Technology Data Exchange (ETDEWEB)

There has been considerable interest in producing and studying nanoparticle materials because of the effect of size on their structure, physical and chemical structure. Most studied nanoparticle semiconductors belong to the II-VI group, as they are relatively easy to synthesize and are generally prepared as particulates or in thin film form. Among II-VI compounds, CdS is one of the most studied materials. There are different ways to synthesize CdS nanoparticles such as colloidal particles, chemical decomposition, sol-gel, gas evaporation, magnetron sputtering, electrostatic deposition, and etc. {gamma}-irradiation is one of the effective methods for synthesis of nanomaterials. These nonomaterials have been extensively used in the preparation of nanocrystalline metals, metal oxides, and metal-polymer composites. However, The preparation of CdS nanoparticle and CdS/ polyacrylonitrile nanocomposite by {gamma}-irradiation method at room temperature and ambient ...

British Library Electronic Table of Contents (United Kingdom)

Ferroelectric barium strontium titanate (Ba0.7Sr0.3TiO3)(BST) thin films have been prepared from barium 2-ethylhexanoate [Ba[CH3(CH2)3CH(C2H5)CO2]2], strontium 2-ethylhexanoate [Sr[CH3(CH2)3CH(C2H5)CO2]2] and titanium(IV) isopropoxide [TiOCH(CH3)2]4 precursors using a modified sol-gel technique. The precursor except [TiOCH(CH3)2]4 were synthesized in the laboratory. Transparent and crack-free films were fabricated on pre-cleaned quartz substrates by spin coating. The structural and optical properties of films annealed at different temperatures have been investigated. The as-fired films were found to be amorphous that crystallized to the tetragonal phase after annealing at 550degreeC for 1h in air. The lattice constants "a" and "c" were found to be 3.974A and 3.990A, respectively. The grain...

Energy Technology Data Exchange (ETDEWEB)

One of the alternative ideas to solve the spent fuel issues, the partitioning and transmutation (P and T) technology has been developed for decades. Moreover, the concept of LILW production from P and T are proposed by Bowman. A PEACER (Proliferationresistant, Environmental-friendly Accident-tolerant, Continuable and Economical Reactor), based on pyrochemical process and Pb-Bi coolant transmutation reactor, has been conceptually designed to be able to convert all PWR spent fuel into low and intermediate level waste for near-surface disposal. In this study, the acceptance criteria for near-surface disposal facility is derived by the methodology for establishment of acceptance criteria. Then acceptable TRU decontamination factor (DF) and LLFP removal efficiency in order to meet acceptance criteria is evaluated.

International Nuclear Information System (INIS)

The main objective of this paper is to identify conditions which affect public concern (either increase or decrease) and political acceptance for developing and implementing programmes for geologic disposal of long-lived radioactive waste. It also looks how citizens and relevant actors can be associated in the decision making process in such a way that their input is enriching the outcome towards a more socially robust and sustainable solution. Finally, it aims at learning from the interaction how to optimise risk management addressing needs and expectations of the public and of other relevant stakeholders. In order to meet these objectives, factors of relevance for societal acceptance conditions are identified, described and analysed. Subsequently these factors are looked for in the real world of nuclear waste management through cases in several countries. The analysis is conducted for six stages of a repository programme and implementation ...

International Nuclear Information System (INIS)

Transparent aluminum doped zinc oxide (ZnO:Al, AZO) conducting thin films with a high-preferential c-axis orientation were synthesized using a new sol-gel formula. The films were deposited using a spin-coating route onto borosilicate glass substrates. We used propylene glycol methyl ether (PGME) as the solvent in place of ethylene glycol monomethyl ether (EGME), which is commonly used because it is easier to deposit onto the substrates. PGME is also superior in terms of health and safety. PGME solvent does not need to settle for several days before use and can be spin-coated as soon as the raw material and solvent are mixed. The effects of this novel solvent on the structural, morphological, electrical and optical properties are discussed using XRD, SEM, a four-point probe and UV-VIS spectrophotometry. It was found that the films produced with PGME showed a high-preferential c-axis orientation and compact microstructure in comparison films produced using EGME. The ...

Energy Technology Data Exchange (ETDEWEB)

Nano-particles of CeO{sub 2} with the smallest average particle size (18.7 nm) and spherical morphology were obtained from a mixture solution of Ce(NO{sub 3}){sub 3}{center_dot}6H{sub 2}O, citric acid, polyvinyl alcohol by an auto-combustion process exploiting sol-gel as precursors. The course of size control and shape control by polyvinyl alcohol was examined in detail. A transmission electron microscopy (TEM) and an atomic force microscopy (AFM) were employed to characterize the particle-size and morphology of CeO{sub 2} particles. In addition, a sort of nano-metric solid acid SO{sub 4}{sup 2-}/CeO{sub 2} based on CeO{sub 2} nano-particles was prepared by macerating, filtering, drying and calcining processes. The particle-size of SO{sub 4}{sup 2-}/CeO{sub 2} was also assessed by TEM. The composition of SO{sub 4}{sup 2-}/CeO{sub 2} was analyzed by X-ray diffraction (XRD) and infrared spectra (IR). The influencing factors in the formation of SO{sub 4}{sup ...

Energy Technology Data Exchange (ETDEWEB)

Thin solid films of CeO[sub 2] and mixed CeO[sub 2]-TiO[sub 2] were prepared by the sol-gel route via the dip-coating technique. Particulate sols of ceria were made from inorganic ((NH[sub 4])[sub 2]Ce(NO[sub 3])[sub 6]) precursor which were used for preparation of CeO[sub 2] thin solid films while CeO[sub 2]-TiO[sub 2] coatings have been made by using mixed organic-inorganic (Ti(OiPr)[sub 4] and CeCl[sub 3].7H[sub 2]O) precursors. The solar transmission values (T[sub s]) of both coatings are in the range 0.6-0.8 and depend on coating thickness. Cyclic voltammetric (CV) measurements show that the CeO[sub 2]/LiOH system exhibits higher overall electrochemical reversibility when compared to the CeO[sub 2]-TiO[sub 2]/LiOH system. The CeO[sub 2]/LiOH system is also less sensitive with regard to the coating thickness. Coulometric measurements show that CeO[sub 2] exhibits a larger storage capability which was determined as a function of the coating thickness. ...

Energy Technology Data Exchange (ETDEWEB)

V{sub 2}O{sub 5} based compounds are interesting low potential materials for rechargeable cathodes of lithium electrochemical generators. However, the ionic conductivity and the reversibility of electrochemical cycling of V{sub 2}O{sub 5} are limited by the possibilities of lithium insertion. This work shows that the doping of vanadium pentoxide by a M{sup 3+} trivalent transition element (M Fe, Al, Cr or La) allows to intercalate a more important amount of lithium and to improve the behaviour of the material during cycling. These materials of M{sub 0.11}V{sub 2}O{sub 5.16} formula are obtained by sol-gel synthesis. the electrochemical study of the Fe compound has shown that it is a mixed oxide with a behaviour similar to V{sub 2}O{sub 5}. The maximum capacity is of about 2 F/mole in the case of Fe, Al and Cr compounds and of about 1.7 F/mole in the case of La. The structural evolution of the Fe compound has been followed during the chemical insertion of Li and the ...

International Nuclear Information System (INIS)

Iron doped semiconducting nanoparticles Sn1-xFexO2 with x=0, 0.001, 0.002, 0.003, 0.004, 0.01 and 0.03 were prepared by a sol-gel method. The X-ray diffraction, Transmission Electron Microscopy measurements confirm the rutile structure with no impurity phase. The three characteristic lines of electron spin resonance (ESR) are observed in the doped samples for all compositions, which is a clear evidence for rhombic Fe3+ in rutile phase. The line width of ESR increases with increase in Fe concentration due to induced disorder. The spin-pumping effect is observed at temperatures below 250 K for the samples with x=0.01 and 0.03. However, based on the Curie-Weiss susceptibility, iron is in paramagnetic state and is subject to weak antiferromagnetic interaction. Blue shift in the optical band gap is observed with increase in the Fe content. -- Graphical abstract: The ESR spectra reveal that the nature of Fe in Sn1-xFexO2 samples is isolated rhombic Fe3+-ion in rutile ...

International Nuclear Information System (INIS)

Graphical abstract: Ordered mesoporous organic-inorganic composite film has been achieved by sol-gel and spin-coating techniques. We believe that the mesoporous composite films have a potential application as a protect coating of bipolar plate material. Display Omitted Research highlights: ? Ordered mesoporous composite film was deposited on the 304 stainless steel. ? This composite film exhibited excellent protective performance in 0.5 M H_2SO_4. ? The film exhibited a high surface tension with water contact angle close to 90"o. - Abstract: The organic-inorganic composite film was deposited on the 304 stainless steel as bipolar plate material for proton exchange membrane fuel cells by spin-coating method. As shown by XRD, N_2 adsorption-desorption and TEM, the composite films exhibit ordered mesoporous structures. The corrosion tests in 0.5 M H_2SO_4 system displayed that, compared with 304SS, the composite films made corrosion potential shifted to positive ...

Energy Technology Data Exchange (ETDEWEB)

A new thin film manufacturing method is established to add a function to glass material surface, as a new material technology which harmonizes with global environment, and is suitable for resource re-utilization and energy conservation. It is intended to develop a leading technology to promote recycling of colored glasses by applying this technical method to colored glasses. Fiscal 1998 has implemented subsequently to fiscal 1997 the following subjects in the three research items composed of a new manufacturing method of functional thin films, application of the functional thin films to colored glasses, and the comprehensive investigative studies: establishment of an industrial manufacturing method for color coating liquid and evaluation of basic characteristics of the colored functional thin films, optimization of element technology for photo-sensitive gel films by means of chemically modifying metallic alkoxide, tests of forming films on glass bottles and plate glasses by using a ...

Energy Technology Data Exchange (ETDEWEB)

An estimated 265 million tons of hazardous waste are generated annually in the United States. Traditional waste disposal methods are inadequate, and many are no longer environmentally acceptable. Still, the waste increases along with demands for clean, environmentally safe methods for dealing with it. Faced with these demands, many hazardous waste generators are turning for help to co-processing,'' technology that goes beyond a no-impact solution to one of net positive impact, both environmentally and economically. This paper describes co-processing.

Science.gov (United States)

ACCEPTING THE CHALLENGE: EXAMINING INFANTRY AND MILITARY POLICE EMPLOYMENT OF COMPETENCIES ON THE TWENTY-FIRST ...

Energy Technology Data Exchange (ETDEWEB)

This study was undertaken to determine if a combined treatment (marinating in natural plant extracts or vacuum) with irradiation could have a synergistic effect, in order to prevent the lipid oxidation resulting in the development of undesirable flavours. The fresh chicken legs were irradiated at 0,3 and 5 kGy. The fatty acids composition of lipids was identified using gas liquid chromatography. The effect of irradiation treatment combined with a pre-treatment on the fatty acids composition was followed. The day after irradiation, ten panallists were asked to evaluate, using the instruction scaling, the overall appearance, the odor, the flavor and the overall acceptability of the samples. The major fatty acids identified in lipids were oleic acid, palmitic acid, palmitoleic acid and stearic acid. Pre-treatments have a significant effect on linoleic acid (C18:2) and higher fatty acids. The unsaturated fatty acids derived from phospholipids ...

International Nuclear Information System (INIS)

There are several radioactive source terms in nuclear power plant's design and construction. The radioactivity source in systems and components is derived from the reactor coolant activity and provide the parameters used to determine secondary system equilibrium activities and annually releasing amounts to environment. The reactor coolant activity standard(ANSI-Nl8.l) had been periodically revised. In Korea, the utility should do the PSR for NPP's. The objective of PSR is to determine by means of a comprehensive assessment of an existing nuclear power plant to what extent the plant meets current internationally accepted safety standards and practices. So, Kori 3 NPP's reactor coolant activity is reviewing with the anticipated source terms. The comparative results of RCS average activity is lower one fifth (1/5) #approx# one tenth(1/10) than ANSI/ANS N18.1-1999.

CERN Document Server

In this review, I concentrate on describing observations of spatially resolved emission in symbiotic stars at sub-arcsecond scales. In some of the closer objects, the highest resolutions discussed here correspond to linear dimensions similar to the supposed binary separation. A total of 17 stars well accepted as symbiotics are now observed to show sub-arcsecond structure, almost twice the number at the time of the last review in 1987. Furthermore, we now have access to HST imagery to add to radio interferometry. From such observations we can derive fundamental parameters of the central systems, investigate the variation of physical parameters across the resolved nebulae and probe the physical mechanisms of mass loss and interactions between ejecta and the circumstellar medium. Suggestions for future work are made and the potential of new facilities in both the radio and optical domains is described. This review complements that by Corradi (this ...

Energy Technology Data Exchange (ETDEWEB)

Components of various forest and agricultural residue biomass-including the polyphenolic compounds-were converted into aqueous solution and/or suspension by extraction and digestion. Some biomass components reacted vigorously under alkaline catalysis with formaldehyde and initially showed a high degree of exothermic reaction; however, other components did not react as vigorously under these conditions, indicating that different biomass materials require different methods to obtain optimum reactivity for the copolymerization with phenol. Our primary goal is to develop adhesives capable of producing acceptable bond quality, as determined by the wood products industries` standards, under a reasonable range of gluing conditions. Copolymer resins of phenol, formaldehyde, and biomass components were synthesized and evaluated for gluability of bonding exterior grade structural replaced with chemicals derived from peanut hulls, pecan shell flour, pecan ...

International Nuclear Information System (INIS)

Due to the failure of the instrument and control devices of nuclear power plants caused by aging, nuclear power plants occasionally trip. Even a trip of a single nuclear power plant (NPP) causes an extravagant economical loss and deteriorates public acceptance of nuclear power plants. Therefore, the replacement of the instrument and control devices with proper consideration of the aging effect is necessary in order to prevent the inadvertent trip. In this paper we investigated the optimal replacement periods of the control computer's components of Wolsung nuclear power plant Unit 1. We first derived mathematical models of optimal replacement periods to the digital control computer's components of Wolsung NPP Unit 1 and calculated the optimal replacement periods analytically. We compared the periods with the replacement periods currently used at Wolsung NPP Unit 1. The periods used at Wolsung is not based on mathematical analysis, but on ...

J-STORE (Japan)

Full Text Available

International Nuclear Information System (INIS)

The author describes the purpose, classification and main process of acceptance test of full scope simulator of Daya Bay Nuclear Power Plant, including the correction of non-conformance items which are discovered during the performance of acceptance tests. The results of the acceptance tests show that the model accepted by the full scope simulator of Daya Bay Nuclear Power Plant is fully able to cope with the simulation of normal transients and incidental transients and the performance of the simulator indeed compiled with the technical specifications which are defined n the relevant contracts.

Science.gov (United States)

... Abstract : Two traces in flexible cables used in the Milstar agile beam antenna system failed during acceptance testing. ...

Energy Technology Data Exchange (ETDEWEB)

All these summaries will be included in the database from the published literature sources. (PSB)

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

The economic value of environmental goods is commonly determined using the concepts of willingness to pay (WTP) or willingness to accept (WTA). However, the WTP/WTA observed in different countries (or between individuals) will differ according to socio-economic characteristics, in particular income. This notion of differentiated values for otherwise identical goods (say, a given reduction in mortality risk) has been criticized as unethical, most recently in the context of the 'social cost' chapter of the IPCC Second Assessment Report. These critics argue that, being a function of income, WTP/WTA estimates reflect the unfairness in the current income distribution, and for equity reasons uniform per-unit values should therefore be applied across individuals and countries. This paper analyses the role of equity in the aggregation of climate change damage estimates, using basic tools of welfare economics. It shows one way of how WTP/WTA estimates can be corrected in ...

Energy Technology Data Exchange (ETDEWEB)

The availability of polysilicon feedstock has become a major issue for the photovoltaic (PV) industry in recent years. Most of the current polysilicon feedstock is derived from rejected material from the semiconductor industry. However, the reject material can become scarce and more expensive during periods of expansion in the integrated-circuit industry. Continued rapid expansion of the PV crystalline-silicon industry will eventually require a dedicated supply of polysilicon feedstock to produce solar cells at lower costs. The photovoltaic industry can accept a lower purity polysilicon feedstock (solar-grade) compared to the semiconductor industry. The purity requirements and potential production techniques for solar-grade polysilicon have been reviewed. One interesting process from previous research involves reactive gas blowing of the molten silicon charge. As an example, Dosaj et all reported a reduction of metal and boron impurities from ...

Science.gov (United States)

This study presents a novel approach to modeling the electrocardiogram (ECG): the Gaussian pulse decomposition. Constituent waves of the ECG are decomposed into and represented by Gaussian pulses using an iterative algorithm: the chip away decomposition (ChAD) algorithm. At each iteration, a nonlinear minimization method is used to fit a portion of the ECG waveform with a single Gaussian pulse, which is then subtracted from the ECG waveform. The process iterates on the resulting residual waveform until the normalized mean square error is below an acceptable level. Three different minimization methods were compared for their applicability to the ChAD algorithm; the Nelder-Mead simplex method was found to be more noise-tolerant than the Newton-Raphson method or the steepest descent method. Using morphologically different ECG waveforms from the MIT-BIH arrhythmia database, it was demonstrated that the ChAD algorithm is capable of modeling not only normal beats, but ...

International Nuclear Information System (INIS)

Purpose: An inverse treatment planning algorithm for tomotherapy is described. Methods and Materials: The algorithm iteratively computes a set of nonnegative beam intensity profiles that minimizes the least-squares residual dose defined in the target and selected normal tissue regions of interest. At each iteration the residual dose distribution is transformed into a set of residual beam profiles using an inversion method derived from filtered backprojection image reconstruction theory. These 'residual' profiles are used to correct the current beam profile estimates resulting in new profile estimates. Adaptive filtering is incorporated into the inversion model so that the gross structure of the dose distribution is optimized during initial iterations of the algorithm, and the fine structure corresponding to edges is obtained at later iterations. A three dimensional, kernel based, convolution/superposition dose model is used to compute dose during each iteration. ...

UK PubMed Central (United Kingdom)

The evaluation of biological markers is recognized as necessary to the future of toxicology, epidemiology, and quantitative risk assessment. For biological markers to become widely accepted, their validity...Full Text Available

Science.gov (United States)

15 to 75% of the gun barrel diameter. Similarly, model masses typically vary from 0.01 to 100 .... taining acceptable levels of gun barrel erosion. The ...

International Nuclear Information System (INIS)

(1978). United States Hukai, D. Boston Univ., MA Simmons, RE Hukai, RY

UK PubMed Central (United Kingdom)

Absolute measurements of cerebral blood flow (CBF) are an important endpoint in studies of cerebral pathophysiology. Currently no accepted method exists for in vivo longitudinal...Full Text Available

UK PubMed Central (United Kingdom)

The Mitochondrial Free Radical Theory of Aging (MFRTA) is currently one of the most widely accepted theories used to explain aging....Full Text Available

Science.gov (United States)

... 2. Help women become accepted by providing job-related training, creating flexible work groups with good climates, and encourage supervisors to ...

Science.gov (United States)

Valve Flow Characteristics. 3-68. 3-40. Valve Operating Current Vs. Temperature ...... VALVE FLOW CHARACTERISTICS. Acceptance Test 4/29/74. SINs 002 & 004 ...

UK PubMed Central (United Kingdom)

U.v.-visible-absorption and e.p.r. spectroscopy were used to study the type 2 and type 3 copper centres in the mercury derivative of laccase. After treatment with peroxide the mercury derivative of...Full Text Available

Science.gov (United States)

Binary mixtures of dipyrone and pitophenone hydrochloride are assayed by zero-crossing second- and third-derivative spectrophotometry and by ratio-spectra first- and second-derivative spectrophotometry. In the first method, calibration plots are linear at 266.5 and 302.5 nm (dipyrone, second derivative), and 257 and 286 nm (pitophenone second derivative) and 242 and 278.3 nm (dipyrone third derivative), and 228.5 and 300 nm (pitophenone, third-derivative). By the second method, lines of regression are linear at 235 and 262 nm (dipyrone, first derivative), and 229.5 and 288.5 nm (pitophenone, first-derivative), and 249.7 and 268 nm (dipyrone, second derivative), and 280.5 and 300 nm (pitophenone, second-derivative). In all methods calibration curves follow the Beer's law up to 40 ...

Science.gov (United States)

Traditionally, market researchers have sought some formula to predict the acceptance of a new product or innovation in advance of its introduction. Perhaps a universal marketing formula will never be found. However, a summary of 3000 research studies, conducted in the United States and in other countries of the world, on how people accept new ideas promises more insight into the subject of the marketing of passive design and products than ever before.

Energy Technology Data Exchange (ETDEWEB)

The acceptances to be obtained during the first operational run, refer to measures proving the functional integrity of the turbine control system and assuring the compliance with the maximum allowable overspeed in case of lead changes or perturbations. The Guideline concerns essentially speed, power, and pressure controllers coupled to generators. It may be appropriately extended to steam turbines serving other purposes.

International Nuclear Information System (INIS)

Brief item.

International Science & Technology Center (ISTC)

Development the New Effective Pesticides in the Series of Pyrimine and Sym-Triazine Derivatives

J-STORE (Japan)

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Science.gov (United States)

Not Available

Science.gov (United States)

No Abstract Available

J-STORE (Japan)

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Energy Technology Data Exchange (ETDEWEB)

The usefulness of radioiodination via demetallation of aryltrimethylsilanes was demonstrated. The radioiodination reaction was found to be very rapid and the regiospecific incorporation of radioiodine could be carried out with high radiochemical yields and high radiospecific activity. {sup 125}I-Labeled dimethylaminoethyl iodophenoxyacetate derivatives (5a-e), dimethylaminoethyl iodophenoxyacetamide derivatives (7a-c), iodophenoxyethyl ethylenediamine derivatives (9,14) and an iodophenoxyethylpiperazine derivative (18) were efficiently synthesized from the corresponding aryltrimethylsilyl intermediates (4a-e, 6a-c, 8, 13, 17) by this method. (author).

Energy Technology Data Exchange (ETDEWEB)

What technical, economic and institutional factors make radioactive and/or hazardous waste management technologies publicly acceptable? The goal of this paper is to initiate an identification of factors likely to render radioactive and hazardous waste management technologies publicly acceptable and to provide guidance on how technological R&D might be revised to enhance the acceptability of alternative waste management technologies. Technology development must attend to the full range of technology characteristics (technical, engineering, physical, economic, health, environmental, and socio-institutional) relevant to diverse stakeholders. ORNL`s efforts in recent years illustrate some attempts to accomplish these objectives or, at least, to build bridges toward the integrated design of waste management technologies.

British Library Electronic Table of Contents (United Kingdom)

Abstract Micronutrient deficiencies are a public health concern among young children in low-income countries, and novel strategies are needed to improve the nutritional status of children at risk. One promising approach is the use of lipid-based nutrient supplements (LNS), which can be added to complementary food at the time of consumption. The optimal amount of zinc to include in LNS is uncertain, and concerns have been expressed about possible adverse effects of zinc on sensory characteristics of LNS. We conducted a series of acceptability studies of LNS containing either 0 or 10-mg of zinc per daily 20-g LNS dose among Burkinabe children 9-15 months old and their mothers. These acceptability studies included observations of children's consumption, maternal and child sensory reaction to ...

Energy Technology Data Exchange (ETDEWEB)

Waveform correlation detectors compare a signal template with successive windows of a continuous data stream and report a detection when the correlation coefficient, or some comparable detection statistic, exceeds a specified threshold. Since correlation detectors exploit the fine structure of the full waveform, they are exquisitely sensitive when compared to power (STA/LTA) detectors. The drawback of correlation detectors is that they require complete knowledge of the signal to be detected, which limits such methods to instances of seismicity in which a very similar signal has already been observed by every station used. Such instances include earthquake swarms, aftershock sequences, repeating industrial seismicity, and many other forms of controlled explosions. The reduction in the detection threshold is even greater when the techniques are applied to arrays since stacking can be performed on the individual channel correlation traces to achieve significant array gain. In previous ...

UK PubMed Central (United Kingdom)

BackgroundThe cachexia-anorexia syndrome impacts on patients' physical independence and quality of life. New treatments are required and need to be evaluated using acceptable and...Full Text Available

UK PubMed Central (United Kingdom)

Bellevue Hospital, the oldest public hospital in the United States and a lineal descendant of an infirmary for slaves, accepted its first African-American resident, Dr. Ubert Conrad Vincent, in 1918....Full Text Available

UK PubMed Central (United Kingdom)

The difficulties created by the lack of generally accepted views on classification, diagnostic criteria and natural history of the cutaneous lymphomata are discussed. Only the lymphomata which remain...Full Text Available

Wastenet

... The main goal was the analysis of the Environmental Kuznets Curve hypothesis for the Czech Republic. A paper by Bruha and Scasny, accepted to the European Society of Ecological Economics, ( Lisbon June 2005), analyses driving forces (including economic policy) on ...

UK PubMed Central (United Kingdom)

Purpose: This paper reviews and reassesses the internationally accepted niches or ‘targets’ in bone marrow that are sensitive to the induction of leukaemia and primary...Full Text Available

International Nuclear Information System (INIS)

The guide describes a method acceptable to the NRC staff for complying with the Commission's regulations with regard to quality assurance requirements for installation, inspection, and testing of mechanical equipment and systems for water-cooled and high-temperature gas-cooled nuclear power plants.

UK PubMed Central (United Kingdom)

The widely accepted oxidative stress theory of aging postulates that aging results from accumulation of oxidative damage. Surprisingly, data from the longest-living rodent known, naked mole-rats [MRs;...Full Text Available

UK PubMed Central (United Kingdom)

It is generally accepted that hypoxia and recovery from oxygen deprivation contribute to the breakdown and ulceration of human skin. The effects of these stresses on proliferation, differentiation...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundLittle is known about the acceptability of internet and telephone treatments, or what factors might influence patient interest in receiving treatments via...Full Text Available

UK PubMed Central (United Kingdom)

PurposeIn situ fixation for mild to moderate slipped capital femoral epiphysis (SCFE) remains an acceptable treatment methodology in most centers. Satisfactory fixation results have...Full Text Available

UK PubMed Central (United Kingdom)

It is now widely accepted that novel infectious disease can be a leading cause of serious population decline and even outright extinction in some invertebrate and vertebrate groups (e.g., amphibians)....Full Text Available

UK PubMed Central (United Kingdom)

Health has long been intertwined with the foreign policies of states. In recent years, however, global health issues have risen to the highest levels of international politics and have become accepted...Full Text Available

UK PubMed Central (United Kingdom)

It is generally accepted that mammalian oocytes are frequently suffering from chromosome segregation errors during meiosis I, which have severe consequences, including pregnancy loss, developmental...Full Text Available

UK PubMed Central (United Kingdom)

The interaction of β-cyclodextrin (β-CD) with mixed bilayers composed of sphingomylein and cholesterol (Chol) above and below the accepted stable complexation...Full Text Available

UK PubMed Central (United Kingdom)

Extensive gene expression during meiosis is a hallmark of spermatogenesis. Although it was generally accepted that RNA transcription ceases during meiosis, recent observations suggest that some transcription...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundPosttransfusion hepatitis B virus (HBV) infection still occurs although its incidence has been substantially reduced since the introduction of screening of hepatitis B...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundMany health care professionals use spinal palpatory exams as a primary and well-accepted part of the evaluation of spinal pathology. However, few studies have explored...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Study of the conversion of chicken litter to biogas for the production of energy. There was an additional requirement that after extracting the energy from the chicken litter the nutrient value of the raw chicken litter had to be returned to the Ak-Chin Farms for use as fertilizer in a form and delivery method acceptable to the Farm.

UK PubMed Central (United Kingdom)

To diagnose asymptomatic bacterial vaginosis (BV), self-sampled vaginal smears were collected during a study of risk factors for preterm birth in African American women. More than 90% of those...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundImproving nutrition knowledge among children may help them to make healthier food choices. The aim of this study was to assess the effectiveness and acceptability of a...Full Text Available

UK PubMed Central (United Kingdom)

SummaryHeadache due to the pressure of nasal mucosa in the absence of inflammation of the nose and paranasal sinuses is a clinical entity that has gained wide acceptance. Concha bullosa...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The visual impact of wind turbines is one of the main factors affecting public acceptance of wind parks. This paper evaluates the visual impact of a wind park in Chania, Crete, using the Spanish method of evaluation. The outcomes are combined with the psychometric testing of the residents by the use of questionnaires and with the values of the Spanish method about various scenarios concerning the size of the wind park (double, half, one wind turbine). The results of the study prove that the quantification of the potential visual impact could minimize this, apparently, main reason that affects public acceptance. (author)

Energy Technology Data Exchange (ETDEWEB)

A large acceptance, high stopping power Bragg curve spectrometer has been developed for use in coincidence experiments with heavy ions. The electron collection fields are radial and position information is obtained from a resistive anode. The detector is 60 cm deep and operates at pressures of up to 2.5 atm of P-10 gas. It is mated to a scattering chamber which allows it to be moved out of plane during coincidence measurements. Factors affecting the performance of the detector are discussed, and results obtained with the detector are presented. (orig.).

Energy Technology Data Exchange (ETDEWEB)

In developing new brain imaging agents for single photon emission computed tomography (SPECT), we synthesized eleven radioiodinated phenoxyacetic acid derivatives and investigated the relationship between the chemical structure and in vivo characteristics. Biodistribution studies in mice revealed high initial brain uptake for all the compounds. Blood radioactivity level depended markedly upon the chemical stability of the compound. The alpha,alpha-dimethylester derivative, amide derivatives and diamine derivatives, which were stable to hydrolysis, showed low blood activity levels following intravenous administration. Disappearance of the ester and amide compounds from the brain was rapid. However, the diamine derivatives displayed improved retention in the brain. Compounds 3a and 4 possessed the best combination of high brain uptake and sufficient retention to be useful as potential ...

UK PubMed Central (United Kingdom)

Receptor protein tyrosine phosphatase T (PTPRT/PTPρ) is frequently mutated in human cancers including colon, lung, gastric and skin cancers. More than half of the identified tumor-derived...Full Text Available

International Nuclear Information System (INIS)

The excess molar volumes V_m"E for binary liquid mixtures containing dipropylene glycol monomethyl ether or dipropylene glycol monobutyl ether and methanol, 1-propanol, 1-pentanol and 1-heptanol have been measured as a function of composition using a continuous dilution dilatometer at T=(288.15, 298.15, and 308.15) K and atmospheric pressure over the whole concentration range. The excess volume results allowed the following mixing quantities to be reported in all range of concentrations or at equimolar concentrations: #alpha#, volume expansivity; (#partial deriv#V_m"E/#partial deriv#T)_p; (#partial deriv#H"E/#partial deriv#P)_T at T=298.15 K. The obtained results have been compared at T=298.15 K with the calculated values by using the Flory theory of liquid mixtures. The theory predicts the #alpha#, and #alpha#"E values rather well, while the calculated values of (#partial ...

International Nuclear Information System (INIS)

Ring opening dynamics of diarylethene derivative (BTF6) in n-hexane are studied by femtosecond transient absorption and time resolved spontaneous fluorescence techniques. Cyclo-reversion time constant is obtained.

UK PubMed Central (United Kingdom)

Platelet-derived growth factor (PDGF) is a potent moderator of soft tissue repair through induction of the inflammatory phase of repair and subsequent enhanced collagen deposition. We examined the effect...Full Text Available

UK PubMed Central (United Kingdom)

A series of N-alkylamide epoxides have shown considerable selective activity against insects. The N-ethyl and 7,11-dichloro-N-ethyl derivatives showed particularly pronounced activity, and this paper...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundDespite numerous treatments available for deteriorated cutaneous wound healing such as a diabetic foot, there is still the need for more effective therapy. Adipose-derived...Full Text Available

UK PubMed Central (United Kingdom)

In this article, we report anticancer activity of 14 anthracenedione derivatives separated from the secondary metabolites of the mangrove endophytic fungi Halorosellinia sp. (No. 1403)...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundBacterial constituents, such as Gram-negative derived lipopolysaccharide (LPS), can initiate inflammatory bone loss through induction of host-derived inflammatory...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

English 2006 2 p. Brazil Rocha, RM Centro Tecnico Aeroespacial, Sao

International Nuclear Information System (INIS)

This patent describes a radioiodinated benzodiazepine derivative. It comprises a lower alkyl group with 1-4 C-atoms and a radioactive iodine.

Science.gov (United States)

This study tested the prediction, derived from the goal-setting hypothesis, that the facilitating

CERN Document Server

Kaluza-Klein higher derivative induced gravity is studied for its application in the inflationary universe. The stability of an inflationary solution in a $D+4$-dimensional anisotropic space is analyzed carefully. We show that there is two nontrivial constraints derived from the static assumptions on the $D$-dimensional scale factor $d$ and scalar field $\\psi$. We find that a physical inflationary solution is consistent with the above constraints. In addition, a compact formula for the non-redundant $4+D$ dimensional Friedmann equation is also derived for convenience. Possible implications are also discussed in this paper.

CERN Document Server

Let $\\A$ be an irreducible Coxeter arrangement and $\\bfk$ be a multiplicity of $\\A$. We study the derivation module $D(\\A, \\bfk)$. Any two-dimensional irreducible Coxeter arrangement with even number of lines is decomposed into two orbits under the action of the Coxeter group. In this paper, we will {explicitly} construct a basis for $D(\\A, \\bfk)$ assuming $\\bfk$ is constant on each orbit. Consequently we will determine the exponents of $(\\A, \\bfk)$ under this assumption. For this purpose we develop a theory of universal derivations and introduce a map to deal with our exceptional cases.

Energy Technology Data Exchange (ETDEWEB)

The authors investigate anomalous terms in finite superconformal transformations in N = 4 SU(2)-extended superconformal algebras (SCA). Based on the superspace formalism they obtain super Schwarzian derivatives for the N = 4 SCA. Solutions for global superconformal transformations with the vanishing super-Schwarzian derivatives are given.

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption of proline and its hydroxy derivatives on the surface of graphitized thermal carbon black (GTCB) were calculated. The arrangement of hydroxyl groups in the amino acid molecule was shown to influence their adsorption on GTCB. The influence of internal rotation angles in proline and its hydroxy derivative molecules on their adsorption on GTCB was studied.

Energy Technology Data Exchange (ETDEWEB)

A formula for calculating the Dirac S-matrix for central Lorentz scalar and vector potentials is derived by use of a new amplitude-phase method. The derivation also makes use of certain invariants of the reduced 2-spinor radial Dirac equations.

International Nuclear Information System (INIS)

A consistent mathematical derivation is given for the Sommerfeld fine structure electromagnetic coupling 1/?-bar 0=?0-bar 1/137.036. Following 't Hooft's holographic principle two complimentary forms of the derivation are given both leading to the E(?) theoretical value, namely ?-bar 0=(20)(1/?)4=137.082039311. The experimental value is subsequently found by projection as ?-bar 0(exp)=137/[cos(?/?-bar 0)]-bar 137.036.

Energy Technology Data Exchange (ETDEWEB)

Y-zeolite supported catalysts were applied to the hydrocracking of coal-derived liquids. By the introduction of two-stage upgrading consisting of hydrotreating and hydrocracking, Wandoan coal-derived middle distillate was hydrocracked over Ni-Mo/Y-zeolite, producing a high gasoline fraction yield. Zeolite supported catalysts gave little hydrocracked compounds in the hydroprocessing of coal-derived heavy oils, even after hydrotreatment. The reaction inhibitors which seriously poison the active sites of zeolites were found to be small nitrogen-containing molecules. In the hydroprocessing of coal-derived heavy oils, zeolite supported catalysts were inferior to alumina supported catalysts. This is due to the high hydrocracking but low hydrogenation activity of zeolite supported catalysts. 22 refs., 5 figs., 11 tabs.

International Nuclear Information System (INIS)

This publication identifies conditions which affect (either increase or decrease) public concern for and political acceptance of the development and implementation of programmes for geological disposal of long lived radioactive waste. It also looks at how interested citizens can be associated in the decision making process in such a way that their input enriches the outcome of a more socially robust and sustainable solution. The publication also considers how to optimize risk management, addressing the needs and expectations of the public and of other relevant stakeholders. Factors of relevance for societal acceptance conditions are identified for the different stages of a repository programme and implementation process, from policy development to the realization of the repository itself. Further, they are described and analysed through case studies from several countries, illustrating the added value of broadening the technical dimension with ...

International Nuclear Information System (INIS)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyro-processing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than 98.5% of LLFP have to be removed to meet below dose constraint within the DF more than 5.0E+03. Besides, ...

International Nuclear Information System (INIS)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than 98.5% of LLFP have to be removed to meet below dose constraint within the DF more than 5.0E + 03. Besides, ...

Energy Technology Data Exchange (ETDEWEB)

Acceptance Testing of the WRAP 1 Plant Control System Hardware will be conducted throughout the construction of WRAP I with the final testing on the Process Area hardware being completed in November 1996. The hardware tests will be broken out by the following functional areas; Local Control Units, Operator Control Stations in the WRAP Control Room, DMS Server, PCS Server, Operator Interface Units, printers, DNS terminals, WRAP Local Area Network/Communications, and bar code equipment. This document will contain completed copies of each of the hardware tests along with the applicable test logs and completed test exception reports.

British Library Electronic Table of Contents (United Kingdom)

Many new technologies and approaches to the provision of comfort inside buildings such as displacement ventilation, mixed-mode strategies, personally controllable (task-ambient) designs, chilled beams as well as some old but recently fashionable ones such as natural ventilation are prompting a rethink of the accepted comfort wisdom. How can a single combination of thermal environmental parameters be deemed unacceptable in a conventional heating ventilation and air-conditioning setting, and yet be regarded as acceptable, or even pleasant, in a naturally ventilated or mixed-mode setting? Why do current comfort standards prescribe static and isothermal conditions for comfort in one building, and dynamic and spatially variable indoor climates for comfort in another? The phenomenon of alliesthe...

International Nuclear Information System (INIS)

Objective: To investigate the X-ray radiation dose patients dealt with the hepatic intervention. Methods: Thermoluminescence and tissue-equivalent anthropomorphic phantom were used to measure the X-ray radiation dose in patients dealt with the hepatic intervention in 85 patients. Results: The peak skin dose in the patients who accepted hepatic intervention was from 179.95 to 1759.00 mGy, effective dose approached 29.22 mSv (male), 29.27 mSv (female). Conclusion: Hepatic intervention is now regarded as an important therapeutic method for liver cancer. However, the patients were exposed to too much X-ray radiation during interventional procedures. Some more effective protection should be taken to decrease the X-ray radiation dose accepted by patients. (authors)

Energy Technology Data Exchange (ETDEWEB)

The market potential for the fan atomized burner (FAB) in water and space heating applications was examined. The major findings of the study are as follows. (1). The FAB`s low-input capability allows development of oil-fired room heaters and wall furnaces, a new market area for oil heat. (2). Among conventional oil-fired products, furnaces will benefit most from the burner`s low input capability due to (1) their quick delivery of heat and (2) their more prevalent use in warmer climates and smaller homes. (3). The greatest potential for increased product sales or oil sales exists in the use of the burner with new products (i.e., room heaters). Sales of boilers and direct-fired water heaters are not likely to increase with the use of the burner. (4). Acceptance of the burner will be dependent on proof of reliability. Proof of better reliability than conventional burners would accelerate acceptance.

Energy Technology Data Exchange (ETDEWEB)

We have developed an energy-extension method of a Bragg curve counter (BCC) at the high-energy end for the measurements of double-differential cross-sections (DDXs) of fragment productions induced by tens of MeV protons. In this method, we estimate the incident energies of the fragments penetrating a BCC on the basis of the energy loss and atomic number (Z). We applied this method to the DDX measurements of the {sup nat}C(p, Li) and {sup nat}C(p, Be) reactions induced by 70 MeV protons. The validity of this method has been confirmed by comparing the DDXs of beryllium with theoretical predictions of the PHITS code and the two-body kinematics. This method improves the energy acceptance of the BCC for light fragments twice as wide as that of a conventional method without remodeling of the BCC and any loss of the original advantages.

Energy Technology Data Exchange (ETDEWEB)

There are many different types of open pit mining operations around the world, and the challenge for any drive system manufacturer is to produce a system(s) that will work satisfactorily in these mines. Several factors must be considered such as vehicle speed requirements, available engine horsepower, mine rolling resistance, grades, grade lengths, payload, and tire sizes. How well a particular drive system performs depends on the size, weight, and available tractive/retarding effort. In addition to performance, the system must also have an operating cost that will be acceptable over the life of the equipment. Today the choice of drive systems is not only between mechanical and electrical drives, but also within these categories are the different manufacturers. Regardless of how the power is provided to the rear wheels, the job must be accomplished reliably and at an acceptable cost. This paper covers the characteristics of an electric drive ...

Energy Technology Data Exchange (ETDEWEB)

I describe a search for anomalous production of Z pairs through a new massive resonance X in 2.5-2.9 fb{sup -1} of p{bar p} collisions at {radical}s = 1.96 TeV using the CDFII Detector at the Fermilab Tevatron. I reconstruct Z pairs through their decays to electrons, muons, and quarks. To achieve perhaps the most efficient lepton reconstruction ever used at CDF, I apply a thorough understanding of the detector and new reconstruction software heavily revised for this purpose. In particular, I have designed and employ new general-purpose algorithms for tracking at large {eta} in order to increase muon acceptance. Upon analyzing the unblinded signal samples, I observe no X {yields} ZZ candidates and set upper limits on the production cross section using a Kaluza-Klein graviton-like acceptance.

Energy Technology Data Exchange (ETDEWEB)

Grain refinement behavior of copper alloys cast in permanent molds was investigated. This is one of the least studied subjects in copper alloy castings. Grain refinement is not widely practiced for leaded copper alloys cast in sand molds. Aluminum bronzes and high strength yellow brasses, cast in sand and permanent molds, were usually fine grained due to the presence of more than 2% iron. Grain refinement of the most common permanent mold casting alloys, leaded yellow brass and its lead-free replacement EnviroBrass III, is not universally accepted due to the perceived problem of hard spots in finished castings and for the same reason these alloys contain very low amounts of iron. The yellow brasses and Cu-Si alloys are gaining popularity in North America due to their low lead content and amenability for permanent mold casting. These alloys are prone to hot tearing in permanent mold casting. Grain refinement is one of the solutions for reducing this problem. ...

International Nuclear Information System (INIS)

In developing new brain imaging agents for single photon emission computed tomography (SPECT), we synthesized eleven radioiodinated phenoxyacetic acid derivatives and investigated the relationship between the chemical structure and in vivo characteristics. Biodistribution studies in mice revealed high initial brain uptake for all the compounds. Blood radioactivity level depended markedly upon the chemical stability of the compound. The #alpha#,#alpha#-dimethylester derivative (1e), amide derivatives (2a-c) and diamine derivatives (3a, b, 4), which were stable to hydrolysis, showed low blood activity levels following i.v. administration. Disappearance of the ester and amide compounds from the brain was rapid. However, the diamine derivatives displayed improved retention in the brain. Compounds 3a and 4 possessed the best combination of high brain uptake and sufficient retention to be ...

International Nuclear Information System (INIS)

Using an ab initio pseudopotential method within a generalized gradient approximation of the density functional theory, the structural, electronic, and phonon properties of SrS in the B1 (NaCl) and B2 (CsCl) structures have been studied. The calculated lattice constants, static bulk modulus, and first-order pressure derivative of the bulk modulus are reported for both the B1 and B2 structures and compared with previous experimental and theoretical calculations. Electronic band structures and densities of states have been derived for SrS. Subsequently, a linear-response approach to the density functional theory is used to derive the phonon frequencies and densities of states.

CERN Document Server

Using some modification of the standard fermion technique we derive factorized formula for spin operator matrix elements (form-factors) between general eigenstates of the Hamiltonian of quantum Ising chain in a transverse field of finite length. The derivation is based on the approach recently used to derive factorized formula for Z_N-spin operator matrix elements between ground eigenstates of the Hamiltonian of the Z_N-symmetric superintegrable chiral Potts quantum chain. The obtained factorized formulas for the matrix elements of Ising chain coincide with the corresponding expressions obtained by the Separation of Variables Method.

International Nuclear Information System (INIS)

The symmetry properties of the Coulomb potential allow for a dynamical spin-1/2 description of any fixed n level of a hydrogenlike atom in a time-dependent sufficiently weak electric and/or magnetic field. An explicit expression for the time dependence of the l,m amplitudes pertaining to a general n level is derived. The derivation follows on purely algebraic operations. Based on the derivation, we give analytical n-independent solutions to established and proposed schemes for driving the atom into a high angular-momentum state.

Science.gov (United States)

... Values of absorption maxima, X.nax, and associated molar extinction coefficients, c, as well as values of the n-octanol/water partition coefficient( ...

UK PubMed Central (United Kingdom)

Phytoestrogens are plant derived compounds found in a wide variety of foods, most notably soy. A litany of health benefits including a lowered risk of osteoporosis, heart disease, breast cancer,...Full Text Available

UK PubMed Central (United Kingdom)

Hyaluronan (HA), a non-sulfated glycosaminoglycan, is widely used in the clinic for viscosurgery, viscosupplementation, and treatment of osteoarthritis. Four decades of chemical modification...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Mono- and disubstituted novel derivatives of the heptaene nystatin analog 28,29-didehydronystatin A1 (S44HP, 1) were obtained by chemical modification of the exocyclic C-16 carboxyl and/or an amino group of mycosamine moiety. The strategy of preparation of mono- and double-modified polyene macrolides was based on the use of intermediate hydrophobic N-Fmoc (9-fluorenylmethoxycarbonyl) derivatives that facilitated the procedures of isolation and purification of new compounds. The antifungal activity of the new derivatives was first tested in vitro against yeasts and filamentous fungi, allowing the selection of the most active compounds that were subsequently tested for acute toxicity in mice. 2-(N,N-dimethylamino)ethylamide of 1 (2) and 2-(N,N-dimethylamino)ethylamide of N-fructopyranosyl-28...

Science.gov (United States)

The synthesis and structural characterization of a novel In(III) complex is described. The reaction

British Library Electronic Table of Contents (United Kingdom)

Reactive blue 2 (RB-2) had been characterized as a relatively potent ectonucleoside triphosphate diphosphohydrolase (E-NTPDase) inhibitor with some selectivity for NTPDase3. In search for the pharmacophore and to analyze structure-activity relationships we synthesized a series of truncated derivatives and analogs of RB-2, including 1-amino-2-sulfo-4-ar(alk)ylaminoanthraquinones, 1-amino-2-methyl-4-arylaminoanthraquinones, 1-amino-4-bromoanthraquinone 2-sulfonic acid esters and sulfonamides, and bis-(1-amino-4-bromoanthraquinone) sulfonamides, and investigated them in preparations of rat NTPDase1, 2, and 3 using a capillary electrophoresis assay. Several 1-amino-2-sulfo-4-ar(alk)ylaminoanthraquinone derivatives inhibited E-NTPDases in a concentration-dependent manner. The 2-sulfonate group ...

Science.gov (United States)

Not Available

Energy Technology Data Exchange (ETDEWEB)

Wall thickness measurement of pipe is very important of the structural integrity of the industrial plant. However, the radiography method has an advantage because the ability of penetrating the insulated pipe. This will have economic benefit for industry. Moreover, the era of digital radiography has more advantages because the speed of radiographic work, less exposure time and no chemical used for film development. Either the conventional radiography or digital radiology, the wall thickness measurement is using the tangential radiography technique (TRT). In case, of a large diameter, pipe (more than inches) the determination maximum penetration wall thickness must be taken into the consideration. This paper is revisited the mathematical derivation of the determination of wall thickness measurement based on tangential radiography technique (TRT). The mathematical approach used in this derivation is the Pythagoras theorem and geometrical ...

Science.gov (United States)

... The phenol and cresylic acid stream is flashed in a thin film evaporator over a concentrated sulfuric acid mixture to remove pyridine type substances ...

British Library Electronic Table of Contents (United Kingdom)

The molecular environment of the key subdomain IIId of the internal ribosome entry site (IRES) element of hepatitis C virus (HCV) RNA in the binary complex with the human 40S ribosomal subunit was studied. To this end, HCV IRES derivatives bearing perfluorophenylazido groups activatable by mild UV at nucleotides G263 or A275 in the subdomain IIId stem were used. They were prepared by the complementary addressed modification of the corresponding RNA transcript with alkylating oligodeoxyribonucleotide derivatives. None of the RNA derivatives were shown to be crosslinked to the 18S rRNA. It was found that the photoreactive groups of the IRES G263 and A275 nucleotides are crosslinked to ribosomal proteins S3a, S14, and S16. For the IRES derivative with the photoreactive group in nucleotide G26...

DEFF Research Database (Denmark)

Udgivelsesdato: 2009-Dec

UK PubMed Central (United Kingdom)

The effects of temperatures, durations of treatment, and derivations from spermatophores or spermaries on in vitro acrosome reaction of the spermatozoa in the Chinese mitten crab Eriocheir sinensis...Full Text Available

Science.gov (United States)

this, however, was a real environmental threat since various drums containing jet fuel, Bunker C, diesel and other petroleum derivatives were on fire. The CAPECO...

Science.gov (United States)

... derived and which describes fundamentally flux enhancement across an artificial membrane or skin: Keywords: Transdermal drug delivery system. ...

Science.gov (United States)

... The third series used a correlated parameter covariance matrix derived from a generic database of modeling uncertainty for space structures [5-1 ...

UK PubMed Central (United Kingdom)

We develop and investigate numerically a thermodynamically consistent model of two-dimensional multicomponent vesicles in an incompressible viscous fluid. The model is derived using an energy...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Density functional theory calculations were performed to study the effects of different substituents and bridge groups on the heats of formation (HOFs), thermal stability, and detonation properties for a series of diiminotetrazole derivatives. The isodesmic reaction method was employed to calculate the HOFs of the derivatives using total energies obtained from electronic structure calculations. The bond dissociation energies and bond orders for the weakest bonds were analyzed to investigate the thermal stability of the diiminotetrazole derivatives. The detonation velocities and pressures were evaluated by using the semiempirical Kamlet-Jacobs equations, based on the theoretical densities and HOFs. These results provide basic information for the molecular design of novel high-energy density...

Energy Technology Data Exchange (ETDEWEB)

Necessary conditions are derived for compact aggregates of solid matter to develop from loose local clumps of dust grains in a contracting protostellar cloud.

Science.gov (United States)

PMID:17103063

Science.gov (United States)

This data set consists of land derived from high resolution imagery and was analyzed according to the Coastal Change ... ...

Science.gov (United States)

This data set consists of land derived from high resolution imagery and was analyzed according to the Coastal Change ... ...

Science.gov (United States)

... Coastal Monitoring and Assessment, the University of Hawaii, BAE Systems Spectral Solutions and Analytical Laboratories of Hawaii, LLC. ... ...

KoreaScience (Korea)

Full Text Available

UK PubMed Central (United Kingdom)

The avermectins were introduced in 1981 and constitute a potent new class of anthelmintic agents. They are naturally-derived products of microbial action displaying an exceptionally wide range of antiparasitic...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Valuing present citizen's values regarding the risks they face is an important aspect of risk assessment and risk acceptability. Conferences like VALDOR are held for this reason. Governments like Sweden have national referendums on various risk-prone enterprises. The results of these referendums can determine the future of these programs. In the United States, when guidelines are set for determining acceptable levels of risk, the relevant federal agencies are often required to provide a comment period regarding proposed guidelines in order to ascertain the judgments, including the weights place on certain values, of individual members of society as well as stakeholder groups. After the comment period ends, the agency decides on the acceptable level of risk, taking into account the comments from present citizens. Do we also have a duty to value the not-yet-existing values of future citizens, especially if the risks ...

Energy Technology Data Exchange (ETDEWEB)

This paper is concerned with methods of limiting the build-up of transient voltages between sheath and armor in long armored power cables. Calculations by a frequency dependent cable model demonstrate that this voltage can be efficiently limited to an acceptable level by introducing sheath-armor bondings at regular intervals, or by using a semiconductive sheath-armor interlayer. The paper investigates the required minimum length between bondings, as well as the required conductivity of the sheath-armor interlayer if the use of bondings is to be avoided.

Energy Technology Data Exchange (ETDEWEB)

The paper discusses the potential environmental impacts associated with the operation of a large, say 350 MWe, gas-fired combined cycle power station. It concludes that if appropriate control methods are introduced at the design stage of the plant, environmental impacts are minimal and can be considered acceptable. (author).

Energy Technology Data Exchange (ETDEWEB)

This article illustrates what typical accept/reject curves might look like and discusses progress made in developing the required inspection techniques for flaw dimensioning. Consideration is given to the relative significance of blunt versus planar types of flaws, and of inherent limitations to the depths of certain types of flaws. Finally, consideration is given to the realities of implementing proposed procedures under field conditions. These are summarized in a series of technical options for implementation of program results.

Energy Technology Data Exchange (ETDEWEB)

This document provides stakeholder evaluations on innovative technologies to be used in the remediation of volatile organic compounds from soils and ground water. The technologies evaluated are; in-well vapor stripping, in-situ bioremediation, and gas membrane separation.

Energy Technology Data Exchange (ETDEWEB)

The Rocky Flats Plant, located approximately 26 km northwest of downtown Denver, Colorado, has developed an emergency response atmospheric dispersion model for complex terrain applications. Plant personnel would use the model, known as the Terrain-Responsive Atmospheric Code (TRAC) (Hodgin 1985) to project plume impacts and provide off-site protective action recommendations to the State of Colorado should a hazardous material release occur from the facility. The Colorado Department of Health (CDH) entered into an interagency agreement with the Rocky Flats Plant prime contractor, EG&G Rocky Flats, and the US Department of Energy to evaluate TRAC as an acceptable emergency response tool. After exhaustive research of similar evaluation processes from other emergency response and regulatory organizations, the interagency committee devised a formal acceptance process. The process contains an evaluation protocol (Hodgin and Smith 1992), ...

International Nuclear Information System (INIS)

Appendix B to 10 CFR Part 50 establishes overall quality assurance requirements for the design, construction and operation of safety-related structures, systems, and components. This guide presents a method acceptable to the Commission for complying with these regulations with regard to overall quality assurance program requirements during design and construction of nuclear power plants. Input to this guide has been provided by the Advisory Committee on Reactor Safeguards.

Energy Technology Data Exchange (ETDEWEB)

A phenomenological model is presented for prediction of the combustion characteristics of a quiescent chamber diesel engine. Predictions with the model have shown acceptable agreement with a range of experimental data. The major physical processes controlling combustion have been characterized, and the dominant role of air entrainment and turbulent mixing confirmed quantitatively. 45 refs.

Science.gov (United States)

The Multiple Address Processing Unit (MAPU) of the AN/TGC-26 tape relay center was originally designed to process ACP 127 message format. With the advent of JANAP 128 as a standardized message format a pressing need was felt for a MAPU modification to all...

British Library Electronic Table of Contents (United Kingdom)

ABSTRACT Extending the unified theory of acceptance and use of technology (UTAUT) model, this study postulates a model of online social support. The model is empirically tested using data from undergraduates in Taiwan regarding their usage of instant messaging (IM). The test results indicate that all model paths are significant, except that the path between online social support and facilitating conditions is insignificant. This study offers limitations and implications.

International Nuclear Information System (INIS)

The possibility of having properly designed multinational fuel cycle agreements which would contribute to public acceptance of nuclear energy are explored. The advantages of existing international cooperation in the field of uranium enrichment and nuclear waste disposal and reprocessing are discussed. The possible forms of multinational co-operation under an international organisation, committed the non-proliferation and operating under international law and covering storage facilities, security of raw materials and the nuclear fuel cycle are summarised in model form. (U.K.).

Energy Technology Data Exchange (ETDEWEB)

Accelerated aging tests such as high temperature burn-in, which are in current use on Bendix Kansas City Division's (BKC) purchased small and medium scale integrated circuits, were evaluated to determine if they are effective and necessary to ensure the required reliability. A theoretical analysis, a literature search, and a study of lot acceptance results were used to assess the value of integrated circuit burn-in.

International Nuclear Information System (INIS)

The concept of preliminary transmutation of minor actinides before placement to the long-term storage is considered. The purpose of such preliminary transmutation before ultimate storage is to incinerate a part of actinides and to transform another part into new actinides providing low level of radiotoxicity accumulated in the storage. Modes of transmutation in reactors of PWR, PHWR (CANDU), and Superfenix types are compared. Among power reactors, heavy-water PHWR type reactor is most acceptable for preliminary transmutation. (author)

Energy Technology Data Exchange (ETDEWEB)

The existence of propagating spin waves above T/sub c/ in Ni and Fe has been widely accepted since this picture was first advocated in 1973. In this brief review of our current neutron scattering experiments on Fe and Ni we will present convincing evidence showing that this picture is incorrect. In addition, we will demonstrate that over wide ranges of ..omega.., q and temperature, both Fe and Ni follow a simple paramagnetic scattering function of the spin diffusion type. 19 references.

Science.gov (United States)

A cylindrical multiwire drift chamber is the central detector of the AMPIR spectrometer. It has 4{pi} acceptance angle and was designed to study pion-nucleon reactions. The chamber can determine the three coordinates through the electron drift time and charge division ration. The paper describes the layout and design of the chamber, the test bench, the data output circuit, the design parameters, and the results of computer simulations and tests.

Energy Technology Data Exchange (ETDEWEB)

The Technical Safety Requirements (TSRs) for the Cold Vacuum Drying Facility define acceptable conditions, safe boundaries, bases thereof, and management or administrative controls required to ensure safe operation. Controls required for public safety, significant defense-in-depth, significant worker safety, and for maintaining radiological and toxicological consequences below risk evaluation guidelines are included.

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis was used for the determination of Cu, Y and Ba in very thin high-temperature superconducting films. The precision of the method is better than 3% for about 1 #mu#m thick films. The atomic emission ICP spectrometry was used to testify results of XRF analysis. An acceptable agreement of both methods was obtained. (author) 4 refs.; 2 tabs.

International Nuclear Information System (INIS)

The rare earth antimonates RE_3Sb_5O_1_2 constitute an isostructural series, where the rare earth site symmetry is S_4. The spectroscopic properties of pure or doped compounds of this family are studied in order to derive their energy level schemes and to simulate them through the crystal field theory, by using the approximated D_2_d potential. The paramagnetic susceptibilities are calculated with the derived wavefunctions and compared to experiment.

UK PubMed Central (United Kingdom)

Some acylhydrazine derived ONO donor Schiff bases and their Co(II) and Ni(II) complexes have been prepared having the same metal ion (cation) but different anions. These synthesized metal(II)...Full Text Available

CERN Document Server

Dwarf galaxies are generally faint. To derive their age and metallicity distributions, it is critical to optimize the use of any collected photon. Koleva et al., using full spectrum fitting, have found strong population gradients in some dwarf elliptical galaxies. Here, we show that the population profiles derived with this method are consistent and more precise than those obtained with spectrophotometric indices. This allows studying fainter objects in less telescope time.

Energy Technology Data Exchange (ETDEWEB)

The reduction of four-vector and electromagnetic fields produced by spin-1 tachyons has been derived in terms of standard helicity representations of inhomogeneous Lorentz group, and the conditions for these superluminal electromagnetic fields to satisfy the Maxwell's field equations have been derived. 16 refs.

International Nuclear Information System (INIS)

We investigate the q-deformation of the BRST algebra, the algebra of the ghost, matter and gauge fields on one spacetime point using the result of the bicovariant differential calculus. There are two nilpotent operations in the algebra, the BRST transformation #delta#_B and the derivative d. We show that one can define the covariant commutation relations among the fields and their derivatives consistently with these two operations as well as the *-operation, the antimultiplicative inner involution. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Dithiolato-nickel complexes with multisulfur ligands derived from benzenehexathiolate have been synthesized. The properties of the monomeric and polymeric complexes have been characterized by ESR spectroscopic and magnetochemical data and by electrical conductivity measurements. The prepared complexes are paramagnetic and have characteristic absorptions between 800 and 1000 nm. (orig.).

Energy Technology Data Exchange (ETDEWEB)

This paper outlines the development of an organizational model which will be used to determine the influence of supervisory and management functions in a nuclear power plant (NPP) on risk. A theoretical conceptualization, derived from the empirical literature, is used to describe the organizational structure of NPPs. The parameters and variables associated with this dynamic, process-oriented model are detailed. Applications of the model and preliminary insights derived from this conceptualization are discussed.

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for deriving hydrolized polyacrylonitrile from a water-based alkali solution. This process is meant to improve the thermal stability of clay drilling solutions by employing the hydrolized product to treat aliphatic non-water-soluble C/sub 8/-C/sub 16/ spirits in an organic dispersant during the presence of acidity and while the solution is being heated.

UK PubMed Central (United Kingdom)

The yeast phosphatidylinositol transfer protein (Sec14p) is required for biogenesis of Golgi-derived transport vesicles and cell viability, and this essential Sec14p requirement is abrogated by inactivation...Full Text Available

UK PubMed Central (United Kingdom)

Dendritic cells (DC) are the most potent antigen-presenting cells and play a central role in the induction of antiviral immune responses. Recently, we have shown that monocyte-derived DC (MoDC) from...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Explicit analytical formulas are derived for the stress intensity factors at the tips of a main crack and of a microcrack for the two-dimensional case of a collinear microcrack. This configuration is used to derive an estimate of the toughness degradation due to microcracks linking up with an advancing main crack. The implications of this estimate for theoretical predictions of the toughening due to stress-induced microcracking are discussed.

CERN Document Server

In the positive column of a neon glow discharge, two different types of ionization waves occur simultaneously. The low-dimensional chaos arising from the nonlinear interaction between the two waves is controlled by a continuous feedback technique. The control strategy is derived from the time-delayed autosynchronization method. Two spatially displaced points of observation are used to obtain the control information, using the propagation characteristics of the chaotic wave.

Energy Technology Data Exchange (ETDEWEB)

The available measurements on the cosmic-ray antiproton/proton ratio show an excess of antiprotons above predictions derived in the framework of the standard picture of cosmic-ray origin and propagation. Calculations are performed of the production from collisions of cosmic rays with the interstellar gas under the condition of distributed reacceleration. It could be shown that the calculated antiproton/proton ratio is enhanced compared to that derived from the leaky box model, but it remains difficult to bring it into agreement with the data by reasonable astrophysical assumptions. 15 references.

Energy Technology Data Exchange (ETDEWEB)

An ignition timing control apparatus is described for an internal combustion engine having a reference ignition timing comprising: sensing means for sensing vibrations including knocks of the engine; knock signal deriving means for deriving knock signals from the output of the sensing means; correction magnitude determining means for determining from the knock signals derived by the knock signal deriving means of ignition timing correction magnitude for suppressing the occurrence of knock; displacement magnitude determining means for determining from at least one of an output of the knock signal deriving means and an output of the correction magnitude determining means as a displacement magnitude for the reference ignition timing corresponding to the octane rating of a fuel used in the engine; and ignition timing determining means for setting the reference ignition timing at an ...

International Nuclear Information System (INIS)

Assessment on the back end fuel cycle, in PEACER (Proliferation-resistant Environmental-friendly Accident-tolerant Continuable and Economical Reactor) that was designated as a new transmutation concept, was performed. Recovery system of uranium and TRU for PEACER is based on pyroprocessing. In the assessment of Long-Lived Fission Products (LLFP) wastes, initially "9"0Sr and "1"3"7Cs are dominant contributor nuclides until 30 years and especially "9"0Sr and "1"3"7Cs have the highest activity and decay heat than other LLFP. In this study, recovery of "9"0Sr and "1"3"7Cs is recommended for reducing of wastes loading. The acceptable decontamination factor is investigated by the toxicity of PEACER spent fuel. The acceptable decontamination factor is about 1.02E+05 for the actinides from PEACER spent fuel after 10 years cooling, 4.26E+05 after 100 years cooling, 1.97E+04 after 300 years cooling, 9.52E+03 after 1000 years cooling.

International Nuclear Information System (INIS)

The Mixed Waste Management Facility, or MWMF, has been proposed as a national testbed facility for the demonstration and evaluation of technologies that are alternatives to incineration for the treatment of mixed low-level waste. The facility design will enable evaluation of technologies at pilot scale, including all aspects of the processes, from receiving and feed preparation to the preparation of final forms for disposal. The MWMF will reduce the risk of deploying such technologies by addressing the following: (1) Engineering development and scale-up. (2) Process integration and activation of the treatment systems. (3) Permitting and stakeholder issues. In light of the severe financial constraints imposed on the DOE and federal programs, DOE/HQ requested a study to assess the cost benefit for the MWMF given other potential alternatives to meet waste treatment needs. The MVVMF Project was asked to consider alternatives specifically associated with commercialization and privatization ...

International Nuclear Information System (INIS)

The Quality Assurance Requirements and Description (QARD) is the principal quality assurance document for the Civilian Radioactive Waste Management Program (Program). It establishes the minimum requirements for the Quality Assurance Program. The QARD contains regulatory requirements and program commitments necessary for the development of an effective quality assurance program. Quality assurance implementing documents must be based on, and consistent with, QARD requirements. The QARD applies to the following: (1) acceptance of spent nuclear fuel and high-level radioactive waste; (2) transport of spent nuclear fuel and high-level radioactive waste; (3) the Monitored Retrievable Storage (MRS) facility through application for an operating license; (4) Mined Geologic Disposal System (MGDS), including the site characterization activities (exploratory studies facility (ESF) and surface based testing), through application for an operating license; (5) the high-level-waste ...

Energy Technology Data Exchange (ETDEWEB)

The goal of this project was to demonstrate that a new low-expanding ceramic (Ca{sub 0.6},Mg{sub 0.4})Zr{sub 4}(PO{sub 4}){sub 6}, hereafter referred to as CMZP, could be used as an exhaust manifold liner in off-road diesel engines and provide improved engine efficiency (by permitting higher engine operating temperature). This study has successfully demonstrated this improvement and further engine testing (and possible manufacturing) is presently underway at Caterpillar Inc. Laboratories. Basically this program involved two subcontracts: one to Virginia Tech to develop sintering procedures for CMZP, and one to Caterpillar, Inc. to develop slip casting procedures for CMZP. Nearly 100kg of CMZP were prepared by MATVA, Inc. and Virginia Tech for use by Caterpillar. Virginia Tech developed detailed sintering procedures for CMZP and Caterpillar developed slip casting procedures and manufactured several exhaust manifold elbows. These elbows have been cast into prototype cylinder heads and ...

Energy Technology Data Exchange (ETDEWEB)

A porous tooling system was selected for the processing of Graphite/PMR-15 Polyimide laminates in thickness up to 3.2 mm. (0.125 inch). This tool system must have a reasonable strength, permeability dimensional stability, and thermal conductivity to accomplish curing at 600 F and 200 psi and 200 psi autoclave temperature and pressure. A permeability measuring apparatus was constructed and permeability vs. casting water level determined to produce tools at three different permeability levels. On these tools, laminates of 5, 11, and 22 plies (.027, .060, and 0.121 inch) were produced and evaluated by ultrasonic, mechanical, and thermal tests to determine the effect of the tool permeability on the cured laminates. All tools produced acceptable laminates at 5 and 11 plies but only the highest permeability produced acceptable clear ultrasonic C-Scans. Recommendations are made for future investigations of design geometry, and strengthening techniques ...

Energy Technology Data Exchange (ETDEWEB)

A method to control charge transfer reaction in DNA using hybrid nanometer-sized TiO{sub 2} nanoparticles was developed. In this system extended charge separation reflects the sequence of DNA and was measured using metallic silver deposition or by photocurrent response. Light-induced extended charge separation in these systems was found to be dependent on the DNA-bridge length and sequence. The yield of photocatalytic deposition of silver was studied in systems having GG accepting sites imbedded in AT runs at varying distances from the TiO{sub 2} nanoparticle surface. Weak distance dependence of charge separation indicative of a hole hopping through mediating adenine (A) sites was found. The quantum yield of silver deposition in the system having a GG accepting site placed 8.5 {angstrom} from the nanoparticle surface was found to be {Phi} = 0.70 (70%) and {Phi} = 0.56 (56%) for (A){sub n} and (AT){sub n/2} bridge, respectively. Hole injection ...

Energy Technology Data Exchange (ETDEWEB)

To dispose the radioactive waste drums, the waste form's integrity and the nuclides inventories must be assured according to the national and site waste acceptance criteria. Because they might be would gravely affected the performance objectives of disposal site. Our national regulation for the waste inventory related to 'Radioactive Waste Acceptance Criteria' requires that the activities of 13 nuclides and gross {alpha} must be measured and the 95 % of nuclides incorporated in the drum must be identified. It is very difficult to measure the radioactivity with accuracy from the regulated waste drum(200L), and have a large error in the analysis results. In present, there are two system, SGS (Segmented Gamma Scanning System) and TGS (Tomographic Gamma Scanning System) for the analysis of radionuclides from the waste drums. In general, it is known that the accuracy of TGS is below 20 % and that of SGS is below 30 %. The ...

Energy Technology Data Exchange (ETDEWEB)

Commercial development of oil shale resources will produce vast quantities of processed shale waste. The presence of potentially toxic trace elements, inorganic salts, and potentially toxic residual organic constitutents make the disposal of vast quantities of processed shale a potential environmental problem. To be environmentally acceptable, processed shale disposal must: result in a physically stable structure, prevent or minimize release of potentially toxic compounds, and provide an economically acceptable post-land use. Water is the common element underlying all factors important to the environmental stability of disposed solid waste. The leaching and transport of solubles by water in processed shale embankments may result in degradation of local surface and groundwater quality. The major purpose of this research is to physically model, study, and describe the redistribution and movement of water and percolates in lifts of disposed ...