Science.gov (United States)

No Abstract Available

Energy Technology Data Exchange (ETDEWEB)

Objective of the project is characterization of electrode reactions in molten salt by using metal oxides and silica-based electrode. The scope of project are characterization of metal oxide properties in molten salt and miniaturization of 3-electrode electrochemical test cell. Electrochemical micro-cell for actinide-LiCl-KCl molten salt was newly designed. Electroless and electrochemical deposition technique was applied to Mo coating on quartz tube. From the design of electrode and 3-electrode electrochemical cell suitable for the tests in molten salt electrolyte, so it is anticipated to get the information on the electrochemical behavior of metallic electrode in molten salt and to secure the information on oxidation/reduction behavior of actinide

Energy Technology Data Exchange (ETDEWEB)

Hybrid electric vehicles (HEV) need long-lived high-power batteries as energy storage devices. Batteries based on lithium-ion technology can meet the high-power goals but have been unable to meet HEV calendar-life requirements. As part of the US Department of Energy's Advanced Technology Development (ATD) Program, diagnostic studies are being conducted on 18650-type lithium-ion cells that were subjected to accelerated aging tests at temperatures ranging from 40 to 70 C. This article summarizes data obtained by gas chromatography, liquid chromatography, electron microscopy, X-ray spectroscopy and electrochemical techniques, and identifies cell components that are responsible for the observed impedance rise and power fade.

Science.gov (United States)

Metal cations of arsenic, antimony, tin, manganese, zinc, cadmium, indium, and thallium have been evaluated in a preliminary way as possible3 inhibitors for controlling denting corrision observed in steam generators used with pressurized water reactors (PWR). The rationale for this approach was based upon the well-known inhibition effects of metal cations on corrosion rates in electrolyte/metal systems. A review of corrosion inhibition by metal cations (H. Leidheiser, Jr., Corrosion 36, 339 (1982)) has identified eleven inhibition mechanisms. The major test methods used for this evaluation were: (1) Isothermal capsule tests of carbon/steel/Inconel 600 tube bulging rates at temperatures up to 288/sup 0/C in seawater/copper-nickel chloride bulge-accelerating solutions. (2) Immersion weight-loss tests of steel coupled to Inconel 600 in boiling (102/sup 0/C) 3% sodium chloride solutions. In addition, ...

Energy Technology Data Exchange (ETDEWEB)

Two accelerated aging test procedures are proposed for use on solid dielectric extruded distribution cables under wet conditions. One test method is a fixed time duration test in which the degree of cable specimen aging is assessed in terms of breakdown tests, while the other test method is a time to breakdown test in which the cable specimens are voltage stressed until failure ensues.

International Nuclear Information System (INIS)

(Jun 1984). United States Clough, RL Gillen, KT Sandia Nat'l Laboratories

International Nuclear Information System (INIS)

The author discusses the accelerated aging tests performed using Hondo and Maya as aging resids with a commercial large pore hydrotreating catalyst. The results from these tests were compared with those obtained under a normal full life test. The test resid was a sample of a typical refinery charge and the activities for sulfur and vanadium removal were determined at 720"0F after successive brief periods of exposure to the heavier oils.

Energy Technology Data Exchange (ETDEWEB)

The electrochemical oxidation as a method to destroy drug residues like Aspirin {sup trademark}, tetracycline or gentamicin in water was investigated with C-Anode (modified by manganese oxides) and Pt Anode. The mechanism of Aspirin {sup trademark} and tetracycline oxidation and the influence of the biocide effect was observed using GC-MS and three different microbiological tests. In general the biological availability increases with progressive oxidation of the antibiotics. (orig.)

British Library Electronic Table of Contents (United Kingdom)

Flue gas desulfurization systems (FGDs) are operated in severely corrosive environments that cause sulfuric acid dew-point corrosion. The corrosion behavior of low-alloy steels was tested using electrochemical techniques (electrochemical impedance spectroscopy, potentiodynamic tests, potentiostatic tests), and the corrosion products were analyzed by scanning electron microscopy and X-ray photoelectron spectroscopy. The electrochemical results showed that alloying W with small amounts of Sb, Cu, and Co improves the corrosion resistance of steels. The results of surface analyses showed that the surface of the steels alloyed with W consisted of W oxides and higher amounts of Sb and Cu oxides. This suggests that the addition of W promotes the formation of a protective WO3 film, in addition to ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes the dielectric and accelerated aging tests on prototype {plus minus}500 kV dc oil-filled self-contained cables. The extensive test program was required to evaluate the High-Voltage cables for the St. Lawrence river crossing of the {plus minus}500 kV Quebec-New England HVDC power transmission system. The paper relates the main elements of the test program. It describes the required insulation levels, the characteristics of the cables supplied by three different manufacturers, as well as the cables' installation for the type tests and accelerated aging tests. Details of the test program and procedures followed to carry out the tests are given. Findings of the tests are also reported.

Energy Technology Data Exchange (ETDEWEB)

Improved test techniques are needed for evaluating the inherent stability of middle distillate fuels both in surveillance and in procurement activities. A project was initiated to define and evaluate the contributing conditions leading to the formation of deleterious products in accelerated aging tests of middle distillate fuels and to relate these results to an experimental definition of more repeatable/reliable middle distillate fuel stability test technique(s). A literature search was conducted to provide a list of stability test techniques and their interpretations which could be used in a correlative middle distillate fuel stability test program. For this program, seven accelerated stability tests were chosen and evaluated using a set of six test fuels. The test techniques ...

International Nuclear Information System (INIS)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. This paper describes the roles on corrosion. A corrosion test on precipitate-containing and precipitate-free materials made from pure zirconium and a small quantity of iron and chromium, rest potential measurements on an intermetallic compound of Zr(FeCr)_2 and zirconium matrix, and a galvanic coupling test of those were performed. Results showed that corrosion behavior of zirconium alloys could be attributed to the electrochemical properties of intermetallic compounds precipitated in each alloy. Namely, the cathodic and anodic polarization characteristics were associated with anodic protection provided by the precipitates on the alloys and the precipitates ...

Energy Technology Data Exchange (ETDEWEB)

Radiation-and-thermal-combined degradation of ethylene-propylene rubber (EP rubber) and chlorosulfonated polyethylene (CSM) as cable insulating and jacketing materials were evaluated by accelerated aging tests and a method to assess the lifetime of these materials under practical application was studied. EP rubber and CSM of experimental formulation were degraded at accelerated rates, that are 50 [approx] 1000 times the degradation rate under a standard condition (1Gy/h, 50degC). The degradation was investigated by measuring the tensile properties. In the accelerated aging tests, rates of elongation decrease owing to degradation for both EP rubber and CSM were in proportion to increase in accelerated rate. Behaviors of elongation changes showed little difference with accelerated rate. EP rubber lifetime estimated from sequential aging ...

International Nuclear Information System (INIS)

Initial design parameters and early operational results of a 50 MeV high brightness electron linear accelerator are described. The system utilizes a radio frequency electron gun operating at a frequency of 2.856 GHz and a nominal output energy of 4.5 MeV followed by two, 2#pi#/3 mode, disc loaded, traveling wave accelerating sections. The gun cathode is photo excited with short (6 psec) laser pulses giving design peak currents of a few hundred amperes. The system will be utilized to carry out infra-red FEL studies and investigation of new high gradient accelerating structures.

International Nuclear Information System (INIS)

Intergranular corrosion (IGC) resistance of types 304LN and 316LN stainless steels (SS) thermally aged at 823, 873, and 923 K for various durations was assessed by ASTM A262 practice A test (electrolytic etch test) and electrochemical potentiodynamic reactivation (EPR) test. The results indicated that the type 316LN SS has significantly improved IGC resistance compared to 304LN SS. Based on the results of these tests, time-temperature-sensitization (TTS) diagrams were developed for both alloys. The secondary precipitates formed during thermal aging treatments were electrochemically extracted and analyzed by X-ray diffraction (XRD) to determine the types of precipitates formed during the aging treatments. The results indicated that the precipitates were mostly of M_2_3C_6 carbides.

British Library Electronic Table of Contents (United Kingdom)

Manganese dioxide (MnO2) was prepared using the ultrasonic method. Its electrochemical performance was evaluated as the cathode material for a high voltage hybrid capacitor. And the specific capacitance of the MnO2 electrode reached 240 F.g-1. The new hybrid capacitor was constructed, combining Al/Al2O3 as the anode and MnO2 as the cathode with electrolyte for the aluminum electrolytic capacitor to solve the problem of low working voltage of a supercapacitor unit. The results showed that the hybrid capacitor had a high energy density and the ability of quick charging and discharging according to the electrochemical performance test. The capacitance was 84.4 mF, and the volume and mass energy densities were greatly improved compared to those of the traditional aluminum electrolytic capacito...

Energy Technology Data Exchange (ETDEWEB)

Accelerated aging tests such as high temperature burn-in, which are in current use on Bendix Kansas City Division's (BKC) purchased small and medium scale integrated circuits, were evaluated to determine if they are effective and necessary to ensure the required reliability. A theoretical analysis, a literature search, and a study of lot acceptance results were used to assess the value of integrated circuit burn-in.

Energy Technology Data Exchange (ETDEWEB)

The development of structural barriers for nuclear waste packages involves selection of candidate materials, their screening by mechanical and corrosion testing, rigorous accelerated testing, and evaluation and comparison with other package elements. This document presents results from work conducted on titanium and ferrous alloys.

International Nuclear Information System (INIS)

Radiation-and-thermal-combined degradation of some kinds of cable insulating and jacketing materials was evaluated by accelerated aging tests. Plasticized polyvinyl chloride (PVC), silicone rubber, crosslinked and non-crosslinked halogen-free flame-retardant polyolefins (NH-XLPO and NH-PO) and ethylene-propylene rubber (EP rubber) of experimental formulation were degraded at accelerated rates, that are 50-1000 times the degradation rate under standard conditions (e.g.; 1Gy/h, 50degC), and a method to assess the lifetime of these materials under standard conditions was studied. The degradation was investigated by measuring tensile properties. In the accelerated aging tests, rates of elongation decrease owing to degradation for these materials were in proportion to the increase in accelerated rate. The PVC lifetime estimated from sequential aging ...

International Nuclear Information System (INIS)

This paper shows how molecular theory paves the way for accelerated aging tests of safety-related equipment in nuclear power plants, as required by NRC qualification programs. Arrhenius' model, based on an equation, provides useful information regarding the extent of molecular change as a function of time and temperature. Critical to determining the aging characteristics and qualified life of organic materials is the activation energy concept, which is derived from information gathered when the molecular reaction of the material is documented over the entire life cycle. In accelerated-aging applications, the importance of the model lies in characterizing the chemical related reactions of materials. The problem with the Arrhenius approach is that, in generating a testing period of reasonable duration, a rather high test temperature must be selected which may lead to an added and ...

Energy Technology Data Exchange (ETDEWEB)

A study was conducted under the auspices of the Coordinating Research Council, Inc. (CRC) to assess the potential effects of gasoline octane quality on vehicle acceleration performance. Twelve participating laboratories, representing both the oil and the automotive industries, tested a total of 182 vehicles as part of the 1989 CRC Octane Number Requirement Survey. The vehicles consisted of 78 with electronic knock control systems and 104 without. All testing was performed using the 1989/1990 CRC FBRU fuel series. The results showed that acceleration performance of vehicles with knock sensors was significantly affected by gasoline octane quality. Octane effects on acceleration performance were most pronounced at maximum-throttle (detent) conditions and at octane levels below the vehicles' octane requirements; however, some knock-sensor vehicles did show improved ...

International Nuclear Information System (INIS)

Long-term aging of organic materials in reactor containment buildings has become a major issue within the nuclear community. In this article, the status of radiation-aging qualification test requirements in several countries is reviewed, and problems with the current aging methodologies are described. These problems include dose-rate and synergistic effects and environmental synergisms, which have been found for many different polymeric materials. A number of approaches to improved accelerated-radiation-aging tests for prediction of long-term aging behavior are discussed together with their limitations.

Energy Technology Data Exchange (ETDEWEB)

An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorption (TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at different temperatures. The TPD experiments consist of heating the samples from room temperature to 950 C and of ...

Science.gov (United States)

We study a two-level atom in interaction with a real massless scalar quantum field in a spacetime with a reflecting boundary. The presence of the boundary modifies the quantum fluctuations of the scalar field, which in turn modifies the radiative properties of atoms. We calculate the rate of change of the mean atomic energy of the atom for both inertial motion and uniform acceleration. It is found that the modifications induced by the presence of a boundary make the spontaneous radiation rate of an excited inertial atom oscillate near the boundary and this oscillatory behavior may offer a possible opportunity for experimental tests for geometrical (boundary) effects in flat spacetime. While for accelerated atoms, the transitions from ground states to excited states are found to be possible even in a vacuum due to changes in the vacuum fluctuations induced by both the presence of the boundary and the ...

Energy Technology Data Exchange (ETDEWEB)

A description of the FEL experiment underway at the 10 kA, 5 MeV Experimental Test Accelerator (ETA) is described. The facility has been designed to investigate the high-gain operation of an FEL.

Science.gov (United States)

To calibrate channels A1 to A4 for particles with Z >= 1, tests were done on the IBIS accelerator at AERE, Harwell, which gave protons up to 3 MeV. ...

Energy Technology Data Exchange (ETDEWEB)

In the present work, electrochemical measurements and corrosion tests in NaCl solutions were carried out to study the effect of aging treatments on pitting corrosion behavior in a 8090 alloy and its high purity Al-Li binary alloy analogue. The pitting corrosion characteristics and corrosion resistance of the 8090 alloy have been determined in relation to precipitation microstructures. (orig.).

International Nuclear Information System (INIS)

This paper evaluates the performance of asphalt membranes by examining the chemical and permeability changes experienced by the asphalt during aging tests. The aging process was accelerated by exposing the asphalt to elevated temperatures, high oxygen concentrations, and increased strengths of aqueous oxidizing agents. The synergistic effects of the variables are evaluated by using a fractional factorial experimental design. The installation costs for a catalytically airblown asphalt liner are roughly half that of the typical polymeric materials, and also less than the rubberized asphalt membrane. The results of the initial accelerated aging tests of the asphalt membranes indicate that this material will provide stable, long-term leachate isolation in a mill tailings environment.

Energy Technology Data Exchange (ETDEWEB)

In a work studying the corrosion and tarnishing properties of a variety of copper alloys, the alloy Cu-A110-Sn5 was found to show an excellent corrosion resistance in neutral solutions, where copper and most conventional Cu alloys are covered by thick nonprotective surface layers. The passive films formed on this alloy were characterized with electrochemical and photoelectrochemical methods. The pH dependence of the passivation and of the photocurrent behavior of the Cu-A110-Sn5 alloy clearly indicates that the passivity of this alloy in neutral solutions is due to a formation of passive film enriched with aluminum oxide. At corrosion potential a strong increase in the corrosion resistance with time is due to a gradual enrichment of the surface with aluminum oxide. This can be seen in the photocurrent spectra which change from cooper-type to aluminum-type with time. At higher applied potentials the formation of an aluminum-type oxide film is strongly ...

Energy Technology Data Exchange (ETDEWEB)

Three-dimensional porous Sn thin film electrodes were prepared by electroless deposition on copper foam, then its morphology and electrochemical property were studied by means of scanning electron microscope (SEM), X-ray diffraction (XRD), electrochemical cycling test and cyclic voltammetry (CV). The porous framework and micro-holes have shown a great structure advantage in restricting severe volume changes when the Sn thin film was employed as anode for lithium-ion battery. The film electrode of sample C with an initial capacity of 676 mAh g{sup -1} showed good cycle performance displayed by retaining a capacity of 313 mAh g{sup -1} after 100 cycles.

International Nuclear Information System (INIS)

A series of spinel Li4Ti5O12 samples were synthesized via a composite molten-salt method (CMSM) using the mixtures of LiCl and KCl with different L values (L is defined as the molar ratio of LiCl:KCl) as the reaction media. It is found that the melting point of the composite molten salt can effectively influence the formation of particles, and leads to different electrochemical performances of the as-prepare Li4Ti5O12. The investigations of X-ray diffraction (XRD), particle size distribution (PSD), Brunauer-Emmet-Teller (BET) surface area, and scanning electron microscopy (SEM) indicate that the as-prepared Li4Ti5O12 with L = 1.5 is a pure phase, and has uniform homogeneous octahedral shape particles, rather narrow PSD, and high BET surface area. Electrochemical tests show that the optimized Li4Ti5O12 with L = 1.5 has an initial discharge capacity of 169 mAh g-1 and an initial charge-discharge efficiency of 94% at 0.2 C ...

Energy Technology Data Exchange (ETDEWEB)

Cold plasma nitriding treatment was performed to improve the corrosion resistance of C38 carbon steel. Nitriding process was conducted using a radiofrequency nitrogen plasma discharge for different times of treatment on non-heated substrates. The modification of the corrosion resistance characteristic of the C38 steel due to the treatment in acid medium (1 M HCl) were investigated by gravimetric and electrochemical tests such as potentiodynamic polarisation curves and electrochemical impedance spectroscopy (EIS). It was shown that the plasma nitriding treatment improves the corrosion resistance. Indeed, in the gravimetric tests, nitrided samples showed lower weight loss and lower corrosion rate in comparison to untreated one. In the Tafel polarisation tests, the nitrided samples showed greatly reduced corrosion current densities, anodic dissolution and also retarded the hydrogen ...

Energy Technology Data Exchange (ETDEWEB)

Spherical {beta}-Ni(OH){sub 2} was modified by a low-cost method of normal ball milling (NBM), and the physical properties of both ball-milled and un-milled Ni(OH){sub 2} were characterized by transmission electron microscopy, specific surface area, particle size distribution and X-ray diffraction. It was found that NBM could obviously increase the surface area, decrease the particle and crystallite size, and reduce the crystallinity of {beta}-Ni(OH){sub 2}, which were advantageous to the improvement of the electrochemical activity of Ni(OH){sub 2}. NBM also lowered the packing density and flowability of Ni(OH){sub 2}, as revealed by the measurements of tapping density and angle of repose. Electrochemical performances of pasted nickel electrodes with an addition of ball-milled Ni(OH){sub 2} to spherical Ni(OH){sub 2} as the active material were investigated, and were compared with those of the pure spherical Ni(OH){sub 2} electrodes. ...

Energy Technology Data Exchange (ETDEWEB)

An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution [1-3] according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorpt(TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at different temperatures. The TPD experiments consist of heating the samples from room temperature to 950 C and ...

Energy Technology Data Exchange (ETDEWEB)

As part of a coordinated program, AECL is developing a set of tools to aid with the prediction and management of steam generator performance. Although stress corrosion cracking (of Alloy 800) has not been detected in any operating steam generator, for life management it is necessary to develop mechanistic models to predict the conditions under which stress corrosion cracking is plausible. Therefore, constant extension rate tests were carried out for Alloy 800 under various steam generator crevice chemistry conditions at applied potentials. These tests were designed to evaluate the stress corrosion cracking susceptibility of Alloy 800 under CANDU( steam generator operating conditions. Based on the experimental results, the recommended electrochemical corrosion potential/pH zone for Alloy 800 determined by electrochemical polarization measurements was verified with the respect of stress corrosion cracking ...

Energy Technology Data Exchange (ETDEWEB)

The Electric Fuel Limited (EFL) refuelable zinc-air battery system is currently being tested in a number of electric vehicle demonstration projects, the largest of which is a field test of zinc-air postal vans sponsored chiefly by Deutsche Post AG (the German Post Office). The zinc-air battery is not recharged electrically, but rather is refueled through a series of mechanical and electrochemical steps that will require a special infrastructure in commercial application. As part of the German Post Office field test program, Electric Fuel designed and constructed a pilot zinc anode regeneration plant in Bremen, Germany. This plant is capable of servicing up to 100 commercial vans per week, which is adequate for the field test vehicle fleet. This paper will describe the design and operation of each of the areas and devices within the plant.

Energy Technology Data Exchange (ETDEWEB)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. In the previous paper, corrosion mechanism was elucidated by the anodic protection-precipitates degradation model. This paper describes the roles on hydrogen pickup. 633 K pure water autoclave test was performed on high purity zirconium, Zr-0.2Fe, Zr-0.2Cr, and Zr-0.1Fe-0.1Cr alloys. Hydrogen analysis after the corrosion test showed that hydrogen pickup ratio of Zr-0.2Fe alloy was about 80%. It was much higher than about 30% of pure Zr and about 10% of both Zr-0.2Cr and Zr-0.1Fe-0.1Cr alloys. Larger hydrogen content was introduced into Zr-0.2Fe alloy than the other ones by the cathodic hydrogen charging under coulombic equivalence. The precipitates at metal-oxide interface could ...

Energy Technology Data Exchange (ETDEWEB)

The Two-Beam Accelerator (TBA) consists of a long high-gradient accelerator structure (HGS) adjacent to an equal-length Free Electron Laser (FEL). In the FEL, a beam propagates through a long series of undulators. At regular intervals, waveguides couple microwave power out of the FEL into the HGS. To replenish energy given up by the FEL beam to the microwave field induction accelerator units are placed periodically along the length or the FEL. In this manner it is expected to achieve gradients of more than 250 MV/m and thus have serious option for a 1 TeV /times/ 1 TeV linear collider. The state of present theoretical understanding of the TBA is presented with particular emphasis upon operation of the ''steady-state'' FEL, phase and amplitude control of the rf wave, and suppression of sideband instabilities. Experimental work has focused upon the development of a suitable HGS and the ...

Energy Technology Data Exchange (ETDEWEB)

Accelerated aging tests on gold bridgewired detonator assemblies to determine compatibility of the Au and Pd-In-Sn solder with the organic explosive, PENT, have revealed an unusual corrosion process. These tests, conducted at 74/sup 0/C and 54/sup 0/C indicated a preferential attack of the gold. A matrix of corrosion test units was established to study this corrosion problem with accelerating temperatures up to 100/sup 0/C. Scanning electron microscopy (SEM), energy dispersive x-ray (EDX), and x-ray diffraction techniques were used to determine the extent of the corrosion and identify the corrosion products. Results indicate the preferential attack of the gold was due to HCN formed by decomposition of the explosive powder (PETN) at high temperatures. Other associated reactions were also observed including subsequent attack of the solder by the gold corrosion product and degradation ...

Energy Technology Data Exchange (ETDEWEB)

The fundamental mechanisms underlying the chemical degradation of polymers can change as a function of environmental stress level. When this occurs, it greatly complicates any attempt to use accelerated tests for predicting long-term material degradation behaviors. Understanding how degradation mechanisms can change at different stress levels facilitates both the design and the interpretation of aging tests. Oxidative degradation is a predominant mechanism for many polymers exposed to a variety of different environments in the presence of air, and there are two mechanistic considerations which are widely applicable to material oxidation. One involves a physical process, oxygen diffusion, as a rate-limiting step. This mechanism can predominate at high stress levels. The second is a chemical process, the time-dependent decomposition of peroxide species. This leads to chain branching and can become a rate-controlling factor at ...

International Nuclear Information System (INIS)

This paper describes new test methodologies to obtain data used to evaluate the ultimate seismic strength of Nuclear Power Plant (NPP) equipment related to nuclear safety. The paper first reviews existing equipment seismic test data from the viewpoint of the evaluation of their ultimate seismic strength and/or seismic design margins, and extracts the issues in the existing data with regard to their applicability to the evaluation. Then, the paper proposes new test methodologies for the equipment to evaluate their ultimate seismic strength. The test methodology of the equipment employs a vibration amplification system to a shaking table and enhances its applicable maximum acceleration up to 6g. The test methodology herein is cost effective for obtaining test data that is indispensable for evaluating proper seismic margins of NPPs. (author)

Energy Technology Data Exchange (ETDEWEB)

This paper describes the implementations of a fuzzy logic based self-tuned controller to improve the stability of electric power systems. The stabilizing signal is computed using the standard fuzzy membership function depending on the speed/acceleration state of the generator in the phase plane. The performance of the proposed stabilizer is demonstrated by practical implementation using a digital signal processor mounted on a PC-AT. Results of the experimental tests on a physical model of a power system are presented.

CERN Document Server

The CLIC (Compact Linear Collider) high-gradient RF structure testing program has been carried out in order to gain insight into the physical processes involved in RF breakdown, determine the mechanisms that limit gradient and produce damage so that technical concepts can be developed which allow higher accelerating gradients. Two main paths towards higher gradients have emerged from this program, and the performances of two new structures which incorporate them are presented.

British Library Electronic Table of Contents (United Kingdom)

The term biological motion is often used by researchers studying the patterns of movement generated by living forms and in sports. We studied a pattern recognition system of motion in sport using biological motion data. Biological motion data are acquired using a 3D motion capture system. However, 3D motion capture systems are very expensive. In this article, a biological motion capture system was built using acceleration sensors. Our proposed system uses the technique of Gaussian fitting and regression analysis. We tested our proposed system in pattern recognition of outdoor tennis and its evaluations.

Energy Technology Data Exchange (ETDEWEB)

The radiation degradation behavior of three commercial polyvinyl chloride (PVC) materials has been investigated. All three exhibit an interesting reversal in the trend of the tensile strength part way through the aging experiment: the tensile strength first drops, then rises. The early drop is associated with oxidative scission; the rise is associated with crosslinking and is preceded by the material reaching the gel point. It was also found that the tensile elongation tended to level out in advanced stages of aging with the leveling-out values dependent on the dose rate. These phenomena pose complications for the design of accelerated aging tests.

International Nuclear Information System (INIS)

TiO2 addition into boiling water reactor (BWR) primary system is being developed as a method to mitigate stress corrosion cracking (SCC) of the BWR structural materials. This technique aims for electrochemical corrosion potential (ECP) decrease of reactor materials by photo-excitation reaction under Cherenkov irradiation. ECP measurement tests have been conducted in the test loop in BWR to investigate the feasibility of the SCC mitigation method with TiO2. The test results showed that the ECP of TiO2 deposited materials was decreased to 2 technique was confirmed to be feasible as a SCC mitigation method for BWR structural materials without hydrogen injection. (author)

Energy Technology Data Exchange (ETDEWEB)

The fluid-induced vibration level of instrumented capsule, which was manufactured for fuel irradiation test at the reactor core of HANARO, was investigated. For this purpose, the instrumented capsule was loaded at the OR site of the HANARO design verification test facility that could simulate identical flow condition as the HANARO core. Then, vibration signals of the instrumented capsule subjected to various flow conditions were measured by using vibration sensors. In time domain analysis, maximum amplitudes and RMS values of the measured acceleration and displacement signals were obtained. By using frequency domain analysis, frequency components of the fluid-induced vibration were analyzed. In addition, natural frequencies of the instrumented capsule were obtained by performing modal test. The frequency analysis results showed that the natural frequency components near 7.5Hz and 17.5Hz were dominant in ...

International Nuclear Information System (INIS)

Three different techniques for pitting corrosion potential measurement on austenitic stainless steel (Fe18Cr10Ni) were compared: conventional polarization method, a new Avesta electrochemical corrosion measurement cell and a scratch technique. Special attention was paid to the effects of crevice corrosion during pitting corrosion potential measurement and to their elimination. Development of a rapid test technique for reliable pitting corrosion potential determination was aimed at and resulted from comparison of the different techniques.

Energy Technology Data Exchange (ETDEWEB)

In order to improve the capacity and service life of cathodes, the effect of carboxy-methyl cellulose, soot, silica gel and fibres was examined. Structural tests and electrical and electro-chemical measurements are used for this. The additives can affect crystallization in the manufacturing stage of the electrodes and can increase the storage capacity for water and the electronic conductivity. They act to stabilize the mass in cyclic operation. Soot additive has little effect on the properties of the electrode, but the other substances increase the service life or the use of the mass. (LU).

Energy Technology Data Exchange (ETDEWEB)

Accelerated aging tests have been conducted to evaluate the long-term durability of cementitious material against aggressive ions. In tests, cementitious specimens were immersed in the solutions containing concentrated aggressive ions at high temperature and it promoted diffusion of the ions in the specimen. This method would be suitable for the evaluation on the aging as the alteration of the specimen would be expected to resemble the natural behavior. This paper presents a classification of alteration mechanism in the immersion tests using MgCl{sub 2} and Na{sub 2}SO{sub 4} solution. This classification was done by relating the changes of compressive strength to microscopic and mineralogical changes.

Energy Technology Data Exchange (ETDEWEB)

Corrosion probes are being developed and combined with an existing measurement technology to provide a tool for assessing the extent of corrosion of metallic materials on the fireside in coal-fired boilers. The successful development of this technology will provide power plant operators the ability to (1) accurately monitor metal loss in critical regions of the boiler, such as waterwalls, superheaters, and reheaters; and (2) use corrosion rates as process variables. In the former, corrosion data could be used to schedule maintenance periods and in the later, processes can be altered to decrease corrosion rates. The research approach involves laboratory research in simulated environments that will lead to field tests of corrosion probes in coal-fired boilers. Laboratory research has already shown that electrochemically-measured corrosion rates for ash-covered metals are similar to actual mass loss corrosion rates. ...

Energy Technology Data Exchange (ETDEWEB)

The Fermilab Linac Upgrade is planned to increase the energy of the H- linac from 200 to 400 MeV. This is intended to reduce the incoherent space-charge tuneshift at injection into the 8 GeV Booster which can limit either the brightness or the total intensity of the beam. The Linac Upgrade will be achieved by replacing the last four 201.25 MHz drift-tube tanks which accelerate the beam from 116 to 200 MeV, with seven 805 MHz side-coupled cavity modules operating at an average axial field of abut 7.5 MV/m. This will allow acceleration to 400 MeV in the existing Linac enclosure. Each accelerator module will be driven with a klystron-based rf power supply. A prototype rf modulator has been built and tested at Fermilab, and a prototype 12 MW klystron is being fabricated by Litton Electron Devices. Fabrication of production accelerator modules is in progress. 8 figs., 4 tabs.

Energy Technology Data Exchange (ETDEWEB)

The Tevatron accelerator at Fermilab incorporates long two-phase helium passages. During magnet design, the generalized flow map of Baker was used to predict homogeneous flow. Longer than expected magnet time constants led to this investigation. The importance of predicting the flow regime has been amplified with the advent of non-horizontal accelerator designs. A test setup was constructed at Fermilab to investigate two-phase helium flow regimes for conditions practical in accelerator designs. The setup consisted of a standard Tevatron satellite refrigerator, subcooling dewar, heater, 35 m long transfer line, and a specialized end box. A knife blade on the midplane of the transfer line diverted the flow from the upper and lower halves of the pipe to separate vessels in the end box. The amount of liquid above and below the plane was measured at various total mass flow rates and liquid percentages. The ...

Science.gov (United States)

A comparative analysis between conventional passive twin tube dampers and skyhook-controlled magneto-rheological fluid (MRF) dampers for motorcycle front suspensions is provided, based on single axis testing in a damper test rig and suspension performance testing in road trials. Performance motorcycles, while boasting extremely light suspension components and competition-ready performance, have an inherent weakness in comfort, as the suspension systems are designed primarily for racing purposes. Front suspension acceleration and shock loading transmit directly through the front suspension triple clamp into the rider's arms and shoulders, causing rapid fatigue in shoulder muscles. Magneto-rheological fluid dampers and skyhook control systems offer an alternative to conventional sport motorcycle suspensions - both performance and comfort can be combined in the same package. Prototype MRF dampers designed ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of the Microelectronic Evaluation Laboratory at Sandia is to develop a program for evaluating CMOS LSI (complementary metal oxide silicon - large scale integrated) technology devices which are being used for the first time in a weapon system. These evaluations are based on accelerated aging studies and electrical tests to determine the reliability and life of the devices. In accelerated aging, specific, controlled stresses are applied to the device to accelerate time-to-failure. Data are used tin mathematical models to estimate life in acutal use. The stresses used for this technology are temperature and voltage. The devices are stored at temperatures with or without voltage applied (steady-state or cyclical) and periodically tested until at least 50% failures are encountered. Since most current technologies use epoxy-die-attachment, aging temperatures must be under ...

Energy Technology Data Exchange (ETDEWEB)

Short communication.

International Nuclear Information System (INIS)

Short communication.

Energy Technology Data Exchange (ETDEWEB)

Advances in the theory and practice of stress corrosion cracking (SCC) are reviewed for the period 1965-1990. The proceedings of two landmark conferences are used as a basis for discussion: Ohio State University (1967) and Kohler, WI (1988). The discussion is developed around the following topics: metal-environment combinations, testing, fractography, metallurgical aspects, electrochemical aspects and crack chemistry, mechanisms, and prediction and mitigation. It is concluded that the main developments since 1967 are the recognition of the lack of specificity of SCC environments, the use of slow strain rate and fracture mechanics testing, quantitative SEM fractography, studies of grain boundary structure and compositions, transient electrochemistry of bare metal surfaces, measurement and modelling of crack chemistry, elaboration of several SCC models, including slip-dissolution and film induced cleavage, and mitigation by ...

Energy Technology Data Exchange (ETDEWEB)

Corrosion behavior of deposition coated specimens prepared by the technique proposed by the authors is investigated in salt immersion tests, and also those of pure magnesium, 3N, 4N and 6N grades, and magnesium alloys, AZ31 and AZ91E, are investigated for comparison. Inhomogeneous corrosion occurs in AZ31 and AZ91E alloys when buffered solutions with pH values of 6.5 and 9.0 including 1% NaCl and a conventional 3% NaCl solution are used for immersion tests, while 6N-Mg shows homogeneous corrosion in such solutions. Corrosion behavior of the deposition coated specimen resembles that of 6N-Mg. Purification process included in the deposition coating technique provides homogeneity in microstructural and electrochemical terms, which results in improving corrosion resistance. (orig.)

International Nuclear Information System (INIS)

Due to the well-establish corrosion problems of Alloy 600 as a steam-generator material and the subsequent focus on thermally treated (TT) Alloy 690 and Alloy 800 as alternative materials, a systematic analysis of the corrosion behavior of these two latter alloys is warranted. Corrosion test results for Alloys 690 TT and 800 were collected and organized in the form of corrosion mode diagrams. Selected data for mill annealed (MA) Alloy 600 were also included for reference. The corrosion mode diagrams correlate the modes of corrosion degradation observed in tests as functions of the environment pH and electrochemical potential (ECP). The diagrams confirm that Alloys 690TT shows some susceptibility in caustic environments, and Alloy 800 shows susceptibility in both caustic and highly acidic environments. (authors). 6 figs., 5 refs.

Energy Technology Data Exchange (ETDEWEB)

Beyond a great number of applications in mineral process, the hydrocyclone separation has been used recently in an increasing number of fields, such as: environmental engineering, petrochemical engineering, food engineering, electrochemical engineering, pulp bioengineering, processes and paper industries, among others. Nowadays, the produced water is treated and then reinjected in the surface and also in return to the formation. In the offshore platforms, the produced water can be directly discarded in the ocean, since the dispersed phase concentration (oil) is according to Brazilian regulating agency limits. The basic principle used in hydrocyclone separation is the centrifugal sedimentation machine: the suspended particles are submitted to centrifugal acceleration, which separates them from the fluid. The basic geometry of a hydrocyclone consists of four parts: a cylindrical section for feeding, a conical section for swirling, an overflow and ...

Energy Technology Data Exchange (ETDEWEB)

For the first time, rheological phase method, a simple and effective route, is applied to synthesize novel cathode material LiCoPO{sub 4}. X-ray diffraction spectrometer (XRD), X-ray photoelectron spectrometer (XPS), transmission electron microscope (TEM) and electrochemical impedance spectroscopy (EIS) are taken to investigate this material, respectively. XRD figure shows that the rheological sample is better crystallized than the solid-state one. XPS result of the rheological sample exhibits that the valence of Co is 2+. TEM images show that better dispersed particles with smaller size can be formed by rheological method comparing to the solid-state route. Charge-discharge test is carried out in the range of 3.0-5.0 V at 0.2 mA cm{sup -2}. The initial discharge capacity for rheological phase and solid-state powder is 71.5 and 30.9 mAh g{sup -1}, respectively. The better electrochemical property should be ascribed to the ...

Energy Technology Data Exchange (ETDEWEB)

The lithium battery, also called `lithium-carbon` or `lithium ion`, is today the most promising candidate that can reach the expected minimum traction performances of electric powered vehicles. Thanks to a more than 20 years experience on lithium generators and to a specific research program on lithium batteries, the SAFT company has developed a 100 Ah electrochemical system, and full-scale prototypes have been manufactured for this application. These prototypes use the Li{sub x}NiO{sub 2} lithiated graphite electrochemical pair and were tested in terms of their electrical performances. Energy characteristics of 125 Wh/kg and 265 Wh/dm{sup 3} could be obtained. The possibility of supplying a power greater than 200 W/kg, even at low temperature (-10 deg. C) has been demonstrated with these elements. A full battery set of about 20 kWh was built and its evaluation is in progress. It comprises the electronic control systems for ...

Energy Technology Data Exchange (ETDEWEB)

A three-dimensional computational fluid dynamics (CFD) electrochemical model has been created to model high-temperature electrolysis stack performance and steam electrolysis in the Idaho National Laboratory (INL) Integrated Lab Scale (ILS) experiment. The model is made of 60 planar cells stacked on top of each other operated as Solid Oxide Electrolysis Cells (SOEC). Details of the model geometry are specific to a stack that was fabricated by Ceramatec, Inc. and tested at INL. Inlet and outlet plenum flow and distribution are considered. Mass, momentum, energy, and species conservation and transport are provided via the core features of the commercial CFD code FLUENT. A solid-oxide fuel cell (SOFC) model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. The FLUENT SOFC user defined subroutine was modified for this work to allow for operation in the SOEC mode. ...

International Nuclear Information System (INIS)

An analysis is presented of the motion of test particles in Goedel's universe. Both geodesical and nongeodesical motions are considered; the accelerations for nongeodesical motions are given. Examples for closed timelike world lines are shown and the dynamical conditions for time travel in Goedel's space-time are discussed. It is shown that these conditions alone do not suffice to exclude time travel in Goedel's space-time. (author).

CERN Document Server

A quantitative description is presented of the non-linear current-voltage response in superconducting niobium cavities for accelerator application. It is based on a fit for a large sample of data from cavity tests of different kind. Trial functions for the surface resistance describing this non-linear relation are established by a least square data fit. Those trial functions yielding the best fit are quantitatively explained by basic physics.

Energy Technology Data Exchange (ETDEWEB)

The authors present design methodology and initial experimental results for a high power microwave switch. The switch is designed for application to the pulse compression system associated with the Next Linear Collider Test Accelerator (NLCTA). The switch is based on the excitation of a plasma layer within a silicon wafer by either a laser or an electron beam. They investigate problems associated with high power operation of such a switch. They explore solutions to the problems of thermal runaway, avalanche breakdown, photo-emission, and secondary emission.

Energy Technology Data Exchange (ETDEWEB)

Electric and hybrid-electric vehicles are being developed and commercialized around the world at a rate never before seen. These efforts are driven by the prospect of vehicles with lower emissions and higher fuel efficiencies. The widespread adaptation of such vehicles promises a cleaner environment and a reduction in the rate of accumulation of greenhouse gases, Critical to the success of this technology is the use of electrochemical power sources such as batteries and fuel cells, which can convert chemical energy to electrical energy more efficiently and quietly than internal combustion engines. This overview will concentrate on the work being conducted in the US to develop advanced propulsion systems for the electric and hybrid vehicles, This work is spearheaded by the US Advanced Battery Consortium (USABC) for electric vehicles and the Partnership for a New Generation of Vehicle (PNGV) for hybrid-electric vehicles, both of which can be read about on the world ...

CERN Document Server

The International Linear Collider Main Linacs are based on superconducting accelerator structures operating at 1.3 GHz. The basis for this design has been developed and tested at DESY and R&D is progressing at many laboratories around the world including DESY, Orsay, KEK, FNAL, SLAC, Cornell, and JLAB. The status of the TESLA-style cavities and rf system will be reviewed and parameters for the ILC linac will be described. The role of the different linac test facilities will discussed and the critical items and R&D program to support a Conceptual Design and Technical Design will be outlined.

International Nuclear Information System (INIS)

In the scope of the nuclear plants lifetime study, the behavior of the cooling towers is discussed. The main geometrical characteristics of the cooling towers in the French nuclear power plants, are presented. The surveyance program, the risks of accident, the research and development actions are considered. The results of the investigations of the cooling tower structure show that it is a multidiciplinary problem and needs the development of experimental and theoretical methods. Concerning the regenerators, the surveyance actions under operating conditions, the accelerated aging tests, and some aspects of the mechanical resistance, are underlined. It is shown that mainly the creep tests will allow the lifetime estimation of the materials developed for the regenerators.

CERN Document Server

A Bragg curve ionization chamber for acceleration mass spectrometry

Energy Technology Data Exchange (ETDEWEB)

Ultra High Vacuum (UHV) test setup for electron gun testing has been developed. The development of next generation light sources and accelerators require development of klystron as a radio frequency power source, and in turn electron gun. This UHV electron gun test setup can be used to test the electron guns ranging from high average current, quasi-continuous wave to high peak current, single pulse etc. An electron gun has been designed, fabricated, assembled and tested for insulation up to 80 kV under the programme to develop high power klystron for future accelerators. Further testing includes the electron emission parameters characterization of the cathode, as it determines the development of a reliable and efficient electron gun with high electron emission current and high life time as well. This needs a clean ultra ...

Energy Technology Data Exchange (ETDEWEB)

The authors report experimental results on a high gradient 17 GHz RF photocathode gun. The photocathode RF gun is a novel electron beam source intended to meet the requirements set by future high-energy linear colliders and next generation free electron lasers. A coupled pair of pillbox TM{sub 010}-like resonators is excited by sidewall coupled microwaves at 17 GHz. A picosecond ultraviolet laser pulse illuminates one wall of the structure at the axis of symmetry. Electrons are released by the photoelectric effect and are accelerated by the electric field of the microwaves in the cavity. The high frequency of operation raises the RF breakdown limit allowing strong electric fields to be used. In turn, the intense fields result in rapid acceleration of the electrons to relativistic speeds and reduced space charge induced emittance growth.

Energy Technology Data Exchange (ETDEWEB)

In order to verify long-term reliability of amorphous alloy wound core distribution transformers, accelerated aging tests and field trials used by actual transformers were practiced. As for accelerated aging tests, short-circuit tests were added to imitate mechanical stress in operation on a utility's distribution system. As a result, even after the equivalent of 30 years, which was the normal expected transformer's life, magnetic characteristic was unchanged, so these transformers could be operated. Also, about field trials, two hundred transformers of four kinds were installed on a utility's distribution system to look into no-load characteristics. They were equipped with a mechanism to measure load current, background vibration and lightning surge current, so the influence for magnetic characteristic could be inspected. As a result, remarkable change ...

Energy Technology Data Exchange (ETDEWEB)

The insulating oil used in a transformer is a critical component, as its service life is typically 20 years with possibly little or no maintenance. Partial discharges (PD), thermal overloads and static discharges continually subject the oil to chemical deterioration during its operating life. To ensure equipment reliability during service, it is important that the initial quality of the new insulating oil should meet the required acceptance specifications and preferably be pre-tested before use. Accelerated aging tests have been devised to determine the life expectancy of oil in service by using forced air or oxygen flow into the oil, the presence of a copper catalyst, and at elevated temperatures. The more important standards relating to transformer application are discussed and highlights of the more important aspects of the oxidation chemistry of hydrocarbons are included. The ultimate aim of the project is the ...

Environmental Research Database

ObjectivesThe overall scientific aim of this project is, through development of an appropriate numerical modelling tool, to identify and investigate the mechanisms that control the current observed rapid thinning and acceleration of Greenland outlet glaciers and to investigate their likely future behaviour in the context of climate warming. This aim is addressed through the four major specific objectives below. These objectives build on each and therefore the order of priority is driven by the order in wh [continued...]DescriptionCurrently, the Greenland ice sheet is undergoing rapid changes in the coastal regions which have been attributed to a general warming trend to the regions climate over the last decade. Several of the narrow and fast flowing outlet glaciers that drain the ice sheet into the sea are observed to have accelerated their flow and thinned. For instance, Jakobshavn Isbrae on the West coast of Greenland has almost doubled its ...

Energy Technology Data Exchange (ETDEWEB)

The performance of four different organic coating systems applied to carbon and weathering steel coupons has been assessed in this investigation. applied on the surface of carbon steel and weathering steel coupons. The coupons have been evaluated using five different tests, three field tests and two accelerated tests. The field tests were carried out at three atmospheric stations, located at COSIPA in Cubatao-SP, at Alto da Serra in Cubatao-SP and at Paula Souza in Sao Paulo city. The accelerated tests consisted of (a) exposure to alternate cycles of ultraviolet radiation/condensation combined with salt spray cycles (UVCON combined with Salt Spray) and of (b) exposure to alternate cycles of ultraviolet radiation/condensation combined with the Prohesion test. The performance of the coatings was assessed by visual ...

Energy Technology Data Exchange (ETDEWEB)

The Mediated Electrochemical Oxidation (MEO) system is an aqueous process which treats low-level mixed wastes by oxidizing the organic components of he waste into carbon dioxide and water. As MEO system continues to run, dissolved ash and radionuclides slowly accumulate in the anolyte and must be removed to maintain process efficiency. At such time, all of the anolyte is pumped into a still feed tank, and the silver ions need to be removed before sending the solution to a thin-film evaporator for further concentration. The efficiency of removing silver ions in the solution needs to be high enough such that the residual silver sent to Final Forms would be less than 1% wt. The purpose of this work is to develop an efficient process to remove silver ions during the MEO cleanout and to demonstrate the capability of centrifugation for separating small silver chloride particles from the solution. This development work includes lab scale experiments and bench scale ...

Energy Technology Data Exchange (ETDEWEB)

Plasma nitriding was applied to improve the surface performance of titanium bipolar plate. XRD and SEM results showed a titanium nitride layer was formed after nitridation. In comparison with pure titanium, the interfacial contact resistance of plasma nitrided titanium was reduced to some extent by the nitridation treatment. However, high corrosion current was observed under electrochemical tests in 0.5 M H{sub 2}SO{sub 4} + 5 ppm HF. Both the electrical conductivity and corrosion resistance of the surface of plasma nitriding titanium did not reach the level of graphite. Some more improvements are expected in the plasma nitriding process or another surface modification on pure titanium. (author)

Energy Technology Data Exchange (ETDEWEB)

The lithium carbon batteries studied in this paper use plasticized polymer electrolytes made with passive polymer matrix swollen by a liquid electrolyte with a high ionic conductivity (> 10{sup -3} S/cm at 25 deg. C). The polymers used to prepare the gels are polyacrylonitrile (PAN) and vinylidene poly-fluoride (PVdF). The electrochemical and physical properties of these materials are analyzed according to their composition. The behaviour of solid electrolytes with different materials of lithium ion insertion (graphite and LiNiO{sub 2}) are studied and compared to liquid electrolytes. The parameters taken into account are the reversible and irreversible capacities, the cycling performance and the admissible current densities. Finally, complete lithium ion batteries with gelled electrolytes were manufactured and tested. (J.S.) 2 refs.

British Library Electronic Table of Contents (United Kingdom)

The kinetics of the electropolymerization of 3-amino-1,2,4-triazole on a brass substrate in alkaline solution containing methanol was investigated using cyclic polarization, chronoamperometry, electrochemical impedance techniques and scanning electronic microscopy. The polymeric film was prepared by successive cycles of potential of a 60Cu-Zn electrode between 0 and 1.6V. During the second cycle, the oxidation peak of the monomer disappears indicating the formation of the insulating film. We have also shown that the monomer oxidation reaction is essentially irreversible and controlled by a diffusion process. The protective effect of the film formed on brass has been studied in a 3%NaCl and 3%NaCl+S2- solution. The results showed important inhibition efficiency, about 96% for 4h of testing ...

Energy Technology Data Exchange (ETDEWEB)

The deterioration of AA2024, AA6061 and AA7475 anodised in an environmentally-compliant tartaric acid/sulphuric acid electrolyte has been examined as a function of the immersion time in the electrolyte after termination of anodising. By transmission electron microscopy and scanning electron microscopy, degradation of the porous oxide film was qualitatively observed on AA2024. Electrochemical impedance spectroscopy revealed that AA2024 and AA7075 were more sensitive to prolonged immersion in the anodising electrolyte compared with AA6061, due to increased barrier layer thinning rates and increased susceptibility to localized corrosion. Salt spray tests confirmed the previous, indicating decay of anticorrosion performance for AA2024 and AA7075.

Science.gov (United States)

The authors report here, for the first time, high frequency testing of a new type of electrochemical double layer capacitor (EDLC), based on carbon aerogels: the Aerocapacitor. Carbon aerogels, are a novel type of carbon foam developed by Lawrence Livermore National Laboratory for military applications. The unique properties of carbon aerogels, high surface area (700 m{sup 2}/g), high density (1g/cc), well controlled pore diameter and high material conductivity (25 S/cm) made it an ideal EDLC electrode material. Using carbon aerogel as the electrode material, the authors have developed Aerocapacitors. These new EDLC`s have a frequency response comparable to that of aluminum electrolytic capacitors and are thus ideally suited to power conversion applications.

International Nuclear Information System (INIS)

More than sixty base-isolated buildings have been built in Japan. A number of base-isolation systems were considered in our research, which was intended to establish the effectiveness of base-isolation systems. We conducted research on silicone rubber bearings. Generally, silicone rubber is durable and its characteristics are not dependent on the temperature within the relevant design range. The first part of the report covers material and elements testing. After the bearings were installed in the building, we performed forced vibration tests in both the horizontal and vertical directions. These test results form the next section. After several experiments, we carried out earthquake observations. We report on the effectiveness of the system in reducing response acceleration during a small displacement. This system was installed in the building in March 1992

Energy Technology Data Exchange (ETDEWEB)

A 500 keV negative-ion based NBI system is under construction for NB current drive and plasma core heating in high density plasma in JT-60U. Part of the beamline and the high voltage power supply required for a verification test of an ion source was completed in March 1995. After having done a high potential test of the power supply, the negative-ion generation and acceleration tests started in June 1995 aiming at deuterium beams of 500 keV, 22A. In initial experiment, deuterium negative-ion beams of 410 keV, 6.1A (2.5 MW) for 0.2 sec, so far, have been achieved. This is the world highest D{sup {minus}} current and negative ion beam power. The construction of the total system will be completed by the beginning of 1996, and the beam injection will start in March 1996.

International Nuclear Information System (INIS)

... NUCLEAR FUEL CYCLE AND FUEL MATERIALS borophosphate glass

Energy Technology Data Exchange (ETDEWEB)

The main physical processes allowing negative ion production by surface sputtering for further acceleration in tandem acceleration are briefly reviewed. The sputtering yield and the probability of negative ion ejection are discussed. The properties of negative ion beams for an efficient acceleration in tandem accelerators are also discussed, with an emphasis on space charge problems. The main features and performances of the heavy negative ion injector of the Bucharest tandem accelerator are given.

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides advanced battery R&D; technology transfer to industry; technical analyses, assessments, modeling, and databases; and independent testing and post-test analyses of advanced batteries. These capabilities and services are being offered to the US Advanced Battery Consortium (USABC) and Cooperative Research and Development Agreements (CRADA) are being negotiated for USABC-sponsored work at ANL. A small portion of DOE`s cost share for USABC projects has been provided to ANL to continue R&D and testing activities on key technologies that were previously supported directly by DOE. This report summarizes progress on these USABC projects during the period of April I through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into ...

CERN Document Server

The LHC magnet tests operation team developed various innovative techniques, particularly since early 2004, to complete the superconductor magnet tests by Feb. 2007. Overall and cryogenic priority handling, rapid on-bench thermal cycling, rule-based goodness evaluation on round-the-clock basis, multiple, mashed web systems are some of these techniques applied with rigour for successful tests completion in time. This paper highlights these operation empowerment tools which had a pivotal role for success. A priority handling method was put in place to enable maximum throughput from twelve test benches, having many different constraints. For the cryogenics infrastructure, it implied judicious allocation of limited resources to the benches. Rapid On-Bench Thermal Cycle was a key strategy to accelerate magnets tests throughput, saving time and simplifying logistics. ...

Energy Technology Data Exchange (ETDEWEB)

For evaporation crystallization of extremely corrosive FGD scrubber solutions which - depending on the process - can lead all the way to a product suitable for depositing, an economic equipment concept based on metallic construction materials was to be investigated. In a parameter study, electrochemical test methods were used to determine the influence of the pH value, the Fe{sup 3+}, F and So{sub 2} contents in a solution containing 200 g/l CaCl{sub 2}+30 g/l NaCl at 80deg C on the resistance to pitting corrosion of stainless steels and NiCrMo alloys. In addition, electrochemical and wet corrosion tests (e.g. crevice corrosion) were conducted using original FGD scrubber solutions with 43-50% dry substance from the power plants Reuter-West, Oberhavel and Rudow of the BEWAG, Berlin. The results were compared to those of standardized and non-standardized short-term tests for ...

International Nuclear Information System (INIS)

A series of Model Tests of Embedment Effect on Reactor Buildings has been carried out by the Nuclear Power Engineering Corporation (NUPEC), under the sponsorship of the Ministry of International Trade and Industry (MITI) of Japan. Seismic response of an embedded reactor building is greatly affected by the non-linearity of the backfill soil. However, quite few experimental data have been obtained so far. The objective of this study is to qualitatively evaluate the non-linear behavior of the backfill soil through shaking table tests. Its effects to the seismic response of a reactor building constructed at a soft rock site can be made clear through the tests. Non-linear effects of the backfill soil on the seismic response of the embedded reactor building model were evaluated experimentally. Based on the sinusoidal and seismic wave excitation tests, the following conclusions were obtained regarding the ...

International Nuclear Information System (INIS)

We propose to investigate the spontaneous emission of radiation arising out of the interaction of a relativistic electron beam with a metallic grating (the Smith-Purcell effect). The work will concentrate, primarily, in the 50-120 #mu#m part of the infrared spectrum and will be an extension of the work begun by the Oxford-Dartmouth-Essex collaboration; one of the early objectives of the project will be to develop a quantitative understanding of the power spectrum of the emitted radiation over a wide range of emission angles. In particular, the limits of relativistic peaking of forward directed emission will be investigated. The electron beam will be produced by laser irradiation of a metallic cathode in the terminal of a small Van de Graff accelerator located in the Technische Universitaet, Muenchen. Beam energies will be in the range of 2 - 4 MeV. Initial tests on photoproduction of electrons have yielded 10 mA pulses with a width of about 20 ...

International Nuclear Information System (INIS)

In support of Stockpile Stewardship activities, accelerated aging tests on a plutonium alloy enriched with 7.3 at.% of "2"3"8Pu is underway using dilatometry at 35, 50, and 65 deg. C and immersion density measurements of materials stored at 50 deg. C. Changes in density are expected from radiation damage in the lattice and helium in-growth. After 25 equivalent years of aging, the dilatometry data shows that the alloys at 35 deg. C have expanded in volume by 0.11-0.12% and have started to exhibit a near linear expansion behavior primarily caused by the helium accumulation. The average He-to-vacancy ratio from tested specimens was determined to be around 2.55. The model for the lattice damage and helium in-growth accurately represents the volume swelling at 35 deg. C. The density converted from the dilatometry corresponds well to the decreasing density trend of reference plutonium alloys as a function of time.

Energy Technology Data Exchange (ETDEWEB)

A CRC cooperative program was conducted to determine the difference in octane requirements between technical raters and 'customers' (the general driving public). The tests were conducted in two phases, with the second being a repeat of the first to verify the results obtained. The trained raters used the CRC E-15 procedure to determine the octane requirement of the vehicles while the customers' perception and objection to knock were determined through the use of a questionnaire. The customers' responses (perception and objection level) were based upon audible knock, acceleration performance, and after-run on a series of full-boiling-range customer/rater unleaded (FBRCU) reference-fuels. Data were analyzed from 168 1988-1991 model-year vehicles, with 126 of these tested in Phase II. The results showed that the customers, objections and perceptions were overwhelmingly based on knock, rather ...

Energy Technology Data Exchange (ETDEWEB)

Thomas Jefferson National Accelerator Facility experiment E01-012 measured the 3He spin structure functions and virtual photon asymmetries in the resonance region in the momentum transfer range 1.0 < Q2 < 4.0 (GeV/c)2. Our date, when compared with existing deep inelastic scattering data, can be used to test quark-hadron duality in g1 and A1 for 3He and the neutron. Preliminary results for A{sub 1}{sup {sup 3}He} are presented, as well as some details about the experiment.

Science.gov (United States)

Self-magnetically insulated, high-voltage transmission lines are used in inertial confinement fusion particle accelerators in order to transmit power from the vacuum insulator to the diode. This paper describes a time-dependent 2-D code (MITL) for calculating (for planar or triplate geometries) the motion of test electrons through the tapered input or output convolutes of such lines. MITL results show that the electron canonical momentum in the direction of the flow changes as the electron passes through the convoluted geometry; it is suggested that these electrons lead to losses observed in long self-magnetically insulated lines.

Energy Technology Data Exchange (ETDEWEB)

This paper summarizes the investigation of horizontal direction drilling and the subsequent experimental installation of a natural gas network in a suburb of Paris, France. Three aspects of drilling were studied prior to implementation: (1) reliability of the technique and quality of pipelaying to ensure long-term supply main operation; (2) ability to assess the successfulness of the work by assessing preliminary conditions; and (3) economonic viability. Measurement of tensile stress on polyethylene pipe during pulling and comparative accelerated aging tests on scratched pipe were performed. In the implementation phase, 300 meters of pipe were laid daily, by using three machines simultaneously, at a cost comparable to that of conventional techniques.

Energy Technology Data Exchange (ETDEWEB)

This work demonstrate the gasoline volatility influence, at T 10%, T 50% and T 90% distillation points, on the dynamic performance of Otto cycle engines equipped with fuel sequential electronic injection system, by using test standard procedures in dynamometer. For each distillation points three value ranges were established, giving the rise of 27 different gasoline mixtures. The effects of variation in each point on consumption, power and acceleration were verified.

Energy Technology Data Exchange (ETDEWEB)

An apparatus was designed and built for the purpose of exposing samples of solid polymers to varying temperatures, atmospheres and stress levels while quantitatively recording the resulting chemiluminescence. Preliminary data were acquired with this apparatus that show a correlation between an enhanced chemiluminescence signal at a low level of applied stress and a decrease in tensile strength for the most commonly used epoxy resin in high performance fiber composites, TGMDA DDS. The studies with cellular silicone cushions (which are used to accommodate thermal expansion and contraction) have defined the temperature regimes in which accelerated aging tests are valid for extrapolation to ambient temperature. Preliminary data on Kevlar fibers is also discussed.

International Nuclear Information System (INIS)

Power extraction using a dielectric-loaded (DL) waveguide is a way to generate high-power radio frequency (RF) waves for future particle accelerators, especially for two-beam-acceleration. In a two-beam-acceleration scheme, a low-energy, high-current particle beam is passed through a deceleration section of waveguide (decelerator), where the power from the beam is partially transferred to trailing electromagnetic waves (wakefields); then with a properly designed RF output coupler, the power generated in the decelerator is extracted to an output waveguide, where finally the power can be transmitted and used to accelerate another usually high-energy low-current beam. The decelerator, together with the RF output coupler, is called a power extractor. At Argonne Wakefield Accelerator (AWA), we designed a 7.8GHz power extractor with a circular DL waveguide and tested ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

CERN Document Server

Modified gravity theories may provide an alternative to dark energy to explain cosmic acceleration. We argue that the observational program developed to test dark energy needs to be augmented to capture new tests of gravity on astrophysical scales. Several distinct signatures of gravity theories exist outside the linear regime, especially owing to the screening mechanism that operates inside halos like the Milky Way to ensure that gravity tests in the solar system are satisfied. This opens up several decades in length scale and new classes of galaxies at low-redshift that can be exploited by surveys. While theoretical work on models of gravity is in the early stages, we can already identify new regimes which cosmological surveys could target to test gravity. These include: 1. A small scale component that focuses on the interior and vicinity of galaxy and cluster halos. 2. ...

Energy Technology Data Exchange (ETDEWEB)

Commonly used EV battery tests are not very suitable for testing hybrid vehicle batteries, which may be primarily intended to supply vehicle acceleration power. The capacity of hybrid vehicle batteries will be relatively small, they will typically operate over a restricted range of states-of-charge, and they may seldom if ever be fully recharged. Further, hybrid propulsion system designs will commonly impose a higher regeneration content than is typical for electric vehicles. New test methods have been developed for use in characterizing battery performance and life for hybrid vehicle use. The procedures described in this paper were developed from the requirements of the government-industry cooperative Partnership for A New Generation of Vehicles (PNGV) program; however, they are expected to have broad application to the testing of energy storage devices for hybrid vehicles. The ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R&D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of July 1, 1992 through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into ...

Energy Technology Data Exchange (ETDEWEB)

Weight loss measurements were performed in 20% and 28% hydrochloric acid at 90/sup 0/C on carbon steel, 22Cr5Ni duplex stainless steel, and two superaustenitic steels - 27Cr31Ni3Mo and 19Cr25Ni4Mo -, in presence of organic substances used singly or mixed. The organic substances examined were quaternary ammonium salts (1-4-pyridyl)-pyridinium chloride hydrochloride, dodecylpyridiniumchloride, benzyldimethylstearylammonium chloride, and dodecyltrimethylammonium bromide), alkynols (1-octyn-3-ol, propargyl alcohol) and trans-cinnamaldehyde. The synergistic effect of potassium iodide on the inhibitive efficiency of the organic substances was studied. The variations of corrosion rate during the test time (normally six hours) were recorded by means of polarization resistance measurements. Polarization curves were also recorded. The results showed that the corrosion rates of the four steels examined can be reduced to less than 1 mg/cm/sup -2/ . h/sup -1/ using ternary ...

Energy Technology Data Exchange (ETDEWEB)

This paper reports on a series of laboratory and controlled test site measurements of the thermal conductivity of polyisocyanurate foam laminated boardstock roof insulations produced with several different blowing agents; CFC-11, HCFC-123, HCFC-14lb, and two blends of the HCFCs. The behavior of the experimental foams with HCFCs is compared to that of conventional polyisocyanurate foam blown with CFC-11. Thermal drift observed from two years of field exposure is compared to laboratory accelerated aging tests and the laboratory and field measurement techniques are described. This work is part of a Joint Industry/Government Project established in the United States to evaluate the technical viability of HCFC alternative blowing agents for polyisocyanurate foam roof insulations.

CERN Document Server

Prospective presentation is given for the experimental program of the KLOE-2 Collaboration, to be performed using the DA$\\Phi$NE $e^+e^-$ collider upgraded in luminosity. Data with the total luminosity of 25 fb$^{-1}$ are aimed to be collected in 3 years. Major modifications of the accelerator and the spectrometer are described. The KLOE-2 physics program contains: CKM unitarity and lepton universality tests, $\\gamma\\gamma$ physics, search for quantum decoherence and testing CPT conservation, low-energy QCD, rare kaon decays, physics of $\\eta$ and $\\eta^\\prime$, structure of low-mass scalars, contribution of vacuum polarization to $(g-2)_{\\mu}$, possible search for WIMP dark matter. In this paper only selected physics subjects are reported.

Energy Technology Data Exchange (ETDEWEB)

Under 10CFR50 Appendix B, utilities have a commitment to establish and maintain material control programs to assure the safety and reliability of their power plants. The guidelines in this report discuss methods of establishing, maintaining, and extending the shelf life of limited life items. In addition, these guidelines establish justifiable shelf lives for a sample of 70 items and review the effects of environmental conditions. Moreover, the guidelines are consistent with utility qualification test documentation and provide for evaluation of items with expired shelf lives. These guidelines set precedent by indicating that the shelf life is greater than previously available for many items. This increase in shelf life has been established through natural and accelerated aging tests.

International Nuclear Information System (INIS)

The critical part of the trimetallic transition joint (type 304 stainless steel/Alloy 800/2.25 Cr-1 Mo steel), the Alloy 800/2.25 Cr-1 Mo steel joint welded with Inconel 182, was subjected to thermal cycling between room temperature and 873 K. The thermal cycling test procedure used produces accelerated failures in transition joints similar to those observed in steam generators of operating power plants. On thermal cycling, precipitation at the weld/ferritic steel interface decreased on post-weld heat treatment. This precipitation increased with increased prior ageing and applied stress. The results of these tests indicated a considerable improvement in performance of the trimetallic transition joint compared to the direct (bimetallic) transition joint. (orig.).

CERN Document Server

A non-resonant RF cavity loaded with amorphous alloy cores has been designed and tested. The cavity has a re-entrant structure loaded with 8 amorphous alloy toroidal core and its characteristic impedance is designed as 450 Omega . The RF power is fed by 1 kW solid state amplifier using a step-up transformer with 1:9 impedance ratio. In the high power test, an accelerating gap voltage of more than 900 V was measured with input power of 1 kW in the frequency range of 1 to 10 MHz. The voltage standing wave ratio (VSWR) was less than 2.0. The results prove that the cavity may be used successfully within a compact proton synchrotron for a cancer therapy facility. (3 refs).

Energy Technology Data Exchange (ETDEWEB)

Two austenitic steels, 316 Stainless Steel and Alloy 800, have been examined under conditions of both isothermal low cycle fatigue (LCF) and thermomechanical fatigue (TMF). The TMF tests were conducted between 649 and 360/sup 0/C with a carefully controlled triangular waveform. The LCF tests were performed at 649/sup 0/C and both kinds of tests were subjected to a strain range of 0.5%. TMF shortened life to 40% for 316 Stainless Steel and to 5% for Alloy 800. The microstructural evolution occurring in both alloys has been examined and we conclude these do not play a role in the life shortening caused by TMF. The TMF does produce asymmetric hysteresis loops with large tensile peak stresses in tests where the maximum temperature corresponded with the peak compressive stress. The influence of TMF on fatigue crack growth rates has been measured and it was found that TMF accelerated ...

DEFF Research Database (Denmark)

The notes describe in detail primary and secondary galvanic cells, fuel cells, electrochemical synthesis and electroplating processes, corrosion: measurments, inhibitors, cathodic and anodic protection, details of metal dissolution reactions, Pourbaix diagrams and purification of waste water from galvanic industries.

Energy Technology Data Exchange (ETDEWEB)

Cathodic arc deposition is an established and industrially applied technique for the formation of nitrides (e.g. TiN); it can also be used for metal oxide thin film formation. A cathodic arc plasma source with the desired cathode material is operated in an oxygen atmosphere of appropriate pressure, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on accelerator components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}-Y{sub ...

Energy Technology Data Exchange (ETDEWEB)

Alloy 690 and Alloy600 are used as a material for the steam generator tubing in the pressurized water reactor(PWR) of nuclear power plants due to its high corrosion resistance. Although those are a highly corrosion resistance material, their stress corrosion cracking(SCC) have been found on occasion, which are deeply related to a surface oxide film on a base material which have occurred on the primary side as well as the secondary side of a tubing. And The SCC is accelerated in the existing Pb which is the impurity of secondary steam generator components. The Oxide on a steel surface in an aqueous solution above 100 .deg. C is composed of a duplex film structure. The inner layer of the oxide is dense and less porous, which is formed by a growth of the oxide layer on the metal surface. The outer layer of the oxide is less adhesive, which is formed by a dissolution and precipitation mechanism. Growth processes of the inner layer and the outer layer occur at the ...

Energy Technology Data Exchange (ETDEWEB)

Pellet injectors are needed to fuel long pulse tokamak plasmas and other magnetic confinement devices. For this purpose, an apparatus has been developed that forms 1.3-mm-diam pellets of frozen deuterium at a rate of 40 pellets per second and accelerates them to a speed of 1 km/s. Pellets are formed by extruding a billet of solidified deuterium through a 1.3-mm-diam nozzle at a speed of 5 cm/s. The extruding deuterium is chopped with a razor knife, forming 1.3-mm right circular cylinders of solid deuterium. The pellets are accelerated by synchronously injecting them into a high speed rotating arbor containing a guide track, which carries them from a point near the center of rotation to the periphery. The pellets leave the wheel after 150/sup 0/ of rotation at double the tip speed. The centrifuge is formed in the shape of a centrifugal catenary and is constructed of high strength KEVLAR/epoxy composite. This arbon has been ...

Energy Technology Data Exchange (ETDEWEB)

The personal neutron dosimetry becomes more important with the increasing use of nuclear and accelerator facilities. The solid state track detector, film badge and thermo-luminescent dosimeter have widely been used as passive-type personal neutron dosimeters, but the real-time neutron dosimeter is strongly needed. A real time personal dosimeter which could give neutron dose equivalent over wide energy range from thermal to 10 odd MeV by using two neutron sensors has been developed by our group. For practical commercial product, some changes from these prototype sensors have recently been done by Fuji Electric Co. Ltd. The purpose of this work is the final performance test of the dosimeter just before sale. We checked again about the sensitivity in the monoenergetic neutron field from 8 keV to 15 MeV and in the neutron fields around a few accelerator facilities. (author)

Energy Technology Data Exchange (ETDEWEB)

In cooling systems, an improved control of scale deposit and corrosion processes is a major challenge and an realistic evaluation tool for water treatments is of the utmost economic importance. In this study, a channel flow cell was used to allow in-situ electrochemical measurements in well defined electrolyte tube flowing conditions. An expression of the mass transfer towards the electrode was established where the diffusion-limited current is a function of Re{sup 1/3} in the laminar regime and was verified experimentally using the redox couples Fe[CN]{sub 6}{sup 4-}/ Fe[CN]{sub 6}{sup 3-} and O{sub 2}/OH{sup -}. This hydrodynamically controlled experimental device was developed to investigate scale deposit processes and to evaluate scale inhibitor efficiency using a electrochemical quartz crystal microbalance. Experiments were performed on three different waters, at various flow rates and temperatures. The efficiency of a well known ...

Energy Technology Data Exchange (ETDEWEB)

The fine scale mechanical probing capability of NI-AFM was used to examine hydrogen interaction with plasticity. To realize this, an electrochemical three electrode setup was incorporated into the NI-AFM. The developed ECNI-AFM is capable of performing nanoindentation as well as imaging surfaces inside electrolytes. The developed ECNI-AFM setup was used to examine the effect of cathodically charged hydrogen on dislocation nucleation in pure metals and alloys. It was shown that hydrogen reduces the pop-in load in all of the tested materials except Cu. The reduced pop-in load can be interpreted as the HELP mechanism. Classical dislocation theory was used to model the homogeneous dislocation nucleation and it was shown that H reduces the activation energy for dislocation nucleation in H sensitive metals which are not undergoing a phase transformation. The activation energy for dislocation nucleation is related to the material specific parameters; ...

Energy Technology Data Exchange (ETDEWEB)

The possibilities to electrodeposit thick coatings composed of nanoparticles of Sb and Sb{sub 2}O{sub 3} for use as high-capacity anode materials in Li-ion batteries have been investigated. It is demonstrated that the stability of the coatings depends on their Sb{sub 2}O{sub 3} concentrations as well as microstructure. The electrodeposition reactions in electrolytes with different pH and buffer capacities were studied using chronopotentiometry and electrochemical quartz crystal microbalance measurements. The obtained deposits, which were characterised with XRD and SEM, were also tested as anode materials in Li-ion batteries. The influence of the pH and buffer capacity of the deposition solution on the composition and particle size of the deposits were studied and it is concluded that depositions from a poorly buffered solution of antimony-tartrate give rise to good anode materials due to the inclusion of precipitated Sb{sub 2}O{sub 3} ...

Science.gov (United States)

... Accession Number : ADA079641. Title : Relation of the One-Phase Stefan Problem to the Seepage of Liquids and Electrochemical Machining,. ...

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This paper describes an investigation of electrodeposited Zn-14% Ni and aluminium-based SermeTel 1140/962 coatings as possible replacements for cadmium. Slow strain rate tests were performed to measure the extent of direct hydrogen embrittlement of a high strength steel substrate as a result of the coating process and of hydrogen re-embrittlement caused by coating corrosion. The level of re-embrittlement was shown to depend on both the electrochemical potential of the coating and its barrier properties. Zn-14% Ni coatings caused the most re-embrittlement as they had the most active potential and contained through-thickness defects which left the steel exposed to hydrogen uptake. The microstructure of the high strength steel was also shown to be an important factor affecting the extent of embrittlement. AerMet 100 steel was more resistant than 300M steel and this was attributed to the presence of reverted austenite surrounding the martensite ...

Energy Technology Data Exchange (ETDEWEB)

Nitridation of Cr-bearing alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant CrN or Cr{sub 2}N base surfaces of interest for a range of electrochemical devices, including fuel cells, batteries, and sensors. This paper presents results of exploratory studies of the nitridation of commercially available, high Cr (30-35 wt%) Ni-Cr alloys and a ferritic high Cr (29 wt%) stainless steel for proton exchange membrane fuel cell (PEMFC) bipolar plates. A high degree of corrosion resistance in sulfuric acid solutions designed to simulate bipolar plate conditions and low ICR values were achieved. Oxygen impurities in the nitriding environment were observed to play a significant role in the nitrided surface structures that formed, with detrimental effects for the Ni-Cr base alloys, but beneficial effects for the stainless steel alloy. Positive results from single-cell fuel cell testing are also ...

International Nuclear Information System (INIS)

A nitric acid solution containing Cr_2O_7"2"- ion is used for a corrosion test which simulates the condition in a nuclear fuel reprocessing plant. As the effect of Cr content on the corrosion resistance of stainless steel is not yet fully understood in that solution, the effects of Cr content in an alloy and that of Cr_2O_7"2"- ion in nitric acid on the corrosion rate were studied by using electro-chemical measurements. The increase of Cr content reduced the general corrosion rate in nitric acid solution without Cr_2O_7"2"- ion, however it increased that in nitric acid solution containing Cr_2O_7"2"- ion. It is considered that the reversal of the Cr content dependency is due to a rise of the corrosion potential caused by addition of Cr_2O_7"2"- ion to the potential region where a high Cr alloy shows higher anodic dissolution rate than a low Cr content alloy. (author).

Energy Technology Data Exchange (ETDEWEB)

Monitoring brine chemistry to determine the extent of potential adverse reactions was simplified by the development of a field brine test kit and a series of nomographs. Results of the kit analyses serve as input to the nomographs, which provide a graphic means of determining the scaling tendency (Saturation Index value) of a brine. Brines that do not tend to form scale may be corrosive. Saturation Index values have been correlated with various processes using data from geopressured wells in the Gulf Coast area. Control of scale in surface equipment of geopressured wells by chemical inhibitors has been successful. Downhole treatment with inhibitors to prevent scale formation in the production tubing is being investigated. Laboratory simulations indicate that an inhibitor squeeze treatment may be successful at the Gladys McCall No. 1 well. Inhibitor mixtures exhibit additive behavior at minimum concentration levels; however, behavior at maximum concentration may ...

Energy Technology Data Exchange (ETDEWEB)

Acrylonitrile electropolymerization (in an aprotic and anhydrous medium) has been used as a way to build thin, homogeneous and covering polyacrylonitrile layers grafted on the surface of usual metals and specially on copper-based shape memory alloy: Cu-Zn-Al. The results of the study first confirm the possibility of grafting thin and covering polyacrylonitrile layers on Cu-Zn-Al surface. The morphology of the films however is influenced by the geometry of the polycristalline structure of the alloy and its superficial defects. Samples obtained after grafting polyacrylonitrile films were submitted to corrosion tests based on Electrochemical Impedance Spectroscopy (EIS) measurements in a NaCl/H{sub 2}O medium. Results show that some post-treatments of the grafted films are necessary to improve their protective role, while preserving the strong interfacial bondings. Actually, thermal and mechanical cycling of the shape memory alloy covered by ...

Energy Technology Data Exchange (ETDEWEB)

Deposition of hard coatings may influence the mechanical properties of the bulk material and its corrosion resistance. In this work we study the hardness of the coated and the back side of 100Cr6 steel plates. Electrochemical corrosion tests were performed in O{sub 2}-saturated acetate buffer of pH 5.6 at 25degC. Chromium nitride and titanium nitride coatings prepared by different physical vapour deposition processes, such as arc, thermionic arc evaporation, magnetron sputtering and ion-beam-assisted deposition (IBAD) were compared. The results show that, for sufficient corrosion protection, chromium nitride layers have to be thicker than 500 nm. An increased nitrogen partial pressure in the evaporation chamber of the IBAD process improves the corrosion resistance significantly. The hardness of the substrates was reduced in the case of thermoionic arc evaporation only, indicating a deposition temperature of more than 250degC. For this process, ...

Energy Technology Data Exchange (ETDEWEB)

Without stable hardware any program will fail. The frustration and expense of supporting bad hardware can drain an organization, delay progress, and frustrate everyone involved. At Stanford Linear Accelerator Center (SLAC), we have created a testing method that helps our group, SLAC Computer Services (SCS), weed out potentially bad hardware and purchase the best hardware at the best possible cost. Commodity hardware changes often, so new evaluations happen periodically each time we purchase systems and minor re-evaluations happen for revised systems for our clusters, about twice a year. This general framework helps SCS perform correct, efficient evaluations. This article outlines SCS's computer testing methods and our system acceptance criteria. We expanded the basic ideas to other evaluations such as storage, and we think the methods outlined in this article has helped us choose hardware that is much more stable ...

Energy Technology Data Exchange (ETDEWEB)

ATLAS is one of the four experiments which will take place at the LHC, the CERN future protons collider. This accelerator, which should start in 2007, will allow to continue the studies carried out by its predecessors, as the standard model Higgs boson and new physics searches. The very high luminosity -10 fb{sup -1} during the first three functioning years, then 100 fb{sup -1}- and the 14 TeV in the frame center will ease these studies. The Centre de Physique des Particules de Marseille took part in the ATLAS collaboration, taking in charge half of the End-cap electromagnetic calorimeter modules construction. The description of this sub-detector and the construction steps, in particular the electrical tests which allow the stacking validation, are presented in this document. These tests results, obtained for the live first production modules, are analysed. The pre-series module (module 0) performances, obtained with beam ...

Energy Technology Data Exchange (ETDEWEB)

Contamination of the lube-oil with hard abrasive particles leads to a three-body abrasive wear mechanism that highly accelerates piston ring/cylinder liner wear in coal-fueled diesel engines. One approach to reducing that wear is to modify the size and orientation of surface asperities on the cylinder to enhance the formation of a hydrodynamic film, and to provide avenues of escape for particles that would otherwise be trapped in the wear zone. Another approach is to introduce additives into the contaminated lube-oil that further enhance hydrodynamic film formation, form chemical films on the wearing surfaces, or form films on the contaminant particles. This work focuses on defining the effects of cylinder liner surface finish, various configurations of slots in the cylinder liner surface, and various additives in the contaminated lube-oil on the wear process. Wear tests were initiated in a bench apparatus using coal-ash contaminated lube-oil ...

Energy Technology Data Exchange (ETDEWEB)

Vacuum insulation panels (VIP) offer excellent thermal resistance properties that can enhance the energy efficiency of insulating systems, save space and contribute to energy consumption reductions. However, VIPs are not used much in Canada, and new commitments to carbon dioxide reductions has created the need to study the prospect of using VIPs in various components of a building envelope. For that reason, assessment methods for the applicability and sustainability of VIPs for use in building envelope construction were developed. There are practical aspects regarding the long-term performance and application of VIPs in building construction. Air molecules and water molecules can permeate through the foil and seams of the VIPs, causing a reduction in thermal resistance. This paper addresses some of the test methods that may accelerate long term changes in thermal resistance. Results were presented from tests using elevated ...

Energy Technology Data Exchange (ETDEWEB)

During the previous 9 months the major part of the Fusion-FEM has been constructed. The 2 MV Insulated Core Transformer, the electron gun, the accelerator, the focusing lenses and the undulator have been tested on-site. In the present - temporary - set-up, the electron beam line consists of a 12 A, 80 keV thermionic electron gun, a 2 MeV dc accelerator, beam transport optics, the undulator and a collector. The gun is mounted in the high voltage terminal, which is now at -2 MV, and the undulator and mm-wave system am at ground potential outside the SF{sub 6}-filled pressure tank. This so-called inverse set-up allows easy access to the larger part of the beam line, the undulator and the mm-wave system, which is important in the conditioning phase. The decelerator and depressed collector am not yet installed. The design of the electron beam line has been optimised using the GPS particle-tracking code and the TOSCA code. The ...

Energy Technology Data Exchange (ETDEWEB)

Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the Hanford Site call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank`s structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the actual NCRW and NCAW both chemically and physically. The tests ...

International Nuclear Information System (INIS)

The Anisotropic Analytical Algorithm (AAA) is a new pencil beam convolution/superposition algorithm proposed by Varian for photon dose calculations. The configuration of AAA depends on linear accelerator design and specifications. The purpose of this study was to investigate the accuracy of AAA for an Elekta SL25 linear accelerator for small fields and intensity modulated radiation therapy (IMRT) treatments in inhomogeneous media. The accuracy of AAA was evaluated in two studies. First, AAA was compared both with Monte Carlo (MC) and the measurements in an inhomogeneous phantom simulating lung equivalent tissues and bone ribs. The algorithm was tested under lateral electronic disequilibrium conditions, using small fields (2x2 cm"2). Good agreement was generally achieved for depth dose and profiles, with deviations generally below 3% in lung inhomogeneities and below 5% at interfaces. However, the effects of attenuation and ...

CERN Document Server

The diffuse morphology and transient nature of coronal mass ejections (CMEs) make them difficult to identify and track using traditional image processing techniques. We apply multiscale methods to enhance the visibility of the faint CME front. This enables an ellipse characterisation to objectively study the changing morphology and kinematics of a sample of events imaged by the Large Angle Spectrometric Coronagraph (LASCO) onboard the Solar and Heliospheric Observatory (SOHO) and the Sun Earth Connection Coronal and Heliospheric Investigation (SECCHI) onboard the Solar Terrestrial Relations Observatory (STEREO). The accuracy of these methods allows us to test the CMEs for non-constant acceleration and expansion. We exploit the multiscale nature of CMEs to extract structure with a multiscale decomposition, akin to a Canny edge detector. Spatio-temporal filtering highlights the CME front as it propagates in time. We apply an ellipse ...

Energy Technology Data Exchange (ETDEWEB)

This journal contains the following articles (1) The Grand Challenge of Thermonuclear Ignition--Commentary by Edward I. Moses; (2) Orchestrating the World's Most Powerful Laser--The computer control system for the National Ignition Facility will soon have about 1.4-million lines of code running on more than 750 computers; (3) A Randon Walk through Time and Space--Albert einstein's 1905 papers on Brownian motion, random fluctuations, and statistical mechanics are fundamental to many Livermore research projects; (4) The Search for Methane in Earth's Mantle--Scientists are discovering that Earth's mantle may have untapped reserves of methane; and (5) Testing the Physics of Nuclear Isomers--Results from a tri-laboratory project contradict claims of accelerated release of energy from the nuclear isomer hafnium-178.

Energy Technology Data Exchange (ETDEWEB)

It has been recently suggested by Arkani-Hamed, Dimopoulos and Dvali that gravity may become strong at energies not far above the electroweak scale and thus remove the hierarchy problem. Such a scenario can be tested at both present and future accelerators since towers of Kaluza-Klein gravitons and associated scalar fields now play an important phenomenological role. In this paper we examine several processes for their sensitivity to a low scale for quantum gravity including deep inelastic ep scattering at DESY HERA, high precision low energy {nu}N scattering, Bhabha and Mo/ller scattering at linear colliders and both fermion and gluon pair production at {gamma}{gamma} colliders. {copyright} {ital 1999} {ital The American Physical Society}

International Nuclear Information System (INIS)

It has been recently suggested by Arkani-Hamed, Dimopoulos and Dvali that gravity may become strong at energies not far above the electroweak scale and thus remove the hierarchy problem. Such a scenario can be tested at both present and future accelerators since towers of Kaluza-Klein gravitons and associated scalar fields now play an important phenomenological role. In this paper we examine several processes for their sensitivity to a low scale for quantum gravity including deep inelastic ep scattering at HERA, high precision low energy #nu#N scattering, Bhabha and Moller scattering at linear colliders and fermion pair production at #gamma##gamma# colliders

International Nuclear Information System (INIS)

The effect of helium on the mechanical properties and fracture behaviors of a type 316 austenitic steel is presented. Helium implantation was performed by 30-MeV #alpha#-particle injection on very small, thin specimens, using a cyclotron accelerator. Average helium content in the He-deposited region was 50 to 2000 appm He. These specimens showed the transition of fracture mode from transgranular to intergranular fracture in elevated temperature tests. The transition temperature decreased with increase in the amount of implanted helium. For example, in the case of 2000 appm and 500 appm He implantation, the transition temperatures were between 773 and 873 K and 873 and 973 K, respectively. (orig.).

International Nuclear Information System (INIS)

The radiation induced reactions in LDPE in the presence of phenolic type antioxidants have been studied. It was shown that various antioxidants can influence the polyethylene network formation and the radical yield in different ways. The dependence of network structure on absorbed doses was determined by gel analysis, hot-set test and extraction of antioxidants for samples irradiated with accelerated electrons. It was found that the antioxidants eluted from polyethylene in higher percentage influence polymer crosslinking to a smaller degree. The ESR studies of #gamma#-irradiated blends of polyethylene with antioxidant indicate the presence of alkyl and phenoxyl radicals. The role of antioxidant molecules on radiation induced reactions in polyethylene-antioxidant systems is considered. The correlation between the network structure and the type of additive in polyethylene is also discussed. (author).

Energy Technology Data Exchange (ETDEWEB)

Accurate prediction of tube surface temperature is important for determining whether accelerated superheater corrosion will occur in kraft recovery boilers. A heat transfer model, which combines an iterative numerical solution scheme with a more realistic flue gas flow field obtained from the CFD code FLUENT, has been developed to predict the tube, steam and flue gas temperatures in the superheater region. Results of tests performed for a recovery boiler show that temperatures predicted using the model are in good agreement with actual temperatures measured using thermocouples. The presence of a large flue gas recirculation zone above the bullnose is shown to have an adverse effect on the heat transfer in the superheater region. 9 refs., 12 figs., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

Incomplete convergence in numerical simulation such as computational physics simulations and/or Monte Carlo simulations can enter into the calculation of the objective function in an optimization problem, producing noise, bias, and topo- graphical inaccuracy in the objective function. These affect accuracy and convergence rate in the optimization problem. This paper is concerned with global searching of a diverse parameter space, graduating to accelerated local convergence to a (hopefully) global optimum, in a framework that acknowledges convergence uncertainty and manages model resolu- tion to efficiently reduce uncertainty in the final optimum. In its own right, the global-to-local optimization engine employed here (devised for noise tolerance) performs better than other classical and contemporary optimization approaches tried individually and in combination on the "industrial" test problem to be presented.

Energy Technology Data Exchange (ETDEWEB)

Coilguns have the ability to provide magnetic pressure to projectiles which results in near constant acceleration. However, to achieve this performance and control projectile hearing, significant constraints are placed on the design of the coils. We are developing coils to produce an effective projectile base pressure of 100 MPa (1kbar) as a step toward reaching base pressures of 200 MPa. The design uses a scalable technology applicable to the entire range of breech to muzzle coils of a multi-stage launcher. This paper presents the design of capacitor-driven coils for launching nominal 50 mm, 350 gram projectiles. Design criteria, constraints, mechanical stress analysis, launcher performance, and test results are discussed.

CERN Document Server

The Arnowitt-Deser-Misner canonical formulation of general relativity is extended to the covariant brane-world theory in arbitrary dimensions. The exclusive probing of the extra dimensions makes a substantial difference, allowing for the construction of a non-constrained canonical theory. The quantum states of the brane-world geometry are defined by the Tomonaga-Schwinger equation, whose integrability conditions are determined by the classical perturbations of submanifolds contained in the Nash's differentiable embedding theorem. In principle, quantum brane-world theory can be tested by current experiments in astrophysics and by near future laboratory experiments at Tev energy. The implications to the black-hole information loss problem, to the accelerating cosmology, and to a quantum mathematical theory of four-sub manifolds are briefly commented.

Energy Technology Data Exchange (ETDEWEB)

Accelerator concepts for heavy-ion fusion require small emittance, high-current beams. Such applications could include funnels in which high-current, like-charged particle beams are interlaced to double beam current while retaining small emittances. The first experimental demonstration confirming the beam dynamics of the funnel principle was recently completed at Los Alamos National Laboratory. A single-leg prototype 5-MeV, H{sup {minus}} funnel was successfully tested. This single-beam demonstration explored physics issues of a two-beam funnel. It contained elements for emittance control, position control, and rf deflection, as well as diagnostics for measurement of beam intensity, position and angle centroids, energy and phase centroids, and transverse and longitudinal phase-space distributions. Results of the experiment will be presented along with comparisons to simulations. 7 refs., 5 figs.

Energy Technology Data Exchange (ETDEWEB)

Buried ridge stripe lasers have been grown on InP in two steps by gas source molecular beam epitaxy. The active structure consists of a compressively strained layer multi quantum well with an equivalent wavelength emission at 1.5 [mu]m. The stripe was defined by reactive ion etching. A threshold current of 22 mA was reproducibly obtained on a laser length of 500 [mu]m. A CW output power of 48 mW per facet was achieved. In addition, preliminary accelerated aging tests have shown the high reliability the structure. (orig.)

UK PubMed Central (United Kingdom)

Based on the assumption that an accelerated proliferation process prevails in tumour cell residues after surgery, the possibility that treatment acceleration would offer a therapeutic advantage in postoperative...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Ion acceleration has now been demonstrated with the IFA-2 collective ion accelerator system. The IFA-2 system is described, photoionization experiments are summarized, and ion results are presented. Using a 1 MeV electron beam and a 30 cm acceleration length, IFA-2 has produced 5 MeV H/sup +/, 10 MeV D/sup +/, and 20 MeV He/sup + +/. This means that accelerating fields of 33 MV/m over 30 cm have been achieved with a controlled collective accelerator for the first time.

CERN Document Server

Background information on the high energy physics program and the proposed Stanford linear electron accelerator project

International Nuclear Information System (INIS)

... electron guns linear accelerators magnetrons multivibrators pulse generators

International Nuclear Information System (INIS)

Flow Accelerated Corrosion (FAC) of Carbon Steel (CS) piping has been one of main issues in Light-Water Nuclear Reactor (LWRs). Wall thinning of CS piping due to FAC increases potential risk of pipe rupture and cost for inspection and replacement of damaged pipes. In particular, corrosion products generated by FAC of CS piping brought steam generator (SG) tube corrosion and degradation of thermal performance, when it intruded and accumulated in secondary side of PWR. To preserve SG integrity by suppressing the corrosion of CS, High-AVT chemistry (Feedwater pH9.8#+-#0.2) has been adopted to Tsuruga-2 (1160 MWe PWR, commercial operation in 1987) in July 2005 instead of conventional Low-AVT chemistry (Feedwater pH 9.3). By the High-AVT adoption, the accumulation rate of iron in SG was reduced to one-quarter of that under conventional Low-AVT. As a result, a tendency to degradation of the SG thermal efficiency was improved. On the other hand, it was clarified that ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to determine the thermal reliability of stearic acid, palmitic acid, myristic acid and lauric acid as latent heat energy storage materials with respect to various numbers of thermal cycles. The fatty acids, as phase change materials (PCMs), of industrial grade (purity between 90% and 97%) were subjected to accelerated thermal cycle tests. The differential scanning calorimetry (DSC) analysis technique was applied to the PCMs after 0, 120, 560, 850 and 1200 melt/freeze cycles in order to measure the melting temperatures and the latent heats of fusion of the PCMs. The DSC results indicated that the change in melting temperature for the PCMs was in the range of 0.07-7.87 {sup o}C, and the change in latent heat of fusion was -1.0% to -27.7%, except for stearic acid between 560 and 1200 melt/freeze cycles. However, the decrease in the latent heats of fusion for all the PCMs was not regular with increasing thermal cycles. ...

Energy Technology Data Exchange (ETDEWEB)

Superconducting rf cavities are increasingly used in accelerators. Gradient is a parameter of particular importance for the ILC. Much progress in gradient has been made over the past decade, overcoming problems of multipacting, field emission, and breakdown triggered by surface impurities. However, the quenching limit of the surface magnetic field for niobium remains a hard limitation on cavity fields sustainable with this technology. Further exploration of materials and preparation may offer a path to surpassing the current limit. For this purpose, we have designed a resonant test cavity. One wall of the cavity is formed by a flat sample of superconducting material; the rest of the cavity is copper or niobium. The H field on the sample wall is 75% higher than on any other surface. Multipacting is avoided by use of a mode with no surface electric field. The cavity will be resonated through a coupling iris with high-power rf at superconducting ...

International Nuclear Information System (INIS)

We have already developed three conventional and one periodic permanent (PPM) type 50-MW class klystrons, a smart modulator, and the first HOM-free accelerator structure (Choke-mode type, full-scale high power model). A very stable ceramic high voltage monitor was successfully tested up to 367-kV with a 4.5-#mu#sec pulse. A new C-band SiC type high power rf-load, advancing the power handling capability up to 50-MW is now being designed. It should have excellent mass production characteristics as it uses circularly symmetric TM_0_1_1 chained cavities. The first high power prototype of an rf compressor cavity made of a low thermal expansion material (super Invar) was designed to provide stable operation even with a very high Q of 200-k, it was successfully tested the output rf power up to 135-MW, 0.5-#mu#sec pulse width and 50-pps repetition rate. The C-band linac rf-system will be used for the SASE-FEL (SCSS) production ...

Energy Technology Data Exchange (ETDEWEB)

In order to improve the long term reliability of lead-salt diode lasers, ohmic contacts of multilayer, thin-film structures consisting of In plus Au, Pt, Ni, and Pd have been studied. Diode lasers of PbSnTe fabricated with a variety of contacts were tested during room-temperature storage and during accelerated aging tests. The results show that contact reliablility can be improved when multiple overlapping films are used. After 4500 h of baking at 60 /sup 0/C, lasers with In-Au-Pd-Au contacts on both sides showed the least resistance increase (10%). For lasers with In-Au-Pt-Au contacts, 1 h of baking at 60 /sup 0/C is equivalent to 2 d storage at room temperature. Extrapolating these results, a 70% increase in contact resistance is expected for this type of laser after 9000 d of storage at room temperture. Our data also suggests that a smaller increase in contact resistance can be expected for lasers fabricated with ...

International Nuclear Information System (INIS)

It is one of the most important subjects to estimate the flow-related stability of the heat exchanger tubes. A large scale model steam generator has been developed to verify the stability of the tubes in the Japanese PWR steam generators for the two-phase flow-induced vibration and to accumulate related technical data of thermal-hydraulic and flow-induced vibration of U-bend tube bundle. The model steam generator has 230 U-bend tubes of 46 different radius and 5 columns for each of practical diameter and material, and the anti vibration bars are inserted into each spacing between tube arrays. The freon R123 has been used as the secondary side fluid in stead of water-steam two-phase. In the test, void fraction and interfacial velocities in U-bend and straight tube-bundle are measured with bi-optical probes, and vibration responses of some selected tubes are measured with strain gauges and accelerators. It is verified that the U-bend tubes are ...

Energy Technology Data Exchange (ETDEWEB)

The effect of alloying Sn, Pb, As, Sb and P on the dezincification of commercial brass 60Cu-39Zn-1Pb has been investigated in 1% CuCl{sub 2} solution by immersion studies and electrochemical measurements. Specimens with a smooth surface finish exhibited more resistance to dezincification. Appreciable inhibitive effect on dezincification was observed for the 55Cu-40Zn-3Pb-2Sn brass composition. The galvanic coupling of lead phase with the matrix accelerated corrosion. To improve the dezincification resistance of the Sn containing brass, As, Sb and P were added at two different levels (0.05% and 0.1%). Brass of composition 48.95Cu-45Zn-5Pb-1Sn-0.05As was more resistant indicating the synergistic effect of Sn and As. The effect of 0.05 and 0.1% of arsenic addition with various concentrations of zinc was also studied. The alloy of composition 57.90Cu-40Zn-2Pb-0.1As showed better corrosion resistance than the alloy containing 1% Sn and 0.05% As ...

Energy Technology Data Exchange (ETDEWEB)

In the present paper, the chemical composition of passive films formed on both phases of two types of duplex stainless steels (UNS S31803 and UNS S32304) is determined at the micro-scale using Auger electron spectroscopy (AES). Samples were either mechanically polished (down to diamond pastes) or electrochemically etched in acidic solutions. The micro-electrochemical behavior of samples was then determined in sodium chloride media by means of the electrochemical micro-cell technique (capillary diameters of 30 {mu}m). The results obtained were analyzed considering the passive film chemical composition. Quantitative relationships between electrochemical parameters and the distribution of chromium and iron in the oxide layer were found. Due to differences in mechanical properties between ferrite and austenite, a heterogeneous stress distribution is generated in both phases. A method based on ...

Energy Technology Data Exchange (ETDEWEB)

Magnetic separation of several classes of antibiotics was investigated using electrochemical magnetic seeding. Electrocoagulation with a sacrificial anode followed by addition of magnetite particles was applied for the magnetic seeding of antibiotics. With electrochemical magnetic seeding using an iron anode, tetracycline antibiotics (oxytetracycline, chlortetracycline, doxycycline and tetracycline) and cephalosporin antibiotic (cefdinir) were rapidly removed from synthetic wastewater by magnetic separation using a neodymium magnet. Iron and aluminium anodes were suitable for magnetic seeding of the antibiotics. The results indicated that the ability of antibiotics to form strong complex with iron and aluminium allowed the higher removal by magnetic separation. This method would be appropriate for rapid treatment of antibiotics in wastewater.

Energy Technology Data Exchange (ETDEWEB)

'Objective of this project is to develop and use Electrochemical Emission Spectroscopy (EES) and other electrochemical techniques as in situ tools for exploring corrosion mechanisms of iron and carbon steel in highly alkaline solutions and for continuously monitoring corrosion on structural materials in DOE liquid waste storage system. In particular, the author will explore the fundamental aspects of the passive behavior of pure iron since breakdown of passivity leads to localized corrosion. This report summarizes work after 1 year of a 3 year project.'

CERN Document Server

A last look at the green field, in the triangular wedge of land stray radiation near the CERN accelerators.

KoreaScience (Korea)

Full Text Available

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Future insertion quadrupoles with large apertures and high gradients will be required for the Phase II luminosity upgrade (10{sup 35} cm{sup -2}s{sup -1}) of the Large Hadron Collider (LHC). Although improved designs, based on NbTi, are being considered as an intermediate step for the Phase I upgrade, the Nb{sub 3}Sn conductor is presently the best option that meets the ultimate performance goals for both operating field and temperature margin. As part of the development of Nb{sub 3}Sn magnet technology, the LHC Accelerator Research Program (LARP) developed and tested several 1-meter long, 90-mm aperture Nb{sub 3}Sn quadrupoles. The first two series of magnet used OST MJR 54/61 (TQ01 series) and OST RRP 54/61 (TQ02 series) strands. The third series (TQ03) used OST RRP 108/127 conductor. The larger number of sub-elements and the consequent reduction of the effective filament size, together with an increased fraction of copper and a lower Jc were ...

Energy Technology Data Exchange (ETDEWEB)

The Neutral Beam Test Facility (NBTF) to be realized in Padoa will test the Neutral Beam Injection (NBI), one of the Heating and Current Drive Systems foreseen for ITER. The NBI is based on the acceleration of hydrogen or deuterium negative ions up to 1 MeV. This work has been aimed at assessing the tritium release from the NBTF in order to provide data for the safety analysis. In particular, the diffusion of the tritium through the neutral beam target material (the CuCrZr alloy calorimeter panels) has been assessed by using literature data of the diffusion coefficient. The tritium generated inside the calorimeter panels moves into both the vacuum and water side: the tritium diffusion flux has been evaluated during the beam-on (200 deg. C) and the beam-off (20 deg. C) phases of the NBTF experiments consisting of an interim campaign and a final test. The penetration depth of the tritium through the 2 mm ...

Energy Technology Data Exchange (ETDEWEB)

We prepared cathodes with various types of activated carbon and measured the cathodes' electrochemical performance according to the kind of activated carbon. Activated carbon supplies airflow channels and reaction sites in the cathode of zinc air batteries. When we use activated carbon with a high specific surface area as the cathode's catalyst substrate, we expect high electrochemical performance because this type of carbon provides more air flow channels and reaction sites. We focused on investigating the relationship between the cathode's pore structure and its electrochemical characterizations. We also studied the effects of the various activated carbon materials on the zinc air batteries' performance. Increasing the macropores or mesopores in the activated carbon resulted in achieving more power from the battery. (author)

International Nuclear Information System (INIS)

The electrochemical/spectroscopic integrated measurement system was designed and set up for spectro-electrochemical measurements of lanthanide and actinide ions in high temperature molten salt media. A compact electrochemical cell and electrode system was also developed for the minimization of reactants, and consequently minimization of radioactive waste generation. By applying these equipment, oxidation and reduction behavior of lanthanide and actinide ions in molten salt media have been made. Also, thermodynamic parameter values are determined by interpreting the results obtained from electrochemical measurements. Several lanthanide ions exhibited fluorescence properties in molten salt. Also, UV-VIS measurement provided the detailed information regarding the oxidation states of lanthanide and actinide ions in high temperature molten salt media

Energy Technology Data Exchange (ETDEWEB)

The electrochemical metal dissolution of 100Cr6 steel in sodium chloride solution, applying high electrolyte flow rates and high current densities, has been studied with a view to the influence of material heterogeneities such as carbide segregation lines in the steel matrix. It was shown that the presence of such segregations is responsible for the formation of troughs on the specimen surface during electrochemical dissolution. A mechanism for trough formation was proposed. A dedicated heat treatment applied to the 100Cr6 steel eliminated the carbide segregation lines and established a soft annealed, fine-grained microstructure containing globular carbides. Subsequent electrochemical dissolution did not show any development of surface irregularities as troughs. (orig.)

British Library Electronic Table of Contents (United Kingdom)

The electrochemical behavior of Sb(III) ions was investigated in LiCl-KCl molten salt at 673K. The reaction mechanism and transport parameters of electroactive species were determined by transient electrochemical techniques (such as cyclic voltammetry, square wave voltammetry, chronopotentiometry and chronoamperometry) at a molybdenum electrode. The results showed that electrochemical reduction of Sb(III) in LiCl-KCl melts occurred in a reaction step with an exchange of three electrons. A voltammogram with a different scan rate in LiCl-KCl containing 1.45x10^-^4molcm^-^3 SbCl3 showed that the deposition/dissolution reaction of Sb(III) ions was not completely reversible. The diffusion coefficient of Sb(III) ions was 1.65(+/-0.01)x10^-^5cm^-^2s^-^1 at 673K. The electroreduction of Sb(III) io...

UK PubMed Central (United Kingdom)

SummaryA microreactor for electrochemical synthesis has been designed and fabricated. It has been shown that different reactions can be carried out successfully using simple protocols.

Energy Technology Data Exchange (ETDEWEB)

The stress corrosion cracking (SCC) susceptibility of 13% Cr martensitic (UNS S42000) and supermartensitic (UNS S41125) steels in sodium chloride solutions in the presence of thiosulphate was evaluated by slow strain rate tests (SSRT). The tests were performed in 5% sodium chloride solutions buffered at pH 2.7, 3.5, 4.5 and 6.0 in the absence and presence of thiosulphate in a concentration range between 10{sup -6} and 10{sup -3} M, at 25 {+-} 0.1 C. The electrochemical behaviour of the two steels in the different solutions was determined by recording the anodic and cathodic polarisation curves. 13% Cr martensitic steel showed SCC in 5% sodium chloride solutions with pH {<=} 4.5 in the presence of 3 x 10{sup -6} thiosulphate. Decreasing the chloride ion concentration from 50 to 10 g/l, the critical concentration of thiosulphate to provoke SCC susceptibility increased from 3 x 10{sup -6} to 1 x 10{sup -5} M. The ...

International Nuclear Information System (INIS)

The thermo-chemical treatments of steels with plasma is normally carried out in low-pressure ionized gaseous atmospheres. Among the treatments used most often are: nitruration, carburization and boronized. A plasma can also generate at atmospheric pressure. One way to produce it is with an electrochemical cell that works at a relatively high inter-electrode voltage and under conditions of heavy gas generation. This type of plasma is known as electrolytic plasma. This work studies the feasibility of using electrolytic plasma for the surface processing of steels. Two processes were selected: boronized and nitruration., for the hardening of two types of steel: one with low carbon (1020) and one with low alloy (4140). In the case of the nitruration, the 1020 steel was first aluminized. The electrolytes were aqueous solutions of borax for the boronizing and urea for the nitruration. The electrolytic plasmas were classified qualitatively, in relation with their ...

International Nuclear Information System (INIS)

The current status of research and development in the realm of physics and technology of collective ion acceleration in systems with a virtual cathode (VC) is reviewed. Three major acceleration methods and devices developed on their basis are considered: reflex triodes and their modifications, gas-filled vircators, and vacuum vircators with a Luce diode. Experimental data are outlined and the principal physical models interpreting these data are described. New ion acceleration techniques whose realization involves the production and disappearance of the VC are also discussed. All methods of collective ion acceleration are compared and the possible ways for the further development of this promising scientific field are highlighted. (reviews of topical problems)

Energy Technology Data Exchange (ETDEWEB)

Large scale experiments were performed to determine the effectiveness of thermal glow plug igniters to burn hydrogen in a condensing steam environment due to the presence of water sprays. The experiments were designed to determine if a detonation or accelerated flame could occur in a hydrogen-air-steam mixture which was initially nonflammable due to steam dilution but was rendered flammable by rapid steam condensation due to water sprays. Eleven Hydrogen Igniter Tests were conducted in the test vessel. The vessel was instrumented with pressure transducers, thermocouple rakes, gas grab sample bottles, hydrogen microsensors, and cameras. The vessel contained two prototypic engineered systems: (1) a deliberate hydrogen ignition system and (2) a water spray system. Experiments were conducted under conditions scaled to be nearly prototypic of those expected in Advanced Light Water Reactors (such as the Combustion Engineering ...

Energy Technology Data Exchange (ETDEWEB)

This paper presents results of a laboratory and field study of naphthenic acid corrosion and the development of an effective chemical inhibitor for this type of corrosive attack. In the laboratory corrosion test, which involved 20 hour weight loss measurements in high flash solvent with a total acid number (TAN) of 16 mg KOH/gm at a temperature of 600 F (316 C), blank corrosion rates averaged 140 to 150 mpy (3.56 to 3.81 mm/y). Inhibited rates averaged about 10 to 12 mpy (0.254 to 0.305 mm/y). The field test was carried out on a heavy vacuum gas oil (HVGO) stream at 550 F (288 C) . Blanks varied from a high of 425 mpy (10.79 mm/y) for a 24 hour test to a low of about 100 mpy (2.54 mm/y) for a 150 hour test. Both electrical resistance (ER) probes and weight loss coupons showed corrosion rates below 5 mpy (0.127 mm/y) as long as they were adequately passivated. Passivation consisted of exposing the ...

Energy Technology Data Exchange (ETDEWEB)

This program is concerned with the development of an advanced method for the separation of hydrogen sulfides from coal gas. The process utilizes an electrochemical membrane which removes hydrogen sulfide without cooling the gas and with negligible pressure loss through the separator.

Energy Technology Data Exchange (ETDEWEB)

Electrochemical cyclic potentiodynamic polarization (CPP) experiments were performed on several candidate high-performance waste package container materials to evaluate their susceptibility to localized corrosion in aqueous environments relevant to the potential underground high-level nuclear waste repository. This paper presents the results of this study showing the effects of chloride ion (Cl) concentrations, pH, temperature, and electrochemical potential scan rate on the pitting corrosion behavior of these materials.

Energy Technology Data Exchange (ETDEWEB)

In this report, we outline the progress achieved in two distinct under the DOE-sponsored cross section project: the initial results obtained from the pulsed 14 MeV neutron facility, and a cooperative effort with Argonne National Laboratory in the measurement of fast neutron cross sections in yttrium. In the 14 MeV neutron laboratory, this year has seen the maturation of the project into one in which initial scattering measurements are now underway. We have improved the accelerator and ion source in several significant ways, so that neutron intensities have now been proven to be adequate for our series of elastic scattering angular distribution measurements outlined in our initial proposal of two years ago. We have successfully tested all components of the time-of-flight spectrometer and recorded initial neutron spectra from the ring targets that we have obtained for our first angular distribution measurements. Examples of the time-of-flight ...

International Nuclear Information System (INIS)

Consensus reached in the last few years that fourth generation light source will most likely be a X-ray or a UV coherent source based on single-pass high-gain free electron laser (FEL), such as Self Amplified Spontaneous Emission (SASE), or seeded high-gain harmonic-generation (HGHG) free electron lasers. High-gain (>10"7) required for single-pass FEL puts great constrain on the quality of electron beam, and demands detailed distribution information of electron beam in six-dimension. The typical accelerator system for single-pass FEL consists of a photocathode RF gun injection system, a linac and magnetic bunch compressors, and a long undulator. The major challenges in beam diagnostics for single-pass FEL are to characterize the pico-seconds high-brightness electron beam in six-dimension produced by photocathode RF gun injector, and improve the stability and reliability of the photocathode RF gun injection system. Characterization of short electron bunch ...