Energy Technology Data Exchange (ETDEWEB)

The paper presents a procedure for the calculation of an absorption-refrigeration plant that uses an LiBr/ZnBr{sub 2}/CH{sub 3}OH solution and is driven throughout the year by heat received from a solar pond. The calculations for the solar pond are based on a finite-difference solution of the transient heat conduction differential equation during the year, and the operation of the refrigeration unit is simulated by the use of functions describing the thermodynamic behaviour of the working medium. On the basis of the procedure devised, correlations and nomographs are developed that describe the seasonally optimum operation of the proposed composite system. The nomographs may be employed for a first estimation in the design of such systems. (Author).

International Nuclear Information System (INIS)

Several refrigerators for liquid helium and liquid nitrogen systems have been integrated successfully into IGC manufactured whole body Magnetic Resonance Imaging (MRI) magnet systems. The refrigerators have been tested in systems with magnetic fields of 0.6T to 1.5T. Tests were performed to study the effectiveness of the refrigerators, the magnetic field effects on the refrigerators, the effect of the refrigerators on the field uniformity and magnetic resonance image quality. The interface between the refrigerator and the whole body MRI magnet system cryostat was specifically designed to allow retrofit to the existing IGC magnet systems, while ensuring good heat transfer characteristics and good vibration isolation from the cryostat. The interface between the ...

Energy Technology Data Exchange (ETDEWEB)

A compact and energy independent solar-powered refrigeration unit was to be developed to store and transport small quantities of high-quality commodities needing refrigeration. This unit comprises the following matched components: thermo-electrical refrigerator unit, solar generator and transport equipment. The solar generator is a specially developed panel with 36 cells. This unit may best be used in human medicine, veterinary medicine, environmental protection analysis, laboratories and leisure time activities. (BWI)

International Nuclear Information System (INIS)

Thermoacoustics deals with the conversion of heat energy into sound energy and vice versa. It is a new and emerging technology which has a strong potential towards the development of sustainable and renewable energy systems by utilizing waste heat or solar energy. Although simple to fabricate, the designing of thermoacoustic devices is very challenging. In the present study, a comprehensive design and optimization algorithm is developed for designing thermoacoustic devices. The unique feature of the present algorithm is its ability to design thermoacoustically-driven thermoacoustic refrigerators that can serve as sustainable refrigeration systems. In addition, new features based on the energy balance are also included to design individual thermoacoustic engines and acoustically-driven thermoacoustic refrigerators. As a case study, a thermoacoustically-driven thermoacoustic ...

Energy Technology Data Exchange (ETDEWEB)

Ejector refrigeration systems are usually designed to utilize low grade energy for driving the cycle. They also have low maintenance cost because they operate without a compressor. Mainly, the ejector performance directly affects the refrigerating performance. Therefore, an investigation on the characteristics and an efficient design of the ejector are important to improve ejector refrigeration systems. In this study, the computational fluid dynamics (CFD) code, FLUENT, is employed to predict the flow phenomena and performance of CPM and CMA steam ejectors. The ejector refrigeration system, using water as the working fluid, is operated at 120-140 C boiler temperature and 5-15 C evaporator temperature. CFD can predict ejector performance very well and reveal the effect of operating conditions on an effective area that is directly related to ...

Energy Technology Data Exchange (ETDEWEB)

The following manual chapters are outlined and described: overview, boilers, juice evaporators, feed mills, refrigeration, additional energy savings potentials, emerging technologies, optimization of integrated plant energy systems, and economics. (MHR)

Energy Technology Data Exchange (ETDEWEB)

This original volume of the Appliances Atlas includes discussion of residential appliances, commercial refrigeration and cooking, and office equipment. (The residential appliances section has since been updated in the E Source 1994 Residential Appliances Technology Atlas.) The commercial refrigeration section contains details on efficiency opportunities through load reduction and mechanical system improvements, while commercial cooking covers improvements to electric and gas fryers, griddles, ovens, cooktops, broilers, and steam equipment. The office equipment section offers discussion of trends and energy use of computers and their components, imaging technologies, and communication equipment. (Published under the former name, Competitek.)

Energy Technology Data Exchange (ETDEWEB)

The build-up of frost on unit cooler surfaces, if not periodically cleared, will eventually cause impairment of the unit's performance, eventually rendering it useless. Thus it is necessary, in spaces below freezing, to provide an external supply of heat to warm the unit sufficiently to melt the frost and remove it. In large central-plant-type systems the most common method employed for supplying heat is from the high-pressure side of the refrigeration system, referred to as hot gas defrost. Although the heat thus captured for use in melting frost would otherwise be rejected external to the system, the defrosting process is not free of cost. There are significant losses associated with the process the magnitude of which have not heretofore been fully identified. This paper looks at the heat and mass transfer and fluid flow mechanisms involved in the hot gas defrost process in large commercial ...

International Nuclear Information System (INIS)

We theoretically investigate the features of two-photon absorption in a coherently driven four-level atomic system with closed-loop configuration. It is found that two-photon absorption can be completely suppressed just by properly adjusting the relative phase of four coherent low-intensity driving fields and the atomic system becomes transparent against two-photon absorption. From a physical point of view, we explicitly explain these results in terms of quantum interference induced by two different two-photon excitation channels.

Energy Technology Data Exchange (ETDEWEB)

A cooling system was developed which could be used even in such areas where the maximum and minimum temperatures of a day might differ widely. The system features in that a latent heat storage unit is connected to the natural circulation cooling unit consisting of 2 heat exchangers where condensed gas (refrigerant) which performs gas-liquid change has been sealed, enabling to cool objects night and day without the requirement for any power source. Electronic equipment was installed in an insulated shelter. Lauric acid and refrigerant R-22 were used as the latent heat storage medium and the heat transport medium respectively. Natural convection heat transfer performance of the outside surfaces of the condenser and the evaporator and the transient behavior of the system during the melting and solidification periods of the latent heat storage medium were tested. As a result of a 48 ...

International Nuclear Information System (INIS)

The authors have performed a preliminary design for a persistent GHz NMR magnet at 23.5 T and 1.8 K operating conditions. In this paper the authors shall address the issues of realistic conductor selection, the coil design, the magnetic and mechanical analysis of the coil, and the required field uniformity. In addition, they shall describe the GHz magnet cryostat with a practical 1.8 K J-T refrigerator system. Finally vibration isolation system and field shield design and its associated field harmonics will be analyzed.

Energy Technology Data Exchange (ETDEWEB)

One of the important aspects in an absorption system is the effectiveness in which the gas and liquid phases come into contact with each other. An effective absorption process will provide sufficient contacting area for the gas and liquid phases to interact upon. With this in mind, work was conducted to evaluate carbon dioxide (CO{sub 2}) absorption into aqueous solutions of monoethanolamine (MEA) using two different types of contacting devices: gas absorption membrane (GAM) modules and traditional packed columns. The performance of these two absorption devices was compared to one another using the overall mass transfer coefficient (K{sub G}a{sub v}) as a basis. The GAM module contained microporous polypropylene hollow fibre membranes and the packed absorption column contained Sulzer DX structured packing. The results indicate that GAM ...

Energy Technology Data Exchange (ETDEWEB)

The application of differential optical absorption (DOA) techniques for the in-situ determination of the chemical composition of coal gasification process streams is investigated. Absorption spectra of relevant molecular species and the temperature and pressure effects on DOA-determined spectral characteristics of these species will be determined and cataloged. A system will be configured, assembled, and tested.

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The refrigerant two-phase flows in a distributor and a simulated plate heat exchanger with a single passage used in a compression-type refrigerator were visualized by real-time neutron radiography. For a distributor, the liquid fraction in the each tube was measured by some image processing method. On the other hand, for a plate heat exchanger, the two-dimensional distribution of void fraction was measured quantitatively by the umbra method. As a result, it was shown that the dynamic behaviors of refrigerant at the inlet of the section strongly affected on the performance, that is, a distribution performance of a distributor and a liquid distribution in a plate heat exchanger. (author)

Energy Technology Data Exchange (ETDEWEB)

Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill-withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. Five regions of the U.S.A. were studied for underground storage development and PB-KBB reviewed the literature ...

British Library Electronic Table of Contents (United Kingdom)

A mission to the surface of Venus would have high scientific value, but most electronic devices and sensors cannot operate at the 450degreeC ambient surface temperature of Venus. Power and cooling systems were analyzed for Venus surface operation. A radioisotope power and cooling system was designed to provide electrical power for a probe operating on the surface of Venus. For a mission duration of substantial length, the use of thermal mass to maintain an operable temperature range is likely impractical, and active refrigeration may be required to keep components at a temperature below ambient. Due to the high thermal convection of the high-density atmosphere, the heat rejection temperature was assumed to be at a 500degreeC radiator temperature, 50degreeC above ambient. The radioisotope S...

British Library Electronic Table of Contents (United Kingdom)

In this study, usage of a variable speed refrigeration system in latent heat thermal energy storage (LHTES) system is investigated to increase energy storage efficiency. Four different compressor speed control cases are compared to obtain a constant heat transfer fluid (HTF) temperature at the inlet of the energy storage tank. These control cases are (i) control with evaporation temperature, (ii) control with ethylene glycol temperature at the outlet section of evaporator, (iii) control with suction pressure of the compressor and (iv) on/off control. By means of the experimental analysis the best control strategy is obtained as control with Case (ii), in terms of stability of inlet temperature of heat transfer fluid, variations of energy efficiency of LHTES and coefficient of performance (...

Energy Technology Data Exchange (ETDEWEB)

This paper presents the performance analysis on a hybrid air-conditioning system according to the hybrid building energy system of the green building demonstration project in Shanghai, in which a 150 m{sup 2} solar collector is used to power two 10 kW adsorption chillers, a vapor compression heat pump is used to cool air in the evaporating end while the condensing heating at about 80{sup o}C is fully used to regenerate a liquid desiccant dehumidification system. In the hybrid system, the sensible cooling to the air is treated mainly by solar adsorption cooling and vapor compression cooling, whereas the latent heat is treated by the liquid desiccant dehumidification system with regeneration from the condensing heat of the heat pump. The results show that the performance of this system is 44.5% higher than conventional vapor compression system ...

Energy Technology Data Exchange (ETDEWEB)

Theoretical development for temperature measurements via narrow line, infrared absorption of carbon dioxide (CO{sub 2}) is presented. The proposed technique is based on rapid-scanning of two adjacent absorption line shapes. Spectroscopic considerations for sensitivity to temperature measurements are discussed. Several line pairs are evaluated, and the R(58) and R(60) transitions of the (00{sup 0}1){l_arrow}(00{sup 0}0) band are suggested for use in high temperature measurements for combustion systems.

Energy Technology Data Exchange (ETDEWEB)

As research for the chemical properties of lanthanide molecules in the dry system, electrochemical and ultraviolet-visible optical measurements on the chloride molten salt system have been conducted at Research Reactor Institute, Kyoto University. The reduction behavior of Ln(III)-Ln(0) and Ln(II) are measured on La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, and Yb by the cyclic voltammetry. The molar absorption coefficients of the f-f transition are measured by the measurement of ultraviolet-visible absorption spectra on Pr, Nd, Ho and Gd. From the comparison of the optical data between wet and dry systems, the characteristics of photon absorption are discussed in the molten salt. (H. Katsuta)

Energy Technology Data Exchange (ETDEWEB)

This manual is presented in 8 chapters plus appendices. Chapters 1 and 2 are included as background information. The economic insulation thickness is found using the following chapters: Chapter 3, cost of energy (heat and refrigeration); Chapter 4, cost of insulation, and Chapter 5, economic thickness determination. Each of these chapters contains a worksheet, which provides a step-by-step procedure for solving the problem. Nomographs are included in each section for simplifying the required calculations. For subambient temperature systems, the economic insulation thickness calculated with Chapters 3 to 5 should be compared to the thickness required to prevent condensation (sweating), as calculated with Chapter 6. Chapter 7 presents the procedure for calculating economic insulation for retrofit situations. Sample problems are included in Chapter 8.

Energy Technology Data Exchange (ETDEWEB)

Magnetic refrigeration uses the temperature- and field-dependence of the entropy of some magnetic materials to accomplish cooling. Because of the intrinsically high efficiency of the magnetization and demagnetization process and because of the potential for excellent heat transfer between solids and fluids, magnetic refrigerators promise to have higher efficiency than existing gas-cycle refrigerators. Many ground-based and space-based applications could benefit significantly from the cost savings implied by higher efficiency. Other attributes of these devices are high reliability and low volume and mass per unit cooling power. The development of these refrigerators is underway at several places around the world, including the Los Alamos National Laboratory. The progress to date has been encouraging but some problems have been clearly identified. The arguments for high efficiency and the problems that ...

International Nuclear Information System (INIS)

We have performed X-ray magnetic diffraction (XMD) experiment of ferromagnets at the Photon Factory (PF) of the High Energy Accelerator Research Organization (KEK) in Tsukuba. In this study, we have upgraded the XMD experimental system in order to apply this method to as many samples as possible. Upgrade was made for (1) the X-ray counting system and related measurement program, (2) the electromagnet, and (3) the refrigerator. The performance of the system was enhanced so that (1) the counting rate capability was improved from 104cps to 105cps, (2) the maximum magnetic field was increased from 0.85T to 2.15T, and (3) the lowest sample temperature was reduced from 15K to 5K. The new system was applied to an orbital ordering compound of YTiO3, and we obtained spin magnetic form factor for the reflection plane (010) perpendicular to the b axis. The magnetic field of 2T was needed to ...

Energy Technology Data Exchange (ETDEWEB)

Condensing two-phase channel flow occurs in many industrial applications, including heating and refrigeration systems. It can also occur in certain nuclear reactor accidents. For example, during a small-break loss-of-coolant accident in a pressurized water reactor, following the partial depletion of the primary coolant, condensation of steam on the primary side of the steam generator tubes can provide a heat sink for disposal of the decay heat generated in the reactor core. Condensing two-phase flow can also play an important role in the operation of the passive emergency cooling system in the advanced simplified boiling water reactor. Here, steady-state condensation in the presence of a noncondensable in a concurrent two-phase channel flow is analyzed using a two-fluid model. The effect of noncondensables on the combined heat transfer at the liquid-gas mixture interphase is accounted for by using the stagnant film model, ...

International Nuclear Information System (INIS)

A system for real-time neutron radiography of moving objects is described. It comprise a source adapted to generate a continuous uninterrupted series of neutron pulses. Each pulse has a predetermined peak power and duration compatible with the framing times of a real-time video imaging system. A transporter moves an object to be examined to bring sequentially position selected portions of the object in the path of the pulses. Where the object itself has moving components, pulses are sequentially incident on the object. According to any dissimilarities, the object will alter the intensity of the neutrons passing therethrough. In order to record separately the changes in the neutron intensity, for each pulse, an imager is positioned to receive the neutron beam pulses which have been altered by their passage through the object and produce images indicating intensity alterations. A refrigerated beryllium filter can be used to ...

Energy Technology Data Exchange (ETDEWEB)

A diffuse-reflectance capability for the Fourier transform infrared spectrometer at the Y-12 Plant Laboratory has been implemented. A sample cell with a 25 to 400/sup 0/C temperature-controlled sample stage and an ultrahigh-vacuum-to-atmospheric pressure gas-handling capability has been developed. Absorbance of light from the spectrometer beam, resulting from the beam being scattered from a powder sample, can be measured. This capability of detecting molecular species on and in powders is to be used to study chemisorption on actinide and rare-earth metals, alloys, and compounds. Cell design is described along with experiments demonstrating its performance in detecting moisture absorption on uranium oxide, moisture and carbon dioxide absorption on the lithium hydride/hydroxide system, and carbon dioxide absorption on potassium borohydride. 13 figures.

CERN Document Server

We describe a method of determining the system parameters in non-eclipsing interacting binaries. We find that the extent to which an observer sees the shape of the Roche-lobe of the secondary star governs the amount of distortion of the absorption line profiles. The width and degree of asymmetry of the phase-resolved absorption line profiles show a characteristic shape, which depends primarily on the binary inclination and gravity darkening exponent. We show that, in principle, by obtaining high spectral and time resolution spectra of quiescent cataclysmic variables or low mass X-ray binaries in which the mass-losing star is visible, fitting the shape of absorption line profiles will allow one to determine not only the mass function of the binary, but also the binary inclination and hence the mass of the binary components.

International Nuclear Information System (INIS)

Full text. Here we present a status report of the Schenberg antenna, which started commissioning runs in September 2006 under the full support of FAPESP. In its first commissioning runs we tested three preliminary parametric transducer systems, which did not achieve a high enough performance for placing the antenna sensitivity in the range of the calibrator capacitor. Instead of improving the calibrator, making it capable of introducing a larger input force, we decided to go to a radical upgrading operation: replacing the three transducers for a complete set of six transducers, with better sensitivity and arranged according to the truncated icosahedron configuration, plus two extra ones; starting to install the dilution refrigerator; installing wires, cables, and amplifiers for the complete set of transducer circuits; and a new suspension and vibration isolation system for the cabling and microstrip antennas. We also have ...

Energy Technology Data Exchange (ETDEWEB)

Panel cooling of buildings offers energy savings over conventional space-cooling systems. We present a procedure for calculating the performance of H[sub 2]O-LiBr absorption-panel cooling systems, in which the evaporator is the panel itself. Nomographs have been developed for this approach. Under the conditions examined, the H[sub 2]O-LiBr absorption unit operates with a theoretical performance coefficient of about 90% and with a practically constant specific cooling capacity of 2394 kJ/kg H[sub 2]O. For common values of the parameters involved, the panel cooling power varies from 25 to 175 W/m[sup 2] and the cooling water mass-flow through the panel is 40-260 g/m[sup 2]h. The thermal power needed to drive the system varies from 27 to 200 W/m[sup 2] and the associated temperatures from 70 to 100[sup o]C; thus, the system may be operated on solar energy. ...

Energy Technology Data Exchange (ETDEWEB)

Absorption and desorption rate data for the system CO/sub 2/-hot carbonate solutions are presented. The data are interpreted on the basis of a film-theory model developed following the procedure recently presented by Astarita and Savage. The agreement is very satisfactory. Values of the kinetic constant of the rate-determining step, previously known only up to a temperature of 40/sup 0/C, have been obtained up to 110/sup 0/C.

Energy Technology Data Exchange (ETDEWEB)

This report discusses: shape coexistence in {sup 184}Pt; nuclear structure of {sup 187}Ir; g-factors of excited states; OLNO-2; and refrigerator development.

Energy Technology Data Exchange (ETDEWEB)

The role of dietary calcium and phosphorus in modifying the intestinal absorption of lead and also the effect of lead ingestion on the metabolism of cholecalciferol were studied in chicks. The efficiency of absorption of /sup 203/Pb and /sup 47/Ca was increased when the animals were fed a low calcium diet and treated with cholecalciferol. The synthesis of the vitamin D-induced calcium-binding protein (CaBP) was correspondingly increased. When the chicks were depleted of vitamin D and repleted with 1,25-dihydroxycholecalciferol (1,25(OH)/sub 2/D/sub 3/) as their only source of the vitamin, the absorption of both /sup 47/Ca and /sup 203/Pb was unaffected by dietary calcium levels, and no change in CaBP levels occurred. Low dietary intake of phosphorus resulted in an increase in /sup 47/Ca and /sup 203/Pb absorption and in CaBP synthesis when the animals were treated with cholecalciferol. However, when the ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes the design, operation, and performance of an HVAC system installed as part of a project to demonstrate energy efficiency and environmental responsibility in commercial buildings. The systems installed in the 2180 m{sup 2} office building provide superior air quality and thermal comfort while requiring only half the electrical energy of conventional systems primarily because of the hydronic heating and cooling system. Gas use for the building is higher than expected because of longer operating hours and poor performance of the boiler/absorption chiller.

Energy Technology Data Exchange (ETDEWEB)

A solar energy collection and conversion system is disclosed in which a cassegrain mirror system is rotated about a diurnal axis, which axis is adjusted for seasonal variations in the incidence of the sun's rays on the earth's surface. A black body absorption cavity filled with translucent or transparent fluid material is used for direct absorption of the sun's rays. The incident solar energy is absorbed directly by the fluid medium. The fluid within the cavity may be maintained under extremely high pressures and temperatures in order to utilize this fluid as a heat storage medium. Such heat storage is facilitated by apparatus which permits a change in the volume of the reflective cavity in response to the temperature or pressure of the fluid within the cavity.

Science.gov (United States)

The visible absorption spectra of 1,4-(dihydroxy)-9,10-anthraquinone and of Co(II), Ni(II), Cu(II) and Zn(II) chelates have been studied in different organic solvents. This system provides a model for the anthracycline antibiotics and their metal chelates. The band structure of the spectrum has been determined using the second and fourth derivatives of the spectrum. The visible absorption band of the parent molecule can be assigned to a single electronic state with a reduced dipole moment in the excited state; structure in this band is ascribed to two overlapping vibrational progressions. In contrast, the dianion (hydroxy protons removed) shows a single electronic state with an increased dipole moment in the excited state; structure in this band can be assigned to a single vibrational progression. All of the metal chelates show spectra which are similar in appearance to that of the dianion although the identity of the metal ...

Energy Technology Data Exchange (ETDEWEB)

Critical properties of a fluid or fluid mixtures are important for describing fluid phase behavior, predicting physical properties, developing equations of state, and designing supercritical-fluid extraction processes, and compression and refrigeration units. The predictive capability of the Peng-Robinson-Styjek-Vera (PRSV-2) equation of state (1986) for critical properties of binary mixtures was investigated. The procedure adopted by Heidemann and Khalil (1980) and discussed by Abu-Eishah et al. (1998) was followed. An optimized value for the binary interaction parameter based on minimization of error between experimental and predicted critical temperatures was used. The standard and the average of the absolute relative deviations in critical properties are included. The predicted critical temperature and pressure for several nonpolar and polar systems agree well with experimental data and are always better than those predicted by the ...

Energy Technology Data Exchange (ETDEWEB)

The Tevatron accelerator at Fermilab incorporates long two-phase helium passages. During magnet design, the generalized flow map of Baker was used to predict homogeneous flow. Longer than expected magnet time constants led to this investigation. The importance of predicting the flow regime has been amplified with the advent of non-horizontal accelerator designs. A test setup was constructed at Fermilab to investigate two-phase helium flow regimes for conditions practical in accelerator designs. The setup consisted of a standard Tevatron satellite refrigerator, subcooling dewar, heater, 35 m long transfer line, and a specialized end box. A knife blade on the midplane of the transfer line diverted the flow from the upper and lower halves of the pipe to separate vessels in the end box. The amount of liquid above and below the plane was measured at various total mass flow rates and liquid percentages. The results show that stratified flow occurs at much higher liquid ...

Energy Technology Data Exchange (ETDEWEB)

The merits of single stage absorption heat pumps coupled to simple distillation for effluent treatment are discussed. An experimental integrated absorption heat pump effluent purification system (IAHPEPS) was built and operated with water-lithium bromide as a working mixture. This unit has been used to raise the temperature and hence, the vapour pressure of the impure water contained in one vessel, to the point where pure water vapour will distil from impure effluent solution (tap water or brine) and condense in a second vessel used to collect pure water. Pure effluent production rates of between 0.5 and 4.3 kg h{sup -1} were obtained. The actual coefficient of performance (COP{sub A}) and the heat pump effectiveness varied from 1.1 to 1.4 and 0.58 to 0.72, respectively. The results from the small scale systems indicate the likely results from industrial scale units which could be operated with low ...

British Library Electronic Table of Contents (United Kingdom)

The treatment of peat with the solutions of phosphoric, citric, and oxalic acids in concentrations of 10???4 and 10???2 mol/l at solid phase to liquid ratios of 1: 2.5 and 1: 5 increased the absorption of ammonia by 6.4???39.7%. The absorption of ammonia was higher than the concentration of doping ion-exchange groups by a factor of 5???2000. With the use of EPR and IR spectroscopy, it was found that this phenomenon was caused by the transformation of polyconjugation systems as a result of the interaction of acids with the organic matrix of peat by a macrocoordination mechanism, which also improved the technological characteristics of the resulting sorbents. The absence of the destruction of organic matter with the use of low concentrations of weak acids makes it possible to use these sorbe...

CERN Document Server

We report on the magnetic hyperthermia properties of chemically synthesized ferromagnetic 11 and 16 nm Fe(0) nanoparticles of cubic shape displaying the saturation magnetization of bulk iron. The specific absorption rate measured on 16 nm nanocubes is 1690+-160 W/g at 300 kHz and 66 mT. This corresponds to specific losses-per-cycle of 5.6 mJ/g, largely exceeding the ones reported in other systems. A way to quantify the degree of optimization of any system with respect to hyperthermia applications is proposed. Applied here, this method shows that our nanoparticles are not fully optimized, probably due to the strong influence of magnetic interactions on their magnetic response. Once protected from oxidation and further optimized, such nano-objects could constitute efficient magnetic cores for biomedical applications requiring very large heating power.

International Nuclear Information System (INIS)

A prototype for a quasi-cw, and high-average power free electron laser (FEL) driven by a 15 MeV superconducting rf linac has been developed, and constructed at Tokai, JAERI since 1989. Cryogenic and accelerating fields' performances of four JAERI superconducting accelerator modules have been realized without any serious problem in the FEL accelerator vault and experimental hall. Since modification and related maintenance of the cryogenic refrigerator system for the driver were completed in the middle of October 1995, the system has run with no trouble, and the driver has been continuously run very successfully up to now. The optical resonator system and related electron beam transport system have been modified to realize larger acceptance than the old for both of the undulator radiation and energetic electron beam in 1995 Japanese fiscal year. In the modification, an alignment and ...

International Nuclear Information System (INIS)

Development of evaluation technology of electrochemical reactions is very essential to understand chemical behavior of actinides and lanthanides in molten salt media in relation to the development of Pyrochemical process. The on-line electrochemical/spectroscopic measurement system is to produce electrochemical parameters and thermodynamic parameters of actinides and lanthanides in molten salts by using spectroscopic techniques such as UV-VIS absorption as well as electrochemical in-situ measurement techniques. The on-line electrochemical/spectroscopic measurement system can be applied to understand the chemical reactions and oxidation states of actinides and lanthanides in molten salts eventually for the Pyrochemical process

British Library Electronic Table of Contents (United Kingdom)

An optical fiber methane sensing system utilizing a super-luminescent diode (SLD) in the 1.33-mm band and a fiber Fabry-Perot tunable filter (FFP-TF) is developed. A two-step reference measuring method, which is based on differential absorption technique, is employed; a reference channel is introduced to eliminate the fluctuation of the illuminant spectrum, and the reference wavelength acquired by tuning the FFP-TF is introduced to eliminate the environmental influence. The two-step reference measuring method has improved the reliability and stability of the system. A minimum detectable methane concentration of 0.3% has been experimentally achieved.

International Nuclear Information System (INIS)

The operation and safety of both fossil-fuel and nuclear power stations depend on adequate cooling of the thermal source involved. This is usually accomplished using liquid coolants that are forced through the high temperature regions by a pumping system; this fluid then transports the thermal energy to another section of the power station. However, fluids that undergo boiling during this process create vapor that can be detrimental, and influence safe operation of other system components. The behavior of this vapor, or void, as it is generated and transported through the system is critical in predicting the operational and safety performance. This study uses two advanced penetrating radiation techniques, Real Time Neutron Radiography (RTNR), and High Speed X-Ray Tomography (HS-XCT), to examine void generation and transport behavior in a flow boiling system. The geometries studied were tube side flow ...

British Library Electronic Table of Contents (United Kingdom)

A solar-driven 10-ton LiBr/H2O single-effect absorption cooling system has been designed and installed at the School of Renewable Energy Technology (SERT), Phitsanulok, Thailand. Construction took place in 2005, after which this system became fully operational and has been supplying cooling for our main testing buildings air-conditioning. Data on the systems operation were collected during 2006 and analyzed to find the extent to which solar energy replaced conventional energy sources. Here, we present these data and show that the 72m2 evacuated tube solar collector delivered a yearly average solar fraction of 81%, while the remaining 19% of thermal energy required by the chiller was supplied by a LPG-fired backup heating unit. We also show that the economics of this cooling system are domi...

UK PubMed Central (United Kingdom)

The efficacy of tamsulosin at the cost of a relatively benign side effect profile has been attributed to receptor selectivity directed at the α_1a and α_1d adrenergic...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The complex formation of zirconium with biphenyl mono- and biscatecholyazo derivatives has been studied spectrophotometrically. The composition of the complexes, form and charge of complex-forming zirconium ions have been established. A procedure is suggested for calculation of molar absorptivities and stability constants for each of the complexes formed simultaneously in the system. Possible complex formation schemes have been studied. The data obtained were used to develop a spectrophotometric method of determining zirconium in the presence of large amounts of copper.

Energy Technology Data Exchange (ETDEWEB)

The paper reported the results of fiscal 1994 studies on solar energy in the New Sunshine Project. Relating to the technical development for the practical use of photovoltaic power systems, the development of manufacturing technologies for low-cost substrates and the development of element technology for manufacturing low-cost polycrystalline cells/modules were reported as the development of technology for thin substrate polycrystalline solar cells for practical use. As to the research on fabrication technology for thin film solar cells for practical use, reports were made on the research on low-cost fabrication technology for large-area modules and the technological development for qualitative improvement, etc. In respect to the technological development for super-high efficiency solar cells, reported were the technological development for super-high efficiency single crystalline silicon solar cells and the technological development for crystalline compound solar ...

Energy Technology Data Exchange (ETDEWEB)

Oregon State University (OSU) and the Pacific Northwest National Laboratory (PNNL) were funded by the U.S. Department of Energy to conduct research focused on resolving the key technical issues that limited the deployment of efficient and extremely compact microtechnology based heat actuated absorption heat pumps and gas absorbers. Success in demonstrating these technologies will reduce the main barriers to the deployment of a technology that can significantly reduce energy consumption in the building, automotive and industrial sectors while providing a technology that can improve our ability to sequester CO{sub 2}. The proposed research cost $939,477. $539,477 of the proposed amount funded research conducted at OSU while the balance ($400,000) was used at PNNL. The project lasted 42 months and started in April 2001. Recent developments at the Pacific Northwest National Laboratory and Oregon State University suggest that the performance of ...

British Library Electronic Table of Contents (United Kingdom)

A method for range-resolved gas sensing using path-integrated optical systems is presented. The method involves dividing an absorption path into several measurement segments and extracting the gas concentration in each segment from two path-integrated measurements. We implemented the method with tunable lasers (a 1389-nm VCSEL and a 10.9-?m pulsed quantum cascade laser) and a group of retro reflectors (RRs) distributed along absorption paths. Using a rotating mirror with the VCSEL configuration, we could scan a group of seven tape RRs spaced by 10?cm in ??9?ms to extract an H2O concentration profile. Reduced H2O concentrations were recorded in the segments purged with dry air. Hollow corner cube RRs were used in the quantum cascade laser configuration at distances up to 1.1?km from the las...

International Nuclear Information System (INIS)

The X-ray intensity ratio K_#beta#/K_#alpha# has been measured by using a 10 mCi "5"5Fe source (Mn K X-rays) and high resolution Si(Li) detector system coupled to a computer-controlled multichannel analyzer over the range of 15#<=#Z#<=#22. Correction have been made to the measured relative intensities (K_#alpha# and K_#beta# X-rays) for self-absorption in the sample, air, Be-window absorption and detection efficiency. The results are compared with those of other experiments and with the Scofield calculations. (author) 13 refs.; 3 figs.; 2 tabs.

British Library Electronic Table of Contents (United Kingdom)

The fully developed electrically conducting micropolar fluid flow and heat transfer along a semi-infinite vertical porous moving plate is studied including the effect of viscous heating and in the presence of a magnetic field applied transversely to the direction of the flow. The Darcy-Brinkman-Forchheimer model which includes the effects of boundary and inertia forces is employed. The differential equations governing the problem have been transformed by a similarity transformation into a system of non-dimensional differential equations which are solved numerically by element free Galerkin method. Profiles for velocity, microrotation and temperature are presented for a wide range of plate velocity, viscosity ratio, Darcy number, Forchhimer number, magnetic field parameter, heat absorption ...

Energy Technology Data Exchange (ETDEWEB)

Many commercial processes for the removal of carbon dioxide from high-pressure gases use aqueous potassium carbonate systems promoted by secondary amines. This paper presents thermodynamic and kinetic data for aqueous potassium carbonate promoted by piperazine. Research has been performed at typical absorber conditions for the removal of CO{sub 2} from flue gas. Piperazine, used as an additive in 20-30 wt% potassium carbonate, was investigated in a wetted-wall column using a concentration of 0.6 m at 40-80{sup o}C. The addition of 0.6 m piperazine to a 20 wt% potassium carbonate system decreases the CO{sub 2} equilibrium partial pressure by approximately 85% at intermediate CO{sub 2} loading. The distribution of piperazine species in the solution was determined by proton NMR. Using the speciation data and relevant equilibrium constants, a model was developed to predict system speciation and equilibrium. The addition of 0.6 ...

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as ``hindered`` amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE ...

Energy Technology Data Exchange (ETDEWEB)

This handbook provides the necessary tools for the engineer to design forced-cooled HPOF pipe-type cable systems. It represents the final objective of a major project which included an extensive research program at the Waltz Mill Forced-Cooling Test Facility. The formulas and procedures presented in this handbook are consistent with the results of this program as well as other full-scale and model investigations. Introductory material, including historical information, general design concepts and basic heat transfer and fluid dynamics theory is given for those who are unfamiliar with the fundamental principles of forced-cooling. The nucleus of the handbook consists of equations and calculating procedures for determining forced-cooled parameters and thermal/hydraulic performance levels. Both simple and sophisticated procedures have been provided, with the more complex procedures treating such areas as the thermal interaction between cable pipes as well as the ...

Energy Technology Data Exchange (ETDEWEB)

This report discusses: shape coexistence in {sup 184}Pt; nuclear structure of {sup 187}Ir; g-factors of excited states; OLNO-2; and refrigerator development.

Energy Technology Data Exchange (ETDEWEB)

In most countries, residential electricity consumption typically ranges from 20% to 40% of total electricity consumption. This energy is used for heating, cooling, refrigeration and other end-uses. Significant energy savings are possible if new appliance purchases are for models with higher efficiency than that of existing models. There are several ways to ensure or encourage such an outcome, for example, appliance rebates, innovative procurement, and minimum efficiency standards. This paper focuses on the latter approach. At the present time, the US is the only country with comprehensive appliance energy efficiency standards. However, many other countries, such as Australia, Canada, the European Community (EC), Japan and Korea, are considering enacting standards. The greatest potential impact of minimum efficiency standards for appliances is in the developing countries (e.g., China and India), where saturations of household appliances are relatively low but ...

International Nuclear Information System (INIS)

... biological effects body burden diet intestinal absorption lead lead 203 man

Energy Technology Data Exchange (ETDEWEB)

The gastrointestinal absorption of lead was markedly increased in human subjects who had fasted before ingesting lead. Food in the gut was found to reduce lead absorption, and the effect of dietary constituents on /sup 203/Pb absorption was investigated. The greatest reduction in absorption was caused by minerals. This dependence of lead absorption on dietary constituents complicates the establishment of safe levels of lead in food and water.

Energy Technology Data Exchange (ETDEWEB)

The electric power industry can use the carbon dioxide absorption process to capture carbon from high-volume flue gas. However, the current cost of the process is too high due to the approximation method used in process design. The absorption column is typically designed with parameters that are assumed to be constant over the whole length of the column, resulting in an oversized unit. This approximation method is no longer valid given new environmental and economic concerns. In order to develop an accurate column design for high-efficiency carbon dioxide (CO{sub 2}) capture, it is necessary to understand the phenomena taking place in the system. A mechanistic model is presented for a robust absorber design that takes into account mass-transfer and hydrodynamic behaviour within the CO{sub 2} absorption columns. The capture performance of a packed column under a wide range of design and operating ...

International Nuclear Information System (INIS)

In the microwave tokamak experiment (MTX) program, we are concentrating on experiments using intense, free-electron laser (FEL) generated microwave pulses. In initial FEL experiments, several diagnostic instruments were operated during injection of microwave pulses with peak powers to 0.2 GW at durations of 10 ns. Fixed and spatially scanning microwave detectors and receivers and a 48-element calorimeter on the inside wall of MTX diagnosed the GW-level FEL microwave pulses. With these diagnostics, linear-wave absorption and efficiencies of transmission through the quasi-optical transport system were studied. In addition, several radially resolved measurements of plasma density, temperature, and emission were made during FEL injection and were used in the analysis of microwave absorption data. A timing system, slaved to the FEL pulse arrival time, is capable of accuracy to a few nanoseconds in order to ...

Energy Technology Data Exchange (ETDEWEB)

Reinforcement of the legislation concerning the emission of atmospheric pollutants, aerosols, refrigerants, solvents etc and the reduction of the greenhouse effect, has led to the development of performing instruments for the survey and control of ambient air quality and for the limitation of exhaust gases, combustion products, volatile organic compounds (VOC), particulates and noxious compounds in the atmosphere. This study is divided in 4 main parts. The first part describes the context of the air quality control: the problems linked with the environment and health, the pollutants characteristics, the pollution levels and the detection sensitivity of instruments according to the different type of pollutants (petroleum products, VOCs, ozone compounds, particulates, smells..), the protocols of air pollution measurements and their application (chimney smokes, industrial volatile compounds, indoor and ambient air quality, exhaust gases from automobiles), and the ...

British Library Electronic Table of Contents (United Kingdom)

''Hybrid'' hydrogen storage, where hydrogen is stored in both the solid material and as a high pressure gas in the void volume of the tank can improve overall system efficiency by up to 50% compared to either compressed hydrogen or solid materials alone. Thermodynamically, high equilibrium hydrogen pressures in metal-hydrogen systems correspond to low enthalpies of hydrogen absorption-desorption. This decreases the calorimetric effects of the hydride formation-decomposition processes which can assist in achieving high rates of heat exchange during hydrogen loading-removing the bottleneck in achieving low charging times and improving overall hydrogen storage efficiency of large hydrogen stores. Two systems with hydrogenation enthalpies close to -20kJ/mol H2 were studied to investigate the h...

Energy Technology Data Exchange (ETDEWEB)

This paper describes research and development activities at the University of Regina, Saskatchewan, Canada on Optimization of CO{sub 2} Extraction Process Technologies. The ultimate goal of this research is to develop better and more effective CO{sub 2} separation processes which can be used to recover CO{sub 2} from industrial sources such as coal-fired power plants and coal gasification complexes at the lowest possible capital and operating costs. The research program has been supported by Saskatchewan Power Corporation, Saskatchewan Energy and Mines, Prairie Coal Ltd., the Canada Centre for Mineral and Energy Technology (CANMET), Fluor Daniel Inc. (USA), Sulzer Chemtech (Switzerland), Wascana Energy Inc., and Natural Sciences and Engineering Research Council of Canada (NSERC). Currently, six parallel and complementary projects have been carried out at the Process Systems Laboratory. These projects are: (1) Searching for new sterically hindered amines for high ...

Energy Technology Data Exchange (ETDEWEB)

The carbon dioxide capture potential of amine amino acid salts (AAAS), formed by mixing equinormal amounts of amino acids; e.g. glycine. B-alanine and sarcosine, with an organic base; 3-(methylamino)propylamine (MAPA), was assessed by comparison with monoethanolamine (MEA), and with amino acid salt (AAS) from amino acid neutralized with an inorganic base; potassium hydroxide (KOH). Carbon dioxide absorption and desorption experiments were carried out on the solvent systems at 40{sup o}C and 80{sup o}C respectively. Experimental results showed that amine amino acid salts have similar CO{sub 2} absorption properties to MEA of the same concentration. They also showed good signs of stability during the experiments. Amino acid salt from an inorganic base, KOH, showed lower performance in CO{sub 2} absorption than the amine amino acid salts (AAAS) mainly due to a lower equilibrium temperature sensitivity. ...

Energy Technology Data Exchange (ETDEWEB)

This report details the data, assumptions and methodology for end-use forecasting of appliance energy use in the US residential sector. Our analysis uses the modeling framework provided by the Appliance Model in the Residential End-Use Energy Planning System (REEPS), which was developed by the Electric Power Research Institute. In this modeling framework, appliances include essentially all residential end-uses other than space conditioning end-uses. We have defined a distinct appliance model for each end-use based on a common modeling framework provided in the REEPS software. This report details our development of the following appliance models: refrigerator, freezer, dryer, water heater, clothes washer, dishwasher, lighting, cooking and miscellaneous. Taken together, appliances account for approximately 70% of electricity consumption and 30% of natural gas consumption in the US residential sector. Appliances are thus important to those ...

International Nuclear Information System (INIS)

Tarapur Atomic Power Station unit-4 is first 540 MWe pressurized heavy water reactor. Heavy water is used as the coolant and moderator. With reactor operation tritium is formed by absorption of neutron by Deuterium atoms. Experience in the 220 MWe indicates that tritium is main contributor to the internal dose of radiation workers. Study on Tritium build up in Primary Heat Transport (PHT) and Moderator (MOD) system was carried out at the initial stage of the operation of the unit-3 and 4. This paper brings out tritium activity buildup in the PHT and MOD systems and its comparison with 220 MWe reactors. This paper helps in estimation of the internal dose contribution to the radiation workers at TAPS 3 and 4. (author)

Energy Technology Data Exchange (ETDEWEB)

Remote detection of chemicals using LIDAR (Light Detection and Ranging) utilizing DIAL (Differential Absorption LIDAR) is now a standard detection technique for both military and civilian activities. We have developed a novel nonlinear optical phase conjugation system that can reduce the effects of speckle noise and atmospheric turbulence on DIAL remote detection systems. We have shown numerically and experimentally that it is possible to increase the signal-to-noise (S/N) ratio for LIDAR systems under certain conditions using optical phase conjugation. This increase in S/N can result in more accurate detection of chemical effluents while simultaneously reducing the time necessary to acquire this information.

Energy Technology Data Exchange (ETDEWEB)

Microporous membranes are suitable for the CO{sub 2}-MEA (monoethanolamine) system because the overall mass transfer coefficient K of the membrane is approximately 10 times larger than that of composite membranes consisting of microporous membranes and homogeneous membranes. The overall volumetric mass transfer coefficient K{center_dot} of the hollow-fiber contact is more than 5 times larger than that of a conventional packed bed, which suggests that adorption using the present method has the advantage of making the absorption more compact. 8 refs., 7 figs., 4 tabs.

Energy Technology Data Exchange (ETDEWEB)

The design of separation devices, particularly for solvent-based selective removal of H{sub 2}S from CO{sub 2}, requires an accurate mathematical model. Unfortunately, this requirement for high accuracy is often in conflict with the need for efficient computation. The addition of more and more complicated analyses, such as a move from Henry's law to a method incorporating gas and liquid activities for computing vapor liquid equilibria, may give a more accurate solution, but only at the cost of decreased computational efficiency. The efforts in this work have been directed toward two goals. The first was to develop an accurate mathematical model for the aqueous methyldiethanolamine (MDEA) system. The steady-state packed column model developed in this work has been tested with data from Schubert (1988) to verify its accuracy. The second goal was to modify the model to improve its computational efficiency. Areas such as vapor-liquid equilibrium calculations, ...

Energy Technology Data Exchange (ETDEWEB)

Bremstrahlung Isochromat Spectroscopy (BIS). The XES spectra were collected using a Specs electron gun for the excitation and the XES 350 grating monochromator and channel plate system from Scienta as the photon detection. Spectra were collected in 'normal mode,' where the electron gun kinetic energy (KE) and the energy position of the center of the channel plate were both fixed and the energy distribution in the photon (hv) spectrum was derived from the intensities distributed across the channel plate detector in the energy dispersal direction. The polycrystalline Ce sample was oxidized by exposure to air at ambient pressures. After introduction to the ultra-high vacuum system, the oxidized sample was bombarded with Ar, to clean the topmost surface region and stabilize the surface and near surface regions. Although CeO{sub 2} would be the thermodynamically preferred composition in an oxygen rich environment, the combination ...

Science.gov (United States)

Gas phase oxidation and catalytic oxidation of element mercury (Hg(0)) to bivalent mercury (Hg(2+)) were proposed to improve the mercury removal efficiency in the wet flue gas desulfurization (WFGD) system. However, the re-emission of Hg(0), generated by the reduction of absorbed Hg(2+), would lead to a damping of the total mercury removal efficiency. In this paper, the absorption and reduction behaviors of bivalent mercury in the Ca-based WFGD slurry were evaluated in our purpose-built device. According to our experimental results, the slurry chemistry (such as CaSO(3) content, SO(4)(2-), Cl(-) and pH value) had a strong influence on the reduction of absorbed bivalent mercury. And the inlet concentrations of SO(2) and O(2) contribute little to the mercury absorption. Within the typical pH value range of 4.5-5.5, about 70% of inlet bivalent mercury was converted to Hg(0). The re-emission of Hg would be greatly retarded with ...

Energy Technology Data Exchange (ETDEWEB)

Calcium and phosphorus were mainly responsible for reducing the gastrointestinal absorption of lead in human subjects. The effect of calcium was greater than phosphorus, and their combined effect was more than additive. Increasing weights of calcium and phosphorus progressively reduced lead absorption. The relationship between absorption and increasing weights could be described by two negative exponentials. These effects could be explained if lead competed with calcium and phosphorus for common transport mechanisms in the gut. Milk was also found to reduce lead absorption. Adding milk to the diet of people with low dietary calcium intake could reduce the possibility of increased absorption of ingested lead.

Energy Technology Data Exchange (ETDEWEB)

There are two non-equivalent sites of yttrium in the lattice of Y{sub 2}SiO{sub 5}. Both of them may be occupied substitutionally by Er{sup 3+}, resulting in a laser active material. We measured absorption spectra of Y{sub 2}SiO{sub 5}:Er{sup 3+} at several low temperatures and we studied its emission spectrum at 4.2 K following selective excitation of individual Stark components of the {sup 4}I{sub 13}2/ to {sup 4}I{sub 15}2/ transition by the light of a tunable colour centre laser. The results of these two experiments allow classification of the absorption and emission lines into two independent systems, thus yielding two energy level schemes 1 and 2. Moreover, simple crystal field calculations strongly suggest from which Y{sub 2}SiO{sub 5} crystallographic site spectrum 1 arises, and from which one spectrum 2. (author)

International Nuclear Information System (INIS)

EPR and FT-IR absorption measurements have been performed for xCuO.(100-x)[2Bi2O3.B2O3] glass system, with 0?x?50 mol%. The mode in which the addition of the copper ions influences the structure of 2Bi2O3.B2O3 glass matrix was analyzed. The EPR absorption spectra revealed the presence in the glass structure of Cu2+ ions in axially distorted octahedral environments. EPR data pointed out the simultaneous presence of Cu2+ and Cu+ ionic species in the glasses with x?5 mol%. For x>10 mol%, the Cu2+ ions participate in the superexchange magnetic interactions, which increase with CuO content. The FT-IR spectra showed the presence of some bands that are assigned to vibrations of Bi-O bonds from BiO3 pyramidal and BiO6 octahedral units and B-O bonds from BO3 and BO4 units. The data obtained by these measurements reveal the structural changes in the 2Bi2O3.B2O3 glass matrix by controlled doping of CuO.

International Nuclear Information System (INIS)

Americium extraction in different oxidation states in two-phase aqueous system based on polyethylene glycol is investigated. Conditions for quantitative extraction of americium (3) and americium (5) from ammonium sulfate solutions within pH=3-5 interval in the presence of arsenazo 3 are found. Composition of the produced americium complexes with reagent is determined; americium (3) interacts with arsenazo 3 in ammonium sulfate solutions with the formation of MeR and Me_2R composition complexes. Absorption spectrum characteristics of americium (3) and- (5) complexes with arsenazo 3 in ammonium sulfate solutions and extracts based polyethylene glycol aqueous solutions are given. Molar extinction coefficients of americium complexes with arsenazo (3) in these solutions are determined.

Science.gov (United States)

For the efficient operation of a cavity ringdown spectroscopy (CRDS) system utilized with a continuous-wave (cw) laser, we numerically analyze the coupling efficiency of a cw laser to a ringdown cavity in terms of changes in the scanning rate, the laser linewidth, and the mirror reflectivity. We also demonstrate a new simple design for a CRDS system that can produce a CRDS signal with only a piezoelectric transducer (PZT), without the acousto-optic modulator that is usually adopted to switch off the cw laser beam that enters the cavity. Furthermore, we investigate the feasibility of the cw CRDS technique with a fast-scanning PZT by recording a CRDS spectrum of acetylene overtones. The detection sensitivity that corresponds to the noise-equivalent absorption is found to be approximately 3 x 10(-9)/cm. PMID:18305817

International Nuclear Information System (INIS)

A tissue-equivalent dosimetry system has been developed for use in absorbed dose determinations with physical models of Reference Man. The dosimeter used was a thermo-luminescent dosimeter (TLD) powder which was mixed with a 'tissue-equivalent' material and modeled to closely approximate an organ's geometry and absorption properties. A separation procedure was developed by which the TLD powder was washed and the 'tissue-equivalent' material, a wax, was dissolved and extracted following the irradiation of the model. The procedure was tested to determine losses of powder, homogeneity of the powder's distribution throughout the wax, the effects of the separation procedure upon the powder and the statistical behavior of the procedure. The results of these tests established the feasibility of the procedure. A full-scale model of the pancreas was tested and the results supported the validity of the technique. (author)

Energy Technology Data Exchange (ETDEWEB)

The first application of optical Stark modulation has been applied to measure spatially precise Stark-modulated IR absorption spectra in a flame.

International Nuclear Information System (INIS)

... 45 p. absorption spectroscopy errors lead lead 203 beta decay radioisotopes

Energy Technology Data Exchange (ETDEWEB)

This book brings together the 103 presentations given at the 2. conference of the international institute of refrigeration (IIF/IIR) about air conditioning in high rise office buildings. The main themes are: design of air conditioning equipment for high buildings; air quality and thermal comfort inside these buildings; constraints and possible improvements of the refrigeration equipment used; energy conservation; fire protection and smokes detection. All themes are presented both on the technical and economical points of view and concern more particularly the buildings of Chinese cities. This publication is available both on the book and CD-Rom forms. (J.S.)

CERN Document Server

We performed a spectroscopic galaxy survey, complete to $m_{F814W}\\leq20.3$ ($L_B>0.15L_B^{\\star}$ at z=0.3), within 100x100'' of the quasar Q1127-145 ($z_{em}=1.18$). The VLT/UVES quasar spectrum contains three $z_{abs}<0.33$ MgII absorption systems. We obtained eight new galaxy redshifts, adding to the four previously known, and galaxy star formation rates (SFRs) and metallicities were computed where possible. A strong MgII system [$W_r(2796)=1.8$A], which is a known damped Ly$\\alpha$ absorber (DLA), had three previously identified galaxies; we found two additional galaxies associated with this system. These five galaxies form a group with diverse properties, such as a luminosity range of $0.04\\leq L_B\\leq0.63 L_B^{\\star}$, an impact parameter range of $17\\leq D \\leq 241$ kpc and velocity dispersion of $\\sigma$=115 km/s. The DLA group galaxy redshifts span beyond the 350 km/s velocity ...

International Nuclear Information System (INIS)

Carbon-14 was analysed by direct absorption of carbon dioxide on the mixture of organic amine compound and scintillation cocktail then counted by low level liquid scintillation counter. This method can be applied for radiocarbon dating. In this study, the effects of carbon dioxide absorption, and counting efficiency were investigated using various commercial available cocktail. It was found that permafluor V and Ready Gel showed the highest carbon dioxide absorption whereas the Permafluor V showed the highest counting efficiency

KoreaScience (Korea)

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KoreaScience (Korea)

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KoreaScience (Korea)

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Wastenet

... Carbon capture and storage Waste Prevention and Recycling EU clean air strategy Environmental liability: Applying the 'polluter pays' principle What goes around ...comes around: Recycling and climate change Behind closed doors: Air quality in buildings Keeping cool with refrigerants: The F-gas review Regions fighting climate ...

Energy Technology Data Exchange (ETDEWEB)

This overview of research conducted at ORNL in 1991 presents information on the subjects of biology, physics, and the environment. Specific topics include gene mutations in kidney disease, technology assessments in thermonuclear fusion, submarine hunting technology, ozone-safe refrigerants, optical data storage via surface enhanced raman spectroscopy, and waste mitigating microbes. (GHH)

International Nuclear Information System (INIS)

The fundamental optical absorption of ion crystals characterizes the creation of different free low energetic electronic excitation (the excitons and electron-hole pairs), but their straight registration is not possible because of incommensurable big absorption factor of alkali halide monocrystals. So to registration the spectrums of alkali halide monocrystal very fine layers are necessary. We have received fine films of Nal and KCl in system of KCl-Nal-KCl, KCl-KI-KCl on the base of universal vacuum post VUP-4, VUP-5 by thermal evaporation. A unique spectral unit has been created For this on the basic the SDL-2 complex. Complex consists of radiator, systems of condensers, monochromators MDR-12 and MDR-23, receivers of radiation, controller by unit. Connect and control of monochromators by means of IBM-compatible computer has been created. Kinematics schemes of monochromators provide consequent removing ...

Energy Technology Data Exchange (ETDEWEB)

The chemistries of reactants, plasticizers, solvents and additives in an epoxy paint are discussed. Polyamide additives may play an important role in the absorption of molecular iodine by epoxy paints. It is recommended that the unsaturation of the polyamide additive in the epoxy cure be determined. Experimental studies of water absorption by epoxy resins are discussed. These studies show that absorption can disrupt hydrogen bonds among segments of the polymers and cause swelling of the polymer. The water absorption increases the diffusion coefficient of water within the polymer. Permanent damage to the polymer can result if water causes hydrolysis of ether linkages. Water desorption studies are recommended to ascertain how water absorption affects epoxy paint.

International Nuclear Information System (INIS)

Studies of the gastrointestinal absorption of lead-203 chloride were carried out on 11 normal subjects, 7 males and 4 females. Whole body counting of these subjects after administration of 74 kBq (2 #mu#Ci) of cyclotron-produced lead-203 chloride showed a mean absorption of 21.3% of the dose with a range from 10.4 to 47.7%. The male subjects had a lower mean absorption of 18.1% of the dose compared with a mean of 26.9% in the females. Although this difference did not reach statistical significance, it is postulated that male/female differences in absorption may relate to differences in iron saturation of the subjects.

International Nuclear Information System (INIS)

Water chemistry of nuclear power plants has played an important role in reduction of personnel doses, structural materials and fuel integrity assurance, and reduction of radioactive wastes production. Further contributions are requested for advanced utilization of the LWR, advanced fuels and aging management of plants. Since water chemistry has an effect on all structure and materials immersed and at the same time affected by them, the optimum control not sticking to specific issues and covering the whole plant is required for these requests. Taking account of roles and activities of the industry, governmental institutes and academia, road maps on research and development plans for water chemistry were compiled into identified eleven items with targets and counter measures taken, such as common basic technologies, dose reduction, SCC mitigation, fuel cans corrosion/hydrogen absorption mitigation, condition based maintenance and flow accelerated corrosion ...

International Nuclear Information System (INIS)

A photoacoustic (PA) imaging system based on an ultrasonic Fresnel zone plate (FZP) transducer is developed for the purpose of imaging biological tissue. This FZP transducer has a two-zone negative zone plate piezoelectric material pattern, and an optical fibre is integrated with the transducer on the symmetric axis of the zone plates to deliver laser pulses to the sample. The focal characteristic of the FZP transducer is analysed by theoretical prediction and experimental measurement, and the measured results are in good agreement with the predicted results. The limited-field back-projection deconvolution algorithm combined with the coherence-factor weighting technique is used to reconstruct the optical absorption distribution. The experiments were performed with phantoms and the blood vessels of chicken embryo chorioallantoic membrane. The results demonstrate that PA imaging using the FZP transducer has the ability to image biological tissue ...

British Library Electronic Table of Contents (United Kingdom)

Studies addressed to a deep understanding of the structure/property relationship on the near infrared (NIR)-emissive erbium-quinolinolate complexes, which are of interest for low-cost photonic systems, are reviewed. The role of the 8-quinolinolate ligand (Q), which studies also as sensitizer to overcome the weak absorptivity of lanthanide ion, is discussed. Synthetic and structural aspects are reported to revise the old assumption that these complexes are analogous in structure to AlQ3 and to point out the specificity of the lanthanide coordination chemistry. In fact depending on reaction conditions, species with high coordination numbers and differing for nuclearity and stoichiometry have been isolated and fully characterized. In some instances it has been shown that coordinated water mol...

Science.gov (United States)

Photoacoustic microscopy (PAM) offers label-free, optical absorption contrast. A high-speed, high-resolution PAM system in an inverted microscope configuration with a laser pulse repetition rate of 100,000 Hz and a stationary ultrasonic transducer was built. Four-dimensional in vivo imaging of microcirculation in mouse skin was achieved at 18 three-dimensional volumes per second with repeated two-dimensional raster scans of 100 by 50 points. The corresponding twodimensional B-scan (50 A-lines) frame rate was 1800 Hz, and the one-dimensional A-scan rate was 90,000 Hz. The lateral resolution is 0.23+/-0.03 ?m for Au nano-wire imaging, which is 2.0 times below the diffraction limit.

International Nuclear Information System (INIS)

Since Taiwan lacks sufficient self-produced energy, increasing energy efficiency and energy savings are essential aspects of Taiwan's energy policy. This work summarizes the energy savings implemented by 303 firms in Taiwan's textile industry from the on-line Energy Declaration System in 2008. It was found that the total implemented energy savings amounted to 46,074 ton of oil equivalent (TOE). The energy saving was equivalent to 94,614 MWh of electricity, 23,686 kl of fuel oil and 4887 ton of fuel coal. It represented a potential reduction of 143,669 ton in carbon dioxide emissions, equivalent to the annual carbon dioxide absorption capacity of a 3848 ha plantation forest. This study summarizes energy-saving measures for energy users and identifies the areas for making energy saving to provide an energy efficiency baseline.

Energy Technology Data Exchange (ETDEWEB)

Pyrochemical processing of nuclear fuels using molten salts has attracted much attention because of its potential to be applied for a future spent nuclear fuel management. In the pyrochemical processing, there are a number of steps to electro-refine and electro-win each element of lanthanides and actinides, commonly called trans-uranic elements (TRU). In order to materialize the pyrochemical processing in the nuclear power plant environments, qualitatively and quantitatively monitoring of each elements is necessary. Thus, we have undertaken to develop an on-line observing system of the TRU in LiCl-KCl molten salt media by using electrochemical and spectroscopic methods. In this work, the electrochemical and spectroscopic behaviors of europium as a proxy material for TRU were investigated simultaneously in the LiCl-KCl molten salt.

Energy Technology Data Exchange (ETDEWEB)

In the electrorefining step of the pyrochemical process, actinide ions dissolved in the LiCl-KCl eutectic salt are recovered as pure actinide metals at a cathode for a re-use as a nuclear fuel from the aspect of its nonproliferation of the nuclear fuel cycles. The lanthanide species dissolved in the LiCl-KCl eutectic salt play an important role in an effective metal purification during the electrorefining step, so it is necessary to understand the chemical and physical behaviors of lanthanides in molten salt. The in situ spectroscopic measurement system and studies according to temperature changes are essential for better understandable information. To our knowledge, the absorption studies of lanthanides at high temperatures have been reported before, but the fluorescence studies of those at high temperature are not reported yet. We will discuss here the fluorescence behaviors of lanthanides in LiCl-KCl molten salt medium according to a ...

CERN Document Server

Two-dimensional simulations of the coarsening process of the isotropic/smectic-A phase transition are presented using a high-order Landau-de Gennes type free energy model. Defect annihilation laws for smectic disclinations, elementary dislocations, and total dislocation content are determined. The computed evolution of the orientational correlation length and disclination density is found to be in agreement with previous experimental observations showing that disclination interactions dominate the coarsening process. The mechanism of smectic disclination movement, limited by the absorption and emission of elementary dislocations, is found to be facilitated by curvature walls connecting interacting disclinations. At intermediate times in the coarsening process, split-core dislocation formation and interactions displaying an effective disclination quadrupole configuration are observed. This work provides the framework for further understanding of the formation and ...

British Library Electronic Table of Contents (United Kingdom)

In this paper, the unsteady MHD free convection heat and mass transfer of viscous fluid flowing through a Darcian porous regime adjacent to a moving vertical semi-infinite plate under Soret and Dufour effect have been examined. Viscous dissipation effects are included in the energy equation. A uniform magnetic field is applied transversely to the direction of the flow. The differential equations governing the problem have been transformed by a similarity transformation into a system of non-dimensional differential equations which are solved numerically by element free Galerkin method. The influence of Grashof number (Gr), magnetic parameter (M), heat absorption parameter (Q), permeability parameter (K), Schmidt number (Sc), Soret number (Sr), and Dufour number (Du) on the velocity, tempera...

Energy Technology Data Exchange (ETDEWEB)

The MTX explored the plasma heating effects of 140 GHz microwaves from both Gyrotrons and from the IMP FEL wiggler. The Gyrotron was long pulse length (0.5 seconds maximum) and the FEL produced short-pulse length, high-peak power, single and burst modes of 140 GHZ microwaves. Full-power operations of the IMP FEL wiggler were commenced in April of 1992 and continued into October of 1992. The Experimental Test Accelerator H (ETA-II) provided a 50-nanosecond, 6-MeV, 2--3 kAmp electron beam that was introduced co-linear into the IMP FEL with a 140 GHz Gyrotron master oscillator (MO). The FEL was able to amplify the MO signal from approximately 7 kW to peaks consistently in the range of 1--2 GW. This microwave pulse was transmitted into the MTX and allowed the exploration of the linear and non-linear effects of short pulse, intense power in the MTX plasma. Single pulses were used to explore and gain operating experience in the parameter space of the IMP FEL, and finally evaluate ...

Science.gov (United States)

The use of ceramics as energy absorbents has been studied by many researchers and some improvements in the ballistic performance of ceramic tiles have been made by coating them with different classes of materials (e.g. E-glass/epoxy, carbon-fiber/epoxy, etc.). Using ceramics for energy absorbing applications leads to a significant weight reduction of the system. Therefore, any modification to the ceramic configuration in the system which leads to more energy absorption with the same or less areal density is significant. On the other hand, polyurea has been proved to be an excellent energy dissipating agent in many applications. Inspired by this, we are studying the effect of coating ceramics with polyurea and other materials, on the energy absorption and ballistic performance of the resulting ceramic-based composites. In this study, we investigate the effect of polyurea on ballistic efficiency of ...

Energy Technology Data Exchange (ETDEWEB)

The paper is Part 2 of the study on the thermodynamic and thermoeconomic analyses of trigeneration system with a gas-diesel engine. In Part 1, thermodynamic and thermoeconomic methodologies for such a comprehensive analysis were provided, while this paper applies the developed methodology to an actual TRIGEN system with a rated output of 6.5 MW gas-diesel engine installed in the Eskisehir Industry Estate Zone, Turkey. Energy and exergy efficiencies, equivalent electrical efficiency, the Public Utility Regulatory Policies Act (PURPA) efficiency, fuel energy saving ratio, fuel exergy saving ratio and other thermodynamic performance parameters are determined for the TRIGEN system. The efficiencies of energy, exergy, PURPA and equivalent electrical efficiency of the entire system are found to be 58.97%, 36.13%, 45.7% and 48.53%, respectively. For the whole system and its components, ...

International Nuclear Information System (INIS)

To facilitate potential cost savings in pipe whip protection design, TVA conducted a 1'' high pressure line break test to investigate the pipe whip behavior. The test results are available to EPRI as a data base for a generic study on nonlinear dynamic behavior of piping systems and pipe whip phenomena. This paper describes a nonlinear dynamic analysis of the TVA high energy line tests using ABAQUS-EPGEN code. The analysis considers the effects of large deformation and high strain rate on resisting moment and energy absorption capability of the analyzed piping system. The numerical results of impact forces, impact velocities, and reaction forces at pipe supports are compared to the TVA test data. The pipe whip impact time and forces have also been calculated per the current NRC guidelines and compared. The calculated pipe support reaction forces prior to impact have been found to be in good agreement with the TVA test data ...

International Nuclear Information System (INIS)

The survivability of the final optic, which must sit in the line of sight of high-energy neutrons and gamma rays, is a key issue for any laser-driven inertial fusion energy (IFE) concept. Previous work has concentrated on the use of reflective optics. Here, we introduce and analyze the use of a transmissive final optic for the IFE application. Our experimental work has been conducted at a range of doses and dose rates, including those comparable to the conditions at the IFE final optic. The experimental work, in conjunction with detailed analysis, suggests that a thin, fused silica Fresnel lens may be an attractive option when used at a wavelength of 351 nm. Our measurements and molecular dynamics simulations provide convincing evidence that the radiation damage, which leads to optical absorption, not only saturates but that a 'radiation annealing' effect is observed. A system-level description is provided, including Fresnel lens and phase ...

Energy Technology Data Exchange (ETDEWEB)

In portal images with high energy X-ray (10 MV), it is sometimes difficult to verify the irradiation field because of the low contrast. Especially, in the abdominal and pelvic region, the deterioration of portal image quality is remarkable. To solve this problem, we took portal images using computed radiography (FCR). Also, we develop a technique in which a copper plate (3 mm) and lead foil (0.3 mm) are closely set in the front and rear of the photostimulable phosphor plate (imaging plate), for increased energy absorption. As a result, image quality was very high and we confirmed image improvement using observer performance experiments. We made a special cassette which can closely set metallic plates to imaging plate and load FCR-7000 directly. Therefore, image process becomes simple, and suitable for routine work. In computed radiography, image processing (tone scale modification and edge enhancement) is possible, and is advantageous portal imaging. When PACS is ...

UK PubMed Central (United Kingdom)

A method is reported which permits selective suppression of absorption of radioactive strontium from ingested food material, permitting the calcium to be available to the body. Studies were carried...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundSeveral aromatic amines (AA) could cause bladder cancer and are an occupational hygiene problem in the workplace. However, little is known about the percutaneous absorption...Full Text Available

UK PubMed Central (United Kingdom)

To investigate the fate of intrinsic factor and cobalamin during cobalamin absorption, we incubated enterocytes isolated from guinea pig ileum for periods of up to 30 min with ⁵⁷Co-labeled...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.

Energy Technology Data Exchange (ETDEWEB)

The stirling cryocooler ILK 15 is a machine with simple drive concept. This machine works with a conventional built-in electric motor and crank drive and needs a power input of about 500 W. The refrigerating capacity is 15 W at 80 K with a cooldown time of 12 minutes. The cooler is somehow a replacement for the Gifford-McMahon cycle coolers, which are bigger and heavier. The Stirling cryocooler was designed to cool HTSC-components. (orig.) [Deutsch] Der Stirlingkuehler ILK 15 ist eine Kaeltemaschine mit einfachem Antriebskonzept. Die Maschine arbeitet mit einem konventionellen Elektroeinbaumotor und Kurbeltrieb. Sie benoetigt eine Antriebsleistung von 500 W und hat eine Kaelteleistung von 15 W bis 80 K und eine Einkuehlzeit von 12 Minuten. Die Maschine kann als Alternative zur wesentlich groesseren und schweren Gifford-McMahon-Maschine gesehen und bei der Kuehlung von HTSL-Komponenten eingesetzt werden. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Compact heat exchangers have traditionally found wide application in the transportation industry, where they are used as evaporators and condensers in vapor compression cycles for air conditioning and refrigeration. Such heat exchangers possess numerous attractive features including high thermal effectiveness, small size, low weight, design flexibility, and pure counterflow, and they can accommodate multiple streams. Today, there is a widespread interest in expanding the range of application of compact heat exchangers to include phase-change heat transfer in the process industries, among others. An overall objective of this effort is to provide the basis for establishing design technology in this area. In the present study, small channel flow boiling heat transfer was extended to a rectangular channel (4.06 {times} 1.70 mm) using refrigerant 12 (R-12). As with the circular tube studies, the flow channel wall was electrically heated providing a ...

KoreaScience (Korea)

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International Nuclear Information System (INIS)

This is a preliminary study on the sound absorption properties of two tropical hardwoods, Light Red Meranti and Ramin, and their wood-polymer composites. Sound absorption is measured using a standing wave apparatus. The samples are of one thickness (7 mm) and cut longitudinally. Wood-polymer composites are made by impregnating the samples with methyl methacrylate which is polymerized in situ through #gamma#-irradiation. Both woods and their composites are better sound absorbers at higher sound frequencies. With partial impregnation, the absorption coefficients are improved upon particularly in the region between 1-3 kHz. (author).

International Nuclear Information System (INIS)

Rats and guinea pigs were fed "2"3"8Pu either biologically incorporated into alfalfa (by growth of the plant on soil containing Pu) or added as a solution to alfalfa, or were gavaged with a Pu solution. Depending upon the plant material fed, there appeared to be a twofold increase in "2"3"8Pu-gut absorption by the rat and a two- to fourfold increase in the guinea pig as compared with absorption from the Pu solution. The data, though limited and variable, suggest that Pu bound to plant tissue may have higher gut absorptivity than inorganic Pu in both herbivorous and nonherbivorous rodents.

Science.gov (United States)

... The data were transformed into total hemispherical emittance values and correlated with respect to ceramic coating thickness and temperature ...

Science.gov (United States)

... energy absorption characteristics of composite sandwich panels, thermoplastic energy-absorbing subfloor structures, and shoulder belt pre- tensioners. ...

Energy Technology Data Exchange (ETDEWEB)

Once again residual austenite as one component of the microstructure of steels is the basis for discussion among experts. Very often the phenomen of the stabilisation of residual austenite is the focus of interest. In this paper the influence of ageing on residual austenite transformations is discussed, with ageing taking place in a temperature range between ambient and M/sub s/-temperature after quenching from different austenitizing temperatures by means of subzero refrigeration. Results which are typical for 100Cr6 steel are presented and discussed.

Energy Technology Data Exchange (ETDEWEB)

Compact heat exchangers are being increasingly considered for condensation applications in the process, cryogenic, aerospace, power and refrigeration industries. In this paper, different configurations available for condensation applications are analyzed and the current state-of-the-knowledge for the design of compact condensers is evaluated. The key technical issues for the design and development of compact heat exchangers for condensation applications are analyzed and major advantages are identified. The experimental data and performance prediction methods reported in the literature are analyzed to evaluate the present design capabilities for different compact heat-exchanger configurations. The design flexibility is evaluated for the development of new condensation applications, including integration with other process equipment.

Energy Technology Data Exchange (ETDEWEB)

In studying the absorption of carbon dioxide by absorbents impregnated with alkanol amines, researchers used a laboratory-scale packed column to determine the overall gas-phase mass-transfer coefficients and enhancement factors. A model derived for the mechanism of the chemical reaction taking place in the interfacial layer accounts for the effect of the reaction upon the absorption rate better than other models.

Energy Technology Data Exchange (ETDEWEB)

The absolute absorption of ozone in the midinfrared has been measured relative to 253.7-nm ultraviolet absorption to an accuracy of 1% using a Bruker Fourier transform spectrometer. These new results agree with previous measurements by diode laser measurements after the latter are corrected for more recent infrared calculations and ultraviolet cross sections. They also agree with a determination based on refractive index measurements in the infrared. 16 refs., 4 figs., 3 tabs.

Energy Technology Data Exchange (ETDEWEB)

Over the past 40 years, cavern storage of LPG's, petrochemicals, such as ethylene and propylene, and other petroleum products has increased dramatically. In 1991, the Gas Processors Association (GPA) lists the total U.S. underground storage capacity for LPG's and related products of approximately 519 million barrels (82.5 million cubic meters) in 1,122 separate caverns. Of this total, 70 are hard rock caverns and the remaining 1,052 are caverns in salt deposits. However, along the eastern seaboard of the U.S. and the Pacific northwest, salt deposits are not available and therefore, storage in hard rocks is required. Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available ...

International Nuclear Information System (INIS)

Spectral room temperature photoluminescence (pl) of polycrystalline Cu(In,Ga)Se2 films (CIGSe) is evaluated with respect to optoelectronic properties and in particular for the determination of the splitting of quasi-Fermi levels (EFn - EFp). For lateral resolution of ? 1 ?m a confocal pl-setup is used. The depth profile of the excess carrier densities determining the rates of radiative transitions strongly govern the spectral pl-shape which has been numerically modeled with a matrix transfer formalism. In this optical approach we discriminate for wave propagation and attenuation in a multilayer system between a plane-wave ansatz and a 3D-spherical formalism, depending on excitation area large or small/similar compared to the thickness of the absorber. In both cases re-absorption of photons in energetic regimes with absorption approaches unity, from which the splitting of the quasi-Fermi levels is preferentially deduced, ...

International Nuclear Information System (INIS)

A series of crown ethers carrying a pyrene group with nitrogen-sulfur donor atoms, that differ in having three, four and five sulfur atoms in the macrocycle was designed and synthesized by the reaction of the corresponding macrocyclic compound and 1-bromomethylpyrene. The influence of metal cations such as Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+ and Al3+ on the spectroscopic properties of the ligands was investigated in acetonitrile-dichloromethane (1:1) by means of absorption and emission spectrometry. Absorption spectra show isosbestic points in the spectrophotometric titration of Fe2+, Zn2+, Cu2+, Pb2+ and Hg2+. The results of spectrophotometric titration experiments disclosed the complexation compositions and complex stability constants of the novel ligands with Fe2+, Zn2+, Cu2+, Pb2+ and Hg2+ cations. The monoazatetrathia crown ether showed good sensitivity for Cu2+ with linearity in the range 5.0x10-7-2.5x10-6 M and ...

Energy Technology Data Exchange (ETDEWEB)

Measurements of local mass fluxes of liquid, local number fluxes of the drop and local drop size distributions at various locations in the test column were made for wide ranges of liquid flow rates and gas flow rates. An empirical correlation for the volume mean diameter of the drop at the nozzle exit was proposed. Measurements of the rates of absorption of carbon dioxide from carbon dioxide-air mixtures with water sprays (physical absorption) and aqueous sodium hydroxide sprays (chemical absorption) were made for wide range so fluid flow rates, feed gas concentrations, and initial alkali concentrations. The observed dimensionless rates of absorption were compared with the theoretical values by assuming penetration model with second-order irreversible reaction. 11 refs., 7 figs.

Energy Technology Data Exchange (ETDEWEB)

The absorption of solar heat and the attendant thermal and mechanical loadings on the tubes of cavity receivers depend predominantly on the flux distribution of the incident solar radiation. For an axially symmetric cavity receiver with a parabolic dish collector, it is simple to determine the insolation pattern on the receiver internal surfaces if the system is ideal. In such a system the surface of the dish is perfectly parabolic (no contour flaws are present), and the sun's central ray impinges on the dish surface parallel to the focal axis (no sun tracking flaws are present). These two conditions cannot be achieved in practice, and therefore the feasible parabolic dish system is referred to as a real system although, in actual fact, it is only an approximation to any actual system. The purpose of this paper is to devise calculation principles which ...

Science.gov (United States)

Using static Michelson interferometer to get the spectrum information of measurement targets for spectrum identification, under the condition that the interference length is constant, the system can be optimized by BP neural network algorithm for the mixed spectral separation process. Thereby it can realize improving the recognition probability of camouflage target. Collecting the spectrum information in field of view (FOV) by the interferometer and linear array CCD detector, composing the set of mixed spectrum data, with known absorption spectrum of the material as a hidden layer of rules, it used BP neural network to separate the mixed spectrum data. Experiment with different distances, different combinations of mixed background spectrum as the initial data, using steel target (size: 1.5 m x 1.5 m) made of four kinds, the recognition probability of non-camouflage target is about 90% by BP neural network algorithm or the traditional algorithm, ...

Energy Technology Data Exchange (ETDEWEB)

Self-assembled monolayers (SAMs) on various metal, semiconductor or insulator substrates can be easily modified with specific functional groups of interest and have promising applications in surface wetting (hydrophobic/hydrophilic modification), tribology, corrosion protection, sensor electrodes modification, molecular and biomolecular recognition, protein adsorption, cell adhesion, and molecular- or organic-electronic device fabrications. In this paper, we highlight recent progress in the development of SAMs on solid substrates as well as their practical applications, with particular emphasis on the characterization of self-assembled aromatic thiol monolayers with different functional groups on Au(1 1 1) using synchrotron-based photoemission spectroscopy and near-edge X-ray absorption fine structure measurements. The SAM-related molecular orientation, electronic structures, and chemical bonding are presented. Using copper(II) phthalocyanine as a model ...

International Nuclear Information System (INIS)

A calculation program (URA 6.F4) was elaborated on FORTRAN IV language, that through finite differences solves the unidimensional scalar Helmholtz equation, assuming only one energy group, in spherical cylindrical or plane geometry. The purpose is the determination of the flow distribution in a reactor of spherical cylindrical or plane geometry and the critical dimensions. Feeding as entrance datas to the program the geometry, diffusion coefficients and macroscopic transversals cross sections of absorption and fission for each region. The differential diffusion equation is converted with its boundary conditions, to one system of homogeneous algebraic linear equations using the box integration technique. The investigation on criticality is converted then in a succession of eigenvalue problems for the critical eigenvalue. In general, only is necessary to solve the first eigenvalue and its corresponding eigenvector, employing the power method. The ...

Energy Technology Data Exchange (ETDEWEB)

A number of amines can be employed for all volatile treatment (AVT) of steam generator (SG) systems of nuclear power reactors. These amines form complexes with Cu{sup 2+} and Ni{sup 2+} ions which come into water due to corrosion. The redox reactions of a number of Cu(II)-AVT amine complexes and the stability of the transient species formed have been studied by pulse radiolysis technique. Rate constants for the reaction of e{sub aq}{sup -} with a number of Cu(II)-amine complexes have been determined by following the decay of e{sub aq}{sup -} absorption. Stability of Cu(I)-amine complexes was studied by following the kinetics of the bleaching signal formed at the {lambda}{sub max} of the Cu(II) amine complex. Except for Cu(I)-triethanolamine complex all other Cu(I)-amine complexes were found to be stable. One-electron oxidation of Cu(II) amine complexes was studied using azidyl radicals for the oxidation reaction as OH radicals react with the ...

International Nuclear Information System (INIS)

There has been a growing interest in new laser systems for use at mid-infra-red wavelengths, driven by requirements for a number of diverse applications. Developments in mid-IR coating technology are following three major thrusts. In the first, the potential of ion-assisted process is being exploited and the technology is already becoming well established in the optical coating industry. In the second, the benefits of using gas-phase precursors are being explored, driven by the potential of avoiding the generation of second phase inclusion in the coatings with associated reduction in laser damage threshold. Research is also addressing the use of nanocomposite materials with an engineered microstructure to produce coatings with dielectric properties of choice. This paper presents a review of progress in some of these areas with special emphasis on the comparison of the properties of materials at DF laser wavelengths. Evidence is presented which suggests that laser ...

Energy Technology Data Exchange (ETDEWEB)

Sheep red blood cells (SRBCs) were labelled with a concanavalin A-luminol-bovine serum albumin conjugate specific for the transmembrane anion transport protein (Band 3) and exposed to 2450-MHz continuous-wave microwave radiation at an average specific absorption rate of 91W/kg for 10 min. The temperature was held constant at 25, 37, 40, 42, or 45C with an airflow heat-exchange system. Following exposure to microwave or air heating, the decrease in residual base-activated chemiluminescence (CL) of the SRBCs was measured as an indication of infield oxidase activity. Air heating resulted in a significant decrease in residual CL at temperatures above 37C (74% decrease at 45C). Microwave radiation inhibited the decline in residual CL above 37C. At 45C the inhibition was 40%. The results suggest microwave radiation either reversibly altered the thermodynamics of oxygen binding to haemoglobin or failed to energize a significant portion of the ...

International Nuclear Information System (INIS)

The design of a gaging head for a portable radionuclide X-ray fluorescence analyzer is described. The gaging head is designed as a construction unit system which enables the application of lateral reflexion geometry as well as of coaxial geometry. It is designed so that adjustment from one geometry to the other is labour and time saving. The selection of characteristic radiation is performed by a couple of Ross' differential filters. These filters are prepared by a novel technique developed by our laboratory. The filter exchange is effected by the longitudinal move of the couple of filters encapsulated in a holder. The shift of the filters is controlled by means of a triggering mechanism situated in the body of the gaging head handle. This design makes is possible to handle the gaging head during measurements with one hand. A simple interchange of the absorption filter for the transmissive filter allows the operator to avoid any unwanted shift ...

British Library Electronic Table of Contents (United Kingdom)

Two-layered dissolving microneedles of which acral portion contained leuprolide acetate (LA) as solid dispersion were prepared with sodium chondroitin sulfate as the base and the systemic absorption efficiency of LA was studied in rats after administration to their abdominal skin. A patch contained 100 dissolving microneedles of which length and basement diameter were 469.8+/-4.7mm and 284.5+/-9.8mm, where LA content was 14.3+/-1.6mg. In vitro dissolution experiment showed that LA was released from dissolving microneedle patch within 3min. LA was stable in the patch, % recoveries for 3 months were 102.2+/-1.9-95.3+/-1.9%. One and half-patch of LA dissolving microneedles were administered to the rat skin and plasma LA concentrations were measured by LC-MS/MS. Plasma LA concentrations increa...

Energy Technology Data Exchange (ETDEWEB)

Introduced herein is microwave irradiation for the adsorption and desorption of environmental pollutants. Microwaves may be used in two ways, other than through elevation of temperature of a system as a whole with the adsorbent such as activated carbon serving as the heating medium. The first is the application by which desorption is caused to take place of specified molecules. For example, zeolite that has adsorbed water is regenerated when it is irradiated with microwaves in a stream of cooling gas. This is because only the moisture is heated since zeolite is a non-carbon adsorbent that absorbs microwaves but a little. Another case is reported in which microwaves are utilized to desorb H2S, H2O, CO, etc., from molecular sieves. In the second application, coexisting materials different in absorptivity are exposed to irradiation. The adsorption of microwave-absorbent materials is inhibited while that of the others is accelerated. For example, ...

Energy Technology Data Exchange (ETDEWEB)

The paper presents the preparation, X-ray powder diffraction data as well as some magnetic and spectroscopic properties of a new uranium(III) complex bromide of the formula NH{sub 4}UBr{sub 4}.1.5CH{sub 3}CN.6H{sub 2}O. The compound crystallizes in the monoclinic system with a=11.877 A, b=6.385 A, c=6.815 A, {beta}=101.29deg and Z=2. In the 60-240 K range it follows the Curie-Weiss law with {theta}=-37.24 K and {mu}{sub eff}=3.20 B.M. The IR and UV-VIS absorption spectra were recorded in the 80-4000 cm{sup -1} and 4000-26000 cm{sup -1} spectral ranges respectively. Thermal decomposition at a non-static high vacuum enabled the conversion of the compound into pure and anhydrous UBr{sub 3}. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Simultaneously extracted metals (SEM) and acid volatile sulfide (AVS) show the potential for toxicity on the basis of their ratio. Accordingly, the authors spiked cadmium in a range for which Cd/AVS ratios were from 0.2 to 10 in the sediment with its weight about 8 kg in each batch. Dialysis samplers with a cation ion-exchange resin (Dowex 50W-X4) collection were used in a laboratory for the determination of free cadmium concentrations in pore water of the collected sediment. When equilibrium was reached among cadmium in pore water, sediment, and ion-exchange resin, cadmium exchanged onto resin phase was regenerated with 1 N hydrochloric acid (OPTIMA grade) and determined using an atomic absorption spectrophotometer (Zeeman 5000) with a graphite furnace accessory. Cadmium determined using the dialysis sampler is considered as free cadmium which is related to the metal bioavailability toward aquatic biota. The developed methodology provides a new technique for ...

Energy Technology Data Exchange (ETDEWEB)

Sodium-dependent high-affinity choline uptake was measured in the striatum, frontal cortex, hippocampus, and hypothalamus of rats after acute exposure (45 min) to pulsed (2 microseconds, 500 pps) or continuous-wave 2,450-MHz microwaves in cylindrical waveguides or miniature anechoic chambers. In all exposure conditions, the average whole-body specific absorption rate was at 0.6 W/kg. Decrease in choline uptake was observed in the frontal cortex after microwave exposure in all of the above irradiation conditions. Regardless of the exposure system used, hippocampal choline uptake was decreased after exposure to pulsed but not continuous-wave microwaves. Striatal choline uptake was decreased after exposure to either pulsed or continuous-wave microwaves in the miniature anechoic chamber. No significant change in hypothalamic choline uptake was observed under any of the exposure conditions studied. We conclude that depending on the parameters of the ...

CERN Document Server

Recent X-ray and radio observations have identified a transient low-mass X-ray binary (LMXB) located only 0.1 pc in projection from the Galactic center, CXOGC J174540.0-290031. In this paper, we report the detailed analysis of X-ray and infrared observations of the transient and its surroundings. Chandra bservations detect the source at a flux of F_X = 2e-12 erg cm^-2 s^-1 (2-8 keV). After accounting for absorption both in the interstellar medium and in material local to the source, the implied luminosity of the source is only L_X = 4e34 erg/s (2-8 keV; D=8 kpc). However, the diffuse X-ray emission near the source also brightened by a factor of 2. The enhanced diffuse X-ray emission lies on top of a known ridge of dust and ionized gas that is visible infrared images. We interpret the X-ray emission as scattered flux from the outburst, and determine that the peak luminosity of CXOGC J174540.0-290031 was >2e36 erg/s. We suggest that the relatively small observed ...

International Nuclear Information System (INIS)

Tritium is produced in large quantities at heavy water nuclear power reactors via the neutron activation reaction "2H(n,#gamma#)"3H. At Wolsung nuclear power plant which has a CANDU reactor, the tritium concentrations in coolant and in moderator systems are 1.5 Ci/Kg-D_2O and 35 Ci/kg-D_2O, respectively, after 12 years of operation. The airborne tritium concentration in main access area is normally less than 5 MPCa except short-term peaks. The average tritium concentrations in main access controlled areas are normally less than 100 MPCa. Tritium is mainly present in the air of workplace of CANDU reactors as a tritiated water vapour. Airborne tritiated water vapour enters the workers body via inhalation and absorption through skin and can result in a significant dose. The occupational doses from tritium at Wolsung NPP have been maintained below 1 man-Sv per year so far. The tritium contribution to the total plant man-Sv changes between 30 ...

Science.gov (United States)

The spectral dependences of absorption photoinduced in a pure bismuth titanium oxide crystal by 532-nm laser pulses are studied. It is shown that optical absorption in the crystal in the range from 492 to 840 nm increases with increasing exposure. The photoinduced absorption relaxes in the dark for more than 60 hours. A model of photoinduced absorption is proposed which assumes the population of two trap centres with the normal energy distribution law for the concentrations of electrons photoexcited from donors to the conduction band. This model well describes the spectral dependences of photoinduced absorption by using the average ionisation energies of the traps E{sub 1} = 1.60 eV and E{sub 2} = 2.57 eV. The model is used to estimate the increase in the photorefractive sensitivity of a bismuth titanium oxide crystal in the near IR region, which was earlier observed after exposing ...

Energy Technology Data Exchange (ETDEWEB)

Three typical Japanese coals of non-coking coal, coking coal and anthracite were heat-treated with KOH, and change in their pore structure was examined by absorption of N2, X-ray diffraction and TEM observation. In addition, the relation between a coal rank and pore structure was also studied by absorption experiment of N2. In experiment, the mixture of coal and KOH in a nickel holder was heat-treated in N2 gas flow at heating rate of 2{degree}C/min, and held at a fixed temperature for one hour. To clarify the pore structure, N2 absorption isotherms were measured at -196{degree}C under nearly 76cmHg using a commercially available full-automatic absorption measurement equipment. Based on the X-ray diffraction and TEM observation results on activated coals, the relation between the N2 absorption and pore structure was studied. The results are summarized as follows: (1) The yield and ...

International Nuclear Information System (INIS)

We have measured the redshift evolution of the density of Lyman limit systems (LLSs) in the intergalactic medium over the redshift range 0 < z < 6. We have used two new quasar samples to (1) improve coverage at z #approx# 1, with GALEX grism spectrograph observations of 50 quasars with 0.8 < z_e_m < 1.3, and (2) extend coverage to z #approx# 6, with Keck ESI spectra of 25 quasars with 4.17 < z_e_m < 5.99. Using these samples together with published data, we find that the number density of LLS per unit redshift, n(z), can be well fit by a simple evolution of the form n(z) = n_3_._5[(1 + z)/4.5]"#gamma# with n_3_._5 = 2.80 #+-# 0.33 and #gamma# = 1.94"+"0"."3"6_-_0_._3_2 for the entire range 0 < z < 6. We have also reanalyzed the evolution of damped Ly#alpha# systems (DLAs) in the redshift range 4 < z < 5 using our high-redshift quasar sample. We find a total of 17 DLAs and sub-DLAs, which we have analyzed in ...

Energy Technology Data Exchange (ETDEWEB)

Applying a total energy absorption {gamma}-ray detector composed of 12 bricks (5x5 cm{sup 2}, 7.5 cm thick) of Bi{sub 4}Ge{sub 3}O{sub 12}(BGO) scintillators, the absolute measurement of capture cross sections for Au and Sb has been made in an energy region between 0.01 eV and 10 eV using the linac time-of-flight method. Incident thermal neutron flux was absolutely determined by using the BGO detection system with a Sm sample. To extend the neutron flux measurement from the thermal neutron region to higher neutron energy, the {sup 10}B(n, {alpha} {gamma}) reaction was applied. Absolute capture yield for the relevant capture sample was obtained by the saturated capture yield at a large resonance of the sample. Gold was selected to investigate the application of the BGO detection system to the absolute measurement of the capture cross sections, since the {sup 197}Au(n, {gamma}){sup 198}Au reaction cross section is a well ...

Energy Technology Data Exchange (ETDEWEB)

The authors measured the absorption of CO{sub 2} in alkaline 0.5 M/0.5 M sodium carbonate/bicarbonate buffers containing either saccharose and sodium arsenite or saccharose and formaldehyde. Absorption enhancement increased upon increasing the concentration of either of the catalysts, but the joint action of the two was always less than the sum of their individual effects, the difference being a function of the acidities and concentrations of the catalysts and the pH of the carbonate/bicarbonate buffer solution

Science.gov (United States)

... Values of absorption maxima, X.nax, and associated molar extinction coefficients, c, as well as values of the n-octanol/water partition coefficient( ...

International Nuclear Information System (INIS)

Available in abstract form only. Full text of publication follows: In this study. simulation of carbon dioxide absorption by Sodium Hydroxide solution in a packed bed has been investigated. At first, mass and energy balances were applied around a differential height of the bed. So, the governing equations were obtained. Surface renewal theory by Danckwerts was used to represent the mass transfer operation Finally, by changing the operating parameters like solvent temperature, inlet gas composition pressure and height of the bed, the effect of these parameters on the absorption and the composition of carbon dioxide in exit stream have been investigated. (authors)

Energy Technology Data Exchange (ETDEWEB)

Application of an optimization technique to extract the non-ideal parameters of gas absorption with chemical reactions process was described. The gas absorption was modeled using mass transfer theory to represent the realistic behaviors of an absorber. The model was a highly non-linear iterative model which correlated the overall rate of absorption as the function of unknown non-ideal parameters, including the physical liquid mass transfer coefficient and the wetted interfacial area of of packings. The optimization program was developed to minimize the sum of squares of relative errors between the model predictions and the experimental data. Four sets of experimental data (case studies) with different operating conditions were used for extracting parameters. Comparisons between predicted and experimental measured overall absorption rate were in good agreement, average absolute value of relative errors ...

Science.gov (United States)

in early 1992 from Lord Corporation, were also found. For both the reflective and absorptive polyurethanes, the fresh paint fluoresces significantly ...

International Nuclear Information System (INIS)

... School of Plant Biology. v. 23(2) p. 316-322. carbon dioxide absorption carbon

International Nuclear Information System (INIS)

Deferoxamine (DFA) (250 mg/kg), orally administered to rats, decreased Pu absorption from orally administered "2"3"8Pu(NO_3)_4 by about 1/3. The calcium salt of diethylenetriaminepentaacetic acid (Ca-DTPA), given orally 5 to 10 min after the Pu, increased absorption about four times. DFA given 10 min before the DTPA decreased the effect of the latter by a factor of two. Deferoxamine administration prior to inhalation treatment of man with DTPA may be one way to decrease possible DTPA-enhanced gut absorption of Pu.

KoreaScience (Korea)

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The transfer of /sup 203/Pb and/or /sup 47/Ca across the intestinal epithelium of the chick was investigated, with emphasis given to the functional role of cholecalciferol (vitamin D-3). /sup 203/Pb, after introduction in the intestinal lumen, is rapidly accumulated by the intestinal tissue, and only a fraction of /sup 203/ Pb is translocated parenterally (absorbed). Cholecalciferol did not significantly affect the accumulation of /sup 203/Pb by intestinal tissue but did accelerate /sup 203/Pb movement across the basal-lateral membrane. In contrast, cholecalciferol both decreased /sup 47/Ca tissue levels and increased /sup 47/Ca absorption. In rachitic chicks, the rate of absorption of /sup 203/Pb was greater in the distal than in the proximal segments of the intestine; after cholecalciferol repletion, the degree of absorption in all segments was similar, indicating the order of cholecalciferol effectiveness as duodenum ...

Energy Technology Data Exchange (ETDEWEB)

The significant and rapid reduction of greenhouse gas emissions is recognized as necessary to mitigate the potential climate effects from global warming. The postcombustion capture (PCC) and storage of carbon dioxide (CO{sub 2}) produced from the use of fossil fuels for electricity generation is a key technology needed to achieve these reductions. The most mature technology for CO{sub 2} capture is reversible chemical absorption into an aqueous amine solution. In this study the results from measurements of the CO{sub 2} absorption capacity of aqueous amine solutions for 76 different amines are presented. Measurements were made using both a novel isothermal gravimetric analysis (IGA) method and a traditional absorption apparatus. Seven amines, consisting of one primary, three secondary, and three tertiary amines, were identified as exhibiting outstanding absorption capacities. Most have a number of ...

UK PubMed Central (United Kingdom)

Aerosol particles are ubiquitous in the troposphere and exert an important influence on global climate and the environment. They affect climate through scattering, transmission, and absorption of...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The bulk removal of CO/sub 2/ from industrial gases is a frequently applied process in the field of gas-treating. Usually chemical solvents are used in order to increase both the solvent-loading capacity and the absorption rate. These solvents often are aqueous solutions of alkanolamines. The loaded-liquid is regenerated at high temperatures with the aid steam. In the present study absorption rates are experimentally determined in various mixtures of amines over a wide range of concentrations. Simultaneously, a model was developed for the description of mass transfer accompanied by parallel reversible chemical reactions. The equations of this mass transfer model could not be solved analytically and therefore numerical techniques were used to obtain an exact description of this process. This model also includes the asymptotic situations of homogeneous catalysts and shuttle mechanism for which in the literature several approximate solutions have ...

Energy Technology Data Exchange (ETDEWEB)

Heat transfer experiments were performed in the post-CHF two-phase flow regime in a vertical tube. The tube inside diameter was 7.75 mm, and the boiling fluid was R-113. The experiments were performed at steady state by means of liquid heating of the test tube. Wall superheats were maintained below 70 C for heat exchanger/steam generator application. The mass flux range of the data was 379-816 kg m{sup -2} s{sup -1}. The use of R-113 significantly extended the property range of the existing low wall-superheat data base. Experimental data are presented in tabular as well as graphical form, and the results were used with low wall-superheat data from other fluids to add generality to a predictive heat transfer correlation. (orig.)

Energy Technology Data Exchange (ETDEWEB)

This study describes the construction of a simple mathematical model its validation through the simulation in transient state of a real cycle performed by a solar refrigerator based on physical adsorption using an activated carbon/methanol pair. The deviation from experimental results was 4% for the cycled mass of methanol, 2.2 % for maximum collector average temperature, and 3 x 10{sup -3} for the theoretical cycle coefficient of performance. Additional simulations of the same cycle inputting values representing different types and larger amounts of activated carbon showed the possibility of increasing the cycled methanol mass up to about 150%. (author) 26 refs., 16 figs., 9 tabs.

Energy Technology Data Exchange (ETDEWEB)

Banning CFCs in foamed insulations has led to an intensive search for alternatives which do not incur the penalty of increased thickness. The most promising of these are silica aerogels, which have proven to be the leading material, when it comes to thermal insulation and environmental protection. Refrigerators insulated with aerogels have been tested and compared to conventionally insulated ones. Results showed a substantial contribution to the energy performance. Boiler manufacturers using aerogel have been able to reduce energy consumption of water heaters by 20%. Float glass elements evacuated and filled with aerogel as well as aerogel insulated polyester lightwalls and bubble skylights yield excellent U-values and significantly reduced energy losses in buildings. (author)

International Nuclear Information System (INIS)

The term 'Post-CHF' was generally used in the two-phase flow regime in tube flow occurring downstream of the CHF. It has various other names such as dispersed flow, liquid-deficient flow, mist flow and film boiling because the two-phase regime is characterized by a continuous vapor phase with discrete liquid drops and a non-wetted heated surface. The regime has been adopted in a lot of applications including nuclear power plants, fossil power plants, steam generators, refrigeration systems and spray cooling, In particular, this regime has a considerable importance in the areas of light water reactor(LWR) accident analysis (off-normal operating conditions) and design in heat exchangers operating in the once-through mode where subcooled liquid enters the exchanger and superheated vapor exits. Recently, innovative PWRs adopt very high power density increases and so require increased safety margins. For instance, advanced PWRs would be going to use ...

International Nuclear Information System (INIS)

The Procedure determining the concentrations of total rare earth and their determination with a new reagent, tribromochlorophosphonazo (CPA-tB), that is 7-[1-(2, 4, 6-tribromo-phenyl) azo]-2-[1-(2-phosphono-4-chloro-phenyl) azo]-chromotropic acid, in high-level liquid waste and some characters of CPA-tB are studied. CPA-tB and its complexes of rare earth elements are stable in the glycol-H_2O system. Adding glycol shifts the absorption spectrum to left and increases the molar extinction coefficient. The molar extinction coefficients are respectively 7.16 x 10"4 (Y), 11.9 x 10"4 (La), 11.7 x 10"4 (Ce, Pr), 11.9 x 10"4 (Nd), 11.6 x 10"4 (Sm, Eu), 11.4 x 10"4 (Gd) and 11.4 x 10"4 (RE) in the glycol-H_2C_2O_4-H_3PO_4-H_2O system at 643 nm. Th interferes severely the determination of total rare earth, and other elements, U(<100 #mu#g), Al(<20 #mu#g), Fe(<400 #mu#g), Ni,Zr(<100 #mu#g respectively) and some anions, ...

International Nuclear Information System (INIS)

The study area is located in the Bekaa plain of Lebanon totaling about 12753 ha. It lies between the eastern foothills of Mount Lebanon chain and expands across the Litani River towards the foothills of the eastern Anti-Lebanon Mountains. Its characteristics, i.e. natural terrain, climate and socio-economy, make it vulnerable especially due to soil pollution. This paper tries to identify the nature and level of soil pollution by heavy metals. Valley slopes represent a complex landform and lithology that contributed to the formation of different soil. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. Throughout the central part of the plain, groundwater table is abundant and relatively high (<1.0 m. locally) that multiplies the vulnerability of the soil-groundwater system. There are different sources of pollution, such as industrial (tanneries, batteries, leather manufacturing), solid and liquid wastes, and agricultural due ...

Environmental Research Database

DescriptionIn young pigs the post-weaning period is generally characterised by a marked reduction in voluntary feed intake, poor growth and development, and diarrhoea. The associated reduction in digestive and absorptive capacity of the gastrointestinal tract decreases the overall efficiency of nutrient capture and utilisation, thereby causing an increase in nutrient loading to the environment. The reduction in digestive and absorptive efficiency after weaning has implications for lifetime performance be [continued...

International Nuclear Information System (INIS)

Brief summaries are given of research carried out in the following areas: absorption spectroscopy of titanium, niobium, and molybdenum in uranium alloys; atomic absorption spectroscopy of selenium in stainless steel, computer program improvements for spectrophotometer control, and detection of beryllium in stack gases; electrolysis for inactivation of bacteria in cooling-tower water; improved solvent analysis by gas chromatography; sequential radionuclide separation for various sample matrices; progress on an electron microprobe analyzer; and miscellaneous projects.

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the reaction of carbon dioxide in MDEA solutions were studied both experimentally and theoretically. It is concluded that MDEA acts as a homogeneous catalyst for CO/sub 2/ hydrolysis, and as a result the rate of absorption in aqueous MDEA solutions is significantly larger than one would calculate by simply taking into account the alkalinity of the reaction. A possible zwitterion mechanism is proposed for this reaction. The minor effect of ionic strength were also studied with the presence of other ions. 19 references, 6 figures.

International Nuclear Information System (INIS)

During electrolysis of a "2"4"8Cm(III) solution in 2M K_2CO_3 at pH=13, partial oxidation of curium to a higher oxidation state, probably Cm(IV), was observed. The absorption spectra of Cm(III) and Cm(IV) in K_2CO_3 solution were recorded and the molar extinction coefficients of main absorption bands of curium were evaluated. (author).

Energy Technology Data Exchange (ETDEWEB)

The carbon content of silicon single crystals and polycrystals has been measured by charged particle activation analysis (CPAA) and infrared absorption. The authors obtained a linear relationship between the absorption coefficient at 605 cm/sup -1/ and the carbon content obtained by CPAA. They obtained a conversion factor of (1.00 +- 0.03) 10/sup 17//cm/sup 2/ for a 100% substitutional carbon.

Energy Technology Data Exchange (ETDEWEB)

A model for combined mass and heat transfer during nonisothermal gas absorption in a two-phase gas- liquid bubbly medium with a high gas content and/or large times of gas-liquid contact is suggested. Diffusion and thermal interactions between bubbles is taken into account in the approximation of a cellular model of a bubbly medium whereby a bubbly medium is viewed as a periodic structure consisting of identical spherical cells with periodic boundary conditions at a cell boundary. Distribution of concentration of dissolved gas, temperature distribution in liquid and coefficients of mass and heat transfer during nonisothermal absorption of a soluble pure gas from a bubble by liquid are determined. In the limiting case of absorption without heat release the derived formulas recover the expressions for isothermal absorption. (orig.). With 1 fig., 1 tab. [Deutsch] Es wird ein Modell vorgestellt, das den ...

Energy Technology Data Exchange (ETDEWEB)

Absorption of the excimer laser radiations of 193-nm argon fluorine and 308-nm xenon chloride in balanced salt solution, sodium hyaluronate, and human cadaver eyes was measured. The absorption of these materials as considerably different for the two wavelengths; we found that 308-nm light experienced much less absorption than the 193-nm light. The extinction coefficient (k) for 308 nm was k = 0.19/cm for balanced salt solution and k = 0.22/cm for sodium hyaluronate. In contrast to this, the extinction coefficient for 193 nm was k = 140/cm for balanced salt solution and k = 540/cm for sodium hyaluronate. Two 1-day-old human phakic cadaver eyes showed complete absorption with both wavelengths. Using aphakic eyes, incomplete absorption was noted at the posterior pole with 308 nm and complete absorption was noted with 193 nm. The extinction in the anterior part of ...

Energy Technology Data Exchange (ETDEWEB)

This critical review with 28 references examines absorption and emission in the v2 band of the carbon dioxide molecule at around the 15micron wavelength. The argument for additional infrared absorption, the enhanced greenhouse effect due to increased carbon dioxide concentrations, and radiation transport and increased emissions are discussed. Experiments studying the transmission spectra of pure carbon dioxide and carbon dioxide in nitrogen, and comparing them with the results of climate modelling using the HITRAN and GEISA databases, are described.

CERN Document Server

Recent high spatial and spectral resolution investigations of the diffuse interstellar medium (ISM) have found significant evidence for small-scale variations in the interstellar gas on scales less than or equal to 1 pc. To better understand the nature of small-scale variations in the ISM, we have used the KPNO WIYN Hydra multi-object spectrograph, which has a mapping advantage over the single-axis, single-scale limitations of studies using high proper motion stars and binary stars, to obtain moderate resolution (~12 km/s) interstellar Na I D absorption spectra of 172 stars toward the double open cluster h and Chi Persei. All of the sightlines toward the 150 stars with spectra that reveal absorption from the Perseus spiral arm show different interstellar Na I D absorption profiles in the Perseus arm gas. Additionally, we have utilized the KPNO Coude Feed spectrograph to obtain high-resolution (~3 km/s) interstellar Na I D ...

International Nuclear Information System (INIS)

The absorption spectra of plutonium ions in nitric acid have been described. There is a characteristic change in the absorption spectra of Pu v in lithium nitrate solutions. In 2 M-lithium nitrate a new peak at 969 nm and high absorption at 1200 nm are noticed. A decrease in the absorption by about 20% and the appearance of a new shoulder at 1120 nm in 6 M-lithium nitrate are found. There is no change in the spectrum in 4 M-lithium nitrate. The absorption spectra of plutonium ions in the spectral range 200 - 400 nm are interesting. All plutonium ions have an intense band in the region 250 - 260 nm as well as a less intense and rather diffuse band at 320 - 330 nm in lithium nitrate solutions the sharp band at 250 - 260 nm has disappeared. This suggests that this band is very sensitive to the environmental field. The band is probably produced by 5 F"q#-># 5 f"q"-"1 6 d transition ...

Energy Technology Data Exchange (ETDEWEB)

The aim of this work was to study acute alterations of the enterohepatic recirculation (EHR) of bile acids 3 days after an 8-Gy radiation exposure in vivo in the rat by a washout technique. Using this technique in association with HPLC analysis, the EHR of the major individual bile acids was determined in control and irradiated animals. Ex vivo ileal taurocholate absorption was also studied in Ussing chambers. Major hepatic enzyme activities involved in bile acid synthesis were also measured. Measurements of bile acid intestinal content and intestinal absorption efficiency calculation from washout showed reduced intestinal absorption with significant differences from one bile acid to another: absorption of taurocholate and tauromuricholate was decreased, whereas absorption of the more hydrophobic taurochenodeoxycholate was increased, suggesting that intestinal passive diffusion was ...

International Nuclear Information System (INIS)

The differing susceptibility of individuals to the toxic effects of chronic lead exposure has never been fully understood. As the major intake of lead in the human is from food and beverages, any variation between individuals of the quantity of lead absorbed from the gut, and of the distribution and excretion of this lead, may account for the differences in individual susceptibility. The food and beverages themselves may have an influence, and to investigate their effects on absorption, distribution and excretion of lead, experiments were performed on normal subjects using a short lived radionuclide of lead, "2"0"3Pb, and instruments generally available in Nuclear Medicine. Lead absorption between different individuals showed a wide variation when "2"0"3Pb was taken as a single dose between meals. Minerals were found to be mainly responsible for affecting absorption when one subject ingested "2"0"3Pb in control meals from ...

International Nuclear Information System (INIS)

Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO_2 absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the P branch of the fundamental absorption band (2150--1950 cm"-"1) while the CO_2 vibrational-rotational lines were from the far wing of the R branch of the #nu#_3 fundamental band (2395--2380 cm"-"1). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO_2/N_2 gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the ...

Energy Technology Data Exchange (ETDEWEB)

Manganese model complexes, relevant to the oxygen-evolving complex (OEC) in photosynthesis, were studied with Mn K-edge X-ray absorption near-edge spectroscopy (XANES), Mn Kb X-ray emission spectroscopy (XES), and vibrational spectroscopy. A more detailed understanding was obtained of the influence of nuclearity, overall structure, oxidation state, and ligand environment of the Mn atoms on the spectra from these methods. This refined understanding is necessary for improving the interpretation of spectra of the OEC. Mn XANES and Kb XES were used to study a di-(mu)-oxo and a mono-(mu)-oxo di-nuclear Mn compound in the (III,III), (III,IV), and (IV,IV) oxidation states. XANES spectra show energy shifts of 0.8 - 2.2 eV for 1-electron oxidation-state changes and 0.4 - 1.8 eV for ligand-environment changes. The shifts observed for Mn XES spectra were approximately 0.21 eV for oxidation state-changes and only approximately 0.04 eV for ligand-environment changes. This ...

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Both solvent extraction and spectrophotometric techniques were used to show the alterations that gamma radiation causes in the behavior of tetracycline molecule as far as its extracting and complexing power are concerned. The effect of gamma radiation on the solid tetracycline molecule, benzyl alcohol and on the solution of both was examined in solvent extraction systems whose aqueous phases were made up by {sup 152} Eu-{sup 154}Eu radioactive tracer solutions and whose organic phases were constituted by tetracycline-benzyl alcohol solutions. Experiments were performed in order to determine whether or not the water used for the pre-saturation of benzyl alcohol would influence the radiolysis of tetracycline. Solvent extraction and spectrophotometry were the techniques used to obtain the necessary data. Absorption spectra of irradiated tetracycline benzyl alcohol solutions submitted to several gamma radiation doses were examined and the ...

Energy Technology Data Exchange (ETDEWEB)

This work presents a study of the {sup 1}P{sup 0} excited states of He that can be reached by absorption of a single photon carrying an energy close to the double ionization threshold (DIT) (79 eV). Above the DIT, these states are the double continuum states; below, they are the double excited states. These two types of states are tightly coupled to the single continuum states with or without excitation of the residual ion He{sup +}, owing to their degeneracy in energy. In a one-photon process, these states can only be formed owing to the electronic correlations in the system which must be well described to obtain quantitative good results. Our study is a part of the work which aims at a united description of all these doubly excited, ionized-excited, and double continuum states. We use the Hyperspherical R-Matrix with Semiclassical Outgoing Waves (HRM-SOW) method, initially dedicated to double photoionization studies. We extend it to extract ...

Energy Technology Data Exchange (ETDEWEB)

The mechanism of cobalt uptake was investigated using cells of the giant alga Chara corallina in which it is possible to resolve separately uptake by the cell wall and actual influx across the cell membrane. The absorption of {sup 60}Co by Chara cells appeared to saturate within 2 h. but this was mainly due to rapid uptake into the cell wall which accounted for 87-92% of the total activity. Even after prolonged desorption most of the cell-associated {sup 60}Co was found on the cell wall. The intracellular distribution of absorbed {sup 60}Co was investigated by fractionating the cell into cytoplasm and vacuole. It was shown that {sup 60}Co influx to the vacuole occurs simultaneously with influx to the cytoplasm. The transported species appears to be Co{sup 2+} rather than the less charged Co(OH){sup +} or Co(O){sub 2}. {sup 60}Co influx is pH dependent (optimum pH 7-9), and is sensitive to some other divalent metals. Influx from solutions containing 1 {mu}M {sup ...

Energy Technology Data Exchange (ETDEWEB)

The compound semiconductor system InGaAsN exhibits many intriguing properties which are particularly useful for the development of innovative high efficiency thin film solar cells and long wavelength lasers. The bandgap in these semiconductors can be varied by controlling the content of N and In and the thin films can yet be lattice-matched to GaAs. In the present work, x-ray absorption fine structure (XAFS) and grazing incidence x-ray scattering (GIXS) techniques have been employed to probe the local environment surrounding both N and In atoms as well as the interface morphology of InGaAsN thin films epitaxially grown on GaAs. The soft x-ray XAFS results around nitrogen K-edge reveal that N is in the sp{sup 3} hybridized bonding configuration in InGaAsN and GaAsN, suggesting that N impurities most likely substitute for As sites in these two compounds. The results of In K-edge XAFS suggest a possible trend of a slightly larger coordination ...

Energy Technology Data Exchange (ETDEWEB)

The present paper explains the exhaust sources of and measures against CO2, and possibility of driving the electric cars which utilize the solar energy. In the combustion-related field, the thermal power generation attained to 24.6% which was the largest in exhaust quantity of CO2 on a division-by-division basis in FY 1990. On the consumers' side, four large consumption type industries which are steel, cement, paper, pulp and chemical industries totally occupy 64.2% of the exhaust quantity from all the industries. The emission from the cars occupies 17% of all the traffic-related exhaust quantity. The measures consist of decrease, fixation and absorption, among which the decrease is important. Newly developed electric cars comprise GM's Impact in spring, 1990, Nissan's FEN in 1991 and Tokyo Electric Power's IZA. The IZA is a 1800cc class direct drive system-driven sporty sedan which has been much improved for ...

Energy Technology Data Exchange (ETDEWEB)

The shortage of fresh water is increasing at alarming levels, even in temperate zones. Desalination of brackish and seawater is being considered as a solution to growing water demands. Seawater desalination can be accomplished through reverse osmosis, vapor compression, vapor absorption and thermally driven systems. The most suitable process for large-scale desalination plants is successive brine evaporation-condensation with intermediate heat recovery. However, higher process efficiency could be achieved. The use of low temperature heat sources in seawater desalination requires an efficient method of evaporation and condensation at relatively low vapor pressures. This could be achieved in a humidification-dehumidification process using circulated air to enhance evaporation of water. Simulation models, however, neglect either the heat of evaporation or the changes in air and water properties within humidification and condensation towers. ...

Energy Technology Data Exchange (ETDEWEB)

Arsenic in soils from the Asarco lead smelter in East Helena, Montana was characterized by X-ray absorption spectroscopy (XAS). Arsenic oxidation state and geochemical speciation were analyzed as a function of depth (two sampling sites) and surface distribution. These results were compared with intensive desorption/dissolution experiments performed in a pH stat reactor for samples from the site with the highest degree of As heterogeneity. The objectives of the study were to investigate the solid-phase geochemical As speciation, assess the speciation of As in solutions equilibrated with the solids under controlled pH (pH=4 or 6) and Eh (using hydrogen or air) environments, observe the effects of phosphate on the release of As into solution, and examine the effects of phosphate on metal mobility in the systems. Arsenic was predominantly found in the As(V) valence state, though there was evidence that As(III) and As(0) were present also. The ...